Molecular dinamics of tetrahedral clelate compounds of Cd(2) in solutions

International Nuclear Information System (INIS)

Nivorozhkin, L.E.; Minkin, V.I.; Borisenko, N.I.; Konstantinovskij, L.E.; Korobov, M.S.; Olekhnovich, R.Ya.

1981-01-01

Interconversion kinetics of enantiomers of tetrahedral intracomplex compounds of metals (ICM) on the base of unsymmetric ligands in solu-- tions is studied for several series of compounds according to the temperature dependence of the shape of line of prochiral substituents using the methods of the dynamic NMR (DNMR). The use of tetracoordinated ICM in the solutions of synthesized compounds of Cd(2) with the inclusion of magnetic isotope 111 Cd(S=1/2) to study molecular dynamics and the application of the corresponding methods of calculation of the DNMR signal forms permitted to clearly separate the mechanisms of digonal twist and degenerated ligand exchange. In ICM solutions the low-barrier transformations, connected with intramolecular digonal twist, take place as well as high-barrier processes of degenerated ligand exchange. The technique suggested can be applied to the studies of ICM molecular dynamics with other magnetic isotopes of metals ( 207 Pb, 199 Hg, etc.) and rapid non-degenerated ligand exchanges [ru

Physical Compatibility of Magnesium Sulfate and Sodium Bicarbonate in a Pharmacy-compounded Bicarbonate-buffered Hemofiltration Solution

Science.gov (United States)

Moriyama, Brad; Henning, Stacey A.; Jin, Haksong; Kolf, Mike; Rehak, Nadja N.; Danner, Robert L.; Walsh, Thomas J.; Grimes, George J.

2011-01-01

PURPOSE To assess the physical compatibility of magnesium sulfate and sodium bicarbonate in a pharmacy-compounded bicarbonate-buffered hemofiltration solution used at the National Institutes of Health Clinical Center (http://www.cc.nih.gov). METHODS Two hemofiltration fluid formulations with a bicarbonate of 50 mEq/L and a magnesium of 1.5 mEq/L or 15 mEq/L were prepared in triplicate with an automated compounding device. The hemofiltration solution with a bicarbonate of 50 mEq/L and a magnesium of 1.5 mEq/L contains the maximum concentration of additives that we use in clinical practice. The hemofiltration solution of 15 mEq/L of magnesium and 50 mEq/L of bicarbonate was used to study the physicochemical properties of this interaction. The solutions were stored without light protection at 22 to 25 °C for 48 hours. Physical compatibility was assessed by visual inspection and microscopy. The pH of the solutions was assayed at 3 to 4 hours and 52 to 53 hours after compounding. In addition, electrolyte and glucose concentrations in the solutions were assayed at two time points after preparation: 3 to 4 hours and 50 to 51 hours. RESULTS No particulate matter was observed by visual and microscopic inspection in the compounded hemofiltration solutions at 48 hours. Electrolyte and glucose concentrations and pH were similar at both time points after solution preparation. CONCLUSION Magnesium sulfate (1.5 mEq/L) and sodium bicarbonate (50 mEq/L) were physically compatible in a pharmacy-compounded bicarbonate-buffered hemofiltration solution at room temperature without light protection at 48 hours. PMID:20237384

Formulation and stability of an extemporaneously compounded oral solution of chlorpromazine HCl.

Science.gov (United States)

Prohotsky, Daniel L; Juba, Katherine M; Zhao, Fang

2014-12-01

Chlorpromazine is a phenothiazine antipsychotic which is often used in hospice and palliative care to treat hiccups, delirium, and nausea. With the discontinuation of the commercial oral solution concentrate, there is a need to prepare this product by extemporaneous compounding. This study was initiated to identify an easy-to-prepare formulation for the compounding pharmacist. A stability study was also conducted to select the proper storage conditions and establish the beyond-use date. Chlorpromazine HCl powder and the Ora-Sweet® syrup vehicle were used to prepare the 100 mg/mL solution. Once the feasibility was established, a batch of the solution was prepared and packaged in amber plastic prescription bottles for a stability study. These samples were stored at refrigeration (2-8°C) or room temperature (20-25°C) for up to 3 months. At each monthly time point, the samples were evaluated by visual inspection, pH measurement, and high performance liquid chromatography (HPLC). A separate forced stability study was conducted to confirm that the HPLC method was stability indicating. A clear and colorless solution of 100 mg/mL chlorpromazine HCl was obtained by dissolving the drug powder in Ora-Sweet® with moderate agitation. The stability study results indicated that this solution product remained unchanged in visual appearance or pH at both refrigeration and room temperature for up to 3 months. The HPLC results also confirmed that all stability samples retained 93.6-101.4% of initial drug concentration. Chlorpromazine HCl solution 100 mg/mL can be compounded extemporaneously by dissolving chlorpromazine HCl drug powder in Ora-Sweet®. The resulting product is stable for at least three months in amber plastic prescription bottles stored at either refrigeration or room temperature.

Safe handling of potential peroxide forming compounds and their corresponding peroxide yielded derivatives.

Energy Technology Data Exchange (ETDEWEB)

Sears, Jeremiah Matthew; Boyle, Timothy J.; Dean, Christopher J.

2013-06-01

This report addresses recent developments concerning the identification and handling of potential peroxide forming (PPF) and peroxide yielded derivative (PYD) chemicals. PPF chemicals are described in terms of labeling, shelf lives, and safe handling requirements as required at SNL. The general peroxide chemistry concerning formation, prevention, and identification is cursorily presented to give some perspective to the generation of peroxides. The procedure for determining peroxide concentrations and the proper disposal methods established by the Hazardous Waste Handling Facility are also provided. Techniques such as neutralization and dilution are provided for the safe handling of any PYD chemicals to allow for safe handling. The appendices are a collection of all available SNL documentation pertaining to PPF/PYD chemicals to serve as a single reference.

The solubilities of significant organic compounds in HLW tank supernate solutions -- FY 1995 progress report

International Nuclear Information System (INIS)

Barney, G.S.

1996-01-01

At the Hanford Site organic compounds were measured in tank supernate simulant solutions during FY 1995. This solubility information will be used to determine if these organic salts could exist in solid phases (saltcake or sludges) in the waste where they might react violently with the nitrate or nitrite salts present in the tanks. Solubilities of sodium glycolate, succinate, and caproate salts; iron and aluminum and butylphosphate salts; and aluminum oxalate were measured in simulated waste supernate solutions at 25 degree C, 30 degree C, 40 degree C, and 50 degree C. The organic compounds were selected because they are expected to exist in relatively high concentrations in the tanks. The solubilities of sodium glycolate, succinate, caproate, and butylphosphate in HLW tank supernate solutions were high over the temperature and sodium hydroxide concentration ranges expected in the tanks. High solubilities will prevent solid sodium salts of these organic acids from precipitating from tank supernate solutions. The total organic carbon concentrations (YOC) of actual tank supernates are generally much lower than the TOC ranges for simulated supernate solutions saturated (at the solubility limit) with the organic salts. This is so even if all the dissolved carbon in a given tank and supernate is due to only one of these eight soluble compounds (an unlikely situation). Metal ion complexes of and butylphosphate and oxalate in supernate solutions were not stable in the presence of the hydroxide concentrations expected in most tanks. Iron and aluminum dibutylphosphate compounds reacted with hydroxide to form soluble sodium dibutylphosphate and precipitated iron and aluminum hydroxides. Aluminum oxalate complexes were also not stable in the basic simulated supernate solutions. Solubilities of all the organic salts decrease with increasing sodium hydroxide concentration because of the common ion effect of Na+. Increasing temperatures raised the solubilities of the organic

Characterization and handling solutions through development and adaptation of available technologies

International Nuclear Information System (INIS)

Michel, W.S.; Frazee, C.

1998-01-01

The Department of Energy (DOE) faces unique challenges in characterizing and handling its mixed wastes. Mixed waste is low-level or transuranic (TRU) contaminated wastes containing Resource Conservation and Recovery Act (RCRA) hazardous materials. Characterization and material handling technologies will be required to solve pretreatment and disposal needs, and to meet transportation requirements. The Mixed Waste Focus Area (MWFA) will fund the development and demonstration of characterization and material handling technologies to ensure the availability to support the DOE mixed waste needs. The MWFA will be evaluating commercially available and laboratory developed technologies for applicability in meeting these needs. Improved systems will be developed, on the commercial or laboratory side, as needed to address unmet needs. Studies/demonstrations are taking place this year to evaluate the capabilities of existing systems and identify technology gaps. Calls for proposals will be made to both industry and laboratory to identify work to address those gaps. Prioritization of applicable proposals will take place and activities funded appropriately to address characterization and material handling needs

Dopamine transporter SPECT imaging of the peroral addicts of compound codeine phosphate solution

International Nuclear Information System (INIS)

Sun Taotao; Hu Shu; Jia Shaowei; Chen Qing; Fan Rong

2010-01-01

Objective: To study the damage to striatum in patients perorally addicted to compound codeine phosphate solution by using the brain dopamine transporter SPECT imaging. Methods: Patients perorally addicted to compound codeine phosphate solution (n = 29) and addicted to heroin (n = 27), as well as healthy volunteers (n = 31) were included in the study. Each of them underwent dopamine transporter (DAT) SPECT imaging with 99 Tc m -2β-[N, N'-bis-( 2- mercaptoethyl ) ethylenediamino] methyl, 3β-(4-chlorophenyl)tropane ( 99 Tc m -TRODAT-1). The striatum volume (V, cm 3 ), mass (m, g) and radioactivity ratio (Ra) of striatum to whole brain were calculated using physio-mathematical modeling method. Results: Bilateral striatum of healthy volunteers showed typical 'panda eyes' pattern and the distribution of DAT was uniform and symmetrical. Bilateral striatum of patients addicted to compound codeine phosphate showed impaired tracer uptake, similar to those addicted to heroin. The V, m and Ra of bilateral striatum of patients addicted to compound codeine phosphate were (23.68±4.94) cm 3 , (24.87±5.19) g and (5.01±0.88) %, respectively, which were significantly lower than those of healthy controls: (35.39 ±4.42) cm 3 ,(37.16±4.64) g and (7.93±0.86)% (t =-9.69, -9.69, - 13.01, all P =0.000), but significantly higher than those addicted to heroin: (18.87±4.66) cm 3 , (19.81±4.90) g and (4.26±1.02) % (t =3.74, 3.74, 2.96, P = 0.000, 0.000, 0.005). Conclusion: Long-term peroral intake of compound codeine phosphate solution may damage the function of cerebral striatum, which is someway similar to though less severe than, the impairment caused by heroin. (authors)

Solutions for Safe Hot Coil Evacuation and Coil Handling in Case of Thick and High Strength Steel

Directory of Open Access Journals (Sweden)

Sieberer Stefan

2016-01-01

Full Text Available Currently hot rolling plants are entering the market segment for thick gauges and high strength steel grades where the elastic bending property of the strip leads to internal forces in the coil during coiling operation. The strip tends to open. Primetals is investigating several possibilities to facilitate safe coil evacuation and coil handling under spring-back conditions. The contribution includes finite element models of such mechanical solutions. Results of parameter variation and stability limits of case studies are presented in the paper.

Rates of Decomposition of N-Chloramine Disinfectant Compounds in Aqueous Solutions

International Nuclear Information System (INIS)

EI-Bellihi, E.E.

2009-01-01

The effect of temperature, ph, and salt effects on the decomposition kinetics of hydrolysis of N-chloramine disinfectant compounds [chloramine-B, chloramine-T, N-chlorosuccinimide (NCS), and 1,3-dichloro-5,5-dimethyl hydantoin (DCDMH or Halane)] in aqueous solutions was studied. The results should that the hydrolytic stability of CB and CT is greater than that of NCS and halane. Using CT, which is practical in use for its long contact times, reduced its initial concentration in aqueous solution from 100 ppm to about 20 ppm after a period of 6 months. The study also showed that the rate of hydrolysis of NCS is almost independent on the H + ions concentration. On the other hand, the rates of hydrolysis of CB and CT depend strongly on the hydrogen ion (H + ) concentration where the kinetic of the reaction changes from zero-order to a first order. The thermodynamic parameters of activation were calculated and showed that the entropies of activation have large negative values due to the increase in electrostriction and in a loss of freedom of the solvent water molecules associated with the separation of ions in the transition state. A linear compensation between ΔH and ΔS suggests that in the pure aqueous solutions, the reaction mechanism is almost the same for all the chloramine compounds under investigation

Diazo compounds in continuous-flow technology.

Science.gov (United States)

Müller, Simon T R; Wirth, Thomas

2015-01-01

Diazo compounds are very versatile reagents in organic chemistry and meet the challenge of selective assembly of structurally complex molecules. Their leaving group is dinitrogen; therefore, they are very clean and atom-efficient reagents. However, diazo compounds are potentially explosive and extremely difficult to handle on an industrial scale. In this review, it is discussed how continuous flow technology can help to make these powerful reagents accessible on large scale. Microstructured devices can improve heat transfer greatly and help with the handling of dangerous reagents safely. The in situ formation and subsequent consumption of diazo compounds are discussed along with advances in handling diazomethane and ethyl diazoacetate. The potential large-scale applications of a given methodology is emphasized. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hammerhead ribozyme activity and oligonucleotide duplex stability in mixed solutions of water and organic compounds

Directory of Open Access Journals (Sweden)

Shu-ichi Nakano

2014-01-01

Full Text Available Nucleic acids are useful for biomedical targeting and sensing applications in which the molecular environment is different from that of a dilute aqueous solution. In this study, the influence of various types of mixed solutions of water and water-soluble organic compounds on RNA was investigated by measuring the catalytic activity of the hammerhead ribozyme and the thermodynamic stability of an oligonucleotide duplex. The compounds with a net neutral charge, such as poly(ethylene glycol, small primary alcohols, amide compounds, and aprotic solvent molecules, added at high concentrations changed the ribozyme-catalyzed RNA cleavage rate, with the magnitude of the effect dependent on the NaCl concentration. These compounds also changed the thermodynamic stability of RNA base pairs of an oligonucleotide duplex and its dependence on the NaCl concentration. Specific interactions with RNA molecules and reduced water activity could account for the inhibiting effects on the ribozyme catalysis and destabilizing effects on the duplex stability. The salt concentration dependence data correlated with the dielectric constant, but not with water activity, viscosity, and the size of organic compounds. This observation suggests the significance of the dielectric constant effects on the RNA reactions under molecular crowding conditions created by organic compounds.

Radiolytic investigations of solutions of organophosphorus compounds in cyclohexane and benzene

International Nuclear Information System (INIS)

Otrebski, W.

1981-01-01

Organphosphorus compounds are used in various branches of the chemical industry, but in many cases the reaction mechanisms are not well elucidated and less is known about the intermediates of organophosphines. In order to learn more about these rather complicated processes several organophosphorus compounds were used as model substrates in cyclohexane or benzene solution. The systems have been investigated applying the pulse radiolysis technique and steady-state irradiation methods. As representative solutes were chosen diphenylphosphinous chloride, diphenylmethylphosphine, and triphenylphosphine. By means of the pulse radiolysis it was possible to obtain spectroscopic and kinetic data for characterization of the various transients. The final radiolytic products have been analyzed following steady-state and multipulse radiolysis. Since some of the rate constants were not directly accessible by the applied kinetic method, they have been determined by simulation computation. Thereby the experimental data obtained by pulse radiolysis were used. Based on the kinetic, spectroscopic and computed data as well as on the identification of final products, it was possible to elucidate the reaction mechanism of the diphenylphosphinous chloride/cyclohexane system. As a main primary specie was identified the diphenylphoshorus radical. Its spectral and kinetic data have been determined. The reactions of diphenylmethylphosphine involve the same radical, but only to a lesser extent. The reactions of the primary radiolysis products with triphenylphosphine yield mainly adducts. The results represent a contribution in the field of reaction kinetics of organophosphorus compounds. (author)

The pulse radiolysis of aqueous solutions of simple RCN compounds

International Nuclear Information System (INIS)

Draganic, I.G.; Draganic, Z.D.; Markovic, V.M.

1976-01-01

Fast kinetic spectrophotometry was used to study the absorption spectra of short-living intermediates produced by reactions of RCN molecules with H, esub(aq) - and OH. The spectra were obtained on the microsecond time scale after an electron pulse from a Febetron 707 accelerator in aqueous solutions of the following compounds: hydrocyanic acid, acetonitrile, propionitrile, malononitrile and succinonitrile. It has been found that all intermediates absorb in the U.V. range (lamba 9 dm 3 mol -1 s -1 . In the presence of an efficient scavenger for hydroxyl radicals, the same transient spectra were registered in acid and neutral solutions suggesting that the protonations of esub(aq) - adducts of these RCN molecules were complete within a submicrosecond time interval. (author)

Better fuel handling system performance through improved elastomers and seals

Energy Technology Data Exchange (ETDEWEB)

Wensel, R G; Metcalfe, R [Atomic Energy of Canada Ltd., Chalk River, ON (Canada)

1997-12-31

In the area of elastomers, tests have identified specific compounds that perform well in each class of CANDU service. They offer gains in service life, sometimes by factors of ten or more. Moreover, the aging characteristics of these specific compounds are being thoroughly investigated, whereas many elastomers used previously were either non-specific or their aging was unknown. In this paper the benefits of elastomer upgrading, as well as the deficiencies of current station elastomer practices, are discussed in the context of fuel handling equipment. Guidelines for procurement, storage, handling and condition monitoring of elastomer seals are outlined. (author). 3 figs.

Better fuel handling system performance through improved elastomers and seals

International Nuclear Information System (INIS)

Wensel, R.G.; Metcalfe, R.

1996-01-01

In the area of elastomers, tests have identified specific compounds that perform well in each class of CANDU service. They offer gains in service life, sometimes by factors of ten or more. Moreover, the aging characteristics of these specific compounds are being thoroughly investigated, whereas many elastomers used previously were either non-specific or their aging was unknown. In this paper the benefits of elastomer upgrading, as well as the deficiencies of current station elastomer practices, are discussed in the context of fuel handling equipment. Guidelines for procurement, storage, handling and condition monitoring of elastomer seals are outlined. (author). 3 figs

A Solution-Based Temperature Sensor Using the Organic Compound CuTsPc

Directory of Open Access Journals (Sweden)

Shahino Mah Abdullah

2014-06-01

Full Text Available An electrochemical cell using an organic compound, copper (II phthalocyanine-tetrasulfonic acid tetrasodium salt (CuTsPc, has been fabricated and investigated as a solution-based temperature sensor. The capacitance and resistance of the ITO/CuTsPc solution/ITO chemical cell has been characterized as a function of temperature in the temperature range of 25–80 °C. A linear response with minimal hysteresis is observed. The fabricated temperature sensor has shown high consistency and sensitive response towards a specific range of temperature values.

Solution for remote handling in accelerator installations

International Nuclear Information System (INIS)

Burgerjon, J.J.; Ekberg, E.L.; Grisham, D.L.; Horne, R.A.; Meyer, R.E.; Flatau, C.R.; Wilson, K.B.

1977-01-01

A description is given of a remote-handling system designed for the Los Alamos Clinton P. Anderson Meson Physics Facility (LAMPF), versatile enough to be used in a variety of situations found around particle accelerators. The system consists of a bilateral (force-reflecting) servomanipulator installed on an articulated hydraulic boom. The boom also carries the necessary tools and observation devices. The whole slave unit can be moved by crane or truck to the area of operation. A control cable connects the slave unit with the control station, located at a safe distance in a trailer. Various stages of development as well as some operating experience are discussed

Solute-solute interactions in intermetallic compounds

Energy Technology Data Exchange (ETDEWEB)

Banerjee, Debashis; Murray, Ryan; Collins, Gary S., E-mail: collins@wsu.edu [Washington State University, Department of Physics and Astronomy (United States); Zacate, Matthew O. [Northern Kentucky University, Department of Physics and Geology (United States)

2017-11-15

Experiments were carried out on highly ordered GdAl{sub 2} samples containing extremely dilute mole fractions of{sup 111}In/Cd probe-atom solutes (about 10{sup −11}), intrinsic antisite atoms Al{sub Gd} having mole fractions of order 0-10{sup −2}, and doped with Ag solutes at mole fractions of order 10{sup −2}. Three types of defect interactions were investigated. (1) Quadrupole interactions caused by Ag-solute atoms neighboring{sup 111}In/Cd solute probe atoms were detected using the method of perturbed angular correlation of gamma rays (PAC). Three complexes of pairs of In-probes and Ag-solutes occupying neighboring positions on Gd- and Al-sublattices were identified by comparing site fractions in Gd-poor and Gd-rich GdAl{sub 2}(Ag) samples and from the symmetry of the quadrupole interactions. Interaction enthalpies between solute-atom pairs were determined from temperature dependences of observed site fractions. Repulsive interactions were observed for close-neighbor complexes In{sub Gd}+Ag{sub Gd} and In{sub Gd}+Ag{sub Al} pairs, whereas a slightly attractive interaction was observed for In{sub Al}+Ag{sub Al}. Interaction enthalpies were all small, in the range ±0.15 eV. (2) Quadrupole interactions caused by intrinsic antisite atoms Al{sub Gd} neighboring In{sub Gd} probes were also detected and site fractions measured as a function of temperature, as in previous work on samples not doped with Ag-solutes [Temperature- and composition-driven changes in site occupation of solutes in Gd{sub 1+3x}Al{sub 2−3x}, Zacate and Collins (Phys. Rev. B69, 174202 (1))]. However, the effective binding enthalpy between In{sub Gd} probe and Al{sub Gd} antisite was found to change sign from -0.12 eV (attractive interaction) in undoped samples to + 0.24 eV (repulsive) in Ag-doped samples. This may be attributed to an attractive interaction between Al{sub Gd} antisite atoms and Ag-dopants that competes with the attractive interaction between In{sub Gd} and Al{sub Gd

New, clean handling process introduced to improve cable quality

Energy Technology Data Exchange (ETDEWEB)

Hunt, C G

1990-05-01

The clean room system introduced by Canada Wire and Cable Limited in its Toronto plant for its cable manufacturing operation is described. While clean room technology is common in the food processing industry, optical and aerospace manufacturing processes, this is the first time it has been applied to wire and cable extrusion in North America. The purpose of the clean compound handling system is to prevent particle contamination in the shielding and cable insulation materials, as part of an effort to prevent premature underground electric cable failures. Two rooms are dedicated to handling different types of insulation compound, two are dedicated to receiving semi-conducting shielding material, and the fifth room functions as an air lock for the two insulation rooms. The atmosphere is highly regulated with programmable logic control. The air supply filters capture 99.97% of all particles 0.3 microns or larger. The system also maintains air temperature, relative humidity and static pressure. The life variability of cross-linked polyethylene primary distribution cable is dependant on five factors: material purity, extra clean compound handling, cable design, manufacturing process, and installation and operation practices. The clean room system is expected to result in cable that is more resistant to water treeing failures. 2 figs.

Liver dysfunction among workers handling 5-nitro-o-toluidine.

Science.gov (United States)

Shimizu, H; Kumada, T; Nakano, S; Kiriyama, S; Sone, Y; Honda, T; Watanabe, K; Nakano, I; Fukuda, Y; Hayakawa, T

2002-02-01

5-Nitro-o-toluidine is an aromatic nitro amino compound. While other aromatic compounds are known to damage the human liver and are registered as toxic substances, toxicity information concerning 5-nitro-o-toluidine is lacking. To investigate the hepatotoxicity of 5-nitro-o-toluidine. Of 15 workers in the same factory who handled 5-nitro-o-toluidine, three were hospitalised with symptoms of acute liver dysfunction. Suspecting a link between liver dysfunction and working conditions, we correlated workplace factors with clinical findings in all 15 workers. Blood biochemistry tests indicated liver damage in seven of 15 study subjects. Workers who handled 5-nitro-o-toluidine and nitrosyl sulphuric acid often loosened their respiratory protective equipment shortly after 5-nitro-o-toluidine powder had been dispersed into the air of the room. No potential hepatotoxins were present except for 5-nitro-o-toluidine. Six of the affected workers had handled 5-nitro-o-toluidine 12 to 20 times; the seventh worker had handled the powder three times; and the other eight workers without liver dysfunction had handled the material once or twice. No other significant differences in background were evident between the affected and unaffected workers, such as age, sex, or protective measures. Histological findings during recovery from liver damage were similar to those of acute viral hepatitis. None of the 15 subjects has demonstrated liver damage since the factory was closed. A link between liver dysfunction and 5-nitro-o-toluidine exposure is suggested by greater severity of liver dysfunction associated with more episodes of handling.

A model for transfer baggage handling at airports

DEFF Research Database (Denmark)

Barth, Torben C.; Timler Holm, Janus; Lindorff Larsen, Jakob

This work deals with the handling of baggage from passengers changing aircraft at an airport. The transfer baggage problem is to assign the bags from each arriving aircraft to an infeed area into the airport infrastructure. The infrastructure will then distribute the bags to the handling faciliti...... is studied and future approaches for improving robustness are discussed. The presented solution approach runs successfully as part of the operation control systems at Frankfurt Airport since 2008.......This work deals with the handling of baggage from passengers changing aircraft at an airport. The transfer baggage problem is to assign the bags from each arriving aircraft to an infeed area into the airport infrastructure. The infrastructure will then distribute the bags to the handling facilities...... and robustness. The model can be solved with a commercial MIP-solver. Furthermore, the use of the model in the dynamic environment during daily operations is introduced. The model includes two different approaches for increasing the robustness of the generated solutions. The uncertainty of the input data...

Organic radionuclide compounds in soil solutions and their role in elements absorption in plants

International Nuclear Information System (INIS)

Agapkin, G.I.; Tikhomirov, F.A.

1991-01-01

The results of reference experiments with introduction of radioactive labels ( 35 S, 45 Ca, 59 Fe, 85 , 125 I) into 5 types of climatophytic soils by the method of radiogel-chromatography allow to ascertain that in soil solutions 59 Fe and 125 I incorporate completely and 35 S, 45 Ca and 85 Sr incorporate by 60-90 % into the composition of one of three fractions of organic compounds with molecular masses of 4x10 2 -6x10 4 . It is shown that significant variations between soils in the absorption of such radionuclides as 4 5 Ca, 58 Fe, 85 Sr and 125 I are celated to a different degree of their transport into soil solutions as well as to differencies in their distribution by molecular-mass fractions of water-soluble organic compounds

Comparison Between Premixed and Compounded Parenteral Nutrition Solutions in Hospitalized Patients Requiring Parenteral Nutrition.

Science.gov (United States)

Beattie, Colleen; Allard, Johane; Raman, Maitreyi

2016-04-01

Parenteral nutrition (PN) may be provided through compounded or premixed solutions. To determine the proportion of stable custom-compounded PN prescriptions that would fit within a 20% deviance of an existing premixed PN solution. A retrospective study design was used. Inpatients who received PN in non-critical care units in the preceding year were screened for eligibility. Results are reported descriptively as means (95% confidence intervals) and proportions. We reviewed 97 PN prescriptions that met inclusion criteria. Stable hospital PN prescriptions compared with the reference premixed prescription provided 1838 (1777-1898) vs 1843 (1781-1905) kcal/d, P = .43; dextrose, 266 (254-277) vs 225 (216-234) g/d, P magnesium, 5.4 (4.8-5.4) vs 7.6 (7.4-7.9) mmol/L. Calories and protein were remarkably similar, but dextrose, lipid, and electrolytes differed between hospital PN and the reference premixed prescription. We believe that there may be a role for premixed solutions in quaternary centers in stable non-critically ill patients. © 2016 American Society for Parenteral and Enteral Nutrition.

Gas-handling system for studies of tritium-containing materials

International Nuclear Information System (INIS)

Carstens, D.H.W.

1975-01-01

A gas handling system for preparation and study of tritium containing compounds and materials is described. The system at any one time can handle amounts of DT gas up to about 3 moles and has provisions for purification, storage, and measurement of the gas. Experimental conditions covering the ranges 20 to 800 0 C and 0.1 Pa to 137 MPa (10 -2 torr to 20,000 psi) can be maintained. (auth)

The Handling of Constant Volumes of Various Concentrations of ...

African Journals Online (AJOL)

The Handling of Constant Volumes of Various Concentrations of Seawater by the Jackass Penguin Spheniscus Demersus. T Erasmus. Abstract. This paper reports on the effects of varying the concentration of sea water dosed at a rate of 10% of body mass on the handling of fluid and solutes by jackass penguins ...

Development of viable solutions for the synthesis of sulfur bearing single crystals

Science.gov (United States)

Lin, Xiao; Bud'ko, Sergey L.; Canfield, Paul C.

2012-07-01

The discovery of high temperature superconductivity in FeAs and FeSe based compounds has once again focused the condensed matter community on the need to systematically explore compounds containing chalcogens and pnictogens. Whereas some solution growth techniques have been developed to handle P and As, and Sb and Bi are versatile solvents in their own right, S has remained a problematic element to incorporate into conventional solution growth. To a large extent its low boiling point, combined with its polymeric nature in a molten state have made S an uninviting solvent. In this paper we present our development of a range of binary sulfur bearing solutions (some even sulfur rich) and demonstrate how we have been able to use these as useful starting points for the growth of a wide range of transition metal-sulfur-X ternary compounds. We present growth details and basic characterization data for Ni3Bi2S2, Co3Sn2S2, Fe2GeS4, CoSSb, and CePd3S4. In addition we present a remarkably simple method for the growth of single crystalline Co with crystallization taking place below the Curie temperature.

Large-scale exfoliation of inorganic layered compounds in aqueous surfactant solutions

Energy Technology Data Exchange (ETDEWEB)

Smith, Ronan J.; King, Paul J.; Lotya, Mustafa; Wirtz, Christian; Khan, Umar; De, Sukanta; O' Neill, Arlene; Coleman, Jonathan N. [School of Physics, Trinity College Dublin, Dublin 2 (Ireland); CRANN, Trinity College Dublin, Dublin 2 (Ireland); Duesberg, Georg S. [CRANN, Trinity College Dublin, Dublin 2 (Ireland); School of Chemistry, Trinity College Dublin, Dublin 2 (Ireland); Grunlan, Jaime C.; Moriarty, Gregory [Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Chen, Jun [Intelligent Polymer Research Institute, ARC Centre of Excellence for Electromaterials Science, AIIM Facility, University of Wollongong, NSW 2522 (Australia); Wang, Jiazhao [Institute for Superconducting and Electronic Materials, ARC Centre of Excellence for Electromaterials Science, University of Wollongong, NSW 2522 (Australia); Minett, Andrew I. [Laboratory for Sustainable Technology, School of Chemical and Biomolecular Engineering, University of Sydney, Sydney, NSW 2006 (Australia); Nicolosi, Valeria [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

2011-09-08

A method to exfoliate MoS{sub 2} in large quantities in surfactant-water solutions is described. The layered material tends to be exfoliated as dispersions of thin, relatively defect-free flakes with lateral sizes of hundreds of nanometers. This method can be extended to a range of other layered compounds. The dispersed flakes can be mixed with nanotubes or graphene to greate functional hybrid materials. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Adsorption isotherm studies of chromium (VI) from aqueous solutions using sol-gel hydrotalcite-like compounds

Energy Technology Data Exchange (ETDEWEB)

Ramos-Ramirez, Esthela, E-mail: ramosre@quijote.ugto.mx [Centro de Investigaciones en Quimica Inorganica de la Universidad de Guanajuato, Noria Alta s/n, Col. Noria Alta, C.P. 36050, Guanajuato, Gto. (Mexico); Gutierrez Ortega, Norma L.; Conteras Soto, Cesar A. [Centro de Investigaciones en Quimica Inorganica de la Universidad de Guanajuato, Noria Alta s/n, Col. Noria Alta, C.P. 36050, Guanajuato, Gto. (Mexico); Instituto Nacional de Investigaciones Nucleares, Carretera Mexico-Toluca s/n, km 36.5, La Marquesa, Coyoacan Mexico, C.P. 52750 (Mexico); Olguin Gutierrez, Maria T. [Instituto Nacional de Investigaciones Nucleares, Carretera Mexico-Toluca s/n, km 36.5, La Marquesa, Coyoacan Mexico, C.P. 52750 (Mexico)

2009-12-30

In under-developed countries, industries such as paint and pigment manufacturing, leather tanning, chrome plating and textile processing, usually discharge effluents containing Cr(VI) and Cr(III) into municipal sanitary sewers. It has been reported that Cr(VI) acts as a powerful epithelial irritant and as a human carcinogen. In the present work, hydrotalcite-like compounds with a Mg/Al ratio = 2 were synthesized by the sol-gel method. The hydrotalcite-like compounds and their corresponding thermally treated products were characterized by powder X-ray diffraction, infrared spectroscopy and N{sub 2} adsorption. The hydrotalcite-like compounds and the heated solids were used as adsorbents for Cr(VI) in aqueous solutions. Adsorption isotherm studies of Cr(VI) from aqueous solution are described. The adsorbent capacity was determined using the Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherm models. The Cr(VI) adsorption isotherm data fit best to the Langmuir isotherm model. The maximum Cr(VI) uptake by hydrotalcite and the heated solids was determined using the Langmuir equation and was found to range between 26 and 29 mg Cr(VI)/g adsorbent.

Adsorption isotherm studies of chromium (VI) from aqueous solutions using sol-gel hydrotalcite-like compounds

International Nuclear Information System (INIS)

Ramos-Ramirez, Esthela; Gutierrez Ortega, Norma L.; Conteras Soto, Cesar A.; Olguin Gutierrez, Maria T.

2009-01-01

In under-developed countries, industries such as paint and pigment manufacturing, leather tanning, chrome plating and textile processing, usually discharge effluents containing Cr(VI) and Cr(III) into municipal sanitary sewers. It has been reported that Cr(VI) acts as a powerful epithelial irritant and as a human carcinogen. In the present work, hydrotalcite-like compounds with a Mg/Al ratio = 2 were synthesized by the sol-gel method. The hydrotalcite-like compounds and their corresponding thermally treated products were characterized by powder X-ray diffraction, infrared spectroscopy and N 2 adsorption. The hydrotalcite-like compounds and the heated solids were used as adsorbents for Cr(VI) in aqueous solutions. Adsorption isotherm studies of Cr(VI) from aqueous solution are described. The adsorbent capacity was determined using the Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherm models. The Cr(VI) adsorption isotherm data fit best to the Langmuir isotherm model. The maximum Cr(VI) uptake by hydrotalcite and the heated solids was determined using the Langmuir equation and was found to range between 26 and 29 mg Cr(VI)/g adsorbent.

Adsorption isotherm studies of chromium (VI) from aqueous solutions using sol-gel hydrotalcite-like compounds.

Science.gov (United States)

Ramos-Ramírez, Esthela; Ortega, Norma L Gutiérrez; Soto, Cesar A Contreras; Gutiérrez, Maria T Olguín

2009-12-30

In under-developed countries, industries such as paint and pigment manufacturing, leather tanning, chrome plating and textile processing, usually discharge effluents containing Cr(VI) and Cr(III) into municipal sanitary sewers. It has been reported that Cr(VI) acts as a powerful epithelial irritant and as a human carcinogen. In the present work, hydrotalcite-like compounds with a Mg/Al ratio=2 were synthesized by the sol-gel method. The hydrotalcite-like compounds and their corresponding thermally treated products were characterized by powder X-ray diffraction, infrared spectroscopy and N(2) adsorption. The hydrotalcite-like compounds and the heated solids were used as adsorbents for Cr(VI) in aqueous solutions. Adsorption isotherm studies of Cr(VI) from aqueous solution are described. The adsorbent capacity was determined using the Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherm models. The Cr(VI) adsorption isotherm data fit best to the Langmuir isotherm model. The maximum Cr(VI) uptake by hydrotalcite and the heated solids was determined using the Langmuir equation and was found to range between 26 and 29 mg Cr(VI)/g adsorbent.

Interaction of tellurium and tellurium-containing semiconductor compounds with solutions of HI-HNO3-H2O system

International Nuclear Information System (INIS)

Tomashik, V.N.; Sava, A.A.; Tomashik, Z.F.

1994-01-01

As a result of experimental investigations and physical-chemical simulation are established regularities of solution of semiconducting tellurium-containing compounds in HI-HNO 3 -H 2 O systems. In HNO 3 -HI system solutions enriched by HNO 3 are not used for CdTe treatment but HI enriched solution are similar in composition with I 2 -HI solutions. Solution of the given tellurium-containing materials proceeds by a chemical mechanism and is determined by tellurium oxidation with iodine

Process for the elimination of organic compounds in solution or in suspension from an aqueous solution such as a radioactive effluent

International Nuclear Information System (INIS)

Cordero, G.; Gauthier, F.; Perotin, J.P.; Saulze, J.L.

1991-01-01

Organic compounds such as complexing agents (for instance citric acid, EDTA and tartric acid) are oxidized with Co 3+ ions. For this purpose a cobalt (II) salt is added to the aqueous solution and Co 3+ ions required for oxidation are continuously generated by electrolysis. The cobalt salt is preferentially cobalt nitrate [fr

A Perspective on Remote Handling Operations and Human Machine Interface for Remote Handling in Fusion

International Nuclear Information System (INIS)

Haist, B.; Hamilton, D.; Sanders, St.

2006-01-01

A large-scale fusion device presents many challenges to the remote handling operations team. This paper is based on unique operational experience at JET and gives a perspective on remote handling task development, logistics and resource management, as well as command, control and human-machine interface systems. Remote operations require an accurate perception of a dynamic environment, ideally providing the operators with the same unrestricted knowledge of the task scene as would be available if they were actually at the remote work location. Traditional camera based systems suffer from a limited number of viewpoints and also degrade quickly when exposed to high radiation. Virtual Reality and Augmented Reality software offer great assistance. The remote handling system required to maintain a tokamak requires a large number of different and complex pieces of equipment coordinating to perform a large array of tasks. The demands on the operator's skill in performing the tasks can escalate to a point where the efficiency and safety of operations are compromised. An operations guidance system designed to facilitate the planning, development, validation and execution of remote handling procedures is essential. Automatic planning of motion trajectories of remote handling equipment and the remote transfer of heavy loads will be routine and need to be reliable. This paper discusses the solutions developed at JET in these areas and also the trends in management and presentation of operational data as well as command, control and HMI technology development offering the potential to greatly assist remote handling in future fusion machines. (author)

Reactor neutron converter into antineutrinos on base of lithium compounds and their solutions

International Nuclear Information System (INIS)

Lyutostanskij, Yu.S.; Lyashchuk, V.I.

1990-01-01

A study on the possibility of using various lithium compounds as substances for reactor neutron converter into antineutrinos, was made. It is concluded that heavy water LiOD, LiODxD 2 O, LiD solutions are the most promising ones. They provide for high efficiency with reduction of the required lithium mass (300-350 times maximum) as compared with pure lithium converter

Modified solution calorimetry approach for determination of vaporization and sublimation enthalpies of branched-chain aliphatic and alkyl aromatic compounds at T = 298.15 K

International Nuclear Information System (INIS)

Varfolomeev, Mikhail A.; Novikov, Vladimir B.; Nagrimanov, Ruslan N.; Solomonov, Boris N.

2015-01-01

Highlights: • Solution enthalpies of 18 branching-chain alkyl aromatic and aliphatic compounds in cyclohexane were measured. • Group contributions to the enthalpy of solvation due to branching and substitution in carbon chain were evaluated. • Modified solution calorimetry based approach for determination of vaporization/sublimation enthalpies was proposed. • This approach provides vaporization/sublimation enthalpies directly at T = 298.15 K. • Vaporization/sublimation enthalpies of 35 branched-chain alkyl aromatic and aliphatic compounds were determined. - Abstract: The enthalpies of solution, solvation and vaporization/sublimation are interrelated values combined in the simplest thermodynamic circle. Hence, experimental determination of vaporization/sublimation enthalpy can be substituted by experimentally simpler determination of solution enthalpy when solvation enthalpy is known. Previously it was found that solvation enthalpies of a wide range of unbranched aliphatic and aromatic solutes in saturated hydrocarbons are in good linear correlation with their molar refraction values. This allows to estimate the vaporization/sublimation enthalpy of any unbranched organic compound from its solution enthalpy in saturated hydrocarbon and molar refraction. In the present work this approach was modified for determination of vaporization/sublimation enthalpy of branched-chain alkyl aromatic and aliphatic compounds. Group contributions to the enthalpy of solvation due to the branching of carbon chain were evaluated. Enthalpies of solution at infinite dilution of 18 branched-chain aliphatic and alkyl aromatic compounds were measured at T = 298.15 K. Vaporization/sublimation enthalpies for 35 branched aliphatic and alkyl aromatic compounds were determined by using modified solution calorimetry approach. These values are in good agreement with available literature data on vaporization/sublimation enthalpies obtained by conventional methods.

Mobility of arsenic and its compounds in soil and soil solution: the effect of soil pretreatment and extraction methods.

Science.gov (United States)

Száková, J; Tlustos, P; Goessler, W; Frková, Z; Najmanová, J

2009-12-30

The effect of soil extraction procedures and/or sample pretreatment (drying, freezing of the soil sample) on the extractability of arsenic and its compounds was tested. In the first part, five extraction procedures were compared with following order of extractable arsenic portions: 2M HNO(3)>0.43 M CH(3)COOH>or=0.05 M EDTA>or=Mehlich III (0.2M CH(3)COOH+0.25 M NH(4)NO(3)+0.013 M HNO(3)+0.015 M NH(4)F+0.001 M EDTA) extraction>water). Additionally, two methods of soil solution sampling were compared, centrifugation of saturated soil and the use of suction cups. The results showed that different sample pretreatments including soil solution sampling could lead to different absolute values of mobile arsenic content in soils. However, the interpretation of the data can lead to similar conclusions as apparent from the comparison of the soil solution sampling methods (r=0.79). For determination of arsenic compounds mild extraction procedures (0.05 M (NH(4))(2)SO(4), 0.01 M CaCl(2), and water) and soil solution sampling using suction cups were compared. Regarding the real soil conditions the extraction of fresh samples and/or in situ collection of soil solution are preferred among the sample pretreatments and/or soil extraction procedures. However, chemical stabilization of the solutions should be allowed and included in the analytical procedures for determination of individual arsenic compounds.

Potential of the octanol-water partition coefficient (logP) to predict the dermal penetration behaviour of amphiphilic compounds in aqueous solutions.

Science.gov (United States)

Korinth, Gintautas; Wellner, Tanja; Schaller, Karl Heinz; Drexler, Hans

2012-11-23

Aqueous amphiphilic compounds may exhibit enhanced skin penetration compared with neat compounds. Conventional models do not predict this percutaneous penetration behaviour. We investigated the potential of the octanol-water partition coefficient (logP) to predict dermal fluxes for eight compounds applied neat and as 50% aqueous solutions in diffusion cell experiments using human skin. Data for seven other compounds were accessed from literature. In total, seven glycol ethers, three alcohols, two glycols, and three other chemicals were considered. Of these 15 compounds, 10 penetrated faster through the skin as aqueous solutions than as neat compounds. The other five compounds exhibited larger fluxes as neat applications. For 13 of the 15 compounds, a consistent relationship was identified between the percutaneous penetration behaviour and the logP. Compared with the neat applications, positive logP were associated with larger fluxes for eight of the diluted compounds, and negative logP were associated with smaller fluxes for five of the diluted compounds. Our study demonstrates that decreases or enhancements in dermal penetration upon aqueous dilution can be predicted for many compounds from the sign of logP (i.e., positive or negative). This approach may be suitable as a first approximation in risk assessments of dermal exposure. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

Ionic liquid solutions as extractive solvents for value-added compounds from biomass.

Science.gov (United States)

Passos, Helena; Freire, Mara G; Coutinho, João A P

2014-12-01

In the past few years, the number of studies regarding the application of ionic liquids (ILs) as alternative solvents to extract value-added compounds from biomass has been growing. Based on an extended compilation and analysis of the data hitherto reported, the main objective of this review is to provide an overview on the use of ILs and their mixtures with molecular solvents for the extraction of value-added compounds present in natural sources. The ILs (or IL solutions) investigated as solvents for the extraction of natural compounds, such as alkaloids, flavonoids, terpenoids, lipids, among others, are outlined. The extraction techniques employed, namely solid-liquid extraction, and microwave-assisted and ultrasound-assisted extractions, are emphasized and discussed in terms of extraction yields and purification factors. Furthermore, the evaluation of the IL chemical structure and the optimization of the process conditions (IL concentration, temperature, biomass-solvent ratio, etc.) are critically addressed. Major conclusions on the role of the ILs towards the extraction mechanisms and improved extraction yields are additionally provided. The isolation and recovery procedures of the value-added compounds are ascertained as well as some scattered strategies already reported for the IL solvent recovery and reusability. Finally, a critical analysis on the economic impact versus the extraction performance of IL-based methodologies was also carried out and is here presented and discussed.

SOLISOL-handling of solid solutions. Version 1.1

International Nuclear Information System (INIS)

Boerjesson, S.; Emren, A.

1992-09-01

SOLISOL is a C computer program designed to model geochemical reactions involving solid solutions. The program searches equilibrium concentrations of the components in the aqueous phase and the solid solution given by limited quantities of the solid solution components. The equilibrium code PHREEQE is used as a subprogram in SOLISOL. Subprograms external to PHREEQE extract information from PHREEQE results, take care of conserved properties, calculate solubilities and produce inputdata for PHREEQE. The essential idea in this process is to calculate solubilities for the components in terms of saturation indices, and give directions to PHREEQE on how to search for the equilibrium under those constraints. (au)

Photocatalytic hydrogen evolution from aqueous solutions of organophosphorous compounds

Energy Technology Data Exchange (ETDEWEB)

Kozlova, Ekaterina A.; Vorontsov, Alexander V. [Boreskov Institute of Catalysis and Novosibirsk State University, Novosibirsk 630090 (Russian Federation)

2010-07-15

Photocatalytic hydrogen production from water solutions of dimethyl methylphosphonate (DMMP), trimethyl phosphate (TMP), triethyl phosphate (TEP), and radiation protective amine WR 2721, that imitate nerve chemical warfare agents was studied for the first time. Platinized titianium dioxide Degussa P25 was used as catalyst. No significant hydrogen evolution was detected without organic electron donors - sacrificial agents. The hydrogen evolution rate was shown to grow slowly with the rise of initial DMMP concentration. The initial rate vs. DMMP concentration curve is well fitted by Langmuir-Hinshelwood (L-H) equation. The DMMP adsorption constant obtained from the L-H equation fit is markedly higher than that obtained from the Langmuir adsorption isotherm. Reactions of full destruction into inorganic products of the four organophosphorous compounds were conducted. Amounts of evolved hydrogen and carbon dioxide were completely consistent with stoichiometry of proposed reaction. There were no initial compounds and only trace of total organic carbon after the end of the reaction. Complete water purification and production of an amount of valuable hydrogen was achieved. Intermediates of DMMP oxygen-free destruction were identified by means of GC/MS. They were the same as those in the case of DMMP photocatalytic oxidation. A mechanism of hydrogen evolution that explains smaller rates of mineralization compared to photocatalytic oxidation by oxygen was proposed. (author)

Robotic liquid handling and automation in epigenetics.

Science.gov (United States)

Gaisford, Wendy

2012-10-01

Automated liquid-handling robots and high-throughput screening (HTS) are widely used in the pharmaceutical industry for the screening of large compound libraries, small molecules for activity against disease-relevant target pathways, or proteins. HTS robots capable of low-volume dispensing reduce assay setup times and provide highly accurate and reproducible dispensing, minimizing variation between sample replicates and eliminating the potential for manual error. Low-volume automated nanoliter dispensers ensure accuracy of pipetting within volume ranges that are difficult to achieve manually. In addition, they have the ability to potentially expand the range of screening conditions from often limited amounts of valuable sample, as well as reduce the usage of expensive reagents. The ability to accurately dispense lower volumes provides the potential to achieve a greater amount of information than could be otherwise achieved using manual dispensing technology. With the emergence of the field of epigenetics, an increasing number of drug discovery companies are beginning to screen compound libraries against a range of epigenetic targets. This review discusses the potential for the use of low-volume liquid handling robots, for molecular biological applications such as quantitative PCR and epigenetics.

Preparation and certification of solutions of perdeuterated polycyclic aromatic compounds intended for use as surrogate internal standards

International Nuclear Information System (INIS)

Quilliam, M.A.; Hardstaff, W.R.; Anacleto, J.F.; LeBlanc, M.D.; Stergiopoulos, V.; Dick, K.L.; Bowser, M.T.; Curtis, J.M.; Embree, D.J.; Sim, P.G.; Boyd, R.K.

1994-01-01

Two standard solutions of deuterated polycyclic aromatic compounds (PACs) have been prepared for use as surrogate internal standards. Solution DPAC-1 contains 21 deuterated PACs, and is intended for use with mass spectrometric (MS) detection. Most of the difficulties in certifying concentrations in DPAC-1 arose from the fact that none of the individual compounds was 100% deuterated, so that effects of mass spectrometric fragmentation are convoluted with those of isotopic distributions. The best methods are discussed for using such internal standards so as to minimize these problems, together with those arising from kinetic isotope effects. Solution DPAC-2 contains 6 deuterated PACs, and is primarily intended for use with reversed-phase high-performance liquid chromatography (HPLC) with fluorescence detection (FLD, dural programmed wavelength mode), in which the signals for analyte and internal standard are separated chromatographically rather than via the detector. Full details of the preparation of these solutions are described. In addition, examples of their use in the analysis of a certified coal-tar extract (NIST SRM 1597) are described briefly. In one example a novel HPLC-MS technique was employed, and in the other the HPLC-FLD technique was used. (orig.)

A Reverse Logistics Network Model for Handling Returned Products

Directory of Open Access Journals (Sweden)

Nizar Zaarour

2014-07-01

obtained the optimal solution at a fraction of the time used by the traditional nonlinear model and solution procedure, as well as the ability to handle up to 150 customers as compared to 30 in the conventional nonlinear model. As such, the proposed linear model is more suitable for actual industry applications than the existing models.

WISE TECHNOLOGY FOR HANDLING BIG DATA FEDERATIONS

NARCIS (Netherlands)

Valentijn, E; Begeman, Kornelis; Belikov, Andrey; Boxhoorn, Danny; Verdoes Kleijn, Gijs; McFarland, John; Vriend, Willem-Jan; Williams, Owen; Soille, P.; Marchetti, P.G.

2014-01-01

The effective use of Big Data in current and future scientific missions requires intelligent data handling systems which are able to interface the user to complicated distributed data collections. We review the WISE Concept of Scientific Information Systems and the WISE solutions for the storage and

Combating wear in bulk solids handling plants

Energy Technology Data Exchange (ETDEWEB)

1986-01-01

A total of five papers presented at a seminar on problems of wear caused by abrasive effects of materials in bulk handling. Topics of papers cover the designer viewpoint, practical experience from the steel, coal, cement and quarry industries to create an awareness of possible solutions.

Development of liquid handling techniques in microgravity

Science.gov (United States)

Antar, Basil N.

1995-01-01

A large number of experiments dealing with protein crystal growth and also with growth of crystals from solution require complicated fluid handling procedures including filling of empty containers with liquids, mixing of solutions, and stirring of liquids. Such procedures are accomplished in a straight forward manner when performed under terrestrial conditions in the laboratory. However, in the low gravity environment of space, such as on board the Space Shuttle or an Earth-orbiting space station, these procedures sometimes produced entirely undesirable results. Under terrestrial conditions, liquids usually completely separate from the gas due to the buoyancy effects of Earth's gravity. Consequently, any gas pockets that are entrained into the liquid during a fluid handling procedure will eventually migrate towards the top of the vessel where they can be removed. In a low gravity environment any folded gas bubble will remain within the liquid bulk indefinitely at a location that is not known a priori resulting in a mixture of liquid and vapor.

Installation and method for handling fuel assemblies of fast nuclear reactors

International Nuclear Information System (INIS)

Aubert, Michel; Renaux, Charley.

1982-01-01

This invention concerns an installation and a method for handling the assemblies which makes it possible to have a large revolving plug smaller in diameter than that of the presently known solutions. This large, coaxial to the core, revolving plug has a handling arm enabling a fraction of the assemblies to be reached and deposited in a handling well. Through a small offset revolving plug the remainder of the assemblies can be reached and deposited in a pick-up well accessible to the arm of the large revolving plug [fr

How to Handle Difficult Parents: Proven Solutions for Teachers. Second Edition

Science.gov (United States)

Tingley, Suzanne Capek

2012-01-01

"How to Handle Difficult Parents" is a funny, but practical, guide to working effectively with parents and avoiding unnecessary conflict. Whether you're a teacher (regular or special education) or a coach, this book will give you practical suggestions regarding what to say and how to say it to parents who question your lesson plans, challenge your…

Solution synthesis of germanium nanocrystals

Science.gov (United States)

Gerung, Henry [Albuquerque, NM; Boyle, Timothy J [Kensington, MD; Bunge, Scott D [Cuyahoga Falls, OH

2009-09-22

A method for providing a route for the synthesis of a Ge(0) nanometer-sized material from. A Ge(II) precursor is dissolved in a ligand heated to a temperature, generally between approximately 100.degree. C. and 400.degree. C., sufficient to thermally reduce the Ge(II) to Ge(0), where the ligand is a compound that can bond to the surface of the germanium nanomaterials to subsequently prevent agglomeration of the nanomaterials. The ligand encapsulates the surface of the Ge(0) material to prevent agglomeration. The resulting solution is cooled for handling, with the cooling characteristics useful in controlling the size and size distribution of the Ge(0) materials. The characteristics of the Ge(II) precursor determine whether the Ge(0) materials that result will be nanocrystals or nanowires.

Reactivity of Cork Extracts with (+)-Catechin and Malvidin-3-O-glucoside in Wine Model Solutions: Identification of a New Family of Ellagitannin-Derived Compounds (Corklins).

Science.gov (United States)

Azevedo, Joana; Fernandes, Ana; Oliveira, Joana; Brás, Natércia F; Reis, Sofia; Lopes, Paulo; Roseira, Isabel; Cabral, Miguel; Mateus, Nuno; de Freitas, Victor

2017-10-04

The aim of this study was to evaluate the reactivity of phenolic compounds extracted from cork stoppers to wine model solutions with two major wine components, namely, (+)-catechin and malvidin-3-O-glucoside. Besides the formation of some compounds already described in the literature, these reactions also yielded a new family of ellagitannin-derived compounds, named herein as corklins. This new family of compounds that were found to result from the interaction between ellagitannins in alcoholic solutions and (+)-catechin were structurally characterized by mass spectroscopy, nuclear magnetic resonance, and computational methods.

Structural and functional characterization of solute binding proteins for aromatic compounds derived from lignin: p-coumaric acid and related aromatic acids.

Science.gov (United States)

Tan, Kemin; Chang, Changsoo; Cuff, Marianne; Osipiuk, Jerzy; Landorf, Elizabeth; Mack, Jamey C; Zerbs, Sarah; Joachimiak, Andrzej; Collart, Frank R

2013-10-01

Lignin comprises 15-25% of plant biomass and represents a major environmental carbon source for utilization by soil microorganisms. Access to this energy resource requires the action of fungal and bacterial enzymes to break down the lignin polymer into a complex assortment of aromatic compounds that can be transported into the cells. To improve our understanding of the utilization of lignin by microorganisms, we characterized the molecular properties of solute binding proteins of ATP-binding cassette transporter proteins that interact with these compounds. A combination of functional screens and structural studies characterized the binding specificity of the solute binding proteins for aromatic compounds derived from lignin such as p-coumarate, 3-phenylpropionic acid and compounds with more complex ring substitutions. A ligand screen based on thermal stabilization identified several binding protein clusters that exhibit preferences based on the size or number of aromatic ring substituents. Multiple X-ray crystal structures of protein-ligand complexes for these clusters identified the molecular basis of the binding specificity for the lignin-derived aromatic compounds. The screens and structural data provide new functional assignments for these solute-binding proteins which can be used to infer their transport specificity. This knowledge of the functional roles and molecular binding specificity of these proteins will support the identification of the specific enzymes and regulatory proteins of peripheral pathways that funnel these compounds to central metabolic pathways and will improve the predictive power of sequence-based functional annotation methods for this family of proteins. Copyright © 2013 Wiley Periodicals, Inc.

