WorldWideScience

Sample records for heavy petroleum residues

  1. Production of petroleum bitumen by oxidation of heavy oil residue with sulfur

    Science.gov (United States)

    Tileuberdi, Ye.; Akkazyn, Ye. A.; Ongarbayev, Ye. K.; Imanbayev, Ye. I.; Mansurov, Z. A.

    2018-03-01

    In this paper production of bitumen adding elemental sulfur at oxidation of oil residue are investigated. The objects of research were distilled residue of Karazhanbas crude oil and elemental sulfur. These oil residue characterized by a low output of easy fractions and the high content of tar-asphaltene substances, therefore is the most comprehensible feedstock for producing bitumen. The sulfur is one of the oil product collected in oil extraction regions. Oxidation process of hydrocarbons carried out at temperatures from 180 up to 210 °С without addition of sulfur and with the addition of sulfur (5-10 wt. %) for 4 hours. At 200 °С oxidation of hydrocarbons with 5, 7 and 10 wt.% sulfur within 3-4 h allows receiving paving bitumen on the mark BND 200/300, BND 130/200, BN 90/130 and BN 70/30. Physical and mechanical characteristics of oxidation products with the addition of 5-7 wt. % sulfur corresponds to grade of paving bitumen BND 40/60. At the given temperature oxidized for 2.5-3 h, addition of 10 wt. % sulfur gave the products of oxidation describing on parameters of construction grades of bitumen (BN 90/10).

  2. A tiered analytical protocol for the characterization of heavy oil residues at petroleum-contaminated hazardous waste sites

    International Nuclear Information System (INIS)

    Pollard, S.J.T.; Kenefick, S.L.; Hrudey, S.E.; Fuhr, B.J.; Holloway, L.R.; Rawluk, M.

    1994-01-01

    The analysis of hydrocarbon-contaminated soils from abandoned refinery sites in Alberta, Canada is used to illustrate a tiered analytical approach to the characterization of complex hydrocarbon wastes. Soil extracts isolated from heavy oil- and creosote-contaminated sites were characterized by thin layer chromatography with flame ionization detection (TLC-FID), ultraviolet fluorescence, simulated distillation (GC-SIMDIS) and chemical ionization GC-MS analysis. The combined screening and detailed analytical methods provided information essential to remedial technology selection including the extent of contamination, the class composition of soil extracts, the distillation profile of component classes and the distribution of individual class components within various waste fractions. Residual contamination was characteristic of heavy, degraded oils, consistent with documented site operations and length of hydrocarbon exposure at the soil surface

  3. Use of ultrasound in petroleum residue upgradation

    Energy Technology Data Exchange (ETDEWEB)

    Sawarkar, A.N.; Pandit, A.B.; Samant, S.D.; Joshi, J.B. [Mumbai Univ., Mumbai (India). Inst. of Chemical Technology

    2009-06-15

    The importance of bottom-of-the barrel upgrading has increased in the current petroleum refining scenario because of the progressively heavier nature of crude oil. Heavy residues contain large concentrations of metals such as vanadium and nickel which foul catalysts and reduce the potential effect of residue fluidized catalytic cracking. This study showed that the cavitational energy induced by ultrasound be be successfully used to upgrade hydrocarbon mixtures. Conventional processes for the upgrading of residual feedstocks, such as thermal cracking and catalytic cracking, were carried out in the temperature range of 400-520 degrees C. Experiments were performed on 2 vacuum residues, Arabian mix vacuum residue (AMVR) and Bombay high vacuum residue (BHVR) and 1 Haldia asphalt (HA). These were subjected to acoustic cavitation for different reaction times from 15 to 120 minutes at ambient temperature and pressure. Two acoustic cavitation devices were compared, namely the ultrasonic bath and ultrasonic horn. In particular, this study compared the ability of these 2 devices to upgrade the petroleum residues to lighter, more value-added products. Different surfactants were used to examine the effect of ultrasound on upgrading the residue when emulsified in water. In order to better understand the reaction mechanism, a kinetic model was developed based on the constituents of the residue. The ultrasonic horn was found to be more effective in bringing about the upgrading than ultrasonic bath. The study also showed that the acoustic cavitation of the aqueous emulsified hydrocarbon mixture could reduce the asphaltenes content to a greater extent than the acoustic cavitation of non-emulsified hydrocarbon mixture. 20 refs., 11 tabs., 17 figs.

  4. Natural radioactivity in petroleum residues

    International Nuclear Information System (INIS)

    Gazineu, M.H.P.; Gazineu, M.H.P.; Hazin, C.A.; Hazin, C.A.

    2006-01-01

    The oil extraction and production industry generates several types of solid and liquid wastes. Scales, sludge and water are typical residues that can be found in such facilities and that can be contaminated with Naturally Occurring Radioactive Material (N.O.R.M.). As a result of oil processing, the natural radionuclides can be concentrated in such residues, forming the so called Technologically Enhanced Naturally Occurring Radioactive Material, or T.E.N.O.R.M.. Most of the radionuclides that appear in oil and gas streams belong to the 238 U and 232 Th natural series, besides 40 K. The present work was developed to determine the radionuclide content of scales and sludge generated during oil extraction and production operations. Emphasis was given to the quantification of 226 Ra, 228 Ra and 40 K since these radionuclides,are responsible for most of the external exposure in such facilities. Samples were taken from the P.E.T.R.O.B.R.A.S. unity in the State of Sergipe, in Northeastern Brazil. They were collected directly from the inner surface of water pipes and storage tanks, or from barrels stored in the waste storage area of the E and P unit. The activity concentrations for 226 Ra, 228 Ra and 40 K were determined by using an HP Ge gamma spectrometric system. The results showed concentrations ranging from 42.7 to 2,110.0 kBq/kg for 226 Ra, 40.5 to 1,550.0 kBq/kg for 228 Ra, and 20.6 to 186.6 kBq/kg for 40 K. The results highlight the importance of determining the activity concentration of those radionuclides in oil residues before deciding whether they should be stored or discarded to the environment. (authors)

  5. Process to hydroform heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Sinfelt, J.H.; Barnett, A.E.

    1977-02-17

    The invention concerns the hydroforming of heavy petrol. A particularly high degree of conversion of paraffins into aromatic substances is achieved. This leads to a a considerable increase of the octane number above 100. The hydroforming takes place by contacting the initial product with a catalyst in the presence of hydrogen. The temperature here is 427/sup 0/ to 566/sup 0/C. A mixture of 0.05-2 wt.% iridium, 0.5-2 wt.% gold, silver and copper serves as catalyst. It is coated on an oxidic carrier with a large surface, e.g. aluminium oxide with a surface of 50-300 m/sup 2//g. The larger the surface, the greater the reaction rate. The iridium acts as active catalyst, gold reduces the cracking activity of the catalyst and improves the product yield in the boiling range of benzine.

  6. Technological alternatives for the handling of high viscosity heavy crude oil and of petroleum residuals; Alternativas tecnologicas para el manejo de crudos pesados de alta viscosidad y residuales de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez S, Ramon; Peralta M, Maria Vita; Gonzalez Santalo, Jose M; Herrera V, J Ramon; Arriola M, Alejandro M; Manzanares P, Emilio; Romo M, Cesar A; Palacios L, Elvia M [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2006-07-01

    This work presents the technological capacity that, through the years, has been developed in emulsions of heavy oil in water preparations, as well as the potential application that this technology has in the electrical sector and the problem reduction during the extraction and handling of high viscosity heavy oils. Within this technological development it first appears the process for the formation of emulsions of residual petroleum within lots, followed by the preparation of emulsions in a continuous way within a laboratory model, and finally the production in greater scale in a pilot plant, including more and more adequate tense-actives for the formation of emulsions. Also experimental systems are presented to execute static stability and dynamic tests in different conditions, pumping tests for the handling of these emulsions and burning tests for their combustion. All of this with the purpose of consolidating the technology of residual petroleum emulsions as a profitable alternative that replaces the heavy fuel oil and to solve specific problems of the oil industry, among other benefits. [Spanish] Este trabajo exhibe la capacidad tecnologica que, a traves de los anos, se ha desarrollado en la preparacion de emulsiones de aceites pesados en agua; asi como el potencial de aplicacion que tiene dicha tecnologia en el sector electrico y la reduccion de problemas durante la extraccion y manejo de aceites pesados de alta viscosidad. Dentro de este desarrollo tecnologico figura primero el proceso para la formacion de emulsiones de residuales de petroleo dentro de lotes, seguido por la preparacion de emulsiones en continuo dentro de un laboratorio modelo, y finalmente la produccion a mayor escala en una planta piloto, incluyendo cada vez mas adecuados tenso-activos para la formacion de las emulsiones. Tambien se presentan sistemas experimentales para ejecutar pruebas de estabilidad estatica y dinamica en diferentes condiciones, pruebas de bombeo para el manejo de estas

  7. Interpreting residues of petroleum hydrocarbons in wildlife tissues

    International Nuclear Information System (INIS)

    Hall, R.J.; Coon, N.C.

    1988-08-01

    This report is the first publication in the field of environmental-contaminant effects on wildlife to tell the reader how to interpret the results of analytical chemical results. Specifically, the publication describes how to interpret residues of petroleum hydrocarbons in wildlife tissues. Pollutant oil residues in avian species are emphasized

  8. Study of sulfur and vanadium in heavy petroleum products

    Energy Technology Data Exchange (ETDEWEB)

    Novelli, J.M.

    1982-10-01

    Sulfur compounds in heavy oil fractions (>450/sup 0/C) are studied in the first part of this work. After chemical oxidation by metachloroperbenzoic acid to obtain sulfones, sulfur compounds are analyzed by infrared spectroscopy for their qualitative and quantitative repartition. The method can be applied for the study of sulfur containing molecules before and after structural modifications of petroleum fractions by any chemical refining processes. In a second part vanadium is characterized in asphalt by physicochemical and chemical methods. 80% of the vanadium in a Boscan asphalt is under the form of porphyrins. Different associations are evidenced in petroleum fractions and metalloporphyrins, but the liaison between the vanadyl group and heterocondensate from asphalts is the more frequent.

  9. Phase behaviour of heavy petroleum fractions in pure propane and n-butane and with methanol as co-solvent

    International Nuclear Information System (INIS)

    Canziani, D.; Ndiaye, P.M.; Franceschi, Elton; Corazza, Marcos L.; Vladimir Oliveira, J.

    2009-01-01

    This work reports phase equilibrium experimental results for heavy petroleum fractions in pure propane and n-butane as primary solvents and using methanol as co-solvent. Three kinds of oils were investigated from Marlim petroleum: a relatively light fraction coming from the first distillation of crude petroleum at atmospheric pressure (GOP - heavy gas oil of petroleum), the residue of such distillation (RAT) and the crude petroleum sample. Phase equilibrium measurements were performed in a high-pressure, variable-volume view cell, following the static synthetic method, over the temperature range of 323 K to 393 K, pressures up to 10 MPa and overall compositions of heavy component varying from 1 wt% to 40 wt%. Transition pressures for low methanol and oil concentrations were very close for GOP, RAT, and crude Marlim when using propane as the primary solvent. Close to propane critical temperature, two and three-phase transitions were observed for GOP and Marlim when methanol was increased. When n-butane was used as primary solvent, all transitions observed were of (vapour + liquid) type with transition pressure values smaller than those obtained for propane.

  10. Hydrogenation upgrading of heavy oil residues

    Energy Technology Data Exchange (ETDEWEB)

    Krichko, A.A.; Maloletnev, A.S.; Mazneva, O.A.; Galkina, N.I. [Fossil Fuel Inst., Moscow (Russian Federation). Hydrogenation and Gasification Dept.; Suvorov, U.P.; Khadjiev, S.N. [Inst. Oil and Chemical Synthesis, Moscow (Russian Federation). Hydrogenation of Heavy Residues Dept.

    1997-12-31

    At present time in the world there is no simple and effective technology at low pressure (<15-20 MPa) which could give the opportunity to use oil residues for distillate fractions production. In Russia a process for hydrogenation (up 6 MPa hydrogen pressure) of high boiling point (b.p. >520 C) oil products, including high S, V and Ni contents ones, into distillates, feedstock for catalytic cracking (b.p. 360-520 C) and metal concentrates. The main point of the new process is as follows: the water solution of catalytic additive, for which purpose water soluble metal salts of VI-VIII groups are used, is mixed with heavy oil residues, dispersed and then subjected to additional supercavitation in a special apparatus. (orig.)

  11. HDHPLUS/SHP : heavy residue hydroconversion technology

    Energy Technology Data Exchange (ETDEWEB)

    Morel, F. [Axens, Rueil Malmaison (France)

    2009-07-01

    This presentation described an integrated refinery process that achieves nearly full conversion of heavy and refractory residues into ultra high quality and ultra low sulphur transportation fuels with a yield great than 100 volume per cent. The Axens, IFP and Intevep/PDVSA Alliance combined the HDHPLUS vacuum residue slurry technology with Sequential Hydro Processing (SHP) of primary hydrocracked products. Both technologies have undergone extensive testing at a refinery in Puerto La Cruz (RPLC), Venezuela to begin production of 50,000 BPSD in 2012. The demonstration unit at Intevep has been used to investigate production of effluent for the downstream SHP processing. This paper also reviewed the SHP bench unit operations at IFP's Lyon research center in France and disclosed the final product yields and qualities. The test results have shown the expected RPLC deep conversion commercial unit performances and fully secure its design basis. tabs., figs.

  12. Radiation processing studies on residual fractions of Olowi petroleum crude oil

    International Nuclear Information System (INIS)

    Sarfo, A.K.

    2011-01-01

    Residual fuel oil is an inexpensive boiler fuel that can replace diesel in some industrial boilers. The viscous waxy nature of residual fuel oil makes it very difficult to use in industries where fuel storage tanks have no heating elements to keep the fuel at temperatures at which it would easily flow. Irradiation is currently being studied as a cost effective means of cracking heavy petroleum crude oil into lighter and more valuable products. Research has shown that irradiation can replace the conventional methods of cracking petroleum with economical benefits. Gamma radiation from a cobalt-60 source was applied to the residue obtained after refining crude oil in this research study, with the intention of causing a similar cracking phenomenon. The main objective of the study was to evaluate the possibility of using gamma radiation to reduce the viscosity of residual fractions of crude oil used as residual fuel oil. This was done by exposing samples of residual fuel oil in glass jars to 9 different doses of gamma radiation, at room temperature and an elevated temperature of 60 degrees Celsius to determine and quantify the effect of radiation on residual fuel oil obtained from the Tema Oil Refinery. The pour points of the irradiated samples were not affected by radiation doses up to 200 kGy while the changes in viscosity for irradiation at room temperature were not significant. Irradiation at 60 degrees Celsius induced a small but significant increase in viscosity at 1 kGy and 200 kGy absorbed doses of irradiation. Irradiation fuels were stable in relation to viscosity, density and pour point over a period of 20 days after exposure. The flash point of irradiated samples, however, decreased by 5.26, 10.53 and 11.34% for 30, 50 and 80 kGy absorbed doses of radiation respectively. Cumulative and continuous doses gave similar results for pour point, density, viscosity and flash point measurements up to 50 kGy. Comparative cost analysis of methods used in maintaining low

  13. Characterization of heavy crude oils and petroleum residues

    Energy Technology Data Exchange (ETDEWEB)

    Tissot, B.

    1984-01-01

    Proceedings of an international symposium held in Lyon in 1984, consisting of typescript versions of five plenary lectures and a large number of research papers in the areas of geochemical analysis, fractionation and characterization, and relations between structure and properties.

  14. Process from removing benzine, toluene, etc. , from petroleum residues, coal tar, and shale tar, etc

    Energy Technology Data Exchange (ETDEWEB)

    Hlawaty, F

    1888-08-11

    A process is described for the preparation of ligroin and its homologs as well as naphthalene and anthracene consisting in leading superheated water vapor into a mixture of petroleum residues (or mineral coal tar, etc.) heated to about 400/sup 0/C with cellulosic substances as sage shreds, sea grass, or straw, with addition of caustic alkali.

  15. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    None

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt. The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degrees} C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3--5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  16. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Carbognani, L.; Hazos, M.; Sanchez, V. (INTEVEP, Filial de Petroleos de Venezuela, SA, Caracas (Venezuela)); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  17. Methanogenic degradation of petroleum hydrocarbons in subsurface environments remediation, heavy oil formation, and energy recovery.

    Science.gov (United States)

    Gray, N D; Sherry, A; Hubert, C; Dolfing, J; Head, I M

    2010-01-01

    Hydrocarbons are common constituents of surface, shallow, and deep-subsurface environments. Under anaerobic conditions, hydrocarbons can be degraded to methane by methanogenic microbial consortia. This degradation process is widespread in the geosphere. In comparison with other anaerobic processes, methanogenic hydrocarbon degradation is more sustainable over geological time scales because replenishment of an exogenous electron acceptor is not required. As a consequence, this process has been responsible for the formation of the world's vast deposits of heavy oil, which far exceed conventional oil assets such as those found in the Middle East. Methanogenic degradation is also a potentially important component of attenuation in hydrocarbon contamination plumes. Studies of the organisms, syntrophic partnerships, mechanisms, and geochemical signatures associated with methanogenic hydrocarbon degradation have identified common themes and diagnostic markers for this process in the subsurface. These studies have also identified the potential to engineer methanogenic processes to enhance the recovery of energy assets as biogenic methane from residual oils stranded in petroleum systems. Copyright 2010 Elsevier Inc. All rights reserved.

  18. Petroleum

    International Nuclear Information System (INIS)

    Anon.

    2000-01-01

    Here are briefly summarized 1)the OPEC decisions and their consequences concerning the production of petroleum in the world 2)some news about the petroleum industry in Chad and in Iraq 3)some news about the new pipelines constructed or to be constructed in the world 4)some news about the LPG industry (start of a LPG extraction unit in Argentina, legislation in France for LPG vehicles) 4)and some news about the petroleum distribution in France. (O.M.)

  19. Petroleum

    International Nuclear Information System (INIS)

    Anon.

    2000-01-01

    Here are gathered the results of the year 1999 concerning the petroleum industry in France ('UFIP' data), the market quotations of crude oil, the prices of fuels in France and in Portugal and some news about the petroleum industry in Algeria (privatization, exploration-offshore, repurchase), in Iraq (exports, contracts with foreign companies), in Russian Federation (petroleum pipelines and oil ports constructions) and in Chad (production sharing, offshore sites discoveries). (O.M.)

  20. The conversion of waste plastics/petroleum residue mixtures to transportation fuels

    International Nuclear Information System (INIS)

    Ali, M.F.; Siddiqui, M.N.

    2005-01-01

    Plastics have become the material of choice in the modern world and its applications in the industrial field are continually increasing. Presently the plastics are manufactured for various uses such as: consumer packaging, wires, pipes, containers, bottles, appliances, electrical/electronic parts, computers and automotive parts. Most of he post consumer, plastic products are discarded and end up as mixed plastic municipal waste. The disposal of his waste has become a major social concern. Mixed plastic waste (MPW) recycling is still very much in its infancy. Approximately 20 million tons of plastic waste is generated in the United States of America, while about 15 million tons is generated throughout the Europe. With existing recycle efforts, only 7% of the MPW are recycled to produce low-grade plastic products such as plastic sacks, pipes, plastic fencing, and garden furniture. The current plastic reclamation technology options are generally grouped into the following four types: (i) Primary: The processing of plastic for use comparable to the original application. (ii) Secondary: The processing of plastics waste into new products with a lower quality level. (iii) Tertiary: The chemical or thermal processing of plastic waste to their basic hydrocarbon feedstock. The resulting raw materials are then reprocessed into plastic material or other products of the oil refining process. (iv) Quaternary: The incineration of plastics waste to recover energy. This paper deals exclusively with tertiary recycling by pyrolysis and catalytic cracking of plastics waste alone and by coprocessing with petroleum residue or heavy oils to fuels and petrochemical feedstock for further processing in existing refinery and petrochemical units. (author)

  1. Combined strategy for the precipitation of heavy metals and biodegradation of petroleum in industrial wastewaters

    International Nuclear Information System (INIS)

    Perez, R.M.; Cabrera, G.; Gomez, J.M.; Abalos, A.; Cantero, D.

    2010-01-01

    The precipitation of chromium(III), copper(II), manganese(II) and zinc(II) by biogenic hydrogen sulfide generated by sulfate-reducing bacteria, Desulfovibrio sp., and the degradation of total petroleum hydrocarbons (TPH) in the presence of heavy metal by Pseudomonas aeruginosa AT18 have been carried out. An anaerobic stirred tank reactor was used to generate hydrogen sulfide with Desulfovibrio sp. culture and the precipitation of more than 95% of each metal was achieved in 24 h (metal solutions contained: 60, 49, 50 and 80 mg L -1 of chromium, copper, manganese and zinc sulfates). A stirred tank reactor with P. aeruginosa AT18, in the presence of the heavy metal solution and 2% (v/v) of petroleum, led to the degradation of 60% of the total petroleum hydrocarbons and the removal of Cr(III) 99%, Cu(II) 93%, Zn(II) 46% and Mn(II) 88% in the medium through biosorption phenomena. These results enabled the development of an integrated system in which the two processes were combined. The overall aim of the study was achieved, with 84% of TPH degraded and all of the metals completely removed. Work is currently underway aimed at improving this system (decrease in operation time, culture of P. aeruginosa in anaerobic conditions) in an effort to apply this process in the bioremediation of natural media contaminated with heavy metals and petroleum.

  2. Efficiency of lipopeptide biosurfactants in removal of petroleum hydrocarbons and heavy metals from contaminated soil.

    Science.gov (United States)

    Singh, Anil Kumar; Cameotra, Swaranjit Singh

    2013-10-01

    This study describes the potential application of lipopeptide biosurfactants in removal of petroleum hydrocarbons and heavy metals from the soil samples collected from industrial dumping site. High concentrations of heavy metals (like iron, lead, nickel, cadmium, copper, cobalt and zinc) and petroleum hydrocarbons were present in the contaminated soil samples. Lipopeptide biosurfactant, consisting of surfactin and fengycin was obtained from Bacillus subtilis A21. Soil washing with biosurfactant solution removed significant amount of petroleum hydrocarbon (64.5 %) and metals namely cadmium (44.2 %), cobalt (35.4 %), lead (40.3 %), nickel (32.2 %), copper (26.2 %) and zinc (32.07 %). Parameters like surfactant concentration, temperature, agitation condition and pH of the washing solution influenced the pollutant removing ability of biosurfactant mixture. Biosurfactant exhibited substantial hydrocarbon solubility above its critical micelle concentration. During washing, 50 % of biosurfactant was sorbed to the soil particles decreasing effective concentration during washing process. Biosurfactant washed soil exhibited 100 % mustard seed germination contradictory to water washed soil where no germination was observed. The results indicate that the soil washing with mixture of lipopeptide biosurfactants at concentrations above its critical micelle concentration can be an efficient and environment friendly approach for removing pollutants (petroleum hydrocarbon and heavy metals) from contaminated soil.

  3. AN ALTERNATIVE APPROACH TO THE USE OF HEAVY OIL RESIDUE

    Directory of Open Access Journals (Sweden)

    Eugene Dashut

    2013-01-01

    Full Text Available We consider an alternative approach to the existing oil refining, in which instead of a single priority that emerged in the traditional approach, we consider two: get the light component and a heavy residue used for the production of new construction materials.

  4. Tolerance of Four Tropical Tree Species to Heavy Petroleum Contamination

    NARCIS (Netherlands)

    Perez-Hernandez, I.; Ochoa-Gaona, S.; Schroeder, R.H.A.; Rivera-Cruz, M.C.; Geissen, V.

    2013-01-01

    Four species of trees were selected to evaluate the tolerance to heavy crude oil contamination by means of a tolerance index integrating germination, height, biomass and survival as variables. Fresh seeds to Cedrela odorata (tropical cedar), Haematoxylum campechianum (tinto bush), Swietenia

  5. Radiation method of sulfide compound transformation in petroleum products

    International Nuclear Information System (INIS)

    Nadirov, N.K.; Zajkina, R.F.; Zajkin, Yu.A.; Mamonova, T.B.; Bakirova, S.F.

    1997-01-01

    Processes of sulphuric compounds transformation for petroleum and heavy residuals under radiation and thermal treatment action are studied. It is shown that sulphuric compounds are concentrated in heavy fractions as a result of radiation processing. Heavy petroleum products irradiation provokes considerable decrease in the content of mercaptans, disulphides and sulphides, which transfer to sulphoxides and sulphones appearing during radiation-induced oxidation process. (author)

  6. Levels of Petroleum Hydrocarbons and some Heavy Metals in ...

    African Journals Online (AJOL)

    Michael Horsfall

    has outlets to the Atlantic Ocean. The river which supports major commercial ... acidification. Oils and solids or viscous grease present were separated from liquid samples by filtration. After extraction, the residue after solvent evaporation was weighed to determine the oil and grease content. Compounds volatilized at or ...

  7. Heavy residues from very mass asymmetric heavy ion reactions

    International Nuclear Information System (INIS)

    Hanold, K.A.

    1994-08-01

    The isotopic production cross sections and momenta of all residues with nuclear charge (Z) greater than 39 from the reaction of 26, 40, and 50 MeV/nucleon 129 Xe + Be, C, and Al were measured. The isotopic cross sections, the momentum distribution for each isotope, and the cross section as a function of nuclear charge and momentum are presented here. The new cross sections are consistent with previous measurements of the cross sections from similar reaction systems. The shape of the cross section distribution, when considered as a function of Z and velocity, was found to be qualitatively consistent with that expected from an incomplete fusion reaction mechanism. An incomplete fusion model coupled to a statistical decay model is able to reproduce many features of these reactions: the shapes of the elemental cross section distributions, the emission velocity distributions for the intermediate mass fragments, and the Z versus velocity distributions. This model gives a less satisfactory prediction of the momentum distribution for each isotope. A very different model based on the Boltzman-Nordheim-Vlasov equation and which was also coupled to a statistical decay model reproduces many features of these reactions: the shapes of the elemental cross section distributions, the intermediate mass fragment emission velocity distributions, and the Z versus momentum distributions. Both model calculations over-estimate the average mass for each element by two mass units and underestimate the isotopic and isobaric widths of the experimental distributions. It is shown that the predicted average mass for each element can be brought into agreement with the data by small, but systematic, variation of the particle emission barriers used in the statistical model. The predicted isotopic and isobaric widths of the cross section distributions can not be brought into agreement with the experimental data using reasonable parameters for the statistical model

  8. Petroleum.

    Science.gov (United States)

    McManus, T. R.; And Others

    1989-01-01

    This review of petroleum covers: crude oil; fuels, gaseous and liquid; lubricants, oils, and greases; asphalts, bitumens, tars, and pitches; hydrocarbons; physical properties; metals in oil; nonmetallic elements and heterocompounds; and analytical methods and apparatus. (MVL)

  9. Extra heavy oil and refinery residues upgrading through Eni Slurry Technology : first EST commercial unit

    Energy Technology Data Exchange (ETDEWEB)

    Rispoli, G.; Sanfilippo, D.; Amoroso, A [Eni S.p.A., Rome (Italy)

    2009-07-01

    The production of heavy crude oils is projected to continue to grow in the upstream oil industry given that large reserves of unconventional extra heavy crude and bitumen exist in several geographic areas including Canada and Venezuela. As reserves of conventional crude oil continue to decline, these unconventional feedstocks are becoming an opportunity to pursue, but they require effective technologies for upgrading and meeting the growing demand for light and middle distillate fuels. This paper described the proprietary technology that offers a solution to upstream and downstream oil producers for bottom-of-the-barrel upgrading. En i Slurry Technology (EST) is constructing an industrial plant in its Sannazzaro refinery in Italy. The plant is designed to convert 23,000 BPSD of vacuum residue into high quality diesel and other valuable refinery streams such as liquefied petroleum gas, naphtha and jet fuel. EST is an H-addition process characterized by the use of a special homogeneous isothermal intrinsically safe reactor, and of a nano-dispersed non-ageing catalyst. EST converts more than 98 per cent of any type of residues to about 110 per cent volume of light products and distillates or extra heavy oils to high quality bottomless SCO. In typical performance, HDS is greater than 85 per cent, HDM greater than 99 per cent and HDCCR greater than 97 per cent. EST also achieves the target of zero fuel oil - zero coke. 12 refs., 4 tabs., 5 figs.

  10. Evaluation of AISI 316L stainless steel welded plates in heavy petroleum environment

    International Nuclear Information System (INIS)

    Carvalho Silva, Cleiton; Pereira Farias, Jesualdo; Batista de Sant'Ana, Hosiberto

    2009-01-01

    This work presents the study done on the effect of welding heating cycle on AISI 316L austenitic stainless steel corrosion resistance in a medium containing Brazilian heavy petroleum. AISI 316L stainless steel plates were welded using three levels of welding heat input. Thermal treatments were carried out at two levels of temperatures (200 and 300 deg. C). The period of treatment in all the trials was 30 h. Scanning electronic microscopy (SEM) and analysis of X-rays dispersive energy (EDX) were used to characterize the samples. Weight loss was evaluated to determine the corrosion rate. The results show that welding heating cycle is sufficient to cause susceptibility to corrosion caused by heavy petroleum to the heat affected zone (HAZ) of the AISI 316L austenitic stainless steel

  11. Petroleum residues degradation in laboratory-scale by rhizosphere bacteria isolated from the mangrove ecosystem

    Science.gov (United States)

    Rinanti, A.; Nainggolan, I. J.

    2018-01-01

    This research is about petroleum bioremediation experiment to obtain bacterial isolate from mangrove ecosystem which potentially degrade petroleum. It was conducted in an Erlenmeyer batch system filled with growth medium of Stone Mineral Salt Solution (SMSS) plus petroleum residue, placed in an incubator shaker with a rotation speed of 120 rpm, temperature 3000C, for 14 research days. Indigenous bacteria that have been isolated and identified from the roots of mangrove plants are Ochrobactrum anthropi and Bacillus sp., Ralstonia pickettii and Bacillus circulans. Those bacteriain both monoculture and consortium form (mixed culture) are incorporated into erlenmeyer as remediator agents. All bacteria can utilize hydrocarbon compounds, but Ralstonia pickettii and Bacillus circulans reached exponential phase faster with more cell count than other bacteria. Compared to single cultures, petroleum degradation by a bacterial consortium provides a higher TPH reduction efficiency, i.e. at 5%, 10%, and 15% of initial TPH of 94.4%, 72%, and 80.3%, respectively. This study proved that all bacteria could optimize hydrocarbon compounds up to 15% TPH load.

  12. Treatment of heavy hydrocarbons, such as petroleum, shale oil, etc

    Energy Technology Data Exchange (ETDEWEB)

    Mercurio, M

    1939-02-04

    A process is described for treating heavy hydrocarbons in two operations: The first (operation) consisting of distilling in contact with neutral metals such as iron, copper, nickel, etc., or even stones, according to a known method, without pressure or with only a slight pressure or also by conducting the vapors into a receiver containing the materials mentioned, without pressure or with only a slight pressure, and causing condensation in one or the other ways for cooling by means of a submerged spiral; the second operation consisting in submitting the hydrocarbons recovered from the first operation, or otherwise, to the action of oxygen or ozone for recovering them from the carbon, purifying, desulfurizing, and rendering them inodorous, all these matters constituting the novelty of the invention.

  13. Removal and recovery of heavy metals of residual water industrial

    International Nuclear Information System (INIS)

    Gil P, Edison

    1999-01-01

    On the next work the state of the art about the different methods and technologies for the present removal and recovery of heavy metals for the de-contamination and control of industrial wastewater is presented. Further more, it is introduce a removal alternative for chromium (III) and chromium (V I) using a solid waste material as an adsorbent, obtaining successful results which makes this proposal circumscribe into the clean technology program and residues bag

  14. Physicochemical determinations of petroleum, heavy fuel derivative and combustion nanoparticles

    International Nuclear Information System (INIS)

    Frias Bullain, Jorge; Padron Rodriguez, M.; Perez Barcala, B.; Lopez Guerra, S.

    2016-01-01

    In the investigation, a crude from Cuban Northern Heavy Oil Belt and its fuel oil fraction was characterized by chemical and physical techniques. Subsequent to the characterization of the derivative, MSI gas analyzer was performed, to identify and quantify concentrations of chemical species, in correspondence with EPA (2007) for external sources. Total suspended particles collected in filter holder were identified using the gravimetric method (ISO 9096). With the intention of knowing the magnitude of polycyclic aromatic hydrocarbons reported in literature were chosen the higher and lower molecular mass and measured on the basis of its polar covalent radii. Total aromatic hydrocarbons were identified using activated charcoal with subsequent elution with nhexane for analysis by ultraviolet spectroscopy in a Genesys 10 UV spectrophotometer. Environmental pollution control in the oil sector, is evaluated in three states. The particles in the states mentioned above, whose dimensions are between (1-100) x10-9 meters are called nanoparticles. Nanotechnology currently offers firm steps in the development of different nanoparticles, which are applied directly to the mineralogical industry. Contributions stand out sharply operations: exploration, drilling and refining oil. (Author)

  15. Thermal and catalytic decomposition behavior of PVC mixed plastic waste with petroleum residue

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Mohammad Farhat; Siddiqui, Mohammad Nahid [Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia)

    2005-08-15

    The pyrolysis and hydropyrolysis of PVC mixed plastic waste alone and with petroleum residue was carried out at 150 and 350{sup o}C under N{sub 2} gas and at 430{sup o}C under 6.5MPa H{sub 2} gas pressure. The behavior of plastic waste during thermal and catalytic decomposition has also been studied in single- and two-stage reaction processes. In the individual pyrolysis process, both the petroleum residue and polystyrene (PS) undergo more than 90% conversion to liquid and gaseous products, whereas low-density polyethylene (LDPE) and high-density polyethylene (HDPE) yielded lower conversions products, and polypropylene (PP) and polyvinyl chloride (PVC) afforded somewhere a moderate to high conversion products. In a single-stage pyrolysis reaction, PVC was processed with petroleum residue at 150 and 430{sup o}C, under N{sub 2} gas for 1h at each temperature in a glass reactor. The model PVC and waste PVC showed slight variations in the products distribution obtained from the glass reactor. In two-stage process, model PVC, vacuum gas oil (VGO) and a number of different catalysts were used in a stainless steel autoclave micro tubular reactor at 350{sup o}C under the stream of N{sub 2} gas for 1h and at 430{sup o}C under 950psi (6.5MPa) H{sub 2} pressure for the duration of 2h. Significantly, different products distributions were obtained. Among the catalysts used, fluid catalytic cracking (FCC) and hydrocracking catalysts (HC-1) were most effective in producing liquid fuel (hexane soluble) materials. The study shows that the catalytic coprocessing of PVC with VGO is a feasible process by which PVC and VGO materials can be converted into transportation fuels.

  16. [Compositions and residual properties of petroleum hydrocarbon in contaminated soil of the oilfields].

    Science.gov (United States)

    Hu, Di; Li, Chuan; Dong, Qian-Qian; Li, Li-Ming; Li, Guang-He

    2014-01-01

    The aims of this study were to determine the compositions and residual properties of petroleum hydrocarbon in soil, as well as to identify the source and weathering degree of the pollution. A total of 5 producing wells in Gudao and Hekou oil producing region of Shengli oilfields were analyzed. More than 50 individual target compounds including straight-and branched-chain alkanes( n-alkanes, pristine and phytane) and polycyclic aromatic hydrocarbons (PAHs) in soil samples and crude oil were determined by gas chromatography-mass spectrometry (GC-MS). The percentages of chain alkanes and PAHs in total solvent extractable matters(TSEM) of soil samples were both much lower than those in the crude oil samples. The compositions of petroleum hydrocarbon in soil samples differed from those in crude oil, which indicated the n-alkanes with carbon numbers contaminated soils, the relationship between the index and petroleum hydrocarbon compounds was analyzed using principal component analysis (PCA). The results showed that the n-alkanes with carbon numbers > 33 and the PAHs with rings between 3 and 5 were much harder to degrade. PCA of 4 indexes for source identification revealed more than 50% of the soil samples were polluted by crude oil, which needs more attention during remediation.

  17. Petroleum

    International Nuclear Information System (INIS)

    Chautard, S.

    2008-01-01

    While petroleum has become an indispensable product in our everyday life, it is more and more question of an oil shortage. This book makes a status of the real situation. Starting from the industrial revolution and the history of oil exploitation, it explains the main present day stakes: the depletion of reserves, the environmental aspects and the search for alternative energy solutions. (J.S.)

  18. Petroleum residue upgrading with dispersed catalysts: Part 2. Effect of operating conditions

    Energy Technology Data Exchange (ETDEWEB)

    Panariti, N.; Del Bianco, A.; Del Piero, G. [ENITECNOLOGIE S.p.A, Via Maritano 26, 20097 San Donato Mil (Italy); Marchionna, M. [SNAMPROGETTI S.p.A, Via Maritano 26, 20097 San Donato Mil (Italy); Carniti, P. [Universita degli Studi di Milano, Dip. Chimica Fisica ed Elettrochimica, Via Celoria 20, Milan (Italy)

    2000-12-04

    The hydrotreatment of a petroleum residue in the presence of dispersed molybdenite was carried out within a wide range of operating conditions and catalyst loading. The effect of reaction severity as well as of molybdenum concentration on product distribution and quality was studied. Based on the experimental results, a simplified reaction scheme was proposed. The hydroprocessing of the residue was described in terms of the competition between two reactions: the direct conversion of the feedstock to distillate and coke, and the catalytic hydrogenation. Compared to thermal conditions, the presence of dispersed molybdenite controls very well coke formation; however, a trend of increasing formation of solids was observed at high catalyst concentrations. The overall upgrading of the feedstock requires significant amounts of molybdenum as well as relatively high hydrogen pressure.

  19. Will Venezuelan extra-heavy oil be a significant source of petroleum in the next decades?

    International Nuclear Information System (INIS)

    Sena, Marcelo Fonseca Monteiro de; Rosa, Luiz Pinguelli; Szklo, Alexandre

    2013-01-01

    Unconventional oil resources are needed to complement petroleum supply in the next decades. However, given the restrictions that pertain to the production of these resources, this article evaluates the availability of Venezuelan unconventional oil for helping meet the future worldwide petroleum demand. Venezuela has the world's second-largest oil reserves, but the majority of it is unconventional extra-heavy oil from the Orinoco Oil Belt. The perspective of Venezuelan production, the ways in which PDVSA, the state oil company, will raise funds for planned investments and the future oil price predictions are used to assess Venezuela's ability to serve as a source of unconventional oil in the coming years. Findings indicate that Venezuelan crude oil will be increasingly able to provide part of the marginal petroleum supply at a level predicted in global scenarios but short of that predicted by the country's government. Operational difficulties and the effort to raise financial resources for the oil production in the Belt require urgency in overcoming difficulties. As conventional production in Venezuela will stabilise in the coming years and the country is dependent on oil production, Venezuela will rely on extra-heavy oil extraction to ensure increased oil production and the stabilisation of internal accounts. - Highlights: • We analyse the future unconventional oil production capacity of Venezuela. • The study is based on operational capacity, investments capacity and future prices. • The study indicates a production shorter than that predicted by the Venezuelan government. • Venezuela can provide part of the marginal petroleum supply in the coming years

  20. Heavy-metal removal from petroleum oily sludge using lemon- scented geraniums[General Conference

    Energy Technology Data Exchange (ETDEWEB)

    Badawieh, A.; Elektorowicz, M. [Concordia Univ., Montreal, PQ (Canada). Dept. of Building, Civil and Environmental Engineering

    2006-07-01

    Finding an acceptable method to manage oily sludge generated during petroleum processes is one of the challenges currently facing the petroleum industry. This study investigated the response of plants to heavy-metal removal from oily sludge to determine the feasibility of using phytoremediation technologies as a treatment method for oily sludge. In particular, scented geraniums (Pelargonium sp. Frensham) have shown a strong capability to survive harsh conditions such as poor soil, high/low temperatures, high heavy-metal concentrations and low water content. In response to this observation, this feasibility study placed scented geraniums in a series of pots containing oily sludge where heavy-metal concentrations were artificially increased up to 2000 ppm. Plants were grown in two systems over a period of 50 days. The first system included oily sludge and soil while the second system included oily sludge, soil and compost. The study revealed that the scented geraniums accumulated up to 1600 mg, 1000 mg, and 1200 mg, of cadmium, nickel and vanadium respectively per 1 kg of the plant's dry weight. The results suggest that phytoremediation technology may be a potential method for successfully treating or pretreating oily sludge in the field.

  1. Remediation of soil co-contaminated with petroleum and heavy metals by the integration of electrokinetics and biostimulation.

    Science.gov (United States)

    Dong, Zhi-Yong; Huang, Wen-Hui; Xing, Ding-Feng; Zhang, Hong-Feng

    2013-09-15

    Successful remediation of soil co-contaminated with high levels of organics and heavy metals is a challenging task, because that metal pollutants in soil can partially or completely suppress normal heterotrophic microbial activity and thus hamper biodegradation of organics. In this study, the benefits of integrating electrokinetic (EK) remediation with biodegradation for decontaminating soil co-contaminated with crude oil and Pb were evaluated in laboratory-scale experiments lasting for 30 days. The treated soil contained 12,500 mg/kg of total petroleum hydrocarbons (TPH) and 450 mg/kg Pb. The amendments of EDTA and Tween 80, together with a regular refreshing of electrolyte showed the best performance to remediate this contaminated soil. An important function of EDTA-enhanced EK treatment was to eliminate heavy metal toxicity from the soil, thus activating microbial degradation of oil. Although Tween 80 reduced current, it could serve as a second substrate for enhancing microbial growth and biodegradation. It was found that oil biodegradation degree and microbial numbers increased toward the anode and cathode. Microbial metabolism was found to be beneficial to metal release from the soil matrix. Under the optimum conditions, the soil Pb and TPH removal percentages after 30 days of running reached 81.7% and 88.3%, respectively. After treatment, both the residual soil Pb and TPH concentrations met the requirement of the Chinese soil environmental quality standards. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. Heavy residue properties in intermediate energy nuclear collisions with gold

    International Nuclear Information System (INIS)

    Aleklett, K.; Sihver, L.; Liljenzin, J.O.; Seaborg, G.T.

    1990-10-01

    We have measured the target fragment production cross sections and angular distributions for the interaction of 32, 44 and 93 MeV/nucleon argon, 35 and 43 MeV/nucleon krypton with gold. The fragment isobaric yield distributions, moving frame angular distributions and velocities have been deduced from these data. This fission cross section decreases with increasing projectile energy and the heavy residue cross section increases. The ratio v parallel /v cn increases approximately linearly with mass removed from the target. 21 refs., 8 figs

  3. Hydrogen Solubility in Heavy Undefined Petroleum Fractions Using Group Contributions Methods

    Directory of Open Access Journals (Sweden)

    Aguilar-Cisneros Humberto

    2017-01-01

    Full Text Available Hydrogen solubility in heavy undefined petroleum fractions is estimated by taking as starting point a method of characterization based on functional groups [ Carreón-Calderón et al. (2012 Ind. Eng. Chem. Res. 51, 14188-14198 ]. Such method provides properties entering into equations of states and molecular pseudostructures formed by non-integer numbers of functional groups. Using Vapor-Liquid Equilibria (VLE data from binary mixtures of known compounds, interaction parameters between hydrogen and the calculated functional groups were estimated. Besides, the incorporation of the hydrogen-carbon ratio of the undefined petroleum fractions into the method allows the corresponding hydrogen solubility to be properly estimated. This procedure was tested with seven undefined petroleum fractions from 27 to 6 API over wide ranges of pressure and temperature (323.15 to 623.15 K. The results seem to be in good agreement with experimental data (overall Relative Average Deviation, RAD < 15%.

  4. Petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Lugg, W G

    1967-07-01

    This discussion of the Canadian petroleum industry for the year 1966 includes production statistics and operating procedures, reserve estimates, exploration and development, transportation, refining, and marketing. Most sectors of the Canadian industry had an excellent year in 1966, featured by continued exploration and development successes in the Rainbow Lake-Zama Lake region of northwestern Alberta and a record value of production that exceeded $900 million for all liquid hydrocarbons. Production of crude oil and natural gas liquids exceeded one million bopd. Crude oil producers supplied 58% of the total crude oil requirements for Canadian refineries. Oil reserves increased due primarily to the application of secondary recovery and the discovery of new reserves. Total pipeline construction decreased, and there was a small increase in refinery capacity.

  5. Effects of humic acid on phytodegradation of petroleum hydrocarbons in soil simultaneously contaminated with heavy metals

    Institute of Scientific and Technical Information of China (English)

    Soyoung Park; Ki Seob Kim; Jeong-Tae Kim; Daeseok Kang; Kijune Sung

    2011-01-01

    The use of humic acid (HA) to enhance the efficiency of phytodegradation of petroleum hydrocarbons in soil contaminated with diesel fuel was evaluated in this study.A sample of soil was artificially contaminated with commercially available diesel fuel to an initial total petroleum hydrocarbons (TPH) concentration of 2300 mg/kg and four heavy metals with concentrations of 400 mg/kg for Pb,200 mg/kg for Cu,12 mg/kg for Cd,and 160 mg/kg for Ni.Three plant species,Brassica campestris,Festuca arundinacea,and Helianthus annuus,were selected for the phytodegradation experiment.Percentage degradation of TPH in the soil in a control pot supplemented with HA increased to 45% from 30% without HA.The addition of HA resulted in an increases in the removal of TPH from the soil in pots planted with B.campestris,F.arundinacea,and H.annuus,enhancing percentage degradation to 86%,64%,and 85% from 45%,54%,and 66%,respectively.The effect of HA was also observed in the degradation of n-alkanes within 30 days.The rates of removal of n-alkanes in soil planted with B.campestris and H.annuus were high for n-alkanes in the range of C11-C28.A dynamic increase in dehydrogenase activity was observed during the last 15 days of a 30-day experimental period in all the pots amended with HA.The enhanced biodegradation performance for TPHs observed might be due to an increase in microbial activities and bioavailable TPH in soils caused by combined effects of plants and HA.The results suggested that HA could act as an enhancing agent for phytodegradation of petroleum hydrocarbons in soil contaminated with diesel fuel and heavy metals.

  6. Evaluation of phytoremediation of petroleum hydrocarbon and heavy metals with using Catharanthus roseus

    Directory of Open Access Journals (Sweden)

    Mehri Askary Mehrabadi

    2014-08-01

    Full Text Available Crude oil pollution is an inevitable worldwide phenomenon in oil producing and consuming areas that stems from human error, accidental discharge and other sources. The aim of this study was to evaluate the phytoremediation potential of vinca in petroleum-polluted soil. The experiment was laid out as a completely randomized design in 3 replications with different concentrations of crude oil (0, 0.5, 1, 2, 3 and 4 % V/W in pot planting stage. At the end of the 70-day period, soil samples were analyzed for total hydrocarbons removal. Contents of pb, zn and Ni were measured by atomic absorption from the soils and the leaves. Statistical analysis of data were performed on the basis of duncan’s test and by using of SPSS16 software. In concentrations higher than 3 % no growth was observed. The growth parameters such as stem length, stem fresh and dry matter decreased progressively from 0.5-3 % crude oil in soil. The results showed heavy metal accumulation in plant leaves and reduction of them in the soil. Heavy metals containing zinc, lead and nickel in plant increased in different concentration of crude oil. Total hydrocarbons and heavy metals containing zinc, lead and nickel reduced were in planted contaminated soil. This study showed that Periwinkle was able to grow and survive in low concentrations of oil and reduced pollutants in the soil. Based upon these results, Catharanthus roseus can be used as phytoremediator of petroleum-contaminated soil in low concentrations.

  7. Assessment of heavy metal residues in water, fish tissue and human ...

    African Journals Online (AJOL)

    MICHAEL HORSFALL

    ABSTRACT: Residual levels of lead, chromium, cadmium and zinc in water and fish tissue from. Ubeji River ... Key Words : Heavy metal residues , Fish tissue, Human blood, Ubeji River. ... is of critical concern because of their toxicity and.

  8. Chemical reaction engineering studies on cocracking of petroleum vacuum residue with coal, plastics, and biomass (bagasse and petrocrop)

    Energy Technology Data Exchange (ETDEWEB)

    Ahmaruzzaman, M.; Sharma, D.K. [Indian Institute of Technology, New Delhi (India). Centre for Energy Studies

    2007-07-01

    This article deals with the studies on cocracking of petroleum vacuum residue (XVR) with thermosetting plastic, I. e., bakelite (BL), Samla coal (SC), biomass, I. e., bagasse (BG) or C. procera (CL) and their binary, ternary, and quaternary mixtures in a thermogravimetric analyzer (TGA). The kinetic studies were performed using the Coats and Redfern kinetic modeling equation. The overall activation energies obtained were 25 kJ/mole for petroleum vacuum residue, 99 kJ/mole for polypropylene, 21 kJ/mole for coal, 23 kJ/mole for Calotropis procera, and 25 kJ/mole for the combination of these four materials. However, other models, such as van Krevelan et al. and Horowitz and Metzger have also been used in some cases to compare the results with those obtained by the Coats and Redfern kinetic models. In the present work, the effect of catalysts on the cracking of Basra vacuum residue (BVR) has also been reported.

  9. Petroleum hydrocarbon residues in the marine environment of Bassein-Mumbai

    International Nuclear Information System (INIS)

    Chouksey, M.K.; Kadam, A.N.; Zingde, M.D.

    2005-01-01

    The paper reports PHc contamination in water, sediment and biota of the coastal area of Bassein-Mumbai in relation to relatively less polluted sites (Dabhol and Ratnagiri) off the west coast of India. To facilitate inter-comparison three standards have been used though the results are reported in terms of SAM (Residue of Saudi Arabian Mix crude). The concentration of PHc in water off Bassein-Mumbai varies widely (2.9-39.2 μg l -1 ) as compared to the average baseline (2.8 μgl -1 ) with higher values generally confined to creeks and estuaries. The higher concentration of PHc in the bottom water of shallow areas is attributed to the contribution from the sediment-associated petroleum residue. High concentration of PHc in the surficial sediment of inshore area Ratnagiri (107.7 ppm, dry wt) is perhaps the remnants of an oil spill that occurred in the Bombay High region on May 17, 1993. The majority of values of PHc concentration in the surficial sediment of the Bassein-Mumbai region exceed 15 ppm (dry wt) against the expected background ( -1 respectively is estimated for cores U11 and U12. Substantial increase in the concentration of PHc in sediment after 1950 in cores T8 and T10 correlates well with the establishment of refineries on the western shore of the Thane Creek in 1955-1960. A minor peak in most cores in the top 10 cm sediment probably results from biological transfer of PHc lower into the sediment by benthic organisms. Excess of PHc retained in the sediment of the Bassein-Mumbai region over the biogenic background is estimated at 40,000 t. The PHc residues (1.8-10.8 ppm, wet wt) in fish caught off Bassein-Mumbai do not suggest bioaccumulation. (author)

  10. Ultrasonic measurements on residual stress in autofrettged thick walled petroleum pipes

    International Nuclear Information System (INIS)

    Woias, G.; Mizera, J.

    2008-01-01

    The residual stresses in a component or structure are caused by incompatible permanent deformation and related gradient of plastic/elastic strains. They may be generated or modified at every stage in the components life cycle, from original material production to final disposal. Residual stresses can be measured by non-destructive techniques, including X-ray and neutron diffraction, magnetic and ultrasonic methods. The selection of the optimum measurement technique should take account volumetric resolution, material, geometry and access to the component. For large metallic components neutron diffraction is of prime importance as it provides quantitative information on stresses in relatively large volume of methods disregarding its shape complexity. Residual stresses can play a significant role in explaining or preventing failure of components of industrial installations. One example of residual stresses preventing failure are the ones generated by shot peening, inducing surface compressive stresses that improve the fatigue life. Petroleum refinery piping is generally characterized by large-diameters, operated at elevated temperature and under high pressure. Pipelines of a polyethylene plant working in one of the Polish refineries are subjected to pressures exceeding 300 MPa at temperatures above 200 o C. The pipes considered here were pressurized with pressure of 600 MPa. The wall thickness of the pipes is 27 mm and pipe dimensions are 46 x 100 mm. The material is steel with Re=580 MPa. Due to pressurizing, the components retain compressive stresses at the internal surface. These stresses increase resistance to cracking of the pipes. Over the period of exploitation these stresses diminish due to temperature activated relaxation or creep. The purpose of the project is to verify kinetics of such a relaxation process and calibrate alternative methods of their measurements. To avoid stress relaxation, numerical analysis from Finite Element Modelling (FEM)gave an

  11. Structure and properties of compositions based on petroleum sulfonic acids

    Energy Technology Data Exchange (ETDEWEB)

    Tutorskii, I.A.; Sultanova, A.S.; Belkina, E.V.; Fomin, A.G. [Lomonosov Academy of Fine Chemical Technology, Moscow (Russian Federation)

    1995-03-01

    Colloidal characteristics of compositions based on petroleum sulfonic acids were studied. Neutralized heavy oil residue exhibits surface-active properties and contains an ultradisperse filler. Analysis of the compositions by size-exclusion-chromatography shows deep structural changes in the heavy acid residue upon neutralization with calcium carbonate.

