WorldWideScience

Sample records for hard nonporous surface

  1. Recovery and Disinfection of Two Human Norovirus Surrogates, Feline Calicivirus and Murine Norovirus, from Hard Nonporous and Soft Porous Surfaces.

    Science.gov (United States)

    Yeargin, Thomas; Fraser, Angela; Huang, Guohui; Jiang, Xiuping

    2015-10-01

    Human norovirus is a leading cause of foodborne disease and can be transmitted through many routes, including environmental exposure to fomites. In this study, both the recovery and inactivation of two human norovirus surrogates, feline calicivirus (FCV) and murine norovirus (MNV), on hard nonporous surfaces (glass) and soft porous surfaces (polyester and cotton) were evaluated by both plaque assay and reverse transcription quantitative PCR method. Two disinfectants, sodium hypochlorite (8.25%) and accelerated hydrogen peroxide (AHP, at 4.25%) were evaluated for disinfection efficacy. Five coupons per surface type were used to evaluate the recovery of FCV and MNV by sonication and stomaching and the disinfection of each surface type by using 5 ml of disinfectant for a contact time of 5 min. FCV at an initial titer of ca. 7 log PFU/ml was recovered from glass, cotton, and polyester at 6.2, 5.4, and 3.8 log PFU/ml, respectively, compared with 5.5, 5.2, and 4.1 log PFU/ml, respectively, for MNV with an initial titer of ca. 6 log PFU/ml. The use of sodium hypochlorite (5,000 ppm) was able to inactivate both FCV and MNV (3.1 to 5.5 log PFU/ml) below the limit of detection on all three surface types. AHP (2,656 ppm) inactivated FCV (3.1 to 5.5 log PFU/ml) below the limit of detection for all three surface types but achieved minimal inactivation of MNV (0.17 to 1.37 log PFU/ml). Reduction of viral RNA by sodium hypochlorite corresponded to 2.72 to 4.06 log reduction for FCV and 2.07 to 3.04 log reduction for MNV on all three surface types. Reduction of viral RNA by AHP corresponded to 1.89 to 3.4 log reduction for FCV and 0.54 to 0.85 log reduction for MNV. Our results clearly indicate that both virus and surface types significantly influence recovery efficiency and disinfection efficacy. Based on the performance of our proposed testing method, an improvement in virus recovery will be needed to effectively validate virus disinfection of soft porous surfaces.

  2. Evaporation of HD Droplets From Nonporous, Inert Surfaces in TGA Microbalance Wind Tunnels

    Science.gov (United States)

    2008-09-01

    2007 4. TITLE AND SUBTITLE Evaporation of HD Droplets from Nonporous, Inert Surfaces in TGA Microbalancc Wind Tunnels 5a. CONTRACT NUMBER DAAD13...hr (lightly swirled on a rotating plateau). Then, the glass was rinsed with dematerialized water and dried (using appropriate fat-free non-felting

  3. Composite sampling of a Bacillus anthracis surrogate with cellulose sponge surface samplers from a nonporous surface.

    Directory of Open Access Journals (Sweden)

    Jenia A M Tufts

    Full Text Available A series of experiments was conducted to explore the utility of composite-based collection of surface samples for the detection of a Bacillus anthracis surrogate using cellulose sponge samplers on a nonporous stainless steel surface. Two composite-based collection approaches were evaluated over a surface area of 3716 cm2 (four separate 929 cm2 areas, larger than the 645 cm2 prescribed by the standard Centers for Disease Control (CDC and Prevention cellulose sponge sampling protocol for use on nonporous surfaces. The CDC method was also compared to a modified protocol where only one surface of the sponge sampler was used for each of the four areas composited. Differences in collection efficiency compared to positive controls and the potential for contaminant transfer for each protocol were assessed. The impact of the loss of wetting buffer from the sponge sampler onto additional surface areas sampled was evaluated. Statistical tests of the results using ANOVA indicate that the collection of composite samples using the modified sampling protocol is comparable to the collection of composite samples using the standard CDC protocol (p  =  0.261. Most of the surface-bound spores are collected on the first sampling pass, suggesting that multiple passes with the sponge sampler over the same surface may be unnecessary. The effect of moisture loss from the sponge sampler on collection efficiency was not significant (p  =  0.720 for both methods. Contaminant transfer occurs with both sampling protocols, but the magnitude of transfer is significantly greater when using the standard protocol than when the modified protocol is used (p<0.001. The results of this study suggest that composite surface sampling, by either method presented here, could successfully be used to increase the surface area sampled per sponge sampler, resulting in reduced sampling times in the field and decreased laboratory processing cost and turn-around times.

  4. Use of quantum dots in aqueous solution to detect blood fingermarks on non-porous surfaces.

    Science.gov (United States)

    Becue, Andy; Moret, Sébastien; Champod, Christophe; Margot, Pierre

    2009-10-30

    A new and original reagent based on the use of highly fluorescent cadmium telluride (CdTe) quantum dots (QDs) in aqueous solution is proposed to detect weak fingermarks in blood on non-porous surfaces. To assess the efficiency of this approach, comparisons were performed with one of the most efficient blood reagents on non-porous surfaces, Acid Yellow 7 (AY7). To this end, four non-porous surfaces were studied, i.e. glass, transparent polypropylene, black polyethylene, and aluminium foil. To evaluate the sensitivity of both reagents, sets of depleted fingermarks were prepared, using the same finger, initially soaked with blood, which was then successively applied on the same surface without recharging it with blood or latent secretions. The successive marks were then cut in halves and the halves treated separately with each reagent. The results showed that QDs were equally efficient to AY7 on glass, polyethylene and polypropylene surfaces, and were superior to AY7 on aluminium. The use of QDs in new, sensitive and highly efficient latent and blood mark detection techniques appears highly promising. Health and safety issues related to the use of cadmium are also discussed. It is suggested that applying QDs in aqueous solution (and not as a dry dusting powder) considerably lowers the toxicity risks.

  5. Fingerprint detection and using intercalated CdSe nanoparticles on non-porous surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Algarra, Manuel, E-mail: malgarra67@gmail.com [Centro de Geología da Universidade do Porto, Departamento de Geociências, Ambiente e Ordenamemto do Territorio do Porto, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre 687, 4169-007 Porto (Portugal); Radotić, Ksenija; Kalauzi, Aleksandar; Mutavdžić, Dragosav; Savić, Aleksandar [Institute for Multidisciplinary Research, University of Belgrade, Kneza Višeslava 1, 11000 Beograd (Serbia); Jiménez-Jiménez, José; Rodríguez-Castellón, Enrique [Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Málaga, Campus de Teatinos s/n, 29071Málaga (Spain); Silva, Joaquim C.G. Esteves da [Centro de Investigação em Química (CIQ-UP). Faculdade de Ciências da Universidade do Porto, Rua do Campo Alegre 687, 4169-007 Porto (Portugal); Guerrero-González, Juan José [Policía Científica, Cuerpo Nacional de Policía, Málaga (Spain)

    2014-02-17

    Graphical abstract: -- Highlights: •Fluorescent nanocomposite based on the inclusion of CdSe quantum dots in porous phosphate heterostructures. •Characterized by FTIR, XRD and fluorescence spectroscopies. •Deconvolution of the emission spectra was confirmed by using multivariate curve resolution (MCR) method. •Application for fingerprint detection and analysis on different non-porous surfaces. -- Abstract: A fluorescent nanocomposite based on the inclusion of CdSe quantum dots in porous phosphate heterostructures, functionalized with amino groups (PPH-NH{sub 2}@CdSe), was synthesized, characterized and used for fingerprint detection. The main scopes of this work were first to develop a friendly chemical powder for detecting latent fingerprints, especially in non-porous surfaces; their further intercalation in PPH structure enables not to spread the fluorescent nanoparticles, for that reason very good fluorescent images can be obtained. The fingerprints, obtained on different non-porous surfaces such as iron tweezers, mobile telephone screen and magnetic band of a credit card, treated with this powder emit a pale orange luminescence under ultraviolet excitation. A further image processing consists of contrast enhancement that allows obtaining positive matches according to the information supplied from a police database, and showed to be more effective than that obtained with the non-processed images. Experimental results illustrate the effectiveness of proposed methods.

  6. Investigation of Critical Heat Flux Enhancement for Porous and Non-porous Structures without Surface Wettability Improvement

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Han; Bang, In Cheol [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2014-05-15

    Nanoparticles and nano-sheets have been used in base fluids to enhance the BHT and CHF. Nanoparticles such as Al{sub 2}O{sub 3}, TiO{sub 2}, ZnO, Ag, Au and SiC have been studied for investigating the enhancement in the BHT and CHF. Most of the studies illustrated the enhancement in the heat transfer and CHF based on nanoparticle deposition during boiling occurrences. Research on nanotechnology in boiling experiments such as the deposition of particles on heating surfaces, nanowires, and thin film coatings laid on a substrate was investigated as point of effective heat transfer methods. A theoretical model to predict the CHF based on the dynamic receding contact angle, which includes surface-liquid interaction effects, was accommodated the change of surface wettability due to the deposition of nanoparticles. Park et al., however, reported the reverse results that the enhancement in the CHF could not be explained by the relation of the improved surface wettability. They focused on the change of hydrodynamic instability wavelength due to the deposition of nanoparticles and concluded that the change of instability wavelength could be considered as the CHF enhancement mechanism. Therefore, an experimental CHF study without the change of surface wettability should be conducted to define the parameters attributing to the CHF. This paper presents a study on the enhancement BHT and CHF with porous and non-porous surfaces deposited on a bare indium tin oxide (ITO) surface using FC-72 refrigerant. Plasma enhanced chemical vapor deposition (PECVD) system was applied to deposit the SiC surface as non-porous structure and porous SiC-coated surface was manufactured by deposition of nanoparticles. For graphene surface, rapid thermal annealing (RTA) method and nanoparticles of graphene oxide were used for non-porous and porous structure, respectively. In the present work the study of the BHT and CHF is conducted using non-porous and porous heater surfaces without the effect of

  7. Small particle reagent based on crystal violet dye for developing latent fingerprints on non-porous wet surfaces

    Directory of Open Access Journals (Sweden)

    Richa Rohatgi

    2015-12-01

    Full Text Available Small particle reagent (SPR is a widely used method for developing latent fingerprints on non-porous wet surfaces. SPR based on zinc carbonate hydroxide monohydrate, ZnCo3·2Zn(OH2·H2O – also called basic zinc carbonate – has been formulated. The other ingredients of the formulation are crystal violet dye and a commercial liquid detergent. The composition develops clear, sharp and detailed fingerprints on non-porous items, after these were immersed separately in clean and dirty water for variable periods of time. The ability of the present formulation to detect weak and faint chance prints not only enhances its utility, but also its potentiality in forensic case work investigations. The raw materials used to prepare the SPR are cost-effective and non-hazardous.

  8. SUPER HARD SURFACED POLYMERS

    Energy Technology Data Exchange (ETDEWEB)

    Mansur, Louis K [ORNL; Bhattacharya, R [UES, Incorporated, Dayton, OH; Blau, Peter Julian [ORNL; Clemons, Art [ORNL; Eberle, Cliff [ORNL; Evans, H B [UES, Incorporated, Dayton, OH; Janke, Christopher James [ORNL; Jolly, Brian C [ORNL; Lee, E H [Consultant, Milpitas, CA; Leonard, Keith J [ORNL; Trejo, Rosa M [ORNL; Rivard, John D [ORNL

    2010-01-01

    High energy ion beam surface treatments were applied to a selected group of polymers. Of the six materials in the present study, four were thermoplastics (polycarbonate, polyethylene, polyethylene terephthalate, and polystyrene) and two were thermosets (epoxy and polyimide). The particular epoxy evaluated in this work is one of the resins used in formulating fiber reinforced composites for military helicopter blades. Measures of mechanical properties of the near surface regions were obtained by nanoindentation hardness and pin on disk wear. Attempts were also made to measure erosion resistance by particle impact. All materials were hardness tested. Pristine materials were very soft, having values in the range of approximately 0.1 to 0.5 GPa. Ion beam treatment increased hardness by up to 50 times compared to untreated materials. For reference, all materials were hardened to values higher than those typical of stainless steels. Wear tests were carried out on three of the materials, PET, PI and epoxy. On the ion beam treated epoxy no wear could be detected, whereas the untreated material showed significant wear.

  9. Persistence of the 2009 pandemic influenza A (H1N1 virus in water and on non-porous surface.

    Directory of Open Access Journals (Sweden)

    Amélie Dublineau

    Full Text Available Knowledge of influenza A virus survival in different environmental conditions is a key element for the implementation of hygiene and personal protection measures by health authorities. As it is dependent on virus isolates even within the same subtype, we studied the survival of the 2009 H1N1 pandemic (H1N1pdm virus in water and on non-porous surface. The H1N1pdm virus was subjected to various environmental parameters over time and tested for infectivity. In water, at low and medium salinity levels and 4°C, virus survived at least 200 days. Increasing temperature and salinity had a strong negative effect on the survival of the virus which remained infectious no more than 1 day at 35°C and 270 parts per thousand (ppt of salt. Based on modeled data, the H1N1pdm virus retained its infectivity on smooth non-porous surface for at least 7 days at 35°C and up to 66 days at 4°C. The H1N1pdm virus has thus the ability to persist in water and on glass surface for extended periods of time, even at 35°C. Additional experiments suggest that external viral structures in direct contact with the environment are mostly involved in loss of virus infectivity.

  10. Thermal desorption characteristics of CO, O2 and CO2 on non-porous water, crystalline water and silicate surfaces at sub-monolayer and multilayer coverages

    CERN Document Server

    Noble, J A; Dulieu, F; Fraser, H J

    2011-01-01

    The desorption characteristics of molecules on interstellar dust grains are important for modelling the behaviour of molecules in icy mantles and, critically, in describing the solid-gas interface. In this study, a series of laboratory experiments exploring the desorption of three small molecules from three astrophysically relevant surfaces are presented. The desorption of CO, O2 and CO2 at both sub-monolayer and multilayer coverages was investigated from non-porous water, crystalline water and silicate surfaces. Experimental data was modelled using the Polanyi-Wigner equation to produce a mathematical description of the desorption of each molecular species from each type of surface, uniquely describing both the monolayer and multilayer desorption in a single combined model. The implications of desorption behaviour over astrophysically relevant timescales are discussed.

  11. Different effects of surface heterogeneous atoms of porous and non-porous carbonaceous materials on adsorption of 1,1,2,2-tetrachloroethane in aqueous environment.

    Science.gov (United States)

    Chen, Weifeng; Ni, Jinzhi

    2017-05-01

    The surface heterogeneous atoms of carbonaceous materials (CMs) play an important role in adsorption of organic pollutants. However, little is known about the surface heterogeneous atoms of CMs might generate different effect on adsorption of hydrophobic organic compounds by porous carbonaceous materials - activated carbons (ACs) and non-porous carbonaceous materials (NPCMs). In this study, we observed that the surface oxygen and nitrogen atoms could decrease the adsorption affinity of both ACs and NPCMs for 1,1,2,2-tetrachloroethane (TeCA), but the degree of decreasing effects were very different. The increasing content of surface oxygen and nitrogen ([O + N]) caused a sharper decrease in adsorption affinity of ACs (slope of lg (kd/SA) vs [O + N]: -0.098∼-0.16) than that of NPCMs (slope of lg (kd/SA) vs [O + N]: -0.025∼-0.059) for TeCA. It was due to the water cluster formed by the surface hydrophilic atoms that could block the micropores and generate massive invalid adsorption sites in the micropores of ACs, while the water cluster only occupied the surface adsorption sites of NPCMs. Furthermore, with the increasing concentration of dissolved TeCA, the effect of surface area on adsorption affinity of NPCMs for TeCA kept constant while the effect of [O + N] decreased due to the competitive adsorption between water molecule and TeCA on the surface of NPCMs, meanwhile, both the effects of micropore volume and [O + N] on adsorption affinity of ACs for TeCA were decreased due to the mechanism of micropore volume filling. These findings are valuable for providing a deep insight into the adsorption mechanisms of CMs for TeCA.

  12. Characterisation of surface ionisation and adsorption of phenol and 4-nitrophenol on non-porous carbon blacks

    OpenAIRE

    Carrott, Peter; Carrott, Manuela; Vale, Tania; Valente Nabais, Joao; Mourao, Paulo

    2008-01-01

    The adsorption of phenol and 4-nitrophenol from aqueous solutions by carbon blacks was studied. Particular attention was paid to the characterisation of the surface chemistry and ionisation of the carbon blacks by use of a simple carbon surface ionisation model, as well as the use of a normalised form of the Freundlich equation for the analysis of the adsorption isotherms. The results indicated that the solutes interact directly with the graphene layers and that the adsorpti...

  13. Detection of anionic energetic material residues in enhanced fingermarks on porous and non-porous surfaces using ion chromatography.

    Science.gov (United States)

    Love, Catherine; Gilchrist, Elizabeth; Smith, Norman; Barron, Leon

    2013-09-10

    The ability to link criminal activity and identity using validated analytical approaches can be of great value to forensic scientists. Herein, the factors affecting the recovery and detection of inorganic and organic energetic material residues within chemically or physically enhanced fingermarks on paper and glass substrates are presented using micro-bore anion exchange chromatography with suppressed conductivity detection. Fingermarks on both surfaces were enhanced using aluminium powder or ninhydrin after spiking with model test mixtures or through contact with black-powder substitutes. A quantitative study of the effects of environmental/method interferences, the sweat matrix, the surface and the enhancement technique on the relative anion recovery of forensically relevant species is presented. It is shown that the analytical method could detect target analytes at the nanogram level even within excesses of enhancement reagents and their reaction products when using solid phase extraction and/or microfiltration. To our knowledge, this work demonstrates for the first time that ion chromatography can detect anions in energetic materials within fingermarks on two very different surfaces, after operational enhancement techniques commonly used by forensic scientists and police have been applied.

  14. SURFACES OF HARD-SPHERE SYSTEMS

    Directory of Open Access Journals (Sweden)

    Dietrich Stoyan

    2014-07-01

    Full Text Available In various situations surfaces appear that are formed by systems of hard spheres. Examples are porous layers as surfaces of sand heaps and biofilms or fracture surfaces of concrete. The present paper considers models where a statistically homogeneous system of hard spheres with random radii is intersected by a plane and the surface is formed by the spheres with centers close to this plane. Formulae are derived for various characteristics of such surfaces: for the porosity profile, i.e. the local porosity in dependence on the distance from the section plane and for the geometry of the sphere caps that look above the section plane.It turns out that these characteristics only depend on the first-order characteristics of the sphere system, its sphere density and the sphere radius distribution.Comparison with empirically studied biofilms shows that the model is realistic.

  15. Tenacity of human norovirus and the surrogates feline calicivirus and murine norovirus during long-term storage on common nonporous food contact surfaces.

    Science.gov (United States)

    Mormann, Sascha; Heißenberg, Cathrin; Pfannebecker, Jens; Becker, Barbara

    2015-01-01

    The transfer of human norovirus (hNV) to food via contaminated surfaces is highly probable during food production, processing, and preparation. In this study, the tenacity of hNV and its cultivable surrogates feline calicivirus (FCV) and murine norovirus (MNV) on two common nonporous surface materials at two storage temperatures was directly compared. Virus titer reduction on artificially inoculated stainless steel and plastic carriers was monitored for 70 days at room temperature and at 7°C. Viruses were recovered at various time points by elution. Genomes from intact capsids (hNV, FCV, and MNV) were quantified with real-time reverse transcription (RT) PCR, and infectivity (FCV and MNV) was assessed with plaque assay. RNase treatment before RNA extraction was used to eliminate exposed RNA and to assess capsid integrity. No significant differences in titer reduction were found between materials (stainless steel or plastic) with the plaque assay or the real-time quantitative RT-PCR. At room temperature, infectious FCV and MNV were detected for 7 days. Titers of intact hNV, FCV, and MNV capsids dropped gradually and were still detectable after 70 days with a loss of 3 to 4 log units. At 7°C, the viruses were considerably more stable than they were at room temperature. Although only MNV infectivity was unchanged after 70 days, the numbers of intact capsids (hNV, FCV, and MNV) were stable with less than a 1-log reduction. The results indicate that hNV persists on food contact surfaces and seems to remain infective for weeks. MNV appears to be more stable than FCV at 7°C, and thus is the most suitable surrogate for hNV under dry conditions. Although a perfect quantitative correlation between intact capsids and infective particles was not obtained, real-time quantitative RT-PCR provided qualitative data about hNV inactivation characteristics. The results of this comparative study might support future efforts in assessment of foodborne virus risk and food safety.

  16. Methods and Guidance for Testing the Efficacy of Antimicrobials against Biofilm Bacteria on Hard, Non-Porous Surfaces

    Science.gov (United States)

    EPA is announcing the availability of two test methods (MB-19 and MB-20) for evaluating the efficacy of antimicrobial pesticides against two biofilm bacteria, Pseudomonas aeruginosa and Staphylococcus aureus.

  17. Induction surface hardening of hard coated steels

    DEFF Research Database (Denmark)

    Pantleon, Karen; Kessler, Olaf; Hoffmann, Franz

    1999-01-01

    . The effect of induction surface hardening on the properties of the coating-substrate-systems is mainly characterized using investigations of microstructure and chemical composition as well as measurements of hardness and residual stresses in dependence on the distance from the surface. Furthermore......, the scratch test is used to estimate critical loads for cohesive and adhesive failure of the coatings. Additionally, distortion measurements are carried out. The results emphasize the advantage of induction surface hardening as a method of subsequent heat treatment of CVD-coated steels....

  18. Induction surface hardening of hard coated steels

    DEFF Research Database (Denmark)

    Pantleon, Karen; Kessler, Olaf; Hoffmann, Franz

    1999-01-01

    -process is the high deposition temperature, consequently the properties of steel substrates are negatively influenced. Therefore, a subsequent heat treatment of the coated steels is necessary to restore the properties of steels ready for operation. Induction surface hardening is used as a method of heat treatment....... The effect of induction surface hardening on the properties of the coating-substrate-systems is mainly characterized using investigations of microstructure and chemical composition as well as measurements of hardness and residual stresses in dependence on the distance from the surface. Furthermore......, the scratch test is used to estimate critical loads for cohesive and adhesive failure of the coatings. Additionally, distortion measurements are carried out. The results emphasize the advantage of induction surface hardening as a method of subsequent heat treatment of CVD-coated steels....

  19. Surface modulation of dental hard tissues

    Science.gov (United States)

    Tantbirojn, Daranee

    Tooth surfaces play a central role in the equilibrium of dental hard tissues, in which contrasting processes lead to loss or deposition of materials. The central interest of this Thesis was the modulation of tooth surfaces to control such equilibrium. Four specific studies were carried out to investigate different classes of surface modulating agents. These are: (1) Ionic modulation of the enamel surface to enhance stain removal . Dental stain is the most apparent form of tooth surface deposit. The nature of extrinsic stain in terms of spatial chemical composition was studied by using electron probe microanalysis. An ionic surface modulating agent, sodium tripolyphosphate (STPP), was evaluated. Image analysis methodologies were developed and the ability of STPP in stain removal was proved. (2) Thin film modulation with substantive polymeric coating and the effect on in vitro enamel de/re-mineralization . A novel polymeric coating that formed a thin film on the tooth surface was investigated for its inhibitory effect on artificial enamel caries, without interfering with the remineralization process. The preventive effect was distinct, but the mineral redeposition was questionable. (3) Thick film modulation with fluoride containing sealants and the effect on in vitro enamel and root caries development. Fluoride incorporated into resin material is an example of combining different classes of surface modulating agents to achieve an optimal outcome. A proper combination, such as in resin modified glass ionomer, showed in vitro caries inhibitory effect beyond the material boundary in both enamel and dentin. (4) Thick film modulation with dental adhesives and the determination of adhesion to dentin. Dentin adhesives modulate intracoronal tooth surfaces by enhancing adhesion to restorative materials. Conventional nominal bond tests were inadequate to determine the performance of current high strength adhesives. It was shown that interfacial fracture toughness test was more

  20. Analysis of surface hardness of artificially aged resin composites

    Directory of Open Access Journals (Sweden)

    Denise Cremonezzi Tornavoi

    2012-02-01

    Full Text Available This study evaluated the effect of artificially accelerated aging (AAA on the surface hardness of eight composite resins: Filtek Z250, Filtek Supreme, 4 Seasons, Herculite, P60, Tetric Ceram, Charisma, and Filtek Z100. Sixteen specimens were made from the test piece of each material, using an 8.0 × 2.0 mm teflon matrix. After 24 hours, eight specimens from each material were submitted to three surface hardness readings using a Shimadzu Microhardness Tester for 5 seconds at a load of 50 gf. The other eight specimens remained in the artificially accelerated aging machine for 382 hours and were submitted to the same surface hardness analysis. The means of each test specimen were submitted to the Kolmogorov-Smirnov test (p > 0.05, ANOVA and Tukey test (p < 0.05. With regard to hardness (F = 86.74, p < 0.0001 the analysis showed significant differences among the resin composite brands. But aging did not influence the hardness of any of the resin composites (F = 0.39, p = 0.53. In this study, there was interaction between the resin composite brand and the aging factors (F = 4.51, p < 0.0002. It was concluded that notwithstanding the type of resin, AAA did not influence surface hardness. However, with regard to hardness there was a significant difference among the resin brands.

  1. Effect of UV and electrochemical surface treatments on the adsorption and reaction of linear alcohols on non-porous carbon fibre

    Science.gov (United States)

    Osbeck, S.; Ward, S.; Idriss, H.

    2013-04-01

    The adsorption properties of untreated, electrochemically treated and ultra-violet/ozone treated polyacrylonitrile based carbon fibres were investigated using temperature programmed desorption (TPD) on a series of linear alcohols as probes in order to understand its surface properties. Surface uptake was found to be sensitive to both the surface treatment and the nature of the adsorbates. Surface coverage increased with increasing alcohol chain due to the increase in their polarizability. It also increased with the level of surface oxygen of the fibres most likely because it facilitates the Osbnd H bond dissociation of the alcohol functional group. In addition, the desorption temperature (during TPD) tracked the surface oxygen levels (as determined from XPS O1s signal) suggesting increasing in the adsorption energy. The reactions of C1-C4 linear alcohols were also investigated on the surface of the fibre carbon. The main reaction was dehydrogenation to the corresponding aldehydes; the dehydration reaction to olefins was not observed. The dehydrogenation reaction was sensitive to the length of the alky chain. It was highest for methanol (to formaldehyde) and decreased with increasing the carbon number. Overall TPD of linear alcohols was shown to be a promising method for quantifying the level and strength of bonding occurring on carbon fibre surfaces.

  2. White Layer of Hard Turned Surface by Sharp CBN Tool

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xue-ping; SONG He-chuan; C.Richard Liu

    2005-01-01

    White layers in hard turned surfaces were identified and measured as a function of turning parameters based on the Taguchi method. It reveals that white layers generate on the machine surface in the absence of tool flank wear, and white layer depth varies with the different combinations of hard turning parameters. Turning speed has the most important impact on white layer depth, feed rate follows, and cutting depth at last. The white layer generation consequently suggests a strong couple relation to the heat generation and thermal process of hard turning operation. White layer disappears under an optimal combination of turning parameters by Taguchi method. It suggests that a superior surface integrity without white layer is feasible under some selected combinations of turning parameters by a sharp CBN cutting tool.

  3. Photodetachment of H- near a Hard Spherical Surface

    Institute of Scientific and Technical Information of China (English)

    M. Haneef; Iftikhar Ahmad; A. Afaq; A. Rahman

    2012-01-01

    The photodetachment of a hydrogen negative ion (H- ) near a hard spherical surface is investigated by using the theoretical imaging method. The surface is oriented in such a fashion that the laser polarization direction is perpendicular to the principal axis of the spherical surface. Analytical expressions are derived for the detached-electron flux and photodetachment cross section. Strong interference patterns are observed in the detached-electron flux, while no visible oscillations are found in the photodetachment cross section.%The photodetachment of a hydrogen negative ion (H-) near a hard spherical surface is investigated by using the theoretical imaging method.The surface is oriented in such a fashion that the laser polarization direction is perpendicular to the principal axis of the spherical surface.Analytical expressions are derived for the detachedelectron flux and photodetachment cross section.Strong interference patterns are observed in the detachedelectron flux,while no visible oscillations are found in the photodetachment cross section.

  4. Nano-Bio Interactions of Porous and Nonporous Silica Nanoparticles of Varied Surface Chemistry: A Structural, Kinetic, and Thermodynamic Study of Protein Adsorption from RPMI Culture Medium.

    Science.gov (United States)

    Lehman, Sean E; Mudunkotuwa, Imali A; Grassian, Vicki H; Larsen, Sarah C

    2016-01-26

    Understanding complex chemical changes that take place at nano-bio interfaces is of great concern for being able to sustainably implement nanomaterials in key applications such as drug delivery, imaging, and environmental remediation. Typical in vitro assays use cell viability as a proxy to understanding nanotoxicity but often neglect how the nanomaterial surface can be altered by adsorption of solution-phase components in the medium. Protein coronas form on the nanomaterial surface when incubated in proteinaceous solutions. Herein, we apply a broad array of techniques to characterize and quantify protein corona formation on silica nanoparticle surfaces. The porosity and surface chemistry of the silica nanoparticles have been systematically varied. Using spectroscopic tools such as FTIR and circular dichroism, structural changes and kinetic processes involved in protein adsorption were evaluated. Additionally, by implementing thermogravimetric analysis, quantitative protein adsorption measurements allowed for the direct comparison between samples. Taken together, these measurements enabled the extraction of useful chemical information on protein binding onto nanoparticles in solution. Overall, we demonstrate that small alkylamines can increase protein adsorption and that even large polymeric molecules such as poly(ethylene glycol) (PEG) cannot prevent protein adsorption in these systems. The implications of these results as they relate to further understanding nano-bio interactions are discussed.

  5. Surface Integrity in Turning of Annealed Brass: Hardness Prediction

    Science.gov (United States)

    Zurita, O.; Di Graci, V.

    2012-07-01

    The purpose of this study was to obtain a comprehensive understanding of the effects of cutting parameters (depth of cut, feed rate, and cutting speed) on the surface integrity of, in terms of superficial hardening, annealed brass during a turning process. The results indicate that no significant phase transformations occurred for any of the turning conditions evaluated; however, microstructural changes were observed, as well as changes in the superficial hardness were measured. It was found that when the studied cutting parameters increase, the superficial hardness increases, with the cutting speed having less influence (2.56%), and feed rate having the greatest effect (22.67%). Finally, a mathematical expression is proposed, which relates the cutting parameters to the maximum hardness obtained for a given cutting condition.

  6. Surface Hardness of Friction Stir Welded AA6063 Pipe

    OpenAIRE

    Ismail Azman; Awang Mokhtar

    2014-01-01

    The external surface hardness of friction stir welded aluminum alloy 6063 pipe joint was investigated in this paper. The 89mm of outside diameter pipe with 5mm of wall thickness was used as test pipe piece for this experiment on closed butt joint configuration by utilising Bridgeport 2216 CNC milling machine and orbital clamping unit specially designed to cater for this task and function. Several welded samples were produced on varying process parameters which were successfully joined by usin...

  7. Removal of lead contaminated dusts from hard surfaces.

    Science.gov (United States)

    Lewis, Roger D; Condoor, Sridhar; Batek, Joe; Ong, Kee Hean; Backer, Denis; Sterling, David; Siria, Jeff; Chen, John J; Ashley, Peter

    2006-01-15

    Government guidelines have widely recommended trisodium phosphate (TSP) or "lead-specific" cleaning detergents for removal of lead-contaminated dust (LCD) from hard surfaces, such as floors and window areas. The purpose of this study was to determine if low-phosphate, non-lead-specific cleaners could be used to efficiently remove LCD from 3 types of surfaces (vinyl flooring, wood, and wallpaper). Laboratory methods were developed and validated for simulating the doping, embedding, and sponge cleaning of the 3 surface types with 4 categories of cleaners: lead-specific detergents, nonionic cleaners, anionic cleaners, and trisodium phosphate (TSP). Vinyl flooring and wood were worn using artificial means. Materials were ashed, followed by ultrasound extraction, and anodic stripping voltammetry (ASV). One-way analysis of variance approach was used to evaluate the surface and detergent effects. Surface type was found to be a significant factor in removal of lead (p < 0.001). Vinyl flooring cleaned better than wallpaper by over 14% and wood cleaned better than wallpaper by 13%. There was no difference between the cleaning action of vinyl flooring and wood. No evidence was found to support the use of TSP or lead-specific detergents over all-purpose cleaning detergents for removal of lead-contaminated dusts. No-phosphate, non-lead-specific detergents are effective in sponge cleaning of lead-contaminated hard surfaces and childhood lead prevention programs should consider recommending all-purpose household detergents for removal of lead-contaminated dust after appropriate vacuuming.

  8. Studying Polymer Transport on Soft and Hard Surfaces

    Science.gov (United States)

    Kumar, Sanat

    2007-03-01

    We have employed experiments and simulations to understand the factors controlling the transport of polymers on surfaces. From an experimental viewpoint we have focused on the transport of DNA (single stranded) on lipid bilayers. We show that this behavior is slaved to the mobility of the lipids. More surprisingly, it appears that the transport of molecules adsorbed on surfaces follows the same dependence on lipid mobility as for molecules incorporated into the lipid layer. The ability to control this surface diffusion through the introduction of posts or varying the strength of adsorption (by the use of an AC field normal to the surfaces) will also be studied. Theoretically we have used molecular dynamics simulations of a polymer chain of length N dissolved in explicit solvent and adsorbed as a pancake at the solid-liquid interface to discriminate between respective influences on surface diffusion of hydrodynamics and adsorption energetics. Only for analytically-smooth surfaces do we observe a strong influence of hydrodynamics; the polymer lateral diffusion constant, D, scales as D 1/N^3/4, more weakly than for implicit solvent. For atomistic surface corrugation with uniform surface chemical makeup, D 1/N instead. This suggests that while we can understand the results for diffusion on lipid surfaces, more recent experimental observations of stronger N dependence for diffusion on hard solid surfaces originate not in hydrodynamic interactions but in spatially patchy energetic interactions.

  9. Optimization of surface integrity in dry hard turning using RSM

    Indian Academy of Sciences (India)

    Suha K Shihab; Zahid A Khan; Aas Mohammad; Arshad Noor Siddiquee

    2014-10-01

    This paper investigates the effect of different cutting parameters (cutting speed, feed rate, and depth of cut) on surface integrity defined in terms of surface roughness and microhardness in dry hard turning process. The workpiece material used was hardened alloy steel AISI 52100 and it was machined on a CNC lathe with coated carbide tool under different settings of cutting parameters. Three cutting parameters each at three levels were considered in the study. Central composite design (CCD) of experiment was used to collect experimental data for surface roughness and microhardness. Statistical analysis of variance (ANOVA) was performed to determine significance of the cutting parameters. The results were analysed using an effective procedure of response surface methodology (RSM) to determine optimal values of cutting parameters. Several diagnostic tests were also performed to check the validity of assumptions. The results indicated that feed rate is the dominant factor affecting the surface roughness whereas the cutting speed is found to be the dominant factor affecting the microhardness. Results also revealed that within the range investigated, good surface integrity is achieved when feed rate and depth of cut are near their low levels and cutting speed is at high level. Finally, the optimal cutting parameters and model equations to predict the surface roughness and microhardness are proposed.

  10. Effects of home bleaching on surface hardness and surface roughness of an experimental nanocomposite

    Science.gov (United States)

    Zuryati, Ab-Ghani; Qian, Ooi Qian; Dasmawati, Mohamad

    2013-01-01

    Objective: Home bleaching agents may not be safe for composite resins. The purpose of this study was to evaluate the effects of 10 and 20% Opalescence® PF home bleaching agents on the surface roughness and hardness of universal nanocomposite (Filtek Z350), anterior nanocomposite (KeLFiL), and nanohybrid composite (TPH 3). Materials and Methods: Fifty-four composite resin samples with 18 samples for each type of composite resin were prepared using acrylic molds (4 × 2 mm). Each type of composite resin was further divided into three groups [n = 6 controls were placed in distilled water for 14 days and the other two groups of n = 6 were bleached with 10 and 20% carbamide peroxide (CP), respectively for 14 days]. Surface hardness of the composite resin was tested with a Vickers hardness tester, whereas surface roughness was tested with atomic force microscopy (AFM). Results: There were significant changes in the surface hardness of KeLFiL and TPH 3. However, all the tested materials showed no significant changes in the surface roughness. Conclusion: After 14 days of home bleaching treatment, there was no adverse effect on the surface roughness of all three composite resins, although the surface hardness for KeLFiL and TPH 3 were significantly reduced. PMID:23956541

  11. Effects of home bleaching on surface hardness and surface roughness of an experimental nanocomposite

    Directory of Open Access Journals (Sweden)

    Ab-Ghani Zuryati

    2013-01-01

    Full Text Available Objective: Home bleaching agents may not be safe for composite resins. The purpose of this study was to evaluate the effects of 10 and 20% Opalescence ® PF home bleaching agents on the surface roughness and hardness of universal nanocomposite (Filtek Z350, anterior nanocomposite (KeLFiL, and nanohybrid composite (TPH 3. Materials and Methods: Fifty-four composite resin samples with 18 samples for each type of composite resin were prepared using acrylic molds (4 × 2 mm. Each type of composite resin was further divided into three groups [n = 6 controls were placed in distilled water for 14 days and the other two groups of n = 6 were bleached with 10 and 20% carbamide peroxide (CP, respectively for 14 days]. Surface hardness of the composite resin was tested with a Vickers hardness tester, whereas surface roughness was tested with atomic force microscopy (AFM. Results: There were significant changes in the surface hardness of KeLFiL and TPH 3. However, all the tested materials showed no significant changes in the surface roughness. Conclusion: After 14 days of home bleaching treatment, there was no adverse effect on the surface roughness of all three composite resins, although the surface hardness for KeLFiL and TPH 3 were significantly reduced.

  12. Comparison of time-dependent changes in the surface hardness of different composite resins

    OpenAIRE

    Ozcan, Suat; Yikilgan, Ihsan; Uctasli, Mine Betul; Bala, Oya; Kurklu, Zeliha Gonca Bek

    2013-01-01

    Objective: The aim of this study was to evaluate the change in surface hardness of silorane-based composite resin (Filtek Silorane) in time and compare the results with the surface hardness of two methacrylate-based resins (Filtek Supreme and Majesty Posterior). Materials and Methods: From each composite material, 18 wheel-shaped samples (5-mm diameter and 2-mm depth) were prepared. Top and bottom surface hardness of these samples was measured using a Vicker's hardness tester. The samples wer...

  13. [Physicochemical fundamentals on the cleaning of hard surfaces (author's transl)].

    Science.gov (United States)

    Schwuger, M J; Kurzendörfer, C P

    1979-03-01

    The primary process in the cleaning of hard surfaces is the adsorption of the active substance of the detergent at the interfaces: liquid/gas, liquid/liquid, liquid/solid. This primary step in the cleaning process induces secondary processes which in turn are responsible for the soil removal from the surface of the substrate. The first requirement for a cleaning effect is that the dirt and the substrate be well wetted by the cleaning solution as a result of a reduction in surface tension and of the adsorption at the solid/liquid interface. The further secondary processes which effect the removal of dirt vary considerably, depending on the type of dirt (e.g. oils, pigments). In the case of oily and greasy dirt, rolling-up penetration, formation of mixed phases, emulsification and solubilization are of importance. For pigments, the surface pressure of the adsorption layer and the electrostatic repulsion are the determining factors. The processes of pigment dispersion, emulsification and solubilization are, in addition, extremely important for the stabilization of the dirty wash bath and the prevention of deposits on the substrate. The essential active substances of the detergents are surfactant and complexing agents, the first being unspecifically adsorbed by hydrophobic interactions, and the latter specifically by polar interactions. They influence one another mutually and are responsible for an optimal cleaning effect when they occur in suitable mixing ratios; the special constitutional characteristics of the individual surfactant and complexing agents, must also be considered.

  14. Surface Hardness of Resin Cement Polymerized under Different Ceramic Materials

    Directory of Open Access Journals (Sweden)

    Pimmada Kesrak

    2012-01-01

    Full Text Available Objectives. To evaluate the surface hardness of two light-cured resin cements polymerized under different ceramic discs. Methods. 40 experimental groups of 2 light-cured resin cement specimens (Variolink Veneer and NX3 were prepared and polymerized under 5 different ceramic discs (IPS e.max Press HT, LT, MO, HO, and Cercon of 4 thicknesses (0.5, 1.0, 1.5, and 2.0 mm, Those directly activated of both resin cements were used as control. After light activation and 37∘C storage in an incubator, Knoop hardness measurements were obtained at the bottom. The data were analyzed with three-way ANOVA, t-test, and one-way ANOVA. Results. The KHN of NX3 was of significantly higher than that of Variolink Veneer (<0.05. The KHN of resin cement polymerized under different ceramic types and thicknesses was significant difference (<0.05. Conclusion. Resin cements polymerized under different ceramic materials and thicknesses showed statistically significant differences in KHN.

  15. Surface hardness behaviour of Ti–Al–Mo alloys

    Indian Academy of Sciences (India)

    Raja Ram Prasad; Shankar Azad; A K Singh; R K Mandal

    2008-08-01

    The microhardness characteristics of various micro-constituents formed in the Ti–Al–Mo alloys have been investigated. Four alloys having compositions, Ti–40Al–2Mo, Ti–42Al–2Mo, Ti–40Al–6Mo and Ti–42Al–6Mo, have been chosen for this purpose. All of these were heat treated at 1300°C and 1400°C for 1 h and water quenched. All the specimens after above heat treatments have displayed load independent Vickers hardness values (VHN) around 300 g of applied load. The average surface hardness characteristic of the alloys is largely found to be dictated by the phases that are present. The microstructural specific VHN values vary between 600 and 750. The indentation behaviour, however, is governed by the morphologies and length scales of microstructures. The most remarkable finding of the present study pertains to the formation of shear bands around the periphery of the indenter for a finer basket weave microstructure in the Ti–40Al–2Mo. The cluster of finely located slip steps was clearly seen. Such a report is lacking in literature in this class of alloys.

  16. Composition and method for cleaning hydrocarbon oil from hard surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Blezard, M.; Mcallister, W.H.

    1983-09-28

    Hydrocarbon oils are cleaned from hard, inorganic surfaces by the application of an aqueous solution, such as seawater, containing a mixture of alkoxylated alcohol, carboxylic acid, alkyl phenol, or nonionic phosphate ester, with an alkyl mono- or di-ethanolamide or an ethoxylated or polyethoxylated alkyl mono- or di-ethanolamide. The method is of particular value for cleaning drilling oil from rock cuttings in offshore drilling operations, such as cold North Sea installations. Specific examples are a C10 primary alcohol, which is ethoxylated with 5 moles of ethylene oxide, mixed with a coconut diethanolamide. Typically, the mixture is supplied as a concentrate which is dissolved in, or diluted with, water to provide the cleansing solution at the site of the rig. 21 claims.

  17. Sticking of molecules on non-porous amorphous water ice

    CERN Document Server

    He, Jiao; Vidali, Gianfranco

    2016-01-01

    Accurate modeling of physical and chemical processes in the interstellar medium requires detailed knowledge of how atoms and molecule adsorb on dust grains. However, the sticking coefficient, a number between 0 and 1 that measures the first step in the interaction of a particle with a surface, is usually assumed in simulations of ISM environments to be either 0.5 or 1. Here we report on the determination of the sticking coefficient of H$_2$, D$_2$, N$_2$, O$_2$, CO, CH$_4$, and CO$_2$ on non-porous amorphous solid water (np-ASW). The sticking coefficient was measured over a wide range of surface temperatures using a highly collimated molecular beam. We showed that the standard way of measuring the sticking coefficient --- the King-Wells method --- leads to the underestimation of trapping events in which there is incomplete energy accommodation of the molecule on the surface. Surface scattering experiments with the use of a pulsed molecular beam are used instead to measure the sticking coefficient. Based on th...

  18. Superhydrophobicity of Bionic Alumina Surfaces Fabricated by Hard Anodizing

    Institute of Scientific and Technical Information of China (English)

    Jing Li; Feng Du; Xianli Liu; Zhonghao Jiang; Luquan Ren

    2011-01-01

    Bionic alumina samples were fabricated on convex dome type aluminum alloy substrate using hard anodizing technique.The convex domes on the bionic sample were fabricated by compression molding under a compressive stress of 92.5 MPa.The water contact angles of the as-anodized bionic samples were measured using a contact angle meter (JC2000A) with the 3 μL water drop at room temperature.The measurement of the wetting property showed that the water contact angle of the unmodified as-anodized bionic alumina samples increases from 90° to 137° with the anodizing time.The increase in water contract angle with anodizing time arises from the gradual formation of hierarchical structure or composite structure.The structure is composed of the micro-scaled alumina columns and pores.The height of columns and the depth of pores depend on the anodizing time.The water contact angle increases significantly from 96° to 152° when the samples were modified with self-assembled monolayer of octadecanethiol (ODT),showing a change in the wettability from hydrophobicity to super-hydrophobicity.This improvement in the wetting property is attributed to the decrease in the surface energy caused by the chemical modification.

  19. Comparison of time-dependent changes in the surface hardness of different composite resins

    Science.gov (United States)

    Ozcan, Suat; Yikilgan, Ihsan; Uctasli, Mine Betul; Bala, Oya; Kurklu, Zeliha Gonca Bek

    2013-01-01

    Objective: The aim of this study was to evaluate the change in surface hardness of silorane-based composite resin (Filtek Silorane) in time and compare the results with the surface hardness of two methacrylate-based resins (Filtek Supreme and Majesty Posterior). Materials and Methods: From each composite material, 18 wheel-shaped samples (5-mm diameter and 2-mm depth) were prepared. Top and bottom surface hardness of these samples was measured using a Vicker's hardness tester. The samples were then stored at 37°C and 100% humidity. After 24 h and 7, 30 and 90 days, the top and bottom surface hardness of the samples was measured. In each measurement, the rate between the hardness of the top and bottom surfaces were recorded as the hardness rate. Statistical analysis was performed by one-way analysis of variance, multiple comparisons by Tukey's test and binary comparisons by t-test with a significance level of P = 0.05. Results: The highest hardness values were obtained from each two surfaces of Majesty Posterior and the lowest from Filtek Silorane. Both the top and bottom surface hardness of the methacrylate based composite resins was high and there was a statistically significant difference between the top and bottom hardness values of only the silorane-based composite, Filtek Silorane (P < 0.05). The lowest was obtained with Filtek Silorane. The hardness values of all test groups increased after 24 h (P < 0.05). Conclusion: Although silorane-based composite resin Filtek Silorane showed adequate hardness ratio, the use of incremental technic during application is more important than methacrylate based composites. PMID:24966724

  20. Preparation of A-type zeolite membranes on nonporous metal supports by using electrophoretic technique

    Institute of Scientific and Technical Information of China (English)

    HUANG Aisheng; LIU Jie; LI Yanshuo; LIN Yuesheng; YANG Weishen

    2004-01-01

    A-type zeolite membranes were prepared onthe nonporous metal supports by using electrophoretic tech-nique. The as-synthesized membranes were characterized byXRD and SEM. The effect of the applied potential on theformation of the A-type zeolite membrane was investigated,and the formation mechanism of zeolite membrane in theelectric field was discussed. The results showed that thenegative charged zeolite particles could migrate to the anodemetal surface homogenously and rapidly under the action ofthe applied electric field, consequently formed uniform anddense membranes in short time. The applied potential hadgreat effect on the membrane formation, and more uniformand denser zeolite membranes were prepared on the non-porous metal supports with 1 V potential.

  1. Transfer efficiency of bacteria and viruses from porous and nonporous fomites to fingers under different relative humidity conditions.

    Science.gov (United States)

    Lopez, Gerardo U; Gerba, Charles P; Tamimi, Akrum H; Kitajima, Masaaki; Maxwell, Sheri L; Rose, Joan B

    2013-09-01

    Fomites can serve as routes of transmission for both enteric and respiratory pathogens. The present study examined the effect of low and high relative humidity on fomite-to-finger transfer efficiency of five model organisms from several common inanimate surfaces (fomites). Nine fomites representing porous and nonporous surfaces of different compositions were studied. Escherichia coli, Staphylococcus aureus, Bacillus thuringiensis, MS2 coliphage, and poliovirus 1 were placed on fomites in 10-μl drops and allowed to dry for 30 min under low (15% to 32%) or high (40% to 65%) relative humidity. Fomite-to-finger transfers were performed using 1.0 kg/cm(2) of pressure for 10 s. Transfer efficiencies were greater under high relative humidity for both porous and nonporous surfaces. Most organisms on average had greater transfer efficiencies under high relative humidity than under low relative humidity. Nonporous surfaces had a greater transfer efficiency (up to 57%) than porous surfaces (<6.8%) under low relative humidity, as well as under high relative humidity (nonporous, up to 79.5%; porous, <13.4%). Transfer efficiency also varied with fomite material and organism type. The data generated can be used in quantitative microbial risk assessment models to assess the risk of infection from fomite-transmitted human pathogens and the relative levels of exposure to different types of fomites and microorganisms.

  2. Under-surface hardness of light-cured nanofilled resin composites of different shades

    Science.gov (United States)

    Ramanitya, A.; Indrani, D. J.; Herda, E.

    2017-08-01

    The objective of the this study was to analyze the under-surface hardness of light-cured nanofilled composite resins of different shades. The specimens were resin composites of each light (B1), medium (A3), and dark (C3) shades packed in a cylinder mold and subsequently polymerized. The hardness was tested using a Knoop system. The hardness test results for the bright (B1), medium (A3), and dark (C3) shades were 82.4+1.1, 75.9+1.2 and 65.9+1.9, respectively, and indicated significant differences between the under-surface hardness of each shade. It was concluded that resin composites of darker to brigher shades demonstrated lower to higher under-surface hardness.

  3. Hard Surface Layers by Pack Boriding and Gaseous Thermo-Reactive Deposition and Diffusion Treatments

    DEFF Research Database (Denmark)

    Christiansen, Thomas Lundin; Bottoli, Federico; Dahl, Kristian Vinter

    2017-01-01

    subjected to TRD (chromizing and titanizing) and boriding treatments. For the steels with low carbon content, chromizing results in surface alloying with chromium, i.e., formation of a (soft) “stainless” surface zone. Steels containing higher levels of carbon form chromium carbide (viz. Cr23C6, Cr7C3......) layers with hardnesses up to 1800 HV. Titanizing of ARNE tool steel results in a surface layer consisting of TiC with a hardness of approximately 4000 HV. Duplex treatments, where boriding is combined with subsequent (TRD) titanizing, result in formation of hard TiB2 on top of a thick layer of Fe...

  4. Effects of home bleaching on surface hardness and surface roughness of an experimental nanocomposite

    OpenAIRE

    Ab-Ghani Zuryati; Ooi Qian Qian; Mohamad Dasmawati

    2013-01-01

    Objective: Home bleaching agents may not be safe for composite resins. The purpose of this study was to evaluate the effects of 10 and 20% Opalescence ® PF home bleaching agents on the surface roughness and hardness of universal nanocomposite (Filtek Z350), anterior nanocomposite (KeLFiL), and nanohybrid composite (TPH 3). Materials and Methods: Fifty-four composite resin samples with 18 samples for each type of composite resin were prepared using acrylic molds (4 × 2 mm). Each type of co...

  5. Improvement of hardness of aluminium AA1200 by laser surface alloying

    CSIR Research Space (South Africa)

    Mabhali, Luyolo AB

    2010-07-01

    Full Text Available Aluminium is vastly used in industry due to its low cost, light weight and excellent workability, but lacks in wear resistance and hardness. Laser alloying is used to improve the surface properties such as hardness by modifying the composition...

  6. Density functional theory of liquid crystals and surface anchoring: hard Gaussian overlap-sphere and hard Gaussian overlap-surface potentials.

    Science.gov (United States)

    Avazpour, A; Avazpour, L

    2010-12-28

    This article applies the density functional theory to confined liquid crystals, comprised of ellipsoidal shaped particles interacting through the hard Gaussian overlap (HGO) potential. The extended restricted orientation model proposed by Moradi and co-workers [J. Phys.: Condens. Matter 17, 5625 (2005)] is used to study the surface anchoring. The excess free energy is calculated as a functional expansion of density around a reference homogeneous fluid. The pair direct correlation function (DCF) of a homogeneous HGO fluid is approximated, based on the optimized sum of Percus-Yevick and Roth DCF for hard spheres; the anisotropy introduced by means of the closest approach parameter, the expression proposed by Marko [Physica B 392, 242 (2007)] for DCF of HGO, and hard ellipsoids were used. In this study we extend an our previous work [Phys. Rev. E 72, 061706 (2005)] on the anchoring behavior of hard particle liquid crystal model, by studying the effect of changing the particle-substrate contact function instead of hard needle-wall potentials. We use the two particle-surface potentials: the HGO-sphere and the HGO-surface potentials. The average number density and order parameter profiles of a confined HGO fluid are obtained using the two particle-wall potentials. For bulk isotropic liquid, the results are in agreement with the Monte Carlo simulation of Barmes and Cleaver [Phys. Rev. E 71, 021705 (2005)]. Also, for the bulk nematic phase, the theory gives the correct density profile and order parameter between the walls.

  7. Surface hardness of different restorative materials after long-term immersion in sports and energy drinks.

    Science.gov (United States)

    Erdemir, Ugur; Yildiz, Esra; Eren, Meltem Mert; Ozel, Sevda

    2012-01-01

    The purpose of this study was to evaluate the effect of sports and energy drinks on the surface hardness of different restorative materials over a 6-month period. Forty-two disk-shaped specimens were prepared for each of the four restorative materials tested: Compoglass F, Filtek Z250, Filtek Supreme, and Premise. Specimens were immersed for 2 min daily, up to 6 months, in six storage solutions (n=7 per material for each solution): distilled water, Powerade, Gatorade, X-IR, Burn, and Red Bull. Surface hardness was measured at baseline, after 1 week, 1 month, and 6 months. Data were analyzed statistically using repeated measures ANOVA followed by the Bonferroni test for multiple comparisons (α=0.05). Surface hardness of the restorative materials was significantly affected by both immersion solution and immersion period (p<0.001). All tested solutions induced significant reduction in surface hardness of the restorative materials over a 6-month immersion period.

  8. Effect of plasma nitriding time on surface properties of hard chromium electroplated AISI 1010 steel

    Energy Technology Data Exchange (ETDEWEB)

    Kocabas, Mustafa [Yildiz Technical Univ., Istanbul (Turkey). Metallurgical and Materials Engineering Dept.; Danisman, Murat [Gedik Univ., Istanbul (Turkey). Electrical and Electronic Engineering Dept.; Cansever, Nurhan [Yildiz Technical Univ., Istanbul (Turkey); Uelker, Suekrue [Afyon Kocatepe Univ. (Turkey). Dept. of Mechanical Engineering

    2015-06-01

    Properties of steel can be enhanced by surface treatments such as coating. In some cases, further treatments such as nitriding can also be used in order to get even better results. In order to investigate the properties of nitride layer on hard Cr coated AISI 1010 steel, substrates were electroplated to form hard Cr coatings. Then hard Cr coatings were plasma nitrided at 700 C for 3 h, 5 h and 7 h and nitride phases on the coatings were investigated by X-ray diffraction analysis. The layer thickness and surface properties of nitride films were investigated by scanning electron microscopy. The hardness and adhesion properties of Cr-N phases were examined using nano indentation and Daimler-Benz Rockwell C adhesion tests. The highest measured hardness was 24.1 GPa and all the three samples exhibited poor adhesion.

  9. Comparative Evaluation of Quantitative Test Methods for Gases on a Hard Surface

    Science.gov (United States)

    2017-02-01

    COMPARATIVE EVALUATION OF QUANTITATIVE TEST METHODS FOR GASES ON A HARD SURFACE ECBC-TR-1426 Vipin Rastogi... Quantitative Test Methods for Gases on a Hard Surface 5a. CONTRACT NUMBER IAG DW-21-83021801-2 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S...ABSTRACT: In this study, two quantitative test methods were evaluated (the Three Step Method [TSM] and the Quantitative Disk Carrier Test [QCT]) for

  10. An investigation into the effects of hard turning surface integrity on component service life

    Science.gov (United States)

    Smith, Stephen Ray

    Hard machining is the machining of materials at 45 HRC or greater. Recent improvements in machine tools and tool material have made hard machining a viable option. In order for hard machining to gain acceptance, it must be shown that as a finishing process, it will provide surfaces that meet the same quality standards as grinding. This research addressed the relationship between surface integrity generated by finishing processes and component service life. Fatigue and wear testing were utilized to determine the impact of hard turning as compared to the traditional finishing process of grinding. Test specimens were generated under controlled manufacturing processes and included five distinct surface conditions: hard turned with continuous white layer on the surface, hard turned with no white layer, ground, and hard turned and ground specimens subsequently superfinished. Extensive fatigue and wear testing was conducted to determine the performance of each surface condition relative to the other conditions. The surface integrity of each surface condition was thoroughly characterized through surface topography mapping, metallographic inspection, residual stress measurement, TEM analysis, and nanoindentation hardness measurements. The most significant conclusions were that the presence of white layers generated using new tooling did not affect the fatigue life or wear characteristics of the specimens. In fact, the physical evidence resulting from this investigation suggests that under controlled conditions (i.e. limited tool wear), the white layer is nothing more than an artifact resulting from the manufacturing process and does not contribute to the service life of the specimen. While the phase and crystallographic structure of the white layer is identical to the bulk material, the grains within the white layer have undergone significant grain refinement and the white layer is harder. Experiments were conducted that demonstrated that the physical characteristics of

  11. Microstructural and hardness gradients in Cu processed by high pressure surface rolling

    DEFF Research Database (Denmark)

    He, Q. Y.; Zhu, X.-M.; Mei, Q. S.

    2017-01-01

    in the topmost surface to the microscale in the bulk. The hardness varies from 1.37 GPa at the topmost surface to about 0.6 GPa in the coarse-grained matrix. The results of the investigation demonstrate that the HPSR process shows good potential for the generation of thick gradient microstructures on the surface...

  12. Microstructural and Hardness Study of Pulsed Nd:YAG Laser Surface Alloyed Aluminum with Iron

    Science.gov (United States)

    Ansari, Mohammad; Soltani, Reza; Heydarzadeh Sohi, Mahmoud; Valefi, Zia

    2016-04-01

    In the present study, the feasibility of the formation of surface layers containing hard iron aluminides on AA6061-T6 aluminum via pre-plasma spraying with iron and subsequently double surface melting by pulsed Nd:YAG laser is studied. The effects of single and double laser surface melting on microstructure, phase formation, and hardness of the treated layers are examined. Single-step laser treatment resulted in the presence of undissolved iron particles surrounded by lump-like Al5Fe2 and needle-like Al3Fe intermetallic compounds. Double laser surface melting dissolved the retained undissolved irons and resulted in the formation of Al-Al3Fe eutectic structure. Microhardness profiles along cross section and top surface of the treated layers indicated that laser surface alloying with iron enhanced the hardness of the aluminum to more than twice of that of the base material.

  13. Effect of surfactant on surface hardness of dental stone and investment casts produced from polyvinyl siloxane duplicating materials.

    Science.gov (United States)

    Al-Johani, Attalah; Clark, Robert K F; Juszczyk, Andrzej S; Radford, David R

    2008-06-01

    Polyvinylsiloxane duplicating materials are typically treated with a topical surfactant before pouring dental models, but the use of topical surfactants in the dental laboratory may affect the surface hardness of the resultant models. The effect of two different topical surfactants on surface hardness of two dental stones (FujiRock and Dentstone) and one phosphate bonded investment material (Croform WB) produced from polyvinyl siloxane (PVS) dental laboratory duplicating moulds was investigated. Topical surfactants affected the surface hardness of FujiRock, Dentstone and Croform WB investment material. Surface hardness of FujiRock increased with Wax-Mate surfactant. However, surface hardness of Croform WB investment material decreased with both topical surfactants.

  14. Evaluation of the Various Drying Methods on Surface Hardness of Type IV Dental Stone

    Science.gov (United States)

    Sudhakar, A; Srivatsa, G; Shetty, Rohit; Rajeswari, C L; Manvi, Supriya

    2015-01-01

    Background: Studies regarding the effect of various methods to increase the surface hardness of Type IV dental stone are not conclusive. Therefore, this study was carried out to evaluate the effect of air drying, micro oven drying and die hardener on surface hardness of Type IV dental stone. Materials and Methods: A standard metal die was fabricated; polyvinyl siloxane impression material was used to make the molds of metal die. A total of 120 specimens were obtained from two different die stones and were grouped as Group A (kalrock) and Group B (pearl stone), and were subjected to air drying for 24 h, micro oven drying and application of die hardener. These models were then subjected to surface hardness testing using the knoop hardness instrument. The obtained data were subjected to statistical analysis. Results: The hardness of Group A specimens was 64 ± 0.54 Knoop hardness number (KHN) after application of die hardener, 60.47 ± 0.41 KHN after 24 h air drying, 58.2 ± 0.88 after microwave oven drying and 24.6 ± 0.4 after 1 h air drying. The hardness of Group B specimens was 45.59 ± 0.63 KHN after application of die hardener, 40.2 ± 0.63 KHN after 24 h air drying, 38.28 ± 0.55 KHN after microwave oven drying and 19.91 ± 0.64 KHN after 1 h air drying. Conclusion: Group A showed better results than Group B at all times. Application of the die hardener showed highest hardness values followed in the order by 24 h air drying, microwave oven drying and 1 h air drying in both groups. The study showed that air drying the dies for 24 h followed by application of a single layer of the die hardener produced the best surface hardness and is recommended to be followed in practice. PMID:26124610

  15. Effect of radiant heat on the surface hardness of glass polyalkenoate (ionomer) cement.

    Science.gov (United States)

    Woolford, M J

    1994-12-01

    The use of heat to improve mechanical properties of materials is a widely accepted phenomenon. It has been studied in dentistry with a view to improving the properties of resin composite. Dental cements may benefit by the application of heat, in particular with regard to their early surface properties. This study was carried out to examine the effect of the application of radiant heat to the surface hardness of one type of glass polyalkenoate cement. It was found that raising the temperature of the surface of the cement to a maximum of 60 degrees C significantly improved the early surface hardness of the material. The application of a high level of heat also improved the surface hardness of the cement after 24 h compared to cement which had not been heat treated. The use of heat would appear to accelerate the matrix-forming reaction of the material and although further work is necessary this technique may have clinical application.

  16. Surface hardness changes induced by O-, Ca- or P-ion implantation into titanium.

    Science.gov (United States)

    Ikeyama; Nakao; Morikawa; Yokogawa; Wielunski; Clissold; Bell

    2000-12-30

    Titanium or titanium alloys are very attractive biomedical materials. Biocompatible elements of oxygen, calcium and phosphorus were implanted into titanium and changes of surface hardness were measured using an ultra micro indenter (UMIS-2000). A multiple load-partial unload procedure that can reveal a hardness versus depth profile was adopted. Depth profiles of concentration of implanted ions were obtained by SIMS measurement. For O and P implantation, it is observed that the hardness increases with the increases in the dose. O implantation produced the largest increase in hardness, up to 2.2 times higher than the unimplanted titanium. On the other hand, Ca implantation produced only a small increase in the hardness that was independent of the ion dose. The surface oxide layer of a Ca implanted titanium sample was much thicker than the unimplanted samples or those implanted with O and P ions. The depth of maximum hardness increases with increasing energy of implanted ions. The depths of the maximum hardness occur at indentation depths of one-third to one-eighth of the mean ranges of implanted ions.

  17. INFLUENCE OF CARBON CONTENT OF MARTENSITE STEELS ON HARDNESS RE-DISTRIBUTION NEAR WORN SURFACE

    Institute of Scientific and Technical Information of China (English)

    Y.P. Ma

    2002-01-01

    After three-body abrasion, the hardness re-distribution near the worn surface has aclose relationship with the carbon content of martensite steel. It is considered thatthere is a competition between the work-hardening and the temper softening, whichresults from deformation and friction heat of material. When the carbon content ofmartensite steel is below about 0.6%, the subsurface hardness distribution of materialis a softened layer sandwiched between two hardened layers, but above 0.6%C, nosoftened region appears on the hardness re-distribution curve.

  18. Surface properties of hard protective coatings studied by optical techniques

    Science.gov (United States)

    Jaglarz, Janusz; Wolska, N.; Mitura, K.; Duraj, R.; Marszalek, K. W.; El Kouari, Y.

    2016-06-01

    The paper describes optical study of SiC, C and NiC layers deposited on Si substrates by double beam ion sputtering (DBIS) method. The following optical methods: ellipsometry, bidirectional reflection distribution function (BRDF) and total integrated scattering (TIS) studies have been applied. The obtained results allowed us to determine the refractive indices, extinction coefficients and the roughness parameters of DBIS films. Also surface profiles of optical constants determined from scanning ellipsometric measurements have been presented. The power spectral density functions (PSD) of surface roughness for studied samples have been determined. The influence of the deposition technology on film topography has been discussed.

  19. Influence of Combined Hard and Fine Machining on the Surface Properties of Cemented Carbides

    Directory of Open Access Journals (Sweden)

    U. Engel

    2012-09-01

    Full Text Available As a result of recent developments in cold forging cemented carbides are increasingly used as tool materials. Due to their high hardness only electrical discharge machining (EDM and grinding are suitable for tool machining. The structure of tool surface has significant influence on dominating failure mechanisms wear and fatigue. For improvement of tribological conditions the surface is polished in a finale processing step. The result of hard and fine machining is a specific combination of coarse and fine structure which is determined by processing parameters. The different surface structures lead to a particular tool behavior in forming process. This paper aims to show the influence of combined hard and fine machining on the surface properties of cemented carbides.

  20. Microstructure and hardness of WC-Co particle reinforced iron matrix surface composite

    OpenAIRE

    Zhang Peng; Zeng Shaolian; Zhang Zhiguo

    2013-01-01

    In this study, a high Cr cast iron surface composite material reinforced with WC-Co particles 2-6 mm in size was prepared using a pressureless sand mold infiltration casting technique. The composition, microstructure and hardness were determined by means of energy dispersive spectrometry (EDS), electron probe microanalysis (EPMA), scanning electron microscope (SEM) and Rockwell hardness measurements. It is determined that the obtained composite layer is about 15 mm thick with a WC-Co particle...

