Investigation of surface halide modification of nitrile butadiene rubber

Science.gov (United States)

Sukhareva, K. V.; Mikhailov, I. A.; Andriasyan, Yu O.; Mastalygina, E. E.; Popov, A. A.

2017-12-01

The investigation is devoted to the novel technology of surface halide modification of rubber samples based on nitrile butadiene rubber (NBR). 1,1,2-trifluoro-1,2,2-trichlorethane was used as halide modifier. The developed technology is characterized by production stages reduction to one by means of treating the rubber compound with a halide modifier. The surface halide modification of compounds based on nitrile butadiene rubber (NBR) was determined to result in increase of resistance to thermal oxidation and aggressive media. The conducted research revealed the influence of modification time on chemical resistance and physical-mechanical properties of rubbers under investigation.

The alkali halide disk technique in infra-red spectrometry : Anomalous behaviour of some samples dispersed in alkali halide disks

NARCIS (Netherlands)

Tolk, A.

1961-01-01

Some difficulties encountered in the application of the alkali halide disk technique in infra-red spectrometry are discussed. Complications due to interaction of the sample with the alkali halide have been studied experimentally. It was found that the anomalous behaviour of benzoic acid, succinic

Fabrication of high temperature superconductors

Science.gov (United States)

Balachandran, Uthamalingam; Dorris, Stephen E.; Ma, Beihai; Li, Meiya

2003-06-17

A method of forming a biaxially aligned superconductor on a non-biaxially aligned substrate substantially chemically inert to the biaxially aligned superconductor comprising is disclosed. A non-biaxially aligned substrate chemically inert to the superconductor is provided and a biaxially aligned superconductor material is deposited directly on the non-biaxially aligned substrate. A method forming a plume of superconductor material and contacting the plume and the non-biaxially aligned substrate at an angle greater than 0.degree. and less than 90.degree. to deposit a biaxially aligned superconductor on the non-biaxially aligned substrate is also disclosed. Various superconductors and substrates are illustrated.

Treatment of alcaline metals halides for developing crystals

International Nuclear Information System (INIS)

Spurney, R.W.

1974-01-01

A process is described whereby crystals of an alkaline metal halide may be dried and placed in a crucible for development by the Bridgeman-Stockbarger method. Purified alkaline halides from a suspension are dried and formed into dense cakes of transverse section slightly smaller than that of the crucible, where they are packed, melted and grown into crystals according to the Bridgeman-Stockbarger technique. This method applies to the preparation of alkaline halide crystals, particularly sodium iodide for optical elements or scintillation counters [fr

Cation-Dependent Light-Induced Halide Demixing in Hybrid Organic-Inorganic Perovskites.

Science.gov (United States)

Sutter-Fella, Carolin M; Ngo, Quynh P; Cefarin, Nicola; Gardner, Kira L; Tamura, Nobumichi; Stan, Camelia V; Drisdell, Walter S; Javey, Ali; Toma, Francesca M; Sharp, Ian D

2018-06-13

Mixed cation metal halide perovskites with increased power conversion efficiency, negligible hysteresis, and improved long-term stability under illumination, moisture, and thermal stressing have emerged as promising compounds for photovoltaic and optoelectronic applications. Here, we shed light on photoinduced halide demixing using in situ photoluminescence spectroscopy and in situ synchrotron X-ray diffraction (XRD) to directly compare the evolution of composition and phase changes in CH(NH 2 ) 2 CsPb-halide (FACsPb-) and CH 3 NH 3 Pb-halide (MAPb-) perovskites upon illumination, thereby providing insights into why FACs-perovskites are less prone to halide demixing than MA-perovskites. We find that halide demixing occurs in both materials. However, the I-rich domains formed during demixing accumulate strain in FACsPb-perovskites but readily relax in MA-perovskites. The accumulated strain energy is expected to act as a stabilizing force against halide demixing and may explain the higher Br composition threshold for demixing to occur in FACsPb-halides. In addition, we find that while halide demixing leads to a quenching of the high-energy photoluminescence emission from MA-perovskites, the emission is enhanced from FACs-perovskites. This behavior points to a reduction of nonradiative recombination centers in FACs-perovskites arising from the demixing process and buildup of strain. FACsPb-halide perovskites exhibit excellent intrinsic material properties with photoluminescence quantum yields that are comparable to MA-perovskites. Because improved stability is achieved without sacrificing electronic properties, these compositions are better candidates for photovoltaic applications, especially as wide bandgap absorbers in tandem cells.

Continuous lengths of oxide superconductors

Science.gov (United States)

Kroeger, Donald M.; List, III, Frederick A.

2000-01-01

A layered oxide superconductor prepared by depositing a superconductor precursor powder on a continuous length of a first substrate ribbon. A continuous length of a second substrate ribbon is overlaid on the first substrate ribbon. Sufficient pressure is applied to form a bound layered superconductor precursor powder between the first substrate ribbon and the second substrate ribbon. The layered superconductor precursor is then heat treated to establish the oxide superconducting phase. The layered oxide superconductor has a smooth interface between the substrate and the oxide superconductor.

Formability of ABX3 (X=F,Cl,Br,I) halide perovskites

International Nuclear Information System (INIS)

Li Chonghea; Lu Xionggang; Ding Weizhong; Feng Liming; Gao Yonghui; Guo Ziming

2008-01-01

In this study a total of 186 complex halide systems were collected; the formabilities of ABX 3 (X = F, Cl, Br and I) halide perovskites were investigated using the empirical structure map, which was constructed by Goldschmidt's tolerance factor and the octahedral factor. A model for halide perovskite formability was built up. In this model obtained, for all 186 complex halides systems, only one system (CsF-MnF 2 ) without perovskite structure and six systems (RbF-PbF 2 , CsF- BeF 2 , KCl-FeCl 2 , TlI-MnI 2 , RbI-SnI 2 , TlI-PbI 2 ) with perovskite structure were wrongly classified, so its predicting accuracy reaches 96%. It is also indicated that both the tolerance factor and the octahedral factor are a necessary but not sufficient condition for ABX 3 halide perovskite formability, and a lowest limit of the octahedral factor exists for halide perovskite formation. This result is consistent with our previous report for ABO 3 oxide perovskite, and may be helpful to design novel halide materials with the perovskite structure. (orig.)

Synthesis, Reactivity and Stability of Aryl Halide Protecting Groups towards Di-Substituted Pyridines

Directory of Open Access Journals (Sweden)

Ptoton Mnangat Brian

2016-03-01

Full Text Available This paper reports the synthesis and reactivity of different Benzyl derivative protecting groups. The synthesis and stability of Benzyl halides, 4-methoxybenzyl halides, 3,5-dimethoxybenzyl halides, 3,4-dimethoxybenzyl halides, 3,4,5-trimethoxybenzyl halide protecting groups and their reactivity towards nitrogen atom of a di-substituted pyridine ring in formation of pyridinium salts is also reported.

High temperature reactions between molybdenum and metal halides

International Nuclear Information System (INIS)

Boeroeczki, A.; Dobos, G.; Josepovits, V.K.; Hars, Gy.

2006-01-01

Good colour rendering properties, high intensity and efficacy are of vital importance for high-end lighting applications. These requirements can be achieved by high intensity discharge lamps doped with different metal halide additives (metal halide lamps). To improve their reliability, it is very important to understand the different failure processes of the lamps. In this paper, the corrosion reactions between different metal halides and the molybdenum electrical feed-through electrode are discussed. The reactions were studied in the feed-through of real lamps and on model samples too. X-ray photoelectron spectroscopy (XPS) was used to establish the chemical states. In case of the model samples we have also used atomic absorption spectroscopy (AAS) to measure the reaction product amounts. Based on the measurement results we were able to determine the most corrosive metal halide components and to understand the mechanism of the reactions

Halide-Dependent Electronic Structure of Organolead Perovskite Materials

KAUST Repository

Buin, Andrei

2015-06-23

© 2015 American Chemical Society. Organometal halide perovskites have recently attracted tremendous attention both at the experimental and theoretical levels. These materials, in particular methylammonium triiodide, are still limited by poor chemical and structural stability under ambient conditions. Today this represents one of the major challenges for polycrystalline perovskite-based photovoltaic technology. In addition to this, the performance of perovskite-based devices is degraded by deep localized states, or traps. To achieve better-performing devices, it is necessary to understand the nature of these states and the mechanisms that lead to their formation. Here we show that the major sources of deep traps in the different halide systems have different origin and character. Halide vacancies are shallow donors in I-based perovskites, whereas they evolve into a major source of traps in Cl-based perovskites. Lead interstitials, which can form lead dimers, are the dominant source of defects in Br-based perovskites, in line with recent experimental data. As a result, the optimal growth conditions are also different for the distinct halide perovskites: growth should be halide-rich for Br and Cl, and halide-poor for I-based perovskites. We discuss stability in relation to the reaction enthalpies of mixtures of bulk precursors with respect to final perovskite product. Methylammonium lead triiodide is characterized by the lowest reaction enthalpy, explaining its low stability. At the opposite end, the highest stability was found for the methylammonium lead trichloride, also consistent with our experimental findings which show no observable structural variations over an extended period of time.

Chapter 27. Superconductors

International Nuclear Information System (INIS)

Vavra, O.

2007-01-01

In this chapter author deals with superconductors and superconductivity. Different chemical materials used as high-temperature superconductors are presented. Some applications of superconductivity are presented.

Solvated Positron Chemistry. Competitive Positron Reactions with Halide Ions in Water

DEFF Research Database (Denmark)

Christensen, Palle; Pedersen, Niels Jørgen; Andersen, J. R.

1979-01-01

It is shown by means of the angular correlation technique that the binding of positrons to halides is strongly influenced by solvation effects. For aqueous solutions we find increasing values for the binding energies between the halide and the positron with increasing mass of the halide...

Superconductors with excess quasiparticles

International Nuclear Information System (INIS)

Elesin, V.F.; Kopaev, Y.V.

1981-01-01

This review presents a systematic kinetic theory of nonequilibrium phenomena in superconductors with excess quasiparticles created by electromagnetic or tunnel injection. The energy distributions of excess quasiparticles and of nonequilibrium phonons, dependence of the order parameter on the power and frequency (or intensity) of the electromagnetic field, magnetic properties of nonequilibrium superconductors, I-V curves of superconductor-insulator-superconductor junctions, and other properties are described in detail. The stability of superconducting states far from thermodynamic equilibrium is investigated and it is shown that characteristic instabilities leading to the formation of nonuniform states of a new type or phase transitions of the first kind are inherent to superconductors with excess quasiparticles. The results are compared with experimental data

Hybrid molecule/superconductor assemblies

International Nuclear Information System (INIS)

McDevitt, J.T.; Haupt, S.G.; Riley, D.R.; Zhao, J.; Zhou, J.P., Jones, C.

1993-01-01

The fabrication of electronic devices from molecular materials has attracted much attention recently. Schottky diodes, molecular transistors, metal-insulator-semiconductor diodes, MIS field effect transistors and light emitting diodes have all been prepared utilizing such substances. The active elements in these devices have been constructed by depositing the molecular phase onto the surface of a metal, semiconductor or insulating substrate. With the recent discovery of high temperature superconductivity, new opportunities now exist for the study of molecule/superconductor interactions as well as for the construction of novel hybrid molecule/superconductor devices. In this paper, methods for preparing the initial two composite molecule/semiconductor devices will be reported. Consequently, light sensors based on dye-coated superconductor junctions as well as molecular switches fashioned from conductive polymer coated superconductor junctions as well as molecular switches fashioned from conductive polymer coated superconductor microbridges will be discussed. Moreover, molecule/superconductor energy and electron transfer phenomena will be illustrated also for the first time

Entropy in halide perovskites

Science.gov (United States)

Katan, Claudine; Mohite, Aditya D.; Even, Jacky

2018-05-01

Claudine Katan, Aditya D. Mohite and Jacky Even discuss the possible impact of various entropy contributions (stochastic structural fluctuations, anharmonicity and lattice softness) on the optoelectronic properties of halide perovskite materials and devices.

Two classes of superconductors discovered in our material research: Iron-based high temperature superconductor and electride superconductor

International Nuclear Information System (INIS)

Hosono, Hideo

2009-01-01

We discovered two new classes of superconductors in the course of material exploration for electronic-active oxides. One is 12CaO . 7Al 2 O 3 crystal in which electrons accomodate in the crystallographic sub-nanometer-sized cavities. This material exhibiting metal-superconductor transition at 0.2 K is the first electride superconductor. The other is iron oxypnicitides with a layered structure. This superconductor is rather different from high T c cuprates in several respects. The high T c is emerged by doping carriers to the metallic parent phases which undergo crystallographic transition (tetra to ortho) and Pauli para to antiferromagnetic transition at ∼150 K. The T c is robust to impurity doping to the Fe sites or is induced by partial substitution of the Fe 2+ sites with Co 2+ or Ni 2+ . This article gives a brief summary of these discoveries and recent advances.

Strong nonequilibrium coherent states in mesoscopic superconductor-semiconductor-superconductor junctions

DEFF Research Database (Denmark)

Kutchinsky, Jonatan; Wildt, Morten; Taboryski, Rafael Jozef

1999-01-01

A biased superconductor-normal metal-superconductor junction is known to be a strong nonequilibrium system, where Andreev scattering at the interfaces creates a quasiparticle distribution function far from equilibrium, a manifestation of this is the well-known subgap structure in the I...

Development of superconductor bulk for superconductor bearing

Energy Technology Data Exchange (ETDEWEB)

Kim, Chan Joong; Jun, Byung Hyuk; Park, Soon Dong (and others)

2008-08-15

Current carrying capacity is one of the most important issues in the consideration of superconductor bulk materials for engineering applications. There are numerous applications of Y-Ba-Cu-O (YBCO) bulk superconductors e.g. magnetic levitation train, flywheel energy storage system, levitation transportation, lunar telescope, centrifugal device, magnetic shielding materials, bulk magnets etc. Accordingly, to obtain YBCO materials in the form of large, single crystals without weak-link problem is necessary. A top seeded melt growth (TSMG) process was used to fabricate single crystal YBCO bulk superconductors. The seeded and infiltration growth (IG) technique was also very promising method for the synthesis of large, single-grain YBCO bulk superconductors with good superconducting properties. 5 wt.% Ag doped Y211 green compacts were sintered at 900 .deg. C {approx} 1200 .deg.C and then a single crystal YBCO was fabricated by an infiltration method. A refinement and uniform distribution of the Y211 particles in the Y123 matrix were achieved by sintering the Ag-doped samples. This enhancement of the critical current density was ascribable to a fine dispersion of the Y211 particles, a low porosity and the presence of Ag particles. In addition, we have designed and manufactured large YBCO single domain with levitation force of 10-13 kg/cm{sup 2} using TSMG processing technique.

Quasiparticle current in superconductor-semiconductor-superconductor junctions

International Nuclear Information System (INIS)

Tartakovskij, A.V.; Fistul', M.V.

1988-01-01

It is shown that the quasiparticle current in a superconductor-semiconductor-superconductor junction may significantly increase as a result of resonant passage of the quasiparticle along particular trajectories from periodically situated localized centers. A prediction of the theory is that with increasing junction resistance there should be a change from an excessive current to a insufficient current on the current-voltage characteristics (at high voltages). The effect of transparency of the boundaries on resonance tunneling in such junctions is also investigated

Coupling spin qubits via superconductors

DEFF Research Database (Denmark)

Leijnse, Martin; Flensberg, Karsten

2013-01-01

We show how superconductors can be used to couple, initialize, and read out spatially separated spin qubits. When two single-electron quantum dots are tunnel coupled to the same superconductor, the singlet component of the two-electron state partially leaks into the superconductor via crossed...... Andreev reflection. This induces a gate-controlled singlet-triplet splitting which, with an appropriate superconductor geometry, remains large for dot separations within the superconducting coherence length. Furthermore, we show that when two double-dot singlet-triplet qubits are tunnel coupled...... to a superconductor with finite charging energy, crossed Andreev reflection enables a strong two-qubit coupling over distances much larger than the coherence length....

The coacervation of aqueous solutions of tetraalkylammonium halides

International Nuclear Information System (INIS)

Mugnier de Trobriand, Anne.

1979-09-01

The coacervation of aqueous solutions of tatraalkylammonium halides in the presence of not of inorganic halides and acids has been studied, considering thermodynamic and spectroscopic aspects. The importance of dispersion forces as well as forces resulting from hydrophobic hydration has been assessed. The analogy between these systems and anionic ion exchange resins has been shown especially for Uranium VI extraction [fr

Computational screening of mixed metal halide ammines

DEFF Research Database (Denmark)

Jensen, Peter Bjerre; Lysgaard, Steen; Quaade, Ulrich

2013-01-01

Metal halide ammines, e.g. Mg(NH3)6Cl2 and Sr(NH3)8Cl2, can reversibly store ammonia, with high volumetric hydrogen storage capacities. The storage in the halide ammines is very safe, and the salts are therefore highly relevant as a carbon-free energy carrier in future transportation infrastructure...... selection. The GA is evolving from an initial (random) population and selecting those with highest fitness, a function based on e.g. stability, release temperature and storage capacity. The search space includes all alkaline, alkaline earth, 3d and 4d metals and the four lightest halides. In total...... the search spaces consists of millions combinations, which makes a GA ideal, to reduce the number of necessary calculations. We are screening for a one step release from either a hexa or octa ammine, and we have found promising candidates, which will be further investigated ? both computationally...

Catalytic effect of halide additives ball milled with magnesium hydride

Energy Technology Data Exchange (ETDEWEB)

Malka, I.E.; Bystrzycki, J. [Department of Advanced Materials and Technologies, Military University of Technology, Kaliskiego 2, 00-908 Warsaw (Poland); Czujko, T. [Department of Advanced Materials and Technologies, Military University of Technology, Kaliskiego 2, 00-908 Warsaw (Poland); CanmetENERGY, Hydrogen Fuel Cells and Transportation Energy, Natural Resources (Canada)

2010-02-15

The influence of various halide additives milled with magnesium hydride (MgH{sub 2}) on its decomposition temperature was studied. The optimum amount of halide additive and milling conditions were evaluated. The MgH{sub 2} decomposition temperature and energy of activation reduction were measured by temperature programmed desorption (TPD) and differential scanning calorimetry (DSC). The difference in catalytic efficiency between chlorides and fluorides of the various metals studied is presented. The effects of oxidation state, valence and position in the periodic table for selected halides on MgH{sub 2} decomposition temperature were also studied. The best catalysts, from the halides studied, for magnesium hydride decomposition were ZrF{sub 4}, TaF{sub 5}, NbF{sub 5}, VCl{sub 3} and TiCl{sub 3}. (author)

Theory of Josephson effect in d-wave superconductor/diffusive ferromagnet/d-wave superconductor junctions

NARCIS (Netherlands)

Yokoyama, T.; Tanaka, Y.; Golubov, Alexandre Avraamovitch

2007-01-01

We study Josephson effect in d-wave superconductor/diffusive ferromagnet/d-wave superconductor junctions, changing the exchange field and the angles between the normal to the interfaces and the crystal axes of d-wave superconductors. We find a 0–π transition at a certain value of the exchange field.

Alkali metal and alkali earth metal gadolinium halide scintillators

Science.gov (United States)

Bourret-Courchesne, Edith; Derenzo, Stephen E.; Parms, Shameka; Porter-Chapman, Yetta D.; Wiggins, Latoria K.

2016-08-02

The present invention provides for a composition comprising an inorganic scintillator comprising a gadolinium halide, optionally cerium-doped, having the formula A.sub.nGdX.sub.m:Ce; wherein A is nothing, an alkali metal, such as Li or Na, or an alkali earth metal, such as Ba; X is F, Br, Cl, or I; n is an integer from 1 to 2; m is an integer from 4 to 7; and the molar percent of cerium is 0% to 100%. The gadolinium halides or alkali earth metal gadolinium halides are scintillators and produce a bright luminescence upon irradiation by a suitable radiation.

Melt processed high-temperature superconductors

CERN Document Server

1993-01-01

The achievement of large critical currents is critical to the applications of high-temperature superconductors. Recent developments have shown that melt processing is suitable for producing high J c oxide superconductors. Using magnetic forces between such high J c oxide superconductors and magnets, a person could be levitated.This book has grown largely out of research works on melt processing of high-temperature superconductors conducted at ISTEC Superconductivity Research Laboratory. The chapters build on melt processing, microstructural characterization, fundamentals of flux pinning, criti

Ivar Giaever, Tunneling, and Superconductors

Science.gov (United States)

dropdown arrow Site Map A-Z Index Menu Synopsis Ivar Giaever, Tunneling, and Superconductors Resources with in Superconductors Measured by Electron Tunneling; Physical Review Letters, Vol. 5 Issue 4: 147 - 148 ; August 15, 1960 Electron Tunneling Between Two Superconductors; Physical Review Letters, Vol. 5 Issue 10

Methyl halide emissions from greenhouse-grown mangroves

Science.gov (United States)

Manley, Steven L.; Wang, Nun-Yii; Walser, Maggie L.; Cicerone, Ralph J.

2007-01-01

Two mangrove species, Avicennia germinans and Rhizophora mangle, were greenhouse grown for nearly 1.5 years from saplings. A single individual of each species was monitored for the emission of methyl halides from aerial tissue. During the first 240 days, salinity was incrementally increased with the addition of seawater, and was maintained between 18 and 28‰ for the duration of the study. Exponential growth occurred after 180 days. Methyl halide emissions normalized to leaf area were measured throughout the study and varied dramatically. Emission rates normalized to land area (mg m-2 y-1), assuming a LAI = 5, yielded 82 and 29 for CH3Cl, 10 and 1.6 for CH3Br, and 26 and 11 for CH3I, for A. germinans and R. mangle, respectively. From these preliminary determinations, only CH3I emissions emerge as being of possible global atmospheric significance. This study emphasizes the need for field studies of methyl halide emissions from mangrove forests.

Complexes in polyvalent metal - Alkali halide melts

International Nuclear Information System (INIS)

Akdeniz, Z.; Tosi, M.P.

1991-03-01

Experimental evidence is available in the literature on the local coordination of divalent and trivalent metal ions by halogens in some 140 liquid mixtures of their halides with alkali halides. After brief reference to classification criteria for main types of local coordination, we focus on statistical mechanical models that we are developing for Al-alkali halide mixtures. Specifically, we discuss theoretically the equilibrium between (AlF 6 ) 3- and (AlF 4 ) - complexes in mixtures of AlF 3 and NaF as a function of composition in the NaF-rich region, the effect of the alkali counterion on this equilibrium, the possible role of (AlF 5 ) 2- as an intermediate species in molten cryolite, and the origin of the different complexing behaviours of Al-alkali fluorides and chlorides. We also present a theoretical scenario for processes of structure breaking and electron localization in molten cryolite under addition of sodium metal. (author). 26 refs, 2 tabs

Oxide superconductors

International Nuclear Information System (INIS)

Cava, R.J.

2000-01-01

This article briefly reviews ceramic superconductors from historical and materials perspectives. It describes the factors that distinguish high-temperature cuprate superconductors from most electronic ceramics and places them in the context of other families of superconducting materials. Finally, it describes some of the scientific issues presently being actively pursued in the search for the mechanism for high-temperature superconductivity and the directions of research into new superconducting ceramics in recent years

Lamp-Ballast Compatibility Index for Efficient Ceramic Metal Halide Lamp Operation

OpenAIRE

Sourish Chatterjee

2013-01-01

Development of energy efficient products and exploration of energy saving potential are major challenges for present day’s technology. Ceramic Metal Halide lamp is the latest improved version of metal halide lamp that finds its wide applications in indoor commercial lighting especially in retail shop lighting. This lamp shows better performance in terms of higher lumen per watt and colour constancy in comparison to conventional metal halide lamp. The inherent negative incremental impedance of...

Making and Breaking of Lead Halide Perovskites

KAUST Repository

Manser, Joseph S.

2016-02-16

A new front-runner has emerged in the field of next-generation photovoltaics. A unique class of materials, known as organic metal halide perovskites, bridges the gap between low-cost fabrication and exceptional device performance. These compounds can be processed at low temperature (typically in the range 80–150 °C) and readily self-assemble from the solution phase into high-quality semiconductor thin films. The low energetic barrier for crystal formation has mixed consequences. On one hand, it enables inexpensive processing and both optical and electronic tunability. The caveat, however, is that many as-formed lead halide perovskite thin films lack chemical and structural stability, undergoing rapid degradation in the presence of moisture or heat. To date, improvements in perovskite solar cell efficiency have resulted primarily from better control over thin film morphology, manipulation of the stoichiometry and chemistry of lead halide and alkylammonium halide precursors, and the choice of solvent treatment. Proper characterization and tuning of processing parameters can aid in rational optimization of perovskite devices. Likewise, gaining a comprehensive understanding of the degradation mechanism and identifying components of the perovskite structure that may be particularly susceptible to attack by moisture are vital to mitigate device degradation under operating conditions. This Account provides insight into the lifecycle of organic–inorganic lead halide perovskites, including (i) the nature of the precursor solution, (ii) formation of solid-state perovskite thin films and single crystals, and (iii) transformation of perovskites into hydrated phases upon exposure to moisture. In particular, spectroscopic and structural characterization techniques shed light on the thermally driven evolution of the perovskite structure. By tuning precursor stoichiometry and chemistry, and thus the lead halide charge-transfer complexes present in solution, crystallization

The evidence of unconventional pairing in heavy fermion superconductors and high-Tc superconductors

International Nuclear Information System (INIS)

Tien, C.; Wur, C.S.; Jiang, I.M.

1989-01-01

Recently there has been a great deal of interest in two classes of superconductors, heavy fermion superconductors and high T c copper oxide superconductors. The behavior and nature of superconductivity in these two classes of materials are very similar. The temperature dependences of spin-lattice relaxation time (T 1 ) and spin-spin relaxation time (T 2 ) of 9 Be in UBe 13 are quite similar to those of 63 Cu and 89 Y in YBa 2 Cu 3 O 7-δ . The Knight shift of UBe 13 is unchanged during the superconducting phase transition. The Knight shift of YBa 2 Cu 3 O 7-δ changes from the value in the normal state K n /K s = 1 at T ≥ T c to K n /K s = 0.5 at T = 6 K. Both do not approach zero as expected in BCS theory. The acoustic attenuation is enhanced just below T c instead of rapid drop near T c for these two superconducting system. Neither the enhancement, the temperature variation, nor any other anomalous behaviors appear to be mirrored in EPR data for heavy Fermion superconductors and high T c superconductors. This strongly suggests that the unconventional pairing mechanism which induces superconductivity in heavy fermion materials might also involve in high T c superconductors

Miscellaneous Lasing Actions in Organo-Lead Halide Perovskite Films.

Science.gov (United States)

Duan, Zonghui; Wang, Shuai; Yi, Ningbo; Gu, Zhiyuan; Gao, Yisheng; Song, Qinghai; Xiao, Shumin

2017-06-21

Lasing actions in organo-lead halide perovskite films have been heavily studied in the past few years. However, due to the disordered nature of synthesized perovskite films, the lasing actions are usually understood as random lasers that are formed by multiple scattering. Herein, we demonstrate the miscellaneous lasing actions in organo-lead halide perovskite films. In addition to the random lasers, we show that a single or a few perovskite microparticles can generate laser emissions with their internal resonances instead of multiple scattering among them. We experimentally observed and numerically confirmed whispering gallery (WG)-like microlasers in polygon shaped and other deformed microparticles. Meanwhile, owing to the nature of total internal reflection and the novel shape of the nanoparticle, the size of the perovskite WG laser can be significantly decreased to a few hundred nanometers. Thus, wavelength-scale lead halide perovskite lasers were realized for the first time. All of these laser behaviors are complementary to typical random lasers in perovskite film and will help the understanding of lasing actions in complex lead halide perovskite systems.

Single Crystals of Organolead Halide Perovskites: Growth, Characterization, and Applications

KAUST Repository

Peng, Wei

2017-04-01

With the soaring advancement of organolead halide perovskite solar cells rising from a power conversion efficiency of merely 3% to more than 22% shortly in five years, researchers’ interests on this big material family have been greatly spurred. So far, both in-depth studies on the fundamental properties of organolead halide perovskites and their extended applications such as photodetectors, light emitting diodes, and lasing have been intensively reported. The great successes have been ascribed to various superior properties of organolead halide hybrid perovskites such as long carrier lifetimes, high carrier mobility, and solution-processable high quality thin films, as will be discussed in Chapter 1. Notably, most of these studies have been limited to their polycrystalline thin films. Single crystals, as a counter form of polycrystals, have no grain boundaries and higher crystallinity, and thus less defects. These characteristics gift single crystals with superior optical, electrical, and mechanical properties, which will be discussed in Chapter 2. For example, organolead halide perovskite single crystals have been reported with much longer carrier lifetimes and higher carrier mobilities, which are especially intriguing for optoelectronic applications. Besides their superior optoelectronic properties, organolead halide perovskites have shown large composition versatility, especially their organic components, which can be controlled to effectively adjust their crystal structures and further fundamental properties. Single crystals are an ideal platform for such composition-structure-property study since a uniform structure with homogeneous compositions and without distraction from grain boundaries as well as excess defects can provide unambiguously information of material properties. As a major part of work of this dissertation, explorative work on the composition-structure-property study of organic-cation-alloyed organolead halide perovskites using their single

Common phase diagram for low-dimensional superconductors

International Nuclear Information System (INIS)

Michalak, Rudi

2003-01-01

A phenomenological phase diagram which has been derived for high-temperature superconductors from NMR Knight-shift measurements of the pseudogap is compared to the phase diagram that is obtained for organic superconductors and spin-ladder superconductors, both low-dimensional systems. This is contrasted to the phase diagram of some Heavy Fermion superconductors, i.e. superconductors not constrained to a low dimensionality

Fine uniform filament superconductors

Science.gov (United States)

Riley, Jr., Gilbert N.; Li, Qi; Roberts, Peter R.; Antaya, Peter D.; Seuntjens, Jeffrey M.; Hancock, Steven; DeMoranville, Kenneth L.; Christopherson, Craig J.; Garrant, Jennifer H.; Craven, Christopher A.

2002-01-01

A multifilamentary superconductor composite having a high fill factor is formed from a plurality of stacked monofilament precursor elements, each of which includes a low density superconductor precursor monofilament. The precursor elements all have substantially the same dimensions and characteristics, and are stacked in a rectilinear configuration and consolidated to provide a multifilamentary precursor composite. The composite is thereafter thermomechanically processed to provide a superconductor composite in which each monofilament is less than about 50 microns thick.