Nuclear liability claims handling and costs - Germany and some comparative solutions

International Nuclear Information System (INIS)

Harbruecker, D.

2000-01-01

Comparison of legal status in Central Europe: coverage by insurance and State intervention, coverage of legal expenses and interests on awards technical problems of claims handing after a nuclear incident: guidelines to be prepared by insurer before and not after an incident occurred, demands on provider of financial security claims handling for part guaranteed by State to be transferred to insurer, necessary regulations of such arrangements (author)

Design and Implementation of Company Tailored Automated Material Handling

DEFF Research Database (Denmark)

Langer, Gilad; Bilberg, Arne

1996-01-01

This article focuses on the problems of analysing automation of material handling systems in order to develop an efficient automated solution that is specifically tailored to the company. The research has resulted in development of new methods for evaluating factory automation from design...... to implementation. The goals of the research were to analyse and evaluate automation in order to obtain an advantageous combination of human and automated resources. The idea is to asses different solutions in a virtual environment, where experiments and analyses can be performed so that the company can justify...... for their application with computer aided information processing tools. The framework is named the "Automated Material Handling (AMH) Preference GuideLine". The research has been carried out in close co-operation with Danish and European industry, where implementations of automation can be referred to. It is our...

Adaptive control of manipulators handling hazardous waste

International Nuclear Information System (INIS)

Colbaugh, R.; Glass, K.

1994-01-01

This article focuses on developing a robot control system capable of meeting hazardous waste handling application requirements, and presents as a solution an adaptive strategy for controlling the mechanical impedance of kinematically redundant manipulators. The proposed controller is capable of accurate end-effector impedance control and effective redundancy utilization, does not require knowledge of the complex robot dynamic model or parameter values for the robot or the environment, and is implemented without calculation of the robot inverse transformation. Computer simulation results are given for a four degree of freedom redundant robot under adaptive impedance control. These results indicate that the proposed controller is capable of successfully performing important tasks in robotic waste handling applications. (author) 3 figs., 39 refs

Kinetics and mechanism of superoxide radical reactions with some biologically important compounds in aqueous solutions. Pulse radiolysis

Science.gov (United States)

Revina, A. A.; Amiragova, M. I.; Volod'ko, V. V.; Vannikov, A. V.

Microsecond pulse radiolysis of oxygenated aqueous solutions containing 0.02 mol dm -3 sodium formate and 2 mmol dm -3 phosphate buffer at pH 7 was used to generate superoxide anion radicals. The influence of some biologically important compounds upon the rate of O ⨪2 decay was monitored spectrophotometrically in the range of 245-300 nm. Hematoporphyrin (HP), hemin C (HC), catalase (Cat), cobalt sulfophthalocyanine (CoTSPc) were studied. Among the investigated compounds only Cat was found to show a high catalytic efficiency towards the self-decay of O ⨪2. A red shift of O ⨪2 absorption band and slowing down of its decay were observed to take place by adding HP or CoTSPc to the solutions containing formate ions in excess. This effect is associated with the formation of a transient superoxo-complex. An appearance of an intermediate species with absorption maxima at 350 nm and half-life of about 2s was observed to accompany the superoxo-complex of CoTSPc decay. In the aerated solution of HP the intensity of absorbance at 260 nm was found to be independent of the presence of formate ions.

Kinetics and mechanism of superoxide radical reactions with some biologically important compounds in aqueous solutions. Pulse radiolysis

International Nuclear Information System (INIS)

Revina, A.A.; Volod'ko, V.V.; Vannikov, A.V.

1989-01-01

Microsecond pulse radiolysis of oxygenated aqueous solutions containing 0.02 mol dm -3 sodium formate and 2 mmol dm -3 phosphate buffer at pH 7 was used to generate superoxide anion radicals. The influence of some biologically important compounds upon the rate of O 2 .-bar decay as monitored spectrophotometrically in the range of 245-300 nm. Hematoporphyrin (HP), hemin C (HC), catalase (Cat), cobalt sulfophthalocyanine (CoTSPc) were studied. Among the investigated compounds only Cat was found to show a high catalytic efficiency towards the self-decay of O 2 .-bar . A red shift of 0 2 .-bar absorption band and slowing down of its decay were observed to take place by adding HP or CoTSPc to the solutions containing formate ions in excess. This effect is associated with the formation of a transient superoxo-complex. An appearance of an intermediate species with absorption maxima at 350 nm and half-life of about 2 s was observed to accompany the superoxo-complex of CoTSPc decay. In the aerated solution of HP the intensity of absorbance at 260 nm was found to be independent of the presence of formate ions. (author)

The Application of Online Check-in in the Process of Passenger Handling in Air Transportation

Directory of Open Access Journals (Sweden)

František Adamčík

2017-11-01

Full Text Available Passenger handling is one of the most important activities any passenger is obliged to carry out prior to boarding the plane to depart. For the handling process to be safeguarded, it is inevitable to perform the services involved in it fast and efficiently so as to prevent idle times or delays during the procedures potentially resulting in delay of flight. By gradual development of the so-called web-based information technologies, some of the activities involved in the handling process can be delegated to the passengers themselves, thereby achieving a faster course of the passenger handling process. In this contribution the authors are dealing with the status quo of the on-line web-based check-in process in air transportation forecasting the expected course of events in these services in the future. Next, based on analyzing functions and characteristics of similar solutions available in the market, the authors are putting forward their new proposal of their own design of a self-service, on-line system of passenger handling with the aim to simplify and expedite the entire handling process. It is the aim of the authors to develop a competitive design in terms of costs as well as new function and services not offered by the hitherto existing with emphasis on improving efficiency of passenger handling at the airports. The resulting solution thanks to internet based technologies is platform independent and fully applicable to the process of airport passenger handling. To an equal extent, the solutions are being applied by the authors to the educational process, as a training tool for the preparation of the aviation personnel and also as part of simulation models for research in the field of airport processes optimization.

Advanced dust monitoring system applied to new TRU handling facility of JAERI

International Nuclear Information System (INIS)

Yabuta, H.; Shigeta, Y.; Sawahata, K.; Hasegawa, K.

1993-01-01

In JAERI, a large, scale multipurpose facility is under construction, which consists of a TRU waste management testing installation, a solution fuel treatment installation and critical assemblies with uranium and/or plutonium solution fuel. The facility is also equipped with a lot of gloveboxes for handling and treatment of solution fuel and hot cells for research on reprocessing process. As there may be a relatively high potential of air contamination, it is important to monitor air contamination effectively and efficiently. An advanced dust monitoring system was introduced for convenience of handling and automatical measurement of filter papers, by developing a filter-holder with an IC memory and a radioactivity measuring device with an automatic filter-holder changing mechanism as a part of a centralized monitoring system with a computer

Investigation of six-membered carbocyclic compounds as a molecular switch block of room temperature phosphorescence in nondeoxygenated {beta}-cyclodextrin solution

Energy Technology Data Exchange (ETDEWEB)

Zhang Hairong; Wei Yansheng; Jin Weijun; Liu Changsong

2003-05-07

An aerated aqueous solution, intense room temperature phosphorescence (RTP) of nitrogen heterocyclic compounds (NHCs) and polyaromatic hydrocarbons (PAHs) can be observed when micro amounts of six-membered carbocyclic compounds (6-MCCs) are introduced in {beta}-cyclodextrin ({beta}-CD) solution. In order to find the predominating factors of the enhanced phosphorescence observed with this novel approach, 22 typical phosphors of NHCs and PAHs were carefully screened and served as model compounds. The role of the inner heavy atom, the substituent group and the host-guest molecules space-matching on the RTP of different phosphors were investigated. The results demonstrated that the enhancement effects of cyclohexane, bromocyclohexane and cyclohexanol for the RTP of NHCs and PAHs have precedence over traditional halide alkanes such as 1,2-dibromoethane (DBE), exhibiting an obvious sequence as following: cyclohexane > bromocyclohexane > cyclohexanol. This new approach compared with other RTP methods is simple, convenient and fast.

Investigation of six-membered carbocyclic compounds as a molecular switch block of room temperature phosphorescence in nondeoxygenated β-cyclodextrin solution

International Nuclear Information System (INIS)

Zhang Hairong; Wei Yansheng; Jin Weijun; Liu Changsong

2003-01-01

An aerated aqueous solution, intense room temperature phosphorescence (RTP) of nitrogen heterocyclic compounds (NHCs) and polyaromatic hydrocarbons (PAHs) can be observed when micro amounts of six-membered carbocyclic compounds (6-MCCs) are introduced in β-cyclodextrin (β-CD) solution. In order to find the predominating factors of the enhanced phosphorescence observed with this novel approach, 22 typical phosphors of NHCs and PAHs were carefully screened and served as model compounds. The role of the inner heavy atom, the substituent group and the host-guest molecules space-matching on the RTP of different phosphors were investigated. The results demonstrated that the enhancement effects of cyclohexane, bromocyclohexane and cyclohexanol for the RTP of NHCs and PAHs have precedence over traditional halide alkanes such as 1,2-dibromoethane (DBE), exhibiting an obvious sequence as following: cyclohexane > bromocyclohexane > cyclohexanol. This new approach compared with other RTP methods is simple, convenient and fast

Applying remote handling attributes to the ITER neutral beam cell monorail crane

Energy Technology Data Exchange (ETDEWEB)

Crofts, O., E-mail: Oliver.Crofts@CCFE.ac.uk [CCFE, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Allan, P.; Raimbach, J. [CCFE, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Tesini, A.; Choi, C.-H. [ITER Organisation, CS90 046, 13067 St. Paul les Durance Cedex (France); Damiani, C.; Van Uffelen, M. [Fusion for Energy, C/Josep Pla 2, Torres Diagonal Litoral-B3, E-08019 Barcelona (Spain)

2013-10-15

The maintenance requirements for the equipment in the ITER neutral beam cell require components to be lifted and transported within the cell by remote means. To meet this requirement, the provision of an overhead crane with remote handling capabilities has been initiated. The layout of the cell has driven the design to consist of a monorail crane that travels on a branched monorail track attached to the cell ceiling. This paper describes the principle design constraints and how the remote handling attributes were applied to the concept design of the monorail crane, concentrating on areas where novel design solutions have been required and on the remote recovery requirements and solutions.

Applying remote handling attributes to the ITER neutral beam cell monorail crane

International Nuclear Information System (INIS)

Crofts, O.; Allan, P.; Raimbach, J.; Tesini, A.; Choi, C.-H.; Damiani, C.; Van Uffelen, M.

2013-01-01

The maintenance requirements for the equipment in the ITER neutral beam cell require components to be lifted and transported within the cell by remote means. To meet this requirement, the provision of an overhead crane with remote handling capabilities has been initiated. The layout of the cell has driven the design to consist of a monorail crane that travels on a branched monorail track attached to the cell ceiling. This paper describes the principle design constraints and how the remote handling attributes were applied to the concept design of the monorail crane, concentrating on areas where novel design solutions have been required and on the remote recovery requirements and solutions

Moving and handling education in the community: technological innovations to improve practice.

Science.gov (United States)

Wanless, Stephen; Page, Andrea

2009-12-01

Efforts to reduce injuries associated with patient handling are often based on tradition and personal experience rather than sound educational theory. The purpose of this article is to summarize current evidence for educational interventions designed to reduce primary care staff injuries: a significant problem for decades. Evidence suggests that the current 'classroom' teaching of moving and handling is ineffective. There is a growing body of evidence to support newer interventions that are effective or show promise in reducing musculoskeletal injuries in health professionals (Freitag et al, 2007). The authors discuss potential solutions through moving and handling-related motion capture simulation and the use of e-learning to promote an understanding of the principles associated with patient handling tasks.

Improvements in or relating to handling of flue gas

International Nuclear Information System (INIS)

Ingham, R.V.

1986-01-01

The patent describes improvements in the method for handling flue gas from the burning of fossil fuels. The method relates to cleaning the flue gas, from which the sulphur compounds are removed. The gas in then heated by heat derived from a nuclear source, which may be nuclear waste. The heat treatment gives efficient atmospheric dispersion from the chimney. (U.K.)

Handling of wet residues in industry

DEFF Research Database (Denmark)

Villanueva, Alejandro

is fundamental in most disposal routes for clarifying the possibility of treating the residue. The better the characterisation from the start is, the easier the assessment of the feasible disposal alternatives becomes. The decision about the handling/disposal solution for the residue is a trade-off between......, and can depend on factors such as the investment capacity, the relationships with the stakeholders, or the promotion of its environmental profile....

Common handling procedures conducted in preclinical safety studies result in minimal hepatic gene expression changes in Sprague-Dawley rats.

Directory of Open Access Journals (Sweden)

Yudong D He

Full Text Available Gene expression profiling is a tool to gain mechanistic understanding of adverse effects in response to compound exposure. However, little is known about how the common handling procedures of experimental animals during a preclinical study alter baseline gene expression. We report gene expression changes in the livers of female Sprague-Dawley rats following common handling procedures. Baseline gene expression changes identified in this study provide insight on how these changes may affect interpretation of gene expression profiles following compound exposure. Rats were divided into three groups. One group was not subjected to handling procedures and served as controls for both handled groups. Animals in the other two groups were weighed, subjected to restraint in Broome restrainers, and administered water via oral gavage daily for 1 or 4 days with tail vein blood collections at 1, 2, 4, and 8 hours postdose on days 1 and 4. Significantly altered genes were identified in livers of animals following 1 or 4 days of handling when compared to the unhandled animals. Gene changes in animals handled for 4 days were similar to those handled for 1 day, suggesting a lack of habituation. The altered genes were primarily immune function related genes. These findings, along with a correlating increase in corticosterone levels suggest that common handling procedures may cause a minor immune system perturbance.

Gel chromatographic behavior of Tc-99m-labeled compounds in aqueous solution

International Nuclear Information System (INIS)

Suzuki, T.; Wagner, H.N. Jr.; Burns, H.D.; Dannals, F.F.

1984-01-01

The purpose of this study was to elucidate the interaction of Tc-99m-labeled compounds (Tc-99m 0/sub 4/-bar, Tc-99m glucoheptonate, Tc-99m DTPA, Tc-99m disofenin) with the chromatographic gels, to determine their relative molecular sizes and molecular structures in aqueous solution, which are based on their biomenbrane transport mechanism and quality control analysis. Each Tc-99m-labeled compound was eluted and analyzed by three different gel chromatrography systems varying buffers: Sephadex G-25, Sephadex LH-20 and Bio-Gel P-4. The best separation between the elution peaks of all compounds except Tc-99m glucoheptonate was achieved on Sephadex G-25 in methanol-0.025OM Tris-HCL buffer (pH 7.6) (1:1) which could avoid the aromatic interaction with the gels. Tc-99m glucoheptonate was well eluted only on a Bio-Gel P-4 column but its elution peak was not separated from other compounds' peaks. The elution of Tc-99m disofenin was delayed on Sephadex G-25 gel and Bio-Gel P-4 columns in 0.9% NaCl and Tris-HCl buffer(ph 7.6) and on Sephadex LH-20 column in methanol-Tris-HCl buffer, because of the aromatic ring interaction with the gels. The relative molecular size index ( Kav ) calculated from the elution volume of the gel chromatography. Kav of Tc-99m 0/sub 4/-bar(MW=163), Tc-99m DTPA (MW=492?) and TC-99m disofenin (MW=707) on Sephadex G-25 in methanol-0.025OM Tris-HCl buffer(pH 7.6) (1:1), which was the most suitable combination of the gel and the buffer, were 0.976, 0.477 and 0.200, respectively. They inversely correlated with their estimated molecular weight. The interaction of Tc-99m-labeled compounds with the chromatographic gels should be considered in quality control procedure for Tc-99m radiopharamaceuticals

Superphenix 1 primary handling system fabrication and testing

International Nuclear Information System (INIS)

Branchu, J.; Ebbinghaus, K.; Gigarel, C.

1985-01-01

Primary handling covers the operations performed for spent fuel removal, new fuel insertion, and the insodium storage outside the new or spent fuel vessel. This equipment typifies many of the difficulties encountered with the project as a whole: fabrication coordination when several countries are involved and design and construction of very large, relatively complex components. Detailed design studies were mainly influenced by thermal and seismic requirements, as applicable to sodium-immersed structures. Where possible, well-tried mechanical solutions were used, but widely differing techniques were involved, ranging from the high precision fabrication of structures and mechanisms comprising numerous component parts, implying complex machining operations. No particular problems were encountered during the sodium testing of the primary handling equipment. Trends for the 1500-MW (electric) breeder include investigation of the advisability of fuel storage in the core lattice and the possibility of handling system simplification

Cathodic behaviours of a CrO sub 3 -graphite intercalation compound in non-aqueous solutions

Energy Technology Data Exchange (ETDEWEB)

Kurihara, M.; Miura, T.; Kishi, T. (Keio University, Tokyo (Japan). Faculty of Science)

1991-08-05

CrO{sub 3}-graphite intercalation compound (GIC) specimen was prepared by solvent method using acetic acid as a solvent and potassium permanganate as a catalyst, and its cathodic behavior in a lithium cell was studied in non-aqueous solutions (1 mol/dm{sup 3} LiClO{sub 4} in propylene carbonate (PC) or dimethylsulfoxide (DMSO)). Changes in electronic and layered lattice structures induced by cathodic reduction were measured by electron spin resonance method and X-ray diffraction one, respectively. As a result, electrochemical insertion of Li into CrO{sub 3}-GIC proceeded only in DMSO solution where reduction of Cr components was followed by that of graphite units. The amount of discharge electricity for CrO{sub 3}-GIC in DMSO solution was three times as large as that for graphite. Although the effect of non-aqueous solutions on the lithiation reaction was not yet clear fundamentally, it was expected that another electrolyte solutions are probably found out based on this experiments from which Li is inserted into CrO{sub 3}-GIC at higher discharge potentials. 22 refs., 9 figs., 1 tab.

Fuel handling machine and auxiliary systems for a fuel handling cell

International Nuclear Information System (INIS)

Suikki, M.

2013-10-01

This working report is an update for as well as a supplement to an earlier fuel handling machine design (Kukkola and Roennqvist 2006). A focus in the earlier design proposal was primarily on the selection of a mechanical structure and operating principle for the fuel handling machine. This report introduces not only a fuel handling machine design but also auxiliary fuel handling cell equipment and its operation. An objective of the design work was to verify the operating principles of and space allocations for fuel handling cell equipment. The fuel handling machine is a remote controlled apparatus capable of handling intensely radiating fuel assemblies in the fuel handling cell of an encapsulation plant. The fuel handling cell is air tight space radiation-shielded with massive concrete walls. The fuel handling machine is based on a bridge crane capable of traveling in the handling cell along wall tracks. The bridge crane has its carriage provided with a carousel type turntable having mounted thereon both fixed and telescopic masts. The fixed mast has a gripper movable on linear guides for the transfer of fuel assemblies. The telescopic mast has a manipulator arm capable of maneuvering equipment present in the fuel handling cell, as well as conducting necessary maintenance and cleaning operations or rectifying possible fault conditions. The auxiliary fuel handling cell systems consist of several subsystems. The subsystems include a service manipulator, a tool carrier for manipulators, a material hatch, assisting winches, a vacuum cleaner, as well as a hose reel. With the exception of the vacuum cleaner, the devices included in the fuel handling cell's auxiliary system are only used when the actual encapsulation process is not ongoing. The malfunctions of mechanisms or actuators responsible for the motion actions of a fuel handling machine preclude in a worst case scenario the bringing of the fuel handling cell and related systems to a condition appropriate for

Fuel handling machine and auxiliary systems for a fuel handling cell

Energy Technology Data Exchange (ETDEWEB)

Suikki, M. [Optimik Oy, Turku (Finland)

2013-10-15

This working report is an update for as well as a supplement to an earlier fuel handling machine design (Kukkola and Roennqvist 2006). A focus in the earlier design proposal was primarily on the selection of a mechanical structure and operating principle for the fuel handling machine. This report introduces not only a fuel handling machine design but also auxiliary fuel handling cell equipment and its operation. An objective of the design work was to verify the operating principles of and space allocations for fuel handling cell equipment. The fuel handling machine is a remote controlled apparatus capable of handling intensely radiating fuel assemblies in the fuel handling cell of an encapsulation plant. The fuel handling cell is air tight space radiation-shielded with massive concrete walls. The fuel handling machine is based on a bridge crane capable of traveling in the handling cell along wall tracks. The bridge crane has its carriage provided with a carousel type turntable having mounted thereon both fixed and telescopic masts. The fixed mast has a gripper movable on linear guides for the transfer of fuel assemblies. The telescopic mast has a manipulator arm capable of maneuvering equipment present in the fuel handling cell, as well as conducting necessary maintenance and cleaning operations or rectifying possible fault conditions. The auxiliary fuel handling cell systems consist of several subsystems. The subsystems include a service manipulator, a tool carrier for manipulators, a material hatch, assisting winches, a vacuum cleaner, as well as a hose reel. With the exception of the vacuum cleaner, the devices included in the fuel handling cell's auxiliary system are only used when the actual encapsulation process is not ongoing. The malfunctions of mechanisms or actuators responsible for the motion actions of a fuel handling machine preclude in a worst case scenario the bringing of the fuel handling cell and related systems to a condition appropriate for

A Review of Toxicity and Use and Handling Considerations for Guanidine, Guanidine Hydrochloride, and Urea.

Energy Technology Data Exchange (ETDEWEB)

Ertell, Katherine GB

2006-03-27

This is a technical report prepared for Oregon Sustainable Energy, LLC, under Agreement 06-19 with PNNL's Office of Small Business Programs. The request was to perform a review of the toxicity and safe handling of guanidine. The request was later amended to add urea. This report summarizes the toxicity data available in the scientific literature and provides an interpretation of the results and recommendations for handling these compounds.

Photoproduction of hydrogen peroxide in aqueous solution from model compounds for chromophoric dissolved organic matter (CDOM)

International Nuclear Information System (INIS)

Clark, Catherine D.; Bruyn, Warren de; Jones, Joshua G.

2014-01-01

Highlights: • CDOM produces hydrogen peroxide in sunlit surface waters. • Quinone moieties have been proposed as the photo-active chromophore in CDOM. • Hydrogen peroxide is produced in irradiated aqueous quinone solutions. • Concentrations and production rates are comparable to humic and fulvic acids. • Optical properties post-irradiation were similar to CDOM. - Abstract: To explore whether quinone moieties are important in chromophoric dissolved organic matter (CDOM) photochemistry in natural waters, hydrogen peroxide (H 2 O 2 ) production and associated optical property changes were measured in aqueous solutions irradiated with a Xenon lamp for CDOM model compounds (dihydroquinone, benzoquinone, anthraquinone, napthoquinone, ubiquinone, humic acid HA, fulvic acid FA). All compounds produced H 2 O 2 with concentrations ranging from 15 to 500 μM. Production rates were higher for HA vs. FA (1.32 vs. 0.176 mM h −1 ); values ranged from 6.99 to 0.137 mM h −1 for quinones. Apparent quantum yields (Θ app ; measure of photochemical production efficiency) were higher for HA vs. FA (0.113 vs. 0.016) and ranged from 0.0018 to 0.083 for quinones. Dihydroquinone, the reduced form of benzoquinone, had a higher production rate and efficiency than its oxidized form. Post-irradiation, quinone compounds had absorption spectra similar to HA and FA and 3D-excitation–emission matrix fluorescence spectra (EEMs) with fluorescent peaks in regions associated with CDOM

TSTA compound cryopump

International Nuclear Information System (INIS)

Batzer, T.H.; Patrick, R.E.; Call, W.R.

1980-01-01

The Tritium System Test Assembly (TSTA), at the Los Alamos Scientific Laboratory, is intended to demonstrate realistic fuel supply and cleanup scenarios for future fusion reactors. The vacuum pumps must be capable of handling large quantities of reactor exhaust gases consisting largely of mixtures of hydrogen and helium isotopes. Cryocondensing pumps will not pump helium at 4.2 K; while cryosorption pumps using molecular sieves or charcoal have good helium pumping speed, the adsorbent clogs with condensed hydrogen while pumping mixtures of both. A solution to this problem is a compound design whereby the first stage condenses the hydrogen and the second, or sorption, stage pumps the helium. The TSTA pump designed at Lawrence Livermore National Laboratory uses argon gas to cryotrap the helium in the helium-hydrogen mixture. The argon is sprayed directly onto the 4.2 K surface at a rate proportional to the helium flow rate, permitting continuous pumping of the helium-hydrogen mixtures in a single-stage pump. However, the possibility of differential desorption as a first stage in the TSTA gas separation cycle required the inclusion of a first-stage hydrogen isotope condenser. The design, performance, and operating characteristics are discussed

The solubilities of significant organic compounds in HLW tank supernate solutions

International Nuclear Information System (INIS)

Barney, G.S.

1994-08-01

Large quantities of organic chemicals used in reprocessing spent nuclear-fuels at the Hanford Site have accumulated in underground high-level radioactive waste tanks. The organic content of these tanks must he known so that the potential for hazardous reactions between organic components and sodium nitrate/nitrite salts in the waste can he evaluated. The solubilities of organic compounds described in this report will help determine if they are present in the solid phases (salt cake and sludges) as well as the liquid phase (interstitial liquor/supernate) in the tanks. The solubilities of five significant sodium salts of carboxylic acids and aminocarboxylic acids [sodium oxalate, formate, citrate, nitrilotriacetate (NTA) and ethylendiaminetetraacetate (EDTA)] were measured in a simulated supernate solution at 25 degrees C, 30 degrees C, 40 degrees C, and 50 degrees C

Characterization of aerosols in uranium handling facilities and its impact on the assessment of internal dose

International Nuclear Information System (INIS)

Roy, Ankush; Rao, D.D.; Sawant, Pramilla D.; Khan, Arshad; Srinivasan, P.; Chandrashekara, A.

2016-01-01

In nuclear facilities, compounds of uranium such as Magnesium DiUranate (MDU) U 3 O 8 , UO 2 etc. are handled in different stages of operation. There may be a possibility of intake of these compounds by radiation workers during the course of their work. The internal doses received by the workers depend not only on the quantity but also the physiochemical characteristics of the radioactive contaminant. The depositions in different regions of lung of these inhaled aerosols depend on their particle size; whereas the clearance is dependent upon the chemical nature. In this study, aerosol characterization is carried out in four different Uranium Handling Facilities (UF) for realistic assessment of internal dose to the radiation worker

Using accelerometry to quantify prey attack and handling behaviours in piscivorous pike Esox lucius

DEFF Research Database (Denmark)

Deurs, Mikael van; Andersson, A.; Vinterstare, J.

2017-01-01

Accelerometer technology was used to evaluate behaviours in the teleost ambush predator pike Esox lucius foraging on crucian carp Carassius carassius. Automated rule-based estimates of prey-size determined handling time were obtained and are compared with video-recorded behaviours. Solutions to t...... attachment and the limitations imposed by battery-time and data-logging capacities are evaluated......Accelerometer technology was used to evaluate behaviours in the teleost ambush predator pike Esox lucius foraging on crucian carp Carassius carassius. Automated rule-based estimates of prey-size determined handling time were obtained and are compared with video-recorded behaviours. Solutions to tag...

Chemical state analysis of iron(III) compounds precipitated homogeneously from solutions containing urea by means of Moessbauer spectrometry and x-ray diffractometry

International Nuclear Information System (INIS)

Ujihira, Yusuke; Ohyabu, Matashige; Murakami, Tetsuro; Horie, Tsuyoshi.

1978-01-01

Chemical states of iron(III) compounds, precipitated homogeneously by heating the iron(III) salt solution at 363 K in the presence of urea, was studied by means of Moessbauer spectrometry and X-ray diffractometry. The pH-time relation of urea hydrolysis revealed that the precipitation process from homogeneous solution is identical to the hydrolysis of iron(III) ion at pH around 2 under the homogeneous supply of OH - ion, which is generated by hydrolysis of urea. Accordingly, iron(III) oxide hydroxide or similar compounds to the hydrolysis products of iron(III) ion was precipitated by the precipitation from homogeneous solution methods. Akaganeite (β-FeOOH) was crystallized from 0.1 M iron(III) chloride solution. Goethite(α-FeOOH) and hematite(α-Fe 2 O 3 ) was precipitated from 0.1 M iron(III) nitrate solution, vigorous liberation of OH - ion favoring the crystallization of hematite. The addition of chloride ion to the solution resulted in the formation of akaganeite. Basic salt of iron sulfate[NH 4 Fe 3 (OH) 6 (SO 4 ) 2 ] and goethite were formed from 0.1 M iron(III) sulfate solution, the former being obtained in the more moderate condition of the urea hydrolysis ( 363 K). (author)

Remote systems and automation in radioactive waste package handling

International Nuclear Information System (INIS)

Gneiting, B.C.; Hayward, M.L.

1987-01-01

A proof-of-principle test was conducted at the Hanford Engineering Development Laboratory (HEDL) to demonstrate the feasibility of performing cask receiving and unloading operations in a remote and partially automated manner. This development testing showed feasibility of performing critical cask receipt, preparation, and unloading operations from a single control station using remote controls and indirect viewing. Using robotics and remote automation in a cask handling system can result in lower personnel exposure levels and cask turnaround times while maintaining operational flexibility. An automated cask handling system presents a flexible state-of-the-art, cost effective alternative solution to hands-on methods that have been used in the past

Solubility of some phenolic compounds in aqueous alkali metal nitrate solutions from (293.15 to 318.15) K

Energy Technology Data Exchange (ETDEWEB)

Noubigh, Adel [Laboratoire de Physico-chimie des materiaux, IPEST, BP51, 2070 La MARSA (Tunisia)], E-mail: Adel.anoubigh@ipest.rnu.tn; Cherif, Mourad [IPEIEM, Universite de Tunis-El Manar, BP244. 2096. El Manar II (Tunisia); Provost, Elise [Laboratoire Chimie et procedes, ENSTA, 32 Rue de Boulevard Victor, 75739 Paris, Cedex 15 (France); Abderrabba, Manef [Laboratoire de Physico-chimie des materiaux, IPEST, BP51, 2070 La MARSA (Tunisia)

2008-11-15

This paper is continuation of the study concerning the solubility-temperature dependence data for some phenolic compounds (PhC), contained in olive mill wastewater (OMWW), in two nitrate salts (KNO{sub 3} and NaNO{sub 3}) aqueous solutions. The solubilities of PhC were determined in the temperature ranging from (293.15 to 318.15) K. It has been observed that the solubility, in aqueous nitrate solutions, increases with increasing temperature. Results showed that alkali metal nitrate has a salting-out effect on the solubility of PhC. The effect of the anion of the electrolyte on the solubility of PhC is observed by comparing these results with values reported in the previous papers for the effect of LiCl, NaCl and KCl. For each cation, the solubilites of the phenolic compounds are higher with nitrate anion than with chloride anion. Results were interpreted in terms of the salt hydration shells and the ability of the solute to form hydrogen-bond with water. The solubility data were accurately correlated by a semi empirical equation. The standard molar Gibbs free energies of transfer of PhC ({delta}{sub tr}G{sup 0}) from pure water to aqueous solutions of the nitrate salts have been calculated from the solubility data. The decrease in solubility is correlated to the positive {delta}{sub tr}G{sup 0} value which is mainly of enthalpic origin.

Online air analysis of reduced sulfur compounds at a swine facility

Science.gov (United States)

Reduced sulfur compounds are emitted from waste management handling and can be important in odor production and atmospheric chemistry. Data on the emissions of these compounds have been obtained using off-line sampling and analysis methods, but on-line methods providing information on temporal chang...

Posttraining handling facilitates memory for auditory-cue fear conditioning in rats.

Science.gov (United States)

Hui, Isabel R; Hui, Gabriel K; Roozendaal, Benno; McGaugh, James L; Weinberger, Norman M

2006-09-01

A large number of studies have indicated that stress exposure or the administration of stress hormones and other neuroactive drugs immediately after a learning experience modulates the consolidation of long-term memory. However, there has been little investigation into how arousal induced by handling of the animals in order to administer these drugs affects memory. Therefore, the present study examined whether the posttraining injection or handling procedure per se affects memory of auditory-cue classical fear conditioning. Male Sprague-Dawley rats, which had been pre-handled on three days for 1 min each prior to conditioning, received three pairings of a single-frequency auditory stimulus and footshock, followed immediately by either a subcutaneous injection of a vehicle solution or brief handling without injection. A control group was placed back into their home cages without receiving any posttraining treatment. Retention was tested 24 h later in a novel chamber and suppression of ongoing motor behavior during a 10-s presentation of the auditory-cue served as the measure of conditioned fear. Animals that received posttraining injection or handling did not differ from each other but showed significantly less stimulus-induced movement compared to the non-handled control group. These findings thus indicate that the posttraining injection or handling procedure is sufficiently arousing or stressful to facilitate memory consolidation of auditory-cue classical fear conditioning.

Dust prevention in bulk material transportation and handling

Science.gov (United States)

Kirichenko, A. V.; Kuznetsov, A. L.; Pogodin, V. A.

2017-10-01

The environmental problem of territory and atmosphere pollution caused by transportation and handling of dust-generating bulk cargo materials is quite common for the whole world. The reducing of weight of fine class coal caused by air blowing reaches the level of 0.5-0.6 t per railcar over the 500 km transportation distance, which is equal to the loss of 1 % of the total weight. The studies showed that all over the country in the process of the railroad transportation, the industry loses 3-5 metric tonnes of coal annually. There are several common tactical measurers to prevent dust formation: treating the dust-producing materials at dispatch point with special liquid solutions; watering the stacks and open handling points of materials; frequent dust removing and working area cleaning. Recently there appeared several new radical measures for pollution prevention in export of ore and coal materials via sea port terminals, specifically: wind-dust protection screens, the container cargo handling system of delivery materials to the hold of the vessels. The article focuses on the discussion of these measures.

Safety handling of beryllium for fusion technology R and D

International Nuclear Information System (INIS)

Yoshida, Hiroshi; Okamoto, Makoto; Terai, Takayuki; Odawara, Osamu; Ashibe, Kusuo; Ohara, Atsushi.

1992-07-01

Feasibility of beryllium use as a blanket neutron multiplier, first wall and plasma facing material has been studied for the D-T burning experiment reactors such as ITER. Various experimental work of beryllium and its compounds will be performed under the conditions of high temperature and high energy particle exposure simulating fusion reactor conditions. Beryllium is known as a hazardous substance and its handling has been carefully controlled by various health and safe guidances and/or regulations in many countries. Japanese regulations for hazardous substance provide various guidelines on beryllium for the protection of industrial workers and environment. This report was prepared for the safe handling of beryllium in a laboratory scale experiments for fusion technology R and D such as blanket development. Major items in this report are; (1) Brief review of guidances and regulations in USA, UK and Japan. (2) Safe handling and administration manuals at beryllium facilities in INEL, LANL and JET. (3) Conceptual design study of beryllium handling facility for small to mid-scale blanket R and D. (4) Data on beryllium toxicity, example of clinical diagnosis of beryllium disease, and environmental occurence of beryllium. (5) Personnel protection tools of Japanese Industrial Standard for hazardous substance. (author) 61 refs

Current US strategy and technologies for spent fuel handling

International Nuclear Information System (INIS)

Bennett, P.C.; Stringer, J.B.

1999-01-01

The United States Department of Energy has recently completed a topical safety analysis report outlining the design and operation of a Centralized Interim Storage Facility for spent commercial nuclear fuel. During the course of the design, dose assessments indicated the need for remote operation of many of the cask handling operations. Use of robotic equipment was identified as a desirable handling solution that is capable of automating many of the operations to maintain throughput, and sufficiently flexible to handle five or more different storage cask designs in varying numbers on a given day. This paper discusses the facility and the dose assessment leading to this choice, and reviews factors to be considered when choosing robotics or automation. Further, a new computer simulation tool to quantify dose to humans working in radiological environments, the Radiological Environment Modeling System (REMS), is introduced. REMS has been developed to produce a more accurate estimate of dose to radiation workers in new activities with radiological hazards. (author)

A Decomposition Model for HPLC-DAD Data Set and Its Solution by Particle Swarm Optimization

Directory of Open Access Journals (Sweden)

Lizhi Cui

2014-01-01

Full Text Available This paper proposes a separation method, based on the model of Generalized Reference Curve Measurement and the algorithm of Particle Swarm Optimization (GRCM-PSO, for the High Performance Liquid Chromatography with Diode Array Detection (HPLC-DAD data set. Firstly, initial parameters are generated to construct reference curves for the chromatogram peaks of the compounds based on its physical principle. Then, a General Reference Curve Measurement (GRCM model is designed to transform these parameters to scalar values, which indicate the fitness for all parameters. Thirdly, rough solutions are found by searching individual target for every parameter, and reinitialization only around these rough solutions is executed. Then, the Particle Swarm Optimization (PSO algorithm is adopted to obtain the optimal parameters by minimizing the fitness of these new parameters given by the GRCM model. Finally, spectra for the compounds are estimated based on the optimal parameters and the HPLC-DAD data set. Through simulations and experiments, following conclusions are drawn: (1 the GRCM-PSO method can separate the chromatogram peaks and spectra from the HPLC-DAD data set without knowing the number of the compounds in advance even when severe overlap and white noise exist; (2 the GRCM-PSO method is able to handle the real HPLC-DAD data set.

Molecular mechanism of radiosensitization by nitro compounds

International Nuclear Information System (INIS)

Kagiya, T.; Wada, T.; Nishimoto, S.I.

1984-01-01

In this chapter a molecular mechanism of radiosensitization by electron-affinic nitro compounds is discussed, mainly on the basis of the results of the radiation-induced chemical studies of DNA-related compounds in aqueous solutions. In Section II the general aspects of the radiation chemistry of organic compounds in the absence and presence of oxygen in aqueous solution are shown in order to demonstrate characteristic differences between radiation chemical reactions in hypoxic and oxic cells. The effects of nitro compounds on the radiolysis yields of DNA-related compounds in aqueous solutions are described in Section III. In Section IV the retardation effects of misonidazole on the radiation chemical processes of DNA-related compounds are shown along with the reaction characteristics of misonidazole with hydroxyl radical ( . OH) and hydrated electron (e/sub aq/-bar) produced by the radiolysis of water. The promotion of radiation-induced oxidation of thymine into thymine glycol (TG) by nitro radiosensitizers in deoxygenated solution and the relations between the activity of nitro compound for the thymine glycol formation and the enhancement activity measured in vitro are described in Section V. Finally, the protection against radiation-induced damage of thymine by a sulfhydryl compound of glutathione and the ability of electron-affinic compounds to decompose the intracellular radioprotector are described in Section VI

Remote systems and automation in radioactive waste package handling

International Nuclear Information System (INIS)

Gneiting, B.C.; Hayward, M.L.

1987-01-01

A proof-of-principle test was conducted at the Hanford Engineering Development Laboratory (HEDL) to demonstrate the feasibility of performing cask receiving and unloading operations in a remote and partially automated manner. This development testing showed feasibility of performing critical cask receipt, preparation, and unloading operations from a single control station using remote controls and indirect viewing. Using robotics and remote automation in a cask handling system can result in lower personnel exposure levels and cask turnaround times while maintaining operational flexibility. An automated cask handling system presents a flexible state-of-the-art, cost effective alternative solution to hands-on methods that have been used in the past. 7 refs., 13 figs

Technical session 4: Health and safety issues. Working environment control in beryllium handling area

International Nuclear Information System (INIS)

Yonehara, K.; Natori, Y.; Tatenuma, K.; Nakamichi, Masaru

2016-01-01

Beryllium (Be) and its intermetallic compound (beryllide) are recommended from Japan as the most promising solid neutron multiplier for nuclear fusion power plant. The shape as the neutron multiplier is small sphere (pebble), and the mass production technology of it must be developed urgently. Beryllium is the substance regulated by the law of Ordinance on Prevention of Hazards Due to Specified the Chemical Substances Control. We'll report on a way of the operational environmental management to make a safe Be handling area for the Be handling researchers and workers. (author)

Handling of multiassembly sealed baskets between reactor storage and a remote handling facility

International Nuclear Information System (INIS)

Massey, J.V.; Kessler, J.H.; McSherry, A.J.

1989-06-01

The storage of multiple fuel assemblies in sealed (welded) dry storage baskets is gaining increasing use to augment at-reactor fuel storage capacity. Since this increasing use will place a significant number of such baskets on reactor sites, some initial downstream planning for their future handling scenarios for retrieving multi-assembly sealed baskets (MSBs) from onsite storage and transferring and shipping the fuel (and/or the baskets) to a federally operated remote handling facility (RHF). Numerous options or at-reactor and away-from-reactor handling were investigated. Materials handling flowsheets were developed along with conceptual designs for the equipment and tools required to handle and open the MSBs. The handling options were evaluated and compared to a reference case, fuel handling sequence (i.e., fuel assemblies are taken from the fuel pool, shipped to a receiving and handling facility and placed into interim storage). The main parameters analyzed are throughout, radiation dose burden and cost. In addition to evaluating the handling of MSBs, this work also evaluated handling consolidated fuel canisters (CFCs). In summary, the handling of MSBs and CFCs in the store, ship and bury fuel cycle was found to be feasible and, under some conditions, to offer significant benefits in terms of throughput, cost and safety. 14 refs., 20 figs., 24 tabs

Nuclear fuel handling apparatus

International Nuclear Information System (INIS)

Andrea, C.; Dupen, C.F.G.; Noyes, R.C.

1977-01-01

A fuel handling machine for a liquid metal cooled nuclear reactor in which a retractable handling tube and gripper are lowered into the reactor to withdraw a spent fuel assembly into the handling tube. The handling tube containing the fuel assembly immersed in liquid sodium is then withdrawn completely from the reactor into the outer barrel of the handling machine. The machine is then used to transport the spent fuel assembly directly to a remotely located decay tank. The fuel handling machine includes a decay heat removal system which continuously removes heat from the interior of the handling tube and which is capable of operating at its full cooling capacity at all times. The handling tube is supported in the machine from an articulated joint which enables it to readily align itself with the correct position in the core. An emergency sodium supply is carried directly by the machine to provide make up in the event of a loss of sodium from the handling tube during transport to the decay tank. 5 claims, 32 drawing figures

Characterization of some electronic spectral parameters for doped Nd (III) ion in saturated aqueous solution of some pharmaceutical compounds

International Nuclear Information System (INIS)

Naulakha, Neelam; Soni, K.P.; Bhati, P.R.

2000-01-01

The stereo-environment of doped Nd(III) ion in various saturated solutions of some medicinal compounds has been studied for various electronic spectral parameters. The various electronic parameters, viz., Slater Condon (F k ), Lande (ζ 4f ) intensity of hypersensitive band ( 4 G 5/2 ), bonding parameter (b 1/2 ), Judd-Ofelt parameter (Tλ) and Racah parameter (E k ) for Nd(III) ion doped in saturated solution of diphenylhydramine, tripelennamine, chlorophenaramine, promethazine, terfinadine, naproxen, fenoprofen, flurbiprofen, oxaprozine, ketoprofen and ibuprofen have been studied. (author)

Study and Evaluation of Innovative Fuel Handling Systems for Sodium-Cooled Fast Reactors: Fuel Handling Route Optimization

Directory of Open Access Journals (Sweden)

Franck Dechelette

2014-01-01

Full Text Available The research for technological improvement and innovation in sodium-cooled fast reactor is a matter of concern in fuel handling systems in a view to perform a better load factor of the reactor thanks to a quicker fuelling/defueling process. An optimized fuel handling route will also limit its investment cost. In that field, CEA has engaged some innovation study either of complete FHR or on the optimization of some specific components. This paper presents the study of three SFR fuel handling route fully described and compared to a reference FHR option. In those three FHR, two use a gas corridor to transfer spent and fresh fuel assembly and the third uses two casks with a sodium pot to evacuate and load an assembly in parallel. All of them are designed for the ASTRID reactor (1500 MWth but can be extrapolated to power reactors and are compatible with the mutualisation of one FHS coupled with two reactors. These three concepts are then intercompared and evaluated with the reference FHR according to four criteria: performances, risk assessment, investment cost, and qualification time. This analysis reveals that the “mixed way” FHR presents interesting solutions mainly in terms of design simplicity and time reduction. Therefore its study will be pursued for ASTRID as an alternative option.

Pharmaceutical Compounds in Wastewater: Wetland Treatment as a Potential Solution

OpenAIRE

White, John R.; Belmont, Marco A.; Metcalfe, Chris D.

2006-01-01

Pharmaceutical compounds are being released into the aquatic environment through wastewater discharge around the globe. While there is limited removal of these compounds within wastewater treatment plants, wetland treatment might prove to be an effective means to reduce the discharge of the compounds into the environment. Wetlands can promote removal of these pharmaceutical compounds through a number of mechanisms including photolysis, plant uptake, microbial degradation, and sorption to the ...

Critical experiments for large scale enriched uranium solution handling

International Nuclear Information System (INIS)

Tanner, J.E.; Forehand, H.M.

1985-01-01

The authors have performed 17 critical experiments with a concentrated aqueous uranyl nitrate solution contained in an annular cylindrical tank, with annular cylindrical absorbers of stainless steel and/or polyethylene inside. k/sub eff/ calculated by KENO IV, employing 16-group Hansen-Roach cross sections, average 0.977. There is a variation of the calculational bias among the separate experiments, but it is too small to allow assigning it to specific components of the equipment. They are now performing critical experiments with a more concentrated uranyl nitrate solution in pairs of very squat cylindrical tanks with disc shaped absorbers and reflectors of carbon steel, stainless steel, nitronic-50, plain and borated polyethylene. These experiments are in support of upgrading fuel reprocessing at the Idaho Chemical Processing Plant

Observations on human-technology interaction aspects in remote handling for fusion

International Nuclear Information System (INIS)

Salminen, Karoliina

2009-01-01

Remote handling can been seen as cooperation between human and machine. One of the characteristics of remote handling is that there is always a human involved in the technique: there is always a human guiding and supervising the movements and deciding the actions of the machine. Unlike many other fields of remote handling for fusion, the human-technology interaction side has not been studied carefully recently. The state-of-the-art research about different kinds of remote handling systems shows that there is a lot of information available in this subject, but there is a clear need for studies where the special needs of ITER are taken into account. During the PREFIT programme, the human-interaction aspects of remote handling have been studied, and the goal has been to find solutions compatible with ITER. Some of the aspects that make ITER a unique system are its new technology combining state-of-the-art knowledge from several different fields, and its very international working environment. When discussing the human aspects, the fact of the multinational cooperation cannot be neglected. Since the majority of the information found in the literature review is not about remote handling, references need to be taken from other industries, like aviation. This article consists of ITER remote handling relevant findings in state-of-the-art research and information and knowledge gained during the PREFIT programme, especially during the training periods at JET in Culham and at CEA in Fontenay-aux-Roses. It also discusses the importance of human-technology interaction field in remote handling, especially in ITER.

Removal of 4-Ethylphenol and 4-Ethylguaiacol with Polyaniline-Based Compounds in Wine-Like Model Solutions and Red Wine

Directory of Open Access Journals (Sweden)

Verónica Carrasco-Sánchez

2015-08-01

Full Text Available Volatile phenols, such as 4-ethyphenol (4-EP and 4-ethylguaiacol (4-EG, are responsible for the “Brett character” found in wines contaminated with Brettanomyces yeast (i.e., barnyard, animal, spicy and smoky aromas. In these trials, we explore the effectiveness of polyaniline-based compounds (polyaniline emeraldin salt (PANI-ES and polyanaline emeraldin base (PANI-EB, for the removal of 4-EP and 4-EG from acidic model solutions and red wine. First, a screening study, performed in an acidified 12% ethanol solution, was used to optimize parameters such as contact time and the amount of polymers required to remove 4-EP and 4-EG. Then, the trapping ability of PANI agents towards 4-EP and 4-EG was evaluated in a model solution containing other wine phenolics that could potentially be trapped by PANI (i.e., gallic acid and 4-methylcatechol. The results of this trial showed that both PANI compounds were capable of removing 4-EP, 4-EG, regardless of the presence of other phenolic compounds present at a much higher concentration. Finally, the capturing ability of PANI was evaluated in a red wine sample containing 5 mg·L−1 of 4-EP, 5 mg·L−1 of 4-EG and 2.03 ± 0.02 g·L−1 of total phenolics. The results showed that PANI-EB removed significantly more 4-EP and 4-EG than PANI-ES. For instance, a treatment with 10 mg·mL−1 of PANI-EB produced a 67.8% reduction of 4-EP, 50% reduction of 4-EG and 41.38% decrease in total phenols.

[New-type electrodeless excilamp for advanced treatment on nitrogen-heterocyclic compounds (NHCs) in aqueous solution].

Science.gov (United States)

Ye, Zhao-Lian; Wang, Bin; Lu, Juan-Juan; Li, Feng; Zhang, Ren-Xi

2012-03-01

A novel 206 nm excilamp generated by microwave-driven Kr/I2 mixtures was employed for nitrogen-heterocyclic compounds (NHCs) degradation in aqueous solution. The photodissociation efficiencies of indole and quinoline with 206 nm excilamp were estimated on the basis of removal efficiency of targeted compounds and the loss of total organic carbon (TOC). The results indicated that removal efficiency of 20 mg x L(-1) indole was as high as 62.0% after 80 min and TOC loss efficiency of 50.7% for 150 min. The irradiation time, initial concentration and pH value had some influences on quinoline degradation. Indole removal efficiency and TOC loss was markedly higher than that of quinoline under the same condition. The intermediates were identified qualitatively by gas chromatography/mass spectrum (GC/MS) with headspace sampling after they were extracted by rotary evaporator. GC/MS analysis indicated that indole and quinoline underwent ring-open dissociation under 206 nm irradiation, as a result, benzene, xylene, acetate, aldehyde, as well as ester compounds were formed, while indole aggregation reaction occurred during indole photodegradation. At last, degradation mechanisms of quinoline and indole in aqueous media with 206 nm excilamp were proposed on the basis of intermediates.

Haptic shared control improves hot cell remote handling despite controller inaccuracies

NARCIS (Netherlands)

van Oosterhout, J.; Abbink, D. A.; Koning, J. F.; Boessenkool, H.; Wildenbeest, J. G. W.; Heemskerk, C. J. M.

2013-01-01

A promising solution to improve task performance in ITER hot cell remote handling is the use of haptic shared control. Haptic shared control can assist the human operator along a safe and optimal path with continuous guiding forces from an intelligent autonomous controller. Previous research tested

Pharmaceutical Compounds in Wastewater: Wetland Treatment as a Potential Solution

Directory of Open Access Journals (Sweden)

John R. White

2006-01-01

Full Text Available Pharmaceutical compounds are being released into the aquatic environment through wastewater discharge around the globe. While there is limited removal of these compounds within wastewater treatment plants, wetland treatment might prove to be an effective means to reduce the discharge of the compounds into the environment. Wetlands can promote removal of these pharmaceutical compounds through a number of mechanisms including photolysis, plant uptake, microbial degradation, and sorption to the soil. We review relevant laboratory research on these various mechanisms and provide data on the few studies that have examined wetland removal. There is a need to document the degree to which various pharmaceutical compounds are removed in full-scale treatment wetlands, as there is a paucity of data on overall pharmaceutical removal rates.

Traditional and New methods for the Preparation of Diazocarbonyl Compounds

Directory of Open Access Journals (Sweden)

ANTONIO C.B. BURTOLOSO

2018-04-01

Full Text Available ABSTRACT For many years diazocarbonyl compounds have been studied due to their versatility and usability in many chemical transformations. In this review, we summarize the traditional methods to prepare these compounds as well as the new methods and recent improvements in experimental procedures. Moreover, emergence of continuous flow techniques has allowed safer and environmentally friendly procedures for the handling of diazomethane and diazo compounds and will also be a topic in this review.

Photoproduction of hydrogen peroxide in aqueous solution from model compounds for chromophoric dissolved organic matter (CDOM).

Science.gov (United States)

Clark, Catherine D; de Bruyn, Warren; Jones, Joshua G

2014-02-15

To explore whether quinone moieties are important in chromophoric dissolved organic matter (CDOM) photochemistry in natural waters, hydrogen peroxide (H2O2) production and associated optical property changes were measured in aqueous solutions irradiated with a Xenon lamp for CDOM model compounds (dihydroquinone, benzoquinone, anthraquinone, napthoquinone, ubiquinone, humic acid HA, fulvic acid FA). All compounds produced H2O2 with concentrations ranging from 15 to 500 μM. Production rates were higher for HA vs. FA (1.32 vs. 0.176 mM h(-1)); values ranged from 6.99 to 0.137 mM h(-1) for quinones. Apparent quantum yields (Θ app; measure of photochemical production efficiency) were higher for HA vs. FA (0.113 vs. 0.016) and ranged from 0.0018 to 0.083 for quinones. Dihydroquinone, the reduced form of benzoquinone, had a higher production rate and efficiency than its oxidized form. Post-irradiation, quinone compounds had absorption spectra similar to HA and FA and 3D-excitation-emission matrix fluorescence spectra (EEMs) with fluorescent peaks in regions associated with CDOM. Copyright © 2014 Elsevier Ltd. All rights reserved.

Device for analyzing a solution

International Nuclear Information System (INIS)

Marchand, Joseph.

1978-01-01

The device enables a solution containing an antigen to be analyzed by the radio-immunology technique without coming up against the problems of antigen-antibody complex and free antigen separation. This device, for analyzing a solution containing a biological compound capable of reacting with an antagonistic compound specific of the biological compound, features a tube closed at its bottom end and a component set and immobilized in the bottom of the tube so as to leave a capacity between the bottom of the tube and its lower end. The component has a large developed surface and is so shaped that it allows the solution to be analyzed to have access to the bottom of the tube; it is made of a material having some elastic deformation and able to take up a given quantity of the biological compound or of the antagonistic compound specific of the biological compound [fr

On current US strategy and technologies for spent fuel handling

International Nuclear Information System (INIS)

Bennett, P.C.

1997-01-01

The US Department of Energy has recently completed a topical safety analysis report outlining the design and operation of a Centralized Interim Storage Facility for spent commercial nuclear fuel. During the course of the design, dose assessments indicated the need for remote operation of many of the cask handling operations. Use of robotic equipment was identified as a desirable handling solution that is capable of automating many of the operations to maintain throughput, and sufficiently flexible to handle five or more different storage cask designs in varying numbers on a given day. This paper discusses the facility and the dose assessment leading to this choice, and reviews factors to be considered when choosing robotics or automation. Further, a new computer simulation tool to quantify dose to humans working in radiological environments, the Radiological Environment Modeling System (REMS), is introduced. REMS has been developed to produce a more accurate estimate of dose to radiation workers in new activities with radiological hazards

The solvent extraction of zinc, iron, and indium from chloride solutions by neutral organophosphorus compounds

International Nuclear Information System (INIS)

Preston, J.S.; Du Preez, A.C.

