WorldWideScience

Sample records for helium liquefaction plant

  1. Helium refrigeration system for hydrogen liquefaction applications

    Nair, J. Kumar, Sr.; Menon, RS; Goyal, M.; Ansari, NA; Chakravarty, A.; Joemon, V.

    2017-02-01

    Liquid hydrogen around 20 K is used as cold moderator for generating “cold neutron beam” in nuclear research reactors. A cryogenic helium refrigeration system is the core upon which such hydrogen liquefaction applications are built. A thermodynamic process based on reversed Brayton cycle with two stage expansion using high speed cryogenic turboexpanders (TEX) along with a pair of compact high effectiveness process heat exchangers (HX), is well suited for such applications. An existing helium refrigeration system, which had earlier demonstrated a refrigeration capacity of 470 W at around 20 K, is modified based on past operational experiences and newer application requirements. Modifications include addition of a new heat exchanger to simulate cryogenic process load and two other heat exchangers for controlling the temperatures of helium streams leading out to the application system. To incorporate these changes, cryogenic piping inside the cold box is suitably modified. This paper presents process simulation, sizing of new heat exchangers as well as fabrication aspects of the modified cryogenic process piping.

  2. The Liquefaction of Hydrogen and Helium Using Small Coolers

    Green, Michael A.

    2006-01-01

    This report discusses the history of the liquefaction of hydrogen and helium using small coolers. This history dates form the 1960's when two stage GM coolers capable of reaching 7 K were used to liquefy helium and hydrogen by suing an added compressor and J-T circuit. Liquefaction using the added circuit failed to become mainstream because the J-T valve and heat exchanger clogged because of impurities in the gas being liquefied. Liquefaction using a GM cooler without an added J-T circuit proved to be difficult because the first stage was not used to pre-cool the gas coming to the second stage of the cooler. Once the gas being liquefied was pre-cooled using the cooler first stage, improvements in the liquefaction rates were noted. The advent of low temperature pulse tube cooler (down to 2.5 K) permitted one to achieve dramatic improvement is the liquefactions rates for helium. Similar but less dramatic improvements are expected for hydrogen as well. Using the PT-415 cooler, one can expect liquefaction rates of 15 to 20 liters per day for helium or hydrogen provided the heat leak into the cooler and the storage vessel is low. A hydrogen liquefier for MICE is presented at the end of this report

  3. Role of expanders in helium liquefaction cycles: Parametric studies using Collins cycle

    Thomas, Rijo Jacob; Ghosh, Parthasarathi; Chowdhury, Kanchan

    2011-01-01

    Large scale helium liquefaction/refrigeration plant is a key subsystem of fusion devices. Performance of these plants is dependent on a number of geometric and operating parameters of its constituting components such as compressors, heat exchangers, expanders, valves, etc. Expander has been chosen as the subject matter of analyses in the present study. As the sensible cold of helium vapor is lost in liquefiers, the expanders in liquefaction cycles have to provide more refrigeration than those in refrigeration cycles. The expander parameters such as rate of mass flow, operating pressure, inlet temperature, etc. are inter-dependent, and hence, it is difficult to predict the system behavior with variation of a particular parameter. This necessitates the use of process simulators. Parametric studies have been performed on Collins helium liquefaction cycle using Aspen HYSYS. Collins cycle has all the basic characteristics of a large-scale helium liquefier and the results of this study may be extrapolated to understand the behavior of large scale helium liquefiers. The study shows that the maximum liquid production is obtained when 80% of the compressor flow is diverted through the expanders and it is equally distributed between the two expanders. The relationships between the liquid production and the isentropic efficiency of expanders are almost linear and both the higher and lower temperature expanders exhibit similar trends.

  4. Role of expanders in helium liquefaction cycles: Parametric studies using Collins cycle

    Thomas, Rijo Jacob, E-mail: rijojthomas@gmail.com [Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur, West Bengal 721302 (India); Ghosh, Parthasarathi; Chowdhury, Kanchan [Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur, West Bengal 721302 (India)

    2011-06-15

    Large scale helium liquefaction/refrigeration plant is a key subsystem of fusion devices. Performance of these plants is dependent on a number of geometric and operating parameters of its constituting components such as compressors, heat exchangers, expanders, valves, etc. Expander has been chosen as the subject matter of analyses in the present study. As the sensible cold of helium vapor is lost in liquefiers, the expanders in liquefaction cycles have to provide more refrigeration than those in refrigeration cycles. The expander parameters such as rate of mass flow, operating pressure, inlet temperature, etc. are inter-dependent, and hence, it is difficult to predict the system behavior with variation of a particular parameter. This necessitates the use of process simulators. Parametric studies have been performed on Collins helium liquefaction cycle using Aspen HYSYS. Collins cycle has all the basic characteristics of a large-scale helium liquefier and the results of this study may be extrapolated to understand the behavior of large scale helium liquefiers. The study shows that the maximum liquid production is obtained when 80% of the compressor flow is diverted through the expanders and it is equally distributed between the two expanders. The relationships between the liquid production and the isentropic efficiency of expanders are almost linear and both the higher and lower temperature expanders exhibit similar trends.

  5. An optimum cold end configuration for helium liquefaction cycles

    Minta, M.; Smith, J.L.

    1984-01-01

    This chapter examines the effect of the non-ideal behavior of helium at low temperature on the performance of helium liquefaction cycles. The effect is isolated by means of a continuum model for the precooling stage. The cold end losses are due primarily to the composite effect of the non-ideality of helium at low temperatures and the heat exchanger losses, in addition to the component losses fixed by the expander/compressor efficiencies. Topics considered include continuously distributed full-pressure ratio expanders, continuously distributed full-flow expanders, the heat exchange effect (ideal gas working fluid, real gas working fluid), and cold end configuration. The cold end configuration minimizes the cycle cold end losses

  6. An entropy flow optimization technique for helium liquefaction cycles

    Minta, M.; Smith, J.L.

    1984-01-01

    This chapter proposes a new method of analyzing thermodynamic cycles based on a continuous distribution of precooling over the temperature range of the cycle. The method gives the optimum distribution of precooling over the temperature range of the cycle by specifying the mass flow to be expanded at each temperature. The result is used to select a cycle configuration with discrete expansions and to initialize the independent variables for final optimization. Topics considered include the continuous precooling model, the results for ideal gas, the results for real gas, and the application to the design of a saturated vapor compression (SVC) cycle. The optimization technique for helium liquefaction cycles starts with the minimization of the generated entropy in a cycle model with continuous precooling. The pressure ratio, the pressure level and the distribution of the heat exchange are selected based on the results of the continuous precooling analysis. It is concluded that the technique incorporates the non-ideal behavior of helium in the procedure and allows the trade-off between heat exchange area and losses to be determined

  7. Role of heat exchangers in helium liquefaction cycles: Simulation studies using Collins cycle

    Thomas, Rijo Jacob, E-mail: rijojthomas@gmail.com [Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur 721302 (India); Ghosh, Parthasarathi; Chowdhury, Kanchan [Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur 721302 (India)

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer Role of heat exchangers in basic helium liquefier analyzed to design large-scale ones. Black-Right-Pointing-Pointer Heat exchangers that determine inlet temperature to expanders are more significant. Black-Right-Pointing-Pointer Limiting values of nondimensional UA for each heat exchanger have been determined. Black-Right-Pointing-Pointer Extra area distributed such that effectiveness of all heat exchangers increase uniformly. Black-Right-Pointing-Pointer Heat exchanger performance variation have little influence on the optimum expander flow. - Abstract: Energy efficiency of large-scale helium liquefiers generally employed in fusion reactors and accelerators is determined by the performance of their constituting components. Simulation with Aspen HYSYS{sup Registered-Sign} V7.0, a commercial process simulator, helps to understand the effects of heat exchanger parameters on the performance of a helium liquefier. Effective UA (product of overall heat transfer coefficient U, heat transfer surface area A and deterioration factor F) has been taken as an independent parameter, which takes into account all thermal irreversibilities and configuration effects. Nondimensionalization of parameters makes the results applicable to plants of any capacity. Rate of liquefaction is found to increase linearly with the effectiveness of heat exchangers. Performance of those heat exchangers that determine the inlet temperatures to expanders have more influence on the liquid production. Variation of sizes of heat exchangers does not affect the optimum rate of flow through expanders. Increasing UA improves the rate of liquid production; however, the improvement saturates at limiting UA. Maximum benefit in liquefaction is obtained when the available heat transfer surface area is distributed in such a way that the effectiveness remains equal for all heat exchangers. Conclusions from this study may be utilized in analyzing and designing large helium

  8. Role of heat exchangers in helium liquefaction cycles: Simulation studies using Collins cycle

    Thomas, Rijo Jacob; Ghosh, Parthasarathi; Chowdhury, Kanchan

    2012-01-01

    Highlights: ► Role of heat exchangers in basic helium liquefier analyzed to design large-scale ones. ► Heat exchangers that determine inlet temperature to expanders are more significant. ► Limiting values of nondimensional UA for each heat exchanger have been determined. ► Extra area distributed such that effectiveness of all heat exchangers increase uniformly. ► Heat exchanger performance variation have little influence on the optimum expander flow. - Abstract: Energy efficiency of large-scale helium liquefiers generally employed in fusion reactors and accelerators is determined by the performance of their constituting components. Simulation with Aspen HYSYS ® V7.0, a commercial process simulator, helps to understand the effects of heat exchanger parameters on the performance of a helium liquefier. Effective UA (product of overall heat transfer coefficient U, heat transfer surface area A and deterioration factor F) has been taken as an independent parameter, which takes into account all thermal irreversibilities and configuration effects. Nondimensionalization of parameters makes the results applicable to plants of any capacity. Rate of liquefaction is found to increase linearly with the effectiveness of heat exchangers. Performance of those heat exchangers that determine the inlet temperatures to expanders have more influence on the liquid production. Variation of sizes of heat exchangers does not affect the optimum rate of flow through expanders. Increasing UA improves the rate of liquid production; however, the improvement saturates at limiting UA. Maximum benefit in liquefaction is obtained when the available heat transfer surface area is distributed in such a way that the effectiveness remains equal for all heat exchangers. Conclusions from this study may be utilized in analyzing and designing large helium plants.

  9. Exergy analysis of helium liquefaction systems based on modified Claude cycle with two-expanders

    Thomas, Rijo Jacob; Ghosh, Parthasarathi; Chowdhury, Kanchan

    2011-06-01

    Large-scale helium liquefaction systems, being energy-intensive, demand judicious selection of process parameters. An effective tool for design and analysis of thermodynamic cycles for these systems is exergy analysis, which is used to study the behavior of a helium liquefaction system based on modified Claude cycle. Parametric evaluation using process simulator Aspen HYSYS® helps to identify the effects of cycle pressure ratio and expander flow fraction on the exergetic efficiency of the liquefaction cycle. The study computes the distribution of losses at different refrigeration stages of the cycle and helps in selecting optimum cycle pressures, operating temperature levels of expanders and mass flow rates through them. Results from the analysis may help evolving guidelines for designing appropriate thermodynamic cycles for practical helium liquefaction systems.

  10. Re-Condensation and Liquefaction of Helium and Hydrogen Using Coolers

    Green, Michael A.

    2009-01-01

    Coolers are used to cool cryogen free devices at temperatures from 5 to 30 K. Cryogen free cooling involves a temperature drop within the device being cooled and between the device and the cooler cold heads. Liquid cooling with a liquid cryogen distributed over the surface of a device combined with re-condensation can result in a much lower temperature drop between the cooler and the device being cooled. The next logical step beyond simple re-condensation is using a cooler to liquefy the liquid cryogen in the device. A number of tests of helium liquefaction and re-condensation of helium have been run using a pulse tube cooler in the drop-in mode. This report discusses the parameter space over which re-condensation and liquefaction for helium and hydrogen can occur.

  11. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  12. Thermodynamic design of hydrogen liquefaction systems with helium or neon Brayton refrigerator

    Chang, Ho-Myung; Ryu, Ki Nam; Baik, Jong Hoon

    2018-04-01

    A thermodynamic study is carried out for the design of hydrogen liquefaction systems with helium (He) or neon (Ne) Brayton refrigerator. This effort is motivated by our immediate goal to develop a small-capacity (100 L/h) liquefier for domestic use in Korea. Eight different cycles are proposed and their thermodynamic performance is investigated in comparison with the existing liquefaction systems. The proposed cycles include the standard and modified versions of He Brayton refrigerators whose lowest temperature is below 20 K. The Brayton refrigerator is in direct thermal contact with the hydrogen flow at atmospheric pressure from ambient-temperature gas to cryogenic liquid. The Linde-Hampson system pre-cooled by a Ne Brayton refrigerator is also considered. Full cycle analysis is performed with the real properties of fluids to estimate the figure of merit (FOM) under an optimized operation condition. It is concluded that He Brayton refrigerators are feasible for this small-scale liquefaction, because a reasonably high efficiency can be achieved with simple and safe (low-pressure) operation. The complete cycles with He Brayton refrigerator are presented for the development of a prototype, including the ortho-to-para conversion.

  13. Small scale demand type neon liquefaction plant

    Dube, W.P.; Slifka, A.J.; Bitsy, R.M.; Sparks, L.L.; Johnson, K.B.

    1990-01-01

    Low-temperature measurement of the thermal conductivity of insulating materials is generally made using a boil-off calorimetry technique involving liquid hydrogen (LH2). Liquid neon (LNe) has nearly the same normal boiling point as LH2, but has a much larger heat of vaporization, allowing extended run times. The main drawback of using LNe has been its excessive cost; $170.00 versus $1.50/l for LH2 (1989 prices). A neon liquefaction plant has been designed and constructed to capture, purify, and refrigerate the neon boil-off from calorimetry experiments. Recycling the neon reduces operating costs to approximately $20/l. The system consists of a purification section, a heat exchanger, LNe and LH2 storage dewars, and a fully automated control system. After purification, neon is liquified in the heat exchanger by LH2 flowing countercurrently through stainless steel cooling coils. Hydrogen flow is automatically adjusted to keep the neon at its normal saturation temperature, 27 K. The liquid neon is then stored in a dewar placed directly below the heat exchanger

  14. Hydrothermal Liquefaction of Wastewater Treatment Plant Solids

    Billing, Justin M.

    2016-10-16

    Feedstock cost is the greatest barrier to the commercial production of biofuels. The merits of any thermochemical or biological conversion process are constrained by their applicability to the lowest cost feedstocks. At PNNL, a recent resource assessment of wet waste feedstocks led to the identification of waste water treatment plant (WWTP) solids as a cost-negative source of biomass. WWTP solids disposal is a growing environmental concern [1, 2] and can account for up to half of WWTP operating costs. The high moisture content is well-suited for hydrothermal liquefaction (HTL), avoiding the costs and parasitic energy losses associated with drying the feedstock for incineration. The yield and quality of biocrude and upgraded biocrude from WWTP solids is comparable to that obtained from algae feedstocks but the feedstock cost is $500-1200 less per dry ton. A collaborative project was initiated and directed by the Water Environment & Reuse Foundation (WERF) and included feedstock identification, dewatering, shipping to PNNL, conversion to biocrude by HTL, and catalytic hydrothermal gasification of the aqueous byproduct. Additional testing at PNNL included biocrude upgrading by catalytic hydrotreatment, characterization of the hydrotreated product, and a preliminary techno-economic analysis (TEA) based on empirical results. This short article will cover HTL conversion and biocrude upgrading. The WERF project report with complete HTL results is now available through the WERF website [3]. The preliminary TEA is available as a PNNL report [4].

  15. Analysis of engineering cycles power, refrigerating and gas liquefaction plant

    Haywood, R W

    1991-01-01

    Extensively revised, updated and expanded, the fourth edition of this popular text provides a rigorous analytical treatment of modern energy conversion plant. Notable for both its theoretical and practical treatment of conventional and nuclear power plant, and its studies of refrigerating and gas-liquefaction plant. This fourth edition now includes material on topics of increasing concern in the fields of energy 'saving' and reduction of environmental pollution. This increased coverage deals specifically with the following areas: CHP (cogeneration) plant, studies of both gas and coal burning p

  16. Failure analysis at a 2 kW helium liquefaction facility; Fehleranalyse bei einer 2kW- Heliumverfluessigungsanlage

    Klenk, Rafael; Bobien, Steffen; Neumann, Holger [KIT Campus Nord, Eggenstein-Leopoldshafen (Germany). Bereich Kryotechnik

    2016-07-01

    At the Institute for Technical Physics of the KIT Campus Nord helium is cooled respectively liquefied by means of the Claude process. This process is beside the Brayton and Joule-Thomson process meanwhile a standard process for the liquefaction of helium. As example here a 2 kW low-temperature helium facility shall be evaluated by means of different, superordinated failure sources. This consists of condensers, heat exchangers, expansion turbines and a Joule-Thomson valve. The facility respectively component failures are divided in failures of the condenser, turbine units and failures by external factors. For this entries of the last twelve years are token. This listing shall give information about repeating events, so that here directed facility improvements can be token up.

  17. Helium turbomachinery operating experience from gas turbine power plants and test facilities

    McDonald, Colin F.

    2012-01-01

    The closed-cycle gas turbine, pioneered and deployed in Europe, is not well known in the USA. Since nuclear power plant studies currently being conducted in several countries involve the coupling of a high temperature gas-cooled nuclear reactor with a helium closed-cycle gas turbine power conversion system, the experience gained from operated helium turbomachinery is the focus of this paper. A study done as early as 1945 foresaw the use of a helium closed-cycle gas turbine coupled with a high temperature gas-cooled nuclear reactor, and some two decades later this was investigated but not implemented because of lack of technology readiness. However, the first practical use of helium as a gas turbine working fluid was recognized for cryogenic processes, and the first two small fossil-fired helium gas turbines to operate were in the USA for air liquefaction and nitrogen production facilities. In the 1970's a larger helium gas turbine plant and helium test facilities were built and operated in Germany to establish technology bases for a projected future high efficiency large nuclear gas turbine power plant concept. This review paper covers the experience gained, and the lessons learned from the operation of helium gas turbine plants and related test facilities, and puts these into perspective since over three decades have passed since they were deployed. An understanding of the many unexpected events encountered, and how the problems, some of them serious, were resolved is important to avoid them being replicated in future helium turbomachines. The valuable lessons learned in the past, in many cases the hard way, particularly from the operation in Germany of the Oberhausen II 50 MWe helium gas turbine plant, and the technical know-how gained from the formidable HHV helium turbine test facility, are viewed as being germane in the context of current helium turbomachine design work being done for future high efficiency nuclear gas turbine plant concepts. - Highlights:

  18. Liquid helium plant in Dubna

    Agapov, N.N.; Baldin, A.M.; Kovalenko, A.D.

    1995-01-01

    The liquid-helium cooling capacity installed at the Laboratory of High Energies is about 5 kw at a 4.5 K temperature level. It is provided with four industrial helium liquefiers of 1.6 kw/4.5 K each. They have been made by the Russian enterprise NPO GELYMASH and upgraded by the specialists of the Laboratory. The first one was put into operation in 1980, the two others in 1991, and the last one is under commissioning. The development of the LHE cryoplant was concerned with the construction of the new superconducting accelerator Nuclotron aimed to accelerate nuclei and heavy ions up to energies of 6 GeV/u. The first test run at the Nuclotron was carried out in March 1993, and the total running time has been about 2000 hours up to now. Since 1992 the cryoplant has been intensively used by the users outside the Laboratory. More than a million liters of liquid helium was provided in 1993 for such users. The reliability of the cryoplant system was as high as 98 percent for 4500 hours of operation in 1993-1994. 7 refs., 4 figs., 1 tab

  19. Low-Cost Methane Liquefaction Plant and Vehicle Refueling Station

    Wilding, B.; Bramwell, D.

    1999-01-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is currently negotiating a collaborative effort with Pacific Gas and Electric (PG and E) that will advance the use of liquefied natural gas (LNG) as a vehicle fuel. We plan to develop and demonstrate a small-scale methane liquefaction plant (production of 5,000 to 10,000 gallons per day) and a low-cost ($150,000) LNG refueling station to supply fuel to LNG-powered transit buses and other heavy-duty vehicles. INEEL will perform the research and development work. PG and E will deploy the new facilities commercially in two demonstration projects, one in northern California, and one in southern California

  20. Assessment of materials selection and performance for direct-coal- liquefaction plants in the United States

    Olsen, A.R.; Judkins, R.R.; Keiser, J.R.

    1996-09-01

    Several direct coal liquefaction processes have been demonstrated at the pilot plant level in the United States. Presently only one plant remains operational, namely, the Hydrocarbon Technologies, Inc., 4.0- ton-per-day process development unit in Lawrenceville, New Jersey. The period from 1974 to 1982 saw the greatest amount of development of direct coal liquefaction in the United States with four major pilot plants being devoted to variants of this technology. The plants included the SRC-I plant at Wilsonville, Alabama, which operated from 1974 to 1992; the SRC-I/II plant at Fort Lewis, Washington, which operated from 1974 to 1981; the H-Coal plant at Catlettsburg, Kentucky, which operated from 1980 to 1982; and the Exxon Coal Liquefaction Pilot Plant at Baytown, Texas, which operated from 1980 to 1982. Oak Ridge National Laboratory scientists and engineers were actively involved in many phases and technical disciplines at all four of these plants, especially in materials testing, evaluation, and failure analyses. In addition, ORNL materials scientists and engineers conducted reviews of the demonstration and commercial plant designs for materials selections. The ORNL staff members worked closely with materials engineers at the pilot plants in identifying causes of materials degradation and failures, and in identifying solutions to these problems. This report provides a comprehensive summary of those materials activities. Materials performance data from laboratory and coal liquefaction pilot plant tests, failure analyses, and analyses of components after use in pilot plants were reviewed and assessed to determine the extent and causes of materials degradation in direct coal liquefaction process environments. Reviews of demonstration and commercial plant design documents for materials selections were conducted. These reviews and assessments are presented to capture the knowledge base on the most likely materials of construction for direct coal liquefaction plants.

  1. Characterisation of Liquefaction Effects for Beyond-Design Basis Safety Assessment of Nuclear Power Plants

    Bán, Zoltán; Győri, Erzsébet; János Katona, Tamás; Tóth, László

    2015-04-01

    Preparedness of nuclear power plants to beyond design base external effects became high importance after 11th of March 2011 Great Tohoku Earthquakes. In case of some nuclear power plants constructed at the soft soil sites, liquefaction should be considered as a beyond design basis hazard. The consequences of liquefaction have to be analysed with the aim of definition of post-event plant condition, identification of plant vulnerabilities and planning the necessary measures for accident management. In the paper, the methodology of the analysis of liquefaction effects for nuclear power plants is outlined. The case of Nuclear Power Plant at Paks, Hungary is used as an example for demonstration of practical importance of the presented results and considerations. Contrary to the design, conservatism of the methodology for the evaluation of beyond design basis liquefaction effects for an operating plant has to be limited to a reasonable level. Consequently, applicability of all existing methods has to be considered for the best estimation. The adequacy and conclusiveness of the results is mainly limited by the epistemic uncertainty of the methods used for liquefaction hazard definition and definition of engineering parameters characterizing the consequences of liquefaction. The methods have to comply with controversial requirements. They have to be consistent and widely accepted and used in the practice. They have to be based on the comprehensive database. They have to provide basis for the evaluation of dominating engineering parameters that control the post-liquefaction response of the plant structures. Experience of Kashiwazaki-Kariwa plant hit by Niigata-ken Chuetsu-oki earthquake of 16 July 2007 and analysis of site conditions and plant layout at Paks plant have shown that the differential settlement is found to be the dominating effect in case considered. They have to be based on the probabilistic seismic hazard assessment and allow the integration into logic

  2. Thermodynamic analysis and economical evaluation of two 310-80 K pre-cooling stage configurations for helium refrigeration and liquefaction cycle

    Zhu, Z. G.; Zhuang, M.; Jiang, Q. F.; Y Zhang, Q.; Feng, H. S.

    2017-12-01

    In 310-80 K pre-cooling stage, the temperature of the HP helium stream reduces to about 80 K where nearly 73% of the enthalpy drop from room temperature to 4.5 K occurs. Apart from the most common liquid nitrogen pre-cooling, another 310-80 K pre-cooling configuration with turbine is employed in some helium cryoplants. In this paper, thermodynamic and economical performance of these two kinds of 310-80 K pre-cooling stage configurations has been studied at different operating conditions taking discharge pressure, isentropic efficiency of turbines and liquefaction rate as independent parameters. The exergy efficiency, total UA of heat exchangers and operating cost of two configurations are computed. This work will provide a reference for choosing 310-80 K pre-cooling stage configuration during design.

  3. Conceptual design of an integrated hydrothermal liquefaction and biogas plant for sustainable bioenergy production

    Hoffmann, Jessica; Rudra, Souman; Toor, Saqib

    2013-01-01

    Initial process studies carried out in Aspen Plus on an integrated thermochemical conversion process are presented herein. In the simulations, a hydrothermal liquefaction (HTL) plant is combined with a biogas plant (BP), such that the digestate from the BP is converted to a biocrude in the HTL...... grid or for CHP. An estimated 62–84% of the biomass energy can be recovered in the biofuels....

  4. Helium turbomachine design for GT-MHR power plant

    McDonald, C.F.; Orlando, R.J.

    1994-07-01

    The power conversion system in the gas turbine modular helium reactor (GT-MHR) power plant is based on a highly recuperated closed Brayton cycle. The major component in the direct cycle system is a helium closed-cycle gas turbine rated at 286 MW(e). The rotating group consists of an intercooled helium turbocompressor coupled to a synchronous generator. The vertical rotating assembly is installed in a steel vessel, together with the other major components (i.e., recuperator, precooler, intercooler, and connecting ducts and support structures). The rotor is supported on an active magnetic bearing system. The turbine operates directly on the reactor helium coolant, and with a temperature of 850 degree C (1562 degree F) the plant efficiency is over 47%. This paper addresses the design and development planning of the helium turbomachine, and emphasizes that with the utilization of proven technology, this second generation nuclear power plant could be in service in the first decade of the 21st century

  5. FY 1980 Report on results of Sunshine Project. Development of coal liquefaction techniques (Development of materials for the coal liquefaction plant); 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sekitan ekika plant zairyo no kaihatsu

    NONE

    1981-03-01

    A 1 T/D solvent-extraction type coal liquefaction test plant was constructed and operated to obtain the technical data for the design of, and establish the techniques for, an efficient coal liquefaction plant. The FY 1980 program includes surveys on the materials for coal liquefaction plants, covering those already developed and under development, to clarify the problematical points; drafting the test schedules; and conceptual designs of the material testing facilities. The major problems involved in the materials for coal liquefaction plants include erosion by fluidizing coal slurry, hydrogen embrittlement of the reactor materials, and corrosion by the liquefaction products (e.g., stress-corrosion cracking of austenitic steel, and corrosion by organic acids). The surveys on materials research trends suggest that USA seems to concentrate their research efforts on the reactor materials. The corrosion tests are mostly of in-plant tests, but the stress corrosion and slurry erosion tests are conducted on a laboratory scale. The conceptual designs are drawn for some testing units, e.g., the loop type material testing unit and basic testing unit for jet-spray type slurry erosion. (NEDO)

  6. HeREF-2003: Helium Refrigeration Techniques

    2003-01-01

    CERN Technical Training 2003: Learning for the LHC ! Theory, Technology, Maintenance and Control of Helium Refrigerators HeREF-2003 is a course in the framework of the 2002 Technical Training Programme, that will provide a complete introduction to Helium refrigeration, with a practical approach to theory, technology, maintenance and control of Helium refrigeration installations. Theoretical aspects and equations will be limited to a minimum. HeREF-2003 targets an audience of technicians and operators of Helium refrigeration plants at CERN, as well as physicists and engineers needing an overview of current Helium refrigeration techniques. HeREF-2003 will address, among other, issues related to component technology, installation maintenance, process control and Helium purity. A commented visit to a couple of CERN Helium refrigeration or liquefaction plants will also take place. Duration: 7 half days (4 mornings and 3 afternoons), 6-10 October, 2003 Cost per participant: 500.- CHF Language: Bilingual English...

  7. HeREF-2003 : Helium Refrigeration Techniques

    2003-01-01

    CERN Technical Training 2003: Learning for the LHC ! Theory, Technology, Maintenance and Control of Helium Refrigerators HeREF-2003 is a course in the framework of the 2002 Technical Training Programme, that will provide a complete introduction to Helium refrigeration, with a practical approach to theory, technology, maintenance and control of Helium refrigeration installations. Theoretical aspects and equations will be limited to a minimum. HeREF-2003 targets an audience of technicians and operators of Helium refrigeration plants at CERN, as well as physicists and engineers needing an overview of current Helium refrigeration techniques. HeREF-2003 will address, among other, issues related to component technology, installation maintenance, process control and Helium purity. A commented visit to a couple of CERN Helium refrigeration or liquefaction plants will also take place. • Duration: 7 half days (4 mornings and 3 afternoons), 6-10 October, 2003 • Cost per participant: 500.- CHF ...

  8. Simulation and Optimization of an Innovative Dual Mixed Component Refrigerant Cycle (DMRC) for Natural Gas Offshore Liquefaction Plants

    SHAHBA, L.A.; Fahmy, M.F.M.

    2004-01-01

    Simulation and optimization of an innovative liquefaction process used for the LNG production , namely the Dual Mixed Refrigerant Process (DMRC) has been conducted using the HYSYS simulator .This new process is especially suitable for off shore natural gas liquefaction plants. A numerical optimization technique has been used to determine the optimum conditions for Egyptian natural gas feed source. The investigation of the effect of different compositions of the Mixed refrigerants used was conducted. Meanwhile, the investigation of the influence of the temperature of cooling water used was conducted. The best optimum conditions for the DMRC process were determined .The optimum results achieved for the DMRC process revealed that the DMRC process can be successfully applied as a promising technique for off shore natural gas liquefaction plants

  9. Development, modelling and evaluation of a small-scale gas liquefaction plant

    Nguyen, Tuong-Van; Rothuizen, Erasmus Damgaard; Markussen, Wiebke Brix

    2017-01-01

    A small-scale gas liquefaction plant was developed and analysed based on process simulation tools and pilot tests. It will be installed in harbours, easing the penetration of liquefied natural gas (LNG) as a maritime fuel, in a sector facing more stringent environmental regulations. The proposed...... plant uses a multi-component refrigerant together with a propane precooling cycle and plate heat exchangers, to achieve a higher performance. This LNG production concept was modelled based on the Danish natural gas composition. Firstly, the total power consumption and heat transfer conductance were...... minimised by optimising the operating conditions and the refrigerant composition. The effects of varying feed and refrigerant compositions were analysed. Secondly, the system layouts were evaluated by conducting an exergetic assessment. Finally, the most promising layouts were validated by pilot plant...

  10. Achievement report for fiscal 1982 on Sunshine Program. Research and development of coal liquefaction technology (Conceptual designs for coal liquefaction pilot plants - Solvent extraction liquefaction process); 1982 nendo sekitan ekika gijutsu no kenkyu kaihatsu seika hokokusho. Sekitan ekika pilot plant no gainen sekkei (yozai chushutsu ekikaho)

    NONE

    1983-03-01

    This research aims to prepare conceptual designs for a 250t/d-class and 500t/d-class coal liquefaction pilot plants based on the achievement of research on solvent extraction liquefaction of coal. It also aims to define the solvent extraction process and provide decision-making material relative to the development and promotion of coal liquefaction technologies in the future. Development started in 1978 of the technology of solvent extraction liquefaction of coal, and a 1t/d PDU (process development unit) was completed in 1981. Studies through its operation have continued for more than 3000 hours already, and technical data are being accumulated steadily. Techniques acquired through operating the 1t/d PDU have been put together, and rough process conditions are established. A rough process result is achieved of the same conditions. In these two respects, the newly developed process is equal to other processes. The phenomena in this process are roughly grasped. It is deemed that, with the existing technique combined with the technique acquired here, a technological level has been reached where conceptual designs of large pilot plants may be worked out for solvent extraction liquefaction of coal. Under the circumstances, with a view to developing a commercial plant whose main products will be fuel oils, conceptual designs are prepared for large pilot plants, and are compiled into this report. (NEDO)

  11. Report on 1979 result of R and D under Sunshine Project. Development of coal liquefaction technology (development of solvent treatment and liquefaction plant); 1979 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Yozai shori ekika plant no kaihatsu

    NONE

    1980-03-01

    A report was made on the result for fiscal 1979 of the development of a coal solvent treatment and liquefaction plant. With the purpose of establishing a technology of making equipment for a coal liquefaction plant by a solvent treatment method, R and D were conducted on a solid liquid separation method and on the construction and operation of an experimental equipment having a scale of the maximum 1 t/day coal processing, providing technical data for the construction of an efficient coal liquefaction equipment. In studying the operation of a centrifugal separator, it was run using heating solvent, dummy slurry and coal extraction slurry, with no abnormality found in each equipment and with knowledge obtained of the separation state of the solid. The machine is capable of obtaining SRC of 0.2-0.3% low ash contents. Water operation was performed for the extraction processing device (agitation tank, heating furnace, compression pump, circulation pump, etc.) of the 1 t/day experimental plant and, as a result, a relation was confirmed between a water flow rate and pressure loss of the piping part. The detailed design, manufacture and installation were completed for a part (pulverizer, solvent tank, feeding pump, etc.) of the equipment for the coal pre-processing slurry making process and the extraction process, with a trial run implemented for adjustment and confirmation of the operation. The cold/hot continuous trial run by a solvent smoothly proceeded, proving the performance to be the same as the specifications. (NEDO)

  12. Helium heater design for the helium direct cycle component test facility. [for gas-cooled nuclear reactor power plant

    Larson, V. R.; Gunn, S. V.; Lee, J. C.

    1975-01-01

    The paper describes a helium heater to be used to conduct non-nuclear demonstration tests of the complete power conversion loop for a direct-cycle gas-cooled nuclear reactor power plant. Requirements for the heater include: heating the helium to a 1500 F temperature, operating at a 1000 psia helium pressure, providing a thermal response capability and helium volume similar to that of the nuclear reactor, and a total heater system helium pressure drop of not more than 15 psi. The unique compact heater system design proposed consists of 18 heater modules; air preheaters, compressors, and compressor drive systems; an integral control system; piping; and auxiliary equipment. The heater modules incorporate the dual-concentric-tube 'Variflux' heat exchanger design which provides a controlled heat flux along the entire length of the tube element. The heater design as proposed will meet all system requirements. The heater uses pressurized combustion (50 psia) to provide intensive heat transfer, and to minimize furnace volume and heat storage mass.

  13. Reassessment of liquefaction potential and estimation of earthquake- induced settlements at Paducah Gaseous Diffusion Plant, Paducah, Kentucky. Final report

    Sykora, D.W.; Yule, D.E.

    1996-04-01

    This report documents a reassessment of liquefaction potential and estimation of earthquake-induced settlements for the U.S. Department of Energy (DOE), Paducah Gaseous Diffusion Plant (PGDP), located southwest of Paducah, KY. The U.S. Army Engineer Waterways Experiment Station (WES) was authorized to conduct this study from FY91 to FY94 by the DOE, Oak Ridge Operations (ORO), Oak Ridge, TN, through Inter- Agency Agreement (IAG) No. DE-AI05-91OR21971. The study was conducted under the Gaseous Diffusion Plant Safety Analysis Report (GDP SAR) Program

  14. Simulation and statistical analysis for the optimization of nitrogen liquefaction plant with cryogenic Claude cycle using process modeling tool: ASPEN HYSYS

    Joshi, D.M.

    2017-01-01

    Cryogenic technology is used for liquefaction of many gases and it has several applications in food process engineering. Temperatures below 123 K are considered to be in the field of cryogenics. Extreme low temperatures are a basic need for many industrial processes and have several applications, such as superconductivity of magnets, space, medicine and gas industries. Several methods can be used to obtain the low temperatures required for liquefaction of gases. The process of cooling or refrigerating a gas to a temperature below its critical temperature so that liquid can be formed at some suitable pressure, which is below the critical pressure, is the basic liquefaction process. Different cryogenic cycle configurations are designed for getting the liquefied form of gases at different temperatures. Each of the cryogenic cycles like Linde cycle, Claude cycle, Kapitza cycle or modified Claude cycle has its own advantages and disadvantages. The placement of heat exchangers, Joule-Thompson valve and turboexpander decides the configuration of a cryogenic cycle. Each configuration has its own efficiency according to the application. Here, a nitrogen liquefaction plant is used for the analysis purpose. The process modeling tool ASPEN HYSYS can provide a software simulation approach before the actual implementation of the plant in the field. This paper presents the simulation and statistical analysis of the Claude cycle with the process modeling tool ASPEN HYSYS. It covers the technique used to optimize the liquefaction of the plant. The simulation results so obtained can be used as a reference for the design and optimization of the nitrogen liquefaction plant. Efficient liquefaction will give the best performance and productivity to the plant.

  15. Simulation and statistical analysis for the optimization of nitrogen liquefaction plant with cryogenic Claude cycle using process modeling tool: ASPEN HYSYS

    Joshi, D. M.

    2017-09-01

    Cryogenic technology is used for liquefaction of many gases and it has several applications in food process engineering. Temperatures below 123 K are considered to be in the field of cryogenics. Extreme low temperatures are a basic need for many industrial processes and have several applications, such as superconductivity of magnets, space, medicine and gas industries. Several methods can be used to obtain the low temperatures required for liquefaction of gases. The process of cooling or refrigerating a gas to a temperature below its critical temperature so that liquid can be formed at some suitable pressure, which is below the critical pressure, is the basic liquefaction process. Different cryogenic cycle configurations are designed for getting the liquefied form of gases at different temperatures. Each of the cryogenic cycles like Linde cycle, Claude cycle, Kapitza cycle or modified Claude cycle has its own advantages and disadvantages. The placement of heat exchangers, Joule-Thompson valve and turboexpander decides the configuration of a cryogenic cycle. Each configuration has its own efficiency according to the application. Here, a nitrogen liquefaction plant is used for the analysis purpose. The process modeling tool ASPEN HYSYS can provide a software simulation approach before the actual implementation of the plant in the field. This paper presents the simulation and statistical analysis of the Claude cycle with the process modeling tool ASPEN HYSYS. It covers the technique used to optimize the liquefaction of the plant. The simulation results so obtained can be used as a reference for the design and optimization of the nitrogen liquefaction plant. Efficient liquefaction will give the best performance and productivity to the plant.

  16. Report on 1979 result of Sunshine Project (detailed design). Part 1. Forty t/day solvolysis coal liquefaction pilot plant; 1979 nendo 40T/nichi solvolysis sekitan pilot plant shosai sekkei. 1

    NONE

    1980-03-01

    The subject design documents are the compilation of the result of the design operation for the 'detailed design of 40 t/day class solvolysis coal liquefaction pilot plant'. The design of this pilot plant was conducted using, as the fundamental reference, the basic data provided by Kyushu National Industrial Research Institute and Kyushu University and the results of a contract research on '1 t/day class solvolysis coal liquefaction plant'. The subject detailed design was intended for Phase 1 centering on a single stage liquefaction - coal liquefaction (transformation into pitch) by solvolysis liquefaction reaction. The areas covered consists of the pre-treatment process, material mixing process, reaction process, reaction freezing process, coke separation process, SR recovery process, pitch refining process, utility facilities, and waste water treatment facilities. Incidentally, the processes for which the design operation has been completed this year, particularly the reaction process, coke separation process, SR recovery process, etc., are in the field untrodden technologically in the world; therefore, their design method is supposed to be established from the results of the R and D on coal liquefaction, '1 t/day class solvolysis coal liquefaction plant.' (NEDO)

  17. Report on 1979 result of Sunshine Project (detailed design). Part 1. Forty t/day solvolysis coal liquefaction pilot plant; 1979 nendo 40T/nichi solvolysis sekitan pilot plant shosai sekkei. 1

    NONE

    1980-03-01

    The subject design documents are the compilation of the result of the design operation for the 'detailed design of 40 t/day class solvolysis coal liquefaction pilot plant'. The design of this pilot plant was conducted using, as the fundamental reference, the basic data provided by Kyushu National Industrial Research Institute and Kyushu University and the results of a contract research on '1 t/day class solvolysis coal liquefaction plant'. The subject detailed design was intended for Phase 1 centering on a single stage liquefaction - coal liquefaction (transformation into pitch) by solvolysis liquefaction reaction. The areas covered consists of the pre-treatment process, material mixing process, reaction process, reaction freezing process, coke separation process, SR recovery process, pitch refining process, utility facilities, and waste water treatment facilities. Incidentally, the processes for which the design operation has been completed this year, particularly the reaction process, coke separation process, SR recovery process, etc., are in the field untrodden technologically in the world; therefore, their design method is supposed to be established from the results of the R and D on coal liquefaction, '1 t/day class solvolysis coal liquefaction plant.' (NEDO)

  18. CERN Technical Training 2002: Learning for the LHC ! HeREF-2002 : Helium Refrigeration Techniques

    Davide Vitè

    2002-01-01

    Theory, Technology, Maintenance and Control of Helium Refrigerators HeREF-2002 is a new course, in the framework of the 2002 Technical Training Programme, that will provide a complete introduction to Helium refrigeration, with a practical approach to theory, technology, maintenance and control of Helium refrigeration installations. Theoretical aspects and equations will be limited to a minimum. HeREF-2002 targets an audience of technicians and operators of Helium refrigeration plants at CERN, as well as physicists and engineers needing an overview of current Helium refrigeration techniques. HeREF-2002 will address, among other, issues related to component technology, installation maintenance, process control and Helium purity. A commented visit to a couple of CERN Helium refrigeration or liquefaction plants will also take place. Duration: 7 half days (5 mornings and 2 afternoons), 21-25 October 2002. Estimated cost: 300.- CHF Language: Bilingual English-French. The course support will be in English, the...

  19. CERN Technical Training 2002: Learning for the LHC! HEREF-2002 : HELIUM REFRIGERATION TECHNIQUES

    Davide Vitè

    2002-01-01

    Theory, Technology, Maintenance and Control of Helium Refrigerators HeREF-2002 is a new course, in the framework of the 2002 Technical Training Programme, that will provide a complete introduction to Helium refrigeration, with a practical approach to theory, technology, maintenance and control of Helium refrigeration installations. Theoretical aspects and equations will be limited to a minimum. HeREF-2002 targets an audience of technicians and operators of Helium refrigeration plants at CERN, as well as physicists and engineers needing an overview of current Helium refrigeration techniques. HeREF-2002 will address, among other, issues related to component technology, installation maintenance, process control and Helium purity. A commented visit to a couple of CERN Helium refrigeration or liquefaction plants will also take place. Duration: 7 half days (5 mornings and 2 afternoons), 21-25 October, 2002. Estimated cost: 300.- CHF Language: Bilingual English-French. The course support will be in English, the ...

  20. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvent extraction and liquefaction plant (development of a 1-t/d experimental plant and research on the solvent extraction and liquefaction process); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, yozai chushutsu ekika plant no kaihatsu seika hokokusho. 1t/d jikken plant no kaihatsu (yozai chushutsu ekika process no kenkyu)

    NONE

    1982-03-01

    Among the items of the solvent extraction and liquefaction plant technologies in the Sunshine Project in fiscal 1981, this paper describes the achievements in developing a 1-t/d experimental plant and the solvent extraction and liquefaction process. Basic facilities were completed by giving expansion constructions on the extraction reaction column, gas-liquid separation column, and hydrogenation reaction column. The operation was performed with the primary object placed on verifying the effect of measures on problems that have been extracted, and checking the solvent balance. The conversion rate at an extraction reaction temperature of 450 degrees C was 83%, agreeing with the result of the fundamental study. The solvent has turned light as a result of 153-hour continuous operation, but circulating use was possible. Progress of the reaction has become easily controllable in the hydrogenation system. Fundamental discussions were given on engineering aspects, which require further accumulation of data. In the research of the solvent extraction and liquefaction process, fiscal 1981 has performed discussions on liquefaction catalysts, and on the effect of the hydrogen donating solvents. The discussions were for the fundamental research to establish adequate conditions for the 1-t/d experimental plant by operating a small continuous operation facility to its full extent, and by using a batch type reaction device. Screening was also carried out on catalysts. (NEDO)

  1. Hydrothermal Liquefaction and Upgrading of Municipal Wastewater Treatment Plant Sludge: A Preliminary Techno-Economic Analysis

    Snowden-Swan, Lesley J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Zhu, Yunhua [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Jones, Susanne B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Elliott, Douglas C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Schmidt, Andrew J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hallen, Richard T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Billing, Justin M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hart, Todd R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fox, Samuel P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Maupin, Gary D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-06-08

    A preliminary process model and techno-economic analysis (TEA) was completed for fuel produced from hydrothermal liquefaction (HTL) of sludge waste from a municipal wastewater treatment plant (WWTP) and subsequent biocrude upgrading. The model is adapted from previous work by Jones et al. (2014) for algae HTL, using experimental data generated in fiscal year 2015 (FY15) bench-scale HTL testing of sludge waste streams. Testing was performed on sludge samples received from MetroVancouver’s Annacis Island WWTP (Vancouver, B.C.) as part of a collaborative project with the Water Environment and Reuse Foundation (WERF). The full set of sludge HTL testing data from this effort will be documented in a separate report to be issued by WERF. This analysis is based on limited testing data and therefore should be considered preliminary. Future refinements are necessary to improve the robustness of the model, including a cross-check of modeled biocrude components with the experimental GCMS data and investigation of equipment costs most appropriate at the smaller scales used here. Environmental sustainability metrics analysis is also needed to understand the broader impact of this technology pathway. The base case scenario for the analysis consists of 10 HTL plants, each processing 100 dry U.S. ton/day (92.4 ton/day on a dry, ash-free basis) of sludge waste and producing 234 barrel per stream day (BPSD) biocrude, feeding into a centralized biocrude upgrading facility that produces 2,020 barrel per standard day of final fuel. This scale was chosen based upon initial wastewater treatment plant data collected by the resource assessment team from the EPA’s Clean Watersheds Needs Survey database (EPA 2015a) and a rough estimate of what the potential sludge availability might be within a 100-mile radius. In addition, we received valuable feedback from the wastewater treatment industry as part of the WERF collaboration that helped form the basis for the selected HTL and upgrading

  2. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvolysis liquefaction plant (development of a 1 t/d experimental plant and research on solvolysis liquefaction process); Sekitan ekika gijutsu no kenkyu kaihatsu, solvolysis ekika plant no kaihatsu seika hokokusho. 1t/nichi jikken plant no kaihatsu (solvolysis ekika process no kenkyu)

    NONE

    1982-03-01

    This paper describes the achievements in the Sunshine Project in fiscal 1981 in development of a solvolysis liquefaction plant. The solvolysis process is characterized by performing the first stage reaction (liquefaction) in a short time by using hydrogenated heavy solvent produced spontaneously in the process. This short-time liquefaction reaction was carried out continuously by using a 1-t/d experimental plant, and a prospect was obtained on smooth operation and realization of the device. A test using a testing device allowing the temperature to rise within several minutes was performed on the effectiveness of a hydrogenated coal based heavy solvent (fractions of a hydrogenated heavy anthracene as a model) as a study on the first stage reaction. Partially hydrogenated materials of polycyclic condensed aromatics in the heavy solvent is largely involved in the initial reaction. In the solid-liquid separation, solids and heavy fractions are selected and removed from the first stage reaction products, and the light fraction is supplied into the second stage reaction (hydrogenation). The solvent deliming process was tested by using a batch type solid-liquid separator, whose effectiveness was verified. Studies were performed by using Australian sub-bituminous coal on operation of a continuous operation device consisted of systems for the first stage reaction (liquefaction), solid-liquid separation, second stage reaction (hydrogenation), and solvent circulation. (NEDO)

  3. FY 1980 Report on results of Sunshine Project. Development of coal liquefaction techniques (Development of 1 T/D test plant, and researches on the solvent-extraction type liquefaction process); 1980 nendo sekitan ekika gijutsu no kaihatsu, yozai chushutsu ekika plant no kaihatsu seika hokokusho. 1t/nichi jikken plant no kaihatsu, yozai chushutsu ekika process no kenkyu

    NONE

    1981-03-01

    This program is aimed at establishing the techniques for solvent-extraction type coal liquefaction plant by constructing and operating a 1 T/D test plant to obtain the technical data for the efficient plant. The test plant is operated to confirm the effects of temperature and coal slurry concentration on liquefaction conversion by the solvent-extraction for a short time in the furnace for the extraction unit. The extraction type coal liquefaction tests can be conducted for a reaction time of around 1 hour by the test plant. The recycled solvent purification unit is installed, to regenerate the hydrogen donor solvent. For researches on the solvent-extraction type coal liquefaction process, the continuous extraction is conducted, to investigate the effects of extraction reaction rate at relatively low pressure. The optimum hydrogenation conditions are studied for the test plant. It is confirmed that a Mo-based catalyst is suitable for the hydrogenation. The batch type reaction system is operated to investigate the liquid yield of Wandoan coal, and recycled solvent balances and compositions. (NEDO)

  4. Coal liquefaction becomes viable

    NONE

    2005-11-15

    In 2003 the May/June issue of CoalTrans International speculated that coal liquefaction would become viable due to falling coal prices. This has not proved the case but the sustained high oil price is sparking new interest. A survey by Energy Intelligence and Marketing Research during November 2005 revealed a growth in the number of projects under development or at the feasibility stage. The article reports projects in China, the USA, Australia, New Zealand, the Philippines and India. China is commissioning the first wave of large liquefaction plants. The key question is whether other countries, particularly the USA, will follow.

  5. Report on results for fiscal 1997 (B edition) on development of coal liquefaction technology. Development of bituminous coal liquefaction technology (research by pilot plant) 1/2; 1997 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Rekiseitan ekika gijutsu no kaihatsu (pilot plant ni yoru kenkyu) 2/2

    NONE

    1998-06-01

    This paper reports the operation of a pilot plant of a bituminous coal liquefaction technology as the 1/2 report. The operation research of the Run-2 through the Run-4-2 was conducted using, as the material, tanitoharum coal which is operating basis coal. The Run-2 achieved a coal charging continuous operation for 42 days. During the operation of 80% slurry supply load, various data were obtained including material balance under the NEDOL standard liquefaction conditions, with a liquefaction yield of 54% daf coal achieved. Steam blowing into the heating tube was found effective as measures to cope with coking generation in the heating furnace of a vacuum distillation tower. The softening point of liquefaction residuals was improved to 178 degrees C through the extracting adjustment of reduced pressure heavy gravity light oil fraction for washing. The Run-3/4-1 achieved a plant load ratio of 100% and a long-term coal charging continuous operation for 80 days, while the Run-3 achieved a slurry supply load of 100% under the NEDOL standard liquefaction conditions. The Run-4-1 achieved a high liquefaction yield of 58wt% daf coal. Performance was confirmed of a neutron beam source irradiation apparatus/measuring system and a tracer injection equipment. (NEDO)

  6. Maintenance free gas bearing helium blower for nuclear plant

    Molyneaux, A., Dr; Harris, M., Prof; Sharkh, S., Prof; Hill, S.; de Graaff, T.

    2017-08-01

    This paper describes the design, testing and operation of novel helium blowers used to recirculate the helium blanketing gas in the nuclear reactor used as a neutron source at the Institut Laue Langevan, Grenoble, France. The laser sintered shrouded centrifugal wheel operates at speeds up to 45000 rpm supported on helium lubricated hydrodynamic spiral groove bearings, and is driven by a sensorless permanent magnet motor. The entire machine is designed to keep the helium gas (polluted by a small amount of D2O) out of contact with any iron or copper materials which would contribute to the corrosion of parts of the circuit. It is designed to have zero maintenance during a lifetime of 40,000 hours of continuous operation. This paper will describe the spiral groove journal and thrust bearings. Design and manufacture of the 1 kW motor and centrifugal wheel will be explained including their CFD and FEA analyses. Measurements of rotor displacement will be presented showing the behaviour under factory testing as well as details of the measured centrifugal wheel and motor performances. Two machines are incorporated into the circuit to provide redundancy and the first blower has been in continuous operation since Jan 2015. The blower was designed, manufactured, assembled and tested in the UK using predominantly UK suppliers.

  7. Helium production technology based on natural gas combustion and beneficial use of thermal energy

    Nakoryakov Vladimir E.

    2016-01-01

    Full Text Available Helium is widely used in all industries, including power plant engineering. In recent years, helium is used in plants operating by the Brayton cycle, for example, in the nuclear industry. Using helium-xenon mixture in nuclear reactors has a number of advantages, and this area is rapidly developing. The hydrodynamics and mass transfer processes in single tubes with various cross-sections as well as in inter-channel space of heating tube bundle were studied at the Institute of Thermophysics, Siberian Branch of the Russian Academy of Sciences. Currently, there is a strongest shortage in helium production. The main helium production method consists in the liquefaction of the natural gas and subsequent separation of helium from remaining gas with its further purification using membranes.

  8. Some research and development on power plants with helium gas turbine units

    Kaplan, M.P.

    1983-01-01

    Research and development projects pursued at the S. M. Kirov Kharkov Turbine Factory Production Association for Nuclear Turbomachinery Manufacturing have probed into prospective use of helium as the working medium in nuclear power facilities. The projects under study are compared mainly in terms of heat efficiency. Solutions are also being sought for problems centering around high efficiency in helium turbocompressors combined with shortening of axial dimensions. Different types of power plants are being compared with attention given to features of the flow passages of turbocompressors. The projects were developed for helium temperatures and pressures downstream of the reactor 950 0 C and 4.8 MPa, and thermal reactor output 2250 MW(th). The reactor is assumed to be served by two turbine plants in the turbocompressor designs

  9. Development of brown coal liquefaction. Design, construction and operation of a 50 t/d pilot plant

    1985-08-01

    As for the development of 50t/d pilot plant for the development of liquefaction plant of Victorian brown coal in Australia, outline of the results of the researches in 1984 is reported from the following 4 viewpoints; 1: design of process apparatuses, 2: manufacture of apparatuses, 3: field work of the construction, 4: preparation for operation of the plant. On the first item, the outline of ordering designed equipment from Japanese and Australian companies is described. On the second item the acceptance of purchasing goods from Japan and Australia and promotion of the inspection and quality assurance system. On the third item, contents of the continuous construction of the first stage are described. On the fourth item, the establishment and review of rules and regulations, training and education for operators, enviromental assessment, contents of safety and maintenance work and commissioning work by the promoting department for preparation of operation are described. Moreover support works of wide range for the promotion and adoption by necessary personnel, labour unions, the state of labour and activities for local discricts are described.

  10. A novel conceptual design of parallel nitrogen expansion liquefaction process for small-scale LNG (liquefied natural gas) plant in skid-mount packages

    He, Tianbiao; Ju, Yonglin

    2014-01-01

    The utilization of unconventional natural gas is still a great challenge for China due to its distribution locations and small reserves. Thus, liquefying the unconventional natural gas by using small-scale LNG plant in skid-mount packages is a good choice with great economic benefits. A novel conceptual design of parallel nitrogen expansion liquefaction process for small-scale plant in skid-mount packages has been proposed. It first designs a process configuration. Then, thermodynamic analysis of the process is conducted. Next, an optimization model with genetic algorithm method is developed to optimize the process. Finally, the flexibilities of the process are tested by two different feed gases. In conclusion, the proposed parallel nitrogen expansion liquefaction process can be used in small-scale LNG plant in skid-mount packages with high exergy efficiency and great economic benefits. - Highlights: • A novel design of parallel nitrogen expansion liquefaction process is proposed. • Genetic algorithm is applied to optimize the novel process. • The unit energy consumption of optimized process is 0.5163 kWh/Nm 3 . • The exergy efficiency of the optimized case is 0.3683. • The novel process has a good flexibility for different feed gas conditions

  11. Magnetic refrigerator for hydrogen liquefaction

    Numazawa, T [National Institute for Materials Science, Tsukuba (Japan); Kamlya, K. [Japan Atomic Energy Agency, Naka (Japan); Utaki, T. [Osaka University, Osaka (Japan); Matsumoto, K. [Kanazawa University, Kanazawa (Japan)

    2013-06-15

    This paper reviews the development status of magnetic refrigeration system for hydrogen liquefaction. There is no doubt that hydrogen is one of most important energy sources in the near future. In particular, liquid hydrogen can be utilized for infrastructure construction consisting of storage and transportation. Liquid hydrogen is in cryogenic temperatures and therefore high efficient liquefaction method must be studied. Magnetic refrigeration which uses the magneto-caloric effect has potential to realize not only the higher liquefaction efficiency > 50 %, but also to be environmentally friendly and cost effective. Our hydrogen magnetic refrigeration system consists of Carnot cycle for liquefaction stage and AMR (active magnetic regenerator) cycle for precooling stages. For the Carnot cycle, we develop the high efficient system > 80 % liquefaction efficiency by using the heat pipe. For the AMR cycle, we studied two kinds of displacer systems, which transferred the working fluid. We confirmed the AMR effect with the cooling temperature span of 12 K for 1.8 T of the magnetic field and 6 second of the cycle. By using the simulation, we estimate the total efficiency of the hydrogen liquefaction plant for 10 kg/day. A FOM of 0.47 is obtained in the magnetic refrigeration system operation temperature between 20 K and 77 K including LN2 work input.

  12. FY 1981 Report on the results of Sunshine Project. Research and development of techniques for liquefaction of coal (Development of extraction type liquefaction plant using brown coal-based solvent and researches on milling at high temperature in oil); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, kattankei yozai chushutsu ekika plant no kaihatsu seika hokokusho. Koon yuchu funsai no kenkyu

    NONE

    1982-03-01

    This program is aimed at establishment of the techniques for milling of brown coal treated by primary dehydration and slurry adjustment, and secondary hydration plant, as part of the project for developing the techniques for liquefaction of brown coal. Brown coal (Australian Yallourn coal) treated by primary dehydration, solvents (creosote and decrystallized anthracene), and catalysts are used as the stock samples, to investigate the coal characteristics with respect to milling crushability, dehydration and liquefaction reactivity, and the slurries are prepared by changing coal charge rate, solvent and preparation temperature, to collect the data regarding, e.g., coal concentration, coal particle size, moisture level and liquefaction reactivity. It is found that milling crushability tends to decrease as coal charge rate or solvent/coal ratio increases whether creosote or decrystallized anthracene is used as the solvent. Milling crushability is unaffected by slurry preparation temperature. Content of residual moisture in the slurry decreases to 1% or less, when slurry preparation temperature is increased to 100 degrees C or higher. Liquefaction reactivity of the slurry shows slight dependence on slurry preparation temperature, when it is increased to 180 degrees C. (NEDO)

  13. PIP-II Cryogenic System and the evolution of Superfluid Helium Cryogenic Plant Specifications

    Chakravarty, Anindya [Fermilab; Rane, Tejas [Fermilab; Klebaner, Arkadiy [Fermilab

    2017-07-06

    The PIP-II cryogenic system consists of a Superfluid Helium Cryogenic Plant (SHCP) and a Cryogenic Distribution System (CDS) connecting the SHCP to the Superconducting (SC) Linac consisting of 25 cryomodules. The dynamic heat load of the SC cavities for continuous wave (CW) as well as pulsed mode of operation has been listed out. The static heat loads of the cavities along with the CDS have also been discussed. Simulation study has been carried out to compute the supercritical helium (SHe) flow requirements for each cryomodule. Comparison between the flow requirements of the cryomodules for the CW and pulsed modes of operation have also been made. From the total computed heat load and pressure drop values in the CDS, the basic specifications for the SHCP, required for cooling the SC Linac, have evolved.

  14. Final report on research project: Soil liquefaction testing and evaluation for Kozloduy nuclear power plant units 5 and 6

    Simeonov, S [Energoproekt plc., Power Consulting Engineers, Hydropower Division, Sofia (Bulgaria)

    1995-07-01

    The object of this study is the region of the channels of additional technical water supply of Kozloduy NPP, Units 5 and 6. This region is chosen because there are enough data for water saturated sands, necessary for the analysis, including data from cyclic triaxial tests and standard penetration tests. Three kinds ofprocedures for estimation of liquefaction potential of water saturated sands are used in the study. The results obtained by different procedures were compared, analyzed and conclusions drawn about the liquefaction potential of water saturated sands in the area of the channels of additional technical water supply.

  15. Development of technology for brown coal liquefaction. Design, construction and operation of pilot plant; development of 50t/d pilot plant

    1986-08-01

    As for the development of 50t/d pilot plant for the development of liquefaction plant of Victorian brown coal in Austraria, outline of the contents about the second stage construction following the first stage construction up to this time is reported from the following 4 viewpoints; 1: design of process apparatuses, 2: manufacture of apparatuses, 3: fieldwork of the construction and 4: operation of the first stage facilities. On the first item the outline of detail design made by Japanese and Australian companies is described. On the second item the acceptance of purchasing goods from Japan and Australia and the condition of inspection and quality assurance to specific principal parts are described. On the third item the supplementary construction of the first stage, contents of constructions of the second stage are described. On the fourth item, preparation for operation, target, the whole circumstances and the results of maintenance, especially review of operation technique, training of operators, and occurrence and repair of troubles are described. As other relevant works, envirommental assessment, waste disposal, enviromental monitoring for exhaust gases, drainage and working enviroments, safety measure, educational training and moreover activities for local district people and the state of labor market as the support for execution of the project are described.