Two-band superconductor magnesium diboride

International Nuclear Information System (INIS)

Xi, X X

2008-01-01

This review focuses on the most important features of the 40 K superconductor MgB 2 -the weakly interacting multiple bands (the σ and π bands) and the distinct multiple superconducting energy gaps (the σ and π gaps). Even though the pairing mechanism of superconductor MgB 2 is the conventional electron-phonon coupling, the prominent influence of the two bands and two gaps on its properties sets it apart from other superconductors. It leads to markedly different behaviors in upper critical field, vortex structure, magnetoresistance and many other superconducting and normal-state properties in MgB 2 from single-band superconductors. Further, it gives rise to new physics that does not exist in single-band superconductors, such as the internal Josephson effects between the two order parameters. These unique phenomena depend sensitively on scattering inside and between the two bands, and the intraband and interband scattering can be modified by chemical substitution and irradiation. MgB 2 has brought unprecedented attention to two-band superconductivity, which has been found to exist in other old and new superconductors. The legacy of MgB 2 will be long lasting because of this, as well as the lessons it teaches in terms of the search for new phonon-mediated higher T c superconductors

Granular Superconductors and Gravity

Science.gov (United States)

Noever, David; Koczor, Ron

1999-01-01

As a Bose condensate, superconductors provide novel conditions for revisiting previously proposed couplings between electromagnetism and gravity. Strong variations in Cooper pair density, large conductivity and low magnetic permeability define superconductive and degenerate condensates without the traditional density limits imposed by the Fermi energy (approx. 10(exp -6) g cu cm). Recent experiments have reported anomalous weight loss for a test mass suspended above a rotating Type II, YBCO superconductor, with a relatively high percentage change (0.05-2.1%) independent of the test mass' chemical composition and diamagnetic properties. A variation of 5 parts per 104 was reported above a stationary (non-rotating) superconductor. In experiments using a sensitive gravimeter, bulk YBCO superconductors were stably levitated in a DC magnetic field and exposed without levitation to low-field strength AC magnetic fields. Changes in observed gravity signals were measured to be less than 2 parts in 108 of the normal gravitational acceleration. Given the high sensitivity of the test, future work will examine variants on the basic magnetic behavior of granular superconductors, with particular focus on quantifying their proposed importance to gravity.

Local Polar Fluctuations in Lead Halide Perovskite Crystals

Science.gov (United States)

Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z.; Egger, David A.; Hull, Trevor; Stoumpos, Constantinos C.; Zheng, Fan; Heinz, Tony F.; Kronik, Leeor; Kanatzidis, Mercouri G.; Owen, Jonathan S.; Rappe, Andrew M.; Pimenta, Marcos A.; Brus, Louis E.

2017-03-01

Hybrid lead-halide perovskites have emerged as an excellent class of photovoltaic materials. Recent reports suggest that the organic molecular cation is responsible for local polar fluctuations that inhibit carrier recombination. We combine low-frequency Raman scattering with first-principles molecular dynamics (MD) to study the fundamental nature of these local polar fluctuations. Our observations of a strong central peak in the cubic phase of both hybrid (CH3 NH3 PbBr3 ) and all-inorganic (CsPbBr3 ) lead-halide perovskites show that anharmonic, local polar fluctuations are intrinsic to the general lead-halide perovskite structure, and not unique to the dipolar organic cation. MD simulations indicate that head-to-head Cs motion coupled to Br face expansion, occurring on a few hundred femtosecond time scale, drives the local polar fluctuations in CsPbBr3 .

High temperature superconductor current leads

International Nuclear Information System (INIS)

Zeimetz, B.; Liu, H.K.; Dou, S.X.

1996-01-01

Full text: The use of superconductors in high electrical current applications (magnets, transformers, generators etc.) usually requires cooling with liquid Helium, which is very expensive. The superconductor itself produces no heat, and the design of Helium dewars is very advanced. Therefore most of the heat loss, i.e. Helium consumption, comes from the current lead which connects the superconductor with its power source at room temperature. The current lead usually consists of a pair of thick copper wires. The discovery of the High Temperature Superconductors makes it possible to replace a part of the copper with superconducting material. This drastically reduces the heat losses because a) the superconductor generates no resistive heat and b) it is a very poor thermal conductor compared with the copper. In this work silver-sheathed superconducting tapes are used as current lead components. The work comprises both the production of the tapes and the overall design of the leads, in order to a) maximize the current capacity ('critical current') of the superconductor, b) minimize the thermal conductivity of the silver clad, and c) optimize the cooling conditions

Transmission formalism for supercurrent flow in multiprobe superconductor-semiconductor-superconductor devices

International Nuclear Information System (INIS)

van Wees, B.J.; Lenssen, K.H.; Harmans, C.J.P.M.

1991-01-01

A theoretical study is given of supercurrent flow in a one-dimensional semiconductor channel coupled to superconductors at both ends. In addition, the channel is coupled to a semiconductor reservoir by means of a junction with variable coupling strength var-epsilon. The supercurrent I(cphi) is calculated from the phase-coherent propagation of electronlike and holelike excitations emitted by the superconductor reservoirs, together with electron and hole excitations from the semiconductor reservoir. The effect of temperature and var-epsilon on I(cphi) is studied. It is shown that a voltage applied between the semiconductor reservoir and the superconductors modifies the I(cphi) relation, even in the limit var-epsilon →0

Non-hydrolytic metal oxide films for perovskite halide overcoating and stabilization

Science.gov (United States)

Martinson, Alex B.; Kim, In Soo

2017-09-26

A method of protecting a perovskite halide film from moisture and temperature includes positioning the perovskite halide film in a chamber. The chamber is maintained at a temperature of less than 200 degrees Celsius. An organo-metal compound is inserted into the chamber. A non-hydrolytic oxygen source is subsequently inserted into the chamber. The inserting of the organo-metal compound and subsequent inserting of the non-hydrolytic oxygen source into the chamber is repeated for a predetermined number of cycles. The non-hydrolytic oxygen source and the organo-metal compound interact in the chamber to deposit a non-hydrolytic metal oxide film on perovskite halide film. The non-hydrolytic metal oxide film protects the perovskite halide film from relative humidity of greater than 35% and a temperature of greater than 150 degrees Celsius, respectively.

Evaluating superconductors for microwave applications

International Nuclear Information System (INIS)

Hammond, B.; Bybokas, J.

1989-01-01

It is becoming increasingly obvious that some of the earliest applications for high Tc superconductors will be in the microwave market. While this is a major opportunity for the superconductor community, it also represents a significant challenge. At DC or low frequencies a superconductor can be easily characterized by simple measurements of resistivity and magnetic susceptibility versus temperature. These parameters are fundamental to superconductor characterization and various methods exist for measuring them. The only valid way to determine the microwave characteristics of a superconductor is to measure it at microwave frequencies. It is for this reason that measuring microwave surface resistance has emerged as one of the most demanding and telling tests for materials intended for high frequency applications. In this article, the theory of microwave surface resistance is discussed. Methods for characterizing surface resistance theoretically and by practical implementation are described

Methyl halide emission estimates from domestic biomass burning in Africa

Science.gov (United States)

Mead, M. I.; Khan, M. A. H.; White, I. R.; Nickless, G.; Shallcross, D. E.

Inventories of methyl halide emissions from domestic burning of biomass in Africa, from 1950 to the present day and projected to 2030, have been constructed. By combining emission factors from Andreae and Merlet [2001. Emission of trace gases and aerosols from biomass burning. Global Biogeochemical Cycles 15, 955-966], the biomass burning estimates from Yevich and Logan [2003. An assessment of biofuel use and burning of agricultural waste in the developing world. Global Biogeochemical Cycles 17(4), 1095, doi:10.1029/2002GB001952] and the population data from the UN population division, the emission of methyl halides from domestic biomass usage in Africa has been estimated. Data from this study suggest that methyl halide emissions from domestic biomass burning have increased by a factor of 4-5 from 1950 to 2005 and based on the expected population growth could double over the next 25 years. This estimated change has a non-negligible impact on the atmospheric budgets of methyl halides.

Solar cells, structures including organometallic halide perovskite monocrystalline films, and methods of preparation thereof

KAUST Repository

Bakr, Osman M.

2017-03-02

Embodiments of the present disclosure provide for solar cells including an organometallic halide perovskite monocrystalline film (see fig. 1.1B), other devices including the organometallic halide perovskite monocrystalline film, methods of making organometallic halide perovskite monocrystalline film, and the like.

Definition of a high intensity metal halide discharge reference lamp

NARCIS (Netherlands)

Stoffels, W.W.; Baede, A.H.F.M.; Mullen, van der J.J.A.M.; Haverlag, M.; Zissis, G.

2006-01-01

The design of a ref. metal halide discharge lamp is presented. This lamp is meant as a common study object for researchers working on metal halide discharge lamps, who by using the same design will be able to compare results between research groups, diagnostic techniques and numerical models. The

Unraveling halide hydration: A high dilution approach.

Science.gov (United States)

Migliorati, Valentina; Sessa, Francesco; Aquilanti, Giuliana; D'Angelo, Paola

2014-07-28

The hydration properties of halide aqua ions have been investigated combining classical Molecular Dynamics (MD) with Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Three halide-water interaction potentials recently developed [M. M. Reif and P. H. Hünenberger, J. Chem. Phys. 134, 144104 (2011)], along with three plausible choices for the value of the absolute hydration free energy of the proton (ΔG [minus sign in circle symbol]hyd[H+]), have been checked for their capability to properly describe the structural properties of halide aqueous solutions, by comparing the MD structural results with EXAFS experimental data. A very good agreement between theory and experiment has been obtained with one parameter set, namely LE, thus strengthening preliminary evidences for a ΔG [minus sign in circle symbol]hyd[H] value of -1100 kJ mol(-1) [M. M. Reif and P. H. Hünenberger, J. Chem. Phys. 134, 144104 (2011)]. The Cl(-), Br(-), and I(-) ions have been found to form an unstructured and disordered first hydration shell in aqueous solution, with a broad distribution of instantaneous coordination numbers. Conversely, the F(-) ion shows more ordered and defined first solvation shell, with only two statistically relevant coordination geometries (six and sevenfold complexes). Our thorough investigation on the effect of halide ions on the microscopic structure of water highlights that the perturbation induced by the Cl(-), Br(-), and I(-) ions does not extend beyond the ion first hydration shell, and the structure of water in the F(-) second shell is also substantially unaffected by the ion.

Friction in levitated superconductors

International Nuclear Information System (INIS)

Brandt, E.H.

1988-01-01

A type I superconductor levitated above a magnet of low symmetry has a unique equilibrium position about which it may oscillate freely. In contrast, a type II superconductor has a continuous range of stable equilibrium positions and orientations where it floats rigidly without swinging or orbiting as if it were stuck in sand. A strong internal friction conspicuously indicates the existence and unpinning of flux lines in oxide superconductors levitated above liquid nitrogen. It is shown how these effects follow from the hysteretic magnetization curves and how the energy is dissipated

Superconductor-semiconductor-superconductor planar junctions of aluminium on DELTA-doped gallium arsenide

DEFF Research Database (Denmark)

Taboryski, Rafael Jozef; Clausen, Thomas; Kutchinsky, jonatan

1997-01-01

We have fabricated and characterized planar superconductor-semiconductor-superconductor (S-Sm-S) junctions with a high quality (i.e. low barrier) interface between an n++ modulation doped conduction layer in MBE grown GaAs and in situ deposited Al electrodes. The Schottky barrier at the S...

78 FR 51463 - Energy Conservation Program: Energy Conservation Standards for Metal Halide Lamp Fixtures

Science.gov (United States)

2013-08-20

... merging the metal halide lamp fixture and the high-intensity discharge (HID) lamp rulemakings. This NOPR... Conservation Program: Energy Conservation Standards for Metal Halide Lamp Fixtures; Proposed Rule #0;#0;Federal...: Energy Conservation Standards for Metal Halide Lamp Fixtures AGENCY: Office of Energy Efficiency and...

Superconductor stability 90: A review

International Nuclear Information System (INIS)

Dresner, L.

1990-01-01

This paper reviews some recent developments in the field of stability of superconductors. The main topics dealt with are hydrodynamic phenomena in cable-in-conduit superconductors, namely, multiple stability, quench pressure, thermal expulsion, and thermal hydraulic quenchback, traveling normal zones in large, composite conductors, such as those intended for SMES, and the stability of vapor-cooled leads made of high-temperature superconductors. 31 refs., 5 figs

Energetics of the ruthenium-halide bond in olefin metathesis (pre)catalysts

KAUST Repository

Falivene, Laura; Poater, Albert; Cazin, Catherine S J; Slugovc, Christian; Cavallo, Luigi

2013-01-01

A DFT analysis of the strength of the Ru-halide bond in a series of typical olefin metathesis (pre)catalysts is presented. The calculated Ru-halide bond energies span the rather broad window of 25-43 kcal mol-1. This indicates that in many systems dissociation of the Ru-halide bond is possible and is actually competitive with dissociation of the labile ligand generating the 14e active species. Consequently, formation of cationic Ru species in solution should be considered as a possible event. © 2013 The Royal Society of Chemistry.

Development of halide copper vapor laser (the characteristics of using Cul)

International Nuclear Information System (INIS)

Oouti, Kazumi; Wada, Yukio; Sasao, Nobuyuki

1990-01-01

We are developing halide copper vapor laser that is high efficiency and high reputation rate visible laser. Halide copper vapor laser uses halide copper of copper vapor source. It melts low temperature in comporison with metal copper, because laser tube structure is very simple and it can operate easy. This time, we experiment to use Cul for copper vapor source. We resulted maximum output energy 17.8 (W) and maximum efficiency 0.78 (%) when operate condition was reputation rate 30 (kHz), gas pressure 90 (Torr), charging voltage 13 (kV). (author)

Broadly tunable metal halide perovskites for solid-state light-emission applications

NARCIS (Netherlands)

Adjokatse, Sampson; Fang, Hong-Hua; Loi, Maria Antonietta

2017-01-01

The past two years have witnessed heightened interest in metal-halide perovskites as promising optoelectronic materials for solid-state light emitting applications beyond photovoltaics. Metal-halide perovskites are low-cost solution-processable materials with excellent intrinsic properties such as

Optimization of superconductor--normal-metal--superconductor Josephson junctions for high critical-current density

International Nuclear Information System (INIS)

Golub, A.; Horovitz, B.

1994-01-01

The application of superconducting Bi 2 Sr 2 CaCu 2 O 8 and YBa 2 Cu 3 O 7 wires or tapes to electronic devices requires the optimization of the transport properties in Ohmic contacts between the superconductor and the normal metal in the circuit. This paper presents results of tunneling theory in superconductor--normal-metal--superconductor (SNS) junctions, in both pure and dirty limits. We derive expressions for the critical-current density as a function of the normal-metal resistivity in the dirty limit or of the ratio of Fermi velocities and effective masses in the clean limit. In the latter case the critical current increases when the ratio γ of the Fermi velocity in the superconductor to that of the weak link becomes much less than 1 and it also has a local maximum if γ is close to 1. This local maximum is more pronounced if the ratio of effective masses is large. For temperatures well below the critical temperature of the superconductors the model with abrupt pair potential on the SN interfaces is considered and its applicability near the critical temperature is examined

Topological surface states in nodal superconductors.

Science.gov (United States)

Schnyder, Andreas P; Brydon, Philip M R

2015-06-24

Topological superconductors have become a subject of intense research due to their potential use for technical applications in device fabrication and quantum information. Besides fully gapped superconductors, unconventional superconductors with point or line nodes in their order parameter can also exhibit nontrivial topological characteristics. This article reviews recent progress in the theoretical understanding of nodal topological superconductors, with a focus on Weyl and noncentrosymmetric superconductors and their protected surface states. Using selected examples, we review the bulk topological properties of these systems, study different types of topological surface states, and examine their unusual properties. Furthermore, we survey some candidate materials for topological superconductivity and discuss different experimental signatures of topological surface states.

Topological surface states in nodal superconductors

International Nuclear Information System (INIS)

Schnyder, Andreas P; Brydon, Philip M R

2015-01-01

Topological superconductors have become a subject of intense research due to their potential use for technical applications in device fabrication and quantum information. Besides fully gapped superconductors, unconventional superconductors with point or line nodes in their order parameter can also exhibit nontrivial topological characteristics. This article reviews recent progress in the theoretical understanding of nodal topological superconductors, with a focus on Weyl and noncentrosymmetric superconductors and their protected surface states. Using selected examples, we review the bulk topological properties of these systems, study different types of topological surface states, and examine their unusual properties. Furthermore, we survey some candidate materials for topological superconductivity and discuss different experimental signatures of topological surface states. (topical review)

Pinning and creep in superconductors

International Nuclear Information System (INIS)

Ovchinnikov, Yu.N.

1994-01-01

All superconductors can be separated into two large groups: type I and type II. The behaviour of these two groups in a magnetic field is quite different. The superconductors of type I, in a strong magnetic field, enter the intermediate state. Phenomenological picture of this state was given by Landau. The type II superconductors, in strong magnetic fields, form the mixed state (or Shubnikov phase). The microscopic picture of the mixed state was given by Abrikosov on the basis of Ginzburg-Landau equations. In ideal homogeneous superconductors the free energy is not changed if all the vortex structure is shifted on some distance u. The transport current will be proportional, therefore, to the electric field E. All the real superconductors, however, are inhomogeneous. Inhomogeneities interact with vortex lattice and pin it. In this new state the transport current below some critical value does not lead to the motion of the flux lattice and to the energy dissipation. The value of critical current strongly depends on the type of inhomogeneities, on the value of magnetic field and on temperature. In new layered superconductors, the critical current depends also on the orientation of the magnetic field B with respect to the layer planes. Temperature and quantum fluctuations lead to the transition between different metastable states in superconductors with current. As a result, the vortex lattice slowly moves (creep phenomenon). Below we will briefly discuss all these phenomena. (orig.)

Systemic analysis of thermodynamic properties of lanthanide halides

International Nuclear Information System (INIS)

Mirsaidov, U.; Badalov, A.; Marufi, V.K.

1992-01-01

System analysis of thermodynamic characteristics of lanthanide halides was carried out. A method making allowances for the influence of spin and orbital moments of momentum of the main states of lanthanide trivalent ions in their natural series was employed. Unknown in literature thermodynamic values were calculated and corrected for certain compounds. The character of lanthanide halide thermodynamic parameter change depending on ordinal number of the metals was ascertained. Pronouncement of tetrad-effect in series of compounds considered was pointed out

Electrodynamics of spin currents in superconductors

International Nuclear Information System (INIS)

Hirsch, J.E.

2008-01-01

In recent work we formulated a new set of electrodynamic equations for superconductors as an alternative to the conventional London equations, compatible with the prediction of the theory of hole superconductivity that superconductors expel negative charge from the interior towards the surface. Charge expulsion results in a macroscopically inhomogeneous charge distribution and an electric field in the interior, and because of this a spin current is expected to exist. Furthermore, we have recently shown that a dynamical explanation of the Meissner effect in superconductors leads to the prediction that a spontaneous spin current exists near the surface of superconductors (spin Meissner effect). In this paper we extend the electrodynamic equations proposed earlier for the charge density and charge current to describe also the space and time dependence of the spin density and spin current. This allows us to determine the magnitude of the expelled negative charge and interior electric field as well as of the spin current in terms of other measurable properties of superconductors. We also provide a 'geometric' interpretation of the difference between type I and type II superconductors, discuss how superconductors manage to conserve angular momentum, discuss the relationship between our model and Slater's seminal work on superconductivity, and discuss the magnitude of the expected novel effects for elemental and other superconductors. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

Two-Dimensional Halide Perovskites for Emerging New- Generation Photodetectors

DEFF Research Database (Denmark)

Tang, Yingying; Cao, Xianyi; Chi, Qijin

2018-01-01

Compared to their conventional three-dimensional (3D) counterparts, two-dimensional (2D) halide perovskites have attracted more interests recently in a variety of areas related to optoelectronics because of their unique structural characteristics and enhanced performances. In general, there are two...... distinct types of 2D halide perovskites. One represents those perovskites with an intrinsic layered crystal structure (i.e. MX6 layers, M = metal and X = Cl, Br, I), the other defines the perovskites with a 2D nanostructured morphology such as nanoplatelets and nanosheets. Recent studies have shown that 2D...... halide perovskites hold promising potential for the development of new-generation photodetectors, mainly arising from their highly efficient photoluminescence and absorbance, color tunability in the visible-light range and relatively high stability. In this chapter, we present the summary and highlights...

Kohn anomalies in superconductors

International Nuclear Information System (INIS)

Flatte, M.E.

1994-01-01

The detailed behavior of phonon dispersion curves near momenta which span the electronic Fermi sea in a superconductor is presented. An anomaly, similar to the metallic Kohn anomaly, exists in a superconductor's dispersion curves when the frequency of the photon spanning the Fermi sea exceeds twice the superconducting energy gap. This anomaly occurs at approximately the same momentum but is stronger than the normal-state Kohn anomaly. It also survives at finite temperature, unlike the metallic anomaly. Determination of Fermi-surface diameters from the location of these anomalies, therefore, may be more successful in the superconducting phase than in the normal state. However, the superconductor's anomaly fades rapidly with increased phonon frequency and becomes unobservable when the phonon frequency greatly exceeds the gap. This constraint makes these anomalies useful only in high-temperature superconductors such as La 1.85 Sr 0.15 CuO 4

Processing of Mixed Oxide Superconductors

Science.gov (United States)

1990-07-01

rapid changes world wide a major research centre on high Tc superconductors was awarded to Cambridge which involved moving the work and people to a...reports and paper is in the appendices. Separation Ceramic superconductors tend to be mixtures of phases, especially when first discovered. It would...properties of the superconducting state will in principle allow superconducting material to be levitated from the non superconductor and several designs

Inhomogeneous superconductors

International Nuclear Information System (INIS)

Tinkham, M.

1978-01-01

The coherence length xi and penetration depth lambda set the characteristic length scales in superconductors, typically 100 to 5,000 A. A lattice of flux lines, each carrying a single quantum, can penetrate type II superconductors, i.e., those for which kappa identical with lambda/xi > 1/√2. Inhomogeneities on the scale of the flux lattice spacing are required to pin the lattice to prevent dissipative flux motion. Recent work using voids as pinning centers has demonstrated this principle, but practical materials rely on cold-work, inclusions of second phases, etc., to provide the inhomogeneity. For stability against thermal fluctuations, the superconductor should have the form of many filaments of diameter 10 to 100 μm imbedded in a highly conductive normal metal matrix. Such wire is made by drawing down billets of copper containing rods of the superconductor. An alternative approach is the metallurgical one of Tsuei, which leads to thousands of superconducting filamentary segments in a copper matrix. The superconducting proximity effect causes the whole material to superconduct at low current densities. At high current densities, the range of the proximity effect is reduced so that the effective superconducting volume fraction falls below the percolation threshold, and a finite resistance arises from the copper matrix. But, because of the extremely elongated filaments, this resistance is orders of magnitude lower than that of the normal wire, and low enough to permit the possibility of technical applications

Large area bulk superconductors

Science.gov (United States)

Miller, Dean J.; Field, Michael B.

2002-01-01

A bulk superconductor having a thickness of not less than about 100 microns is carried by a polycrystalline textured substrate having misorientation angles at the surface thereof not greater than about 15.degree.; the bulk superconductor may have a thickness of not less than about 100 microns and a surface area of not less than about 50 cm.sup.2. The textured substrate may have a thickness not less than about 10 microns and misorientation angles at the surface thereof not greater than about 15.degree.. Also disclosed is a process of manufacturing the bulk superconductor and the polycrystalline biaxially textured substrate material.

Measuring condensate fraction in superconductors

International Nuclear Information System (INIS)

Chakravarty, Sudip; Kee, Hae-Young

2000-01-01

An analysis of off-diagonal long-range order in superconductors shows that the spin-spin correlation function is significantly influenced by the order if the order parameter is anisotropic on a microscopic scale. Thus, magnetic neutron scattering can provide a direct measurement of the condensate fraction of a superconductor. It is also argued that recent measurements in high-temperature superconductors come very close to achieving this goal. (c) 2000 The American Physical Society

Passivation Of High-Temperature Superconductors

Science.gov (United States)

Vasquez, Richard P.

1991-01-01

Surfaces of high-temperature superconductors passivated with native iodides, sulfides, or sulfates formed by chemical treatments after superconductors grown. Passivating compounds nearly insoluble in and unreactive with water and protect underlying superconductors from effects of moisture. Layers of cuprous iodide and of barium sulfate grown. Other candidate passivating surface films: iodides and sulfides of bismuth, strontium, and thallium. Other proposed techniques for formation of passivating layers include deposition and gas-phase reaction.

Electrochemistry of plutonium in molten halides

International Nuclear Information System (INIS)

McCurry, L.E.; Moy, G.M.M.; Bowersox, D.F.

1987-01-01

The electrochemistry of plutonium in molten halides is of technological importance as a method of purification of plutonium. Previous authors have reported that plutonium can be purified by electrorefining impure plutonium in various molten haldies. Work to eluciate the mechanism of the plutonium reduction in molten halides has been limited to a chronopotentiometric study in LiCl-KCl. Potentiometric studies have been carried out to determine the standard reduction potential for the plutonium (III) couple in various molten alkali metal halides. Initial cyclic voltammetric experiments were performed in molten KCL at 1100 K. A silver/silver chloride (10 mole %) in equimolar NaCl-KCl was used as a reference electrode. Working and counter electrodes were tungsten. The cell components and melt were contained in a quartz crucible. Background cyclic voltammograms of the KCl melt at the tungsten electrode showed no evidence of electroactive impurities in the melt. Plutonium was added to the melt as PuCl/sub 3/, which was prepared by chlorination of the oxide. At low concentrations of PuCl/sub 3/ in the melt (0.01-0.03 molar), no reduction wave due to the reduction of Pu(III) was observed in the voltammograms up to the potassium reduction limit of the melt. However on scan reversal after scanning into the potassium reduction limit a new oxidation wave was observed

Impact of the organic halide salt on final perovskite composition for photovoltaic applications

KAUST Repository

Moore, David T.

2014-08-01

The methylammonium lead halide perovskites have shown significant promise as a low-cost, second generation, photovoltaic material.Despite recent advances, however, there are still a number of fundamental aspects of their formation as well as their physical and electronic behavior that are not well understood. In this letter we explore the mechanism by which these materials crystallize by testing the outcome of each of the reagent halide salts. We find that components of both salts, lead halide and methylammonium halide, are relatively mobile and can be readily exchanged during the crystallization process when the reaction is carried out in solution or in the solid state. We exploit this fact by showing that the perovskite structure is formed even when the lead salt\\'s anion is a non-halide, leading to lower annealing temperature and time requirements for film formation. Studies into these behaviors may ultimately lead to improved processing conditions for photovoltaic films. © 2014 Author(s).

Impact of the organic halide salt on final perovskite composition for photovoltaic applications

Directory of Open Access Journals (Sweden)

David T. Moore

2014-08-01

Full Text Available The methylammonium lead halide perovskites have shown significant promise as a low-cost, second generation, photovoltaic material. Despite recent advances, however, there are still a number of fundamental aspects of their formation as well as their physical and electronic behavior that are not well understood. In this letter we explore the mechanism by which these materials crystallize by testing the outcome of each of the reagent halide salts. We find that components of both salts, lead halide and methylammonium halide, are relatively mobile and can be readily exchanged during the crystallization process when the reaction is carried out in solution or in the solid state. We exploit this fact by showing that the perovskite structure is formed even when the lead salt's anion is a non-halide, leading to lower annealing temperature and time requirements for film formation. Studies into these behaviors may ultimately lead to improved processing conditions for photovoltaic films.

Chiral superconductors.

Science.gov (United States)

Kallin, Catherine; Berlinsky, John

2016-05-01

Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed.

Signatures of Majorana Kramers pairs in superconductor-Luttinger liquid and superconductor-quantum dot-normal lead junctions

DEFF Research Database (Denmark)

Kim, Younghyun; Liu, Dong E.; Gaidamauskas, Erikas

2016-01-01

Time-reversal invariant topological superconductors are characterized by the presence of Majorana Kramers pairs localized at defects. One of the transport signatures of Majorana Kramers pairs is the quantized differential conductance of $4e^2/h$ when such a one-dimensional superconductor is coupled...... to that in a spin-triplet superconductor - normal lead junction. We also study here a quantum dot coupled to a normal lead and a Majorana Kramers pair and investigate the effect of local repulsive interactions leading to an interplay between Kondo and Majorana correlations. Using a combination of renormalization...... sector of the topological superconductor. We investigate the stability of the Majorana phase with respect to Gaussian fluctuations....

Observation of vapor pressure enhancement of rare-earth metal-halide salts in the temperature range relevant to metal-halide lamps

Energy Technology Data Exchange (ETDEWEB)

Curry, J. J.; Henins, A.; Hardis, J. E. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Estupinan, E. G. [Osram Sylvania Inc., Beverly, Massachusetts 01915 (United States); Lapatovich, W. P. [Independent Consultant, 51 Pye Brook Lane, Boxford, Massachusetts 01921 (United States); Shastri, S. D. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2012-02-20

Total vapor-phase densities of Dy in equilibrium with a DyI{sub 3}/InI condensate and Tm in equilibrium with a TmI{sub 3}/TlI condensate have been measured for temperatures between 900 K and 1400 K. The measurements show strong enhancements in rare-earth vapor densities compared to vapors in equilibrium with the pure rare-earth metal-halides. The measurements were made with x-ray induced fluorescence on the sector 1-ID beam line at the Advanced Photon Source. The temperature range and salt mixtures are relevant to the operation of metal-halide high-intensity discharge lamps.

Modelling of bulk superconductor magnetization

International Nuclear Information System (INIS)

Ainslie, M D; Fujishiro, H

2015-01-01

This paper presents a topical review of the current state of the art in modelling the magnetization of bulk superconductors, including both (RE)BCO (where RE = rare earth or Y) and MgB 2 materials. Such modelling is a powerful tool to understand the physical mechanisms of their magnetization, to assist in interpretation of experimental results, and to predict the performance of practical bulk superconductor-based devices, which is particularly important as many superconducting applications head towards the commercialization stage of their development in the coming years. In addition to the analytical and numerical techniques currently used by researchers for modelling such materials, the commonly used practical techniques to magnetize bulk superconductors are summarized with a particular focus on pulsed field magnetization (PFM), which is promising as a compact, mobile and relatively inexpensive magnetizing technique. A number of numerical models developed to analyse the issues related to PFM and optimise the technique are described in detail, including understanding the dynamics of the magnetic flux penetration and the influence of material inhomogeneities, thermal properties, pulse duration, magnitude and shape, and the shape of the magnetization coil(s). The effect of externally applied magnetic fields in different configurations on the attenuation of the trapped field is also discussed. A number of novel and hybrid bulk superconductor structures are described, including improved thermal conductivity structures and ferromagnet–superconductor structures, which have been designed to overcome some of the issues related to bulk superconductors and their magnetization and enhance the intrinsic properties of bulk superconductors acting as trapped field magnets. Finally, the use of hollow bulk cylinders/tubes for shielding is analysed. (topical review)

Two-dimensional Semiconductor-Superconductor Hybrids

DEFF Research Database (Denmark)

Suominen, Henri Juhani

This thesis investigates hybrid two-dimensional semiconductor-superconductor (Sm-S) devices and presents a new material platform exhibiting intimate Sm-S coupling straight out of the box. Starting with the conventional approach, we investigate coupling superconductors to buried quantum well....... To overcome these issues we integrate the superconductor directly into the semiconducting material growth stack, depositing it in-situ in a molecular beam epitaxy system under high vacuum. We present a number of experiments on these hybrid heterostructures, demonstrating near unity interface transparency...

