WorldWideScience

Sample records for heavy oil exportation

  1. Exports of crude oil, 1988

    International Nuclear Information System (INIS)

    1989-06-01

    Effective June 1, 1985, licensing and charging of oil exports ended. The Board now issues export orders specifying neither volumes nor prices and covering an exportation period of up to 1 year for light crude oil and up to 2 years for heavy crude oil, available on request to both Canadian and foreign companies. The Board has assumed a monitoring role, and export prices and volumes are reported monthly by exporters. This annual report provides a review of the volumes and prices associated with the supply and disposition of Canadian crude oil during 1988. Highlights are given with detailed information on prices, both internationally, in Canada, and the Chicago posted price by light or heavy crude, and on volumes including capacity and disposition in both domestic and export markets. A short description of the import market is included. Comparisons are made with the previous year. Export volumes of light crude oil in 1988 increased by 13% to average 50,200 m 3 /d. Export volumes of heavy crude also increased by ca 13% to 62,600 m 3 /d. 15 figs., 2 tabs

  2. Challenges for the heavy oil exportation though pipelines in deep waters; Desafios da exportacao de oleos pesados atraves de oleodutos em aguas profundas

    Energy Technology Data Exchange (ETDEWEB)

    Andreolli, Ivanilto; Borges Filho, Jonas P.; Gaspari, Eduardo F. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Due to the high pressures, low temperatures, and high viscosities involved, the heavy oil exportation in deep waters through pipelines imposes a number of challenges to be feasible. The viscosities involved in such scenarios are usually very high, which brings most of the system to a laminar flow even for the higher flow rates. In a laminar flow the viscosity is linearly and directly related to the frictional pressure drop and so its precise determination is crucial for the correct results from simulations in transient or in steady state, including the modeling thermal. This work presents some results in steady state and transient simulations of heavy oil of deg API around 16 and pipe length of approximately 20km. For the analyses in the steady state was concluded that in low outflows the required pressures can surpass the pressures in high outflows. In the transient regimen was concluded that in case of long stop, the return to the full outflow surpasses 6 days and the replacement of the fluids from the pipe by diesel is a solution to reduce significantly this time. (author)

  3. Russian crude-oil production and export still increasing

    International Nuclear Information System (INIS)

    Purho, P.

    2001-01-01

    Russian crude-oil production is still increasing. In 2000 the annual production 6.48 mb/d was about 6% higher than a year before. In 2001 the production is expected to rise near the level 7 mb/d, so the increase in production volume is fast. However, the production is still far away from the maximum level of the former Soviet Union, 12 mb/d. At the moment Russia is the second largest oil producer right after Saudi Arabia. The increase in production is based on intensified use of old oil fields caused by improved technology. The oil export of Russia far abroad in 2000 was 2.5 mb/d and near abroad into FSU countries only about 180 000 b/d. The recent export of crude-oil has been near the maximum export capacity corresponding to 2.7 mb/d. About 61 million tons of oil products were exported in 2000, and even the export of oil products is increasing. Most of this was gas oil and heavy fuel oil, but also the export of gasoline was significant. The export of oil and oil products is mainly based on shipments, but also the share of train transport is high. Nearly all the crude oil is transported west either by ships or via pipelines. The share of railway transport is only few percents. Russia will continue its own oil pumping policy despite of the appeals of OPEC for reduction of oil production. Opinion in Russia is that if the increase of production and export serves the interests of Russia, it will also be carried out. The target value for crude oil for 2002 is 22 USD per barrel. The Russian crude oil production is estimated to grow up to 7.4 - 8.4 mb/d by the year 2010

  4. Oil exports under GATT and the WTO

    International Nuclear Information System (INIS)

    Abdallah, H.

    2005-01-01

    This paper will try to focus on two aspects of oil production policy under the General Agreement on Tariffs and Trade (GATT) and the World Trade Organization. The first is how freely an oil producer can regulate the quantity of oil production and exports without violating GATT rules and the second is how an oil exporter could benefit from GATT rules to overstep barriers to market access imposed by oil-importing countries. (author)

  5. Heavy oils clean up

    International Nuclear Information System (INIS)

    Collitt, R.

    1997-01-01

    High production, transport and refining costs have long led oil companies to shun heavy crude oils. Advances in the technology of upgrading heavy oils, however, are likely to reduce transport costs and improve the refinery output. Research and development by Venezuela's state oil company, Petroleos de Venezuela (PDVSA), has resulted in a process called Aquaconversion which permits the upgrading of heavy crude oils using a catalyst and the hydrogen from steam. This may be carried out at the wellhead in small low-pressure and relatively inexpensive units. In addition, higher distillate yields of higher value could be produced by revamping the thermal cracking units of refineries to incorporate the new technology. This has generated considerable interest in Venezuela's large extra-heavy crude oil reserves and has led multinational oil companies along with PDVSA to pledge $17 billion to their development. Even at a $2 to $3 per barrel upgrading cost, Venezuela's extra heavy crudes are competitive with lighter oils from other countries. Other major markets for the new technology are likely to be China and Russia, given their own large heavy crude reserves. (UK)

  6. Utah Heavy Oil Program

    Energy Technology Data Exchange (ETDEWEB)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  7. Oil exporting countries need nuclear power

    International Nuclear Information System (INIS)

    Stauffer, T.R.

    1982-01-01

    The economic rationale for nuclear power in the oil exporting countries is analysed, with the collateral objective of defining the size of the potential market in terms of the exporting countries' economic opportunities and energy needs. The need for appropriate new institutions for licensing reactors, training personnel, and starting up plants follows directly from the size of the market and the economic incentives for the oil exporters to husband gas and oil. Gas and oil resources of the Middle Eastern countries are discussed, and future electricity needs estimated. (author)

  8. Outlook for Saskatchewan heavy oil

    International Nuclear Information System (INIS)

    Youzwa, P.

    1993-01-01

    Some of the opportunities and challenges currently facing the heavy oil industry in Saskatchewan are discussed from a government perspective. By the end of September 1993, 220 heavy oil wells were drilled in the province, and 26% of the land sales in 1993 were in heavy oil areas. About 41% of the wells drilled in heavy oil areas were horizontal oil wells. Of the total horizontal wells drilled in Saskatchewan, 48% are for heavy oil, and horizontal well production averages 85 bbl/d. Initial trends suggest that horizontal wells both accelerate production and contribute to ultimate recovery. Total heavy oil production in 1992 reached 28.9 million bbl and recoverable reserves in 1991 were 262.3 million bbl, or 1.5% of total oil in place. The low recovery is not only due to technical factors such as high viscosity but also to low investment in the heavy oil sector due to poor economics. It is hoped that lower interest and exchange rates, the success of horizontal wells and the provincial royalty structure will maintain the recent increase in heavy oil activity. The provincial government recently launched a comprehensive energy strategy in which development of a heavy oil strategy is an important component. Total heavy oil reserves exceed those of light and medium oil and have significant development potential. The Saskatchewan government wishes to adopt a cooperative and partnership approach in its dealings with the heavy oil industry to help realize this potential. 9 figs

  9. Ex-USSR: Oil exporter or importer?

    International Nuclear Information System (INIS)

    Khartukov, E.M.

    1993-01-01

    Political disintegration and economic perestroika in the former Soviet Union (FSU) have major international ramifications and some of these can be found in the oil sector. An overview is presented of the FSU oil industry, including the conditions preceding and following the breakup. Early effects of the breakup included shortages of liquid fuels and the introduction of a strict export quota and license system. The likelihood of disruptions in oil exports, caused by political clashes between Russia and the other oil-transporting republics is low. Rapid decentralization of the Soviet oil trade is likely to bring forth currency-starved national exporters that may add substantially to international market competition and further undercut unstable world oil prices. In the short term, the FSU oil industry will suffer from inevitable imbalances which will manifest themselves in regional oil shortages and gluts spreading towards neighbouring international markets. In the medium and longer term the cooperating parts will become more self-reliant or infrastructurally independent and will speed natural growth and integration into neighbouring petroleum markets. Crude oil and oil product balances of the FSU republics are presented. 2 refs., 2 figs., 7 tabs

  10. Carburetor for heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Gautreau, L

    1905-03-06

    This invention relates to a carburetor for heavy oils in which the combustion liquid circulates successively in two annular spaces at the top and bottom of the vaporizer heated by the gas from the outlet and returning from there, after having been conveniently heated, to the constant level by an appropriate tube; the constant level can be surrounded by an annular chamber in which circulates a part of the gas from the outlet.

  11. Pipeline capacity and heavy oil markets

    International Nuclear Information System (INIS)

    Scott, G.R.

    1993-01-01

    Aspects of transporting heavy crude to markets from Canadian sources are discussed, with reference to pipeline expansion, western Canadian crude supply, and exports to various Petroleum Administration for Defense Districts (PADDs) in the USA. Pipeline expansions have been proposed by Interprovincial Pipeline, Trans Mountain Pipeline, Rangeland, and Wascana, and some of these proposals are in the review stage. Western Canadian crude supply is expected to peak at 1.9 million bbl/d in 1996. An increase in heavy crude supply is expected but this increase will not be sufficient to offset a decline in light crude supply. Adequate pipeline capacity should exist with the Interprovincial expansion volume of 170,000 bbl/d and the Trans Mountain expansion of 38,000 bbl/d forecast to be in place by 1995. Canadian crude exports to the USA have steadily increased since 1989, and heavy crude exports have grown an average of 20,000 bbl/d each year. In PADD Region IV, oil production is declining and ca 20,000 bbl/d of heavy crude will be needed by the year 2000; additional pipeline capacity will be required. In PADD Region II, Canadian heavy crude imports are ca 390,000 bbl/d and further market opportunities exist, after the Interprovincial expansion is complete. When the various combinations of possible pipeline expansions or reversals are considered, a range of heavy crude near-term growth potentials is obtained in which Canadian heavy oil would displace offshore heavy oil supplied to USA refineries. This potential is seen to range from 35,000 bbl/d to 200,000 bbl/d. 7 refs., 20 figs., 3 tabs

  12. Converting heavy oils into light oils, etc

    Energy Technology Data Exchange (ETDEWEB)

    Mony, H

    1915-12-22

    A process is described for transforming heavy oils obtained by the carbonization of lignites, peats, coals, shales into light oils, and also the heavy oils of mineral and vegetable origin, consisting of heating the heavy oils or tars in the presence of one or more solid substances or liquids suitably chosen to cause the distillation of the oils under atmospheric pressure at an appropriate temperature; solid and liquid substances which favor the production of light products under the influence of heat being added preferably to the oil to be treated before putting it in the retort and before heating, so that light oils are obtained by treatment of the heavy oils in a single operation.

  13. NEB view of development potential and markets for heavy crude oil. [Canada

    Energy Technology Data Exchange (ETDEWEB)

    Scotland, W A; Gutek, A M.H.

    1977-01-01

    The phased reduction in total crude oil and equivalent exports, from 911 Mpbd in 1974 to 465 Mbpd in 1976, has no doubt had a disruptive effect on the rate of development of heavy crude oil reserves. The effect could have become more series as total exports continued to drop. However, the separate licensing of heavy crude oil for export will allow heavy crude oil to enter available markets until the early 1980s. The construction of one or several upgrading facilities by the early 1980s, combined with growing domestic requirements for heavy crude oil feedstock, could make the disposition of heavy oil largely independent of the purchasing patterns of export markets. The prospect of increased market stability combined with increasing cash flows should provide an appropriate environment to optimize the role that heavy oil resources can play in Canada's future energy balance. (12 refs.)

  14. Exploring crude oil production and export capacity of the OPEC Middle East countries

    International Nuclear Information System (INIS)

    Matsumoto, Ken'ichi; Voudouris, Vlasios; Stasinopoulos, Dimitrios; Rigby, Robert; Di Maio, Carlo

    2012-01-01

    As the world economy highly depends on crude oil, it is important to understand the dynamics of crude oil production and export capacity of major oil-exporting countries. Since crude oil resources are predominately located in the OPEC Middle East, these countries are expected to have significant leverage in the world crude oil markets by taking into account a range of uncertainties. In this study, we develop a scenario for crude oil export and production using the ACEGES model considering uncertainties in the resource limits, demand growth, production growth, and peak/decline point. The results indicate that the country-specific peak of both crude oil export and production comes in the early this century in the OPEC Middle East countries. On the other hand, they occupy most of the world export and production before and after the peak points. Consequently, these countries are expected to be the key group in the world crude oil markets. We also find that the gap between the world crude oil demand and production broadens over time, meaning that the acceleration of the development of ultra-deep-water oil, oil sands, and extra-heavy oil will be required if the world continuous to heavily rely on oil products. - Highlights: ► We simulate the future scenario of crude oil export and production using ACEGES. ► The simulated results are analyzed using the GAMLSS framework. ► The peak points of oil export and production will come early in this century. ► The OPCE Middle East will produce most of the world crude oil in the near future. ► These countries will continuously be the key players in the crude oil markets.

  15. Principles of heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Szasz, S.E.; Thomas, G.W.

    1965-10-01

    Rising exploration costs have prompted greater interest in the large known deposits of heavy oil in North America. Because of high oil viscosities in such reservoirs, recoveries are poor, fluid drives are inefficient and production rates are uneconomical. Viscosity reduction can best be accomplished by heating the reservoir. The basic aspects of reservoir heating are reviewed and those processes which are of practical importance in heavy oil reservoirs are discussed. Wellbore heating frequently can be applied to heavy oil reservoirs to increase production rates. In hot waterflooding, the water requirements are much higher than an ordinary waterflood. Steam floods are more attractive, but operating costs are generally high. Conduction heating processes appear most promising. Among these is included the cyclic steam-soak process. A simple method is presented for estimating the performance from the first cycle of steam injection into the formation, assuming gravity as the only driving energy. An example calculation for a typical heavy oil reservoir is given. (26 refs.)

  16. Oil sands and heavy oil development issues and prospects under a Liberal government

    International Nuclear Information System (INIS)

    Shiry, J.

    1993-01-01

    A short review is presented of some of the factors affecting development of the western Canadian oil sands and heavy oil deposits to the year 2000. The Alberta oil sands resource has at least 1 trillion bbl of recoverable oil. At current prices, technology is the key to reducing costs to a more economic level. Cash operating costs have halved to $15/bbl over the past decade and the oil sands companies have programs to halve that figure again. A problem is the rising cost of natural gas as a fuel, which could jeopardize further development of both oil sand and heavy oil resources. In Saskatchewan, over 25 billion bbl of heavy oil are estimated to be in place. The biggest question is what percentage can be recovered; again, technology such as horizontal wells, 3-dimensional seismic, and steam assisted recovery is playing an important role. Concerns are expressed about the intentions of the new Liberal government concerning oil sand/heavy oil development, especially on the issues of foreign investment, exports, and environmental policy. A Liberal energy policy is not likely to allow U.S. direct investment in an oil sands plant to be tied to export of production, and the energy- and emissions-intensive nature of the oil sand/heavy oil industry will tend to make environmental approvals difficult

  17. Trends in heavy oil production and refining in California

    International Nuclear Information System (INIS)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II.

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10 degrees to 20 degrees API gravity) production in California has increased from 20% of the state's total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation's energy production and refining capability. California is the recipient and refines most of Alaska's 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources

  18. Russia vows to end oil export tax

    International Nuclear Information System (INIS)

    Beck, R.J.

    1992-01-01

    This paper reports that Russia will eliminate its oil export tax by 1994 and until then will allow some exemptions, Russian officials have assured a group of US tax specialists. They stopped short of saying it would be repealed by the end of the year, the Ken Crawford, a member of a Tax Foundation delegation visiting Russia and managing partner of KPMG Peat Marwick's Moscow office. The export tax was one of several tax related Russian economic issues on which the US experts and Russian officials exchanged views early this month. The 15 member delegation was in Moscow on invitation from Russia's Ministry of Finance and State Committee on Taxation to help develop guidelines for laws governing Russia's taxation of foreign investment. The US group was sponsored by the Tax Foundation, Washington, DC, a nonprofit, nonpartisan tax and fiscal policy research and public education group

  19. Process for removing heavy metal compounds from heavy crude oil

    Science.gov (United States)

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  20. IMPACT OF CPO EXPORT DUTIES ON MALAYSIAN PALM OIL INDUSTRY

    OpenAIRE

    Ibragimov Abdulla; Fatimah Mohamed Arshad; B. K. Bala; Kusairi Mohd Noh; Muhammad Tasrif

    2014-01-01

    In January 2013, Malaysia reduced the export duty structure to be in line with the Indonesia’s duty structure. Both countries export crude and processed palm oil. Since Malaysia and Indonesia are close competitors and they compete in the same market, a change in export duty rate in one country will affect the other. Indonesia, as the world’s biggest palm oil producer, has drastically widened the values between the crude palm oil and refined palm oil export taxes since October 2011...

  1. Uranium exports could match oil imports

    International Nuclear Information System (INIS)

    McIntyre, H.C.

    1977-01-01

    Apart from a temporary embargo while safeguards are negotiated, the Canadian government limits uranium exports so as to guarantee fuel for every Canadian reactor built or planned for 30 years. On the basis of present known reserves of 172 Gg of 'cheap' U 3 O 8 and 33 of 'dear', that would mean phasing out exports after the mid 1980's, but probably much more 'dear' uranium remains to be discovered. Provincial taxation and restrictions on foreign ownership may be limitations. Discoveries range over eleven areas, but production capacity at present is 14190 Mg/d from Ontario and 3400 from Saskatchewan, with 8800 mothballed and 4860 planned or being rehabilitated. The price has jumped to $95/kg, so that uranium exports may cover half the cost of oil imports. All producers use sulfuric acid leaching, except Eldorado, which uses carbonate leaching; a process using tertiary amine is being developed. Development of the organic-cooled Th/ 233 U fuelled reactor may greatly extend fuel resources. (N.D.H.)

  2. Chinese refining capacity for Canadian heavy oil

    International Nuclear Information System (INIS)

    Bruce, G.W.

    2006-01-01

    This paper discussed China's refining capacity in relation to exports of Canadian heavy oil. Demand for oil is increasing throughout the world, and China is expected to consume 25 per cent of the projected yearly oil supplies. Alberta currently has an estimated 174 billion barrels of recoverable bitumen, and produces 1.06 million barrels per day. Production is expected to increase to 4.5 million barrels per day by the year 2020. Currently bitumen blends are refined and diluted with naphtha and sweet synthetic crude oil. Bitumen is a challenging feedstock for refineries, and requires thermal production methods or gasification processes. Primary conversion into sour synthetic crude is typically followed by hydrocracking and further refining into finished petroleum products. There are currently 50 refineries in China with a 7.4 million barrel per day capacity. Coastal refineries using imported crude oil have a 4 million barrel per day capacity. New facilities are being constructed and existing plants are being upgraded in order to process heavier and more sour crude oils. However, current refining capabilities in Chinese refineries have a limited ability for resid conversion. It was concluded that while China has a refining infrastructure, only refineries on the coast will use oil sands-derived feedstocks. However, there are currently opportunities to design refineries to match future feedstocks. tabs., figs

  3. Economic dynamics of exporting countries and restructuring their oil industries

    International Nuclear Information System (INIS)

    De La Vega Navarro, A.

    1994-01-01

    The author analyses the re-organization of oil industries in exporting countries. The approach takes internal and external dynamics of these countries' economic crisis into account. It finally makes proposals with a view to a different consistency for the economic development of these countries. This could include a change from pure ''exporting countries'' to ''countries that (among other activities) export oil'' and which will not be conditioned by the incertitude of the international oil market. This in turn means that public oil companies will have to replace thinking in terms of oil rents and assume their industrial and productive role on both national and international levels. (Author). 21 refs., 1 tab

  4. Increasing oil recovery from heavy oil waterfloods

    Energy Technology Data Exchange (ETDEWEB)

    Brice, B.W. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[BP Exploration, Calgary, AB (Canada)

    2008-10-15

    In an effort to optimize waterflood strategies in Alaska, the authors examined the results of up to 50 years of waterflooding on 166 western Canadian waterfloods recovering oil of less than 30 degrees API. The study determined the best operating practices for heavy oil waterflooding by investigating the difference between waterflooding of heavy oil and lighter oil counterparts. Operators of light oil waterflooding are advised to begin waterflooding early and maintain the voidage replacement ratio (VRR) at 1. However, this study showed that it is beneficial to delay the start of waterflooding until a certain fraction of the original oil in place was recovered. Varying the VRR was also shown to correlate with increased ultimate recovery. This statistical study of 166 western Canadian waterfloods also examined the effect of injection strategy and the effect of primary production before waterflooding. Some pre-waterflood production and under injection time is advantageous for ultimate recovery by waterfloods. Specific recommendations were presented for waterfloods in reservoirs with both high and low API gravity ranges. Each range showed a narrow sweet spot window where improved recovery occurred. 27 refs., 13 figs.

  5. Exports of Palm Oil from Ghana: A Demand Analysis

    OpenAIRE

    Kuwornu, John K.M.; Darko, Francis A.; Osei-Asare, Yaw B.; Egyir, Irene S.

    2009-01-01

    Studies have shown that the economy of Ghana cannot afford to rely solely on cocoa exports. It is imperative to diversify the export base of the Ghanaian economy. In this respect, the palm oil sub-sector of the agricultural sector, which until the early part of the 20th century was the major agricultural export commodity of Ghana, needs to be considered for promotion. Currently the palm oil industry faces the challenge of bleak export potential. This study examines trends in the quantity expo...

  6. Lifting the US crude oil export ban: A numerical partial equilibrium analysis

    International Nuclear Information System (INIS)

    Langer, Lissy; Huppmann, Daniel; Holz, Franziska

    2016-01-01

    The upheaval in global crude oil markets and the boom in shale oil production in North America brought scrutiny on the US export ban for crude oil from 1975. The ban was eventually lifted in early 2016. This paper examines the shifts of global trade flows and strategic refinery investments in a spatial, game-theoretic partial equilibrium model. We consider detailed oil supply chain infrastructure with multiple crude oil types, distinct oil products, as well as specific refinery configurations and modes of transport. Prices, quantities produced and consumed, as well as infrastructure and refining capacity investments are endogenous to the model. We compare two scenarios: an insulated US crude oil market, and a counter-factual with lifted export restrictions. We find a significant expansion of US sweet crude exports with the lift of the export ban. In the US refinery sector, more (imported) heavy sour crude is transformed. Countries importing US sweet crude gain from higher product output, while avoiding costly refinery investments. Producers of heavy sour crude (e.g. the Middle East) are incentivised to climb up the value chain to defend their market share and maintain their dominant position. - Highlights: • We study the impacts of lifting the US crude ban on global oil flows and investments. • We find massive expansion of US sweet crude oil exports. • We analyze the resulting welfare effects for US producers, refiners and consumers. • We indicate the changes on global trade patterns. • We conclude that lifting the ban is the right policy for the US and the global economy.

  7. Oil flow in deep waters: comparative study between light oils and heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Andreolli, Ivanilto [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2009-12-19

    Ultra deeper waters fields are being exploited due to technological development. Under this scenario, the flow design is accomplished through pipelines subjected to low temperature and high pressure. Moreover, these flow lines are usually long causing a fast fluid cooling, which may affect flow assurance in some cases. Problems during topsides production plant's restart might occur if the oil is viscous and even in steady state a significant different behavior can be noticed, if compared to a less viscous oil. A comparison between light and heavy oil through a case study with the objective to show some heavy oil flow particularities is the purpose of this paper. Permanent and transient analyses for a specific geometry are presented. The results showed that thermal and proper viscosity modeling are required for heavy oil flow, differently from that of light oil flow, due to the exponential viscosity dependence to temperature and because the predominant laminar regime. In addition, on heavier and heavier oil flow systems, it is essential to consider exportation system's restart. (author)

  8. EMPLOYMENT EFFECT OF INDONESIA’S NON-OIL EXPORT

    Directory of Open Access Journals (Sweden)

    Nur Feriyanto

    2011-09-01

    Full Text Available Indonesian government needs both domestic and foreign investments to accelerate its economic development. The investments enable promoting export and creating higher employment level. This research uses a path analysis method to analyze time series data of the period 1990 to 2009. It finds that both domestic and foreign direct investments significantly and positively influence Indonesia’s non-oil exports. In addition, it suggests that non-oil export performance can eventually lead to an increase in employment level in Indonesia. The policy implication of these results is that Indonesian government should encourage investment to promote export and absorb more labor. Keywords: Foreign direct investment, domestic investment, non-oil export, labor absorptionJEL classification numbers: F42, F43

  9. Depletion policies for oil-exporting developing economies

    Energy Technology Data Exchange (ETDEWEB)

    Stournaras, Y A

    1984-01-01

    The fact that most oil-exporting countries are developing economies has important implications for oil supply which have not been properly taken into account in the literature on exhaustible resource depletion. The way in which depletion policies are affected by trade uncertainty, given the high degree of the major oil exporters' 'dependence' on crude oil revenues, by investment time lags which delay the exploitation of (some of) these countries' comparative advantage in a petroleum based development, and by ideological objections to the ideal of a rentier society and to foreign capital are examined.

  10. Water issues associated with heavy oil production.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  11. Heavy oil in Saskatchewan: Building on strengths

    International Nuclear Information System (INIS)

    1994-02-01

    Saskatchewan has reserves of 17.6 billion bbl of heavy oil located in the west-central part of the province. The first oil well was drilled in 1945 and production of heavy oil has increased gradually, reaching 79,000 bbl/d in 1992. In recent years, the production pattern has not matched trends in investment; since 1982/83, the relative proportion of heavy oil drilling has declined significantly. A study is presented which analyzes trends in heavy oil investment, production, economics, and markets, with a focus on determining the causes for lack of investment in the heavy oil sector and evaluating the opportunities and constraints for long-term sustainability of this industry. Industry background is provided, with presentation of the key resource characteristics, reserve potential, and production and investment trends. Markets both in Canada and the USA are analyzed in detail, possible future trends are suggested. The effect of development of refinery capacity on heavy oil developments is examined. The logistics of shipping heavy oil to markets are detailed. The economics of Saskatchewan heavy oil production are established, taking into account all relevant cost components including taxes, royalties, and netbacks to producers. Issues of relevance affecting the heavy oil industry are discussed, including the need for environmental safeguards. 25 figs., 24 tabs

  12. US refining capacity for Canadian heavy oil : current overview and future potential

    International Nuclear Information System (INIS)

    Paget, S.

    2006-01-01

    This presentation provided an overview of the Canadian oil sands industry and investigated the potential heavy oil refining capacity of the United States. An outline of the first commercial developments of steam assisted gravity drainage (SAGD) in Alberta's oil sands was provided. Canada's reserves were compared with oil shale and heavy oil reserves in the United States and Venezuela. Influences of Canadian developments from western Canadian conventional crude oil were reviewed, and an oil sands production forecast was provided. Recent refining developments in the United States include delayed coking; catalytic cracking; fluid coking; flexicoking; and LC-fining. However, many oil sand producers are now choosing to upgrade oil, and producers are currently saturating United States markets with heavy crude oil. Canadian crude prices reached $90 per barrel in 2006. Heavy oil pipelines are now being constructed and existing heavy oil pipelines are being expanded. ConocoPhillips is planning to invest $1 billion for a new heavy oil coker, while BP is investing $3 billion for a heavy oil refinery in Indiana which plans to refine Canadian crude oil supplies. However, bitumens from Alberta are volatile in price, and excess Canadian production must be exported. Less than 10 per cent of western Canadian crude has tidewater access, and capital providers are concerned about cost over-runs. In order for the Canadian oil sands industry to succeed, refining capacity in the United States must be expanded, and open access must be provided to the Gulf coast as well as to the Pacific Ocean. tabs., figs

  13. Pacific Basin Heavy Oil Refining Capacity

    Directory of Open Access Journals (Sweden)

    David Hackett

    2013-02-01

    Full Text Available The United States today is Canada’s largest customer for oil and refined oil products. However, this relationship may be strained due to physical, economic and political influences. Pipeline capacity is approaching its limits; Canadian oil is selling at substantive discounts to world market prices; and U.S. demand for crude oil and finished products (such as gasoline, has begun to flatten significantly relative to historical rates. Lower demand, combined with increased shale oil production, means U.S. demand for Canadian oil is expected to continue to decline. Under these circumstances, gaining access to new markets such as those in the Asia-Pacific region is becoming more and more important for the Canadian economy. However, expanding pipeline capacity to the Pacific via the proposed Northern Gateway pipeline and the planned Trans Mountain pipeline expansion is only feasible when there is sufficient demand and processing capacity to support Canadian crude blends. Canadian heavy oil requires more refining and produces less valuable end products than other lighter and sweeter blends. Canadian producers must compete with lighter, sweeter oils from the Middle East, and elsewhere, for a place in the Pacific Basin refineries built to handle heavy crude blends. Canadian oil sands producers are currently expanding production capacity. Once complete, the Northern Gateway pipeline and the Trans Mountain expansion are expected to deliver an additional 500,000 to 1.1 million barrels a day to tankers on the Pacific coast. Through this survey of the capacity of Pacific Basin refineries, including existing and proposed facilities, we have concluded that there is sufficient technical capacity in the Pacific Basin to refine the additional Canadian volume; however, there may be some modifications required to certain refineries to allow them to process Western Canadian crude. Any additional capacity for Canadian oil would require refinery modifications or

  14. Dynamic correlation between stock market and oil prices: The case of oil-importing and oil-exporting countries

    OpenAIRE

    Filis, George; Degiannakis, S.; Floros, C.

    2011-01-01

    The paper investigates the time-varying correlation between stock market prices and oil prices for oil-importing and oil-exporting countries. A DCC-GARCH-GJR approach is employed to test the above hypothesis based on data from six countries; Oil-exporting: Canada, Mexico, Brazil and Oil-importing: USA, Germany, Netherlands. The contemporaneous correlation results show that i) although time-varying correlation does not differ for oil-importing and oil-exporting economies, ii) the correlation i...

  15. Exporting Alaskan North Slope crude oil: Benefits and costs

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    The Department of Energy study examines the effects of lifting the current prohibitions against the export of Alaskan North Slope (ANS) crude. The study concludes that permitting exports would benefit the US economy. First, lifting the ban would expand the markets in which ANS oil can be sold, thereby increasing its value. ANS oil producers, the States of California and Alaska, and some of their local governments all would benefit from increased revenues. Permitting exports also would generate new economic activity and employment in California and Alaska. The study concludes that these economic benefits would be achieved without increasing gasoline prices (either in California or in the nation as a whole). Lifting the export ban could have important implications for US maritime interests. The Merchant Marine Act of 1970 (known as the Jones Act) requires all inter-coastal shipments to be carried on vessels that are US-owned, US-crewed, and US-built. By limiting the shipment of ANS crude to US ports only, the export ban creates jobs for the seafarers and the builders of Jones Act vessels. Because the Jones Act does not apply to exports, however, lifting the ban without also changing US maritime law would jeopardize the jobs associated with the current fleet of Jones Act tankers. Therefore the report analyzes selected economic impacts of several maritime policy alternatives, including: Maintaining current law, which allows foreign tankers to carry oil where export is allowed; requiring exports of ANS crude to be carried on Jones Act vessels; and requiring exports of ANS crude to be carried on vessels that are US-owned and US-crewed, but not necessarily US-built. Under each of these options, lifting the export ban would generate economic benefits.

  16. Exporting Alaskan North Slope crude oil: Benefits and costs

    International Nuclear Information System (INIS)

    1994-06-01

    The Department of Energy study examines the effects of lifting the current prohibitions against the export of Alaskan North Slope (ANS) crude. The study concludes that permitting exports would benefit the US economy. First, lifting the ban would expand the markets in which ANS oil can be sold, thereby increasing its value. ANS oil producers, the States of California and Alaska, and some of their local governments all would benefit from increased revenues. Permitting exports also would generate new economic activity and employment in California and Alaska. The study concludes that these economic benefits would be achieved without increasing gasoline prices (either in California or in the nation as a whole). Lifting the export ban could have important implications for US maritime interests. The Merchant Marine Act of 1970 (known as the Jones Act) requires all inter-coastal shipments to be carried on vessels that are US-owned, US-crewed, and US-built. By limiting the shipment of ANS crude to US ports only, the export ban creates jobs for the seafarers and the builders of Jones Act vessels. Because the Jones Act does not apply to exports, however, lifting the ban without also changing US maritime law would jeopardize the jobs associated with the current fleet of Jones Act tankers. Therefore the report analyzes selected economic impacts of several maritime policy alternatives, including: Maintaining current law, which allows foreign tankers to carry oil where export is allowed; requiring exports of ANS crude to be carried on Jones Act vessels; and requiring exports of ANS crude to be carried on vessels that are US-owned and US-crewed, but not necessarily US-built. Under each of these options, lifting the export ban would generate economic benefits

  17. Non oil exports finance and economic development in Saudi Arabia

    OpenAIRE

    Alsakran, Abdullah

    2014-01-01

    This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel University Oil is an important part of the Saudi economy. With the volatility of oil prices and the pressing needs of economic growth and development, the Saudi Arabian government has planned to diversify its sources of income. To this end, the majority of effort has focused on developing the non-oil export sectors, particularly in manufacturing. Despite government efforts to enhance the ratio of non-...

  18. Estimation of the Impacts of Non-Oil Traditional and NonTraditional Export Sectors on Non-Oil Export of Azerbaijan

    Directory of Open Access Journals (Sweden)

    Nicat Hagverdiyev

    2016-12-01

    Full Text Available The significant share of oil sector of the Azerbaijan export portfolio necessitates promotion of non-oil exports. This study analyzes weather the commodities which contain the main share (more than 70% in non-oil export are traditional or non-traditional areas, using the so-called Commodity-specific cumulative export experience function, for the 1995-2015 time frame. Then, the impact of traditional and non-traditional exports on non-oil GDP investigated employing econometric model. The results of the study based on 16 non-oil commodities show that cotton, tobacco, and production of mechanic devices are traditional sectors in non-oil export. The estimation results of the model indicate that both, traditional and non-traditional non-oil export sectors have economically and statistically significant impact on non-oil GDP.

  19. Oil Spill Related Heavy Metal: A Review

    International Nuclear Information System (INIS)

    Ahmad Dasuki Mustafa; Hafizan Juahir; Kamaruzzaman Yunus; Mohammad Azizi Amran; Che Noraini Che Hasnam; Fazureen Azaman; Ismail Zainal Abidin; Syahril Hirman Azmee; Nur Hishaam Sulaiman

    2015-01-01

    Oil spill occurs every day worldwide and oil contamination is a significant contributor for the higher levels of heavy metals in the environment. This study is purposely to summarize the heavy metals which significant to major oil spill incidents around the world and effects of toxic metals to human health. The study performed a comprehensive review of relevant scientific journal articles and government documents concerning heavy metals contamination and oil spills. Overall, the heavy metals most frequently been detected in oil spill related study where Pb>Ni>V>Zn>Cd and caused many effects to human health especially cancer. In conclusion, the comparison of heavy metal level between the post - spill and baseline levels must be done, and implementation of continuous monitoring of heavy metal. In addition, the result based on the strategies must be transparent to public in order to maintaining human health. (author)

  20. Ex-Soviet Union: oil exporter or importer

    International Nuclear Information System (INIS)

    Khartukov, E.M.

    1993-01-01

    Perestroika of the Soviet economy and the political disintegration of the USSR have raised questions about the international ramifications of the ongoing economic and political developments in the world's largest oil-producing country. First of all, it relates to their impact on the quantity and quality of oil exports from the former Soviet Union (FSU). On the other hand, the opening of the national oil industry to foreign investors focuses their ever growing attention on the complicated internal, inter-republic oil issues which emerged after the sudden fragmentation of the Soviet oil empire into a dozen of sovereign but still interdependent parts. 1 fig., 7 tabs

  1. The future for heavy crude oil

    International Nuclear Information System (INIS)

    Horsnell, P.

    1995-01-01

    The expectation, still held in 1993, that the light oil-heavy crude oil differential would go on increasing in favour of light oil has not been fulfilled. Current perceptions are that heavy oil will continue to be relatively strong and there is no inevitable upward trend in light-heavy crude differentials. Non-OPEC production has grown significantly lighter overall in recent years and is likely to continue so for several more years. This is due to expanded light oil production in the North Sea, Latin America and the Far East, and contractions in heavy oil production in Russia and the USA. OPEC production has also become lighter with, in particular, an expansion in light oil and contraction in heavy grades from Saudi Arabia. At the same time, the nature of the demand from refineries has changed with the introduction of new units designed to process the residium from heavy oil distillation. Thus the supply of light oil has expanded while demand for it has contracted with the reverse being true for heavy oil. (2 figures, 1 table) (UK)

  2. Heavy Oil Recovery Ohmsett Test Report

    Science.gov (United States)

    2012-06-01

    U.S. The first phase of separation is to refloat the oil for physical collection using a conveyor belt or rope mop oil skimmer. The open discharge is...inverted cone-shroud installed in the Frac tank for physical collection using a conveyor belt or rope mop oil skimmer. Heavy Oil Recovery Ohmsett Test...develop and test viable designs for systems which can detect and recover oil from subsurface environments. This is the second major report within this

  3. Horizontal well impact on heavy oil supply

    International Nuclear Information System (INIS)

    Bowers, B.; Bielecki, J.; Hu, J.; Wall, B.; Drummond, K.

    1993-01-01

    Horizontal wells can take advantage of gravity drainage mechanisms, which can be important in conventional heavy oil and bitumen recovery. Horizontal drilling will impact on the development of established conventional heavy oil pools by infill drilling and application of enhanced recovery techniques. There will also be an impact on the development of extensions to established and newly discovered heavy oil pools, as well as a major impact on development of bitumen resources. To assess the impact of horizontal drilling on heavy oil supply, high-impact and low-impact scenarios were evaluated under specified oil-price assumptions for four heavy oil areas in Saskatchewan and Alberta. Horizontal well potential for infill drilling, waterflood projects, and thermal projects was assessed and estimates were made of such developments as reserves additions and heavy oil development wells under the two scenarios. In the low case, projected supply of conventional heavy oil and bitumen stabilizes at a level in the 90,000-94,000 m 3 /d after 1994. In the high case, overall supply continuously grows from 80,000 m 3 /d in 1992 to 140,000 m 3 /d in 2002. Through application of horizontal drilling, reserves additions in western Canada could be improved by ca 100 million m 3 by 2002. 14 figs., 6 tabs

  4. The role of Canadian heavy crude oil in the North American market

    Energy Technology Data Exchange (ETDEWEB)

    Mink, F J; Antonia, H A

    1977-01-01

    Canadian reserves of heavy gravity crude oil are vast and the potential producibility from those reserves is expected to be surplus to Canadian requirements into the 1990s. This study focuses on the impact that market constraints may have on the future supply of heavy gravity crude oils from the W. Canadian basin. It observes that severe export restrictions will not only limit the orderly development of available reserves in the area but also will impair the prospects of additional enhanced recovery of conventional heavy crude reserves and restrict future experimental applications of oil sands recovery in the Cold Lake deposit of Alberta. Since it is expected that export restrictions for heavy gravity crude oil will be lifted in the future, the outlook for expanded development of indigenous reserves is promising.

  5. How equity markets view heavy oil

    International Nuclear Information System (INIS)

    Janisch, M.L.

    2001-01-01

    A review of heavy oil economics was presented in this power point presentation with particular focus on investor motivation, the importance of heavy oil, and an outlook on commodity price for oil and natural gas. Heavy oil from oil sands is playing a major role on the Canadian domestic production front as well as globally. Almost all senior Canadian producers have a major heavy oil project in the works. Oil prices are forecasted to remain strong, but a more bullish outlook is expected for natural gas prices for both the short and long term. Natural gas drilling has increased, but the number of natural gas wells as a percentage of total wells has decreased. Recent Canadian drilling activity has placed more emphasis on crude oil production which has contributed to the lower overall natural gas drilling success rate. It was shown that infrastructure issues regarding tankers, refining capacity (at or near capacity) will be the major factor affecting the availability of crude products to market. It was also shown that heavy oil differentials have increased substantially, which could be a potential issue if oil prices begin to weaken. 1 tab., 12 figs

  6. Analysis of oil export dependency of MENA countries: Drivers, trends and prospects

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharyya, Subhes C.; Blake, Andon [CEPMLP, University of Dundee, Dundee DD1 4HN, Scotland (United Kingdom)

    2010-02-15

    The purpose of this paper is to analyse how oil export dependencies of Middle East and North African (MENA) oil producers have evolved over the past two decades and to identify the main driving factors from an energy policy perspective. The paper expresses the oil export dependency of each economy in terms of a multiplicative identity that captures effective export price, export to primary oil supply ratio, oil dependency and oil export intensity of the country. Using the data for 1980-2006, the evolution in these factors is investigated for seven MENA countries and the influence of the above factors is decomposed using the Laspeyres index. The analysis shows that energy price and increasing energy intensity in the MENA countries have influenced the overall oil export dependency. Reducing the energy intensity can improve oil export revenue share to GDP by 5-10% in most of the countries while Iran can gain significantly by increasing its export volume. (author)

  7. Analysis of oil export dependency of MENA countries: Drivers, trends and prospects

    International Nuclear Information System (INIS)

    Bhattacharyya, Subhes C.; Blake, Andon

    2010-01-01

    The purpose of this paper is to analyse how oil export dependencies of Middle East and North African (MENA) oil producers have evolved over the past two decades and to identify the main driving factors from an energy policy perspective. The paper expresses the oil export dependency of each economy in terms of a multiplicative identity that captures effective export price, export to primary oil supply ratio, oil dependency and oil export intensity of the country. Using the data for 1980-2006, the evolution in these factors is investigated for seven MENA countries and the influence of the above factors is decomposed using the Laspeyres index. The analysis shows that energy price and increasing energy intensity in the MENA countries have influenced the overall oil export dependency. Reducing the energy intensity can improve oil export revenue share to GDP by 5-10% in most of the countries while Iran can gain significantly by increasing its export volume. (author)

  8. Maximizing heavy oil value while minimizing environmental impact with HTL upgrading of heavy to light oil

    Energy Technology Data Exchange (ETDEWEB)

    Koshka, E. [Ivanhoe Energy Inc., Calgary, AB (Canada)

    2009-07-01

    This presentation described Ivanhoe Energy Inc.'s proprietary HTL upgrading technology which was designed to process heavy oil in the field to cost effectively produce an upgraded synthetic oil that meets pipeline requirements. Steam and electricity are generated from the energy produced during the process. HTL improves the economics of heavy oil production by reducing the need for natural gas and diluent, and by capturing most of the heavy to light oil price differential. Integrated HTL heavy oil production also provides many environmental benefits regarding greenhouse gas (GHG) emissions. The HTL upgrading process is ready for full scale application. tabs., figs.

  9. The Asymmetric Effects of Oil Shocks on an Oil-exporting Economy

    OpenAIRE

    Omar Mendoza; David Vera

    2010-01-01

    We estimate the effects of unexpected changes in oil prices on output for the case of Venezuela, an oil-exporting economy. Following Hamilton (2003), Lee et al. (1995), and Mork (1989), we estimate measures of oil shocks and determine the effect of these

  10. Technology management for heavy oil

    International Nuclear Information System (INIS)

    Kerr, R.

    1994-01-01

    The framework for investment in research and development (R ampersand D) at a medium-sized Canadian petroleum company is described. The importance of R ampersand D is illustrated by a graph showing the strong positive correlation between R ampersand D intensity and sales for companies in the mainstream oil and gas sector in the USA. Strong R ampersand D efforts also help to maintain market share and enhance corporate ability to transfer technology into its operations. Three ways of structuring, developing, and transferring technology are outlined: using in-house R ampersand D facilities, which is too costly for medium-sized firms; having a central group responsible for funding third-party R ampersand D, transferring technology into the company, and being aware of technology activities within and outside the company; and complete decentralizing of R ampersand D, in which operations decides how, when, and what to spend on R ampersand D. For the medium-sized company, the second option is considered the best choice. Essential R ampersand D administration practices for such a company are reviewed, including corporate support, an updated technology strategy, central funding with a separate budget from operations, a portfolio of R ampersand D projects and ideas, collaboration with other organizations, and effective communication of R ampersand D activity and results to the company. At the company studied, Wascana Energy, R ampersand D is being focused on three priority areas: production technology, enhanced recovery, and heavy oil upgrading. It is estimated that the monetary benefits of R ampersand D in these three areas could be as much as $100 million. The evaluation of R ampersand D performance is then discussed and critical factors for R ampersand D success are listed. 3 figs., 1 tab

  11. Major oil exporters may profit rather than lose, in a carbon-constrained world

    International Nuclear Information System (INIS)

    Persson, Tobias A.; Azar, C.; Johansson, D.; Lindgren, K.

    2007-01-01

    The Organization of Petroleum Exporting Countries (OPEC) claims compensation for losses in expected oil export revenues due to CO 2 mitigation measures in developing countries. These losses are expected for two primary reasons: a reduction in the consumption of oil in importing countries and a reduction in the producer price of oil (taxation in an importing country implies a transfer of rents from producers to consumers). So far, most studies have focused on these two mechanisms and corroborated that revenue losses for OPEC are to be expected. However, there are also mechanisms that may be expected to raise the price of oil products. In a cost-effective regime for dealing with climate change, i.e., a regime in which all or most countries participate and in which the same carbon price is applied on all carbon-emitting activities, the cost of using unconventional oil, or synthetic diesel from coal, will increase even more than the cost of using conventional oil. Given that reserves of conventional oil are expected to dwindle over time, heavy oils and coal to liquids might set the long-run price for liquid fuels, which means that the price of oil would increase beyond the carbon fee; i.e., the rent on conventional oil would increase. We use an energy-economic optimization model to analyze these three mechanisms. We find that the net present value of OPEC revenue from conventional oil increases slightly (at most by 4 percent) with a global CO 2 restriction regime. We also consider conditions under which this result does not hold

  12. Canadian operators boost heavy oil production

    International Nuclear Information System (INIS)

    Perdue, J.M.

    1996-01-01

    Recent technological advances in slurry pipelining, horizontal wells, and thermal recovery techniques have made recovery of Canadian heavy oil resources more economical. In addition, reduced government royalties have made investment in these difficult reservoirs more attractive. As a result, activity has increased in heavy-oil fields in Alberta and Saskatchewan. This paper review the various oil sand recovery projects under development in the area and the current government policies which are helping to develop them. The paper also provides brief descriptions of the equipment and technologies that have allowed a reduced cost in the development. Items discussed include surface mining techniques, horizontal drilling, reservoir engineering techniques, separation processes, and thermal recovery

  13. The asymmetric relationship between oil revenues and economic activities: The case of oil-exporting countries

    International Nuclear Information System (INIS)

    Mehrara, Mohsen

    2008-01-01

    This paper examines the nonlinear or asymmetric relationship between oil revenues and output growth in oil-exporting countries, applying a dynamic panel framework and two different measures of oil shocks. The main results in this paper confirm the stylized facts that in heavily oil-dependent countries lacking the institutional mechanisms de-linking fiscal expenditure from current revenue, oil revenue shocks tend to affect the output in asymmetric and nonlinear ways. The findings suggest that output growth is adversely affected by the negative oil shocks, while oil booms or the positive oil shocks play a limited role in stimulating economic growth. The findings have practical policy implications for decision makers in the area of macroeconomic planning. The use of stabilization and savings funds and diversification of the real sector seems crucial to minimize the harmful effects of oil booms and busts

  14. Exports, government size and economic growth (Evidence from Iran as a developing oil-export based economy)

    NARCIS (Netherlands)

    S.F. Dizaji (Sajjad Faraji)

    2012-01-01

    textabstractIn this study, I investigate the short run and long run effects of government size and exports on the economic growth of Iran as a developing oil export based economy for the period of 1974 to 2008. For this purpose I use the bounds testing approach to cointegration and error correction

  15. Canadian heavy oil supply and demand

    International Nuclear Information System (INIS)

    Eynon, G.

    1997-01-01

    The wealth of business opportunities presented by Canada's vast heavy oil and bitumen resources in the face of declining reserves of light and medium crude were discussed. It was argued that Western Canadian producers, as a group, appear to lack the appreciation of the impacts of midstream and downstream sectors of the heavy oil business. The vertical integration of the heavy oil industry in Venezuela was cited as an example of the direction that Canadian producers should travel to achieve the control over their own destiny through ownership of the means of transportation, refining and marketing that is commensurate with their growing importance in the energy sector. The opportunities are great, but long-term success will require a sophisticated and integrated business approach. 4 figs

  16. Heavy mineral concentration from oil sand tailings

    Energy Technology Data Exchange (ETDEWEB)

    Chachula, F.; Erasmus, N. [Titanium Corp. Inc., Regina, SK (Canada)

    2008-07-01

    This presentation described a unique technique to recover heavy minerals contained in the froth treatment tailings produced by oil sand mining extraction operations in Fort McMurray, Alberta. In an effort to process waste material into valuable products, Titanium Corporation is developing technology to recover heavy minerals, primarily zircon, and a portion of bitumen contained in the final stage of bitumen processing. The process technology is being developed to apply to all mined oil sands operations in the Fort McMurray region. In 2004, Titanium Corporation commissioned a pilot research facility at the Saskatchewan Research Council to test dry oil sands tailings. In 2005, a bulk sampling pilot plant was connected to the fresh oil sands tailings pipeline on-site in Fort McMurray, where washed sands containing heavy minerals were processed at a pilot facility. The mineral content in both deposited tailings and fresh pipeline tailings was assessed. Analysis of fresh tailings on a daily basis identified a constant proportion of zircon and higher levels of associated bitumen compared with the material in the deposited tailings. The process flow sheet design was then modified to remove bitumen from the heavy minerals and concentrate the minerals. A newly modified flotation process was shown to be a viable processing route to recover the heavy minerals from froth treatment tailings. 8 refs., 9 tabs., 12 figs.

  17. Catalytic hydroprocessing of heavy oil feedstocks

    International Nuclear Information System (INIS)

    Okunev, A G; Parkhomchuk, E V; Lysikov, A I; Parunin, P D; Semeikina, V S; Parmon, V N

    2015-01-01

    A grave problem of modern oil refining industry is continuous deterioration of the produced oil quality, on the one hand, and increase in the demand for motor fuels, on the other hand. This necessitates processing of heavy oil feedstock with high contents of sulfur, nitrogen and metals and the atmospheric residue. This feedstock is converted to light oil products via hydrogenation processes catalyzed by transition metal compounds, first of all, cobalt- or nickel-promoted molybdenum and tungsten compounds. The processing involves desulfurization, denitrogenation and demetallization reactions as well as reactions converting heavy hydrocarbons to lighter fuel components. The review discusses the mechanisms of reactions involved in the heavy feedstock hydroprocessing, the presumed structure and state of the catalytically active components and methods for the formation of supports with the desired texture. Practically used and prospective approaches to catalytic upgrading of heavy oil feedstock as well as examples of industrial processing of bitumen and vacuum residues in the presence of catalysts are briefly discussed. The bibliography includes 140 references

  18. Catalytic hydroprocessing of heavy oil feedstocks

    Science.gov (United States)

    Okunev, A. G.; Parkhomchuk, E. V.; Lysikov, A. I.; Parunin, P. D.; Semeikina, V. S.; Parmon, V. N.

    2015-09-01

    A grave problem of modern oil refining industry is continuous deterioration of the produced oil quality, on the one hand, and increase in the demand for motor fuels, on the other hand. This necessitates processing of heavy oil feedstock with high contents of sulfur, nitrogen and metals and the atmospheric residue. This feedstock is converted to light oil products via hydrogenation processes catalyzed by transition metal compounds, first of all, cobalt- or nickel-promoted molybdenum and tungsten compounds. The processing involves desulfurization, denitrogenation and demetallization reactions as well as reactions converting heavy hydrocarbons to lighter fuel components. The review discusses the mechanisms of reactions involved in the heavy feedstock hydroprocessing, the presumed structure and state of the catalytically active components and methods for the formation of supports with the desired texture. Practically used and prospective approaches to catalytic upgrading of heavy oil feedstock as well as examples of industrial processing of bitumen and vacuum residues in the presence of catalysts are briefly discussed. The bibliography includes 140 references.

  19. RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek; William E. Brigham

    1999-06-01

    The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

  20. Active carbon catalyst for heavy oil upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Fukuyama, Hidetsugu; Terai, Satoshi [Technology Research Center, Toyo Engineering Corporation, 1818 Azafujimi, Togo, Mobara-shi, Chiba 297-00017 (Japan); Uchida, Masayuki [Business Planning and Exploring Department, Overseas Business Development and Marketing Division, Toyo Engineering Corporation, 2-8-1 Akanehama, Narashino-shi, Chiba 275-0024 (Japan); Cano, Jose L.; Ancheyta, Jorge [Maya Crude Treatment Project, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas No. 152, Col. San Bartolo Atepehuacan, Mexico D.F. 07730 (Mexico)

    2004-11-24

    The active carbon (AC) catalyst was studied by hydrocracking of Middle Eastern vacuum residue (VR) for heavy oil upgrading. It was observed that the active carbon has the affinity to heavy hydrocarbon compounds and adsorption selectivity to asphaltenes, and exhibits better ability to restrict the coke formation during the hydrocracking reaction of VR. The mesopore of active carbon was thought to play an important role for effective conversion of heavy hydrocarbon compounds into lighter fractions restricting carbon formation. The performance of the AC catalyst was examined by continuous hydrocracking by CSTR for the removal of such impurities as sulfur and heavy metals (nickel and vanadium), which are mostly concentrated in the asphaltenes. The AC catalyst was confirmed to be very effective for the removal of heavy metals from Middle Eastern VR, Maya/Istmo VR and Maya VR. The extruded AC catalysts were produced by industrial manufacturing method. The application test of the extruded AC catalyst for ebullating-bed reactor as one of the commercially applicable reactors was carried out at the ebullating-bed pilot plant for 500h. The ebullition of the extruded AC catalyst was successfully traced and confirmed by existing {gamma}-ray density meter. The extruded AC catalyst showed stable performance with less sediment formation at an equivalent conversion by conventional alumina catalyst at commercial ebullating-bed unit. The degradation of the AC catalyst at the aging test was observed to be less than that of the conventional alumina catalyst. Thus, the AC catalyst was confirmed to be effective and suitable for upgrading of heavy oil, especially such heavy oils as Maya, which contains much heavy metals.

  1. Clerget 100 hp heavy-oil engine

    Science.gov (United States)

    Leglise, Pierre

    1931-01-01

    A complete technical description of the Clerget heavy-oil engine is presented along with the general characteristics. The general characteristics are: 9 cylinders, bore 120 mm, stroke 130 mm, four-stroke cycle engine, rated power limited to 100 hp at 1800 rpm; weight 228 kg; propeller with direct drive and air cooling. Moving parts, engine block, and lubrication are all presented.

  2. How equity markets view heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Janisch, M. L. [Nesbitt Burns Research, Toronto, ON (Canada)

    1996-12-31

    Factors that influence the equity market in investment decisions vis-a-vis the oil sands/heavy oil industry were reviewed. The importance of financing methods (debt, royalty trusts, common equity), liquidity of investments, absolute vs. relative performance, comparative economics vis-a-vis conventional oil producers, oil prices, operating cost drivers (technology, natural gas costs, cost/availability of diluent), transportation and refining capacity, were summarized. In the final analysis, consistent economic success on a large scale, combined with an assessment of available alternatives, were considered to be the most likely motivators for portfolio managers. As a cautionary note, it was noted that traditionally, oil and gas investors have not been known to be in the forefront to invest in research and development.

  3. How equity markets view heavy oil

    International Nuclear Information System (INIS)

    Janisch, M. L.

    1996-01-01

    Factors that influence the equity market in investment decisions vis-a-vis the oil sands/heavy oil industry were reviewed. The importance of financing methods (debt, royalty trusts, common equity), liquidity of investments, absolute vs. relative performance, comparative economics vis-a-vis conventional oil producers, oil prices, operating cost drivers (technology, natural gas costs, cost/availability of diluent), transportation and refining capacity, were summarized. In the final analysis, consistent economic success on a large scale, combined with an assessment of available alternatives, were considered to be the most likely motivators for portfolio managers. As a cautionary note, it was noted that traditionally, oil and gas investors have not been known to be in the forefront to invest in research and development

  4. Research on oil recovery mechanisms in heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, Anthony R.; Brigham, William E., Castanier, Louis M.

    2000-03-16

    The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties, (2) in-situ combustion, (3) additives to improve mobility control, (4) reservoir definition, and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx.

  5. Value of NMR logging for heavy oil characterization

    Energy Technology Data Exchange (ETDEWEB)

    Chen, S.; Chen, J.; Georgi, D. [Baker Hughes, Calgary, AB (Canada); Sun, B. [Chevron Energy Technology Co., Calgary, AB (Canada)

    2008-07-01

    Non-conventional, heavy oil fields are becoming increasingly important to the security of energy supplies and are becoming economically profitable to produce. Heavy oil reservoirs are difficult to evaluate since they are typically shallow and the connate waters are very fresh. Other heavy oil reservoirs are oil-wet where the resistivities are not indicative of saturation. Nuclear magnetic resonance (NMR) detects molecular level interactions. As such, it responds distinctively to different hydrocarbon molecules, thereby opening a new avenue for constituent analysis. This feature makes NMR a more powerful technique than bulk oil density or viscosity measurements for characterizing oils, and is the basis for detecting gas in heavy oil fields. NMR logging, which measures fluid in pore space directly, is capable of separating oil from water. It is possible to discern movable from bound water by analyzing NMR logs. The oil viscosity can be also quantified from NMR logs, NMR relaxation time and diffusivity estimates. The unique challenges for heavy oil reservoir characterization for the NMR technique were discussed with reference to the extra-fast decay of the NMR signal in response to extra-heavy oil/tars, and the lack of sensitivity in measuring very slow diffusion of heavy oil molecules. This paper presented various methods for analyzing heavy oil reservoirs in different viscosity ranges. Heavy oil fields in Venezuela, Kazakhstan, Canada, Alaska and the Middle East were analyzed using different data interpretation approaches based on the reservoir formation characteristics and the heavy oil type. NMR direct fluid typing was adequate for clean sands and carbonate reservoirs while integrated approaches were used to interpret extra heavy oils and tars. It was concluded that NMR logs can provide quantitative measures for heavy oil saturation, identify sweet spots or tar streaks, and quantify heavy oil viscosity within reasonable accuracy. 14 refs., 16 figs.

  6. 76 FR 52994 - Application for a License To Export Heavy Water

    Science.gov (United States)

    2011-08-24

    ... NUCLEAR REGULATORY COMMISSION Application for a License To Export Heavy Water Pursuant to 10 CFR... (liters). producing an active water). pharmaceutical ingredient known as CTP-499, which incorporates heavy water as the source of deuterium to achieve the hydrogen-deuterium exchange. November 30, 2010 December...

  7. Oil prices, fiscal policy, and economic growth in oil-exporting countries

    Science.gov (United States)

    El-Anshasy, Amany A.

    This dissertation argues that in oil-exporting countries fiscal policy could play an important role in transmitting the oil shocks to the economy and that the indirect effects of the changes in oil prices via the fiscal channel could be quite significant. The study comprises three distinct, yet related, essays. In the first essay, I try to study the fiscal policy response to the changes in oil prices and to their growing volatility. In a dynamic general equilibrium framework, a fiscal policy reaction function is derived and is empirically tested for a panel of 15 oil-exporters covering the period 1970--2000. After the link between oil price shocks and fiscal policy is established, the second essay tries to investigate the impact of the highly volatile oil prices on economic growth for the same sample, controlling for the fiscal channel. In both essays the study employs recent dynamic panel-data estimation techniques: System GMM. This approach has the potential advantages of minimizing the bias resulting from estimating dynamic panel models, exploiting the time series properties of the data, controlling for the unobserved country-specific effects, and correcting for any simultaneity bias. In the third essay, I focus on the case of Venezuela for the period 1950--2001. The recent developments in the cointegrating vector autoregression, CVAR technique is applied to provide a suitable framework for analyzing the short-run dynamics and the long-run relationships among oil prices, government revenues, government consumption, investment, and output.

  8. Heavy Silicone Oil and Intraocular Inflammation

    Directory of Open Access Journals (Sweden)

    Francesco Morescalchi

    2014-01-01

    Full Text Available In the past two decades, many advances have been made in vitrectomy instrumentation, surgical techniques, and the use of different tamponade agents. These agents serve close retinal breaks, confine eventual retinal redetachment, and prevent proliferative vitreoretinopathy (PVR. Long-acting gases and silicone oil are effective internal tamponade agents; however, because their specific gravity is lower than that of the vitreous fluid, they may provide adequate support for the superior retina but lack efficacy for the inferior retina, especially when the fill is subtotal. Thus, a specific role may exist for an internal tamponade agent with a higher specific gravity, such as heavy silicone oils (HSOs, Densiron 68, Oxane HD, HWS 45-300, HWS 46-3000, and HeavySil. Some clinical evidence seems to presume that heavy tamponades are more prone to intraocular inflammation than standard silicone if they remain in the eye for several months. In this review, we discuss the fundamental clinical and biochemical/molecular mechanisms involved in the inflammatory response after the use of heavy tamponade: toxicity due to impurities or instability of the agent, direct toxicity and immunogenicity, oil emulsification, and mechanical injury due to gravity. The physical and chemical properties of various HSOs and their efficacy and safety profiles are also described.

  9. Economic Exposure to Oil Price Shocks and the Fragility of Oil-Exporting Countries

    Directory of Open Access Journals (Sweden)

    Toon Vandyck

    2018-04-01

    Full Text Available From a price range between 100 and 120 USD (U.S. dollars per barrel in 2011–2014, the crude oil price fell from mid-2014 onwards, reaching a level of 26 USD per barrel in January 2016. Here we assess the economic consequences of this strong decrease in the oil price. A retrospective analysis based on data of the past 25 years sheds light on the vulnerability of oil-producing regions to the oil price volatility. Gross domestic product (GDP and government revenues in many Gulf countries exhibit a strong dependence on oil, while more diversified economies improve resilience to oil price shocks. The lack of a sovereign wealth fund, in combination with limited oil reserves, makes parts of Sub-Saharan Africa particularly vulnerable to sustained periods of low oil prices. Next, we estimate the macroeconomic impacts of a 60% oil price drop for all regions in the world. A numerical simulation yields a global GDP increase of roughly 1% and illustrates how the regional impact on GDP relates to oil export dependence. Finally, we reflect on the broader implications (such as migration flows of macroeconomic responses to oil prices and look ahead to the challenge of structural change in a world committed to limiting global warming.

  10. Pre-electrocoalescer unit adapted to the extra-heavy oil characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Noik, C.; Dalmazzone, C. [IFP, Rueil-Malmaison (France); Glenat, P. [Total, Paris (France)

    2008-10-15

    This paper described a dehydration process that can break water oil emulsions to mobilize extra heavy oils and bitumen extra heavy oils. The dehydration process is based on solvent mixture with additives injection. It involves large amount of additives, fairly high operating temperatures, solvent addition, and long retention time inside the vessels. The process could be improved by electrocoalescence, thereby reducing the amount of additive and reducing the retention times of vessels to reach oil export specifications. However, commercial electrocoalescence processes are not suitable for extra heavy oils because of the presence of polar heavy components limiting the electrocoalescence effect and therefore, limiting the efficiency of electrostatic coalescer. This paper presented a study whose objective was to determine the most efficient electrocoalescence parameters considering the characteristics of two types of heavy crude oils issued from cold and thermal productions. The paper presented experimental results for electrocoalescence additive selection and for the optimization of electrical parameters. The paper described the materials and methods, including fluids characterization; viscosity; differential scanning calorimetry; dispersion rig; electrical stability tester; and electrocoalescer rig. It was concluded that crude oils produced by thermal production schemes seemed more sensitive to the temperature effect than crudes produced by cold production. 10 refs., 3 tabs., 23 figs.

  11. Process of transforming into light oils heavy oils from carbonization of lignites, coals, etc

    Energy Technology Data Exchange (ETDEWEB)

    Mony, H

    1926-12-20

    A process is described for transforming into light oils the heavy oils coming from the carbonization of lignites, peats, coals, and shales, and heavy oils from original minerals and vegetables, consisting of heating the heavy oils or tars in the presence of one or more solid or liquid substances conveniently chosen, with a veiw to effect distillation of the oils under atmospheric pressure at an appropriate temperature, the solids or liquid substances favoring the formation of light products under the influence of heat, being preferably added to the oil before admitting it to the retort and heating, so that the light oils are obtained from the heavy oils in a single operation.

  12. Net oil exports embodied in China's international trade: An input–output analysis

    International Nuclear Information System (INIS)

    Tang, Xu; Zhang, Baosheng; Feng, Lianyong; Snowden, Simon; Höök, Mikael

    2012-01-01

    As the world's second largest oil importer, China has been one of the important factors which affect the global oil market. In recent years, China has attained great international trade surplus through exporting a large number of “Made in China” products even during the global economic crisis. Due to direct and indirect effects in production chain, each 'Made in China' product contains oil directly or indirectly. China is exporting much oil through “Made in China” products, which is not often considered even within China. An input–output model is established to calculate oil embodied in the international trade of China. The research results suggest the following: China's net oil exports embodied in the international trade were 87.02 million tonnes in 2007; manufacture of communication equipment, computers and other electronic equipment is the largest sector to export embodied oil; United States, China Hong Kong SAR and Netherlands are the top three countries and regions which benefit most from the embodied oil in “Made in China” products. China's adjusted degree of dependence on foreign oil is 24.9% in 2007, and 38.4% in 2011 if net oil exports embodied in international trade are considered. -- Highlights: ► Model is established based on IO analysis to calculate the net oil exports embodied in China's international trade. ► China's net oil exports through “Made in China” products are 87 million tones in 2007. ► United States, China Hong Kong SAR and Netherlands benefit most from the embodied oil in China's international trade. ► China's degree of dependence on foreign oil can be reduced obviously if oil embodied in international trade are considered.

  13. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek; Louis M. Castanier

    2002-09-30

    The Stanford University Petroleum Research Institute (SUPRI-A) conducts a broad spectrum of research intended to help improve the recovery efficiency from difficult to produce reservoirs including heavy oil and fractured low permeability systems. Our scope of work is relevant across near-, mid-, and long-term time frames. The primary functions of the group are to conduct direction-setting research, transfer research results to industry, and educate and train students for careers in industry. Presently, research in SUPRI-A is divided into 5 main project areas. These projects and their goals include: (1) Multiphase flow and rock properties--to develop better understanding of the physics of displacement in porous media through experiment and theory. This category includes work on imbibition, flow in fractured media, and the effect of temperature on relative permeability and capillary pressure. (2) Hot fluid injection--to improve the application of nonconventional wells for enhanced oil recovery and elucidate the mechanisms of steamdrive in low permeability, fractured porous media. (3) Mechanisms of primary heavy oil recovery--to develop a mechanistic understanding of so-called ''foamy oil'' and its associated physical chemistry. (4) In-situ combustion--to evaluate the effect of different reservoir parameters on the insitu combustion process. (5) Reservoir definition--to develop and improve techniques for evaluating formation properties from production information. What follows is a report on activities for the past year. Significant progress was made in all areas.