  16. FY 1980 Report on results of Sunshine Project. Research and development of coal liquefaction techniques (Development of direct hydrogenation type liquefaction plant and 2.4 T/D test plant); 1980 nendo sekitan ekika gijutsu no kenkyu kaihatsu, chokusetsu suiten ekika plant no kaihatsu seika hokokusho. 2.4T/nichi jikken plant no kaihatsu

    NONE

    1981-03-01

    This program is aimed at construction and operation of a 2.4 T/D test plant for eventual commercialization of the direct hydrogenation type liquefaction process. The FY 1980 program includes designs of the test plant, procurement and manufacture of some equipment, and works for construction of the bases, buildings and scaffolds. The construction site for the 2.4 T/D plant was changed in July 1980 from Mitsui Engineering and Shipbuilding's Chiba works to NKK's Keihin Steelworks, which was accompanied by some changes in the basic and detailed designs. The detailed designs were reviewed for construction of the test plant, to reflect the results of the individual elementary researches. The works for the FY 1980 program also include preparations for obtaining approvals of plant construction, based on the revised designs, from the related government offices, and equipment procurement. This paper presents the major drawings for the plant construction, including those for PID designs, overall plant layouts, piping systems, buildings, scaffolds, and pipe racks. The loading data are also included. (NEDO)

  17. Options for helium circulation in a hydrogen production plant VHTR-Si: thermal-economic comparative

    Mendoza A, A.; Francois L, J. L.; Anaya D, A.

    2011-11-01

    The technologies that take advantage of the heat of nuclear reactors of IV generation are of great interest, due to their high energy efficiencies and to their strong economic potential. An example of these technologies is the sulfur-iodine process coupled to a nuclear reactor of high temperature cooled by helium. In this process heat is transferred from the nuclear reactor to the chemical plant by means of two cycles of helium interconnected by an intermediate heat exchanger. The first, denominated primary cycle of cooling, removes the heat of the nuclear reactor, transferring to the secondary cycle to be distributed to equipment s in the chemical plant. The pass of the helium gas through the equipment s that compose each one of the cycles, implies pressure losses that should be compensated necessarily by re-compression to maintain a stable state in the system, causing the energy consumption, usually rejected in the energy analyses. When to this energy is added the energy required in the hydrogen plant: energy required by the pumping systems, will decrease the efficiency of the nucleus-chemical complex, increasing the even cost of the hydrogen. In this work, three options to supply the compression energy and pumping (CEP) to the system are proposed, and these are analyzed thermodynamic and economically. The results indicate that to consider the CEP in the economic analysis increases between 1.5 and 3% the even cost of the hydrogen, and that the option with more energy efficiency is not necessarily the best for the nucleus-chemical complex. (Author)

  18. Report on results of R and D of coal liquefaction technology under Sunshine Project in fiscal 1981. Development of direct hydro-liquefaction plant (research on liquefaction by bench scale equipment, and research on solid-liquid separation method); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, chokusetsu suiten ekika plant no kaihatsu seika hokokusho. Bench scale sochi ni yoru ekika kenkyu, koeki bunriho ni kansuru kenkyu

    NONE

    1982-03-01

    This paper explains the results of development of direct hydro-liquefaction plant under the Sunshine Project in fiscal 1981. As element studies for supplementing and supporting a 2.4 t/day PDU (process development unit), in the research using a 0.1 t/day bench scale continuous type equipment of fiscal 1981, a hydrogenation experiment was conducted for anthracene oil and also, an examination was made on the reaction conditions of Taiheiyo coal and Horonai coal, as well as on the catalyst and reaction ratio and on the product material distribution. A medium oil equalizing test was performed using Taiheiyo coal in order to obtain knowledge about equalized medium oil. Liquefaction characteristics in the preheating process and reaction process were elucidated by means of a semi-batch device. Comparative studies were made between domestic and overseas coals, in coal properties and liquefaction characteristics using a shaking type autoclave. The performance of iron-sulfur based catalysts was also examined. In the research on a solid-liquid separation method, the basic properties of coal liquefied crude oil were measured such as general properties, solid grading distribution and distillation characteristics, with the basic tests carried out for standing separation, filtrating separation and centrifuging separation, providing selected materials of the solid-liquid separation method suitable for the crude oil produced by the direct hydro-liquefaction method. In addition, studies were conducted on the use of residual oil generated by solid-liquid separation, providing knowledge of the viscosity and thermal cracking. (NEDO)

  19. Report on results for fiscal 1997 (B edition) on development of coal liquefaction technology. Development of bituminous coal liquefaction technology (research by pilot plant) 1/2; 1997 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B gan). Rekiseitan ekika gijutsu no kaihatsu (pilot plant ni yoru kenkyu) 1/2

    NONE

    1998-06-01

    Through the design, construction and operation of a pilot plant, the NEDOL method was verified, with its operation technology established, and also with a target set in collecting and accumulating data and knowledge required for a commercial plant in the future. With the Run-2, 3, 4 implemented using operating basis coal as the material, the operating stability of equipment/machines was confirmed, and a method of obtaining material balance as well as the operation technology was established, thereby demonstrating the NEDOL process, proving a long-term continuous operability and verifying the highest liquefaction yield. In addition, various process data, engineering data, operation control data, etc., were acquired, classified and analyzed. In the Run-3/4-1, a long-term coal charging continuous operation for 80 days was achieved, as was a high liquefaction yield of 58%. Moreover, data of material balance and thermal balance were obtained, with the performance confirmed of various kinds of equipment. Using the operating basis coat as the material, the coal charging operation of the Run-4-2 was commenced, with the performance verification test carried out for a neutron attenuation tracer method (NAT method), for the purpose of obtaining data of the flow characteristics of the liquefaction reaction tower. (NEDO)

  20. Hydrothermal Liquefaction and Upgrading of Municipal Wastewater Treatment Plant Sludge: A Preliminary Techno-Economic Analysis, Rev.1

    Snowden-Swan, Lesley J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Zhu, Yunhua [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Jones, Susanne B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Elliott, Douglas C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Schmidt, Andrew J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hallen, Richard T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Billing, Justin M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hart, Todd R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fox, Samuel P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Maupin, Gary D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-09-01

    A preliminary process model and techno-economic analysis (TEA) was completed for fuel produced from hydrothermal liquefaction (HTL) of sludge waste from a municipal wastewater treatment plant (WWTP) and subsequent biocrude upgrading. The model is adapted from previous work by Jones et al. (2014) for algae HTL, using experimental data generated in fiscal year 2015 (FY15) bench-scale HTL testing of sludge waste streams. Testing was performed on sludge samples received from Metro Vancouver’s Annacis Island WWTP (Vancouver, B.C.) as part of a collaborative project with the Water Environment and Reuse Foundation (WERF). The full set of sludge HTL testing data from this effort will be documented in a separate report to be issued by WERF. This analysis is based on limited testing data and therefore should be considered preliminary. In addition, the testing was conducted with the goal of successful operation, and therefore does not represent an optimized process. Future refinements are necessary to improve the robustness of the model, including a cross-check of modeled biocrude components with the experimental GCMS data and investigation of equipment costs most appropriate at the relatively small scales used here. Environmental sustainability metrics analysis is also needed to understand the broader impact of this technology pathway. The base case scenario for the analysis consists of 10 HTL plants, each processing 100 dry U.S. ton/day (92.4 ton/day on a dry, ash-free basis) of sludge waste and producing 234 barrel per stream day (BPSD) biocrude, feeding into a centralized biocrude upgrading facility that produces 2,020 barrel per standard day of final fuel. This scale was chosen based upon initial wastewater treatment plant data collected by PNNL’s resource assessment team from the EPA’s Clean Watersheds Needs Survey database (EPA 2015a) and a rough estimate of what the potential sludge availability might be within a 100-mile radius. In addition, we received

  1. Recent run-time experience and investigation of impurities in turbines circuit of Helium plant of SST-1

    Panchal, P.; Panchal, R.; Patel, R.

    2013-01-01

    One of the key sub-systems of Steady State superconducting Tokamak (SST-1) is cryogenic 1.3 kW at 4.5 K Helium refrigerator/liquefier system. The helium plant consists of 3 nos. of screw compressors, oil removal system, purifier and cold-box with 3 turbo expanders (turbines) and helium cold circulator. During the recent SST-1 plasma campaigns, we observed high pressure drop of the order of 3 bar between the wheel outlet of turbine A and the wheel inlet of turbine - B. This was significant higher values of pressures drop across turbines, which reduced the speed of turbine A and B and in turn reduced the overall plant capacity. The helium circuits in the plant have 10-micron filter at the mouth of turbine - B. Initially, major suspects of such high blockage are assumed to be air-impurity, dust particles or collapse of filter. Several breaks in plant operation have been taken to warm up the turbines circuits up to 90 K to remove condensation of air-impurities at filter. Still this exercise did not solve blockage of filter in turbine circuits. A detailed investigation exercise with air/water regeneration and rinsing of cold box as well as purification of helium gas in buffer tanks are carried out to remove air impurities from cold-box. A trial run of cold box was executed in liquefier mode with turbines up to cryogenic temperatures and solved blockage in turbine circuits. The paper describes run-time experience of helium plant with helium impurity in turbine circuits, methods to remove impurity, demonstration of turbine performance and lessons learnt during this operation. (author)

  2. Summary of the achievements in fiscal 1991 in developing the coal liquefaction technology and the bituminous coal liquefaction technology. Studies by using a pilot plant; 1991 nendo sekitan ekika gijutsu kaihatsu rekiseitan ekika gijutsu no kaihatsu seika gaiyo. Pilot plant ni yoru kenkyu

    NONE

    1992-08-01

    This paper describes the achievements in 1991 on studies on the bituminous coal liquefaction technology using a pilot plant. Based on the detailed design of the 150-t/d pilot plant, study problems and analysis items were reviewed, and a material balance acquiring method and a reaction column data analyzing method were discussed. Utilization of the liquefaction simulator was attempted. Efficient execution of the pilot plant operation study requires to have the basic and support study achievements reflected on the pilot plant operation, and clarify the roles to be played by the groups. Therefore, discussion items were compiled. The overall process plan for the design and construction was reviewed based on the plan discussed in fiscal 1990. Fiscal 1991 has launched common civil engineering constructions. The operation plans for the main four facilities in the pilot plant, which have been prepared in fiscal 1988, were continued of reviewing to cope with the situation of the decreased construction budget. The budget was reviewed again in fiscal 1991, which would present a prospect of starting the operation in fiscal 1995. Annual reviews on the basic operation plans for the main four facilities and the conceptions taken to date were put into order. The project management system was also expanded and re-arranged, including the information registration and retrieval system. (NEDO)

  3. Helium circulator design concepts for the modular high temperature gas-cooled reactor (MHTGR) plant

    McDonald, C.F.; Nichols, M.K.; Kaufman, J.S.

    1988-01-01

    Two helium circulators are featured in the Modular High-Temperature Gas-Cooled Reactor (MHTGR) power plant - (1) the main circulator, which facilitates the transfer of reactor thermal energy to the steam generator, and (2) a small shutdown cooling circulator that enables rapid cooling of the reactor system to be realized. The 3170 kW(e) main circulator has an axial flow compressor, the impeller being very similar to the unit in the Fort St. Vrain (FSV) plant. The 164 kW(e) shutdown cooling circulator, the design of which is controlled by depressurized conditions, has a radial flow compressor. Both machines are vertically oriented, have submerged electric motor drives, and embody rotors that are supported on active magnetic bearings. As outlined in this paper, both machines have been conservatively designed based on established practice. The circulators have features and characteristics that have evolved from actual plant operating experience. With a major goal of high reliability, emphasis has been placed on design simplicity, and both machines are readily accessible for inspection, repair, and replacement, if necessary. In this paper, conceptual design aspects of both machines are discussed, together with the significant technology bases. As appropriate for a plant that will see service well into the 21st century, new and emerging technologies have been factored into the design. Examples of this are the inclusion of active magnetic bearings, and an automated circulator condition monitoring system. (author). 18 refs, 20 figs, 13 tabs

  4. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Data 4. Development of coal liquefaction technology/Development of solvent extraction liquefaction technology/Development of brown coal solvent extraction plant (Development of 50t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (Shiryo 4). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Research is conducted for the development of a liquefaction plant (50t/d pilot plant) for Australia's Victorian brown coal. In fiscal 1981, using the process concept and design data obtained through the study of elements, a detailed design of a primary hydrogenation system is drawn, part of the equipment is procured, and on-site construction work is started. The book is a collection of materials which include instrumentation-related drawings covering an instrumentation loop sketch, instrument inspection specifications (flow meter, level gage, pressure gage, thermometer, regulation meter, analyzing meter, signal receiving meter, and instrument board), general specifications for electrical instrumentation facilities, etc. (NEDO)

  5. Report on the achievements in the projects subsidized by the Sunshine Project in fiscal 1981. Data 2. Development of a coal liquefaction technology - development of a solvent extraction and liquefaction technology - 'development of a brown coal based solvent extraction plant' (Development of a 50-t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (shiryo 2). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Developmental researches were carried out on a liquefaction plant for the Victoria brown coal produced in Australia (a 50-t/d pilot plant). In fiscal 1981, detailed design was performed on the primary hydrogenation system by using the process conception and the design data obtained in the element studies. Part of the devices was procured, and the site construction was begun. The present data is a collection of drawings in relation with the machine design, such as the piping specifications, standard piping drawings, piping design procedures, piping drawings, pipe lists, and device inspection specifications. In relation with the instrumentation design, the instrumentation engineering specifications and meter lists. (NEDO)

  6. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Data 4. Development of coal liquefaction technology/Development of solvent extraction liquefaction technology/Development of brown coal solvent extraction plant (Development of 50t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (Shiryo 4). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Research is conducted for the development of a liquefaction plant (50t/d pilot plant) for Australia's Victorian brown coal. In fiscal 1981, using the process concept and design data obtained through the study of elements, a detailed design of a primary hydrogenation system is drawn, part of the equipment is procured, and on-site construction work is started. The book is a collection of materials which include instrumentation-related drawings covering an instrumentation loop sketch, instrument inspection specifications (flow meter, level gage, pressure gage, thermometer, regulation meter, analyzing meter, signal receiving meter, and instrument board), general specifications for electrical instrumentation facilities, etc. (NEDO)

  7. Process optimization of helium cryo plant operation for SST-1 superconducting magnet system

    Panchal, P.; Panchal, R.; Patel, R.; Mahesuriya, G.; Sonara, D.; Srikanth G, L. N.; Garg, A.; Christian, D.; Bairagi, N.; Sharma, R.; Patel, K.; Shah, P.; Nimavat, H.; Purwar, G.; Patel, J.; Tanna, V.; Pradhan, S.

    2017-02-01

    Several plasma discharge campaigns have been carried out in steady state superconducting tokamak (SST-1). SST-1 has toroidal field (TF) and poloidal field (PF) superconducting magnet system (SCMS). The TF coils system is cooled to 4.5 - 4.8 K at 1.5 - 1.7 bar(a) under two phase flow condition using 1.3 kW helium cryo plant. Experience revealed that the PF coils demand higher pressure heads even at lower temperatures in comparison to TF coils because of its longer hydraulic path lengths. Thermal run away are observed within PF coils because of single common control valve for all PF coils in distribution system having non-uniform lengths. Thus it is routine practice to stop the cooling of PF path and continue only TF cooling at SCMS inlet temperature of ˜ 14 K. In order to achieve uniform cool down, different control logic is adopted to make cryo stable system. In adopted control logic, the SCMS are cooled down to 80 K at constant inlet pressure of 9 bar(a). After authorization of turbine A/B, the SCMS inlet pressure is gradually controlled by refrigeration J-T valve to achieve stable operation window for cryo system. This paper presents process optimization for cryo plant operation for SST-1 SCMS.

  8. Liquefaction technology assessment. Final report

    1979-05-01

    A survey of coal liquefaction technology and analysis of projected relative performance of high potential candidates has been completed and the results are reported here. The key objectives of the study included preparation of a broad survey of the status of liquefaction processes under development, selection of a limited number of high potential process candidates for further study, and an analysis of the relative commercial potential of these candidates. Procedures which contributed to the achievement of the above key goals included definition of the characteristics and development status of known major liquefaction process candidates, development of standardized procedures for assessing technical, environmental, economic and product characteristics for the separate candidates, and development of procedures for selecting and comparing high potential processes. The comparisons were made for three production areas and four marketing areas of the US. In view of the broad scope of the objectives the survey was a limited effort. It used the experience gained during preparation of seven comprehensive conceptual designs/economic evaluations plus comprehensive reviews of the designs, construction and operation of several pilot plants. Results and conclusions must be viewed in the perspective of the information available, how this information was treated, and the full context of the economic comparison results. Comparative economics are presented as ratios; they are not intended to be predictors of absolute values. Because the true cost of constructing and operating large coal conversion facilities will be known only after commercialization, relative values are considered more appropriate. (LTN)

  9. FY 1980 Report on results of Sunshine Project. Research and development of coal liquefaction techniques (Development of direct hydrogenation type liquefaction plant and researches on liquefaction reactions in the presence of iron-based catalyst); 1980 nendo sekitan ekika gijutsu no kenkyu kaihatsu, chokusetsu suiten ekika plant no kaihatsu seika hokokusho. Tetsukei shokubai ni yoru ekika hanno no kenkyu

    NONE

    1981-03-01

    This program is aimed at development of iron-based catalyst suited for direct hydrogenation type coal liquefaction by elucidating the effects of the catalyst on the liquefaction reactions. The iron-based catalyst seems to act as the radical stabilizer rather than the reaction promoter, because the increased quantity of the catalyst and increased H{sub 2} pressure share the common pattern rather than the catalyst enhances the activity, which is associated with increased reaction temperature or residence time. This is more notably observed when the coal species is changed to brown coal. In other words, recombination of the decomposition products by polycondensation is accelerated in the presence of the catalyst in decomposition of brown coal from bituminous coal, with the result that the catalyst effects are more notably observed. Whether this results from difference in age between brown coal and bituminous coal or content of specific types of ashes should be elucidated, because this point is considered to deeply relate to eventual development of the liquefaction reaction system. The FY 1980 program includes the primary screening of different types of iron compounds and tests of some iron-metal-based catalysts. (NEDO)

  10. Achievement report on developing coal liquefaction technologies in fiscal 1999 - edition B. Development of bituminous coal liquefaction technology (studies by using pilot plant); 1999 nendo sekitan ekika gijutsu kaihatsu seika hokokusho B. Rekiseitan ekika gijutsu no kaihatsu (pilot plant ni yoru kenkyu)

    NONE

    2000-03-01

    With an objective to improve the environment by substituting petroleum energy by coal, and by reducing emission of SOx and NOx, research and development has been performed on coal liquefaction technologies. This paper summarizes the achievements thereof in fiscal 1999. In the disassembling study, wear, corrosion, and wall thickness change were investigated, and non-destructive inspection was performed on the major four facilities, and such newly developed devices as the liquefying catalyst manufacturing facilities, the slurry heat exchanger, and the let-down valves. The sampled test pieces were investigated of changes in the mechanical properties by means of the metallic structure inspection, hardness test, tensile test, and impact test. Deposits in the devices were investigated of their depositing conditions and constituents. The result reveals that the 3 Cr-1Mo-1/4V-Ti-B steel developed for the high-temperature, high-pressure, and hydrogen environment of the coal liquefaction plant showed excellent low-temperature tenacity and maintained good characteristics. No problems were discovered in corrosion resistance if PP using materials are used. The slurry handling centrifugal pump and instrumentation vales were worn out severely requiring replacements during the operation, for which further discussions are desired to be given. (NEDO)

  11. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvent extraction and liquefaction plant (research and development of solid-liquid separation process); Sekitan ekika gijutsu no kenkyu kaihatsu, yozai chushutsu ekika plant no kaihatsu, koeki bunriho no kenkyu kaihatsu seika hokokusho

    NONE

    1982-03-01

    Among researches on solvent extraction and liquefaction technologies in the Sunshine Project in fiscal 1981, this paper describes the achievements in development of a solid-liquid separation technology. In the research of operation of a centrifugal separation device, a solid-liquid separation test was performed on slurry extracted from the Australian Wandoan coal being sub-bituminous coal. The deliming rate has reached 99% equilibrium at an addition rate of 20% by weight of anti-solvent (a kind of normal paraffin, which reduces solubility of part of coal extracts and enhances removal rates of ash and solids by utilizing coagulating action of the extracts). Asphaltene among the liquefaction formed materials may be recovered nearly completely, but the recovery rate for pre-asphaltene was lower. An operation test was also carried out by using slurry extracted in a 1 t/d experimental plant. In the study on operation of a 5-l/h continuous sedimentation and separation device, a maximum effect was derived with addition of anti-solvent at 25% by weight and at a stirring rate of 700 rpm. The solid-liquid separability changes depending on the kind of slurry. The low conversion rate slurry becomes difficult of separation because its viscosity is high and the difference in density between solids and liquid is small. Furthermore, the high conversion rate slurry has become difficult of separation due to small particle size of the solids. (NEDO)

  12. Creep properties of heat-resistant superalloys for nuclear plants in helium

    Shimizu, Shigeki; Satoh, Keisuke; Honda, Yoshio; Matsuda, Shozo; Murase, Hirokazu

    1979-01-01

    Creep properties of candidate superalloys for VHTR components in a helium environment at both temperatures of 800 0 C and 900 0 C were compared with those of the same alloys in the atmospheric condition, and the superalloys were contrasted with each other from the viewpoint of high temperature structural design. At 800 0 C, no significant effect of a helium environment on creep properties of the superalloys is observed. At 900 0 C, however, creep strength of Inconel 617, Incoloy 800 and Incoloy 807 in the helium environment decrease more than in the atmospheric environment. In Hastelloy X and Inconel 625, there is no significant difference between creep strengths in helium and those in the atmospheric condition. Concerning So and St values in helium at 900 0 C, Inconel 617 and Hastelloy X are clearly superior to other superalloys. (author)

  13. FY 1994 report on the Coal Liquefaction Committee; 1994 nendo sekitan ekika iinkai hokokusho

    NONE

    1995-03-01

    The paper reported the FY 1994 activities of the Coal Liquefaction Committee. The Coal Liquefaction Committee in this fiscal year was held on November 29, 1994 (1st) and March 22, 1995 (2nd), and report was made on the bituminous coal liquefaction study and state of the R and D of liquefaction base technology. Report was also made on the state of construction of bituminous coal liquefaction PP, outline of the results of the PSU operation, outline of the 11th Japan-U.S. JTM, etc. In the liquefaction base study, report/discussion were made about the improvement/rationalization of liquefaction process, study of innovative technology of coal liquefaction, study of coal liquefaction conditions, study for higher liquefaction element technology, project on the internationalization of coal liquefaction technology, etc. As to the relation of the entrained bed coal gasification power plant, report/discussion were made about survey/study on the processing of coal for coal gasification use (survey of coal kind selection, development of information processing system for coal conversion technology). Besides, as a topic, report was made on the economical evaluation/calculation of a commercial plant for brown coal liquefaction. (NEDO)

  14. Creep properties of heat-resistant superalloys for nuclear plants in helium

    Shimizu, Shigeki; Satoh, Keisuke; Matsuda, Shozo; Murase, Hirokazu; Fujioka, Junzo.

    1979-01-01

    In order to estimate the creep and rupture strengths of candidate alloys for the intermediate heat exchanger of VHTR, creep and stress rupture tests in impure helium were conducted on Hastelloy X, Inconel 617, Inconel 625, Incoloy 800 and Incoloy 807 at 900 0 C. The results were discussed in comparison with those in air and the alloys were examined from the point of view of the elevated temperature structural design. The main results obtained are summarized as follows: (1) No appreciable decrease in creep and rupture strengths in helium as compared with those in air is observed on Hastelloy X and Inconel 625. On the contrary, the creep and rupture strengths of Inconel 617 in helium decrease slightly as compared with those in air. In the case of Incoloy 807, the creep strength to cause 1 percent total strain and that to initiate secondary creep increase remarkably in helium as compared with those in air. However, the creep strength to cause initiation of tertiary creep and the rupture strength in helium remarkably decrease as compared with those in air. (2) The order of magnitude of the S 0 value for each material in helium is as follows; Hastelloy X > Inconel 617 > Incoloy 807 > Inconel 625 > Incoloy 800 Meanwhile, that of the S sub(t) value in helium is; Inconel 617 > Hastelloy X > Incoloy 807 > Inconel 625 > Incoloy 800. (author)

  15. Hydrothermal liquefaction of biomass

    Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

    2011-01-01

    This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

  16. Prospect of coal liquefaction in Indonesia

    Hartiniati; Dasuki, A.S.; Artanto, Yu.; Sulaksono, D.; Gunanjar

    1997-01-01

    With the current known oil reserves of about 11 billion barrel and annual production of approximately 500 million barrel, the country's oil reserves will be depleted by 2010, and Indonesia would have become net oil importer if no major oil fields be found somewhere in the archipelago. Under such circumstances the development of new sources of liquid fuel becomes a must, and coal liquefaction can be one possible solution for the future energy problem in Indonesia, particularly in the transportation sector due to the availability of coal in huge amount. This paper present the prospect of coal liquefaction in Indonesia and look at the possibility of integrating the process with HTR as a heat supplier. Evaluation of liquidability of several low grade Indonesian coals will also be presented. Coal from South Banko-Tanjung Enim is found to be one of the most suitable coal for liquefaction. Several studies show that an advanced coal liquefaction technology recently developed has the potential to reduce not only the environmental impact but also the production cost. The price of oil produced in the year 2000 is expected to reach US $ 17.5 ∼ 19.2/barrel and this will compete with the current oil price. Not much conclusion can be drawn from the idea of integrating HTR with coal liquefaction plant due to limited information available. (author). 7 figs, 3 tabs

  17. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Data 5. Development of coal liquefaction technology/Development of solvent extraction liquefaction technology/Development of brown coal solvent extraction plant (Development of 50t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (shiryo 5). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Research is conducted for the development of a liquefaction plant (50t/d pilot plant) for Australia's Victorian brown coal. In fiscal 1981, using the process concept and design data obtained through the study of elementary matters, a detailed design of a primary hydrogenation system is drawn, part of the equipment is procured, and on-site construction work is started. The book is a collection of materials which include engineering specifications related to electrical designs, lists of electrical items, specifications related to civil engineering designs, drawings such as planning drawings, and a detailed construction design drawn by an Australian engineering corporation and related documents and drawings. Concerning the manufacture of mechanical systems, items procurable in Japan, specifications of items procurable in Australia, lists, drawings, etc., are shown. Also included are the details of on-site preparation for construction and on-site work, conceptual designs of processes of dehydration, deashing, and secondary hydrogenation, etc. (NEDO)

  18. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Data 5. Development of coal liquefaction technology/Development of solvent extraction liquefaction technology/Development of brown coal solvent extraction plant (Development of 50t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (shiryo 5). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Research is conducted for the development of a liquefaction plant (50t/d pilot plant) for Australia's Victorian brown coal. In fiscal 1981, using the process concept and design data obtained through the study of elementary matters, a detailed design of a primary hydrogenation system is drawn, part of the equipment is procured, and on-site construction work is started. The book is a collection of materials which include engineering specifications related to electrical designs, lists of electrical items, specifications related to civil engineering designs, drawings such as planning drawings, and a detailed construction design drawn by an Australian engineering corporation and related documents and drawings. Concerning the manufacture of mechanical systems, items procurable in Japan, specifications of items procurable in Australia, lists, drawings, etc., are shown. Also included are the details of on-site preparation for construction and on-site work, conceptual designs of processes of dehydration, deashing, and secondary hydrogenation, etc. (NEDO)

  19. Report on the achievements in the projects subsidized by the Sunshine Project in fiscal 1981. Data 3. Development of a coal liquefaction technology - development of a solvent extraction and liquefaction technology - 'development of a brown coal based solvent extraction plant' (Development of a 50-t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (shiryo 3). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Developmental researches were carried out on a liquefaction plant for the Victoria brown coal produced in Australia (a 50-t/d pilot plant). In fiscal 1981, detailed design was performed on the primary hydrogenation system by using the process conception and the design data obtained in the element studies. Part of the devices was procured, and the site construction was begun. The present data is a collection of drawings in relation with the instrumentation design, such as the meter specifications, front view drawings for meter panels, drawings for panel arrangement in the central control room, a computer room layout drawing, control system explanation drawings, interlock diagrams, and the instrumentation power supply diagrams. (NEDO)

  20. Hydrothermal liquefaction of biomass

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

    2014-01-01

    Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...

  1. Thirty years of screw compressors for helium; Dreissig Jahre Schraubenkompressoren fuer Helium

    Wahl, H. [Kaeser Kompressoren GmbH, Coburg (Germany). Technisches Buero/Auftragskonstruktion

    2007-07-01

    KAESER helium compressors, as well as their other industrial compressors, will be further developed with the intention to improve the availability and reliability of helium liquefaction systems. Further improvement of compressor and control system efficiency will ensure a low and sustainable operating cost. Fast supply of replacement parts with several years of warranty is ensured by a world-wide distribution system and is also worked on continuously. (orig.)

  2. Report on the achievements in development of a coal liquefaction technology (a solvent extraction and liquefaction technology) in the Sunshine Project in fiscal 1981. Data 1. Development of a brown coal based solvent extraction plant (50 t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (shiryo 1). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    This paper describes the data-1 for developing a brown coal based solvent extraction plant in the Sunshine Project in fiscal 1981. The data are for the development of a liquefaction plant for Victoria brown coal produced in Australia (a 50-t/d pilot plant). Fiscal 1981 has performed detailed design on the primary hydrogenation system by using the process conception and the design data obtained in the element studies. Part of the machines and devices was procured, and the site construction was begun. Detailed design documents and drawings were prepared. The data collected in relation with the plant design included the followings: device lists, entire factory layout drawings, device arrangement drawings, process flow sheets, utility flow sheets (fuel gas and fuel oil systems, steam and condensate systems, air for instrumentation, plant air, cooling water supply and return, industrial water and treated water, a waste water treatment system, a nitrogen system, and a waste gas system), public pollution preventing facilities, hazardous location classifying plans, and material balances. The data collected in relation with the machine design included pressure vessel engineering specifications, heat exchanger engineering specifications, and device purchase specifications. (NEDO)

  3. Liquefaction of uranium tailings

    1992-02-01

    Numerical methods for assessing the liquefaction potential of soils are reviewed with a view to their application to uranium tailings. The method can be divided into two categories: total stress analysis, where changes in pore pressure are not considered in the soil model, and effective stress analysis, where changes in pore pressure are included in the soil model. Effective stress analysis is more realistic, but few computer programs exist for such analysis in two or three dimensions. A simple linearized, two-dimensional, finite element effective stress analysis which incorporates volumetric compaction due to shear motion is described and implemented. The new program is applied to the assessment of liquefaction potential of tailings in the Quirke Mine tailings area near Elliot Lake, Ontario. The results are compared with those of a total stress analysis. Both analyses indicate liquefaction would occur if a magnitude 6.0 earthquake were to occur near the area. However, the extent of liquefaction predicted by the effective stress analysis is much less than that predicted by the total stress analysis. The results of both methods are sensitive to assumed material properties and to the method used to determine the cyclic shear strength of the tailings. Further analysis, incorporating more in situ and/or laboratory data, is recommended before conclusions can be made concerning the dynamic stability of these tailings

  4. Japan's New Sunshine Project. 1994 annual summary of coal liquefaction and gasification

    NONE

    1995-08-01

    This paper summarizes the report for fiscal 1994 on research and development related to coal liquefaction and gasification. In the research and development of coal liquefaction technologies, reports were given on research of liquefaction characteristics of different coals and liquefaction process thereof, and on research of catalysts for the coal liquefaction. In the research and development of coal gasification technologies, reports were given on fundamental studies on gasification characteristics of different coals. In the research and development of liquefaction technologies for bituminous coal, reports were given on design, construction and operation of a bituminous coal liquefaction pilot plant with a capacity of 150 t/d, and the operation supporting studies on the pilot plant. In the fundamental research on the coal liquefaction process, reports were given on refining technologies and utilization of the refined materials, and studies on environment preservation in applying the coal liquefaction technologies. In the research on hydrogen manufacturing technologies by using the fundamental coal technology, reports were given on design, construction and operational studies of a pilot plant. In the research and development of the coal gasification technologies, reports were given on development of a jet-flow gasified coal electric power plant, selection of coals, and development of a data processing system. (NEDO)

  5. Japan's New Sunshine Project. 1994 annual summary of coal liquefaction and gasification

    NONE

    1995-08-01

    This paper summarizes the report for fiscal 1994 on research and development related to coal liquefaction and gasification. In the research and development of coal liquefaction technologies, reports were given on research of liquefaction characteristics of different coals and liquefaction process thereof, and on research of catalysts for the coal liquefaction. In the research and development of coal gasification technologies, reports were given on fundamental studies on gasification characteristics of different coals. In the research and development of liquefaction technologies for bituminous coal, reports were given on design, construction and operation of a bituminous coal liquefaction pilot plant with a capacity of 150 t/d, and the operation supporting studies on the pilot plant. In the fundamental research on the coal liquefaction process, reports were given on refining technologies and utilization of the refined materials, and studies on environment preservation in applying the coal liquefaction technologies. In the research on hydrogen manufacturing technologies by using the fundamental coal technology, reports were given on design, construction and operational studies of a pilot plant. In the research and development of the coal gasification technologies, reports were given on development of a jet-flow gasified coal electric power plant, selection of coals, and development of a data processing system. (NEDO)

  6. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Development of coal liquefaction plant (Research on total system); 1981 nendo sekitan ekika plant no kaihatsu (total system no kenkyu) seika hokokusho

    NONE

    1982-03-01

    For a quantitative analysis of a coal liquefaction process and its constituent sub-processes from both engineering and economic viewpoints, research is conducted for the development of a coal liquefaction process simulator. In the development of a liquefaction simulator, surveys and studies are performed relative to a coal liquefaction process, which is the object of this development effort, its system, existing like simulators, computation for the estimation of the physical properties that a liquefaction simulator should be equipped with, liquefaction yield prediction model, unit operation model, etc. Based on the results of these studies, a conceptual system design is drawn, which is the first step toward the programming of a more concrete software program. Also compiled into this book are the contents of advice and guidance provided by the total system committee in the period September 1981-February 1982 on the research for the development of a liquefaction simulator, and reports by researchers who were dispatched to the U.S. etc. for the development of a coal liquefaction simulator. (NEDO)

  7. Prospects for application of high-temperature helium reactor (HTHR) to provide for power needs in refineries and petrochemical plants

    Feigin, E.A.; Raud, E.A.; Romanova, E.G.; Panasenko, P.A.; Nikitin, V.N.

    1990-01-01

    An analysis performed shows that heat supply from High Temperature Helium Reactor (HTHR) located several miles from crude oil refining units, operating at 360-400 deg. C, can be arranged to use organic heat-carriers. At higher operating temperatures most acceptable are saline carriers. However the final choice of heat carries requires extra research including that on a large scale basis in order to improve the technology and equipment of the heat-supply system. The following problems can be solved by implementing HTHRs at the crude oil processing and petrochemical plants: improving pollution control, making more hydrocarbon fuel available for other uses, intensifying the operation of process units, and making them less fire hazardous, increasing the power efficiency of process plants

  8. System analysis for HTTR-GT/H2 plant. Safety analysis of HTTR for coupling helium gas turbine and H2 plant

    Sato, Hiroyuki; Yan, Xing L.; Ohashi, Hirofumi

    2017-08-01

    High Temperature Gas-cooled Reactor (HTGR) is expected to extend the use of nuclear heat to a wider spectrum of industrial applications because of the high temperature heat supply capability and inherently safe characteristics. Japan Atomic Energy Agency initiated a nuclear cogeneration demonstration project with helium gas turbine power generation and thermochemical hydrogen production utilizing the High Temperature engineering Test Reactor (HTTR), the first HTGR in Japan. This study carries out safety evaluation for the HTTR gas turbine hydrogen cogeneration test plant (HTTR-GT/H 2 plant). The evaluation was conducted for the events newly identified corresponding to the coupling of helium gas turbine and hydrogen production plant to the HTTR. The results showed that loss of load event does not have impact on temperature of fuel and reactor coolant pressure boundary. In addition, reactor coolant pressure does not exceed the evaluation criteria. Furthermore, it was shown that reactor operation can be maintained against temperature transients induced by abnormal events in hydrogen production plant. (author)

  9. FY 1992 report on the Coal Liquefaction Committee; 1992 nendo sekitan ekika iinkai hokokusho

    NONE

    1993-03-01

    The paper reported activities of the Coal Liquefaction Committee in FY 1992. In the 1st committee meeting, report/discussion were made of the summary of the FY 1992 R and D plan on the bituminous coal liquefaction, brown coal liquefaction and the common/basic technology. Further, the following were reported as topics: results of the operation by bituminous coal liquefaction PSU and small equipment, state of arrangement of the results of the brown coal liquefaction project, making of the basic policy for development of the common/basic technology, construction of package of coal liquefaction technology. In the 2nd committee meeting, the summary of the results of the FY 1992 R and D was reported/discussed. As to the development of bituminous coal liquefaction technology, study using pilot plant and support study were reported. Concerning the development of brown coal liquefaction technology, study using a 50t/d pilot plant and complementary study of operation. Relating to the development of the common/basic technology, trial manufacture/development of plant equipment/materials, survey of selection of coal kind, etc. The paper also reported a scheme on the evaluation of efficiency of the brown coal liquefaction process. (NEDO)

  10. Coal liquefaction committee report for fiscal 1981; 1981 nendo sekitan ekika iinkai hokokusho

    NONE

    1982-03-01

    For the assurance of smooth progress of coal technology development endeavors, the New Energy and Industrial Technology Development Organization (NEDO) has installed coal technology development committees (general committee on coal technologies, coal liquefaction committee, plant materials committee, coal type survey committee, total system committee, and coal gasification committee). The coal liquefaction committee deliberates and evaluates liquefaction technology and propels forward smoothly the efforts to develop the technology. Under the coal liquefaction committee, there are four subcommittees, which are the 1st subcommittee (primary liquefaction subcommittee), 2nd subcommittee (solid/liquid separation subcommittee), 3rd subcommittee (secondary hydrogenation subcommittee), and the 4th subcommittee (brown coal liquefaction subcommittee). The 2nd and 3rd subcommittees deal with common tasks as they were studied in fiscal 1980. The 1st subcommittee incorporates into itself the old subcommittees that respectively worked on the three liquefaction processes (the direct hydrogenation process, the solvent extraction process, and the Solvolysis process), and is designed to provide a site for information exchange. A brown coal liquefaction committee is incorporated into the coal liquefaction committee as the 4th subcommittee. This report is a compilation of the agendas of the respective subcommittees of the coal liquefaction committee. (NEDO)

  11. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvent extraction and liquefaction plant (research and development of secondary hydrogenation); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, yozai chushutsu ekika plant no kaihatsu seika hokokusho. Niji suiten no kenkyu kaihatsu

    NONE

    1982-03-01

    Among the items of the Sunshine Project in fiscal 1981 for development of a solvent extraction and liquefaction plant, this paper describes the achievements in developing secondary hydrogenation. A small continuous hydrogenation device equipped with three reaction columns that can be filled with catalyst of 50 cc, and a dedicated testing room were designed, and orders were placed with manufacturers. The fabrication, assembly, delivery, installation, piping and wiring were all completed. The device passed a completion inspection based on the high-pressure gas safety assurance law in December 1981. After leakage due to gas and material oil was checked, a trial operation was performed, and verified of normal operation. A screening test was carried out on three kinds of commercially available and prototype catalysts before testing the SRC containing material for studying the secondary hydrogenation. The circulating solvent having a boiling point from 180 to 430 degree C (F56-01) was used as the test sample. In order to investigate the relationship between the kinds of solvent used for the SRC fraction and the secondary hydrogenation capability, solvents were made by treating the spent solvent F56-01. Trial manufacture was begun on the alumina based catalyst as a deliming catalyst, and on the red mud, bauxite and alumina based catalysts as hydrogenation and decomposition catalysts. (NEDO)

  12. Residual Liquefaction under Standing Waves

    Kirca, V.S. Ozgur; Sumer, B. Mutlu; Fredsøe, Jørgen

    2012-01-01

    This paper summarizes the results of an experimental study which deals with the residual liquefaction of seabed under standing waves. It is shown that the seabed liquefaction under standing waves, although qualitatively similar, exhibits features different from that caused by progressive waves....... The experimental results show that the buildup of pore-water pressure and the resulting liquefaction first starts at the nodal section and spreads towards the antinodal section. The number of waves to cause liquefaction at the nodal section appears to be equal to that experienced in progressive waves for the same...

  13. Summary of FY 1980 results of Sunshine Project. Development of coal liquefaction techniques; 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sunshine keikaku itaku kenkyu kaihatsu

    NONE

    1981-03-01

    This report summarizes the results of the 3 R and D themes for coal liquefaction techniques, pursued by the Sunshine Project; (1) development of solvent extraction type liquefaction plant, and brown coal liquefaction technique R and D demonstration surveys, (2) development of solvolysis type liquefaction plant, and (3) development of direct hydrogenation type liquefaction plant. For the theme (1), the 1 T/D test plant, solid/liquid separator and small-size continuous settlement separator are constructed, and partly completed. The elementary studies include solvent extraction type liquefaction process, materials for coal liquefaction plant and solid/liquid separation. Australia's Victoria brown coal and Chinese coal are studied to clarify the possible problems involved in liquefaction of these coal species for commercialization of the liquefaction techniques in the early stage. The elementary techniques studied include dehydration of brown coal, milling at high temperature in oil, de-ashing, and secondary and primary hydrogenation. For the theme (2), the 1 T/D plant is inspected and maintained to clarify the problems involved in the continuous operation, revamped and repaired as necessary, given preventive maintenance, and tested for operability confirmation. The elementary studies include solvolysis type liquefaction process, scale-up, hydrogenation plant for solvolysis pitch. For the item (3), the 2.4 T/D test plant is constructed, and the elementary studies are conducted, for, e.g., liquefaction reactions in the presence of an iron-based catalyst. (NEDO)

  14. Summary of FY 1980 results of Sunshine Project. Development of coal liquefaction techniques; 1980 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho. Sunshine keikaku itaku kenkyu kaihatsu

    NONE

    1981-03-01

    This report summarizes the results of the 3 R and D themes for coal liquefaction techniques, pursued by the Sunshine Project; (1) development of solvent extraction type liquefaction plant, and brown coal liquefaction technique R and D demonstration surveys, (2) development of solvolysis type liquefaction plant, and (3) development of direct hydrogenation type liquefaction plant. For the theme (1), the 1 T/D test plant, solid/liquid separator and small-size continuous settlement separator are constructed, and partly completed. The elementary studies include solvent extraction type liquefaction process, materials for coal liquefaction plant and solid/liquid separation. Australia's Victoria brown coal and Chinese coal are studied to clarify the possible problems involved in liquefaction of these coal species for commercialization of the liquefaction techniques in the early stage. The elementary techniques studied include dehydration of brown coal, milling at high temperature in oil, de-ashing, and secondary and primary hydrogenation. For the theme (2), the 1 T/D plant is inspected and maintained to clarify the problems involved in the continuous operation, revamped and repaired as necessary, given preventive maintenance, and tested for operability confirmation. The elementary studies include solvolysis type liquefaction process, scale-up, hydrogenation plant for solvolysis pitch. For the item (3), the 2.4 T/D test plant is constructed, and the elementary studies are conducted, for, e.g., liquefaction reactions in the presence of an iron-based catalyst. (NEDO)

  15. Report on the achievements in the projects subsidized by the Sunshine Project in fiscal 1981. Data 2. Development of a coal liquefaction technology - development of a solvent extraction and liquefaction technology - 'development of a brown coal based solvent extraction plant' (Development of a 50-t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (shiryo 2). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Developmental researches were carried out on a liquefaction plant for the Victoria brown coal produced in Australia (a 50-t/d pilot plant). In fiscal 1981, detailed design was performed on the primary hydrogenation system by using the process conception and the design data obtained in the element studies. Part of the devices was procured, and the site construction was begun. The present data is a collection of drawings in relation with the machine design, such as the piping specifications, standard piping drawings, piping design procedures, piping drawings, pipe lists, and device inspection specifications. In relation with the instrumentation design, the instrumentation engineering specifications and meter lists. (NEDO)

  16. A preliminary study on the optimal configuration and operating range of a “microgrid scale” air liquefaction plant for Liquid Air Energy Storage

    Borri, E.; Tafone, A.; Romagnoli, A.; Comodi, G.

    2017-01-01

    Highlights: • A liquefaction cycle for a microgrid scale Liquid Air Energy Storage is proposed. • Different liquefaction cycles are compared by means of parametric analysis. • The optimal configuration proposed is a Kapitza cycle with two stage compression. • The specific consumption of the optimal configuration is around 700 kW h/t. • Specific consumption reduces to 532 kW h/t if a pressurized phase separator is used. - Abstract: Liquid Air Energy Storage systems represent a sustainable solution to store energy. Although a lot of interest is dedicated to large scale systems (up to 300 tons per day), a small-scale Liquid Air Energy Storage can be used as energy storage as part of a microgrid and/or an energy distribution network. However, when scaling down the size of the system, the round trip efficiency decreases due to the low performance of the liquefaction process. In this paper a preliminary study on the optimal configuration for a microgrid scale liquefaction cycle (10 tons per 12 h) for a Liquid Air Energy Storage application is proposed in order to minimize the specific consumption. The Linde, Claude and Kapitza cycles are modelled and compared by means of a parametric analysis carried out with the software Aspen HYSYS. The results show that the two stages compression Kapitza cycle operating at 40 bar represents an optimal solution in terms of performance and cycle configuration resulting in a specific consumption of about 700 kW h/t. The analysis also shows that the implementation of a pressurized phase separator leads to a reduction of the specific consumption as high as 21% (≈550 kW h/t).

  17. Helium turbo-expander with an alternator

    Akiyama, Yoshitane

    1980-01-01

    Study was made on a helium turbo-expander, the heart of helium refrigerator systems, in order to develop a system which satisfies the required conditions. A helium turbo-expander with externally pressurized helium gas bearings at the temperature of liquid nitrogen and an alternator as a brake have been employed. The essential difference between a helium turbo-expander and a nitrogen turbo-expander was clarified. The gas bearing lubricated with nitrogen at room temperature and the gas bearing lubricated with helium at low temperature were tested. The flow rate of helium in a helium refrigerator for a large superconducting magnet is comparatively small, therefore a helium turbine must be small, but the standard for large turbine design can be applied to such small turbine. Using the alternator as a brake, the turbo-expander was easily controllable electrically. The prototype turbo-expander was made, and the liquefaction test with it and MHD power generation test were carried out. (Kako, I.)

  18. Two-stage liquefaction of a Spanish subbituminous coal

    Martinez, M.T.; Fernandez, I.; Benito, A.M.; Cebolla, V.; Miranda, J.L.; Oelert, H.H. (Instituto de Carboquimica, Zaragoza (Spain))

    1993-05-01

    A Spanish subbituminous coal has been processed in two-stage liquefaction in a non-integrated process. The first-stage coal liquefaction has been carried out in a continuous pilot plant in Germany at Clausthal Technical University at 400[degree]C, 20 MPa hydrogen pressure and anthracene oil as solvent. The second-stage coal liquefaction has been performed in continuous operation in a hydroprocessing unit at the Instituto de Carboquimica at 450[degree]C and 10 MPa hydrogen pressure, with two commercial catalysts: Harshaw HT-400E (Co-Mo/Al[sub 2]O[sub 3]) and HT-500E (Ni-Mo/Al[sub 2]O[sub 3]). The total conversion for the first-stage coal liquefaction was 75.41 wt% (coal d.a.f.), being 3.79 wt% gases, 2.58 wt% primary condensate and 69.04 wt% heavy liquids. The heteroatoms removal for the second-stage liquefaction was 97-99 wt% of S, 85-87 wt% of N and 93-100 wt% of O. The hydroprocessed liquids have about 70% of compounds with boiling point below 350[degree]C, and meet the sulphur and nitrogen specifications for refinery feedstocks. Liquids from two-stage coal liquefaction have been distilled, and the naphtha, kerosene and diesel fractions obtained have been characterized. 39 refs., 3 figs., 8 tabs.

  19. BP and NCB to collaborate in coal liquefaction study. [Supercritical gas extraction; dissolution in anthracene oil

    1978-02-17

    British Petroleum and NCB are collaborating in a two year study of coal liquefaction which could result in a demonstration plant being built. The two liquefaction techniques which the NCB is developing at present are supercritical extraction, and dissolution in anthracene oil. A disadvantage of the latter process is that high grade coking coals must be used.

  20. Fiscal 1997 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1997 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    NONE

    1998-03-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. In the modification of facilities, equipment and devices were procured for the product oil reforming facilities and their installation was partly accomplished. In the coal injection operation, a 60-day slurry operation was conducted, using coal types of the upper limit and lower limit qualities, for expanding the scope of coal types applicable to the NEDOL process and for exploring optimum conditions, and another operation of 37 days was conducted using Chinese coal and Chinese-prepared liquefaction catalysts, and the two operations were studied for difference in yields and in operationality. Characteristics of the liquefaction reactors were investigated and basic studies were made relative to the physical property of the yielded coal oil. In the operation for maintenance, the 1st liquefaction reactor was singly operated for an 8-day slurry operation, which was to check the progress of liquefaction in a 1-reactor setup. Concerning the reforming of the product oil, the hydrogenation reactors were checked for their response to temperature control. Moreover, hydrogenation solvents were produced for the PSU and for China. (NEDO)

  1. Fiscal 1996 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1996 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    NONE

    1997-03-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. In the modification of facilities, detailed designs were prepared for product oil reforming facilities and some equipment and devices were procured. In addition, the 3rd liquefaction reactor cone section and the neutron attenuation-aided measuring device were refurbished. In the injection of coal, a 62-day and 23-day slurry injection operations were accomplished using Tanito Harum coal, when the impact imposed on the yield of the product, etc., by the change of liquefaction catalysts and by gas phase hydrogen concentration enriching conditions was investigated, and the unit was examined for operationality. During a 42-day operation for maintenance, the unit was operated using only the slurry heater for the investigation of the initial reaction in liquefaction, and studies were conducted about the heater exit temperature, G/L (gas-liquid ratio), and the effect to ensue from the use of a different solvent. In the effort to develop and evaluate new materials, implantation tests were conducted for metallic materials and the 3rd liquefaction reactor was subjected to a non-destructive inspection. Wastewater from the process was examined for quality, and environment-related measurements were performed for the atmosphere. (NEDO)

  2. Cooperative research in coal liquefaction

    Huffman, G.P.; Sendlein, L.V.A. (eds.)

    1991-05-28

    Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

  3. Canada's helium output rising fast

    1966-12-01

    About 12 months from now, International Helium Limited will be almost ready to start up Canada's second helium extraction plant at Mankota, in Saskatchewan's Wood Mountain area about 100 miles southwest of Moose Jaw. Another 80 miles north is Saskatchewan's (and Canada's) first helium plant, operated by Canadian Helium and sitting on a gas deposit at Wilhelm, 9 miles north of Swift Current. It contains almost 2% helium, some COD2U, and the rest nitrogen. One year in production was apparently enough to convince Canadian Helium that the export market (it sells most of its helium in W. Europe) can take a lot more than it's getting. Construction began this summer on an addition to the Swift Current plant that will raise its capacity from 12 to 36MMcf per yr when it goes on stream next spring. Six months later, International Helium's 40 MMcf per yr plant to be located about 4 miles from its 2 Wood Mountain wells will double Canada's helium output again.

  4. Hydrothermal Liquefaction of Biomass

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international

  5. Japan`s sunshine project. 17.. 1992 annual summary of coal liquefaction and gasification

    1993-09-01

    This report describes the achievement of coal liquefaction and gasification technology development in the Sunshine Project for FY 1992. It presents the research and development of coal liquefaction which includes studies on reaction mechanism of coal liquefaction and catalysts for coal liquefaction, the research and development of coal gasification technologies which includes studies on gasification characteristics of various coals and improvement of coal gasification efficiency, the development of bituminous coal liquefaction which includes engineering, construction and operation of a bituminous coal liquefaction pilot plant and research by a process supporting unit (PSU), the development of brown coal liquefaction which includes research on brown coal liquefaction with a pilot plant and development of techniques for upgrading coal oil from brown coal, the development of common base technologies which includes development of slurry letdown valves and study on upgrading technology of coal-derived distillates, the development of coal-based hydrogen production technology with a pilot plant, the development of technology for entrained flow coal gasification, the assessment of coal hydrogasification, and the international co-operation. 4 refs., 125 figs., 39 tabs.

  6. Liquid helium

    Atkins, K R

    1959-01-01

    Originally published in 1959 as part of the Cambridge Monographs on Physics series, this book addresses liquid helium from the dual perspectives of statistical mechanics and hydrodynamics. Atkins looks at both Helium Three and Helium Four, as well as the properties of a combination of the two isotopes. This book will be of value to anyone with an interest in the history of science and the study of one of the universe's most fundamental elements.

  7. Development of helium turbines associated with high temperature nuclear reactors for electric power plants

    Chaboseau, J.

    1975-01-01

    First, the system is defined and found perfectly adapted, in the industrial meaning of the term, to the utilization with high temperature nuclear reactors. Subsequently, a realistic determination of its original feature and that of the turbine is tempted: these features are few, particularly if the existence of numerous, already utilized, direct cycle devices is considered. Then, the influence of main characteristic parameters is evaluated, i.e. the choice of thermodynamic cycle, the utilization of helium, the principle of the layout and the rating of the power station. It appears to be sure that the engineering designs are of great importance for the turbine designer. For the latter, however, the technical aspects of the required developments will be of the conventional type. The character and the importance of these developments will mainly depend on how the system is spread in industry. It seems possible that the reasonable choice of the data of the first generating station allows to reduce the preliminary developments to a minimum amount while ensuring the subsequent evolution of the techniques. The inherent research of perfectness of the system justifies to anticipate long-term developments which are pursued in parallel with the commissioning of subsequent generations of power stations [fr

  8. Operating Manual of Helium Refrigerator (Rev. 2)

    Song, K.M.; Son, S.H.; Kim, K.S.; Lee, S.K.; Kim, M.S. [Korea Electric Power Research Institute, Taejon (Korea)

    2002-07-01

    A helium refrigerator was installed as a supplier of 20K cold helium to the cryogenic distillation system of WTRF pilot plant. The operating procedures of the helium refrigerator, helium compressor and auxiliary apparatus are described for the safety and efficient operation in this manual. The function of the helium refrigerator is to remove the impurities from the compressed helium of about 250psig, to cool down the helium from ambient temperature to 20K through the heat exchanger and expansion engine and to transfer the cold helium to the cryogenic distillation system. For the smoothly operation of helium refrigerator, the preparation, the start-up, the cool-down and the shut-down of the helium refrigerator are described in this operating manual. (author). 3 refs., 14 tabs.

  9. EXPLORATORY RESEARCH ON NOVEL COAL LIQUEFACTION CONCEPT

    Brandes, S.D.; Winschel, R.A.

    1998-11-30

    The report presents a summary the work performed under DOE Contract No. DE-AC22-95PC95050. Investigations performed under Task 4--Integrated Flow Sheet Testing are detailed. In this program, a novel direct coal liquefaction technology was investigated by CONSOL Inc. with the University of Kentucky Center for Applied Energy Research and LDP Associates. The process concept explored consists of a first-stage coal dissolution step in which the coal is solubilized by hydride ion donation. In the second stage, the products are catalytically upgraded to refinery feedstocks. Integrated first-stage and solids-separation steps were used to prepare feedstocks for second-stage catalytic upgrading. An engineering and economic evaluation was conducted concurrently with experimental work throughout the program. Approaches to reduce costs for a conceptual commercial plant were recommended at the conclusion of Task 3. These approaches were investigated in Task 4. The economic analysis of the process as it was defined at the conclusion of Task 4, indicates that the production of refined product (gasoline) via this novel direct liquefaction technology is higher than the cost associated with conventional two-stage liquefaction technologies.

  10. FY 1991 report on the bituminous coal liquefaction section; 1991 nendo rekiseitan ekikabukai hokokusho

    NONE

    1992-03-01

    The paper reported activities of the bituminous coal liquefaction section in FY 1991. In the 1st bituminous coal liquefaction section meeting, report/discussion were made on the outline of the plan on the FY 1991 research using pilot plant and the support study of pilot plant. In the 2nd section meeting, report was made on 'How the development of coal liquefaction technology should be in the 21st century,' a report made by the joint section of bituminous coal/brown coal liquefaction. In the 3rd section meeting, report/discussion were made on the state of progress of the FY 1991 R and D and results. In the study using the bituminous coal liquefaction pilot plant, report was made on the outline of construction of a 150t/d pilot plant, study on the acquisition of material balance, analytical study of the data on liquefaction tower, testing survey on properties of coal slurry, and testing survey on slurry preheating furnace. In the support study of pilot plant, report was made on the study using 1t/d PUS, study on the development of the optimum coal refining technology and improvement in the distillate distribution, study of conditions for coal liquefaction and study of solvent hydrogenation catalyst. (NEDO)

  11. Helium cryogenics

    Van Sciver, Steven W

    2012-01-01

    Twenty five years have elapsed since the original publication of Helium Cryogenics. During this time, a considerable amount of research and development involving helium fluids has been carried out culminating in several large-scale projects. Furthermore, the field has matured through these efforts so that there is now a broad engineering base to assist the development of future projects. Helium Cryogenics, 2nd edition brings these advances in helium cryogenics together in an updated form. As in the original edition, the author's approach is to survey the field of cryogenics with emphasis on helium fluids. This approach is more specialized and fundamental than that contained in other cryogenics books, which treat the associated range of cryogenic fluids. As a result, the level of treatment is more advanced and assumes a certain knowledge of fundamental engineering and physics principles, including some quantum mechanics. The goal throughout the work is to bridge the gap between the physics and engineering aspe...

  12. Capacity enhancement of indigenous expansion engine based helium liquefier

    Doohan, R. S.; Kush, P. K.; Maheshwari, G.

    2017-02-01

    Development of technology and understanding for large capacity helium refrigeration and liquefaction at helium temperature is indispensable for coming-up projects. A new version of helium liquefier designed and built to provide approximately 35 liters of liquid helium per hour. The refrigeration capacity of this reciprocating type expansion engine machine has been increased from its predecessor version with continuous improvement and deficiency debugging. The helium liquefier has been built using components by local industries including cryogenic Aluminum plate fin heat exchangers. Two compressors with nearly identical capacity have been deployed for the operation of system. Together they consume about 110 kW of electric power. The system employs liquid Nitrogen precooling to enhance liquid Helium yield. This paper describes details of the cryogenic expander design improvements, reconfiguration of heat exchangers, performance simulation and their experimental validation.

  13. Proposal for the award of an industrial services contract for the operation and maintenance of liquid helium cryogenic plants

    2000-01-01

    This document concerns the award of an Industrial Services contract for the operation and maintenance of liquid helium cryogenic plants. Following a market survey carried out among 54 firms in twelve Member States, a call for tenders (IT-2719/LHC) was sent on 18 August 2000 to two firms and four consortia, two consisting of two firms and two consisting of three firms, in five Member States. By the closing date, CERN had received tenders from one firm and three consortia, in four Member States. The Finance Committee is invited to agree to the negotiation of a contract with the consortium AIR LIQUIDE (FR) - LINDE KRYOTECHNIK (CH) - SERCO (DE), the lowest bidder, for an initial period of four years from 17 July 2001 for a total amount of 19 804 400 Swiss francs, not subject to revision until 16 July 2005. The contract will include options for two one-year extensions beyond the initial four-year period. The consortium has indicated the following distribution by country of the contract value covered by this adjudi...

  14. Secondary liquefaction in ethanol production

    2007-01-01

    The invention relates to a method of producing ethanol by fermentation, said method comprising a secondary liquefaction step in the presence of a themostable acid alpha-amylase or, a themostable maltogenic acid alpha-amylase.......The invention relates to a method of producing ethanol by fermentation, said method comprising a secondary liquefaction step in the presence of a themostable acid alpha-amylase or, a themostable maltogenic acid alpha-amylase....

  15. Case studies on direct liquefaction of low rank Wyoming coal

    Adler, P.; Kramer, S.J.; Poddar, S.K. [Bechtel Corp., San Francisco, CA (United States)

    1995-12-31

    Previous Studies have developed process designs, costs, and economics for the direct liquefaction of Illinois No. 6 and Wyoming Black Thunder coals at mine-mouth plants. This investigation concerns two case studies related to the liquefaction of Wyoming Black Thunder coal. The first study showed that reducing the coal liquefaction reactor design pressure from 3300 to 1000 psig could reduce the crude oil equivalent price by 2.1 $/bbl provided equivalent performing catalysts can be developed. The second one showed that incentives may exist for locating a facility that liquifies Wyoming coal on the Gulf Coast because of lower construction costs and higher labor productivity. These incentives are dependent upon the relative values of the cost of shipping the coal to the Gulf Coast and the increased product revenues that may be obtained by distributing the liquid products among several nearby refineries.