Ultrafast time-resolved spectroscopy of lead halide perovskite films

Science.gov (United States)

Idowu, Mopelola A.; Yau, Sung H.; Varnavski, Oleg; Goodson, Theodore

2015-09-01

Recently, lead halide perovskites which are organic-inorganic hybrid structures, have been discovered to be highly efficient as light absorbers. Herein, we show the investigation of the excited state dynamics and emission properties of non-stoichiometric precursor formed lead halide perovskites grown by interdiffusion method using steady-state and time-resolved spectroscopic measurements. The influence of the different ratios of the non-stoichiometric precursor solution was examined. The observed photoluminescence properties were correlated with the femtosecond transient absorption measurements.

Lanthanide doped strontium-barium cesium halide scintillators

Science.gov (United States)

Bizarri, Gregory; Bourret-Courchesne, Edith; Derenzo, Stephen E.; Borade, Ramesh B.; Gundiah, Gautam; Yan, Zewu; Hanrahan, Stephen M.; Chaudhry, Anurag; Canning, Andrew

2015-06-09

The present invention provides for a composition comprising an inorganic scintillator comprising an optionally lanthanide-doped strontium-barium, optionally cesium, halide, useful for detecting nuclear material.

Iron pnictide superconductors

International Nuclear Information System (INIS)

Tegel, Marcus Christian

2011-01-01

The scope of this dissertation therefore has not only been the synthesis of various new superconducting and non-superconducting iron pnictides of several structural families but also their in-depth crystallographic and physical characterisation. In Chapters 3 - 6, the family of the ZrCuSiAs-type (1111) compounds is subject of discussion. The solid solution series La(Co x Fe 1-x )PO is analysed regarding magnetic and superconducting properties and the new compounds EuMnPF and REZnPO, as well as the new superconductor parent compound SrFeAsF are presented. Chapters 7 - 9 are dedicated to the new iron arsenide superconductors of the ThCr 2 Si 2 -type (122 family). Therein, also the discovery of the first superconductor in this structural family, Ba 0.6 K 0.4 Fe 2 As 2 , is unveiled. A detailed examination of the complete solid solution series (Ba 1-x K x )Fe 2 As 2 is presented. Moreover, the crystallographic phase transitions of the closely related compounds SrFe 2 As 2 and EuFe 2 As 2 are characterised and the superconductors Sr 1-x K x Fe 2 As 2 and Ca 1-x Na x Fe 2 As 2 are examined for magnetic and phononic excitations. In Chapter 10, the redetermined crystal structure of the superconductor Fe(Se 1-x Te x ) (11-type) is presented from a chemist's point of view. Chapters 11 - 14 look into the superconducting and non-superconducting iron arsenides of more complex structural families (32522-type and 21311-type). Therein, crystallographic and magnetic details of Sr 3 Sc 2 O 5 Fe 2 As 2 are presented and Ba 2 ScO 3 FeAs and Sr 2 CrO 3 FeAs, the first two members of the new 21311-type are portrayed. Sr 2 CrO 3 FeAs is looked at in close detail with various methods, so e.g. the spin structure of the magnetically ordered compound is solved and a possible reason for the absence of superconductivity in this compound is given. Finally, the superconductor Sr 2 VO 3 FeAs is scrutinised and necessary prerequisites for superconductivity in this compound are suggested. (orig.)

Neutron irradiation effects in advanced superconductors

International Nuclear Information System (INIS)

Yoshida, H.; Kodaka, H.; Miyata, K.; Hayashi, Y.; Atobe, K.

1988-01-01

This paper reports the effects of neutron irradiation on superconducting transitions studied by susceptibility and resistivity measurements for A15 type compounds, Laves-phase compounds and oxide superconductors. For A15 superconductors, the transition temperature (T c ) decreased with increasing neutron fluence and showed large drop started at about 5 x 10 18 n/cm 2 (E > 0.1 MeV). Post-irradiation annealing gave recovery of T c , but the behaviors were different for the materials with different composition and microstructure. The Laves-phase compounds showed less degradation than the A15 superconductors. For oxide superconductors very sensitive transition change was observed, including the radiation-induced superconductivity

Future applications of superconductors for industrial use

International Nuclear Information System (INIS)

Reddy, S.P.

1988-01-01

Superconductors have been in existence for many years. Recent developments in superconductivity at higher temperatures are directed towards the potential use of superconductors at ambient temperatures. The diligent efforts of the scientific, engineering, and political agencies in researching and developing superconducting materials have resulted in encouraging accomplishments. Although superconductors could be used in every branch of electrical engineering, the authors focuses on a few areas in this paper. The power distribution and utilization in a typical industry is compared to that of a system using superconductors. Brief discussions of various machines with superconductors at ambient temperatures, based on developments made so far on large superconducting machines, for potential industrial applications are included in this paper

NSSEFF Designing New Higher Temperature Superconductors

Science.gov (United States)

2017-04-13

AFRL-AFOSR-VA-TR-2017-0083 NSSEFF - DESIGINING NEW HIGHER TEMPERATURE SUPERCONDUCTORS Meigan Aronson THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF...2015 4. TITLE AND SUBTITLE NSSEFF - DESIGINING NEW HIGHER TEMPERATURE SUPERCONDUCTORS 5a.  CONTRACT NUMBER 5b.  GRANT NUMBER FA9550-10-1-0191 5c...materials, identifying the most promising candidates. 15. SUBJECT TERMS TEMPERATURE, SUPERCONDUCTOR 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF

Superconductors in the power grid materials and applications

CERN Document Server

2015-01-01

Superconductors offer high throughput with low electric losses and have the potential to transform the electric power grid. Transmission networks incorporating cables of this type could, for example, deliver more power and enable substantial energy savings. Superconductors in the Power Grid: Materials and Applications provides an overview of superconductors and their applications in power grids. Sections address the design and engineering of cable systems and fault current limiters and other emerging applications for superconductors in the power grid, as well as case studies of industrial applications of superconductors in the power grid. Expert editor from highly respected US government-funded research centre Unique focus on superconductors in the power grid Comprehensive coverage

High temperature superconductor accelerator magnets

NARCIS (Netherlands)

van Nugteren, J.

2016-01-01

For future particle accelerators bending dipoles are considered with magnetic fields exceeding 20T. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and

Charge transport in junctions between d-wave superconductors

International Nuclear Information System (INIS)

Barash, Y.S.; Galaktionov, A.V.; Zaikin, A.D.

1995-01-01

We develop a microscopic analysis of superconducting and dissipative currents in junctions between superconductors with d-wave symmetry of the order parameter. We study the proximity effect in such superconductors and show that for certain crystal orientations the superconducting order parameter can be essentially suppressed in the vicinity of a nontransparent specularly reflecting boundary. This effect strongly influences the value and the angular dependence of the dc Josephson current j S . At T∼T c it leads to a crossover between j S ∝T c -T and j S ∝(T c -T) 2 respectively for homogeneous and nonhomogeneous distribution of the order parameter in the vicinity of a tunnel junction. We show that at low temperatures the current-phase relation j S (cphi) for superconductor--normal-metal--superconductor junctions and short weak links between d-wave superconductors is essentially nonharmonic and contains a discontinuity at cphi=0. This leads to further interesting features of such systems which can be used for pairing symmetry tests in high-temperature superconductors (HTSC). We also investigated the low-temperature I-V curves of normal-metal--superconductor and superconductor-superconductor tunnel junctions and demonstrated that depending on the junction type and crystal orientation these curves show zero-bias anomalies I∝V 2 , I∝V 2 ln(1/V), and I∝V 3 caused by the gapless behavior of the order parameter in d-wave superconductors. Many of our results agree well with recent experimental findings for HTSC compounds

Making superconductors

International Nuclear Information System (INIS)

McDonald, W.K.

1981-01-01

A method is described of producing composite rod or wire of increased strength and fineness wherein the composite is formed by reducing a lamina of two metals which have been rolled to form a cylindrical billet in which one of the metals is in expanded form. The composite produced can be encased in copper and fabricated to produce a superconductor. Alloys contemplated for producing superconductors are Nb 3 Sn, Nb 3 Ga, Nb 3 Ge, Nb 3 Si, Nb-Ti, V 3 Ga, V 3 Si, V 3 Sn, V 3 Al, and V 3 Ge laminated on bronze, Al, Cu, Ta, or combinations thereof. (author)

Improved catalytic properties of halohydrin dehalogenase by modification of the halide-binding site.

Science.gov (United States)

Tang, Lixia; Torres Pazmiño, Daniel E; Fraaije, Marco W; de Jong, René M; Dijkstra, Bauke W; Janssen, Dick B

2005-05-03

Halohydrin dehalogenase (HheC) from Agrobacterium radiobacter AD1 catalyzes the dehalogenation of vicinal haloalcohols by an intramolecular substitution reaction, resulting in the formation of the corresponding epoxide, a halide ion, and a proton. Halide release is rate-limiting during the catalytic cycle of the conversion of (R)-p-nitro-2-bromo-1-phenylethanol by the enzyme. The recent elucidation of the X-ray structure of HheC showed that hydrogen bonds between the OH group of Tyr187 and between the Odelta1 atom of Asn176 and Nepsilon1 atom of Trp249 could play a role in stabilizing the conformation of the halide-binding site. The possibility that these hydrogen bonds are important for halide binding and release was studied using site-directed mutagenesis. Steady-state kinetic studies revealed that mutant Y187F, which has lost both hydrogen bonds, has a higher catalytic activity (k(cat)) with two of the three tested substrates compared to the wild-type enzyme. Mutant W249F also shows an enhanced k(cat) value with these two substrates, as well as a remarkable increase in enantiopreference for (R)-p-nitro-2-bromo-1-phenylethanol. In case of a mutation at position 176 (N176A and N176D), a 1000-fold lower catalytic efficiency (k(cat)/K(m)) was obtained, which is mainly due to an increase of the K(m) value of the enzyme. Pre-steady-state kinetic studies showed that a burst of product formation precedes the steady state, indicating that halide release is still rate-limiting for mutants Y187F and W249F. Stopped-flow fluorescence experiments revealed that the rate of halide release is 5.6-fold higher for the Y187F mutant than for the wild-type enzyme and even higher for the W249F enzyme. Taken together, these results show that the disruption of two hydrogen bonds around the halide-binding site increases the rate of halide release and can enhance the overall catalytic activity of HheC.

Search for Majorana fermions in topological superconductors.

Energy Technology Data Exchange (ETDEWEB)

Pan, Wei [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Shi, Xiaoyan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Hawkins, Samuel D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Klem, John Frederick [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2014-10-01

The goal of this project is to search for Majorana fermions (a new quantum particle) in a topological superconductor (a new quantum matter achieved in a topological insulator proximitized by an s-wave superconductor). Majorana fermions (MFs) are electron-like particles that are their own anti-particles. MFs are shown to obey non-Abelian statistics and, thus, can be harnessed to make a fault-resistant topological quantum computer. With the arrival of topological insulators, novel schemes to create MFs have been proposed in hybrid systems by combining a topological insulator with a conventional superconductor. In this LDRD project, we will follow the theoretical proposals to search for MFs in one-dimensional (1D) topological superconductors. 1D topological superconductor will be created inside of a quantum point contact (with the metal pinch-off gates made of conventional s-wave superconductors such as niobium) in a two-dimensional topological insulator (such as inverted type-II InAs/GaSb heterostructure).

Room temperature superconductors

International Nuclear Information System (INIS)

Sleight, A.W.

1995-01-01

If the Holy Grail of room temperature superconductivity could be achieved, the impact on could be enormous. However, a useful room temperature superconductor for most applications must possess a T c somewhat above room temperature and must be capable of sustaining superconductivity in the presence of magnetic fields while carrying a significant current load. The authors will return to the subject of just what characteristics one might seek for a compound to be a room temperature superconductor. 30 refs., 3 figs., 1 tab

Applications of superconductors to electric motors

International Nuclear Information System (INIS)

McConnell, B.W.

1988-01-01

This paper reviews previous experience in applying superconductors to electric motors and examines the difficulties encountered. While motors and generators have a common basis, several significant differences exist. The application of high temperature superconductors to the major electric motor types is discussed and expected difficulties are presented. The limitations imposed by various motor designs are reflected in a statement of the desired material properties for high temperature superconductor electric motor applications

luminescence in coloured alkali halide crystals

Indian Academy of Sciences (India)

have studied the effect of annealing in chlorine gas on the ML of X-rayed KCl crystals. ..... high temperature because of the thermal bleaching of the coloration in alkali halide ..... [31] J Hawkins, Ph.D. Thesis (University of Reading, 1976).

Nonmagnetic impurities in magnetic superconductors

International Nuclear Information System (INIS)

Mineev, V.P.

1989-01-01

The magnetization and magnetic field arising around the nonmagnetic impurity in magnetic superconductor with triplet pairing are found. The relationship of these results with the data of recent (gm)sR experiments in heavy fermionic superconductor U 1 - x Th x Be 13 is presented

Holographic complexity in gauge/string superconductors

Directory of Open Access Journals (Sweden)

Davood Momeni

2016-05-01

Full Text Available Following a methodology similar to [1], we derive a holographic complexity for two dimensional holographic superconductors (gauge/string superconductors with backreactions. Applying a perturbation method proposed by Kanno in Ref. [2], we study behaviors of the complexity for a dual quantum system near critical points. We show that when a system moves from the normal phase (T>Tc to the superconductor phase (T

Superconductors: The long road ahead

International Nuclear Information System (INIS)

Foner, S.; Orlando, T.P.

1988-01-01

Before the discovery of high-temperature superconductors, progress in superconductivity was measured by quite small increases in critical temperature, often of less than one degree. Today, there is no reason to believe that the dramatic leaps in critical temperature inaugurated by superconducting ceramics are over. Researchers may find new high-temperature superconducting materials with less severe technical limitations than the ceramics we know today. And if the day ever comes when a superconductor can be reliably manufactured to operate effectively at room temperature, then superconductors will be incorporated in a broad range of everyday household devices - motors, appliances, even children's toys - with a large consumer market. High-temperature superconductors may also cause us to extensively revise our traditional theories about how superconductivity works. Should it run out that superconductivity in ceramics involves new physical mechanisms, then these mechanisms could lead to applications never considered before. The recent discoveries have already reinvigorated superconductivity research. What was once largely the domain of a relatively small group of scientists has become a genuinely multidisciplinary realm. Now physicists, materials scientists, chemists, metallurgists, ceramists, and solid-state electronics engineers are all focusing on superconductivity. The cross-fertilization of these disciplines should contribute to further discoveries of importance to the practical application of superconductors

The superconductor revolutions and the (slow) applications evolution

International Nuclear Information System (INIS)

Foner, S.

1990-01-01

The discovery in the 1960's of type 2 superconductors with high critical current densities in high magnetic fields (and the development of NbTi in particular) led to the first revolution. The discovery of high temperature superconductors (HTS) started the second revolution. At this stage ceramists became involved with superconductors. I will assess the status of various superconductor applications, progress of HTS and their possible applications at 4.2K, and near-term needs for superconducting materials operating at 30T in specialized facilities. Reasons for the slow growth of superconductor applications will be reviewed

Purcell effect in an organic-inorganic halide perovskite semiconductor microcavity system

International Nuclear Information System (INIS)

Wang, Jun; Wang, Yafeng; Hu, Tao; Wu, Lin; Shen, Xuechu; Chen, Zhanghai; Cao, Runan; Xu, Fei; Da, Peimei; Zheng, Gengfeng; Lu, Jian

2016-01-01

Organic-inorganic halide perovskite semiconductors with the attractive physics properties, including strong photoluminescence (PL), huge oscillator strengths, and low nonradiative recombination losses, are ideal candidates for studying the light-matter interaction in nanostructures. Here, we demonstrate the coupling of the exciton state and the cavity mode in the lead halide perovskite microcavity system at room temperature. The Purcell effect in the coupling system is clearly observed by using angle-resolved photoluminescence spectra. Kinetic analysis based on time-resolved PL reveals that the spontaneous emission rate of the halide perovskite semiconductor is significantly enhanced at resonance of the exciton energy and the cavity mode. Our results provide the way for developing electrically driven organic polariton lasers, optical devices, and on-chip coherent quantum light sources

"Fluctuoscopy" of Superconductors

Science.gov (United States)

Varlamov, A. A.

Study of fluctuation phenomena in superconductors (SCs) is the subject of great fundamental and practical importance. Understanding of their physics allowed to clear up the fundamental properties of SC state. Being predicted in 1968, one of the fluctuation effects, namely paraconductivity, was experimentally observed almost simultaneously. Since this time, fluctuations became a noticeable part of research in the field of superconductivity, and a variety of fluctuation effects have been discovered. The new wave of interest to fluctuations (FL) in superconductors was generated by the discovery of cuprate oxide superconductors (high-temperature superconductors, HTS), where, due to extremely short coherence length and low effective dimensionality of the electron system, superconductive fluctuations manifest themselves in a wide range of temperatures. Moreover, anomalous properties of the normal state of HTS were attributed by many theorists to strong FL in these systems. Being studied in the framework of the phenomenological Ginzburg-Landau theory and, more extensively, in diagrammatic microscopic approach, SC FLs side by side with other quantum corrections (weak localization, etc.) became a new tool for investigation and characterization of such new systems as HTS, disordered electron systems, granular metals, Josephson structures, artificial super-lattices, etc. The characteristic feature of SC FL is their strong dependence on temperature and magnetic fields in the vicinity of phase transition. This allows one to definitely separate the fluctuation effects from other contributions and to use them as the source of information about the microscopic parameters of a material. By their origin, SC FLs are very sensitive to relaxation processes, which break phase coherence. This allows using them for versatile characterization of SC. Today, one can speak about the " fluctuoscopy" of superconductive systems. In review, we present the qualitative picture both of thermodynamic

Testability issues in Superconductor Electronics

NARCIS (Netherlands)

Kerkhoff, Hans G.; Arun, Arun J.

2004-01-01

An emerging technology for solutions in high-end applications in computing and telecommunication is superconductor electronics. A system-level study has been carried out to verify the feasibility of DfT in superconductor electronics. In this paper, we present how this can be realized to monitor

Unconventional superconductors. Anisotropy and multiband effects

Energy Technology Data Exchange (ETDEWEB)

Askerzade, Iman [Ankara Univ. (Turkey). Center of Excellence of Superconductivity Research of Turkey; Azerbaijan National Academy of Sciences (Azerbaijan). Inst. of Physics

2012-07-01

This book deals with the new class of materials unconventional superconductors, cuprate compounds, borocarbides, magnesium-diboride and oxypnictides. It gives a systematical review of physical properties of novel superconductors. There is an increasing number of fundamental properties of these compounds which are relevant to future applications, opening new possibilities. The theoretical explanation is presented as generalization of Ginzburg-Landau phenomenology and microscopical Eliashberg theory for multiband and anisotropic superconductors. Various applications of this approaches and time dependent version of two-band Ginzburg-Landau theory are considered. An important topic are fluctuations in two-band and anisotropic superconductors. Significant new results on current problems are presented to stimulate further research. Numerous illustrations, diagrams and tables make this book useful as a reference for students and researchers. (orig.)

Unconventional superconductors anisotropy and multiband effects

CERN Document Server

Askerzade, Iman

2012-01-01

This book deals with the new class of materials unconventional superconductors, cuprate compounds, borocarbides, magnesium-diboride and oxypnictides. It gives a systematical review of physical properties of novel  superconductors. There is an increasing number of fundamental properties of these compounds which are relevant to future applications, opening new possibilities. The theoretical explanation is presented as generalization of Ginzburg-Landau phenomenology and microscopical Eliashberg theory for multiband and anisotropic superconductors. Various applications of this approachs and time dependent version of two-band Ginzburg-Landau theory are considered. An important topic are fluctuations in two-band and anisotropic superconductors. Significant  new results on current problems are presented to stimulate further research. Numerous illustrations, diagrams and tables make this book useful as a reference for students and researchers.

Progress of metallic superconductors in Japan

Energy Technology Data Exchange (ETDEWEB)

Tachikawa, Kyoji, E-mail: tacsuper@keyaki.cc.u-tokai.ac.jp [Faculty of Engineering, Tokai University, 4-1-1, Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan)

2013-01-15

Highlights: ► Japanese contributions on the R and D of different metallic superconductors are summarized. ► Nb–Ti wires have been developed for MRI, accelerator, MAGLEV train and other applications. ► Multifilamentary Nb{sub 3}Sn wires with excellent performance have been developed for high-field use. ► Long-length Nb{sub 3}Al wires with promising strain tolerance have been fabricated by a new process. -- Abstract: This article overviews the development of metallic superconductors in Japan covering different kinds of alloys and intermetallic compounds. Metallic superconductors have opened many new application areas in science and technology. Japan has been one of the leading countries in the world, both in the research and development and in large-scale manufacturing of metallic superconductors.

Preparation of superconductor precursor powders

Science.gov (United States)

Bhattacharya, Raghunath

1998-01-01

A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic and/or reduced particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of all metals in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity. Superconductors which can be formed from the precursor powder include pellet and powder-in-tube products.

10 CFR 431.322 - Definitions concerning metal halide lamp ballasts and fixtures.

Science.gov (United States)

2010-01-01

... high intensity discharge fixture, the efficiency of a lamp and ballast combination, expressed as a... lamps. Metal halide lamp means a high intensity discharge lamp in which the major portion of the light... 10 Energy 3 2010-01-01 2010-01-01 false Definitions concerning metal halide lamp ballasts and...

Complexes of alkylphenols with aluminium halides

International Nuclear Information System (INIS)

Golounin, A.V.

1997-01-01

Interaction of aluminium halides with alkylphenols is studied through the NMR method. The peculiarity of complex formation of pentamethylphenol with AlI 3 is revealed. By AlI 3 action on the pentamethylphenol the complexes are formed both of keto- and oxy form [ru

Pinning and creep in high-Tc superconductors

International Nuclear Information System (INIS)

Ovchinnikov, Yu.N.; Ivlev, B.I.

1992-01-01

The angular and magnetic field dependence of a critical current parallel to the layers in the layered superconductors is studied. The critical current value is found for a superconductor with strong pinning centers. Quantum flux creep in sufficiently perfect layered high-Tc superconductors is discussed. The cross-over temperature between activated and quantum creep is found. (orig.)

Topological Insulators and Superconductors for Innovative Devices

Science.gov (United States)

2015-03-20

Final 3. DATES COVERED (From - To) 20120321 - 20150320 4. TITLE AND SUBTITLE Topological insulators and superconductors for innovative...locking, which hold promise for various innovative devices. Similarly, topological superconductors are associated with exotic surface states, which...298 (Rev. 8/98) Prescribed by ANSI Std. Z39.18 Final Report Title: Topological Insulators and Superconductors for Innovative Devices

Effect of exciton pairing on the stationary Josephson current in superconductor-semimetal-superconductor junctions

International Nuclear Information System (INIS)

Itskovich, I.F.; Shekhter, R.I.

1983-01-01

The effect of exciton pairing of charge carriers in a semimetal on the stationary Josephson current in superconductor-semimetal-superconductor junctions is considered. It is shown that the phase transition of the semimetal interlayer into an exciton dielectric state for T/sub γ/< T/sub c/ (T/sub γ/, T/sub c/ are the superconducting and exciton transition temperatures, respectively) is accompanied by a kink on the critical current j/sub c/ versus temperature curve at the point T = T/sub γ/. A sharp nonmonotonic temperature dependence of the reduced current j/sub c//j/sub c/0 (j/sub c/0 is the critical current at T/sub γ/ = 0) is also possible in the range T< T/sub γ/. At low temperatures T<< v/sub 1,2//d<< T/sub γ/ (v/sub 1,2/ are the Fermi velocities of the carriers in the semimetal, d is the thickness of the interlayer) the critical current of the superconductor-semimetal-superconductor junction is exponentially smaller than the current in the absence of exciton pairing

Method for preparation of superconductors

Energy Technology Data Exchange (ETDEWEB)

Barber, A.C.; McDougall, I.L.

1975-07-10

The invention deals with a method to prepare a superconductor consisting of a superconducting compound of at least two elements. It especially deals with superconductors which surround a superconducting intermetallic compounds of at least two elements, examples of which are Nb/sub 2/Sn and Nb/sub 3/Al.

Recent status of superconductors for accelerator magnets

International Nuclear Information System (INIS)

Greene, A.F.

1992-01-01

A survey is given of superconductor wire and cable which has been or will be used for construction of dipole magnets for all of the large European and US superconducting accelerator rings. Included is a simplified view of the construction methods and operating requirements of an accelerator dipole magnet, with emphasis on required superconductor performance. The methods of fabricating Nb-Ti superconductors are described, including the critical parameters and materials requirements. The superconductor performance requirements are summarized in an effort to relate why these are important to accelerator designers. Some of the recently observed time dependent effects are covered briefly

Maximizing and stabilizing luminescence from halide perovskites with potassium passivation

Science.gov (United States)

Abdi-Jalebi, Mojtaba; Andaji-Garmaroudi, Zahra; Cacovich, Stefania; Stavrakas, Camille; Philippe, Bertrand; Richter, Johannes M.; Alsari, Mejd; Booker, Edward P.; Hutter, Eline M.; Pearson, Andrew J.; Lilliu, Samuele; Savenije, Tom J.; Rensmo, Håkan; Divitini, Giorgio; Ducati, Caterina; Friend, Richard H.; Stranks, Samuel D.

2018-03-01

Metal halide perovskites are of great interest for various high-performance optoelectronic applications. The ability to tune the perovskite bandgap continuously by modifying the chemical composition opens up applications for perovskites as coloured emitters, in building-integrated photovoltaics, and as components of tandem photovoltaics to increase the power conversion efficiency. Nevertheless, performance is limited by non-radiative losses, with luminescence yields in state-of-the-art perovskite solar cells still far from 100 per cent under standard solar illumination conditions. Furthermore, in mixed halide perovskite systems designed for continuous bandgap tunability (bandgaps of approximately 1.7 to 1.9 electronvolts), photoinduced ion segregation leads to bandgap instabilities. Here we demonstrate substantial mitigation of both non-radiative losses and photoinduced ion migration in perovskite films and interfaces by decorating the surfaces and grain boundaries with passivating potassium halide layers. We demonstrate external photoluminescence quantum yields of 66 per cent, which translate to internal yields that exceed 95 per cent. The high luminescence yields are achieved while maintaining high mobilities of more than 40 square centimetres per volt per second, providing the elusive combination of both high luminescence and excellent charge transport. When interfaced with electrodes in a solar cell device stack, the external luminescence yield—a quantity that must be maximized to obtain high efficiency—remains as high as 15 per cent, indicating very clean interfaces. We also demonstrate the inhibition of transient photoinduced ion-migration processes across a wide range of mixed halide perovskite bandgaps in materials that exhibit bandgap instabilities when unpassivated. We validate these results in fully operating solar cells. Our work represents an important advance in the construction of tunable metal halide perovskite films and interfaces that can

Broadly tunable metal halide perovskites for solid-state light-emission applications

OpenAIRE

Adjokatse, Sampson; Fang, Hong-Hua; Loi, Maria Antonietta

2017-01-01

The past two years have witnessed heightened interest in metal-halide perovskites as promising optoelectronic materials for solid-state light emitting applications beyond photovoltaics. Metal-halide perovskites are low-cost solution-processable materials with excellent intrinsic properties such as broad tunability of bandgap, defect tolerance, high photoluminescence quantum efficiency and high emission color purity (narrow full-width at half maximum). In this review, the photophysical propert...

Cation-Dependent Light-Induced Halide Demixing in Hybrid Organic-Inorganic Perovskites

OpenAIRE

Sutter-Fella, CM; Ngo, QP; Cefarin, N; Gardener, K; Tamura, N; Stan, CV; Drisdell, WS; Javey, A; Toma, FM; Sharp, ID

2018-01-01

© 2018 American Chemical Society. Mixed cation metal halide perovskites with increased power conversion efficiency, negligible hysteresis, and improved long term stability under illumination, moisture, and thermal stressing have emerged as promising compounds for photovoltaic and optoelectronic applications. Here, we shed light on photo-induced halide demixing using in-situ photoluminescence spectroscopy and in-situ synchrotron X-ray diffraction (XRD) to directly compare the evolution of comp...

Ac losses of transposed superconductors

International Nuclear Information System (INIS)

Eckert, D.; Enderlein, G.; Lange, F.

1975-01-01

Eastham and Rhodes published results of loss measurements on transposed superconducting NbTi cables and concluded basing on an extrapolation to very large numbers of wires that transposed superconductors could be used favorably in cables for power transmission. There are some reasons to question the correctness of their extrapolation. Losses were calculated for transposed superconductors in self field and got results different from those of Eastham and Rhodes. Loss measurements were performed the results of which give evidence for the correctness of our calculations. The results lead to the conclusion that the use of transposed cables of irreversible type 2 superconductors for power transmission is not advantageous

Refined global methyl halide budgets with respect to rapeseed (Brassica napus) by life-cycle measurements

Science.gov (United States)

Jiao, Y.; Acdan, J.; Xu, R.; Deventer, M. J.; Rhew, R. C.

2017-12-01

A precise quantification of global methyl halide budgets is needed to evaluate the ozone depletion potential of these compounds and to predict future changes of stratospheric ozone. However, the global budgets of methyl halides are not balanced between currently identified and quantified sources and sinks. Our study re-evaluated the methyl bromide budget from global cultivated rapeseed (Brassica napus) through life-cycle flux measurements both in the greenhouse and in the field, yielding a methyl bromide emission rate that scales globally to 1.0 - 1.2 Gg yr-1. While this indicates a globally significant source, it is much smaller than the previously widely cited value of 5 - 6 Gg yr-1(Mead et al., 2008), even taking into account the near tripling of annual global yield of rapeseed since the previous evaluation was conducted. Our study also evaluated the methyl chloride and methyl iodide emission levels from rapeseed, yielding emission rates that scale to 5.4 Gg yr-1 for methyl chloride and 1.8 Gg yr-1 of methyl iodide. The concentrations of the methyl donor SAM (S-adenosyl methionine) and the resultant product SAH (S-Adenosyl-L-homocysteine) were also analyzed to explore their role in biogenic methyl halide formation. Halide gradient incubations showed that the magnitude of methyl halide emissions from rapeseed is highly correlated to soil halide levels, thus raising the concern that the heterogeneity of soil halide contents geographically should be considered when extrapolating to global budget.

Iron-Based Superconductors as Odd-Parity Superconductors

Directory of Open Access Journals (Sweden)

Jiangping Hu

2013-07-01

Full Text Available Parity is a fundamental quantum number used to classify a state of matter. Materials rarely possess ground states with odd parity. We show that the superconducting state in iron-based superconductors is classified as an odd-parity s-wave spin-singlet pairing state in a single trilayer FeAs/Se, the building block of the materials. In a low-energy effective model constructed on the Fe square bipartite lattice, the superconducting order parameter in this state is a combination of an s-wave normal pairing between two sublattices and an s-wave η pairing within the sublattices. The state has a fingerprint with a real-space sign inversion between the top and bottom As/Se layers. The results suggest that iron-based superconductors are a new quantum state of matter, and the measurement of the odd parity can help to establish high-temperature superconducting mechanisms.

Solar cells, structures including organometallic halide perovskite monocrystalline films, and methods of preparation thereof

KAUST Repository

Bakr, Osman; Peng, Wei; Wang, Lingfei

2017-01-01

Embodiments of the present disclosure provide for solar cells including an organometallic halide perovskite monocrystalline film (see fig. 1.1B), other devices including the organometallic halide perovskite monocrystalline film, methods of making

Fabrication and study of hybrid molecule/superconductor assemblies

International Nuclear Information System (INIS)

McDevitt, J.T.; Haupt, S.G.; Jurbergs, D.; Riley, D.R.; Zhao, J.; Zhou, J.P.; Lo, K.; Grassi, J.; Jones, C.