  1. ANALYSIS OF SURFACE ROUGHNESS IN HARD TURNING BY USING TAGUCHI METHOD

    Directory of Open Access Journals (Sweden)

    DR.S.D.DESHMUKH

    2013-02-01

    Full Text Available Hard turning is defined as the turning of hardened ferrous metals with Rockwell-C hardness ratings ranging from 45 to 70. Hard turning has the potential to reduce production costs by replacing more costly and less agile grinding operations on hard materials especially in finishing processes (Konig et al., 1990. PCBN tools tend to be damaged more severely than conventional cutting tools of mild turning under vibrations because of their relatively brittle property. In addition, the finishing process, which is often involved with hard turning, has a much smaller tolerance of surface precision than other machining processes. This paper is focused on hard turning of 20 MnCr5 Steel. The purpose of this paper is to analyze optimum cutting conditions to get lowest surface roughness in turning of 20 MnCr5 Steel.Taguchi method has been used for this. An orthogonal array, the signal to noise ratio and analysis of variance (ANOVA are employed toinvestigate the cutting characteristics. The results indicate that feed rate has significant role to play in producing lower surface roughness followed by cutting speed. The cutting insert used is ceramic based TNGA 160404 .

  2. Effects of different solutions on the surface hardness of composite resin materials.

    Science.gov (United States)

    Yanikoğlu, Nuran; Duymuş, Zeynep Yeşil; Yilmaz, Baykal

    2009-05-01

    In this study, the surface hardness of five light-cured composite resins were evaluated, namely: filled (Estelite), nanofil (AElite), unfilled (Valux Plus), hybrid (Tetric ceram), and Ormocer-based (Admira) composite resins. The microhardness values of composite specimens were measured at the top and bottom surfaces after 24 hours or 30 days of immersion in different solutions (tea, coffee, Turkish coffee, mouthwash, cola, and distilled water). Comparisons were made with univariate analysis of variance and Duncan's multiple range test. It was found that rough specimens of reinforced nano-hybrid composite material immersed in cola for 30 days had the lowest surface hardness (33.20), whereas rough specimens of hybrid composite material immersed in cola for 24 hours had the highest surface hardness (156.00). In both tea and coffee, the top surfaces tended to be harder than the bottom ones. In conclusion, the five different materials exhibited different hardnesses, and that the hardness values of composite materials were statistically different in different immersion solutions.

  3. Surface Modification of Biomaterials in Hard Tissue Applications

    Institute of Scientific and Technical Information of China (English)

    LIU Xuan-yong; DING Chuan-xian; CHU Paul K

    2004-01-01

    Surface modification technologies are quite common in the biomedical field to improve the mechanical,chemical, physical and biological properties of implants such as artificial joint and cardiovascular devices. In this paper, recent progress in the investigation of the bioactivity and biocompatibility enhancement of implants using plasma spraying and plasmabased ion implantation (PIII) is described. Plasma sprayed hydroxyapatite (HA) coatings are commonly used as bioactive coatings but the relatively poor adhesion between the coatings and titanium is one of main disadvantages which have limited their biomedical applications. In our recent studies, novel bioactive coatings, such as wollastonite and dicalcium silicate, were deposited onto titanium to enhance the surfaces bioactivity and biocompatibility. Our results indicate that plasma sprayed wollastonite and dicalcium silicate coatings possess excellent bioactivity as well as relatively high bonding strength. Plasma immersion ion implantation was also employed to improve the anti-corrosion and biological properties of implants.

  4. Effect of radiotherapy on the hardness and surface roughness of two composite resins.

    Science.gov (United States)

    Viero, Flavio Luiz; Boscolo, Frab Norberto; Demarco, Flavio Fernando; Faot, Fernanda

    2011-01-01

    The knowledge about the potential adverse effects of radiotherapy compared to dental composites is a useful information for the clinician's decision regarding adoption of repairs or replacement of dental restorations during oral cancer treatment. This study evaluated the effects of irradiation on microhardness and surface roughness of a microfilled and a packable composite resin. The microfilled composite resin demonstrated significantly lower microhardness and a smoother surface compared to the packable composite resin (p composite resins (P surface hardness (P > 0.05). Meanwhile, irradiation did not produce a significantly rougher surface (P > 0.05), but specimens submitted to abrasion exhibited a significant increase in surface roughness for both composite resins (P hardness of tested composite resins, it does not interfere with surface roughness.

  5. Methods of improvement in hardness of composite surface layer on cast steel

    OpenAIRE

    J. Szajnar; P. Wróbel; T. Wróbel

    2008-01-01

    The paper presents a method of usable properties of surface layers improvement of cast carbon steel 200–450, by put directly in founding process a composite surface layer on the basis of Fe-Cr-C alloy and next its remelting with use of welding technology TIG – Tungsten Inert Gas. Technology of composite surface layer guarantee mainly increase in hardness and abrasive wear resistance of cast steel castings on machine elements. This technology can be competition for generally applied welding te...

  6. Enabling ultra high precision on hard steels using surface defect machining

    OpenAIRE

    2014-01-01

    This paper is an extension to an idea coined during the 13th EUSPEN Conference (P6.23) named "surface defect machining" (SDM). The objective of this work was to demonstrate how a conventional CNC turret lathe can be used to obtain ultra high precision machined surface finish on hard steels without recourse to a sophisticated ultra precision machine tool. An AISI 4340 hard steel (69 HRC) workpiece was machined using a CBN cutting tool with and without SDM. Post-machining measurements by a Form...

  7. Effects of TIG Surface Melting and Chromium Surface Alloying on Microstructure,Hardness and Wear Resistance of ADI

    Institute of Scientific and Technical Information of China (English)

    A Amirsadeghi; M Heydarzadeh Sohi; S F Kashani Bozorg

    2008-01-01

    Microhardness and wear resistance of different mierostruetures formed by TIG (tungsten inert gas) surface melting and chromium surface alloying (using ferrochromium) of ADI (austempered ductile iron) were studied.Surface melting resulted in the formation of a ledeburitic structure in the melted zone,and this structure has a hardness up to 896 HV as compared to 360 HV in that of ADI.Moreover,chromium surface alloying resulted in the formation of different structures including:(1) a hypereuteetic structure consisting of primary (Fe,Cr)7C3 carbides and a eutectie matrix of transformed austenite (into martensite and retained austenite),as also (Fe,Cr)7C3 carbides,with a hardness of 1 078 HV;(2) a hypoeutectic structure consisting of the same eutectic along with transformed primary austenite,with a hardness of 755 HV;and (3) a ledeburitic structure with an acieular morphology and a hardness of 896 HV.The results also indicated that surface melting reduced the wear rate of the ADI by approximately 37%.Also,chromium surface alloying yielded a superior wear behavior and reduced the wear rate of the treated specimens by about 38% and 70%,depending on the structures formed.

  8. Amine modification of nonporous silica nanoparticles reduces inflammatory response following intratracheal instillation in murine lungs.

    Science.gov (United States)

    Morris, Angie S; Adamcakova-Dodd, Andrea; Lehman, Sean E; Wongrakpanich, Amaraporn; Thorne, Peter S; Larsen, Sarah C; Salem, Aliasger K

    2016-01-22

    Amorphous silica nanoparticles (NPs) possess unique material properties that make them ideal for many different applications. However, the impact of these materials on human and environmental health needs to be established. We investigated nonporous silica NPs both bare and modified with amine functional groups (3-aminopropyltriethoxysilane (APTES)) in order to evaluate the effect of surface chemistry on biocompatibility. In vitro data showed there to be little to no cytotoxicity in a human lung cancer epithelial cell line (A549) for bare silica NPs and amine-functionalized NPs using doses based on both mass concentration (below 200μg/mL) and exposed total surface area (below 14m(2)/L). To assess lung inflammation, C57BL/6 mice were administered bare or amine-functionalized silica NPs via intra-tracheal instillation. Two doses (0.1 and 0.5mg NPs/mouse) were tested using the in vivo model. At the higher dose used, bare silica NPs elicited a significantly higher inflammatory response, as evidence by increased neutrophils and total protein in bronchoalveolar lavage (BAL) fluid compared to amine-functionalized NPs. From this study, we conclude that functionalization of nonporous silica NPs with APTES molecules reduces murine lung inflammation and improves the overall biocompatibility of the nanomaterial.

  9. Comparison of linear dimensional change, surface hardness and surface roughness of refractory model prepared from two different duplicating media.

    Science.gov (United States)

    Porwal, Amit; Chandrashekhar, Naveen H; Nadiger, Ramesh K; Meshramkar, Roseline D; Guttal, Satyabodh S

    2011-03-01

    The aim of this study was to evaluate and compare the linear dimensional change, surface hardness and surface roughness of the refractory casts poured against different duplicating media. Polyvinyl siloxane and Agar-agar were used for duplicating the stainless steel die. Sixty refractory models were prepared which were divided into two groups: I and II with 30 samples each respectively. Each group was subdivided into 3 subgroups with 10 samples each which were treated differently. All the specimens were measured for the linear dimensional change and surface hardness and the obtained data was statistically analyzed. Surface roughness was evaluated qualitatively taking SEM photomicrographs. Statistical analysis of linear dimensional change using one-way ANOVA showed statistically significant difference between subgroups of group I and non-significant difference between subgroups of group II. One-way ANOVA for Brinell hardness number showed statistically significant difference between the subgroups of group I & II. Student's 't' test results for linear dimensional change among different subgroups of group I & II showed significant difference between IA-IIA, IB-IIB, IC-IIC. Similarly 't'-test results for Brinell hardness number showed significant difference between subgroups IA-IIA, IB-IIB, and IC-IIC. Surface characteristics of the refractory casts poured against polyvinyl siloxane duplicating media were found to be better than the Agar media.

  10. Surface Hardness of Dental Composite Resin Restorations in Response to Preventive Agents.

    Science.gov (United States)

    Al-Samadani, Khalid H

    2016-12-01

    To assess the impact of using preventive mouthwash agents on the surface hardness of various resins composites. Hundred specimens were prepared from five types of composite resin material in a Teflon mold. Five specimens from each type of restorative materials (Herculite XRV Ultra, Estelite Σ Quick, Z Hermack, Versa Comp Sultan, and Empress Direct IPS) were evaluated posttreatment with immersion in four types of preventive mouthwashes gels and rinses - group 1: Flocare gel (0.4% stannous fluoride), group 2: Pascal gel (topical APF fluoride), group 3: Pro-relief mouthwash (Na fluoride), and group 4: Plax Soin mouthwash (Na fluoride) - at 37°C in a dark glass container at 24, 48, and 72 hours. Surface hardness measurement was made for each tested material. Statistically, we analyzed the mean values with one-way analysis of variance (ANOVA) and Tukey's test, with significance level of p composite resin materials showed decrease in their surface hardness with the time elapsed (24, 48, and 72 hours) postimmersion in the preventive mouthwashes and gels except the Herculite XRV Ultra and Versa Comp Sultan materials. Flocare gel group showed increase in the surface hardness after 48 hours of immersion than the other periods and in Estelite Σ Quick after 72 hours. There was significant differences in all materials tested with the immersion in the preventive mouthwashes and gels, such as Flocare gel (0.4% stannous fluoride), Pro-relief mouthwash (Na fluoride), and Plax Soin mouthwash (Na fluoride) except Pascal gel (topical APF fluoride) (p > 0.05), at time intervals mentioned earlier (p resin composite materials was decreased surface hardness with the time elapse of immersion for all materials except the Flocare gel group, which contains 0.4% stannous fluoride as a preventive ingredient increases the surface hardness after 48 h for Herculite XRV Ultra and Versa Comp Sultan and Estelite Σ Quick after 72 hours. The preventive agents in the form of mouthwash and gel are

  11. Effect of radiation light characteristics on surface hardness of paint-on resin for shade modification.

    Science.gov (United States)

    Arikawa, Hiroyuki; Kanie, Takahito; Fujii, Koichi; Ban, Seiji

    2005-12-01

    The purpose of this study was to investigate the effect of radiation light characteristics--of different types of clinical light-curing unit--on polymerization efficiency, as determined by the surface hardness of light-cured paint-on resins. Four shades of paint-on resin for shade modification of restorative resins were used. Materials were cured using one laboratory and three clinical light-curing units with different light sources, namely tungsten-halogen, LED, plasma arc, and xenon flash lamps. Knoop hardness measurements were taken at both the top and bottom surfaces of the specimens to assess the mechanical properties and degree of polymerization. Both LED and plasma arc light units caused significantly poorer surface hardness than the halogen and laboratory xenon lights. In addition, the transparent shade was more sensitive to surface hardness than other chromatic shades. Our results indicated that the polymerization efficiency of paint-on resin was significantly influenced by the radiation light characteristics of clinical light-curing units.

  12. Microstructures of alloyed and dispersed hard particles in the aluminium surface

    CSIR Research Space (South Africa)

    Pityana, S

    2010-03-01

    Full Text Available Laser surface alloying of A1200 aluminium alloy was carried out using a 4.4 kW Nd:YAG laser. Powder mixtures of SiC and TiC hard particles were injected into the laser generated melt pool on the aluminium substrate using a commercial powder feeder...

  13. Surface hardness properties of resin-modified glass ionomer cements and polyacid-modified composite resins.

    Science.gov (United States)

    Bayindir, Yusuf Ziya; Yildiz, Mehmet

    2004-11-15

    In this study the top and bottom surface hardness of two polyacid-modified composite resins (PMCRs), one resin-modified glass ionomer cement (RMGIC), and one composite resin were evaluated. The affect of water storage on their hardness was also investigated. The study was conducted using four different groups, each having five specimens obtained from fiberglass die molds with a diameter of 5 mm and a height of 2 mm. Measurements were made on the top and bottom surface of each specimen and recorded after 24 hours and again at 60 days. All tested materials showed different hardness values, and the values of top surfaces of the specimens were found to be higher than the bottom surface in all test groups. There was no statistical difference in the Vickers hardness (HV) values when the test specimens were kept in water storage. In conclusion Hytac displayed microhardness values higher than Vitremer and Dyract. We found the order of HV values to be Surfil > Hytac > Dyract > Vitremer, respectively. Vitremer presented the lowest microhardness level and Surfil the highest.

  14. Hardening Effect on Machined Surface for Precise Hard Cutting Process with Consideration of Tool Wear

    Institute of Scientific and Technical Information of China (English)

    YANG Yongheng

    2014-01-01

    During hard cutting process there is severe thermodynamic coupling effect between cutting tool and workpiece, which causes quenching effect on finished surfaces under certain conditions. However, material phase transformation mechanism of heat treatment in cutting process is different from the one in traditional process, which leads to changes of the formation mechanism of damaged layer on machined workpiece surface. This paper researches on the generation mechanism of damaged layer on machined surface in the process of PCBN tool hard cutting hardened steel Cr12MoV. Rules of temperature change on machined surface and subsurface are got by means of finite element simulation. In phase transformation temperature experiments rapid transformation instrument is employed, and the effect of quenching under cutting conditions on generation of damaged layer is revealed. Based on that, the phase transformation points of temperature under cutting conditions are determined. By experiment, the effects of cutting speed and tool wear on white layer thickness in damaged layer are revealed. The temperature distribution law of third deformation zone is got by establishing the numerical prediction model, and thickness of white layer in damaged layer is predicted, taking the tool wear effect into consideration. The experimental results show that the model prediction is accurate, and the establishment of prediction model provides a reference for wise selection of parameters in precise hard cutting process. For the machining process with high demanding on surface integrity, the generation of damaged layer on machined surface can be controlled precisely by using the prediction model.

  15. Hard-bottom succession of subtidal epibenthic communities colonizing hidden and exposed surfaces off northern Chile

    Directory of Open Access Journals (Sweden)

    Aldo S. Pacheco

    2010-03-01

    Full Text Available The biodiversity of hard-bottom substrata comprises species growing on exposed rock and in hidden microhabitats, such as cracks and crevices. This study examines the succession of epibenthic organisms colonizing an artificial substratum with one surface exposed and one surface hidden on a vertical wall off northern Chile. On each sampling date species coverage of three replicate panels on both surfaces was assessed. The hidden surface was dominated in terms of coverage by the bryozoans Membranipora isabelleana and Lagenicella variabilis, while algae were absent. In contrast, the exposed surface was dominated by encrusting red corallines and the red alga Rhodymenia corallina. At the end of the experimental period both surfaces were dominated by colonial suspension feeders, but showed a different community structure and successional pattern. On the exposed surface, competitive exclusion was identified as an important aspect of succession, whereas on the hidden surface this pattern was not observed. These findings have implications for overall biodiversity, because pioneer species that are not able to survive long periods on exposed surfaces become restricted to hidden surfaces, from where they spread laterally. Thus, hidden microhabitats provide refuges for certain species, and may play an important role in the overall succession on rock faces. We conclude that examination of hidden microhabitats is necessary in order to fully understand succession in hard-bottom habitats.

  16. Impact of refrigeration on the surface hardness of hybrid and microfilled composite resins.

    Science.gov (United States)

    Osternack, Fernando Henrique Ruppel; Caldas, Danilo Biazzetto de Menezes; Rached, Rodrigo Nunes; Vieira, Sérgio; Platt, Jeffrey A; Almeida, Janaina Bertoncelo de

    2009-01-01

    This in vitro study evaluated the Knoop hardness of the composite resins Charisma (C) and Durafill VS (D) polymerized in 3 different conditions: at room temperature (A) (23 +/- 1 degrees C); refrigerated at 4 +/- 1 degrees C and immediately photo-activated after removal from the refrigerator (0); and, refrigerated at 4 +/- 1 degrees C and photo-activated after a bench time of 15 min at room temperature (15). One hundred and twenty specimens (4 mm diameter and 2 mm depth) were made using a stainless steel mold and following manufacturer's instructions. All specimens were tested immediately after polymerization (I) and after 7 days of water storage in the dark at room temperature (7d). The data were subjected to ANOVA and post-hoc Tukey's test (alpha=0.05). On the top surface, C(AI) was statistically similar to C(15I) and D(AI) to D(15I) (p>0.05). On the bottom surface, C(AI) presented higher hardness values when compared to COI and C(15I) (p0.05) on the bottom surfaces for any tested polymerization condition. After 7 days of storage, the Knoop hardness decreased significantly (psurface (p>0.05). D(07d) showed higher Knoop hardness (psurface when compared to the other groups.

  17. Surface Roughness Analysis in the Hard Milling of JIS SKD61 Alloy Steel

    Directory of Open Access Journals (Sweden)

    Huu-That Nguyen

    2016-06-01

    Full Text Available Hard machining is an efficient solution that can be used to replace the grinding operation in the mold and die manufacturing industry. In this study, an attempt is made to analyze the effect of process parameters on workpiece surface roughness (Ra in the hard milling of JIS (Japanese Industrial Standard SKD61 steel, based on a combination of the Taguchi method and response surface methodology (RSM. The cutting parameters are selected based on the structural dynamic analysis of the machine tool. A set of experiments is designed according to the Taguchi technique. The average Ra is measured by a Mitutoyo Surftest SJ-400, and then analysis of variance (ANOVA is performed to determine the influences of cutting parameters on the given Ra. Quadratic mathematical modeling is introduced for prediction of the Ra during the hard milling process. The predicted values are in reasonable agreement with the observation of experiments. In an effort to obtain the minimizing Ra, a single objective optimization is employed based on the desirability function. The result shows that the percentage error between measured and predicted values of Ra is 3.2%, which is found to be insignificant. Eventually, the milled surface roughness under the optimized machining conditions is 0.122 µm. This finding shows that grinding may be replaced by finish hard milling in the mold and die manufacturing field.

  18. Surface hardness comparison of resins polymerized by argon, xenon, and conventional light sources

    Science.gov (United States)

    Blankenau, Richard J.; Pace, Scott; Powell, G. L.; Wilwerding, Terry

    1996-04-01

    A great deal of discussion has taken place regarding how to properly polymerize light activated resins. Claims are made that effective testing can be made by using surface hardness tests on samples with various dental instruments. Although these tests would probably identify a material that had been very poorly polymerized it would not identify materials that were properly polymerized. The lack of consistent, reproducible forces and evaluation of the results make these test practically worthless. Surface hardness which is important clinically has value when combined with evaluation of the surface immediately adjacent to the light source and the surface adjacent to the tooth. Also immediate and 24 hour testing to allow for continued polymerization is helpful in determining how to achieve best results for our patients. A variety of new light sources have been introduced to dentistry with claims of faster and better polymerizations. The visible light units are also undergoing improvements to include built in meters to monitor light output. The purpose of this study was to evaluate the top and bottom surface hardness of a composite resin using the following light sources: argon, xenon, and two visible light sources.

  19. Measures to reduce glyphosate runoff from hard surfaces, 2: effect of time interval between application and first precipitation event

    NARCIS (Netherlands)

    Luijendijk, C.D.; Beltman, W.H.J.; Smidt, R.A.; Pas, van der L.J.T.; Kempenaar, C.

    2005-01-01

    In this research the effect of moisture conditions of hard surfaces on emission of herbicides from hard surfaces was quantified. In addition the dissipation of glyphosate applied on brick-pavement is determined in time. The outdoor experiment was carried out on 3 and 17 June 2003. In previous

  20. Measures to reduce glyphosate runoff from hard surfaces, 2: effect of time interval between application and first precipitation event

    NARCIS (Netherlands)

    Luijendijk, C.D.; Beltman, W.H.J.; Smidt, R.A.; Pas, van der L.J.T.; Kempenaar, C.

    2005-01-01

    In this research the effect of moisture conditions of hard surfaces on emission of herbicides from hard surfaces was quantified. In addition the dissipation of glyphosate applied on brick-pavement is determined in time. The outdoor experiment was carried out on 3 and 17 June 2003. In previous resear

  1. Effect of food simulating liquids on surface hardness of two dental resin composites

    Directory of Open Access Journals (Sweden)

    Ghavam M.

    2009-12-01

    Full Text Available "nBackground and Aim: Decreasing the hardness of dental restorative composites after curing in oral environment can influence their clinical durability. The aim of this study was to evaluate the effect of food-simulating liquids such as 25%, 50%, 75 % ethanol and 50 % heptane on surface hardness of two composites - (Gradia and P60 after curing and immersing time of 24 hours and 7 days."nMaterials and Methods: 45 specimens of each composite were prepared in a stainless steel mold with 6 mm diameter and 2 mm depth. 5 specimens of each composite were tested for microhardness immediately after curing as the control group. The other specimens of each composite were randomly divided into eight groups. Each specimen was immersed in one of the following solutions 25%, 50%, 75 % ethanol and 50 % heptane for either 24 hours or 7 days. Then the specimens were taken out of the solutions and washed and dried and transferred to the refrigerator until performing the test. In standard conditions, surface microhardness of specimens was evaluated by the microhardness device based on Vickers. The data were analyzed by one way ANOVA 3 way ANOVA and Tukey Post Hoc tests. The level of significance was set at p<0.05."nResults: Surface hardness of P60 composite was higher than that of Gradia. An analysis of variance in gradia and p60 showed significant difference between the control and all the other groups (P<0.05 except the 25% ethanol (P=0.514. After 24 hours all the solutions had significant effect on Gradia (P<0.05 except 50% and 75% ethanol (P=0.793. After 7 days all the solutions had significant effect on Gradia except 50% and 25% ethanol (P=0.385and 50% and 75% ethanol (P=0.150 According to P60 after both 24 hours and 7 days all the solutions had significant effect on the hardness. 50 % heptane increased the hardness (P=0.00. 75% ethanol significantly decreased the hardness (P=0.000 followed by 50% (P=0.001 and 25% ethanol (P=0.007."nConclusion: Based on the

  2. Hydrophobic acrylic hard coating by surface segregation of hyper-branched polymers

    Science.gov (United States)

    Haraguchi, Masayuki; Hirai, Tomoyasu; Ozawa, Masaaki; Miyaji, Katsuaki; Tanaka, Keiji

    2013-02-01

    The ability of hyperbranched polymers (HBPs) to preferentially segregate to the surface of its matrix owing to its unique structure makes it a good candidate as a surface modifier. One particular challenge in its application as an efficient surface modifier, however, is its possible elimination from the surface due to the lack of attachments between a HBP (modifier) and its host material (polymer matrix). Here, we present a novel approach to efficiently prevent the removal of HBPs from the surface of its host material by directly reacting a HBP containing fluoroalkyl segments (F-HBP) to a multi-functional acrylate monomer prior to curing. We also have characterized surface structure and wettability of the acrylic hard coating material by X-ray photoelectron spectroscopic and contact angle measurements, respectively. The results show that since F-HBP was segregated at the surface, the surface became hydrophobic and more stable. Thus, we claim that our approach results in the formation of a water-repellent acrylic hard coating material.

  3. Microstructure and hardness of WC-Co particle reinforced iron matrix surface composite

    Directory of Open Access Journals (Sweden)

    Zhang Peng

    2013-11-01

    Full Text Available In this study, a high Cr cast iron surface composite material reinforced with WC-Co particles 2-6 mm in size was prepared using a pressureless sand mold infiltration casting technique. The composition, microstructure and hardness were determined by means of energy dispersive spectrometry (EDS, electron probe microanalysis (EPMA, scanning electron microscope (SEM and Rockwell hardness measurements. It is determined that the obtained composite layer is about 15 mm thick with a WC-Co particle volumetric fraction of ~38%. During solidification, interface reaction takes place between WC-Co particles and high chromium cast iron. Melting and dissolving of prefabricated particles are also found, suggesting that local Co melting and diffusion play an important role in promoting interface metallurgical bonding. The composite layer is composed of ferrite and a series of carbides, such as (Cr, W, Fe23C6, WC, W2C, M6C and M12C. The inhomogeneous hardness in the obtained composite material shows a gradient decrease from the particle reinforced metal matrix composite layer to the matrix layer. The maximum hardness of 86.3 HRA (69.5 HRC is obtained on the particle reinforced surface, strongly indicating that the composite can be used as wear resistant material.

  4. Effects of 35% Carbamide Peroxide Gel on Surface Roughness and Hardness of Composite Resins

    OpenAIRE

    Sharafeddin, F; GR. Jamalipour

    2010-01-01

    Objective: Bleaching agents may not be safe for dental materials. The purpose of this in-vitro study was to evaluate the effects of Opalescent Quick “in-office bleaching gel” containing 35% carbamide peroxide on the surface roughness and hardness of microfilled (Heliomolar) and hybride (Spectrum TPH) composite resins. Materials and Methods: Twenty specimens of Spectrum TPH composite resins and twenty Heliomolar composite resins were fabricated using a metallic ring (6.5 mm diameter and 2.5 mm...

  5. The effect of acidulated phosphate fluoride application on dental enamel surfaces hardness

    Directory of Open Access Journals (Sweden)

    Edhie Arief P

    2007-09-01

    Full Text Available Enamel demineralization by acid is the first step of caries process. It has recently been shown that acidulated phosphate fluoride (APF can maintain the hardness of enamel surface. The aim of this study was examine the effect of APF application in the hardest of enamel surface. Fifty extracted teeth were cut at their crown, 40 teeth were taken randomly then divided into 4 groups, group 1 as the control, group 2 was treated with APF for 1 minute, group 3 for 4 minutes and group 4 for 7 minutes, then all the samples were washed with demineralized water. To see the effect of APF, all of the samples were soaked in lactic acid demineralization solution with pH 4,5 for 72 hours., the hardness of the surfaces of those samples before and after the treatment was measured by Micro Vickers Hardness Tester. The data were analyzed using One-Way ANOVA and LSD tests. In conclusion, 1.23% APF gel can reduce higher enamel demineralization.

  6. Methods of improvement in hardness of composite surface layer on cast steel

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2008-08-01

    Full Text Available The paper presents a method of usable properties of surface layers improvement of cast carbon steel 200–450, by put directly in founding process a composite surface layer on the basis of Fe-Cr-C alloy and next its remelting with use of welding technology TIG – Tungsten Inert Gas. Technology of composite surface layer guarantee mainly increase in hardness and abrasive wear resistance of cast steel castings on machine elements. This technology can be competition for generally applied welding technology (surfacing by welding and thermal spraying. However the results of studies show, that is possible to connection of both methods founding and welding of surface hardening of cast steel castings. In range of experimental plan was made test castings with composite surface layer, which next were remelted with energy 0,8 and 1,6 kJ/cm. Usability for industrial applications of test castings was estimated by criterion of hardness and abrasive wear resistance of type metal-mineral.

  7. Relevance of roughness parameters of surface finish in precision hard turning.

    Science.gov (United States)

    Jouini, Nabil; Revel, Philippe; Bigerelle, Maxence

    2014-01-01

    Precision hard turning is a process to improve the surface integrity of functional surfaces. Machining experiments are carried out on hardened AISI 52100 bearing steel under dry condition using c-BN cutting tools. A full factorial experimental design is used to characterize the effect of cutting parameters. As surface topography is characterized by numerous roughness parameters, their relative relevance is investigated by statistical indices of performance computed by combining the analysis of variance, discriminant analysis and the bootstrap method. The analysis shows that the profile Length ratio (Lr) and the Roughness average (Ra) are the relevant pair of roughness parameters which best discriminates the effect of cutting parameters and enable the classification of surfaces which cannot be distinguished by one parameter: low profile length ratio Lr (Lr = 100.23%) is clearly distinguished from an irregular surface corresponding to a profile length ratio Lr (Lr = 100.42%), whereas the roughness average Ra values are nearly identical.

  8. The influence of topical application of grapeseed extract gel on enamel surface hardness after demineralization

    Science.gov (United States)

    Saragih, D. A.; Herda, E.; Triaminingsih, S.

    2017-08-01

    The aim of this study was to analyze the influence of topical application of 6.5% and 12.5% grapeseed extract gels for duration of application 16 and 32 minutes on the enamel surface hardness following tooth demineralization by an energy drink. The samples were 21 bovine teeth that underwent demineralization by immersion in the energy drink for 5 minutes in an incubator at 37°C. The demineralized specimens were randomly divided into a control group and 2 treatment groups. The control group was immersed in artificial saliva for 6 hours at 37°C, whereas the treatment groups were treated with topical 6.5% and 12.5% grapeseed extract gels for durations of 16 and 32 minutes and then immersed in artificial saliva for 6 hours at 37°C. The hardness was measured with a Knoop hardness tester. Statistical analysis by repeated ANOVA and one-way ANOVA revealed a significant increase in the enamel hardness value (p0.05).

  9. Effect of cariogenic biofilm challenge on the surface hardness of direct restorative materials in situ.

    Science.gov (United States)

    Barbosa, Renata Pereira de Sousa; Pereira-Cenci, Tatiana; Silva, Wagner Missio da; Coelho-de-Souza, Fabio Herrmann; Demarco, Flávio Fernando; Cenci, Maximiliano Sérgio

    2012-05-01

    The presence of cariogenic biofilm could result in surface degradation of composite and ionomeric restorative materials. Thus, this study evaluated in situ the alterations in the surface microhardness of these materials under biofilm accumulation and cariogenic challenge. In a split-mouth, double-blind, cross-over study, 10 volunteers wore palatal intra-oral devices containing bovine enamel slabs restored with composite resin (CR - Z250) or resin-modified glass ionomer (RMGI - Vitremer). Two phases of 14 days were carried out, one for each restorative material. In one side of the device, biofilm was allowed to accumulate under a plastic mesh, whereas in the opposing side, regular brushing was carried out 3 times/day with a dentifrice containing 1100 μg F/g as NaF. A 20% sucrose solution was applied extra-orally 10×/day on each restored dental slab. Knoop microhardness was used to calculate the percentage of surface hardness loss (%SHL). All materials showed a decrease in surface hardness after the in situ period. The restorative materials presented the following average for %SHL: RMGI without biofilm accumulation=8.9 and with biofilm accumulation=25.6, CR without biofilm accumulation=14.7 and with biofilm accumulation=17.0. Biofilm accumulation and the presence of cariogenic challenge promoted faster degradation of ionomeric materials, but this was not observed for composite resin. The oral environment affects the surface hardness of aesthetic restorative materials. Biofilm accumulation and cariogenic challenge promote surface degradation for ionomeric materials, but not for composite resin. Copyright © 2012 Elsevier Ltd. All rights reserved.

  10. Effect of polishing techniques and time on surface roughness, hardness and microleakage of resin composite restorations.

    Science.gov (United States)

    Venturini, Daniela; Cenci, Maximiliano Sérgio; Demarco, Flávio Fernando; Camacho, Guilherme Brião; Powers, John M

    2006-01-01

    This study evaluated the effects of immediate and delayed polishing on the surface roughness, microhardness and microleakage of a microfilled (Filtek A110) and a hybrid (Filtek Z250) resin composite. Standardized preparations were made on the buccal surfaces of 256 bovine teeth; half were restored with each composite (128 teeth per composite). Immediately after curing, gross finishing was carried out with #280 sandpaper. The specimens restored with each composite were divided into two subgroups. The first group (IM) was polished immediately after gross finishing, using three different systems (n=16): Sequence A, Sof-Lex; Sequence B, Flexicups and Sequence C, Flexicups + Jiffy Polishing Brush + Flexibuffs. The specimens were then stored for three weeks in saline 37 degrees C. The second group (DE) was stored for two weeks, then polished with the same systems and stored for one additional week. The controls (n=16) were analyzed without polishing. Five readings per specimen were taken for surface roughness and hardness. After immersion in basic fuchsin, microleakage was evaluated (40x) using standardized scores. The data were analyzed at a significance level of 0.05, with analysis of variance and an SNK test (surface roughness and microhardness) or with Kruskal-Wallis (microleakage). In both composites, only for the sequential technique was there an influence of delay in polishing on roughness (Ra). Flexicups exhibited the highest Ra of the three systems. The IM and Filtek Z-250 groups showed higher hardness than the DE and Filtek A-110 groups, respectively. Dentin margins showed more leakage than enamel margins; the sequential technique produced more leakage than the other techniques in dentin (pcomposite, time and polishing technique--had a significant influence on surface roughness, hardness and microleakage. Generally, immediate polishing produced no detrimental effect compared to delayed polishing.

  11. Surface texture and hardness of dental alloys processed by alternative technologies

    Science.gov (United States)

    Porojan, Liliana; Savencu, Cristina E.; Topală, Florin I.; Porojan, Sorin D.

    2017-08-01

    Technological developments have led to the implementation of novel digitalized manufacturing methods for the production of metallic structures in prosthetic dentistry. These technologies can be classified as based on subtractive manufacturing, assisted by computer-aided design/computer-aided manufacturing (CAD/CAM) systems, or on additive manufacturing (AM), such as the recently developed laser-based methods. The aim of the study was to assess the surface texture and hardness of metallic structures for dental restorations obtained by alternative technologies: conventional casting (CST), computerized milling (MIL), AM power bed fusion methods, respective selective laser melting (SLM) and selective laser sintering (SLS). For the experimental analyses metallic specimens made of Co-Cr dental alloys were prepared as indicated by the manufacturers. The specimen structure at the macro level was observed by an optical microscope and micro-hardness was measured in all substrates. Metallic frameworks obtained by AM are characterized by increased hardness, depending also on the surface processing. The formation of microstructural defects can be better controlled and avoided during SLM and MIL process. Application of power bed fusion techniques, like SLS and SLM, is currently a challenge in dental alloys processing.

  12. In situ studies of complex PLD-grown films using hard X-ray surface diffraction

    Science.gov (United States)

    Willmott, P. R.; Schlepütz, C. M.; Patterson, B. D.; Herger, R.; Lange, M.; Meister, D.; Maden, D.; Brönnimann, Ch.; Eikenberry, E. F.; Hülsen, G.; Al-Adwan, A.

    2005-07-01

    A novel ultra-high vacuum chamber for growing films via pulsed laser deposition and studying the growth processes in situ using hard synchrotron radiation is presented. The chamber is mounted onto a 5-circle surface diffractometer and contains a large cylindrical-section beryllium window, which allows an extensive range of reciprocal space to be probed. The chamber is primarily used to perform surface diffraction measurements, for which much of the most valuable information derives from the weakest signals. With this in mind, we have employed a photon-counting area pixel detector system, which reduces data acquisition times by one to two orders of magnitude and concomitantly increases the potential volume of data that can be acquired for any given sample before the surface degrades due to surface contamination or radiation damage. Examples are presented of initial results obtained using this system.

  13. Supramolecular adhesives to hard surfaces: adhesion between host hydrogels and guest glass substrates through molecular recognition.

    Science.gov (United States)

    Takashima, Yoshinori; Sahara, Taiga; Sekine, Tomoko; Kakuta, Takahiro; Nakahata, Masaki; Otsubo, Miyuki; Kobayashi, Yuichiro; Harada, Akira

    2014-10-01

    Supramolecular materials based on host-guest interactions should exhibit high selectivity and external stimuli-responsiveness. Among various stimuli, redox and photo stimuli are useful for its wide application. An external stimuli-responsive adhesive system between CD host-gels (CD gels) and guest molecules modified glass substrates (guest Sub) is focused. Here, the selective adhesion between host gels and guest substrates where adhesion depends on molecular complementarity is reported. Initially, it is thought that adhesion of a gel material onto a hard material might be difficult unless many guest molecules modified linear polymers immobilize on the surface of hard materials. However, reversible adhesion of the CD gels is observed by dissociating and re-forming inclusion complex in response to redox and photo stimuli.

  14. Thick and hard anodized aluminum film with large pores for surface composites

    Institute of Scientific and Technical Information of China (English)

    WANG Hui; WANG Hao-wei

    2004-01-01

    Al-base surface self-lubricating composites need thick and hard alumina membranes with large pores to add lubricants easily. This kind of porous alumina layer was fabricated in additive-containing, phosphoric acid-based solution. The effects of additive containing organic carboxylic acid and Ce salt on the properties of the oxide film and mechanism were investigated in detail with SEM and EDAX analyses. The results show that the pore diameter is about 100 nm, the film thickness increases by 4 -5 times, and the Vickers hardness improves by about 50% through adding some amount of organic carboxylic acid and Ce salt. Such an improvement in properties is explained in terms of a lower film dissolving velocity and better film quality in compound solution.

  15. Surface roughness and hardness of a composite resin: influence of finishing and polishing and immersion methods

    Directory of Open Access Journals (Sweden)

    Ana Luísa Botta Martins de Oliveira

    2010-09-01

    Full Text Available This study evaluated the finishing and polishing effect on the surface roughness and hardness of the Filtek Supreme XT, in fluoride solutions. Specimens were prepared (n = 140 with half of the samples finished and polished with Super-Snap® disks. The experimental groups were divided according to the presence or absence of finishing and polishing and immersion solutions (artificial saliva, sodium fluoride solution at 0.05% - manipulated, Fluordent Reach, Oral B, Fluorgard. The specimens remained immersed in artificial saliva for 24 hours and were then subjected to initial analysis (baseline of surface roughness and Vickers microhardness. Next, they were immersed in different fluoride solutions for 1 min/day, for 60 days. Afterwards, a new surface roughness and microhardness reading was conducted. The data were submitted to a two-way ANOVA and Tukey's test (5% significance level. For the comparison of mean roughness and hardness at baseline and after 60 days, the paired Student t test was used. The results showed that the surface roughness and microhardness of the Filtek Supreme XT were influenced by the finishing and polishing procedure, independently of the immersion methods.

  16. Analytical Modeling of Surface Roughness, Hardness and Residual Stress Induced by Deep Rolling

    Science.gov (United States)

    Magalhães, Frederico C.; Abrão, Alexandre M.; Denkena, Berend; Breidenstein, Bernd; Mörke, Tobias

    2016-12-01

    Deep rolling is a mechanical surface treatment that can significantly alter the features of metallic components and despite the fact that it has been used for a long time, to date the influence of the interaction among the principal process parameters has not been thoroughly understood. Aiming to fulfill this gap, this work addresses the effect of deep rolling on surface finish and mechanical properties from the analytical and experimental viewpoints. More specifically, the influence of deep rolling pressure and number of passes on surface roughness, hardness and residual stress induced on AISI 1060 steel is investigated. The findings indicate that the surface roughness after deep rolling is closely related to the yield strength of the work material and the available models can satisfactorily predict the former parameter. Better agreement between the mathematical and experimental hardness values is achieved when a single deep rolling pass is employed, as well as when the yield strength of the work material increases. Compressive residual stress is generally induced after deep rolling, irrespectively of the selected heat treatment and deep rolling parameters. Finally, the model proposed to predict residual stress provides results closest to the experimental data especially when the annealed material is considered.

  17. Analysis of the relationship between the surface hardness and wear resistance of indirect composites used as veneer materials.

    Science.gov (United States)

    Faria, Adriana Cláudia Lapria; Benassi, Ubiratan Menezes; Rodrigues, Renata Cristina Silveira; Ribeiro, Ricardo Faria; Mattos, Maria da Gloria Chiarello de

    2007-01-01

    This study evaluated the surface hardness and wear resistance of indirect composites (Artglass and Solidex) and the existence of a correlation between these properties. Twenty-four specimens (12 per material) were fabricated using a polytetrafluoroethylene matrix (5.0 mm in diameter; 7.0 mm high) following an incremental technique. Polymerization was done with a xenon stroboscopic light curing unit. After polishing, the specimens were stored in water at 37 degrees C during either 1 day (n=6 per material) or 55 days (n=6 per material), after which Vickers surface hardness and wear resistance were assessed. Data were analyzed statistically by unpaired Student t-test, two-way ANOVA and Tukey's test. SURFACE HARDNESS: Artglass had higher surface hardness than Solidex after 1-day immersion period (p0.05). Comparing the materials at both periods, Artglass means differed significantly to each other (p0.05). WEAR RESISTANCE: Solidex had higher wear than Artglass after 1-day immersion period (p0.05). Comparing the materials at both periods, Artglass means differed significantly to each other (p0.05). These results suggest that Artglass was better than Solidex in terms of hardness and wear resistance after 1-day water immersion. However, it was more susceptible to degradation, showing greater wear after 55 days. In conclusion, there was an inverse correlation between surface hardness and wear resistance for both Artglass and Solidex indirect composites, that is the higher the hardness, the lower the wear.

  18. In Situ Production of Hard Metal Matrix Composite Coating on Engineered Surfaces Using Laser Cladding Technique

    Science.gov (United States)

    Raza, Mohammad Shahid; Hussain, Manowar; Kumar, Vikash; Das, Alok Kumar

    2016-11-01

    The growing need for high wear-resistant surface with enhanced physical properties has led to extensive researches in the field of surface engineering. Laser cladding emerged to be a promising method to achieve these objectives in a cost-effective way. The present paper studies the viability of cladding of tungsten disulfide (WS2) powder by using 400 W continuous-wave fiber laser. WS2 was used as a coating material, which was decomposed at higher temperature and underwent several chemical reactions. By this process, in situ formation of metal matrix composites and hard face coating on the substrate surface were attained. The characterization of laser cladded surface was done to study its morphological, microstructural, mechanical and tribological properties. It was observed that cladding of WS2 powder on 304 SS resulted in the formation of Cr-W-C-Fe metal matrix composite having improved mechanical and tribological properties. The value of microhardness of the coated surface was found to increase three to four times in comparison with the parent material surface. Wear test results indicated a decrease in wear by 1/9th (maximum) as compared to the parent 304 SS surface. The volume fractions of tungsten particles on the cladded surface were also investigated through EDS analysis.

  19. In Situ Production of Hard Metal Matrix Composite Coating on Engineered Surfaces Using Laser Cladding Technique

    Science.gov (United States)

    Raza, Mohammad Shahid; Hussain, Manowar; Kumar, Vikash; Das, Alok Kumar

    2017-01-01

    The growing need for high wear-resistant surface with enhanced physical properties has led to extensive researches in the field of surface engineering. Laser cladding emerged to be a promising method to achieve these objectives in a cost-effective way. The present paper studies the viability of cladding of tungsten disulfide (WS2) powder by using 400 W continuous-wave fiber laser. WS2 was used as a coating material, which was decomposed at higher temperature and underwent several chemical reactions. By this process, in situ formation of metal matrix composites and hard face coating on the substrate surface were attained. The characterization of laser cladded surface was done to study its morphological, microstructural, mechanical and tribological properties. It was observed that cladding of WS2 powder on 304 SS resulted in the formation of Cr-W-C-Fe metal matrix composite having improved mechanical and tribological properties. The value of microhardness of the coated surface was found to increase three to four times in comparison with the parent material surface. Wear test results indicated a decrease in wear by 1/9th (maximum) as compared to the parent 304 SS surface. The volume fractions of tungsten particles on the cladded surface were also investigated through EDS analysis.

  20. Investigation of invisible oscillation on the photodetachment cross-section of H$_{2}^{-}$ near a hard surface

    Indian Academy of Sciences (India)

    Muhammad Haneef; Suneela Arif; Jehan Akbar; Muhammad Zahir; Nasrullah Shah; Kamran Abid

    2013-07-01

    Induced effects in the photodetached electron spectra from a diatomic negative ion (H$_{2}^{-}$) near a hard surface are investigated. A -polarized laser is used to knock off electrons from H$_{2}^{-}$ in the vicinity of a hard surface. Theoretical imaging method is used to derive a generalized modulation function for the total photodetachment cross-section, which describes invisible oscillation. It is found that the hard surface strongly affects the detached electron flux as well as total photodetachment cross-section. There exists strong dependence on the distance of H$_{2}^{-}$ from the hard surface and also on the separation of atomic centres of H$_{2}^{-}$. Unlike the detached electron flux, no visible oscillations are noted in the photodetachment cross-section.

  1. Effects of aluminum oxide addition on the flexural strength, surface hardness, and roughness of heat-polymerized acrylic resin

    Directory of Open Access Journals (Sweden)

    Mahroo Vojdani

    2012-09-01

    Conclusion: Reinforcement of the conventional heat-cured acrylic resin with 2.5 wt% Al2O3 powder significantly increased its flexural strength and hardness with no adverse effects on the surface roughness.

  2. Monte Carlo Simulations of Density Profiles for Hard-Sphere Chain Fluids Confined Between Surfaces

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Covering a wide range of bulk densities, density profiles for hard-sphere chain fluids (HSCFs) with chain length of 3,4,8,20,32 and 64 confined between two surfaces were obtained by Monte Carlo simulations using extended continuum configurational-bias (ECCB) method. It is shown that the enrichment of beads near surfaces is happened at high densities due to the bulk packing effect, on the contrary, the depletion is revealed at low densities owing to the configurational entropic contribution. Comparisons with those calculated by density functional theory presented by Cai et al. indicate that the agreement between simulations and predictions is good. Compressibility factors of bulk HSCFs calculated using volume fractions at surfaces were also used to test the reliability of various equations of state of HSCFs by different authors.

  3. Tooth enamel surface micro-hardness with dual species Streptococcus biofilm after exposure to Java turmeric (Curcuma xanthorrhiza Roxb.) extract

    Science.gov (United States)

    Isjwara, F. R. G.; Hasanah, S. N.; Utami, Sri; Suniarti, D. F.

    2017-08-01

    Streptococcus biofilm on tooth surfaces can decrease mouth environment pH, thus causing enamel demineralization that can lead to dental caries. Java Turmeric extract has excellent antibacterial effects and can maintain S. mutans biofilm pH at neutral levels for 4 hours. To analyze the effect of Java Turmeric extract on tooth enamel micro-hardness, the Java Turmeric extract was added on enamel tooth samples with Streptococcus dual species biofilm (S. sanguinis and S. mutans). The micro-hardness of enamel was measured by Knoop Hardness Tester. Results showed that Curcuma xanthorrhiza Roxb. could not maintain tooth enamel surface micro-hardness. It is concluded that Java Turmeric extract ethanol could not inhibit the hardness of enamel with Streptococcus dual species biofilm.

  4. Evaluation of hardness and surface roughness of two maxillofacial silicones following disinfection

    OpenAIRE

    2009-01-01

    The purpose of this study was to evaluate the Shore A hardness and surface roughness of two silicones for maxillofacial prosthetic treatment, under the influence of chemical disinfection and storage. Twenty-eight specimens were obtained, half of which were made of Silastic MDX 4-4210 silicone and, the other half were made of Silastic 732 RTV silicone. The specimens were divided into four groups: Silastic 732 RTV and MDX 4-4210 with disinfection 3 times a week with Efferdent tablets and the sa...

  5. The effect of CPP-ACP paste on the surface hardness of glass ionomer cement when immersed in orange juice

    Science.gov (United States)

    Nadia, A. A.; Eriwati, Y. K.; Damiyanti, M.

    2017-08-01

    This study aims to identify the effect of CPP-ACP paste on the surface hardness of glass ionomer cement (GIC) when immersed in orange juice. Eighteen specimens of Fuji IX GIC were divided into three groups: no CPP-ACP added (group A); CPP-ACP applied for three minutes (group B); and CPP-ACP applied for 30 minutes (group C). Specimens were immersed in orange juice and tested for surface hardness using a Vickers hardness tester. Data were analyzed using the one-way ANOVA (p = juice consumption.

  6. Effect of inhomogeneity of light from light curing units on the surface hardness of composite resin.

    Science.gov (United States)

    Arikawa, Hiroyuki; Kanie, Takahito; Fujii, Koichi; Takahashi, Hideo; Ban, Seiji

    2008-01-01

    This study investigated the characteristics of output light from different types of light curing units, and their effects on polymerization of light-activated composite resin. Three quartz-tungsten-halogen lamps, one plasma arc lamp, and one LED light curing unit were used. Intensity distribution of light emitted from the light guide tip was measured at 1.0-mm intervals across the guide tip. Distribution of Knoop hardness number on the surface of resin irradiated with the light curing units was also measured. For all units, inhomogeneous distribution of light intensity across the guide tip was observed. Minimum light intensity values were 19-80% of the maximum values. In terms of surface hardness, inhomogeneous distribution was also observed for the materials irradiated with the tested units. Minimum values were 53-92% of the maximum values. Our results indicated that markedly inhomogeneous light emitted from light curing unit could result in inhomogeneous polymerization in some areas of the restoration below the light guide tip.

  7. Forecasting development of the network of highways with hard surface with consideration of competitive advantages

    Directory of Open Access Journals (Sweden)

    Shevchuk Yaroslav V.

    2013-03-01

    Full Text Available The article uses Lotka-Volterra equations to analyse competition between the highway and railway transportation networks and competitive ability of the network with the cement concrete and asphalt concrete road coverings. Modelling the process of development by the Lotka-Volterra equations lies in selection of parameters of the model in such a manner, so that model trajectories would be very similar to approximating trends by factual data. In accordance with the results of model forecasting of development of highway and railway networks the article makes a model forecasting of development of highway and railway networks by 2080. Within the framework of the Lotka-Volterra equations, the article conducts modelling of development of earth roads and roads with hard surface and studies competition between the roads with cement concrete and asphalt concrete road coverings (type 1, on the one hand, and road-mix and bituminous macadam roads (type 2. The article establishes that earth roads do not compete with the roads with hard surface, although this type of roads was viable in the post-war period due to its cheapness.

  8. FFT and Wavelet-Based Analysis of the Influence of Machine Vibrations on Hard Turned Surface Topographies

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    With hard turning, which is an attractive alternative to existing grinding processes, surface quality is of great importance. Signal processing techniques were used to relate workpiece surface topography to the dynamic behavior of the machine tool. Spatial domain frequency analyses based on fast Fourier transform were used to analyze the tool behavior. Wavelet reconstruction was used for profile filtering. The results show that machine vibration remarkably affects the surface topography at small feed rates, but has negligible effect at high feed rates. The analyses also show how to control the surface quality during hard turning.

  9. Surface topography, hardness, and frictional properties of GFRP for esthetic orthodontic wires.

    Science.gov (United States)

    Inami, Toshihiro; Tanimoto, Yasuhiro; Yamaguchi, Masaru; Shibata, Yo; Nishiyama, Norihiro; Kasai, Kazutaka

    2016-01-01

    In our previous study, glass-fiber-reinforced plastics (GFRPs) made from polycarbonate and glass fiber for esthetic orthodontic wires were prepared by using pultrusion. The purpose of the present study was to investigate the surface topography, hardness, and frictional properties of GFRPs. To investigate how fiber diameter affects surface properties, GFRP round wires with a diameter of 0.45 mm (0.018 in.) were prepared incorporating either 13 μm (GFRP-13) or 7 μm (GFRP-7) glass fibers. As controls, stainless steel (SS), cobalt-chromium-nickel alloy, β-titanium (β-Ti) alloy, and nickel-titanium (Ni-Ti) alloy were also evaluated. Under scanning electron microscopy and scanning probe microscopy, the β-Ti samples exhibited greater surface roughness than the other metallic wires and the GFRP wires. The dynamic hardness and elastic modulus of GFRP wires obtained by the dynamic micro-indentation method were much lower than those of metallic wires (p < 0.05). Frictional forces against the polymeric composite brackets of GFRP-13 and GFRP-7 were 3.45 ± 0.49 and 3.60 ± 0.38 N, respectively; frictional forces against the ceramic brackets of GFRP-13 and GFRP-7 were 3.39 ± 0.58 and 3.87 ± 0.48 N, respectively. For both bracket types, frictional forces of GFRP wires and Ni-Ti wire were nearly half as low as those of SS, Co-Cr, and β-Ti wires. In conclusion, there was no significant difference in surface properties between GFRP-13 and GFRP-7; presumably because both share the same polycarbonate matrix. We expect that GFRP wires will deliver superior sliding mechanics with low frictional resistance between the wire and bracket during orthodontic treatment.

  10. Effect of antibacterial agents on the surface hardness of a conventional glass-ionomer cement

    Directory of Open Access Journals (Sweden)

    Tamer Tüzüner

    2012-02-01

    Full Text Available In atraumatic restorative treatment (ART, caries removal with hand excavation instruments is not as efficient as that with rotary burs in eliminating bacteria under the glass ionomer cements (GICs. Thus, different antibacterial agents have been used in recent studies to enhance the antibacterial properties of the GICs, without jeopardizing their basic physical properties. OBJECTIVE: The objective of this study was to evaluate the effect of antibacterial agents on the surface hardness of a conventional GIC (Fuji IX using Vickers microhardness [Vickers hardness number (VHN] test. MATERIAL AND METHODS: Cetrimide (CT, cetylpyridinium chloride (CPC and chlorhexidine (CHX were added to the powder and benzalkonium chloride (BC was added to the liquid of Fuji IX in concentrations of 1% and 2%, and served as the experimental groups. A control group containing no additive was also prepared. After the completion of setting reaction, VHN measurements were recorded at 1, 7, 15, 30, 60, and 90 days after storage in 37°C distilled water. A one-way ANOVA was performed followed by a Dunnett t test and Tamhane T2 tests and also repeated measurements ANOVA was used for multiple comparisons in 95% confidence interval. RESULTS: VHN results showed significant differences between the control and the experimental groups at all time periods (p<0.05 for all. Significant differences were observed between all study periods for individual groups (p<0.05. After 7 days, VHNs were decreased in all experimental groups while they continued to increase in the control group. BC and CHX groups demonstrated the least whereas CT and CPC groups exhibited most adverse effect on the hardness of set cements. CONCLUSIONS: Despite the decreased microhardness values in all experimental groups compared to the controls after 7 up to 90 days, incorporating certain antibacterial agents into Fuji IX GIC showed tolerable microhardness alterations within the limitations of this in vitro study.

  11. Theory of compact nonporous windscreens for infrasonic measurements.

    Science.gov (United States)

    Zuckerwar, Allan J

    2010-06-01

    The principle of the compact nonporous windscreen is based on the great penetrability of infrasound through matter. The windscreen performance is characterized by the ratio of the sound pressure at an interior microphone, located in the center of a windscreen, to the incident sound pressure in the free field. The frequency dependence of this pressure ratio is derived as a function of the windscreen material and geometric properties. Four different windscreen geometries are considered: a subsurface, box-shaped windscreen, a cylindrical windscreen of infinite length, a cylindrical windscreen of finite length, and a spherical windscreen. Results are presented for windscreens made of closed-cell polyurethane foam and for typical dimensions of each of the above geometries. The cylindrical windscreen of finite length, featuring evanescent radial modes, behaves as a unity-gain, low-pass filter, cutting off sharply at the end of the infrasonic range. The remaining geometries reveal a pass band that extends well into the audio range, terminated by a pronounced peak beyond which the response plummets rapidly.

  12. Response surface and neural network based predictive models of cutting temperature in hard turning

    Directory of Open Access Journals (Sweden)

    Mozammel Mia

    2016-11-01

    Full Text Available The present study aimed to develop the predictive models of average tool-workpiece interface temperature in hard turning of AISI 1060 steels by coated carbide insert. The Response Surface Methodology (RSM and Artificial Neural Network (ANN were employed to predict the temperature in respect of cutting speed, feed rate and material hardness. The number and orientation of the experimental trials, conducted in both dry and high pressure coolant (HPC environments, were planned using full factorial design. The temperature was measured by using the tool-work thermocouple. In RSM model, two quadratic equations of temperature were derived from experimental data. The analysis of variance (ANOVA and mean absolute percentage error (MAPE were performed to suffice the adequacy of the models. In ANN model, 80% data were used to train and 20% data were employed for testing. Like RSM, herein, the error analysis was also conducted. The accuracy of the RSM and ANN model was found to be ⩾99%. The ANN models exhibit an error of ∼5% MAE for testing data. The regression coefficient was found to be greater than 99.9% for both dry and HPC. Both these models are acceptable, although the ANN model demonstrated a higher accuracy. These models, if employed, are expected to provide a better control of cutting temperature in turning of hardened steel.

  13. The effect of cutting process on surface microstructure and hardness of pure and Al 6061 aluminium alloy

    Directory of Open Access Journals (Sweden)

    Adnan Akkurt

    2015-09-01

    Full Text Available In this study pure aluminium and Al 6061 aluminium alloy material had been cut with saw, milling, submerged plasma, plasma, laser, wire electric discharge machining, oxyfuel and Abrasive water jet. Microstructures and hardness variations of cut surfaces which obtained with different processes have been investigated. Results of the study show that the hardness and surface quality of the cut surface is affected from the kind of cutting process. Microstructure of cut surfaces is affected from the kind of cutting process. Microstructural changes during cutting of the materials are observed with all of the cutting process other than Abrasive water jet. Abrasive water jet method can be effectively used in industrial applications where no microstructural changes and hardness reduction is essential.

  14. Surface roughness and cutting forces modeling for optimization of machining condition in finish hard turning of AISI 52100 steel

    Energy Technology Data Exchange (ETDEWEB)

    Azizi, Mohamed Walid; Belhadi, Salim; Yallese, Mohamed Athmane [Univ. of Guelma, Guelma (Algeria); Mabrouki, Tarek; Rigal, Jean Francois [Univ. of Lyon, Lyon (France)

    2012-12-15

    An experimental investigation was conducted to analyze the effect of cutting parameters (cutting speed, feed rate and depth of cut) and workpiece hardness on surface roughness and cutting force components. The finish hard turning of AISI 52100 steel with coated Al2O3 + TiC mixed ceramic cutting tools was studied. The planning of experiment were based on Taguchi's L27 orthogonal array. The response table and analysis of variance (ANOVA) have allowed to check the validity of linear regression model and to determine the significant parameters affecting the surface roughness and cutting forces. The statistical analysis reveals that the feed rate, workpiece hardness and cutting speed have significant effects in reducing the surface roughness; whereas the depth of cut, workpiece hardness and feed rate are observed to have a statistically significant impact on the cutting force components than the cutting speed. Consequently, empirical models were developed to correlate the cutting parameters and workpiece hardness with surface roughness and cutting forces. The optimum machining conditions to produce the lowest surface roughness with minimal cutting force components under these experimental conditions were searched using desirability function approach for multiple response factors optimization. Finally, confirmation experiments were performed to verify the pertinence of the developed empirical models.

  15. Measurement of surface roughness and flank wear on hard martensitic stainless steel by CBN and PCBN cutting tools

    Directory of Open Access Journals (Sweden)

    S. Thamizhmanii

    2008-12-01

    Full Text Available Purpose: The experiments with different operating parameters using CBN and PCBN tools on hard AISI 440 C material were investigated in this paper.Design/methodology/approach: In this research AISI 440 C stainless was used under hard condition. The cutting tools are having three cutting edges and each edge repeated for 5 times. The test conducted by each cutting edge was termed as trail 1, 2, 3, 4 & 5. The length of cutting was 150 mm and each trail. The surface roughness and flank wear, crater wear and BUE were measured by SEM.Findings: The surface roughness was low by CBN at high turning cutting speed and the flank wear was high. The surface roughness was high by PCBN tool than CBN tool and flank wear recorded was low for PCBN tool than CBN tool. The chips produced were saw tooth in all operating parameters. The CBN tool was unable to withstand heat at cutting zone and hence more flank wear occurred. The PCBN tool sustained the temperature and less tool wear occurred. More crater wear formed on PCBN tools where as CBN tool produced less crater wear. The formation of crater wear on the rake face was due to rough surface of the saw tooth chips.Practical implications: The investigation results will provide useful information to applying CBN and PCBN cutting tools in hard turning stainless steels.Originality/value: Hard turning is a latest technology and possible to turn all hard materials. The hard turning produce net shaped products and reduces machining time, low cost per products, etc. The difficult to cut materials like stainless steels was turned by super hard cutting tools like CBN and PCBN to achieve good surface roughness, dimensional control and reduced tool wear.

  16. Formulation effects and the off-target transport of pyrethroid insecticides from urban hard surfaces.

    Science.gov (United States)

    Jorgenson, Brant C; Young, Thomas M

    2010-07-01

    Controlled rainfall experiments utilizing drop-forming rainfall simulators were conducted to study various factors contributing to off-target transport of off-the-shelf formulated pyrethroid insecticides from concrete surfaces. Factors evaluated included active ingredient, product formulation, time between application and rainfall (set time), and rainfall intensity. As much as 60% and as little as 0.8% of pyrethroid applied could be recovered in surface runoff depending primarily on product formulation, and to a lesser extent on product set time. Resulting wash-off profiles during one-hour storm simulations could be categorized based on formulation, with formulations utilizing emulsifying surfactants rather than organic solvents resulting in unique wash-off profiles with overall higher wash-off efficiency. These higher wash-off efficiency profiles were qualitatively replicated by applying formulation-free neat pyrethroid in the presence of independently applied linear alkyl benzene sulfonate (LAS) surfactant, suggesting that the surfactant component of some formulated products may be influential in pyrethroid wash-off from urban hard surfaces.

  17. Diffusion and Clustering of Carbon Dioxide on non-porous Amorphous Solid Water

    CERN Document Server

    He, Jiao; Vidali, Gianfranco

    2016-01-01

    Observations by ISO and Spitzer towards young stellar objects (YSOs) showed that CO$_2$ segregates in the icy mantles covering dust grains. Thermal processing of ice mixture was proposed as responsible for the segregation. Although several laboratory studied thermally induced segregation, a satisfying quantification is still missing. We propose that the diffusion of CO$_2$ along pores inside water ice is the key to quantify segregation. We combined Temperature Programmed Desorption (TPD) and Reflection Absorption InfraRed Spectroscopy (RAIRS) to study how CO$_2$ molecules interact on a non-porous amorphous solid water (np-ASW) surface. We found that CO$_2$ diffuses significantly on a np-ASW surface above 65~K and clusters are formed at well below one monolayer. A simple rate equation simulation finds that the diffusion energy barrier of CO$_2$ on np-ASW is 2150$\\pm$50 K, assuming a diffusion pre-exponential factor of 10$^{12}$ s$^{-1}$. This energy should also apply to the diffusion of CO$_2$ on wall of pores...

  18. Modeling of the effect of freezer conditions on the hardness of ice cream using response surface methodology.

    Science.gov (United States)

    Inoue, K; Ochi, H; Habara, K; Taketsuka, M; Saito, H; Ichihashi, N; Iwatsuki, K

    2009-12-01

    The effect of conventional continuous freezer parameters [mix flow (L/h), overrun (%), drawing temperature ( degrees C), cylinder pressure (kPa), and dasher speed (rpm)] on the hardness of ice cream under varying measured temperatures (-5, -10, and -15 degrees C) was investigated systematically using response surface methodology (central composite face-centered design), and the relationships were expressed as statistical models. The range (maximum and minimum values) of each freezer parameter was set according to the actual capability of the conventional freezer and applicability to the manufacturing process. Hardness was measured using a penetrometer. These models showed that overrun and drawing temperature had significant effects on hardness. The models can be used to optimize freezer conditions to make ice cream of the least possible hardness under the highest overrun (120%) and a drawing temperature of approximately -5.5 degrees C (slightly warmer than the lowest drawing temperature of -6.5 degrees C) within the range of this study. With reference to the structural elements of the ice cream, we suggest that the volume of overrun and ice crystal content, ice crystal size, and fat globule destabilization affect the hardness of ice cream. In addition, the combination of a simple instrumental parameter and response surface methodology allows us to show the relation between freezer conditions and one of the most important properties-hardness-visually and quantitatively on the practical level.

  19. Enhancing surface integrity and corrosion resistance of laser cladded Cr-Ni alloys by hard turning and low plasticity burnishing

    Science.gov (United States)

    Zhang, Peirong; Liu, Zhanqiang

    2017-07-01

    In this research, the enhancements of surface integrity and corrosion resistance of the laser cladded parts by combined hard turning with low plasticity burnishing (LPB) were presented by both potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The investigated results indicated that the corrosion resistance of the laser cladded parts could be improved by combined hard turning with LPB than by sole hard turning. An innovative model was proposed to explain the corrosion mechanism of the laser cladded parts after hybrid machining. Both surface adsorption and passive film were observed to dominate the corrosion resistance of the hybrid machined Cr-Ni alloys by laser cladding. The surface integrity led to the inhomogeneity of passive film, and then altered the corrosion resistance of the machined samples. In terms of the surface integrity factors, residual compressive stresses and surface finish were found to play more important roles in improving the corrosion resistance than the grain refinement and microhardness of the machined surface layer materials did. Based on the research results, anti-corrosion parts with laser cladded alloys could be fabricated by hybrid machining using the combination of hard turning and LPB.