1985-01-01

The preparation of several neutral organophosphorus compounds and their evaluation as selective extractants for zinc in chloride media are described. The compounds belong to the series trialkyl phosphates (RO) 3 PO, dialkyl alkylphosphonates R'PO(OR) 2 , alkyl dialkylphosphinates R 2 'PO(OR), and trialkyl-phosphine oxides R 3 'PO. They were characterized by measurement of their physical properties (melting and boiling points, refractive indices, and densities), and their purities were confirmed by osmometric determination of their molecular masses; by carbon and hydrogen microanalysis; by the titrimetric determination of acidic impurities; and, for liquid products, by comparison of their experimental molar refractivities with empirical values. Metal-distribution equilibria were determined for solutions of the extractants in xylene and aqueous phase containing 0,5 to 5,0 M sodium chloride. Moderately good selectivities were shown for zinc(II) over iron(III), and excellent selectivities were shown for zinc(II) over iron(II), copper(II), lead(II), and cadmium(II). The extraction of indium(III) was similar to that of zinc(II). The extraction of zinc(III), iron(III), and indium(III) increased markedly through the series. (RO) 3 PO 2 2 'PO(OR) 3 'PO. The incorporation of phenyl groups into the compounds led to weaker extraction. The extracted complexes of zinc(II), iron(III), and indium(III) have the stoichiometries ZnCl 2 L 2 ,FeCl 3 L 2 (H 2 O), and InCl 3 L 2 (H 2 O) respectively, where L represents the neutral organophosphorus compound

Drilling solutions developed on organo-silicon compounds

Energy Technology Data Exchange (ETDEWEB)

Belov, V P

1981-01-01

Confirms the positive effect of polymers on various clay solutions, including heavy barite, over a wide range of temperatures. Depending on the mineralogical composition of the solid phase of the solution and its level of mineralization, these substances may be used as reagent-stabilizers or viscosity reducers and, in certain instances, as combined-action reagents.

Compounds in dictionary-based Cross-language information retrieval_revised

Directory of Open Access Journals (Sweden)

2002-01-01

Full Text Available Compound words form an important part of natural language. From the cross-lingual information retrieval (CLIR point of view it is important that many natural languages are highly productive with compounds, and translation resources cannot include entries for all compounds. Also, compounds are often content bearing words in a sentence. In Swedish, German and Finnish roughly one tenth of the words in a text prepared for information retrieval purposes are compounds. Important research questions concerning compound handling in dictionary-based cross-language information retrieval are 1 compound splitting into components, 2 normalisation of components, 3 translation of components and 4 query structuring for compounds and their components in the target language. The impact of compound processing on the performance of the cross-language information retrieval process is evaluated in this study and the results indicate that the effect is clearly positive.

Proposal for intake model for workers at IPEN-CNEN/SP who handle 131 I

International Nuclear Information System (INIS)

Todo, A.S.; Potiens Junior, A.J.; Gaburo, J.C.; Sanches, M.P.; Oliveira, E.M.

1997-01-01

The intake model for the two groups of workers at IPEN-CNEN/SP is presented. They handle iodine compounds during the processing of irradiated targets and at labeling of radiopharmaceutical compounds. The intake model for the workers are proposed from the knowledge of the activities carried out in the plant and the internal monitoring program of the workers. In this study, the intake is considered to be taken uniformly during the days of major activities carried out by the workers. In practice, the application of this model has be shown suitable, for the studied groups

Method for purifying bidentate organophosphorus compounds

International Nuclear Information System (INIS)

Schulz, W.W.

1977-01-01

Bidentate organophosphorus compounds useful for extracting actinide elements from acidic nuclear waste solutions are purified of undesirable acidic impurities by contacting the compounds with ethylene glycol which preferentially extracts the impurities found in technical grade bidentate compounds

Recommendations for cask features for robotic handling from the Advanced Handling Technology Project

International Nuclear Information System (INIS)

Drotning, W.

1991-02-01

This report describes the current status and recent progress in the Advanced Handling Technology Project (AHTP) initiated to explore the use of advanced robotic systems and handling technologies to perform automated cask handling operations at radioactive waste handling facilities, and to provide guidance to cask designers on the impact of robotic handling on cask design. Current AHTP tasks have developed system mock-ups to investigate robotic manipulation of impact limiters and cask tiedowns. In addition, cask uprighting and transport, using computer control of a bridge crane and robot, were performed to demonstrate the high speed cask transport operation possible under computer control. All of the current AHTP tasks involving manipulation of impact limiters and tiedowns require robotic operations using a torque wrench. To perform these operations, a pneumatic torque wrench and control system were integrated into the tool suite and control architecture of the gantry robot. The use of captured fasteners is briefly discussed as an area where alternative cask design preferences have resulted from the influence of guidance for robotic handling vs traditional operations experience. Specific robotic handling experiences with these system mock-ups highlight a number of continually recurring design principles: (1) robotic handling feasibility is improved by mechanical designs which emphasize operation with limited dexterity in constrained workspaces; (2) clearances, tolerances, and chamfers must allow for operations under actual conditions with consideration for misalignment and imprecise fixturing; (3) successful robotic handling is enhanced by including design detail in representations for model-based control; (4) robotic handling and overall quality assurance are improved by designs which eliminate the use of loose, disassembled parts. 8 refs., 15 figs

Solution microcalorimeter for measuring heats of solution of radioactive elements and compounds

International Nuclear Information System (INIS)

Raschella, D.L.

1978-12-01

The microcalorimeter vessel is constructed of tantalum metal, with a nominal volume of 5 cm 3 . Its energy equivalent is 24 J K -1 when containing 5 cm 3 H 2 O. The thermal leakage modulus is 0.010 min -1 . A thermistor is employed as the temperature sensor. The operating sensitivity is about 1 x 10 -5 K (300 μJ). The performance of the calorimetry system was tested using tris(hydroxymethyl)aminomethane (TRIS) and magnesium metal. The results of the TRIS experiments, at a concentration of 1 g dm -3 in 0.1 N HCl at 298 K, yielded a heat of solution of -29.606 +- 0.063 kJ mol -1 . The magnesium experiments, in 1 N HCl at 298 K, gave a heat of solution of -465.965 +- 1.136 kJ mol -1 . The heat of solution of curium-248 metal in 1 N HCl at 298 K was measured. The experiments, which should not be considered definitive, yielded a heat of solution of -606.4 +- 1.8 kJ mol -1 . A single measurement in 6 N HCl gave a heat of solution of -602.3 kJ mol -1 . From these results the heat of formation of Cm 3+ /sub (aq)/ is calculated to be -607.2 +- 2.5 kJ mol -1

The route from problem to solution in multistep continuous flow synthesis of pharmaceutical compounds.

Science.gov (United States)

Bana, Péter; Örkényi, Róbert; Lövei, Klára; Lakó, Ágnes; Túrós, György István; Éles, János; Faigl, Ferenc; Greiner, István

2017-12-01

Recent advances in the field of continuous flow chemistry allow the multistep preparation of complex molecules such as APIs (Active Pharmaceutical Ingredients) in a telescoped manner. Numerous examples of laboratory-scale applications are described, which are pointing towards novel manufacturing processes of pharmaceutical compounds, in accordance with recent regulatory, economical and quality guidances. The chemical and technical knowledge gained during these studies is considerable; nevertheless, connecting several individual chemical transformations and the attached analytics and purification holds hidden traps. In this review, we summarize innovative solutions for these challenges, in order to benefit chemists aiming to exploit flow chemistry systems for the synthesis of biologically active molecules. Copyright © 2016 Elsevier Ltd. All rights reserved.

The claims handling process of liability insurance in South Africa

Directory of Open Access Journals (Sweden)

Jacoline van Jaarsveld

2015-04-01

Full Text Available Liabilities play a very important financial role in business operations, professional service providers as well as in the personal lives of people. It is possible that a single claim may even lead to the bankruptcy of the defendant. The claims handling process of liability insurance by short-term insurers is therefore very important to these parties as it should be clear that liability claims may have enormous and far-reaching financial implications for them. The objective of this research paper embodies the improvement of financial decision-making by short-term insurers with regard to the claims handling process of liability insurance. Secondary data was initially studied which provided the basis to compile a questionnaire for the empirical survey. The leaders of liability insurance in the South African short-term insurance market that represented 69.5% of the annual gross written premiums received for liability insurance in South Africa were the respondents of the empirical study. The perceptions of these short-term insurers provided the primary data for the vital conclusions of this research. This paper pays special attention to the importance of the claims handling factors of liability insurance, how often the stipulations of liability insurance policies are adjusted by the short-term insurers to take the claims handling factors into consideration, as well as the problem areas which short-term insurers may experience during the claims handling process. Feasible solutions to address the problem areas are also discussed.

Biosorption of Phenolic Compounds from Aqueous Solutions using Pine (Pinus densiflora Sieb Bark Powder

Directory of Open Access Journals (Sweden)

Siva Kumar Nadavala

2014-07-01

Full Text Available The present study describes the development of a new bioadsorbent from lignocellulosic wastes of agricultural origin. The biosorption capacity of an agricultural solid waste, pine bark (Pinus densiflora Sieb., to remove phenolic compounds (phenol, 2-chlorophenol (2-CPh, and 4- chlorophenol (4-CPh from aqueous solutions under batch equilibrium conditions was investigated. The morphological characteristics of the biosorbent were evaluated by BET surface area analysis, Fourier transform infrared spectroscopy (FTIR, elemental analysis, an X-ray diffractometer (XRD, and a scanning electron microscope (SEM. Batch experiments were conducted to investigate the effect of initial pH (2 to 10, contact time, initial concentration of adsorbate (50 to 200 mg/L, and biosorbent dosage. The biosorption of phenolic compounds decreased with increasing pH, and the highest biosorption capacity was achieved at a pH of 6.0. Biosorption equilibrium was established in 120 min. The biosorption equilibrium data were fitted and analyzed with Langmuir, Freundlich, and Dubinin-Radushkevich isotherm equations, as well as four adsorption kinetic models. The kinetics data fitted well into the pseudo-second-order kinetic model, with a correlation coefficient greater than 0.993. The maximum monolayer biosorption capacity of pine bark for phenol, 2-CPh, and 4-CPh was found to be 142.85, 204.08, and 263.15 mg/g, respectively, as calculated by the Langmuir model at 30 ± 1 °C. Pine bark could be used as a new effective, low-cost biosorbent material with good uptake capacity and rapid kinetics for the removal of phenolic compounds from aqueous media.

Surface modification of polystyrene with atomic oxygen radical anions-dissolved solution

International Nuclear Information System (INIS)

Wang Lian; Yan Lifeng; Zhao Peitao; Torimoto, Yoshifumi; Sadakata, Masayoshi; Li Quanxin

2008-01-01

A novel approach to surface modification of polystyrene (PS) polymer with atomic oxygen radical anions-dissolved solution (named as O - water) has been investigated. The O - water, generated by bubbling of the O - (atomic oxygen radical anion) flux into the deionized water, was characterized by UV-absorption spectroscopy and electron paramagnetic resonance (EPR) spectroscopy. The O - water treatments caused an obvious increase of the surface hydrophilicity, surface energy, surface roughness and also caused an alteration of the surface chemical composition for PS surfaces, which were indicated by the variety of contact angle and material characterization by atomic force microscope (AFM) imaging, field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), and attenuated total-reflection Fourier transform infrared (ATR-FTIR) measurements. Particularly, it was found that some hydrophilic groups such as hydroxyl (OH) and carbonyl (C=O) groups were introduced onto the polystyrene surfaces via the O - water treatment, leading to the increases of surface hydrophilicity and surface energy. The active oxygen species would react with the aromatic ring molecules on the PS surfaces and decompose the aromatic compounds to produce hydrophilic hydroxyl and carbonyl compounds. In addition, the O - water is also considered as a 'clean solution' without adding any toxic chemicals and it is easy to be handled at room temperature. Present method may suit to the surface modification of polymers and other heat-sensitive materials potentially

Radiation-induced nitration of organic compounds in aqueous solutions

International Nuclear Information System (INIS)

Ershov, B.G.; Gordeev, A.V.; Bykov, G.L.; Moisy, P.

2012-01-01

Radiolysis in aqueous nitrate and acetic acid solutions and nitrate/nitric acid and phenol was studied. The radiolysis of these solutes occurs with circle NO 2 radical, which is the active nitrating agent. Accumulation of nitromethane and nitrite was determined during γ-irradiation of aqueous solutions containing acetic and nitrate solutions. Irradiation of aqueous phenol-nitrate/nitric acid solutions results in the formation of 2- and 4-nitrophenols.

Radiation-induced nitration of organic compounds in aqueous solutions

Energy Technology Data Exchange (ETDEWEB)

Ershov, B.G.; Gordeev, A.V.; Bykov, G.L. [Russian Academy of Sciences, Moscow (Russian Federation). Frumkin Inst. of Physical Chemistry and Electrochemistry; Moisy, P. [CEA, Bagnols sur Ceze (France). Nuclear Energy Div.

2012-07-01

Radiolysis in aqueous nitrate and acetic acid solutions and nitrate/nitric acid and phenol was studied. The radiolysis of these solutes occurs with {sup circle} NO{sup 2} radical, which is the active nitrating agent. Accumulation of nitromethane and nitrite was determined during {gamma}-irradiation of aqueous solutions containing acetic and nitrate solutions. Irradiation of aqueous phenol-nitrate/nitric acid solutions results in the formation of 2- and 4-nitrophenols.

Experimental investigation of the impact of compound-specific dispersion and electrostatic interactions on transient transport and solute breakthrough

Science.gov (United States)

Muniruzzaman, Muhammad; Rolle, Massimo

2017-02-01

This study investigates the effects of compound-specific diffusion/dispersion and electrochemical migration on transient solute transport in saturated porous media. We conducted laboratory bench-scale experiments, under advection-dominated regimes (seepage velocity: 0.5, 5, 25 m/d), in a quasi two-dimensional flow-through setup using pulse injection of multiple tracers (both uncharged and ionic species). Extensive sampling and measurement of solutes' concentrations (˜1500 samples; >3000 measurements) were performed at the outlet of the flow-through setup, at high spatial and temporal resolution. The experimental results show that compound-specific effects and charge-induced Coulombic interactions are important not only at low velocities and/or for steady state plumes but also for transient transport under high flow velocities. Such effects can lead to a remarkably different behavior of measured breakthrough curves also at very high Péclet numbers. To quantitatively interpret the experimental results, we used four modeling approaches: classical advection-dispersion equation (ADE), continuous time random walk (CTRW), dual-domain mass transfer model (DDMT), and a multicomponent ionic dispersion model. The latter is based on the multicomponent formulation of coupled diffusive/dispersive fluxes and was used to describe and explain the electrostatic effects of charged species. Furthermore, we determined experimentally the temporal profiles of the flux-related dilution index. This metric of mixing, used in connection with the traditional solute breakthrough curves, proved to be useful to correctly distinguish between plume spreading and mixing, particularly for the cases in which the sole analysis of integrated concentration breakthrough curves may lead to erroneous interpretation of plume dilution.

The handling of data from experiments

CERN Document Server

Davies, H E

1974-01-01

The use of small computers in on-line experiments in high-energy physics is briefly indicated. The requirement for an above-average performance (data-handling rates up to 1.5 Mbit/sec) is described, emphasizing the problem of data acquisition; data rates and buffering, data storage, and the importance of flexibility are dealt with. The discussion of hardware solutions to the special problems posed by on- line experiments includes the use of CAMAC interfaces, systems of linked computers, and the use of special processors which perform the first steps of data analysis very rapidly. A section on the software solution to data acquisition problems treats the requirements for flexibility and ease of use, giving as an example a comparison of a manufacturer-supplied Editor and CERN's ORION Editor, and concludes with an outline of the need for direct access to more powerful computers, giving as an illustration the FOCUS and Omega/SFM networks. (0 refs).

Advanced robotics handling and controls applied to Mixed Waste characterization, segregation and treatment

International Nuclear Information System (INIS)

Grasz, E.; Huber, L.; Horvath, J.; Roberson, P.; Wilhelmsen, K.; Ryon, R.

1994-11-01

At Lawrence Livermore National Laboratory under the Mixed Waste Operations program of the Department of Energy Robotic Technology Development Program (RTDP), a key emphasis is developing a total solution to the problem of characterizing, handling and treating complex and potentially unknown mixed waste objects. LLNL has been successful at looking at the problem from a system perspective and addressing some of the key issues including non-destructive evaluation of the waste stream prior to the materials entering the handling workcell, the level of automated material handling required for effective processing of the waste stream objects (both autonomous and tele-operational), and the required intelligent robotic control to carry out the characterization, segregation, and waste treating processes. These technologies were integrated and demonstrated in a prototypical surface decontamination workcell this past year

SaaS Platform for Time Series Data Handling

Science.gov (United States)

Oplachko, Ekaterina; Rykunov, Stanislav; Ustinin, Mikhail

2018-02-01

The paper is devoted to the description of MathBrain, a cloud-based resource, which works as a "Software as a Service" model. It is designed to maximize the efficiency of the current technology and to provide a tool for time series data handling. The resource provides access to the following analysis methods: direct and inverse Fourier transforms, Principal component analysis and Independent component analysis decompositions, quantitative analysis, magnetoencephalography inverse problem solution in a single dipole model based on multichannel spectral data.

An Investigation of Large Tilt-Rotor Hover and Low Speed Handling Qualities

Science.gov (United States)

Malpica, Carlos A.; Decker, William A.; Theodore, Colin R.; Lindsey, James E.; Lawrence, Ben; Blanken, Chris L.

2011-01-01

A piloted simulation experiment conducted on the NASA-Ames Vertical Motion Simulator evaluated the hover and low speed handling qualities of a large tilt-rotor concept, with particular emphasis on longitudinal and lateral position control. Ten experimental test pilots evaluated different combinations of Attitude Command-Attitude Hold (ACAH) and Translational Rate Command (TRC) response types, nacelle conversion actuator authority limits and inceptor choices. Pilots performed evaluations in revised versions of the ADS-33 Hover, Lateral Reposition and Depart/Abort MTEs and moderate turbulence conditions. Level 2 handling qualities ratings were primarily recorded using ACAH response type in all three of the evaluation maneuvers. The baseline TRC conferred Level 1 handling qualities in the Hover MTE, but there was a tendency to enter into a PIO associated with nacelle actuator rate limiting when employing large, aggressive control inputs. Interestingly, increasing rate limits also led to a reduction in the handling qualities ratings. This led to the identification of a nacelle rate to rotor longitudinal flapping coupling effect that induced undesired, pitching motions proportional to the allowable amount of nacelle rate. A modification that counteracted this effect significantly improved the handling qualities. Evaluation of the different response type variants showed that inclusion of TRC response could provide Level 1 handling qualities in the Lateral Reposition maneuver by reducing coupled pitch and heave off axis responses that otherwise manifest with ACAH. Finally, evaluations in the Depart/Abort maneuver showed that uncertainty about commanded nacelle position and ensuing aircraft response, when manually controlling the nacelle, demanded high levels of attention from the pilot. Additional requirements to maintain pitch attitude within 5 deg compounded the necessary workload.

Concept design of DEMO divertor cassette remote handling: Simply supported beam approach

Energy Technology Data Exchange (ETDEWEB)

Mozzillo, Rocco [CREATE, University of Naples Federico II, DII, P.le Tecchio 80, 80125, Naples (Italy); Di Gironimo, Giuseppei, E-mail: peppe.digironimo@gmail.com [CREATE, University of Naples Federico II, DII, P.le Tecchio 80, 80125, Naples (Italy); Mäkinen, Harri [VTT Technical Research Centre of Finland, P.O. Box 1300, FI-33101 Tampere (Finland); Miccichè, Gioacchino [ENEA – CR Brasimone, I-40032 Camugnano, BO (Italy); Määttä, Timo [VTT Technical Research Centre of Finland, P.O. Box 1300, FI-33101 Tampere (Finland)

2017-03-15

Highlights: • The present work focused on a new approach to the design of DEMO Divertor Cassette Remote Handling Equipment. • The work provides an alternative approach to the design based on the concept of a simply supported beam. • The approach proposed focuses a Divertor Cassette mover that performs the maintenance of the three cassettes at each port. • First rough dimensioning of the main components has been provided and demonstrating the feasibility of the design solutions. • The main idea of the work consisted on a design capable to use knowledge already adopted in industrial contexts. - Abstract: The present work focused on the development of a new approach to the concept design of DEMO Divertor Cassette (DC) Remote Handling Equipment (RHE). The approach is based on three main assumptions: the DC remote handling activities and the equipment shall be simplified as much as possible; technologies well known and consolidated in the industrial context can be adopted also in the nuclear fusion field; the design of the RHE should be based on a simply supported beam approach instead of cantilever approach. In detail, during the maintenance activities the barycentre of the DC is centred with respect to DC supports. This solution could simplify the design of RHE with a consequent reduction of the design and development costs. Moreover also the DC remote handling tasks shall be simplified in order to better manage the DC maintenance processes. For this reason the DC assembly and disassembly process has been simplified dividing the main sequences in basic movements. For each movement a dedicated tool has been conceived.

Semiconducting compounds and devices incorporating same

Science.gov (United States)

Marks, Tobin J.; Facchetti, Antonio; Boudreault, Pierre-Luc; Miyauchi, Hiroyuki

2016-01-19

Disclosed are molecular and polymeric compounds having desirable properties as semiconducting materials. Such compounds can exhibit desirable electronic properties and possess processing advantages including solution-processability and/or good stability. Organic transistor and photovoltaic devices incorporating the present compounds as the active layer exhibit good device performance.

Operative experience in handling enriched uranium compounds in an U3O8 production plant

International Nuclear Information System (INIS)

Friedenthal, M.; Cardenas Yucra, H.R.; Cinat, E.; Pino, H.F.; Surin, C.

1987-01-01

The design of a nuclear installation associated with chemical processes depends fundamentally on the risks derived from the materials and process used. The operative experience brings useful data mainly related to the ventilation and equipment design that allow to improve the handling of operational incidents and maintenance work. The paper presents the results extracted from a production campaign; ambient and personal monitoring results from monitorings performed routinely and during special interventions are commented. (Author)

Full scale tests on remote handled FFTF fuel assembly waste handling and packaging

International Nuclear Information System (INIS)

Allen, C.R.; Cash, R.J.; Dawson, S.A.; Strode, J.N.

1986-01-01

Handling and packaging of remote handled, high activity solid waste fuel assembly hardware components from spent FFTF reactor fuel assemblies have been evaluated using full scale components. The demonstration was performed using FFTF fuel assembly components and simulated components which were handled remotely using electromechanical manipulators, shielding walls, master slave manipulators, specially designed grapples, and remote TV viewing. The testing and evaluation included handling, packaging for current and conceptual shipping containers, and the effects of volume reduction on packing efficiency and shielding requirements. Effects of waste segregation into transuranic (TRU) and non-transuranic fractions also are discussed

Thermodynamic and structure-property study of liquid-vapor equilibrium for aroma compounds.

Science.gov (United States)

Tromelin, Anne; Andriot, Isabelle; Kopjar, Mirela; Guichard, Elisabeth

2010-04-14

Thermodynamic parameters (T, DeltaH degrees , DeltaS degrees , K) were collected from the literature and/or calculated for five esters, four ketones, two aldehydes, and three alcohols, pure compounds and compounds in aqueous solution. Examination of correlations between these parameters and the range values of DeltaH degrees and DeltaS degrees puts forward the key roles of enthalpy for vaporization of pure compounds and of entropy in liquid-vapor equilibrium of compounds in aqueous solution. A structure-property relationship (SPR) study was performed using molecular descriptors on aroma compounds to better understand their vaporization behavior. In addition to the role of polarity for vapor-liquid equilibrium of compounds in aqueous solution, the structure-property study points out the role of chain length and branching, illustrated by the correlation between the connectivity index CHI-V-1 and the difference between T and log K for vaporization of pure compounds and compounds in aqueous solution. Moreover, examination of the esters' enthalpy values allowed a probable conformation adopted by ethyl octanoate in aqueous solution to be proposed.

Influence of thermal treatment on the stability of phenolic compounds and the microbiological quality of sucrose solution following osmotic dehydration of highbush blueberry fruits.

Science.gov (United States)

Kucner, Anna; Papiewska, Agnieszka; Klewicki, Robert; Sójka, Michał; Klewicka, Elżbieta

2014-01-01

Osmotic dehydration is a process of the partial removal of water which is based on immersion of material having cellular structure in a hypertonic solution. Osmotic dehydration is used as a pretreatment for the dehydration of foods before they are subjected to further processing such as freezing, freeze drying, vacuum drying. Management of spent syrup is one of the most important problems related to osmotic dewatering. Osmotic solutions are heavily polluted with of carbohydrates, remains of the dehydrated material and microorganisms. The aim of this study was to determine the effect of thermal treatment on the content of phenolic compounds and the microbiological quality of sucrose solution used in 15 cycles of osmotic dehydration of highbush blueberry (Vaccinium corymbosum L.) fruits. The tested material was 65.0 ±0.5°Brix sucrose solution used for 15 cycles of osmotic dehydration of highbush blueberry (Vaccinium corymbosum L.). Osmotic dehydration was conducted at 40°C for 120 min using fruits previously subjected to enzymatic pretreatment. The thermal treatment of sucrose solution was conducted at 70, 80, 90, 100 and 115°C for 20, 40 and 60 s. The sucrose solution was analysed in terms of total polyphenols, particular polyphenols using high performance liquid chromatography and microbiological analysis was subjected. Thermal treatment at 70-115°C for 20 s caused degradation of 8.5% to 12.7% of polyphenols, while as much as 23.1% of polyphenols were degraded at 115°C after 60 s. The present paper proposes heating parameters that are optimal from the point of view of phenolic compound retention and microbiological quality: thermal treatment of syrup at 100°C for 40 s. Under these conditions, total polyphenols retention was 94.5%, while the retention of individual phenolic compounds varied from 89.2% to 37.2%, and that of flavan-3-ols amounted to 89.5%. The studied manner of syrup treatment eliminated the problem of syrup contamination with yeasts and molds

Airborne Release of Particles in Overheating Incidents Involving Plutonium Metal and Compounds

Energy Technology Data Exchange (ETDEWEB)

Schwendiman, L. C.; Mishima, J.; Radasch, C. A. [Battelle Memorial Institute, Pacific Northwest Laboratory, Richland, WA (United States)

1968-12-15

Ever-increasing utilization of nuclear fuels will result in wide-scale plutonium recovery processing, reconstitution of fuels, transportation, and extensive handling of this material. A variety of circumstances resulting in overheating and fires involving plutonium may occur, releasing airborne particles. This work describes the observations from a study in which the airborne release of plutonium and its compounds was measured during an exposure of the material of interest containing plutonium to temperatures which may result from fires. Aerosol released from small cylinders of metallic plutonium ignited in air at temperatures from 410 to 650 Degree-Sign C ranged from 3 x 10{sup -6} to 5 x 10{sup -5} wt%. Particles smaller than 15{mu}m in diameter represented as much as 0.03% of the total released. Large plutonium pieces weighing from 456 to 1770 g were ignited and allowed to oxidize completely in air with a velocity of around 500 cm/sec. Release rates of from 0.0045 to 0.032 wt% per hour were found. The median mass diameter of airborne material was 4 {mu}m. Quenching the oxidation with magnesium oxide sand reduced the release to 2.9 X 10{sup -4} wt% per hour. Many experiments were carried out in which plutonium compounds as powders were heated at temperatures ranging from 700 to 1000 Degree-Sign C with several air flows. Release rates ranged from 5 x 10{sup -8} to 0.9 wt% per hour, depending upon the compound and the conditions imposed. The airborne release from boiling solutions of plutonium nitrate were roughly related to energy of boiling, and ranged from 4 x 10{sup -4} to 2 x 10{sup -1} % for the evaporation of 90% of the solution. The fraction airborne when combustibles contaminated with plutonium are burned is under study. The data reported can be used in assessing the consequences of off-standard situations involving plutonium and its compounds in fires. (author)

Handling stress may confound murine gut microbiota studies

Directory of Open Access Journals (Sweden)

Cary R. Allen-Blevins

2017-01-01

Full Text Available Background Accumulating evidence indicates interactions between human milk composition, particularly sugars (human milk oligosaccharides or HMO, the gut microbiota of human infants, and behavioral effects. Some HMO secreted in human milk are unable to be endogenously digested by the human infant but are able to be metabolized by certain species of gut microbiota, including Bifidobacterium longum subsp. infantis (B. infantis, a species sensitive to host stress (Bailey & Coe, 2004. Exposure to gut bacteria like B. infantisduring critical neurodevelopment windows in early life appears to have behavioral consequences; however, environmental, physical, and social stress during this period can also have behavioral and microbial consequences. While rodent models are a useful method for determining causal relationships between HMO, gut microbiota, and behavior, murine studies of gut microbiota usually employ oral gavage, a technique stressful to the mouse. Our aim was to develop a less-invasive technique for HMO administration to remove the potential confound of gavage stress. Under the hypothesis that stress affects gut microbiota, particularly B. infantis, we predicted the pups receiving a prebiotic solution in a less-invasive manner would have the highest amount of Bifidobacteria in their gut. Methods This study was designed to test two methods, active and passive, of solution administration to mice and the effects on their gut microbiome. Neonatal C57BL/6J mice housed in a specific-pathogen free facility received increasing doses of fructooligosaccharide (FOS solution or deionized, distilled water. Gastrointestinal (GI tracts were collected from five dams, six sires, and 41 pups over four time points. Seven fecal pellets from unhandled pups and two pellets from unhandled dams were also collected. Qualitative real-time polymerase chain reaction (qRT-PCR was used to quantify and compare the amount of Bifidobacterium, Bacteroides, Bacteroidetes, and

Ergonomic material-handling device

Science.gov (United States)

Barsnick, Lance E.; Zalk, David M.; Perry, Catherine M.; Biggs, Terry; Tageson, Robert E.

2004-08-24

A hand-held ergonomic material-handling device capable of moving heavy objects, such as large waste containers and other large objects requiring mechanical assistance. The ergonomic material-handling device can be used with neutral postures of the back, shoulders, wrists and knees, thereby reducing potential injury to the user. The device involves two key features: 1) gives the user the ability to adjust the height of the handles of the device to ergonomically fit the needs of the user's back, wrists and shoulders; and 2) has a rounded handlebar shape, as well as the size and configuration of the handles which keep the user's wrists in a neutral posture during manipulation of the device.

Composition and method for stabilizing radiolabelled compounds using thiocarbonylated diethylenetriamines

International Nuclear Information System (INIS)

Tzodikov, N.R.

1984-01-01

Radiolabelled compounds, such as amino acids, nucleosides, vitamins and drugs, are stabilised against radiolytic decomposition by adding a solution of a thiocarbonylated diethylenetriamine to a solution of the radiolabelled compound. (author)

Food applications of natural antimicrobial compounds

Science.gov (United States)

Lucera, Annalisa; Costa, Cristina; Conte, Amalia; Del Nobile, Matteo A.

2012-01-01

In agreement with the current trend of giving value to natural and renewable resources, the use of natural antimicrobial compounds, particularly in food and biomedical applications, becomes very frequent. The direct addition of natural compounds to food is the most common method of application, even if numerous efforts have been made to find alternative solutions to the aim of avoiding undesirable inactivation. Dipping, spraying, and coating treatment of food with active solutions are currently applied to product prior to packaging as valid options. The aim of the current work is to give an overview on the use of natural compounds in food sector. In particular, the review will gather numerous case-studies of meat, fish, dairy products, minimally processed fruit and vegetables, and cereal-based products where these compounds found application. PMID:23060862

Food applications of natural antimicrobial compounds.

Science.gov (United States)

Lucera, Annalisa; Costa, Cristina; Conte, Amalia; Del Nobile, Matteo A

2012-01-01

In agreement with the current trend of giving value to natural and renewable resources, the use of natural antimicrobial compounds, particularly in food and biomedical applications, becomes very frequent. The direct addition of natural compounds to food is the most common method of application, even if numerous efforts have been made to find alternative solutions to the aim of avoiding undesirable inactivation. Dipping, spraying, and coating treatment of food with active solutions are currently applied to product prior to packaging as valid options. The aim of the current work is to give an overview on the use of natural compounds in food sector. In particular, the review will gather numerous case-studies of meat, fish, dairy products, minimally processed fruit and vegetables, and cereal-based products where these compounds found application.

Food applications of natural antimicrobial compounds

Directory of Open Access Journals (Sweden)

Matteo Alessandro eDel Nobile

2012-08-01

Full Text Available In agreement with the current trend of giving value to natural and renewable resources, the use of natural antimicrobial compounds, particularly in food and biomedical applications, becomes very frequent. The direct addition of natural compounds to food is the most common method of application, even if numerous efforts have been made to find alternative solutions to the aim of avoiding undesirable inactivation. Dipping, spraying and coating treatment of food with active solutions are currently applied to product prior to packaging as valid options. The aim of the current work is to give an overview on the use of natural compounds in food sector. In particular, the review will gather numerous case-studies of meat, fish, dairy products, minimally processed fruit and vegetables and cereal-based products where these compounds found application.

Coprecipitation of 137Cs and 85Sr microquantities with complex compound [M(18-crown-6)]BPH4 (M=Na+, Cs+) from neutral and alkaline solutions

International Nuclear Information System (INIS)

Konovalova, N.A.; Rumer, I.A.; Kulyukhin, S.A.

2009-01-01

The paper reports the possibility of joint separation of 137 Cs and 85 Sr from neutral and alkaline aqueous solutions by their coprecipitation with the solid phase of complex compounds [M(18-crown-6)]BPh 4 (M=Na + , Cs + ), as well as to study the coprecipitation of 137 Cs and 85 Sr with the solid phase CsBPh 4 . It is found that complex compounds [M(18-crown-6)]BPh 4 (M=Na + , Cs + ) increased the degree of 85 Sr separation from solutions virtually two- to threefold vs. CsBPh 4 . Chloride and nitrate were found to have hardly any impact on the coprecipitation of 137 Cs and 85 Sr with [M(18-crown-6)]BPh 4 (M = Na + , Cs + ). (orig.)

Concept design of divertor remote handling system for the FAST machine

Energy Technology Data Exchange (ETDEWEB)

Di Gironimo, G., E-mail: giuseppe.digironimo@unina.it [Association Euratom/ENEA/CREATE, Università di Napoli Federico II, 80125 Napoli (Italy); Labate, C.; Renno, F. [Association Euratom/ENEA/CREATE, Università di Napoli Federico II, 80125 Napoli (Italy); Brolatti, G.; Crescenzi, F.; Crisanti, F. [CR ENEA Frascati, Via E. Fermi 27, Frascati (RM) (Italy); Lanzotti, A. [Association Euratom/ENEA/CREATE, Università di Napoli Federico II, 80125 Napoli (Italy); Lucca, F. [LT Calcoli SaS, Piazza Prinetti 26/B, 23807 Merate (Italy); Siuko, M. [VTT Systems Engineering, Tekniikankatu 1, 33720 Tampere (Finland)

2013-10-15

The paper presents a concept design of a remote handling (RH) system oriented to maintenance operations on the divertor second cassette in FAST, a satellite of ITER tokamak. Starting from ITER configuration, a suitably scaled system, composed by a cassette multifunctional mover (CMM) connected to a second cassette end-effector (SCEE), can represent a very efficient solution for FAST machine. The presence of a further system able to open the divertor port, used for RH aims, and remove the first cassette, already aligned with the radial direction of the port, is presumed. Although an ITER-like system maintains essentially shape and proportions of its reference configuration, an appropriate arrangement with FAST environment is needed, taking into account new requirements due to different dimensions, weights and geometries. The use of virtual prototyping and the possibility to involve a great number of persons, not only mechanical designers but also physicist, plasma experts and personnel assigned to remote handling operations, made them to share the multiphysics design experience, according to a concurrent engineering approach. Nevertheless, according to the main objective of any satellite tokamak, such an approach benefits the study of enhancements to ITER RH system and the exploration of alternative solutions.

The handling, hazards, and maintenance of heavy liquids in the geologic laboratory

Science.gov (United States)

Hauff, Phoebe L.; Airey, Joseph

1980-01-01

In geologic laboratories the organic heavy liquids bromoform, methylene iodide, tetrabromoethane, and clerici compounds have been used for years in mineral separation processes. Because the volume of use of these compounds is low, insufficient data is available on their toxic properties. This report is an attempt to summarize the known data from published and industry sources. The physical properties, hazards of handling,proper storage facilities, and adequate protective Clothing are discussed for each compound as well as for their common and less-common solvents. Toxicity data for these materials is listed along with exposure symptoms and suggested first aid treatments. Safety for the worker is emphasized. Three reclamation methods which recover the solvent used as a dilutant and purify the heavy liquid are discussed and illustrated. These include: the water cascade, re fluxing-distillation-condensation, and flash evaporation methods. Various techniques for restoration and stabilization of these heavy liquids are also included.

Compilation of Requirements for Safe Handling of Fluorine and Fluorine-Containing Products of Uranium Hexafluoride Conversion

International Nuclear Information System (INIS)

Ferrada, J.J.; Hightower, J.R.; Begovich, J.M.

2000-01-01

Public Law (PL) 105--204 requires the U.S. Department of Energy to develop a plan for inclusion in the fiscal year 2000 budget for conversion of the Department's stockpile of depleted uranium hexafluoride (DUF6) to a more stable form over an extended period. The conversion process into a more stable form will produce fluorine compounds (e.g., elemental fluorine or hydrofluoric acid) that need to be handled safely. This document compiles the requirements necessary to handle these materials within health and safety standards, which may apply in order to ensure protection of the environment and the safety and health of workers and the public

Development of spent fuel remote handling technology

International Nuclear Information System (INIS)

Yoon, J. S.; Hong, H. D.; Kim, S. H.

2004-02-01

In this research, the remote handling technology is developed for the advanced spent fuel conditioning process which gives a possible solution to deal with the rapidly increasing spent fuels. In detail, a fuel rod slitting device is developed for the decladding of the spent fuel. A series of experiments has been performed to find out the optimal condition of the spent fuel voloxidation which converts the UO 2 pellet into U 3 O 8 powder. The design requirements of the ACP equipment for hot test is established by analysing the modular requirement, radiation hardening and thermal protection of the process equipment, etc. The prototype of the servo manipulator is developed. The manipulator has an excellent performance in terms of the payload to weight ratio that is 30 % higher than that of existing manipulators. To provide reliability and safety of the ACP, the 3 dimensional graphic simulator is developed. Using the simulator the remote handling operation is simulated and as a result, the optimal layout of ACP is obtained. The supervisory control system is designed to control and monitor the several different unit processes. Also the failure monitoring system is developed to detect the possible accidents of the reduction reactor

New exact travelling wave solutions of nonlinear physical models

International Nuclear Information System (INIS)

Bekir, Ahmet; Cevikel, Adem C.

2009-01-01

In this work, we established abundant travelling wave solutions for some nonlinear evolution equations. This method was used to construct travelling wave solutions of nonlinear evolution equations. The travelling wave solutions are expressed by the hyperbolic functions, the trigonometric functions and the rational functions. The ((G ' )/G )-expansion method presents a wider applicability for handling nonlinear wave equations.

30o inclination in handles of plastic boxes can reduce postural and muscular workload during handling

Directory of Open Access Journals (Sweden)

Luciana C. C. B. Silva

2013-06-01

Full Text Available BACKGROUND: The handling of materials, which occurs in the industrial sector, is associated with lesions on the lumbar spine and in the upper limbs. Inserting handles in industrial boxes is a way to reduce work-related risks. Although the position and angle of the handles are significant factors in comfort and safety during handling, these factors have rarely been studied objectively. OBJECTIVE: To compare the handling of a commercial box and prototypes with handles and to evaluate the effects on upper limb posture, muscle electrical activity, and perceived acceptability using different grips while handling materials from different heights. METHOD: Thirty-seven healthy volunteers evaluated the handles of prototypes that allowed for changes in position (top and bottom and angle (0°, 15°, and 30°. Wrist, elbow, and shoulder movements were evaluated using electrogoniometry and inclinometry. The muscle electrical activity in the wrist extensors, biceps brachii, and the upper portion of the trapezius was measured using a portable electromyographer. The recorded data on muscle movements and electrical activity were synchronized. Subjective evaluations of acceptability were evaluated using a visual analog scale. RESULTS AND CONCLUSIONS: The prototypes with handles at a 30° angle produced the highest acceptability ratings, more neutral wrist positions, lower levels of electromyographic activity for the upper trapezius, and lower elevation angles for the arms. The different measurement methods were complementary in evaluating the upper limbs during handling.

Sample handling and chemical procedures for efficacious trace analysis of urine by neutron activation analysis

International Nuclear Information System (INIS)

Blotcky, A.J.; Rack, E.P.; Roman, F.R.

1988-01-01

Important for the determination of trace elements, ions, or compounds in urine by chemical neutron activation analysis is the optimization of sample handling, preirradiation chemistry, and radioassay procedures necessary for viable analysis. Each element, because of its natural abundance in the earth's crust and, hence, its potential for reagent and environmental contamination, requires specific procedures for storage, handling, and preirradiation chemistry. Radioassay techniques for radionuclides vary depending on their half-lives and decay characteristics. Described in this paper are optimized procedures for aluminum and selenium. While 28 Al (T 1/2 = 2.24 min) and 77m Se(T 1/2 = 17.4s) have short half-lives, their gamma-ray spectra are quite different. Aluminum-28 decays by a 1779-keV gamma and 77m Se by a 162-keV gamma. Unlike selenium, aluminum is a ubiquitous element in the environment requiring special handling to minimize contamination in all phases of its analytical determination

New transport and handling contract

CERN Multimedia

SC Department

2008-01-01

A new transport and handling contract entered into force on 1.10.2008. As with the previous contract, the user interface is the internal transport/handling request form on EDH: https://edh.cern.ch/Document/TransportRequest/ To ensure that you receive the best possible service, we invite you to complete the various fields as accurately as possible and to include a mobile telephone number on which we can reach you. You can follow the progress of your request (schedule, completion) in the EDH request routing information. We remind you that the following deadlines apply: 48 hours for the transport of heavy goods (up to 8 tonnes) or simple handling operations 5 working days for crane operations, transport of extra-heavy goods, complex handling operations and combined transport and handling operations in the tunnel. For all enquiries, the number to contact remains unchanged: 72202. Heavy Handling Section TS-HE-HH 72672 - 160319

Compendium of shock wave data. Section C. Organic compounds excluding hydrocarbons. Section D. Mixtures. Section E. Mixtures and solutions without chemical characterization. Compendium index

International Nuclear Information System (INIS)

van Thiel, M.; shaner, J.; Salinas, E.

1977-06-01

This volume lists thermodynamic data for organic compounds excluding hydrocarbons, mixtures, and mixtures and solutions without chemical characterization. Alloys and some minerals are included among the mixtures. This volume also contains the index for the three-volume compendium

Translation of Japanese Noun Compounds at Super-Function Based MT System

Science.gov (United States)

Zhao, Xin; Ren, Fuji; Kuroiwa, Shingo

Noun compounds are frequently encountered construction in nature language processing (NLP), consisting of a sequence of two or more nouns which functions syntactically as one noun. The translation of noun compounds has become a major issue in Machine Translation (MT) due to their frequency of occurrence and high productivity. In our previous studies on Super-Function Based Machine Translation (SFBMT), we have found that noun compounds are very frequently used and difficult to be translated correctly, the overgeneration of noun compounds can be dangerous as it may introduce ambiguity in the translation. In this paper, we discuss the challenges in handling Japanese noun compounds in an SFBMT system, we present a shallow method for translating noun compounds by using a word level translation dictionary and target language monolingual corpus.

Method of removing uranium and its compounds from mine wastewaters and from aqueous solutions discharged in hydrometallurgical uranium ore treatment

International Nuclear Information System (INIS)

Jilek, R.; Prochazka, H.; Kuhr, I.; Fuska, J.; Nemec, P.; Katzer, J.

1974-01-01

The separation of uranium and its compounds from mine wastewaters and from water solutions discharged from uranium ore hydrometallurgical treatment, and its eventual simultaneous concentration in the biomass during uranium ore technological processing are described. The solutions are replenished with nutrients necessary for the growth of microorganisms, mainly with nitrogen, carbon and phosphorus and inoculated with fungi. During submersion cultivation, uranium incorporates in the mycelium, or is bound physico-chemically to the mycelium components. Together with these components, uranium is mechanically separated, i.e., by filtration, centrifugation or sedimentation. Organisms of the Fungi imperfecti class, mainly the Aspergillus and Penicillium genera are used for cultivation which may be continuous or semicontinuous. (B.S.)

The effect of pH on the corrosion behavior of intermetallic compounds Ni{sub 3}(Si,Ti) and Ni{sub 3}(Si,Ti) + 2Mo in sodium chloride solutions

Energy Technology Data Exchange (ETDEWEB)

Priyotomo, Gadang, E-mail: gada001@lipi.go.id; Nuraini, Lutviasari, E-mail: Lutviasari@gmail.com [Research Center for Metallurgy and Material, Indonesian Institute of Sciences, Kawasan PUSPIPTEK Gd.474, Setu, Tangerang Selatan, Banten 15314 (Indonesia); Kaneno, Yasuyuki, E-mail: kaneno@mtr.osakafu-u.ac.id [Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531 (Japan)

2015-12-29

The corrosion behavior of the intermetallic compounds, Ni{sub 3}(Si,Ti) (L1{sub 2}: single phase) and Ni{sub 3}(Si,Ti) + 2Mo (L1{sub 2} and (L12 + Ni{sub ss}) mixture region), has been investigated using an immersion test, electrochemical method and surface analytical method (SEM; scanning electron microscope and EDAX: Energy Dispersive X-ray) in 0.5 kmol/m{sup 3} NaCl solutions at various pH. The corrosion behavior of nickel alloy C-276 was studied under the same experimental conditions as a reference. It was found that the uniform attack was observed on Ni{sub 3}(Si,Ti) for the immersion test at lower pH, while the pitting attack was observed on this compound for this test at neutral solution. Furthermore, Ni{sub 3}(Si,Ti)+2Mo had the preferential dissolution of L1{sub 2} compared to (L1{sub 2} + Ni{sub ss}) mixture region at lower pH, while pitting attack occurred in (L1{sub 2} + Ni{sub ss}) mixture region at neutral solution. For both intermetallic compounds, the magnitude of pitting and uniform attack decrease with increasing pH of solutions. From the immersion test and polarization curves, the corrosion resistance of Ni{sub 3}(Si,Ti)+2Mo is lower than that of Ni{sub 3}(Si,Ti), while the nickel alloy C-276 is the highest one at various pH of solutions. On the other hand, in the lower pH of solutions, the corrosion resistance of tested materials decreased significantly compared to those in neutral and higher pH of solutions.

Thermochemical investigation into coordination ability of zinc and cadmium alkyl compounds in solutions

International Nuclear Information System (INIS)

Aleksandrov, Yu.A.; Fedostseva, G.A.; Tsvetkov, V.G.; Lebedev, S.A.; Kozyrkin, B.I.

1983-01-01

Enthalpies of zinc alkyl compounds mixing, as well as those of dimethyl cadmium mixing with hexane, previously used as a solvent during the study of liquid-phase autooxidation of Me 2 Cd and Me 2 Zn, and with a series of organic bases at 298 K and at components ratio 1:1 or 1:2, are determined. Using calorimetric method dimethyl cadmium association in liquid state has been evaluated. Coordination ability of zinc alkyl compounds is higher than for the corresponding cadmium compounds. With the increase of alkyl radical length the electron seeking ability of zinc compounds decreases. On the basis of thermochemical data relative stability of coordination compounds of zinc and cadmium alkyl compounds with certain alkyl compounds of group 6 elements is evaluated: it has the maximum value for sulfur compounds

Challenge in manufacturing electrolyte solutions for lithium and lithium ion batteries quality control and minimizing contamination level

Science.gov (United States)

Heider, U.; Oesten, R.; Jungnitz, M.

The quality of electrolytes for lithium batteries are a major topic in science and battery industries. The solvents and lithium salts should be of highest purity. Therefore, during preparation and handling of electrolyte solutions, the contamination level has to be minimized and the quality during packaging, storage and transportation has to be guaranteed. Especially, protic impurities are found to be very critical for LiPF 6-based electrolytes. The influence of water is reported to be tremendous. But also other protic impurities like alcohols are considered to play an important role in the electrolyte quality. The reaction of the protic impurities with LiPF 6 leads to the formation of HF which further reacts with cathode active materials (e.g., spinel) and the passivating films of the cathode and anode. For a better understanding of the protic impurities and their role in the electrolyte quality a systematic investigation of different impurities was carried out. Electrolytes were doped with different protic compounds. Then the electrolyte was analyzed for protic impurities and HF in dependence of time. First results showing the relation between protic impurities and HF are presented and discussed. In addition, different packaging materials for the electrolyte solutions were investigated. Storage tests were carried out at different temperatures and in different atmospheres. Results on contamination levels, influence of packaging, high temperature storage and handling are addressed.

Evaluating the Open Source Data Containers for Handling Big Geospatial Raster Data

Directory of Open Access Journals (Sweden)

Fei Hu

2018-04-01

Full Text Available Big geospatial raster data pose a grand challenge to data management technologies for effective big data query and processing. To address these challenges, various big data container solutions have been developed or enhanced to facilitate data storage, retrieval, and analysis. Data containers were also developed or enhanced to handle geospatial data. For example, Rasdaman was developed to handle raster data and GeoSpark/SpatialHadoop were enhanced from Spark/Hadoop to handle vector data. However, there are few studies to systematically compare and evaluate the features and performances of these popular data containers. This paper provides a comprehensive evaluation of six popular data containers (i.e., Rasdaman, SciDB, Spark, ClimateSpark, Hive, and MongoDB for handling multi-dimensional, array-based geospatial raster datasets. Their architectures, technologies, capabilities, and performance are compared and evaluated from two perspectives: (a system design and architecture (distributed architecture, logical data model, physical data model, and data operations; and (b practical use experience and performance (data preprocessing, data uploading, query speed, and resource consumption. Four major conclusions are offered: (1 no data containers, except ClimateSpark, have good support for the HDF data format used in this paper, requiring time- and resource-consuming data preprocessing to load data; (2 SciDB, Rasdaman, and MongoDB handle small/mediate volumes of data query well, whereas Spark and ClimateSpark can handle large volumes of data with stable resource consumption; (3 SciDB and Rasdaman provide mature array-based data operation and analytical functions, while the others lack these functions for users; and (4 SciDB, Spark, and Hive have better support of user defined functions (UDFs to extend the system capability.

Remote handling machines

International Nuclear Information System (INIS)

Sato, Shinri

1985-01-01

In nuclear power facilities, the management of radioactive wastes is made with its technology plus the automatic techniques. Under the radiation field, the maintenance or aid of such systems is important. To cope with this situation, MF-2 system, MF-3 system and a manipulator system as remote handling machines are described. MF-2 system consists of an MF-2 carrier truck, a control unit and a command trailer. It is capable of handling heavy-weight objects. The system is not by hydraulic but by electrical means. MF-3 system consists of a four-crawler truck and a manipulator. The truck is versatile in its posture by means of the four independent crawlers. The manipulator system is bilateral in operation, so that the delicate handling is made possible. (Mori, K.)

No fluorinated compounds in the uranium conversion process: risk analysis and proposition of pictograms

International Nuclear Information System (INIS)

Jeronimo, Adroaldo Clovis; Oliveira, Wagner dos Santos

2012-01-01

The plants comprising the chemical conversion of uranium, which are part of the nuclear fuel cycle, present some risks, among others, because are associated with the non-fluorinated compounds handled in these processes. This study is the analysis of the risks associated with these compounds, i e, the non-fluorinated reactants and products, handled in different chemical processing plants, which include the production of uranium hexafluoride, while emphasizing the responsibilities and actions that fit to the chemical engineer with regard to minimizing risks during the various stages. The work is based on the experience gained during the development and mastery of the technology of production of uranium hexafluoride, the IPEN/ CNEN-SP, during the '80s, with the support of COPESP -Navy of Brazil. (author)

Synthesis, electrochemical, spectrophotometric and potentiometric studies of two azo-compounds derived from 4-amino-2-methylquinoline in ethanolic-aqueous buffered solutions

Energy Technology Data Exchange (ETDEWEB)

El-Attar, Mona A.; Ghoneim, Mohamed M. [Analytical Chemistry Research Unit, Chemistry Department, Tanta University (Egypt); Ismail, Iqbal M., E-mail: maema.2011@yahoo.com [Chemistry Department, Faculty of Science, King Abdul Aziz University, Jeddah (Saudi Arabia)

2012-08-15

Two azo-compounds, 2-methyl-4-(5-amino-2-hydroxy-phenylazo)-quinoline (2) and 2-methyl-4-(2-hydroxy-5-nitrophenylazo)-quinoline, derived from 4-amino-2-methylquinoline were synthesized. Their chemical structures were characterized and confirmed by means of elemental chemical analysis, infrared (IR) spectroscopy, {sup 1}H nuclear magnetic resonance (NMR) and mass spectrometry (MS). The electrochemical behavior of the starting compound (4-amino-2-methylquinoline) and of the two synthesized azo-derivatives was studied at the mercury electrode in the B-R universal buffer at various pH values (2-11.5) containing 40% (v/v) ethanol using dc-polarography, cyclic voltammetry and controlled-potential coulometry. Their electrode reaction pathways were elucidated and discussed. The dissociation constants (pKa) of the examined compounds, stability constants and stoichiometry of their complexes in solution with some transition metal ions (Co(II), Ni(II), Cu(II), La(III) and UO{sup 2+}{sub 2}) were determined. (author)

Recovery of mercury from mercury compounds via electrolytic methods

Science.gov (United States)

Grossman, Mark W.; George, William A.

1988-01-01

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Safety of Cargo Aircraft Handling Procedure

Directory of Open Access Journals (Sweden)

Daniel Hlavatý

2017-07-01

Full Text Available The aim of this paper is to get acquainted with the ways how to improve the safety management system during cargo aircraft handling. The first chapter is dedicated to general information about air cargo transportation. This includes the history or types of cargo aircraft handling, but also the means of handling. The second part is focused on detailed description of cargo aircraft handling, including a description of activities that are performed before and after handling. The following part of this paper covers a theoretical interpretation of safety, safety indicators and legislative provisions related to the safety of cargo aircraft handling. The fourth part of this paper analyzes the fault trees of events which might occur during handling. The factors found by this analysis are compared with safety reports of FedEx. Based on the comparison, there is a proposal on how to improve the safety management in this transportation company.

A review of the radiation chemistry of iodine compounds in aqueous solution

International Nuclear Information System (INIS)

Sellers, R.M.

1977-06-01

Large amounts of radioactive iodine are formed in the fission of uranium in nuclear reactors. Some of this may be released to the coolant from the fuel either by diffusion through the canning material, or following the failure of a fuel pin. The iodine, which is released mainly as I 2 and methyl iodide, is transported with the coolant and, in direct cycle water cooled reactors, some is carried over with the steam to the turbines, where contamination may build up in the vicinity of steam leaks. Any assessment of the mechanism of the transport of iodine requires a knowledge of the relative amounts of the various oxidation states present, and must consider not only the thermal behaviour of iodine in water, but also the radiation chemical effects. A review is presented of the radiation chemistry of inorganic iodine compounds and methyl iodide in aqueous solutions. A number of unstable intermediates have been identified including species with iodide in valency states II, IV, VI and VIII. A considerable number of discrepancies exist in the literature data, and requirements for further work are identified. (author)

Calixarene-mediated liquid membrane transport of choline conjugates 3: The effect of handle variation on neurotransmitter transport.

Science.gov (United States)

Collins, James L; Fujii, Ayu; Roshandel, Sahar; To, Cuong-Alexander; Schramm, Michael P

2017-07-01

Upper rim phosphonic acid functionalized calix[4]arene affects selective transport of multiple molecular payloads through a liquid membrane. The secret is in the attachment of a receptor-complementary handle to the payload. We find that the trimethylammonium ethylene group present in choline is one of several general handles for the transport of drug and drug-like species. Herein we compare the effect of handle variation against the transport of serotonin and dopamine. We find that several ionizable amine termini handles are sufficient for transport and identify two ideal candidates. Their performance is significantly enhanced in HEPES buffered solutions. This inquiry completes a series of 3 studies aimed at optimization of this strategy. In completion a new approach towards synthetic receptor mediated selective small molecule transport has emerged; future work in vesicular and cellular systems will follow. Copyright © 2017 Elsevier Ltd. All rights reserved.