  14. Hydrogenation upgrading of heavy oil residues

    Energy Technology Data Exchange (ETDEWEB)

    Krichko, A.A.; Maloletnev, A.S.; Mazneva, O.A.; Galkina, N.I. [Fossil Fuel Inst., Moscow (Russian Federation). Hydrogenation and Gasification Dept.; Suvorov, U.P.; Khadjiev, S.N. [Inst. Oil and Chemical Synthesis, Moscow (Russian Federation). Hydrogenation of Heavy Residues Dept.

    1997-12-31

    At present time in the world there is no simple and effective technology at low pressure (<15-20 MPa) which could give the opportunity to use oil residues for distillate fractions production. In Russia a process for hydrogenation (up 6 MPa hydrogen pressure) of high boiling point (b.p. >520 C) oil products, including high S, V and Ni contents ones, into distillates, feedstock for catalytic cracking (b.p. 360-520 C) and metal concentrates. The main point of the new process is as follows: the water solution of catalytic additive, for which purpose water soluble metal salts of VI-VIII groups are used, is mixed with heavy oil residues, dispersed and then subjected to additional supercavitation in a special apparatus. (orig.)

  15. Heavy oils processing materials requirements crude processing

    Energy Technology Data Exchange (ETDEWEB)

    Sloley, Andrew W. [CH2M Hill, Englewood, CO (United States)

    2012-07-01

    Over time, recommended best practices for crude unit materials selection have evolved to accommodate new operating requirements, feed qualities, and product qualities. The shift to heavier oil processing is one of the major changes in crude feed quality occurring over the last 20 years. The three major types of crude unit corrosion include sulfidation attack, naphthenic acid attack, and corrosion resulting from hydrolyzable chlorides. Heavy oils processing makes all three areas worse. Heavy oils have higher sulfur content; higher naphthenic acid content; and are more difficult to desalt, leading to higher chloride corrosion rates. Materials selection involves two major criteria, meeting required safety standards, and optimizing economics of the overall plant. Proper materials selection is only one component of a plant integrity approach. Materials selection cannot eliminate all corrosion. Proper materials selection requires appropriate support from other elements of an integrity protection program. The elements of integrity preservation include: materials selection (type and corrosion allowance); management limits on operating conditions allowed; feed quality control; chemical additives for corrosion reduction; and preventive maintenance and inspection (PMI). The following discussion must be taken in the context of the application of required supporting work in all the other areas. Within that context, specific materials recommendations are made to minimize corrosion due to the most common causes in the crude unit. (author)

  16. Energy substitution in oil-exporting LDC's the Indonesian experience

    Energy Technology Data Exchange (ETDEWEB)

    Rose, A.; Soelistijo, U. (Pennsylvania State University, University Park (USA). Dept. of Mineral Economics)

    1989-02-01

    Many oil-exporting LDCs defy the stereotype of an OPEC country with an excess of oil reserves for current and future needs. In this paper it is suggested that serious consideration be given to the substitution of other fossil energy resources for oil used domestically in order to release more oil for export. This will generate more foreign exchange and extend the life of the reserve base. A coal-oil substitution programme for Indonesia is presented and analysed to illustrate the economic development benefits of this strategy. 11 refs., 1 fig., 4 tabs.

  17. Density and viscosity modeling and characterization of heavy oils

    DEFF Research Database (Denmark)

    Cisneros, Sergio; Andersen, Simon Ivar; Creek, J

    2005-01-01

    to thousands of mPa center dot s. Essential to the presented extended approach for heavy oils is, first, achievement of accurate P nu T results for the EOS-characterized fluid. In particular, it has been determined that, for accurate viscosity modeling of heavy oils, a compressibility correction in the way...... are widely used within the oil industry. Further work also established the basis for extending the approach to heavy oils. Thus, in this work, the extended f-theory approach is further discussed with the study and modeling of a wider set of representative heavy reservoir fluids with viscosities up...

  18. Heavy crude oils - From Geology to Upgrading - An Overview

    International Nuclear Information System (INIS)

    Huc, A.Y.

    2010-01-01

    Heavy oils, extra-heavy oils and tar sands are major players for the future of energy. They represent a massive world resource, at least the size of conventional oils. They are found all over the world but Canada and Venezuela together account, by themselves, for more than half of world deposits. They share the same origin as the lighter conventional oils, but their geological fate drove them into thick, viscous tar-like crude oils. Most of them result from alteration processes mediated by microbial degradation. They are characterized by a low content of lighter cuts and a high content of impurities such as sulfur and nitrogen compounds and metals; so, their production is difficult and deployment of specific processes is required in order to enhance their transportability and to upgrade them into valuable products meeting market needs, and honouring environmental requirements. Although these resources are increasingly becoming commercially producible, less than 1% of total heavy crude oil deposits worldwide are under active development. The voluntarily wide scope of this volume encompasses geology, production, transportation, upgrading, economics and environmental issues of heavy oils. It does not pretend to be exhaustive, but to provide an authoritative view of this very important energy resource. Besides presenting the current status of knowledge and technology involved in exploiting heavy oils, the purpose is to provide an insight into technical, economic and environmental challenges that should be taken up in order to increase the efficiency of production and processing, and finally to give a prospective view of the emerging technologies which will contribute to releasing the immense potential reserves of heavy oil and tar deposits. Contents: Part 1. Heavy Crude Oils.1. Heavy Crude Oils in the Perspective of World Oil Demand. 2. Definitions and Specificities. 3. Geological Origin of Heavy Crude Oils. 4. Properties and composition. Part 2. Reservoir Engineering

  19. Implications of lifting the ban on the export of Alaskan crude oil

    Energy Technology Data Exchange (ETDEWEB)

    1990-03-26

    Present legislation effectively bans the export of crude oil produced in the United States. The ban has been in effect for years and is particularly stringent with respect to crude oil produced in Alaska, particularly on the North Slope. The Alaska crude export ban is specifically provided for in the Trans-Alaska Pipeline Authorization Act of 1973 and in other legislation. It was imposed for two reasons. The first was to reduce US dependence on imported crude oil. The Arab oil embargo had been imposed shortly before the Act was passed and a greater measure of energy independence was considered imperative at that time. The second reason was to assure that funds expended in building an Alaskan pipeline would benefit domestic users rather than simply employed to facilitate shipments to other countries. The main objective of this report is to estimate the potential impacts on crude oil prices that would result from lifting the export ban Alaskan crude oil. The report focuses on the Japanese market and the US West Coast market. Japan is the principal potential export market for Alaskan crude oil. Exports to that market would also affect the price of Alaskan crude oil as well as crude oil and product prices on the West Coast and the volume of petroleum imported in that area. 3 figs., 8 tabs.

  20. Non-aqueous heavy oil extraction from oil sand

    Energy Technology Data Exchange (ETDEWEB)

    Bohnert, George [National Nuclear Security Administration (United States)

    2011-07-01

    The Kansas City plant operated by Honeywell has a long history of working with DOE NNSA on engineering and manufacturing services supporting national security requirements. The plant has developed a non-aqueous method for heavy oil extraction from oil sands. This method is environmentally friendly as it does not use any external body of water, which would normally be contaminated in the conventional method. It is a 2 phase process consisting of terpene, limonene or alpha pinene, and carbon dioxide. The CO2 and terpene phases are both closed loop systems which minimizes material loss. The limonene and alpha pinene are both naturally derived solvents that come from citrus sources or pine trees respectively. Carbon dioxide is an excellent co-solvent with terpene. There is also a possibility for heat loss recovery during the distillation phase. This process produces clean dry sand. Laboratory tests have concluded that this using non-aqueous liquids process works effectively.

  1. Heavy gas oils as feedstock for petrochemicals

    Energy Technology Data Exchange (ETDEWEB)

    Clark, P.D. [Nova Chemicals Ltd., Calgary, AB (Canada); Du Plessis, D. [Alberta Energy Research Inst., Edmonton, AB (Canada)]|[Alberta Economic Development and Trade, Edmonton, AB (Canada)

    2004-07-01

    This presentation reviewed the possibilities for converting heavy aromatic compounds and gas oils obtained from Alberta bitumen into competitively priced feedstock for high value refined products and petrochemicals. Upgrading bitumen beyond synthetic crude oil to refined products and petrochemicals would add value to bitumen in Alberta by expanding the petrochemical industry by providing a secure market for co-products derived from the integration of bitumen upgrading and refining. This presentation also reviewed conventional feedstocks and processes; by-products from bitumen upgrading and refining; production of light olefins by the fluid catalytic cracking (FCC) and hydrocracking process; deep catalytic cracking, catalytic pyrolysis and PetroFCC processes; technical and economic evaluations; and opportunities and challenges. Conventional feeds for steam cracking were listed along with comparative yields on feedstock. The use of synthetic gas liquids from oil sands plants was also reviewed. Current FCC type processes for paraffinic feedstocks are not suitable for Alberta's bitumen, which require better technologies based on hydrotreating and new ring opening catalysts. tabs., figs.

  2. Well performance relationships in heavy foamy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, R.; Mahadevan, J. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Tulsa Univ., Tulsa, OK (United States)

    2008-10-15

    The viscosities and thermodynamic properties of heavy oils are different from conventional oils. Heavy oil reservoirs have foamy behaviour and the gas/oil interface stabilizes in the presence of asphaltenes. In the case of conventional oils, gas evolves from the solution when the formation pressure reaches the bubble point pressure. This study modelled the fluid properties of heavy foamy oils and their influence on the inflow performance relationship (IPR). An expression for inflow performance in heavy oil was developed by including the properties of foamy oil into a space averaged flow equation assuming pseudo-steady state conditions. The unique feature of this study was that the density, formation volume factor and solution gas-oil ratio were modelled as functions of entrained gas fraction. The newly developed expression for inflow performance of foamy oils may also be used to model conventional oil inflow by setting the entrained gas fraction to zero in the fluid property models. The results of the inflow performance of foamy oil and conventional oil were compared and an outflow performance relationship was calculated. The study showed that the inflow performance in foamy oil is influenced by entrained gas. The surface flow rates and bottom-hole flow rates are also influenced by the presence of entrained gas, with heavy foamy oil showing a higher volumetric production rate than conventional oil. The outflow performance curve depended on the fluid properties of the foamy oil. A nodal analysis of the well performance showed that the conventional calculation methods underestimate the production from foamy oil wells because they do not consider the effect of entrained gas which lowers density and improves the mobility of foamy oil. 14 refs., 2 tabs., 20 figs., 1 appendix.

  3. The heavy oil refiners needs in the future

    International Nuclear Information System (INIS)

    Sauer, J.W.

    1991-01-01

    In the 1970s oil crisis, the high price differential that developed between heavy and light crude led to an expansion in heavy crude processing geared to producing light oil products. The subsequent collapse in prices meant that heavy crudes with low netbacks were shut in, heavy crude refining capacity exceeded the restrained production of heavy crudes, and refineries were operating at losses. However, the low prices for oil rekindled demand and spare production capacity has been absorbed. The crude oil price is forecast to rise to ca $27/bbl by the late 1990s, which is favorable for heavy crude oil production. Nevertheless, investments in heavy crude production are exposed to a high degree of risk. A strategy for dealing with this risk is to integrate into downstream, which makes more sense for heavy crude producers than for conventional producers. On the other hand, such integration is capital-intensive, and light oils will likely be favored in crude oil production developments for the next several years. Low prices for natural gas will make it hard to find markets for residual fuel made from heavy crudes. 8 figs

  4. Exports of petroleum products, 1987

    International Nuclear Information System (INIS)

    1988-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1987 calendar year. A discussion of petroleum product imports is included in order to put exports in the context of the overall trade. Exports of the above petroleum products averaged 22,200 m 3 /d in 1987, up 15% from 1986 levels. Exports of middle distillates and aviation fuel had the largest gains in 1987. Export prices for light petroleum products stayed relatively close to USA spot prices. The heavy fuel oil price was below the New York spot price in the beginning of 1987 but remained close for the rest of the year. Canada's petroleum products exports were made to 5 countries while imports came from at least 13 countries. The USA remained Canada's largest trading partner in petroleum products. Exports to Japan and the Far East rose ca 60% over 1986. Product outturns for export were 9% of total Canadian refinery throughput. Exports of aviation turbine fuel from Ontario began in April 1987. The top single exporter in Canada was Irving Oil Ltd. with 2,485,000 m 3 . Irving was also the top exporter in 1986. 11 figs., 4 tabs

  5. New heavy crude oil flow improver increases delivery : application scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, J.; Johnston, R.; Lauzon, P. [ConocoPhillips Specialty Products Inc., Houston, TX (United States)

    2009-07-01

    Flow improvers or drag reducing agents have been used for over 25 years as a method to increase fluid flow in hydrocarbon pipelines. The technology is effective in refined projects, light and medium crude oils. This paper presented a new development in flow improver technology that allows treatment of heavy crude oil slates. It discussed case studies of flow improver treatment of heavy oils in various pipeline system as well as factors that affect commercial success. tabs., figs.

  6. 1170-MW(t) HTGR-PS/C plant application study report: heavy oil recovery application

    International Nuclear Information System (INIS)

    Rao, R.; McMain, A.T. Jr.

    1981-05-01

    This report describes the application of a high-temperature gas-cooled reactor (HTGR) which operates in a process steam/cogeneration (PS/C) mode in supplying steam for enhanced recovery of heavy oil and in exporting electricity. The technical and economic merits of an 1170-MW(t) HTGR-PS/C are compared with those of coal-fired plants and (product) oil-fired boilers for this application. The utility requirements for enhanced oil recovery were calculated by establishing a typical pattern of injection wells and production wells for an oil field similar to that of Kern County, California. The safety and licensing issues of the nuclear plant were reviewed, and a comparative assessment of the alternative energy sources was performed. Technically and economically, the HTGR-PS/C plant has attractive merits. The major offsetting factors would be a large-scale development of a heavy oil field by a potential user for the deployment of a 1170-MW(t) HTGR-PS/C; plant and the likelihood of available prime heavy oil fields for the mid-1990 operation

  7. Research on heavy oil degradation by four thermophilic bacterial strains

    Energy Technology Data Exchange (ETDEWEB)

    Bao, M.; Chen, Q.; Liu, Z.; Li, Y. [Ocean Univ. of China, Qingdao, Shandong (China)

    2009-07-01

    The Shengli oilfield is the second largest onshore oil field in China, with a crude oil output of approximately 30 million tons per year. The large quantities of wastewater that are produced during thermal recovery methods have posed a challenge in terms of water reuse, reinjection and discharge. The important aspect of wastewater treatment is the removal of residual heavy oil. Biological methods are considered to be efficient in solving this problem. This paper reported on a study in which 4 thermophilic microorganisms which had the ability to biodegrade heavy oil were screened from heavy oil wastewater in the Shengli oilfield. Their degradation to heavy oil was discussed and the suitable biodegradation conditions of these bacteria were investigated. The study showed that the degrading efficiency of heavy oil by the 4 bacteria was up to 42.0, 47.6, 55.6 and 43.4 per cent in the wastewater which contained 500 mg per litre of heavy oil, respectively. The crude oil samples were analyzed using gas chromatography/flame ionization detection (GC/FID) and gas chromatography/mass spectrometry (GC/MS) before and after degradation. The single 4 strains demonstrated strong biodegradability to normal alkanes and aromatics, and the average degrading efficiency was about 50 and 35 per cent. The degrading efficiency of the mixed 4 strains was better than the single ones, particularly for the poor biodegradable hydrocarbons such as phenanthrenes and fluorines. 21 refs., 2 tabs., 17 figs.

  8. Global Integration, Non-Oil Export and Economic Growth in Nigeria

    Directory of Open Access Journals (Sweden)

    Ozoemena Stanley Nwodo

    2017-03-01

    Full Text Available This study focuses on global integration, non-oil export and economic growth in Nigeria. The direct and interaction effect of the both openness variables and non-oil export on economic growth in Nigeria is investigated using quarterly data from 1986-2014. For analysis, it uses one measures of financial openness: de facto (total capital flow variables following Aizenman and Noy (2009.and a measure of trade openness adopted by Okoh (2004. The study applies the Autoregressive Distributed Lag Model (ARDL. The results show positive impact of non-oil export on economic growth in Nigeria both in the short run and in the long run, negative effect of trade and financial openness on economic growth however, the result recorded a negative effect of the interaction of trade openness and non-oil export on economic growth and a positive effect of the interaction of financial openness and non-oil export on economic growth. Thus, the study recommends among others that government should get the fundamentals right in the economy first that will boost non-oil sector before opening the economy for trade.

  9. Tail dependence between oil and stocks of major oil-exporting countries using the CoVaR approach

    Directory of Open Access Journals (Sweden)

    Nader Trabelsi

    2017-12-01

    Full Text Available This paper investigates the negative tail risk dependence between oil shocks and stock indices (at aggregated and desegregated levels for Saudi Arabia (KSA, United Arab Emirates (UAE and Russia, over the period between 2007 and 2016. DCC-MGARCH approach and CoVaR measure are employed to assess the oil shock exposure. The results show that the tail dependence is significant and depends on the origin of the oil shocks, with intensity that varies across countries and sectors. Keywords: Oil price shocks, Oil-exporting countries, Conditional VaR, JEL Classification: C58, G11, Q4

  10. Testing Method of Degrading Heavy Oil Pollution by Microorganisms

    Science.gov (United States)

    Wu, Qi; Zhao, Lin; Ma, Aijin

    2018-01-01

    With the development of human society, we are more and more relying on the petrochemical energy. The use of petrochemical energy not only brings us great convenience, but is also accompanied by a series of environmental pollution problems, especially oil pollution. Since it is impractical to restore all pollution problems, the proper use of some remedial measures, under the guidance of functional orientation, may be sufficient to minimize the risk of persistent and diffusing pollutants. In recent years, bioremediation technology has been gradually developed into a promising stage and has played a crucial role in the degradation of heavy oil pollution. Specially, microbes in the degradation of heavy oil have made a great contribution. This paper mainly summarizes the different kinds of microorganisms for degrading heavy oil and the detection method for degradation efficiency of heavy oil pollution.

  11. Heavy oil : PetroChina's perspective

    Energy Technology Data Exchange (ETDEWEB)

    He, C. [PetroChina Co., Ltd., Beijing (China)

    2010-07-01

    This keynote presentation discussed China's future in relation to heavy oil refining. An overview of PetroChina's overseas operations was also presented. China currently has six 200,000 bpd refineries as well as an additional 12 refineries with a 100,000 bpd capacity that are able to process lower quality feedstocks with a high acid and sulphur content. Seven new 200,000 bpd refineries will be built by 2020. Poor and heavy crude oil from global heavy oil reserves will form a significant percentages of China's refinery feedstocks, and Canada is expected to provide a significant portion of its heavy oil and bitumen resources for further refining in China. China's existing refineries are being reconfigured and optimized for the processing of heavy crude oils. Additional hydrotreating and hydrocracking technologies have been added, and resid fluid catalytic cracking technologies have been retrofitted. China envisages a future with steady increases in oil consumption, high oil prices, and an increased reliance on heavy and poor quality crude oils. China's strong economic growth will increase demand for petrochemical feedstocks. Various research organizations and institutions have been established to accelerate innovation and technology development for ensuring that clean fuels standards are met. New refineries in China will include resid upgrading and new generation catalyst technologies. Details of various technologies were included. tabs., figs.

  12. Proceedings of the world heavy oil congress 2011

    International Nuclear Information System (INIS)

    2011-01-01

    The World Heavy Oil Congress 2011 took place March 2011 in Edmonton, Alberta, Canada. This congress is an international gathering of heavy oil experts and professionals which takes place every 18 months to discuss issues and opportunities facing the heavy oil industry in terms of commercial, technical, regulatory and geo-political areas. Innovative solutions for improving performance, reducing costs and mitigating environmental impacts are presented. Hundreds of presentations were made, courses were delivered, and over 100 companies from 30 countries exhibited. The congress had support from various companies and government entities.This conference featured 133 papers, all of have been catalogued separately for inclusion in this database.

  13. The properties of heavy oils and Orimulsion : another look

    International Nuclear Information System (INIS)

    Fingas, M.; Hollebone, B.; Wang, Z.; Smith, P.

    2003-01-01

    A comparison was made between the physical properties and behaviour indicators of several heavy oils, including Orimulsion. Most heavy oils are rich in resins, asphaltenes, heavy saturates and heavy aromatics and their behaviour may vary during spills due to their different densities. The authors examined the change in density with changes in weathering and temperature. The authors noted two phenomena associated with the behaviour of heavy oils in water, namely sinking and over-washing. Sinking was defined as the bulk sinking of oil to the bottom or an intermediate layer. Over-washing was described as the washing of a layer of water over dense oil at sea while the oil is still close to the surface. The problem with over-washing is that it is not always visible to observers from a ship. The authors briefly reviewed the literature on the topic of dense oil behaviour. To determine whether extensive weathering could render oils heavier than water, weathering experiments were performed on dense oils. Results showed that weathering is rarely a sole factor in the bulk sinking of oil. For the oil to sink after weathering, its density would have to be very close to that of water. Weathering studies have shown that little weathering occurs on sunken oil after it is submerged. The uptake of particulate matter is the most important process in increasing density. The authors also discussed sinking prediction equations and provided a mathematical description of the conditions required for oil to be covered by a layer of water. A summary of the dynamics of Orimulsion as measured in a test tank was also included. 21 refs., 3 tabs., 3 figs

  14. Heavy and Thermal Oil Recovery Production Mechanisms, SUPRI TR-127

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, Anthony R.; Brigham, William E.; Castanier, Louis M.

    2001-09-07

    The program spans a spectrum of topics and is divided into five categories: (i) multiphase flow and rock properties, (ii) hot fluid injection, (iii) primary heavy-oil production, (iv) reservoir definition, and (v) in-situ combustion.

  15. Early Decomposition of Retained Heavy Silicone Oil Droplets

    Directory of Open Access Journals (Sweden)

    Touka Banaee

    2012-01-01

    Full Text Available Purpose: To report a case of early decomposition of retained heavy silicone oil droplets. Case Report: The single highly myopic eye of a 16-year-old boy with history of scleral buckling and buckle revision developed redetachment due to inferior retinal dialysis. The patient underwent pars plana vitrectomy and injection of heavy silicone oil. Early emulsification of the silicone oil was observed following surgery, which was removed 4 weeks later in another operation. Retained heavy silicone droplets lost their heavier- than-water specific gravity within 2 months together with extensive iris depigmentation, and release of pigment granules into the anterior chamber and vitreous cavity. Conclusion: This case report demonstrates that heavy silicone oil droplets can undergo in vivo chemical decomposition with possible toxic effects on ocular tissues.

  16. Soil Remediation Demonstration Project: Biodegradation of Heavy Fuel Oils

    National Research Council Canada - National Science Library

    Reynolds, Charles

    1997-01-01

    .... Low-cost treatments applicable to small-scale spills are needed. The object of this CPAR project was to examine using cost-effective, on-site bioremediation techniques for heavy-oil-contaminated soil in cold regions...

  17. Energy consumption and economic growth: The case of oil exporting countries

    International Nuclear Information System (INIS)

    Mehrara, Mohsen

    2007-01-01

    This paper examines the causal relationship between the per capita energy consumption and the per capita GDP in a panel of 11 selected oil exporting countries by using panel unit-root tests and panel cointegration analysis. The results show a unidirectional strong causality from economic growth to energy consumption for the oil exporting countries. The findings have practical policy implications for decision makers in the area of macroeconomic planning. In most major oil exporting countries, government policies keep domestic prices bellow free market level, resulting in high levels of domestic energy consumption. The results imply that the energy conservation through reforming energy price policies has no damaging repercussions on economic growth for this group of countries. (author)

  18. SOVENT BASED ENHANCED OIL RECOVERY FOR IN-SITU UPGRADING OF HEAVY OIL SANDS

    Energy Technology Data Exchange (ETDEWEB)

    Munroe, Norman

    2009-01-30

    With the depletion of conventional crude oil reserves in the world, heavy oil and bitumen resources have great potential to meet the future demand for petroleum products. However, oil recovery from heavy oil and bitumen reservoirs is much more difficult than that from conventional oil reservoirs. This is mainly because heavy oil or bitumen is partially or completely immobile under reservoir conditions due to its extremely high viscosity, which creates special production challenges. In order to overcome these challenges significant efforts were devoted by Applied Research Center (ARC) at Florida International University and The Center for Energy Economics (CEE) at the University of Texas. A simplified model was developed to assess the density of the upgraded crude depending on the ratio of solvent mass to crude oil mass, temperature, pressure and the properties of the crude oil. The simplified model incorporated the interaction dynamics into a homogeneous, porous heavy oil reservoir to simulate the dispersion and concentration of injected CO2. The model also incorporated the characteristic of a highly varying CO2 density near the critical point. Since the major challenge in heavy oil recovery is its high viscosity, most researchers have focused their investigations on this parameter in the laboratory as well as in the field resulting in disparaging results. This was attributed to oil being a complex poly-disperse blend of light and heavy paraffins, aromatics, resins and asphaltenes, which have diverse behaviors at reservoir temperature and pressures. The situation is exacerbated by a dearth of experimental data on gas diffusion coefficients in heavy oils due to the tedious nature of diffusivity measurements. Ultimately, the viscosity and thus oil recovery is regulated by pressure and its effect on the diffusion coefficient and oil swelling factors. The generation of a new phase within the crude and the differences in mobility between the new crude matrix and the

  19. The rapid growth of domestic oil consumption in Saudi Arabia and the opportunity cost of oil exports foregone

    International Nuclear Information System (INIS)

    Gately, Dermot; Al-Yousef, Nourah; Al-Sheikh, Hamad M.H.

    2012-01-01

    We analyze the rapid growth of Saudi Arabia's domestic oil consumption, a nine-fold increase in 40 years, to nearly 3 million barrels per day, about one-fourth of production. Such rapid growth in consumption – 5.7% annually, which is 37% faster than its income growth of 4.2% – will challenge Saudi Arabia's ability to increase its oil exports, which are relied upon in long-term world oil projections by the International Energy Agency (IEA), US Department of Energy (DOE) and British Petroleum (BP). However, these institutions assume unprecedented slowdowns in Saudi oil consumption – from 5.7% annual growth historically to less than 2% in the future – allowing them to project increases in Saudi oil exports. Using 1971–2010 data, we estimate that the income responsiveness (elasticity) of oil consumption is at least 1.5—using both Ordinary Least Squares regression and Cointegration methods. We believe that continued high growth rates for domestic oil consumption are more likely than the dramatic slowdowns projected by IEA, DOE and BP. This will have major implications for Saudi production and export levels. - Highlights: ► We analyze the rapid growth of Saudi Arabia's domestic oil consumption, now one-fourth of production. ► Estimated income elasticity of oil demand at least 1.5, using OLS and Co-integration. ► Yet IEA, DOE and BP project unprecedented slowdowns, from 5.7% historically to below 2%, half the rate of income growth. ► Continued high growth rates are more likely, with major implications for Saudi production and export levels.

  20. The PTRC : a world leader in enhanced heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Kristoff, B.; Knudsen, R.; Asghari, K. [Petroleum Technology Research Centre, Regina, SK (Canada); Pappas, E.S. [Saskatchewan Research Council, Saskatoon, SK (Canada)

    2006-07-01

    The Petroleum Technology Research Centre (PTRC) fosters knowledge and progressive technologies to enhance the recovery of petroleum. This paper discussed the PTRC's leadership in enhanced heavy oil recovery, with particular reference to core research program such as heavy oil (post) cold flow; enhanced waterflooding; miscible/immiscible solvent injection; and near-wellbore conformance control. Other projects that were presented included a joint implementation of vapour extraction project (JIVE); and the IEA greenhouse gas (GHG) Weyburn-Midale carbon dioxide monitoring and storage project. The JIVE project will develop, demonstrate and evaluate solvent vapour extraction processes for enhanced oil recovery in heavy oil reservoirs. The GHG Weyburn-Midale project, launched in 2000, studies carbon dioxide injection and storage in partially depleted oil reservoirs. It was concluded that the PTRC continues to develop technologies to meet the world's energy requirements while mitigating both immediate and long-term environmental impacts. 4 figs.

  1. Government and industry roles in heavy oil resource development

    International Nuclear Information System (INIS)

    Sharp, D.A.

    1994-01-01

    Developing a heavy oil deposit in Canada requires proper reservoir selection and ongoing resrvoir management. The number of unexploited heavy oil reservoirs whch can be economically produced through primary methods is rapidly declining. In addition, primary recoveries of 5-10% of the heavy oil in place are unacceptable and recovery rates of over 50% are needed. Enhanced thermal recovery projects are therefore needed, but these entail significant technical and commodity pricing risks. It is suggested that provincial governments recognize those risks and offer incentives by not encumbering such projects with up-front royalties. If industry is to assume the risks, governments must develop a fiscal regime that allows for a satisfactory return on capital and acceptable sharing of profits. At the federal level, it is suggested to broaden the interpretation of research and development activity to include enhanced recovery projects, making the tax breaks available to scientific research also available to heavy oil development. Government policies favoring heavy oil in Saskatchewan and Alberta are cited as good examples of ways to encourage the heavy oil industry

  2. Assessment and bioremediation of heavy metals from crude oil ...

    African Journals Online (AJOL)

    The assessment of the levels of heavy metals present in crude oil contaminated soil and the application of the earthworm - Hyperiodrilus africanus with interest on the bioremediation of metals from the contaminated soil was investigated within a 90-days period under laboratory conditions. Selected heavy metals such as ...

  3. Extraction of heavy oil by supercritical carbon dioxide

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Spirov, Pavel; Søgaard, Erik Gydesen

    2010-01-01

    The present study deals with the extraction of heavy oil by supercritical carbon dioxide at the pressure values changing from 16 to 56 MPa at the fixed value of temperature: 60oC. The amount of the recovered liquid phase of oil was calculated as a percentage of the extracted amount to the initial...... 40 gm of oil. The noticeable breackover point in the graph of the oil recovery versus pressure was observed at 27 MPa, which was in concordance with the conclusions from chromatographic analysis of the extracted oil samples. But the recovery rate of 14 % at this pressure value was not high enough...

  4. An economic Manifesto for the oil exporting countries of the Persian Gulf

    Directory of Open Access Journals (Sweden)

    Hossein Askari

    2006-12-01

    Full Text Available The oil-exporting countries of the Persian Gulf have failed economically and socially. It is time for a radical new approach to managing oil revenues while oil and gas reserves last. We propose an approach to cut the level of oil revenues available to governments to zero while incorporating a formal “Oil Fund for All Generations”. Others have proposed and implemented oil funds but in our proposal the government would (in time lose all access to oil revenues; by taking easy money away from governments and rulers, the likelihood of waste, corruption and wars will be reduced, and there will be better chance of adopting and implementing rational economic policies to enhance equity across generations.

  5. Heavy crude oil and synthetic crude market outlook

    International Nuclear Information System (INIS)

    Crandall, G.R.

    1997-01-01

    This presentation included an outline of the international heavy crude supply and demand versus Canadian heavy crude supply and disposition, and pricing outlook for synthetic crudes. Differences among crude oils such as light sweet, light sour, heavy and bitumen were described and illustrated with respect to their gravity, API, percentage of sulphur, metals and nitrogen. Internationally, heavy and sour crude supplies are forecast to increase significantly over the next four years. Discoveries of light sour crude in offshore Gulf of Mexico will provide a major new source of sour crude to U.S. Gulf Coast refineries. Venezuela's supplies of heavy and sour crude are also expected to increase over the next few years. Mexico and Canada have plans to increase their heavy crude production. All of the crudes will be aimed at the U.S. Gulf Coast and Midwest markets. Pentanes and condensates are also expected to increase based on the growing Canadian natural gas production. Diluent demand will also grow to match Canadian heavy crude/bitumen production. U.S. midwest refiners are proposing expansions to allow them to process more Canadian heavy crude oil. At present, only a few refineries are equipped to process significant amounts of synthetic crude. It was suggested that to absorb available heavy and synthetic production, increased penetration into both Canadian and U.S. markets will be required. Some refineries may have to be modified to process heavy and synthetic oil supplies. Heavy oil and synthetic producers may need to develop relationships with refiners such as joint ventures and term supply agreements to secure markets. 2 tabs., 12 figs

  6. The political role of national oil companies in the large exporting countries : the Venezuela case

    International Nuclear Information System (INIS)

    Mommer, B.

    1994-01-01

    This paper starts by defining the role of mining companies vis-a vis the landlords in a modern economy. Then it examines the role international oil companies played in exporting countries. Finally the role of national oil companies is analyzed following the same scheme : what is their contribution to the development of a new landlord-tenant relationship, nationally and internationally ? ''Petroleos de Venezuela'' is taken as an example. (Author). 27 refs

  7. AFM annual report 1983 (Petroleum Industry). [Export Federation for Mineral Oil, Federal Republic of Germany]. AFM Jahresbericht 1983

    Energy Technology Data Exchange (ETDEWEB)

    1983-01-01

    The annual report 1983 of the Export Federation for Mineral Oil (AFM) contains informations about the mineral oil economics, the market development for selected main products and the environmental protection. The AFM terms (standard conditions for barge transactions) for the mineral oil industry are given. The AFM Oil Market Report Daily has extended the frame of its reports in 1983.

  8. HEAVY-OIL PRODUCTION USING EMULSION FLOODING

    African Journals Online (AJOL)

    user

    ... American Petroleum Institute, EOR = Enhanced Oil Recovery, GOR = Gas Oil Ratio ... concentration, 166.003 is the constant (molar mass of ... (molar mass of CaCO3),1M is the constant value. ... volume of prepared oil-in-water emulsion, that.

  9. Statistical properties of country risk ratings under oil price volatility: Evidence from selected oil-exporting countries

    International Nuclear Information System (INIS)

    Liu, Chang; Sun, Xiaolei; Chen, Jianming; Li, Jianping

    2016-01-01

    This paper focuses on the application of panel models for identification and analysis of influence of oil price volatility on statistical properties of country risk ratings which stem from uncertainty of macroeconomic fluctuations. Firstly, two statistical properties of country risk ratings, volatility clustering and asymmetrical revision were identified in a theoretical framework based on Cruces (2006). Secondly, considering the oil price volatility, numerical experiments were conducted based on extended models to test and verify specific properties of country risk ratings in selected oil-exporting countries. Empirical results suggest that properties of country risk remain comparatively steady despite oil price volatility. It is also found that the oil price volatility can obviously exaggerate the country risk volatility, as it happened during 2007–2009. Country clustering based on the properties of country risk ratings shows that the selected countries maintain a significant clustering tendency. These features are of great importance for estimating risk exposure of international trade and investments in oil export during extreme situations. - Highlights: •Relationship between oil price volatility and country risk is the focus. •An extended model based on Cruces (2006) is proposed. •Volatility clustering and asymmetrical revision of country risk ratings is explored. •Oil price volatility can obviously exaggerate properties of country risk volatility.

  10. Air toxics from heavy oil production and consumption

    International Nuclear Information System (INIS)

    Lipfert, F.W.; DePhillips, M.P.; Moskowitz, P.D.

    1992-01-01

    This report assesses the potential impact of recent Federal and state regulations for airborne toxic substances on the production and consumption of heavy fuel oils. Emissions of nickel from heavy oil production in California are considered in some detail, in conjunction with California state regulations for toxic emissions. Although the use of thermal energy from heavy crude oils could in theory be impacted by toxic air pollution regulations, recent trends towards the use of natural gas for the required extraction energy appear to provide substantial relief, in addition to reducing emissions of criteria air pollutants. However, the consumption of residual fuel oils containing toxic metals could result in higher population exposures to these substances and their attendant risks may be worthy of more detailed analysis

  11. Proceedings of the heavy oil Latin America congress 2011

    International Nuclear Information System (INIS)

    2011-01-01

    This conference brought experts together to explore the challenges faced and opportunities available in the dynamic emerging market for heavy oil which Latin America offers. The conference was attended by over 700 delegates from around the world representing official and private agencies, Latin American governments, national oil companies and service companies in heavy oil producing countries. These participants were given the opportunity to learn about the entire value chain of Latin America's heavy oil industry, with emphasis on balancing challenging environmental and social issues with operational best practices, and they also the opportunity to share their knowledge and expertise with their peers. 17 of the 29 papers presented during this conference have been catalogued separately for inclusion in this database.

  12. The density behaviour of heavy oils in water

    International Nuclear Information System (INIS)

    Fingas, M.; Hollebone, B.; Fieldhouse, B.

    2006-01-01

    The recent concern regarding the difficulty of cleaning up Low API gravity oils (LAPIO) spilled in water was discussed. Sinking and overwashing are 2 phenomena related to the behaviour of these heavy oils in water. Sinking refers to the complete submergence of the oil to the bottom of a waterbody, while over-washing refers to the overflowing of a layer of water over dense oil at sea when the oil is still close to the surface. The latter is important because even a micron-layer of water could render the oil undetectable, particularly at acute viewing angles, such as from a ship. This paper reviewed the properties of heavy oil, the prediction of density changes and the sinking/over-washing of heavy oil. In particular, it discussed a spill which occurred in August 2005 when 11 tank cars from train derailment spilled 800,000 litres of Bunker fuel mixed with high PAH-containing pole-treating oil into Lake Wabamun, Alberta. The behaviour of the oil included submergence, neutral buoyancy, resurfacing and formation of several types of aggregates of oil. This study summarized the behaviours and processes that transformed the particles of oil into small tar balls, larger logs, sheets, and large lumps into a slick. Sediment uptake or loss was found to be the major process that caused the changes in density. The behaviour of the oils was compared with respect to density and uptake of various types of sediment. The paper also reviewed the literature on dense oil behaviour. Weathering experiments performed on dense oils to determine if extensive weathering could render oils heavier than water showed that rarely is weathering the only factor in the bulk sinking of oil. Once an oil is submerged, little weathering occurs, either by dissolution or volatilization. The uptake of particulate matter is the most important process in increasing density. This study reviewed over-washing experiments to develop a mathematical solution of the conditions required for oil to be covered by a

  13. Press freedom, oil exports, and risk for natural disasters: a challenge for climato-economic theory?

    Science.gov (United States)

    Arantes, Joana; Grace, Randolph C; Kemp, Simon

    2013-10-01

    Does the interaction between climactic demands, monetary resources, and freedom suggest a more general relationship between the environmental challenges that human societies face and their resources to meet those challenges? Using data on press freedom (Van de Vliert 2011a), we found no evidence of a similar interaction with natural resources (as measured by oil exports) or risk for natural disasters.

  14. Placing Brazil's heavy acid oils on international markets

    International Nuclear Information System (INIS)

    Szklo, Alexandre Salem; Machado, Giovani; Schaeffer, Roberto; Felipe Simoes, Andre; Barboza Mariano, Jacqueline

    2006-01-01

    This paper identifies the international market niches of Brazil's heavy acid oils. It analyzes the perspectives for making wider use of heavy acid oils, assessing their importance for certain oil-producing regions such as Brazil, Venezuela, West Africa, the North Sea and China. Within this context, the oil produced in the Marlim Field offshore Brazil is of specific interest, spurred by the development of its commercial brand name for placement on international markets and backed by ample production volumes. This analysis indicates keener international competition among acid oils produced in Brazil, the North Sea and the West Coast of Africa, through to 2010. However, over the long term, refinery conversion capacity is the key factor for channeling larger volumes of heavy acid oils to the international market. In this case, the future of acid oil producers will depend on investments in refineries close to oil product consumption centers. For Brazil, this means investments in modifying its refineries and setting up partnerships in the downstream segment for consumer centers absorbing all products of high added value, such as the USA and even Southeast Asia and Western Europe

  15. Structural Study of Asphaltenes from Iranian Heavy Crude Oil

    Directory of Open Access Journals (Sweden)

    Davarpanah L.

    2015-11-01

    Full Text Available In the present study, asphaltene precipitation from Iranian heavy crude oil (Persian Gulf off-shore was performed using n-pentane (n-C5 and n-heptane (n-C7 as light alkane precipitants. Several analytical techniques, each following different principles, were then used to structurally characterize the precipitated asphaltenes. The yield of asphaltene obtained using n-pentane precipitant was higher than asphaltene precipitated with the use of n-heptane. The asphaltene removal affected the n-C5 and n-C7 maltene fractions at temperatures below 204°C, as shown by the data obtained through the simulated distillation technique. Viscosity of heavy oil is influenced by the asphaltene content and behavior. The viscosity dependence of the test heavy oil on the shear rate applied was determined and the flow was low at y. above 25 s-1 . The reconstituted heavy oil samples were prepared by adding different amounts of asphaltenes to the maltenes (deasphalted heavy oil and asphaltene effects were more pronounced at the low temperature of 25°C as compared with those at the higher temperatures. According to the power law model used in this study the flowability of the test heavy oil exhibited a pseudoplastic character. Structural results obtained from Fourier Transform InfraRed (FTIR spectroscopy showed the presence of the different functional groups in the precipitated asphaltenes. For instance, the presence of different hydrocarbons (aliphatic, aromatic and alicyclic based on their characteristics in the FTIR spectra was confirmed. Resins are effective dispersants, and removal of this fraction from the crude oil is disturbing to the colloidal nature of heavy oil; asphaltene flocculation and precipitation eventually occur. Appearance of pores in the Scanning Electron Microscopy (SEM images was used as an indicator of the resin detachment. With the use of 1H and 13C Nuclear Magnetic Resonance (NMR spectroscopy, two important structural parameters of the

  16. Exports of petroleum products, 1988

    International Nuclear Information System (INIS)

    1989-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1988 calendar year. A discussion of petroleum product imports is included in order to put exports in the context of the overall trade. Exports of the above petroleum products averaged 32,000 m 3 /d in 1988, up 44% from 1987 levels. Each product except aviation fuel registered increases in export volumes, which reached the highest total volume of the decade. The main reason for the large increase was the first full year of production from the export-directed refinery at Come By Chance, Newfoundland. Export prices for light petroleum products stayed relatively close to USA spot prices. The heavy fuel oil price was mostly above the USA east coast spot price during 1988. Attractive prices on the USA east coast resulted in a few cargoes of middle distillate and motor gasoline shipped from British Columbia. Petroleum products imports came from 12 countries; Quebec had the largest volume of imports in 1988. The USA remained Canada's largest trading partner in petroleum products. Western exporters view the Far East as an ongoing important market. The top single exporter in Canada was Newfoundland Processing, with 32% of the total export volume. 12 figs., 3 tabs

  17. Floating Heavy Oil Recovery: Current State Analysis

    Science.gov (United States)

    2006-07-27

    recovered oil to a chute cause some build-up of oil, but the retained amount was not considered substantial enough to warrant any design changes. The GT...unit was the Lamor Brush Conveyor (shown in Figure 7) which uses a yellow V- brush design to recover oils and uses a propeller to draw water through...deals with the transfer of product that has already been collected and contained (Moffatt et al., 2004). The Coast Guard Research and Development

  18. Oil-field equipment in Romania. Export trade information

    International Nuclear Information System (INIS)

    Tinis, R.

    1991-09-01

    The Industry Sector Analyses (I.S.A.) for oil field equipment contains statistical and narrative information on projected market demand, end-users, receptivity of Romanian consumers to U.S. products, the competitive situation - Romanian production, total import market, U.S. market position, foreign competition, and competitive factors, and market access - Romanian tariffs, non-tariff barriers, standards, taxes and distribution channels. The I.S.A. provides the United States industry with meaningful information regarding the Romanian market for oil field equipment

  19. Tweens demulsification effects on heavy crude oil/water emulsion

    Directory of Open Access Journals (Sweden)

    Nastaran Hayati Roodbari

    2016-09-01

    Full Text Available The demulsification role of Tweens (nonionic polymers was determined in the separation of water from heavy crude oil emulsion. According to the previous researches, these nonionic polymers, having hydrophilic and lipophilic groups, are appropriate for making oil in water emulsion. In this research their effects in certain concentrations on demulsifying of water in crude oil emulsion were proved. High molecular weight, alkenes’ chains and groups of ketone and ester in these polymers can improve their performance for the demulsification of water in crude oil emulsion. Their efficiencies are improved with electronegative groups such as oxygen. They leave no corrosion effect because they are neutral and do not leave counter ions.

  20. Should you trust your heavy oil viscosity measurement?

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, L.; Miller, K.; Almond, R. [Petrovera Resources Ltd., Edmonton, AB (Canada)

    2003-07-01

    For the last 60 years, the heavy oil and bitumen reservoirs from western Canada have been exploited with varying degrees of success. There are many factors that may effect heavy oil and bitumen production rates. Primary production rates, which vary greatly from field to field, were found to improve with the addition of steam. Viscosity is the single most valued criteria in predicting cold production response from a new field. It is also the criteria used to determine whether thermal process are needed to reduce oil viscosity, or whether horizontal or vertical wells should be used. This study examined why production forecasts based on oil viscosity alone have been poor. It is based on an extensive data collection project in the Elk Point area reservoir which has lower than expected and erratic cold production rates. Viscosity values from the same wells were found to vary by a factor of four or more. One of the objectives of this study was to encourage commercial labs to develop an industry-wide standard method of heavy oil sample cleaning and viscosity measurement. It is generally understood that viscosity increases with an increase in the concentration of asphaltenes, but there is little information to quantify the relationship. Some studies suggest that viscosity increases logarithmically with increasing asphaltenes. It was concluded that the prediction of the viscosity of heavy oils and bitumens is very empirical, but there are ways to improve data comparisons and evaluation by applying available information from other scientific fields. 23 refs., 5 tabs., 6 figs.

  1. Exchange rate of the US dollar and the J curve: the case of oil exporting countries

    International Nuclear Information System (INIS)

    Yousefi, A.; Wirjanto, T.S.

    2003-01-01

    This study examines the effects of changes in the exchange rate of the US dollar on the trade balances of three oil-exporting countries, namely Iran, Venezuela and Saudi Arabia. An exchange rate pass-through model is applied to allow changes in the exchange rate of the dollar to affect prices of traded goods. Then, the impact of changes in prices on the quantities of imports and exports of these economies is estimated. The results suggest a partial exchange rate pass-through to these countries' import and export prices in terms of the US dollar. While the three countries raise the price of their primary export (namely crude oil) in response to a depreciation of the dollar, Saudi Arabia's long-run pricing strategy in securing a larger market share stands in contrast to that of the two other OPEC members. The sum of the estimated long-run price elasticities of demand for imports and exports is found to exceed unity for Iran and Venezuela, but less than unity for Saudi Arabia. (author)

  2. Exchange rate of the US dollar and the J curve. The case of oil exporting countries

    International Nuclear Information System (INIS)

    Yousefi, Ayoub; Wirjanto, Tony S.

    2003-01-01

    This study examines the effects of changes in the exchange rate of the US dollar on the trade balances of three oil-exporting countries, namely Iran, Venezuela and Saudi Arabia. An exchange rate pass-through model is applied to allow changes in the exchange rate of the dollar to affect prices of traded goods. Then, the impact of changes in prices on the quantities of imports and exports of these economies is estimated. The results suggest a partial exchange rate pass-through to these countries' import and export prices in terms of the US dollar. While the three countries raise the price of their primary export (namely crude oil) in response to a depreciation of the dollar, Saudi Arabia's long-run pricing strategy in securing a larger market share stands in contrast to that of the two other OPEC members. The sum of the estimated long-run price elasticities of demand for imports and exports is found to exceed unity for Iran and Venezuela, but less than unity for Saudi Arabia

  3. Oil price shocks: Sectoral and dynamic adjustments in a small-open developed and oil-exporting economy

    International Nuclear Information System (INIS)

    Dissou, Yazid

    2010-01-01

    The recent uptrend in oil prices represents both an opportunity and a challenge for small-open developed and oil-exporting countries. Using Canada as a study case and in contrast to most studies that use aggregate models, this paper employs a multi-sector, intertemporal general equilibrium model to provide perspectives on the sectoral, aggregate and dynamic adjustments of a sustained increase in oil prices. It highlights the transmission channels through which the rise in oil prices affects the domestic economy. The simulation results suggest that the shock would have positive aggregate impacts, but would also spur the reallocation of resources and would therefore induce disparities in sectoral adjustments. The suggested contraction in some industries could not however be attributed to a pure Dutch disease phenomenon because of, among other factors, the cost-push effect induced by the increase in oil prices.

  4. Injection of heavy fuel oil into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Paloposki, T. [Helsinki Univ. of Technology, Otaniemi (Finland); Hakala, J.; Mannila, P.; Laukkanen, J. [Oulu Univ. (Finland)

    1996-12-31

    This study deals with the injection and combustion of heavy fuel oil in blast furnaces. The injection of the oil was studied experimentally in a small-scale test rig. The combustion of the oil was analysed with a commercial computer program for flow and combustion simulations. Results from computer simulations show that the combustion of the oil can be improved by decreasing the size of the oil drops and by enhancing the mixing between the oil drops and the hot blast. The devolatilization rate of the oil mainly depends on the size of the oil drops. The combustion rate of the volatiles mainly depends on the effectiveness of turbulent mixing with combustion air. Methods to decrease the size of the oil drops were sought in the experimental part of the study. Experimental results show that the size of the oil drops increases with increasing mass flow rate of the oil and decreases with increasing velocity of the hot blast. Methods to improve the mixing between the oil drops and the hot blast are suggested but have not yet been experimentally tested. (author) (4 refs.)

  5. Injection of heavy fuel oil into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Paloposki, T [Helsinki Univ. of Technology, Otaniemi (Finland); Hakala, J; Mannila, P; Laukkanen, J [Oulu Univ. (Finland)

    1997-12-31

    This study deals with the injection and combustion of heavy fuel oil in blast furnaces. The injection of the oil was studied experimentally in a small-scale test rig. The combustion of the oil was analysed with a commercial computer program for flow and combustion simulations. Results from computer simulations show that the combustion of the oil can be improved by decreasing the size of the oil drops and by enhancing the mixing between the oil drops and the hot blast. The devolatilization rate of the oil mainly depends on the size of the oil drops. The combustion rate of the volatiles mainly depends on the effectiveness of turbulent mixing with combustion air. Methods to decrease the size of the oil drops were sought in the experimental part of the study. Experimental results show that the size of the oil drops increases with increasing mass flow rate of the oil and decreases with increasing velocity of the hot blast. Methods to improve the mixing between the oil drops and the hot blast are suggested but have not yet been experimentally tested. (author) (4 refs.)

  6. Comparative analysis of fiscal terms for Alberta oil sands and international heavy and conventional oils

    International Nuclear Information System (INIS)

    Van Meurs, P.

    2007-01-01

    There are considerable differences between international heavy oil and Alberta oil sands projects, notably the high viscosity of the bitumen in the oil sands reservoirs. The oil sands bitumen do not flow to wells without heating the bitumen, thereby adding to the already high cost of Alberta oil sand operations. This report provided an economic comparison of Alberta oil sands and international heavy oil projects. It also included a brief scoping review to compare with conventional oil regimes. Full exploration costs including the costs of dry holes were allocated to conventional oil operations in order to obtain a proper comparison. This investigation included the costs of dry holes. The report was a follow up to an earlier study released on April 12, 2007 on the preliminary fiscal evaluation of Alberta oil sand terms. The report provided an economic framework and described project selection. It then provided a discussion of production, costs and price data. Four adjusted projects were presented and compared with Alberta. The Venezuelan royalty formula was also discussed. Last, the report provided a detailed fiscal analysis. Comparisons were offered with Cold Lake and Athabasca Mine. A review of some other fiscal systems applicable to conventional oil were also outlined. It was concluded that Alberta oil sands developments are very competitive. It would be possible to modestly increase government revenues, without affecting the international competitive position of Alberta with respect to conventional oil. There is also some possibility to increase the base royalty on the Alberta oil sands without losing competitiveness. tabs., figs

  7. Viscous fingering effects in solvent displacement of heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Cuthiell, D. [Suncor Energy, Fort McMurray, AB (Canada); Kissel, G.; Jackson, C.; Frauenfeld, T.W.J.; Fisher, D. [Alberta Research Council, Devon, AB (Canada); Rispler, K. [Saskatchewan Research Council, Saskatoon, SK (Canada)

    2004-07-01

    Vapour Extraction (VAPEX) is a solvent-based process that is analogous to steam-assisted gravity drainage (SAGD) for the recovery of heavy oil. A cyclic solvent process is preferred for thin reservoirs, particularly primary-depleted reservoirs. In a cyclic steam stimulation process, a solvent is injected into the reservoir for a period of time before oil is produced from the well. Viscous fingering is a phenomena that characterizes several solvent-based processes for the recovery of heavy oil. A combined experimental and simulation study was conducted to characterize viscous fingering under heavy oil recovery conditions (high ratio of oil to solvent viscosity). Four experiments were conducted in heavy oil-saturated sand packs. Three involved injection of a miscible, liquid solvent at the bottom of the sand pack. The heavy oil in these experiments was displaced upwardly. The fourth experiment involved top-down injection of a gaseous solvent. The miscible liquid displacement was dominated by one solvent finger which broke through to a producing well at the other end of the sand pack. Breakthrough times were similar to that at lower viscosity. The fourth experiment showed fingering along with features of a gravity-driven VAPEX process. Key features of the experiment and realistic fingering patterns were numerically simulated using a commercial reservoir simulator. It was emphasized that accurate modelling of dispersion is necessary in matching the observed phenomena. The simulations should include the capillary effects because of their significance for gaseous fingering and the VAPEX processes. 17 refs., 2 tabs., 20 figs.

  8. The case for a large heavy oil stream

    International Nuclear Information System (INIS)

    Reimer, P.

    2005-01-01

    EnCana Corporation markets significant proprietary and third party crude oil production in North America. This presentation presented details of EnCana's projected resources as well as estimated proved reserves in Canadian oil sands. Details of the Western Canadian heavy oil market were presented. Issues concerning Western Canadian Select (WCS) were also presented, including details of distillation and asphalt characteristics. Details of the WCS synthetic bitumen synergy were examined, as well as quality management issues. It was suggested that further optimization of WCS facilities include reduced operating complexity; less tank proliferation; delivery quality consistency; and reliability. WCS refiner advantages were also evaluated. Shipping and ramping details were discussed, along with growth potential. It was noted that WCS satisfies all the criteria for a benchmark crude. It was concluded that the case for a large Canadian heavy oil stream includes reduced operating complexity; optimized logistics; delivery quality consistency; improved stream liquidity; and enhanced price discovery. tabs., figs

  9. Down-hole catalytic upgrading of heavy crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Weissman, J.G.; Kessler, R.V.; Sawicki, R.A.; Belgrave, J.D.M.; Laureshen, C.J.; Mehta, S.A.; Moore, R.G.; Ursenbach, M.G. [University of Calgary, Calgary, AB (Canada). Dept. of Chemical and Petroleum Engineering

    1996-07-01

    Several processing options have been developed to accomplish near-well bore in-situ upgrading of heavy crude oils. These processes are designed to pass oil over a fixed bed of catalyst prior to entering the production well, the catalyst being placed by conventional gravel pack methods. The presence of brine and the need to provide heat and reactant gases in a down-hole environment provide challenges not present in conventional processing. These issues were addressed and the processes demonstrated by use of a modified combustion tube apparatus. Middle-Eastern heavy crude oil and the corresponding brine were used at the appropriate reservoir conditions. In-situ combustion was used to generate reactive gases and to drive fluids over a heated sand or catalysts bed, simulating the catalyst contacting portion of the proposed processes. The heavy crude oil was found to be amenable to in-situ combustion at anticipated reservoir conditions, with a relatively low air requirement. Forcing the oil to flow over a heated zone prior to production results in some upgrading of the oil, as compared to the original oil, due to thermal effects. Passing the oil over a hydroprocessing catalyst located in the heated zone results in a product that is significantly upgraded as compared to either the original oil or thermally processed oil. Catalytic upgrading is due to hydrogenation and the results in about a 50% sulfur removal and an 8{degree} API gravity increase. Additionally, the heated catalyst was found to be efficient at converting CO to additional H{sub 2}. While all of the technologies needed for a successful field trial of in-situ catalytic upgrading exist, a demonstration has yet to be undertaken. 27 refs., 5 figs., 5 tabs.

  10. Influence of Oil Viscosity on Alkaline Flooding for Enhanced Heavy Oil Recovery

    Directory of Open Access Journals (Sweden)

    Yong Du

    2013-01-01

    Full Text Available Oil viscosity was studied as an important factor for alkaline flooding based on the mechanism of “water drops” flow. Alkaline flooding for two oil samples with different viscosities but similar acid numbers was compared. Besides, series flooding tests for the same oil sample were conducted at different temperatures and permeabilities. The results of flooding tests indicated that a high tertiary oil recovery could be achieved only in the low-permeability (approximately 500 mD sandpacks for the low-viscosity heavy oil (Zhuangxi, 390 mPa·s; however, the high-viscosity heavy oil (Chenzhuang, 3450 mPa·s performed well in both the low- and medium-permeability (approximately 1000 mD sandpacks. In addition, the results of flooding tests for the same oil at different temperatures also indicated that the oil viscosity put a similar effect on alkaline flooding. Therefore, oil with a high-viscosity is favorable for alkaline flooding. The microscopic flooding test indicated that the water drops produced during alkaline flooding for oils with different viscosities differed significantly in their sizes, which might influence the flow behaviors and therefore the sweep efficiencies of alkaline fluids. This study provides an evidence for the feasibility of the development of high-viscosity heavy oil using alkaline flooding.

  11. Directions in refining and upgrading of heavy oil and bitumen

    International Nuclear Information System (INIS)

    Dawson, B.; Parker, R. J.; Flint, L.

    1997-01-01

    The expansion of heavy oil transportation, marketing and refining facilities over the past two decades have been reviewed to show the strides that several Canadian refiners have taken to build up the facilities required to process synthetic crude oil (SCO). Key points made at a conference, convened by the National Centre for Upgrading Technology (NCUT), held in Edmonton during September 1997 to discuss current and future directions in the refining and marketing of heavy oil, bitumen and SCO, were summarized. Among the key points mentioned were: (1) the high entry barriers faced by centralized upgraders, (2) the advantages of integrating SCO or heavy oil production with downstream refining, (3) the stiff competition from Venezuela and Mexico that both SCO and heavy oil will face in the U.S. PADD II market, (4) the differences between Canadian refiners who have profited from hydrocracking and are better able to handle coker-based SCO, and American refiners who rely chiefly on catalytic cracking and are less able to process the highly aromatic SCO, and (5) the disproportionate cost in the upgrading process represented by the conversion of asphaltenes. Challenges and opportunities for key stakeholders, i.e. producers, refiners, marketers and technology licensors also received much attention at the Edmonton conference

  12. Research on weathering and biomarkers in heavy fuel oil

    International Nuclear Information System (INIS)

    Ma, Q.; Li, Z.; Yu, Z.

    2008-01-01

    The fate of oil spilled in the ocean depends on several physicochemical and biological factors such as evaporation, dissolution, microbial degradation and photo-oxidation. These weathering processes decrease the low molecules in spilled oils which reduces the harmful effects of spilled oil to the ocean and biota near the spill. In addition to changing the composition of the oil, some weathering processes are key to identifying the spilled oil. As such, the relationship between the weathering processes and the changes in oil composition must be well understood. This paper used gas chromatography and mass spectrometry (GC/MS) to analyze changes of chemical components in heavy fuel oil by weathering in static seawater. The major alkanes of heavy fuel oil include C8 to C33, while the major aromatics include benzene, naphthalene, phenanthrene and dibenzothiophene. After 24 weeks of weathering in seawater, the alkanes from n-C8 to n-C15 evaporated in order of increasing carbon number. The susceptibility of n-alkanes was correlated with carbon numbers. The aromatics evaporated in order of increasing carbon and ring number as weathering time increased. 8 refs., 3 tabs., 5 figs

  13. Visualization of viscous coupling effects in heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz-Arango, J.D. [Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory; Kantzas, A. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory

    2008-10-15

    Some heavy oil reservoirs in Venezuela and Canada have shown higher than expected production rates attributed to the effects of foamy oil or enhanced solution gas drive. However, foamy oil 2-phase flow does not fully explain oil rate enhancement in heavy oil reservoirs. In this study, flow visualization experiments were conducted in a 2-D etched network micromodel in order to determine the effect of the viscosity ratio on oil mobility at the pore scale. The micromodel's pattern was characterized by macroscopic heterogeneities with a random network of larger pore bodies interconnected with a random network of smaller pore throats. Displacement tests were conducted with green-dyed distilled water as a wetting phase. N-octane, bromododecane and mineral oil were used as non-wetting phases. An unsteady-state method was used to obtain displacement data, and the Alternate method was used to calculate relative permeabilities. Results of the study showed that relative permeabilities depended on the viscosity ratio of the fluids flowing through the porous medium. Channel and annular flows co-existed, and water lubrication was stronger at higher water saturations. The results of the study explained the abnormally high production rates in heavier oil fields. 19 refs., 3 tabs., 14 figs.

  14. The effect of oil revenues instability on the oil-based and labor-exporting economies: The case of the Arab region

    International Nuclear Information System (INIS)

    Al-Abbasi, M.A.

    1991-01-01

    The changes in the trend of the oil-export earnings in the oil-based economics not only affected the growth of the domestic economics not only affected the growth of the domestic economies but influenced the economic activities in the neighboring labor-exporting economies. This study investigates and tests the hypothesis that uncertainty associated with fluctuations in oil-export earnings affect adversely the economic growth in the oil-based economies of the Middle East. In addition, it seeks to examine the hypothesis that the impact of such fluctuations has been transmitted to the neighboring labor-exporting economies, during the period 1970-1986. Results show that oil-export instability does indeed create a wave of fluctuations in the domestic economic activity of the oil-based economies through the negative effect on investment, government spending, and domestic output. For the labor-exporting economies, results suggest that the flow of workers' remittances have had a positive impact on investment and income growth. Results also indicate that the rate of economic growth in the oil-based economies sets a broad limit on the range of feasible growth in the labor-exporting economies

  15. Exports of petroleum products, 1989

    International Nuclear Information System (INIS)

    1990-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1989 calendar year. A discussion of petroleum product imports is included in order to put exports in the context of the overall trade. Exports of the above petroleum products averaged 30,400 m 3 /d in 1989, down 5% from 1988 levels. Motor gasoline shipments showed the largest decrease, down 1,500 m 3 to 7,700 m 3 /d. Export prices for light petroleum products stayed relatively close to USA spot prices except in June and July 1989, when attractive prices were obtained for shipments from the prairie provinces. The heavy fuel oil export price was similar to the USA east coast spot price in 1989, except in December. Canada's petroleum products imports in 1989 were 21,600 m 3 /d, compared to 18,400 m 3 /d in 1988. Imports of heavy fuel oil in eastern Canada rose 36% in 1989 because of industries switching from electricity and the high demand for thermal power generation. The USA remained Canada's largest trading partner in petroleum products. The top single exporter in 1989, as in 1988, was Newfoundland Processing, with a volume of 3,484,500 m 3 . 24 figs., 4 tabs

  16. Heavy oil supply economics and supply response to low oil prices

    International Nuclear Information System (INIS)

    Fisher, L.

    1999-01-01

    The dynamics of the heavy oil industry are examined, including prices, market demand, supply and supply costs. Price assumptions are provided for the reference case oil price (west Texas intermediate at Cushing). Supply cost methodology is explained. Capital and operating costs for various heavy oil and synthetic sources are derived from modeling results. The range of supply costs for heavy oil and bitumen from various sources, supply costs in terms of reference case market values and in terms of 1995-1996 average market values for Bow River crude, are derived. The CERI long term supply forecast model is explained. Western Canada upstream oil and gas cash flow and capital expenditures, eastern Canada exploration and expenditures by hydrocarbon type, and Canadian heavy oil and bitumen production based on reference case prices are estimated. Based on these projections the outlook for heavy oil at reference case prices for better than average quality resources is judged to be economic. Lower quality resources will require technology gains for successful commercialization. SAGD is a likely candidate in this respect. Again based on reference prices, production is forecast to decline by 100 Kb/d over the next five years. Diluent supply is considered to be adequate throughout the forecast period. As far as thermal bitumen is concerned, the growth could, in fact, exceed the projection, but if so, more upgrading will be required. 11 figs

  17. Heavy oil processing impacts refinery and effluent treatment operations

    Energy Technology Data Exchange (ETDEWEB)

    Thornthwaite, P. [Nalco Champion, Northwich, Cheshire (United Kingdom)

    2013-11-01

    Heavy oils are becoming more common in Europe. The processing of heavier (opportunity or challenge) crudes, although financially attractive, introduce additional challenges to the refiner. These challenges are similar whether they come from imported crudes or in the future possibly from shale oils (tight oils). Without a strategy for understanding and mitigating the processing issues associated with these crudes, the profit potential may be eroded by decreased equipment reliability and run length. This paper focuses on the impacts at the desalter and how to manage them effectively while reducing the risks to downstream processes. Desalters have to deal with an increased viscosity, density (lower API gravity), higher solids loading, potential conductivity issues, and asphaltene stability concerns. All these factors can lead to operational problems impacting downstream of the desalter, both on the process and the water side. The other area of focus is the effluent from the desalter which can significantly impact waste water operations. This can take the form of increased oil under-carry, solids and other contaminants originating from the crudes. Nalco Champion has experience in working with these challenging crudes, not only, Azeri, Urals and African crudes, but also the Canadian oil sands, US Shale oil, heavy South American crudes and crudes containing metal naphthenates. Best practices will be shared and an outlook on the effects of Shale oil will be given. (orig.)

  18. AN ALTERNATIVE APPROACH TO THE USE OF HEAVY OIL RESIDUE

    Directory of Open Access Journals (Sweden)

    Eugene Dashut

    2013-01-01

    Full Text Available We consider an alternative approach to the existing oil refining, in which instead of a single priority that emerged in the traditional approach, we consider two: get the light component and a heavy residue used for the production of new construction materials.