  20. Impact of the hard-coded parameters on the hydrologic fluxes of the land surface model Noah-MP

    Science.gov (United States)

    Cuntz, Matthias; Mai, Juliane; Samaniego, Luis; Clark, Martyn; Wulfmeyer, Volker; Attinger, Sabine; Thober, Stephan

    2016-04-01

    Land surface models incorporate a large number of processes, described by physical, chemical and empirical equations. The process descriptions contain a number of parameters that can be soil or plant type dependent and are typically read from tabulated input files. Land surface models may have, however, process descriptions that contain fixed, hard-coded numbers in the computer code, which are not identified as model parameters. Here we searched for hard-coded parameters in the computer code of the land surface model Noah with multiple process options (Noah-MP) to assess the importance of the fixed values on restricting the model's agility during parameter estimation. We found 139 hard-coded values in all Noah-MP process options, which are mostly spatially constant values. This is in addition to the 71 standard parameters of Noah-MP, which mostly get distributed spatially by given vegetation and soil input maps. We performed a Sobol' global sensitivity analysis of Noah-MP to variations of the standard and hard-coded parameters for a specific set of process options. 42 standard parameters and 75 hard-coded parameters were active with the chosen process options. The sensitivities of the hydrologic output fluxes latent heat and total runoff as well as their component fluxes were evaluated. These sensitivities were evaluated at twelve catchments of the Eastern United States with very different hydro-meteorological regimes. Noah-MP's hydrologic output fluxes are sensitive to two thirds of its standard parameters. The most sensitive parameter is, however, a hard-coded value in the formulation of soil surface resistance for evaporation, which proved to be oversensitive in other land surface models as well. Surface runoff is sensitive to almost all hard-coded parameters of the snow processes and the meteorological inputs. These parameter sensitivities diminish in total runoff. Assessing these parameters in model calibration would require detailed snow observations or the

  1. In vivo guided vascular regeneration with a non-porous elastin-like polypeptide hydrogel tubular scaffold.

    Science.gov (United States)

    Mahara, Atsushi; Kiick, Kristi L; Yamaoka, Tetsuji

    2017-01-28

    Herein, we demonstrate a new approach for small-caliber vascular reconstruction using a non-porous elastin-like polypeptide hydrogel tubular scaffold, based on the concept of guided vascular regeneration (GVR). The scaffolds are composed of elastin-like polypeptide, (Val-Pro-Gly-Ile-Gly)n , for compliance matching and antithrombogenicity and an Arg-Gly-Asp (RGD) motif for connective tissue regeneration. When the polypeptide was mixed with an aqueous solution of β-[Tris(hydroxymethyl)phosphino]propionic acid at 37°C, the polypeptide hydrogel was rapidly formed. The elastic modulus of the hydrogel was 4.4kPa. The hydrogel tubular scaffold was formed in a mold and reinforced with poly(lactic acid) nanofibers. When tubular scaffolds with an inner diameter of 1 mm and length of 5 mm were implanted into rat abdominal aortae, connective tissue grew along the scaffold luminal surface from the flanking native tissues, resulting in new blood vessel tissue with a thickness of 200 μm in 1 month. In contrast, rats implanted with control scaffolds without the RGD motif died. These results indicate that the non-porous hydrogel tubular scaffold containing the RGD motif effectively induced rapid tissue regeneration and that GVR is a promising strategy for the regeneration of small-diameter blood vessels. This article is protected by copyright. All rights reserved.

  2. One-step surface selective modification of UV-curable hard coatings with photochemical metal organics

    Science.gov (United States)

    Lee, Yoon Kwang; Park, Chang-Sun; Park, Hyung-Ho

    2016-12-01

    An organic-inorganic hybrid bi-layer film with a selective distribution of inorganic components was synthesized from a one-pot process of UV irradiation. A photochemical metal oxide precursor (Sr 2-ethylhexanoate) varying from 0 to 4 wt% was dispersed in UV-curable coating materials. Under UV exposure, the bi-layer started reacting simultaneously but at different rates due to differences in the two UV-condensable components' reactivity. The effects of the dispersed inorganic component on the surface morphology and mechanical properties were investigated by atomic force microscopy and nanoindentation, respectively. The reaction process and rates were studied from linkage change using Fourier transform infrared spectroscopy at various UV exposure times (0-30 min). The elemental distribution and the interface on the coating layer were characterized by X-ray photoelectron spectroscopy from Ar etching, revealing continuous and gradual composition changes in depth. The results showed that a flattened and surface-selectively hardened SrO containing the coating film could be obtained by this simple process. Consequently, a small ratio of photochemical metal oxide reinforced the organic hard coating film's mechanical properties through the formation of an effective SrO top layer.

  3. Eleven-month-old infants infer differences in the hardness of object surfaces from observation of penetration events.

    Directory of Open Access Journals (Sweden)

    Tomoko eImura

    2015-08-01

    Full Text Available Previous studies have shown different developmental trajectories for object recognition of solid and non-solid objects. However, there is no evidence as to whether infants have expectations regarding certain attributes of objects, such as surface hardness, in the absence of tactile information. In the present study, we examined infants’ perception of the hardness of object surfaces from visually presented penetration events using the familiarization–novelty preference procedure. Experiment 1 showed that by 11 months old infants distinguished a relatively soft surface from a crusty surface based on changes in the velocity of a moving object as the moving object penetrated the surface of the target object. Experiment 2 ruled out the possibility that infants were merely sensitive to differences in the velocity changes in the stimuli.

  4. Study of surface integrity AISI 4140 as result of hard, dry and high speed machining using CBN

    Science.gov (United States)

    Ginting, B.; Sembiring, R. W.; Manurung, N.

    2017-09-01

    The concept of hard, dry and high speed machining can be combined, to produce high productivity, with lower production costs in manufacturing industry. Hard lathe process can be a solution to reduce production time. In lathe hard alloy steels reported problems relating to the integrity of such surface roughness, residual stress, the white layer and the surface integrity. AISI 4140 material is used for high reliable hydraulic system components. This material includes in cold work tool steel. Consideration election is because this material is able to be hardened up to 55 HRC. In this research, the experimental design using CCD model fit with three factors, each factor is composed of two levels, and six central point, experiments were conducted with 1 replications. The experimental design research using CCD model fit.

  5. Influence of mouth rinses on the surface hardness of dental resin nano-composite

    OpenAIRE

    Khan, Aftab Ahmed; Siddiqui, Adel Zia; Mohsin, Syed Fareed; Al-Kheraif, Abdulaziz A

    2015-01-01

    Objective: The aim of this research was to assess the effect of mouth rinses with and without alcohol on the hardness of dental nano-filled composite. Methods: The micro-hardness of fifty circular disk shaped specimens of 7 mm x 2 mm were measured after 14 days. Specimens were immersed into alcohol containing (Listerine and Colgate Perioguard) and alcohol-free (Prodent and Sensodyne Oral antiseptic) mouth rinse solutions. Artificial saliva served as the control. Vickers Micro-hardness was mea...

  6. Utility of tantalum (Ta) coating to improve surface hardness in vitro bioactivity and biocompatibility of Co–Cr

    Energy Technology Data Exchange (ETDEWEB)

    Pham, Vuong-Hung [WCU Hybrid Materials Program, Department of Materials Science and Engineering, Seoul National University, Seoul, 151-742 (Korea, Republic of); Advanced Institute for Science and Technology (AIST), Hanoi University of Science and Technology (HUST), No 1, Dai Co Viet Road, Ha Noi (Viet Nam); Lee, Seung-Hee; Li, Yuanlong; Kim, Hyoun-Ee [WCU Hybrid Materials Program, Department of Materials Science and Engineering, Seoul National University, Seoul, 151-742 (Korea, Republic of); Shin, Kwan-Ha [Department of Dental Laboratory Science and Engineering, Korea University, Seoul, 136-703 (Korea, Republic of); Koh, Young-Hag, E-mail: kohyh@korea.ac.kr [Department of Dental Laboratory Science and Engineering, Korea University, Seoul, 136-703 (Korea, Republic of)

    2013-06-01

    This study reports the utility of tantalum (Ta) coating for improving the surface hardness, in vitro bioactivity and biocompatibility of Co–Cr implants. The use of direct current sputtering allowed for the deposition of a dense and uniform Ta film onto a Co–Cr substrate, which was composed of β-phase Ta grains. This hard Ta coating significantly improved the surface hardness of the Co–Cr by a factor of > 2.3. In addition, the Ta-deposited Co–Cr substrate showed a vigorous precipitation of apatite crystals on its surface after 4 weeks of immersion in simulated body fluid, suggesting its excellent in vitro bioactivity. This bioactive Ta coating led to a considerable improvement in the in vitro biocompatibility of the Co–Cr, which was assessed in terms of the attachment, proliferation and differentiation of pre-osteoblasts (MC3T3-E1). - Highlights: • Dense and uniform Ta film was deposited onto a Co–Cr substrate using DC sputtering. • The Ta coating significantly enhanced the surface hardness of the Co–Cr. • The in vitro biocompatibility of the Co–Cr was also significantly improved.

  7. The toxicity of plastic nanoparticles to green algae as influenced by surface modification, medium hardness and cellular adsorption

    NARCIS (Netherlands)

    Nolte, Tom M.; Hartmann, Nanna B.; Kleijn, Mieke; Garnæs, Jørgen; Meent, van de Dik; Jan Hendriks, A.; Baun, Anders

    2017-01-01

    To investigate processes possibly underlying accumulation and ecological effects of plastic nano-particles we have characterized their interaction with the cell wall of green algae. More specifically, we have investigated the influence of particle surface functionality and water hardness (Ca2+

  8. THE EFFECT OF THE APPLICATION OF 20% CARBAMIDE PEROXIDE ON THE GLASS IONOMER CEMENT TYPE II SURFACE HARDNESS

    Directory of Open Access Journals (Sweden)

    Ali Noerdin

    2015-06-01

    Full Text Available In dental bleaching, carbamide peroxide is usually used at concentration of 10%, 15%, to 20%. The result of our previous study showed that the application of 10% and 15% carbamide peroxide bleaching agent has increased the surface hardness of glass ionomer cement. The purpose of this study was to observe the effect of 20% carbamide peroxide bleaching to glass ionomer surface hardness. Twenty specimens of glass ionomer type II after exposed to 20% carbamide peroxide were divided into two application time groups: 4 and 8 hours per day. Glass ionomer cement surface hardness was measured by Vickers Microhardness Tester series HMV-2 with a weight of 0,025 Hv for 20 seconds. The measurement was conducted at before/no application, after a week, and after 2 weeks of application in both groups. It can be concluded that the application of 20% carbamide peroxide bleaching agent could increase the surface hardness of glass ionomer cement after 1 week and 2 weeks application period.

  9. The toxicity of plastic nanoparticles to green algae as influenced by surface modification, medium hardness and cellular adsorption

    NARCIS (Netherlands)

    Nolte, Tom M.; Hartmann, Nanna B.; Kleijn, Mieke; Garnæs, Jørgen; Meent, van de Dik; Jan Hendriks, A.; Baun, Anders

    2017-01-01

    To investigate processes possibly underlying accumulation and ecological effects of plastic nano-particles we have characterized their interaction with the cell wall of green algae. More specifically, we have investigated the influence of particle surface functionality and water hardness (Ca2+ conce

  10. Effect of compaction pressure and powder grade on the microstructure, hardness and surface topography of steam oxidized sintered iron

    Energy Technology Data Exchange (ETDEWEB)

    Mello, J.D.B. de; Hutchings, I.M. [Univ. of Cambridge (United Kingdom); Binder, R. [Embraco, Joinville, S.C. (Brazil); Klein, A.N. [Labmat, UFSC, Florianopolis, S.C. (Brazil)

    2000-07-01

    Steam oxidation has proved to be an effective process to improve the properties of sintered iron components. The wear processes of such surfaces might be expected to be influenced by the presence of pores, the extent of pore closure and the nature and morphology of the oxide produced. In this paper, the influence of compaction pressure and powder grade on the microstructure, oxide content, hardness and surface topography of steam treated sintered iron is analysed. Specimens prepared from atomised powders in different sizes were compacted using 4 different pressure, sintered and then subjected to a continuous steam treatment. A clear influence of the processing parameters on porosity was highlighted. Low porosity is always associated with high compaction pressure and greater powder size. Decreasing powder size always leads to high hardness. Samples produced with smaller powder size show a continuous decrease in hardness as the compaction pressure increases although for the large powder size there is a slight increase to a constant value of ultimate hardness. For the intermediate grain size a maximum hardness is obtained as the compaction pressure increases. X-ray diffraction shows that the oxide layer is composed of magnetite and haematite. No general correlation was found between topographic features, examined using vertical scanning interferometry, and processing parameters or microstructure. (orig.)

  11. Diffusion and Clustering of Carbon Dioxide on Non-porous Amorphous Solid Water

    Science.gov (United States)

    He, Jiao; Emtiaz, Shahnewaj M.; Vidali, Gianfranco

    2017-03-01

    Observations by ISO and Spitzer toward young stellar objects showed that CO2 segregates in the icy mantles covering dust grains. Thermal processing of the ice mixture was proposed as being responsible for the segregation. Although several laboratories studied thermally induced segregation, a satisfying quantification is still missing. We propose that the diffusion of CO2 along pores inside water ice is the key to quantify segregation. We combined Temperature Programmed Desorption and Reflection Absorption InfraRed Spectroscopy to study how CO2 molecules interact on a non-porous amorphous solid water (np-ASW) surface. We found that CO2 diffuses significantly on an np-ASW surface above 65 K and clusters are formed at well below one monolayer. A simple rate equation simulation finds that the diffusion energy barrier of CO2 on np-ASW is 2150 ± 50 K, assuming a diffusion pre-exponential factor of 1012 s‑1. This energy should also apply to the diffusion of CO2 on the wall of pores. The binding energy of CO2 from CO2 clusters and CO2 from H2O ice has been found to be 2415 ± 20 K and 2250 ± 20 K, respectively, assuming the same prefactor for desorption. CO2–CO2 interaction is stronger than CO2–H2O interaction, in agreement with the experimental finding that CO2 does not wet the np-ASW surface. For comparison, we carried out similar experiments with CO on np-ASW, and found that the CO–CO interaction is always weaker than CO–H2O. As a result, CO wets the np-ASW surface. This study should be of help to uncover the thermal history of CO2 on the icy mantles of dust grains.

  12. Evaluation the Effect of Cellulose Nanocrystalline Particles on Flexural Strength and Surface Hardness of Autoploymerized Temporary Fixed Restoration Resin

    Directory of Open Access Journals (Sweden)

    Forouzesh Shirgaee Talari

    2016-12-01

    Full Text Available Background: Autopolymerized acrylic resin is commonly used material for construction of temporary restoration; however it has insufficient mechanical properties. The purpose of this study was to evaluate the effect of adding cellulose nano-particles on flexural strength and surface hardness of auto-polymerised acrylic resin. Materials and Method: Following the acid hydrolysis of microcrystalline cellulose particles to achieve cellulose nanocrystals (CNC particles, 40 specimens were fabricated for each test that divided to four groups (n=10 coded AD. group A was the control group (without adding CNC. specimens in other three groups (B-D were reinforced with CNC at loading of 1,2.5,5 wt%. flexural strength was assessed with a three-point bending test using a universal testing machine. surface hardness testing was conducted using a Vickers hardness tester. One way ANOVA and Tucky test were used to analyzed the data.scanning electron microscopy (SEM observed was applied to evaluate the fracture pattern. Results: A significant increase in flexural strength was observed in group with 2.5% cellulose nanofillers (P=2.5%,however no significant increase was observed in surface hardness. The SEM observation demonstrated brittle fracture in pure PMMA. By adding 2.5% wt of cellulose nanofillers, the characteristics of fracture is almost ductile, but in 5% wt of nanofillers,several cracks and void was observed at fracture surface. Conclusion:Reinforcement of the Autopolymerized acrylic resin with 2.5% wt cellulose nanofillers significantly increased its flexural strength with no adverse effect on the surface hardness.

  13. Effects of cutting parameters and machining environments on surface roughness in hard turning using design of experiment

    Science.gov (United States)

    Mia, Mozammel; Bashir, Mahmood Al; Dhar, Nikhil Ranjan

    2016-07-01

    Hard turning is gradually replacing the time consuming conventional turning process, which is typically followed by grinding, by producing surface quality compatible to grinding. The hard turned surface roughness depends on the cutting parameters, machining environments and tool insert configurations. In this article the variation of the surface roughness of the produced surfaces with the changes in tool insert configuration, use of coolant and different cutting parameters (cutting speed, feed rate) has been investigated. This investigation was performed in machining AISI 1060 steel, hardened to 56 HRC by heat treatment, using coated carbide inserts under two different machining environments. The depth of cut, fluid pressure and material hardness were kept constant. The Design of Experiment (DOE) was performed to determine the number and combination sets of different cutting parameters. A full factorial analysis has been performed to examine the effect of main factors as well as interaction effect of factors on surface roughness. A statistical analysis of variance (ANOVA) was employed to determine the combined effect of cutting parameters, environment and tool configuration. The result of this analysis reveals that environment has the most significant impact on surface roughness followed by feed rate and tool configuration respectively.

  14. Comparison of Surface Hardness of Various Shades of Twinky Star Colored Compomer Light-cured with QTH and LED Units

    Science.gov (United States)

    Khodadadi, Effat; Khafri, Soraya; Aziznezhad, Mahdiyeh

    2016-01-01

    Introduction Colored compomers are a group of restorative materials that were introduced in 2002 to repair primary teeth, and they provide attractive color and ease of use in pediatric dentistry. The aim of this study was to evaluate the effect of QTH and LED light-curing units on the surface hardness of different colors of Twinky Star compomers. Methods In this experimental study, a composite resin (Z250, 3M, and USA), an ionosit compomer (DMG, Germany) with A3 shade and 8 different Twinky Star colored compomer (Voco, Germany) samples were used. In all, 100 samples were prepared with 10 samples in each group, i.e., 10 Z250 composite resin, 10 ionosit compomers, and 10 Twinky Star compomer samples of each color. The samples were prepared in a 4×4-mm Teflon mold. Half of the samples were light-cured with QTH and the other half with LED units. Then, the surface microhardness was measured by Vickers hardness test. The data were analyzed with IBM-SPSS version 22, using the t-test and ANOVA. Results Two-way ANOVA showed that the mean surface hardness of the compomer samples cured with the QTH unit was significantly higher than that cured with the LED unit (p < 0.001). In each curing unit, surface hardness of some materials exhibited significant differences with the highest hardness being observed in the Z250 composite resin (650.35 ± 56.320) and the lowest hardness being detected in the ionosit compomers (461.10 ± 96.170). One-way ANOVA also showed that, among the different colors of the Twinky Star compomer, the lowest hardness with both units (QTH and LED) was observed in the gold color (214.32 ± 22.026 and 175.116 ± 15.918, respectively). Conclusion The colored compomer and the type of light-curing unit affected the microhardnesses of the surfaces. Different colors of Twinky Star compomers exhibited different surface microhardnesses. PMID:27382444

  15. Evaluate the Effect of Commercially Available Denture Cleansers on Surface Hardness and Roughness of Denture Liners at Various Time Intervals

    Science.gov (United States)

    Mohammed, Hilal S.; Singh, Sumeet; Hari, Prasad A.; Amarnath, G. S.; Kundapur, Vinaya; Pasha, Naveed; Anand, M.

    2016-01-01

    Background and objective: Chemical cleansing by denture cleansers is first choice for denture plaque control. The most common problems while using denture cleansers are hardening, porosity, odor sorption, water sorption, solubility, and colour change, bacterial and fungal growth. Chemical cleansing procedures have been found to have an effect on the physical and mechanical properties of denture liners. Thus, this study was conducted to evaluate the effect of commercially available denture cleansers on surface hardness and roughness of acrylic and silicon based denture liners at various time interval. Method: Two autopolymerising denture liners Kooliner (acrylic) and GC reline soft (silicon) were tested with two commercially available denture cleansers, polident and efferdent plus. Total of 120 specimens were prepared and all the specimens were divided into six groups based on the relining materials and denture cleansers used. Surface hardness and surface roughness was tested using Shore A durometer and profilometer respectively at the end of day 1, day 7, day 30 and day 90. All the specimens were stored in artificial saliva throughout the study. Cleanser solution was prepared daily by adding Polident and Efferdent plus denture cleanser tablet into 250ml of enough very warm (not hot) water. Acrylic and silicon liner groups were cleansed in a solution of denture cleanser and water for 15 minutes daily, rinsed with water and stored in artificial saliva at room temperature. The data was analyzed with one way ANOVA and independent t-test. Result: The acrylic soft lining showed gradual hardening and increase in surface roughness after immersion in denture cleanser and also with time. Acrylic liner material showed maximum hardness and roughness with Polident followed by Efferdent plus and water (control group). Silicone lining material showed a slight difference in hardness and roughness between the test group and control group. There was a slight increase in hardness in

  16. a Finite Difference Numerical Model for the Propagation of Finite Amplitude Acoustical Blast Waves Outdoors Over Hard and Porous Surfaces

    Science.gov (United States)

    Sparrow, Victor Ward

    1990-01-01

    This study has concerned the propagation of finite amplitude, i.e. weakly non-linear, acoustical blast waves from explosions over hard and porous media models of outdoor ground surfaces. The nonlinear acoustic propagation effects require a numerical solution in the time domain. To model a porous ground surface, which in the frequency domain exhibits a finite impedance, the linear phenomenological porous model of Morse and Ingard was used. The phenomenological equations are solved in the time domain for coupling with the time domain propagation solution in the air. The numerical solution is found through the method of finite differences. The second-order in time and fourth -order in space MacCormack method was used in the air, and the second-order in time and space MacCormack method was used in the porous medium modeling the ground. Two kinds of numerical absorbing boundary conditions were developed for the air propagation equations to truncate the physical domain for solution on a computer. Radiation conditions first were used on those sides of the domain where there were outgoing waves. Characteristic boundary conditions secondly are employed near the acoustic source. The numerical model agreed well with the Pestorius algorithm for the propagation of electric spark pulses in the free field, and with a result of Pfriem for normal plane reflection off a hard surface. In addition, curves of pressure amplification versus incident angle for waves obliquely incident on the hard and porous surfaces were produced which are similar to those in the literature. The model predicted that near grazing finite amplitude acoustic blast waves decay with distance over hard surfaces as r to the power -1.2. This result is consistent with the work of Reed. For propagation over the porous ground surface, the model predicted that this surface decreased the decay rate with distance for the larger blasts compared to the rate expected in the linear acoustics limit.

  17. The microstructure and surface hardness of Ti6Al4V alloy implanted with nitrogen ions at an elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Vlcak, Petr, E-mail: petr.vlcak@fs.cvut.cz [Department of Physics, Faculty of Mechanical Engineering, Czech Technical University in Prague, Technicka 4, 16607 Prague (Czech Republic); Cerny, Frantisek [Department of Physics, Faculty of Mechanical Engineering, Czech Technical University in Prague, Technicka 4, 16607 Prague (Czech Republic); Drahokoupil, Jan [Department of Metals, Institute of Physics, AS CR, v.v.i., Na Slovance 2, 182 21 Prague (Czech Republic); Sepitka, Josef [Department of Mechanics, Biomechanics and Mechatronics, Faculty of Mechanical Engineering, Czech Technical University in Prague, Technicka 4, 16607 Prague (Czech Republic); Tolde, Zdenek [Department of Materials Engineering, Faculty of Mechanical Engineering, Czech Technical University in Prague, Technicka 4, 16607 Prague (Czech Republic)

    2015-01-25

    Highlights: • The Ti6Al4V samples were implanted with 90 keV nitrogen ions. • The samples were annealed at 500 °C during the ion implantation process. • An elevated temperature increases the mobility of the atoms and the quantity of TiN. • The hardness showed a significant increase compared to room temperature implantation. - Abstract: The effect of an elevated temperature during nitrogen ion implantation on the microstructure and on the surface hardness of Ti6Al4V titanium alloy was examined. The implantation process was carried out at fluences of 1 ⋅ 10{sup 17}, 2.7 ⋅ 10{sup 17} and 6 ⋅ 10{sup 17} cm{sup −2} and at ion energy 90 keV. The implanted samples were annealed at 500 °C during the implantation process. X-ray diffraction analysis was performed to obtain a phase characterization and a phase quantification in the implanted sample surface. The surface hardness was investigated by nanoindentation testing, and the nitrogen depth distribution was measured by Rutherford Backscattering Spectroscopy. Elevated temperature led to increased formation of a TiN compound. It was found that a mixture of TiN and an α-Ti(+N) solid solution had a predominant amount of TiN for samples with fluence of 2.7 ⋅ 10{sup 17} cm{sup −2} or higher. Elevated temperature during ion implantation caused an increase in surface hardening more towards the depth of the substrate in comparison with room temperature implantation. The hardness showed a remarkably significant increase at a fluence of 1 ⋅ 10{sup 17} and 2.7 ⋅ 10{sup 17} cm{sup −2} compared to samples implanted at the same fluences and at room temperature. There is a discussion of such mechanisms that explain the observed hardening more towards the depth of the substrate, and the increase in hardness.

  18. Composition and hardness of mullite coatings formed with direct current power supply on LY12 aluminum alloy surface

    Institute of Scientific and Technical Information of China (English)

    XIN Shi-gang; JIANG Zhao-hua; LI Yan-ping; ZHANG Ji-lin

    2005-01-01

    The surface modification of aluminum and its alloys using plasma technology is increasingly being investigated. Thick ceramic coatings with high hardness on aluminum alloys can be prepared successfully using a micro-plasma oxidation (MPO) technique. In this work, the composition, microstructure and elemental distribution of ceramic coatings formed by MPO on LY 12 aluminum alloy and its hardness are investigated using XRD, EPMA and microhardness instruments. The results show that the ceramic coatings consist of mullite, γ -Al2 O3 and a lot of amorphous matter. The content of silicon in the coatings increases from interface to the coatings, however, the content of aluminum decreases along this direction. The maximum hardness of ceramic coatings is up to 9. 2 GPa.

  19. Study of variation in surface morphology, chemical composition, crystallinity and hardness of laser irradiated silver in dry and wet environments

    Science.gov (United States)

    Ali, Nisar; Bashir, Shazia; Umm-i-Kalsoom; Begum, Narjis; Hussain, Tousif

    2017-07-01

    Variation in surface morphology, chemical composition, crystallinity and hardness of laser irradiated silver in dry and wet ambient environments has been investigated. For this purpose, the silver targets were exposed for various number of laser pulses in ambient environment of air, ethanol and de-ionized water for various number of laser pulses i.e. 500, 1000, 1500 and 2000. Scanning Electron Microscope (SEM) was employed to investigate the surface morphology of irradiated silver. SEM analysis reveals significant surface variations for both dry and wet ambient environments. For lower number of pulses, in air environment significant mass removal is observed but in case of ethanol no significant change in surface morphology is observed. In case of de-ionized water small sized cavities are observed with formation of protrusions with spherical top ends. For higher number of laser pulses, refilling of cavities by shock liquefied material, globules and protrusions are observed in case of dry ablation. For ablation in ethanol porous and coarse periodic ripples are observed whereas, for de-ionized water increasing density of protrusions is observed for higher number of pulses. EDS analysis exhibits the variation in chemical composition along with an enhanced diffusion of oxygen under both ambient conditions. The crystal structure of the exposed targets were explored by X-ray Diffraction (XRD) technique. XRD results support the EDS results. Formation of Ag2O in case of air and ethanol whereas, Ag2O and Ag3O in case of de-ionized water confirms the diffusion of oxygen into the silver surface after irradiation. Vickers Hardness tester was employed to measure the hardness of laser treated targets. Enhanced hardness is observed after irradiation in both dry and wet ambient environments. Initial decrease and then increase in hardness is observed with increase in number of laser pulses in air environment. In case of ethanol, increase in number of laser pulses results in

  20. In situ plasma fabrication of ceramic-like structure on polymeric implant with enhanced surface hardness, cytocompatibility and antibacterial capability.

    Science.gov (United States)

    Liu, Jun; Zhang, Wei; Shi, Haigang; Yang, Kun; Wang, Gexia; Wang, Pingli; Ji, Junhui; Chu, Paul K

    2016-05-01

    Polymeric materials are commonly found in orthopedic implants due to their unique mechanical properties and biocompatibility but the poor surface hardness and bacterial infection hamper many biomedical applications. In this study, a ceramic-like surface structure doped with silver is produced by successive plasma implantation of silicon (Si) and silver (Ag) into the polyamine 66 (PA66) substrate. Not only the surface hardness and elastic modulus are greatly enhanced due to the partial surface carbonization and the ceramic-like structure produced by the reaction between energetic Si and the carbon chain of PA66, but also the antibacterial activity is improved because of the combined effects rendered by Ag and SiC structure. Furthermore, the modified materials which exhibit good cytocompatibility upregulate bone-related genes and proteins expressions of the contacted bone mesenchymal stem cells (BMSCs). For the first time, it explores out that BMSCs osteogenesis on the antibacterial ceramic-like structure is mediated via the iNOS and nNOS signal pathways. The results reveal that in situ plasma fabrication of an antibacterial ceramic-like structure can endow PA66 with excellent surface hardness, cytocompatibility, as well as antibacterial capability.

  1. Diamond-like carbon coatings enhance the hardness and resilience of bearing surfaces for use in joint arthroplasty.

    Science.gov (United States)

    Roy, M E; Whiteside, L A; Xu, J; Katerberg, B J

    2010-04-01

    The purpose of this study was to evaluate the potential of a hard diamond-like carbon (DLC) coating to enhance the hardness and resilience of a bearing surface in joint replacement. The greater hardness of a magnesium-stabilized zirconium (Mg-PSZ) substrate was expected to provide a harder coating-substrate composite microhardness than the cobalt-chromium alloy (CoCr) also used in arthroplasty. Three femoral heads of each type (CoCr, Mg-PSZ, DLC-CoCr and DLC-Mg-PSZ) were examined. Baseline (non-coated) and composite coating/substrate hardness was measured by Vickers microhardness tests, while nanoindentation tests measured the hardness and elastic modulus of the DLC coating independent of the Mg-PSZ and CoCr substrates. Non-coated Mg-PSZ heads were considerably harder than non-coated CoCr heads, while DLC coating greatly increased the microhardness of the CoCr and Mg-PSZ substrates. On the nanoscale the non-coated heads were much harder than on the microscale, with CoCr exhibiting twice as much plastic deformation as Mg-PSZ. The mechanical properties of the DLC coatings were not significantly different for both the CoCr and Mg-PSZ substrates, producing similar moduli of resilience and plastic resistance ratios. DLC coatings greatly increased hardness on both the micro and nano levels and significantly improved resilience and resistance to plastic deformation compared with non-coated heads. Because Mg-PSZ allows less plastic deformation than CoCr and provides a greater composite microhardness, DLC-Mg-PSZ will likely be more durable for use as a bearing surface in vivo.

  2. Flywheel starter ring gear failures and hardness variation reduction in surface hardening process

    Directory of Open Access Journals (Sweden)

    Selçuk Can Yücel

    2015-10-01

    This technical paper summarizes the case study conducted for truck flywheel starter ring gears with diameter of 470 mm in order to reduce hardness variation by optimization of induction hardening and tempering processes.

  3. Flywheel starter ring gear failures and hardness variation reduction in surface hardening process

    OpenAIRE

    Selçuk Can Yücel; Levent Özenli; Türker Gençol; Ersoy Alanyalı

    2015-01-01

    In general technical applications, truck heavy duty engine flywheel starter ring gears teeth is conventionally induction hardened and tempered in order to meet metallurgical aspects on specification. Especially for large sectioned starter ring gears (in this case diameter of the gear is 470 mm) the critical issue is to maintain a stable hardness distribution on gear cross sections. These hardness variations in process could yield to: 1. High scrap costs due to out of specification parts. ...

  4. Integration Process Development for Improved Compatibility with Organic Non-Porous Ultralow-k Dielectric Fluorocarbon on Advanced Cu Interconnects

    Science.gov (United States)

    Gu, Xun; Tomita, Yugo; Nemoto, Takenao; Miyatani, Kotaro; Saito, Akane; Kobayashi, Yasuo; Teramoto, Akinobu; Kuroda, Rihito; Kuroki, Shin-Ichiro; Kawase, Kazumasa; Nozawa, Toshihisa; Matsuoka, Takaaki; Sugawa, Shigetoshi; Ohmi, Tadahiro

    2012-05-01

    Integration of an organic non-porous ultralow-k dielectric, fluorocarbon (k= 2.2), into advanced Cu interconnects was demonstrated. The challenges of process-induced damage, such as delamination and variances of both the structure and electrical properties of the fluorocarbon during fabrication, were investigated on Cu/fluorocarbon damascene interconnects. A titanium-based barrier layer, instead of a tantalum-based barrier layer, was used to avoid delamination between Cu and fluorocarbon in Cu/fluorocarbon interconnects. A moisture-hermetic dielectric protective layer was also effective to avoid damage induced by wet chemical cleaning. On the other hand, a post-etching nitrogen plasma treatment to form a stable protective layer on the surface of the fluorocarbon was proposed for the practical minimization of damage introduction to fluorocarbon in the following damascene process, such as post-etching cleaning.

  5. 21 CFR 888.3353 - Hip joint metal/ceramic/polymer semi-constrained cemented or nonporous uncemented prosthesis.

    Science.gov (United States)

    2010-04-01

    ... cemented or nonporous uncemented prosthesis. 888.3353 Section 888.3353 Food and Drugs FOOD AND DRUG... prosthesis. (a) Identification. A hip joint metal/ceramic/polymer semi-constrained cemented or nonporous uncemented prosthesis is a device intended to be implanted to replace a hip joint. This device...

  6. Microstructure, Hardness and Impact Toughness of Heat-Treated Nanodispersed Surface and Friction Stir-Processed Aluminum Alloy AA7075

    Science.gov (United States)

    Refat, M.; Elashery, A.; Toschi, S.; Ahmed, M. M. Z.; Morri, A.; El-Mahallawi, I.; Ceschini, L.

    2016-11-01

    Friction stir processing (FSP) is a recent surface engineering processing technique that is gaining wide recognition for manufacturing nanodispersed surface composites, which are of high specific strength, hardness and resistance to wear and corrosion. Herein, four-pass FSP was applied on aluminum alloy 7075 (AA7075-O) with and without the addition of alumina nanoparticles (Al2O3) of average size 40 nm. All FSP parameters were constant at 40 mm/min transverse speed, 500 rpm and tilt angle of 3°. FSP rotation direction was reversed every other pass. The friction stir-processed materials were sectioned and solution treated at 515 °C for 1.5 h, followed by age hardening at 120 °C for 12, 24, 36, 48 and 60 h. The effect of heat treatment regimes on microstructure, hardness and toughness was examined, as well as the fracture mode. The new friction stir-processed surfaces without and with nanodispersion showed enhancement in the hardness of the surface of the AA7075-O material (65 HV) to almost a double (100 and 140 HV) after four-pass FSP (before heat treatment) without and with incorporating nanoalumina particles, respectively. After 48-h aging at 120 °C, a significant enhancement in impact toughness was achieved for both the friction stir-processed without and with nanodispersion (181 and 134 J, respectively), compared to the reference material AA7075 in T6 condition (104 J).

  7. Fabrication of hard-coated optical absorbers with microstructured surfaces using etched ion tracks: Toward broadband ultra-low reflectance

    Energy Technology Data Exchange (ETDEWEB)

    Amemiya, Kuniaki, E-mail: k.amemiya@aist.go.jp [National Metrology Institute of Japan (NMIJ), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8563 (Japan); Koshikawa, Hiroshi; Yamaki, Tetsuya; Maekawa, Yasunari [Quantum Beam Science Center, Japan Atomic Energy Agency (JAEA), 1233 Watanuki, Takasaki, Gunma 370-1292 (Japan); Shitomi, Hiroshi; Numata, Takayuki; Kinoshita, Kenichi; Tanabe, Minoru; Fukuda, Daiji [National Metrology Institute of Japan (NMIJ), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8563 (Japan)

    2015-08-01

    Highlights: • A hard-coated optical absorber with microstructured surface was fabricated. • Etched ion tracks coated with diamond-like carbon were used. • The reflectance was below 2% for wavelengths in the 400–1400 nm range. • Fabricated optical absorber exhibited temporal durability and mechanical stability. • Further improvement of the design and process will yield reflectance of ∼0.1%. - Abstract: Broadband low reflectance materials have various applications in the field of optical energy management; however, materials with ultra-low reflectance (below 0.1%) have been considered as mechanically delicate. We have developed a novel hard-surface optical absorber with microstructured, diamond-like carbon coated ion tracks on CR-39 plastic substrate. The spectral reflectance of the first prototype was below 2% for wavelengths ranging from 400 nm to 1400 nm; moreover, the optical absorber had mechanically hard surface and exhibited temporal durability. Choosing the appropriate design of the surface structure and coating layer is likely to reduce the reflectance to the order of 0.1%. This technique yields easy-to-handle broadband ultra-low reflectance absorbers.

  8. Bacteriophages reduce experimental contamination of hard surfaces, tomato, spinach, broccoli, and ground beef by Escherichia coli O157:H7.

    Science.gov (United States)

    Abuladze, Tamar; Li, Manrong; Menetrez, Marc Y; Dean, Timothy; Senecal, Andre; Sulakvelidze, Alexander

    2008-10-01

    A bacteriophage cocktail (designated ECP-100) containing three Myoviridae phages lytic for Escherichia coli O157:H7 was examined for its ability to reduce experimental contamination of hard surfaces (glass coverslips and gypsum boards), tomato, spinach, broccoli, and ground beef by three virulent strains of the bacterium. The hard surfaces and foods contaminated by a mixture of three E. coli O157:H7 strains were treated with ECP-100 (test samples) or sterile phosphate-buffered saline buffer (control samples), and the efficacy of phage treatment was evaluated by comparing the number of viable E. coli organisms recovered from the test and control samples. Treatments (5 min) with the ECP-100 preparation containing three different concentrations of phages (10(10), 10(9), and 10(8) PFU/ml) resulted in statistically significant reductions (P = E. coli O157:H7 organisms recovered from the glass coverslips. Similar treatments resulted in reductions of 100%, 95%, and 85%, respectively, in the number of E. coli O157:H7 organisms recovered from the gypsum board surfaces; the reductions caused by the two most concentrated phage preparations were statistically significant. Treatment with the least concentrated preparation that elicited significantly less contamination of the hard surfaces (i.e., 10(9) PFU/ml) also significantly reduced the number of viable E. coli O157:H7 organisms on the four food samples. The observed reductions ranged from 94% (at 120 +/- 4 h posttreatment of tomato samples) to 100% (at 24 +/- 4 h posttreatment of spinach samples). The data suggest that naturally occurring bacteriophages may be useful for reducing contamination of various hard surfaces, fruits, vegetables, and ground beef by E. coli O157:H7.

  9. Pulsed erbium laser ablation of hard dental tissue: the effects of atomized water spray versus water surface film

    Science.gov (United States)

    Freiberg, Robert J.; Cozean, Colette D.

    2002-06-01

    It has been established that the ability of erbium lasers to ablate hard dental tissue is due primarily to the laser- initiated subsurface expansion of the interstitial water trapped within the enamel and that by maintaining a thin film of water on the surface of the tooth, the efficiency of the laser ablation is enhanced. It has recently been suggested that a more aggressive ablative mechanism, designated as a hydrokinetic effect, occurs when atomized water droplets, introduced between the erbium laser and the surface of the tooth, are accelerated in the laser's field and impact the tooth's surface. It is the objective of this study to determine if the proposed hydrokinetic effect exists and to establish its contribution to the dental hard tissue ablation process. Two commercially available dental laser systems were employed in the hard tissue ablation studies. One system employed a water irrigation system in which the water was applied directly to the tooth, forming a thin film of water on the tooth's surface. The other system employed pressurized air and water to create an atomized mist of water droplets between the laser hand piece and the tooth. The ablative properties of the two lasers were studied upon hard inorganic materials, which were void of any water content, as well as dental enamel, which contained interstitial water within its crystalline structure. In each case the erbium laser beam was moved across the surface of the target material at a constant velocity. When exposing material void of any water content, no ablation of the surfaces was observed with either laser system. In contrast, when the irrigated dental enamel was exposed to the laser radiation, a linear groove was formed in the enamel surface. The volume of ablated dental tissue associated with each irrigation method was measured and plotted as a function of the energy within the laser pulse. Both dental laser systems exhibited similar enamel ablation rates and comparable ablated surface

  10. The Role of Diffusion Media in Nitriding Process on Surface Layers Characteristics of AISI 4140 with and without Hard Chrome Coatings

    Directory of Open Access Journals (Sweden)

    K.A. Widi

    2016-09-01

    Full Text Available The surface layer characteristics of the AISI 4140 tool steel treated by nitriding gas before and after hard chrome plating utilizing pure nitrogen diffusion media (fluidized bed reactor and the without gas (muffle reactor has been studied experimentally. The result shows that nitriding substrate with hard chrome layers has nitrogen atoms concentration almost twice greater than that without hard chrome layers. After being given a hard chrome plating, nitriding on AISI 4140 steel generally has a nitrogen concentration of up to 4 times more than the substrate without hard chrome coating. Almost the entire specimen showed the highest concentration of N atoms in the area below the surface (hardening depth of 200 to 450 µm. N atoms diffusion depth profile has a correlation with hardening depth profile, especially on the specimens layered with hard chromium. The substrate without hard chrome plating tends to have higher surface hardness than the sub-surface. The results show that the effectiveness and efficiency of the gas nitriding diffusion process can be produced without the use of gas in the muffle reactor but the specimens must be hard chromium coated first. This phenomenon can be explained by the role of the passive layer formation that works as a barrier to keeps the spreading of N atoms concentrated in sub-surface areas.

  11. Influence of mouth rinses on the surface hardness of dental resin nano-composite.

    Science.gov (United States)

    Khan, Aftab Ahmed; Siddiqui, Adel Zia; Mohsin, Syed Fareed; Al-Kheraif, Abdulaziz A

    2015-01-01

    The aim of this research was to assess the effect of mouth rinses with and without alcohol on the hardness of dental nano-filled composite. The micro-hardness of fifty circular disk shaped specimens of 7 mm x 2 mm were measured after 14 days. Specimens were immersed into alcohol containing (Listerine and Colgate Perioguard) and alcohol-free (Prodent and Sensodyne Oral antiseptic) mouth rinse solutions. Artificial saliva served as the control. Vickers Micro-hardness was measured with a 30gram load for 30 seconds dwell time by using a diamond indenter. Significant differences were represented by pSensodyne Oral antiseptic mouth rinses with control group(p>0.05). Control specimens depicted highest value of micro-hardness(60.5746 ± 3.2703) compared to the lowest value seen in specimens immersed in Listerine solvent(54.4687 ± 1.0937). Alcohol containing mouth rinsing solutions have more deleterious effect on hardness of nano composites as compared to alcohol-free mouth rinses.

  12. Study of surface roughness and flank wear in hard turning of AISI 4140 steel with coated ceramic inserts

    Energy Technology Data Exchange (ETDEWEB)

    Das, Sudhansu Ranjan; Kuma, Amaresh [National Institute of Technology, Jamshedpur (India); Dhupal, Debabrata [Veer Surendra Sai University of Technology, Burla (India)

    2015-10-15

    This experimental investigation deals with dry hard turning of AISI 4140 steel using PVD-TiN coated Al{sub 2}O{sub 3}+TiCN mixed ceramic inserts. The combined effect of cutting parameters (cutting speed, feed and depth of cut) on performance characteristics such as surface roughness and flank wear is explored by Full factorial design (FFD) and analysis of variance (ANOVA). The results show that feed is the principal cutting parameter influencing surface roughness, followed by cutting speed. However, flank wear is affected by the cutting speed and interaction of feed-depth of cut, although depth of cut has not been found statistically significant, but flank wear is an increasing function of depth of cut. Observations are made on the machined surface, and worn tool by Scanning electron microscope (SEM) to establish the process. Abrasion was the major wear mechanism found during hard turning within the studied range. The effect of tool wear on surface roughness was also studied. The experimental data were analyzed to predict the optimal range of surface roughness and flank wear. Based on Response surface methodology (RSM), mathematical models were developed for surface roughness (Ra) and flank wear (VB) with 95% confidence level. Finally, under optimum cutting conditions (obtained by response optimization technique), tool life was evaluated to perform cost analysis for justifying the economic viability of coated ceramic inserts in hard turning. The estimated machining cost per part for TiN coated ceramic was found to be lower (Rs. 12.31) because of higher tool life (51 min), which results in the reduction of downtime and increase in savings.

  13. Experimental investigation and modelling of surface roughness and resultant cutting force in hard turning of AISI H13 Steel

    Science.gov (United States)

    Boy, M.; Yaşar, N.; Çiftçi, İ.

    2016-11-01

    In recent years, turning of hardened steels has replaced grinding for finishing operations. This process is compared to grinding operations; hard turning has higher material removal rates, the possibility of greater process flexibility, lower equipment costs, and shorter setup time. CBN or ceramic cutting tools are widely used hard part machining. For successful application of hard turning, selection of suitable cutting parameters for a given cutting tool is an important step. For this purpose, an experimental investigation was conducted to determine the effects of cutting tool edge geometry, feed rate and cutting speed on surface roughness and resultant cutting force in hard turning of AISI H13 steel with ceramic cutting tools. Machining experiments were conducted in a CNC lathe based on Taguchi experimental design (L16) in different levels of cutting parameters. In the experiments, a Kistler 9257 B, three cutting force components (Fc, Ff and Fr) piezoelectric dynamometer was used to measure cutting forces. Surface roughness measurements were performed by using a Mahrsurf PS1 device. For statistical analysis, analysis of variance has been performed and mathematical model have been developed for surface roughness and resultant cutting forces. The analysis of variance results showed that the cutting edge geometry, cutting speed and feed rate were the most significant factors on resultant cutting force while the cutting edge geometry and feed rate were the most significant factor for the surface roughness. The regression analysis was applied to predict the outcomes of the experiment. The predicted values and measured values were very close to each other. Afterwards a confirmation tests were performed to make a comparison between the predicted results and the measured results. According to the confirmation test results, measured values are within the 95% confidence interval.

  14. Capillary liquid chromatography separations using non-porous pillar array columns

    NARCIS (Netherlands)

    de Malsche, Wim; de Bruyne, S.; op de Beek, J.; Sandra, P.; Gardeniers, Johannes G.E.; Desmet, G.; Lynen, F.

    2012-01-01

    We report on a series of explorative experiments wherein a non-porous pillar array column (NP-PAC) is coupled to a commercial capillary LC instrument. The performance of the system was evaluated by both non-retained and retained experiments using several types of samples. In order to minimize

  15. Capillary liquid chromatography separations using non-porous pillar array columns

    NARCIS (Netherlands)

    Malsche, de D.M.W.; Bruyne, de S.; Beek, op de J.; Sandra, P.; Gardeniers, J.G.E.; Desmet, G.; Lynen, F.

    2012-01-01

    We report on a series of explorative experiments wherein a non-porous pillar array column (NP-PAC) is coupled to a commercial capillary LC instrument. The performance of the system was evaluated by both non-retained and retained experiments using several types of samples. In order to minimize interf

  16. Surface roughness-aided hard X-ray emission from carbon nanotubes

    Indian Academy of Sciences (India)

    Suman Bagchi; P Prem Kiran; M K Bhuyan; M Krishnamurthy; K Yang; A M Rao; G Ravindra Kumar

    2010-12-01

    Efficient low debris hard X-ray source based on multiwalled carbon nanotubes (MWNT) irradiated by intense, femtosecond laser over an intensity range of 1015 –1017 W cm−2 2 is reported. The MWNT targets yield two orders of magnitude higher X-rays (indicating significant enhancement of laser coupling) and three orders of magnitude lower debris compared to conventional metallic targets under identical experimental conditions. The simple analytical model explains the basic experimental observations and also serves as a guide to design efficient targets to achieve low-debris laser plasma-based hard X-ray sources at low laser intensities suitable for multi-kHz operation.

  17. Hardness of celluloid strip-finished or polished composite surfaces with time

    OpenAIRE

    Park, S. H.; KREJCI,Ivo; Lutz, F

    2000-01-01

    An in-vitro study revealed that a celluloid strip-finished composite surface discolored more than the polished composite surface. Thus, the celluloid strip-finished composite surface may not cure enough compared with the polished composite surface.

  18. The effect of three different mouthrinses on the surface hardness, gloss and colour change of bleached nano composite resins.

    Science.gov (United States)

    Gurgan, Sevil; Yalcin Cakir, Filiz

    2008-09-01

    This in vitro study evaluated the effects of three mouthrinses (Listerine--alcohol containing, Oral B--alcohol free and Rembrandt Plus--peroxide whitening rinse) on the surface hardness, gloss and colour of a nanofill (Filtek Supreme) and nanohybrid (Simile) composite resin that had been subjected to bleaching treatment. 30 specimens of each material were fabricated and randomly divided into three groups of 10. The hardness, gloss and CIE Lab colour parameters of each specimen were assessed prior to the experiments. Specimens were exposed to the 10% carbamide peroxide bleaching agent (Vivastyle) for 2 hours per day for 14 days. Following the bleaching treatment measurements were repeated. The specimens were then conditioned with mouthrinses for 12 hours which was equivalent in time to 1 year of two minutes daily use. The specimens were measured again for hardness, gloss and colour and data were subjected to the statistical analysis. The result of this study showed no statististical difference between the restorative materials after bleaching and the use of mouthrinses (p > 0.05). Bleaching treatment and the use of mouthrinses af fected the hardness, gloss and colour of both resins. Significant differences were observed with the use of mouthrinses for all parameters (p < 0.05). Rembrandt Plus promoted the greatest changes, followed by Listerine and Oral B.

  19. Effect of LED curing on the microleakage, shear bond strength and surface hardness of a resin-based composite restoration.

    Science.gov (United States)

    Oberholzer, Theunis G; Du Preez, Ignatius C; Kidd, M

    2005-06-01

    To determine the effect of Light emitting diode (LED) curing on dental resins, microleakage, shear bond strength and surface hardness of a dental composite cured with different LEDs were determined and compared with conventional halogen curing. For microleakage, Class V cavities were restored with Esthet-X, divided into groups, and exposed to one of the curing protocols (Elipar Freelight in soft start and standard modes; Ultra-Lume 2; Spectrum 800). Standard dye penetration tests were performed and the data summarised in a 2-way contingency table of observed frequencies. The Chi-square test was used (psurface hardness, samples of Esthet-X were exposed to the light-curing units (LCUs). Vickers hardness was determined on the upper and the bottom surfaces. Data was subjected to statistical analysis using ANOVA (phardness score for the halogen light was significantly lower than for the LED lights (p<0.01). The Spectrum 800 and the Elipar Freelight (soft start) have significantly higher shear bond strengths than the others (p<0.01). It was concluded that the LED source is more efficient for a comparable overall power output.

  20. Surface roughness and hardness of yttria stabilized zirconia (Y-TZP after 10 years of simulated brushing

    Directory of Open Access Journals (Sweden)

    Lucas Miguel Candido

    Full Text Available Introduction: The Y-TZP zirconia used for prosthetic infrastructure, in some clinical situations, can be exposed to the oral environment. In these situations, a polished surface without changes is extremely important. Objective: The aim of this study was to evaluate the mean roughness (Ra and Vickers hardness of Y-TZP zirconia (Lava™ after simulating ten years of brushing. Material and method: Thirty-six Y-TZP bar-shaped specimens (20mm X 4mm X 1.2mm were divided into three groups: storage in distilled water (DW, n=12, control; brushing with distilled water (BDW, n=12 and brushing with distilled water and fluoride toothpaste (BFT, n=12. Brushing was performed using a brushing machine with a soft-bristled toothbrush, simulating 10 years of brushing (878.400 cycles, 100gf. The mean roughness (Ra in μm and Vickers hardness (VHN of all specimens were measured twice: before and after the experimental treatment, in profilometer and microhardness tester (500gf, 30 seconds, respectively. Data were analyzed using the two-way ANOVA test (α = 0.05. Result: The interaction between groups was not significant for roughness (p = 0.701 nor for hardness (p = 0.928. The final averages for Ra (μm were equal to: DW - 0.63; BDW - 0.64; and, BFT - 0.68. The final averages for Vickers hardness (VHN were: DW - 1301.16; BDW - 1316.60; and, BFT - 1299.58. Conclusion: It was concluded that the brushing with distilled or fluoridated toothpaste was not able to change the roughness and hardness of Y-TZP zirconia used in this study.

  1. MODIFICATION OF CARBON STEEL BY LASER SURFACE MELTING: PART I: EFFECT OF LASER BEAM TRAVELLING SPEED ON MICROSTRUCTURAL FEATURES AND SURFACE HARDNESS

    Directory of Open Access Journals (Sweden)

    Hashem F. El-Labban

    2013-01-01

    Full Text Available The present study aims to improve the surface hardness of carbon steel by application of laser surface melting of effective conditions. The travelling speed of laser beam during this treatment is one of the important treatment conditions. This study aims to investigate the effect of laser surface melting with different beam speeds on macro and microstructure as well as the hardness distribution through the thickness of carbon steel. To achieve this target, three different travelling speeds (1500, 1000 and 500 mm min-1 at a constant beam power of 800 W were chosen in this study. The resulted laser treated specimens were investigated in macro and microscopically scale using optical and scanning electron microscope. Hardness measurements were also carried out through the thickness of the laser treated specimens. The laser treated areas with all used travelling speeds results in melted and solidified zone on the surface of the steel. In the same time, Plates of acicular martensite structure were observed within the upper part of the melted and solidified zone in almost all experimental conditions, while some bainite structure in ferrite grains are detected in its lower part. By increasing the travelling speed, the depth of the laser treated zone was decreases, while travelling speed has much less significant effect on the laser treated zone width. The size of the formed martensite plates was increased by decreasing the travelling speed from 1500 to 500 mm min-1. On the other hand, the travelling speed has a straight effect on the length of the acicular martensite; as the travelling speed increases, the acicular martensite became longer, while it shows fine acicular martensite at lower travelling speeds. The depth that full martensite structure can be reached is increased by increasing travelling speed. At lower travelling speed (500 mm min-1, large amount of bainite structure is observed at the center of the treated zone up to its lower end. The

  2. The effect of Coca-Cola and fruit juices on the surface hardness of glass-ionomers and 'compomers'.

    Science.gov (United States)

    Aliping-McKenzie, M; Linden, R W A; Nicholson, J W

    2004-11-01

    The interaction of tooth-coloured dental restorative materials (a conventional glass-ionomer, two resin-modified glass-ionomers and two compomers) with acidic beverages has been studied with the aim of investigating how long-term contact affects solution pH and specimen surface hardness. For each material (ChemFil Superior, ChemFlex, Vitremer Core Build-Up/Restorative, Fuji II LC, Dyract AP and F2000) disc-shaped specimens were prepared and stored in sets of six in the following storage media: 0.9% NaCl (control), Coca-Cola, apple juice and orange juice. After time intervals of 1 day, 1 week, 1 month, 3 months, 4 months, 6 months and 1 year, solution pH and Vickers Hardness Number were determined for each individual specimen. Differences were analysed by anova followed by Student-Newman-Keuls post hoc analysis. All materials were found to reduce the pH of the 0.9% NaCl, but to increase the pH of the acidic beverages. The conventional glass-ionomers dissolved completely in apple juice and orange juice, but survived in Coca-Cola, albeit with a significantly reduced hardness after 1 year. The other materials survived in apple juice and orange juice, but showed greater reductions in surface hardness in these beverages than in Coca-Cola. Fruit juices were thus shown to pose a greater erosive threat to tooth coloured materials than Coca-Cola, a finding which is similar to those concerning dentine and enamel towards these drinks.

  3. Softening Behavior of Hardness and Surface Fatigue of Rolling-Sliding Contact in the Case of Developed Alloy Steels

    Science.gov (United States)

    Redda, Daniel Tilahun; Nakanishi, Tsutomu; Deng, Gang

    To get high performance, downsizing and weight saving of the power transmission systems, the improvement of machine elements has been required. In this study, case-carburized gear materials for a high load-carrying capacity were developed. Low-alloyed steels with 1%Cr-0.2%Mo, 1%Cr-0.2%Mo-1%Si and 1%Cr-0.2%Mo-2%Ni (Cr-Mo steel, Cr-Mo-Si steel and Cr-Mo-Ni steel) were melted in a hypoxia vacuum. Test rollers were made of the developed steels, and they were carburized (Type A and Type B), hardened and tempered. Heating retention tests were carried out to investigate the softening behavior of hardness at high heating temperatures in the case of the developed steels. Roller tests were conducted under the rolling-sliding contact and high-load conditions to study the surface fatigue of the developed steels. From the obtained test results, it was found that the softening behavior of surface hardness at high temperatures in the cases of Cr-Mo-Si steel (Type A) and Cr-Mo-Ni steel (Type B) is lower than that in the cases of Cr-Mo steel (Type A) and Cr-Mo steel (Type B). In the cases of Cr-Mo-Si steel (A) and Cr-Mo-Ni steel (B), micro- and small-pitting area ratios are smaller and large-pitting life is longer than those in the cases of Cr-Mo steel(A) and Cr-Mo steel(B) under the same carburizing treatment method and high-load conditions. Furthermore, the relationship between the softening behavior of surface hardness on the heating pattern and the surface fatigue on the rolling-sliding contact of the developed alloy steels was clarified.

  4. Standard Test Method to Determine Color Change and Staining Caused by Aircraft Maintenance Chemicals upon Aircraft Cabin Interior Hard Surfaces

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2001-01-01

    1.1 This test method covers the determination of color change and staining from liquid solutions, such as cleaning or disinfecting chemicals or both, on painted metallic surfaces and nonmetallic surfaces of materials being used inside the aircraft cabin. The effects upon the exposed specimens are measured with the AATCC Gray Scale for Color Change and AATCC Gray Color Scale for Staining. Note 1—This test method is applicable to any colored nonmetallic hard surface in contact with liquids. The selected test specimens are chosen because these materials are present in the majority of aircraft cabin interiors. 1.2This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  5. The effect of different insertion techniques on the depth of cure and vickers surface micro-hardness of two bulk-fill resin composite materials

    Science.gov (United States)

    El-Hoshy, Ahmed-Zohair; Abou-Elenein, Karim

    2017-01-01

    Background The aim of this study was to evaluate the Vickers surface micro-hardness and the depth of cure of two bulk-fill resin composites and one incremental-fill resin composite. Material and Methods Two Bulk-fill dental resin composites (X-tra Fil, Voco; Sonic-FillTM 2, Kerr Corporation) and an incremental-fill dental resin composite (Filtek™ Z250 XT, 3M ESPE) were used. Sixty cylindrical specimens of 4 mm thickness were prepared using split Teflon moulds. Specimens were divided into six groups (n=10) according to the type of the material used and according to the insertion technique applied (bulk or incremental). Prepared specimens were stored dry in complete darkness at 37°C for 24 hours. All specimens were tested for their Vickers surface micro-hardness, on their top and bottom surfaces. The depth of cure of the tested specimens was assessed by calculating the hardness ratio for each specimen. The Vickers surface micro-hardness and depth of cure data were analyzed for normality using Kolmogorov-Smirnov and Shapiro-Wilk tests. Independent sample-t test was used to compare between two groups while One-way ANOVA was used to compare between more than two groups. Results Significant difference in the Vickers surface micro-hardness and depth of cure values was demonstrated among the tested materials (Pcure values (bottom/top hardness ratio) respectively while Z250 XT recorded 0.776±0.141. Conclusions X-tra Fil showed highest Vickers surface micro-hardness values on both top and bottom surfaces, whether inserted in increments or bulk. Both bulk-fill resin composites showed higher depth of cure for both insertion techniques. Key words:Depth of cure, Vickers surface micro-hardness, bulk-fill resin composite, insertion techniques. PMID:28210447

  6. Assessment of Tablet Surface Hardness by Laser Ablation and Its Correlation With the Erosion Tendency of Core Tablets.

    Science.gov (United States)

    Narang, Ajit S; Breckenridge, Lydia; Guo, Hang; Wang, Jennifer; Wolf, Abraham Avi; Desai, Divyakant; Varia, Sailesh; Badawy, Sherif

    2017-01-01

    Surface erosion of uncoated tablets results in processing problems such as dusting and defects during coating and is governed by the strength of particle bonding on tablet surface. In this study, the correlation between dusting tendency of tablets in a coating pan with friability and laser ablation surface hardness was assessed using tablets containing different concentrations of magnesium stearate and tartaric acid. Surface erosion propensity of different batches was evaluated by assessing their dusting tendency in the coating pan. In addition, all tablets were analyzed for crushing strength, friability, modified friability test using baffles in the friability apparatus, and weight loss after laser ablation. Tablets with similar crushing strength showed differences in their surface erosion and dusting tendency when rotated in a coating pan. These differences did not correlate well with tablet crushing strength or friability but did show reasonably good correlation with mass loss after laser ablation. These results suggest that tablet surface mass loss by laser ablation can be used as a minipiloting (small-scale) tool to assess tablet surface properties during early stages of drug product development to assess the risk of potential large-scale manufacturing issues.

  7. Effects of mouthwashes on Knoop hardness and surface roughness of dental composites after different immersion times

    Directory of Open Access Journals (Sweden)

    Diogo de Azevedo Miranda

    2011-04-01

    Full Text Available The aim of this in vitro study was to evaluate the effect of different mouthwashes on superficial roughness and Knoop hardness of two resin composites. Eighty specimens (6 mm Ø and 2 mm height were prepared and divided into eight experimental groups (n = 10 according to the resin composites (4 Seasons and Esthet X, and storage solutions (G1 - Distilled water; G2 - Colgate Plax Overnight; G3 - Colgate Plax Alcohol Free; and G4 - Colgate Plax Whitening. The initial hardness and roughness readings (T1 were measured and then the specimens were stored in 2 mL of mouthwash for 12 h (T2 and 24 h (T3. The data were analyzed with repeat-measures two-way ANOVA and Tukey's test (α = 5%. Regardless of the type of solution and time of exposure, there was no statistical difference for roughness between the resins (p = 0.44. G4 and G8 presented higher roughness means than G1, G3, G5 and G7, after 12 and 24 hours of immersion. For Knoop microhardness analysis, there was a significant reduction for all groups after 12 hours and 24 hours. We conclude that the mouthwashes containing hydrogen peroxide and/or alcohol decrease the microhardness of the resins tested; however, the mouthwash containing hydrogen peroxide had a higher deleterious effect on roughness.

  8. A Comparative Clinical Study of the Effect of Denture Cleansing on the Surface Roughness and Hardness of Two Denture Base Materials

    Science.gov (United States)

    Moussa, Amani Ramadan; Dehis, Wessam Mohamed; Elboraey, Asmaa Nabil; ElGabry, Hisham Samir

    2016-01-01

    AIM: This study aimed to verify the influence of oral environment and denture cleansers on the surface roughness and hardness of two different denture base materials. METHODS: A total of sixteen identical removable disc specimens (RDS) were processed. Eight RDS were made from heat-cured acrylic resin (AR) and the other eight were fabricated from thermoplastic injection moulded resin (TR). Surface roughness and hardness of DRS were measured using ultrasonic profilometry and Universal testing machine respectively. Then the four RDS (two AR and two of TR) were fixed to each maxillary denture, after three months RDS were retrieved. Surface roughness and hardness of RDS have measured again. RESULTS: The surface roughness measurements revealed no significant difference (p >0.05) for both disc groups at baseline. However, both groups showed a significant increase in the surface roughness after three months with higher mean value for (TR) group. On the other hand, the (AR) group showed higher hardness mean value than (TR) group at baseline with no significant decrease in the hardness values (p >0.05) following three months follow-up period. CONCLUSIONS: Denture cleansers have an effect on the denture’s surface roughness and hardness concurrently with an oral condition which will consequently influence the complete dentures’ lifetime and patients’ satisfaction. PMID:27703578

  9. Investigation of Plasma Spray Coatings as an Alternative to Hard Chrome Plating on Internal Surfaces

    Science.gov (United States)

    2006-09-14

    alloy Ni-988 Praxair WC-Co self fluxing 50%(WC 12Co) 50%(33Ni 9Cr 3.5Fe 2Si 2B 0.5C) SM 5803 Sulzer Metco (WC 12Co) 25(Ni-Based Superalloy ) SM...Micro Hardness [HV0.3] Cracks 10012402-1 SM 5803 (WC 12Co) 25(Ni-Based Superalloy ) Ar/He/H2 5.3 82.2 671 Micro cracks 10012502-1 D2002 (WC...o n V o lu m e L o ss ( m m 3 ) Figure 4-28. Abrasion resistance of EHC and plasma spray coatings. Ring Coated (block) disc Figure

  10. The toxicity of plastic nanoparticles to green algae as influenced by surface modification, medium hardness and cellular adsorption.

    Science.gov (United States)

    Nolte, Tom M; Hartmann, Nanna B; Kleijn, J Mieke; Garnæs, Jørgen; van de Meent, Dik; Jan Hendriks, A; Baun, Anders

    2017-02-01

    To investigate processes possibly underlying accumulation and ecological effects of plastic nano-particles we have characterized their interaction with the cell wall of green algae. More specifically, we have investigated the influence of particle surface functionality and water hardness (Ca(2+) concentration) on particle adsorption to algae cell walls. Polystyrene nanoparticles with different functional groups (non-functionalized, -COOH and -NH2) as well as coated (starch and PEG) gold nanoparticles were applied in these studies. Depletion measurements and atomic force microscopy (AFM) showed that adsorption of neutral and positively charged plastic nanoparticles onto the cell wall of P. subcapitata was stronger than that of negatively charged plastic particles. Results indicated that binding affinity is a function of both inter-particle and particle-cell wall interactions which are in turn influenced by the medium hardness and particle concentration. Physicochemical modelling using DLVO theory was used to interpret the experimental data, using also values for interfacial surface free energies. Our study shows that material properties and medium conditions play a crucial role in the rate and state of nanoparticle bio-adsorption for green algae. The results show that the toxicity of nanoparticles can be better described and assessed by using appropriate dose metrics including material properties, complexation/agglomeration behavior and cellular attachment and adsorption. The applied methodology provides an efficient and feasible approach for evaluating potential accumulation and hazardous effects of nanoparticles to algae caused by particle interactions with the algae cell walls.