  12. Light-particle emission and heavy residues from nucleus-nucleus collisions

    International Nuclear Information System (INIS)

    Caplar, R.; Hoelbling, S.; Gentner, R.; Lassen, L.; Oberstedt, A.

    1991-01-01

    We have investigated the interrelation between light-particle multiplicities and mass resp. charge distributions of heavy residues from complete and incomplete fusion of heavy ions. We have shown that a simple statistical model provides the possibility of quantitatively correlating heavy-residue distributions and corresponding light-particle multiplicities both at the Coulomb barrier and at higher energies where preequilibrium emission occurs. (author). 8 refs, 4 figs, 1 tab

  13. Heavy metals behavior during thermal plasma vitrification of incineration residues

    International Nuclear Information System (INIS)

    Cerqueira, N.; Vandensteendam, C.; Baronnet, J.M.

    2005-01-01

    In the developed world, incineration of wastes is widely and increasingly practiced. Worldwide, a total of approximately 100 millions of tons of municipal solid waste (MSW) material is incinerated annually. Incineration of one ton of MSW leads to the formation of 30 to 50 kg of fly ash, depending on the type of incinerator. The waste disposal of these dusts already causes great problems today; they are of low bulk density, they contain high concentrations of hazardous water-soluble heavy metal compounds, organohalogen compounds (dioxines, furanes), sulfur, and chlorinated compounds. Thermal processes, based mainly on electrical arc processes, show great promise: the residues are melted at high temperature and converted in a relatively inert glass. A few tens of plants, essentially in Japan and Taiwan, have been in industrial operation for a few years. To be authorized to be dumped in a common landfill, the glassy product has to satisfy the leaching test procedure to ensure long-term durability. But to satisfy the regulation to be reused, for example as a nonhazardous standard material in road building, the glassy product would probably include contents in some heavy metals lower than critical limits. So today, there are two alternatives: the first one is to improve the heavy toxic metals evaporation to get a 'light' glassy product and to recycle separately the said separated metals; the second is on the contrary to improve the incorporation of a maximum of heavy metals into the vitreous silicate matrix. Whatever, it is highly required to control, in situ and in real time, volatility of these metals during ash melting under electrical arc. The objective of this work was to reach basic data about metals volatility under the plasma column of an electrical arc transferred on the melt: an experiment has been designed to examine the effects of processing conditions, such as melt temperature, melt composition, and furnace atmosphere, upon volatilization and glassy slag

  14. Removal of residual contaminants in petroleum-contaminated soil by Fenton-like oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Lu Mang [School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, 333001, Jiangxi Province (China); State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); Zhang Zhongzhi, E-mail: zzzhang1955@hotmail.com [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); Qiao Wei; Guan Yueming; Xiao Meng; Peng Chong [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China)

    2010-07-15

    The degradation of bioremediation residues by hydrogen peroxide in petroleum-contaminated soil was investigated at circumneutral pH using a Fenton-like reagent (ferric ion chelated with EDTA). Batch tests were done on 20 g soil suspended in 60 mL aqueous solution containing hydrogen peroxide and Fe{sup 3+}-EDTA complex under constant stirring. A slurry reactor was used to treat the soil based on the optimal reactant conditions. Contaminants were characterized by Fourier transform infrared spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry. The results showed that the optimal treatment condition was: the molar ratio of hydrogen peroxide to iron = 200:1, and pH 7.0. Under the optimum condition, total dichloromethane-extractable organics were reduced from 14,800 to 2300 mg kg{sup -1} soil when the accumulative H{sub 2}O{sub 2} dosage was 2.45 mol kg{sup -1} soil during the reactor treatment. Abundance of viable cells was lower in incubated Fenton-like treated soil than in untreated soil. Oxidation of contaminants produced remarkable compositional and structural modifications. A fused ring compound, identified as C{sub 34}H{sub 38}N{sub 1}, was found to exhibit the greatest resistance to oxidation.

  15. Comparative study on sulphur reduction from heavy petroleum - Solvent extraction and microwave irradiation approach

    Energy Technology Data Exchange (ETDEWEB)

    Mohammed, Abdullahi Dyadya; Isah, Abubakar Garba; Umaru, Musa; Ahmed, Shehu [Department of Chemical Engineering, Federal University of Technology, P.M.B 65, Minna (Nigeria); Abdullahi, Yababa Nma [National Petroleum Investment Management Services (Nigeria National Petroleum Corporation), Lagos (Nigeria)

    2012-07-01

    Sulphur- containing compounds in heavy crude oils are undesirable in refining process as they affect the quality of the final product, cause catalyst poisoning and deactivation in catalytic converters as well as causing corrosion problems in oil pipelines, pumps and refining equipment aside environmental pollution from their combustion and high processing cost. Sulphur reduction has being studied using microwave irradiation set at 300W for 10 and 15minutes and oxidative- solvent extraction method using n- heptane and methanol by 1:1, 1:2 and 1:3 crude- solvent ratios after being oxidized with hydrogen peroxide, H2O2 oxidants. Percentage sulphur removal with n- heptane solvent by 1:1 and 1:2 are 81.73 and 85.47%; but extraction using methanol by different observed ratios gave less sulphur reduction. Indeed when microwave irradiated at 300W for 10 and 15minutes, 53.68 and 78.45% reduction were achieved. This indicates that microwave irradiation had caused oxidation by air in the oven cavity and results to formation of alkyl radicals and sulphoxide from sulphur compound in the petroleum. The prevailing sulphur found in the crude going by FT-IR results is sulphides which oxidized to sulphoxide or sulphones. It is clear that sulphur extraction with heptane is more efficient than microwave irradiation but economically due to demands for solvent and its industrial usage microwave irradiation can serve as alternative substitute for sulphur reduction in petroleum. Sulphur reduction by microwave radiation should be up- scaled from laboratory to a pilot plant without involving extraction column in the refining.

  16. Gasification of coal as efficient means of environment protection and hydrogenation of heavy oils residues

    Energy Technology Data Exchange (ETDEWEB)

    Krichko, A.A.; Maloletnev, A.S. [Fossil Fuel Institute, Moscow (Russian Federation)

    1995-12-31

    The Russia`s more then 50% of coals produced in its European part contain over 2,5% of sulphur, and the coals containing less than 1.5% of sulphurs comprise ca.20%. Thus, utilisation of the sulphide coals is inevitable, and there a problem arises concerning the technology of their sensible use and considering the requirements on the environment protection. Russia`s specialists have developed a design and construction for a steam-gas installation with a closed cycle gasification of the solid fuel. The gasification process will proceed in the fluidized bed under forced pressure of the steam-air blast. Characteristic features of this process are the following: a higher efficiency (the capacity of one gas generator is 3-3,5 times larger than that attained in the present gas generators of the Lurgy`s type): 2-2,5 times decreased fuel losses as compared to the Winkler`s generators; retention of the sensible heat, resulting in an increased total energy efficiency. The main task for petroleum refining industry at the present stage is the increase of depth of oil processing with the aim to intensify motor fuel production. One of the ways to solve the problem is to involve heavy oil residues into the processing. But the high metal and asphaltenes contents in the latter make the application of traditional methods and processes more difficult. Up to now there is no simple and effective technology which could give the opportunity to use oil residues for distillate fractions production. In Fossil fuel institute a process for hydrogenation of high boiling oil products, including with high sulphur, vanadium and nickel contents ones, into distillates and metals concentrates. The main point of the new process is as follows: the water solution of catalytic additive, for which purpose water soluble metal salts of VI-VIII groups are used, is mixed with tar, dispersed and then subjected to additional supercavitation in a special apparatus.

  17. Evaluation of gastrointestinal solubilization of petroleum hydrocarbon residues in soil using an in vitro physiologically based model.

    Science.gov (United States)

    Holman, Hoi-Ying N; Goth-Goldstein, Regine; Aston, David; Yun, Mao; Kengsoontra, Jenny

    2002-03-15

    Petroleum hydrocarbon residues in weathered soils may pose risks to humans through the ingestion pathway. To understand the factors controlling their gastrointestinal (GI) absorption, a newly developed experimental extraction protocol was used to model the GI solubility of total petroleum hydrocarbon (TPH) residues in highly weathered soils from different sites. The GI solubility of TPH residues was significantly higher for soil contaminated with diesel than with crude oil. Compared to the solubility of TPH residues during fasted state,the solubility of TPH residues during fat digestion was much greater. Diesel solubility increased from an average of 8% during the "gallbladder empty" phase of fasting (and less than 0.2% during the otherfasting phase) to an average of 16% during fat digestion. For crude oil, the solubility increased from an average of 1.2% during the gallbladder empty phase of fasting (and undetectable during the other fasting phase) to an average of 4.5% during fat digestion. Increasing the concentration of bile salts also increased GI solubility. GI solubility was reduced by soil organic carbon but enhanced by the TPH content.

  18. Recycling used palm oil and used engine oil to produce white bio oil, bio petroleum diesel and heavy fuel

    Science.gov (United States)

    Al-abbas, Mustafa Hamid; Ibrahim, Wan Aini Wan; Sanagi, Mohd. Marsin

    2012-09-01

    Recycling waste materials produced in our daily life is considered as an additional resource of a wide range of materials and it conserves the environment. Used engine oil and used cooking oil are two oils disposed off in large quantities as a by-product of our daily life. This study aims at providing white bio oil, bio petroleum diesel and heavy fuel from the disposed oils. Toxic organic materials suspected to be present in the used engine oil were separated using vacuum column chromatography to reduce the time needed for the separation process and to avoid solvent usage. The compounds separated were detected by gas chromatography-mass spectrometry (GC-MS) and found to contain toxic aromatic carboxylic acids. Used cooking oils (thermally cracked from usage) were collected and separated by vacuum column chromatography. White bio oil produced was examined by GC-MS. The white bio oil consists of non-toxic hydrocarbons and is found to be a good alternative to white mineral oil which is significantly used in food industry, cosmetics and drugs with the risk of containing polycyclic aromatic compounds which are carcinogenic and toxic. Different portions of the used cooking oil and used engine were mixed to produce several blends for use as heavy oil fuels. White bio oil was used to produce bio petroleum diesel by blending it with petroleum diesel and kerosene. The bio petroleum diesel produced passed the PETRONAS flash point and viscosity specification test. The heat of combustion of the two blends of heavy fuel produced was measured and one of the blends was burned to demonstrate its burning ability. Higher heat of combustion was obtained from the blend containing greater proportion of used engine oil. This study has provided a successful recycled alternative for white bio oil, bio petroleum fuel and diesel which can be an energy source.

  19. New statistical function for the angular distribution of evaporation residues produced by heavy ions

    International Nuclear Information System (INIS)

    Rigol, J.

    1994-01-01

    A new statistical function has been found for modelling the angular distribution of evaporation residues produced by heavy ions. Experimental results are compared with the calculated ones. 11 refs.; 4 figs. (author)

  20. Monitoring of ground water quality and heavy metals in soil during large scale bioremediation of petroleum hydrocarbon contaminated waste in India: case studies

    Directory of Open Access Journals (Sweden)

    Ajoy Kumar Mandal

    2014-10-01

    Full Text Available Bioremediation using microbes has been well accepted as an environmentally friendly and economical treatment method for disposal of hazardous petroleum hydrocarbon contaminated waste (oily waste and this type of bioremediation has been successfully conducted in laboratory and on a pilot scale in various countries, including India. Presently there are no federal regulatory guidelines available in India for carrying out field-scale bioremediation of oily waste using microbes. The results of the present study describe the analysis of ground water quality as well as selected heavy metals in oily waste in some of the large-scale field case studies on bioremediation of oily waste (solid waste carried out at various oil installations in India. The results show that there was no contribution of oil and grease and selected heavy metals to the ground water in the nearby area due to adoption of this bioremediation process. The results further reveal that there were no changes in pH and EC of the groundwater due to bioremediation. In almost all cases the selected heavy metals in residual oily waste were within the permissible limits as per Schedule – II of Hazardous Waste Management, Handling and Transboundary Movement Act, Amendment 2008, (HWM Act 2008, by the Ministry of Environment and Forests (MoEF, Government of India (GoI.

  1. The influence of dissolved petroleum hydrocarbon residues on natural phytoplankton biomass

    Digital Repository Service at National Institute of Oceanography (India)

    Shailaja, M.S.

    on phytoplankton biomass varies depending on the nature rather than the quantity of petroleum hydrocarbons present. Culture studies with unialgal Nitzschia sp. in seawater collected from selected stations in the study area as well as in artificial seawater spiked...

  2. Bioremediation of heavy metals and petroleum hydrocarbons in diesel contaminated soil with the earthworm: Eudrilus eugeniae.

    Science.gov (United States)

    Ekperusi, Ogheneruemu Abraham; Aigbodion, Iruobe Felix

    2015-01-01

    A laboratory study on the bioremediation of diesel contaminated soil with the earthworm Eudrilus eugeniae (Kingberg) was conducted. 5 ml of diesel was contaminated into soils in replicates and inoculated with E. eugeniae for 90 days. Physicochemical parameters, heavy metals and total petroleum hydrocarbons were analyzed using AAS. BTEX in contaminated soil and tissues of earthworms were determined with GC-FID. The activities of earthworms resulted in a decrease in pH (3.0 %), electrical conductivity (60.66 %), total nitrogen (47.37 %), chloride (60.66 %), total organic carbon (49.22 %), sulphate (60.59 %), nitrate (60.65 %), phosphate (60.80 %), sodium (60.65 %), potassium (60.67 %), calcium (60.67 %), magnesium (60.68 %), zinc (60.59 %), manganese (60.72 %), copper (60.68 %), nickel (60.58 %), cadmium (60.44 %), vanadium (61.19 %), chromium (53.60 %), lead (60.38 %), mercury (61.11 %), arsenic (80.85 %), TPH (84.99 %). Among the BTEX constituents, only benzene (8.35 %) was detected in soil at the end of the study. Earthworm tissue analysis showed varying levels of TPH (57.35 %), benzene (38.91 %), toluene (27.76 %), ethylbenzene (42.16 %) and xylene (09.62 %) in E. eugeniae at the end of the study. The study has shown that E. eugeniae could be applied as a possible bioremediator in diesel polluted soil.

  3. Process and catalysis for hydrocracking of heavy oil and residues

    Energy Technology Data Exchange (ETDEWEB)

    Morel, F.; Kressmann, S. [Centre d' Etudes et de developpement Indutriel ' Rene Navarre' , Vernaison (France); Harle, V.; Kasztelan, S. [Division Cinetique et Catalyse, Rueil-Malmaison (France)

    1997-07-01

    Atmospheric or vacuum residue can be converted into valuable distillates using reaction temperature, high hydrogen pressure and low contact time hydroprocessing units. Various residue hydrocracking processes are now commercially employed using fixed bed, moving bed or ebullated bed reactors. The choice of process type depends mainly on the amount of metals and asphaltenes in the feed and on the level of conversion required. Various improvements have been introduced in the last decade to increase run length, conversion level, products qualities and stability of the residual fuel. These improvements include on stream catalysts replacement systems, swing reactors, improved feed distribution, guard bed materials limiting pressure drop, coke resistant catalysts, complex association of catalysts using particle size, activity and pore size grading. Further improvement of the resistance of catalysts to deactivation by coke and metal deposits and of the hydrodenitrogenation activity are two major challenges for the development of new residue hydrocracking catalysts and processes. 29 refs.

  4. Effect of temperature on the level of corrosion caused by heavy petroleum on AISI 304 and AISI 444 stainless steel

    Directory of Open Access Journals (Sweden)

    João Paulo Sampaio Eufrásio Machado

    2006-06-01

    Full Text Available This work presents a study on the influence of national heavy petroleum in the corrosion of the AISI 444 and AISI 304 stainless steels in simulated refining operation conditions. The petroleum was first characterized through physicochemical analysis (density, fluidity point, viscosity, sulfur concentration. In an attempt to understand the corrosion effect of temperature and of the type of heating the referred types of steel thermal treatments were carried out at three levels of temperature (200, 300 and 400 °C. The procedure was done in conditions close to those in the distillation column. Heat was gradually increased from room temperature, and directly heated to working temperature. Each treatment took 4 hours to be completed. Scanning electronic microscopy (SEM and the analysis of X rays dispersive energy (EDX were used after the trials to characterize the samples. The results show that treatment temperature, as well as the type of heating, has distinct influences on each type of steel.

  5. Pyrolysis and reutilization of plant residues after phytoremediation of heavy metals contaminated sediments: For heavy metals stabilization and dye adsorption.

    Science.gov (United States)

    Gong, Xiaomin; Huang, Danlian; Liu, Yunguo; Zeng, Guangming; Wang, Rongzhong; Wei, Jingjing; Huang, Chao; Xu, Piao; Wan, Jia; Zhang, Chen

    2018-04-01

    This study aimed to investigate the effect of pyrolysis on the stabilization of heavy metals in plant residues obtained after phytoremediation. Ramie residues, being collected after phytoremediation of metal contaminated sediments, were pyrolyzed at different temperatures (300-700 °C). Results indicated that pyrolysis was effective in the stabilization of Cd, Cr, Zn, Cu, and Pb in ramie residues by converting the acid-soluble fraction of metals into residual form and decreasing the TCLP-leachable metal contents. Meanwhile, the reutilization potential of using the pyrolysis products generated from ramie residues obtained after phytoremediation as sorbents was investigated. Adsorption experiments results revealed that the pyrolysis products presented excellent ability to adsorb methylene blue (MB) with a maximum adsorption capacity of 259.27 mg/g. This study demonstrated that pyrolysis could be used as an efficient alternative method for stabilizing heavy metals in plant residues obtained after phytoremediation, and their pyrolysis products could be reutilized for dye adsorption. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. Removal of heavy metals from aqueous solution by Carrot residues

    International Nuclear Information System (INIS)

    Eslamzadeh, T.; Nasernejad, B.; Bonakdar Pour, B.; Zamani, A.; Esmaail-Beygi, M.

    2004-01-01

    The removal of Copper(II), Zinc(II), and Chromium (III) from wastewater by carrot residues was investigated to evaluate cation exchange capacity. The effects of solution P H and co-ions were studied in batch experiments. Adsorption equilibria were initially rapidly established, and then decreased markedly after 10 min. Column experiments were carried out in a glass column filled with carrot residues to evaluate the metal removal capacity. The influences of the feed concentration and feed rate were also studied in order to compare the dynamic capacity for metal binding in different feed concentrations

  7. Effects of operating conditions on compositional characteristics and reaction kinetics of liquid derived by delayed coking of nigerian petroleum residue

    Directory of Open Access Journals (Sweden)

    O. O. Bello

    2006-09-01

    Full Text Available The thermal upgrading of Nigerian petroleum residue was studied at relatively low pressure in a delayed coking reactor system. In this work, the intent was to investigate the effects of process variables such as reaction temperature (200(0C to 600(0C, reaction time (0 to 120min, additive concentration loading and additive-to-residue ratio on the amounts and quality of organic liquid product (OLP. The liquid products derived from the delayed coking process were characterized by means of instrumental analysis of gas-liquid chromatography. Results obtained from the analyses of the OLP revealed an upward trend of the conversion process and the selectivity of the aromatic compounds with additive-to-residue ratio (ARR and increase in temperature. This led to maximum yield of 37.2% achieved with ARR of 5 compared to 31% achieved with ordinary thermal conversion. The selectivity for aromatic hydrocarbons was maximum at 83.1wt% the selectivity towards aromatics and aliphatic hydrocarbons were highest for methanol-potassium hydroxide and methanol respectively. In all additive system cases, maximum OLP was produced at an optimum reaction temperature of 370(0C in the delayed coking reactor and at higher residence time. The gaseous product consisted of carbon monoxide and carbon dioxide and C1 - C6 hydrocarbons, which amounted to about 20 to 30 wt% of liquid distillate. The information obtained in this study show that the organic liquid products are amenable to characterization procedure and provided the basis for the identification of processes for upgrading Nigerian petroleum residue and such other starting materials such as bitumen or fossil fuel coal liquids.

  8. Effects of residues from municipal solid waste landfill on corn yield and heavy metal content

    International Nuclear Information System (INIS)

    Prabpai, S.; Charerntanyarak, L.; Siri, B.; Moore, M.R.; Noller, Barry N.

    2009-01-01

    The effects of residues from municipal solid waste landfill, Khon Kaen Municipality, Thailand, on corn (Zea mays L.) yield and heavy metal content were studied. Field experiments with randomized complete block design with five treatments (0, 20, 40, 60 and 80% v/v of residues and soil) and four replications were carried out. Corn yield and heavy metal contents in corn grain were analyzed. Corn yield increased by 50, 72, 85 and 71% at 20, 40, 60 and 80% treatments as compared to the control, respectively. All heavy metals content, except cadmium, nickel and zinc, in corn grain were not significantly different from the control. Arsenic, cadmium and zinc in corn grain were strongly positively correlated with concentrations in soil. The heavy metal content in corn grain was within regulated limits for human consumption.

  9. Impact of toxic heavy metals and pesticide residues in herbal products

    Directory of Open Access Journals (Sweden)

    Nema S. Shaban

    2016-03-01

    Full Text Available Medicinal plants have a long history of use in therapy throughout the world and still make an important part of traditional medicine. The World Health Organization (WHO estimates that 65%–80% of the world's populations depend on the herbal products as their primary form of health care. This review is conducted to provide a general idea about chemical contaminants such as heavy metals and pesticide residues as major common contaminants of the herbal medicine, which impose serious health risks to human health. Additionally, we aim to provide different analytical methods for analysis of heavy metals and pesticide residues in the herbal medicine.

  10. Evaluation of heavy metals in hazardous automobile shredder residue thermal residue and immobilization with novel nano-size calcium dispersed reagent.

    Science.gov (United States)

    Lee, Chi-Hyeon; Truc, Nguyen Thi Thanh; Lee, Byeong-Kyu; Mitoma, Yoshiharu; Mallampati, Srinivasa Reddy

    2015-10-15

    This study was conducted to synthesize and apply a nano-size calcium dispersed reagent as an immobilization material for heavy metal-contaminated automobile shredder residues (ASR) dust/thermal residues in dry condition. Simple mixing with a nanometallic Ca/CaO/PO4 dispersion mixture immobilized 95-100% of heavy metals in ASR dust/thermal residues (including bottom ash, cavity ash, boiler and bag filter ash). The quantity of heavy metals leached from thermal residues after treatment by nanometallic Ca/CaO/PO4 was lower than the Korean standard regulatory limit for hazardous waste landfills. The morphology and elemental composition of the nanometallic Ca/CaO-treated ASR residue were characterized by field emission scanning election microscopy combined with electron dispersive spectroscopy (FE-SEM/EDS). The results indicated that the amounts of heavy metals detectable on the ASR thermal residue surface decreased and the Ca/PO4 mass percent increased. X-ray diffraction (XRD) pattern analysis indicated that the main fraction of enclosed/bound materials on ASR residue included Ca/PO4- associated crystalline complexes, and that immobile Ca/PO4 salts remarkably inhibited the desorption of heavy metals from ASR residues. These results support the potential use of nanometallic Ca/CaO/PO4 as a simple, suitable and highly efficient material for the gentle immobilization of heavy metals in hazardous ASR thermal residue in dry condition. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. Heavy metal residues in tissues of marine turtles

    International Nuclear Information System (INIS)

    Storelli, M.M.; Marcotrigiano, G.O.

    2003-01-01

    Heavy metal concentrations in the tissues of marine turtles are presented. The most frequently monitored elements are mercury, cadmium and lead; and the tissues mainly analysed in nearly all the stranded individuals are muscle, liver and kidney. The highest mercury and cadmium levels were found in liver and kidney respectively; the majority of the lead burden existed in bones and carapace, while arsenic was present mainly in muscle tissue. Mercury occurred quite completely as methylmercury in muscle, whereas in liver the main form was the inorganic one. Arsenic was exclusively present in the metallorganic form either in muscle tissue or in liver. Metals in the eggs were mainly present in the yolk. Significantly higher concentration of mercury, copper, zinc and iron were found in yolk than albumen, while shell contained highest levels of manganese and copper. The load of trace metals in these animals strictly correlated with the species seems to depend on their different food behaviour

  12. Heavy metal residues in tissues of marine turtles

    Energy Technology Data Exchange (ETDEWEB)

    Storelli, M.M.; Marcotrigiano, G.O

    2003-04-01

    Heavy metal concentrations in the tissues of marine turtles are presented. The most frequently monitored elements are mercury, cadmium and lead; and the tissues mainly analysed in nearly all the stranded individuals are muscle, liver and kidney. The highest mercury and cadmium levels were found in liver and kidney respectively; the majority of the lead burden existed in bones and carapace, while arsenic was present mainly in muscle tissue. Mercury occurred quite completely as methylmercury in muscle, whereas in liver the main form was the inorganic one. Arsenic was exclusively present in the metallorganic form either in muscle tissue or in liver. Metals in the eggs were mainly present in the yolk. Significantly higher concentration of mercury, copper, zinc and iron were found in yolk than albumen, while shell contained highest levels of manganese and copper. The load of trace metals in these animals strictly correlated with the species seems to depend on their different food behaviour.

  13. Depletion of penicillin G residues in heavy sows after intramuscular injection. Part I: Tissue residue depletion

    Science.gov (United States)

    Heavy sows (n=126) were treated with penicillin G procaine at a 5x label dose (33,000 IU/kg) for 3 consecutive days by intramuscular (IM) injection using 3 separate patterns (treatments) of drug administration (42 sows per treatment). Treatments differed by pattern and maximum injection volume per s...

  14. Concentration of paramagnetic centres at low-temperature thermal destruction of asphaltenes of heavy petroleum distillates

    Directory of Open Access Journals (Sweden)

    Dolomatov M.U., Rodionov A.A., Gafurov M.R., Petrov A.V., Biktagirov T.B., Bakhtizin R.Z., Makarchikov S.O., Khairudinov I.Z., Orlinskii S.B.

    2016-11-01

    Full Text Available Changes of paramagnetic centers (PC concentration in dispersed petroleum systems were studied in the process of low-temperature thermolysis. The kinetic model of PC concentration dynamics based on the processes of unpaired electrons formation during singlet-triplet transitions, weak chemical bonds dissociation and recombination of free radicals is proposed.

  15. Petroleum hydrocarbon residues in the marine environment of Bassein-Mumbai

    Digital Repository Service at National Institute of Oceanography (India)

    Chouksey, M.K.; Kadam, A.N.; Zingde, M.D.

    .elsevier.com/locate/marpolbul 637–647 oxygen (DO) and nutrients in water (Zingde, 1999); heavy metals in water, sediment and organisms (Zingde and Desai, 1981; Patel et al., 1985; Pillai et al., 1987; Bhosale and Sahu, 1991; Sahu and Bhosale, 1991; Sharma et al., 1994; Ram et al... accounting for higher concentrations of PHc in the segment upstream of station U6. Considerable deterioration in water quality of the inner zone of the Ulhas estuary with respect to pH, DO, nutrients, heavy metals, etc. due to anthropogenic perturbations has...

  16. Measurement of residual radioactivity in cooper exposed to high energy heavy ion beam

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Eunjoo; Nakamura, Takashi [Tohoku Univ., Sendai (Japan). Cyclotron and Radioisotope Center; Uwamino, Yoshitomo; Ito, Sachiko; Fukumura, Akifumi

    1999-03-01

    The residual radioactivities produced by high energy heavy ions have been measured using the heavy ion beams of the Heavy Ion Medical Accelerator (HIMAC) at National Institute of Radiological Sciences. The spatial distribution of residual radioactivities in 3.5 cm, 5.5 cm and 10 cm thick copper targets of 10 cm x 10 cm size bombarded by 290 MeV/u, 400 MeV/u-{sup 12}C ion beams and 400 MeV/u-{sup 20}Ne ion beam, respectively, were obtained by measuring the gamma-ray activities of 0.5 mm thick copper foil inserted in the target with a high purity Ge detector after about 1 hour to 6 hours irradiation. (author)

  17. Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling

    Energy Technology Data Exchange (ETDEWEB)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng, E-mail: shends@zju.edu.cn

    2013-10-15

    Highlights: • Cu, Zn, Pb, and Ni are enriched in bottom ash from WEEE dismantling residues. • The heavy metal residual fraction restricts transfer in the incinerator. • Pre-treatment to remove heavy metals from WEEE residues would reduce emissions. -- Abstract: The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (T{sub Cd} = 69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required.

  18. Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling

    International Nuclear Information System (INIS)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng

    2013-01-01

    Highlights: • Cu, Zn, Pb, and Ni are enriched in bottom ash from WEEE dismantling residues. • The heavy metal residual fraction restricts transfer in the incinerator. • Pre-treatment to remove heavy metals from WEEE residues would reduce emissions. -- Abstract: The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (T Cd = 69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required

  19. The pentane- and toluene-soluble fractions of a petroleum residue and three coal tars by size exclusion chromatography and UV-fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Karaca, F.; Millan-Agorio, M.; Morgan, T.J.; Bull, I.D.; Herod, A.A.; Kandiyoti, R. [University of London Imperial College Science Technology & Medicine, London (United Kingdom). Dept. of Chemical Engineering

    2008-01-15

    A petroleum atmospheric pressure distillate residue and three tars derived from different coals using different severities of thermal treatment were separated into seven fractions using column chromatography on silica and sequential elution by the solvent sequence pentane, toluene, acetonitrile, pyridine, 1-methyl-2-pyrrolidinone (NMP) and water. The fractions from the four extractions have been compared using size exclusion chromatography (SEC) in NMP as eluent and by synchronous ultra-violet-fluorescence (UV-F). This paper concerns the pentane and toluene soluble fractions only since these are the least polar fractions. By SEC, the size of the aromatic molecules increased from the first pentane soluble fractions to the toluene-soluble fractions, with the petroleum residue fractions of larger size than the equivalent fractions from coal liquids. The three coal tars showed significant differences, indicating that temperature of pyrolysis had a significant effect on the molecular size. Synchronous UV-F spectra of the four sets of fractions, in solution in NMP, again showed significant differences between the petroleum residue and the coal tars, as well as amongst the three coal tars. In general, the petroleum residue fractions contained smaller aromatic clusters than the coal liquid fractions. These low-polarity fractions contained material excluded from the column porosity in SEC that was unlikely to consist of aggregates of polar molecules.

  20. Evaluation of heavy metals in hazardous automobile shredder residue thermal residue and immobilization with novel nano-size calcium dispersed reagent

    International Nuclear Information System (INIS)

    Lee, Chi-Hyeon; Truc, Nguyen Thi Thanh; Lee, Byeong-Kyu; Mitoma, Yoshiharu; Mallampati, Srinivasa Reddy

    2015-01-01

    Graphical abstract: Schematic representation of possible mechanisms determining the heavy metals immobilization efficiencyof ASR dust/thermal residues after treatment with nanometallic Ca/CaO/PO 4 . - Highlights: • Nanometallic Ca/CaO/PO 4 for heavy metals immobilization in ASR residue. • Heavy metals immobilization in dry condition attained about 95–100%. • Remaining heavy metals were lower than the Korean standard regulatory limit. • The amounts of heavy metals detectable on the ASR dust surface decreased. • Nanometallic Ca/CaO/PO 4 has a promising potential for heavy metal remediation. - Abstract: This study was conducted to synthesize and apply a nano-size calcium dispersed reagent as an immobilization material for heavy metal-contaminated automobile shredder residues (ASR) dust/thermal residues in dry condition. Simple mixing with a nanometallic Ca/CaO/PO 4 dispersion mixture immobilized 95–100% of heavy metals in ASR dust/thermal residues (including bottom ash, cavity ash, boiler and bag filter ash). The quantity of heavy metals leached from thermal residues after treatment by nanometallic Ca/CaO/PO 4 was lower than the Korean standard regulatory limit for hazardous waste landfills. The morphology and elemental composition of the nanometallic Ca/CaO-treated ASR residue were characterized by field emission scanning election microscopy combined with electron dispersive spectroscopy (FE-SEM/EDS). The results indicated that the amounts of heavy metals detectable on the ASR thermal residue surface decreased and the Ca/PO 4 mass percent increased. X-ray diffraction (XRD) pattern analysis indicated that the main fraction of enclosed/bound materials on ASR residue included Ca/PO 4 − associated crystalline complexes, and that immobile Ca/PO 4 salts remarkably inhibited the desorption of heavy metals from ASR residues. These results support the potential use of nanometallic Ca/CaO/PO 4 as a simple, suitable and highly efficient material for the gentle

  1. Evaluation of heavy metals in hazardous automobile shredder residue thermal residue and immobilization with novel nano-size calcium dispersed reagent

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Chi-Hyeon; Truc, Nguyen Thi Thanh [Department of Civil and Environmental Engineering, University of Ulsan, Daehak-ro 93, Nam-gu, Ulsan 680-749 (Korea, Republic of); Lee, Byeong-Kyu, E-mail: bklee@ulsan.ac.kr [Department of Civil and Environmental Engineering, University of Ulsan, Daehak-ro 93, Nam-gu, Ulsan 680-749 (Korea, Republic of); Mitoma, Yoshiharu [Department of Environmental Sciences, Prefectural University of Hiroshima, 562 Nanatsuka-Cho Shobara City, Hiroshima 727-0023 (Japan); Mallampati, Srinivasa Reddy, E-mail: srireddys@ulsan.ac.kr [Department of Civil and Environmental Engineering, University of Ulsan, Daehak-ro 93, Nam-gu, Ulsan 680-749 (Korea, Republic of)

    2015-10-15

    Graphical abstract: Schematic representation of possible mechanisms determining the heavy metals immobilization efficiencyof ASR dust/thermal residues after treatment with nanometallic Ca/CaO/PO{sub 4}. - Highlights: • Nanometallic Ca/CaO/PO{sub 4} for heavy metals immobilization in ASR residue. • Heavy metals immobilization in dry condition attained about 95–100%. • Remaining heavy metals were lower than the Korean standard regulatory limit. • The amounts of heavy metals detectable on the ASR dust surface decreased. • Nanometallic Ca/CaO/PO{sub 4} has a promising potential for heavy metal remediation. - Abstract: This study was conducted to synthesize and apply a nano-size calcium dispersed reagent as an immobilization material for heavy metal-contaminated automobile shredder residues (ASR) dust/thermal residues in dry condition. Simple mixing with a nanometallic Ca/CaO/PO{sub 4} dispersion mixture immobilized 95–100% of heavy metals in ASR dust/thermal residues (including bottom ash, cavity ash, boiler and bag filter ash). The quantity of heavy metals leached from thermal residues after treatment by nanometallic Ca/CaO/PO{sub 4} was lower than the Korean standard regulatory limit for hazardous waste landfills. The morphology and elemental composition of the nanometallic Ca/CaO-treated ASR residue were characterized by field emission scanning election microscopy combined with electron dispersive spectroscopy (FE-SEM/EDS). The results indicated that the amounts of heavy metals detectable on the ASR thermal residue surface decreased and the Ca/PO{sub 4} mass percent increased. X-ray diffraction (XRD) pattern analysis indicated that the main fraction of enclosed/bound materials on ASR residue included Ca/PO{sub 4}− associated crystalline complexes, and that immobile Ca/PO{sub 4} salts remarkably inhibited the desorption of heavy metals from ASR residues. These results support the potential use of nanometallic Ca/CaO/PO{sub 4} as a simple, suitable and

  2. Heavy metal residues in beef carcasses in Beni-Suef abattoir, Egypt

    Directory of Open Access Journals (Sweden)

    Fathy A. Khalafalla

    2011-09-01

    Full Text Available A total of 300 samples were collected from cattle slaughtered in the Beni-Suef abattoir in Egypt. Samples included muscle, liver and kidney. Animals were randomly selected from the slaughter line. The age of the slaughtered cattle was less than three years (18-30 months. Samples were packed separately in plastic bags, identified and stored at -18°C until analysis which was performed at the Max Rubner Institute in Kulmbach, Germany, for the following heavy metals residues: lead, cadmium, mercury, arsenic, chromium and nickel in beef muscle, liver and kidney samples. The results revealed that the overall mean residual levels of lead were 8.77 µg/kg, 42.70 µg/kg and 109.42 µg/kg fresh weight in muscle, liver and kidney samples, respectively, while the mean residual levels of cadmium were 1.40 µg/kg, 14.16 µg/kg and 62.56 µg/kg fresh weight, respectively, and the mean arsenic residual levels were 5.06 µg/kg, 4.64 µg/kg and 14.92 µg/kg fresh weight, respectively. The mean residual levels of mercury were 3.91 µg/kg, 5.81 µg/kg and 10.14 µg/kg fresh weight, respectively, and the residual levels of chromium were 11.20 µg/kg, 21.85 µg/kg and 25.49 µg/kg fresh weight, respectively. Finally, the mean residual levels of nickel were 21.17 µg/kg, 14.59 µg/kg and 34.95 µg/kg fresh weight, respectively. The mean values of all heavy metals examined were low and did not exceed the permissible limits adopted by different organisations. Most heavy metals accumulated in higher concentrations in the kidney in comparison to the liver and muscle.

  3. The microstructure of petroleum vacuum residue films for bituminous concrete: a microscopy approach

    NARCIS (Netherlands)

    Sourty, E.; Tamminga, A.Y.; Michels, M.A.J.; Vellinga, W.P.; Meijer, H.E.H.

    2011-01-01

    Selected carbon-rich refinery residues (‘binders’) mixed with mineral particles can form composite materials (‘bituminous concrete’) with bulk mechanical properties comparable to those of cement concrete. The microstructural mechanism underlying the remarkable composite properties has been related

  4. A novel process for heavy residue hydroconversion using a recoverable pseudo-homogenous catalyst PHC system

    Energy Technology Data Exchange (ETDEWEB)

    Romocki, S.M.; Rhodey, W.G. [Mobis Energy Inc., Calgary, AB (Canada)

    2008-10-15

    This paper described a pseudo-homogenous catalyst (PHC) designed to refine heavy hydrocarbon residues containing sulfur, nitrogen, metals, and asphaltene impurities known to clog pores and deactivate traditional hydrocrackers. The heavy residue hydroconversion (HRH) process incorporated a single particle, chemically generated PHC uniformly distributed in the feed. Thermal decomposition within the reaction system of a water-in-oil emulsion containing ammonium paramolybdate was used to form molybdenum oxide, which was then sulfided within the feed in order to create an ultra-dispersed suspension of catalytically active molybdenum disulfide particles measuring between 2 and 9 nm. A proprietary online catalyst recovery and regeneration step was used to maintain high catalyst activity. The molybdenum was then recovered from a purge stream and then reintroduced to the catalyst preparation area as a catalyst precursor. After being conditioned, the feed was combined with hydrogen and a water-oil catalyst emulsion and introduced into a furnace. Heavy components were cracked, hydrogenated and converted to lighter products. The high performance catalyst system was able to convert 95 per cent of residues at pressures below 7.3 Mpa and at reaction temperatures ranging between 400 and 460 degrees C. The catalyst was tested at a pilot plant using Athabasca vacuum bottoms. It was concluded that the HRH process is now being successfully used to produce 200 barrels of heavy oil per day. Designs for commercial installations are now being prepared. 4 refs., 2 tabs., 2 figs.

  5. Développements récents dans le domaine de l'hydrotraitement des fractions lourdes Advances in the Hydrotreatment of Heavy Petroleum Feedstocks

    Directory of Open Access Journals (Sweden)

    Jacquin Y.

    2006-11-01

    Full Text Available L'évolution du raffinage vers une utilisation des produits pétroliers pour les usages des transports et comme base pour la pétrochimie renforce l'intérêt pour les procédés de transformation des fractions lourdes du pétrole en fractions légères correspondant au marché actuel. Les problèmes posés par le raffinage des résidus de distillation sont semblables à ceux rencontrés pour le traitement des bruts lourds non conventionnels. Les méthodes qui sont actuellement envisagées peuvent être classées en 2 catégories : les méthodes de raffinage avec rejet de carbone comme la cokéfaction et le désasphaltage et les méthodes sans rejet de carbone comme la viscoréduction, l'hydroviscoréduction et l'hydrotraitement catalytique. Chacune de ces techniques est examinée en précisant les rendements en produits liquides qu'elle permet d'atteindre et les hydrotraitements complémentaires nécessaires pour obtenir des produits répondant aux spécifications du marché des produits pétroliers. Les progrès réalisés dans la conception des catalyseurs utilisés pour le traitement des produits lourds permet aujourd'hui d'envisager l'hydrotraitement direct des résidus sous vide de la majorité des bruts raffinés. The increasing use of refined petroleum products for transportation purposes and as petrochemical bases reinforces interest in processes for converting heavy fractions into light fractions suitable for today's market. The refining of distillation residues involves difficulties similar to unconventional heavy-crude processing. As of now methods may be classified in two categories: (i refining methods with carbon rejection such as coking and deasphalting processes, and (ii methods without carbon rejection such as visbreaking, hydrovisbreaking and catalytic hydrotreating. Each of these techniques is examined, taking into account the liquid-product yields it may reach, and the additional hydrotreatments necessary to meet market

  6. Ex situ bioremediation of a soil contaminated by mazut (heavy residual fuel oil)--a field experiment.

    Science.gov (United States)

    Beškoski, Vladimir P; Gojgić-Cvijović, Gordana; Milić, Jelena; Ilić, Mila; Miletić, Srdjan; Solević, Tatjana; Vrvić, Miroslav M

    2011-03-01

    Mazut (heavy residual fuel oil)-polluted soil was exposed to bioremediation in an ex situ field-scale (600 m(3)) study. Re-inoculation was performed periodically with biomasses of microbial consortia isolated from the mazut-contaminated soil. Biostimulation was conducted by adding nutritional elements (N, P and K). The biopile (depth 0.4m) was comprised of mechanically mixed polluted soil with softwood sawdust and crude river sand. Aeration was improved by systematic mixing. The biopile was protected from direct external influences by a polyethylene cover. Part (10 m(3)) of the material prepared for bioremediation was set aside uninoculated, and maintained as an untreated control pile (CP). Biostimulation and re-inoculation with zymogenous microorganisms increased the number of hydrocarbon degraders after 50 d by more than 20 times in the treated soil. During the 5 months, the total petroleum hydrocarbon (TPH) content of the contaminated soil was reduced to 6% of the initial value, from 5.2 to 0.3 g kg(-1) dry matter, while TPH reduced to only 90% of the initial value in the CP. After 150 d there were 96%, 97% and 83% reductions for the aliphatic, aromatic, and nitrogen-sulphur-oxygen and asphaltene fractions, respectively. The isoprenoids, pristane and phytane, were more than 55% biodegraded, which indicated that they are not suitable biomarkers for following bioremediation. According to the available data, this is the first field-scale study of the bioremediation of mazut and mazut sediment-polluted soil, and the efficiency achieved was far above that described in the literature to date for heavy fuel oil. Copyright © 2011 Elsevier Ltd. All rights reserved.

  7. Determination of pollutant elements and heavy metals in petroleum sludge and scale at Heglig field Sudan

    International Nuclear Information System (INIS)

    Amir, N. T.

    2012-02-01

    The release of pollutant metals from petroleum industry in to ecosystems represents a serious hazard for the biosphere, because of their toxicity. The objective of this study was to determine the levels of some elements in petroleum sludge and scales collected from petroleum production area in Heglig oil field located in South Kordofan State. The concentration of Ca, Fe, V, Mn,Ni, Cu, Zn, Cs, Sr, Zr, Y and Pb in sludge and scale samples have been determined using energy dispersive x-ray fluorescence (EDXRF) equipped with a point source of 1 09C d. The concentration of Ca and Fe in scale samples were found to fall in range of 15,49-23.28% and 0.98-5.13%, respectively. The a verge elemental concentrations of Ti, Mn, Ni, Cu, Zn, Sr,Y, and Pb in scale samples were 2917.8, 567.74, 23.21, 23.05, 101.67, 31.38, 177.06 and 24.12 (mg/kg), respectively. The concentrations of Ca and Fe in sludge samples ranged from 1.98-8.82% and 0.71-5.19%, respectively and the a verge elemental concentrations of Cs, V, Mn,Cu, Zn, Pb, Sr, Y and Zr were 7.44, 92,59, 557.36, 7.67, 162.72,28.67, 65.02, 45.64 and 52.15 (mg/kg), respectively. Correlation analysis revealed lock of any significant correlation between elemental concentrations in sludge and scales. (Author)

  8. [A socio-economic profile of exposed populations to petroleum exploration residues].

    Science.gov (United States)

    Corrêa, Gyselle Guimarães; Malhão, Thainá Alves; Asmus, Carmen Ildes Rodrigues Fróes; Coeli, Cláudia Medina

    2011-09-01

    Environmental Macro-Area Five (EMA-5) is located in Rio de Janeiro. Their municipalities are suffering the consequences of rapid urbanization, especially after the discovery of large reserves of petroleum and natural gas (PNG) in the Campos Basin. To describe the socio-economic profile of the region and compare their indicators in space and time. This is an ecological study, which made comparisons between the 11 municipalities of EMA-5. It is based on the behavior of the indicators before and after the increase in royalties and special participatioms (RPE) and the division of the production areas of PNG (main production area - MPA - and the border zone of MPA, BZMPA). The period of analysis of the indicators ranged from 1991 to 2005. Higher values of gross domestic product per capita were found in the municipalities of MPA, especially Macaé. The same occurred in the RPE per capita, especially Rio das Ostras (higher value) and Nova Friburgo (lower value). In 2004, more than 50% of total revenues of municipalities were dependent on the funds derived from royalties. In 2000, Nova Friburgo had the best Human Development Index. The highest value of the Quality Index of Municipalities Potential for Development was found in Macaé. The major indexes of Social Exclusion was found in Macaé, Nova Friburgo and Rio das Ostras. It was found, in the municipalities of MPA, economic growth with great exclusive reliance on royalties. It should invest in alternative economic activities for which there is no damage to the population with the completion of these resources.

  9. Proceedings of the 2002 Petroleum Society of CIM/SPE/CHOA International Thermal Operations and Heavy Oil Symposium, International Conference on Horizontal Well Technology, and Canadian Heavy Oil Association Business Conference : Resources 2 Reserves 2 Results. CD ROM ed.

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    This three day conference combined the Petroleum Society's International Horizontal Well and Technology Conference, the Society of Petroleum Engineer's (SPE) International Thermal Operations and Heavy Oil Symposium, and the Canadian Heavy Oil Association's (CHOA) Annual Business Meeting. The 87 presentations covered all aspects of heavy oil, thermal, and horizontal well technology from geosciences and drilling to economics and environment. The themes included financing, turning projects into results, eliminating the downstream barriers to oil sand development in North America and the world, and emerging technologies for horizontal or heavy oil applications. The conference included the following 20 sessions: (1) thermal operations/engineering, (2) well testing/productivity of horizontal wells, (3) heavy oil operations, (4) environmental aspects of heavy oil projects, (5) upgrading/pipelines, (6) economics and project appraisal, (7) simulation studies of thermal projects, (8) multilaterals, (9) horizontal wells in conventional reservoirs, (10) cold production of heavy oil, (11) horizontal drilling in thermal projects, (12) simulation studies of horizontal wells, (13) horizontal drilling technology, (14) thermal field studies and horizontal wells in heavy oil, (15) completion/production technology of horizontal and thermal wells, (16) physics and PVT of heavy oil recovery processes, (17) reservoir characterization/geosciences, (18) horizontal injectors/produced water technology, (19) emerging technologies, and (20) reservoir geomechanics/fracturing. Tutorials were also organized to provide opportunity to review areas that have undergone major changes. A total of 73 papers were indexed separately for inclusion in the database. refs., tabs., figs.

  10. Heavy metal immobilization in soil near abandoned mines using eggshell waste and rapeseed residue.

    Science.gov (United States)

    Lee, Sang Soo; Lim, Jung Eun; El-Azeem, Samy A M Abd; Choi, Bongsu; Oh, Sang-Eun; Moon, Deok Hyun; Ok, Yong Sik

    2013-03-01

    Heavy metal contamination of agricultural soils has received great concern due to potential risk to human health. Cadmium and Pb are largely released from abandoned or closed mines in Korea, resulting in soil contamination. The objective of this study was to evaluate the effects of eggshell waste in combination with the conventional nitrogen, phosphorous, and potassium fertilizer (also known as NPK fertilizer) or the rapeseed residue on immobilization of Cd and Pb in the rice paddy soil. Cadmium and Pb extractabilities were tested using two methods of (1) the toxicity characteristics leaching procedure (TCLP) and (2) the 0.1 M HCl extraction. With 5 % eggshell addition, the values of soil pH were increased from 6.33 and 6.51 to 8.15 and 8.04 in combination with NPK fertilizer and rapeseed residue, respectively, compared to no eggshell addition. The increase in soil pH may contribute to heavy metal immobilization by altering heavy metals into more stable in soils. Concentrations of TCLP-extracted Cd and Pb were reduced by up to 67.9 and 93.2 % by addition of 5 % eggshell compared to control. For 0.1 M HCl extraction method, the concentration of 0.1 M HCl-Cd in soils treated with NPK fertilizer and rapeseed residue was significantly reduced by up to 34.01 and 46.1 %, respectively, with 5 % eggshell addition compared to control. A decrease in acid phosphatase activity and an increase in alkaline phosphatase activity at high soil pH were also observed. Combined application of eggshell waste and rapeseed residue can be cost-effective and beneficial way to remediate the soil contaminated with heavy metals.

  11. Study of structure and residual stresses in cold rotary swaged tungsten heavy alloy

    Czech Academy of Sciences Publication Activity Database

    Kunčická, L.; Kocich, R.; Hervoches, Charles; Macháčková, A.

    2017-01-01

    Roč. 705, č. 9 (2017), s. 25-31 ISSN 0921-5093 R&D Projects: GA MŠk LM2015056 Institutional support: RVO:61389005 Keywords : Tungsten heavy alloy * residual stresses * neutron scattering * electron microscopy * work hardening Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 3.094, year: 2016

  12. Treatment of Petroleum Sludge By Using Solidification/Stabilization (S/S) Method : Effect of Hydration Days to Heavy Metals Leaching and Strength

    Science.gov (United States)

    Murshid, N.; Kamil, N. A. F. M.; Kadir, A. A.

    2018-04-01

    Petroleum sludge is one of the major solid wastes generated in the petroleum industry. Generally, there are numbers of heavy metals in petroleum sludge and one treatment that is gaining prominence to treat a variety of mixed organic and inorganic waste is solidification/stabilization (S/S) method. The treatment protects human health and the environment by immobilizing contaminants within the treated material and prevents migration of the contaminants. In this study, solidification/stabilization (S/S) method has been used to treat the petroleum sludge. The comparison of hydration days, namely, 7th and 28th days in these cement-based waste materials were studied by using Synthetic Precipitate Leaching Procedure (SPLP). The results were compared to the United States Environmental Protection Agency (USEPA) standards. The results for leaching test concluded that less percentage OPC gave maximum concentration of heavy metals leaching due to deficient in Calcium Oxide (CaO), which is can caused weak solidification in the mixture. Physical and mechanical properties conducted such as compressive strength and density test. From the results, it shows addition up to of 30percentage PS give results which comply with minimum landfill dispose limit. The results shows correlation between strength and density are strong regression coefficient of 82.7%. In conclusion, S/S method can be alternative disposal method for PS in the same time complies with standard for minimum landfill disposal limit. The results for leaching test concluded the less OPC percentage gave maximum concentration of heavy metals leaching.