  19. Elasticity and competitiveness of Indonesia’s palm oil export in India market

    Directory of Open Access Journals (Sweden)

    Awan Setya Dewanta

    2016-10-01

    Full Text Available This study examines the elasticity and competitiveness of Indonsia’s palm oil export in the India market, 1990 -2014. The methods used are Error Correction Model (ECM and Revealed Comparative Advantage (RCA approach. The results shows that the price is inelastic in short-term but it is elastic in long-term. The income and exchange rate are elastic in the long-term. There is also a decline in competitiveness in the market India. These findings also demonstrate that palm oil is normal goods and can be easily substituted with the same products of other countries or other vegetable oils. It threatens the Indonesian palm oil competitiveness in the Indian market.

  20. The Success of Economic Policies in Russia: Dependence on Crude Oil vs. Export Diversification

    Directory of Open Access Journals (Sweden)

    Elena Kuzmenko

    2017-01-01

    Full Text Available In the light of numerous debates around Russia’s dependence on crude oil and the necessity to diversify the Russian economy, the present paper investigates how closely federal budget revenues, structure of export basket and GDP growth in Russia are tied up with crude oil prices (POIL on the one hand and the real effective exchange rate of ruble (REER on the other. The study covers the period from 2000:Q1 till 2014:Q4 and employs index analysis along with vector error correction model (VECM based on Johansen co‑integration technique. The calculated REER revealed its significant appreciation, that together with a high share of mineral products in total Russian exports points to Dutch disease presence. The constructed econometric models revealed the existence of long‑run relationships among the analyzed indicators. Post‑estimation tests proved the validity of the VECMs. According to the obtained results, in order to stimulate “non‑oil” exports monetary authorities should depreciate national currency, whilst fiscal burden should be mild towards “non oil” producers. However, the observed dynamics of macroeconomic indicators points to the fact that the Russian economy is still substantially influenced by POIL and this influence is much more stronger than it is exerted by fiscal and monetary regulators. It allows us to conclude that crude oil will continue to play, at least in foreseeable future, a dominant role in further development of the Russian economy.

  1. Greenhouse gases: How does heavy oil stack up?

    International Nuclear Information System (INIS)

    Ottenbreit, R.J.

    1991-01-01

    Life-cycle emissions of direct greenhouse gases (GHG) have been calculated to elucidate the global warming impacts of various fossil fuel feedstocks. Calculations were made for the transportation sector using five fossil fuel sources: natural gas, light crude oil, conventional heavy oil, crude bitumen recovered through in-situ steam stimulation, and crude bitumen recovered through mining. Results suggest that fuels sourced from light crude oil have the lowest GHG emissions, while conventional heavy oil has the highest GHG emission levels for this application. Emissions of methane can constitute a significant portion of the life-cycle GHG emissions of a fossil fuel. For all the fossil fuels examined, except conventional heavy oil, GHG emissions associated with their production, transport, processing, and distribution are less than one third of their total life-cycle emissions. The remainder is associated with end use. This confirms that consumers of fossil fuel products, rather than fossil fuel producers, have the most leverage to reduce GHG emissions. 2 figs

  2. Canadian oilsands, heavy oil poised for surge in development

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    Operators in Canada's oilsands and heavy oil regions are on the brink of a period of growth that could last well into the next century. Several factors are combining in a scenario a National Task Force report on oilsands says could dramatically increase investment and production in the next 25 years. By then, massive oilsands and heavy oil reserves in northern Alberta could account for as much as 50%--perhaps more--of Canada's oil production. Technological improvements in recovery and processing have slashed production costs and put nonconventional oil on a more competitive footing with declining reserves of conventional crude in western Canada. At the same time, persistent lobbying by industry and a well researched national study have persuaded federal and provincial governments to introduce a new royalty and fiscal regime designed to bolster oilsands investment. New policies give clear incentives to investors to put money into oilsands and heavy oil projects. Policies also will provide a generic tax treatment for all new projects, long a major objective of oilsands promoters. Previously, royalty and tax agreements were negotiated for project case by case. This paper reviews the resource base and the new operational developments resulting from these policies

  3. Solar-Assisted Fast Cleanup of Heavy Oil Spill by a Photothermal Sponge

    KAUST Repository

    Chang, Jian; Shi, Yusuf; Wu, Mengchun; Li, Renyuan; Shi, Le; Jin, Yong; Qing, Weihua; Tang, Chuyang; Wang, Peng

    2018-01-01

    of the photothermal effect to heating the heavy oil by using sunlight as energy source to significantly reduce the viscosity of the heavy oil and thus to achieve a fast heavy oil cleanup. A carbon nanotube (CNT) modified polyurethane sponge was fabricated

  4. Light and Heavy Tactical Wheeled Vehicle Fuel Consumption Evaluations Using Fuel Efficient Gear Oils (FEGO)

    Science.gov (United States)

    2016-05-01

    UNCLASSIFIED LIGHT AND HEAVY TACTICAL WHEELED VEHICLE FUEL CONSUMPTION EVALUATIONS USING FUEL EFFICIENT GEAR OILS (FEGO) FINAL... HEAVY TACTICAL WHEELED VEHICLE FUEL CONSUMPTION EVALUATIONS USING FUEL EFFICIENT GEAR OILS (FEGO) FINAL REPORT TFLRF No. 477 by Adam C...August 2014 – March 2016 4. TITLE AND SUBTITLE LIGHT AND HEAVY TACTICAL WHEELED VEHICLE FUEL CONSUMPTION EVALUATIONS USING FEUL EFFICIENT GEAR OILS

  5. Improved heavy oil recovery by low rate waterflooding

    Energy Technology Data Exchange (ETDEWEB)

    Mai, A. [Laricina Energy Ltd., Calgary, AB (Canada); Kantzas, A. [Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory

    2008-10-15

    Waterflooding techniques are frequently used to recover oil in low viscosity or marginal heavy oil reservoirs. This paper described a low-rate waterflooding oil recovery mechanism. The mechanism was determined by examining the effect of sand permeability on the impact of viscous force contributions. Changes in permeability and injection rates parameters were studied in order to evaluate the significance of imbibition, and a method of quantifying the effect of capillary forces was presented. The mechanism was demonstrated in an experimental study that used sand packs of varying permeabilities wet-packed into cores with overburden pressures. A fixed injection rate was used to investigate waterflooding in the different permeability systems with 2 different oils. Overall recovery rates were examined as a function of injection velocity. An analysis of normalized oil production rates demonstrated that viscous forces are more important during the early phases of waterflooding. The study showed that breakthrough oil recovery values increased with higher permeability values. However, when injection rates were reduced to low frontal velocity values, the correlation between sand permeability and breakthrough oil recovery resulted in low permeability rates. Lower permeability porous media resulted in more restrictive flow conditions. However, the capillary force components increased as a result of the smaller pore sizes, which in turn led to enhanced water imbibition and higher oil recovery values after water breakthrough. It was concluded that waterflooding rates can be modified later in the recovery process in order to improve final oil recovery values. 21 refs., 3 tabs., 11 figs.

  6. Mapping reactor operating regimes for heavy gas oil hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Munteanu, Mugurel Catalin; Chen, Jinwen [CanmetENERGY, Natural Resources Canada (Canada)

    2011-07-01

    Hydrotreating (HDT) is used in oil refineries at temperatures of 350-400 degree C and pressure of 50-100 bars in a fixed bed to improve the quality of distillate fraction. HDT operates as a gas-liquid-solid process, trickle bed. Efforts have been made to model it but volatilization of liquid oil is often ignored. The aim of this paper is to predict vapor-liquid equilibrium (VLE) for a typical heavy distillate feed in pilot plant hydrotreaters. The study was conducted under various operating conditions and a flash calculation program calibrated in-house was used to predict VLE. VLE values were found and results showed that higher pressure, lower gas/oil ratio and temperature should be used to maintain the desired operating regimes when hydrotreating heavy distillate feed. This study determined the operating conditions for maintaining the desired operating regimes and these findings could be useful for operators.

  7. An Estimate of Recoverable Heavy Oil Resources of the Orinoco Oil Belt, Venezuela

    Science.gov (United States)

    Schenk, Christopher J.; Cook, Troy A.; Charpentier, Ronald R.; Pollastro, Richard M.; Klett, Timothy R.; Tennyson, Marilyn E.; Kirschbaum, Mark A.; Brownfield, Michael E.; Pitman, Janet K.

    2009-01-01

    The Orinoco Oil Belt Assessment Unit of the La Luna-Quercual Total Petroleum System encompasses approximately 50,000 km2 of the East Venezuela Basin Province that is underlain by more than 1 trillion barrels of heavy oil-in-place. As part of a program directed at estimating the technically recoverable oil and gas resources of priority petroleum basins worldwide, the U.S. Geological Survey estimated the recoverable oil resources of the Orinoco Oil Belt Assessment Unit. This estimate relied mainly on published geologic and engineering data for reservoirs (net oil-saturated sandstone thickness and extent), petrophysical properties (porosity, water saturation, and formation volume factors), recovery factors determined by pilot projects, and estimates of volumes of oil-in-place. The U.S. Geological Survey estimated a mean volume of 513 billion barrels of technically recoverable heavy oil in the Orinoco Oil Belt Assessment Unit of the East Venezuela Basin Province; the range is 380 to 652 billion barrels. The Orinoco Oil Belt Assessment Unit thus contains one of the largest recoverable oil accumulations in the world.

  8. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    None

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt. The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degrees} C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3--5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  9. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Carbognani, L.; Hazos, M.; Sanchez, V. (INTEVEP, Filial de Petroleos de Venezuela, SA, Caracas (Venezuela)); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  10. Investment requirements in the oil industry of the independent oil exporting countries in the face of environmental challenges

    International Nuclear Information System (INIS)

    Rahmat, H.; Hamid, A.A.

    1992-01-01

    The oil industry has to operate under environmental constraints which involve commercial risks. Oil companies need to treat environmental management as an investment as well as an insurance problem, assessing risks and costs and deciding how to minimize them most cost effectively. Petroleum development in Malaysia is accelerating. In view of the high visibility of the industry and the wide publicity generated by a few incidents which have taken place outside Malaysia the national oil company, Petronas, is constantly vigilant in its efforts to preserve the environment. Oil producing countries like Malaysia will need to continue to set aside some of the revenue they obtain from the oil industry and use it for protecting the environment to ensure public acceptance and ultimately, orderly growth of their industry. Clearly they are less able to do so if their income is lessened through the interference with free trade among nations even if the purported reasons for the interference is the environment itself. Ultimately the environmental investment requirement in the oil industry of the independent and developing oil exporting countries is free trade without price distortions. The 1989 Langkawi Declaration on the Environment of the Commonwealth Heads of Government is appended to this article. (author)

  11. Expanding solvent SAGD in heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Govind, P.A. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[ConocoPhillips Canada Resources Corp., Calgary, AB (Canada); Das, S.; Wheeler, T.J. [Society of Petroleum Engineers, Richardson, TX (United States)]|[ConocoPhillips Co., Houston, TX (United States); Srinivasan, S. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Texas Univ., Austin, TX (United States)

    2008-10-15

    Steam assisted gravity drainage (SAGD) projects have proven effective for the recovery of oil and bitumen. Expanding solvent (ES) SAGD pilot projects have also demonstrated positive results of improved performance. This paper presented the results of a simulation study that investigated several important factors of the ES-SAGD process, including solvent types; concentration; operating pressure; and injection strategy. The objectives of the study were to examine the effectiveness of the ES-SAGD process in terms of production acceleration and energy requirements; to optimize solvent selection; to understand the effect of dilation in unconsolidated oil sands and the directional impact on reservoir parameters and oil production rate in ES-SAGD; and to understand the impact of operating conditions such as pressure, solvent concentration, circulation preheating period and the role of conduction heating and grid size in this process. The advantages of ES-SAGD over SAGD were also outlined. The paper presented results of sensitivity studies that were conducted on these four factors. Conclusions and recommendations for operating strategy were also offered. It was concluded that dilation is an important factor for SAGD performance at high operating pressure. 8 refs., 15 figs.

  12. New lube oil for stationary heavy fuel engines

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    An extensively field-tested diesel engine lubricating oil for medium speed, heavy fuel stationary engine applications has been introduced by Caltex Petroleum, in Dallas, Texas. The new oil is similar to a product developed and marketed for marine medium speed heavy fuel propulsion and auxillary engine applications by one of its two parent companies, Chevron. Detailed are results of two field evaluations in Caterpillar 3600 series engines installed at Kimberly Clark (KCPI) and Sime Darby (SDPI), both in the Philippines. Both were one year, 7000-plus hour field evaluations of a new, 40 BN trunk piston engine oil (TPEO), identified as Caltex Delo 3400, SAE 40 engine lube oil. The oil uses the new Phenalate additive technology developed by Chevron Chemical Company`s Oronite Additives Division. This technology is designed to improve engine cleanliness in regard to soft black sludge and piston deposits. The focus of the field evaluations was the performance of the lubricating oil. During controlled tests at Sime Darby, the most noticeable improvement over another technology was in the control of sludge deposits. This improvement was seen in all areas where black sludge forms, such as the rocker cover, crankcase cover and valve assemblies. 4 figs.

  13. Recycling used palm oil and used engine oil to produce white bio oil, bio petroleum diesel and heavy fuel

    Science.gov (United States)

    Al-abbas, Mustafa Hamid; Ibrahim, Wan Aini Wan; Sanagi, Mohd. Marsin

    2012-09-01

    Recycling waste materials produced in our daily life is considered as an additional resource of a wide range of materials and it conserves the environment. Used engine oil and used cooking oil are two oils disposed off in large quantities as a by-product of our daily life. This study aims at providing white bio oil, bio petroleum diesel and heavy fuel from the disposed oils. Toxic organic materials suspected to be present in the used engine oil were separated using vacuum column chromatography to reduce the time needed for the separation process and to avoid solvent usage. The compounds separated were detected by gas chromatography-mass spectrometry (GC-MS) and found to contain toxic aromatic carboxylic acids. Used cooking oils (thermally cracked from usage) were collected and separated by vacuum column chromatography. White bio oil produced was examined by GC-MS. The white bio oil consists of non-toxic hydrocarbons and is found to be a good alternative to white mineral oil which is significantly used in food industry, cosmetics and drugs with the risk of containing polycyclic aromatic compounds which are carcinogenic and toxic. Different portions of the used cooking oil and used engine were mixed to produce several blends for use as heavy oil fuels. White bio oil was used to produce bio petroleum diesel by blending it with petroleum diesel and kerosene. The bio petroleum diesel produced passed the PETRONAS flash point and viscosity specification test. The heat of combustion of the two blends of heavy fuel produced was measured and one of the blends was burned to demonstrate its burning ability. Higher heat of combustion was obtained from the blend containing greater proportion of used engine oil. This study has provided a successful recycled alternative for white bio oil, bio petroleum fuel and diesel which can be an energy source.

  14. Development of oil and gas exports from Northern Russia

    International Nuclear Information System (INIS)

    Backlund, Anders

    1995-01-01

    The study is a part of Insrop Subprogram III, ''Trade and Commercial Shipping'' and compares the transportation costs from Northern Russia to markets with costs from competing areas. LNG transportation is focused but some comments are made on oil transportation and include most cost factors that can differ compared to present transportation with emphasis on the actual sea transportation costs. A separate discussion on the differences caused by operating mode is included. The results will give a starting point for more detailed comparisons on the effects of different solutions for total costs. An economic feasibility study is made on LNG transportation from the Kharasevey area on the Yamal peninsula to Rotterdam. Demand and need for icebreaking vessels is discussed. The study has investigated the different factors influencing the selection of a transportation system and a calculation has been made as to the costs for seaborne transportation which technically does not seem to be a problem. However, the amount of published data on the prevailing conditions is still limited. It is essential that an extensive data collection and formation process is to be started. Economic calculations for the transportation of LNG from the Kharasevey area to Rotterdam for independent year-round operation are made, including production and storage costs. The possible extra costs for navigating in the Northern Sea Route (NSR) vary from 1,1 USD/cu.m. to about 3 USD/cu.m., where the cheapest alternative is for chartering two Kapitan Dranitsyn-class icebreakers for 270 days/year and the most expensive alternative being the full NSR fee for all visits. These costs represent 10-30 % of the sea transportation costs but only 3-10 % of the total costs. If we take into consideration that the market price for LNG today is about 100 USD/cu.m., then there are potentials in the supply of LNG from Yamal to the European market and the alternative can be competitive. The Arctic alternative is expected

  15. Development of oil and gas exports from Northern Russia

    Energy Technology Data Exchange (ETDEWEB)

    Backlund, Anders

    1995-07-01

    The study is a part of Insrop Subprogram III, ''Trade and Commercial Shipping'' and compares the transportation costs from Northern Russia to markets with costs from competing areas. LNG transportation is focused but some comments are made on oil transportation and include most cost factors that can differ compared to present transportation with emphasis on the actual sea transportation costs. A separate discussion on the differences caused by operating mode is included. The results will give a starting point for more detailed comparisons on the effects of different solutions for total costs. An economic feasibility study is made on LNG transportation from the Kharasevey area on the Yamal peninsula to Rotterdam. Demand and need for icebreaking vessels is discussed. The study has investigated the different factors influencing the selection of a transportation system and a calculation has been made as to the costs for seaborne transportation which technically does not seem to be a problem. However, the amount of published data on the prevailing conditions is still limited. It is essential that an extensive data collection and formation process is to be started. Economic calculations for the transportation of LNG from the Kharasevey area to Rotterdam for independent year-round operation are made, including production and storage costs. The possible extra costs for navigating in the Northern Sea Route (NSR) vary from 1,1 USD/cu.m. to about 3 USD/cu.m., where the cheapest alternative is for chartering two Kapitan Dranitsyn-class icebreakers for 270 days/year and the most expensive alternative being the full NSR fee for all visits. These costs represent 10-30 % of the sea transportation costs but only 3-10 % of the total costs. If we take into consideration that the market price for LNG today is about 100 USD/cu.m., then there are potentials in the supply of LNG from Yamal to the European market and the alternative can be competitive. The Arctic

  16. Preparation Of Pure Carbon From Heavy Oil Fly Ash

    International Nuclear Information System (INIS)

    ABU ZAID, A.H.M.

    2010-01-01

    The Egyptian production of heavy oil is approximately 12 million tons of heavy oil per year and approximately 5.3 million tons of this amount is used as fuel in the electric power stations. Based on the fact that the ash content of Egyptian heavy oil is approximately 0.2 %, about 10600 tons of fly ash is produced per/year which causes a lot of environmental problems such as dusting, release of the acidic liquids and heavy metals such as vanadium, nickel, zinc and unburned carbon. Treatment of fly ash by leaching of vanadium and zinc was carried out under different conditions to achieve the best leaching efficiency of both vanadium and zinc by sodium hydroxide. The leaching efficiency obtained was 91% for vanadium and 98% for zinc. This study was concerned with the precipitation of zinc at pH 7.5 as zinc hydroxide and the precipitation of vanadium as ammonium metavanadate at pH 8.5. Leaching of nickel, iron and other elements from the residue was carried out by 2M HCl under different conditions. The achieved leaching efficiency of nickel was 95% where as that of iron was 92%. Precipitation efficiency of both nickel and iron were 99.9%. The residue, which contains mainly unburned carbon, have been washed two times with water and dried at 200 o C then ground to < 300μm. According to the achieved analysis of the obtained carbon, it can be characterized as pure carbon

  17. The impact of oil-export dependency on a developing country; The case of Algeria

    Energy Technology Data Exchange (ETDEWEB)

    Heidarian, J. (World Bank, Washington, DC (USA)); Green, R.D. (Howard Univ., Washington, DC (US). Dept. of Economics)

    1989-10-01

    A large oil export sector is often considered to be a potential spur to diversification and full modernization in third world countries, especially when a central government controls and plans the use of oil revenues with such goals in mind. We evaluate this proposition by developing a 12-equation Keynesian econometric model of the Algerian economy. The model's equations, estimated using ordinary least squares, are robust with strong R-squares, significant t-tests for the independent variables, and reasonable Durbin-Watson statistics. Historical simulations track the true variables rather closely. Our RMSEs (percentage) are in general better than those in most studies of less-developed countries, ranging from 7 to 21%. Our results indicate that there has been a growing dependency of most major economic sectors on oil revenues, both before and after nationalization. Improvements in oil exports will, ceteris paribus, lead to elastic increases in luxury imports and domestic consumption, and inelastic increases in domestic investment. Thus, the goals of diversification, modernization and industrialization will not be met under the current set of policies in Algeria. (author).

  18. America's gas tank : the high cost of Canada's oil and gas export strategy

    International Nuclear Information System (INIS)

    Price, M.; Bennett, J.

    2002-10-01

    The high environmental cost of exporting oil and gas from Canada to the United States is discussed. The increased demand for fossil fuels by the United States has coincided with Canada's deregulation of the energy industry and a greater control of Canadian energy companies by American interests. The authors note that most of the oil and gas produced in Canada is exported to the United States, where many of the extraction and production decisions affecting Canadians and the Canadian environment are made. It was cautioned that if the current trend continues, oil and gas development will degrade habitat for endangered species and greenhouse gases will escalate. This is because the fossil fuel industry, particularly the development of Alberta's tar sands, is helping to increase greenhouse gas emissions outside of Canada by selling fossil fuels that are burned outside of Canada. It is recommended that federal and provincial governments in Canada should shift their policies away from fossil fuel production and promote renewable energy production. The United States plans to increase Canadian oil and gas imports in the coming decade, requiring more wells to be drilled and pipelines to carry it. If the fossil fuel industry proceeds with the current plans, greenhouse gas emissions in Canada will grow to 827 million tonnes by 2010, 44 per cent beyond the Kyoto target, having an overall negative impact on public health, wildlife and fresh water supplies. refs., tabs., figs

  19. Chemically evolving systems for oil recovery enhancement in heavy oil deposits

    Science.gov (United States)

    Altunina, L. K.; Kuvshinov, I. V.; Kuvshinov, V. A.; Stasyeva, L. A.

    2017-12-01

    This work presents the results of laboratory studies and field tests of new physicochemical technologies for enhanced oil recovery of heavy oil fields under natural development conditions and with thermal-steam stimulation using oil-displacing "smart" systems. The systems are based on surfactants and buffer systems. Their rheological and acid-base properties can be regulated by their chemical evolution directly in the formation. Field tests of the technologies carried out on high-viscosity oil deposit in the Usinskoye oilfield have shown that the EOR technologies are environmentally friendly and technologically effective.

  20. Transport interests and environmental regimes. The Baltic Sea transit of Russian oil exports

    International Nuclear Information System (INIS)

    Knudsen, Olav F.

    2010-01-01

    In the environmentally exposed Baltic Sea, a prolonged confrontation has set the transport interests of Russian crude oil against environmental interests, promoted by Russia's neighbours. During the 1990s all the Baltic littoral states - including Russia - collaborated well on marine environmental issues. When Russian oil exports accelerated after 1999, this environmental understanding broke down. Russian interests shifted as its oil income suddenly rose drastically. The confrontation peaked over a proposal to make the entire Baltic Sea into a particularly sensitive sea area (PSSA) under the International Maritime Organization (IMO). The proposal was adopted by the IMO in spite of Russian objections. The article shows how environmental interests trump transport interests in a manner that may not be sustainable. The case illustrates the need for environmental collaboration to be flexible in the face of shifting constellations of competing interests. (author)

  1. Ranking oil viscosity in heavy-oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Bonnie, R.J.M. [Halliburton Energy Services, Calgary, AB (Canada); Seccombe, J. [BP Alaska, AK (United States)

    2005-11-01

    This paper discussed attempts to identify lower viscosity zones within the Ugnu formation at Milne Point field in Alaska through the use of Nuclear Magnetic Resonance (NMR) measurements. To date, only 1 well has been completed in the Ugnu, and BP Alaska is now engaged in studies to find ways to commercialize the formation. While geochemical analysis of oil samples extracted from sidewall cores has successfully identified sweet spots, the costs are prohibitive and they are too slow for real-time decision-making. NMR data acquisition offers a more economical, continuous and almost instantaneous alternative. Two wells were logged and analyzed using both logging while drilling (LWD) NMR and wire log (WL)-NMR tools. With the WL-NMR tool, data were collected in continuous passes and in a series of 45 minute stationary points, acquiring both routine T{sub 2} and diffusion editing data to predict oil viscosity. The LWD-NMR tool was set up to acquire T{sub 1} data when drilling. Forward modelling was used to generate NMR T{sub 2} spectra for reservoir parameters. The NMR logs indicate that the technology is a viable non-radioactive porosity measurement alternative. Data quality had high-vertical resolution and spectral resolution and showed good agreement with density-derived porosity. Zones with viscous oil were located and findings were validated by geochemical analyses. Bandwidth limitation was the only obstacle that prevented real time application of the NMR ranking process. 6 refs., 11 figs.

  2. Exports of petroleum products, 1990

    International Nuclear Information System (INIS)

    1991-04-01

    A summary is presented of exports of motor gasoline, middle distillate, aviation turbine fuel, heavy fuel oil, and partially processed oil from Canada for the 1990 calendar year. Exports of the above petroleum products averaged 34,000 m 3 /d in 1990, up 12% from 1989 levels. The increase reflects increased output from the Come By Chance refinery in Newfoundland. Motor gasoline exports increased 35% to 10,500 m 3 /d, reflecting refinery upgrading in eastern Canada. Export prices were generally in line with spot product prices in the USA. Spot prices rose sharply following the Kuwait crisis in August 1990 but fell again in November. The spot price for jet fuel rose more dramatically in that period than for other products, reflecting increased military demand. In winter 1989/90 and during the Kuwait conflict, the export price of heating oil tended to track the USA spot price. Petroleum products imports in 1990 were 18,500 m 3 /d, compared to 21,900 m 3 /d in 1988. Imports were lower partially as a result of higher crude runs in Quebec and a Quebec refinery expansion. Imports of heavy fuel oil in eastern Canada continued to be strong in comparison to the mid-1980s. The top single exporter in 1990, as in 1989, was Newfoundland Processing, with a volume of 4,506,400 m 3 . 13 figs., 5 tabs

  3. Geothermal and heavy-oil resources in Texas

    Energy Technology Data Exchange (ETDEWEB)

    Seni, S.J.; Walter, T.G.

    1994-01-01

    In a five-county area of South Texas, geopressured-geothermal reservoirs in the Paleocene-Eocene Wilcox Group lie below medium- to heavy-oil reservoirs in the Eocene Jackson Group. This fortuitous association suggests the use of geothermal fluids for thermally enhanced oil recovery (TEOR). Geothermal fairways are formed where thick deltaic sandstones are compartmentalized by growth faults. Wilcox geothermal reservoirs in South Texas are present at depths of 11,000 to 15,000 ft (3,350 to 4,570 m) in laterally continuous sandstones 100 to 200 ft (30 to 60 m) thick. Permeability is generally low (typically 1 md), porosity ranges from 12 to 24 percent, and temperature exceeds 250{degrees}F (121{degrees}C). Reservoirs containing medium (20{degrees} to 25{degrees} API gravity) to heavy (10{degrees} to 20{degrees} API gravity) oil are concentrated along the Texas Coastal Plain in the Jackson-Yegua Barrier/Strandplain (Mirando Trend), Cap Rock, and Piercement Salt Dome plays and in the East Texas Basin in Woodbine Fluvial/Deltaic Strandplain and Paluxy Fault Line plays. Injection of hot, moderately fresh to saline brines will improve oil recovery by lowering viscosity and decreasing residual oil saturation. Smectite clay matrix could swell and clog pore throats if injected waters have low salinity. The high temperature of injected fluids will collapse some of the interlayer clays, thus increasing porosity and permeability. Reservoir heterogeneity resulting from facies variation and diagenesis must be considered when siting production and injection wells within the heavy-oil reservoir. The ability of abandoned gas wells to produce sufficient volumes of hot water over the long term will also affect the economics of TEOR.

  4. Focusing on heavy oil, technology and people. Annual report 1995

    International Nuclear Information System (INIS)

    Anon.

    1995-01-01

    Financial information from CS Resources and a review of operations in 1995 was made available for the benefit of shareholders. CS Resources has been involved in the resource development of the Western Canada Sedimentary Basin for some time. Since becoming public in 1989, CS Resources have experienced continued profitable growth through such programs as thermal and enhanced recovery of heavy oils, and through the exploration of natural gas and light crude oil. This report presented an operations review, consolidated financial statements, a seven year historical summary, production statistics, and a seven year share price and other common share information. tabs., figs

  5. Microbial ecology of methanogenic crude oil biodegradation; from microbial consortia to heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Head, Ian M.; Maguire, Michael J.; Sherry, Angela; Grant, Russell; Gray, Neil D.; Aitken, Carolyn M.; Martin Jones, D.; Oldenburg, Thomas B.P.; Larter, Stephen R. [Petroleum Research Group, Geosciences, University of Calgary (Canada)

    2011-07-01

    This paper presents the microbial ecology of methanogenic crude oil biodegradation. Biodegraded petroleum reservoirs are one of the most dramatic indications of the deep biosphere. It is estimated that heavy oil and oil sands will account for a considerable amount of energy production in the future. Carbon, a major resource for deep subsurface microorganisms, and energy are contained in large quantities in petroleum reservoirs. The aerobic to anaerobic paradigm shift is explained. A key process for in-situ oil biodegradation in petroleum reservoirs is methanogenesis. New paradigms for in-reservoir crude oil biodegradation are discussed. Variations in anaerobic degradation of crude oil hydrocarbons are also discussed. A graph shows the different patterns of crude oil biodegradation under sulfate-reducing and methanogenic conditions. Alternative anaerobic alkane activation mechanisms are also shown. From the study, it can be concluded that methanogenic crude oil degradation is of global importance and led to the establishment of the world's enormous heavy oil deposits.

  6. A Review of Laboratory-Scale Research on Upgrading Heavy Oil in Supercritical Water

    Directory of Open Access Journals (Sweden)

    Ning Li

    2015-08-01

    Full Text Available With the growing demand for energy and the depletion of conventional crude oil, heavy oil in huge reserve has attracted extensive attention. However, heavy oil cannot be directly refined by existing processes unless they are upgraded due to its complex composition and high concentration of heteroatoms (N, S, Ni, V, etc.. Of the variety of techniques for heavy oil upgrading, supercritical water (SCW is gaining popularity because of its excellent ability to convert heavy oil into valued, clean light oil by the suppression of coke formation and the removal of heteroatoms. Based on the current status of this research around the world, heavy oil upgrading in SCW is summarized from three aspects: Transformation of hydrocarbons, suppression of coke, and removal of heteroatoms. In this work, the challenge and future development of the orientation of upgrading heavy oil in SCW are pointed out.

  7. Proceedings of ITOHOS 2008 : The 2008 SPE/PS/CHOA International Thermal Operations and Heavy Oil Symposium : Heavy Oil : Integrating the Pieces

    International Nuclear Information System (INIS)

    2008-10-01

    This multi-disciplinary conference and exhibition combined the Society of Petroleum Engineers (SPE) and the Petroleum Society's (PS) international thermal operations and heavy oil symposium, and the Canadian Heavy Oil Association's (CHOA) annual business meeting. The conference provided a forum to examine emerging technologies and other critical issues affecting the global heavy oil and bitumen industry. The most current technologies from around the world that enhance the recovery of heavy oil and bitumen from oil sand deposits were also showcased. The technical program encompassed the economic, technical, and environmental challenges that the petroleum industry is currently facing. The sessions of the conference were entitled: artificial lift; mining, extraction and cold production; simulation; solvent processes; reservoir characterization; steam generation and water treatment; and, in-situ combustion in Canada. The conference also featured a series of short courses and tutorials on heavy oil wellbore completions and design; drilling horizontal heavy oil wells and steam assisted gravity drainage (SAGD) wells; geomechanical based reservoir monitoring; thermal well design; fiber optic thermal monitoring; heavy oil thermal recovery and economics; wellbore slotting; advanced geomechanics; and, an overview of cold heavy oil production with sand (CHOPS). All 91 presentations from the conference have been catalogued separately for inclusion in this database. refs., tabs., figs

  8. Proceedings of ITOHOS 2008 : The 2008 SPE/PS/CHOA International Thermal Operations and Heavy Oil Symposium : Heavy Oil : Integrating the Pieces

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-10-15

    This multi-disciplinary conference and exhibition combined the Society of Petroleum Engineers (SPE) and the Petroleum Society's (PS) international thermal operations and heavy oil symposium, and the Canadian Heavy Oil Association's (CHOA) annual business meeting. The conference provided a forum to examine emerging technologies and other critical issues affecting the global heavy oil and bitumen industry. The most current technologies from around the world that enhance the recovery of heavy oil and bitumen from oil sand deposits were also showcased. The technical program encompassed the economic, technical, and environmental challenges that the petroleum industry is currently facing. The sessions of the conference were entitled: artificial lift; mining, extraction and cold production; simulation; solvent processes; reservoir characterization; steam generation and water treatment; and, in-situ combustion in Canada. The conference also featured a series of short courses and tutorials on heavy oil wellbore completions and design; drilling horizontal heavy oil wells and steam assisted gravity drainage (SAGD) wells; geomechanical based reservoir monitoring; thermal well design; fiber optic thermal monitoring; heavy oil thermal recovery and economics; wellbore slotting; advanced geomechanics; and, an overview of cold heavy oil production with sand (CHOPS). All 91 presentations from the conference have been catalogued separately for inclusion in this database. refs., tabs., figs.

  9. The impacts of the export ban on Alaskan crude oil trade

    International Nuclear Information System (INIS)

    Farah, P.G.; Bausell, C.W.; Vogelsang, A.

    1990-01-01

    The authors investigated the petroleum markets impacts of lifting the ban on Alaska North Slope (ANS) crude oil exports. This paper reports on some aspects of this investigation. The economic analysis relied heavily on the modeling of the ANS crude trade conducted on behalf of GAO by the Energy Information Administration (EIA) using the Transportation and Refining of International Petroleum model (TRIP). In contrast to previous studies, this one suggests that transportation costs may not be the only major factor in the realignment of ANS crude trade in response to lifting the ban. The differences in the yields of ANS crude and various crudes used by refiners in Pacific Rim countries on the one hand, and the product demand slates of the US West Coast and the potential buyers of ANS crude in Pacific Rim may also figure prominently in determining the reallocation of ANS crude if exports are permitted

  10. Pipeline flow of heavy oil with temperature-dependent viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Maza Quinones, Danmer; Carvalho, Marcio da Silveira [Pontifical Catholic University of Rio de Janeiro (PUC-Rio), RJ (Brazil). Dept. of Mechanical Engineering], E-mail: msc@puc-rio.br

    2010-07-01

    The heavy oil produced offshore needs to be transported through pipelines between different facilities. The pipelines are usually laid down on the seabed and are submitted to low temperatures. Although heavy oils usually present Newtonian behavior, its viscosity is a strong function of temperature. Therefore, the prediction of pressure drops along the pipelines should include the solution of the energy equation and the dependence of viscosity to temperature. In this work, an asymptotic model is developed to study this problem. The flow is considered laminar and the viscosity varies exponentially with temperature. The model includes one-dimensional equations for the temperature and pressure distribution along the pipeline at a prescribed flow rate. The solution of the coupled differential equation is obtained by second-order finite difference. Results show a nonlinear behavior as a result of coupled interaction between the velocity, temperature, and temperature dependent material properties. (author)

  11. A study on ultra heavy oil gasification technology

    Energy Technology Data Exchange (ETDEWEB)

    Kidoguchi, Kazuhiro; Ashizawa, Masami; Taki, Masato; Ishimura, Masato; Takeno, Keiji

    2000-07-01

    Raising the thermal efficiency of a thermal power plant is an important issue from viewpoints of effective energy utilization and environmental protection. In view of raising the thermal efficiency, a gas turbine combined cycle power generation is considered to be very effective. The thermal efficiency of the latest LNG combined cycle power plant has been raised by more than 50%. On the other hand, the diversification of fuels to ensure supply stability is also an important issue, particularly in Japan where natural resources are scarce. Because of excellent handling characteristics petroleum and LNG which produces clean combustion are used in many sectors, and so the demand for such fuels is expected to grow. However, the availability of such fuels is limited, and supplies will be exhausted in the near future. The development of a highly efficient and environment-friendly gas turbine combined cycle using ultra heavy oil such as Orimulsion{trademark} (trademark of BITOR) is thus a significant step towards resolving these two issues. Chubu Electric Power Co, Inc., the Central Research Institute of Electric Power Industry (CRIEPI), and Mitsubishi Heavy Industries, Ltd. (MHI) conducted a collaboration from 1994 to 1998 with the objective of developing an ultra heavy oil integrated gasification combined cycle (IGCC). Construction of the ultra heavy oil gasification testing facility (fuel capacity:2.4t/d) was completed in 1995, and Orimulsion{trademark} gasification tests were carried out in 1995 and 1996. In 1997, the hot dedusting facility with ceramic filter and the water scrubber used as a preprocessor of a wet desulfurization process were installed. Gasification and clean up the syngs tests were carried out on Orimulsion{trademark}, Asmulsion{trademark} (trademark of Nisseki Mitsubishi K.K.), and residue oil in 1997 and 1998. The results of the collaboration effort are described below.

  12. REVENUE FROM EXPORTING OIL, INCOME DISTRIBUTION, AND ECONOMIC PROGRESS IN THE MIDDLE EAST

    Directory of Open Access Journals (Sweden)

    Mehdi MOHAGHEGH

    2009-07-01

    Full Text Available The increases in petrodollars received by oil produ cing countries of the Middle East in the past few years can become a reality again when the wo rld economy recovers from this recession. The access to so much hard currency in the past co uld have potentially impr oved the economies of these nations beyond imagination. Economic de velopment specialists regard reaching some goals such as higher growth rate of real output, less chronic inflation, Improvements in education and healthcare services, greater diversity in the economy and in exports, greater equality in the distribution of income, and lower unemployment rate as indication of economic progress or socio –economic improvements in a developing country. The purpose of this paper is to evaluate the relative success of the Oil-Produc ing Countries of the Middle East in achieving the above socio- economic goals within the context of huge inflows of petrodollars into their countries every year. Through analysis of data from the region the author of this paper has obtained convincing evidence in support of the view that the oil-exporting nations have, for the most part, wasted the abundant and extremely valuable foreign curr encies that they have received every year for the past several decades.

  13. Coal fired steam generation for heavy oil recovery

    International Nuclear Information System (INIS)

    Firmin, K.

    1992-01-01

    In Alberta, some 21,000 m 3 /d of heavy oil and bitumen are produced by in-situ recovery methods involving steam injection. The steam generation requirement is met by standardized natural-gas-fired steam generators. While gas is in plentiful supply in Alberta and therefore competitively priced, significant gas price increases could occur in the future. A 1985 study investigating the alternatives to natural gas as a fuel for steam generation concluded that coal was the most economic alternative, as reserves of subbituminous coal are not only abundant in Alberta but also located relatively close to heavy oil and bitumen production areas. The environmental performance of coal is critical to its acceptance as an alternate fuel to natural gas, and proposed steam generator designs which could burn Alberta coal and control emissions satisfactorily are assessed. Considerations for ash removal, sulfur dioxide sorption, nitrogen oxides control, and particulate emission capture are also presented. A multi-stage slagging type of coal-fired combustor has been developed which is suitable for application with oilfield steam generators and is being commissioned for a demonstration project at the Cold Lake deposit. An economic study showed that the use of coal for steam generation in heavy oil in-situ projects in the Peace River and Cold Lake areas would be economic, compared to natural gas, at fuel price projections and design/cost premises for a project timing in the mid-1990s. 7 figs., 3 tabs

  14. Using Polymer Alternating Gas to Enhance Oil Recovery in Heavy Oil

    Science.gov (United States)

    Yang, Yongzhi; Li, Weirong; Zhou, Tiyao; Dong, Zhenzhen

    2018-02-01

    CO2 has been used to recover oil for more than 40 years. Currently, about 43% of EOR production in U.S. is from CO2 flooding. CO2 flooding is a well-established EOR technique, but its density and viscosity nature are challenges for CO2 projects. Low density (0.5 to 0.8 g/cm3) causes gas to rise upward in reservoirs and bypass many lower portions of the reservoir. Low viscosity (0.02 to 0.08 cp) leads to poor volumetric sweep efficiency. So water-alternating-gas (WAG) method was used to control the mobility of CO2 and improve sweep efficiency. However, WAG process has some other problems in heavy oil reservoir, such as poor mobility ratio and gravity overriding. To examine the applicability of carbon dioxide to recover viscous oil from highly heterogeneous reservoirs, this study suggests a new EOR method--polymer-alternating gas (PAG) process. The process involves a combination of polymer flooding and CO2 injection. To confirm the effectiveness of PAG process in heavy oils, a reservoir model from Liaohe Oilfield is used to compare the technical and economic performance among PAG, WAG and polymer flooding. Simulation results show that PAG method would increase oil recovery over 10% compared with other EOR methods and PAG would be economically success based on assumption in this study. This study is the first to apply PAG to enhance oil recovery in heavy oil reservoir with highly heterogeneous. Besides, this paper provides detailed discussions and comparison about PAG with other EOR methods in this heavy oil reservoir.

  15. The effects of oil shocks on government expenditures and government revenues nexus in Iran (as a developing oil-export based economy)

    NARCIS (Netherlands)

    S.F. Dizaji (Sajjad Faraji)

    2012-01-01

    textabstractThe main purpose of this study is to investigate the dynamic relationship between government revenues and government expenditures in Iran as a developing oil export based economy. Moreover, I want to know how government expenditures and revenues respond to oil price (revenue) shocks. I

  16. Steam injection and enhanced bioremediation of heavy fuel oil contamination

    International Nuclear Information System (INIS)

    Dablow, J.; Hicks, R.; Cacciatore, D.

    1995-01-01

    Steam injection has been shown to be successful in remediating sites impacted by heavy fuel oils. Field demonstrations at both pilot and full scale have removed No. 2 diesel fuel and Navy Special Fuel Oil (No. 5 fuel oil) from impacted soils. Removal mechanisms include enhanced volatilization of vapor- and adsorbed-phase contaminants and enhanced mobility due to decreased viscosity and associated residual saturation of separate- and adsorbed-phase contaminants. Laboratory studies have shown that indigenous biologic populations are significantly reduced, but are not eliminated by steam injection operations. Populations were readily reestablished by augmentation with nutrients. This suggests that biodegradation enhanced by warm, moist, oxygenated environments can be expected to further reduce concentrations of contaminants following cessation of steam injection operations

  17. Microbial enhanced heavy crude oil recovery through biodegradation using bacterial isolates from an Omani oil field.

    Science.gov (United States)

    Al-Sayegh, Abdullah; Al-Wahaibi, Yahya; Al-Bahry, Saif; Elshafie, Abdulkadir; Al-Bemani, Ali; Joshi, Sanket

    2015-09-16

    Biodegradation is a cheap and environmentally friendly process that could breakdown and utilizes heavy crude oil (HCO) resources. Numerous bacteria are able to grow using hydrocarbons as a carbon source; however, bacteria that are able to grow using HCO hydrocarbons are limited. In this study, HCO degrading bacteria were isolated from an Omani heavy crude oil field. They were then identified and assessed for their biodegradation and biotransformation abilities under aerobic and anaerobic conditions. Bacteria were grown in five different minimum salts media. The isolates were identified by MALDI biotyper and 16S rRNA sequencing. The nucleotide sequences were submitted to GenBank (NCBI) database. The bacteria were identified as Bacillus subtilis and B. licheniformis. To assess microbial growth and biodegradation of HCO by well-assay on agar plates, samples were collected at different intervals. The HCO biodegradation and biotransformation were determined using GC-FID, which showed direct correlation of microbial growth with an increased biotransformation of light hydrocarbons (C12 and C14). Among the isolates, B. licheniformis AS5 was the most efficient isolate in biodegradation and biotransformation of the HCO. Therefore, isolate AS5 was used for heavy crude oil recovery experiments, in core flooding experiments using Berea core plugs, where an additional 16 % of oil initially in place was recovered. This is the first report from Oman for bacteria isolated from an oil field that were able to degrade and transform HCO to lighter components, illustrating the potential use in HCO recovery. The data suggested that biodegradation and biotransformation processes may lead to additional oil recovery from heavy oil fields, if bacteria are grown in suitable medium under optimum growth conditions.

  18. Investigation and development of heavy oil upgrading catalysts. 3

    Energy Technology Data Exchange (ETDEWEB)

    Lee, D.K.; Lee, I.C.; Yoon, W.L.; Lee, H.T.; Chung, H.; Hwang, Y.J.; Park, S.H. [Korea Inst. of Energy Research, Taejon (Korea, Republic of)

    1995-12-01

    This study aimed at the domestic development of HDS catalysts which are most fundamental and wide-used in the petroleum refinery. In this year, some experimental works were conducted for developing the effective utilization technology of the novel dispersed-catalysts in the hydro-desulfurization of heavy oils, and improving the reaction performance of alumina-supported Mo-based hydro-treating catalysts conventionally used in most of refineries. First, it was experimentally proved that the dispersed catalysts of Co-Mo could be employed for the hydro-desulfurization of a heavy atmospheric residual oil excluding the catalyst deactivation. The utilization of a carbon-expanded reactor in combination with this dispersed catalyst system exhibited an enhanced reaction performance and provided an efficient way for the separation and recovery of the dispersed catalytic component from oils. Second, the tungsten-incorporated WCoMo/{gamma}-Al{sub 2}O{sub 3} catalyst revealed the improved catalytic performance in the various hydro-treating reactions and in the initial deactivation rates for the high pressure hydro-treatment of a heavy oil as compared with the commercial CoMo/{gamma}-Al{sub 2}O{sub 3} catalyst. This new experimental finding for the promoting role of the monomeric WO{sub 3} species in CoMo/{gamma}-Al{sub 2}O{sub 3} catalyst may be generally applicable to the Mo-based alumina-sulfide phase, higher catalytic activity, and more extended service life. (author). 101 refs., 33 figs., 18 tabs.

  19. Uranium exports could match oil imports. [status and prospects of the Canadian uranium industry

    Energy Technology Data Exchange (ETDEWEB)

    McIntyre, H C

    1977-04-01

    Apart from a temporary embargo while safeguards are negotiated, the Canadian government limits uranium exports so as to guarantee fuel for every Canadian reactor built or planned for 30 years. On the basis of present known reserves of 172 Gg of 'cheap' U/sub 3/O/sub 8/ and 33 of 'dear', that would mean phasing out exports after the mid 1980's, but probably much more 'dear' uranium remains to be discovered. Provincial taxation and restrictions on foreign ownership may be limitations. Discoveries range over eleven areas, but production capacity at present is 14190 Mg/d from Ontario and 3400 from Saskatchewan, with 8800 mothballed and 4860 planned or being rehabilitated. The price has jumped to $95/kg, so that uranium exports may cover half the cost of oil imports. All producers use sulfuric acid leaching, except Eldorado, which uses carbonate leaching; a process using tertiary amine is being developed. Development of the organic-cooled Th//sup 233/U fuelled reactor may greatly extend fuel resources.

  20. Reduction of light oil usage as power fluid for jet pumping in deep heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Chen, S.; Li, H.; Yang, D. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Regina Univ., SK (Canada); Zhang, Q. [China Univ. of Petroleum, Dongying, Shandong (China); He, J. [China National Petroleum Corp., Haidan District, Beijing (China). PetroChina Tarim Oilfield Co.

    2008-10-15

    In deep heavy oil reservoirs, reservoir fluid can flow more easily in the formation as well as around the bottomhole. However, during its path along the production string, viscosity of the reservoir fluid increases dramatically due to heat loss and release of the dissolved gas, resulting in significant pressure drop along the wellbore. Artificial lifting methods need to be adopted to pump the reservoir fluids to the surface. This paper discussed the development of a new technique for reducing the amount of light oil used for jet pumping in deep heavy oil wells. Two approaches were discussed. Approach A uses the light oil as a power fluid first to obtain produced fluid with lower viscosity, and then the produced fluid is reinjected into the well as a power fluid. The process continues until the viscosity of the produced fluid is too high to be utilized. Approach B combines a portion of the produced fluid with the light oil at a reasonable ratio and then the produced fluid-light oil mixture is used as the power fluid for deep heavy oil well production. The viscosity of the blended power fluid continue to increase and eventually reach equilibrium. The paper presented the detailed processes of both approaches in order to indicate how to apply them in field applications. Theoretic models were also developed and presented to determine the key parameters in the field operations. A field case was also presented and a comparison and analysis between the two approaches were discussed. It was concluded from the field applications that, with a certain amount of light oil, the amount of reservoir fluid produced by using the new technique could be 3 times higher than that of the conventional jet pumping method. 17 refs., 3 tabs., 6 figs.

  1. Health Care Expenditure and GDP in Oil Exporting Countries: Evidence From OPEC Data, 1995-2012.

    Science.gov (United States)

    Fazaeli, Ali Akbar; Ghaderi, Hossein; Salehi, Masoud; Fazaeli, Ali Reza

    2015-06-11

    There is a large body of literature examining income in relation to health expenditures. The share of expenditures in health sector from GDP in developed countries is often larger than in non-developed countries, suggesting that as the level of economic growth increases, health spending increase, too. This paper estimates long-run relationships between health expenditures and GDP based on panel data of a sample of 12 countries of the Organization of the Petroleum Exporting Countries (OPEC), using data for the period 1995-2012. We use panel data unit root tests, cointegration analysis and ECM model to find long-run and short-run relation. This study examines whether health is a luxury or a necessity for OPEC countries within a unit root and cointegration framework. Panel data analysis indicates that health expenditures and GDP are co-integrated and have Engle and Granger causality. In addition, in oil countries that have oil export income, the share of government expenditures in the health sector is often greater than in private health expenditures similar developed countries. The findings verify that health care is not a luxury good and income has a robust relationship to health expenditures in OPEC countries.

  2. MIC risk in the Halfdan oil export system quantified with a DNA-based diagnostic tool

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, Jan; Rasmussen, Kim; Andersen, Kenneth [Maersk Oil (Denmark); Holmkvist, Lars [DTI Oil and Gas (Denmark)

    2011-07-01

    The paper presents the risk involved due to microbial influenced corrosion (MIC) using the halfdan oil export system. With growth of assets, scale and microbial fouling, corrosion and souring have increased. Some of the consequences to operators include, safety issues and loss of production. An example of the effects caused by MIC is the Valhall platform in the Norwegian sector, which was shut down for 80 days. Some of the factors causing bacterial growth and MIC are O2, CO2, and H2S, solids. Consideration of four objectives, corrosive products, microbiological activities, microbes, and spatially associating microbes is very important for diagnosing MIC. The objective of the halfdan study was to investigate the corrosion mechanism in the oil export spool section. Observations show severe pitting inside the pipelines. Suggestions for the operator, including the risk assessment of MIC, are given along with a summary of results. It can be concluded that there is a certain need in the industry to understand and act upon MIC.

  3. Experimental study of heavy oil-water flow structure effects on relative permeabilities in a fracture filled with heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Shad, S.; Gates, I.D.; Maini, B.B. [Calgary Univ., AB (Canada). Dept. of Chemical and Petroleum Engineering]|[Alberta Ingenuity Centre for In Situ Energy, Edmonton, AB (Canada)

    2008-10-15

    An experimental apparatus was used to investigate the flow of water in the presence of heavy oil within a smooth-walled fracture. Different flow patterns were investigated under a variety of flow conditions. Results of the experiments were used to determine the accuracy of VC, Corey, and Shad and Gates models designed to represent the behaviour of oil wet systems. The relative permeability concept was used to describe the behaviour of multiple phases flowing through porous media. A smooth-walled plexiglass Hele-Shaw cell was used to visualize oil and water flow. Changes in flow rates led to different flow regimes. The experiment demonstrated that water flowed co-currently in the form of droplets or slugs. Decreases in the oil flow rate enlarged the size of the water droplets as well as the velocity, until eventually the droplets coalesced and became water slugs. Droplet appearance or disappearance directly impacted the oil and water saturation levels. Changes in fluid saturation altered the pressure gradient. Darcy's law for the 2 liquid phases were used to calculate relative permeability curves. The study showed that at low water saturation, oil relative permeability reached as high as 2.5, while water relative permeability was lower than unity. In the presence of a continuous water channel, water drops formed in oil, and the velocity of the drops was lower than their velocity under a discontinuous water flow regime. It was concluded that the Shad and Gates model overestimated oil relative permeability and underestimated water relative permeability. 38 refs., 2 tabs., 9 figs.

  4. Solar-Assisted Fast Cleanup of Heavy Oil Spill by a Photothermal Sponge

    KAUST Repository

    Chang, Jian

    2018-04-16

    Rapid cleanup of heavy oil spill is always considered as a great challenge because the conventional porous oil sorbents cannot efficiently remove them due to the high viscosity of the oil (>1000 mPa·s). In this work, we take advantage of the photothermal effect to heating the heavy oil by using sunlight as energy source to significantly reduce the viscosity of the heavy oil and thus to achieve a fast heavy oil cleanup. A carbon nanotube (CNT) modified polyurethane sponge was fabricated as photothermal sorbent that exhibited superhydrophobicity, superoleophilicity, as well as outstanding absorption capacity of heavy oil. Thanks to the excellent photothermal effect of CNTs, the modified sponge achieved nearly full sunlight absorption (99%). The resulting solar heating effectively reduced the viscosity of the heavy oil, which enabled the modified sponge to quickly absorb heavy oil of 20 times its own weight under sun illumination. This solar-assisted heavy oil sorbent design is promising for future remediation of viscous oil-spills.

  5. Building on comparative experience : the Venezuelan extra-heavy crude oil projects

    International Nuclear Information System (INIS)

    Valentine, T.E.

    2004-01-01

    This paper reviewed legal considerations regarding heavy and extra heavy oil production in both Canada and Venezuela. The paper focused on Venezuela's extra heavy oil projects in the Orinoco Oil Belt, one of the world's largest accumulation of bitumen with an estimated reserve of 1.2 trillion barrels. The paper described the following four projects: the Petrozuata, Cerro Negro, SINCOR, and Hamaca heavy oil projects which are all congressionally approved joint ventures for extra-heavy crudes in the Orinoco Belt. It also described the legal regime which governs heavy oil projects in Venezuela, including the Organic Gaseous Hydrocarbon Law and the Organic Hydrocarbon Law. Twenty congressional conditions which have been imposed were also outlined along with the legal considerations and lessons learned regarding new extra-heavy crude projects under the two legal regimes. 1 fig

  6. The impact of heavy and acid oil production in PETROBRAS downstream area; A influencia dos petroleos pesados e acidos no parque de refino da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Perisse, Juarez Barbosa; Oddone, Maria Regina Rezende; Bela, Donizeti Aurelio Silva [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    PETROBRAS is facing a great challenge processing heavy and acid oils. The low API of the more recent offshore discoveries leads to an increase in vacuum residue yields which is one important component of the fuel oil's 'pool'. The fuel oil demand is expected to decrease along the next years due to natural gas substitution and to environmental issues, generating exceeding fuel oil exportation at low prices. This paper will discuss World and PETROBRAS technological choices to process these oils meeting the required future demand and quality. A comparison among various residue conversion technologies is also presented in this paper focused on the reduction of fuel oil production and on the improvement of diesel / gasoline rate. Another important issue that will be discussed in this paper is related to the different solutions implemented all over the world to deal with the crude acidity problem and the solutions adopted by PETROBRAS. (author)

  7. Radioactivity concentration and heavy metal content in fuel oil and oil-ashes in Venezuela

    International Nuclear Information System (INIS)

    Barros, H.; Sajo-Bohus, L.; Abril, J.M.; Greaves, E.D.

    2004-01-01

    During the last years an intensive national program was developed to determine the environmental radioactivity levels in Venezuela. Gamma dose and the radon concentrations indoors, in drinking water, in caves and in artificial cavities including the effect of radon transported to the surface with the earth gas have been studied. To continue this project the oil and other natural energy resource should be considered. It is expected that the environmental radiation level is modified in regions where the oil industrial activity is more aggressive such as in the Zulia State and the Faja Petrolifera del Orinoco, (Central Region). In these regions Venezuela is producing 1.750 thousand barrels of oil from the near-to-the- surface or deep oil drilling. Petroleum constitutes an important source of energy and as the majority of natural source contains radionuclides and their disintegration products, being U, Ra, Pb, Bi, Po and K the most often encountered. The combustion of petroleum concentrate in the ashes those radioelements, and later enter the environment by different ways producing adverse effects on the quality of man life. The concentration of radioelements varies greatly between oil fields, then we still requiring local survey studies in this area. Moreover due to the recent national interest in recycling processes, it becomes important to take precaution in the selection of materials that may contain by-products of industrial origin, including oil. In fact the oil ashes, oil slurry and other mining by-products are thought to be employable in the building industry. The concentration of radioactivity in the ash from thermoelectric power plants that use petroleum as a primary energy source was determined. The analysis include the two major thermoelectric power plants in Venezuela, Ricardo Zuluaga on the northern sea side of Caracas and Planta Centro on the littoral of Carabobo State. The study cover different samples: fuel oil No 6, ashes, heavy and medium petroleum

  8. Feasibility study of heavy oil recovery in the Midcontinent region (Kansas, Missouri, Oklahoma)

    Energy Technology Data Exchange (ETDEWEB)

    Olsen, D.K.; Johnson, W.I.

    1993-08-01

    This report is one of a series of publications assessing the feasibility/constraints of increasing domestic heavy oil production. Each report covers a select area of the United States. The Midcontinent (Kansas, Nssouri, Oklahoma) has produced significant oil, but contrary to early reports, the area does not contain the huge volumes of heavy oil that, along with the development of steam and in situ combustion as oil production technologies, sparked the area`s oil boom of the 1960s. Recovery of this heavy oil has proven economically unfeasible for most operators due to the geology of the formations rather than the technology applied to recover the oil. The geology of the southern Midcontinent, as well as results of field projects using thermal enhanced oil recovery (TEOR) methods to produce the heavy oil, was examined based on analysis of data from secondary sources. Analysis of the performance of these projects showed that the technology recovered additional heavy oil above what was produced from primary production from the consolidated, compartmentalized, fluvial dominated deltaic sandstone formations in the Cherokee and Forest City basins. The only projects producing significant economic and environmentally acceptable heavy oil in the Midcontinent are in higher permeability, unconsolidated or friable, thick sands such as those found in south-central Oklahoma. There are domestic heavy oil reservoirs in other sedimentary basins that are in younger formations, are less consolidated, have higher permeability and can be economically produced with current TEOR technology. Heavy oil production from the carbonates of central and wester Kansas has not been adequately tested, but oil production is anticipated to remain low. Significant expansion of Midcontinent heavy oil production is not anticipated because the economics of oil production and processing are not favorable.

  9. Oil Prices, Credit Risks in Banking Systems, and Macro-Financial Linkages across GCC Oil Exporters

    Directory of Open Access Journals (Sweden)

    Saleh Alodayni

    2016-11-01

    Full Text Available This paper assesses the effect of the recent 2014–2015 oil price slump on the financial stability in the Gulf Cooperation Council (GCC region. The first objective of this paper is to assess how oil price shock propagates within the macroeconomy and how the macro shocks transmit to GCC banks’ balance sheets. This part of the paper implements a System Generalized Method of Moments (GMM and a Panel Fixed Effect Model to estimate the response of nonperforming loans (NPLs to its macroeconomic determinants. The second objective of this paper is to assess any negative feedback effects between the GCC banking systems and the economy. The paper, therefore, implements a Panel VAR model to explore the macro-financial linkages between GCC banking systems and the real economy. The results indicate that oil price, non-oil GDP, interest rate, stock prices, and housing prices are major determinants of NPLs across GCC banks and the overall financial stability in the region. Credit risk shock tends to propagate disturbances to non-oil GDP, credit growth, and stock prices across GCC economies. A higher level of NPLs restricts banks’ credit growth and can dampen economic growth in these economies. The results support the notion that disturbances in banking systems lead to unwanted economic consequences for the real sector.

  10. Viscoplastic sculpting in stable triple layer heavy oil transport flow

    Science.gov (United States)

    Sarmadi, Parisa; Hormozi, Sarah; A. Frigaard, Ian

    2017-11-01

    In we introduced a novel methodology for efficient transport of heavy oil via a triple layer core-annular flow. Pumping pressures are significantly reduced by concentrating high shear rates to a lubricating layer, while ideas from Visco-Plastic Lubrication are used to eliminate interfacial instabilities. We purposefully position a shaped unyielded skin of a viscoplastic fluid between the transported oil and the lubricating fluid layer to balance the density difference between the fluids. Here we address the sculpting of the shaped skin within a concentric inflow manifold. We use the quasi-steady model to provide inputs to an axisymmetric triple layer computation, showing the development of the streamwise skin profile and establishment of the flow. For this, we use a finite element discretization with the augmented-Lagrangian method to represent the yield surface behaviour accurately and a PLIC method to track the interface motion.

  11. Improving reservoir history matching of EM heated heavy oil reservoirs via cross-well seismic tomography

    KAUST Repository

    Katterbauer, Klemens; Hoteit, Ibrahim

    2014-01-01

    process. While becoming a promising technology for heavy oil recovery, its effect on overall reservoir production and fluid displacements are poorly understood. Reservoir history matching has become a vital tool for the oil & gas industry to increase

  12. Monetary compensations in climate policy through the lens of a general equilibrium assessment: The case of oil-exporting countries

    International Nuclear Information System (INIS)

    Waisman, Henri; Rozenberg, Julie; Hourcade, Jean Charles

    2013-01-01

    This paper investigates the compensations that major oil producers have claimed for since the Kyoto Protocol in order to alleviate the adverse impacts of climate policy on their economies. The amount of these adverse impacts is assessed through a general equilibrium model which endogenizes both the reduction of oil exportation revenues under international climate policy and the macroeconomic effect of carbon pricing on Middle-East's economy. We show that compensating the drop of exportation revenues does not offset GDP and welfare losses because of the time profile of the general equilibrium effects. When considering instead compensation based on GDP losses, the effectiveness of monetary transfers proves to be drastically limited by general equilibrium effects in opened economies. The main channels of this efficiency gap are investigated and its magnitude proves to be conditional upon strategic and policy choices of the Middle-East. This leads us to suggest that other means than direct monetary compensating transfers should be discussed to engage the Middle-East in climate policies. - Highlights: • We endogenize the interplay between climate policy, oil markets and the macroeconomy. • We quantify the transfers to compensate climate policy losses in oil-exporting countries. • We assess the general equilibrium effect of monetary transfers in opened economies. • The macroeconomic efficiency of transfers is altered by general equilibrium effects. • Monetary compensation schemes are not efficient for oil exporters in climate policy

  13. Measurement of molecular diffusion coefficients of carbon dioxide and methane in heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Gu, Y.; Tharanivasan, A.K.; Yang, C. [Regina Univ., SK (Canada)

    2004-07-01

    Vapour extraction (VAPEX) is a solvent-based thermal recovery process which is considered to be a viable process for recovering heavy oil. In order to develop a solvent-based enhanced oil recovery (EOR) operation, it is necessary to know the rate and extent of oil mobilization by the solvent. The molecular diffusion coefficient of solvent gas in heavy oil must be known. In this study, the pressure decay method was used to measure the molecular diffusivity of a gas solvent in heavy oil by monitoring the decaying pressure. The pressure decay method is a non-intrusive method in which physical contact is made between the gas solvent and the heavy oil. The pressure versus time data are measured until the heavy oil reaches complete saturation. The diffusion coefficient can be determined from the measured data and a mathematical model. In this study, the molecular diffusion coefficients of carbon dioxide-heavy oil and methane-heavy oil systems were measured and compared. The experiments were performed in closed high-pressure cells at constant reservoir temperature. An analytical solution was also obtained to predict the pressure in the gas phase and for the boundary conditions at the solvent-heavy oil interface for each solvent. Solvent diffusivity was determined by finding the best match of the numerically predicted and experimentally measured pressures.

  14. Well integrity in heavy oil wells : challenges and solutions

    Energy Technology Data Exchange (ETDEWEB)

    Taoutaou, S.; Osman, T.M.; Mjthab, M. [Schlumberger (Syrian Arab Republic); Succar, N. [Oudeh Petroleum, Damascus (Syrian Arab Republic)

    2010-07-01

    The Oudeh Petroleum Company (OPC) has used cyclic steam (the Huff and Puff technique) since 2006 to produce heavy oil from its OPC field that has an estimated 79.49 to 95.39 million cubic meters of oil contained in the Jurassic and Triassic reservoirs of the Butmah and Kurachine formations in Syria. Accumulations of oil and gas are present in the main Oudeh structure at depths between 1300 and 2250 meters. The Huff and Puff technique involves 3 phases. In the first phase which lasts about 1 month, steam is injected at 348 degrees C and 17.MPa to melt the wax condensate in the formation in order to decrease heavy oil viscosity. Phase 2 involves 3 soaking days. In phase 3, which lasts 2 to 3 months, the production rate is doubled compared to wells without steam. The cycle is then resumed once the pressure drops. The temperature cycling can compromise the well integrity through loss of hydraulic isolation in the cement sheath and thereby reduce hydrocarbon recovery. This paper described how the OPC has managed to achieved complete well integrity using an advanced cement system in more than 200 wells exposed to steam injection temperatures up to 348 degrees C and the associated high induced thermal stresses. The methodology for risk analysis of the cement sheath failure under steam stimulation was described along with the selection criteria for the advanced cement system to withstand temperature cycling. Two case histories involving a 50 well database were presented. 5 refs., 2 tabs., 13 figs.

  15. Proceedings of the World Heavy Oil Congress : unconventional oil challenging conventional expectations

    International Nuclear Information System (INIS)

    2008-01-01

    This international technical and business conference provided a forum to promote heavy oil technology and foster relationships between supply and demand countries. The interactive forum between global industry professionals addressed technological, strategic and environmental challenges facing the unconventional oil industry, including seeking innovative, low cost technologies, driving high costs down; educating and leading the workforce to maintain high standards of production; and ensuring that the footprint on the land is as light as possible. It emphasized that as demand for the uses of heavy oil grows, so does the responsibility of managing sustainability not just from an environmental and social perspective, but also with respect to supply, including manpower and infrastructure. The technical conference featured sessions on advanced and enhanced processes; combustion processes; drilling and completions; geology and reservoir; heavy oil exploitation and development; mining, extraction and transportation; non thermal processes; production and operations; reservoir monitoring; SAGD processes; sustainable development; thermal processes; and, upgrading technology. All 124 presentations from the technical conference were catalogued separately for inclusion in this database. refs., tabs., figs

  16. Residency of rhenium and osmium in a heavy crude oil

    Science.gov (United States)

    DiMarzio, Jenna M.; Georgiev, Svetoslav V.; Stein, Holly J.; Hannah, Judith L.