  16. Motor fuels made by direct liquefaction of coal, peat and biomass. Drivmedel genom direktfoervaetskning av kol, torv och biomassa

    Granath, L; Karlsson, G; Karlsson, G; Nilsson, T

    1981-01-01

    The Department of Chemical Technology at the Royal Institute of Technology has completed a system study concerning direct liquefaction of peat and biomass to produce transportation fuel. A comprehensive survey of coal liquefaction is included. Gasoline produced in Sweden from direct liquefaction of imported coal may compete with regular gasoline at the earliest around 1985. Biomass can become a competitive alternative to black coal at the beginning of the 21st century. Methanol can be produced from wood with a higher efficiency than the transportation fuels which are produced by direct liquefaction. The peat is not good source for liquefaction as wood chips. A continuously working liquefaction plant designed also for peat among other substances is under construction at the Royal Institute of Technology, Stockholm.

  17. Achievement report on developing coal liquefaction technologies in fiscal 1998 - edition B. Development of bituminous coal liquefaction technology (studies by using pilot plant) 2/2; 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho B. 2/2. Rekiseitan ekika gijutsu no kaihatsu (pilot plant ni yoru kenkyu)

    NONE

    1999-03-01

    With an objective to improve the environment by substituting petroleum energy by coal, and by reducing emission of SOx and NOx, research and development has been performed on coal liquefaction technologies. This paper summarizes the achievements thereof in fiscal 1998. In the operation study, the coal charging operation has been carried out for 269 days (6,169 hours) in total since the operation has been launched, and the targets were achieved. In the facility repairs, periodical inspections were performed including daily maintenance during the operation, the legal inspection on the boiler and the pressure vessel of the category one after completing the RUN-5, and disassembling and opening inspections on other devices. After having completed the RUN-6 and 7, the final verification inspection and the facility rinsing were performed after the operation studies have been completed. The data acquired in the facility maintenance were summarized as part of the technological package after the assessment. The investigative researches have executed development of a liquefying reaction simulator, tests and investigations on pulverization of the liquefying catalyst, evaluation on the activity of the used hydrogenating catalyst, and investigation on the effect of the coal liquefaction facilities and products on the environment. The technologies were investigated on coal liquefaction, and the plans for disassembling studies were established. (NEDO)

  18. Fiscal 1998 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1998 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    NONE

    1999-06-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. For the modification of facilities, product oil reforming facilities were installed. In the coal injection operation, a 59-day slurry operation was carried out using Tanito Harum coal, which was for the evaluation of the reforming effect under the product reforming conditions, operationality, and liquefaction characteristics. A 37-day slurry operation was also performed using Chinese coal, which was intended to pursue improved cost performance and to collect the light oil fraction in the flow of reforming operation. In the operation for maintenance, investigations were conducted into conditions for hydrogenation in a 1-through operation involving the solvent hydrogenation process and the normal pressure distillation facilities and into the effect of pre-hydrogenation solvent properties, which aimed at grasping the effect of product oil reforming measures and their influence on operationality. In the survey of environments, the properties of wastewater from the liquefaction process using Tanito Harum coal were studied and toxicity evaluation tests were conducted for activated sludge. (NEDO)

  19. Plasma electrolytic liquefaction of cellulosic biomass

    Dingliang, TANG; Xianhui, ZHANG; Si-ze, YANG

    2018-04-01

    In this paper, the rapid liquefaction of a corncob was achieved by plasma electrolysis, providing a new method for cellulosic biomass liquefaction. The liquefaction rate of the corncob was 95% after 5 min with polyethylene glycol and glycerol as the liquefying agent. The experiments not only showed that H+ ions catalyzed the liquefaction of the corncob, but also that using accelerated H+ ions, which were accelerated by an electric field, could effectively improve the liquefaction efficiency. There was an obvious discharge phenomenon, in which the generated radicals efficiently heated the solution and liquefied the biomass, in the process of plasma electrolytic liquefaction. Finally, the optimum parameters of the corncob liquefaction were obtained by experimentation, and the liquefaction products were analyzed.

  20. Report on the achievements in the projects subsidized by the Sunshine Project in fiscal 1981. Data 3. Development of a coal liquefaction technology - development of a solvent extraction and liquefaction technology - 'development of a brown coal based solvent extraction plant' (Development of a 50-t/d pilot plant); 1981 nendo sekitan ekika gijutsu no kaihatsu seika hokokusho (shiryo 3). Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (50ton/nichi pilot plant no kaihatsu))

    NONE

    1982-03-01

    Developmental researches were carried out on a liquefaction plant for the Victoria brown coal produced in Australia (a 50-t/d pilot plant). In fiscal 1981, detailed design was performed on the primary hydrogenation system by using the process conception and the design data obtained in the element studies. Part of the devices was procured, and the site construction was begun. The present data is a collection of drawings in relation with the instrumentation design, such as the meter specifications, front view drawings for meter panels, drawings for panel arrangement in the central control room, a computer room layout drawing, control system explanation drawings, interlock diagrams, and the instrumentation power supply diagrams. (NEDO)

  1. Economically viable large-scale hydrogen liquefaction

    Cardella, U.; Decker, L.; Klein, H.

    2017-02-01

    The liquid hydrogen demand, particularly driven by clean energy applications, will rise in the near future. As industrial large scale liquefiers will play a major role within the hydrogen supply chain, production capacity will have to increase by a multiple of today’s typical sizes. The main goal is to reduce the total cost of ownership for these plants by increasing energy efficiency with innovative and simple process designs, optimized in capital expenditure. New concepts must ensure a manageable plant complexity and flexible operability. In the phase of process development and selection, a dimensioning of key equipment for large scale liquefiers, such as turbines and compressors as well as heat exchangers, must be performed iteratively to ensure technological feasibility and maturity. Further critical aspects related to hydrogen liquefaction, e.g. fluid properties, ortho-para hydrogen conversion, and coldbox configuration, must be analysed in detail. This paper provides an overview on the approach, challenges and preliminary results in the development of efficient as well as economically viable concepts for large-scale hydrogen liquefaction.

  2. FY 1980 Report on results of research and development project, recommissioned by Sunshine Project. Development of direct hydrogenation type coal liquefaction plant (Development of power recovery system by hydrohoist); 1980 nendo chokusetsu suiten ekika plant no kaihatsu seika hokokusho. Hydrohoist ni yoru doryoku kaishu system no kaihatsu

    NONE

    1981-03-01

    The R and D program was implemented for a hydrohoist system, with the objectives to reduce wear and power requirements in the direct hydrogenation type coal liquefaction plant. Direct hydrogenation, operating at elevated pressure in the presence of catalyst, is suitable for liquefaction of coal to produce light liquid products, which are in great demand. However, there are many mechanical problems to be solved, because the plant is operated under very severe conditions. The proposed hydrohoist system combines supply of the feed slurry with the let-down step for the slurry effluent as the product of the high-pressure system, to save energy by recovering power from the effluent slurry and, at the same time, reduce wear of the pumps and let-down valves, for the direct hydrogenation plant operating at 150 to 300 kg/cm{sup 2} in the presence of catalyst to liquefy coal. Such a system has been already commercialized for transferring coal and other minerals. In the FY 1980, basic tests are conducted using a small autoclave, to extract the problematical points for the test system. The results serve as the bases for designs and construction of the basic test system by which the hydrohoist system is to be studied and evaluated. (NEDO)

  3. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Survey of Australian industrial capability and construction capability relative to Australian brown coal liquefaction plant construction project; 1981 nendo Goshu kattan ekika plant no kensetsu ni kakawaru kogyoryoku, kensetsu kojiryoku ni kansuru chosa seika hokokusho

    NONE

    1982-03-01

    The industrial capability and construction capability of Australia are surveyed in relation with the project of constructing a brown coal liquefaction plant there. Australian heavy industry is conspicuously advanced in the field of mining machinery involving coal, iron ore, and other mineral resources. On the other hand, in the fields of general-purpose machinery for plants and of civil engineering machinery, it is behind other countries in terms of technology and cost because of the small market. When an industrial project is implemented in Australia, consulting firms, engineering contractors, etc., operate independently from each other, and the project is propelled forward under a perfect specialization system. Labor-related problems in the civil engineering and construction industry are the recruitment of laborers which is difficult and the delay in and suspension of construction due to labor disputes that take place very frequently. In Victoria State where a brown coal liquefaction plant is under construction, the availability of laborers specializing in construction is rather higher than in other states, and there is no important problem in this respect. One cannot be too prudent in Victoria State, however, since it includes a region which is the most notorious in Australia in terms of labor-management dispute. (NEDO)

  4. Liquefaction resistance of calcareous sands

    Sandoval Vallejo, Eimar

    2012-01-01

    Calcareous sands are unique in terms of their origin, mineralogy, shape, fragility and intra particle porosity. This article presents results from an experimental program carried out to study the liquefaction resistance of a calcareous sand retrieved from Cabo Rojo at Puerto Rico. The experimental program included mineralogical characterization, index properties, and undrained cyclic triaxial tests on isotropically consolidated reconstituted samples. Due to the large variation in the calcareous sand properties, results are compared with previous researches carried out on other calcareous sands around the world. Results showed a wide range in the liquefaction resistance of the studied calcareous sands. Cabo Rojo sand experienced greater liquefaction resistance than most of the calcareous sands used for comparison. Important differences in the excess pore pressure generation characteristics were also found.

  5. Thermal-hydraulic optimization of flexible transfer lines for liquid helium; Thermohydraulische Optimierung flexibler Transferleitungen fuer Fluessighelium

    Dittmar, Nico; Haberstroh, Christoph; Hesse, U. [Technische Univ. Dresden (Germany). Bitzer-Stiftungsprofessur fuer Kaelte-, Kryo- und Kompressorentechnik; Wolfram, M.; Krzyzowski, M.; Raccanelli, A. [CryoVac Gesellschaft fuer Tieftemperaturtechnik mbH und Co. KG, Troisdorf (Germany)

    2014-07-01

    Cooling systems and applications at very low temperatures are based on the use of liquid helium as cryogenic agent; the normal boiling temperature of helium-4 is 4.2 K. Due to the restricted economic production possibilities and the high energetic expenditure for helium liquefaction an efficient and sustainable handling with the resources is recommended. In university facilities the liquid helium is usually stored in containers and filled into smaller containers for transport using cryogenic transfer lines. This procedure can cause 20% loss by evaporation due to heat input and friction pressure losses. The gaseous helium has to be collected for re-liquefaction. The contribution shows that using systematic measurements an increase of the transfer rate and the efficiency of the helium filling system can be reached by a modified transfer line design.

  6. Helium Inventory Management For LHC Cryogenics

    Pyarali, Maisam

    2017-01-01

    The LHC is a 26.7 km circumference ring lined with superconducting magnets that operate at 1.9 K. These magnets are used to control the trajectory of beams of protons traveling in opposite directions and collide them at various experimental sites across the LHC where their debris is analyzed. The focus of this paper is the cryogenic system that allows the magnets to operate in their superconducting states. It aims to highlight the operating principles of helium refrigeration and liquefaction, with and without nitrogen pre-cooling; discuss the various refrigerators and liquefiers used at CERN for both LHC and Non-LHC applications, with their liquefaction capacities and purposes; and finally to deliberate the management of the LHC inventory and how it contributes to the strategic decision CERN makes regarding the inventory management during the Year-End Technical Stop (YETS), Extended Year-End Technical Stop (EYETS) and long shutdowns.

  7. Fiscal 1991 report. Coal liquefaction committee; 1991 nendo sekitan ekika iinkai hokokusho

    NONE

    1992-03-01

    The committee in this fiscal year had the 1st meeting in July 1991, the 2nd in August 1991, and the 3rd in March 1992, when fiscal 1990 research and development results, fiscal 1991 research and development programs, fiscal 1991 research and development results, etc., were reported and deliberated. At the 2nd meeting, the meaning of coal liquefaction technology development and how to go ahead with the task were described, which topic for discussion was entitled 'How coal liquefaction technology should be for the 21st century.' After discussion, it was agreed upon that a coal liquefaction technology package be completed in fiscal 2000 based on the absorption of each other's findings and on the utilization of basic studies common to both to be realized through the exchange of technologies between the brown coal liquefaction project and the bituminous coal liquefaction project. Under the brown coal liquefaction project, a 50 ton/day pilot plant was built and operated in Victoria, Australia, and the operation was completed in October 1990. The results of research and development under the coal brown liquefaction project will be compiled by fiscal 1993. (NEDO)

  8. Survey on development of brown coal liquefaction techniques; Kattan ekika gijutsu ni kansuru chosa

    NONE

    1980-09-01

    Described herein are results of literature survey on brown coal liquefaction reactions and elementary techniques. Liquefaction of brown coal in the presence of CO and steam, or CO, H{sub 2} and steam has been investigated. It is not clear by the literature survey whether it is superior to the normal process which uses hydrogen. Brown coal contains moisture at high contents, and the drying techniques are necessary to be developed for its liquefaction. The future coal liquefaction plant will be much larger than the past one, and there are a number of problems to be solved, such as those involved in the designs of large-sized high-pressure slurry pumps, heat exchangers and preheaters. It is also necessary to develop the materials of and production techniques for large reactors which are serviceable under severe conditions. The solid-liquid separation for liquefaction products involves a number of the elementary techniques characteristic of coal liquefaction processes, and needs many technological developments. The one-stage brown coal liquefaction process is compared with the two-stage process for the secondary hydrogenation of SCR, but no clear conclusions are reached. (NEDO)

  9. Outline of research achievement of fiscal 1983. Development of coal liquefaction technologies; Sekitan ekika gijutsu kaihatsu. 1983 nendo kenkyu seika no gaiyo

    NONE

    1983-07-01

    Reported are the results of (1) the development of bituminous coal liquefaction technology, (2) development of brown coal liquefaction technology, (3) experimental fabrication and development of plant equipment and materials therefor, and (4) a survey on coal type selection. The goals of the development are mentioned below. Under Item (1), an optimum liquefaction process and a solid/liquid separation process are to be defined, the effect of iron-based catalysts upon liquefaction reaction is to be elucidated, a technology for constructing a direct hydroliquefaction unit is to be established, and a plant using such a unit is to be developed. Under Item (2), an optimum liquefaction technology is to be established, high in economic efficiency and reliability, by subjecting Australia's Victoria brown coal to the direct liquefaction process. In particular, a new brown coal liquefaction technology is to be established, which will be an organic combination of a novel, raw brown coal slurry dehydration technology, a solvent deashing technology, and the secondary hydrogenation technology, all centering on the basic technology of primary hydrogenation. Under Item (3), reactor materials, accessory materials, slurry pumps, etc., are to be experimentally manufactured and developed further. Under Item (4), data are to be collected on coal resources, coal quality, liquefaction characteristics, etc., during the process of technology development for liquefaction, etc. Furthermore, methods are to be established for the effective utilization of liquefaction products and for their optimum refining. (NEDO)

  10. EARTHQUAKE INDUCED LIQUEFACTION ANALYSIS OF

    liquefaction analysis of Tendaho earth-fill dam, which is part ... sugar cane plantation in an area of 60,000 hectares. The project .... The model is prepared using the QUAKE/W program for the ..... Geo-slope International, Ltd., Canada. Dynamic ...

  11. Report on results of R and D of coal liquefaction technology under Sunshine Project in fiscal 1981 (development of motive force recovery system by hydrohoist); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, chokusetsu suiten ekika plant no kaihatsu seika hokokusho. Hydrohoist ni yoru doryoku kaishu system no kaihatsu

    NONE

    1982-03-01

    This paper explains the results of development of a hydrohoist system in a direct hydro-liquefaction plant under the Sunshine Project in fiscal 1981. Coal liquefaction deals with three phases of gas, liquid and solid at high pressures of 100-300 kg/cm{sup 2}. Slurry consisting of coal, catalyst and solvent is once fed into a supply chamber by a low pressure slurry pump. A high pressure slurry formed in a liquefaction reactor, after the separation of gaseous object, is boosted by a booster pump and force-fitted into the supply chamber from the above, discharging the slurry in the chamber to the high pressure reactor side. Since the high pressure product is used as the driving liquid, a force-feeding motive force can be greatly curtailed. It is a motive force recovery type hydrohoist. The product slurry in the supply chamber is discharged from a valve in the upper part; with the inner pressure going down quickly, the discharge valve wears very little. The basic experimental equipment was manufactured in fiscal 1980, with a test research conducted using the improved main equipment in fiscal 1981, and with the conceptual design of the hydrohoist also implemented on the assumption that it was applied to a pilot plant. (NEDO)

  12. Report for fiscal 1994 by subcommittee on coal liquefaction basic technology; 1994 nendo ekika kiban gijutsu bukai hokokusho

    NONE

    1995-03-01

    This report covers the proceedings of subcommittee meetings. Using PDUs (process development unit), comparison is made between bituminous coal-derived oils (150t/d plant for the Indonesian coal) and brown coal-derived oils (50t/d plant for the Yallourn coal), product quality is improved by a 2-stage refining process, engines are tested, etc., all these demonstration and research efforts intended to win social recognition for coal liquefaction products. Among basic studies, there are the development of technologies for reforming coal-derived oils and for mixing them will petroleum, development of new catalysts for reforming, development of a technology for separating heterocompounds and the like, and the development of their applications. Furthermore, technologies are developed for environmentally friendly coal liquefaction, feasibility of coal liquefaction technology internationalization is deliberated, and technical researches and joint researches are conducted. At the second meeting of the subcommittee, achievements relative to the refining and applications of liquefaction products are presented, including the hydrorefining of naphtha, heating oil, and light oil; development of new catalysts; heterocompound separation technology; and the development of new applications. In relation with the development of environmentally friendly coal liquefaction technologies, studies are presented on liquefaction conditions and on the upgrading of basic technologies of liquefaction. Also referred to are the reports delivered at a meeting on liquefaction catalysts (January 1995). (NEDO)

  13. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981 for development of a solvent extraction and liquefaction technology. Development of a brown coal based solvent extraction plant (Research on a primary hydrogenation technology, research on a deliming technology, research on a secondary hydrogenation technology, research on a dehydrogenation technology, and research on liquefaction from catalytic aspect); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu seika hokokusho. Yozai chushutsu ekika gijutsu no kaihatsu (kattankei yozai chushutsu plant no kaihatsu (ichiji suiten gijutsu no kenkyu, dakkai gijutsu no kenkyu, niji suiten gijutsu no kenkyu, shokubaimen kara no ekika kenkyu))

    NONE

    1982-03-01

    This paper describes the achievements in development of brown coal based solvent extraction in the Sunshine Project in fiscal 1981. Element researches were performed to complement and support the development of a liquefaction technology for brown coal produced in Victoria, Australia by using a 50-T/D pilot plant. For the primary hydrogenation technology, a manufacturing experiment was completed by means of nine cycles using a brown coal balancing solvent in a 0.1-t/day bench scale test. Distribution of the formed materials, the solvent properties, and the SRC properties have become nearly constant after 5 to 6 cycles. A test using a batch type device was performed to derive the relationship among dissolution parameters, SRC recovery rates, and deliming rates by using different solvents. For the secondary hydrogenation technology, SRC being the heavy fraction in a primary hydrogenation system (+420 degrees C) was hydrogenated by using an Ni{center_dot}Mo based catalyst at 360 degrees C and 250 kg/cm{sup 2}. A prospect was attained that the processing is possible by using a fixed bed reactor. A test using a small continuous dehydration testing device was carried out by using creosote oil as the solvent and by varying the evaporator operating conditions. Dehydration rate of 90 to 95% was obtained. Discussions were given on selecting catalysts for the secondary hydrogenation of the fixed bed method, and on factors of activity deterioration. A secondary hydrogenation test reactor of the suspended bed method was completed. (NEDO)

  14. Report on results of R and D of coal liquefaction technology in fiscal 1981; 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu seika setsumeisho

    NONE

    1982-03-01

    This paper explains the results of development of coal liquefaction technology under the Sunshine Project in fiscal 1981. In connection with solvent extraction and liquefaction, an 1 t/day experimental plant was completed for bituminous coals and operated continuously for 153 hours. An examination also started for the development of a 250 t/day pilot plant. As the element studies, R and D is in progress on the solvent extraction and liquefaction process, solid-liquid separation, secondary hydrogenation, and plant materials. In brown coals, the construction work of a 50 t/day pilot plant started for the purpose of establishing liquefaction technology for brown coal in Victoria State, Australia, with a part of the equipment manufactured. As the element studies, research was conducted on primary hydrogenation, deliming, secondary hydrogenation, dehydration and catalysts. In solvolysis liquefaction, a short-time concluding liquefaction reaction was continuously performed by a plant of 1 t/day scale. In direct hydro-liquefaction, a 2.4 t/day experimental plant was constructed, with the element studies conducted successively. In other words, researches were carried out by the bench scale plant on liquefaction, solid-liquid separation, iron-based catalysts, catalyst and reutilization, motive force recovery system by hydrohoist, and effect of preheating and deaeration. (NEDO)

  15. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Research and development of materials for coal liquefaction plant (Research on materials); 1981 nendo sekitan ekika plant zairyo no kenkyu kaihatsu (zairyo no kenkyu) seika hokokusho

    NONE

    1982-03-01

    Research and development is started of materials for constituting a liquefaction reactor which is the primary apparatus in the coal liquefaction process. Tested in the basic research on the designing of alloys for the reactor are Cr-Mo-V-Ti based alloys prepared by adding V, Ti, and B to Cr-Mo based alloys presently in use as materials for pressure vessels. They are melted and 50kg test ingots of steel are prepared, and an alloy with a constitution of Low Si-3%Cr-1%Mo-0.25%V-0.02%Ti-0.002%B is selected. In the designing of alloys to serve as stainless steel overlay welding materials and in the development of basic welding technologies, studies are conducted in search for materials that exhibit excellent durability under the conditions of liquefaction reaction and for technologies in this connection. These are accomplished using a test device installed this fiscal year, which is capable of reproducing high-temperature high-pressure hydrogen atmosphere. As the result, basic technologies are acquired, which will enable the achievement of the goal. In the study of on-site production technologies using medium-size ingots as the materials, an 85-ton medium size steel ingot of a new chemical constitution of Low Si-3Cr-1Mo-1/4V-Ti-B is melted, and a shell which is 400mm in thickness and 2m in internal diameter is forged, and the shell is subjected to a property and performance qualification test. (NEDO)

  16. Hydrogen Transfer during Liquefaction of Elbistan Lignite to Biomass; Total Reaction Transformation Approach

    Koyunoglu, Cemil; Karaca, Hüseyin

    2017-12-01

    structure involved in the recycling through the liquefaction plant if it is being installed. As a result of this study, results obtained from oil + gas data shows that when distilled water is used instead of tetraline during liquefaction of EL combined with manure, abundant crude hydrogen transfer takes place not because of using distilled water as a solvent but only with manure considered as a hydrogen sources. Furthermore, while adding manure into coal of liquefaction is also an alternative for current oil production.

  17. Advances in Seabed Liquefaction and its Implications for Marine Structures

    Sumer, B. Mutlu

    2013-01-01

    A review is presented of recent advances in seabed liquefaction and its implications for marine structures. The review is organized in seven sections: Residual liquefaction, including the sequence of liquefaction, mathematical modelling, centrifuge modelling and comparison with standard wave-flum......-flume results; Momentary liquefaction; Floatation of buried pipelines; Sinking of pipelines and marine objects; Liquefaction at gravity structures; Stability of rock berms in liquefied soils; and Impact of seismic-induced liquefaction....

  18. Coal liquefaction still a dream

    Overberg, H

    1982-03-19

    Liquefaction of coal is not profitable in West Germany and will not be so far some time to coal. This is true for West German and imported coal. The result may be improved but not changed by combined conversion of coal and top residues of distilleries. These are the main statements of a study carried out by Messrs. Veba Oel AG, Gelsenkirchen, on behalf of the Federal Minister for Research and Technology. The results of the study are presented in 20 volumes.

  19. Helium crystals

    Lipson, S.G.

    1987-01-01

    Hexagonal close-packed helium crystals in equilibrium with superfluid have been found to be one of the few systems in which an anisotropic solid comes into true thermodynamic equilibrium with its melt. The discovery of roughening transitions at the liquid-solid interface have shown this system to be ideal for the study of the statistical mechanics of interface structures. We describe the effect of roughening on the shape and growth of macroscopic crystals from both the theoretical and experimental points of view. (author)

  20. Commissioning and Operational Experience with 1 kW Class Helium Refrigerator/Liquefier for SST-1

    Dhard, C. P.; Sarkar, B.; Misra, Ruchi; Sahu, A. K.; Tanna, V. L.; Tank, J.; Panchal, P.; Patel, J. C.; Phadke, G. D.; Saxena, Y. C.

    2004-06-01

    The helium refrigerator/liquefier (R/L) for the Steady State Super conducting Tokamak (SST-1) has been developed with very stringent specifications for the different operational modes. The total refrigeration capacity is 650 W at 4.5 K and liquefaction capacity of 200 l/h. A cold circulation pump is used for the forced flow cooling of 300 g/s supercritical helium (SHe) for the magnet system (SCMS). The R/L has been designed also to absorb a 200 W transient heat load of the SCMS. The plant consists of a compressor station, oil removal system, on-line purifier, Main Control Dewar (MCD) with associated heat exchangers, cold circulation pump and warm gas management system. An Integrated Flow Control and Distribution System (IFDCS) has been designed, fabricated and installed for distribution of SHe in the toroidal and poloidal field coils as well as liquid helium for cooling of 10 pairs of current leads. A SCADA based control system has been designed using PLC for R/L as well as IFDCS. The R/L has been commissioned and required parameters were achieved confirming to the process. All the test results and commissioning experiences are discussed in this paper.

  1. Japan`s New Sunshine Project. 1996 Annual Summary of Coal Liquefaction and Gasification; 1996 nendo new sunshine keikaku seika hokokusho gaiyoshu. Sekitan no ekika gasuka

    NONE

    1997-11-01

    In reference to the results of the research and development under the fiscal 1996 New Sunshine Project, a report was summed up on coal liquefaction and coal gasification. As to the R and D of coal liquefaction technology, researches were conducted on liquefaction characteristics and engineering properties by coal kind, catalysts for coal liquefaction, liquefaction reaction of coal and reformation utilization of the liquefied products, liquefaction reaction mechanism and coking mechanism, solubility of coal in solvent and catalytic reaction mechanism, solvent reaction mechanism by hydrogen donor solvent, etc. Concerning the R and D of coal gasification technology, made were the basic study of eco-technology adaptable gasification technology and the study of coal gasification enhancing technology. Further, as to the development of bituminous coal liquefaction technology, carried out were the study in pilot plants and the support study of pilot plants. Additionally, R and D were done of the basic technology of coal liquefaction such as upgrading technology and environmentally acceptable coal liquefaction technology, and of coal hydrogasification technology. 3 refs., 81 figs., 25 tabs.

  2. Liquefaction macrophenomena in the great Wenchuan earthquake

    Chen, Longwei; Yuan, Xiaoming; Cao, Zhenzhong; Hou, Longqing; Sun, Rui; Dong, Lin; Wang, Weiming; Meng, Fanchao; Chen, Hongjuan

    2009-06-01

    On May 12, 2008 at 14:28, a catastrophic magnitude M s 8.0 earthquake struck the Sichuan Province of China. The epicenter was located at Wenchuan (31.00°N, 103.40°E). Liquefaction macrophenomena and corresponding destruction was observed throughout a vast area of 500 km long and 200 km wide following the earthquake. This paper illustrates the geographic distribution of the liquefaction and the relationship between liquefaction behavior and seismic intensity, and summarizes the liquefaction macrophenomena, including sandboils and waterspouts, ground subsidence, ground fissures etc., and relevant liquefaction features. A brief summary of the structural damage caused by liquefaction is presented and discussed. Based on comparisons with liquefaction phenomena observed in the 1976 Tangshan and 1975 Haicheng earthquakes, preliminary analyses were performed, which revealed some new features of liquefaction behavior and associated issues arising from this event. The site investigation indicated that the spatial non-uniformity of liquefaction distribution was obvious and most of the liquefied sites were located in regions of seismic intensity VIII. However, liquefaction phenomena at ten different sites in regions of seismic intensity VI were also observed for the first time in China mainland. Sandboils and waterspouts ranged from centimeters to tens of meters, with most between 1 m to 3 m. Dramatically high water/sand ejections, e.g., more than 10 m, were observed at four different sites. The sand ejections included silty sand, fine sand, medium sand, course sand and gravel, but the ejected sand amount was less than that in the 1976 Tangshan earthquake. Possible liquefaction of natural gravel soils was observed for the first time in China mainland.

  3. Japan`s New Sunshine Project. 20. 1995 annual summary of coal liquefaction and gasification

    NONE

    1996-10-01

    The paper described a summary of the 1995 study on coal liquefaction and gasification under the New Sunshine Project. As for coal liquefaction, a study was made of liquefaction characteristics and catalysts of various coals. Also studied were liquefaction conditions for quality improvement of liquefaction products, an evaluation method of quality of coal liquid, and a utilization method of coal liquid. In order to prevent carbonization and realize effective liquefaction, a study was conducted for elucidation of the reaction mechanism of high pressure hydrogenation. In a 150t/d pilot plant using hydrogen transfer hydrogenation solvents, the NEDOL method was studied using various catalysts and kinds of coals. This is a step prior to data acquisition for engineering, actual construction of equipment and operation. A 1t/d process supporting unit is a unit to support it. The unit conducts studies on slurry letdown valves and synthetic iron sulfide catalysts, screening of Chinese coals, etc. As to coal gasification, the paper added to the basic research the combined cycle power generation using entrained flow coal gasification for improvement of thermal efficiency and environmental acceptability and the HYCOL method for hydrogen production. 68 refs., 40 figs.

  4. Thermodynamic design of natural gas liquefaction cycles for offshore application

    Chang, Ho-Myung; Lim, Hye Su; Choe, Kun Hyung

    2014-09-01

    A thermodynamic study is carried out for natural gas liquefaction cycles applicable to offshore floating plants, as partial efforts of an ongoing governmental project in Korea. For offshore liquefaction, the most suitable cycle may be different from the on-land LNG processes under operation, because compactness and simple operation are important as well as thermodynamic efficiency. As a turbine-based cycle, closed Claude cycle is proposed to use NG (natural gas) itself as refrigerant. The optimal condition for NG Claude cycle is determined with a process simulator (Aspen HYSYS), and the results are compared with fully-developed C3-MR (propane pre-cooled mixed refrigerant) JT cycles and various N2 (nitrogen) Brayton cycles in terms of efficiency and compactness. The newly proposed NG Claude cycle could be a good candidate for offshore LNG processes.

  5. Achievement report on developing coal liquefaction technologies in fiscal 1998 - edition B. Development of bituminous coal liquefaction technology (studies by using pilot plant) 1/2; 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho B. 1/2. Rekiseitan ekika gijutsu no kaihatsu (pilot plant ni yoru kenkyu)

    NONE

    1999-03-01

    With an objective to improve the environment by substituting petroleum energy by coal, and by reducing emission of SOx and NOx, research and development has been performed on coal liquefaction technologies. This paper summarizes the achievements thereof in fiscal 1998. In the operation study RUN-5, the operation was carried out by using the Tanito Harum coal of Indonesia, and raising the slurry concentration to 50% by weight. The operation stability when the high concentration slurry was used was verified, and the liquefying reaction column fluidity property data, and the material balance and heat balance data were acquired by using the NAT method. In the RUN-6 and 7, for the purpose of verifying the applicability of the NEDOL process to the wide range of coal types as the process feature, the Adaro coal of Indonesia and the Ikejima coal of Japan were used, and the operation at high slurry concentration was performed at 80% load and under the standard NEDOL conditions. The operation stability when the upper and lower limit coals was used was verified, and the operability at high slurry concentration was identified. At the same time, the liquefying reaction column fluidity property data, and the material balance and heat balance data were acquired. The development targets established by the Industrial Technology Council have all been achieved. (NEDO)

  6. Report on the achievements in research and development of a coal liquefaction technology in the Sunshine Project in fiscal 1981. Development of a solvolysis liquefaction plant (research on realization of solvolysis pitch hydrogenation equipment); Sekitan ekika gijutsu no kenkyu kaihatsu, solvolysis ekika plant no kaihatsu seika hokokusho. Solvolysis pitch no suiten sochika kenkyu

    NONE

    1982-03-01

    Among researches on solvolysis coal liquefaction technologies in the Sunshine Project in fiscal 1981, this paper describes the research on realization of solvolysis pitch hydrogenation equipment. In realizing a hydrogenation and decomposition reacting equipment for the second stage reaction process, it is important to stabilize operation by preventing coking and catalytic deterioration in elevated temperature zones. Therefore, a reactor of catalytic fluid system was assumed. Fiscal 1981 has fabricated and experimented a flow testing equipment for the purpose of acquiring data for realization of the equipment. A reactor that can deal with temperatures higher than 400 degrees C was installed in a 0.1-t/d continuously operating equipment. For selecting adequate operating conditions, an operation manual was prepared from the results of the cold model test and the fundamental test on hydrogenation and decomposition. The devices used were verified to have good operability. As the gasification rate increases when the reaction temperature is raised, resulting in reduced oil yield, it is necessary to keep the temperature lower than 430 degrees C. Increased pressure does not increase the oil yield as much as it increases hydrogen consumption, hence pressure of 200 kg/cm{sup 2} or lower is suitable. The secondary hydrogenation solvent requires no proton donation performance, and light fraction should be preferable. Catalysts were also discussed, and a clue to improvements was obtained. (NEDO)

  7. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Biddy, M.; Davis, R.; Jones, S.

    2013-03-01

    This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  8. Wave liquefaction in soils with clay content

    Kirca, Özgür; Sumer, B. Mutlu; Fredsøe, Jørgen

    2012-01-01

    The paper presents the results of an experimental study of the influence of clay content (in silt-clay and sand-clay mixtures) on liquefaction beneath progressive waves. The experiments showed that the influence of clay content is very significant. Susceptibility of silt to liquefaction is increa...

  9. Report on the FY 1998 results of the New Sunshine Project (B version). Development of coal liquefaction technology (Development of base technology of liquefaction (Project on internationalization of coal liquefaction technology)); 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Ekika kiban gijutsu no kaihatsu (sekitan ekika gijutsu no kokusaika jigyo)

    NONE

    1999-03-01

    In 1994, a memorandum on the research cooperation was agreed between NEDO and BPPT (The Agency for the Assessment and Application Technology) in Indonesia, based on the request for the coal liquefaction technology cooperation from BPPT. It includes the following items: conference for professionals to be held, invitation and training of Indonesian engineers, activity for joint field survey and potential survey of location of coal liquefaction commercial plant. Further in 1997, the secondary memorandum was concluded for the potential survey for securing the hydrogen required for coal liquefaction by coal gasification. The survey was summarized as the potential survey for location of coal liquefaction. In the testing study for improving economical efficiency of liquefaction process, it was made clear that the higher the Fe content of Banko coal is, the higher the reaction of liquefaction is, and that Fe compounds in coal show catalysis. In the Soroako area in Sulawesi island, there are the nickel mine run by PT. Inco. Soroako limonite is promising as catalyst material for commercial-scale coal liquefaction. In the gasification method, the plant construction cost increases, but the production amount of coal-derived liquid can be increased. That is more profitable than the production of hydrogen from natural gas. (NEDO)

  10. Coal liquefaction with preasphaltene recycle

    Weimer, Robert F.; Miller, Robert N.

    1986-01-01

    A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

  11. Reducing capital and operating costs in gas processing, liquefaction, and storage

    Krusen, III, L C [Phillips Petroleum Co., Bartlesville, OK (United States). Research Div.

    1997-06-01

    The LNG industry is unanimous that capital costs must be reduced throughout the chain, and especially at the liquefaction facility including associated gas processing and LNG storage. The Ken ai LNG plant provides an example of how both reduced capital and operating costs were attained. This paper will cover cost production strategies that can be applied to liquefaction processes in general, and will than focus on their realization in the Phillips Optimized Cascade LNG process. The paper concludes that reduced LNG plant costs are attainable. (Author).

  12. Reducing capital and operating costs in gas processing, liquefaction, and storage

    Krusen, L.C. III

    1997-01-01

    The LNG industry is unanimous that capital costs must be reduced throughout the chain, and especially at the liquefaction facility including associated gas processing and LNG storage. The Ken ai LNG plant provides an example of how both reduced capital and operating costs were attained. This paper will cover cost production strategies that can be applied to liquefaction processes in general, and will than focus on their realization in the Phillips Optimized Cascade LNG process. The paper concludes that reduced LNG plant costs are attainable. (Author)

  13. Ultralow temperature helium compressor for Japan Atomic Energy Research Institute

    Asakura, Hiroshi

    1988-01-01

    Ishikawajima Harima Heavy Industries Co., Ltd. started the development of an ultralow temperature helium compressor for helium liquefaction in 1984 jointly with Japan Atomic Energy Research Institute, and has delivered the first practical machine to the Superconductive Magnet Laboratory of JAERI. For a large superconductive magnet to be used in the stable state for a fusion reactor, conventional superconductive materials (NbTi, NbTi 3 Sn, etc.) must be used, being cooled forcibly with supercritical helium. The supercritical helium which is compressed above the critical pressure of 228 kPa has a stable cooling effect since the thermal conductivity does not change due to the evaporation of liquid helium. In order to maintain the temperature of the supercritical helium below 4 K before it enters a magnet, a heat exchanger is used. The compressor that IHI has developed has the ability to reduce the vapor pressure of liquid helium from atmospheric pressure to 50.7 kPa, and can attain the temperature of 3.5 K. The specification of this single stage centrifugal compressor is: mass flow rate 25 - 64 g/s, speed 80,000 rpm, adiabatic efficiency 62 - 69 %. The structure and the performance are reported. (K.I.)

  14. Fiscal 1994 achievement report 1/2. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1994 nendo seika hokokusho 1/2. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    NONE

    1995-03-01

    The operation of a 1t/d PSU (process support unit) was studied in the NEDOL coal liquefaction process. Modification was made, which involved the installation of a high-temperature/high-pressure sampling device for observing reaction and fluidity in the liquefaction reactor, a differential pressure measuring device, and a neutron attenuation-aided measuring device. Relative to coal injection, a 49.5-day and 49.3-day slurry injections were carried out using Tanito Harum coal, when impacts on the product yield and the operability of the unit were examined. A verification test was conducted for an improved hydrogenation catalyst, and liquefaction reactor characteristics were investigated. During a 19-day operation for the study of maintenance, newly installed equipment and devices were verified for function, and operating methods were probed into. In the survey of environments, characteristics were examined of the wastewater discharged from the Tanito Harum coal liquefaction process, and wastewater treatment methods were studied. The air, odor, and tar mist were examined with the PSU in operation, and the measured values were found to be below the management limits showing that its operation did not pose any problems relating to working environments. (NEDO)

  15. Earthquake-induced liquefaction in Ferland, Quebec

    Tuttle, M.; Seeber, L.

    1991-02-01

    Detailed geological investigations are under way at a number of liquefaction sites in the Ferland-Boilleau valley, Quebec, where sand boils, ground cracks and liquefaction-related damages to homes were documented immediately following the Ms=6.0, Mblg=6.5 Saguenay earthquake of November 25, 1988. To date, results obtained from these subsurface investigations of sand boils at two sites in Ferland, located about 26 km from the epicentre, indicate that: the Saguenay earthquake induced liquefaction in late-Pleistocene and Holocene sediments which was recorded as sand dikes, sills and vents in near-surface sediments and soils; earthquake-induced liquefaction and ground failure have occurred in this area at least three times in the past 10,000 years; and, the size and morphology of liquefaction features and the liquefaction susceptibility of source layers of the features may be indicative of the intensity of ground shaking. These preliminary results are very promising and suggest that with continued research liquefaction features will become a useful tool in glaciated terrains, such as northeastern North America, for determining not only the timing and location but also the size of past earthquakes

  16. Fiscal 1991 report on the brown coal liquefaction section meeting; 1991 nendo kattan ekika bukai hokokusho

    NONE

    1992-03-01

    At the 1st through 5th brown coal liquefaction group meetings held for the fiscal year, reports are delivered and discussions are made about the progress of research and development. At the 1st meeting, a fiscal 1991 brown coal liquefaction research plan is introduced, and discussed. At the 2nd meeting, an interim report on the brown coal liquefaction technology development project is discussed. At the 3rd meeting (a joint meeting of the brown coal and bituminous coal liquefaction groups), an agendum entitled 'what the development of brown/bituminous coal liquefaction technologies for the 21st century should be' is reported, and discussed. At the 4th meeting, reports are made on the results of deliberation at the Industrial Technology Council, progress of the follow-up study, progress of the collection of achievements, and so forth. At the 5th meeting, the outline of the follow-up study, the collection of achievements in the pilot plant study (a project report preparation schedule and materials evaluation), the progress of pilot plant dismantling work, etc., are reported and discussed. (NEDO)

  17. Fiscal 1991 report on the brown coal liquefaction section meeting; 1991 nendo kattan ekika bukai hokokusho

    NONE

    1992-03-01

    At the 1st through 5th brown coal liquefaction group meetings held for the fiscal year, reports are delivered and discussions are made about the progress of research and development. At the 1st meeting, a fiscal 1991 brown coal liquefaction research plan is introduced, and discussed. At the 2nd meeting, an interim report on the brown coal liquefaction technology development project is discussed. At the 3rd meeting (a joint meeting of the brown coal and bituminous coal liquefaction groups), an agendum entitled 'what the development of brown/bituminous coal liquefaction technologies for the 21st century should be' is reported, and discussed. At the 4th meeting, reports are made on the results of deliberation at the Industrial Technology Council, progress of the follow-up study, progress of the collection of achievements, and so forth. At the 5th meeting, the outline of the follow-up study, the collection of achievements in the pilot plant study (a project report preparation schedule and materials evaluation), the progress of pilot plant dismantling work, etc., are reported and discussed. (NEDO)

  18. Helium refrigerator-liquefier system for MHD generator

    Akiyama, Y.; Ishii, H.; Mori, Y.; Yamamoto, M.; Wada, R.; Ando, M.

    1974-01-01

    MHD power generators have been investigated in the Electro-Technical Laboratory as one of the National Research and Development Programmes. A helium refrigerator-liquefier system has been developed to cool the superconducting magnet for a 1000 kW class MHD power generator. The turboexpander with low temperature gas bearings and an alternator had been developed for the MHD project at the Electro-Technical Laboratory previously. The liquefaction capacity is 250 iota/h and the refrigeration power is 2.9 kW at 20 K. The superconducting magnet is 50 tons and the cryostat has a liquid helium volume of 2700 iota. The evaporation rate is 60 to 80 iota/h. It takes, in all 2 to 3 weeks to fill the cryostat with liquid helium. (author)

  19. Combined Reverse-Brayton Joule Thompson Hydrogen Liquefaction Cycle

    Shimko, Martin A. [Gas Equipment Engineering Corporation, Milford, CT (United States); Dunn, Paul M. [Gas Equipment Engineering Corporation, Milford, CT (United States)

    2011-12-31

    The following is a compilation of Annual Progress Reports submitted to the DOE’s Fuel Cell Technologies Office by Gas Equipment Engineering Corp. for contract DE-FG36-05GO15021. The reports cover the project activities from August 2005 through June 2010. The purpose of this project is to produce a pilot-scale liquefaction plant that demonstrates GEECO’s ability to meet or exceed the efficiency targets set by the DOE. This plant will be used as a model to commercialize this technology for use in the distribution infrastructure of hydrogen fuel. It could also be applied to markets distributing hydrogen for industrial gas applications. Extensive modeling of plant performance will be used in the early part of the project to identify the liquefaction cycle architecture that optimizes the twin goals of increased efficiency and reduced cost. The major challenge of the project is to optimize/balance the performance (efficiency) of the plant against the cost of the plant so that the fully amortized cost of liquefying hydrogen meets the aggressive goals set by DOE. This project will design and build a small-scale pilot plant (several hundred kg/day) that will be both a hardware demonstration and a model for scaling to larger plant sizes (>50,000 kg/day). Though an effort will be made to use commercial or near-commercial components, key components that will need development for either a pilot- or full-scale plant will be identified. Prior to starting pilot plant fabrication, these components will be demonstrated at the appropriate scale to demonstrate sufficient performance for use in the pilot plant and the potential to achieve the performance used in modeling the full-scale plant.

  20. Liquefaction susceptibility of fine-grained soils: preliminary study report. Final report, September 1985-March 1986

    Chang, N.Y.

    1987-09-01

    Soil liquefaction, a hazardous ground failure induced by strong motion earthquakes, can cause catastrophic damage to structures such as dams, bridges, power plants, and water-front structures and may involve great losses of life. Examples of liquefaction and resulting damage were observed during the Alaska (1964), Niigata, Japan (1964), and Tangshan, China (1976), earthquakes. Ground failure due to earthquake-induced soil liquefaction may manifest itself as excessive settlement, loss of bearing capacity, sand boiling, and flow slides. The liquefaction potential of clean sands has been studied extensively for the last two decades. However, case histories revealed that liquefied sands were seldom clean. They may contain various percentages of silt or clay or both. In fact, the Chinese observation in the Tansghan earthquake indicated that some cohesive soils may have liquefied. If this indeed had happened, then structures underlain by fine-grained soils, with a marginal safety factor based on the liquefaction criteria normally applied to sands, may actually be unsafe. Thus there is an urgent need for establishing new criteria for the liquefaction susceptibility of soils to include those identified as fine-grained. The author, Professor N.Y. Chang of the University of Colorado at Denver, visited several Chinese agencies and and universities in and near Beijing, China, in the summer of 1985 in an attempt to investigate and verify reported data on the liquefaction of cohesive soils during the Tangshan earthquake of 1976 and to negotiate cooperative research into the problem. This report presents the result of supportive literature review and the findings of the China trip.

  1. Histotripsy Liquefaction of Large Hematomas.

    Khokhlova, Tatiana D; Monsky, Wayne L; Haider, Yasser A; Maxwell, Adam D; Wang, Yak-Nam; Matula, Thomas J

    2016-07-01

    Intra- and extra-muscular hematomas result from repetitive injury as well as sharp and blunt limb trauma. The clinical consequences can be serious, including debilitating pain and functional deficit. There are currently no short-term treatment options for large hematomas, only lengthy conservative treatment. The goal of this work was to evaluate the feasibility of a high intensity focused ultrasound (HIFU)-based technique, termed histotripsy, for rapid (within a clinically relevant timeframe of 15-20 min) liquefaction of large volume (up to 20 mL) extra-vascular hematomas for subsequent fine-needle aspiration. Experiments were performed using in vitro extravascular hematoma phantoms-fresh bovine blood poured into 50 mL molds and allowed to clot. The resulting phantoms were treated by boiling histotripsy (BH), cavitation histotripsy (CH) or a combination in a degassed water tank under ultrasound guidance. Two different transducers operating at 1 MHz and 1.5 MHz with f-number = 1 were used. The liquefied lysate was aspirated and analyzed by histology and sized in a Coulter Counter. The peak instantaneous power to achieve BH was lower than (at 1.5 MHz) or equal to (at 1 MHz) that which was required to initiate CH. Under the same exposure duration, BH-induced cavities were one and a half to two times larger than the CH-induced cavities, but the CH-induced cavities were more regularly shaped, facilitating easier aspiration. The lysates contained a small amount of debris larger than 70 μm, and 99% of particulates were smaller than 10 μm. A combination treatment of BH (for initial debulking) and CH (for liquefaction of small residual fragments) yielded 20 mL of lysate within 17.5 minutes of treatment and was found to be most optimal for liquefaction of large extravascular hematomas. Copyright © 2016 World Federation for Ultrasound in Medicine & Biology. Published by Elsevier Inc. All rights reserved.

  2. Assessment and mitigation of liquefaction

    Czelada, J. A.; Melentijevic, S.

    2014-01-01

    The simplified empirical procedure in its original form presented in Youd et al (2001) and some further developments given in Idriss and Boulanger (2006) for evaluating liquefaction resistance of soils is presented in this paper only for the criteria based on standard penetration test (SPT). Methods for estimating the ground improvement techniques by stone columns and dynamics compaction are presented. For stone columns Priebe method (1995) and homogenized method (equivalent parameters) are present. for dynamic compaction methods proposed by Recomendacion Geotecnica para las Obras Maritimas y/o Porturaria - ROM 0.5-05 (2005) and Nashed et al. (2009) are described. These analysis methods for each ground improvement technique are compared in two different case histories showing similar results in each one. (Author)

  3. Coal liquefaction process streams characterization and evaluation

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  4. Survey on peripheral techniques of brown coal liquefaction techniques; Kattan ekika gijutsu ni kansuru shuhen gijutsu no chosa

    NONE

    1980-09-01

    Described herein are results of survey on brown coal liquefaction techniques and peripheral techniques, centered by COSTEAM process under development in USA, solubilization by alcohol and liquefaction and cracking with the aid of tetrahydroquinoline as the hydrogen donor under development in Japan, and low-temperature carbonization and new promising techniques. The COSTEAM process shows higher reaction rates, conversions and oil yields for brown coal liquefaction than the one using hydrogen gas. Some of the problems involved in this process high viscosity and oxygenated compound content of the product oil. The product oil is acceptable as fuel for power generating plants and can be produced at a moderate cost, but may be unsuitable as vehicle fuel. Coal liquefaction and solubilization processes are mainly represented by those which use hydrogen. The hydrogen cost, which is high, determines the product price. The processes which use alcohol or tetrahydroquinoline are still in the experimental stage. (NEDO)

  5. Catalytic activity of pyrite for coal liquefaction reaction; Tennen pyrite no shokubai seino ni kansuru kento

    Hirano, K.; Kozu, M.; Okada, T.; Kobayashi, M. [Nippon Coal Oil Co. Ltd., Tokyo (Japan)

    1996-10-28

    Since natural pyrite is easy to obtain and cheap as coal liquefaction catalyst, it is to be used for the 150 t/d scale NEDOL process bituminous coal liquefaction pilot plant. NEDO and NCOL have investigated the improvement of catalytic activity of pulverized natural pyrite for enhancing performance and economy of the NEDOL process. In this study, coal liquefaction tests were conducted using natural pyrite catalyst pulverized by dry-type bowl mill under nitrogen atmosphere. Mechanism of catalytic reaction of the natural pyrite was discussed from relations between properties of the catalyst and liquefaction product. The natural pyrite provided an activity to transfer gaseous hydrogen into the liquefaction product. It was considered that pulverized pyrite promotes the hydrogenation reaction of asphaltene because pulverization increases its contact rate with reactant and the amount of active points on its surface. It was inferred that catalytic activity of pyrite is affected greatly by the chemical state of Fe and S on its surface. 3 refs., 4 figs., 1 tab.

  6. A study on the hydrotreating of coal hydro liquefaction residue and its kinetics

    Huang, J.; Lu, X.; Zhang, D.; Gao, J. [Department of Chemical Engineering for Energy Resources, East China University of Science and Technology, Shanghai (China)

    2010-09-15

    Hydro-conversion of coal hydro liquefaction residue obtained from a 6 t/day pilot plant of Shenhua Group in Shanghai was carried out under the hydrotreating condition. The coal hydro liquefaction residue and its product were extracted in sequence with n-hexane, toluene and tetrahydrofuran in a Soxhlet apparatus. The n-hexane soluble fractions increased with the increase of reaction temperature and time. Its amount increased from 14.14% to a maximum of 40.86% under the conditions of 470 {sup o}C and 30 min, which meant that moderate extension of coal residence time in the coal hydro liquefaction reactor is beneficial to the increase of oil yield. A 4-lumped kinetic model of coal hydro liquefaction residue hydro-conversion was performed using solubility-based lumped fractions. In the model, the tetrahydrofuran insoluble fractions were classified into two parts: easily reactive part and unreactive part. The kinetic parameters were estimated by a fourth-order Runge-Kutta method and a nonlinear least squares method, and the apparent activation energies were calculated according to the Arrhenius Equation. A large quantity of total catalyst consisting of remained liquefaction catalyst, part of the mineral from raw coal and additive Fe-based catalyst could considerably reduce the apparent activation energy of hydro-conversion for the toluene insoluble/tetrahydrofuran insoluble fractions to 36.79 kJ-mol{sup -1}. The calculated values of the model coincided well with the experimental values. (authors)

  7. Fiscal 1989 report. Coal liquefaction committee; 1989 nendo sekitan ekika iinkai hokokusho

    NONE

    1990-03-01

    The committee in this fiscal year had its 1st meeting in June 1989 and 2nd meeting in March 1990, when fiscal 1989 research and development programs and fiscal 1989 research and development results, etc., were reported and discussed. The operating status of the 1 ton/day PSU (process supporting unit) for bituminous coal liquefaction was reported and discussed. The report included its 1st operation for the demonstration of a long-term stable run under standard conditions that continued for trouble-free 50 days, the 2nd operation for the investigation of the effect of liquefaction reaction temperature in which the liquefaction yield recorded the maximum at 450 degrees C with the collection of coal oils of 55 wt.% on the average, and the 3rd operation for the investigation of the effects of liquefaction reaction pressure and catalyst injection size whose details were being analyzed. Reported in relation with the brown coal liquefaction pilot plant was a comprehensive operation of a series of 1st hydrogenation, solvent deashing, and 2nd hydrogenation processes completed after a continuous operation of 460 hours establishing a total operating time of 1050 hours. (NEDO)

  8. Characteristics of process oils from HTI coal/plastics co-liquefaction runs

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A. [and others

    1995-12-31

    The objective of this project is to provide timely analytical support to DOE`s liquefaction development effort. Specific objectives of the work reported here are presented. During a few operating periods of Run POC-2, HTI co-liquefied mixed plastics with coal, and tire rubber with coal. Although steady-state operation was not achieved during these brief tests periods, the results indicated that a liquefaction plant could operate with these waste materials as feedstocks. CONSOL analyzed 65 process stream samples from coal-only and coal/waste portions of the run. Some results obtained from characterization of samples from Run POC-2 coal/plastics operation are presented.

  9. Basic studies on coal liquefaction reaction, reforming and utilization of liquefaction products

    Shiraishi, M. (National Institute for Resources and Environment, Tsukuba (Japan))

    1993-09-01

    This report describes the achievement of research and development of coal liquefaction technologies in the Sunshine Project for FY 1992, regarding the coal liquefaction reaction, reforming and utilization of liquefaction products. For the fundamental study on coal liquefaction reaction, were investigated effect of asphaltene in petroleum residue on coprocessing, pretreatment effect in coprocessing of Taiheiyo coal and tarsand bitumen using oil soluble catalyst, solubilization and liquefaction of Taiheiyo coal at mild conditions with the aid of super acid, and flash hydropyrolysis of finely pulverized swollen coal under high hydrogen pressure. On the other hand, for the study on hydrotreatment of coal derived liquid, were investigated catalytic hydroprocessing of Wandoan coal liquids, production of gasoline from coal liquids by fluid catalytic cracking, solvent extraction of phenolic compounds from coal liquids, and separation of hetero compounds in coal liquid by means of high pressure crystallization. Further progress in these studies has been confirmed. 9 figs., 6 tabs.

  10. Liquid helium target

    Fujii, Y.; Kitami, T.; Torikoshi, M.

    1984-12-01

    A liquid helium target system has been built and used for the experiment on the reaction 4 He(γ, p). The target system has worked satisfactorily; the consumption rate of liquid helium is 360 ml/h and the cryogenic system retains liquid helium for about ten hours. The structure, operation and performance of the target system are reported. (author)

  11. Fiscal 1989 report on the bituminous coal liquefaction section meeting; 1989 nendo rekiseitan ekika bukai hokokusho

    NONE

    1990-03-01

    At the 1st, 2nd, and 3rd group meetings held for the fiscal year, reports are given and discussions are made about the progress of research and development. Reported and discussed in relation to the progress of the pilot plant support research are studies with the 1t/d PSU (process supporting unit) (Nippon Steel Corporation, Mitsui Coal Liquefaction Co., Ltd., and Japan Coal Oil Co., Ltd.); improvement on distillate distribution (Sumitomo Metal Industries, Ltd.); development of an optimum decalcification technique (Sumitomo Coal Mining Co., Ltd., and Sumitomo Metal Industries, Ltd.); studies of solvent hydrogenation catalysts (Sumitomo Metal Mining Co., Ltd., and Chiyoda Corp.); and studies of coal liquefaction conditions (Mitsui Engineering and Shipbuilding Co., Ltd.). In relation to studies using a bituminous coal liquefaction pilot plant, the progress of the 150t/d PP (pilot plant) effort (Japan Coal Oil, Co., Ltd.) and the outlines of pilot surveys (Japan Coal Oil Co., Ltd.) are reported and discussed, the latter covering liquefaction solvent performance optimization, slurry preheating furnaces, coal slurry properties, and so forth. (NEDO)

  12. Fiscal 1990 report on the bituminous coal liquefaction section meeting; 1990 nendo rekiseitan ekika bukai hokokusho

    NONE

    1991-03-01

    At the 1st, 2nd, and 3rd group meetings held for the fiscal year, reports are delivered and discussions are made concerning the progress of research and development activities. Reported and discussed in relation to the pilot plant support research, etc., are studies with the 1t/d PSU (process supporting unit) (Nippon Steel Corporation, Mitsui Coal Liquefaction Co., Ltd., and Japan Coal Oil Co., Ltd.); development of an optimum coal refining technique (Sumitomo Coal Mining Co., Ltd.); development of an optimum pretreatment technique and improvement on distillate distribution (Sumitomo Metal Industries, Ltd.); studies of coal liquefaction conditions (Mitsui Engineering and Shipbuilding Co., Ltd.); and studies of solvent hydrogenation catalysts (Sumitomo Metal Mining Co., Ltd., and Chiyoda Corp.). Reported and discussed in relation to researches using a bituminous coal liquefaction pilot plant are the progress of the 150t/d PP (pilot plant) effort (Japan Coal Oil Co., Ltd.) and the outlines of pilot surveys (Japan Coal Oil Co., Ltd.), the latter covering liquefaction solvent performance optimization, slurry pre-heating furnaces, coal slurry properties, and so forth. (NEDO)

  13. Fiscal 1993 report. Coal liquefaction committee; 1993 nendo sekitan ekika iinkai hokokusho

    NONE

    1994-03-01

    The committee in this fiscal year had the 1st meeting in July 1993, the 2nd in December 1993, and the 3rd in March 1994, when fiscal 1993 research and development programs and results were reported and discussed. Reported and discussed at the 2nd meeting were the compilation of brown coal liquefaction technology development project results, evaluation report on the same, hydrorefining of oil from brown coal and the research and development of application technologies for the same, and an environmental safety evaluation test on the same. In selecting a standard coal for the operation of the 150 ton/day pilot plant, PSU (process supporting unit)-aided studies were made on the analytical values presented by coals, yield of the liquid, yield of the liquefaction residue, yield of the generated gas, amount of the hydrogen consumed, coal oil properties, liquefaction residue properties, operationality, etc. On-site investigations were conducted also in Indonesia, and a conclusion was reached that Tanito Harum coal would be the most suitable for the pilot plant. Concerning the liquefaction catalyst for the pilot plant, a report was given on a comparison made between the activity of a synthetic iron sulfide and that of natural pyrite. (NEDO)

  14. Coal liquefaction and gas conversion: Proceedings. Volume 1

    1993-12-31

    Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  15. Development of continuous bench scale unit for direct liquefaction

    Yoon, Wang Lai [Korea Inst. of Energy and Resources, Daeduk (Korea, Republic of)

    1996-12-31

    Batch coal liquefaction experiments using tubing bombs and continuous experiments by cell liquefaction test facility were carried out. The main purpose was to maximize the coal liquefaction yields by improving the activity of coal dissolution catalysts which are oil soluble transition metal naphthenate and to supplement the incomplete research results. In the meantime, the study on the reaction characteristics of coal liquefaction and coal liquid upgrading catalyst upon sulfiding conditions and phosphorous addition have been conducted (author). 102 refs., 35 figs.

  16. Development of continuous bench scale unit for direct liquefaction

    Yoon, Wang Lai [Korea Inst. of Energy and Resources, Daeduk (Korea, Republic of)

    1995-12-31

    Batch coal liquefaction experiments using tubing bombs and continuous experiments by cell liquefaction test facility were carried out. The main purpose was to maximize the coal liquefaction yields by improving the activity of coal dissolution catalysts which are oil soluble transition metal naphthenate and to supplement the incomplete research results. In the meantime, the study on the reaction characteristics of coal liquefaction and coal liquid upgrading catalyst upon sulfiding conditions and phosphorous addition have been conducted (author). 102 refs., 35 figs.