A database for extract solutions in general relativity

International Nuclear Information System (INIS)

Horvath, I.; Horvath, Zs.; Lukacs, B.

1993-07-01

The field of equations of General Relativity are coupled second order partial differential equations. Therefore no general method is known to generate solutions for prescribed initial and boundary conditions. In addition, the meaning of the particular coordinates cannot be known until the metric is not found. Therefore the result must permit arbitrary coordinate transformations, i.e. most kinds of approximating methods are improper. So exact solutions are necessary and each one is an individual product. For storage, retrieval and comparison database handling techniques are needed. A database of 1359 articles is shown (cross-referred at least once) published in 156 more important journals. It can be handled by dBase III plus on IBM PC's. (author) 5 refs.; 5 tabs

Ergonomics and patient handling.

Science.gov (United States)

McCoskey, Kelsey L

2007-11-01

This study aimed to describe patient-handling demands in inpatient units during a 24-hour period at a military health care facility. A 1-day total population survey described the diverse nature and impact of patient-handling tasks relative to a variety of nursing care units, patient characteristics, and transfer equipment. Productivity baselines were established based on patient dependency, physical exertion, type of transfer, and time spent performing the transfer. Descriptions of the physiological effect of transfers on staff based on patient, transfer, and staff characteristics were developed. Nursing staff response to surveys demonstrated how patient-handling demands are impacted by the staff's physical exertion and level of patient dependency. The findings of this study describe the types of transfers occurring in these inpatient units and the physical exertion and time requirements for these transfers. This description may guide selection of the most appropriate and cost-effective patient-handling equipment required for specific units and patients.

Equipment for the handling of thorium materials

International Nuclear Information System (INIS)

Heisler, S.W. Jr.; Mihalovich, G.S.

1988-01-01

The Feed Materials Production Center (FMPC) is the United States Department of Energy's storage facility for thorium. FMPC thorium handling and overpacking projects ensure the continued safe handling and storage of the thorium inventory until final disposition of the materials is determined and implemented. The handling and overpacking of the thorium materials requires the design of a system that utilizes remote handling and overpacking equipment not currently utilized at the FMPC in the handling of uranium materials. The use of remote equipment significantly reduces radiation exposure to personnel during the handling and overpacking efforts. The design system combines existing technologies from the nuclear industry, the materials processing and handling industry and the mining industry. The designed system consists of a modified fork lift truck for the transport of thorium containers, automated equipment for material identification and inventory control, and remote handling and overpacking equipment for material identification and inventory control, and remote handling and overpacking equipment for repackaging of the thorium materials

Distributed computing for FTU data handling

Energy Technology Data Exchange (ETDEWEB)

Bertocchi, A. E-mail: bertocchi@frascati.enea.it; Bracco, G.; Buceti, G.; Centioli, C.; Giovannozzi, E.; Iannone, F.; Panella, M.; Vitale, V

2002-06-01

The growth of data warehouse in tokamak experiment is leading fusion laboratories to provide new IT solutions in data handling. In the last three years, the Frascati Tokamak Upgrade (FTU) experimental database was migrated from IBM-mainframe to Unix distributed computing environment. The migration efforts have taken into account the following items: (1) a new data storage solution based on storage area network over fibre channel; (2) andrew file system (AFS) for wide area network file sharing; (3) 'one measure/one file' philosophy replacing 'one shot/one file' to provide a faster read/write data access; (4) more powerful services, such as AFS, CORBA and MDSplus to allow users to access FTU database from different clients, regardless their O.S.; (5) large availability of data analysis tools, from the locally developed utility SHOW to the multi-platform Matlab, interactive data language and jScope (all these tools are now able to access also the Joint European Torus data, in the framework of the remote data access activity); (6) a batch-computing cluster of Alpha/CompaqTru64 CPU based on CODINE/GRD to optimize utilization of software and hardware resources.

Quantitative method of determining beryllium or a compound thereof in a sample

Science.gov (United States)

McCleskey, T. Mark; Ehler, Deborah S.; John, Kevin D.; Burrell, Anthony K.; Collis, Gavin E.; Minogue, Edel M.; Warner, Benjamin P.

2010-08-24

A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.

New coordination compounds of Cr(III) used in leather tanning

Science.gov (United States)

Crudu, Marian; Sibiescu, Doina; Rosca, Ioan; Sutiman, Daniel; Vizitiu, Mihaela; Apostolescu, Gabriela

2009-01-01

Some new coordination compounds of Cr(III) using as ligand N-hydroxy - succinimide, were obtained and studied. The combination ratio, central atom: ligand were 1:1; 1:2 and 1:3. The new complex compounds were studied using UV-Vis spectroscopy, conductance and pH measurements. The studies of obtaining and of stability of the new compounds were accomplished in aqueous solutions using methods characteristic for coordination compounds: conductance and pH measurements. The combination ratios and the stability constants were determined with methods characteristic for studies in solutions.

How to Handle Abuse

Science.gov (United States)

... Handle Abuse KidsHealth / For Kids / How to Handle Abuse What's in this article? Tell Right Away How Do You Know Something Is Abuse? ... babysitter, teacher, coach, or a bigger kid. Child abuse can happen anywhere — at ... building. Tell Right Away A kid who is being seriously hurt ...

Waste Handling Building Conceptual Study

International Nuclear Information System (INIS)

G.W. Rowe

2000-01-01

The objective of the ''Waste Handling Building Conceptual Study'' is to develop proposed design requirements for the repository Waste Handling System in sufficient detail to allow the surface facility design to proceed to the License Application effort if the proposed requirements are approved by DOE. Proposed requirements were developed to further refine waste handling facility performance characteristics and design constraints with an emphasis on supporting modular construction, minimizing fuel inventory, and optimizing facility maintainability and dry handling operations. To meet this objective, this study attempts to provide an alternative design to the Site Recommendation design that is flexible, simple, reliable, and can be constructed in phases. The design concept will be input to the ''Modular Design/Construction and Operation Options Report'', which will address the overall program objectives and direction, including options and issues associated with transportation, the subsurface facility, and Total System Life Cycle Cost. This study (herein) is limited to the Waste Handling System and associated fuel staging system

Practices of Handling

DEFF Research Database (Denmark)

Ræbild, Ulla

to touch, pick up, carry, or feel with the hands. Figuratively it is to manage, deal with, direct, train, or control. Additionally, as a noun, a handle is something by which we grasp or open up something. Lastly, handle also has a Nordic root, here meaning to trade, bargain or deal. Together all four...... meanings seem to merge in the fashion design process, thus opening up for an embodied engagement with matter that entails direction giving, organizational management and negotiation. By seeing processes of handling as a key fashion methodological practice, it is possible to divert the discourse away from...... introduces four ways whereby fashion designers apply their own bodies as tools for design; a) re-activating past garment-design experiences, b) testing present garment-design experiences c) probing for new garment-design experiences and d) design of future garment experiences by body proxy. The paper...

Studies about interaction of hydrogen isotopes with metals and intermetallic compounds

International Nuclear Information System (INIS)

Vasut, F.; Anisoara, P.; Zamfirache, M.

2003-01-01

Hydrogen is a non-toxic but highly inflammable gas. Compared to other inflammable gases, its range of inflammability in air is much broader (4-74.5%) but it also vaporizes much more easily. Handling of hydrogen in form of hydrides enhances safety. The interaction of hydrogen with metals and intermetallic compounds is a major field within physical chemistry. Using hydride-forming metals and intermetallic compounds, for example, recovery, purification and storage of heavy isotopes in tritium containing system can solve many problems arising in the nuclear-fuel cycle. The paper presents the thermodynamics and the kinetics between hydrogen and metal or intermetallic compounds. (author)

Preliminary study of a blanket handling device and evaluation of the feasibility of eliminating the spread of radioactive contamination

International Nuclear Information System (INIS)

Leger, D.; Djerassi, H.; Maupou, M.; Charruyer, P.; Salpietro, E.

1988-01-01

A study concerning progress and future development of the BLANKET HANDLING DEVICE of NET-DN tokamak and the related potentialities against contamination dispersal during handling of internal segments. To prevent the dust dispersion during the mantainance operations, there are three options: a Tight-Intermediate Containment (TIC), a Containment Transfer Unit (CTU) or the dust fixation on the internal components. The design of the BHD takes account of multivarious dimensioning requirements (geometrical and dimensional constraints, including characteristics of the segments and torus), environmental and operational constraints (safety, lifetime, maintainability, cooling of Blanket segments, containment). The possible solutions concerning protection of special devices, during handling and travelling, are discussed

SRV-automatic handling device

International Nuclear Information System (INIS)

Yamada, Koji

1987-01-01

Automatic handling device for the steam relief valves (SRV's) is developed in order to achieve a decrease in exposure of workers, increase in availability factor, improvement in reliability, improvement in safety of operation, and labor saving. A survey is made during a periodical inspection to examine the actual SVR handling operation. An SRV automatic handling device consists of four components: conveyor, armed conveyor, lifting machine, and control/monitoring system. The conveyor is so designed that the existing I-rail installed in the containment vessel can be used without any modification. This is employed for conveying an SRV along the rail. The armed conveyor, designed for a box rail, is used for an SRV installed away from the rail. By using the lifting machine, an SRV installed away from the I-rail is brought to a spot just below the rail so that the SRV can be transferred by the conveyor. The control/monitoring system consists of a control computer, operation panel, TV monitor and annunciator. The SRV handling device is operated by remote control from a control room. A trial equipment is constructed and performance/function testing is carried out using actual SRV's. As a result, is it shown that the SRV handling device requires only two operators to serve satisfactorily. The required time for removal and replacement of one SRV is about 10 minutes. (Nogami, K.)

Modification of ginseng flavors by bitter compounds found in chocolate and coffee.

Science.gov (United States)

Sook Chung, Hee; Lee, Soo-Yeun

2012-06-01

Ginseng is not widely accepted by U.S. consumers due to its unfamiliar flavors, despite its numerous health benefits. Previous studies have suggested that the bitter compounds in chocolate and coffee may mask the off-flavors of ginseng. The objectives of this study were to: (1) profile sensory characteristics of ginseng extract solution, caffeine solution, cyclo (L-Pro-L-Val) solution, theobromine solution, and 2 model solutions simulating chocolate bitterness; and (2) determine the changes in the sensory characteristics of ginseng extract solution by the addition of the bitter compounds found in chocolate and coffee. Thirteen solutions were prepared in concentrations similar to the levels of the bitter compounds found in coffee and chocolate products. Twelve panelists participated in a descriptive analysis panel which included time-intensity ratings. Ginseng extract was characterized as sweeter, starchier, and more green tea than the other sample solutions. Those characteristics of ginseng extract were effectively modified by the addition of caffeine, cyclo (L-Pro-L-Val), and 2 model solutions. A model solution simulating dark chocolate bitterness was the least influenced in intensities of bitterness by the addition of ginseng extract. Results from time-intensity ratings show that the addition of ginseng extract increased duration time in certain bitterness of the 2 model solutions. Bitter compounds found in dark chocolate could be proposed to effectively mask the unique flavors of ginseng. Future studies blending aroma compounds of chocolate and coffee into such model solutions may be conducted to investigate the influence on the perception of the unique flavors through the congruent flavors. © 2012 Institute of Food Technologists®

Grain Handling and Storage.

Science.gov (United States)

Harris, Troy G.; Minor, John

This text for a secondary- or postecondary-level course in grain handling and storage contains ten chapters. Chapter titles are (1) Introduction to Grain Handling and Storage, (2) Elevator Safety, (3) Grain Grading and Seed Identification, (4) Moisture Control, (5) Insect and Rodent Control, (6) Grain Inventory Control, (7) Elevator Maintenance,…

Determination of the activity of a molecular solute in saturated solution

International Nuclear Information System (INIS)

Nordstroem, Fredrik L.; Rasmuson, Ake C.

2008-01-01

Prediction of the solubility of a solid molecular compound in a solvent, as well as, estimation of the solution activity coefficient from experimental solubility data both require estimation of the activity of the solute in the saturated solution. The activity of the solute in the saturated solution is often defined using the pure melt at the same temperature as the thermodynamic reference. In chemical engineering literature also the activity of the solid is usually defined on the same reference state. However, far below the melting temperature, the properties of this reference state cannot be determined experimentally, and different simplifications and approximations are normally adopted. In the present work, a novel method is presented to determine the activity of the solute in the saturated solution (=ideal solubility) and the heat capacity difference between the pure supercooled melt and solid. The approach is based on rigorous thermodynamics, using standard experimental thermodynamic data at the melting temperature of the pure compound and solubility measurements in different solvents at various temperatures. The method is illustrated using data for ortho-, meta-, and para-hydroxybenzoic acid, salicylamide and paracetamol. The results show that complete neglect of the heat capacity terms may lead to estimations of the activity that are incorrect by a factor of 12. Other commonly used simplifications may lead to estimations that are only one-third of the correct value

Determination of the activity of a molecular solute in saturated solution

Energy Technology Data Exchange (ETDEWEB)

Nordstroem, Fredrik L. [Department of Chemical Engineering and Technology, Royal Institute of Technology, 100 44 Stockholm (Sweden); Rasmuson, Ake C. [Department of Chemical Engineering and Technology, Royal Institute of Technology, 100 44 Stockholm (Sweden)], E-mail: rasmuson@ket.kth.se

2008-12-15

Prediction of the solubility of a solid molecular compound in a solvent, as well as, estimation of the solution activity coefficient from experimental solubility data both require estimation of the activity of the solute in the saturated solution. The activity of the solute in the saturated solution is often defined using the pure melt at the same temperature as the thermodynamic reference. In chemical engineering literature also the activity of the solid is usually defined on the same reference state. However, far below the melting temperature, the properties of this reference state cannot be determined experimentally, and different simplifications and approximations are normally adopted. In the present work, a novel method is presented to determine the activity of the solute in the saturated solution (=ideal solubility) and the heat capacity difference between the pure supercooled melt and solid. The approach is based on rigorous thermodynamics, using standard experimental thermodynamic data at the melting temperature of the pure compound and solubility measurements in different solvents at various temperatures. The method is illustrated using data for ortho-, meta-, and para-hydroxybenzoic acid, salicylamide and paracetamol. The results show that complete neglect of the heat capacity terms may lead to estimations of the activity that are incorrect by a factor of 12. Other commonly used simplifications may lead to estimations that are only one-third of the correct value.

A Globally Distributed System for Job, Data, and Information Handling for High Energy Physics

Energy Technology Data Exchange (ETDEWEB)

Garzoglio, Gabriele [DePaul Univ., Chicago, IL (United States)

2006-01-13

The computing infrastructures of the modern high energy physics experiments need to address an unprecedented set of requirements. The collaborations consist of hundreds of members from dozens of institutions around the world and the computing power necessary to analyze the data produced surpasses already the capabilities of any single computing center. A software infrastructure capable of seamlessly integrating dozens of computing centers around the world, enabling computing for a large and dynamical group of users, is of fundamental importance for the production of scientific results. Such a computing infrastructure is called a computational grid. The SAM-Grid offers a solution to these problems for CDF and DZero, two of the largest high energy physics experiments in the world, running at Fermilab. The SAM-Grid integrates standard grid middleware, such as Condor-G and the Globus Toolkit, with software developed at Fermilab, organizing the system in three major components: data handling, job handling, and information management. This dissertation presents the challenges and the solutions provided in such a computing infrastructure.

TRANSPORT/HANDLING REQUESTS

CERN Multimedia

Groupe ST/HM

2002-01-01

A new EDH document entitled 'Transport/Handling Request' will be in operation as of Monday, 11th February 2002, when the corresponding icon will be accessible from the EDH desktop, together with the application instructions. This EDH form will replace the paper-format transport/handling request form for all activities involving the transport of equipment and materials. However, the paper form will still be used for all vehicle-hire requests. The introduction of the EDH transport/handling request form is accompanied by the establishment of the following time limits for the various services concerned: 24 hours for the removal of office items, 48 hours for the transport of heavy items (of up to 6 metric tons and of standard road width), 5 working days for a crane operation, extra-heavy transport operation or complete removal, 5 working days for all transport operations relating to LHC installation. ST/HM Group, Logistics Section Tel: 72672 - 72202

Preliminary criteria for the handling of radioactive tea

International Nuclear Information System (INIS)

Oezemre, A.Y.

1993-01-01

Two years after the Chernobyl accident, tea plantations in northeastern Turkey, at Rize and its surroundings especially, were affected by radioactive fallout. As a radiological countermeasure, the turkish Atomic energy commission (AEC) was called in before tea packing and set up a maximum permissible limit of 12,500 Bq/kg for dry tea in the market; 58,078 t of radioactive tea (≥ 25,000 Bq/kg) were set apart as radioactive waste. In its concern to determine the best solution about the handling of radioactive tea and considering the national conditions, the AEC developed four preliminary criteria that led to select the burial option. (author)

Yields of hydrogen peroxide from the reaction of hydroxyl radical with organic compounds in solution and ice

Directory of Open Access Journals (Sweden)

T. Hullar

2011-07-01

Full Text Available Hydrogen peroxide (HOOH is a significant oxidant in atmospheric condensed phases (e.g., cloud and fog drops, aqueous particles, and snow that also photolyzes to form hydroxyl radical (^•OH. ^•OH can react with organics in aqueous phases to form organic peroxyl radicals and ultimately reform HOOH, but the efficiency of this process in atmospheric aqueous phases, as well as snow and ice, is not well understood. We investigate HOOH formation from ^•OH attack on 10 environmentally relevant organic compounds: formaldehyde, formate, glycine, phenylalanine, benzoic acid, octanol, octanal, octanoic acid, octanedioic acid, and 2-butoxyethanol. Liquid and ice samples with and without nitrate (as an ^•OH source were illuminated using simulated solar light, and HOOH formation rates were measured as a function of pH and temperature. For most compounds, the formation rate of HOOH without nitrate was the same as the background formation rate in blank water (i.e., illumination of the organic species does not produce HOOH directly, while formation rates with nitrate were greater than the water control (i.e., reaction of ^•OH with the organic species forms HOOH. Yields of HOOH, defined as the rate of HOOH production divided by the rate of ^•OH production, ranged from essentially zero (glycine to 0.24 (octanal, with an average of 0.12 ± 0.05 (95 % CI. HOOH production rates and yields were higher at lower pH values. There was no temperature dependence of the HOOH yield for formaldehyde or octanedioic acid between −5 to 20 °C and ice samples had approximately the same HOOH yield as the aqueous solutions. In contrast, HOOH yields in formate solutions were higher at 5 and 10 °C compared to −5 and 20 °C. Yields of HOOH in ice for solutions containing nitrate and either phenylalanine, benzoate, octanal, or octanoic acid were indistinguishable from zero. Our HOOH yields were approximately

Equation of liquidus curve of primary crystallization of congruently melting of Asub(m)Bsub(n) compound in regular solutions approximation

International Nuclear Information System (INIS)

Glazov, V.M.; Pavlova, L.M.; Moskvinova, N.A.

1975-01-01

A general solution was obtained for the Prigozhin and Defey equation on the basis of which a liquidus equation was derived describing the primary crystallization of Asub(m)Bsub(n)-type compounds. The Prigozhin and Defey equation described a general case of the melting process of having a narrow homogeneity region at a certain temperature T:(Asub(m)Bsub(n))sub(s) reversible m(A)sub(L) n(B)sub(L). They have obtained a differential equation for the liquids curve describing the equilibrium state between the primary Asub(m)Bsub(n) crystals and the liquid solution. The obtained equation was tested by a comparison with the experimental liquidus curves corresponding to the primary crystallization of gallium and indium sesquitellurides in Ga-Te and In-Te systems. The liquidus curves were made more precise by means of a detailed thermographic study of a series of melts located to the right and left of Ga 2 Te 3 and In 2 Te 3 compounds. Computer calculations of liquidus curves corresponding to the primary crystallization of Ga 2 Te 3 and In 2 Te 3 were carried out with the aid of the last of the above-mentioned equations. The obtained results show that the derived equations can be used in studying the nature of intermolecular reactions in systems in which congruent intermediate phases of complex composition are present

Cask system design guidance for robotic handling

International Nuclear Information System (INIS)

Griesmeyer, J.M.; Drotning, W.D.; Morimoto, A.K.; Bennett, P.C.

1990-10-01

Remote automated cask handling has the potential to reduce both the occupational exposure and the time required to process a nuclear waste transport cask at a handling facility. The ongoing Advanced Handling Technologies Project (AHTP) at Sandia National Laboratories is described. AHTP was initiated to explore the use of advanced robotic systems to perform cask handling operations at handling facilities for radioactive waste, and to provide guidance to cask designers regarding the impact of robotic handling on cask design. The proof-of-concept robotic systems developed in AHTP are intended to extrapolate from currently available commercial systems to the systems that will be available by the time that a repository would be open for operation. The project investigates those cask handling operations that would be performed at a nuclear waste repository facility during cask receiving and handling. The ongoing AHTP indicates that design guidance, rather than design specification, is appropriate, since the requirements for robotic handling do not place severe restrictions on cask design but rather focus on attention to detail and design for limited dexterity. The cask system design features that facilitate robotic handling operations are discussed, and results obtained from AHTP design and operation experience are summarized. The application of these design considerations is illustrated by discussion of the robot systems and their operation on cask feature mock-ups used in the AHTP project. 11 refs., 11 figs

Compilation of Requirements for Safe Handling of Fluorine and Fluorine-Containing Products of Uranium Hexafluoride Conversion

Energy Technology Data Exchange (ETDEWEB)

Ferrada, J.J.

2000-04-03

Public Law (PL) 105-204 requires the U.S. Department of Energy to develop a plan for inclusion in the fiscal year 2000 budget for conversion of the Department's stockpile of depleted uranium hexafluoride (DUF{sub 6}) to a more stable form over an extended period. The conversion process into a more stable form will produce fluorine compounds (e.g., elemental fluorine or hydrofluoric acid) that need to be handled safely. This document compiles the requirements necessary to handle these materials within health and safety standards, which may apply in order to ensure protection of the environment and the safety and health of workers and the public. Fluorine is a pale-yellow gas with a pungent, irritating odor. It is the most reactive nonmetal and will react vigorously with most oxidizable substances at room temperature, frequently with ignition. Fluorine is a severe irritant of the eyes, mucous membranes, skin, and lungs. In humans, the inhalation of high concentrations causes laryngeal spasm and broncospasms, followed by the delayed onset of pulmonary edema. At sublethal levels, severe local irritation and laryngeal spasm will preclude voluntary exposure to high concentrations, unless the individual is trapped or incapacitated. A blast of fluorine gas on the shaved skin of a rabbit causes a second degree burn. Lower concentrations cause severe burns of insidious onset, resulting in ulceration, similar to the effects produced by hydrogen fluoride. Hydrofluoric acid is a colorless, fuming liquid or gas with a pungent odor. It is soluble in water with release of heat. Ingestion of an estimated 1.5 grams produced sudden death without gross pathological damage. Repeated ingestion of small amounts resulted in moderately advanced hardening of the bones. Contact of skin with anhydrous liquid produces severe burns. Inhalation of AHA or aqueous hydrofluoric acid mist or vapors can cause severe respiratory tract irritation that may be fatal. Based on the extreme chemical

Production management of window handles

Directory of Open Access Journals (Sweden)

Manuela Ingaldi

2014-12-01

Full Text Available In the chapter a company involved in the production of aluminum window and door handles was presented. The main customers of the company are primarily companies which produce PCV joinery and wholesalers supplying these companies. One chosen product from the research company - a single-arm pin-lift window handle - was described and its production process depicted technologically. The chapter also includes SWOT analysis conducted in the research company and the value stream of the single-arm pin-lift window handle.

7 CFR 58.443 - Whey handling.

Science.gov (United States)

2010-01-01

... 7 Agriculture 3 2010-01-01 2010-01-01 false Whey handling. 58.443 Section 58.443 Agriculture... Procedures § 58.443 Whey handling. (a) Adequate sanitary facilities shall be provided for the handling of whey. If outside, necessary precautions shall be taken to minimize flies, insects and development of...

Report on the handling of safety information concerning flammable gases and ferrocyanide at the Hanford waste tanks

International Nuclear Information System (INIS)

1990-07-01

This report discusses concerns safety issues, and management at Hanford Tank Farm. Concerns center on the issue of flammable gas generation which could ignite, and on possible exothermic reactions of ferrocyanide compounds which were added to single shell tanks in the 1950's. It is believed that information concerning these issues has been mis-handled and the problems poorly managed

Report on the handling of safety information concerning flammable gases and ferrocyanide at the Hanford waste tanks

Energy Technology Data Exchange (ETDEWEB)

1990-07-01

This report discusses concerns safety issues, and management at Hanford Tank Farm. Concerns center on the issue of flammable gas generation which could ignite, and on possible exothermic reactions of ferrocyanide compounds which were added to single shell tanks in the 1950's. It is believed that information concerning these issues has been mis-handled and the problems poorly managed. (CBS)

Luminescence properties of copper(I), zinc(II) and cadmium(II) coordination compounds with picoline ligands

Energy Technology Data Exchange (ETDEWEB)

Małecki, Jan Grzegorz, E-mail: gmalecki@us.edu.pl; Maroń, Anna

2017-06-15

Mononuclear coordination compounds of copper(I) – [Cu(PPh{sub 3}){sub 2}(picoline)(NO{sub 3})], zinc(II) – [ZnCl{sub 2}(picoline){sub 2}] (picoline=3– and 4–methylpyridine) and polymeric cadmium(II) – [CdCl{sub 2}(β-picoline){sub 2}]{sub n} were prepared and their luminescence properties in solid state and acetonitrile solutions were determined. Single crystal X-ray crystallography revealed distorted tetrahedral geometry around the central ions of the compounds. The compounds exhibit green photoluminescence in solid state and in acetonitrile solutions. The emission of copper(I) compounds originated from metal-to-ligand charge transfer state combined with nitrato-to-picoline charge transfer state i.e. ({sup 1}(M+X)LCT). The presence of nitrato ligand in the coordination sphere of copper(I) compounds quenches the emission. Luminescence of zinc(II) and cadmium(II) compounds results from chloride-to-picoline charge transfer state and the quantum efficiency in the case of the polymeric Cd(II) compound reaches 39%. The photoluminescence quantum yields of the mononuclear zinc(II) compounds vary from 10 to 16% depending on the conditions (solid state, solution). - Graphical abstract: Coordination compounds of copper(I), zinc(II) and polymeric cadmium(II) with picoline ligands were prepared and their luminescence properties in solid state and acetonitrile solutions were determined. The compounds exhibit green photoluminescence in solid state and in acetonitrile solutions. Emission of copper(I) compounds originated from {sup 1}(M+X)LCT state. Luminescence of zinc(II) and cadmium(II) compounds results from chloride-to-picoline charge transfer state and the quantum efficiency in the case of the polymeric Cd(II) compound reaches 39%. The photoluminescence quantum yields of the mononuclear zinc(II) compounds vary from 10 to 16% depending on the conditions (solid state, solution).

Self-aggregation of liquids from biomass in aqueous solution

International Nuclear Information System (INIS)

Lomba, Laura; Giner, Beatriz; Zuriaga, Estefanía; Moya, Juana; Lafuente, Carlos

2013-01-01

Highlights: • Aggregation behaviour of liquids from biomass in aqueous solution has been studied. • Standard Gibbs free energies of aggregation have been calculated. • Solubility in water of these compounds has been determined. • Critical aggregation concentration decreases as the solubility in water does. -- Abstract: Aggregation of several chemicals from biomass: furfural derived compounds (furfural, 5-methylfurfural, furfuryl alcohol and tetrahydrofurfuryl alcohol), lactate derived compounds (methyl lactate, ethyl lactate and butyl lactate), acrylate derived compound (methyl acrylate) and levulinate compounds (methyl levulinate, ethyl levulinate and butyl levulinate) in aqueous solution has been characterised at T = 298.15 K through density, ρ, speed of sound, u, and isentropic compressibilities, κ S , measurements. In addition the standard Gibbs free energies of aggregation have been also calculated. Furthermore, in order to deepen insight the behaviour of these chemicals in aqueous solution, the solubility of these compounds has been measured at T = 298.15 K

Analysis of Pharmaceutical and Personal Care Compounds in Wastewater Sludge and Aqueous Samples using GC-MS/MS

Energy Technology Data Exchange (ETDEWEB)

Zhong, Lirong [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mitroshkov, Alexandre V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Gilmore, Tyler J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2016-03-15

The Bioenergy Program at Pacific Northwest National Laboratory (PNNL) is evaluating the feasibility of converting wastewater sludge materials to fuels. Wastewater sludge from various municipalities will be used in the evaluation process and as with any municipal waste, there is the potential for residual contaminates to remain in the sludge following wastewater treatment. Many surveys and studies have confirmed the presence of pharmaceuticals in municipal wastewater and effluents (World Health Organization, 2011). Determination of the presence and concentrations of the contaminants is required to define the proper handling of this sludge. A list of targeted compounds was acquired from the literature and an analytical method was developed for the pharmaceutical and personal care compounds. The presence of organics complicated the analytical techniques and, in some cases, the precision of the results. However, residual concentrations of a range of compounds were detected in the wastewater sludge and the presence and concentrations of these compounds will be considered in identifying the appropriate handling of this material in conduct of research.

Development of commercial robots for radwaste handling

International Nuclear Information System (INIS)

Colborn, K.A.

1988-01-01

The cost and dose burden associated with low level radwaste handling activities is a matter of increasing concern to the commercial nuclear power industry. This concern is evidenced by the fact that many utilities have begun to revaluate waste generation, handling, and disposal activities at their plants in an effort to improve their overall radwaste handling operations. This paper reports on the project Robots for Radwaste Handling, to identify the potential of robots to improve radwaste handling operations. The project has focussed on the potential of remote or automated technology to improve well defined, recognizable radwaste operations. The project focussed on repetitive, low skill level radwaste handling and decontamination tasks which involve significant radiation exposure

Behaviour of organic sulfur compounds in HPLC

International Nuclear Information System (INIS)

Freyholdt, T.

1982-01-01

The retention behaviour of organic sulfur compounds in the reverse-bonded-phase chromatography is characterized by determining the retention indices according to Kovats. The results of these studies show that the solubility of organic compounds in the eluting agent and the molar sorption surfaces of the solutes are the main factors determining the retention behaviour. Knowledge of the retention indices of above-mentioned compounds allows a quick interpretation of chromatograms obtained through a product analysis of γ-irradiated aqueous solutions of organic sulfur compounds. Dithia compounds of the type CH 3 -S-(CH 2 )sub(n)-S-Ch 3 (1 1. 2,4-Dithiapentane (n = 1) however will yield primarily monothio-S-methyl formate as a stable end product. The formation of oxygenic reaction products proceeds via sulfur-centred radical kations. Spin trapping experiments with nitroxyl radicals show that it is possible to trap radiation-chemically produced radicals of sulfurous substrates, but the thus obtained adducts with half-life periods of 4-5 min. cannot be identified by means of NMR, IR or mass spectroscopy. (orig.) [de

Overview of toxicity data and risk assessment methods for evaluating the chemical effects of depleted uranium compounds

International Nuclear Information System (INIS)

Hartmann, H.M.; Monette, F.A.; Avci, H.I.

2000-01-01

In the United States, depleted uranium is handled or used in several chemical forms by both governmental agencies and private industry (primarily companies producing and machining depleted uranium metal for military applications). Human exposure can occur as a result of handling these compounds, routine low-level effluent releases to the environment from processing facilities, or materials being accidentally released from storage locations or during processing or transportation. Exposure to uranium can result in both chemical and radiological toxicity, but in most instances chemical toxicity is of greater concern. This article discusses the chemical toxic effects from human exposure to depleted uranium compounds that are likely to be handled during the long-term management and use of depleted uranium hexafluoride (UF 6 ) inventories in the United States. It also reviews representative publications in the toxicological literature to establish appropriate reference values for risk assessments. Methods are described for evaluating chemical toxicity caused by chronic low-level exposure and acute exposure. Example risk evaluations are provided for illustration. Preliminary results indicate that chemical effects of chronic exposure to uranium compounds under normal operating conditions would be negligibly small. Results also show that acute exposures under certain accident conditions could cause adverse chemical effects among the populations exposed.

Development of a novel and customizable two-solution mixing type spray nozzle for one-step preparation of nanoparticle-containing microparticles.

Science.gov (United States)

Ozeki, Tetsuya; Akiyama, Yusuke; Takahashi, Norimitsu; Tagami, Tatsuaki; Tanaka, Toshiyuki; Fujii, Masashi; Okada, Hiroaki

2012-01-01

Production of drug nanoparticles is an effective strategy to enhance solubility and oral absorption of water-insoluble drugs. The handling of drug nanoparticles has been an important issue in drug formulation because nanoparticles easily aggregate each other and redispersion of these particles is very difficult. In the present study, we developed a unique two-solution mixing type spray nozzle that can prepare drug nanoparticles in microparticles in one step without any common solvent and surfactant, and then, the prepared formulation were evaluated. Ethylcellulose (EC) and mannitol (MAN) were used as a model polymer of water-insoluble compound and a water-soluble carrier, respectively. We characterized the EC/MAN microparticles produced by the novel spray nozzle when customizing the nozzle parts to mix EC and MAN solution. Relatively smaller EC nanoparticles (customizable parts in the nozzle. In addition, the core of EC nanoparticles (<50 nm) was also observed by atomic force microscopy. We also found that the mixing time in the nozzle parts affected the size and the standard deviation of EC nanoparticles. These results suggest that the size of EC nanoparticles in MAN microparticles is controllable by using this unique nozzle. After all, we could prepare MAN microparticles containing EC nanoparticles in one step by using the novel nozzle. The drug/MAN microparticles formulation produced by the nozzle may be useful for the handling of drug nanoparticles.

Preoperational checkout of the remote-handled transuranic waste handling at the Waste Isolation Pilot Plant

International Nuclear Information System (INIS)

1987-09-01

This plan describes the preoperational checkout for handling Remote-Handled Transuranic (RH-TRU) Wastes from their receipt at the Waste Isolation Pilot Plant (WIPP) to their emplacement underground. This plan identifies the handling operations to be performed, personnel groups responsible for executing these operations, and required equipment items. In addition, this plan describes the quality assurance that will be exercised throughout the checkout, and finally, it establishes criteria by which to measure the success of the checkout. 7 refs., 5 figs

Preference Handling for Artificial Intelligence

OpenAIRE

Goldsmith, Judy; University of Kentucky; Junker, Ulrich; ILOG

2009-01-01

This article explains the benefits of preferences for AI systems and draws a picture of current AI research on preference handling. It thus provides an introduction to the topics covered by this special issue on preference handling.

Religious Serpent Handling and Community Relations.

Science.gov (United States)

Williamson, W Paul; Hood, Ralph W

2015-01-01

Christian serpent handling sects of Appalachia comprise a community that has long been mischaracterized and marginalized by the larger communities surrounding them. To explore this dynamic, this article traces the emergence of serpent handling in Appalachia and the emergence of anti-serpent-handling state laws, which eventually failed to curb the practice, as local communities gave serpent handling groups support. We present two studies to consider for improving community relations with serpent handling sects. In study 1, we present data relating the incidence of reported serpent-bite deaths with the rise of anti-serpent-handling laws and their eventual abatement, based on increasing acceptance of serpent handlers by the larger community. Study 2 presents interview data on serpent bites and death that provide explanations for these events from the cultural and religious perspective. We conclude that first-hand knowledge about serpent handlers, and other marginalized groups, helps to lessen suspicion and allows them to be seen as not much different, which are tendencies that are important for promoting inter-community harmony.

Expanded Occupational Safety and Health Administration 300 log as metric for bariatric patient-handling staff injuries.

Science.gov (United States)

Randall, Stephen B; Pories, Walter J; Pearson, Amy; Drake, Daniel J

2009-01-01

injury associated with manual bariatric patient handling should help healthcare institutions identify deficiencies in their current injury prevention program and focus resources more precisely for safer, systems-based bariatric patient-handling solutions. Effective patient handling systems should also reduce the aura of fear that might be present in some caregivers when mobilizing a bariatric patient.

Safe handling of tritium

International Nuclear Information System (INIS)

1991-01-01

The main objective of this publication is to provide practical guidance and recommendations on operational radiation protection aspects related to the safe handling of tritium in laboratories, industrial-scale nuclear facilities such as heavy-water reactors, tritium removal plants and fission fuel reprocessing plants, and facilities for manufacturing commercial tritium-containing devices and radiochemicals. The requirements of nuclear fusion reactors are not addressed specifically, since there is as yet no tritium handling experience with them. However, much of the material covered is expected to be relevant to them as well. Annex III briefly addresses problems in the comparatively small-scale use of tritium at universities, medical research centres and similar establishments. However, the main subject of this publication is the handling of larger quantities of tritium. Operational aspects include designing for tritium safety, safe handling practice, the selection of tritium-compatible materials and equipment, exposure assessment, monitoring, contamination control and the design and use of personal protective equipment. This publication does not address the technologies involved in tritium control and cleanup of effluents, tritium removal, or immobilization and disposal of tritium wastes, nor does it address the environmental behaviour of tritium. Refs, figs and tabs

How Retailers Handle Complaint Management

DEFF Research Database (Denmark)

Hansen, Torben; Wilke, Ricky; Zaichkowsky, Judy

2009-01-01

This article fills a gap in the literature by providing insight about the handling of complaint management (CM) across a large cross section of retailers in the grocery, furniture, electronic and auto sectors. Determinants of retailers’ CM handling are investigated and insight is gained as to the......This article fills a gap in the literature by providing insight about the handling of complaint management (CM) across a large cross section of retailers in the grocery, furniture, electronic and auto sectors. Determinants of retailers’ CM handling are investigated and insight is gained...... as to the links between CM and redress of consumers’ complaints. The results suggest that retailers who attach large negative consequences to consumer dissatisfaction are more likely than other retailers to develop a positive strategic view on customer complaining, but at the same time an increase in perceived...

7 CFR 926.9 - Handle.

Science.gov (United States)

2010-01-01

... the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Marketing Agreements and Orders; Fruits, Vegetables, Nuts), DEPARTMENT OF AGRICULTURE DATA COLLECTION, REPORTING AND RECORDKEEPING REQUIREMENTS APPLICABLE TO CRANBERRIES NOT SUBJECT TO THE CRANBERRY MARKETING ORDER § 926.9 Handle. Handle...

Molar extinction coefficients of solutions of some organic compounds

Indian Academy of Sciences (India)

efficients of these compounds have been used to calculate effective atomic numbers and electron densities. The additivity ... Molar extinction coefficients; effective atomic numbers; electron density. PACS Nos 29.30. ... the radiation path and is linearly dependent on the concentration of the absorbing species. This is most ...

INFLUENCE OF INORGANIC COMPOUNDS ON THE PROCESS OF PHOTOCATALYSIS OF BIOLOGICALLY ACTIVE COMPOUNDS

Directory of Open Access Journals (Sweden)

Edyta Kudlek

2017-07-01

Full Text Available Constant increase in concentration of organic micropollutants in the water environment influences the development of methods for their effective elimination from various matrices released into aquatic ecosystems. One of widely described in literature processes for the decomposition of hardly-biodegradable pollutants is the process of heterogeneous photocatalysis. The paper presents the influence of inorganic substances on the decomposition of polycyclic aromatic hydrocarbons (anthracene and benzo[a]pyrene, industrial admixtures - octylphenol and pharmaceutical compounds - diclofenac in the photocatalysis process conducted in the presence of TiO2. It has been shown that the presence of Cl- ions did not affect the photochemical reaction of the micropollutant decomposition. Whereas, the presence of CO3(2-, SO4(2- and HPO4(2- ions inhibited the decolonization of octylphenol and diclofenac, while the degradation efficiency of anthracene and benzo[a]pyrene was reduced only by the presence of CO3(2- and HCO3- anions. The photooxidation of micropollutants in solutions containing Al(3+ oraz Fe(3+ cations proceeded with a much lower efficiency than that for solution without inorganic compounds. The analysis of the kinetics of the photocatalytic decomposition of selected micropollutants show a decrease in the reaction rate constant and an increase in their half-life due to the blocking of theactive semiconductor centers by inorganic compounds. In addition,the toxicological analysis inducated the generation of micropollutant oxidation by-products, which aggravate the quality of treated aqueous solutions.

Thoron and associated risks in the handling of thorium compounds

International Nuclear Information System (INIS)

Pradel, J.; Billard, F.

1959-01-01

1. Thorium compounds continually give off thoron and its daughters and their radioactivity can constitute a danger for operators who may inhale them. 2. By analogy with radon the maximum admissible content in air of thoron and its daughters has been set at 10 -7 μc/cm 3 . However the differences in behaviour between radon and its active deposit on the one hand, and thoron and its daughters on the other, appear great enough to justify more thorough investigation. In fact it seemed probable that, contrary to what takes place with radon, the thoron + thorium A content at a given point may differ appreciable from the thorium B + thorium C + thorium C' + thorium C'' content at the same point, because of the considerable differences in half-life which allow a greater or lesser distribution. 3. To determine the relative concentrations it was necessary to develop a method for estimating thoron in equilibrium with thorium A, the measurement of thorium B and its daughters being carried out in the conventional way by counting the activity collected on a filter. 4. Another object of this study was to estimate the danger presented by thoron in equilibrium with thorium A in the immediate vicinity of thorium sources, in a plant extracting thorium from urano-thorianite. (author) [fr

Effects of solution P H on the adsorption of aromatic compounds from aqueous solutions by activated carbon

International Nuclear Information System (INIS)

Nouri, S.; Haghseresht, F.; Lu, M.

2002-01-01

Absorption of p-Cresol, Benzoic acid and Nitro Benzene by activated carbon from dilute aqueous solutions was carried out under controlled ph conditions at 310 k. In acidic conditions, well below the pK a of all solutes, it was observed that the adsorbate solubility and the electron density of its aromatic ring were the influencing factors on the extent of the adsorption by affecting the extent of London dispersion forces. In higher solution ph conditions, on the other hand, it was found that the electrostatic forces played a significant role on the extent of adsorption. The Effect of ph must be considered from its combined effects on the carbon surface and on the solute molecules. It was found that the uptake of the molecular forms of the aromatic solutes was dependent on the substituents of the aromatic ring. Adsorption of the solutes in higher P H values was found to be dependent on the concentration of anionic form of the solutes. All isotherms were fitted into Freundlich Isotherm Equations

Remote handling at LAMPF

International Nuclear Information System (INIS)

Grisham, D.L.; Lambert, J.E.

1983-01-01

Experimental area A at the Clinton P. Anderson Meson Physics Facility (LAMPF) encompasses a large area. Presently there are four experimental target cells along the main proton beam line that have become highly radioactive, thus dictating that all maintenance be performed remotely. The Monitor remote handling system was developed to perform in situ maintenance at any location within area A. Due to the complexity of experimental systems and confined space, conventional remote handling methods based upon hot cell and/or hot bay concepts are not workable. Contrary to conventional remote handling which require special tooling for each specifically planned operation, the Monitor concept is aimed at providing a totally flexible system capable of remotely performing general mechanical and electrical maintenance operations using standard tools. The Monitor system is described

Radiation-induced destruction of organic compounds in aqueous solutions by dual oxidation/reduction mechanism

Energy Technology Data Exchange (ETDEWEB)

Chaychiana, M.; Silverman, J.; Al-Sheikhly, M. [Department of Materials Science and Engineering, University of Maryland (United States); Poster, D.; Neta, P.; Huie, R. [Chemical Science and Technology Laboratory, National Institute of Standard and Technology (United States)

2011-07-01

This research presents the feasibility and mechanisms of using high energy electrons for the dechlorination of polychlorinated biphenyls (PCBs) in marine sediment, and hazardous organic compounds in waste water. The remediation of the organic contaminants by ionizing radiation is achieved by means of both reduction and oxidation processes. PCBs in marine sediment can be effectively dechlorinated by reduction, while toxic organic compounds in water are removed mainly by oxidation. Radiolytic degradation of aqueous suspensions of PCBs in marine sediments in the presence of isopropanol was also studied. Addition of isopropanol was necessary to enhance the radiolytic yield and the dechlorination of PCBs. Also presented are results from an examination of the oxidative and reductive effects of electron-beam irradiation on the concentrations of six organic solvents in water. The organic solvents in water were prepared to mimic a pharmaceutical waste stream. Radiation-induced destruction of benzene was also investigated using pulse radiolysis technique. Pulse radiolysis with spectrophotometric and conductometric detection was utilized to study the formation and reactions of radicals from benzene and dienes in aqueous solutions. The benzene OH adduct, {sup ●}C{sub 6}H{sub 6}OH, reacts with O{sub 2} (k = 3x10{sup 8} L mol{sup -1} s{sup -1}) in a reversible reaction. The peroxyl radical, HOC{sub 6}H{sub 6}O{sub 2}{sup ●}, undergoes O{sub 2}●- elimination, bimolecular decay, and reaction with benzene to initiate a chain reaction, depending on the dose rate, benzene concentration, and pH. The occurrence of the chain reaction is demonstrated in low-dose-rate gamma radiolysis experiments where the consumption of O{sub 2} was monitored. (author)

Process for removing a mixture containing iodine and alkyl iodine compounds from a gas phase or aqueous solution with ion-exchange resins

Energy Technology Data Exchange (ETDEWEB)

Shimizu, H; Mizuuchi, A; Yokoyama, F

1968-10-04

Iodine and alkyl iodine compounds are removed from a gas phase or aqueous solution containing salts, iodine and iodine compounds, such as the ambient gas in a reactor, if an accident should occur. The process comprises contacting the phase or solution: (a) with a hydrogen type strongly acidic cationic exchange resin, (b) with an anionic exchange resin containing quarternary ammonium and (c) with an anionic exchange resin containing free basic type tertiary amine, in this order or by reversing the order of the two anionic exchange resins. Although no problems arise in the liquid phase reaction, the ion-exchange resins in the gas phase reaction are desired in the moist state in order to stable maintain the migration speed of the materials to be removed regardless of the relative humidity of the amibent gas. In example I, Amberlite IRA-900 of 200 mm thickness as the lowermost bed, Amberlite IRA93 of 200 mm thickness as the middle bed and Amberlite 200 of 200 mm thickness as the uppermost bed were filled respectively, in a methacrylate resin cylinder with an inner diameter of 25 mm. A solution containing 15.9 mg/1 of iodine, 41.2 mg/1 of methyl iodide and 550 mg/1 of sodium carbonate flows at a rate of 15 liter/hr downward through the beds. As a result of testing, no iodine, iodine ions, iodic acid ions and methyl iodine were detected. The amount of water the beds could treat was 60 times the total quantity of the filled resins.

From proton nuclear magnetic resonance spectra to pH. Assessment of {sup 1}H NMR pH indicator compound set for deuterium oxide solutions

Energy Technology Data Exchange (ETDEWEB)

Tynkkynen, Tuulia, E-mail: tuulia.tynkkynen@uku.fi [Laboratory of Chemistry, Department of Biosciences, University of Kuopio, PO Box 1627, 70211 Kuopio (Finland); Tiainen, Mika; Soininen, Pasi; Laatikainen, Reino [Laboratory of Chemistry, Department of Biosciences, University of Kuopio, PO Box 1627, 70211 Kuopio (Finland)

2009-08-19

In this study, a protocol for pH determination from D{sub 2}O samples using {sup 1}H NMR pH indicator compounds was developed and assessed by exploring the pH-dependency of 13 compounds giving pH-dependent {sup 1}H NMR signals. The indicators cover the pH range from pH* 0 to 7.2. Equations to transform the indicator chemical shifts to pH estimates are given here for acetic acid, formic acid, chloroacetic acid, dichloroacetic acid, creatine, creatinine, glycine, histidine, 1,2,4-triazole, and TSP (2,2,3,3-tetradeutero-3-(trimethylsilyl)-propionic acid). To characterize the method in presence of typical solutes, the effects of common metabolites, albumin and ionic strength were also evaluated. For the ionic strengths, the effects were also modelled. The experiments showed that the use of pH sensitive {sup 1}H NMR chemical shifts allows the pH determination of typical metabolite solutions with accuracy of 0.01-0.05 pH units. Also, when the ionic strength is known with accuracy better than 0.1 mol dm{sup -3} and the solute concentrations are low, pH{sub nmr}{sup *} (the NMR estimate of pH) can be assumed to be within 0.05 pH units from potentiometrically determined pH.

MRI of meniscal bucket-handle tears

Energy Technology Data Exchange (ETDEWEB)

Magee, T.H.; Hinson, G.W. [Menorah Medical Center, Overland Park, KS (United States). Dept. of Radiology

1998-09-01

A meniscal bucket-handle tear is a tear with an attached fragment displaced from the meniscus of the knee joint. Low sensitivity of MRI for detection of bucket-handle tears (64% as compared with arthroscopy) has been reported previously. We report increased sensitivity for detecting bucket-handle tears with the use of coronal short tau inversion recovery (STIR) images. Results. By using four criteria for diagnosis of meniscal bucket-handle tears, our overall sensitivity compared with arthroscopy was 93% (28 of 30 meniscal bucket-handle tears seen at arthroscopy were detected by MRI). The meniscal fragment was well visualized in all 28 cases on coronal STIR images. The double posterior cruciate ligament sign was seen in 8 of 30 cases, the flipped meniscus was seen in 10 of 30 cases and a fragment in the intercondylar notch was seen in 18 of 30 cases. (orig.)

EPR investigations on technetium compounds

International Nuclear Information System (INIS)

Abram, U.; Munze, R.; Kirmse, R.; Stach, J.

1986-01-01

Stimulated by the widespread use of the isotope /sup 99m/Tc in the field of nuclear medicine, there has been a substantial growth of interest in the chemistry of this man-made element. A particular need emerges for analytical methods allowing solution investigations of coordination compounds of technetium with low substance use. Considering these facts, Electron Paramagnetic Resonance Spectroscopy (EPR) appears to be a very suitable method because only very small amounts of the compounds are needed (lower than 1 mg). The resulting spectra give information regarding the valence state, symmetry and bonding properties of the compounds under study

MyMolDB: a micromolecular database solution with open source and free components.

Science.gov (United States)

Xia, Bing; Tai, Zheng-Fu; Gu, Yu-Cheng; Li, Bang-Jing; Ding, Li-Sheng; Zhou, Yan

2011-10-01

To manage chemical structures in small laboratories is one of the important daily tasks. Few solutions are available on the internet, and most of them are closed source applications. The open-source applications typically have limited capability and basic cheminformatics functionalities. In this article, we describe an open-source solution to manage chemicals in research groups based on open source and free components. It has a user-friendly interface with the functions of chemical handling and intensive searching. MyMolDB is a micromolecular database solution that supports exact, substructure, similarity, and combined searching. This solution is mainly implemented using scripting language Python with a web-based interface for compound management and searching. Almost all the searches are in essence done with pure SQL on the database by using the high performance of the database engine. Thus, impressive searching speed has been archived in large data sets for no external Central Processing Unit (CPU) consuming languages were involved in the key procedure of the searching. MyMolDB is an open-source software and can be modified and/or redistributed under GNU General Public License version 3 published by the Free Software Foundation (Free Software Foundation Inc. The GNU General Public License, Version 3, 2007. Available at: http://www.gnu.org/licenses/gpl.html). The software itself can be found at http://code.google.com/p/mymoldb/. Copyright © 2011 Wiley Periodicals, Inc.

Carbon-13 magnetic relaxation rates or iron (III) complexes of some biogenic amines and parent compounds in aqueous solutions

International Nuclear Information System (INIS)

Lai, A.; Monduzzi, M.; Saba, G.

1980-01-01

Spin-lattice relaxation rates (R 1 ) from naturally occuring C-13 F.T. N.M.R. spectra of some catecholamines and parent compounds with Iron(III) at pD = 4 were determined in order to elucidate the molecular mechanism underlying their association in aqueous solutions. Complexation was observed only for catecholic ligands. The R 1 values were used to calculate iron-carbon scaled distances, and two complexation models were proposed where the catecholic function binds Fe(III) in the first and second coordination spheres respectively. The latter case was shown to be the consistent with the molecular geometries. (orig.)

METHOD OF RECOVERING URANIUM COMPOUNDS

Science.gov (United States)

Poirier, R.H.

1957-10-29

S>The recovery of uranium compounds which have been adsorbed on anion exchange resins is discussed. The uranium and thorium-containing residues from monazite processed by alkali hydroxide are separated from solution, and leached with an alkali metal carbonate solution, whereby the uranium and thorium hydrorides are dissolved. The carbonate solution is then passed over an anion exchange resin causing the uranium to be adsorbed while the thorium remains in solution. The uranium may be recovered by contacting the uranium-holding resin with an aqueous ammonium carbonate solution whereby the uranium values are eluted from the resin and then heating the eluate whereby carbon dioxide and ammonia are given off, the pH value of the solution is lowered, and the uranium is precipitated.

Sophisticated fuel handling system evolved

International Nuclear Information System (INIS)

Ross, D.A.

1988-01-01

The control systems at Sellafield fuel handling plant are described. The requirements called for built-in diagnostic features as well as the ability to handle a large sequencing application. Speed was also important; responses better than 50ms were required. The control systems are used to automate operations within each of the three main process caves - two Magnox fuel decanners and an advanced gas-cooled reactor fuel dismantler. The fuel route within the fuel handling plant is illustrated and described. ASPIC (Automated Sequence Package for Industrial Control) which was developed as a controller for the plant processes is described. (U.K.)

Quenching characteristics of bathocuproinedisulfonic acid, disodium salt in aqueous solution and copper sulfate plating solution

Science.gov (United States)

Koga, Toshiaki; Hirakawa, Chieko; Takeshita, Michinori; Terasaki, Nao

2018-04-01

Bathocuproinedisulfonic acid, disodium salt (BCS) is generally used to detect Cu(I) through a color reaction. We newly found BCS fluorescence in the visible blue region in an aqueous solution. However, the fluorescence mechanism of BCS is not well known, so we should investigate its fundamental information. We confirmed that the characteristics of fluorescence are highly dependent on the molecular concentration and solvent properties. In particular, owing to the presence of the copper compound, the fluorescence intensity extremely decreases. By fluorescence quenching, we observed that a copper compound concentration of 10-6 mol/L or less could easily be measured in an aqueous solution. We also observed BCS fluorescence in copper sulfate plating solution and the possibility of detecting monovalent copper by fluorescence reabsorption.

Simplified Production of Organic Compounds Containing High Enantiomer Excesses

Science.gov (United States)

Cooper, George W. (Inventor)

2015-01-01

The present invention is directed to a method for making an enantiomeric organic compound having a high amount of enantiomer excesses including the steps of a) providing an aqueous solution including an initial reactant and a catalyst; and b) subjecting said aqueous solution simultaneously to a magnetic field and photolysis radiation such that said photolysis radiation produces light rays that run substantially parallel or anti-parallel to the magnetic field passing through said aqueous solution, wherein said catalyst reacts with said initial reactant to form the enantiomeric organic compound having a high amount of enantiomer excesses.

The natural angle between the hand and handle and the effect of handle orientation on wrist radial/ulnar deviation during maximal push exertions.

Science.gov (United States)

Young, Justin G; Lin, Jia-Hua; Chang, Chien-Chi; McGorry, Raymond W

2013-01-01

The purpose of this experiment was to quantify the natural angle between the hand and a handle, and to investigate three design factors: handle rotation, handle tilt and between-handle width on the natural angle as well as resultant wrist radial/ulnar deviation ('RUD') for pushing tasks. Photographs taken of the right upper limb of 31 participants (14 women and 17 men) performing maximal seated push exertions on different handles were analysed. Natural hand/handle angle and RUD were assessed. It was found that all of the three design factors significantly affected natural handle angle and wrist RUD, but participant gender did not. The natural angle between the hand and the cylindrical handle was 65 ± 7°. Wrist deviation was reduced for handles that were rotated 0° (horizontal) and at the narrow width (31 cm). Handles that were tilted forward 15° reduced radial deviation consistently (12-13°) across handle conditions. Manual materials handling (MMH) tasks involving pushing have been related to increased risk of musculoskeletal injury. This study shows that handle orientation influences hand and wrist posture during pushing, and suggests that the design of push handles on carts and other MMH aids can be improved by adjusting their orientation to fit the natural interface between the hand and handle.