    2018-01-01

    Rhenium-osmium (Re-Os) isotope geochemistry is an emerging tool for the study of oil formation and migration processes, and a new technology for petroleum exploration. Little is known, however, about the residency of Re and Os within asphaltene and maltene sub-fractions of crude oil. This information is crucial for understanding the 187Re-187Os radiometric clock held in petroleum systems and for interpreting geochronology for key processes such as oil formation, migration, and biodegradation. In this study, a heavy crude oil was separated into soluble (maltene, MALT) and insoluble (asphaltene, ASPH) fractions using n-heptane as the asphaltene-precipitating agent. The asphaltenes were separated sequentially into sub-fractions using two different solvent pairs (heptane-dichloromethane and acetone-toluene), and the bulk maltenes were separated into saturate, aromatic, and resin (SAR) fractions using open column chromatography. Each asphaltene and maltene sub-fraction was analyzed for Re and Os. The asphaltene sub-fractions and the bulk ASPH, MALT, and crude oil were analyzed for a suite of trace metals by ICP-MS. Our results show that Re and Os concentrations co-vary between the asphaltene sub-fractions, and that both elements are found mostly in the more polar and aromatic sub-fractions. Significant Re and Os are also present in the aromatic and resin fractions of the maltenes. However, each asphaltene and maltene sub-fraction has a distinct isotopic composition, and sub-fractions are not isochronous. This suggests that asphaltene sub-fractionation separates Re-Os complexes to the point where the isotopic integrity of the geochronometer is compromised. The mobility of individual Re and Os isotopes and the decoupling possibilities between radiogenic 187Os produced from 187Re remain elusive, but their recognition in this study is a critical first step. Re and Os correlate strongly with Mo and Cd in the asphaltene sub-fractions, suggesting that these metals occupy

  17. Applying CFD in the Analysis of Heavy Oil/Water Separation Process via Hydrocyclone

    OpenAIRE

    K Angelim; A De Lima; J Souza; S Neto; V Oliveira; G Moreira

    2017-01-01

    In recent years most of the oil reserves discovered has been related to heavy oil reservoirs whose reserves are abundant but still show operational difficulties. This fact provoked great interest of the petroleum companies in developing new technologies for increasing the heavy oil production. Produced water generation, effluent recovered from the production wells together with oil and natural gas, is among the greatest potential factors for environmental degradation. Thus, a new scenario of ...

  18. GLOBAL PROSPECTS OF SYNTHETIC DIESEL FUEL PRODUCED FROM HYDROCARBON RESOURCES IN OIL&GAS EXPORTING COUNTRIES

    Directory of Open Access Journals (Sweden)

    Tomislav Kurevija

    2007-12-01

    Full Text Available Production of synthetic diesel fuel through Fischer-Tropsch process is a well known technology which dates from II World War, when Germany was producing transport fuel from coal. This process has been further improved in the South Africa due to period of international isolation. Today, with high crude oil market cost and increased demand of energy from China and India, as well as global ecological awareness and need to improve air quality in urban surroundings, many projects are being planned regarding production of synthetic diesel fuel, known as GTL (Gas To Liquid. Most of the future GTL plants are planned in oil exporting countries, such are Qatar and Nigeria, where natural gas as by-product of oil production is being flared, losing in that way precious energy and profit. In that way, otherwise flared natural gas, will be transformed into synthetic diesel fuel which can be directly used in all modern diesel engines. Furthermore, fossil fuel transportation and distribution technology grid can be used without any significant changes. According to lower emissions of harmful gasses during combustion than fossil diesel, this fuel could in the future play a significant part of EU efforts to reach 23% of alternative fuel share till 2020., which are now mostly relied on biodiesel, LPG (liquefied petroleum gas and CNG (compressed natural gas.

  19. Visualized study of thermochemistry assisted steam flooding to improve oil recovery in heavy oil reservoir with glass micromodels

    NARCIS (Netherlands)

    Lyu, X.; Liu, Huiqing; Pang, Zhanxi; Sun, Zhixue

    2018-01-01

    Steam channeling, one serious problem in the process of steam flooding in heavy oil reservoir, decreases the sweep efficiency of steam to cause a lower oil recovery. Viscosity reducer and nitrogen foam, two effective methods to improve oil recovery with different mechanism, present a satisfactory

  20. The national oil companies and the modernization of tax regimes in oil exporting countries

    International Nuclear Information System (INIS)

    Rodriguez-Padilla, V.

    1994-01-01

    The analysis of tax regimes for oil national companies leads through three conclusions : i) current tax regimes are economically inefficient but they may be corrected without changing the institutional framework ; ii) there is no optimal tax regime but certain principles such as equity, adaptability and neutrality have to be respected; iii) contracts and concessions might be appropriated tools while maintaining the monopoly of the national company but such a choice poses political and ideological problems. (Author). 26 refs., 1 fig., 1 tab

  1. Analysis of domestic price and inflation determinants in Iran (as a developing oil-export based economy)

    NARCIS (Netherlands)

    S.F. Dizaji (Sajjad Faraji)

    2011-01-01

    textabstractAbstract The objective of this study is to examine and investigate both behaviour and determinants of domestic prices and inflation rate in Iran as a developing oil export based economy. I apply two models; the first model is for investigating the main determinants of domestic prices

  2. Clean coal and heavy oil technologies for gas turbines

    Energy Technology Data Exchange (ETDEWEB)

    Todd, D.M. [GE Industrial & Power Systems, Schenectady, NY (United States)

    1994-12-31

    Global power generation markets have shown a steady penetration of GT/CC technology into oil and gas fired applications as the technology has matured. The lower cost, improved reliability and efficiency advantages of combined cycles can now be used to improve the cost of electricity and environmental acceptance of poor quality fuels such as coal, heavy oil, petroleum coke and waste products. Four different technologies have been proposed, including slagging combustors, Pressurized Fluidized Bed Combustion (PFBC), Externally Fired Combined Cycle (EFCC) and Integrated Gasification Combined Cycle (IGCC). Details of the technology for the three experimental technologies can be found in the appendix. IGCC is now a commercial technology. In the global marketplace, this shift is being demonstrated using various gasification technologies to produce a clean fuel for the combined cycle. Early plants in the 1980s demonstrated the technical/environmental features and suitability for power generation plants. Economics, however, were disappointing until the model F GT technologies were first used commercially in 1990. The economic break-through of matching F technology gas turbines with gasification was not apparent until 1993 when a number of projects were ordered for commercial operation in the mid-1990s. GE has started 10 new projects for operation before the year 2000. These applications utilize seven different gasification technologies to meet specific application needs. Early plants are utilizing low-cost fuels, such as heavy oil or petroleum coke, to provide economics in first-of-a-kind plants. Some special funding incentives have broadened the applications to include power-only coal plants. Next generation gas turbines projected for commercial applications after the year 2000 will contribute to another step change in technology. It is expected that the initial commercialization process will provide the basis for clear technology choices on future plants.

  3. Proceedings of the Canadian Heavy Oil Association Conference : Heavy oil, the business of evolution

    International Nuclear Information System (INIS)

    2003-01-01

    gas industry to exchange knowledge about fueling options, emerging technologies for resource recovery, and markets and logistics. Most of the papers were presented in Power-Point format with several viewgraphs depicting processes used mostly to recover bitumen from the tar sand and oil sand deposits in Western Canada. The enhanced recovery methods ranged from chemical recovery and thermal recovery methods such as steam assisted gravity drainage (SAGD) and toe-to-heel air injection (THAI). Separation processes and sorbent recovery methods were also discussed. The conference featured 11 presentations, of which 5 were indexed separately for inclusion in this database. refs., tabs., figs

  4. Sunlight Induced Rapid Oil Absorption and Passive Room-Temperature Release: An Effective Solution toward Heavy Oil Spill Cleanup

    KAUST Repository

    Wu, Mengchun

    2018-05-18

    Rapid cleanup and easy recovery of spilled heavy oils is always a great challenge due to their high viscosity (>103 mPa s). One of the efficient methods to absorb highly viscous oils is to reduce their viscosity by increasing their temperature. In this work, the authors integrate the sunlight‐induced light‐to‐heat conversion effect of polypyrrole (PPy) and thermoresponsive property of poly(N‐isopropylacrylamide) (PNIPAm) into the melamine sponge, which successfully delivers a fast heavy oil absorption under sunlight and passive oil release underwater at room temperature. Thanks to the rationally designed functionalities, the PNIPAm/PPy functionalized sponges possess oleophilicity and hydrophobicity under sunlight. Due to the photothermal effect of PPy, the sponges locally heat up contacting heavy oil under sunlight and reduce its viscosity to a point where the oil voluntarily flow into the pores of the sponge. The material in this work is able to rapidly absorb the heavy oil with room temperature viscosity as high as ≈1.60 × 105 mPa s. The absorbed oil can be passively forced out the sponge underwater at room temperature due to the hydrophilicity of PNIPAm. The sunlight responsive and multifunctional sponge represents a meaningful attempt in coming up with a sustainable solution toward heavy oil spill.

  5. Sunlight Induced Rapid Oil Absorption and Passive Room-Temperature Release: An Effective Solution toward Heavy Oil Spill Cleanup

    KAUST Repository

    Wu, Mengchun; Shi, Yusuf; Chang, Jian; Li, Renyuan; Ong, Chi Siang; Wang, Peng

    2018-01-01

    Rapid cleanup and easy recovery of spilled heavy oils is always a great challenge due to their high viscosity (>103 mPa s). One of the efficient methods to absorb highly viscous oils is to reduce their viscosity by increasing their temperature. In this work, the authors integrate the sunlight‐induced light‐to‐heat conversion effect of polypyrrole (PPy) and thermoresponsive property of poly(N‐isopropylacrylamide) (PNIPAm) into the melamine sponge, which successfully delivers a fast heavy oil absorption under sunlight and passive oil release underwater at room temperature. Thanks to the rationally designed functionalities, the PNIPAm/PPy functionalized sponges possess oleophilicity and hydrophobicity under sunlight. Due to the photothermal effect of PPy, the sponges locally heat up contacting heavy oil under sunlight and reduce its viscosity to a point where the oil voluntarily flow into the pores of the sponge. The material in this work is able to rapidly absorb the heavy oil with room temperature viscosity as high as ≈1.60 × 105 mPa s. The absorbed oil can be passively forced out the sponge underwater at room temperature due to the hydrophilicity of PNIPAm. The sunlight responsive and multifunctional sponge represents a meaningful attempt in coming up with a sustainable solution toward heavy oil spill.

  6. Relation of sulfur with hydrocarbons in Brazilian heavy and extra-heavy crude oil; Relacao do enxofre com os hidrocarbonetos em petroleos pesados e extra pesados brasileiros

    Energy Technology Data Exchange (ETDEWEB)

    Iorio, Sonia Maria Badaro Mangueira; Guimaraes, Regina Celia Lourenco; Silva, Maria do Socorro A. Justo da [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Costa, Alexander Vinicius Moraes da [Fundacao Gorceix, Ouro Preto, MG (Brazil)

    2008-07-01

    As the occurrence of heavy and extra-heavy oils increases sensitively, their participation in the refineries feeding also becomes greater. Heavy oils usually have lower price than a light one, because they produce lower quality derivatives and it's more difficult to meet the specifications. Crude oils are a complex mixture, mostly compounded by carbon and hydrogen and also by impurities like sulfur, nitrogen, oxygen and metals. Sulfur is the third most abundant component of crude oils, following carbon and hydrogen. In general there is a strong positive correlation between the concentrations of polar compounds (aromatics, resins and asphaltenes), and the sulfur content. This work presents graphically sulfur content and polar compounds concentrations for Brazilian and foreign heavy and extra-heavy oils (< 20 deg API). The results of the data analysis indicate that Brazilian crude oils behave differently from foreign heavy and extra-heavy oils. (author)

  7. Acute aquatic toxicity of heavy fuel oils. Summary of relevant test data

    Energy Technology Data Exchange (ETDEWEB)

    Comber, M.I.H.; Den Haan, K.; Djemel, N.; Eadsforth, C.V.; King, D.; Parkerton, T.; Paumen, M.L.; Dmytrasz, B.

    2011-12-15

    This report describes the experimental procedures and results obtained in acute ecotoxicity tests on several heavy fuel oil (HFO) samples. Water accommodated fractions (WAFs) of these samples were tested for toxicity to the rainbow trout (Oncorhynchus mykiss), the crustacean zooplankter (Daphnia magna) and green algae (Selenastrum capricornutum). These results assist in determining the environmental hazard from heavy fuel oil.

  8. Acute aquatic toxicity of heavy fuel oils. Summary of relevant test data

    International Nuclear Information System (INIS)

    Comber, M.I.H.; Den Haan, K.; Djemel, N.; Eadsforth, C.V.; King, D.; Parkerton, T.; Paumen, M.L.; Dmytrasz, B.

    2011-12-01

    This report describes the experimental procedures and results obtained in acute ecotoxicity tests on several heavy fuel oil (HFO) samples. Water accommodated fractions (WAFs) of these samples were tested for toxicity to the rainbow trout (Oncorhynchus mykiss), the crustacean zooplankter (Daphnia magna) and green algae (Selenastrum capricornutum). These results assist in determining the environmental hazard from heavy fuel oil.

  9. Workshop Papers: Directions and Marketing of Synthetic Crude Oil and Heavy Oil

    International Nuclear Information System (INIS)

    1997-01-01

    This workshop was organized by the National Centre for Upgrading Technology in an effort to bring together experts from the various sectors of the petroleum industry to outline their views of the directions that the synthetic crude oil market will pursue over the next decade and into the 21. century. The motivation for the Workshop came from the many announcements during 1996 and 1997 by several Canadian oil companies about plans to initiate or expand their heavy oil and synthetic crude production. During the same period, at least one US refiner also announced plans to revamp an existing refinery to allow it to process Canadian heavy oil and synthetic crude. The workshop was organized to review these plans and to discuss such questions as (1) Would the selected technologies be the familiar carbon rejection or hydrogen addition methods, or would there be radical advanced technologies? (2) Would the products be fully or partially upgraded? (3) How would they be processed in the refinery? (4) Would there be a market? This collection of papers or viewgraphs comprise all the formal presentations given at the workshop. The final section also contains the edited notes recorded during the question and answer periods. refs., tabs., figs

  10. Proceedings of the oil sands and heavy oil technologies conference and exhibition

    International Nuclear Information System (INIS)

    2009-01-01

    This conference provided a forum for oil sands industry leaders to review the current and future state of technology in this frontier environment. Presentations were delivered by key personnel involved in groundbreaking projects with a renewed focus on oil sands technology and equipment, viewed from the strategic level with case studies and reports on application technologies designed to optimize oil sands operations. The presentations addressed a wide range of issues related to the environmental impacts of oil sands processing facilities, including innovative water and wastewater solutions for heavy oil producers for bitumen mining, in-situ and upgrading facilities. New advances in sulphur treatment technologies were highlighted along with technologies designed to increase the energy efficiency and energy consumption rates of upgrader and processing facilities. Advances in carbon dioxide (CO 2 ) capture and storage systems were also discussed along with geopolitical and economic evaluations of the future of the oil sands industry. The conference featured 59 presentations, of which 48 have been catalogued separately for inclusion in this database. refs., tabs., figs

  11. Feasibility study of heavy oil recovery in the Permian Basin (Texas and New Mexico)

    International Nuclear Information System (INIS)

    Olsen, D.K.; Johnson, W.I.

    1993-05-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Permian Basin of West Texas and Southeastern New Mexico is made up of the Midland, Delaware, Val Verde, and Kerr Basins; the Northwestern, Eastern, and Southern shelves; the Central Basin Platform, and the Sheffield Channel. The present day Permian Basin was one sedimentary basin until uplift and subsidence occurred during Pennsylvanian and early Permian Age to create the configuration of the basins, shelves, and platform of today. The basin has been a major light oil producing area served by an extensive pipeline network connected to refineries designed to process light sweet and limited sour crude oil. Limited resources of heavy oil (10'' to 20'' API gravity) occurs in both carbonate and sandstone reservoirs of Permian and Cretaceous Age. The largest cumulative heavy oil production comes from fluvial sandstones of the Cretaceous Trinity Group. Permian heavy oil is principally paraffinic and thus commands a higher price than asphaltic California heavy oil. Heavy oil in deeper reservoirs has solution gas and low viscosity and thus can be produced by primary and by waterflooding. Because of the nature of the resource, the Permian Basin should not be considered a major heavy oil producing area

  12. Research and development in heavy and extra heavy oil upgrading in PDVSA-Intevep: aqua conversion

    International Nuclear Information System (INIS)

    Pereira, Pedro; Machin, Ivan; Salerno, Gladys; Cotte, Edgar; Higuerey, Ingrid; Andriollo, Antida; Cordova, Jose; Zacarias, Luis; Marzin, Roger; Rivas, Guaicaipuro

    1999-01-01

    After twenty five years of Intevep's creation, is now a good time to revise, from a technical and conceptual perspective, some of the ideas developed in one of the activities that this institution has more persistently sustained. The referred activity targets at the generation of new processes for the upgrading of the bitumen or extra heavy crude oils that Venezuela possesses. This revision concludes in an eclectic synthesis method for the selection and harmonization of the various different advances made through the research performed on processes such as HDH, coking, visbreaking, partial or selective steam reforming and others. Thus, from conceptually different research perspectives a new PDVSA's process already known as as aqua conversion has been assembled. The deepening in the use of this methodology may lead to other new and better upgrading technologies or to improve the existing for the same. All this keeping in mind that whatever these technologies are proprietary or from third parties is of low relevance in front of the mayor objective of commercializing the wide extra heavy oil reservoirs of this country

  13. Improving Oil Recovery (IOR) with Polymer Flooding in a Heavy-Oil River-Channel Sandstone Reservoir

    OpenAIRE

    Lu, Hongjiang

    2009-01-01

    Most of the old oil fields in China have reached high water cut stage, in order to meet the booming energy demanding, oil production rate must be kept in the near future with corresponding IOR (Improving Oil Recovery) methods. Z106 oilfield lies in Shengli Oilfields Area at the Yellow River delta. It was put into development in 1988. Since the oil belongs to heavy oil, the oil-water mobility ratio is so unfavourable that water cut increases very quickly. Especially for reservoir Ng21, the san...

  14. Worldwide cheap and heavy oil productions: A long-term energy model

    International Nuclear Information System (INIS)

    Guseo, Renato

    2011-01-01

    Crude oil, natural gas liquids, heavy oils, deepwater oils, and polar oils are non-renewable energy resources with increasing extraction costs. Two major definitions emerge: regular or 'cheap' oil and non-conventional or 'heavy' oil. Peaking time in conventional oil production has been a recent focus of debate. For two decades, non-conventional oils have been mixed with regular crude oil. Peaking time estimation and the rate at which production may be expected to decline, following the peak, are more difficult to determine. We propose a two-wave model for world oil production pattern and forecasting, based on the diffusion of innovation theories: a sequential multi-Bass model. Historical well-known shocks are confirmed, and new peaking times for crude oil and mixed oil are determined with corresponding depletion rates. In the final section, possible ties between the dynamics of oil extraction and refining capacities are discussed as a predictive symptom of an imminent mixed oil peak in 2016. - Highlights: → Production of conventional and non-conventional oils in aggregate time series. → Decomposition modelling and forecasting with a multi-regime model. → Diffusion of innovation theories and appropriateness of applying Bass concepts to the extraction of oil resources. → Partially overlapping oil extraction processes. → Refining capacities and dynamics of oil extraction.

  15. Letting Off Steam and Getting Into Hot Water - Harnessing the Geothermal Energy Potential of Heavy Oil Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Teodoriu, Catalin; Falcone, Gioia; Espinel, Arnaldo

    2007-07-01

    The oil industry is turning its attention to the more complex development of heavy oil fields in order to meet the ever increasing demands of the manufacturing sector. The current thermal recovery techniques of heavy oil developments provide an opportunity to benefit from the geothermal energy created during the heavy oil production process. There is scope to improve the current recovery factors of heavy oil reservoirs, and there is a need to investigate the associated geothermal energy potential that has been historically neglected. This paper presents a new concept of harnessing the geothermal energy potential of heavy oil reservoirs with the co-production of incremental reserves. (auth)

  16. Challenges of executing heavy oil projects in today's market

    International Nuclear Information System (INIS)

    Brunka, G.

    2001-01-01

    Alberta's industrial project scene from 1981 to 2000 was presented in this power point presentation with particular focus on proposed bitumen recovery projects and heavy oil project challenges. A graph depicting GTG world orders by region (Americas, Asia and Europe) showed that U.S. market continues to drive global growth. Major industrial projects in Alberta were highlighted and employment requirements by sector were outlined. In addition, mitigation measures that are needed to successfully deal with the unique challenges of today's market were described. It was noted that in recent years lower capital expenditure by the industry in general has resulted in corporate downsizing or mergers which in turn have resulted in lower technical and operational knowledge. Some of the current challenges facing the industry are new demands for water treatment expertise and an aging workforce. It was concluded that effective mitigation will require a disciplined approach within a flexible framework.1 tab., 7 figs

  17. Heavy oil reservoirs recoverable by thermal technology. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Kujawa, P.

    1981-02-01

    This volume contains reservoir, production, and project data for target reservoirs thermally recoverable by steam drive which are equal to or greater than 2500 feet deep and contain heavy oil in the 8 to 25/sup 0/ API gravity range. Data were collected from three source types: hands-on (A), once-removed (B), and twice-removed (C). In all cases, data were sought depicting and characterizing individual reservoirs as opposed to data covering an entire field with more than one producing interval or reservoir. The data sources are listed at the end of each case. This volume also contains a complete listing of operators and projects, as well as a bibliography of source material.

  18. The Importance of Target Market Selection for More Profitable Olive Oil Exports by Turkey: A Case Study

    Directory of Open Access Journals (Sweden)

    Mustafa METE

    2015-12-01

    Full Text Available In this study, the quotas and taxes implemented by EU to Turkey were examined and it was observed that these policies have negative effects on Turkey’s olive oil exports. Due to the restrictive policies and low profitability in the entry to the EU market, it was determined that Turkey should be directed to the markets that have higher profitability compared with the exports to EU countries. These detections were carried out in accordance with the information obtained from International Trade Center (ITC and Market Access Database (MAD. As a result of the detections it has been found that exports to the EU countries are more profitable and the entry to the market is easier than to the US. As a result of the researches in ITC and MAD databases, actual companies in oil imports in the US market have been determined and it has shown by examining a bill of loading sample that the firms that make olive oils exports in Turkey easily enter new target markets if they know the usage of the databases

  19. Transformation of heavy gas oils derived from oil sands to petrochemical feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Du Plessis, D.; Laureshen, C. [Alberta Energy Research Inst., Edmonton, AB (Canada)

    2006-07-01

    Alberta's petrochemical industry is primarily based on ethane. However, ethane could potentially impede future growth of Alberta's petrochemical industry because of increasing cost and diminishing supplies. Alternately, the rapidly growing oil sands production could provide abundant new feedstocks. Different integration schemes and technologies were evaluated in this study. Research on converting bitumen-derived heavy gas oil into petrochemical feedstock has resulted in the development of two novel technologies and process integration schemes, notably the NOVA heavy oil laboratory catalyst (NHC) process and the aromatic ring cleavage (ARORINCLE) process. This paper described progress to date on these two projects. The paper presented the experimental results for each scheme. For the ARORINCLE process, results were discussed in terms of the effect of process parameters on the hydrogenation step; effect of process parameters on the ring cleavage step; and integrating the upgrading and petrochemical complex. Early laboratory stage results of these two technologies were found to be encouraging. The authors recommended that work should progress to larger scale demonstration of the NHC and ARORINCLE technologies., 13 refs., 2 tabs., 5 figs.

  20. COMPETITIVE POSITION OF THE MAIN PRODUCERS AND EXPORTERS OF OILSEEDS AND VEGETABLE OILS IN THE INTRA-EU TRADE

    Directory of Open Access Journals (Sweden)

    Karolina Pawlak

    2014-09-01

    Full Text Available The aim of the paper was to assess the competitive position of the main producers and exporters of oilseeds and vegetable oils in the intra-EU trade in 2004 and 2012. The competitiveness was assessed with the use of a selected set of quantitative measures of international competitive position. Moreover, some shares of the analysed countries in the intra-EU trade, as well as relative export intensity of oilseeds and vegetable oils in these countries were estimated. On the basis of the conducted analyses it is possible to conclude that apart from Germany in trade in rapeseed and soya beans, as well as the Netherlands in trade in rapeseed and sunflower-seed, the main producers and exporters of oilseeds were competitive on the Single European Market. Excluding soya-bean oil produced in the EU mainly from imported raw material, competitive advantage of most of the countries decreased together with the level of processing and was lower in trade in vegetable oils.

  1. A New Model for Describing the Rheological Behavior of Heavy and Extra Heavy Crude Oils in the Presence of Nanoparticles

    Directory of Open Access Journals (Sweden)

    Esteban A. Taborda

    2017-12-01

    Full Text Available The present work proposes for the first time a mathematical model for describing the rheological behavior of heavy and extra-heavy crude oils in the presence of nanoparticles. This model results from the combination of two existing mathematical models. The first one applies to the rheology of pseudoplastic substances, i.e., the Herschel-Bulkley model. The second one was previously developed by our research group to model the rheology of suspensions, namely the modified Pal and Rhodes model. The proposed model is applied to heavy and extra heavy crude oils in the presence of nanoparticles, considering the effects of nanoparticles concentration and surface chemical nature, temperature, and crude oil type. All the experimental data evaluated exhibited compelling goodness of fitting, and the physical parameters in the model follow correlate well with variations in viscosity. The new model is dependent of share rate and opens new possibilities for phenomenologically understanding viscosity reduction in heavy crude by adding solid nanoparticles and favoring the scale-up in enhanced oil recovery (EOR and/or improved oil recovery (IOR process.

  2. A fundamental research for upgrading heavy oil using syngas as hydrogen source

    Energy Technology Data Exchange (ETDEWEB)

    Yan, D.; Yuan, M.; Sun, X.; Zhao, S. [China Univ. of Petroleum, Beijing (China). State Key Laboratory of Heavy Oil Processing

    2006-07-01

    The stock of heavy oil and residue from petroleum fractions has become more important as a component in supplying demands for fuel and petrochemical feeds. Finding economical means of upgrading heavy oils is extremely important in order to ensure future fuel supply. A number of new technologies for upgrading heavy oils have been evaluated, including residual fluid catalytic cracking (RFCC), hydrogenation, thermal conversion, and solvent deasphalting. However, the commercial application of such technologies is mainly constrained by the metal and residual carbon concentrations that are present in all heavy oils. Conventional technologies used to upgrade vacuum residue (VR) result in heavy coke formation, with a consequential reduction in the life of expensive, high-performance catalysts. The hydro upgrading process can significantly remove the concentration of heteroatom such as sulfur, nitrogen, and metals in the liquid products. This paper investigated upgrading of heavy oil using syngas as an alternative hydrogen source with a dispersed catalyst. The paper discussed the experiment with reference to the feedstock and catalyst precursors; finely dispersed catalysts preparation; experimental apparatus; experimental design and procedure; and analysis. The results were presented in terms of effects of catalyst dispersion; effect of hydro-upgrading heavy oil using syngas as alternative source; and effects of different catalysts on residue hydrocracking. Last, the paper discussed the properties of the hydrocracked oil treated with syngas. The study confirmed the effectiveness of the slurry bed hydrocracking catalyst using syngas as a hydrogen source. 23 refs., 8 tabs., 16 figs.

  3. Social and economic vulnerability indicators for oil exporting countries: methodology and comparison analysis; Indicadores de vulnerabilidade socioeconomica para paises exportadores de petroleo: metodologia e analise comparativa

    Energy Technology Data Exchange (ETDEWEB)

    Jesus, Fernanda Delgado de

    2009-04-15

    The oil exporting countries can be vulnerable to this row-material as the oil importing ones, due to their social economic dependence of the revenues generated by the oil and gas sector. So, it is also important for those countries the analysis of their social economic vulnerability in order to contribute for the comprehension of their real actions related to their production strategies, aiming to affect oil price and market-share. Due to that, this thesis proposes a methodology based on social economic indicators of oil exporting countries, which will enclose the following aspects: physical, productive, commercial, macro economic, fiscal and social. These indicators will be applied to the OPEC members, Norway and Mexico, and orientated through a normalized scale as in a multicriteria methodology (AHP - Analytic Hierarchy Process). The analyzed results will drive the social economic implications, and the studied countries will be classified in a scale that goes from very favorable to very unfavorable. The results point the main social economic fragilities of the oil exporting countries, designing pathways to Brazil and their possible exporting ambitions. The most important considerations that became from the vulnerable oil export countries experiences refers to the necessity to straight and increases their macro economic foundations, industrial diversification incentives and the creation of an stabilization fund (based on oil revenues) for the future generations, or to severe oil prices oscillations periods in the international market (author)

  4. Upgrading of heavy crude oil with supported and unsupported transition metals

    Energy Technology Data Exchange (ETDEWEB)

    Nares, H.R.; Schacht-Hernandez, P.; Cabrera-Reyes, M.C.; Ramirez-Garnica, M.; Cazarez-Candia, O. [Instituto Mexicano del Petroleo, Atepehuacan (Mexico)

    2006-07-01

    Heavy crude oil presents many problems such as difficulty in transportation, low processing capacity in refineries, and low mobility through the reservoir due to high viscosity which affects the index of productivity of the wells. Because of these challenges, it is necessary to enhance heavy crude oil, both aboveground and underground. The effects of several metallic oxides used to upgrade heavy crude oil properties were examined in order to increase the mobility of reservoir oil by reducing viscosity and improving the quality of the oil. This can be accomplished by reducing the asphaltene and sulfur contents and increasing the American Petroleum Institute (API) gravity using transition metal supported in alumina and unsupported from transition metals derived from either acetylacetonate or alkylhexanoate in liquid phase homogeneously mixed with heavy crude oil as well as metal transition supported in alumina. KU-H heavy crude oil from the Golf of Mexico was studied. The results were obtained by Simulated Distillation and True Boiling Point (TBP). It was concluded that the use of crude oil thermal hydrocracking allowed the API gravity to increase and considerably reduce the viscosity. As a result, the productivity index in wells was increased. However there is a high formation of coke that could damage the conductivity of the rock and then reduce the potential of oil recovery. 27 refs., 3 tabs., 5 figs.

  5. In situ upgrading of heavy oil under steam injection with tetralin and catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Mohammad, A.A. [Texas A and M Univ., College Station, TX (United States); Mamora, D.D. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Texas A and M Univ., College Station, TX (United States)

    2008-10-15

    Steam injection has become the most successful thermal recovery method for heavy oil production. Heavy oil refineries use upgrading processes to improve oil quality. They generally involve the use of catalysts that are used to remove heavy metals, sulfur and nitrogen, or used in hydro-treating and hydro-cracking. In-situ upgrading is thought to have advantages over conventional surface upgrading technology. Experiments were performed to verify the feasibility of in-situ upgrading of heavy crude oil. A hydrogen donor called tetralin was used along with an organometallic catalyst, at steam injection temperatures and pressures normally encountered in the field. Crude oil from the Jobo Oil Field, located in Venezuela was used. The paper described the experimental methodology with reference to the injection cell; fluid injection system; fluid production system; data measurement and recording system; and experimental procedure. It also discussed the extent of upgrading by comparing the properties of the original and produced oil. Oil properties that were measured and compared included hydrogen-to-carbon ratio; heavy metal content; viscosity; and API gravity. The paper also presented a comparison of oil recovery and fluid production between all cases. It was concluded that in the field, the reaction time was significantly longer than encountered in the experiments and may lead to further upgrading, assuming the catalyst could be dispersed in the formation. 10 refs., 1 tab., 9 figs.

  6. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    Energy Technology Data Exchange (ETDEWEB)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. It was hoped that the successful application of these technologies would result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs.

  7. Renewable and non-renewable energy consumption and economic growth: Evidence from MENA Net Oil Exporting Countries.

    OpenAIRE

    Kahia, Montassar; Ben Aissa, Mohamed Safouane

    2014-01-01

    This study investigate the relationship between renewable and non-renewable energy consumption and economic growth in a sample of 13 MENA Net Oil Exporting Countries covering the period 1980–2012 within a multivariate panel framework. The Pedroni (1999, 2004), Kao (1999) as well as the Westerlund (2007) panel cointegration tests indicate that there is a long-run equilibrium relationship between real GDP, renewable energy consumption, non-renewable energy consumption, real gross fixed capital ...

  8. The Parallel Market for Foreign Exchange in an Oil Exporting Economy; The Case of Iran, 1978-1990

    OpenAIRE

    Adnan Mazarei

    1995-01-01

    This paper provides a model for the determination of the parallel market exchange rate premium in a country where oil export earnings accrue directly to the government, and foreign exchange is centrally allocated for the importation of specific goods. Next, it studies the parallel market for foreign exchange In the Islamic Republic of Iran during the period 1978-90. The paper then examines the various time series properties of parallel market exchange rate in Iran, and the evidence of the rol...

  9. Analysis of the impact of the Kyoto Protocol on the export revenues of OPEC member states and on the oil import requirements of non-Annex I countries

    NARCIS (Netherlands)

    Linden NH van der; Linde C van der; Lako P; Rooijen SNM van; Netherlands Energy Research; Netherlands Institute of International Relations; NOP

    2000-01-01

    The members of the Organisation of Petroleum Exporting Countries (OPEC) continue to voice their concerns about the adverse impact of the implementation of greenhouse gas emission reduction policies on the oil exporting countries. Referring to Article 4.8 of the UNFCCC, the OPEC is of the opinion

  10. Design and implementation of a caustic flooding EOR pilot at Court Bakken heavy oil reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Xie, J.; Chung, B.; Leung, L. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Nexen Inc., Calgary, AB (Canada)

    2008-10-15

    Successful waterflooding has been ongoing since 1988 at the Court Bakken heavy oil field in west central Saskatchewan. There are currently 20 injectors and 28 active oil producers in the Court main unit which is owned by Nexen and Pengrowth. The Court pool has an estimated 103.8 mmbbl of original oil in place (OOIP), of which 24 per cent has been successfully recovered after 20 years of waterflooding. A high-level enhanced oil recovery (EOR) screening study was conducted to evaluate other EOR technologies for a heavy oil reservoir of this viscosity range (17 degrees API). Laboratory studies showed that caustic flooding may enhance oil recovery after waterflooding at the Court Bakken heavy oil pool. A single well test demonstrated that caustic injection effectively reduced residual oil saturation. A sector model reservoir simulation revealed that caustic flood could achieve 9 per cent incremental oil recovery in the pilot area. Following the promising laboratory results, a successful caustic flood pilot was implemented at Court heavy oil pool where the major challenges encountered were low reservoir pressure and water channeling. 6 refs., 2 tabs., 6 figs.

  11. PM From the Combustion of heavy fuel oils

    KAUST Repository

    Elbaz, Ayman M.

    2018-03-30

    This work presents an experimental study investigating the formation and oxidation of particulate matter from the combustion of heavy fuel oil, HFO, droplets. The study includes results from both a falling droplet in a drop tube furnace and a suspended droplet in a heated convective flow. The falling droplets in a heated coflow air with variable temperature path and velocity were combusted and the resulting particles, cenospheres, were collected. To characterize the microstructure of these particles, scanning electron microscopy (SEM), and energy dispersive X-Ray (EDX) analysis were used. The particles were found to have either a porous or a skeleton/membrane morphology. The percentage of particles of either type appears to be related to the thermal history, which was controlled by the heated co-flow velocity. In the suspended droplet experiments, by suspending the droplet on a thermocouple, the temperature inside the droplet was measured while simultaneously imaging the various burning phases. A number of specific phases were identified, from liquid to solid phase combustion are presented and discussed. The droplet ignition temperature was seen to be independent of the droplet size. However, the liquid phase ignition delay time and the droplet lifetime were directly proportional to the initial droplet diameter.

  12. Trace metals in heavy crude oils and tar sand bitumens

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J.G.

    1990-11-28

    Fe, Ni, and V are considered trace impurities in heavy crude oils and tar sand bitumens. In order to understand the importance of these metals, we have examined several properties: (1) bulk metals levels, (2) distribution in separated fractions, (3) size behavior in feeds and during processing, (4) speciation as a function of size, and (5) correlations with rheological properties. Some of the results of these studies show: (1) V and Ni have roughly bimodal size distributions, (2) groupings were seen based on location, size distribution, and Ni/V ratio of the sample, (3) Fe profiles are distinctively different, having a unimodal distribution with a maximum at relatively large molecular size, (4) Fe concentrations in the tar sand bitumens suggest possible fines solubilization in some cases, (5) SARA separated fractions show possible correlations of metals with asphaltene properties suggesting secondary and tertiary structure interactions, and (6) ICP-MS examination for soluble ultra-trace metal impurities show the possibility of unexpected elements such as U, Th, Mo, and others at concentrations in the ppB to ppM range. 39 refs., 13 figs., 5 tabs.

  13. Design of the PE-3 hot heavy oil loading line

    Energy Technology Data Exchange (ETDEWEB)

    Mayants, Alex; Lanan, Glenn; Janardhanan, K. [INTEC Engineering, Houston, TX (United States); Gomes, Marcelino; Garcia, Amaury [TRANSPETRO - PETROBRAS Transportes, Rio de Janeiro, RJ (Brazil)

    2003-07-01

    The leaking of the PE-2 pipeline into Guanabara Bay. Rio de Janeiro, during late 2000 attracted widespread attention in Brazil and around the world. The safe design and operation of pipelines transporting hot, heavy hydrocarbons is critical for avoiding future oil spills. Conventional methods for designing pipelines that transport hot products rely on soil overburden to control upheaval buckling. However, extremely poor soil strength, combined with sediment mobility, led to the failure of the PE-2 pipeline. The serious consequences led TRANSPETRO to specify that the highest standards (DNV Safety Class High) were to be applied to the design and fabrication of the replacement PE-3 pipeline. The design was also required to withstand a large number of operational cycles, i.e. three (3) hot to cold cycles per week for the entire 40 years of the pipeline's design life. To meet these design challenges, several pipeline configurations were examined. A unique zigzag configuration was selected for this pipeline project. (author)

  14. New Procedure to Develop Lumped Kinetic Models for Heavy Fuel Oil Combustion

    KAUST Repository

    Han, Yunqing; Elbaz, Ayman M.; Roberts, William L.; Im, Hong G.

    2016-01-01

    A new procedure to develop accurate lumped kinetic models for complex fuels is proposed, and applied to the experimental data of the heavy fuel oil measured by thermogravimetry. The new procedure is based on the pseudocomponents representing

  15. New technology for producing petrochemical feedstock from heavy oils derived from Alberta oil sands

    International Nuclear Information System (INIS)

    Oballa, M.; Simanzhenkov, V.; Clark, P.; Laureshen, C.; Plessis du, D.

    2006-01-01

    This paper presented the results of a study demonstrating the feasibility of producing petrochemical feedstock or petrochemicals from vacuum gas oils derived from oil sands. A typical bitumen upgrader flow scheme was integrated with several new technologies and coupled with an ethane/propane cracker. Technologies included steam cracking, fluid catalytic cracking (FCC); and the catalytic pyrolysis process (CPP). The scheme was then integrated with the Nova Heavy Oil Cracking (NHC) technology. The NHC process uses a reactor to perform catalytic cracking followed by a main tower that separates gas and liquid products. Aromatic ring cleavage (ARORINCLE) technology was explored as a method of catalytic treatment. Experimental runs were conducted in a laboratory scale fixed bed reactor. A stacked catalyst bed was used, followed by a zeolite-based noble metal catalyst. Examples from process run results were presented. Results indicated that the NHC technology should be used on an FCC unit technology platform. The ARORINCLE technology was considered for use on a hydrotreating unit technology platform. Once the catalysts are fully developed and demonstrated, the economics of the technologies will be enhanced through the construction of world-scale complexes integrating upgrading, refining and petrochemical plants. refs., tabs., figs

  16. Refining fuels of the heavy gas--oil type

    Energy Technology Data Exchange (ETDEWEB)

    Bruzac, J F.A.

    1930-01-28

    This invention has for its object the production of a new type of gas-oil fuel, obtained from crude petroleum, shale oil, and peat oil, according to the method of treatment mentioned, by means of which is obtained from gas oil, shale oil, lignite oil, and peat oil (deprived of asphaltic, and bituminous, resinous, and sulfur compounds), a fuel suitable for running Diesel, Junkers, and Clerget motors and all others of the same kind, by diminishing considerably the fouling and attack on the metal.

  17. Organic geochemistry of heavy/extra heavy oils from sidewall cores, Lower Lagunillas Member, Tia Juana Field, Maracaibo Basin, Venenzuela

    Energy Technology Data Exchange (ETDEWEB)

    Tocco, R.; Alberdi, M. [PDVSA-Inteveo S.A., Caracas (Venezuela)

    2002-10-01

    The study of 22 oils from sidewall cores taken at different depths in the Lower Lagunillas Member, well LSJ-AB, Tia Juana Field, Maracaibo Lake is presented, with the purpose of predicting the intervals that present the best crude oil quality. Differences were detected in the biodegradation levels of the studied samples, which are correlated with the depth at which the sidewall core was taken. The API gravity was considered for the oils from each sidewall core and it was found that toward the top of the sequence, the oils have an API gravity of 10.6-11.2{sup o}C, while toward the base part of the sequence, the well produces extra heavy oils with an API gravity that varies between 8.2 and 8.7{sup o}. 12 refs., 5 figs., 1 tab.

  18. Case study in Venezuela : performance of multiphase meter in extra heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Marin, A. [Petroleos de Venezuela SA, Caracas (Venezuela); Bornia, O.; Pinguet, B. [Schlumberger Canada Ltd., Edmonton, AB (Canada)

    2008-10-15

    The performance of a multiphase meter that combines Venturi and multi energy gamma rays was investigated during operation in an extra heavy oil field in Venezuela. The Orocual field in Monagas is one of the most diverse oilfields in Venezuela. It produces gas condensate, light and medium oil and has recently started to produce from a heavy and extra-heavy oil reservoir, with a gravity between 8.6 and 11 API and a viscosity range from 6 Pa.s to more than 20 Pa.s at line conditions. Petroleos de Venezuela SA (PDVSA) is currently using cold production systems in this field. PDVSA attempted to estimate the liquid flow rate using conventional storage tanks but was unable to evaluate the gas production in such an environment of low GOR with emulsion, large amounts of foam and high viscosity. Since the density of heavy oil is close to the density of water, gravity separation cannot be applied. Also, since heavy oil is very viscous, proper separation requires a long retention time, which is not feasible in terms of space or economy. In addition, gas bubbles could not flow freely and remained as a gas phase trapped inside the liquid, resulting in an overestimation of some of the liquid flow rate. In order to measure the field's oil, water and gas flow rates, PDVSA tried several multiphase meters but found that a Venturi and multi energy gamma ray combination was the only solution able to accurately measure multiphase flow in its extra heavy oil. A test demonstrated that, compared to a tank system, the overall uncertainty of the Venturi combination was better than 2 per cent. This extended the operating envelope for PDVSA for using this multiphase metering technology, providing the capability to monitor and optimize in real-time the production in this extra heavy oil field. 15 refs., 10 figs.

  19. Process for gasification of heavy hydrocarbons or salvaged oil. [German patent

    Energy Technology Data Exchange (ETDEWEB)

    Koch, C

    1978-09-14

    The invention refers to the separation of solids which are carried over during evaporation of salvaged oil (oil recovered from used oil or fat). They are removed by exposing the oil vapour to an acceleration of 500 g to 20,000g in a hot gas cyclone. Subsequently the cleaned gas is converted to fission gas in a fission gas generator using an air-water gas mixture and is taken to the combustion equipment. By this process salvaged oil and heavy hydrocarbons can be used for burning in Diesel engines without previous refining.

  20. Proceedings of the 2002 Petroleum Society of CIM/SPE/CHOA International Thermal Operations and Heavy Oil Symposium, International Conference on Horizontal Well Technology, and Canadian Heavy Oil Association Business Conference : Resources 2 Reserves 2 Results. CD ROM ed.

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    This three day conference combined the Petroleum Society's International Horizontal Well and Technology Conference, the Society of Petroleum Engineer's (SPE) International Thermal Operations and Heavy Oil Symposium, and the Canadian Heavy Oil Association's (CHOA) Annual Business Meeting. The 87 presentations covered all aspects of heavy oil, thermal, and horizontal well technology from geosciences and drilling to economics and environment. The themes included financing, turning projects into results, eliminating the downstream barriers to oil sand development in North America and the world, and emerging technologies for horizontal or heavy oil applications. The conference included the following 20 sessions: (1) thermal operations/engineering, (2) well testing/productivity of horizontal wells, (3) heavy oil operations, (4) environmental aspects of heavy oil projects, (5) upgrading/pipelines, (6) economics and project appraisal, (7) simulation studies of thermal projects, (8) multilaterals, (9) horizontal wells in conventional reservoirs, (10) cold production of heavy oil, (11) horizontal drilling in thermal projects, (12) simulation studies of horizontal wells, (13) horizontal drilling technology, (14) thermal field studies and horizontal wells in heavy oil, (15) completion/production technology of horizontal and thermal wells, (16) physics and PVT of heavy oil recovery processes, (17) reservoir characterization/geosciences, (18) horizontal injectors/produced water technology, (19) emerging technologies, and (20) reservoir geomechanics/fracturing. Tutorials were also organized to provide opportunity to review areas that have undergone major changes. A total of 73 papers were indexed separately for inclusion in the database. refs., tabs., figs.

  1. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Process

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Yanis C.; Akkutlu, Yucel; Amilik, Pouya; Kechagia, Persefoni; Lu, Chuan; Shariati, Maryam; Tsimpanogiannis, Ioannis; Zhan, Lang

    2000-01-19

    The emphasis of this work was on investigating the mechanisms and factors that control the recovery of heavy oil, with the objective to improve recovery efficiencies. For this purpose, the interaction of flow, transport and reaction at various scales (from the pore-network to the field scales) were studied. Particular mechanisms investigated included the onset of gas flow in foamy oil production and in in-situ steam drive, gravity drainage in steam process, the development of sustained combustion fronts and the propagation of foams in porous media. Analytical, computational and experimental methods were utilized to advance the state of the art in heavy oil recovery. Successful completion of this research was expected to lead to improvements in the recovery efficiency of various heavy oil processes.

  2. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Processes; SEMIANNUAL

    International Nuclear Information System (INIS)

    Yorstos, Yanis C.

    2002-01-01

    The emphasis of this work was on investigating the mechanisms and factors that control the recovery of heavy oil with the objective to improve recovery efficiencies. For this purpose the interaction of flow transport and reaction at various scales from the pore network to the field scales were studied. Particular mechanisms to be investigated included the onset of gas flow in foamy oil production and in in-situ steam drive, gravity drainage in steam processes, the development of sustained combustion fronts and the propagation of foams in porous media. Analytical, computational and experimental methods were utilized to advance the state of the art in heavy oil recovery. Successful completion of this research was expected to lead to improvements in the Recovery efficiency of various heavy oil processes

  3. Increasing Heavy Oil in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies. Annual Report, March 30, 1995--March 31, 1996

    International Nuclear Information System (INIS)

    Allison, Edith

    1996-12-01

    The objective of this project is to increase heavy oil reserves in a portion of the Wilmington Oil Field, near Long Beach, California, by implementing advanced reservoir characterization and thermal production technologies. Based on the knowledge and experience gained with this project, these technologies are intended to be extended to other sections of the Wilmington Oil Field, and, through technology transfer, will be available to increase heavy oil reserves in other slope and basin clastic (SBC) reservoirs

  4. Development of a purification system at Dhruva to treat oil contaminated and chemically impure heavy water

    International Nuclear Information System (INIS)

    Suttraway, S.K.; Mishra, V.; Bitla, S.V.; Ghosh, S.K.

    2006-01-01

    Dhruva, a 100 MW (thermal) Research reactor uses Heavy Water as moderator, reflector and coolant. Normally during plant operation, the Heavy water from the system gets removed during operational and maintenance activities and this collected heavy water gets degraded and contaminated in the process. The degraded heavy water meeting the chemical specification requirement of the up gradation plant is sent for up gradation. Part of the Heavy water collected is contaminated with various organic and inorganic impurities and therefore cannot be sent for IP up gradation as it does not meet the chemical specification of the up gradation plant. This contaminated Heavy water was being stored in SS drums. Over the years of Reactor operation reasonable amount of contaminated Heavy water got collected in the plant. This Heavy water collected from leakages, during routine maintenance, operational activities and fuelling operation had tritium activity and variety of contamination including oil, chlorides, turbidity due to which the specific conductivity was very high. It was decided to purify this Heavy water in house to bring it up to up gradation plant chemical specification requirement. There were number of challenges in formulating a scheme to purify this Heavy water. The scheme needed to be simple and compact in design which could be set up in the plant itself. It should not pose radiological hazards due to radioactive Heavy water during its purification and handling. The contaminated Heavy water collected in drums had varying chemistry and IP. The purification plant should be able to do batch processing so that the different IP and chemical quality of Heavy water stored in different drums are not mixed during purification. It should be capable of removing the oil, chlorides, turbidity and decrease the conductivity to acceptable limits of the Up gradation plant. A purification plant was developed and commissioned after detail laboratory studies and trials. This paper explains

  5. Experimental and numerical modeling of heavy-oil recovery by electrical heating

    Energy Technology Data Exchange (ETDEWEB)

    Hascakir, B.; Akin, S. [Middle East Technical Univ., Ankara (Turkey); Babadagli, T. [Alberta Univ., Edmonton, AB (Canada)

    2008-10-15

    This study examined the applicability of electrical heating as a heavy oil recovery system in 2 heavy oil fields in Turkey. The physical and chemical properties of samples from the 2 fields were compiled and measured. The samples were then subjected to electrical heating. A retort technique was used to determine oil recovery performance under various conditions. Different types of iron powders were also applied in order to reduce oil viscosity. In situ viscosity reduction levels during the heating process were measured using a history matching procedure that considered data obtained during the laboratory experiments. The study demonstrated that the addition of iron power to the oil samples caused the polar components of the oil to decrease. Oil viscosity was strongly influenced by the magnetic fields created by the iron powders. An analysis of the experimental data showed that significant viscosity reductions of 88 per cent were obtained for the samples when iron additions of 0.5 per cent were used. Data from the experiments were used to develop mathematical models in order to consider thermal diffusion coefficients, oil viscosity, and relative permeability parameters. It was concluded that the cost of producing 1 barrel of oil using the method cost approximately US $5. After a period of 70 days, 320 barrels of petroleum were produced using the method. Oil production rates increased to 440 barrels over the same time period when iron additions were used. 30 refs., 6 tabs., 12 figs.

  6. Removing heavy fuel oil from the submerged wreck of the Jacob Luckenbach

    Energy Technology Data Exchange (ETDEWEB)

    Moffatt, C [PCCI Inc./GPC, Williamsburg, VA (United States); Beaver, T [Global Diving and Salvage Inc., Seattle, WA (United States); Snyder, B [PCCI Inc., Alexandria, VA (United States)

    2003-07-01

    The Jacob Luckenbach cargo carrier sank in July 1953 just west of the Golden Gate Bridge in San Francisco, California after being struck by another vessel. It was carrying a cargo of military vehicles and railroad parts and was topped with heavy No.6 residual oil in deep and double bottom tanks. In 2002, the sunken ship was named as the source of mystery oil spills along the California coast. In response, the United States Coast Guard contracted Titan Maritime LLC and PCCI Inc. to conduct a vessel assessment and removal available oil. Diving services were provided by Seattle-based Global Diving and Salvage. The recovery operation proved difficult due to cold-water saturation diving at depths to 55 metres, strong currents, bad weather and poor subsea visibility. Pumping the heavy residual oil from the tanks also proved to be difficult because some tanks contained oil that was much more viscous than normal No.6 fuel oil, and the tanks had to be heated to more than 78 degrees C to allow for better fluid flow. Some of the abnormal differences in fuel oil rheologies were described along with the tools used to find and recover the oil and to minimize leaks in the wreck. The project, although more difficult than expected, was successful in removing all accessible oil and mitigating the potential for a catastrophic oil release. More than 460 metric tons of heavy fuel oil and emulsified water-in-oil product was removed from the wreck. One of the most important lessons learned was that cohesiveness and a united front are very much needed when a diverse group of salvage personnel are brought together. 1 tab., 5 figs.

  7. Utilizing natural gas huff and puff to enhance production in heavy oil reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Wenlong, G.; Shuhong, W.; Jian, Z.; Xialin, Z. [Society of Petroleum Engineers, Kuala Lumpur (Malaysia)]|[PetroChina Co. Ltd., Beijing (China); Jinzhong, L.; Xiao, M. [China Univ. of Petroleum, Beijing (China)

    2008-10-15

    The L Block in the north structural belt of China's Tuha Basin is a super deep heavy oil reservoir. The gas to oil ratio (GOR) is 12 m{sup 3}/m{sup 3} and the initial bubble point pressure is only 4 MPa. The low production can be attributed to high oil viscosity and low flowability. Although steam injection is the most widely method for heavy oil production in China, it is not suitable for the L Block because of its depth. This paper reviewed pilot tests in which the natural gas huff and puff process was used to enhance production in the L Block. Laboratory experiments that included both conventional and unconventional PVT were conducted to determine the physical property of heavy oil saturated by natural gas. The experiments revealed that the heavy oil can entrap the gas for more than several hours because of its high viscosity. A pseudo bubble point pressure exists much lower than the bubble point pressure in manmade foamy oils, which is relative to the depressurization rate. Elastic energy could be maintained in a wider pressure scope than natural depletion without gas injection. A special experimental apparatus that can stimulate the process of gas huff and puff in the reservoir was also introduced. The foamy oil could be seen during the huff and puff experiment. Most of the oil flowed to the producer in a pseudo single phase, which is among the most important mechanisms for enhancing production. A pilot test of a single well demonstrated that the oil production increased from 1 to 2 cubic metres per day to 5 to 6 cubic metres per day via the natural gas huff and puff process. The stable production period which was 5 to 10 days prior to huff and puff, was prolonged to 91 days in the first cycle and 245 days in the second cycle. 10 refs., 1 tab., 12 figs.

  8. Hamaca Heavy Oil Project : lessons learned and an evolving development strategy

    Energy Technology Data Exchange (ETDEWEB)

    Gipson, L.J.; Owen, R.; Robertson, C.R. [Petrolera Ameriven/Phillips Petroleum, Caracas, (Venezuela)

    2002-07-01

    The Hamaca extra-heavy crude oil project is one of four integrated extra-heavy crude oil development projects underway in the Faja stratigraphic trap in the Orinoco heavy oil belt of eastern Venezuela. The Faja contains about 1.2 trillion barrels of heavy and extra heavy crude oil. It is divided into the Machete, Zuata, Hamaca and Cerro Negro regions that have been developed by Petroleos de Venezuela SA (PDVSA). The Hamaca region is further subdivided into 25 blocks. The Hamaca integrated project will involve the drilling of more than 1000 horizontal wells over a 35 year period. The project will also involve the installation of more than 200 miles of crude and naptha pipelines, plus an upgrading refinery to convert the 8 API extra heavy crude into a 26 API final product. This presentation describes the performance of the different well types and highlights Petrolera Ameriven's criteria and strategy for future development. Openhole log data superimposed on 2D and 3D seismic displays are presented to show how they can be used for geosteering. 2 refs., 10 figs.

  9. Proceedings of the 5. NCUT upgrading and refining conference 2009 : bitumen, synthetic crude oil and heavy oil

    International Nuclear Information System (INIS)

    2009-01-01

    This conference examined various upgrading technologies related to bitumen production. It provided a forum to review new developments to exploit oil sands bitumen and extra heavy crudes in terms of production, upgrading and environmental issues facing the industry. This 2009 conference focused on the many existing and emerging technical solutions that will help consolidate the position of the vast reserves in Western Canada as a sustainable source of crudes for North America and other selected markets. Some of the technical challenges that have an effect on upgrading include poor quality bitumen and heavy oils; bitumen and diluent blending; pipeline issues; desalting; fouling and corrosion; high costs; dependence on natural gas for energy; poor middle distillates; and greenhouse gas emissions. The sessions of the conference were entitled: heavy oil and bitumen upgrading technologies; secondary upgrading and refining technologies; bitumen transportation; and bitumen and heavy oil processability. The conference featured a total of 50 presentations and posters, of which 43 have been catalogued separately for inclusion in this database. tabs., figs

  10. Impact of heavy metals on the oil products biodegradation process.

    Science.gov (United States)

    Zukauskaite, Audrone; Jakubauskaite, Viktorija; Belous, Olga; Ambrazaitiene, Dalia; Stasiskiene, Zaneta

    2008-12-01

    Oil products continue to be used as a principal source of energy. Wide-scale production, transport, global use and disposal of petroleum have made them major contaminants in prevalence and quantity in the environment. In accidental spills, actions are taken to remove or remediate or recover the contaminants immediately, especially if they occur in environmentally sensitive areas, for example, in coastal zones. Traditional methods to cope with oil spills are confined to physical containment. Biological methods can have an advantage over the physical-chemical treatment regimes in removing spills in situ as they offer biodegradation of oil fractions by the micro-organisms. Recently, biological methods have been known to play a significant role in bioremediation of oil-polluted coastal areas. Such systems are likely to be of significance in the effective management of sensitive coastal ecosystems chronically subjected to oil spillage. For this reason the aim of this paper is to present an impact of Mn, Cu, Co and Mo quantities on oil biodegradation effectiveness in coastal soil and to determine the relationship between metal concentrations and degradation of two oil products (black oil and diesel fuel). Soil was collected in the Baltic Sea coastal zone oil products degradation area (Klaipeda, Lithuania). The experiment consisted of two parts: study on the influence of micro-elements on the oil product biodegradation process; and analysis of the influence of metal concentration on the number of HDMs. The analysis performed and results obtained address the following areas: impact of metal on a population of hydrocarbon degrading micro-organisms, impact of metals on residual concentrations of oil products, influence of metals on the growth of micro-organisms, inter-relation of metal concentrations with degradation rates. Statistical analysis was made using ;Statgraphics plus' software. The influence of metals on the growth of micro-organisms, the biodegradation process

  11. Potential to reduce emissions of sulphur dioxide through reducing sulphur levels in heavy and light fuel oils - a discussion paper

    International Nuclear Information System (INIS)

    Tushingham, M.; Bellamy, J.

    2001-01-01

    Background information on the sulphur levels in light fuel oil (used in residential heating) and heavy fuel oil (used as industrial fuel oil) is provided. In addition to the description of sulphur levels in light and heavy fuel oils, the report also provides a summary of regulatory limits in Canada and elsewhere, and a description of the emission benefits of decreasing sulphur in fuels. 4 refs., 10 tabs., 12 figs

  12. National extra heavy crude oil upgrade; Melhoramento de petroleos extra pesados nacionais no ambiente de producao

    Energy Technology Data Exchange (ETDEWEB)

    Medina, Lilian Camen; Zilio, Evaldo L.; Guimarae, Regina C.; Tosta, Luiz C. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas; Barros, Ricardo S. de [Fundacao Universitaria Jose Bonifacio (FUJB), Rio de Janeiro, RJ (Brazil); Leite, Luiz Fernando T. [PETROBRAS S.A., Vitoria, ES (Brazil). Unidade de Negocios-ES

    2008-07-01

    Brazilian petroleums are becoming increasingly heavy, reaching values of up to 7 deg API, which classifies them as extra heavy. They are also very viscous, sometimes presenting values as 10184 mm{sup 2}/s to 50 deg C. These two factors affect production operations like lifting, flow assurance and primary processing, with implications on transporting and refining. Trading these kinds of oils is also difficult; once there are not many refineries in the world able to process them. Due to these facts and also to the lower yield on premium products, the international market value is lower than the reference oil, for example, oil 'Brent'. Studies indicate that in some heavy oils fields the process of well lifting and also the flow in pipelines is almost impracticable in a first analysis, mainly offshore field, impacting both technically and economically the development of the production of a new field. Therefore it becomes necessary implement efforts to develop alternatives to increase oil's API density and at the same time reduce the viscosity of extra heavy oil inside the well, i.e. through a process of upgrading assuring its flow and consequently their production, primary processing and refining, increasing, the value of marketing. (author)

  13. Will Venezuelan extra-heavy oil be a significant source of petroleum in the next decades?

    International Nuclear Information System (INIS)

    Sena, Marcelo Fonseca Monteiro de; Rosa, Luiz Pinguelli; Szklo, Alexandre

    2013-01-01

    Unconventional oil resources are needed to complement petroleum supply in the next decades. However, given the restrictions that pertain to the production of these resources, this article evaluates the availability of Venezuelan unconventional oil for helping meet the future worldwide petroleum demand. Venezuela has the world's second-largest oil reserves, but the majority of it is unconventional extra-heavy oil from the Orinoco Oil Belt. The perspective of Venezuelan production, the ways in which PDVSA, the state oil company, will raise funds for planned investments and the future oil price predictions are used to assess Venezuela's ability to serve as a source of unconventional oil in the coming years. Findings indicate that Venezuelan crude oil will be increasingly able to provide part of the marginal petroleum supply at a level predicted in global scenarios but short of that predicted by the country's government. Operational difficulties and the effort to raise financial resources for the oil production in the Belt require urgency in overcoming difficulties. As conventional production in Venezuela will stabilise in the coming years and the country is dependent on oil production, Venezuela will rely on extra-heavy oil extraction to ensure increased oil production and the stabilisation of internal accounts. - Highlights: • We analyse the future unconventional oil production capacity of Venezuela. • The study is based on operational capacity, investments capacity and future prices. • The study indicates a production shorter than that predicted by the Venezuelan government. • Venezuela can provide part of the marginal petroleum supply in the coming years

  14. Improving reservoir history matching of EM heated heavy oil reservoirs via cross-well seismic tomography

    KAUST Repository

    Katterbauer, Klemens

    2014-01-01

    Enhanced recovery methods have become significant in the industry\\'s drive to increase recovery rates from oil and gas reservoirs. For heavy oil reservoirs, the immobility of the oil at reservoir temperatures, caused by its high viscosity, limits the recovery rates and strains the economic viability of these fields. While thermal recovery methods, such as steam injection or THAI, have extensively been applied in the field, their success has so far been limited due to prohibitive heat losses and the difficulty in controlling the combustion process. Electromagnetic (EM) heating via high-frequency EM radiation has attracted attention due to its wide applicability in different environments, its efficiency, and the improved controllability of the heating process. While becoming a promising technology for heavy oil recovery, its effect on overall reservoir production and fluid displacements are poorly understood. Reservoir history matching has become a vital tool for the oil & gas industry to increase recovery rates. Limited research has been undertaken so far to capture the nonlinear reservoir dynamics and significantly varying flow rates for thermally heated heavy oil reservoir that may notably change production rates and render conventional history matching frameworks more challenging. We present a new history matching framework for EM heated heavy oil reservoirs incorporating cross-well seismic imaging. Interfacing an EM heating solver to a reservoir simulator via Andrade’s equation, we couple the system to an ensemble Kalman filter based history matching framework incorporating a cross-well seismic survey module. With increasing power levels and heating applied to the heavy oil reservoirs, reservoir dynamics change considerably and may lead to widely differing production forecasts and increased uncertainty. We have shown that the incorporation of seismic observations into the EnKF framework can significantly enhance reservoir simulations, decrease forecasting

  15. The containment of heavy oil in flowing water

    International Nuclear Information System (INIS)

    Brown, H.M.; Goodman, R.H.; Nicholson, P.

    1992-01-01

    Viscous bitumen from Alberta oil sand deposits is diluted with a gas condensate before pipeline transport. Because of its unique properties, the diluent/bitumen mix (dilbit) may require novel containment and recovery techniques in the case of an accidental spill. Preliminary experiments were conducted in a large flowing water channel to determine whether several conventional containment devices could be utilized to trap weathered and emulsified dilbit and bitumen. These devices included a conventional river boom, a nylon fine-weave net, and a low-pressure bubble barrier. The behavior of the oil samples during boom failure was noted in order to understand more completely the mechanisms of failure. The river boom failed to hold viscous floating oil by vortex shedding at flows of under 0.25 m/s. A fine mesh net successfully trapped both floating and mid-channel neutrally buoyant oil but the retention time depends on the oil viscosity. The bubble barrier was not successful in trapping either floating viscous oil or neutrally buoyant oil. At low water velocities, the barrier was able to divert some oils but in an inconsistent manner. The results indicate that conventional barriers need improvement to be effective at higher water velocities and suggest that new concepts in containment should be considered. 9 refs., 3 figs., 2 tabs

  16. Origin of an unusual heavy oil from the Baiyinchagan depression, Erlian basin, northern China

    Energy Technology Data Exchange (ETDEWEB)

    Haiping Huang [China University of Geosciences, Beijing (China); University of Newcastle, Newcastle upon Tyne (United Kingdom). School of Civil Engineering and Geosciences; Guangxi Jin [China University of Geosciences, Beijing (China); Exploration and Development Institute, Puyang (China); Changsong Lin; Yabin Zheng [China University of Geosciences, Beijing (China)

    2003-01-01

    A detailed organic geochemical analysis of six oil samples from the Baiyinchagan depression in the Erlian basin, Northern China, was carried out in order to evaluate their origin. The oils are reservoired at a very shallow depth (223-560 m subsurface) and their chemical and physical properties vary greatly, ranging from normal to extremely heavy oil. The preservation of non-biodegraded oil in such a shallow reservoir is possibly related with palaeo-pasteurization of the reservoir before uplift. Maturity difference is not the primary control on the chemical and physical properties of the oils and there is considerable geochemical evidence to suggest the additional influence of in-reservoir/post-accumulation processes such as biodegradation, water-washing and (possibly) evaporation. Whereas some oils appear to be less affected, others are moderately biodegraded up to level 4 on the [Peters and Moldowan, 1993] scale, with sterane distributions largely unaffected and 25-norhopanes undetected. Contrary to classical biodegradation, the unusual heavy oil shows little evidence of biodegradation from aliphatic components. Water-washing is suggested to be the primary process leading to its formation since the severe alteration of soluble aromatic hydrocarbons is observed. In addition, since the oils have been uplifted significantly after accumulation, evaporation and/or leakage to modify oil compositions cannot be ruled out. (author)

  17. Applying CFD in the Analysis of Heavy Oil/Water Separation Process via Hydrocyclone

    Directory of Open Access Journals (Sweden)

    K Angelim

    2017-06-01

    Full Text Available In recent years most of the oil reserves discovered has been related to heavy oil reservoirs whose reserves are abundant but still show operational difficulties. This fact provoked great interest of the petroleum companies in developing new technologies for increasing the heavy oil production. Produced water generation, effluent recovered from the production wells together with oil and natural gas, is among the greatest potential factors for environmental degradation. Thus, a new scenario of the oil industry appears requiring improvement in treatment units for produced water. Among the technological improvements in the facilities, the use of hydrocyclones has been applied in the treatment of the oily water. In this sense, this study aims to investigate numerically the separation process of heavy oil from a water stream via hydrocyclone, using the computational fluid dynamics technique. In the mathematical modeling was considered a two-phase, three-dimensional, stationary, isothermal and turbulent flow. Results of streamlines, pressure and volume fraction fields of the involved phases (oil and water into the hydrocyclone, and mechanical efficiency and pumping power of the fluids are shown and analyzed. In conclusion, it seems that with increasing fluid input velocity in the device there is an increase in pressure drop, indicating a greater pumping energy consumption of the mixture, and greatly influences the separation process efficiency.