  17. Studies on characteristics of fluid dynamics in the coal liquefaction reactor; Sekitan ekika hanno tonai no ryudo tokusei

    Sakawaki, K.; Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Mochizuki, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Tachikawa, N.; Moki, T.; Ishikawa, I. [Japan Atomic Energy Research Institute, Tokyo (Japan)

    1996-10-28

    To design the coal liquefaction reactor of large scale plant in future, it is important to understand characteristics of fluid dynamics within the coal liquefaction reactor. In this study, to measure the fluid dynamics of liquid phase within the coal liquefaction reactor operated under high temperature and high pressure coal liquefaction condition, neutron attenuating tracer (NAT) technique, one of the tracer test methods, was applied using 1 t/d coal treating PSU. The residence time of liquid phase within the reactor can be measured by utilizing property of neutron of being absorbed by materials. The tracer was injected at the inlets of first and third reactors, and the neutron was counted at each outlet. The concentration of tracer was derived from the discrete value, to determine the residence time distribution of liquid phase. The mean residence time of liquid phase in the single first reactor and in the total three reactors were prolonged under the severe operation conditions of liquefaction. The more severe the liquefaction operation condition was, the more active the mixing of liquid phase was in the first reactor. It was found that the progress of reaction was accelerated. 2 refs., 5 figs., 1 tab.

  18. System evaluation of offshore platforms with gas liquefaction processes

    Nguyen, Tuong-Van; de Oliveira Júnior, Silvio

    2018-01-01

    Abstract Floating, production, storage and offloading plants are facilities used for offshore processing of hydrocarbons in remote locations. At present, the produced gas is injected back into the reservoir instead of being exported. The implementation of refrigeration processes offshore for liqu......Abstract Floating, production, storage and offloading plants are facilities used for offshore processing of hydrocarbons in remote locations. At present, the produced gas is injected back into the reservoir instead of being exported. The implementation of refrigeration processes offshore...... improvements are discussed based on an energy and exergy analysis. Compared to a standard platform where gas is directly injected into the reservoir, the total power consumption increases by up to 50%, and the exergy destruction within the processing plant doubles when a liquefaction system is installed....... It is therefore essential to conduct a careful analysis of the trade-off between the capital costs and operating revenues for such options....

  19. Some aspects of optimising the reactor core for a 600 MW(e) high temperature helium turbine power plant

    Hansen, U; Presser, W

    1972-04-24

    For the HHT 600 MW(e) power plant a core design with Triagonal blocks containing 24 channels with directly cooled fuel pins was considered. The design was found to require a low HM loading in the fuel zone to achieve favourable economic merits. For low HM densities a strong incentive exists to aim for burn-ups between 80 and 100 GWd/t. At the present an average discharge irradiation of 80 GWd/t was thought feasible and a reference design with a HM density of 0.6 g/cm {sup 3} in both core zones was chosen. The optimisation is not likely to be upset by local hot channel effects as a special investigation into the influence of safety margins found no changes in fuel cycle economics.

  20. Coal liquefaction and gas conversion contractors review conference: Proceedings

    NONE

    1995-11-01

    This volume contains 55 papers presented at the conference. They are divided into the following topical sections: Direct liquefaction; Indirect liquefaction; Gas conversion (methane conversion); and Advanced research liquefaction. Papers in this last section deal mostly with coprocessing of coal with petroleum, plastics, and waste tires, and catalyst studies. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  1. Residual liquefaction of seabed under standing waves

    Kirca, V.S. Ozgur; Sumer, B. Mutlu; Fredsøe, Jørgen

    2013-01-01

    This paper presents the results of an experimental study of the seabed liquefaction beneath standing waves. Silt (with d50 =0.070mm) was used in the experiments. Two kinds of measurements were carried out: pore water pressure measurements and water surface elevation measurements. These measurements...... were synchronized with video recording of the liquefaction process from the side. The ranges of the various quantities in the experiments were wave height H= 5.9-12.0 cm, wave period T= 1.09s, and water depth h=30 cm. The experiments show that the seabed liquefaction under standing waves, although...... qualitatively similar, show features different from that caused by progressive waves. The pore water pressure builds up (or accumulated) in the areas around the node and subsequently spreads out toward the antinodes. The experimental results imply that this transport is caused by a diffusion mechanism...

  2. Biomass Indirect Liquefaction Strategy Workshop Summary Report

    none,

    2014-07-01

    This report is based on the proceedings of the U.S. Department of Energy Bioenergy Technologies Office Biomass Indirect Liquefaction Strategy Workshop. The workshop, held March 20–21, 2014, in Golden, Colorado, discussed and detailed the research and development needs for biomass indirect liquefaction. Discussions focused on pathways that convert biomass-based syngas (or any carbon monoxide, hydrogen gaseous stream) to liquid intermediates (alcohols or acids) and further synthesize those intermediates to liquid hydrocarbons that are compatible as either a refinery feed or neat fuel.

  3. Liquefaction chemistry and kinetics: Hydrogen utilization studies

    Rothenberger, K.S.; Warzinski, R.P.; Cugini, A.V. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    The objectives of this project are to investigate the chemistry and kinetics that occur in the initial stages of coal liquefaction and to determine the effects of hydrogen pressure, catalyst activity, and solvent type on the quantity and quality of the products produced. The project comprises three tasks: (1) preconversion chemistry and kinetics, (2) hydrogen utilization studies, and (3) assessment of kinetic models for liquefaction. The hydrogen utilization studies work will be the main topic of this report. However, the other tasks are briefly described.

  4. Fundamental studies of coal liquefaction

    1995-01-01

    The authors have examined the pyrolysis of Argonne samples of Wyodak and Illinois No. 6 coal in argon, undecane, Tetralin, and water. The effects of the pyrolysis on individual particles of coal were monitored visually in a cell with diamond windows capable of operation to temperature and pressures in excess of 500{degrees}C and 3000 psi. The changes in the particles from ambient to 460{degrees}C were recorded in real time on video tape, and images were then taken from the tape record and analyzed. The study showed that in argon both coals developed tars at 350{degrees}-370{degrees}C. The tars then quickly evaporated, leaving core particles remarkably similar in size and shape to the initial particles. These observations suggest that coal does not melt nor become fully liquid when heated. Nor does the softened coal undergo crosslinking to generate coke. Rather the simple loss of volatiles leaves behind the core residue as coke. Contrary to the common view, there appears to be no link between the bond-breaking processes yielding tar and the interaction of the coal with H-donors leading to liquefaction. Water as a medium was surprising in its effect. Both coals began to shrink at 300{degrees}-350{degrees}C, with the effect appearing to be more of an erosion rather than a uniform loss of substance as seen in Tetralin. The Wyodak continued to shrink to 460{degrees}C to about half its initial size. With the Illinois No. 6 coal, however, the process reversed at around 420{degrees}C, and the particles appeared to grow with the evolution of a tar, continuing to 460{degrees}C. The authors submit that this final observation is evidence for hydrothermal synthesis of hydrocarbons at these conditions.

  5. Solutions for Liquid Nitrogen Pre-Cooling in Helium Refrigeration Cycles

    Wagner, U

    2000-01-01

    Pre-cooling of helium by means of liquid nitrogen is the oldest and one of the most common process features used in helium liquefiers and refrigerators. Its two principle tasks are to allow or increase the rate of pure liquefaction, and to permit the initial cool-down of large masses to about 80 K. Several arrangements for the pre-cooling process are possible depending on the desired application. Each arrangement has its proper advantages and drawbacks. The aim of this paper is to review the possible process solutions for liquid nitrogen pre-cooling and their particularities.

  6. Cooling with Superfluid Helium

    Lebrun, P; Tavian, L [European Organization for Nuclear Research, Geneva (Switzerland)

    2014-07-01

    The technical properties of helium II (‘superfluid’ helium) are presented in view of its applications to the cooling of superconducting devices, particularly in particle accelerators. Cooling schemes are discussed in terms of heat transfer performance and limitations. Large-capacity refrigeration techniques below 2 K are reviewed, with regard to thermodynamic cycles as well as process machinery. Examples drawn from existing or planned projects illustrate the presentation. Keywords: superfluid helium, cryogenics.

  7. Improvements on mapping soil liquefaction at a regional scale

    Zhu, Jing

    Earthquake induced soil liquefaction is an important secondary hazard during earthquakes and can lead to significant damage to infrastructure. Mapping liquefaction hazard is important in both planning for earthquake events and guiding relief efforts by positioning resources once the events have occurred. This dissertation addresses two aspects of liquefaction hazard mapping at a regional scale including 1) predictive liquefaction hazard mapping and 2) post-liquefaction cataloging. First, current predictive hazard liquefaction mapping relies on detailed geologic maps and geotechnical data, which are not always available in at-risk regions. This dissertation improves the predictive liquefaction hazard mapping by the development and validation of geospatial liquefaction models (Chapter 2 and 3) that predict liquefaction extent and are appropriate for global application. The geospatial liquefaction models are developed using logistic regression from a liquefaction database consisting of the data from 27 earthquake events from six countries. The model that performs best over the entire dataset includes peak ground velocity (PGV), VS30, distance to river, distance to coast, and precipitation. The model that performs best over the noncoastal dataset includes PGV, VS30, water table depth, distance to water body, and precipitation. Second, post-earthquake liquefaction cataloging historically relies on field investigation that is often limited by time and expense, and therefore results in limited and incomplete liquefaction inventories. This dissertation improves the post-earthquake cataloging by the development and validation of a remote sensing-based method that can be quickly applied over a broad region after an earthquake and provide a detailed map of liquefaction surface effects (Chapter 4). Our method uses the optical satellite images before and after an earthquake event from the WorldView-2 satellite with 2 m spatial resolution and eight spectral bands. Our method

  8. Thermoeconomic optimization of a cryogenic refrigeration cycle for re-liquefaction of the LNG boil-off gas

    Sayyaadi, Hoseyn; Babaelahi, M. [Faculty of Mechanical Engineering-Energy Division, K.N. Toosi University of Technology, P.O. Box: 19395-1999, No. 15-19, Pardis Str., Mollasadra Ave., Vanak Sq., Tehran 1999 143344 (Iran)

    2010-09-15

    The development of the liquefaction process for the Liquefied Natural Gas (LNG) boil-off re-liquefaction plants will be addressed to provide an environmentally friendly and cost effective solution for the gas transportation. In this manner, onboard boil-off gas (BOG) re-liquefaction system as a cryogenic refrigeration cycle is utilized in order to re-liquefy the BOG and returns it to the cargo tanks instead of burning it. In this paper, a thermoeconomic optimization of the LNG-BOG liquefaction system is performed. A thermoeconomic model based on energy and exergy analyses and an economic model according to the total revenue requirement (TRR) are developed. Minimizing of the unit cost of the refrigeration effect as a product of BOG re-liquefaction plant is performed using the genetic algorithm. Results of thermoeconomic optimization are compared with corresponding features of the base case system. Finally, sensitivity of the total cost of the system product with respect to the variation of some operating parameters is studied. (author)

  9. Contribution to the experimental study of the polarized liquid helium-3; Contributions a l'etude experimentale de l'helium-3 liquide polarise

    Villard, B

    1999-07-15

    Spin-polarized liquid helium-3 is prepared by laser optical pumping in low magnetic field and at room temperature, prior to fast liquefaction of the polarized sample. The use of a new helium-3 cryostat enabled us to obtain liquid helium-3 with polarization rates up to 25 % at well-stabilized temperatures (around 0.5 K). We could thereby study the effect of nuclear polarization on liquid-vapour equilibrium, and particularly on the saturated vapour pressure. Very sensitive capacitive gauges were developed. We estimated (to first order in M{sup 2}) the expected effects when the polarization M is suddenly destroyed. These effects were experimentally observed in helium-3/helium-4 mixtures, in pure helium-3, only a transient increase in pressure has been recorded. We then describe in a third part a preliminary experiment which aimed at determining the longitudinal relaxation time T1 in mixtures. Relaxation on the walls is efficiently reduced by a cesium coating and T1s of order 20 minutes were observed. A careful determination of the helium-3 concentration in the liquid phase was made. Finally we studied the effects of dipolar field on transverse polarisation decay in our strongly polarized samples. We observed the free precession of polarization after a NMR pulse, and analysed in detail its decay time constant as a function of different parameters. This time constant drastically varied with the tipping angle, an effect which could be linked to NMR dynamical instabilities. (author)

  10. Dispersed-phase catalysis in coal liquefaction

    Utz, B.R.; Cugini, A.V.; Frommell, E.A.

    1990-01-01

    This paper reports that the specific reaction (activation) conditions for the conversion of catalyst precursors to unsupported catalyst have a direct effect on the catalytic activity and dispersion. The importance of reaction intermediates in decomposition of ammonium heptamolybdate and ammonium tetrathiomolybdate, and the sensitivity of these intermediates to reaction conditions, were studied in coal liquefaction systems. Recent results indicate that optimization of activation conditions facilitates the formation of a highly dispersed and active form of molybdenum disulfide for coal liquefaction. The use of the catalyst precursors ammonium heptamolybdate, ammonium tetrathiomolybdate, and molybdenum trisulfide for the conversion of coal to soluble products will be discussed. The use of an unsupported dispersed-phase catalyst for direct coal liquefaction is not a novel concept and has been employed in may studies with varying success. Dispersed-phase catalysts soluble and oil-soluble salts, and as finely divided powders. While some methods of catalyst introduction give higher dispersion of the catalyst and greater activity for the liquefaction of coal, all of the techniques allow the formation of a finely dispersed inorganic phase

  11. Hydrothermal Liquefaction of the Microalgae Phaeodactylum tricornutum

    Sigaard Christensen, Per; Peng, Gaël; Vogel, Frédéric

    2014-01-01

    The microalgae Phaeodactylum tricornutum was processed by hydrothermal liquefaction in order to assess the influence of reaction temperature and reaction time on the product and elemental distribution. The experiments were carried out at different reaction times (5 and 15 min) and over a wide range...

  12. Evaluating liquefaction potential. A case history

    Blystra, A.R.

    1991-01-01

    Several earthen hydropower embankment dams in the midwestern United States were constructed using hydraulic fill methods and are liable to liquefaction during an earthquake due to the use of very loose, saturated sand in the embankment or foundations. A case history is presented describing the methodology used in evaluating the liquefaction potential of the largest earthfill dam in Michigan. The methodology includes the use of standard penetration and cone penetration test data in the formulation of a simplified procedure. Field investigations, laboratory testing, and analyses used are described. In addition to the drilling program, field work included an extensive ground penetrating radar survey, acoustic emission testing, and an electrical resistivity survey. It was found that the lowest calculated factor of safety against liquefaction is 0.63 for a loose zone ca 140 feet below the top of the embankment, and the factor of safety against slope failure, should the zone liquefy, is 1.49. It was concluded that while liquefaction is possible, post earthquake stability is adequate. 6 refs., 3 figs., 1 tab

  13. Liquefaction of torrefied wood using microwave irradiation

    Mengchao Zhou; Thomas Eberhardt; Pingping Xin; Chung-Yun Hse; Hui Pan

    2016-01-01

    Torrefaction is an effective pretreatment method to improve the uniformity and quality of lignocellulosic biomass before further thermal processing (e.g., gasification, combustion). The objective of this study was to determine the impacts of torrefaction as a pretreatment before liquefaction. Wood chips were torrefied for 2 h at three different temperatures (230, 260,...

  14. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Survey of Australian industrial capability and construction capability relative to Australian brown coal liquefaction plant construction project (Annexed materials: Lists of projects undertaken by important corporations in Australia); 1981 nendo Goshu kattan ekika plant no kensetsu ni kakawaru kogyoryoku, kensetsu kojiryoku ni kansuru chosa seika hokokusho (fuzoku shiryo). Australia ni okeru shuyo kigyo no jisshi project list

    NONE

    1982-03-01

    In relation with the construction of an Australian brown coal liquefaction plant, a survey is conducted into projects being undertaken by important businesses in Australia, and lists are compiled about them. Mentioned in the lists are the head office, directors, number of employees, line of business, contents of projects, the names of clients, etc., for each of 12 corporations including consulting firms and engineering contractors such as the Bechtel Pacific Corporation Limited. Named in the lists also are 17 manufacturers of pipes and tubes, pressure vessels, heat exchangers, tower tanks, steel structures and other fabricated metallic items, boilers, water treatment systems, pumps, electrical equipment, instrumentation, valves, iron and steel, etc. Furthermore, in relation with civil engineering and construction, 7 corporations including the Citra Constructions Limited are mentioned. (NEDO)

  15. Helium the disappearing element

    Sears, Wheeler M

    2015-01-01

    The subject of the book is helium, the element, and its use in myriad applications including MRI machines, particle accelerators, space telescopes, and of course balloons and blimps. It was at the birth of our Universe, or the Big Bang, where the majority of cosmic helium was created; and stellar helium production continues. Although helium is the second most abundant element in the Universe, it is actually quite rare here on Earth and only exists because of radioactive elements deep within the Earth. This book includes a detailed history of the discovery of helium, of the commercial industry built around it, how the helium we actually encounter is produced within the Earth, and the state of the helium industry today. The gas that most people associate with birthday party balloons is running out. “Who cares?” you might ask. Well, without helium, MRI machines could not function, rockets could not go into space, particle accelerators such as those used by CERN could not operate, fiber optic cables would not...

  16. Helium dilution refrigerator

    1973-01-01

    A new system of continuous heat exchange for a helium dilution refrigerator is proposed. The 3 He effluent tube is concurrent with the affluent mixed helium tube in a vertical downward direction. Heat exchange efficiency is enhanced by placing in series a number of elements with an enlarged surface area

  17. Helium localisation in tritides

    Flament, J.L.; Lozes, G.

    1982-06-01

    Study of titanium and LaNi 5 type alloys tritides lattice parameters evolution revealed that helium created by tritium decay remains in interstitial sites up to a limit material dependant concentration. Beyond this one exceeding helium precipites in voids [fr

  18. Report on the bituminous coal liquefaction sub-committee in fiscal 1992; 1992 nendo rekiseitan ekika bukai hokokusho

    NONE

    1993-03-01

    This paper reports the activities of the bituminous coal liquefaction sub-committee in the Sunshine Project in fiscal 1992. With an intention of developing a technology on the process (NEDOL) suitable for liquefaction of wide range of coal types placing sub-bituminous coal at the center, researches were carried out by using a pilot plant, and engineering data purposed for practical application of the technology were acquired. The construction of the pilot plant was launched in fiscal 1991. It is necessary to execute the pilot plant plan steadily in the future, and at the same time, reliably acquire different data by means of supportive researches. Economic performance of the process is also important. The first sub-committee meeting presented the following agenda: the status of constructing the 150-t/d pilot plant, tests and investigations thereon, research works by using a 1-t/d PSU, development of the most suitable coal refining technology, development of a coal pretreatment technology, improvement of the distilled oil distribution, studies on coal liquefaction conditions, and studies on solvent hydrogenating catalysts. The second sub-committee meeting presented the following agenda: the status of constructing the pilot plant, tests and investigations on improving the performance of natural pylite catalyst and circulating solvent, technological investigations on structuring a liquefying reaction data analyzing system, studies using a 1-t/d PSU, development of the most suitable coal refining technology, studies on coal liquefaction conditions, and studies on solvent hydrogenating catalysts. (NEDO)

  19. A preliminary analysis of floating production storage and offloading facilities with gas liquefaction processes

    Nguyen, Tuong-Van; Carranza-Sánchez, Yamid Alberto; Junior, Silvio de Oliveira

    2016-01-01

    Floating, production, storage and offloading (FPSO) plants are facilities used in upstream petroleum processing. They have gained interest because they are more flexible than conventional plants and can be used for producing oil and gas in deep-water fields. In general, gas export is challenging...... because of the lack of infrastructure in remote locations. The present work investigates the possibility of integrating liquefaction processes on such facilities, considering two mixed-refrigerant and two expansion-based processes suitable for offshore applications. Two FPSO configurations are considered...... in this work, and they were suggested by Brazilian operators for fields processing natural gas with moderate to high content of carbon dioxide. The performance of the combined systems is analysed by conducting energy and exergy analyses. The integration of gas liquefaction results in greater power consumption...

  20. Helium behaviour in implanted boron carbide

    Motte Vianney

    2015-01-01

    Full Text Available When boron carbide is used as a neutron absorber in nuclear power plants, large quantities of helium are produced. To simulate the gas behaviour, helium implantations were carried out in boron carbide. The samples were then annealed up to 1500 °C in order to observe the influence of temperature and duration of annealing. The determination of the helium diffusion coefficient was carried out using the 3He(d,p4He nuclear reaction (NRA method. From the evolution of the width of implanted 3He helium profiles (fluence 1 × 1015/cm2, 3 MeV corresponding to a maximum helium concentration of about 1020/cm3 as a function of annealing temperatures, an Arrhenius diagram was plotted and an apparent diffusion coefficient was deduced (Ea = 0.52 ± 0.11 eV/atom. The dynamic of helium clusters was observed by transmission electron microscopy (TEM of samples implanted with 1.5 × 1016/cm2, 2.8 to 3 MeV 4He ions, leading to an implanted slab about 1 μm wide with a maximum helium concentration of about 1021/cm3. After annealing at 900 °C and 1100 °C, small (5–20 nm flat oriented bubbles appeared in the grain, then at the grain boundaries. At 1500 °C, due to long-range diffusion, intra-granular bubbles were no longer observed; helium segregates at the grain boundaries, either as bubbles or inducing grain boundaries opening.

  1. Status of health and environmental research relative to direct coal liquefaction: 1976 to the present

    Gray, R.H.; Cowser, K.E. (eds.)

    1982-06-01

    This document describes the status of health and environmental research efforts, supported by the US Department of Energy (DOE), to assist in the development of environmentally acceptable coal liquefaction processes. Four major direct coal liquefaction processes are currently in (or have been investigated at) the pilot plant stage of development. Two solvent refined coal processes (SRC-I and -II), H-coal (a catalytic liquefaction process) and Exxon donor solvent (EDS). The Pacific Northwest Laboratory was assigned responsibility for evaluating SRC process materials and prepared comprehensive health and environmental effects research program plans for SRC-I and -II. A similar program plan was prepared for H-coal process materials by the Oak Ridge National Laboratory. A program has been developed for EDS process materials by Exxon Research and Engineering Co. The program includes short-term screening of coal-derived materials for potential health and ecological effects. Longer-term assays are used to evaluate materials considered most representative of potential commercial practice and with greatest potential for human exposure or release to the environment. Effects of process modification, control technologies and changing operational conditions on potential health and ecological effects are also being evaluated. These assessments are being conducted to assist in formulating cost-effective environmental research programs and to estimate health and environmental risks associated with a large-scale coal liquefaction industry. Significant results of DOE's health and environmental research efforts relative to coal liquefaction include the following: chemical characterization, health effects, ecological fate and effects, amelioration and risk assessment.

  2. A liquid helium saver

    Avenel, O.; Der Nigohossian, G.; Roubeau, P.

    1976-01-01

    A cryostat equipped with a 'liquid helium saver' is described. A mass flow rate M of helium gas at high pressure is injected in a counter-flow heat exchanger extending from room to liquid helium temperature. After isenthalpic expansion through a calibrated flow impedance this helium gas returns via the low pressure side of the heat exchanger. The helium boil-off of the cryostat represents a mass flow rate m, which provides additional precooling of the incoming helium gas. Two operating regimes appear possible giving nearly the same efficiency: (1) high pressure (20 to 25 atm) and minimum flow (M . L/W approximately = 1.5) which would be used in an open circuit with helium taken from a high pressure cylinder; and (2) low pressure (approximately = 3 atm), high flow (M . L/W > 10) which would be used in a closed circuit with a rubber diaphragm pumping-compressing unit; both provide a minimum theoretical boil-off factor of about 8%. Experimental results are reported. (U.K.)

  3. Energy consumption, destruction of exergy and boil off during the process of liquefaction, transport and regasification of liquefied natural gas

    Stradioto, Diogo Angelo; Schneider, Paulo Smith [Dept. of Mechanical Engineering. Universidade Federal do Rio Grande do Sul, Porto Alegre (Brazil)], e-mail: pss@mecanica.ufrgs.br

    2010-07-01

    A supply chain of Liquefied Natural Gas (LNG) is composed by several processes like extraction, purification, liquefaction, storage, transport, regasification and distribution. In all these stages, processes need of energy. The main objective of this work is to quantify the energy consumption, mass loss and exergy destruction occurred throughout the chain. Results show that the process of liquefaction is the largest consumer of energy. Storage and transport by ship are responsible for the bigger mass losses and regasification is the process of larger destruction of exergy. A case study is performed considering a stream of pure methane at the input of a liquefaction plant, and evaluates energy along the chain, ending up at the distribution of NG after its regasification. (author)

  4. Study on fundamental features of helium turbomachine for high temperature gas-cooled reactor

    Wang Jie; Gu Yihua

    2004-01-01

    The High temperature gas-cooled reactor (HTGR) coupled with helium turbine cycle is considered as one of the leading candidates for future nuclear power plants. The HTGR helium turbine cycle was analyzed and optimized. Then the focal point of investigation was concentrated on the fundamental thermodynamic and aerodynamic features of helium turbomachine. As a result, a helium turbomachine is different from a general combustion gas turbine in two main design features, that is a helium turbomachine has more blade stages and shorter blade length, which are caused by the helium property and the high pressure of a closed cycle, respectively. (authors)

  5. Direct catalytic hydrothermal liquefaction of spirulina to biofuels with hydrogen

    Zeng, Qin; Liao, Hansheng; Zhou, Shiqin; Li, Qiuping; Wang, Lu; Yu, Zhihao; Jing, Li

    2018-01-01

    We report herein on acquiring biofuels from direct catalytic hydrothermal liquefaction of spirulina. The component of bio-oil from direct catalytic hydrothermal liquefaction was similar to that from two independent processes (including liquefaction and upgrading of biocrude). However, one step process has higher carbon recovery, due to the less loss of carbons. It was demonstrated that the yield and HHV of bio-oil from direct catalytic algae with hydrothermal condition is higher than that from two independent processes.

  6. Two-stage coal liquefaction without gas-phase hydrogen

    Stephens, H.P.

    1986-06-05

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  7. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  8. Experimental study on the liquefaction of cellulose in supercritical ethanol

    Peng, Jinxing; Liu, Xinyuan; Bao, Zhenbo

    2018-03-01

    Cellulose is the major composition of solid waste for producing biofuel; cellulose liquefaction is helpful for realizing biomass supercritical liquefaction process. This paper is taking supercritical ethanol as the medium, liquefied cellulose with the intermittence installation of high press cauldron. Experiments have studied technical condition and the technology parameter of cellulose liquefaction in supercritical ethanol, and the pyrolysis mechanism was analysed based on the pyrolysis product. Results show that cellulose can be liquefied, can get good effect through appropriate technology condition. Under not catalyst, highest liquefaction rate of cellulose can reach 73.5%. The composition of the pyrolysis product was determined by GC-MS.

  9. Potential applications of high temperature helium

    Schleicher, R.W. Jr.; Kennedy, A.J.

    1992-09-01

    This paper discusses the DOE MHTGR-SC program's recent activity to improve the economics of the MHTGR without sacrificing safety performance and two potential applications of high temperature helium, the MHTGR gas turbine plant and a process heat application for methanol production from coal

  10. A novel vortex tube-based N2-expander liquefaction process for enhancing the energy efficiency of natural gas liquefaction

    Qyyum Muhammad Abdul

    2017-01-01

    Full Text Available This research work unfolds a simple, safe, and environment-friendly energy efficient novel vortex tube-based natural gas liquefaction process (LNG. A vortex tube was introduced to the popular N2-expander liquefaction process to enhance the liquefaction efficiency. The process structure and condition were modified and optimized to take a potential advantage of the vortex tube on the natural gas liquefaction cycle. Two commercial simulators ANSYS® and Aspen HYSYS® were used to investigate the application of vortex tube in the refrigeration cycle of LNG process. The Computational fluid dynamics (CFD model was used to simulate the vortex tube with nitrogen (N2 as a working fluid. Subsequently, the results of the CFD model were embedded in the Aspen HYSYS® to validate the proposed LNG liquefaction process. The proposed natural gas liquefaction process was optimized using the knowledge-based optimization (KBO approach. The overall energy consumption was chosen as an objective function for optimization. The performance of the proposed liquefaction process was compared with the conventional N2-expander liquefaction process. The vortex tube-based LNG process showed a significant improvement of energy efficiency by 20% in comparison with the conventional N2-expander liquefaction process. This high energy efficiency was mainly due to the isentropic expansion of the vortex tube. It turned out that the high energy efficiency of vortex tube-based process is totally dependent on the refrigerant cold fraction, operating conditions as well as refrigerant cycle configurations.

  11. A novel vortex tube-based N2-expander liquefaction process for enhancing the energy efficiency of natural gas liquefaction

    Qyyum, Muhammad Abdul; Wei, Feng; Hussain, Arif; Ali, Wahid; Sehee, Oh; Lee, Moonyong

    2017-11-01

    This research work unfolds a simple, safe, and environment-friendly energy efficient novel vortex tube-based natural gas liquefaction process (LNG). A vortex tube was introduced to the popular N2-expander liquefaction process to enhance the liquefaction efficiency. The process structure and condition were modified and optimized to take a potential advantage of the vortex tube on the natural gas liquefaction cycle. Two commercial simulators ANSYS® and Aspen HYSYS® were used to investigate the application of vortex tube in the refrigeration cycle of LNG process. The Computational fluid dynamics (CFD) model was used to simulate the vortex tube with nitrogen (N2) as a working fluid. Subsequently, the results of the CFD model were embedded in the Aspen HYSYS® to validate the proposed LNG liquefaction process. The proposed natural gas liquefaction process was optimized using the knowledge-based optimization (KBO) approach. The overall energy consumption was chosen as an objective function for optimization. The performance of the proposed liquefaction process was compared with the conventional N2-expander liquefaction process. The vortex tube-based LNG process showed a significant improvement of energy efficiency by 20% in comparison with the conventional N2-expander liquefaction process. This high energy efficiency was mainly due to the isentropic expansion of the vortex tube. It turned out that the high energy efficiency of vortex tube-based process is totally dependent on the refrigerant cold fraction, operating conditions as well as refrigerant cycle configurations.

  12. Conceptual study of hydrogen donor solvent in the NEDOL coal liquefaction process

    Kouzu, M.; Onozaki, M.; Oi, S. [Mitsui SRC Co Ltd, Tokyo (Japan)

    2002-03-01

    A 150 ton/day coal liquefaction pilot plant (PP) of the NEDOL process, supported by New Energy and Industrial Technology Development Organization (NEDO), was operated successfully for a total of 269 days at Kashima, Japan. With a great number of data obtained through the operation, the design procedure for the NEDOL process was studied. Middle and heavy oils from the coal employed were recycled as a hydrogen-donor solvent after hydrotreatment over Ni Mo/gamma-Al2O{sub 3} in a trickle bed reactor. The hydrogen donating ability of the solvent was high enough to obtain higher oil yield (50-58 wt%) at the aromaticity of ca. 0.45. Life expectancy of solvent hydrotreatment catalyst, requisite to the hydrotreater design, was estimated under PP operating conditions. In addition, physical properties of the solvent required for process design were determined, and hydrodynamics in the liquefaction bubble column reactors were examined. Taking the obtained hydrodynamics and thermal behavior into consideration, a design procedure of the liquefaction bubble column reactors was establsihed using a process simulator (CARD) validated by the product yields of PP. The simulation including distillation and solvent hydrotreatment showed that the content of heavy oil fraction (b.p. 350 - 538{degree} C) in the solvent was a determinant factor in the design of a large scale plant based on the NEDOL process.

  13. Liquefaction of lignohemicellulosic waste by processing with carbon monoxide and water

    El-Saied, H

    1977-09-01

    The liquefaction of lignohemicellulosic waste by processing with carbon monoxide and water for 10 minutes at 250/sup 0/-440/sup 0/C and 40 to 70 atm initial pressure in a rocking autoclave produced benzene-soluble heavy oil in yields up to 80%. High conversion and yields were favored by high thermal stress, short reaction times, and sufficient hydrogen to prevent radical recombination in the critical liquefaction stages. The addition of sodium or calcium hydroxide, sodium carbonate, iron oxide, etc. in small amounts gave good oil yields under less severe conditions. Lignins from rice straw, bagasse, and other grasses gave higher yields than the woody lignin obtained from cotton stalks. In products obtained by liquefying black liquor lignohemicellulose from an Eyptian rice straw pulping plant, the hydrogen-carbon atomic ratio was 1.0 to 1.3:1.

  14. Production of Advanced Biofuels via Liquefaction - Hydrothermal Liquefaction Reactor Design: April 5, 2013

    Knorr, D.; Lukas, J.; Schoen, P.

    2013-11-01

    This report provides detailed reactor designs and capital costs, and operating cost estimates for the hydrothermal liquefaction reactor system, used for biomass-to-biofuels conversion, under development at Pacific Northwest National Laboratory. Five cases were developed and the costs associated with all cases ranged from $22 MM/year - $47 MM/year.

  15. Liquefaction Microzonation of Babol City Using Artificial Neural Network

    Farrokhzad, F.; Choobbasti, A.J.; Barari, Amin

    2012-01-01

    that will be less susceptible to damage during earthquakes. The scope of present study is to prepare the liquefaction microzonation map for the Babol city based on Seed and Idriss (1983) method using artificial neural network. Artificial neural network (ANN) is one of the artificial intelligence (AI) approaches...... microzonation map is produced for research area. Based on the obtained results, it can be stated that the trained neural network is capable in prediction of liquefaction potential with an acceptable level of confidence. At the end, zoning of the city is carried out based on the prediction of liquefaction...... that can be classified as machine learning. Simplified methods have been practiced by researchers to assess nonlinear liquefaction potential of soil. In order to address the collective knowledge built-up in conventional liquefaction engineering, an alternative general regression neural network model...

  16. The direct liquefaction proof of concept program

    Comolli, A.G.; Lee, L.K.; Pradhan, V.R.; Stalzer, R.H. [New York & Puritan Avenues, Lawrenceville, NJ (United States)

    1995-12-31

    The goal of the Proof of Concept (POC) Program is to develop Direct Coal Liquefaction and associated transitional technologies towards commercial readiness for economically producing premium liquid fuels from coal in an environmentally acceptable manner. The program focuses on developing the two-stage liquefaction (TSL) process by utilizing geographically strategic feedstocks, commercially feasible catalysts, new prototype equipment, and testing co-processing or alternate feedstocks and improved process configurations. Other high priority objectives include dispersed catalyst studies, demonstrating low rank coal liquefaction without solids deposition, improving distillate yields on a unit reactor volume basis, demonstrating ebullated bed operations while obtaining scale-up data, demonstrating optimum catalyst consumption using new concepts (e.g. regeneration, cascading), producing premium products through on-line hydrotreating, demonstrating improved hydrogen utilization for low rank coals using novel heteroatom removal methods, defining and demonstrating two-stage product properties for upgrading; demonstrating efficient and economic solid separation methods, examining the merits of integrated coal cleaning, demonstrating co-processing, studying interactions between the preheater and first and second-stage reactors, improving process operability by testing and incorporating advanced equipment and instrumentation, and demonstrating operation with alternate coal feedstocks. During the past two years major PDU Proof of Concept runs were completed. POC-1 with Illinois No. 6 coal and POC-2 with Black Thunder sub-bituminous coal. Results from these operations are continuing under review and the products are being further refined and upgraded. This paper will update the results from these operations and discuss future plans for the POC program.

  17. Report on the FY 1998 results of the New Sunshine Project (B version). Data attached 2. Development of coal liquefaction technology (Development of base technology of liquefaction (Project on internationalization of coal liquefaction technology)); 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Ekika kiban gijutsu no kaihatsu (sekitan ekika gijutsu no kokusaika jigyo (fuzoku shiryo 2))

    NONE

    1999-03-01

    As a part of the project for internationalization of coal liquefaction technology, this paper reported on the potential survey for location of Indonesian low grade coal liquefaction (study of applicability of the improved BCL process and survey of hydrogen production technology using coal gasification). The survey was conducted of a locational possibility of a coal liquefaction commercial plant to be located at mine site in South Sumatra for Banko coal raw material. The improved BCL process was applied in which the results of the study by NBCL Takasago Research Institute were reflected. Further, the hydrogen production was studied by gasification of Banko coal, and the comparison was made with the conventional natural gas reforming method. As a result of the study using information/knowledge obtained during the conceptual design of Australian brown coal, the construction cost of commercial scale liquefaction plant with the Banko coal processing amount of 30,000 tons/day became 549.8 billion yen in the case of using natural gas as raw material for hydrogen production. This construction cost is the lowest as compared with 601.7 billion yen in the demonstrative BCL process and with 577.1 billion yen in the advanced BCL process. This is a process making use of features of Banko coal. The process for hydrogen production by the steam reforming method using natural gas has an advantage of increasing the production amount of coal-derived liquid the most of the three other methods. (NEDO)

  18. Report on the FY 1998 results of the New Sunshine Project (B version). Data attached 1. Development of coal liquefaction technology (Development of base technology of liquefaction (Project on internationalization of coal liquefaction technology)); 1998 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Ekika kiban gijutsu no kaihatsu (sekitan ekika gijutsu no kokusaika jigyo (fuzoku shiryo-1))

    NONE

    1999-03-01

    As a part of the project for internationalization of coal liquefaction technology, this paper reported on the potential survey for location of Indonesian low grade coal liquefaction (study of applicability of the improved BCL process and survey of hydrogen production technology using coal gasification). The survey was conducted of a locational possibility of a coal liquefaction commercial plant to be located at mine site in South Sumatra for Banko coal raw material. The improved BCL process was applied in which the results of the study by NBCL Takasago Research Institute were reflected. Further, the hydrogen production was studied by gasification of Banko coal, and the comparison was made with the conventional natural gas reforming method. As a result of the study using information/knowledge obtained during the conceptual design of Australian brown coal, the construction cost of commercial scale liquefaction plant with the Banko coal processing amount of 30,000 tons/day became 549.8 billion yen in the case of using natural gas as raw material for hydrogen production. This construction cost is the lowest as compared with 601.7 billion yen in the demonstrative BCL process and with 577.1 billion yen in the advanced BCL process. This is a process making use of features of Banko coal. The process for hydrogen production by the steam reforming method using natural gas has an advantage of increasing the production amount of coal-derived liquid the most of the three other methods. (NEDO)

  19. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  20. Thermodynamic Evaluation of Floating Production Storage and Offloading Facilities with Liquefaction Processes

    Nguyen, Tuong-Van; Sánchez, Yamid Alberto Carranza; Junior, Silvio de Oliveira

    2016-01-01

    Floating, production, storage and offloading (FPSO) plants are facilities used in upstream petroleum processing.They have gained interest because they are more flexible than conventional plants and can be used for producingoil and gas in deep-water fields. In general, gas export is challenging...... because of the lack of infrastructure in remotelocations. The present work investigates the possibility of integrating liquefaction processes on such facilities, consideringfour possible petroleum compositions, which differ in their contents of carbon dioxide, light and heavy hydrocarbons.The performance...

  1. Shear wave velocity-based evaluation and design of stone column improved ground for liquefaction mitigation

    Zhou, Yanguo; Sun, Zhengbo; Chen, Jie; Chen, Yunmin; Chen, Renpeng

    2017-04-01

    The evaluation and design of stone column improvement ground for liquefaction mitigation is a challenging issue for the state of practice. In this paper, a shear wave velocity-based approach is proposed based on the well-defined correlations of liquefaction resistance (CRR)-shear wave velocity ( V s)-void ratio ( e) of sandy soils, and the values of parameters in this approach are recommended for preliminary design purpose when site specific values are not available. The detailed procedures of pre- and post-improvement liquefaction evaluations and stone column design are given. According to this approach, the required level of ground improvement will be met once the target V s of soil is raised high enough (i.e., no less than the critical velocity) to resist the given earthquake loading according to the CRR- V s relationship, and then this requirement is transferred to the control of target void ratio (i.e., the critical e) according to the V s- e relationship. As this approach relies on the densification of the surrounding soil instead of the whole improved ground and is conservative by nature, specific considerations of the densification mechanism and effect are given, and the effects of drainage and reinforcement of stone columns are also discussed. A case study of a thermal power plant in Indonesia is introduced, where the effectiveness of stone column improved ground was evaluated by the proposed V s-based method and compared with the SPT-based evaluation. This improved ground performed well and experienced no liquefaction during subsequent strong earthquakes.

  2. The cryogenic helium cooling system for the Tokamak physics experiment

    Felker, B.; Slack, D.S.; Wendland, C.R.

    1995-01-01

    The Tokamak Physics Experiment (TPX) will use supercritical helium to cool all the magnets and supply helium to the Vacuum cryopumping subsystem. The heat loads will come from the standard steady state conduction and thermal radiation sources and from the pulsed loads of the nuclear and eddy currents caused by the Central Solenoid Coils and the plasma positioning coils. The operations of the TPX will begin with pulses of up to 1000 seconds in duration every 75 minutes. The helium system utilizes a pulse load leveling scheme to buffer out the effects of the pulse load and maintain a constant cryogenic plant operation. The pulse load leveling scheme utilizes the thermal mass of liquid and gaseous helium stored in a remote dewar to absorb the pulses of the tokamak loads. The mass of the stored helium will buffer out the temperature pulses allowing 5 K helium to be delivered to the magnets throughout the length of the pulse. The temperature of the dewar will remain below 5 K with all the energy of the pulse absorbed. This paper will present the details of the heat load sources, of the pulse load leveling scheme operations, a partial helium schematic, dewar temperature as a function of time, the heat load sources as a function of time and the helium temperature as a function of length along the various components that will be cooled

  3. Direct liquefaction proof-of-concept facility

    Alfred G. Comolli; Peizheng Zhou; HTI Staff

    2000-01-01

    The main objective of the U.S. DOE, Office of Fossil Energy, is to ensure the US a secure energy supply at an affordable price. An integral part of this program was the demonstration of fully developed coal liquefaction processes that could be implemented if market and supply considerations so required, Demonstration of the technology, even if not commercialized, provides a security factor for the country if it is known that the coal to liquid processes are proven and readily available. Direct liquefaction breaks down and rearranges complex hydrocarbon molecules from coal, adds hydrogen, and cracks the large molecules to those in the fuel range, removes hetero-atoms and gives the liquids characteristics comparable to petroleum derived fuels. The current processes being scaled and demonstrated are based on two reactor stages that increase conversion efficiency and improve quality by providing the flexibility to adjust process conditions to accommodate favorable reactions. The first stage conditions promote hydrogenation and some oxygen, sulfur and nitrogen removal. The second stage hydrocracks and speeds the conversion to liquids while removing the remaining sulfur and nitrogen. A third hydrotreatment stage can be used to upgrade the liquids to clean specification fuels.

  4. Mars Propellant Liquefaction Modeling in Thermal Desktop

    Desai, Pooja; Hauser, Dan; Sutherlin, Steven

    2017-01-01

    NASAs current Mars architectures are assuming the production and storage of 23 tons of liquid oxygen on the surface of Mars over a duration of 500+ days. In order to do this in a mass efficient manner, an energy efficient refrigeration system will be required. Based on previous analysis NASA has decided to do all liquefaction in the propulsion vehicle storage tanks. In order to allow for transient Martian environmental effects, a propellant liquefaction and storage system for a Mars Ascent Vehicle (MAV) was modeled using Thermal Desktop. The model consisted of a propellant tank containing a broad area cooling loop heat exchanger integrated with a reverse turbo Brayton cryocooler. Cryocooler sizing and performance modeling was conducted using MAV diurnal heat loads and radiator rejection temperatures predicted from a previous thermal model of the MAV. A system was also sized and modeled using an alternative heat rejection system that relies on a forced convection heat exchanger. Cryocooler mass, input power, and heat rejection for both systems were estimated and compared against sizing based on non-transient sizing estimates.

  5. Achievement report for fiscal 1981 on Sunshine Part 2. Program-assisted project. Research and development of coal liquefaction technology (Development of direct coal hydroliquefaction plant; development of 2.4T/day-capable research plant); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu / chokusetsu suiten ekika plant no kaihatsu seika hokokusho. 2. 2.4t/nichi jikken plant no kaihatsu

    NONE

    1982-03-01

    For the goal of developing a direct coal hydroliquefaction plant, designing of a 2.4T/day-capable research plant is conducted as in the preceding fiscal year, devices are purchased and manufactured, and construction work is carried out. The construction work is now over, and the plant is subjected to various inspections by the relevant Government offices. Preparatory tasks are discharged for the study of operation. The material of the 2.4T/day-capable research plant presented here is a compilation of charts of the piping routes, charts of civil engineering and construction, charts of instrumentation, charts of electrical systems, documents of approvals and licenses, etc. (NEDO)

  6. Cooperative Research Program in Coal-Waste Liquefaction

    Gerald Huffman

    2000-03-31

    The results of a feasibility study for a demonstration plant for the liquefaction of waste plastic and tires and the coprocessing of these waste polymers with coal are presented. The study was conducted by a committee that included nine representatives from the CFFS, six from the U.S. Department of Energy - Federal Energy Technology Center (FETC), and four from Burns and Roe, Inc. The study included: (1) An assessment of current recycling practices, particularly feedstock recycling in Germany; (2) A review of pertinent research, and a survey of feedstock availability for various types of waste polymers; and (3) A conceptual design for a demonstration plant was developed and an economic analysis for various feedstock mixes. The base case for feedstock scenarios was chosen to be 200 tons per day of waste plastic and 100 tons per day of waste tires. For this base case with oil priced at $20 per barrel, the return on investment (ROI) was found to range from 9% to 20%, using tipping fees for waste plastic and tires typical of those existing in the U.S. The most profitable feedstock appeared to waste plastic alone, with a plant processing 300 t/d of plastic yielding ROI's from 13 to 27 %, depending on the tipping fees for waste plastic. Feedstock recycling of tires was highly dependent on the price that could be obtained for recovered carbon. Addition of even relatively small amounts (20 t/d) of coal to waste plastic and/or coal feeds lowered the ROI's substantially. It should also be noted that increasing the size of the plant significantly improved all ROI's. For example, increasing plant size from 300 t/d to1200 t/d approximately doubles the estimated ROI's for a waste plastic feedstock.

  7. Helium refrigerator for 'SULTAN'

    Arpagaus, M.; Erlach, H.; Quack, H.

    1984-01-01

    The authors describe the helium refrigerator designed for the SULTAN test facility. SULTAN (Supraleiter-Testanlage) is intended to serve for the developments and testing of high field superconducting magnets. These magnets are needed mainly for future applications in nuclear fusion. (Auth.)

  8. Cosmological helium production simplified

    Bernstein, J.; Brown, L.S.; Feinberg, G.

    1988-01-01

    We present a simplified model of helium synthesis in the early universe. The purpose of the model is to explain clearly the physical ideas relevant to the cosmological helium synthesis, in a manner that does not overlay these ideas with complex computer calculations. The model closely follows the standard calculation, except that it neglects the small effect of Fermi-Dirac statistics for the leptons. We also neglect the temperature difference between photons and neutrinos during the period in which neutrons and protons interconvert. These approximations allow us to express the neutron-proton conversion rates in a closed form, which agrees to 10% accuracy or better with the exact rates. Using these analytic expressions for the rates, we reduce the calculation of the neutron-proton ratio as a function of temperature to a simple numerical integral. We also estimate the effect of neutron decay on the helium abundance. Our result for this quantity agrees well with precise computer calculations. We use our semi-analytic formulas to determine how the predicted helium abundance varies with such parameters as the neutron life-time, the baryon to photon ratio, the number of neutrino species, and a possible electron-neutrino chemical potential. 19 refs., 1 fig., 1 tab

  9. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Part 1. Research and development of coal liquefaction technology (Development of direct coal hydroliquefaction plant; development of 2.4T/day-capable research plant); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu / chokusetsu suiten ekika plant no kaihatsu seika hokokusho. 1. 2.4t/nichi jikken plant no kaihatsu

    NONE

    1982-03-01

    The above-named plant is constructed, and studies are conducted on its operation. Before the construction of this 2.4T/day-capable research plant, its details were designed in fiscal 1979 when the plan placed the plant at the Chiba establishment of the Mitsui Engineering and Shipbuilding Co., Ltd. The plan was altered in July of fiscal 1980 for the plant to be built at the Keihin steelworks site of the NKK Corporation, and then partial modification was implemented for the basic and detailed designs of the plant for the second year running. Furthermore, a review was made so that the results of the element studies that followed the designing of the details would be embodied, and the changes were reflected on orders placed for equipment and construction work. These processes culminated in the 2.4T/day-capable research plant, now complete and subjected to inspections by the relevant Government offices. In a study of the operation of the plant, an operating procedure is worked out, and water-handling tests are conducted for each of the stages of operation. The plant will be subjected to a full test operation, improved as required, studied for proper operation, and will undergo additional construction work as required, all these in preparation for a continuous operation in the future. (NEDO)

  10. Design of a Natural Gas Liquefaction System with Minimum Components

    Bergese, Franco

    2004-01-01

    In this work an economic method for liquefying natural gas by diminishing its temperature by means of the Joule-Thomson effect is presented.The pressures from and to which the gas must be expanded arose from a thermodynamic calculation optimizing the cost per unit mass of Liquefied Natural Gas LNG).It was determined that the gas should be expanded from 200 atm to 4 atm.This expansion ratio can be used in different scales.Large Scale: liquefaction of gas at well.It takes advantage of the fact that the gas inside the well is stored at high pressure.The gas is expanded in a valve / nozzle and then compressed to the pressure of the local pipeline system.The objective of this project is to export natural gas as LNG, which is transported by ships to the markets of consumption.Using this method of liquefaction, the LNG production levels are limited to a fraction of the production of the well, due to the injection of the un condensed gas into the local pipelines system.Medium Scale: A high pressure pipeline is the source of the gas.The expansion is performed and then the gas is again compressed to the pressure of a lower pressure pipeline into which the gas is injected.The pressure reductions of natural gas are performed nearby big cities.The aim of this project scale is the storage of fuel for gas thermal power plants during periods of low energy consumption for later burning when the resource is limited. Another possibility that offers this size of plant is the transportation of gas to regions where the resource is unavailable.This transportation would be carried out by means of cistern trucks, in the same way that conventional liquid fuels are transported.Small scale: the place of production would be a CNG refueling station. The source of gas is in this case a gas pipeline of urban distribution and the gas should be compressed with the compressor of the refueling station.Compressors have generally low loading factor and the periods of time when they are not producing

  11. Coal liquefaction technologies for producing ultra clean fuel

    Tahir, M.S.; Haq, N.U.; Nasir, H.; Islam, N.

    2011-01-01

    The expanding demand for petroleum, accompanied by the diminishing petroleum reserves and the energy security, has intensified the significance in coal liquefaction technologies (CTL) globally and specially in Pakistan. Pakistan is rich in coal resources, but short of petroleum. The Geological Survey of Pakistan based on wide spread drilling over an area of 9000 sq. km, a total of 175 billion tons of coal resource potential has been assessed. This paper overviews a general introduction on the mechanisms and processes of CLT such as direct coal liquefaction (DCL) and indirect coal liquefaction (ICL) technologies. (author)

  12. Influence of clay content on wave-induced liquefaction

    Kirca, V.S. Ozgur; Sumer, B. Mutlu; Fredsøe, Jørgen

    2014-01-01

    of measurements were carried out: (1) pore-water pressure measurements across the soil depth and (2) water-surface elevation measurements. These measurements were synchronized with video recordings of the liquefaction process from the side. The ranges of the various quantities in the experiments were wave height...... of silt and clay was not liquefied. Sand may become prone to liquefaction with the introduction of clay, contrary to the general perception that this type of sediment is normally liquefaction-resistant under waves. For instance, sand with d50 50:4 mmwas liquefied with CC510:8%, whereas sand with d50 50...

  13. Thermal optimization of the helium-cooled power leads for the SSC

    Demko, J.A.; Schiesser, W.E.; Carcagno, R.; McAshan, M.; McConeghy, R.

    1992-01-01

    The optimum thermal design of the power leads for the Superconducting Super Collider (SSC) will minimize the amount of Carnot work (which is a combination of refrigeration and liquefaction work) required. This optimization can be accomplished by the judicious selection of lead length and diameter. Even though an optimum set of dimensions is found, the final design must satisfy other physical constraints such as maximum allowable heat leak and helium vapor mass flow rate. A set of corresponding lengths and diameters has been determined that meets these requirements for the helium vapor-cooled, spiral-fin power lead design of the SSC. Early efforts by McFee and Mallon investigated optimizing power leads for cryogenic applications with no convection cooling. Later designs utilized the boiled-off helium vapor to cool the lead. One notable design for currents up to several thousand amps is presented by Efferson based on a series of recommendations discussed by Deiness. Buyanov presents many theoretical models and design formulae but does not demonstrate an approach to thermally optimizing the design of a vapor-cooled lead. In this study, a detailed numerical thermal model of a power lead design for the SSC has been developed. It was adapted from the dynamic model developed by Schiesser. This model was used to determine the optimum dimensions that minimize the Carnot refrigeration and liquefaction work due to the leads. Since the SSC leads will be cooled by supercritical helium, the flow of vapor is regulated by a control valve. These leads include a superconducting portion at the cold end. All of the material properties in the model are functions of temperature, and for the helium are functions of pressure and temperature. No pressure drop calculations were performed as part of this analysis. The diameter that minimizes the Carnot work was determined for four different lengths at a design current of 6600 amps

  14. Thermal optimization of the helium-cooled power leads for the SSC

    Demko, J.A.; Schiesser, W.E.; Carcagno, R.; McAshan, M.; McConeghy, R.

    1992-03-01

    The optimum thermal design of the power leads for the Superconducting Super Collider (SSC) will minimize the amount of Carnot work (which is a combination of refrigeration and liquefaction work) required. This optimization can be accomplished by the judicious selection of lead length and diameter. Even though an optimum set of dimensions is found, the final design must satisfy other physical constraints such as maximum allowable heat leak and helium vapor mass flow rate. A set of corresponding lengths and diameters has been determined that meets these requirements for the helium vapor-cooled, spiral-fin power lead design of the SSC. Early efforts by McFee and Mallon investigated optimizing power leads for cryogenic applications with no convection cooling. Later designs utilized the boiled-off helium vapor to cool the lead. One notable design for currents up to several thousand amps is presented by Efferson based on a series of recommendations discussed by Deiness. Buyanov presents many theoretical models and design formulate but does not demonstrate an approach to thermally optimizing the design of a vapor-cooled lead. A method for optimizing superconducting magnet current leads is described by Maehata et al. The approach assumes that the helium boil-off caused by heat conduction along with power lead into the low-temperature helium is used to cool the lead. The optimum solution is found when the heat flow at the cold end is minimized.. In this study, a detailed numerical thermal model of a power lead design for the SSC has been developed. It was adapted from the dynamic model developed by Schiesser. This model was used to determine the optimum dimensions that minimize the Carnot refrigeration and liquefaction work due to the leads

  15. Feasibility of lunar Helium-3 mining

    Kleinschneider, Andreas; Van Overstraeten, Dmitry; Van der Reijnst, Roy; Van Hoorn, Niels; Lamers, Marvin; Hubert, Laurent; Dijk, Bert; Blangé, Joey; Hogeveen, Joel; De Boer, Lennaert; Noomen, Ron

    -3 fusion were calculated using a predicted minimum energy price in 2040 of 30.4 Euro/MWh. Annual costs are between 427.7 to 1,347.9 billion Euro, with annual expected profit ranging from -724.0 to 260.0 billion Euro. Due to the large scale of the mission, it has also been evaluated for providing 0.1% and 1% of the global energy demand in 2040. For 1%, the annual costs are 45.6 to 140.3 billion Euro and the expected annual profits are -78.0 to 23.1 billion Euro. For 0.1%, the annual costs are 7.7 to 20.5 billion Euro. The annual expected profits are -14.3 to -0.8 billion Euro. Feasibility has been addressed in three aspects. Technically, the mission is extremely challenging and complex. However, most required technologies exist or could be developed within a reasonable time span. From a political and legal perspective, the current international treaties hardly provide any framework for a lunar mining operation. Financially, the mission only produces a net profit in the best case, and only for medium- to large-scale operations, which require a very large initial investment. To make lunar Helium-3 usage possible, further research should concentrate on the mining operation and costs of fusion plants, as their impact by far outranks all other mission elements. Different transportation concepts may be investigated nevertheless. Many - not only technical - challenges concerning Helium-3 mining are still to be addressed. Although only a starting point for further investigations, this study shows that, despite popular claims, lunar Helium-3 is unsuitable to provide a significant percentage of the global energy demand in 2040.

  16. Operations aspects of the Fermilab Central Helium Liquefier facility

    Geynisman, M.G.; Makara, J.N.

    1996-09-01

    The Fermilab Central Helium Liquefier (CHL) facility consists of helium and nitrogen reliquefier plants operated 24 hours-a-day to supply LHe at 4.6 K and LN 2 for the Fermilab Tevatron superconducting proton-antiproton collider ring and to recover warm return gases. Operating aspects of CHL, including different equipment and systems reliability, availability, maintenance experience, safety concerns, and economics aspects are discussed

  17. Evaluation of US demo helium-cooled blanket options

    Wong, C.P.C.; McQuillan, B.W.; Schleicher, R.W.

    1995-10-01

    A He-V-Li blanket design was developed as a candidate for the U.S. fusion demonstration power plant. This paper presents an 18 MPa helium-cooled, lithium breeder, V-alloy design that can be coupled to the Brayton cycle with a gross efficiency of 46%. The critical issue of designing to high gas pressure and the compatibility between helium impurities and V-alloy are addressed

  18. Operations aspects of the Fermilab Central Helium Liquefier Facility

    Geynisman, M.G.; Makara, J.N.

    1995-03-01

    The Fermilab Central Helium Liquefier (CHL) facility consists of helium and nitrogen reliquefier plants operated 24 hours-a-day to supply LHe at 4.6 degrees K and LN 2 for the Fermilab Tevatron superconducting proton-antiproton collider ring and to recover warm return gases. Operating aspects of CHL, including different equipment and systems reliability, availability, maintenance experience, safety concerns, and economics aspects are discussed

  19. Report on the bituminous coal liquefaction sub-committee in fiscal 1993; 1993 nendo rekiseitan ekika bukai hokokusho

    NONE

    1994-03-01

    This paper reports the activities of the bituminous coal liquefaction sub-committee in fiscal 1993. With an intention of developing a technology on the process (NEDOL) suitable for liquefaction of wide range of coal types placing sub-bituminous coal at the center, researches were carried out by using a pilot plant, and engineering data purposed for practical application of the technology were acquired. The construction of the pilot plant, launched in fiscal 1991, will be performed under the operation research plan for efficient operation, based on the result of discussing the total project cost in fiscal 1992. The status of constructing the 150-t/d pilot plant in fiscal 1993 is in the phase of making the foundations subsequently from fiscal 1992, procurement of devices and construction materials, constructions of iron structures, installation, heat insulation, and painting, and building the central control building and piping facilities outside the battery limit. The paper also reports the tests and investigations on improving performance of natural pylite catalyst, the tests and investigations on improving performance of circulating solvent, and the technological investigations on structuring a liquefying reaction data analyzing system. For the supportive researches on the pilot plant, the paper describes studies by using a 1-t/d PSU, studies on coal liquefaction conditions, studies on synthesized iron sulfide catalysts, and studies on solvent hydrogenating catalysts. A comprehensive discussion was also given. (NEDO)

  20. Design verification and acceptance tests of the ASST-A helium refrigeration system

    Ganni, V.; Apparao, T.V.V.R.

    1993-07-01

    Three similar helium refrigerator systems have been installed at the Superconducting Super Collider Laboratory (SSCL) N15 site; the ASST-A system, which will be used for the accelerator system's full cell string test; the N15-B system, which will be used for string testing in the tunnel; and a third plant, dedicated to magnet testing at the Magnet Testing Laboratory. The ASST-A and N15-B systems will ultimately be a part of the collider's N15 sector station equipment. Each of these three systems has many subsystems, but the design basis for the main refrigerator is the same. Each system has a guaranteed capacity of 2000 W of refrigeration and 20 g/s liquefaction at 4.5K. The testing and design verification of the ASST-A refrigeration system consisted of parametric tests on the compressors and the total system. A summary of the initial performance test data is given in this paper. The tests were conducted for two cases: in the first, all four compressors were operating; in the second, only one compressor in each stage was operating. In each case, tests were conducted in three modes of operation described later on. The process design basis supplied by the manufacturers and used in the design of the main components -- the compressor, and expanders and heat exchangers for the coldbox -- were used to reduce the actual test data using process simulation methodology. In addition, the test results and the process design submitted by the manufacturer were analyzed using exergy analysis. This paper presents both the process and the exergy analyses of the manufacturer's design and the actual test data for Case 1. The process analyses are presented in the form of T-S diagrams. The results of the exergy analyses comparing the exergy losses of each component and the total system for the manufacturer's design and the test data are presented in the tables

  1. Numerical simulation of liquefaction behaviour of granular materials ...

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    cles using Discrete Element Method (DEM) is used to study the liquefaction behaviour of ... studies have focussed on the stress-strain relation- ... experimentation still remains quite problematic. ... distorting the periodic cell and changing its vol-.