A MGy radiation-hardened sensor instrumentation link for nuclear reactor monitoring and remote handling

Energy Technology Data Exchange (ETDEWEB)

Verbeeck, Jens; Cao, Ying [KU Leuven - KUL, Div. LRD-MAGyICS, Kasteelpark Arenberg 10, 3001 Heverlee (Belgium); Van Uffelen, Marco; Mont Casellas, Laura; Damiani, Carlo; Morales, Emilio Ruiz; Santana, Roberto Ranz [Fusion for Energy - F4E, c/Josep,n deg. 2, Torres Diagonal Litoral, Ed. B3, 08019 Barcelona (Spain); Meek, Richard; Haist, Bernhard [Oxford Technologies Ltd. OTL, 7 Nuffield Way, Abingdon OX14 1RL (United Kingdom); De Cock, Wouter; Vermeeren, Ludo [SCK-CEN, Boeretang 200, 2400 Mol (Belgium); Steyaert, Michiel [KU Leuven, ESAT-MICAS, KasteelparkArenberg 10, 3001 Heverlee (Belgium); Leroux, Paul [KU Leuven, ESAT-MICAS, KasteelparkArenberg 10, 3001 Heverlee (Belgium)

2015-07-01

Decommissioning, dismantling and remote handling applications in nuclear facilities all require robotic solutions that are able to survive in radiation environments. Recently raised safety, radiation hardness and cost efficiency demands from both the nuclear regulatory and the society impose severe challenges in traditional methods. For example, in case of the dismantling of the Fukushima sites, solutions that survive accumulated doses higher than 1 MGy are mandatory. To allow remote operation of these tools in nuclear environments, electronics were used to be shielded with several centimeters of lead or even completely banned in these solutions. However, shielding electronics always leads to bulky and heavy solutions, which reduces the flexibility of robotic tools. It also requires longer repair time and produces extra waste further in a dismantling or decommissioning cycle. In addition, often in current reactor designs, due to size restrictions and the need to inspect very tight areas there are limitations to the use of shielding. A MGy radiation-hardened sensor instrumentation link developed by MAGyICS provides a solution to build a flexible, easy removable and small I and C module with MGy radiation tolerance without any shielding. Hereby it removes all these pains to implement electronics in robotic tools. The demonstrated solution in this poster is developed for ITER Remote Handling equipments operating in high radiation environments (>1 MGy) in and around the Tokamak. In order to obtain adequately accurate instrumentation and control information, as well as to ease the umbilical management, there is a need of front-end electronics that will have to be located close to those actuators and sensors on the remote handling tool. In particular, for diverter remote handling, it is estimated that these components will face gamma radiation up to 300 Gy/h (in-vessel) and a total dose of 1 MGy. The radiation-hardened sensor instrumentation link presented here, consists

9 CFR 3.118 - Handling.

Science.gov (United States)

2010-01-01

... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Handling. 3.118 Section 3.118 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE ANIMAL WELFARE STANDARDS Specifications for the Humane Handling, Care, Treatment, and Transportation of Marine...

Safety measuring for sodium handling

Energy Technology Data Exchange (ETDEWEB)

Jeong, Ji Young; Jeong, K C; Kim, T J; Kim, B H; Choi, J H

2001-09-01

This is the report for the safety measures of sodium handling. These contents are prerequisites for the development of sodium technology and thus the workers participate in sodium handling and experiments have to know them perfectly. As an appendix, the relating parts of the laws are presented.

Low temperature solution synthesis of zinc antimonide, manganese antimonide, and strontium ruthenate compounds

Science.gov (United States)

Noblitt, Jennifer Lenkner

2011-12-01

Increasing energy demands are fueling research in the area of renewable energy and energy storage. In particular, Li-ion batteries and superconducting wires are attractive choices for energy storage. Improving safety, simplifying manufacturing processes, and advancing technology to increase energy storage capacity is necessary to compete with current marketed energy storage devices. These advancements are accomplished through the study of new materials and new morphologies. Increasing dependence on and rising demand for portable electronic devices has continued to drive research in the area of Li-ion batteries. In order to compete with existing batteries and be applicable to future energy needs such as powering hybrid vehicles, the drawbacks of Li-ion batteries must be addressed including (i) low power density, (ii) safety, and (iii) high manufacturing costs. These drawbacks can be addressed through new materials and morphologies for the anode, cathode, and electrolyte. New intermetallic anode materials such as ZnSb, MnSb, and Mn2Sb are attractive candidates to replace graphite, the current industry standard anode material, because they are safer while maintaining comparable theoretical capacity. Electrodeposition is an inexpensive method that could be used for the synthesis of these electrode materials. Direct electrodeposition allows for excellent electrical contact to the current collector without the use of a binder. To successfully electrodeposit zinc and manganese antimonides, metal precursors with excellent solubility in water were needed. To promote solubility, particularly for the antimony precursor, coordinating ligands were added to the deposition bath solutions. This work shows that the choice of coordinating ligand and metal-ligand speciation can alter both the electrochemistry and the film composition. This work focuses on the search for appropriate coordinating ligands, solution pH, and bath temperatures so that high quality films of ZnSb, MnSb, and

Gas-liquid partitioning of halogenated volatile organic compounds in aqueous cyclodextrin solutions

Energy Technology Data Exchange (ETDEWEB)

Ondo, Daniel; Barankova, Eva [Department of Physical Chemistry, Institute of Chemical Technology, Technicka 5, 166 28 Prague 6 (Czech Republic); Dohnal, Vladimir, E-mail: dohnalv@vscht.cz [Department of Physical Chemistry, Institute of Chemical Technology, Technicka 5, 166 28 Prague 6 (Czech Republic)

2011-08-15

Highlights: > Binding of halogenated VOCs with cyclodextrins examined through g-l partitioning. > Complex stabilities reflect host-guest size matching and hydrophobic interaction. > Presence of halogens in the guest molecule stabilizes the binding. > Thermodynamic origin of the binding varies greatly among the systems studied. > Results obey the guest-CD global enthalpy-entropy compensation relationship. - Abstract: Gas-liquid partitioning coefficients (K{sub GL}) were measured for halogenated volatile organic compounds (VOCs), namely 1-chlorobutane, methoxyflurane, pentafluoropropan-1-ol, heptafluorobutan-1-ol, {alpha},{alpha},{alpha}-trifluorotoluene, and toluene in aqueous solutions of natural {alpha}-, {beta}-, and {gamma}-cyclodextrins (CDs) at temperatures from (273.35 to 326.35) K employing the techniques of headspace gas chromatography and inert gas stripping. The binding constants of the 1:1 inclusion complex formation between the VOCs and CDs were evaluated from the depression of the VOCs volatility as a function of CD concentration. The host-guest size matching and the hydrophobic interaction concept were used to rationalize the observed widely different affinity of the VOC-CD pairs to form the inclusion complex. The enthalpic and entropic component of the standard Gibbs free energy of complex formation as derived from the temperature dependence of the binding constant indicate the thermodynamic origin of the binding to vary greatly among the systems studied, but follow the global enthalpy-entropy compensation relationships reported previously in the literature.

Study of ITER equatorial port plug handling system and vacuum sealing interface

Energy Technology Data Exchange (ETDEWEB)

Martins, Jean-Pierre [Association Euratom CEA, CEA/DSM/IRFM, Cadarache, F-13108 Saint-Paul-lez-Durance (France)], E-mail: jean-pierre.martins@cea.fr; Doceul, Louis; Marol, Sebastien; Delchie, Elise [Association Euratom CEA, CEA/DSM/IRFM, Cadarache, F-13108 Saint-Paul-lez-Durance (France); Cordier, Jean-Jacques; Levesy, Bruno; Tesini, Alessandro [ITER International Organization, F-13108 Saint-Paul-lez-Durance cedex (France); Ciattaglia, Emanuela [EFDA CSU - Garching, Boltzmannstr. 2, D-85748 Garching (Germany); Tivey, Richard [Max-Planck-Institut fuer Plasmaphysik, Boltzmannstr. 2, 85748 Garching (Germany); Gillier, Rene; Abbes, Christophe [GARLOCK - Sealing Technologies - 90, rue de la roche du Geai, F-42029 St-Etienne cedex 1 (France)

2009-06-15

In the field of the ITER port plug engineering and integration task, CEA has contributed to define proposals concerning the port plugs vacuum sealing interface with the vessel flange and the equatorial plug handling. The 2001 baseline vacuum flange sealing consisted of TIG welding of a 316L strip plate on to U shapes. This arrangement presented some issues like welding access, implementation of tools, lip consumption, complex local leak test, continuous leak checking. Therefore, an alternate sealing solution based on the use of metallic gaskets is proposed. The different technical aspects are discussed to explain how this design can simplify the maintenance and deal with safety and vacuum requirements. The design of the mechanical attachment and vacuum sealing of the plug has constantly evolved, but the associated remote handling equipment was not systematically reviewed. An update of the cask and maintenance procedure was studied in order to design it in accordance with the last generic plug flange design. This includes a concept of a gripping system that uses the plug flange bolting area and, to help the remote handling process, a cantilever assisting system is suggested to increase the reliability of the transfer operation between vacuum vessel and cask.

Selected solutions and design features from the design of remotely handled filters and the technology of remote filter handling. Previous operating experience with these components in the PASSAT facility

International Nuclear Information System (INIS)

Jannakos, K.; Lange, W.; Potgeter, G.; Furrer, J.; Wilhelm, J.G.

1981-01-01

In a prototype filter offgas cleaning system for reprocessing plants (PASSAT) built at the Karlsruhe Nuclear Research Center a fullscale filter cell with remotely handled filters for aerosol and iodine removal and the corresponding remote handling systems for exchange, bagging out, packaging and disposal of spent filter elements has been installed and run in trial operation since July 1978. The filters and the replacement techniques have been tested for the past two years or so and so far have always worked satisfactory over the test period involving some 150 replacement events. Neither wear nor corrosion phenomena were found in the filter housings and the replacement systems. The seals and clamping devices were selected so that during operation the prescribed leak rates of -3 Torr l/s were always maintained on the filter lid, the seat of the filter element and the cell lock. The total clamping loads for the filter element and the filter lid amount to approx. 20 kN. The force necessary to separate the filter element from the filter housing is approx. 3.5 kN. No ruptures of seals or gaskets were to be detected. The design of the filters and of the handling systems has been found satisfactorily in the cold test operation so far and can be recommended for use in nuclear facilities. In all experiments conducted until now PASSAT has worked without any failure. All operating data required in the specifications were met in the test period. The maximum pressure loss in the system with loaded filter elements amounts to some 3000 mm of water. After operation with iodine and NO/sub x/, plant components exposed to 100% relative humidity and condensate showed corrosion

Asthma, guides for diagnostic and handling

International Nuclear Information System (INIS)

Salgado, Carlos E; Caballero A, Andres S; Garcia G, Elizabeth

1999-01-01

The paper defines the asthma, includes topics as diagnostic, handling of the asthma, special situations as asthma and pregnancy, handling of the asthmatic patient's perioperatory and occupational asthma

Photoprocesses of coordination compounds and dyes in solution ...

Indian Academy of Sciences (India)

design materials for visible light energy conversion.21c. The focus of this review is the ..... adsorbed onto the zeolite–Y as compared to that in the other nanoporous host mate- ..... recombine in dark to generate the reactants back in solution.

Remote-handled transuranic system assessment appendices. Volume 2

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-11-01

Volume 2 of this report contains six appendices to the report: Inventory and generation of remote-handled transuranic waste; Remote-handled transuranic waste site storage; Characterization of remote-handled transuranic waste; RH-TRU waste treatment alternatives system analysis; Packaging and transportation study; and Remote-handled transuranic waste disposal alternatives.

Remote-handled transuranic system assessment appendices. Volume 2

International Nuclear Information System (INIS)

1995-11-01

Volume 2 of this report contains six appendices to the report: Inventory and generation of remote-handled transuranic waste; Remote-handled transuranic waste site storage; Characterization of remote-handled transuranic waste; RH-TRU waste treatment alternatives system analysis; Packaging and transportation study; and Remote-handled transuranic waste disposal alternatives

Sterilization of solutions for parenterals products. Problem analysis

Directory of Open Access Journals (Sweden)

Yanelys Montes-González

2017-09-01

Full Text Available The solutions for the formulation of parenteral products must be sterile before the aseptic formulation process. For this reason, different methods of sterilization referred in the literature are analyzed. Thermodynamic criteria that rule the sterilization are presented. Furthermore, previous experiences in the sterilization of solutions for the formulation of parental products in an autoclave are analyzed, that take large time of processing and only low volumes of solution can be handled. Using jacketed stirred tanks for the sterilization may solve the problem and, therefore, criteria for the design of the later that allow to process high volumes of solution for the formulation of parenteral products are shown.

Progress in the conceptual design of the ITER cask and plug remote handling system

Energy Technology Data Exchange (ETDEWEB)

Locke, Darren, E-mail: darren.locke@f4e.europa.eu [Fusion for Energy Agency (F4E), Torres Diagonal Litoral B3, Josep Pla 2, 08019 Barcelona (Spain); González Gutiérrez, Carmen; Damiani, Carlo [Fusion for Energy Agency (F4E), Torres Diagonal Litoral B3, Josep Pla 2, 08019 Barcelona (Spain); Friconneau, Jean-Pierre; Martins, Jean-Pierre [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul Lez Durance (France)

2014-10-15

Highlights: • The CPRHS is a complex system with a significant number of complicated interfaces. • Significant effort is being made to ensure that the system requirements are clearly defined. • This solution relates to planned operations and also anticipation of rescue operations. • With the CPRHS performing a safety function process control is being put in place. • All these factors will have a significant impact on the success of the CPRHS. - Abstract: One function of the ITER remote maintenance system is the transportation of in-vessel components and remote handling systems to and from the vacuum vessel and docking stations in the Hot Cell via dedicated galleries and lift. The cask and plug remote handling system (CPRHS) has been adopted as the solution to provide this nuclear confinement and transportation. This paper discusses the development of the conceptual design to-date and presents the processes being implemented to effectively control the subsequent CPRHS development. The CPRHS is a complex suite of systems with a significant number of interfaces with other ITER systems. Significant effort is being made to ensure that the system requirements are comprehensively defined and carefully managed and a feasible solution is developed – including planned and rescue operations. With the CPRHS performing a critical confinement function appropriate processes are being put in place to control the system development of the CPRHS. The expectation is that the combination of these factors will have a significant impact on the successful implementation of the CPRHS.

Progress in the conceptual design of the ITER cask and plug remote handling system

International Nuclear Information System (INIS)

Locke, Darren; González Gutiérrez, Carmen; Damiani, Carlo; Friconneau, Jean-Pierre; Martins, Jean-Pierre

2014-01-01

Highlights: • The CPRHS is a complex system with a significant number of complicated interfaces. • Significant effort is being made to ensure that the system requirements are clearly defined. • This solution relates to planned operations and also anticipation of rescue operations. • With the CPRHS performing a safety function process control is being put in place. • All these factors will have a significant impact on the success of the CPRHS. - Abstract: One function of the ITER remote maintenance system is the transportation of in-vessel components and remote handling systems to and from the vacuum vessel and docking stations in the Hot Cell via dedicated galleries and lift. The cask and plug remote handling system (CPRHS) has been adopted as the solution to provide this nuclear confinement and transportation. This paper discusses the development of the conceptual design to-date and presents the processes being implemented to effectively control the subsequent CPRHS development. The CPRHS is a complex suite of systems with a significant number of interfaces with other ITER systems. Significant effort is being made to ensure that the system requirements are comprehensively defined and carefully managed and a feasible solution is developed – including planned and rescue operations. With the CPRHS performing a critical confinement function appropriate processes are being put in place to control the system development of the CPRHS. The expectation is that the combination of these factors will have a significant impact on the successful implementation of the CPRHS

Reduction of neptunium(V) and uranium(VI) in bicarbonate solutions by iron(II)

International Nuclear Information System (INIS)

Gogolev, A.V.; Zakharova, E.V.; Rodygina, N.I.; Fedoseev, A.M.; Shilov, V.P.

2006-01-01

Interaction of Np(VI) and Fe(II) compounds in bicarbonate solutions is investigated. Interaction of Np(V) with Fe(II) in the presence of phthalate-ions is studied briefly. Fe(II) compounds reduce Np(V) compounds in saturated with Ar or CO 2 solutions with any bicarbonate-ion concentrations. Chemical reaction kinetics is studied. Reduction of U(VI) by Fe(II) compounds takes place in the case of diluted bicarbonate solutions. UO 2 and FeOOH are products of reaction at raised temperatures [ru

Thermal expansion and thermal diffusivity properties of Co-Si solid solutions and intermetallic compounds

International Nuclear Information System (INIS)

Ruan, Ying; Li, Liuhui; Gu, Qianqian; Zhou, Kai; Yan, Na; Wei, Bingbo

2016-01-01

Highlights: • Length change difference between rapidly and slowly solidified Co-Si alloy occurs at high temperature. • Generally CTE increases with an increasing Si content. • The thermal diffusion abilities are CoSi 2 > Co 95 Si 5 > Co 90 Si 10 > Co 2 Si > CoSi if T exceeds 565 K. • All the CTE and thermal diffusivity variations with T satisfy linear or polynomial relations. - Abstract: The thermal expansion of Co-Si solid solutions and intermetallic compounds was measured via dilatometric method, compared with the results of first-principles calculations, and their thermal diffusivities were investigated using laser flash method. The length changes of rapidly solidified Co-Si alloys are larger than those of slowly solidified alloys when temperature increases to around 1000 K due to the more competitive atom motion. The coefficient of thermal expansion (α) of Co-Si alloy increases with an increasing Si content, except that the coefficient of thermal expansion of Co 95 Si 5 influenced by both metastable structure and allotropic transformation is lower than that of Co 90 Si 10 at a higher temperature. The thermal expansion abilities of Co-Si intermetallic compounds satisfy the relationship of Co 2 Si > CoSi > CoSi 2 , and the differences of the coefficients of thermal expansion between them increase with the rise of temperature. The thermal diffusivity of CoSi 2 is evidently larger than the values of other Co-Si alloys. If temperature exceeds 565 K, their thermal diffusion abilities are CoSi 2 > Co 95 Si 5 > Co 90 Si 10 > Co 2 Si > CoSi. All the coefficient of thermal expansion and thermal diffusivity variations with temperature satisfy linear or polynomial relations.

Too hot to handle? Analytic solutions for massive neutrino or warm dark matter cosmologies

Science.gov (United States)

Slepian, Zachary; Portillo, Stephen K. N.

2018-05-01

We obtain novel closed-form solutions to the Friedmann equation for cosmological models containing a component whose equation of state is that of radiation (w = 1/3) at early times and that of cold pressureless matter (w = 0) at late times. The equation of state smoothly transitions from the early to late-time behavior and exactly describes the evolution of a species with a Dirac Delta function distribution in momentum magnitudes |p_0| (i.e. all particles have the same |p_0|). Such a component, here termed "hot matter", is an approximate model for both neutrinos and warm dark matter. We consider it alone and in combination with cold matter and with radiation, also obtaining closed-form solutions for the growth of super-horizon perturbations in each case. The idealized model recovers t(a) to better than 1.5% accuracy for all a relative to a Fermi-Dirac distribution (as describes neutrinos). We conclude by adding the second moment of the distribution to our exact solution and then generalizing to include all moments of an arbitrary momentum distribution in a closed-form solution.

DDOS ATTACK DETECTION SIMULATION AND HANDLING MECHANISM

Directory of Open Access Journals (Sweden)

Ahmad Sanmorino

2013-11-01

Full Text Available In this study we discuss how to handle DDoS attack that coming from the attacker by using detection method and handling mechanism. Detection perform by comparing number of packets and number of flow. Whereas handling mechanism perform by limiting or drop the packets that detected as a DDoS attack. The study begins with simulation on real network, which aims to get the real traffic data. Then, dump traffic data obtained from the simulation used for detection method on our prototype system called DASHM (DDoS Attack Simulation and Handling Mechanism. From the result of experiment that has been conducted, the proposed method successfully detect DDoS attack and handle the incoming packet sent by attacker.

Solid phase extraction of hydroxyaromatic compounds from aquatic environment

Directory of Open Access Journals (Sweden)

P. T. Sukhanov

2012-01-01

Full Text Available The dependence of extraction parameters of hydroxyaromatic compounds on sort of polyurethane foam, nature and composition of solution deposited on a polymer foam, content of inorganic salt in solution.

Ergonomics of disposable handles for minimally invasive surgery.

Science.gov (United States)

Büchel, D; Mårvik, R; Hallabrin, B; Matern, U

2010-05-01

The ergonomic deficiencies of currently available minimally invasive surgery (MIS) instrument handles have been addressed in many studies. In this study, a new ergonomic pistol handle concept, realized as a prototype, and two disposable ring handles were investigated according to ergonomic properties set by new European standards. In this study, 25 volunteers performed four practical tasks to evaluate the ergonomics of the handles used in standard operating procedures (e.g., measuring a suture and cutting to length, precise maneuvering and targeting, and dissection of a gallbladder). Moreover, 20 participants underwent electromyography (EMG) tests to measure the muscle strain they experienced while carrying out the basic functions (grasp, rotate, and maneuver) in the x, y, and z axes. The data measured included the number of errors, the time required for task completion, perception of pressure areas, and EMG data. The values for usability in the test were effectiveness, efficiency, and user satisfaction. Surveys relating to the subjective rating were completed after each task for each of the three handles tested. Each handle except the new prototype caused pressure areas and pain. Extreme differences in muscle strain could not be observed for any of the three handles. Experienced surgeons worked more quickly with the prototype when measuring and cutting a suture (approximately 20%) and during precise maneuvering and targeting (approximately 20%). On the other hand, they completed the dissection task faster with the handle manufactured by Ethicon. Fewer errors were made with the prototype in dissection of the gallbladder. In contrast to the handles available on the market, the prototype was always rated as positive by the volunteers in the subjective surveys. None of the handles could fulfil all of the requirements with top scores. Each handle had its advantages and disadvantages. In contrast to the ring handles, the volunteers could fulfil most of the tasks more

A compound crack in a pipe under tension

International Nuclear Information System (INIS)

Zahoor, A.

1992-01-01

Limit load and J-resistance curve solutions are developed for a compound crack in a pipe subjected to axial tension. The solutions are based on thick-walled cylinder assumption and the J solution can be applied with load-displacement data from one pipe test. The J-R solution can be used to assess the effect of loading type on the material's resistance to crack extension when used with previously published solution for bending moment loading. (orig.)

A compound crack in a pipe under tension

Energy Technology Data Exchange (ETDEWEB)

Zahoor, A. (Zenith Corp., Rockville, MD (United States))

1992-03-01

Limit load and J-resistance curve solutions are developed for a compound crack in a pipe subjected to axial tension. The solutions are based on thick-walled cylinder assumption and the J solution can be applied with load-displacement data from one pipe test. The J-R solution can be used to assess the effect of loading type on the material's resistance to crack extension when used with previously published solution for bending moment loading. (orig.).

Radiological safety aspects of handling plutonium

International Nuclear Information System (INIS)

Sundararajan, A.R.

2016-01-01

Department of Atomic Energy in its scheme of harnessing the nuclear energy for electrical power generation and strategic applications has given a huge role to utilization of plutonium. In the power production programme, fast reactors with plutonium as fuel are expected to play a major role. This would require establishing fuel reprocessing plants to handle both thermal and fast reactor fuels. So in the nuclear fuel cycle facilities variety of chemical, metallurgical, mechanical operations have to be carried out involving significant inventories of "2"3"9 Pu and associated radionuclides. Plutonium is the most radiotoxic radionuclide and therefore any facility handling it has to be designed and operated with utmost care. Two problems of major concern in the protection of persons working in plutonium handling facilities are the internal exposure to the operating personnel from uptake of plutonium and transplutonic nuclides as they are highly radiotoxic and the radiation exposure of hands and eye lens during fuel fabrication operations especially while handling recycled high burn up plutonium. In view of the fact that annual limit for intake is very small for "2"3"9Pu and its radiation emission characteristics are such that it is a huge challenge for the health physicists to detect Pu in air and in workers. This paper discusses the principles and practices followed in providing radiological surveillance to workers in plutonium handling areas. The challenges in protecting the workers from receiving exposures to hands and eye lens in handling high burn up plutonium are also discussed. The sites having Pu fuel cycle facilities should have trained medical staff to handle cases involving excessive intake of plutonium. (author)

Enclosure for handling high activity materials

International Nuclear Information System (INIS)

Jimeno de Osso, F.

1977-01-01

One of the most important problems that are met at the laboratories producing and handling radioisotopes is that of designing, building and operating enclosures suitable for the safe handling of active substances. With this purpose in mind, an enclosure has been designed and built for handling moderately high activities under a shielding made of 150 mm thick lead. In this report a description is given of those aspects that may be of interest to people working in this field. (Author)

Enclosure for handling high activity materials

Energy Technology Data Exchange (ETDEWEB)

Jimeno de Osso, F

1977-07-01

One of the most important problems that are met at the laboratories producing and handling radioisotopes is that of designing, building and operating enclosures suitable for the safe handling of active substances. With this purpose in mind, an enclosure has been designed and built for handling moderately high activities under a shielding made of 150 mm thick lead. In this report a description is given of those aspects that may be of interest to people working in this field. (Author)

Computing and data handling requirements for SSC [Superconducting Super Collider] and LHC [Large Hadron Collider] experiments

International Nuclear Information System (INIS)

Lankford, A.J.

1990-05-01

A number of issues for computing and data handling in the online in environment at future high-luminosity, high-energy colliders, such as the Superconducting Super Collider (SSC) and Large Hadron Collider (LHC), are outlined. Requirements for trigger processing, data acquisition, and online processing are discussed. Some aspects of possible solutions are sketched. 6 refs., 3 figs

Allergic contact dermatitis due to highly reactive halogenated compounds

Energy Technology Data Exchange (ETDEWEB)

Pickering, F C; Ive, F A

1983-11-01

Ten cases of dermatitis in a fine organic chemicals plant are reported. These cases were all due to exposure to chemical compounds with reactive bromine or chlorine atoms. This type of chemical is always extremely irritant, but evidence is put forward to suggest that these cases were the result of allergic sensitization. Chemicals with reactive halogen atoms should always be handled with extreme care and patch testing should be approached with caution.

Specialization and Flexibility in Port Cargo Handling

Directory of Open Access Journals (Sweden)

Hakkı KİŞİ

2016-11-01

Full Text Available Cargo handling appears to be the fundamental function of ports. In this context, the question of type of equipment and capacity rate need to be tackled with respect to cargo handling principles. The purpose of this study is to discuss the types of equipment to be used in ports, relating the matter to costs and capacity. The question is studied with a basic economic theoretical approach. Various conditions like port location, size, resources, cargo traffic, ships, etc. are given parameters to dictate the type and specification of the cargo handling equipment. Besides, a simple approach in the context of cost capacity relation can be useful in deciding whether to use specialized or flexible equipment. Port equipment is sometimes expected to be flexible to handle various types of cargo as many as possible and sometimes to be specialized to handle one specific type of cargo. The cases that might be suitable for those alternatives are discussed from an economic point of view in this article. Consequently, effectiveness and efficiency criteria play important roles in determining the handling equipment in ports.

Indium flotation from hydrometallurgical solutions

International Nuclear Information System (INIS)

Sviridov, V.V.; Mal'tsev, G.I.; Petryakova, N.K.; Gomzikov, A.I.

1980-01-01

The principal possibility of flotation of indium small quantities (10 -4 gxion/l) is established from sulphuric-acid solutions of leaching converter dusts of the copper melting production in the form of complex compounds with sodium hexametaphosphate and cation-active nitrogen-containing surfactants. It is shown that the flotation process effectiveness is determined by the molar ratio of hexametaphosphate and collector introduced into the solution, solution oxidity and surfactant nature

HMSRP Hawaiian Monk Seal Handling Data

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This data set contains records for all handling and measurement of Hawaiian monk seals since 1981. Live seals are handled and measured during a variety of events...

Inorganic, coordination and organometallic compounds

International Nuclear Information System (INIS)

Jursik, F.

1978-01-01

Separation of cations and anions of inorganic, coordination and metalloorganic compounds by the method of liquid column chromatography is considered. Common scheme of multicomponent cation mixture is suggesteed. Separation conditions, adsrbents, eluents, pH value solution concenstration, elution rate are also suggested. Separation of rare earth elements Cs, Be, Cd, Te, Th, U, Mo, Re, V, Ru, Zr, In compounds is considered as an example of liquid column chromatography application. Data on column chromatography application are summarized in a table

Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds with Hypervalent Iodine Reagents.

Science.gov (United States)

Hari, Durga Prasad; Waser, Jerome

2016-02-24

Alkynes have found widespread applications in synthetic chemistry, biology, and materials sciences. In recent years, methods based on electrophilic alkynylation with hypervalent iodine reagents have made acetylene synthesis more flexible and efficient, but they lead to the formation of one equivalent of an iodoarene as side-product. Herein, a more efficient strategy involving a copper-catalyzed oxy-alkynylation of diazo compounds with ethynylbenziodoxol(on)e (EBX) reagents is described, which proceeds with generation of nitrogen gas as the only waste. This reaction is remarkable for its broad scope in both EBX reagents and diazo compounds. In addition, vinyl diazo compounds gave enynes selectively as single geometric isomers. The functional groups introduced during the transformation served as easy handles to access useful building blocks for synthetic and medicinal chemistry.

Work-related musculoskeletal risks associated with nurses and nursing assistants handling overweight and obese patients: A literature review.

Science.gov (United States)

Choi, Sang D; Brings, Kathryn

2015-01-01

Nurses and nursing assistants are susceptible to work-related musculoskeletal disorders and injuries (WMSDs) due to the increase in overweight and obese patients they are handling on a daily basis. This study aimed to review work-related musculoskeletal hazards and risks associated with handling overweight and obese patients, and summarize the recommended interventions to mitigate musculoskeletal concerns among nurses and nursing assistants. Approximately 350 publications were initially screened and 22 refereed articles were used to synthesize for this study on the bases of inclusion/exclusion relevance and strength of evidence on overweight or obese patient handling. Evidence suggested that the work-related musculoskeletal risks among nurses and nursing assistants included sprains/strains, low back pain, wrist, knee and shoulder injuries. The findings indicated that the WMSD risks increased when nurses and nursing assistants were manually moving or lifting patients, especially when the patients were overweight or obese. The recommended solutions included the lifting/transfer equipment and devices, ergonomic assessments and controls, no-lift policies, and training and education. To alleviate the risk of musculoskeletal disorders and injuries among nurses and nursing assistants handling overweight or obese patients, additional research and development into what safe patient handling interventions suit this growing population needs to be addressed.

Risk assessment related to manual handling on choosen work possition in foundry Alstom Power Sp. z o. o.

Directory of Open Access Journals (Sweden)

G. Kowal

2010-04-01

Full Text Available Manual handling remains one of the different types of transport inside working place, although technological progress and modernorganization of work. Manual transport as a transport inside working place is related to foundry industry. According to polish lawregulations employer has to give consideration to manual handling in professional risk assessment and introduce actions for manualhandling reduction. In Foundry Elblag case there is found that in many processes manual handling are made by workers. For example wecan choose melting processes (additives manual feeding, mixing and pulling metallurgical slag, etc. or fettling processes like grinding.Objective of that analysis was to define level of risk related to manual handling in work stand chosen and define activities impacted onrisk assessment result with biggest range. For risk reduction, technical and organizational solutions were shown (better ergonomically work stand, method of work and worker’s awareness about good practices. In this study methods related to manual handling risk assessment were described, focus on KIM method used in Foundry Elblag. Key Item Method allow to estimate the risk by simple calculation based on key indicators (time rating points, rating points of mass, posture or work condition. Points were chosen based on timekeeping, information from workers and foreman.

Preparation and properties of organo(acetylacetonato)antimony(V) compounds

NARCIS (Netherlands)

Meinema, H.A.; Noltes, J.G.

Organo(acetylacetonato)antimony(V) compounds of the types R2SbCl2Acac, R4SbAcac, PhSbCl3Acac and Cl4SbAcac have been synthesized. The compounds are monomeric in solution. IR and PMR data of these compounds, which contain a chelated Acac ligand have been discussed. Ph2SbCl2Acac shows abnormal

Management of transport and handling contracts

CERN Document Server

Rühl, I

2004-01-01

This paper shall outline the content, application and management strategies for the various contracts related to transport and handling activities. In total, the two sections Logistics and Handling Maintenance are in charge of 27 (!) contracts ranging from small supply contracts to big industrial support contracts. The activities as well as the contracts can generally be divided into four main topics "Vehicle Fleet Management"; "Supply, Installation and Commissioning of Lifting and Hoisting Equipment"; "Equipment Maintenance" and "Industrial Support for Transport and Handling". Each activity and contract requires different approaches and permanent adaptation to the often changing CERN's requirements. In particular, the management and the difficulties experienced with the contracts E072 "Maintenance of lifting and hoisting equipment", F420 "Supply of seven overhead traveling cranes for LHC" and S090/S103 "Industrial support for transport and handling" will be explained in detail.

KNOWLEDGE-BASED ROBOT VISION SYSTEM FOR AUTOMATED PART HANDLING

Directory of Open Access Journals (Sweden)

J. Wang

2012-01-01

Full Text Available

ENGLISH ABSTRACT: This paper discusses an algorithm incorporating a knowledge-based vision system into an industrial robot system for handling parts intelligently. A continuous fuzzy controller was employed to extract boundary information in a computationally efficient way. The developed algorithm for on-line part recognition using fuzzy logic is shown to be an effective solution to extract the geometric features of objects. The proposed edge vector representation method provides enough geometric information and facilitates the object geometric reconstruction for gripping planning. Furthermore, a part-handling model was created by extracting the grasp features from the geometric features.

AFRIKAANSE OPSOMMING: Hierdie artikel beskryf ‘n kennis-gebaseerde visiesisteemalgoritme wat in ’n industriёle robotsisteem ingesluit word om sodoende intelligente komponenthantering te bewerkstellig. ’n Kontinue wasige beheerder is gebruik om allerlei objekinligting deur middel van ’n effektiewe berekeningsmetode te bepaal. Die ontwikkelde algoritme vir aan-lyn komponentherkenning maak gebruik van wasige logika en word bewys as ’n effektiewe metode om geometriese inligting van objekte te bepaal. Die voorgestelde grensvektormetode verskaf voldoende inligting en maak geometriese rekonstruksie van die objek moontlik om greepbeplanning te kan doen. Voorts is ’n komponenthanteringsmodel ontwikkel deur die grypkenmerke af te lei uit die geometriese eienskappe.

Design safety features of containments used for handling plutonium in Reprocessing Plants

International Nuclear Information System (INIS)

Aherwal, P.; Achuthan, P.V.

2016-01-01

The plutonium present in spent fuel is separated from the associated uranium and fission products using solvent extraction cycles in process cells. Product plutonium nitrate solution containing trace concentrations of uranium and fission products is treated in the reconversion facility through a precipitation-calcination route and converted to sinterable grade plutonium oxide (PuO 2 ). All chemical operations involving materials with high plutonium content, both in solid and solution forms are carried out in glove boxes. Glove box provides an effective isolation from radioactive materials handled and acts as a barrier between the operator and the source of radiation. These glove boxes are interconnected for sequential operations and the interconnected glove box trains are installed within secondary enclosures called double skin which provides double barrier protection to operators

Ergonomics: safe patient handling and mobility.

Science.gov (United States)

Hallmark, Beth; Mechan, Patricia; Shores, Lynne

2015-03-01

This article reviews and investigates the issues surrounding ergonomics, with a specific focus on safe patient handling and mobility. The health care worker of today faces many challenges, one of which is related to the safety of patients. Safe patient handling and mobility is on the forefront of the movement to improve patient safety. This article reviews the risks associated with patient handling and mobility, and informs the reader of current evidence-based practice relevant to this area of care. Copyright © 2015 Elsevier Inc. All rights reserved.

Remote handling equipment

International Nuclear Information System (INIS)

Clement, G.

1984-01-01

After a definition of intervention, problems encountered for working in an adverse environment are briefly analyzed for development of various remote handling equipments. Some examples of existing equipments are given [fr

Welding method by remote handling

International Nuclear Information System (INIS)

Hashinokuchi, Minoru.

1994-01-01

Water is charged into a pit (or a water reservoir) and an article to be welded is placed on a support in the pit by remote handling. A steel plate is disposed so as to cover the article to be welded by remote handling. The welding device is positioned to the portion to be welded and fixed in a state where the article to be welded is shielded from radiation by water and the steel plate. Water in the pit is drained till the portion to be welded is exposed to the atmosphere. Then, welding is conducted. After completion of the welding, water is charged again to the pit and the welding device and fixing jigs are decomposed in a state where the article to be welded is shielded again from radiation by water and the steel plate. Subsequently, the steel plate is removed by remote handling. Then, the article to be welded is returned from the pit to a temporary placing pool by remote handling. This can reduce operator's exposure. Further, since the amount of the shielding materials can be minimized, the amount of radioactive wastes can be decreased. (I.N.)

Oseltamivir compounding in the hospital pharmacy during the (H1N1 influenza pandemic

Directory of Open Access Journals (Sweden)

Márcia Lúcia de Mário Marin

2010-01-01

Full Text Available AIMS: Pandemics impose large demands on the health care system. The supply of appropriate chemotherapeutic agents, namely oseltamivir solution, presented a serious challenge in the recent influenza pandemic. This study reports on the rational series of pharmacotechnical steps that were followed to appropriately handle bulk oseltamivir powder to meet the increased demand. METHODS: During a six-week period in August and September of 2009, a task force was created in the Central Pharmacy of Hospital das Clínicas to convert imported oseltamivir phosphate into ready-to-use solution for utilization by physicians and public health authorities. The protocol included dissolution, physico-chemical tests and the bottling of a liquid microdose formulation for emergency room and outpatient dispensing with adequate quality control during all phases. RESULTS: The successful production routine was based on a specially designed flowchart according to which a batch of 33210 g of oseltamivir powder was converted into 32175 solution units during the aforementioned period with a net loss of only 2.6%. The end products were bottles containing 50 ml of 15 mg/mL oseltamivir solution. The measured concentration was stable and accurate (97.5% - 102.0% of the nominal value. The drug was prescribed as both a prophylactic and therapeutic agent. DISCUSSION: Hospital pharmacies are conventionally engaged in the manipulation of medical prescriptions and specialty drugs. They are generally responsible for only small-scale equipment used for manufacturing and quality-control procedures. The compounding of oseltamivir was a unique effort dictated by exceptional circumstances. CONCLUSION: The shortage of oseltamivir solution for clinical use was solved by emergency operationalization of a semi-industrial process in which bulk powder was converted into practical vials for prompt delivery.

Precipitation of organic arsenic compounds and their degradation products during struvite formation

Energy Technology Data Exchange (ETDEWEB)

Lin, Jin-Biao; Yuan, Shoujun [School of Civil Engineering, Hefei University of Technology, Hefei 230009 (China); Institute of Water Treatment and Wastes Reutilization, Hefei University of Technology, Hefei 230009 (China); Wang, Wei, E-mail: dwhit@126.com [School of Civil Engineering, Hefei University of Technology, Hefei 230009 (China); Institute of Water Treatment and Wastes Reutilization, Hefei University of Technology, Hefei 230009 (China); Hu, Zhen-Hu, E-mail: zhhu@hfut.edu.cn [School of Civil Engineering, Hefei University of Technology, Hefei 230009 (China); Institute of Water Treatment and Wastes Reutilization, Hefei University of Technology, Hefei 230009 (China); Yu, Han-Qing [Department of Chemistry, University of Science & Technology of China, Hefei 230026 (China)

2016-11-05

Highlights: • Organic and inorganic arsenic compounds precipitated during struvite formation. • Precipitation of organic arsenic compounds in struvite decreased with increasing pH. • Arsenate easily precipitate in struvite as compared to organic arsenic compounds. • Arsenic compounds in solution affected the shape of struvite crystallization products. - Abstract: Roxarsone (ROX) and arsanilic acid (ASA) have been extensively used as organoarsenic animal feed additives. Organic arsenic compounds and their degradation products, arsenate (As(V)) and arsenite (As(III)), exist in the effluent from anaerobic reactors treating animal manure contaminated by ROX or ASA with ammonium (NH{sub 4}{sup +}-N) and phosphate (PO{sub 4}{sup 3−}-P) together. Therefore, arsenic species in the effluent might be involved in the struvite formation process. In this study, the involvement of organic arsenic compounds and their degradation products As(V) and As(III) in the struvite crystallization was investigated. The results demonstrated that arsenic compounds did not substantially affect the PO{sub 4}{sup 3−}-P recovery, but confirmed the precipitation of arsenic during struvite formation. The precipitation of arsenic compounds in struvite was considerably affected by a solution pH from 9.0 to 11.0. With an increase in pH, the content of ASA and ROX in the precipitation decreased, but the contents of As(III) and As(V) increased. In addition, the arsenic content of As(V) in the struvite was higher than that of As(III), ASA and ROX. The results indicated that the struvite could be contaminated when the solution contains arsenic species, but that could be minimized by controlling the solution pH and maintaining anaerobic conditions during struvite formation.

Handling equipment Selection in open pit mines by using an integrated model based on group decision making

Directory of Open Access Journals (Sweden)

Abdolreza Yazdani-Chamzini

2012-10-01

Full Text Available Process of handling equipment selection is one of the most important and basic parts in the project planning, particularly mining projects due to holding a high charge of the total project's cost. Different criteria impact on the handling equipment selection, while these criteria often are in conflicting with each other. Therefore, the process of handling equipment selection is a complex and multi criteria decision making problem. There are a variety of methods for selecting the most appropriate equipment among a set of alternatives. Likewise, according to the sophisticated structure of the problem, imprecise data, less of information, and inherent uncertainty, the usage of the fuzzy sets can be useful. In this study a new integrated model based on fuzzy analytic hierarchy process (FAHP and fuzzy technique for order preference by similarity to ideal solution (FTOPSIS is proposed, which uses group decision making to reduce individual errors. In order to calculate the weights of the evaluation criteria, FAHP is utilized in the process of handling equipment selection, and then these weights are inserted to the FTOPSIS computations to select the most appropriate handling system among a pool of alternatives. The results of this study demonstrate the potential application and effectiveness of the proposed model, which can be applied to different types of sophisticated problems in real problems.

Actinide-handling experience for training and education of future expert under J-ACTINET

International Nuclear Information System (INIS)

Osaka, Masahiko; Sato, Isamu; Miwa, Shuhei; Konashi, Kenji; Li, Dexin; Homma, Yoshiya; Yamamura, Tomoo; Hayashi, Hirokazu; Minato, Kazuo; Sekimoto, Syun; Kubota, Takumi; Fukutani, Satoshi; Hori, Junichi; Okumura, Ryo; Uehara, Akihiro; Fujii, Toshiyuki; Yamana, Hajimu; Kurosaki, Ken; Muta, Hiroaki; Ohishi, Yuji; Yamanaka, Shinsuke; Uno, Masayoshi; Yaita, Tsuyoshi

2011-01-01

Summer schools for future experts have successfully been completed under Japan Actinide Network (J-ACTINET) for the purpose of development of human resources who are expected to be engaged in every areas of actinide-research/engineering. The first summer school was held in Ibaraki-area in August 2009, followed by the second one in Kansai-area in August 2010. Two summer schools have focused on actual experiences of actinides in actinide-research fields for university students and young researchers/engineers as an introductory course of actinide-researches. Many efforts were made to awaken interests into actinide-researches inside the participants during short periods of schools, 3 to 4 days. As actinides must be handled inside special apparatuses such as an air-tight globe-box with well-trained and qualified technicians, programs were optimized for effective experiences of actinides-handling. Several quasi actinide-handling experiences at the actinide-research fields have attracted attentions of participants at the first school in Ibaraki-area. The actual experiments using actinides-containing solutions have been carried out at the second school in Kansai-area. Future summer schools will be held every year for the sustainable human resource development in various actinide-research fields, together with other training and education programs conducted by the J-ACTINET. (author)

Civilsamfundets ABC: H for Handling

DEFF Research Database (Denmark)

Lund, Anker Brink; Meyer, Gitte

2015-01-01

Hvad er civilsamfundet? Anker Brink Lund og Gitte Meyer fra CBS Center for Civil Society Studies gennemgår civilsamfundet bogstav for bogstav. Vi er nået til H for Handling.......Hvad er civilsamfundet? Anker Brink Lund og Gitte Meyer fra CBS Center for Civil Society Studies gennemgår civilsamfundet bogstav for bogstav. Vi er nået til H for Handling....

The technique on handling radiation

International Nuclear Information System (INIS)

1997-11-01

This book describes measurement of radiation and handling radiation. The first part deals with measurement of radiation. The contents of this part are characteristic on measurement technique of radiation, radiation detector, measurement of energy spectrum, measurement of radioactivity, measurement for a level of radiation and county's statistics on radiation. The second parts explains handling radiation with treating of sealed radioisotope, treating unsealed source and radiation shield.

Uranium hexafluoride handling

International Nuclear Information System (INIS)

1991-01-01

The United States Department of Energy, Oak Ridge Field Office, and Martin Marietta Energy Systems, Inc., are co-sponsoring this Second International Conference on Uranium Hexafluoride Handling. The conference is offered as a forum for the exchange of information and concepts regarding the technical and regulatory issues and the safety aspects which relate to the handling of uranium hexafluoride. Through the papers presented here, we attempt not only to share technological advances and lessons learned, but also to demonstrate that we are concerned about the health and safety of our workers and the public, and are good stewards of the environment in which we all work and live. These proceedings are a compilation of the work of many experts in that phase of world-wide industry which comprises the nuclear fuel cycle. Their experience spans the entire range over which uranium hexafluoride is involved in the fuel cycle, from the production of UF 6 from the naturally-occurring oxide to its re-conversion to oxide for reactor fuels. The papers furnish insights into the chemical, physical, and nuclear properties of uranium hexafluoride as they influence its transport, storage, and the design and operation of plant-scale facilities for production, processing, and conversion to oxide. The papers demonstrate, in an industry often cited for its excellent safety record, continuing efforts to further improve safety in all areas of handling uranium hexafluoride

Beginning SharePoint 2013 building business solutions

CERN Document Server

Perran, Amanda; Mason, Jennifer; Rogers, Laura

2013-01-01

Learn to build business solutions with SharePoint 2013 Now in its third edition, this perennial bestseller features a complete overhaul for the latest version of SharePoint. A must-have for building business solutions in SharePoint, real-world scenarios address critical information management problems and detailed descriptions explain how to efficiently and successfully handle these challenges. Plus, best practices for configuration and customization round out the coverage of getting started with SharePoint 2013 so that you can confidently make this platform work for your business

Determination of the solubility of Np(IV), Pu(III) - (VI),Am(III) - (VI), and Te(IV), (V) hydroxo compounds in 0.5 - 14 M NaOH solutions

Energy Technology Data Exchange (ETDEWEB)

Delegard, C.H.

1996-09-24

The solubilities of Am(III), Np(IV), Pu(IV), Tc(IV), Np(V), Pu(V), Am(V), and Tc(V) hydroxo compounds were studied in 0.5 to 14 M NaOH solutions at 25{+-}2 {degrees}C. The effects of fluoride, phosphate, carbonate, oxalate, and some other organic complexing agents on the solubilities of Np(IV), Pu(IV), and TC(IV) hydroxides were investigated at 1.0 and 4.0 M NAOH. Some predictions were made on the dissolved (I.V) and (V) species present in alkali solutions.

Exact Solutions to a Combined sinh-cosh-Gordon Equation

International Nuclear Information System (INIS)

Wei Long

2010-01-01

Based on a transformed Painleve property and the variable separated ODE method, a function transformation method is proposed to search for exact solutions of some partial differential equations (PDEs) with hyperbolic or exponential functions. This approach provides a more systematical and convenient handling of the solution process of this kind of nonlinear equations. Its key point is to eradicate the hyperbolic or exponential terms by a transformed Painleve property and reduce the given PDEs to a variable-coefficient ordinary differential equations, then we seek for solutions to the resulting equations by some methods. As an application, exact solutions for the combined sinh-cosh-Gordon equation are formally derived. (general)

The remote handling compatibility analysis of the ITER generic upper port plug structure

Energy Technology Data Exchange (ETDEWEB)

Ronden, D.M.S., E-mail: d.m.s.ronden@differ.nl [FOM Institute DIFFER, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Dammann, A. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul-lez-Durance (France); Elzendoorn, B. [FOM Institute DIFFER, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Giacomin, T. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul-lez-Durance (France); Heemskerk, C. [Heemskerk Innovative Technology, Merelhof 2, 2172 HZ Sassenheim (Netherlands); Loesser, D. [Princeton Plasma Physics Laboratory, Princeton, NJ 08543-0451 (United States); Maquet, P. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul-lez-Durance (France); Oosterhout, J. van [FOM Institute DIFFER, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Pak, S.; Pitcher, C.S.; Portales, M.; Proust, M.; Udintsev, V.S.; Walsh, M.J. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul-lez-Durance (France)

2014-10-15

Highlights: • We describe the remote handling compatibility of the ITER generic upper port plug. • Concepts are presented of specific design solutions to improve RH compatibility. • Simulation in VR of the GUPP DSM replacement indicates possible collisions. • Specific tooling concepts are proposed for GUPP handling equipment for the hot cell. - Abstract: The ITER diagnostics generic upper port plug (GUPP) is developed as a standardized design for all diagnostic upper port plugs, in which a variety of payloads can be mounted. Here, the remote handling compatibility analysis (RHCA) of the GUPP design is presented that was performed for the GUPP final design review. The analysis focuses mainly on the insertion and extraction procedure of the diagnostic shield module (DSM), a removable cassette that contains the diagnostic in-vessel components. It is foreseen that the DSM is a replaceable component – the procedure of which is to be performed inside the ITER hot cell facility (HCF), where the GUPP can be oriented in a vertical position. The DSM removal procedure in the HCF consists of removing locking pins, an M30 sized shoulder bolt and two electrical straps through the use of a dexterous manipulator, after which the DSM is lifted out of the GUPP by an overhead crane. For optimum access to its internals, the DSM is mounted in a handling device. The insertion of a new or refurbished DSM follows the reverse procedure. The RHCA shows that the GUPP design requires a moderate amount of changes to become fully compatible with RH maintenance requirements.

The remote handling compatibility analysis of the ITER generic upper port plug structure

International Nuclear Information System (INIS)

Ronden, D.M.S.; Dammann, A.; Elzendoorn, B.; Giacomin, T.; Heemskerk, C.; Loesser, D.; Maquet, P.; Oosterhout, J. van; Pak, S.; Pitcher, C.S.; Portales, M.; Proust, M.; Udintsev, V.S.; Walsh, M.J.

2014-01-01

Highlights: • We describe the remote handling compatibility of the ITER generic upper port plug. • Concepts are presented of specific design solutions to improve RH compatibility. • Simulation in VR of the GUPP DSM replacement indicates possible collisions. • Specific tooling concepts are proposed for GUPP handling equipment for the hot cell. - Abstract: The ITER diagnostics generic upper port plug (GUPP) is developed as a standardized design for all diagnostic upper port plugs, in which a variety of payloads can be mounted. Here, the remote handling compatibility analysis (RHCA) of the GUPP design is presented that was performed for the GUPP final design review. The analysis focuses mainly on the insertion and extraction procedure of the diagnostic shield module (DSM), a removable cassette that contains the diagnostic in-vessel components. It is foreseen that the DSM is a replaceable component – the procedure of which is to be performed inside the ITER hot cell facility (HCF), where the GUPP can be oriented in a vertical position. The DSM removal procedure in the HCF consists of removing locking pins, an M30 sized shoulder bolt and two electrical straps through the use of a dexterous manipulator, after which the DSM is lifted out of the GUPP by an overhead crane. For optimum access to its internals, the DSM is mounted in a handling device. The insertion of a new or refurbished DSM follows the reverse procedure. The RHCA shows that the GUPP design requires a moderate amount of changes to become fully compatible with RH maintenance requirements

Handling Pyrophoric Reagents

Energy Technology Data Exchange (ETDEWEB)

Alnajjar, Mikhail S.; Haynie, Todd O.

2009-08-14

Pyrophoric reagents are extremely hazardous. Special handling techniques are required to prevent contact with air and the resulting fire. This document provides several methods for working with pyrophoric reagents outside of an inert atmosphere.

An improved technique for oral administration of solutions of test ...

African Journals Online (AJOL)

Medicut intravenous cannula as an improvised oral cannula to administer solutions of drugs and test substances to experimental rats. Techniques of handling and manipulating the rat with the goal of having the eosophagus as straight as possible ...

Corrosion evaluation of uranyl nitrate solution evaporator and denitrator in Tokai reprocessing plant

International Nuclear Information System (INIS)

Yamanaka, Atsushi; Hashimoto, Kowa; Uchida, Toyomi; Shirato, Yoji; Isozaki, Toshihiko; Nakamura, Yoshinobu

2011-01-01

The Tokai reprocessing plant (TRP) adopted the PUREX method in 1977 and has reprocessed spent nuclear fuel of 1140 tHM (tons of heavy metals) since then. The reprocessing equipment suffers from various corrosion phenomena because of high nitric acidity, solution ion concentrations, such as uranium, plutonium, and fission products, and temperature. Therefore, considering corrosion performance in such a severe environment, stainless steels, titanium steel, and so forth were employed as corrosion resistant materials. The severity of the corrosive environment depends on the nitric acid concentration and the temperature of the solution, and uranium in the solution reportedly does not significantly affect the corrosion of stainless steels and controls the corrosion rates of titanium steel. The TRP equipment that handles uranyl nitrate solution operates at a low nitric acid concentration and has not experienced corrosion problems until now. However, there is a report that corrosion rates of some stainless steels increase in proportion to rising uranium concentrations. The equipment that handles the uranyl nitrate solution in the TRP includes the evaporators, which concentrate uranyl nitrate to a maximum concentration of about 1000 gU/L (grams of uranium per liter), and the denitrator, where uranyl nitrate is converted to UO 3 powder at about 320degC. These equipments are therefore required to grasp the degree of the progress of corrosion to handle high-temperature and high-concentration uranyl nitrate. The evaluation of this equipment on the basis of thickness measurement confirmed only minor corrosion and indicated that the equipment would be fully adequate for future operation. (author)

ATA diagnostic data handling system: an overview

International Nuclear Information System (INIS)

Chambers, F.W.; Kallman, J.; McDonald, J.; Slominski, M.

1984-01-01

The functions to be performed by the ATA diagnostic data handling system are discussed. The capabilities of the present data acquisition system (System 0) are presented. The goals for the next generation acquisition system (System 1), currently under design, are discussed. Facilities on the Octopus system for data handling are reviewed. Finally, we discuss what has been learned about diagnostics and computer based data handling during the past year

Automation of 3D micro object handling process

DEFF Research Database (Denmark)

Gegeckaite, Asta; Hansen, Hans Nørgaard

2007-01-01

Most of the micro objects in industrial production are handled with manual labour or in semiautomatic stations. Manual labour usually makes handling and assembly operations highly flexible, but slow, relatively imprecise and expensive. Handling of 3D micro objects poses special challenges due to ...