  18. Quarterly oil statistics. Second quarter, 1978

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    This issue presents rapid and accurate information on supply and disposal of crude oil, oil products, and natural gas, including production, refinery output, trade, bunkers, refinery fuel and losses and stock changes. Detailed import and export data are given for 42 origins and 29 destinations for crude oil and products. NGL, feedstocks, naphtha, LPG, gasoline, kerosene, gas/diesel oil, and heavy fuel oil (residual) are covered. (DLC)

  19. The potential applications in heavy oil EOR with the nanoparticle and surfactant stabilized solvent-based emulsion

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, F. [Texas A and M Univ., College Station, TX (United States)

    2010-07-01

    The main challenges in developing the heavy oil reservoirs in the Alaska North Slope (ANS) include technical challenges regarding thermal recovery; sand control and disposal; high asphaltene content; and low in-situ permeability. A chemical enhanced oil recovery method may be possible for these reservoirs. Solvent based emulsion flooding provides mobility control; oil viscosity reduction; and in-situ emulsification of heavy oil. This study evaluated the potential application of nano-particle-stabilized solvent based emulsion injection to enhance heavy oil recovery in the ANS. The optimized micro-emulsion composition was determined using laboratory tests such as phase behaviour scanning, rheology studies and interfacial tension measurements. The optimized nano-emulsions were used in core flooding experiments to verify the recovery efficiency. The study revealed that the potential use of this kind of emulsion flooding is a promising enhanced oil recovery process for some heavy oil reservoirs in Alaska, Canada and Venezuela. 4 refs., 2 tabs., 10 figs.

  20. The effect of ZnO nanoparticles on improved oil recovery in spontaneous imbibition mechanism of heavy oil production

    Science.gov (United States)

    Tajmiri, M.; Ehsani, M. R.; Mousavi, S. M.; Roayaei, E.; Emadi, A.

    2015-07-01

    Spontaneous imbibition (SI) gets a controversial subject in oil- wet carbonate reservoirs. The new concept of nanoparticles applications in an EOR area have been recently raised by researches about oil viscosity reduction and generate emulsion without surfactant. But a lot of questions have been remained about which nanoparticles can alter wettability from oil- wet to water- wet to improve oil recovery. This study introduces the new idea of adding ZnO nanoparticles (0.2%wt concentration) by experimental work on oil recovery. The main goals of this research were to prove that ZnO nanoparticles have the ability to reduce viscosity and also alter wettability. The ultimate objective was to determine the potential of these nanoparticles to imbibe into and displace oil. Through the use of Amott- cell, laboratory tests were conducted in two experiments on four cylindrical core samples (three sandstones and one carbonate) were taken from real Iranian heavy oil reservoir. In the first experiment, core samples were saturated by crude oil and in the second experiment, nanoparticles were flooding into core samples and then saturated by crude oil for about two weeks and after that they were immersed in distilled water and the amount of recovery was monitored during 30 days for both tests. We expected that ZnO nanoparticles decreased the surface tension which reduced the capillary forces through SI and wettability alteration took place towards a more water-wet system and caused the oil relative permeability to increase which dominated the gravitational forces to pull out the oil. Our results proved this expectation from ZnO nanoparticles clearly because carbonate core was oil- wet and the capillary pressure was high and negative to push water into the core so the original oil in place (OOIP) was zero whereas by adding ZnO nanoparticles OOIP was increased to 8.89%. SI yielded recovery values from 17.3, 2 and 15 without nanoparticles to 20.68, 17.57 and 36.2 % OOIP with

  1. Proceedings of the Canadian Heavy Oil Association's annual business conference : out of the chute

    International Nuclear Information System (INIS)

    2004-01-01

    This conference provided a forum for advanced technology experts in the upstream petroleum industry and heavy oil industry to exchange information about emerging technologies for resource recovery, refining, markets, trade and logistics. It was divided into 4 sessions entitled: (1) natural gas and upgrading alternatives, (2) project management issues, (3) project updates, and (4) business and markets. The presentations outlined the use of fuel substitutions and the implications for upgrading, controlling the capital costs of oil sand projects and construction issues facing heavy oil. Trends and factors affecting the petroleum industry in Canada were discussed with particular reference to the Asian interest in Alberta's oil sands and the need for a transportation corridor to bring products to southern markets. The conference featured 12 presentations, of which 6 were indexed separately for inclusion in this database. refs., tabs., figs

  2. Well and Inflow Performance Relationship for Heavy Oil Reservoir under Heating Treatment

    KAUST Repository

    Hakiki, Farizal

    2017-10-17

    Well and Inflow Performance Relationship, termed TPR and IPR, respectively have been the unfailing methods to predict well performance. It is further to determine the schemes on optimising production. The main intention of the study is to explore TPR and IPR under heating treatment for heavy oil well. Klamono is a mature field which mostly has depleted wells, it produces heavy oil within 18.5 °API (>0.95 g/cc oil density), and therefore, artificial lifting method is necessary. Sucker Road Pump (SRP) and Electrical Submersible Pump (ESP) are the most deployed artificial lifting method in this reservoir. To boost the heavy oil production, the application of Electric Downhole Heater (EDH) in Well KLO-X1 is being studied. Whole Klamono\\'s production is more than 100,000 blpd within 97-99% water cut. By installing EDH, oil viscosity is decreased hence oil mobility ratio will play a role to decrease water cut. EDH is installed together with the tubing joint to simplify its application in the wellbore. The study shows that EDH application can elevate fluid (mixed oil and brine) temperature. Oil viscosity confirms a reduction from 68 to 46 cP. The gross well production is up to 12.2 bopd due optimising its outflow performance and reducing 97.5 to 96.9% water cut. The field data gives an incremental of 4.9 bopd. The computational results only show an attainment of net oil production up to 8.3 bopd (2 bopd incremental). The EDH works to lessen both density and viscosity as we hypothesised for the mechanism of thermally induced oil production improvement. The evaluation study on its economics aspect exhibits good result that is 1.4 USD/bbl additional profit margin according to field data despite the challenging annual rig rent cost. Following the field data, the expected net income through analytical model revealed that this project is financially promising.

  3. Pore-scale modelling of the effect of viscous pressure gradients during heavy oil depletion experiments

    Energy Technology Data Exchange (ETDEWEB)

    Bondino, I. [Total E and P UK Ltd., London (United Kingdom); McDougall, S.R. [Heriot-Watt Univ., Edinburgh (United Kingdom); Hamon, G. [Total E and P Canada Ltd., Calgary, AB (Canada)

    2009-07-01

    In solution gas drive, when the reservoir pressure is lowered below the bubble point, bubbles nucleate and grow within saturated oil. A period of internal gas-phase expansion maintains reservoir pressure, driving oil to the wellbore region. Continued pressure reduction eventually leads to the formation of a connected gas phase that is capable of being produced along with the oleic phase. As a result, the total produced gas-oil ratio in the well begins to increase. Once the connected gas phase develops, oil production begins to decrease. This general description can be inadequate in the context of heavy oils where additional characteristics, such as foamy oil, and atypically high recoveries are observed. In order to improve the simulation of solution gas drive for heavy oil in the framework of a pre-existing pore-scale network simulator, a dynamic gas-oil interface tracking algorithm was used to determine the mobilization of bubbles under intense pressure gradients. The model was used to characterize both the stationary capillary controlled growth of bubbles characteristic of slow depletion rates in the far wellbore region and the flow phenomena in the near wellbore region. A rationale for interpreting a range of flow mechanism, their associated gas relative permeabilities and critical gas saturations was also proposed. The paper first presented a description of the dynamic pore network model in terms of its' ability to model the porous space; and mobilize gas under viscous pressure gradients and unsteady-state gas relative permeabilities. The dynamic network modelling of heavy oil depletion experiments at different rates and the prediction of the experimental gas saturations were then presented along with a discussion on critical gas saturations. It was concluded that foamy oil behaviour can be observed in situations where capillary pressures are overcome by viscous pressure gradients. 47 refs., 5 tabs., 17 figs.

  4. Well and Inflow Performance Relationship for Heavy Oil Reservoir under Heating Treatment

    KAUST Repository

    Hakiki, Farizal; Aditya, A.; Ulitha, D. T.; Shidqi, M.; Adi, W. S.; Wibowo, K. H.; Barus, M.

    2017-01-01

    Well and Inflow Performance Relationship, termed TPR and IPR, respectively have been the unfailing methods to predict well performance. It is further to determine the schemes on optimising production. The main intention of the study is to explore TPR and IPR under heating treatment for heavy oil well. Klamono is a mature field which mostly has depleted wells, it produces heavy oil within 18.5 °API (>0.95 g/cc oil density), and therefore, artificial lifting method is necessary. Sucker Road Pump (SRP) and Electrical Submersible Pump (ESP) are the most deployed artificial lifting method in this reservoir. To boost the heavy oil production, the application of Electric Downhole Heater (EDH) in Well KLO-X1 is being studied. Whole Klamono's production is more than 100,000 blpd within 97-99% water cut. By installing EDH, oil viscosity is decreased hence oil mobility ratio will play a role to decrease water cut. EDH is installed together with the tubing joint to simplify its application in the wellbore. The study shows that EDH application can elevate fluid (mixed oil and brine) temperature. Oil viscosity confirms a reduction from 68 to 46 cP. The gross well production is up to 12.2 bopd due optimising its outflow performance and reducing 97.5 to 96.9% water cut. The field data gives an incremental of 4.9 bopd. The computational results only show an attainment of net oil production up to 8.3 bopd (2 bopd incremental). The EDH works to lessen both density and viscosity as we hypothesised for the mechanism of thermally induced oil production improvement. The evaluation study on its economics aspect exhibits good result that is 1.4 USD/bbl additional profit margin according to field data despite the challenging annual rig rent cost. Following the field data, the expected net income through analytical model revealed that this project is financially promising.

  5. 15 CFR Supplement No. 3 to Part 754 - Statutory Provisions Dealing With Exports of Crude Oil

    Science.gov (United States)

    2010-01-01

    ... States or that would cause substantial harm to consumers, including noncontiguous States and Pacific... either exchanged in similar quantity for convenience or increased efficiency of transportation with persons or the government of an adjacent foreign state, or which is temporarily exported for convenience...

  6. Comparative assessment of structural-mechanical properties of heavy oils of timano-pechorskaya province

    Directory of Open Access Journals (Sweden)

    Н. К. Кондрашева

    2017-06-01

    Full Text Available The physicochemical properties of heavy oils of Yaregskoe and Usinskoe deposits and the residues of atmospheric distillation of petroleum (fuel oil recovered from them are presented. The group composition of oil and the residues of its atmospheric distillation (fuel oil is determined. When using X-ray fluorescence energy dispersive spectrometer, the content of metals in the products is determined. A conclusion is drawn about the distribution of metals in the initial oil and fuel oil. On the basis of rheological characteristics, the type of liquids is determined in accordance with Newton's law, as well as the presence of an anomaly in the viscosity of the studied media at different temperatures. The energy values of the thixotropy of heavy oils of Usinskoe and Yaregskoe deposits, as well as the activation energy of the viscous flow of all media studied, are obtained. The phase transition of atmospheric residues at 60 °C is discovered. Dependences of the enthalpy and entropy of the viscous flow of the studied hydrocarbon media are obtained with an increase in temperature from 10 to 140 °C. The dependences of the oil molecules and atmospheric residues jumping frequency on viscosity are obtained for the first time.

  7. The optimal currency-peg for an oil exporting country: The case of Saudi Arabia

    International Nuclear Information System (INIS)

    Almasbahi, M.S.

    1990-01-01

    In a world of generalized floating exchange rates, it is not enough to solve the problem of exchange rate policy by determining whether to peg or float the currency under consideration. It is also necessary to choose to what major currency to peg. The main purpose of this study is to investigate and determine empirically the optimum currency peg for the Saudi riyal. To accomplish this goal, a simple conventional trade model, that includes variables found in many other studies of import and export demand, was used. In addition, an exchange rate term was added as a separate independent variable in the import and export demand equations in order to assess the effect of exchange rate on the trade flows. The criteria for the optimal currency peg in this study were based on two factors. First, the error statistics for projected imports and exports using alternative exchange rate regimes. Second, variances of projected imports, exports and trade balance using alternative exchange rate regimes. The exchange rate has a significant impact on the Saudia Arabian trade flows which implies that changes in the riyals value affect the Saudi trade deficit. Moreover, the exchange rate has a more powerful effect on its aggregate imports than on the world demand for its exports. There is also a strong support for the hypothesis that the exchange rate affects the value of the Saudi bilateral trade with its five major trade partners. On the aggregate level, the SDR peg seems to be the best currency peg for the Saudi riyal since it provides the best prediction errors and the lowest variance for the trade balance. Finally, on the disaggregate level, the US dollar provides the best performance and yields the best results among all the six currency pegs considered in this study

  8. Extra heavy oil and refinery residues upgrading through Eni Slurry Technology : first EST commercial unit

    Energy Technology Data Exchange (ETDEWEB)

    Rispoli, G.; Sanfilippo, D.; Amoroso, A [Eni S.p.A., Rome (Italy)

    2009-07-01

    The production of heavy crude oils is projected to continue to grow in the upstream oil industry given that large reserves of unconventional extra heavy crude and bitumen exist in several geographic areas including Canada and Venezuela. As reserves of conventional crude oil continue to decline, these unconventional feedstocks are becoming an opportunity to pursue, but they require effective technologies for upgrading and meeting the growing demand for light and middle distillate fuels. This paper described the proprietary technology that offers a solution to upstream and downstream oil producers for bottom-of-the-barrel upgrading. En i Slurry Technology (EST) is constructing an industrial plant in its Sannazzaro refinery in Italy. The plant is designed to convert 23,000 BPSD of vacuum residue into high quality diesel and other valuable refinery streams such as liquefied petroleum gas, naphtha and jet fuel. EST is an H-addition process characterized by the use of a special homogeneous isothermal intrinsically safe reactor, and of a nano-dispersed non-ageing catalyst. EST converts more than 98 per cent of any type of residues to about 110 per cent volume of light products and distillates or extra heavy oils to high quality bottomless SCO. In typical performance, HDS is greater than 85 per cent, HDM greater than 99 per cent and HDCCR greater than 97 per cent. EST also achieves the target of zero fuel oil - zero coke. 12 refs., 4 tabs., 5 figs.

  9. The influence of South Korean energy policy on OPEC oil exports

    International Nuclear Information System (INIS)

    Almansoori, Ali

    2014-01-01

    South Korea is the fifth top oil importer worldwide with 64% of its oil coming from OPEC member countries. Over the last 30 years, South Korea accounted for a rapid increase in energy use. This in turn led South Korea to be totally dependent on oil imports. Due to this increase, South Korea has been experiencing drastic changes in its energy system which could potentially impact its dependence on OPEC oil import. External and internal factors have forced South Korea to change its energy strategy and targets. These targets would be achieved by reducing its energy intensity and utilizing electricity and renewable energies in order to reduce its dependence on oil consumption. “Low Carbon, Green Growth” is one policy along with many other energy policies developed by South Korea for reducing greenhouse gases, thus this policy is receiving a remarkable attention today. These national policies along with other international ones are needed to mitigate greenhouse gas emissions and promote other green initiatives. This study puts emphasis on these policies as well as uses them to predict the future energy profile of South Korea and how these policies will impact on oil imports from OPEC member countries. - Highlights: • Analyze energy policy of South Korea and its energy profiles. • Study the factors that affect South Korea to change its energy strategy and targets. • Analyze the implications of South Korean energy policy on oil imports from OPEC. • South Korea will continue importing oil from OPEC countries for the next decade

  10. Export of 134 Cs and 137 Cs in the Fukushima river systems at heavy rains by Typhoon Roke in September 2011

    Directory of Open Access Journals (Sweden)

    S. Nagao

    2013-10-01

    Full Text Available At stations on the Natsui River and the Same River in Fukushima Prefecture, Japan, effects of a heavy rain event on radiocesium export were studied after Typhoon Roke during 21–22 September 2011, six months after the Fukushima Dai-ichi Nuclear Power Plant accident. Radioactivity of 134Cs and 137Cs in river waters was 0.009–0.098 Bq L−1 in normal flow conditions during July–September 2011, but it increased to 0.85 Bq L−1 in high flow conditions because of heavy rains occurring with the typhoon. The particulate fractions of 134Cs and 137Cs were 21–56% of total radiocesium in the normal flow condition, but were close to 100% after the typhoon. These results indicate that the pulse input of radiocesium associated with suspended particles from land to coastal ocean occurred because of the heavy rain event. Export flux of 134Cs and 137Cs attributable to the heavy rain accounts for 30–50% of the annual radiocesium flux from inland to coastal ocean region in 2011. Results show that rain events are one factor contributing to the transport and dispersion of radiocesium in river watersheds and coastal marine environments.

  11. The Geopolitics of Shale Gas : The Implications of the US' Shale Gas Revolution on Intrastate Stability within Traditional Oil- and Natural Gas-Exporting Countries in the EU Neighborhood

    OpenAIRE

    Jong, S. de; Auping, W.; Govers, J.; Peters, M.C.A.M.; Widdershoven, C.J.C.G.; Weterings, R.A.P.M.

    2014-01-01

    The US’ shale gas revolution could in the long term destabilize traditional oil- and gas exporters in the European Union (EU) neighborhood: A combination of substitution effects and greater energy efficiency, could put pressure on the price of oil, leading to fiscal difficulties in traditional hydrocarbon exporting countries.

  12. SWINE MANURE SOLIDS SEPARATION AND THERMOCHEMICAL CONVERSION TO HEAVY OIL

    Directory of Open Access Journals (Sweden)

    Shuangning Xiu

    2009-05-01

    Full Text Available Separation of solids from liquid swine manure and subsequent thermo-chemical conversion (TCC of the solids fraction into oil is one way of reducing the waste strength and odor emission. Such processing also provides a potential means of producing renewable energy from animal wastes. Gravity settling and mechanical separation techniques, by means of a centrifuge and belt press, were used to remove the solids from liquid swine manure. The solid fractions from the above separation processes were used as the feedstock for the TCC process for oil production. Experiments were conducted in a batch reactor with a steady temperature 305 oC, and the corresponding pressure was 10.34 Mpa. Gravity settling was demonstrated to be capable of increasing the total solids content of manure from 1% to 9%. Both of the mechanical separation systems were able to produce solids with dry matter around 18% for manure, with 1% to 2% initial total solids. A significant amount of volatile solid (75.7% was also obtained from the liquid fraction using the belt press process. The oil yields of shallow pit manure solids and deep pit manure solids with belt press separation were 28.72% and 29.8% of the total volatile solids, respectively. There was no visible oil product obtained from the deep pit manure solids with centrifuge separation. It is believed that it is the volatile solid content and the other components in the manure chemical composition which mainly deter-mine the oil production.

  13. Hydrogenation active sites of unsupported molybdenum sulfide catalysts for hydroprocessing heavy oils

    Energy Technology Data Exchange (ETDEWEB)

    Iwata, Y.; Araki, Y.; Honna, K. [Tsukuba-branch, Advanced Catalyst Research Laboratory, Petroleum Energy Center, 1-1 Higashi, Tsukuba, 305-8565 Ibaraki (Japan); Miki, Y.; Sato, K.; Shimada, H. [National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, 305-8565 Ibaraki (Japan)

    2001-02-20

    The purpose of the present study was to elucidate the nature of the hydrogenation active sites on unsupported molybdenum sulfide catalysts, aimed at the improvement of the catalysts for the slurry processes. The number of hydrogenation active sites was found to relate to the 'inflection' on the basal plane of the catalyst particles. The comparison of the catalytic activity to that of an oil-soluble catalyst in the hydroprocessing of heavy oils suggests that the performance of the oil-soluble catalyst was near the maximum, unless another component such as Ni or Co was incorporated.

  14. A business process for enhanced heavy oil recovery research and development

    International Nuclear Information System (INIS)

    Carlson, P.; Campbell, M.; Kantzas, A.

    1995-01-01

    Husky Oil's enhanced oil recovery (EOR) research management processes for reducing process development time and increasing investment efficiency were described. The considerations that went into the development of the plan a decade ago were reviewed and new ideas incorporated into the revised plan were presented. Four case studies were presented to illustrate the need for process to reservoir matching. A need for strategic research planning was emphasized. Proposed technologies for enhancement of heavy oil reservoir productivity were presented in tabular form. 1 tab., 7 figs

  15. Exporting climate change and environmental degradation. How Dutch public money is used to finance the oil industry

    International Nuclear Information System (INIS)

    Hamilton, J.; Stockman, L.; Muttitt, G.; Horta, K.; Kochladze, M.; Lisitsyn, D.; Barannikova, N.

    2005-06-01

    According to this report Dutch public money is being used to support oil production in developing countries through Multilateral Development Banks (MDBs) such as the World Bank and European Bank for Reconstruction and Development (EBRD), and other International Financial Institutions (IFIs) such as Atradius (the Dutch Export Credit Agency) and the European Investment Bank (EIB). The Dutch government contributes to MDBs in two ways: through financial contributions using public money and by voting on the boards of the banks. This report demonstrates the need for far greater parliamentary oversight over the Dutch role in MDBs to keep the use of Dutch public money in line with Dutch government policy. Three case studies illustrate that recent oil projects financed and supported by MDBs and other Dutch government departments are failing the poor and undermining national and international targets on development and climate change: the Cameroon Pipeline in West Africa; the Baku-T'bilisi-Ceyhan pipeline system in the South Caucasus and the Sakhalin-II Oil and Gas Project in far eastern Russia.

  16. Simulation studies of steam-propane injection for the Hamaca heavy oil field

    Energy Technology Data Exchange (ETDEWEB)

    Venturini, G.J.; Mamora, D.D. [Texas A and M Univ., Austin, TX (United States)

    2003-07-01

    Laboratory experiments have been conducted at Texas A and M University to examine the use of steam additives such as propane, methane and nitrogen to improve the production of heavy oils and increase steam recovery efficiency. In particular, the use of steam-propane injection for heavy Hamaca crude oil with API gravity of 9.3 and viscosity of 25,000 cp at 50 degrees C was examined. Experimental runs involved the injection of steam or propane into injection cells at a constant rate, temperature and cell outlet pressure. The experimental results suggest that the use of steam-propane injection may translate to reduction of fuel costs for field injections. Initially, propane-steam injection resulted in a two-month oil production acceleration compared to pure steam injection. A significant gain in discounted revenue and savings in steam injection costs could be realized. The study also showed the oil product rate peak with steam-propane injection was much higher than that with pure steam injection. The oil production acceleration increases with increasing propane content. Oil recovery at the end of a five-year forecast period increases by 6.7 per cent of original oil in place (OOIP) compared to 2.3 per cent OOIP with pure steam injection. 12 refs., 6 tabs., 28 figs.

  17. Uncovering the exposure mechanisms of sunken heavy oil that makes it chronically toxic to early life stages of fish

    International Nuclear Information System (INIS)

    Martin, J.; Young, G.; Lemire, B.; Hodson, P.

    2010-01-01

    A train derailment in 2005 caused the release of 150,000 litres of No. 6 heavy fuel oil into a lake in Alberta. The oil is a residue of the crude oil refinement process and contains 3-4 ringed alkylated forms of polycyclic aromatic hydrocarbons (PAH) that are known to cause sub-lethal toxic responses during the early life stages of rainbow trout. Because the oil does not disperse well, oil patches still persist in near-shore sediments of the lake where fish spawn. This study assessed how the behaviour of heavy oil in water interacts with exposure and toxicity to the early life stages of fish. Daily renewal tests with heavy fuel oil coated on glass plate demonstrated higher levels of toxicity to trout embryos than oil that was mechanically or chemically dispersed. A flow-through oil gravel column was used to assess whether the toxic constituents of the heavy oil are transferred quickly enough to cause toxicity. The aim of the study was to develop exposure and toxicity test methods that accurately reflect the behaviour of heavy oil after a spill.

  18. Transport and Phase Equilibria Properties for Steam Flooding of Heavy Oils

    Energy Technology Data Exchange (ETDEWEB)

    Gabitto, Jorge; Barrufet, Maria

    2002-11-20

    The objectives of this research included experimental determination and rigorous modeling and computation of phase equilibrium diagrams, volumetric, and transport properties of hydrocarbon/CO2/water mixtures at pressures and temperatures typical of steam injection processes for thermal recovery of heavy oils.

  19. Fluid and Rock Property Controls On Production And Seismic Monitoring Alaska Heavy Oils

    Energy Technology Data Exchange (ETDEWEB)

    Liberatore, Matthew [Colorado School of Mines, Golden, CO (United States); Herring, Andy [Colorado School of Mines, Golden, CO (United States); Prasad, Manika [Colorado School of Mines, Golden, CO (United States); Dorgan, John [Colorado School of Mines, Golden, CO (United States); Batzle, Mike [Colorado School of Mines, Golden, CO (United States)

    2012-10-30

    The goal of this project is to improve recovery of Alaskan North Slope (ANS) heavy oil resources in the Ugnu formation by improving our understanding of the formation's vertical and lateral heterogeneities via core evaluation, evaluating possible recovery processes, and employing geophysical monitoring to assess production and modify production operations.

  20. Experimental and Theoretical Determination of Heavy Oil Viscosity Under Reservoir Conditions; ANNUAL

    International Nuclear Information System (INIS)

    Gabitto, Jorge; Barrufet, Maria

    2002-01-01

    The main objective of this research was to propose a simple procedure to predict heavy oil viscosity at reservoir conditions as a function of easily determined physical properties. This procedure will avoid costly experimental testing and reduce uncertainty in designing thermal recovery processes

  1. Asphaltene precipitation and its effects on the vapour extraction (VAPEX) heavy oil recovery process

    Energy Technology Data Exchange (ETDEWEB)

    Luo, P.; Wang, X.; Gu, Y. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Regina Univ., SK (Canada). Petroleum Technology Research Centre; Zhang, H. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Core Laboratories Canada Ltd., Calgary, AB (Canada); Moghadam, L. [Fekete Associates Inc., Calgary, AB (Canada)

    2008-10-15

    One of the most important physical phenomena during the solvent vapour extraction (VAPEX) of heavy oil recovery is asphaltene precipitation. After the asphaltene precipitation occurs, the produced heavy oil is deasphalted in-situ, resulting in a lower viscosity and better quality. However, precipitated asphaltenes may plug some small pores of the reservoir formation, thus reducing its permeability. This paper examined the effects of three operating factors on the asphaltene precipitation during the VAPEX process, notably solvent type; operating pressure; and sand-pack permeability. Eight VAPEX tests were conducted to recover two different Lloydminster heavy oil samples from a rectangular sand-packed physical model with a butane mixture and propane as the respective solvents. The accumulative heavy oil and solvent production from the physical model were measured in the entire VAPEX process. The paper described the materials, experimental set-up, and experimental preparation. The VAPEX test was also explained. Results were presented for sand consolidation; solvent effect; pressure effect; and permeability effect. It was concluded that when the extracting solvent is in a liquid-gas state, asphaltene precipitation occurs and leads to in-situ deasphalting. 15 refs., 3 tabs., 6 figs.

  2. Physicochemical and heavy metals values of Nigerian crude oil ...

    African Journals Online (AJOL)

    NPDC) Benin City representing three different oil wells each for Onshore and Offshore and labeled A, B, C for Onshore and D, E, F for offshore were analyzed for their ash content, volatile matter, pH, relative density and metal content. The results ...

  3. Use of an oiled gravel column dosing system to characterize exposure and toxicity of fish to sunken heavy oil on spawning substrates

    International Nuclear Information System (INIS)

    Martin, J.; Hodson, P.

    2010-01-01

    In August 2005, a freight train derailment near the shore of Lake Wabamun near Edmonton, Alberta resulted in the release of nearly 150,000 litres of Bunker C oil on the lakeshore. The purpose of this study was to define the toxic load of oil in sediments to better describe the exposure and toxicity of fish to sunken heavy oil on spawning substrates. Heavy Bunker C fuel contains a complex mixture of polycyclic aromatic hydrocarbons (PAH), particularly the 3-4 ringed alkylated forms that cause sublethal toxic responses in early life stages of rainbow trout (Oncorhynchus mykiss). Oil patches still persist in near-shore sediments where fish spawn. This study evaluated how the behaviour of heavy oil in water interacts with exposure and toxicity to trout embryo. Flow-through oiled gravel columns were used to determine whether the toxic constituents of heavy oil are transferred to water quickly enough to cause toxicity. Embryonic trout exposed to the outflow of these columns showed signs of sublethal toxicity and dose-dependent mortality. In addition, column output of hydrocarbons and CYP1A induction in fish were flow-dependent. The desorption kinetics of the gravel column dosing was characterized in order to evaluate the toxicity of oil on these substrates and relate it back to toxicity of oil in sediments. The time to steady-state desorption of oil constituents in water was first determined, and then the rate at which different classes of oil constituents partition into water were identified.

  4. Petrophysical studies in heavy oil sands with early water production - Hamaca area, Orinoco Oil Belt

    Energy Technology Data Exchange (ETDEWEB)

    Salisch, H.A.

    1982-07-01

    This study describes the main lines of petrophysical research in the Hamaca-Pao region of the Orinoco Oil Belt. The techniques and parameters most appropriate for petrophysical studies in the area of interest are discussed. Field tests have confirmed the conclusions of this study on early water production and low oil recovery. Steam injection was shown to be a means for increasing oil mobility to such a degree that significant amounts of additional oil can be produced.

  5. Dispersed catalysts for transforming extra heavy crude oil into transportable upgraded crude: phase identification

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, S.; Canizales, E.; Machin, I. [Gerencia Depttal de Investigacion Estrategica en Refinacion PDVSA Intevep (Venezuela); Segovia, X.; Rivas, A.; Lopez, E.; Pena, J.P.; Rojas, J.D.; Sardella, R. [Gerencia Depttal de Infraestructura y Mejoramiento en Faja Petrolifera PDVSA Intevep (Venezuela)

    2011-07-01

    A new technology to convert extra heavy crude oil into transportable upgraded crude has been developed. A water/oil emulsion composed of steam and catalyst precursors is introduced in the feed which then generates unsupported dispersed catalyst in situ under thermal decomposition. The aim of this paper is to characterize the particles. The study was conducted in a laboratory and on a pilot scale on three different vacuum residues using high resolution transmission electron microscopy and a transmission electron microscope. Results showed that the particles were formed by oxides and inorganic sulphur based in transition metals and their sizes ranged between 5 and 120 nm; in addition, good dispersion was observed. This study demonstrated that the process involved in the generation of dispersed catalyst is extremely complex and showed that further work with heavy crude oils and its residua is required to understand the mechanisms involved.

  6. Molecular design of high performance zwitterionic liquids for enhanced heavy-oil recovery processes.

    Science.gov (United States)

    Martínez-Magadán, J M; Cartas-Rosado, A R; Oviedo-Roa, R; Cisneros-Dévora, R; Pons-Jiménez, M; Hernández-Altamirano, R; Zamudio-Rivera, L S

    2018-03-01

    Branched gemini zwitterionic liquids, which contain two zwitterionic moieties of linked quaternary-ammonium and carboxylate groups, are proposed as chemicals to be applied in the Enhanced Oil Recovery (EOR) from fractured carbonate reservoirs. The zwitterionic moieties are bridged between them through an alkyl chain containing 12 ether groups, and each zwitterionic moiety has attached a long alkyl tail including a CC double bond. A theoretical molecular mechanism over which EOR could rest, consisting on both the disaggregation of heavy oil and the reservoir-rock wettability alteration, was suggested. Results show that chemicals can both reduce the viscosity and remove heavy-oil molecules from the rock surface. Copyright © 2018. Published by Elsevier Inc.

  7. Canadian heavy crude oil and bitumen: Some new and old ideas

    International Nuclear Information System (INIS)

    Scott, G.R.

    1992-01-01

    Canadian conventional heavy oil and bitumen production has been steadily increasing over the last five years. This rise is forecast to continue under modest future crude oil pricing assumptions. During 1990 and 1991, the heavy oil market suffered from wide pricing differentials relative to light crude due to market reductions in Montreal and a feedstock shift at Uno-Ven's Chicago refinery, as well as an increase in the percentage of heavy in the world crude oil supply because of the Iraqi war. These have been offset by price-related bitumen production cuts and minor refinery capacity growth at other locations. The industry is poised for positive change with modest but stable prices and reduced light-heavy differentials caused, in part, by anticipated market expansion due to the June start-up of the Conco coker (50,000 bbl/d) in Montana and the anticipated late fall start up of the Bi-Provincial Upgrader in Saskatchewan (50,000 bbl/d blend). For the future, refinery upgrading and new grass roots refinery additions are suggested for western Canada. Associated transportation savings and condensate blending stock costs are two areas of advantage. Taken together with environmental problems in other densely populated market areas, it makes sense to build new heavy processing capacity near Edmonton but only after all current capacity is debottlenecked and inexpensive additions to current facilities are completed. New capacity will only be built when the heavy/light price differential on feed stock provides economic justification. 11 refs., 2 tabs

  8. A technique for evaluating the oil/heavy-oil viscosity changes under ultrasound in a simulated porous medium.

    Science.gov (United States)

    Hamidi, Hossein; Mohammadian, Erfan; Junin, Radzuan; Rafati, Roozbeh; Manan, Mohammad; Azdarpour, Amin; Junid, Mundzir

    2014-02-01

    Theoretically, Ultrasound method is an economical and environmentally friendly or "green" technology, which has been of interest for more than six decades for the purpose of enhancement of oil/heavy-oil production. However, in spite of many studies, questions about the effective mechanisms causing increase in oil recovery still existed. In addition, the majority of the mechanisms mentioned in the previous studies are theoretical or speculative. One of the changes that could be recognized in the fluid properties is viscosity reduction due to radiation of ultrasound waves. In this study, a technique was developed to investigate directly the effect of ultrasonic waves (different frequencies of 25, 40, 68 kHz and powers of 100, 250, 500 W) on viscosity changes of three types of oil (Paraffin oil, Synthetic oil, and Kerosene) and a Brine sample. The viscosity calculations in the smooth capillary tube were based on the mathematical models developed from the Poiseuille's equation. The experiments were carried out for uncontrolled and controlled temperature conditions. It was observed that the viscosity of all the liquids was decreased under ultrasound in all the experiments. This reduction was more significant for uncontrolled temperature condition cases. However, the reduction in viscosity under ultrasound was higher for lighter liquids compare to heavier ones. Pressure difference was diminished by decreasing in the fluid viscosity in all the cases which increases fluid flow ability, which in turn aids to higher oil recovery in enhanced oil recovery (EOR) operations. Higher ultrasound power showed higher liquid viscosity reduction in all the cases. Higher ultrasound frequency revealed higher and lower viscosity reduction for uncontrolled and controlled temperature condition experiments, respectively. In other words, the reduction in viscosity was inversely proportional to increasing the frequency in temperature controlled experiments. It was concluded that cavitation

  9. Damage to and recovery of coastlines polluted with C-heavy oil spilled from the Nakhodka.

    Science.gov (United States)

    Hayakawa, Kazuichi; Nomura, Maki; Nakagawa, Takuya; Oguri, Seiji; Kawanishi, Takuya; Toriba, Akira; Kizu, Ryoichi; Sakaguchi, Toshifumi; Tamiya, Eiichi

    2006-03-01

    The damage to and recovery of the Japanese coastline from Suzu, Ishikawa Prefecture to Mikuni, Fukui Prefecture was investigated visually over three years after a C-heavy oil spill from the Russian tanker "Nakhodka" in the Japan Sea on January 2, 1997. The beached C-heavy oil tended to remain for a long time on coasts of bedrock and boulder/cobble/pebble but it was removed rapidly from coasts of gravel/sand and man-made structures such as concrete tetrapods. On the coasts of the latter type, wave energy appeared to be the main force removing the oil. One year after the spill, C-heavy oil tended to remain strongly on the sheltered coasts of bedrock and boulder/cobble/pebble. Even on coasts of this type, the contamination was remarkably absent by 2 years after the spill. The concentration levels of polycyclic aromatic hydrocarbons (PAHs) in oil lumps, sand and seawater were monitored during 3 years following the spill. The concentrations of PAHs having 2 or 3 rings decreased more quickly than did those of PAHs having 4 or more rings, suggesting that volatilization was the main cause of the decrease. On the other hand, the concentrations of PAHs having 4 to 6 rings did not start to decrease until 7 months after the spill. The main cause of the decrease seemed to be photolysis. The concentration of BaP in seawater off the polluted coasts was high 1 month after the spill and then decreased. Three years after the spill, the level fell to the sub ng/L level, which was as low as the level in seawater along unpolluted clean coasts in Japan. The concentration of BaP in greenling was higher than the normal level only during the first two months after the spill. These results suggest that the coastlines in Ishikawa and Fukui Prefectures that were polluted with C-heavy oil recovered in 3 years.

  10. Increase oil recovery of heavy oil in combustion tube using a new catalyst based nickel ionic solution

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez-Garnica, M.A.; Hernandez-Perez, J.R.; Cabrera-Reves, M.C.; Schacht-Hernandez, P. [Inst. Mexicano del Petroleo, Mexico City (Mexico); Mamora, D.D. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Texas A and M Univ., College Station, TX (United States)

    2008-10-15

    An ionic liquid-based nickel catalyst was used in conjunction with a combustion tube as an in situ process for heavy oil. The experimental system was comprised of a fluid injection system; a combustion tube; a fluid production system; a gas chromatograph; and a data recording system. Injected nitrogen and air was controlled by a mass flow controller. Nitrogen was used to pressurize the combustion tube and flush the system. Air was injected at a rate of 3 L per minute throughout the combustion run. Liquids leaving the combustion tube passed through a 2-stage separation process. Gases passing through the condenser were kept at low temperatures. Fractions of produced gas were analyzed by the chromatograph. Data loggers were used to obtain data at 30 second intervals. Two combustion experiments were conducted to obtain production times, temperature profiles, and the quality of the oil produced by the catalyst. Combustion tests were conducted with and without the catalyst. An analysis of the experimental data showed that use of the nickel catalyst resulted in increases in oil production as well as higher combustion efficiencies. Use of the catalyst also resulted in a faster combustion front and accelerated oil production. It was concluded that the produced oil contained fewer impurities than oil produced during the control experiment. 23 refs., 3 tabs., 9 figs.

  11. Process for hydroprocessing heavy oils utilizing sepiolite-based catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Auden, C.A.; Yan, T.-Y.

    1986-04-15

    A process is described for demetallizing and desulfurizing a hydrocarbon oil comprising contacting the hydrocarbon oil in the presence of hydrogen and a sepiolite-based catalyst composition under conditions of pressure and temperature sufficient to effect demetallization and desulfurization. The sepiolite-based catalyst composition has been prepared by first contacting the sepiolite with an aqueous solution of a first metal salt, then contacting the resultant metal ion-exchanged sepiolite with an aqueous solution of a compound of a second metal selected from the group consisting of molybdenum, tungsten and vanadium, and finally contacting the resultant metal-exchanged sepiolite product with an aqueous solution of a magnesium compound, thereby effecting a magnesium ion-exchange with the metal-exchanged sepiolite product and neutralizing acid sites on the sepiolite product.

  12. In-situ burning of heavy oils and Orimulsion : mid-scale burns

    International Nuclear Information System (INIS)

    Fingas, M.F.; Fieldhouse, B.; Brown, C.E.; Gamble, L.

    2004-01-01

    In-situ burning is considered to be a viable means to clean oil spills on water. In-situ burning, when performed under the right conditions, can reduce the volume of spilled oil and eliminate the need to collect, store, transport and dispose of the recovered oil. This paper presented the results of bench-scale in-situ burning tests in which Bunker C, Orimulsion and weathered bitumen were burned outdoors during the winter in burn pans of approximately 1 square metre. Each test was conducted on salt water which caused the separation of the bitumen from the water in the Orimulsion. Small amounts of diesel fuel was used to ignite the heavy oils. Quantitative removal of the fuels was achieved in all cases, but re-ignition was required for the Orimulsion. Maximum efficiency was in the order of 70 per cent. The residue was mostly asphaltenes and resins which cooled to a solid, glass like material that could be readily removed. The study showed that the type of oil burned influences the behaviour of the burns. Bunker C burned quite well and Orimulsion burned efficiently, but re-ignition was necessary. It was concluded that there is potential for burning heavy oils of several types in-situ. 6 refs., 7 tabs., 18 figs

  13. Stabilization of heavy oil-water emulsions using a bio/chemical emulsifier mixture

    Energy Technology Data Exchange (ETDEWEB)

    Farahbakhsh, A.; Taghizadeh, M.; Movagharnejad, K. [Chemical Engineering Department, Babol University of Technology, Babol (Iran, Islamic Republic of); Yakhchali, B. [National Institute of Genetic Engineering and Biotechnology, Tehran (Iran, Islamic Republic of)

    2011-11-15

    In this study, the viscosity reduction of heavy oil has been investigated through the formation of oil-water emulsion using a bio/chemical emulsifier mixture. Four bioemulsifiers from indigenous Rhodococcus ergthropolis and Bacillus licheniformis strains were used to stabilize a highly-viscous oil-in-water emulsion. The Taguchi method with an L{sub 9} orthogonal array design was used to investigate the effect of various control factors on the formation of the oil/water emulsions. An emulsion with lowest viscosity was formed using ACO4 strain. The substantial stability of the oil-in-water emulsion allows the heavy oil to be transported practically over long distances or remain stationary for a considerable period of time prior to utilization. As the result of Taguchi analysis, the temperature and concentration of the emulsifier had a significant influence on viscosity reduction of the emulsion. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Exporting the 'Norwegian Model': The effect of administrative design on oil sector performance

    International Nuclear Information System (INIS)

    Thurber, Mark C.; Hults, David R.; Heller, Patrick R.P.

    2011-01-01

    Norway has administered its petroleum resources using three distinct government bodies: a national oil company engaged in commercial hydrocarbon operations; a government ministry to direct policy; and a regulatory body to provide oversight and technical expertise. Norway's relative success in managing its hydrocarbons has prompted development institutions to consider whether this 'Norwegian Model' of separated government functions should be recommended to other oil-producing countries. By studying ten countries that have used widely different approaches in administering their hydrocarbon sectors, we conclude that separation of functions is not a prerequisite to successful oil sector development. Countries where separation of functions has worked are characterized by the combination of high institutional capacity and robust political competition. Unchallenged leaders often appear able to adequately discharge commercial and policy/regulatory functions using the same entity, although this approach may not be robust against political changes. Where institutional capacity is lacking, better outcomes may result from consolidating commercial, policy, and regulatory functions until such capacity has further developed. Countries with vibrant political competition but limited institutional capacity pose the most significant challenge for oil sector reform: Unitary control over the sector is impossible but separation of functions is often difficult to implement. - Highlights: → The 'Norwegian Model' separates commercial, policy, and regulatory functions in oil. → We study ten oil-producing countries to assess the separation of functions model. → The model is useful where there is institutional capacity and political competition. → Consolidation of functions can work better when political power is concentrated. → Countries with low capacity may also be better off consolidating functions.

  15. Industry sector analysis, Mexico: Oil and gas field machinery and equipment. Export Trade Information

    International Nuclear Information System (INIS)

    1990-04-01

    The Industry Sector Analyses (I.S.A.) for oil and gas field machinery and equipment contains statistical and narrative information on projected market demand, end-users, receptivity of Mexican consumers to U.S. products, the competitive situation - Mexican production, total import market, U.S. market position, foreign competition, and competitive factors, and market access - Mexican tariffs, non-tariff barriers, standards, taxes and distribution channels. The I.S.A. provides the United States industry with meaningful information regarding the Mexican market for oil and gas field machinery and equipment

  16. SIMULATION AND OPTIMIZATION OF THE HYDRAULIC FRACTURING OPERATION IN A HEAVY OIL RESERVOIR IN SOUTHERN IRAN

    Directory of Open Access Journals (Sweden)

    REZA MASOOMI

    2017-01-01

    Full Text Available Extraction of oil from some Iranian reservoirs due to high viscosity of their oil or reducing the formation permeability due to asphaltene precipitation or other problems is not satisfactory. Hydraulic fracturing method increases production in the viscous oil reservoirs that the production rate is low. So this is very important for some Iranian reservoirs that contain these characteristics. In this study, hydraulic fracturing method has been compositionally simulated in a heavy oil reservoir in southern Iran. In this study, the parameters of the fracture half length, the propagation direction of the cracks and the depth of fracturing have been considered in this oil reservoir. The aim of this study is to find the best scenario which has the highest recovery factor in this oil reservoir. For this purpose the parameters of the length, propagation direction and depth of fracturing have been optimized in this reservoir. Through this study the cumulative oil production has been evaluated with the compositional simulation for the next 10 years in this reservoir. Also at the end of this paper, increasing the final production of this oil reservoir caused by optimized hydraulic fracturing has been evaluated.

  17. Heavy oil recovery: the challenger to minimize environmental damages; Recolhimento de oleo pesado: o desafio para reducao de impactos ambientais

    Energy Technology Data Exchange (ETDEWEB)

    Maia, Frederico de Azevedo; Wegner, Isaac Rafael [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The maritime accidents that result in oil spill are high on the public environmental concerns, because of these; the oil industry has a high priority to prevent and control them. Heavy oils, the most difficult kind of oil to be recovered, could impact the maritime environmental with a different approach, it could impact the water column and the sea bottom, so much different them the float oil. One these environmental impacts could be done by. This challenger have been overcome by the development of procedures that manner the heavy oil behavior on waterways, gulf and sea could be understood. Once this process could be understood to become easy monitoring the oil track and mitigate the oil impact on the water environment. This paper describe how the PETROBRAS Environmental Response Team has been establish a mean do conduce this task. (author)

  18. A fast-track preliminary thermo-mechanical design of oil export pipelines from P-56 platform

    Energy Technology Data Exchange (ETDEWEB)

    Solano, Rafael F.; Mendonca, Salete M. de [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Franco, Luciano D.; Walker, Alastair; El-Gebaly, Sherif H. [INTECSEA, Rio de Janeiro, RJ (Brazil)

    2009-12-19

    The oil export pipelines of Marlim Sul field Module 3, Campus Basin, offshore Brazil, will operate in high pressure and temperature conditions, and will be laid on seabed crossing ten previously laid pipelines along the routes. In terms of thermo-mechanical design, these conditions turn out to be great challenges. In order to obtain initial results and recommendations for detail design, a preliminary thermo-mechanical design of pipelines was carried out as a fast-track design before the bid. This way, PETROBRAS can assess and emphasize the susceptibility of these lines to lateral buckling and pipeline walking behavior. Therefore, PETROBRAS can present a preliminary mitigation strategy for lateral buckling showing solutions based on displacement controlled criteria and by introducing buckle initiation along the pipeline using distribution buoyancy. Besides that, axial displacements and loads at the pipeline ends can be furnished also in order to provide a basis for the detailed design. The work reported in this paper follows the SAFEBUCK JIP methodology and recommendation, which were used to determine the allowable strain and maximum allowable VAS (Virtual Anchor Spacing) considered in the buckling mitigation strategy. The paper presents also the formation of uncontrolled buckles on the seabed and the propensity for pipeline walking in its sections between buckles. The buckling mitigation strategy established in this preliminary design confirms that the oil pipeline specifications are adequate to maintain integrity during design life. (author)

  19. Analysis of the first CHOPS pilot for heavy oil production in Kuwait

    Energy Technology Data Exchange (ETDEWEB)

    Sanyal, Tirtharenu; Al-Sammak, Ibrahim [Kuwait Oil Company (Kuwait)

    2011-07-01

    Cold heavy oil production with sand (CHOPS) is a technique for extracting difficult heavy crude oil by simply pumping it out of the sands, often using progressive cavity pumps. This technique was tested in a pilot heavy oil production project at one of the fields in Kuwait. The pilot performance of three wells is presented in this paper as is an analysis of the pilot results, which provide important clues for understanding the reservoir description issues as well as sand production characteristics. This process found an intimate relationship between rock mechanics and the fluid viscosity and flow potential of the formation. The wells seemed to develop an enlarged well bore around them, giving a high negative skin factor. Moreover, the lower viscosity of the oil and absence of any strong directional geomechanical trend could be possible reasons for the absence of wormhole development, which has often been observed in other CHOPS operations. The initial burst of sand production needs to be addressed by optimizing the perforation policy.

  20. Maximizing heavy-oil recovery by containing steam through optimized cementing

    Energy Technology Data Exchange (ETDEWEB)

    Ravi, K.; Hunter, B.; Kulakofsky, D [Halliburton Energy Services, Calgary, AB (Canada)

    2008-10-15

    As the world's oil and gas reserves decline, interest in unconventional sources, such as heavy oil, is increasing in response to global energy demand. Conventional methods are not sufficient to produce highly viscous heavy oil, and measures must be taken to decrease its viscosity. Although steam injection is an option, steam heats the casing and the cement sheath posing considerable thermal stress on the casing and the cement sheath. This paper described the design procedures that are required for evaluating the properties needed in the cement sheath in order to assist in withstanding thermal stresses. The steps needed to deliver an optimized cement system were presented. The paper presented an illustration of a typical wellbore for heavy-oil application and listed the parameters responsible for the extent of heat loss. These included formation properties; cement sheath thermal conductivity; steam-injection rate; and steam quality. The paper also described the Zhang unified mechanistic model which involved the temperature, pressure, steam quality, and heat loss changes as a function of the depth and the surroundings. Recommendations for withstanding well operations, hole cleaning, and slurry placement were also presented. Insurance for incomplete drilling fluid displacement and cement with the ability to react and respond were also proposed. It was concluded that in thermal recovery wells, energy loss to the surroundings could be reduced by lowering the thermal conductivity of the cement sheath. This could greatly improve the economics of such wells. 9 refs., 5 figs.

  1. Chemical Flooding in Heavy-Oil Reservoirs: From Technical Investigation to Optimization Using Response Surface Methodology

    Directory of Open Access Journals (Sweden)

    Si Le Van

    2016-09-01

    Full Text Available Heavy-oil resources represent a large percentage of global oil and gas reserves, however, owing to the high viscosity, enhanced oil recovery (EOR techniques are critical issues for extracting this type of crude oil from the reservoir. According to the survey data in Oil & Gas Journal, thermal methods are the most widely utilized in EOR projects in heavy oil fields in the US and Canada, and there are not many successful chemical flooding projects for heavy oil reported elsewhere in the world. However, thermal methods such as steam injection might be restricted in cases of thin formations, overlying permafrost, or reservoir depths over 4500 ft, for which chemical flooding becomes a better option for recovering crude oil. Moreover, owing to the considerable fluctuations in the oil price, chemical injection plans should be employed consistently in terms of either technical or economic viewpoints. The numerical studies in this work aim to clarify the predominant chemical injection schemes among the various combinations of chemical agents involving alkali (A, surfactant (S and polymer (P for specific heavy-oil reservoir conditions. The feasibilities of all potential injection sequences are evaluated in the pre-evaluation stage in order to select the most efficient injection scheme according to the variation in the oil price which is based on practical market values. Finally, optimization procedures in the post-evaluation stage are carried out for the most economic injection plan by an effective mathematic tool with the purpose of gaining highest Net Present Value (NPV of the project. In technical terms, the numerical studies confirm the predominant performances of sequences in which alkali-surfactant-polymer (ASP solution is injected after the first preflushing water whereby the recovery factor can be higher than 47%. In particular, the oil production performances are improved by injecting a buffering viscous fluid right after the first chemical slug

  2. Effect of ultrasonic intensity and frequency on oil/heavy-oil recovery from different wettability rocks

    Energy Technology Data Exchange (ETDEWEB)

    Naderi, K.; Babadagli, T. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Alberta Univ., Edmonton, AB (Canada)

    2008-10-15

    This study identified the mechanisms that are responsible for additional oil recovery that is often observed following an earthquake. It focused on the theory that harmonics of low frequency waves create high frequency waves as they penetrate into rock formations. A series of experiments were conducted on oil-wet rocks with high oil viscosities. The objective was to better understand how ultrasonic energy affects oil recovery at core and pore scale. Cylindrical sandstone cores were placed in imbibition cells to examine how the presence of initial water saturation can affect recovery, and how the recovery changes for different oil viscosities. An increase in oil recovery was observed with ultrasonic energy in all cases. The additional recovery with ultrasonic energy lessened as the oil viscosity increased. Ultrasonic intensity and frequency were shown to be critical to the performance, which is important since ultrasonic waves have limited penetration into porous medium. This is a key disadvantage for commercializing this promising process for well stimulation. Therefore, the authors designed a set-up to measure the ultrasonic energy penetration capacity in different media, notably air, water and slurry. The set-up could identify which types of reservoirs are most suitable for ultrasonic application. Imbibition experiments revealed that ultrasonic radiation increases recovery, and is much more significant in oil wet cases, where initial water saturation facilitate oil recovery. Higher frequency showed a higher rate of recovery compared to lower frequency, but the ultimate recovery was not changed substantially. 46 refs., 1 tab., 16 figs.

  3. Hydroprocessing full-range of heavy oils and bitumen using ultradispersed catalysts at low severity

    Science.gov (United States)

    Peluso, Enzo

    The progressive exhaustion of light crude oils is forcing the petroleum industry to explore new alternatives for the exploitation of unconventional oils. New approaches are searching for technologies able to produce, transport and refine these feedstocks at lower costs, in which symbiotic processes between the enhanced oil recovery (EOR) and the conventional upgrading technologies are under investigation. The process explored in this thesis is an interesting alternative for in-situ upgrading of these crude oils in the presence of ultradispersed (UD) catalysts, which are included as a disperse phase able to circulate along with the processed feed. The objectives of this work are: (a) study the performance of UD catalysts in the presence of a full range (non fractioned) heavy oil and bitumen and (b) evaluate the recyclability of the UD catalysts. Four different heavy crude oils were evaluated in the presence with UD catalysts at a total pressure of 2.8 MPa, residence time of 8 hours and reaction temperatures from 360 up to 400ºC. Thermal and catalytic hydro-processing were compared in terms of conversion and product stability. A comparison between the different crude oils was additionally derived in terms of SARA, initial micro-carbon content and virgin oil stability among other properties. Advantages of catalytic hydro-processing over thermal hydro-processing were evidenced, with UD catalysts playing an essential hydrogenating role while retarding coke formation; microcarbon and asphaltenes reduction in the presence of UD catalysts was observed. To evaluate the feasibility of recycling the UD catalysts, a micro-slurry recycled unit was developed as part of this research. These main results showed: (a) a successful design of this unit, (b) that temperature, LHSV and fractional recycling ratio have more impact on VGO conversion, while pressure has almost no effect, and (c) an UD catalysts agglomeration process was detected, however this process is slow and reversible.

  4. Treatment of heavy hydrocarbons, such as petroleum, shale oil, etc

    Energy Technology Data Exchange (ETDEWEB)

    Mercurio, M

    1939-02-04

    A process is described for treating heavy hydrocarbons in two operations: The first (operation) consisting of distilling in contact with neutral metals such as iron, copper, nickel, etc., or even stones, according to a known method, without pressure or with only a slight pressure or also by conducting the vapors into a receiver containing the materials mentioned, without pressure or with only a slight pressure, and causing condensation in one or the other ways for cooling by means of a submerged spiral; the second operation consisting in submitting the hydrocarbons recovered from the first operation, or otherwise, to the action of oxygen or ozone for recovering them from the carbon, purifying, desulfurizing, and rendering them inodorous, all these matters constituting the novelty of the invention.

  5. Heavy crude and tar sands - the long-term oil reserve

    Energy Technology Data Exchange (ETDEWEB)

    Barnea, J

    1984-10-01

    It appears that heavy crude and tar sands occur in many sedimentary areas, and estimates of known world-wide quantities exceed those known for conventional light crude resources. Although there are not precise figures available, production could be as high as three million barrels per day, with Venezuela, the US, and Canada the largest producers. There are different scales to measure the costs of production because of differences in the quality of various types of heavy crude and tar sands. Economic development of these resources should banish fears of oil scarcity in the foreseeable future. A center for information exchange through international meetings and publications is under development.

  6. Effects-driven chemical fractionation of heavy fuel oil to isolate compounds toxic to trout embryos.

    Science.gov (United States)

    Bornstein, Jason M; Adams, Julie; Hollebone, Bruce; King, Thomas; Hodson, Peter V; Brown, R Stephen

    2014-04-01

    Heavy fuel oil (HFO) spills account for approximately 60% of ship-source oil spills and are up to 50 times more toxic than medium and light crude oils. Heavy fuel oils contain elevated concentrations of polycyclic aromatic hydrocarbons (PAHs) and alkyl-PAHs, known to be toxic to fish; however, little direct characterization of HFO toxicity has been reported. An effects-driven chemical fractionation was conducted on HFO 7102 to separate compounds with similar chemical and physical properties, including toxicity, to isolate the groups of compounds most toxic to trout embryos. After each separation, toxicity tests directed the next phase of fractionation, and gas chromatography-mass spectrometry analysis correlated composition with toxicity, with a focus on PAHs. Low-temperature vacuum distillation permitted the separation of HFO into 3 fractions based on boiling point ranges. The most toxic of these fractions underwent wax precipitation to remove long-chain n-alkanes. The remaining PAH-rich extract was further separated using open column chromatography, which provided distinct fractions that were grouped according to increasing aromatic ring count. The most toxic of these fractions was richest in PAHs and alkyl-PAHs. The results of the present study were consistent with previous crude oil studies that identified PAH-rich fractions as the most toxic. © 2013 SETAC.

  7. Funding the heavy oil sector's innovation : maximizing Canada's R and D tax credit

    International Nuclear Information System (INIS)

    Hill, G.S.; Bernard, M.; Cheung, S.

    2008-01-01

    Canada offers one of the most generous, broadly applicable business tax incentives for eligible research and development projects in the world. The scientific research and experimental development (SR and ED) program is administered by the Canada Revenue Agency and is the single largest federal program, providing over 3 billion dollars in tax assistance to Canadian businesses in 2006. The development of in-situ oil sands recovery technologies such as steam assisted gravity drainage and other techniques have been research-intensive undertakings that have historically benefited from the SR and ED program, many of which are now commercial available technologies. The SR and ED program definition, eligible activities, eligible expenditures, and benefits were described in this paper. These benefits include the ability to deduct qualifying expenditures currently or to defer them indefinitely, as well as investment tax credits that reduce taxes payable on a dollar for dollar basis. Research and development in the heavy oil and oil sands industries was also discussed with reference to platforms for research and development; areas of potential SR and ED. It was concluded that the SR and ED program is a vital source of financing to many Canadian corporations, and could offer significant assistance to companies in the heavy oil and oil sands sector by returning 20-35 per cent of the expenditures back at the federal level as a tax credit. 5 refs

  8. Hydrodenitrogenation of heavy oil--1. Survey of hydrodenitrogenation catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, M.; Ono, T.; Togari, O.

    1979-11-01

    Forty catalysts consisting of binary oxides of silica/alumina, zirconium dioxide, titanium dioxide, or magnesium oxide or alumina/boron oxide, titanium dioxide, zirconium dioxide, or phosphorus pentoxide in various proportions, or of alumina alone, were screened for their activity for hydrodenitrogenation (kn) and hydrodesulfurization (ks) of a Gach Saran vacuum gas oil containing 0.16Vertical Bar3< nitrogen and 2.0Vertical Bar3< sulfur. The activities were correlated with the acid amount and acid strength of the catalysts as measured by temperature-programed desorption of ammonia. The mixed oxides of silica had low kn and low ks, and the kn was proportional to the acidity. The unmixed alumina catalysts showed low kn and high ks and no obvious relationship between activity and acidity. The binary alumina catalysts showed high kn and high ks and no obvious correlation between acidity and activity. Generally, catalysts with high acid strength had the lowest kn, especially the unmixed alumina.

  9. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Processes

    Energy Technology Data Exchange (ETDEWEB)

    Yortsos, Yanis C.

    2002-10-08

    In this report, the thrust areas include the following: Internal drives, vapor-liquid flows, combustion and reaction processes, fluid displacements and the effect of instabilities and heterogeneities and the flow of fluids with yield stress. These find respective applications in foamy oils, the evolution of dissolved gas, internal steam drives, the mechanics of concurrent and countercurrent vapor-liquid flows, associated with thermal methods and steam injection, such as SAGD, the in-situ combustion, the upscaling of displacements in heterogeneous media and the flow of foams, Bingham plastics and heavy oils in porous media and the development of wormholes during cold production.

  10. Enhanced heavy oil recovery on depleted long core system by CH{sub 4} and CO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Shi, R.; Kantzas, A. [Calgary Univ., AB (Canada). Tomographic Imaging and Porous Media Laboratory

    2008-10-15

    As demand for energy continues to increase and production of conventional oil declines, additional development of heavy oil and bitumen recovery processes and technologies is required in order to meet future energy demands. However, if productions are to be achieved economically, heavy oil viscosity must be reduced. Two methods are normally used to reduce heavy oil viscosity, notably thermal processes such as steam assisted gravity drainage and solvent processes. This paper described a laboratory study of potential post-cold production strategies for heavy oil reservoirs. Methane and carbon dioxide were injected in two depleted long cores. The purpose of the study was to improve understanding of the heavy oil solution gas drive mechanism and to assess methane and carbon dioxide recharging as a potential recovery method for heavy oil reservoirs. It also sought to establish a baseline for comparison against one another. The paper described the methodology and provided a summary of previous production history. It was concluded that the saturation and production time difference between the glass beads core and the sandpack core indicate the permeability difference between the two cores. 12 refs., 2 tabs., 14 figs.

  11. GLOBAL PROSPECTS OF SYNTHETIC DIESEL FUEL PRODUCED FROM HYDROCARBON RESOURCES IN OIL&GAS EXPORTING COUNTRIES

    OpenAIRE

    Kurevija, Tomislav; Kukulj, Nenad; Rajković, Damir

    2007-01-01

    Production of synthetic diesel fuel through Fischer-Tropsch process is a well known technology which dates from II World War, when Germany was producing transport fuel from coal. This process has been further improved in the South Africa due to period of international isolation. Today, with high crude oil market cost and increased demand of energy from China and India, as well as global ecological awareness and need to improve air quality in urban surroundings, many projects are being planned...

  12. Applying CFD in the Analysis of Heavy-Oil Transportation in Curved Pipes Using Core-Flow Technique

    Directory of Open Access Journals (Sweden)

    S Conceição

    2017-06-01

    Full Text Available Multiphase flow of oil, gas and water occurs in the petroleum industry from the reservoir to the processing units. The occurrence of heavy oils in the world is increasing significantly and points to the need for greater investment in the reservoirs exploitation and, consequently, to the development of new technologies for the production and transport of this oil. Therefore, it is interesting improve techniques to ensure an increase in energy efficiency in the transport of this oil. The core-flow technique is one of the most advantageous methods of lifting and transporting of oil. The core-flow technique does not alter the oil viscosity, but change the flow pattern and thus, reducing friction during heavy oil transportation. This flow pattern is characterized by a fine water pellicle that is formed close to the inner wall of the pipe, aging as lubricant of the oil flowing in the core of the pipe. In this sense, the objective of this paper is to study the isothermal flow of heavy oil in curved pipelines, employing the core-flow technique. A three-dimensional, transient and isothermal mathematical model that considers the mixture and k-e  turbulence models to address the gas-water-heavy oil three-phase flow in the pipe was applied for analysis. Simulations with different flow patterns of the involved phases (oil-gas-water have been done, in order to optimize the transport of heavy oils. Results of pressure and volumetric fraction distribution of the involved phases are presented and analyzed. It was verified that the oil core lubricated by a fine water layer flowing in the pipe considerably decreases pressure drop.

  13. Effect of Co Mo/HSO3-functionalized MCM-41 over heavy oil

    International Nuclear Information System (INIS)

    Schacht, P.; Ramirez G, M.; Ramirez, S.; Aguilar P, J.; Norena F, L.; Abu, I.

    2010-01-01

    The potential of Co-Mo metals supported on functionalized MCM-41 as catalyst to hydrodesulfurization of heavy oil has been explored in this work. The MCM-41 functionalized sample was synthesized according to method previously reported into the support by simultaneous impregnation. The catalyst was characterized by specific surface area and X-ray diffraction. The pore channel of MCM-41 was confirmed by transmission electronic microscopy and infra red spectroscopy. Catalytic activity tests were carried out using heavy oil from Gulf of Mexico. The API gravity was increased from 12.5 to 20.2, the kinematics viscosity was decreased from 18,700 to 110 c St at 298 K, the contents of asphaltene and sulfur were also reduced. (Author)

  14. Bioremediation: is it the solution to reclamation of heavy oil contaminated soils in the Canadian climate?

    International Nuclear Information System (INIS)

    Goodman, R.; Nicholson, P.; Varga, M.; Boadi, D.; Yang, A.