  2. On the risk of liquefaction of buffer and backfill

    Pusch, R. [Geodevelopment AB, Lund (Sweden)

    2000-10-01

    The necessary prerequisites for liquefaction of buffers and backfills in a KBS-3 repository exist but the stress conditions and intended densities practically eliminate the risk of liquefaction for single earthquakes with magnitudes up to M=8 and normal duration. For buffers rich in expandable minerals it would be possible to reduce the density at water saturation to 1,700 - 1,800 kg/m{sup 3} or even less without any significant risk of liquefaction, while the density at saturation of backfills with 10 - 15% expandable clay should not be reduced to less than about 1,900 kg/m{sup 3}. Since the proposed densities of both buffers and backfills will significantly exceed these minimum values it is concluded that there is no risk of liquefaction of the engineered soil barriers in a KBS-3 repository even for very significant earthquakes.

  3. On the risk of liquefaction of buffer and backfill

    Pusch, R.

    2000-10-01

    The necessary prerequisites for liquefaction of buffers and backfills in a KBS-3 repository exist but the stress conditions and intended densities practically eliminate the risk of liquefaction for single earthquakes with magnitudes up to M=8 and normal duration. For buffers rich in expandable minerals it would be possible to reduce the density at water saturation to 1,700 - 1,800 kg/m 3 or even less without any significant risk of liquefaction, while the density at saturation of backfills with 10 - 15% expandable clay should not be reduced to less than about 1,900 kg/m 3 . Since the proposed densities of both buffers and backfills will significantly exceed these minimum values it is concluded that there is no risk of liquefaction of the engineered soil barriers in a KBS-3 repository even for very significant earthquakes

  4. Initial Earthquake Centrifuge Model Experiments for the Study of Liquefaction

    Steedman, R

    1998-01-01

    .... These are intended to gather data suitable for the development of improved design approaches for the prediction of liquefaction under earthquake loading using the new centrifuge facility at the WES...

  5. Whole Algae Hydrothermal Liquefaction: 2014 State of Technology

    Jones, Susanne B.; Zhu, Yunhua; Snowden-Swan, Lesley J.; Anderson, Daniel; Hallen, Richard T.; Schmidt, Andrew J.; Albrecht, Karl O.; Elliott, Douglas C.

    2014-07-30

    This report describes the base case yields and operating conditions for converting whole microalgae via hydrothermal liquefaction and upgrading to liquid fuels. This serves as the basis against which future technical improvements will be measured.

  6. An Advanced Wet Expansion Turbine for Hydrogen Liquefaction, Phase I

    National Aeronautics and Space Administration — This proposal is responsive to NASA SBIR Topic X10.01, specifically, the need for efficient small- to medium-scale hydrogen liquefaction technologies including...

  7. Technical and economic aspects of brown coal gasification and liquefaction

    Speich, P.

    1980-01-01

    A number of gasification and liquefaction processes for Rhenish brown coal are investigated along with the technical and economic aspects of coal beneficiation. The status of coal beneficiation and the major R + D activities are reviewed. (orig.) [de

  8. Assessment of Soil Liquefaction Potential Based on Numerical Method

    Choobasti, A. Janalizadeh; Vahdatirad, Mohammad Javad; Torabi, M.

    2012-01-01

    Paying special attention to geotechnical hazards such as liquefaction in huge civil projects like urban railways especially in susceptible regions to liquefaction is of great importance. A number of approaches to evaluate the potential for initiation of liquefaction, such as Seed and Idriss...... simplified method have been developed over the years. Although simplified methods are available in calculating the liquefaction potential of a soil deposit and shear stresses induced at any point in the ground due to earthquake loading, these methods cannot be applied to all earthquakes with the same...... accuracy, also they lack the potential to predict the pore pressure developed in the soil. Therefore, it is necessary to carry out a ground response analysis to obtain pore pressures and shear stresses in the soil due to earthquake loading. Using soil historical, geological and compositional criteria...

  9. Advanced direct liquefaction concepts for PETC generic units

    1992-04-01

    In the Advance Coal Liquefaction Concept Proposal (ACLCP) carbon monoxide (CO) and water have been proposed as the primary reagents in the pretreatment process. The main objective of this project is to develop a methodology for pretreating coal under mild conditions based on a combination of existing processes which have shown great promise in liquefaction, extraction and pyrolysis studies. The aim of this pretreatment process is to partially depolymerise the coal, eliminate oxygen and diminish the propensity for retograde reactions during subsequent liquefaction. The desirable outcome of the CO pretreatment step should be: (1) enhanced liquefaction activity and/or selectivity toward products of higher quality due to chemical modification of the coal structure; (2) cleaner downstream products; (3) overall improvement in operability and process economics.

  10. New method for evaluating liquefaction potential

    Arulmoli, K.; Arulanandan, K.; Seed, H.B.

    1985-01-01

    A new method of indexing the grain and aggregate properties of sand using electrical parameters is described. Correlations are established between these parameters and relative density, D /sub r/ , cyclic stress ratio, /tau//sigma'/sub 0/, and K2 /sub max/ . An electrical probe, used to predict these parameters from in-situ electrical measurements, is described. Evaluations are made of D /sub r/ and /tau//sigma/sub 0/, which are compared with values measured independently from controlled laboratory tests. Reasonable agreement is found between predicted and measured values. The potential applicability of the electrical probe in the field is shown by evaluation of liquefaction and nonliquefaction at sites affected by the 1906 San Francisco, Niigata and Tangshan earthquakes.

  11. Potential of soil liquefaction at Perlis, northern region of Malalysia

    Ghazaly, Zuhayr Md; Rahim, Mustaqqim Abdul; Nasir, Mohamad Amzar Bin Mhd; Isa, Nur Fitriah; Zaki, Mohd Faiz Mohammad; Hassan, Zulkarnain Bin; Ismail, Zul-Atfi Bin

    2017-09-01

    Soil liquefaction is earthquake's secondary effect which could cause fatal damages and structures instability. Despite Malaysia been located in stable zone of Pacific Ring of Fire, few significant surrounded quakes like Sumatra-Andaman earthquake had prompted Malaysian's public concern, especially in Perlis area, on local seismic resistant. Hence, this research presents the analysis result of liquefaction potential of the soils, as the secondary effect of earthquake, within Perlis, northern region of Malaysia; the next strong and sustainable metropolis by using semi-empirical procedures introduced by Seed and Idriss. The study consists of two stages which were determination of the local geological and geotechnical site conditions within Perlis and analysis of soil liquefaction susceptibility by using various methods and liquefaction potential by using Simplified Procedure developed by Seed and Idriss on stress approach. There were consist of four phases implemented in order to achieve the objectives targeted for the study after problem being identified. Firstly, a comprehensive review of literature on liquefaction at Perlis was carried out. Second phase was data collection process that includes collection of Site Investigation (SI) report. Thirdly, data analysis was carried out by utilizing suitable method. The final phase was to draw conclusion and recommendation for this study. It can be concluded that the overall Perlis due to earthquake moment magnitude below 7.5 has no potential to soil liquefaction. However, with the range of liquefaction potential of 1.60 to 5.64 in Kuala Perlis area, it is liquefiable. The development of liquefaction severity map of Perlis, Malaysia in this research, may be used by others as a reference for seismic design and standard safety measures as well as for further research work.

  12. Liquefaction Potential for Soil Deposits in Muscat, Oman

    El Hussain, I. W.; Deif, A.; Girgis, M.; Al-Rawas, G.; Mohamed, A.; Al-Jabri, K.; Al-Habsi, Z.

    2015-12-01

    Muscat is located in the northeastern part of Oman on a narrow strip between Oman coast and Oman Mountains, which is the place for at least four earthquakes of order of 5.2 magnitude in the last 1300 years. The near surface geology of Muscat varies from hard rocks in the eastern, southern and western parts to dense and lose sediments in the middle and northern parts. Liquefaction occurs in saturated cohesionless soils when its shear strength decreased to zero due to the increase of pore pressure. More than 500 boreholes in Muscat area were examined for their liquefaction susceptibility based on the soil characteristics data. Only soils susceptible to liquefaction are further considered for liquefaction hazard assessment. Liquefaction occurs if the cyclic stress ratio (CSR) caused by the earthquake is higher than the cyclic resistance ratio (CRR) of the soil. CSR values were evaluated using PGA values at the surface obtained from previously conducted seismic hazard and microzonation studies. CRR for Muscat region is conducted using N values of SPT tests from numerous borehole data and the shear wave velocity results from 99 MASW surveys over the entire region. All the required corrections are conducted to get standardized (N1) 60 values, to correct shear-wave velocity, and scale the results for Mw 6.0 instead of the proposed 7.5 (magnitude scaling factor). Liquefaction hazard maps are generated using the minimum factor of safety (FS) at each site as a representative of the FS against liquefaction at that location. Results indicate that under the current level of seismic hazard, liquefaction potential is possible at few sites along the northern coast where alluvial soils and shallow ground water table are present. The expected soft soil settlement is also evaluated at each liquefiable site.

  13. Neutral helium beam probe

    Karim, Rezwanul

    1999-10-01

    This article discusses the development of a code where diagnostic neutral helium beam can be used as a probe. The code solves numerically the evolution of the population densities of helium atoms at their several different energy levels as the beam propagates through the plasma. The collisional radiative model has been utilized in this numerical calculation. The spatial dependence of the metastable states of neutral helium atom, as obtained in this numerical analysis, offers a possible diagnostic tool for tokamak plasma. The spatial evolution for several hypothetical plasma conditions was tested. Simulation routines were also run with the plasma parameters (density and temperature profiles) similar to a shot in the Princeton beta experiment modified (PBX-M) tokamak and a shot in Tokamak Fusion Test Reactor tokamak. A comparison between the simulation result and the experimentally obtained data (for each of these two shots) is presented. A good correlation in such comparisons for a number of such shots can establish the accurateness and usefulness of this probe. The result can possibly be extended for other plasma machines and for various plasma conditions in those machines.

  14. Antiprotonic helium atomcules

    Sauge Sébastien

    2012-10-01

    Full Text Available About 3% of antiprotons ( stopped in helium are long-lived with microsecond lifetimes, against picoseconds in all other materials. This unusual longevity has been ascribed to the trapping of on metastable bound states in He+ helium atom-molecules thus named atomcules. Apart from their unique dual structure investigated by laser spectroscopy – a near-circular quasi-classical Rydberg atom with l ~ n – 1 ~ 37 or a special diatomic molecule with a negatively charged nucleus in high rotational state with J = l – the chemical physics aspects of their interaction with other atoms or molecules constitute an interesting topic for molecular physics. While atomcules may resist to million collisions in helium, molecular contaminants such as H2 are likely to destroy them in a single one, down to very low temperatures. In the Born-Oppenheimer framework, we interpret the molecular interaction obtained by ab initio quantum chemical calculations in terms of classical reactive channels, with activation barriers accounting for the experiments carried out in He and H2. From classical trajectory Monte Carlo simulations, we show that the thermalization stage strongly quenches initial populations, thus reduced to a recovered 3 % trapping fraction. This work illustrates the pertinence of chemical physics concepts to the study of exotic processes involving antimatter. New insights into the physico-chemistry of cold interstellar radicals are anticipated.

  15. Mongolian coal liquefaction test; Mongorutan no ekika tokusei

    Yamamoto, H.; Kubo, H. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Tsedevsuren, T. [National Research Center of Chemistry and Technology of Coal in Mongoria (Mongolia)

    1996-10-28

    This paper describes the results of liquefaction tests of Mongolian coals using an autoclave and a flow micro reactor. Uvdughudag coal, Hootiinhonhor coal, and Shivee-Ovoo coal were used for liquefaction tests with an autoclave. Oil yields of Uvdughudag and Hootiinhonhor coals were 55.56 wt% and 55.29 wt%, respectively, which were similar to that of Wyoming coal. Similar results were obtained, as to produced gas and water yields. These coals were found to be suitable for coal liquefaction. Lower oil yield, 42.55 wt% was obtained for Shivee-Ovoo coal, which was not suitable for liquefaction. Liquefaction tests were conducted for Uvdughudag coal with a flow micro reactor. The oil yield was 55.7 wt%, which was also similar to that of Wyoming coal, 56.1 wt%. Hydrogen consumption of Uvdughudag coal was also similar to that of Wyoming coal. From these, Uvdughudag coal can be a prospective coal for liquefaction. From the distillation distribution of oil, distillate fraction yield below 350{degree}C of Uvdughudag coal was 50.7 wt%, which was much higher than that of Wyoming coal, 35.6 wt%. Uvdughudag coal is a coal with high light oil fraction yield. 2 figs., 5 tabs.

  16. U.S. DOE indirect coal liquefaction program: An overview

    Shen, J.; Schmetz, E.; Winslow, J.; Tischer, R. [Dept. of Energy, Germantown, MD (United States); Srivastava, R.

    1997-12-31

    Coal is the most abundant domestic energy resource in the United States. The Fossil Energy Organization within the US Department of Energy (DOE) has been supporting a coal liquefaction program to develop improved technologies to convert coal to clean and cost-effective liquid fuels to complement the dwindling supply of domestic petroleum crude. The goal of this program is to produce coal liquids that are competitive with crude at $20 to $25 per barrel. Indirect and direct liquefaction routes are the two technologies being pursued under the DOE coal liquefaction program. This paper will give an overview of the DOE indirect liquefaction program. More detailed discussions will be given to the F-T diesel and DME fuels which have shown great promises as clean burning alternative diesel fuels. The authors also will briefly discuss the economics of indirect liquefaction and the hurdles and opportunities for the early commercial deployment of these technologies. Discussions will be preceded by two brief reviews on the liquid versus gas phase reactors and the natural gas versus coal based indirect liquefaction.

  17. Indirect coal liquefaction - the first commercial CTL project in the USA

    Radtke, K.; Battensby, D.; Marsico, C.; Hooper, M.; Mather, C. [Uhde GmbH (Germany)

    2006-07-01

    The polygeneration of fuels, chemical and power offers an innovative and economically advantageous way to utilise disadvantaged fuels, such as lignite, waste coal and petroleum coke, in a coal-to-liquids (CTL) plant by means of integration of three main process blocks: gasification island to convert coal into clean synthesis gas; Fischer-Tropsch synthesis to convert synthesis gas into clean liquid fuels and chemicals; and combustion of synthesis gas to produce electric power and steam. This paper describes the process and technology side of this indirect coal liquefaction project with key plant data that has been elaborated for a commercial scale CTL project, which is expected to be the first CTL plant in the USA. The plant will use the Shell Coal Gasification process. 6 figs.

  18. Surface electrons of helium films

    Studart, N.; Hipolito, O.

    1986-01-01

    Theoretical calculations of some properties of two-dimensional electrons on a liquid helium film adsorbed on a solid substrate are reviewed. We describe the spectrum of electron bound states on bulk helium as well on helium films. The correlational properties, such as the structure factor and correlation energy, are determined as functions of the film thickness for different types of substrates in the framework of a Generalized Random-Phase Approximation. The collective excitations of this system are also described. The results for electrons on the surface of thin films and bulk helium are easily obtained. we examine the electron interaction with the excitations of the liquid helium surface resulting in a new polaron state, which was observed very recently. The ground state energy and the effective mass of this polaron are determined by using the path-integral formalism and unitary-transformation method. Recent speculations about the phase diagram of electrons on the helium film are also discussed. (Author) [pt

  19. Coal liquefaction process streams characterization and evaluation: Application of liquid chromatographic separation methods to THF-soluble portions of integrated two-stage coal liquefaction resids

    Green, J.B.; Pearson, C.D.; Young, L.L.; Green, J.A. [National Inst. for Petroleum and Energy Research, Bartlesville, OK (United States)

    1992-05-01

    This study demonstrated the feasibility of using non-aqueous ion exchange liquid chromatography (NIELC) for the examination of the tetrahydrofuran (THF)-soluble distillation resids and THF-soluble whole oils derived from direct coal liquefaction. The technique can be used to separate the material into a number of acid, base, and neutral fractions. Each of the fractions obtained by NIELC was analyzed and then further fractionated by high-performance liquid chromatography (HPLC). The separation and analysis schemes are given in the accompanying report. With this approach, differences can be distinguished among samples obtained from different process streams in the liquefaction plant and among samples obtained at the same sampling location, but produced from different feed coals. HPLC was directly applied to one THF-soluble whole process oil without the NIELC preparation, with limited success. The direct HPLC technique used was directed toward the elution of the acid species into defined classes. The non-retained neutral and basic components of the oil were not analyzable by the direct HPLC method because of solubility limitations. Sample solubility is a major concern in the application of these techniques.

  20. Effects of Long-Duration Ground Motions on Liquefaction Hazards

    Greenfield, Michael W.

    Soil liquefaction during past earthquakes has caused extensive damage to buildings, bridges, dam, pipelines and other elements of infrastructure. Geotechnical engineers use empirical observations from earthquake case histories in conjunction with soil mechanics to predict the behavior of liquefiable soils. However, current empirical databases are insufficient to evaluate the behavior of soils subject to long-duration earthquakes, such as a possible Mw = 9.0 Cascadia Subduction Zone earthquake. The objective of this research is to develop insight into the triggering and effects of liquefaction due to long-duration ground motions and to provide recommendations for analysis and design. Recorded ground motions from 21 case histories with surficial evidence of liquefaction showed marked differences in soil behavior before and after liquefaction was triggered. In some cases, strong shaking continued for several minutes after the soil liquefied, and a variety of behaviors were observed including dilation pulses, continued softening due to soil fabric degradation, and soil stiffening due to pore pressure dissipation and drainage. Supplemental field and laboratory investigations were performed at three sites that liquefied during the 2011 Mw = 9.0 Tohoku earthquake. The recorded ground motions and field investigation data were used in conjunction with laboratory observations, analytical models, and numerical models to evaluate the behavior of liquefiable soils subjected to long-duration ground motions. Observations from the case histories inspired a framework to predict ground deformations based on the differences in soil behavior before and after liquefaction has triggered. This framework decouples the intensity of shaking necessary to trigger liquefaction from the intensity of shaking that drives deformation by identifying the time when liquefaction triggers. The timing-based framework promises to dramatically reduce the uncertainty in deformation estimates compared to

  1. Sinking during earthquakes: Critical acceleration criteria control drained soil liquefaction

    Clément, C.; Toussaint, R.; Stojanova, M.; Aharonov, E.

    2018-02-01

    This article focuses on liquefaction of saturated granular soils, triggered by earthquakes. Liquefaction is defined here as the transition from a rigid state, in which the granular soil layer supports structures placed on its surface, to a fluidlike state, in which structures placed initially on the surface sink to their isostatic depth within the granular layer. We suggest a simple theoretical model for soil liquefaction and show that buoyancy caused by the presence of water inside a granular medium has a dramatic influence on the stability of an intruder resting at the surface of the medium. We confirm this hypothesis by comparison with laboratory experiments and discrete-element numerical simulations. The external excitation representing ground motion during earthquakes is simulated via horizontal sinusoidal oscillations of controlled frequency and amplitude. In the experiments, we use particles only slightly denser than water, which as predicted theoretically increases the effect of liquefaction and allows clear depth-of-sinking measurements. In the simulations, a micromechanical model simulates grains using molecular dynamics with friction between neighbors. The effect of the fluid is captured by taking into account buoyancy effects on the grains when they are immersed. We show that the motion of an intruder inside a granular medium is mainly dependent on the peak acceleration of the ground motion and establish a phase diagram for the conditions under which liquefaction happens, depending on the soil bulk density, friction properties, presence of water, and peak acceleration of the imposed large-scale soil vibrations. We establish that in liquefaction conditions, most cases relax toward an equilibrium position following an exponential in time. We also show that the equilibrium position itself, for most liquefaction regimes, corresponds to the isostatic equilibrium of the intruder inside a medium of effective density. The characteristic time to relaxation is

  2. Orion A helium abundance

    Tsivilev, A.P.; Ershov, A.A.; Smirnov, G.T.; Sorochenko, R.L.

    1986-01-01

    The 22.4-GHz (H,He)66-alpha and 36.5-GHz (H,He)56-alpha radio recombination lines have been observed at several Jaffe-Pankonin positions in the central part of the Orion A source. The measured relative abundance of ionized helium increases with distance, averaging 11.6 percent at peripheral points. The observed behavior is interpreted by a blister-type model nebula, which implies that Orion A has a true He abundance of 12 percent, is moving with a radial velocity of 5 km/sec, and is expanding. 18 references

  3. Simulation of liquid helium

    Ceperley, D.M.

    1985-07-01

    The author discusses simulation methods for quantum mechanical systems at finite temperatures. Recently it has been shown that static properties of some quantum systems can be obtained by simulation in a straightforward manner using path integrals, albeit with an order of magnitude more computing effort needed than for the corresponding classical systems. Some dynamical information can be gleaned from these simulations as will be discussed below. But this is very limited - there is no quantum version of the molecular dynamics method. The path integral method is illustrated by discussing the application to liquid helium. 12 refs., 8 figs

  4. Summary of the research achievements in fiscal 1988. Development of coal liquefaction technologies; Sekitan ekika gijutsu kaihatsu. 1988 nendo kenkyu seika no gaiyo

    NONE

    1989-03-01

    This paper reports the summary of the research and development works in fiscal 1988. The following researches were carried out: as development of a bituminous coal liquefaction technology, studies by using a pilot plant, studies on support of the pilot plant (studies by using an experimental plant (studies by using a 1-t/d PSU, development of an optimal pretreatment technology for coals to be used for liquefaction, studies on improvement in fraction oil distribution in the NEDOL process, and studies by using a 1-t/d plant)), and (studies by using a small device (studies on coal liquefying conditions, and studies on solvent hydrogenation catalysts)). Studies were carried out on operation of the pilot plant, and on support of the pilot plant operation. Materials for auxiliary machinery were developed (including in-plant test of new materials), and so were the devices (including development of a let-down valve) as trial fabrication and development of the plant devices and materials. As coal type selection and survey, coal types were surveyed, and liquefaction performance of Chinese coals was tested. In order to develop applications of coal liquefied products and a refining technology, developments were carried out on up-grading of the coal liquefied oil, a petroleum mixing technology, and a technology to separate hetero compounds in coal liquefied oil, and applications of the compounds. (NEDO)

  5. High Efficiency Regenerative Helium Compressor, Phase I

    National Aeronautics and Space Administration — Helium plays several critical rolls in spacecraft propulsion. High pressure helium is commonly used to pressurize propellant fuel tanks. Helium cryocoolers can be...

  6. Perspectives on Lunar Helium-3

    Schmitt, Harrison H.

    1999-01-01

    Global demand for energy will likely increase by a factor of six or eight by the mid-point of the 21st Century due to a combination of population increase, new energy intensive technologies, and aspirations for improved standards of living in the less-developed world (1). Lunar helium-3 (3He), with a resource base in the Tranquillitatis titanium-rich lunar maria (2,3) of at least 10,000 tonnes (4), represents one potential energy source to meet this rapidly escalating demand. The energy equivalent value of 3He delivered to operating fusion power plants on Earth would be about 3 billion per tonne relative to today's coal which supplies most of the approximately 90 billion domestic electrical power market (5). These numbers illustrate the magnitude of the business opportunity. The results from the Lunar Prospector neutron spectrometer (6) suggests that 3He also may be concentrated at the lunar poles along with solar wind hydrogen (7). Mining, extraction, processing, and transportation of helium to Earth requires new innovations in engineering but no known new engineering concepts (1). By-products of lunar 3He extraction, largely hydrogen, oxygen, and water, have large potential markets in space and ultimately will add to the economic attractiveness of this business opportunity (5). Inertial electrostatic confinement (IEC) fusion technology appears to be the most attractive and least capital intensive approach to terrestrial fusion power plants (8). Heavy lift launch costs comprise the largest cost uncertainty facing initial business planning, however, many factors, particularly long term production contracts, promise to lower these costs into the range of 1-2000 per kilogram versus about 70,000 per kilogram fully burdened for the Apollo Saturn V rocket (1). A private enterprise approach to developing lunar 3He and terrestrial IEC fusion power would be the most expeditious means of realizing this unique opportunity (9). In spite of the large, long-term potential

  7. A helium regenerative compressor

    Swift, W.L.; Nutt, W.E.; Sixsmith, H.

    1994-01-01

    This paper discusses the design and performance of a regenerative compressor that was developed primarily for use in cryogenic helium systems. The objectives for the development were to achieve acceptable efficiency in the machine using conventional motor and bearing technology while reducing the complexity of the system required to control contamination from the lubricants. A single stage compressor was built and tested. The compressor incorporates aerodynamically shaped blades on a 218 mm (8.6 inches) diameter impeller to achieve high efficiency. A gas-buffered non-contact shaft seal is used to oppose the diffusion of lubricant from the motor bearings into the cryogenic circuit. Since it is a rotating machine, the flow is continuous and steady, and the machine is very quiet. During performance testing with helium, the single stage machine has demonstrated a pressure ratio of 1.5 at a flow rate of 12 g/s with measured isothermal efficiencies in excess of 30%. This performance compares favorably with efficiencies generally achieved in oil flooded screw compressors

  8. Catalytic multi-stage liquefaction (CMSL)

    Comolli, A.G.; Ganguli, P.; Karolkiewicz, W.F.; Lee, T.L.K.; Pradhan, V.R.; Popper, G.; Smith, T.; Stalzer, R.H.

    1996-11-01

    Reported herein are the details and the results of laboratory and bench scale experiments that were conducted at Hydrocarbon Technologies, Inc. under DOE Contract No. DE-AC22-93PC92147 during the period of October 1, 1992, to December 31, 1995. The program results described herein build on the previous technology base and investigating additional methods to improve the economics of producing transportation fuels from coal. This included purely physical parameters, coal treatment and variation in solvent to coal ratio, the use of syngas to replace part of the hydrogen as the reducing gas, the use of dispersed catalyst in addition to and replacing the supported catalyst, and the co-processing of coal with plastic waste material. The overall objective of this program is to produce liquid fuels from direct coal liquefaction at a cost that is competitive with conventional fuels. The report includes the results of an economic assessment of the various process strategies that were evaluated during this program. A summary of the technical/economic evaluations is given in Volume I, Section II of this report. The experimental details of the eleven run of the program are given in Volume I, Section III and Volume II of this report. The details of the technical evaluations are given in the Volume III of the report.

  9. Hydrothermal Liquefaction Treatment Hazard Analysis Report

    Lowry, Peter P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wagner, Katie A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-09-12

    Hazard analyses were performed to evaluate the modular hydrothermal liquefaction treatment system. The hazard assessment process was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. The analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public. The following selected hazardous scenarios received increased attention: •Scenarios involving a release of hazardous material or energy, controls were identified in the What-If analysis table that prevent the occurrence or mitigate the effects of the release. •Scenarios with significant consequences that could impact personnel outside the immediate operations area, quantitative analyses were performed to determine the potential magnitude of the scenario. The set of “critical controls” were identified for these scenarios (see Section 4) which prevent the occurrence or mitigate the effects of the release of events with significant consequences.

  10. Helium production in reactor materials

    Lippincott, E.P.; McElroy, W.N.; Farrar, H. IV.

    1975-02-01

    Comparisons of integral helium production measurements with predictions based on ENDF/B Version IV cross sections have been made. It is concluded that an ENDF/B helium production cross section file should be established in order to ensure a complete and consistent cross section evaluation to meet accuracies required for LMFBR, CTR, and LWR applications. (U.S.)

  11. Assessment of liquefaction potential during earthquakes by arias intensity

    Kayen, R.E.; Mitchell, J.K.

    1997-01-01

    An Arias intensity approach to assess the liquefaction potential of soil deposits during earthquakes is proposed, using an energy-based measure of the severity of earthquake-shaking recorded on seismograms of the two horizontal components of ground motion. Values representing the severity of strong motion at depth in the soil column are associated with the liquefaction resistance of that layer, as measured by in situ penetration testing (SPT, CPT). This association results in a magnitude-independent boundary that envelopes initial liquefaction of soil in Arias intensity-normalized penetration resistance space. The Arias intensity approach is simple to apply and has proven to be highly reliable in assessing liquefaction potential. The advantages of using Arias intensity as a measure of earthquake-shaking severity in liquefaction assessment are: Arias intensity is derived from integration of the entire seismogram wave form, incorporating both the amplitude and duration elements of ground motion; all frequencies of recorded motion are considered; and Arias intensity is an appropriate measure to use when evaluating field penetration test methodologies that are inherently energy-based. Predictor equations describing the attenuation of Arias intensity as a function of earthquake magnitude and source distance are presented for rock, deep-stiff alluvium, and soft soil sites.

  12. Energy-based numerical models for assessment of soil liquefaction

    Amir Hossein Alavi

    2012-07-01

    Full Text Available This study presents promising variants of genetic programming (GP, namely linear genetic programming (LGP and multi expression programming (MEP to evaluate the liquefaction resistance of sandy soils. Generalized LGP and MEP-based relationships were developed between the strain energy density required to trigger liquefaction (capacity energy and the factors affecting the liquefaction characteristics of sands. The correlations were established based on well established and widely dispersed experimental results obtained from the literature. To verify the applicability of the derived models, they were employed to estimate the capacity energy values of parts of the test results that were not included in the analysis. The external validation of the models was verified using statistical criteria recommended by researchers. Sensitivity and parametric analyses were performed for further verification of the correlations. The results indicate that the proposed correlations are effectively capable of capturing the liquefaction resistance of a number of sandy soils. The developed correlations provide a significantly better prediction performance than the models found in the literature. Furthermore, the best LGP and MEP models perform superior than the optimal traditional GP model. The verification phases confirm the efficiency of the derived correlations for their general application to the assessment of the strain energy at the onset of liquefaction.

  13. Seismic behavior of breakwaters on complex ground by numerical tests: Liquefaction and post liquefaction ground settlements

    Gu, Linlin; Zhang, Feng; Bao, Xiaohua; Shi, Zhenming; Ye, Guanlin; Ling, Xianzhang

    2018-04-01

    A large number of breakwaters have been constructed along coasts to protect humans and infrastructures from tsunamis. There is a risk that foundation soils of these structures may liquefy, or partially liquefy during the earthquake preceding a tsunami, which would greatly reduce the structures' capacity to resist the tsunami. It is necessary to consider not only the soil's liquefaction behavior due to earthquake motions but also its post-liquefaction behavior because this behavior will affect the breakwater's capacity to resist an incoming tsunami. In this study, numerical tests based on a sophisticated constitutive model and a soil-water coupled finite element method are used to predict the mechanical behavior of breakwaters and the surrounding soils. Two real breakwaters subjected to two different seismic excitations are examined through numerical simulation. The simulation results show that, earthquakes affect not only the immediate behavior of breakwaters and the surrounding soils but also their long-term settlements due to post-earthquake consolidation. A soil profile with thick clayey layers beneath liquefied soil is more vulnerable to tsunami than a soil profile with only sandy layers. Therefore, quantitatively evaluating the seismic behavior of breakwaters and surrounding soils is important for the design of breakwater structures to resist tsunamis.

  14. Optimization for microwave-assisted direct liquefaction of bamboo residue in glycerol/methanol mixtures

    Jiulong Xie; Jinqiu Qi; Chungyun Hse; Todd F. Shupe

    2015-01-01

    Bamboo residues were liquefied in a mixture of glycerol and methanol in the presence of sulfuric acid using microwave energy. We investigated the effects of liquefaction conditions, including glycerol/methanol ratio, liquefaction temperature, and reaction time on the conversion yield. The optimal liquefaction conditions were under the temperature of 120

  15. Liquefaction behaviors of bamboo residues in a glycerol-based solvent using microwave energy

    Jiulong Xie; Chung-Yun Hse; Todd F. Shupe; Jinqiu Qi; Hui Pan

    2014-01-01

    Liquefaction of bamboo was performed in glycerol–methanol as co-solvent using microwave energy and was evaluated by characterizing the liquefied residues. High efficiency conversion of bamboo was achieved under mild reaction conditions. Liquefaction temperature and time interacted to affect the liquefaction reaction. Fourier transform infrared analyzes of the residues...

  16. Helium behaviour in nuclear glasses

    Fares, T.

    2011-01-01

    The present thesis focuses on the study of helium behavior in R7T7 nuclear waste glass. Helium is generated by the minor actinides alpha decays incorporated in the glass matrix. Therefore, four types of materials were used in this work. These are non radioactive R7T7 glasses saturated with helium under pressure, glasses implanted with 3 He + ions, glasses doped with curium and glasses irradiated in nuclear reactor. The study of helium solubility in saturated R7T7 glass has shown that helium atoms are inserted in the glass free volume. The results yielded a solubility of about 10 16 at. cm -3 atm. -1 . The incorporation limit of helium in this type of glass has been determined; its value amounted to about 2*10 21 at. cm -3 , corresponding to 2.5 at.%. Diffusion studies have shown that the helium migration is controlled by the single population dissolved in the glass free volume. An ideal diffusion model was used to simulate the helium release data which allowed to determine diffusion coefficients obeying to the following Arrhenius law: D = D 0 exp(-E a /kBT), where D 0 = 2.2*10 -2 and 5.4*10 -3 cm 2 s -1 and E a = 0.61 eV for the helium saturated and the curium doped glass respectively. These results reflect a thermally activated diffusion mechanism which seems to be not influenced by the glass radiation damage and helium concentrations studied in the present work (up to 8*10 19 at. g -1 , corresponding to 0.1 at.%). Characterizations of the macroscopic, structural and microstructural properties of glasses irradiated in nuclear reactor did not reveal any impact associated with the presence of helium at high concentrations. The observed modifications i.e. a swelling of 0.7 %, a decrease in hardness by 38 %, an increase between 8 and 34 % of the fracture toughness and a stabilization of the glass structure under irradiation, were attributed to the glass nuclear damage induced by the irradiation in reactor. Characterizations by SEM and TEM of R7T7 glasses implanted

  17. Hydrothermal liquefaction of microalgae to produce biofuels: state of the art and future prospects

    Vlaskin, M. S.; Chernova, N. I.; Kiseleva, S. V.; Popel', O. S.; Zhuk, A. Z.

    2017-09-01

    The article presents a review of the state of the art and lines of research on hydrothermal liquefaction (HTL) of microalgae (MA). The main advantages of this technology for production of biofuel are that it does not require predrying of the feedstock and ensures a relatively high product yield—the ratio of the end product weight to the feedstock weight—owing to the fact that all the microalgal components, viz., lipids, proteins, and carbohydrates, are converted into biofuel. MA hydrothermal liquefaction is considered to be a promising technology for conversion of biomass and is a subject of a series of research studies and, judging by the available publications, the scope of research in this field is expanding currently. However, many significant problems remain unsolved. In particular, an active searched is being conducted for suitable strains that will ensure not only a high lipid yield—necessary to convert microalgae into biodiesel—but also higher biomass productivity and a higher biofuel yield; the chemical reactions that occur during the hydrothermal treatment are being studied; and the effect of significant process variables, such as temperature, heating rate, holdup time at the maximum temperature, biomass concentration in the water suspension, biochemical and elemental compositions of the microalgae, use of catalysts, etc., on the liquefaction processes is being studied. One of the urgent tasks is also the reduction of the nitrogen content in the resulting biofuel. Studies aimed at the development of a continuous process and rational heat-processing plants for thermal microalgal conversion are being conducted to increase the energy efficiency of the HTL process, in particular, to provide the heat recovery and separation of the end product.

  18. Gas turbine modular helium reactor in cogeneration

    Leon de los Santos, G.

    2009-10-01

    This work carries out the thermal evaluation from the conversion of nuclear energy to electric power and process heat, through to implement an outline gas turbine modular helium reactor in cogeneration. Modeling and simulating with software Thermo flex of Thermo flow the performance parameters, based on a nuclear power plant constituted by an helium cooled reactor and helium gas turbine with three compression stages, two of inter cooling and one regeneration stage; more four heat recovery process, generating two pressure levels of overheat vapor, a pressure level of saturated vapor and one of hot water, with energetic characteristics to be able to give supply to a very wide gamma of industrial processes. Obtaining a relationship heat electricity of 0.52 and efficiency of net cogeneration of 54.28%, 70.2 MW net electric, 36.6 MW net thermal with 35% of condensed return to 30 C; for a supplied power by reactor of 196.7 MW; and with conditions in advanced gas turbine of 850 C and 7.06 Mpa, assembly in a shaft, inter cooling and heat recovery in cogeneration. (Author)

  19. Liquefaction under drained condition, from the lab to reality ?

    Clément, Cécile; Aharonov, Einat; Stojanova, Menka; Toussaint, Renaud

    2015-04-01

    Liquefaction constitutes a significant natural hazard in relation to earthquakes and landslides. This effect can cause buildings to tilt or sink into the soil, mud-volcanoes, floatation of buried objects, long-runout landslides, etc. In this work we present a new understanding regarding the mechanism by which buildings sink and tilt during liquefaction caused by earthquakes. Conventional understanding of liquefaction explains most observed cases as occurring in an undrained, under-compacted, layer of sandy soil saturated with water [1]: According to that understanding, the under compacted sandy layer has the tendency to compact when a load is applied. In our case the load comes from ground shaking during an earthquake. When the soil compacts, the fluid pore pressure rises. Because in undrained conditions the fluid cannot flow out, the pore pressure builds up. The weight of buildings is in this case transferred from the grains of the soil to the pore water. The soil loses its rigidity and it flows like a liquid. From this model scientists made theoretical and empirical laws for geotechnical use and buildings construction. Despite the success of this conventional model in many cases, liquefied soils were also observed under drained conditions, and in previously compacted soils, which doesn't agree with the assumption of the model quoted above. One of the famous liquefaction events is the Kobe port destruction during the 1995 earthquake. A simple calculation of the Deborah number following Goren et al ([2][3]) shows that the undrained constraint was not met below the Kobe port during the 1995 earthquake. We propose another model, of liquefaction in drained granular media. According to our model the mere presence of water in granular media is enough to cause liquefaction during an earthquake, provided that the water reaches close to the surface. Our computations are based on the buoyancy force, and we take into account the static fluid pressure only. For small

  20. The sequence of sediment behaviour during wave-induced liquefaction

    Sumer, B. Mutlu; Hatipoglu, Figen; Fredsøe, Jørgen

    2006-01-01

    to be in agreement with recent centrifuge wave-tank experiments. As for the final stage of the sequence of processes (formation of ripples), the ripple steepness (normalized with the angle of repose) for sediment with liquefaction history is found to be the same as that in sediment with no liquefaction history.......This paper presents the results of an experimental investigation of the complete sequence of sediment behaviour beneath progressive waves. The sediment was silty with d(50) = 0.060 mm. Two kinds of measurements were carried out: pore-water pressure measurements (across the sediment depth...... of liquefaction and compaction fronts in the sediment and (iii) the characteristics of the orbital motion of the liquefied sediment including the motion of the interface between the water body and the sediment. The ranges of the various quantities in the tests were: wave height, H = 9-17 cm, wave period, T = 1...

  1. Ground motions estimates for a cascadia earthquake from liquefaction evidence

    Dickenson, S.E.; Obermeier, S.F.

    1998-01-01

    Paleoseismic studies conducted in the coastal regions of the Pacific Northwest in the past decade have revealed evidence of crustal downdropping and subsequent tsunami inundation, attributable to a large earthquake along the Cascadia subduction zone which occurred approximately 300 years ago, and most likely in 1700 AD. In order to characterize the severity of ground motions from this earthquake, we report on results of a field search for seismically induced liquefaction features. The search was made chiefly along the coastal portions of several river valleys in Washington, rivers along the central Oregon coast, as well as on islands in the Columbia River of Oregon and Washington. In this paper we focus only on the results of the Columbia River investigation. Numerous liquefaction features were found in some regions, but not in others. The regional distribution of liquefaction features is evaluated as a function of geologic and geotechnical factors at each site in order to estimate the intensity of ground shaking.

  2. Photoionization of helium dimers

    Havermeier, Tilo

    2010-01-01

    The helium dimer is one of the most weakly bound systems in the universe. This makes it an interesting quantum mechanical object for investigation. These Van der Waals Clusters can be produced in an expansion of a cryogenic gas jet through a small nozzle into vacuum. In the present experiment we examine the interaction of He dimers with synchrotron radiation at an energy range from 64 to 78 eV. We observed different pathways leading to single ionization of both He atoms of the dimer compound. This two close standing ions begin now to dissociate in cause of their coulomb potential. All charged fragments were detected in coincidence with a COLTRIMS system. Especially Interatomic Coulombic Decay (ICD) and the two step process (TS1) were clearly identified. Furthermore a distribution of the internuclear distance was obtained from the measured Kinetic Energy Release (KER). (orig.)

  3. Exotic helium molecules

    Portier, M.

    2007-12-01

    We study the photo-association of an ultracold cloud of magnetically trapped helium atoms: pairs of colliding atoms interact with one or two laser fields to produce a purely long range 4 He 2 (2 3 S 1 -2 3 P 0 ) molecule, or a 4 He 2 (2 3 S 1 -2 3 S 1 ) long range molecule. Light shifts in one photon photo-association spectra are measured and studied as a function of the laser polarization and intensity, and the vibrational state of the excited molecule. They result from the light-induced coupling between the excited molecule, and bound and scattering states of the interaction between two metastable atoms. Their analysis leads to the determination of the scattering length a = (7.2 ± 0.6) ruling collisions between spin polarized atoms. The two photon photo-association spectra show evidence of the production of polarized, long-range 4 He 2 (2 3 S 1 -2 3 S 1 ) molecules. They are said to be exotic as they are made of two metastable atoms, each one carrying a enough energy to ionize the other. The corresponding lineshapes are calculated and decomposed in sums and products of Breit-Wigner and Fano profiles associated to one and two photon processes. The experimental spectra are fit, and an intrinsic lifetime τ = (1.4 ± 0.3) μs is deduced. It is checked whether this lifetime could be limited by spin-dipole induced Penning autoionization. This interpretation requires that there is a quasi-bound state close to the dissociation threshold in the singlet interaction potential between metastable helium atoms for the theory to match the experiment. (author)

  4. Transport fuels from two-stage coal liquefaction

    Benito, A.; Cebolla, V.; Fernandez, I.; Martinez, M.T.; Miranda, J.L.; Oelert, H.; Prado, J.G. (Instituto de Carboquimica CSIC, Zaragoza (Spain))

    1994-03-01

    Four Spanish lignites and their vitrinite concentrates were evaluated for coal liquefaction. Correlationships between the content of vitrinite and conversion in direct liquefaction were observed for the lignites but not for the vitrinite concentrates. The most reactive of the four coals was processed in two-stage liquefaction at a higher scale. First-stage coal liquefaction was carried out in a continuous unit at Clausthal University at a temperature of 400[degree]C at 20 MPa hydrogen pressure and with anthracene oil as a solvent. The coal conversion obtained was 75.41% being 3.79% gases, 2.58% primary condensate and 69.04% heavy liquids. A hydroprocessing unit was built at the Instituto de Carboquimica for the second-stage coal liquefaction. Whole and deasphalted liquids from the first-stage liquefaction were processed at 450[degree]C and 10 MPa hydrogen pressure, with two commercial catalysts: Harshaw HT-400E (Co-Mo/Al[sub 2]O[sub 3]) and HT-500E (Ni-Mo/Al[sub 2]O[sub 3]). The effects of liquid hourly space velocity (LHSV), temperature, gas/liquid ratio and catalyst on the heteroatom liquids, and levels of 5 ppm of nitrogen and 52 ppm of sulphur were reached at 450[degree]C, 10 MPa hydrogen pressure, 0.08 kg H[sub 2]/kg feedstock and with Harshaw HT-500E catalyst. The liquids obtained were hydroprocessed again at 420[degree]C, 10 MPa hydrogen pressure and 0.06 kg H[sub 2]/kg feedstock to hydrogenate the aromatic structures. In these conditions, the aromaticity was reduced considerably, and 39% of naphthas and 35% of kerosene fractions were obtained. 18 refs., 4 figs., 4 tabs.

  5. Liquefaction of solid carbonaceous material with catalyst recycle

    Gupta, Avinash; Greene, Marvin I.

    1992-01-01

    In the two stage liquefaction of a carbonaceous solid such as coal wherein coal is liquefied in a first stage in the presence of a liquefaction solvent and the first stage effluent is hydrogenated in the presence of a supported hydrogenation catalyst in a second stage, catalyst which has been previously employed in the second stage and comminuted to a particle size distribution equivalent to 100% passing through U.S. 100 Mesh, is passed to the first stage to improve the overall operation.

  6. Hydrothermal liquefaction of microalgae's for bio oil production

    Toor, Saqib; Reddy, Harvind; Deng, Shuguang

    process water for algae cultivation. GC-MS, elemental analyzer, calorimeter and nutrient analysis were used to analyze bio-crude, lipid-extracted algae and water samples produced in the hydrothermal liquefaction process. The highest bio-oil yield of 46% was obtained on Nannochloropsis salina at 310 °C...... and 107 bar. For Spirulina platensis algae sample, the highest bio-oil yield is 38% at 350 °C and 195 bar. Preliminary data also indicate that a lipid-extracted algae solid residue sample obtained in the hydrothermal liquefaction process contains a high level of proteins...

  7. Cooperative research in coal liquefaction. Final report, May 1, 1990-- April 30, 1991

    Huffman, G.P. [ed.

    1992-02-15

    The Consortium for Fossil Fuel Liquefaction Science (CFFLS) is currently engaged in a three year contract with the US Department of Energy investigating a range of research topics dealing with direct coal liquefaction. This report summarizes the results of this program in its second year, from May 1, 1990 to April 30, 1991. Accomplishments for this period are presented for the following tasks: Iron-based catalysts for coal liquefaction, exploratory research on coal conversion, novel coal liquefaction concepts, and novel catalysts for coal liquefaction.

  8. Electronic properties of physisorbed helium

    Kossler, Sarah

    2011-01-01

    This thesis deals with electronic excitations of helium physisorbed on metal substrates. It is studied to what extent the electronic properties change compared to the gas phase due to the increased helium density and the proximity of the metal. Furthermore, the influence of different substrate materials is investigated systematically. To this end, up to two helium layers were adsorbed onto Ru (001), Pt (111), Cu (111), and Ag (111) surfaces in a custom-made cryostat. These samples were studied spectroscopically using synchrotron radiation and a time-of-flight detector. The experimental results were then analyzed in comparison with extensive theoretical model calculations.

  9. Electronic properties of physisorbed helium

    Kossler, Sarah

    2011-09-22

    This thesis deals with electronic excitations of helium physisorbed on metal substrates. It is studied to what extent the electronic properties change compared to the gas phase due to the increased helium density and the proximity of the metal. Furthermore, the influence of different substrate materials is investigated systematically. To this end, up to two helium layers were adsorbed onto Ru (001), Pt (111), Cu (111), and Ag (111) surfaces in a custom-made cryostat. These samples were studied spectroscopically using synchrotron radiation and a time-of-flight detector. The experimental results were then analyzed in comparison with extensive theoretical model calculations.

  10. Assessment of liquefaction-induced hazards using Bayesian networks based on standard penetration test data

    Tang, Xiao-Wei; Bai, Xu; Hu, Ji-Lei; Qiu, Jiang-Nan

    2018-05-01

    Liquefaction-induced hazards such as sand boils, ground cracks, settlement, and lateral spreading are responsible for considerable damage to engineering structures during major earthquakes. Presently, there is no effective empirical approach that can assess different liquefaction-induced hazards in one model. This is because of the uncertainties and complexity of the factors related to seismic liquefaction and liquefaction-induced hazards. In this study, Bayesian networks (BNs) are used to integrate multiple factors related to seismic liquefaction, sand boils, ground cracks, settlement, and lateral spreading into a model based on standard penetration test data. The constructed BN model can assess four different liquefaction-induced hazards together. In a case study, the BN method outperforms an artificial neural network and Ishihara and Yoshimine's simplified method in terms of accuracy, Brier score, recall, precision, and area under the curve (AUC) of the receiver operating characteristic (ROC). This demonstrates that the BN method is a good alternative tool for the risk assessment of liquefaction-induced hazards. Furthermore, the performance of the BN model in estimating liquefaction-induced hazards in Japan's 2011 Tōhoku earthquake confirms its correctness and reliability compared with the liquefaction potential index approach. The proposed BN model can also predict whether the soil becomes liquefied after an earthquake and can deduce the chain reaction process of liquefaction-induced hazards and perform backward reasoning. The assessment results from the proposed model provide informative guidelines for decision-makers to detect the damage state of a field following liquefaction.

  11. Report on the coal liquefaction committee in fiscal 1992; 1992 nendo sekitan ekika iinkai hokokusho

    NONE

    1993-03-01

    This paper reports the activities of the coal liquefaction committee in fiscal 1992. The first committee meeting was held on August 21. After having confirmed the minutes of the previous meeting, an explanation was given on the research and development plans in fiscal 1992. The explanation covered the general explanation, bituminous coal liquefaction, brown coal liquefaction, and the common and fundamental aspects. The presented topics included the achievements in the operations using a bituminous coal liquefaction PSU and a small device, the status of compiling the achievements in the brown coal liquefaction project, preparation of the basic policy on developing the common basic technologies, and structuring of a coal liquefaction technology package. The second meeting was held on March 18, 1993. The meeting verified the minutes of the previous meeting, and gave the sub-committee reports for fiscal 1992. The sub-committees include those for bituminous coal liquefaction, brown coal liquefaction, environmental safety evaluation, and separation and refining technologies. As the summary of the achievements in fiscal 1992, descriptions were given on the bituminous coal liquefaction, brown coal liquefaction, and common and basic aspects. The fiscal 1993 plan presented included the budget aspect. A description was given as a topic on the economic performance evaluation and the working scheme (the execution plan) for the brown coal liquefaction process. (NEDO)

  12. Cooperative research in coal liquefaction. Technical progress report, May 1, 1993--April 30, 1994

    Huffman, G.P. [ed.

    1994-10-01

    Accomplishments for the past year are presented for the following tasks: coliquefaction of coal with waste materials; catalysts for coal liquefaction to clean transportation fuels; fundamental research in coal liquefaction; and in situ analytical techniques for coal liquefaction and coal liquefaction catalysts some of the highlights are: very promising results have been obtained from the liquefaction of plastics, rubber tires, paper and other wastes, and the coliquefaction of wastes with coal; a number of water soluble coal liquefaction catalysts, iron, cobalt, nickel and molybdenum, have been comparatively tested; mossbauer spectroscopy, XAFS spectroscopy, TEM and XPS have been used to characterize a variety of catalysts and other samples from numerous consortium and DOE liquefaction projects and in situ ESR measurements of the free radical density have been conducted at temperatures from 100 to 600{degrees}C and H{sub 2} pressures up to 600 psi.

  13. Techno-economic Assessment of Integrated Hydrothermal Liquefaction and Combined Heat and Power Production from Lignocellulose Residues

    Mohamed Magdeldin

    2018-03-01

    Full Text Available Waste biomass as a mean for global carbon dioxide emissions mitigation remains under-utilized. This is mainly due to the low calorific value of virgin feedstock, characterized generally with high moisture content. Aqueous processing, namely hydrothermal liquefaction in subcritical water conditions, has been demonstrated experimentally to thermally densify solid lignocellulose into liquid fuels without the pre-requisite and energy consuming drying step. This study presents a techno-economic evaluation of an integrated hydrothermal liquefaction system with downstream combined heat and power production from forest residues. The utilization of the liquefaction by-products and waste heat from the elevated processing conditions, coupled with the chemical upgrading of the feedstock enables the poly-generation of biocrude, electricity and district heat. The plant thermal efficiency increases by 3.5 to 4.6% compared to the conventional direct combustion case. The economic assessment showed that the minimum selling price of biocrude, based on present co-products market prices, hinders commercialization and ranges between 138 EUR to 178 EUR per MWh. A sensitivity analysis and detailed discussion on the techno-economic assessment results are presented for the different process integration and market case scenarios.

  14. Helium cooling of fusion reactors

    Wong, C.P.C.; Baxi, C.; Bourque, R.; Dahms, C.; Inamati, S.; Ryder, R.; Sager, G.; Schleicher, R.

    1994-01-01

    On the basis of worldwide design experience and in coordination with the evolution of the International Thermonuclear Experimental Reactor (ITER) program, the application of helium as a coolant for fusion appears to be at the verge of a transition from conceptual design to engineering development. This paper presents a review of the use of helium as the coolant for fusion reactor blanket and divertor designs. The concept of a high-pressure helium cooling radial plate design was studied for both ITER and PULSAR. These designs can resolve many engineering issues, and can help with reaching the goals of low activation and high performance designs. The combination of helium cooling, advanced low-activation materials, and gas turbine technology may permit high thermal efficiency and reduced costs, resulting in the environmental advantages and competitive economics required to make fusion a 21st century power source. ((orig.))

  15. Laser spectroscopy of antiprotonic helium

    Hori, M

    2005-01-01

    When antiprotons (i.e. the antimatter counterpart of protons) are stopped in helium gas, 97% of them annihilate within picoseconds by reacting with the helium nuclei; a 3% fraction, however, survive with an anomalously long lifetime of several microseconds. This longevity is due to the formation of antiprotonic helium, which is a three-body Rydberg atom composed of an antiproton, electron, and helium nucleus. The ASACUSA experimental collaboration has recently synthesized large numbers of these atoms using CERN's Antiproton Decelerator facility, and measured the atom's transition frequencies to 60 parts per billion by laser spectroscopy. By comparing the experimental results with recent three-body QED calculations and the known antiproton cyclotron frequency, we were able to show that the antiproton mass and charge are the same as the corresponding proton values to a precision of 10 parts per billion. Ongoing and future series of experiments will further improve the experimental precision by using chirp-compe...

  16. High Accuracy Vector Helium Magnetometer

    National Aeronautics and Space Administration — The proposed HAVHM instrument is a laser-pumped helium magnetometer with both triaxial vector and omnidirectional scalar measurement capabilities in a single...

  17. Hydrothermal liquefaction of barley straw to bio-crude oil

    Zhu, Zhe; Rosendahl, Lasse; Toor, Saqib

    2015-01-01

    Hydrothermal liquefaction (HTL) of barley straw with K2CO3 at different temperatures (280–400 C) was conducted and compared to optimize its process conditions; the aqueous phase as a co-product from this process was recycled to explore the feasibility of implementing wastewater reuse for bio...

  18. Mineral catalysis of oil producing reactions in coal liquefaction

    Shridharani, K.G.

    1983-01-01

    This work was concerned primarily with the development of a relatively inexpensive, readily available, high activity catalyst that can be used as a disposable catalyst in coal liquefaction processes. For a fair evaluation of the developmental mineral catalyst (presulfided iron oxide), it was necessary to determine at different stages of this work, whether catalyst inhibition, deactivation or activity was the limiting factor in coal liquefaction catalysis. First, different routes were explored to prepare a high hydrogenation activity, iron-based catalyst. Naphthalene hydrogenation was used as a model reaction to rate the hydrogenation activities of different additives. Presulfiding of iron oxide with H/sub 2/S, under controlled conditions, rendered the highest hydrogenation activity mineral catalyst, which had a hydrogenation activity even greater than that of commercial CoMo/Al/sub 2/O/sub 3/ catalyst sulfided with creosote oil and hydrogen. Sulfiding of CoMo/Al/sub 2/O/sub 3/ catalyst with H/sub 2/S remarkably improved its initial hydrogenation activity. Second, the catalyst inhibition and deactivation during liquefaction were studied. Liquefaction-process solvents contain a number of compounds that can either deactivate or inhibit the hydrogenation activity of a catalyst. Finally, the hydrocracking activity of the presulfided iron oxide catalyst was compared with that of commercial catalysts, CoMo/Al/sub 2/O/sub 3/ and low alumina FCC catalyst.

  19. Finite Element Modelling of Seismic Liquefaction in Soils

    Galavi, V.; Petalas, A.; Brinkgreve, R.B.J.

    2013-01-01

    Numerical aspects of seismic liquefaction in soils as implemented in the finite element code, PLAXIS, is described in this paper. After description of finite element equations of dynamic problems, three practical dynamic boundary conditions, namely viscous boundary tractions, tied degrees of freedom

  20. Biological production of alcohols from coal through indirect liquefaction

    Barik, S; Prieto, S; Harrison, S B; Clausen, E C; Gaddy, J L

    1988-08-01

    The purpose of this project is to demonstrate the feasibility of producing liquid fuels from the components of synthesis gas through biological indirect liquefaction. The results of pure culture and natural source screening studies aimed at finding organisms capable of carrying out the conversions are presented and discussed. 17 refs., 2 figs., 8 tabs.

  1. The making of Andersen’s liquefaction chart

    Sabaliauskas, Tomas; Ibsen, Lars Bo

    Andersen’s chart (Andersen & Berre, 1999) is a graphical method of observing cyclic soil response. It allows observing soil response to various stress amplitudes that can lead to liquefaction, excess plastic deformation stabilizing soil response.The process of obtaining the original chart has been...

  2. Determination of Liquefaction Potential using Artificial Neural Networks

    Farrokhzad, F; Choobbasti, A.J; Barari, Amin

    2011-01-01

    The authors propose an alternative general regression model based on neural networks, which enables analysis of summary data obtained by liquefaction analysis according to usual methods. For that purpose, the data from some thirty boreholes made during field investigations in Babol, in the Iranian...

  3. Liquefaction of ground tire rubber at low temperature.

    Cheng, Xiangyun; Song, Pan; Zhao, Xinyu; Peng, Zonglin; Wang, Shifeng

    2018-01-01

    Low-temperature liquefaction has been investigated as a novel method for recycling ground tire rubber (GTR) into liquid using an environmentally benign process. The liquefaction was carried out at different temperatures (140, 160 and 180 °C) over variable time ranges (2-24 h) by blending the GTR with aromatic oil in a range from 0 to 100 parts per hundred rubber (phr). The liquefied GTR was separated into sol (the soluble fraction of rubber which can be extracted with toluene) and gel fractions (the solid fraction obtained after extraction) to evaluate the reclaiming efficiency. It was discovered that the percentage of the sol fraction increased with time, swelling ratio and temperature. Liquefied rubber was obtained with a high sol fraction (68.34 wt%) at 140 °C. Simultaneously, separation of nano-sized carbon black from the rubber networks occurred. The separation of carbon black from the network is the result of significant damage to the cross-linked-network that occurs throughout the liquefaction process. During liquefaction, a competitive reaction between main chain scission and cross-link bond breakage takes place. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Thermochemical liquefaction characteristics of microalgae in sub- and supercritical ethanol

    You, Qiao; Chen, Liang [College of Environmental Science and Engineering, Hunan University, Changsha (China); Key Laboratory of Environment Biology and Pollution Control, Ministry of Education, Changsha (China)

    2011-01-15

    Thermochemical liquefaction characteristics of Spirulina, a kind of high-protein microalgae, were investigated with the sub- and supercritical ethanol as solvent in a 1000 mL autoclave. The influences of various liquefaction parameters on the yields of products (bio-oil and residue) from the liquefaction of Spirulina were studied, such as the reaction temperature (T), the S/L ratio (R{sub 1}, solid: Spirulina, liquid: ethanol), the solvent filling ratio (R{sub 2}) and the type and dosage of catalyst. Without catalyst, the bio-oil yields were in the range of 35.4 wt.% and 45.3 wt.% depending on the changes of T, R{sub 1} and R{sub 2}. And the bio-oil yields increased generally with increasing T and R{sub 2}, while the bio-oil yields reduced with increasing R{sub 1}. The FeS catalyst was certified to be an ideal catalyst for the liquefaction of Spirulina microalgae for its advantages on promoting bio-oil production and suppressing the formation of residue. The optimal dosage of catalyst (FeS) was ranging from 5-7 wt.%. The elemental analyses and FT-IR and GC-MS measurements for the bio-oils revealed that the liquid products have much higher heating values than the crude Spirulina sample and fatty acid ethyl ester compounds were dominant in the bio-oils, irrespective of whether catalyst was used. (author)

  5. Direct liquefaction of plastics and coprocessing of coal with plastics

    Huffman, G.P.; Feng, Z.; Mahajan, V. [Univ. of Kentucky, Lexington, KY (United States)

    1995-12-31

    The objectives of this work were to optimize reaction conditions for the direct liquefaction of waste plastics and the coprocessing of coal with waste plastics. In previous work, the direct liquefaction of medium and high density polyethylene (PE), polypropylene (PPE), poly(ethylene terephthalate) (PET), and a mixed plastic waste, and the coliquefaction of these plastics with coals of three different ranks was studied. The results established that a solid acid catalyst (HZSM-5 zeolite) was highly active for the liquefaction of the plastics alone, typically giving oil yields of 80-95% and total conversions of 90-100% at temperatures of 430-450 {degrees}C. In the coliquefaction experiments, 50:50 mixtures of plastic and coal were used with a tetralin solvent (tetralin:solid = 3:2). Using approximately 1% of the HZSM-5 catalyst and a nanoscale iron catalyst, oil yields of 50-70% and total conversion of 80-90% were typical. In the current year, further investigations were conducted of the liquefaction of PE, PPE, and a commingled waste plastic obtained from the American Plastics Council (APC), and the coprocessing of PE, PPE and the APC plastic with Black Thunder subbituminous coal. Several different catalysts were used in these studies.