  13. New heavy aggregate for offshore petroleum pipeline concrete coating Central West Sinai, Egypt

    Directory of Open Access Journals (Sweden)

    M.I. Abdou

    2014-12-01

    Full Text Available In this paper the local materials used in concrete mix are studied in a manner that they can resist the aggressive marine environment and mechanical damage, which can occur at several stages during transportation, construction and installation of the pipelines. In earlier studies we succeeded in finding the Egyptian ilmenite ore adequate for concrete weight coating and already utilized for many pipeline projects in Egypt. According to the presence of about 30% titanium oxides in ilmenite composition which may be extracted to be used in others strategically fields, the object of this paper is to study and evaluate the mechanical, chemical and physical properties of another local hematite high density iron ore to be used in subsea concrete weight coating for offshore petroleum pipelines. The results indicate that the local material of Um Bogma hematite iron ore can substitute both imported iron ore and local ilmenite from Abu Ghalaga in this field to reduce the cost effective and increased economical value of local ores. Laboratory and field tests were conducted for the hematite ore forming a concrete mix, composed of hematite ore, cement and fresh water according to international concrete coating specification requirements, the ore produces a concrete mix with 190–195 pcf minimum dry density and compressive strength, after 28 days of hydration, varying from 40 to 45 N/mm2 (400–450 kg/cm2 which comply with the international standards and specifications of submarine petroleum pipeline coating. In addition, local hematite shows superior results than local ilmenite and achieves 190 pcf instead of 180 pcf in case of using ilmenite.

  14. Petroleum residue upgrading with dispersed catalysts. Part 1. Catalysts activity and selectivity

    Energy Technology Data Exchange (ETDEWEB)

    Panariti, N.; Del Bianco, A.; Del Piero, G. [ENITECNOLOGIE S.p.A, Via Maritano 26, 20097 San Donato Mil. (Italy); Marchionna, M. [SNAMPROGETTI S.p.A, Via Maritano 26, 20097 San Donato Mil. (Italy)

    2000-12-04

    The results of a study aimed at the identification of the relevant chemical aspects involved in the process of upgrading heavy feedstocks in the presence of dispersed catalysts are discussed. The catalytic activity of different compounds was compared in terms of products yields and quality. Moreover, a detailed and systematic characterization of the catalysts recovered at the end of the reactions was achieved. The experimental work provided quite a large set of data, allowing to investigate the factors that may affect catalyst activity (precursor solubility, rate of activation, degree of dispersion, presence of promoters, etc.). The results of this study demonstrate that the best performances are obtained by the microcrystalline molybdenite generated in situ by oil-soluble precursors. The nature of the organic ligand does not play a very relevant role in influencing the hydrogenation activity. The presence of phosphorus, however, significantly enhances hydrodemetallation, at least in terms of vanadium removal. Bimetallic precursors show a slight synergistic effect towards the hydrodesulfurization reaction. Microsized powdered catalyst precursors have a much lower catalytic activity compared to the oil-soluble ones.

  15. Novel synthesis and applications of Thiomer solidification for heavy metals immobilization in hazardous ASR/ISW thermal residue.

    Science.gov (United States)

    Baek, Jin Woong; Mallampati, Srinivasa Reddy; Park, Hung Suck

    2016-03-01

    The present paper reports the novel synthesis and application of Thiomer solidification for heavy metal immobilization in hazardous automobile shredder residues and industrial solid waste (ASR/ISW) thermal residues. The word Thiomer is a combination of the prefix of a sulfur-containing compound "Thio" and the suffix of "Polymer" meaning a large molecule compound of many repeated subunits. To immobilize heavy metals, either ASR/ISW thermal residues (including bottom and fly ash) was mixed well with Thiomer and heated at 140°C. After Thiomer solidification, approximately 91-100% heavy metal immobilization was achieved. The morphology and mineral phases of the Thiomer-solidified ASR/ISW thermal residue were characterized by field emission-scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction (XRD), which indicated that the amounts of heavy metals detectable on the ASR/ISW thermal residue surface decreased and the sulfur mass percent increased. XRD indicated that the main fraction of the enclosed/bound materials on the ASR/ISW residue contained sulfur associated crystalline complexes. The Thiomer solidified process could convert the heavy metal compounds into highly insoluble metal sulfides and simultaneously encapsulate the ASR/ISW thermal residue. These results show that the proposed method can be applied to the immobilization of ASR/ISW hazardous ash involving heavy metals. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. The microstructure of petroleum vacuum residue films for bituminous concrete: a microscopy approach.

    Science.gov (United States)

    Sourty, E D; Tamminga, A Y; Michels, M A J; Vellinga, W-P; Meijer, H E H

    2011-02-01

    Selected carbon-rich refinery residues ('binders') mixed with mineral particles can form composite materials ('bituminous concrete') with bulk mechanical properties comparable to those of cement concrete. The microstructural mechanism underlying the remarkable composite properties has been related to the appearance of a rigid percolating network consisting of asphaltenes and mineral particles [Wilbrink M. et al. (2005) Rigidity percolation in dispersions with a structured visco-elastic matrix. Phys. Rev. E71, 031402]. In this paper, we explore the microstructure of thin binder films of varying thickness with a number of microscopic characterization techniques, and attempt to relate the observed microstructure to the distinctive mechanical behaviour. Two binders, only one of which has been proven to be suitable for bituminous concrete were investigated, and their microstructure compared. Both binders show the formation of asphaltene aggregates. The binder suitable for bituminous concrete is distinguished by the fact that the asphaltenes show a stronger tendency towards such aggregation, due to a higher concentration and less stabilization in the maltene phase. They also show a clear affinity to other species (such as waxes) and may act as nucleation sites for crystals and aggregates of those species. © 2010 The Authors Journal compilation © 2010 The Royal Microscopical Society.

  17. Heavy metal, trace element and petroleum hydrocarbon pollution in the Arabian Gulf: Review

    OpenAIRE

    Afnan Mahmood Freije

    2015-01-01

    The Arabian Gulf environmental status was assessed based on studies conducted in Bahrain, Kuwait, Oman, Saudi Arabia, Qatar, and United Arab Emirates (UAE) during 1983–2011. This review examines all sorts of pollutions in the Arabian Gulf area over the last three decades. Approximately 50 published studies were reviewed in order to determine the pollution status in the Arabian Gulf regarding heavy metals and organic substances. Three types of environmental pollutions including marine and coas...

  18. Simultaneous application of chemical oxidation and extraction processes is effective at remediating soil Co-contaminated with petroleum and heavy metals.

    Science.gov (United States)

    Yoo, Jong-Chan; Lee, Chadol; Lee, Jeung-Sun; Baek, Kitae

    2017-01-15

    Chemical extraction and oxidation processes to clean up heavy metals and hydrocarbon from soil have a higher remediation efficiency and take less time than other remediation processes. In batch extraction/oxidation process, 3% hydrogen peroxide (H 2 O 2 ) and 0.1 M ethylenediaminetetraacetic acid (EDTA) could remove approximately 70% of the petroleum and 60% of the Cu and Pb in the soil, respectively. In particular, petroleum was effectively oxidized by H 2 O 2 without addition of any catalysts through dissolution of Fe oxides in natural soils. Furthermore, heavy metals bound to Fe-Mn oxyhydroxides could be extracted by metal-EDTA as well as Fe-EDTA complexation due to the high affinity of EDTA for metals. However, the strong binding of Fe-EDTA inhibited the oxidation of petroleum in the extraction-oxidation sequential process because Fe was removed during the extraction process with EDTA. The oxidation-extraction sequential process did not significantly enhance the extraction of heavy metals from soil, because a small portion of heavy metals remained bound to organic matter. Overall, simultaneous application of oxidation and extraction processes resulted in highly efficient removal of both contaminants; this approach can be used to remove co-contaminants from soil in a short amount of time at a reasonable cost. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration.

    Science.gov (United States)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Hu, Li-Fang; Shen, Dong-Sheng

    2014-05-15

    Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36mm, with preferable conditions being 400rpm rotation speed, 5min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling. Copyright © 2014 Elsevier B.V. All rights reserved.

  20. Pyrolysis of petroleum residues while making use of the hydrogen potential of polymer waste; Pyrolyse von Erdoelrueckstaenden unter Nutzung des Wasserstoffpotentials von Polymerabfaellen

    Energy Technology Data Exchange (ETDEWEB)

    Klemens, I; Butz, T; Rahimian, I; Linde, A [Institut fuer Erdoel- und Erdgasforschung, Clausthal-Zellerfeld (Germany)

    1998-09-01

    The hydrogen potential contained in waste plastics is to be utilized optimally for cracking of petroleum residues. Homogeneous distribution of the plastic particles in the petroleum residue is to ensure short distances between the hydrogen donor and acceptor, a sufficently large reaction surface, and stable mixing for further processing. Apart from homogeneity, another factor of interest is the influence of mixed-in polymer particles on the colloidal stability of the petroleum residue and the physico-chemical properties of the mixtures. With a view to further processing, the mixtures were analyzed for high-temperature stability, flow characteristics, and reaction behaviour during pyrolysis. (orig.) [Deutsch] Ziel dieses Vorhabens ist es, das in den Kunststoffabfaellen vorhandene Wasserstoffpotential optimal fuer eine tiefergehende Spaltung der Erdoelrueckstaende nutzbar zu machen. Durch eine homogene Verteilung der Kunststoffpartikel im Erdoelrueckstand soll ein moeglichst kurzer Transportweg zwischen Wasserstoff-Donor und -Akkzeptor, eine ausreichend grosse Reaktionsoberflaeche und eine fuer weitere Verarbeitungsschritte notwendige stabile Mischung erreicht werden. Ebenso interessant wie die Homogenitaet solcher Gemische ist auch der Einfluss der eingemengten Polymerteilchen auf die Kolloidstabilitaet des Erdoelrueckstandes und die physikalisch-chemischen Eigenschaften der Mischungen. Im Hinblick auf eine technische Weiterverarbeitung werden die Gemische besonders auf ihre Stabilitaet bei erhoehten Temperaturen (Heisslagerstabilitaet), ihr Fliessverhalten sowie ihr Reaktionsverhalten waehrend der Pyrolyse untersucht. (orig.)

  1. Method for evaluationo of the 3D residual stress field from X-ray diffraction measurements on heavy weldments

    International Nuclear Information System (INIS)

    Larsson, L.E.; Sandstroem, R.

    1982-03-01

    A method for evaluation of the three dimensional residual 30 stress distribution in heavy weldmwents has been developed. The evaluation is based on measured stress data at a number of depth levels below the plate surface. The method has been applied to two measurements on heavy weldments of A 553 B steel. Comparison to a previous evaluation shows good agreement. (Authors)

  2. Contamination by heavy metals and petroleum hydrocarbons: a threat to mangroves

    Directory of Open Access Journals (Sweden)

    Thaís dos Santos Alencar

    2016-12-01

    Full Text Available The mangrove ecosystem is one of the most productive ecosystems on the planet with relevant ecological importance. It offers several services such as protection of the coastal region, immobilization of contaminants, as it is a food source and refuge for various organisms. However, mangroves are threatened by human activities. Oil spills in areas close to mangroves, for example, are potential sources for the entry of contaminants such as heavy metals and hydrocarbons. Among other sources of threat, we list industrial waste and sewage, mining and fertilizer use. When they reach the mangroves, these contaminants may cause several negative effects and affect its balance.

  3. Characterization of Flame Cut Heavy Steel: Modeling of Temperature History and Residual Stress Formation

    Science.gov (United States)

    Jokiaho, T.; Laitinen, A.; Santa-aho, S.; Isakov, M.; Peura, P.; Saarinen, T.; Lehtovaara, A.; Vippola, M.

    2017-12-01

    Heavy steel plates are used in demanding applications that require both high strength and hardness. An important step in the production of such components is cutting the plates with a cost-effective thermal cutting method such as flame cutting. Flame cutting is performed with a controlled flame and oxygen jet, which burns the steel and forms a cutting edge. However, the thermal cutting of heavy steel plates causes several problems. A heat-affected zone (HAZ) is generated at the cut edge due to the steep temperature gradient. Consequently, volume changes, hardness variations, and microstructural changes occur in the HAZ. In addition, residual stresses are formed at the cut edge during the process. In the worst case, unsuitable flame cutting practices generate cracks at the cut edge. The flame cutting of thick steel plate was modeled using the commercial finite element software ABAQUS. The results of modeling were verified by X-ray diffraction-based residual stress measurements and microstructural analysis. The model provides several outcomes, such as obtaining more information related to the formation of residual stresses and the temperature history during the flame cutting process. In addition, an extensive series of flame cut samples was designed with the assistance of the model.

  4. Transfer of heavy metals to biota after remediation of contaminated soils with calcareous residues.

    Science.gov (United States)

    Pérez-Sirvent, Carmen; Martínez-Sánchez, Maria Jose; Agudo, Ines; Gonzalez, Eva; Perez-Espinosa, Victor; Belen Martínez, Lucia; Hernández, Carmen; García-Fernandez, Antonio Juan; Bech, Jaime

    2013-04-01

    A study was carried out to evaluate the assimilation of heavy metals by three types of horticultural plants (broccoli, lettuce and leek), different parts of which are destined for human and farm animals consumption (leaves, roots, fruits). Five consecutive crops of each vegetable were obtained in greenhouse. In a second stage, experiments were carried out with rabbits fed with such vegetables. The plants were cultivated in four types of soil. The first one was contaminated by heavy metals (S1), the second was a uncontaminated soil (blank soil) (S2), the third was the material obtained by mixing S1 with residues coming from demolition and construction activities (S3); while the fourth was the result of remediating S1 with lime residues coming from quarries (S4). The total metal content (As, Pb, Cd and Zn) of the soil samples, rizosphere, leached water and vegetable samples, were measured, and both the translocation and bioconcentration factors (TF and BCF, respectively) were calculated. In the second stage, the effect caused in rabbits fed with the vegetables was monitorized using both external observation and the analysis of blood, urine, and the levels of metals in muscles, liver and kidney. The statistical analysis of the results obtained showed that there were no significant differences in the heavy metal levels for the vegetables cultivated in S2, S3 and S4. The results for soil sample S1 did not have a normal distribution since the growing of the vegetables were not homogeneous and also strongly dependent on the type of vegetal. As regards the effect caused in rabbits, significant differences were observed for the animals fed with plants cultivated in S1 compared with the others.

  5. Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration

    International Nuclear Information System (INIS)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Hu, Li-Fang; Shen, Dong-Sheng

    2014-01-01

    Highlights: • The highest metal reduction occurs at a 2.36 mm sieving size. • Washing promotes heavy metal recycling without secondary pollution. • Sieving and washing are environmentally friendly pretreatments for WEEE wastes. - Abstract: Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36 mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36 mm, with preferable conditions being 400 rpm rotation speed, 5 min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling

  6. Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration

    Energy Technology Data Exchange (ETDEWEB)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi [Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012 (China); Hu, Li-Fang [College of Quality and Safety Engineering, China Jiliang University, Hangzhou 310018 (China); Shen, Dong-Sheng, E-mail: shends@zju.edu.cn [Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012 (China)

    2014-05-01

    Highlights: • The highest metal reduction occurs at a 2.36 mm sieving size. • Washing promotes heavy metal recycling without secondary pollution. • Sieving and washing are environmentally friendly pretreatments for WEEE wastes. - Abstract: Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36 mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36 mm, with preferable conditions being 400 rpm rotation speed, 5 min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling.

  7. Spatial distribution and sources of heavy metals and petroleum hydrocarbon in the sand flats of Shuangtaizi Estuary, Bohai Sea of China.

    Science.gov (United States)

    Yang, Xiaolong; Yuan, Xiutang; Zhang, Anguo; Mao, Yuze; Li, Qiang; Zong, Humin; Wang, Lijun; Li, Xiaodong

    2015-06-15

    The concentrations of heavy metals and petroleum hydrocarbons (PHCs) in surface sediments were investigated in the sand flats of Shuangtaizi Estuary, Bohai Sea of China in May, 2013. Ecological risk assessment indicated that most heavy metals cause low ecological risk to the estuarine environment, with the exception of Cd and Hg (considerable and moderate risk, respectively). Principal component analysis in combination with correlation analysis among heavy metals, PHCs and geological factors (e.g., granularity) was used to identify possible sources of pollutants in Shuangtaizi Estuary. Results showed that the main pollution sources of the area come from anthropogenic factors, such as sewage discharge and oil exploitation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Petroleum marketing monthly

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data.

  9. Modeling and simulation of a pseudo-two-phase gas-liquid column reactor for thermal hydrocracking of petroleum heavy fractions

    Directory of Open Access Journals (Sweden)

    E.M. Matos

    2002-07-01

    Full Text Available This work presents a model to predict the behavior of velocity, gas holdup and local concentration fields in a pseudo-two-phase gas-liquid column reactor applied for thermal hydrocracking of petroleum heavy fractions. The model is based on the momentum and mass balances for the system, using an Eulerian-Eulerian approach. Using the k-epsilon model,fluid dynamics accounts for both laminar and turbulent flows, with discrete small bubbles (hydrogen flowing in a continuous pseudohomogeneous liquid phase (oil and catalyst particles. The petroleum is assumed to be a mixture of pseudocomponents, grouped by similar chemical structural properties, and the thermal hydrocracking is taken into account using a kinetic network based on these pseudocomponents.

  10. CFD (Computational Fluid Dynamics) simulators and thermal cracking of heavy oil and ultraheavy residues using microreactor

    Energy Technology Data Exchange (ETDEWEB)

    Jardini, Andre L.; Bineli, Aulus R.R.; Viadana, Adriana M.; Maciel, Maria Regina Wolf; Maciel Filho, Rubens [State University of Campinas (UNICAMP), SP (Brazil). School of Chemical Engineering; Medina, Lilian C.; Gomes, Alexandre de O. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES); Barros, Ricardo S. [University Foundation Jose Bonifacio (FUJB), Rio de Janeiro, RJ (Brazil)

    2008-07-01

    In this paper, the design of microreactor with microfluidics channels has been carried out in Computer Aided Design Software (CAD) and constructed in rapid prototyping system to be used in chemical reaction processing of the heavy oil fractions. The flow pattern properties of microreactor (fluid dynamics, mixing behavior) have been considered through CFD (computational fluid dynamics) simulations. CFD calculations are also used to study the design and specification of new microreactor developments. The potential advantages of using a microreactor include better control of reaction conditions, improved safety and portability. A more detailed crude assay of the raw national oil, whose importance was evidenced by PETROBRAS/CENPES allows establishing the optimum strategies and processing conditions, aiming at a maximum utilization of the heavy oil fractions, towards valuable products. These residues are able to be processed in microreactor, in which conventional process like as hydrotreating, catalytic and thermal cracking may be carried out in a much more intensified fashion. The whole process development involves a prior thermal study to define the possible operating conditions for a particular task, the microreactor design through computational fluid dynamics and construction using rapid prototyping. This gives high flexibility for process development, shorter time, and costumer/task oriented process/product development. (author)

  11. Heavy-residue isoscaling as a probe of the symmetry energy of hot fragments

    International Nuclear Information System (INIS)

    Souliotis, G.A.; Shetty, D.V.; Keksis, A.; Bell, E.; Jandel, M.; Veselsky, M.; Yennello, S.J.

    2006-01-01

    The isoscaling properties of isotopically resolved projectile residues from peripheral collisions of 86 Kr (25 MeV/nucleon) 64 Ni (25 MeV/nucleon), and 136 Xe (20 MeV/nucleon) beams on various target pairs are employed to probe the symmetry energy coefficient of the nuclear binding energy. The present study focuses on heavy projectile fragments produced in peripheral and semiperipheral collisions near the onset of multifragment emission (E * /A=2-3 MeV). For these fragments, the measured average velocities are used to extract excitation energies. The excitation energies, in turn, are used to estimate the temperatures of the fragmenting quasiprojectiles in the framework the Fermi gas model. The isoscaling analysis of the fragment yields provided the isoscaling parameters α that, in combination with temperatures and isospin asymmetries provided the symmetry energy coefficient of the nuclear binding energy of the hot fragmenting quasiprojectiles. The extracted values of the symmetry energy coefficient at this excitation energy range (2-3 MeV/nucleon) are lower than the typical liquid-drop model value ∼25 MeV corresponding to ground-state nuclei and show a monotonic decrease with increasing excitation energy. This result is of importance in the formation of hot nuclei in heavy-ion reactions and in hot stellar environments such as supernova

  12. Dual catalyst system for the hydrocracking of heavy oils and residues

    Energy Technology Data Exchange (ETDEWEB)

    Bellussi, G. [ENI S.p.A., San Donato Milanese (Italy)

    2011-07-01

    One of the major challenges for our and for the future generations is the development of a sustainable energy supply system based mainly on renewable sources with no environmental impact. This task is necessary to limit the negative effects of green-house gas on the hearth and to allows the forecasted population growth. However, it is not yet clear the time span needed to reach the objective. The total world energy consumption in 2008 amounted to 8428 Mtoe. In a reference scenario, this amount is expected to grow to 16790 Mtoe in 2030 and the contribution expected by sources, according to the International Energy Agency, will be: oil 29.8 %, coal 29.1 %, natural gas 21,2 %, nuclear 5.7 %, hydroelectric 2.4 %, others (Renewable and waste, geothermal, solar, wind, tide,..) [1]. This picture indicates that for several decades, we must still rely on fossil fuels, avoid running out of this precious energy reserves of our planet and reducing the environmental damage arising from their use. For these reason there is a growing need for the efficient upgrading of the heavy oil streams for a better utilization of every barrel of oil produced and for bringing to production also the huge reserves of unconventional fossil sources, such as the heavy oils and the tar sands. Since several years many companies have R and D project aimed to the conversion of heavy residues through a hydrocracking slurry technology, which, with respect to other competing technologies, such as those based on fixed or ebullated bed, can convert all the feedstock to distillates, avoiding the production of fuel oil or coke. In this lecture the advancement in this area will be presented and discussed, highlighting the potentiality offered by the improvement of the catalyst system. (orig.)

  13. Recovery of Trace and Heavy Metals from Coal Combustion Residues for Reuse and Safe Disposal: A Review

    Science.gov (United States)

    Kumar, Ashvani; Samadder, Sukha Ranjan; Elumalai, Suresh Pandian

    2016-09-01

    The safe disposal of coal combustion residues (CCRs) will remain a major public issue as long as coal is used as a fuel for energy production. Both dry and wet disposal methods of CCRs create serious environmental problems. The dry disposal method creates air pollution initially, and the wet disposal method creates water pollution as a result of the presence of trace and heavy metals. These leached heavy metals from fly ash may become more hazardous when they form toxic compounds such as arsenic sulfite (As2S3) and lead nitrate (N2O6Pb). The available studies on trace and heavy metals present in CCRs cannot ensure environmentally safe utilization. In this work, a novel approach has been offered for the retrieval of trace and heavy metals from CCRs. If the proposed method becomes successful, then the recovered trace and heavy metals may become a resource and environmentally safe use of CCRs may be possible.

  14. Residual cannabis levels in blood, urine and oral fluid following heavy cannabis use.

    Science.gov (United States)

    Odell, Morris S; Frei, Matthew Y; Gerostamoulos, Dimitri; Chu, Mark; Lubman, Dan I

    2015-04-01

    An understanding of tetrahydrocannabinol (THC) kinetics and residual levels after cannabis use is essential in interpreting toxicology tests in body fluids from live subjects, particularly when used in forensic settings for drug abuse, traffic and interpersonal violence cases. However the current literature is largely based on laboratory studies using controlled cannabis dosages in experienced users, with limited research investigating the kinetics of residual THC concentrations in regular high dose cannabis users. Twenty-one dependent cannabis users were recruited at admission to two residential detoxification units in Melbourne, Australia. After being provided with information about, and consenting to, the study, subjects volunteered to provide once-daily blood, urine and oral fluid (saliva) samples for seven consecutive days following admission, involving cessation and abstinence from all cannabis use. Blood and oral fluid specimens were analysed for THC and urine specimens for the metabolite THC-COOH. In some subjects THC was detectable in blood for at least 7 days and oral fluid specimens were positive for THC up to 78 h after admission to the unit. Urinary THC-COOH concentrations exceeded 1000 ng/mL for some subjects 129 h after last use. The presented blood THC levels are higher and persist longer in some individuals than previously described, our understanding and interpretation of THC levels in long term heavy cannabis users may need to be reconsidered. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

  15. Residual radioactivity guidelines for the heavy water components test reactor at the Savannah River Site

    International Nuclear Information System (INIS)

    Owen, M.B. Smith, R.; McNeil, J.

    1997-04-01

    Guidelines were developed for acceptable levels of residual radioactivity in the Heavy Water Components Test Reactor (HWCTR) facility at the conclusion of its decommissioning. Using source terms developed from data generated in a detailed characterization study, the RESRAD and RASRAD-BUILD computer codes were used to calculate derived concentration guideline levels (DCGLs) for the radionuclides that will remain in the facility. The calculated DCGLs, when compared to existing concentrations of radionuclides measured during a 1996 characterization program, indicate that no decontamination of concrete surfaces will be necessary. Also, based on the results of the calculations, activated concrete in the reactor biological shield does not have to be removed, and imbedded radioactive piping in the facility can remain in place. Viewed in another way, the results of the calculations showed that the present inventory of residual radioactivity in the facility (not including that associated with the reactor vessel and steam generators) would produce less than one millirem per year above background to a hypothetical individual on the property. The residual radioactivity is estimated to be approximately 0.04 percent of the total inventory in the facility as of March, 1997. According to the results, the only radionuclides that would produce greater than 0.0.1-millirem per year are Am-241 (0.013 mrem/yr at 300 years), C-14 (0.022 mrem/yr at 1000 years) and U-238 (0.034 mrem/yr at 6000 years). Human exposure would occur only through the groundwater pathways, that is, from water drawn from, a well on the property. The maximum exposure would be approximately one percent of the 4 millirem per year ground water exposure limit established by the U.S. Environmental Protection Agency. 11 refs., 13 figs., 15 tabs

  16. Characterization of liquid products from the co-cracking of ternary and quaternary mixture of petroleum vacuum residue, polypropylene, Samla coal and Calotropis Procera

    Energy Technology Data Exchange (ETDEWEB)

    M. Ahmaruzzaman; D.K. Sharma [Indian Institute of Technology Delhi, New Delhi (India). Centre for Energy Studies

    2008-08-15

    The co-cracking of the petroleum vacuum residue (XVR) with polypropylene (PP), Samla coal (SC) and Calotropis procera (CL) has been carried out in a batch reactor under isothermal conditions at atmospheric pressure. The liquids obtained by co-cracking have been characterized by Fourier transform infrared spectroscopy, high performance liquid chromatography, {sup 1}H nuclear magnetic resonance (NMR), {sup 13}C NMR, gel permeation chromatography (GPC), and inductively coupled argon plasma analyses. It was found that the liquid products obtained from the co-cracking of ternary and quaternary mixtures of the petroleum vacuum residue with polypropylene, coal and C. procera contained less than 1 ppm of Ni and V. The HPLC analyses indicates that the liquids obtained from the cracking of ternary mixture of XVR+PP+CL were mainly aliphatic in nature (saturates content 87.4%). NMR analyses showed that the aromatic carbon contents decreased (15.0%) in the liquid products derived from the co-cracking of quaternary mixtures of XVR+PP+SC+CL compared to their theoretical averages (taking the averages of aromatic carbon contents of the liquids from XVR, PP, SC and CL individually). The overall results indicated that there exists a definite interaction of reactive species when XVR, PP, SC and CL were co-cracked together. 27 refs., 5 tabs.

  17. Review of preliminary results of the project `Co-cracking of plastics and petroleum residues`; Uebersicht zu den ersten Ergebnissen des Projektes Cocracking von Kunststoffen und Erdoelrueckstand

    Energy Technology Data Exchange (ETDEWEB)

    Uhmann, R; Koepsel, R F; Kuchling, T; Simanjenkov, V [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Energieverfahrenstechnik und Chemieingenieurwesen

    1998-09-01

    Coprocessing of petroleum residues and plastics is a promising technology, although some problems concerning waste plastics must be clarified prior to its implementation. In general, it can be stated that with a careful choice of operating parameter combinations, oil yields will be higher than for thermal treatment of petroleum residues alone (e.g. a 35% yield increase is achieved by adding 25% of plastics, which is a disproportionately high increase). Waste plastics thus become a valuable material for processing. (orig.) [Deutsch] Das untersuchte Coprocessing von VR und Kunststoffen ist ein erfolgversprechender Weg der Kunststoffverwertung und des tiefen Crackens von Erdoelrueckstand. Die Klaerung der mit Altkunststoffen verbundenen Fragen bedarf weiterer Untersuchungen. Allgemein kann festgestellt werden, dass bei entsprechenden Parameterkombinationen bessere Oelausbeuten erzielt werden als bei der thermischen Behandlung von reinem VR. Ein Beispiel dafuer ist in der Abbildung 10 dargestellt. Durch eine 25%-ige Erhoehung der Einsatzstoffmasse durch Kunststoffzugabe wird eine im Vergleich zu reinem VR um ca. 36% hoehere Oelausbeute erzielt, was einer ueberproportionalen Erhoehung entspricht. Altkunststoff wird bei diesem Prozess unter Nutzung des Wasserstoff-potentials von Polymeren zu einem wertvollen Einsatzstoff. (orig.)

  18. Petroleum marketing annual 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-24

    The Petroleum Marketing Annual (PMA) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysis, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the fob and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Annual. For this production, all estimates have been recalculated since their earlier publication in the Petroleum Marketing Monthly (PMM). These calculations made use of additional data and corrections that were received after the PMM publication date.

  19. Petroleum marketing annual 1994

    International Nuclear Information System (INIS)

    1995-01-01

    The Petroleum Marketing Annual (PMA) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysis, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the fob and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Annual. For this production, all estimates have been recalculated since their earlier publication in the Petroleum Marketing Monthly (PMM). These calculations made use of additional data and corrections that were received after the PMM publication date

  20. The Food Safety of Livestock Products (Meatball, Corned Beef, Beef Burger and Sausage Studied from Heavy Metal Residues Contamination

    Directory of Open Access Journals (Sweden)

    E Harlia

    2010-01-01

    Full Text Available The aims of animal husbandry improvements are to increase both the quality and the quantity of livestock production and to ensure the safety of the product. It is necessarry for consumers to pay attention to the food safety of livestock product because it is related to human's health. The research was conducted to determine the food safety of livestock product condition by detecting heavy metal residues on several food products from livestock like meatball, corned beef, burger’s beef, and sausages. This research was explored by using survey's method and purposive technique sampling, then the resulted data were descriptively analyzed. The observed variables were heavy metal contents such as Plumbum (Pb and Cadmium (Cd in which being measured by using AAS (Atomic Absorption Spectrophotometri . The result showed that in general, heavy metal residue of Pb from several livestock products (meatball, corned beef, beef burger, and sausages were smaller than Maximum Residue Limit (MRL, while the Cd’s residue was partly over the MRL concentration, therefore further action has to be taken as it affects the human's health. (Animal Production 12(1: 50-54 (2010 Key words : food safety, MRL, heavy metal Pb, Cd.

  1. Hydrometallurgical recovery of heavy metals from low grade automobile shredder residue (ASR): An application of advanced Fenton process (AFP).

    Science.gov (United States)

    Singh, Jiwan; Lee, Byeong-Kyu

    2015-09-15

    To investigate the leaching and recovery of heavy metals from low-grade automobile shredder residue (ASR), the effects of nitric acid (HNO3) and hydrogen peroxide (H2O2) concentrations, liquid/solid (L/S) ratio, leaching temperature and ASR particle size fractions on the heavy metal leaching rate were determined. The heavy metals were recovered by fractional precipitation and advanced Fenton process (AFP) at different pHs. The toxicity characteristic leaching procedure (TCLP) test was also performed in the residue remaining after heavy metal leaching to evaluate the potential toxicity of ASR. The heavy metal leaching efficiency was increased with increasing HNO3 and H2O2 concentrations, L/S ratio and temperature. The heavy metal leaching efficiencies were maximized in the lowest ASR size fraction at 303 K and L/S ratio of 100 mL/g. The kinetic study showed that the metal leaching was best represented by a second-order reaction model, with a value of R(2) > 0.99 for all selected heavy metals. The determined activation energy (kJ/mol) was 21.61, 17.10, 12.15, 34.50, 13.07 and 11.45 for Zn, Fe, Ni, Pb, Cd and Cr, respectively. In the final residue, the concentrations of Cd, Cr and Pb were under their threshold limits in all ASR size fractions. Hydrometallurgical metal recovery was greatly increased by AFP up to 99.96% for Zn, 99.97% for Fe, 95.62% for Ni, 99.62% for Pb, 94.11% for Cd and 96.79% for Cr. AFP is highly recommended for the recovery of leached metals from solution even at low concentrations. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. The influence of baking fuel on residues of polycyclic aromatic hydrocarbons and heavy metals in bread.

    Science.gov (United States)

    Ahmed, M T; Abdel Hadi el-S; el-Samahy, S; Youssof, K

    2000-12-30

    The influence of fuel type used to bake bread on the spectrum and concentrations of some polycyclic aromatic hydrocarbons and heavy metals in baked bread was assessed. Bread samples were collected from different bakeries operated by either electricity, solar, mazot or solid waste and their residue content of PAHs and heavy metals was assessed. The total concentration of PAHs detected in mazot, solar, solid waste and electricity operated bakeries had an average of 320.6, 158.4, 317.3 and 25.5 microgkg(-1), respectively. Samples collected from mazot, solar and solid waste operated bakeries have had a wide spectrum of PAHs, in comparison to that detected in bread samples collected from electricity operated bakeries. Lead had the highest concentrations in the four groups of bread samples, followed by nickel, while the concentrations of zinc and cadmium were the least. The concentration of lead detected in bread samples produced from mazot, solar, solid waste and electricity fueled bakeries were 1375.5, 1114, 1234, and 257.3 microgkg(-1), respectively. Estimated daily intake of PAHs based on bread consumption were 48.2, 28.5, 80. 1, and 4.8 microg per person per day for bread produced in bakeries using mazot, solar, solid waste and electricity, respectively. Meanwhile, the estimated daily intake of benzo (a) pyrene were 3.69, 2.65, 8.1, and 0.81 microg per person per day for bread sample baked with mazot, solar, solid waste and electricity, respectively. The daily intake of lead, based on bread consumption was 291, 200.5, 222, and 46.31 microg per person per day for bread sample baked with mazot, solar, solid waste and electricity, respectively. The present work has indicated the comparatively high level of daily intake of benzo (a) pyrene and lead in comparison to levels reported from many other countries and those recommended by international regulatory bodies. It is probable that residues detected in bread samples are partially cereal-borne but there is strong

  3. Petroleum marketing monthly, May 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-26

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  4. Comparative bioremediation of heavy metals and petroleum hydrocarbons co-contaminated soil by natural attenuation, phytoremediation, bioaugmentation and bioaugmentation-assisted phytoremediation.

    Science.gov (United States)

    Agnello, A C; Bagard, M; van Hullebusch, E D; Esposito, G; Huguenot, D

    2016-09-01

    Biological remediation technologies are an environmentally friendly approach for the treatment of polluted soils. This study evaluated through a pot experiment four bioremediation strategies: a) natural attenuation, b) phytoremediation with alfalfa (Medicago sativa L.), c) bioaugmentation with Pseudomonas aeruginosa and d) bioaugmentation-assisted phytoremediation, for the treatment of a co-contaminated soil presenting moderate levels of heavy metals (Cu, Pb and Zn at 87, 100 and 110mgkg(-1) DW, respectively) and petroleum hydrocarbons (3800mgkg(-1) DW). As demonstrated by plant biomass and selected physiological parameters alfalfa plants were able to tolerate and grow in the co-contaminated soil, especially when soil was inoculated with P. aeruginosa, which promoted plant growth (56% and 105% increase for shoots and roots, respectively) and appeared to alleviate plant stress. The content of heavy metals in alfalfa plants was limited and followed the order: Zn>Cu>Pb. Heavy metals were mainly concentrated in plant roots and were poorly translocated, favouring their stabilization in the root zone. Bioaugmentation of planted soil with P. aeruginosa generally led to a decrease of plant metal concentration and translocation. The highest degree of total petroleum hydrocarbon removal was obtained for bioaugmentation-assisted phytoremediation treatment (68%), followed by bioaugmentation (59%), phytoremediation (47%) and natural attenuation (37%). The results of this study demonstrated that the combined use of plant and bacteria was the most advantageous option for the treatment of the present co-contaminated soil, as compared to natural attenuation, bioaugmentation or phytoremediation applied alone. Copyright © 2015 Elsevier B.V. All rights reserved.

  5. Petroleum marketing monthly

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  6. Petroleum marketing monthly

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    Petroleum Marketing Monthly (PPM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o. b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  7. Petroleum marketing monthly

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  8. Crude oil derived petroleum products in the aquatic environment: priorities for control

    International Nuclear Information System (INIS)

    Grimwood, M.J.

    2001-01-01

    The available data on the environmental fate, behaviour and toxicity of five groups of petroleum products is reviewed and the information used to identify the priority of oil products for pollution control to protect the aquatic environment. The oil product groups comprise gasolines, kerosenes, other light fuel oil distillates, residual heavy fuel oils and lubricating oils. (author)

  9. Long-term performance of anaerobic digestion for crop residues containing heavy metals and response of microbial communities.

    Science.gov (United States)

    Lee, Jongkeun; Kim, Joonrae Roger; Jeong, Seulki; Cho, Jinwoo; Kim, Jae Young

    2017-01-01

    In order to investigate the long-term stability on the performance of the anaerobic digestion process, a laboratory-scale continuous stirred-tank reactor (CSTR) was operated for 1100 days with sunflower harvested in a heavy metal contaminated site. Changes of microbial communities during digestion were identified using pyrosequencing. According to the results, soluble heavy metal concentrations were lower than the reported inhibitory level and the reactor performance remained stable up to OLR of 2.0g-VS/L/day at HRT of 20days. Microbial communities commonly found in anaerobic digestion for cellulosic biomass were observed and stably established with respect to the substrate. Thus, the balance of microbial metabolism was maintained appropriately and anaerobic digestion seems to be feasible for disposal of heavy metal-containing crop residues from phytoremediation sites. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Assessment of heavy metal and petroleum hydrocarbon contamination in the Sultanate of Oman with emphasis on harbours, marinas, terminals and ports.

    Science.gov (United States)

    Jupp, Barry P; Fowler, Scott W; Dobretsov, Sergey; van der Wiele, Henk; Al-Ghafri, Ahmed

    2017-08-15

    The assessment here includes data on levels of contaminants (petroleum hydrocarbons and heavy metals) in sediments and biomonitor organisms, including the eulittoral rock oyster Saccostrea cucullata and subtidal biomonitors, the barnacle Balanus trigonus and the antipatharian coral Antipathes sp., at harbours, marinas, terminals and large ports along the coastline of Oman. TBT levels in harbour and port sediments up to a maximum of 100ppb TBT dry weight are highlighted. Oysters contained concentrations up to 367ppm mg TPH/kg dry weight. The maximum levels of Cd, Cu, Pb and Zn were found in the subtidal sediments and barnacles at the oil tanker loading Single Buoy Mooring stations in Mina Al Fahal. In general, the levels of most of the contaminants analysed are at low to moderate concentrations compared to those in highly contaminated sites such as shipyards and dry docks, but continued monitoring is recommended especially during any dredging campaigns. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Bioremediation of soils contaminated with polycyclic aromatic hydrocarbons, petroleum, pesticides, chlorophenols and heavy metals by composting: Applications, microbes and future research needs.

    Science.gov (United States)

    Chen, Ming; Xu, Piao; Zeng, Guangming; Yang, Chunping; Huang, Danlian; Zhang, Jiachao

    2015-11-01

    Increasing soil pollution problems have caused world-wide concerns. Large numbers of contaminants such as polycyclic aromatic hydrocarbons (PAHs), petroleum and related products, pesticides, chlorophenols and heavy metals enter the soil, posing a huge threat to human health and natural ecosystem. Chemical and physical technologies for soil remediation are either incompetent or too costly. Composting or compost addition can simultaneously increase soil organic matter content and soil fertility besides bioremediation, and thus is believed to be one of the most cost-effective methods for soil remediation. This paper reviews the application of composting/compost for soil bioremediation, and further provides a critical view on the effects of this technology on microbial aspects in contaminated soils. This review also discusses the future research needs for contaminated soils. Copyright © 2015 Elsevier Inc. All rights reserved.

  12. Fate of heavy metals in vertical subsurface flow constructed wetlands treating secondary treated petroleum refinery wastewater in Kaduna, Nigeria.

    Science.gov (United States)

    Mustapha, Hassana Ibrahim; van Bruggen, J J A; Lens, P N L

    2018-01-02

    This study examined the performance of pilot-scale vertical subsurface flow constructed wetlands (VSF-CWs) planted with three indigenous plants, i.e. Typha latifolia, Cyperus alternifolius, and Cynodon dactylon, in removing heavy metals from secondary treated refinery wastewater under tropical conditions. The T. latifolia-planted VSF-CW had the best heavy metal removal performance, followed by the Cyperus alternifolius-planted VSF-CW and then the Cynodon dactylon-planted VSF-CW. The data indicated that Cu, Cr, Zn, Pb, Cd, and Fe were accumulated in the plants at all the three VSF-CWs. However, the accumulation of the heavy metals in the plants accounted for only a rather small fraction (0.09-16%) of the overall heavy metal removal by the wetlands. The plant roots accumulated the highest amount of heavy metals, followed by the leaves, and then the stem. Cr and Fe were mainly retained in the roots of T. latifolia, Cyperus alternifolius, and Cynodon dactylon (TF < 1), meaning that Cr and Fe were only partially transported to the leaves of these plants. This study showed that VSF-CWs planted with T. latifolia, Cyperus Alternifolius, and Cynodon dactylon can be used for the large-scale removal of heavy metals from secondary refinery wastewater.

  13. Hydrogen and energy recovery by gasification of petroleum coke from heavy crude refining; Recuperacion de hidrogeno y energia mediante gasificacion de coques de petroleo provenientes de refinacion de crudos pesados

    Energy Technology Data Exchange (ETDEWEB)

    Paniagua-Rodriguez, J.C [Universidad Michoacana de San Nicolas de Hidalgo, Morelia, Michoacan (Mexico); Jimenez-Garcia, G. [Instituto Tecnologico del Valle de Morelia, Morelia, Michoacan (Mexico); Maya-Yescas, R. [Universidad Michoacana de San Nicolas de Hidalgo, Morelia, Michoacan (Mexico)]. E-mail: rmayay@umich.mx

    2013-03-15

    Heavy oils exhibit high yields to bottom-of barrel products (low commercial value); depending on the metals content and on carbon residue the upgrading of bottoms could follow either hydroprocessing or carbon rejection. In particular the Mexican Maya, which is the most refined crude in Mexico, is upgraded by carbon rejection via delayed coking of vacuum residue. In order to obtain acceptable economic profit, it is necessary to transform that carbon (mainly petroleum coke) into useful higher added value products. Coke gasification could be used to obtain hydrogen and/or energy (preferable electrical), via the reaction of coke molecules with oxygen, carbon dioxide and water. Departing from the empiric formulas of five petroleum cokes, a kinetic scheme that consists of three linearly independent stoichiometric equations was recently developed; by including the enthalpy of each reaction and considering the gasification reactor as adiabatic, it is possible to predict product stream composition and high pressure steam that could be generated by the process. [Spanish] Los crudos pesados exhiben rendimientos altos a productos de-fondo-de-barril (de bajo valor comercial); dependiendo del contenido de metales y del residuo carbonoso, la mejora de fondos puede llevarse a cabo por hidrotratamiento o rechazo de carbon. En particular el crudo Maya, que es el mas refinado en Mexico, se mejora via rechazo de carbon por coquizacion retardada del residuo de vacio. A fin de obtener ganancias aceptables, es necesario transformar ese carbon (coque de petroleo, principalmente) en producto util de alto valor agregado. La gasificacion de coque puede usarse para obtener hidrogeno y/o energia (electrica de preferencia), via la reaccion de moleculas de coque con oxigeno, dioxido de carbono y agua. Recientemente se desarrollo un esquema cinetico que consiste de tres reacciones linealmente independientes, partiendo de las formulas empiricas de cinco coques de petroleo; incluyendo la entalpia

  14. Low-temperature thermal decomposition of heavy petroleum distillates: interconnection between the electrical properties and concentration of paramagnetic centres

    Science.gov (United States)

    Dolomatov, M.; Gafurov, M.; Rodionov, A.; Mamin, G.; González, L. Miquel; Vakhin, A.; Petrov, A.; Bakhtizin, R.; Khairudinov, I.; Orlinskii, S.

    2018-05-01

    Changes of paramagnetic centers (PC) concentration in petroleum dispersed systems (PDS) are studied in the process of low-temperature thermolysis. Complex investigation of physicochemical, rheological and electrophysical properties of high-boiling oil fractions is performed. Based on the analysis of the experimental results it can be concluded that the PDS under investigation can be regarded as amorphous broadband organic semiconductors for which PC plays a role of dopant. It shows the perspectives of the asphaltenes usage as a basis for the photovoltaic devices.

  15. Effects of rapeseed residue on lead and cadmium availability and uptake by rice plants in heavy metal contaminated paddy soil.

    Science.gov (United States)

    Ok, Yong Sik; Usman, Adel R A; Lee, Sang Soo; Abd El-Azeem, Samy A M; Choi, Bongsu; Hashimoto, Yohey; Yang, Jae E

    2011-10-01

    Rapeseed (Brassica napus L.) has been cultivated for biodiesel production worldwide. Winter rapeseed is commonly grown in the southern part of Korea under a rice-rapeseed double cropping system. In this study, a greenhouse pot experiment was conducted to assess the effects of rapeseed residue applied as a green manure alone or in combinations with mineral N fertilizer on Cd and Pb speciation in the contaminated paddy soil and their availability to rice plant (Oryza sativa L.). The changes in soil chemical and biological properties in response to the addition of rapeseed residue were also evaluated. Specifically, the following four treatments were evaluated: 100% mineral N fertilizer (N100) as a control, 70% mineral N fertilizer+rapeseed residue (N70+R), 30% mineral N fertilizer+rapeseed residue (N30+R) and rapeseed residue alone (R). The electrical conductivity and exchangeable cations of the rice paddy soil subjected to the R treatment or in combinations with mineral N fertilizer treatment, N70+R and N30+R, were higher than those in soils subjected to the N100 treatment. However, the soil pH value with the R treatment (pH 6.3) was lower than that with N100 treatment (pH 6.9). Use of rapeseed residue as a green manure led to an increase in soil organic matter (SOM) and enhanced the microbial populations in the soil. Sequential extraction also revealed that the addition of rapeseed residue decreased the easily accessible fraction of Cd by 5-14% and Pb by 30-39% through the transformation into less accessible fractions, thereby reducing metal availability to the rice plant. Overall, the incorporation of rapeseed residue into the metal contaminated rice paddy soils may sustain SOM, improve the soil chemical and biological properties, and decrease the heavy metal phytoavailability. Copyright © 2011 Elsevier Ltd. All rights reserved.

  16. Petroleum marketing monthly, June 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in five sections: Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. The feature article is entitled ``The Second Oxygenated Gasoline Season.`` 7 figs., 50 tabs.

  17. Petroleum marketing monthly, July 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-07-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  18. Evaluation of ground calcite/water heavy media cyclone suspensions for production of residual plastic concentrates.

    Science.gov (United States)

    Gent, Malcolm; Sierra, Héctor Muñiz; Menéndez, Mario; de Cos Juez, Francisco Javier

    2018-01-01

    Viable recycled residual plastic (RP) product(s) must be of sufficient quality to be reusable as a plastic or source of hydrocarbons or fuel. The varied composition and large volumes of such wastes usually requires a low cost, high through-put recycling method(s) to eliminate contaminants. Cyclone separation of plastics by density is proposed as a potential method of achieving separations of specific types of plastics. Three ground calcite separation medias of different grain size distributions were tested in a cylindrical cyclone to evaluate density separations at 1.09, 1.18 and 1.27 g/cm 3 . The differences in separation recoveries obtained with these medias by density offsets produced due to displacement of separation media solid particles within the cyclone caused by centrifugal settling is evaluated. The separation density at which 50% of the material of that density is recovered was found to increase from 0.010 to 0.026 g/cm 3 as the separation media density increased from 1.09 to 1.27 g/cm 3 . All separation medias were found to have significantly low Ep 95 values of 0.012-0.033 g/cm 3 . It is also demonstrated that the presence of an excess content of 75%) resulted in reduced separation efficiencies. It is shown that the optimum separations were achieved when the media density offset was 0.03-0.04 g/cm 3 . It is shown that effective heavy media cyclone separations of RP denser than 1.0 g/cm 3 can produce three sets of mixed plastics containing: PS and ABS/SAN at densities of >1.0-1.09 g/cm 3 ; PC, PMMA at a density of 1.09-1.18 g/cm 3 ; and PVC and PET at a density of >1.27 g/cm 3 . Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Metal accumulation in the polychaete Hediste japonica with emphasis on interaction between heavy metals and petroleum hydrocarbons

    International Nuclear Information System (INIS)

    Sun Fuhong; Zhou Qixing

    2007-01-01

    The accumulation of cadmium (Cd) and copper (Cu) in the polychaete Hediste japonica exposed to the mixture of Cd (or Cu) and petroleum hydrocarbons (PHCs) was investigated and compared with that exposed to single Cd (or Cu). The increased bioavailability of Cd or Cu with exposure concentrations resulted in an increase in the accumulation and net accumulation rate of Cd or Cu during single metal exposure. The net accumulation rate of Cd increased, but the net accumulation rate of Cu decreased with exposure time during single metal exposure, suggesting that H. japonica could actively regulate Cu burden in their body by inhibition of absolute uptake or promotion of excretion. The interactions between Cd (or Cu) and PHCs had complicated influences on the net accumulation rate of Cd and Cu in H. japonica under the condition of the binary mixture, which are dependent on their concentration combinations and exposure time. - The influences of petroleum hydrocarbons on Cd and Cu accumulation in H. japonica depend on their concentration combinations and exposure time

  20. Total petroleum hydrocarbons and heavy metals in the surface sediments of Bohai Bay, China: long-term variations in pollution status and adverse biological risk.

    Science.gov (United States)

    Zhou, Ran; Qin, Xuebo; Peng, Shitao; Deng, Shihuai

    2014-06-15

    Surface sediments collected from 2001 to 2011 were analyzed for total petroleum hydrocarbons (TPH) and five heavy metals. The sediment concentration ranges of TPH, Zn, Cu, Pb, Cd and Hg were 6.3-535 μg/g, 58-332 μg/g, 7.2-63 μg/g, 4.3-138 μg/g, 0-0.98μg/g, and 0.10-0.68 μg/g, respectively. These results met the highest marine sediment quality standards in China, indicating that the sediment was fairly clean. However, based on the effects range-median (ERM) quotient method, the calculated values for all of the sampling sites were higher than 0.10, suggesting that there was a potential adverse biological risk in Bohai Bay. According to the calculated results, the biological risk decreased from 2001 to 2007 and increased afterwards. High-risk sites were mainly distributed along the coast. This study suggests that anthropogenic influences might be responsible for the potential risk of adverse biological effects from TPH and heavy metals in Bohai Bay. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Uptake of Heavy Metal Residues from Sewerage Sludge in the Milk of Goat and Cattle during Summer Season

    Directory of Open Access Journals (Sweden)

    Bilal Aslam, Ijaz Javed*, Faqir Hussain Khan and Zia-ur-Rahman

    2011-01-01

    Full Text Available Uptake of different heavy metal residues including cadmium (Cd, chromium (Cr, nickel (Ni, led (Pb, arsenic (As, and mercury (Hg were determined in goat and cattle milk collected from two areas, each consisted of three sites. Area 1 was selected in the North-East and Area 2 in the North-West of Faisalabad city along the main sewerage drains. Levels of Cd, Cr, Ni, Pb, As and Hg in the milk of goat and cattle were higher than the most reported values in the literature. The levels of heavy metal residues in the milk of cattle from Area 1 were higher than those present in cattle milk from Area 2. However, in case of goat milk the residual values from Area 1 and Area 2 were non-significantly different. It was concluded that the levels of Cd, Cr, Ni, Pb, As and Hg in the milk of goat and cattle were higher than reported values in the literature.