  11. Hard electronics; Hard electronics

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Hard material technologies were surveyed to establish the hard electronic technology which offers superior characteristics under hard operational or environmental conditions as compared with conventional Si devices. The following technologies were separately surveyed: (1) The device and integration technologies of wide gap hard semiconductors such as SiC, diamond and nitride, (2) The technology of hard semiconductor devices for vacuum micro- electronics technology, and (3) The technology of hard new material devices for oxides. The formation technology of oxide thin films made remarkable progress after discovery of oxide superconductor materials, resulting in development of an atomic layer growth method and mist deposition method. This leading research is expected to solve such issues difficult to be easily realized by current Si technology as high-power, high-frequency and low-loss devices in power electronics, high temperature-proof and radiation-proof devices in ultimate electronics, and high-speed and dense- integrated devices in information electronics. 432 refs., 136 figs., 15 tabs.

  12. Nanostructured Hardening of Hard Alloys Surface Layers Through Electron Irradiation in Heavy Inert Gas Plasma Conditions

    Science.gov (United States)

    Ovcharenko, V. E.; Ivanov, Yu F.; Ivanov, K. V.; Mokhovikov, A. A.; Baohai, Yu; Hua, Xu Yun

    2016-08-01

    The paper presents research and experimental findings which prove that metal ceramic composite surface layer contains micro constituents’ hierarchies in the form of secondary nano sized inclusions inside ceramic phases. These inclusions have typical dimensions from several tens to several hundreds of nano meters. It has been shown that multi level structure-phase condition, developed in a nano sized area, effects physical and tribological properties of a metal ceramic composite surface layer.

  13. Formulation Effects and the Off-target Transport of Pyrethroid Insecticides from Urban Hard Surfaces

    OpenAIRE

    2010-01-01

    Controlled rainfall experiments utilizing drop forming rainfall simulators were conducted to study various factors contributing to off-target transport of off-the-shelf formulated pyrethroid insecticides from concrete surfaces. Factors evaluated included active ingredient, product formulation, time between application and rainfall (set time), and rainfall intensity. As much as 60% and as little as 0.8% of pyrethroid applied could be recovered in surface runoff depending primarily on product f...

  14. Laser desorption ionization-time-of-flight mass analysis of perfluoropolyether monolayer directly from hard disk medium surface.

    Science.gov (United States)

    Kudo, Toshiji; Macht, Marcus; Kuroda, Masami

    2011-07-15

    Modern life is dependent on computer technology, and because the volume of digital data in the world is increasing rapidly, the importance of data storage devices is also increasing rapidly. Among them, demands for magnetic disk drive well-known as hard disk drives is quite huge and information recording density on the disk media is continuing to grow dramatically. For the research and development of the magnetic disk media, it is critical to investigate and characterize the lubricant layer formed on the disk media surface. However, it is difficult because the layer is only a monolayer which has only approximately 1 nm thickness in many cases. Although matrix-assisted laser desorption ionization-time-of-flight-mass spectrometry (MALDI-TOF-MS) measurements of monolayers have already been reported (Su, J.; Mrksich, M. Langmuir, 2003, 19, 4867-4870), lubricants used here are (co)polymers which have molecular weight distributions and are mixtures of various degrees of polymerization. This can reduce the sensitivity of MS measurement because the number (or density) of distinct single molecular species is lower than for homogeneous samples. In this report, direct measurement and characterization of lubricant monolayers using the LDI-TOF-MS instrument is performed to gain insight into detailed information like average molecular weight, polymer distribution, and two-dimensional mapping directly from magnetic disk monolayers. To our knowledge, this is the first time such information was acquired directly from hard disk media. The technique reported here might open up new possibilities also for investigations of various electronic devices other than magnetic hard disks.

  15. Effects of Hard Surface Grinding and Activation on Electroless-Nickel Plating on Cast Aluminium Alloy Substrates

    Directory of Open Access Journals (Sweden)

    Olawale Olarewaju Ajibola

    2014-01-01

    Full Text Available This work examined effects of hard surface polishing grits and activation on electroless-nickel (EN plating on cast aluminium alloy substrates in sodium hypophosphite baths. As-received aluminium alloy sample sourced from automobile hydraulic brake master cylinder piston was melted in electric furnace and sand cast into rod. The cast samples were polished using different grits (60 μm–1200 μm before plating. The effects on adhesion, appearance, and quantity of EN deposits on substrates were studied. Observation shows that the quantity of EN deposit is partly dependent on the alloy type and roughness of the surface of the substrates, whereas the adhesion and brightness are not solely controlled by the degree of surface polishing. The best yield in terms of adhesion and appearance was obtained from the activation in zincate and palladium chloride solutions. Higher plating rates (g/mm2/min of 3.01E-05, 2.41E-05, and 2.90E-05 were obtained from chromate, zincate, and chloride than 8.49E-06, 8.86E-06, and 1.69E-05 as obtained from HCl etched, NaOH, and H2O activated surfaces, respectively.

  16. Influence of an Angular Hatching Exposure Strategy on the Surface Roughness During Picosecond Laser Ablation of Hard Materials

    Science.gov (United States)

    Daniel, Christian; Manderla, Jannik; Hallmann, Sina; Emmelmann, Claus

    Innovative chip breakers for cutting tools made of very hard materials require laser ablation and demand a high quality regarding the manufactured surface. When processing materials such as polycrystalline cubic boron-nitride or tungsten carbide the surface roughness by laser ablation reaches Sa = 1,0-2,9 μm compared to Sa = 0,42 μm achieved by grinding. Therefore in the presented research the influence of the hatching exposure strategy on surface roughness during picosecond laser ablation of tungsten carbide is examined. The areal, layerwise ablation process is separated into its elements which are represented by intersection zones between single and multiple laser vectors. Thus two mechanisms of roughness formation are identified and described by model functions. Further the mechanisms are transferred to areal ablation in which surface roughness decreases due to improved hatching angles compared to a commonly used one of φ= 0°/90°. With this approach the roughness is reduced by approximately factor 2,0-3,5 to Sa = 0,82 μm. In conclusion guidelines are derived which present favorable settings for high quality laser ablation processes.

  17. Hard X-ray photoelectron and X-ray absorption spectroscopy characterization of oxidized surfaces of iron sulfides

    Science.gov (United States)

    Mikhlin, Yuri; Tomashevich, Yevgeny; Vorobyev, Sergey; Saikova, Svetlana; Romanchenko, Alexander; Félix, Roberto

    2016-11-01

    Hard X-ray photoelectron spectroscopy (HAXPES) using an excitation energy range of 2 keV to 6 keV in combination with Fe K- and S K-edge XANES, measured simultaneously in total electron (TEY) and partial fluorescence yield (PFY) modes, have been applied to study near-surface regions of natural polycrystalline pyrite FeS2 and pyrrhotite Fe1-xS before and after etching treatments in an acidic ferric chloride solution. It was found that the following near-surface regions are formed owing to the preferential release of iron from oxidized metal sulfide lattices: (i) a thin, no more than 1-4 nm in depth, outer layer containing polysulfide species, (ii) a layer exhibiting less pronounced stoichiometry deviations and low, if any, concentrations of polysulfide, the composition and dimensions of which vary for pyrite and pyrrhotite and depend on the chemical treatment, and (iii) an extended almost stoichiometric underlayer yielding modified TEY XANES spectra, probably, due to a higher content of defects. We suggest that the extended layered structure should heavily affect the near-surface electronic properties, and processes involving the surface and interfacial charge transfer.

  18. The effect of different beverages on surface hardness of nanohybrid resin composite and giomer

    Directory of Open Access Journals (Sweden)

    Saijai Tanthanuch

    2014-01-01

    Full Text Available Aims: To investigate the effects of five beverages (apple cider, orange juice, Coca-Cola, coffee, and beer on microhardness and surface characteristic changes of nanohybrid resin composite and giomer. Materials and Methods: Ninety-three specimens of each resin composite and giomer were prepared. Before immersion, baseline data of Vicker′s microhardness was recorded and surface characteristics were examined using scanning electron microscopy (SEM. Five groups of discs (n = 18 were alternately immersed in 25 mL of each beverage for 5 s and in 25 mL of artificial saliva for 5 s for 10 cycles. Specimens were then stored in artificial saliva for 24 h. This process was repeated for 28 days. After immersion, specimens were evaluated and data were analyzed by two-way repeated analysis of variance (ANOVA, Tukey′s honestly significant difference (HSD, and a t-test (α = 0.05. Results: Microhardness of all groups significantly decreased after being immersed in the tested beverages (P < 0.05. SEM photomicrographs presented surface degradation of all groups. Conclusions: The effect of these beverages on the surface of both restorative materials also depended upon the exposure time and chemical composition of the restorative materials and beverages.

  19. Laser surface alloying (LSA) of aluminium (AA 1200) with TiB2 for hardness improvement

    CSIR Research Space (South Africa)

    Popoola, AP

    2010-10-01

    Full Text Available The present work deals with the development of Aluminium metal matrix composite (MMC) using TiB2 reinforcement. The aim is to improve the microhardness property of the substrate. The surface of the aluminium was sand blasted to improve its laser...

  20. Surface properties of poly(ethylene oxide)-based segmented block copolymers with monodisperse hard segments

    NARCIS (Netherlands)

    Husken, D.; Feijen, Jan; Gaymans, R.J.

    2009-01-01

    The surface properties of segmented block copolymers based on poly(ethylene oxide) (PEO) segments and monodisperse crystallizable tetra-amide segments were studied. The monodisperse crystallizable segments (T6T6T) were based on terephthalate (T) and hexamethylenediamine (6). Due to the crystallinity

  1. Surface roughness evaluation of various cutting materials in hard turning of AISI H11

    Directory of Open Access Journals (Sweden)

    H. Aouici

    2016-04-01

    Full Text Available This paper describes a comparison of surface roughness between ceramics and cubic boron nitride (CBN7020 cutting tools when machining of AISI H11 hot work steels treated at 50 HRC. Plan is designed according to Taguchi’s L18 (21×32 orthogonal array. The response surface methodology (RSM and analysis of variance (ANOVA were used to check the validity of multiple linear regression models and to determine the effects, contribution, significance and optimal machine settings of process parameters, namely, cutting speed, feed rate and depth of cut on machining parameters on the Ra and Rt. The results of this research work showed that, the feed rate was found to be a dominant factor on the surface roughness, followed by the cutting speed, lastly the depth of cut. The CBN7020 cutting tool showed the better performance than that of ceramic based cutting tool. In addition, the combination of low feed rate and high cutting speed is necessary for minimizing the surface roughness.

  2. Effects of conditioners on surface hardness of hair fibers: an investigation using atomic force microscopy.

    Science.gov (United States)

    Ruetsch, S B; Kamath, Y K; Kintrup, L; Schwark, H-J

    2003-01-01

    Conditioners are known to have a prophylactic effect on hair damage caused by cosmetic chemical treatments or mechanical grooming procedures. They are known to impart softness and smoothness to hair by moisturizing the fiber. Since the amount of conditioners deposited on the fiber is very small in quantity, it is conceivable that mainly the surface is moisturized. This is especially true of polymeric conditioners, which deposit preferentially on the surface of the fiber, rather than penetrate into the cortex. Therefore, this study strictly investigates whether cationic polymeric conditioners impart softness to the surface cuticle cell as a result of their hydrophilicity, with no regard to its applicability to cosmetic effects. Such softening can be detected by indentation of the surface and can be quantified by measuring the depth of the indent in real time. Atomic force microscopy (AFM), equipped with nano-indentation capability, is ideally suited for this purpose. In this work it was used to determine changes in the microhardness (micromechanical properties) of the hair fiber surface as a result of fiber/conditioner/moisture interactions. In a preliminary study, we observed that the scale faces of hair treated with Polyquaternium 10 (PQ-10) conditioner gave deeper indents, while scale edges yielded shallower ones in comparison to cuticle cells of untreated hair. This suggests that the conditioner softens the scale face and hardens the scale edges. However, because of significant amounts of conditioner residues left on the scale face, this conclusion was rather ambiguous. Therefore, the study was repeated in which multiple indentations were made on the surface cuticle cells of a larger number of the same hair fibers before and after multiple applications of the conditioner. This reduces errors due to fiber-to-fiber variation in pre-existing microhardness differences in surface cuticle cells. Also, the larger number of fibers investigated in the current work

  3. On the application of response surface methodology for predicting and optimizing surface roughness and cutting forces in hard turning by PVD coated insert

    Directory of Open Access Journals (Sweden)

    Hessainia Zahia

    2015-04-01

    Full Text Available This paper focuses on the exploitation of the response surface methodology (RSM to determine optimum cutting conditions leading to minimum surface roughness and cutting force components. The technique of RSM helps to create an efficient statistical model for studying the evolution of surface roughness and cutting forces according to cutting parameters: cutting speed, feed rate and depth of cut. For this purpose, turning tests of hardened steel alloy (AISI 4140 (56 HRC were carried out using PVD – coated ceramic insert under different cutting conditions. The equations of surface roughness and cutting forces were achieved by using the experimental data and the technique of the analysis of variance (ANOVA. The obtained results are presented in terms of mean values and confidence levels. It is shown that feed rate and depth of cut are the most influential factors on surface roughness and cutting forces, respectively. In addition, it is underlined that the surface roughness is mainly related to the cutting speed, whereas depth of cut has the greatest effect on the evolution of cutting forces. The optimal machining parameters obtained in this study represent reductions about 6.88%, 3.65%, 19.05% in cutting force components (Fa, Fr, Ft, respectively. The latters are compared with the results of initial cutting parameters for machining AISI 4140 steel in the hard turning process.

  4. The toxicity of plastic nanoparticles to green algae as influenced by surface modification, medium hardness and cellular adsorption

    DEFF Research Database (Denmark)

    Nolte, Tom M.; Hartmann, Nanna B.; Kleijn, J. Mieke

    2017-01-01

    To investigate processes possibly underlying accumulation and ecological effects of plastic nano-particles we have characterized their interaction with the cell wall of green algae. More specifically, we have investigated the influence of particle surface functionality and water hardness (Ca2......+ concentration) on particle adsorption to algae cell walls. Polystyrene nanoparticles with different functional groups (non-functionalized, −COOH and −NH2) as well as coated (starch and PEG) gold nanoparticles were applied in these studies. Depletion measurements and atomic force microscopy (AFM) showed...... that adsorption of neutral and positively charged plastic nanoparticles onto the cell wall of P. subcapitata was stronger than that of negatively charged plastic particles. Results indicated that binding affinity is a function of both inter-particle and particle-cell wall interactions which are in turn influenced...

  5. Condensation of steam on the surface of hard coated copper discs

    Science.gov (United States)

    Koch, G.; Zhang, D. C.; Leipertz, A.

    At atmospheric pressure filmwise (FWC) and dropwise (DWC) condensation have been studied on the surface of copper discs which were coated by silicon-modified amorpheous hydrogenated carbon (a-C:H-Si) films of different thickness. On vertically oriented surfaces the DWC heat transfer coefficients were found to be larger by a factor of about 10 than the FWC coefficients which follow as function of surface subcooling temperature quite well Nusselt's theory. Varying the angle of surface inclination, the DWC coefficient decreased down to about 40% of the vertical-surface values for 180° (face down orientation). The mean value for all inclination angles between 30° and 180° was calculated to be 87.6% of the maximum value for the 90°-orientation. Partly coating of the copper surface indicates a strong heat transfer enhancement of DWC over FWC even for relative small coated parts (e.g., 19%-coating yields an enhancement by a factor 2.3 for a cooling water flow rate of 4 m3/h). The diamond like properties of the a-C:H-coatings promise long stand times and thus application also in real technical condensation systems. Zusammenfassung Die Film-(FK) und Tropfenkondensation (TK) von Wasserdampf bei Umgebungsdruck wurde unter-sucht. Dabei wurden mit Silicium modifizierte amorphe Kohlenwasserstoff-Schichten (a-C:H-Si) in unterschiedlichen Dicken auf Kupferscheiben eingesetzt. Mit der TK werden an vertikal orientierten Kondensatoroberflächen Wärmeüber-gangskoeffizienten erreicht, die um den Faktor 10 größer sind als bei FK, deren Wärmeübergangskoeffizienten als Funktion der Unterkühlung in sehr guter Übereinstimmung zur Nusseltschen Wasserhauttheorie ermittelt wurden. Bei einer Wandneigung von 180° (waagerechte Wand und hängende Tropfen) betragen die Wärmeübergangskoeffizienten bei TK nur 40% der Maximalwerte, die bei vertikaler Orientierung erreicht werden. Der Mittelwert über die Neigungswinkel von 30°-180° wird berechnet zu 87.6% der Maximalwerte bei der 90

  6. Surface hardness evaluation of different composite resin materials: influence of sports and energy drinks immersion after a short-term period

    Directory of Open Access Journals (Sweden)

    Ugur Erdemir

    2013-04-01

    Full Text Available Objectives: This study evaluated the effect of sports and energy drinks on the surface hardness of different composite resin restorative materials over a 1-month period. Material and Methods: A total of 168 specimens: Compoglass F, Filtek Z250, Filtek Supreme, and Premise were prepared using a customized cylindrical metal mould and they were divided into six groups (N=42; n=7 per group. For the control groups, the specimens were stored in distilled water for 24 hours at 37°C and the water was renewed daily. For the experimental groups, the specimens were immersed in 5 mL of one of the following test solutions: Powerade, Gatorade, X-IR, Burn, and Red Bull, for two minutes daily for up to a 1-month test period and all the solutions were refreshed daily. Surface hardness was measured using a Vickers hardness measuring instrument at baseline, after 1-week and 1-month. Data were statistically analyzed using Multivariate repeated measure ANOVA and Bonferroni's multiple comparison tests (α=0.05. Results: Multivariate repeated measures ANOVA revealed that there were statistically significant differences in the hardness of the restorative materials in different immersion times (p<0.001 in different solutions (p<0.001. The effect of different solutions on the surface hardness values of the restorative materials was tested using Bonferroni's multiple comparison tests, and it was observed that specimens stored in distilled water demonstrated statistically significant lower mean surface hardness reductions when compared to the specimens immersed in sports and energy drinks after a 1-month evaluation period (p<0.001. The compomer was the most affected by an acidic environment, whereas the composite resin materials were the least affected materials. Conclusions: The effect of sports and energy drinks on the surface hardness of a restorative material depends on the duration of exposure time, and the composition of the material.

  7. Hard electronics; Hard electronics

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In the fields of power conversion devices and broadcasting/communication amplifiers, high power, high frequency and low losses are desirable. Further, for electronic elements in aerospace/aeronautical/geothermal surveys, etc., heat resistance to 500degC is required. Devices which respond to such hard specifications are called hard electronic devices. However, with Si which is at the core of the present electronics, the specifications cannot fully be fulfilled because of the restrictions arising from physical values. Accordingly, taking up new device materials/structures necessary to construct hard electronics, technologies to develop these to a level of IC were examined and studied. They are a technology to make devices/IC of new semiconductors such as SiC, diamond, etc. which can handle higher temperature, higher power and higher frequency than Si and also is possible of reducing losses, a technology to make devices of hard semiconducter materials such as a vacuum microelectronics technology using ultra-micro/high-luminance electronic emitter using negative electron affinity which diamond, etc. have, a technology to make devices of oxides which have various electric properties, etc. 321 refs., 194 figs., 8 tabs.

  8. Effects of Alloying Elements on Microstructure, Hardness, Wear Resistance, and Surface Roughness of Centrifugally Cast High-Speed Steel Rolls

    Science.gov (United States)

    Ha, Dae Jin; Sung, Hyo Kyung; Park, Joon Wook; Lee, Sunghak

    2009-11-01

    A study was made of the effects of carbon, tungsten, molybdenum, and vanadium on the wear resistance and surface roughness of five high-speed steel (HSS) rolls manufactured by the centrifugal casting method. High-temperature wear tests were conducted on these rolls to experimentally simulate the wear process during hot rolling. The HSS rolls contained a large amount (up to 25 vol pct) of carbides, such as MC, M2C, and M7C3 carbides formed in the tempered martensite matrix. The matrix consisted mainly of tempered lath martensite when the carbon content in the matrix was small, and contained a considerable amount of tempered plate martensite when the carbon content increased. The high-temperature wear test results indicated that the wear resistance and surface roughness of the rolls were enhanced when the amount of hard MC carbides formed inside solidification cells increased and their distribution was homogeneous. The best wear resistance and surface roughness were obtained from a roll in which a large amount of MC carbides were homogeneously distributed in the tempered lath martensite matrix. The appropriate contents of the carbon equivalent, tungsten equivalent, and vanadium were 2.0 to 2.3, 9 to 10, and 5 to 6 pct, respectively.

  9. Evaluation of the Biotic Ligand Model relative to other site-specific criteria derivation methods for copper in surface waters with elevated hardness.

    Science.gov (United States)

    Van Genderen, Eric; Gensemer, Robert; Smith, Carrie; Santore, Robert; Ryan, Adam

    2007-08-30

    The goal of this study was to evaluate the reliability of the Biotic Ligand Model to predict Cu toxicity in very hard surface water (>200 mg/L as CaCO(3)), relative to current copper criteria methodologies (hardness-based equation and the water-effect ratio; WER). To test these methods, we conducted acute Cu toxicity tests with three aquatic test species (Ceriodaphnia dubia, Daphnia pulex and Pimephales promelas) in seven surface waters. The sites were representative of effluent-dependent or effluent-dominated streams common to the arid western United States of America (arid West) and a wide range of water quality variables were tested. In addition, concurrent Cu toxicity tests were conducted in laboratory waters that were matched to hardness and alkalinity of the sites to facilitate calculation of WER values. Results were used to characterize empirical relationships between water quality characteristics and Cu toxicity, and to compare measured Cu toxicity with Biotic Ligand Model (BLM) predictions. Acute toxicity tests were also conducted with C. dubia and P. promelas in a range of Ca or Mg-dominated hardness concentrations to determine the independent effects of Ca or Mg on Cu toxicity at high hardness levels. Conclusions from this study suggest that the BLM generates appropriate criteria for the waters tested in this study when compared to the hardness-based equation or WER approach. Although the historical site-specific methods are useful for surface waters with hardness alkalinity, Ca, Mg and Na). Therefore, the BLM offers an improved alternative to the hardness-based and WER approaches, particularly for situations where the current methods would be under-protective of sensitive aquatic life.

  10. Effects of distance from tip of LED light-curing unit and curing time on surface hardness of nano-filled composite resin

    Science.gov (United States)

    Shafadilla, V. A.; Usman, M.; Margono, A.

    2017-08-01

    Polymerization process depends on several variables, including the hue, thickness, and translucency of the composite resin, the size of the filler particles, the duration of exposure to light (the curing time), the intensity of the light, and the distance from the light. This study aimed to analyze the effects of the distance from the tip of the light-emitting diode (LED) light-curing unit and of curing time on the surface hardness of nano-filled composite resin. 60 specimens were prepared in a mold and divided into 6 groups based on various curing distances and times: 2 mm, 5 mm, and 8 mm and 20 seconds and 40 seconds. The highest surface hardness was seen in the group both closest to the tip and having the longest curing time, while the lowest hardness was seen in the group both farthest from the tip and having the shortest curing time. Significant differences were seen among the various tip distances, except for in the two groups that had 8-mm tip distances, which had no significant differences due to curing time. Both decreased distance from the tip of the LED light-curing unit and increased curing time increase the surface hardness of nano-filled composite resin. However, curing time increases the surface hardness only if the tip distance is ≤ 5 mm.

  11. Dichotomy Between Black Hole and Neutron Star Accretion: Effect of Hard Surface

    Science.gov (United States)

    Dhang, Prasun; Mukhopadhyay, Banibrata; Sharma, Prateek

    2016-07-01

    Estimates of accretion rate on to compact objects have been explored based on the well-known, spherically symmetric, inviscid, steady-state solution given by Bondi. This solution assumes that there is a sink of mass at the center -- which in case of a black hole (BH) corresponds to the advection of matter across the event horizon. Other stars, such as a neutron star (NS), have surfaces and hence the infalling matter has to come to rest at the surface. We study the initial value problem in which the matter distribution is uniform and at rest at time t=0 with different inner radial boundary conditions for BHs and NSs: inflow boundary condition valid for BHs; and reflective or settling boundary condition for NSs. We obtain a similarity solution for the flow with inner inflow and reflective boundary conditions (assuming a cold ambient medium) and compare with numerical simulations of the Euler equations. One-dimensional simulations show the formation of an outward propagating and a standing shock in NS system for reflective and settling boundary conditions respectively. Two-dimensional simulations show that both these flows are unstable (locally to convection and globally to a standing shock instability). Numerical simulations show that in steady state, spherical accretion rate on to a NS for reflective boundary condition is suppressed by orders of magnitude compared to that on to a BH.

  12. Effect of fluoride-free and fluoridated carbamide peroxide gels on the hardness and surface roughness of aesthetic restorative materials

    Directory of Open Access Journals (Sweden)

    Homayoon Alaghehmand

    2013-01-01

    Full Text Available Background: Bleaching products may show some side effects on soft and hard tissues and restorative materials in the oral cavity. This study evaluated the effect of carbamide peroxide gel with and without fluoride ions on the microhardness and surface roughness of tooth-colored restorative materials. Materials and Methods: In this in-vitro study, 76 cubic specimens (4 mm 3 × 4 mm 3 × 3 mm 3 were fabricated from 4 aesthetic A3-shade restorative materials. These materials consisted of two composite resins and two glass ionomers. The specimens made from each material were treated with the following surface treatments: 1. Control group: The specimens were not bleached and were stored in normal saline. Group 2. Fluoridated 20% carbamide peroxide gel, treated 3 h a day for 4 weeks. Group 3. Treated 1 h a day with fluoride-less 22% carbamide peroxide for two weeks. From each group, three other specimens were selected to be evaluated in terms of changes in surface roughness, under scanning electron microscopy (SEM. Results: In this study, fluoridated 20% carbamide peroxide gel increased the microhardness of the four aesthetic restorative materials. The fluoride-free carbamide peroxide 22% reduced the microhardness of the four used materials, which this change was significant for Vitremer and Amelogen. SEM analyses showed changes in surface roughness of glass ionomer specimens. Conclusion: The effect of bleaching on the microhardness of restorative materials is material dependent. Before the application of bleaching systems on the glass ionomer materials, the application of a protective barrier should be considered.

  13. Hard X-ray photoelectron and X-ray absorption spectroscopy characterization of oxidized surfaces of iron sulfides

    Energy Technology Data Exchange (ETDEWEB)

    Mikhlin, Yuri, E-mail: yumikh@icct.ru [Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of sciences, Akademgorodok, 50/24, Krasnoyarsk, 660036 (Russian Federation); Tomashevich, Yevgeny [Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of sciences, Akademgorodok, 50/24, Krasnoyarsk, 660036 (Russian Federation); Vorobyev, Sergey [Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of sciences, Akademgorodok, 50/24, Krasnoyarsk, 660036 (Russian Federation); Siberian Federal University, Svobodny pr. 79, Krasnoyarsk, 660041 (Russian Federation); Saikova, Svetlana [Siberian Federal University, Svobodny pr. 79, Krasnoyarsk, 660041 (Russian Federation); Romanchenko, Alexander [Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of sciences, Akademgorodok, 50/24, Krasnoyarsk, 660036 (Russian Federation); Félix, Roberto [Renewable Energy, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Lise-Meitner-Campus, Hahn-Meitner-Platz 1, 14109 Berlin (Germany)

    2016-11-30

    Highlights: • Pyrite and pyrrhotite in-air abraded and etched in aqueous Fe{sup 3+} solution were studied. • HAXPES (2 keV-6 keV) and Fe K-, S K-edge XANES (TEY and PFY mode) were measured. • Outer “polysulfide”, strongly S-excessive layers are no more than 1–4 nm thick. • “Metal-depleted” layers depend on the treatment and differ for pyrite and pyrrhotite. • Extended nearly-stoichiometric “defective” underlayers were detected using TEY XANES. - Abstract: Hard X-ray photoelectron spectroscopy (HAXPES) using an excitation energy range of 2 keV to 6 keV in combination with Fe K- and S K-edge XANES, measured simultaneously in total electron (TEY) and partial fluorescence yield (PFY) modes, have been applied to study near-surface regions of natural polycrystalline pyrite FeS{sub 2} and pyrrhotite Fe{sub 1−x}S before and after etching treatments in an acidic ferric chloride solution. It was found that the following near-surface regions are formed owing to the preferential release of iron from oxidized metal sulfide lattices: (i) a thin, no more than 1–4 nm in depth, outer layer containing polysulfide species, (ii) a layer exhibiting less pronounced stoichiometry deviations and low, if any, concentrations of polysulfide, the composition and dimensions of which vary for pyrite and pyrrhotite and depend on the chemical treatment, and (iii) an extended almost stoichiometric underlayer yielding modified TEY XANES spectra, probably, due to a higher content of defects. We suggest that the extended layered structure should heavily affect the near-surface electronic properties, and processes involving the surface and interfacial charge transfer.

  14. Mechanical touch responses of Arabidopsis TCH1-3 mutant roots on inclined hard-agar surface

    Science.gov (United States)

    Zha, Guodong; Wang, Bochu; Liu, Junyu; Yan, Jie; Zhu, Liqing; Yang, Xingyan

    2016-01-01

    The gravity-induced mechanical touch stimulus can affect plant root architecture. Mechanical touch responses of plant roots are an important aspect of plant root growth and development. Previous studies have reported that Arabidopsis TCH1-3 genes are involved in mechano-related events, how-ever, the physiological functions of TCH1-3 genes in Arabidopsis root mechanoresponses remain unclear. In the present study, we applied an inclined hard agar plate method to produce mechanical touch stimulus, and provided evidence that altered mechanical environment could influence root growth. Furthermore, tch1-3 Arabidopsis mutants were investigated on inclined agar surfaces to explore the functions of TCH1-3 genes on Arabidopsis root mechanoresponses. The results showed that two tch2 mutants, cml24-2 and cml24-4, exhibited significantly reduced root length, biased skewing, and decreased density of lateral root. In addition, primary root length and density of lateral root of tch3 (cml12-2) was significantly decreased on inclined agar surfaces. This study indicates that the tch2 and tch3 mutants are hypersensitive to mechanical touch stimulus, and TCH2 (CML24-2 and CML24-4) and TCH3 (CML12-2) genes may participate in the mechanical touch response of Arabidopsis roots.

  15. Surface-groundwater interactions in hard rocks in Sardon Catchment of western Spain: an integrated modeling approach

    Science.gov (United States)

    Hassan, S.M. Tanvir; Lubczynski, Maciek W.; Niswonger, Richard G.; Zhongbo, Su

    2014-01-01

    The structural and hydrological complexity of hard rock systems (HRSs) affects dynamics of surface–groundwater interactions. These complexities are not well described or understood by hydrogeologists because simplified analyses typically are used to study HRSs. A transient, integrated hydrologic model (IHM) GSFLOW (Groundwater and Surface water FLOW) was calibrated and post-audited using 18 years of daily groundwater head and stream discharge data to evaluate the surface–groundwater interactions in semi-arid, ∼80 km2 granitic Sardon hilly catchment in Spain characterized by shallow water table conditions, relatively low storage, dense drainage networks and frequent, high intensity rainfall. The following hydrological observations for the Sardon Catchment, and more generally for HRSs were made: (i) significant bi-directional vertical flows occur between surface water and groundwater throughout the HRSs; (ii) relatively large groundwater recharge represents 16% of precipitation (P, 562 mm.y−1) and large groundwater exfiltration (∼11% of P) results in short groundwater flow paths due to a dense network of streams, low permeability and hilly topographic relief; deep, long groundwater flow paths constitute a smaller component of the water budget (∼1% of P); quite high groundwater evapotranspiration (∼5% of P and ∼7% of total evapotranspiration); low permeability and shallow soils are the main reasons for relatively large components of Hortonian flow and interflow (15% and 11% of P, respectively); (iii) the majority of drainage from the catchment leaves as surface water; (iv) declining 18 years trend (4.44 mm.y−1) of groundwater storage; and (v) large spatio-temporal variability of water fluxes. This IHM study of HRSs provides greater understanding of these relatively unknown hydrologic systems that are widespread throughout the world and are important for water resources in many regions.

  16. Surface hardness evaluation of different composite resin materials: influence of sports and energy drinks immersion after a short-term period.

    Science.gov (United States)

    Erdemir, Ugur; Yildiz, Esra; Eren, Meltem Mert; Ozel, Sevda

    2013-01-01

    This study evaluated the effect of sports and energy drinks on the surface hardness of different composite resin restorative materials over a 1-month period. A total of 168 specimens: Compoglass F, Filtek Z250, Filtek Supreme, and Premise were prepared using a customized cylindrical metal mould and they were divided into six groups (N=42; n=7 per group). For the control groups, the specimens were stored in distilled water for 24 hours at 37°C and the water was renewed daily. For the experimental groups, the specimens were immersed in 5 mL of one of the following test solutions: Powerade, Gatorade, X-IR, Burn, and Red Bull, for two minutes daily for up to a 1-month test period and all the solutions were refreshed daily. Surface hardness was measured using a Vickers hardness measuring instrument at baseline, after 1-week and 1-month. Data were statistically analyzed using Multivariate repeated measure ANOVA and Bonferroni's multiple comparison tests (α=0.05). Multivariate repeated measures ANOVA revealed that there were statistically significant differences in the hardness of the restorative materials in different immersion times (pmaterials was tested using Bonferroni's multiple comparison tests, and it was observed that specimens stored in distilled water demonstrated statistically significant lower mean surface hardness reductions when compared to the specimens immersed in sports and energy drinks after a 1-month evaluation period (pmaterials were the least affected materials. The effect of sports and energy drinks on the surface hardness of a restorative material depends on the duration of exposure time, and the composition of the material.

  17. Morphology observation for surface orange peel and fracture in tension sample of aluminum-alloy sheet and characterization of nano hardness

    Institute of Scientific and Technical Information of China (English)

    Ma Mingtu; Mei Huashen; Lu Hongzhou; Yang Hongya; Wu Emei; Zhou Mingbo

    2012-01-01

    The tension property of aluminum-alloy sheet with different microstructures is measured, and the surface and tension fracture morphology of tension sample with and without orange peel are observed by using scanning electron microscope (SEM). Surface roughness and nano hardness of tension sample are measured. The results show that the average elongation of the samples with orange peel is lower than that without orange peel ; especially the r value of per- pendicular to the rolling direction is much lower than that without orange peel. The tension surface of the orange peel samples is very rough; various parameters of surface roughness are higher. Under the observation of SEM, a wider slid- ing band with a micro crack on the surface of orange peel sample can be found. The various parameters of surface rough- ness without orange peel sample are near to zero, the sliding band is narrow and without micro cracks. The dimple width in tensile fracture of orange peel sample is larger than that without orange peel sample, but shear lip is narrower. The nano hardness testing results show that samples with orange peel behave high elastic modulus, high hardness, and high maximum load, but low plastic deformation depth. These mentioned features can completely describe surface and frac- ture morphology of tension samt31es with oranze peel.

  18. Microbial diversity and dynamics throughout manufacturing and ripening of surface ripened semi-hard Danish Danbo cheeses investigated by culture-independent techniques

    DEFF Research Database (Denmark)

    Ryssel, Mia; Johansen, Pernille; Abu Al-Soud, Waleed

    2015-01-01

    Microbial successions on the surface and in the interior of surface ripened semi-hard Danish Danbo cheeses were investigated by culture-dependent and -independent techniques. Culture-independent detection of microorganisms was obtained by denaturing gradient gel electrophoresis (DGGE) and pyroseq.......9%±7.8% of the OTUs throughout the cheese processing. The microbial dynamics described at genus level in this study add to a comprehensive understanding of the complex microbiota existing especially on surface ripened semi-hard cheeses.......Microbial successions on the surface and in the interior of surface ripened semi-hard Danish Danbo cheeses were investigated by culture-dependent and -independent techniques. Culture-independent detection of microorganisms was obtained by denaturing gradient gel electrophoresis (DGGE....... As expected, microbial profiles of the surface and the interior of the cheeses diverged. During cheese production pyrosequencing determined Lactococcus as the dominating genus on cheese surfaces, representing on average 94.7%±2.1% of the OTUs. At day 6 Lactococcus spp. declined to 10.0% of the OTUs, whereas...

  19. Correlation of microstructure with hardness and wear resistance in (TiC, SiC)/stainless steel surface composites fabricated by high-energy electron-beam irradiation

    Science.gov (United States)

    Yun, Eunsub; Kim, Yong Chan; Lee, Sunghak; Kim, Nack J.

    2004-03-01

    Stainless-steel-based surface composites reinforced with TiC and SiC carbides were fabricated by high-energy electron beam irradiation. Four types of powder/flux mixtures, i.e., TiC, (Ti + C), SiC, and (Ti + SiC) powders with 40 wt. pct of CaF2 flux, were deposited evenly on an AISI 304 stainless steel substrate, which was then irradiated with an electron beam. TiC agglomerates and pores were found in the surface composite layer fabricated with TiC powders because of insufficient melting of TiC powders. In the composite layer fabricated with Ti and C powders having lower melting points than TiC powders, a number of primary TiC carbides were precipitated while very few TiC agglomerates or pores were formed. This indicated that more effective TiC precipitation was obtained from the melting of Ti and C powders than of TiC powders. A large amount of precipitates such as TiC and Cr7C3 improved the hardness, high-temperature hardness, and wear resistance of the surface composite layer two to three times greater than that of the stainless steel substrate. In particular, the surface composite fabricated with SiC powders had the highest volume fraction of Cr7C3 distributed along solidification cell boundaries, and thus showed the best hardness, high-temperature hardness, and wear resistance.

  20. In vitro evaluation of topical fluoride pH and their effect on surface hardness of composite resin-based restorative materials.

    Science.gov (United States)

    Mujeeb, Abdul; Mansuri, Samir; Hussain, Seema Abid; Ramaswamy, Kausar

    2014-03-01

    The aim of the study was to correlate the pH and fluoride ion uptake with surface hardness of composite resin based restorative materials after topical fluoride application. Forty disks of each of test materials Composite (Filtek Z350XT, 3M ESPE, St Paul, MN, USA), Resin modified glass ionomer (Vitremer) and Compomer (Dyract AP) were made and ten disks of each material were placed in different test solutions - 1.23% APF gel, Sodium fluoride mouth rinse, 0.9% neutral fluoride and distilled water (Control group). After 36 hours of immersion, specimens were subjected to microhardness testing machine for evaluation of surface hardness. The greater hardness deterioration for all materials resulted with 1.23% APF gel when compared to the control group. Composite (Filtek Z350XT, 3M ESPE, St Paul, MN, USA) showed 17.13 VHN (control group 59.11 VHN). Vitremer showed 9.71 VHN (control group 37.71 VHN). Compomer showed 19.22 VHN (control group 36.78 VHN). 1.23% ApF gel significantly decreased hardness of composite, Vitremer and Compomer. Hardness deterioration associated with sodium fluoride mouth rinse and 0.9% neutral fluoride was less compared to 1.23% ApF gel.

  1. SiO2-nanocomposite film coating of CAD/CAM composite resin blocks improves surface hardness and reduces susceptibility to bacterial adhesion.

    Science.gov (United States)

    Kamonwanon, Pranithida; Hirose, Nanako; Yamaguchi, Satoshi; Sasaki, Jun-Ichi; Kitagawa, Haruaki; Kitagawa, Ranna; Thaweboon, Sroisiri; Srikhirin, Toemsak; Imazato, Satoshi

    2017-01-31

    Composite resin blocks for computer-aided design/computer-aided manufacturing (CAD/CAM) applications have recently become available. However, CAD/CAM composite resins have lower wear resistance and accumulate more plaque than CAD/CAM ceramic materials. We assessed the effects of SiO2-nanocomposite film coating of four types of CAD/CAM composite resin blocks: Cerasmart, Katana Avencia block, Lava Ultimate, and Block HC on surface hardness and bacterial attachment. All composite blocks with coating demonstrated significantly greater Vickers hardness, reduced surface roughness, and greater hydrophobicity than those without coating. Adhesion of Streptococcus mutans to the coated specimens was significantly less than those for the uncoated specimens. These reduced levels of bacterial adherence on the coated surface were still evident after treatment with saliva. Surface modification by SiO2-nanocomposite film coating has potential to improve wear resistance and susceptibility to plaque accumulation of CAD/CAM composite resin restorations.

  2. SELF-ASSEMBLED MICRO-DOMAINS ON THE UPPERMOST SURFACE OF FLUORINATED POLY(CARBONATE URETHANE)S WITH FLUORINATED SIDE CHAIN ATTACHED ON HARD SEGMENTS

    Institute of Scientific and Technical Information of China (English)

    Hong Tan; Min Guo; Jie-hua Li; Xing-yi Xie; Yin-ping Zhong; Qiang Fu

    2004-01-01

    The surface phase separated structure of polyurethanes is always desired due to the advantage of better biocompatibility, compared with the homogeneous one. The key issue is how to control and characterize the surface morphology. In this work, we report the uppermost surface morphology of fluorinated poly(carbonate urethane)s with fluorinated side chains attached to hard segments as studied by AFM, XPS and contact angle measurement. A self-assembled micro-domain with the fluorinated side chain standing up on the uppermost surface has been proposed for polyurethane with higher fluorinated content, based on the result obtained.

  3. Experimental research on the effect of the ball burnishing process, using new kinematical scheme on hardness and phase composition of surface layer of AISI 304L stainless steel

    Directory of Open Access Journals (Sweden)

    Dimitrov Diyan M.

    2017-01-01

    Full Text Available In this paper, experimental results about hardness and phase composition of surface layer of AISI 304L SS, machined by using ball burnishing process, conducted under a new kinematic scheme, are presented. The effect of different combinations of the process regime parameters on the amount of strain induced martensitic phase, is discussed. The amounts of austenitic and strain induced martensitic phases are identified by x-ray diffractometer. Micro hardness along the depth of the hardened layer is measured. Conclusions about the influence of the ball burnishing process on strain induced martensitic phase are given.

  4. Preparation and Characterization of Non-porous Superparamagnetic Microspheres with Epoxy Groups by Dispersion Polymerization

    Institute of Scientific and Technical Information of China (English)

    马志亚; 官月平; 刘先桥; 刘会洲

    2005-01-01

    Non-porous superparamagnetic polymer microspheres with epoxy groups were prepared by dispersion polymerization of glycidyl methacrylate (GMA) in the presence of magnetic iron oxide (Fe3O4) nanoparticles coated with oleic acid. The polymerization was carried out in the ethanol/water medium using polyvinylpyrrolidone (PVP) and 2,2’-azobisisobutyronitrile (AIBN) as stabilizer and initiator, respectively. The magnetic microspheres obtained were characterized with scanning electron microscopy (SEM), vibrating sample magnetometry (VSM) and Fourier transform infrared spectroscopy (FTIR). The results showed that the magnetic microspheres had an average size of-1μm with superparamagnetic characteristics. The saturation magnetization was found to be 4.5emu.g-1. There was abundance of epoxy groups with density of 0.028 mmol·g-1 in microspheres. The magnetic PGMA microspheres have extensive potential uses in magnetic bioseparation and biotechnology.

  5. Spot morphology of non-contact printed protein molecules on non-porous substrates with a range of hydrophobicities

    NARCIS (Netherlands)

    Mujawar, L.H.; Norde, W.; Amerongen, van A.

    2013-01-01

    Non-contact inkjet printing technology is one of the most promising tools for producing microarrays. The quality of the microarray depends on the type of the substrate used for printing biomolecules. Various porous and non-porous substrates have been used in the past, but due to low production cost

  6. Spot morphology of non-contact printed protein molecules on non-porous substrates with a range of hydrophobicities

    NARCIS (Netherlands)

    Mujawar, L.H.; Norde, W.; Amerongen, van A.

    2013-01-01

    Non-contact inkjet printing technology is one of the most promising tools for producing microarrays. The quality of the microarray depends on the type of the substrate used for printing biomolecules. Various porous and non-porous substrates have been used in the past, but due to low production cost

  7. Comparison of surface roughness and chip characteristics obtained under different modes of lubrication during hard turning of AISI H13 tool work steel.

    Science.gov (United States)

    Raj, Anil; Wins, K. Leo Dev; Varadarajan, A. S.

    2016-09-01

    Surface roughness is one of the important parameters, which not only affects the service life of a component but also serves as a good index of machinability. Near Dry Machining, methods (NDM) are considered as sustainable alternative for workshops trying to bring down their dependence on cutting fluids and the hazards associated with their indiscriminate usage. The present work presents a comparison of the surface roughness and chip characteristics during hard turning of AISI H13 tool work steel using hard metal inserts under two popular NDM techniques namely the minimal fluid application and the Minimum Quantity Lubrication technique(MQL) using an experiment designed based on Taguchi's techniques. The statistical method of analysis of variance (ANOVA) was used to determine the relative significance of input parameters consisting of cutting speed, feed and depth of cut on the attainable surface finish and the chip characteristics. It was observed that the performance during minimal fluid application was better than that during MQL application.

  8. Optimization on hardness and internal stress of micro-electroformed NiCo/nano-Al2O3 composites with the constraint of low surface roughness

    Science.gov (United States)

    Hung, Shih-Yu

    2009-01-01

    In this paper, Ni-Co/nano-Al2O3 composite electroforming was used to make the metallic micro-mold for a microlens array. The microstructures require higher hardness to improve the wear resistance and lifetime. Nano-Al2O3 was applied to strengthen the Ni-Co matrix by a new micro-electroforming technique. The hardness and internal stress of Ni-Co/nano-Al2O3 composite deposit were investigated. The results showed that the hardness increased with the increasing Al2O3 content, but at the cost of deformation. Increasing the Al2O3 content in the composite was not always beneficial to the electroformed mold for microlens array fabrication. This work will concentrate on the relationship between important mechanical properties and electrolyte parameters of Ni-Co/nano-Al2O3 composite electroforming. Electrolyte parameters such as Al2O3 content, Al2O3 particle diameter, Co content, stress reducer and current density will be examined with respect to internal stress and hardness. In the present study, low stress and high hardness electroforming with the constraint of low surface roughness is carried out using SNAOA algorithm to reduce internal stress and increase service life of micro-mold during the forming process. The results show that the internal stress and the RMS roughness are only 0.54 MPa and 4.8 nm, respectively, for the optimal electrolyte parameters combination of SNAOA design.

  9. In Vitro Evaluation of the Enamel Surface Hardness Reduction in Primary and Permanent Teeth Caused by Two Most Common Acidic Soft Drinks

    Directory of Open Access Journals (Sweden)

    Nozari A.

    2011-05-01

    Full Text Available Statement of Problem: Dental erosion is defined as the loss of tooth substance by chemical processes not involving bacteria. Dental erosion has been found to be a common cause of tooth wear. Clinically apparent erosion has been found to be related to dietary factors such as the acid content of the beverages.Purpose: Evaluation of enamel erosion in the primary and permanent teeth as the result of two most common acidic drinks produced in Iranian factories, Mirinda and Pepsi.Materials and Method: The outermost surfaces of 20 primary and 20 permanent teeth were polished flat by using the finest grade sandpaper and water in order to facilitate the proper measurement. The specimens were then prepared by cutting 3-4 mm of the buccal surface of teeth by diamond burs. The specimens were then rinsed with distilled water and stored in 100˚10 humidity before testing. The surface micro-hardness of each specimen was measured by micro vickers Hardness tester before, after 5 minutes, and 10 minutes exposure to fresh solution of each drink (10 teeth per test group. Mann-Whitney and Wilcoxon signed rank tests were used for the estatistical analysis.Results: The results showed that both drinks, Mirinda and Pepsi, produced significant surface hardness loss at 5 and 10 minutes of exposure time ( p =0.05. The amount of erosive effect was changed as the exposure time increased (change from 5 to 10 minutes. There was no statistically significant difference between the amounts of surface hardness loss in the primary and permanent enamel ( p >0.05. Conclusion: Both drinks may have almost similar but significant erosive effect on the primary and permanent enamel surfaces. Although there wasn’t any difference between erosive effect of the two beverages, this effect was increased with increase in time. The primary teeth enamel was not found to be more susceptibe to acidic beverage-induced erosion than the permanent teeth.

  10. Surface-groundwater interactions in hard rocks in Sardon Catchment of western Spain: an integrated modeling approach

    NARCIS (Netherlands)

    Tanvir Hassan, S.M.; Lubczynski, M.; Niswonger, R.G.; Su, Zhongbo

    2014-01-01

    The structural and hydrological complexity of hard rock systems (HRSs) affects dynamics of surface–groundwater interactions. These complexities are not well described or understood by hydrogeologists because simplified analyses typically are used to study HRSs. A transient, integrated hydrologic

  11. Biodiversity of green algae covering artificial hard substrate surfaces in a suburban environment: a case study using molecular approaches.

    Science.gov (United States)

    Hallmann, Christine; Hoppert, Michael; Mudimu, Opayi; Friedl, Thomas

    2016-10-01

    In Middle European suburban environments green algae often cover open surfaces of artificial hard substrates. Microscopy reveals the Apatococcus/Desmococcus morphotype predominant over smaller coccoid forms. Adverse conditions such as limited water availability connected with high PAR and UV irradiance may narrow the algal diversity to a few specialists in these subaerial habitats. We used rRNA gene cloning/sequencing from both DNA extracts of the biofilms without culturing as well as cultures, for the unambiguous determination of the algal composition and to assess the algal diversity more comprehensively. The culture independent approach revealed mainly just two genera (Apatococcus, Trebouxia) for all study sites and five molecular operational taxonomic units (OTUs) for a particular study site, which based on microscopic observation was the one with the highest morphological diversity. The culture approach, however, revealed seven additional OTUs from five genera (Chloroidium, Coccomyxa, Coenochloris, Pabia, Klebsormidium) and an unidentified trebouxiophyte lineage for that same site; only two OTUs were shared by both approaches. Two OTUs or species were recovered for which references have been isolated only from Antarctica so far. However, the internal transcribed spacer (ITS) sequence differences among them supported they are representing distinct populations of the same species. Within Apatococcus five clearly distinct groups of ITS sequences, each putatively representing a distinct species, were recovered with three or four such ITS types co-occurring at the same study site. Except for the streptophyte Klebsormidium only members of Trebouxiophyceae were detected suggesting these algae may be particularly well-adapted to subaerial habitats.

  12. Influence of filler type on wet skid resistance of SSBR/BR composites: Effects from roughness and micro-hardness of rubber surface

    Science.gov (United States)

    Wang, Yuan-Xia; Wu, You-Ping; Li, Wen-Ji; Zhang, Li-Qun

    2011-01-01

    The wet skid resistance (WSR) of SSBR/BR(solution styrene-butadiene rubber/butadiene rubber) composites filled with carbon black, silica, and nano-diamond partly replacing carbon black or silica, respectively, was measured with a portable British Pendulum Skid Tester (BPST). A dynamic mechanical thermal analyzer was used to obtain the viscoelasticity of the composites. A 3D scanning white-light interfering profilometer was used and the scratch test performed to characterize surface roughness and micro-roughness, respectively, of the composites. WSR of the silica-filled composite was better than that of the carbon black-filled one, and further enhancement of WSR was obtained by replacing silica with nano-diamond. Tan δ of the composites at 0 °C, 10 Hz, and tensile strain of 2% did not show good correlation with WSR. The surface roughness of the composites had effects on WSR. The scratch test indicated that the higher the hardness of the filler in the composite, the higher the micro-hardness and the better the WSR. Therefore, the surface micro-hardness of the composites is an important factor affecting WSR, besides viscoelasticity and surface roughness.

  13. Effect of the irradiance distribution from light curing units on the local micro-hardness of the surface of dental resins.

    Science.gov (United States)

    Haenel, Thomas; Hausnerová, Berenika; Steinhaus, Johannes; Price, Richard B T; Sullivan, Braden; Moeginger, Bernhard

    2015-02-01

    An inhomogeneous irradiance distribution from a light-curing unit (LCU) can locally cause inhomogeneous curing with locally inadequately cured and/or over-cured areas causing e.g. monomer elution or internal shrinkage stresses, and thus reduce the lifetime of dental resin based composite (RBC) restorations. The aim of the study is to determine both the irradiance distribution of two light curing units (LCUs) and its influence on the local mechanical properties of a RBC. Specimens of Arabesk TOP OA2 were irradiated for 5, 20, and 80s using a Bluephase® 20i LCU in the Low mode (666mW/cm(2)), in the Turbo mode (2222mW/cm(2)) and a Celalux® 2 (1264mW/cm(2)). The degree of conversion (DC) was determined with an ATR-FTIR. The Knoop micro-hardness (average of five specimens) was measured on the specimen surface after 24h of dark and dry storage at room temperature. The irradiance distribution affected the hardness distribution across the surface of the specimens. The hardness distribution corresponded well to the inhomogeneous irradiance distributions of the LCU. The highest reaction rates occurred after approximately 2s light exposure. A DC of 40% was reached after 3.6 or 5.7s, depending on the LCU. The inhomogeneous hardness distribution was still evident after 80s of light exposure. The irradiance distribution from a LCU is reflected in the hardness distribution across the surface. Irradiance level of the LCU and light exposure time do not affect the pattern of the hardness distribution--only the hardness level. In areas of low irradiation this may result in inadequate resin polymerization, poor physical properties, and hence premature failure of the restorations as they are usually much smaller than the investigated specimens. It has to be stressed that inhomogeneous does not necessarily mean poor if in all areas of the restoration enough light intensity is introduced to achieve a high degree of cure. Copyright © 2014 Academy of Dental Materials. Published by

  14. THE INFLUENCE OF SURFACE-MORPHOLOGY AND WETTABILITY ON THE INFLAMMATORY RESPONSE AGAINST POLY(L-LACTIC ACID) - A SEMIQUANTITATIVE STUDY WITH MONOCLONAL-ANTIBODIES

    NARCIS (Netherlands)

    LAM, KH; SCHAKENRAAD, JM; GROEN, H; ESSELBRUGGE, H; DIJKSTRA, PJ; FEIJEN, J; NIEUWENHUIS, P

    1995-01-01

    In this study, the influence of surface morphology and wettability of both degradable and nondegradable polymer films on the inflammatory response after subcutaneous implantation in the rat was investigated. Degradable nonporous, porous, and ''combi'' (porous with a nonporous layer on one side) poly

  15. The influence of surface morphology and wettability on the inflammatory response against poly(L-lactic acid): A semi-quantitative study with monoclonal antibodies

    NARCIS (Netherlands)

    Lam, K.H.; Schakenraad, J.M.; Groen, H.; Esselbrugge, H.; Dijkstra, P.J.; Feijen, J.; Nieuwenhuis, P.

    1995-01-01

    In this study, the influence of surface morphology and wettability of both degradable and nondegradable polymer films on the inflammatory response after subcutaneous implantation in the rat was investigated. Degradable nonporous, porous, and combi (porous with a nonporous layer on one side) poly(L-l

  16. Comparison of the effect of resin infiltrant, fluoride varnish, and nano-hydroxy apatite paste on surface hardness and streptococcus mutans adhesion to artificial enamel lesions

    OpenAIRE

    Aziznezhad, Mahdiye; Alaghemand, Homayoon; Shahande, Zahra; Pasdar, Nilgoon; Bijani, Ali; Eslami, Abdolreza; Dastan, Zohre

    2017-01-01

    Introduction Dental caries is a major public health problem, and Streptococcus mutans is considered the main causal agent of dental caries. This study aimed to compare the effect of three re-mineralizing materials: resin infiltrant, fluoride varnish, and nano-hydroxy apatite paste on the surface hardness and adhesion of Streptococcus mutans as noninvasive treatments for initial enamel lesions. Methods This experimental study was conducted from December 2015 through March 2016 in Babol, Iran. ...

  17. Occupational Exposure to Cobalt and Tungsten in the Swedish Hard Metal Industry: Air Concentrations of Particle Mass, Number, and Surface Area

    Science.gov (United States)

    Bryngelsson, Ing-Liss; Pettersson, Carin; Husby, Bente; Arvidsson, Helena; Westberg, Håkan

    2016-01-01

    Exposure to cobalt in the hard metal industry entails severe adverse health effects, including lung cancer and hard metal fibrosis. The main aim of this study was to determine exposure air concentration levels of cobalt and tungsten for risk assessment and dose–response analysis in our medical investigations in a Swedish hard metal plant. We also present mass-based, particle surface area, and particle number air concentrations from stationary sampling and investigate the possibility of using these data as proxies for exposure measures in our study. Personal exposure full-shift measurements were performed for inhalable and total dust, cobalt, and tungsten, including personal real-time continuous monitoring of dust. Stationary measurements of inhalable and total dust, PM2.5, and PM10 was also performed and cobalt and tungsten levels were determined, as were air concentration of particle number and particle surface area of fine particles. The personal exposure levels of inhalable dust were consistently low (AM 0.15mg m−3, range industrial settings. Regression analysis implied the use of stationary determined mass-based and particle surface area aerosol concentration as proxies for various exposure measures in our study. PMID:27143598

  18. In vitro Comparison of the Effct Cola Beverage on Surface Hardness of Siloran-Based (p90 and Methyl Methacrylate-Based (p60 Composites

    Directory of Open Access Journals (Sweden)

    Z.Khamverdi

    2016-11-01

    Full Text Available Introduction: Th characteristics of a suitable restoration material is having acceptable mechanical properties, protecting teeth against decay and ease of use in clinics. Diet can affct properties of restorative materials in the mouth. Since amongst important properties of composite restorations are mechanical properties such as hardness, the aim of this study was evaluation of the effct of Coca-Cola Beverages on surface hardness of a silorane based p90( and methyl methacrylate p60( composites. Methods: In this experimental study, thirty disc-shaped specimens 5 × 2 mm( of each of methyl methacrylate based Filtek p60, 3M Dental Products, USA( and a silorane based Filtek p90, 3M Dental Products, USA( composite resins were prepared, according to manufacturers' instructions. Specimens were randomly divided to four groups as follows N = 15(: G1: Filtek p90 without exposure to Coca-Cola, G2: Filtek p90 with exposure to Coca-Cola, G3: Filtek p60 without expure to Coca-Cola, G4: Filtek p60 with expure to Coca-Cola. Th specimens were exposed to regular sof drinks Coca-Cola, Khoshgovar, Tehran, Iran( at room temperature for seven days with a frequency of three times daily for 20 minutes at a time. In the remaining times of the day, they were kept in distilled water. Thn, micro hardness measurements were made for each specimen with a Vickers hardness testing machine Buehler, Lake Bluff IL, USA( under 500 g of force for 15 seconds. Data were analyzed using SPSS 18 and independent t-test at a signifiance level of 0.05. Results: Micro hardness values of four groups were G1: 68.28 ± 2.65; G2:59.56 ± 6.61; G3: 93.5 ± 2.38; and G4:86.76 ± 5.47, respectively. Th results of this study showed that Coca-Cola reduces the surface hardness of the two composite materials P > 0.05(. Conclusions: Th results showed the hardness of both Filtek p90 and Filtek p60 composite signifiantly decreases with Coca-Cola but the reduction was equal.

  19. REVIEW ON POROUS AND NON-POROUS FLAT PLATE AIR COLLECTOR WITH MIRROR ENCLOSURE

    Directory of Open Access Journals (Sweden)

    M. PRADHAPRAJ,

    2010-09-01

    Full Text Available In solar air heater, flat plat collectors are the best heat transferring devices. But the effectiveness of these collectorsis very low because of lack of technology. Solar assisted heated air is successfully used for drying applications and space heating under controlled conditions. From the solar flat plate air heater the hot air is transferred to a conventional dryer or to the combined heater and drying chamber directly. Hence, solar assisted air heaters arecheaper and reliable. The important factors affecting these systems are the solar radiation, mechanical loading, temperature and leakage. The air heater efficiency depends on the design of the system as well as the construction materials and the assembly. The solar air heating systems has acceptable life span of 15 to 20 years. The addition ofside mirror enclosures is to increase the amount of solar radiation absorption at the collector plate so that the collector increases the yield and operate in a higher temperature range. Therefore with the addition of side mirrors one can able to maximize the output of fixed flat plate collectors. A flat plate air collector will be more efficient if it is made up of porous medium when comparing it with the non porous collectors according to the study. In this paper, the performances of porous and non-porous absorber plates are discussed. Also the possible methods of finding out air leakages and the methodology adopted for the performance and efficiency calculations are also discussed.

  20. The biocompatibility of porous vs non-porous bone cements: a new methodological approach

    Directory of Open Access Journals (Sweden)

    C. Dall'Oca

    2014-06-01

    Full Text Available Composite cements have been shown to be biocompatible, bioactive, with good mechanical properties and capability to bind to the bone. Despite these interesting characteristic, in vivo studies on animal models are still incomplete and ultrastructural data are lacking. The acquisition of new ultrastructural data is hampered by uncertainties in the methods of preparation of histological samples due to the use of resins that melt methacrylate present in bone cement composition. A new porous acrylic cement composed of polymethylmetacrylate (PMMA and β-tricalciumphosphate (β-TCP was developed and tested on an animal model. The cement was implanted in femurs of 8 New Zealand White rabbits, which were observed for 8 weeks before their sacrifice. Histological samples were prepared with an infiltration process of LR white resin and then the specimens were studied by X-rays, histology and scanning electron microscopy (SEM. As a control, an acrylic standard cement, commonly used in clinical procedures, was chosen. Radiographic ultrastructural and histological exams have allowed finding an excellent biocompatibility of the new porous cement. The high degree of osteointegration was demonstrated by growth of neo-created bone tissue inside the cement sample. Local or systemic toxicity signs were not detected. The present work shows that the proposed procedure for the evaluation of biocompatibility, based on the use of LR white resin allows to make a thorough and objective assessment of the biocompatibility of porous and non-porous bone cements.

  1. Comparative evaluation of surface hardness and depth of cure of silorane and methacrylate-based posterior composite resins: An in vitro study

    Directory of Open Access Journals (Sweden)

    Abhishek Agrawal

    2015-01-01

    Full Text Available Aim: This in vitro study was carried out to compare the effect of LED light curing system on polymerization and hardness of silorane-based and methacrylate-based posterior composite resin. Materials and Methods: A total of 40 samples, 20 of silorane-based composite Filtek P-90 and 20 of methacrylate-based composite Heliomolar HB measuring 2 mm thickness and 8 mm diameter were prepared using Teflon molds and cured using LED curing light. The samples were polished and tested in Knoop hardness tester using a 50-gram load and dwell time of 15 seconds on top and bottom surfaces. The percentage depth of cure was calculated, and statistical analysis was performed using two-way ANOVA test and Student t- test. Results: Higher statistically significant values were seen for both the top and bottom surface hardness in silorane-based resins than methacrylate-based resins on LED light curing. Conclusion: Greater depth of cure was achieved in silorane-based posterior composite than in methacrylate-based posterior composite resins with a statistically significant difference.

  2. New Method for Hard Sludge Removal from Tube Plate Surfaces: The AREVA Enhanced Inner Bundle Lancing Process

    Energy Technology Data Exchange (ETDEWEB)

    Stoss, J.; Santibanez, M.

    2014-07-01

    AREVA is currently conducting the final steps to start-up an enhanced technology to remove hard sludge deposits from the inner bundle area of the tube sheets. This inner bundle area at the top of the tube plate is the location with the lowest flow velocity of the circulating water at the secondary closed loop. The reduced water speed causes increased accumulation of ferrite oxides at these locations. (Author)

  3. Comparison of the effect of resin infiltrant, fluoride varnish, and nano-hydroxy apatite paste on surface hardness and streptococcus mutans adhesion to artificial enamel lesions.

    Science.gov (United States)

    Aziznezhad, Mahdiye; Alaghemand, Homayoon; Shahande, Zahra; Pasdar, Nilgoon; Bijani, Ali; Eslami, Abdolreza; Dastan, Zohre

    2017-03-01

    Dental caries is a major public health problem, and Streptococcus mutans is considered the main causal agent of dental caries. This study aimed to compare the effect of three re-mineralizing materials: resin infiltrant, fluoride varnish, and nano-hydroxy apatite paste on the surface hardness and adhesion of Streptococcus mutans as noninvasive treatments for initial enamel lesions. This experimental study was conducted from December 2015 through March 2016 in Babol, Iran. Artificial enamel lesions were created on 60 enamel surfaces, which were divided into two groups: Group A and Group B (30 subjects per group). Group A was divided into three subgroups (10 samples in each subgroup), including fluoride varnish group, nano-hydroxy apatite paste group (Nano P paste), and resin infiltrant group (Icon-resin). In Group A, the surface hardness of each sample was measured in three stages: First, on an intact enamel (baseline); second, after creating artificial enamel lesions; third, after application of re-mineralizing materials. In Group B, the samples were divided into five subgroups, including intact enamel, demineralized enamel, demineralized enamel treated with fluoride varnish, Nano P paste, and Icon-resin. In Group B, standard Streptococcus mutans bacteria adhesion (PTCC 1683) was examined and reported in terms of colony forming units (CFU/ml). Then, data were analyzed using ANOVA, Kruskal-Wallis, Mann-Whitney, and post hoc tests. In Group A, after treatment with re-mineralizing materials, the Icon-resin group had the highest surface hardness among the studied groups, then the Nano P paste group and fluoride varnish group, respectively (p = 0.035). In Group B, in terms of bacterial adhesion, fluoride varnish group had zero bacterial adhesion level, and then the Nano P paste group, Icon-resin group, intact enamel group, and the de-mineralized enamel group showed bacterial adhesion increasing in order (p enamel and fluoride varnish had the highest reduction level for

  4. The influence of surface roughness on the bond strength of composite to dental hard tissues after Er:YAG laser irradiation

    Science.gov (United States)

    Gardner, Andrew K.; Staninec, Michal; Fried, Daniel

    2005-03-01

    The uniformity of laser treated hard tissue surfaces depends on the laser beam quality and the degree of spatial overlap between adjacent laser pulses. Since the surface roughness or surface topography is expected to influence adhesion, our aim in this study was to assess the influence of the surface topography on the adhesion of composite to both enamel and dentin treated at the optimal conditions for the efficient ablation of those tissues with the Er:YAG laser. Human dentin and bovine enamel samples were uniformly irradiated by an Er:YAG laser operating with a pulse duration of 20-30-μs. The laser pulses were 300-μm in diameter with the laser operating in a single TEM00 transverse mode, and the distance between laser spots was varied from 50-200-μm. A motion control system and a pressurized spray system incorporating a microprocessor controlled pulsed nozzle for water delivery, were used to ensure uniform treatment of the entire surface. Shear bond testing was used to evaluate the adhesive strength in order to assess the suitability of laser treated surfaces for bonding. The effect of the degree of overlap of adjacent laser pulses on the surface roughness and the shear bond strength of composite to enamel and dentin is reported.