  6. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil

    Zheng, Ji-Lu, E-mail: triace@163.com; Zhu, Ming-Qiang; Wu, Hai-tang

    2015-09-15

    Highlights: • Swine carcasses can be converted to bio-oil by alkaline hydrothermal liquefaction. • It seems that the use of the bio-oil for heat or CHP is technically suitable. • Some valuable chemicals were found in the bio-oils. • The bio-oil and the solid residue constituted an energy efficiency of 93.63% for the feedstock. • The solid residue can be used as a soil amendment, to sequester C and for preparing activated carbon. - Abstract: It is imperative that swine carcasses are disposed of safely, practically and economically. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil was performed. Firstly, the effects of temperature, reaction time and pH value on the yield of each liquefaction product were determined. Secondly, liquefaction products, including bio-oil and solid residue, were characterized. Finally, the energy recovery ratio (ERR), which was defined as the energy of the resultant products compared to the energy input of the material, was investigated. Our experiment shows that reaction time had certain influence on the yield of liquefaction products, but temperature and pH value had bigger influence on the yield of liquefaction products. Yields of 62.2 wt% bio-oil, having a high heating value of 32.35 MJ/kg and a viscosity of 305cp, and 22 wt% solid residue were realized at a liquefaction temperature of 250 °C, a reaction time of 60 min and a pH value of 9.0. The bio-oil contained up to hundreds of different chemical components that may be classified according to functional groups. Typical compound classes in the bio-oil were hydrocarbons, organic acids, esters, ketones and heterocyclics. The energy recovery ratio (ERR) reached 93.63%. The bio-oil is expected to contribute to fossil fuel replacement in stationary applications, including boilers and furnaces, and upgrading processes for the bio-oil may be used to obtain liquid transport fuels.

  7. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil

    Zheng, Ji-Lu; Zhu, Ming-Qiang; Wu, Hai-tang

    2015-01-01

    Highlights: • Swine carcasses can be converted to bio-oil by alkaline hydrothermal liquefaction. • It seems that the use of the bio-oil for heat or CHP is technically suitable. • Some valuable chemicals were found in the bio-oils. • The bio-oil and the solid residue constituted an energy efficiency of 93.63% for the feedstock. • The solid residue can be used as a soil amendment, to sequester C and for preparing activated carbon. - Abstract: It is imperative that swine carcasses are disposed of safely, practically and economically. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil was performed. Firstly, the effects of temperature, reaction time and pH value on the yield of each liquefaction product were determined. Secondly, liquefaction products, including bio-oil and solid residue, were characterized. Finally, the energy recovery ratio (ERR), which was defined as the energy of the resultant products compared to the energy input of the material, was investigated. Our experiment shows that reaction time had certain influence on the yield of liquefaction products, but temperature and pH value had bigger influence on the yield of liquefaction products. Yields of 62.2 wt% bio-oil, having a high heating value of 32.35 MJ/kg and a viscosity of 305cp, and 22 wt% solid residue were realized at a liquefaction temperature of 250 °C, a reaction time of 60 min and a pH value of 9.0. The bio-oil contained up to hundreds of different chemical components that may be classified according to functional groups. Typical compound classes in the bio-oil were hydrocarbons, organic acids, esters, ketones and heterocyclics. The energy recovery ratio (ERR) reached 93.63%. The bio-oil is expected to contribute to fossil fuel replacement in stationary applications, including boilers and furnaces, and upgrading processes for the bio-oil may be used to obtain liquid transport fuels

  8. Continuous production of bio-oil by catalytic liquefaction from wet distiller’s grain with solubles (WDGS) from bio-ethanol production

    Toor, Saqib Sohail; Rosendahl, Lasse; Nielsen, Mads Pagh; Glasius, Marianne; Rudolf, Andreas; Iversen, Steen Brummerstedt

    2012-01-01

    Bio-refinery concepts are currently receiving much attention due to the drive toward flexible, highly efficient systems for utilization of biomass for food, feed, fuel and bio-chemicals. One way of achieving this is through appropriate process integration, in this particular case combining enzymatic bio-ethanol production with catalytic liquefaction of the wet distillers grains with soluble, a byproduct from the bio-ethanol process. The catalytic liquefaction process is carried out at sub-critical conditions (280–370 °C and 25 MPa) in the presence of a homogeneous alkaline and a heterogeneous Zirconia catalyst, a process known as the Catliq ® process. In the current work, catalytic conversion of WDGS was performed in a continuous pilot plant with a maximum capacity of 30 dm 3 h −1 of wet biomass. In the process, WDGS was converted to bio-oil, gases and water-soluble organic compounds. The oil obtained was characterized using several analysis methods, among them elementary analysis and GC–MS. The study shows that WDGS can be converted to bio oil with high yields. The results also indicate that through the combination of bio-ethanol production and catalytic liquefaction, it is possible to significantly increase the liquid product yield and scope, opening up for a wider end use applicability. -- Highlights: ► Hydrothermal liquefaction of wet biomass. ► Product phase analysis: oil, acqeous, gas and mineral phase. ► Energy and mass balance evaluation.

  9. 21 CFR 184.1355 - Helium.

    2010-04-01

    ... colorless, odorless, flavorless, nonflammable, inert gas. It is lighter than air and is produced by the liquefaction and purification of natural gas. (b) The ingredient must be of a purity suitable for its intended...

  10. Cryogenic filter method produces super-pure helium and helium isotopes

    Hildebrandt, A. F.

    1964-01-01

    Helium is purified when cooled in a low pressure environment until it becomes superfluid. The liquid helium is then filtered through iron oxide particles. Heating, cooling and filtering processes continue until the purified liquid helium is heated to a gas.

  11. Semi-automated landform classification for hazard mapping of soil liquefaction by earthquake

    Nakano, Takayuki

    2018-05-01

    Soil liquefaction damages were caused by huge earthquake in Japan, and the similar damages are concerned in near future huge earthquake. On the other hand, a preparation of soil liquefaction risk map (soil liquefaction hazard map) is impeded by the difficulty of evaluation of soil liquefaction risk. Generally, relative soil liquefaction risk should be able to be evaluated from landform classification data by using experimental rule based on the relationship between extent of soil liquefaction damage and landform classification items associated with past earthquake. Therefore, I rearranged the relationship between landform classification items and soil liquefaction risk intelligibly in order to enable the evaluation of soil liquefaction risk based on landform classification data appropriately and efficiently. And I developed a new method of generating landform classification data of 50-m grid size from existing landform classification data of 250-m grid size by using digital elevation model (DEM) data and multi-band satellite image data in order to evaluate soil liquefaction risk in detail spatially. It is expected that the products of this study contribute to efficient producing of soil liquefaction hazard map by local government.

  12. Achievement report for fiscal 1993 on research under Sunshine Program. Research on direct liquefaction reaction of coal; 1993 nendo sekitan no chokusetsu ekika hanno ni kansuru kenkyu seika hokokusho

    NONE

    1994-03-01

    The reaction velocity constant of coal or the distribution of products in a high-pressure hydrocracking process of coal are found not to be affected by the temperature rise rate. The liquefaction of coal using CO and water is analyzed using a high-pressure differential thermal analyzer. The hydrogen gas generated during the water gas reaction reacts with CO for the formation of alcohols, carbonic acid, etc. The reaction rate is found to be higher when the specimen contains more oxygen. When coals greatly different from each other in terms of thermolytic reactivity, caking property, and intersolubility with medium oils are mixed, synergistic effects are exhibited, positive when active hydrogen supply is abundant and negative when it is short. In the case of the Hokkaido coal which contains 73.0-87.4% carbon, the grain diameter does not affect the liquefaction rate when the coal is crushed to the 48-mesh size approximately. Reaction velocity in direct liquefaction does not relate to hydrogen pressure. Asphaltenes in coal liquefaction are produced at the beginning of reaction, to be reduced in molecular weight due to cleavage of methylene crosslinks with the progress of reaction. Studies are conducted in a 0.1t/d-capable bench plant about liquefaction reaction characteristics and coal liquid properties, and chemical structures. (NEDO)

  13. Design of generic coal conversion facilities: Indirect coal liquefaction, Fischer-Tropsch synthesis

    1991-10-01

    A comprehensive review of Fischer-Tropsch (F-T) technology, including fixed, fluidized, and bubble column reactors, was undertaken in order to develop an information base before initiating the design of the Fischer-Tropsch indirect liquefaction PDU as a part of the Generic Coal Conversion Facilities to be built at the Pittsburgh Energy Technology Center (PETC). The pilot plant will include a fixed bed and slurry bubble column reactor for the F-T mode of operation. The review encompasses current status of both these technologies, their key variables, catalyst development, future directions, and potential improvement areas. However, more emphasis has been placed on the slurry bubble column reactor since this route is likely to be the preferred technology for commercialization, offering process advantages and, therefore, better economics than fixed and fluidized bed approaches.

  14. Y-12 site-specific earthquake response analysis and soil liquefaction assessment

    Ahmed, S.B.; Hunt, R.J.; Manrod, W.E. III.

    1995-01-01

    A site-specific earthquake response analysis and soil liquefaction assessment were performed for the Oak Ridge Y-12 Plant. The main purpose of these studies was to use the results of the analyses for evaluating the safety of the performance category -1, -2, and -3 facilities against the natural phenomena seismic hazards. Earthquake response was determined for seven (7), one dimensional soil columns (Fig. 12) using two horizontal components of the PC-3 design basis 2000-year seismic event. The computer program SHAKE 91 (Ref. 7) was used to calculate the absolute response accelerations on top of ground (soil/weathered shale) and rock outcrop. The SHAKE program has been validated for horizontal response calculations at periods less than 2.0 second at several sites and consequently is widely accepted in the geotechnical earthquake engineering area for site response analysis

  15. Hydrothermal liquefaction of agricultural and forestry wastes: state-of-the-art review and future prospects.

    Cao, Leichang; Zhang, Cheng; Chen, Huihui; Tsang, Daniel C W; Luo, Gang; Zhang, Shicheng; Chen, Jianmin

    2017-12-01

    Hydrothermal liquefaction has been widely applied to obtain bioenergy and high-value chemicals from biomass in the presence of a solvent at moderate to high temperature (200-550°C) and pressure (5-25MPa). This article summarizes and discusses the conversion of agricultural and forestry wastes by hydrothermal liquefaction. The history and development of hydrothermal liquefaction technology for lignocellulosic biomass are briefly introduced. The research status in hydrothermal liquefaction of agricultural and forestry wastes is critically reviewed, particularly for the effects of liquefaction conditions on bio-oil yield and the decomposition mechanisms of main components in biomass. The limitations of hydrothermal liquefaction of agricultural and forestry wastes are discussed, and future research priorities are proposed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Bed system performance in helium circulation mode

    Kim, Yean Jin; Jung, Kwang Jin; Ahn, Do Hee; Chung, Hong Suk [UST, Daejeon (Korea, Republic of); Kang, Hee Suk [KAERI, Daejeon (Korea, Republic of); Yun, Sei Hun [NFRI, Deajeon (Korea, Republic of)

    2016-05-15

    As a part of the International Thermonuclear Experimental Reactor (ITER) Project, We have conducted an experiment for storing hydrogen to depleted uranium and zirconium cobalt. The helium blanket effect has been observed in experiments using metal hydrides. The collapse of the hydrogen isotopes are accompanied by the decay heat and helium-3. Helium-3 dramatically reduces the hydrogen isotope storage capacity by surrounding the metal. This phenomenon is called a helium blanket effect. In addition the authors are working on the recovery and removal techniques of helium-3. In this paper, we discuss the equipment used to test the helium blanket effect and the results of a helium circulation experiment. The helium-3 produced surrounds the storage material surface and thus disturbs the reaction of the storage material and the hydrogen isotope. Even if the amount of helium-3 is small, the storage capacity of the SDS bed significantly drops. This phenomenon is the helium blanket effect. To resolve this phenomenon, a circulating loop was introduced. Using a circulating system, helium can be separated from the storage material. We made a helium loop that includes a ZrCo bed. Then using a metal bellows pump, we tested the helium circulation.

  17. Post-liquefaction soil-structure interaction for buried structures: Sensitivity analysis studies

    Pires, J.A.; Ang, H.S.; Katayama, I.; Satoh, M.

    1993-01-01

    The post liquefaction behavior of buried conduits is analyzed and sensitivity analysis is conducted to investigate the damage potential of the forces induced in the buried lifelines following seismically induced liquefaction of the surrounding soil. Various lifeline configurations and loading conditions are considered. The loading conditions considered are: buoyancy forces and permanent ground displacements parallel to the lifeline axis. Pertinent parameters for the soil-lifeline interaction following liquefaction are identified. (author)

  18. Novel combined cycle configurations for propane pre-cooled mixed refrigerant (APCI) natural gas liquefaction cycle

    Mortazavi, Amir; Alabdulkarem, Abdullah; Hwang, Yunho; Radermacher, Reinhard

    2014-01-01

    Highlights: • 10 New LNG plants driver cycle enhancement configurations were developed. • All the 14 enhancement options design variables were optimized to demonstrate their energy saving potentials. • The best driver cycle enhancement option improved the driver cycle energy efficiency by 38%. • The effects of technological advancements on the performances of the enhancement options were studied. - Abstract: A significant amount of energy is required for natural gas liquefaction. Due to the production scale of LNG plants, they consume an intensive amount of energy. Consequently, any enhancement to the energy efficiency of LNG plants will result in a considerable reduction in natural gas consumption and CO 2 emission. Compressor drivers are the main energy consumer in the LNG plants. In this paper, 14 different driver cycle enhancement options were considered. A number of these options have not been proposed for the LNG plants. The new driver cycle development was performed by analyzing and optimizing the design variables of four conventional driver cycle enhancement options. The optimization results were used to develop more efficient cycles through mitigating the active constrains and driver cycle innovations. Based on the current available technologies five of our newly developed driver cycle configurations have higher efficiency than the most efficient existing conventional driver cycle. The best developed driver cycle enhancement option improved the base driver cycle energy efficiency by 38%. The effects of technological advancement on the performances of the all driver cycle enhancement options were also considered

  19. Nitrogen expander cycles for large capacity liquefaction of natural gas

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun [Hong Ik University, Department of Mechanical Engineering, Seoul, 121-791 (Korea, Republic of); Choe, Kun Hyung [Korea Gas Corporation, Incheon, 406-130 (Korea, Republic of)

    2014-01-29

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity.

  20. Nitrogen expander cycles for large capacity liquefaction of natural gas

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun; Choe, Kun Hyung

    2014-01-01

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity.

  1. Nitrogen expander cycles for large capacity liquefaction of natural gas

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun; Choe, Kun Hyung

    2014-01-01

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity

  2. Direct liquefaction of low-rank coals under mild conditions

    Braun, N.; Rinaldi, R. [Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany)

    2013-11-01

    Due to decreasing of petroleum reserves, direct coal liquefaction is attracting renewed interest as an alternative process to produce liquid fuels. The combination of hydrogen peroxide and coal is not a new one. In the early 1980, Vasilakos and Clinton described a procedure for desulfurization by leaching coal with solutions of sulphuric acid/H{sub 2}O{sub 2}. But so far, H{sub 2}O{sub 2} has never been ascribed a major role in coal liquefaction. Herein, we describe a novel approach for liquefying low-rank coals using a solution of H{sub 2}O{sub 2} in presence of a soluble non-transition metal catalyst. (orig.)

  3. Multi-objective optimization of a joule cycle for re-liquefaction of the Liquefied Natural Gas

    Sayyaadi, Hoseyn; Babaelahi, M.

    2011-01-01

    Highlights: → A typical LNG boil off gas re-liquefaction plant system is optimized. → Objective functions based on thermodynamic and thermoeconomic analysis are obtained. → The cost of the system product and the exergetic efficiency are optimized, simultaneously. → A decision-making process for selection of the final optimal design is introduced. → Results obtained using various optimization scenarios are compared and discussed. - Abstract: A LNG re-liquefaction plant is optimized with a multi-objective approach which simultaneously considers exergetic and exergoeconomic objectives. In this regard, optimization is performed in order to maximize the exergetic efficiency of plant and minimize the unit cost of the system product (refrigeration effect), simultaneously. Thermodynamic modeling is performed based on energy and exergy analyses, while an exergoeconomic model based on the total revenue requirement (TRR) are developed. Optimization programming in MATLAB is performed using one of the most powerful and robust multi-objective optimization algorithms namely NSGA-II. This approach which is based on the Genetic Algorithm is applied to find a set of Pareto optimal solutions. Pareto optimal frontier is obtained and a final optimal solution is selected in a decision-making process. An example of decision-making process for selection of the final solution from the available optimal points of the Pareto frontier is presented here. The feature of selected final optimal system is compared with corresponding features of the base case and exergoeconomic single-objective optimized systems and discussed.

  4. Design of generic coal conversion facilities: Process release---Direct coal liquefaction

    1991-09-01

    The direct liquefaction portion of the PETC generic direct coal liquefaction process development unit (PDU) is being designed to provide maximum operating flexibility. The PDU design will permit catalytic and non-catalytic liquefaction concepts to be investigated at their proof-of-the-concept stages before any larger scale operations are attempted. The principal variations from concept to concept are reactor configurations and types. These include thermal reactor, ebullating bed reactor, slurry phase reactor and fixed bed reactor, as well as different types of catalyst. All of these operating modes are necessary to define and identify the optimum process conditions and configurations for determining improved economical liquefaction technology.

  5. Characteristics estimation of coal liquefaction residue; Sekitan ekika zansa seijo no suisan ni kansuru kento

    Itonaga, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Okada, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

    1996-10-28

    The paper studied a possibility of estimating characteristics of coal liquefaction residue from liquefaction conditions in the case of fixing coal kind in the NEDOL process coal liquefaction PSU. Wyoming coal was used for the study, and the already proposed simplified liquefaction reaction models were used. Among material balances explained by the models, those of asphaltene, preasphaltene, THF insoluble matters are concerned with residue composition. Ash content is separately calculated from ash balance. Reaction velocity constants of simplified liquefaction reaction models which influence the residue composition were obtained by the multiple regression method from experimental results in the past. The estimation expression of residue viscosity was introduced from residue ash/composition. When the residue composition is estimated by the model from liquefaction conditions, and the residue viscosity is obtained using it, the higher the liquefaction temperature is, the higher the residue viscosity is. The result obtained well agreed the measuring result. The simplified liquefaction model of a certain coal kind has been established, and characteristics of residue can be estimated even at liquefaction conditions which have never been experienced before if there is a certain amount of the accumulated data on residue composition/characteristics. 4 refs., 4 figs., 4 tabs.

  6. Pierre Gorce working on a helium pump.

    1975-01-01

    This type of pump was designed by Mario Morpurgo, to circulate liquid helium in superconducting magnets wound with hollow conductors. M. Morpurgo, Design and construction of a pump for liquid helium, CRYIOGENICS, February 1977, p. 91

  7. Convective mixing in helium white dwarfs

    Vauclair, G.; Fontaine, G.

    1979-01-01

    The conditions under which convective mixing episodes take place between the helium envelopes and the underlying carbon layers in helium-rich white dwarfs are investigated. It is found that, for essentially any value of the initial helium content less than the maximum mass a helium convection zone can have, mixing does occur, and leads, in the vast majority of cases, to an almost pure carbon superficial composition. Mixing products that show only traces of carbon while retaining helium-dominated envelopes are possible only if the initial helium content is quite close to the maximum possible mass of the helium convection zone. In the presence of turbulence, this restriction could be relaxed, however, and the helium-rich lambda4670 stars may possibly be explained in this fashion

  8. The making of Andersen’s liquefaction chart

    Sabaliauskas, Tomas; Ibsen, Lars Bo

    2017-01-01

    Andersen’s chart (Andersen & Berre, 1999) is a graphical method of observing cyclic soil response. It allows observing soil response to various stress amplitudes that can lead to liquefaction, excess plastic deformation stabilizing soil response.The process of obtaining the original chart has been improved. Algorithm based approximation is introduced. Pore pressure dependent ultimate bearing capacity normalization factor is introduced to normalize the chart.

  9. The current status of coal liquefaction technologies - Panorama 2008

    2008-01-01

    In 2008, a first coal liquefaction unit to produce motor fuel (20,000 BPSD) will come on-stream in Shenhua, China (in the Ercos region of Inner Mongolia). Other, more ambitious projects have been announced in China for between now and 2020. Since oil production is expected to peak in the medium term, this technology may develop regionally in the next 20 years to cover ever-increasing demand for motor fuel

  10. New magnetic refrigeration materials for the liquefaction of hydrogen

    Gschneidner, K.A.; Takeya, H.; Moorman, J.O.; Pecharsky, V.K.; Malik, S.K.; Zimm, C.B.

    1994-01-01

    Five heavy lanthanide ferromagnetic intermetallic compounds were studied as potential magnetic refrigerants for the liquefaction of hydrogen gas. (Dy 0.5 Er 0.5 )Al 2 and TbNi 2 appear to be better refrigerants than GdPd for a Joule-Brayton cycle refrigerator, while (Gd 0.54 Er 0.46 )AlNi seems to be a suitable refrigerant for an Ericsson cycle refrigerator

  11. Hydrothermal liquefaction of biomass: Developments from batch to continuous process

    Elliott, DC; Biller, P; Ross, AB; Schmidt, AJ; Jones, SB

    2015-01-01

    This review describes the recent results in hydrothermal liquefaction (HTL) of biomass in continuous-flow processing systems. Although much has been published about batch reactor tests of biomass HTL, there is only limited information yet available on continuous-flow tests, which can provide a more reasonable basis for process design and scale-up for commercialization. High-moisture biomass feedstocks are the most likely to be used in HTL. These materials are described and results of their pr...

  12. Development of an extruder-feeder biomass direct liquefaction process

    White, D.H.; Wolf, D. (Arizona Univ., Tucson, AZ (United States). Dept. of Chemical Engineering)

    1991-10-01

    As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE's Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt% wood flour in wood oil derived vacuum bottoms at pressures up to 3000 psi. The extruder-feeder has been integrated with a unique reactor by the University to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a high pressure reactor in the biomass liquefaction process. An experimental facility was constructed and following shakedown operations, wood crude oil was produced by mid-1985. By July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3000 psi and temperatures from 350{degree}C to 430{degree}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt% residual oxygen were produced. 38 refs., 82 figs., 26 tabs.

  13. A Characterization and Evaluation of Coal Liquefaction Process Streams

    NONE

    1998-10-01

    An updated assessment of the physico-chemical analytical methodology applicable to coal-liquefaction product streams and a review of the literature dealing with the modeling of fossil-fuel resid conversion to product oils are presented in this document. In addition, a summary is provided for the University of Delaware program conducted under this contract to develop an empirical test to determine relative resid reactivity and to construct a computer model to describe resid structure and predict reactivity.

  14. Helium localization around the microscopic impurities embedded to liquid helium

    Gordon, E.B.; Shestakov, A.F.

    2000-01-01

    The structure and properties of the environment round the impurity atoms (Im) embedded in liquid helium are considered. It is shown that there are two qualitatively different types of structure of the He atom layer next to Im - attraction and repulsion structures. For the center attraction structure (strong Im-He interaction) the Im-He separation is longer than the equilibrium one for the pair Im-He potential, and the density and localization of He atoms are higher than in the bulk. It this case the He atom content in the layer, n, is almost independent of applied pressure. In the repulsion structure realized for alkaline metal atoms the Im-He separation is shorter than the equilibrium one and the density is lower than in the helium bulk. At T approx 1 K occupied are several states with different n and their energies differ only by approx 0.1 K, an increase in pressure resulting in a considerable reduction of n. The optical and EPR spectra of the atoms embedded to liquid and solid helium are interpreted on the basis of the analysis carried out. A simple model is proposed to evaluate the helium surroundings characteristics from the experimental pressure dependences of atomic line shifts in the absorption and emission spectra. The attraction structures in 3 He - 4 He mixtures are suggested to be highly enriched by 4 He atoms which the repulsion structures - by 3 He atoms. a possibility for existence of phase transitions in helium shells surrounding impurity atoms is considered

  15. Helium behaviour in aluminium under hydrostatic pressure

    Sokurskij, Yu.N.; Tebus, V.N.; Zudilin, V.A.; Tumanova, G.M.

    1989-01-01

    Effect of hydrostatic compression on equilibrium helium bubbles in low aluminium-lithium alloy irradiated in reactor at 570 K is investigated. Measurements of hydrostatic density and electron-microscopic investigations have shown, that application of up to 2 GPa pressure reduces equilibrium size of helium bubbles and reduces helium swelling. Kinetics and thermodynamics of the process are considered with application of 'rigid sphere' equation which describes helium state in bubbles

  16. Machine learning modelling for predicting soil liquefaction susceptibility

    P. Samui

    2011-01-01

    Full Text Available This study describes two machine learning techniques applied to predict liquefaction susceptibility of soil based on the standard penetration test (SPT data from the 1999 Chi-Chi, Taiwan earthquake. The first machine learning technique which uses Artificial Neural Network (ANN based on multi-layer perceptions (MLP that are trained with Levenberg-Marquardt backpropagation algorithm. The second machine learning technique uses the Support Vector machine (SVM that is firmly based on the theory of statistical learning theory, uses classification technique. ANN and SVM have been developed to predict liquefaction susceptibility using corrected SPT [(N160] and cyclic stress ratio (CSR. Further, an attempt has been made to simplify the models, requiring only the two parameters [(N160 and peck ground acceleration (amax/g], for the prediction of liquefaction susceptibility. The developed ANN and SVM models have also been applied to different case histories available globally. The paper also highlights the capability of the SVM over the ANN models.

  17. Solvent recyclability in a multistep direct liquefaction process

    Hetland, M.D.; Rindt, J.R. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31

    Direct liquefaction research at the Energy & Environmental Research Center (EERC) has, for a number of years, concentrated on developing a direct liquefaction process specifically for low-rank coals (LRCs) through the use of hydrogen-donating solvents and solvents similar to coal-derived liquids, the water/gas shift reaction, and lower-severity reaction conditions. The underlying assumption of all of the research was that advantage could be taken of the reactivity and specific qualities of LRCs to produce a tetrahydrofuran (THF)-soluble material that might be easier to upgrade than the soluble residuum produced during direct liquefaction of high-rank coals. A multistep approach was taken to produce the THF-soluble material, consisting of (1) preconversion treatment to prepare the coal for solubilization, (2) solubilization of the coal in the solvent, and (3) polishing to complete solubilization of the remaining material. The product of these three steps can then be upgraded during a traditional hydrotreatment step. The results of the EERC`s research indicated that additional studies to develop this process more fully were justified. Two areas were targeted for further research: (1) determination of the recyclability of the solvent used during solubilization and (2) determination of the minimum severity required for hydrotreatment of the liquid product. The current project was funded to investigate these two areas.

  18. Technology for advanced liquefaction processes: Coal/waste coprocessing studies

    Cugini, A.V.; Rothenberger, K.S.; Ciocco, M.V. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    The efforts in this project are directed toward three areas: (1) novel catalyst (supported and unsupported) research and development, (2) study and optimization of major operating parameters (specifically pressure), and (3) coal/waste coprocessing. The novel catalyst research and development activity has involved testing supported catalysts, dispersed catalysts, and use of catalyst testing units to investigate the effects of operating parameters (the second area) with both supported and unsupported catalysts. Several supported catalysts were tested in a simulated first stage coal liquefaction application at 404{degrees}C during this performance period. A Ni-Mo hydrous titanate catalyst on an Amocat support prepared by Sandia National laboratories was tested. Other baseline experiments using AO-60 and Amocat, both Ni-Mo/Al{sub 2}O{sub 3} supported catalysts, were also made. These experiments were short duration (approximately 12 days) and monitored the initial activity of the catalysts. The results of these tests indicate that the Sandia catalyst performed as well as the commercially prepared catalysts. Future tests are planned with other Sandia preparations. The dispersed catalysts tested include sulfated iron oxide, Bayferrox iron oxide (iron oxide from Miles, Inc.), and Bailey iron oxide (micronized iron oxide from Bailey, Inc.). The effects of space velocity, temperature, and solvent-to-coal ratio on coal liquefaction activity with the dispersed catalysts were investigated. A comparison of the coal liquefaction activity of these catalysts relative to iron catalysts tested earlier, including FeOOH-impregnated coal, was made. These studies are discussed.

  19. Explosive helium burning in white dwarf stars

    Khokhlov, A.M. (AN SSSR, Moscow. Astronomicheskij Sovet)

    1984-04-01

    Helium burning kinetics in white dwarfs has been considered at constant temperatures T >= 10/sup 9/ K and densities rho >10/sup 5/ g/cm/sup 3/. It is found, that helium detonation in white dwarfs does not lead to formation of light (A < 56) elements. Thus, helium white dwarf model for supernova 1 is inconsistent with observations.

  20. Clustering of Helium Atoms at a ½

    Berg, F. v.d.; Heugten, W. v.; Caspers, L.M.; Veen, A. v.; Hosson, J.Th.M. de

    1977-01-01

    Atomistic calculations on a ½<111>{110} edge dislocation show a restricted tendency of clustering of helium atom along this dislocation. Clusters with up to 4 helium atoms have been studied. A cluster with 3 helium proved to be most stable.

  1. Muonium and neutral muonic helium

    Orth, H.

    1981-01-01

    In this brief article the current status on muonium spectroscopy with emphasis on recent developments will be summarized. The experimental and theoretical progress of the muonic helium atom will be reviewed. Future directions in this field of research will be discussed. (orig./HSI)

  2. Electric response in superfluid helium

    Chagovets, Tymofiy

    2016-01-01

    Roč. 488, May (2016), s. 62-66 ISSN 0921-4526 R&D Projects: GA ČR GP13-03806P Institutional support: RVO:68378271 Keywords : superfluid helium * electric response * second sound * ions in He II Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.386, year: 2016

  3. Production of negative helium ions

    Toledo, A.S. de; Sala, O.

    1977-01-01

    A negative helium ion source using potassium charge exchange vapor has been developed to be used as an injector for the Pelletron accelerator. 3 He and α beam currents of up to 2μA have been extracted with 75% particle transmission through the machine [pt

  4. Post-cyclic behavior of low plasticity silt under full and limited liquefaction using triaxial compression testing.

    2010-02-01

    During an earthquake, liquefaction does not happen all the time. It depends on the duration and magnitude of the earthquake and the properties (with relationship to resistance of liquefaction) of the low plasticity silt. Under low duration or magnitu...

  5. Simplicity works for superfluid helium

    Bowley, Roger

    2000-01-01

    The famous philosopher Karl Popper once said that ''science is the art of systematic oversimplification''. Indeed, when faced with a new puzzle the trick is to simplify it without losing the essential physics - something that is easier said than done. However, this approach has paid off recently in low-temperature physics. Last year Richard Packard, Seamus Davis and co-workers at the University of California at Berkeley encountered a puzzling new phenomenon in superfluid helium-3, a quantum fluid that remains a liquid close to absolute zero and exhibits unusual properties such as the ability to flow without friction (A Machenkov et al. 1999 Phys. Rev. Lett. 83 3860). Previous experiments had revealed that certain effects in liquid helium are analogous to effects observed in superconductors, materials that lose all resistance to electric current at low temperatures. When the Berkeley researchers connected two reservoirs of superfluid helium-3, the superfluid flowed back and forth through apertures that formed a ''weak link'' between the two containers. This behaviour is similar to the oscillatory current of electrons that can flow across an insulating gap separating two superconductors - a device that is known as a Josephson junction. What was puzzling about the Berkeley results was that the helium-3 had two different stable configurations, both of which behaved in an unconventional way compared with a Josephson junction. This puzzle has now been solved independently by Sidney Yip at the National Center for Theoretical Sciences in Taiwan, and by Janne Viljas and Erkki Thuneberg at the Helsinki University of Technology in Finland (Phys. Rev. Lett. 1999 83 3864 and 3868). In this article the author describes the latest research on superfluid helium. (UK)

  6. Simplicity works for superfluid helium

    Bowley, Roger [University of Nottingham, Nottingham (United Kingdom)

    2000-02-01

    The famous philosopher Karl Popper once said that ''science is the art of systematic oversimplification''. Indeed, when faced with a new puzzle the trick is to simplify it without losing the essential physics - something that is easier said than done. However, this approach has paid off recently in low-temperature physics. Last year Richard Packard, Seamus Davis and co-workers at the University of California at Berkeley encountered a puzzling new phenomenon in superfluid helium-3, a quantum fluid that remains a liquid close to absolute zero and exhibits unusual properties such as the ability to flow without friction (A Machenkov et al. 1999 Phys. Rev. Lett. 83 3860). Previous experiments had revealed that certain effects in liquid helium are analogous to effects observed in superconductors, materials that lose all resistance to electric current at low temperatures. When the Berkeley researchers connected two reservoirs of superfluid helium-3, the superfluid flowed back and forth through apertures that formed a ''weak link'' between the two containers. This behaviour is similar to the oscillatory current of electrons that can flow across an insulating gap separating two superconductors - a device that is known as a Josephson junction. What was puzzling about the Berkeley results was that the helium-3 had two different stable configurations, both of which behaved in an unconventional way compared with a Josephson junction. This puzzle has now been solved independently by Sidney Yip at the National Center for Theoretical Sciences in Taiwan, and by Janne Viljas and Erkki Thuneberg at the Helsinki University of Technology in Finland (Phys. Rev. Lett. 1999 83 3864 and 3868). In this article the author describes the latest research on superfluid helium. (UK)

  7. Comparative study on liquefaction of creosote and chromated copper arsenate (CCA)-treated wood and untreated southern pine wood: effects of acid catalyst content, liquefaction time, temperature, and phenol to wood ratio

    Hui Pan; Chung-Yun Hse; Todd F. Shupe

    2009-01-01

    Creosote- and chromated copper arsenate (CCA)-treated wood waste and untreated southern pine wood were liquefied with phenol and sulfuric acid. The effects of sulfuric acid content, liquefaction time, liquefaction temperature, and phenol to wood ratio on liquefaction rate (i.e., wood residue content) were investigated and analyzed by analysis of variance (...

  8. Japan`s Sunshine Project. 1991 annual summary of coal liquefaction and gasification; 1991 nendo sunshine keikaku seika hokokusho gaiyoshu. Sekitan no ekika gas ka

    1992-07-01

    Out of the research and development on the 1991 Sunshine Project, the results of coal liquefaction/gasification are reported. The basic research of coal liquefaction/gasification is conducted. The research plan for a 150 ton/day scale pilot plant (PP) is worked out for the development of bituminous coal liquefaction technology by NEDOL process. Data of PSU (Process Support Units) operation, especially, are studied. Concerning the data obtained through dismantling of the 50 ton/day PP in Australia which uses Australian Victoria coal due to completion of its operation and also obtained from its support research, they are reflected in the design of a demonstration plant, and the results are arranged for study. Research and development on refining technology of coal-derived liquid such as Illinois coal liquid and on application technology of its products are made. For the development of coal-use hydrogen production technology, conducted is the research of a high temperature gasification PP by entrained flow bed process which is the core of the coal gasification technology. Elementary study with a 2 ton/day furnace is made for the development of the entrained flow bed coal gasification combined cycle power generation system. Also conducted are PP construction, adjusting operation and the overall research operation.

  9. Liquefaction of Lignocellulose in Fractionated Light Bio-Oil: Proof of Concept and Techno-Economic Assessment

    Kumar, S.; Lange, Jean Paul; van Rossum, G.; Kersten, Sascha R.A.

    2015-01-01

    The direct thermal liquefaction of lignocellulose can provide a biocrude that could be used as a precursor for biofuels. However, earlier attempts to use the whole reactor effluent as a liquefaction medium, by recycling it to the liquefaction reactor, were hampered by the buildup of heavy products.

  10. Renewable chemical feedstocks from integrated liquefaction processing of lingocellulosic materials using microwave energy

    Junming Xu; Jianchun Jiang; Chung-Yun Hse; Todd F. Shupe

    2012-01-01

    The objective of this investigation was to find a simple method for the production of phenolic rich products and sugar derivatives (biopolyols) via separation of liquefied lingocellulosic materials. Liquefaction of lignocellulosic materials was conducted in methanol at 180 °C for 15 min with the conversion of raw materials at about 75%. After liquefaction, the...

  11. Design, synthesis, and characterization of novel fine-particle, unsupported catalysts for coal liquefaction

    Klein, M.T.

    1991-12-30

    The purpose of this work is to investigate the kinetics-assisted design, synthesis and characterization of fme-pardcle, unsupported catalysts for coal liquefaction. The goal is to develop a fundamental understanding of coal catalysis and catalysts that will, in turn, allow for the specification of a novel optimal catalyst for coal liquefaction.

  12. Influence of solvent type on microwave-assisted liquefaction of bamboo

    Jiulong Xie; Chung Hse; Todd F. Shupe; Tingxing Hu

    2016-01-01

    Microwave-assisted liquefaction of bamboo in glycerol, polyethylene glycerol (PEG), methanol, ethanol, and water were comparatively investigated by evaluating the temperature-dependence for conversion and liquefied residue characteristics. The conversion for the liquefaction in methanol, ethanol, and water increased with an increase in reaction temperature, while that...

  13. Dynamic dielectric properties of a wood liquefaction system using polyethylene glycol and glycerol

    Mengchao Zhou; Thomas L. Eberhardt; Bo Cai; Chung-Yun Hse; Hui Pan

    2017-01-01

    Microwave-assisted liquefaction has shown potential for rapid thermal processing of lignocellulosic biomass. The efficiency of microwave heating depends largely on the dielectric properties of the materials being heated. The objective of this study was to investigate the dynamic interactions between microwave energy and the reaction system during the liquefaction of a...

  14. Online helium inventory monitoring of JLab cryogenic systems

    Hasan, N.; Knudsen, P.; Wright, M.

    2017-12-01

    There are five cryogenic plants at Jefferson Lab which support the LINAC, experiment hall end-stations and test facility. The majority of JLab’s helium inventory, which is around 15 tons, is allocated in the LINAC cryo-modules, with the majority of the balance of helium distributed at the cryogenic-plant level mainly as stored gas and liquid for stable operation. Due to the organic evolution of the five plants and independent actions within the experiment halls, the traditional inventory management strategy suffers from rapid identification of potential leaks. This can easily result in losses many times higher than the normally accepted (average) loss rate. A real-time program to quickly identify potential excessive leakage was developed and tested. This program was written in MATLAB© for portability, easy diagnostics and modification. It interfaces directly with EPICS to access the cryogenic system state, and with and NIST REFPROP© for real fluid properties. This program was validated against the actual helium offloaded into the system. The present paper outlines the details of the inventory monitoring program, its validation and a sample of the achieved results.

  15. Evaluation of soil liquefaction potential for level ground during earthquakes. A summary report

    Seed, H.B.; Arango, I.; Chan, C.K.

    1975-10-01

    The results of a three-year research program conducted to investigate the settlement and liquefaction of sands under multi-directional shaking are evaluated. The investigation indicated that the behavior of a saturated sand under cyclic loading conditions is a function of its geologic and seismic history and grain structure as well as its placement density. It is concluded that the resistance to liquefaction of a sand deposit can best be estimated by laboratory testing on undisturbed samples. It is shown that cyclic triaxial tests used in conjunction with appropriate correction factors to account for multi-directional shaking, simple shear loading conditions, and overconsolidation effects can provide valid data on cyclic loading characteristics. The concepts of ''limited strain potential'' and acceptable value of the factor of safety against initial liquefaction are introduced. Finally, the two basic methods for evaluating liquefaction potential and the effects of liquefaction are reviewed and updated with the information obtained through this research effort

  16. Kinetics of coal liquefaction during heating-up and isothermal stages

    Xian Li; Haoquan Hu; Shengwei Zhu; Shuxun Hu; Bo Wu; Meng Meng [Dalian University of Technology, Dalian (China). Institute of Coal Chemical Engineering

    2008-04-15

    Direct liquefaction of Shenhua bituminous coal was carried out in a 500 ml autoclave with iron catalyst and coal liquefaction cycle-oil as solvent at initial hydrogen of 8.0 MPa, residence time of 0-90 min. To investigate the liquefaction kinetics, a model for heating-up and isothermal stages was developed to estimate the rate constants of both stages. In the model, the coal was divided into three parts, easy reactive part, hard reactive part and unreactive part, and four kinetic constants were used to describe the reaction mechanism. The results showed that the model is valid for both heating-up and isothermal stages of liquefaction perfectly. The rate-controlled process for coal liquefaction is the reaction of preasphaltene plus asphaltene (PAA) to oil plus gas (O + G). The upper-limiting conversion of isothermal stage was estimated by the kinetic calculation. 21 refs., 4 figs., 4 tabs.

  17. Coal liquefaction policy in China: Explaining the policy reversal since 2006

    Rong Fang; Victor, David G.

    2011-01-01

    China has emerged as a leader in coal liquefaction. While the country's abundant coal resources and acute concerns about oil security help explain China's interest in liquefaction, the driving forces for this industry are complicated and policy has been inconsistent. Since 2006 Beijing has tried to slow down the development of liquefaction; even as China has become more dependent on imported oil, the central government has been wary about the large impact of liquefaction technologies on scarce resources such as water. However, local government officials in coal rich areas have strong incentives to pour investment into the technology, which helps explain the uneven development and policy. The future of coal liquefaction will depend on how these forces unfold along with major Beijing-led reforms in the Chinese coal industry, which is closing smaller mines and favoring the emergence of larger coal producing firms. Those reforms will have mixed effects on liquefaction. They temporarily contribute to higher prices for coal while over the longer term creating coal companies that have much greater financial and technical skills needed to deploy technologies such as coal liquefaction at a scale needed if this energy pathway is to be competitive with conventional sources of liquid fuel. - Highlights: ► We explain swings in Chinese policy on coal liquefaction, a possible substitute for imported oil. ► Since 2006 Beijing's support has waned due to fears about environmental impacts and cost of liquefaction. ► Local governments in some coal rich regions remain strongly supportive. ► Volatile oil prices and rising coal prices make this industry more risky than previously thought. ► Consolidation of the coal industry will have mixed effects on viability of liquefaction projects.

  18. Impulse approximation in solid helium

    Glyde, H.R.

    1985-01-01

    The incoherent dynamic form factor S/sub i/(Q, ω) is evaluated in solid helium for comparison with the impulse approximation (IA). The purpose is to determine the Q values for which the IA is valid for systems such a helium where the atoms interact via a potential having a steeply repulsive but not infinite hard core. For 3 He, S/sub i/(Q, ω) is evaluated from first principles, beginning with the pair potential. The density of states g(ω) is evaluated using the self-consistent phonon theory and S/sub i/(Q,ω) is expressed in terms of g(ω). For solid 4 He resonable models of g(ω) using observed input parameters are used to evaluate S/sub i/(Q,ω). In both cases S/sub i/(Q, ω) is found to approach the impulse approximation S/sub IA/(Q, ω) closely for wave vector transfers Q> or approx. =20 A -1 . The difference between S/sub i/ and S/sub IA/, which is due to final state interactions of the scattering atom with the remainder of the atoms in the solid, is also predominantly antisymmetric in (ω-ω/sub R/), where ω/sub R/ is the recoil frequency. This suggests that the symmetrization procedure proposed by Sears to eliminate final state contributions should work well in solid helium

  19. Probabilistic versus deterministic hazard assessment in liquefaction susceptible zones

    Daminelli, Rosastella; Gerosa, Daniele; Marcellini, Alberto; Tento, Alberto

    2015-04-01

    Probabilistic seismic hazard assessment (PSHA), usually adopted in the framework of seismic codes redaction, is based on Poissonian description of the temporal occurrence, negative exponential distribution of magnitude and attenuation relationship with log-normal distribution of PGA or response spectrum. The main positive aspect of this approach stems into the fact that is presently a standard for the majority of countries, but there are weak points in particular regarding the physical description of the earthquake phenomenon. Factors like site effects, source characteristics like duration of the strong motion and directivity that could significantly influence the expected motion at the site are not taken into account by PSHA. Deterministic models can better evaluate the ground motion at a site from a physical point of view, but its prediction reliability depends on the degree of knowledge of the source, wave propagation and soil parameters. We compare these two approaches in selected sites affected by the May 2012 Emilia-Romagna and Lombardia earthquake, that caused widespread liquefaction phenomena unusually for magnitude less than 6. We focus on sites liquefiable because of their soil mechanical parameters and water table level. Our analysis shows that the choice between deterministic and probabilistic hazard analysis is strongly dependent on site conditions. The looser the soil and the higher the liquefaction potential, the more suitable is the deterministic approach. Source characteristics, in particular the duration of strong ground motion, have long since recognized as relevant to induce liquefaction; unfortunately a quantitative prediction of these parameters appears very unlikely, dramatically reducing the possibility of their adoption in hazard assessment. Last but not least, the economic factors are relevant in the choice of the approach. The case history of 2012 Emilia-Romagna and Lombardia earthquake, with an officially estimated cost of 6 billions

  20. Thermostable endoglucanases in the liquefaction of hydrothermally pretreated wheat straw

    Siika-aho Matti

    2011-01-01

    Full Text Available Abstract Background Thermostable enzymes have several benefits in lignocellulose processing. In particular, they potentially allow the use of increased substrate concentrations (because the substrate viscosity decreases as the temperature increases, resulting in improved product yields and reduced capital and processing costs. A short pre-hydrolysis step at an elevated temperature using thermostable enzymes aimed at rapid liquefaction of the feedstock is seen as an attractive way to overcome the technical problems (such as poor mixing and mass transfer properties connected with high initial solid loadings in the lignocellulose to ethanol process. Results The capability of novel thermostable enzymes to reduce the viscosity of high-solid biomass suspensions using a real-time viscometric measurement method was investigated. Heterologously expressed enzymes from various thermophilic organisms were compared for their ability to liquefy the lignocellulosic substrate, hydrothermally pretreated wheat straw. Once the best enzymes were identified, the optimal temperatures for these enzymes to decrease substrate viscosity were compared. The combined hydrolytic properties of the thermostable preparations were tested in hydrolysis experiments. The studied mixtures were primarily designed to have good liquefaction potential, and therefore contained an enhanced proportion of the key liquefying enzyme, EGII/Cel5A. Conclusions Endoglucanases were shown to have a superior ability to rapidly reduce the viscosity of the 15% (w/w; dry matter hydrothermally pretreated wheat straw. Based on temperature profiling studies, Thermoascus aurantiacus EGII/Cel5A was the most promising enzyme for biomass liquefaction. Even though they were not optimized for saccharification, many of the thermostable enzyme mixtures had superior hydrolytic properties compared with the commercial reference enzymes at 55°C.

  1. Hydrogen Process Coupling to Modular Helium Reactors

    Shenoy, Arkal; Richards, Matt; Buckingham, Robert

    2009-01-01

    The U.S. Department of Energy (DOE) has selected the helium-cooled High Temperature Gas-Cooled Reactor (HTGR) as the concept to be used for the Next Generation Nuclear Plant (NGNP), because it is the most advanced Generation IV concept with the capability to provide process heat at sufficiently high temperatures for production of hydrogen with high thermal efficiency. Concurrently with the NGNP program, the Nuclear Hydrogen Initiative (NHI) was established to develop hydrogen production technologies that are compatible with advanced nuclear systems and do not produce greenhouse gases. The current DOE schedule for the NGNP Project calls for startup of the NGNP plant by 2021. The General Atomics (GA) NGNP pre-conceptual design is based on the GA Gas Turbine Modular Helium Reactor (GT-MHR), which utilizes a direct Brayton cycle Power Conversion System (PCS) to produce electricity with a thermal efficiency of 48%. The nuclear heat source for the NGNP consists of a single 600-MW(t) MHR module with two primary coolant loops for transport of the high-temperature helium exiting the reactor core to a direct cycle PCS for electricity generation and to an Intermediate Heat Exchanger (IHX) for hydrogen production. The GA NGNP concept is designed to demonstrate hydrogen production using both the thermochemical sulfur-iodine (SI) process and high-temperature electrolysis (HTE). The two primary coolant loops can be operated independently or in parallel. The reactor design is essentially the same as that for the GT-MHR, but includes the additional primary coolant loop to transport heat to the IHX and other modifications to allow operation with a reactor outlet helium temperature of 950 .deg. C (vs. 850 .deg. C for the GT-MHR). The IHX transfers a nominal 65 MW(t) to the secondary heat transport loop that provides the high-temperature heat required by the SI-based and HTE-based hydrogen production facilities. Two commercial nuclear hydrogen plant variations were evaluated with

  2. Self-trapping of helium in metals

    Wilson, W.D.; Bisson, C.L.; Baskes, M.I.

    1981-01-01

    Atomistic calculations are presented which demonstrate that helium atoms in a metal lattice are able to cluster with each other, producing vacancies and nearby self-interstitial defects. Even a small number of helium atoms is found to be sufficient to create these large distortions. As few as five interstitial helium can spontaneously produce a lattice vacancy and nearby self-interstitial. An eight-helium-atom cluster gives rise to two such defects, and 16 helium atoms to more than five self-interstitial vacancy pairs. It was noted that the self-interstitials prefer to agglomerate on the same ''side'' of the helium cluster rather than to spread themselves out uniformly. The binding energy of each additional helium atom to these clusters increases with helium concentration and the trap is apparently unsaturable. A rate theory using these atomistic binding energies has been used to calculate the kinetics of helium-bubble nucleation and growth. The results are consistent with measurements of the properties of helium resulting from tritium decay

  3. Helium in inert matrix dispersion fuels

    Veen, A. van; Konings, R.J.M.; Fedorov, A.V.

    2003-01-01

    The behaviour of helium, an important decay product in the transmutation chains of actinides, in dispersion-type inert matrix fuels is discussed. A phenomenological description of its accumulation and release in CERCER and CERMET fuel is given. A summary of recent He-implantation studies with inert matrix metal oxides (ZrO 2 , MgAl 2 O 4 , MgO and Al 2 O 3 ) is presented. A general picture is that for high helium concentrations helium and vacancy defects form helium clusters which convert into over-pressurized bubbles. At elevated temperature helium is released from the bubbles. On some occasions thermal stable nano-cavities or nano-pores remain. On the basis of these results the consequences for helium induced swelling and helium storage in oxide matrices kept at 800-1000 deg. C will be discussed. In addition, results of He-implantation studies for metal matrices (W, Mo, Nb and V alloys) will be presented. Introduction of helium in metals at elevated temperatures leads to clustering of helium to bubbles. When operational temperatures are higher than 0.5 melting temperature, swelling and helium embrittlement might occur

  4. Latent hazard related to a hydrogen liquefaction installation

    Spoendlin, R.

    1961-01-01

    In this note, the author reports an attempt of analysis of hazards which could be related to a hydrogen liquefaction installation in order to identify the most appropriate safety measures. In order to do so, experiments have been performed on electrostatic charges born by solid crystals in liquid hydrogen, and explosion tests have been performed on a mixture of solid oxygen and liquid hydrogen. Moreover, the author tried to analyse accidents which occurred in this field by performing a survey among scientists working in laboratories in different countries

  5. Ground Characterization Studies in Canakkale Pilot Site of LIQUEFACT Project

    Ozcep, F.; Oztoprak, S.; Aysal, N.; Bozbey, I.; Tezel, O.; Ozer, C.; Sargin, S.; Bekin, E.; Almasraf, M.; Cengiz Cinku, M.; Ozdemir, K.

    2017-12-01

    The our aim is to outline the ground characterisation studies in Canakkale test site. Study is based on the EU H2020 LIQUEFACT project entitled "Liquefact: Assessment and mitigation of liquefaction potential across Europe: a holistic approach to protect structures / infrastructures for improved resilience to earthquake-induced liquefaction disasters". Objectives and extent of ground characterization for Canakkale test site includes pre-existing soil investigation studies and complementary field studies. There were several SPT and geophysical tests carried out in the study area. Within the context of the complementary tests, six (6) study areas in the test site were chosen and complementary tests were carried out in these areas. In these areas, additional boreholes were opened and SPT tests were performed. It was decided that additional CPT (CPTU and SCPT) and Marchetti Dilatometer (DMT) tests should be carried out within the scope of the complementary testing. Seismic refraction, MASW and micro tremor measurements had been carried out in pre-existing studies. Shear wave velocities obtained from MASW measurements were evaluated to the most rigorous level. These tests were downhole seismic, PS-logging, seismic refraction, 2D-ReMi, MASW, micro tremor (H/V Nakamura method), 2D resistivity and resonance acoustic profiling (RAP). RAP is a new technique which will be explained briefly in the relevant section. Dynamic soil properties had not been measured in pre-existing studies, therefore these properties were investigated within the scope of the complementary tests. Selection of specific experimental tests of the complementary campaign was based on cost-benefit considerations Within the context of complementary field studies, dynamic soil properties were measured using resonant column and cyclic direct shear tests. Several sieve analyses and Atterberg Limits tests which were documented in the pre-existing studies were evaluated. In the complementary study carried out

  6. Liquefaction of Saturated Soil and the Diffusion Equation

    Sawicki, Andrzej; Sławińska, Justyna

    2015-06-01

    The paper deals with the diffusion equation for pore water pressures with the source term, which is widely promoted in the marine engineering literature. It is shown that such an equation cannot be derived in a consistent way from the mass balance and the Darcy law. The shortcomings of the artificial source term are pointed out, including inconsistencies with experimental data. It is concluded that liquefaction and the preceding process of pore pressure generation and the weakening of the soil skeleton should be described by constitutive equations within the well-known framework of applied mechanics. Relevant references are provided

  7. Rationale for continuing R&D in indirect coal liquefaction

    Gray, D.; Tomlinson, G. [MITRE Corp., McLean, VA (United States)

    1995-12-31

    The objective of this analysis is to use the world energy demand/supply model developed at MITRE to examine future liquid fuels supply scenarios both for the world and for the United States. This analysis has determined the probable extent of future oil resource shortages and the likely time frame in which the shortages will occur. The role that coal liquefaction could play in helping to alleviate this liquid fuels shortfall is also examined. The importance of continuing R&D to improve process performance and reduce the costs of coal-derived transportation fuel is quantified in terms of reducing the time when coal liquids will become competitive with petroleum.

  8. The Comparative Analysis of the Efficiency of Coal Liquefaction Technologies

    Rudyka Viktor I.

    2017-12-01

    Full Text Available Organization of production of synthetic liquid fuels (SLF in Ukraine becomes an especially topical and at the same time complex scientific and applied task, taking into consideration criteria of the techno-ecological and economic rationality. The article presents a methodical approach to the comparative analysis of efficiency of the main methods and technologies for the synthetic liquid fuels production and a carried out testing, the results of which allowed to conclude that the most rational is the technology of indirect coal liquefaction based on coal thermal plasma gasification.

  9. Probabilistic liquefaction hazard analysis at liquefied sites of 1956 Dunaharaszti earthquake, in Hungary

    Győri, Erzsébet; Gráczer, Zoltán; Tóth, László; Bán, Zoltán; Horváth, Tibor

    2017-04-01

    Liquefaction potential evaluations are generally made to assess the hazard from specific scenario earthquakes. These evaluations may estimate the potential in a binary fashion (yes/no), define a factor of safety or predict the probability of liquefaction given a scenario event. Usually the level of ground shaking is obtained from the results of PSHA. Although it is determined probabilistically, a single level of ground shaking is selected and used within the liquefaction potential evaluation. In contrary, the fully probabilistic liquefaction potential assessment methods provide a complete picture of liquefaction hazard, namely taking into account the joint probability distribution of PGA and magnitude of earthquake scenarios; both of which are key inputs in the stress-based simplified methods. Kramer and Mayfield (2007) has developed a fully probabilistic liquefaction potential evaluation method using a performance-based earthquake engineering (PBEE) framework. The results of the procedure are the direct estimate of the return period of liquefaction and the liquefaction hazard curves in function of depth. The method combines the disaggregation matrices computed for different exceedance frequencies during probabilistic seismic hazard analysis with one of the recent models for the conditional probability of liquefaction. We have developed a software for the assessment of performance-based liquefaction triggering on the basis of Kramer and Mayfield method. Originally the SPT based probabilistic method of Cetin et al. (2004) was built-in into the procedure of Kramer and Mayfield to compute the conditional probability however there is no professional consensus about its applicability. Therefore we have included not only Cetin's method but Idriss and Boulanger (2012) SPT based moreover Boulanger and Idriss (2014) CPT based procedures into our computer program. In 1956, a damaging earthquake of magnitude 5.6 occurred in Dunaharaszti, in Hungary. Its epicenter was located

  10. Study on thermochemical liquefaction of biomass feedstocks; Biomass genryo no yuka hanno tokusei ni kansuru kisoteki kenkyu

    NONE

    1997-02-10

    Liquefaction is applied to various biomass wastes and unused biomass to study characteristics of the liquefaction in each case. The paper described the system of the conversion and use of biomass into energy, conducted the positioning of the liquefaction, and outlined a history of the liquefaction chemistry and the study. To obtain basic data of characteristics of the liquefaction of various biomass raw materials, the liquefaction was conducted changing operational factors for the purpose of clarifying the product distribution of oil and by-products and oil properties. A comprehensive consideration was made of the liquefaction based on basic data and literature reports on the liquefaction of various biomass. From the above-mentioned studies, it was concluded that the energy can be recovered in a form of oil by applying the liquefaction to various biomass materials. A series of the study clarified effects of various operational factors on characteristics of the liquefaction as well as effects of classification of biomass materials and composition of the materials on characteristics of the liquefaction. 141 refs., 78 figs., 56 tabs.

  11. Cooperative research in coal liquefaction infratechnology and generic technology development: Final report, October 1, 1985 to December 31, 1986

    Sendlein, L.V.A.

    1987-06-29

    During the first year of its research program, the Consortium for Fossil Fuel Liquefaction Science has made significant progress in many areas of coal liquefaction and coal structure research. Research topics for which substantial progress has been made include integrated coal structure and liquefaction studies, investigation of differential liquefaction processes, development and application of sophisticated techniques for structural analysis, computer analysis of multivariate data, biodesulfurization of coal, catalysis studies, co-processing of coal and crude oil, coal dissolution and extraction processes, coal depolymerization, determination of the liquefaction characteristics of many US coals for use in a liquefaction database, and completion of a retrospective technology assessment for direct coal liquefaction. These and related topics are discussed in considerably more detail in the remainder of this report. Individual projects are processed separately for the data base.

  12. Helium diffusion in nickel at high temperatures

    Philipps, V.

    1980-09-01

    Helium has been implanted at certain temperatures between 800 and 1250 0 C into single and polycrystalline Ni-samples with implantation depths between 15 and 90 μm. Simultaneously the helium reemission from the sample is measured by a mass-spectrometer. It has been shown that the time dependence of the observed reemission rate is governed by volume diffusion of the helium. Measuring this time dependence as a function of temperature the helium diffusion constant has been determined. The He-diffusion is interpreted as a interstitial diffusion hindered by thermal vacancies. Depending on the implantation depth more or less of the implanted helium remains in the sample and forms large helium bubbles. (orig./GSCH)

  13. Test of a cryogenic helium pump

    Lue, J.W.; Miller, J.R.; Walstrom, P.L.; Herz, W.

    1981-01-01

    The design of a cryogenic helium pump for circulating liquid helium in a magnet and the design of a test loop for measuring the pump performance in terms of mass flow vs pump head at various pump speeds are described. A commercial cryogenic helium pump was tested successfully. Despite flaws in the demountable connections, the piston pump itself has performed satisfactorily. A helium pump of this type is suitable for the use of flowing supercritical helium through Internally Cooled Superconductor (ICS) magnets. It has pumped supercritical helium up to 7.5 atm with a pump head up to 2.8 atm. The maximum mass flow rate obtained was about 16 g/s. Performance of the pump was degraded at lower pumping speeds

  14. Backscattered Helium Spectroscopy in the Helium Ion Microscope: Principles, Resolution and Applications

    van Gastel, Raoul; Hlawacek, G.; Dutta, S.; Poelsema, Bene

    2015-01-01

    We demonstrate the possibilities and limitations for microstructure characterization using backscattered particles from a sharply focused helium ion beam. The interaction of helium ions with matter enables the imaging, spectroscopic characterization, as well as the nanometer scale modification of

  15. Helium leak testing methods in nuclear applications

    Ahmad, Anis

    2004-01-01

    Helium mass-spectrometer leak test is the most sensitive leak test method. It gives very reliable and sensitive test results. In last few years application of helium leak testing has gained more importance due to increased public awareness of safety and environment pollution caused by number of growing chemical and other such industries. Helium leak testing is carried out and specified in most of the critical area applications like nuclear, space, chemical and petrochemical industries

  16. Report on the brown coal liquefaction sub-committee in fiscal 1992; 1992 nendo kattan ekika bukai hokokusho

    NONE

    1993-03-01

    This paper reports the activities of the brown coal liquefaction sub-committee in fiscal 1992. The first sub-committee meeting presented an interim report on the status of progress in complementary researches in fiscal 1992. The report covers the following items: discussions on effects of reaction factors on scale deposition in a preheater and a reactor and the liquefaction oil yield, supplementary experiments to enhance recovery rate of naphtha from under-flow in the de-ashing system and enhance accuracy of expression to estimate the interface precipitation velocity, and discussions on product oil types and catalyst types. The second sub-committee meeting reported fundamental discussions on the primary hydrogenation and hot water treatment of brown coal as an interim report on the achievements, and discussions on de-ashing and catalyst properties, liquefying reaction activity and scaling performance of catalysts. The third meeting reported the support on compiling the achievements by means of collecting complementary data of the pilot plant using PDU. A 7,800-hour life verification test was completed on the fixed bed secondary hydrogenation catalyst. A method was established to recover naphtha from the under-flow in a de-ashing settler. An expression to estimate the interface precipitation velocity was also established. Affirmation was made on the pylite catalyst performance, and reactivity of the category A coal assumed in the demonstration device. (NEDO)

  17. LNG plant combined with power plant

    Aoki, I; Kikkawa, Y [Chiyoda Chemical Engineering and Construction Co. Ltd., Tokyo (Japan)

    1997-06-01

    The LNG plant consumers a lot of power of natural gas cooling and liquefaction. In some LNG plant location, a rapid growth of electric power demand is expected due to the modernization of area and/or the country. The electric power demand will have a peak in day time and low consumption in night time, while the power demand of the LNG plant is almost constant due to its nature. Combining the LNG plant with power plant will contribute an improvement the thermal efficiency of the power plant by keeping higher average load of the power plant, which will lead to a reduction of electrical power generation cost. The sweet fuel gas to the power plant can be extracted from the LNG plant, which will be favorable from view point of clean air of the area. (Author). 5 figs.