  2. Coking of residue hydroprocessing catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Gray, M.R.; Zhao, Y.X. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical Engineering; McKnight, C.A. [Syncrude Canada Ltd., Edmonton, AB (Canada); Komar, D.A.; Carruthers, J.D. [Cytec Industries Inc., Stamford, CT (United States)

    1997-11-01

    One of the major causes of deactivation of Ni/Mo and Co/Mo sulfide catalysts for hydroprocessing of heavy petroleum and bitumen fractions is coke deposition. The composition and amount of coke deposited on residue hydroprocessing catalysts depends on the composition of the liquid phase of the reactor. In the Athabasca bitumen, the high molecular weight components encourage coke deposition at temperatures of 430 to 440 degrees C and at pressures of 10 to 20 MPa hydrogen pressure. A study was conducted to determine which components in the heavy residual oil fraction were responsible for coking of catalysts. Seven samples of Athabasca vacuum residue were prepared by supercritical fluid extraction with pentane before being placed in the reactor. Carbon content and hydrodesulfurization activity was measured. It was concluded that the deposition of coke depended on the presence of asphaltenes and not on other compositional variables such as content of nitrogen, aromatic carbon or vanadium.

  3. Releasing characteristics and fate of heavy metals from phytoremediation crop residues during anaerobic digestion.

    Science.gov (United States)

    Lee, Jongkeun; Park, Ki Young; Cho, Jinwoo; Kim, Jae Young

    2018-01-01

    In this study, lab-scale batch tests were conducted to investigate releasing characteristics of heavy metals according to degradation of heavy metal containing biomass. The fate of heavy metals after released from biomass was also determined through adsorption tests and Visual MINTEQ simulation. According to the anaerobic batch test results as well as volatile solids and carbon balance analyses, maximum of 60% by wt. of biomass was degraded. During the anaerobic biodegradation, among Cd, Cu, Ni, Pb, and Zn, only Cu and Zn were observed in soluble form (approximately 40% by wt. of input mass). The discrepancy between degradation ratio of biomass and ratio of released heavy metals mass from biomass was observed. It seems that this discordance was caused by the fate (i.e., precipitated with sulfur/hydroxide or adsorbed onto sorbents) of each heavy metal types in solution after being released from biomass. Thus, releasing characteristics and fate of heavy metal should be considered carefully to predict stability of anaerobic digestion process for heavy metal-containing biomass. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Petroleum marketing annual, 1990

    International Nuclear Information System (INIS)

    1991-01-01

    The Petroleum Marketing Annual contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. (VC)

  5. Heavy Metal Pollution Potential of Zinc Leach Residues Discarded in çinkur Plant

    OpenAIRE

    ALTUNDOĞAN, H. Soner; ERDEM, Mehmet; ORHAN, Ramazan

    1998-01-01

    In this paper, results of the study on heavy metals solubility behaviour of filter cakes from leaching of clinkerized Waelz oxide and flue dust collected during clinkerization in çinkur plant are given. The release of heavy metals into water was investigated by subjecting the cakes to solubility tests systematically. The effect of contact time, pH, liquid/solid ratio and successive extractions on the releasing of heavy metals (Cd, Pb, Mn and Zn) into water was examined and their conc...

  6. Effects of thermal treatment on mineralogy and heavy metal behavior in iron oxide stabilized air pollution control residues

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Bender-Koch, C.; Starckpoole, M. M.

    2000-01-01

    Stabilization of air pollution control residues by coprecipitation with ferrous iron and subsequent thermal treatment (at 600 and 900 °C) has been examined as a means to reduce heavy metal leaching and to improve product stability. Changes in mineralogy and metal binding were analyzed using various...... analytical and environmental techniques. Ferrihydrite was formed initially but transformed upon thermal treatment to more stable and crystalline iron oxides (maghemite and hematite). For some metals leaching studies showed more substantial binding after thermal treatment, while other metals either....... Thermal treatment of the stabilized residues produced structures with an inherently better iron oxide stability. However, the concentration of metals in the leachate generally increased as a consequence of the decreased solubility of metals in the more stable iron oxide structure....

  7. Preparation and adsorption characteristics for heavy metals of active silicon adsorbent from leaching residue of lead-zinc tailings.

    Science.gov (United States)

    Lei, Chang; Yan, Bo; Chen, Tao; Xiao, Xian-Ming

    2018-05-19

    To comprehensively reuse the leaching residue obtained from lead-zinc tailings, an active silicon adsorbent (ASA) was prepared from leaching residue and studied as an adsorbent for copper(II), lead(II), zinc(II), and cadmium(II) in this paper. The ASA was prepared by roasting the leaching residue with either a Na 2 CO 3 /residue ratio of 0.6:1 at 700 °C for 1 h or a CaCO 3 /residue ratio of 0.8:1 at 800 °C for 1 h. Under these conditions, the available SiO 2 content of the ASA was more than 20%. The adsorption behaviors of the metal ions onto the ASA were investigated and the Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models were used to analyze the adsorption isotherm. The result showed that the maximum adsorption capacities of copper(II), lead(II), cadmium(II), and zinc(II) calculated by the Langmuir model were 3.40, 2.83, 0.66, and 0.62 mmol g -1 , respectively. The FT-IR spectra of the ASA and the mean free adsorption energies indicated that ion exchange was the mechanism of copper(II), lead(II), and cadmium(II) adsorption and that chemical reaction was the mechanism of zinc(II) adsorption. These results provide a method for reusing the leaching residue obtained from lead-zinc tailings and show that the ASA is an effective adsorbent for heavy metal pollution remediation.

  8. Petroleum marketing monthly, December 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-05

    This publication provides information and statistical data on a variety of crude oils and refined petroleum products. It presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include domestic first purchase price, f.o.b. and landed cost of imported crude, and refiners` acquisition cost of crude. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane.

  9. New technology for the emulsification of petroleum residuals in water; Nueva tecnologia para la emulsificacion de residuales del petroleo en agua

    Energy Technology Data Exchange (ETDEWEB)

    Peralta, M. Vita; Arriola, Alejandro M.; Sanchez S, Ramon; Manzanares P, Emilio; Romo M, Cesar A.; Yery de Coss P, R. [Instituto de Investigaciones Electricas, Temixco, Morelos (Mexico)

    2001-07-01

    It turns out of interest to Comision Federal de Electricidad and Petroleos Mexicanos to reduce costs of fuel oil, reducing the viscosity of the residues petroleum of high vacuum distillation emulsifying these with water. The parameters that define the characteristics of the emulsions are mainly the relation of their components, viscosity, size and drop distribution and its stability. The experimental work began producing emulsions in form of lots, using samples of approximately 500 milliliters of vacuum residue. In this first stage, at different concentrations, were examined eight different surfactants, as well as combinations among them, also seven different stabilizers were used. With these tests it has been managed to identify the concentrations, as well as the most adequate relations of surfactants and stabilizers for the production of emulsions of vacuum residues in water. The size and drop distribution has been determined by means of an optical LEICA microscope, model DMLS, that has adapted a photographic system in which an emulsion photo is obtained and, later, a system of analysis of images is used for obtaining of the values of the diameter of the drops present in the emulsion. Finally, by means of statistical software the average size of the particles is obtained, as well as the drop size distribution. The tests results of emulsions that remain fluid are shown and an example of the microstructure of an emulsion of vacuum residue-in-water is given. As well as an example of histogram of the drop size distribution of an emulsion of vacuum distillation-in-water, and another one of the viscosity in function of temperature at different cut efforts in one emulsion of vacuum distillate residue-in-water. [Spanish] Resulta de interes para la Comision Federal de Electricidad y Petroleos Mexicanos reducir costos del combustoleo, reduciendo la viscosidad de los residuos de vacio emulsionando estos en agua. Los parametros que definen las caracteristicas de las

  10. Petroleum marketing annual, 1991

    International Nuclear Information System (INIS)

    1992-08-01

    The Petroleum Marketing Annual contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. For this publication, all estimates have been recalculated since their earlier publication in the Petroleum Marketing Monthly (PMM). These calculations made use of additional data and corrections that were received after the PMM publication dates

  11. Petroleum marketing annual 1993

    International Nuclear Information System (INIS)

    1995-01-01

    The Petroleum Marketing Annual (PMA) contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board (f.o.b.) and landed cost of imported crude oil, and the refiners acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. For this publication, all estimates have been recalculated since their earlier publication in the Petroleum Marketing Monthly (PMM). These calculations made use of additional data and corrections that were received after the PMM publication dates

  12. Petroleum marketing annual 1993

    Energy Technology Data Exchange (ETDEWEB)

    1995-01-01

    The Petroleum Marketing Annual (PMA) contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board (f.o.b.) and landed cost of imported crude oil, and the refiners acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. For this publication, all estimates have been recalculated since their earlier publication in the Petroleum Marketing Monthly (PMM). These calculations made use of additional data and corrections that were received after the PMM publication dates.

  13. Utilization of steel, pulp and paper industry solid residues in forest soil amendment: relevant physicochemical properties and heavy metal availability.

    Science.gov (United States)

    Mäkelä, Mikko; Watkins, Gary; Pöykiö, Risto; Nurmesniemi, Hannu; Dahl, Olli

    2012-03-15

    Industrial residue application to soil was investigated by integrating granulated blast furnace or converter steel slag with residues from the pulp and paper industry in various formulations. Specimen analysis included relevant physicochemical properties, total element concentrations (HCl+HNO3 digestion, USEPA 3051) and chemical speciation of chosen heavy metals (CH3COOH, NH2OH·HCl and H2O2+H2O2+CH3COONH4, the BCR method). Produced matrices showed liming effects comparable to commercial ground limestone and included significant quantities of soluble vital nutrients. The use of converter steel slag, however, led to significant increases in the total concentrations of Cr and V. Subsequently, total Cr was attested to occur as Cr(III) by Na2CO3+NaOH digestion followed by IC UV/VIS-PCR (USEPA 3060A). Additionally, 80.6% of the total concentration of Cr (370 mg kg(-1), d.w.) occurred in the residual fraction. However, 46.0% of the total concentration of V (2470 mg kg(-1), d.w.) occurred in the easily reduced fraction indicating potential bioavailability. Copyright © 2011 Elsevier B.V. All rights reserved.

  14. Gender differences in residual effect of prior drop jumps on oxygen uptake during heavy cycling exercise

    Directory of Open Access Journals (Sweden)

    Neringa Baranauskienė

    2017-12-01

    Conclusions: Prior eccentric–concentric exercise of thigh muscles (100 drop jumps accelerates VO2 kinetics at the start and increases VO2 during steady state of heavy cycling only in the male group. So, prior exercise of such type has a higher negative impact on cycling economy in men than in women and this might be related to greater muscle damage and fatigue in physically active male persons after plyometric exercise.

  15. Crude petroleum

    International Nuclear Information System (INIS)

    1990-01-01

    Crude petroleum statistics by country of production, export values and import values from 1983 to 1988 are given. Table A.1 of the Annex includes free market prices and price indices for crude petroleum based on average of Dubai, United Kingdom Brent and Alaska N Slope crude prices (price expressed in dollars/barrel). The data sources are: Crude petroleum United Nations Statistical Office; OPEC Annual Statistical Bulletin, and Petroleum Economist. For trade the sources of data are: National trade statistics; United Nations international trade statistics; International Moneytary Fund (IMF); Organization of the Petroleum Exporting Countries (OPEC); UNCTAD secretariat estimates. Tabs

  16. Evaluation of remediation techniques in soils affected by residual contamination with heavy metals and arsenic.

    Science.gov (United States)

    García-Carmona, M; Romero-Freire, A; Sierra Aragón, M; Martínez Garzón, F J; Martín Peinado, F J

    2017-04-15

    Residual soil pollution from the Aznalcóllar mine spill is still a problem in some parts of the affected area, today converted in the Guadiamar Green Corridor. Dispersed spots of polluted soils, identified by the absence of vegetation, are characterized by soil acid pH and high concentrations of As, Pb, Cu and Zn. Ex situ remediation techniques were performed with unrecovered soil samples. Landfarming, Composting and Biopiles techniques were tested in order to immobilize pollutants, to improve soil properties and to promote vegetation recovery. The effectiveness of these techniques was assessed by toxicity bioassays: Lactuca sativa L. root elongation test, Vibrio fischeri bioluminescence reduction test, soil induced respiration test, and Eisenia andrei survival and metal bioaccumulation tests. Landfarming and Composting were not effective techniques, mainly due to the poor improvement of soil properties which maintained high soluble concentrations of Zn and Cu after treatments. Biopile technique, using adjacent recovered soils in the area, was the most effective action in the reduction of soil toxicity; the improvement of soil properties and the reduction in pollutants solubility were key to improve the response of the tested organisms. Therefore, the mixture of recovered soils with polluted soils in the areas affected by residual contamination is considered a more suitable technique to reduce the residual pollution and to promote the complete soil recovery in the Guadiamar Green Corridor. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Petroleum marketing monthly, August 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-08-15

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product Sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  18. Petroleum marketing monthly, September 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum product sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  19. Near target residues from the peripheral interaction of relativistic heavy ions with bismuth

    International Nuclear Information System (INIS)

    Aleklett, K.; Morrissey, D.J.; Loveland, W.; Moody, K.; Seaborg, G.T.

    1979-01-01

    Isotopic distributions for the near target residues Au and Tl were measured radioanalytically for the reaction of 8.0-GeV 20 Ne ions with 209 Bi. The isotopic production cross section for Au and Tl isotopes were calculated by using a macroscopic abrasion-ablation model and a microscopic intranuclear cascade-evaporation model. The importance of the neutron skin in determining the yield of these products from the peripheral interactions was also explored in the framework of the macroscopic model. 3 figures

  20. The long term release of heavy metals from combustion residues and slags

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, J.N.

    1996-12-31

    This treatise details methodology which may be used to construct a model of the geochemical evolution in a waste repository and the changes in leachate composition over time. The pH and Eh of the leachant, as well as major complexing anions control the leaching of heavy metals over very long times due to solubility constraints. The pH and the Eh of the leachate changes when the buffering capacity of the waste has been exhausted. It is possible that the altered pH and Eh conditions in the leachate at later times may allow leaching of heavy metals at considerably higher concentrations than those present earlier during the leaching process. The model developed requires data which may be obtained from simple laboratory experiments in order to describe the reactive properties of the waste. Because of the complexity of the real system, the model uses `generalised` minerals which react with the inflowing oxygen and acidity to buffer the pH and Eh of the leachant. In this way, the chemistry of the leachant may be modelled without the need for a detailed geochemical description of the waste material. The model is intended to be simple and flexible enough that it may be adapted to different waste types with reasonable ease. The results obtained indicate that the redox and the pH-buffering characteristics of the waste are very important in determining the leaching of trace metals. The results also illustrate the strong influence that diffusional transport of CO{sub 2} and O{sub 2} may have upon the long term leaching behaviour. The model predictions have not, as yet, been reconciled with field leachate measurements. This will form a major part of the continued work with this project 38 refs, 63 figs, 11 tabs

  1. Petroleum Marketing Annual, 1989

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-18

    This report contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for us by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board (f.o.b.) and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 13 figs., 51 tabs.

  2. Analysis and characterization of heavy residues produced in 129Xe + natSn reactions between 8 and 25 AMeV

    International Nuclear Information System (INIS)

    Moisan, J.

    2008-06-01

    Studies with the INDRA multidetector of the 129 Xe + nat Sn reactions showed the unexpected existence of heavy fragments with a charge as large as Z=70. The charges of Xe and Sn are 54 and 50 respectively. Reactions between nuclei with a charge product greater than 2700 are dominated by deep inelastic collisions. For Xe + Sn the product is exactly 2700. After these observations, 129 Xe + nat Sn reactions at 8, 12, 15, 20 and 25 AMeV have been done. It will then be possible to clarify if the heavy residues are formed by an incomplete fusion, massive transfers occurring in deep inelastic collisions or a very asymmetric fission of a compound system. This work will present experimental results obtained by the analysis of these experiments. We will show that heavy residues are formed with a production cross-section of 10 -2 mb. Angular distributions show that the residues can be produced by an incomplete fusion of the projectile and the target. The study of the products in coincidence with the residues shows that a compound system was formed, followed by a fission producing the residue and a lighter fragment. The comparison with a phenomenological model, HIPSE, confirms that the model is valid at these energies

  3. Proceedings of the 3. NCUT meeting on upgrading and refining of heavy oil, bitumen and synthetic crude oil and the 2. symposium on stability and compatibility during the production, transportation and refining of petroleum

    International Nuclear Information System (INIS)

    2003-01-01

    This conference highlights new developments in refining processes for heavy oil, bitumen, and synthetic crudes. The oil sands/heavy oil industry in Canada has grown significantly in the last decade and could triple by 2012 to reach 2.6 million barrels per day. Experts from the petroleum industry, government organizations and technology providers attended this conference which identified technology gaps and areas where improvements are needed. The presentations demonstrated that many new technologies associated with heavy oil bitumen upgrading and refining have posed compatibility and stability challenges for pipeliners, upgraders and refiners. One of the issues addressed at the conference was the effect of upgrading technologies on market price due to the expected increase in production. Another important issue is how production of bitumen can be increased without significantly increasing greenhouse gas emissions from the refineries and upgrading facilities. The sessions of the conference were entitled: new technology developments in bitumen upgrading; secondary upgrading developments and expanded product opportunities; environmental issues and expanded oil sands development; and, stability and compatibility during the production, transportation and refining of petroleum. Twenty six presentations were indexed separately for inclusion in this database. tabs., figs

  4. Degradability of n-alkanes during ex situ natural bioremediation of soil contaminated by heavy residual fuel oil (mazut

    Directory of Open Access Journals (Sweden)

    Ali Ramadan Mohamed Muftah

    2013-01-01

    Full Text Available It is well known that during biodegradation of oil in natural geological conditions, or oil pollutants in the environment, a degradation of hydrocarbons occurs according to the well defined sequence. For example, the major changes during the degradation process of n-alkanes occur in the second, slight and third, moderate level (on the biodegradation scale from 1 to 10. According to previous research, in the fourth, heavy level, when intensive changes of phenanthrene and its methyl isomers begin, n-alkanes have already been completely removed. In this paper, the ex situ natural bioremediation (unstimulated bioremediation, without addition of biomass, nutrient substances and biosurfactant of soil contaminated with heavy residual fuel oil (mazut was conducted during the period of 6 months. Low abundance of n-alkanes in the fraction of total saturated hydrocarbons in the initial sample (identification was possible only after concentration by urea adduction technique showed that the investigated oil pollutant was at the boundary between the third and the fourth biodegradation level. During the experiment, an intense degradation of phenanthrene and its methyl-, dimethyl-and trimethyl-isomers was not followed by the removal of the remaining n-alkanes. The abundance of n-alkanes remained at the initial low level, even at end of the experiment when the pollutant reached one of the highest biodegradation levels. These results showed that the unstimulated biodegradation of some hydrocarbons, despite of their high biodegradability, do not proceed completely to the end, even at final degradation stages. In the condition of the reduced availability of some hydrocarbons, microorganisms tend to opt for less biodegradable but more accessible hydrocarbons.

  5. Petroleum price

    International Nuclear Information System (INIS)

    Chevallier, B.

    2009-01-01

    The 'AFTP' conference on 'petroleum prices' organized by Total last March, tries to explain the different aspects of the crisis we undergo for July 2007 and its consequential effects on the petroleum markets (supply, demand evolvements, impacts on reserves, prices, refining...). (O.M.)

  6. Lasers and petroleum in Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    da Costa, G.; Guerri, G.; Calatroni, J. (Universidad Simon Bolivar, Caracas (Venezuela). Lab. de Optica Cuantica)

    1978-06-01

    The viscosity of heavy hydrocarbons is one reason why conventional drilling methods are insufficient for petroleum extraction in Venezuela at a depth of 1000 m. The Quantum Optics Laboratory of Simon Bolivar University in Caracas is conducting a search for novel perforation and heating tools for petroleum extraction. Basic research is being carried out using a 10 MW TEA-CO/sub 2/ laser. The laser is not only a research tool but a matter of national interests, as petroleum is Venezuela's main export article.

  7. Petroleum marketing monthly, March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-10

    This report for March 1995, provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly. A glossary is included.

  8. Effect of water-washing on the co-removal of chlorine and heavy metals in air pollution control residue from MSW incineration.

    Science.gov (United States)

    Yang, Zhenzhou; Tian, Sicong; Ji, Ru; Liu, Lili; Wang, Xidong; Zhang, Zuotai

    2017-10-01

    The present study systemically investigated the effect of a water-washing process on the removal of harmful chlorides, sulfates, and heavy metals in the air pollution control (APC) residue from municipal solid wastes incineration (MSWI), for sake of a better reuse and disposal of this kind of waste. In addition, the kinetic study was conducted to reveal the releasing mechanism of relevant element in the residue. The results show that, over 70wt.% of chlorides and nearly 25wt.% of sulfates in the residue could be removed by water washing. Based on an economical consideration, the optimal operation conditions for water washing of APC residue was at liquid/solid (L/S) ratio of 3mL:1g and extracting time of 5min. As expected, the concentrations of Co, Cr, Fe, Ni, V and Cu in the washing effluent increased with time during the washing process. However, the extracting regime differs among different heavy metals. The concentrations of Ba and Mn increased firstly but declined afterwards, and concentrations of Pb and Zn gradually declined while Cd and As kept constant with the increase of extracting time. It is worth mentioning that the bubbling of CO 2 into the washing effluent is promisingly effective for a further removal of Pb, Cu and Zn. Furthermore, kinetic study of the water washing process reveals that the extracting of heavy metals during water washing follows a second-order model. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Electrodialytic removal of heavy metals and chloride from municipal solid waste incineration fly ash and air pollution control residue in suspension - test of a new two compartment experimental cell

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor Marie; Magro, Cátia; Guedes, Paula

    2015-01-01

    Municipal solid waste incineration (MSWI) residues such as fly ash and air pollution control (APC) residues are classified as hazardous waste and disposed of, although they contain potential resources. The most problematic elements in MSWI residues are leachable heavy metals and salts. For reuse...... of MSWI residues in for instance concrete, the aim of remediation should be reduction of the heavy metal leaching, while at the same time keeping the alkaline pH, so the residue can replace cement. In this study a MSWI residues were subjected to electrodialytic remediation under various experimental...... heavy metal leaching except when the pH was reduced to a level below 8 for the fly ash. On the other hand, Cr leaching increased by the electrodialytic treatment. Cl leaching from the MSWI residues was less dependent on experimental conditions and was reduced in all experiments compared to the initial...

  10. Petroleum marketing monthly, November 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-11-09

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed costs of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  11. Petroleum marketing monthly, July 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-07-15

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  12. Petroleum marketing monthly, January 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-01

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  13. Petroleum marketing monthly, August 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-10

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  14. Petroleum marketing monthly, February 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-25

    The Petroleum Marketing Monthly is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  15. Petroleum marketing monthly, April 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-04-12

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  16. Petroleum marketing monthly, March 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-22

    The Petroleum Marketing Monthly is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, education institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  17. Petroleum marketing monthly, August 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-11-07

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 12 figs., 49 tabs.

  18. Petroleum marketing monthly, October 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-07

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase prices, the f.o b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates residuals, aviation fuels, kerosene, and propane are presented.

  19. Quantification of heavy metals from residual waste and ashes from the treatment plant of residual water Reciclagua and,effects for the health of those workers which manipulate those residuals

    International Nuclear Information System (INIS)

    Guerrero D, J.J.

    2004-01-01

    concentrations greater than 0.5% in weight, as long as the analysis of plasma emission spectroscopy very low concentrations are identified already that this method causes the destruction of the sample achieving the identification of all the present elements. With the obtained results we are able to compare the concentrations of the metals before and after the leaching and we calculate by this way the percentage of efficiency for each one of the variables that were managed in the development of the study, obtaining the extraction of those toxic, and valuable metals, present in the muds until of 100%. Based on the results we can mention that the workers are exposed to aerosols and powders of these toxic residuals which contain heavy metals. (Author)

  20. Petroleum marketing monthly with data for April 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-05

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data on the Petroleum Marketing Monthly. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: Summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption.

  1. Petroleum marketing monthly, June 1995 with data for March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-16

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: Summary Statistics Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption.

  2. Exports of petroleum products, 1989

    International Nuclear Information System (INIS)

    1990-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1989 calendar year. A discussion of petroleum product imports is included in order to put exports in the context of the overall trade. Exports of the above petroleum products averaged 30,400 m 3 /d in 1989, down 5% from 1988 levels. Motor gasoline shipments showed the largest decrease, down 1,500 m 3 to 7,700 m 3 /d. Export prices for light petroleum products stayed relatively close to USA spot prices except in June and July 1989, when attractive prices were obtained for shipments from the prairie provinces. The heavy fuel oil export price was similar to the USA east coast spot price in 1989, except in December. Canada's petroleum products imports in 1989 were 21,600 m 3 /d, compared to 18,400 m 3 /d in 1988. Imports of heavy fuel oil in eastern Canada rose 36% in 1989 because of industries switching from electricity and the high demand for thermal power generation. The USA remained Canada's largest trading partner in petroleum products. The top single exporter in 1989, as in 1988, was Newfoundland Processing, with a volume of 3,484,500 m 3 . 24 figs., 4 tabs

  3. Effect of field exposure to 38-year-old residual petroleum hydrocarbons on growth, condition index, and filtration rate of the ribbed mussel, Geukensia demissa

    International Nuclear Information System (INIS)

    Culbertson, Jennifer B.; Valiela, Ivan; Olsen, Ylva S.; Reddy, Christopher M.

    2008-01-01

    In September 1969, the Florida barge spilled 700,000 L of No. 2 fuel oil into the salt marsh sediments of Wild Harbor, MA. Today a substantial amount, approximately 100 kg, of moderately degraded petroleum remains within the sediment and along eroding creek banks. The ribbed mussels, Geukensia demissa, which inhabit the salt marsh creek bank, are exposed to the spilled oil. Examination of short-term exposure was done with transplantation of G. demissa from a control site, Great Sippewissett marsh, into Wild Harbor. We also examined the effects of long-term exposure with transplantation of mussels from Wild Harbor into Great Sippewissett. Both the short- and long-term exposure transplants exhibited slower growth rates, shorter mean shell lengths, lower condition indices, and decreased filtration rates. The results add new knowledge about long-term consequences of spilled oil, a dimension that should be included when assessing oil-impacted areas and developing management plans designed to restore, rehabilitate, or replace impacted areas. - Mussels exposed to petroleum in transplant and field experiments exhibited significant long-term effects

  4. Persistent free radicals, heavy metals and PAHs generated in particulate soot emissions and residue ash from controlled combustion of common types of plastic

    International Nuclear Information System (INIS)

    Valavanidis, Athanasios; Iliopoulos, Nikiforos; Gotsis, George; Fiotakis, Konstantinos

    2008-01-01

    The production and use of polymeric materials worldwide has reached levels of 150 million tonnes per year, and the majority of plastic materials are discarded in waste landfills where are burned generating toxic emissions. In the present study we conducted laboratory experiments for batch combustion/burning of commercial polymeric materials, simulating conditions of open fire combustion, with the purpose to analyze their emissions for chemical characteristics of toxicological importance. We used common types of plastic materials: poly(vinyl chloride) (PVC), low and high density poly(ethylene) (LDPE, HDPE), poly(styrene) (PS), poly(propylene) (PP) and poly(ethylene terephthalate) (PET). Samples of particulate smoke (soot) collected on filters and residue solid ash produced by controlled burning conditions at 600-750 deg. C are used for analysis. Emissions of particulate matter, persistent free radicals embedded in the carbonaceous polymeric matrix, heavy metals, other elements and PAHs were determined in both types of samples. Results showed that all plastics burned easily generating charred residue solid ash and black airborne particulate smoke. Persistent carbon- and oxygen-centered radicals, known for their toxic effects in inhalable airborne particles, were detected in both particulate smoke emissions and residue solid ash. Concentrations of heavy metals and other elements (determined by Inductively Coupled Plasma Emission Spectrometry, ICP, method) were measured in the airborne soot and residue ash. Toxic heavy metals, such as Pb, Zn, Cr, Ni, and Cd were relatively at were found at low concentrations. High concentrations were found for some lithophilic elements, such as Na, Ca, Mg, Si and Al in particulate soot and residue solid ash. Measurements of PAHs showed that low molecular weight PAHs were at higher concentrations in the airborne particulate soot than in the residue solid ash for all types of plastic. Higher-ringed PAHs were detected at higher

  5. Persistent free radicals, heavy metals and PAHs generated in particulate soot emissions and residue ash from controlled combustion of common types of plastic.

    Science.gov (United States)

    Valavanidis, Athanasios; Iliopoulos, Nikiforos; Gotsis, George; Fiotakis, Konstantinos

    2008-08-15

    The production and use of polymeric materials worldwide has reached levels of 150 million tonnes per year, and the majority of plastic materials are discarded in waste landfills where are burned generating toxic emissions. In the present study we conducted laboratory experiments for batch combustion/burning of commercial polymeric materials, simulating conditions of open fire combustion, with the purpose to analyze their emissions for chemical characteristics of toxicological importance. We used common types of plastic materials: poly(vinyl chloride) (PVC), low and high density poly(ethylene) (LDPE, HDPE), poly(styrene) (PS), poly(propylene) (PP) and poly(ethylene terephthalate) (PET). Samples of particulate smoke (soot) collected on filters and residue solid ash produced by controlled burning conditions at 600-750 degrees C are used for analysis. Emissions of particulate matter, persistent free radicals embedded in the carbonaceous polymeric matrix, heavy metals, other elements and PAHs were determined in both types of samples. Results showed that all plastics burned easily generating charred residue solid ash and black airborne particulate smoke. Persistent carbon- and oxygen-centered radicals, known for their toxic effects in inhalable airborne particles, were detected in both particulate smoke emissions and residue solid ash. Concentrations of heavy metals and other elements (determined by Inductively Coupled Plasma Emission Spectrometry, ICP, method) were measured in the airborne soot and residue ash. Toxic heavy metals, such as Pb, Zn, Cr, Ni, and Cd were relatively at were found at low concentrations. High concentrations were found for some lithophilic elements, such as Na, Ca, Mg, Si and Al in particulate soot and residue solid ash. Measurements of PAHs showed that low molecular weight PAHs were at higher concentrations in the airborne particulate soot than in the residue solid ash for all types of plastic. Higher-ringed PAHs were detected at higher

  6. The use of nuclear energy for obtaining petroleum

    International Nuclear Information System (INIS)

    Waldmann, H.; Koch, C.; Thelen, H.J.; Kappe, P.

    1982-01-01

    After some basic considerations of petroleum demand, petroleum supply and petroleum reserves, the article gives a survey of the various methods of obtaining petroleum. The use of energy in the form of steam and electricity in the previously used processes and in conventional deposits requires up to 50% of the energy contained in the oil obtained. Now unconventional sources of petroleum (tertiary petroleum, heavy fractions and shale oil) could become of interest to West Germany in the near future. The economy of production can be determined by the energy source used, to a large extent. A series of possibilities are discussed for using nuclear steam raising systems for this purpose. (UA) [de

  7. Monitoring of ground water quality and heavy metals in soil during large scale bioremediation of petroleum hydrocarbon contaminated waste in India: case studies

    OpenAIRE

    Ajoy Kumar Mandal; Atanu Jana; Abhijit Datta; Priyangshu M. Sarma; Banwari Lal; Jayati Datta

    2014-01-01

    Bioremediation using microbes has been well accepted as an environmentally friendly and economical treatment method for disposal of hazardous petroleum hydrocarbon contaminated waste (oily waste) and this type of bioremediation has been successfully conducted in laboratory and on a pilot scale in various countries, including India. Presently there are no federal regulatory guidelines available in India for carrying out field-scale bioremediation of oily waste using microbes. The results of th...

  8. Petroleum hydrocarbons

    International Nuclear Information System (INIS)

    Farrington, J.W.; Teal, J.M.; Parker, P.L.

    1976-01-01

    Methods for analysis of petroleum hydrocarbons in marine samples are presented. Types of hydrocarbons present and their origins are discussed. Principles and methods of analysis are outlined. Infrared spectrometry, uv spectrometry, gas chromatography, mass spectroscopy, and carbon 14 measurements are described

  9. Petroleum under the microscope

    Energy Technology Data Exchange (ETDEWEB)

    Scott, J

    1920-01-01

    Kerogen may have been formed by a gradual change of vegetable matter into kerogen globules that were intimately mixed with clay and other minerals. As these globules accumulated, the more volatile constituents were eliminated, leaving the remainder as a heavy residue. This process is termed inspissation.

  10. Exports of petroleum products, 1987

    International Nuclear Information System (INIS)

    1988-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1987 calendar year. A discussion of petroleum product imports is included in order to put exports in the context of the overall trade. Exports of the above petroleum products averaged 22,200 m 3 /d in 1987, up 15% from 1986 levels. Exports of middle distillates and aviation fuel had the largest gains in 1987. Export prices for light petroleum products stayed relatively close to USA spot prices. The heavy fuel oil price was below the New York spot price in the beginning of 1987 but remained close for the rest of the year. Canada's petroleum products exports were made to 5 countries while imports came from at least 13 countries. The USA remained Canada's largest trading partner in petroleum products. Exports to Japan and the Far East rose ca 60% over 1986. Product outturns for export were 9% of total Canadian refinery throughput. Exports of aviation turbine fuel from Ontario began in April 1987. The top single exporter in Canada was Irving Oil Ltd. with 2,485,000 m 3 . Irving was also the top exporter in 1986. 11 figs., 4 tabs

  11. Exports of petroleum products, 1988

    International Nuclear Information System (INIS)

    1989-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1988 calendar year. A discussion of petroleum product imports is included in order to put exports in the context of the overall trade. Exports of the above petroleum products averaged 32,000 m 3 /d in 1988, up 44% from 1987 levels. Each product except aviation fuel registered increases in export volumes, which reached the highest total volume of the decade. The main reason for the large increase was the first full year of production from the export-directed refinery at Come By Chance, Newfoundland. Export prices for light petroleum products stayed relatively close to USA spot prices. The heavy fuel oil price was mostly above the USA east coast spot price during 1988. Attractive prices on the USA east coast resulted in a few cargoes of middle distillate and motor gasoline shipped from British Columbia. Petroleum products imports came from 12 countries; Quebec had the largest volume of imports in 1988. The USA remained Canada's largest trading partner in petroleum products. Western exporters view the Far East as an ongoing important market. The top single exporter in Canada was Newfoundland Processing, with 32% of the total export volume. 12 figs., 3 tabs

  12. Ecological and health risks assessment and spatial distribution of residual heavy metals in the soil of an e-waste circular economy park in Tianjin, China.

    Science.gov (United States)

    Han, Wei; Gao, Guanghai; Geng, Jinyao; Li, Yao; Wang, Yingying

    2018-04-01

    Ziya Circular Economy Park is the biggest e-waste recycle park in North China before 2011, its function was then transformed in response to regulations and rules. In this paper, investigation was conducted to research the residual concentrations of 14 analytes (12 heavy metals and 2 non-metals) in the surface soil of Ziya Circular Economy Park and surrounding area. Both ecological and health assessments were evaluated using GI (geo-accumulation index) and NPI (Nemerow pollution index), and associated health risk was assessed by using USEPA model. According to the ecological risk assessment, Cu, Sb, Cd, Zn and Co were seriously enriched in the soil of the studied area. The health risk assessment proposed by USEPA indicated no significant health risks to the population. Soil properties, such as pH and organic matter, were found to correlate with the enrichment of heavy metals. Arsenic concentrations in the soil were found positively correlated to dead bacteria concentrations. Spatial distribution of heavy metals revealed that Ziya Circular Economy Park was the dominant pollution source in the studied area. Findings in this study suggest that enough attention should be payed to the heavy metal pollution in Ziya Circular Economy Park. Copyright © 2018 Elsevier Ltd. All rights reserved.

  13. Petroleum apocalypse

    International Nuclear Information System (INIS)

    Cochet, Y.

    2005-09-01

    Oil prices are increasing while current explanations for this phenomenon are no longer satisfactory. The cheap petroleum era is ending and this problem can seriously convulse our lifestyles. Transports, agriculture, plastics, clothes, medicines: petroleum is everywhere. This is why the rise of hydrocarbons price will not be a simple economic shock but the end of the world like the one we know. However, it is still possible to postpone this event to a later date and to limit its effects by the implementation of a new oil sobriety era. This implies to already organize the decay of materials and energy consumption, together with keeping solidarity, democracy and peace up. In this condition only the transition will be less painful. (J.S.)

  14. FRACTURED PETROLEUM RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Abbas Firoozabadi

    1999-06-11

    The four chapters that are described in this report cover a variety of subjects that not only give insight into the understanding of multiphase flow in fractured porous media, but they provide also major contribution towards the understanding of flow processes with in-situ phase formation. In the following, a summary of all the chapters will be provided. Chapter I addresses issues related to water injection in water-wet fractured porous media. There are two parts in this chapter. Part I covers extensive set of measurements for water injection in water-wet fractured porous media. Both single matrix block and multiple matrix blocks tests are covered. There are two major findings from these experiments: (1) co-current imbibition can be more efficient than counter-current imbibition due to lower residual oil saturation and higher oil mobility, and (2) tight fractured porous media can be more efficient than a permeable porous media when subjected to water injection. These findings are directly related to the type of tests one can perform in the laboratory and to decide on the fate of water injection in fractured reservoirs. Part II of Chapter I presents modeling of water injection in water-wet fractured media by modifying the Buckley-Leverett Theory. A major element of the new model is the multiplication of the transfer flux by the fractured saturation with a power of 1/2. This simple model can account for both co-current and counter-current imbibition and computationally it is very efficient. It can be orders of magnitude faster than a conventional dual-porosity model. Part II also presents the results of water injection tests in very tight rocks of some 0.01 md permeability. Oil recovery from water imbibition tests from such at tight rock can be as high as 25 percent. Chapter II discusses solution gas-drive for cold production from heavy-oil reservoirs. The impetus for this work is the study of new gas phase formation from in-situ process which can be significantly

  15. Petroleum marketing monthly, June 1999, with data for March 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-06-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: Initial Estimates; Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. 7 figs., 50 tabs.

  16. Petroleum marketing monthly, May 1998, with data for February 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-05-01

    The Petroleum Marketing Monthly (PMM) provides Information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  17. Petroleum marketing monthly, July 1998 with data for April 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  18. Petroleum marketing monthly: August 1998, with data for May 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-08-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. 7 figs., 50 tabs.

  19. Petroleum marketing monthly, September 1998, with data for June 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  20. Petroleum marketing monthly, December 1998 with data for September 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  1. Petroleum marketing monthly, May 1999, with data for February 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: Initial Estimates; Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. 7 figs., 50 tabs.

  2. Petroleum marketing monthly, January 1999 with data for October 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-01-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  3. Petroleum marketing monthly, July 1999, with data for April 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: initial estimates; summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 70 tabs.

  4. Petroleum marketing monthly, November 1998, with data for August 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: Summary statistics; Crude oil prices; Prices of petroleum products; Volumes of petroleum products; and Prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  5. Petroleum marketing monthly, October 1998, with data for July 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-10-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: Summary statistics; Crude oil prices; Prices of petroleum products; Volumes of petroleum products; and Prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  6. Petroleum marketing monthly, June 1998, with data from March 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-06-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  7. Petroleum marketing monthly, March 1999 with data for December 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.

  8. Petroleum marketing monthly, February 1999 with data for November 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-02-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products are presented in the Petroleum Marketing Monthly in six sections: Initial Estimates; Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. 7 figs., 50 tabs.

  9. Petroleum marketing monthly, September 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-14

    This document designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and for the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  10. Petroleum marketing monthly, June 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-06-10

    This publication is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented.

  11. Use of filler limestone and construction and demolition residues for remediating soils contaminated with heavy metals: an assessment by means of plant uptake.

    Science.gov (United States)

    Banegas, Ascension; Martinez-Sanchez, Maria Jose; Agudo, Ines; Perez-Sirvent, Carmen

    2010-05-01

    A greenhouse trial was carried out to evaluate the assimilation of heavy metals by three types of horticultural plants (lettuce, broccoli and alfalfa), different parts of which are destined for human and animal consumption (leaves, roots, fruits). The plants were cultivated in four types of soil, one uncontaminated (T1), one soil collected in the surrounding area of Sierra Minera (T2), the third being remediated with residues coming from demolition and construction activities (T3) and the four remediated with filler limestone (T4). To determine the metal content, soil samples were first ground to a fine powder using an agate ball mill. Fresh vegetable samples were separated into root and aboveground biomass and then lyophilized. The DTPA-extractable content was also determined to calculate the bioavailable amount of metal. Finally, the translocation factor (TF) and bioconcentration factor (BCF) were calculated. Arsenic levels were obtained by using atomic fluorescence spectrometry with an automated continuous flow hydride generation (HG-AFS) spectrometer and Cd, Pb and Zn was determined by electrothermal atomization atomic absorption spectrometry (ETAAS) or flame atomic absorption spectrometry (FAAS). Samples of the leached water were also obtained and analyzed. According to our results, the retention of the studied elements varies with the type of plant and is strongly decreased by the incorporation of filler limestone and/or construction and demolition residues to the soils. This practice represents a suitable way to reduce the risk posed to the biota by the presence of high levels of heavy metal in soil.

  12. A fundamental research for upgrading heavy oil using syngas as hydrogen source

    Energy Technology Data Exchange (ETDEWEB)

    Yan, D.; Yuan, M.; Sun, X.; Zhao, S. [China Univ. of Petroleum, Beijing (China). State Key Laboratory of Heavy Oil Processing

    2006-07-01

    The stock of heavy oil and residue from petroleum fractions has become more important as a component in supplying demands for fuel and petrochemical feeds. Finding economical means of upgrading heavy oils is extremely important in order to ensure future fuel supply. A number of new technologies for upgrading heavy oils have been evaluated, including residual fluid catalytic cracking (RFCC), hydrogenation, thermal conversion, and solvent deasphalting. However, the commercial application of such technologies is mainly constrained by the metal and residual carbon concentrations that are present in all heavy oils. Conventional technologies used to upgrade vacuum residue (VR) result in heavy coke formation, with a consequential reduction in the life of expensive, high-performance catalysts. The hydro upgrading process can significantly remove the concentration of heteroatom such as sulfur, nitrogen, and metals in the liquid products. This paper investigated upgrading of heavy oil using syngas as an alternative hydrogen source with a dispersed catalyst. The paper discussed the experiment with reference to the feedstock and catalyst precursors; finely dispersed catalysts preparation; experimental apparatus; experimental design and procedure; and analysis. The results were presented in terms of effects of catalyst dispersion; effect of hydro-upgrading heavy oil using syngas as alternative source; and effects of different catalysts on residue hydrocracking. Last, the paper discussed the properties of the hydrocracked oil treated with syngas. The study confirmed the effectiveness of the slurry bed hydrocracking catalyst using syngas as a hydrogen source. 23 refs., 8 tabs., 16 figs.

  13. Petroleum. [Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    1976-01-01

    An introductory chapter of world wide petroleum history is followed by a comprehensive record of the petroliferous basins of Venezuela. Exploration, productivity, production statistics, reserves, geologic structures, and the distribution of oil and gas fields are described separately for the Maracaibo-Falcon basin, Apure-Barinas basin, E. Venezuela basin, and Tuy-Cariaco basin. The descriptions include geographic distribution, geomorphologic outline of the basins, lithology and thickness of sediments, structural development, present structural conditions in which oil and gas fields occur, and their distribution in the basins. Economic factors are discussed in an appendix. 145 references.

  14. Study on molecular modelling of the selectivity of catalysts for heavy petroleum fractions hydrocracking; Etude sur molecule modele des parametres regissant la selectivite des catalyseurs d'hydrocraquage des charges lourdes

    Energy Technology Data Exchange (ETDEWEB)

    Leite, L.

    2000-10-19

    Hydrocracking is a catalytic petroleum refining process that is commonly applied to upgrade the heavier fractions obtained from the distillation of crude oils. Nowadays the European demand for good quality middle distillates (kerosene and gas-oil) is high and one important goal for the refining is to transform selectively feedstocks into middle distillates. To understand how this transformation occurs, studies on model compounds have been investigated. Numerous studies have been devoted to paraffin hydrocracking. However theses molecules do not fully represent heavy petroleum fraction. Taking into account that the trend in the future will be to treat heavier feedstocks containing a large quantity of PNA (Polynuclear Aromatic hydrocarbons), the understanding of their transformation under hydrocracking conditions is a key point. In this study, we studied hydrocracking of phenanthrene over platinum on acid solids catalysts. Our main aim was to compare hydrocracking catalysts in term of catalytic activity and selectivity toward primary products thanks to our model reaction and to correlate these catalytic performances with acid solid properties and especially to rationalize the effects due to the acidity and the porosity of the acid solids. Catalytic experiments emphasised an effect of the porous structure on the selectivities. The acidity of the catalysts seemed to impose the catalytic activity but did not permit to explain the selectivities. This 'effect of the structure' has been clarified with the simulation of intermediate products adsorption and diffusion in the studied structures thanks to a molecular modelling study. Indeed, the selectivities obtained during phenanthrene hydrocracking have been linked up with the intermediate products adsorption energies in the structures. The results of this study permit to propose that the key-step for selectivities determination is the physical desorption of the primary products. (author)

  15. Petroleum industry in 2004

    International Nuclear Information System (INIS)

    2005-01-01

    This document presents a detailed outlook of the petroleum industry in the world and more particularly in France in 2005: evolution of crude oil prices; petroleum exploration and production in the world and in France; the French para-petroleum and petroleum industry; the oil supplies; the refining activities; the evolution of products quality and the substitution fuels; the domestic transports, the storage and consumption of petroleum products; the fiscality, prices and distribution of petroleum products. (J.S.)

  16. Thermal Treatment of Iron Oxide Stabilized APC Residues from Waste Incineration and the Effect on Heavy Metal Binding

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Stackpoole, M.; Bender-Koch, C.

    2000-01-01

    Iron oxide stabilized APC residues from MSWI were heat treated at 600°C and 900°C. The thermal treatments resulted in a change in product stability by forcing a transformation in the mineralogical structures of the products. The treatments, moreover, simulated somewhat the natural aging processes...

  17. Heavy Metal Residues in Soil and Accumulation in Maize at Long-Term Wastewater Irrigation Area in Tongliao, China

    Directory of Open Access Journals (Sweden)

    Yintao Lu

    2015-01-01

    Full Text Available Soil and plant samples were collected from Tongliao, China, during the maize growth cycle between May and October 2010. Heavy metals, such as Cr, Pb, Ni, and Zn, were analyzed. The concentrations of Cr, Pb, Ni, and Zn in the wastewater-irrigated area were higher than those in the topsoil from the groundwater-irrigated area. The concentrations of metals in the maize increased as follows: Pb < Ni < Zn < Cr. In addition, Cr, Pb, and Ni mainly accumulated in the maize roots, and Zn mainly accumulated in the maize fruit. The results of translocation factors (TF and bioconcentration factors (BCF of maize for heavy metals revealed that maize is an excluder plant and a potential accumulator plant and can serve as an ideal slope remediation plant. In addition, the increasing heavy metal contents in soils that have been polluted by wastewater irrigation must result in the accumulation of Cr, Pb, Ni, and Zn in maize. Thus, the pollution level can be decreased by harvesting and disposing of and recovering the plant material.

  18. Gasification in petroleum refinery of 21. century; La gazeification dans la raffinerie du petrole du 21. siecle

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E. [IMAF Group, Ottawa, Ontario (Canada)

    1999-07-01

    The worldwide trends in the crude oil supply indicate a continuous increase of the heavy crudes. The increase in the yield of distillation residues is complemented by an increase in their sulfur content. Additional distillates are produced by upgrading the residues. The upgrading step generates final residues, such as visbreaking tar, coke and asphalt which are produced by visbreaking, coking and de-asphalting, respectively. The final residues can be converted to usable products such as hydrogen, steam, electricity, ammonia and chemicals. For this purpose, gasification has emerged as the technology of choice because of its superior environmental performance when compared with the competing means for residue utilization. Also, refinery sludges can be co-gasified with the final residues and as such, be converted to usable products. If integrated with the petroleum refinery, gasification can diminish any environmental problems associated with residue and sludge disposal. The economic indicators of the refinery can improve as well. The trends in deregulation of the power market enable petroleum refineries to enter this lucrative market either alone or in a partnership with the utilities. The potential of co-production of chemicals and steam with electricity offers the flexibility to respond to market demands. Gasification technology is commercially proven. Among several types, entrained bed gasifiers are the gasifiers of choice. A number of commercial projects in Europe, Asia and United States use a gasifier employing either a slurry feeding system or a dry feeding system. (author)

  19. Petroleum hydrocarbon concentration in sediments along northern west coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Ram, A.; Kadam, A.N.

    Gas chromatography revealed that nonpolar material extracted from surface sediments collected along the northern west coast of India was originated from petroleum hydrocarbon residue. Petroleum hydrocarbon levels as determinEd. by fluorescence...

  20. Depletion of penicillin G residues in heavy sows after intramuscular injection. Part II: application of kidney inhibition swab tests.

    Science.gov (United States)

    Shelver, Weilin L; Lupton, Sara J; Newman, David J; Larsen, Steven; Smith, David J

    2014-07-30

    Sows (n = 126; 228 ± 30.1 kg) were administered daily IM doses of penicillin G procaine (33 000 IU/kg bw; 5× the label dose) for 3 consecutive days using three different administration patterns. Within treatment, six sows each were slaughtered on withdrawal day 5, 10, 15, 20, 25, 32, and 39. Tissues (injection site, kidney, liver, skeletal muscle) or body fluids (serum and urine) were screened for penicillin G using the KIS test, recently adopted by the USDA Food Safety and Inspection Service. The IM administration patterns had no discernible effect on penicillin G depletion. Residues were depleted more rapidly from liver and skeletal muscle and more slowly from kidney and urine. Kidney was the most sensitive and suitable tissue for detecting penicillin G residues on-site, with two positive results after a 39-day withdrawal period. Urine was the most suitable ante-mortem surrogate to predict the results of kidney tests.

  1. Field reconnaissance and estimation of petroleum hydrocarbon and heavy metal contents of soils affected by the Ebocha-8 oil spillage in Niger Delta, Nigeria.