Compound forming extractants, solvating solvents and inert solvents IUPAC chemical data series

CERN Document Server

Marcus, Y; Kertes, A S

2013-01-01

Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part III: Compound Forming Extractants, Solvating Solvents, and Inert Solvents focuses on the compilation of equilibrium constants of various compounds, such as acids, ions, salts, and aqueous solutions. The manuscript presents tables that show the distribution reactions of carboxylic and sulfonic acid extractants and their dimerization and other reactions in the organic phase and extraction reactions of metal ions from aqueous solutions. The book also states that the inorganic anions in these solutions are irrelevant, since they d

Process for recovering tungsten from alkaline leaching solution of tungsten ores

International Nuclear Information System (INIS)

Onozaki, S.; Nemoto, S.; Hazeyama, T.

1976-01-01

This invention relates to a process for recovering tungsten from an alkaline leaching solution of tungsten ores. This invention comprises adjusting the pH of an alkaline leaching solution which is obtained by lixiviating ore containing tungsten with an alkaline solution to 7--8 with acid to oxidize molybdic acid ions in the solution, adding a sulfide donor, then precipitating molybdenum sulfide compounds by adjusting the pH value of the solution to 2--3. Tungstic acid ions are recovered as calcium tungstate by the addition of a calcium ion donor after the molybdenum sulfide compounds are separated

Plans and equipment for criticality measurements on plutonium-uranium nitrate solutions

International Nuclear Information System (INIS)

Lloyd, R.C.; Clayton, E.D.; Durst, B.M.

1982-01-01

Data from critical experiments are required on the criticality of plutonium-uranium nitrate solutions to accurately establish criticality control limits for use in processing and handling of breeder type fuels. Since the fuel must be processed both safely and economically, it is necessary that criticality considerations be based on accurate experimental data. Previous experiments have been reported on plutonium-uranium solutions with Pu weight ratios extending up to some 38 wt %. No data have been presented, however, for plutonium-uranium nitrate solutions beyond this Pu weight ratio. The current research emphasis is on the procurement of criticality data for plutonium-uranium mixtures up to 60 wt % Pu that will serve as the basis for handling criticality problems subsequently encountered in the development of technology for the breeder community. Such data also will provide necessary benchmarks for data testing and analysis on integral criticality experiments for verification of the analytical techniques used in support of criticality control. Experiments are currently being performed with plutonium-uranium nitrate solutions in stainless steel cylindrical vessels and an expandable slab tank system. A schematic of the experimental systems is presented

Sequence trajectory generation for garment handling systems

OpenAIRE

Liu, Honghai; Lin, Hua

2008-01-01

This paper presents a novel generic approach to the planning strategy of garment handling systems. An assumption is proposed to separate the components of such systems into a component for intelligent gripper techniques and a component for handling planning strategies. Researchers can concentrate on one of the two components first, then merge the two problems together. An algorithm is addressed to generate the trajectory position and a clothes handling sequence of clothes partitions, which ar...

Enhanced wood fuel handling: market and design studies

Energy Technology Data Exchange (ETDEWEB)

Landen, R.; Rippengal, R.; Redman, A.N.

1997-09-01

This report examines the potential for the manufacture and sale of novel wood fuel handling systems as a means of addressing users' concerns regarding current capital costs and potential high labour costs of non-automated systems. The report considers fuel handling technology that is basically appropriate for wood-fired heating systems of between c.100kW and c.1MW maximum continuous rating. This report details work done by the project collaborators in order to: (1) assess the current status of wood fuel handling technology; (2) evaluate the market appetite for improved wood fuel handling technology; (3) derive capital costs which are acceptable to customers; (4) review design options; and (5) select one or more design options worthy of further development. The current status of wood fuel handling technology is determined, and some basic modelling to give guidance on acceptable capital costs of 100-1000kW wood fuel handling systems is undertaken. (author)

Review of pulmonary toxicity of indium compounds to animals and humans

International Nuclear Information System (INIS)

Tanaka, Akiyo; Hirata, Miyuki; Kiyohara, Yutaka; Nakano, Makiko; Omae, Kazuyuki; Shiratani, Masaharu; Koga, Kazunori

2010-01-01

Due to the increased production of ITO, the potential health hazards arising from occupational exposure to this material have attracted much attention. This review consists of three parts: 1) toxic effects of indium compounds on animals, 2) toxic effects of indium compounds on humans, and 3) recommendations for preventing exposure to indium compounds in the workplace. Available data have indicated that insoluble form of indium compounds, such as ITO, indium arsenide (InAs) and indium phosphide (InP), can be toxic to animals. Furthermore, InP has demonstrated clear evidence of carcinogenic potential in long-term inhalation studies using experimental animals. As for the dangers to humans, some data are available concerning adverse health effects to workers who have been exposed to indium-containing particles. The Japan Society for Occupational Health recommended the value of 3 μg/L of indium in serum as the occupational exposure limit based on biological monitoring to preventing adverse health effects in workers resulting from occupational exposure to indium compounds. Accordingly, it is essential that much greater attention is focused on human exposure to indium compounds, and precautions against possible exposure to indium compounds are most important with regard to health management among indium-handling workers.

Problems in tritium handling in fusion reactors studies at CEA within the european effort

International Nuclear Information System (INIS)

Roth, E.; Hircq, B.; Fidelle, J.P.

1988-01-01

Technological aspects of tritium handling linked with the operation of a fusion reactor are reviewed. Tritium storage is discussed from the point of view of the volumme of a single unit and of the nature of the metal bed. Purification of tritium and recovery from tritiated compounds is studied, including conversion from water to the gaseous form. Interaction of tritium and structural materials is developed from the point of view of corrosion, embrittlement, permeation. A flowsheet displaying a conception of a reference tritium circuit is proposed, and consideration is given to specifications of large components, namely pumps and gatevalves for tritium circuits

Inhibitory action of an heterocyclic organic compound containing amine group for copper corrosion in 5,0 M nitric acid solution

Energy Technology Data Exchange (ETDEWEB)

El-Naggar, M.M.; Abdallah, M. [Benha Univ., Benha (Egypt). Chemistry Dept., Faculty of Science

2000-10-01

An heterocyclic organic compound containing amine group namely: 3-mercaptomethyl-4amino-5-hydroxy-1, 2, 4-triazole compound 1{sub a} was tested as a new inhibitor for copper corrosion in 5.0 M HNO{sub 3} solution. It proved to have a high value of inhibition efficiency (> 99.9%) at an inhibitor concentration of {>=} 2.5 x 10{sup -}3 M. A parallelism is established between the results obtained from weight loss, thermometric and galvanostatic polarization techniques. The high protective effect of compound I{sub a} is related to the decomposition of HNO{sub 2} formed through the autocatalytic cycle. The decomposition of HNO{sub 2} could be attributed to its reaction with the adsorbed inhibitor amine group. Furthermore, the results indicated that compound I{sub a} provides long-term protection and behaves as a mixed inhibitor type with a predominant cathodic effectiveness. [Italian] E' stato valutato, quale nuovo inibitore della corrosione del rame in soluzione 5.0 M di HNO{sub 3}, un composto organico eterociclico contenente un amino gruppo, chiamato: 3-mercaptometil-4amino-5-idrossi-1, 2, 4-triazolo composto I{sub a}. Questi, ad una concentrazione {>=} 2.5 x 10{sup -}3 M, ha dimostrato di possedere un elevato valore di efficienza di inibizione (> 99.9%). E' stato stabilito un parallelismo tra i risultati ottenuti dalla perdita di peso, da misure termometriche e di polarizzazione galvanostatica. L'elevato effetto protettivo del composto I{sub a} e' correlato alla decomposizione dell'HNO{sub 2} formatosi attraverso il ciclo autocatalitico. La decomposizione di HNO{sub 2} puo' essere attribuita alla sua reazione con il gruppo inibitore aminico adsorbito. Inoltre, i risultati indicano che il composto I{sub a} fornisce una protezione a lungo termine e si comporta come un inibitore di tipo misto con una predominante efficienza catodica.

A boring solution

Energy Technology Data Exchange (ETDEWEB)

Radiuk, M I; Iushkova, N E; Kozubovskii, A I

1979-10-25

A boring solution is being patented for boring for oil and gas, which can be used in wells, where the temperature of the circulating liquid reaches 100/sup 0/. Polyvinyl acetate emulsion (PVE) is added for the purpose of decreasing viscosity of the solution at a temperature of agression into the boring solution containing clay, water, carboxymethylcellulose (CBC), a chloride from the number of sodium, potassium, or magnesium chlorides. The solution has the following composition in %: clay, 10 to 20; CBC, 1.5 to 2.0; chloride, 5 to 20; PVE, 0.5 to 2; water, up to 100. In accordance to GOST 1000-62 for the accepted PVE, the compound has the following composition, in %: monomer, 0.8; dry residue, greater than or equal to 50; plasticizer (tributyl phthalate), 5 to 15. The boring solution is processed according to the following method. The original solution, containing clay, water, salts, receives 1.5 to 2% CBC and afterwards it is processed with 0.5 to 2% PVE.

Superhard Rhenium/Tungsten Diboride Solid Solutions.

Science.gov (United States)

Lech, Andrew T; Turner, Christopher L; Lei, Jialin; Mohammadi, Reza; Tolbert, Sarah H; Kaner, Richard B

2016-11-02

Rhenium diboride (ReB 2 ), containing corrugated layers of covalently bonded boron, is a superhard metallic compound with a microhardness reaching as high as 40.5 GPa (under an applied load of 0.49 N). Tungsten diboride (WB 2 ), which takes a structural hybrid between that of ReB 2 and AlB 2 , where half of the boron layers are planar (as in AlB 2 ) and half are corrugated (as in ReB 2 ), has been shown not to be superhard. Here, we demonstrate that the ReB 2 -type structure can be maintained for solid solutions of tungsten in ReB 2 with tungsten content up to a surprisingly large limit of nearly 50 atom %. The lattice parameters for the solid solutions linearly increase along both the a- and c-axes with increasing tungsten content, as evaluated by powder X-ray and neutron diffraction. From micro- and nanoindentation hardness testing, all of the compositions within the range of 0-48 atom % W are superhard, and the bulk modulus of the 48 atom % solid solution is nearly identical to that of pure ReB 2 . These results further indicate that ReB 2 -structured compounds are superhard, as has been predicted from first-principles calculations, and may warrant further studies into additional solid solutions or ternary compounds taking this structure type.

Oxidation of refractory sulfur compounds over Ti-containing mesoporous molecular sieves prepared by using a fluorosilicon compound.

Science.gov (United States)

Jeong, Kwang-Eun; Cho, Chin-Soo; Chae, Ho-Jeong; Kim, Chul-Ung; Jeong, Soon-Yong

2010-05-01

Titanium containing mesoporous molecular sieve (Ti-MMS) catalysts were studied for the oxidative desulfurization of refractory sulfur compounds. Ti-MMS catalysts were synthesized from fluorosilicon compounds and Ti with the hydrolysis reaction of H2SiF6 in an ammonia-surfactant mixed solution. The solid products were characterized by XRD, XRF, nitrogen adsorption, and diffuse reflectance UV-vis spectroscopy. Effects of Ti loading and oxidant/sulfur mole ratio, and sulfur species on ODS activity were investigated.

Remote handling for an ISIS target change

International Nuclear Information System (INIS)

Broome, T.A.; Holding, M.

1989-01-01

During 1987 two ISIS targets were changed. This document describes the main features of the remote handling aspects of the work. All the work has to be carried out using remote handling techniques. The radiation level measured on the surface of the reflector when the second target had been removed was about 800 mGy/h demonstrating that hands on operations on any part of the target reflector moderator assembly is not practical. The target changes were the first large scale operations in the Target Station Remote Handling Cell and a great deal was learned about both equipment and working practices. Some general principles emerged which are applicable to other active handling tasks on facilities like ISIS and these are discussed below. 8 figs

Materials Handling. Module SH-01. Safety and Health.

Science.gov (United States)

Center for Occupational Research and Development, Inc., Waco, TX.

This student module on materials handling is one of 50 modules concerned with job safety and health. It presents the procedures for safe materials handling. Discussed are manual handling methods (lifting and carrying by hand) and mechanical lifting (lifting by powered trucks, cranes or conveyors). Following the introduction, 15 objectives (each…

Incorporating Handling Qualities Analysis into Rotorcraft Conceptual Design

Science.gov (United States)

Lawrence, Ben

2014-01-01

This paper describes the initial development of a framework to incorporate handling qualities analyses into a rotorcraft conceptual design process. In particular, the paper describes how rotorcraft conceptual design level data can be used to generate flight dynamics models for handling qualities analyses. Also, methods are described that couple a basic stability augmentation system to the rotorcraft flight dynamics model to extend analysis to beyond that of the bare airframe. A methodology for calculating the handling qualities characteristics of the flight dynamics models and for comparing the results to ADS-33E criteria is described. Preliminary results from the application of the handling qualities analysis for variations in key rotorcraft design parameters of main rotor radius, blade chord, hub stiffness and flap moment of inertia are shown. Varying relationships, with counteracting trends for different handling qualities criteria and different flight speeds are exhibited, with the action of the control system playing a complex part in the outcomes. Overall, the paper demonstrates how a broad array of technical issues across flight dynamics stability and control, simulation and modeling, control law design and handling qualities testing and evaluation had to be confronted to implement even a moderately comprehensive handling qualities analysis of relatively low fidelity models. A key outstanding issue is to how to 'close the loop' with an overall design process, and options for the exploration of how to feedback handling qualities results to a conceptual design process are proposed for future work.

Enclosure for handling high activity materials abstract

International Nuclear Information System (INIS)

Jimeno de Osso, F.; Dominguez Rodriguez, G.; Cruz Castillo, F. de la; Rodriguez Esteban, A.

1977-01-01

One of the most important problems that are met at the laboratories producing and handling radioisotopes is that of designing, building and operating enclosures suitable for the safe handling of active substances. With that purpose in mind, an enclosure has been designed and built for handling moderately high activities under a shielding made of 150 mm thick lead. A description is given of those aspects that may be of interest to people working in this field. (author) [es

Interaction of Brilliant Blue dye solution with soil and its effect on mobility of compounds around the zones of preferenial flows at spruce stand

Directory of Open Access Journals (Sweden)

Bebej Juraj

2017-06-01

Full Text Available We performed field experiment with 10 g l−1 concentration of Brilliant Blue solutes in 100 l of water sprinkling on 1 × 1 m surface of the Dystric Cambisol. Consequently, four vertical profiles were exposed at experimental plot after 2 hours (CUT 2, 24 hours (CUT 24, 27 hours (CUT 27 and after 504 hours (CUT 504 in order to analyse spatiotemporal interactions among the BB solution (Na-salts, soil exchangeable complex and fine earth soil (% samples extracted from both the high and low coloured zones located around the optically visualised macropore preferred flow (PF zones. The concentration changes were quantifying via soil profiles not affected by BB (termed as REF located in the close vicinity of experimental plot. Observed changes in pH (H2O, chemical composition of fineearth soil, as well as in concentration of Na+ in soil exchangeable complex to suggest, the BB dye solution didn’t represent an inert tracer, but compounds strongly involved in reaction with surrounding soils. Recorded chemical trends seems to be the result both the competitive processes between the Na+ of BB dye solution and composition of surrounding soil exchangeable complex, as well and the spatial-temporal controlled mechanism of dye solution transfer in soil.

Antimicrobial compounds from leaf extracts of Jatropha curcas, Psidium guajava, and Andrographis paniculata.

Science.gov (United States)

Rahman, M M; Ahmad, S H; Mohamed, M T M; Ab Rahman, M Z

2014-01-01

The present research was conducted to discover antimicrobial compounds in methanolic leaf extracts of Jatropha curcas and Andrographis paniculata and ethanolic leaf extract of Psidium guajava and the effectiveness against microbes on flower preservative solution of cut Mokara Red orchid flowers was evaluated. The leaves were analyzed using gas chromatography-mass spectrometry. A total of nine, 66, and 29 compounds were identified in J. curcas, P. guajava, and A. paniculata leaf extracts, with five (88.18%), four (34.66%), and three (50.47%) having unique antimicrobial compounds, respectively. The experimental design on vase life was conducted using a completely randomized design with 10 replications. The flower vase life was about 6 days in the solution containing the P. guajava and A. paniculata leaf extracts at 15 mg/L. Moreover, solution with leaf extracts of A. paniculata had the lowest bacterial count compared to P. guajava and J. curcas. Thus, these leaf extracts revealed the presence of relevant antimicrobial compounds. The leaf extracts have the potential as a cut flower solution to minimize microbial populations and extend flower vase life. However, the activities of specific antimicrobial compounds and double or triple combination leaf extracts to enhance the effectiveness to extend the vase life need to be tested.

[Effect of compound hypertonic saline solution on septic rats].

Science.gov (United States)

Dong, Fang; Xu, Liang; Xu, Gang; Wang, Huabing; Lu, Huizhi; Cai, Liping

2015-01-01

To study the effect of compound hypertonic saline solution ( HSD ) on sepsis. 133 male Wistar rats were divided into four groups, sham operation group ( n = 15 ), cecal ligation and puncture ( CLP ) group ( n = 45 ), CLP plus normal saline ( NS ) group ( n = 45 ), and CLP plus HSD group ( n = 28 ). A rat model of sepsis was reproduced by CLP, and the rats in sham operation group received celiotomy without ligation and puncture. All rats in four groups received subcutaneous injection of 30 mL/kg 0.9% sodium chloride after laparotomy. The rats in CLP plus NS group and CLP plus HSD group received infusion of 5 mL/kg 0.9% sodium chloride or 7.5% sodium chloride/6% dextran post CLP via jugular vein for 3 hours, with the infusion rate of 0.4 mL×kg(-1)×min(-1). The survival rate of each group was observed 9 hours and 18 hours after laparotomy. Mean arterial pressure ( MAP ) at 0, 9, 18 hours were monitored. Blood specimens were collected from all rats 0, 9 and 18 hours after laparotomy, respectively, for measurement of the plasma levels of tumor necrosis factor-α ( TNF-α), interleukin-1β ( IL-1β ), and procalcitonin ( PCT ). The rats were all sacrificed, and their lung tissues were harvested for the neutrophil count in bronchoalveolar lavage fluid ( BALF ), myeloperoxidase ( MPO ) activity in lung tissue, wet/dry weight ratio ( W/D ) of lung, and pathological changes in lung tissue. There was no death in the sham operation group. The survival rates at 9 hours and 18 hours were 62.2% and 31.1% in the CLP group, 57.8% and 35.6% in the CLP plus NS group, 85.7% and 64.3% in the CLP plus HSD group, and they were all significantly higher compared with those of the CLP group and the CLP plus NS group ( Pmicroscope, no pathobiological changes were found in sham operation group. The lung tissues in the CLP group and the CLP plus NS group showed congestion, edema, infiltrating inflammatory changes, while the inflammatory changes in the lung tissue in the CLP plus HSD group

New hydrotalcite-like compounds containing yttrium

Energy Technology Data Exchange (ETDEWEB)

Fernandez, J.M.; Barriga, C.; Ulibarri, M.A. [Universidad de Cordoba (Spain)] [and others

1997-01-01

The synthesis of hydrotalcite-type compounds containing yttrium was carried out by the coprecipitation of Mg(II), Al(III), and Y(III) cations at 60 degrees C with strong alkaline solutions. Thermal treatments were applied and changes studied.

Development of tritium-handling technique

International Nuclear Information System (INIS)

Ohmura, Hiroshi; Hosaka, Akio; Okamoto, Takahumi

1988-01-01

The overview of developing activities for tritium-handling techniques in IHI are presented. To establish a fusion power plant, tritium handling is one of the key technologies. Recently in JAERI, conceptual design of FER (Fusion Experimental Reactor) has been carried out, and the FER system requires a processing system for a large amount of tritium. IHI concentrate on investigation of fuel gas purification, isotope separation and storage systems under contract with Toshiba Corporation. Design results of the systems and each components are reviewed. IHI has been developing fundamental handling techniques which are the ZrNi bed for hydrogen isotope storage and isotope separation by laser. The ZrNi bed with a tritium storage capacity of 1000 Ci has been constructed and recovery capability of the hydrogen isotope until 10 -4 Torr {0.013 Pa} was confirmed. In laser isotope separation, the optimum laser wave length has been determined. (author)

Handling of waste in ports

International Nuclear Information System (INIS)

Olson, P.H.

1994-01-01

The regulations governing the handling of port-generated waste are often national and/or local legislation, whereas the handling of ship-generated waste is governed by the MARPOL Convention in most parts of the world. The handling of waste consists of two main phases -collection and treatment. Waste has to be collected in every port and on board every ship, whereas generally only some wastes are treated and to a certain degree in ports and on board ships. This paper considers the different kinds of waste generated in both ports and on board ships, where and how it is generated, how it could be collected and treated. The two sources are treated together to show how some ship-generated waste may be treated in port installations primarily constructed for the treatment of the port-generated waste, making integrated use of the available treatment facilities. (author)

Magnetic resonance imaging of meniscal bucket-handle tears

International Nuclear Information System (INIS)

Dfouni, N.; Garcia, J.; Kindynis, Ph.; Bosson, D.

1997-01-01

To define MR signs of meniscal bucket-handle tears and evaluate the diagnostic efficiency of this technique. Retrospective study of 30 patients with a meniscal bucket-handle tear and 30 with a different type of tear, all proven by arthroscopy. The following MR signs of a bucket-handle tear were evaluated: 'separate meniscal fragment, 'double posterior cruciate ligament', 'snake sign' and 'double anterior horn'. A correct diagnosis of a bucket-handle tear was only made in 18/30 of patients. Several of the MR signs were seen in the same patient in 17 cases. A double posterior cruciate ligament was present only in cases of medial meniscus tears. The 12 menisci without these signs, and therefore not diagnosed as bucket-handle tears, were all classified as meniscal tears on the basis of signal extending to the meniscal surface. Nine of these were not displaced into the inter-condylar notch at arthroscopy. The interobserver agreement was excellent: kappa 0.88. The diagnosis of a bucket-handle meniscal tear, if it is displaced, can be made when one or more of the four MR evaluated signs are present. Other forms of meniscal tears are only exceptionally diagnosed as bucket-handle tears. (authors)

Can radiation damage to protein crystals be reduced using small-molecule compounds?

Energy Technology Data Exchange (ETDEWEB)

Kmetko, Jan [Kenyon College, Gambier, OH 43022 (United States); Warkentin, Matthew; Englich, Ulrich; Thorne, Robert E., E-mail: ret6@cornell.edu [Cornell University, Ithaca, NY 14853 (United States); Kenyon College, Gambier, OH 43022 (United States)

2011-10-01

Free-radical scavengers that are known to be effective protectors of proteins in solution are found to increase global radiation damage to protein crystals. Protective mechanisms may become deleterious in the protein-dense environment of a crystal. Recent studies have defined a data-collection protocol and a metric that provide a robust measure of global radiation damage to protein crystals. Using this protocol and metric, 19 small-molecule compounds (introduced either by cocrystallization or soaking) were evaluated for their ability to protect lysozyme crystals from radiation damage. The compounds were selected based upon their ability to interact with radiolytic products (e.g. hydrated electrons, hydrogen, hydroxyl and perhydroxyl radicals) and/or their efficacy in protecting biological molecules from radiation damage in dilute aqueous solutions. At room temperature, 12 compounds had no effect and six had a sensitizing effect on global damage. Only one compound, sodium nitrate, appeared to extend crystal lifetimes, but not in all proteins and only by a factor of two or less. No compound provided protection at T = 100 K. Scavengers are ineffective in protecting protein crystals from global damage because a large fraction of primary X-ray-induced excitations are generated in and/or directly attack the protein and because the ratio of scavenger molecules to protein molecules is too small to provide appreciable competitive protection. The same reactivity that makes some scavengers effective radioprotectors in protein solutions may explain their sensitizing effect in the protein-dense environment of a crystal. A more productive focus for future efforts may be to identify and eliminate sensitizing compounds from crystallization solutions.

Can radiation damage to protein crystals be reduced using small-molecule compounds?

International Nuclear Information System (INIS)

Kmetko, Jan; Warkentin, Matthew; Englich, Ulrich; Thorne, Robert E.

2011-01-01

Free-radical scavengers that are known to be effective protectors of proteins in solution are found to increase global radiation damage to protein crystals. Protective mechanisms may become deleterious in the protein-dense environment of a crystal. Recent studies have defined a data-collection protocol and a metric that provide a robust measure of global radiation damage to protein crystals. Using this protocol and metric, 19 small-molecule compounds (introduced either by cocrystallization or soaking) were evaluated for their ability to protect lysozyme crystals from radiation damage. The compounds were selected based upon their ability to interact with radiolytic products (e.g. hydrated electrons, hydrogen, hydroxyl and perhydroxyl radicals) and/or their efficacy in protecting biological molecules from radiation damage in dilute aqueous solutions. At room temperature, 12 compounds had no effect and six had a sensitizing effect on global damage. Only one compound, sodium nitrate, appeared to extend crystal lifetimes, but not in all proteins and only by a factor of two or less. No compound provided protection at T = 100 K. Scavengers are ineffective in protecting protein crystals from global damage because a large fraction of primary X-ray-induced excitations are generated in and/or directly attack the protein and because the ratio of scavenger molecules to protein molecules is too small to provide appreciable competitive protection. The same reactivity that makes some scavengers effective radioprotectors in protein solutions may explain their sensitizing effect in the protein-dense environment of a crystal. A more productive focus for future efforts may be to identify and eliminate sensitizing compounds from crystallization solutions

Evaluation of BTEX and phenol removal from aqueous solution by multi-solute adsorption onto smectite organoclay.

Science.gov (United States)

Carvalho, M N; da Motta, M; Benachour, M; Sales, D C S; Abreu, C A M

2012-11-15

The removal process of BTEX and phenol was evaluated. The smectite organoclay for single-solute system reached removal was evaluated by adsorption on smectite organoclay adsorbent by kinetic and equilibrium efficiencies between 55 and 90% while was reached between 30 and 90% for multi-solute system at 297 K and pH 9. The Langmuir-Freundlich model was used to fit the experimental data with correlation coefficient between 0.98 and 0.99 providing kinetic and equilibrium parameter values. Phenol and ethylbenzene presented high maximum adsorbed amount, 8.28 and 6.67 mg/g, respectively, compared to the other compounds for single-solute. Toluene and p-xylene presented high values of adsorption constant which indicates a high adsorption affinity of compounds to organoclay surface and high binding energy of adsorption. Phenol presented low kinetic adsorption constant value indicating slow rate of adsorption. Copyright © 2012 Elsevier B.V. All rights reserved.

How to Handle Impasses in Bargaining.

Science.gov (United States)

Durrant, Robert E.

Guidelines in an outline format are presented to school board members and administrators on how to handle impasses in bargaining. The following two rules are given: there sometimes may be strikes, but there always will be settlements; and on the way to settlements, there always will be impasses. Suggestions for handling impasses are listed under…

New System For Tokamak T-10 Experimental Data Acquisition, Data Handling And Remote Access

International Nuclear Information System (INIS)

Sokolov, M. M.; Igonkina, G. B.; Koutcherenko, I. Yu.; Nurov, D. N.

2008-01-01

For carrying out the experiments on nuclear fusion devices in the Institute of Nuclear Fusion, Moscow, a system for experimental data acquisition, data handling and remote access (further 'DAS-T10') was developed and has been used in the Institute since the year 2000. The DAS-T10 maintains the whole cycle of experimental data handling: from configuration of data measuring equipment and acquisition of raw data from the fusion device (the Device), to presentation of math-processed data and support of the experiment data archive. The DAS-T10 provides facilities for the researchers to access the data both at early stages of an experiment and well afterwards, locally from within the experiment network and remotely over the Internet.The DAS-T10 is undergoing a modernization since the year 2007. The new version of the DAS-T10 will accommodate to modern data measuring equipment and will implement improved architectural solutions. The innovations will allow the DAS-T10 to produce and handle larger amounts of experimental data, thus providing the opportunities to intensify and extend the fusion researches. The new features of the DAS-T10 along with the existing design principles are reviewed in this paper

Main regularities of radiolytic transformations of bifunctional organic compounds

International Nuclear Information System (INIS)

Petryaev, E.P.; Shadyro, O.I.

1985-01-01

General regularities of the radiolysis of bifunctional organic compounds (α-diols, ethers of α-diols, amino alcohols, hydroxy aldehydes and hydroxy asids) in aqueous solutions from the early stages of the process to formation of finite products are traced. It is pointed out that the most characteristic course of radiation-chemical, transformation of bifunctional compounds in agueous solutions in the fragmentation process with monomolecular decomposition of primary radicals of initial substrances and simultaneous scission of two vicinal in respect to radical centre bonds via five-membered cyclic transient state. The data obtained are of importance for molecular radiobiology

Hyperbolic Location Fingerprinting: A Calibration-Free Solution for Handling Differences in Signal Strength

DEFF Research Database (Denmark)

Kjærgaard, Mikkel Baun; Munk, Carsten Valdemar

2008-01-01

records fingerprints as signal-strength ratios between pairs of base stations instead of absolute signal-strength values. The proposed solution has been evaluated by extending two well-known location fingerprinting techniques to hyperbolic location fingerprinting. The extended techniques have been tested...

Numerical-solution package for transient two-phase-flow equations

International Nuclear Information System (INIS)

Mahaffy, J.H.; Liles, D.

1982-01-01

The methods presented have proven to be extremely reliable tools for reactor safety analysis. They can handle a wide range of fluid conditions and time scales with minimal failures, while maintaining time step sizes well above those possible with most other techniques. This robustness is due not only to the finite-difference equations themselves, but also to the choice of solution technique, because poorly chosen iterative solution procedures often require a limit on the time-step size for proper convergence of the iteration

WASTE HANDLING BUILDING FIRE PROTECTION SYSTEM DESCRIPTION DOCUMENT

Energy Technology Data Exchange (ETDEWEB)

J. D. Bigbee

2000-06-21

The Waste Handling Building Fire Protection System provides the capability to detect, control, and extinguish fires and/or mitigate explosions throughout the Waste Handling Building (WHB). Fire protection includes appropriate water-based and non-water-based suppression, as appropriate, and includes the distribution and delivery systems for the fire suppression agents. The Waste Handling Building Fire Protection System includes fire or explosion detection panel(s) controlling various detectors, system actuation, annunciators, equipment controls, and signal outputs. The system interfaces with the Waste Handling Building System for mounting of fire protection equipment and components, location of fire suppression equipment, suppression agent runoff, and locating fire rated barriers. The system interfaces with the Waste Handling Building System for adequate drainage and removal capabilities of liquid runoff resulting from fire protection discharges. The system interfaces with the Waste Handling Building Electrical Distribution System for power to operate, and with the Site Fire Protection System for fire protection water supply to automatic sprinklers, standpipes, and hose stations. The system interfaces with the Site Fire Protection System for fire signal transmission outside the WHB as needed to respond to a fire emergency, and with the Waste Handling Building Ventilation System to detect smoke and fire in specific areas, to protect building high-efficiency particulate air (HEPA) filters, and to control portions of the Waste Handling Building Ventilation System for smoke management and manual override capability. The system interfaces with the Monitored Geologic Repository (MGR) Operations Monitoring and Control System for annunciation, and condition status.

WASTE HANDLING BUILDING FIRE PROTECTION SYSTEM DESCRIPTION DOCUMENT

International Nuclear Information System (INIS)

J. D. Bigbee

2000-01-01

The Waste Handling Building Fire Protection System provides the capability to detect, control, and extinguish fires and/or mitigate explosions throughout the Waste Handling Building (WHB). Fire protection includes appropriate water-based and non-water-based suppression, as appropriate, and includes the distribution and delivery systems for the fire suppression agents. The Waste Handling Building Fire Protection System includes fire or explosion detection panel(s) controlling various detectors, system actuation, annunciators, equipment controls, and signal outputs. The system interfaces with the Waste Handling Building System for mounting of fire protection equipment and components, location of fire suppression equipment, suppression agent runoff, and locating fire rated barriers. The system interfaces with the Waste Handling Building System for adequate drainage and removal capabilities of liquid runoff resulting from fire protection discharges. The system interfaces with the Waste Handling Building Electrical Distribution System for power to operate, and with the Site Fire Protection System for fire protection water supply to automatic sprinklers, standpipes, and hose stations. The system interfaces with the Site Fire Protection System for fire signal transmission outside the WHB as needed to respond to a fire emergency, and with the Waste Handling Building Ventilation System to detect smoke and fire in specific areas, to protect building high-efficiency particulate air (HEPA) filters, and to control portions of the Waste Handling Building Ventilation System for smoke management and manual override capability. The system interfaces with the Monitored Geologic Repository (MGR) Operations Monitoring and Control System for annunciation, and condition status

Quinone-induced protein handling changes: Implications for major protein handling systems in quinone-mediated toxicity

International Nuclear Information System (INIS)

Xiong, Rui; Siegel, David; Ross, David

2014-01-01

Para-quinones such as 1,4-Benzoquinone (BQ) and menadione (MD) and ortho-quinones including the oxidation products of catecholamines, are derived from xenobiotics as well as endogenous molecules. The effects of quinones on major protein handling systems in cells; the 20/26S proteasome, the ER stress response, autophagy, chaperone proteins and aggresome formation, have not been investigated in a systematic manner. Both BQ and aminochrome (AC) inhibited proteasomal activity and activated the ER stress response and autophagy in rat dopaminergic N27 cells. AC also induced aggresome formation while MD had little effect on any protein handling systems in N27 cells. The effect of NQO1 on quinone induced protein handling changes and toxicity was examined using N27 cells stably transfected with NQO1 to generate an isogenic NQO1-overexpressing line. NQO1 protected against BQ–induced apoptosis but led to a potentiation of AC- and MD-induced apoptosis. Modulation of quinone-induced apoptosis in N27 and NQO1-overexpressing cells correlated only with changes in the ER stress response and not with changes in other protein handling systems. These data suggested that NQO1 modulated the ER stress response to potentiate toxicity of AC and MD, but protected against BQ toxicity. We further demonstrated that NQO1 mediated reduction to unstable hydroquinones and subsequent redox cycling was important for the activation of the ER stress response and toxicity for both AC and MD. In summary, our data demonstrate that quinone-specific changes in protein handling are evident in N27 cells and the induction of the ER stress response is associated with quinone-mediated toxicity. - Highlights: • Unstable hydroquinones contributed to quinone-induced ER stress and toxicity

Quinone-induced protein handling changes: Implications for major protein handling systems in quinone-mediated toxicity

Energy Technology Data Exchange (ETDEWEB)

Xiong, Rui; Siegel, David; Ross, David, E-mail: david.ross@ucdenver.edu

2014-10-15

Para-quinones such as 1,4-Benzoquinone (BQ) and menadione (MD) and ortho-quinones including the oxidation products of catecholamines, are derived from xenobiotics as well as endogenous molecules. The effects of quinones on major protein handling systems in cells; the 20/26S proteasome, the ER stress response, autophagy, chaperone proteins and aggresome formation, have not been investigated in a systematic manner. Both BQ and aminochrome (AC) inhibited proteasomal activity and activated the ER stress response and autophagy in rat dopaminergic N27 cells. AC also induced aggresome formation while MD had little effect on any protein handling systems in N27 cells. The effect of NQO1 on quinone induced protein handling changes and toxicity was examined using N27 cells stably transfected with NQO1 to generate an isogenic NQO1-overexpressing line. NQO1 protected against BQ–induced apoptosis but led to a potentiation of AC- and MD-induced apoptosis. Modulation of quinone-induced apoptosis in N27 and NQO1-overexpressing cells correlated only with changes in the ER stress response and not with changes in other protein handling systems. These data suggested that NQO1 modulated the ER stress response to potentiate toxicity of AC and MD, but protected against BQ toxicity. We further demonstrated that NQO1 mediated reduction to unstable hydroquinones and subsequent redox cycling was important for the activation of the ER stress response and toxicity for both AC and MD. In summary, our data demonstrate that quinone-specific changes in protein handling are evident in N27 cells and the induction of the ER stress response is associated with quinone-mediated toxicity. - Highlights: • Unstable hydroquinones contributed to quinone-induced ER stress and toxicity.

Handling Kids in Crisis with Care

Science.gov (United States)

Bushinski, Cari

2018-01-01

The Handle with Care program helps schools help students who experience trauma. While at the scene of an event like a domestic violence call, drug raid, or car accident, law enforcement personnel determine the names and school of any children present. They notify that child's school to "handle ___ with care" the next day, and the school…

Survey of tritiated oil sources and handling practices

International Nuclear Information System (INIS)

Miller, J.M.

1994-08-01

Tritium interactions with oil sources (primarily associated with pumps) in tritium-handling facilities can lead to the incorporation of tritium in the oil and the production of tritiated hydrocarbons. This results in a source of radiological hazard and the need for special handling considerations during maintenance, decontamination, decommissioning and waste packaging and storage. The results of a general survey of tritiated-oil sources and their associated characteristics, handling practices, analysis techniques and waste treatment/storage methods are summarized here. Information was obtained from various tritium-handling laboratories, fusion devices, and CANDU plants. 38 refs., 1 fig

Effects of handling on fear reactions in young Icelandic horses

DEFF Research Database (Denmark)

Marsbøll, Anna Feldberg; Christensen, Janne Winther

2015-01-01

To investigate the effect of a short-term standardised handling procedure on reactions of young horses in 2 types of fear tests (including and excluding human handling). Study design An experimental study with 3-year-old Icelandic horses (n = 24). Methods Handled horses (n = 12) were trained according...... to a standardised handling procedure whereas controls (n = 12) remained untrained. Behavioural and heart rate responses in a novel object test and 2 handling fear tests (HFTs) were measured. The HFTs were conducted with both an unknown (HFT-unknown) and a known handler (HFT-known). Results There was no effect...... correlated significantly between tests. Conclusions Previous handling may affect the behavioural fear response of horses when handled by their usual handler, whereas this effect did not apply to an unknown handler. Heart rates appeared unaffected by handling and may be a more reliable indicator...

Handling wood shavings

Energy Technology Data Exchange (ETDEWEB)

1974-09-18

Details of bulk handling equipment suitable for collection and compressing wood waste from commercial joinery works are discussed. The Redler Bin Discharger ensures free flow of chips from storage silo discharge prior to compression into briquettes for use as fuel or processing into chipboard.

Unresolved issues for the disposal of remote-handled transuranic waste in the Waste Isolation Pilot Plant

International Nuclear Information System (INIS)

Silva, M.K.; Neill, R.H.

1994-09-01

The purpose of the Waste Isolation Pilot Plant (WIPP) is to dispose of 176,000 cubic meters of transuranic (TRU) waste generated by the defense activities of the US Government. The envisioned inventory contains approximately 6 million cubic feet of contact-handled transuranic (CH TRU) waste and 250,000 cubic feet of remote handled transuranic (RH TRU) waste. CH TRU emits less than 0.2 rem/hr at the container surface. Of the 250,000 cubic feet of RH TRU waste, 5% by volume can emit up to 1,000 rem/hr at the container surface. The remainder of RH TRU waste must emit less than 100 rem/hr. These are major unresolved problems with the intended disposal of RH TRU waste in the WIPP. (1) The WIPP design requires the canisters of RH TRU waste to be emplaced in the walls (ribs) of each repository room. Each room will then be filled with drums of CH TRU waste. However, the RH TRU waste will not be available for shipment and disposal until after several rooms have already been filled with drums of CH TRU waste. RH TRU disposal capacity will be loss for each room that is first filled with CH TRU waste. (2) Complete RH TRU waste characterization data will not be available for performance assessment because the facilities needed for waste handling, waste treatment, waste packaging, and waste characterization do not yet exist. (3) The DOE does not have a transportation cask for RH TRU waste certified by the US Nuclear Regulatory Commission (NRC). These issues are discussed along with possible solutions and consequences from these solutions. 46 refs

The low-level waste handling challenge at the Feed Materials Production Center

International Nuclear Information System (INIS)

Harmon, J.E.; Diehl, D.E.; Gardner, R.L.

1988-02-01

The management of low-level wastes from the production of depleted uranium at the Feed Materials Production Center presents an enormous challenge. The recovery of uranium from materials contaminated with depleted uranium is usually not economical. As a result, large volumes of wastes are generated. The Westinghouse Materials Company of Ohio has established an aggressive waste management program. Simple solutions have been applied to problems in the areas of waste handling and waste minimization. The success of this program has been demonstrated by the reduction of low-level waste inventory at the Feed Materials Production Center. 8 refs., 4 figs

The low-level waste handling challenge at the Feed Materials Production Center

International Nuclear Information System (INIS)

Harmon, J.E.; Diehl, D.E.; Gardner, R.L.

1988-01-01

The management of low-level wastes from the production of depleted uranium at the Feed Materials Production Center presents an enormous challenge. The recovery of uranium from materials contaminated with depleted uranium is usually not economical. As a result, large volumes of wastes are generated. The Westinghouse Materials Company of Ohio has established an aggressive waste management program. Simple solutions have been applied to problems in the areas of waste handling and waste minimization. The success of this program has been demonstrated by the reduction of low-level waste inventory at the Feed Materials Production Center

Tritium handling trade studies and design options for the GA/ANL TNS

International Nuclear Information System (INIS)

Mintz, J.M.; Clemmer, R.G.; Maroni, V.A.

1978-01-01

A comprehensive effort involving members of both the General Atomic Company (GA) and the Argonne National Laboratory (ANL) has been undertaken to define the objectives, criteria and potential systems design solutions that accrue to the tritium handling systems for the next logical step in tokamak reactor development (TNS). A primary focus of these activities has been a systematic analysis of fuel cycle parameters and trade studies on the sensitivity of these parameters to reactor design and operating conditions. Principal results of these analyses and an assembly of potentially useful design concepts for various subsystems of the fuel cycle are presented

Handling of bulk solids theory and practice

CERN Document Server

Shamlou, P A

1990-01-01

Handling of Bulk Solids provides a comprehensive discussion of the field of solids flow and handling in the process industries. Presentation of the subject follows classical lines of separate discussions for each topic, so each chapter is self-contained and can be read on its own. Topics discussed include bulk solids flow and handling properties; pressure profiles in bulk solids storage vessels; the design of storage silos for reliable discharge of bulk materials; gravity flow of particulate materials from storage vessels; pneumatic transportation of bulk solids; and the hazards of solid-mater

Torus sector handling system

International Nuclear Information System (INIS)

Grisham, D.L.

1981-01-01

A remote handling system is proposed for moving a torus sector of the accelerator from under the cryostat to a point where it can be handled by a crane and for the reverse process for a new sector. Equipment recommendations are presented, as well as possible alignment schemes. Some general comments about future remote-handling methods and the present capabilities of existing systems will also be included. The specific task to be addressed is the removal and replacement of a 425 to 450 ton torus sector. This requires a horizontal movement of approx. 10 m from a normal operating position to a point where its further transport can be accomplished by more conventional means (crane or floor transporter). The same horizontal movement is required for reinstallation, but a positional tolerance of 2 cm is required to allow reasonable fit-up for the vacuum seal from the radial frames to the torus sector. Since the sectors are not only heavy but rather tall and narrow, the transport system must provide a safe, stable, and repeatable method fo sector movement. This limited study indicates that the LAMPF-based method of transporting torus sectors offers a proven method of moving heavy items. In addition, the present state of the art in remote equipment is adequate for FED maintenance

Pretreatment Solution for Water Recovery Systems

Science.gov (United States)

Muirhead, Dean (Inventor)

2018-01-01

Chemical pretreatments are used to produce usable water by treating a water source with a chemical pretreatment that contains a hexavalent chromium and an acid to generate a treated water source, wherein the concentration of sulfate compounds in the acid is negligible, and wherein the treated water source remains substantially free of precipitates after the addition of the chemical pretreatment. Other methods include reducing the pH in urine to be distilled for potable water extraction by pretreating the urine before distillation with a pretreatment solution comprising one or more acid sources selected from a group consisting of phosphoric acid, hydrochloric acid, and nitric acid, wherein the urine remains substantially precipitate free after the addition of the pretreatment solution. Another method described comprises a process for reducing precipitation in urine to be processed for water extraction by mixing the urine with a pretreatment solution comprising hexavalent chromium compound and phosphoric acid.

Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy.

Science.gov (United States)

Pavlov, Alexander A; Denisov, Gleb L; Kiskin, Mikhail A; Nelyubina, Yulia V; Novikov, Valentin V

2017-12-18

Spin transitions in spin-crossover compounds are now routinely studied in the solid state by magnetometry; however, only a few methods exist for studies in solution. The currently used Evans method, which relies on NMR spectroscopy to measure the magnetic susceptibility, requires the availability of a very pure sample of the paramagnetic compound and its exact concentration. To overcome these limitations, we propose an alternative NMR-based technique for evaluating spin-state populations by only using the chemical shifts of a spin-crossover compound; those can be routinely obtained for a solution that contains unknown impurities and paramagnetic admixtures or is contaminated otherwise.

Getting to grips with remote handling and robotics

Energy Technology Data Exchange (ETDEWEB)

Mosey, D [Ontario Hydro, Toronto (Canada)

1984-12-01

A report on the Canadian Nuclear Society Conference on robotics and remote handling in the nuclear industry, September 1984. Remote handling in reactor operations, particularly in the Candu reactors is discussed, and the costs and benefits of use of remote handling equipment are considered. Steam generator inspection and repair is an area in which practical application of robotic technology has made a major advance.

Handling knowledge on osteoporosis - a qualitative study

DEFF Research Database (Denmark)

Nielsen, Dorthe; Huniche, Lotte; Brixen, Kim

2013-01-01

Scand J Caring Sci; 2012 Handling knowledge on osteoporosis - a qualitative study The aim of this qualitative study was to increase understanding of the importance of osteoporosis information and knowledge for patients' ways of handling osteoporosis in their everyday lives. Interviews were...

Redefining NHS complaint handling--the real challenge.

Science.gov (United States)

Seelos, L; Adamson, C

1994-01-01

More and more organizations find that a constructive and open dialogue with their customers can be an effective strategy for building long-term customer relations. In this context, it has been recognized that effective complaint-contact handling can make a significant contribution to organizations' attempts to maximize customer satisfaction and loyalty. Within the NHS, an intellectual awareness exists that effective complaint/contact handling can contribute to making services more efficient and cost-effective by developing customer-oriented improvement initiatives. Recent efforts have focused on redefining NHS complaint-handling procedures to make them more user-friendly and effective for both NHS employees and customers. Discusses the challenges associated with opening up the NHS to customer feedback. Highlights potential weaknesses in the current approach and argues that the real challenge is for NHS managers to facilitate a culture change that moves the NHS away from a long-established defensive complaint handling practice.

Adsorption of Volatile Organic Compounds from Aqueous Solution by Granular Activated Carbon in Batch System

International Nuclear Information System (INIS)

Zeinali, F.; Ghoreyshi, A. A.; Najafpour, G.

2011-01-01

Chlorinated hydrocarbons and aromatics are the major volatile organic compounds that contaminate the ground water and industrial waste waters. The best way to overcome this problem is to recover the dissolved compounds in water. In order to evaluate the potential ability of granular activated carbon for recovery of volatile organic compounds from water, the equilibrium adsorption was investigated. This study deals with the adsorption of dichloromethane as a typical chlorinated volatile organic compound and toluene as the representative of aromatic volatile organic compounds on a commercial granular activated carbon. The adsorption isotherms of these two volatile organic compounds on granular activated carbon were measured at three different temperatures, toluene at 293, 303 and 313 K and dichloromethane at 298, 303 and 313 K within their solubility concentration range in water. The maximum adsorption capacity of dichloromethane and toluene adsorption by granular activated carbon was 4 and 0.2 mol/Kg-1, respectively. The experimental data obtained were correlated with different adsorption isotherm models. The Langmuir model was well adapted to the description of dichloromethane adsorption on granular activated carbon at all three temperatures, while the adsorption of toluene on granular activated carbon was found to be well described by the Langmuir-BET hybrid model at all three temperatures. The heat of adsorption was also calculated based on the thermodynamic equation of Clausius Clapeyron, which indicates the adsorption process is endothermic for both compounds.

Treating contaminated organic compounds using the DETOX process

International Nuclear Information System (INIS)

Elsberry, K.; Dhooge, P.M.

1993-01-01

Waste matrices containing organic compounds, radionuclides, and metals pose difficult problems in waste treatment and disposal when the organic compounds and/or metals are considered to be hazardous. This paper describes the results of bench-scale studies of DETOX applied to the components of liquid mixed wastes, with the goal of establishing parameters for designing a prototype waste treatment unit. Apparent reaction rate orders for organic compounds and the dependence of apparent reaction rate on solution composition and the contact area were measured for vacuum pump oil, scintillation fluids, and trichloroethylene. Reaction rate was superior in chloride-based solutions and was proportional to the contact area above about 20 g/kg loading of organic material. Oxidations in 4-L volume, mixed bench-top reactor have given destruction efficiencies of 0.999999+ g/g for common organic compounds. Reaction rates achieved in the mixed bench-top reactor were one to two orders of magnitude greater than had been achieved in unmixed reactions; a thoroughly mixed reactor should be capable of oxidizing 10 to 100+ g of organic material per L-hr. Results are also presented on the solvation efficiency of DETOX for mercury, cerium, and neodymium, and for removal/destruction of organic compounds sorbed on vermiculite. The next stage of development will be converting the bench-top unit to continuous processing

Molar extinction coefficients of solutions of some organic compounds

Indian Academy of Sciences (India)

(C4H8O2), succinimide (C4H5NO2) as estimated from the measured absorbance of. 7 radiations in their ... species in the solution and ε is called the molar absorptivity or extinction coefficient. (l mol-1cm-1 or ... Integration of eq. (4) leads to.

MHSS: a material handling system simulator

Energy Technology Data Exchange (ETDEWEB)

Pomernacki, L.; Hollstien, R.B.

1976-04-07

A Material Handling System Simulator (MHSS) program is described that provides specialized functional blocks for modeling and simulation of nuclear material handling systems. Models of nuclear fuel fabrication plants may be built using functional blocks that simulate material receiving, storage, transport, inventory, processing, and shipping operations as well as the control and reporting tasks of operators or on-line computers. Blocks are also provided that allow the user to observe and gather statistical information on the dynamic behavior of simulated plants over single or replicated runs. Although it is currently being developed for the nuclear materials handling application, MHSS can be adapted to other industries in which material accountability is important. In this paper, emphasis is on the simulation methodology of the MHSS program with application to the nuclear material safeguards problem. (auth)

The Laplace series solution for local fractional Korteweg-de Vries equation

Directory of Open Access Journals (Sweden)

Ye Shan-Shan

2016-01-01

Full Text Available In this paper, we consider a new application of the local fractional Laplace series expansion method to handle the local fractional Korteweg-de Vries equation. The obtained solution with non-differentiable type shows that the technology is accurate and efficient.

Development of Safe Food Handling Guidelines for Korean Consumers.

Science.gov (United States)

Kang, Hee-Jin; Lee, Min-Woo; Hwang, In-Kyeong; Kim, Jeong-Weon

2015-08-01

The purpose of this study was to develop guidelines for Korean consumers with regard to safe food handling practices at home by identifying current food handling issues. Korean consumers' behaviors regarding their safe food handling were identified via survey questionnaires that included items on individual hygiene practices, prepreparation steps when cooking, the cooking process, and the storage of leftover foods. The subjects were 417 Korean parents with elementary school children living in Seoul and Gyeonggi Province in the central area of Korea. The survey results revealed gaps between the knowledge or practices of Korean consumers and scientific evidence pertaining to safe food handling practices. Based on these findings, a leaflet on safe food handling guidelines was developed in accordance with Korean food culture. These guidelines suggest personal hygiene practices as well as fundamental principles and procedures for safe food handling from the stage of food purchase to that of keeping leftover dishes. A pilot application study with 50 consumers revealed that the guidelines effectively improved Korean consumers' safe food handling practices, suggesting that they can serve as practical educational material suitable for Korean consumers.

Where humans meet machines innovative solutions for knotty natural-language problems

CERN Document Server

Markowitz, Judith

2013-01-01

Where Humans Meet Machines: Innovative Solutions for Knotty Natural-Language Problems brings humans and machines closer together by showing how linguistic complexities that confound the speech systems of today can be handled effectively by sophisticated natural-language technology. Some of the most vexing natural-language problems that are addressed in this book entail   recognizing and processing idiomatic expressions, understanding metaphors, matching an anaphor correctly with its antecedent, performing word-sense disambiguation, and handling out-of-vocabulary words and phrases. This fourteen-chapter anthology consists of contributions from industry scientists and from academicians working at major universities in North America and Europe. They include researchers who have played a central role in DARPA-funded programs and developers who craft real-world solutions for corporations. These contributing authors analyze the role of natural language technology in the global marketplace; they explore the need f...

Bonding in inorganic compounds: a study by x-ray photoelectron spectroscopy

International Nuclear Information System (INIS)

Avanzino, S.C.

1978-10-01

Core electron binding energies were measured for a variety of inorganic and organometallic compounds using gas-phase X-ray photoelectron spectroscopy (XPS). The atomic charge distributions in these molecules are deduced from the binding energies, often leading to a better understanding of the bonding in these compounds. The XPS spectra of fifteen volatile tin compounds were recorded. The data suggest that the metal d orbitals are not significantly involved in the bonding. The oxygen ls XPS spectra of gaseous CH 3 Mn(CO) 5 , [π-C 5 H 5 Fe(CO) 2 ] 2 , and Co 4 (CO) 12 can be readily resolved into separate peaks due to bridging and terminal carbonyl groups. The C ls spectrum of Fe(CO) 5 consists of a single symmetric peak. The carbonyl ligand core binding energies of transition-metal carbonyl complexes are sensitive to differences in the metal-to-CO ligand bonding. Both C ls and O ls carbonyl binding energies correlate well with average C-O stretching force constants or average C-O stretching frequencies. The metal and carbonyl binding energies in a series of pentacarbonylmanganese complexes LMn(CO) 5 are a good measure of the relative electronegativities of the ligands L. High-quality X-ray photoelectron spectra have been obtained for compounds dissolved in glycerin solutions, and aqueous solutions were converted into glycerin solutions which gave good XRSspectra of the solutes. The technique appears promising as a future analytical application of X-ray photoelectron spectroscopy. The shifts in the binding energies of oxygen, chlorine, and carbon atoms in some isoelectronic isostructural compounds can be explained in terms of simple trends in atomic charges

Chemical deposition methods using supercritical fluid solutions

Science.gov (United States)

Sievers, Robert E.; Hansen, Brian N.

1990-01-01

A method for depositing a film of a desired material on a substrate comprises dissolving at least one reagent in a supercritical fluid comprising at least one solvent. Either the reagent is capable of reacting with or is a precursor of a compound capable of reacting with the solvent to form the desired product, or at least one additional reagent is included in the supercritical solution and is capable of reacting with or is a precursor of a compound capable of reacting with the first reagent or with a compound derived from the first reagent to form the desired material. The supercritical solution is expanded to produce a vapor or aerosol and a chemical reaction is induced in the vapor or aerosol so that a film of the desired material resulting from the chemical reaction is deposited on the substrate surface. In an alternate embodiment, the supercritical solution containing at least one reagent is expanded to produce a vapor or aerosol which is then mixed with a gas containing at least one additional reagent. A chemical reaction is induced in the resulting mixture so that a film of the desired material is deposited.

Environmental and safety aspects. The best of 'powder handling and processing' 1989 - 1997. 'Bulk solids handling' 1992 - 1997 (H/2000)

Energy Technology Data Exchange (ETDEWEB)

Woehlbier, R.H. (ed.)