  18. LNG plant combined with power plant

    Aoki, I.; Kikkawa, Y.

    1997-01-01

    The LNG plant consumers a lot of power of natural gas cooling and liquefaction. In some LNG plant location, a rapid growth of electric power demand is expected due to the modernization of area and/or the country. The electric power demand will have a peak in day time and low consumption in night time, while the power demand of the LNG plant is almost constant due to its nature. Combining the LNG plant with power plant will contribute an improvement the thermal efficiency of the power plant by keeping higher average load of the power plant, which will lead to a reduction of electrical power generation cost. The sweet fuel gas to the power plant can be extracted from the LNG plant, which will be favorable from view point of clean air of the area. (Author). 5 figs

  19. Subtask 3.9 - Direct Coal Liquefaction Process Development

    Aulich, Ted; Sharma, Ramesh

    2012-07-01

    The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha middle distillate stream for upgrading and 2) a recycle stream was completed in May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.

  20. Novel use of residue from direct coal liquefaction process

    Jianli Yang; Zhaixia Wang; Zhenyu Liu; Yuzhen Zhang [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion

    2009-09-15

    Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA), a superior commercial modifier. Asphalts modified by two DCLRs meet the specifications of ASTM D5710 and BSI BS-3690 designated for the TLA-modified asphalts. The required addition amount for the DCLRs tested is less than that for TLA due possibly to the high content of asphaltene in DCLRs. Different compatibility was observed for the asphalts with the same penetration grade but from the different origin. Different components in the DCLR play different roles in the modification. Positive synergetic effects among the fractions were observed, which may due to the formation of the stable colloid structure. Unlike polymer-type modifier, the structure of asphalt-type modifier has a similarity with petroleum asphalts which favors the formation of a stable dispersed polar fluid (DPF) colloid structure and improves the performance of pavement asphalt. 12 refs., 1 fig., 6 tabs.

  1. Efficient Air Desulfurization Catalysts Derived from Pig Manure Liquefaction Char

    Rajiv Wallace

    2017-11-01

    Full Text Available Biochar from the liquefaction of pig manure was used as a precursor of H2S desulfurization adsorbents. In its inorganic matter, it contains marked quantities of calcium, magnesium and iron, which are known as hydrogen sulfide oxidation catalysts. The char was used either as-received or mixed with 10% nanographite. The latter was added to increase both the content of the carbon phase and conductivity. ZnCl2 in two different ratios of char to an activation agent (1:1 and 1:2 was used to create the porosity in the carbon phase. The content of the later was between 18–45%. The activated samples adsorbed 144 mg/g H2S. Sulfur was the predominant product of reactive adsorption. Its deposition in the pore system and blockage of the most active pores ceased the materials’ activity. The presence of the catalytic phase was necessary but not sufficient to guarantee good performance. The developed porosity, which can store oxidation products in the resulting composite, is essential for the good performance of the desulfurization process. The surface of the composite with nanographite showed the highest catalytic activity, similar to that of the commercial Midas® carbon catalyst. The results obtained indicate that a high quality reactive adsorbent/catalyst for H2S removal can be obtained from pig manure liquefaction wastes.

  2. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction

    Chunshan, Song; Kirby, S.; Schmidt, E. [Pennsylvania State Univ., University Park, PA (United States)] [and others

    1995-12-31

    The objective of this project is to explore bimetallic dispersed catalysts for more efficient coal liquefaction. Coal liquefaction involves cleavage of methylene, dimethylene and ether bridges connecting various aromatic units and the reactions of various oxygen functional groups. This paper describes recent results on (1) hydrodeoxygenation of O-containing polycyclic model compounds using novel organometallic catalyst precursors; and (2) activity and selectivity of dispersed Fe catalysts from organometallic and inorganic precursors for hydrocracking of 4-(1-naphthylmethyl) bibenzyl. The results showed that some iron containing catalysts have higher activity in the sulfur-free form, contrary to conventional wisdom. Adding sulfur to Fe precursors with Cp-ligands decreased the activity of the resulting catalyst. This is in distinct contrast to the cases with iron pentacarbonyl and superfine Fe{sub 2}O{sub 3}, where S addition increased their catalytic activity substantially. A positive correlation between sulfur addition and increased activity can be seen, but a reversed trend between Fe cluster size and hydrocracking conversion could be observed, for carbonyl-type Fe precursors. It is apparent that the activity and selectivity of Fe catalysts for NMBB conversion depends strongly on both the type of ligand environment, the oxidation state and the number of intermetal bonds in the molecular precursor.

  3. Behaviour of helium after implantation in molybdenum

    Viaud, C.; Maillard, S.; Carlot, G.; Valot, C.; Gilabert, E.; Sauvage, T.; Peaucelle, C.; Moncoffre, N.

    2009-01-01

    This study deals with the behaviour of helium in a molybdenum liner dedicated to the retention of fission products. More precisely this work contributes to evaluate the release of implanted helium when the gas has precipitated into nanometric bubbles close to the free surface. A simple model dedicated to calculate the helium release in such a condition is presented. The specificity of this model lays on the assumption that the gas is in equilibrium with a simple distribution of growing bubbles. This effort is encouraging since the calculated helium release fits an experimental dataset with a set of parameters in good agreement with the literature

  4. Helium Extraction from LNG End Flash

    Kim, Donghoi

    2014-01-01

    Helium is an invaluable element as it is widely used in industry such as cryo-genics and welding due to its unique properties. However, helium shortage is expected in near future because of increasing demand and the anxiety of sup-ply. Consequently, helium production has attracted the attention of industry. The main source of He is natural gas and extracting it from LNG end-flash is considered as the most promising way of producing crude helium. Thus, many process suppliers have proposed proc...

  5. Helium supply demand in future years

    Laverick, C.

    1975-01-01

    Adequate helium will be available to the year 2000 AD to meet anticipated helium demands for present day applications and the development of new superconducting technologies of potential importance to the nation. It is almost certain that there will not be enough helium at acceptable financial and energy cost after the turn of the century to meet the needs of the many promising helium based technologies now under development. Serious consideration should be given to establishing priorities in development and application based upon their relative value to the country. In the first half of the next century, three ways of estimating helium demand lead to cumulative ranges of from 75 to 125 Gcf (economic study), 89 to 470 Gcf (projected national energy growth rates) and 154 to 328 Gcf (needs for new technologies). These needs contrast with estimated helium resources in natural gas after 2000 AD which may be as low as 10 or 126 Gcf depending upon how the federal helium program is managed and the nation's natural gas resources are utilized. The technological and financial return on a modest national investment in further helium storage and a rational long term helium program promises to be considerable

  6. Report for fiscal 1995 by basic liquefaction technology subcommittee; 1995 nendo ekika kiban gijutsu bukai hokokusho

    NONE

    1996-03-01

    Delivered at the 1st meeting are a report on the fiscal 1995 research plan and an interim report, involving the use of coal-derived oils, research on refining technology using a PDU (process developing unit), reforming technology and petroleum blending technology for coal-derived oils, development of new reforming catalysts, technology of heterocompound separation, and the development of applications. Reported in relation with the development of environmentally friendly coal liquefaction technology are the study of coal liquefaction conditions, study of the upgrading of basic liquefaction techniques for the improvement and rationalization of the liquefaction process, and a project of liquefaction technology internationalization. A report is also given on a liquefaction catalyst study meeting. At the 2nd meeting, reports are delivered on the development of environmentally friendly coal liquefaction technology, including a briefing on the situation in general, designing of highly active catalysts, elucidation of the mechanism of emergence of activity, achievement of the marginal yield of coal-derived oils, and the properties of catalyst attached to coal. Delivered in relation with the use of coal-derived oils and technology for their refining are a briefing on the situation in general and reports on the blockup to occur in the naphtha fraction process and measures to counter the problem, control of the metamorphosis of active metals in reaction, heterocompound separation technology, and the development of applications. (NEDO)

  7. Post Hoc Analysis of Passive Cavitation Imaging for Classification of Histotripsy-Induced Liquefaction in Vitro.

    Bader, Kenneth B; Haworth, Kevin J; Maxwell, Adam D; Holland, Christy K

    2018-01-01

    Histotripsy utilizes focused ultrasound to generate bubble clouds for transcutaneous tissue liquefaction. Bubble activity maps are under development to provide image guidance and monitor treatment progress. The aim of this paper was to investigate the feasibility of using plane wave B-mode and passive cavitation images to be used as binary classifiers of histotripsy-induced liquefaction. Prostate tissue phantoms were exposed to histotripsy pulses over a range of pulse durations (5- ) and peak negative pressures (12-23 MPa). Acoustic emissions were recorded during the insonation and beamformed to form passive cavitation images. Plane wave B-mode images were acquired following the insonation to detect the hyperechoic bubble cloud. Phantom samples were sectioned and stained to delineate the liquefaction zone. Correlation between passive cavitation and plane wave B-mode images and the liquefaction zone was assessed using receiver operating characteristic (ROC) curve analysis. Liquefaction of the phantom was observed for all the insonation conditions. The area under the ROC (0.94 versus 0.82), accuracy (0.90 versus 0.83), and sensitivity (0.81 versus 0.49) was greater for passive cavitation images relative to B-mode images ( ) along the azimuth of the liquefaction zone. The specificity was greater than 0.9 for both imaging modalities. These results demonstrate a stronger correlation between histotripsy-induced liquefaction and passive cavitation imaging compared with the plane wave B-mode imaging, albeit with limited passive cavitation image range resolution.

  8. Effect of pre-swelling of coal on its liquefaction properties

    Hengfu Shui; Zhicai Wang; Meixia Cao [Anhui University of Technology, Ma' anshan (China). School of Chemistry & Chemical Engineering

    2007-07-01

    The effects of pre-swelling of Shenhua coal on its liquefaction property were studied in this paper. It was found that pre-swelling treatments of Shenhua coal in three solvents, i.e toluene (TOL), N-methyl-2-pyrrolidinone (NMP) and tetralin (THN) increased its liquefaction conversion, and the liquefied product distributions were also quite different. Removal of the pre-swelling solvent from the swollen coals further increased the liquefaction conversion compared to that of the swollen coals with the swelling solvent existed in them. It was found that oil and gas yields for the liquefaction of swollen coals in NMP and TOL with swelling solvent existed dramatically decreased. Pre-swelling in THN at 120{sup o}C gave the highest liquefaction conversion, however the liquefaction conversion decreased with the increase of pre-swelling temperature in the case of NMP. TG and FTIR analyses of raw coal, the swollen coals and liquefied products were carried out and the mechanism of the effects of pre-swelling of coal on its extraction and liquefaction behaviors were probed in the paper. 12 refs., 6 figs., 3 tabs.

  9. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report

    Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

    1997-11-01

    Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

  10. Liquefaction induced by earthquakes in Japan. Jiban no ekijoka/ekijoka saigai chosa kenkyu no seika

    Tono, I [Nation Inst. for Enviromental Studies, Tsukuba (Japan)

    1992-09-01

    Disaster caused by liquefaction is an important problem for the development of water-front because most of the places suffered from liquefaction disasters recently are located on sandy grounds. The damaged cases in the past due to liquefaction induced by earthquakes are grouped into: subsidence and inclination caused by the loss of supporting force of the ground, coming to the surface of buried structures due to excess pore hydrostatic pressure, destruction of lifeline accompanying the fluidization of ground, breakdown of bulkhead, retaining wall, etc. by increased earth pressure, sinking of soil structures, ground fissure, sliding, and immersion in floods and submergence of farms due to spouting of underground water. As regards prediction of liquefaction, description is made on the prediction of the occurrence of liquefaction and liquefaction prediction for which sedimentation environment is taken into consideration. Open-cut investigation can be said as the most effective means for accurate learning of the depth, thickness and sedimentation structure of liquefied layers. Liquefaction layers found in remains are also introduced. 16 refs., 6 figs.

  11. Evaluation of helium impurity impacts on Spent Nuclear Fuel project processes (OCRWM)

    SHERRELL, D.L.

    1999-09-21

    This document identifies the types and quantities of impurities that may be present within helium that is introduced into multi-canister overpacks (MCO)s by various SNF Project facilities, including, but not limited to the Cold Vacuum Drying (CVD) Facility (CVDF). It then evaluates possible impacts of worst case impurity inventories on MCO drying, transportation, and storage processes. Based on the evaluation results, this document: (1) concludes that the SNF Project helium procurement specification can be a factor-of-ten less restrictive than a typical vendor's standard offering (99.96% pure versus the vendor's 99.997% pure standard offering); (2) concludes that the CVDF's current 99.5% purity requirement is adequate to control the quality of the helium that is delivered to the MCO by the plant's helium distribution system; and (3) recommends specific impurity limits for both of the above cases.

  12. Evaluation of helium impurity impacts on Spent Nuclear Fuel project processes (OCRWM)

    SHERRELL, D.L.

    1999-01-01

    This document identifies the types and quantities of impurities that may be present within helium that is introduced into multi-canister overpacks (MCO)s by various SNF Project facilities, including, but not limited to the Cold Vacuum Drying (CVD) Facility (CVDF). It then evaluates possible impacts of worst case impurity inventories on MCO drying, transportation, and storage processes. Based on the evaluation results, this document: (1) concludes that the SNF Project helium procurement specification can be a factor-of-ten less restrictive than a typical vendor's standard offering (99.96% pure versus the vendor's 99.997% pure standard offering); (2) concludes that the CVDF's current 99.5% purity requirement is adequate to control the quality of the helium that is delivered to the MCO by the plant's helium distribution system; and (3) recommends specific impurity limits for both of the above cases

  13. New helium spectrum variable and a new helium-rich star

    Walborn, N.R.

    1974-01-01

    HD 184927, known previously as a helium-rich star, has been found to have a variable helium spectrum; the equivalent widths of five He I lines are larger by an average of 46 percent on a 1974 spectrogram than on one obtained with the same equipment in 1970. HD 186205 has been found to be a new, pronounced helium-rich star. (auth)

  14. Helium transfer line installation details.

    G. Perinic

    2007-01-01

    A particularity of the 32 m long four in one helium transfer line in between the cold box in USC55 and the cavern UX5 is the fact that the transfer line passes through a hole in the crane rail support beam. In order to ensure the alignment of the suspension rail in the interconnecting tunnel with the hole in the rail support as well as the connection points at both ends required precise measurements of the given geometries as well as the installation of a temporary target for the verification of the theoretical predictions.

  15. Helium bubble bursting in tungsten

    Sefta, Faiza; Juslin, Niklas; Wirth, Brian D.

    2013-01-01

    Molecular dynamics simulations have been used to systematically study the pressure evolution and bursting behavior of sub-surface helium bubbles and the resulting tungsten surface morphology. This study specifically investigates how bubble shape and size, temperature, tungsten surface orientation, and ligament thickness above the bubble influence bubble stability and surface evolution. The tungsten surface is roughened by a combination of adatom “islands,” craters, and pinholes. The present study provides insight into the mechanisms and conditions leading to various tungsten topology changes, which we believe are the initial stages of surface evolution leading to the formation of nanoscale fuzz

  16. Achievement report for fiscal 1984 on Sunshine Program. Research on liquefaction characteristics different between coal types and on technical physical properties; 1984 nendo tanshu ni yoru ekika tokusei to kogakuteki busseichi ni kansuru kenkyu seika hokokusho

    NONE

    1985-03-01

    Liquefaction characteristics of coal specimens, collected from many locations across the world, are determined so as to make clear the correlations between coal type and liquefaction reactivity. Conducted for this purpose are the analysis of chemical structures of the specimens, liquefaction tests in an autoclave using various catalysts and medium oils, liquefaction tests in a 0.1t/d bench plant, investigation of the constituents of the generated oil and their separation, and the secondary stabilization treatment for the commercialization of the product. The reaction tower is kept under constant conditions, the state of the liquid mixture in the reaction tower is evaluated by tracking the flow of coal out of the reaction tower after switchover from anthracene oil to coal paste, the gas flow in the reaction tower is estimated by tracking time-wise changes in the concentration level of inert gas at the reaction tower outlet port, the inert gas having been injected in pulses into the reaction system operating under the reaction conditions. For the implementation of the above-mentioned steps, a system is designed and constructed for directly collecting samples from the vapor phase section in the reaction tower operating under given reaction conditions (temperature: 400-450 degrees C, pressure 150-300kg/cm{sup 2}), and experiments are conducted to collect gas/liquid equilibrium data in the reaction tower under the given reaction conditions. (NEDO)

  17. Report on the Sunshine Project in fiscal 1990. Studies on liquefaction characteristics by coal types and on engineering properties; 1990 nendo tanshu ni yoru ekika tokusei to kogakuteki busseichi ni kansuru kenkyu hokokusho

    NONE

    1990-07-01

    This paper describes the achievements at the Government Industrial Development Laboratory, Hokkaido in the Sunshine Project in fiscal 1990. Surveys were carried on different catalytic activities for co-liquefaction of various types of coals. The Ru system was found preferable in acquiring fatty family products of low boiling points. Reactions of co-liquefaction constituents do not progress independently, but have positive interaction. Adding Ru is effective in accelerating hydrogenation of condensed aromatic rings and hydrogenation of cleaving nucleus, but in view of the hydrogenating decomposition capability, the Mo-system may be better. In a liquefaction plant test, diesel oil was manufactured by reforming and improving the Yallourn coal light oil. However, the oxygen content was too high, aggravating the temperature distribution control in catalyst bed, and not having achieved the intended denitrification rate. Discussions were given on co-liquefaction of the depressurization residues of Cold Lake (CLVB[vacuum bottom])/Athabasca (ATVB) and Battle River coal. The CLCVB and ATVB were turned into lower molecules easily through hydrogenation treatment. The reaction characteristics reflected the characteristics of medium oil. Depolymerization of coal has progressed faster in ATVB. In the study on the engineering property values, discussions were given on behavior of solid particles in a bubble column, and gas hold-up of slurry. (NEDO)

  18. Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

    Hoffman, G.P. [ed.

    1994-07-01

    This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

  19. Experimental validation of a mathematical model for seabed liquefaction in waves

    Sumer, B. Mutlu; Kirca, Özgür; Fredsøe, Jørgen

    2011-01-01

    This paper summarizes the results of an experimental study directed towards the validation of a mathematical model for the buildup of pore water pressure and resulting liquefaction of marine soils under progressive waves. Experiments were conducted under controlled conditions with silt ( d50 = 0.......070 mm) in a wave flume with a soil pit. Waves with wave heights in the range 7.7-18 cm with the water depth 55 cm and the wave period 1.6 s enabled us to study both the liquefaction and no-liquefaction regime pore water pressure buildup. The experimental data was used to validate the model. A numerical...

  20. Spectroscopy of antiproton helium atoms

    Hayano, Ryugo

    2005-01-01

    Antiproton helium atom is three-body system consisting of an antiproton, electrons and a helium nucleus (denoted by the chemical symbol, p-bar H + ). The authors produced abundant atoms of p-bar 4 He + , and p-bar 3 He + in a cooled He gas target chamber stopping the p-bar beam decelerated to approximately 100 keV in the Antiproton Decelerator at CERN. A precision laser spectroscopy on the atomic transitions in the p-bar 4 He + , and in p-bar 3 He + was performed. Principle of laser spectroscopy and various modifications of the system to eliminate factors affecting the accuracy of the experiment were described. Deduced mass ratio of antiproton and proton, (|m p -bar - m p |)/m p reached to the accuracy of 10 ppb (10 -8 ) as of 2002, as adopted in the recent article of the Particle Data Group by P.J. Mohr and B.N. Taylor. This value is the highest precise data for the CPT invariance in baryon. In future, antihydrogen atoms will be produced in the same facility, and will provide far accurate value of antiproton mass thus enabling a better confirmation of CPT theorem in baryon. (T. Tamura)

  1. Strange matter and Big Bang helium synthesis

    Madsen, J.; Riisager, K.

    1985-01-01

    Stable strange quark matter produced in the QCD phase transition in the early universe will trap neutrons and repel protons, thus reducing primordial helium production, Ysub(p). For reasonable values of Ysub(p), the radius of strange droplets must exceed 10 -6 cm if strange matter shall solve the dark-matter problem without spoiling Big Bang helium synthesis. (orig.)

  2. Post-giant evolution of helium stars

    Schoenberner, D.

    1977-01-01

    Extremely hydrogen deficient stars (helium stars and R Coronae Borealis variables) are considered to be remnants of double shell source stars (of the asymptotic giant branch). The evolution of stars with a condensed C/O-core and a helium envelope is followed numerically from the red giant stage to the white dwarf domain, crossing the regions of R CrB- and helium stars (so far analyzed). They have typically masses M/M(sun) = 0.7 and luminosities log L/L(sun) = 4.1. The time for crossing the helium star domain is some 10 3 years. The corresponding times in the R CrB-region amounts up to several 10 4 years. The lower limit of the death rate of helium stars is estimated to be 4 x 10 -14 pc -3 yr -1 . This value is only a factor of ten lower than the birth rate of all non-DA white dwarfs. It is therefore possible that the helium stars are the precursors of helium rich white dwarfs. As a consequence, a significant fraction of all stars which end their lives as white dwarfs should pass through the helium star phase. (orig.) [de

  3. Organ protection by the noble gas helium

    Smit, K.F.

    2017-01-01

    The aims of this thesis were to investigate whether helium induces preconditioning in humans, and to elucidate the mechanisms behind this possible protection. First, we collected data regarding organ protective effects of noble gases in general, and of helium in particular (chapters 1-3). In chapter

  4. Radioactive ions and atoms in superfluid helium

    Dendooven, P.G.; Purushothaman, S.; Gloos, K.; Aysto, J.; Takahashi, N.; Huang, W.; Harissopulos, S; Demetriou, P; Julin, R

    2006-01-01

    We are investigating the use of superfluid helium as a medium to handle and manipulate radioactive ions and atoms. Preliminary results on the extraction of positive ions from superfluid helium at temperatures close to 1 K are described. Increasing the electric field up to 1.2 kV/cm did not improve

  5. Modeling Secondary Neutral Helium in the Heliosphere

    Müller, Hans-Reinhard; Möbius, Eberhard; Wood, Brian E.

    2016-01-01

    An accurate, analytic heliospheric neutral test-particle code for helium atoms from the interstellar medium (ISM) is coupled to global heliospheric models dominated by hydrogen and protons from the solar wind and the ISM. This coupling enables the forward-calculation of secondary helium neutrals from first principles. Secondaries are produced predominantly in the outer heliosheath, upwind of the heliopause, by charge exchange of helium ions with neutral atoms. The forward model integrates the secondary production terms along neutral trajectories and calculates the combined neutral helium phase space density in the innermost heliosphere where it can be related to in-situ observations. The phase space density of the secondary component is lower than that of primary neutral helium, but its presence can change the analysis of primaries and the ISM, and can yield valuable insight into the characteristics of the plasma in the outer heliosheath. (paper)

  6. Exotic helium molecules; Molecules exotiques d'helium

    Portier, M

    2007-12-15

    We study the photo-association of an ultracold cloud of magnetically trapped helium atoms: pairs of colliding atoms interact with one or two laser fields to produce a purely long range {sup 4}He{sub 2}(2{sup 3}S{sub 1}-2{sup 3}P{sub 0}) molecule, or a {sup 4}He{sub 2}(2{sup 3}S{sub 1}-2{sup 3}S{sub 1}) long range molecule. Light shifts in one photon photo-association spectra are measured and studied as a function of the laser polarization and intensity, and the vibrational state of the excited molecule. They result from the light-induced coupling between the excited molecule, and bound and scattering states of the interaction between two metastable atoms. Their analysis leads to the determination of the scattering length a = (7.2 {+-} 0.6) ruling collisions between spin polarized atoms. The two photon photo-association spectra show evidence of the production of polarized, long-range {sup 4}He{sub 2}(2{sup 3}S{sub 1}-2{sup 3}S{sub 1}) molecules. They are said to be exotic as they are made of two metastable atoms, each one carrying a enough energy to ionize the other. The corresponding lineshapes are calculated and decomposed in sums and products of Breit-Wigner and Fano profiles associated to one and two photon processes. The experimental spectra are fit, and an intrinsic lifetime {tau} = (1.4 {+-} 0.3) {mu}s is deduced. It is checked whether this lifetime could be limited by spin-dipole induced Penning autoionization. This interpretation requires that there is a quasi-bound state close to the dissociation threshold in the singlet interaction potential between metastable helium atoms for the theory to match the experiment. (author)

  7. Exotic helium molecules; Molecules exotiques d'helium

    Portier, M

    2007-12-15

    We study the photo-association of an ultracold cloud of magnetically trapped helium atoms: pairs of colliding atoms interact with one or two laser fields to produce a purely long range {sup 4}He{sub 2}(2{sup 3}S{sub 1}-2{sup 3}P{sub 0}) molecule, or a {sup 4}He{sub 2}(2{sup 3}S{sub 1}-2{sup 3}S{sub 1}) long range molecule. Light shifts in one photon photo-association spectra are measured and studied as a function of the laser polarization and intensity, and the vibrational state of the excited molecule. They result from the light-induced coupling between the excited molecule, and bound and scattering states of the interaction between two metastable atoms. Their analysis leads to the determination of the scattering length a = (7.2 {+-} 0.6) ruling collisions between spin polarized atoms. The two photon photo-association spectra show evidence of the production of polarized, long-range {sup 4}He{sub 2}(2{sup 3}S{sub 1}-2{sup 3}S{sub 1}) molecules. They are said to be exotic as they are made of two metastable atoms, each one carrying a enough energy to ionize the other. The corresponding lineshapes are calculated and decomposed in sums and products of Breit-Wigner and Fano profiles associated to one and two photon processes. The experimental spectra are fit, and an intrinsic lifetime {tau} = (1.4 {+-} 0.3) {mu}s is deduced. It is checked whether this lifetime could be limited by spin-dipole induced Penning autoionization. This interpretation requires that there is a quasi-bound state close to the dissociation threshold in the singlet interaction potential between metastable helium atoms for the theory to match the experiment. (author)

  8. Coal liquefaction: A research and development needs assessment: Final report, Volume II

    Schindler, H.D.; Burke, F.P.; Chao, K.C.; Davis, B.H.; Gorbaty, M.L.; Klier, K.; Kruse, C.W.; Larsen, J.W.; Lumpkin, R.E.; McIlwain, M.E.; Wender, I.; Stewart, N.

    1989-03-01

    Volume II of this report on an assessment of research needs for coal liquefaction contains reviews of the five liquefaction technologies---direct, indirect, pyrolysis, coprocessing, and bioconversion. These reviews are not meant to be encyclopedic; several outstanding reviews of liquefaction have appeared in recent years and the reader is referred to these whenever applicable. Instead, these chapters contain reviews of selected topics that serve to support the panel's recommendations or to illustrate recent accomplishments, work in progress, or areas of major research interest. At the beginning of each of these chapters is a brief introduction and a summary of the most important research recommendations brought out during the panel discussions and supported by the material presented in the review. A review of liquefaction developments outside the US is included. 594 refs., 100 figs., 60 tabs.

  9. Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

    Wiser, W. H.

    1980-09-01

    Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

  10. Subtask 3.3 - Feasibility of Direct Coal Liquefaction in the Modern Economic Climate

    Benjamin Oster; Joshua Strege; Marc Kurz; Anthony Snyder; Melanie Jensen

    2009-06-15

    Coal liquefaction provides an alternative to petroleum for the production of liquid hydrocarbon-based fuels. There are two main processes to liquefy coal: direct coal liquefaction (DCL) and indirect coal liquefaction (ICL). Because ICL has been demonstrated to a greater extent than DCL, ICL may be viewed as the lower-risk option when it comes to building a coal liquefaction facility. However, a closer look, based on conversion efficiencies and economics, is necessary to determine the optimal technology. This report summarizes historical DCL efforts in the United States, describes the technical challenges facing DCL, overviews Shenhua's current DCL project in China, provides a DCL conceptual cost estimate based on a literature review, and compares the carbon dioxide emissions from a DCL facility to those from an ICL facility.

  11. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, January--March 1992

    1992-04-01

    In the Advance Coal Liquefaction Concept Proposal (ACLCP) carbon monoxide (CO) and water have been proposed as the primary reagents in the pretreatment process. The main objective of this project is to develop a methodology for pretreating coal under mild conditions based on a combination of existing processes which have shown great promise in liquefaction, extraction and pyrolysis studies. The aim of this pretreatment process is to partially depolymerise the coal, eliminate oxygen and diminish the propensity for retograde reactions during subsequent liquefaction. The desirable outcome of the CO pretreatment step should be: (1) enhanced liquefaction activity and/or selectivity toward products of higher quality due to chemical modification of the coal structure; (2) cleaner downstream products; (3) overall improvement in operability and process economics.

  12. Report on results for fiscal 1997 on development of coal liquefaction technology . Development of liquefaction base technology (studies on development and internationalization of environmentally benign coal liquefaction technology); 1997 nendo sekitan ekika gijutsu seika hokokusho. Ekika kiban gijutsu no kaihatsu (kankyo chowagata sekitan ekika gijutsu no kaihatsu oyobi kokusaika kenkyu)

    NONE

    1998-03-01

    The research objective is the development of environmentally benign coal liquefaction technology and the studies on internationalization of coal liquefaction technology. Implemented for the former are (1) research on improvement and rationalization of liquefaction process and (2) research on advancement of liquefaction base technology. In (1), studies were made on in-oil preprocessing technology and scale suppressing measures for the purpose of obtaining reform/high grade of coal, and on improvement of liquefied oil collecting ratio, sophistication of coal slurry and attainment of light oil/high grade from liquefied crude oil for the purpose of optimizing liquefaction reactive conditions and improving a solvent. In (2), in developing high activity/high dispersion type new catalysts, catalytic sufurization behavior and activity manifestation mechanism were explored, as were iron hydroxide based iron ore properties and liquefaction reactive characteristics. The initial reactive characteristics of liquefaction for example were investigated for the purpose of collecting basic data for expanding kinds of coal. In order to attain the latter objective of the research, a feasibility study of liquefaction location was conducted, as were the investigation including sampling of iron ore for catalytic material and the investigation of coal gasification technology. After the completion of the Australian brown coal liquefaction project, the development of the coal liquefaction technology commenced in fiscal 1994 produced a number of useful records and ended in 1997. (NEDO)

  13. Determination of helium in beryl minerals

    Souza Barcellos, E. de.

    1985-08-01

    In order to obtain the diffusion coefficients of helium in beryl and phenacite samples at various temperatures, helium leak rates were measured in these minerals at these temperatures. Mass spectrometry (MS) was used to obtain helium leak rates and the gas flow was plotted against time. The gas quantity determined by MS was first obtained at various temperatures until no helium leak rate was detected. After that, these samples were irradiated with fast neutrons to produce helium which was measured again. This procedure was used to estimate the experimental error. The quantity of helium produced by interaction of gamma radiation with beryl minerals was theoretically calculated from the amount of thorium-232 at the neighbourhood of the samples. The quantity of helium produced in the minerals due to uranium and thorium decay was calculated using the amount of these heavy elements, and the results were compared with the amounts determined by MS. The amount of potassium-40 was determined in order to derive the quantity of argonium-40, since some workers found argonium in excess in these minerals. The quantity of helium in the beryl samples (s) was determined in the center and in the surface of the samples in order to obtain informations about the effectiveness of the Be(α, η) He reaction. Beryl and phenacite minerals were choosen in this research since they are opposite each other with respect to the helium contents. Both have beryllium in their compositon but beryl hold a large amount of helium while phenacite, in spite of having about three times more beryllium than beryl, do not hold the gas. (author) [pt

  14. Pressure swing adsorption cycle for natural gas pretreatment for liquefaction

    Mann, R.E.

    1984-01-10

    An improved apparatus and method for a regeneration of a solid adsorbent used to pretreat a gas before liquefaction. The spent adsorbent is subjected to a two-step regenerative process, in the first of which the adsorbent is subjected to a low pressure produced by the use of mechanical vacuum pumps. When the pressure of the atmosphere in contact with the adsorbent has been reduced to a level sufficiently low to insure that the gas will flow under laminar rather than viscous conditions, the adsorbent is exposed to the action of a cryoplate condenser maintained at a sufficiently low temperature to cause any molecules of water which impinge thereon to condense and freeze, thereby reducing the partial pressure of water vapor within the chamber. The reduced partial pressure of the water vapor in turn causes adsorbed water on the adsorbent to be desorbed, thereby effectively removing the water from the adsorbent and depositing it as solid ice on the cryoplate condenser.

  15. Experimental Study of Subcritical Water Liquefaction of Biomass

    Zhu, Zhe; Toor, Saqib; Rosendahl, Lasse

    2014-01-01

    In this work, hydrothermal liquefaction (HTL) of wood industry residues (wood, bark, sawdust) and macroalgae for producing biofuels has been investigated under subcritical water conditions (at temperature of 300 C), with and without the presence of catalyst. The effects of catalyst and biomass type...... bio-crudes were analyzed. The results showed that the higher heating values (HHVs) were in the range of 24.15 to 31.79 MJ/kg, and they were enhanced in the presence of catalyst, except for that of the macroalgae. The solid residues were characterized by heating value, SEM and FTIR. It was found...... that the addition of K2CO3 lowered the solids quality in terms of the heating values, while it did not have apparent effect on the functional groups of solid residues. SEM analysis of the raw biomass and solid residues revealed that the char formation for wood, sawdust and macroalgae had initially finished when...

  16. Characterization of solid residues from coal liquefaction processes. Phase I

    Potter, J.; McDougall, W.M.; Kybett, B.D.; Neufeld, C.

    1981-01-01

    Various coal liquefaction and beneficiation processes are being investigated by independent research groups sponsored by the Canadian Federal Government. These processes include the co-processing of heavy oils and bitumen with coal, oxygen removal and hydrogenation of coal and supercritical gas extraction of coal. The end products, gaseous and liquid fuels and insoluble organic residues, vary with the experimental conditions. The physical properties and origin of the insoluble residue may influence such factors as degree of conversion, efficiency of the process, and ultimately, gaseous and liquid yields. One of the most suitable methods of assessing the nature of the insoluble residues is the use of petrography. This report deals with petrographic assessment of the coals and residues from various coal conversion processes; attempts were made to characterize the solid phases in the residues; to assess them in a quantitative manner and where possible; to correlate the results with experimental data; and to assess their effects on conversion. (30 refs.)

  17. Zeolites as Catalysts for Fuels Refining after Indirect Liquefaction Processes

    Arno de Klerk

    2018-01-01

    Full Text Available The use of zeolite catalysts for the refining of products from methanol synthesis and Fisher–Tropsch synthesis was reviewed. The focus was on fuels refining processes and differences in the application to indirect liquefaction products was compared to petroleum, which is often a case of managing different molecules. Processes covered were skeletal isomerisation of n-butenes, hydroisomerisation of n-butane, aliphatic alkylation, alkene oligomerisation, methanol to hydrocarbons, ethanol and heavier alcohols to hydrocarbons, carbonyls to hydrocarbons, etherification of alkenes with alcohols, light naphtha hydroisomerisation, catalytic naphtha reforming, hydroisomerisation of distillate, hydrocracking and fluid catalytic cracking. The zeolite types that are already industrially used were pointed out, as well as zeolite types that have future promise for specific conversion processes.

  18. GIS-based soil liquefaction susceptibility map of Mumbai city for earthquake events

    Mhaske, Sumedh Yamaji; Choudhury, Deepankar

    2010-03-01

    The problem of liquefaction of soil during seismic event is one of the important topics in the field of Geotechnical Earthquake Engineering. Liquefaction of soil is generally occurs in loose cohesionless saturated soil when pore water pressure increases suddenly due to induced ground motion and shear strength of soil decreases to zero and leading the structure situated above to undergo a large settlement, or failure. The failures took place due to liquefaction induced soil movement spread over few square km area continuously. Hence this is a problem where spatial variation involves and to represent this spatial variation Geographic Information System (GIS) is very useful in decision making about the area subjected to liquefaction. In this paper, GIS software GRAM++ is used to prepare soil liquefaction susceptibility map for entire Mumbai city in India by marking three zones viz. critically liquefiable soil, moderately liquefiable soil and non liquefiable soil. Extensive field borehole test data for groundwater depth, standard penetration test (SPT) blow counts, dry density, wet density and specific gravity, etc. have been collected from different parts of Mumbai. Simplified procedure of Youd et al. (2001) is used for calculation of factor of safety against soil liquefaction potential. Mumbai city and suburban area are formed by reclaiming lands around seven islands since 1865 till current date and still it is progressing in the area such as Navi Mumbai and beyond Borivali to Mira road suburban area. The factors of safety against soil liquefaction were determined for earthquake moment magnitude ranging from Mw = 5.0 to 7.5. It is found that the areas like Borivali, Malad, Dahisar, Bhandup may prone to liquefaction for earthquake moment magnitude ranging from Mw = 5.0 to 7.5. The liquefaction susceptibility maps were created by using GRAM++ by showing the areas where the factor of safety against the soil liquefaction is less than one. Proposed liquefaction

  19. Microbial liquefaction of peat for the production of synthetic fuels

    Gunasekaran, M.

    1988-01-01

    Objectives of this study were: to evaluate the potential of using various microorganisms to hydrolyse and liquify peat; to determine the optimal conditions for peat hydrolysis and liquefaction; to study the co-metabolizable substances; to separate the compounds present in liquified peat by alumina and silica acid chromatography and capillary gas chromatography; and to identify the compounds in liquified peat by capillary GC-Mass spectrometry. Organisms used in the study include: Coprinus comatus, Coriolus hirsutus, Ganoderma lucidum, Lentinus edodes, Lenzites trabea, Phanerochaete chrysosporium, Pleurotus ostreatus, P. sapidus, Polyporus adjustus, Neurospora sitophila, Rhizophus arrhizus, Bacillus subtilis, Acinetobacter sp. and Alcaligenes sp. The fungi were maintained and cultivated in potato dextrose agar at 30 C. The bacteria were maintained in nutrient agar at 30 C. We have also initiated work on coal solubilization in addition to the studies on peat liquefaction. A relatively new substratum or semi-solid base for culture media called Pluronic F-127, or Polyol (BASF, New Jersey). Objectives of this study were: (1) to study the growth patterns of Candida ML 13 on pluronic as substratum; (2) to determine the rate of microbial coal solubilization on pluronic F-127 amended in different growth media; (3) to separate the mycelial mat of Candida ML 13 from unsolubilized coal particles and solubilized coal products from pluronic F-127; (4) to determine the effects of pH on microbial coal solubilization in pluronic F-127 media; (5) the effect of concentration of pluronic F-127 in media on coal solubilization; and, (6) to study the role of extracellular factors secreted by Candida ML 13 on coal solubilization in pluronic F-127 media. Results are discussed. 4 refs.

  20. The multipurpose helium refrigerators/liquefiers for the new CERN experimental area

    Eber, N; Kurtcuoglu, K; Senn, A

    1979-01-01

    The helium plants described have a nominal capacity of 100 liters/hour or 400 Watts at 4.4K and can also be operated in mixed duty over the whole performance range. The plants feature oilfree labyrinth-piston compressors and turboexpanders with self-supporting gas bearings plus magnetic auxiliary bearings. The greatest peculiarity of the new plants is the first time combined use of cold and warm ejectors. (1 refs).

  1. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1991

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  2. Review and experimental study on pyrolysis and hydrothermal liquefaction of microalgae for biofuel production

    Chiaramonti, David; Prussi, Matteo; Buffi, Marco; Rizzo, Andrea Maria; Pari, Luigi

    2017-01-01

    Highlights: • A review of microalgae thermochemical conversion to bioliquids was carried out. • We focused on pyrolysis and hydrothermal liquefaction for biocrude/biofuels. • Original experimental research on microalgae pyrolysis was also carried out. • Starvation does not impact significant on the energy content of the biocrude. • This result is relevant for designing full scale microalgae production plants. - Abstract: Advanced Biofuels steadily developed during recent year, with several highly innovative processes and technologies explored at various scales: among these, lignocellulosic ethanol and CTO (Crude Tall Oil)-biofuel technologies already achieved early-commercial status, while hydrotreating of vegetable oils is today fully commercial, with almost 3.5 Mt/y installed capacity worldwide. In this context, microalgae grown in salt-water and arid areas represent a promising sustainable chain for advanced biofuel production but, at the same time, they also represent a considerable challenge. Processing microalgae in an economic way into a viable and sustainable liquid biofuel (a low-cost mass-product) is not trivial. So far, the most studied microalgae-based biofuel chain is composed by microorganism cultivation, lipid accumulation, oil extraction, co-product valorization, and algae oil conversion through conventional esterification into Fatty Acids Methyl Esters (FAME), i.e. Biodiesel, or Hydrotreated Esters and Fatty Acids (HEFA), the latter representing a very high quality drop-in biofuel (suitable either for road transport or for aviation). However, extracting the algae oil at low cost and industrial scale is not yet a mature process, and there is not yet industrial production of algae-biofuel from these two lipid-based chains. Another option can however be considered: processing the algae through dedicated thermochemical reactors into advanced biofuels, thus approaching the downstream processing of algae in a completely different way than

  3. Life cycle assessment of bio-jet fuel from hydrothermal liquefaction of microalgae

    Fortier, Marie-Odile P.; Roberts, Griffin W.; Stagg-Williams, Susan M.; Sturm, Belinda S.M.

    2014-01-01

    Highlights: • A life cycle assessment of bio-jet fuel from wastewater algae was performed. • We used experimental data from algae cultivation through hydrothermal liquefaction. • We performed Monte Carlo and sensitivity analyses with ranges of parameter values. • Transport of moderately dewatered algae increased life cycle climate change impacts. • Collocation and heat integration reduce life cycle greenhouse gas emissions by 76%. - Abstract: Bio-jet fuel is increasingly being produced from feedstocks such as algae and tested in flight. As the industry adopts bio-jet fuels from various feedstocks and conversion processes, life cycle assessment (LCA) is necessary to determine whether these renewable fuels result in lower life cycle greenhouse gas (LC-GHG) emissions than conventional jet fuel. An LCA was performed for a functional unit of 1 GJ of bio-jet fuel produced through thermochemical conversion (hydrothermal liquefaction (HTL)) of microalgae cultivated in wastewater effluent. Two pathways were analyzed to compare the impacts of siting HTL at a wastewater treatment plant (WWTP) to those of siting HTL at a refinery. Base cases for each pathway were developed in part using primary data from algae production in wastewater effluent and HTL experiments of this algae at the University of Kansas. The LC-GHG emissions of these cases were compared to those of conventional jet fuel, and a sensitivity analysis and Monte Carlo analyses were performed. When algal conversion using HTL was modeled at a refinery versus at the WWTP site, the transportation steps of biomass and waste nutrients were major contributors to the LC-GHG emissions of algal bio-jet fuel. The LC-GHG emissions were lower for the algal bio-jet fuel pathway that performs HTL at a WWTP (35.2 kg CO 2eq /GJ for the base case) than for the pathway for HTL at a refinery (86.5 kg CO 2eq /GJ for the base case). The LCA results were particularly sensitive to the extent of heat integration, the source of

  4. The helium effect at grain boundaries in Fe-Cr alloys: A first-principles study

    Zemła, M.R., E-mail: marcin.zemla@wimpw.edu.pl [Faculty of Materials Science and Engineering, Warsaw University of Technology, Wołoska 141, 02-507 Warsaw (Poland); Wróbel, J.S.; Wejrzanowski, T. [Faculty of Materials Science and Engineering, Warsaw University of Technology, Wołoska 141, 02-507 Warsaw (Poland); Nguyen-Manh, D. [CCFE, Culham Science Centre, Abingdon, Oxon OX14 3DB (United Kingdom); Kurzydłowski, K.J. [Faculty of Materials Science and Engineering, Warsaw University of Technology, Wołoska 141, 02-507 Warsaw (Poland)

    2017-02-15

    Helium is produced in the structural materials in nuclear power plants by nuclear transmutation following neutron irradiation. Since the solubility of helium in all metals is extremely low, helium tends to be trapped at defects such as vacancies, dislocations and grain boundaries, which cause material embrittlement. Density functional theory (DFT) calculations were performed in order to investigate the helium effect at grain boundaries (GBs) in iron-chromium alloys. Both cohesive energy and magnetic properties at symmetric Σ3(1 1 1) and Σ5(2 1 0) tilt Fe GBs are studied in the presence of Cr and He atoms. It is found that the presence of Cr atoms increases cohesive energy, at different He concentrations, and strongly influences magnetic properties at the GBs. The effect of the segregation energy of helium atom as a function of the different positions of Cr atoms located inside/outside a GB has been considered. Results of the present first-principles study enable one to clarify the role of Cr in understanding the helium effect in Fe-Cr-based alloys.

  5. Continuous high-solids corn liquefaction and fermentation with stripping of ethanol.

    Taylor, Frank; Marquez, Marco A; Johnston, David B; Goldberg, Neil M; Hicks, Kevin B

    2010-06-01

    Removal of ethanol from the fermentor during fermentation can increase productivity and reduce the costs for dewatering the product and coproduct. One approach is to recycle the fermentor contents through a stripping column, where a non-condensable gas removes ethanol to a condenser. Previous research showed that this approach is feasible. Savings of $0.03 per gallon were predicted at 34% corn dry solids. Greater savings were predicted at higher concentration. Now the feasibility has been demonstrated at over 40% corn dry solids, using a continuous corn liquefaction system. A pilot plant, that continuously fed corn meal at more than one bushel (25 kg) per day, was operated for 60 consecutive days, continuously converting 95% of starch and producing 88% of the maximum theoretical yield of ethanol. A computer simulation was used to analyze the results. The fermentation and stripping systems were not significantly affected when the CO(2) stripping gas was partially replaced by nitrogen or air, potentially lowering costs associated with the gas recycle loop. It was concluded that previous estimates of potential cost savings are still valid. (c) 2010. Published by Elsevier Ltd. All rights reserved.

  6. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  7. Commercial helium reserves, continental rifting and volcanism

    Ballentine, C. J.; Barry, P. H.; Hillegonds, D.; Fontijn, K.; Bluett, J.; Abraham-James, T.; Danabalan, D.; Gluyas, J.; Brennwald, M. S.; Pluess, B.; Seneshens, D.; Sherwood Lollar, B.

    2017-12-01

    Helium has many industrial applications, but notably provides the unique cooling medium for superconducting magnets in medical MRI scanners and high energy beam lines. In 2013 the global supply chainfailed to meet demand causing significant concern - the `Liquid Helium Crisis' [1]. The 2017 closure of Quatar borders, a major helium supplier, is likely to further disrupt helium supply, and accentuates the urgent need to diversify supply. Helium is found in very few natural gas reservoirs that have focused 4He produced by the dispersed decay (a-particle) of U and Th in the crust. We show here, using the example of the Rukwa section of the Tanzanian East African Rift, how continental rifting and local volcanism provides the combination of processes required to generate helium reserves. The ancient continental crust provides the source of 4He. Rifting and associated magmatism provides the tectonic and thermal mechanism to mobilise deep fluid circulation, focusing flow to the near surface along major basement faults. Helium-rich springs in the Tanzanian Great Rift Valley were first identified in the 1950's[2]. The isotopic compositions and major element chemistry of the gases from springs and seeps are consistent with their release from the crystalline basement during rifting [3]. Within the Rukwa Rift Valley, helium seeps occur in the vicinity of trapping structures that have the potential to store significant reserves of helium [3]. Soil gas surveys over 6 prospective trapping structures (1m depth, n=1486) show helium anomalies in 5 out of the 6 at levels similar to those observed over a known helium-rich gas reservoir at 1200m depth (7% He - Harley Dome, Utah). Detailed macroseep gas compositions collected over two days (n=17) at one site allows us to distinguish shallow gas contributions and shows the deep gas to contain between 8-10% helium, significantly increasing resource estimates based on uncorrected values (1.8-4.2%)[2,3]. The remainder of the deep gas is

  8. Report on the achievements in the Sunshine Project in fiscal 1988. Development of a collection and processing system for data of the coal liquefaction process; 1988 nendo sekitan ekika process nado no data no shushu, shori system nado no kaihatsu seika hokokusho

    NONE

    1989-03-01

    Storing and managing comprehensively a huge amount of data acquired in developing the coal liquefaction technologies would greatly contribute to moving forward the development of the coal liquefaction technologies, and realizing a commercial plant being the ultimate goal. It is intended to investigate the current status of information management systems used for development projects being implemented or planned in developing the coal liquefaction technologies. It is also intended to structure a coal liquefaction database system to utilize comprehensively and effective the information discovered by the above investigation. The current fiscal year has performed developments on the following items to structure a coal liquefaction database system by using a computer: (1) conceptual design of the fundamental database, and (2) basic design on a general technological information retrieval system. The development during the current fiscal year established a method to classify levels of data accommodation for the fundamental database based on the investigation and analysis of the experimental data. In addition, with regard to the general technological information retrieval system, summarization was performed on the specifications of the hardware and software, the basic configuration, the input and output specifications, and the retrieval screens. (NEDO)

  9. Thermal properties of biopolyol from oil palm fruit fibre (OPFF) using solvolysis liquefaction technique

    Kormin, Shaharuddin; Rus, Anika Zafiah M.; Azahari, M. Shafiq M.

    2017-09-01

    Liquefaction is known to be an effective method for converting biomass into a biopolyol. The biomass liquefaction of oil palm fruit waste (PFW) in the presence of liquefaction solvent/polyhydric alcohol (PA): polyethylene glycol 400 (PEG400) using sulfuric acid as catalyst was studied. For all experiments, the liquefaction was conducted at 150°C and atmospheric pressure. The mass ratio of OPFW to liquefaction solvents used in all the experiments was, 1/3. Thermogravimetric analyses (TGA) were used to analyze their biopolyol and residue behaviors. It was found that thermal stability of oil palm mesocarp fibre (PM), oil palm shell (PS) and oil palm kernel (PK) fibre exhibited the first degradation of hard segment at (232, 104, 230°C) and the second degradation of soft segment at (314, 226, 412°C) as compared to PM, PS and PK residue which (229, 102, 227°C) of hard segment and (310, 219, 299°C) of segment, respectively. This behavior of thermal degradation of the hard segment and soft segment of biopolyol was changes after undergo solvolysis liquefaction process. The result analysis showed that the resulting biopolyol and its residue was suitable monomer for polyurethane (PU) synthesis for the production of PU foams.

  10. Prediction of strain energy-based liquefaction resistance of sand-silt mixtures: An evolutionary approach

    Baziar, Mohammad H.; Jafarian, Yaser; Shahnazari, Habib; Movahed, Vahid; Amin Tutunchian, Mohammad

    2011-11-01

    Liquefaction is a catastrophic type of ground failure, which usually occurs in loose saturated soil deposits under earthquake excitations. A new predictive model is presented in this study to estimate the amount of strain energy density, which is required for the liquefaction triggering of sand-silt mixtures. A wide-ranging database containing the results of cyclic tests on sand-silt mixtures was first gathered from previously published studies. Input variables of the model were chosen from the available understandings evolved from the previous studies on the strain energy-based liquefaction potential assessment. In order to avoid overtraining, two sets of validation data were employed and a particular monitoring was made on the behavior of the evolved models. Results of a comprehensive parametric study on the proposed model are in accord with the previously published experimental observations. Accordingly, the amount of strain energy required for liquefaction onset increases with increase in initial effective overburden pressure, relative density, and mean grain size. The effect of nonplastic fines on strain energy-based liquefaction resistance shows a more complicated behavior. Accordingly, liquefaction resistance increases with increase in fines up to about 10-15% and then starts to decline for a higher increase in fines content. Further verifications of the model were carried out using the valuable results of some downhole array data as well as centrifuge model tests. These verifications confirm that the proposed model, which was derived from laboratory data, can be successfully utilized under field conditions.

  11. Effect of pre-swelling of coal on its solvent extraction and liquefaction properties

    Hengfu Shui; Zhicai Wang; Meixia Cao [Anhui University of Technology, Ma' anshan (China). School of Chemistry and Chemical Engineering

    2008-10-15

    Effects of pre-swelling of coal on solvent extraction and liquefaction properties were studied with Shenhua coal. It was found that pre-swelling treatments of the coal in three solvents, i.e., toluene (TOL), N-methyl-2-pyrrolidinone (NMP) and tetralin (THN) increased its extraction yield and liquefaction conversion, and differed the liquefied product distributions. The pre-swollen coals after removing the swelling solvents showed increased conversion in liquefaction compared with that of the swollen coals in the presence of swelling solvents. It was also found that the yields of (oil + gas) in liquefaction of the pre-swollen coals with NMP and TOL dramatically decreased in the presence of swelling solvent. TG and FTIR analyses of the raw coal, the swollen coals and the liquefied products were carried out in order to investigate the mechanism governing the effects of pre-swelling treatment on coal extraction and liquefaction. The results showed that the swelling pre-treatment could disrupt some non-covalent interactions of the coal molecules, relax its network structure and loosened the coal structure. It would thus benefit diffusion of a hydrogen donor solvent into the coal structure during liquefaction, and also enhance the hydrogen donating ability of the hydrogen-rich species derived from the coal. 21 refs., 4 figs., 3 tabs.

  12. Preliminary study of soil liquefaction hazard at Terengganu shoreline, Peninsular Malaysia

    Hashim, H.; Suhatril, M.; Hashim, R.

    2017-06-01

    Terengganu is a shoreline state located in Peninsular Malaysia which is a growing hub for port industries and tourism centre. The northern part offers pristine settings of a relax beach areas whereas the southern part are observed to be a growing centre for development. The serious erosion on soil deposit along the beach line presents vulnerable soil condition to soil liquefaction consists of sandy with low plasticity and shallow ground water. Moreover, local earthquake from nearby fault have present significant tremors over the past few years which need to be considered in the land usage or future development in catering the seismic loading. Liquefaction analysis based on field standard penetration of soil is applied on 546 boreholes scattered along the shoreline areas ranging 244 km of shoreline stretch. Based on simplified approach, it is found that more than 70% of the studied areas pose high liquefaction potential since there are saturated loose sand and silt deposits layer ranges at depth 3 m and up to 20 m. The presence of clay deposits and hard stratum at the remaining 30% of the studied areas shows good resistance to soil liquefaction hence making the area less significant to liquefaction hazard. Result indicates that liquefaction improving technique is advisable in future development of shoreline areas of Terengganu state.

  13. Effect of Recycle Solvent Hydrotreatment on Oil Yield of Direct Coal Liquefaction

    Shansong Gao

    2015-07-01

    Full Text Available Effects of the recycle solvent hydrotreatment on oil yield of direct coal liquefaction were carried out in the 0.18 t/day direct coal liquefaction bench support unit of National Engineering Laboratory for Direct Coal Liquefaction (China. Results showed that the hydrogen-donating ability of the hydrogenated recycle solvent improved and the hydrogen consumption of solvent hydrotreatment was increased by decreasing liquid hourly space velocity (LHSV from 1.5 to 1.0 h−1 and increasing reaction pressure from 13.7 to 19.0 MPa. The hydrogen-donating ability of the hydrogenated recycle solvent was enhanced, thus promoting the oil yield and coal conversion of the liquefaction reaction. The coal conversion and distillates yield of coal liquefaction were increased from 88.74% to 88.82% and from 47.41% to 49.10%, respectively, with the increase in the solvent hydrotreatment pressure from 13.7 to 19.0 MPa. The coal conversion and distillates of coal liquefaction were increased from 88.82% to 89.27% and from 49.10% to 54.49%, respectively, when the LHSV decreased from 1.5 to 1.0 h−1 under the solvent hydrotreatment pressure of 19.0 MPa.

  14. A novel process for small-scale pipeline natural gas liquefaction

    He, T.B.; Ju, Y.L.

    2014-01-01

    Highlights: • A novel process was proposed to liquefy natural gas by utilizing the pressure exergy. • The process is zero energy consumption. • The maximum liquefaction rate of the process is 12.61%. • The maximum exergy utilization rate is 0.1961. • The economic analysis showed that the payback period of the process is quit short. - Abstract: A novel process for small-scale pipeline natural gas liquefaction is designed and presented. The novel process can utilize the pressure exergy of the pipeline to liquefy a part of natural gas without any energy consumption. The thermodynamic analysis including mass, energy balance and exergy analysis are adopted in this paper. The liquefaction rate and exergy utilization rate are chosen as the objective functions. Several key parameters are optimized to approach the maximum liquefaction rate and exergy utilization rate. The optimization results showed that the maximum liquefaction rate is 12.61% and the maximum exergy utilization rate is 0.1961. What is more, the economic performances of the process are also discussed and compared by using the maximum liquefaction rate and exergy utilization rate as indexes. In conclusion, the novel process is suitable for pressure exergy utilization due to its simplicity, zero energy consumption and short payback period

  15. Helium hammer in superfluid transfer

    Tward, E.; Mason, P. V.

    1984-01-01

    Large transient pressure pulses, referred to as a helium hammer, which occurred in the transfer line of the main cryogenic tank during the development tests of the Infrared Astronomical Satellite, launched on January 25, 1983, are analyzed, and the measures taken to prevent a failure described. The modifications include an installation of a 2.3-liter surge tank upstream, and a back-up relief valve downstream, of a burst disk. The surge tank is designed to attenuate a 0.33-MPa pressure pulse at the inlet down to 0.092 MPa at the outlet. A mechanism of the pulse generation is suggested, which involves flashing and rapid recondensation of the small amount of liquid entering the warm section of a transition to room temperature.

  16. Commissioning and operational results of helium refrigeration system at JLab for the 12GeV upgrade

    Knudsen, Peter N. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Ganni, Venkatarao [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Dixon, Kelly D. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Norton, Robert O. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Creel, Jonathan D. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States)

    2015-12-01

    The new 4.5 K refrigerator system at the Jefferson Lab (JLab) Central Helium Liquefier (CHL-2) for the 12 GeV upgrade was commissioned in late spring of 2013, following the commissioning of the new compressor system, and has been supporting 12 GeV LINAC commissioning since that time. Six design modes were tested during commissioning, consisting of a maximum capacity, nominal capacity, maximum liquefaction, maximum refrigeration, maximum fill and a stand-by/reduced load condition. The maximum capacity was designed to support a 238 g/s, 30 K and 1.16 bar cold compressor return flow, a 15 g/s, 4.5 K liquefaction load and a 12.6 kW, 35-55 K shield load. The other modes were selected to ensure proper component sizing and selection to allow the cold box to operate over a wide range of conditions and capacities. The cold box system is comprised of two physically independent cold boxes with interconnecting transfer-lines. The outside (upper) 300-60 K vertical cold box has no turbines and incorporates a liquid nitrogen pre-cooler and 80-K beds. The inside (lower) 60-4.5 K horizontal cold box houses seven turbines that are configured in four expansion stages including one Joule-Thompson expander and a 20-K bed. The helium compression system has five compressors to support three pressure levels in the cold box. This paper will summarize the analysis of the test data obtained over the wide range of operating conditions and capacities which were tested.

  17. Friendly fermions of helium-three

    Leggatt, T.

    1976-01-01

    The importance of helium in showing up the effects of atomic indistinguishability and as a material by which to test some of the most fundamental principles of quantum mechanics is discussed. Helium not only remains liquid down to zero temperature but of the two isotopes helium-three has intrinsic spin 1/2 and should therefore obey the Pauli principle, while helium-four has spin zero and is expected to undergo Bose condensation. Helium-three becomes superfluid at temperatures of a few thousandths of a degree above absolute zero by the bulk liquid collecting its atoms into spinning pairs. There are three different superfluid phases, now conveniently called A, B and A 1 and each is characterised by a different behaviour of the spin and/or relative angular motion of the atoms composing the Cooper pairs. Problems surrounding the complicated physical system of helium-three are discussed. It is suggested that the combined coherence and directionality of superfluid helium-three should create some fascinating physics. (U.K.)

  18. Seismological measurement of solar helium abundance

    Vorontsov, S.V.; Pamyatnykh, A.A.