    Science.gov (United States)

    Osuji, Leo C; Onojake, Chukunedum M

    2006-04-01

    Field reconnaissance of the Ebocha-8 oil spill-affected site at Obiobi/Obrikom in the Niger Delta region of Nigeria was carried out to assess the extent of damage to the terrestrial ecosystem and delimit the epicenter of oil spillage. Following three successive reconnaissance surveys, the area to be sampled was delimited (200 x 200 m2), and soil samples were collected using the grid method from three replicate quadrats at two depths, surface (0-15 cm) and subsurface (15-30 cm). A geographically similar area located 50 m adjacent to the oil-polluted area was used as a reference (control) site. Total hydrocarbon content (THC) and heavy metal concentrations were later determined in the laboratory by extraction and spetrophotemetric techniques. Generally, the THC of soils at surface and subsurface depths of the oil-polluted plots was 2.06 x 10(4) +/- 4.97 x 10(3) mg/kg and 1.67 x 10(3) +/- 3.61 x 10(2) mg/kg soil, respectively, (no overlap in standard errors at 95% confidence limit) while concentrations of heavy metals(Pb, Cd, V, Cu and Ni) were enhanced, especially at the surface. The high levels of THC and heavy metals may predispose the site, which hitherto served as arable agricultural land, to impaired fertility and possible conflagration. When concentrations of heavy metals reach the levels obtained in this study, they may become toxic to plants or possibly bio-accumulate, thus leading to toxic reactions along the food chain. While the spilled-oil may have contributed to the enhanced levels of the metals in the affected soils, physico-chemical properties of the soils, mobility of metals, and the intense rainfall and flooding that preceded the period of study may have also contributed in part to their enhanced concentrations. The presence of high hydrocarbon content may cause oxygen deprivation, which may result in the death of soil fauna by asphyxiation. There is, therefore, an urgent need to clear the affected site of these excess hydrocarbon deposits so as to

  2. Petroleum geophysics

    Energy Technology Data Exchange (ETDEWEB)

    2010-07-01

    The book is compiled from a series of e-learning modules. GeoCLASS is an e-learning system with contents from petroleum geophysics. It is the result of collaboration between professors at the University of Bergen and the University of Oslo, and its material has been used as curriculum in master program courses at these universities for several years. Using a unique feature to GeoCLASS, these advanced scientific topics are presented on multiple levels. The introductions open the door to this vast pool of knowledge, accessible even for high school students. Enter the door, and you enter the modules. Various levels of content are presented, and the more advanced levels can be shielded from the regular user, and only accessed by those with particular interest. The chapters in the book are: Elastic waves; Survey planning; Seismic acquisition; Basic seismic signal theory and processing; Seismic imaging; Seismic attributes; Rock physics; Reservoir monitoring. (AG)

  3. Petroleum and natural gas

    Energy Technology Data Exchange (ETDEWEB)

    060,

    1965-02-01

    Substantial increases in demand for Canadian petroleum and natural gas in both domestic and export markets resulted in another good year throughout the main sectors of the industry. In February, production averaged 850,000 bpd, or about 8% more than 1963 output of crude oil and natural gas liquids. Construction began on the first full scale plant for the extraction of oil from the Athabasca bituminous sands. In 1964, exploratory and development drilling in western Canada increased 10% from the previous year. A total of 15.5 million ft was drilled, the largest since the record drilling year of 1956. The main oil field development areas in Alberta were the House Mountain, Deer Mountain and Goose River Fields, and the Bantry-Taber heavy oil region in southeastern Alberta. Oil reserves were increased substantially by waterflood pressure maintenance projects in many of the older oil fields. The largest oil accumulation discovered in 1964 was the Syvia-Honda Field in the Devonian Gilwood sandstone in N.-central Alberta. Two graphs illustrate the crude petroleum in Canada in millions of barrels from 1940 to 1964, and natural gas in Canada in billions of cu ft from 1950 to 1964. The outlook for the industry in 1965 is good.

  4. Production of heavy evaporation residues in the reactions induced by an extracted 48Ca beam on a 208Pb target

    International Nuclear Information System (INIS)

    Eremin, A.V.; Chepigin, V.I.; Itkis, M.G.

    1998-01-01

    The production cross sections of the isotopes 253-255 No were measured for the heavy ion complete fusion reaction 48 Ca + 208 Pb using the electrostatic recoil separator VASSILISSA. The obtained excitation functions for the reaction products formed after the evaporation of 1-3 neutrons from the compound nucleus are discussed and compared with the data obtained earlier and with the results of the statistical model calculations. The background conditions at the extraction of the correlated events of the reaction product decay are also considered from the point of view of future experiments on the superheavy element synthesis in the complete fusion reactions induced by 48 Ca projectiles

  5. Analysis of petroleum oily sludge producing in petroleum field of Rio Grande do Norte, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Cicero de Souza; Lima, Regineide Oliveira; Silva, Edjane Fabiula Buriti da; Castro, Kesia Kelly Vieira de; Chiavone Filho, Osvaldo; Araujo, Antonio Souza de [Universidade Federal do Rio Grande do Norte (UFRN), RN (Brazil)

    2012-07-01

    In exploration and production of petroleum is generated solid waste different and components other. The petroleum oily sludge is a complex mix of components different (water, oil and solid). The petroleum oily sludge generally has other residues and is formed during production and operations, transport, storage and petroleum refining (atmospheric residue, vacuum residue and catalytic cracking residue). However, according to its origin, the compositions can be found quite varied for sludge. Observing the process steps production and refining is possible to locate its main sources and percentage contributions in terms of waste generation. The elemental analysis was performed with oily sludge from region and it showed different composition. For carbon element and hydrogen, small differences was observed, but for was observed greater differences for Oxygen element. The sludge has different inorganic and organic composition. The sludge from oil water separator (OWS) 2 showed a greater amount of oil (94.88%), this may indicate a residue of aggregate high for petroleum industry. In analysis of Saturates, Aromatics, Resins and Asphaltenes (SARA), the sludge from unloading showed amount high of saturates. The inorganic material separated from sludge was characterized and sludge from OWS 2 had high amount sulfur (41.57%). The sludge analyzed showed organic components high values, so it can be treated and reprocessed in process units petroleum industry. The analysis thermal degradation had a better setting for treated oily sludge. (author)

  6. A semi-exclusive study of heavy-residue production in the 40Ar+Ag reaction at 35 MeV/u incident energy

    International Nuclear Information System (INIS)

    Bizard, G.; Brou, R.

    1985-01-01

    Heavy residues created in the reaction Ar+Ag at 35 MeV/u have been detected at various forward angles. Their velocity spectra (quite different from the corresponding spectra measured at 27 MeV/u) show that these events result both from central and peripheral reactions and that the fusion component has dramatically decreased. Coincident light charged particles spectra have been obtained in a large solid angle forward hodoscope. The analysis of these spectra allows to differentiate peripheral and central collisions. The proton spectra are analysed in terms of emitting sources. There is no need for a participant zone in peripheral reactions. Instead protons are emitted either from the target-like or from the projectile-like fragments. However projectile sequential emission is not sufficient to explain all the high energy protons

  7. Petroleum marketing monthly, November 1991. [Contains glossary

    Energy Technology Data Exchange (ETDEWEB)

    1991-11-07

    The Petroleum Marketing Monthly is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 12 figs., 53 tabs.

  8. Petroleum Marketing Monthly, January 1991. [Contains Glossary

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-09

    The Petroleum Marketing Monthly (PMM) is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 12 figs., 55 tabs.

  9. ETBP (Extended True Boiling Point) curve extension of extra heavy crudes; Extensao da curva PEV (Ponto de Ebulicao Verdadeiro) de petroleos extrapesados por destilacao molecular e ampliacao da caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Rodrigo S.; Batistella, Cesar B.; Maciel, Maria Regina W.; Maciel Filho, Rubens [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Quimica; Medina, Lilian C. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2008-07-01

    For the determination of the TBP (True Boiling Point) Curve, which defines the yield of petroleum products, the ASTM D2892 method for petroleum distillation and ASTM D5236 method for vacuum distillation of heavy hydrocarbons were applied. Furthermore, from these distillations, cuts that are submitted to several analyses to determine its physical-chemical properties are obtained, and all this information generates the evaluation of petroleum. For heavy petroleum, these conventional methods have been limited, since the total distilled percentage determined for temperatures up to 565 deg C (maximum reached with ASTM D5236 method) is lower for these oils, reducing the points of the curve, limiting its information. To improve this data set for heavy oils, a methodology for the extension of TBP curve through molecular distillation was established. It was possible to reach values up to 700 deg C, representing a considerable progress for the extension of TBP curve. The objective of this work is to present the results of Extended TBP curve for a heavy petroleum and characterization carried out through the cuts and residues obtained in molecular distillation of the residue 'Zeta' 400 deg C+ (fancy name), made by ASTM D2892 method. (author)

  10. Petroleum 2006. Statistical elements

    International Nuclear Information System (INIS)

    2007-06-01

    This document gathers in 5 parts, the main existing statistical data about petroleum industry in France and in the rest of the world, together with an insight on other energy sources: 1 - petroleum in the French economy (petroleum and other energies, petroleum and transports, petroleum and energy in the industry, the residential and tertiary sectors, environment: 42 pages); 2 - the French petroleum industry (exploration, production, foreign trade, transports, refining, storage, petrochemistry: 66 pages); 3 - the French market of petroleum products (evolution of sales by product and detail by region for the past year: 38 pages); 4 - prices and taxes of petroleum products (world prices and rates for crude and refined products, evolution of fret rates, retail prices and French taxes: 28 pages); 5 - petroleum in the world (world energy production and consumption, detailed petroleum activity by main areas and for the main countries: 112 pages). (J.S.)

  11. Determination of Leacheability of U, Th and Heavy Metals of Water Leached Purification (WLP) Residue and Soil from Bauxite Mining Area using Toxicity Characteristic Leaching Technique

    International Nuclear Information System (INIS)

    Siti Aminah Omar; Suhaimi Hamzah; Shamsiah Abdul Rahman

    2016-01-01

    The study was conducted to analyse the leachability of U, Th and heavy metals Cu, Cd, As, Pb, Mn, Zn, Ba, Se, Cr and Fe of water leached purification (WLP) residue gathered from Lynas Malaysia Sdn Bhd and soil from bauxite mining area, Kuantan. Their toxicity was assessed using the toxicity characteristic leaching procedure (TCLP) developed by the United States Environmental Protection Agency. The concentration of the elements studied was analysed using inductively coupled plasma mass spectrometry (ICP-MS). Results from the analysis indicated that the concentrations for all the elements studied in this project are well below than the TCLP regulatory limit. The concentrations of U and Th in leached solution were between 0.01 - 0.20 Bq/ kg. The concentrations of the multi elements were mostly between 0.02 - 1471 μg/ l, but certain elements such as Fe had concentration as high as 4707 μg/ l. Hence, it can be concluded that the WLP residue from Lynas and soil from bauxite mining area are very stable in the environment and does not pose any environmental problem. (author)

  12. Pesticide residues, heavy metals, and DNA damage in sentinel oysters Crassostrea gigas from Sinaloa and Sonora, Mexico.

    Science.gov (United States)

    Vázquez-Boucard, Celia; Anguiano-Vega, Gerardo; Mercier, Laurence; Rojas del Castillo, Emilio

    2014-01-01

    Pesticides and heavy metals were analyzed in sentinel Crassostrea gigas oysters placed in six aquaculture sites close to a contaminated agricultural region. Each site was sampled twice. Tests revealed the presence of organochlorine (OC) pesticides in the oysters at concentrations varying from 31.8 to 72.5 μg/kg for gamma-hexachlorocyclohexane (γ-HCH); from 1.2 to 3.1 μg/kg for dichlorodiphenyldichloroethylene (4,4-DDE); from 1.6 to 2.3 μg/kg for endosulfan I; and from 1.4 to 41.2 μg/kg for endosulfan II, as well as heavy metals in concentrations that exceeded Mexican tolerance levels (405.5 to 987.8 μg/g for zinc; 4.2 to 7.3 μg/g for cadmium; and 7.2 to 9.9 μg/g for lead). Significant levels of DNA damage in oyster hemocytes were also detected. There was a significant, positive correlation between genotoxic damage and concentration of nickel or the presence of endosulfan II. Cellular viability evaluated by cytotoxic analyses was found to be high at 80%. Marked inhibition in activity of acetylcholinesterase (AChE ) and induction of glutathione S-transferase (GST) activity was noted. Data demonstrated a significant relation between AChE activity inhibition and presence of endosulfan II, γ-HCH, copper, lead, and 4,4-DDE, as well as between AChE and GST activity at different sites.

  13. Figures on petroleum 1981

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    This table taken out from the 1981 annual report 1981 contains an introductory remark on the reorganization of mineral oil statistics up to January 82. It is followed by the tables ranged as follows: refinery capacity and production, crude oil supply, GDR-coverings, import of petroleum products, petroleum consumption, export of petroleum products, transport, oil storage tanks, motor vehicle stock, taxes and tariffs, petroleum export trade, energy consumption and world petroleum numbers. In parts the tables contain comparative figures back to 1950.

  14. Heavy metal water pollution associated with the use of sewage sludge compost and limestone outcrop residue for soil restoration: effect of saline irrigation.

    Science.gov (United States)

    Pérez-Gimeno, Ana; Navarro-Pedreño, Jose; Gómez, Ignacio; Belén Almedro-Candel, María; Jordán, Manuel M.; Bech, Jaume

    2015-04-01

    The use of composted sewage sludge and limestone outcrop residue in soil restoration and technosol making can influence the mobility of heavy metals into groundwater. The use of compost from organic residues is a common practice in soil and land rehabilitation, technosol making, and quarry restoration (Jordán et al. 2008). Compost amendments may improve the physical, chemical, and biological properties of soils (Jordão et al. 2006; Iovieno et al. 2009). However, the use of compost and biosolids may have some negative effects on the environment (Karaca 2004; Navarro-Pedreño et al. 2004). This experiment analyzed the water pollution under an experimental design based on the use of columns (0-30 cm) formed by both wastes. Two waters of different quality (saline and non-saline) were used for irrigation. The presence of heavy metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in the leachates was checked under controlled conditions inside a greenhouse (mean values: 20°±5°C and around 60% relative humidity). Sixteen 30-cm tall columns made of PVC pipe with internal diameters of 10.5 cm were prepared. The columns were filled with one of these materials: either sewage sludge compost (SW) or limestone outcrop residue (LR), fraction (determine if the accumulation of heavy metals in waters may be determinant for future pollution. References: Iovieno P, Morra L, Leone A, Pagano L, Alfani A (2009) Effect of organic and mineral fertilizers on soil respiration and enzyme activities of two Mediterranean horticultural soils. Biol Fert Soils doi:10.1007/s00374-009-0365-z. Jordán MM, Pina S, García-Orenes F, Almendro-Candel MB, García-Sánchez E (2008) Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries. Environ Geol doi:10.1007/s00254-007-0991-4. Jordão CP, Nascentes CC, Cecon PR, Fontes RLF, Pereira JL (2006) Heavy metal availability in soil amended with composted urban solid wastes. Environ Monit

  15. Petroleum Hydrocarbons Contamination Profile of Ochani Stream in ...

    African Journals Online (AJOL)

    Michael Horsfall

    ABSTRACT: Petroleum hydrocarbon contamination profile, heavy metals and .... potential conduits for oil and water migrating from the ... by Gas Chromatography: Soil / sediment / sludge ..... fractions contained in the dump pits) which have.

  16. Characterization of Petroleum Hydrocarbon Decomposing Fungi Isolated from Mangrove Rhizosphere

    Directory of Open Access Journals (Sweden)

    Nuni Gofar

    2011-01-01

    Full Text Available The research was done to obtain the isolates of soil borne fungi isolated from mangrove rhizosphere which were capable of degrading petroleum hydrocarbon compounds. The soil samples were collected from South Sumatra mangrove forest which was contaminated by petroleum. The isolates obtained were selected based on their ability to survive, to grow and to degrade polycyclic aromatic hydrocarbons in medium containing petroleum residue. There were 3 isolates of soil borne hydrocarbonoclastic fungi which were able to degrade petroleum in vitro. The 3 isolates were identified as Aspergillus fumigates, A. parasiticus, and Chrysonilia sitophila. C. sitophila was the best isolate to decrease total petroleum hydrocarbon (TPH from medium containing 5-20% petroleum residue.

  17. Thermodynamic study of adsorptive desulfurization of heavy naphthenic petroleum distillates; Estudo termodinamico da dessulfurizacao adsortiva de destilados naftenicos pesados de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Suzy; Moreira, Alexandre Marques; Souza, Selene M.A. Guelli Ulson de; Brandao, Heloisa Lima; Souza, Antonio Augusto Ulson de [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2008-07-01

    Environmental concern can be easily observed by the many studies that have been made in the area of development of alternatives and cleaner energy sources. However, oil is still the main energy source of world and, as such, there is great effort in making the oil derivatives cleaner. Many researches are being done in order to remove impurities from oil, such as sulphur. This paper presents the study of the removal of sulfur organic compounds of heavy distillated oil by adsorption process with activated carbon. It obtained the concentration of the fluid phase in equilibrium with the adsorbent phase, to the temperatures of 50, 100 and 150 deg C. The tests were conducted in a batch system, with three types of trade oils. The analyses were done in an analyzer of total sulphur Oxford LAB-X 3000, to obtain the efficiency of the sulphur removal process using activated carbon. The largest adsorptive capacities were found in the temperature of 150 deg C, featuring an endothermic adsorptive phenomenon. The light oils had greater adsorptive capacity at all temperatures that can be explained by the presence of inhibitors or by selectivity to the size of the sulphide compound's chain. (author)

  18. Quantification of heavy metals from residual waste and ashes from the treatment plant of residual water Reciclagua and,effects for the health of those workers which manipulate those residuals; Cuantificacion de metales pesados de lodo residual y cenizas de la planta tratadora de aguas residuales Reciclagua y efectos a la salud de los trabajadores que manipulan los residuos

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero D, J.J

    2004-07-01

    concentrations greater than 0.5% in weight, as long as the analysis of plasma emission spectroscopy very low concentrations are identified already that this method causes the destruction of the sample achieving the identification of all the present elements. With the obtained results we are able to compare the concentrations of the metals before and after the leaching and we calculate by this way the percentage of efficiency for each one of the variables that were managed in the development of the study, obtaining the extraction of those toxic, and valuable metals, present in the muds until of 100%. Based on the results we can mention that the workers are exposed to aerosols and powders of these toxic residuals which contain heavy metals. (Author)

  19. Petroleum marketing monthly with data for January 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-04-01

    This publication provides information and statistical data on a variety of crude oils and refined petroleum products. Statistics on crude oil costs and refined petroleum products sales are presented. Data on crude oil include the domestic purchase price, the free on board and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oils and sales of petroleum products are presented in five sections: (1) summary statistics, (2) crude oil prices, (3) prices of petroleum products, (4) volumes of petroleum products, and (5) prime supplier sales volumes of petroleum products for local consumption. 50 tabs.

  20. A quantitative assessment of risks of heavy metal residues in laundered shop towels and their use by workers.

    Science.gov (United States)

    Connor, Kevin; Magee, Brian

    2014-10-01

    This paper presents a risk assessment of exposure to metal residues in laundered shop towels by workers. The concentrations of 27 metals measured in a synthetic sweat leachate were used to estimate the releasable quantity of metals which could be transferred to workers' skin. Worker exposure was evaluated quantitatively with an exposure model that focused on towel-to-hand transfer and subsequent hand-to-food or -mouth transfers. The exposure model was based on conservative, but reasonable assumptions regarding towel use and default exposure factor values from the published literature or regulatory guidance. Transfer coefficients were derived from studies representative of the exposures to towel users. Contact frequencies were based on assumed high-end use of shop towels, but constrained by a theoretical maximum dermal loading. The risk estimates for workers developed for all metals were below applicable regulatory risk benchmarks. The risk assessment for lead utilized the Adult Lead Model and concluded that predicted lead intakes do not constitute a significant health hazard based on potential worker exposures. Uncertainties are discussed in relation to the overall confidence in the exposure estimates developed for each exposure pathway and the likelihood that the exposure model is under- or overestimating worker exposures and risk. Copyright © 2014 Elsevier Inc. All rights reserved.

  1. Bioaccessibility and health risk of heavy metals in ash from the incineration of different e-waste residues.

    Science.gov (United States)

    Tao, Xiao-Qing; Shen, Dong-Sheng; Shentu, Jia-Li; Long, Yu-Yang; Feng, Yi-Jian; Shen, Chen-Chao

    2015-03-01

    Ash from incinerated e-waste dismantling residues (EDR) may cause significant health risks to people through ingestion, inhalation, and dermal contact exposure pathways. Ashes of four classified e-waste types generated by an incineration plant in Zhejiang, China were collected. Total contents and the bioaccessibilities of Cd, Cu, Ni, Pb, and Zn in ashes were measured to provide crucial information to evaluate the health risks for incinerator workers and children living in vicinity. Compared to raw e-waste in mixture, ash was metal-enriched by category incinerated. However, the physiologically based extraction test (PBET) indicates the bioaccessibilities of Ni, Pb, and Zn were less than 50 %. Obviously, bioaccessibilities need to be considered in noncancer risk estimate. Total and PBET-extractable contents of metal, except for Pb, were significantly correlated with the pH of the ash. Noncancer risks of ash from different incinerator parts decreased in the order bag filter ash (BFA) > cyclone separator ash (CFA) > bottom ash (BA). The hazard quotient for exposure to ash were decreased as ingestion > dermal contact > inhalation. Pb in ingested ash dominated (>80 %) noncancer risks, and children had high chronic risks from Pb (hazard index >10). Carcinogenic risks from exposure to ash were under the acceptable level (incinerated ash are made.

  2. Stormwater induced input of Pb, Cd, As, Zn and other toxic heavy metals into the sewer system of a region characterized by mining residues. Final report

    International Nuclear Information System (INIS)

    Cichos, C.; Muehle, K.

    1993-06-01

    An estimation of heavy metal transport within the river Freiberger Mulde as well as detailed knowledge about pollutant concentration in sewage sludges, in surface soil and in various mining residues give rise to assume that stormwater induced input especially of As, Pb, Cd and Zn into the sewer system of the town of Freiberg has a significant share of contribution to the high pollution of the river. It is the aim of the project to determine the heavy metal input quantitatively where beside the entire transport above all the main transport ways are to be investigated. In the first period of research reported about a movable monitoring station with rainfall gauge, flow rate meter and automatic sampler had to be supplied. First results of stormwater effects at the main intercepting sewer were discussed on the basis of dry-wether flow. For precipitation intensities of 0.5-1 mm/10 min with 4 to 5fold discharge rates at the maximum the measurements showed about 2 to 6fold dry-wether diurnal loads during a rain wether flow of only one hour. Thus, for the case of flood flow up to 100fold diurnal loads may be expected within an hour. The pollutant transport depends on the intensity of rain and on the duration of dry wether before the rain. Further studies above all apply to the main ways of transport but simultaneously to the entire loads to be measured before the storm sewage overflow. Data to be expected in this way may contribute to a long-term simulation of the sewerage as an important aid for planning storage basins. (orig.) [de

  3. Bacterial Utilization of Petroleum in Liquid and Simulated Soil ...

    African Journals Online (AJOL)

    ... by the weight of extracted residual oil indicated that the extents of oil removal in the stimulated and/or bioaugmented soils were significantly high in relation to unsupplemented and uninoculated controls. Keywords: Bacterial utilization, Petroleum in liquid, Petroleum in soil, Environments Bio-Research Vol. 6 (2) 2008: pp.

  4. Petroleum marketing monthly with data for October 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-01

    This publication presents statistical data on crude oil costs and refined petroleum products sales. Data on petroleum include the domestic first purchase price, landed cost of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane.

  5. Phytochemical properties of some solvent fractions of petroleum ...

    African Journals Online (AJOL)

    African Journal of Biotechnology ... The chloroform (A), ethyl acetate (B) and ethyl acetate residue (C) fractions of crude petroleum ether ... Fraction B showed the highest susceptibility (25) to Bacillus subtilis, and was active against the fungus, ...

  6. Petroleum Sector (NAICS 324)

    Science.gov (United States)

    Find relevant environmental regulations for the petroleum industry (NAICS 324), including National Emission Standards for Hazardous Air Pollutants (NESHAP)s for petroleum refineries and gasoline dispensing & effluent guidelines for oil and gas extraction

  7. The petroleum industry in 2003

    International Nuclear Information System (INIS)

    2004-01-01

    This 2004 edition of the petroleum industry activities presents results and data concerning the crude oil prices evolution, the petroleum exploration and production in france and in the world, the para-petroleum industry, the hydrocarbons supplies, the refining, the quality evolution of the substitution products and fuels, the internal transports of petroleum products, the petroleum products storage, the petroleum products consumption, the petroleum products prices and taxation, the petroleum products distribution. (A.L.B.)

  8. Influence of partial replacement of soya bean meal by faba beans or peas in heavy pigs diet on meat quality, residual anti-nutritional factors and phytoestrogen content.

    Science.gov (United States)

    Gatta, Domenico; Russo, Claudia; Giuliotti, Lorella; Mannari, Claudio; Picciarelli, Piero; Lombardi, Lara; Giovannini, Luca; Ceccarelli, Nello; Mariotti, Lorenzo

    2013-06-01

    The study evaluated the partial substitution of soybean meal by faba beans (18%) or peas (20%) as additional protein sources in diets destined for typical Italian heavy pig production. It compared animal performances, meat quality, the presence of residual anti-nutritional factors (ANF) and phytoestrogens in plasma and meat and the possible effects on pig health, by evaluating oxidative, inflammatory and pro-atherogenic markers. The results showed that the productive performances, expressed as body weight and feed conversion ratio, of pigs fed with faba bean and pea diets were similar to those of pigs fed only the soybean meal. Meat quality of pigs fed with the three diets was similar in colour, water-holding capacity, tenderness and chemical composition. Despite the higher levels of phytoestrogen in the plasma of pigs fed only the soybean meal, phytoestrogen concentration in the muscle was equivalent to that of animals fed diets with faba beans, whereas pigs fed a diet with peas showed a lower concentration. Inflammation and pro-atherogenic parameters did not show significant differences among the three diets. Overall, the partial substitution of soybean meal by faba beans appears more interesting than with peas, particularly in relation to the higher amount of polyphenols in the diet and the highest concentration of phytoestrogens found in the plasma and muscle of animals, while the pyrimidine anti-nutritional compounds present in the diet did not appear to accumulate and had no effect on the growth performance of animals.

  9. The world petroleum industry

    International Nuclear Information System (INIS)

    Mons, L.

    2005-01-01

    This study proposes a global vision of the petroleum industry, a precise and well argued state of the art of the petroleum markets. It defines the strategical challenges which the petroleum companies are exposed and allows to anticipate the sector evolutions. It details the key acts of the last three years, the financial performances of the companies. (A.L.B.)

  10. Petroleum hydrocarbon concentration in surface sediments in continental shelf region along the central west coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Ram, A.; Kadam, A.N.

    Gas chromatography revealed that nonpolar material extracted from surface sediments collected along the northern west coast of India was originated from petroleum hydrocarbon residue. Petroleum hydrocarbon levels as determinEd. by fluorescence...

  11. Petroleum marketing monthly, June 1997 with data for March 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  12. Petroleum marketing monthly, March 1998, with data for December 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  13. Petroleum marketing monthly, September 1997 with data for June 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  14. Petroleum marketing monthly, January 1998 with data for October 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  15. Petroleum marketing monthly, April 1996 with data for January 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-02

    The Petroleum Marketing Monthly provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane.

  16. Petroleum marketing monthly, March 1996 with data for December 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-08

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane.

  17. Petroleum marketing monthly, May 1997 with data for February 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  18. Petroleum marketing monthly, January 1996 with data for October 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-01-04

    The Petroleum Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane.

  19. Petroleum marketing monthly, November 1997 with data for August 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  20. Petroleum marketing monthly, April 1997 with data for January 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-04-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  1. Petroleum marketing monthly, February 1997 with data for November 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-02-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  2. Petroleum marketing monthly, October 1997 with data for July 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  3. The characterization of petroleum and creosote-contaminated soils: Class component analysis by thin layer chromatography with flame ionization detection

    International Nuclear Information System (INIS)

    Pollard, S.J.T.; Hrudey, S.E.; Fuhr, B.J.; Alex, R.F.; Holloway, L.R.

    1992-01-01

    The assessment and reclamation of coal tar, creosote and petroleum-contaminated sites is emerging as a major challenge to industry and the federal and provincial Canadian governments. Contaminants frequently include polynuclear aromatic compounds (PAH), several high molecular weight analogues of which are documented carcinogens. Adaptation of thin layer chromatography with flame ionization detection for the analysis of hydrocarbon-contaminated soils is described. The method is directly applicable to the analysis of oily waste extracts from petroleum and creosote wood preservative site soils and is capable of distinguishing between the saturate, aromatic and polar components of waste residues. The method provides a rapid, low cost class component analysis of heavy hydrocarbon waste extracts and is particularly useful for estimating the extent of weathering experienced by chronically exposed hydrocarbon wastes in the soil environment. As such, it is useful as a screening tool for a preliminary assessment of the biotreatability or inherent recalcitrance of hydrocarbon waste mixtures. 11 refs., 5 figs

  4. Petroleum fiscality indicators

    International Nuclear Information System (INIS)

    2008-02-01

    This document presents the different taxes imposed to petroleum products in France: domestic tax on petroleum products (TIPP) and added value tax (TVA). A comparison is made with the fiscality into effect in other European countries for some petroleum products. Then, the fiscality is detailed for the different petroleum products and automotive fuels with its regional modulations. Finally, the fiscal measures adopted in 2007 are detailed. They concern the transposition of the European directive 2003-96/CE into French right and some fiscal regime changes given to some economical sectors particularly penalized by the rise of petroleum energy prices in 2007. (J.S.)

  5. Petroleum industry 1996

    International Nuclear Information System (INIS)

    1997-01-01

    A survey on petroleum industry activities in France and in the world in 1996 is presented. The different parts and themes of the study are: evolution of the petroleum market (international and French markets, supply and demand, prices, mark-up and taxation in France and in Europe); activities in the petroleum industries (exploration and production, maritime transportation, inland transportation and storage, refining, quality of petroleum products and substitution fuels, oil distribution); environment and safety (refining, distribution and evolution of products, pipeline and maritime transportation, exploration and production); situation of the sector's companies (oil groups, para-petroleum French industry, scientific and technical research)

  6. Application of a multimolecular marker approach to fingerprint petroleum pollution in the marine environment

    International Nuclear Information System (INIS)

    Barakat, Assem O.; Mostafa, Alaa R.; Rullkoetter, Juergen; Hegazi, Abdel Rahman

    1999-01-01

    In an attempt to investigate the suitability of a multibiological marker approach for defining the origin of petroleum pollution in marine systems, the aliphatic hydrocarbon composition of tar ball samples collected from the beaches of a small island impacted by heavy tar loads were determined by gas chromatography and gas chromatography/mass spectrometry. The tar ball samples, as collected, were at low stages of biodegradation and had diverse physical appearance. The majority of the samples (as many as 7 of the 10) appeared to be heavy fuel oils - possibly Bunker C. The GC traces for the other three tar balls, however, indicated that they were crude oils probably from tanker ballast washings or other non-point sources like the oil entering from the adjacent North Mediterranean. The biomarkers for the sterane and hopane series in these samples, however, had remained unaffected by weathering, and their distributions revealed significant differences among the samples suggesting multiple sources of the tar balls. The tar ball samples could be genetically subdivided into four groups on the basis of their biomarker fingerprints. A marine carbonate or evaporite, hypersaline, anoxic depositional environment of the petroleum source rock for Type I residues could be inferred from the even-carbon-number predominance of n-alkanes, the high relative abundance of gammacerane and the predominance of C 35 relative to C 34 17α(H)-homohopanes. Higher plant contribution and a deltaic environment of source rock deposition could be concluded for Type II residues from the high concentrations of oleanane and diasteranes. On the other hand, Type III residues possessed geochemical characteristics consistent with a normal marine carbonate or evaporite source depositional environment under normal saline, reducing conditions. Finally, type IV residues had biomarker signatures intermediate between Types II and III. (Author)

  7. Petroleum Supply Monthly

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  8. Petroleum supply monthly

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blends, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  9. Petroleum marketing monthly, May 1996 with data for February 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-02

    The Petroleum Marketing Monthly provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  10. Petroleum marketing monthly, May 1995 with data for February 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-09

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  11. Petroleum marketing monthly, April 1999, with data for January 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-04-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly. 56 tabs.

  12. Petroleum marketing monthly with data for May 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-08-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  13. Petroleum marketing monthly, October 1995 with data for July 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-03

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost Of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  14. Petroleum marketing monthly with data for September 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures and accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  15. Petroleum marketing monthly, June 1996: With data for March 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-04

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o. b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  16. Petroleum marketing monthly, September 1995 with data for June 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-31

    The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the fob and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.

  17. Exports of petroleum products, 1990

    International Nuclear Information System (INIS)

    1991-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1990 calendar year. Exports of the above petroleum products averaged 34,000 m 3 /d in 1990, up 12% from 1989 levels. The increase reflects increased output from the Come By Chance refinery in Newfoundland. Motor gasoline exports increased 35% to 10,500 m 3 /d, reflecting refinery upgrading in eastern Canada. Export prices were generally in line with spot product prices in the USA. Spot prices rose sharply following the Kuwait crisis in August 1990 but fell again in November. The spot price for jet fuel rose more dramatically in that period than for other products, reflecting increased military demand. In winter 1989/90 and during the Kuwait conflict, the export price of heating oil tended to track the USA spot price. Petroleum products imports in 1990 were 18,500 m 3 /d, compared to 21,900 m 3 /d in 1988. Imports were lower partially as a result of higher crude runs in Quebec and a Quebec refinery expansion. Imports of heavy fuel oil in eastern Canada continued to be strong in comparison to the mid-1980s. The top single exporter in 1990, as in 1989, was Newfoundland Processing, with a volume of 4,506,400 m 3 . 13 figs., 5 tabs

  18. The petroleum industry in 2005

    International Nuclear Information System (INIS)

    2006-01-01

    This document provides information on the petroleum industry for the year 2005. It discusses the world gas and petroleum markets, the world and french petroleum exploration and production, the petroleum and byproducts industry in France, the hydrocarbons supplying, the refining in France, the evolution of the products and fuels substitution quality, the internal transports of petroleum products, the storage consumption and taxes of petroleum products, the prices and distribution of the petroleum products. (A.L.B.)

  19. Heavy Metals and the Petroleum Industr

    Science.gov (United States)

    1993-05-01

    460 11 Fat Rendering 220 210 70 460 6 Bakery 150 330 430 280 2 Misc. Foods 350 150 110 1100 6 Brewery 410 60 40 470 5 Soft Drinks/ Flavoring 2040 180...arsenic react with -SH groups and can form coordination complexes and chelates with various compounds and structures in the cell .’ The -SH and...important in the function of the human body. It is present in the circulatory system, and a component in the formation of bones and teeth. Calcium is

  20. Shale oil. I. Genesis of oil shales and its relation to petroleum and other fuels

    Energy Technology Data Exchange (ETDEWEB)

    McKee, R H; Manning, P D.V.

    1927-01-01

    Oil-shale kerogen originated from resinous vegetation residues of past eras, whereas well petroleum was formed from oil shales by pressure and mild heat. Petroleum migrated to its present reservoir from neighboring oil-shale deposits, leaving a residue of black bituminous shales. The high carbon dioxide content of gases present in petroleum wells originated from kerogen, as it gives off carbon dioxide gas before producing soluble oil or bitumen.

  1. Petroleum marketing monthly, September 1990. [Contains Glossary

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-11

    This report is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, education institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners' acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 12 figs., 55 tabs.

  2. Petroleum marketing monthly, October 1991. [Contains glossary

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-10

    This report is designed to give information and statistical data about a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiner's acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. 12 figs., 55 tabs.

  3. Petroleum industry in CIS

    International Nuclear Information System (INIS)

    Vaillaud, P.

    1992-01-01

    This paper gives statistical data on petroleum and natural gas industry in USSR and in Eastern Europe: crude oil and gas production, petroleum and natural gas deposits, exports, fuel consumption, pipelines network (total length, compressor or pump stations), petroleum refineries. This paper describes also air pollution (carbon dioxide and sulfur dioxide) and Environmental effects of coal and lignite using in fossil power plants in Eastern Europe. 17 figs., 7 tabs

  4. Petroleum and ethics

    International Nuclear Information System (INIS)

    Henn, N.; Train, E.; Chagnoux, H.; Heinzle, P.; Daubresse, M.; Bret-Rouzaut, N.; Fradin, J.

    2000-01-01

    7 articles in this data sheet, they concern: political stakes and stakes of the industrial petroleum sector towards ethical questions; establishment of associations attending to human and environmental questions; examples of of ethical, environmental and safety policy in an industrialized country (ExxonMobil) and in a developing country (TotalFina); synthesis of the ethical problems that the petroleum industry encounter in industrialized and developing countries; considerations on the communication stakes in petroleum companies with the general public. (O.M.)

  5. Canadian petroleum history bibliography

    Energy Technology Data Exchange (ETDEWEB)

    Cass, D.

    2003-09-27

    The Petroleum History Bibliography includes a list of more than 2,000 publications that record the history of the Canadian petroleum industry. The list includes books, theses, films, audio tapes, published articles, company histories, biographies, autobiographies, fiction, poetry, humour, and an author index. It was created over a period of several years to help with projects at the Petroleum History Society. It is an ongoing piece of work, and as such, invites comments and additions.

  6. Petroleum and geopolitics

    International Nuclear Information System (INIS)

    Chaigneau, P.

    2004-01-01

    Todays, petroleum companies consider that despite the constant increase of petroleum consumption, petroleum will remain the main energy source for at least 40 years. However, after the Iraq conflict, new regional situations are changing. China, for instance, with its growing up demand, will change the physiognomy of the oil market. In parallel, from Indonesia to Africa, petroleum and religion interfere and explain the new conflict areas. As for the US strategy, which is not limited to the energy paradigm, it largely integrates energy in the main lines of its diplomacy, from the 'Wide Middle East' to the 'Sahel initiative', and in its position with respect to Venezuela

  7. Petroleum Refinery Effluents Treatment by Advanced Oxidation Process with Methanol

    Energy Technology Data Exchange (ETDEWEB)

    Shoucheng, Wen [Yangtze Univ., HuBei Jingzhou (China)

    2014-02-15

    Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is 440 .deg. C, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%.

  8. Petroleum Refinery Effluents Treatment by Advanced Oxidation Process with Methanol

    International Nuclear Information System (INIS)

    Shoucheng, Wen

    2014-01-01

    Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is 440 .deg. C, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%

  9. Petroleum electrical properties characterization; Caracterizaco de propriedades eletricas de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Ueti, Edson; Sens, Marcio Antonio [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil)], e-mail: ueti@cepel.br

    2006-07-01

    Presently, petroleum wells consist predominantly of heavy type petroleum, that is submitted to decantation and separation of water, through desalinisation process. If this process is not efficient, the metallic piping will be severely corroded during refining. Hence, the knowledge of petroleum electric properties is essential for optimizing the separation of water from petroleum, by indicating its humidity in laboratory testing conditions. The present work shows an experimental procedure based on disposable cells for electric characterization of liquid polymeric materials. The use of standard cells is unfeasible, due to the petroleum physical characteristics. The procedures for the evaluation of electric properties shown in this work are applied for dielectric constant values up to 200 kHz, as well as for the electric conductivity in direct current and the electrical strength in industrial frequency. (author)

  10. Financing petroleum agreements

    International Nuclear Information System (INIS)

    Robson, C.J.V.

    1994-01-01

    This chapter describes the typical type of financing agreements which are currently used to finance North Sea petroleum projects whether they are in the cause of development or have been developed and are producing. It deals with the agreements which are entered into to finance borrowings for petroleum projects on a non-resource or limited resource basis. (UK)

  11. Fundamentals of Petroleum.

    Science.gov (United States)

    Bureau of Naval Personnel, Washington, DC.

    Basic information on petroleum is presented in this book prepared for naval logistics officers. Petroleum in national defense is discussed in connection with consumption statistics, productive capacity, world's resources, and steps in logistics. Chemical and geological analyses are made in efforts to familiarize methods of refining, measuring,…

  12. Petroleum systems of Indonesia

    NARCIS (Netherlands)

    Doust, H.; Noble, R.A.

    2008-01-01

    Indonesia contains many Tertiary basins, several of which have proven to be very prolific producers of oil and gas. The geology and petroleum systems of these productive basins are reviewed, summarized and updated according to the most recent developments. We have linked the recognized petroleum

  13. Petroleum and international policy

    International Nuclear Information System (INIS)

    Pertuzio, A.

    2002-01-01

    To illustrate the relation between the petroleum and the international policy, the author presents the place of the petroleum industry in the international relations by an analysis of the historical aspects, the states and international organizations interventions and the prices evolution. (A.L.B.)

  14. Petroleum supply monthly, April 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-04-01

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographical regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US. The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the US.

  15. Uptake and elimination kinetics of heavy metals by earthworm ...

    African Journals Online (AJOL)

    Earthworm inoculation of petroleum hydrocarbon contaminated soil is thought to catalyze the bioremediation. Most bioremediation studies focus on the petroleum hydrocarbon content and not on the heavy metals. Here, the uptake kinetics of heavy metals by earthworm in used engine oil contaminated soil was investigated.

  16. Uptake of heavy metals by Brachiaria Decumbens and its mutant as a remediation agent for soil contaminated with oil sludge

    International Nuclear Information System (INIS)

    Ahmad Nazrul Abd Wahid; Latiffah Noordin; Abdul Razak Ruslan; Hazlina Abdullah; Khairuddin Abdul Rahim

    2006-01-01

    The Malaysian petroleum industry produces thousands of tonnes of oil sludge per year. Oil sludge is the residue accumulated during processing of petroleum at petroleum processing plants. Besides soil, mud and sand, oil sludge is often rich in radioactive substances, heavy metals and other toxic materials from hydrocarbon group which could contaminate and environment. In the present study the pasture grass Brachiaria decumbens and its mutant B. decumbens Kluang Comel were evaluated on their effectiveness as remediation agents for contaminated soils. The contaminating agent tested was the oil sludge with its hydrocarbons vaporised, obtained from the Waste Management Centre, MINT. Amongst the indicators for an effective remediation agent is the ability to accumulate heavy metals in their tissues without affecting their growth. This trial was conducted at MINT glasshouse, whereby the test plants were planted in pots in soil added with vaporised oil sludge. Analysis of heavy metals was through Inductive Coupled Plasma Mass Spectrometry (ICPMS) and Neutron Activation Analysis (NAA). This paper discusses the accumulation of heavy metals by B. decumbens and its mutant Kluang Comel and their growth performance, hence assessing their suitability as remediation agent in soil contaminated with oil sludge. (Author)

  17. Petroleum supply annual 1996: Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-01

    The Petroleum Supply Annual (PSA) contains information on the supply and disposition of crude oil and petroleum products. The publication reflects data that were collected from the petroleum industry during 1996 through annual and monthly surveys. The PSA is divided into two volumes. This first volume contains three sections: Summary Statistics, Detailed Statistics, and Refinery Capacity; each with final annual data. The summary statistics section show 16 years of data depicting the balance between supply, disposition and ending stocks for various commodities including crude oil, motor gasoline, distillate fuel oil, residual fuel oil, jet fuel propane/propylene, and liquefied petroleum gases. The detailed statistics section provide 1996 detailed statistics on supply and disposition, refinery operations, imports and exports, stocks, and transportation of crude oil and petroleum products. The refinery capacity contain listings of refineries and associated crude oil distillation and downstream capacities by State, as of January 1, 1997, as well as summaries of corporate refinery capacities and refinery storage capacities. In addition, refinery receipts of crude oil by method of transportation for 1996 are provided. Also included are fuels consumed at refineries, and lists of shutdowns, sales, reactivations, and mergers during 1995 and 1996. 16 figs., 59 tabs.

  18. Petroleum supply annual 1996: Volume 1

    International Nuclear Information System (INIS)

    1997-06-01

    The Petroleum Supply Annual (PSA) contains information on the supply and disposition of crude oil and petroleum products. The publication reflects data that were collected from the petroleum industry during 1996 through annual and monthly surveys. The PSA is divided into two volumes. This first volume contains three sections: Summary Statistics, Detailed Statistics, and Refinery Capacity; each with final annual data. The summary statistics section show 16 years of data depicting the balance between supply, disposition and ending stocks for various commodities including crude oil, motor gasoline, distillate fuel oil, residual fuel oil, jet fuel propane/propylene, and liquefied petroleum gases. The detailed statistics section provide 1996 detailed statistics on supply and disposition, refinery operations, imports and exports, stocks, and transportation of crude oil and petroleum products. The refinery capacity contain listings of refineries and associated crude oil distillation and downstream capacities by State, as of January 1, 1997, as well as summaries of corporate refinery capacities and refinery storage capacities. In addition, refinery receipts of crude oil by method of transportation for 1996 are provided. Also included are fuels consumed at refineries, and lists of shutdowns, sales, reactivations, and mergers during 1995 and 1996. 16 figs., 59 tabs

  19. Petroleum marketing monthly with data for April 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-07-01

    This publication provides information and statistical data on a variety of crude oil costs and refined petroleum products sales. Data on crude oil include the domestic first purchase price, the free on board price and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The data provided are compiled from six Energy Information Administration survey forms. 50 tabs.

  20. Petroleum question. Die Oelfrage

    Energy Technology Data Exchange (ETDEWEB)

    Mommer, B

    1983-01-01

    The author analyses the development of the world petroleum market and its pricing factors to the present on the basis of the theory of ground rent, in which the part played by absolute ground rent, differential rent, and free and national state property in the capitalist mode of production is determined. His investigation of economic policy traces the absorbing history of the petroleum production and policy of the United States of America, which for so long governed the world market, the development of Venezuela into a petroleum country (whose true history is here revealed for the first time), the penetration of the middle East by the international petroleum leaseholders' capital and their cartel, the formation of the OPEC, and finally the 'victory' of the lather over the petroleum combines in the international petroleum crisis of 1970-1973. The book closes with a survey at the start of the 80s and an outlook into the foreseeable future. What is really hidden behind the quarrels about prices, profit, taxes, royalties, franchise agreements, production quotas, nationalization and so forth and behind the economic, political, and even moral arguments of the parties concerned turns out to be the fight of the petroleum ground proprietors for the ground rent - but to win a victory in this fight means ultimately to face its limitations, too. Blindness to the economic and political importance of ground rent, right from the theoretical approach, also created a major cause of the false diagnoses and forecasts on the petroleum market western economic scientists were misled into, and thus of the surprise effect that came in the form of the petroleum crisis of the early 1970s.

  1. Caspian sea: petroleum challenges

    International Nuclear Information System (INIS)

    2005-01-01

    The Caspian sea is one of the world areas the most promising in terms of investments and petroleum development. This study presents the petroleum challenges generated by this hydrocarbons reserve. The first part discusses the juridical status (sea or lake), the petroleum and the gas reserves, the ecosystem and the today environment (fishing and caviar), the geostrategic situation and the transport of gas and oil. It provides also a chronology from 1729 to 2005, a selection of Internet sites, books and reports on the subject and identity sheets of the countries around the Caspian sea. (A.L.B.)

  2. Petroleum investment in Kazakhstan

    International Nuclear Information System (INIS)

    Friedrich, M.

    1994-01-01

    There is no specific petroleum legislation as such in place in Kazakhstan and tax legislation is unsophisticated. Regulation of operations is subject to generally applicable legislation. A brief account of the difficulties which exist for both sides in renegotiating a contract is given. Since the competence to enter into contracts with foreign companies has not been fully defined, the first problem when applying for petroleum rights is the identification of a negotiating partner. A summary of terms and conditions and a list of the main laws applicable to petroleum operations are included. (UK)

  3. Petroleum: the new deal

    International Nuclear Information System (INIS)

    Magalhaes, St.; Kan, E.

    2008-01-01

    The drop of oil prices imposes a revision of development and investment strategies of petroleum and para-petroleum companies, while technologies under study try to optimize the exploration and production costs. Following the financial and economical crises, the petroleum industry is preparing its restructuring: new profitability threshold of projects, slowing down of the activity, expected surge of mergers. Despite the crisis, the R and D for the exploitation of tar sands still goes on while on the offshore side, R and D has never been so active to take up the challenge of extreme deep sea conditions. (J.S.)

  4. Petroleum marketing monthly, December 1996 with data for September 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    This report provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

  5. Collimator system for the stabilization of the dynamical residual-gas pressure in the heavy-ion synchrotron SIS18; Kollimatorsystem zur Stabilisierung des dynamischen Restgasdruckes im Schwerionensynchrotron SIS18

    Energy Technology Data Exchange (ETDEWEB)

    Omet, Carsten

    2009-01-15

    In order to achieve higher beam intensities of heavy ion beams in ring accelerators, low charge state ions can be used. By lowering the charge state, the space charge limit is shifted to higher particle numbers and stripping losses can be avoided. During test operation of the SIS18 at GSI with high intensity low charge state heavy ion beams, strong intensity dependent beam losses have been observed. It was found that these beam losses are originated to a large extent by the change of charge state of the circulating ions during collisions with residual gas atoms. The resulting deviation of m/q relative to the reference ion leads, in combination with dispersive elements in the ion optic lattice, to a modified trajectory, followed by the loss of the ion on the beam pipe. At the impact position, loosely bound residual gas molecules are released by ion stimulated desorption which increases the residual gas pressure locally. This pressure rise itself enhances the charge exchange rate, which can develop into a self amplifying process of pressure rise and subsequent beam loss. A method for the stabilization of the dynamic residual gas pressure is the use of special catcher systems, which minimize the production of desorption gases and remove them by strong pumping. Therefore, the pressure on the beam axis should remain as stable as possible. Other processes, e.g. Coulomb scattering of the beam ions by residual gas particles and unavoidable systematic beam losses can increase the gas pressure additionally. The pressure in the accelerator is further subjected to ionization of the residual gas atoms themselves, thermal out gassing of the beam pipes, insertions and pumps. In this work, a detailed numerical model of the interplay between the residual gas pressure dynamics in the accelerator, possible stabilization measures, e.g. by catchers and the resulting beam life time has been developed. The forecasted beam life times and pressures are verified by machine experiments, as

  6. Petroleum refining and air quality

    International Nuclear Information System (INIS)

    Raimbault, C.

    1992-01-01

    This paper studies the methods which may be developed in petroleum refineries or during petroleum products using for air pollution abatement: petroleum products desulfurization, lead elimination in gasoline and catalytic converters to reduce sulfur dioxide and nitrogen oxides in exhaust gases. Investments and costs estimation to adapt petroleum refineries for environment protection is also given. 1 ref., 6 figs., 6 tabs

  7. Figures of the petroleum industry

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    The statistic tables give informations about: Reserves and production of petroleum and natural gas, supply of crude petroleum in the Federal Republic of Germany, pipelines, tanker ships, petroleum refineries, petroleum consumption, storage and distribution, automobiles, prices, taxis and energy consumption. The data compilations are primarily given for the Federal Republic of Germany.

  8. Petroleum supply monthly, January 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    Data presented describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States. The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  9. Apparatus for extracting petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Coogan, J

    1921-01-18

    An apparatus for extracting petroleum from petroleum bearing sand or shale is described comprising a container for liquids, the container being divided into a plurality of compartments, an agitator mounted within the container and below the liquid level and having its forward end opening into one of the compartments, means for delivering sand or shale to the forward end of the agitator, means for subjecting the sand or shale to the action of a solvent for the petroleum while the sand or shale is being agitated and is submerged, the first-mentioned compartment being adapted to receive the extracted petroleum and means for removing the treated sand or shale from adjacent the rear end of the agitator.

  10. Petroleum supply annual 1992

    International Nuclear Information System (INIS)

    1993-01-01

    The Petroleum Supply Annual (PSA) contains information on the supply and disposition of crude oil and petroleum products. The publication reflects data that were collected from the petroleum industry during 1992 through annual and monthly surveys. The PSA is divided into two volumes. The first volume contains four sections: Summary Statistics, Detailed Statistics, Refinery Capacity, and Oxygenate Capacity each with final annual data. This second volume contains final statistics for each month of 1992, and replaces data previously published in the Petroleum Supply Monthly (PSM). The tables in Volumes 1 and 2 are similarly numbered to facilitate comparison between them. Explanatory Notes, located at the end of this publication, present information describing data collection, sources, estimation methodology, data quality control procedures, modifications to reporting requirements and interpretation of tables. Industry terminology and product definitions are listed alphabetically in the Glossary

  11. Petroleum Vapor Intrusion

    Science.gov (United States)

    One type of vapor intrusion is PVI, in which vapors from petroleum hydrocarbons such as gasoline, diesel, or jet fuel enter a building. Intrusion of contaminant vapors into indoor spaces is of concern.

  12. Material-balance assessment of the New Albany-Chesterian petroleum system of the Illinois basin

    Science.gov (United States)

    Lewan, M.D.; Henry, M.E.; Higley, D.K.; Pitman, Janet K.