    1997-01-01

    The issue of bioremediation of heavy oil contaminated soils in cold climates was discussed. No model of the bioremediation system for cold climates exists. Environmental groups use three environmental concepts as the basis to evaluate petroleum activities: (1) cradle to grave responsibility, (2) the precautionary principle, and (3) sustainable development. The reclamation of an abandoned petroleum production facility must meet stringent standards. Most sites are contaminated with weathered hydrocarbons, brine and other chemicals that have been used at the location. Bioremediation, either in-situ or ex-situ, is one of the lowest cost remediation techniques available and has been used extensively by the downstream petroleum industry in warm climates. However, there are many unresolved issues with the use of bioremediation in cold climates, for heavy or weathered crude oil products and in areas of clay or other low permeability. Some of these unresolved issues are highlighted

  15. Effect of Co Mo/HSO{sub 3}-functionalized MCM-41 over heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Schacht, P.; Ramirez G, M.; Ramirez, S. [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas No. 152, 07730 Mexico D. F. (Mexico); Aguilar P, J.; Norena F, L. [Universidad Autonoma Metropolitana, Unidad Azcapotzalco, Av. San Pablo No. 180, 02200 Mexico D. F. (Mexico); Abu, I., E-mail: pschacha@imp.m [University of Calgary, Department of Chemical and Petroleum Engineering, 2500 University Drive NW, Calgary, Alberta T2N 1N4 (Canada)

    2010-07-01

    The potential of Co-Mo metals supported on functionalized MCM-41 as catalyst to hydrodesulfurization of heavy oil has been explored in this work. The MCM-41 functionalized sample was synthesized according to method previously reported into the support by simultaneous impregnation. The catalyst was characterized by specific surface area and X-ray diffraction. The pore channel of MCM-41 was confirmed by transmission electronic microscopy and infra red spectroscopy. Catalytic activity tests were carried out using heavy oil from Gulf of Mexico. The API gravity was increased from 12.5 to 20.2, the kinematics viscosity was decreased from 18,700 to 110 c St at 298 K, the contents of asphaltene and sulfur were also reduced. (Author)

  16. Potential application of oxygen containing gases to enhance gravity drainage in heavy oil bearing reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Lakatos, I. [Hungarian Academy of Sciences, Miscolc (Hungary). Lab. for Mining Chemistry; Bauer, K. [Hungarian Academy of Sciences, Miscolc (Hungary). Lab. for Mining Chemistry; Lakatos-Szabo, J. [Hungarian Academy of Sciences, Miscolc (Hungary). Lab. for Mining Chemistry

    1997-06-01

    In the frame of laboratory studies the effect of air/natural CO{sub 2} mixtures on chemical composition of crude oil and gas phase, the rheological and interfacial properties, the flow mechanism and the safety measures were analyzed. The tests were performed at reservoir conditions (200 bar and 109 C) using natural rock, oil and gas samples. The oxygen content of the gas phase and the gas/oil ratio varied within wide limits. Both crude and asphaltene-free oil were used to determine the consequences of the low temperature oxidation. On the basis of the experimental results it was found that the oxygen content of the cap gas had been completely consumed by the chemical reactions (oxidation, condensation and water formation) before the asphaltene content set in equilibrium. Nearly 9% excess asphaltene formation was observed in both the crude and the asphaltene-free oils. The substantial increase in asphaltene content and the presence of colloidal water results in a measurable change in rheological and interfacial properties. Despite these factors the flow and displacement mechanism is only slightly influenced if the reservoir is of fractured character. On the other hand the in-situ oxidation of this heavy crude oil improves the efficiency of bitumen production and the quality of product used mostly for road construction. As a final statement, it was concluded that replacing the CO{sub 2} with oxygen containing inert gas, the chemical reactions can be in-situ regulated without jeopardizing the recovery efficiency. Application of the artificial gas cap concept opens new perspectives in EOR technology of karstic and fractured reservoirs containing medium and heavy crude oils in those cases where CO{sub 2} or CH gas is not available. (orig./MSK)

  17. Process development, design and operation of off-line purification system for oil-contaminated impure heavy water

    International Nuclear Information System (INIS)

    Bose, H.; Rakesh Kumar; Gandhi, H.C.; Unny, V.K.P.; Ghosh, S.K.; Mishra, Vivek; Shukla, D.K.; Duraisamy, S.; Agarwal, S.K.

    2004-01-01

    A large volume of degraded, tritiated heavy water contaminated with mineral oil and ionic impurities have accumulated at Dhruva in the past years of reactor operation as a result of routine operation and maintenance activities. The need was felt for a simple and efficient process that could be set up and operated locally at site using readily available materials, to purify the accumulated impure heavy waters at Dhruva so as to make them acceptable at the up gradation facilities. After a detailed laboratory study, a three stage clean-up process was developed which could purify a highly turbid oil-water emulsion to yield clear, oil-free and de-mineralized heavy water at reasonable rates of volume through-put. Based on the laboratory data, a suitably scaled up purification unit has been designed and commissioned which in the past few months has processed a sizeable volume of oil-contaminated heavy water waste from Dhruva, with most satisfactory results

  18. Non-linear, connectivity and threshold-dominated runoff-generation controls DOC and heavy metal export in a small peat catchment

    Science.gov (United States)

    Birkel, Christian; Broder, Tanja; Biester, Harald

    2017-04-01

    Peat soils act as important carbon sinks, but they also release large amounts of dissolved organic carbon (DOC) to the aquatic system. The DOC export is strongly tied to the export of soluble heavy metals. The accumulation of potentially toxic substances due to anthropogenic activities, and their natural export from peat soils to the aquatic system is an important health and environmental issue. However, limited knowledge exists as to how much of these substances are mobilized, how they are mobilized in terms of flow pathways and under which hydrometeorological conditions. In this study, we report from a combined experimental and modelling effort to provide greater process understanding from a small, lead (Pb) and arsenic (As) contaminated upland peat catchment in northwestern Germany. We developed a minimally parameterized, but process-based, coupled hydrology-biogeochemistry model applied to simulate detailed hydrometric and biogeochemical data. The model was based on an initial data mining analysis, in combination with regression relationships of discharge, DOC and element export. We assessed the internal model DOC-processing based on stream-DOC hysteresis patterns and 3-hourly time step groundwater level and soil DOC data (not used for calibration as an independent model test) for two consecutive summer periods in 2013 and 2014. We found that Pb and As mobilization can be efficiently predicted from DOC transport alone, but Pb showed a significant non-linear relationship with DOC, while As was linearly related to DOC. The relatively parsimonious model (nine calibrated parameters in total) showed the importance of non-linear and rapid near-surface runoff-generation mechanisms that caused around 60% of simulated DOC load. The total load was high even though these pathways were only activated during storm events on average 30% of the monitoring time - as also shown by the experimental data. Overall, the drier period 2013 resulted in increased nonlinearity, but

  19. NORM emissions from heavy oil and natural gas fired power plants in Syria

    International Nuclear Information System (INIS)

    Al-Masri, M.S.; Haddad, Kh.

    2012-01-01

    Naturally occurring radioactive materials (NORM) have been determined in fly and bottom ash collected from four major Syrian power plants fired by heavy oil and natural gas. 210 Pb and 210 Po were the main NORM radionuclides detected in the fly and bottom ash. 210 Pb activity concentrations have reached 3393 ± 10 Bq kg −1 and 4023 ± 7 Bq kg −1 in fly ash and bottom ash, respectively; lower values of 210 Po were observed due to its high volatility. In addition, 210 Po and 210 Pb annual emissions in bottom ash from mixed (heavy oil and natural gas) fired power plants varied between 2.7 × 10 9 –7.95 × 10 9 Bq and 3.5 × 10 9 –10 10 Bq, respectively; higher emissions of 210 Po and 210 Pb from gas power plants being observed. However, the present study showed that 210 Po and 210 Pb emissions from thermal power plants fired by natural gas are much higher than the coal power plants operated in the World. - Highlights: ► NORM have been determined in fly and bottom ash collected from Syrian power plants fired by heavy oil and natural gas. ► 210 Pb and 210 Po were the main NORM radionuclides detected in the fly and bottom ash. ► 210 Po and 210 Pb annual emissions from these power plants were estimated.

  20. SO2 pollution of heavy oil-fired steam power plants in Iran

    International Nuclear Information System (INIS)

    Nazari, S.; Shahhoseini, O.; Sohrabi-Kashani, A.; Davari, S.; Sahabi, H.; Rezaeian, A.

    2012-01-01

    Steam power plants using heavy oil provided about 17.4%, equivalent to 35.49 TWh, of electricity in Iran in 2007. However, having 1.55–3.5 weight percentage of sulfur, heavy oil produces SO 2 pollutant. Utilization of Flue Gas Desulfurization systems (FGD) in Iran's steam power plants is not common and thereby, this pollutant is dispersed in the atmosphere easily. In 2007, the average emission factor of SO 2 pollutant for steam power plants was 15.27 g/kWh, which means regarding the amount of electricity generated by steam power plants using heavy oil, 541,000 Mg of this pollutant was produced. In this study, mass distribution of SO 2 in terms of Mg/yr is considered and dispersion of this pollutant in each of the 16 steam power plants under study is modeled using Atmospheric Dispersion Modeling System (ADMS). Details of this study are demonstrated using Geographical Information System (GIS) software, ArcGIS. Finally, the average emission factor of SO 2 and the emission of it in Iran's steam power plants as well as SO 2 emission reduction programs of this country are compared with their alternatives in Turkey and China.

  1. Dual catalyst system for the hydrocracking of heavy oils and residues

    Energy Technology Data Exchange (ETDEWEB)

    Bellussi, G. [ENI S.p.A., San Donato Milanese (Italy)

    2011-07-01

    One of the major challenges for our and for the future generations is the development of a sustainable energy supply system based mainly on renewable sources with no environmental impact. This task is necessary to limit the negative effects of green-house gas on the hearth and to allows the forecasted population growth. However, it is not yet clear the time span needed to reach the objective. The total world energy consumption in 2008 amounted to 8428 Mtoe. In a reference scenario, this amount is expected to grow to 16790 Mtoe in 2030 and the contribution expected by sources, according to the International Energy Agency, will be: oil 29.8 %, coal 29.1 %, natural gas 21,2 %, nuclear 5.7 %, hydroelectric 2.4 %, others (Renewable and waste, geothermal, solar, wind, tide,..) [1]. This picture indicates that for several decades, we must still rely on fossil fuels, avoid running out of this precious energy reserves of our planet and reducing the environmental damage arising from their use. For these reason there is a growing need for the efficient upgrading of the heavy oil streams for a better utilization of every barrel of oil produced and for bringing to production also the huge reserves of unconventional fossil sources, such as the heavy oils and the tar sands. Since several years many companies have R and D project aimed to the conversion of heavy residues through a hydrocracking slurry technology, which, with respect to other competing technologies, such as those based on fixed or ebullated bed, can convert all the feedstock to distillates, avoiding the production of fuel oil or coke. In this lecture the advancement in this area will be presented and discussed, highlighting the potentiality offered by the improvement of the catalyst system. (orig.)

  2. SOLVENT-BASED ENHANCED OIL RECOVERY PROCESSES TO DEVELOP WEST SAK ALASKA NORTH SLOPE HEAVY OIL RESOURCES

    Energy Technology Data Exchange (ETDEWEB)

    David O. Ogbe; Tao Zhu

    2004-01-01

    A one-year research program is conducted to evaluate the feasibility of applying solvent-based enhanced oil recovery processes to develop West Sak and Ugnu heavy oil resources found on the Alaska North Slope (ANS). The project objective is to conduct research to develop technology to produce and market the 300-3000 cp oil in the West Sak and Ugnu sands. During the first phase of the research, background information was collected, and experimental and numerical studies of vapor extraction process (VAPEX) in West Sak and Ugnu are conducted. The experimental study is designed to foster understanding of the processes governing vapor chamber formation and growth, and to optimize oil recovery. A specially designed core-holder and a computed tomography (CT) scanner was used to measure the in-situ distribution of phases. Numerical simulation study of VAPEX was initiated during the first year. The numerical work completed during this period includes setting up a numerical model and using the analog data to simulate lab experiments of the VAPEX process. The goal was to understand the mechanisms governing the VAPEX process. Additional work is recommended to expand the VAPEX numerical study using actual field data obtained from Alaska North Slope.

  3. Field development planning for an offshore extra heavy oil in the Gulf of Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Garcia, G.; Anguiano-Rojas, J. [PEMEX Exploration and Production, Mexico City (Mexico)

    2009-07-01

    This paper presented a phased development strategy for an offshore extra-heavy oil development located in the Gulf of Mexico. The Ayatsil-1 oil field is located in an upper Cretaceous brecciated formation. One of the primary concerns of the project is the infrastructure that is needed to handle low reservoir temperatures and high viscosity, low gravity API oil. A delineation well was drilled in order to confirm the areal extension of the reservoir. The field contains an estimated 3.1 billion barrels of oil-in-place. The project will involve the installation of fixed platforms and production platforms. Electric submersible pumps (ESPs) and multiphase pumps will be used to transport the oil from between 17 to 25 wells. Analyses were conducted to determine transport mechanisms as well as gathering networks in both stationary and transitory regimes. The viscosity of live and dead oil in the reservoirs must be accurately measured in relation to temperature in order to define the artificial systems that will be used to reduce viscosity. Results from several studies will be used to determine the feasibility of various chemical, thermal, and diluent applications. 6 refs., 3 figs.

  4. Experimental optimization of catalytic process in-situ for heavy oil and bitumen upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Shah, A.; Fishwick, R.P.; Leeke, G.A.; Wood, J. [Birmingham Univ., Birmingham (United Kingdom); Rigby, S.P.; Greaves, M. [Bath Univ., Bath (United Kingdom)

    2010-07-01

    Peak crude oil production is expected to occur in the second decade of this century, followed by a phase of permanent decline in conventional crude oil production. However, very large resources of heavy oil and bitumen exist throughout the world, most notably in Canada and Venezuela. The high viscosity and density of these non-conventional crude oils require more energy intensive operations for production and upgrading, and also for transportation. As such, they are more costly to extract. This paper described some of the technological innovations that are being considered to extract heavier oil supplies with reduced environmental impact. The toe-to-heel air injection (THAI) process and its catalytic added-on (CAPRI) process combine in-situ combustion with catalytic upgrading using an annular catalyst packed around a horizontal producer well. Results of an experimental study concerning optimization of catalyst type and operating conditions showed that CAPRI can effect further upgrading of partially upgraded THAI oil, with upgrading levels of viscosity and API gravity dependent upon temperature and flow rate. 20 refs., 8 tabs., 10 figs.

  5. Production of jet fuel using heavy crude oil; Producao de combustiveis de aviacao a partir de petroleos pesados

    Energy Technology Data Exchange (ETDEWEB)

    Om, Neyda [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica; Cavado, Alberto; Reyes, Yordanka [Centro de Pesquisas do Petroleo, Cidade de Havana (Cuba); Dominguez, Zulema [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE)

    2004-07-01

    The production of heavy crude oils increased in the last years in the world. Crude oils with high density, viscosity, acidity and sulfur, nitrogen, metals and asphaltenes contents, by the others hand, low stability and low product quality. The challenger of many refiners is find solutions to refine the heavy crude oils, and produce fuels with certify quality, such as Jet Fuel. The principal aviation technique on the world work with gas turbines engines feted for jet fuel (JET A1). The quality specifications of this fuel are establish by International Norms: ASTM-1655, DEF STAN 91-91-3 (DERD 2494) and joint Fuelling System Check List. The world technologies to obtain jet fuel from mixtures of heavy crude oil with middle crude oils are: Atmospheric distillation, with a posterior hydrogenation and finally the additivation. Studies carried out have demonstrates that the Cubans heavy crude oils is characterized for having API less than 10, raised viscosity, high sulfur content (>6%) and asphaltenes content (more than 15%). These properties provide to its derivatives of low quality. This paper define the characteristic of Cuban heavy crude oil, the technology and operational conditions to produce jet fuel (Jet A1) and the quality of fuel produced. (author)

  6. Impact of rainfall patterns and frequency on the export of pesticides and heavy-metals from agricultural soils.

    Science.gov (United States)

    Meite, Fatima; Alvarez-Zaldívar, Pablo; Crochet, Alexandre; Wiegert, Charline; Payraudeau, Sylvain; Imfeld, Gwenaël

    2018-03-01

    The combined influence of soil characteristics, pollutant aging and rainfall patterns on the export of pollutants from topsoils is poorly understood. We used laboratory experiments and parsimonious modeling to evaluate the impact of rainfall characteristics on the ponding and the leaching of a pollutant mixture from topsoils. The mixture included the fungicide metalaxyl, the herbicide S-metolachlor, as well as copper (Cu) and zinc (Zn). Four rainfall patterns, which differed in their durations and intensities, were applied twice successively with a 7days interval on each soil type. To evaluate the influence of soil type and aging, experiments included crop and vineyard soils and two stages of pollutant aging (0 and 10days). The global export of pollutants was significantly controlled by the rainfall duration and frequency (Pexport of metalaxyl (44.5±21.5% of the initial mass spiked in the soils), S-metolachlor (8.1±3.1%) and Cu (3.1±0.3%). Soil compaction caused by the first rainfall reduced in the second rainfall the leaching of remaining metalaxyl, S-metolachlor, Cu and Zn by 2.4-, 2.9-, 30- and 50-fold, respectively. In contrast, soil characteristics and aging had less influence on pollutant mass export. The soil type significantly influenced the leaching of Zn, while short-term aging impacted Cu leaching. Our results suggest that rainfall characteristics predominantly control export patterns of metalaxyl and S-metolachlor, in particular when the aging period is short. We anticipate our study to be a starting point for more systematic evaluation of the dissolved pollutant ponding/leaching partitioning and the export of pollutant mixtures from different soil types in relation to rainfall patterns. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. The impact of multiphase behaviour on coke deposition in heavy oil hydroprocessing catalysts

    Science.gov (United States)

    Zhang, Xiaohui

    Coke deposition in heavy oil catalytic hydroprocessing remains a serious problem. The influence of multiphase behaviour on coke deposition is an important but unresolved question. A model heavy oil system (Athabasca vacuum bottoms (ABVB) + decane) and a commercial heavy oil hydrotreating catalyst (NiMo/gamma-Al 2O3) were employed to study the impact of multiphase behaviour on coke deposition. The model heavy oil mixture exhibits low-density liquid + vapour (L1V), high-density liquid + vapour (L2V), as well as low-density liquid + high-density liquid + vapour (L1L2V) phase behaviour at a typical hydroprocessing temperature (380°C). The L2 phase only arises for the ABVB composition range from 10 to 50 wt %. The phase behaviour undergoes transitions from V to L2V, to L1L2V, to L1V with increasing ABVB compositions at the pressure examined. The addition of hydrogen into the model heavy oil mixtures at a fixed mass ratio (0.0057:1) does not change the phase behaviour significantly, but shifts the phase regions and boundaries vertically from low pressure to high pressure. In the absence of hydrogen, the carbon content, surface area and pore volume losses for catalyst exposed to the L1 phase are greater than for the corresponding L2 phase despite a higher coke precursor concentration in L2 than in L1. By contrast, in the presence of hydrogen, the carbon content, surface area and pore volume losses for the catalyst exposed to the L2 phase are greater than for the corresponding L1 phase. The higher hydrogen concentration in L1 appears to reverse the observed results. In the presence of hydrogen, L2 was most closely associated with coke deposition, L1 less associated with coke deposition, and V least associated with coke deposition. Coke deposition is maximized in the phase regions where the L2 phase arises. This key result is inconsistent with expectation and coke deposition models where the extent of coke deposition, at otherwise fixed reaction conditions, is asserted to

  8. Response to heavy, non-floating oil spilled in a Great Lakes river environment: a multiple-lines-of-evidence approach for submerged oil assessment and recovery

    Science.gov (United States)

    Dollhopf, Ralph H.; Fitzpatrick, Faith A.; Kimble, Jeffrey W.; Capone, Daniel M.; Graan, Thomas P.; Zelt, Ronald B.; Johnson, Rex

    2014-01-01

    The Enbridge Line 6B pipeline release of diluted bitumen into the Kalamazoo River downstream of Marshall, MI in July 2010 is one of the largest freshwater oil spills in North American history. The unprecedented scale of impact and massive quantity of oil released required the development and implementation of new approaches for detection and recovery. At the onset of cleanup, conventional recovery techniques were employed for the initially floating oil and were successful. However, volatilization of the lighter diluent, along with mixing of the oil with sediment during flooded, turbulent river conditions caused the oil to sink and collect in natural deposition areas in the river. For more than three years after the spill, recovery of submerged oil has remained the predominant operational focus of the response. The recovery complexities for submerged oil mixed with sediment in depositional areas and long-term oil sheening along approximately 38 miles of the Kalamazoo River led to the development of a multiple-lines-of-evidence approach comprising six major components: geomorphic mapping, field assessments of submerged oil (poling), systematic tracking and mapping of oil sheen, hydrodynamic and sediment transport modeling, forensic oil chemistry, and net environmental benefit analysis. The Federal On-Scene Coordinator (FOSC) considered this information in determining the appropriate course of action for each impacted segment of the river. New sources of heavy crude oils like diluted bitumen and increasing transportation of those oils require changes in the way emergency personnel respond to oil spills in the Great Lakes and other freshwater ecosystems. Strategies to recover heavy oils must consider that the oils may suspend or sink in the water column, mix with fine-grained sediment, and accumulate in depositional areas. Early understanding of the potential fate and behavior of diluted bitumen spills when combined with timely, strong conventional recovery methods can

  9. Achievement report for fiscal 1997 on research under New Sunshine Program. Research on heavy oil hydrogenation and heavy oil/coal coprocessing; 1997 nendo jushitsuyu no suisoka shori narabi ni jushitsuyu/sekitan no coprocessing ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    The achievements of the Hokkaido National Industrial Research Institute relating to the titled research are reported. In the study relating to the structural properties of heavy oils, the structures of products of Green River shale oil carbonization is analyzed, heterofunctional groups contained in the oil are subjected to FT-IR (Fourier transform infrared) spectroscopic analysis, and their forms of existence are investigated. In the study relating to the hydrogenation process of heavy oils, findings obtained from experiments are reported, which involve the processing of shale oil by hydrogenation and changes brought about in its chemical structure, hydrogenation of oil sand bitumen, kinetics of hydrocracking of bitumen at a high conversion rate, and a lumping model for bitumen hydrocracking reaction. In the study relating to the coprocessing of heavy oil/coal, coprocessing is experimented for coal and shale oil, coal and oil sand bitumen, and other combinations, and the results are reported. Also, a review is made of the transfer of hydrogen in coprocessing. (NEDO)

  10. Soils washing for removal of heavy oil: Naval Air Engineering Center, Lakehurst, NJ

    International Nuclear Information System (INIS)

    Nash, J.H.; Traver, R.P.

    1991-01-01

    With the recognition that large tracts of land are currently unusable as a result of either accidental spills or past industrial practices (such as oil field development), the USEPA Office of Research and Development evaluated soil washing as an alternative remedial technology for heavy oil contaminated soil at a site located on the Naval Air Engineering Center (NAEC), Lakehurst, New Jersey. The researchers used a self-contained, 100-pound-per-hour soil washer. Electrical, pneumatic, and fluid-pumping capabilities were provided by the trailer-mounted system at a remote No. 6 type oil spill site at the Navy base. Chloroform extracts of the contaminated sandy soil recovered a 0.91 gram/milliliter, 950 centistoke viscosity, dark brown, non-PCB oil. By using a surfactant/solvent solution at ambient temperatures, contaminant levels on the soil were reduced from 3.8% (38,000 milligram/kilogram-RCRA hazardous waste designation) to as low as 0.035% (350 milligram/kilogram) oil concentration. Supplemental laboratory evaluations extending the pilot field evaluations showed at elevated temperatures (120F) that residual oil contamination was less than 0.01% (100 milligram/kilogram). This final oil concentration in the treated soil would be defined as clean under the New Jersey Environmental Cleanup and Responsibilities Act (ECRA). A continuous belt press filter was used to recover the oil in a 47% solids cake that could be used as a secondary fuel feed to a waste boiler. The wash water solution was treated and recycled permitting economical operations

  11. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2001-08-08

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a

  12. Real time, real fast : drilling horizontal wells in a heavy oil environment

    Energy Technology Data Exchange (ETDEWEB)

    Balke, S.C.; Rosauer, M.S. [Petrolera Ameriven/Phillips Petroleum, Caracas, (Venezuela)

    2002-07-01

    Eastern Venezuela's Orinoco Tar Belt or the Faja Petrolifera del Orinoco is one of the largest heavy oil fields in the world, containing more than 1.2 trillion barrels of heavy and extra heavy oil with API gravity of 10 to 6. The field is 320 miles long by 40 miles wide and is divided into the Machete, Zuata, Hamaca and Cerro Negro. It has been under production since the 1970s by Venezuela's national oil company, Petroleos de Venezuela SA. The region is only marginally cost effective because of the high costs associated with development. It is expected that the Hamaca Project, which is centrally located in the Orinoco Tar Belt can be effectively and economically developed by applying the latest technology and innovative techniques. Petrolera Ameriven has committed to develop the 250 square mile Hamaca area. The objective is to produce 165,000 acres at rate of 190,000 BOPD for the life of the project. The challenge is that when the oil is cooled and degasified it looks more like a tar or asphalt for paving roads. In addition, the major reservoirs within the field were deposited in low stand and transgressive system tracks consisting of meandering fluvial to fluvial-tidal deltaic deposits. Methods such as logging while drilling (LWD), satellite links and continuous updating and real-time visualization were applied to assess and mitigate risks. These methods made it possible to accurately place the shoe of the build sections for control of well directions. The methods also made it possible to identify sand/shale interfaces, determine the redirection of the drill bit, locate non-pay zones and help plan well paths to optimize production. The technologies developed were also effective in minimizing development costs, thereby improving the financial viability of the project. 1 ref., 16 figs.

  13. The Trans-Caspian energy route: Cronyism, competition and cooperation in Kazakh oil export

    Energy Technology Data Exchange (ETDEWEB)

    Guliyev, Farid [School of Humanities and Social Sciences, Jacobs University Bremen, Campus Ring 1, D-28759 Bremen (Germany)], E-mail: f.guliyev@jacobs-university.de; Akhrarkhodjaeva, Nozima [School of Humanities and Social Sciences, Jacobs University Bremen, Campus Ring 1, D-28759 Bremen (Germany)

    2009-08-15

    The article delineates the major national, regional and international level stakeholders in the westward Trans-Caspian transportation of Kazakh oil, supplemented with a discussion of the prospect of expansion of the Trans-Caspian/South Caucasus corridor in light of the presumably harmful effect of the war between Russia and Georgia in August 2008. It demonstrates that while foreign companies have been backed by their respective governments, national firms have also enjoyed considerable state support, partly due to their close links to the interests of state elites in Kazakhstan and Azerbaijan. It appears that most companies along the shipping line either belong to the governments of Kazakhstan or Azerbaijan, directly or indirectly (through subsidiaries), or enjoy favoritism and a near monopoly in their markets (crony capitalism). Some of these firms are privately owned but registered in offshore tax havens, while some others have rather obscure ownership structures and corporate profiles. It suggests that cronyism and state capture comprise that politico-economic environment within which the future of Caspian transport systems will have to be decided.

  14. The Trans-Caspian energy route. Cronyism, competition and cooperation in Kazakh oil export

    Energy Technology Data Exchange (ETDEWEB)

    Guliyev, Farid; Akhrarkhodjaeva, Nozima [School of Humanities and Social Sciences, Jacobs University Bremen, Campus Ring 1, D-28759 Bremen (Germany)

    2009-08-15

    The article delineates the major national, regional and international level stakeholders in the westward Trans-Caspian transportation of Kazakh oil, supplemented with a discussion of the prospect of expansion of the Trans-Caspian/South Caucasus corridor in light of the presumably harmful effect of the war between Russia and Georgia in August 2008. It demonstrates that while foreign companies have been backed by their respective governments, national firms have also enjoyed considerable state support, partly due to their close links to the interests of state elites in Kazakhstan and Azerbaijan. It appears that most companies along the shipping line either belong to the governments of Kazakhstan or Azerbaijan, directly or indirectly (through subsidiaries), or enjoy favoritism and a near monopoly in their markets (crony capitalism). Some of these firms are privately owned but registered in offshore tax havens, while some others have rather obscure ownership structures and corporate profiles. It suggests that cronyism and state capture comprise that politico-economic environment within which the future of Caspian transport systems will have to be decided. (author)

  15. The Trans-Caspian energy route. Cronyism, competition and cooperation in Kazakh oil export

    International Nuclear Information System (INIS)

    Guliyev, Farid; Akhrarkhodjaeva, Nozima

    2009-01-01

    The article delineates the major national, regional and international level stakeholders in the westward Trans-Caspian transportation of Kazakh oil, supplemented with a discussion of the prospect of expansion of the Trans-Caspian/South Caucasus corridor in light of the presumably harmful effect of the war between Russia and Georgia in August 2008. It demonstrates that while foreign companies have been backed by their respective governments, national firms have also enjoyed considerable state support, partly due to their close links to the interests of state elites in Kazakhstan and Azerbaijan. It appears that most companies along the shipping line either belong to the governments of Kazakhstan or Azerbaijan, directly or indirectly (through subsidiaries), or enjoy favoritism and a near monopoly in their markets (crony capitalism). Some of these firms are privately owned but registered in offshore tax havens, while some others have rather obscure ownership structures and corporate profiles. It suggests that cronyism and state capture comprise that politico-economic environment within which the future of Caspian transport systems will have to be decided. (author)

  16. Changes in the biological activity of heavy metal- and oil-polluted soils in urban recreation territories

    Science.gov (United States)

    Trifonova, T. A.; Zabelina, O. N.

    2017-04-01

    Urban recreation areas of different sizes were investigated in the city of Vladimir. The degree of their contamination with heavy metals and oil products was revealed. The content of heavy metals exceeded their maximum permissible concentrations by more than 2.5 times. The total content of heavy metals decreased in the sequence: Zn > Pb > Co > Mn > Cr > Ni. The mass fraction of oil products in the studied soils varied within the range of 0.016-0.28 mg/g. The reaction of soils in public gardens and a boulevard was neutral or close to neutral; in some soil samples, it was weakly alkaline. The top layer of all the soils significantly differed from the lower one by the higher alkalinity promoting the deposition of heavy metals there. As the content of Ni, Co, and Mn increased and exceeded the background concentrations, but did not reach the three-fold value of the maximum permissible concentrations, the activity of catalase was intensified. The stimulating effect of nickel on the catalase activity was mostly pronounced at the neutral soil reaction. The urease activity increased when heavy metals and oil products were present together in the concentrations above the background ones, but not higher than the three-fold maximal permissible concentrations for heavy metals and 0.3 mg/g for the content of oil products. The nitrifying activity was inhibited by oil hydrocarbons that were recorded in the soils in different amounts.

  17. Measurement of volatiles, semi-volatiles and heavy metals in an oil burn test

    International Nuclear Information System (INIS)

    Li, K.; Caron, T.; Landriault, M.; Pare, J.R.J.; Fingas, M.

    1992-01-01

    Tests involving meso-scale burning of Louisiana crude oil were conducted, and during each burn, extensive samples were taken from the oil, residue, and the smoke plume. The detailed analytical work employed to obtain and analyze the burn samples is outlined and discussed. The analytical parameters included volatiles and semi-volatiles of environmental interests as well as heavy metals typically contained in the starting crude oil. Because the smoke plume did not always impinge on the samplers, the ground samplers did not collect sufficient samples for a definitive analysis. Crude/residue analyses showed the burn resulted in a significant reduction of polycyclic aromatic hydrocarbons (PAH) in the original oil. Most of the reduction was thought to be simply evaporation or destruction from combustion. The residue did not have the degree of enrichment of the higher molecular weight PAHs as was the case in bench-scale burn experiments. Volatile organic compound and dioxin/furan measurements likewise did not show high levels of contamination from the burn itself. Most of the elevated levels of contaminants could probably be due to evaporation of the oil itself. Insufficient sampling was conducted to investigate the background levels from the weathering process. A novel means of sampling using a small remote controlled helicopter was attempted and sufficiently interesting results were obtained to indicate the potential of this passive sampling device for future work. 5 refs., 4 figs

  18. The influence of diffusion and dispersion on heavy oil recovery by VAPEX

    Energy Technology Data Exchange (ETDEWEB)

    Alkindi, A. [Imperial College, London (United Kingdom); Muggeridge, A. [Society of Petroleum Engineers, London (United Kingdom)]|[Imperial College, London (United Kingdom); Al-Wahaibi, Y. [Society of Petroleum Engineers, Dubai (United Arab Emirates)]|[Sultan Qaboos Univ., Muscat (Oman)

    2008-10-15

    Heavy oil recovery using vapour extraction (VAPEX) is a promising improved oil recovery technique. However, field application of this process has been limited due to concerns that favourable laboratory recoveries may not scale up to the field level. Previous laboratory studies of VAPEX in porous media have obtained much higher production rates than predicted either by analytic models derived from Hele-Shaw experiments or numerical simulation. The difference between experimental and simulation models has been explained by assuming greater mixing between vapour and oil than would be expected from molecular diffusion. Convective dispersion is a plausible justification for this increase. This paper investigated the role of convective dispersion on oil recovery by VAPEX using a combination of well characterized laboratory experiments and numerical simulation. So that all mechanisms contributing to increased-mixing apart from convective dispersion were eliminated, a first contact miscible fluid system was used. Longitudinal and transverse dispersion coefficients were experimentally measured as a function of flow-rate and viscosity ratio. VAPEX drainage experiments were then conducted over a range of injection rates. The paper also discussed the comparison of laboratory measurements of oil drainage rates with those predicted by the Butler-Mokrys analytical model and numerical simulation using either molecular diffusion or convective dispersion. Last, the paper discussed the use of the numerical model in investigating the impact of rate, well separation, and reservoir geometry on recovery. 21 refs., 4 tabs., 12 figs.

  19. Associating Polymer Networks Based on Cyclodextrin Inclusion Compounds for Heavy Oil Recovery

    Directory of Open Access Journals (Sweden)

    Xi Li

    2018-01-01

    Full Text Available This work evaluates an approach to improve the enhanced heavy oil recovery performance of hydrophobic associating polymer. A polymeric system based on water-soluble hydrophobic associating polymer (WSHAP and cyclodextrin (CD polymer was proposed in this work. Addition of CD polymer to WSHAP forms interpolymer bridges by inclusion of CD groups with hydrophobic tails, and thereby the network structure is strengthened. The proposed system offers good viscoelasticity, pronounced shear thinning, and interesting viscosity-temperature relations. Sand pack tests indicated that the proposed system can build high resistance factor during the propagation in porous media, and its moderate adsorption phenomenon was represented by the thickness of the adsorbed layer. The relationship between effective viscosity and oil recovery increment indicated that the proposed system can significantly reduce the residual oil saturation due to the “piston-like” propagation. The overall oil recovery was raised by 5.7 and 24.5% of the original oil in place compared with WSHAP and partially hydrolyzed polyacrylamide (HPAM, respectively.

  20. Expediting the chemistry of hematite nanocatalyst for catalytic aquathermolysis of heavy crude oil

    Science.gov (United States)

    Khalil, Munawar

    In upstream exploration and production of heavy and extra heavy oil, catalytic aquathermolysis is a process where steam (along with catalyst) is injected into the reservoir to improve oil production. The improvement of oil production has been associated with the reduction of heavy oil's viscosity due to the degradation of large hydrocarbon molecules (resin and asphaltene fractions) which mostly the result of desulphurization of organosulphur compounds. In this work, the potential of hematite (alpha-Fe2O3) nanoparticles, a nontoxic, inexpensive and the most stable phase of iron oxide, was investigated for aquathermolysis application. This dissertation encompasses the synthesis, surface modification, catalytic activity, and catalysis mechanism of hematite nanoparticles in aquathermolysis. In the first part of this study, a simple hydrothermal method was successfully developed to synthesize hematite nanoparticles with high purity and good crystallinity. Using this method, the size, crystal's growth rate, shape, and dispersity of the nanoparticles can be controlled by the amount of iron precursor, precipitation agent, temperature and reaction time. Furthermore, the surface chemistry of hematite nanoparticle was modified in order to improve particle dispersibility in hydrocarbon phase. Based on the result, oleic acid (OA) was successfully grafted on the surface of hematite nanoparticles by forming a monodentate interaction and changed the surface property of the nanoparticles from hydrophilic to hydrophobic. As the result, nanoparticles were able to be transferred from aqueous phase to non-polar phase, vice versa, depending on the amount of oleic acid used for modification. In the third part of this work, the catalytic activity and catalytic mechanism of hematite nanoparticles to catalyze desulphurization reaction were studied. It is found that hematite nanoparticles have a good catalytic activity to decompose a highly stable aromatic organosulphur compound, i

  1. Feasibility study of the in-situ combustion in shallow, thin, and multi-layered heavy oil reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, L. [Society of Petroleum Engineers, Kuala Lumpur (Malaysia)]|[Daqing Petroleum Inst., Beijing (China); Yu, D. [Daqing Petroleum Inst., Beijing (China); Gong, Y. [China National Petroleum Corp., Beijing (China). Liaohe Oilfield; Wang, P.; Zhang, L. [China National Petroleum Corp., Beijing (China). Huabei Oilfield; Liu, C. [China National Petroleum Corp., Beijing (China). JiLin Oilfield

    2008-10-15

    In situ combustion is a process where oxygen is injected into oil reservoirs in order to oxidize the heavier components of crude oil. The oil is driven towards the production wells by the combustion gases and steam generated by the combustion processes. This paper investigated dry and wet forward in situ combustion processes designed for an oil reservoir with thin sand layers. Laboratory and numerical simulations were conducted to demonstrate the feasibility of the processes in a shallow, thin, heterogenous heavy oil reservoir in China. Combustion tube experiments were conducted in order to determine fuel consumption rates. A numerical geological model was constructed to represent the reservoir conditions. Gas, water, oil and solid phases were modelled. Four processes were considered: cracking; pyrolysis of heavy fractions; the combustion of light and heavy fractions; and the combustion of coke. Oil recovery rates were calculated for a period of 10 years. Reactor experiments were conducted to investigate igniting temperatures and air injection rates using an apparatus comprised of an electric heater, oil sand pack tube and a computerized control system. Experiments were performed at different temperature and injection rates. The experiments demonstrated that ignition times and air volumes decreased when air temperature was increased. Results of the study showed that a 20 per cent increase in oil recovery using the in situ combustion processes. It was concluded that adequate air injection rates are needed to ensure effective combustion front movement. 4 refs., 6 tabs., 4 figs.

  2. Heavy-oil recovery in naturally fractured reservoirs with varying wettability by steam solvent co-injection

    Energy Technology Data Exchange (ETDEWEB)

    Al Bahlani, A. [Alberta Univ., Edmonton, AB (Canada); Babadagli, T. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Alberta Univ., Edmonton, AB (Canada)

    2008-10-15

    Steam injection may not be an efficient oil recovery process in certain circumstances, such as in deep reservoirs, where steam injection may be ineffective because of hot-water flooding due to excessive heat loss. Steam injection may also be ineffective in oil-wet fractured carbonates, where steam channels through fracture zones without effectively sweeping the matrix oil. Steam flooding is one of the many solutions for heavy oil recovery in unconsolidated sandstones that is in commercial production. However, heavy-oil fractured carbonates are more challenging, where the recovery is generally limited only to matrix oil drainage gravity due to unfavorable wettability or thermal expansion if heat is introduced during the process. This paper proposed a new approach to improve steam/hot-water injection and efficiency for heavy-oil fractured carbonate reservoirs. The paper provided background information on oil recovery from fractured carbonates and provided a statement of the problem. Three phases were described, including steam/hot-waterflooding phase (spontaneous imbibition); miscible flooding phase (diffusion); and steam/hot-waterflooding phase (spontaneous imbibition or solvent retention). The paper also discussed core preparation and saturation procedures. It was concluded that efficient oil recovery is possible using alternate injection of steam/hot water and solvent. 43 refs., 1 tab., 13 figs.

  3. Simultaneous cleanup of soil polluted with crude oil and heavy metals

    International Nuclear Information System (INIS)

    Groudeva, V.; Doycheva, A.; Groudev, S.

    2005-01-01

    Some soils in a site located in the Northwestern part of Bulgaria were heavily polluted with crude oil and some heavy metals (copper, zinc, cadmium, lead). The oil was light, with a specific gravity of about 0.8 g/cm 3 , rich in paraffins and with a very low content of asphaltene-resinous substances. The heavy metals were present mainly as the relevant sulphide minerals but products from the oxidation of sulphides were also present. The oil and the above-mentioned heavy metals were present mainly in the upper soil layers (mainly in the horizon A). Preliminary laboratory experiments in reactors and lysimeters revealed that it was possible to remove most of the contaminants in the soil by using the activity of the indigenous soil microflora. This activity was enhanced by suitable changes in the levels of some essential environmental factors such as pH and water, oxygen and nutrient contents of the soil. It was also found that the inoculation of the soil with active oil-degrading and metal-solubilizing microorganisms caused a considerable positive effect on the soil clean up. A pilot-scale operation for a simultaneous biological removal of the oil and heavy metals from the soil was carried out using the heap technique. Some data about this pilot-scale operation are presented in this paper. At the end of the treatment, the contents of pollutants in the soil were decreased below the permissible levels for soil of such type. At the same time, the chemical composition, structure and main physical and water properties of the soil were altered to a small extent, regardless of the fact that its pH was decreased to about 3.5. The addition of lime to the treated soil increased this pH to about 5.5 and in this way prevented the further acidification of the soil and the generation of acid drainage after rainfall. It must be noted that the removal of contaminants from the control heap was negligible, even after a period of about three years

  4. Characterization of methane emissions from five cold heavy oil production with sands (CHOPS) facilities.

    Science.gov (United States)

    Roscioli, Joseph R; Herndon, Scott C; Yacovitch, Tara I; Knighton, W Berk; Zavala-Araiza, Daniel; Johnson, Matthew R; Tyner, David R

    2018-03-07

    Cold heavy oil production with sands (CHOPS) is a common oil extraction method in the Canadian provinces of Alberta and Saskatchewan that can result in significant methane emissions due to annular venting. Little is known about the magnitude of these emissions, nor their contributions to the regional methane budget. Here the authors present the results of field measurements of methane emissions from CHOPS wells and compare them with self-reported venting rates. The tracer ratio method was used not only to analyze total site emissions but at one site it was also used to locate primary emission sources and quantify their contributions to the facility-wide emission rate, revealing the annular vent to be a dominant source. Emissions measured from five different CHOPS sites in Alberta showed large discrepancies between the measured and reported rates, with emissions being mainly underreported. These methane emission rates are placed in the context of current reporting procedures and the role that gas-oil ratio (GOR) measurements play in vented volume estimates. In addition to methane, emissions of higher hydrocarbons were also measured; a chemical "fingerprint" associated with CHOPS wells in this region reveals very low emission ratios of ethane, propane, and aromatics versus methane. The results of this study may inform future studies of CHOPS sites and aid in developing policy to mitigate regional methane emissions. Methane measurements from cold heavy oil production with sand (CHOPS) sites identify annular venting to be a potentially major source of emissions at these facilities. The measured emission rates are generally larger than reported by operators, with uncertainty in the gas-oil ratio (GOR) possibly playing a large role in this discrepancy. These results have potential policy implications for reducing methane emissions in Alberta in order to achieve the Canadian government's goal of reducing methane emissions by 40-45% below 2012 levels within 8 yr.

  5. Heavy Metal In Food Ingredients In Oil Refi nery Industrial Area, Dumai

    Directory of Open Access Journals (Sweden)

    Dian Sundari

    2016-06-01

    Full Text Available Background: Industrial waste generally contains a lot of heavy metals such as Plumbum (Pb, Arsenic (As, Cadmium(Cd and Mercury (Hg, which can contaminate the surrounding environment and cause health problems. Bioaccumulation ofheavy metals from the environment can occur in foodstuffs. The study aims to determine levels of heavy metals Pb, Cd, Asand Hg in foodstuffs in the oil refi nery industry. Methods: The analytical method used Atomic Absorption Spectrophotometer(AAS. Samples were taken from two locations, namely: the exposed area and non exposed area. The sample consisted ofcassava, papaya leaves, fern leaves, cassava leaves, guava, papaya and catfi sh. Results: The analysis showed levels ofmetals As in all samples at exposed locations is below the maximum limit of SNI, the location is not exposed only in catfi shlevels of As (2.042 mg/kg exceeds the SNI. Cd levels of both locations are not detected. Pb levels in catfi sh in exposedlocations (1,109 mg/kg exceeds the SNI. Hg levels in leaves of papaya, cassava leaves, fern leaves, cassava and fruitpapaya exceed SNI. Conclusion: There has been a heavy metal contamination in foodstuffs. Recommendation: Thelocal people are advised to be careful when consuming food stuffs from oil refi nery industrial area.

  6. Microbial enhanced heavy oil recovery by the aid of inhabitant spore-forming bacteria: an insight review.

    Science.gov (United States)

    Shibulal, Biji; Al-Bahry, Saif N; Al-Wahaibi, Yahya M; Elshafie, Abdulkader E; Al-Bemani, Ali S; Joshi, Sanket J

    2014-01-01

    Crude oil is the major source of energy worldwide being exploited as a source of economy, including Oman. As the price of crude oil increases and crude oil reserves collapse, exploitation of oil resources in mature reservoirs is essential for meeting future energy demands. As conventional recovery methods currently used have become less efficient for the needs, there is a continuous demand of developing a new technology which helps in the upgradation of heavy crude oil. Microbial enhanced oil recovery (MEOR) is an important tertiary oil recovery method which is cost-effective and eco-friendly technology to drive the residual oil trapped in the reservoirs. The potential of microorganisms to degrade heavy crude oil to reduce viscosity is considered to be very effective in MEOR. Earlier studies of MEOR (1950s) were based on three broad areas: injection, dispersion, and propagation of microorganisms in petroleum reservoirs; selective degradation of oil components to improve flow characteristics; and production of metabolites by microorganisms and their effects. Since thermophilic spore-forming bacteria can thrive in very extreme conditions in oil reservoirs, they are the most suitable organisms for the purpose. This paper contains the review of work done with thermophilic spore-forming bacteria by different researchers.

  7. Microbial Enhanced Heavy Oil Recovery by the Aid of Inhabitant Spore-Forming Bacteria: An Insight Review

    Directory of Open Access Journals (Sweden)

    Biji Shibulal

    2014-01-01

    Full Text Available Crude oil is the major source of energy worldwide being exploited as a source of economy, including Oman. As the price of crude oil increases and crude oil reserves collapse, exploitation of oil resources in mature reservoirs is essential for meeting future energy demands. As conventional recovery methods currently used have become less efficient for the needs, there is a continuous demand of developing a new technology which helps in the upgradation of heavy crude oil. Microbial enhanced oil recovery (MEOR is an important tertiary oil recovery method which is cost-effective and eco-friendly technology to drive the residual oil trapped in the reservoirs. The potential of microorganisms to degrade heavy crude oil to reduce viscosity is considered to be very effective in MEOR. Earlier studies of MEOR (1950s were based on three broad areas: injection, dispersion, and propagation of microorganisms in petroleum reservoirs; selective degradation of oil components to improve flow characteristics; and production of metabolites by microorganisms and their effects. Since thermophilic spore-forming bacteria can thrive in very extreme conditions in oil reservoirs, they are the most suitable organisms for the purpose. This paper contains the review of work done with thermophilic spore-forming bacteria by different researchers.

  8. Development of the Write Process for Pipeline-Ready Heavy Oil

    Energy Technology Data Exchange (ETDEWEB)

    Lee Brecher; Charles Mones; Frank Guffey

    2009-03-07

    Work completed under this program advances the goal of demonstrating Western Research Institute's (WRI's) WRITE{trademark} process for upgrading heavy oil at field scale. MEG Energy Corporation (MEG) located in Calgary, Alberta, Canada supported efforts at WRI to develop the WRITE{trademark} process as an oil sands, field-upgrading technology through this Task 51 Jointly Sponsored Research project. The project consisted of 6 tasks: (1) optimization of the distillate recovery unit (DRU), (2) demonstration and design of a continuous coker, (3) conceptual design and cost estimate for a commercial facility, (4) design of a WRITE{trademark} pilot plant, (5) hydrotreating studies, and (6) establish a petroleum analysis laboratory. WRITE{trademark} is a heavy oil and bitumen upgrading process that produces residuum-free, pipeline ready oil from heavy material with undiluted density and viscosity that exceed prevailing pipeline specifications. WRITE{trademark} uses two processing stages to achieve low and high temperature conversion of heavy oil or bitumen. The first stage DRU operates at mild thermal cracking conditions, yielding a light overhead product and a heavy residuum or bottoms material. These bottoms flow to the second stage continuous coker that operates at severe pyrolysis conditions, yielding light pyrolyzate and coke. The combined pyrolyzate and mildly cracked overhead streams form WRITE{trademark}'s synthetic crude oil (SCO) production. The main objectives of this project were to (1) complete testing and analysis at bench scale with the DRU and continuous coker reactors and provide results to MEG for process evaluation and scale-up determinations and (2) complete a technical and economic assessment of WRITE{trademark} technology to determine its viability. The DRU test program was completed and a processing envelope developed. These results were used for process assessment and for scaleup. Tests in the continuous coker were intended to

  9. The effect of low molecular weight multifunctional additives on heavy oil viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Oldenburg, T.B.P.; Yarranton, H.W.; Larter, S.R. [Calgary Univ., AB (Canada)

    2010-07-01

    Crude oils contain many small multifunctional low molecular weight components that act as linking molecules between larger functionalized species. The linkage molecules have a significant impact on the flow properties of hydrocarbon systems. This study investigated the use of a low molecular weight multiheteroatom species (LMWMH) as a molecular Velcro linking high molecular weight components together. LMWMH species were added to Albertan bitumens and heavy oil, and their impact on viscosity was investigated. Results of the experimental studies were then compared with the effects of hydrocarbon solvents on similar samples. The LMWMH species included bifunctional species and analogous alkyl and aryl monoamines that acted as blocking molecules to hinder the association of larger petroleum species. Density and viscosity measurements were conducted. A correlation method was used to predict the viscosity of the solvent-diluted heavy oil and bitumen samples. The study showed that of the tested additives, only aniline demonstrated an additional viscosity-reducing effect. The aniline inhibited asphaltene association and is a promising candidate for enhanced in-situ bitumen viscosity reduction. 23 refs., 4 tabs.

  10. Identification of 3-phase flow patterns of heavy oil from pressure drop and flow rate data

    Energy Technology Data Exchange (ETDEWEB)

    Pacheco, F.; Bannwart, A.C.; Mendes, J.R.P. [Campinas State Univ., Sao Paulo (Brazil); Serapiao, A.B.S. [Sao Paulo State Univ., Sao Paulo (Brazil)

    2008-07-01

    Pipe flow of oil-gas-water mixtures poses a complex thermo-fluid dynamical problem. This paper examined the relationship between phase flow rates, flow pattern identification, and pressure drop in 3-phase water-assisted heavy oil in the presence of a gaseous phase. An artificial intelligence program called a support vector machine (SVM) was used to determine relevant parameters for flow pattern classification. Data from a 3-phase flow of heavy oil with gas and water in a vertical pipe was used in the study. The data were used to train the machine, which then predicted the flow pattern of the remaining data. Tests with different parameters and training data were then performed. The study showed that the proposed SVM flow pattern identification process accurately predicted flow patterns. It was concluded that the SVM took a relatively short amount of time to train. Future research is needed to apply the tool to larger flow datasets. 5 refs., 1 tab., 2 figs.

  11. CFD (Computational Fluid Dynamics) simulators and thermal cracking of heavy oil and ultraheavy residues using microreactor

    Energy Technology Data Exchange (ETDEWEB)

    Jardini, Andre L.; Bineli, Aulus R.R.; Viadana, Adriana M.; Maciel, Maria Regina Wolf; Maciel Filho, Rubens [State University of Campinas (UNICAMP), SP (Brazil). School of Chemical Engineering; Medina, Lilian C.; Gomes, Alexandre de O. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES); Barros, Ricardo S. [University Foundation Jose Bonifacio (FUJB), Rio de Janeiro, RJ (Brazil)

    2008-07-01

    In this paper, the design of microreactor with microfluidics channels has been carried out in Computer Aided Design Software (CAD) and constructed in rapid prototyping system to be used in chemical reaction processing of the heavy oil fractions. The flow pattern properties of microreactor (fluid dynamics, mixing behavior) have been considered through CFD (computational fluid dynamics) simulations. CFD calculations are also used to study the design and specification of new microreactor developments. The potential advantages of using a microreactor include better control of reaction conditions, improved safety and portability. A more detailed crude assay of the raw national oil, whose importance was evidenced by PETROBRAS/CENPES allows establishing the optimum strategies and processing conditions, aiming at a maximum utilization of the heavy oil fractions, towards valuable products. These residues are able to be processed in microreactor, in which conventional process like as hydrotreating, catalytic and thermal cracking may be carried out in a much more intensified fashion. The whole process development involves a prior thermal study to define the possible operating conditions for a particular task, the microreactor design through computational fluid dynamics and construction using rapid prototyping. This gives high flexibility for process development, shorter time, and costumer/task oriented process/product development. (author)

  12. Evaluation of heavy-oil and tar sands in Bourbon, Crawford, and Cherokee Counties, Kansas. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Ebanks, W.J. Jr.; James, G.W.; Livingston, N.D.

    1977-12-01

    The current national energy-resource situation has provided the incentive to investigate more fully deposits of heavy-oil bearing sandstone in southeastern Kansas, as part of a larger, three-state study. The results of this study indicate that the size of the heavy-oil resource in the three Kansas counties studied is smaller than earlier estimates suggested. A resource of 200 to 225 million barrels of oil in-place is estimated to be present in areas of ''known oil occurrence,'' as established by this study. The amount of this in-place resource which may be considered to be reserves, that is, recoverable under existing technology and economics, is zero. The estimates of resource-size are severely downgraded from earlier estimates mainly because of the discontinuous nature of the potential reservoir sandstone bodies and because of the thinness and shaliness of some of these sandstones. The earlier impression of these heavy-oil reservoirs, at least in Kansas, as being widespread, heavily oil saturated, ''blanket'' sandstones unfortunately is not correct. There are areas, shown on maps, which may warrant further investigation because of locally good oil-saturation, i.e., more than 400 barrels per acre foot, in trends of sandstone thicker than 20 feet. It is concluded that there will be no widespread exploitation of subsurface heavy-oil sandstones within the areas of Bourbon, Crawford, and Cherokee Counties, Kansas. Smaller areas indicated here may warrant further drilling and investigation, but the potential size of the heavy-oil resource is severely downgraded from earlier estimates.

  13. Numerical Simulation Study on Steam-Assisted Gravity Drainage Performance in a Heavy Oil Reservoir with a Bottom Water Zone

    Directory of Open Access Journals (Sweden)

    Jun Ni

    2017-12-01

    Full Text Available In the Pikes Peak oil field near Lloydminster, Canada, a significant amount of heavy oil reserves is located in reservoirs with a bottom water zone. The properties of the bottom water zone and the operation parameters significantly affect oil production performance via the steam-assisted gravity drainage (SAGD process. Thus, in order to develop this type of heavy oil resource, a full understanding of the effects of these properties is necessary. In this study, the numerical simulation approach was applied to study the effects of properties in the bottom water zone in the SAGD process, such as the initial gas oil ratio, the thickness of the reservoir, and oil saturation of the bottom water zone. In addition, some operation parameters were studied including the injection pressure, the SAGD well pair location, and five different well patterns: (1 two corner wells, (2 triple wells, (3 downhole water sink well, (4 vertical injectors with a horizontal producer, and (5 fishbone well. The numerical simulation results suggest that the properties of the bottom water zone affect production performance extremely. First, both positive and negative effects were observed when solution gas exists in the heavy oil. Second, a logarithmical relationship was investigated between the bottom water production ratio and the thickness of the bottom water zone. Third, a non-linear relation was obtained between the oil recovery factor and oil saturation in the bottom water zone, and a peak oil recovery was achieved at the oil saturation rate of 30% in the bottom water zone. Furthermore, the operation parameters affected the heavy oil production performance. Comparison of the well patterns showed that the two corner wells and the triple wells patterns obtained the highest oil recovery factors of 74.71% and 77.19%, respectively, which are almost twice the oil recovery factors gained in the conventional SAGD process (47.84%. This indicates that the optimized SAGD process

  14. Model compounds for heavy crude oil components and tetrameric acids: Characterization and interfacial behaviour

    Energy Technology Data Exchange (ETDEWEB)

    Nordgaard, Erland Loeken

    2009-07-01

    The tendency during the past decades in the quality of oil reserves shows that conventional crude oil is gradually being depleted and the demand being replaced by heavy crude oils. These oils contain more of a class high-molecular weight components termed asphaltenes. This class is mainly responsible for stable water-in-crude oil emulsions. Both heavy and lighter crude oils in addition contain substantial amounts of naphthenic acids creating naphthenate deposits in topside facilities. The asphaltene class is defined by solubility and consists of several thousand different structures which may behave differently in oil-water systems. The nature of possible sub fractions of the asphaltene has been received more attention lately, but still the properties and composition of such is not completely understood. In this work, the problem has been addressed by synthesizing model compounds for the asphaltenes, on the basis that an acidic function incorporated could be crucial. Such acidic, poly aromatic surfactants turned out to be highly inter facially active as studied by the pendant drop technique. Langmuir monolayer compressions combined with fluorescence of deposited films indicated that the interfacial activity was a result of an efficient packing of the aromatic cores in the molecules, giving stabilizing interactions at the o/w interface. Droplet size distributions of emulsions studied by PFG NMR and adsorption onto hydrophilic silica particles demonstrated the high affinity to o/w interfaces and that the efficient packing gave higher emulsion stability. Comparing to a model compound lacking the acidic group, it was obvious that sub fractions of asphaltenes that contain an acidic, or maybe similar hydrogen bonding functions, could be responsible for stable w/o emulsions. Indigenous tetrameric acids are the main constituent of calcium naphthenate deposits. Several synthetic model tetra acids have been prepared and their properties have been compared to the indigenous

  15. New Procedure to Develop Lumped Kinetic Models for Heavy Fuel Oil Combustion

    KAUST Repository

    Han, Yunqing

    2016-09-20

    A new procedure to develop accurate lumped kinetic models for complex fuels is proposed, and applied to the experimental data of the heavy fuel oil measured by thermogravimetry. The new procedure is based on the pseudocomponents representing different reaction stages, which are determined by a systematic optimization process to ensure that the separation of different reaction stages with highest accuracy. The procedure is implemented and the model prediction was compared against that from a conventional method, yielding a significantly improved agreement with the experimental data. © 2016 American Chemical Society.

  16. Glaciotectonics in the Cold Lake area and implications for steam-assisted heavy-oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Andriashek, L.D.; Fenton, M.M. [Alberta Geological Survey, Calgary, AB (Canada); Freitas de, T.; Mann, G. [Imperial Oil of Canada, Calgary, AB (Canada)

    1999-11-01

    A study was conducted to show how the depositional history of the Alberta`s Cold Lake region can have an impact on the use of steam assisted heavy-oil recovery in the oil sands region. The bitumens are found mainly within the 50 m thick estuarine and fluvial sandstone of the Cretaceous Clearwater Formation of the Mannville Group, at a depth of approximately 450 m. The stratigraphic sequences within the Mannville Group were presented. It has been determined that glaciotectonics have played a major role in the depositional history of the area. It was also determined that a good understanding of the hydrostratigraphic complexity makes it possible to better manage local ground water resources and to effectively plan further groundwater withdrawal sites.

  17. Enhancing heavy oil recovery using foam injection in applications to cyclic steam stimulation

    Energy Technology Data Exchange (ETDEWEB)

    Isaacs, E. [Alberta Energy Research Inst., Edmonton, AB (Canada); Yuan, J.Y. [Canadian Natural Resources Ltd., Calgary, AB (Canada)

    2008-07-01

    Cyclic steam stimulation (CSS) is a widely used heavy oil production technology. However, steam-based processes that are not stabilized can develop conformance as the steam can over-ride and channel past oil-bearing zones. This presentation discussed a refined CSS steam foaming process designed to improve recovery in marginal cycles. Laboratory studies were initially conducted to examine surfactant properties and flow behaviour in porous media. The results of numerical simulations were then applied to the steam-foaming portion of the CSS process. Results of the study showed that during the foam co-injection with steam stage, the steam injection rate did not alter. Improvement to the CSS process varied, indicating that earlier foam forming surfactant co-injection was preferable when steam-foam performance was constant in all cycles. It was concluded that the steam foaming process may improve bitumen production without requiring additional steam. 13 refs., 5 figs.

  18. Modeling of cobalt-based catalyst use during CSS for low-temperature heavy oil upgrading

    Science.gov (United States)

    Kadyrov, R.; Sitnov, S.; Gareev, B.; Batalin, G.

    2018-05-01

    One of the methods, which is actively used on deposits of heavy oils of the Upper Kungurian (Ufimian) sandstones of the Republic of Tatarstan, is cyclic steam simulation (CSS). This method consists of 3 stages: injection, soaking, and production. Steam is injected into a well at a temperature of 300 to 340° C for a period of weeks to months. Then, the well is allowed to sit for days to weeks to allow heat to soak into the formation. Finally, the hot oil is pumped out of the well for a period of weeks or months. Once the production rate falls off, the well is put through another cycle. The injection of the catalyst solution before the injection of steam opens the possibility for upgrading the heavy oil in the process of aquathermolysis directly in the reservoir. In this paper, the possibility of using a catalyst precursor based on cobalt for upgrading the hydrocarbons of this field in the process of their extraction is represented. SARA analysis on oil saturated sandstones shows an increase in the proportion of saturated hydrocarbons by 11.1% due to the hydrogenation of aromatic hydrocarbons and their derivatives, the content of resins and asphaltenes are remained practically unchanged. A new method for estimating the adsorption of a catalyst based on taking into account the change in the concentration of the base metal before and after simulation of catalyst injection in the thermobaric conditions of the reservoir is proposed. During the study of catalyst adsorption in the rock, when simulating the CSS process, it is found that almost 28% of the cobalt, which is the main element of the catalyst precursor, is retained in the rock.

  19. Accurate numerical simulation of reaction-diffusion processes for heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Govind, P.A.; Srinivasan, S. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Texas Univ., Austin, TX (United States)

    2008-10-15

    This study evaluated a reaction-diffusion simulation tool designed to analyze the displacement of carbon dioxide (CO{sub 2}) in a simultaneous injection of carbon dioxide and elemental sodium in a heavy oil reservoir. Sodium was used due to the exothermic reaction of sodium with in situ that occurs when heat is used to reduce oil viscosity. The process also results in the formation of sodium hydroxide that reduces interfacial tension at the bitumen interface. A commercial simulation tool was used to model the sodium transport mechanism to the reaction interface through diffusion as well as the reaction zone's subsequent displacement. The aim of the study was to verify if the in situ reaction was able to generate sufficient heat to reduce oil viscosity and improve the displacement of the heavy oil. The study also assessed the accuracy of the reaction front simulation tool, in which an alternate method was used to model the propagation front as a moving heat source. The sensitivity of the simulation results were then evaluated in relation to the diffusion coefficient in order to understand the scaling characteristics of the reaction-diffusion zone. A pore-scale simulation was then up-scaled to grid blocks. Results of the study showed that when sodium suspended in liquid CO{sub 2} is injected into reservoirs, it diffuses through the carrier phase and interacts with water. A random walk diffusion algorithm with reactive dissipation was implemented to more accurately characterize reaction and diffusion processes. It was concluded that the algorithm modelled physical dispersion while neglecting the effect of numerical dispersion. 10 refs., 3 tabs., 24 figs.

  20. Design investigation of the HTR for the opening of very heavy oil deposits

    International Nuclear Information System (INIS)

    Gao, Z.

    1985-02-01

    In the north-east of China there are rich deposits of very heavy oil, which are to be found in a depth of 1500-1700 m. For opening an interaction of 370-390 0 Celsius steam is necessary. The HTR is well suited to produce the steam. A nuclear heat source of 1000 MWsub(th) makes possible the production of 1.5 million tons oil per year. This is a 30-40 per cent higher production of oil compared to the oil-fired steam production. Two concepts of smaller pebble bed reactors are suited as heat sources: the HTR-MEDUL-334 with a thermal power of the 334 MW and fuelled in the multiple run-through scheme and the HTR-OTTO-200 with 200 MW and once-through fuelling. Three or five reactors can be combined in the modular way to provide the power of 1000 MW. For both reactors the design, the neutron-physical and thermohydraulic behaviour are followed in the computer simulation. A central zone of the pebble bed reactor is fuelled with elements of strongly reduced fissile content. Due to the reduced power density the maximum fuel temperature appearing in extreme accidents is limited and accordingly the release of the fission products is avoided. (orig.) [de

  1. Investigating the effect of steam, CO{sub 2}, and surfactant on the recovery of heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Tian, S.; He, S. [China Univ. of Petroleum, Beijing (China). MOE Key Laboratory of Petroleum Engineering; Qu, L. [Shengli Oil Field Co. (China)]|[SINOPEC, Shengli (China)

    2008-10-15

    This paper presented the results of a laboratory study and numerical simulation in which the mechanisms of steam injection with carbon dioxide (CO{sub 2}) and surfactant were investigated. The incremental recoveries of 4 different scenarios were compared and analyzed in terms of phase behaviour. The study also investigated the effect of CO{sub 2} dissolution in oil and water; variation of properties of CO{sub 2}-oil phase equilibrium and CO{sub 2}-water phase equilibrium; variation of viscosity; and, oil volume and interfacial tension (IFT) during the recovery process. The expansion of a steam and CO{sub 2} front was also examined. A field application case of a horizontal well in a heavy oil reservoir in Shengli Oilfield in China was used to determine the actual dynamic performance of the horizontal well and to optimize the injection parameters of the CO{sub 2} and surfactant. The study revealed that oil recovery with the simultaneous injection of steam, CO{sub 2} and surfactant was higher than that of steam injection, steam with CO{sub 2} and steam with surfactant. The improved flow performance in super heavy oil reservoirs could be attributed to CO{sub 2} dissolution in oil which can swell the oil and reduce oil viscosity significantly. The proportion of CO{sub 2} in the free gas phase, oil phase and water phase varies with changes in reservoir pressure and temperature. CO{sub 2} decreases the temperature of the steam slightly, while the surfactant decreases the interfacial tension and helps to improve oil recovery. The study showed that the amount of injected CO{sub 2} and steam has a large effect on heavy oil recovery. Although oil production was found to increase with an increase in injected amounts, the ratio of oil to injected fluids must be considered to achieve optimum recovery. High steam quality and temperature can also improve super heavy oil recovery. The oil recovery was less influenced by the effect of the surfactant than by the effect of CO{sub 2

  2. Uptake of heavy metals by Brachiaria Decumbens and its mutant as a remediation agent for soil contaminated with oil sludge

    International Nuclear Information System (INIS)

    Ahmad Nazrul Abd Wahid; Latiffah Noordin; Abdul Razak Ruslan; Hazlina Abdullah; Khairuddin Abdul Rahim

    2006-01-01

    The Malaysian petroleum industry produces thousands of tonnes of oil sludge per year. Oil sludge is the residue accumulated during processing of petroleum at petroleum processing plants. Besides soil, mud and sand, oil sludge is often rich in radioactive substances, heavy metals and other toxic materials from hydrocarbon group which could contaminate and environment. In the present study the pasture grass Brachiaria decumbens and its mutant B. decumbens Kluang Comel were evaluated on their effectiveness as remediation agents for contaminated soils. The contaminating agent tested was the oil sludge with its hydrocarbons vaporised, obtained from the Waste Management Centre, MINT. Amongst the indicators for an effective remediation agent is the ability to accumulate heavy metals in their tissues without affecting their growth. This trial was conducted at MINT glasshouse, whereby the test plants were planted in pots in soil added with vaporised oil sludge. Analysis of heavy metals was through Inductive Coupled Plasma Mass Spectrometry (ICPMS) and Neutron Activation Analysis (NAA). This paper discusses the accumulation of heavy metals by B. decumbens and its mutant Kluang Comel and their growth performance, hence assessing their suitability as remediation agent in soil contaminated with oil sludge. (Author)

  3. Degradation potential and microbial community structure of heavy oil-enriched microbial consortia from mangrove sediments in Okinawa, Japan.