2000-07-01

The book contains articles published either during 1992-1997 in ''bulk solids handling'' or during 1989-1997 in ''powder handling and processing''. Main topics are aspects of safety and environmental protection in bulk solids handling: dusts, hazardous powders, prevention and mitigation of dust explosions, powdered coal handling, dedusting, filters, electrostatic precipitation, materials recovery, occupational safety.(uke)

7 CFR 959.126 - Handling of culls.

Science.gov (United States)

2010-01-01

... 7 Agriculture 8 2010-01-01 2010-01-01 false Handling of culls. 959.126 Section 959.126 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Marketing Agreements...) Handled for canning or freezing. (b) As a safeguard against culls entering fresh market channels each...

Survey of postharvest handling, preservation and processing ...

African Journals Online (AJOL)

Survey of postharvest handling, preservation and processing practices along the camel milk chain in Isiolo district, Kenya. ... Despite the important contribution of camel milk to food security for pastoralists in Kenya, little is known about the postharvest handling, preservation and processing practices. In this study, existing ...

Handling uncertainty through adaptiveness in planning approaches

NARCIS (Netherlands)

Zandvoort, M.; Vlist, van der M.J.; Brink, van den A.

2018-01-01

Planners and water managers seek to be adaptive to handle uncertainty through the use of planning approaches. In this paper, we study what type of adaptiveness is proposed and how this may be operationalized in planning approaches to adequately handle different uncertainties. We took a

PREPD O and VE remote handling system

International Nuclear Information System (INIS)

Theil, T.N.

1985-01-01

The Process Experimental Pilot Plant (PREPP) at the Idaho National Engineering Laboratory is designed for volume reduction and packaging of transuranic (TRU) waste. The PREPP opening and verification enclosure (O and VE) remote handling system, within that facility, is designed to provide examination of the contents of various TRU waste storage containers. This remote handling system will provide the means of performing a hazardous operation that is currently performed manually. The TeleRobot to be used in this system is a concept that will incorporate and develop man in the loop operation (manual mode), standardized automatic sequencing of end effector tools, increased payload and reach over currently available computer-controlled robots, and remote handling of a hazardous waste operation. The system is designed within limited space constraints and an operation that was originally planned, and is currently being manually performed at other plants. The PREPP O and VE remote handling system design incorporates advancing technology to improve the working environment in the nuclear field

Harvesting and handling agricultural residues for energy

Energy Technology Data Exchange (ETDEWEB)

Jenkins, B.M.; Summer, H.R.

1986-05-01

Significant progress in understanding the needs for design of agricultural residue collection and handling systems has been made but additional research is required. Recommendations are made for research to (a) integrate residue collection and handling systems into general agricultural practices through the development of multi-use equipment and total harvest systems; (b) improve methods for routine evaluation of agricultural residue resources, possibly through remote sensing and image processing; (c) analyze biomass properties to obtain detailed data relevant to engineering design and analysis; (d) evaluate long-term environmental, social, and agronomic impacts of residue collection; (e) develop improved equipment with higher capacities to reduce residue collection and handling costs, with emphasis on optimal design of complete systems including collection, transportation, processing, storage, and utilization; and (f) produce standard forms of biomass fuels or products to enhance material handling and expand biomass markets through improved reliability and automatic control of biomass conversion and other utilization systems. 118 references.

Electrochemical studies, in-situ and ex-situ characterizations of different manganese compounds electrodeposited in aerated solutions

International Nuclear Information System (INIS)

Peulon, S.; Lacroix, A.; Chausse, A.; Larabi-Gruet, N.

2007-01-01

This work deals with the electrodeposition of manganese compounds. A systematic study of the synthesis experimental conditions has been carried out, and the obtained depositions have been characterized by different ex-situ analyses methods (XRD, FTIR, SEM). The in-situ measurements of mass increase with a quartz microbalance during the syntheses have allowed to estimate the growth mechanisms which are in agreement with the ex-situ characterizations. The cation has an important role in the nature of the electrodeposited compounds. In presence of sodium, a mixed lamellar compound Mn(III)/Mn(IV), the birnessite, is deposited, whereas in presence of potassium, bixbyite is formed (Mn 2 O 3 ), these two compounds having a main role in the environment. The substrate can also influence the nature of the formed intermediary compounds. Little studied compounds such as feitkneichtite (β-MnOOH) and groutite (α-MnOOH) have been revealed. (O.M.)

The Conceptual Design of a Mechatronic System to Handle Bedridden Elderly Individuals.

Science.gov (United States)

Bruno, Silva; José, Machado; Filomena, Soares; Vítor, Carvalho; Demétrio, Matos; Karolina, Bezerra

2016-05-19

The ever-growing percentage of elderly people in developed countries have made Ambient Assisted Living (AAL) solutions an important subject to be explored and developed. The increase in geriatric care requests are overburdening specialized institutions that cannot cope with the demand for support. Patients are forced to have to remain at their homes encumbering the spouse or close family members with the caregiver role. This caregiver is not always physically and technically apt to assist the bedridden person with his/her meals and hygiene/bath routine. Consequently, a solution to assist caregivers in these tasks is of the utmost importance. This paper presents an approach for supporting caregivers when moving and repositioning Bedridden Elderly Peoples (BEPs) in home settings by means of a mechatronic system inspired by industrial conveyers. The proposed solution is able to insert itself underneath the patient, due to its low-profile structural properties, and retrieve and reallocate him/her. Ideally, the proposed mechatronic system aims to promote autonomy by reducing handling complexity, alter the role of the caregiver from physically handler of the BEP to an operator/supervisor role, and lessen the amount of effort expended by caregivers and BEPs alike.

The Conceptual Design of a Mechatronic System to Handle Bedridden Elderly Individuals

Directory of Open Access Journals (Sweden)

Silva Bruno

2016-05-01

Full Text Available The ever-growing percentage of elderly people in developed countries have made Ambient Assisted Living (AAL solutions an important subject to be explored and developed. The increase in geriatric care requests are overburdening specialized institutions that cannot cope with the demand for support. Patients are forced to have to remain at their homes encumbering the spouse or close family members with the caregiver role. This caregiver is not always physically and technically apt to assist the bedridden person with his/her meals and hygiene/bath routine. Consequently, a solution to assist caregivers in these tasks is of the utmost importance. This paper presents an approach for supporting caregivers when moving and repositioning Bedridden Elderly Peoples (BEPs in home settings by means of a mechatronic system inspired by industrial conveyers. The proposed solution is able to insert itself underneath the patient, due to its low-profile structural properties, and retrieve and reallocate him/her. Ideally, the proposed mechatronic system aims to promote autonomy by reducing handling complexity, alter the role of the caregiver from physically handler of the BEP to an operator/supervisor role, and lessen the amount of effort expended by caregivers and BEPs alike.

The Conceptual Design of a Mechatronic System to Handle Bedridden Elderly Individuals

Science.gov (United States)

Bruno, Silva; José, Machado; Filomena, Soares; Vítor, Carvalho; Demétrio, Matos; Karolina, Bezerra

2016-01-01

The ever-growing percentage of elderly people in developed countries have made Ambient Assisted Living (AAL) solutions an important subject to be explored and developed. The increase in geriatric care requests are overburdening specialized institutions that cannot cope with the demand for support. Patients are forced to have to remain at their homes encumbering the spouse or close family members with the caregiver role. This caregiver is not always physically and technically apt to assist the bedridden person with his/her meals and hygiene/bath routine. Consequently, a solution to assist caregivers in these tasks is of the utmost importance. This paper presents an approach for supporting caregivers when moving and repositioning Bedridden Elderly Peoples (BEPs) in home settings by means of a mechatronic system inspired by industrial conveyers. The proposed solution is able to insert itself underneath the patient, due to its low-profile structural properties, and retrieve and reallocate him/her. Ideally, the proposed mechatronic system aims to promote autonomy by reducing handling complexity, alter the role of the caregiver from physically handler of the BEP to an operator/supervisor role, and lessen the amount of effort expended by caregivers and BEPs alike. PMID:27213383

30 CFR 75.817 - Cable handling and support systems.

Science.gov (United States)

2010-07-01

... High-Voltage Longwalls § 75.817 Cable handling and support systems. Longwall mining equipment must be provided with cable-handling and support systems that are constructed, installed and maintained to minimize... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Cable handling and support systems. 75.817...

Abiotic synthesis of organic compounds from carbon disulfide under hydrothermal conditions.

Science.gov (United States)

Rushdi, Ahmed I; Simoneit, Bernd R T

2005-12-01

Abiotic formation of organic compounds under hydrothermal conditions is of interest to bio, geo-, and cosmochemists. Oceanic sulfur-rich hydrothermal systems have been proposed as settings for the abiotic synthesis of organic compounds. Carbon disulfide is a common component of magmatic and hot spring gases, and is present in marine and terrestrial hydrothermal systems. Thus, its reactivity should be considered as another carbon source in addition to carbon dioxide in reductive aqueous thermosynthesis. We have examined the formation of organic compounds in aqueous solutions of carbon disulfide and oxalic acid at 175 degrees C for 5 and 72 h. The synthesis products from carbon disulfide in acidic aqueous solutions yielded a series of organic sulfur compounds. The major compounds after 5 h of reaction included dimethyl polysulfides (54.5%), methyl perthioacetate (27.6%), dimethyl trithiocarbonate (6.8%), trithianes (2.7%), hexathiepane (1.4%), trithiolanes (0.8%), and trithiacycloheptanes (0.3%). The main compounds after 72 h of reaction consisted of trithiacycloheptanes (39.4%), pentathiepane (11.6%), tetrathiocyclooctanes (11.5%), trithiolanes (10.6%), tetrathianes (4.4%), trithianes (1.2%), dimethyl trisulfide (1.1%), and numerous minor compounds. It is concluded that the abiotic formation of aliphatic straight-chain and cyclic polysulfides is possible under hydrothermal conditions and warrants further studies.

Cooper-Harper Experience Report for Spacecraft Handling Qualities Applications

Science.gov (United States)

Bailey, Randall E.; Jackson, E. Bruce; Bilimoria, Karl D.; Mueller, Eric R.; Frost, Chad R.; Alderete, Thomas S.

2009-01-01

A synopsis of experience from the fixed-wing and rotary-wing aircraft communities in handling qualities development and the use of the Cooper-Harper pilot rating scale is presented as background for spacecraft handling qualities research, development, test, and evaluation (RDT&E). In addition, handling qualities experiences and lessons-learned from previous United States (US) spacecraft developments are reviewed. This report is intended to provide a central location for references, best practices, and lessons-learned to guide current and future spacecraft handling qualities RDT&E.

Cellular Manufacturing System with Dynamic Lot Size Material Handling

Science.gov (United States)

Khannan, M. S. A.; Maruf, A.; Wangsaputra, R.; Sutrisno, S.; Wibawa, T.

2016-02-01

Material Handling take as important role in Cellular Manufacturing System (CMS) design. In several study at CMS design material handling was assumed per pieces or with constant lot size. In real industrial practice, lot size may change during rolling period to cope with demand changes. This study develops CMS Model with Dynamic Lot Size Material Handling. Integer Linear Programming is used to solve the problem. Objective function of this model is minimizing total expected cost consisting machinery depreciation cost, operating costs, inter-cell material handling cost, intra-cell material handling cost, machine relocation costs, setup costs, and production planning cost. This model determines optimum cell formation and optimum lot size. Numerical examples are elaborated in the paper to ilustrate the characterictic of the model.

Handling of Solid Residues

International Nuclear Information System (INIS)

Medina Bermudez, Clara Ines

1999-01-01

The topic of solid residues is specifically of great interest and concern for the authorities, institutions and community that identify in them a true threat against the human health and the atmosphere in the related with the aesthetic deterioration of the urban centers and of the natural landscape; in the proliferation of vectorial transmitters of illnesses and the effect on the biodiversity. Inside the wide spectrum of topics that they keep relationship with the environmental protection, the inadequate handling of solid residues and residues dangerous squatter an important line in the definition of political and practical environmentally sustainable. The industrial development and the population's growth have originated a continuous increase in the production of solid residues; of equal it forms, their composition day after day is more heterogeneous. The base for the good handling includes the appropriate intervention of the different stages of an integral administration of residues, which include the separation in the source, the gathering, the handling, the use, treatment, final disposition and the institutional organization of the administration. The topic of the dangerous residues generates more expectation. These residues understand from those of pathogen type that are generated in the establishments of health that of hospital attention, until those of combustible, inflammable type, explosive, radio-active, volatile, corrosive, reagent or toxic, associated to numerous industrial processes, common in our countries in development

Experimental Research on the Determination of the Coefficient of Sliding Wear under Iron Ore Handling Conditions

Directory of Open Access Journals (Sweden)

G. Chen

2017-09-01

Full Text Available The handling of iron ore bulk solids maintains an increasing trend due to economic development. Because iron ore particles have hard composites and irregular shapes, the bulk solids handling equipment surface can suffer from severe sliding wear. Prediction of equipment surface wear volume is beneficial to the efficient maintenance of worn areas. Archard’s equation provides a theoretical solution to predict wear volume. To use Archard’s equation, the coefficient of sliding wear must be determined. To our best knowledge, the coefficient of sliding wear for iron ore handling conditions has not yet been determined. In this research, using a pin-on-disk tribometer, the coefficients of sliding wear for both Sishen particles and mild steel are determined with regard to iron ore handling conditions. Both naturally irregular and spherical shapes of particles are used to estimate average values of wear rate. Moreover, the hardness and inner structures of Sishen particles are examined, which adds the evidence of the interpretation of wear results. It is concluded that the coefficients of sliding wear can vary largely for both Sishen particle and mild steel. The wear rate decreases from transient- to steady-state. The average coefficient of sliding wear is capable of predicting wear with respect to long distances at the steady-state. Two types of sliding friction are distinguished. In addition, it is found that the temperature rise of the friction pairs has negligible influence on wear rate.

The formation of nitrogeneous compounds in the γ-radiolyses of liquid nitrogen solutions of hydrogen, methane, and ethane

International Nuclear Information System (INIS)

Horigome, Keiichi; Hirokami, Shun-ichi; Sato, Shin

1978-01-01

The γ-radiolyses of liquid nitrogen solutions of hydrogen, methane, and ethane have been reinvestigated. A complete survey of nitrogen-containing products has been attempted. The nitrogeneous compounds observed were ammonia (0.7) and hydrogen azide (0.02) in the case of hydrogen, ammonia (0.3), hydrogen cyanide (0.1), methyl azide (0.01), and a polymer in the case of methane, and ammonia (0.3), hydrogen cyanide (0.05), acetonitrile (0.04), ethyl azide (0.01), and a polymer in the case of ethane. The values in parentheses are the G-values obtained at optimum conditions. The hydrolysis of the polymer obtained with methane gave formaldehyde in amounts which correspond to the fact that the G-value of the nitrogen atoms which were converted into the polymer is about 1.0. In order to explain these results, possible reaction mechanisms are discussed. (auth.)

Repository waste-handling operations, 1998

International Nuclear Information System (INIS)

Cottam, A.E.; Connell, L.

1986-04-01

The Civilian Radioactive Waste Management Program Mission Plan and the Generic Requirements for a Mined Geologic Disposal System state that beginning in 1998, commercial spent fuel not exceeding 70,000 metric tons of heavy metal, or a quantity of solidified high-level radioactive waste resulting from the reprocessing of such a quantity of spent fuel, will be shipped to a deep geologic repository for permanent storage. The development of a waste-handling system that can process 3000 metric tons of heavy metal annually will require the adoption of a fully automated approach. The safety and minimum exposure of personnel will be the prime goals of the repository waste handling system. A man-out-of-the-loop approach will be used in all operations including the receipt of spent fuel in shipping casks, the inspection and unloading of the spent fuel into automated hot-cell facilities, the disassembly of spent fuel assemblies, the consolidation of fuel rods, and the packaging of fuel rods into heavy-walled site-specific containers. These containers are designed to contain the radionuclides for up to 1000 years. The ability of a repository to handle more than 6000 pressurized water reactor spent-fuel rods per day on a production basis for approximately a 23-year period will require that a systems approach be adopted that combines space-age technology, robotics, and sophisticated automated computerized equipment. New advanced inspection techniques, maintenance by robots, and safety will be key factors in the design, construction, and licensing of a repository waste-handling facility for 1998

20 CFR 658.421 - Handling of JS-related complaints.

Science.gov (United States)

2010-04-01

... 20 Employees' Benefits 3 2010-04-01 2010-04-01 false Handling of JS-related complaints. 658.421... ADMINISTRATIVE PROVISIONS GOVERNING THE JOB SERVICE SYSTEM Job Service Complaint System Federal Js Complaint System § 658.421 Handling of JS-related complaints. (a) No JS-related complaint shall be handled at the...

Fuel handling grapple for nuclear reactor plants

International Nuclear Information System (INIS)

Rousar, D.L.

1992-01-01

This patent describes a fuel handling system for nuclear reactor plants. It comprises: a reactor vessel having an openable top and removable cover and containing therein, submerged in water substantially filling the reactor vessel, a fuel core including a multiplicity of fuel bundles formed of groups of sealed tube elements enclosing fissionable fuel assembled into units, the fuel handling system consisting essentially of the combination of: a fuel bundle handling platform movable over the open top of the reactor vessel; a fuel bundle handling mast extendable downward from the platform with a lower end projecting into the open top reactor vessel to the fuel core submerged in water; a grapple head mounted on the lower end of the mast provided with grapple means comprising complementary hooks which pivot inward toward each other to securely grasp a bail handle of a nuclear reactor fuel bundle and pivot backward away from each other to release a bail handle; the grapple means having a hollow cylindrical support shaft fixed within the grapple head with hollow cylindrical sleeves rotatably mounted and fixed in longitudinal axial position on the support shaft and each sleeve having complementary hooks secured thereto whereby each hook pivots with the rotation of the sleeve secured thereto; and the hollow cylindrical support shaft being provided with complementary orifices on opposite sides of its hollow cylindrical and intermediate to the sleeves mounted thereon whereby the orifices on both sides of the hollow cylindrical support shaft are vertically aligned providing a direct in-line optical viewing path downward there-through and a remote operator positioned above the grapple means can observe from overhead the area immediately below the grapple hooks

Dielectric properties of binary solutions a data handbook

CERN Document Server

Akhadov, Y Y

1980-01-01

Dielectric Properties of Binary Solutions focuses on the investigation of the dielectric properties of solutions, as well as the molecular interactions and mechanisms of molecular processes that occur in liquids. The book first discusses the fundamental formulas describing the dielectric properties of liquids and dielectric data for binary systems of non-aqueous solutions. Topics include permittivity and dielectric dispersion parameters of non-aqueous solutions of organic and inorganic compounds. The text also tackles dielectric data for binary systems of aqueous solutions, including permittiv

Money handling influences BMI: a survey of cashiers

OpenAIRE

Shraddha Karve; Ketaki Shurpali; Neelesh Dahanukar; Maithili Jog; Milind Watve

2008-01-01

Money is a recent phenomenon in the evolutionary history of man and therefore no separate brain centre to handle money is likely to have evolved. The brain areas activated by food reward and money reward are extensively overlapping. In an experimental set-up, hunger was demonstrated to influence money related decisions and money related thoughts to influence hunger. This suggests that the brain areas evolved for handling food related emotions are exapted to handle money and therefore there co...

Advanced handling-systems with enhanced performance flexibility

International Nuclear Information System (INIS)

1986-04-01

This report describes the results of a project related to future applications and requirements for advanced handling systems. This report consists of six chapters. Following the description of the aims the tools for setting up the requirements for the handling systems including the experience during the data acquisition process is described. Furthermore some information is given about the current state of the art of robotics and manipulators. Of paramount importance are the descriptions of applications and related concepts in the following chapters leading to specific categories of advanced handling units. The paper closes with the description of the first concepts for realization. (orig./HP) [de

How the NWC handles software as product

Energy Technology Data Exchange (ETDEWEB)

Vinson, D.

1997-11-01

This tutorial provides a hands-on view of how the Nuclear Weapons Complex project should be handling (or planning to handle) software as a product in response to Engineering Procedure 401099. The SQAS has published the document SQAS96-002, Guidelines for NWC Processes for Handling Software Product, that will be the basis for the tutorial. The primary scope of the tutorial is on software products that result from weapons and weapons-related projects, although the information presented is applicable to many software projects. Processes that involve the exchange, review, or evaluation of software product between or among NWC sites, DOE, and external customers will be described.

Conceptual design of CFETR divertor remote handling compatible structure

International Nuclear Information System (INIS)

Dai, Huaichu; Yao, Damao; Cao, Lei; Zhou, Zibo; Li, Lei

2016-01-01

Highlights: • Conceptual design for the CFETR divertor have been proposed, especially the divertor remote handling compatible structure. • The degrees of freedom of the divertor are analyzed in order to validate the design the divertor supports structure. • Besides the ITER-like scheme, a new scheme for the divertor remote handling compatible supports is proposed, that is the rack and pinion mechanism. • The installation/removel process is verified through simulation in Delmia in order to check design quality for remote handling requirements. - Abstract: Divertor is one of key components of tokamak fusion reactor. The CFETR is China Fusion Engineering Test Reactor. Its divertor will expose to tritium environment and neutron radiation. Materials of the divertor will be radioactived, and cannot be handled by personnel directly. To develop structure which compatible with robots handle for installation, maintenance and removing is required. This paper introduces a conceptual design of CFETR divertor module which compatible with remote handling end-effectors. The divertor module is confined by inner and outer support. The inner support is only confined divertor module radial, toroidal and vertical moving freedom degrees, but not confined rotating freedom degrees. The outer support is the structure that can confine rotating freedom degrees and should also be compatible with remote handling end-effectors.

Conceptual design of CFETR divertor remote handling compatible structure

Energy Technology Data Exchange (ETDEWEB)

Dai, Huaichu, E-mail: yaodm@ipp.ac.cn [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); University of Science and Technology of China, Hefei (China); Yao, Damao; Cao, Lei; Zhou, Zibo; Li, Lei [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China)

2016-11-15

Highlights: • Conceptual design for the CFETR divertor have been proposed, especially the divertor remote handling compatible structure. • The degrees of freedom of the divertor are analyzed in order to validate the design the divertor supports structure. • Besides the ITER-like scheme, a new scheme for the divertor remote handling compatible supports is proposed, that is the rack and pinion mechanism. • The installation/removel process is verified through simulation in Delmia in order to check design quality for remote handling requirements. - Abstract: Divertor is one of key components of tokamak fusion reactor. The CFETR is China Fusion Engineering Test Reactor. Its divertor will expose to tritium environment and neutron radiation. Materials of the divertor will be radioactived, and cannot be handled by personnel directly. To develop structure which compatible with robots handle for installation, maintenance and removing is required. This paper introduces a conceptual design of CFETR divertor module which compatible with remote handling end-effectors. The divertor module is confined by inner and outer support. The inner support is only confined divertor module radial, toroidal and vertical moving freedom degrees, but not confined rotating freedom degrees. The outer support is the structure that can confine rotating freedom degrees and should also be compatible with remote handling end-effectors.

21 CFR 58.107 - Test and control article handling.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Test and control article handling. 58.107 Section... GOOD LABORATORY PRACTICE FOR NONCLINICAL LABORATORY STUDIES Test and Control Articles § 58.107 Test and control article handling. Procedures shall be established for a system for the handling of the test and...

9 CFR 2.131 - Handling of animals.

Science.gov (United States)

2010-01-01

... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Handling of animals. 2.131 Section 2.131 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE ANIMAL WELFARE REGULATIONS Miscellaneous § 2.131 Handling of animals. (a) All licensees who maintain wild...

Development of spent fuel remote handling technology

Energy Technology Data Exchange (ETDEWEB)

Park, B. S.; Yoon, J. S.; Hong, H. D. (and others)

2007-02-15

In this research, the remote handling technology was developed for the ACP application. The ACP gives a possible solution to reduce the rapidly cumulative amount of spent fuels generated from the nuclear power plants in Korea. The remote technologies developed in this work are a slitting device, a voloxidizer, a modified telescopic servo manipulator and a digital mock-up. A slitting device was developed to declad the spent fuel rod-cuts and collect the spent fuel UO{sub 2} pellets. A voloxidizer was developed to convert the spent fuel UO{sub 2} pellets obtained from the slitting process in to U{sub 3}O{sub 8} powder. Experiments were performed to test the capabilities and remote operation of the developed slitting device and voloxidizer by using simulated rod-cuts and fuel in the ACP hot cell. A telescopic servo manipulator was redesigned and manufactured improving the structure of the prototype. This servo manipulator was installed in the ACP hot cell, and the target module for maintenance of the process equipment was selected. The optimal procedures for remote operation were made through the maintenance tests by using the servo manipulator. The ACP digital mockup in a virtual environment was established to secure a reliability and safety of remote operation and maintenance. The simulation for the remote operation and maintenance was implemented and the operability was analyzed. A digital mockup about the preliminary conceptual design of an enginnering-scale ACP was established, and an analysis about a scale of facility and remote handling was accomplished. The real-time diagnostic technique was developed to detect the possible fault accidents of the slitting device. An assessment of radiation effect for various sensors was also conducted in the radiation environment.

DEM Solutions Develops Answers to Modeling Lunar Dust and Regolith

Science.gov (United States)

Dunn, Carol Anne; Calle, Carlos; LaRoche, Richard D.

2010-01-01

With the proposed return to the Moon, scientists like NASA-KSC's Dr. Calle are concerned for a number of reasons. We will be staying longer on the planet's surface, future missions may include dust-raising activities, such as excavation and handling of lunar soil and rock, and we will be sending robotic instruments to do much of the work for us. Understanding more about the chemical and physical properties of lunar dust, how dust particles interact with each other and with equipment surfaces and the role of static electricity build-up on dust particles in the low-humidity lunar environment is imperative to the development of technologies for removing and preventing dust accumulation, and successfully handling lunar regolith. Dr. Calle is currently working on the problems of the electrostatic phenomena of granular and bulk materials as they apply to planetary surfaces, particularly to those of Mars and the Moon, and is heavily involved in developing instrumentation for future planetary missions. With this end in view, the NASA Kennedy Space Center's Innovative Partnerships Program Office partnered with OEM Solutions, Inc. OEM Solutions is a global leader in particle dynamics simulation software, providing custom solutions for use in tackling tough design and process problems related to bulk solids handling. Customers in industries such as pharmaceutical, chemical, mineral, and materials processing as well as oil and gas production, agricultural and construction, and geo-technical engineering use OEM Solutions' EDEM(TradeMark) software to improve the design and operation of their equipment while reducing development costs, time-to-market and operational risk. EDEM is the world's first general-purpose computer-aided engineering (CAE) tool to use state-of-the-art discrete element modeling technology for the simulation and analysis of particle handling and manufacturing operations. With EDEM you'can quickly and easily create a parameterized model of your granular solids

ITER L 6 equatorial maintenance duct remote handling study

International Nuclear Information System (INIS)

Millard, J.

1996-09-01

The status and conclusions of a preliminary study of equatorial maintenance duct remote handling is reported. Due to issues with the original duct design a significant portion of the study had to be refocused on equatorial duct layout studies. The study gives an overview of some of the options for design of these ducts and the impact of the design on the equipment to work in the duct. To develop a remote handling concept for creating access through the ducts the following design tasks should be performed: define the operations sequences for equatorial maintenance duct opening and closing; review the remote handling requirements for equatorial maintenance duct opening and closing; design concept for door and pipe handling equipment and to propose preliminary procedures for material handling outsides the duct. 35 figs

A non-differentiable solution for the local fractional telegraph equation

Directory of Open Access Journals (Sweden)

Li Jie

2017-01-01

Full Text Available In this paper, we consider the linear telegraph equations with local fractional derivative. The local fractional Laplace series expansion method is used to handle the local fractional telegraph equation. The analytical solution with the non-differentiable graphs is discussed in detail. The proposed method is efficient and accurate.

Ergonomic design and evaluation of the handle for an endoscopic dissector.

Science.gov (United States)

Shimomura, Yoshihiro; Minowa, Keita; Kawahira, Hiroshi; Katsuura, Tetsuo

2016-05-01

The purpose of this study was to design an endoscopic dissector handle and objectively assess its usability. The handles were designed with increased contact area between the fingers and thumb and the eye rings, and the eye rings were modified to have a more perpendicular insertion angle to the finger midline. Four different handle models were compared, including a conventional product. Subjects performed dissection, exclusion, grasping, precision manipulation and precision handling tasks. Electromyography and subjective evaluations were measured. Compared to conventional handles, the designated handle reduced the muscle load in the extensor and flexor muscles of the forearm and increased subjective stability. The activity of the first dorsal interosseous muscle was sometimes influenced by the shape of the other parts. The ergonomically designed endoscopic dissector handle used in this study achieved high usability. Medical instrument designs based on ergonomic concepts should be assessed with objective indices. Practitioner Summary: The endoscopic dissector handles were designed with increased contact area and more suitable insertion angle between the fingers and thumb and the eye rings. Compared to conventional handles, the designated handle reduced the muscle load in the extensor and flexor muscles of the forearm and increased subjective stability.

Single-molecule mechanics of protein-labelled DNA handles

Directory of Open Access Journals (Sweden)

Vivek S. Jadhav

2016-01-01

Full Text Available DNA handles are often used as spacers and linkers in single-molecule experiments to isolate and tether RNAs, proteins, enzymes and ribozymes, amongst other biomolecules, between surface-modified beads for nanomechanical investigations. Custom DNA handles with varying lengths and chemical end-modifications are readily and reliably synthesized en masse, enabling force spectroscopic measurements with well-defined and long-lasting mechanical characteristics under physiological conditions over a large range of applied forces. Although these chemically tagged DNA handles are widely used, their further individual modification with protein receptors is less common and would allow for additional flexibility in grabbing biomolecules for mechanical measurements. In-depth information on reliable protocols for the synthesis of these DNA–protein hybrids and on their mechanical characteristics under varying physiological conditions are lacking in literature. Here, optical tweezers are used to investigate different protein-labelled DNA handles in a microfluidic environment under different physiological conditions. Digoxigenin (DIG-dsDNA-biotin handles of varying sizes (1000, 3034 and 4056 bp were conjugated with streptavidin or neutravidin proteins. The DIG-modified ends of these hybrids were bound to surface-modified polystyrene (anti-DIG beads. Using different physiological buffers, optical force measurements showed consistent mechanical characteristics with long dissociation times. These protein-modified DNA hybrids were also interconnected in situ with other tethered biotinylated DNA molecules. Electron-multiplying CCD (EMCCD imaging control experiments revealed that quantum dot–streptavidin conjugates at the end of DNA handles remain freely accessible. The experiments presented here demonstrate that handles produced with our protein–DNA labelling procedure are excellent candidates for grasping single molecules exposing tags suitable for molecular

45 CFR 650.19 - Electronic invention handling.

Science.gov (United States)

2010-10-01

... Report or a Final Invention Statement and Certification. (b) Questions on use of iEdison and requests for... 45 Public Welfare 3 2010-10-01 2010-10-01 false Electronic invention handling. 650.19 Section 650... PATENTS § 650.19 Electronic invention handling. (a) Grantees must use the iEdison Invention Information...

An Optimized Small Tissue Handling System for Immunohistochemistry and In Situ Hybridization.

Directory of Open Access Journals (Sweden)

Giovanni Anthony

Full Text Available Recent development in 3D printing technology has opened an exciting possibility for manufacturing 3D devices on one's desktop. We used 3D modeling programs to design 3D models of a tissue-handling system and these models were "printed" in a stereolithography (SLA 3D printer to create precision histology devices that are particularly useful to handle multiple samples with small dimensions in parallel. Our system has been successfully tested for in situ hybridization of zebrafish embryos. Some of the notable features include: (1 A conveniently transferrable chamber with 6 mesh-bottomed wells, each of which can hold dozens of zebrafish embryos. This design allows up to 6 different samples to be treated per chamber. (2 Each chamber sits in a well of a standard 6-well tissue culture plate. Thus, up to 36 different samples can be processed in tandem using a single 6 well plate. (3 Precisely fitting lids prevent solution evaporation and condensation, even at high temperatures for an extended period of time: i.e., overnight riboprobe hybridization. (4 Flat bottom mesh maximizes the consistent treatment of individual tissue samples. (5 A magnet-based lifter was created to handle up to 6 chambers (= 36 samples in unison. (6 The largely transparent resin aids in convenient visual inspection both with eyes and using a stereomicroscope. (7 Surface engraved labeling enables an accurate tracking of different samples. (8 The dimension of wells and chambers minimizes the required amount of precious reagents. (9 Flexible parametric modeling enables an easy redesign of the 3D models to handle larger or more numerous samples. Precise dimensions of 3D models and demonstration of how we use our devices in whole mount in situ hybridization are presented. We also provide detailed information on the modeling software, 3D printing tips, as well as 3D files that can be used with any 3D printer.

Mathematical modeling of solute transport in the subsurface

International Nuclear Information System (INIS)

Naymik, T.G.

1987-01-01

A review of key works on solute transport models indicates that solute transport processes with the exception of advection are still poorly understood. Solute transport models generally do a good job when they are used to test scientific concepts and hypotheses, investigate natural processes, systematically store and manage data, and simulate mass balance of solutes under certain natural conditions. Solute transport models generally are not good for predicting future conditions with a high degree of certainty, or for determining concentrations precisely. The mathematical treatment of solute transport far surpasses their understanding of the process. Investigations of the extent of groundwater contamination and methods to remedy existing problems show the along-term nature of the hazard. Industrial organic compounds may be immiscible in water, highly volatile, or complexed with inorganic as well as other organic compounds; many remain stable in nature almost indefinitely. In the worst case, future disposal of hazardous waste may be restricted to deep burial, as is proposed for radioactive wastes. For investigations pertinent to transport of radionuclides from a geologic repository, the process cannot be fully understood without adequate thermodynamic and kinetic data bases

Procedure to remove dissolved nickel and/or radium compounds from water and facility therefor

International Nuclear Information System (INIS)

Moravec, J.

2004-01-01

Dissolved nickel and/or radium compounds are removed from water on a granular material such as quartz sand, crushed coal or granulated MnO 2 whose surface contains oxides of manganese MnO x . The compounds to be removed are adsorbed into the MnO x layer. Subsequently the adsorbed compounds are desorbed with a reductant, such as sodium sulfite, which is present in a concentration forming a redox potential of -5 to -120 mV, and with a solution of sodium polyphosphate, such as sodium hexametaphosphate (NaPO 3 ) n . Two variants are possible: either MnO x is first acted upon with the reductant and subsequently with the polyphosphate, or a mixed solution of the two agents is used. The excess of the agents is removed with water or with a KMnO 4 solution at 0.001 to 25 g/L. The granular material as well as the agent solutions (after concentration) are reusable. (P.A.)

Hot Laboratories and Remote Handling

International Nuclear Information System (INIS)

2007-01-01

The Opening talk of the workshop 'Hot Laboratories and Remote Handling' was given by Marin Ciocanescu with the communication 'Overview of R and D Program in Romanian Institute for Nuclear Research'. The works of the meeting were structured into three sections addressing the following items: Session 1. Hot cell facilities: Infrastructure, Refurbishment, Decommissioning; Session 2. Waste, transport, safety and remote handling issues; Session 3. Post-Irradiation examination techniques. In the frame of Section 1 the communication 'Overview of hot cell facilities in South Africa' by Wouter Klopper, Willie van Greunen et al, was presented. In the framework of the second session there were given the following four communications: 'The irradiated elements cell at PHENIX' by Laurent Breton et al., 'Development of remote equipment for DUPIC fuel fabrication at KAERI', by Jung Won Lee et al., 'Aspects of working with manipulators and small samples in an αβγ-box, by Robert Zubler et al., and 'The GIOCONDA experience of the Joint Research Centre Ispra: analysis of the experimental assemblies finalized to their safe recovery and dismantling', by Roberto Covini. Finally, in the framework of the third section the following five communications were presented: 'PIE of a CANDU fuel element irradiated for a load following test in the INR TRIGA reactor' by Marcel Parvan et al., 'Adaptation of the pole figure measurement to the irradiated items from zirconium alloys' by Yury Goncharenko et al., 'Fuel rod profilometry with a laser scan micrometer' by Daniel Kuster et al., 'Raman spectroscopy, a new facility at LECI laboratory to investigate neutron damage in irradiated materials' by Lionel Gosmain et al., and 'Analysis of complex nuclear materials with the PSI shielded analytical instruments' by Didier Gavillet. In addition, eleven more presentations were given as posters. Their titles were: 'Presentation of CETAMA activities (CEA analytic group)' by Alain Hanssens et al. 'Analysis of

The ITER EC H and CD Upper Launcher: Analysis of vertical Remote Handling applied to the BSM maintenance

International Nuclear Information System (INIS)

Grossetti, Giovanni; Aiello, Gaetano; Heemskerk, Cock; Elzendoorn, Ben; Geßner, Robby; Koning, Jarich; Meier, Andreas; Ronden, Dennis; Späh, Peter; Scherer, Theo; Schreck, Sabine; Strauß, Dirk; Vaccaro, Alessandro

2013-01-01

This paper deals with Remote Handling activities foreseen on the Blanket Shield Module, the plasma facing component of the ITER Electron Cyclotron Heating and Current Drive Upper Launcher. The maintenance configuration considered here is the Vertical Remote Handling, meaning gravity acting along the launcher radial axis. The plant, where the maintenance under consideration is occurring, is the Hot Cell Facility Work Cell. The study here reported has been carried out within the presently ongoing EFDA Goal Oriented Training program on Remote Handling (GOT-RH), which aims to support ITER activities. This document and its contents have to be considered as part of a more vast RAMI analysis to be developed within the GOT-RH, which aims to maximize the Electron Cyclotron Heating and Current Drive system availability. The Baseline CAD model of the Electron Cyclotron Heating and Current Drive Upper Launcher is currently in its preliminary design phase and does not provide enough details for developing a fully detailed maintenance strategy. Therefore, through a System Engineering approach, a set of assumptions was conceived on the launcher structure, as a basis for development of a Remote Handling strategy. Moreover, to compare different design solutions related to the possibility of integrating a quasi-optical component into the Blanket Shield Module, a Trade-Off was made, and its contents are shown here. The outcome of this System Engineering approach has been formalized into Task Definition Forms whose contents are reported here. The Remote Handling strategy presented in this work will be tested in the near future both through Virtual Reality simulations and through prototype experiments

The ITER EC H and CD Upper Launcher: Analysis of vertical Remote Handling applied to the BSM maintenance

Energy Technology Data Exchange (ETDEWEB)

Grossetti, Giovanni, E-mail: giovanni.grossetti@kit.edu [Karlsruhe Institute of Technology, Association KIT-EURATOM, P.O. Box 3640, D-76021 Karlsruhe (Germany); Aiello, Gaetano [Karlsruhe Institute of Technology, Association KIT-EURATOM, P.O. Box 3640, D-76021 Karlsruhe (Germany); Heemskerk, Cock [Heemskerk Innovative Technology, Merelhof 2, 2172 HZ Sassenheim (Netherlands); Elzendoorn, Ben [FOM Institute DIFFER, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Geßner, Robby [Karlsruhe Institute of Technology, Association KIT-EURATOM, P.O. Box 3640, D-76021 Karlsruhe (Germany); Koning, Jarich [Heemskerk Innovative Technology, Merelhof 2, 2172 HZ Sassenheim (Netherlands); Meier, Andreas [Karlsruhe Institute of Technology, Association KIT-EURATOM, P.O. Box 3640, D-76021 Karlsruhe (Germany); Ronden, Dennis [FOM Institute DIFFER, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Späh, Peter; Scherer, Theo; Schreck, Sabine; Strauß, Dirk; Vaccaro, Alessandro [Karlsruhe Institute of Technology, Association KIT-EURATOM, P.O. Box 3640, D-76021 Karlsruhe (Germany)

2013-10-15

This paper deals with Remote Handling activities foreseen on the Blanket Shield Module, the plasma facing component of the ITER Electron Cyclotron Heating and Current Drive Upper Launcher. The maintenance configuration considered here is the Vertical Remote Handling, meaning gravity acting along the launcher radial axis. The plant, where the maintenance under consideration is occurring, is the Hot Cell Facility Work Cell. The study here reported has been carried out within the presently ongoing EFDA Goal Oriented Training program on Remote Handling (GOT-RH), which aims to support ITER activities. This document and its contents have to be considered as part of a more vast RAMI analysis to be developed within the GOT-RH, which aims to maximize the Electron Cyclotron Heating and Current Drive system availability. The Baseline CAD model of the Electron Cyclotron Heating and Current Drive Upper Launcher is currently in its preliminary design phase and does not provide enough details for developing a fully detailed maintenance strategy. Therefore, through a System Engineering approach, a set of assumptions was conceived on the launcher structure, as a basis for development of a Remote Handling strategy. Moreover, to compare different design solutions related to the possibility of integrating a quasi-optical component into the Blanket Shield Module, a Trade-Off was made, and its contents are shown here. The outcome of this System Engineering approach has been formalized into Task Definition Forms whose contents are reported here. The Remote Handling strategy presented in this work will be tested in the near future both through Virtual Reality simulations and through prototype experiments.

Regulatory process for material handling equipment

International Nuclear Information System (INIS)

Rajendran, S.; Agarwal, Kailash

2017-01-01

Atomic Energy (Factories) Rules (AEFR) 1996, Rule 35 states, 'Thorough inspection and load testing of a Crane shall be done by a Competent Person at least once every 12 months'. To adhere to this rule, BARC Safety Council constituted 'Material Handling Equipment Committee (MHEC)' under the aegis of Conventional Fire and Safety Review Committee (CFSRC) to carry out periodical inspection and certification of Material Handling Equipment (MHE), tools and tackles used in BARC Facilities at Trombay, Tarapur and Kalpakkam

Testing of FFTF fuel handling equipment

International Nuclear Information System (INIS)

Coleman, D.W.; Grazzini, E.D.; Hill, L.F.

1977-07-01

The Fast Flux Test Facility has several manual/computer controlled fuel handling machines which are exposed to severe environments during plant operation but still must operate reliably when called upon for reactor refueling. The test programs for two such machines--the Closed Loop Ex-Vessel Machine and the In-Vessel Handling Machine--are described. The discussion centers on those areas where design corrections or equipment repairs substantiated the benefits of a test program prior to plant operation

PND fuel handling decontamination: facilities and techniques

International Nuclear Information System (INIS)

Pan, R.Y.

1996-01-01

The use of various decontamination techniques and equipment has become a critical part of Fuel Handling maintenance work at Ontario Hydro's Pickering Nuclear Division. This paper presents an overview of the set up and techniques used for decontamination in the PND Fuel Handling Maintenance Facility and the effectiveness of each. (author). 1 tab., 9 figs

On the Partial Analytical Solution of the Kirchhoff Equation

KAUST Repository

Michels, Dominik L.

2015-09-01

We derive a combined analytical and numerical scheme to solve the (1+1)-dimensional differential Kirchhoff system. Here the object is to obtain an accurate as well as an efficient solution process. Purely numerical algorithms typically have the disadvantage that the quality of solutions decreases enormously with increasing temporal step sizes, which results from the numerical stiffness of the underlying partial differential equations. To prevent that, we apply a differential Thomas decomposition and a Lie symmetry analysis to derive explicit analytical solutions to specific parts of the Kirchhoff system. These solutions are general and depend on arbitrary functions, which we set up according to the numerical solution of the remaining parts. In contrast to a purely numerical handling, this reduces the numerical solution space and prevents the system from becoming unstable. The differential Kirchhoff equation describes the dynamic equilibrium of one-dimensional continua, i.e. slender structures like fibers. We evaluate the advantage of our method by simulating a cilia carpet.

On the Partial Analytical Solution of the Kirchhoff Equation

KAUST Repository

Michels, Dominik L.; Lyakhov, Dmitry; Gerdt, Vladimir P.; Sobottka, Gerrit A.; Weber, Andreas G.

2015-01-01

We derive a combined analytical and numerical scheme to solve the (1+1)-dimensional differential Kirchhoff system. Here the object is to obtain an accurate as well as an efficient solution process. Purely numerical algorithms typically have the disadvantage that the quality of solutions decreases enormously with increasing temporal step sizes, which results from the numerical stiffness of the underlying partial differential equations. To prevent that, we apply a differential Thomas decomposition and a Lie symmetry analysis to derive explicit analytical solutions to specific parts of the Kirchhoff system. These solutions are general and depend on arbitrary functions, which we set up according to the numerical solution of the remaining parts. In contrast to a purely numerical handling, this reduces the numerical solution space and prevents the system from becoming unstable. The differential Kirchhoff equation describes the dynamic equilibrium of one-dimensional continua, i.e. slender structures like fibers. We evaluate the advantage of our method by simulating a cilia carpet.

Critical experiments on an enriched uranium solution system containing periodically distributed strong thermal neutron absorbers

International Nuclear Information System (INIS)

Rothe, R.E.

1996-01-01

A series of 62 critical and critical approach experiments were performed to evaluate a possible novel means of storing large volumes of fissile solution in a critically safe configuration. This study is intended to increase safety and economy through use of such a system in commercial plants which handle fissionable materials in liquid form. The fissile solution's concentration may equal or slightly exceed the minimum-critical-volume concentration; and experiments were performed for high-enriched uranium solution. Results should be generally applicable in a wide variety of plant situations. The method is called the 'Poisoned Tube Tank' because strong neutron absorbers (neutron poisons) are placed inside periodically spaced stainless steel tubes which separate absorber material from solution, keeping the former free of contamination. Eight absorbers are investigated. Both square and triangular pitched lattice patterns are studied. Ancillary topics which closely model typical plant situations are also reported. They include the effect of removing small bundles of absorbers as might occur during inspections in a production plant. Not taking the tank out of service for these inspections would be an economic advantage. Another ancillary topic studies the effect of the presence of a significant volume of unpoisoned solution close to the Poisoned Tube Tank on the critical height. A summary of the experimental findings is that boron compounds were excellent absorbers, as expected. This was true for granular materials such as Gerstley Borate and Borax; but it was also true for the flexible solid composed of boron carbide and rubber, even though only thin sheets were used. Experiments with small bundles of absorbers intentionally removed reveal that quite reasonable tanks could be constructed that would allow a few tubes at a time to be removed from the tank for inspection without removing the tank from production service

Emerging role of phenolic compounds as natural food additives in fish and fish products.

Science.gov (United States)

Maqsood, Sajid; Benjakul, Soottawat; Shahidi, Fereidoon

2013-01-01

Chemical and microbiological deteriorations are principal causes of quality loss of fish and fish products during handling, processing, and storage. Development of rancid odor and unpleasant flavor, changes of color and texture as well as lowering nutritional value in fish can be prevented by appropriate use of additives. Due to the potential health hazards of synthetic additives, natural products, especially antioxidants and antimicrobial agents, have been intensively examined as safe alternatives to synthetic compounds. Polyphenols (PP) are the natural antioxidants prevalent in fruits, vegetables, beverages (tea, wine, juices), plants, seaweeds, and some herbs and show antioxidative and antimicrobial activities in different fish and fish products. The use of phenolic compounds also appears to be a good alternative for sulphiting agent for retarding melanosis in crustaceans. Phenolic compounds have also been successfully employed as the processing aid for texture modification of fish mince and surimi. Thus, plant polyphenolic compounds can serve as potential additives for preventing quality deterioration or to retain the quality of fish and fish products.

Uranium hexafluoride handling. Proceedings

Energy Technology Data Exchange (ETDEWEB)

1991-12-31

The United States Department of Energy, Oak Ridge Field Office, and Martin Marietta Energy Systems, Inc., are co-sponsoring this Second International Conference on Uranium Hexafluoride Handling. The conference is offered as a forum for the exchange of information and concepts regarding the technical and regulatory issues and the safety aspects which relate to the handling of uranium hexafluoride. Through the papers presented here, we attempt not only to share technological advances and lessons learned, but also to demonstrate that we are concerned about the health and safety of our workers and the public, and are good stewards of the environment in which we all work and live. These proceedings are a compilation of the work of many experts in that phase of world-wide industry which comprises the nuclear fuel cycle. Their experience spans the entire range over which uranium hexafluoride is involved in the fuel cycle, from the production of UF{sub 6} from the naturally-occurring oxide to its re-conversion to oxide for reactor fuels. The papers furnish insights into the chemical, physical, and nuclear properties of uranium hexafluoride as they influence its transport, storage, and the design and operation of plant-scale facilities for production, processing, and conversion to oxide. The papers demonstrate, in an industry often cited for its excellent safety record, continuing efforts to further improve safety in all areas of handling uranium hexafluoride. Selected papers were processed separately for inclusion in the Energy Science and Technology Database.

A multi-component patient-handling intervention improves attitudes and behaviors for safe patient handling and reduces aggression experienced by nursing staff

DEFF Research Database (Denmark)

Risør, Bettina Wulff; Casper, Sven Dalgas; Andersen, Lars L.

2017-01-01

This study evaluated an intervention for patient-handling equipment aimed to improve nursing staffs' use of patient handling equipment and improve their general health, reduce musculoskeletal problems, aggressive episodes, days of absence and work-related accidents. As a controlled before......-after study, questionnaire data were collected at baseline and 12-month follow-up among nursing staff at intervention and control wards at two hospitals. At 12-month follow-up, the intervention group had more positive attitudes towards patient-handling equipment and increased use of specific patient......-handling equipment. In addition, a lower proportion of nursing staff in the intervention group had experienced physically aggressive episodes. No significant change was observed in general health status, musculoskeletal problems, days of absence or work-related accidents. The intervention resulted in more positive...

PND fuel handling decontamination: facilities and techniques

Energy Technology Data Exchange (ETDEWEB)

Pan, R Y [Ontario Hydro, Toronto, ON (Canada)

1997-12-31

The use of various decontamination techniques and equipment has become a critical part of Fuel Handling maintenance work at Ontario Hydro`s Pickering Nuclear Division. This paper presents an overview of the set up and techniques used for decontamination in the PND Fuel Handling Maintenance Facility and the effectiveness of each. (author). 1 tab., 9 figs.

A combined constraint handling framework: an empirical study

DEFF Research Database (Denmark)

Si, Chengyong; Hu, Junjie; Lan, Tian

2017-01-01

This paper presents a new combined constraint handling framework (CCHF) for solving constrained optimization problems (COPs). The framework combines promising aspects of different constraint handling techniques (CHTs) in different situations with consideration of problem characteristics. In order...

Novel Data Mining Methods for Virtual Screening of Biological Active Chemical Compounds

KAUST Repository

Soufan, Othman M.

2016-11-23

Drug discovery is a process that takes many years and hundreds of millions of dollars to reveal a confident conclusion about a specific treatment. Part of this sophisticated process is based on preliminary investigations to suggest a set of chemical compounds as candidate drugs for the treatment. Computational resources have been playing a significant role in this part through a step known as virtual screening. From a data mining perspective, availability of rich data resources is key in training prediction models. Yet, the difficulties imposed by big expansion in data and its dimensionality are inevitable. In this thesis, I address the main challenges that come when data mining techniques are used for virtual screening. In order to achieve an efficient virtual screening using data mining, I start by addressing the problem of feature selection and provide analysis of best ways to describe a chemical compound for an enhanced screening performance. High-throughput screening (HTS) assays data used for virtual screening are characterized by a great class imbalance. To handle this problem of class imbalance, I suggest using a novel algorithm called DRAMOTE to narrow down promising candidate chemicals aimed at interaction with specific molecular targets before they are experimentally evaluated. Existing works are mostly proposed for small-scale virtual screening based on making use of few thousands of interactions. Thus, I propose enabling large-scale (or big) virtual screening through learning millions of interaction while exploiting any relevant dependency for a better accuracy. A novel solution called DRABAL that incorporates structure learning of a Bayesian Network as a step to model dependency between the HTS assays, is showed to achieve significant improvements over existing state-of-the-art approaches.

Experience of safety and performance improvement for fuel handling equipment

International Nuclear Information System (INIS)

Gyoon Chang, Sang; Hee Lee, Dae

2014-01-01

The purpose of this study is to provide experience of safety and performance improvement of fuel handling equipment for nuclear power plants in Korea. The fuel handling equipment, which is used as an important part of critical processes during the refueling outage, has been improved to enhance safety and to optimize fuel handling procedures. Results of data measured during the fuel reloading are incorporated into design changes. The safety and performance improvement for fuel handling equipment could be achieved by simply modifying the components and improving the interlock system. The experience provided in this study can be useful lessons for further improvement of the fuel handling equipment. (authors)

Neonatal handling induces anovulatory estrous cycles in rats

Directory of Open Access Journals (Sweden)

Gomes C.M.

1999-01-01

Full Text Available Since previous work has shown that stimulation early in life decreases sexual receptiveness as measured by the female lordosis quotient, we suggested that neonatal handling could affect the function of the hypothalamus-pituitary-gonadal axis. The effects of neonatal handling on the estrous cycle and ovulation were analyzed in adult rats. Two groups of animals were studied: intact (no manipulation, N = 10 and handled (N = 11. Pups were either handled daily for 1 min during the first 10 days of life or left undisturbed. At the age of 90 days, a vaginal smear was collected daily at 9:00 a.m. and analyzed for 29 days; at 9:00 a.m. on the day of estrus, animals were anesthetized with thiopental (40 mg/kg, ip, the ovaries were removed and the oviduct was dissected and squashed between 2 glass slides. The number of oocytes of both oviductal ampullae was counted under the microscope. The average numbers for each phase of the cycle (diestrus I, diestrus II, proestrus and estrus during the period analyzed were compared between the two groups. There were no significant differences between intact and handled females during any of the phases. However, the number of handled females that showed anovulatory cycles (8 out of 11 was significantly higher than in the intact group (none out of 10. Neonatal stimulation may affect not only the hypothalamus-pituitary-adrenal axis, as previously demonstrated, but also the hypothalamus-pituitary-gonadal axis in female rats.

Effective Teaching Practices in Handling Non Readers

Directory of Open Access Journals (Sweden)

Jacklyn S. Dacalos

2016-08-01

Full Text Available The study determined the effective teaching practices in handling nonreaders. This seeks to answer the following objectives: describe the adjustments, effective strategies, and scaffolds utilized by teachers in handling nonreaders; differentiate the teachers’ reading adjustments, strategies and scaffolds in teaching nonreaders; analyze the teaching reading efficiency of nonreaders using effective teaching reading strategies; and find significant correlation of nonreaders’ grades and reading teachers’ reading adjustments, strategies and scaffolds. This study utilized mixed methods of research. Case studies of five public schools teachers were selected as primary subjects, who were interviewed in handling nonreaders in the areas of adjustments, strategies, and reading scaffolds. Actual teaching observation was conducted according to the five subjects’ most convenient time. In ascertaining the nonreaders’ academic performance, the students’ grades in English subject was analyzed using T-Test within subject design. Handling nonreaders in order to read and understand better in the lesson is an arduous act, yet; once done with effectiveness and passion, it yielded a great amount of learning success. Effective teaching practices in handling nonreaders comprised the use of teachers’ adjustments, strategies, and scaffolds to establish reading mastery, exposing them to letter sounds, short stories, and the use of follow-up. WH questions enhanced their reading performance significantly. Variations of reading teachers’ nature as: an enabler, a facilitator, a humanist, a behaviorist, and an expert, as regards to their teaching practices, were proven significant to students’ reading effectiveness.

The training for nuclear fuel handling at EDF

International Nuclear Information System (INIS)

Marion, J.P.

1999-01-01

The handling of fuel assemblies in a nuclear power plant presents 3 types of work: the taking delivery of fresh fuel, the refueling and the disposal of spent fuel. These operations are realized by teams made up of 3 handling operators and a supervisor. The refueling is made by 3*8-hour teams. These handling operations are important for the nuclear safety, a mishandling can damage the fuel cladding which is the first containment barrier, so a training center (CETIC) has been created. This center was founded in 1986 by EDF and Framatome, the purpose was to validate maintenance procedures, to test handling equipment and to train the teams which work on site. Various training programmes have been set up and a system of qualification degrees has been organized. The CETIC is fitted up with equipment that are full-sized mockups of real installations. Fuel assemblies don't react in a similar way to the different mechanical and neutronic stresses they undergo while they are in the core, they get deformed and the handling operations become more delicate. The mockup fuel assemblies are quite deformed to train the teams and prepare them to face any real situation. (A.C.)