    1991-01-01

    The internal structure and evolution of the Sun depends on its chemical composition, particularly the helium abundance. In addition, the helium abundance in the solar envelope is thought to represent the protosolar value, making it a datum of cosmological significance. Spectroscopic measurements of the helium abundance are uncertain, and the most reliable estimates until now have come from the calibration of solar evolutionary models. The frequencies of solar acoustic oscillations are sensitive, however, to the behaviour of the speed of sound in the Sun's helium ionization zone, which allows a helioseismological determination of the helium abundance. Sound-speed inversion of helioseismological data can be used for this purpose, but precise frequency measurements of high-degree oscillation modes are needed. Here we describe a new approach based on an analysis of the phase shift of acoustic waves of intermediate-degree modes. From the accurate intermediate-mode data now available, we obtain a helium mass fraction Y=0.25±0.01 in the solar convection zone, significantly smaller than the value Y=0.27-0.29 predicted by recent solar evolutionary models. The discrepancy indicates either that initial helium abundance was reduced in the envelope by downward diffusion or that the protosolar value was lower than currently accepted. (author)

  19. Report on the achievements in the Sunshine Project in fiscal 1986. Surveys on systems to structure a coal liquefaction database; 1986 nendo sekitan ekika database kochiku no tame no system chosa seika hokokusho

    NONE

    1987-03-01

    Surveys are carried out on the current status of information control systems for development projects being performed or planned in developing coal liquefaction technologies. The conception for structuring a coal liquefaction database (CLDB) is made clear to manage comprehensively and utilize effectively the information in the systems. Section 3 investigated and analyzed the current status of data processing for experimental plants. The data for each experimental plant are processed individually. Therefore, it is preferable that the CLDB shall be provided with accommodating locations to receive respective data. Section 4 put into order the flows of operation and information in the coal liquefaction research, and depicted an overall configuration diagram for the system. Section 5 discusses problems in structuring this system. There is a large number of problems to be discussed from now on, not only in the technological aspect, but in analyzing the organizational roles of NEDO and commissioned business entities, and the needs of users. The last section summarizes the steps and schedule for developing this system. The development steps should preferably be implemented stepwise along the progress of the experimental plants, in such an order as the fundamental database, analysis database and engineering database. (NEDO)

  20. Superfluid helium-4: An introductory review

    Vinen, W.F.

    1983-01-01

    Helium was first liquefied by Kamerlingh Onnes in Leiden in July 1908, an achievement that followed much careful and painstaking work. On the same day Onnes reduced the temperature of his helium to a value approaching lK, and he must therefore have produced and observed the superfluid phase. These experimental discoveries led very quickly to a series of remarkable theoretical contributions that laid the foundations for all subsequent work. The period since the second world war has of course seen an enormous amount of work on superfluid helium-4. In reviewing it the author tries to see it in terms of two threads: one originating from Landau; the other from London

  1. Superfluid helium at subcritical active core

    Vasil'ev, V.V.; Lopatkin, A.V.; Muratov, V.G.; Rakhno, I.L.

    2002-01-01

    Power range and neutron flux wherein super thermal source was realized at high volume of superfluid helium were investigated. MCU, BRAND, MCNP codes were used for the calculation of reactors. It is shown that the availability of full-size diameter for cryogenic source of ultracold neutrons, as the source with superfluid helium is considered, is possible in the reflector of subcritical assembly. Results obtained from the MCNP-4B code application demonstrated that the density of thermal neutron flux in helium must be not higher than 2.3 x 10 11 s -1 cm -2 [ru

  2. Low-temperature centrifugal helium compressor

    Kawada, M.; Togo, S.; Akiyama, Y.; Wada, R.

    1974-01-01

    A centrifugal helium compressor with gas bearings, which can be operated at the temperature of liquid nitrogen, has been investigated. This compressor has the advantages that the compression ratio should be higher than the room temperature operation and that the contamination of helium could be eliminated. The outer diameter of the rotor is 112 mm. The experimental result for helium gas at low temperature shows a flow rate of 47 g/s and a compression ratio of 1.2 when the inlet pressure was 1 ata and the rotational speed 550 rev/s. The investigation is now focused on obtaining a compression ratio of 1.5. (author)

  3. Helium compressor aerodynamic design considerations for MHTGR circulators

    McDonald, C.F.

    1988-01-01

    Compressor aerodynamic design considerations for both the main and shutdown cooling circulators in the Modular High-Temperature Gas-Cooled Reactor (MHTGR) plant are addressed in this paper. A major selection topic relates to the impeller type (i.e., axial or radial flow), and the aerothermal studies leading to the selection of optimum parameters are discussed. For the conceptual designs of the main and shutdown cooling circulators, compressor blading geometries were established and helium gas flow paths defined. Both circulators are conservative by industrial standards in terms of aerodynamic and structural loading, and the blade tip speeds are particularly modest. Performance characteristics are presented, and the designs embody margin to ensure that pressure-rise growth potential can be accomodated should the circuit resistance possibly increase as the plant design advances. The axial flow impeller for the main circulator is very similar to the Fort St. Vrain (FSV) helium compressor which performs well. A significant technology base exists for the MHTGR plant circulators, and this is highlighted in the paper. (author). 15 refs, 16 figs, 12 tabs

  4. Co-liquefaction of micro algae with coal. 2; Bisai sorui to sekitan no kyoekika hanno. 2

    Ueda, C.; Matsui, T.; Otsuki, M.; Ikenaga, N.; Suzuki, T. [Kansai University, Osaka (Japan). Faculty of Engineering

    1996-10-28

    For the removal and recycle of CO2, a global warming gas, utilization of photosynthesis by micro algae is investigated. Formed micro algae are decomposed into CO2, H2O and CH4 again, which does not result in the permanent fixation. For the effective utilization of these micro algae, creation of petroleum alternate energy was tried through the co-liquefaction of micro algae with coal. Were investigated influences of the reaction temperature during the co-liquefaction and influences of catalysts, such as Fe(CO)5-S, Ru(CO)12, and Mo(CO)6-S, which are effective for the coal liquefaction. Micro algae, such as chlorella, spirulina, and littorale, and Yallourn brown coal were tested. It was found that co-liquefaction of micro algae with coal can be successfully proceeded under the same conditions as the liquefaction of coal. The oil yield obtained from the co-liquefaction in the presence of Fe(CO)5-S, an effective catalyst for coal liquefaction, agreed appropriately with the arithmetical mean value from separate liquefaction of coal and micro algae. It was suggested that pyrrhotite, an active species for coal liquefaction, was sufficiently formed by increasing the addition of sulfur. 2 refs., 7 figs., 1 tab.

  5. Experimental assessment of the liquefaction resistance of calcareous biogenous sands

    Sandoval Eimar

    2012-10-01

    Full Text Available

    ABSTRACT

    Liquefaction is a phenomenon in which soils, typically sands, suddenly loose a substantial amount of their shear strength and stiffness, this often triggered by large-magnitude earthquakes. Most liquefaction research has focused on silicate-based sands and not on other sand types, such as calcareous biogenous sands Calcareous sands are usually composed of skeletal or non-skeletal remains of marine organisms, with unique characteristics in terms of their mineralogy surface roughness, particle shape, crushability, and intraparticle porosity. The unique characteristics of calcareous sands suggest that their geotechnical engineering behaviour can be substantially different compared to that of terrigenous sands, including their behaviour under seismic loading, which have not been very well studied

    This paper presents the results of an experimental programme aimed at studying the cyclic liquefaction resistance of uncemented calcareous biogenous sands retrieved from south-western Puerto Rico Evaluation of liquefaction potential involved a comprehensive set of isotropically consolidated undrained cyclic triaxial tests on reconstituted samples of this calcareous sand. The programme also included tests on Ottawa terrigenous silica sand samples prepared and tested in similar conditions for comparison purposes.

    In general, the experimental results showed that Cabo Rojo calcareous sands had higher liquefaction resistance compared to Ottawa silica sands tested under similar conditions. Important differences between calcareous and silica sands regarding pore pressure generation characteristics and axial strain accumulation were also observed


  6. Use of separating nozzles or ultra-centrifuges for obtaining helium from gas mixtures containing helium

    Reimann, T.

    1987-01-01

    To obtain helium from gas mixtures containing helium, particularly from natural gas, it is proposed to match the dimensions of the separation devices for a ratio of the molecular weights to be separated of 4:1 of more, which ensures a higher separation factor and therefore a smaller number of separation stages to be connected in series. The process should make reasonably priced separation of helium possible. (orig./HP) [de

  7. Relation between the conditions of helium ion implantation and helium void equilibrium parameters

    Neklyudov, I.M.; Rybalko, V.F.; Ruzhitskij, V.V.; Tolstolutskaya, G.D.

    1981-01-01

    The conditions of helium thermodynamic equilibrium in a system of voids produced by helium ion bombardment of a metal sample are studied. As an initial equation for description of the equilibrium the Clapeyron equation was used. The equation is obtained relating basic parameters of helium voids (average diameter and density) to irradiation parameters (dose, ion energy (straggling)) and properties of the metal (surface tension coefficient, yield strength). Comparison of the calculations with experimental data on helium in nickel found in literature shows that the equation yields satisfactory resutls for the dose range 1.10 16 -1x10 17 cm -2 and temperatures T [ru

  8. CALCULATED REGENERATOR PERFORMANCE AT 4 K WITH HELIUM-4 AND HELIUM-3

    Radebaugh, Ray; Huang Yonghua; O'Gallagher, Agnes; Gary, John

    2008-01-01

    The helium-4 working fluid in regenerative cryocoolers operating with the cold end near 4 K deviates considerably from an ideal gas. As a result, losses in the regenerator, given by the time-averaged enthalpy flux, are increased and are strong functions of the operating pressure and temperature. Helium-3, with its lower boiling point, behaves somewhat closer to an ideal gas in this low temperature range and can reduce the losses in 4 K regenerators. An analytical model is used to find the fluid properties that strongly influence the regenerator losses as well as the gross refrigeration power. The thermodynamic and transport properties of helium-3 were incorporated into the latest NIST regenerator numerical model, known as REGEN3.3, which was used to model regenerator performance with either helium-4 or helium-3. With this model we show how the use of helium-3 in place of helium-4 can improve the performance of 4 K regenerative cryocoolers. The effects of operating pressure, warm-end temperature, and frequency on regenerators with helium-4 and helium-3 are investigated and compared. The results are used to find optimum operating conditions. The frequency range investigated varies from 1 Hz to 30 Hz, with particular emphasis on higher frequencies

  9. Diffusion of helium and nucleation-growth of helium-bubbles in metallic materials

    Zhang Chonghong; Chen Keqin; Wang Yinshu

    2001-01-01

    Studies of diffusion and aggregation behaviour of helium in metallic materials are very important to solve the problem of helium embrittlement in structural materials used in the environment of nuclear power. Experimental studies on helium diffusion and aggregation in austenitic stainless steels in a wide temperature range have been performed in authors' research group and the main results obtained are briefly summarized. The mechanism of nucleation-growth of helium-bubbles has been discussed and some problems to be solved are also given

  10. Charged condensate and helium dwarf stars

    Gabadadze, Gregory; Rosen, Rachel A, E-mail: gg32@nyu.edu, E-mail: rar339@nyu.edu [Center for Cosmology and Particle Physics, Department of Physics, New York University, New York, NY 10003 (United States)

    2008-10-15

    White dwarf stars composed of carbon, oxygen and heavier elements are expected to crystallize as they cool down below certain temperatures. Yet, simple arguments suggest that the helium white dwarf cores may not solidify, mostly because of zero-point oscillations of the helium ions that would dissolve the crystalline structure. We argue that the interior of the helium dwarfs may instead form a macroscopic quantum state in which the charged helium-4 nuclei are in a Bose-Einstein condensate, while the relativistic electrons form a neutralizing degenerate Fermi liquid. We discuss the electric charge screening, and the spectrum of this substance, showing that the bosonic long-wavelength fluctuations exhibit a mass gap. Hence, there is a suppression at low temperatures of the boson contribution to the specific heat-the latter being dominated by the specific heat of the electrons near the Fermi surface. This state of matter may have observational signatures.

  11. On the helium gas leak test

    Nishikawa, Akira; Ozaki, Susumu

    1975-01-01

    The helium gas leak test (Helium mass spectrometer testing) has a leak detection capacity of the highest level in practical leak tests and is going to be widely applied to high pressure vessels, atomic and vacuum equipments that require high tightness. To establish a standard test procedure several series of experiments were conducted and the results were investigated. The conclusions are summarized as follows: (1) The hood method is quantitatively the most reliable method. The leak rate obtained by tests using 100% helium concentration should be the basis of the other method of test. (2) The integrating method, bell jar method, and vacuum spray method can be considered quantitative when particular conditions are satisfied. (3) The sniffer method is not to be considered quantitive. (4) The leak rate of the hood, integrating, and bell jar methods is approximately proportional to the square of the helium partial pressure. (auth.)

  12. Helium-Hydrogen Recovery System, Phase I

    National Aeronautics and Space Administration — Immense quantities of expensive liquefied helium are required at Stennis and Kennedy Space Centers for pre-cooling rocket engine propellant systems prior to filling...

  13. KSTAR Helium Refrigeration System Design and Manufacturing

    Dauguet, P.; Briend, P.; Abe, I.; Fauve, E.; Bernhardt, J.-M.; Andrieu, F.; Beauvisage, J.

    2006-01-01

    The tokamak developed in the KSTAR (Korean Superconducting Tokamak Advanced Research) project makes intensive use of superconducting magnets operated at 4.5 K. The cold components of the KSTAR tokamak require forced flow of supercritical helium for magnets/structure, boiling liquid helium for current leads, and gaseous helium for thermal shields. The cryogenic system will provide stable operation and full automatic control. A three-pressure helium cycle composed of six turbines has been customised design for this project. The '' design '' operating mode results with a system composed of a 9 kW refrigerator (including safety margin) and using gas and liquid storages for mass balancing. During Shot/Standby mode, the heat loads are highly time-dependent. A thermal damper is used to smooth these variations and will allow stable operation. (author)

  14. Realization of mechanical rotation in superfluid helium

    Gordon, E. B.; Kulish, M. I.; Karabulin, A. V.; Matyushenko, V. I.; Dyatlova, E. V.; Gordienko, A. S.; Stepanov, M. E.

    2017-09-01

    The possibility of using miniaturized low-power electric motors submerged in superfluid helium for organization of rotation inside a cryostat has been investigated. It has been revealed that many of commercial micromotors can operate in liquid helium consuming low power. Turret with 5 sample holders, assembled on the base of stepper motor, has been successfully tested in experiments on the nanowire production in quantized vortices of superfluid helium. Application of the stepper motor made it possible in a single experiment to study the effect of various experimental parameters on the yield and quality of the nanowires. The promises for continuous fast rotation of the bath filled by superfluid helium by using high-speed brushless micromotor were outlined and tested. Being realized, this approach will open new possibility to study the guest particles interaction with the array of parallel linear vortices in He II.

  15. Helium leak testing the Westinghouse LCP coil

    Merritt, P.A.; Attaar, M.H.; Hordubay, T.D.

    1983-01-01

    The tests, equipment, and techniques used to check the Westinghouse LCP coil for coolant flow path integrity and helium leakage are unique in terms of test sensitivity and application. This paper will discuss the various types of helium leak testing done on the LCP coil as it enters different stages of manufacture. The emphasis will be on the degree of test sensitivity achieved under shop conditions, and what equipment, techniques and tooling are required to achieve this sensitivity (5.9 x 10 -8 scc/sec). Other topics that will be discussed are helium flow and pressure drop testing which is used to detect any restrictions in the flow paths, and the LCP final acceptance test which is the final leak test performed on the coil prior to its being sent for testing. The overall allowable leak rate for this coil is 5 x 10 -6 scc/sec. A general evaluation of helium leak testing experience are included

  16. Near field characteristics of buoyant helium plumes

    pressure tubing. Helium gas enters the bottom of the settling chamber, passing through two ... A 40 mesh, flat stainless steel screen is placed across the orifice exit. ... PIV and PLIF measurements are carried out in phase resolved manner.

  17. Hybrid Circuit QED with Electrons on Helium

    Yang, Ge

    Electrons on helium (eHe) is a 2-dimensional system that forms naturally at the interface between superfluid helium and vacuum. It has the highest measured electron mobility, and long predicted spin coherence time. In this talk, we will first review various quantum computer architecture proposals that take advantage of these exceptional properties. In particular, we describe how electrons on helium can be combined with superconducting microwave circuits to take advantage of the recent progress in the field of circuit quantum electrodynamics (cQED). We will then demonstrate how to reliably trap electrons on these devices hours at a time, at millikelvin temperatures inside a dilution refrigerator. The coupling between the electrons and the microwave resonator exceeds 1 MHz, and can be reproduced from the design geometry using our numerical simulation. Finally, we will present our progress on isolating individual electrons in such circuits, to build single-electron quantum dots with electrons on helium.

  18. Helium cosmic ray flux measurements at Mars

    Lee, Kerry; Pinsky, Lawrence; Andersen, Vic; Zeitlin, Cary; Cleghorn, Tim; Cucinotta, Frank; Saganti, Premkumar; Atwell, William; Turner, Ron

    2006-01-01

    The helium energy spectrum in Martian orbit has been observed by the MARIE charged particle spectrometer aboard the 2001 Mars Odyssey spacecraft. The orbital data were taken from March 13, 2002 to October 28, 2003, at which time a very intense Solar Particle Event caused a loss of communication between the instrument and the spacecraft. The silicon detector stack in MARIE is optimized for the detection of protons and helium in the energy range below 100MeV/n, which typically includes almost all of the flux during SPEs. This also makes MARIE an efficient detector for GCR helium in the energy range of 50-150MeV/n. We will present the first fully normalized flux results from MARIE, using helium ions in this energy range

  19. Helium cosmic ray flux measurements at Mars

    Lee, Kerry [University of Houston, 4800 Calhoun Rd. Houston, TX 77204 (United States)]. E-mail: ktlee@ems.jsc.nasa.gov; Pinsky, Lawrence [University of Houston, 4800 Calhoun Rd. Houston, TX 77204 (United States); Andersen, Vic [University of Houston, 4800 Calhoun Rd. Houston, TX 77204 (United States); Zeitlin, Cary [National Space Biomedical Research Institute, Baylor College of Medicine, Houston, TX (United States); Cleghorn, Tim [NASA Johnson Space Center, 2101 NASA Road 1, Houston, TX 77058 (United States); Cucinotta, Frank [NASA Johnson Space Center, 2101 NASA Road 1, Houston, TX 77058 (United States); Saganti, Premkumar [Prairie View A and M University, P.O. Box 519, Prairie View, TX 77446-0519 (United States); Atwell, William [The Boeing Company, Houston, TX (United States); Turner, Ron [Advancing National Strategies and Enabling Results (ANSER), Arlington, Virginia (United States)

    2006-10-15

    The helium energy spectrum in Martian orbit has been observed by the MARIE charged particle spectrometer aboard the 2001 Mars Odyssey spacecraft. The orbital data were taken from March 13, 2002 to October 28, 2003, at which time a very intense Solar Particle Event caused a loss of communication between the instrument and the spacecraft. The silicon detector stack in MARIE is optimized for the detection of protons and helium in the energy range below 100MeV/n, which typically includes almost all of the flux during SPEs. This also makes MARIE an efficient detector for GCR helium in the energy range of 50-150MeV/n. We will present the first fully normalized flux results from MARIE, using helium ions in this energy range.

  20. Unconventional Coal in Wyoming: IGCC and Gasification of Direct Coal Liquefaction Residue

    Schaffers, William Clemens

    Two unconventional uses for Wyoming Powder River Basin coal were investigated in this study. The first was the use of coal fired integrated gasification combined cycle (IGCC) plants to generate electricity. Twenty-eight different scenarios were modeled using AspenPlusRTM software. These included slurry, mechanical and dried fed gasifiers; Wyodak and Green River coals, 0%, 70%, and 90% CO2 capture; and conventional evaporative vs air cooling. All of the models were constructed on a feed basis of 6,900 tons of coal per day on an "as received basis". The AspenPlus RTM results were then used to create economic models using Microsoft RTM Excel for each configuration. These models assumed a 3 year construction period and a 30 year plant life. Results for capital and operating costs, yearly income, and internal rates of return (IRR) were compared. In addition, the scenarios were evaluated to compare electricity sales prices required to obtain a 12% IRR and to determine the effects of a carbon emissions tax on the sales price. The second part of the study investigated the gasification potential of residue remaining from solvent extraction or liquefaction of Powder River Basin Coal. Coal samples from the Decker mine on the Wyoming-Montana border were extracted with tetralin at a temperature of 360°C and pressure of 250 psi. Residue from the extraction was gasified with CO2 or steam at 833°C, 900°C and 975°C at pressures of 0.1 and 0.4 MPa. Product gases were analyzed with a mass spectrometer. Results were used to determine activation energies, reaction order, reaction rates and diffusion effects. Surface area and electron microscopic analyses were also performed on char produced from the solvent extraction residue.

  1. Effects of helium impurities on superalloys

    Selle, J.E.

    1977-07-01

    A review of the literature on the effects of helium impurities on superalloys at elevated temperatures was undertaken. The actual effects of these impurities vary depending on the alloy, composition of the gas atmosphere, and temperature. In general, exposure in helium produces significant but not catastrophic changes in the structure and properties of the alloys. The effects of these treatments on the structure, creep, fatigue, and mechanical properties of the various alloys are reviewed and discussed. Suggestions for future work are presented

  2. Electrons on the surface of liquid helium

    Lambert, D.K.

    1979-05-01

    Spectroscopic techniques were used to study transitions of electrons between bound states in the potential well near a helium surface. The charge density distribution of electrons on the surface was independently obtained from electrical measurements. From the measurements, information was obtained both about the interaction of the bound state electrons with the surface of liquid helium and about local disorder in the positions of electrons on the surface

  3. Effect of helium on void swelling in vanadium

    Brimhall, J.L.; Simonen, E.P.

    1975-01-01

    Little difference in void microstructural swelling of vanadium is observed when helium is injected simultaneously with a 46- or 5-MeV nickel beam as compared to no helium injection, at least at high dose rates. At lower dose rates, a strong helium effect is seen when the helium is injected prior to heavy ion bombardment. The effect of the helium is shown to be a strong function of the overall displacement damage rate

  4. The problem of helium in structural materials for fusion reactor

    Nikiforov, A.S.; Zakharov, A.P.; Chuev, V.I.

    1982-01-01

    The processes of helium buildup in some metals and alloys at different energy neutron flux irradiation under thermonuclear reactor conditions are considered. The data on high temperature helium embrittlement of a number of stainless steels, titanium and aluminium alloys etc. are given A review of experiments concerning the implanted helium behaviour is presented. Possible reactions between helium atoms and point defects or their clusters are discussed. Analysed are material structure variations upon buildup in them up to 1 at % of helium

  5. Sonic Helium Detectors in the Fermilab Tevatron

    Bossert, R. J.

    2006-04-01

    In the Fermilab Tevatron cryogenic system there are many remotely located low-pressure plate relief valves that must vent large volumes of cold helium gas when magnet quenches occur. These valves can occasionally stick open or not reseat completely, resulting in a large helium loss. As such, the need exists for a detector to monitor the relief valve's discharge area for the presence of helium. Due to the quantity needed, cost is an important factor. A unit has been developed and built for this purpose that is quite inexpensive. Its operating principle is based on the speed of sound, where two closely matched tubes operate at their acoustic resonant frequency. When helium is introduced into one of these tubes, the resulting difference in acoustic time of flight is used to trigger an alarm. At present, there are 39 of these units installed and operating in the Tevatron. They have detected many minor and major helium leaks, and have also been found useful in detecting a rise in the helium background in the enclosed refrigerator buildings. This paper covers the construction, usage and operational experience gained with these units over the last several years.

  6. Sonic helium detectors in the Fermilab Tevatron

    Bossert, R.J.; Fermilab

    2006-01-01

    In the Fermilab Tevatron cryogenic system there are many remotely located low-pressure plate relief valves that must vent large volumes of cold helium gas when magnet quenches occur. These valves can occasionally stick open or not reseat completely, resulting in a large helium loss. As such, the need exists for a detector to monitor the relief valve's discharge area for the presence of helium. Due to the quantity needed, cost is an important factor. A unit has been developed and built for this purpose that is quite inexpensive. Its operating principle is based on the speed of sound, where two closely matched tubes operate at their acoustic resonant frequency. When helium is introduced into one of these tubes, the resulting difference in acoustic time of flight is used to trigger an alarm. At present, there are 39 of these units installed and operating in the Tevatron. They have detected many minor and major helium leaks, and have also been found useful in detecting a rise in the helium background in the enclosed refrigerator buildings. This paper covers the construction, usage and operational experience gained with these units over the last several years

  7. Separation of compressor oil from helium

    Strauss, R.; Perrotta, K.A.

    1982-01-01

    Compression of helium by an oil-sealed rorary screw compressor entrains as much as 4000 parts per million by weight of liquid and vapor oil impurities in the gas. The reduction below about 0.1 ppm for cryogenic applications is discussed. Oil seperation equipment designed for compressed air must be modified significantly to produce the desired results with helium. The main differences between air and helium filtration are described. A description of the coalescers is given with the continuous coalescing of liquid mist from air or other gas illustrated. Oil vapor in helium is discussed in terms of typical compressor oils, experimental procedure for measuring oil vapor concentration, measured volatile hydrocarbons in the lubricants, and calculated concentration of oil vapor in Helium. Liquid oil contamination in helium gas can be reduced well below 0.1 ppm by a properly designed multiple state coalescing filter system containing graded efficiency filter elements. The oil vapor problem is best attached by efficiently treating the oil to remove most of the colatiles before charging the compressor

  8. Use of TVO sensors for level monitoring in mixed liquid helium container; Einsatz von TVO-Sensoren zur Fuellstandsueberwachung im durchmischten Fluessigheliumbehaelter

    Richter, T.; Hollik, M.; Lietzow, R. [Karlsruher Institut fuer Technologie (KIT), Eggenstein-Leopoldshafen (Germany). Inst. fuer Technische Physik

    2015-07-01

    For the acceptance test of 26 current leads for the fusion test reactor JT-60SA in Japan the Karlsruhe Institute of Technology (KIT) constructed a current lead test system CuLTKa (Current Lead Test Facility Karlsruhe). The facility consists of a total of five cryostat and is connected with a refrigeration system. One of cryostats is used for the temperature control of a cooling flow for the experiment and contains therefore a 400 liter liquid helium container. In this there is a coiled tube located through which the helium flow (4 bar and 5.5 K) for cooling the cold contacts is cooled to bath temperature (4.5 K). During normal operation a continuous liquefaction takes place in this tank. The level is measured by a superconducting level probe and controlled by a heater via a corresponding heating load. These processes result in a permanent mixing and thus homogeneous temperature distribution throughout the container. To hedge disruption of the level probe or the heater a lower (tank empty) and an upper (tank full) cut-off point were provided. For this TVO sensors are used which act as limit switches for automatic operation of the helium cooler. This paper presents the detailed construction and the encountered obstacles in using this approach in the plant CuLTKa. It highlights the reasons and explains the followed modifications, whereby a use of TVO sensors for the said purpose has been made possible in CuLTKa. Here are holistically both the mechanical also metrological aspects described. [German] Fuer die Abnahmetests von 26 Stromzufuehrungen fuer den Fusionstestreaktor JT-60SA in Japan wurde im Karlsruher Institut fuer Technologie (KIT) eine Stromzufuehrungstestanlage CuLTKa (Current Lead Test Facility Karlsruhe) aufgebaut. Die Anlage besteht aus insgesamt fuenf Kryostaten und ist mit einer Kaelteanlage verbunden. Einer der Kryostate dient zur Temperierung eines Kuehlstromes fuer das Experiment und enthaelt dafuer einen 400 l Fluessigheliumbehaelter. In diesem

  9. Helium-cooled nuclear reactor

    Longton, P.B.; Cowen, H.C.

    1975-01-01

    In helium cooled HTR's there is a by-pass circuit for cleaning purposes in addition to the main cooling circuit. This is to remove such impurities as hydrogen, methane, carbon monoxide and water from the coolant. In this system, part of the coolant successively flows first through an oxidation bed of copper oxide and an absorption bed of silica gel, then through activated charcoal or a molecular sieve. The hydrogen and carbon monoxide impurities are absorbed and the dry gas is returned to the main cooling circuit. To lower the hydrogen/water ratio without increasing the hydrogen fraction in the main cooling circuit, some of the hydrogen fraction converted into water is added to the cooling circuit. This is done, inter alia, by bypassing the water produced in the oxidation bed before it enters the absorption bed. The rest of the by-pass circuit, however, also includes an absorption bed with a molecular sieve. This absorbs the oxidized carbon monoxide fraction. In this way, such side effects as the formation of additional methane, carburization of the materials of the by-pass circuit or loss of graphite are avoided. (DG/RF) [de

  10. Recombination of positive helium ions in gaseous helium

    Shyu, J.S.

    1988-01-01

    The Wigner-Keck Monte Carlo trajectory method and the resonance complex theory are employed to calculate the rate coefficient k for H e + ions recombining in gaseous helium in the temperature range 80 2 + is obtained from a Morse potential and a long range ion-induced dipole interaction term. The three body He 3 + interaction is represented by an approximate expression which, for practical purpose, depends on the same parameters that determine the two body interaction. Russell had employed the Wigner-Keck Monte Carlo trajectory method to the same reaction. Unlike his calculation, in which the final quasibound states are treated as continuous, we apply the JWKB approximation to quantize those quasibound states. Both the values of k, calculated from two different quasibound state treatments, are found to be very close and give good agreement with experimental results obtained by Biondi, although they are still 10% to 20% lower than the experimental results. The resonance complex theory, developed by Roberts et al, is then employed to investigated de-excitation from the highest quasibound state, which can be populated by inward tunneling through the rotational (centrifugal) barrier. It is found that this strongly supports a suggestion proposed by Russell. He had suggested that the remaining difference between the Wigner-Keck method and experiment might be largely due to the formation of highly excited quasibound states. The statistical errors of the rate constants, which is the sun of results obtained from both methods, are kept less then 5% by running 2500 trajectories in the first method and 500 in the second

  11. Helium mobility in advanced nuclear ceramics

    Agarwal, Shradha

    2014-01-01

    The main goal of this work is to improve our knowledge on the mechanisms able to drive the helium behaviour in transition metal carbides and nitrides submitted to thermal annealing or ion irradiation. TiC, TiN and ZrC polycrystals were implanted with 3 MeV 3 He ions at room temperature in the fluence range 2 * 10 15 et 6 * 10 16 cm -2 . Some of them have been pre-irradiated with self-ions (14 MeV Ti or Zr). Fully controlled thermal annealing tests were subsequently carried out in the temperature range 1000 - 1600 C for two hours. The evolution of the helium depth distribution in function of implantation dose, temperature and pre-irradiation dose was measured thanks to the deuteron-induced nuclear reaction 3 He(d, p 0 ) 4 He between 900 keV and 1.8 MeV. The microstructure of implanted and annealed samples was investigated by transmission electron microscopy on thin foils prepared using the FIB technique. Additional characterization tools, as X-ray diffraction and Raman microspectrometry, have been also applied in order to obtain complementary information. Among the most relevant results obtained, the following have to be outlined: - double-peak helium depth profile was measured on as implanted sample for the three compounds. The first peak is located near the end of range and includes the major part of helium, a second peak located close to the surface corresponds to the helium atoms trapped by the native vacancies; - the helium retention capacity in transition metal carbides and nitrides submitted to fully controlled thermal treatments varies according to ZrC 0.92 ≤ TiC 0.96 ≤ TiN 0.96 ; - whatever the investigated material, a self-ion-induced pre-damaging does not modify the initial helium profile extent. The influence of the post-implantation thermal treatment remains preponderant in any case; - the apparent diffusion coefficient of helium is in the range 4 * 10 -18 - 2 * 10 -17 m 2 s -1 in TiC0.96 and 3.5 * 10 -19 - 5.3 * 10 -18 m 2 s -1 in TiN 0.96 between

  12. Properties of Direct Coal Liquefaction Residue Modified Asphalt Mixture

    Jie Ji

    2017-01-01

    Full Text Available The objectives of this paper are to use Direct Coal Liquefaction Residue (DLCR to modify the asphalt binders and mixtures and to evaluate the performance of modified asphalt mixtures. The dynamic modulus and phase angle of DCLR and DCLR-composite modified asphalt mixture were analyzed, and the viscoelastic properties of these modified asphalt mixtures were compared to the base asphalt binder SK-90 and Styrene-Butadiene-Styrene (SBS modified asphalt mixtures. The master curves of the asphalt mixtures were shown, and dynamic and viscoelastic behaviors of asphalt mixtures were described using the Christensen-Anderson-Marasteanu (CAM model. The test results show that the dynamic moduli of DCLR and DCLR-composite asphalt mixtures are higher than those of the SK-90 and SBS modified asphalt mixtures. Based on the viscoelastic parameters of CAM models of the asphalt mixtures, the high- and low-temperature performance of DLCR and DCLR-composite modified asphalt mixtures are obviously better than the SK-90 and SBS modified asphalt mixtures. In addition, the DCLR and DCLR-composite modified asphalt mixtures are more insensitive to the frequency compared to SK-90 and SBS modified asphalt mixtures.

  13. Air liquefaction and enrichment system propulsion in reusable launch vehicles

    Bond, W. H.; Yi, A. C.

    1994-07-01

    A concept is shown for a fully reusable, Earth-to-orbit launch vehicle with horizontal takeoff and landing, employing an air-turborocket for low speed and a rocket for high-speed acceleration, both using liquid hydrogen for fuel. The turborocket employs a modified liquid air cycle to supply the oxidizer. The rocket uses 90% pure liquid oxygen as its oxidizer that is collected from the atmosphere, separated, and stored during operation of the turborocket from about Mach 2 to 5 or 6. The takeoff weight and the thrust required at takeoff are markedly reduced by collecting the rocket oxidizer in-flight. This article shows an approach and the corresponding technology needs for using air liquefaction and enrichment system propulsion in a single-stage-to-orbit (SSTO) vehicle. Reducing the trajectory altitude at the end of collection reduces the wing area and increases payload. The use of state-of-the-art materials, such as graphite polyimide, in a direct substitution for aluminum or aluminum-lithium alloy, is critical to meet the structure weight objective for SSTO. Configurations that utilize 'waverider' aerodynamics show great promise to reduce the vehicle weight.

  14. Hydrotreating of heavy distillate derived from Wandoan coal liquefaction

    Sato, Y. [National Institute for Resources and Environment, Osaka (Japan). Hydrocarbon Research Lab.

    1997-12-03

    The paper reports how the hydrotreatment of coal-derived heavy distillate, obtained from the liquefaction of Wandoan coal using a 1 t/day bench unit, was performed to clarify the effects of catalyst species, reaction temperature and hydrogen pressure on the chemical composition of the product. Experimental runs were carried out over alumina-supported Go-Mo and Ni-Mo catalysts in a fixed bed reactor of 20 ml in volume at 350-390{degree}C under hydrogen pressure of 50-150 kg/cm{sup 2}G with liquid hourly space velocity (LHSV) of 0.5-2 h{sup -1}. The product, as analyzed by gas chromatography, indicated that larger amounts of alkylbenzenes such as toluene or xylenes were produced at the elevated temperature of 390{degree}C, but the concentrations of condensed aromatics such as naphthalene, biphenyl, fluorene and phenanthrene decreased with the severity of reaction conditions. Pyrene and methylpyrene decreased in amount with a shorter LHSV and higher hydrogen pressure, but increased at higher temperature of 390{degree}C. Shorter LHSV and higher hydrogen pressure are much more effective in hydrogenation, hydrodnitrogenation and hydrodeoxygenation than the higher reaction temperature up to 390{degree}C.

  15. [Longjintonglin Capsules for type IIIA prostatitis accompanied by abnormal semen liquefaction: A clinical observation].

    Cai, Hong-cai; Wan, Chang-chun; Geng, Qiang; Liu, Wei; Zhang, Guo-wei; Shang, Xue-jun; Huang, Yu-feng

    2016-01-01

    To evaluate the therapeutic effect of Longjintonglin Capsules on type IIIA prostatitis accompanied by abnormal semen liquefaction. We selected 140 patients with type IIIA prostatitis accompanied by abnormal semen liquefaction according to the diagnostic standards of the American Institutes of Health (NIH) and treated them with Longjintonglin Capsules orally 3 capsules once tid for 12 weeks. We obtained the NIH Chronic Prostatitis Symptom Indexes (NIH-CPSI), traditional Chinese medicine (TCM) syndrome scores, leukocyte count in the expressed prostatic secretion (EPS), semen liquefaction time, and the results of semen analysis and compared these indicators before and after the treatment. Of the 140 cases, 132 were included in this study, excluding 8 due to their incomplete case histories. Before and after 4, 8 and 12 weeks of medication, the total NIH-CPSI scores were 24.52 ± 5.43, 21.28 ± 4.85, 18.01 ± 4.28, and 14.49 ± 3.65 (P prostatitis were cured and another 72 well responded, with an overall response rate of 78.0%. Of those with abnormal semen liquefaction, 61 were cured, 39 well responded, and 32 failed to respond, with an overall effectiveness rate of 75.8%. Semen analysis showed significantly increased percentage of progressively motile sperm after 4, 8 and 12 weeks of medication as compared with the baseline (P prostatitis accompanied by abnormal semen liquefaction.

  16. A spotlight on liquefaction: evidence from clinical settings and experimental models in tuberculosis.

    Cardona, Pere-Joan

    2011-01-01

    Liquefaction is one of the most intriguing aspects of human tuberculosis. It is a major cause of the transition from the infection to active disease (tuberculosis, TB) as well as the transmission of M. tuberculosis to other persons. This paper reviews the natural history of liquefaction in humans from a pathological and radiological point of view and discusses how the experimental models available can be used to address the topic of liquefaction and cavity formation. Different concepts that have been related to liquefaction, from the influence of immune response to mechanical factors, are reviewed. Synchronic necrosis or apoptosis of infected macrophages in a close area, together with an ineffective fibrosis, appears to be clue in this process, in which macrophages, the immune response, and bacillary load interact usually in a particular scenario: the upper lobes of the lung. The summary would be that even if being a stochastic effect, liquefaction would result if the organization of the intragranulomatous necrosis (by means of fibrosis) would be disturbed.

  17. A Spotlight on Liquefaction: Evidence from Clinical Settings and Experimental Models in Tuberculosis

    Pere-Joan Cardona

    2011-01-01

    Full Text Available Liquefaction is one of the most intriguing aspects of human tuberculosis. It is a major cause of the transition from the infection to active disease (tuberculosis, TB as well as the transmission of M. tuberculosis to other persons. This paper reviews the natural history of liquefaction in humans from a pathological and radiological point of view and discusses how the experimental models available can be used to address the topic of liquefaction and cavity formation. Different concepts that have been related to liquefaction, from the influence of immune response to mechanical factors, are reviewed. Synchronic necrosis or apoptosis of infected macrophages in a close area, together with an ineffective fibrosis, appears to be clue in this process, in which macrophages, the immune response, and bacillary load interact usually in a particular scenario: the upper lobes of the lung. The summary would be that even if being a stochastic effect, liquefaction would result if the organization of the intragranulomatous necrosis (by means of fibrosis would be disturbed.

  18. Retesting of liquefaction and nonliquefaction case histories from the 1976 Tangshan earthquake

    Moss, R.E.S.; Kayen, R.E.; Tong, L.-Y.; Liu, S.-Y.; Cai, G.-J.; Wu, J.

    2011-01-01

    A field investigation was performed to retest liquefaction and nonliquefaction sites from the 1976 Tangshan earthquake in China. These sites were carefully investigated in 1978 and 1979 by using standard penetration test (SPT) and cone penetration test (CPT) equipment; however, the CPT measurements are obsolete because of the now nonstandard cone that was used at the time. In 2007, a modern cone was mobilized to retest 18 selected sites that are particularly important because of the intense ground shaking they sustained despite their high fines content and/or because the site did not liquefy. Of the sites reinvestigated and carefully reprocessed, 13 were considered accurate representative case histories. Two of the sites that were originally investigated for liquefaction have been reinvestigated for cyclic failure of fine-grained soil and removed from consideration for liquefaction triggering. The most important outcome of these field investigations was the collection of more accurate data for three nonliquefaction sites that experienced intense ground shaking. Data for these three case histories is now included in an area of the liquefaction triggering database that was poorly populated and will help constrain the upper bound of future liquefaction triggering curves. ?? 2011 American Society of Civil Engineers.

  19. Assessment of Soil Liquefaction Potential in Defence Housing Authority, Karachi, Pakistan

    Sumaira Asif Khan

    2017-04-01

    Full Text Available The occurrence of liquefaction phenomenon may be induced in the event of a large magnitude earthquake but sometimes loose, saturated and poorly graded sand may be subjected to liquefaction due to the vibration produced by other sources. Liquefaction could cause damage to building and infrastructure due to sudden increase of pore pressure in the loose layers of saturated sand causing the loss of bearing capacity and shear strength. Defence Housing Authority (DHA is the well planned residential scheme established by Pakistan Army along the coastal belt of Karachi. The soil occurring in DHA is fine grained, poorly graded and mainly comprises of sandy silt and silty sand of Recent age, where water table is encountered at very shallow depth. Hence, it is important to assess the geotechnical behavior of the soil in DHA area, where most of the high rise buildings and mega civil structures are being constructed. In present study, seismic soil liquefaction was evaluated at 15 sites (30 bore holes in DHA by using simplified empirical method in terms of Factor of Safety (FS. The Relative Density (RD was determined with the help of Standard Penetration Test (SPT data. Grain size analysis was also carried out on each borehole samples. The results revealed that the DHA area is vulnerable to liquefaction during severe seismic event of magnitude between 6.5 and 7.5 in Karachi.

  20. The real gas behaviour of helium as a cooling medium for high-temperature reactors

    Hewing, G.

    1977-01-01

    The article describes the influence of the real gas behaviour on the variables of state for the helium gas and the effects on the design of high-temperature reactor plants. After explaining the basic equations for describing variables and changes of state of the real gas, the real and ideal gas behaviour is analysed. Finally, the influence of the real gas behaviour on the design of high-temperature reactors in one- and two-cycle plants is investigated. (orig.) [de

  1. Isolation and characterization of cellulose nanofibers from bamboo using microwave liquefaction combined with chemical treatment and ultrasonication

    Jiulong Xie; Chung Hse; Cornelis F. De Hoop; Tingxing Hu; Jinqiu Qi; Todd F. Shupe

    2016-01-01

    Cellulose nanofibers were successfully isolated from bamboo using microwave liquefaction combinedwith chemical treatment and ultrasonic nanofibrillation processes. The microwave liquefaction couldeliminate almost all the lignin in bamboo, resulting in high cellulose content residues within 7 min, andthe cellulose enriched residues could be readily purified by...

  2. Microwave-assisted liquefaction of wood with polyhydric alcohols and its application in preparation of polyurethane (PU) foams

    Hui Pan; Zhifeng Zheng; Chung Y. Hse

    2011-01-01

    Microwave radiation was used as the heating source in southern pine wood liquefaction with PEG/glycerin binary solvent. It was found that microwave heating was more efficient than conventional oil bath heating for wood liquefaction. The wood residue content of the H2SO4 catalyzed liquefied wood dropped to zero within 5 min with microwave heating. The resulting...

  3. Investigation of bio-composites using Novolac type liquefied wood resin: effects of liquefaction and fabrication conditions

    Hui Pan; Chung-Yun Hse; Todd F. Shupe

    2009-01-01

    Wood liquefaction using an organic solvent and an acid catalyst has long been studied as a novel technique to utilize biomass as an alternative to petroleum-based products. Oxalic acid is a weaker organic acid than a mineral acid and wood liquefaction with oxalic acid as a catalyst will result in a higher amount of wood residue than that with a mineral acid....

  4. Two-stage alkaline hydrothermal liquefaction of wood to biocrude in a continuous bench-scale system

    Sintamarean, Iulia-Maria; Grigoras, Ionela; Jensen, Claus Uhrenholt

    2017-01-01

    unit. In total, 100 kg of wood paste with 25% dry matter is processed at 400 °C and 30 MPa, demonstrating the usefulness of this two-stage liquefaction strategy. An additional advantage liquefaction of such pretreated wood shows increased biocrude yields with approximately 10% compared to the case...

  5. Towards helium-3 neutron polarizers

    Tasset, F.

    1995-01-01

    With a large absorption cross-section entirely due to antiparallel spin capture, polarized helium-3 is presently the most promising broad-band polarizer for thermal and epithermal neutrons. Immediate interest was raised amongst the neutron community when a dense gaseous 3 He polarizer was used for the first time in 1988, on a pulsed neutron beam at Los Alamos. With 20 W of laser power on a 30 cm long, 8.6 atm target, 40% 3 He polarization was achieved in a recent polarized electron scattering experiment at SLAC. In this technique the 3 He nuclei are polarized directly at an appropriate high pressure through spin-exchange collisions with a thick, optically pumped rubidium vapor. A different and competitive approach is being presently developed at Mainz University in collaboration with ENS Paris and now the ILL. A discharge is established in pure 3 He at low pressure producing excited metastable atoms which can be optically pumped with infra-red light. Highly effective exchange collision with the atoms remaining in the ground state quickly produces 75% polarization at 1.5 mbar. A truly non-magnetic system then compresses the polarized gas up to several bars as required. The most recent machine comprises a two-stage glass-titanium compressor. In less than 1 h it can inflate a 100 cm 3 target cell with three bars of polarized gas. The very long relaxation times (several days) now being obtained at high pressure with a special metallic coating on the glass walls, the polarized cell can be detached and inserted in the neutron beam as polarizer. We expect 50% 3 He-polarization to be reached soon, allowing such filters to compete favorably with existing Heusler-crystal polarizers at thermal and short neutron wavelengths. It must be stressed that such a system based on a 3 He polarization factory able to feed several passive, transportable, polarizers is well matched to neutron scattering needs. (orig.)

  6. Rotons, Superfluidity, and Helium Crystals

    Balibar, Sébastien

    2006-09-01

    Fritz London understood that quantum mechanics could show up at the macroscopic level, and, in 1938, he proposed that superfluidity was a consequence of Bose-Einstein condensation. However, Lev Landau never believed in London's ideas; instead, he introduced quasiparticles to explain the thermodynamics of superfluid 4He and a possible mechanism for its critical velocity. One of these quasiparticles, a crucial one, was his famous "roton" which he considered as an elementary vortex. At the LT0 conference (Cambridge, 1946), London criticized Landau and his "theory based on the shaky grounds of imaginary rotons". Despite their rather strong disagreement, Landau was awarded the London prize in 1960, six years after London's death. Today, we know that London and Landau had both found part of the truth: BEC takes place in 4He, and rotons exist. In my early experiments on quantum evaporation, I found direct evidence for the existence of rotons and for evaporation processes in which they play the role of photons in the photoelectric effect. But rotons are now considered as particular phonons which are nearly soft, due to some local order in superfluid 4He. Later we studied helium crystals which are model systems for the general study of crystal surfaces, but also exceptional systems with unique quantum properties. In our recent studies of nucleation, rotons show their importance again: by using acoustic techniques, we have extended the study of liquid 4He up to very high pressures where the liquid state is metastable, and we wish to demonstrate that the vanishing of the roton gap may destroy superfluidity and trigger an instability towards the crystalline state.

  7. Preliminary study on helium turbomachine for high temperature gas-cooled reactor

    Chen Yihua; Wang Jie; Zhang Zuoyi

    2003-01-01

    In the high temperature gas-cooled reactor (HTGR), gas turbine cycle is a new concept in the field of nuclear power. It combines two technologies of HTGR and gas turbine cycle, which represent the state-of-the-art technologies of nuclear power and fossil fuel generation respectively. This approach is expected to improve safety and economy of nuclear power plant significantly. So it is a potential scheme with competitiveness. The heat-recuperated cycle is the main stream of gas turbine cycle. In this cycle, the work medium is helium, which is very different from the air, so that the design features of the helium turbomachine and combustion gas turbomachine are different. The paper shows the basic design consideration for the heat-recuperated cycle as well as helium turbomachine and highlights its main design features compared with combustion gas turbomachine

  8. Effects of helium ions of an early embryo on postembryonic leaf development in Brassica napus L.

    Sakurai, Noboru [Tokyo Metropolitan Industrial Technology Research Institute, Tokyo (Japan); Minami, Harufumi [Tokyo Metropolitan Agricultural Experiment Station, Tachikawa, Tokyo (Japan); Shikazono, Naoya; Tanaka, Atsushi; Watanabe, Hiroshi [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment

    2000-12-01

    We examined postembryonic effects after helium ion and gamma ray irradiation of an isolated whole flower (a flower with pedicel) of Brassica napus through a flower organ culture, and estimated the effects of irradiation on embryogenesis in sexual reproductive stages. The whole flowers were irradiated with 30 Gy of helium ions and gamma rays in the early globular embryo and/or torpedo embryo stages. The helium ion and gamma ray irradiation of early globular embryos caused some drastic malformations in the first true leaves. Those malformations were classified into four types: cup-shaped, funnel-shaped, shrunk and the other varied leaves. The types were observed in 40% of plants that developed first true leaves. Both cup-shaped and funnel-shaped types were observed in over 15%. On the other hand, the irradiation of gamma rays of torpedo embryos caused sectors lacking chlorophyll in first true leaves. (author)

  9. High-temperature helium-loop facility

    Tokarz, R.D.

    1981-09-01

    The high-temperature helium loop is a facility for materials testing in ultrapure helium gas at high temperatures. The closed loop system is capable of recirculating high-purity helium or helium with controlled impurities. The gas loop maximum operating conditions are as follows: 300 psi pressure, 500 lb/h flow rate, and 2100 0 F temperature. The two test sections can accept samples up to 3.5 in. diameter and 5 ft long. The gas loop is fully instrumented to continuously monitor all parameters of loop operation as well as helium impurities. The loop is fully automated to operate continuously and requires only a daily servicing by a qualified operator to replenish recorder charts and helium makeup gas. Because of its versatility and high degree of parameter control, the helium loop is applicable to many types of materials research. This report describes the test apparatus, operating parameters, peripheral systems, and instrumentation system. The experimental capabilities and test conand presents the results that have been obtained. The study has been conducted using a four-phase approach. The first phase develops the solution to the steady-state radon-diffusion equation in one-dimensieered barriers; disposal charge analysis; analysis of spent fuel policy implementation; spent f water. Field measurements and observations are reported for each site. Analytical data and field measurements are presented in tables and maps. Uranium concentrations in the sediments which were above detection limits ranged from 0.10 t 51.2 ppM. The mean of the logarithms of the uranium concentrations was 0.53. A group of high uranium concentrations occurs near the junctions of quadrangles AB, AC, BB, a 200 mK. In case 2), x-ray studies of isotopic phase separation in 3 He-- 4 He bcc solids were carried out by B. A. Fraass

  10. Microstructural observation on helium injected and creep ruptured JPCA

    Yamamoto, N.; Shiraishi, H.; Hishinuma, A.

    1986-01-01

    Detailed and quantitative TEM observation was performed on high temperature helium injected and creep ruptured JPCA to seek the prominent TiC distribution developed for suppression of helium embrittlement. Three different preinjection treatments were adopted for changing the TiC distribution. Considerable degradation in creep rupture strength by helium occurred in solution-annealed specimens, although there was much less effect of other treatments which included aging prior to injection. The concentration of helium at grain boundaries and the promotion of precipitation by helium during injection were responsible for the degradation. Therefore, the presence of TiC precipitates before helium introduction will help prevent degradation. On the other hand, the rupture elongation was reduced by helium after all treatments, although helium trapping by TiC precipitates in the matrix was successfully achieved. Consequently, the combined use of several methods may be necessary for further suppression of helium embrittlement. (orig.)

  11. Standard Guide for Simulation of Helium Effects in Irradiated Metals

    American Society for Testing and Materials. Philadelphia

    1996-01-01

    1.1 This guide provides advice for conducting experiments to investigate the effects of helium on the properties of metals where the technique for introducing the helium differs in some way from the actual mechanism of introduction of helium in service. Simulation techniques considered for introducing helium shall include charged particle implantation, exposure to α-emitting radioisotopes, and tritium decay techniques. Procedures for the analysis of helium content and helium distribution within the specimen are also recommended. 1.2 Two other methods for introducing helium into irradiated materials are not covered in this guide. They are the enhancement of helium production in nickel-bearing alloys by spectral tailoring in mixed-spectrum fission reactors, and isotopic tailoring in both fast and mixed-spectrum fission reactors. These techniques are described in Refs (1-5). Dual ion beam techniques (6) for simultaneously implanting helium and generating displacement damage are also not included here. This lat...

  12. Resistivity studies of interstitial helium mobility in niobium

    Chen, C.G.; Birnbaum, H.K.; Johnson, A.B. Jr.

    1979-01-01

    The mobility of interstitial helium in Nb and Nb-O alloys was studied in the temperature range of 10-383 K using resistivity measurements. The helium was introduced by radioactive decay of solute tritium (approximately 1 at%). At T < 100 K the resistivity increased due to conversion of tritium trapped at oxygen interstititals to helium. The formation of helium caused a very significant resistance increase at room temperature and above. The results suggest that helium is mobile at temperatures above 295 K and that the precipitation of large helium bubbles occurs along grain boundaries. The mobile helium species may either be single interstitials or small helium clusters. The activation enthalpy for the diffusion of the mobile helium species was estimated to be about 55 kJ/mol (0.66 eV). (Auth.)

  13. Quantum statistics and liquid helium 3 - helum 4 mixtures

    Cohen, E.G.D.

    1979-01-01

    The behaviour of liquid helium 3-helium 4 mixtures is considered from the point of view of manifestation of quantum statistics effects in macrophysics. The Boze=Einstein statistics is shown to be of great importance for understanding superfluid helium-4 properties whereas the Fermi-Dirac statistics is of importance for understanding helium-3 properties. Without taking into consideration the interaction between the helium atoms it is impossible to understand the basic properties of liquid helium 33 - helium 4 mixtures at constant pressure. Proposed is a simple model of the liquid helium 3-helium 4 mixture, namely the binary mixture consisting of solid spheres of two types subjecting to the Fermi-Dirac and Bose-Einstein statistics relatively. This model predicts correctly the most surprising peculiarities of phase diagrams of concentration dependence on temperature for helium solutions. In particular, the helium 4 Bose-Einstein statistics is responsible for the phase lamination of helium solutions at low temperatures. It starts in the peculiar critical point. The helium 4 Fermi-Dirac statistics results in incomplete phase lamination close to the absolute zero temperatures, that permits operation of a powerful cooling facility, namely refrigerating machine on helium solution

  14. The high-temperature helium test facility (HHV)

    Noack, G.; Weiskopf, H.

    1977-03-01

    The report describes the high-temperature helium test facility (HHV). Construction of this plant was started in 1972 by Messrs. BBC, Mannheim, on behalf of the Kernforschungsanlage Juelich. By the end of 1976, the construction work is in its last stage, so that the plant may start operation early in 1977. First of all, the cycle system and the arrangement of components are dealt with, followed by a discussion of individual components. Here, emphasis is laid on components typical for HHT systems, while conventional components are mentioned without further structural detail. The projected test programme for the HHV facility in phase IB of the HHT project is shortly dealt with. After this, the potential of this test facility with regard to the possible use of test components and to fluid- and thermodynamic boundary conditions is pointed out. With the unique potential the facility offers here, aspects of shortened service life at higher cycle temperatures do not remain disregarded. (orig./UA) [de

  15. Achievement report on contract research. Large-scale project - Results of 1st-phase research and development of MHD power generation system; Plant system no hyoka. Ogata project dai 1 ki MHD hatsuden system kenkyu kaihatsu seika hokokusho

    NONE

    1976-03-01

    Described in detail involving the results of component development, assessment, and the indication of problems are the power generation channel, superconductive magnets and a helium refrigeration and liquefaction unit, seeds collector, heat exchanger, combustor, etc. Described involving the result and effect of power generation system research and development and the indication of problems is the research on Mark V and Mark VI operation tests. Described in relation to thermal performance calculation, economic effectiveness calculation, and environmental conservation involving an MHD (magnetohydrodynamic) power plant are the combustion of heavy oil, combustion of natural gas, plant having a 1,000MW power generator as its base load, control of NOx and sulfur in MHD power generation, etc. As for planning for the next stage, the configuration of a 10MW MHD power generation plant, its equipment, construction cost, and preliminary element research, etc., are described. Furthermore, propositions are presented concerning future plans and the prospect of commercial MHD power generators, technological ripple effects due to MHD power generation research and development, and research and development in the future. (NEDO)

  16. Biomass Direct Liquefaction Options. TechnoEconomic and Life Cycle Assessment

    Tews, Iva J.; Zhu, Yunhua; Drennan, Corinne; Elliott, Douglas C.; Snowden-Swan, Lesley J.; Onarheim, Kristin; Solantausta, Yrjo; Beckman, David

    2014-07-31

    The purpose of this work was to assess the competitiveness of two biomass to transportation fuel processing routes, which were under development in Finland, the U.S. and elsewhere. Concepts included fast pyrolysis (FP), and hydrothermal liquefaction (HTL), both followed by hydrodeoxygenation, and final product refining. This work was carried out as a collaboration between VTT (Finland), and PNNL (USA). The public funding agents for the work were Tekes in Finland and the Bioenergy Technologies Office of the U.S. Department of Energy. The effort was proposed as an update of the earlier comparative technoeconomic assessment performed by the IEA Bioenergy Direct Biomass Liquefaction Task in the 1980s. New developments in HTL and the upgrading of the HTL biocrude product triggered the interest in reinvestigating this comparison of these biomass liquefaction processes. In addition, developments in FP bio-oil upgrading had provided additional definition of this process option, which could provide an interesting comparison.

  17. Activity and selectivity of three molybdenum catalysts for coal liquefaction reactions

    Curtis, C.W.; Pellegrino, J.L.

    The activity and selectivity of three different molybdenum catalysts for reactions occurring in coal liquefaction, specifically for hydrogenation (HYD), hydrodeoxygenation (HDO), hydrodenitrogenation (HDN), hydrodesulfurization (HDS), and hydrocracking (HYC), have been examined. The three molybdenum catalysts used were molybdenum napthenate, molybdenum on ..gamma..-alumina, and a precipitated, disordered MoS/sub 2/. Molybdenum naphthenate was most selective for HYD and HDN. All three catalysts exhibited approximately equal activity for HDS and HDO and little selectivity for HYC of alkyl bridge structures. The activity and selectivity of the three molybdenum catalysts for producing hydrocarbons and removing heteroatoms from coal during liquefaction were determined and compared. Molybdenum naphthenate was the most active catalyst for hydrocarbon production and removal of nitrogen- and oxygen-containing species during coal liquefaction. 31 refs., 4 figs., 7 tabs.

  18. Numerical analysis of stone columns in mitigating liquefaction effects in embankment fills

    Borghei, Z.; Soroush, A. [Amirkabir University of Technology, Tehran, (Iran, Islamic Republic of); Noorzad, A. [Power and Water University of Technology, Tehran, (Iran, Islamic Republic of)

    2010-07-01

    The traditional approach to liquefaction in embankment fills is to use in-situ densification. The use of stone columns offers the possibility of preventing liquefaction and associated settlements while reducing the cost and time required for treatment. This paper investigated the behaviour of stone columns using a numerical method. The study focused on a case study, a sand layer beneath two wall tanks, butane and propane NGL, located on Siri Island, Persian Gulf, Iran. Numerical analyses were carried out to evaluate the rate of excess pore pressure build-up in the improved ground. The numerical model results were compared to the simulation results from a centrifuge test for a uniform 19m-thick liquefiable sand layer. The numerical methodology was verified. The results showed that the stone columns can significantly increase the rate of pore pressure dissipation and reduce the settlement. It was found that the installation process densifies the surrounding soil, decreasing the liquefaction potential.

  19. Efficient direct coal liquefaction of a premium brown coal catalyzed by cobalt-promoted fumed oxides

    Trautmann, M.; Loewe, A.; Traa, Y. [Stuttgart Univ. (Germany). Inst. of Chemical Technology

    2013-11-01

    The search for alternatives in the fuel sector is an important technological challenge. An interim solution could be provided by direct coal liquefaction. Hydrogen economy and the lack of an efficient catalyst are the main obstacles for this process. We used a premium German brown coal with a high H/C molar ratio of 1.25 and nanostructured cobalt catalysts to improve the efficiency of direct coal liquefaction. We were able to recover and recycle the catalyst efficiently and reached good brown coal conversions and oil yields with single-stage coal liquefaction. The oil quality observed almost reached that of a conventional crude oil considering higher heating value (HHV), H/C molar ratio and aliphatic content. (orig.)

  20. Subcritical hydrothermal liquefaction of barley straw in fresh water and recycled aqueous phase

    Zhu, Zhe; Toor, Saqib; Rosendahl, Lasse

    2014-01-01

    This project focuses on the investigation of addition of aqueous phase in the production of biofuel from biomass through hydrothermal liquefaction (HTL) technology. Hydrothermal liquefaction is a wet thermal conversion process, which can convert all kinds of biomass to fuels. In this study, barley...... straw was first liquefied in fresh distilled water with the presence of K2CO3 catalyst at 300 C as the reference run. Afterwards, the aqueous phase which is obtained from liquefaction process in the previous run was recycled and used as the reaction medium from the second to the fourth run....... With the addition of recycling aqueous phase in HTL process, it is expected that the amount of the waste water and energy consumption can be reduced. The effect of water recirculation on product yield and properties was investigated in this study. The results showed that bio-oil yield was 34.85 wt% when the barley...