1994-01-01

The fabrication of electronic devices from molecular materials has attracted much attention recently. Schottky diodes, molecular transistors, metal-insulator-semiconductor diodes, MIS field effect transistors and light emitting diodes have all been prepared utilizing such substances. The active elements in these devices have been constructed by depositing the molecular phase onto the surface of a metal, semiconductor or insulating substrate. With the recent discovery of high temperature superconductivity, new opportunities now exist for the study of molecule/superconductor interactions as well as for the construction of novel hybrid molecule/superconductor devices. In this paper, methods for preparing the first two classes of composite molecule/superconductor devices are reported. Consequently, light sensors based on organic dye-coated superconductor junctions as well as molecular switches fashioned from organic conductive polymer-coated superconductor microbridges are discussed. Moreover, the initial results related to the study of molecule/superconductor energy and electron transfer phenomena are reported

Strongly disordered superconductors

International Nuclear Information System (INIS)

Muttalib, K.A.

1982-01-01

We examine some universal effects of strong non-magnetic disorder on the electron-phonon and electron-electron interactions in a superconductor. In particular we explicitly take into account the effect of slow diffusion of electrons in a disordered medium by working in an exact impurity eigenstate representation. We find that the normal diffusion of electrons characterized by a constant diffusion coefficient does not lead to any significant correction to the electron-phonon or the effective electron-electron interactions in a superconductor. We then consider sufficiently strong disorder where Anderson localization of electrons becomes important and determine the effect of localization on the electron-electron interactions. We find that due to localization, the diffusion of electrons becomes anomalous in the sense that the diffusion coefficient becomes scale dependent. This results in an increase in the effective electron-electron interaction with increasing disorder. We propose that this provides a natural explanation for the unusual sensitivity of the transition temperature T/sub c/ of the high T/sub c/ superconductors (T/sub c/ > 10 0 K) to damage effects

Axial force in a superconductor magnet journal bearing

Science.gov (United States)

Postrekhin, E.; Chong, Wang; Ki Bui, Ma; Chen, Quark; Chu, Wei-Kan

Using superconductors and magnets, a journal bearing could be made from a permanent magnet cylinder in a superconductor ring. We have assembled a prototype superconductor magnet journal bearing of this configuration, and investigated the behavior of the axial force that it can provide. We have put together a numerical model of the interaction between the permanent magnet and the superconductor that is capable of describing these experimental results semi-quantitatively. Combining direct experimental measurements and using the numerical models proposed, we have achieved a qualitative understanding of the behavior of the axial force and its relationship of to the dimensions of the magnet and material quality such as the homogeneity of the superconductor that constitute the bearing.

Heterofacial alkylation of alkylenediamines by higher alkyl halides

International Nuclear Information System (INIS)

Semenov, V.A.; Kryshko, G.M.; Sokal'skaya, L.I.; Zhukova, N.G.

1985-01-01

A study of the physiochemical properties of alkylenediamines substituted by lower alkyls, showed that they possess increased complex-forming ability with respect to salts of different metals as titanium, niobium, zirconium, molybdenum, and zinc. To create a simpler method of synthesis of higher tetraaklyalkylalklyenediamines, based on the use of the accessible domestic raw material, the authors investigated the reaction of alkylenediamines with various alkyl halides. It was established that the best reagents can be obtained using alkyl bromides. It is concluded that the procedure of alkylation of alkylenediamines by higher alkyl halides in the presence of water developed permits the production of terraalkylalkylenediamines in one step with good yield and with purity acceptable for use as extraction reagents

Electromagnetic properties of metals and superconductors

International Nuclear Information System (INIS)

Sinha, K.P.

1977-01-01

Part 1: Metals. 1. Introduction. 1.1. Normal and anomalous skin effects. 2. Helicons and magneto-plasma waves. 3. Helicon-phonon interaction. 3.1. Magneto-plasma (Alfven) waves. 4. Cyclotron waves. 5. Spin waves in electron system. Part 2: Superconductors. 6. Introduction. 6.1. Response to weak electromagnetic fields. 7. Effect of strong radiation field on superconductors. 8. Laser-induced non-equilibrium state in superconductors. 9. Possibility of photon-induced electron pairing - one-boson processes. 10. Possibility of photon-induced electron pairing -two-boson processes. (author)

Sealed glass coating of high temperature ceramic superconductors

Science.gov (United States)

Wu, Weite; Chu, Cha Y.; Goretta, Kenneth C.; Routbort, Jules L.

1995-01-01

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

Dynamics of superconductor bearings in a cryogenic failure

Energy Technology Data Exchange (ETDEWEB)

Rastogi, Amit [Department of Engineering, Cambridge University, Cambridge CB2 1PZ (United Kingdom)]. E-mail: Amit.Rastogi@avizatechnology.com; Campbell, A.M. [Department of Engineering, Cambridge University, Cambridge CB2 1PZ (United Kingdom); Coombs, T.A. [Department of Engineering, Cambridge University, Cambridge CB2 1PZ (United Kingdom)

2006-08-01

The dynamics of superconductor bearings in a cryogenic failure scenario have been analyzed. As the superconductor warms up, the rotor goes through multiple resonance frequencies, begins to slow down and finally touches down when the superconductor goes through its transition temperature. The bearing can be modelled as a system of springs with axial, radial and cross stiffness. These springs go through various resonant modes as the temperature of the superconductor begins to rise. We have presented possible explanations for such behaviour.

Lasing in robust cesium lead halide perovskite nanowires

Science.gov (United States)

Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A.; Wong, Andrew B.; Dou, Letian; Ma, Jie; Wang, Lin-Wang; Leone, Stephen R.; Yang, Peidong

2016-01-01

The rapidly growing field of nanoscale lasers can be advanced through the discovery of new, tunable light sources. The emission wavelength tunability demonstrated in perovskite materials is an attractive property for nanoscale lasers. Whereas organic–inorganic lead halide perovskite materials are known for their instability, cesium lead halides offer a robust alternative without sacrificing emission tunability or ease of synthesis. Here, we report the low-temperature, solution-phase growth of cesium lead halide nanowires exhibiting low-threshold lasing and high stability. The as-grown nanowires are single crystalline with well-formed facets, and act as high-quality laser cavities. The nanowires display excellent stability while stored and handled under ambient conditions over the course of weeks. Upon optical excitation, Fabry–Pérot lasing occurs in CsPbBr3 nanowires with an onset of 5 μJ cm−2 with the nanowire cavity displaying a maximum quality factor of 1,009 ± 5. Lasing under constant, pulsed excitation can be maintained for over 1 h, the equivalent of 109 excitation cycles, and lasing persists upon exposure to ambient atmosphere. Wavelength tunability in the green and blue regions of the spectrum in conjunction with excellent stability makes these nanowire lasers attractive for device fabrication. PMID:26862172

Quantum confinement effect of two-dimensional all-inorganic halide perovskites

KAUST Repository

Cai, Bo; Li, Xiaoming; Gu, Yu; Harb, Moussab; Li, Jianhai; Xie, Meiqiu; Cao, Fei; Song, Jizhong; Zhang, Shengli; Cavallo, Luigi; Zeng, Haibo

2017-01-01

Quantum confinement effect (QCE), an essential physical phenomenon of semiconductors when the size becomes comparable to the exciton Bohr radius, typically results in quite different physical properties of low-dimensional materials from their bulk counterparts and can be exploited to enhance the device performance in various optoelectronic applications. Here, taking CsPbBr3 as an example, we reported QCE in all-inorganic halide perovskite in two-dimensional (2D) nanoplates. Blue shifts in optical absorption and photoluminescence spectra were found to be stronger in thinner nanoplates than that in thicker nanoplates, whose thickness lowered below ∼7 nm. The exciton binding energy results showed similar trend as that obtained for the optical absorption and photoluminescence. Meanwile, the function of integrated intensity and full width at half maximum and temperature also showed similar results, further supporting our conclusions. The results displayed the QCE in all-inorganic halide perovskite nanoplates and helped to design the all-inorganic halide perovskites with desired optical properties.

Quaternary oxide halides of group 15 with zinc and cadmium

International Nuclear Information System (INIS)

Rueck, Nadia

2014-01-01

The present thesis ''Quaternary oxide halides of group 15 with zinc and cadmium'' deals with the chemical class of oxide halides, which contain d-block element cations and pnicogens. Over the past few years compounds containing pnicogene cations are intensively investigated. The reason for this is the free electron pair of the Pn"3"+ cation, which is responsible for some interesting properties. Free electron pairs do not only impact the spatial structure of molecules but also the properties of materials. The object of this work was the synthesis and characterization of compounds containing Pn"3"+ cations with free electron pairs. Due to the structure-determining effect of these free electron pairs and in combination with halides it is possible to synthesize compounds with low-dimensional structures like chains and layers. In these compounds the structure is separated into halophilic and chalcophilic sub-structures, which are held together only by weak Van der Waals forces.

Quantum confinement effect of two-dimensional all-inorganic halide perovskites

KAUST Repository

Cai, Bo

2017-09-07

Quantum confinement effect (QCE), an essential physical phenomenon of semiconductors when the size becomes comparable to the exciton Bohr radius, typically results in quite different physical properties of low-dimensional materials from their bulk counterparts and can be exploited to enhance the device performance in various optoelectronic applications. Here, taking CsPbBr3 as an example, we reported QCE in all-inorganic halide perovskite in two-dimensional (2D) nanoplates. Blue shifts in optical absorption and photoluminescence spectra were found to be stronger in thinner nanoplates than that in thicker nanoplates, whose thickness lowered below ∼7 nm. The exciton binding energy results showed similar trend as that obtained for the optical absorption and photoluminescence. Meanwile, the function of integrated intensity and full width at half maximum and temperature also showed similar results, further supporting our conclusions. The results displayed the QCE in all-inorganic halide perovskite nanoplates and helped to design the all-inorganic halide perovskites with desired optical properties.

Deformation of high-temperature superconductors

International Nuclear Information System (INIS)

Goretta, K.C.; Routbort, J.L.; Miller, D.J.; Chen, N.; Dominguez-Rodriguez, A.; Jimenez-Melendo, M.; De Arellano-Lopez, A.R.

1994-08-01

Of the many families of high-temperature superconductors, only the properties of those discovered prior to 1989 - Y-Ba-Cu-O, Tl-Ba(Sr)-Ca-Cu-O, and Bi(Pb)-Sr-Ca-Cu-O - have been studied extensively. Deformation tests have been performed on YBa 2 Cu 3 O x (Y-123), YBa 2 Cu 4 O x (Y-124), TlBa 2 Ca 2 Cu 3 O x (Bi-2223). The tests have revealed that plasticity is generally limited in these compounds and that the rate-controlling diffusional kinetics for creep are very slow. Nevertheless, hot forming has proved to be quite successful for fabrication of bulk high-temperature superconductors, so long as deformation rates are low or large hydrostatic stresses are applied. Steady-state creep data have proved to be useful in designing optimal heat treatments for superconductors and in support of more-fundamental diffusion experiments. The high-temperature superconductors are highly complex oxides, and it is a challenge to understand their deformation responses. In this paper, results of interest and operant creep mechanisms will be reviewed

Strain effects in oxide superconductors

International Nuclear Information System (INIS)

Wada, H.; Kuroda, T.; Sekine, H.; Yuyama, M.; Itoh, K.

1991-01-01

Strain sensitivities of superconducting properties are critical to high magnetic field applications of superconductors, since critical temperature, T c , upper critical field, H c2 , and critical current (density), I c (J c ), are all degraded under strains. Oxide superconductors so far known are all very fragile, thus requiring to be fabricated in the form of composite. In the case of practical metallic superconductors, such as Nb 3 Sn and V 3 Ga, the so-called bronze method has been developed where these superconducting intermetallics are enveloped in a ductile metallic sheath. Recently, a fabrication method similar to the bronze method has been developed for the Bi 2 Sr 2 Ca 2 Cu 3 O x superconductors using Ag tubes as sheath. In the present study mono- and multicore BiPbSrCaCuO tape conductors were prepared by means of this Ag-sheath composite method, and examined in terms of strain sensitivity by measuring their T c and I c (J c ) under bending or tensile strains. (orig.)

Iron pnictide superconductors

Energy Technology Data Exchange (ETDEWEB)

Tegel, Marcus Christian

2011-03-22

The scope of this dissertation therefore has not only been the synthesis of various new superconducting and non-superconducting iron pnictides of several structural families but also their in-depth crystallographic and physical characterisation. In Chapters 3 - 6, the family of the ZrCuSiAs-type (1111) compounds is subject of discussion. The solid solution series La(Co{sub x}Fe{sub 1-x})PO is analysed regarding magnetic and superconducting properties and the new compounds EuMnPF and REZnPO, as well as the new superconductor parent compound SrFeAsF are presented. Chapters 7 - 9 are dedicated to the new iron arsenide superconductors of the ThCr{sub 2}Si{sub 2}-type (122 family). Therein, also the discovery of the first superconductor in this structural family, Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2}, is unveiled. A detailed examination of the complete solid solution series (Ba{sub 1-x}K{sub x})Fe{sub 2}As{sub 2} is presented. Moreover, the crystallographic phase transitions of the closely related compounds SrFe{sub 2}As{sub 2} and EuFe{sub 2}As{sub 2} are characterised and the superconductors Sr{sub 1-x}K{sub x}Fe{sub 2}As{sub 2} and Ca{sub 1-x}Na{sub x}Fe{sub 2}As{sub 2} are examined for magnetic and phononic excitations. In Chapter 10, the redetermined crystal structure of the superconductor Fe(Se{sub 1-x}Te{sub x}) (11-type) is presented from a chemist's point of view. Chapters 11 - 14 look into the superconducting and non-superconducting iron arsenides of more complex structural families (32522-type and 21311-type). Therein, crystallographic and magnetic details of Sr{sub 3}Sc{sub 2}O{sub 5}Fe{sub 2}As{sub 2} are presented and Ba{sub 2}ScO{sub 3}FeAs and Sr{sub 2}CrO{sub 3}FeAs, the first two members of the new 21311-type are portrayed. Sr{sub 2}CrO{sub 3}FeAs is looked at in close detail with various methods, so e.g. the spin structure of the magnetically ordered compound is solved and a possible reason for the absence of superconductivity in this compound is

Iron pnictide superconductors

Energy Technology Data Exchange (ETDEWEB)

Tegel, Marcus Christian

2011-03-22

The scope of this dissertation therefore has not only been the synthesis of various new superconducting and non-superconducting iron pnictides of several structural families but also their in-depth crystallographic and physical characterisation. In Chapters 3 - 6, the family of the ZrCuSiAs-type (1111) compounds is subject of discussion. The solid solution series La(Co{sub x}Fe{sub 1-x})PO is analysed regarding magnetic and superconducting properties and the new compounds EuMnPF and REZnPO, as well as the new superconductor parent compound SrFeAsF are presented. Chapters 7 - 9 are dedicated to the new iron arsenide superconductors of the ThCr{sub 2}Si{sub 2}-type (122 family). Therein, also the discovery of the first superconductor in this structural family, Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2}, is unveiled. A detailed examination of the complete solid solution series (Ba{sub 1-x}K{sub x})Fe{sub 2}As{sub 2} is presented. Moreover, the crystallographic phase transitions of the closely related compounds SrFe{sub 2}As{sub 2} and EuFe{sub 2}As{sub 2} are characterised and the superconductors Sr{sub 1-x}K{sub x}Fe{sub 2}As{sub 2} and Ca{sub 1-x}Na{sub x}Fe{sub 2}As{sub 2} are examined for magnetic and phononic excitations. In Chapter 10, the redetermined crystal structure of the superconductor Fe(Se{sub 1-x}Te{sub x}) (11-type) is presented from a chemist's point of view. Chapters 11 - 14 look into the superconducting and non-superconducting iron arsenides of more complex structural families (32522-type and 21311-type). Therein, crystallographic and magnetic details of Sr{sub 3}Sc{sub 2}O{sub 5}Fe{sub 2}As{sub 2} are presented and Ba{sub 2}ScO{sub 3}FeAs and Sr{sub 2}CrO{sub 3}FeAs, the first two members of the new 21311-type are portrayed. Sr{sub 2}CrO{sub 3}FeAs is looked at in close detail with various methods, so e.g. the spin structure of the magnetically ordered compound is solved and a possible reason for the absence of superconductivity in this compound

Superconductors at the nanoscale. From basic research to applications

Energy Technology Data Exchange (ETDEWEB)

Woerdenweber, Roger [Forschungszentrum Juelich GmbH (Germany). Peter Gruenberg Inst.; Moshchalkov, Victor [KU Leuven (Belgium). Inst. for Nanoscale Physics and Chemistry; Bending, Simon [Bath Univ. (United Kingdom). School of Physics; Tafuri, Francesco (ed.) [Seconda Univ. di Napoli, Aversa (Italy)

2017-07-01

By covering theory, design, and fabrication of nanostructured superconducting materials, this monograph is an invaluable resource for research and development. This book contains the following chapters: Tutorial on nanostructured superconductors; Imaging vortices in superconductors: from the atomic scale to macroscopic distances; Probing vortex dynamics on a single vortex level by scanning ac-susceptibility microscopy; STM studies of vortex cores in strongly confined nanoscale superconductors; Type-1.5 superconductivity; Direct visualization of vortex patterns in superconductors with competing vortex-vortex interactions; Vortex dynamics in nanofabricated chemical solution deposition high-temperature superconducting films; Artificial pinning sites and their applications; Vortices at microwave frequencies; Physics and operation of superconducting single-photon devices; Josephson and charging effect in mesoscopic superconducting devices; NanoSQUIDs: Basics and recent advances; Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8} intrinsic Josephson junction stacks as emitters of terahertz radiation; Interference phenomena in superconductor-ferromagnet hybrids; Spin-orbit interactions, spin currents, and magnetization dynamics in superconductor/ferromagnet hybrids; Superconductor/ferromagnet hybrids.

Surface electrostatic waves in bounded high temperature superconductors

International Nuclear Information System (INIS)

Averkov, Yu.O.; Yakovenko, V.M.

2008-01-01

The dispersion relations of surface electrostatic waves propagating along the surface of semi bounded layered superconductor and in the slab of layered superconductor are theoretically investigated. An arbitrary inclination of superconductor layers to the interface of a vacuum - crystal and an arbitrary direction of propagation of surface waves in the plane of the interface are taking into account. The possibility of initiation of an absolute instability during the propagation of a non-relativistic plasma stream above the surface of the layered superconductor is shown

Thorium valency in molten alkali halides in equilibrium with metallic thorium

International Nuclear Information System (INIS)

Smirnov, M.V.; Kudyakov, V.Ya.

1983-01-01

Metallic thorium is shown to corrode in molten alkali halides even in the absence of external oxidizing agents, alkali cations acting as oxidizing agents. Its corrosion rate grows in the series of alkali chlorides from LiCl to CsCl at constant temperature. Substituting halide anions for one another exerts a smaller influence, the rate rising slightly in going from chlorides to bromides and iodides, having the same alkali cations. Thorium valency is determined coulometrically, the metal being dissolved anodically in molten alkali halides and their mixtures. In fluoride melts it is equal to 4 but in chloride, bromide and iodide ones, as a rule, it has non-integral values between 4 and 2 which diminish as the temperature is raised, as the thorium concentration is lowered, as the radii of alkali cations decrease and those of halide anions increase. The emf of cells Th/N ThHlsub(n) + (1-N) MHl/MHl/C, Hlsub(2(g)) where Hl is Cl, Br or I, M is Li, Na, K, Cs or Na + K, and N < 0.05, is measured as a function of concentration at several temperatures. Expressions are obtained for its concentration dependence. The emf grows in the series of alkali chlorides from LiCl to CsCl, other conditions being equal. (author)

Low resistivity contact to iron-pnictide superconductors

Science.gov (United States)

Tanatar, Makariy; Prozorov, Ruslan; Ni, Ni; Bud& #x27; ko, Sergey; Canfield, Paul

2013-05-28

Method of making a low resistivity electrical connection between an electrical conductor and an iron pnictide superconductor involves connecting the electrical conductor and superconductor using a tin or tin-based material therebetween, such as using a tin or tin-based solder. The superconductor can be based on doped AFe.sub.2As.sub.2, where A can be Ca, Sr, Ba, Eu or combinations thereof for purposes of illustration only.

Photothermal measurements of superconductors

International Nuclear Information System (INIS)

Kino, G.S.; Wu, X.D.; Kapitulnik, A.; Fishman, I.

1993-01-01

The authors have developed a new photothermal technique to investigate electronic phase transitions of high temperature superconductors. The phase shift of the thermal wave yields the anisotropic thermal diffusivity coefficient of the sample. The amplitude of the photothermal signal is sensitive to electronic phase transitions of the second kind. The technique is completely noncontacting and nondestructive, and is well suited to measure small and fragile single-crystal high-T c superconductors. The measurements give good agreement with fluctuation theory near the transition temperature. They have studied diffusion in, and superconducting fluctuations of, single crystals of YBa 2 Cu 3 O 7-δ and Bi 2 Sr 2 CaCu 2 O 8 . Both systems show fluctuation effects beyond Gaussian fluctuations. While YBa 2 Cu 3 O 7-δ behaves as a three-dimensional anisotropic superconductor, results on Bi 2 Sr 2 CaCu 2 O 8 indicate strong two-dimensional effects

Transfer Hydro-dehalogenation of Organic Halides Catalyzed by Ruthenium(II) Complex.

Science.gov (United States)

You, Tingjie; Wang, Zhenrong; Chen, Jiajia; Xia, Yuanzhi

2017-02-03

A simple and efficient Ru(II)-catalyzed transfer hydro-dehalogenation of organic halides using 2-propanol solvent as the hydride source was reported. This methodology is applicable for hydro-dehalogenation of a variety of aromatic halides and α-haloesters and amides without additional ligand, and quantitative yields were achieved in many cases. The potential synthetic application of this method was demonstrated by efficient gram-scale transformation with catalyst loading as low as 0.5 mol %.

GaN/NbN epitaxial semiconductor/superconductor heterostructures

Science.gov (United States)

Yan, Rusen; Khalsa, Guru; Vishwanath, Suresh; Han, Yimo; Wright, John; Rouvimov, Sergei; Katzer, D. Scott; Nepal, Neeraj; Downey, Brian P.; Muller, David A.; Xing, Huili G.; Meyer, David J.; Jena, Debdeep

2018-03-01

Epitaxy is a process by which a thin layer of one crystal is deposited in an ordered fashion onto a substrate crystal. The direct epitaxial growth of semiconductor heterostructures on top of crystalline superconductors has proved challenging. Here, however, we report the successful use of molecular beam epitaxy to grow and integrate niobium nitride (NbN)-based superconductors with the wide-bandgap family of semiconductors—silicon carbide, gallium nitride (GaN) and aluminium gallium nitride (AlGaN). We apply molecular beam epitaxy to grow an AlGaN/GaN quantum-well heterostructure directly on top of an ultrathin crystalline NbN superconductor. The resulting high-mobility, two-dimensional electron gas in the semiconductor exhibits quantum oscillations, and thus enables a semiconductor transistor—an electronic gain element—to be grown and fabricated directly on a crystalline superconductor. Using the epitaxial superconductor as the source load of the transistor, we observe in the transistor output characteristics a negative differential resistance—a feature often used in amplifiers and oscillators. Our demonstration of the direct epitaxial growth of high-quality semiconductor heterostructures and devices on crystalline nitride superconductors opens up the possibility of combining the macroscopic quantum effects of superconductors with the electronic, photonic and piezoelectric properties of the group III/nitride semiconductor family.

Environmental Effects on the Photophysics of Organic-Inorganic Halide Perovskites.

Science.gov (United States)

Galisteo-López, Juan F; Anaya, M; Calvo, M E; Míguez, H

2015-06-18

The photophysical properties of films of organic-inorganic lead halide perovskites under different ambient conditions are herein reported. We demonstrate that their luminescent properties are determined by the interplay between photoinduced activation and darkening processes, which strongly depend on the atmosphere surrounding the samples. We have isolated oxygen and moisture as the key elements in each process, activation and darkening, both of which involve the interaction with photogenerated carriers. These findings show that environmental factors play a key role in the performance of lead halide perovskites as efficient luminescent materials.

Advancement on Lead-Free Organic-Inorganic Halide Perovskite Solar Cells: A Review.

Science.gov (United States)

Sani, Faruk; Shafie, Suhaidi; Lim, Hong Ngee; Musa, Abubakar Ohinoyi

2018-06-14

Remarkable attention has been committed to the recently discovered cost effective and solution processable lead-free organic-inorganic halide perovskite solar cells. Recent studies have reported that, within five years, the reported efficiency has reached 9.0%, which makes them an extremely promising and fast developing candidate to compete with conventional lead-based perovskite solar cells. The major challenge associated with the conventional perovskite solar cells is the toxic nature of lead (Pb) used in the active layer of perovskite material. If lead continues to be used in fabricating solar cells, negative health impacts will result in the environment due to the toxicity of lead. Alternatively, lead free perovskite solar cells could give a safe way by substituting low-cost, abundant and non toxic material. This review focuses on formability of lead-free organic-inorganic halide perovskite, alternative metal cations candidates to replace lead (Pb), and possible substitutions of organic cations, as well as halide anions in the lead-free organic-inorganic halide perovskite architecture. Furthermore, the review gives highlights on the impact of organic cations, metal cations and inorganic anions on stability and the overall performance of lead free perovskite solar cells.

Topological superconductors: a review.

Science.gov (United States)

Sato, Masatoshi; Ando, Yoichi

2017-07-01

This review elaborates pedagogically on the fundamental concept, basic theory, expected properties, and materials realizations of topological superconductors. The relation between topological superconductivity and Majorana fermions are explained, and the difference between dispersive Majorana fermions and a localized Majorana zero mode is emphasized. A variety of routes to topological superconductivity are explained with an emphasis on the roles of spin-orbit coupling. Present experimental situations and possible signatures of topological superconductivity are summarized with an emphasis on intrinsic topological superconductors.

Metal induced gap states at alkali halide/metal interface

International Nuclear Information System (INIS)

Kiguchi, Manabu; Yoshikawa, Genki; Ikeda, Susumu; Saiki, Koichiro

2004-01-01

The electronic state of a KCl/Cu(0 0 1) interface was investigated using the Cl K-edge near-edge X-ray absorption fine structure (NEXAFS). A pre-peak observed on the bulk edge onset of thin KCl films has a similar feature to the peak at a LiCl/Cu(0 0 1) interface, which originates from the metal induced gap state (MIGS). The present result indicates that the MIGS is formed universally at alkali halide/metal interfaces. The decay length of MIGS to an insulator differs from each other, mainly due to the difference in the band gap energy of alkali halide

Neutron-scattering studies of magnetic superconductors

International Nuclear Information System (INIS)

Sinha, S.K.; Crabtree, G.W.; Hinks, D.G.; Mook, H.A.; Pringle, O.A.

1982-01-01

Results obtained in the last few years obtained by neutron diffraction on the nature of the magnetic ordering in magnetic superconductors are reviewed. Emphasis is given to studies of the complex intermediate phase in ferromagnetic superconductors where both superconductivity and ferromagnetism appear to coexist

Ground state, collective mode, phase soliton and vortex in multiband superconductors.

Science.gov (United States)

Lin, Shi-Zeng

2014-12-10

This article reviews theoretical and experimental work on the novel physics in multiband superconductors. Multiband superconductors are characterized by multiple superconducting energy gaps in different bands with interaction between Cooper pairs in these bands. The discovery of prominent multiband superconductors MgB2 and later iron-based superconductors, has triggered enormous interest in multiband superconductors. The most recently discovered superconductors exhibit multiband features. The multiband superconductors possess novel properties that are not shared with their single-band counterpart. Examples include: the time-reversal symmetry broken state in multiband superconductors with frustrated interband couplings; the collective oscillation of number of Cooper pairs between different bands, known as the Leggett mode; and the phase soliton and fractional vortex, which are the main focus of this review. This review presents a survey of a wide range of theoretical exploratory and experimental investigations of novel physics in multiband superconductors. A vast amount of information derived from these studies is shown to highlight unusual and unique properties of multiband superconductors and to reveal the challenges and opportunities in the research on the multiband superconductivity.

Metal halides vapor lasers with inner reactor and small active volume.

Science.gov (United States)

Shiyanov, D. V.; Sukhanov, V. B.; Evtushenko, G. S.

2018-04-01

Investigation of the energy characteristics of copper, manganese, lead halide vapor lasers with inner reactor and small active volume 90 cm3 was made. The optimal operating pulse repetition rates, temperatures, and buffer gas pressure for gas discharge tubes with internal and external electrodes are determined. Under identical pump conditions, such systems are not inferior in their characteristics to standard metal halide vapor lasers. It is shown that the use of a zeolite halogen generator provides lifetime laser operation.

Silver halide photographic material providing an image and an unsharp mask

International Nuclear Information System (INIS)

Broadhead, P.; Farnell, G.C.

1981-01-01

Desirable edge effects are produced by normal imagewise exposure and processing of a sensitive radiographic film comprising a transparent film support bearing a layer of a direct-positive silver halide emulsion and a layer of a negative silver halide emulsion and wherein the film comprises means to reduce crossover between the two emulsion layers, one of said emulsion layers being adapted to record a primary image and the other being adapted to record an unsharp mask image. (author)

Monocrystalline halide perovskite nanostructures for optoelectronic applications

NARCIS (Netherlands)

Khoram, P.

2018-01-01

Halide perovskites are a promising class of materials for incorporation in optoelectronics with higher efficiency and lower cost. The solution processability of these materials provides unique opportunities for simple nanostructure fabrication. In the first half of the thesis (chapter 2 and 3) we

Reactivity of halide and pseudohalide ligands

International Nuclear Information System (INIS)

Kukushkin, Yu.N.

1987-01-01

Reactivity of halide and pseudohalide (cyanide, azide, thiocyanate, cyanate) ligands tending to form bridge bonds in transition metal (Re, Mo, W) complexes is considered. Complexes where transition metal salts are ligands of other, complex-forming ion, are described. Transformation of innerspheric pseudohalide ligands is an important way of directed synthesis of these metal coordination compounds

Vibrational Spectra of Discrete UO22+ Halide Complexes in the Gas Phase

International Nuclear Information System (INIS)

Groenewold, G.S.; Van Stipdonk, Michael J.; Oomens, Jos; De Jong, Wibe A.; Gresham, Garold L.; Mcilwain, Michael

2010-01-01

The intrinsic binding of halide ions to the metal center in the uranyl molecule is a topic of ongoing research interest in both the actinide separations and theoretical communities. Investigations of structure in the condensed phases is frequently obfuscated by solvent interactions that can alter ligand binding and spectroscopic properties. The approach taken in this study is to move the uranyl halide complexes into the gas phase where they are free from solvent interactions, and then interrogate their vibrational spectroscopy using infrared multiple photon dissociation (IRMPD). The spectra of cationic coordination complexes having the composition (UO 2 (X)(ACO) 3 ) + (where X = F, Cl, Br and I; ACO = acetone) were acquired using electrospray for ion formation, and monitoring the ion signal from the photoelimination of ACO ligands. The studies showed that the asymmetric ν 3 UO 2 frequency was insensitive to halide identity as X was varied from Cl to I, suggesting that in these pseudo-octahedral complexes, changing the nucleophilicity of the halide did not appreciably alter its binding in the complex. The ν 3 peak in the spectrum of the F-containing complex was 9 cm -1 lower indicating stronger coordination in this complex. Similarly the ACO carbonyl stretches showed that the C=O frequency was relatively insensitive to the identity of the halide, although a modest shift to higher wavenumber was seen for the complexes with the more nucleophilic anions, consistent with the idea that they loosen solvent binding. Surprisingly, the ν 1 stretch was activated when the softer anions Cl, Br and I were present in the complexes. IR studies of the anionic complexes (UO 2 X 3 ) - (where X = Cl - , Br - and I - ) compared the ν 3 UO 2 modes versus halide, and showed that the ν 3 values decreased with increasing anion nucleophilicity. This observation was consistent with DFT calculations that indicated that (UO 2 X 2 ) - -X, and (UO 2 X 2 )·-X - dissociation energies

A Double-Decker Levitation Experiment Using a Sandwich of Superconductors.