    2002-01-01

    The New Albany-Chesterian petroleum system of the Illinois basin is a well-constrained system from which petroleum charges and losses were quantified through a material-balance assessment. This petroleum system has nearly 90,000 wells penetrating the Chesterian section, a single New Albany Shale source rock accounting for more than 99% of the produced oil, well-established stratigraphic and structural frameworks, and accessible source rock samples at various maturity levels. A hydrogen index (HI) map based on Rock-Eval analyses of source rock samples of New Albany Shale defines the pod of active source rock and extent of oil generation. Based on a buoyancy-drive model, the system was divided into seven secondary-migration catchments. Each catchment contains a part of the active pod of source rock from which it derives a petroleum charge, and this charge is confined to carrier beds and reservoirs within these catchments as accountable petroleum, petroleum losses, or undiscovered petroleum. A well-constrained catchment with no apparent erosional or leakage losses is used to determine an actual petroleum charge from accountable petroleum and residual migration losses. This actual petroleum charge is used to calibrate the other catchments in which erosional petroleum losses have occurred. Petroleum charges determined by laboratory pyrolysis are exaggerated relative to the actual petroleum charge. Rock-Eval charges are exaggerated by a factor of 4-14, and hydrouspyrolysis charges are exaggerated by a factor of 1.7. The actual petroleum charge provides a more meaningful material balance and more realistic estimates of petroleum losses and remaining undiscovered petroleum. The total petroleum charge determined for the New Albany-Chesterian system is 78 billion bbl, of which 11.4 billion bbl occur as a accountable in place petroleum, 9 billion bbl occur as residual migration losses, and 57.6 billion bbl occur as erosional losses. Of the erosional losses, 40 billion bbl

  13. Chemical structure investigation on SFEF fractions of Dagang vacuum residue

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z.; Yan, G.; Zhao, S.; Guo, S. [China Univ. of Petroleum, Beijing (China). State Key Laboratory of Heavy Oil Processing; Zhang, Z. [Beijing Aeronautical Technology Research Center, Beijing (China)

    2006-07-01

    One of the most important problems in petroleum chemistry is the molecular structure and composition of heavy oil fractions and its importance in applications pertaining to the recovery, refining, and upgrading of petroleum. This paper presented an investigation into the chemical structure on supercritical fluid extraction and fraction (SFEF) factions of Dagang vacuum residue. Dagang vacuum residue was cut into sixteen fractions and a tailing with SFEF instrument. Then, using a chromatography, all SFEF fractions were further separated into four group compositions, notably saturated hydrocarbons, aromatic hydrocarbons, resins and asphaltenes (SARA). Last, the chemical structure was explored through a thorough analysis of the products from the ruthenium ions-catalyzed oxidation (RICO) reaction of those aromatics, resins and asphaltenes. The paper discussed the experiment in terms of samples and chemicals; supercritical fluid extraction and fraction; SARA separation; and RICO. The results and discussions focused on alkyl side chains attached to aromatic carbon; polymethylene bridges connecting two aromatic units; benzenecarboxylic acids an aromatic units; and others. The study has brought to light useful characterization on covalent molecular structure of two typical SFEF fractions, notably the tenth and fifteen fraction. 17 refs., 6 tabs., 16 figs., 1 appendix.

  14. Photolysis of petroleum

    International Nuclear Information System (INIS)

    Bobra, M.

    1992-05-01

    A study was conducted to examine the chemical and physical changes that occur in oils as a result of photooxidation. A literature review of recent studies in petroleum photochemistry revealed reported effects of photo-induced reactions in petroleum, including changes in color, polymerization, solidification, increases in solubility and toxicity, and changes in interfacial properties. A list of products reported as a result of photolysis of petroleum is presented, including such compounds as aldehydes, ketones, esters, and lactones. The photoreactivity of various petroleum components is discussed and mechanisms of photooxidation of petroleum are suggested. In the experimental portion of the study, a variety of crude oils and petroleum products were used to determine how different oils are affected by photolysis, and to examine the importance of photolysis as a weathering process. Photooxidation products from several oils were isolated and identified, including aliphatic and aromatic acids, alcohols, and phenols. Some physical manifestations attributed to photolysis included yellowing, formation of precipitates or crusts, increases in density and viscosity with time, increases of asphaltene content in some oils, changes in pH of the surrounding water, and emulsification. 51 refs., 38 figs., 18 tabs

  15. Petroleum Hydrocarbons Contamination Profile of Ochani Stream in ...

    African Journals Online (AJOL)

    Petroleum hydrocarbon contamination profile, heavy metals and some physicochemical parameters were investigated in Ochani Stream site in Ejamah Ebubu, Eleme Local Government Area of Rivers State. The results show that a major crude oil spillage occurred at Ejamah Ebubu, Rivers State, Nigeria approximately 30 ...

  16. The effects of Pantoea sp. strain Y4-4 on alfalfa in the remediation of heavy-metal-contaminated soil, and auxiliary impacts of plant residues on the remediation of saline-alkali soils.

    Science.gov (United States)

    Li, Shuhuan; Wang, Jie; Gao, Nanxiong; Liu, Lizhu; Chen, Yahua

    2017-04-01

    The plant-growth-promoting rhizobacterium (PGPR) Y4-4 was isolated from plant rhizosphere soil and identified as Pantoea sp. by 16S rRNA sequence analysis. The effects of strain Y4-4 on alfalfa grown in heavy-metals-contaminated soil was investigated using a pot experiment. In a Cu-rich environment, the shoot dry mass and total dry mass of plants inoculated with strain Y4-4 increased by 22.6% and 21%, and Cu accumulation increased by 15%. In a Pb-Zn-rich environment, the shoot dry mass and total dry mass of plants inoculated with strain Y4-4 increased by 23.4% and 22%, and Zn accumulation increased by 30.3%. In addition, the salt tolerance and biomass of wheat seedlings could be improved by applying strain Y4-4 mixed with plant residue as a result of the Cu-rich plant residues providing copper nutrition to wheat. This study offers an efficient PGPR with strong salt tolerance and a safe strategy for the post-treatment of plant residue.

  17. Heavy fuel and LPG; Fioul et GPL

    Energy Technology Data Exchange (ETDEWEB)

    Philippon, A. [Chambre Syndicale du raffinage, UFIP, 75 - Paris (France)

    1997-12-31

    This paper analyzes the impact of new French combustion and environment regulations on the market of heavy fuels and on refining. The economical context of the petroleum and heavy fuels market is recalled first and then the future evolution of this market and the future impact of new pollution regulations on the refining industry are briefly analyzed. (J.S.)

  18. [Study on the groundwater petroleum contaminant remediation by air sparging].

    Science.gov (United States)

    Wang, Zhi-Qiang; Wu, Qiang; Zou, Zu-Guang; Chen, Hong; Yang, Xun-Chang; Zhao, Ji-Chu

    2007-04-01

    The groundwater petroleum contaminant remediation effect by air sparging was investigated in an oil field. The results show that the soil geological situation has great influence on the air distribution, and the shape of air distribution is not symmetrical to the air sparging (AS) well as axis. The influence distance in the left of AS well is 6 m, and only 4 m in the right. The petroleum removal rate can reach 70% in the zone with higher air saturation, but only 40% in the zone with lower air saturation, and the average petroleum removal rate reaches 60% in the influence zone for 40 days continuous air sparging. The petroleum components in groundwater were analyzed by GC/MS (gas chromatogram-mass spectrograph) before and after experiments, respectively. The results show that the petroleum removal rate has relationship with the components and their properties. The petroleum components with higher volatility are easily removed by volatilization, but those with lower volatility are difficult to remove, so a tailing effect of lingering residual contaminant exists when the air sparging technology is adopted to treat groundwater contaminated by petroleum products.

  19. Petroleum marketing monthly: September 1996, with data for June 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-01

    The Petroleum Marketing Monthly provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Detailed statistics for crude oil, including the price of imported crude oil by country of origin, by gravity, and by crude stream. To aid the reader in determining the market changes, the majority of the tables show data for the report month and previous months for the current year, and the report month for the previous year. 7 figs., 50 tabs.

  20. Characteristics of bicyclic sesquiterpanes in crude oils and petroleum products.

    Science.gov (United States)

    Yang, Chun; Wang, Zhendi; Hollebone, Bruce P; Brown, Carl E; Landriault, Mike

    2009-05-15

    This study presents a quantitative gas chromatography-mass spectrometry analysis of bicyclic sesquiterpanes (BSs) in numerous crude oils and refined petroleum products including light and mid-range distillate fuels, residual fuels, and lubricating oils collected from various sources. Ten commonly recognized bicyclic sesquiterpanes were determined in all the studied crude oils and diesel range fuels with principal dominance of BS3 (C(15)H(28)), BS5 (C(15)H(28)) and BS10 (C(16)H(30)), while they were generally not detected or in trace in light fuel oils like gasoline and kerosene and most lubricating oils. Laboratory distillation of crude oils demonstrated that sesquiterpanes were highly enriched in the medium distillation fractions of approximately 180 to 481 degrees C and were generally absent or very low in the light distillation fraction (boiling point to approximately 180 degrees C) and the heavy residual fraction (>481 degrees C). The effect of evaporative weathering on a series of diagnostic ratios of sesquiterpanes, n-alkanes, and biomarkers was evaluated with two suites of weathered oil samples. The change of abundance of sesquiterpanes was used to determine the extent of weathering of artificially evaporated crude oils and diesel. In addition to the pentacyclic biomarker C(29) and C(30) alphabeta-hopane, C(15) and C(16) sesquiterpanes might be alternative internal marker compounds to provide a direct way to estimate the depletion of oils, particularly diesels, in oil spill investigations. These findings may offer potential applications for both oil identification and oil-source correlation in cases where the tri- to pentacyclic biomarkers are absent due to refining or environmental weathering of oils.

  1. The business of petroleum exploration

    International Nuclear Information System (INIS)

    Steinmetz, R.

    1992-01-01

    This book contains the proceedings of the Business of Petroleum Exploration. The following topics are included: Petroleum business; Economic aspects of the business; Managing business; and Legal, Political, Ethical and environment aspects of the business

  2. Isotope analysis in petroleum exploration

    International Nuclear Information System (INIS)

    Rodrigues, R.

    1982-01-01

    The study about isotopic analysis in petroleum exploration performed at Petrobras Research Center is showed. The results of the petroleum recuperation in same Brazilian basin and shelves are comented. (L.H.L.L.) [pt

  3. Petroleum supply monthly, August 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-08-26

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  4. The petroleum taxation in France

    International Nuclear Information System (INIS)

    2005-09-01

    This document details the french specificities of taxation concerning the petroleum products: the TIPP. It shows how this policy acts upon the petroleum products consumption behavior and how it allows the financing of the decentralization. (A.L.B.)

  5. Computer simulation of deasphalting vacuum residues in a pilot unit; Simulacao computacional de desasfaltacao de residuo de vacuo realizada em unidade piloto

    Energy Technology Data Exchange (ETDEWEB)

    Concha, Viktor Oswaldo Cardenas; Quirino, Filipe Augusto Barral; Koroisgi, Erika Tomie; Rivarola, Florencia Wisnivesky Rocca; Maciel, Maria Regina Wolf; Maciel Filho, Rubens [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Quimica; Medina, Lilian Carmen; Barros, Ricardo Soares de [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2008-07-01

    In the context of the national petroleum industry, it is interesting to keep the production of the paraffinic lubricant oil type I, which implies in the identification of new loads to ensure the feeding of the existing units. Therefore, it is important to carry out carefully the characterization of the oils, defining its potential for fuel, asphalt and lubricant. Aiming to introduce in the characterization and evaluation of petroleum for lubricant, carried out by PETROBRAS/CENPES, information of basic oils, more similar to industrial oils, was built up in the Laboratory of Process Separation Development - LDPS of UNICAMP/FEQ, a deasphalting pilot unit. In this work, the deasphalting process of a vacuum residue of Brazilian petroleum is simulated, using Aspen Plus{sup R} simulator, in order to remove asphaltenes, resins and other heavy components of vacuum residue. The simulations were carried out considering the configuration of the pilot plant, evaluating the extraction in near-critical operational condition applied to a petroleum, using propane as the solvent. The extraction efficiency and the solvent power were evaluated considering variations in temperature, pressure and in the solvent/feed ratio in order to obtain yields with more efficiency in the production of deasphalted oil (DAO), what means more asphaltene removal. (author)

  6. Marks on the petroleum fiscality

    International Nuclear Information System (INIS)

    2007-02-01

    This document offers some marks on the petroleum fiscality in France: the taxes as the 'accises' and the 'TVA', the part of the taxes in the sale price at the service station, the comparison with other countries of Europe, the tax revenues and the Government budget. It provides also marks on the fuels prices formation (margins), the world petroleum markets (supply and demand) and the part of the petroleum companies on the petroleum market. (A.L.B.)

  7. Process for recovering, destroying or displacing a petroleum product on the surface of a liquid

    Energy Technology Data Exchange (ETDEWEB)

    Godin, G H.F.; Bringer Quertier, G M.L.

    1969-01-06

    This process consists in first immobilizing the petroleum product on the surface of water by means of pieces or strips of polyethylene plastic. The petroleum product is then either collected and separated from water, or burned in place. After burning, the solid residue is towed to shore and burned a second time, after which neither ash nor residue is left. The proportion of polyethylene to be used is 1:20 if the product is collected, 1:35 if it is burned.

  8. Petroleum supply monthly, April 1990

    Energy Technology Data Exchange (ETDEWEB)

    None

    1990-06-26

    The Petroleum Supply Monthly (PSM) is one of a family of three publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other two publications are the Weekly Petroleum Status Report (WPSR) and the Petroleum Supply Annual (PSA). Data presented in the Petroleum Supply Monthly describe (PSM) the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply.'' Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: (1) the Summary Statistics and (2) the Detailed Statistics.

  9. Salts, sodium and heavy metals, in residual waters not purified, used for the watering in the cultivation of the sugar cane

    International Nuclear Information System (INIS)

    Mendez Romero, Franky Jose; Gisbert-Banquert, Juan Manuel

    2003-01-01

    In a farm located in the Valencia Lake Basin at northeast of Guacara city (Venezuelan country) and cultivated with sugar cane crop was evaluated during the period of July of 1996 to June of 1997 the salinity, sodicity and heavy metals concentration In municipal wastewater using to gravity Irrigated the sugar cane crop. The salinity was determinate by EC direct measure In Irrigation water (standardized at 25 Celsius degrade, Sodium by flame photometer Calcium and Magnesium by titulation with EDTA Cd, Cu, Fe Mn, Ni and Zn, were determinate by AAS before water samples preserve with NO 3 H. The wastewater quality employ to Irrigated the sugar cane crop was evaluated by mean of the Venezuelan official water Laws (1995) and compare too with the directives mentioned by Pratt and Suarez (1990), Crook and Bastian (1992) and the Mexican official wastewater irrigation laws NOM-CAA-032-ECOL/93 (1993. The results showed than the wastewater using to Irrigated the sugar cane field crop could to bring light and strong problems by salinity and sodium so much the soil as the crop The concentration of Cd, Fe and Cu are outside Limits proposals the Venezuelan official water laws (1995) Also when comparing the results with the other directives all the heavy metal concentration are outside the proposed Limits In each one of them except the Zn. In any case, the continuous use of the wastewater treated in this research could generate potential contamination and toxicity problems by heavy metals, salts and sodium In the crop, soils, groundwater and the people

  10. SWOT ANALYSIS - CHINESE PETROLEUM

    Directory of Open Access Journals (Sweden)

    Chunlan Wang

    2014-01-01

    Full Text Available This article was written in early December 2013,combined with the historical development andthe latest data on the Chinese Petroleum carried SWOT- analysis. This paper discusses corporate resources, cost, management and external factorssuch as the political environment and the marketsupply and demand, conducted a comprehensiveand profound analysis.

  11. SWOT ANALYSIS - CHINESE PETROLEUM

    OpenAIRE

    Chunlan Wang; Lei Zhang; Qi Zhong

    2014-01-01

    This article was written in early December 2013, combined with the historical development and the latest data on the Chinese Petroleum carried SWOTanalysis. This paper discusses corporate resources, cost, management and external factors such as the political environment and the market supply and demand, conducted a comprehensive and profound analysis.

  12. Environmental pollution by petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Murata, T

    1974-06-01

    Pollution causes, cases, and remedies at various stages of petroleum production and usage are reviewed. Petroleum extraction (off-shore drilling and Arctic drilling) can be accompanied by mishaps. In 1971, IMCO (an international safety committee) proposed the partitioning of oil tanker holds into smaller compartments to minimize spillage in case of disaster. Although the solubility of oil in waste water from refineries is reckoned by ppM, the total amount dissolved is not negligible. Petroleum storage and transport on land is complicated by problems of safety in terms of population density as well as by pollution problems. Petroleum end-products such as plastic trash and automobile exhausts contribute to pollution. The role of aldehydes and peroxides in photochemical smog formation must be investigated further. Proper treatment of pollution at each specific point of occurrence, rather than at the end of a production line is recommended. Pollutant concentration for treatment, rather than pollutant dilution for dispersal, should be considered. Technology for pollution abatement is available, but not always economically feasible.

  13. Petroleum industry in 1992

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    This book analyses the major facts and the numbers of 1992, in France and in foreign countries. Its purpose is to be as complete as possible and to present especially all the aspects on a national level: supply, domestic market, prices, exploration, production, stocks, petroleum refining, transports, retailing, financial data

  14. Petroleum: Price trends

    International Nuclear Information System (INIS)

    Babusiaux, Denis; Pierru, Axel

    2010-01-01

    The Organization of Petroleum-Exporting Countries (OPEC), some political leaders and financiers have mainly attributed the price spike of oil in 2008 - followed by a just as spectacular drop in prices - to the speculative moves made by financial investors on the futures market instead of to market fundamentals

  15. Petroleum Vapor - Field Technical

    Science.gov (United States)

    The screening approach being developed by EPA OUST to evaluate petroleum vapor intrusion (PVI) requires information that has not be routinely collected in the past at vapor intrusion sites. What is the best way to collect this data? What are the relevant data quality issues and ...

  16. Non-Petroleum Oils

    Science.gov (United States)

    These include synthetics such as silicone fluids and tung oils, wood-derivative oils such as resin/rosin, animal fats/oil, and seed oils. Many have similar physical properties to petroleum-based, such as water insolubility and formation of slicks.

  17. Residual concentrations of micropollutants in benthic mussels in the coastal areas of Bohai Sea, North China

    International Nuclear Information System (INIS)

    Liu Wenxin; Chen Jianglin; Lin Xiumei; Fan Yongsheng; Tao Shu

    2007-01-01

    Studies of heavy metals and organic pollutants in different benthic mussel species from Bohai Sea show that concentrations of Cd in mussels commonly exceed national biological quality standards. In addition, a site located in Laizhou Bay exhibits higher average concentrations of As, Hg and Pb with respect to the other sites. Residual levels of petroleum hydrocarbons at several sites in Liaodong Bay also exceed quality guidelines. Contents and compositional characteristics of DDT and its metabolites in mussels suggest the probability of recent inputs and potential ecological risks to the local benthic environment. - Residual Cd contents of mussels at many sites in Bohai Sea exceed national marine biological quality standard and compositions of DDT metabolites indicate recent inputs and potential risk

  18. Characterization of Petroleum Hydrocarbons in Post-Burn Crude Oil ...

    African Journals Online (AJOL)

    In the Niger delta, crude oil spilled soils are burned as a means of decontaminating the impacted soils. Gas chromatography - flame ionization detector (GCFID) analyses were performed on oil residues extracted from burnt spilled oil soil samples to facilitate detailed chemical composition and characterization of petroleum ...

  19. Petroleum product market outlook

    International Nuclear Information System (INIS)

    2005-09-01

    The influence of petroleum market disturbances on price increases was discussed with particular reference to Hurricane Katrina and the loss of refinery production and damage to oil infrastructure in the United States. The supply of petroleum products in Canada will be very tight heading into the winter of 2006, despite the fact that Canadian refineries are operating at full capacity to ensure an adequate supply of gasoline and diesel fuel for consumers. In addition to refinery production, petroleum supplies are also determined by the adequacy of inventories and the efficiency of the infrastructure in place to deliver products to where they are needed. The lack of spare capacity has reduced the flexibility of the North American refining system to respond to further disruptions. Refiners were asked to provide information on 4 areas of their operations in order for Natural Resources Canada to analyze the short-term outlook for petroleum products markets. The 4 areas included refinery utilization rates and capability to increase production; any planned refinery turnaround that would affect petroleum product supplies; inventory levels compared to levels in previous years; and, any logistical problems that could affect product distribution. A graph depicting the relationship between Canadian production of gasoline and domestic sales clearly illustrated the seasonal nature of gasoline consumption and that production in Canada is much higher than consumption. Canada exports large volumes of gasoline, primarily to the United States eastern seabord from refineries in Atlantic Canada. The trend is similar for diesel fuel. Demand for both gasoline and diesel is expected to continue to grow in 2005 as high prices have had a limited impact on demand growth. In general, the Ontario/Quebec region is short of gasoline and must import gasoline during the summer months to cover the shortfall. It was noted that motorists and homeowners who heat with oil will bear the burden of higher

  20. Reactivity of Athabasca residue and of its SARA fractions during residue hydroconversion

    Energy Technology Data Exchange (ETDEWEB)

    Verstraete, J.; Danial-Fortain, P.; Gauthier, T.; Merdrignac, I. [IFP-Lyon, Vermaison (France); Budzinski, H. [Bordeaux Univ. (France). ISM-LPTC, UMR CNRS

    2009-07-01

    Residue conversion processes are becoming increasingly important because of the declining market for residual fuel oil and a greater demand for middle distillates. Ebullated-bed hydroconversion is a commercially proven technology for converting heavy feedstocks with high amounts of impurities. The process enables the conversion of atmospheric or vacuum residues at temperatures up to 440 degrees C, and at liquid hourly space velocity (LHSV) conditions in the range of 0.15 to 0.5 per hour. A 540 degrees C conversion of up to 80 weight per cent can be achieved under these conditions. This paper reported on a research study conducted at IFP Lyon in which the residue hydroconversion in a large-scale ebullated bed bench unit was investigated to determine the impact of operating conditions and feed properties on yield and product qualities. Hydrogen was added to the feed in the bench units to keep a high hydrogen partial pressure and favour the catalytic hydroconversion reactions. In a typical test, the reactor was fed with 50 g of feedstock and 0.45 g of crushed equilibrium industrial NiMo catalyst, pressurized hydrogen and quickly heated at the reaction temperature. This paper also discussed the conversion of Athabasca bitumen residue in the large-scale pilot plant and also in the small scale batch reactor. The effect of operating temperature and space velocity was examined. The reactivity of the saturates, aromatics, resins and asphaltenes (SARA) fractions of the bitumen was studied separately in order to better understand the conversion mechanisms and reactivities. The Athabasca bitumen feed and SARA fractions were also analyzed in terms of standard petroleum analysis, SARA fractionation, elemental analysis, size exclusion chromatography (SEC) and 13C NMR. Hydroconversion experiments were conducted in the batch unit at different reaction temperatures and reaction times. A comparison of small-scale batch results with those obtained with the continuous large-scale bench

  1. Identification of petroleum pollution sources

    International Nuclear Information System (INIS)

    Begak, O.Yu.; Syroezhko, A.M.

    2001-01-01

    A possibility of preliminary identification of petroleum pollution sources was investigated on specimens of the Khanty-Mansi autonomous district six deposits and specimens of soil and water polluted by these petroleums. Investigations were conducted using IR Fourier spectroscopy and gamma spectrometry, as well as methods of chromato-mass spectrometry and capillary gas liquid chromatography. Every of studied samples of petroleum from different deposits have an individual radiation impression. Insignificant total content of radionuclides in samples is specific to the Khanty-Mansi petroleum region. Gamma spectrometry admits to identify potential source of petroleum pollution using radionuclides of uranium and thorium series [ru

  2. Petroleum supply monthly, January 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-15

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  3. Petroleum supply monthly, October 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-26

    The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.

  4. Petroleum Supply Monthly, August 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-10-30

    The Petroleum Supply Monthly (PSM) is one of a family of three publications produced by the Petroleum Supply Division within the Energy Information administration (EIA) reflecting different levels of data timeliness and completeness. The other two publications are the Weekly Petroleum Status Report (WPSR) and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) district movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics.

  5. Petroleum supply monthly, September 1991

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-30

    The Petroleum Supply Monthly (PSM) is one of a family of three publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other two publications are the Weekly Petroleum Status Report (WPSR) and the Petroleum Supply Annual (PSA). Data presented in PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administrations for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 states and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics. 65 tabs.

  6. Petroleum Supply Monthly, July 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-28

    Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 states and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.

  7. Yugoslavian Petroleum Refinery development program

    International Nuclear Information System (INIS)

    Ocic, Ozren

    1999-01-01

    This paper shows the analysis of the world petroleum industry development, being an important factor in planning the development of the Yugoslav petroleum industry and Pancevo Petroleum Refinery, as well. Then Yugoslav petroleum industry development is analysed, including the appropriate balances of crude oil production and crude oil products consumption. The way of realizing the basic targets are also proposed. Likewise, the analysis of the condition within West European refineries has been conducted, from the aspects of technology, energy consumption and environmental protection and the same analysis for Pancevo Petroleum Refinery has been presented, too. The analysis of the condition within the refineries in the European Union countries and comparing it with the condition within Pancevo Petroleum Refinery, makes it mainly possible to recognize the development programmes which should be realized in order that Pancevo Petroleum Refinery could reach the refining level of the EU countries. (Original)

  8. Landfilling of waste incineration residues

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Astrup, Thomas; Cai, Zuansi

    2002-01-01

    Residues from waste incineration are bottom ashes and air-pollution-control (APC) residues including fly ashes. The leaching of heavy metals and salts from the ashes is substantial and a wide spectrum of leaching tests and corresponding criteria have been introduced to regulate the landfilling...

  9. Do we have to fear a forth petroleum crash?

    International Nuclear Information System (INIS)

    Jestin-Fleury, N.

    1998-01-01

    This paper analyses the worldwide energy scenarios for the forecasting of petroleum supply and demand in the year 2020: competition with natural gas industry, oil reserves, resources, production, development of new technologies, investments, fields development, drop of production costs, exploitation of tar sands, extra-heavy crudes, bituminous shales, reduction of the petroleum consumption in the transportation sector (development of LPG and electric powered vehicles, chemical conversion of natural gas, fuel cells), increase of the OPEC countries production, evolution of nuclear energy and economical impact of a serious fight against greenhouse gases emission and climate changes. (J.S.)

  10. Heavy metals, salts and organic residues in old solid urban waste landfills and surface waters in their discharge areas: determinants for restoring their impact.

    Science.gov (United States)

    Pastor, J; Hernández, A J

    2012-03-01

    This study was designed to determine the state of polluted soils in the main landfills of the Community of Madrid (central Spain), as part of a continuous assessment of the impacts of urban solid waste (USW) landfills that were capped with a layer of soil 20 years ago. Our analysis of this problem has been highly conditioned by the constant re-use of many of the USW landfills, since they have never been the target of any specific restoration plan. Our periodical analysis of cover soils and soils from discharge areas of the landfills indicates soil pollution has worsened over the years. Here, we examined heavy metal, salts, and organic compounds in soil and surface water samples taken from 15 landfills in the Madrid region. Impacts of the landfill soil covers on nematode and plant diversity were also evaluated. These analyses continue to reveal the presence of heavy metals (Zn, Cu, Cr, Ni, Pb, Cd) in soils, and salts (sulphates, chlorides and nitrates) in soils and surface waters. In addition, non-agricultural organic compounds, mainly aromatic and aliphatic hydrocarbons, often appeared in very high concentrations, and high levels of insecticides such as gamma-HCH (lindane) were also detected in soils. Around 50% of the water samples collected showed chemical demand of oxygen (CDO) values in excess of 150 mg/l. Traces of phenolic compounds were detected in some landfills, some of which exhibited high levels of 2-chlorophenol and pentachlorophenol. All these factors are conditioning both the revegetation of the landfill systems and the remediation of their slopes and terrestrial ecosystems arising in their discharge areas. This work updates the current situation and discusses risks for the health of the ecosystems, humans, domestic animals and wildlife living close to these landfills. Copyright © 2011 Elsevier Ltd. All rights reserved.

  11. Impact of the Prestige oil spill on marsh soils: Relationship between heavy metal, sulfide and total petroleum hydrocarbon contents at the Villarrube and Lires marshes (Galicia, Spain); Impacto de la marea negra del Prestige en suelos de marisma: relacion entre los contenidos de metales pesados, sulfuros e hidrocarburos en las marismas de Villarrube y Lires (Galicia, Espana)

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, L.; Marcet, P.; Covelo, E.F.; Vega, F.A. [Department of Vegetable Biology and Soil Science, Vigo (Spain); Fernandez-Feal, L.; Fernandez-Feal, C. [Escuela Politecnica Superior, Universidad de la Coruna, Ferrol (Spain)

    2004-09-15

    The objectives of this study were to determine the effect of the Prestige oil spill on the total petroleum hydrocarbons and heavy metal contents of soils in two marshes (Lires and Villarrube, Galicia, Spain) and the relationship between their oxidation-reduction potential and the solubility of heavy metals with sulfide and sulfate contents. Soil samples were taken from polluted and unpolluted areas and their petroleum hydrocarbon contents, heavy metal contents and other chemical characteristics were measured. The soils affected by the oil spill show remarkable contents of Cr, Cu, Ni, Pb and V. The Lires marsh soils are more affected by fuel oil than Villarrube marsh. The effects of the contaminating agents on the soils reach distances of up to 500 m from the coastline. In the first 400 m, there are important spatial variations because the fuel oil penetrated into the soils through tidal action and not directly. The Cr, Cu, Ni, Pb and V contents of polluted soils were between 50 and 200 times higher than those of their unpolluted counterparts and the background concentrations in Galician coastal sediments. In the case of Cr, Cu, Ni, Pb and V, their origin through the fuel oil was corroborated by the high correlation (r > 0.90) between the concentrations of these metals and the total petroleum hydrocarbon content of the polluted soils, which shows the combined addition of these metals through the fuel oil. [Spanish] Los objetivos de este trabajo fueron determinar el efecto de la marea negra del buque tanque Prestige en el contenido total de hidrocarburos y de metales pesados en suelos de dos marismas (Lires y Villarrube, Galicia, Espana) y la relacion entre el potencial de oxidacion-reduccion y la solubilidad de los metales pesados con los contenidos de sulfuros y de sulfatos. Se tomaron muestras de suelos de las zonas contaminadas y no contaminadas y se determinaron diversas caracteristicas quimicas, el contenido total de hidrocarburos y de metales pesados. Los

  12. Experimental Assessment of the Mass of Ash Residue During the Burning of Droplets of a Composite Liquid Fuel

    Science.gov (United States)

    Glushkov, D. O.; Zakharevich, A. V.; Strizhak, P. A.; Syrodoi, S. V.

    2018-05-01

    An experimental study has been made of the regularities of burning of single droplets of typical compositions of a composite liquid fuel during the heating by an air flow with a varied temperature (600-900 K). As the basic components of the compositions of the composite liquid fuel, use was made of the: waste of processing (filter cakes) of bituminous coals of ranks K, C, and T, waste motor, turbine, and transformer oils, process mixture of mazut and oil, heavy crude, and plasticizer. The weight fraction of a liquid combustible component (petroleum) product) ranged within 0-15%. Consideration has been given to droplets of a composite liquid fuel with dimensions (radius) of 0.5 to 2 mm. Conditions of low-temperature initiation of combustion to ensure a minimum possible mass of solid incombustible residue have been determined. Petroleum products have been singled out whose addition to the composition of the composite liquid fuel tends to increase the ash mass (compared to the corresponding composition without a liquid combustible component). Approximation dependences have been obtained which permit predicting the influence of the concentration of the liquid petroleum product as part of the composite liquid fuel on the ash-residue mass.

  13. Study of variation grain size in desulfurization process of calcined petroleum coke

    Science.gov (United States)

    Pintowantoro, Sungging; Setiawan, Muhammad Arif; Abdul, Fakhreza

    2018-04-01

    Indonesia is a country with abundant natural resources, such as mineral mining and petroleum. In petroleum processing, crude oil can be processed into a source of fuel energy such as gasoline, diesel, oil, petroleum coke, and others. One of crude oil potentials in Indonesia is petroleum coke. Petroleum coke is a product from oil refining process. Sulfur reducing process in calcined petroleum cokes can be done by desulfurization process. The industries which have potential to become petroleum coke processing consumers are industries of aluminum smelting (anode, graphite block, carbon mortar), iron riser, calcined coke, foundry coke, etc. Sulfur reducing process in calcined petroleum coke can be done by thermal desulfurization process with alkaline substance NaOH. Desulfurization of petroleum coke process can be done in two ways, which are thermal desulfurization and hydrodesulphurization. This study aims to determine the effect of various grain size on sulfur, carbon, and chemical bond which contained by calcined petroleum coke. The raw material use calcined petroleum coke with 0.653% sulfur content. The grain size that used in this research is 50 mesh, then varied to 20 mesh and 100 mesh for each desulfurization process. Desulfurization are tested by ICP, UV-VIS, and FTIR to determine levels of sulfur, carbon, chemical bonding and sulfur dissolved water which contained in the residual washing of calcined petroleum coke. From various grain size that mentioned before, the optimal value is on 100 mesh grain size, where the sulfur content in petroleum coke is 0.24% and carbon content reaches the highest level of 97.8%. Meanwhile for grain size 100 mesh in the desulfurization process is enough to break the chemical bonds of organic sulfur in petroleum coke.

  14. New guidelines for oil spill identification of waterborne petroleum and petroleum products

    Energy Technology Data Exchange (ETDEWEB)

    Faksness, L.G.; Daling, P.S. [SINTEF Energy Research, Trondheim (Norway); Hansen, A.B. [National Environmental Research Inst., Roskilde (Denmark); Kienhuis, P. [RIZA, (Netherlands); Duus, R. [Norwegian Standard Association (Norway)

    2005-07-01

    Advances in interpretive and analytical methods have opened the possibility to improve the existing Nordtest methodology for oil spill identification which was developed in 1991 under the Nordic Council of Ministers. In 2002, the European Committee for Standardization (CEN) established 2 working groups to revise the Nordtest Methodology into the following 2 CEN guidelines: (1) oil spill identification which includes waterborne and petroleum products, and (2) oil spill identification which in addition to including waterborne petroleum and petroleum products, includes analytical methodology and interpretation of results. The revised methodology includes a protocol/decision chart that has 3 tiered levels of analyses and data treatment. The methodology relies on the characterization of diagnostic ratios. The CEN working group intends to use the guidelines as a basis for a national oil spill identification protocol in each European country and for further international use. The methodology can be applied to oil samples of petrogenic origin with boiling points above 200 degrees C, such as crude oils, diesel fuel oils, residual bunker oils, lubricants, and mixtures of oily bilge and sludge samples. It is not intended for automotive gasolines or other light petroleum products. The method has been implemented in most forensic laboratories in Europe and has successfully differentiated between oils from a spill and possible pollution sources. 19 refs., 4 tabs., 10 figs.

  15. New guidelines for oil spill identification of waterborne petroleum and petroleum products

    International Nuclear Information System (INIS)

    Faksness, L.G.; Daling, P.S.; Hansen, A.B.; Kienhuis, P.; Duus, R.

    2005-01-01

    Advances in interpretive and analytical methods have opened the possibility to improve the existing Nordtest methodology for oil spill identification which was developed in 1991 under the Nordic Council of Ministers. In 2002, the European Committee for Standardization (CEN) established 2 working groups to revise the Nordtest Methodology into the following 2 CEN guidelines: (1) oil spill identification which includes waterborne and petroleum products, and (2) oil spill identification which in addition to including waterborne petroleum and petroleum products, includes analytical methodology and interpretation of results. The revised methodology includes a protocol/decision chart that has 3 tiered levels of analyses and data treatment. The methodology relies on the characterization of diagnostic ratios. The CEN working group intends to use the guidelines as a basis for a national oil spill identification protocol in each European country and for further international use. The methodology can be applied to oil samples of petrogenic origin with boiling points above 200 degrees C, such as crude oils, diesel fuel oils, residual bunker oils, lubricants, and mixtures of oily bilge and sludge samples. It is not intended for automotive gasolines or other light petroleum products. The method has been implemented in most forensic laboratories in Europe and has successfully differentiated between oils from a spill and possible pollution sources. 19 refs., 4 tabs., 10 figs

  16. Petroleum resources assessment 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-01

    This report consists of two articles. (1) Petroleum resources assessment of the Okinawa Trough: The hydrocarbon potential has been evaluated for the Tertiary strata in the northwestern margin of the Okinawa Trough on the basis of the pale-ontological, petrological, geochemical data from two wells (Nikkan 8-9 and JDZ 7-3), and geophysical data. (2) Petroliferous basin analysis in Jinju area (2): Petroleum geological studies such as stratigraphy, sedimentology, petrology and organic geochemistry were carried out in the Gyeongsang Supergroup, Junju area. Based on lithofacies and rock color, the sequence can be divided into seven formations which can be organized into two groups (Sindong Group: Nagdong, Hasandong and Jinju formations in ascending order; Hayang Group: Chilgog, Silla Conglomerate, Haman and Jindong formations). (author). 57 refs.

  17. China's petroleum industry

    International Nuclear Information System (INIS)

    Boykiw, A.; Katsuris, D.

    1997-01-01

    Petroleum and natural gas resources, industry organization, production, pipeline construction and other transportation issues, refining and business aspects of the Chinese petroleum and natural gas industries were reviewed. The need for large amounts of foreign capital and western technology to stem the deficit in domestic hydrocarbon supply were emphasized as being responsible for the creation in China of favourable conditions for foreign participation in oil and gas exploration, and for the growing confidence for Western investment in China. The most important considerations for successful participation in the economic development of China include: understanding the roles of networking, cultural affinity and reciprocity; hands-on management; finding an appropriate business partner, agent/distributor, or joint venture partner; and understanding local peculiarities and customs. 3 refs

  18. Geopolitics of petroleum

    International Nuclear Information System (INIS)

    Sebille-Lopez, Ph.

    2006-01-01

    The unexpected rise of oil prices since 2004 reveals some structural weaknesses of oil markets in front of the evolution of demand. It conceals considerable stakes, more political than strategic, like the securing of oil and petroleum product supplies of big consumers like the USA and China. This demand generates deep changes in the relations between the different actors, from Venezuela to Russia, from the Caspian sea to the Arab-Persian gulf, from the Mediterranean sea to the gulf of Guinea. Terrorists, who try to destabilize markets using threats on petroleum infrastructures, add-up a risk dimension to the uncertainties. The author proposes a world tour of the main production areas, along the 'oil roads' where the main strategic manoeuvres take place. He shades light on the main power stakes: pressure, tensions, threats and deals, alliances, ruptures and potential conflicts. The complex and multiple motivations are explained. (J.S.)

  19. India's Downstream Petroleum Sector

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    This study provides a holistic examination of pricing and investment dynamics in India's downstream petroleum sector. It analyses the current pricing practices, highlights the tremendous fiscal cost of current pricing and regulatory arrangements, and examines the sectoral investment dynamics. It also looks at potential paths towards market-based reform along which the Indian government may move, while at the same time protecting energy market access for India's large poor population.

  20. Deodorizing petroleum oils, etc

    Energy Technology Data Exchange (ETDEWEB)

    Haller, A

    1906-06-14

    A process of purifying and deodorizing petroleum oils, gasolines, ethers, benzines, shale oils, resins, and similar products, consisting essentially in passing the vapors of the liquids with a current of hydrogen or of gases high in hydrogen over divided metals, such as nickel, copper, cobalt, iron, platinum, etc., heated to a temperature between 100/sup 0/C and 350/sup 0/C, the vapors passing before entering the apparatus through a column of copper heated to above 350/sup 0/C.

  1. Applications of T-ray spectroscopy in the petroleum field

    Science.gov (United States)

    Al-Douseri, Fatemah M.

    2005-11-01

    Because of heavy usage of petroleum products, which are the main source of energy in daily life and industry, a fast, reliable, and portable analysis system is needed to complement traditional techniques. Terahertz (THz) radiation, or T-rays, is electromagnetic radiation in the 0.1 to 10 THz frequency range. One unique attribute of T-rays is their ability to sensitively measure the induced molecular dipole moments in non-polar liquids such as aromatics, which make up the majority of the contents of many petroleum products. This information can lead to several applications in petroleum analysis. The application of T-rays to petroleum product analysis has the potential to make a significant impact in the petroleum field. In this dissertation, I show the first use of T-ray time-domain spectroscopy and Fourier transform infrared (FTIR) spectroscopy techniques for petroleum product analysis. I report on the feasibility of analyzing selected petroleum products, including gasoline, diesel, lubricating oil, and selected compounds of toluene, ethylbenzene, and xylene (BTEX). With the use of a T-ray time-domain spectrometer. I demonstrate that gasolines with different octane numbers and diesel all show specific absorption coefficients and refractive indexes in the spectral range from 0.5 to 2.0 THz. Furthermore, I report the qualitative and quantitative analysis of selected BTEX components in gasoline and diesel using FTIR spectroscopy in the 50 to 650 cm-1 region. I distinguish gasolines with different octane numbers from diesel and lubricating oil according to their different spectral features. I also determine the concentration of (o, m, p) xylene isomers in gasoline according to their specific absorption bands. The experimental results in this thesis, imply that linking between the knowledge of petroleum products and the development of T-ray spectrometer with the cooperation of industry might translate the T-ray spectroscopic system into a real world application in

  2. Catalysts in petroleum refining and petrochemical industries 1995

    Energy Technology Data Exchange (ETDEWEB)

    Absi-Halabi, M.; Beshara, J.; Qabazard, H.; Stanislaus, A. [eds.] [Petroleum, Petrochemicals and Materials Division, Kuwait Institute of Scientific Research, Kuwait (Kuwait)

    1996-07-01

    Catalysis plays an increasingly critical role in modern petroleum refining and basic petrochemical industries. The market demands for and specifications of petroleum and petrochemical products are continuously changing. They have impacted the industry significantly over the past twenty years. Numerous new refining processes have been developed and significant improvements were made on existing technologies. Catalysts have been instrumental in enabling the industry to meet the continuous challenges posed by the market. As we enter the 21st century, new challenges for catalysis science and technology are anticipated in almost every field. Particularly, better utilization of petroleum resources and demands for cleaner transportation fuels are major items on the agenda. It is against this background that the 2nd International Conference on Catalysts in Petroleum Refining and Petrochemical Industries was organized. The papers from the conference were carefully selected from around 100 submissions. They were a mix of reviews providing an overview of selected areas, original fundamental research results, and industrial experiences. The papers in the proceedings were grouped in the following sections for quick reference: Plenary Papers; Hydroprocessing of Petroleum Residues and Distillates; Fluid Catalytic Cracking; Oxidation Catalysis; Aromatization and Polymerization Catalysis; Catalyst Characterization and Performance. The plenary papers were mostly reviews covering important topics related to the objectives of the conference. The remaining sections cover various topics of major impact on modern petroleum refining and petrochemical industries. A large number of papers dealt with hydroprocessing of petroleum distillates and residues which reflects the concern over meeting future sulfur-level specifications for diesel and fuel oils

  3. Comparative acute toxicity of shale and petroleum derived distillates.

    Science.gov (United States)

    Clark, C R; Ferguson, P W; Katchen, M A; Dennis, M W; Craig, D K

    1989-12-01

    In anticipation of the commercialization of its shale oil retorting and upgrading process, Unocal Corp. conducted a testing program aimed at better defining potential health impacts of a shale industry. Acute toxicity studies using rats and rabbits compared the effects of naphtha, Jet-A, JP-4, diesel and "residual" distillate fractions of both petroleum derived crude oils and hydrotreated shale oil. No differences in the acute oral (greater than 5 g/kg LD50) and dermal (greater than 2 g/kg LD50) toxicities were noted between the shale and petroleum derived distillates and none of the samples were more than mildly irritating to the eyes. Shale and petroleum products caused similar degrees of mild to moderate skin irritation. None of the materials produced sensitization reactions. The LC50 after acute inhalation exposure to Jet-A, shale naphtha, (greater than 5 mg/L) and JP-4 distillate fractions of petroleum and shale oils was greater than 5 mg/L. The LC50 of petroleum naphtha (greater than 4.8 mg/L) and raw shale oil (greater than 3.95 mg/L) also indicated low toxicity. Results demonstrate that shale oil products are of low acute toxicity, mild to moderately irritating and similar to their petroleum counterparts. The results further demonstrate that hydrotreatment reduces the irritancy of raw shale oil.

  4. Industrial, agricultural, and petroleum contaminants in cormorants wintering near the Houston Ship Channel, Texas, USA

    Science.gov (United States)

    King, K.A.; Stafford, C.J.; Cain, B.W.; Mueller, A.J.; Hall, H.D.

    1987-01-01

    Double-crested cormorants (Phalacrocorax auritus ) collected in the Houston Ship Channel, Texas, USA, in November shortly after their fall migration contained residues of several industrial, agricultural, and petroleum contaminants including polychlorinated styrenes (PCS's), polychlorinated biphenyls (PCB's), DDE, and petroleum hydrocarbons. PCS concentrations in over-wintering birds collected in late February were three times higher than those in birds collected in November. PCB and petroleum concentrations remained at about the same level throughout the 3-month winter period. Petroleum hydrocarbons were present in all cormorants and residues in some individuals exceeded 25 ppm (wet weight). Mean DDE residues in samples collected in November and February were less than 1 ppm. Low concentrations of five other organochlorine compounds, not detected in cormorants collected in November, were recovered in birds collected in February.

  5. Significance of treated agrowaste residue and autochthonous inoculates (Arbuscular mycorrhizal fungi and Bacillus cereus) on bacterial community structure and phytoextraction to remediate soils contaminated with heavy metals.

    Science.gov (United States)

    Azcón, Rosario; Medina, Almudena; Roldán, Antonio; Biró, Borbála; Vivas, Astrid

    2009-04-01

    In this study, we analyzed the impact of treatments such as Aspergillus niger-treated sugar beet waste (SB), PO4(3-) fertilization and autochthonous inoculants [arbuscular mycorrhizal (AM) fungi and Bacillus cereus], on the bacterial community structure in a soils contaminated with heavy metals as well as, the effectiveness on plant growth (Trifolium repens). The inoculation with AM fungi in SB amended soil, increased plant growth similarly to PO4(3-) addition, and both treatments matched in P acquisition but bacterial biodiversity estimated by denaturing gradient gel electrophoresis of amplified 16S rDNA sequences, was more stimulated by the presence of the AM fungus than by PO4(3-) fertilization. The SB amendment plus AM inoculation increased the microbial diversity by 233% and also changed (by 215%) the structure of the bacterial community. The microbial inoculants and amendment used favoured plant growth and the phytoextraction process and concomitantly modified bacterial community in the rhizosphere; thus they can be used for remediation. Therefore, the understanding of such microbial ecological aspects is important for phytoremediation and the recovery of contaminated soils.

  6. Future petroleum energy resources of the world

    Science.gov (United States)

    Ahlbrandt, T.S.

    2002-01-01

    and gas endowment estimates. Whereas petroleum resources in the world appear to be significant, certain countries such as the United States may run into import deficits, particularly oil imports from Mexico and natural gas from both Canada and Mexico. The new assessment has been used as the reference supply case in energy supply models by the International Energy Agency and the Energy Information Agency of the Department of Energy. Climate energy modeling groups such as those at Stanford University, Massachusetts Institute of Technology, and others have also used USGS estimates in global climate models. Many of these models using the USGS estimates converge on potential oil shortfalls in 2036-2040. However, recent articles using the USGS (2000) estimates suggest peaking of oil in 2020-2035 and peaking of non-OPEC (Organization of Petroleum-Exporting Countries) oil in 2015-2020. Such a short time framework places greater emphasis on a transition to increased use of natural gas; i.e., a methane economy. Natural gas in turn may experience similar supply concerns in the 2050-2060 time frame according to some authors. Coal resources are considerable and provide significant petroleum potential either by extracting natural gas from them, by directly converting them into petroleum products, or by utilizing them to generate electricity, thereby reducing natural gas and oil requirements by fuel substitution. Non-conventional oil and gas are quite common in petroleum provinces of the world and represent a significant resources yet to be fully studied and developed. Seventeen non-conventional AU including coal-bed methane, basin-center gas, continuous oil, and gas hydrate occurrences have been preliminarily identified for future assessment. Initial efforts to assess heavy oil deposits and other non-conventional oil and gas deposits also are under way.

  7. Comparative assessment of structural-mechanical properties of heavy oils of timano-pechorskaya province

    Directory of Open Access Journals (Sweden)

    Н. К. Кондрашева

    2017-06-01

    Full Text Available The physicochemical properties of heavy oils of Yaregskoe and Usinskoe deposits and the residues of atmospheric distillation of petroleum (fuel oil recovered from them are presented. The group composition of oil and the residues of its atmospheric distillation (fuel oil is determined. When using X-ray fluorescence energy dispersive spectrometer, the content of metals in the products is determined. A conclusion is drawn about the distribution of metals in the initial oil and fuel oil. On the basis of rheological characteristics, the type of liquids is determined in accordance with Newton's law, as well as the presence of an anomaly in the viscosity of the studied media at different temperatures. The energy values of the thixotropy of heavy oils of Usinskoe and Yaregskoe deposits, as well as the activation energy of the viscous flow of all media studied, are obtained. The phase transition of atmospheric residues at 60 °C is discovered. Dependences of the enthalpy and entropy of the viscous flow of the studied hydrocarbon media are obtained with an increase in temperature from 10 to 140 °C. The dependences of the oil molecules and atmospheric residues jumping frequency on viscosity are obtained for the first time.

  8. Problems of radiation safety of petroleum and gas production

    International Nuclear Information System (INIS)

    Garibov, A.A.

    2002-01-01

    Oil and gas production is the basis of economy of the Azerbaijan Republic and its cause in ecological and radioecology problems. One form this problem is the pollution by radionuclides of environment at the time of gas and petroleum production. At the time of petroleum and gas production the three-phase radionuclides are emitted in atmosphere: Emissions consisted from solid U-238, Ra-226, Th-232, K-40 discharged to atmosphere at the time of production, exploring and exploitation of petroleum and gas. They are presented in compounds of sand, clay, and petroleum residues; During the drilling and production the gross quantities of water flows out and collects. These water areas consist of radium, uranium, Th and K-40 dissolved in water salts; There are the radionuclides being in 902 condition emitted in atmosphere at the places of petroleum and gas production. The radon and its isotopes are emitted at this time; At the places of petroleum and gas production it is observed at local pollution areas polluted by solid emissions that at this territories the doze of exposition power variable 100 - 1000 micro/hour. The radioactivity at this system according to 2-1000 year/k consists from Ra, K-40, and U. At this areas the value of total background changes 5 - 1000 micro R/hour. The total radioactivity of water polls formed at the places of petroleum and gas production consisted 50 -150 Bq/L. In the case of gas the separated radionuclides are mainly consisted from Radon and its isotopes. In the compound of produced gas the concentration of radon varied 20 - 1700 Bq/m 3 . Thus, at the places of petroleum and gas production radioactive pollutants emitted to atmosphere, forms the polluted environment for working and living people at the same territory. This problem's status haven't been investigated thoroughly, the sources of pollution hasn't been uncovered concretely, the cleaning technology for polluted areas is unknown

  9. 2005 yearly days of petroleum

    International Nuclear Information System (INIS)

    Constant, R.; Susbielles, G.

    2005-01-01

    14 articles are gathered in this data sheet; they deal with the opening address of the 2005 petroleum days; the hydrocarbons: the evolutive resource; the para-petroleum engineers and the Europe; the speech of Mr Francois Loos; the Shell global scenarios to 2025; the evolution of the gas resource and its uses; the French para-petroleum industry; Bernard Bensaid, Corinne Sagary, Armelle Saniere, economic studies, IFP; the contribution of the innovation and of the technology in the diversification of the hydrocarbons supply; innovation and diversification of the petroleum resource: the point of view of Total; research, development and diversification of the petroleum resource; innovation in services companies; innovation in study and development and engineering; the closing address of the 2005 petroleum days. (O.M.)

  10. Basic petroleum research. Final report

    International Nuclear Information System (INIS)

    Roesjoe, Bjarne; Stiksrud, Helge

    2004-01-01

    An overview of projects in the field of basic petroleum research (PetroForsk) is presented. A brief presentation of some of the projects is included, as well as political comments on the value of these projects. The research program Basic Petroleum Research (PetroForsk) was established in 1998 and ended in 2004. The program has been part of the Research Council of Norway's long-term effort in petroleum research (ml)

  11. Indicators on the world petroleum markets

    International Nuclear Information System (INIS)

    2000-10-01

    This paper presents tendencies of the petroleum industry market. It analyses the petroleum demand and supply, the prices elaboration, the petroleum market and the OPEC objective, the third petroleum crisis of the year 2000 and gives some data concerning the petroleum market. (A.L.B.)