A Rule-Based Local Search Algorithm for General Shift Design Problems in Airport Ground Handling

DEFF Research Database (Denmark)

Clausen, Tommy

We consider a generalized version of the shift design problem where shifts are created to cover a multiskilled demand and fit the parameters of the workforce. We present a collection of constraints and objectives for the generalized shift design problem. A local search solution framework with mul......We consider a generalized version of the shift design problem where shifts are created to cover a multiskilled demand and fit the parameters of the workforce. We present a collection of constraints and objectives for the generalized shift design problem. A local search solution framework...... with multiple neighborhoods and a loosely coupled rule engine based on simulated annealing is presented. Computational experiments on real-life data from various airport ground handling organization show the performance and flexibility of the proposed algorithm....

Human factors issues in fuel handling

International Nuclear Information System (INIS)

Beattie, J.D.; Iwasa-Madge, K.M.; Tucker, D.A.

1994-01-01

The staff of the Atomic Energy Control Board wish to further their understanding of human factors issues of potential concern associated with fuel handling in CANDU nuclear power stations. This study contributes to that objective by analysing the role of human performance in the overall fuel handling process at Ontario Hydro's Darlington Nuclear Generating Station, and reporting findings in several areas. A number of issues are identified in the areas of design, operating and maintenance practices, and the organizational and management environment

Development of high intensity beam handling system, 4

International Nuclear Information System (INIS)

Yamanoi, Yutaka; Tanaka, Kazuhiro; Minakawa, Michifumi

1992-01-01

We have constructed the new counter experimental hall at the KEK 12 GeV Proton Synchrotron (KEK-PS) in order to handle high intensity primary proton beams of up to 1x10 3 pps (protons per second), which is one order of magnitude greater than the present beam intensity of the KEK-PS, 1x10 12 pps. New technologies for handling high-intensity beams have, then, been developed and employed in the construction of the new hall. A part of our R/D work on handling high intensity beams will be reported. (author)

Structure of diphosphine complexes of Co(II) in solutions of organic compounds

International Nuclear Information System (INIS)

Saraev, V.V.; Mandyuk, I.M.; Ratovskii, G.V.; Dmitrieva, T.V.; Shmidt, F.K.

1987-01-01

The structure of the dichloride complexes of cobalt(II) with 1,2-bis(diphenylphosphino)ethane (DPPE) and 1,1-bis(diphenylphosphino)methane (DPPM) in organic solvents has been investigated by ESR and electronic spectroscopy. It has been shown that the low-spin complex Co(DPPE) 2 Cl 2 exists in dichloroethane and ethanol solutions in the form of a trigonal bipyramid. Cobalt dichloride reacts with DPPM to form 1:1 and 1:2 complexes, between which there is an equilibrium in a dichloroethane solution. The equilibrium is displaced under the action of the free diphosphine toward the formation of the 1:2 complex. Elimination of the diphosphine from the coordination sphere of cobalt occurs in an ethanol solution

Certain Aliphatic Nitramines and Related Compounds

Science.gov (United States)

1944-11-29

compounds are ruite unstable. It has beer , impossible to prepare N-iodcmifcramines by any synthesis thus far attempted and the N-bromonitramines...end of tb’f. tine the solution v;as soured over 1500 g. of crac3:cd ice end neutralised with about GOO z» ot sodium bicarbonate. After extraction

Electrical Conductivity and Chemical Composition of Soil Solution: Comparison of Solution Samplers in Tropical Soils

Directory of Open Access Journals (Sweden)

Davi Lopes do Carmo

2016-01-01

Full Text Available ABSTRACT Soil solution samplers may have the same working principle, but they differ in relation to chemical and physical characteristics, cost and handling, and these aspects exert influence on the chemical composition of the soil solution obtained. This study was carried out to evaluate, over time, the chemical composition of solutions extracted by Suolo Acqua, with the hydrophilic membrane (HM as a standard, using soils with contrasting characteristics, and to determine the relationship between electrical conductivity (EC and concentration of ions and pH of soil solution samples. This study was carried out under laboratory conditions, using three soils samples with different clay and organic matter (OM contents. Soil solution contents of F−, Cl−, NO−3, Br−, SO42−, Na+, NH4+, K+, Mg2+, Ca2+, were analyzed, as well as inorganic, organic, and total C contents, pH, and EC, in four successive sampling times. Soil solution chemical composition extracted by the Suolo Acqua sampler is similar to that collected by the HM, but the Suolo Acqua extracted more Na+ and soluble organic C than the HM solution. Solution EC, cation and anion concentrations, and soluble C levels are higher in the soil with greater clay and OM contents (Latossolo and Cambissolo in this case. Soil solution composition varied over time, with considerable changes in pH, EC, and nutrient concentrations, especially associated with soil OM. Thus, single and isolated sampling of the soil solution must be avoided, otherwise composition of the soil solution may not be correctly evaluated. Soil solution EC was regulated by pH, as well as the sum of cation and anion concentrations, and the C contents determined in the soil liquid phase.

New solutions of the generalized ellipsoidal wave equation

Directory of Open Access Journals (Sweden)

Harold Exton

1999-10-01

Full Text Available Certain aspects and a contribution to the theory of new forms of solutions of an algebraic form of the generalized ellipsoidal wave equation are deduced by considering the Laplace transform of a soluble system of linear differential equations. An ensuing system of non-linear algebraic equations is shown to be consistent and is numerically implemented by means of the computer algebra package MAPLE V. The main results are presented as series of hypergeometric type of there and four variables which readily lend themselves to numerical handling although this does not indicate all of the detailedanalytic properties of the solutions under consideration.

Execution Constraint Verification of Exception Handling on UML Sequence Diagrams

NARCIS (Netherlands)

Ciraci, S.; Sözer, Hasan; Aksit, Mehmet; Havinga, W.K.

2011-01-01

Exception handling alters the control flow of the program. As such, errors introduced in exception handling code may influence the overall program in undesired ways. To detect such errors early and thereby decrease the programming costs, it is worthwhile to consider exception handling at design

Pulse radiolysis of catalase in solution: Pt. 1

International Nuclear Information System (INIS)

Gebicka, Lidia; Metodiewa, Diana; Gebicki, J.L.

1989-01-01

The time-course of absorption changes of oxygen-saturated solutions of bovine-liver catalase after pulse radiolysis have been studied. The rate constant of formation of Compound I due to the reaction of catalase with hydrogen peroxide has been estimated to be 2.0 x 10 7 dm 3 mol -1 s -1 . Radiation generated super-oxide radicals reduce Compound I to Compound II with a rate constant of 5.0 x 10 6 dm 3 mol -1 s -1 . The formation of Compound III in the direct reaction of O 2 - with catalase has also been observed. (author)

Simulating and visualizing deflections of a remote handling mechanism

International Nuclear Information System (INIS)

Saarinen, Hannu; Hämäläinen, Vesa; Karjalainen, Jaakko; Määttä, Timo; Siuko, Mikko; Esqué, Salvador; Hamilton, David

2013-01-01

Highlights: ► An infinitesimal transformation represents elastic deflections. ► Equivalent spring factor is used to combine several deformations. ► Initial VR model accuracy improved from 80 to 5 mm. ► The deflection model is capable of adapting to changes in load at the end-effector. ► The algorithms and approach described are generic and can be adopted for other mechanisms. -- Abstract: Continuing ITER divertor second cassette (SC) remote handling (RH) test campaign has been carried out at divertor test platform (DTP2) in Finland. One of the goals has been to develop and implement efficient algorithms and software tools for simulating and visualizing for the operator the non-instrumented deflections of the RH mechanisms under loading conditions. Based on assumptions of the classical beam theory, the presented solution suggests utilization of an infinitesimal transformation to represent elastic deflections in a mechanical structure. Both structural analysis and measurements of the real structure are utilised during the process. The solution suggests one possible implementation strategy of a software component called structural simulator (SS), which is a software component of the remote handling control system (RHCS) architectural model specified by ITER organisation. Utilisation of the proposed SS necessitates modification of the initial virtual reality (VR) model of RH equipment to a format, which can visually represent the structural deflections. In practise this means adding virtual joints into the model. This will improve the accuracy of the VR visualization and will ensure that the virtual representation of the RH equipment closely aligns with the actual RH equipment. Cassette multifunctional mover (CMM) and second cassette end effector (SCEE) carrying SC were selected to be the initial target system for developing the approach. Demonstrations proved that the approach used can give high levels of accuracy even in complex structures such as the CMM

Simulating and visualizing deflections of a remote handling mechanism

Energy Technology Data Exchange (ETDEWEB)

Saarinen, Hannu, E-mail: hannu.saarinen@vtt.fi [VTT, Technical Research Centre of Finland, Tekniikankatu 1, 33720 Tampere (Finland); Hämäläinen, Vesa; Karjalainen, Jaakko; Määttä, Timo; Siuko, Mikko [VTT, Technical Research Centre of Finland, Tekniikankatu 1, 33720 Tampere (Finland); Esqué, Salvador [Fusion for Energy, Torres Diagonal Litoral B3, Josep Pla 2, 08019 Barcelona (Spain); Hamilton, David [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul Lez Durance (France)

2013-10-15

Highlights: ► An infinitesimal transformation represents elastic deflections. ► Equivalent spring factor is used to combine several deformations. ► Initial VR model accuracy improved from 80 to 5 mm. ► The deflection model is capable of adapting to changes in load at the end-effector. ► The algorithms and approach described are generic and can be adopted for other mechanisms. -- Abstract: Continuing ITER divertor second cassette (SC) remote handling (RH) test campaign has been carried out at divertor test platform (DTP2) in Finland. One of the goals has been to develop and implement efficient algorithms and software tools for simulating and visualizing for the operator the non-instrumented deflections of the RH mechanisms under loading conditions. Based on assumptions of the classical beam theory, the presented solution suggests utilization of an infinitesimal transformation to represent elastic deflections in a mechanical structure. Both structural analysis and measurements of the real structure are utilised during the process. The solution suggests one possible implementation strategy of a software component called structural simulator (SS), which is a software component of the remote handling control system (RHCS) architectural model specified by ITER organisation. Utilisation of the proposed SS necessitates modification of the initial virtual reality (VR) model of RH equipment to a format, which can visually represent the structural deflections. In practise this means adding virtual joints into the model. This will improve the accuracy of the VR visualization and will ensure that the virtual representation of the RH equipment closely aligns with the actual RH equipment. Cassette multifunctional mover (CMM) and second cassette end effector (SCEE) carrying SC were selected to be the initial target system for developing the approach. Demonstrations proved that the approach used can give high levels of accuracy even in complex structures such as the CMM

7 CFR 1924.259 - Handling dwelling construction complaints.

Science.gov (United States)

2010-01-01

... 7 Agriculture 12 2010-01-01 2010-01-01 false Handling dwelling construction complaints. 1924.259 Section 1924.259 Agriculture Regulations of the Department of Agriculture (Continued) RURAL HOUSING... Construction Defects § 1924.259 Handling dwelling construction complaints. This section describes the procedure...

CANDU-9/480-SEU fuel handling system assessment document

International Nuclear Information System (INIS)

Hwang, Jeong Ki; Jo, C. H.; Kim, H. M.; Morikawa, D. T.

1996-11-01

This report summarize the rationale for the CANDU 9 fuel handling system, and the design choices recommended for components of the system. Some of the design requirements applicable to the CANDU 9 480-SEU fuel handling design choices are described. These requirements imposed by the CANDU 9 project. And the design features for the key components of fuel handling system, such as the fuelling machine, the carriage, the new fuel transfer system and the irradiated fuel transfer system, are described. The carriage seismic load evaluations relevant to the design are contained in the appendices. The majority of the carriage components are acceptable, or will likely be acceptable with some redesign. The concept for the CANDU 9 fuel handling system is based on proven CANDU designs, or on improved CANDU technology. Although some development work must be done, the fuel handling concept is judged to be feasible for the CANDU 9 480-SEU reactor. (author). 2 refs

MDMA ('Ecstasy'), oxytocin and vasopressin modulate social preference in rats: A role for handling and oxytocin receptors.

Science.gov (United States)

Ramos, Linnet; Hicks, Callum; Caminer, Alex; Couto, Kalliu; Narlawar, Rajeshwar; Kassiou, Michael; McGregor, Iain S

In laboratory rats, peripheral administration of the neuropeptides oxytocin (OT) and vasopressin (AVP) induces similar prosocial effects (i.e. increased adjacent lying) to the party drug 3,4-methylenedioxymethamphetamine (MDMA), which are sensitive to vasopressin V 1A receptor (V 1A R) antagonism. Here, we employed a social preference paradigm to further compare the prosocial effects of OT, AVP and MDMA. We also investigated the possible involvement of the V 1A R and oxytocin receptor (OTR) in rodent social preference. The social preference paradigm measures investigation times towards an empty wire cage (presented for 4min) followed by an identical cage containing a novel rat (also presented for 4min). Social preference is defined as greater investigation time towards the inhabited cage than the empty cage. Results indicated that well-handled rats exhibited no social preference at baseline, while intraperitoneally injected MDMA (5mg/kg), OT (0.5mg/kg) and AVP (0.005mg/kg) increased social preference. However, this effect was primarily due to reduced investigation of the empty cage. In contrast, rats that received minimal prior handling displayed a social preference at baseline, while MDMA (5mg/kg), OT (0.5mg/kg) and AVP (0.005mg/kg) reduced investigation times towards both the empty and inhabited cages. Lower doses of MDMA, OT and AVP were ineffective. The OTR antagonist Compound 25 (C25, 5mg/kg), but not the V 1A R antagonist SR49059 (1mg/kg), reduced the baseline social preference seen in minimally-handled rats and prevented the social preference induced by OT and AVP (but not MDMA) in well-handled rats. Overall, these results further confirm prosocial actions of MDMA, OT and AVP, which are dependent on handling history. These findings also indicate that social preference is sensitive to OTR rather than V 1A R modulation. Copyright © 2016 Elsevier Inc. All rights reserved.

Player-Specific Conflict Handling Ontology

Directory of Open Access Journals (Sweden)

Charline Hondrou

2014-09-01

Full Text Available This paper presents an ontology that leads the player of a serious game - regarding conflict handling - to the educative experience from which they will benefit the most. It provides a clearly defined tree of axioms that maps the player’s visually manifested affective cues and emotional stimuli from the serious game to conflict handling styles and proposes interventions. The importance of this ontology lies in the fact that it promotes natural interaction (non-invasive methods and at the same time makes the game as player-specific as it can be for its educational goal. It is an ontology that can be adapted to different educational theories and serve various educational purposes.

340 Waste Handling Facility interim safety basis

International Nuclear Information System (INIS)

Bendixsen, R.B.

1995-01-01

This document establishes the interim safety basis (ISB) for the 340 Waste Handling Facility (340 Facility). An ISB is a documented safety basis that provides a justification for the continued operation of the facility until an upgraded final safety analysis report is prepared that complies with US Department of Energy (DOE) Order 5480.23, Nuclear Safety Analysis Reports. The ISB for the 340 Facility documents the current design and operation of the facility. The 340 Facility ISB (ISB-003) is based on a facility walkdown and review of the design and operation of the facility, as described in the existing safety documentation. The safety documents reviewed, to develop ISB-003, include the following: OSD-SW-153-0001, Operating Specification Document for the 340 Waste Handling Facility (WHC 1990); OSR-SW-152-00003, Operating Limits for the 340 Waste Handling Facility (WHC 1989); SD-RE-SAP-013, Safety Analysis Report for Packaging, Railroad Liquid Waste Tank Cars (Mercado 1993); SD-WM-TM-001, Safety Assessment Document for the 340 Waste Handling Facility (Berneski 1994a); SD-WM-SEL-016, 340 Facility Safety Equipment List (Berneski 1992); and 340 Complex Fire Hazard Analysis, Draft (Hughes Assoc. Inc. 1994)

Modern materials based on refractory compounds

International Nuclear Information System (INIS)

Kosolapova, T.Ya.

1979-01-01

Discussed are the existing methods for synthesizing powders of binary refractory compounds and high-productivity techniques which hold promise as regards the manufacture of highly disperse and pure powders. Plasmochemical synthesis is shown to be an effective method for obtaining practically all carbides, nitrides and borides. A description is given of three main methods for obtaining single crystals of refractory compounds (TiN, TiC, ZrC, ZrB 2 , NbC) fairly perfect in structure and composition. These processes include deposition from vapour-gas phase, melting in arc plasma and crystallization from solutions in metallic melts. The advantages have been shown of the self-propagating high-temperature synthesis of refractory compounds, ensuring the manufacture of products, close in composition to stoichiometric ones simultaneously with forming of items. Mechanical, thermal, abrasive, and resistive characteristics of the above materials are presented

Synthesis and structural characterization of actinide oxalate compounds

International Nuclear Information System (INIS)

Tamain, C.

2011-01-01

Oxalic acid is a well-known reagent to recover actinides thanks to the very low solubility of An(IV) and An(III) oxalate compounds in acidic solution. Therefore, considering mixed-oxide fuel or considering minor actinides incorporation in ceramic fuel materials for transmutation, oxalic co-conversion is convenient to synthesize mixed oxalate compounds, precursors of oxide solid solutions. As the existing oxalate single crystal syntheses are not adaptable to the actinide-oxalate chemistry or to their manipulation constrains in gloves box, several original crystal growth methods were developed. They were first validate and optimized on lanthanides and uranium before the application to transuranium elements. The advanced investigations allow to better understand the syntheses and to define optimized chemical conditions to promote crystal growth. These new crystal growth methods were then applied to a large number of mixed An1(IV)-An2(III) or An1(IV)-An2(IV) systems and lead to the formation of the first original mixed An1(IV)-An2(III) and An1(IV)-An2(IV) oxalate single crystals. Finally thanks to the first thorough structural characterizations of these compounds, single crystal X-ray diffraction, EXAFS or micro-RAMAN, the particularly weak oxalate-actinide compounds structural database is enriched, which is essential for future studied nuclear fuel cycles. (author) [fr

ITER - torus vacuum pumping system remote handling issues

International Nuclear Information System (INIS)

Stringer, J.

1992-11-01

This report describes further design issues concerning remote maintenance of torus vacuum pumping systems options for ITER. The key issues under investigation in this report are flask support systems for valve seal exchange operations for the compound cryopump scheme and remote maintenance of a proposed multiple turbomolecular pump (TMP) system, an alternative ITER torus exhaust pumping option. Previous studies have shown that the overhead support methods for seal exchange flask equipment could malfunction due to valve/flask misalignment. A floor-mounted support system is described in this report. This scheme provides a more rigid support system for seal exchange operations. An alternative torus pumping system, based on the use of multiple TMPs, is studied from a remote maintenance standpoint. In this concept, centre distance spacing for pump/valve assemblies is too restrictive for remote maintenance. Recommendations are made for adequate spacing of these assemblies based on commercially-available 0.8 m and 1.0 m diameter valves. Fewer pumps will fit in this arrangement, which implies a need for larger TMPs. Pumps of this size are not commercially available. Other concerns regarding the servicing and storage of remote handling equipment in cells are also identified. (9 figs.)

Efficiency Evaluation of Handling of Geologic-Geophysical Information by Means of Computer Systems

Science.gov (United States)

Nuriyahmetova, S. M.; Demyanova, O. V.; Zabirova, L. M.; Gataullin, I. I.; Fathutdinova, O. A.; Kaptelinina, E. A.

2018-05-01

Development of oil and gas resources, considering difficult geological, geographical and economic conditions, requires considerable finance costs; therefore their careful reasons, application of the most perspective directions and modern technologies from the point of view of cost efficiency of planned activities are necessary. For ensuring high precision of regional and local forecasts and modeling of reservoirs of fields of hydrocarbonic raw materials, it is necessary to analyze huge arrays of the distributed information which is constantly changing spatial. The solution of this task requires application of modern remote methods of a research of the perspective oil-and-gas territories, complex use of materials remote, nondestructive the environment of geologic-geophysical and space methods of sounding of Earth and the most perfect technologies of their handling. In the article, the authors considered experience of handling of geologic-geophysical information by means of computer systems by the Russian and foreign companies. Conclusions that the multidimensional analysis of geologicgeophysical information space, effective planning and monitoring of exploration works requires broad use of geoinformation technologies as one of the most perspective directions in achievement of high profitability of an oil and gas industry are drawn.

Remote handling technology for nuclear fuel cycle facilities

International Nuclear Information System (INIS)

Sakai, Akira; Maekawa, Hiromichi; Ohmura, Yutaka

1997-01-01

Design and R and D on nuclear fuel cycle facilities has intended development of remote handling and maintenance technology since 1977. IHI has completed the design and construction of several facilities with remote handling systems for Power Reactor and Nuclear Fuel Development Corporation (PNC), Japan Atomic Energy Research Institute (JAERI), and Japan Nuclear Fuel Ltd. (JNFL). Based on the above experiences, IHI is now undertaking integration of specific technology and remote handling technology for application to new fields such as fusion reactor facilities, decommissioning of nuclear reactors, accelerator testing facilities, and robot simulator-aided remote operation systems in the future. (author)

Solid waste handling

International Nuclear Information System (INIS)

Parazin, R.J.

1995-01-01

This study presents estimates of the solid radioactive waste quantities that will be generated in the Separations, Low-Level Waste Vitrification and High-Level Waste Vitrification facilities, collectively called the Tank Waste Remediation System Treatment Complex, over the life of these facilities. This study then considers previous estimates from other 200 Area generators and compares alternative methods of handling (segregation, packaging, assaying, shipping, etc.)

Mars Sample Handling Functionality

Science.gov (United States)

Meyer, M. A.; Mattingly, R. L.

2018-04-01

The final leg of a Mars Sample Return campaign would be an entity that we have referred to as Mars Returned Sample Handling (MRSH.) This talk will address our current view of the functional requirements on MRSH, focused on the Sample Receiving Facility (SRF).

Remote handling demonstration of ITER blanket module replacement

International Nuclear Information System (INIS)

Kakudate, S.; Nakahira, M.; Oka, K.; Taguchi, K.; Obara, K.; Tada, E.; Shibanuma, K.; Tesini, A.; Haange, R.; Maisonnier, D.

2001-01-01

In ITER, the in-vessel components such as blanket are to be maintained or replaced remotely since they will be activated by 14 MeV neutrons, and a complete exchange of shielding blanket with breeding blanket is foreseen after the Basic Performance Phase. The blanket is segmented into about seven hundred modules to facilitate remote maintainability and allow individual module replacement. For this, the remote handing equipment for blanket maintenance is required to handle a module with a dead weight of about 4 tonne within a positioning accuracy of a few mm under intense gamma radiation. According to the ITER R and D program, a rail-mounted vehicle manipulator system was developed and the basic feasibility of this system was verified through prototype testing. Following this, development of full-scale remote handling equipment has been conducted as one of the ITER Seven R and D Projects aiming at a remote handling demonstration of the ITER blanket. As a result, the Blanket Test Platform (BTP) composed of the full-scale remote handling equipment has been completed and the first integrated performance test in March 1998 has shown that the fabricate remote handling equipment satisfies the main requirements of ITER blanket maintenance. (author)

Cobalt, nickel and cadmium coordination compounds with phenylacetylhydrazine

Energy Technology Data Exchange (ETDEWEB)

Machkhoshvili, R.I.; Metreveli, D.P.; Mitaishvili, G.Sh.; Shchelokov, R.N.

1985-03-01

In the process of interaction of aqueous-ethanol solutions of chlorides, sulphates, nitrates, thiocyanates of cobalt, nickel, cadmium and phenylacetylhydrazine in neutral or low-acid medium coordination compounds: (M(EAG)/sub 3/)X/sub 2/ (M=Co, Ni; X=Cl, 1/2SO/sub 4/, NO/sub 3/), Cd(FAG)/sub 2/X/sub 2/ (X = Cl, 1/2SO/sub 4/, NCS), Ni(EAG)/sub 2/(NCS)/sub 2/, where FAG C/sub 6/H/sub 5/CH/sub 2/xCONHNH/sub 2/, have been synthesized. In the reactions of aqueous-ethanol solutions of (Co(NH/sub 3/)/sub 5/Cl)Cl/sub 2/ and phenylacetylhydrazine the complex Co(C/sub 6/H/sub 5/CH/sub 2/CONNH/sub 2/)/sub 3/ is prepared. Certain physicochemical properties and IR absorption spectra of the coordination compounds synthesized are studied.

Human factors issues in fuel handling

Energy Technology Data Exchange (ETDEWEB)

Beattie, J D; Iwasa-Madge, K M; Tucker, D A [Humansystems Inc., Milton, ON (Canada)

1994-12-31

The staff of the Atomic Energy Control Board wish to further their understanding of human factors issues of potential concern associated with fuel handling in CANDU nuclear power stations. This study contributes to that objective by analysing the role of human performance in the overall fuel handling process at Ontario Hydro`s Darlington Nuclear Generating Station, and reporting findings in several areas. A number of issues are identified in the areas of design, operating and maintenance practices, and the organizational and management environment. 1 fig., 4 tabs., 19 refs.

Teacher Training to Handle Bullying in the School in Indonesia

Directory of Open Access Journals (Sweden)

Hidayatus Sholihah

2016-02-01

Full Text Available There are several students in Indonesia who have suffered from injury or even died because of bullying. As a consequence, school teachers in Indonesia need to be trained to handle and prevent bullying. This essay examines the importance of pre-service and in service teacher training in order to reduce and prevent bullying in school in Indonesia by examining the problem of bullying, discussing the effects of it and providing areas of training to help teachers to tackle bullying. There are several reasons why bullying becomes serious problem in school. First of all, bullying is a complex task for teachers because it is difficult to identify and, teachers find it difficult to differentiate between bullying and fighting or horseplay. Moreover, teachers lack the knowledge and skills to handle bullying. Bullying has negative effects not only on victims but also on bullies. Victims feel lonely, depressed, and often have low self-esteem, while bullies often exhibit sign of bad temper or depression. Areas of teachers pre- service and in- service training are1 assisting teachers to differentiate between bullying and fighting or horse playing 2 developing skills to communicate with bullies and to manage classrooms where bullying occurs. In conclusion, teacher training is a good solution to tackle bullying at school in Indonesia because teachers are in the front line to solve this problem. Permalink/DOI: http://dx.doi.org/10.15408/tjems.v2i1.1786

Blanket handling concepts for future fusion power plants

International Nuclear Information System (INIS)

Bogusch, E.; Gottfried, R.; Maisonnier, D.

2003-01-01

In the frame of the power plant conceptual studies (PPCS) launched by the European Commission, two main blanket handling concepts have been investigated with respect to engineering feasibility and the impact on the plant availability and on cost: the large module handling concept (LMHC) and the large sector handling concept (LSHC). The LMHC has been considered as the reference handling concept while the LSHC has been considered as an attractive alternative to the LMHC due to its potential of smaller replacement times and hence increasing the plant availability. Although no principle feasibility issue has been identified, a number of engineering issues have been highlighted for the LSHC that would require considerable efforts for their resolution. Since its availability of about 77% based on a replacement time for all the internals of about 4.2 months is slightly lower than for the LMHC, the LMHC remains the reference blanket replacement concept for a conceptual reactor

Ethical Infrastructure and Successful Handling of Workplace Bullying

Directory of Open Access Journals (Sweden)

Kari Einarsen

2017-03-01

Full Text Available Antecedents and consequences of workplace bullying are well documented. However, the mea- sures taken against workplace bullying, and the effectiveness of such measures, have received less attention. This study addresses this knowledge gap by exploring the role of ethical infrastructure in perceived successful handling of reported workplace bullying. Ethical infrastructure refers to formal and informal systems that enable ethical behavior and disable unethical behavior in organizations. A survey was sent to HR managers and elected head safety representatives (HSRs in all Norwegian municipality organizations. Overall, 216 organizations responded (response rate = 50.2 percent. The ethical infrastructure accounted for 39.4% of the variance in perceived suc- cessful handling of workplace bullying. Formal sanctions were the only unique and signi cant contributor to the perceived successful handling of workplace bullying. The results substantiate the argument that organizations’ ethical infrastructure relate to the HR managers and HSRs’ percep- tions regarding their organizations’ handling of workplace bullying.

Novel Additive Manufacturing Pneumatic Actuators and Mechanisms for Food Handling Grippers

Directory of Open Access Journals (Sweden)

Carlos Blanes

2014-07-01

Full Text Available Conventional pneumatic grippers are widely used in industrial pick and place robot processes for rigid objects. They are simple, robust and fast, but their design, motion and features are limited, and they do not fulfil the final purpose. Food products have a wide variety of shapes and textures and are susceptible to damaged. Robot grippers for food handling should adapt to this wide range of dimensions and must be fast, cheap, reasonably reliable, and with cheap and reasonable maintenance costs. They should not damage the product and must meet hygienic conditions. The additive manufacturing (AM process is able to manufacture parts without significant restrictions, and is Polyamide approved as food contact material by FDA. This paper presents that, taking the best of plastic flexibility, AM allows the implementation of novel actuators, original compliant mechanisms and practical grippers that are cheap, light, fast, small and easily adaptable to specific food products. However, if they are not carefully designed, the results can present problems, such as permanent deformations, low deformation limits, and low operation speed. We present possible solutions for the use of AM to design proper robot grippers for food handling. Some successful results, such as AM actuators based on deformable air chambers, AM compliant mechanisms, and grippers developed in a single part will be introduced and discussed.

The influence of iron coordination compounds on producing capacity of some crops

International Nuclear Information System (INIS)

Rakhimova, M.M.; Yusupov, Z.N.; Nurmatov, T.M.; Dzhafarov, M.I.

1993-01-01

Present article is devoted to influence of iron coordination compounds on producing capacity of some crops. The influence of aqueous solutions of iron coordination compounds with anions of acetic and ethylen diamin disuccinic acids on germinative energy and germination of cotton crops and grapes was studied in laboratory conditions. The conducted researches shown that application of iron coordination compounds improves the growth, fruiting and the quality of studied crops.

Hoisting appliances and fuel handling equipment at nuclear facilities

International Nuclear Information System (INIS)

1987-01-01

The guide is followed by the Finnish Centre for Radiation and Nuclear Safety (STUK) in regulating hoisting and handling equipment Class 3 at nuclear facilities. The guide is applied e.g. to the following equipment: reactor building overhead cranes, hoisting appliances at nuclear fuel storages, fuel handling machines, other hoisting appliances, which because of nuclear safety aspects are classified in Safety Class 3, and load-bearing devices connected with the above equipment, such as replaceable hoisting tools and auxiliary lifting devices. The regulating of hoisting and handling equipment comprises the following stages: handling of preliminary and final safety analysis reports, inspection of the construction plan, supervision of fabrication and construction inspection, and supervision of initial start-up and commissioning inspection

Synthesis and Characterization of Furanic Compounds

Science.gov (United States)

2013-09-01

Furanamine. Solvent 2-Furanamine Acetone — Chloroform — Dimethylacetamide (DMAc) — Dimethylsulfoxide ( DMSO ) + Methanol ± Tetrahydrofuran (THF...4 Figure 4. 1 H NMR of 2-Furanamine in D2O solvent ...Spectra for the furanic compounds were obtained in a 0.1%–0.5% deuterated solvent solutions. 3. Synthesis 3.1 General The following monomers and

46 CFR 151.25-2 - Cargo handling space.

Science.gov (United States)

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo handling space. 151.25-2 Section 151.25-2 Shipping... BULK LIQUID HAZARDOUS MATERIAL CARGOES Environmental Control § 151.25-2 Cargo handling space. Pump rooms, compressor rooms, refrigeration rooms, heating rooms, instrument rooms or other closed spaces...

Safe handling of radiation sources

International Nuclear Information System (INIS)

Abd Nasir Ibrahim; Azali Muhammad; Ab Razak Hamzah; Abd Aziz Mohamed; Mohammad Pauzi Ismail

2004-01-01

This chapter discussed the subjects related to the safe handling of radiation sources: type of radiation sources, method of use: transport within premises, transport outside premises; Disposal of Gamma Sources

Titanium zirconium and hafnium coordination compounds with vanillin thiosemicarbazone

International Nuclear Information System (INIS)

Konunova, Ts.B.; Kudritskaya, S.A.

1987-01-01

Coordination compounds of titanium zirconium and hafnium tetrachlorides with vanillin thiosemicarbazone of MCl 4 x nLig composition, where n=1.5, 4 for titanium and 1, 2, 4 for zirconium and hafnium, are synthesized. Molar conductivity of ethanol solutions is measured; IR spectroscopic and thermochemical investigation are carried out. The supposition about ligand coordination via sulfur and azomethine nitrogen atoms is made. In all cases hafnium forms stable compounds than zirconium

Fluidic delivery of homogeneous solutions through carbon tube bundles

International Nuclear Information System (INIS)

Srikar, R; Yarin, A L; Megaridis, C M

2009-01-01

A wide array of technological applications requires localized high-rate delivery of dissolved compounds (in particular, biological ones), which can be achieved by forcing the solutions or suspensions of such compounds through nano or microtubes and their bundled assemblies. Using a water-soluble compound, the fluorescent dye Rhodamine 610 chloride, frequently used as a model drug release compound, it is shown that deposit buildup on the inner walls of the delivery channels and its adverse consequences pose a severe challenge to implementing pressure-driven long-term fluidic delivery through nano and microcapillaries, even in the case of such homogeneous solutions. Pressure-driven delivery (3-6 bar) of homogeneous dye solutions through macroscopically-long (∼1 cm) carbon nano and microtubes with inner diameters in the range 100 nm-1 μm and their bundled parallel assemblies is studied experimentally and theoretically. It is shown that the flow delivery gradually shifts from fast convection-dominated (unobstructed) to slow jammed convection, and ultimately to diffusion-limited transport through a porous deposit. The jamming/clogging phenomena appear to be rather generic: they were observed in a wide concentration range for two fluorescent dyes in carbon nano and microtubes, as well as in comparable transparent glass microcapillaries. The aim of the present work is to study the physics of jamming, rather than the chemical reasons for the affinity of dye molecules to the tube walls.

49 CFR 172.317 - KEEP AWAY FROM HEAT handling mark.

Science.gov (United States)

2010-10-01

... 49 Transportation 2 2010-10-01 2010-10-01 false KEEP AWAY FROM HEAT handling mark. 172.317 Section... REQUIREMENTS, AND SECURITY PLANS Marking § 172.317 KEEP AWAY FROM HEAT handling mark. (a) General. For... of Division 5.2 must be marked with the KEEP AWAY FROM HEAT handling mark specified in this section...

A Perspective on Equipment Design for Fusion Remote Handling

International Nuclear Information System (INIS)

Mills, S.; Haist, B.; Hamilton, D.

2006-01-01

For 8 years, JET remote operations have become more capable and confident. Many tasks have been successfully completed, even those never intended to be remote maintenance activities. The general approach to the provision of remote handling equipment at JET has been the preferred use of commercially-off-the-shelf equipment. In the areas of electrical, electronic, software and control this approach has been generally achievable. However, in the area of mechanical equipment it has been more difficult. In particular the RH tooling has been almost entirely bespoke as its requirements are highly sensitive to the design of the JET component being handled and there are many design variations. Hence, JET has required the design and manufacture of over 700 types of bespoke RH equipment. This paper will discuss the experience of introducing and developing remote handling mechanical equipment for JET. The paper will cover the relationship between the remote handling equipment and the JET component design and the potential for improving the design function. A major lesson from the introduction of remote handling to JET has been demonstration of the very close interdependency of the design of JET components with design of remote handling tooling. The JET remote handling manual was originally introduced as the vehicle to ensure remote handling compatibility by the introduction of standards. Experience has shown that in general the remote handling manual approach has been insufficient. Future fusion machines will be much more complex than JET and will demand even greater remote handling compatibility. This paper will discuss possible methods for improving this process. Equipment operating in a high radiation environment must be dependable It may spend part of its time in areas that would be extremely difficult to recover from in the case of failure. The equipment may also have a high duty cycle to minimise shutdown times and probably cannot be manually inspected on a frequent

Analysis of Handling Processes of Record Versions in NoSQL Databases

Directory of Open Access Journals (Sweden)

Yu. A. Grigorev

2015-01-01

Full Text Available This article investigates the handling processes versions of a record in NoSQL databases. The goal of this work is to develop a model, which enables users both to handle record versions and work with a record simultaneously. This model allows us to estimate both a time distribution for users to handle record versions and a distribution of the count of record versions. With eventual consistency (W=R=1 there is a possibility for several users to update any record simultaneously. In this case, several versions of records with the same key will be stored in database. When reading, the user obtains all versions, handles them, and saves a new version, while older versions are deleted. According to the model, the user’s time for handling the record versions consists of two parts: random handling time of each version and random deliberation time for handling a result. Record saving time and records deleting time are much less than handling time, so, they are ignored in the model. The paper offers two model variants. According to the first variant, client's handling time of one record version is calculated as the sum of random handling times of one version based on the count of record versions. This variant ignores explicitly the fact that handling time of record versions may depend on the update count, performed by the other users between the sequential updates of the record by the current client. So there is the second variant, which takes this feature into consideration. The developed models were implemented in the GPSS environment. The model experiments with different counts of clients and different ratio between one record handling time and results deliberation time were conducted. The analysis showed that despite the resemblance of model variants, a difference in change nature between average values of record versions count and handling time is significant. In the second variant dependences of the average count of record versions in database and

Uranium hexafluoride: A manual of good handling practices. Revision 7

International Nuclear Information System (INIS)

1995-01-01

The United States Enrichment Corporation (USEC) is continuing the policy of the US Department of Energy (DOE) and its predecessor agencies in sharing with the nuclear industry their experience in the area of uranium hexafluoride (UF 6 ) shipping containers and handling procedures. The USEC has reviewed Revision 6 or ORO-651 and is issuing this new edition to assure that the document includes the most recent information on UF 6 handling procedures and reflects the policies of the USEC. This manual updates the material contained in earlier issues. It covers the essential aspects of UF 6 handling, cylinder filling and emptying, general principles of weighing and sampling, shipping, and the use of protective overpacks. The physical and chemical properties of UF 6 are also described. The procedures and systems described for safe handling of UF 6 presented in this document have been developed and evaluated during more than 40 years of handling vast quantities of UF 6 . With proper consideration for its nuclear properties, UF 6 may be safely handled in essentially the same manner as any other corrosive and/or toxic chemical

Immobilization of N-Heterocyclic Carbene Compounds: A Synthetic Perspective.

Science.gov (United States)

Zhong, Rui; Lindhorst, Anja C; Groche, Florian J; Kühn, Fritz E

2017-02-08

Over the course of the past 15 years the success story of N-heterocyclic carbene (NHC) compounds in organic, inorganic, and organometallic chemistry has been extended to another dimension. The immobilization of NHC compounds, undergoing continuous diversification, broadens their range of applications and leads to new solutions for challenges in catalytic and synthetic chemistry. This review intends to present a synthetic toolkit for the immobilization of NHC compounds, giving the reader an overview on synthetic techniques and strategies available in the literature. By individually summarizing and assessing the synthetic steps of the immobilization process, a comprehensive picture of the strategies and methodologies for the immobilization of NHC compounds is presented. Furthermore, the characterization of supported NHC compounds is discussed in detail in order to set up necessary criteria for an in-depth analysis of the immobilized derivatives. Finally, the catalytic applications of immobilized NHC compounds are briefly reviewed to illustrate the practical use of this technique for a broad variety of reaction types.

Optimal event handling by multiple unmanned aerial vehicles

NARCIS (Netherlands)

de Roo, Martijn; Frasca, Paolo; Carloni, Raffaella

This paper proposes a control architecture for a fleet of unmanned aerial vehicles that is responsible for handling the events that take place in a given area. The architecture guarantees that each event is handled by the required number of vehicles in the shortest time, while the rest of the fleet

Remote technologies for handling spent fuel

International Nuclear Information System (INIS)

Ramakumar, M.S.

1999-01-01

The nuclear programme in India involves building and operating power and research reactors, production and use of isotopes, fabrication of reactor fuel, reprocessing of irradiated fuel, recovery of plutonium and uranium-233, fabrication of fuel containing plutonium-239, uranium-233, post-irradiation examination of fuel and hardware and handling solid and liquid radioactive wastes. Fuel that could be termed 'spent' in thermal reactors is a source for second generation fuel (plutonium and uranium-233). Therefore, it is only logical to extend remote techniques beyond handling fuel from thermal reactors to fuel from fast reactors, post-irradiation examination etc. Fabrication of fuel containing plutonium and uranium-233 poses challenges in view of restriction on human exposure to radiation. Hence, automation will serve as a step towards remotisation. Automated systems, both rigid and flexible (using robots) need to be developed and implemented. Accounting of fissile material handled by robots in local area networks with appropriate access codes will be possible. While dealing with all these activities, it is essential to pay attention to maintenance and repair of the facilities. Remote techniques are essential here. There are a number of commonalities in these requirements and so development of modularized subsystems, and integration of different configurations should receive attention. On a long-term basis, activities like decontamination, decommissioning of facilities and handling of waste generated have to be addressed. While robotized remote systems have to be designed for existing facilities, future designs of facilities should take into account total operation with robotic remote systems. (author)

DOE handbook: Tritium handling and safe storage

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

The DOE Handbook was developed as an educational supplement and reference for operations and maintenance personnel. Most of the tritium publications are written from a radiological protection perspective. This handbook provides more extensive guidance and advice on the null range of tritium operations. This handbook can be used by personnel involved in the full range of tritium handling from receipt to ultimate disposal. Compliance issues are addressed at each stage of handling. This handbook can also be used as a reference for those individuals involved in real time determination of bounding doses resulting from inadvertent tritium releases. This handbook provides useful information for establishing processes and procedures for the receipt, storage, assay, handling, packaging, and shipping of tritium and tritiated wastes. It includes discussions and advice on compliance-based issues and adds insight to those areas that currently possess unclear DOE guidance.

DOE handbook: Tritium handling and safe storage

International Nuclear Information System (INIS)

1999-03-01

The DOE Handbook was developed as an educational supplement and reference for operations and maintenance personnel. Most of the tritium publications are written from a radiological protection perspective. This handbook provides more extensive guidance and advice on the null range of tritium operations. This handbook can be used by personnel involved in the full range of tritium handling from receipt to ultimate disposal. Compliance issues are addressed at each stage of handling. This handbook can also be used as a reference for those individuals involved in real time determination of bounding doses resulting from inadvertent tritium releases. This handbook provides useful information for establishing processes and procedures for the receipt, storage, assay, handling, packaging, and shipping of tritium and tritiated wastes. It includes discussions and advice on compliance-based issues and adds insight to those areas that currently possess unclear DOE guidance

Automated system for handling tritiated mixed waste

International Nuclear Information System (INIS)

Dennison, D.K.; Merrill, R.D.; Reitz, T.C.

1995-03-01

Lawrence Livermore National Laboratory (LLNL) is developing a semi system for handling, characterizing, processing, sorting, and repackaging hazardous wastes containing tritium. The system combines an IBM-developed gantry robot with a special glove box enclosure designed to protect operators and minimize the potential release of tritium to the atmosphere. All hazardous waste handling and processing will be performed remotely, using the robot in a teleoperational mode for one-of-a-kind functions and in an autonomous mode for repetitive operations. Initially, this system will be used in conjunction with a portable gas system designed to capture any gaseous-phase tritium released into the glove box. This paper presents the objectives of this development program, provides background related to LLNL's robotics and waste handling program, describes the major system components, outlines system operation, and discusses current status and plans

High-Z organic-scintillation solution

International Nuclear Information System (INIS)

Berlman, I.B.; Fluornoy, J.M.; Ashford, C.B.; Lyons, P.B.

1983-01-01

In the present experiment, an attempt is made to raise the average Z of a scintillation solution with as little attendant quenching as possible. Since high-Z atoms quench by means of a close encounter, such encounters are minimized by the use of alkyl groups substituted on the solvent, solute, and heavy atoms. The aromatic compound 1,2,4-trimethylbenzene (pseudocumene) is used as the solvent; 4,4''-di(5-tridecyl)-p-terphenyl (SC-180) as the solute; and tetrabutyltin as the high-Z material. To establish the validity of our ideas, various experiments have been performed with less protected solvents, and heavy atoms. These include benzene, toluene, p-terphenyl, bromobutane, and bromobenzene

Stud bolt handling equipment for reactor vessel

International Nuclear Information System (INIS)

Bunyan, T.W.

1989-01-01

Reactor vessel stud bolt handling equipment includes means for transferring a stud bolt to a carrier from a parking station, or vice versa. Preferably a number of stud bolts are handled simultaneously. The transfer means may include cross arms rotatable about extendable columns, and the equipment is mounted on a mobile base for movement into and out of position. Each carrier comprises a tubular socket and an expandable sleeve to grip a stud bolt. (author)

About brachytherapy for the handling of cancer

International Nuclear Information System (INIS)

Campos, Tarcisio P.R.; Silva, Nilton O.; Damaso, Renato S.; Costa, Helder R.; Borges, Paulo H.R.; Mendes, Bruno M.

2000-01-01

The technique of brachytherapy is argued in this article. The 'hardware' and 'necessary software' for the handling are summarily presented. Being the macro-dosimetry an important stage in the radiation therapy procedure, a simplified method of doses evaluation in conventional brachytherapy is presented. In an illustrative form, isodoses of a three-dimensional distribution of linear sources are drawn on a digitalized X-ray picture, exemplifying the handling of breast brachytherapy by sources of iridium

The physical and chemical characteristics of 175Yb-EDTMP labelled compound

International Nuclear Information System (INIS)

Azmairit Aziz; Marlina; Muhammad Basit Febrian

2010-01-01

Bone pain is a common complication for patient with bone metastases from breasts, prostate and lung cancers. The derivative of phosphonate groups, i.e. diphosphonate as well as poly phosphonate ligands e.g. EDTMP have high affinity in bone matrix. The labeled compound of 175 Yb-EDTMP can be used as an alternative radiopharmaceutical for bone pain palliation. The compound of 175 Yb-EDTMP can be produced by labeling of ethylenediamine tetramethylene phosphonic acid (EDTMP) with itterbium-175 ( 175 YbCl 3 ). Before 175 Yb-EDTMP is used for bone pain palliation in nuclear medicine, the compound have to be characterized to full fill the criteria of the good radiopharmaceutical. The physical and chemical characteristics of 175 Yb-EDTMP had been studied. It consists of: pH, solution clearity, the radiochemical purity that was determined by paper chromatography and paper electrophoresis techniques, electricity charge was determined by paper electrophoresis, stability, lipophilicity of 175 Yb-EDTMP was obtained by determination of octanol-water partition and the plasma binding protein was in-vitro investigated with precipitation method using 5% of trichloroacetic acid solution, and the binding to hydroxyapatite. From the experiment, it was obtained that the 175 Yb-EDTMP solution has the pH of 7, clear, the radiochemical purity of 98.66 ± 0.53%, and the negative electric charge. The compound of 175 Yb-EDTMP has lipophilicity (P) of 0.0135 ± 0.003%, the human plasma binding protein of 8.94 ± 0.66%, and the hydroxyapatite binding of 94.78 ± 2.16%. Stability evaluation indicated that 175 Yb-EDTMP solution was still stable for nine days at room temperature with the radiochemical purity more than 95% (98.62 ± 0.83%). This study expects that 175 Yb-EDTMP compound can fulfill the requirement as radiopharmaceutical for use in palliative treatment of painful bone metastases and supports the development of nuclear medicine in Indonesia. (author)

Apparatus for handling control rod drives

International Nuclear Information System (INIS)

Akimoto, A.; Watanabe, M.; Yoshida, T.; Sugaya, Z.; Saito, T.; Ishii, Y.

1979-01-01

An apparatus for handling control rod drives (CRD's) attached by detachable fixing means to housings mounted in a reactor pressure vessel and each coupled to one of control rods inserted in the reactor pressure vessel is described. The apparatus for handling the CRD's comprise cylindrical housing means, uncoupling means mounted in the housing means for uncoupling each of the control rods from the respective CRD, means mounted on the housing means for effecting attaching and detaching of the fixing means, means for supporting the housing means, and means for moving the support means longitudinally of the CRD

Complying with US and European complaint handling requirements.

Science.gov (United States)

Donawa, M E

1997-09-01

The importance of customer complaints for providing valuable information on the use of medical devices is clearly reflected in United States (US) and European quality system requirements for handling complaints. However, there are significant differences in US and European complaint handling requirements. This article will discuss those differences and methods for ensuring compliance.

Safety issues in robotic handling of nuclear weapon parts

International Nuclear Information System (INIS)

Drotning, W.; Wapman, W.; Fahrenholtz, J.

1993-01-01

Robotic systems are being developed by the Intelligent Systems and Robotics Center at Sandia National Laboratories to perform automated handling tasks with radioactive weapon parts. These systems will reduce the occupational radiation exposure to workers by automating operations that are currently performed manually. The robotic systems at Sandia incorporate several levels of mechanical, electrical, and software safety for handling hazardous materials. For example, tooling used by the robot to handle radioactive parts has been designed with mechanical features that allow the robot to release its payload only at designated locations in the robotic workspace. In addition, software processes check for expected and unexpected situations throughout the operations. Incorporation of features such as these provides multiple levels of safety for handling hazardous or valuable payloads with automated intelligent systems

Production of metals and compounds by radiation chemistry

Science.gov (United States)

Marsik, S. J.; Philipp, W. H.

1969-01-01

Preparation of metals and compounds by radiation induced chemical reactions involves irradiation of metal salt solutions with high energy electrons. This technique offers a method for the preparation of high purity metals with minimum contamination from the container material or the cover gas.

Explicit solutions for exit-only radioactive decay chains

International Nuclear Information System (INIS)

Yuan, Ding; Kernan, Warnick

2007-01-01

In this study, we extended Bateman's [Proc. Cambridge Philos. Soc. 15, 423 (1910)] original work for solving radioactive decay chains and explicitly derived analytic solutions for generic exit-only radioactive decay problems under given initial conditions. Instead of using the conventional Laplace transform for solving Bateman's equations, we used a much simpler algebraic approach. Finally, we discuss methods of breaking down certain classes of large decay chains into collections of simpler chains for easy handling

Additive scheme for calculation of solvation enthalpies of heterocyclic aromatic compounds. Sublimation/vaporization enthalpy at 298.15 K

International Nuclear Information System (INIS)

Solomonov, Boris N.; Nagrimanov, Ruslan N.; Mukhametzyanov, Timur A.

2016-01-01

Highlights: • Additivity scheme for solvation enthalpies estimation of heteroaromatic compounds was proposed. • Method for determination of vaporization/sublimation enthalpies directly at 298.15 K was developed. • Solution enthalpies of 25 heteroaromatic compounds were measured. • Vaporization/sublimation enthalpies of 44 heteroaromatic compounds were determined. • Obtained values are in good agreement with the results of conventional methods. - Abstract: Hereby we propose a method for determination of vaporization and sublimation enthalpies of heterocyclic and carbonyl-containing aromatic compounds at 298.15 K. According to this method vaporization and sublimation enthalpies at 298.15 K are determined based on enthalpies of solvation and solution. Solvation enthalpies of heteroatomatic and carbonyl-containing compounds are calculated using an additive scheme from the solvation enthalpy of closest aromatic hydrocarbon and contributions related to the exchange of CH-groups of hydrocarbon with corresponding substituent atoms or groups. Measured solution enthalpies together with calculated solvation enthalpies allowed to calculate corresponding vaporization and sublimation enthalpies at 298.15 K for a large number of heterocyclic and carbonyl-containing compounds. We have also found that in a number of cases instead of solution enthalpy in benzene at 298.15 K fusion enthalpy at the melting temperature can be used. Comparison between literature data and calculated vaporization and sublimation enthalpies demonstrates satisfactory performance of the proposed method.

Additive scheme for calculation of solvation enthalpies of heterocyclic aromatic compounds. Sublimation/vaporization enthalpy at 298.15 K

Energy Technology Data Exchange (ETDEWEB)

Solomonov, Boris N., E-mail: boris.solomonov@kpfu.ru; Nagrimanov, Ruslan N.; Mukhametzyanov, Timur A.

2016-06-10

Highlights: • Additivity scheme for solvation enthalpies estimation of heteroaromatic compounds was proposed. • Method for determination of vaporization/sublimation enthalpies directly at 298.15 K was developed. • Solution enthalpies of 25 heteroaromatic compounds were measured. • Vaporization/sublimation enthalpies of 44 heteroaromatic compounds were determined. • Obtained values are in good agreement with the results of conventional methods. - Abstract: Hereby we propose a method for determination of vaporization and sublimation enthalpies of heterocyclic and carbonyl-containing aromatic compounds at 298.15 K. According to this method vaporization and sublimation enthalpies at 298.15 K are determined based on enthalpies of solvation and solution. Solvation enthalpies of heteroatomatic and carbonyl-containing compounds are calculated using an additive scheme from the solvation enthalpy of closest aromatic hydrocarbon and contributions related to the exchange of CH-groups of hydrocarbon with corresponding substituent atoms or groups. Measured solution enthalpies together with calculated solvation enthalpies allowed to calculate corresponding vaporization and sublimation enthalpies at 298.15 K for a large number of heterocyclic and carbonyl-containing compounds. We have also found that in a number of cases instead of solution enthalpy in benzene at 298.15 K fusion enthalpy at the melting temperature can be used. Comparison between literature data and calculated vaporization and sublimation enthalpies demonstrates satisfactory performance of the proposed method.

Beam handling and transport solutions

Energy Technology Data Exchange (ETDEWEB)

Maggiore, M. [Laboratori Nazionali di Legnaro, INFN, Via Universita' 2, Legnaro (PD) (Italy); Cirrone, G. A. P.; Schillaci, F.; Scuderi, V. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali del Sud, Via Santa Sofia 62, Catania, Italy and Institute of Physics Czech Academy of Science, ELI-Beamlines project, Na Slovance 2, Prague (Czech Republic); Carpinelli, M. [INFN Sezione di Cagliari, c/o Dipartimento di Fisica, Università di Cagliari, Cagliari (Italy); Cuttone, G.; Romano, F. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali del Sud, Via Santa Sofia 62, Catania (Italy); Tramontana, A. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali del Sud, Via Santa Sofia 62, Catania, Italy and Universita' degli Studi di Catania, Dipartimento di Fisica, Via S. Sofia 64, Catania (Italy)

2013-07-26

The main purpose of the present study is to investigate the possibility to characterize the particle beams produced by the laser-target interaction in terms of collection, focusing and energy selection in order to evaluate the feasibility of a laser-driven facility in the field of medical application and, in particular, for hadrontherapy.

Beam handling and transport solutions

International Nuclear Information System (INIS)

Maggiore, M.; Cirrone, G. A. P.; Schillaci, F.; Scuderi, V.; Carpinelli, M.; Cuttone, G.; Romano, F.; Tramontana, A.

2013-01-01

The main purpose of the present study is to investigate the possibility to characterize the particle beams produced by the laser-target interaction in terms of collection, focusing and energy selection in order to evaluate the feasibility of a laser-driven facility in the field of medical application and, in particular, for hadrontherapy

Modelling uptake into roots and subsequent translocation of neutral and ionisable organic compounds

DEFF Research Database (Denmark)

Trapp, Stefan

2000-01-01

A study on uptake of neutral and dissociating organic compounds from soil solution into roots, and their subsequent translocation, was undertaken using model simulations. The model approach combines the processes of lipophilic sorption, electrochemical interactions, ion trap, advection in xylem...... and dilution by growth. It needs as input data, apart fromplant properties, log KOW, pKa and the valency number of the compound, and pH and chemical concentration in the soil solution. Equilibrium and dynamic (steady-state) models were tested against measured data from several authors, including non...

Project Execution Plan for the Remote Handled Low-Level Waste Disposal Project