  5. Microbial diversity and dynamics throughout manufacturing and ripening of surface ripened semi-hard Danish Danbo cheeses investigated by culture-independent techniques.

    Science.gov (United States)

    Ryssel, Mia; Johansen, Pernille; Al-Soud, Waleed Abu; Sørensen, Søren; Arneborg, Nils; Jespersen, Lene

    2015-12-23

    Microbial successions on the surface and in the interior of surface ripened semi-hard Danish Danbo cheeses were investigated by culture-dependent and -independent techniques. Culture-independent detection of microorganisms was obtained by denaturing gradient gel electrophoresis (DGGE) and pyrosequencing, using amplicons of 16S and 26S rRNA genes for prokaryotes and eukaryotes, respectively. With minor exceptions, the results from the culture-independent analyses correlated to the culture-dependent plating results. Even though the predominant microorganisms detected with the two culture-independent techniques correlated, a higher number of genera were detected by pyrosequencing compared to DGGE. Additionally, minor parts of the microbiota, i.e. comprising cheeses diverged. During cheese production pyrosequencing determined Lactococcus as the dominating genus on cheese surfaces, representing on average 94.7%±2.1% of the OTUs. At day 6 Lactococcus spp. declined to 10.0% of the OTUs, whereas Staphylococcus spp. went from 0.0% during cheese production to 75.5% of the OTUs at smearing. During ripening, i.e. from 4 to 18 weeks, Corynebacterium was the dominant genus on the cheese surface (55.1%±9.8% of the OTUs), with Staphylococcus (17.9%±11.2% of the OTUs) and Brevibacterium (10.4%±8.3% of the OTUs) being the second and third most abundant genera. Other detected bacterial genera included Clostridiisalibacter (5.0%±4.0% of the OTUs), as well as Pseudoclavibacter, Alkalibacterium and Marinilactibacillus, which represented cheeses was dominated by Lactococcus spp. comprising on average 93.9%±7.8% of the OTUs throughout the cheese processing. The microbial dynamics described at genus level in this study add to a comprehensive understanding of the complex microbiota existing especially on surface ripened semi-hard cheeses.

  6. Effects of surface hydrophilicity and microtopography on early stages of soft and hard tissue integration at non-submerged titanium implants: an immunohistochemical study in dogs.

    Science.gov (United States)

    Schwarz, Frank; Ferrari, Daniel; Herten, Monika; Mihatovic, Ilja; Wieland, Marco; Sager, Martin; Becker, Jürgen

    2007-11-01

    The aim of the present study was to investigate the effects of surface hydrophilicity and microtopography on soft and hard tissue integration at non-submerged titanium implants. Implantation of conventional sand-blasted large grit and acid-etched (SLA) and chemically modified SLA (modSLA) titanium implants with differently structured transmucosal surfaces (SLA implants: machined [M-SLA] or SLA [SLA-SLA]; modSLA implants: mod acid-etched [modA] [modA-modSLA] or modSLA [modSLA-modSLA]) was performed bilaterally in the upper and lower jaws of 15 beagle dogs. The animals were sacrificed after 1, 4, 7, 14, or 28 days. Tissue reactions were assessed histomorphometrically and immunohistochemically using monoclonal antibodies to transglutaminase II (angiogenesis) and osteocalcin. Although the junctional epithelium commonly was separated from M-SLA and SLA-SLA implants by a gap, the epithelial cells appeared to be in close contact with modA-modSLA surfaces after 14 days of healing. Moreover, modA-modSLA and modSLA-modSLA groups showed a well-vascularized subepithelial connective tissue exhibiting collagen fibers that started to extend and attach partially perpendicular to the implant surface. The highest and statistically significant mean bone-to-implant contact areas were observed in the modA-modSLA and modSLA-modSLA groups at days 7, 14, and 28. Within the limits of this study, it may be concluded that soft and hard tissue integration was influenced mainly by surface hydrophilicity rather than by microtopography.

  7. Synthesis of Silver-Doped Titanium TiO2 Powder-Coated Surfaces and Its Ability to Inactivate Pseudomonas aeruginosa and Bacillus subtilis

    Directory of Open Access Journals (Sweden)

    Saman Khan

    2013-01-01

    Full Text Available Hard, nonporous environmental surfaces in daily life are now receiving due recognition for their role in reducing the spread of several nosocomial infections. In this work, we established the photokilling effects of 1% silver-doped titanium dioxide TiO2. The nanoparticles synthesized by liquid impregnation method were characterized using X-ray diffraction (XRD, energy dispersive spectroscopy (EDS, and scanning electron microscopy (SEM. The Ag-TiO2 nanoparticle coatings that have been applied on glass and venetian blind surfaces were effective in generating a loss of viability of two bacteria (Pseudomonas aeruginosa and Bacillus subtilis after two hours of illumination under normal light in the visible spectrum. Such surfaces can be applicable to medical and other facilities where the potential for infection should be controlled.

  8. Benefit of precise control of surface reaction by new patterning technique for small-contact etching with TiN hard mask

    Science.gov (United States)

    Tabata, Masahiro; Tsuji, Akihiro; Katsunuma, Takayuki; Honda, Masanobu

    2017-06-01

    We introduce state-of-the art small-contact etching by a new patterning technique using atomic layer etching (ALE) for sub-5 nm technology generation. In small-contact etching, SiO2 is etched by using a TiN hard mask with the progress of the miniaturization process. However, when applying the conventional method to small-contact etching with a TiN mask, etch stop is caused by excess deposition on the SiO2 film. From the results of surface analysis by X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy-energy-dispersive X-ray spectroscopy (TEM-EDX), it is considered that the deposition is formed by the reaction of fluorocarbon (FC) plasma and TiN. To solve this problem, we have developed a quasi-ALE technique to improve the ALE process to make it more suitable for SiO2 etching. By adopting this technique to small-contact etching with a TiN hard mask, etch stop was significantly reduced. Quasi-ALE precisely controls the surface reaction by controlling the radical flux and ion flux independently. Therefore, the reaction of FC plasma and TiN leading to etch stop can be minimized. Quasi-ALE can resolve the etch-stop issue due to the TiN mask used in the conventional method.

  9. A facile approach to the synthesis of non-porous and microporous sub-micron spherical zirconia and alumina-zirconia solid solution.

    Science.gov (United States)

    Ghotbi, Mohammad Yeganeh; Nasiri, Vida; Rafiee, Mehdi

    2013-01-01

    Amorphous monodisperse sub-micron spherical zirconia and alumina/zirconia solid solution particles were prepared by hydrolysis of zirconium and aluminum salts in ethanol. The heat-treatment process of the amorphous materials in air atmosphere at 500°C for 2h leaded to the production of non-porous zirconia and alumina/zirconia solid solution in tetragonal phase. The alkaline etching process of the as-prepared alumina/zirconia solid solution resulted in the formation of mono-modal microporous material with specific surface area of 125.0 m(2) g(-1) in comparison with 2. 9m(2) g(-1) for the parent material. Thermal analysis of the solid solution revealed that the incorporation of aluminum ions in the zirconia structure has decreased the phase transformation temperature from amorphous to crystalline structure. Moreover, optical study confirmed the presence of oxygen vacancy defect by substitution of tetravalent cations, Zr(4+) by trivalent cations, Al(3+) in zirconia lattice.

  10. Spot morphology of non-contact printed protein molecules on non-porous substrates with a range of hydrophobicities.

    Science.gov (United States)

    Mujawar, Liyakat Hamid; Norde, Willem; van Amerongen, Aart

    2013-01-21

    Non-contact inkjet printing technology is one of the most promising tools for producing microarrays. The quality of the microarray depends on the type of the substrate used for printing biomolecules. Various porous and non-porous substrates have been used in the past, but due to low production cost and easy availability, non-porous substrates like glass and plastic are preferred over porous substrates. On these non-porous substrates, obtaining spot uniformity and a high signal to noise ratio is a big challenge. In our research work, we have modified pristine glass slides using various silanes to produce a range of hydrophobic glass substrates. The hydrophobicities of the slides expressed in the contact angle (θ) of a sessile drop of water were 49°, 61°, 75°, 88° and 103°. Using a non-contact inkjet printer, microarrays of biotinylated biomolecules (BSA and IgG) were produced on these modified glass substrates, pristine (untreated) glass and also on HTA polystyrene slides. The uniformity of the spots, reflecting the distribution of the biomolecules in the spots, was analyzed and compared using confocal laser scanning microscopy (CLSM). The quality of the spots was superior on the glass slide with a contact angle of ∼75°. We also investigated the influence of the hydrophobicity of the substrate on a two-step, real diagnostic antibody assay. This nucleic acid microarray immunoassay (NAMIA) for the detection of Staphylococcus aureus showed that on highly hydrophilic (θ 100°) the assay signal was low, whereas an excellent signal was obtained on the substrates with intermediate contact angles, θ ∼ 61° and θ ∼ 75°, respectively.

  11. Accommodative Behavior of Non-porous Molecular crystal at Solid-Gas and Solid-Liquid Interface

    OpenAIRE

    Mande, Hemant M.; Ghalsasi, Prasanna S.

    2015-01-01

    Molecular crystals demonstrate drastically different behavior in solid and liquid state, mainly due to their difference in structural frameworks. Therefore, designing of unique structured molecular compound which can work at both these interfaces has been a challenge. Here, we present remarkable ‘molecular’ property by non-porous molecular solid crystal, dinuclear copper complex (C6H5CH(X)NH2)2CuCl2, to reversibly ‘adsorb’ HCl gas at solid-gas interface as well as ‘accommodate’ azide anion at...

  12. Determination of the surface band bending in InxGa1−xN films by hard x-ray photoemission spectroscopy

    Directory of Open Access Journals (Sweden)

    Mickael Lozac'h, Shigenori Ueda, Shitao Liu, Hideki Yoshikawa, Sang Liwen, Xinqiang Wang, Bo Shen, Kazuaki Sakoda, Keisuke Kobayashi and Masatomo Sumiya

    2013-01-01

    Full Text Available Core-level and valence band spectra of InxGa1−xN films were measured using hard x-ray photoemission spectroscopy (HX-PES. Fine structure, caused by the coupling of the localized Ga 3d and In 4d with N 2s states, was experimentally observed in the films. Because of the large detection depth of HX-PES (~20 nm, the spectra contain both surface and bulk information due to the surface band bending. The InxGa1−xN films (x = 0–0.21 exhibited upward surface band bending, and the valence band maximum was shifted to lower binding energy when the mole fraction of InN was increased. On the other hand, downward surface band bending was confirmed for an InN film with low carrier density despite its n-type conduction. Although the Fermi level (EF near the surface of the InN film was detected inside the conduction band as reported previously, it can be concluded that EF in the bulk of the film must be located in the band gap below the conduction band minimum.

  13. The wear resistance of cobalt free hard surfaced alloys in nuclear power conditions. Literary survey; Kobolttivapaiden pinnoitteiden kulumiskestaevyys ydinvoimalaitosolosuhteissa. Kirjallisuusselvitys

    Energy Technology Data Exchange (ETDEWEB)

    Kosonen, A.M. [VTT Manufacturing Technology, Espoo (Finland)

    1996-07-01

    Cobalt based alloys are widely used in nuclear power plants despite of the resulting increase of the activity level in primary circuit. The other remarkable source of cobalt is construction materials, in which cobalt is as an impurity element. This report presents the research results from work done in England, USA, Canada, Japan, Sweden and France during the last few years. For example EPRI has funded the research of iron based NOREM surfacing alloys. In Japan iron based CORELOY and Cobaless surfacing alloys as well as ceramic coatings have been investigated. There are plenty of promising results from new cobalt free surfacing alloys in comparison with Stellite 6. The final approvement can be done only when these surfacing alloys have been used in real size valves. When evaluating the behaviour of cobalt free alloys in real circumstances one has to take into account especially the type, size and design of a valve and the welding method. (orig.) (25 refs.).

  14. Development of bacterial biofilms on artificial corals in comparison to surface-associated microbes of hard corals.

    Directory of Open Access Journals (Sweden)

    Michael John Sweet

    Full Text Available Numerous studies have demonstrated the differences in bacterial communities associated with corals versus those in their surrounding environment. However, these environmental samples often represent vastly different microbial micro-environments with few studies having looked at the settlement and growth of bacteria on surfaces similar to corals. As a result, it is difficult to determine which bacteria are associated specifically with coral tissue surfaces. In this study, early stages of passive settlement from the water column to artificial coral surfaces (formation of a biofilm were assessed. Changes in bacterial diversity (16S rRNA gene, were studied on artificially created resin nubbins that were modelled from the skeleton of the reef building coral Acropora muricata. These models were dip-coated in sterile agar, mounted in situ on the reef and followed over time to monitor bacterial community succession. The bacterial community forming the biofilms remained significantly different (R = 0.864 p<0.05 from that of the water column and from the surface mucus layer (SML of the coral at all times from 30 min to 96 h. The water column was dominated by members of the α-proteobacteria, the developed community on the biofilms dominated by γ-proteobacteria, whereas that within the SML was composed of a more diverse array of groups. Bacterial communities present within the SML do not appear to arise from passive settlement from the water column, but instead appear to have become established through a selection process. This selection process was shown to be dependent on some aspects of the physico-chemical structure of the settlement surface, since agar-coated slides showed distinct communities to coral-shaped surfaces. However, no significant differences were found between different surface coatings, including plain agar and agar enhanced with coral mucus exudates. Therefore future work should consider physico-chemical surface properties as

  15. In-situ investigation of laser surface modifications of WC-Co hard metals inside a scanning electron microscope

    Science.gov (United States)

    Mueller, H.; Wetzig, K.; Schultrich, B.; Pompe, Wolfgang; Chapliev, N. I.; Konov, Vitaly I.; Pimenov, S. M.; Prokhorov, Alexander M.

    1989-05-01

    The investigation of laser interaction with solid surfaces and of the resulting mechanism of surface modification are of technical interest to optimize technological processes, and they are also of fundamental scientific importance. Most instructive indormation is available with the ail of the in-situ techniques. For instance, measuring of the photon emission of the irradiated surface ane the plasma torch (if it is produced) simultaneously to laser action, makes it possible to gain a global characterization of the laser-solid interaction. In order to obtain additional information about surface and structure modifications in microscopic detail , a laser and scanning electron microscope were combined in to a tandem equipment (LASEM). Inside this eqiipment the microscopic observation is carried out directly at the laser irradiated area without any displacement of the sample. In this way, the stepwise development of surface modification during multipulse irradiation is visible in microscopic details and much more reliable information about the surface modification process is obtainable in comparison to an external laser irradiation. Such kind of equipments were realized simultaneously and independently in the Institut of General Physics (Moscow) and the Central Institute of Solid State Physics and Material Research (Dresden) using a CO2 and a LTd-glass-laser, respectively. In the following the advantages and possibilities of a LASEM shall be demonstrated by some selected investigations of WC-CO hardmeta. The results were obtained in collaboration by both groups with the aid of the pulsed CO2-laser. The TEA CO2 laser was transmitted through a ZnSe-window into the sample chamber of the SEM and focused ofAo tfte sample surface. It was operated in TEM - oo mode with a repetition rate of about 1 pulse per second. A peak power density of about 160 MW/cm2 was achieved in front of the sample surface.

  16. Analysis of roughness and surface hardness of a dental composite using atomic force microscopy and microhardness testing.

    Science.gov (United States)

    da Silva, Marcos Aurélio Bomfim; Fardin, Aline Barbirato; de Vasconcellos, Renata Carvalho Cabral; Santos, Lucineide de Melo; Tonholo, Josealdo; da Silva, José Ginaldo; dos Reis, José Ivo Limeira

    2011-06-01

    The objective of this study was to evaluate the influence of a cola soft drink (CSD) and coffee on the microhardness and surface roughness of composite resin. Fifty cavities were prepared on the vestibular surface of bovine incisors and restored with nanoparticulate resin. The teeth were divided into five groups (n = 10): group A (control), immersion in artificial saliva (AS) for 14 days; group B, immersion in coffee for 15 min (3×/day) for 7 days followed by immersion in AS for another 7 days; group C, immersion in CSD for 15 min (3×/day) for 7 days followed by immersion in AS for another 7 days; group D, immersion in AS for 7 days, immersion in coffee for 15 min (3×/day) for 7 days; group E, immersion in AS for 7 days, immersion in CSD for 15 min (3×/day) for 7 days. After the immersion periods the specimens were analyzed for their microhardness and surface roughness. The data were subjected to analysis of variance (ANOVA) followed by t-test with 5% significance. Group A presented the highest average microhardness and lowest surface roughness, so it was possible to conclude that the consumption of CSD and coffee alters the microhardness and surface roughness of new restorations.

  17. Effect of laser surface hardening on the microstructure, hardness and residual stresses of austempered ductile iron grades

    Energy Technology Data Exchange (ETDEWEB)

    Soriano, C., E-mail: csoriano@tekniker.es [Tekniker-IK4, Manufacturing Processes Department, Avda. Otaola 20, CP-20600, Eibar (Gipuzkoa) (Spain); Leunda, J.; Lambarri, J.; Garcia Navas, V.; Sanz, C. [Tekniker-IK4, Manufacturing Processes Department, Avda. Otaola 20, CP-20600, Eibar (Gipuzkoa) (Spain)

    2011-06-01

    A study of the laser surface hardening process of two austempered ductile iron grades, with different austempering treatments has been carried out. Hardening was performed with an infrared continuous wave Nd:YAG laser in cylindrical specimens. The microstructure of the laser hardened samples was investigated using an optical microscope, microhardness profiles were measured and surface and radial residual stresses were studied by an X-ray diffractometer. Similar results were achieved for both materials. A coarse martensite with retained austenite structure was found in the treated area, resulting in a wear resistant effective layer of 0.6 mm to 1 mm with a microhardness between 650 HV and 800 HV. Compressive residual stresses have been found at the hardened area being in agreement with the microhardness and microstructural variations observed. The achieved results point out that the laser surface hardening is a suitable method for improving the mechanical properties of austempered ductile irons.

  18. Characterization of a flat superpolished mandrel prototype with hard (TiN / SiC) overcoating to enhance the surface durability

    CERN Document Server

    Spiga, D

    2015-01-01

    A number of hard X-Ray (10 - 100 KeV) astronomical missions of near future will make use of multilayer-coated focusing mirrors. The technology based on Nickel electroformed replication is suitable for the multilayer optics realization, since multi-modular telescopes are foreseen. For example, for the Constellation-X mission there is the need of realizing up to 14 identical modules (12 flight modules plus two spares) which can be replicated by the same series of mandrels. The Ni replication approach is derived from the method already successfully used for making the Au coated soft X-ray mirrors with good imaging performances of the missions BeppoSAX, XMM-Newton and Swift. In the technological extension of the process to the multilayer optics fabrication, it would be convenient to overcoat the external surface of mandrels (normally in Kanigen) with a layer made of a very hard material. This would help to maintain the very low roughness level requested by the application (typically less than a couple of Angstrom...

  19. Profiling the progression of cancer: separation of microsomal proteins in MCF10 breast epithelial cell lines using nonporous chromatophoresis.

    Science.gov (United States)

    O'Neil, Kimberly A; Miller, Fred R; Barder, Timothy J; Lubman, David M

    2003-07-01

    The heterogeneity of cellular protein expression has stimulated development of separations targeting smaller groups of related proteins rather than entire proteomes. The following work describes the development of a technique for the characterization of membrane subproteomes from five different breast epithelial cell lines. Intact membrane proteins are separated by hydrophobicity in the first dimension using nonporous reversed-phase high-performance liquid chromatography (RP-HPLC) to generate unique chromatographic profiles. Fractions of eluent are further separated using sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) to create distinct banding patterns. This hybrid liquid phase/gel phase method circumvents issues of membrane protein precipitation and provides a simple strategy aimed at isolating and characterizing a traditionally underrepresented protein class. Membrane protein profiles are created that discriminate between microsomal fractions of breast epithelial cells in different stages of neoplastic progression. Proteins are subsequently identified using matrix-assisted laser desorption/ionization - mass spectrometry (MALDI-MS) mass fingerprinting and MALDI-quadrupole time of flight - tandem mass spectrometry (QTOF-MS/MS) peptide sequencing. Furthermore, as this strategy preserves intact protein structure, further characterization can be performed on proteins producing mass fingerprint spectra and fragmentation spectra that did not result in database protein identifications. The coupling of nonporous RP-HPLC with SDS-PAGE provides a useful alternative to two-dimensional PAGE (2-D-PAGE) for membrane protein analysis.

  20. Morphological Study Of Border Area Of Pulp-Capping Materials And Er:YAG Laser Prepared Hard Dental Surface

    Directory of Open Access Journals (Sweden)

    Stefanova Vessela P.

    2015-03-01

    Full Text Available Introduction: Vital pulp therapy involves biologically based therapeutic activities aimed at restoring health and preserving the vitality of cariously or traumatically damaged pulp. Adaptation of pulp-capping materials to the prepared tooth surface may be the key to the success of biological tooth treatment.

  1. 40 CFR 761.369 - Pre-cleaning the surface.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Pre-cleaning the surface. 761.369... PROHIBITIONS Double Wash/Rinse Method for Decontaminating Non-Porous Surfaces § 761.369 Pre-cleaning the surface. If visible PCB-containing liquid is present on the surface to be cleaned, thoroughly wipe or...

  2. Morphological Study Of Border Area Of Pulp-Capping Materials And Er:YAG Laser Prepared Hard Dental Surface.

    Science.gov (United States)

    Stefanova, Vessela P; Tomov, Georgi T; Tsanova, Snezhana Ts

    2015-01-01

    Vital pulp therapy involves biologically based therapeutic activities aimed at restoring health and preserving the vitality of cariously or traumatically damaged pulp. Adaptation of pulp-capping materials to the prepared tooth surface may be the key to the success of biological tooth treatment. To investigate the area of adaptation of synthetic tricalcium silicate cement, calcium hydroxide cement and mineral trioxide-aggregate to the dentin surface, prepared with the help of Er:YAG dental laser. Four extracted human tooth cavities were prepared with the help of Er:YAG dental laser (LiteTouch, Syneron, Israel), establishing microcommunication with the pulp chamber less than 1 mm in diameter. As pulp-capping materials in the cavities we used tricalcium silicate cement (Biodentine, Septodont, France), calcium hydroxide cement (Dycal) and mineral-trioxide aggregate (ProRoot MTA), stirred and administered according to manufacturers' instructions. The first material fills the whole cavity and the other two are spread in a thin layer and sealed with glass ionomer cement. Thus prepared, the samples were left for three days at 37°C in humidified environment. The samples were prepared for scanning electron microscopy (SEM) by standard methodology. The border area surfaces of the materials and the dentin were scanned using electron microscopy. The morphological changes occurring to the Er:YAG laser prepared dentin and the structural characteristics of the studied pulp-capping materials are demonstrated using scanograms. The border areas where good contact of materials and dentinal tubules is established are thoroughly studied. Good adaptation is seen in three-calcium silicate cement, followed by mineral trioxide aggregate and calcium hydroxide cement. The dentin surface, prepared with Er:YAG laser demonstrates a very good adaptation of the three tested pulp-capping materials.

  3. Tribological characterization of selected hard coatings

    OpenAIRE

    Karlsson, Patrik

    2009-01-01

    Hard coatings are often used for protection of tool surfaces due to coating properties like low friction and high wear resistance. Even though many of the hard coatings have been tested for wear, it is important to try new wear test setups to fully understand tribological mechanisms and the potential of hard coatings. Few experiments have been performed with dual-coated systems where the sliding contact surfaces are coated with the same, or different, hard coating. The dual-coated system coul...

  4. Standard hardness conversion tables for metals relationship among brinell hardness, vickers hardness, rockwell hardness, superficial hardness, knoop hardness, and scleroscope hardness

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2007-01-01

    1.1 Conversion Table 1 presents data in the Rockwell C hardness range on the relationship among Brinell hardness, Vickers hardness, Rockwell hardness, Rockwell superficial hardness, Knoop hardness, and Scleroscope hardness of non-austenitic steels including carbon, alloy, and tool steels in the as-forged, annealed, normalized, and quenched and tempered conditions provided that they are homogeneous. 1.2 Conversion Table 2 presents data in the Rockwell B hardness range on the relationship among Brinell hardness, Vickers hardness, Rockwell hardness, Rockwell superficial hardness, Knoop hardness, and Scleroscope hardness of non-austenitic steels including carbon, alloy, and tool steels in the as-forged, annealed, normalized, and quenched and tempered conditions provided that they are homogeneous. 1.3 Conversion Table 3 presents data on the relationship among Brinell hardness, Vickers hardness, Rockwell hardness, Rockwell superficial hardness, and Knoop hardness of nickel and high-nickel alloys (nickel content o...

  5. Hard X-ray photoelectron spectra (HXPES) of bulk non-conductor vitreous SiO{sub 2}: Minimum linewidths and surface chemical shifts

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Y.F., E-mail: Yongfeng.hu@lightsource.ca [Canadian Light Source, Saskatoon, SK (Canada); Xiao, Q.; Wang, D.; Cui, X. [Canadian Light Source, Saskatoon, SK (Canada); Nesbitt, H.W. [Department of Earth Sciences, University of Western Ontario, London, ONT (Canada); Bancroft, G.M. [Department of Chemistry, University of Western Ontario, London, ONT (Canada)

    2015-07-15

    Highlights: • Electronic structure of non-conducting glass studied by hard X-ray photoelectron spectroscopy. • A thin film of Cr was deposited on the vitreous SiO{sub 2} glass to overcome the sample charging. • Excellent O 1s and Si 1s linewidths were obtained, matching those reported using the laboratory based Kratos Axis Ultra spectrometer equipped with a magnetic compensation system. • The bulk and interface states of non-conducting samples are studied as a function of photon energy. - Abstract: Hard X-ray photoelectron spectra (2200 eV to 5000 eV photon energies) have been obtained for the first time on a bulk non-conductor, vitreous SiO{sub 2}, on a high resolution (E/ΔE of 10,000) synchrotron beamline at the Canadian Light Source (CLS). To minimize charging and differential charging, the SiO{sub 2} was coated with very thin layers (0.5 to 1.5 nm) of Cr metal. The O 1s linewidth obtained at 2500 eV photon energy was 1.26 eV—the minimum linewidth for SiO{sub 2}—and in good agreement with that obtained at 1486 eV on a Kratos Axis Ultra spectrometer equipped with a magnetic charge compensation system. The Si 1s linewidth of 1.5 eV, somewhat broader than that previously obtained at 1486 eV on the Si 2p{sub 3/2} line of 1.16 eV, is mainly due to the much larger inherent Si 1s linewidth (0.5 eV) compared to the inherent Si 2p linewidth (<0.1 eV). Both linewidths are dominated by the large final state vibrational broadening previously described. The Cr coating produces surface monolayers of interfacial Cr “suboxide” (Cr-subox), Cr metal, and a surface Cr oxide (Cr-surfox). Cr-subox (Si−O−Cr) gives rise to the weak near-surface Si 1s peak, while both oxides give rise to both the weak surface O 1s peak and the Cr 2p oxide peak. Both the O 1s and Si 1s surface peaks are shifted by ∼2 eV relative to the large bulk Si 1s and O 1s peaks. The weak Si 1s and O 1s surface peaks along with the Cr 2p oxide peak decrease in intensity greatly as the photon

  6. Rigid, non-porous and tunable hybrid p-aminobenzoate/TiO2 materials: Toward a fine structural determination of the immobilized RhCl(Ph3)3 complex

    KAUST Repository

    Espinas, Jeff

    2015-05-01

    By exchange of ligands, Wilkinson complex RhCl(PPh3)3 are immobilized on p-aminobenzoate/TiO2 with different organic loading (6, 11 and 16%). This new hybrid material exhibit a linear correlation between the ligand content of the starting TiO2 and the rhodium loading, showing the accessibility of all surfaces amines fonctions on the non-porous parent materials. 1H, 13C, and 1D, 2D INAQUEDATE refocused and J-resolved 31P solid-state NMR confirm the well-defined structure [(≡TiO)2(n{right tail}2-O2C-C6H4-NH2)RhCl-cis-(PPh3)2]. New immobilized catalysts show interesting activity in cyclohexene hydroformylation.

  7. A new hand-held optical reflectometer to measure enamel erosion: correlation with surface hardness and calcium release.

    Science.gov (United States)

    Carvalho, Thiago Saads; Baumann, Tommy; Lussi, Adrian

    2016-04-28

    In the present study, the surface reflection intensity (SRI) was measured from enamel with different induced erosion degrees using a hand-held pen-size reflectometer (Hand-Held) and a Table-Top reflectometer. To validate the Hand-Held reflectometer, we correlated its optical signals with the change of surface microhardness (SMH), and amount of calcium released from the enamel samples during erosion. We used 124 tooth enamel specimens that were exposed to an erosive challenge of either 1, 2, 4, 6, 8, or 10 minutes. SRI and SMH were measured before and after the erosive challenge and we also measured the amount of calcium released to the citric acid. Relative SRI loss (rSRIloss) and relative SMH loss (rSMHloss) were calculated. rSRIloss from the Hand-Held and the Table-Top reflectometers were similar and significantly correlated to rSMHloss and calcium release. The regression analyses showed a significant association between rSRIloss from both reflectometers and rSMHloss and calcium, showing that both reflectometers can be used to measure erosive demineralization of enamel. The Hand-Held reflectometer is capable of assessing in vitro erosion, correlating to other commonly used methods. It is small, easy to handle and provides fast measurement, being a possible candidate to measure erosion in clinical studies.

  8. Collagen hydrogels incorporated with surface-aminated mesoporous nanobioactive glass: Improvement of physicochemical stability and mechanical properties is effective for hard tissue engineering.

    Science.gov (United States)

    El-Fiqi, Ahmed; Lee, Jae Ho; Lee, Eun-Jung; Kim, Hae-Won

    2013-12-01

    Collagen (Col) hydrogels have poor physicochemical and mechanical properties and are susceptible to substantial shrinkage during cell culture, which limits their potential applications in hard tissue engineering. Here, we developed novel nanocomposite hydrogels made of collagen and mesoporous bioactive glass nanoparticles (mBGns) with surface amination, and addressed the effects of mBGn addition (Col:mBG = 2:1, 1:1 and 1:2) and its surface amination on the physicochemical and mechanical properties of the hydrogels. The amination of mBGn was shown to enable chemical bonding with collagen molecules. As a result, the nanocomposite hydrogels exhibited a significantly improved physicochemical and mechanical stability. The hydrolytic and enzymatic degradation of the Col-mBGn hydrogels were slowed down due to the incorporation of mBGn and its surface amination. The mechanical properties of the hydrogels, specifically the resistance to loading as well as the stiffness, significantly increased with the addition of mBGn and its aminated form, as assessed by a dynamic mechanical analysis. Mesenchymal stem cells cultivated within the Col-mBGn hydrogels were highly viable, with enhanced cytoskeletal extensions, due to the addition of surface aminated mBGn. While the Col hydrogel showed extensive shrinkage (down to ∼20% of initial size) during a few days of culture, the shrinkage of the mBGn-added hydrogel was substantially reduced, and the aminated mBGn-added hydrogel had no observable shrinkage over 21 days. Results demonstrated the effective roles of aminated mBGn in significantly improving the physicochemical and mechanical properties of Col hydrogel, which are ultimately favorable for applications in stem cell culture for bone tissue engineering.

  9. Polished Stone Value Test and its relationship with petrographic parameters (hardness contrast and modal composition and surface micro-roughness in natural and artificial aggregates

    Directory of Open Access Journals (Sweden)

    Fernández, A.

    2013-09-01

    Full Text Available The goal of this work was first to establish the relationships between the PSV values and the microstructural and mineralogical features of the aggregates and surface micro-roughness, and then to establish the behavioural differences between natural and artificial aggregates. The results obtained indicate that the surface micro-roughness and the different PSV values of the natural aggregates are strongly governed by the existence of minerals with different degrees of hardness, together with the proportion of these minerals. In contrast, the different degree of porosity in artificial aggregates (a furnace slag was seen to be responsible for its high surface micro-roughness and PSV values. Finally, the PSV and a petrographic parameter (Overall Hardness Contrast, ΔH were seen to be related by an exponential curve (PSV=39.726ΔH0.057 with an extremely good fit, providing a good tool to estimate PSVs in natural and artificial aggregates from petrographic parameters.El objetivo de este trabajo es establecer, por un lado, las relaciones existentes del CPA con las características petrográficas de los áridos, así como su microrrugosidad superficial y, por otro, las diferencias de comportamiento entre áridos naturales y artificiales. Los resultados indican que en los áridos naturales la microrrugosidad superficial y el diferente valor del CPA están determinados, en gran medida, por las diferencias de dureza de sus minerales y también por la proporción en la que estos minerales se encuentran en las distintas litologías. Sin embargo, en los áridos artificiales (escorias de fundición su elevada porosidad es la responsable de su marcada microrrugosidad superficial y su elevado valor del CPA. Finalmente, se relaciona el CPA con un parámetro petrográfico (Contraste de Dureza Global, ΔH mediante una curva exponencial, cuyo excelente índice de regresión hace que sea factible estimar mediante el estudio petrográfico de un árido su valor del CPA

  10. A preliminary study on pressure-plate evaluation of forelimb toe-heel and mediolateral hoof balance on a hard vs. a soft surface in sound ponies at the walk and trot

    NARCIS (Netherlands)

    Oosterlinck, M; Royaux, E; Back, W|info:eu-repo/dai/nl/125023707; Pille, F

    2014-01-01

    REASONS FOR PERFORMING STUDY: Thus far, pressure-plate analysis has been limited to measurements on a hard surface, whereas equine athletes routinely perform on a deformable substrate. OBJECTIVES: To explore pressure-plate analysis on arena footing. STUDY DESIGN: Nonrandomised crossover study using

  11. A preliminary study on pressure-plate evaluation of forelimb toe-heel and mediolateral hoof balance on a hard vs. a soft surface in sound ponies at the walk and trot

    NARCIS (Netherlands)

    Oosterlinck, M; Royaux, E; Back, W; Pille, F

    2014-01-01

    REASONS FOR PERFORMING STUDY: Thus far, pressure-plate analysis has been limited to measurements on a hard surface, whereas equine athletes routinely perform on a deformable substrate. OBJECTIVES: To explore pressure-plate analysis on arena footing. STUDY DESIGN: Nonrandomised crossover study using

  12. The wear resistance of cobalt free hard surfaced alloys in nuclear power plant conditions. Test results; Kobolttivapaiden pinnoitteiden kulumiskestaevyys ydinvoimalaitosolosuhteissa. Koetulokset

    Energy Technology Data Exchange (ETDEWEB)

    Kosonen, A.M. [VTT Manufacturing Technology, Espoo (Finland)

    1996-09-01

    Use of cobalt containing materials is restricted in primary circuits of nuclear power plants since the cobalt is activated in the reactor core. The resulting isotope leads to increase of activity in the primary circuit. This report presents the results of the wear resistance tests of four hard facing alloys. The test method was a pin on plate test. The pins were coated with hard-facing alloys and the plates were manufactured from stainless steel. The tested materials were nickel based Stellite 6, wolfram carbide (WC), METCO 442 and cobalt based Stellite 6. Tests were carried out in simulated BWR-environment. According to the results of these tests it is not possible to get any differences between any hard facing alloys if the hardness of the plate material is much lower than that of the hard facing alloys examined. (orig.) (4 refs.).

  13. Virucidal Activity of Fogged Chlorine Dioxide- and Hydrogen Peroxide-Based Disinfectants against Human Norovirus and Its Surrogate, Feline Calicivirus, on Hard-to-Reach Surfaces

    Directory of Open Access Journals (Sweden)

    Naim Montazeri

    2017-06-01

    Full Text Available Human norovirus (NoV is the leading cause of foodborne illnesses in the United States. Norovirus is shed in high numbers in the feces and vomitous of infected individuals. Contact surfaces contaminated with bodily fluids harboring infectious virus particles serve as vehicles for pathogen transmission. Environmental stability of NoV and its resistance to many conventional disinfectants necessitate effective inactivation strategies to control the spread of virus. We investigated the efficacy of two commercial disinfectants, hydrogen peroxide (7.5% and a chlorine dioxide (0.2%-surfactant-based product using a fogging delivery system against human NoV GI.6 and GII.4 Sydney strains as well as the cultivable surrogate, feline calicivirus (FCV dried on stainless steel coupons. Log10 reductions in human NoV and FCV were calculated utilizing RNase RT-qPCR and infectivity (plaque assay, respectively. An improved antiviral activity of hydrogen peroxide as a function of disinfectant formulation concentration in the atmosphere was observed against both GII.4 and FCV. At 12.4 ml/m3, hydrogen peroxide achieved a respective 2.5 ± 0.1 and 2.7 ± 0.3 log10 reduction in GI.6 and GII.4 NoV genome copies, and a 4.3 ± 0.1 log10 reduction in infectious FCV within 5 min. At the same disinfectant formulation concentration, chlorine dioxide-surfactant-based product resulted in a respective 1.7 ± 0.2, 0.6 ± 0.0, and 2.4 ± 0.2 log10 reduction in GI.6, GII.4, and FCV within 10 min; however, increasing the disinfectant formulation concentration to 15.9 ml/m3 negatively impacted its efficacy. Fogging uniformly delivered the disinfectants throughout the room, and effectively decontaminated viruses on hard-to-reach surfaces. Hydrogen peroxide delivered by fog showed promising virucidal activity against FCV by meeting the United States EPA 4-log10 reduction criteria for an anti-noroviral disinfectant; however, fogged chlorine dioxide-surfactant-based product did not achieve

  14. Virucidal Activity of Fogged Chlorine Dioxide- and Hydrogen Peroxide-Based Disinfectants against Human Norovirus and Its Surrogate, Feline Calicivirus, on Hard-to-Reach Surfaces.

    Science.gov (United States)

    Montazeri, Naim; Manuel, Clyde; Moorman, Eric; Khatiwada, Janak R; Williams, Leonard L; Jaykus, Lee-Ann

    2017-01-01

    Human norovirus (NoV) is the leading cause of foodborne illnesses in the United States. Norovirus is shed in high numbers in the feces and vomitous of infected individuals. Contact surfaces contaminated with bodily fluids harboring infectious virus particles serve as vehicles for pathogen transmission. Environmental stability of NoV and its resistance to many conventional disinfectants necessitate effective inactivation strategies to control the spread of virus. We investigated the efficacy of two commercial disinfectants, hydrogen peroxide (7.5%) and a chlorine dioxide (0.2%)-surfactant-based product using a fogging delivery system against human NoV GI.6 and GII.4 Sydney strains as well as the cultivable surrogate, feline calicivirus (FCV) dried on stainless steel coupons. Log10 reductions in human NoV and FCV were calculated utilizing RNase RT-qPCR and infectivity (plaque) assay, respectively. An improved antiviral activity of hydrogen peroxide as a function of disinfectant formulation concentration in the atmosphere was observed against both GII.4 and FCV. At 12.4 ml/m(3), hydrogen peroxide achieved a respective 2.5 ± 0.1 and 2.7 ± 0.3 log10 reduction in GI.6 and GII.4 NoV genome copies, and a 4.3 ± 0.1 log10 reduction in infectious FCV within 5 min. At the same disinfectant formulation concentration, chlorine dioxide-surfactant-based product resulted in a respective 1.7 ± 0.2, 0.6 ± 0.0, and 2.4 ± 0.2 log10 reduction in GI.6, GII.4, and FCV within 10 min; however, increasing the disinfectant formulation concentration to 15.9 ml/m(3) negatively impacted its efficacy. Fogging uniformly delivered the disinfectants throughout the room, and effectively decontaminated viruses on hard-to-reach surfaces. Hydrogen peroxide delivered by fog showed promising virucidal activity against FCV by meeting the United States EPA 4-log10 reduction criteria for an anti-noroviral disinfectant; however, fogged chlorine dioxide-surfactant-based product did not achieve a 4-log10

  15. Preparation of Immobilized Metal Affinity Chromatographic Packings Based on Monodisperse Hydrophilic Non-porous Beads and Their Application

    Institute of Scientific and Technical Information of China (English)

    BO Chun-Miao; GONG Bo-Lin; HU Wen-Zhi

    2008-01-01

    Three hydrophilic immobilized metal affinity chromatographic packings for HPLC have been synthesized by chemical modification of 3.0 μm monodisperse non-porous poly(glycidyl methacrylate-co-ethylenedimethacrylate)(PGMMEDMA)beads.The retention behavior of proteins on the metal ion chelated columns loaded with copper(Ⅱ),nickel(Ⅱ)and zin(Ⅱ)ion was studied.The effect of pH on the protein retention Was investigated on both the naked and metal ion chelated columns in the range from 4.0 to 9.0.Four proteins were quickly separated in 3.0 min with linear gradient elution at a flow rate of 3.0 mL/min by using the synthesized Ni2+ -IDA(iminodiacetic acid)packings.The separation time was shorter than other immobilized metal affinity chromatography reported in the literature.Purification of lysozyme from egg white and trypsin on the commercially available trypsin was performed on the naked-IDA and Cu2+ -IDA columns,respectively.The purities of the purified trypsin and lysozyme were more than 92%and 95%,respectively.

  16. New mechanisms for non-porative ultrasound stimulation of cargo delivery to cell cytosol with targeted perfluorocarbon nanoparticles

    Science.gov (United States)

    Soman, N. R.; Marsh, J. N.; Lanza, G. M.; Wickline, S. A.

    2008-05-01

    The cell membrane constitutes a major barrier for non-endocytotic intracellular delivery of therapeutic molecules from drug delivery vehicles. Existing approaches to breaching the cell membrane include cavitational ultrasound (with microbubbles), electroporation and cell-penetrating peptides. We report the use of diagnostic ultrasound for intracellular delivery of therapeutic bulky cargo with the use of molecularly targeted liquid perfluorocarbon (PFC) nanoparticles. To demonstrate the concept, we used a lipid with a surrogate polar head group, nanogold-DPPE, incorporated into the nanoparticle lipid monolayer. Melanoma cells were incubated with nanogold particles and this was followed by insonication with continuous wave ultrasound (2.25 MHz, 5 min, 0.6 MPa). Cells not exposed to ultrasound showed gold particles partitioned only in the outer bilayer of the cell membrane with no evidence of the intracellular transit of nanogold. However, the cells exposed to ultrasound exhibited numerous nanogold-DPPE components inside the cell that appeared polarized inside intracellular vesicles demonstrating cellular uptake and trafficking. Further, ultrasound-exposed cells manifested no incorporation of calcein or the release of lactate dehydrogenase. These observations are consistent with a mechanism that suggests that ultrasound is capable of stimulating the intracellular delivery of therapeutic molecules via non-porative mechanisms. Therefore, non-cavitational adjunctive ultrasound offers a novel paradigm in intracellular cargo delivery from PFC nanoparticles.

  17. Non-porous metal membranes for selective separation of hydrogen from gas mixtures at higher temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Winkelmann, U.; Schulten, R.; Weirich, W.; Kuegler, B.; Luecke, L.; Oertel, M.; Pietsch, M.; Schmitz, J.

    1986-10-01

    Materials for selective separation of hydrogen from gas mixtures by means of a metal membrane must have high permeability for dissolved oxygen, catalytically active surfaces, and mechanical stability in a hydrogen atmosphere. The transition metals Nb, Ta, and V have high hydrogen permeability, but they must be coated with a catalytically active Pd alloy in order to permit hydrogen permeation. The alloy TiNi can be used without a noble metal coating.

  18. 3种消毒方法对石膏模型表面硬度的影响%Influence of three kinds of disinfection methods on surface hardness of gypsum casts

    Institute of Scientific and Technical Information of China (English)

    曹明国; 吴世莲; 陆林侦; 查光玉

    2012-01-01

    目的 研究3种消毒方法对口腔石膏模型表面硬度的影响.方法 制作圆柱体金属模具,硅橡胶取模,分别灌注熟石膏、硬石膏和超硬石膏模型,分别用3种消毒方法对其消毒,包括微波加热、高温高压及紫外线照射,消毒后测定其表面硬度,并进行统计分析.结果 微波加热及紫外线照射对3种石膏模型消毒后,表面硬度差异无统计学意义;高温高压消毒处理后的熟石膏组、硬石膏组、超硬石膏组的表面硬度分别为(3.70±0.25)、(4.46±0.30)、(4.93±0.85)Pa,均比对照组明显降低(P<0.01).结论 微波加热及紫外线照射对石膏模型消毒后,在表面硬度方面对模型无明显影响.%OBJECTIVE To study the influence of three kinds of disinfection methods on surface hardness of oral gypsum casts. METHODS The metal cylinder mould and silicone impression was made. Three kinds of gypsum casts including plaster, dental stone, and high strength dental stone were made and disinfected by three kinds of disinfection methods, which were microwave heating, high temperature and pressure and ultraviolet radiation disinfection. After disinfection, the surface hardness was tested and the statistical analysis was performed. RESULTS Disinfection with microwave heating and ultraviolet radiation did not affect the surface hardness of three kinds of gypsum casts, the difference in surface hardness was not statistically significant; the hardness of three kinds of plaster, dental stone, and high strength dental stone after the disinfection with high temperature and pressure were (3. 70 ± 0. 25, 4. 46 ± 0. 30, and 4. 93 ± 0. 85)Pa, with a significant decreases as compared with the control group (P < 0. 01). CONCLUSION Disinfection by microwave heating and ultraviolet radiation has no significant influence on the surface hardness of the gypsum casts.

  19. Standard test methods for rockwell hardness of metallic materials

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2011-01-01

    1.1 These test methods cover the determination of the Rockwell hardness and the Rockwell superficial hardness of metallic materials by the Rockwell indentation hardness principle. This standard provides the requirements for Rockwell hardness machines and the procedures for performing Rockwell hardness tests. 1.2 This standard includes additional requirements in annexes: Verification of Rockwell Hardness Testing Machines Annex A1 Rockwell Hardness Standardizing Machines Annex A2 Standardization of Rockwell Indenters Annex A3 Standardization of Rockwell Hardness Test Blocks Annex A4 Guidelines for Determining the Minimum Thickness of a Test Piece Annex A5 Hardness Value Corrections When Testing on Convex Cylindrical Surfaces Annex A6 1.3 This standard includes nonmandatory information in appendixes which relates to the Rockwell hardness test. List of ASTM Standards Giving Hardness Values Corresponding to Tensile Strength Appendix X1 Examples of Procedures for Determining Rockwell Hardness Uncertainty Appendix X...

  20. Standard test methods for rockwell hardness of metallic materials

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    1.1 These test methods cover the determination of the Rockwell hardness and the Rockwell superficial hardness of metallic materials by the Rockwell indentation hardness principle. This standard provides the requirements for Rockwell hardness machines and the procedures for performing Rockwell hardness tests. 1.2 This standard includes additional requirements in annexes: Verification of Rockwell Hardness Testing Machines Annex A1 Rockwell Hardness Standardizing Machines Annex A2 Standardization of Rockwell Indenters Annex A3 Standardization of Rockwell Hardness Test Blocks Annex A4 Guidelines for Determining the Minimum Thickness of a Test Piece Annex A5 Hardness Value Corrections When Testing on Convex Cylindrical Surfaces Annex A6 1.3 This standard includes nonmandatory information in appendixes which relates to the Rockwell hardness test. List of ASTM Standards Giving Hardness Values Corresponding to Tensile Strength Appendix X1 Examples of Procedures for Determining Rockwell Hardness Uncertainty Appendix X...

  1. Modification of surface hardness for dual two-phase Ni{sub 3}Al–Ni{sub 3}V intermetallic compound by using energetic ion beam and subsequent thermal treatment

    Energy Technology Data Exchange (ETDEWEB)

    Yoshizaki, H., E-mail: su110040@edu.osakafu-u.ac.jp [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Hashimoto, A.; Kaneno, Y. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Semboshi, S. [Kansai-Center, Institute for Materials Research, Tohoku University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Okamoto, Y. [Quantum Beam Science Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan)

    2015-02-15

    Dual two-phase Ni{sub 3}Al–Ni{sub 3}V intermetallic compound with the ordered structure was irradiated with 16 MeV Au{sup 5+} ions at room temperature. The observation by a transmission electron microscope has revealed that the lattice structure of this intermetallic compound changes from the ordered structure to the disordered A1 (fcc) structure by the ion irradiation, which accompanies a remarkable decrease in the surface hardness. The annealing treatment at elevated temperatures for the irradiated specimen induces the recovery of surface hardness. The present experimental result shows that the combination of energetic ion irradiation and the thermal treatment could be a means of modification for the workability of dual two-phase Ni{sub 3}Al–Ni{sub 3}V intermetallic compound.

  2. Ultrasonic material hardness depth measurement

    Science.gov (United States)

    Good, Morris S.; Schuster, George J.; Skorpik, James R.

    1997-01-01

    The invention is an ultrasonic surface hardness depth measurement apparatus and method permitting rapid determination of hardness depth of shafts, rods, tubes and other cylindrical parts. The apparatus of the invention has a part handler, sensor, ultrasonic electronics component, computer, computer instruction sets, and may include a display screen. The part handler has a vessel filled with a couplant, and a part rotator for rotating a cylindrical metal part with respect to the sensor. The part handler further has a surface follower upon which the sensor is mounted, thereby maintaining a constant distance between the sensor and the exterior surface of the cylindrical metal part. The sensor is mounted so that a front surface of the sensor is within the vessel with couplant between the front surface of the sensor and the part.

  3. Hard sphere model of atom

    CERN Document Server

    Tsekov, R

    2014-01-01

    The finite size effect of electron and nucleus is accounted for in the model of atom. Due to their hard sphere repulsion the energy of the 1s orbital decreases and the corrections amount up to 8 % in Uranium. Several models for boundary conditions on the atomic nucleus surface are discussed as well.

  4. Analysis of the development and performance of hard disks

    OpenAIRE

    Novak, Davorin

    2010-01-01

    With the emergence of new technologies in the field of hard drives we can witness a significant increase of surface density and transfer rate of interfaces which, as a result, enables greater performance and reliability of hard disks. The reason for this are increasing needs for higher capacities and data transfer rate to or from the hard disk. This thesis presents the structure of hard drives, features, performance and reliability of hard drives and alternative data storage technologies. Par...

  5. Experimental investigation of cutting parameters influence on surface roughness and cutting forces in hard turning of X38CrMoV5-1 with CBN tool

    Indian Academy of Sciences (India)

    H Aouici; M A Yallese; A Belbah; M F Ameur; M Elbah

    2013-06-01

    This experimental investigation was conducted to determine the effects of cutting conditions on surface roughness and cutting forces in hard turning of X38CrMoV5-1. This steel was hardened at 50 HRC and machined with CBN tool. This is employed for the manufacture of helicopter rotor blades and forging dies. Combined effects of three cutting parameters, namely cutting speed, feed rate and depth of cut, on the six performance outputs-surface roughness parameters and cutting force components, are explored by analysis of variance (ANOVA). Optimal cutting conditions for each performance level are established. The relationship between the variables and the technological parameters is determined through the response surface methodology (RSM), using a quadratic regression model. Results show how much surface roughness is mainly influenced by feed rate and cutting speed. The depth of cut exhibits maximum influence on cutting force components as compared to the feed rate and cutting speed.

  6. LC4铝合金表面硬质阳极氧化膜制备及表征%Preparation and Characterization of Hard Anodic Oxidation Film on LC4 Aluminum Alloy Surface

    Institute of Scientific and Technical Information of China (English)

    王英才; 陈岁元; 刘平平

    2014-01-01

    目的:在 LC4铝合金表面制备硬质阳极氧化膜,讨论工艺参数对膜层厚度和硬度的影响。方法对阳极氧化的时间、温度、电流密度及正负脉冲电流时间比等参数进行优化实验,通过 OM,SEM,XRD 及显微硬度计等对制备的氧化膜层的厚度、硬度、形貌等进行研究。结果工艺优化后的参数为:温度-2~0℃,正脉冲电流密度4 A/ dm2,负脉冲电流密度1 A/ dm2,正负脉冲电流时间比6:1,氧化时间50 min。得到由一系列直径约为50 nm 的管状单元结构组成的氧化膜,其厚度为36μm,硬度为420HV。结论制备的阳极氧化膜具有致密的组织结构和高的硬度值。%Objective The hard anodic oxidation films were prepared on the surface of the LC4 aluminum alloy and the effects of different parameters on the thickness and hardness of the films were discussed. Methods By optimizing parameters of the anodic ox-idation time, temperature, current density and the positive and negative pulse time ratio, the thickness, hardness and microstruc-ture of the films were studied by means of OM, SEM, XRD, and hardness tester. Results The optimized parameters were: a tem-perature of -2 ~ 0 ℃ , a positive pulse current density of 4 A/ dm2 , a negative pulse current density of 1 A/ dm2 , a positive and negative pulse current time ratio of 6 : 1, and an oxidation time of 50 min. The structure of the oxide film on LC4 aluminum alloy was composed of a series of tubular cells with a diameter of 50 nm, the thickness of anodic oxidation film was 36 μm, and the hard-ness was 420HV. Conclusion The anodic oxidation film had fine structure and high hardness.

  7. The effect of theobromine 200 mg/l topical gel exposure duration against surface enamel hardness resistance from 1% citric acid

    Science.gov (United States)

    Herisa, H. M.; Noerdin, A.; Eriwati, Y. K.

    2017-08-01

    Theobromine can be used to prevent the demineralization of enamel and can stimulate the growth of new enamels. This study analyzes the effect of theobromine’s gel duration exposure on enamel hardness resistance from 1% citric acid. Twenty-eight specimens were divided into three experimental groups; were exposed to theobromine gel 200 mg/l for 16, 48, and 96 minutes; and were then immersed in 1% citric acid. The control group was only immersed in 1% citric acid. Results: A Wilcoxon test showed a significant increase and decrease in enamel microhardness after exposure to theobromine gel and citric acid (p enamel microhardness between different durations of exposure to theobromine gel and immersion in citric acid (p enamel microhardness but did not contribute to the enamel’s hardness resistance after immersion in 1% citric acid. The duration of theobromine gel application affected enamel microhardness and acid resistance.

  8. The combined effects of hardness, pH, and dissolved organic carbon on the chronic toxicity of Zn to D. magna: development of a surface response model.

    Science.gov (United States)

    Heijerick, D G; Janssen, C R; De Coen, W M

    2003-02-01

    The effect of changes in pH, hardness, and dissolved organic carbon (DOC) and the possible interactions among these parameters on the chronic toxicity of zinc to D. magna were investigated. Based on a Central Composite Design, models were developed that can explain the observed variation in EC(10) and EC(50) as a function of these toxicity modifying factors. All three parameters significantly altered the observed effect concentrations based on net reproductive rate. The largest differences in 21-day EC(10)s and EC(50)s caused by these factors were 10.1 and 4.9, respectively. An increase in pH and/or DOC decreased zinc toxicity. The significant interaction between pH and DOC on observed chronic Zn toxicity is in accordance with earlier reported increased sorption efficiency of Zn to humic substances at higher pH levels. Lowest Zn toxicity was observed in tests performed with moderately hard test media (between 200 and 300 mg/L as CaCO(3)). Lower or higher hardness of the test medium resulted in lower effect concentrations. Based on physico-chemical characteristics of the test media, developed models can be used to explain the variation between reported NOECs for Zn and may improve current environmental risk assessment procedures of metals.

  9. Single crystal to single crystal (SC-to-SC) transformation from a nonporous to porous metal-organic framework and its application potential in gas adsorption and Suzuki coupling reaction through postmodification.

    Science.gov (United States)

    Sen, Rupam; Saha, Debraj; Koner, Subratanath; Brandão, Paula; Lin, Zhi

    2015-04-07

    A new amino-functionalized strontium-carboxylate-based metal-organic framework (MOF) has been synthesized that undergoes single crystal to single crystal (SC-to-SC) transformation upon desolvation. Both structures have been characterized by single-crystal X-ray analysis. The desolvated structure shows an interesting 3D porous structure with pendent -NH2 groups inside the pore wall, whereas the solvated compound possesses a nonporous structure with DMF molecules on the metal centers. The amino group was postmodified through Schiff base condensation by pyridine-2-carboxaldehyde and palladium was anchored on that site. The modified framework has been utilized for the Suzuki cross-coupling reaction. The compound shows high activity towards the C-C cross-coupling reaction with good yields and turnover frequencies. Gas adsorption studies showed that the desolvated compound had permanent porosity and was microporous in nature with a BET surface area of 2052 m(2)  g(-1). The material also possesses good CO2 (8 wt %) and H2 (1.87 wt %) adsorption capabilities. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Thermodynamic hardness and the maximum hardness principle

    Science.gov (United States)

    Franco-Pérez, Marco; Gázquez, José L.; Ayers, Paul W.; Vela, Alberto

    2017-08-01

    An alternative definition of hardness (called the thermodynamic hardness) within the grand canonical ensemble formalism is proposed in terms of the partial derivative of the electronic chemical potential with respect to the thermodynamic chemical potential of the reservoir, keeping the temperature and the external potential constant. This temperature dependent definition may be interpreted as a measure of the propensity of a system to go through a charge transfer process when it interacts with other species, and thus it keeps the philosophy of the original definition. When the derivative is expressed in terms of the three-state ensemble model, in the regime of low temperatures and up to temperatures of chemical interest, one finds that for zero fractional charge, the thermodynamic hardness is proportional to T-1(I -A ) , where I is the first ionization potential, A is the electron affinity, and T is the temperature. However, the thermodynamic hardness is nearly zero when the fractional charge is different from zero. Thus, through the present definition, one avoids the presence of the Dirac delta function. We show that the chemical hardness defined in this way provides meaningful and discernible information about the hardness properties of a chemical species exhibiting integer or a fractional average number of electrons, and this analysis allowed us to establish a link between the maximum possible value of the hardness here defined, with the minimum softness principle, showing that both principles are related to minimum fractional charge and maximum stability conditions.

  11. Wear of hard materials by hard particles

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey A.

    2003-10-01

    Hard materials, such as WC-Co, boron carbide, titanium diboride and composite carbide made up of Mo2C and WC, have been tested in abrasion and erosion conditions. These hard materials showed negligible wear in abrasion against SiC particles and erosion using Al2O3 particles. The WC-Co materials have the highest wear rate of these hard materials and a very different material removal mechanism. Wear mechanisms for these materials were different for each material with the overall wear rate controlled by binder composition and content and material grain size.

  12. Photon technology. Hard photon technology; Photon technology. Hard photon gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the application of photon to industrial technologies, in particular, a hard photon technology was surveyed which uses photon beams of 0.1-200nm in wavelength. Its features such as selective atom reaction, dense inner shell excitation and spacial high resolution by quantum energy are expected to provide innovative techniques for various field such as fine machining, material synthesis and advanced inspection technology. This wavelength region has been hardly utilized for industrial fields because of poor development of suitable photon sources and optical devices. The developmental meaning, usable time and issue of a hard photon reduction lithography were surveyed as lithography in ultra-fine region below 0.1{mu}m. On hard photon analysis/evaluation technology, the industrial use of analysis, measurement and evaluation technologies by micro-beam was viewed, and optimum photon sources and optical systems were surveyed. Prediction of surface and surface layer modification by inner shell excitation, the future trend of this process and development of a vacuum ultraviolet light source were also surveyed. 383 refs., 153 figs., 17 tabs.

  13. Lattice structure transformation and change in surface hardness of Ni{sub 3}Nb and Ni{sub 3}Ta intermetallic compounds induced by energetic ion beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Kojima, H., E-mail: sv110021@edu.osakafu-u.ac.jp [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Yoshizaki, H.; Kaneno, Y. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Semboshi, S. [Materials Research Institute (Kansai Center), Tohoku University, Sakai, Osaka 599-8531 (Japan); Hori, F. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Okamoto, Y. [Quantum Beam Science Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan)

    2016-04-01

    Ni{sub 3}Nb and Ni{sub 3}Ta intermetallic compounds, which show the complicated lattice structures were irradiated with 16 MeV Au{sup 5+} ions at room temperature. The X-ray diffraction measurement revealed that the lattice structure of these intermetallic compounds changed from the ordered structures to the amorphous state by the ion irradiation. The irradiation-induced amorphization caused the increase in Vickers hardness. The result was compared with our previous results for Ni{sub 3}Al and Ni{sub 3}V, and was discussed in terms of the intrinsic lattice structures of the samples.

  14. Evaluation of the surface hardness of composite resins before and after polishing at different times Avaliação da dureza superficial de resinas compostas antes e após o polimento em diferentes tempos

    Directory of Open Access Journals (Sweden)

    Michelle Alexandra Chinelatti

    2006-06-01

    Full Text Available PURPOSE: The aim of this study was to evaluate the surface hardness of six composite resins: Revolution, Natural Flow, Fill Magic Flow, Flow-it! (flowables, Silux Plus (microfilled and Z100 (minifilled before and after polishing at different times. MATERIALS AND METHODS: For this purpose, 240 specimens (5mm diameter, 1.4mm high were prepared. Vickers hardness was determined before and after polishing at different times: immediately, 24h, 7 and 21 days after preparation of the samples. Statistical analysis was performed by ANOVA and Tukey test. RESULTS: There was no difference in the hardness of flowable resins, which had lower hardness than the minifilled resin. The minifilled resin showed the highest surface hardness as compared to the other materials (pPROPOSIÇÃO: O objetivo deste estudo foi avaliar a dureza superficial de seis resinas compostas - Revolution, Natural Flow, Fill Magic Flow, Flow-it! (flowables, Silux Plus (micropartículas e Z100 (híbrida - antes e após o polimento realizado em diferentes tempos. MATERIAL E MÉTODO: Foram confeccionados 240 corpos-de-prova circulares (5mm de diâmetro e 1,4mm de altura. A dureza Vickers foi obtida antes e após o polimento realizado em diferentes tempos: imediatamente, 24 horas, 7 dias e 21 dias após a confecção do corpo-de-prova. Os dados foram analisados estatisticamente por meio da ANOVA e do Teste de Tukey. RESULTADOS: Não houve diferença entre as resinas compostas flowable, as quais apresentaram os menores valores de dureza. A resina composta híbrida demonstrou os melhores resultados. Todos os materiais exibiram aumento de dureza após a realização do polimento, que foi mais evidente após 7 dias. CONCLUSÃO: Pôde-se concluir que, independente do tipo de resina composta, a dureza superficial foi consideravelmente maior quando o polimento foi realizado 1 semana após a confecção dos corpos-de-prova.

  15. Determination of Ro 48-3656 in rat plasma by reversed-phase high-performance liquid chromatography. Comparison of 1.5-microm nonporous silica to 3.5-microm porous silica analytical columns.

    Science.gov (United States)

    Paasch, B D; Lin, Y S; Porter, S; Modi, N B; Barder, T J

    1997-12-19

    We describe a method for measuring Ro 48-3656 in EDTA rat plasma by neutral pH, reversed-phase high-performance liquid chromatography using a 1.5-microm nonporous silica, C18 analytical column and UV absorbance detection to support pharmacokinetic studies. We also describe a comparison of the 1.5-microm nonporous silica C18 column versus 3.5-microm porous silica C18 columns. The final method using the 1.5-microm nonporous silica column demonstrated good precision (of both quantification and retention time), accuracy and recovery, linearity of dilution and limit of quantification (40 ng/ml Ro 48-3656 using a 20 microl injection). Samples of neat EDTA rat plasma were prepared by ultrafiltration followed by direct injection onto the HPLC column.

  16. The influence of silane coupling agent and poplar particles on the wet-tability, surface roughness, and hardness of UF-bonded wheat straw (Triticum aestivum L.)/poplar wood particleboard

    Institute of Scientific and Technical Information of China (English)

    Seyedeh Masoumeh Hafezi; Kazem Doosthoseini

    2014-01-01

    We used silane coupling agents to improve the bonding ability between wheat straw particles and UF resin, and investigated surface properties (wettability and surface roughness) and hardness of parti-cleboard made from UF-bonded wheat straw (Triticum aestivum L.) combined with poplar wood as affected by silane coupling agent content and straw/poplar wood particle ratios. We manufactured one-layered particleboard panels at four different ratios of straw to poplar wood par-ticles (0%, 15%, 30% and 45% wheat straw) and silane coupling agent content at three levels of 0, 5% and 10%. Roughness measurements, average roughness (Ra), mean peak-to-valley height (Rz), and root mean square roughness (Rq) were measured on unsanded samples by using a fine stylus tracing technique. We obtained contact angle measurements by using a goniometer connected to a digital camera and computer sys-tem. Boards containing greater amounts of poplar particles had superior hardness compared to control samples and had lower wettability. Panels made with higher amounts of silane had lower Rq values.

  17. Surface modification of the hard metal tungsten carbide-cobalt by boron ion implantation; Oberflaechenmodifikation des Hartmetalls Wolframkarbid-Kobalt durch Bor-Ionenimplantation

    Energy Technology Data Exchange (ETDEWEB)

    Mrotchek, I.

    2007-09-07

    In the present thesis ion beam implantation of boron is studied as method for the increasement of the hardness and for the improvement of the operational characteristics of cutting tools on the tungsten carbide-cobalt base. For the boron implantation with 40 keV energy and {approx}5.10{sup 17} ions/cm{sup 2} fluence following topics were shown: The incoerporation of boron leads to a deformation and remaining strain of the WC lattice, which possesses different stregth in the different directions of the elementary cell. The maximum of the deformation is reached at an implantation temperature of 450 C. The segregation of the new phases CoWB and Co{sub 3}W was detected at 900 C implantation temperature. At lower temperatures now new phases were found. The tribological characteristics of WC-Co are improved. Hereby the maxiaml effect was measured for implantation temperatures from 450 C to 700 C: Improvement of the microhardness by the factor 2..2.5, improvement of the wear resistance by the factor 4. The tribological effects extend to larger depths than the penetration depth of the boron implantation profile. The detected property improvements of the hard metal H3 show the possibility of a practical application of boron ion implantation in industry. The effects essential for a wer decreasement are a hardening of the carbide phase by deformation of the lattice, a hardening of the cobalt binding material and the phase boundaries because of the formation of a solid solution of the implanted boron atoms in Co and by this a blocking of the dislocation movement and the rupture spreading under load.