    Science.gov (United States)

    Bacosa, Hernando P; Suto, Koichi; Inoue, Chihiro

    2013-01-01

    Mangroves constitute valuable coastal resources that are vulnerable to oil pollution. One of the major processes to remove oil from contaminated mangrove sediment is microbial degradation. A study on heavy oil- and hydrocarbon-degrading bacterial consortia from mangrove sediments in Okinawa, Japan was performed to evaluate their capacity to biodegrade and their microbial community composition. Surface sediment samples were obtained from mangrove sites in Okinawa (Teima, Oura, and Okukubi) and enriched with heavy oil as the sole carbon and energy source. The results revealed that all enriched microbial consortia degraded more than 20% of heavy oil in 21 days. The K1 consortium from Okukubi site showed the most extensive degradative capacity after 7 and 21 days. All consortia degraded more than 50% of hexadecane but had little ability to degrade polycyclic aromatic hydrocarbons (PAHs). The consortia were dominated by Pseudomonas or Burkholderia. When incubated in the presence of hydrocarbon compounds, the active bacterial community shifted to favor the dominance of Pseudomonas. The K1 consortium was a superior degrader, demonstrating the highest ability to degrade aliphatic and aromatic hydrocarbon compounds; it was even able to degrade heavy oil at a concentration of 15%(w/v). The dominance and turn-over of Pseudomonas and Burkholderia in the consortia suggest an important ecological role for and relationship between these two genera in the mangrove sediments of Okinawa.

  4. Feasibility study for the installation of a nuclear reactor in thermal stimulation processes in heavy oil extraction from Orinoco oil belt

    International Nuclear Information System (INIS)

    Munoz, A.; Sanchez, R.

    1982-01-01

    Due to strategic need in the exploitation of heavy and extraheavy oil wells of Orinoco oil belt, technical and economical studies have been carried out to determine an optimal method for oil production and exploitation. So far, studies indicate thermal stimulation is the most adequate technique. Experience shows that stimulation cost is high when traditional methods (boilers) are used. The profit is due to the high price of oil in international market. Due to actual oil price trends, evaluation of nontraditional methods to generate steam in thermal stimulation processes (steam injection) is in order. A nuclear reactor as steam generator was evaluated. It was found economical feasibility and saving in fuel cost between 31.08% and 72.63% depending on oil prices

  5. Increasing heavy oil reserves in the Wilmington Oil Field through advanced reservoir characterization and thermal production technologies. Annual report, March 30, 1995--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    The objective of this project is to increase heavy oil reserves in a portion of the Wilmington Oil Field, near Long Beach, California, by implementing advanced reservoir characterization and thermal production technologies. Based on the knowledge and experience gained with this project, these technologies are intended to be extended to other sections of the Wilmington Oil Field, and, through technology transfer, will be available to increase heavy oil reserves in other slope and basin clastic (SBC) reservoirs. The project involves implementing thermal recovery in the southern half of the Fault Block II-A Tar zone. The existing steamflood in Fault Block II-A has been relatively inefficient due to several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery efficiency and reduce operating costs.

  6. Simulation study of the VAPEX process in fractured heavy oil system at reservoir conditions

    Energy Technology Data Exchange (ETDEWEB)

    Azin, Reza; Ghotbi, Cyrus [Department of Chemical and Petroleum Engineering, Sharif Univ. Tech., Tehran (Iran); Kharrat, Riyaz; Rostami, Behzad [Petroleum University of Technology Research Center, Tehran (Iran); Vossoughi, Shapour [4132C Learned Hall, Department of Chemical and Petroleum Engineering, Kansas University, Lawrence, KS (United States)

    2008-01-15

    The Vapor Extraction (VAPEX) process, a newly developed Enhanced Oil Recovery (EOR) process to recover heavy oil and bitumen, has been studied theoretically and experimentally and is found a promising EOR method for certain heavy oil reservoirs. In this work, a simulation study of the VAPEX process was made on a fractured model, which consists of a matrix surrounded by horizontal and vertical fractures. The results show a very interesting difference in the pattern of solvent flow in fractured model compared with the conventional model. Also, in the fractured system, due to differences in matrix and fracture permeabilities, the solvent first spreads through the fractures and then starts diffusing into matrix from all parts of the matrix. Thus, the solvent surrounds the oil bank, and an oil rather than the solvent chamber forms and shrinks as the process proceeds. In addition, the recovery factor is higher at lower solvent injection rates for a constant pore volume of the solvent injected into the model. Also, the diffusion process becomes important and higher recoveries are obtained at low injection rates, provided sufficient time is given to the process. The effect of inter-connectivity of the surrounding fractures was studied by making the side vertical fractures shorter than the side length of the model. It was observed that inter-connectivity of the fractures affects the pattern of solvent distribution. Even for the case of side fractures being far apart from the bottom fracture, the solvent distribution in the matrix was significantly different than that in the model without fractures. Combination of diffusion phenomenon and gravity segregation was observed to be controlling factors in all VAPEX processes simulated in fractured systems. The early breakthrough of the solvent for the case of matrix surrounded by the fracture partially inhibited diffusion of the solvent into the oil and consequently the VAPEX process became the least effective. It is concluded

  7. The Geopolitics of Shale Gas : The Implications of the US' Shale Gas Revolution on Intrastate Stability within Traditional Oil- and Natural Gas-Exporting Countries in the EU Neighborhood

    NARCIS (Netherlands)

    Jong, S. de; Auping, W.; Govers, J.; Peters, M.C.A.M.; Widdershoven, C.J.C.G.; Weterings, R.A.P.M.

    2014-01-01

    The US’ shale gas revolution could in the long term destabilize traditional oil- and gas exporters in the European Union (EU) neighborhood: A combination of substitution effects and greater energy efficiency, could put pressure on the price of oil, leading to fiscal difficulties in traditional

  8. Oil-Sludge Extended Asphalt Mastic Filled with Heavy Oil Fly Ash and Cement Waste for Waterproofing

    Directory of Open Access Journals (Sweden)

    H.I. Al-Abdul Wahhab

    2014-12-01

    Full Text Available Recycling as an economic disposal process for many hazardous waste materials has become a popular means of conserving our planet’s scarce and diminishing natural resources. This paper is a study of the influence of oil sludge (OS on the physical behavior and performance of asphalt filled with heavy oil fly ash (HOFA, cement kiln dust (CKD and limestone dust (LMD. Conventional asphalt consistency tests in addition to a new bond strength (BS test were conducted on the modified asphalt mastics. The results were statistically analyzed and assessed in accordance with American Society for Testing and Materials (ASTM D 332 and ASTM D 449 specifications. Too much OS resulted in strength deterioration of the asphalt mastic, which can be compensated for by filling the mastic with HOFA. OS interacts constructively with the fillers to improve their effectiveness in raising the softening point (SP and viscosity of the asphalt, and also in reducing its penetration and ductility. Even though sludge mastics hold promise as suitable composites for damp proofing and waterproofing, the resulting low flash point (FP and SP of some of these mastics make their suitability for roofing applications questionable.

  9. Analysis of Palm Oil Production, Export, and Government Consumption to Gross Domestic Product of Five Districts in West Kalimantan by Panel Regression

    Science.gov (United States)

    Sulistianingsih, E.; Kiftiah, M.; Rosadi, D.; Wahyuni, H.

    2017-04-01

    Gross Domestic Product (GDP) is an indicator of economic growth in a region. GDP is a panel data, which consists of cross-section and time series data. Meanwhile, panel regression is a tool which can be utilised to analyse panel data. There are three models in panel regression, namely Common Effect Model (CEM), Fixed Effect Model (FEM) and Random Effect Model (REM). The models will be chosen based on results of Chow Test, Hausman Test and Lagrange Multiplier Test. This research analyses palm oil about production, export, and government consumption to five district GDP are in West Kalimantan, namely Sanggau, Sintang, Sambas, Ketapang and Bengkayang by panel regression. Based on the results of analyses, it concluded that REM, which adjusted-determination-coefficient is 0,823, is the best model in this case. Also, according to the result, only Export and Government Consumption that influence GDP of the districts.

  10. Nonthermal plasma reactors for the production of light hydrocarbon olefins from heavy oil

    Directory of Open Access Journals (Sweden)

    G. Prieto

    2003-03-01

    Full Text Available During the last decade, nonthermal plasma technology was applied in many different fields, focusing attention on the destruction of harmful compounds in the air. This paper deals with nonthermal plasma reactors for the conversion of heavy oil into light hydrocarbon olefins, to be employed as gasoline components or to be added in small amounts for the catalytic reduction of nitrogen oxide compounds in the treatment of exhaust gas at power plants. For the process, the plate-plate nonthermal plasma reactor driven by AC high voltage was selected. The reactor was modeled as a function of parameter characteristics, using the methodology provided by the statistical experimental design. The parameters studied were gap distance between electrodes, carrier gas flow and applied power. Results indicate that the reactions occurring in the process of heavy oil conversion have an important selective behavior. The products obtained were C1-C4 hydrocarbons with ethylene as the main compound. Operating the parameters of the reactor within the established operative window of the system and close to the optimum conditions, efficiencies as high as 70 (mul/joule were obtained. These values validate the process as an in-situ method to produce light olefins for the treatment of nitrogen oxides in the exhaust gas from diesel engines.

  11. Rapid detection of soils contaminated with heavy metals and oils by laser induced breakdown spectroscopy (LIBS).

    Science.gov (United States)

    Kim, Gibaek; Kwak, Jihyun; Kim, Ki-Rak; Lee, Heesung; Kim, Kyoung-Woong; Yang, Hyeon; Park, Kihong

    2013-12-15

    A laser induced breakdown spectroscopy (LIBS) coupled with the chemometric method was applied to rapidly discriminate between soils contaminated with heavy metals or oils and clean soils. The effects of the water contents and grain sizes of soil samples on LIBS emissions were also investigated. The LIBS emission lines decreased by 59-75% when the water content increased from 1.2% to 7.8%, and soil samples with a grain size of 75 μm displayed higher LIBS emission lines with lower relative standard deviations than those with a 2mm grain size. The water content was found to have a more pronounced effect on the LIBS emission lines than the grain size. Pelletizing and sieving were conducted for all samples collected from abandoned mining areas and military camp to have similar water contents and grain sizes before being analyzed by the LIBS with the chemometric analysis. The data show that three types of soil samples were clearly discerned by using the first three principal components from the spectral data of soil samples. A blind test was conducted with a 100% correction rate for soil samples contaminated with heavy metals and oil residues. Copyright © 2013 Elsevier B.V. All rights reserved.

  12. Hydrotreatment of heavy oil from coal liquefaction on Sulfide Ni - W Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Zhi-ping Lei; Li-juan Gao; Heng-fu Shui; Shi-biao, Ren; Zhi-cai Wang; Kang-shi Gang, E-mail: shhf@ahut.edu.c [Anhui University of Technology, Maanshan (China). School of Chemistry and Chemical Engineering. Anhui Key Lab. of Coal Clean Conversion and Utilization

    2011-07-01

    Heavy oil (distillation temperature: 320-340 deg C) derived from the direct coal liquefaction process using Shengli coal were hydrotreated using sulfided Ni-Mo/Al{sub 2}O{sub 3}, Ni-W/Al{sub 2}O{sub 3}, and Ni-W/SiO{sub 2} catalysts respectively. The sulfided catalysts were characterized by BET, XRD, H{sub 2}-TPR and NH{sub 3}-TPD respectively. The evaluations of the hydrodenitrogenation (HDN) and hydrodearomatization (HDA) properties of heavy oil on the three catalysts were carried out at 400 deg C and 5.0 MPa initial H2 pressure. The W-based catalysts displayed better performances than Mo-based catalysts for the HDN and HDA reactions. Al{sub 2}O{sub 3} supported catalysts were found to have higher catalytic activities than on SiO{sub 2} supported ones. The activities of sulfided catalysts were associated mainly with the nature of active sites, acidity, metal sulfide crystallite size and the amount of the reducible sulfur species of metal sulfide. (author)

  13. Hydrotreatment of heavy oil from coal liquefaction on Sulfide Ni - W Catalysts

    International Nuclear Information System (INIS)

    Zhi-ping Lei; Li-juan Gao; Heng-fu Shui; Shi-biao, Ren; Zhi-cai Wang; Kang-shi Gang

    2011-01-01

    Heavy oil (distillation temperature: 320-340 deg C) derived from the direct coal liquefaction process using Shengli coal were hydrotreated using sulfided Ni-Mo/Al 2 O 3 , Ni-W/Al 2 O 3 , and Ni-W/SiO 2 catalysts respectively. The sulfided catalysts were characterized by BET, XRD, H 2 -TPR and NH 3 -TPD respectively. The evaluations of the hydrodenitrogenation (HDN) and hydrodearomatization (HDA) properties of heavy oil on the three catalysts were carried out at 400 deg C and 5.0 MPa initial H2 pressure. The W-based catalysts displayed better performances than Mo-based catalysts for the HDN and HDA reactions. Al 2 O 3 supported catalysts were found to have higher catalytic activities than on SiO 2 supported ones. The activities of sulfided catalysts were associated mainly with the nature of active sites, acidity, metal sulfide crystallite size and the amount of the reducible sulfur species of metal sulfide. (author)

  14. An approach for characterization and lumping of plus fractions of heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, I.; Hamouda, A.A. [Stavanger Univ., Stavanger (Norway)

    2008-10-15

    The constituents of hydrocarbons can be classified as either well-defined components or undefined petroleum fractions. This paper presented a newly developed method for characterizing plus fractions of heavy oil, which is particularly important for fluids with high molecular weight and high density. Characterization of plus fractions typically consists of 3 parts, notably splitting the fraction into a certain number of components groups called single carbon number (SCN); estimating the physico-chemical properties of the SCN; and lumping the generated SCN. SCN groups contain hundreds of isomers/components with the same number of carbon atoms. A unique molecular weight cannot be assigned for each SCN group because of the uncertainty of the isomers/components present. Therefore, this work focused on finding a new approach to characterize the undetermined fraction by first splitting the carbon number fraction into a representative number of SCN and then calculating their mole fraction and molecular weight. The method was based on the relationships between three parameter gamma distribution (TPG), experimental mole fraction, molecular weight and SCN data obtained from literature and industry. The method was applied to 5 different heavy oil sample fluids which all showed a left skewed distribution of the mole fraction as a function of carbon number. The predicted molecular weight was found to be close to the generalized molecular weight associated with carbon number, but it differed from one sample to another. 19 refs., 11 tabs., 15 figs.

  15. Features of hydrotreating catalytic cracking feed and heavy slow coking gas oils

    Energy Technology Data Exchange (ETDEWEB)

    Yefremov, N.I.; Kushnarev, D.F.; Frolov, P.A.; Chagovets, A.N.; Kalabin, G.A.

    1993-12-31

    A possible means of more extensive processing of crude oil is the use, in catalytic cracking, of heavy coking gas oils (HCGOs), a feature of which is a higher content of polycyclic aromatic compounds and resins by comparison with straight-run vacuum distillates. The presence of these compounds in catalytic cracking feed causes a reduction in the product yield and increased coke formation. Therefore, one of the problems of hydrotreating feedstock of this kind is the hydrogenation of polycyclic arenes. Processes of extensive desulphurization and denitration occur in parallel, since the sulphur and nitrogen compounds of HCGO are chiefly condensed benzoderivatives of thiophene, pyridine and carbazole, and largely concentrated in heavy aromatic and resinous fractions. The composition of the saturated part of the cracking feed plays a large role in achieving the optimum yields of gaseous and gasoline fractions. Thus an increase in the proportion of cyclanes in the feed raises the gasoline yield. In this way, an investigation of the hydrocarbon conversions during the hydrotreatment of cracking feed is of great importance. The present paper sets out the results for studying the change in the group-structural characteristics of the hydrogenation products of a mixture containing 30% HCGOs according to data of {sup 1}H and {sup 13}C NMR spectroscopy. 7 refs., 7 figs., 1 tab.

  16. Combined production of hydrogen and power from heavy oil gasification: Pinch analysis, thermodynamic and economic evaluations

    Energy Technology Data Exchange (ETDEWEB)

    Domenichini, R.; Gallio, M. [Foster Wheeler Italiana Spa, via Caboto 1, 20094 Corsico (Milano) (Italy); Lazzaretto, A. [University of Padova, Department of Mechanical Engineering, via Venezia 1, 35131 Padova (Italy)

    2010-05-15

    Integrated Gasification Combined Cycle (IGCC) represents a commercially proven technology available for the combined production of hydrogen and electricity power from coal and heavy residue oils. When associated with CO{sub 2} capture and sequestration facilities, the IGCC plant gives an answer to the search for a clean and environmentally compatible use of high sulphur and heavy metal contents fuels, the possibility of installing large size plants for competitive electric power and hydrogen production, and a low cost of CO{sub 2} avoidance. The paper describes two new and realistic configurations of IGCC plant fed by refinery heavy residues and including a CO{sub 2} capture section, which are proposed on the basis of the experience gained in the construction of similar plants. They are based on oxygen blown entrained bed gasification and sized to produce a large amount of hydrogen and to feed one or two gas turbines of the combined cycle unit. The main thermodynamic and technological characteristics of the total plants are evaluated focusing on the heat integration between syngas cooling and combined cycle sections. Moreover, the overall performance characteristics and investment cost are estimated to supply a reliable estimate for the cost of electricity, given a value for the hydrogen selling price. (author)

  17. Combined production of hydrogen and power from heavy oil gasification: Pinch analysis, thermodynamic and economic evaluations

    International Nuclear Information System (INIS)

    Domenichini, R.; Gallio, M.; Lazzaretto, A.

    2010-01-01

    Integrated Gasification Combined Cycle (IGCC) represents a commercially proven technology available for the combined production of hydrogen and electricity power from coal and heavy residue oils. When associated with CO 2 capture and sequestration facilities, the IGCC plant gives an answer to the search for a clean and environmentally compatible use of high sulphur and heavy metal contents fuels, the possibility of installing large size plants for competitive electric power and hydrogen production, and a low cost of CO 2 avoidance. The paper describes two new and realistic configurations of IGCC plant fed by refinery heavy residues and including a CO 2 capture section, which are proposed on the basis of the experience gained in the construction of similar plants. They are based on oxygen blown entrained bed gasification and sized to produce a large amount of hydrogen and to feed one or two gas turbines of the combined cycle unit. The main thermodynamic and technological characteristics of the total plants are evaluated focusing on the heat integration between syngas cooling and combined cycle sections. Moreover, the overall performance characteristics and investment cost are estimated to supply a reliable estimate for the cost of electricity, given a value for the hydrogen selling price.

  18. Near-Infrared Spectroscopy Analysis of Heavy Fuel Oils Using a New Diffusing Support.

    Science.gov (United States)

    Dupuy, Nathalie; Brahem, Zeineb; Amat, Sandrine; Kister, Jacky

    2015-10-01

    The characterization of heavy fuel oils (HFOs), used as fuel for boats, requires the analysis of various properties that are essential for engine optimization and pollution control. For some time, near-infrared (NIR) spectroscopy combined with chemometric treatment of the spectra was used for on-line analysis. This preliminary study included 61 heavy fuels from Europe, America, and Asia with different specifications according to their geographical origin; their refining process; and their physicochemical properties, including density, flash point, viscosity, and sulfur content. We have developed a new method for sampling heavy fuels on a fiberglass cell support. This support offers the advantages of speed, easy implementation, repeatable results, and freedom from problems associated with tank cleaning. Two sample presentations, an integrating sphere and an optical fiber, were used to collect the NIR spectra. A theoretical study of the choice of the value of resolution, scan number, and spectral region was conducted. The best conditions were chosen as a function of the quality of quantitative analysis results on viscosity, sulfur content, flash point, and density. The two collecting methods were compared on the same criteria.

  19. Un Manifesto economico per i paesi del Golfo Persico esportatori di petrolio(An Economic Manifesto for the Oil Exporting Countries of the Persian Gulf

    Directory of Open Access Journals (Sweden)

    Hossein Askari

    2012-04-01

    Full Text Available The oil-exporting countries of the Persian Gulf have failed economically and socially. It is time for a radical new approach to managing oil revenues while oil and gas reserves last. We propose an approach to cut the level of oil revenues available to governments to zero while incorporating a formal "Oil Fund for All Generations". Others have proposed and implemented oil funds but in our proposal the government would (in time lose all access to oil revenues; by taking easy money away from governments and rulers, waste, corruption, military expenditures and wars will be reduced, there will be better chance of adopting and implementing rational economic policies, and equity across generations may be enhanced. Hope may be slowly restored to a region that has lost hope. I paesi del Golfo Persico esportatori di petrolio hanno fallito dal punto di vista economico e sociale. È tempo di adottare un approccio radicalmente nuovo alla gestione dei ricavi petroliferi finché vi sono ancora riserve di petrolio e di gas. Noi proponiamo un approccio finalizzato ad azzerare il livello dei ricavi disponibili per i governi, istituendo allo stesso tempo un formale “Fondo petrolifero per tutte le generazioni”. Fondi petroliferi sono stati ipotizzati e realizzati anche da altri, ma nella nostra proposta il governo perderebbe (col tempo qualunque accesso ai ricavi petroliferi; sottraendo denaro facile ai governi e ai sovrani, la probabilità di sprechi, corruzione e guerre risulterebbe ridotta, e vi sarebbe maggiore possibilità di adottare e mettere in pratica politiche economiche razionali finalizzate ad accrescere l’equità tra le generazioni.  JEL Codes: O13, O53, Q48Keywords: Gas; Oil

  20. Methanogenic degradation of petroleum hydrocarbons in subsurface environments remediation, heavy oil formation, and energy recovery.

    Science.gov (United States)

    Gray, N D; Sherry, A; Hubert, C; Dolfing, J; Head, I M

    2010-01-01

    Hydrocarbons are common constituents of surface, shallow, and deep-subsurface environments. Under anaerobic conditions, hydrocarbons can be degraded to methane by methanogenic microbial consortia. This degradation process is widespread in the geosphere. In comparison with other anaerobic processes, methanogenic hydrocarbon degradation is more sustainable over geological time scales because replenishment of an exogenous electron acceptor is not required. As a consequence, this process has been responsible for the formation of the world's vast deposits of heavy oil, which far exceed conventional oil assets such as those found in the Middle East. Methanogenic degradation is also a potentially important component of attenuation in hydrocarbon contamination plumes. Studies of the organisms, syntrophic partnerships, mechanisms, and geochemical signatures associated with methanogenic hydrocarbon degradation have identified common themes and diagnostic markers for this process in the subsurface. These studies have also identified the potential to engineer methanogenic processes to enhance the recovery of energy assets as biogenic methane from residual oils stranded in petroleum systems. Copyright 2010 Elsevier Inc. All rights reserved.

  1. INTERFACIAL ENERGY DURING THE EMULSIFICATION OF WATER-IN-HEAVY CRUDE OIL EMULSIONS

    Directory of Open Access Journals (Sweden)

    V. Karcher

    2015-03-01

    Full Text Available Abstract The aim of this study was to investigate the interfacial energy involved in the production of water-in-oil (W/O emulsions composed of water and a Brazilian heavy crude oil. For such purpose an experimental set-up was developed to measure the different energy terms involved in the emulsification process. W/O emulsions containing different water volume fractions (0.1, 0.25 and 0.4 were prepared in a batch calorimeter by using a high-shear rotating homogenizer at two distinct rotation speeds (14000 and 22000 rpm. The results showed that the energy dissipated as heat represented around 80% of the energy transferred to the emulsion, while around 20% contributed to the internal energy. Only a very small fraction of the energy (0.02 - 0.06% was stored in the water-oil interface. The results demonstrated that the high energy dissipation contributes to the kinetic stability of the W/O emulsions.

  2. Treatment of heavy oil wastewater by UASB-BAFs using the combination of yeast and bacteria.

    Science.gov (United States)

    Zou, Xiao-Ling

    2015-01-01

    A novel system integrating an upflow anaerobic sludge blanket (UASB) reactor and a two-stage biological aerated filter (BAF) system was investigated as advanced treatment of heavy oil wastewater with large amounts of dissolved recalcitrant organic substances and low levels of nitrogen and phosphorus nutrients. #1 BAF, inoculated with two yeast strains (Candida tropicalis and Rhodotorula dairenensis), was installed in the upper reaches of #2 BAF inoculated with activated sludge. During the 180-day study period, the chemical oxygen demand (COD), ammonia nitrogen (NH3-N), oil and polyaromatic hydrocarbons (PAHs) in the wastewater were removed by 90.2%, 90.8%, 86.5% and 89.4%, respectively. Although the wastewater qualities fluctuated and the hydraulic retention time continuously decreased, the effluent quality index met the national discharge standard steadily. The UASB process greatly improved the biodegradability of the wastewater, while #1 BAF played an important role not only in degrading COD but also in removing oil and high molecular weight PAHs. This work demonstrates that the hybrid UASB-BAFs system containing yeast-bacteria consortium has the potential to be used in bioremediation of high-strength oily wastewater.

  3. A new flooding scheme by horizontal well in thin heavy oil reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Liu, H.; Zhang, H.; Wang, M. [China Univ. of Petroleum, Beijing (China). MOE Key Laboratory of Petroleum Engineering ; Wang, Z. [Shengli Oil Field Co. (China). Dept. of Science and Technology]|[SINOPEC, Shengli (China)

    2008-10-15

    This paper presented a new flooding scheme for single horizontal wells that could improve recovery from thin marginal heavy oil reservoirs or from offshore reservoirs. The scheme involved the use of a multiple tubing string completion in a single wellbore. Special packers were installed within the long completion horizontal interval to establish an injection zone and a production zone. The new flooding scheme also involved simultaneous injection and production. Numerical simulation of the reservoir was used to determine the thickness of the formation and the lower limitation for different viscosities and the optimum time to start steam flooding after steam soaking by economic oil/steam ratio. The peak recovery efficiency of steam flooding was shown to occur when the length of separation section ratio is 0.15 to 0.2. It was concluded that high thermal efficiency in horizontal wells with long completion intervals can be maintained by alternating between steam soaking and steam flooding. Suitable alternation time to steam flooding is a seventh cycle for horizontal wells. Water cut and pressure difference will increase the steam injection rate, and thereby improve the oil production rate. The suitable injection rate for steam flooding is 2.4 t/d.ha.h because of its slow pressure change. 11 refs., 7 figs.

  4. Seabird feathers as monitors of the levels and persistence of heavy metal pollution after the Prestige oil spill

    International Nuclear Information System (INIS)

    Moreno, Rocio; Jover, Lluis; Diez, Carmen; Sanpera, Carola

    2011-01-01

    We measured heavy metal concentrations in yellow-legged gulls (n = 196) and European shags (n = 189) in order to assess the temporal pattern of contaminant exposure following the Prestige oil spill in November 2002. We analysed Pb, Cu, Zn, Cr, Ni and V levels in chick feathers sampled at four colonies during seven post-spill years (2003-2009), and compared results with pre-spill levels obtained from feathers of juvenile shag corpses (grown in spring/summer 2002). Following the Prestige wreck, Cu (4.3-10 μg g -1 ) and Pb concentrations (1.0-1.4 μg g -1 ) were, respectively, between two and five times higher than pre-spill levels (1.5-3.6 and 0.1-0.4 μg g -1 ), but returned to previous background concentrations after three years. Our study highlights the suitability of chick feathers of seabirds for assessing the impact of oil spills on heavy metal contamination, and provides the best evidence to date on the persistence of oil pollution after the Prestige incident. - Highlights: → Seabirds as sentinel species of levels and persistence of heavy metal pollution after oil spills. → Pb, Cu, Zn, Cr, Ni, V in chick feathers of Phalacrocorax aristotelis and Larus michahellis. → Chronic oil pollution in the marine food web for at least three years after the Prestige oil spill. - Monitoring heavy metal in seabird feathers indicated chronic oil pollution in the marine food web for at least three years after the Prestige oil spill.

  5. Spatial variance of POPs and heavy metals in transformer oil-contaminated soil around Tamil Nadu.

    Science.gov (United States)

    Murugan, Karuvelan; Vasudevan, Namasivayam

    2017-09-05

    The persistent organic pollutants in the environment are one of the global issues to their unregulated disposal and informal recycling. This study investigates the contamination of soil with polychlorinated biphenyls (PCBs), polyaromatic hydrocarbons (PAHs), phenolic compounds and heavy metals via spillage of transformer oil (TO). Fresh TO (FTO), used TO (UTO) and soil samples were analysed using GC-MS to confirm the presence of 8 PCB congeners, 16 PAHs and 24 types of phenolic compounds and using inductively coupled plasma optical emission spectrometry to confirm the presence of 7 heavy metals. The chromatographic analysis revealed the levels of mono-, di-, tri-, tetra-, penta-, hexa-, hepta- and octachlorobiphenyls in FTO to be 5.63, 25.24, 0.195, 0.185, 2.169, 1.023 and 5.28 mg/L and the level of mono-, di-, tri-, tetra-, penta- and hexachlorobiphenyls in UTO to be 0.27, 1.21, 1.31, 0.80, 1.77 and 3.90 mg/L. Analysis of soil from 10 different TO-contaminated sites showed the presence of PCBs, PAHs, phenolic compounds and heavy metals in the concentration range of 0.53-42.87 mg/kg, 3.19-246.6 μg/kg, 0.01-4086.45 μg/kg and 1.0-401.3 mg/kg, respectively. The variation in the concentration of these compounds and heavy metals among different sampling sites was determined using principal component analysis (PCA), metric multi-dimensional scaling (MDS) and Bray-Curtis cluster analysis (Bu-CA). The toxicity equivalence factor and the mechanism involved in the disruption of endocrine system are discussed. Thus, this study exemplifies the need for complete ban of PCB-containing TOs in developing countries and urges the need for technology for the disposal of TO.

  6. The Diversity of Endophytic Methylotrophic Bacteria in an Oil-Contaminated and an Oil-Free Mangrove Ecosystem and Their Tolerance to Heavy Metals

    Science.gov (United States)

    Dourado, Manuella Nobrega; Ferreira, Anderson; Araújo, Welington Luiz; Azevedo, João Lúcio; Lacava, Paulo Teixeira

    2012-01-01

    Methylobacterium strains were isolated from mangrove samples collected in Bertioga, SP, Brazil, from locations either contaminated or uncontaminated by oil spills. The tolerances of the strains to different heavy metals were assessed by exposing them to different concentrations of cadmium, lead, and arsenic (0.1 mM, 0.5 mM, 1 mM, 2 mM, 4 mM, and 8 mM). Additionally, the genetic diversity of Methylobacterium spp. was determined by sequence analysis of the 16S rRNA genes. The isolates from the contaminated locations were grouped, suggesting that oil can select for microorganisms that tolerate oil components and can change the methylotrophic bacterial community. Cadmium is the most toxic heavy metal assessed in this work, followed by arsenic and lead, and two isolates of Methylobacterium were found to be tolerant to all three metals. These isolates have the potential to bioremediate mangrove environments contaminated by oil spills by immobilizing the heavy metals present in the oil. PMID:22482056

  7. The diversity of endophytic methylotrophic bacteria in an oil-contaminated and an oil-free mangrove ecosystem and their tolerance to heavy metals.

    Science.gov (United States)

    Dourado, Manuella Nobrega; Ferreira, Anderson; Araújo, Welington Luiz; Azevedo, João Lúcio; Lacava, Paulo Teixeira

    2012-01-01

    Methylobacterium strains were isolated from mangrove samples collected in Bertioga, SP, Brazil, from locations either contaminated or uncontaminated by oil spills. The tolerances of the strains to different heavy metals were assessed by exposing them to different concentrations of cadmium, lead, and arsenic (0.1 mM, 0.5 mM, 1 mM, 2 mM, 4 mM, and 8 mM). Additionally, the genetic diversity of Methylobacterium spp. was determined by sequence analysis of the 16S rRNA genes. The isolates from the contaminated locations were grouped, suggesting that oil can select for microorganisms that tolerate oil components and can change the methylotrophic bacterial community. Cadmium is the most toxic heavy metal assessed in this work, followed by arsenic and lead, and two isolates of Methylobacterium were found to be tolerant to all three metals. These isolates have the potential to bioremediate mangrove environments contaminated by oil spills by immobilizing the heavy metals present in the oil.

  8. Non-Newtonian Flow Characteristics of Heavy Oil in the Bohai Bay Oilfield: Experimental and Simulation Studies

    Directory of Open Access Journals (Sweden)

    Xiankang Xin

    2017-10-01

    Full Text Available In this paper, physical experiments and numerical simulations were applied to systematically investigate the non-Newtonian flow characteristics of heavy oil in porous media. Rheological experiments were carried out to determine the rheology of heavy oil. Threshold pressure gradient (TPG measurement experiments performed by a new micro-flow method and flow experiments were conducted to study the effect of viscosity, permeability and mobility on the flow characteristics of heavy oil. An in-house developed novel simulator considering the non-Newtonian flow was designed based on the experimental investigations. The results from the physical experiments indicated that heavy oil was a Bingham fluid with non-Newtonian flow characteristics, and its viscosity-temperature relationship conformed to the Arrhenius equation. Its viscosity decreased with an increase in temperature and a decrease in asphaltene content. The TPG measurement experiments was impacted by the flow rate, and its critical flow rate was 0.003 mL/min. The TPG decreased as the viscosity decreased or the permeability increased and had a power-law relationship with mobility. In addition, the critical viscosity had a range of 42–54 mPa∙s, above which the TPG existed for a given permeability. The validation of the designed simulator was positive and acceptable when compared to the simulation results run in ECLIPSE V2013.1 and Computer Modelling Group (CMG V2012 software as well as when compared to the results obtained during physical experiments. The difference between 0.0005 and 0.0750 MPa/m in the TPG showed a decrease of 11.55% in the oil recovery based on the simulation results, which demonstrated the largely adverse impact the TPG had on heavy oil production.

  9. Gasification of coal as efficient means of environment protection and hydrogenation of heavy oils residues

    Energy Technology Data Exchange (ETDEWEB)

    Krichko, A.A.; Maloletnev, A.S. [Fossil Fuel Institute, Moscow (Russian Federation)

    1995-12-31

    The Russia`s more then 50% of coals produced in its European part contain over 2,5% of sulphur, and the coals containing less than 1.5% of sulphurs comprise ca.20%. Thus, utilisation of the sulphide coals is inevitable, and there a problem arises concerning the technology of their sensible use and considering the requirements on the environment protection. Russia`s specialists have developed a design and construction for a steam-gas installation with a closed cycle gasification of the solid fuel. The gasification process will proceed in the fluidized bed under forced pressure of the steam-air blast. Characteristic features of this process are the following: a higher efficiency (the capacity of one gas generator is 3-3,5 times larger than that attained in the present gas generators of the Lurgy`s type): 2-2,5 times decreased fuel losses as compared to the Winkler`s generators; retention of the sensible heat, resulting in an increased total energy efficiency. The main task for petroleum refining industry at the present stage is the increase of depth of oil processing with the aim to intensify motor fuel production. One of the ways to solve the problem is to involve heavy oil residues into the processing. But the high metal and asphaltenes contents in the latter make the application of traditional methods and processes more difficult. Up to now there is no simple and effective technology which could give the opportunity to use oil residues for distillate fractions production. In Fossil fuel institute a process for hydrogenation of high boiling oil products, including with high sulphur, vanadium and nickel contents ones, into distillates and metals concentrates. The main point of the new process is as follows: the water solution of catalytic additive, for which purpose water soluble metal salts of VI-VIII groups are used, is mixed with tar, dispersed and then subjected to additional supercavitation in a special apparatus.

  10. Reservoir characterization and monitoring of cold and thermal heavy oil production using multi-transient EM

    Energy Technology Data Exchange (ETDEWEB)

    Engelmark, F. [Petroleum Geo-Services Asia Pacific Pte Ltd., Singapore (Singapore)

    2008-10-15

    This study emphasized the importance of mapping the in situ subsurface distribution of heavy oil for evaluating the amount of oil in place. The multi-transient electromagnetic (MTEM) method was shown to be an ideal method to characterize the large scale distribution of oil, including the average saturation levels, on the scale needed to optimize oil extraction using steam assisted gravity drainage (SAGD) and cyclic steam stimulation (CSS). A feasibility study for an MTEM monitoring project would simulate reservoir temperature, water saturation and salinity to determine the evolution over time expressed in resistivity and the expanding steam chamber. The 4 factors influencing the resistivity in the monitoring phase were discussed. The temperature due to steaming causes a significant drop in resistivity of the affected rock volume, while the changes in water saturation affect resistivity. The drop in salinity of the pore water due to mixing with distilled water originating in the condensation of the injected steam causes an increase in resistivity, while the mineral dissolution and overall volume expansion causes formation damage that permanently changes the rock fabric. The overall effect of steam injection is a reduction in resistivity within the main part of the chamber, with a sudden increase in resistivity in the proximity of the injection well due to salt depletion. The lowered resistivity within a halo outside the steam chamber can be attributed to the heat radiation front expanding faster than the maturing steam chamber. The author noted that reservoir simulators do not yet incorporate the dynamic changes in porosity and permeability that are observed as permanent reductions of the elastic moduli and reduced resistivity. It was concluded that in order to fully describe the evolution of the steam chamber, this so called formation damage must be better understood. 6 refs., 7 figs.

  11. Multicomponent seismic reservoir characterization of a steam-assisted gravity drainage (SAGD) heavy oil project, Athabasca oil sands, Alberta

    Science.gov (United States)

    Schiltz, Kelsey Kristine

    Steam-assisted gravity drainage (SAGD) is an in situ heavy oil recovery method involving the injection of steam in horizontal wells. Time-lapse seismic analysis over a SAGD project in the Athabasca oil sands deposit of Alberta reveals that the SAGD steam chamber has not developed uniformly. Core data confirm the presence of low permeability shale bodies within the reservoir. These shales can act as barriers and baffles to steam and limit production by prohibiting steam from accessing the full extent of the reservoir. Seismic data can be used to identify these shale breaks prior to siting new SAGD well pairs in order to optimize field development. To identify shale breaks in the study area, three types of seismic inversion and a probabilistic neural network prediction were performed. The predictive value of each result was evaluated by comparing the position of interpreted shales with the boundaries of the steam chamber determined through time-lapse analysis. The P-impedance result from post-stack inversion did not contain enough detail to be able to predict the vertical boundaries of the steam chamber but did show some predictive value in a spatial sense. P-impedance from pre-stack inversion exhibited some meaningful correlations with the steam chamber but was misleading in many crucial areas, particularly the lower reservoir. Density estimated through the application of a probabilistic neural network (PNN) trained using both PP and PS attributes identified shales most accurately. The interpreted shales from this result exhibit a strong relationship with the boundaries of the steam chamber, leading to the conclusion that the PNN method can be used to make predictions about steam chamber growth. In this study, reservoir characterization incorporating multicomponent seismic data demonstrated a high predictive value and could be useful in evaluating future well placement.

  12. Electricity generation analyses in an oil-exporting country: Transition to non-fossil fuel based power units in Saudi Arabia

    International Nuclear Information System (INIS)

    Farnoosh, Arash; Lantz, Frederic; Percebois, Jacques

    2014-01-01

    In Saudi Arabia, fossil-fuel is the main source of power generation. Due to the huge economic and demographic growth, the electricity consumption in Saudi Arabia has increased and should continue to increase at a very fast rate. At the moment, more than half a million barrels of oil per day is used directly for power generation. Herein, we assess the power generation situation of the country and its future conditions through a modelling approach. For this purpose, we present the current situation by detailing the existing generation mix of electricity. Then we develop an optimization model of the power sector which aims to define the best production and investment pattern to reach the expected demand. Subsequently, we will carry out a sensitivity analysis so as to evaluate the robustness of the model's by taking into account the integration variability of the other alternative (non-fossil fuel based) resources. The results point out that the choices of investment in the power sector strongly affect the potential oil's exports of Saudi Arabia. For instance, by decarbonizing half of its generation mix, Saudi Arabia can release around 0.5 Mb/d barrels of oil equivalent per day from 2020. Moreover, total power generation cost reduction can reach up to around 28% per year from 2030 if Saudi Arabia manages to attain the most optimal generation mix structure introduced in the model (50% of power from renewables and nuclear power plants and 50% from the fossil power plants). - Highlights: • We model the current and future power generation situation of Saudi Arabia. • We take into account the integration of the other alternative resources. • We consider different scenarios of power generation structure for the country. • Optimal generation mix can release considerable amount of oil for export

  13. Exploration and production. Know-how. Extra-heavy oils and bitumen. Reserves for the future

    International Nuclear Information System (INIS)

    2004-01-01

    How can ever-expanding needs be met without jeopardizing reserve life? The answers can be summed up in a single word: the innovation. In this framework the Group Total developed their research and development activities, which are endowed with a annual budget of more than 100 million dollars. Tools from seismic imaging to thermodynamic modeling of fluids and flows in any type of reservoir can be used in combination in order to steadily reduce uncertainties and control risks. These tools will help make technologically and economically feasible to produce new resources such extra-heavy crudes, very acid gases, deeply-buried reservoirs or oil and gas reserves situated in ultra deep waters. (A.L.B.)

  14. Transient flow assurance for determination of operational control of heavy oil pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Cabrejo, Victor [TransCanada Pipelines Ltd, (Canada); Mohitpour, Mo [Tempsys Pipeline Solutions Inc., (Canada)

    2010-07-01

    Pipeline transmission systems have been designed traditionally using steady state simulations. Steady state simulation provided sufficient values for simple systems, but is limited in dealing with surges in flow rates, loss of facilities and facility operation. A dynamic approach is required to test the capacity of a system for various fluids. This paper investigated the use of transient analysis of liquid pipelines in order to improve the design of these pipelines and to achieve operational benefits. The transient method and its use are discussed. Dynamic analysis was applied to the Keystone Pipeline Project. The purpose of the study was first to determine the system capacity and data for transportation of Heavy DilBit, and then to implement batch transportation of a volume of synthetic crude oil. It was found that the use of transient modeling in design and operational assessment of a liquid pipeline ensures system capability, control, safety and integrity.

  15. Fitting the project into the environment : Gulf Heavy Oil Red Cross Projects

    International Nuclear Information System (INIS)

    Sakires, D.G.; Johannesen, D.V.

    1998-01-01

    A reservoir delineation project by Gulf Canada's Heavy Oil Division was reviewed. The six well drilling program was completed in 1997 with minimal negative environmental impacts. The program, dubbed the Red Cross project, took place in the Northern Boreal Forest of Saskatchewan. Its success is attributed to the early involvement of the regulatory agencies in Saskatchewan, on-site environmental investigations, the development of an environmental protection plan, conscientious construction practices, a monitoring program during construction, and a pro-active reclamation plan. The project area is identified as being environmentally sensitive and important as a wildlife habitat area. This successful project demonstrated the usefulness of pre-project planning and team work between industry and the regulators. Details of the planning, construction and planned remedial reclamation actions are described. 11 refs., 2 tabs

  16. CFD Analysis of Coal and Heavy Oil Gasification for Syngas Production

    DEFF Research Database (Denmark)

    Sreedharan, Vikram

    2012-01-01

    This work deals with the gasification of coal and heavy oil for syngas production using Computational Fluid Dynamics (CFD). Gasification which includes complex physical and chemical processes such as turbulence, multiphase flow, heat and mass transfer and chemical reactions has been modeled using...... phases. Gasification consists of the processes of passive heating, devolatilization, volatiles oxidation, char gasification and gas phase reactions. Attention is given here to the chemical kinetics of the gasification processes. The coal gasification model has been validated for entrained-flow gasifiers...... a discrete phase model. In this model, the continuous phase is described by Eulerian conservation equations and the discrete phase is described by tracking individual particles in a Lagrangian framework. A two-way coupling accounts for momentum, heat and mass transfer between the continuous and discrete...

  17. Reburning and burnout simulations of natural gas for heavy oil combustion

    Energy Technology Data Exchange (ETDEWEB)

    Celso A. Bertran; Carla S.T. Marques; Renato V. Filho [Universidade Estadual de Campinas, Campinas (Brazil). Instituto de Quimica

    2004-01-01

    Reburning and burnout simulations were carried out through PLUG code of CHEMKIN-III using a reduced mechanism, in order to determine preliminary experimental parameters for achieving maximum NOx reduction to implement the reburning technology for heavy oil combustion in pilot scale equipments in Brazil. Gas compositions at the entrance of the reburning zone were estimated by the AComb program. Simulations were performed for eight conditions in the usual range of operational parameters for natural gas reburning. The maximum NO reduction (ca. 50%) was reached with 10 and 17.5% of power via natural gas and 1.5 and 3.0% O{sub 2} excess, respectively, at 1273 K. The model predicts 250 ppm of NO, 50 ppm of CO and air mass flows in the range of about 50 130 kg/h for burnout. 18 refs., 1 fig., 2 tabs.

  18. Selective Production of Aromatic Aldehydes from Heavy Fraction of Bio-oil via Catalytic Oxidation

    International Nuclear Information System (INIS)

    Li, Yan; Chang, Jie; Ouyang, Yong; Zheng, Xianwei

    2014-01-01

    High value-added aromatic aldehydes (e. g. vanillin and syringaldehyde) were produced from heavy fraction of bio-oil (HFBO) via catalytic oxidation. The concept is based on the use of metalloporphyin as catalyst and hydrogen peroxide (H 2 O 2 ) as oxidant under alkaline condition. The biomimetic catalyst cobalt(II)-sulfonated tetraphenylporphyrin (Co(TPPS 4 )) was prepared and characterized. It exhibited relative high activity in the catalytic oxidation of HFBO. 4.57 wt % vanillin and 1.58 wt % syringaldehyde were obtained from catalytic oxidation of HFBO, compared to 2.6 wt % vanillin and 0.86 wt % syringaldehyde without Co(TPPS 4 ). Moreover, a possible mechanism of HFBO oxidation using Co(TPPS 4 )/H 2 O 2 was proposed by the research of model compounds. The results showed that this is a promising and environmentally friendly method for production of aromatic aldehydes from HFBO under Co(TPPS 4 )/H 2 O 2 system

  19. Delayed coking studies on Athabasca bitumen and Cold Lake heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Govindhakannan, J.; Khulbe, C. [National Centre for Upgrading Technology, Devon, AB (Canada); Natural Resources Canada, Devon, AB (Canada). CanmetENERGY

    2009-07-01

    This poster highlighted the results of a study that quantified the delayed coking product yields of Athabasca bitumen and Cold Lake heavy oil. It also investigated the effect of operating pressure and feed rates on product yield and quality. The effect of pressure on conversion of sulphur and nitrogen was also examined. Experimental results revealed that the yield of liquid products decreases and the yields of coke and gases increase as the operating pressure increases. Sulphur and nitrogen conversions increase with increasing pressure. In this study, the yield and quality of delayed coking products were not influenced by the variation in feed rates. It was concluded that feed rate changes do not significantly affect the yield and quality of delayed coking products because the residual liquid and coke trapped in the coker drum reside there for a duration that approaches infinity, compared to much smaller average residence time for vapor-phase compounds. tabs., figs.

  20. Numerical investigation towards a HiTAC condition in a 9MW heavy fuel-oil boiler

    NARCIS (Netherlands)

    Zhu, Shanglong; Venneker, Bart; Roekaerts, Dirk; Pozarlik, Artur; van der Meer, Theo

    2013-01-01

    In this study, several conditions in a 9 MW heavy fuel-oil boiler were numerically studied in order to get a better understanding of the application of HiTAC in such a boiler. Simulations were done with an Euler- Lagrange approach. The Eddy Dissipation model was used for combustion. Simulation

  1. Check Amount of heavy metals in muscle and fish oil Rutilus frisii kutum, Clupeonella cultriventris and Liza saliens

    Directory of Open Access Journals (Sweden)

    S. Salehi Borban

    2017-02-01

    Full Text Available Heavy metal pollution in marine environments and the potential for bioaccumulation of contaminants have been considered as a serious threat for a long time. These contaminants accumulate in fish body and then transferred through the food chain to humans. The aim of this study was to determine the heavy metals cadmium, lead, arsenic, mercury and copper and iron metals in muscle and fish oil (Rutilus frisii kutum ،Clupeonella cultriventris ،Liza saliens. Three samples of Rutilus frisii kutum ،Clupeonella cultriventris and Liza saliens were caught in Mahmoud Abad area. One part of the muscle was dried by freeze drying method and another part was used to extract the oil. Then, using the atomic absorption spectrometric and Mercury Analyzer heavy metals concentrations were determined in muscle and fish oil. The results of muscle showed the highest accumulation of mercury (0.347±0.018, cadmium (0.08±0.001, copper (1.2156±0.059 and iron (2.643±0.231 in Rutilus frisii kutum and the highest level of lead (0.3593±0.015 and arsenic (0.0892±0.001 in Liza saliens. Moreover, in the fish oils samples, lead and mercury had the highest concentrations. The heavy metals in the samples were lower than or close to international standards. Therefore, their use does not pose a health problem for the consumers.

  2. Finger Thickening during Extra-Heavy Oil Waterflooding: Simulation and Interpretation Using Pore-Scale Modelling.

    Directory of Open Access Journals (Sweden)

    Mohamed Regaieg

    Full Text Available Although thermal methods have been popular and successfully applied in heavy oil recovery, they are often found to be uneconomic or impractical. Therefore, alternative production protocols are being actively pursued and interesting options include water injection and polymer flooding. Indeed, such techniques have been successfully tested in recent laboratory investigations, where X-ray scans performed on homogeneous rock slabs during water flooding experiments have shown evidence of an interesting new phenomenon-post-breakthrough, highly dendritic water fingers have been observed to thicken and coalesce, forming braided water channels that improve sweep efficiency. However, these experimental studies involve displacement mechanisms that are still poorly understood, and so the optimization of this process for eventual field application is still somewhat problematic. Ideally, a combination of two-phase flow experiments and simulations should be put in place to help understand this process more fully. To this end, a fully dynamic network model is described and used to investigate finger thickening during water flooding of extra-heavy oils. The displacement physics has been implemented at the pore scale and this is followed by a successful benchmarking exercise of the numerical simulations against the groundbreaking micromodel experiments reported by Lenormand and co-workers in the 1980s. A range of slab-scale simulations has also been carried out and compared with the corresponding experimental observations. We show that the model is able to replicate finger architectures similar to those observed in the experiments and go on to reproduce and interpret, for the first time to our knowledge, finger thickening following water breakthrough. We note that this phenomenon has been observed here in homogeneous (i.e. un-fractured media: the presence of fractures could be expected to exacerbate such fingering still further. Finally, we examine the impact of

  3. Export Failure and its Consequences: Theory and Evidence

    OpenAIRE

    Mora, Jesse

    2015-01-01

    The purpose of this dissertation is to argue that exporting is a risky endeavor and that there are consequences to export failure. Exporters pay high fixed costs to enter foreign markets, yet the majority will not export beyond one year. What happens to these exporters after they fail abroad? For these firms, exporting likely resulted in heavy profit losses. Despite this, trade literature often views exporting as a harmless exercise based on a simple cost-benefit analysis of foreign profits. ...

  4. Pore network modelling of heavy oil depressurization : a parametric study of factors affecting critical gas saturation and three-phase relative permeabilities

    Energy Technology Data Exchange (ETDEWEB)

    Bondino, I.; McDougall, S.D. [Heriot-Watt Univ., Edinburgh, Scotland (United Kingdom); Hamon, G. [TotalFina Elf Exploration and Production (France)

    2002-07-01

    A review of how the bubble nucleation process affects the efficiency of heavy oil recovery was presented along with a discussion regarding a pore-scale simulator technique to depressurize heavy oil systems. A light oil depressurization simulation is also presented in which a straightforward instantaneous nucleation (IN) model and a more intricate progressive nucleation (PN) model have been used. Simulation results are compared to those derived from the heavy oil systems. The nucleation of bubbles, their growth by solute diffusion and expansion, plus the final stages of coalescence migration and production are the main steps in the depressurization process which were accounted for in a 3-phase simulator. The model can also determine the impact of bubble density and gas-oil diffusion coefficient on critical gas saturation and 3-phase relative permeability. The difference in results for light and heavy oils was also highlighted. In the first scenario, the evolution of gas was characterized by embryonic bubbles that are quickly and randomly nucleated once bubble-point pressure is reached. A stochastic algorithm was developed for PN from experimental observations. IN and PN observations were not necessarily contradictory. It was determined that the high interfacial tension of heavy oils leads to a more compact, capillary-dominated pattern of gas evolution compared to light oils, resulting in improved recoveries for heavy oil systems. 23 refs., 6 tabs., 23 figs.

  5. Application of biosurfactants in environmental biotechnology; remediation of oil and heavy metal

    Directory of Open Access Journals (Sweden)

    Ahmad Fahim Mahmud

    2016-07-01

    Full Text Available Many toxic substances have been introduced into environment through human activities. These compounds are danger to human health when they are ultimately or immediately in contact with soil particles. A conventional method to reduce, degrade and remove these substances is associated with some risk. In recent years, microorganisms have proved a unique role in the degradation and detoxification of polluted soil and water environments and, this process has been termed bio reclamation. The diversity of bioemulsifiers/biosurfactants makes them an attractive group and important key roles in various fields of industrial as well as biotechnological applications such as enhanced oil recovery, biodegradation of pollutants, and pharmaceutics. Environmental application of microbial surfactant has been shown as a promising due to solubilization of low solubility compounds, low toxicity observed and efficacy in improving biodegradation. However, it is important to note that full scale tests and more information is require to predict the behavior and model of surfactant function on the remediation process with biosurfactants. The purpose of this review is to describe the state of art in the potential applications of biosurfactants in remediation of environmental pollution caused by oil and heavy metal.

  6. Stereoselective biodegradation of tricyclic terpanes in heavy oils from the Bolivar Coastal Fields, Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    Alberdi, M. [Stanford University (United States). Dept. of Geological and Environmental Sciences; PDVSA-Intevep, Caracas (Venezuela); Moldowan, J.M.; Dahl, J.E. [Stanford University (United States). Dept. of Geological and Environmental Sciences; Peters, K.E. [Mobil Technology Co., Dallas, TX (United States)

    2001-07-01

    Gas chromatography-mass spectrometry (GC-MS) and GC-MS-MS analyses of heavy oils from Bolivar Coastal Fields (Lagunillas Field) show a complete set of demethylated tricyclic terpanes. As is the case for the 25-norhopanes, the demethylated tricyclics are probably formed in reservoirs by microbially-mediated removal of the methyl group from the C-10 position, generating putative 17-nor-tricyclic terpanes. Diastereomeric pairs of tricyclic terpanes are resolved above C{sub 24} due to resolution of 22S and 22R epimers, but the elution order of the 22S and 22R epimers is unknown. Early-eluting diastereomers (EE) predominate over late-eluting diastereomers (LE) (C{sub 25}-C{sub 29}) in the heavily degraded oils, indicating a stereoselective preference for the LE stereoisomers during biodegradation. Conversely, the LE diastereomers predominate over the EE diastereomers in the 17-nor tricyclic series (C{sub 24}-C{sub 28}), indicating that tricyclic terpanes and 17-nor-tricyclic terpanes are directly linked as precursors and products, respectively. A good correlation exists between the destruction of steranes and the demethylation of hopanes and tricyclic terpanes. This suggests that terpane demethylation occurs during sterane destruction and hopane demethylation, although the rate is slower, indicating that tricyclic terpanes are more resistant to biodegradation. (Author)

  7. Determination of asphaltenes in heavy oils using an on-column method

    Energy Technology Data Exchange (ETDEWEB)

    Rogel, E.; Ovalles, C.; Moir, M. [Chevron Energy Technology Co., Richmond, CA (United States); Schabron, J.F. [Western Research Inst., Laramie, WY (United States)

    2009-07-01

    An improved analytical method for determining the asphaltene content in crude oil and petroleum samples was presented. The method used an on-column precipitation technique coupled with an evaporative light scattering detector (ELSD). The column has an inert packing material where the asphaltene was precipitated and re-dissolved using a solvent. Heavy crude oils with asphaltene contents ranging from 5 to 25 per cent w/w were tested. A blend of 90:10 dichloromethane and methanol was used to decrease the influence of hydrocarbon adsorption mechanisms from the polymeric liquid chromatographic phases. A series of laboratory experiments were conducted to compare results obtained using the method with results obtained using traditional gravimetric methods. Regression analysis was used to determine the calibration constants. The study showed that the method can be used as replacement for conventional gravimetric methods when faster results are needed or when sample sizes are small. It was concluded that the method was able to accurately quantify asphaltene contents as low as 120 ppm. 8 refs., 1 tab., 3 figs.

  8. Seismic monitoring of in situ combustion process in a heavy oil field

    International Nuclear Information System (INIS)

    Zadeh, Hossein Mehdi; Srivastava, Ravi P; Vedanti, Nimisha; Landrø, Martin

    2010-01-01

    Three time-lapse 3D seismic surveys are analysed to monitor the effect of in situ combustion, a thermal-enhanced oil recovery process in the Balol heavy oil reservoir in India. The baseline data were acquired prior to the start of the in situ combustion process in four injection wells, while the two monitor surveys were acquired 1 and 2 years after injection start, respectively. We present the results of baseline and second monitor surveys. Fluid substitution studies based on acoustic well logs predict a seismic amplitude decrease at the top reservoir and an increase at the base reservoir. Both the amplitude dimming at the top reservoir and the brightening at the base reservoir are observed in the field data. The extent of the most pronounced 4D anomaly is estimated from the seismic amplitude and time shift analysis. The interesting result of seismic analysis is that the anomalies are laterally shifted towards the northwest, rather than the expected east, from the injector location suggesting a northwest movement of the in situ combustion front. No clear evidence of air leakage into other sand layers, neither above nor below the reservoir sand, is observed. This does not necessarily mean that all the injected air is following the reservoir sand, especially if the thief sand layers are thin. These layers might be difficult to observe on seismic data

  9. Export incentives, exchange rate policy and export growth in Turkey

    NARCIS (Netherlands)

    van Wijnbergen, S.J.G.; Arslan, I.

    1993-01-01

    The driving forces behind the Turkish export miracle, and in fact its very existence, have remained a matter of debate We show there was a boom. As to contributing factors, import growth in the Middle East in excess of import growth elsewhere made a negative contribution. On exports to non-oil

  10. Enhanced heavy oil recovery for carbonate reservoirs integrating cross-well seismic–a synthetic Wafra case study

    KAUST Repository

    Katterbauer, Klemens

    2015-07-14

    Heavy oil recovery has been a major focus in the oil and gas industry to counter the rapid depletion of conventional reservoirs. Various techniques for enhancing the recovery of heavy oil were developed and pilot-tested, with steam drive techniques proven in most circumstances to be successful and economically viable. The Wafra field in Saudi Arabia is at the forefront of utilizing steam recovery for carbonate heavy oil reservoirs in the Middle East. With growing injection volumes, tracking the steam evolution within the reservoir and characterizing the formation, especially in terms of its porosity and permeability heterogeneity, are key objectives for sound economic decisions and enhanced production forecasts. We have developed an integrated reservoir history matching framework using ensemble based techniques incorporating seismic data for enhancing reservoir characterization and improving history matches. Examining the performance on a synthetic field study of the Wafra field, we could demonstrate the improved characterization of the reservoir formation, determining more accurately the position of the steam chambers and obtaining more reliable forecasts of the reservoir’s recovery potential. History matching results are fairly robust even for noise levels up to 30%. The results demonstrate the potential of the integration of full-waveform seismic data for steam drive reservoir characterization and increased recovery efficiency.

  11. Budget deficit remedies and their impact on the non-oil sectors of an oil-exporting country: the case of Kuwait

    International Nuclear Information System (INIS)

    Eltony, M.N.

    1998-01-01

    A model for the non-oil production side of the Kuwaiti economy was developed and estimated. The model, then, was simulated according to various scenarios designed to eliminate the budget deficit by the year 2000, in order to examine the effect on the non-oil sector of the economy. The results indicate that, in terms of its impact on non-oil GDP, the extreme case scenario is harsh, bringing down the level of non-oil GDP by more than 20% by the year 2000 from its level in 1993. The impact on the budget deficit may be very positive, but non-oil production and consumption will decline very rapidly, creating widespread hardship across all economic sectors. The results suggest a better option lies in adopting either of two intermediate case scenarios. While each of these will also cause a decline in non-oil GDP, it will not be to the extent caused by the extreme case scenario

  12. Simultaneous removal of oil and grease, and heavy metals from artificial bilge water using electro-coagulation/flotation.

    Science.gov (United States)

    Rincón, Guillermo J; La Motta, Enrique J

    2014-11-01

    US and international regulations pertaining to the control of bilge water discharges from ships have concentrated their attention to the levels of oil and grease rather than to the heavy metal concentrations. The consensus is that any discharge of bilge water (and oily water emulsion within 12 nautical miles from the nearest land cannot exceed 15 parts per million (ppm). Since there is no specific regulation for metal pollutants under the bilge water section, reference standards regulating heavy metal concentrations are taken from the ambient water quality criteria to protect aquatic life. The research herein presented discusses electro-coagulation (EC) as a method to treat bilge water, with a focus on oily emulsions and heavy metals (copper, nickel and zinc) removal efficiency. Experiments were run using a continuous flow reactor, manufactured by Ecolotron, Inc., and a synthetic emulsion as artificial bilge water. The synthetic emulsion contained 5000 mg/L of oil and grease, 5 mg/L of copper, 1.5 mg/L of nickel, and 2.5 mg/l of zinc. The experimental results demonstrate that EC is very efficient in removing oil and grease. For oil and grease removal, the best treatment and cost efficiency was obtained when using a combination of carbon steel and aluminum electrodes, at a detention time less than one minute, a flow rate of 1 L/min and 0.6 A/cm(2) of current density. The final effluent oil and grease concentration, before filtration, was always less than 10 mg/L. For heavy metal removal, the combination of aluminum and carbon steel electrodes, flow rate of 1 L/min, effluent recycling, and 7.5 amps produced 99% zinc removal efficiency. Copper and nickel are harder to remove, and a removal efficiency of 70% was achieved. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Feasibility to apply the steam assisted gravity drainage (SAGD) technique in the country's heavy crude-oil fields

    International Nuclear Information System (INIS)

    Rodriguez, Edwin; Orjuela, Jaime

    2004-01-01

    The steam assisted gravity drainage (SAGD) processes are one of the most efficient and profitable technologies for the production of heavy crude oils and oil sands. These processes involve the drilling of a couple of parallel horizontal wells, separated by a vertical distance and located near the oil field base. The upper well is used to continuously inject steam into the zone of interest, while the lower well collects all resulting fluids (oil, condensate and formation water) and takes them to the surface (Butler, 1994). This technology has been successfully implemented in countries such as Canada, Venezuela and United States, reaching recovery factors in excess of 50%. This article provides an overview of the technique's operation mechanism and the process most relevant characteristics, as well as the various categories this technology is divided into, including all its advantages and limitations. Furthermore, the article sets the oil field's minimal conditions under which the SAGD process is efficient, which conditions, as integrated to a series of mathematical models, allow to make forecasts on production, thermal efficiency (ODR) and oil to be recovered, as long as it is feasible (from a technical point of view) to apply this technique to a defined oil field. The information and concepts compiled during this research prompted the development of software, which may be used as an information, analysis and interpretation tool to predict and quantify this technology's performance. Based on the article, preliminary studies were started for the country's heavy crude-oil fields, identifying which provide the minimum conditions for the successful development of a pilot project

  14. Development of ocular hypertension secondary to tamponade with light versus heavy silicone oil: A systematic review

    Directory of Open Access Journals (Sweden)

    Vito Romano

    2015-01-01

    Full Text Available Aim: The intraocular silicone oil (SO tamponades used in the treatment of retinal detachment (RD have been associated with a difference ocular hypertension (OH rate. To clarify, if this complication was associated to use of standard SO (SSO versus heavy SO (HSO, we performed a systematic review and meta-analysis of comparative study between two kind of SO (standard or light vs. heavy for the treatment of RD and macular hole, without restriction to study design. Materials and Methods: The methodological quality of two randomized clinical trials (RCTs were evaluated using the criteria given in the Cochrane Handbook for Systematic Reviews of Intervention, while three non-RCTs were assessed with the Newcastle-Ottawa Scale and Strengthening the Reporting of Observational Studies in Epidemiology checklists. We calculated Mantel-Haenszel risk ratio (RR with 95% confidence intervals (95% CIs. The primary outcome was the rate of patients with OH treated with SSO compared to HSO. Results: There were a higher number of rates of OH in HSO compared to SSO. This difference was statistically significant with the fixed effect model (Mantel-Haenszel RR; 1.55; 95% CI, 1.06-2.28; P = 0.02 while there was not significative difference with the random effect model (Mantel-Haenszel RR; 1.51; 95% CI, 0.98-2.33; P = 0.06. Conclusion: We noted a trend that points out a higher OH rate in HSO group compared to SSO, but this finding, due to the small size and variable design of studies, needs to be confirmed in well-designed and large size RCTs.