Science.gov (United States)

Jacob, Anthony T.; And Others

1988-01-01

Shows that the mutual repulsion that enables a superconductor to levitate a magnet and a magnet to levitate a superconductor can be combined into a single demonstration. Uses an overhead projector, two pellets of "1-2-3" superconductor, Nd-Fe-B magnets, liquid nitrogen, and paraffin. Offers superconductor preparation, hazards, and disposal…

Electrochemically reduced titanocene dichloride as a catalyst of reductive dehalogenation of organic halides

International Nuclear Information System (INIS)

Magdesieva, Tatiana V.; Graczyk, Magdalena; Vallat, Alain; Nikitin, Oleg M.; Demyanov, Petr I.; Butin, Kim P.; Vorotyntsev, Mikhail A.

2006-01-01

We have studied a reaction between the reduced form of titanocene dichloride (Cp 2 TiCl 2 ) and a group of organic halides: benzyl derivatives (4-X-C 6 H 4 CH 2 Cl, X = H, NO 2 , CH 3 ; 4-X-C 6 H 4 CH 2 Br, X = H, NO 2 , PhC(O); 4-X-C 6 H 4 CH 2 SCN, X = H, NO 2 ) as well as three aryl halides (4-NO 2 C 6 H 4 Hal, Hal = Cl, Br; 4-CH 3 O-C 6 H 4 Cl). It has been shown that the electrochemical reduction of Cp 2 TiCl 2 in the presence of these benzyl halides leads to a catalytic cycle resulting in the reductive dehalogenation of these organic substrates to yield mostly corresponding toluene derivatives as the main product. No dehalogenation has been observed for aryl derivatives. Based on electrochemical data and digital simulation, possible schemes of the catalytic process have been outlined. For non-substituted benzyl halides halogen atom abstraction is a key step. For the reaction of nitrobenzyl halides the complexation of Ti(III) species with the nitro group takes place, with the electron transfer from Ti(III) to this group (owing to its highest coefficient in LUMO of the nitro benzyl halide) followed by an intramolecular dissociative electron redistribution in the course of the heterolytic C-Hal bond cleavage. The results for reduced titanocene dichloride centers immobilized inside a polymer film showed that the catalytic reductive dehalogenation of the p-nitrobenzyl chloride does occur but with a low efficiency because of the partial deactivation of the film due to the blocking of the electron charge transport between the electrode and catalytic centers

Electrochemically reduced titanocene dichloride as a catalyst of reductive dehalogenation of organic halides

Energy Technology Data Exchange (ETDEWEB)

Magdesieva, Tatiana V. [Department Chemistry, M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation)]. E-mail: tvm@org.chem.msu.ru; Graczyk, Magdalena [LSEO-UMR 5188 CNRS, Universite de Bourgogne, Dijon (France); Vallat, Alain [LSEO-UMR 5188 CNRS, Universite de Bourgogne, Dijon (France); Nikitin, Oleg M. [Department Chemistry, M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation); Demyanov, Petr I. [Department Chemistry, M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation); Butin, Kim P. [Department Chemistry, M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation); Vorotyntsev, Mikhail A. [LSEO-UMR 5188 CNRS, Universite de Bourgogne, Dijon (France)]. E-mail: MV@u-bourgogne.fr

2006-11-12

We have studied a reaction between the reduced form of titanocene dichloride (Cp{sub 2}TiCl{sub 2}) and a group of organic halides: benzyl derivatives (4-X-C{sub 6}H{sub 4}CH{sub 2}Cl, X = H, NO{sub 2}, CH{sub 3}; 4-X-C{sub 6}H{sub 4}CH{sub 2}Br, X = H, NO{sub 2}, PhC(O); 4-X-C{sub 6}H{sub 4}CH{sub 2}SCN, X = H, NO{sub 2}) as well as three aryl halides (4-NO{sub 2}C{sub 6}H{sub 4}Hal, Hal = Cl, Br; 4-CH{sub 3}O-C{sub 6}H{sub 4}Cl). It has been shown that the electrochemical reduction of Cp{sub 2}TiCl{sub 2} in the presence of these benzyl halides leads to a catalytic cycle resulting in the reductive dehalogenation of these organic substrates to yield mostly corresponding toluene derivatives as the main product. No dehalogenation has been observed for aryl derivatives. Based on electrochemical data and digital simulation, possible schemes of the catalytic process have been outlined. For non-substituted benzyl halides halogen atom abstraction is a key step. For the reaction of nitrobenzyl halides the complexation of Ti(III) species with the nitro group takes place, with the electron transfer from Ti(III) to this group (owing to its highest coefficient in LUMO of the nitro benzyl halide) followed by an intramolecular dissociative electron redistribution in the course of the heterolytic C-Hal bond cleavage. The results for reduced titanocene dichloride centers immobilized inside a polymer film showed that the catalytic reductive dehalogenation of the p-nitrobenzyl chloride does occur but with a low efficiency because of the partial deactivation of the film due to the blocking of the electron charge transport between the electrode and catalytic centers.

Impurities and conductivity in a D-wave superconductor

International Nuclear Information System (INIS)

Balatsky, A.V.

1994-01-01

Impurity scattering in the unitary limit produces low energy quasiparticles with anisotropic spectrum in a two-dimensional d-wave superconductor. The authors describe a new quasi-one-dimensional limit of the quasiparticle scattering, which might occur in a superconductor with short coherence length and with finite impurity potential range. The dc conductivity in a d-wave superconductor is predicted to be proportional to the normal state scattering rate and is impurity-dependent. They show that quasi-one-dimensional regime might occur in high-T c superconductors with Zn impurities at low temperatures T approx-lt 10 K

The color of polarization in cuprate superconductors

International Nuclear Information System (INIS)

Hoff, H.A.; Osofsky, M.S.; Lechter, W.L.; Pande, C.S.

1991-01-01

A technique for the identification of individual anisotropic grains in a heterogeneous and opaque material involves the observation of grain color in reflected light through crossed polarizers (color of polarization). Such colors are generally characteristic of particular phases. When grains of many members of the class of hole carrier cuprate superconductors are so viewed at room temperature with a 'daylight' source, a characteristic color of polarization is observed. This color was studied in many of these cuprate superconductors and a strong correlation was found between color and the existence of superconductivity. Two members were also examined of the electron cuprate superconductors and it was found that they possess the same color of polarization as the hole carrier cuprate superconductors so far examined. The commonality of the characteristic color regardless of charge carrier indicates that the presence of this color is independent of carrier type. The correlation of this color with the existence of superconductivity in the cuprate superconductors suggests that the origin of the color relates to the origin of superconductivity. Photometric techniques are also discussed

Out-of-equilibrium spin transport in mesoscopic superconductors.

Science.gov (United States)

Quay, C H L; Aprili, M

2018-08-06

The excitations in conventional superconductors, Bogoliubov quasi-particles, are spin-[Formula: see text] fermions but their charge is energy-dependent and, in fact, zero at the gap edge. Therefore, in superconductors (unlike normal metals) spin and charge degrees of freedom may be separated. In this article, we review spin injection into conventional superconductors and focus on recent experiments on mesoscopic superconductors. We show how quasi-particle spin transport and out-of-equilibrium spin-dependent superconductivity can be triggered using the Zeeman splitting of the quasi-particle density of states in thin-film superconductors with small spin-mixing scattering. Finally, we address the spin dynamics and the feedback of quasi-particle spin imbalances on the amplitude of the superconducting energy gap.This article is part of the theme issue 'Andreev bound states'. © 2018 The Author(s).

Direct ToF-SIMS analysis of organic halides and amines on TLC plates

Energy Technology Data Exchange (ETDEWEB)

Parent, Alexander A. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602 (United States); Anderson, Thomas M. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602 (United States); Michaelis, David J. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602 (United States); Jiang, Guilin [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602 (United States); Savage, Paul B. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602 (United States); Linford, Matthew R. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602 (United States)]. E-mail: mrlinford@chem.byu.edu

2006-07-30

It has been reported that: 'direct analysis of thin layer chromatography (TLC) plates with secondary ion mass spectrometry (SIMS) yields no satisfactory results' (J. Chromatogr. A 1084 (2005) 113-118). While this statement appears to be true in general, we have identified two important classes of compounds, organic halides and amines, that appear to yield to such direct analyses. For example, five organic halides with diverse structures were eluted on normal phase TLC plates. In all cases the halide signals in the negative ion time-of-flight secondary ion mass spectrometry (ToF-SIMS) spectra were notably stronger than the background signals. Similarly, a series of five organic amines with diverse structures were directly analyzed by positive ion ToF-SIMS. In all but one of the spectra characteristic, and sometimes even quasi-molecular ions, were observed. Most likely, the good halide ion yields are largely a function of the electronegativity of the halogens. We also propose that direct analysis of amines on normal phase silica gel is facilitated by the acidity, i.e., proton donation, of surface silanol groups.

Direct ToF-SIMS analysis of organic halides and amines on TLC plates

International Nuclear Information System (INIS)

Parent, Alexander A.; Anderson, Thomas M.; Michaelis, David J.; Jiang, Guilin; Savage, Paul B.; Linford, Matthew R.

2006-01-01

It has been reported that: 'direct analysis of thin layer chromatography (TLC) plates with secondary ion mass spectrometry (SIMS) yields no satisfactory results' (J. Chromatogr. A 1084 (2005) 113-118). While this statement appears to be true in general, we have identified two important classes of compounds, organic halides and amines, that appear to yield to such direct analyses. For example, five organic halides with diverse structures were eluted on normal phase TLC plates. In all cases the halide signals in the negative ion time-of-flight secondary ion mass spectrometry (ToF-SIMS) spectra were notably stronger than the background signals. Similarly, a series of five organic amines with diverse structures were directly analyzed by positive ion ToF-SIMS. In all but one of the spectra characteristic, and sometimes even quasi-molecular ions, were observed. Most likely, the good halide ion yields are largely a function of the electronegativity of the halogens. We also propose that direct analysis of amines on normal phase silica gel is facilitated by the acidity, i.e., proton donation, of surface silanol groups

Radiation damage in the alkali halide crystals

International Nuclear Information System (INIS)

Diller, K.M.

1975-10-01

A general review is given of the experimental data on radiation damage in the alkali halide crystals. A report is presented of an experimental investigation of irradiation produced interstitial dislocation loops in NaCl. These loops are found to exhibit the usual growth and coarsening behaviour during thermal annealing which operates by a glide and self-climb mechanism. It is shown that the recombination of defects in these crystals is a two stage process, and that the loss of interstitials stabilized at the loops is caused by extrinsic vacancies. The theoretical techniques used in simulating point defects in ionic crystals are described. Shell model potentials are derived for all the alkali halide crystals by fitting to bulk crystal data. The fitting is supplemented by calculations of the repulsive second neighbour interactions using methods based on the simple electron gas model. The properties of intrinsic and substitutional impurity defects are calculated. The HADES computer program is used in all the defect calculations. Finally the report returns to the problems of irradiation produced interstitial defects. The properties of H centres are discussed; their structure, formation energies, trapping at impurities and dimerization. The structure, formation energies and mobility of the intermediate and final molecular defects are then discussed. The thermodynamics of interstitial loop formation is considered for all the alklai halide crystals. The nucleation of interstitial loops in NaCl and NaBr is discussed, and the recombination of interstitial and vacancy defects. The models are found to account for all the main features of the experimental data. (author)

Topological insulators and superconductors from string theory

International Nuclear Information System (INIS)

Ryu, Shinsei; Takayanagi, Tadashi

2010-01-01

Topological insulators and superconductors in different spatial dimensions and with different discrete symmetries have been fully classified recently, revealing a periodic structure for the pattern of possible types of topological insulators and superconductors, both in terms of spatial dimensions and in terms of symmetry classes. It was proposed that K theory is behind the periodicity. On the other hand, D-branes, a solitonic object in string theory, are also known to be classified by K theory. In this paper, by inspecting low-energy effective field theories realized by two parallel D-branes, we establish a one-to-one correspondence between the K-theory classification of topological insulators/superconductors and D-brane charges. In addition, the string theory realization of topological insulators and superconductors comes naturally with gauge interactions, and the Wess-Zumino term of the D-branes gives rise to a gauge field theory of topological nature, such as ones with the Chern-Simons term or the θ term in various dimensions. This sheds light on topological insulators and superconductors beyond noninteracting systems, and the underlying topological field theory description thereof. In particular, our string theory realization includes the honeycomb lattice Kitaev model in two spatial dimensions, and its higher-dimensional extensions. Increasing the number of D-branes naturally leads to a realization of topological insulators and superconductors in terms of holography (AdS/CFT).

Static Properties of Superconductor Journal Bearing Substator for Superconductor Flywheel Energy Storage System

International Nuclear Information System (INIS)

Park, B. J.; Jung, S. Y.; Lee, J. P.; Park, B. C.; Jeong, N. H.; Sung, T. H.; Han, Y. H.

2008-01-01

A Superconductor Flywheel Energy Storage System(SFES) mainly consists of a pair of non-contacting High Temperature Superconductor(HTS) bearings that provide very low frictional losses, a composite flywheel with high energy storage density. The HTS bearings, which offer dynamic stability without active control, are the key technology that distinguishes the SFES from other flywheel energy storage devices, and great effort is being put into developing this technology. The Superconductor Journal Bearing(SJB) mainly consists of HTS bulks and a stator, which holds the HTS bulks and also acts as a cold head. Static properties of HTS bearings provide data to solve problems which may occur easily in a running system. Since stiffness to counter vibration is the main parameter in designing an HTS bearing system, we investigate SJB magnetic force through static properties between the Permanent Magnet(PM) and HTS. We measure stiffness in static condition and the results are used to determine the optimal number of HTS bulks for a 100kWh SFES.

Ternary superconductors

International Nuclear Information System (INIS)

Giorgi, A.L.

1987-01-01

Ternary superconductors constitute a class of superconducting compounds with exceptional properties such as high transition temperatures (≅ 15.2 K), extremely high critical fields (H c2 >60 Tesla), and the coexistence of superconductivity and long-range magnetic order. This has generated great interest in the scientific community and resulted in a large number of experimental and theoretical investigations in which many new ternary compounds have been discovered. A review of some of the properties of these ternary compounds is presented with particular emphasis on the ternary molybdenum chalcogenides and the ternary rare earth transition metal tetraborides. The effect of partial substitution of a second metal atom to form pseudoternary compounds is examined as well as some of the proposed correlations between the superconducting transition temperature and the structural and electronic properties of the ternary superconductors

Design study of SMES system using high temperature superconductors

International Nuclear Information System (INIS)

Yoshihara, T.; Masuda, M.; Shintomi, T.; Hasegawa, J.

1988-01-01

Various studies of high Tc superconductors are being energetically pursued all over the world, since IBM Zurich Research Laboratory reported on the superconducting oxide. A new design using a high Tc superconductor is under study for 5000 MWh, on the assumption that it is available like conventional superconductors. Problems related to the Tc SMES system, mainly thermal insulation, refrigeration system, stability of superconductors, etc., are considered. Some design examples of high Tc SMES system are proposed

The critical current of granular superconductor

International Nuclear Information System (INIS)

Ignat'ev, V.K.

1998-01-01

A mechanism of hyper vortex pinning in granular superconductors is proposed to describe the field dependence of the critical current density and pinning potential. The results are in a good agreement with the experiment. The model represents the peak effect and the percolation mechanism of conductivity in ceramic superconductors

Compact terahertz passive spectrometer with wideband superconductor-insulator-superconductor mixer.

Science.gov (United States)

Kikuchi, K; Kohjiro, S; Yamada, T; Shimizu, N; Wakatsuki, A

2012-02-01

We developed a compact terahertz (THz) spectrometer with a superconductor-insulator-superconductor (SIS) mixer, aiming to realize a portable and highly sensitive spectrometer to detect dangerous gases at disaster sites. The receiver cryostat which incorporates the SIS mixer and a small cryocooler except for a helium compressor has a weight of 27 kg and dimensions of 200 mm × 270 mm × 690 mm. In spite of the small cooling capacity of the cryocooler, the SIS mixer is successfully cooled lower than 4 K, and the temperature variation is suppressed for the sensitive measurement. By adopting a frequency sweeping system using photonic local oscillator, we demonstrated a spectroscopic measurement of CH(3)CN gas in 0.2-0.5 THz range.

An unconventional colour superconductor

International Nuclear Information System (INIS)

Huang Mei

2007-01-01

Superfluidity, or superconductivity with mismatched Fermi momenta, appears in many systems such as charge-neutral dense quark matter, asymmetric nuclear matter, and in imbalanced cold atomic gases. The mismatch plays the role of breaking the Cooper pairing, and the pair-breaking state cannot be properly described in the framework of standard BCS theory. I give a brief review on recent theoretical developments in understanding unconventional colour superconductivity, including a gapless colour superconductor, chromomagnetic instabilities and the Higgs instability in the gapless phase. I also introduce a possible new framework for describing an unconventional colour superconductor

Local coordination of polyvalent metal ions in molten halide mixtures

International Nuclear Information System (INIS)

Akdeniz, Z.; Tosi, M.P.

1989-07-01

Ample experimental evidence is available in the literature on the geometry and the stability of local coordination for polyvalent metal ions in molten mixtures of their halides with alkali halides. Recent schemes for classifying this evidence are discussed. Dissociation of tetrahedral halocomplexes in good ionic systems can be viewed as a classical Mott problem of bound-state stability in a conducting matrix. More generally, structural coordinates can be constructed from properties of the component elements, to separate out systems with long-lived fourfold or sixfold coordination and to distinguish between these. (author). 11 refs, 1 fig

Thallous and cesium halide materials for use in cryogenic applications

International Nuclear Information System (INIS)

Lawless, W.N.

1983-01-01

Certain thallous and cesium halides, either used alone or in combination with other ceramic materials, are provided in cryogenic applications such as heat exchange material for the regenerator section of a closed-cycle cryogenic refrigeration section, as stabilizing coatings for superconducting wires, and as dielectric insulating materials. The thallous and cesium halides possess unusually large specific heats at low temperatures, have large thermal conductivities, are nonmagnetic, and are nonconductors of electricity. They can be formed into a variety of shapes such as spheres, bars, rods, or the like and can be coated or extruded onto substrates or wires. (author)

Development and melt growth of novel scintillating halide crystals

Science.gov (United States)

Yoshikawa, Akira; Yokota, Yuui; Shoji, Yasuhiro; Kral, Robert; Kamada, Kei; Kurosawa, Shunsuke; Ohashi, Yuji; Arakawa, Mototaka; Chani, Valery I.; Kochurikhin, Vladimir V.; Yamaji, Akihiro; Andrey, Medvedev; Nikl, Martin

2017-12-01

Melt growth of scintillating halide crystals is reviewed. The vertical Bridgman growth technique is still considered as very popular method that enables production of relatively large and commercially attractive crystals. On the other hand, the micro-pulling-down method is preferable when fabrication of small samples, sufficient for preliminary characterization of their optical and/or scintillation performance, is required. Moreover, bulk crystal growth is also available using the micro-pulling-down furnace. The examples of growths of various halide crystals by industrially friendly melt growth techniques including Czochralski and edge-defined film-fed growth methods are also discussed. Finally, traveling molten zone growth that in some degree corresponds to horizontal zone melting is briefly overviewed.

Alkali Halide Microstructured Optical Fiber for X-Ray Detection

Science.gov (United States)

DeHaven, S. L.; Wincheski, R. A.; Albin, S.

2014-01-01

Microstructured optical fibers containing alkali halide scintillation materials of CsI(Na), CsI(Tl), and NaI(Tl) are presented. The scintillation materials are grown inside the microstructured fibers using a modified Bridgman-Stockbarger technique. The x-ray photon counts of these fibers, with and without an aluminum film coating are compared to the output of a collimated CdTe solid state detector over an energy range from 10 to 40 keV. The photon count results show significant variations in the fiber output based on the materials. The alkali halide fiber output can exceed that of the CdTe detector, dependent upon photon counter efficiency and fiber configuration. The results and associated materials difference are discussed.

Formation of structured nanophases in halide crystals

Czech Academy of Sciences Publication Activity Database

Kulveit, Jan; Demo, Pavel; Polák, Karel; Sveshnikov, Alexey; Kožíšek, Zdeněk

2013-01-01

Roč. 5, č. 6 (2013), s. 561-564 ISSN 2164-6627 R&D Projects: GA ČR GAP108/12/0891 Institutional support: RVO:68378271 Keywords : halide crystals * nucleation Subject RIV: BM - Solid Matter Physics ; Magnetism http://www.aspbs.com/asem.html#v5n6

Theory of the electric current transmission coefficient in the superconductor-insulator-superconductor geometry

International Nuclear Information System (INIS)

Navani, R.

1974-01-01

Tunneling in the superconductor-insulator-superconductor (S'-I-S) geometry, where the two superconductors are not necessarily the same, is studied theoretically. Two different models of the S'-I-S geometry - which we call the ''initial model'' and the ''improved model'' are discussed. For the initial model the potential barrier is flat. In the improved model, however, the differing material properties of the three regions - S', I, and S - are taken into account in an approximate fashion. In addition, applied, contact, and image potentials in the insulator are included. The solid state material properties that are taken to be different are the effective electronic masses in the three regions and the Fermi energies in the two superconductors. The quasiparticle wave functions in the S', I, and S regions are determined for both models as solutions to the Bogoliubov-de Gennes equations. The electric current transmission coefficients (also the reflection coefficient for the initial model) are derived and their behavior is extensively analyzed. Their forms in the thick barrier limit - where L greater than or approximately equal to 5 A - are related to the BCS densities of states. The tunneling current density is found to depend strongly on the tunneling angle. A relation between the angular position of the tunneling current peak and the barrier thickness is given. Finally, it is shown that the choice of insulator material effects the tunneling current, and the effect is greater the thicker the insulating film

Determination of the structural phase and octahedral rotation angle in halide perovskites

Science.gov (United States)

dos Reis, Roberto; Yang, Hao; Ophus, Colin; Ercius, Peter; Bizarri, Gregory; Perrodin, Didier; Shalapska, Tetiana; Bourret, Edith; Ciston, Jim; Dahmen, Ulrich

2018-02-01

A key to the unique combination of electronic and optical properties in halide perovskite materials lies in their rich structural complexity. However, their radiation sensitive nature limits nanoscale structural characterization requiring dose efficient microscopic techniques in order to determine their structures precisely. In this work, we determine the space-group and directly image the Br halide sites of CsPbBr3, a promising material for optoelectronic applications. Based on the symmetry of high-order Laue zone reflections of convergent-beam electron diffraction, we identify the tetragonal (I4/mcm) structural phase of CsPbBr3 at cryogenic temperature. Electron ptychography provides a highly sensitive phase contrast measurement of the halide positions under low electron-dose conditions, enabling imaging of the elongated Br sites originating from the out-of-phase octahedral rotation viewed along the [001] direction of I4/mcm persisting at room temperature. The measurement of these features and comparison with simulations yield an octahedral rotation angle of 6.5°(±1.5°). The approach demonstrated here opens up opportunities for understanding the atomic scale structural phenomena applying advanced characterization tools on a wide range of radiation sensitive halide-based all-inorganic and hybrid organic-inorganic perovskites.

Solvation structures of lithium halides in methanol–water mixtures

International Nuclear Information System (INIS)

Sarkar, Atanu; Dixit, Mayank Kumar; Tembe, B.L.

2015-01-01

Highlights: • Potentials of mean force for Li + -halides are calculated in methanol–water mixtures. • Stable CIP for x methanol = 1.0 becomes unstable at and below x methanol = 0.75. • The Li + ion is preferentially solvated by methanol molecules. • The halide ions are preferentially solvated by water molecules. - Abstract: The potentials of mean force (PMFs) for the ion pairs, Li + −Cl − , Li + −Br − and Li + −I − have been calculated in five methanol–water compositions. The results obtained are verified by trailing the trajectories and calculating the ion pair distance residence times. Local structures around the ions are studied using the radial distribution functions, density profiles, orientational correlation functions, running coordination numbers and excess coordination numbers. The major change in PMF is observed as the methanol mole fraction (x methanol ) is changed from 1.0 to 0.75. The stable contact ion pair occurring for x methanol = 1.0 becomes unstable at and below x methanol = 0.75. The preferential solvation data show that the halide ions are always preferentially solvated by water molecules. Although the lithium ion is preferentially solvated by methanol molecules, there is significant affinity towards water molecules as well

System and method for quench protection of a superconductor

Science.gov (United States)

Huang, Xianrui; Sivasubramaniam, Kiruba Haran; Bray, James William; Ryan, David Thomas

2008-03-11

A system and method for protecting a superconductor from a quench condition. A quench protection system is provided to protect the superconductor from damage due to a quench condition. The quench protection system comprises a voltage detector operable to detect voltage across the superconductor. The system also comprises a frequency filter coupled to the voltage detector. The frequency filter is operable to couple voltage signals to a control circuit that are representative of a rise in superconductor voltage caused by a quench condition and to block voltage signals that are not. The system is operable to detect whether a quench condition exists in the superconductor based on the voltage signal received via the frequency filter and to initiate a protective action in response.

Effective Ginzburg–Landau free energy functional for multi-band isotropic superconductors

International Nuclear Information System (INIS)

Grigorishin, Konstantin V.

2016-01-01

Highlights: • The intergradient coupling of order parameters in a two-band superconductor plays important role and cannot be neglected. • A two-band superconductor must be characterized with a single coherence length and a single Ginzburg–Landau parameter. • Type-1.5 superconductors are impossible. • The free energy functional for a multi-band superconductor can be reduced to the effective single-band Ginzburg–Landau functional. - Abstract: It has been shown that interband mixing of gradients of two order parameters (drag effect) in an isotropic bulk two-band superconductor plays important role – such a quantity of the intergradients coupling exists that the two-band superconductor is characterized with a single coherence length and a single Ginzburg–Landau (GL) parameter. Other quantities or neglecting of the drag effect lead to existence of two coherence lengths and dynamical instability due to violation of the phase relations between the order parameters. Thus so-called type-1.5 superconductors are impossible. An approximate method for solving of set of GL equations for a multi-band superconductor has been developed: using the result about the drag effect it has been shown that the free-energy functional for a multi-band superconductor can be reduced to the GL functional for an effective single-band superconductor.

Magnetic relaxation, flux pinning and critical currents in superconductors

International Nuclear Information System (INIS)

Lichtenberger, K.S.

1991-01-01

A systematic study of the magnetic flux pinning properties in superconductors has been undertaken in an attempt to understand the differences between the flux creep behavior of classical superconductors and high-temperature superconductors (HTSC's). In HTSC's, the ratio of the effective flux pinning energy to the thermal energy, U 0 /kT, is much smaller than that of conventional superconductors, often approaching unity. This results in much larger creep rates in HTSC's than in conventional superconductors. It is necessary to find suitable models that describe flux creep in both classical superconductors and HTSC's. Results show that while these two classes of materials are quantitatively very different, a single pinning barrier mode adequately describes both, within the proper region of the H-T plane. The model is applied to a variety of superconductors and the results are contrasted. Although the H-T plane appears to be very different HTSC's than for conventional superconductors, qualitatively the same physics describes both. In HTSC's, near the upper critical field there exists a relatively wide region of superconducting fluctuations, followed successively by regions of thermodynamic reversibility, thermally assisted flux, flux creep, and finally rigid flux lattice where little, if any, motion of the flux lattice occurs. All of these regions are also present in conventional superconductors, but often much more difficult, especially the irreversibility transition and the fluctuation region. The central finding of the flux creep analysis is that the region of flux creep is defined as a band in the H-T plane in which 2 ≤ U 0 /kT ≤ 100, and that the flux creep model applies best within this band

Electronic structure and superconductivity of FeSe-related superconductors.

Science.gov (United States)

Liu, Xu; Zhao, Lin; He, Shaolong; He, Junfeng; Liu, Defa; Mou, Daixiang; Shen, Bing; Hu, Yong; Huang, Jianwei; Zhou, X J

2015-05-13

FeSe superconductors and their related systems have attracted much attention in the study of iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a superconducting transition temperature (Tc) of ~8 K and it can be dramatically enhanced to 37 K at high pressure. On the other hand, its cousin system, FeTe, possesses a unique antiferromagnetic ground state but is non-superconducting. Substitution of Se with Te in the FeSe superconductor results in an enhancement of Tc up to 14.5 K and superconductivity can persist over a large composition range in the Fe(Se,Te) system. Intercalation of the FeSe superconductor leads to the discovery of the AxFe2-ySe2 (A = K, Cs and Tl) system that exhibits a Tc higher than 30 K and a unique electronic structure of the superconducting phase. A recent report of possible high temperature superconductivity in single-layer FeSe/SrTiO3 films with a Tc above 65 K has generated much excitement in the community. This pioneering work opens a door for interface superconductivity to explore for high Tc superconductors. The distinct electronic structure and superconducting gap, layer-dependent behavior and insulator-superconductor transition of the FeSe/SrTiO3 films provide critical information in understanding the superconductivity mechanism of iron-based superconductors. In this paper, we present a brief review of the investigation of the electronic structure and superconductivity of the FeSe superconductor and related systems, with a particular focus on the FeSe films.

Non-equilibrium spectroscopy of high-Tc superconductors

International Nuclear Information System (INIS)

Krasnov, V M

2009-01-01

In superconductors, recombination of two non-equilibrium quasiparticles into a Cooper pair results in emission of excitation that mediates superconductivity. This is the basis of the proposed new type of 'non-equilibrium' spectroscopy of high T c superconductors, which may open a possibility for direct and unambiguous determination of the coupling mechanism of high T c superconductivity. In case of low T c superconductors, the feasibility of such the non-equilibrium spectroscopy was demonstrated in classical phonon generation-detection experiments almost four decades ago. Recently it was demonstrated that a similar technique can be used for high T c superconductors, using natural intrinsic Josephson junctions both for injection of non-equilibrium quasiparticles and for detection of the non-equilibrium radiation. Here I analyze theoretically non-equilibrium phenomena in intrinsic Josephson junctions. It is shown that extreme non-equilibrium state can be achieved at bias equal to integer number of the gap voltage, which can lead to laser-like emission from the stack. I argue that identification of the boson type, constituting this non-equilibrium radiation would unambiguously reveal the coupling mechanism of high Tc superconductors.