  18. Reconstruction of surface morphology from coherent scattering of ''white'' synchrotron radiation in hard X-ray regime

    Energy Technology Data Exchange (ETDEWEB)

    Sant, Tushar

    2009-07-01

    Energy Dispersive Reflectometry (EDR) beamline at BESSY II provides ''white'' X-rays in the useful energy range of 5surfaces. Technologically smooth wafers of semiconducting materials of Si and GaAs are used as ''trivial'' samples to determine the so called apparatus function. In addition I measured coherent reflectivity maps from thin film of highly scattering material of Pt with high atom number, Z=78 and patterned semiconducting surface like a GaAs surface grating which provides a certain periodicity in the measured scattering intensity. Finally I measured the surface speckles from a spatially confined Si wafer under the constraint that the size of the sample is smaller than the footprint of the incoming beam at the sample position. To reconstruct surface morphology from coherent reflectivity data is a typical inverse problem. Conventional phase retrieval algorithms like Gerchberg-Saxton (GS) algorithm, error reduction (ER) algorithm, hybrid input-output (HIO) algorithm are used in earlier work by other authors. I modified the conventional GS algorithm and ER algorithm which takes into account the additional Fresnel propagator term and also the illumination function at the sample position. I tested the modified algorithm successfully for a model surface in the form of a surface grating. I used the modified algorithm to reconstruct surface morphology from various static speckle measurements I performed at EDR beamline. The surface profiles reconstructed for different samples from the data at different energies (below the critical energy for the material at a particular incident angle) show almost the same roughness behavior for surface height with mean roughness of {proportional_to}1 nm. With the static speckle data I measured I could retrieve a one-dimensional picture of the sample surface with spatial

  19. Change of texture, microdeformation and hardness in surface layer of TiNi alloy depending on the number of pulses of electron beam effects

    Energy Technology Data Exchange (ETDEWEB)

    Meisner, L. L., E-mail: llm@ispms.tsc.ru; Meisner, S. N., E-mail: msn@ispms.tsc.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); National Research Tomsk State University, Tomsk, 634050 (Russian Federation); Markov, A. B., E-mail: a.markov@hq.tsc.ru; Yakovlev, E. V., E-mail: yakovev@lve.hcei.tsc.ru; Ozur, G. E., E-mail: ozur@lve.hcei.tsc.ru [Institute of High Current Electronics SB RAS, Tomsk, 634055 (Russian Federation); Rotshtein, V. P., E-mail: vrotshtein@yahoo.com [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); Tomsk State Pedagogical University, Tomsk, 634050 (Russian Federation); Mironov, Yu. P., E-mail: myp@ispms.tsc.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation)

    2015-10-27

    This work comprises a study of the influence of the pulse number of low-energy high-current electron beam (LEHCEB) exposure on the value and character of distribution of residual elastic stresses, texturing effects and the relationship between structural-phase states and physical and mechanical properties of the modified surface layers of TiNi alloy. LEHCEB processing of the surface of TiNi samples was carried out using a RITM-SP [3] installation. Energy density of electron beam was constant at E{sub s} = 3.9 ± 0.5 J/cm{sup 2}; pulse duration was 2.8 ± 0.3 μs. The number of pulses in the series was changeable, (n = 2–128). It was shown that as the result of multiple LEHCEB processing of TiNi samples, hierarchically organized multilayer structure is formed in the surface layer. The residual stress field of planar type is formed in the modified surface layer as following: in the direction of the normal to the surface the strain component ε{sub ⊥} < 0 (compressing strain), and in a direction parallel to the surface, the strain component ε{sub ||} > 0 (tensile deformation). Texturing effects and the level of residual stresses after LEHCEB processing of TiNi samples with equal energy density of electron beam (∼3.8 J/cm{sup 2}) depend on the number of pulses and increase with the rise of n > 10.

  20. The effect of time in the exposure of theobromine gel to enamel and surface hardness after demineralization with 1% citric acid

    Science.gov (United States)

    Irawan, M. I. P.; Noerdin, A.; Eriwati, Y. K.

    2017-08-01

    Theobromine is one of the alkaloid compounds that can be found in cacao (Theobroma cacao). It is said that theobromine can prevent enamel demineralization. The aim of this research was to evaluate the effect of different exposure times to 200 mg/L theobromine gel on enamel microhardness after demineralization in 1% citric acid. Twenty-eight specimens of human premolar teeth were divided into four groups and were immersed in 1% citric acid (pH 4) for 2.5 minutes. Then 200 mg/L theobromine gel was exposed to the specimens for 16 minutes (n = 7), 48 minutes (n = 7), and 96 minutes (n = 7). Enamel microhardness (KHN) values were tested using the Knoop Microhardness Tester (Shimadzu, Japan) using a 50-gram load for 5 seconds. A statistical test was performed using the Friedman test, Wilcoxon test, Kruskal-Wallis test, and Mann-Whitney test. The results showed a significant decrease, of microhardness values after demineralization with 1% citric acid. There was also a significant increase in hardness (penamel microhardness.

  1. Hardness Tester for Polyur

    Science.gov (United States)

    Hauser, D. L.; Buras, D. F.; Corbin, J. M.

    1987-01-01

    Rubber-hardness tester modified for use on rigid polyurethane foam. Provides objective basis for evaluation of improvements in foam manufacturing and inspection. Typical acceptance criterion requires minimum hardness reading of 80 on modified tester. With adequate correlation tests, modified tester used to measure indirectly tensile and compressive strengths of foam.

  2. Comprehensive hard materials

    CERN Document Server

    2014-01-01

    Comprehensive Hard Materials deals with the production, uses and properties of the carbides, nitrides and borides of these metals and those of titanium, as well as tools of ceramics, the superhard boron nitrides and diamond and related compounds. Articles include the technologies of powder production (including their precursor materials), milling, granulation, cold and hot compaction, sintering, hot isostatic pressing, hot-pressing, injection moulding, as well as on the coating technologies for refractory metals, hard metals and hard materials. The characterization, testing, quality assurance and applications are also covered. Comprehensive Hard Materials provides meaningful insights on materials at the leading edge of technology. It aids continued research and development of these materials and as such it is a critical information resource to academics and industry professionals facing the technological challenges of the future. Hard materials operate at the leading edge of technology, and continued res...

  3. Research on wheel wear volume in grinding of high hardness spherical surface%球面磨削中砂轮磨损量的理论和实验研究

    Institute of Scientific and Technical Information of China (English)

    查体建; 许黎明; 罗睿; 解斌; 时轮

    2013-01-01

    采用分块杯形砂轮磨削高硬度球面时,工件和砂轮接触面积随着砂轮的磨损而发生变化,对磨削力等参数有较大影响.基于展成法球面磨削原理研究了砂轮块的磨损过程,建立了砂轮磨损量、砂轮和工件接触面积的数学模型.实验研究了陶瓷结合剂CBN砂轮精密磨削WC-Co球面涂层材料的砂轮磨损过程,通过SEM实验分析了砂轮的磨损机理,验证了砂轮磨损量计算模型.%When high hardness sphere is ground by block structured cup wheel, the contact area between work-piece and wheel is changed as the wheel's wear, which has great influence on grinding parameters such as grinding force. The wear process was discussed on the principle of the sphere generating method. And the mathematic models were built for calculation of wheel wear volume and contact area between wheel and workpiece. Experiments of CBN wheel grinding of hardness spherical surface were studied and the results indicated the wheel wear mechanism, and verified the theory model of grinding wheel wear volume.

  4. A Novel Approach to Hardness Testing

    Science.gov (United States)

    Spiegel, F. Xavier; West, Harvey A.

    1996-01-01

    This paper gives a description of the application of a simple rebound time measuring device and relates the determination of relative hardness of a variety of common engineering metals. A relation between rebound time and hardness will be sought. The effect of geometry and surface condition will also be discussed in order to acquaint the student with the problems associated with this type of method.

  5. Synthesis of α-MoC 1-x Nanoparticles with a Surface-Modified SBA-15 Hard Template: Determination of Structure-Function Relationships in Acetic Acid Deoxygenation

    Energy Technology Data Exchange (ETDEWEB)

    Baddour, Frederick G. [National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway Golden CO 80401 USA; Nash, Connor P. [National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway Golden CO 80401 USA; Schaidle, Joshua A. [National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway Golden CO 80401 USA; Ruddy, Daniel A. [National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway Golden CO 80401 USA

    2016-06-07

    Surface modification of mesoporous SBA-15 silica generated a hydrophobic environment for a molybdenum diamine (Mo-diamine) precursor solution, enabling direct growth of isolated 1.9+/-0.4 nm α-MoC1-x nanoparticles (NPs) inside the pores of the support. The resulting NP catalysts are bifunctional, and compared to bulk α-MoC1-x and β-Mo2C, the NPs exhibit a greater acid-site:H-site ratio and a fraction of stronger acid sites. The greater acid-site:H-site ratio results in higher decarbonylation (DCO) selectivity during acetic acid hydrodeoxygenation (HDO) reactions, and the stronger acid sites lead to higher activity and ketonization (KET) selectivity at high temperatures. The hard-templating synthetic method could be a versatile route toward carbide NPs of varying size, composition, and phase, on a range of mesoporous oxide supports.

  6. Research on Causes and Precautions of White Spots and White Lines on Hard Anodized Surface%硬质阳极化表面白点白道原因及预防措施

    Institute of Scientific and Technical Information of China (English)

    马永红

    2015-01-01

    通过对铝制精密活门偶件的加工工艺方法的研究,分析了目前铝制精密活门偶件硬质阳极化表面产生白点白道缺陷的原因及预防措施,解决长期以来铝制精密活门偶件一次交检合格率低的问题,提升了精密偶件类的加工能力。%The study reported the causes and precautions of white spots and white lines defect on hard anodized surface of aluminum precision valve coupled parts by research on processing method. The problem of low rate of qualified inspection for aluminum precision valve coupled parts was resolved. The processing capacity for precision parts was improved.

  7. The Effect of Bulk Depth and Irradiation Time on the Surface Hardness and Degree of Cure of Bulk-Fill Composites

    Directory of Open Access Journals (Sweden)

    Farahat F

    2016-09-01

    Full Text Available Statement of Problem: For many years, application of the composite restoration with a thickness less than 2 mm for achieving the minimum polymerization contraction and stress has been accepted as a principle. But through the recent development in dental material a group of resin based composites (RBCs called Bulk Fill is introduced whose producers claim the possibility of achieving a good restoration in bulks with depths of 4 or even 5 mm. Objectives: To evaluate the effect of irradiation times and bulk depths on the degree of cure (DC of a bulk fill composite and compare it with the universal type. Materials and Methods: This study was conducted on two groups of dental RBCs including Tetric N Ceram Bulk Fill and Tetric N Ceram Universal. The composite samples were prepared in Teflon moulds with a diameter of 5 mm and height of 2, 4 and 6 mm. Then, half of the samples in each depth were cured from the upper side of the mould for 20s by LED light curing unit. The irradiation time for other specimens was 40s. After 24 hours of storage in distilled water, the microhardness of the top and bottom of the samples was measured using a Future Tech (Japan- Model FM 700 Vickers hardness testing machine. Data were analyzed statistically using the one and multi way ANOVAand Tukey’s test (p = 0.050. Results: The DC of Tetric N Ceram Bulk Fill in defined irradiation time and bulk depth was significantly more than the universal type (p < 0.001. Also, the DC of both composites studied was significantly (p < 0.001 reduced by increasing the bulk depths. Increasing the curing time from 20 to 40 seconds had a marginally significant effect (p ≤ 0.040 on the DC of both bulk fill and universal studied RBC samples. Conclusions: The DC of the investigated bulk fill composite was better than the universal type in all the irradiation times and bulk depths. The studied universal and bulk fill RBCs had an appropriate DC at the 2 and 4 mm bulk depths respectively and

  8. Dynamic hardness of metals

    Science.gov (United States)

    Liang, Xuecheng

    Dynamic hardness (Pd) of 22 different pure metals and alloys having a wide range of elastic modulus, static hardness, and crystal structure were measured in a gas pulse system. The indentation contact diameter with an indenting sphere and the radius (r2) of curvature of the indentation were determined by the curve fitting of the indentation profile data. r 2 measured by the profilometer was compared with that calculated from Hertz equation in both dynamic and static conditions. The results indicated that the curvature change due to elastic recovery after unloading is approximately proportional to the parameters predicted by Hertz equation. However, r 2 is less than the radius of indenting sphere in many cases which is contradictory to Hertz analysis. This discrepancy is believed due to the difference between Hertzian and actual stress distributions underneath the indentation. Factors which influence indentation elastic recovery were also discussed. It was found that Tabor dynamic hardness formula always gives a lower value than that directly from dynamic hardness definition DeltaE/V because of errors mainly from Tabor's rebound equation and the assumption that dynamic hardness at the beginning of rebound process (Pr) is equal to kinetic energy change of an impact sphere over the formed crater volume (Pd) in the derivation process for Tabor's dynamic hardness formula. Experimental results also suggested that dynamic to static hardness ratio of a material is primarily determined by its crystal structure and static hardness. The effects of strain rate and temperature rise on this ratio were discussed. A vacuum rotating arm apparatus was built to measure Pd at 70, 127, and 381 mum sphere sizes, these results exhibited that Pd is highly depended on the sphere size due to the strain rate effects. P d was also used to substitute for static hardness to correlate with abrasion and erosion resistance of metals and alloys. The particle size effects observed in erosion were

  9. Hardness testing of some fissure-sealing materials.

    Science.gov (United States)

    Ulvestad, H

    1977-11-01

    The mechanical properties of fissure-sealing materials are of significant importance for their durability, i.e. their wear resistance. One of the methods of evaluating a material's resistance to attrition is to apply a hardness test. In the present investigation, the surface hardness of some fissure-sealing materials was tested. Sealants made from diluted composite materials and with inclusion of inorganic filler particles appeared to have a considerable higher surface hardness than the other sealing materials tested.

  10. Hardness and excitation energy

    Indian Academy of Sciences (India)

    Á Nagy

    2005-09-01

    The concept of the ensemble Kohn-Sham hardness is introduced. It is shown that the first excitation energy can be given by the Kohn-Sham hardness (i.e. the energy difference of the ground-state lowest unoccupied and highest occupied levels) plus an extra term coming from the partial derivative of the ensemble exchange-correlation energy with respect to the weighting factor in the limit → 0. It is proposed that the first excitation energy can be used as a reactivity index instead of the hardness.

  11. Steady accretion of an elastic body on a hard spherical surface and the notion of a four-dimensional reference space

    Science.gov (United States)

    Tomassetti, Giuseppe; Cohen, Tal; Abeyaratne, Rohan

    2016-11-01

    Taking the cue from experiments on actin growth on spherical beads, we formulate and solve a model problem describing the accretion of an incompressible elastic solid on a rigid sphere due to attachment of diffusing free particles. One of the peculiar characteristics of this problem is that accretion takes place on the interior surface that separates the body from its support rather than on its exterior surface, and hence is responsible for stress accumulation. Simultaneously, ablation takes place at the outer surface where material is removed from the body. As the body grows, mechanical effects associated with the build-up of stress and strain energy slow down accretion and promote ablation. Eventually, the system reaches a point where internal accretion is balanced by external ablation. The present study is concerned with this stationary regime called "treadmilling". The principal ingredients of our model are: a nonstandard choice of the reference configuration, which allows us to cope with the continually evolving material structure; and a driving force and a kinetic law for accretion/ablation that involves the difference in chemical potential, strain energy and the radial stress. By combining these ingredients we arrive at an algebraic system which governs the stationary treadmilling state. We establish the conditions under which this system has a solution and we show that this solution is unique. Moreover, by an asymptotic analysis we show that for small beads the thickness of the solid is proportional to the radius of the support and is strongly affected by the stiffness of the solid, whereas for large beads the stiffness of the solid is essentially irrelevant, the thickness being proportional to a characteristic length that depends on the parameters that govern diffusion and accretion kinetics.

  12. Crack suppression of SiO2 thin film formed by 157 nm F2 laser induced photochemical surface modification of hard silicone coating film on polycarbonate(Conference Presentation)

    Science.gov (United States)

    Nojiri, Hidetoshi; Okoshi, Masayuki

    2017-03-01

    Light-weighting of vehicle is now strongly required for reducing gasoline consumption and CO2 emission. In this study, F2 laser was irradiated to the surface of hard silicone resin, coated by dip coating method onto the film of acrylic resin on a polycarbonate substrate. The surface part of the silicone resin was photo-chemically modified into SiO2. One of two types of aperture mask, 3×3 mm2 and 50×50 μm2, was set on the sample surface. The single pulse fluence was varied from 4 to 14 mJ/cm2, pulse repetition frequency was set to 10 Hz, and irradiation time was changed from 30 to 120 s. N2 gas was induced around the surface of the sample. After modification, SiO2 modified layer was etched by HF 1% diluted solution, and the etched depth was measured by a stylus-type surface profilometer. As a result of experiments, stress in the SiO2 modified layer increased by increasing of F2 laser irradiation time. In case of using aperture mask of 3×3 mm2, cracks were generated only on the irradiated area for longer irradiation time than 60 s. It is considered that the tensile stress in the modified layer exceeded the tensile fracture strength of 48 MPa of typical SiO2. When a mesh mask of 50×50 μm2 aperture was used, no crack generated even for a long irradiation of 200 s. We found, the tensile stress in SiO2 modified film can be reduced remarkably with using smaller aperture size of mesh mask, and it is very effective to prevent cracking.

  13. Hard probes 2006 Asilomar

    CERN Multimedia

    2006-01-01

    "The second international conference on hard and electromagnetic probes of high-energy nuclear collisions was held June 9 to 16, 2006 at the Asilomar Conference grounds in Pacific Grove, California" (photo and 1/2 page)

  14. Study on surface modification of YG8 hard alloy by C+V ion implantation%YG8硬质合金表面的C+V双离子注入研究

    Institute of Scientific and Technical Information of China (English)

    王世兴; 熊碧军; 李聪; 田修波; 杨士勤

    2011-01-01

    To enhance the property of YG8 hard alloy,two elements of carbon and vanadium were implanted into its surface by using Metal Vapor Vacuum Arc(MEVVA) source with several different doses.The structure of sample surface is characterized and analyzed with metallurgical microscope,X-ray diffraction and Raman spectrum,respectively.The results show that there exist new phases of C,VC,and V7O3 in the sample surface,and that C+V ion implantation actively promotes the formation of DLC structure.Moreover,it can be found that the performances of sample surface(such as microhardness,coefficient of friction and corrosion resistance) are evidently improved.In conclusion,the surface modification of YG8 hard alloy by C+V ion implantation is not only affected by the appearance of new phase,but also related to the implantation mechanism.%为了增强YG8硬质合金的性能,应用金属蒸汽真空弧离子源在其表面进行了几种不同剂量的C+V双离子注入处理.通过金相显微镜、X射线衍射以及拉曼光谱等方法,对注入试样表面进行了结构表征和分析.实验结果表明:注入后硬质合金表面有C、VC和V7O3等新相生成,且C+V双离子注入对形成类金刚石结构有积极地促进作用;此外,还发现了样品表面的硬度、摩擦系数以及防腐蚀能力等性能均得到明显的改善.分析认为,硬质合金表面的C+V双离子注入改性,不仅受到了新相生成的的影响,而且与注入本身的机制相关.

  15. Hard and Soft

    OpenAIRE

    Claes H. de Vreese; Boomgaarden, Hajo G.; Semetko, Holli A.

    2008-01-01

    Abstract Support for European integration is a function no longer only of `hard' economic and utilitarian predictors but also of `soft' predictors such as feelings of identity and attitudes towards immigrants. Focusing on the issue of the potential membership of Turkey in the European Union (EU), this study demonstrates that the importance of `soft' predictors outweighs the role of `hard' predictors in understanding public opinion about Turkish membership. The study draws on survey...

  16. Hardness amplification in nondeterministic logspace

    OpenAIRE

    Gupta, Sushmita

    2007-01-01

    A hard problem is one which cannot be easily computed by efficient algorithms. Hardness amplification is a procedure which takes as input a problem of mild hardness and returns a problem of higher hardness. This is closely related to the task of decoding certain error-correcting codes. We show amplification from mild average case hardness to higher average case hardness for nondeterministic logspace and worst-to-average amplification for nondeterministic linspace. Finally we explore possible ...

  17. Effects of light-curing modes on the polymerization shrinkage and surface hardness of composite resins%光照模式对复合树脂聚合收缩率和表面硬度的影响

    Institute of Scientific and Technical Information of China (English)

    韩冰; 董艳梅; 王晓燕; 高学军

    2011-01-01

    Objective: To investigate the effects of light-curing modes on the polymerization shrinkage and surface hardness of resins and to explore the related clinical relevance. Methods: Resins with filler content of 76% ( mass fraction) were light-cured by high intensity, low intensity and soft start curing modes for 10 s and 20 s, respectively. Specimens for detecting volumetric shrinkage and surface hardness were prepared. Volumetric shrinkage was measured with Acuvol (n =7) and surface hardness were tested with an indenter (n=5). Results: The volumetric shrinkage of composites cured by high intensity, low intensity and soft-start curing mode was: 2.95% ±0. 08%/3.06% ±0.03% (10 s/20 s), 2.98% ± 0. 12%/3.05% ±0. 13% (10 s/20 s), and 3.03% ±0.05%/3. 11% ±0.07% (10 s/20 s), respectively. No significant difference existed among polymerization shrinkage of composites cured by the three light-curing modes (P>0. 05). The hardness of composites cured by high intensity, low intensity and soft-start curing mode was; (36.82 ±4.45) Mpa/(47.58 ±3.16) Mpa (10 s/20 s), (32.30 ±1.33) Mpa/(41.60±1.83) Mpa (10 s/20 s), and (34. 56 ± 1. 38) Mpa/(44. 62 ±2. 13) Mpa (10 s/20 s) , respectively. There existed significant difference among hardness of composites cured by the three light-curing modes ( P<0. 05 ). Polymerization shrinkage was correlated with energy density ( r = -0. 363, P = 0. 018). Surface hardness was also correlated with energy density (r = -0. 890, P < 0.001 ). Conclusion:It would be better to use high intensity curing mode to improve the physical properties of restorations. In order to keep the physical properties of composites, it is necessary to prolong the curing time using soft-start/low intensity curing modes to increase the energy density.%目的:研究光固化模式对复合树脂聚合收缩率和表面硬度的影响,探讨这些因素的影响对临床工作的指导意义.方法:研究使用填料含量为76%(质量分数)的

  18. Effect of hard phases on surface quality of 6061 special-shaped radiator aluminum profile%硬质相对6061铝合金异型散热型材表面质量的影响

    Institute of Scientific and Technical Information of China (English)

    罗淞; 林高用; 曾菊花; 孙利平; 邹艳明; 周玉雄

    2011-01-01

    Contrastive analyses of two kinds of 6061 special-shaped radiator aluminum profiles produced at home and abroad were done by composition analyses, OM, SEM, mechanical tests, energy spectrum analyses and PoDFA inclusion analyses. The results show that the inclusion concentration of the domestic profile is 0.195 mm2/kg, which is obviously higher than that of the imported one (0.016 mm2/kg). There are more spinel MgAl2O4and MgO inclusions with special shapes and high hardness in the domestic profile, which can scratch the surface of molds and worsen the surface quality of profiles. With higher contents of Mg and Si, the strength of the domestic profile is slightly higher than that of the imported one. However, due to the formation of massive, hard and brittle Fe2Si2Al9 phases, its elongation is much lower than that of the imported one, and its surface quality is also affected.%采用化学成分分析、金相分析、扫描电镜、力学性能测试、能谱分析及PoDFA杂质分析等技术对国产6061铝合金异型散热型材和进口同种优质6061铝型材进行对比分析.结果表明:国产型材的杂质总含量为0.195mm2/kg,明显高于进口型材的杂质总含量(0.016 mm2/kg),且其中存在较多的MgAl2O4尖晶石和MgO硬质杂质相,这些物相具有特殊的形态和较高的硬度,在加工过程中易划伤模具表面而降低型材的表面质量;国产6061铝型材中Mg和Si元素的含量均高于进口试样的,但由于形成了较多大块状、硬而脆的Fe2Si2Al9相,导致国产型材的强度虽稍高于进口型材的,但其伸长率却大幅度下降,也影响型材的表面质量.

  19. Application of the Baxter model for hard-spheres with surface adhesion to SANS data for the U(VI) - HNO{sub 3}, TBP-n-dodecane system.

    Energy Technology Data Exchange (ETDEWEB)

    Chiarizia, R.; Nash, K. L.; Jensen, M. P.; Thiyagarajan, P.; Littrell, K. C.

    2003-11-11

    Small-angle neutron scattering (SANS) data for the tri-n-butyl phosphate (TBP)-n-dodecane, HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2} solvent extraction system have been interpreted using the Baxter model for hard spheres with surface adhesion. The increase in the scattering intensity in the low Q range observed when increasing amounts of HNO{sub 3} or UO{sub 2}(NO{sub 3}){sub 2} are transferred into the organic phase has been interpreted as arising from interactions between solute particles. The SANS data have been reproduced using a 12--16 {angstrom} diameter of the hard sphere, d{sub hs}, and a 5.6k{sub B}T-7.1k{sub B}T stickiness parameter, {tau}{sup -1}. When in contact with an aqueous phase, TBP in n-dodecane forms small reverse micelles containing three TBP molecules. Upon extraction of water, HNO{sub 3}, and UO{sub 2}(NO{sub 3}){sub 2}, the swollen micelles interact through attractive forces between their polar cores with a potential energy of about 2k{sub B}T and an effective Hamaker constant of about 4k{sub B}T. The intermicellar attraction, under suitable conditions, leads to third-phase formation. Upon phase splitting, most of the solutes in the original organic phase (water, TBP, HNO{sub 3}, and UO{sub 2}(NO{sub 3}){sub 2}) separate in a continuous phase containing interspersed layers of n-dodecane.

  20. Hardness Response Surface for U-7.5Nb-2.5Zr Alloy: A Study of Recovery/Recrystallization and Phase Transformation Interactions

    Science.gov (United States)

    Lopes, Denise Adorno; de Oliveira Zimmermann, Angelo José; Restivo, Thomaz Augusto Guisard; Padilha, Angelo Fernando

    2015-09-01

    Uranium alloys in monolithic form are an option for creating advanced nuclear fuels with very high uranium density, low isotopic enrichment, and high thermal conductivity. One aspect of the metallic fuel development is to demonstrate the retention of similar γ-phase microstructure (γs) in the fuel alloy after fabrication and during the irradiation process. Unfortunately, there are few recent systematic studies in uranium alloys. Additionally, none of them are addressing the theme of recovery/recrystallization and phase transformations interactions that compose the basic metallurgical knowledge to manufacture nuclear fuel plates. This paper discusses this theme for U-7.5Nb-2.5Zr alloy employing a multivariate statistical technique, namely response surface methodology, to analyze the effect of the following process variables: degree of deformation, temperature, and time. Based on the results, in the range studied, the authors demonstrated that at low temperatures, the interaction between the recovery phenomenon and precipitation of metastable α″ phase (isothermal martensitic shear transformation) shows a dependence with the degree of deformation, with prevalence of recovery for higher levels of this parameter. Interaction between α + γ3 phase nucleation and recrystallization is limited to a narrow temperature range [~848 K to 923 K (575 °C to 650 °C)] and during the first hour of annealing. Additionally, the series of phase transformations, γ → γs → γo → α″, produced by shear was observed to be strongly dependent on crystallographic orientations and this fact could be used to enhance the retention of the metastable γs phase.

  1. Remember Hard but Think Softly: Metaphorical Effects of Hardness/Softness on Cognitive Functions

    Directory of Open Access Journals (Sweden)

    Jiushu Xie

    2016-09-01

    Full Text Available Previous studies have found that bodily stimulation, such as hardness, biases social judgment and evaluation via metaphorical association; however, it remains unclear whether bodily stimulation also affects cognitive functions, such as memory and creativity. The current study used metaphorical associations between hard and rigid and between soft and flexible in Chinese, to investigate whether the experience of hardness affected cognitive functions requiring either rigidity (memory or flexibility (creativity. In Experiment 1, we found that Chinese-speaking participants performed better at recalling previously memorized words while sitting on a hard-surface stool (the hard condition than a cushioned one (the soft condition. In Experiment 2, participants sitting on a cushioned stool outperformed those sitting on a hard-surface stool on a Chinese riddle task, which required creative/flexible thinking, but not on an analogical reasoning task, which required both rigid and flexible thinking. The results suggest the hardness experience affects cognitive functions that are metaphorically associated with rigidity and flexibility. They support the embodiment proposition that cognitive functions and representations could be grounded via metaphorical association in bodily states.

  2. Hard and superhard nanocomposite coatings

    Energy Technology Data Exchange (ETDEWEB)

    Musil, J. [Univ. of West Bohemia, Plzen (Czech Republic). Dept. of Phys.

    2000-03-01

    This article reviews the development of hard coatings from a titanium nitride film through superlattice coatings to nanocomposite coatings. Significant attention is devoted to hard and superhard single layer nanocomposite coatings. A strong correlation between the hardness and structure of nanocomposite coatings is discussed in detail. Trends in development of hard nanocomposite coatings are also outlined. (orig.)

  3. Additional heat treatment of non-porous coatings obtained on medium carbon steel substrates by electron beam cladding of a Ti-Mo-C powder composition

    Science.gov (United States)

    Mul, D. O.; Drobyaz, E. A.; Zimoglyadova, T. A.; Bataev, V. A.; Lazurenko, D. V.; Shevtsova, L. I.

    2016-04-01

    The structure and microhardness of surface layers, obtained by non-vacuum electron beam cladding of Ti-Mo-C powder mixture on a steel substrate after different types of heat treatment, were investigated. After cladding samples were heat treated in a furnace at 200...500 °C, as well as quenched at 860 ° C and then underwent high-temperature tempering. Heat treatment of cladded coatings induced tempering of martensite and precipitation of cementite particles (Fe3C). Transmission electron microscopy of the samples after heating and holding at 300 ° C revealed precipitation of nanosized cubical TiC particles. The formation of hard nanosized particles led to the surface layer microhardness growth. The highest level of microhardness (which was 1.2...1.5-fold higher in comparison with coating microhardness after heat treatment) was achieved after heating of the claded material at 300 °C and 400 °C Additional quenching of samples at 860 °C did not increase the microhardness level.

  4. Session: Hard Rock Penetration

    Energy Technology Data Exchange (ETDEWEB)

    Tennyson, George P. Jr.; Dunn, James C.; Drumheller, Douglas S.; Glowka, David A.; Lysne, Peter

    1992-01-01

    This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of five presentations: ''Hard Rock Penetration - Summary'' by George P. Tennyson, Jr.; ''Overview - Hard Rock Penetration'' by James C. Dunn; ''An Overview of Acoustic Telemetry'' by Douglas S. Drumheller; ''Lost Circulation Technology Development Status'' by David A. Glowka; ''Downhole Memory-Logging Tools'' by Peter Lysne.

  5. Hard-hat day

    CERN Multimedia

    2003-01-01

    CERN will be organizing a special information day on Friday, 27th June, designed to promote the wearing of hard hats and ensure that they are worn correctly. A new prevention campaign will also be launched.The event will take place in the hall of the Main Building from 11.30 a.m. to 2.00 p.m., when you will be able to come and try on various models of hard hat, including some of the very latest innovative designs, ask questions and pass on any comments and suggestions.

  6. Hardness of metallic crystals

    Indian Academy of Sciences (India)

    Wuhui Li; Fengzhang Ren; Juanhua Su; Zhanhong Ma; Ke Cao; Baohong Tian

    2011-07-01

    This paper presents a new formula for calculating the hardness of metallic crystals, resulted from the research on the critical grain size with stable dislocations. The formula is = 6 /[(1 – )], where is the hardness, the coefficient, the shear modulus, the Poisson’s ratio, a function of the radius of an atom () and the electron density at the atom interface (). The formula will not only be used to testify the critical grain size with stable dislocations, but also play an important role in the understanding of mechanical properties of nanocrystalline metals.

  7. Hard exclusive QCD processes

    Energy Technology Data Exchange (ETDEWEB)

    Kugler, W.

    2007-01-15

    Hard exclusive processes in high energy electron proton scattering offer the opportunity to get access to a new generation of parton distributions, the so-called generalized parton distributions (GPDs). This functions provide more detailed informations about the structure of the nucleon than the usual PDFs obtained from DIS. In this work we present a detailed analysis of exclusive processes, especially of hard exclusive meson production. We investigated the influence of exclusive produced mesons on the semi-inclusive production of mesons at fixed target experiments like HERMES. Further we give a detailed analysis of higher order corrections (NLO) for the exclusive production of mesons in a very broad range of kinematics. (orig.)

  8. Mechanism of White Layer Formation on Machined Surface of High-speed Hard Machining%高速硬切削加工表面白层形成机理研究

    Institute of Scientific and Technical Information of China (English)

    陈涛; 刘献礼; 李素燕; 李凯; 刘涛

    2015-01-01

    白层是高速硬切削的特有现象,对加工表面完整性和零件的服役性能有着重要影响.针对高速硬切削加工表面白层问题,进行了对GCrl5淬硬轴承钢高速硬切削试验和表面白层测试,研究了不同切削条件下的白层形成机理,分析了切削速度和刀具磨损状态对白层特征的影响规律.分析结果表明,白层厚度随切削速度和后刀面磨损的增大而增大,而其分布的均匀性和连续性也将变差;切削速度和后刀面磨损的增加引起切削温度升高,导致加工表面快速淬火效应,使得白层厚度增大,其中切削速度的影响较为显著;在切削速度较低(100 m/min左右)时白层的形成机理主要为塑性变形,切削速度超过300 m/min则主要是马氏体相变所致,而在中间切削速度(200 m/min左右)时为2种机理的混合作用结果.%White layer is a unique phenomenon of high-speed hard machining and has significant effects on machined surface integrity and service performance. Focusing on the white layer in high-speed hard machining, the high-speed hard cutting experiment of hardened GCrl5 bearing steel and white layer tests are conducted. The formation mechanism of white layer under various cutting conditions is investigated, and the influence of the cutting speed and flank wear on white layer's features is studied. Analysis results show that the thickness of white layer increases with increasing cutting speed and flank wear, and the uniformity and continuity of the distribution of white layer decreases. Increasing cutting speed and flank wear will increase cutting temperature and result in rapid quenching effect of the machined surface, which causes an increasing of the thickness of white layer. The cutting speed has a more significant influence on the white layer than flank wear. The formation mechanism of white layer is plastic deformation at lower cutting speed (about 100 m/min), and is martensitic phase transformation when the

  9. CSI: Hard Drive

    Science.gov (United States)

    Sturgeon, Julie

    2008-01-01

    Acting on information from students who reported seeing a classmate looking at inappropriate material on a school computer, school officials used forensics software to plunge the depths of the PC's hard drive, searching for evidence of improper activity. Images were found in a deleted Internet Explorer cache as well as deleted file space.…

  10. Hard Probes at ATLAS

    CERN Document Server

    Citron, Z; The ATLAS collaboration

    2014-01-01

    The ATLAS collaboration has measured several hard probe observables in Pb+Pb and p+Pb collisions at the LHC. These measurements include jets which show modification in the hot dense medium of heavy ion collisions as well as color neutral electro-weak bosons. Together, they elucidate the nature of heavy ion collisions.

  11. Rock-hard coatings

    NARCIS (Netherlands)

    Muller, M.

    2007-01-01

    Aircraft jet engines have to be able to withstand infernal conditions. Extreme heat and bitter cold tax coatings to the limit. Materials expert Dr Ir. Wim Sloof fits atoms together to develop rock-hard coatings. The latest invention in this field is known as ceramic matrix composites. Sloof has sign

  12. Budgeting in Hard Times.

    Science.gov (United States)

    Parrino, Frank M.

    2003-01-01

    Interviews with school board members and administrators produced a list of suggestions for balancing a budget in hard times. Among these are changing calendars and schedules to reduce heating and cooling costs; sharing personnel; rescheduling some extracurricular activities; and forming cooperative agreements with other districts. (MLF)

  13. Hard and Soft Governance

    DEFF Research Database (Denmark)

    Moos, Lejf

    2009-01-01

    The governance and leadership at transnational, national and school level seem to be converging into a number of isomorphic forms as we see a tendency towards substituting 'hard' forms of governance, that are legally binding, with 'soft' forms based on persuasion and advice. This article analyses...

  14. Running in Hard Times

    Science.gov (United States)

    Berry, John N., III

    2009-01-01

    Roberta Stevens and Kent Oliver are campaigning hard for the presidency of the American Library Association (ALA). Stevens is outreach projects and partnerships officer at the Library of Congress. Oliver is executive director of the Stark County District Library in Canton, Ohio. They have debated, discussed, and posted web sites, Facebook pages,…

  15. Hard times; Schwere Zeiten

    Energy Technology Data Exchange (ETDEWEB)

    Grunwald, Markus

    2012-10-02

    The prices of silicon and solar wafers keep dropping. According to market research specialist IMS research, this is the result of weak traditional solar markets and global overcapacities. While many manufacturers are facing hard times, big producers of silicon are continuing to expand.

  16. Aerogels of 1D Coordination Polymers: From a Non-Porous Metal-Organic Crystal Structure to a Highly Porous Material

    Directory of Open Access Journals (Sweden)

    Adrián Angulo-Ibáñez

    2016-01-01

    Full Text Available The processing of an originally non-porous 1D coordination polymer as monolithic gel, xerogel and aerogel is reported as an alternative method to obtain novel metal-organic porous materials, conceptually different to conventional crystalline porous coordination polymer (PCPs or metal-organic frameworks (MOFs. Although the work herein reported is focused upon a particular kind of coordination polymer ([M(μ-ox(4-apy2]n, M: Co(II, Ni(II, the results are of interest in the field of porous materials and of MOFs, as the employed synthetic approach implies that any coordination polymer could be processable as a mesoporous material. The polymerization conditions were fixed to obtain stiff gels at the synthesis stage. Gels were dried at ambient pressure and at supercritical conditions to render well shaped monolithic xerogels and aerogels, respectively. The monolithic shape of the synthesis product is another remarkable result, as it does not require a post-processing or the use of additives or binders. The aerogels of the 1D coordination polymers are featured by exhibiting high pore volumes and diameters ranging in the mesoporous/macroporous regions which endow to these materials the ability to deal with large-sized molecules. The aerogel monoliths present markedly low densities (0.082–0.311 g·cm−3, an aspect of interest for applications that persecute light materials.

  17. ASTM D395 Short-Term Compression Set of Solid (Non-Porous) Siloxanes: SE 1700, Sylgard 184, and "New" M9787

    Energy Technology Data Exchange (ETDEWEB)

    Small, Ward [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Pearson, Mark A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Jensen, Wayne A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-09-13

    Compression set of solid (non-porous) Dow Corning SE 1700, Sylgard 184, and “new” M9787 siloxane elastomers was measured according to ASTM D395 Method B. Specimens of SE 1700 were made using (1) the manufacturer’s suggested cure of 150°C for 30 min and (2) an extended cure of 60°C for 6 h and 150°C for 1 h followed by a post-cure under nitrogen purge at 125°C for 12 h. Four specimens of each material were aged at 25-27% compressive strain at 70°C under nitrogen purge for 70 h. Final thickness of each specimen was measured after a 30-min cooling/relaxation period, and compression set relative to deflection was calculated. The average compression set relative to deflection was 6.0% for SE 1700 made using the extended cure and post-cure, 11.3% for SE 1700 made using the manufacturer’s suggested cure, 12.1% for Sylgard 184, and 1.9% for M9787. The extended cure and post-cure reduced the amount of compression set in SE 1700.

  18. Guidance for the Efficacy Evaluation of Products with Sporicidal Claims Against Clostridium difficile (June 2014)

    Science.gov (United States)

    This document provides an update to the Agency’s interim guidance for the efficacy evaluation of antimicrobial pesticides that are labeled for treating hard non-porous surfaces in healthcare settings contaminated with spores of Clostridium difficile.

  19. Guidance for Testing and Labeling Claims against Pandemic 2009 H1N1 Influenza A Virus (Formerly called Swine Flu )

    Science.gov (United States)

    This document provides guidance labeling and testing for antimicrobial pesticides in several forms that are used to treat hard non-porous surfaces in healthcare facilities and other settings against Pandemic 2009 H1N1 influenza A Virus.

  20. Draft PRN 2006-A: Use of Antimicrobial Pesticide Products in Heating, Ventilation, Air Conditioning and Refrigeration Systems (HVAC&R)

    Science.gov (United States)

    This draft notice provides guidance to registrants of EPA-registered antimicrobial products whose labels bear general directions related to hard, non-porous or porous surfaces, but which are not but which are not specifically registered for HVAC uses.

  1. Antimicrobial Testing Methods & Procedures: MB-32-00

    Science.gov (United States)

    Information about ATMP - SOP Quantitative Petri Plate Method (QPM) for Determining the Effectiveness of Antimicrobial Towelettes Against Spores of Clostridium difficile (ATCC 43598) on Inanimate, Hard Non-porous Surfaces - MB-32-00

  2. Antimicrobial Testing Methods & Procedures: MB-31-03

    Science.gov (United States)

    Information about ATMP - SOP Quantitative Disk Carrier Test Method (QCT-2) Modified for Testing Antimicrobial Products Against Spores of Clostridium difficile (ATCC 43598) on Inanimate, Hard, Non-porous Surfaces - MB-31-03

  3. Antimicrobial Testing Methods & Procedures: MB-26-01

    Science.gov (United States)

    Information about ATMP - SOP Neutralization of Microbicidal Activity using the OECD Quantitative Method for Evaluating Bactericidal Activity of Microbicides Used on Hard, Non-Porous Surfaces - MB-26-01

  4. Antimicrobial Testing Methods & Procedures: MB-33-00

    Science.gov (United States)

    Information about ATMP - SOP Quantitative Petri Plate Method (QPM) for Determining the Effectiveness of Antimicrobial Towelettes Against Vegetative Bacteria on Inanimate, Hard, Non-porous Surfaces - MB-33-00

  5. A New method of preparing iso-hardness plots

    Science.gov (United States)

    Kumar, V.; Patwardhan, A. K.

    1993-02-01

    A new approach has been used for the preparation of iso-hardness plots, which are very useful in the heat treating of metals and alloys. An alloy white iron containing ~6% Mn, ~5% Cr, and ~3% Cu was heat treated at 800,850,900,950,1000, and 1050 °C and soaked for 2, 4, 6, 8, and 10 h, respectively, at each of these temperatures followed by air cooling. It was observed that, although the hardness varied linearly with soaking time, its variation with soaking temperature was nonlinear. This can be represented as: H = 98.285e2021.33/T + (0.037 - 0.316 × 10- 4 T) . t where H is Vickers hardness; T is soaking temperature in K; and t is soaking time in seconds. The variation in hardness has been discussed in light of microstructural changes that can take place upon heat treating. A three-dimensional plot of hardness, soaking temperature, and time was prepared based on the above equation. It revealed that the variation in hardness on heat treating can be represented as a surface instead of lines, where the change in the slope of the surface reflects the various transformations occurring in the alloy system. This iso- hardness plot, consisting of contours of constant hardness, has been prepared by projecting the above-mentioned surface on the soaking temperature- time plane. The method of selection of heat treating parameters based on this iso- hardness plot is discussed.

  6. Pengaruh ketebalan bahan dan lamanya waktu penyinaran terhadap kekerasan permukaan resin komposit sinar (Effects of materials thickness and length of light exposure on the surface hardness light-cured composite resins

    Directory of Open Access Journals (Sweden)

    Annette Alexandra Susanto

    2006-03-01

    Full Text Available Light-cured resin composite is one of the most commonly used molding materials due to its easy-to-mold characteristic. Nevertheless, care must be taken while treating this material, especially with respect to material thickness and how long it is exposed to light. Failure to treat the material with these optimal parameters will result in undesired hardness. To determine the most favorable value of these two parameters, an experiment was done with 3 different material thicknesses, and 3 different exposure times. After the sample of the resin composite was removed from its molding, it was stored under humid condition for 24 hours. Afterwards hardness test was done on the sample using Micro Vickers Hardness tester from this experiment, the significant difference in hardness was obtained and the maximum hardness was evaluated from the resin composite sample with 2 mm thickness and 60 seconds light exposure.

  7. Controlling grass weeds on hard surfaces

    DEFF Research Database (Denmark)

    Rask, Anne Merete; Kristoffersen, Palle; Andreasen, Christian

    2012-01-01

    malezas gramíneas. El objetivo de este experimento fue optimizar el control de Poa annua y Lolium perenne, ambas especies muy difíciles de controlar sin herbicidas. La biomasa aérea de 72 plantas por tratamiento se cosechó y los pesos secos se registraron en intervalos regulares para investigar cómo las...... y también el índice de floración de las plantas de P. annua. Sin embargo, solamente murieron unas cuantas plantas. El primer tratamiento afectó la biomasa aérea más que el segundo tratamiento. Un intervalo entre tratamientos de siete días proporcionó la mayor reducción de regeneración de L. perenne...

  8. Investigation of sequential cryogenic hard turning and ball burnishing processes

    Directory of Open Access Journals (Sweden)

    K. Żak

    2014-10-01

    Full Text Available This paper presents a sequential machining process which incorporates CBN hard turning with cryogenic pre-cooling of the workpiece (CHT and ball burnishing (BB. The main goal of this study was to select machining conditions enhancing the quality of parts machined by hard turning including the surface roughness Ra of about 0,2 μm, good bearing properties and reducing the white layer. Changes of surface roughness, surface texture, microstructure alterations and micro-hardness distribution are discusses.

  9. Remember Hard But Think Softly: Metaphorical Effects of Hardness/Softness on Cognitive Functions

    Science.gov (United States)

    Xie, Jiushu; Lu, Zhi; Wang, Ruiming; Cai, Zhenguang G.

    2016-01-01

    Previous studies have found that bodily stimulation, such as hardness biases social judgment and evaluation via metaphorical association; however, it remains unclear whether bodily stimulation also affects cognitive functions, such as memory and creativity. The current study used metaphorical associations between “hard” and “rigid” and between “soft” and “flexible” in Chinese, to investigate whether the experience of hardness affects cognitive functions whose performance depends prospectively on rigidity (memory) and flexibility (creativity). In Experiment 1, we found that Chinese-speaking participants performed better at recalling previously memorized words while sitting on a hard-surface stool (the hard condition) than a cushioned one (the soft condition). In Experiment 2, participants sitting on a cushioned stool outperformed those sitting on a hard-surface stool on a Chinese riddle task, which required creative/flexible thinking, but not on an analogical reasoning task, which required both rigid and flexible thinking. The results suggest the hardness experience affects cognitive functions that are metaphorically associated with rigidity or flexibility. They support the embodiment proposition that cognitive functions and representations can be grounded in bodily states via metaphorical associations. PMID:27672373

  10. Theory of hard photoproduction

    OpenAIRE

    Klasen, Michael

    2002-01-01

    The present theoretical knowledge about photons and hard photoproduction processes, i.e. the production of jets, light and heavy hadrons, quarkonia, and prompt photons in photon-photon and photon-hadron collisions, is reviewed. Virtual and polarized photons and prompt photon production in hadron collisions are also discussed. The most important leading and next-to-leading order QCD results are compiled in analytic form. A large variety of numerical predictions is compared to data from TRISTAN...

  11. Scanning electron microscopy of hair treated in hard water.

    Science.gov (United States)

    Srinivasan, Gautham; Chakravarthy Rangachari, Srinivas

    2016-06-01

    Hardness of water is determined by the amount of calcium carbonate (CaCO3 ) and magnesium sulfate (MgSO4 ) dissolved in it. Hardness of water used for washing hair may damage the hair. The objective of this study is to observe the surface changes due to hard water usage and compare the thickness of hair between hard and soft water treated samples. Ten to 15 hair strands of length 15-20 cm, which were lost during combing, were obtained from 15 healthy female volunteers. Each hair sample was cut into two equal halves to obtain two sets per volunteer. Each hair sample was wrapped around a glass rod. One set of 15 samples was washed with hard water, and the other set was washed with distilled water for 10 minutes on alternate days and air-dried. This procedure was carried out for 30 days. The surface of hair treated in hard and soft water was examined under a scanning electron microscope. The CaCO3 and MgSO4 content of hard and distilled water samples were determined as 212.5 ppm of CaCO3 and 10 ppm of CaCO3 respectively. The mean calcium deposition in hard and distilled water treated hair was determined as 0.804% and 0.26%, respectively. The mean magnesium deposition in hard and distilled water treated hair was determined as 0.34% and 0.078%, respectively. The mean thickness of hair treated in hard water and distilled water were 72.78 and 78.14 μm, respectively. The surface of hard water treated hair has a ruffled appearance with higher mineral deposition and decreased thickness when compared with the surface of distilled water treated hair. © 2015 The International Society of Dermatology.

  12. Hard template synthesis of metal nanowires

    Directory of Open Access Journals (Sweden)

    Go eKawamura

    2014-11-01

    Full Text Available Metal nanowires (NWs have attracted much attention because of their high electron conductivity, optical transmittance and tunable magnetic properties. Metal NWs have been synthesized using soft templates such as surface stabilizing molecules and polymers, and hard templates such as anodic aluminum oxide, mesoporous oxide, carbon nanotubes. NWs prepared from hard templates are composites of metals and the oxide/carbon matrix. Thus, selecting appropriate elements can simplify the production of composite devices. The resulting NWs are immobilized and spatially arranged, as dictated by the ordered porous structure of the template. This avoids the NWs from aggregating, which is common for NWs prepared with soft templates in solution. Herein, the hard template synthesis of metal NWs is reviewed, and the resulting structures, properties and potential applications are discussed.

  13. 杯形砂轮磨削高硬度球面砂轮磨损的研究%Grinding Wheel Wear in Grinding of High Hardness Spherical Surface with Cup Wheel

    Institute of Scientific and Technical Information of China (English)

    查体建; 许黎明; 罗睿; 解斌; 时轮

    2013-01-01

    采用分块杯形砂轮磨削高硬度球面,磨削过程中砂轮磨损不仅影响砂轮磨削性能,而且造成工件和砂轮实际接触面积不断产生变化,影响磨削力和磨削质量.为此,基于展成法磨削原理研究砂轮块磨损后的形状变化,分析了分块砂轮的磨损形式,揭示了进给过程中砂轮块磨损形状的变化规律,推导了砂轮磨损量和砂轮工件接触面积的计算公式,分析了砂轮磨损速度的变化趋势及其影响因素,试验最后研究了砂轮磨损量的变化规律,并验证了砂轮磨损量的计算模型.%High hardness sphere is ground by block structured cup wheel. The wheel' s wear not only affect the grinding performance, but also change the contact area between workpiece and wheel, which have great influence on the surface quality and grinding force. The shape of the worn grinding wheel was discussed on the principle of the sphere generating method, and the wear types were also studied. The variation law of the wear shape in the grinding process was studied , and the mathematic models were built for calculation of amount of wheel wear and contact area between wheel and workpiece. The wear rate and the influential factors on the wheel wear were analyzed. At last the experimental results indicated the wear rate, and verified the theory model of grinding wheel wear.

  14. Optimisation of hardness and tensile strength of friction stir welded ...

    African Journals Online (AJOL)

    DR OKE

    Department of Mechanical Engineering, Bapatla Engineering College, Bapatla, ... surface design matrix were developed by using MINITAB14 software package. ..... search algorithm for multi-criteria optimization in hard turning of AISI D3 Steel.

  15. Friction and hardness of gold films deposited by ion plating and evaporation

    Science.gov (United States)

    Miyoshi, K.; Spalvins, T.; Buckley, D. H.

    1983-01-01

    Sliding friction experiments were conducted with ion-plated and vapor-deposited gold films on various substrates in contact with a 0.025-mm-radius spherical silicon carbide rider in mineral oil. Hardness measurements were also made to examine the hardness depth profile of the coated gold on the substrate. The results indicate that the hardness is influenced by the depth of the gold coating from the surface. The hardness increases with an increase in the depth. The hardness is also related to the composition gradient in the graded interface between the gold coating and the substrate. The graded interface exhibited the highest hardness resulting from an alloy hardening effect. The coefficient of friction is inversely related to the hardness, namely, the load carrying capacity of the surface. The greater the hardness that the metal surface possesses, the lower is the coefficient of friction. The graded interface exhibited the lowest coefficient of friction.

  16. Theory of hard photoproduction

    Energy Technology Data Exchange (ETDEWEB)

    Klasen, M. [Hamburg Univ. (Germany). 2. Inst. fuer Theoretische Physik

    2002-06-01

    The present theoretical knowledge about photons and hard photoproduction processes, i.e. the production of jets, light and heavy hadrons, quarkonia, and prompt photons in photon-photon and photon-hadron collisions, is reviewed. Virtual and polarized photons and prompt photon production in hadron collisions are also discussed. The most important leading and next-to-leading order QCD results are compiled in analytic form. A large variety of numerical predictions is compared to data from TRISTAN, LEP, and HERA and extended to future electron and muon colliders. The sources of all relevant results are collected in a rich bibliography. (orig.)

  17. Laser thermographic technologies for hard copy recording

    Science.gov (United States)

    Bessmel'tsev, Viktor P.; Baev, Sergej G.

    1995-04-01

    Methods of hard copies recording based on thermal interaction of the beam from CO2 or YAG lasers with various kinds of films on any substrates have been developed. The recording processes are single-step and require no additional development. Among them are: (1) Laser thermodestruction of thin mask layers or of a material surface on any kinds of substrates. (2) Laser thermochemical reactions of thermal decomposition of metal salts in solid state phase on a surface of various hygroscopic substrates. The laser recording devices using the methods, described above have been developed and are manufactured now; they allow one to record hard copies with a size of up to 27 X 31 inches, a resolution of 4000 dpi.

  18. Hard and Soft Governance

    DEFF Research Database (Denmark)

    Moos, Lejf

    2009-01-01

    and discusses governance forms at several levels. The first layer is the global: the methods of 'soft governance' that are being utilised by transnational agencies. The second layer is the national and local: the shift in national and local governance seen in many countries, but here demonstrated in the case......The governance and leadership at transnational, national and school level seem to be converging into a number of isomorphic forms as we see a tendency towards substituting 'hard' forms of governance, that are legally binding, with 'soft' forms based on persuasion and advice. This article analyses...... of Denmark, and finally the third layer: the leadership used in Danish schools. The use of 'soft governance' is shifting the focus of governance and leadership from decisions towards influence and power and thus shifting the focus of the processes from the decision-making itself towards more focus...

  19. Hard photoproduction at HERA

    Energy Technology Data Exchange (ETDEWEB)

    Klasen, M. [Laboratoire de Physique Subatomique et de Cosmologie, Universite Joseph Fourier / CNRS-IN2P3, 53 Avenue des Martyrs, F-38026 Grenoble (France)

    2007-07-01

    In view of possible photoproduction studies in ultra-peripheral heavy-ion collisions at the LHC, we briefly review the present theoretical understanding of photons and hard photoproduction processes at HERA, discussing the production of jets, light and heavy hadrons, quarkonia, and prompt photons. We address in particular the extraction of the strong coupling constant from photon structure function and inclusive jet measurements, the infrared safety and computing time of jet definitions, the sensitivity of di-jet cross sections on the parton densities in the photon, factorization breaking in diffractive di-jet production, the treatment of the heavy-quark mass in charm production, the relevance of the color-octet mechanism for quarkonium production, and isolation criteria for prompt photons. (author)

  20. Application of Nonporous Hollow Fiber Membrane Contactor in CO2 Removal%中空纤维致密膜基吸收法在CO2脱除中的应用

    Institute of Scientific and Technical Information of China (English)

    姜尚; 孙承贵; 贾静璇; 康国栋; 曹义鸣; 袁权

    2013-01-01

    In order to investigate the application potential of hollow fiber membrane contactors, a commercial nonporous polyimide hollow fiber membrane contactor (φ200) was tested by using tap water and seawater as absorbents to separate the CO2 from the gas mixture of CO2 and N2. The effects of liquid flow rate, liquid pressure, gas flow rate and gas pressure on the removal efficiency and overall mass transfer coefficient of CO2 were investigated. The experimental results indicate that the membrane resistance and liquid film resistance control the mass transfer when tap water and seawater are employed as absorbents. Furthermore, the removal efficiency is enhanced when the liquid/gas flow rate ratio increases. The nonporous hollow fiber contactor could perform a high CO2 removal with efficiency over 70%by optimizing the operation conditions. Finally, a stable operation process was achieved. This smooth mass transfer process indicates that the nonporous hollow fiber membrane eliminates bubbling problem and weeping problem that are frequently encountered in microporous hollow fiber contactor. Therefore, the non-porous hollow fiber contactor used in this experiment has great potential for application as a gas-liquid contactor.%  以商业φ200聚酰亚胺中空纤维致密膜大组件为接触器,淡水和海水为吸收剂,进行了CO2/N2混合气中CO2的脱除实验。考察了气液相压力和流量对CO2脱除率和过程总传质系数的影响。结果显示,液相压力对膜接触器的影响不大,而加大液/气相流量比可以提高CO2的脱除效率,通过控制操作条件可使膜接触器的CO2脱除率在70%以上。实验过程中,气液两相压力可在较宽范围内独立操作,且无鼓泡和漏液现象发生。研究表明中空纤维致密膜基接触器在CO2气体分离领域具有很好的应用潜力和前景。

  1. 2TB hard disk drive

    CERN Multimedia

    This particular object was used up until 2012 in the Data Centre. It slots into one of the Disk Server trays. Hard disks were invented in the 1950s. They started as large disks up to 20 inches in diameter holding just a few megabytes (link is external). They were originally called "fixed disks" or "Winchesters" (a code name used for a popular IBM product). They later became known as "hard disks" to distinguish them from "floppy disks (link is external)." Hard disks have a hard platter that holds the magnetic medium, as opposed to the flexible plastic film found in tapes and floppies.

  2. Experimental study of surface erosion processes of the icy moons of Jupiter

    CERN Document Server

    Galli, A; Wurz, P; Jost, B; Scheer, J A; Vorburger, A; Tulej, M; Thomas, N; Wieser, M; Barabash, S

    2015-01-01

    We use an existing laboratory facility for space hardware calibration in vacuum to study the impact of energetic ions on water ice. The experiment is intended to simulate the conditions on the surface of Jupiter's icy moons. We present first results of ion sputtering in a sample of porous ice, including the first experimental results for sulphur ion sputtering of ice. The results confirm theoretical predictions and extrapolations from previous sputtering experiments obtained at different impact angles for non-porous water ice.

  3. Hard spheres at a planar hard wall: Simulations and density functional theory

    Directory of Open Access Journals (Sweden)

    R.L. Davidchack

    2016-03-01

    Full Text Available Hard spheres are a central and important model reference system for both homogeneous and inhomogeneous fluid systems. In this paper we present new high-precision molecular-dynamics computer simulations for a hard sphere fluid at a planar hard wall. For this system we present benchmark data for the density profile ρ(z at various bulk densities, the wall surface free energy γ, the excess adsorption Γ, and the excess volume v_{ex}, which is closely related to Γ. We compare all benchmark quantities with predictions from state-of-the-art classical density functional theory calculations within the framework of fundamental measure theory. While we find overall good agreement between computer simulations and theory, significant deviations appear at sufficiently high bulk densities.

  4. Hard coal; Steinkohle

    Energy Technology Data Exchange (ETDEWEB)

    Loo, Kai van de; Sitte, Andreas-Peter [Gesamtverband Steinkohle e.V. (GVSt), Herne (Germany)

    2015-07-01

    International the coal market in 2014 was the first time in a long time in a period of stagnation. In Germany, the coal consumption decreased even significantly, mainly due to the decrease in power generation. Here the national energy transition has now been noticable affected negative for coal use. The political guidances can expect a further significant downward movement for the future. In the present phase-out process of the German hard coal industry with still three active mines there was in 2014 no decommissioning. But the next is at the end of 2015, and the plans for the time after mining have been continued. [German] International war der Markt fuer Steinkohle 2014 erstmals seit langem wieder von einer Stagnation gekennzeichnet. In Deutschland ging der Steinkohlenverbrauch sogar deutlich zurueck, vor allem wegen des Rueckgangs in der Stromerzeugung. Hier hat sich die nationale Energiewende nun spuerbar und fuer die Steinkohlennutzung negativ ausgewirkt. Die politischen Weichenstellungen lassen fuer die Zukunft eine weitere erhebliche Abwaertsbewegung erwarten. Bei dem im Auslaufprozess befindlichen deutschen Steinkohlenbergbau mit noch drei aktiven Bergwerken gab es 2014 keine Stilllegung. Doch die naechste steht zum Jahresende 2015 an, und die Planungen fuer die Zeit nach dem Bergbau sind fortgefuehrt worden.

  5. Development of method for evaluating cell hardness and correlation between bacterial spore hardness and durability

    Directory of Open Access Journals (Sweden)

    Nakanishi Koichi

    2012-06-01

    Full Text Available Abstract Background Despite the availability of conventional devices for making single-cell manipulations, determining the hardness of a single cell remains difficult. Here, we consider the cell to be a linear elastic body and apply Young’s modulus (modulus of elasticity, which is defined as the ratio of the repulsive force (stress in response to the applied strain. In this new method, a scanning probe microscope (SPM is operated with a cantilever in the “contact-and-push” mode, and the cantilever is applied to the cell surface over a set distance (applied strain. Results We determined the hardness of the following bacterial cells: Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, and five Bacillus spp. In log phase, these strains had a similar Young’s modulus, but Bacillus spp. spores were significantly harder than the corresponding vegetative cells. There was a positive, linear correlation between the hardness of bacterial spores and heat or ultraviolet (UV resistance. Conclusions Using this technique, the hardness of a single vegetative bacterial cell or spore could be determined based on Young’s modulus. As an application of this technique, we demonstrated that the hardness of individual bacterial spores was directly proportional to heat and UV resistance, which are the conventional measures of physical durability. This technique allows the rapid and direct determination of spore durability and provides a valuable and innovative method for the evaluation of physical properties in the field of microbiology.

  6. 基于效果的舰载软硬武器近卫火力分配研究%Rearch on Fire Distribution Methods Based on Operation Effect about Attacking Targets in Near Area of Surface Ship Using Shipborn Hard and Soft Weapon

    Institute of Scientific and Technical Information of China (English)

    解维河; 吴从旭; 汪德虎

    2013-01-01

    针对水面舰艇利用软硬杀伤武器抗击近区目标作战使用问题,提出基于毁伤失能和据止等作战效果的软硬武器使用火力决策方法,建立水面舰艇近卫作战软硬武器火力分配模型,通过实例建立模型,并将建立的非线性模型转化成利用匈牙利算法进行解算的指派问题进行模型解算,研究的方法和结果对水面舰艇近卫作战火力分配决策方案的制定具有一定的指导意义.%According to the operational problems about the surface ship using soft and hard weapons against nearly area target,the solution method about the use of the hard and soft weapon fire decision-making method based on the damage disability and stop fighting effect is proposed,the hard and soft weapon fire distribution model and practical use modelis established,transform the nonlinear model into the assignment problem model,and is calculated in Hungary algorithm,the research methods and results of surface ship near area defense firepower allocation decision scheme formulation has certain guiding significance.

  7. Measuring the Hardness of Minerals

    Science.gov (United States)

    Bushby, Jessica

    2005-01-01

    The author discusses Moh's hardness scale, a comparative scale for minerals, whereby the softest mineral (talc) is placed at 1 and the hardest mineral (diamond) is placed at 10, with all other minerals ordered in between, according to their hardness. Development history of the scale is outlined, as well as a description of how the scale is used…

  8. Why All the Hard Work?

    Institute of Scientific and Technical Information of China (English)

    VALERIE; SARTOR

    2011-01-01

    The stereotype of the hard working Chinese has been around for a long time in the West. As early a 1894, Arthur Smith, a missionary who spent 54 years in China, wrote book introducing the hard-working Chinese people to Americans. In his book Chinese Characteristics, Smith wrote about the dili

  9. Phase behavior of hard particles

    NARCIS (Netherlands)

    Duijneveldt, J.S. van; Lekkerkerker, H.N.W.

    1995-01-01

    The phase behavior of hard particles and mixtures thereof is reviewed. Special attention is given to a lattice model consisting of hard hexagons and points on a triangular lattice. This model appears to have two disordered phases and an ordered phase.

  10. Melting of polydisperse hard disks

    NARCIS (Netherlands)

    Pronk, S.; Frenkel, D.

    2004-01-01

    The melting of a polydisperse hard-disk system is investigated by Monte Carlo simulations in the semigrand canonical ensemble. This is done in the context of possible continuous melting by a dislocation-unbinding mechanism, as an extension of the two-dimensional hard-disk melting problem. We find

  11. Melting of polydisperse hard disks

    NARCIS (Netherlands)

    Pronk, S.; Frenkel, D.

    2004-01-01

    The melting of a polydisperse hard-disk system is investigated by Monte Carlo simulations in the semigrand canonical ensemble. This is done in the context of possible continuous melting by a dislocation-unbinding mechanism, as an extension of the two-dimensional hard-disk melting problem. We find th

  12. Cutting capacity of PDC cutters in very hard rock

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    An experimental programm of investigating the cutting capacity of PDC flat cutters in very hard rock has been performed.Experiments include both the cutting of PDC fixed at different angles on the granite core or bar and linear cutting with different static thrust on the block of granite.The effects of the rough degree of rock surface,cutting angles,and static thrust on the cutting capacity of PDC in very hard rock were investigated and analyzed.The results show that the single mode of rotary drilling using PDC cutters is not applied for very hard rocks.

  13. Microstructure and hardness of bovine enamel in roselle extract solution

    Science.gov (United States)

    Dame, M. T.; Noerdin, A.; Indrani, D. J.

    2017-08-01

    The aim of this study was to analyze the effect of roselle extract solution on the microstructure and hardness of bovine enamel. Ten bovine teeth and a 5% concentration of roselle extract solution were prepared. Immersions of each bovine tooth in roselle extract solution were conducted up to 60 minutes. The bovine enamel surface was characterized in hardness and microscopy. It was apparent that the initial hardness was 328 KHN, and after immersion in 15 and 60 min, the values decrease to 57.4 KHN and 11 KHN, respectively. Scanning electron microscopy (SEM) revealed changes in enamel rods after immersion in the roselle extract solution.