  12. Selling petroleum to the military

    International Nuclear Information System (INIS)

    Uscher, R.H.

    1999-01-01

    This article examines what petroleum products and services the US military buys, the contracts awarded to Asian and European refiners for supplies outside the USA, and military specifications and test methods including the specifications of JP-8 battlefield fuel and the JP-8+100 additive package for military aircraft. The way in which the military buys petroleum products is described, and details are given of the types of military contracts, the bidding on Defense Energy Support Center (DESC) petroleum contracts, the performance of military petroleum contracts, socio-economic programmes, the Prompt Payment Act requiring contractors to be paid promptly, and procedures for claims and disputes

  13. Reference data about petroleum fiscality

    International Nuclear Information System (INIS)

    2006-01-01

    This paper explains the different taxes existing in France for the petroleum products (domestic tax on petroleum products, added-value tax), the share of taxes in the retail price, the differences with other European countries, the French Government fiscal receipts and budget. Some information forms are attached to this document and concern: the formation of fuel prices (upstream, refining and transport-distribution margins), the evolution of annual average transport-distribution margins, some reference data about world petroleum markets (supply and demand, prices, market data), and some reference data about the role of oil companies on the petroleum market. (J.S.)

  14. 19 CFR 151.47 - Optional entry of net quantity of petroleum or petroleum products.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 2 2010-04-01 2010-04-01 false Optional entry of net quantity of petroleum or petroleum products. 151.47 Section 151.47 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF... Petroleum and Petroleum Products § 151.47 Optional entry of net quantity of petroleum or petroleum products...

  15. Heavy metal extraction from produced water in the petroleum industry utilizing vegetal oil derivatives as the extractant; Extracao de metais pesados a partir de aguas produzidas na industria do petroleo utilizando derivados de oleo vegetal como extratante

    Energy Technology Data Exchange (ETDEWEB)

    Santana, Dulcineia de Castro [Centro Federal de Educacao Tecnologica de Goias (CEFET/GO), Goiania (Brazil). Coordenacao de Mineracao], e-mail: dcs@cefetgo.br, e-mail: dcs@eq.ufrn.br; Paulo, Joao Bosco de Araujo [Universidade Federal do Rio Grande do Norte (UFRN), Natal (Brazil). Centro de Tecnologia. Dept. de Engenharia Quimica], e-mail: jbosco@eq.ufrn.br; Lima, Raquel Franco de Souza [Universidade Federal do Rio Grande do Norte (UFRN), Natal (Brazil). Centro de Ciencias Exatas e da Terra. Dept. de Geologia], e-mail: raquel@geologia.ufrn.br; Brandao, Paulo Roberto Gomes [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Escola de Engenharia], e-mail: pbrandao@demin.ufmg.br; Fernandes Junior, Wilaci Eutropio [PETROBRAS, RN/CE (Brazil). Unidade de Negocio de Exploracao e Producao do Rio Grande do Norte e Ceara. Gerencia de Desenvolvimento da Producao], e-mail: wilaci@petrobras.com.br

    2007-12-15

    It is well known today that, although being a renewable resource, potable water could also be finite. In the environmental context, very often due to operational costs, the development of new water recycling techniques become significant when faced with the simple adaptation of effluent treatment before final disposal. Produced water comes from exploration operations and/or the production of oil and gas and is generally treated. Following the treatment, part of the produced water is recycled in secondary re-injection operations or steam generation. The remainder, which is the biggest amount, is expelled into the sea through underwater outlets. Millions of liters of water are expelled per day, containing heavy metals such as lead (Pb), cadmium (Cd) and nickel (Ni) in low concentrations. Some of this volume could be recycled for use in the irrigation of oleaginous cultures after this water has been given a suitable post-treatment. This treatment being specified in agreement with Class 3, of CONAMA Resolution No 357 (Brazil, 2005), which establishes the contents as <0,033 mg/L for Pb, <0,01 mg/L for Cd and <0,025 mg/L for Ni. Liquid-liquid extraction is a well known technology for the recovery of metals in aqueous mediums. This work studies the extraction of Pb, Cd, and Ni from a synthetic solution, using QAV solvent (aviation kerosene); and vegetal oil derivatives as the extractant. It is well known that vegetal oil derivatives have a strong complexation power on metals. A bench test basic investigation was made with the objective of studying the selectivity of coconut oil derivatives in the extraction of metals from synthetic solutions. The determination of the heavy metal concentrations in a complex matrix was made by using the atomic absorption spectrometry technique (AAS). The results of the preliminary experiments were promising. (author)

  16. Petroleum hydrocarbon concentrations in eight mollusc species along Tamilnadu coast, Bay of Bengal, India.

    Science.gov (United States)

    Veerasingam, S; Venkatachalapathy, R; Sudhakar, S; Raja, P; Rajeswari, V

    2011-01-01

    Eight mollusc species and sediment samples collected from three different stations along Tamilnadu coast, Bay of Bengal, India were analysed for the levels of petroleum hydrocarbons to elucidate the status of the petroleum residues in mollusc meant for human consumption. The concentrations of petroleum hydrocarbons in sediments along Tamilnadu coast varied from 5.04-25.5 microg/g dw (dry weight). High concentration of petroleum hydrocarbons in the sediment of Uppanar estuary (25.5 +/- 1.45 microg/g dw) was perhaps land and marine based anthropogenic sources of this region. The petroleum hydrocarbon residues in eight mollusc species collected from Uppanar, Vellar and Coleroon estuaries varied between 2.44-6.04 microg/g ww (wet weight). Although the concentration of petroleum hydrocarbons in sediment of the Uppanar region was markedly higher than the background, the petroleum hydrocarbon residues in mollusc collected from Uppanar estuary did not suggest bioaccumulation. The results signified that industrial growth has affected the aquatic environments and regular monitoring will help to adopt stringent pollution control measures for better management of the aquatic region.

  17. Petroleum abundance until when

    International Nuclear Information System (INIS)

    Appert, O.

    1996-01-01

    The petroleum demand goes on to increase. In front of this demand the non Opec supply increases because of new positive explorations, new technologies and a reduction of exploration-production prices. With 10% of worldwide reserves, OECD insures 30% of worldwide production. With 18% of reserves, the non-Opec world insures 48% of worldwide needs. But a return on Middle East where are 65% of reserves is inescapable but it can be all the more brutal since non Opec world consumes its own resources more quickly. 7 figs

  18. International petroleum statistics report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    The International Petroleum Statistics Report is a monthly publication that provides current international oil data. This report presents data on international oil production, demand, imports, exports and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). Section 2 presents an oil supply/demand balance for the world, in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries.

  19. Petroleum supply monthly, March 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-30

    Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. Most time series include preliminary estimates for one month based on the Weekly Petroleum Supply Reporting System; statistics based on the most recent data from the Monthly Petroleum Supply Reporting System (MPSRS); and statistics published in prior issues of the PSM and PSA. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. In most cases, the statistics are presented for several geographic areas -- the United States (50 States and the District of Columbia), five PAD Districts, and 12 Refining Districts. At the US and PAD District level, the total volume and the daily rate of activities are presented. The statistics are developed from monthly survey forms submitted by respondents to the EIA and from data provided from other sources.

  20. Heavy leptons

    International Nuclear Information System (INIS)

    Smith, C.H.L.

    1977-01-01

    The possibility that a new lepton may exist is discussed under the headings; theoretical reasons for the introduction of heavy leptons, classification of heavy leptons (ortho and paraleptons), discrimination between different types of lepton, decays of charged heavy leptons, production of charged heavy leptons (in e + e - storage rings, neutrino production, photoproduction, and hadroproduction), neutral heavy leptons, and hadroleptons. (U.K.)

  1. International petroleum statistics report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    The International Petroleum Statistics Report is a monthly publication that provides current international oil data. This report is published for the use of Members of Congress, Federal agencies, State agencies, industry, and the general public. Publication of this report is in keeping with responsibilities given the Energy Information Administration in Public Law 95-91. The International Petroleum Statistics Report presents data on international oil production, demand, imports, and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). This section contains annual data beginning in 1985, and monthly data for the most recent two years. Section 2 presents an oil supply/demand balance for the world. This balance is presented in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. This section contains annual data for the most recent year, quarterly data for the most recent two quarters, and monthly data for the most recent twelve months. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries. World oil production and OECD demand data are for the years 1970 through 1995; OECD stocks from 1973 through 1995; and OECD trade from 1985 through 1995.

  2. Canadian petroleum industry

    Energy Technology Data Exchange (ETDEWEB)

    Dagher, J.H.

    1969-12-01

    This study covers the following Canadian petroleum industry categories: (1) a brief history; (2) the demand for Alberta crude; (3) U.S. oil policies; (4) overseas exploration; (5) the national oil policy; (6) the Montreal pipeline and its targets; (7) a continental oil policy; and (8) the impact of Arctic reserves. It is noted that large potential benefits will improve from the Manhattan navigating the Northwest Passage. Without prejudging the analysis now applied to the information gathered on this voyage, the Manhattan has greatly contributed to the solution of the problem of access to the Arctic islands. The picture for natural gas is less fraught with uncertainties. Unlike oil, where domestic and international considerations may weigh in U.S. policy decision, Canadian natural gas is likely to be allowed to enjoy its full economic potential in bridging the foreseeable U.S. supply gap and, inasmuch as this potential is ultimately tied with that for crude oil markets, the anticipated U.S. needs for Canadian natural gas may be expected to enhance U.S. interest in the overall well-being of the Canadian petroleum industry.

  3. The future petroleum geologist

    International Nuclear Information System (INIS)

    Berg, R.R.

    1992-01-01

    This paper reports that in July 1985, AAPG President William L. Fisher appointed a select committee to determine the capabilities that will be required of petroleum geologists in the future. His charge to the committee was based on the profound changes and uncertainties that were beginning to be felt in the industry and would surely affect the employment of geologists and their professional practice. These changes are well known: the supply of oil had exceeded demand, the price of oil was unstable, many companies were threatened by debt and buy-outs, and corporate restructuring was underway to meet changing economic conditions. All contributed to great uncertainty about the need and requirements of geological employment and practice. Specifically, President Fisher charged the committee to distinguish those elements of recent times that are cyclic and those that are long-term in their effects; to characterize the state of the industry for the next 25 years; to predict the capabilities that the future petroleum geologist should posses to meet the challenges of the future; and most importantly, the define the role of AAPG and its commitments to the membership under these changing conditions

  4. Petroleum resources assessment (I)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    This report consists of 2 subjects. 1) Petroleum resources assessment on the western part of the Kunsan Basin: Palynomorphs including spores, pollen and organic-walled microfossils and calcareous microfossils such as ostracods, charophytes and gastropods were studied for the biostratigraphic work of Kachi-1 and IIH-1Xa wells. Based on available well data, the rifting probably began in the Cretaceous time had continued until Paleocene. It is considered that compressional force immediately after rifting event deformed sedimentary sections. During the period of Paleocene to middle Miocene, the sediments were deposited in stable environment without particular tectonic event. 2) Petroliferous basin analysis in Taegu area (II): The Nakdong and Jinju formations contain abundant black shales, and thermal maturity of the organic matter reached at the final stage of dry gas generation. These formations also contain thick sandstones which can act as a petroleum reservoir. However, reservoir quality of the sandstones is poor (porosity: < 5%; permeability: < 0.001 md). In these sandstones, secondary pores such as dissolution pores and micropores can act as a tight gas reservoir. (author). 56 refs., 24 tabs., 68 figs.

  5. Facts 2010 - The Norwegian petroleum sector

    Energy Technology Data Exchange (ETDEWEB)

    2010-07-01

    The publication provides a general overview of information regarding the petroleum activities on the Norwegian continental shelf. Content; Foreword; The petroleum sector - Norway's largest industry; Organisation of Norwegian petroleum activity; Government petroleum revenues; Exploration activities; Development and operations; Norwegian gas exports; Decommissioning; Research, technology and industrial development; Environmental considerations in the Norwegian petroleum sector; Petroleum resources; Fields in production; Fields under development; Future developments; Fields where production has ceased; Pipelines and onshore facilities. (AG)

  6. Facts 2010 - The Norwegian petroleum sector

    Energy Technology Data Exchange (ETDEWEB)

    2010-07-01

    The publication provides a general overview of information regarding the petroleum activities on the Norwegian continental shelf. Content; Foreword; The petroleum sector - Norway's largest industry; Organisation of Norwegian petroleum activity; Government petroleum revenues; Exploration activities; Development and operations; Norwegian gas exports; Decommissioning; Research, technology and industrial development; Environmental considerations in the Norwegian petroleum sector; Petroleum resources; Fields in production; Fields under development; Future developments; Fields where production has ceased; Pipelines and onshore facilities. (AG)

  7. Facts 2011 - The Norwegian petroleum sector

    Energy Technology Data Exchange (ETDEWEB)

    2011-07-15

    The publication provides a general overview of information regarding the petroleum activities on the Norwegian continental shelf. Content; Foreword; The petroleum sector - Norway's largest industry; Organisation of Norwegian petroleum activity; Government petroleum revenues; Exploration activities; Development and operations; Norwegian gas exports; Decommissioning; Research, technology and industrial development; Environmental considerations in the Norwegian petroleum sector; Petroleum resources; Fields in production; Fields under development; Future developments; Fields where production has ceased; Pipelines and onshore facilities. (AG)

  8. La conversion des résidus et huiles lourdes : au carrefour du thermique et du catalytique Conversion of Residues and Heavy Oils At the Crossroads of Thermal Cracking and Catalytic Reactions

    Directory of Open Access Journals (Sweden)

    Le Page J. F.

    2006-11-01

    Full Text Available Cet article passe en revue les diverses familles de procédés de conversion des résidus et huiles lourdes. Tous les résultats semblent converger pour accréditer l'idée que dans tous ces procédés, y compris les procédés dits catalytiques, l'essentiel de la conversion des espèces de poids moléculaire élevé, résines et asphaltènes, procède par mécanisme radicalaire : la clef de la conversion profonde, c'est paradoxalement la maîtrise de la condensation radicalaire de ces espèces. Hydrogène seul, hydrogène en présence de solvant donneur, d'additifs ou encore mieux de catalyseurs, sont les armes dont dispose tout raffineur pour affirmer cette maîtrise, dans la mesure où il ne tient pas à fabriquer du coke. Tous ces procédés de conversion des résidus donnent par ailleurs naissance à des produits craqués dont la nature et la distribution rappellent celles des produits de première distillation du pétrole brut dont est issu le résidu soumis au craquage. This article reviews the different families of conversion processes for residues and heavy oils. All the results seem to converge to support the idea that in all these processes, including so-called catalytic processes, most of the conversion of high-molecular-weight species (resins and asphaltenes operates by a radical mechanism. The key to in-depth conversion is, paradoxically, the mastery of the radical condensation of these species. Hydrogen alone, hydrogen in the presence of a donor solvent, of additives or, better yet, of catalysts, are the arms at the disposal of all refiners to assert this mastery, to the extent that they do not want to manufacture coke. All such conversion processes for residues also give rise to cracked products whose nature and distribution recall those of first-distillation products of crude oil, from which the residue comes that is subjected to cracking.

  9. Petroleum industry assists hurricane relief

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper reports that the petroleum industry is aiding victims of last month's Hurricane Andrew with cash, clothing, food, water, and other supplies. Cash contributions announced as of last week totaled more than $2.7 million for distribution in South Florida and South Louisiana. Petroleum industry employees were collecting relief items such as bottled water and diapers for distribution in those areas

  10. The para-petroleum industry

    International Nuclear Information System (INIS)

    2002-07-01

    The para-petroleum industry includes societies that realize studies and installations for the deposits exploitation. This document presents the situation of the para-petroleum industry in 2001, the world investment growth of the activity, the french societies financial results and an inventory of the main operations in the amalgamation domain. (A.L.B.)

  11. Petroleum Biotechnology. Developments and Perspectives

    International Nuclear Information System (INIS)

    Vazquez-Duhalt, R.; Quintero-Ramirez, R.

    2004-01-01

    This book deals with the field of petroleum biorefining and biological upgrade of petroleum; it presents a critical review as well as an integrated overview of the potential biochemical processes, bridging the gap between academia and industry. It addresses today's demanding production challenges, taking into account energy efficient and environmentally friendly processes, and also looks at the future possibility of implementing new refinery systems

  12. Petroleum: An energy profile, 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    This report prepared by the Energy Information Administration covers the following topics: petroleum production and end-use sectors; resources and reserves; exploration and production; LPG sources and processing; motor gasoline octane enhancement; constructing pipelines; the strategic petroleum reserve; imports and exports; marketing; district descriptions and maps; and refinery processes and facilities. 33 figs., 7 tabs.

  13. Heavy metals speciation in solid household waste incineration residues and contribution to the interpretation of volatilization processes; Speciation des metaux lourds dans les residus solides d'usines d'incineration d'ordures menageres et contribution a l'interpretation des processus de vaporisation

    Energy Technology Data Exchange (ETDEWEB)

    Gagnepain, B.

    1998-07-01

    Different types of solid residues of incineration plants have at first been analyzed by complementary techniques. Relative tendencies to the heavy metals speciation have been established. On the one hand, the chemical trapping of heavy metals by ashes as well as their respective mobilities have been characterized by the sequential extraction method. On the other hand, morphology of ashes, localization, repartition and chemical environment of heavy metals have been studied by X-ray microanalysis. It has been shown that Cd and Zn are highly leachable, Cr, Ni and Cu are trapped in ashes and Pb, As have intermediary behaviours with a slow mobility. Concentration gradients of heavy metals in terms of the ashes granulometry have been deduced. An experimental device for studying the vaporization of heavy metals in a fluidized bed (simulation of the heavy metals release during the incineration of household wastes) has been perfected. Experiments have been carried out in conditions (temperature, gaseous atmosphere, residence time) near those of the real processes. A model, coupling the mass and heat transfers with a thermodynamic anticipation of the heavy metals behaviour has been developed and has allowed to exploit these obtained results. (O.M.)

  14. The new challenges of petroleum

    International Nuclear Information System (INIS)

    Gernelle, E.

    2006-02-01

    Petroleum in in the center of our civilization: abundant, easy to use and energy powerful, it is used almost everywhere: transports, lighting, space heating, plastics, fertilizers, cloth industry etc. The 'black-gold' is the object of all stakes, from richness to power. However, petroleum is also at the origin of many evils: pollution, corruption, violence. Today, petroleum is a source of worries: how long will it last? How long will we be able to stand its impacts on environment? This book shades light on all these questions and supplies some concrete elements about this energy source. Content: technological challenges of petroleum; producers: powers and risks; consumers' dependence; to learn more about petroleum. (J.S.)

  15. The petroleum refining industry and the implications for the environment

    International Nuclear Information System (INIS)

    Saraiva, Gerardo Jose de Pontes

    2000-01-01

    The petroleum refining industry is basically concerned with the production of oil, lubricants and intermediate petrochemical products, utilizing crude oil as its main raw material. Petroleum refining, a distillation process that breaks hydrocarbons into fractions, eliminating undesired impurities, generates irreducible residues. Until the industrial revolution, the residues were essentially organic, susceptible to the attack of agents of destruction and transformation (bacterium, fungi, etc). Suddenly, due to the intensification of human activities of modern man, nature scattered across the planet more resistant products, many of them with long life times, that produce a deeper impact in the environment. Almost entirely marine is the pollution that results from increasing quantity of hydrocarbons dumped into the sea, a problem that is aggravated by the development of manufacturing and transportation of petroleum products. The expansion of the petroleum commerce, using essentially maritime transportation, has increased considerably the probability of accidents increasing the risks of environment pollution. This work presents suggestions and possible solutions to minimize the problem of environment pollution, caused by refining and transportation of this combustible, essential to present time industry. (author)

  16. Characterization of residual oils for biodiesel production

    Directory of Open Access Journals (Sweden)

    Edmilson Antonio Canesin

    2014-01-01

    Conclusions: The obtained results suggesting that it is possible to take advantage of these residues for biodiesel production as the obtained products were approved according to the rules established by the National Association of Petroleum (ANP; the bovine samples were the exception regarding moisture and acidity.

  17. Petroleum software profiles

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    A profile of twenty-two software packages designed for petroleum exploration and production was provided. Some focussed on the oil and gas engineering industry, and others on mapping systems containing well history files and well data summaries. Still other programs provided accounting systems designed to address the complexities of the oil and gas industry. The software packages reviewed were developed by some of the best-known groups involved in software development for the oil and gas industry, including among others, Geoquest, the Can Tek Group, Applied Terravision Systems Inc., Neotechnology Consultants Ltd., (12) OGCI Software Inc., Oracle Energy, Production Revenue Information Systems Management, Virtual Computing Services Ltd., and geoLogic Systems Ltd

  18. Petroleum and the economy

    International Nuclear Information System (INIS)

    Bohi, D.R.

    1992-01-01

    In re-examining the effect of energy price shocks on the economy, this article applies several tests to show that the apparent coincidence between price shocks and poor economic performance may be misleading. For example, whereas macroeconomic analysis graphs of employment and GNP clearly indicate an apparent correlation between the 1979 petroleum price hike and economic downturn in the USA, Great Britain and Germany, Japan's performance stayed fairly constant during that period. Additional sectoral analyses of the performances of the western economies show that the impacts of the '74 and '79 oil price shocks were not equally distributed across the different industrial sectors of the various nations. The paper argues that a deeper understanding of the energy-economy relationship is required to reduce these ambiguities

  19. 1992 petroleum software directory

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This book is designed especially for the petroleum industry. Each program listing includes a description of the function, language and memory requirements, operating systems, special accessories required, compatibles and pricing information. A separate section lists the more than 600 companies that produce and sell the programs. Companies are listed alphabetically and include address, phone, fax and telex numbers as well as contact names for each location. Many company listings also include distributors. This book includes information on Accounting/Statistics, Design/Construction/Engineering Graphics, Drilling Engineering and Equipment, Economics/Financial Analysis, Engineering, Exploration, Land and Leasing, Maintenance and Repair/Quality Control/Monitoring, Manufacturing, Maps, Marketing, Pipelines/Shipping/Storage, Production Engineering and Recovery Methods, Synthetic/Alternate Resources and Fuels

  20. Petroleum Business in Nigeria

    International Nuclear Information System (INIS)

    Dublin-Green, W. F.

    1997-01-01

    The petroleum industry is vital to the health of the Nigerian economy as it accounts for over 80% of Nigeria's total export earnings and about 70% of total government revenue. Nigeria has an oil reserve base of 21 billion barrels and gas reserve of 120 trillion cubic feet. With natural gas becoming the worlds fastest growing energy resource, the Nigerian Government has put in place a program to grow her oil reserve base to over 25 billion barrels and significantly increase her gas reserves. An earlier commitment made in 1990 to increase Nigeria's oil reserve base from a level of 16 to 20 billion barrels by 1995 was achieved well ahead of time. This success was largely due to financial incentives offered investors. This healthy business climate still prevails. This paper presents the investment opportunities that Nigeria offers genuine investors in both the upstream and downstream sectors of the industry and defines the legal/regulatory requirements for doing business in Nigeria. We try to give an insight into specific government policies that help to create an enabling environment for investors in the upstream and downstream sectors of the petroleum industry. We showcase the 5 (five) major sedimentary basins with enormous oil and gas potential where exploration/exploitation risks are rated medium to low. We focus on the environment and government's efforts to enforce the rules and guidelines that govern the policy termed the Environment, Safety and Standards. We recognize that the business challenges of the third millennium will dictate new alliances and partnerships that will survive and thrive only in a climate that is safe for the investor. This is the business climate we throw open in Nigeria for investors to come in and do business with us

  1. Bioremediation of petroleum hydrocarbons in soil environments. Report No. EE-141

    Energy Technology Data Exchange (ETDEWEB)

    Rowell, M J; Ashworth, J; Qureshi, A A

    1992-01-01

    The bioremediation of petroleum hydrocarbons in soil environments was reviewed by means of a literature survey and also through discussions with workers in relevent disciplines. This report discusses both the impacts of hydrocarbons on soil and a range of methods available to assist in the decomposition by soil microorganisms. The range of petroleum-based materials considered includes conventional and synthetic crude oils, refined oils, oily sludges, asphalts and bitumens, drilling mud residues, creosote tars and some pesticides.

  2. Proceedings of the Canadian International Petroleum Conference 2005 and the 56. Annual Technical Meeting of the Petroleum Society of CIM : Because Technology Changes Everything. CD ed.

    International Nuclear Information System (INIS)

    2005-01-01

    This conference and trade show outlined the latest technologies associated with hydrocarbon exploration, petroleum geology, resource development, and enhanced recovery. It was attended by local and international participants in the petroleum sector. The 31 sessions highlighted the challenges facing the petroleum industry in terms of maturing basins and focused on issues such as business development and risk management; cold production of heavy oil; health, safety and regulatory issues; and environmental concerns regarding oil and gas development. The presentations were targeted for managers, engineers, technologists, geologists, and other petroleum industry specialists dealing with topical issues such as: well completion; well stimulation; well test analysis; thermal recovery; reservoir characterization; fluid characterization; numerical simulation; computerized simulation; emerging technology; thermal field projects; production operations; business development; and refining facilities. A total of 122 papers have been catalogued separately for inclusion in this database. (author)

  3. Facts 2009 - The Norwegian petroleum sector

    Energy Technology Data Exchange (ETDEWEB)

    2009-07-01

    The publication provides a general overview of information regarding the petroleum activities on the Norwegian continental shelf. Contents: Foreword; The petroleum sector; Norwegian resource management; Government petroleum revenues; Exploration activities; Development and operations; Norwegian gas exports; Decommissioning; Research, technology; Environmental considerations; Petroleum resources; Fields in production; Fields under development; Future developments; Fields where production has ceased; Pipelines and onshore facilities. (AG)

  4. Petroleum coke as energy source: an update

    International Nuclear Information System (INIS)

    Pinelli, G.

    2008-01-01

    A previous review presented a critical evaluation of the use of petroleum coke as energy source. After some years, with reference to increased petroleum coke production, that paper is revised. In particular, the attention is now focused on world petroleum coke market trends and, in regard to petroleum coke used as fuel, on new Italian environment laws. [it

  5. 21 CFR 178.3710 - Petroleum wax.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Petroleum wax. 178.3710 Section 178.3710 Food and... and Production Aids § 178.3710 Petroleum wax. Petroleum wax may be safely used as a component of nonfood articles in contact with food, in accordance with the following conditions: (a) Petroleum wax is a...

  6. Ex-USSR: petroleum activities in 1991

    International Nuclear Information System (INIS)

    1992-01-01

    This paper gives statistical data on economy and petroleum industry in ex-USSR: Primary energy production and consumption (coal, petroleum, natural gas, primary power), petroleum and natural gas reserves, drilling activity, exports and imports of petroleum products, refining capacity. 2 figs., 14 tabs

  7. An estimation of cogeneration potential by using refinery residuals in Mexico

    International Nuclear Information System (INIS)

    Marin-Sanchez, J.E.; Rodriguez-Toral, M.A.

    2007-01-01

    Electric power generation in Mexico is mainly based on fossil fuels, specifically heavy fuel oil, although the use of natural gas combined cycles (NGCC) is becoming increasingly important. This is the main destination that has promoted growing imports of natural gas, currently accounting for about 20% of the total national annual consumption. Available crude oil is becoming heavier; thus refineries should be able to process it, and to handle greater quantities of refinery residuals. If all refinery residuals are used in cogeneration plants serving petroleum refineries, the high heat/power ratio of refinery needs, leads to the availability of appreciable quantities of electricity that can be exported to the public utility. Thus, in a global perspective, Mexican imports of natural gas may be reduced by cogeneration using refinery residuals. This is not the authors' idea; in fact, PEMEX, the national oil company, has been entitled by the Mexican congress to sell its power leftovers to The Federal Electricity Commission (CFE) in order to use cogeneration in the way described for the years to come. A systematic way of determining the cogeneration potential by using refinery residuals from Mexican refineries is presented here, taking into account residual quantities and composition, from a national perspective, considering expected scenarios for Maya crude content going to local refineries in the years to come. Among different available technologies for cogeneration using refinery residuals, it is believed that the integrated gasification combined cycle (IGCC) would be the best option. Thus, considering IGCC plants supplying heat and power to refineries where it is projected to have refinery residuals for cogeneration, the expected electric power that can be sent to the public utility is quantified, along with the natural gas imports mitigation that may be attained. This in turn would contribute to a necessary fuel diversification policy balancing energy, economy and

  8. Bioremediation of petroleum hydrocarbons in soil environments

    International Nuclear Information System (INIS)

    Rowell, M.J.; Ashworth, J.; Qureshi, A.A.

    1992-12-01

    The bioremediation of petroleum hydrocarbons in soil environments was reviewed via a literature survey and discussions with workers in relevant disciplines. The impacts of hydrocarbons on soil are discussed along with a range of methods available to assist in their decomposition by soil microorganisms. The range of petroleum-based materials considered includes conventional and synthetic crude oils, refined oils, sludges, asphalts and bitumens, drilling mud residues, creosote tars, and some pesticides. The degradability of hydrocarbons largely depends upon their aqueous solubility and their adsorption on soil surfaces and, therefore, is related to their molecular structures. The ease of decomposition decreases with increasing complexity of structure, in the order aliphatics > aromatics > heterocyclics and asphaltenes (most recalcitrant). Most soils contain an adequate population of microorganisms and hence bioaugmentation may only be needed in special circumstances. Decomposition is fastest in soils where the hydrocarbon loading rate, aeration, nutrition, moisture, and pH are all optimized. At spill sites there is little control over the application rate, although containment measures can assist in either limiting contamination or distributing it more evenly. The enhancement of bioremediation is discussed in light of all these factors. Other techniques such as enhanced aeration, hydrocarbon decomposition by anaerobic processes, surfactants, and burning are also discussed. 211 refs., 11 figs., 10 tabs

  9. Bioremediation of petroleum hydrocarbons in soil environments

    Energy Technology Data Exchange (ETDEWEB)

    Rowell, M J; Ashworth, J; Qureshi, A A

    1992-12-01

    The bioremediation of petroleum hydrocarbons in soil environments was reviewed via a literature survey and discussions with workers in relevant disciplines. The impacts of hydrocarbons on soil are discussed along with a range of methods available to assist in their decomposition by soil microorganisms. The range of petroleum-based materials considered includes conventional and synthetic crude oils, refined oils, sludges, asphalts and bitumens, drilling mud residues, creosote tars, and some pesticides. The degradability of hydrocarbons largely depends upon their aqueous solubility and their adsorption on soil surfaces and, therefore, is related to their molecular structures. The ease of decomposition decreases with increasing complexity of structure, in the order aliphatics > aromatics > heterocyclics and asphaltenes (most recalcitrant). Most soils contain an adequate population of microorganisms and hence bioaugmentation may only be needed in special circumstances. Decomposition is fastest in soils where the hydrocarbon loading rate, aeration, nutrition, moisture, and pH are all optimized. At spill sites there is little control over the application rate, although containment measures can assist in either limiting contamination or distributing it more evenly. The enhancement of bioremediation is discussed in light of all these factors. Other techniques such as enhanced aeration, hydrocarbon decomposition by anaerobic processes, surfactants, and burning are also discussed. 211 refs., 11 figs., 10 tabs.

  10. Process of converting heavy hydrocarbons, etc

    Energy Technology Data Exchange (ETDEWEB)

    Thiele, F C

    1921-05-27

    A modification is described of the process of the principal Patent 373,060 for splitting and converting heavy hydrocarbons into low-boiling lighter products or into cylinder oil, characterized in that, in place of petroleum, brown-coal oil, shale oil, or the like is distilled in the presence of hydrosilicate as a catalyzer or is heated with refluxing.

  11. Logistics aspects of petroleum pipeline operations

    Directory of Open Access Journals (Sweden)

    W. J. Pienaar

    2010-11-01

    Full Text Available The paper identifies, assesses and describes the logistics aspects of the commercial operation of petroleum pipelines. The nature of petroleum-product supply chains, in which pipelines play a role, is outlined and the types of petroleum pipeline systems are described. An outline is presented of the nature of the logistics activities of petroleum pipeline operations. The reasons for the cost efficiency of petroleum pipeline operations are given. The relative modal service effectiveness of petroleum pipeline transport, based on the most pertinent service performance measures, is offered. The segments in the petroleum-products supply chain where pipelines can play an efficient and effective role are identified.

  12. Panorama of the petroleum industry

    International Nuclear Information System (INIS)

    2005-02-01

    This document provides tables and charts of statistical data concerning the petroleum industry activity in 2004: supply and demand, prices, consumption, service station number and the market. (A.L.B.)

  13. Gasoline from Kumkol deposit petroleum

    International Nuclear Information System (INIS)

    Nadirov, A.N.; Zhizhin, N.I.; Musaeva, Z.G.

    1997-01-01

    Samples of gasoline from petroleum of Kumkol deposit are investigated by chromatographic analysis. It is found, that gasoline is characterizing by increased content of iso-paraffin hydrocarbons. (author)

  14. Dermal uptake of petroleum substances

    NARCIS (Netherlands)

    Jakasa, Ivone; Kezic, Sanja; Boogaard, Peter J.

    2015-01-01

    Petroleum products are complex substances comprising varying amounts of linear and branched alkanes, alkenes, cycloalkanes, and aromatics which may penetrate the skin at different rates. For proper interpretation of toxic hazard data, understanding their percutaneous absorption is of paramount

  15. Petroleum investment conditions in Peru

    International Nuclear Information System (INIS)

    Garcia Schreck, M.

    1996-01-01

    This report focuses on the current petroleum investment conditions in Peru, and Peru's hydrocarbon potential. Investment conditions are examined, and political risk, internal security, the economic environment, and the legal framework for investment are considered. (UK)

  16. Residual effects of prolonged heavy cannabis use

    NARCIS (Netherlands)

    van Amsterdam JGC; van der Laan JW; Slangen JL; LGM

    1996-01-01

    Recente literatuur werd geraadpleegd om na te gaan of langdurig gebruik van van grote hoeveelheden cannabis (dagelijks gebruik gedurende minimaal 6 maanden) leidt tot aanhoudende cognitieve effecten en effecten op het immuunsysteem. Het resultaat van deze studie is weergegeven in het huidige

  17. Petroleum and Water Logistics Operations

    Science.gov (United States)

    2005-06-19

    petroleum office ( SAPO ). The combatant commander JPO coordinates all agree- ments concerning bulk fuel support between com- ponent commands and HNs. For the...commander of the unified command through the JPO. The uni- fied command may also establish SAPOs at the subunified command level to provide in-country or...gency situations. PWRS are usually stored in theater and are monitored by the appropriate combatant commander JPO/ SAPO . MEF Petroleum War Reserve

  18. Colombian petroleum - A good business

    International Nuclear Information System (INIS)

    Carta Petrolera

    1998-01-01

    A great interest exists for Colombia, a country in which the statistics of petroleum and gas production, have been shot to volumes record; where 15 new contracts are signed every year, arriving in December from 1997 to an effective figure record of 107, a country that see grow their exports of raw; a country that every time has more facilities of transport and commercialization of hydrocarbons and it receives to more companies interested in sharing the risk in petroleum search

  19. Fe(CO)5-catalyzed coprocessing of coal and heavy oil vacuum residue using syngas-water as a hydrogen source; Fe(CO)5 shokubai ni yoru gosei gas-mizu wo suisogen to suru sekitan-jushitsuyu no coprocessing

    Energy Technology Data Exchange (ETDEWEB)

    Hata, K.; Wada, K.; Mitsudo, T. [Kyoto University, Kyoto (Japan)

    1996-10-28

    Improvement in efficiency and profitability of hydrogenation reaction of heavy hydrocarbon resources is the most important matter to be done. In this study, coprocessing of coal and heavy oil vacuum residue was conducted using syngas-water as a hydrogen source. For the investigation of effect of the reaction temperature during the coprocessing of Wandoan coal and Arabian heavy vacuum residue using Fe(CO)5 as a catalyst, the conversion, 66.0% was obtained at 425{degree}C. For the investigation of effect of reaction time, the yield of light fractions further increased during the two stage reaction at 400{degree}C for 60 minutes and at 425{degree}C for 60 minutes. Finally, almost 100% of THF-soluble matter was obtained through the reaction using 2 mmol of Fe(CO)5 catalyst at 400{degree}C for 60 minutes, and hydrogenation of heavy oil was proceeded simultaneously. When comparing coprocessing reactions using three kinds of hydrogen sources, i.e., hydrogen, CO-water, and syngas-water, the conversion yield and oil yield obtained by using syngas-water were similar to those obtained by using hydrogen, which demonstrated the effectiveness of syngas-water. 2 refs., 2 figs., 2 tabs.

  20. A study on ultra heavy oil gasification technology

    Energy Technology Data Exchange (ETDEWEB)

    Kidoguchi, Kazuhiro; Ashizawa, Masami; Taki, Masato; Ishimura, Masato; Takeno, Keiji

    2000-07-01

    Raising the thermal efficiency of a thermal power plant is an important issue from viewpoints of effective energy utilization and environmental protection. In view of raising the thermal efficiency, a gas turbine combined cycle power generation is considered to be very effective. The thermal efficiency of the latest LNG combined cycle power plant has been raised by more than 50%. On the other hand, the diversification of fuels to ensure supply stability is also an important issue, particularly in Japan where natural resources are scarce. Because of excellent handling characteristics petroleum and LNG which produces clean combustion are used in many sectors, and so the demand for such fuels is expected to grow. However, the availability of such fuels is limited, and supplies will be exhausted in the near future. The development of a highly efficient and environment-friendly gas turbine combined cycle using ultra heavy oil such as Orimulsion{trademark} (trademark of BITOR) is thus a significant step towards resolving these two issues. Chubu Electric Power Co, Inc., the Central Research Institute of Electric Power Industry (CRIEPI), and Mitsubishi Heavy Industries, Ltd. (MHI) conducted a collaboration from 1994 to 1998 with the objective of developing an ultra heavy oil integrated gasification combined cycle (IGCC). Construction of the ultra heavy oil gasification testing facility (fuel capacity:2.4t/d) was completed in 1995, and Orimulsion{trademark} gasification tests were carried out in 1995 and 1996. In 1997, the hot dedusting facility with ceramic filter and the water scrubber used as a preprocessor of a wet desulfurization process were installed. Gasification and clean up the syngs tests were carried out on Orimulsion{trademark}, Asmulsion{trademark} (trademark of Nisseki Mitsubishi K.K.), and residue oil in 1997 and 1998. The results of the collaboration effort are described below.

  1. Canadian retail petroleum markets study

    International Nuclear Information System (INIS)

    Ervin, M.J.

    1998-02-01

    A retail petroleum market study was conducted to provide a comprehensive overview of the competitiveness of the downstream petroleum industry in Canada and to set a foundation for effective policy development. The downstream petroleum industry, which includes the petroleum refining and marketing sectors, faces a poor public image, competitive pressures from U.S. and offshore refiners, and a broad range of environmental challenges. In this study, 19 markets representing a wide range of conditions were chosen for a detailed review of outlet economics. A market-by-market and regional comparisons of key competitiveness indicators was made in order to identify market and regional competitive differences as potential issues or opportunities within the industry. The study also included a pump price/margin model and provided a general overview of the retail gasoline sub-sector in terms of infrastructure. A review of prices, margins and demand patterns over the past several years was also undertaken to show the relationship between consumer demand patterns and pump price fluctuations. The study presented 22 findings which led to several conclusions and recommendations regarding the competitiveness of Canada's petroleum marketing sector. Two of the key conclusions were that taxation is a significant factor in the price of retail gasoline (about 50 per cent) and that government intervention into petroleum marketing is likely to be a poor alternative to market-based regulation. 18 tabs., 37 figs

  2. Quantification of compositional changes of petroleum hydrocarbons by GC/FID and GC/MS during a long-term bioremediation experiment

    DEFF Research Database (Denmark)

    Jensen, Trine S.; Arvin, Erik; Svensmark, Bo

    2000-01-01

    Samples from a long-term bioremediation experiment contaminated with two crude oils, Arabian Heavy and Gullfax, was used to analyze the compositional change of petroleum hydrocarbons. A time course of five different homologous series of petroleum hydrocarbons were analysed by GC/FID and GC...

  3. International petroleum statistics report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-07-01

    The International Petroleum Statistics Report is a monthly publication that provides current international data. The report presents data on international oil production, demand, imports, and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). This section contains annual data beginning in 1985, and monthly data for the most recent two years. Section 2 presents an oil supply/demand balance for the world. This balance is presented in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. This section contains annual data for the most recent year, quarterly data for the most recent two quarters, and monthly data for the most recent 12 months. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries. World oil production and OECD demand data are for the years 1970 through 1996; OECD stocks from 1973 through 1996; and OECD trade from 1986 through 1996.

  4. International petroleum statistics report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    The International Petroleum Statistics Report presents data on international oil production, demand, imports, exports, and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). This section contains annual data beginning in 1985, and monthly data for the most recent two years. Section 2 presents an oil supply/demand balance for the world. This balance is presented in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. This section contains annual data for the most recent year, quarterly data for the most recent two quarters, and monthly data for the most recent twelve months. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries. World oil production and OECD demand data are for the years 1970 through 1994; OECD stocks from 1973 through 1994; and OECD trade from 1984 through 1994.

  5. International petroleum statistics report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    The International Petroleum Statistics Report presents data on international oil production, demand, imports, and stocks. The report has four sections. Section 1 contains time series data on world oil production, and on oil demand and stocks in the Organization for Economic Cooperation and Development (OECD). This section contains annual data beginning in 1985, and monthly data for the most recent two years. Section 2 presents an oil supply/demand balance for the world. This balance is presented in quarterly intervals for the most recent two years. Section 3 presents data on oil imports by OECD countries. This section contains annual data for the most recent year, quarterly data for the most recent two quarters, and monthly data for the most recent twelve months. Section 4 presents annual time series data on world oil production and oil stocks, demand, and trade in OECD countries. Word oil production and OECD demand data are for the years 1970 through 1995; OECD stocks from 1973 through 1995; and OECD trade from 1985 through 1995.

  6. Iran's petroleum industry

    International Nuclear Information System (INIS)

    Ebneyousef, M.H.; Bogart, A.J.

    1992-01-01

    This paper reports that during the past several years Iran's potentials have been forgotten or ignored by the outside world mainly due to misconceptions, fears, and political concerns attributed to the religious overtone. The intention of the authors is to introduction to the new realities of regional, as well as global geopolitics and the main political and economic aspects of Iran's huge and growing petroleum industry. The fact of the matter is that in the rapidly changing world order the need for a true stability in the region and a global cooperation has been recognized by Iran. The country, with a population of 60 million, is now preparing itself for the major political and economic role thrust upon the nation by the socio-economic changes in the integrating Europe; the outcome of the Iran-Iraq and the Persian Gulf wars, including the likely instability of the autocratic governments of Arab states of the region; the breakup of the former Soviet Union; and market changes in the Far East

  7. A comparison of major petroleum life cycle models | Science ...

    Science.gov (United States)

    Many organizations have attempted to develop an accurate well-to-pump life cycle model of petroleum products in order to inform decision makers of the consequences of its use. Our paper studies five of these models, demonstrating the differences in their predictions and attempting to evaluate their data quality. Carbon dioxide well-to-pump emissions for gasoline showed a variation of 35 %, and other pollutants such as ammonia and particulate matter varied up to 100 %. Differences in allocation do not appear to explain differences in predictions. Effects of these deviations on well-to-wheels passenger vehicle and truck transportation life cycle models may be minimal for effects such as global warming potential (6 % spread), but for respiratory effects of criteria pollutants (41 % spread) and other impact categories, they can be significant. A data quality assessment of the models’ documentation revealed real differences between models in temporal and geographic representativeness, completeness, as well as transparency. Stakeholders may need to consider carefully the tradeoffs inherent when selecting a model to conduct life cycle assessments for systems that make heavy use of petroleum products. This is a qualitative and quantitative comparison of petroleum LCA models intended for an expert audience interested in better understanding the data quality of existing petroleum life cycle models and the quantitative differences between these models.

  8. The petroleum challenge. Present day questions about oil and gas

    International Nuclear Information System (INIS)

    Boussena, S.; Locatelli, C.; Pauwels, J.P.; Swartenbroekx, C.

    2006-04-01

    Will the 21. century be the petroleum challenge century? The petroleum problem is no longer the affair of experts and journalists, it challenges also governments and consumers in pressing terms. If there is today a petroleum problem, there is no oil or gas shortage for the moment. The cumulated oil and gas reserves would allow to face the demand of the century, with the condition that investments in exploration, field development, production, and back-end of oil and gas industries will be done in time. This book, written by specialists of energy economics and geopolitics shows up some of the key questions of our energy future. In particular, it invites us to never forget the basic heavy trends of the hydrocarbons sector in order to never be trapped by superficial extrapolations of short term phenomena. Content: heavy trend of oil prices at the 2020 prospects, natural gas take over?; oil and gas geopolitics: enough of hydrocarbons for the 21. century; Russia and Caspian sea oil and gas weight; China: a new strategic actor of the energy scene; influence of 'futures' market, of speculation, and of stocks on hydrocarbon prices; which future for LNG?; natural gas in the USA: towards a new foreign dependence. (J.S.)

  9. Residual stresses

    International Nuclear Information System (INIS)

    Sahotra, I.M.

    2006-01-01

    The principal effect of unloading a material strained into the plastic range is to create a permanent set (plastic deformation), which if restricted somehow, gives rise to a system of self-balancing within the same member or reaction balanced by other members of the structure., known as residual stresses. These stresses stay there as locked-in stresses, in the body or a part of it in the absence of any external loading. Residual stresses are induced during hot-rolling and welding differential cooling, cold-forming and extruding: cold straightening and spot heating, fabrication and forced fitting of components constraining the structure to a particular geometry. The areas which cool more quickly develop residual compressive stresses, while the slower cooling areas develop residual tensile stresses, and a self-balancing or reaction balanced system of residual stresses is formed. The phenomenon of residual stresses is the most challenging in its application in surface modification techniques determining endurance mechanism against fracture and fatigue failures. This paper discusses the mechanism of residual stresses, that how the residual stresses are fanned and what their behavior is under the action of external forces. Such as in the case of a circular bar under limit torque, rectangular beam under limt moment, reclaiming of shafts welds and peening etc. (author)

  10. Alberta Petroleum Marketing Commission annual report, 1991

    International Nuclear Information System (INIS)

    1992-04-01

    The Alberta Petroleum Marketing Commission has the responsibility of selling the Crown's royalty share of Alberta's crude and synthetic oil production; similar services are provided for natural gas. The Commission also markets crude oil on behalf of producers to North American and offshore consumers. The Commission's position as the largest crude oil marketeer in Canada enables it to provide analyses of industry pricing and marketing trends to the Alberta government. In 1991, the middle east crisis caused prices to spike at the commencement of the Gulf war, but these quickly stabilized. The Commission's receipts of light and medium royalty oil totalled 45.3 million bbl, down 1.5% from 1990, and receipts of heavy crude were 6.1 million bbl, up 5% from 1990. Revenue from crude oil sales was $1,642,244,000, down from $2,078,197,000 in 1990. Loss of the Montreal market through pipeline closure led to increased pressure on prices, particularly on heavy crudes. The Commission's natural gas activities in 1991 included price determination and information collection. 9 figs., 1 tab

  11. Petroleum product deparaffination process

    Energy Technology Data Exchange (ETDEWEB)

    Martynenko, A.G.; Dorodnova, V.S.; Korzhov, Yu.A.

    1980-12-23

    In the process for deparaffination of petroleum products (NP) by treatment of them with carbamide (KA) in the presence of an activator (AK) and solvent with subsequent separation of the forming paraffin-carbamide complex (PKC) the NP is mixed with the AK at a temperature of 5-40/sup 0/ in an NP:AK ratio of 1:0.01-0.03 with subsequent addition of portions of KA at a temperature of 5-20/sup 0/. The advantages of the process in comparison with the known one consists in the fact that the process of complex formation is realized practically without an induction period, and paraffin yield is increased by 27% on the potential with a simultaneous decrease in reagent consumption: KA by 20% and MeOH by 35%. Example -- 100 g of diesel fuel (a 200-360/sup 0/ fraction) is mixed with MeOH (1.3% on the feedstock), which in the obtained mixture is found in a liquid droplet state. To the mixture 40 g KA is added (2/3 of the total amount of KA to be added). The complex formation temperature is held at 35/sup 0/. To the PKC practically forming at once 260 g of solvent (an 85-120/sup 0/ gasoline fraction) and then 20 g KA are added. The temperature is held at 20/sup 0/. The forming suspension of the complex is distinguished by uniformity and the absence of coarse conglomerates. The paraffin yield amounts to 11.8% on the feedstock or 74% on the potential. The melting point of the paraffin is 22/sup 0/. In the described deparaffination scheme according to the proposed process complex formation is carried out in two steps; in a third step the suspension of KA and centrifuged paraffin is separated; the KA is returned to the complex formation reactor, and the centrifuged paraffin --- for solvent regeneration.

  12. Petroleum resources assessment (I)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    On the basis of diverse microfossils such as foraminifers, ostracods, micromulluscs, fossil spores and pollen and calcareous nannofossils derived from 14 drill holes, the sediments are divided into two part, the upper marine part and the lower nonmarine one. Marine part is subdivided into 4 foraminiferal zones and 3 nannofossil zones of Plio-Pleistocene age. In the lower part ranging from Oligocene to Late Miocene 4 palynomoph assemblages are established, which reflect climatic changes fluctuating between subtropical and cool temperate. Some fine sediments occurring in the South Sea continental shelf are rich in organic matter to be hydrocarbon source rock. The organic matter is mainly compared to type 3. However, lower part of the Geobuk-1 and Okdom-1 shows more oil prone geochemical characteristics than other wells. The kerosene is mixture type 1 and type 3 organic matter. The main oil generation zone located between 2,500 m and 3,000 m and gas generation zone from 3,500 m to 4,000 m approximately. Hydrocarbon accumulation could be expected in the trap formed in the period earlier than 10 Ma. as the hydrocarbon started to be expelled at 10 Ma. according to the modeling. Approximately 13,000 Line-km of multichannel seismic data integrated with 14 wells and gravity and magnetic data were analyzed to investigate the structural and stratigraphic evolution of southern part of offshore Korea. The northeast-southwest trending Taiwan-Sinzi Uplift Belt separates the area into two regions with different tectonic features, northwestern and southwestern regions. The potential hydrocarbon traps associated with anticline, tilted fault block, fault, unconformity, and rollover structure exist. This project is consisted of two main subjects. 1) Petroleum resources assessment on the continental shelf basin of the south sea. 2) Petroliferous basin analysis in Taegu area (1). (author). refs., tabs., figs.

  13. Petroleum resources assessment (I)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    This report consists of 2 subjects. 1) Petroleum resources assessment of the Kunsan Basin : Kunsan Basin is mainly filled with Cretaceous and Tertiary clastic sediments, and divided into Southwest Sub-basin, Central Sub-basin and Northeast Sub-basin by uplifts and faults developed in the basin. Microfossils were studied for the biostratigraphic works of drill wells in the Kunsan Basin. The microfossils include organic-walled microfossils such as spores, pollen and nonmarine dinoflagellates and calcareous microfossils such as ostracods, charophytes and gastropods. The fossil assemblages of the Kunsan Basin reveal nonmarine environments ranging from alluvial fan to shallow lacustrine and climatic variation between subtropical and cool temperate temperature in the arid/humid alternating conditions. According to the paleontological data, the Kunsan Basin was initiated in the Early Cretaceous and expanded during Paleogene followed by regional erosion at the closing time of Paleogene on which Neogene sediments have been accumulated. The Paleogene strata show laterally irregular thickness in each Epoch due to migrating depocenter. 2) Petroliferous basin analysis in Hapcheon area (I) : The Cretaceous Gyeongsang Supergroup consists of more than 9 Km sequences of sedimentary and volcanic rocks in Hapcheon-Changyong-Euiryong-Haman area and occupies the middle part of the Milyang subbasin. The Supergroup can be divided into three group; Sindong, Hayang and Yuchon groups in ascending order. Based on rock color, the Sindong Group can be subdivided into Nakdong, Hasandong and Jinju Formations. The Hayang Group can be subdivided into Chilgok, Silla Conglomerate, Haman and Jindong Formations. The Chilgok Formation includes basaltic lava and tuffs in the upper part. The Haman Formation has Kusandong tuff (keybed) in the uppermost part in the Changyong area, whereas the tuff is intercalated below the vocaniclastics in the Haman area. (author). 60 refs., 22 tabs., 61 figs.