Coherent diffusive transport mediated by Andreev reflections at V=Delta/e in a mesoscopic superconductor/semiconductor/superconductor junction

DEFF Research Database (Denmark)

Kutchinsky, Jonatan; Taboryski, Rafael Jozef; Kuhn, Oliver

1997-01-01

We present experiments revealing a singularity in the coherent current across a superconductor/semiconductor/superconductor (SSmS) junction at the bias voltage corresponding to the superconducting energy gap V=Delta/e. The SSmS structure consists of highly doped GaAs with superconducting electrodes...

Superfluid response in heavy fermion superconductors

Science.gov (United States)

Zhong, Yin; Zhang, Lan; Shao, Can; Luo, Hong-Gang

2017-10-01

Motivated by a recent London penetration depth measurement [H. Kim, et al., Phys. Rev. Lett. 114, 027003 (2015)] and novel composite pairing scenario [O. Erten, R. Flint, and P. Coleman, Phys. Rev. Lett. 114, 027002 (2015)] of the Yb-doped heavy fermion superconductor CeCoIn5, we revisit the issue of superfluid response in the microscopic heavy fermion lattice model. However, from the literature, an explicit expression for the superfluid response function in heavy fermion superconductors is rare. In this paper, we investigate the superfluid density response function in the celebrated Kondo-Heisenberg model. To be specific, we derive the corresponding formalism from an effective fermionic large- N mean-field pairing Hamiltonian whose pairing interaction is assumed to originate from the effective local antiferromagnetic exchange interaction. Interestingly, we find that the physically correct, temperature-dependent superfluid density formula can only be obtained if the external electromagnetic field is directly coupled to the heavy fermion quasi-particle rather than the bare conduction electron or local moment. Such a unique feature emphasizes the key role of the Kondo-screening-renormalized heavy quasi-particle for low-temperature/energy thermodynamics and transport behaviors. As an important application, the theoretical result is compared to an experimental measurement in heavy fermion superconductors CeCoIn5 and Yb-doped Ce1- x Yb x CoIn5 with fairly good agreement and the transition of the pairing symmetry in the latter material is explained as a simple doping effect. In addition, the requisite formalism for the commonly encountered nonmagnetic impurity and non-local electrodynamic effect are developed. Inspired by the success in explaining classic 115-series heavy fermion superconductors, we expect the present theory will be applied to understand other heavy fermion superconductors such as CeCu2Si2 and more generic multi-band superconductors.

Synthesis of highly phase pure BSCCO superconductors

Science.gov (United States)

Dorris, S.E.; Poeppel, R.B.; Prorok, B.C.; Lanagan, M.T.; Maroni, V.A.

1995-11-21

An article and method of manufacture (Bi, Pb)-Sr-Ca-Cu-O superconductor are disclosed. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor. 5 figs.

Superconductor in a weak static gravitational field

Energy Technology Data Exchange (ETDEWEB)

Ummarino, Giovanni Alberto [Dipartimento DISAT, Politecnico di Torino, Turin (Italy); National Research Nuclear University MEPhI-Moscow Engineering Physics Institute, Moscow (Russian Federation); Gallerati, Antonio [Dipartimento DISAT, Politecnico di Torino, Turin (Italy)

2017-08-15

We provide the detailed calculation of a general form for Maxwell and London equations that takes into account gravitational corrections in linear approximation. We determine the possible alteration of a static gravitational field in a superconductor making use of the time-dependent Ginzburg-Landau equations, providing also an analytic solution in the weak field condition. Finally, we compare the behavior of a high-T{sub c} superconductor with a classical low-T{sub c} superconductor, analyzing the values of the parameters that can enhance the reduction of the gravitational field. (orig.)

Fluxons in thin-film superconductor-insulator superlattices

DEFF Research Database (Denmark)

Sakai, S.; Bodin, P.; Pedersen, Niels Falsig

1993-01-01

In a system of thin alternating layers of superconductors and insulators the equations describing static and dynamic fluxon solutions are derived. The approach, represented by a useful compact matrix form, is intended to describe systems fabricated for example of niobium or niobium-nitride thin...... films; in the limit of ultrathin superconductor films it may give a model for describing fluxon motion in layered high-Tc superconductors. Numerical examples of current versus voltage curves to be expected in such an experiment are presented. Journal of Applied Physics is copyrighted by The American...

Fracture toughness for copper oxide superconductors

Science.gov (United States)

Goretta, Kenneth C.; Kullberg, Marc L.

1993-01-01

An oxide-based strengthening and toughening agent, such as tetragonal Zro.sub.2 particles, has been added to copper oxide superconductors, such as superconducting YBa.sub.2 Cu.sub.3 O.sub.x (123) to improve its fracture toughness (K.sub.IC). A sol-gel coating which is non-reactive with the superconductor, such as Y.sub.2 BaCuO.sub.5 (211) on the ZrO.sub.2 particles minimized the deleterious reactions between the superconductor and the toughening agent dispersed therethrough. Addition of 20 mole percent ZrO.sub.2 coated with 211 yielded a 123 composite with a K.sub.IC of 4.5 MPa(m).sup.0.5.

Fracture toughness for copper oxide superconductors

Science.gov (United States)

Goretta, K.C.; Kullberg, M.L.

1993-04-13

An oxide-based strengthening and toughening agent, such as tetragonal ZrO[sub 2] particles, has been added to copper oxide superconductors, such as superconducting YBa[sub 2]Cu[sub 3]O[sub x] (123) to improve its fracture toughness (K[sub IC]). A sol-gel coating which is non-reactive with the superconductor, such as Y[sub 2]BaCuO[sub 5] (211) on the ZrO[sub 2] particles minimized the deleterious reactions between the superconductor and the toughening agent dispersed therethrough. Addition of 20 mole percent ZrO[sub 2] coated with 211 yielded a 123 composite with a K[sub IC] of 4.5 MPa(m)[sup 0.5].

Processing Y- and Bi-based superconductors

International Nuclear Information System (INIS)

Balachandran, U.; Dos Santos, D.I.; von Stumberg, A.W.; Graham, S.W.; Singh, J.P.; Youngdahl, C.A.; Goretta, K.C.; Shi, D.; Poeppel, R.B.

1989-01-01

This paper reports on bulk specimens of YBa 2 Cu 3 O x and Bi 2 Sr 2 CaCu 2 O y formed and then processed by sintering in the solid state, in the presence of a liquid phase, or by sinter forging. Both Y- and Bi-based superconductors are difficult to densify by solid-state sintering but easy to densify in the presence of a liquid phase. Effects of sintering conditions on superconducting properties are, however, different between the two materials. These differences will be discussed. Attempts to texture microstructures and increase J c by sinter-forging techniques have been successful for Y-based superconductors, but unsuccessful for Bi-based superconductors

A nonquasiclassical description of inhomogeneous superconductors

International Nuclear Information System (INIS)

Zaikin, A.D.; Panyukov, S.V.

1988-01-01

Exact microscopic equations are derived that make it possible to describe inhomogeneous superconductors when the quasi-classical approach is not suitable. These equations are simpler than the Gorkov equations. The authors generalize the derived equations for describing the nonequilibrium states of inhomogeneous superconductors. It is demonstrated that the derived equations (including the case of a nonequilibrium quasi particle distribution function) may be written in the form of linear differential equations for the simultaneous wave function μ, ν. The quasi-classical limit of such equations is examined. Effective boundary conditions are derived for the μ, ν functions that allow description of superconductors with a sharp change in parameters within the scope of the quasi-classical approach

Electron detachment energies in high-symmetry alkali halide solvated-electron anions

Science.gov (United States)

Anusiewicz, Iwona; Berdys, Joanna; Simons, Jack; Skurski, Piotr

2003-07-01

We decompose the vertical electron detachment energies (VDEs) in solvated-electron clusters of alkali halides in terms of (i) an electrostatic contribution that correlates with the dipole moment (μ) of the individual alkali halide molecule and (ii) a relaxation component that is related to the polarizability (α) of the alkali halide molecule. Detailed numerical ab initio results for twelve species (MX)n- (M=Li,Na; X=F,Cl,Br; n=2,3) are used to construct an interpolation model that relates the clusters' VDEs to their μ and α values as well as a cluster size parameter r that we show is closely related to the alkali cation's ionic radius. The interpolation formula is then tested by applying it to predict the VDEs of four systems [i.e., (KF)2-, (KF)3-, (KCl)2-, and (KCl)3-] that were not used in determining the parameters of the model. The average difference between the model's predicted VDEs and the ab initio calculated electron binding energies is less than 4% (for the twelve species studied). It is concluded that one can easily estimate the VDE of a given high-symmetry solvated electron system by employing the model put forth here if the α, μ and cation ionic radii are known. Alternatively, if VDEs are measured for an alkali halide cluster and the α and μ values are known, one can estimate the r parameter, which, in turn, determines the "size" of the cluster anion.

Local Polar Fluctuations in Lead Halide Perovskite Crystals

Energy Technology Data Exchange (ETDEWEB)

Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z.; Egger, David A.; Hull, Trevor; Stoumpos, Constantinos C.; Zheng, Fan; Heinz, Tony F.; Kronik, Leeor; Kanatzidis, Mercouri G.; Owen, Jonathan S.; Rappe, Andrew M.; Pimenta, Marcos A.; Brus, Louis E.

2017-03-01

Hybrid lead-halide perovskites have emerged as an excellent class of photovoltaic materials. Recent reports suggest that the organic molecular cation is responsible for local polar fluctuations that inhibit carrier recombination. We combine low-frequency Raman scattering with first-principles molecular dynamics (MD) to study the fundamental nature of these local polar fluctuations. Our observations of a strong central peak in the cubic phase of both hybrid (CH3NH3PbBr3) and all-inorganic (CsPbBr3) leadhalide perovskites show that anharmonic, local polar fluctuations are intrinsic to the general lead-halide perovskite structure, and not unique to the dipolar organic cation. MD simulations indicate that head-tohead Cs motion coupled to Br face expansion, occurring on a few hundred femtosecond time scale, drives the local polar fluctuations in CsPbBr3.

Superconductors in the High School Classroom

Science.gov (United States)

Lincoln, James

2017-01-01

In this article, we discuss the behavior of high-temperature superconductors and how to demonstrate them safely and effectively in the high school or introductory physics classroom. Included here is a discussion of the most relevant physics topics that can be demonstrated, some safety tips, and a bit of the history of superconductors. In an effort…

Hexatic vortex glass in disordered superconductors

International Nuclear Information System (INIS)

Chudnovsky, E.M.

1989-01-01

It is shown that interaction of the flux-line lattice with randomly arranged pinning centers should destroy the long-range positional order in the lattice, but not the long-range orientational order. A new phase: hexatic vortex glass, is suggested for the mixed state of disordered, type-II superconductors. Relevance to amorphous and high-T c superconductors is discussed

Method of production multifilamentary intermetallic superconductors

International Nuclear Information System (INIS)

Marancik, W.G.; Young, M.S.

1980-01-01

A method of making A-15 type intermetallic superconductors is disclosed which features elimination of numerous annealing steps. Nb or V filaments are embedded in Cu matrices; annular layers of Sn or Ga, respectively, separated from each other by Cu layers, provide the other component of the intermetallic superconductors Nb3Sn and V3Ga

System and method for quench and over-current protection of superconductor

Science.gov (United States)

Huang, Xianrui; Laskaris, Evangelos Trifon; Sivasubramaniam, Kiruba Haran; Bray, James William; Ryan, David Thomas; Fogarty, James Michael; Steinbach, Albert Eugene

2005-05-31

A system and method for protecting a superconductor. The system may comprise a current sensor operable to detect a current flowing through the superconductor. The system may comprise a coolant temperature sensor operable to detect the temperature of a cryogenic coolant used to cool the superconductor to a superconductive state. The control circuit is operable to estimate the superconductor temperature based on the current flow and the coolant temperature. The system may also be operable to compare the estimated superconductor temperature to at least one threshold temperature and to initiate a corrective action when the superconductor temperature exceeds the at least one threshold temperature.

Methyl halide fluxes from tropical plants under controlled radiation and temperature regimes

Science.gov (United States)

Blei, Emanuel; Yokouchi, Yoko; Saito, Takuya; Nozoe, Susumu

2015-04-01

Methyl halides (CH3Cl, CH3Br, CH3I) contribute significantly to the halogen burden of the atmosphere and have the potential to influence the stratospheric ozone layer through their catalytic effect in the Chapman cycle. As such they have been studied over the years, and many plants and biota have been examined for their potential to act as a source of these gases. One of the potentially largest terrestrial sources identified was tropical vegetation such as tropical ferns and Dipterocarp trees. Most of these studies concentrated on the identification and quantification of such fluxes rather than their characteristics and often the chambers used in these studies were either opaque or only partially transparent to the full solar spectrum. Therefore it is not certain to which degree emissions of methyl halides are innate to the plants and how much they might vary due to radiation or temperature conditions inside the enclosures. In a separate development it had been proposed that UV-radiation could cause live plant materials to be become emitters of methane even under non-anoxic conditions. As methane is chemically very similar to methyl halides and had been proposed to be produced from methyl-groups ubiquitously found in plant cell material there is a relatively good chance that such a production mechanism would also apply to methyl halides. To test whether radiation can affect elevated emissions of methyl halides from plant materials and to distinguish this from temperature effects caused by heat build-up in chambers a set of controlled laboratory chamber enclosures under various radiation and temperature regimes was conducted on four different tropical plant species (Magnolia grandiflora, Cinnamonum camphora, Cyathea lepifera, Angiopteris lygodiifolia), the latter two of which had previously been identified as strong methyl halide emitters. Abscised leaf samples of these species were subjected to radiation treatments such UV-B, UV-A and broad spectrum radiation

Topological insulators and superconductors: tenfold way and dimensional hierarchy

International Nuclear Information System (INIS)

Ryu, Shinsei; Schnyder, Andreas P; Furusaki, Akira; Ludwig, Andreas W W

2010-01-01

It has recently been shown that in every spatial dimension there exist precisely five distinct classes of topological insulators or superconductors. Within a given class, the different topological sectors can be distinguished, depending on the case, by a Z or a Z 2 topological invariant. This is an exhaustive classification. Here we construct representatives of topological insulators and superconductors for all five classes and in arbitrary spatial dimension d, in terms of Dirac Hamiltonians. Using these representatives we demonstrate how topological insulators (superconductors) in different dimensions and different classes can be related via 'dimensional reduction' by compactifying one or more spatial dimensions (in 'Kaluza-Klein'-like fashion). For Z-topological insulators (superconductors) this proceeds by descending by one dimension at a time into a different class. The Z 2 -topological insulators (superconductors), on the other hand, are shown to be lower-dimensional descendants of parent Z-topological insulators in the same class, from which they inherit their topological properties. The eightfold periodicity in dimension d that exists for topological insulators (superconductors) with Hamiltonians satisfying at least one reality condition (arising from time-reversal or charge-conjugation/particle-hole symmetries) is a reflection of the eightfold periodicity of the spinor representations of the orthogonal groups SO(N) (a form of Bott periodicity). Furthermore, we derive for general spatial dimensions a relation between the topological invariant that characterizes topological insulators and superconductors with chiral symmetry (i.e., the winding number) and the Chern-Simons invariant. For lower-dimensional cases, this formula relates the winding number to the electric polarization (d=1 spatial dimensions) or to the magnetoelectric polarizability (d=3 spatial dimensions). Finally, we also discuss topological field theories describing the spacetime theory of

The iron pnictide superconductors an introduction and overview

CERN Document Server

Citro, Roberta

2017-01-01

This book covers different aspects of the physics of iron-based superconductors ranging from the theoretical, the numerical and computational, to the experimental ones. It starts from the basic theory modeling many-body physics in Fe-superconductors and other multi-orbital materials and drreaches up to the magnetic and Cooper pair fluctuations and nematic order. Finally, it offers a comprehensive overview of the most recent advancements in the experimental investigations of iron based superconductors. .

High temperature superconductor cable concepts for fusion magnets

CERN Document Server

AUTHOR|(CDS)2078397

2013-01-01

Three concepts of high temperature superconductor cables carrying kA currents (RACC, CORC and TSTC) are investigated, optimized and evaluated in the scope of their applicability as conductor in fusion magnets. The magnetic field and temperature dependence of the cables is measured; the thermal expansion and conductivity of structure, insulation and filling materials are investigated. High temperature superconductor winding packs for fusion magnets are calculated and compared with corresponding low temperature superconductor cases.

Powder processing of high Tc oxide superconductors and their properties

International Nuclear Information System (INIS)

Vajpei, A.C.; Upadhyaya, G.S.

1992-01-01

Powder processing of ceramics is an established technology and in the area of high T c superconductors, its importance is felt even more significantly. The present monograph is an attempt in this direction to explore the perspectives and practice of powder processing routes towards control and optimization of the microstructure and pertinent properties of high T c oxide superconductors. The monograph consists of 6 chapters. After a very brief introduction (Chapter 1), Chapter 2 describes various classes of high T c oxide superconductors and their phase equilibria. Chapter 3 highlights the preparation of oxide superconductor powders through various routes and details their subtle distinctions. Chapter 4 briefly covers characterisation of the oxide superconductors, laying emphasis on the process-analysis and microstructure. Chapter 5 describes in detail various fabrication techniques for bulk superconductors through the powder routes. The last Chapter (Chapter 6) describing properties of bulk oxide superconductors, discusses the role of subtituents, compositional variations and processing methods on such properties. References are given at the end of each chapter. (orig.)

Quasiclassical treatment and odd-parity/triplet correspondence in topological superconductors

International Nuclear Information System (INIS)

Nagai, Yuki; Nakamura, Hiroki; Machida, Masahiko

2014-01-01

We construct a quasiclassical framework for topological superconductors with a strong spin–orbit coupling such as Cu x Bi 2 Se 3 . In a manner of the quasiclassical treatment, by decomposing the slowly varying component from a total quasiparticle wave function, the original massive Dirac Bogoliubov–de Gennes (BdG) Hamiltonian derived from a tight-binding model represented by an 8 × 8 matrix is reduced to a 4 × 4 matrix. The resultant equations are equivalent to Andreev-type equations of singlet or triplet superconductors, in which the apparent spin–orbit coupling vanishes. Using this formalism, we find that the odd-parity superconductivity in topological superconductors turns to the spin-triplet one. Moreover, in terms of quasiclassical treatment, we show that the topologically-protected zero-energy states in topological superconductors have correspond to the Andreev bound states established in a long history of studies of unconventional superconductors. This clearly indicates that low-energy nontrivial superconducting properties in the topological superconductors can be analyzed using established theoretical descriptions of the spin-triplet superconductors. (author)

Thermal battery. [solid metal halide electrolytes with enhanced electrical conductance after a phase transition

Science.gov (United States)

Carlsten, R.W.; Nissen, D.A.

1973-03-06

The patent describes an improved thermal battery whose novel design eliminates various disadvantages of previous such devices. Its major features include a halide cathode, a solid metal halide electrolyte which has a substantially greater electrical conductance after a phase transition at some temperature, and a means for heating its electrochemical cells to activation temperature.

Superconductor stability, 1983: a review

International Nuclear Information System (INIS)

Dresner, L.

1983-01-01

Three main topics have been discussed in this paper, namely, internally cooled superconductors, cooling by superfluid helium, and metastable magnets. The discussion of each has centered around a dominant idea, and it is fitting to highlight these ideas by way of conclusion. With regard to internally cooled superconductors, most of what we have learned in the last few years centers on the strong motion caused by the thermal expansion of helium. How naive were our early calculations that treated the helium as though it were incompressible. Our discussion of He-II was organized around the Gorter-Mellink relation and the solutions of the nonlinear diffusion equation it gives rise to. And our discussion of metastable magnets revolved around the fruitful concept of the MPZ. These three ideas are sturdy trunks that support much of the thought about superconductor stability that has flowered in the past several years

Edge instabilities of topological superconductors

Energy Technology Data Exchange (ETDEWEB)

Hofmann, Johannes S. [Institut fuer Theoretische Physik und Astrophysik, Universitaet Wuerzburg (Germany); Max-Planck-Institut fuer Festkoerperforschung, Stuttgart (Germany); Assaad, Fakher F. [Institut fuer Theoretische Physik und Astrophysik, Universitaet Wuerzburg (Germany); Schnyder, Andreas P. [Max-Planck-Institut fuer Festkoerperforschung, Stuttgart (Germany)

2016-07-01

Nodal topological superconductors display zero-energy Majorana flat bands at generic edges. The flatness of these edge bands, which is protected by time-reversal and translation symmetry, gives rise to an extensive ground state degeneracy and a diverging density of states. Therefore, even arbitrarily weak interactions lead to an instability of the flat-band edge states towards time-reversal and translation-symmetry broken phases, which lift the ground-state degeneracy. Here, we employ Monte Carlo simulations combined with mean-field considerations to examine the instabilities of the flat-band edge states of d{sub xy}-wave superconductors. We find that attractive interactions induce a complex s-wave pairing instability together with a density wave instability. Repulsive interactions, on the other hand, lead to ferromagnetism mixed with spin-triplet pairing at the edge. We discuss the implications of our findings for experiments on cuprate high-temperature superconductors.

Analysis and modeling of alkali halide aqueous solutions

DEFF Research Database (Denmark)

Kim, Sun Hyung; Anantpinijwatna, Amata; Kang, Jeong Won

2016-01-01

on calculations for various electrolyte properties of alkali halide aqueous solutions such as mean ionic activity coefficients, osmotic coefficients, and salt solubilities. The model covers highly nonideal electrolyte systems such as lithium chloride, lithium bromide and lithium iodide, that is, systems...

A study on the localized corrosion of cobalt in bicarbonate solutions containing halide ions

Energy Technology Data Exchange (ETDEWEB)

Gallant, Danick [Departement de Biologie, Chimie et Sciences de la Sante, Universite du Quebec a Rimouski, 300, Allee des Ursulines, Rimouski, Que., G5L 3A1 (Canada); Departement de Chimie, Universite Laval, Quebec, Que., G1K 7P4 (Canada); Simard, Stephan [Departement de Biologie, Chimie et Sciences de la Sante, Universite du Quebec a Rimouski, 300, Allee des Ursulines, Rimouski, Que., G5L 3A1 (Canada)]. E-mail: stephan_simard@uqar.qc.ca

2005-07-01

The localized attack of cobalt in bicarbonate aqueous solutions containing halide ions was investigated using electrochemical techniques, scanning electron microscopy, UV-visible and Raman spectroscopies. Rotating disc and rotating ring-disc electrodes were used to determine the effect of bicarbonate concentration, solution pH, nature and concentration of the halide ions, convection and potential sweep rate on the corrosion processes. These parameters were found to play a key role on the localized attack induced by halide ions by influencing the production of a Co(HCO{sub 3}){sub 2} precipitate on the pit surface. Potentiostatically generated cobalt oxide films (CoO and Co{sub 3}O{sub 4}) were found to be efficient to reduce pitting corrosion of cobalt.

The new Fe-based superconductors

International Nuclear Information System (INIS)

Mao, Zhiqiang

2011-01-01

The discovery of unconventional superconductivity in doped iron pnictides has ushered in a new era of high temperature superconductivity. The superconductivity of these materials occurs in close proximity to magnetic instability; superconductivity is achieved by suppressing a long-range antiferromagnetic (AFM) order through charge carrier doping or pressure. In this talk, I will first give a brief overview of the phase diagrams of iron-based superconductors, and then talk about our recent research on iron chalcogenide Fe 1+y (Te 1-x Se x ) superconductors, which is structurally the simplest of the Fe-based superconductors. Although the Fermi surface of iron chalcogenides is similar to iron pnictides, the parent compound Fe 1+y Te exhibits AFM order with in-plane magnetic wave-vector (π, 0). This contrasts the pnictide parent compounds where the magnetic order has an in-plane magnetic wave-vector (π, π) that connects hole and electron parts of the Fermi surface. Despite these differences, both the pnictide and chalcogenide Fe-superconductors exhibit superconducting spin resonances around (π, π), suggesting a common symmetry for their superconducting order parameter. A central question in this burgeoning field is therefore how (π, π) superconductivity can emerge from a (π, 0) magnetic instability. I will address this issue in my talk. I will show the phase diagram of electronic and magnetic properties we recently established for this system and discuss the relationship between magnetic coupling and electronic properties. Our results reveal that the magnetic soft mode evolving from the (π, 0)-type magnetic long-range order is associated with weak charge carrier localization. Bulk superconductivity occurs only as magnetic correlations near (π, 0) are strongly suppressed and the magnetic mode at (π, π) becomes dominant; this suggests a common magnetic origin for superconductivity in iron chalcogenide and pnictide superconductors. (author)

Adsorption of molecular additive onto lead halide perovskite surfaces: A computational study on Lewis base thiophene additive passivation

Science.gov (United States)

Zhang, Lei; Yu, Fengxi; Chen, Lihong; Li, Jingfa

2018-06-01

Organic additives, such as the Lewis base thiophene, have been successfully applied to passivate halide perovskite surfaces, improving the stability and properties of perovskite devices based on CH3NH3PbI3. Yet, the detailed nanostructure of the perovskite surface passivated by additives and the mechanisms of such passivation are not well understood. This study presents a nanoscopic view on the interfacial structure of an additive/perovskite interface, consisting of a Lewis base thiophene molecular additive and a lead halide perovskite surface substrate, providing insights on the mechanisms that molecular additives can passivate the halide perovskite surfaces and enhance the perovskite-based device performance. Molecular dynamics study on the interactions between water molecules and the perovskite surfaces passivated by the investigated additive reveal the effectiveness of employing the molecular additives to improve the stability of the halide perovskite materials. The additive/perovskite surface system is further probed via molecular engineering the perovskite surfaces. This study reveals the nanoscopic structure-property relationships of the halide perovskite surface passivated by molecular additives, which helps the fundamental understanding of the surface/interface engineering strategies for the development of halide perovskite based devices.

Superconductor Dynamics

Energy Technology Data Exchange (ETDEWEB)

Gömöry, F [Bratislava, Inst. Elect. Eng. (Slovakia)

2014-07-01

Superconductors used in magnet technology could carry extreme currents because of their ability to keep the magnetic flux motionless. The dynamics of the magnetic flux interaction with superconductors is controlled by this property. The cases of electrical transport in a round wire and the magnetization of wires of various shapes (circular, elliptical, plate) in an external magnetic field are analysed. Resistance to the magnetic field penetration means that the field produced by the superconducting magnet is no longer proportional to the supplied current. It also leads to a dissipation of electromagnetic energy. In conductors with unequal transverse dimensions, such as flat cables, the orientation with respect to the magnetic field plays an essential role. A reduction of magnetization currents can be achieved by splitting the core of a superconducting wire into fine filaments; however, new kinds of electrical currents that couple the filaments consequently appear. Basic formulas allowing qualitative analyses of various flux dynamic cases are presented.

Evolution of new superconductors. Past, present and future

International Nuclear Information System (INIS)

Akimitsu, Jun

2011-01-01

I present here the past and present situations of new superconductors and also the future prospect. Superconductivity has started since Kamerlingh Onnes first observed the zero resistivity. After that, the critical temperature T c was gradually increased. In the early stage of superconductive material investigations, main contribution has been made by B. Matthias and his group. In 1986, a new superconductor La-Ba-Cu-O, which belongs to new category in the superconducting society, has been found by Bednorz and Mueller. After that T c 's have been drastically increased, and finally reached to T c - 164 K in the Hg-compound. Next, I review several new superconductors discovered within 20 years. Finally, I mention my personal perspective to a high-T c superconductor. (author)

Ginsburg-Landau equation around the superconductor-insulator transition

International Nuclear Information System (INIS)

Ng, T.K.

1991-01-01

Based on the scaling theory of localization, we construct a Ginsburg-Landau (GL) equation for superconductors in an arbitrary strength of disordered potential. Using this GL equation, we reexamine the criteria for the superconductor-insulator transition and find that the transition to a localized superconductor can happen on both sides of the (normal) metal-insulator transition, in contrast to a previous prediction by Ma and Lee [Phys. Rev. B 32, 5658 (1985)] that the transition can only be on the insulator side. Furthermore, by comparing our theory with a recent scaling theory of dirty bosons by Fisher et al. [Phys. Rev. Lett. 64, 587 (1990)], we conclude that nontrivial crossover behavior in transport properties may occur in the vicinity of the superconductor-insulator transition

Energy gap of ferromagnet-superconductor bilayers

Energy Technology Data Exchange (ETDEWEB)

Halterman, Klaus; Valls, Oriol T

2003-10-15

The excitation spectrum of clean ferromagnet-superconductor bilayers is calculated within the framework of the self-consistent Bogoliubov-de Gennes theory. Because of the proximity effect, the superconductor induces a gap in the ferromagnet spectrum, for thin ferromagnetic layers. The effect depends strongly on the exchange field in the ferromagnet. We find that as the thickness of the ferromagnetic layer increases, the gap disappears, and that its destruction arises from those quasiparticle excitations with wave vectors mainly along the interface. We discuss the influence that the interface quality and Fermi energy mismatch between the ferromagnet and superconductor have on the calculated energy gap. We also evaluate the density of states in the ferromagnet, and we find it in all cases consistent with the gap results.

Development of superconductor application technology

Energy Technology Data Exchange (ETDEWEB)

Hong, G W; Kim, C J; Lee, H G; Lee, H J; Kim, K B; Won, D Y; Jang, K I; Kwon, S C; Kim, W J; Ji, Y A; Yang, S W; Kim, W K; Park, S D; Lee, M H; Lee, D M; Park, H W; Yu, J K; Lee, I S; Kim, J J; Choi, H S; Chu, Y; Kim, Y S; Kim, D H

1997-09-01

Fabrication of high Tc bulk superconductor and its application, fabrication of superconducting wire for electric power device and analysis for cryogenic system were carried out for developing superconductor application technologies for electric power system. High quality YBaCuO bulk superconductor was fabricated by controlling initial powder preparation process and prototype flywheel energy storage device was designed basically. The superconducting levitation force measuring device was made to examine the property of prepared superconductor specimen. Systematic studies onthe method of starting powder preparation, mechanical fabrication process, heat treatment condition and analysis of plastic deformation were carried out to increase the stability and reproducibility of superconducting wire. A starting power with good reactivity and fine particle size was obtained by mechanical grinding, control of phase assemblage, and emulsion drying method. Ag/BSCCO tape with good cross sectional shape and Jc of 20,000 A/cm{sup 2} was fabricated by applying CIP packing procedure. Multifilamentary wire with Jc of 10,000 A/cm{sup 2} was fabricated by rolling method using square billet as starting shape. The joining of the multifilamentary wire was done by etching and pressing process and showed 50% of joining efficiency. Analysis on the heat loss in cryostat for high Tc superconducting device was carried out for optimum design of the future cryogenic system. (author). 66 refs., 104 figs.

Development of superconductor application technology

International Nuclear Information System (INIS)

Hong, G. W.; Kim, C. J.; Lee, H. G.; Lee, H. J.; Kim, K. B.; Won, D. Y.; Jang, K. I.; Kwon, S. C.; Kim, W. J.; Ji, Y. A.; Yang, S. W.; Kim, W. K.; Park, S. D.; Lee, M. H.; Lee, D. M.; Park, H. W.; Yu, J. K.; Lee, I. S.; Kim, J. J.; Choi, H. S.; Chu, Y.; Kim, Y. S.; Kim, D. H.