  14. ÇEŞİTLİ POSTERİOR KOMPOZİT DOLGULARIN YÜZEY SERTLİKLERİNİN İNCELENMESİ-THE INVESTİGATİON OF THE SURFACE HARDNESS OF VARİOUS POSTERİOR COMPOSİTES

    OpenAIRE

    YÜCEL, Taner; Akıncı, Tevfik; BATUR, Feyzi; Gümüş, Hatice

    2013-01-01

    Anahtar sözcükler : Yüzey sertliği. Posterior Kompozit.Bu araştırmada 2 farklı sistemli (kimyasal ve görünen ışık) sertleşen 4 adet posterior komposit dolgu materyali yüzey sertlikleri ve ışınlanma uniformluğu açısından incelenmiştir. Yüzey sertlik değerlerinin zamana bağlı olarak arttıkları ve ışınlama süresi ile ışın mesafesinin polimerizasyonu etkilediği ortaya konmuştur.Key words : Micro hardness, Posterior composites.The surface hardness of visible light cured and two chemically polimeri...

  15. Hard and soft walls

    CERN Document Server

    Milton, Kimball A

    2011-01-01

    In a continuing effort to understand divergences which occur when quantum fields are confined by bounding surfaces, we investigate local energy densities (and the local energy-momentum tensor) in the vicinity of a wall. In this paper, attention is largely confined to a scalar field. If the wall is an infinite Dirichlet plane, well known volume and surface divergences are found, which are regulated by a temporal point-splitting parameter. If the wall is represented by a linear potential in one coordinate $z$, the divergences are softened. The case of a general wall, described by a potential of the form $z^\\alpha$ for $z>0$ is considered. If $\\alpha>2$, there are no surface divergences, which in any case vanish if the conformal stress tensor is employed. Divergences within the wall are also considered.

  16. Hardness Awareness Seminar

    Science.gov (United States)

    1978-06-01

    coating . c. Designing the exposed surface with extra material which can burn-off without degrading the system performance. d. Placing special thermal...curtains or shields in the cockpit. These are to prevent injury to the crew and to prevent cockpit fires. e. Wearing of special photochromic lenses

  17. Photon technology. Hard photon technology; Photon technology. Hard photon gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Research results of hard photon technology have been summarized as a part of novel technology development highly utilizing the quantum nature of photon. Hard photon technology refers to photon beam technologies which use photon in the 0.1 to 200 nm wavelength region. Hard photon has not been used in industry due to the lack of suitable photon sources and optical devices. However, hard photon in this wavelength region is expected to bring about innovations in such areas as ultrafine processing and material synthesis due to its atom selective reaction, inner shell excitation reaction, and spatially high resolution. Then, technological themes and possibility have been surveyed. Although there are principle proposes and their verification of individual technologies for the technologies of hard photon generation, regulation and utilization, they are still far from the practical applications. For the photon source technology, the laser diode pumped driver laser technology, laser plasma photon source technology, synchrotron radiation photon source technology, and vacuum ultraviolet photon source technology are presented. For the optical device technology, the multi-layer film technology for beam mirrors and the non-spherical lens processing technology are introduced. Also are described the reduction lithography technology, hard photon excitation process, and methods of analysis and measurement. 430 refs., 165 figs., 23 tabs.

  18. Unified approach to hard diffraction

    CERN Document Server

    Peschanski, R

    2001-01-01

    Using a combination of S-Matrix and perturbative QCD properties in the small x_{Bj} regime, we propose a formulation of hard diffraction unifying the partonic (Ingelman-Schlein) Pomeron, Soft Colour Interaction and QCD dipole descriptions.

  19. STUDY ON COMPOSITION, MICROSTRUCTURE AND HARDNESS OF DLC FILMS BY VCAD

    Institute of Scientific and Technical Information of China (English)

    L. Chen; Z.Y. Liu; D.C. Zeng; W.Q. Qiu; Z.H. Yuan; S.S. Lin; H.J. Hou

    2003-01-01

    DLC super-hard films have been deposited on the substrates of single crystalline Si, pure Ti and stainless steel 18-8 by a method of vacuum cathode arc deposition(VCAD). The composition, microstructure and micro-hardness of the films have been studied in this paper. The results indicate that hardness of the DLC films is different on the different substrates. Hardness of the films increases with decreasing in surface roughness of the films. The maximum value of micro-hardness belongs to the DLC films deposited under the hydrogen pressure of 0.35Pa and the negative bias of 100V.

  20. Analysis on Dynamic Response of Hard-Soft-Hard Sandwich Panel Under Blast Loading

    Institute of Scientific and Technical Information of China (English)

    DONG Yongxiang; FENG Shunshan; JIN Jun

    2006-01-01

    Surface contact explosion experiments have been performed for the study of dynamic response of the hard-soft-hard sandwich panel under blast loading.Experimental results have shown that there are four damage modes,including explosion cratering,scabbing of the backside,radial cracking induced failure and circumferential cracking induced failure.It also illustrates that the foam material sandwiched in the multi-layered media has an important effect on damage patterns.The phenomena encountered have been analyzed by the calculation with ALE method.Meanwhile,the optimal analysis of foam material thickness and position in the sandwich panel were performed in terms of experimental and numerical analysis.The proper thickness proportion of the soft layer is about 20% to the thickness of sandwich panel and the thickness of the upper hard layer and lower hard layer is in the ratio of 7 to 3 under the condition in this paper when the total thickness of soft layer remains constant.

  1. Method and apparatus for separating hydrogen from gas mixtures by diffusion through a nonporous wall. Verfahren und Vorrichtung zur Abtrennung von Wasserstoff aus Gasgemischen durch Diffusion durch eine nichtporoese Wand

    Energy Technology Data Exchange (ETDEWEB)

    Behr, F.; Weirich, W.; Schulten, R.

    1983-06-23

    A Cu-saturated alloy containing 10-30% Ti, 3-10% V, 25 wt% Nb, and >30% Ta is used as a nonporous membrane for the separation of H from gas mixtures in nuclear reactors by selective diffusion. The primary side of the alloy contacting the gas mixture is coated with a Pd/Cu or Pd/Ag alloy, whereas the secondary side contacts a Na-K, Li, or Ba-Mg-Ca melt, the affinity of which to H is higher than that of the Ta-base alloy and the Pd-Cu or Pd-Ag coating. The alkali or alkaline-earth metal melt increases the diffusion rate of H through the membrane and prevents the formation of brittle hydrides in the membrane.

  2. NANOCOMPOSITE COATINGS WITH ENHANCED HARDNESS

    Institute of Scientific and Technical Information of China (English)

    J. Musil

    2005-01-01

    The article reviews the present state of the art in the magnetron sputtering of hart and superhard nanocomposite coatings. It is shown that there are (1) two groups of hard and superhard nanocomposites: (i) nc-MN/hard phase and (ii) nc-MN/soft phase, (2) three possible origins of the enhanced hardness: (i) dislocation-dominated plastic deformation, (ii) cohesive forces between atoms and (iii) nanostructure of materials, and (3) huge differences in the microstructure of single- and two-phase films. A main attention is devoted to the formation of nanocrystalline and/or X-ray amorphous films. Such films are created in a vicinity of transitions between (i)crystalline and amorphous phases, (ii) two crystalline phases of different chemical composition or (iii) two different preferred orientations of grains of the sane material from which the coating is composed. The existence of the last transition makes it possible to explain the enhanced hardness in single-phase films. The thermal stability and oxidation resistance of hard nanocomposite films is also shortly discussed.

  3. Turning conditions of Ck 45 steel with alternate hardness zones

    Directory of Open Access Journals (Sweden)

    A. Stoić

    2009-05-01

    Full Text Available Purpose: of this paper is investigation of dynamic impacts on cutting edge during machining of locally hardened steel. Alteration of hardness on a single work piece is a source of impact on tool, which could lead to breakage of cutting tool and work piece surface damage in turning. Influence of material properties (primary hardness is important when work piece is hardened locally by induction and part of material is soft annealed.Design/methodology/approach: Experimental tests of cutting outputs have been done on specimens after induction hardening to evaluate the rate of variation of cutting forces, surface roughness and chip formation because of hardness alteration. Measured data of main cutting force were analyzed in frequency and time domain.Findings: It was found that chip formation condition, chip thickness and chip shape depends on cutting forces alteration in transition areas in the range of 10 to 15%. Much higher alteration of force signal is recorded when machining is performed with low depth of cutting value as a result of backlash in system. The most important value of cutting force correlates with depth of cutting, and roughness correlates oppositely to the hardness.Research limitations/implications: Results and findings presented in this paper are qualitative and might be slightly different in other cutting condition (e.g. other heat treatable steels or other hardening techniques or other single cutting point processes. There is evident force value alteration in the transition (hard to soft state zone.Practical implications: Surface roughness is a consequence of both cutting impacts and of tool/work piece loading condition.Originality/value: Originality of the paper is in analysis for stability of turning to heat treatable steel influenced with alternating work piece hardness. It was recorded edge loading shock overcome from hard to soft machining. It was recorded and analyzed self-exited vibration. A new type of chips: horseshoe

  4. Generalized Soft-and-Hard/DB Boundary

    CERN Document Server

    Lindell, Ismo V

    2016-01-01

    A novel class of boundary conditions is introduced as a generalization of the previously defined class of soft-and-hard/DB (SHDB) boundary conditions. It is shown that the conditions for the generalized soft-and-hard/DB (GSHDB) boundary arise most naturally in a simple and straightforward manner by applying four-dimensional differential-form and dyadic formalism. At a given boundary surface, the GSHDB conditions are governed by two one-forms. In terms of Gibbsian 3D vector and dyadic algebra the GSHDB conditions are defined in terms of two vectors tangential to the boundary surface and two scalars. Considering plane-wave reflection from the GSHDB boundary, for two eigenpolarizations, the GSHDB boundary can be replaced by the PEC or PMC boundary. Special attention is paid to the problem of plane waves matched to the GSHDB boundary, defined by a 2D dispersion equation for the wave vector, making the reflection dyadic indeterminate. Examples of dispersion curves for various chosen parameters of the GSHDB boundar...

  5. Hard Diffraction at D{phi}

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Gilvan A. [Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil). Lab. de Cosmologia e Fisica Experimental de Altas Energias

    2000-07-01

    Full text follows: We review recent Hard Diffraction results from the D{phi} experiment at Fermilab, for the following processes: hard color singlet exchange, hard single diffraction, and hard double pomeron exchange. Measurements of rates, {eta}, E{sub T} and {radical}S dependencies are presented and comparisons made with predictions of several models. (author)

  6. Carbide Type Influence on Tribological Properties of Hard Faced Steel Layer Part II- Experimental Results

    Directory of Open Access Journals (Sweden)

    V. Lazic

    2010-09-01

    Full Text Available In this paper is presented a preceding procedure that should be conducted in order to successfully regenerate damaged forging dies by the hard facing process. After the tool damage types identification, as well as their causes, we have chosen the procedure and the parameters of hard facing that we further corrected by conducting the test hard facings on models. Thus, we were able to relate the experimental results outputs with the repair technology, taking as a criterion the quality of the surface layers wear resistance such as friction coefficient and width of hard faced zone, hardness and its distribution in cross section, then microstructure of characteristic of hard faced zones, etc. This research points out significancy of tribological properties of certain types of carbides and their effects on metal matrix, in which carbides are embedded. Our tribological investigations have shown that the working life of the hard faced tool can be longer than that of the new tool.

  7. Hard Diffraction in Pythia 8

    CERN Document Server

    Rasmussen, Christine O

    2015-01-01

    We present an overview of the options for diffraction implemented in the general--purpose event generator Pythia 8. We review the existing model for low-- and high--mass soft diffraction and present a new model for hard diffraction in pp and ppbar collisions. Both models uses the Pomeron approach pioneered by Ingelman and Schlein, factorising the single diffractive cross section into a Pomeron flux and a Pomeron PDF. The model for hard diffraction is implemented as a part of the multiparton interactions framework, thereby introducing a dynamical rapidity gap survival probability that explicitly breaks factorisation.

  8. Hard Diffraction in Pythia 8

    CERN Document Server

    Rasmussen, Christine O

    2015-01-01

    We present an overview of the options for diffraction implemented in the general-purpose event generator Pythia 8. We review the existing model for soft diffraction and present a new model for hard diffraction. Both models use the Pomeron approach pioneered by Ingelman and Schlein, factorising the diffractive cross section into a Pomeron flux and a Pomeron PDF, with several choices for both implemented in Pythia 8. The model of hard diffraction is implemented as a part of the multiparton interactions (MPI) framework, thus introducing a dynamical gap survival probability that explicitly breaks factorisation.

  9. Hard diffraction in Pythia 8

    Science.gov (United States)

    Overgaard Rasmussen, Christine

    2016-07-01

    We present an overview of the options for diffraction implemented in the general-purpose event generator Pythia 8 [1]. We review the existing model for soft diffraction and present a new model for hard diffraction. Both models use the Pomeron approach pioneered by Ingelman and Schlein, factorising the diffractive cross section into a Pomeron flux and a Pomeron PDF, with several choices for both implemented in Pythia 8. The model of hard diffraction is implemented as a part of the multiparton interactions (MPI) framework, thus introducing a dynamical gap survival probability that explicitly breaks factorisation.

  10. Rolling Contact Fatigue Life Prediction on Bearing Steel Pre-residual Stress Surfaces Induced by Hard Turning%轴承钢硬切削表面残余应力对滚动接触界面疲劳寿命的影响

    Institute of Scientific and Technical Information of China (English)

    李振; 张相琴; 张雪萍; LIU C Richard

    2011-01-01

    为了预测轴承钢硬切削表面残余应力对滚动接触寿命的影响规律,基于高级非线性有限元分析软件MARC,建立了具有平面应变特征的二维滚动接触寿命预测模型,并在二维有限元模型的表面和次表面对应施加了轴承钢硬切削实验所测残余应力,模拟计算典型服役条件下的滚动接触应力;采用基于S-N寿命理论的Miner法则,计算轴承钢滚动界面的疲劳接触寿命,分析了在不同摩擦系数、滚动接触频率和外加载荷工况下,硬切削残余压应力对疲劳寿命的影响.结果表明,硬切削残余压应力可使轴承钢的滚动接触疲劳寿命提高10%~30%.其中,载荷对滚动接触疲劳寿命影响最大,摩擦系数的影响最小.%To predict the effect of the hard turning-induced residual stress on the rolling fatigue life of bearing steel, 2D rolling contact fatigue life model characteristic with plane strain was developed based on MARC. The residual stress on the machined surface and subsurface from the hard turning bearing steel was applied to surface and subsurface of 2D model correspondingly. The rolling contact stress distribution was simulated under the typical services, and the rolling fatigue life of contact interface was predicted by Miner law based on the S-N life theory under compressive stress. After the analysis of rolling fatigue life under different conditions, the effect of different friction, rolling velocity, load on fatigue life with hard turning-induced residual stress was quantitatively investigated. The investigation shows that the hard turning-induced compressive residual stress increases 10%-30% the rolling fatigue life of bearing steel, and the load has the greatest effect on rolling fatigue life while the fiction coefficient has the minimal effect.

  11. Conjugation of diisocyanate side chains to dimethacrylate reduces polymerization shrinkage and increases the hardness of composite resins

    Directory of Open Access Journals (Sweden)

    Yih-Dean Jan

    2014-04-01

    Conclusion: Conjugation of diisocyanate side chains to dimethacrylate represents an effective means of reducing polymerization shrinkage and increasing the surface hardness of dental composite resins.

  12. Hard Trying and These Recipes

    Science.gov (United States)

    Atwell, Nancie

    2003-01-01

    Writers thrive when they are motivated to work hard, have regular opportunities to practice and reflect, and benefit from a knowledgeable teacher who knows writing. Student feedback to lessons during writing workshop helped guide Nancie Atwell in her quest to provide the richest and most efficient path to better writing.

  13. Kinetic theory of hard spheres

    NARCIS (Netherlands)

    Beijeren, H. van; Ernst, M.H.

    1979-01-01

    Kinetic equations for the hard-sphere system are derived by diagrammatic techniques. A linear equation is obtained for the one-particle-one particle equilibrium time correlation function and a nonlinear equation for the one-particle distribution function in nonequilibrium. Both equations are nonloca

  14. Metrics for Hard Goods Merchandising.

    Science.gov (United States)

    Cooper, Gloria S., Ed.; Magisos, Joel H., Ed.

    Designed to meet the job-related metric measurement needs of students interested in hard goods merchandising, this instructional package is one of five for the marketing and distribution cluster, part of a set of 55 packages for metric instruction in different occupations. The package is intended for students who already know the occupational…

  15. Inclusive Hard Diffraction at HERA

    CERN Document Server

    Proskuryakov, Alexander

    2010-01-01

    Recent data from the H1 and ZEUS experiments on hard inclusive diffraction are discussed. Results of QCD analyses of the diffractive deep-inelastic scattering processes are reported. Predictions based on the extracted parton densities are compared to diffractive dijet measurements.

  16. Hard sphere packings within cylinders.

    Science.gov (United States)

    Fu, Lin; Steinhardt, William; Zhao, Hao; Socolar, Joshua E S; Charbonneau, Patrick

    2016-03-07

    Arrangements of identical hard spheres confined to a cylinder with hard walls have been used to model experimental systems, such as fullerenes in nanotubes and colloidal wire assembly. Finding the densest configurations, called close packings, of hard spheres of diameter σ in a cylinder of diameter D is a purely geometric problem that grows increasingly complex as D/σ increases, and little is thus known about the regime for D > 2.873σ. In this work, we extend the identification of close packings up to D = 4.00σ by adapting Torquato-Jiao's adaptive-shrinking-cell formulation and sequential-linear-programming (SLP) technique. We identify 17 new structures, almost all of them chiral. Beyond D ≈ 2.85σ, most of the structures consist of an outer shell and an inner core that compete for being close packed. In some cases, the shell adopts its own maximum density configuration, and the stacking of core spheres within it is quasiperiodic. In other cases, an interplay between the two components is observed, which may result in simple periodic structures. In yet other cases, the very distinction between the core and shell vanishes, resulting in more exotic packing geometries, including some that are three-dimensional extensions of structures obtained from packing hard disks in a circle.

  17. Stress in hard metal films

    NARCIS (Netherlands)

    Janssen, G.C.A.M.; Kamminga, J.D.

    2004-01-01

    In the absence of thermal stress, tensile stress in hard metal films is caused by grain boundary shrinkage and compressive stress is caused by ion peening. It is shown that the two contributions are additive. Moreover tensile stress generated at the grain boundaries does not relax by ion bombardment

  18. Unifying approach to hard diffraction

    CERN Document Server

    Navelet, H

    2001-01-01

    We find a formulation of hard diffraction unifying the partonic (Ingelman-Schlein) Pomeron, Soft Colour Interaction and QCD dipole descriptions. A theoretical interpretation in terms of S-Matrix and perturbative QCD properties in the small x_{Bj} regime is proposed.

  19. Verrucous Carcinoma of Hard Plate

    OpenAIRE

    Parmod Kalstra,Monica Manhas,Rajdeep Sood

    2000-01-01

    VerrucouS squamous cell carcinoma occurs mainly in oral cavity and larynx, buccal mucosa being most commonly involved. One case of verrucous carcinoma involvmg left hard palate (T4 No Mo)in an adult male is being reported who underwent left total maxillectomy. The tumor behaviour andlts management has been dlscussed.

  20. Hard processes in hadronic interactions

    Energy Technology Data Exchange (ETDEWEB)

    Satz, H. [CERN, Geneva (Switzerland)]|[Universitat Bielefeld (Germany); Wang, X.N. [Lawrence Berkeley Lab., CA (United States)

    1995-07-01

    Quantum chromodynamics is today accepted as the fundamental theory of strong interactions, even though most hadronic collisions lead to final states for which quantitative QCD predictions are still lacking. It therefore seems worthwhile to take stock of where we stand today and to what extent the presently available data on hard processes in hadronic collisions can be accounted for in terms of QCD. This is one reason for this work. The second reason - and in fact its original trigger - is the search for the quark-gluon plasma in high energy nuclear collisions. The hard processes to be considered here are the production of prompt photons, Drell-Yan dileptons, open charm, quarkonium states, and hard jets. For each of these, we discuss the present theoretical understanding, compare the resulting predictions to available data, and then show what behaviour it leads to at RHIC and LHC energies. All of these processes have the structure mentioned above: they contain a hard partonic interaction, calculable perturbatively, but also the non-perturbative parton distribution within a hadron. These parton distributions, however, can be studied theoretically in terms of counting rule arguments, and they can be checked independently by measurements of the parton structure functions in deep inelastic lepton-hadron scattering. The present volume is the work of Hard Probe Collaboration, a group of theorists who are interested in the problem and were willing to dedicate a considerable amount of their time and work on it. The necessary preparation, planning and coordination of the project were carried out in two workshops of two weeks` duration each, in February 1994 at CERn in Geneva andin July 1994 at LBL in Berkeley.

  1. Nanostructural Evolution of Hard Turning Layers in Carburized Steel

    Science.gov (United States)

    Bedekar, Vikram

    The mechanisms of failure for components subjected to contact fatigue are sensitive to the structure and properties of the material surface. Although, the bulk material properties are determined by the steel making, forming and the heat treatment; the near surface material properties are altered during final material removal processes such as hard turning or grinding. Therefore, the ability to optimize, modulate and predict the near surface properties during final metal removal operations would be extremely useful in the enhancement of service life of a component. Hard machining is known to induce severely deformed layers causing dramatic microstructural transformations. These transformations occur via grain refinement or thermal phenomena depending upon cutting conditions. The aim of this work is to engineer the near surface nanoscale structure and properties during hard turning by altering strain, strain rate, temperature and incoming microstructure. The near surface material transformations due to hard turning were studied on carburized SAE 8620 bearing steel. Variations in parent material microstructures were introduced by altering the retained austenite content. The strain, strain rate and temperature achieved during final metal cutting were altered by varying insert geometry, insert wear and cutting speed. The subsurface evolution was quantified by a series of advanced characterization techniques such as transmission electron microscopy (TEM), glancing angle X-ray diffraction (GAXRD), X-ray stress evaluation and nanoindentation which were coupled with numerical modeling. Results showed that the grain size of the nanocrystalline near surface microstructure can be effectively controlled by altering the insert geometry, insert wear, cutting speed and the incoming microstructure. It was also evident that the near surface retained austenite decreased at lower cutting speed indicating transformation due to plastic deformation, while it increased at higher cutting

  2. Hardness Measurement of (TiB2-TiAl)/TiAl Symmetrically Function Gradient Materials

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    (TiB2-TiAl)/TiAl symmetrically function gradient materials (FGM) were prepared by spark plasma sintering (SPS). Owing to the difference of the thermal expansion coefficients between TiB2 and TiAl, a compressive surface stress was introduced to the FGM by the thermal expansion mismatch. The hardness values of the uniform materials and the FGM were tested, respectively. For the FGM with a compressive surface stress, hardness is obviously superior to that of the uniform material.When the FGM was subjected to heat treatment,the hardness decreased due to a partial relaxation of the compressive surface stress.

  3. Recent Advances in Hard, Tough, and Low Friction Nanocomposite Coatings

    Institute of Scientific and Technical Information of China (English)

    A.A.Voevodin; J. S. Zabinski; C.Muratore

    2005-01-01

    Nanocomposite coatings demonstrate improved friction and wear responses under severe sliding conditions in extreme environments. This paper provides a review how thin film multilayers and nanocomposites result in hard, tough, low-friction coatings. Approaches to couple multilayered and nanocomposite materials with other surface engineering strategies to achieve higher levels of performance in a variety of tribological applications are also discussed. Encapsulating lubricious phases in hard nanocomposite matrices is one approach that is discussed in detail. Results from state-of-the-art "chameleon" nanocomposites that exhibit reversible adaptability to ambient humidity or temperature are presented.

  4. Effect of coatings on hardness of commercial marbles

    Science.gov (United States)

    Zedef, Veysel

    2016-04-01

    In this study, three type of marble and one granite were chosen to understand if the coating is effective on hardness of the commercial rocks. To understand the hardness of the rock, Schmidt hammer tests were undertaken. The used device allowed us uniaxial compressive strength (UCS) as well as Schmidt rebound (R). The coated samples have clearly high R and UCS values when compared to uncoated samples. The Elazig visne, the well-known marble of Turkey, have 35.6 R and 44.2 MPa UCS values of coated samples. On the other hand, uncoated surface of the same marble have 30.5 R and 35.4 MPa UCS.

  5. The influence of third-order interactions on the density profile of associating hard spheres

    Science.gov (United States)

    Henderson, D.; Sokolowski, S.; Zagorski, R.; Trokhymchuk, A.

    Canonical ensemble Monte Carlo simulations and the non-uniform Percus-Yevick (NPY) equation for the local density are used to study the influence of surface mediated thirdorder interactions on the adsorption of associating hard spheres on a hard wall. A comparison of the NPY density profiles with the computer simulations data indicates that this approximation predicts the fluid structure reasonably well.

  6. Molecular hardness and softness, local hardness and softness, hardness and softness kernels, and relations among these quantities

    Science.gov (United States)

    Berkowitz, Max; Parr, Robert G.

    1988-02-01

    Hardness and softness kernels η(r,r') and s(r,r') are defined for the ground state of an atomic or molecular electronic system, and the previously defined local hardness and softness η(r) and s(r) and global hardness and softness η and S are obtained from them. The physical meaning of s(r), as a charge capacitance, is discussed (following Huheey and Politzer), and two alternative ``hardness'' indices are identified and briefly discussed.

  7. Development of Radiation Hard Scintillators

    CERN Document Server

    Tiras, Emrah; Bilki, Burak; Winn, David; Onel, Yasar

    2016-01-01

    Modern high-energy physics experiments are in ever increasing need for radiation hard scintillators and detectors. In this regard, we have studied various radiation-hard scintillating materials such as Polyethylene Naphthalate (PEN), Polyethylene Terephthalate (PET), our prototype material Scintillator X (SX) and Eljen (EJ). Scintillation and transmission properties of these scintillators are studied using stimulated emission from a 334 nm wavelength UV laser with PMT before and after certain amount of radiation exposure. Recovery from radiation damage is studied over time. While the primary goal of this study is geared for LHC detector upgrades, these new technologies could easily be used for future experiments such as the FCC and ILC. Here we discuss the physics motivation, recent developments and laboratory measurements of these materials.

  8. Schwannoma of the hard palate

    OpenAIRE

    2009-01-01

    Schwannomas are benign encapsulated perineural tumors. The head and neck region is the most common site. Intraoral origin is seen in only 1% of cases, tongue being the most common site; its location in the palate is rare. We report a case of hard-palate schwannoma with bony erosion which was immunohistochemically confirmed. The tumor was excised completely intraorally. After two months of follow-up, the defect was found to be completely covered with palatal mucosa.

  9. Playing Moderately Hard to Get

    Directory of Open Access Journals (Sweden)

    Stephen Reysen

    2013-12-01

    Full Text Available In two studies, we examined the effect of different degrees of attraction reciprocation on ratings of attraction toward a potential romantic partner. Undergraduate college student participants imagined a potential romantic partner who reciprocated a low (reciprocating attraction one day a week, moderate (reciprocating attraction three days a week, high (reciprocating attraction five days a week, or unspecified degree of attraction (no mention of reciprocation. Participants then rated their degree of attraction toward the potential partner. The results of Study 1 provided only partial support for Brehm’s emotion intensity theory. However, after revising the high reciprocation condition vignette in Study 2, supporting Brehm’s emotion intensity theory, results show that a potential partners’ display of reciprocation of attraction acted as a deterrent to participants’ intensity of experienced attraction to the potential partner. The results support the notion that playing moderately hard to get elicits more intense feelings of attraction from potential suitors than playing too easy or too hard to get. Discussion of previous research examining playing hard to get is also re-examined through an emotion intensity theory theoretical lens.

  10. Experimental Study on the Relationship between Hardness and Principal Strain in Tube Hydroforming Process

    Science.gov (United States)

    Wang, G. D.; Chan, L. C.

    2009-11-01

    In order to find a feasible method to evaluate the deformation of tubes during the Tube Hydroforming (THF) process, the hardness and the strain in two selected deformation areas of hydro formed copper tubes (C11000) were measured and tested, and an instinct relationship was found between the hardness and the principal strains of the tubes. The major strain of the surface of tubes had the strongest linear relationship with hardness. A regression formula was used to describe the relationship between hardness and the sensitive strain which is defined in the present work as a dependent variable of major strain and thickness strain.

  11. Why Are Drugs So Hard to Quit?

    Medline Plus

    Full Text Available ... Quitting drugs is hard because addiction is a brain disease. Your brain is like a control tower that sends out ... and choices. Addiction changes the signals in your brain and makes it hard to feel OK without ...

  12. Why Are Drugs So Hard to Quit?

    Medline Plus

    Full Text Available ... Quitting drugs is hard because addiction is a brain disease. Your brain is like a control tower that sends out ... and choices. Addiction changes the signals in your brain and makes it hard to feel OK without ...

  13. Hardness and microstructure of internally oxidized silver alloys

    Energy Technology Data Exchange (ETDEWEB)

    Prorok, B. C.; Park, J. H.; Goretta, K. C.; Balachandran, U.; McNallan, M. J.

    1999-11-11

    Alloys of Ag, Ag/1.12 at.% Mg, and Ag/0.25 at.% Mg-0.25 at.% Ni were internally oxidized at 450 to 825 C and their hardnesses and microstructure were observed. Microhardness profiles showed that hardness was high near the surface and decreased with depth into the sample. Microstructure contained regions of small and large grains, where region sizes were dependent on treatment temperature. Transitions between small- and large-grained regions were abrupt. Treatments at higher temperatures failed to alter grain structure, indicating that Mg-O clusters had indeed pinned the grain boundaries. Clustering was shown to affect the hardness of oxidized alloys, not only by inhibiting grain growth, but also by inhibiting dislocation motion.

  14. Phase diagram of hard snowman-shaped particles.

    Science.gov (United States)

    Dennison, Matthew; Milinković, Kristina; Dijkstra, Marjolein

    2012-07-28

    We present the phase diagram of hard snowman-shaped particles calculated using Monte Carlo simulations and free energy calculations. The snowman particles consist of two hard spheres rigidly attached at their surfaces. We find a rich phase behavior with isotropic, plastic crystal, and aperiodic crystal phases. The crystalline phases found to be stable for a given sphere diameter ratio correspond mostly to the close packed structures predicted for equimolar binary hard-sphere mixtures of the same diameter ratio. However, our results also show several crystal-crystal phase transitions, with structures with a higher degree of degeneracy found to be stable at lower densities, while those with the best packing are found to be stable at higher densities.

  15. Raman Model Predicting Hardness of Covalent Crystals

    OpenAIRE

    Zhou, Xiang-Feng; Qian, Quang-Rui; Sun, Jian; Tian, Yongjun; Wang, Hui-Tian

    2009-01-01

    Based on the fact that both hardness and vibrational Raman spectrum depend on the intrinsic property of chemical bonds, we propose a new theoretical model for predicting hardness of a covalent crystal. The quantitative relationship between hardness and vibrational Raman frequencies deduced from the typical zincblende covalent crystals is validated to be also applicable for the complex multicomponent crystals. This model enables us to nondestructively and indirectly characterize the hardness o...

  16. Hydration entropy change from the hard sphere model.

    Science.gov (United States)

    Graziano, Giuseppe; Lee, Byungkook

    2002-12-10

    The gas to liquid transfer entropy change for a pure non-polar liquid can be calculated quite accurately using a hard sphere model that obeys the Carnahan-Starling equation of state. The same procedure fails to produce a reasonable value for hydrogen bonding liquids such as water, methanol and ethanol. However, the size of the molecules increases when the hydrogen bonds are turned off to produce the hard sphere system and the volume packing density rises. We show here that the hard sphere system that has this increased packing density reproduces the experimental transfer entropy values rather well. The gas to water transfer entropy values for small non-polar hydrocarbons is also not reproduced by a hard sphere model, whether one uses the normal (2.8 A diameter) or the increased (3.2 A) size for water. At least part of the reason that the hard sphere model with 2.8 A size water produces too small entropy change is that the size of water is too small for a system without hydrogen bonds. The reason that the 3.2 A model also produces too small entropy values is that this is an overly crowded system and that the free volume introduced in the system by the addition of a solute molecule produces too much of a relief to this crowding. A hard sphere model, in which the free volume increase is limited by requiring that the average surface-to-surface distance between the solute and water molecules is the same as that between the increased-size water molecules, does approximately reproduce the experimental hydration entropy values.

  17. Study on indium leaching from mechanically activated hard zinc residue

    Directory of Open Access Journals (Sweden)

    Yao J.H.

    2011-01-01

    Full Text Available In this study, changes in physicochemical properties and leachability of indium from mechanically activated hard zinc residue by planetary mill were investigated. The results showed that mechanical activation increased specific surface area, reaction activity of hard zinc residue, and decreased its particle size, which had a positive effect on indium extraction from hard zinc residue in hydrochloric acid solution. Kinetics of indium leaching from unmilled and activated hard zinc residue were also investigated, respectively. It was found that temperature had an obvious effect on indium leaching rate. Two different kinetic models corresponding to reactions which are diffusion controlled, [1-(1- x1/3]2=kt and (1-2x/3-(1-x2/3=kt were used to describe the kinetics of indium leaching from unmilled sample and activated sample, respectively. Their activation energies were determined to be 17.89 kJ/mol (umilled and 11.65 kJ/mol (activated within the temperature range of 30°C to 90°C, which is characteristic for a diffusion controlled process. The values of activation energy demonstrated that the leaching reaction of indium became less sensitive to temperature after hard zinc residue mechanically activated by planetary mill.

  18. 7 CFR 201.21 - Hard seed.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Hard seed. 201.21 Section 201.21 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Agricultural Seeds § 201.21 Hard seed. The label shall show the percentage of hard...

  19. 7 CFR 201.30 - Hard seed.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Hard seed. 201.30 Section 201.30 Agriculture..., Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) FEDERAL SEED ACT FEDERAL SEED ACT REGULATIONS Labeling Vegetable Seeds § 201.30 Hard seed. The label shall show the percentage of hard seed,...

  20. Effect of Relative Thickness on Microstructures and Hardness of TiB2 Particles Reinforced 45 Steel Matrix Surface Composites%相对厚度对TiB2颗粒增强45钢基表面复合材料组织和硬度的影响

    Institute of Scientific and Technical Information of China (English)

    韩文华; 郭长庆; 程军

    2011-01-01

    介绍了采用SHS和V-EPC真空消失模铸造相结合制备二硼化钛颗粒增强钢基表面复合材料的组织和硬度特点,重点研究了相对厚度的影响.利用扫描电镜、电子探针和光学显微镜等观察和分析了复合层的显微组织,并测试了显微硬度.结果表明,随着相对厚度δ的增加,复合材料的组织致密性得到改善,宏观缺陷减少,在相对厚度δ=9时复合材料质量最佳.复合层的组织主要由硬质相TiB2、TiC和基体组成,细小弥散的TiB2和TiC颗粒交替地分布在基体上,组织中呈方形的TiB2颗粒在数量上远远多于呈多边形的TiC颗粒;复合层的硬度随着距合金层表面深度的增加而降低,硬度最大值为1 449 HV.%This paper introduced TiB2 particles reinforced 45 steel matrix surface composites fabricated by self-propagating high-temperature synthesis (SHS) combined with V-EPC foundry technology. The feature of micro structure and hardness of the composite is present. The effect of relative thickness (δ) on the microstructures of the surface composite layer was investigated, and the microscopic structure was observed and analyzed by scanning electron microscopy, electron probe and optical microscope. Then the surface hardness of the composite was tested. The results show that with the increase of relative thickness (δ), quality of the surface composite was improved and macro-defect reduced obviously. When the δ equaled 9, the best quality is obtained. The microstructure of the composite has three different layers, composite layer, transition layer and the matrix layer. The structure of composite layer is mainly consisted of carbide and matrix. Dispersed TiB2 and TiC are alternating distributed on the matrix layer. But the quantity of rectangular TiB2 is more than polygonal TiC. The matrix is formed of pearlite and ferrite. There is very fine pearlite,granular pearlite, ferrite and carbide in the transition layer. Micro-hardness in the

  1. The hard problem of cooperation.

    Directory of Open Access Journals (Sweden)

    Kimmo Eriksson

    Full Text Available Based on individual variation in cooperative inclinations, we define the "hard problem of cooperation" as that of achieving high levels of cooperation in a group of non-cooperative types. Can the hard problem be solved by institutions with monitoring and sanctions? In a laboratory experiment we find that the answer is affirmative if the institution is imposed on the group but negative if development of the institution is left to the group to vote on. In the experiment, participants were divided into groups of either cooperative types or non-cooperative types depending on their behavior in a public goods game. In these homogeneous groups they repeatedly played a public goods game regulated by an institution that incorporated several of the key properties identified by Ostrom: operational rules, monitoring, rewards, punishments, and (in one condition change of rules. When change of rules was not possible and punishments were set to be high, groups of both types generally abided by operational rules demanding high contributions to the common good, and thereby achieved high levels of payoffs. Under less severe rules, both types of groups did worse but non-cooperative types did worst. Thus, non-cooperative groups profited the most from being governed by an institution demanding high contributions and employing high punishments. Nevertheless, in a condition where change of rules through voting was made possible, development of the institution in this direction was more often voted down in groups of non-cooperative types. We discuss the relevance of the hard problem and fit our results into a bigger picture of institutional and individual determinants of cooperative behavior.

  2. Systematic hardness studies on lithium niobate crystals

    Indian Academy of Sciences (India)

    K G Subhadra; K Kishan Rao; D B Sirdeshmukh

    2000-04-01

    In view of discrepancies in the available information on the hardness of lithium niobate, a systematic study of the hardness has been carried out. Measurements have been made on two pure lithium niobate crystals with different growth origins, and a Fe-doped sample. The problem of load variation of hardness is examined in detail. The true hardness of LiNbO3 is found to be 630 ± 30 kg/mm2. The Fe-doped crystal has a larger hardness of 750 ± 50 kg/mm2.

  3. Hard Identity and Soft Identity

    Directory of Open Access Journals (Sweden)

    Hassan Rachik

    2006-04-01

    Full Text Available Often collective identities are classified depending on their contents and rarely depending on their forms. Differentiation between soft identity and hard identity is applied to diverse collective identities: religious, political, national, tribal ones, etc. This classification is made following the principal dimensions of collective identities: type of classification (univocal and exclusive or relative and contextual, the absence or presence of conflictsof loyalty, selective or totalitarian, objective or subjective conception, among others. The different characteristics analysed contribute to outlining an increasingly frequent type of identity: the authoritarian identity.

  4. Sampling hard to reach populations.

    Science.gov (United States)

    Faugier, J; Sargeant, M

    1997-10-01

    Studies on 'hidden populations', such as homeless people, prostitutes and drug addicts, raise a number of specific methodological questions usually absent from research involving known populations and less sensitive subjects. This paper examines the advantages and limitations of nonrandom methods of data collection such as snowball sampling. It reviews the currently available literature on sampling hard to reach populations and highlights the dearth of material currently available on this subject. The paper also assesses the potential for using these methods in nursing research. The sampling methodology used by Faugier (1996) in her study of prostitutes, HIV and drugs is used as a current example within this context.

  5. Radiation Hardness Assurance (RHA) Guideline

    Science.gov (United States)

    Campola, Michael J.

    2016-01-01

    Radiation Hardness Assurance (RHA) consists of all activities undertaken to ensure that the electronics and materials of a space system perform to their design specifications after exposure to the mission space environment. The subset of interests for NEPP and the REAG, are EEE parts. It is important to register that all of these undertakings are in a feedback loop and require constant iteration and updating throughout the mission life. More detail can be found in the reference materials on applicable test data for usage on parts.

  6. Thermopile detector radiation hard readout

    Science.gov (United States)

    Gaalema, Stephen; Van Duyne, Stephen; Gates, James L.; Foote, Marc C.

    2010-08-01

    The NASA Jupiter Europa Orbiter (JEO) conceptual payload contains a thermal instrument with six different spectral bands ranging from 8μm to 100μm. The thermal instrument is based on multiple linear arrays of thermopile detectors that are intrinsically radiation hard; however, the thermopile CMOS readout needs to be hardened to tolerate the radiation sources of the JEO mission. Black Forest Engineering is developing a thermopile readout to tolerate the JEO mission radiation sources. The thermal instrument and ROIC process/design techniques are described to meet the JEO mission requirements.

  7. Loose abrasive lapping hardness of optical glasses and its interpretation.

    Science.gov (United States)

    Lambropoulos, J C; Xu, S; Fang, T

    1997-03-01

    We present an interpretation of the lapping hardness of commercially available optical glasses in terms of a micromechanics model of material removal by subsurface lateral cracking. We analyze data on loose abrasive microgrinding, or lapping at fixed nominal pressure, for many commercially available optical glasses in terms of this model. The Schott and Hoya data on lapping hardness are correlated with the results of such a model. Lapping hardness is a function of the mechanical properties of the glass: The volume removal rate increases approximately linearly with Young's modulus, and it decreases with fracture toughness and (approximately) the square of the Knoop hardness. The microroughness induced by lapping depends on the plastic and elastic properties of the glass, depending on abrasive shape. This is in contrast to deterministic microgrinding (fixed infeed rate), where it is determined from the plastic and fracture properties of the glass. We also show that Preston's coefficient has a similar dependence as lapping hardness on glass mechanical properties, as well as a linear dependence on abrasive size for the case of brittle material removal. These observations lead to the definition of an augmented Preston coefficient during brittle material removal. The augmented Preston coefficient does not depend on glass material properties or abrasive size and thus describes the interaction of the glass surface with the coolant-immersed abrasive grain and the backing plate. Numerical simulations of indentation are used to locate the origin of subsurface cracks and the distribution of residual surface and subsurface stresses, known to cause surface (radial) and subsurface (median, lateral) cracks.

  8. Influence of Zn (II) ion on abrasive-free polishing of hard disk substrate

    Energy Technology Data Exchange (ETDEWEB)

    Lei, Hong, E-mail: hong_lei2005@163.com; Zhao, Rong, E-mail: zr890804@163.com; Chen, Ruling, E-mail: chen_ruling@163.com

    2014-07-01

    With higher requirement setting for hard disk substrate to minimize roughness and defects of the polished surface, abrasive-free polishing (AFP) of hard disk substrate has been put forward in this paper. The effect of Zn (II) ion on the AFP of hard disk substrate in the H{sub 2}O{sub 2} based slurry was investigated by AFP tests. The results indicate that the material removal rate of hard disk substrate polished in slurry with Zn (II) ion is obviously higher than that without Zn (II) ion. And surface polished by slurry containing Zn (II) ion exhibits lower surface roughness and fewer nano-asperity peaks than that without Zn (II) ion. Furthermore, the acting mechanism of Zn (II) ion in AFP of hard disk substrate was analyzed. X-ray photoelectron spectroscopy analysis shows that metal Zn appears on the polished surface, implying the tribochemistry reaction occurs during AFP. The electrochemical reaction between metal Zn and oxide film Ni{sub 2}O{sub 3} on the surface of hard disk substrate during AFP can promote the chemical effect in AFP and lead to the increasing of material removal rate. - Highlights: • Zn (II) ion improves surface quality in abrasive-free polishing (AFP). • The removal rate increases with the increasing of Zn (II) ion content. • Tribo-chemistry reaction exists during AFP. • Zn (II) ion accelerates the electrochemistry reaction during AFP.

  9. Hard Fault Analysis of Trivium

    CERN Document Server

    Yupu, Hu; Yiwei, Zhang

    2009-01-01

    Fault analysis is a powerful attack to stream ciphers. Up to now, the major idea of fault analysis is to simplify the cipher system by injecting some soft faults. We call it soft fault analysis. As a hardware-oriented stream cipher, Trivium is weak under soft fault analysis. In this paper we consider another type of fault analysis of stream cipher, which is to simplify the cipher system by injecting some hard faults. We call it hard fault analysis. We present the following results about such attack to Trivium. In Case 1 with the probability not smaller than 0.2396, the attacker can obtain 69 bits of 80-bits-key. In Case 2 with the probability not smaller than 0.2291, the attacker can obtain all of 80-bits-key. In Case 3 with the probability not smaller than 0.2291, the attacker can partially solve the key. In Case 4 with non-neglectable probability, the attacker can obtain a simplified cipher, with smaller number of state bits and slower non-linearization procedure. In Case 5 with non-neglectable probability,...

  10. Novel Pretreatment of Hard Metal Substrate for Better Performance of Diamond Coated Cutting Tools

    Institute of Scientific and Technical Information of China (English)

    LU Fan-xiu; TANG Wei-zhong; MIAO Jin-qi; HE Li-fu; LI Cheng-ming; CHEN Guang-chao

    2004-01-01

    A surface engineering approach for a novel pre-treatment of hard metal tool substrate for optimum adhesion of diamond coatings is presented. Firstly, an alkaline solution was used to etch the WC grains to generate a rough surface for better mechanical interlocking. Subsequently, surface Co was removed by etching in acid solution. Then the hard metal substrate was boronized to form a compound interlayer which acted as an efficient diffusion barrier to prevent the outward diffusion of Co. Novel nano-microcrystalline composite diamond film coatings with a very smooth surface was deposited on the surface engineering pre-treated hard metal surface. Promising results of measurement in adhesion strength as well as field cutting tests have been obtained.

  11. Effect of wall hardness on hemolysis.

    Science.gov (United States)

    Yasuda, T; Shimokasa, K; Funakubo, A; Fukui, Y

    2000-08-01

    One of the major problems for artificial organs to develop and to improve is the reduction of hemolysis. The optimum designing of less hemolysis artificial organs is achieved through computational analysis and flow visualization techniques. However, it is impossible to know the quantitative relation between hemolysis and these analytic data. Thus, in vitro studies were performed to estimate these devices on hemolysis because there is no standard for designing these devices with less hemolysis. Therefore, it is essential to reveal the relation between blood flow behaviors and hemolysis. Previous studies reported that hemolysis was caused by a combination of physical factors. In particular, shear stress, pressure, and other fluid dynamical effects were shown to induce hemolysis. In another fluid dynamical experiment reported, the collision flow against the sanded wall was considered the most important factor that directly effected blood damage, which led to hemolysis. The blood flow impact of the collision against the wall effected serious damage to red blood cells. The objective of this study was to point out the relationship between physical force (pressure) in collision flow and hemolysis. In vitro tests using bovine blood and a circulation model that included a jet flow that collides against a wall were conducted. In these tests, we changed the material of the wall by replacing silicone rubber of various thicknesses. The thickness of the silicone rubber is inversely proportional to its hardness. The results show that the increasing rate of hemolysis was lower when the surface was coated by silicone rubber. In conclusion, we considered that it is possible to reduce hemolysis by adjusting the hardness of the material and contacted blood flow.

  12. Vickers hardness measurement of ion implanted MgO

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, Y. (TRCRE, JAERI, 1233 Watanuki-machi, Takasaki, Gunma 370-12 (Japan)); Rueck, D.M. (Materialforschung, UNILAC, GSI, D-6100, Darmstadt (Germany)); Vogt, D. (Materialforschung, UNILAC, GSI, D-6100, Darmstadt (Germany)); Leible, K. (Materialforschung, UNILAC, GSI, D-6100, Darmstadt (Germany)); Khubeis, I. (University of Jordan, P.O. Box 13097, Amman (Jordan)); Meyer, O. (INFP, KfK, D-7500, Karlsruhe 1 (Germany))

    1994-06-01

    The Vickers hardness was measured for single crystals of MgO(100) implanted with 130 keV or 1.8 MeV Ar[sup +] ions and with 400 keV Xe[sup 2+] ions by means of the indentation technique with an applied load of 0.4-30 mN. Implantation with 130 keV Ar[sup +] and 400 keV Xe[sup 2+] gave similar results in hardening of MgO surface layers. In addition, the dose dependence of the measured hardness curve showed that a softening mechanism takes place at high doses. High energy implantation (1.8 MeV Ar[sup +]) made a hardened surface layer on MgO. This hardened layer also became softer at high doses. ((orig.))

  13. Investigation of Specificity of Mechanical Properties of Hard Materials on Nanoscale with Use of SPM- Nanohardness Tester

    Science.gov (United States)

    Lvova, N. A.; Blank, V. D.; Gogolinskiy, K. V.; Kulibaba, V. F.

    2007-04-01

    Specifisities of deformation on nanoscale of hard brittle materials with the hardness exceeding 10 GP by means of scanning probe microscope - nanohardness tester "NanoScan" are investigated. It is found, that pile-up is forming at scratching of sample surface with use of diamond indenter. Heigh of this pile-up depends on hardness and elastic modulus of the material. Definition of the contact area without taking into account height of pile-up leads to an overestimation of hardness values. At scratching of silicon carbide surface a transition from plastic flow to fracture is found out. The results received allowed to estimate fracture toughness KIC for silicon carbide.

  14. Effects of hardness and alkalinity in culture and test waters on reproduction of Ceriodaphnia dubia.

    Science.gov (United States)

    Lasier, Peter J; Winger, Parley V; Hardin, Ian R

    2006-10-01

    Ceriodaphnia dubia were cultured in four reconstituted water formulations with hardness and alkalinity concentrations ranging from soft to the moderately hard water that is required by whole-effluent toxicity (WET) testing methods for culturing test organisms. The effects of these culture formulations alone and in combination with two levels of Cl-, SO4(2-), and HCO3- on reproduction of C. dubia were evaluated with the standard three-brood test. Reproduction was significantly reduced when test waters had lower hardness than culture waters. However, reproduction was not significantly different when animals cultured in low-hardness waters were exposed to moderately hard waters. The hardness of the culture water did not significantly affect the sensitivity of C. dubia to the three anions. Conversely, increased hardness in test waters significantly reduced the toxicities of Cl- and SO4(2-), with HCO3- toxicity following the same pattern. Alkalinity exhibited no consistent effect on Cl- and SO4(2-) toxicity. The physiological stress of placing animals cultured in moderately hard water into softer test waters might contribute to marginal failures of otherwise nontoxic effluents. The standard WET protocol should be revised to allow the culture of C. dubia under lower hardness conditions to better represent local surface water chemistries.

  15. Effects of hardness and alkalinity in culture and test waters on reproduction of Ceriodaphnia dubia

    Science.gov (United States)

    Lasier, P.J.; Winger, P.V.; Hardin, I.R.

    2006-01-01

    Ceriodaphnia dubia were cultured in four reconstituted water formulations with hardness and alkalinity concentrations ranging from soft to the moderately hard water that is required by whole-effluent toxicity (WET) testing methods for culturing test organisms. The effects of these culture formulations alone and in combination with two levels of Cl-, SO42, and HCO3- on reproduction of C. dubia were evaluated with the standard three-brood test. Reproduction was significantly reduced when test waters had lower hardness than culture waters. However, reproduction was not significantly different when animals cultured in low-hardness waters were exposed to moderately hard waters. The hardness of the culture water did not significantly affect the sensitivity of C. dubia to the three anions. Conversely, increased hardness in test waters significantly reduced the toxicities of Cl- and SO42-, with HCO3- toxicity following the same pattern. Alkalinity exhibited no consistent effect on Cl- and SO42- toxicity. The physiological stress of placing animals cultured in moderately hard water into softer test waters might contribute to marginal failures of otherwise nontoxic effluents. The standard WET protocol should be revised to allow the culture of C. dubia under lower hardness conditions to better represent local surface water chemistries.

  16. Hard rock, heavy metal, metal

    OpenAIRE

    Hein, Fabien

    2011-01-01

    Le terme générique metal désigne une multitude de genres et de sous-genres musicaux issus de l’appariement du hard rock et du heavy metal. Il résulte d’une agrégation sémantique consécutive de l’érosion et de l’interpénétration de ces termes au cours des années 1980. Leurs modèles canoniques, respectivement représentés par les groupes Led Zeppelin et Black Sabbath, se sont progressivement dilués sous l’effet d’une filiation particulièrement effervescente et féconde : black, thrash, doom, prog...

  17. Probing Strangeness in Hard Processes

    CERN Document Server

    Avakian, H; Cisbani, E; Contalbrigo, M; D'Alesio, U; De Leo, R; Devita, R; Di Nezza, P; Hasch, D; Mirazita, M; Osipenko, M; Pappalardo, L; Rossi, P

    2012-01-01

    Since the discovery of strangeness almost five decades ago, interest in this degree of freedom has grown up and now its investigation spans the scales from quarks to nuclei. Measurements with identified strange hadrons can provide important information on several hot topics in hadronic physics: the strange distribution and fragmentation functions, the nucleon tomography and quark orbital momentum, accessible through the study of the {\\it generalized} parton distribution and the {\\it transverse momentum dependent} parton distribution functions, the quark hadronization in the nuclear medium, the hadron spectroscopy and the search for exotic mesons. The CLAS12 large acceptance spectrometer in Hall B at the Jefferson Laboratory upgraded with a RICH detector together with the 12 GeV CEBAF high intensity, high polarized electron beam can open new possibilities to study strangeness in hard processes allowing breakthroughs in all those areas. This paper summarizes the physics case for a RICH detector for CLAS12. Many...

  18. A hard case for modeling

    Directory of Open Access Journals (Sweden)

    George Marsh

    2002-10-01

    Some fighter pilots alive today owe their survival to tough, low-weight helmets whose qualities have been refined as a result of biomechanical modeling. Porter and his colleagues have modeled the human head as a mechanical arrangement of a heavy ball on a rod support, as a system of soft matter contained in a hard case, as an arrangement of meso-scale sub-systems, and as a combination of material systems built up from the nano-molecular and atomic scales. An extensive modeling hierarchy (Fig. 1 is held on nothing more esoteric than a networked workstation and server architecture. Nevertheless, thanks to a process of focused simplification at each hierarchical level, it is able to predict the mechanical behavior of the human head and its constituents in reacting to impacts with considerable accuracy.

  19. Schwannoma of the hard palate.

    Science.gov (United States)

    Isildak, Huseyin; Yilmaz, Mehmet; Ibrahimov, Metin; Aslan, Mehmet; Karaman, Emin; Enver, Ozgun

    2010-01-01

    About half of all neurogenic tumors are seen in the head and neck region. The types of neurogenic tumors must be distinguished. Schwannomas originate from Schwann cells of the neural sheath and are solitary, well-encapsulated, slow-growing adjacent to the parental nerve but extrinsic to the nerve fascicles.Approximately 25% to 45% of all schwannomas are seen in the head and neck region and are found rarely in the oral cavity. Most of the intraoral schwannomas are located in the tongue. Other less common locations are the buccal mucosa, palate, base of the mouth, gingiva, and lips.In this study, we report a rare case of schwannoma of the hard palate, which was excised intraorally.

  20. Hard X-ray mirrors for Nuclear Security

    Energy Technology Data Exchange (ETDEWEB)

    Descalle, M. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Brejnholt, N. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hill, R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Decker, T. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Alameda, J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Soufli, R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Pivovaroff, M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Pardini, T. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-01-07

    Research performed under this LDRD aimed to demonstrate the ability to detect and measure hard X-ray emissions using multilayer X-ray reflective optics above 400 keV, to enable the development of inexpensive and high-accuracy mirror substrates, and to investigate applications of hard X-ray mirrors of interest to the nuclear security community. Experiments conducted at the European Synchrotron Radiation Facility demonstrated hard X-ray mirror reflectivity up to 650 keV for the first time. Hard X-ray optics substrates must have surface roughness under 3 to 4 Angstrom rms, and three materials were evaluated as potential substrates: polycarbonates, thin Schott glass and a new type of flexible glass called Willow Glass®. Chemical smoothing and thermal heating of the surface of polycarbonate samples, which are inexpensive but have poor intrinsic surface characteristics, did not yield acceptable surface roughness. D263 Schott glass was used for the focusing optics of the NASA NuSTAR telescope. The required specialized hardware and process were costly and motivated experiments with a modified non-contact slumping technique. The surface roughness of the glass was preserved and the process yielded cylindrical shells with good net shape pointing to the potential advantage of this technique. Finally, measured surface roughness of 200 and 130 μm thick Willow Glass sheets was between 2 and 2.5 A rms. Additional results of flexibility tests and multilayer deposition campaigns indicated it is a promising substrate for hard X-ray optics. The detection of U and Pu characteristics X-ray lines and gamma emission lines in a high background environment was identified as an area for which X-ray mirrors could have an impact and where focusing optics could help reduce signal to noise ratio by focusing signal onto a smaller detector. Hence the first one twelvetant of a Wolter I focusing optics for the 90 to 140 keV energy range based on aperiodic multilayer coating was designed. Finally

  1. Transdermal therapeutic system of narcotic analgesics using nonporous membrane (I) : Effect of the ethanol permeability on vinylacetate content of EVA membrane

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, H.; Song, H.Y. [Chungnam National University, Taejon (Korea); Khang, G.S. [Chonbuk National University, Chonju (Korea); Lee, H.B. [Korea Research Institute of Chemical Technology, Taejon (Korea)

    1999-05-01

    The fundamental properties of transdermal therapeutic patch as narcotic analgesics agent has been investigated. From the study of drug and ethanol release patterns from the fentanyl base (FB) patches through diffusion cell and hairless mouse skin, it was observed that the FB release patterns were largely affected by the content of vinyl acetate (VA) of ethylene-co-vinyl acetate (EVA) membrane, and volume fraction of ethanolic solution. Additionally, a variety of control membrane as a function of VA content were examined for swelling following equilibration with ethanolic solutions. Generally, ethanol was incorporated into a transdermal therapeutic device to enable the controlled delivery of enhancer and drug to the skin surface. In vitro skin permeation analysis of the control membrane showed that ethanol flux was linearly related to the ethanol volume fraction. This result was shown that drug permeability increased with increasing as the content of VA. But, the FB flux from saturated aqueous ethanol solutions increases until 80% ethanol volume fraction. Over 80% ethanol volume fraction, the FB flux through skin samples is independent of ethanol volume. These results showed that the decrease in skin permeation due to dehydration nis the dominant effect. 26 refs., 8 figs.

  2. Hardware Assisted ROP Detection Mode (HARD Mode)

    Science.gov (United States)

    2013-08-01

    Distribution A. Cleared for public release; unlimited distribution. USAFA-CN-2013-457 Hardware Assisted ROP Detection Mode (HARD Mode) NATHANIEL HART...457 This report, "Hardware Assisted ROP Detection Mode (HARD Mode)" is presented as a competent treatment of the subj ect, worthy of publication. The...Technical 20120810-20121215 Hardware Assisted ROP Detection Mode (HARD Mode) NATHANIEL HART MICHAEL WINSTEAD MARTIN CARLISLE RODNEY LYKINS MICHAEL

  3. Hardness measures and resolution lower bounds

    OpenAIRE

    Beyersdorff, Olaf; Kullmann, Oliver

    2013-01-01

    Various "hardness" measures have been studied for resolution, providing theoretical insight into the proof complexity of resolution and its fragments, as well as explanations for the hardness of instances in SAT solving. In this report we aim at a unified view of a number of hardness measures, including different measures of width, space and size of resolution proofs. We also extend these measures to all clause-sets (possibly satisfiable).

  4. Unified characterisations of resolution hardness measures

    OpenAIRE

    Beyersdorff, O; Kullmann, O.

    2014-01-01

    Various "hardness" measures have been studied for resolution, providing theoretical insight into the proof complexity of resolution and its fragments, as well as explanations for the hardness of instances in SAT solving. In this paper we aim at a unified view of a number of hardness measures, including different measures of width, space and size of resolution proofs. Our main contribution is a unified game-theoretic characterisation of these measures. As consequences we obtain new relations b...

  5. Shock Waves in Dense Hard Disk Fluids

    OpenAIRE

    Sirmas, Nick; Tudorache, Marion; Barahona, Javier; Radulescu, Matei I.

    2011-01-01

    Media composed of colliding hard disks (2D) or hard spheres (3D) serve as good approximations for the collective hydrodynamic description of gases, liquids and granular media. In the present study, the compressible hydrodynamics and shock dynamics are studied for a two-dimensional hard-disk medium at both the continuum and discrete particle level descriptions. For the continuum description, closed form analytical expressions for the inviscid hydrodynamic description, shock Hugoniot, isentropi...

  6. Comparison of latex body paint with wetted gauze wipes for sampling the chemical warfare agents VX and sulfur mustard from common indoor surfaces.

    Science.gov (United States)

    Hernon-Kenny, Laura A; Behringer, Deborah L; Crenshaw, Michael D

    2016-05-01

    Comparison of solvent-wetted gauze with body paint, a peelable surface sampling media, for the sampling of the chemical warfare agents VX and sulfur mustard from nine surfaces was performed. The nine surfaces sampled are those typical of interior public venues and include smooth, rough, porous, and non-porous surfaces. Overall, solvent-wetted gauze (wipes) performed better for the recovery of VX from non-porous surfaces while body paint (BP) performed better for the porous surfaces. The average percent VX recoveries using wipes and BP, respectively, are: finished wood flooring, 86.2%, 71.4%; escalator handrail, 47.3%, 26.7%; stainless steel, 80.5%, 56.1%; glazed ceramic tile, 81.8%, 44.9%; ceiling tile, 1.77%, 13.1%; painted drywall 7.83%, 21.1%; smooth cement, 0.64%, 10.3%; upholstery fabric, 24.6%, 23.1%; unfinished wood flooring, 9.37%, 13.1%. Solvent-wetted gauze performed better for the recovery of sulfur mustard from three of the relatively non-porous surfaces while body paint performed better for the more porous surfaces. The average percent sulfur mustard recoveries using wipes and BP, respectively, are: finished wood flooring, 30.2%, 2.97%; escalator handrail, 4.40%, 4.09%; stainless steel, 21.2%, 3.30%; glazed ceramic tile, 49.7%, 16.7%; ceiling tile, 0.33%, 11.1%; painted drywall 2.05%, 10.6%; smooth cement, 1.20%, 35.2%; upholstery fabric, 7.63%, 6.03%; unfinished wood flooring, 0.90%, 1.74%.

  7. Potential health impacts of hard water

    National Research Council Canada - National Science Library

    Sengupta, Pallav

    2013-01-01

    ... the hardness of the drinking water. In addition, several epidemiological investigations have demonstrated the relation between risk for cardiovascular disease, growth retardation, reproductive failure, and other health problems...

  8. Effect of a multi-layer infection control barrier on the micro-hardness of a composite resin

    Directory of Open Access Journals (Sweden)

    In-Nam Hwang

    2012-10-01

    Full Text Available OBJECTIVE: The aim of this study was to evaluate the effect of multiple layers of an infection control barrier on the micro-hardness of a composite resin. MATERIAL AND METHODS: One, two, four, and eight layers of an infection control barrier were used to cover the light guides of a high-power light emitting diode (LeD light curing unit (LCU and a low-power halogen LCU. The composite specimens were photopolymerized with the LCUs and the barriers, and the micro-hardness of the upper and lower surfaces was measured (n=10. The hardness ratio was calculated by dividing the bottom surface hardness of the experimental groups by the irradiated surface hardness of the control groups. The data was analyzed by two-way ANOVA and Tukey's HSD test. RESULTS: The micro-hardness of the composite specimens photopolymerized with the LED LCU decreased significantly in the four- and eight-layer groups of the upper surface and in the two-, four-, and eight-layer groups of the lower surface. The hardness ratio of the composite specimens was <80% in the eight-layer group. The micro-hardness of the composite specimens photopolymerized with the halogen LCU decreased significantly in the eight-layer group of the upper surface and in the two-, four-, and eight-layer groups of the lower surface. However, the hardness ratios of all the composite specimens photopolymerized with barriers were <80%. CONCLUSIONS: The two-layer infection control barrier could be used on high-power LCUs without decreasing the surface hardness of the composite resin. However, when using an infection control barrier on the low-power LCUs, attention should be paid so as not to sacrifice the polymerization efficiency.

  9. 不同消毒方法对碳离子改性硅橡胶表面自由能及邵氏硬度的影响%Effect of different disinfection methods on surface free energy and Shore hardness of carbon ion-implanted silicone rubber

    Institute of Scientific and Technical Information of China (English)

    周鑫; 陈兴; 石小花; 王韶亮; 雷泽源; 樊东力; 张一鸣

    2016-01-01

    目的 初步探讨碳离子硅橡胶经过不同消毒试剂与方法处理后其表面亲疏水性、表面自由能以及邵氏硬度的变化情况.方法 碳离子硅橡胶经过70%酒精、2%碱性戊二醛、0.5%碘伏、5.25%次氯酸钠、3%过氧化氢以及134℃高温、高压等消毒试剂或方法处理后,采用静态接触角测定仪检测其表面水、甘油接触角以及邵氏硬度变化情况,采用Owen-Wendt公式计算表面自由能γs、极性分量γsp以及非极性分量γsd变化.结果 碳离子硅橡胶经过5.25%次氯酸钠以及3%过氧化氢处理后,其表面接触角以及表面自由能发生明显变化,前者使得其表面呈现出完全的亲水性;70%酒精、2%碱性戊二醛、0.5%碘伏以及134℃高温、高压等方法对材料表面接触角以及表面自由能等影响较小.不同处理组材料表面邵氏硬度差异均无统计学意义.结论 70%酒精以及134℃高温、高压等消毒方法对碳离子硅橡胶表面性能影响最小,结合操作便利性等因素,70%酒精可认为是该材料最适宜的消毒处理方式.而次氯酸钠消毒液极不利于该材料表面形貌维持,不宜采用.%Objective To study the changes of surface contact angle,surface free energy and Shore hardness of carbon ion-implanted silicone rubber disinfected by different methods.Methods Carbon ionimplanted silicone rubber was treated with 70% alcohol,2% alkaline glutaraldehyde,0.5% iodine volts,5.25% sodium hypochlorite,3% hydrogen peroxide respectively,and high temperature of 134℃ under high pressure for 2 h,and then the surface contact angle and Shore hardness were tested with a contact angle instrument and a Shore durometer (type A).Surface free energy,polar component and nonpolar component were calculated with Owen-Wendt methods.Results The surface quality of carbon ion-implanted silicone rubber was changed after disinfection with 3% hydrogen peroxide and 5.25% sodium

  10. Hardness Evaluation of Composite Resins Cured with QTH and LED

    Directory of Open Access Journals (Sweden)

    Behnaz Esmaeili

    2014-03-01

    Full Text Available Background and aims. Today light cured composites are widely used. Physical and mechanical properties of composites are related to the degree of conversion. Light curing unit (LCU is an important factor for composite polymerization. Aim of this study is evaluation of composite resins hardness using halogen and LED light curing units. Materials and methods. In this study, 30 samples of Filtek Z250 and C-Fill composite resins were provided. Samples were light cured with Ultralume2, Valo and Astralis7. Vickers hardness number (VHN was measured in 0, 1, 2 mm depth. Statistical analysis used: Data were analysed by SPSS software and compared with each other by T-test, one-way and twoway ANOVA and Post-hoc Tukey test. Results. In Filtek Z250, at top surface, VHN of Ultralume2 was higher than VHN of Valo (P = 0.02 and Astralis7 (P = 0.04, but in depth of 1, 2 mm, VHN of Ultralume2 and Astralis7 were almost the same and both LCUs were more than Valo which the difference between Ultralume2 and Valo was significant in depth of 1mm (0.05 and 2mm (0.02. In C-Fill composite, at top surface, Astralis7 showed higher VHN, but in depth of 2 mm, performance of all devices were rather similar. Conclusion. In Z250, which contains camphorquinone initiator, light cure LED Ultra-lume2 with narrow wavelength showed higher hardness number than Valo. In C-fill, in top surface, Astralis7 with more exposure time, resulted higher VHN. But In depth of 2 mm, various light curing devices had rather similar hardness number.