  15. Design of three-phase gravity separators for heavy oils; Projeto de separadores trifasicos para oleos pesados

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Rosivania P.; Bannwart, Antonio C. [Universidade Estadual de Campinas, SP (Brazil); Carvalho, Carlos H.M. de [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    The primary processing of crude oil consists in the separation of oil, gas, water (and solids suspensions, if present), the conditioning of the hydrocarbons for transportation to the refinery, and the water treatment for re-use. With the discovery of significant fields of heavy oil in Brazil, whose densities are close to the density of water and viscosities are about hundreds to thousand times higher than the viscosity of water, the production and primary processing of this fluid with usual technology is not attractive and often unfeasible. It is well known that the demand from the majority of the refineries is that the quantity of water dispersion in the oil (BSW) is below 1%, so this work investigates the behavior of the water dispersion in heavy oil, causing an increase in viscosity and density. Therefore, this work intends to define strategies to efficiently separate these liquids, emphasizing the physical aspects of separation. Mathematica software was used for the equation modeling, which governs the horizontal separation vases dimensioning, allowing the observation of the influence of many variables on the separator dimensions. (author)

  16. Detection of heavy oil on the seabed by application of a 400 kHz multibeam echo sounder

    International Nuclear Information System (INIS)

    Wendelboe, G.; Fonseca, L.; Eriksen, M.; Mutschler, M.; Hvidbak, F.

    2009-01-01

    Marine spills of heavy oil that sink to the sea floor can have significant impacts on marine ecosystems. This paper described a program implemented by the United States Coast Guard to improve operational techniques for the detection, monitoring, and recovery of sunken oil. The program has developed an algorithm based on data from a multibeam echo sounder. The algorithm used calibrated backscatter strengths (BS) to produce a mosaic of the seabed. Values below a pre-specified threshold were sorted into groups using morphological filtering techniques. The angular response curves from each group were then analyzed and compared to a reference BS curve for heavy oil. Response curves below the upper bound curve were defined as oil. The algorithm had a 90 per cent accuracy rate at a recent demonstration using oil 6, Tesoro, Sundex, and asphalt samples. It was concluded that processing times per square mile are approximately 12 hours. Further studies will be conducted to reduce computation times by replacing raw beam-formed data with data that originated solely from the region near the seabed. 15 refs., 15 tabs., 18 figs

  17. Study of crude and plasma-treated heavy oil by low- and high-field 1H NMR

    Energy Technology Data Exchange (ETDEWEB)

    Honorato, Hercilio D. A.; Silva, Renzo C.; Junior, Valdemar Lacerda; Castro, Eustaquio V. R. de; Freitas, Jair C. C. [Research and Methodology Development Laboratory for Crude Oil Analysis - LabPetro, Department of Chemistry, Federal University of Espirito Santo (Brazil)], email: jairccfreitas@yahoo.com.br; Piumbini, Cleiton K.; Cunha, Alfredo G.; Emmerich, Francisco G. [Department of Physics, Federal University of Espirito Santo (Brazil); Souza, Andre A. de; Bonagamba, Tito J. [Institute of Physics of Sao Carlos, University of Sao Paulo (Brazil)

    2010-07-01

    This document is intended to describe the combination of H low-field NMR and thermogravimetry (TG), rheological measurement and H high-field NMR to assess the physical and chemical changes that can occur in a heavy crude oil from treatment in a plasma reactor. This research was done using a heavy crude oil, API gravity of 10.1, which was treated in a double dielectric barrier (DDB) plasma reactor using different plasma gases: natural gas (NG), C02 or H2. The low-field HNMR experiments were conducted in a Maran Ultra spectrometer, from Oxford Instruments, at 27.5? C. After rheological analysis, a reduction in the viscosity of the plasma-treated oils in comparison to that of the crude oil was observed. Finally, it was confirmed that the use of H low-field NMR relaxometry and H high-field NMR spectroscopy allowed a separate analysis of the effects of the plasma treatment on the water and oil fractions to be made.

  18. Controllable synthesis in a continuous mode of unsupported molybdenum catalysts with micro/nano size for heavy oil upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.; Hill, J.M.; Pereira Almao, P.R. [Calgary Univ., AB (Canada)

    2004-07-01

    Heavy oils contain significant amounts of impurities compared to conventional oils, thereby posing a challenge for hydroprocessing operations at refineries. Hydrodesulfurization is one of the important reactions involved in hydroprocessing. Transition metal sulfides have excellent properties in terms of sulphur removal. Molybdenum based catalysts have been used extensively in the petroleum industry for hydrotreating heavy oil fractions. Supported molybdenum based catalysts suffer strong deactivation in the traditional hydrotreating process due to the deposition of carbonaceous components on the surface of the catalyst when they are used in conventional fixed bed reactors. Unsupported catalysts have higher catalytic activity with better metal dispersion. Laboratory experiments were conducted in which micro/nano size unsupported molybdenum catalysts were synthesized from a water/oil emulsion. The catalysts were prepared in a continuous mode for online application to hydroprocessing or in situ upgrading. Dispersed molybdenum catalysts are more suitable for processing heavier feeds because they are less prone to deactivation. Also, their submicron size ensure high activities due to a large specific surface area. They are also sufficiently small to be readily dispersed in the residual oil. 4 refs., 1 tab., 2 figs.

  19. INVESTIGATION OF MULTISCALE AND MULTIPHASE FLOW, TRANSPORT AND REACTION IN HEAVY OIL RECOVERY PROCESSES

    Energy Technology Data Exchange (ETDEWEB)

    Yannis C. Yortsos

    2003-02-01

    This is final report for contract DE-AC26-99BC15211. The report describes progress made in the various thrust areas of the project, which include internal drives for oil recovery, vapor-liquid flows, combustion and reaction processes and the flow of fluids with yield stress. The report consists mainly of a compilation of various topical reports, technical papers and research reports published produced during the three-year project, which ended on May 6, 2002 and was no-cost extended to January 5, 2003. Advances in multiple processes and at various scales are described. In the area of internal drives, significant research accomplishments were made in the modeling of gas-phase growth driven by mass transfer, as in solution-gas drive, and by heat transfer, as in internal steam drives. In the area of vapor-liquid flows, we studied various aspects of concurrent and countercurrent flows, including stability analyses of vapor-liquid counterflow, and the development of novel methods for the pore-network modeling of the mobilization of trapped phases and liquid-vapor phase changes. In the area of combustion, we developed new methods for the modeling of these processes at the continuum and pore-network scales. These models allow us to understand a number of important aspects of in-situ combustion, including steady-state front propagation, multiple steady-states, effects of heterogeneity and modes of combustion (forward or reverse). Additional aspects of reactive transport in porous media were also studied. Finally, significant advances were made in the flow and displacement of non-Newtonian fluids with Bingham plastic rheology, which is characteristic of various heavy oil processes. Various accomplishments in generic displacements in porous media and corresponding effects of reservoir heterogeneity are also cited.

  20. Heavy fuel oil pyrolysis and combustion: kinetics and evolved gases investigated by TGA-FTIR

    KAUST Repository

    Abdul Jameel, Abdul Gani

    2017-08-24

    Heavy fuel oil (HFO) obtained from crude oil distillation is a widely used fuel in marine engines and power generation technologies. In the present study, the pyrolysis and combustion of a Saudi Arabian HFO in nitrogen and in air, respectively, were investigated using non-isothermal thermo-gravimetric analysis (TGA) coupled with a Fourier-transform infrared (FTIR) spectrometer. TG and DTG (differential thermo-gravimetry) were used for the kinetic analysis and to study the mass loss characteristics due to the thermal degradation of HFO at temperatures up to 1000°C and at various heating rates of 5, 10 and 20°C/min, in air and N2 atmospheres. FTIR analysis was then performed to study the composition of the evolved gases. The TG/DTG curves during HFO combustion show the presence of three distinct stages: the low temperature oxidation (LTO); fuel decomposition (FD); and high temperature oxidation (HTO) stages. The TG/DTG curves obtained during HFO pyrolysis show the presence of two devolatilization stages similar to that seen in the LTO stage of HFO combustion. Apart from this, the TG/DTG curves obtained during HFO combustion and pyrolysis differ significantly. Kinetic analysis was also performed using the distributed activation energy model, and the kinetic parameter (E) was determined for the different stages of HFO combustion and pyrolysis processes, yielding a good agreement with the measured TG profiles. FTIR analysis showed the signal of CO2 as approximately 50 times more compared to the other pollutant gases under combustion conditions. Under pyrolytic conditions, the signal intensity of alkane functional groups was the highest followed by alkenes. The TGA-FTIR results provide new insights into the overall HFO combustion processes, which can be used to improve combustor designs and control emissions.

  1. Straw export in continuous winter wheat and the ability of oil radish catch crops and early sowing of wheat to offset soil C and N losses: A simulation study

    DEFF Research Database (Denmark)

    Peltre, Clément; Nielsen, M; Christensen, Bent Tolstrup

    2016-01-01

    The export of winter wheat straw for bioenergy may reduce soil C stocks and affect N losses. Establishing fast-growing catch crops between successive wheat crops could potentially offset some of the C and N losses. Another option is to sow wheat earlier, increasing biomass production during...... the autumn. The effects of straw export, oil radish catch crop and early sowing of wheat on soil C storage, N leaching losses and N2O emissions were simulated by applying the Daisy model to winter wheat grown continuously for a period of 100 years on a sandy loam soil in a Danish climate. The simulations....... Inclusion of the oil radish catch crop could offset this loss by 2–3 percentage points. Earlier sowing of wheat increased straw production by 18% and reduced loss of soil C by 3–5 percentage points compared to normal sowing time with full straw export. Catch crops and early sowing also reduced N...

  2. Speciation and environmental risk assessment of heavy metal in bio-oil from liquefaction/pyrolysis of sewage sludge.

    Science.gov (United States)

    Yuan, Xingzhong; Leng, Lijian; Huang, Huajun; Chen, Xiaohong; Wang, Hou; Xiao, Zhihua; Zhai, Yunbo; Chen, Hongmei; Zeng, Guangming

    2015-02-01

    Liquefaction bio-oil (LBO) produced with ethanol (or acetone) as the solvent and pyrolysis bio-oil (PBO) produced at 550°C (or 850°C) from sewage sludge (SS) were produced, and were characterized and evaluated in terms of their heavy metal (HM) composition. The total concentration, speciation and leaching characteristic of HMs (Cu, Cr, Pb, Zn, Cd, and Ni) in both LBO and PBO were investigated. The total concentration and exchangeable fraction of Zn and Ni in bio-oils were at surprisingly high levels. Quantitative risk assessment of HM in bio-oils was performed by the method of risk assessment code (RAC), potential ecological risk index (PERI) and geo-accumulation index (GAI). Ni in bio-oil produced by pyrolysis at 850°C (PBO850) and Zn in bio-oil by liquefaction at 360°C with ethanol as solvent (LBO-360E) were evaluated to possess very high risk to the environment according to RAC. Additionally, Cd in PBO850 and LBO-360E were evaluated by PERI to have very high risk and high risk, respectively, while Cd in all bio-oils was assessed moderately contaminated according to GAI. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. Earthworms (Eisenia fetida) demonstrate potential for use in soil bioremediation by increasing the degradation rates of heavy crude oil hydrocarbons.

    Science.gov (United States)

    Martinkosky, Luke; Barkley, Jaimie; Sabadell, Gabriel; Gough, Heidi; Davidson, Seana

    2017-02-15

    Crude oil contamination widely impacts soil as a result of release during oil and gas exploration and production activities. The success of bioremediation methods to meet remediation goals often depends on the composition of the crude oil, the soil, and microbial community. Earthworms may enhance bioremediation by mixing and aerating the soil, and exposing soil microorganisms to conditions in the earthworm gut that lead to increased activity. In this study, the common composting earthworm Eisenia fetida was tested for utility to improve remediation of oil-impacted soil. E. fetida survival in soil contaminated with two distinct crude oils was tested in an artificial (lab-mixed) sandy loam soil, and survival compared to that in the clean soil. Crude oil with a high fraction of light-weight hydrocarbons was more toxic to earthworms than the crude oil with a high proportion of heavy polyaromatic and aliphatic hydrocarbons. The heavier crude oil was added to soil to create a 30,000mg/kg crude oil impacted soil, and degradation in the presence of added earthworms and feed, feed alone, or no additions was monitored over time and compared. Earthworm feed was spread on top to test effectiveness of no mixing. TPH degradation rate for the earthworm treatments was ~90mg/day slowing by 200days to ~20mg/day, producing two phases of degradation. With feed alone, the rate was ~40mg/day, with signs of slowing after 500days. Both treatments reached the same end point concentrations, and exhibited faster degradation of aliphatic hydrocarbons C21, decreased. During these experiments, soils were moderately toxic during the first three months, then earthworms survived well, were active and reproduced with petroleum hydrocarbons present. This study demonstrated that earthworms accelerate bioremediation of crude oil in soils, including the degradation of the heaviest polyaromatic fractions. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. A tiered analytical protocol for the characterization of heavy oil residues at petroleum-contaminated hazardous waste sites

    International Nuclear Information System (INIS)

    Pollard, S.J.T.; Kenefick, S.L.; Hrudey, S.E.; Fuhr, B.J.; Holloway, L.R.; Rawluk, M.

    1994-01-01

    The analysis of hydrocarbon-contaminated soils from abandoned refinery sites in Alberta, Canada is used to illustrate a tiered analytical approach to the characterization of complex hydrocarbon wastes. Soil extracts isolated from heavy oil- and creosote-contaminated sites were characterized by thin layer chromatography with flame ionization detection (TLC-FID), ultraviolet fluorescence, simulated distillation (GC-SIMDIS) and chemical ionization GC-MS analysis. The combined screening and detailed analytical methods provided information essential to remedial technology selection including the extent of contamination, the class composition of soil extracts, the distillation profile of component classes and the distribution of individual class components within various waste fractions. Residual contamination was characteristic of heavy, degraded oils, consistent with documented site operations and length of hydrocarbon exposure at the soil surface

  5. Removal of Heavy Metal Ions with Acid Activated Carbons Derived from Oil Palm and Coconut Shells

    Science.gov (United States)

    Rahman, Mokhlesur M.; Adil, Mohd; Yusof, Alias M.; Kamaruzzaman, Yunus B.; Ansary, Rezaul H.

    2014-01-01

    In this work, batch adsorption experiments were carried out to investigate the suitability of prepared acid activated carbons in removing heavy metal ions such as nickel(II), lead(II) and chromium(VI). Acid activated carbons were obtained from oil palm and coconut shells using phosphoric acid under similar activation process while the differences lie either in impregnation condition or in both pretreatment and impregnation conditions. Prepared activated carbons were modified by dispersing hydrated iron oxide. The adsorption equilibrium data for nickel(II) and lead(II) were obtained from adsorption by the prepared and commercial activated carbons. Langmuir and Freundlich models fit the data well. Prepared activated carbons showed higher adsorption capacity for nickel(II) and lead(II). The removal of chromium(VI) was studied by the prepared acid activated, modified and commercial activated carbons at different pH. The isotherms studies reveal that the prepared activated carbon performs better in low concentration region while the commercial ones in the high concentration region. Thus, a complete adsorption is expected in low concentration by the prepared activated carbon. The kinetics data for Ni(II), Pb(II) and Cr(VI) by the best selected activated carbon fitted very well to the pseudo-second-order kinetic model. PMID:28788640

  6. Removal of Heavy Metal Ions with Acid Activated Carbons Derived from Oil Palm and Coconut Shells

    Directory of Open Access Journals (Sweden)

    Mokhlesur M. Rahman

    2014-05-01

    Full Text Available In this work, batch adsorption experiments were carried out to investigate the suitability of prepared acid activated carbons in removing heavy metal ions such as nickel(II, lead(II and chromium(VI. Acid activated carbons were obtained from oil palm and coconut shells using phosphoric acid under similar activation process while the differences lie either in impregnation condition or in both pretreatment and impregnation conditions. Prepared activated carbons were modified by dispersing hydrated iron oxide. The adsorption equilibrium data for nickel(II and lead(II were obtained from adsorption by the prepared and commercial activated carbons. Langmuir and Freundlich models fit the data well. Prepared activated carbons showed higher adsorption capacity for nickel(II and lead(II. The removal of chromium(VI was studied by the prepared acid activated, modified and commercial activated carbons at different pH. The isotherms studies reveal that the prepared activated carbon performs better in low concentration region while the commercial ones in the high concentration region. Thus, a complete adsorption is expected in low concentration by the prepared activated carbon. The kinetics data for Ni(II, Pb(II and Cr(VI by the best selected activated carbon fitted very well to the pseudo-second-order kinetic model.

  7. Electrochemical pretreatment of heavy oil refinery wastewater using a three-dimensional electrode reactor

    Energy Technology Data Exchange (ETDEWEB)

    Wei Lingyong [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); Guo Shaohui, E-mail: cupgsh@163.co [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); Yan Guangxu; Chen Chunmao [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); Jiang Xiaoyan [Liaohe Petrochemical Branch Company, PetroChina, Panjin 124022 (China)

    2010-12-01

    The pretreatment of heavy oil refinery wastewater (HORW) was experimentally investigated using a three-dimensional electrode reactor (TDER) with granular activated carbon (GAC) and porous ceramsite particle (PCP) as the combination particle electrode and DSA type anodes as the anode. The results showed that higher chemical oxygen demand (COD) removal was obtained in TDER comparing with the two-dimensional electrode reactor (without particle electrodes packed), and combination particle electrode was favorable to improve the COD removal efficiency and reduce the energy consumption. The treated HORW under the optimal experimental condition (GAC percentage = 75%, current density = 30 mA/cm{sup 2}, pH not adjusted and treatment time = 100 min) presented that the removal efficiencies of COD, total organic carbon and toxicity units were 45.5%, 43.3% and 67.2%, respectively, and the ratio of 5-day biochemical oxygen demand to COD was increased from 0.10 to 0.29, which is beneficial for further biological treatment. Furthermore, the application of electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry to characterize polar compounds in HORW and their oxidation products was well demonstrated to reveal the composition variation.

  8. Electrochemical pretreatment of heavy oil refinery wastewater using a three-dimensional electrode reactor

    International Nuclear Information System (INIS)

    Wei Lingyong; Guo Shaohui; Yan Guangxu; Chen Chunmao; Jiang Xiaoyan

    2010-01-01

    The pretreatment of heavy oil refinery wastewater (HORW) was experimentally investigated using a three-dimensional electrode reactor (TDER) with granular activated carbon (GAC) and porous ceramsite particle (PCP) as the combination particle electrode and DSA type anodes as the anode. The results showed that higher chemical oxygen demand (COD) removal was obtained in TDER comparing with the two-dimensional electrode reactor (without particle electrodes packed), and combination particle electrode was favorable to improve the COD removal efficiency and reduce the energy consumption. The treated HORW under the optimal experimental condition (GAC percentage = 75%, current density = 30 mA/cm 2 , pH not adjusted and treatment time = 100 min) presented that the removal efficiencies of COD, total organic carbon and toxicity units were 45.5%, 43.3% and 67.2%, respectively, and the ratio of 5-day biochemical oxygen demand to COD was increased from 0.10 to 0.29, which is beneficial for further biological treatment. Furthermore, the application of electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry to characterize polar compounds in HORW and their oxidation products was well demonstrated to reveal the composition variation.

  9. Nervous system disruption and concomitant behavioral abnormality in early hatched pufferfish larvae exposed to heavy oil.

    Science.gov (United States)

    Kawaguchi, Masahumi; Sugahara, Yuki; Watanabe, Tomoe; Irie, Kouta; Ishida, Minoru; Kurokawa, Daisuke; Kitamura, Shin-Ichi; Takata, Hiromi; Handoh, Itsuki C; Nakayama, Kei; Murakami, Yasunori

    2011-08-01

    Spills of heavy oil (HO) over the oceans have been proven to have an adverse effect on marine life. It has been hypothesized that exposure of early larvae of sinking eggs to HO leads largely to normal morphology, whereas abnormal organization of the developing neural scaffold is likely to be found. HO-induced disruption of the nervous system, which controls animal behavior, may in turn cause abnormalities in the swimming behavior of hatched larvae. To clarify the toxicological effects of HO, we performed exposure experiments and morphological and behavioral analyses in pufferfish (Takifugu rubripes) larvae. Fertilized eggs of pufferfish were exposed to 50 mg/L of HO for 8 days and transferred to fresh seawater before hatching. The hatched larvae were observed for their swimming behavior, morphological appearance, and construction of muscles and nervous system. In HO-exposed larvae, we did not detect any anomaly of body morphology. However, they showed an abnormal swimming pattern and disorganized midbrain, a higher center controlling movement. Our results suggest that HO-exposed fishes suffer developmental disorder of the brain that triggers an abnormal swimming behavior and that HO may be selectively toxic to the brain and cause physical disability throughout the life span of these fishes.

  10. Selective Production of Aromatic Aldehydes from Heavy Fraction of Bio-oil via Catalytic Oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yan; Chang, Jie; Ouyang, Yong; Zheng, Xianwei [South China Univ. of Technology, Guangzhou (China)

    2014-06-15

    High value-added aromatic aldehydes (e. g. vanillin and syringaldehyde) were produced from heavy fraction of bio-oil (HFBO) via catalytic oxidation. The concept is based on the use of metalloporphyin as catalyst and hydrogen peroxide (H{sub 2}O{sub 2}) as oxidant under alkaline condition. The biomimetic catalyst cobalt(II)-sulfonated tetraphenylporphyrin (Co(TPPS{sub 4})) was prepared and characterized. It exhibited relative high activity in the catalytic oxidation of HFBO. 4.57 wt % vanillin and 1.58 wt % syringaldehyde were obtained from catalytic oxidation of HFBO, compared to 2.6 wt % vanillin and 0.86 wt % syringaldehyde without Co(TPPS{sub 4}). Moreover, a possible mechanism of HFBO oxidation using Co(TPPS{sub 4})/H{sub 2}O{sub 2} was proposed by the research of model compounds. The results showed that this is a promising and environmentally friendly method for production of aromatic aldehydes from HFBO under Co(TPPS{sub 4})/H{sub 2}O{sub 2} system.

  11. Passive seismic data management and processing to monitor heavy oil steaming operations

    Energy Technology Data Exchange (ETDEWEB)

    Bailey, J.R.; Wang, L. [Society of Petroleum Engineers, Richardson, TX (United States)]|[ExxonMobil Upstream Research Co., Houston, TX (United States); Searles, K.H.; Smith, R.J.; Keith, C.M. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Imperial Oil Ltd., Burnaby, BC (Canada)

    2008-10-15

    Cyclic steam injection (CSS) is a cost-effective means to produce heavy oil at the Cold Lake field in Alberta, Canada. The primary obstacle to economic production is the high viscosity of the bitumen. However the bitumen viscosity decreases significantly with temperature. Steam is injected at fracturing conditions, resulting in dilation and recompaction which propagates stress and strain fields in the overburden. An important design consideration involves the mechanical loads on wells resulting from this production process. A seismic production monitoring system was developed in 1995 in the Cold Lake field in order to provide early detection of casing failures and possible fracturing of the overburden. The method was shown to detect a high percentage of casing failures in the production monitoring system. This paper discussed the use and application of methods developed for passive seismic data analysis. The Cold Lake passive seismic system (CLPS) has evolved into an integrated process with a daily workflow. Personnel have identified roles and responsibilities. The paper provided a discussion of the development of a web-based platform running on the operator's internal network called PSWeb. The progression of work in microseismic monitoring of fracture stimulation treatments was also discussed along with the development of FIDO, which used graphical event processing methods to facilitate data analysis and interpretation. Further development of these tools is ongoing to improve casing failure detection and to incorporate more information from seismic data to understand the impact of the CSS process on overburden integrity. 15 refs., 12 figs., 1 appendix.

  12. Horizontal alternating steam drive process for the Orinoco heavy oil belt in eastern Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    Edgar A. Fernandez R.; Bashbush, J.L. [Schlumberger, Sugar Land, TX (United States)

    2008-10-15

    Horizontal alternating steam drive (HASD) processes use single horizontal wells that cyclically switch between injection and production phases. The steam chambers generated by the wells are laterally driven by the pressure differentials created by adjacent producers to form a sweeping front between the wells. This feasibility study assessed the use of HASD processes at a heavy oil reservoir in Venezuela. The study used numerical simulations from a representative reservoir with a 5-horizontal well array to asses the HASD recovery technique under various scenarios. Sensitivity analyses were also conducted to consider the positioning of the horizontal well placement in the reservoir column; different injection sequences; variations in the duration of injection cycles; injection rates; and the lengths of the horizontal reach of the wells. Results of the study suggested that HASD is a suitable alternative for reservoirs with sands in the 20 foot to 50 foot thickness range. HASD achieved average recovery factors of above 20 per cent over a 15 year period, and required fewer wells than steam assisted gravity drainage (SAGD) processes. It was concluded that the wells must be designed to consider the additional thermal stresses resulting the repeated injection and production cycles associated with HASD processes. The 6 refs., 2 tabs., 16 figs.

  13. Assessment of heavy metals pollution in bottom sediments of the Arabian Gulf after the Gulf War oil spill 1991

    International Nuclear Information System (INIS)

    Nasr, S.M.; Ahmed, M.H.; El-Raey, M.; Frihy, O.E.; Abdel Motti, A.

    1999-01-01

    The major objective of this study was to carry out a sequential geochemical extraction scheme for the partitioning of Fe, Mn, Co, Cu, Zn, Ni, Cr and Pb in the bottom sediments of the Arabian Gulf to detect any potential pollution impact on the gulf sediments following the 1991 gulf war oil spill, and to differentiate between anthropogenic inputs and natural background of heavy metals

  14. Effect of mycorrhizal inoculation on the growth and phytoextraction of heavy metals by maize grown in oil contaminated soil

    International Nuclear Information System (INIS)

    Achakzai, A.K.K.; Liasu, M.O.; Popoola, O.J.

    2011-01-01

    Pot experiments were conducted to investigate the effect of AM (Glomus mosseae ) fungi inoculation (M) on the growth of maize and phyto extraction of selected heavy metals from a soil contaminated with crude oil (C). Four soil treatments, each with three replicates i.e., C/sup +/M/sup +/, M/sup +/, C/sup +/ and control (without oil and inoculum) were conducted. Half of the pots with the soil treatments were planted with singly sown (SS) and the other half with densely sown i.e., four maize seedlings (DS). Various plant growth attributes were measured at weekly intervals Cu/sup 2+/, Ni/sup 2+/, Pb/sup 2+/ and Cd/sup 2+/ in the soil, root and shoot of maize plants were determined separately. Inoculation by AM promoted the vegetative growth attributes in both treatments viz., C/sup +/M/sup +/ and M/+. AM inoculation also promoted the hyper extraction of heavy metals from C/sup +/M/sup +/ soils, but inhibited by soils treated with M/sup +/. High planting density i.e., DS also promoted phyto extraction of heavy metals from uncontaminated (M/sup +/) soils, but had minimal effect on phyto extraction from oil contaminated soils (C/sup +/). Planting density complemented the promotive effect of AM inoculation on phyto extraction of heavy metals from C/sup +/ soils. The hyper extraction of selected metals from soil is more favored by planting density in C/sup +/ soils, whereas AM inoculation tends to exclude heavy metals from potted plants. However, in case of C/sup +/M/sup +/ soils, AM inoculation promotes the hyper extraction of metals more than planting density. While the combination of the two phenomena act synergistically to promote metal hyper extraction from C/sup +/M/sup +/ as well as M/sup +/ soils. (author)

  15. Market survey on products from the Tema Oil Refinery carried out as part of the feasibility study on the Tema Oil Refinery expansion project. Export trade information

    International Nuclear Information System (INIS)

    Anon.

    1991-10-01

    The Tema Oil Refinery (TOR), which was commissioned in 1963, is a simple hydroskimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years some of the equipment in the refinery has deteriorated or become obsolete necessitating major rehabilitation. A feasibility study is investigating the modernization and expansion of the refinery to meet projected market demands until the year 2005. The report presents the results of a market survey done on products from TOR

  16. More oil sand cooperation between Canada and Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    1977-07-01

    Venezuela has pioneered the production of heavy oil, according to Dr. A. Guzman-Reyes, director general of hydrocarbons for the Venezuelan government. The first heavy oil production began in Venezuela 60 yr ago and the oil industry has steadily improved methods of producing and handling heavy oil. The country's producing fields are capable of yielding almost one million barrels of heavy oil daily, although actual production, largely because of market limitations, is about 650,000 bpd. Canada's daily heavy oil production, including the 60,000 bbl of synthetic crude produced daily by the Great Canadian Oil Sands plant, is about 200,000 bbl. Dr. Guzman-Reyes stated that Venezuela intends to rapidly develop heavy oil production and upgrade facilities to maintain its export markets. The national oil company, Petroleos de Venezuela, plans to invest 4 times the amount spent on oil development over the last 60 yr during the next 10 yr, a total of $3 billion by 1980.

  17. Exporting the 'Norwegian Model': The effect of administrative design on oil sector performance

    Energy Technology Data Exchange (ETDEWEB)

    Thurber, Mark C., E-mail: mark.thurber@stanford.edu [Program on Energy and Sustainable Development, Stanford University, Stanford, CA 94305 (United States); Hults, David R. [Program on Energy and Sustainable Development, Stanford University, Stanford, CA 94305 (United States); Heller, Patrick R.P. [Revenue Watch Institute, New York, NY 10019 (United States)

    2011-09-15

    Norway has administered its petroleum resources using three distinct government bodies: a national oil company engaged in commercial hydrocarbon operations; a government ministry to direct policy; and a regulatory body to provide oversight and technical expertise. Norway's relative success in managing its hydrocarbons has prompted development institutions to consider whether this 'Norwegian Model' of separated government functions should be recommended to other oil-producing countries. By studying ten countries that have used widely different approaches in administering their hydrocarbon sectors, we conclude that separation of functions is not a prerequisite to successful oil sector development. Countries where separation of functions has worked are characterized by the combination of high institutional capacity and robust political competition. Unchallenged leaders often appear able to adequately discharge commercial and policy/regulatory functions using the same entity, although this approach may not be robust against political changes. Where institutional capacity is lacking, better outcomes may result from consolidating commercial, policy, and regulatory functions until such capacity has further developed. Countries with vibrant political competition but limited institutional capacity pose the most significant challenge for oil sector reform: Unitary control over the sector is impossible but separation of functions is often difficult to implement. - Highlights: > The 'Norwegian Model' separates commercial, policy, and regulatory functions in oil. > We study ten oil-producing countries to assess the separation of functions model. > The model is useful where there is institutional capacity and political competition. > Consolidation of functions can work better when political power is concentrated. > Countries with low capacity may also be better off consolidating functions.

  18. Export spillovers

    DEFF Research Database (Denmark)

    Choquette, Eliane; Meinen, Philipp

    2015-01-01

    This paper studies the importance of export spillovers in a firm's decision to enter specific export markets and extends the current state of the literature by assessing different mechanisms through which they may occur, namely (i) labour movement, (ii) intra-industry spillovers and (iii) inter......-industry linkages. We do so by exploiting a unique data set covering the universe of manufacturing firms in Denmark for the period 1995–2006 which combines transaction-level export data, firm accounting data, employer–employee linked data and information from yearly input–output tables. We corroborate...... the literature on export spillovers by presenting robust evidence of destination-specific export spillovers. The results suggest that labour mobility as well as intra- and inter-industry linkages (backward linkages) are important channels for export spillovers, while presenting heterogeneous effects across firms...

  19. Injection of multi-azimuth permeable planes in weakly cemented formations for enhanced heavy-oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Hocking, G. [Society of Petroleum Engineers, Richardson, TX (United States)]|[GeoSierra LLC, Norcross, GA (United States); Cavender, T.; Schultz, R.L. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Halliburton Energy Services, Calgary, AB (Canada)

    2008-10-15

    Weakly cemented formations have minimal strength without fracture toughness. As such, the well stimulation process must be different from the fracturing process that occurs in hard rocks. This paper presented field injection experiments of multi-azimuth, injected, vertical planar geometries in several weakly cemented formations. The application of the method to shallow petroleum soft rock reservoirs was described, with particular reference to the thermal and solvent recovery of heavy oil. This study showed that in weakly cemented formations, a well-initiation device can control the azimuth of injected vertical planes, thereby controlling the rate of injection and the viscosity of the injected fluid. The concept of using the multi-azimuth, vertical permeable planes has strong potential in soft-rock formations for enhanced production in both shallow gas and shallow heavy-oil reservoirs. The method can be applied in a single well injector-producer for the continuous injection of steam and the continuous extraction of oil, similar to steam assisted gravity drainage (SAGD) and may be more efficient than a confined horizontal well pair typically used in SAGD. However, the authors noted that the effectiveness of the multi-azimuth process has yet to be proven for oil sand formations. 13 refs., 1 tab., 13 figs.

  20. Chromatographic and spectroscopic analysis of heavy crude oil mixtures with emphasis in nuclear magnetic resonance spectroscopy: A review

    International Nuclear Information System (INIS)

    Silva, Sandra L.; Silva, Artur M.S.; Ribeiro, Jorge C.; Martins, Fernando G.; Da Silva, Francisco A.; Silva, Carlos M.

    2011-01-01

    Graphical abstract: The chromatographic and spectroscopic techniques used to characterize heavy crude oils, although more focused in the nuclear magnetic resonance spectroscopy as the technique of choice, due to its capability to provide great information on the chemical nature of individual types of proton and carbon atoms in different and complex mixtures of crude oils are described. This review is based on 65 references and describes in a critical and interpretative ways the advantages of the NMR spectroscopy as a main technique to be used in crude oil refining industries that want to characterize crude oil fractions and the obtained refined products. Highlights: ► Chromatogrfaphic and spectroscopic techniques used to characterize heavy crude oils have been reviewed. ► This review describes in a critical and interpretative ways the advantages of the NMR spectroscopy as a main technique to be used in crude oil refining industries. ► The progress in the interpretation of the NMR spectra and of different multivariate data analyses and their potential in the identification and characterization of hydrocarbons and their physical and chemical properties have also been reviewed. - Abstract: The state of the art in the characterization of heavy crude oil mixtures is presented. This characterization can be done by different techniques, such as gas chromatography (GC), high performance liquid chromatography (HPLC), thin layer chromatography (TLC), infrared spectroscopy (IR), Raman spectroscopy, nuclear magnetic resonance (NMR) spectroscopy and mass spectrometry (MS). Nuclear magnetic resonance spectroscopy is the technique of choice due to its capability to provide information on the chemical nature of individual types of hydrogen and carbon atoms in different and complex mixtures of crude oils. The progress made in the interpretation of the NMR spectra with the development of new NMR techniques and different multivariate data analyses could give relevant

  1. Electricity generation analyses in an oil-exporting country: Transition to non-fossil fuel based power units in Saudi Arabia

    International Nuclear Information System (INIS)

    Farnoosh, Arash; Lantz, Frederic; Percebois, Jacques

    2013-12-01

    In Saudi Arabia, fossil-fuel is the main source of power generation. Due to the huge economic and demographic growth, the electricity consumption in Saudi Arabia has increased and should continue to increase at a very fast rate. At the moment, more than half a million barrels of oil per day is used directly for power generation. Herein, we assess the power generation situation of the country and its future conditions through a modelling approach. For this purpose, we present the current situation by detailing the existing generation mix of electricity. Then we develop a optimization model of the power sector which aims to define the best production and investment pattern to reach the expected demand. Subsequently, we will carry out a sensitivity analysis so as to evaluate the robustness of the model's by taking into account the integration variability of the other alternative (non-fossil fuel based) resources. The results point out that the choices of investment in the power sector strongly affect the potential oil's exports of Saudi Arabia. (authors)

  2. A Chinese resource curse? The human rights effects of oil export dependence on China versus the United States

    NARCIS (Netherlands)

    Bader, J.; Daxecker, U.

    2015-01-01

    Critiques of China’s ‘oil diplomacy’ center on its alleged disregard for transparency and human rights, yet such claims ignore that the problematic relationship between resource extraction and human rights precedes Chinese market entry. This article explores whether human rights implications are

  3. Export strategy

    DEFF Research Database (Denmark)

    Knudsen, Thorbjørn; Koed Madsen, Tage

    2002-01-01

    It is argued here that traditional export strategy research (encompassing the study of internationalization processes and export performance) is characterized by weak theoretical foundations and could benefit from a reorientation towards a dynamic capabilities perspective (DCP). We seek to draw...... on insights from DCP in order to devise a theoretical basis that could enrich export strategy research. Although our development of DCP insights builds on previous work, it also adds a crucial distinction between knowledge stocks and informational architecture. Changes in architecture are of greater...... importance. Following this elaboration of the dynamic capabilities perspective, we outline some implications and guidelines for future export strategy research....

  4. Reasons for decision in the matter of Altresco Pittsfield L.P., Crestar Energy, Enron Capital and Trade Resources Corp. applications pursuant to Part VI of the National Energy Board Act of Licences to Export Natural Gas and, Husky Oil Operations Ltd., application pursuant to section 32 of the National Energy Board Act to amend a Licence to Export Natural Gas. Vol. 1

    International Nuclear Information System (INIS)

    1996-01-01

    Basis for the National Energy Board's decisions in four gas export applications were presented. Gas export applications were discussed in general terms, followed by a review of each of the four applications. (Altreso Pittsfield L.P., Crestar Energy, Enron Capital and Trade Resources Corp., and Husky Oil Operations Ltd). The reviews took into account the current gas supply, transportation, markets, gas sales contracts, and the status of regulatory authorizations. All four applications were approved. The terms and conditions of the licences to be issued were reproduced in Appendix 1. 1 tab

  5. Projections of the impact of expansion of domestic heavy oil production on the U.S. refining industry from 1990 to 2010. Topical report

    Energy Technology Data Exchange (ETDEWEB)

    Olsen, D.K.; Ramzel, E.B.; Strycker, A.R. [National Institute for Petroleum and Energy Research, Bartlesville, OK (United States). ITT Research Institute; Guariguata, G.; Salmen, F.G. [Bonner and Moore Management Science, Houston, TX (United States)

    1994-12-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil (10{degrees} to 20{degrees} API gravity) production. This report provides a compendium of the United States refining industry and analyzes the industry by Petroleum Administration for Defense District (PADD) and by ten smaller refining areas. The refining capacity, oil source and oil quality are analyzed, and projections are made for the U.S. refining industry for the years 1990 to 2010. The study used publicly available data as background. A linear program model of the U.S. refining industry was constructed and validated using 1990 U.S. refinery performance. Projections of domestic oil production (decline) and import of crude oil (increases) were balanced to meet anticipated demand to establish a base case for years 1990 through 2010. The impact of additional domestic heavy oil production, (300 MB/D to 900 MB/D, originating in select areas of the U.S.) on the U.S. refining complex was evaluated. This heavy oil could reduce the import rate and the balance of payments by displacing some imported, principally Mid-east, medium crude. The construction cost for refining units to accommodate this additional domestic heavy oil production in both the low and high volume scenarios is about 7 billion dollars for bottoms conversion capacity (delayed coking) with about 50% of the cost attributed to compliance with the Clean Air Act Amendment of 1990.

  6. Wettability Alteration of Sandstone and Carbonate Rocks by Using ZnO Nanoparticles in Heavy Oil Reservoirs

    Directory of Open Access Journals (Sweden)

    Masoumeh Tajmiri

    2015-10-01

    Full Text Available Efforts to enhance oil recovery through wettability alteration by nanoparticles have been attracted in recent years. However, many basic questions have been ambiguous up until now. Nanoparticles penetrate into pore volume of porous media, stick on the core surface, and by creating homogeneous water-wet area, cause to alter wettability. This work introduces the new concept of adding ZnO nanoparticles by an experimental work on wettability alteration and oil recovery through spontaneous imbibition mechanism. Laboratory tests were conducted in two experimental steps on four cylindrical core samples (three sandstones and one carbonate taken from a real Iranian heavy oil reservoir in Amott cell. In the first step, the core samples were saturated by crude oil. Next, the core samples were flooded with nanoparticles and saturated by crude oil for about two weeks. Then, the core samples were immersed in distilled water and the amount of recovery was monitored during 30 days for both steps. The experimental results showed that oil recovery for three sandstone cores changed from 20.74, 4.3, and 3.5% of original oil in place (OOIP in the absence of nanoparticles to 36.2, 17.57, and 20.68% of OOIP when nanoparticles were added respectively. Moreover, for the carbonate core, the recovery changed from zero to 8.89% of OOIP by adding nanoparticles. By the investigation of relative permeability curves, it was found that by adding ZnO nanoparticles, the crossover-point of curves shifted to the right for both sandstone and carbonate cores, which meant wettability was altered to water- wet. This study, for the first time, illustrated the remarkable role of ZnO nanoparticles in wettability alteration toward more water-wet for both sandstone and carbonate cores and enhancing oil recovery.

  7. Partitioning of naturally occurring radioactive material (NORM) and heavy metal in terminal crude oil sludge when undergoing thermal treatment

    International Nuclear Information System (INIS)

    Mohd Fuad, H.A.; Muhd Noor Muhd Yunus; Shamsuddin, A.H.; Sopian, K.

    2000-01-01

    In Malaysia currently more than one hundred oil rigs in operation extracting the crude oil, offshore the state of Terengganu, Sabah and Sarawak. Crude oil sludge are generated during the extraction of crude oil from the underground oil reservoir to the oil rigs, the separation process at the oil rigs and its storage at the crude oil terminal. These sludge are considered as Scheduled Waste (contains heavy metals) by Department of Environmental (DOE) and Low Level Radioactive Waste (contain NORM) by the Atomic Energy Licensing Board (AELB), thus cannot be disposed freely without proper control. The current method of disposal, such as land farming is not recommended and will have long term impact to the environment, whereas storage practices in plastic drums does not warrant an ultimate solution. Due to its organic nature, there is a move to treat this sludge by using thermal treatment technology but prior to this, a study has to be carried out to determine the partitioning of the various elements present in the sludge. Gamma spectroscopy and Neutron Activation Analysis (NAA) were used to analyze the concentrations of radionuclides whereas NAA as well as ICP-MS techniques were applied for heavy metal analysis in the sludge samples. The samples were then heated at temperature ranging from 100 degree C - 800 degree C for a period of 30 - 150 minutes. The ash produced at that temperature and duration were then analyzed again for the various elemental concentrations using the above mentioned techniques. The percent volatilization was then derived mathematically. From this study, it was found that the percentage of volatilization varies from 2-70%, which is a function of the elements of concerned, temperature and time. Uranium seems to volatilized much more than the rest of radionuclides. Higher temperature (>500 degree C) and longer exposure time (>60 minutes) promoted metal and radionuclide volatilization significantly. Typical to incinerator operating environment i

  8. A tale of two countries : blessed with huge heavy oil resources, Canada and Venezuela pursue different paths

    International Nuclear Information System (INIS)

    Ball, C.

    2005-01-01

    Both Canada and Venezuela are rich in heavy oil resources. This article presented an overview of current development activities in both countries. International interest in the oil sands region has been highlighted by the French oil company Total's acquisition of Deer Creek Energy Ltd in Alberta for $1.35 billion. The acquisition supports the company's strategy of expanding heavy oil operations in the Athabasca region. With 47 per cent participation in the Sincor project, Total is already a major player in Venezuela. Although the Sincor project is one of the world's largest developments, future investment is in jeopardy due to an unpredictable government and shifts in policy by the state-run oil company Petroleos de Venezuela S.A. (PDVSA). The country's energy minister has recently announced that all existing agreements will be terminated as of December 31, 2005. The government has allowed 6 months for companies to enter into new agreements with new terms. Under revised rules, foreign companies will be required to pay income tax at a rate of 50 per cent. The rate will be applied retroactively to profits made over the last 5 years. Under the new law, agreements could be established under the terms of mixed companies, where Venezuela will have majority equity in the company that exploits the oil. In addition, the government has accused companies of not paying the required income tax levels on contracts, and some companies have been fined as much as $100 million. It was suggested that current difficulties are the result of an incoherent energy policy and an unstable regime. The international oil and gas community is watching developments, and it was anticipated that parties previously considering Venezuela as an investment opportunity will now reconsider. By contrast, Alberta has been praised by oil companies for its stable regulatory regime and its reasonable royalty structure. Thanks to a purge of 18,000 employees from PDVSA by Venezuelan president, Alberta is now

  9. Electron beam technology for multipollutant emissions control from heavy fuel oil-fired boiler.

    Science.gov (United States)

    Chmielewski, Andrzej G; Ostapczuk, Anna; Licki, Janusz

    2010-08-01

    The electron beam treatment technology for purification of exhaust gases from the burning of heavy fuel oil (HFO) mazout with sulfur content approximately 3 wt % was tested at the Institute of Nuclear Chemistry and Technology laboratory plant. The parametric study was conducted to determine the sulfur dioxide (SO2), oxides of nitrogen (NO(x)), and polycyclic aromatic hydrocarbon (PAH) removal efficiency as a function of temperature and humidity of irradiated gases, absorbed irradiation dose, and ammonia stoichiometry process parameters. In the test performed under optimal conditions with an irradiation dose of 12.4 kGy, simultaneous removal efficiencies of approximately 98% for SO2, and 80% for NO(x) were recorded. The simultaneous decrease of PAH and one-ringed aromatic hydrocarbon (benzene, toluene, and xylenes [BTX]) concentrations was observed in the irradiated flue gas. Overall removal efficiencies of approximately 42% for PAHs and 86% for BTXs were achieved with an irradiation dose 5.3 kGy. The decomposition ratio of these compounds increased with an increase of absorbed dose. The decrease of PAH and BTX concentrations was followed by the increase of oxygen-containing aromatic hydrocarbon concentrations. The PAH and BTX decomposition process was initialized through the reaction with hydroxyl radicals that formed in the electron beam irradiated flue gas. Their decomposition process is based on similar principles as the primary reaction concerning SO2 and NO(x) removal; that is, free radicals attack organic compound chains or rings, causing volatile organic compound decomposition. Thus, the electron beam flue gas treatment (EBFGT) technology ensures simultaneous removal of acid (SO2 and NO(x)) and organic (PAH and BTX) pollutants from flue gas emitted from burning of HFO. This technology is a multipollutant emission control technology that can be applied for treatment of flue gas emitted from coal-, lignite-, and HFO-fired boilers. Other thermal processes such

  10. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED IN STABLE NANOPOROUS HOST

    Energy Technology Data Exchange (ETDEWEB)

    Conrad Ingram; Mark Mitchell

    2005-11-15

    Composite materials of SBA-15/zeolite Y were synthesized from zeolite Y precursor and a synthesis mixture of mesoporous silicate SBA-15 via a hydrothermal process in the presence of a slightly acidic media of pH 4-6 with 2M H{sub 2}SO{sub 4}. The SBA-15/ZY composites showed Type IV adsorption isotherms, narrow BJH average pore size distribution of 4.9 nm, surface areas up to 800 m{sup 2}2/g and pore volumes 1.03 cm{sup 3}, all comparable to pure SBA-15 synthesized under similar conditions. Chemical analysis revealed Si/Al ratio down to 8.5 in the most aluminated sample, and {sup 27}AlSS MAS NMR confirmed aluminum was in tetrahedral coordination. This method of introduction of Al in pure T{sub d} coordination is effective in comparison to other direct and post synthesis alumination methods. Bronsted acid sites were evident from a pyridinium peak at 1544 cm-1 in the FTIR spectrum after pyridine adsorption, and from NH{sub 3} -TPD experiments. SBA-15/ZY composites showed significant catalytic activities for the dealkylation of isopropylbenzene to benzene and propene, similar to those of commercial zeolite Y. It was observed that higher conversion for catalysts synthesized with high amount of ZY precursor mixture added to the SBA-15. Over all the composites has shown good catalytic activity. Further studies will be focused on gaining a better understand the nature of the precursor, and to characterize and to locate the acid sites in the composite material. The composite will also be evaluated for heavy oil conversion to naphtha and middle distillates.

  11. Technical and economic feasibility study of enhanced oil recovery in six Colombian fields. Appendix C. Export trade information

    Energy Technology Data Exchange (ETDEWEB)

    1986-09-01

    The primary objectives of the study were to determine which of the reservoirs in the principal fields were amenable to enhanced oil recovery (EOR) processes, to evaluate which process was the most effective from both a technical and economic point of view, and to propose the steps required to further investigate the recommended EOR methods at the laboratory and field (pilot) level. Appendix C is divided into three sections: (A) Casabe Field; (B) La Cira Field; and (C) Tibu-Barco.

  12. Preconditioning methods to improve SAGD performance in heavy oil and bitumen reservoirs with variable oil phase viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Gates, I.D. [Gushor Inc., Calgary, AB (Canada)]|[Calgary Univ., AB (Canada). Dept. of Chemical and Petroleum Engineering; Larter, S.R.; Adams, J.J.; Snowdon, L.; Jiang, C. [Gushor Inc., Calgary, AB (Canada)]|[Calgary Univ., Calgary, AB (Canada). Dept. of Geoscience

    2008-10-15

    This study investigated preconditioning techniques for altering reservoir fluid properties prior to steam assisted gravity drainage (SAGD) recovery processes. Viscosity-reducing agents were distributed in mobile reservoir water. Simulations were conducted to demonstrate the method's ability to modify oil viscosity prior to steam injection. The study simulated the action of water soluble organic solvents that preferentially partitioned in the oil phase. The solvent was injected with water into the reservoir in a slow waterflood that did not displace oil from the near wellbore region. A reservoir simulation model was used to investigate the technique. Shu's correlation was used to establish a viscosity correlation for the bitumen and solvent mixtures. Solvent injection was modelled by converting the oil phase viscosity through time. Over the first 2 years, oil rates of the preconditioned case were double that of the non-preconditioned case study. However, after 11 years, the preconditioned case's rates declined below rates observed in the non-preconditioned case. The model demonstrated that oil viscosity distributions were significantly altered using the preconditioners. The majority of the most viscous oil surrounding the production well was significantly reduced. It was concluded that accelerated steam chamber growth provided faster access to lower viscosity materials at the top of the reservoir. 12 refs., 9 figs.

  13. Feasibility study on the modernization and expansion of the Tema Oil Refinery. Executive Summary. Export trade information

    International Nuclear Information System (INIS)

    Anon.

    1992-04-01

    The Tema Oil Refinery (TOR), which was commissioned in 1963, is a simple hydro-skimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years some of the equipment in the refinery has deteriorated or become obsolete necessitating major rehabilitation. A study of the refinery expansion project takes into consideration earlier studies and, equally important, recognizes the extensive work done by TOR in rehabilitating the refinery. The program, carried out in phases because of funding limitations, has addressed the critical repairs and replacements in the process units and utilities necessary to prolong the life of the refinery and assure reliability and safe operation. It undertook the task of investigating the feasibility of modernizing and expanding the refinery at Tema, Ghana to meet projected market demands until the year 2005. A process planning study was conducted to select the optimal process and utility configuration which would result in economic benefits to Ghana

  14. Effects of temperature and wave conditions on chemical dispersion efficacy of heavy fuel oil in an experimental flow-through wave tank.

    Science.gov (United States)

    Li, Zhengkai; Lee, Kenneth; King, Thomas; Boufadel, Michel C; Venosa, Albert D

    2010-09-01

    The effectiveness of chemical dispersants (Corexit 9500 and SPC 1000) on heavy fuel oil (IFO180 as test oil) has been evaluated under different wave conditions in a flow-through wave tank. The dispersant effectiveness was determined by measuring oil concentrations and droplet size distributions. An analysis of covariance (ANCOVA) model indicated that wave type and temperature significantly (p or = 400 microm). Copyright 2010 Elsevier Ltd. All rights reserved.

  15. Parental exposure to heavy fuel oil induces developmental toxicity in offspring of the sea urchin Strongylocentrotus intermedius.

    Science.gov (United States)

    Duan, Meina; Xiong, Deqi; Yang, Mengye; Xiong, Yijun; Ding, Guanghui

    2018-05-03

    The present study investigated the toxic effects of parental (maternal/paternal) exposure to heavy fuel oil (HFO) on the adult reproductive state, gamete quality and development of the offspring of the sea urchin Strongylocentrotus intermedius. Adult sea urchins were exposed to effluents from HFO-oiled gravel columns for 7 days to simulate an oil-contaminated gravel shore, and then gametes of adult sea urchins were used to produce embryos to determine developmental toxicity. For adult sea urchins, no significant difference in the somatic size and weight was found between the various oil loadings tested, while the gonad weight and gonad index were significantly decreased at higher oil loadings. The spawning ability of adults and fecundity of females significantly decreased. For gametes, no effect was observed on the egg size and fertilization success in any of the groups. However, a significant increase in the percentage of anomalies in the offspring was observed and then quantified by an integrative toxicity index (ITI) at 24 and 48 h post fertilization. The offspring from exposed parents showed higher ITI values with more malformed embryos. The results confirmed that parental exposure to HFO can cause adverse effects on the offspring and consequently affect the recruitment and population maintenance of sea urchins. Copyright © 2018 Elsevier Inc. All rights reserved.

  16. A case history of heavy oil separation in northern Alberta : a singular challenge of demulsifier optimization and application

    Energy Technology Data Exchange (ETDEWEB)

    Wylde, J.J.; Coscio, S.; Barbu, V. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Clariant Oil Services, Montreal, PQ (Canada)

    2008-10-15

    Water-in-oil emulsions are commonly encountered in the oil industry. The type of emulsion formed are determined by the abundance of the two phases. Emulsions can be stabilized by emulsifiers which concentrate themselves at the oil-water interface and form interfacial films that reduce the interfacial tension and promote emulsification and dispersion of droplets. This paper described the continual improvement cycle for the fluid separation process of a heavy oil/oil sands production facility in northern Alberta over a 3 year period. The operator was faced with the challenge of moving away from injection of 2 separate demulsifier formulations to a single product. The different conditions that existed at the two injection locations were described. A newly developed and unique bottle testing method was used to simulate the field conditions. The dilution of the final product blend made a significant difference to the final performance in the field. The field testing and demulsifier optimization exercise showed that the injection of 2 separate demulsifier products before 2007 resulted in trouble free operation. The bottle test procedure required redesign in order to accurately simulate the field use of a single demulsifier product. The general increase in basic sediment and water (BS and W) seen at the Lease Automatic Custody Transfer (LACT) site may be due to the increase in gross fluid throughput, mostly water. Residence times were significantly reduced, and plant operability was continually changing allowing the emulsion to pass through its inversion point. 18 refs., 4 figs.

  17. Experimental study of solvent-based emulsion injection to enhance heavy oil recovery in Alaska North Slope area

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, F.; Mamora, D. [Texas A and M Univ., College Station, TX (United States)

    2010-07-01

    This study examined the feasibility of using a chemical enhanced oil recovery method to overcome some of the technical challenges associated with thermal recovery in the Alaska North Slope (ANS). This paper described the second stage research of an experimental study on nano-particle and surfactant-stabilized solvent-based emulsions for the ANS area. Four successful core flood experiments were performed using heavy ANS oil. The runs included water flooding followed by emulsion flooding; and pure emulsion injection core flooding. The injection rate and core flooding temperature remained constant and only 1 PV micro-emulsion was injected after breakthrough under water flooding or emulsion flooding. Oil recovery increased by 26.4 percent from 56.2 percent original oil in place (OOIP) with waterflooding to 82.6 percent OOIP with injection of emulsion following water flooding. Oil recovery was slightly higher with pure emulsion flooding, at 85.8 percent OOIP. The study showed that low permeability generally resulted in a higher shear rate, which is favourable for in-situ emulsification and higher displacement efficiency. 11 refs., 4 tabs., 20 figs.

  18. The Diversity of Endophytic Methylotrophic Bacteria in an Oil-Contaminated and an Oil-Free Mangrove Ecosystem and Their Tolerance to Heavy Metals

    OpenAIRE

    Dourado, Manuella Nobrega; Ferreira, Anderson; Araújo, Welington Luiz; Azevedo, João Lúcio; Lacava, Paulo Teixeira

    2012-01-01

    Methylobacterium strains were isolated from mangrove samples collected in Bertioga, SP, Brazil, from locations either contaminated or uncontaminated by oil spills. The tolerances of the strains to different heavy metals were assessed by exposing them to different concentrations of cadmium, lead, and arsenic (0.1 mM, 0.5 mM, 1 mM, 2 mM, 4 mM, and 8 mM). Additionally, the genetic diversity of Methylobacterium spp. was determined by sequence analysis of the 16S rRNA genes. The isolates from the ...

  19. Heavy metals screening of rice bran oils and its relation to composition

    Science.gov (United States)

    Rice bran oil contains beneficial compounds that contribute to the high stability of the oil itself, as well as the health of consumers. As a result, rice bran oil has been growing in popularity and is now widely used in many countries. However, concerns have surfaced in recent years related to the ...

  20. Evaluation of biosurfactants grown in corn oil by Rhodococcus rhodochrous on removing of heavy metal ion from aqueous solution

    International Nuclear Information System (INIS)

    Suryanti, Venty; Hastuti, Sri; Pujiastuti, Dwi

    2016-01-01

    The potential application of biosurfactants to remove heavy metal ion from aqueous solution by batch technique was examined. The glycolipids type biosurfactants were grown in a media containing of 20% v/v corn oil with 7 days of fermentation by Rhodococcus rhodochrous. The biosurfactants reduced the surface tension of water of about 51% from 62 mN/m to 30 mN/m. The biosurfactant increased the E24 of water-palm oil emulsion of about 55% from 43% to 97% and could maintain this E24 value of above 50% for up to 9 days. Heavy metal ion removal, in this case cadmium ion, by crude and patially purified biosurfactants has been investigated from aqueous solution at pH 6. Adsorption capacity of Cd(II) ion by crude biosurfactant with 5 and 10 minutes of contact times were 1.74 and 1.82 mg/g, respectively. Additionally, the adsorption capacity of Cd(II) ion by partially purified biosurfactant with 5 and 10 minutes of contact times were 0.79 and 1.34 mg/g, respectively. The results demonstrated that the adsorption capacity of Cd(II) ion by crude biosurfactant was higher than that of by partially purified biosurfactant. The results suggested that the biosurfactant could be used in the removal of heavy metal ions from aqueous solution

  1. Evaluation of biosurfactants grown in corn oil by Rhodococcus rhodochrous on removing of heavy metal ion from aqueous solution

    Science.gov (United States)

    Suryanti, Venty; Hastuti, Sri; Pujiastuti, Dwi

    2016-02-01

    The potential application of biosurfactants to remove heavy metal ion from aqueous solution by batch technique was examined. The glycolipids type biosurfactants were grown in a media containing of 20% v/v corn oil with 7 days of fermentation by Rhodococcus rhodochrous. The biosurfactants reduced the surface tension of water of about 51% from 62 mN/m to 30 mN/m. The biosurfactant increased the E24 of water-palm oil emulsion of about 55% from 43% to 97% and could maintain this E24 value of above 50% for up to 9 days. Heavy metal ion removal, in this case cadmium ion, by crude and patially purified biosurfactants has been investigated from aqueous solution at pH 6. Adsorption capacity of Cd(II) ion by crude biosurfactant with 5 and 10 minutes of contact times were 1.74 and 1.82 mg/g, respectively. Additionally, the adsorption capacity of Cd(II) ion by partially purified biosurfactant with 5 and 10 minutes of contact times were 0.79 and 1.34 mg/g, respectively. The results demonstrated that the adsorption capacity of Cd(II) ion by crude biosurfactant was higher than that of by partially purified biosurfactant. The results suggested that the biosurfactant could be used in the removal of heavy metal ions from aqueous solution.

  2. Evaluation of biosurfactants grown in corn oil by Rhodococcus rhodochrous on removing of heavy metal ion from aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Suryanti, Venty, E-mail: venty@mipa.uns.ac.id; Hastuti, Sri; Pujiastuti, Dwi [Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret University Jl. Ir. Sutami 36A, Surakarta, Central Java 57126 (Indonesia)

    2016-02-08

    The potential application of biosurfactants to remove heavy metal ion from aqueous solution by batch technique was examined. The glycolipids type biosurfactants were grown in a media containing of 20% v/v corn oil with 7 days of fermentation by Rhodococcus rhodochrous. The biosurfactants reduced the surface tension of water of about 51% from 62 mN/m to 30 mN/m. The biosurfactant increased the E24 of water-palm oil emulsion of about 55% from 43% to 97% and could maintain this E24 value of above 50% for up to 9 days. Heavy metal ion removal, in this case cadmium ion, by crude and patially purified biosurfactants has been investigated from aqueous solution at pH 6. Adsorption capacity of Cd(II) ion by crude biosurfactant with 5 and 10 minutes of contact times were 1.74 and 1.82 mg/g, respectively. Additionally, the adsorption capacity of Cd(II) ion by partially purified biosurfactant with 5 and 10 minutes of contact times were 0.79 and 1.34 mg/g, respectively. The results demonstrated that the adsorption capacity of Cd(II) ion by crude biosurfactant was higher than that of by partially purified biosurfactant. The results suggested that the biosurfactant could be used in the removal of heavy metal ions from aqueous solution.

  3. Methodologies, solutions, and lessons learned from heavy oil well testing with an ESP, offshore UK in the Bentley field, block 9/3b

    Energy Technology Data Exchange (ETDEWEB)

    Brennan, Barny; Lucas-Clements, Charles; Kew, Steve [Xcite Energy Resources (United Kingdom); Shumakov, Yakov; Camilleri, Lawrence; Akuanyionwu, Obinna; Tonoglu, Ahmet [Schlumberger (United Kingdom)

    2011-07-01

    Over the past decade, there has been an increase in hydrocarbon demand that led to the production of heavy oil fields in the United Kingdom continental shelf (UKCS). Most of the activity has been confined to exploration and appraisal drilling, the reason being the high uncertainty of the reservoir and fluid properties. Due to the operational complexity inherent to heavy oil, the use of conventional appraisal-well testing technology is limited. A novel technique developed to determine the most appropriate technology for testing wells with heavy oil using an electrical submersible pump (ESP) is presented in this paper. This technique was applied in the Bentley field. Some of the technical challenges include, maintaining fluid mobility using a surface-testing equipment, obtaining accurate flow measurements, a short weather window, and oil and gas separation for metering. Combining technologies such as dual-energy gamma ray venturi multiphase flowmeter, realtime monitoring, and ESP completion made it possible to execute the well test.

  4. Irradiated Sewage Sludge for Production of Fennel (Foeniculum vulgare L.) Plants in Sandy Soil 2- Seed production, oil content, oil constituents and heavy metals in seeds

    International Nuclear Information System (INIS)

    El-Motaium, R. A.; Abo-El-Seoud, M. A.

    2007-01-01

    Field experiment was conducted to study the impact of irradiated and non-irradiated sewage sludge applied to sandy soil on fennel plants (Foeniculum vulgare L.) productivity. In this regards, four rates of sewage sludge application were used (20, 40, 60 and 80 ton/ha) in addition to the mineral fertilizer treatment (control). Sandy soil amended with sewage sludge showed a promising effect on fennel seed yield. A linear gradual increase in seeds yield was observed as the sludge application rate increases. Seeds production increased by 41% to 308% over the control at 80 t /ha application rate, for non-irradiated and irradiated sewage sludge treatments, respectively. Irradiated sewage sludge treatments showed higher fennel seed yield than non-irradiated sewage sludge treatments.Volatile oil percent exhibited no observable variation due to the use of sewage sludge. A few and limited fluctuations could be observed. However, total oil content (cc/plot) increased due to the increase in seeds yield. The magnitude of increase in volatile oil production in response to the sewage sludge application was parallel to the increase in seeds yield. The GLC measurements of the fennel volatile oil reveal that, the t-anethole is the predominant fraction. However, fenchone was detected in relatively moderate concentration. The applied sewage sludge treatment induced some variations in fennel volatile oil constituents. The t.anethole is relatively higher in volatile oil obtained from plants grown on sandy soil fertilized with non-irradiated sewage sludge than the one fertilized with irradiated sewage sludge or chemical fertilizer. In the meantime, the obtained increase in t.anethole was accompanied by a decline in fenchone content. Seeds heavy metals (Zn, Fe, Pb, Cd) were determined. Under all sludge application rates iron and zinc concentrations were in the normal plant concentration range whereas, Cd concentrations were traces.

  5. Argentation chromatography coupled to ultrahigh-resolution mass spectrometry for the separation of a heavy crude oil.

    Science.gov (United States)

    Molnárné Guricza, Lilla; Schrader, Wolfgang

    2017-02-10

    Simplification of highly complex mixtures such as crude oil by using chromatographic methods makes it possible to get more detailed information about the composition of the analyte. Separation by argentation chromatography can be achieved based on the interaction of different strength between the silver ions (Ag + ) immobilized through a spacer on the silica gel surface and the π-bonds of the analytes. Heavy crude oils contain compounds with a high number of heteroatoms (N, O, S) and a high degree of unsaturation thus making them the perfect analyte for argentation chromatography. The direct coupling of argentation chromatography and ultrahigh-resolution mass spectrometry allows to continuously tracking the separation of the many different compounds by retention time and allows sensitive detection on a molecular level. Direct injection of a heavy crude oil into a ultrahigh-resolution mass spectrometer showed components with DBE of up to 25, whereas analytes with DBE of up to 35 could be detected only after separation with argentation chromatography. The reduced complexity achieved by the separation helps increasing the information depth. Copyright © 2016. Published by Elsevier B.V.

  6. Dynamic pore network simulator for modelling buoyancy-driven migration during depressurisation of heavy-oil systems

    Energy Technology Data Exchange (ETDEWEB)

    Ezeuko, C.C.; McDougall, S.R. [Heriot-Watt Univ., Edinburgh (United Kingdom); Bondino, I. [Total E and P UK Ltd., London (United Kingdom); Hamon, G. [Total S.A., Paris (France)

    2008-10-15

    In an attempt to investigate the impact of gravitational forces on gas evolution during solution gas drive, a number of vertically-oriented heavy oil depletion experiments have been conducted. Some of the results of these studies suggest the occurrence of gas migration during these tests. However, a major limitation of these experiments is the difficulty in visualizing the process in reservoir rock samples. Experimental observations using transparent glass models have been useful in this context and provide a sound physical basis for modelling gravitational gas migration in gas-oil systems. This paper presented a new pore network simulator that was capable of modelling the time-dependent migration of growing gas structures. Multiple pore filling events were dynamically modelled with interface tracking allowing the full range of migratory behaviours to be reproduced, including braided migration and discontinuous dispersed flow. Simulation results were compared with experiments and were found to be in excellent agreement. The paper presented the model and discussed the implication of evolution regime on recovery from heavy oil systems undergoing depressurization. The simulation results demonstrated the complex interaction of a number of network and fluid parameters.