1997-09-01

Fabrication of high Tc bulk superconductor and its application, fabrication of superconducting wire for electric power device and analysis for cryogenic system were carried out for developing superconductor application technologies for electric power system. High quality YBaCuO bulk superconductor was fabricated by controlling initial powder preparation process and prototype flywheel energy storage device was designed basically. The superconducting levitation force measuring device was made to examine the property of prepared superconductor specimen. Systematic studies onthe method of starting powder preparation, mechanical fabrication process, heat treatment condition and analysis of plastic deformation were carried out to increase the stability and reproducibility of superconducting wire. A starting power with good reactivity and fine particle size was obtained by mechanical grinding, control of phase assemblage, and emulsion drying method. Ag/BSCCO tape with good cross sectional shape and Jc of 20,000 A/cm 2 was fabricated by applying CIP packing procedure. Multifilamentary wire with Jc of 10,000 A/cm 2 was fabricated by rolling method using square billet as starting shape. The joining of the multifilamentary wire was done by etching and pressing process and showed 50% of joining efficiency. Analysis on the heat loss in cryostat for high Tc superconducting device was carried out for optimum design of the future cryogenic system. (author). 66 refs., 104 figs

Engineered flux-pinning centers in BSCCO TBCCO and YBCO superconductors

Science.gov (United States)

Goretta, K.C.; Lanagan, M.T.; Miller, D.J.; Sengupta, S.; Parker, J.C.; Hu, J.; Balachandran, U.; Siegel, R.W.; Shi, D.

1999-07-27

A method of preparing a high temperature superconductor is disclosed. A method of preparing a superconductor includes providing a powdered high temperature superconductor and a nanophase material. These components are combined to form a solid compacted mass with the material disposed in the polycrystalline high temperature superconductor. This combined mixture is rapidly heated, forming a dispersion of nanophase size particles without a eutectic reaction. These nanophase particles can have a flat plate or columnar type morphology. 4 figs.

2D halide perovskite-based van der Waals heterostructures: contact evaluation and performance modulation

Science.gov (United States)

Guo, Yaguang; Saidi, Wissam A.; Wang, Qian

2017-09-01

Halide perovskites and van der Waals (vdW) heterostructures are both of current interest owing to their novel properties and potential applications in nano-devices. Here, we show the great potential of 2D halide perovskite sheets (C4H9NH3)2PbX4 (X  =  Cl, Br and I) that were synthesized recently (Dou et al 2015 Science 349 1518-21) as the channel materials contacting with graphene and other 2D metallic sheets to form van der Waals heterostructures for field effect transistor (FET). Based on state-of-the-art theoretical simulations, we show that the intrinsic properties of the 2D halide perovskites are preserved in the heterojunction, which is different from the conventional contact with metal surfaces. The 2D halide perovskites form a p-type Schottky barrier (Φh) contact with graphene, where tunneling barrier exists, and a negative band bending occurs at the lateral interface. We demonstrate that the Schottky barrier can be turned from p-type to n-type by doping graphene with nitrogen atoms, and a low-Φh or an Ohmic contact can be realized by doping graphene with boron atoms or replacing graphene with other high-work-function 2D metallic sheets such as ZT-MoS2, ZT-MoSe2 and H-NbS2. This study not only predicts a 2D halide perovskite-based FETs, but also enhances the understanding of tuning Schottky barrier height in device applications.

Current correlations in superconductor - normal metal mesoscopic structures

International Nuclear Information System (INIS)

Bignon, Guillaume

2005-01-01

Thanks to the experimental progress in miniaturization and cryogenics over the last twenty years, it is now possible to build sufficiently small electric circuits where the wave like nature of electron becomes significant. In such electric circuit transport properties like current and noise are modified. It corresponds to the mesoscopic scale. Moreover, connecting a mesoscopic circuit to a superconductor enhances the effects due to interference between electrons since a superconductor is a macroscopic source of coherent electrons pairs: the Cooper pairs. In this thesis, we study current correlations in mesoscopic normal metal - superconductor structures. First, the energy dependence of current noise in a normal metal - superconductor tunnel junction is analysed taking into account weak disorder and interactions. We show that if the normal metal is out of equilibrium, current and noise become independent. Next, we consider the case of a superconductor connected to two normal metals by tunnel junctions. We show that it is possible to change the sign of current crossed correlation by tuning the voltages and that it can be used to probe the size of the Cooper pairs. Lastly, using Usadel's quasi-classic theory, we study the energy dependence of noise in a normal metal - normal metal - superconductor double junction. We show that barrier's transparencies modifies significantly both current and noise. (author) [fr

Upper critical fields and critical current densities of Fe-based superconductors as compared to those of other technical superconductors

Energy Technology Data Exchange (ETDEWEB)

Pallecchi, I., E-mail: ilaria.pallecchi@spin.cnr.it [CNR-SPIN, Corso Perrone 24, 16152 Genova (Italy); Tropeano, M. [Columbus Superconductors S.p.A, Via delle Terre Rosse 30, 16133 Genova (Italy); Lamura, G. [CNR-SPIN, Corso Perrone 24, 16152 Genova (Italy); Pani, M. [Dipartimento di Chimica e Chimica Industriale, Universita di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Palombo, M. [Columbus Superconductors S.p.A, Via delle Terre Rosse 30, 16133 Genova (Italy); Dipartimento di Chimica e Chimica Industriale, Universita di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Dipartimento di Fisica, Universita di Genova, Via Dodecaneso 33, 16146 Genova (Italy); Palenzona, A. [Dipartimento di Chimica e Chimica Industriale, Universita di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Putti, M. [CNR-SPIN, Corso Perrone 24, 16152 Genova (Italy); Dipartimento di Fisica, Universita di Genova, Via Dodecaneso 33, 16146 Genova (Italy)

2012-11-20

Three years since the discovery by the Hosono's group of Fe-based superconductors, an enormous number of compounds, belonging to several different families have been discovered and fundamental properties have been deeply investigated in order to clarify the interplay between magnetisms and superconductivity in these compounds. Indeed, the actual potential of these compounds for practical applications remains still unclear. Fe-based superconductors are midway between high temperature superconductors (HTSCs) and MgB{sub 2}. In Fe-based superconductors the critical current is rather independent of the field, similarly to HTSCs, as a consequence of the exceptionally high upper critical field and strong pinning associated with nm-scale local modulations of the order parameter. They exhibit low anisotropy of the critical current with respect to the crystalline directions, as in the case of MgB{sub 2}, which allows current flow along the c-axis. However, Fe-based superconductor polycrystalline materials currently available still exhibit electromagnetic granularity, like the HTSCs, which suppresses superconducting current flow over long length. Whether the nature of such granularity is extrinsic, as due to spurious phases or cracks between grains or intrinsic, as related to misalignment of adjacent grains, is under debate. These aspects will be reviewed in the light of the recent literature.

Structures of butyl ions formed by electron impact ionization of isomeric butyl halides and alkanes

International Nuclear Information System (INIS)

Shold, D.M.; Ausloos, P.

1978-01-01

Using a pulsed ion cyclotron resonance (ICR) spectrometer, it is demonstrated that at pressures of about 10 -6 Torr and at observation times ranging from 10 -3 to 0.5 s, isobutane, neopentane, 2,2-dimethylbutane, isobutyl halides, and tert-butyl halides form C 4 H 9 + ions having the tertiary structure. In n-alkanes, 2-methylbutane, 3-methylpentane, n-butyl halides, and sec-butyl halides, both sec-C 4 H 9 + and t-C 4 H 9 + ions are observed, the sec-C 4 H 9 + ions surviving without rearrangement for at least 0.1 s. However, in the case of the halides, a collision-induced isomerization of the sec-C 4 H 9 + to the t-C 4 H 9 + ions occurs. The efficiency of this process increases with the basicity of the alkyl halide. Radiolysis experiments carried out at atmospheric pressures indicate, in agreement with ICR and solution experiments, that at times as short as 10 -10 s the majority of the i-C 4 H 9 + ions from isobutyl bromide rearrange to the t-C 4 H 9 + structure. On the other hand, in the radiolysis of both n-hexane and 3-methylpentane, the abundance of t-C 4 H 9 + relative to sec-C 4 H 9 + is substantially smaller than that observed in the ICR experiments, and decreases with decreasing collision interval. It is suggested that about 90% of the i-C 4 H 9 + can rearrange to t-C 4 H 9 + by simple 1,2-hydride shift without involving secondary or protonated methylcyclopropane structures as intermediates. 4 figures, 2 tables

Dipole-dipole van der Waals interaction in alkali halides

International Nuclear Information System (INIS)

Thakur, B.N.; Thakur, K.P.

1978-01-01

Values of van der Waals dipole-dipole constants and interaction energetics of alkali halides are reported using the recent data. The values obtained are somewhat larger than those of earlier workers. (orig.) [de

The improved damping of superconductor bearings for 35 kWh superconductor flywheel energy storage system

International Nuclear Information System (INIS)

Han, Y.H.; Park, B.J.; Jung, S.Y.; Han, S.C.; Lee, W.R.; Bae, Y.C.

2013-01-01

Highlights: ► We made a 35 kWh superconductor flywheel energy storage system. ► The damping coefficient of the superconductor bearing was increased over 3000 N s/m. ► The source of damping was discussed. -- Abstract: A 35 kWh Superconductor Flywheel Energy Storage system (SFES) using hybrid bearing sets, which is composed of a high temperature superconductor (HTS) bearing and an active magnet damper (AMD), has been developed at KEPCO Research Institute (KEPRI). Damping is a source of energy loss but necessary for the stability of the flywheel system. We found that the damping of HTS bearings can be improved by thermal insulating bolts, which play a role of passive type external damper. To investigate the source of the increased damping, damping coefficients were measured with HTS bearings using insulating bolts made of three kinds of polymer materials. The damping coefficient was raised over 3000 N s/m in the case of PEEK bolts. The value was almost a quarter of the AMD. In this study, thermoelastic and Coulomb friction damping mechanisms are discussed. The main damping mechanism was the thermoelastic damping of the bolts themselves. And interfacial gap between the insulating bolt and metal chamber, which increased during the cooling process, was considered to be the cause of the anisotropic damping coefficients. Finally, the effects of the HTS bearings on the first critical speed are shown

Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance

Science.gov (United States)

2017-01-01

This Perspective outlines basic structural and optical properties of lead halide perovskite colloidal nanocrystals, highlighting differences and similarities between them and conventional II–VI and III–V semiconductor quantum dots. A detailed insight into two important issues inherent to lead halide perovskite nanocrystals then follows, namely, the advantages of defect tolerance and the necessity to improve their stability in environmental conditions. The defect tolerance of lead halide perovskites offers an impetus to search for similar attributes in other related heavy metal-free compounds. We discuss the origins of the significantly blue-shifted emission from CsPbBr3 nanocrystals and the synthetic strategies toward fabrication of stable perovskite nanocrystal materials with emission in the red and infrared parts of the optical spectrum, which are related to fabrication of mixed cation compounds guided by Goldschmidt tolerance factor considerations. We conclude with the view on perspectives of use of the colloidal perovskite nanocrystals for applications in backlighting of liquid-crystal TV displays. PMID:28920080

Functional development in density functional theory for superconductors

Energy Technology Data Exchange (ETDEWEB)

Sanna, Antonio; Gross, E.K.U.; Essenberger, Frank [Max Planck Institute of Microstructure Physics, Halle (Saale) (Germany)

2015-07-01

Density functional theory for superconductors (SCDFT) is a fully parameter-free approach to superconductivity that allows for accurate predictions of critical temperature and properties of superconductors. We report on the most recent extensions of the method, in particular the development of new functionals to: (1) incorporate in a correct fashion Migdal's theorem; (2) compute the excitation spectrum; (3) include spin-fluctuation mediated pairing Applications and predictions are shown for a set of materials, including conventional and unconventional superconductors.

Theory of terahertz electric oscillations by supercooled superconductors

Energy Technology Data Exchange (ETDEWEB)

Mishonov, Todor M; Mishonov, Mihail T [Department of Theoretical Physics, Faculty of Physics, University of Sofia St Kliment Ohridski, 5 J Bourchier Boulevard, 1164 Sofia (Bulgaria); Laboratorium voor Vaste-Stoffysica en Magnetisme, Katholieke Universiteit Leuven, Celestijnenlaan 200 D B-3001 Leuven (Belgium)

2005-11-15

We predict that below T{sub c} a regime of negative differential conductivity (NDC) can be reached. The superconductor should be supercooled to Tsuperconductor is created by the excess conductivity of the fluctuation Cooper pairs. We propose NDC of supercooled superconductors to be used as an active medium for generation of electric oscillations. Such generators can be used in the superconducting electronics as a new type THz source of radiation. Oscillations can be modulated by the change of the bias voltage, electrostatic doping by a gate electrode when the superconductor is the channel of a field effect transistor, or by light. When small amplitude oscillations are stabilized near the critical temperature T{sub c} the generator can be used as a bolometer. NDC, which is essential for the applications, is predicted on the basis of analysis of known results for fluctuation conductivity, obtained in previous papers by solving the Boltzmann kinetic equation for the Cooper pairs metastable in the normal phase. The Boltzmann equation for fluctuation Cooper pairs is a result of state-of-the-art application of the microscopic theory of superconductivity. Our theoretical conclusions are based on some approximations like time dependent Ginzburg-Landau theory initially derived for gapless superconductors, but nevertheless can reliably predict the appearance of NDC. NDC is the main ingredient of the proposed technical applications. The maximal frequency at which superconductors can operate as generators is determined by the critical temperature {Dirac_h}/2{pi}{omega}{sub max} {approx} k{sub B}T{sub c}. For high-T{sub c} superconductors this maximal frequency falls well inside the terahertz range. Technical conditions to avoid nucleation of the superconducting phase are briefly discussed. We suggest that nanostructured high-T{sub c} superconductors patterned in a single chip can

Topological insulators and topological superconductors

CERN Document Server

Bernevig, Andrei B

2013-01-01

This graduate-level textbook is the first pedagogical synthesis of the field of topological insulators and superconductors, one of the most exciting areas of research in condensed matter physics. Presenting the latest developments, while providing all the calculations necessary for a self-contained and complete description of the discipline, it is ideal for graduate students and researchers preparing to work in this area, and it will be an essential reference both within and outside the classroom. The book begins with simple concepts such as Berry phases, Dirac fermions, Hall conductance and its link to topology, and the Hofstadter problem of lattice electrons in a magnetic field. It moves on to explain topological phases of matter such as Chern insulators, two- and three-dimensional topological insulators, and Majorana p-wave wires. Additionally, the book covers zero modes on vortices in topological superconductors, time-reversal topological superconductors, and topological responses/field theory and topolo...

Calcium phosphate cements with strontium halides as radiopacifiers.

Science.gov (United States)

López, Alejandro; Montazerolghaem, Maryam; Engqvist, Håkan; Ott, Marjam Karlsson; Persson, Cecilia

2014-02-01

High radiopacity is required to monitor the delivery and positioning of injectable implants. Inorganic nonsoluble radiopacifiers are typically used in nondegradable bone cements; however, their usefulness in resorbable cements is limited due to their low solubility. Strontium halides, except strontium fluoride, are ionic water-soluble compounds that possess potential as radiopacifiers. In this study, we compare the radiopacity, mechanical properties, composition, and cytotoxicity of radiopaque brushite cements prepared with strontium fluoride (SrF2 ), strontium chloride (SrCl2 ·6H2 O), strontium bromide (SrBr2 ), or strontium iodide (SrI2 ). Brushite cements containing 10 wt % SrCl2 ·6H2 O, SrBr2 , or SrI2 exhibited equal to or higher radiopacity than commercial radiopaque cements. Furthermore, the brushite crystal lattice in cements that contained the ionic radiopacifiers was larger than in unmodified cements and in cements that contained SrF2 , indicating strontium substitution. Despite the fact that the strontium halides increased the solubility of the cements and affected their mechanical properties, calcium phosphate cements containing SrCl2 ·6H2 O, SrBr2 , and SrI2 showed no significant differences in Saos-2 cell viability and proliferation with respect to the control. Strontium halides: SrCl2 ·6H2 O, SrBr2 , and SrI2 may be potential candidates as radiopacifiers in resorbable biomaterials although their in vivo biocompatibility, when incorporated into injectable implants, is yet to be assessed. Copyright © 2013 Wiley Periodicals, Inc.

High-T/sub c/ superconductor and its use in superconducting magnets

International Nuclear Information System (INIS)

Green, M.A.

1988-02-01

Many of the proposed uses for the high-T/sub c/ superconductor involve the creation of a magnetic field using superconducting coils. This report will assess what is known about the high-T/sub c/ superconductors and take a realistic look at their potential use in various kinds of superconducting magnets. Based on what is known about the high-T/sub c/ superconductors, one can make a ''wish list'' of things that will make such materials useful for magnets. Then, the following question is asked. If one had a high-T/sub c/ superconductor with the same properties as modern niobium-titanium superconductor, how would the superconductor work in a magnet environment? Finally, this report will show the potential impact of the ideal high-T/sub c/ superconductor on: 1) accelerator dipole and quadrupole magnets, 2) superconducting magnets for use in space, and 3) superconducting solenoids for magnetic resonance imaging. 78 refs., 11 tabs

Sodium-metal halide and sodium-air batteries.

Science.gov (United States)

Ha, Seongmin; Kim, Jae-Kwang; Choi, Aram; Kim, Youngsik; Lee, Kyu Tae

2014-07-21

Impressive developments have been made in the past a few years toward the establishment of Na-ion batteries as next-generation energy-storage devices and replacements for Li-ion batteries. Na-based cells have attracted increasing attention owing to low production costs due to abundant sodium resources. However, applications of Na-ion batteries are limited to large-scale energy-storage systems because of their lower energy density compared to Li-ion batteries and their potential safety problems. Recently, Na-metal cells such as Na-metal halide and Na-air batteries have been considered to be promising for use in electric vehicles owing to good safety and high energy density, although less attention is focused on Na-metal cells than on Na-ion cells. This Minireview provides an overview of the fundamentals and recent progress in the fields of Na-metal halide and Na-air batteries, with the aim of providing a better understanding of new electrochemical systems. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Local polar fluctuations in lead halide perovskites

Science.gov (United States)

Tan, Liang; Yaffe, Omer; Guo, Yinsheng; Brus, Louis; Rappe, Andrew; Egger, David; Kronik, Leeor

The lead halide perovskites have recently attracted much attention because of their large and growing photovoltaic power conversion efficiencies. However, questions remain regarding the temporal and spatial correlations of the structural fluctuations, their atomistic nature, and how they affect electronic and photovoltaic properties. To address these questions, we have performed a combined ab initio molecular dynamics (MD) and density functional theory (DFT) study on CsPbBr3. We have observed prevalent anharmonic motion in our MD trajectories, with local polar fluctuations involving head-to-head motion of A-site Cs cations coupled with Br window opening. We calculate Raman spectra from the polarizability auto-correlation functions obtained from these trajectories and show that anharmonic A-site cation motion manifests as a broad central peak in the Raman spectrum, which increases in intensity with temperature. A comparison of the experimental Raman spectrum of hybrid organometallic MAPbBr3 and fully inorganic CsPbBr3 suggests that structural fluctuations in lead-halide perovskites is more general than rotation of polar organic cations and is intimately coupled to the inorganic framework.

Macroscopic theory of superconductors

International Nuclear Information System (INIS)

Carr, W.J. Jr.

1981-01-01

A macroscopic theory for bulk superconductors is developed in the framework of the theory for other magnetic materials, where ''magnetization'' current is separated from ''free'' current on the basis of scale. This contrasts with the usual separation into equilibrium and nonequilibrium currents. In the present approach magnetization, on a large macroscopic scale, results from the vortex current, while the Meissner current and other surface currents are surface contributions to the Maxwell j. The results are important for the development of thermodynamics in type-II superconductors. The advantage of the description developed here is that magnetization becomes a local concept and its associated magnetic field can be given physical meaning

The role of halide ions on the electrochemical behaviour of iron in alkali solutions

Science.gov (United States)

Begum, S. Nathira; Muralidharan, V. S.; Basha, C. Ahmed

2008-02-01

Active dissolution and passivation of transition metals in alkali solutions is of technological importance in batteries. The performance of alkaline batteries is decided by the presence of halides as they influence passivation. Cyclic voltammetric studies were carried out on iron in different sodium hydroxide solutions in presence of halides. In alkali solutions iron formed hydroxo complexes and their polymers in the interfacial diffusion layer. With progress of time they formed a cation selective layer. The diffusion layer turned into bipolar ion selective layer consisted of halides, a selective inner sublayer to the metal side and cation selective outer layer to the solution side. At very high anodic potentials, dehydration and deprotonation led to the conversion of salt layer into an oxide.

Abiotic Formation of Methyl Halides in the Terrestrial Environment

Science.gov (United States)

Keppler, F.

2011-12-01

Methyl chloride and methyl bromide are the most abundant chlorine and bromine containing organic compounds in the atmosphere. Since both compounds have relatively long tropospheric lifetimes they can effectively transport halogen atoms from the Earth's surface, where they are released, to the stratosphere and following photolytic oxidation form reactive halogen gases that lead to the chemical destruction of ozone. Methyl chloride and methyl bromide account for more than 20% of the ozone-depleting halogens delivered to the stratosphere and are predicted to grow in importance as the chlorine contribution to the stratosphere from anthropogenic CFCs decline. Today methyl chloride and methyl bromide originate mainly from natural sources with only a minor fraction considered to be of anthropogenic origin. However, until as recently as 2000 most of the methyl chloride and methyl bromide input to the atmosphere was considered to originate from the oceans, but investigations in recent years have clearly demonstrated that terrestrial sources such as biomass burning, wood-rotting fungi, coastal salt marshes, tropical vegetation and organic matter degradation must dominate the atmospheric budgets of these trace gases. However, many uncertainties still exist regarding strengths of both sources and sinks, as well as the mechanisms of formation of these naturally occurring halogenated gases. A better understanding of the atmospheric budget of both methyl chloride and methyl bromide is therefore required for reliable prediction of future ozone depletion. Biotic and abiotic methylation processes of chloride and bromide ion are considered to be the dominant pathways of formation of these methyl halides in nature. In this presentation I will focus on abiotic formation processes in the terrestrial environment and the potential parameters that control their emissions. Recent advances in our understanding of the abiotic formation pathway of methyl halides will be discussed. This will

The impact of alkali metal halide electron donor complexes in the photocatalytic degradation of pentachlorophenol

Energy Technology Data Exchange (ETDEWEB)

Khuzwayo, Z., E-mail: zack.khuzwayo@up.ac.za; Chirwa, E.M.N

2017-01-05

Highlights: • Facilitation of photocatalysis using simple metal-halides as VB hole scavengers. • Recombination prevention by coupled valence and conduction band approaches. • Determination of anions critical levels beyond which process retardation occurs. • Determination of the photocatalytic process rate of reaction kinetics. - Abstract: The performance of photocatalytic oxidation of chemical pollutants is subjected to the presence of anion complexes in natural waters. This study investigated the influence of alkali metal (Na{sup +} (sodium), K{sup +} (potassium)) halides (Cl{sup −} (chloride), Br{sup −} (bromide), F{sup −} (fluoride)) as inorganic ion sources in the photocatalytic degradation of pentachlorophenol (PCP) in batch systems. It was found that the exclusive presence of halides in the absence of an electron acceptor adequately facilitated the photocatalyst process below critical levels of anion populations, where beyond the critical point the process was significantly hindered. Below the determined critical point, the performance in some cases near matches that of the facilitation of the photocatalytic process by exclusive oxygen, acting as an electron scavenger. The coupling of halide ions and oxygenation presented significantly improved photo-oxidation of PCP, this was confirmed by the inclusion of formic acid as a comparative electron donor. The Langmuir-Hinshelwood kinetic expression was used to calculate the performance rate kinetics. The probable impact of the halide anions was discussed with regards to the process of electron hole pair recombination prevention.

Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires.

Science.gov (United States)

Zhang, Dandan; Eaton, Samuel W; Yu, Yi; Dou, Letian; Yang, Peidong

2015-07-29

Halide perovskites have attracted much attention over the past 5 years as a promising class of materials for optoelectronic applications. However, compared to hybrid organic-inorganic perovskites, the study of their pure inorganic counterparts, like cesium lead halides (CsPbX3), lags far behind. Here, a catalyst-free, solution-phase synthesis of CsPbX3 nanowires (NWs) is reported. These NWs are single-crystalline, with uniform growth direction, and crystallize in the orthorhombic phase. Both CsPbBr3 and CsPbI3 are photoluminescence active, with composition-dependent temperature and self-trapping behavior. These NWs with a well-defined morphology could serve as an ideal platform for the investigation of fundamental properties and the development of future applications in nanoscale optoelectronic devices based on all-inorganic perovskites.

Development of alkali halide-optics for high power-IR laser

International Nuclear Information System (INIS)

Pohl, L.

1989-01-01

In this work 'Development of Alkali Halide-Optics for High Power-IR Laser' we investigated the purification of sodiumchloride-, potassiumchloride- and potassiumbromide-raw materials. We succeeded to reduce the content of impurities like Cu, Pb, V, Cr, Mn, Fe, Co and Ni in these raw materials to the lower of ppb's by a Complex-Adsorption-Method (CAM). Crystals were grown from purified substances by 'Kyropoulos' method'. Windows were cur thereof, polished and measured by FTIR-spectroscopy. Analytical data showed, that the resulting crystals were of lower quality than the raw materials. Because of this fact crystal-growing-conditions have to undergo a special improvement. Alkali halide windows from other sources on the market had been tested. (orig.) [de

Stability of magnets levitated above superconductors

International Nuclear Information System (INIS)

Davis, L.C.; Logothetis, E.M.; Soltis, R.E.

1988-01-01

The stability of a permanent magnet levitated above a slab of hard superconductor is considered. The force on a dipole magnet over a perfectly diamagnetic disk is calculated. It is found that the radial component of the force is directed outward and is 10%--20% of the image (vertical) force near the edge. Estimates of the magnetic friction force due to flux motion in a hard superconductor are made using Bean's model. The magnitude of the magnetic friction is large enough to stabilize the magnet over most of the disk for typical values of the critical current in ceramic superconductors (∼10 3 A/cm 2 ), but too small for the highest values reported (>10 6 A/cm 2 ). It is conjectured that flux trapping due to inhomogeneities gives rise to transient restoring forces

Method of fabricating composite superconductors

International Nuclear Information System (INIS)

Koike, Y.; Shiraki, H.; Suzuki, E.; Yoshida, M.

1977-01-01

A method of making stabilized superconductors of a composition such as Nb 3 Sn is disclosed. The method includes forming a stock product comprising a tin base alloy as a core with a copper jacket and having a niobium tube clad thereon. The stock product is then embedded in a good thermally and electrically conducting matrix which is then coreduced until the desired size is obtained. This cold worked product is then submitted to a heat treatment to form superconductors of Nb 3 Sn

Development of high temperature superconductors having high critical current density

International Nuclear Information System (INIS)

Hong, Gye Wong; Kim, C. J.; Lee, H.G.; Kwon, S. C.; Lee, H. J.; Kim, K. B.; Park, J. Y.; Jung, C. H.

2000-08-01

Fabrication of high T c superconductors and its applications for electric power device were carried out for developing superconductor application technologies. High quality YBCO superconductors was fabricated by melt texture growth, top-seeded melt growth process and multi-seeded melt growth process and the properties was compared. The critical current density of the melt processed YBCO superconductors was about few 10,000 A/cm 2 and the levitation force was 50 N. The processing time needed for the growth of the 123 single grain was greatly reduced by applying multi-seeding without no significant degradation of the levitation force. The multi-seeded melt growth process was confirmed as a time-saving and cost-effective method for the fabrication of bulk superconductors with controlled crystallographic orientation

Development of high temperature superconductors having high critical current density

Energy Technology Data Exchange (ETDEWEB)

Hong, Gye Wong; Kim, C. J.; Lee, H.G.; Kwon, S. C.; Lee, H. J.; Kim, K. B.; Park, J. Y.; Jung, C. H

2000-08-01

Fabrication of high T{sub c} superconductors and its applications for electric power device were carried out for developing superconductor application technologies. High quality YBCO superconductors was fabricated by melt texture growth, top-seeded melt growth process and multi-seeded melt growth process and the properties was compared. The critical current density of the melt processed YBCO superconductors was about few 10,000 A/cm{sup 2} and the levitation force was 50 N. The processing time needed for the growth of the 123 single grain was greatly reduced by applying multi-seeding without no significant degradation of the levitation force. The multi-seeded melt growth process was confirmed as a time-saving and cost-effective method for the fabrication of bulk superconductors with controlled crystallographic orientation.

Theory of tunneling in metal--superconductor devices: Supercurrents in the superconductor gap at zero temperature

International Nuclear Information System (INIS)

Garcia, N.; Flores, F.; Guinea, F.

1988-01-01

Tunneling experiments in metal-oxide superconductor have shown the existence of ''leakage'' currents for applied voltages V smaller than one-half of the superconductor gap Δ. These currents are independent of temperature T. Recently experiments with scanning tunneling microscopy (STM) and squeezable tunnel junctions have shown that the observation of the superconductor gap depends strongly on the resistance in the junction. In fact only for resistances larger than ∼10 6 Ω the gap is clearly observable. These experiments have been explained in terms of the perturbative Hamiltonian formalism of Bardeen. However, it may happen that this theory while applicable for very large resistances may not be so for small tunnel resistances. We present here a nonperturbative theory in all orders of the transmitivity chemical bondTochemical bond 2 and show the existence of supercurrents for values of V 2 . We believe that experiments in STM and other junctions should be interpreted in the frame of this theory

Spectroscopic investigation of indium halides as substitudes of mercury in low pressure discharges for lighting applications

Energy Technology Data Exchange (ETDEWEB)

Briefi, Stefan

2012-05-22

Low pressure discharges with indium halides as radiator are discussed as substitutes for hazardous mercury in conventional fluorescent lamps. In this work, the applicability of InBr and InCl in a low pressure discharge light source is investigated. The aim is to identify and understand the physical processes which determine the discharge characteristics and the efficiency of the generated near-UV emission of the indium halide molecule and of the indium atom which is created due to dissociation processes in the plasma. As discharge vessels sealed cylindrical quartz glass tubes which contain a defined amount of indium halide and a rare gas are used. Preliminary investigations showed that for a controlled variation of the indium halide density a well-defined cold spot setup is mandatory. This was realized in the utilized experimental setup. The use of metal halides raises the issue, that power coupling by internal electrodes is not possible as the electrodes would quickly be eroded by the halides. The comparison of inductive and capacitive RF-coupling with external electrodes revealed that inductively coupled discharges provide higher light output and much better long term stability. Therefore, all investigations are carried out using inductive RF-coupling. The diagnostic methods optical emission and white light absorption spectroscopy are applied. As the effects of absorption-signal saturation and reabsorption of emitted radiation within the plasma volume could lead to an underestimation of the determined population densities by orders of magnitude, these effects are considered in the data evaluation. In order to determine the electron temperature and the electron density from spectroscopic measurements, an extended corona model as population model of the indium atom has been set up. A simulation of the molecular emission spectra has been implemented to investigate the rovibrational population processes of the indium halide molecules. The impact of the cold spot

Passive superconductor: A viable method of controlling magnetization multipoles in the SSC dipole

International Nuclear Information System (INIS)

Green, M.A.