  11. High-resolution, hard x-ray photoemission investigation of BaFe2As2: Moderate influence of the surface and evidence for a low degree of Fe 3d-As 4p hybridization of electronic states near the Fermi energy

    NARCIS (Netherlands)

    de Jong, S.; Huang, Y.; Huisman, R.; Massee, F.; Thirupathaiah, R.; Gorgoi, M.; Schaefers, F.; Follath, F.; Goedkoop, J.B.; Golden, M.S.

    2009-01-01

    Photoemission data taken with hard x-ray radiation on cleaved single crystals of the barium parent compound of the MFe2As2 pnictide high-temperature superconductor family are presented. Making use of the increased bulk sensitivity upon hard x-ray excitation, and comparing the results to data taken

  12. Hard disks with SCSI interface

    CERN Document Server

    Denisov, O Yu

    1999-01-01

    The testing of 20 models of hard SCSI-disks is carried out: the Fujitsu MAE3091LP; the IBM DDRS-39130, DGHS-318220, DNES-318350, DRHS-36V and DRVS-18V; the Quantum Atlas VI 18.2; the Viking 11 9.1; the Seagate ST118202LW, ST118273LW, ST118273W, ST318203LW, ST318275LW, ST34520W, ST39140LW and ST39173W; and the Western Digital WDE9100-0007, WDE9100-AV0016, WDE9100-AV0030 and WDE9180-0048. All tests ran under the Windows NT 4.0 workstation operating system with Service Pack 4, under video mode with 1024*768 pixel resolution, 32- bit colour depth and V-frequency equal to 85 Hz. The detailed description and characteristics of SCSI stores are presented. Test results (ZD Winstone 99 and ZD WinBench 99 tests) are given in both table and diagram (disk transfer rate) forms. (0 refs).

  13. Nanoscale morphology for high hydrophobicity of a hard sol gel thin film

    Science.gov (United States)

    Wu, Y. L.; Chen, Z.; Zeng, X. T.

    2008-08-01

    It is challenging to obtain a hydrophobic smooth coating with high optical and mechanical properties at the same time because the hydrophobic additives are soft in nature resulting in reduced hardness and durability. This paper reports a durable hydrophobic transparent coating on glass fabricated by sol-gel technology and a low volume medium pressure (LVMP) spray process. The sol-gel formula consists of a pre-linked hydrophobic nano-cluster from hydroxyl-terminated polydimethylsiloxane, titanium tetraisopropoxide and a silica-based sol-gel matrix with silica hard fillers. Polydimethylsiloxane (PDMS) is uniformly distributed throughout the coating layer providing durable hydrophobic property. Mechanical properties are achieved by the hard matrix and hard fillers with the nano-structures. Due to the surface nano-morphology, a high degree of hydrophobicity was maintained with only 10 vol.% PDMS, while the hardness and abrasion resistance of the coatings were not significantly compromised. Chemical analyses by FTIR confirmed the uniform distribution of the PDMS and surface morphology analyses by atomic force microscopy (AFM) displayed the nano-surface structures that enhanced the hydrophobicity. The special surface nanostructures can be quantified using surface Kurtosis and ratio between asperity peak height to distance between peaks. The LVMP process influences the spray droplet size resulting in different surface structures.

  14. A Forging Hardness Dispersion Effect on the Energy Consumption of Machining

    Directory of Open Access Journals (Sweden)

    L. D. Mal'kova

    2015-01-01

    Full Text Available The aim of the work is to evaluate a hardness dispersion of forgings to be further machined, and analyse the impact of this dispersion on the resulting power consumption when cutting.The paper studies the hardness values of three kinds of parts for automotive manufacturing. Sample of each part was n = 100 pieces. Analysis of measurements showed that 46% - 93% of parts meet requirements for a range defined by the work-piece working drawing. It was found that hardness of one batch of forgings is under dispersion, which distribution is governed by the normal law.The work provides calculations for machining the external cylindrical surfaces of the considered parts. In the context of calculating are adopted parameters of the enterprise-processing rate. It is found that power consumption of machining because of the dispersion values of the work-piece hardness is a function of the random BH variable and it itself is a random variable. Two types of samples are considered, namely: the full sample and that of the values that meet requirements for hardness. The coefficient of variation for samples that meet the technical requirements for hardness is lower than for the full samples, so their average value is more reliable characteristic of a set. It was also found that to ensure a reliable prediction of power consumption in designing the manufacturing processes it is necessary to reduce a tolerance range of workpiece hardness to the limit.The work gives a comparative evaluation of electric power consumption per unit cylindrical surface of the parts under consideration. A relative change in the electric power consumed at the minimum and maximum levels of the hardness value was introduced as an evaluation criterion. It is found that with changing hardness of machined work-pieces within the tolerance, the change in power consumption in machining the unit surface reaches 16% while in the case its being out of the specified range it does 47%.

  15. ERRATUM: Work smart, wear your hard hat

    CERN Multimedia

    2003-01-01

    An error appeared in the article «Work smart, wear your hard hat» published in Weekly Bulletin 27/2003, page 5. The impact which pierced a hole in the hard hat worn by Gerd Fetchenhauer was the equivalent of a box weighing 5 kg and not 50 kg.

  16. Retraction of Hard, Lozano, and Tversky (2006)

    Science.gov (United States)

    Hard, B. M.; Lozano, S. C.; Tversky, B.

    2008-01-01

    Reports a retraction of "Hierarchical encoding of behavior: Translating perception into action" by Bridgette Martin Hard, Sandra C. Lozano and Barbara Tversky (Journal of Experimental Psychology: General, 2006[Nov], Vol 135[4], 588-608). All authors retract this article. Co-author Tversky and co-author Hard believe that the research results cannot…

  17. Hard Spring Wheat Technical Committee 2016 Crop

    Science.gov (United States)

    Seven experimental lines of hard spring wheat were grown at up to five locations in 2016 and evaluated for kernel, milling, and bread baking quality against the check variety Glenn. Wheat samples were submitted through the Wheat Quality Council and processed and milled at the USDA-ARS Hard Red Spri...

  18. Numerical Solution of Hard-Core Mixtures

    OpenAIRE

    Buhot, Arnaud; Krauth, Werner

    1997-01-01

    We study the equilibrium phase diagram of binary mixtures of hard spheres as well as of parallel hard cubes. A superior cluster algorithm allows us to establish and to access the demixed phase for both systems and to investigate the subtle interplay between short-range depletion and long-range demixing.

  19. Water hardness reduces the accumulation and toxicity of uranium in a freshwater macrophyte (Ceratophyllum demersum).

    Science.gov (United States)

    Markich, Scott J

    2013-01-15

    There is a lack of good quality data and mechanistic understanding on the effects of true water hardness (calcium (Ca) and magnesium (Mg)) on the bioavailability and toxicity of uranium (U) to freshwater biota. This study determined the effect of true water hardness (20, 75, 150, 275 and 400 mg CaCO(3) L(-1)) on the cell surface binding affinity (log K), accumulation and toxicity (growth inhibition) of U in a submerged, rootless, macrophyte (Ceratophyllum demersum) in a synthetic freshwater with constant alkalinity (13 mg CaCO(3) L(-1)) and pH (6.2) over 7 days. A 20-fold increase in water hardness resulted in a 4-fold decrease in U toxicity (median effect concentration (EC50)=134 μg L(-1)U at 20 mg CaCO(3 )L(-1) hardness, increasing to 547 μg L(-1) U at 400 mg CaCO(3) L(-1) hardness), cell surface binding affinity (log K=6.25 at 20 mg CaCO(3) L(-1) hardness, decreasing to log K=5.64 at 400 mg CaCO(3) L(-1) hardness) and accumulation (the concentration factor decreased from 63 at 20 mg CaCO(3) L(-1) hardness to 15 at 400 mg CaCO(3) L(-1) hardness) of U. Calcium provided a 4-fold greater protective effect against U accumulation and toxicity compared to Mg. Speciation calculations indicated negligible differences in the percentages of key U species (UO(2)(2+), UO(2)OH(+), UO(2)(OH)(2)) over the range of water hardness tested. The inhibition of U binding at the cell surface, and subsequent uptake, by C. demersum, with increasing Ca and/or Mg concentration, may be explained in terms of (i) competition between Ca(2+)/Mg(2+) and UO(2)(2+) (and/or UO(2)OH(+)) for physiologically active sites at the cell surface, and/or (ii) reduced negative charge (electrical potential) at the cell surface, resulting in a decrease in the activity of UO(2)(2+) (and/or UO(2)OH(+)) at the plant/water interface (boundary layer), and consequently, less U bound to physiologically active cell surface sites. In the absence of a biotic ligand model for U, the results of this study (together with

  20. Dentinogenesis imperfecta - hardness and Young's modulus of teeth.

    Science.gov (United States)

    Wieczorek, Aneta; Loster, Jolanta; Ryniewicz, Wojciech; Ryniewicz, Anna M

    2013-01-01

    Dentinogenesis imperfecta type II (DI-II) is the most common dental genetic disease with reported incidence 1 in 8000. Elasticity and hardness of the enamel of teeth are important values which are connected with their resistance to attrition. It is hypothesized that values of physical properties for healthy teeth and teeth with DI-II are different. The aim of the study was to investigate some physical properties of teeth extracted from patients with DI-II in comparison with normal teeth. The material of the study was six teeth: three lower molars, with clinical signs of DI-II, which were extracted due to complications of pulp inflammation and three other lower molars which were extracted for orthodontic reasons - well formed, without any signs of pathology. The surfaces of DI-II and normal teeth were tested on the CSM Instruments Scratch Tester machine (producer CSEM Switzerland) by Oliver and Pharr method. The indenter used was Vicker's VG-73 diamond indenter. Additionally, the Scanning Electron Microscopy (SEM) analysis of the surface of the teeth with DI-II was made. Vickers hardness of the teeth with dental pathology (DI-II) was seven times smaller, and Young's modulus six times smaller than those of healthy teeth. The parameters of hardness and elasticity of enamel of teeth with clinical diagnosis of DI-II were very much smaller than in normal teeth and because of that can be responsible for attrition.

  1. Hardness methods for testing maize kernels.

    Science.gov (United States)

    Fox, Glen; Manley, Marena

    2009-07-08

    Maize is a highly important crop to many countries around the world, through the sale of the maize crop to domestic processors and subsequent production of maize products and also provides a staple food to subsistance farms in undeveloped countries. In many countries, there have been long-term research efforts to develop a suitable hardness method that could assist the maize industry in improving efficiency in processing as well as possibly providing a quality specification for maize growers, which could attract a premium. This paper focuses specifically on hardness and reviews a number of methodologies as well as important biochemical aspects of maize that contribute to maize hardness used internationally. Numerous foods are produced from maize, and hardness has been described as having an impact on food quality. However, the basis of hardness and measurement of hardness are very general and would apply to any use of maize from any country. From the published literature, it would appear that one of the simpler methods used to measure hardness is a grinding step followed by a sieving step, using multiple sieve sizes. This would allow the range in hardness within a sample as well as average particle size and/or coarse/fine ratio to be calculated. Any of these parameters could easily be used as reference values for the development of near-infrared (NIR) spectroscopy calibrations. The development of precise NIR calibrations will provide an excellent tool for breeders, handlers, and processors to deliver specific cultivars in the case of growers and bulk loads in the case of handlers, thereby ensuring the most efficient use of maize by domestic and international processors. This paper also considers previous research describing the biochemical aspects of maize that have been related to maize hardness. Both starch and protein affect hardness, with most research focusing on the storage proteins (zeins). Both the content and composition of the zein fractions affect

  2. Driven self-assembly of hard nanoplates on soft elastic shells

    Institute of Scientific and Technical Information of China (English)

    章尧旸; 华昀峰; 邓真渝

    2015-01-01

    The driven self-assembly behaviors of hard nanoplates on soft elastic shells are investigated by using molecular dynamics (MD) simulation method, and the driven self-assembly structures of adsorbed hard nanoplates depend on the shape of hard nanoplates and the bending energy of soft elastic shells. Three main structures for adsorbed hard nanoplates, including the ordered aggregation structures of hard nanoplates for elastic shells with a moderate bending energy, the collapsed structures for elastic shells with a low bending energy, and the disordered aggregation structures for hard shells, are observed. The self-assembly process of adsorbed hard nanoplates is driven by the surface tension of the elastic shell, and the shape of driven self-assembly structures is determined on the basis of the minimization of the second moment of mass distribution. Meanwhile, the deformations of elastic shells can be controlled by the number of adsorbed rods as well as the length of adsorbed rods. This investigation can help us understand the complexity of the driven self-assembly of hard nanoplates on elastic shells.

  3. Improving hardness of electroless Ni-B coatings using optimized deposition conditions and annealing

    Energy Technology Data Exchange (ETDEWEB)

    Oraon, B. [Department of Mechanical Engineering, Jadavpur University, Kolkata 700 032 (India)], E-mail: b_oraon_65@yahoo.co.in; Majumdar, G. [Department of Mechanical Engineering, Jadavpur University, Kolkata 700 032 (India); Ghosh, B. [Advanced Materials and Solar Photovoltaic Division, School of Energy Studies, Jadavpur University, Kolkata 700 032 (India)

    2008-07-01

    The alkaline borohydride-reduced bath has been used to deposit electroless nickel-boron (Ni-B) coatings on a pure (99.99%) copper substrate. The hardness of the Ni-B coatings has been improved using optimized deposition conditions and thereafter by annealing. The electroless Ni-B deposition per unit area has been considered as the response variable and response surface method (RSM) has been used to optimize the process parameters and the deposition per unit area. The electroless Ni-B coatings have again been formed at the optimized deposition conditions and the as-deposited coating hardness has been evaluated using an empirical model and regression analysis. It has been observed that there is a significant improvement in as-deposited coating hardness. The Ni-B coated specimens formed at optimized deposition conditions have also been annealed at different temperatures ranging from 100 deg. C to 500 deg. C. The hardness of the annealed specimens has been estimated for different annealing temperatures and has been observed that the coating hardness increases with annealing temperature and then further increase in annealing temperature reduces the coating hardness. The coating hardness becomes the highest for annealing temperature of about 300 deg. C. Both the as-deposited and annealed coating hardness have been observed to be significantly higher than that reported by many researchers for electroless Ni-B coatings.

  4. Extended hard-sphere model and collisions of cohesive particles.

    Science.gov (United States)

    Kosinski, Pawel; Hoffmann, Alex C

    2011-09-01

    In two earlier papers the present authors modified a standard hard-sphere particle-wall and particle-particle collision model to account for the presence of adhesive or cohesive interaction between the colliding particles: the problem is of importance for modeling particle-fluid flow using the Lagrangian approach. This technique, which involves a direct numerical simulation of such flows, is gaining increasing popularity for simulating, e.g., dust transport, flows of nanofluids and grains in planetary rings. The main objective of the previous papers was to formally extend the impulse-based hard-sphere model, while suggestions for quantifications of the adhesive or cohesive interaction were made. This present paper gives an improved quantification of the adhesive and cohesive interactions for use in the extended hard-sphere model for cases where the surfaces of the colliding bodies are "dry," e.g., there is no liquid-bridge formation between the colliding bodies. This quantification is based on the Johnson-Kendall-Roberts (JKR) analysis of collision dynamics but includes, in addition, dissipative forces using a soft-sphere modeling technique. In this way the cohesive impulse, required for the hard-sphere model, is calculated together with other parameters, namely the collision duration and the restitution coefficient. Finally a dimensional analysis technique is applied to fit an analytical expression to the results for the cohesive impulse that can be used in the extended hard-sphere model. At the end of the paper we show some simulation results in order to illustrate the model.

  5. The influence of material hardness on liquid droplet impingement erosion

    Energy Technology Data Exchange (ETDEWEB)

    Fujisawa, Nobuyuki, E-mail: fujisawa@eng.niigata-u.ac.jp [Visualization Research Center, Niigata University, 8050, Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181 (Japan); Yamagata, Takayuki, E-mail: yamagata@eng.niigata-u.ac.jp [Visualization Research Center, Niigata University, 8050, Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181 (Japan); Takano, Shotaro; Saito, Kengo [Graduate School of Science and Technology, Niigata University, 8050, Ikarashi 2-Nocho, Nishi-ku, Niigata 950-2181 (Japan); Morita, Ryo; Fujiwara, Kazutoshi; Inada, Fumio [Central Research Institute of Electric Power Industry, 2-11-1, Iwatokita, Komae, Tokyo 201-8511 (Japan)

    2015-07-15

    Highlights: • Liquid droplet impingement erosion is studied for various metal materials. • Average power dependency on droplet velocity is found as 7. • Power dependency on Vickers hardness is found as −4.5. • An empirical formula is constructed for erosion rates of metal materials. • Predicted erosion rate is well correlated with experiment within a factor of 1.5. - Abstract: This paper describes the experimental study on the liquid droplet impingement erosion of metal materials to understand the influence of material hardness on the erosion rate. The experiment is carried out using a water spray jet apparatus with a condition of relatively thin liquid film thickness. The metal materials tested are pure aluminum, aluminum alloy, brass, mild steel, carbon steel and stainless steel. The liquid droplets considered are 30 ± 5 μm in volume average diameter of water, which is the same order of droplet diameter in the actual pipeline in nuclear/fossil power plants. In order to understand the influence of material hardness on the liquid droplet impingement erosion, the scanning electron microscope (SEM) observation on the eroded surface and the measurement of erosion rate are carried out in the terminal stage of erosion. The experimental results indicate that the erosion rates are expressed by the droplet velocity, volume flux, Vickers hardness and the liquid film thickness, which are fundamentals of the liquid droplet impingement erosion. The empirical formula shows that the power index for droplet velocity dependency is found to be 7 with a scattering from 5 to 9 depending on the materials, while the power index for Vickers hardness dependency is found as −4.5.

  6. Theoretical Hardness of Wurtzite-Structured Semiconductors

    Institute of Scientific and Technical Information of China (English)

    GUO Xiao-Ju; XU Bo; LIU Zhong-Yuan; YU Dong-Li; HE Ju-Long; GUO Li-Cong

    2008-01-01

    Vickers hardness calculations of eleven wurtzite-structured semiconductors are performed based on the microscopic hardness model All the parameters are obtained from first-principles calculations. There axe two types of chemical bonds in wurtzite-structured crystals. The overlap populations of the two types of chemical bonds in lonsdaleite are chosen as Pc for wurtzite structure. The calculated bond ionicity values of the wurtzite-structured semiconductors are in good agreement with the ionicities from the dielectric definition. When the hardness of wurtzite-structured crystal is higher than 20GPa, our calculated Vickers hardness is within 10% accuracy. Therefore, the hardness of novel wurtzite-structured crystal could be estimated from first-principles calculations.

  7. Influence of photoactivation method and mold for restoration on the Knoop hardness of resin composite restorations.

    Science.gov (United States)

    Brandt, William Cunha; Silva-Concilio, Lais Regiane; Neves, Ana Christina Claro; de Souza-Junior, Eduardo Jose Carvalho; Sinhoreti, Mario Alexandre Coelho

    2013-09-01

    The aim of this study was to evaluate in vitro the Knoop hardness in the top and bottom of composite photo activated by different methods when different mold materials were used. Z250 (3M ESPE) and XL2500 halogen unit (3M ESPE) were used. For hardness test, conical restorations were made in extracted bovine incisors (tooth mold) and also metal mold (approximately 2 mm top diameter × 1.5 mm bottom diameter × 2 mm in height). Different photoactivation methods were tested: high-intensity continuous (HIC), low-intensity continuous (LIC), soft-start, or pulse-delay (PD), with constant radiant exposure. Knoop readings were performed on top and bottom restoration surfaces. Data were submitted to two-way ANOVA and Tukey's test (p = 0.05). On the top, regardless of the mold used, no significant difference in the Knoop hardness (Knoop hardness number, in kilograms-force per square millimeter) was observed between the photoactivation methods. On the bottom surface, the photoactivation method HIC shows higher means of hardness than LIC when tooth and metal were used. Significant differences of hardness on the top and in the bottom were detected between tooth and metal. The photoactivation method LIC and the material mold can interfere in the hardness values of composite restorations.

  8. Skid resistance and surface roughness testing of historic stone surfaces: advantages and limitations

    Science.gov (United States)

    Török, Ákos

    2013-04-01

    Skid resistance tests are mostly applied for testing road surfaces and almost never applied for testing stones at cultural heritage sites. The present study focuses on the possibilities of using these techniques in assessing the surface roughness of paving stones at a historic site. Two different methods were used in a comparative way to evaluate the surface properties of various types of stones ranging from travertine to non-porous limestone and granite. The applied techniques included the use of SRT pendulum (Skid Resistance Tester) providing USRV values and a mobile equipment to analyze the surface properties (Floor Slide Control) by surface profiling and providing angle of friction. The main aims of tests were to understand the wearing of stone materials due to intense pedestrian use and to detect surface changes/surface roughness and slip resistance within few year periods. The measured loss in surface slip resistance (i.e. USRV values) was in the order of 20% for granites, while most limestones lost at least 40% in terms of USRV values. An opposite trend was detected for a porous travertine type, where the surface became rougher after years of use. The limitations of these techniques are also addressed in the paper. The tests have shown that the introduction of the use of these equipments in heritage studies provide useful information on the longevity of historic stone pavements that are open for public use.

  9. Hard carbon as anode material in lithium batteries: Synthesis and characterization

    Energy Technology Data Exchange (ETDEWEB)

    Baertsch, M.C.; Schmid, L.; Baiker, A.; Novak, P.

    2003-03-01

    Hard carbon is a possible alternative as negative electrode material for rechargeable lithium-ion batteries. A fast production of hard carbon can be reached if the curing time of the precursor is short. Due to the promising results from literature regarding epoxy resin as precursor we produced hard carbon from a commercially available fast-setting epoxy resin. The surface area and pore structure properties of the carbon powder were investigated with gas adsorption methods. The carbon particle size distribution was ana-lysed with a laser diffraction instrument. (author)

  10. Hard sphere crystal nucleation and growth near large spherical impurities

    Science.gov (United States)

    de Villeneuve, V. W. A.; Verboekend, D.; Dullens, R. P. A.; Aarts, D. G. A. L.; Kegel, W. K.; Lekkerkerker, H. N. W.

    2005-11-01

    We report how large spherical impurities affect the nucleation and growth of hard sphere colloidal crystals. Both the impurities and the colloids are fluorescently labelled polymethylmetacrylate particles and are dispersed in an optically and density matching solvent mixture. Crystal growth, initiated either at the impurity surface, or at the sample bottom, was studied by imaging sequences of two-dimensional xy-slices in the plane of the impurity's centre of mass with a laser scanning confocal microscope. At least two factors determine whether a large impurity can function as a seed for heterogeneous nucleation: timescales and impurity curvature. The curvature needs to be sufficiently low for crystal nuclei to form on the impurity surface. If bulk crystal growth has already approached the impurity, bulk growth is dominant over growth of crystallites on the impurity surface. Such surface crystallites eventually reorient to adapt to the overall bulk crystal symmetry.

  11. Aespoe Hard Rock Laboratory. Annual report 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-05-01

    The Aespoe Hard Rock Laboratory has been constructed as part of the preparations for the deep geological repository for spent nuclear fuel in Sweden. The surface and borehole investigations and the research work performed in parallel with construction have provided a thorough test of methods for investigation and evaluation of bedrock conditions for construction of a deep repository. The Tracer Retention Understanding Experiments are made to gain a better understanding of radionuclide retention in the rock and create confidence in the radionuclide transport models that are intended to be used in the licensing of a deep repository for spent fuel. The experimental results of the first tracer test with sorbing radioactive tracers have been obtained. These tests have been subject to blind predictions by the Aespoe Task Force on groundwater flow and transports of solutes. The manufacturing of the CHEMLAB probe was completed during 1996, and the first experiments were started early in 1997. During 1997 three experiments on diffusion in bentonite using {sup 57}Co, {sup 114}Cs,{sup 85}Sr, {sup 99}Tc, and {sup 131}I were conducted. The Prototype Repository Test is focused on testing and demonstrating repository system function. A full scale prototype including six deposition holes with canisters with electric heaters surrounded by highly compacted bentonite will be built and instrumented. The characterization of the rock mass in the area of the prototype repository is in progress. The objectives of the Demonstration of Repository Technology are to develop, test, and demonstrate methodology and equipment for encapsulation and deposition of spent nuclear fuel. The demonstration of handling and deposition will be made in a new drift. The Backfill and Plug Test includes tests of backfill materials and emplacement methods and a test of a full scale plug. The backfill and rock will be instrumented with about 230 transducers for measuring the thermo-hydro-mechanical processes. The

  12. Probing the evolution and morphology of hard carbon spheres

    Energy Technology Data Exchange (ETDEWEB)

    Pol, Vilas G.; Wen, Jianguo; Lau, Kah Chun; Callear, Samantha; Bowron, Daniel T.; Lin, Chi-Kai; Deshmukh, Sanket A.; Sankaranarayanan, Subramanian; Curtiss, Larry A.; David, William; Miller, Dean J.; Thackeray, Michael M.

    2014-03-01

    Monodispersed hard carbon spheres can be synthesized quickly and reproducibly by autogenic reactions of hydrocarbon precursors, notably polyethylene (including plastic waste), at high temperature and pressure. The carbon microparticles formed by this reaction have a unique spherical architecture, with a dominant internal nanometer layered motif, and they exhibit diamond-like hardness and electrochemical properties similar to graphite. In the present study, in-situ monitoring by X-ray diffraction along with electron microscopy, Raman spectroscopy, neutron pair-distribution function analysis, and computational modeling has been used to elucidate the morphology and evolution of the carbon spheres that form from the autogenic reaction of polyethylene at high temperature and pressure. A mechanism is proposed on how polyethylene evolves from a linear chain-based material to a layered carbon motif. Heating the spheres to 2400-2800 °C under inert conditions increases their graphitic character, particularly at the surface, which enhances their electrochemical and tribological properties.

  13. Fuzzy and Regression Modelling of Hard Milling Process

    Directory of Open Access Journals (Sweden)

    A. Tamilarasan

    2014-04-01

    Full Text Available The present study highlights the application of box-behnken design coupled with fuzzy and regression modeling approach for making expert system in hard milling process to improve the process performance with systematic reduction of production cost. The important input fields of work piece hardness, nose radius, feed per tooth, radial depth of cut and axial depth cut were considered. The cutting forces, work surface temperature and sound pressure level were identified as key index of machining outputs. The results indicate that the fuzzy logic and regression modeling technique can be effectively used for the prediction of desired responses with less average error variation. Predicted results were verified by experiments and shown the good potential characteristics of the developed system for automated machining environment.

  14. Influence of Hard Tool Coatings on Process of Stamping

    DEFF Research Database (Denmark)

    Zajec, Bostjan; Podgornik, Bojan; Bay, Niels;

    2007-01-01

    materials and possible hard coatings as alternative tool materials. For this purpose the blanking/punching process was first analyzed by a numerical model and based on the results four different tool materials and three hard coatings were included in the investigation and tested in a model test rig as well......Blanking/punching is a process which enables mass production of very demanding products, such as lamellas for electrical engines, generators and similar devices. Tool wear in the blanking/punching process has large influence on the product surface quality as well as on tool life. Improvement...... of tool life can be achieved by proper selection of tool materials and possible coatings. In mass production the tools are usually made of WC, which however, results in expensive tools and long time of delivery. The aim of the present investigation was to determine the influence of different tool...

  15. A computer simulation investigation into the stability of the AB2 superlattice in a binary hard sphere system

    NARCIS (Netherlands)

    Eldridge, M.D.; Madden, P.A.; Frenkel, D.

    1993-01-01

    The thermodynamic stability of the binary hard-sphere AB2 superlattice structure has been confirmed by means of computer simulations. This is consistent with the results of experimental studies of suspensions of hard-sphere colloidal particles. A fit of the Helmholtz free energy surface for the regi

  16. Modelling of nuclear explosions in hard rock sites

    Energy Technology Data Exchange (ETDEWEB)

    Brunish, W.M.; App, F.N.

    1993-05-01

    This study represents part of a larger effort to systematically model the effects of differing source region properties on ground motion from underground nuclear explosions at the Nevada Test Site. In previous work by the authors the primary emphasis was on alluvium and both saturated and unsaturated tuff. We have attempted to model events on Pahute Mesa, where either the working point medium, or some of the layers above the working point, or both, are hard rock. The complex layering at these sites, however, has prevented us from drawing unambiguous conclusions about modelling hard rock. In order to learn more about the response of hard rock to underground nuclear explosions, we have attempted to model the PILEDRIVER event. PILEDRIVER was fired on June 2, 1966 in the granite stock of Area 15 at the Nevada Test Site. The working point was at a depth of 462.7 m and the yield was determined to be 61 kt. Numerous surface, sub-surface and free-field measurements were made and analyzed by SRI. An attempt was made to determine the contribution of spall to the teleseismic signal, but proved unsuccessful because most of the data from below-shot-level gauges was lost. Nonetheless, there is quite a bit of good quality data from a variety of locations. We have been able to obtain relatively good agreement with the experimental PILEDRIVER waveforms. In order to do so, we had to model the granodiorite as being considerably weaker than ``good quality`` granite, and it had to undergo considerable weakening due to shock damage as well. In addition, the near-surface layers had to be modeled as being weak and compressible and as have a much lower sound speed than the material at depth. The is consistent with a fractured and jointed material at depth, and a weathered material near the surface.

  17. Modelling of nuclear explosions in hard rock sites

    Energy Technology Data Exchange (ETDEWEB)

    Brunish, W.M.; App, F.N.

    1993-01-01

    This study represents part of a larger effort to systematically model the effects of differing source region properties on ground motion from underground nuclear explosions at the Nevada Test Site. In previous work by the authors the primary emphasis was on alluvium and both saturated and unsaturated tuff. We have attempted to model events on Pahute Mesa, where either the working point medium, or some of the layers above the working point, or both, are hard rock. The complex layering at these sites, however, has prevented us from drawing unambiguous conclusions about modelling hard rock. In order to learn more about the response of hard rock to underground nuclear explosions, we have attempted to model the PILEDRIVER event. PILEDRIVER was fired on June 2, 1966 in the granite stock of Area 15 at the Nevada Test Site. The working point was at a depth of 462.7 m and the yield was determined to be 61 kt. Numerous surface, sub-surface and free-field measurements were made and analyzed by SRI. An attempt was made to determine the contribution of spall to the teleseismic signal, but proved unsuccessful because most of the data from below-shot-level gauges was lost. Nonetheless, there is quite a bit of good quality data from a variety of locations. We have been able to obtain relatively good agreement with the experimental PILEDRIVER waveforms. In order to do so, we had to model the granodiorite as being considerably weaker than good quality'' granite, and it had to undergo considerable weakening due to shock damage as well. In addition, the near-surface layers had to be modeled as being weak and compressible and as have a much lower sound speed than the material at depth. The is consistent with a fractured and jointed material at depth, and a weathered material near the surface.

  18. Experimental Investigation of White Layer formation in Hard Turning

    Science.gov (United States)

    Umbrello, D.; Rotella, G.; Crea, F.

    2011-05-01

    Hard turning with super hard cutting tools, like PCBN or Ceramics inserts, represents an interesting advance in the manufacturing industry, regarding the finishing of hardened steels. This innovative machining technique is considered an attractive alternative to traditional finish grinding operations because of the high flexibility, the ability to achieve higher metal removal rates, the possibility to operate without the use of coolants, and the capability to achieve comparable workpiece quality. However, the surface integrity effects of hard machining need to be taken into account due to their influence on the life of machined components. In particular, the formation of a usually undesirable white layer at the surface needs further investigation. Three different mechanisms have been proposed as main responsible of the white layer genesis: (i) microstructural phase transformation due to a rapid heating and quenching, (ii) severe plastic deformation resulting in a homogenous structure and/or a very fine grain size microstructure; (iii) surface reaction with the environment. In this research, an experimental campaign was carried out and several experimental techniques were used in order to analyzed the machined surface and to understand which of the above mentioned theories is the main cause of the white layer formation when AISI 52100 hardened steel is machined by PCBN inserts. In particular, the topography characterization has obtained by means of optical and scanning electron microscope (SEM) while microstructural phase composition and chemical characterization have been respectively detected using X-ray Diffraction (XRD) and Energy-dispersive X-ray spectroscopy (EDS) techniques. The results prove that the white layer is the result of microstructural alteration, i.e. the generation of a martensitic structure.

  19. Effects of the ratio of hardness to Young's modulus on the friction and wear behavior of bilayer coatings

    Science.gov (United States)

    Ni, Wangyang; Cheng, Yang-Tse; Lukitsch, Michael J.; Weiner, Anita M.; Lev, Lenoid C.; Grummon, David S.

    2004-11-01

    We present a study of the effects of the ratio of hardness to Young's modulus on the friction and wear behavior of layered composite coatings. Layered coating structures with the same surface coating but different interlayers were prepared by physical vapor deposition. We found that the ratio of hardness to Young's modulus plays an important role in determining the friction coefficient and wear resistance of layered composite coatings. A low friction coefficient and high wear resistance can be achieved in structures with high ratio of hardness to Young's modulus and moderately high hardness.

  20. 分散聚合法合成含有环氧基的无孔超顺磁性微球及其表征%Preparation and Characterization of Non-porous Superparamagnetic Microspheres with Epoxy Groups by Dispersion Polymerization

    Institute of Scientific and Technical Information of China (English)

    马志亚; 官月平; 刘先桥; 刘会洲

    2005-01-01

    Non-porous superparamagnetic polymer microspheres with epoxy groups were prepared by dispersion polymerization of glycidyl methacrylate (GMA) in the presence of magnetic iron oxide (Fe3 O4) nanoparticles coated with oleic acid. The polymerization was carried out in the ethanol/water medium using polyvinylpyrrolidone (PVP)and 2,2'-azobisisobutyronitrile (AIBN) as stabilizer and initiator, respectively. The magnetic microspheres obtained were characterized with scanning electron microscopy (SEM), vibrating sample magnetometry (VSM) and Fourier transform infrared spectroscopy (FTIR). The results showed that the magnetic microspheres had an average size of have extensive potential uses in magnetic bioseparation and biotechnology.

  1. Fundamentals and hard-switching converters

    CERN Document Server

    Ioinovici, Adrian

    2013-01-01

    Volume 1 Fundamentals and Hard-switching Converters introduces the key challenges in power electronics from basic components to operation principles and presents classical hard- and soft-switching DC to DC converters, rectifiers and inverters. At a more advanced level, it provides comprehensive analysis of DC and AC models comparing the available approaches for their derivation and results. A full treatment of DC to DC hard-switching converters is given, from fundamentals to modern industrial solutions and practical engineering insight. The author elucidates various contradictions and misunderstandings in the literature, for example, in the treatment of the discontinuous conduction operation or in deriving AC small-signal models of converters.

  2. IBM 3390 Hard Disk Platter

    CERN Multimedia

    1991-01-01

    The 3390 disks rotated faster than those in the previous model 3380. Faster disk rotation reduced rotational delay (ie. the time required for the correct area of the disk surface to move to the point where data could be read or written). In the 3390's initial models, the average rotational delay was reduced to 7.1 milliseconds from 8.3 milliseconds for the 3380 family.

  3. A CONTINUUM HARD-SPHERE MODEL OF PROTEIN ADSORPTION.

    Science.gov (United States)

    Finch, Craig; Clarke, Thomas; Hickman, James J

    2013-07-01

    Protein adsorption plays a significant role in biological phenomena such as cell-surface interactions and the coagulation of blood. Two-dimensional random sequential adsorption (RSA) models are widely used to model the adsorption of proteins on solid surfaces. Continuum equations have been developed so that the results of RSA simulations can be used to predict the kinetics of adsorption. Recently, Brownian dynamics simulations have become popular for modeling protein adsorption. In this work a continuum model was developed to allow the results from a Brownian dynamics simulation to be used as the boundary condition in a computational fluid dynamics (CFD) simulation. Brownian dynamics simulations were used to model the diffusive transport of hard-sphere particles in a liquid and the adsorption of the particles onto a solid surface. The configuration of the adsorbed particles was analyzed to quantify the chemical potential near the surface, which was found to be a function of the distance from the surface and the fractional surface coverage. The near-surface chemical potential was used to derive a continuum model of adsorption that incorporates the results from the Brownian dynamics simulations. The equations of the continuum model were discretized and coupled to a CFD simulation of diffusive transport to the surface. The kinetics of adsorption predicted by the continuum model closely matched the results from the Brownian dynamics simulation. This new model allows the results from mesoscale simulations to be incorporated into micro- or macro-scale CFD transport simulations of protein adsorption in practical devices.

  4. Analytic studies of the hard dumbell fluid

    Science.gov (United States)

    Morriss, G. P.; Cummings, P. T.

    A closed form analytic theory for the structure of the hard dumbell fluid is introduced and evaluated. It is found to be comparable in accuracy to the reference interaction site approximation (RISA) of Chandler and Andersen.

  5. Why Are Drugs So Hard to Quit?

    Medline Plus

    Full Text Available ... it free Find out why Close Why Are Drugs So Hard to Quit? National Institute on Drug Abuse (NIDA/NIH) Loading... Unsubscribe from National Institute on Drug Abuse (NIDA/NIH)? Cancel Unsubscribe Working... Subscribe Subscribed ...

  6. Why Are Drugs So Hard to Quit?

    Medline Plus

    Full Text Available ... navigation Sign in Search Loading... Close Yeah, keep it Undo Close This video is unavailable. Watch Queue ... changes the signals in your brain and makes it hard to feel OK without the drug. This ...

  7. Radiation Hard High Performance Optoelectronic Devices Project

    Data.gov (United States)

    National Aeronautics and Space Administration — High-performance, radiation-hard, widely-tunable integrated laser/modulator chip and large-area avalanche photodetectors (APDs) are key components of optical...

  8. Why Are Drugs So Hard to Quit?

    Medline Plus

    Full Text Available ... Feb 7, 2012 Quitting drugs is hard because addiction is a brain disease. Your brain is like ... out signals to direct your actions and choices. Addiction changes the signals in your brain and makes ...

  9. Event Driven Langevin simulations of Hard Spheres

    CERN Document Server

    Scala, Antonio

    2011-01-01

    The blossoming of interest in colloids and nano-particles has given renewed impulse to the study of hard-body systems. In particular, hard spheres have become a real test system for theories and experiments. It is therefore necessary to study the complex dynamics of such systems in presence of a solvent; disregarding hydrodynamic interactions, the simplest model is the Langevin equation. Unfortunately, standard algorithms for the numerical integration of the Langevin equation require that interactions are slowly varying during an integration timestep. This in not the case for hard-body systems, where there is no clearcut between the correlation time of the noise and the timescale of the interactions. Starting first from a splitting of the Fokker-Plank operator associated with the Langevin dynamics, and then from an approximation of the two-body Green's function, we introduce and test two new algorithms for the simulation of the Langevin dynamics of hard-spheres.

  10. Hard target LIDAR calibration for SO2

    CSIR Research Space (South Africa)

    Du Plessis, A

    2006-01-01

    Full Text Available Presentation on hard target LIDAR calibration for SO2. This project aimed at measuring the concentration of the atmospheric pollutants such as gases and mobile laser system for remote detection...

  11. Why Are Drugs So Hard to Quit?

    Medline Plus

    Full Text Available ... later? Sign in to add this video to a playlist. Sign in Share More Report Need to ... 2012 Quitting drugs is hard because addiction is a brain disease. Your brain is like a control ...

  12. Optical waveguides in hard crystalline materials

    NARCIS (Netherlands)

    Pollnau, M.

    2005-01-01

    The recent results of our research group and collaborators in the field of fabrication, characterization, and applications of optical waveguides in hard crystalline materials, specifically in sapphire and Ti:sapphire, are reviewed.

  13. Why Is It So Hard to Quit?

    Science.gov (United States)

    ... to quit? It’s hard to tackle the physical addiction to nicotine . Cigarettes contain nicotine, a highly addictive ... a support group can give you comfort and positive reinforcement. Cut back on caffeine . Caffeine is a ...

  14. Hardness and Methods to Solve CLIQUE

    Institute of Scientific and Technical Information of China (English)

    ZHU Daming; LUAN Junfeng; MA Shaohan

    2001-01-01

    The paper briefly reviews NP-hard optimization problems and their inapproximability. The hardness of solving CLIQUE problem is specifically discussed. A dynamic-programming algorithm and its improved version for CLIQUE are reviewed and some additional analysis is presented. The analysis implies that the improved algorithm, HEWN (hierarchical edge-weighted network), only provides a heuristic or useful method, but cannot be called a polynomial algorithm.

  15. The Chiral Dipolar Hard Sphere Model.

    OpenAIRE

    Mazars, Martial

    2009-01-01

    Abstract A simple molecular model of chiral molecules is presented in this paper : the chiral dipolar hard sphere model. The discriminatory interaction between enantiomers is represented by electrostatic (or magnetic) dipoles-dipoles interactions : short ranged steric repulsion are represented by hard sphere potential and, in each molecule, two point dipoles are located inside the sphere. The model is described in detail and some of its elementary properties are given ; in particul...

  16. Point defects in hard-sphere crystals

    OpenAIRE

    Pronk, S.; Frenkel, D.

    2001-01-01

    We report numerical calculations of the concentration of interstitials in hard-sphere crystals. We find that, in a three-dimensional fcc hard-sphere crystal at the melting point, the concentration of interstitials is 2 * 10^-8. This is some three orders of magnitude lower than the concentration of vacancies. A simple, analytical estimate yields a value that is in fair agreement with the numerical results.

  17. Process for hardening the surface of polymers

    Science.gov (United States)

    Mansur, Louis K.; Lee, Eal H.

    1992-01-01

    Hard surfaced polymers and the method for making them is generally described. Polymers are subjected to simultaneous multiple ion beam bombardment, that results in a hardening of the surface and improved wear resistance.

  18. CO II laser free-form processing of hard tissue

    Science.gov (United States)

    Werner, Martin; Klasing, Manfred; Ivanenko, Mikhail; Harbecke, Daniela; Steigerwald, Hendrik; Hering, Peter

    2007-07-01

    Drilling and surface processing of bone and tooth tissue belongs to standard medical procedures (bores and embeddings for implants, trepanation etc.). Small circular bores can be generally quickly produced with mechanical drills. However problems arise at angled drilling, the need to execute drilling procedures without damaging of sensitive soft tissue structures underneath the bone or the attempt to mill small non-circular cavities in hard tissue with high precision. We present investigations on laser hard tissue "milling", which can be advantageous for solving these problems. The processing of bone is done with a CO II laser (10.6 μm) with pulse durations of 50 - 100 μs, combined with a PC-controlled fast galvanic laser beam scanner and a fine water-spray, which helps keeping the ablation process effective and without thermal side-effects. Laser "milling" of non-circular cavities with 1 - 4 mm width and about 10 mm depth can be especially interesting for dental implantology. In ex-vivo investigations we found conditions for fast laser processing of these cavities without thermal damage and with minimised tapering. It included the exploration of different filling patterns (concentric rings, crosshatch, parallel lines, etc.), definition of maximal pulse duration, repetition rate and laser power, and optimal water spray position. The optimised results give evidence for the applicability of pulsed CO II lasers for biologically tolerable effective processing of deep cavities in hard tissue.

  19. Estimates and Rigorous Bounds on Pore-Fluid Enhanced Shear Modulus in Poroelastic Media with Hard and Soft Anisotropy

    Energy Technology Data Exchange (ETDEWEB)

    Berryman, J G

    2005-01-24

    A general analysis of poroelasticity for hexagonal, tetragonal, and cubic symmetry shows that four eigenvectors are pure shear modes with no coupling to the pore-fluid mechanics. The remaining two eigenvectors are linear combinations of pure compression and uniaxial shear, both of which are coupled to the fluid mechanics. The analysis proceeds by first reducing the problem to a 2 x 2 system. The poroelastic system including both anisotropy in the solid elastic frame (i.e., with ''hard anisotropy''), and also anisotropy of the poroelastic coefficients (''soft anisotropy'') is then studied in some detail. In the presence of anisotropy and spatial heterogeneity, mechanics of the pore fluid produces shear dependence on fluid bulk modulus in the overall poroelastic system. This effect is always present (though sometimes small in magnitude) in the systems studied, and can be comparatively large (up to a maximum increase of about 20 per cent) in some porous media--including porous glass and Schuler-Cotton Valley sandstone. General conclusions about poroelastic shear behavior are also related to some recently derived product formulas that determine overall shear response of these systems. Another method is also introduced based on rigorous Hashin-Shtrikman-style bounds for nonporous random polycrystals, followed by related self-consistent estimates of mineral constants for polycrystals. Then, another self-consistent estimation method is formulated for the porous case, and used to estimate drained and undrained effective constants. These estimates are compared and contrasted with the results of the first method and a consistent picture of the overall behavior is found in three computed examples for polycrystals of grains having tetragonal symmetry.

  20. Hard Horn Design for Quasi-Optical Power Combining Using Solid-State Power Amplifiers

    Science.gov (United States)

    Pickens, W. S.; Epp, L. W.; Hoppe, D. J.

    2004-02-01

    In recent years, there has been significant interest in the use of corrugated, periodic structures to control the wave impedance of a given surface. It has been shown [1] that a quasi-transverse-electromagnetic (TEM) wave can be excited in a waveguide by correctly choosing the impedance at the guide wall. This correctly chosen impedance is referred to as the hard boundary condition. We have taken advantage of this property of the so-called "hard" guide to attempt to create a spatial power combiner/splitter that couples to an array of microstrip patch antennas feeding a bank of monolithic microwave integrated circuit (MMIC) power amplifiers. The hard horn described here employs longitudinal corrugations filled with a low-loss dielectric material along the vertical walls to achieve the hard boundary condition. We believe the use of dielectric-filled corrugations will improve the insertion loss performance over that of a hard guide using dielectric slabs bonded to the guide wall. Additionally, the horn is tapered to its maximum aperture along a cosine curve in order to improve return loss performance. Included in this article is a discussion of the fabrication process of prototype hard horns, measurements of a hard horn prototype, and preliminary modal analysis results.

  1. Hard and Soft Multilayered SiCN Nanocoatings with High Hardness and Toughness

    Directory of Open Access Journals (Sweden)

    S. K. Mishra

    2013-01-01

    Full Text Available Alternate hard and soft layers increase deformation accommodation as thin hard layers slide relative to each other due to shear deformation of low modulus layers. However, the processing of such multilayers is challenging. In the present paper the alternating soft and hard multilayered SiCN coating deposited by magnetron sputtering has been studied and presented. A hardness and modulus of 37 GPa and 317 GPa with elastic recovery of 62% are achieved by alternate hard and soft layer of Si–C–N by magnetron sputtering. The trilayer films sustained even 2000 gf under indentation without failure though substrate plastically deformed. The fracture toughness value KIC was measured to be 9.5–10 MPa m1/2, significantly higher than many reported hard coatings.

  2. Does hard insertion and space improve shock absorption ability of mouthguard?

    Science.gov (United States)

    Takeda, Tomotaka; Ishigami, Keiichi; Handa, Jun; Naitoh, Kaoru; Kurokawa, Katsuhide; Shibusawa, Mami; Nakajima, Kazunori; Kawamura, Shintaro

    2006-04-01

    Mouthguards are expected to reduce sports-related orofacial injuries. Numerous studies have been conduced to improve the shock absorption ability of mouthguards using air cells, sorbothane, metal wire, or hard material insertion. Most of these were shown to be effective; however, the result of each study has not been applied to clinical use. The aim of this study was to develop mouthguards that have sufficient prevention ability and ease of clinical application with focus on a hard insertion and space. Ethylene vinyl acetate (EVA) mouthguard blank used was Drufosoft and the acrylic resin was Biolon (Dreve-Dentamid GMBH, Unna, Germany). Three types of mouthguard samples tested were constructed by means of a Dreve Drufomat (Type SO, Dreve-Dentamid) air pressure machine: the first was a conventional laminated type of EVA mouthguard material; the second was a three layer type with acrylic resin inner layer (hard-insertion); the third was the same as the second but with space that does not come into contact with tooth surfaces (hard + space). As a control, without any mouthguard condition (NOMG) was measured. A pendulum type impact testing machine with interchangeable impact object (steel ball and baseball) and dental study model (D17FE-NC.7PS, Nissin, Tokyo, Japan) with the strain gages (KFG-1-120-D171-11N30C2: Kyowa, Tokyo, Japan) applied to teeth and the accelerometer to the dentition (AS-A YG-2768 100G, Kyowa) were used to measure transmitted forces. Statistical analysis (anova, P shock absorption ability of about 40% was shown with conventional EVA and hard-insertion and about 50% with hard + space. In a baseball that was softer compared with steel ball, a decrease rate is smaller, reduction (EVA = approximately 4%, hard-insertion = approximately 12%, hard + space = approximately 25%) was admitted in the similar order. A significant difference was found with all the combinations except for between EVA and hard-insertion with steel ball (Tukey test). About

  3. Hard-X-Ray-Induced Multistep Ultrafast Dissociation

    Science.gov (United States)

    Travnikova, Oksana; Marchenko, Tatiana; Goldsztejn, Gildas; Jänkälä, Kari; Sisourat, Nicolas; Carniato, Stéphane; Guillemin, Renaud; Journel, Loïc; Céolin, Denis; Püttner, Ralph; Iwayama, Hiroshi; Shigemasa, Eiji; Piancastelli, Maria Novella; Simon, Marc

    2016-05-01

    Creation of deep core holes with very short (τ ≤1 fs ) lifetimes triggers a chain of relaxation events leading to extensive nuclear dynamics on a few-femtosecond time scale. Here we demonstrate a general multistep ultrafast dissociation on an example of HCl following Cl 1 s →σ* excitation. Intermediate states with one or multiple holes in the shallower core electron shells are generated in the course of the decay cascades. The repulsive character and large gradients of the potential energy surfaces of these intermediates enable ultrafast fragmentation after the absorption of a hard x-ray photon.

  4. Radiation-hard/high-speed parallel optical links

    Energy Technology Data Exchange (ETDEWEB)

    Gan, K.K., E-mail: gan@mps.ohio-state.edu [Department of Physics, The Ohio State University, Columbus, OH 43210 (United States); Buchholz, P.; Heidbrink, S. [Fachbereich Physik, Universität Siegen, Siegen (Germany); Kagan, H.P.; Kass, R.D.; Moore, J.; Smith, D.S. [Department of Physics, The Ohio State University, Columbus, OH 43210 (United States); Vogt, M.; Ziolkowski, M. [Fachbereich Physik, Universität Siegen, Siegen (Germany)

    2016-09-21

    We have designed and fabricated a compact parallel optical engine for transmitting data at 5 Gb/s. The device consists of a 4-channel ASIC driving a VCSEL (Vertical Cavity Surface Emitting Laser) array in an optical package. The ASIC is designed using only core transistors in a 65 nm CMOS process to enhance the radiation-hardness. The ASIC contains an 8-bit DAC to control the bias and modulation currents of the individual channels in the VCSEL array. The performance of the optical engine up at 5 Gb/s is satisfactory.

  5. Radiation-hard/high-speed parallel optical links

    Science.gov (United States)

    Gan, K. K.; Buchholz, P.; Heidbrink, S.; Kagan, H. P.; Kass, R. D.; Moore, J.; Smith, D. S.; Vogt, M.; Ziolkowski, M.

    2016-09-01

    We have designed and fabricated a compact parallel optical engine for transmitting data at 5 Gb/s. The device consists of a 4-channel ASIC driving a VCSEL (Vertical Cavity Surface Emitting Laser) array in an optical package. The ASIC is designed using only core transistors in a 65 nm CMOS process to enhance the radiation-hardness. The ASIC contains an 8-bit DAC to control the bias and modulation currents of the individual channels in the VCSEL array. The performance of the optical engine up at 5 Gb/s is satisfactory.

  6. Developing and Studying the Methods of Hard-Facing with Heat-Resisting High-Hardness Steels

    Science.gov (United States)

    Malushin, N. N.; Kovalev, A. P.; Valuev, D. V.; Shats, E. A.; Borovikov, I. F.

    2016-08-01

    The authors develop the methods of hard-facing of mining-metallurgic equipment parts with heat-resisting high-hardness steels on the base of plasma-jet hard-facing in the shielding-alloying nitrogen atmosphere.

  7. Rubber friction on (apparently) smooth lubricated surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Mofidi, M; Prakash, B [Division of Machine Elements, Luleaa University of Technology, Luleaa SE-97187 (Sweden); Persson, B N J [IFF, FZ-Juelich, 52425 Juelich (Germany); Albohr, O [Pirelli Deutschland AG, 64733 Hoechst/Odenwald, Postfach 1120 (Germany)

    2008-02-27

    We study rubber sliding friction on hard lubricated surfaces. We show that even if the hard surface appears smooth to the naked eye, it may exhibit short-wavelength roughness, which may make the dominant contribution to rubber friction. That is, the observed sliding friction is mainly due to the viscoelastic deformations of the rubber by the counterface surface asperities. The results presented are of great importance for rubber sealing and other rubber applications involving (apparently) smooth surfaces.

  8. Rubber friction on (apparently) smooth lubricated surfaces

    Science.gov (United States)

    Mofidi, M.; Prakash, B.; Persson, B. N. J.; Albohr, O.

    2008-02-01

    We study rubber sliding friction on hard lubricated surfaces. We show that even if the hard surface appears smooth to the naked eye, it may exhibit short-wavelength roughness, which may make the dominant contribution to rubber friction. That is, the observed sliding friction is mainly due to the viscoelastic deformations of the rubber by the counterface surface asperities. The results presented are of great importance for rubber sealing and other rubber applications involving (apparently) smooth surfaces.

  9. Water hardness reduces the accumulation and toxicity of uranium in a freshwater macrophyte (Ceratophyllum demersum)

    Energy Technology Data Exchange (ETDEWEB)

    Markich, Scott J., E-mail: smarkich@optusnet.com.au

    2013-01-15

    There is a lack of good quality data and mechanistic understanding on the effects of true water hardness (calcium (Ca) and magnesium (Mg)) on the bioavailability and toxicity of uranium (U) to freshwater biota. This study determined the effect of true water hardness (20, 75, 150, 275 and 400 mg CaCO{sub 3} L{sup −1}) on the cell surface binding affinity (log K), accumulation and toxicity (growth inhibition) of U in a submerged, rootless, macrophyte (Ceratophyllum demersum) in a synthetic freshwater with constant alkalinity (13 mg CaCO{sub 3} L{sup −1}) and pH (6.2) over 7 days. A 20-fold increase in water hardness resulted in a 4-fold decrease in U toxicity (median effect concentration (EC50) = 134 μg L{sup −1} U at 20 mg CaCO{sub 3} L{sup −1} hardness, increasing to 547 μg L{sup −1} U at 400 mg CaCO{sub 3} L{sup −1} hardness), cell surface binding affinity (log K = 6.25 at 20 mg CaCO{sub 3} L{sup −1} hardness, decreasing to log K = 5.64 at 400 mg CaCO{sub 3} L{sup −1} hardness) and accumulation (the concentration factor decreased from 63 at 20 mg CaCO{sub 3} L{sup −1} hardness to 15 at 400 mg CaCO{sub 3} L{sup −1} hardness) of U. Calcium provided a 4-fold greater protective effect against U accumulation and toxicity compared to Mg. Speciation calculations indicated negligible differences in the percentages of key U species (UO{sub 2}{sup 2+}, UO{sub 2}OH{sup +}, UO{sub 2}(OH){sub 2}) over the range of water hardness tested. The inhibition of U binding at the cell surface, and subsequent uptake, by C. demersum, with increasing Ca and/or Mg concentration, may be explained in terms of (i) competition between Ca{sup 2+}/Mg{sup 2+} and UO{sub 2}{sup 2+} (and/or UO{sub 2}OH{sup +}) for physiologically active sites at the cell surface, and/or (ii) reduced negative charge (electrical potential) at the cell surface, resulting in a decrease in the activity of UO{sub 2}{sup 2+} (and/or UO{sub 2}OH{sup +}) at the plant/water interface (boundary layer

  10. Numerical simulation for rheological characteristics of alternating distribution of soft and hard rock layers

    Institute of Scientific and Technical Information of China (English)

    HAN Bing; WANG Zhi-yin; DING Xiu-li; XU Ping

    2006-01-01

    The difficulty of selecting appropriate rheological model and parameters for the alternating distribution of soft and hard rock layers was often encountered due to the unhomogeneity, discontinuity and anisotropy of rock mass. The Burgers and generalized Kelvin models were applied to the soft and hard rock respectively and the rheological parameters were obtained based on the method of optimum separation. By using the simulated code FLAC3D, the stability of surrounding rocks of a certain underground plant was analyzed. The effect of surface load and weakening the parameters intensity of argillaceous and bioclastic interlayers between soft and hard rock on rheological behavior of layer composite rock mass was investigated. The results indicate that the rheological characteristics of soft and hard rock layer in composite rock mass can be described well with above two rheological models.

  11. [The hardness of the traumatic object and the extent of injury (as exemplified by head injuries)].

    Science.gov (United States)

    Shadymov, A B; Kazymov, M A

    2014-01-01

    The objective of the present work was to study the influence of the surface hardness of a traumatic agent on the extent and character of the injury to the soft and bone tissues of the cranial vault associated with various forms of injurious exposure. The authors evaluated forensic medical significance of the hardness as one of the most important properties of the major injurious agents involved in the formation of skull fractures and soft tissue ruptures under effect of an impact action or compression. The objects differing in the hardness of the contact element (striking pin) were studied in comparison with the hardness of the bone tissue. The extent and morphological features of the injuries to the bones and soft tissues in different parts of the skull were compared with reference to deformation and strength characteristics developing in response to a blow and compression.

  12. Thermodynamic and hydrodynamic interaction in concentrated microgel suspensions: Hard or soft sphere behavior?

    Science.gov (United States)

    Eckert, Thomas; Richtering, Walter

    2008-09-28

    The colloidal phase behavior, structure factors, short-time collective diffusion coefficients, and hydrodynamic interactions of concentrated poly(N-isopropylacryamide) (PNiPAM) microgels in dimethylformamide suspensions were measured with simultaneous static and dynamic three-dimensional cross-correlated light scattering. The data are interpreted through comparison with hard sphere theory. The fluid-crystal transition and the static structure factors can be described consistently by the hard sphere approximation. On the other hand, collective diffusion and hydrodynamic interaction cannot be described satisfactorily by the hard sphere model. The microgel structure is different from hard spheres, as the cross-link density decreases with the distance from the particle center leading to a "fuzzy" particle surface with dangling polymer chains. These seem to affect the hydrodynamic interaction much more as compared to direct thermodynamic interaction.

  13. INVESTIGATION OF MACHINABILITY IN Co AND Cr CONTAINING HARD MATERIALS HEATED BY PLASMA ARC

    Directory of Open Access Journals (Sweden)

    Halis Çelik

    1996-02-01

    Full Text Available Turning soft materials is not a problem in these days. But machinability of hard materials have been necessary. A lot of research has been done on machinability of difficult-to-cut materials. The aim of the present study is toinvestigate the machinability of three of hard materials after heating and softening. In this study for machining difficult-to-cut materials, different heating processes were applied and for heating, lately developed plasma heating method was used. To cut the hard material heated by plasma arc, tungsten carbide cutting tool was used. In the study, three different hard materials have been used. These were ferritic steel with 14 % Cr, Ti added cast iron, 8.5 % Cr cast steel and Co-Cr-W alloyed steel which is called stellite 6 and used in the textile industry andat power stations. In this study cutting forces, wear of cutting tool and surface roughness were investigated.

  14. Nitriding of Hard Fe Electrodeposition and Its Effects on Wear Resistance

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Nitriding is employed for the hard Fe electrodeposition toproduce a hard-facing and antiwear coating. It only takes 1 h for the hard Fe coating, which is much shorter than nitriding the Fe and steel. The results showed that the nitriding can increase the microhardness, wear resistance of the coating, as well as the bonding strength of the coating with the substrate. Additionally it can eliminate the brittleness, turn the internal stress of the coating from tension to compression.The wear resistance of the nitrided Fe coating is 4.6 times as high as that of Cr coating. It is simple and economic to combine hard Fe electroplating and nitriding, which is a good technology of the tribological surface modification.

  15. Spatial Mapping and Quantification of Soft and Hard Protein Coronas at Silver Nanocubes

    DEFF Research Database (Denmark)

    Miclaus, Teodora; Bochenkov, Vladimir; Ogaki, Ryosuke;

    2014-01-01

    Protein coronas around silver nanocubes were quantified in serum-containing media using localized surface plasmon resonances. Both soft and hard coronas showed exposure-time and concentration-dependent changes in protein surface density with time-dependent hardening. We observed spatially dependent...... kinetics of the corona-formation at cube edges/corners versus facets at short incubation times, where the polymer stabilization agent delayed corona hardening. The soft corona contained more protein than the hard corona at all time-points (8-fold difference with 10% serum conditions)....

  16. Guidance to Companies on Referring to Registered Disinfectant Products that Meet the CDC Criteria for Use Against the Ebola Virus

    Science.gov (United States)

    There are no EPA-registered products with label claims against the Ebola virus, but enveloped viruses such as Ebola are susceptible to many hospital disinfectants used to disinfect hard, non-porous surfaces. CDC guidance addresses use of such products.

  17. Thermodynamic stability in elastic systems: Hard spheres embedded in a finite spherical elastic solid.

    Science.gov (United States)

    Solano-Altamirano, J M; Goldman, Saul

    2015-12-01

    We determined the total system elastic Helmholtz free energy, under the constraints of constant temperature and volume, for systems comprised of one or more perfectly bonded hard spherical inclusions (i.e. "hard spheres") embedded in a finite spherical elastic solid. Dirichlet boundary conditions were applied both at the surface(s) of the hard spheres, and at the outer surface of the elastic solid. The boundary conditions at the surface of the spheres were used to describe the rigid displacements of the spheres, relative to their initial location(s) in the unstressed initial state. These displacements, together with the initial positions, provided the final shape of the strained elastic solid. The boundary conditions at the outer surface of the elastic medium were used to ensure constancy of the system volume. We determined the strain and stress tensors numerically, using a method that combines the Neuber-Papkovich spherical harmonic decomposition, the Schwartz alternating method, and Least-squares for determining the spherical harmonic expansion coefficients. The total system elastic Helmholtz free energy was determined by numerically integrating the elastic Helmholtz free energy density over the volume of the elastic solid, either by a quadrature, or a Monte Carlo method, or both. Depending on the initial position of the hard sphere(s) (or equivalently, the shape of the un-deformed stress-free elastic solid), and the displacements, either stationary or non-stationary Helmholtz free energy minima were found. The non-stationary minima, which involved the hard spheres nearly in contact with one another, corresponded to lower Helmholtz free energies, than did the stationary minima, for which the hard spheres were further away from one another.

  18. Dry vs. Cryogenic Orthogonal Hard Machining: an Experimental Investigation

    Science.gov (United States)

    Umbrello, D.; Caruso, S.; Di Renzo, S.; Jayal, A. D.; Dillon, O. W.; Jawahir, I. S.

    2011-05-01

    Friction, and consequently heat generation in the cutting zone, significantly affects the tool life, surface integrity and dimensional accuracy, apart from other machining results. Application of a coolant in a cutting process can increase tool life and dimensional accuracy, decrease heat generation, and consequently cutting temperatures, reduce surface roughness and the amount of energy consumed in cutting process, and thus improve the productivity. Furthermore, coolant application also affects the surface microstructural alterations (i.e., white and dark layers) due to a machining operation, which have a significant influence on product performance and life. This paper presents the results of an experimental investigation to determine the effects of cryogenic coolant application on tool wear, cutting forces and machined surface alterations during orthogonal machining of hardened AISI 52100 bearing steel (54±1 HRC). Experiments were performed for dry and cryogenic cutting conditions using chamfered PCBN tool inserts at varying cutting conditions (cutting speed and feed rate). For cryogenic cutting conditions the fluid was applied in the form of a liquid nitrogen jet directed on the three shear cutting zones. Cutting forces, tool wear, cutting temperatures, surface hardness modifications and microstructure alterations were studied in order to evaluate the effects of extreme in-process cooling. The results indicate that cryogenic cooling has the potential to be used for surface integrity enhancement for improved product life and more sustainable functional performance.

  19. Research in the Hard Sciences, and in Very Hard "Softer" Domains

    Science.gov (United States)

    Phillips, D. C.

    2014-01-01

    The author of this commentary argues that physical scientists are attempting to advance knowledge in the so-called hard sciences, whereas education researchers are laboring to increase knowledge and understanding in an "extremely hard" but softer domain. Drawing on the work of Popper and Dewey, this commentary highlights the relative…

  20. Hard Water and Soft Soap: Dependence of Soap Performance on Water Hardness

    Science.gov (United States)

    Osorio, Viktoria K. L.; de Oliveira, Wanda; El Seoud, Omar A.; Cotton, Wyatt; Easdon, Jerry

    2005-01-01

    The demonstration of the performance of soap in different aqueous solutions, which is due to water hardness and soap formulation, is described. The demonstrations use safe, inexpensive reagents and simple glassware and equipment, introduce important everyday topics, stimulates the students to consider the wider consequences of water hardness and…