  14. Residual stresses

    International Nuclear Information System (INIS)

    Macherauch, E.

    1978-01-01

    Residual stresses are stresses which exist in a material without the influence of external powers and moments. They come into existence when the volume of a material constantly changes its form as a consequence of mechanical, thermal, and/or chemical processes and is hindered by neighbouring volumes. Bodies with residual stress are in mechanical balance. These residual stresses can be manifested by means of all mechanical interventions disturbing this balance. Acoustical, optical, radiological, and magnetical methods involving material changes caused by residual stress can also serve for determining residual stress. Residual stresses have an ambivalent character. In technical practice, they are feared and liked at the same time. They cause trouble because they can be the cause for unexpected behaviour of construction elements. They are feared since they can cause failure, in the worst case with catastrophical consequences. They are appreciated, on the other hand, because, in many cases, they can contribute to improvements of the material behaviour under certain circumstances. But they are especially liked for their giving convenient and (this is most important) mostly uncontrollable explanations. For only in very few cases we have enough knowledge and possibilities for the objective evaluation of residual stresses. (orig.) [de

  15. Electroremediation of air pollution control residues in a continuous reactor

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland; Ferreira, Célia M. D.; Hansen, Henrik K.

    2010-01-01

    Air pollution control (APC) residue from municipal solid waste incineration is considered hazardous waste due to its alkalinity and high content of salts and mobile heavy metals. Various solutions for the handling of APC-residue exist, however most commercial solutions involve landfilling. A demand...... were made with raw residue, water-washed residue, acid washed residue and acid-treated residue with emphasis on reduction of heavy metal mobility. Main results indicate that the reactor successfully removes toxic elements lead, copper, cadmium and zinc from the feed stream, suggesting...

  16. The hidden face of the petroleum

    International Nuclear Information System (INIS)

    Laurent, E.

    2006-02-01

    For the first time, a book reveals what that was hidden to the public opinions: why the petroleum crisis of 1973 what only a manipulation, an arrangement between the OPEC and the petroleum companies, why the data concerning the petroleum reserves are wrong and increased by the producers countries, how Washington used the Saudi petroleum weapon to create the Soviet Union fall, and why from march 2001 maps of the Iraq (where were drawn the future petroleum explorations) were working documents for the vice President Cheney and petroleum managers for the ''secret society''. (A.L.B.)

  17. Heavy Chain Diseases

    Science.gov (United States)

    ... of heavy chain produced: Alpha Gamma Mu Alpha Heavy Chain Disease Alpha heavy chain disease (IgA heavy ... the disease or lead to a remission. Gamma Heavy Chain Disease Gamma heavy chain disease (IgG heavy ...

  18. Ireland unveils petroleum tax measures

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper reports that Ireland's government has introduced detailed petroleum tax legislation designed to boost offshore exploration and development. The petroleum tax measures, published last week and included in the government's omnibus finance bill for 1992, will provide Ireland for the first time a comprehensive petroleum tax regime. They include elements which, in tax terms, will make Ireland a most attractive location for oil and gas exploration and development, the Irish Energy Minister Robert Molloy. He the, Exploration companies will now have the benefit of the certainty of a detailed tax framework and attractive tax rates. Debate on the finance bill has begun in the Irish Dail (parliament). Under Ireland's constitution, the budget bill must be approved and signed by the president by the end of May. Failure to approve a budget bill within that time would mean the current government's collapse

  19. Petroleum 1996 - issues and trends

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    Increasingly, users of the Energy Information Administration`s petroleum data and analytical reports have expressed an interest in a recurring report that takes a broad view of the petroleum sector. What is sought is some perspective on the complex interrelationships that comprise an industry and markets accounting for 40 percent of the energy consumed in the United States and ranging from the drilling rig in the oil field to the pump at the local gasoline station. This report comprehensively examines historical trends, and selectively focuses on major issues and the events they represent. It analyzes different dimensions of the industry and related markets in terms of how they relate to a common theme, in this case, the volatility in petroleum markets.

  20. Biological Remediation of Petroleum Contaminants

    Science.gov (United States)

    Kuhad, Ramesh Chander; Gupta, Rishi

    Large volumes of hazardous wastes are generated in the form of oily sludges and contaminated soils during crude oil transportation and processing. Although many physical, chemical and biological treatment technologies are available for petroleum contaminants petroleum contaminants in soil, biological methods have been considered the most cost-effective. Practical biological remediation methods typically involve direct use of the microbes naturally occurring in the contaminated environment and/or cultured indigenous or modified microorganisms. Environmental and nutritional factors, including the properties of the soil, the chemical structure of the hydrocarbon(s), oxygen, water, nutrient availability, pH, temperature, and contaminant bioavailability, can significantly affect the rate and the extent of hydrocarbon biodegradation hydrocarbon biodegradation by microorganisms in contaminated soils. This chapter concisely discusses the major aspects of bioremediation of petroleum contaminants.

  1. International petroleum agreements : Republic of Cuba

    International Nuclear Information System (INIS)

    Skinner, M.A.

    2002-01-01

    Foreign investment in the oil and gas sector has had a profound impact on the development of crude oil production in Cuba. In 1982, in order to encourage economic development, the Cuban government adopted a form of Production Sharing Contract (PSC) for international petroleum agreements. In 1990, the first PSC was negotiated with a consortium of European companies. This was followed in 1992 through 1994 with companies from Canada, Europe and Latin America. Then in 1995, a more comprehensive foreign investment law was enacted to further encourage foreign investment in Cuba. Onshore and shallow water regions of Cuba were divided into 45 blocks, 19 of which were under licence in 2001. In addition, in 1999 the government of Cuba offered 53 blocks in the deep water zones of the Cuban sector of the Gulf of Mexico to foreign investment, of which 6 are already under licence. Most exploration for oil and gas since 1991 has been carried out by foreign companies. Crude oil production in 1991 totalled 11,000 bopd of heavy oil production from the north coast of Cuba. By 2001, domestic crude oil production increased to more than 50,000 bopd, mostly due to foreign investment in exploration and development. This paper described the model form for Cuban Production Sharing Contracts with reference to parties, rights granted, terms, relinquishments, minimum exploration commitments, discovery of hydrocarbons and recovery of petroleum operation expenses. The paper also discussed gross production, cost recovery for contractors, and sharing of profits with contractors and the state oil company, CubaPetroleo. 1 fig

  2. Recent Advances in Petroleum Microbiology

    Science.gov (United States)

    Van Hamme, Jonathan D.; Singh, Ajay; Ward, Owen P.

    2003-01-01

    Recent advances in molecular biology have extended our understanding of the metabolic processes related to microbial transformation of petroleum hydrocarbons. The physiological responses of microorganisms to the presence of hydrocarbons, including cell surface alterations and adaptive mechanisms for uptake and efflux of these substrates, have been characterized. New molecular techniques have enhanced our ability to investigate the dynamics of microbial communities in petroleum-impacted ecosystems. By establishing conditions which maximize rates and extents of microbial growth, hydrocarbon access, and transformation, highly accelerated and bioreactor-based petroleum waste degradation processes have been implemented. Biofilters capable of removing and biodegrading volatile petroleum contaminants in air streams with short substrate-microbe contact times (desulfurization processes with biodesulfurization methods through promotion of selective sulfur removal without degradation of associated carbon moieties. However, since microbes require an environment containing some water, a two-phase oil-water system must be established to optimize contact between the microbes and the hydrocarbon, and such an emulsion is not easily created with viscous crude oil. This challenge may be circumvented by application of the technology to more refined gasoline and diesel substrates, where aqueous-hydrocarbon emulsions are more easily generated. Molecular approaches are being used to broaden the substrate specificity and increase the rates and extents of desulfurization. Bacterial processes are being commercialized for removal of H2S and sulfoxides from petrochemical waste streams. Microbes also have potential for use in removal of nitrogen from crude oil leading to reduced nitric oxide emissions provided that technical problems similar to those experienced in biodesulfurization can be solved. Enzymes are being exploited to produce added-value products from petroleum substrates, and

  3. Petroleum industry opportunities in Guatemala

    International Nuclear Information System (INIS)

    1991-01-01

    The investment opportunities that Guatemala has to offer in the petroleum sector are discussed, highlighting aspects of legislation as well as investment recovery. The increase in seismic and geological information that Guatemala has recently accumulated allows for an increased level of success in petroleum exploration, which coupled with an increase in basic infrastructure and the experience acquired in the administration of the hydrocarbons law, make it more attractive for foreign investment. An overview is presented of the sedimentary basins present, exploratory activity, surface reconnaissance permits, production sharing contracts, prices, taxation, royalties, and options. 7 figs

  4. The petroleum dilemma of Russia

    International Nuclear Information System (INIS)

    Roubinski, Y.

    2004-01-01

    Russia is confronted with major choices in the research of an optimum petroleum strategy. Now the first world exporter, Russia takes advantage of the Usa policy, first importer, which aim to diversify their supply sources since the 11 september 2001, to decrease their dependence from the Saudi Arabia and more generally from the instable Middle East. In another hand, Moscow wants to minimize the dependence of the petroleum benefit and the oils prices fluctuations, by a diversification of its economy structure. These choices define a part of the russian policy in the context of the presidential elections of march 2004. (A.L.B.)

  5. Saudi Arabia: petroleum industry review

    International Nuclear Information System (INIS)

    Shammas, Pierre

    2000-01-01

    A comprehensive review is provided of Saudi Arabia's petroleum industry covering oil and gas exploration and production, refining, oil and gas trade, marketing and Saudi overseas investments. Profiles of key Saudi decision makers are provided. A statistical appendix includes data from the start of oil production in Saudi Arabia in 1938. Part I Geological potential; Part II The Saudi energy economy; Part III Production capacity; Part IV The oil refining sector ; Part V Exports and logistics; Part VI Overseas petroleum industry investments; Part VII The decision makers; Part VIII Statistical Appendix; Reserves, Production, Exports, Prices 1950 to 1999. (Author)

  6. Industrial rag cleaning process for the environmentally safe removal of petroleum-based solvents

    International Nuclear Information System (INIS)

    Fierro, J.V.

    1993-01-01

    A process for the cleaning of industrial rags contaminated with environmentally unsafe petroleum-based solvent is described, comprising the step of: (a) placing a load of the industrial rags in a mechanically driven rotary drum; (b) revolving the drum at a high speed sufficient to physically extract liquid petroleum-based solvent contaminate from the industrial rags; (c) routing the extracted petroleum-based solvent contaminate from the rotary drum to a waste solvent collection line for environmentally safe disposal; (d) revolving the rotary drum to cause a tumbling of the industrial rags while maintaining the temperature within the drum at below the flash point of the petroleum-based solvent; (e) intermittently forcing cold air and hot air through the rotary drum to vaporize solvent from the industrial rags; (f) routing the vaporized petroleum-based solvent contaminant from the rotary drum to a condenser wherein the petroleum-based solvent contaminate is condensed and thereafter further routing said condensed solvent to a waste collection line for environmentally safe disposal; and (g) cleaning the industrial rags in the presence of a dry cleaning solvent to remove residual petroleum-based solvents and soil

  7. Towards the end of full-petroleum

    International Nuclear Information System (INIS)

    2001-01-01

    The experts agree on the petroleum reserves exhausting. Even if some disagreements subsist on the term, the years 2020 seem to be decisive. This paper takes stock on the governments policy facing the petroleum reserves decrease. (A.L.B.)

  8. Stable isotope mass spectrometry in petroleum exploration

    International Nuclear Information System (INIS)

    Mathur, Manju

    1997-01-01

    The stable isotope mass spectrometry plays an important role to evaluate the stable isotopic composition of hydrocarbons. The isotopic ratios of certain elements in petroleum samples reflect certain characteristics which are useful for petroleum exploration

  9. BIOREMEDIATION OF A PETROLEUM-HYDROCARBON

    African Journals Online (AJOL)

    ES OBE

    under field conditions in the bioremediation of a petroleum- hydrocarbon polluted ... an accelerated biodegradation of petroleum hydrocarbons in a polluted agricultural soil ..... 12) Jackson, M.L. Soil chemical analysis. ... biological assay. 3 rd.

  10. Total Petroleum Hydrocarbons (TPH): ToxFAQs

    Science.gov (United States)

    ... a state: This map displays locations where Total Petroleum Hydrocarbons (TPH) is known to be present. On ... I get more information? ToxFAQs TM for Total Petroleum Hydrocarbons (TPH) ( Hidrocarburos Totales de Petróleo (TPH) ) August ...

  11. Canadian Petroleum Products Inst. annual report, 1991

    International Nuclear Information System (INIS)

    1992-01-01

    The Canadian Petroleum Products Institute (CPPI) was created in 1989 as a nonprofit association of Canadian refiners and marketers of petroleum products. In 1991, the Atlantic Petroleum Association, the Quebec Petroleum Association, the Ontario Petroleum Association, the Canada West Petroleum Association, and the Petroleum Association for Conservation of the Canadian Environment (PACE) were integrated into the CPPI. The objective of the CPPI is to serve and represent the refining and marketing sectors of the petroleum industry with respect to environment, health and safety, and business issues. An industry overview is provided, as well as highlights of environmental achievements and challenges, and economics and operations for the year. Lists of CPPI publications, standing committees, and officers are also included. 9 figs

  12. Toxicity of oils and petroleum hydrocarbons to estuarine crustaceans

    Energy Technology Data Exchange (ETDEWEB)

    Tatem, H.E. (Army Engineer Waterways Experiment Station, Vicksburg, MS); Cox, B.A.; Anderson, J.W.

    1978-04-01

    Bioassay experiments with various life stages of three estuarine shrimp and soluble petroleum hydrocarbons (PH) revealed residual Bunker C oil and refined No. 2 fuel oil to be more toxic than two crude oils tested. Larvae of Palaemonetes pugio were slightly more sensitive to the PH than adults, while young penaeid shrimp were shown to be more resistant than older, larger individuals. Shrimp exposed to PH in conjunction with temperature and salinity changes were more susceptible to the PH. Some common aromatic and diaromatic PH, including three naphthalene compounds, were utilized in bioassays. Naphthalenes were highly toxic. The toxicity of petroleum products is closely related to aromatic hydrocarbon content, especially the naphthalenes and related hydrocarbons.

  13. Characterisation and management of concrete grinding residuals.

    Science.gov (United States)

    Kluge, Matt; Gupta, Nautasha; Watts, Ben; Chadik, Paul A; Ferraro, Christopher; Townsend, Timothy G

    2018-02-01

    Concrete grinding residue is the waste product resulting from the grinding, cutting, and resurfacing of concrete pavement. Potential beneficial applications for concrete grinding residue include use as a soil amendment and as a construction material, including as an additive to Portland cement concrete. Concrete grinding residue exhibits a high pH, and though not hazardous, it is sufficiently elevated that precautions need to be taken around aquatic ecosystems. Best management practices and state regulations focus on reducing the impact on such aquatic environment. Heavy metals are present in concrete grinding residue, but concentrations are of the same magnitude as typically recycled concrete residuals. The chemical composition of concrete grinding residue makes it a useful product for some soil amendment purposes at appropriate land application rates. The presence of unreacted concrete in concrete grinding residue was examined for potential use as partial replacement of cement in new concrete. Testing of Florida concrete grinding residue revealed no dramatic reactivity or improvement in mortar strength.

  14. The role of the national petroleum company in petroleum development market

    Energy Technology Data Exchange (ETDEWEB)

    Lee, B J [Korea Energy Economics Institute, Euiwang (Korea, Republic of)

    1997-08-01

    The present century started with the creation of national petroleum companies, and it ends with those national petroleum companies exerting various types of efforts to increase the efficiency of their management. Especially, the efforts of these national petroleum companies are ever intensifying to adapt to new trends in the world petroleum market such as intensified competition, ever-deepening price unstableness, separation of structure between upstream and downstream portions, rapid development of petroleum development technologies, change of political systems and the demise of national borders, ever-increasing consciousness of environmental preservation, etc. Korea cannot be exempt from management rationalization efforts of national petroleum companies. Especially, Korea established its own national petroleum company in order to actively deal with these as its supply system is very weak. Therefore, the national petroleum company should create as many successful petroleum development businesses by actively carrying out petroleum development businesses domestically and overseas in order to establish a stable supply system of petroleum and to support the petroleum development businesses of civilian enterprises more effectively. The national petroleum company must, first of all, replace the bureaucracy with entrepreneurship. Esp., in order to enhance the efficiency of management, short- term outcome should not be emphasized over long-term tenure of petroleum development businesses, and excessive interference of government on the national petroleum company should be excluded. The entrepreneurship of the national petroleum company should be pursued in Positive-sum way, and its public image should be actively promoted through this. 35 refs., 11 figs., 32 tabs.

  15. 77 FR 56421 - Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum...

    Science.gov (United States)

    2012-09-12

    ... Parts 9 and 60 Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum...-9672-3] RIN 2060-AN72 Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or Modification Commenced After May 14, 2007...

  16. 46 CFR 148.04-15 - Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture). 148.04-15 Section 148.04-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND... Requirements for Certain Material § 148.04-15 Petroleum coke, uncalcined; petroleum coke, uncalcined and...

  17. The United States facing their petroleum dependence

    International Nuclear Information System (INIS)

    Noel, P.

    2002-06-01

    In the framework of ''the energy crisis of 2000-2001'', the Cheney report and the petroleum dependence, this study presents a critical examination of the United States petroleum situation, its perception in the american political milieu and the public policies implementing during the last ten years. The first section is devoted to the petroleum supply. In the second section, the american petroleum policy and the energy safety are studied. (A.L.B.)

  18. Fact sheet. Norwegian petroleum activity 1996

    Energy Technology Data Exchange (ETDEWEB)

    Westgaard, T. [ed.

    1996-02-01

    The present report from the Royal Ministry of Industry and Energy deals with the Norwegian petroleum activity. Main topics are as follow: Historical overview; state organisation of petroleum activities; the economic impact of Norwegian oil and gas; state revenues; mainland activities; petroleum resources; production; marketing situation for petroleum products; environmental aspects; the legal and licence framework; licensing rounds; exploration; fields in production; fields under development; discoveries with development plan under consideration; transportation systems; licence interests; company interests. 36 refs., 24 figs., 15 tabs.

  19. Heavy baryons

    International Nuclear Information System (INIS)

    Koerner, J.G.

    1994-06-01

    We review the experimental and theoretical status of baryons containing one heavy quark. The charm and bottom baryon states are classified and their mass spectra are listed. The appropriate theoretical framework for the description of heavy baryons is the Heavy Quark Effective Theory, whose general ideas and methods are introduced and illustrated in specific examples. We present simple covariant expressions for the spin wave functions of heavy baryons including p-wave baryons. The covariant spin wave functions are used to determine the Heavy Quark Symmetry structure of flavour-changing current-induced transitions between heavy baryons as well as one-pion and one-photon transitions between heavy baryons of the same flavour. We discuss 1/m Q corrections to the current-induced transitions as well as the structure of heavy to light baryon transitions. Whenever possible we attempt to present numbers to compare with experiment by making use of further model-dependent assumptions as e.g. the constituent picture for light quarks. We highlight recent advances in the theoretical understanding of the inclusive decays of hadrons containing one heavy quark including polarization. For exclusive semileptonic decays we discuss rates, angular decay distributions and polarization effects. We provide an update of the experimental and theoretical status of lifetimes of heavy baryons and of exclusive nonleptonic two body decays of charm baryons. (orig.)

  20. Speciation of Mercury in Selected Areas of the Petroleum Value Chain.

    Science.gov (United States)

    Avellan, Astrid; Stegemeier, John P; Gai, Ke; Dale, James; Hsu-Kim, Heileen; Levard, Clément; O'Rear, Dennis; Hoelen, Thomas P; Lowry, Gregory V

    2018-02-06

    Petroleum, natural gas, and natural gas condensate can contain low levels of mercury (Hg). The speciation of Hg can affect its behavior during processing, transport, and storage so efficient and safe management of Hg requires an understanding of its chemical form in oil, gas and byproducts. Here, X-ray absorption spectroscopy was used to determine the Hg speciation in samples of solid residues collected throughout the petroleum value chain including stabilized crude oil residues, sediments from separation tanks and condensate glycol dehydrators, distillation column pipe scale, and biosludge from wastewater treatment. In all samples except glycol dehydrators, metacinnabar (β-HgS) was the primary form of Hg. Electron microscopy on particles from a crude sediment showed nanosized (crude oil being processed, i.e. sweet (low sulfur crudes) vs sour (higher sulfur crudes). This information on Hg speciation in the petroleum value chain will inform development of better engineering controls and management practices for Hg.

  1. 1998 annual report of Petroleum Technology Alliance Canada

    International Nuclear Information System (INIS)

    1999-01-01

    Key accomplishments of the Petroleum Technology Alliance of Canada (PTAC) during 1998 are summarized. PTAC is an association that facilitates collaborative research and technology development in the conventional oil and gas industry. Accomplishments in 1998 included the launch of 21 new research and development projects, increased memberships, and 16 successful workshops which focused on PTAC research and development initiatives in environmental impacts, conventional heavy oil, well completions, inactive well management and well abandonment. A financial statement attesting to the PTAC's financial health is included with this annual report. 2 tabs

  2. On the Tengiz petroleum deposit previous study

    International Nuclear Information System (INIS)

    Nysangaliev, A.N.; Kuspangaliev, T.K.

    1997-01-01

    Tengiz petroleum deposit previous study is described. Some consideration about structure of productive formation, specific characteristic properties of petroleum-bearing collectors are presented. Recommendation on their detail study and using of experience on exploration and development of petroleum deposit which have analogy on most important geological and industrial parameters are given. (author)

  3. The petroleum industry in 1999 (editorial)

    International Nuclear Information System (INIS)

    2001-01-01

    This document deals with the petroleum activity in 1999. It provides three economic analysis. The first one concerns the petroleum industry activity in 1999 and the corresponding french energy policy. The second one presents the petroleum activity in the world. The third one presents the hydrocarbons market supplying in France. (A.L.B.)

  4. 78 FR 40131 - National Petroleum Council

    Science.gov (United States)

    2013-07-03

    ... DEPARTMENT OF ENERGY National Petroleum Council AGENCY: Office of Fossil Energy, Department of... Petroleum Council. The Federal Advisory Committee Act (Pub. L. 92-463, 86 Stat. 770) requires that public... Administrative Matters Discussion of Any Other Business Properly Brought Before the National Petroleum Council...

  5. Unit: Petroleum, Inspection Pack, National Trial Print.

    Science.gov (United States)

    Australian Science Education Project, Toorak, Victoria.

    This is a National Trial Print of a unit on petroleum developed for the Australian Science Education Project. The package contains the teacher's edition of the written material and a script for a film entitled "The Extraordinary Experience of Nicholas Nodwell" emphasizing the uses of petroleum and petroleum products in daily life and…

  6. 77 FR 42297 - National Petroleum Council

    Science.gov (United States)

    2012-07-18

    ... DEPARTMENT OF ENERGY National Petroleum Council AGENCY: Department of Energy, Office of Fossil... National Petroleum Council. The Federal Advisory Committee Act (Pub. L. 92-463, 86 Stat. 770) requires that... Matters Discussion of Any Other Business Properly Brought Before the National Petroleum Council...

  7. 76 FR 53889 - National Petroleum Council

    Science.gov (United States)

    2011-08-30

    ... DEPARTMENT OF ENERGY National Petroleum Council AGENCY: Department of Energy, Office of Fossil... Petroleum Council. The Federal Advisory Committee Act (Pub. L. 92-463, 86 Stat. 770) requires that public... Properly Brought Before the National, Petroleum Council, Adjournment. Public Participation: The meeting is...

  8. Investigation and development of heavy oil upgrading catalysts. 3

    Energy Technology Data Exchange (ETDEWEB)

    Lee, D.K.; Lee, I.C.; Yoon, W.L.; Lee, H.T.; Chung, H.; Hwang, Y.J.; Park, S.H. [Korea Inst. of Energy Research, Taejon (Korea, Republic of)

    1995-12-01

    This study aimed at the domestic development of HDS catalysts which are most fundamental and wide-used in the petroleum refinery. In this year, some experimental works were conducted for developing the effective utilization technology of the novel dispersed-catalysts in the hydro-desulfurization of heavy oils, and improving the reaction performance of alumina-supported Mo-based hydro-treating catalysts conventionally used in most of refineries. First, it was experimentally proved that the dispersed catalysts of Co-Mo could be employed for the hydro-desulfurization of a heavy atmospheric residual oil excluding the catalyst deactivation. The utilization of a carbon-expanded reactor in combination with this dispersed catalyst system exhibited an enhanced reaction performance and provided an efficient way for the separation and recovery of the dispersed catalytic component from oils. Second, the tungsten-incorporated WCoMo/{gamma}-Al{sub 2}O{sub 3} catalyst revealed the improved catalytic performance in the various hydro-treating reactions and in the initial deactivation rates for the high pressure hydro-treatment of a heavy oil as compared with the commercial CoMo/{gamma}-Al{sub 2}O{sub 3} catalyst. This new experimental finding for the promoting role of the monomeric WO{sub 3} species in CoMo/{gamma}-Al{sub 2}O{sub 3} catalyst may be generally applicable to the Mo-based alumina-sulfide phase, higher catalytic activity, and more extended service life. (author). 101 refs., 33 figs., 18 tabs.

  9. Solid residues

    International Nuclear Information System (INIS)

    Mulder, E.; Duin, P.J. van; Grootenboer, G.J.

    1995-01-01

    A summary is presented of the many investigations that have been done on solid residues of atmospheric fluid bed combustion (AFBC). These residues are bed ash, cyclone ash and bag filter ash. Physical and chemical properties are discussed and then the various uses of residues (in fillers, bricks, gravel, and for recovery of aluminium) are summarised. Toxicological properties of fly ash and stack ash are discussed as are risks of pneumoconiosis for workers handling fly ash, and contamination of water by ashes. On the basis of present information it is concluded that risks to public health from exposure to emissions of coal fly ash from AFBC appear small or negligible as are health risk to workers in the coal fly ash processing industry. 35 refs., 5 figs., 12 tabs

  10. Panorama of the petroleum industry

    International Nuclear Information System (INIS)

    2003-05-01

    This document provides tables and charts of statistical data concerning the petroleum industry activity in 2002: supply and demand, prices, consumption, service station number and the market. A second part is devoted to the fuel quality and air quality: the constant improvement of the fuels and the investments refining/distribution. (A.L.B.)

  11. A Computerized Petroleum Geology Package.

    Science.gov (United States)

    Moser, Louise E.

    1983-01-01

    Describes a package of computer programs developed to implement an oil exploration game that gives undergraduate students practical experience in applying theoretical principles of petroleum geology. The programs facilitate management of the game by the instructor and enhance the learning experience. (Author/MBR)

  12. PETROLEUM BIOREFINING FOR POLLUTION PREVENTION

    Energy Technology Data Exchange (ETDEWEB)

    John J. Kilbane II

    2002-03-01

    The objective of this project was to isolate and characterize thermophilic bacterial cultures that can be used for the selective removal of nitrogen, sulfur, and/or metals in the biorefining of petroleum. The project was completed on schedule and no major difficulties were encountered. Significant progress was made on multiple topics relevant to the development of a petroleum biorefining process capable of operating at thermophilic temperatures. New cultures capable of selectively cleaving C-N or C-S bonds in molecules relevant to petroleum were obtained, and the genes encoding the enzymes for these unique biochemical reactions were cloned and sequenced. Genetic tools were developed that enable the use of Thermus thermophilus as a host to express any gene of interest, and information was obtained regarding the optimum conditions for the growth of T. thermophilus. The development of a practical biorefining process still requires further research and the future research needs identified in this project include the development of new enzymes and pathways for the selective cleavage of C-N or C-S bonds that have higher specific activities, increased substrate range, and are capable of functioning at thermophilic temperatures. Additionally, there is a need for process engineering research to determine the maximum yield of biomass and cloned gene products that can be obtained in fed-batch cultures using T. thermophilus, and to determine the best configuration for a process employing biocatalysts to treat petroleum.

  13. Volatility Spillovers Across Petroleum Markets

    Czech Academy of Sciences Publication Activity Database

    Baruník, Jozef; Kočenda, Evžen; Vácha, Lukáš

    2015-01-01

    Roč. 36, č. 3 (2015), s. 309-329 ISSN 0195-6574 R&D Projects: GA ČR GA14-24129S Keywords : Volatility spillovers * Asymmetry * Petroleum markets Subject RIV: AH - Economics Impact factor: 1.662, year: 2015 http://library.utia.cas.cz/separaty/2014/E/barunik-0438407.pdf

  14. Petroleum business of high risk

    International Nuclear Information System (INIS)

    Carta Petrolera

    2001-01-01

    The paper is about the economic risk and of the geologic risk that assist the industry of the petroleum; an analysis of these types of risk, possibilities of success and investments to carry out in the search of hydrocarbons are made

  15. Tumaco the other Petroleum face

    International Nuclear Information System (INIS)

    Carta Petrolera

    1997-01-01

    The Tumaco City (Colombia), it is one of the exit points of the Colombian and Ecuadorian petroleum. To Tumaco port arrives 80.000 daily barrels coming from the south of Colombia and Ecuador on the average. Tumaco and Covenas (shipment Port for the Caribbean Sea) they conform the points of shipment of the international trade of hydrocarbons in the country

  16. The petroleum industry in China

    International Nuclear Information System (INIS)

    1993-06-01

    A review is presented of China's petroleum industry. In recent years China has ranked as the world's fifth or sixth largest oil producer, providing ca 20% of China's energy needs and generating US $45 billion in exports during 1988-89. However, domestic oil consumption is rapidly outpacing growth in production, and China may become a net oil importer as early as March 1994 if trends continue. In order to slow declining production rates, China must: introduce modern management techniques, equipment and technology; accelerate exploration to find new reserves; employ the latest equipment and technology, consulting services and foreign training to develop new reserves as quickly as possible; and improve the efficiency with which petroleum is used and traded. Key players including the China National Petroleum Corporation, China National Oil Development Corporation, China National United Oil Company, and China National Offshore Oil Corporation are described. Current Chinese petroleum industry priorities are discussed, together with Canadian capabilities relevant to these activities, and recent bilateral agreements in the sector

  17. Heavy flavors

    International Nuclear Information System (INIS)

    Cox, B.; Gilman, F.J.; Gottschalk, T.D.

    1986-11-01

    A range of issues pertaining to heavy flavors at the SSC is examined including heavy flavor production by gluon-gluon fusion and by shower evolution of gluon jets, flavor tagging, reconstruction of Higgs and W bosons, and the study of rare decays and CP violation in the B meson system. A specific detector for doing heavy flavor physics and tuned to this latter study at the SSC, the TASTER, is described. 36 refs., 10 figs

  18. Behaviour of heavy metals in soils

    NARCIS (Netherlands)

    Harmsen, K.

    1977-01-01

    Fractions of Zn, Cd, Cu, Pb, Fe and Mn extractable with water, a salt solution and dilute acid, and residual fractions were determined in soils with raised contents of heavy metals, near zinc smelters, along a river formerly discharging heavy metals, and in a sewage farm. Special attention

  19. Petroleum Resins: Separation, Character, and Role in Petroleum

    DEFF Research Database (Denmark)

    Andersen, Simon Ivar; Speight, James

    2001-01-01

    are precipitated, adsorbents are added to the n-pentane solutions of the resins and oils, by which process the resins are adsorbed and subsequently recovered by the use of a more polar solvent, and the oils remain in solution. The resin fraction plays an important role in the stability of petroleum and prevents...... separation of the asphaltene constituents as a separate phase. Indeed, the absence of the resin fraction (produced by a variety of methods) from the maltenes influences the ability of the de-resined maltenes to accommodate the asphaltenes either in solution or as a stable part of a colloidal system. In spite....... Suggestions are also made regarding current thoughts of the role of these constituents on the structure and stability of petroleum....

  20. Petroleum Supply Monthly, September 1990. [Contains glossary

    Energy Technology Data Exchange (ETDEWEB)

    Whited, D.; Jacobus, P. (eds.)

    1990-11-28

    Data presented in this PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. 12 figs., 46 tabs.

  1. Petroleum supply monthly, October 1991. [Contains glossary

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-30

    Data presented in this report describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importer, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics 14 figs., 56 tabs.

  2. Petroleum supply monthly, October 1990. [Contains Glossary

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-27

    Data presented in this report describes the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. 12 figs., 54 tabs.

  3. Flow of microemulsion through soil columns contaminated with asphaltic residue; Fluxo de microemulsoes atraves do solo contaminado com residuos asfalticos

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Marcia C.K.; Oliveira, Jose F. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE); Oliveira, Roberto C.G.; Gonzalez, Gazpar [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    2004-07-01

    Nowadays, soil contamination with nonaqueous phase liquids (NAPLs) such as petroleum hydrocarbons is a major environmental problem. Significant efforts have been devoted to the development of processes to remediate sites contaminated with NAPLs. Unfortunately, most of the developed processes proved to be inefficient to remove the organic heavy fraction present in the NAPLs. Nevertheless, in our preliminary bench scale tests it was observed that, due to their high solubilization capacity and stability, microemulsions are able to remove organic heavy fractions like asphaltenes and resins, typically present in crude oils. The present work was dimensioned to evaluate, under up-flow condition, the performance of different microemulsions specially designed to remove asphaltenes fractions from soils using a column test set-up. The contaminant residual concentration was quantified by UV spectroscopy and the microemulsion efficiency determined using mass balance. The results showed that the microemulsions tested have a high capacity for removing asphaltenes fractions from contaminated soils. It was also observed that the predominant removal mechanism, solubilization or mobilization, depends essentially on the microemulsion's chemical formulation. Finally it was verified that microemulsion's formulations based on natural solvents compounds are also efficient for removing asphaltic residues. (author)

  4. Feasibility of high-resolution continuum source molecular absorption spectrometry in flame and furnace for sulphur determination in petroleum products

    Science.gov (United States)

    Kowalewska, Zofia

    2011-07-01

    For the first time, high-resolution molecular absorption spectrometry with a high-intensity xenon lamp as radiation source has been applied for the determination of sulphur in crude oil and petroleum products. The samples were analysed as xylene solutions using vaporisation in acetylene-air flame or in an electrothermally heated graphite furnace. The sensitive rotational lines of the CS molecule, belonging to the ∆ν = 0 vibrational sequence within the electronic transition X 1∑ + → A 1П, were applied. For graphite furnace molecular absorption spectrometry, the Pd + Mg organic modifier was selected. Strong interactions with Pd atoms enable easier decomposition of sulphur-containing compounds, likely through the temporal formation of Pd xS y molecules. At the 258.056 nm line, with the wavelength range covering central pixel ± 5 pixels and with application of interactive background correction, the detection limit was 14 ng in graphite furnace molecular absorption spectrometry and 18 mg kg -1 in flame molecular absorption spectrometry. Meanwhile, application of 2-points background correction found a characteristic mass of 12 ng in graphite furnace molecular absorption spectrometry and a characteristic concentration of 104 mg kg -1 in flame molecular absorption spectrometry. The range of application of the proposed methods turned out to be significantly limited by the properties of the sulphur compounds of interest. In the case of volatile sulphur compounds, which can be present in light petroleum products, severe difficulties were encountered. On the contrary, heavy oils and residues from distillation as well as crude oil could be analysed using both flame and graphite furnace vaporisation. The good accuracy of the proposed methods for these samples was confirmed by their mutual consistency and the results from analysis of reference samples (certified reference materials and home reference materials with sulphur content determined by X-ray fluorescence

  5. Feasibility of high-resolution continuum source molecular absorption spectrometry in flame and furnace for sulphur determination in petroleum products

    Energy Technology Data Exchange (ETDEWEB)

    Kowalewska, Zofia, E-mail: zofia.kowalewska@obr.pl

    2011-07-15

    For the first time, high-resolution molecular absorption spectrometry with a high-intensity xenon lamp as radiation source has been applied for the determination of sulphur in crude oil and petroleum products. The samples were analysed as xylene solutions using vaporisation in acetylene-air flame or in an electrothermally heated graphite furnace. The sensitive rotational lines of the CS molecule, belonging to the {Delta}{nu} = 0 vibrational sequence within the electronic transition X{sup 1}{Sigma}{sup +} {yields} A{sup 1}{Pi}, were applied. For graphite furnace molecular absorption spectrometry, the Pd + Mg organic modifier was selected. Strong interactions with Pd atoms enable easier decomposition of sulphur-containing compounds, likely through the temporal formation of Pd{sub x}S{sub y} molecules. At the 258.056 nm line, with the wavelength range covering central pixel {+-} 5 pixels and with application of interactive background correction, the detection limit was 14 ng in graphite furnace molecular absorption spectrometry and 18 mg kg{sup -1} in flame molecular absorption spectrometry. Meanwhile, application of 2-points background correction found a characteristic mass of 12 ng in graphite furnace molecular absorption spectrometry and a characteristic concentration of 104 mg kg{sup -1} in flame molecular absorption spectrometry. The range of application of the proposed methods turned out to be significantly limited by the properties of the sulphur compounds of interest. In the case of volatile sulphur compounds, which can be present in light petroleum products, severe difficulties were encountered. On the contrary, heavy oils and residues from distillation as well as crude oil could be analysed using both flame and graphite furnace vaporisation. The good accuracy of the proposed methods for these samples was confirmed by their mutual consistency and the results from analysis of reference samples (certified reference materials and home reference materials with

  6. Treatment of products from petroleum, shale, coal, lignite, etc

    Energy Technology Data Exchange (ETDEWEB)

    Jevanoff, V

    1952-06-20

    An improved process is described for treating with sodium plumbite all the products derived from crude petroleum, bituminous shale, coal, lignite, peat, etc., such as gasoline, solvents, lamp oil, gas oil, fuels, etc; the process being essentially characterized by the fact that it consists first in washing the product to be refined with a soda wash; submitting it to a treatment with sodium plumbite, without addition of sulfur, then to eliminate the sulfur plumbite compounds resulting in the treated product, using either redistillation to eliminate products remaining in the residue or filtration over an absorbing material such as active carbon, decolorizing earths.

  7. Simulation of enhanced in-situ biorestoration of petroleum hydrocarbons

    International Nuclear Information System (INIS)

    Borden, R.C.

    1991-01-01

    This paper discusses a general mathematical model being developed to aid in the design and analysis of projects for the enhanced aerobic bioremediation of petroleum-contaminated aquifers. Development of the enhanced biotransformation model is proceeding in three steps: development of an abiotic hydrocarbon dissolution model; coupling the dissolution model with existing equations for simulating aerobic biodegradation; and comparison with laboratory data. The model assumes that the residual hydrocarbon is distributed between two fractions, a fast fraction in equilibrium with the aqueous phase and a slow fraction in which mass transfer is limited. Overall, the model provides an excellent fit to the experimental data and requires a minimum of input parameters

  8. Modeling of petroleum products demand in France

    International Nuclear Information System (INIS)

    Chauvel, A.; Jamin, F.; Cholet, G.

    1995-01-01

    This project was carried out under the responsibility of the Strategy-Economics-Program Division of the ''Institut Francais du Petrole''. The goal was the short-term (12 months) forecasting of the demand with regard to the four leading petroleum products in France - gas oil (GO), automotive (CA), home heating oil (FOD) and heavy fuel oil (FL). It was decided to test an original method (1) and to compare it with the widely used Box and Jenkins method (2), which gives good results for the GO and CA series but which proves disappointing for the FOD and FL series. This study is in two parts: (1) the first part describes the original method by breaking it down into trends and seasonality, with the model being additive or multiplicative. We improved its performances by using the theory of the Weiner filter; (2) the second part concerns Box an Jenkins modeling. This model was used on the unprocessed series and then on the series corrected for the influence of working days with the help of the ''Census-X11'' deseasonalization program. For each method, the principal phases are described for the modeling of gas oil on the French domestic market. For the other products, only the principal results are given, i.e. structure of the model retained, matching with reality, reliability of forecasts. (authors). 5 refs., 5 figs., 9 tabs

  9. Alberta Petroleum Marketing Commission annual report, 1992

    International Nuclear Information System (INIS)

    1993-05-01

    The Alberta Petroleum Marketing Commission has the responsibility of selling the Crown's royalty share of Alberta's crude and synthetic oil production; similar services are provided for natural gas. The Commission also markets crude oil on behalf of producers to North American and offshore consumers. The Commission's position as the largest crude oil marketeer in Canada enables it to provide analyses of industry pricing and marketing trends to the Alberta government. 1992 marked the end of chronically depressed natural gas prices and a significant reduction in natural gas surpluses. A brief overview is presented of crude oil markets in Canada and the USA. The Commission's receipts of light and medium royalty oil totalled 45.3 million bbl, unchanged from 1991, and receipts of heavy crude were 6.3 million bbl, up 4% from 1991. Revenue from crude oil sales was $1.1 billion, down from $1.64 billion in 1991. The Commission's natural gas activities in 1992 included price determination and information collection. 9 figs., 1 tab

  10. Alberta Petroleum Marketing Commission annual report, 1993

    International Nuclear Information System (INIS)

    1994-05-01

    The Alberta Petroleum Marketing Commission has the responsibility of selling the Crown's royalty share of Alberta's crude and synthetic oil production; similar services are provided for natural gas. The Commission also markets crude oil on behalf of producers to North American and offshore consumers. The Commission's position as the largest crude oil marketer in Canada enables it to provide analyses of industry pricing and marketing trends to the Alberta government. 1993 marked the last full year of the Commission operating as Alberta's representative in the energy regulatory arena in Canada and the USA; due to restructuring, these functions will be transferred to the Ministry of Energy in early 1994. A brief overview is presented of crude oil markets in Canada and the USA. The Commission's receipts of light and medium royalty oil totalled 40.2 million bbl, down 11% from 1992, and receipts of heavy crude were 3.7 million bbl, down 42% from 1992. Revenue from crude oil sales was $800 million, down 25% from 1992. The Commission's natural gas activities in 1993 included price determination and information collection. 4 figs., 3 tabs

  11. How if petroleum still had a future

    International Nuclear Information System (INIS)

    Dupin, L.

    2010-01-01

    Despite the oil spill that hits the Gulf of Mexico since April 2010, oil firms are still going on with their technological quest to postpone the hydrocarbons exhaustion. The goal is to increase the reserves by exploiting the less accessible resources. Giving a precise estimation of oil reserves is practically impossible as the capacities announced by the main producers are extremely disputed. They are in general ranging from 960 to 1060 billions of barrels, i.e. 32 to 35 years of actual consumption (deep offshore and heavy oil reserves not included). On the contrary, gas reserves are well known. They are estimated to 175 Tm 3 , which corresponds to 60 years of actual consumption. Additional non-conventional gas reserves represent 900 Tm 3 , from which 4% are accessible today. Before starting to develop new fields, companies try to fully exploit the existing fields using enhanced recovery technologies. In 2009 the petroleum investments have weakened in all sectors except in offshore exploitation. However, the recent accident of the Deepwater Horizon platform in the Gulf of Mexico has brought the safety question to the forefront. (J.S.)

  12. Identification of key oil refining technologies for China National Petroleum Co. (CNPC)

    International Nuclear Information System (INIS)

    Liu Haiyan; Yu Jianning; Xu Jian; Fan Yu; Bao Xiaojun

    2007-01-01

    This paper summarizes the results from the project 'Vision of the Key Petroleum Refining Technologies for China National Petroleum Co. (CNPC) in the Early 21st Century' undertaken by the Department of R and D Administration, CNPC, and its affiliate key laboratory, The Key Laboratory of Catalysis operated by China University of Petroleum, Beijing. The objective of the project was to identify the challenges and opportunities of CNPC's petroleum refining business given increasing economy globalization and stricter environmental regulations. Using the modified Delphi method, four key technologies for CNPC's oil refining industry were identified. They are: integrated fluid catalytic cracking (FCC), hydroprocessing, residue hydrocracking, and high-grade lubricant production. The most significant technology will be the integrated FCC technology that can economically increase the yield of light fractions as well as upgrade transportation fuels. In China, FCC units produce about 80% and 30% commercial gasoline and diesel, respectively. To ensure compliance with future environmental legislation, hydroprocessing technologies, including those related to petroleum product hydrorefining and distillate hydrocracking, should be developed. By combining residue hydrocracking and FCC technologies, poorer quality residua can be processed. Supplying high-grade lube oils is one of the main tasks for CNPC's oil refining industry. Development of hydrodewaxing technologies to manufacture API group II/III base oil is the main direction for CNPC's lubricant production business

  13. Environmental protection and petroleum business

    Energy Technology Data Exchange (ETDEWEB)

    1986-03-01

    This report is a summary of panel discussion concerning environmental protection and petroleum business. Summarized here are country presentations from Iraq, Malaysia, Saudi Arabia, and Venezuela, comments by two Japanese panelists from petroleum companies, questions, answers, and discussions, and summary by the session moderator. The country presentation centered on pollution problems and environmental protection policies in each country, national policy regarding environmental problems, and comprehensive planning for environmental protection in specific industrial areas. The panelists' reports mainly concerned the legal framework for environmental protection in Japan and the importance of investment for environmental protection. Questions and answers clarified the problems. The moderator, when summarizing the panel discussion, stressed that environmental problems should be addressed on a global level and that early preventive measures should be taken, and also emphasized the polluter pays principle.

  14. Association models for petroleum applications

    DEFF Research Database (Denmark)

    Kontogeorgis, Georgios

    2013-01-01

    Thermodynamics plays an important role in many applications in the petroleum industry, both upstream and downstream, ranging from flow assurance, (enhanced) oil recovery and control of chemicals to meet production and environmental regulations. There are many different applications in the oil & gas...... industry, thus thermodynamic data (phase behaviour, densities, speed of sound, etc) are needed to study a very diverse range of compounds in addition to the petroleum ones (CO2, H2S, water, alcohols, glycols, mercaptans, mercury, asphaltenes, waxes, polymers, electrolytes, biofuels, etc) within a very....... Such association models have been, especially over the last 20 years, proved to be very successful in predicting many thermodynamic properties in the oil & gas industry. They have not so far replaced cubic equations of state, but the results obtained by using these models are very impressive in many cases, e...

  15. Types of international petroleum contracts

    International Nuclear Information System (INIS)

    Katz, S.B.

    1992-01-01

    This paper reports on history and development of International Petroleum Contracts. The emphasis in petroleum exploration has steadily shifted away from the domestic oil patch and toward the international arena. Today an estimated 577.3 billion bbl, or approximately 83% of the world's proven oil reserves, lie outside the western hemisphere. The distribution of these proven oil reserves can be broken down into three major socioeconomic categories - developed market economies, centrally planned economies, and developing countries - indicating that fully 76.7% of the world's proven oil reserves occur in developing countries. As multinational oil companies come into contact with the various host countries around the world, their course of action, and the course of the host country's reaction to them, are unfortunately colored by events that proceeded the initial contact

  16. Bolivian petroleum privatization taking shape

    International Nuclear Information System (INIS)

    Anon.

    1995-01-01

    Bolivia is boldly embracing a free market philosophy that extends to liberalization of the country's petroleum sector. Although petroleum industry privatization is being considered by several South American countries, only Argentina has so far completely opened its oil sector and fully privatized its state oil company. The Bolivian government's own version of privatization, capitalization, is a groundbreaking attempt to attract massive investment from the private sector without leaving the government open to accusations of stripping the country's assets for short term electoral gain. The paper discusses the government's strategy to sell the state owned company either as a single unit or to split it into upstream and downstream units. Questions still to be resolved, international interest in the move, bolivian potential, and the gas supply infrastructure are also discussed

  17. Petroleum refining industry in China

    International Nuclear Information System (INIS)

    Walls, W.D.

    2010-01-01

    The oil refining industry in China has faced rapid growth in oil imports of increasingly sour grades of crude with which to satisfy growing domestic demand for a slate of lighter and cleaner finished products sold at subsidized prices. At the same time, the world petroleum refining industry has been moving from one that serves primarily local and regional markets to one that serves global markets for finished products, as world refining capacity utilization has increased. Globally, refined product markets are likely to experience continued globalization until refining investments significantly expand capacity in key demand regions. We survey the oil refining industry in China in the context of the world market for heterogeneous crude oils and growing world trade in refined petroleum products. (author)

  18. Residual basins

    International Nuclear Information System (INIS)

    D'Elboux, C.V.; Paiva, I.B.

    1980-01-01

    Exploration for uranium carried out over a major portion of the Rio Grande do Sul Shield has revealed a number of small residual basins developed along glacially eroded channels of pre-Permian age. Mineralization of uranium occurs in two distinct sedimentary units. The lower unit consists of rhythmites overlain by a sequence of black shales, siltstones and coal seams, while the upper one is dominated by sandstones of probable fluvial origin. (Author) [pt

  19. Isotopic-tracer-aided studies on undesirable effects of heavy metals in the soil-plant system. Part of a coordinated programme on isotopic-tracer-aided studies of agrochemical residue - soil biota interactions

    International Nuclear Information System (INIS)

    Oberlaender, H.E.

    1982-07-01

    Uptake of isotopically labelled mercury (Hg-203), cadmium (Cd-115m) and zinc (Zn-65) from a calcareous chernozem and a podzolized brown earth by spring and winter varieties of wheat, rye and barley was investigated in pot experiments carried out until maturity of the plants. The labelled heavy metals, applied at concentrations innocuous to plant growth (0.5 ppm Hg or Cd, 50 ppm Zn) were determined radiometrically in the straw and in the grains of the harvested plants, as well as in the milling products (bran, semolina and flour) obtained by standard procedures of grain processing. Uptake of mercury was several hundred times smaller than the uptake of cadmium, if both metals were applied to the soil in equal amounts. Whereas the uptake of mercury from the acid soil was insignificant or not detectable, cadmium was taken up from this soil at a much higher rate than from the alkaline soil. Thus, not mercury, but cadmium imposes the greatest hazard on the food chain. Winter varieties of cereals took up more mercury and cadmium than did spring varieties. The content of heavy metals in the plants decreased considerably when plants approached maturity. During translocation through the plants the metals were gradually retained when passing from the stalks (''straw'') into the grains, and from the seed-cover (''bran'') into the endosperm (''flour''). The heavy metal contents of the grain fractions decreased in the order: bran > semolina > flour. Concentrations of heavy metals in flour were 3-8 times smaller than in straw, showing that flour is least affected by heavy metal pollution of cereals via the soil. The metal content of the various flour types was correlated with their percentage of bran and with their ash content. By adding an ion-exchanger to the soil the pattern of relative distribution of heavy metals in mature plants was not changed, but the cadmium content of all cereal products was considerably lowered

  20. Petroleum tax and financial decisions

    International Nuclear Information System (INIS)

    Stensland, G.; Sunnevaag, K.

    1993-03-01

    The work presented in this report focuses on tax motivated financial incentives in the Norwegian petroleum tax system. Of particular concern is the effects of the reserve fund requirement in the Joint Stock Companies Act. Our prime concern is the Norwegian petroleum tax system as applicable from January 1992, but for the sake of comparison, we have also examined the ''old'' Norwegian petroleum tax system. The findings presented in this report can be divided in two parts. Based on an overview over the development in debt and equity for the major part of companies operating on the Norwegian continental shelf it seems reasonable to divide the companies in three groups. The first group is companies which is not in a tax paying position, both ''foreign'' and domestic. These companies seem to use debt as their most important capital source. The second group is Norwegian companies in a tax paying position. These companies also seem to use debt as the most important capital source. The last group is ''foreign'' companies in a tax paying position. This is a group of companies that mainly use equity to finance their investments in the offshore sector. The second part of the report tries to explain these observations. In the report we compare the incentive effects in the new petroleum tax system to the old tax system. The incentives to finance investments with debt is stronger in the new tax system. Several explanations emerge. Firstly, in the old tax system the investor got an effective tax deduction of 12.8% for dividends. This is removed in the new system. Secondly, in the new system 78% tax is included in the financial statements after tax profit calculation and the maximum dividend calculation, while in the old tax system the withholding tax was excluded. 31 refs., 13 figs. 2 tabs