1989-02-01

At injection, the magnetization of the superconductor produces the dominant field error in the SSC dipole magnets. The field generated by magnetization currents in the superconductor is rich in higher symmetric multipoles (normal sextupole, normal decapole, and so on). Pieces of passive superconductor properly located within the bore of the dipole magnet can cancel the higher multipoles generated by the SSC dipole coils. The multipoles generated by the passive superconductor (predominantly sextupole and decapole) are controlled by the angular and radial location of the superconductor, the volume of superconductor, and the size of the superconducting filaments within the passive conductor. This paper will present the tolerances on each of these factors. The paper will show that multipole correction using passive superconductor is in general immune to the effects of temperature and magnetization decay due to flux creep, provided that dipole superconductor and the passive correction superconductor are properly specified. When combined with a lumped correction system, the passive superconductor can be a viable alternative to continuous correction coils within the SSC dipoles. 20 refs., 8 figs., 2 tabs

Passive superconductor a viable method of controlling magnetization multipoles in the SSC dipole

International Nuclear Information System (INIS)

Green, M.A.

1989-01-01

At injection, the magnetization of the superconductor produces the dominant field error in the SSC dipole magnets. The field generated by magnetization currents in the superconductor is rich in higher symmetric multipoles (normal sextupole, normal decapole, and so on). Pieces of passive superconductor properly located within the bore of the dipole magnet can cancel the higher multipoles generated by the SSC dipole coils. The multipoles generated by the passive superconductor (predominantly sextupole and decapole) are controlled by the angular and radial location of the superconductor, the volume of superconductor, and the size of the superconducting filaments within the passive conductor. This paper will present the tolerances on each of these factors. The paper will show that multipole correction using passive superconductor is in general immune to the effects of temperature and magnetization decay due to flux creep, provided that dipole superconductor and the passive correction superconductor are properly specified. When combined with a lumped correction system, the passive superconductor can be a viable alternative to continuous correction coils within the SSC dipoles. 20 refs., 8 figs., 2 tabs

EDITORIAL: Focus on Iron-Based Superconductors FOCUS ON IRON-BASED SUPERCONDUCTORS

Science.gov (United States)

Hosono, Hideo; Ren, Zhi-An

2009-02-01

Superconductivity is the most dramatic and clear cut phenomenon in condensed matter physics. Realization of room temperature superconductors, which would lead to the revolution of our society, is an ultimate goal for researchers. The discovery of high Tc cuprate superconductors in 1986 by Bednorz and Müller triggered intensive research worldwide and the maximum critical temperature has been raised above 100 K. Scientific research on this break-through material clarified a new route to high Tc materials, carrier doping to a Mott insulator with anti-ferromagnetic ordering. High superconductivity occurs in the neighborhood of Mott-insulators and Fermi-metals. Such a view, which was completely new, now stands as a guiding principle for exploring new high Tc materials. Many theoretical approaches to the mechanism for cuprate superconductors have been carried out to understand this unexpected material and to predict new high Tc materials. In 2006 a new superconductor based on iron, LaFeOP, was discovered by a group at Tokyo Institute of Technology, Japan. Iron, as a ferromagnet, was believed to be the last element for the realization of superconductivity because of the way ferromagnetism competes against Cooper pair formation. Unexpectedly, however, the critical temperature remained at 4-6 K irrespective of hole/electron-doping. A large increase in the Tc to 26 K was then found in LaFe[O1-xFx]As by the same group (and was published on 23 February 2008, in the Journal of the American Chemical Society). The Tc of this material was further raised to 43 K under a pressure of 2 GPa and scientists in China then achieved a Tc of 56 K at ambient pressure by replacing La with other rare earth ions with smaller radius—a critical temperature that is second only to the high Tc cuprates. This fast progress has revitalized research within superconductivity and in 2008 there were more than seven international symposia specifically on Fe(Ni)-based superconductors. Through the rapid

Thermomechanical measurements of lead halide single crystals

Czech Academy of Sciences Publication Activity Database

Nitsch, Karel; Rodová, Miroslava

2002-01-01

Roč. 234, č. 2 (2002), s. 701-709 ISSN 0370-1972 R&D Projects: GA AV ČR IAA2010926 Institutional research plan: CEZ:AV0Z1010914 Keywords : PbX 2 (X=Cl, Br, I) * coefficients of linear thermal expansion * polymorphism in lead halides Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.930, year: 2002

Doped Tl-1212 and Tl-1223 superconductors

International Nuclear Information System (INIS)

Eder, M.H.

2001-09-01

This work describes the preparation and characterization of thallium-lead-strontium-barium-calcium-(uranium)-copperoxide (Tl-1212, Tl-1223) high-temperature superconductors. The precursors were prepared via nitrate method. After calcination the oxidic powders were mixed with stoichiometric amounts of an Tl 2 O 3 , PbO, Er 2 O 3 and Gd 2 O 3 by milling and afterwards uniaxial compressed. Sintering was carried out in silver foils. X-ray diffractometry and high-resolution microscopy in combination with scanning electron microscopy (including EDAX) were used to study the influence of varying thallium/lead-, strontium/barium-, calcium/rare earth element ratios and the effect of uranium on the phase composition and microstructure of bulk superconductors. Furthermore the influence of the composition on the electrical and magnetical properties was studied. On phase pure Tl-1212 and Tl-1223 superconductors NMR-measurements were done. Small amounts of gadolinium and erbium instead of calcium and excess-uranium have a positive impact on the electrical and magnetical properties of the Tl-1223 superconductors. Higher amounts of these doping elements favor the Tl-1212 phase. Tl-1212 superconductors with varying thallium/lead- strontium/barium- and calcium/gadolinium ratios were prepared phasepure in wide range of doping. Transition temperatures up to 96 K were achieved. It was shown that lead has an oxidation number of +4 and thallium of +3. (author)

Transport measurements in superconductors: critical current of granular high TC ceramic superconductor samples

International Nuclear Information System (INIS)

Passos, W.A.C.

2016-01-01

This work presents a method to obtain critical current of granular superconductors. We have carried out transport measurements (ρxT curves and VxI curves) in a YBa_2Cu_3O_7_-_δ sample to determine critical current density of it. Some specimens reveal a 'semiconductor-like' behavior (electrical resistivity decreases with increasing temperatures above critical temperature T_c of material) competing with superconductor behavior. Due to high granular fraction of the sample, these competition is clearly noted in ρxT curves. Measurements carried out from 0 to 8500 Oe of applied field show the same behavior, and the critical current density of the samples is shown. (author)

Dislocation unpinning model of acoustic emission from alkali halide ...

Indian Academy of Sciences (India)

The present paper reports the dislocation unpinning model of acoustic emis- sion (AE) from ... Acoustic emission; dislocation; alkali halide crystals; plastic deformation. ..... [5] T Nishimura, A Tahara and T Kolama, Jpn. Metal Inst. 64, 339 (2000).

Force measurements for levitated bulk superconductors

International Nuclear Information System (INIS)

Tachi, Y.; Sawa, K.; Iwasa, Y.; Nagashima, K.; Otani, T.; Miyamoto, T.; Tomita, M.; Murakami, M.

2000-01-01

We have developed a force measurement system which enables us to directly measure the levitation force of levitated bulk superconductors. Experimental data of the levitation forces were compared with the results of numerical simulation based on the levitation model that we deduced in our previous paper. They were in fairly good agreement, which confirms that our levitation model can be applied to the force analyses for levitated bulk superconductors. (author)

Force measurements for levitated bulk superconductors

Energy Technology Data Exchange (ETDEWEB)

Tachi, Y. [Department of Electrical Engineering, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama (Japan); ISTEC, Superconductivity Research Laboratory, 1-16-25 Shibaura, Minato-ku, Tokyo (Japan). E-mail: tachi at istec.or.jp; Uemura, N. [Department of Electrical Engineering, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama (Japan); ISTEC, Superconductivity Research Laboratory, 1-16-25 Shibaura, Minato-ku, Tokyo (Japan); Sawa, K. [Department of Electrical Engineering, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama (Japan); Iwasa, Y. [Francis Bitter Magnet Laboratory, Massachusetts Institute of Technology, Cambridge, MA (United States); Nagashima, K. [Railway Technical Research Institute, Hikari-cho, Kokubunji-shi, Tokyo (Japan); Otani, T.; Miyamoto, T.; Tomita, M.; Murakami, M. [ISTEC, Superconductivity Research Laboratory, 1-16-25 Shibaura, Minato-ku, Tokyo (Japan)

2000-06-01

We have developed a force measurement system which enables us to directly measure the levitation force of levitated bulk superconductors. Experimental data of the levitation forces were compared with the results of numerical simulation based on the levitation model that we deduced in our previous paper. They were in fairly good agreement, which confirms that our levitation model can be applied to the force analyses for levitated bulk superconductors. (author)

High temperature superconductors and other superfluids

CERN Document Server

Alexandrov, A S

2017-01-01

Written by eminent researchers in the field, this text describes the theory of superconductivity and superfluidity starting from liquid helium and a charged Bose-gas. It also discusses the modern bipolaron theory of strongly coupled superconductors, which explains the basic physical properties of high-temperature superconductors. This book will be of interest to fourth year graduate and postgraduate students, specialist libraries, information centres and chemists working in high-temperature superconductivity.

Electromechanical properties of superconductors for DOE/OFE applications. Final report

International Nuclear Information System (INIS)

Ekin, J.W.; Bray, S.L.

1998-01-01

In many superconductor applications, especially large magnets, the superconductor is required to perform while under the influence of strong mechanical forces. These forces are commonly due to residual fabrication stress, differential thermal contraction of dissimilar materials, and electromagnetic forces generated within an energized magnet coil. Thorough knowledge of a superconductor's electrical performance under the influence of these forces (electromechanical properties) is required for successful magnet engineering. This report presents results of research conducted during the period from august 1993 through March 1997 on the electromechanical properties of superconductors for DOE/OFE fusion applications

Filters for mobile radio from high Tc ceramic superconductors

International Nuclear Information System (INIS)

Peterson, G.E.; Wong, E.; Alford, N.McN.

1990-01-01

Mobile radio frequencies lie between 30 MHz and 1,000 MHz. This frequency range is ideal for ceramic high T c superconductors. We have designed Chebyshev, Butterworth and interdigital filters that can employ high T c superconductors in the form of rods, tubes and helices. In general, the performance of these filters at milliwatt power levels is excellent. We will describe fabrication of the superconductors and filter design

Alternative route to metal halide free ionic liquids

International Nuclear Information System (INIS)

Takao, Koichiro; Ikeda, Yasuhisa

2008-01-01

An alternative synthetic route to metal halide free ionic liquids using trialkyloxonium salt is proposed. Utility of this synthetic route has been demonstrated by preparing 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid through the reaction between 1-methylimidazole and triethyloxonium tetra-fluoroborate in anhydrous ether. (author)

High point for CERN and high-temperature superconductors

CERN Multimedia

2007-01-01

Amalia Ballarino is named the Superconductor Industry Person of the year 2006. Amalia Ballarino showing a tape of high-superconducting material used for the LHC current leads.The CERN project leader for the high-temperature superconducting current leads for the LHC, Amalia Ballarino, has received the award for "Superconductor Industry Person of the Year". This award, the most prestigious international award in the development and commercialization of superconductors, is presented by the leading industry newsletter "Superconductor Week". Amalia Ballarino was selected from dozens of nominations from around the world by a panel of recognized leading experts in superconductivity. "It is a great honour for me," says Amalia Ballarino. "It has been many years of hard work, and it’s a great satisfaction to see that the work has been completed successfully." Amalia Ballarino has been working on high-temperature superconducting materials sin...

The thermo-elastic instability model of melting of alkali halides in the Debye approximation

Science.gov (United States)

Owens, Frank J.

2018-05-01

The Debye model of lattice vibrations of alkali halides is used to show that there is a temperature below the melting temperature where the vibrational pressure exceeds the electrostatic pressure. The onset temperature of this thermo-elastic instability scales as the melting temperature of NaCl, KCl, and KBr, suggesting its role in the melting of the alkali halides in agreement with a previous more rigorous model.

Comparative Review on Thin Film Growth of Iron-Based Superconductors

Directory of Open Access Journals (Sweden)

Yoshinori Imai

2017-07-01

Full Text Available Since the discovery of the novel iron-based superconductors, both theoretical and experimental studies have been performed intensively. Because iron-based superconductors have a smaller anisotropy than high-Tc cuprates and a high superconducting transition temperature, there have been a lot of researchers working on the film fabrication of iron-based superconductors and their application. Accordingly, many novel features have been reported in the films of iron-based superconductors, for example, the fabrication of the epitaxial film with a higher Tc than bulk samples, the extraction of the metastable phase which cannot be obtained by the conventional solid state reaction, and so on. In this paper, we review the progress of research on thin film fabrications of iron-based superconductors, especially the four categories: LnFeAs(O,F (Ln = Lanthanide, AEFe2As2 (AE = Alkaline-earth metal, FeCh (Ch = Chalcogen, and FeSe monolayer. Furthermore, we focus on two important topics in thin films of iron-based superconductors; one is the substrate material for thin film growth on the iron-based superconductors, and the other is the whole phase diagram in FeSe1-xTex which can be obtained only by using film-fabrication technique.

Large polarons in lead halide perovskites

Science.gov (United States)

Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan; Joshi, Prakriti P.; Mosconi, Edoardo; Jones, Skyler C.; De Angelis, Filippo; Zhu, X.-Y.

2017-01-01

Lead halide perovskites show marked defect tolerance responsible for their excellent optoelectronic properties. These properties might be explained by the formation of large polarons, but how they are formed and whether organic cations are essential remain open questions. We provide a direct time domain view of large polaron formation in single-crystal lead bromide perovskites CH3NH3PbBr3 and CsPbBr3. We found that large polaron forms predominantly from the deformation of the PbBr3− frameworks, irrespective of the cation type. The difference lies in the polaron formation time, which, in CH3NH3PbBr3 (0.3 ps), is less than half of that in CsPbBr3 (0.7 ps). First-principles calculations confirm large polaron formation, identify the Pb-Br-Pb deformation modes as responsible, and explain quantitatively the rate difference between CH3NH3PbBr3 and CsPbBr3. The findings reveal the general advantage of the soft [PbX3]− sublattice in charge carrier protection and suggest that there is likely no mechanistic limitations in using all-inorganic or mixed-cation lead halide perovskites to overcome instability problems and to tune the balance between charge carrier protection and mobility. PMID:28819647

Potentialities in electronics of new high critical temperature superconductors

International Nuclear Information System (INIS)

Hartemann, P.

1989-01-01

The main electronic applications of superconductors involve the signal processing, the electromagnetic wave detection and the magnetometry. Characteristics of devices based on conventional superconductors cooled by liquid helium are given and the changes induced by incorporating high-temperature superconductors are estimated. After a survey of new superconductor properties, the superconducting devices for analog or digital signal processing are reviewed. The gains predicted for high-temperature superconducting analog devices are considered in greater detail. Different sections deal with the infrared or (sub)millimeter wave detection. The most sensitive apparatuses for magnetic measurements are based on SQUIDs. Features of SQUIDs made of granular high-temperature superconducting material samples (grain boundaries behave as barriers of intrinsic junctions) are discussed [fr

Behaviour of magnetic superconductors in a magnetic field

International Nuclear Information System (INIS)

Buzdin, A.I.

1984-01-01

The behaviour of magnetic superconductors with close ferromagnetic and superconducting transition temperatures in a magnetic field is considered. It is shown that on lowering of the temperature the superconducting transition changes from a second to first order transition. The respective critical fields and dependence of the magnetization on the magnetic field and temperature are found. The magnetization discontinuity in the vortex core in magnetic superconductors is noted. Due to this property and the relatively large scattering cross section, magnetic superconductors are convenient for studying the superconducting vortex lattice by neutron diffraction techniques

Nanostructure of propylammonium nitrate in the presence of poly(ethylene oxide) and halide salts

Science.gov (United States)

Stefanovic, Ryan; Webber, Grant B.; Page, Alister J.

2018-05-01

Nanoscale structure of protic ionic liquids is critical to their utility as molecular electrochemical solvents since it determines the capacity to dissolve salts and polymers such as poly(ethylene oxide) (PEO). Here we use quantum chemical molecular dynamics simulations to investigate the impact of dissolved halide anions on the nanostructure of an archetypal nanostructured protic ionic liquid, propylammonium nitrate (PAN), and how this impacts the solvation of a model PEO polymer. At the molecular level, PAN is nanostructured, consisting of charged/polar and uncharged/nonpolar domains. The charged domain consists of the cation/anion charge groups, and is formed by their electrostatic interaction. This domain solvophobically excludes the propyl chains on the cation, which form a distinct, self-assembled nonpolar domain within the liquid. Our simulations demonstrate that the addition of Cl- and Br- anions to PAN disrupts the structure within the PAN charged domain due to competition between nitrate and halide anions for the ammonium charge centre. This disruption increases with halide concentration (up to 10 mol. %). However, at these concentrations, halide addition has little effect on the structure of the PAN nonpolar domain. Addition of PEO to pure PAN also disrupts the structure within the charged domain of the liquid due to hydrogen bonding between the charge groups and the terminal PEO hydroxyl groups. There is little other association between the PEO structure and the surrounding ionic liquid solvent, with strong PEO self-interaction yielding a compact, coiled polymer morphology. Halide addition results in greater association between the ionic liquid charge centres and the ethylene oxide components of the PEO structure, resulting in reduced conformational flexibility, compared to that observed in pure PAN. Similarly, PEO self-interactions increase in the presence of Cl- and Br- anions, compared to PAN, indicating that the addition of halide salts to PAN

Oxygen diffusion in cuprate superconductors

International Nuclear Information System (INIS)

Routbort, J.L.; Rothman, S.J.

1995-01-01

Superconducting properties of the cuprate superconductors depend on the oxygen content of the material; the diffusion of oxygen is thus an important process in the fabrication and application of these materials. This article reviews studies of the diffusion of oxygen in La 2-x Sr x CuO 4 , YBa 2 Cu 3 O 7- δ, YBa 2 Cu 4 O 8 , and the Bi 2 Sr 2 Ca n-1 Cu n O 2+4 (n = 1, and 2) superconductors, and attempt to elucidate the atomic mechanisms responsible

Resonant halide perovskite nanoparticles

Science.gov (United States)

Tiguntseva, Ekaterina Y.; Ishteev, Arthur R.; Komissarenko, Filipp E.; Zuev, Dmitry A.; Ushakova, Elena V.; Milichko, Valentin A.; Nesterov-Mueller, Alexander; Makarov, Sergey V.; Zakhidov, Anvar A.

2017-09-01

The hybrid halide perovskites is a prospective material for fabrication of cost-effective optical devices. Unique perovskites properties are used for solar cells and different photonic applications. Recently, perovskite-based nanophotonics has emerged. Here, we consider perovskite like a high-refractive index dielectric material, which can be considered to be a basis for nanoparticles fabrication with Mie resonances. As a result, we fabricate and study resonant perovskite nanoparticles with different sizes. We reveal, that spherical nanoparticles show enhanced photoluminescence signal. The achieved results lay a cornerstone in the field of novel types of organic-inorganic nanophotonics devices with optical properties improved by Mie resonances.

A Cluster-Bethe lattice treatment for the F-center in alkali-halides

International Nuclear Information System (INIS)

Queiroz, S.L.A. de; Koiller, B.; Maffeo, B.; Brandi, H.S.

1977-01-01

The electronic structure of the F-center in alkali-halides with the NaCl structure has been studied using the Cluster-Bethe lattice method. The central cluster has been taken as constituted by the vacancy and the nearest- and second- neighbors to it, respectively, cations and anions. The optical transitions have been calculated and compared to experimental data on the location of the peak of the F-absorption band. The agreement obtained indicates that this method may be used to study properties of this defect in alkali halides [pt

Electrochemical specific adsorption of halides on Cu 111, 100, and 211: A Density Functional Theory study

International Nuclear Information System (INIS)

McCrum, Ian T.; Akhade, Sneha A.; Janik, Michael J.

2015-01-01

The specific adsorption of ions onto electrode surfaces can affect electrocatalytic reactions. Density functional theory is used to investigate the specific adsorption of aqueous F − , Cl − , Br − , and I − onto Cu (111), (100), and (211) surfaces. The adsorption is increasingly favorable in the order of F − < Cl − < Br − < I − . The adsorption has a weak dependence on the surface facet, with adsorption most favorable on Cu (100) and least favorable on Cu (111). Potential ranges where specific adsorption would be expected on each facet are reported. The thermodynamics of bulk copper halide (CuX, CuX 2 ) formation are also investigated as a function of potential. CuX formation occurs at potentials slightly more positive of halide specific adsorption and of copper oxidation in aqueous electrolytes. Specifically adsorbed halides and bulk CuX may be present during a variety of electrochemical reactions carried out over a Cu electrode in halide containing electrolyte solutions

Simulating atomic-scale phenomena on surfaces of unconventional superconductors

Energy Technology Data Exchange (ETDEWEB)

Kreisel, Andreas; Andersen, Brian [Niels Bohr Institute (Denmark); Choubey, Peayush; Hirschfeld, Peter [Univ. of Florida (United States); Berlijn, Tom [CNMS and CSMD, Oak Ridge National Laboratory (United States)

2016-07-01

Interest in atomic scale effects in superconductors has increased because of two general developments: First, the discovery of new materials as the cuprate superconductors, heavy fermion and Fe-based superconductors where the coherence length of the cooper pairs is as small to be comparable to the lattice constant, rendering small scale effects important. Second, the experimental ability to image sub-atomic features using scanning-tunneling microscopy which allows to unravel numerous physical properties of the homogeneous system such as the quasi particle excitation spectra or various types of competing order as well as properties of local disorder. On the theoretical side, the available methods are based on lattice models restricting the spatial resolution of such calculations. In the present project we combine lattice calculations using the Bogoliubov-de Gennes equations describing the superconductor with wave function information containing sub-atomic resolution obtained from ab initio approaches. This allows us to calculate phenomena on surfaces of superconductors as directly measured in scanning tunneling experiments and therefore opens the possibility to identify underlying properties of these materials and explain observed features of disorder. It will be shown how this method applies to the cuprate material Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8} and a Fe based superconductor.

Enhancement of mechanical properties of 123 superconductors

Science.gov (United States)

Balachandran, Uthamalingam

1995-01-01

A composition and method of preparing YBa.sub.2 Cu.sub.3 O.sub.7-x superconductor. Addition of tin oxide containing compounds to YBCO superconductors results in substantial improvement of fracture toughness and other mechanical properties without affect on T.sub.c. About 5-20% additions give rise to substantially improved mechanical properties.

The Effective Coherence Length in Anisotropic Superconductors

International Nuclear Information System (INIS)

Polturak, E.; Koren, G.; Nesher, O

1999-01-01

If electrons are transmitted from a normal conductor(N) into a superconductor(S), common wisdom has it that the electrons are converted into Cooper pairs within a coherence length from the interface. This is true in conventional superconductors with an isotropic order parameter. We have established experimentally that the situation is rather different in high Tc superconductors having an anisotropic order parameter. We used epitaxial thin film S/N bilayers having different interface orientations in order to inject carriers from S into N along different directions. The distance to which these carriers penetrate were determined through their effect on the Tc of the bilayers. We found that the effective coherence length is 20A only along the a or b directions, while in other directions we find a length of 250dr20A out of plane, and an even larger value for in-plane, off high symmetry directions. These observations can be explained using the Blonder-Tinkham-Klapwijk model adapted to anisotropic superconductivity. Several implications of our results on outstanding problems with high Tc junctions will be discussed

Stress analysis in high-temperature superconductors under pulsed field magnetization

Science.gov (United States)

Wu, Haowei; Yong, Huadong; Zhou, Youhe

2018-04-01

Bulk high-temperature superconductors (HTSs) have a high critical current density and can trap a large magnetic field. When bulk superconductors are magnetized by the pulsed field magnetization (PFM) technique, they are also subjected to a large electromagnetic stress, and the resulting thermal stress may cause cracking of the superconductor due to the brittle nature of the sample. In this paper, based on the H-formulation and the law of heat transfer, we can obtain the distributions of electromagnetic field and temperature, which are in qualitative agreement with experiment. After that, based on the dynamic equilibrium equations, the mechanical response of the bulk superconductor is determined. During the PFM process, the change in temperature has a dramatic effect on the radial and hoop stresses, and the maximum radial and hoop stress are 24.2 {{MPa}} and 22.6 {{MPa}}, respectively. The mechanical responses of a superconductor for different cases are also studied, such as the peak value of the applied field and the size of bulk superconductors. Finally, the stresses are also presented for different magnetization methods.

First-principles study of γ-ray detector materials in perovskite halides

Science.gov (United States)

Im, Jino; Jin, Hosub; Stoumpos, Constantinos; Chung, Duck; Liu, Zhifu; Peters, John; Wessels, Bruce; Kanatzidis, Mercouri; Freeman, Arthur

2013-03-01

In an effort to search for good γ-ray detector materials, perovskite halide compounds containing heavy elements were investigated. Despite the three-dimensional network of the corner shared octahedra and the extended nature of the outermost shell, its strong ionic character leads to a large band gap, which is one of the essential criteria for γ-ray detector materials. Thus, considering high density and high atomic number, these pervoskite halides are possible candidate for γ-ray detector materials. We performed first-principles calculations to investigate electronic structures and thermodynamic properties of intrinsic defects in the selected perovskite halide, CsPbBr3. The screened-exchange local density approximation scheme was employed to correct the underestimation of the band gap in the LDA method. As a result, the calculated band gap of CsPbBr3 is found to be suitable for γ-ray detection. Furthermore, defect formation energy calculations allow us to predict thermodynamic and electronic properties of possible intrinsic defects, which affect detector efficiency and energy resolution. Supported by the office of Nonproliferation and Verification R &D under Contract No. DE-AC02-06CH11357

On the electronegativity of the high-Tc oxide superconductor

International Nuclear Information System (INIS)

Zhang Liyuan.

1991-08-01

We employ a very useful quantity, the electronegativity, to classify the superconductor. The value of the group average electronegativity to separate superconductor into two categories is 2. Each category has unique chemical bond features. The high-T c oxide superconductor belongs to the second category with group average electronegativity being larger than 2. Their unusual bond nature also gives new insight into some essential factors beneficial to enhance superconductivity. (author). 9 refs, 2 tabs

Single Crystals of Organolead Halide Perovskites: Growth, Characterization, and Applications

KAUST Repository

Peng, Wei

2017-01-01

Despite their outstanding charge transport characteristics, organolead halide perovskite single crystals grown by hitherto reported crystallization methods are not suitable for most optoelectronic devices due to their small aspect ratios

Enhancement of mechanical properties of 123 superconductors

Science.gov (United States)

Balachandran, U.

1995-04-25

A composition and method are disclosed of preparing YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} superconductor. Addition of tin oxide containing compounds to YBCO superconductors results in substantial improvement of fracture toughness and other mechanical properties without affect on T{sub c}. About 5-20% additions give rise to substantially improved mechanical properties.

Highly Efficient Broadband Yellow Phosphor Based on Zero-Dimensional Tin Mixed-Halide Perovskite.

Science.gov (United States)

Zhou, Chenkun; Tian, Yu; Yuan, Zhao; Lin, Haoran; Chen, Banghao; Clark, Ronald; Dilbeck, Tristan; Zhou, Yan; Hurley, Joseph; Neu, Jennifer; Besara, Tiglet; Siegrist, Theo; Djurovich, Peter; Ma, Biwu

2017-12-27

Organic-inorganic hybrid metal halide perovskites have emerged as a highly promising class of light emitters, which can be used as phosphors for optically pumped white light-emitting diodes (WLEDs). By controlling the structural dimensionality, metal halide perovskites can exhibit tunable narrow and broadband emissions from the free-exciton and self-trapped excited states, respectively. Here, we report a highly efficient broadband yellow light emitter based on zero-dimensional tin mixed-halide perovskite (C 4 N 2 H 14 Br) 4 SnBr x I 6-x (x = 3). This rare-earth-free ionically bonded crystalline material possesses a perfect host-dopant structure, in which the light-emitting metal halide species (SnBr x I 6-x 4- , x = 3) are completely isolated from each other and embedded in the wide band gap organic matrix composed of C 4 N 2 H 14 Br - . The strongly Stokes-shifted broadband yellow emission that peaked at 582 nm from this phosphor, which is a result of excited state structural reorganization, has an extremely large full width at half-maximum of 126 nm and a high photoluminescence quantum efficiency of ∼85% at room temperature. UV-pumped WLEDs fabricated using this yellow emitter together with a commercial europium-doped barium magnesium aluminate blue phosphor (BaMgAl 10 O 17 :Eu 2+ ) can exhibit high color rendering indexes of up to 85.

Correlations between entropy and volume of melting in halide salts

International Nuclear Information System (INIS)

Akdeniz, Z.; Tosi, M.P.

1991-09-01

Melting parameters and transport coefficients in the melt are collated for halides of monovalent, divalent and trivalent metals. A number of systems show a deficit of entropy of melting relative to the linear relationships between entropy change and relative volume change on melting that are found to be approximately obeyed by a majority of halides. These behaviours are discussed on the basis of structural and transport data. The deviating systems are classified into three main classes, namely (i) fast-ion conductors in the high-temperature crystal phase such as AgI, (ii) strongly structured network-like systems such as ZnCl 2 , and (iii) molecular systems melting into associated molecular liquids such as SbCl 3 . (author). 35 refs, 1 fig., 3 tabs

Electron refrigeration in hybrid structures with spin-split superconductors

Science.gov (United States)

Rouco, M.; Heikkilä, T. T.; Bergeret, F. S.

2018-01-01

Electron tunneling between superconductors and normal metals has been used for an efficient refrigeration of electrons in the latter. Such cooling is a nonlinear effect and usually requires a large voltage. Here we study the electron cooling in heterostructures based on superconductors with a spin-splitting field coupled to normal metals via spin-filtering barriers. The cooling power shows a linear term in the applied voltage. This improves the coefficient of performance of electron refrigeration in the normal metal by shifting its optimum cooling to lower voltage, and also allows for cooling the spin-split superconductor by reverting the sign of the voltage. We also show how tunnel coupling spin-split superconductors with regular ones allows for a highly efficient refrigeration of the latter.

Influence of electrode, buffer gas and control gear on metal halide lamp performance

International Nuclear Information System (INIS)

Lamouri, A; Naruka, A; Sulcs, J; Varanasi, C V; Brumleve, T R

2005-01-01

In this paper the influence of electrode composition, buffer gas fill pressure and control gear on the performance of metal halide lamps is investigated. It is shown that pure tungsten electrodes improve lumen maintenance and reduce voltage rise over lamp life. An optimum buffer gas fill pressure condition is discovered which allows for reduced electrode erosion during lamp starting as well as under normal operating conditions. Use of electronic control gear is shown to improve the performance of metal halide lamps

Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics.

Science.gov (United States)

Hoke, Eric T; Slotcavage, Daniel J; Dohner, Emma R; Bowring, Andrea R; Karunadasa, Hemamala I; McGehee, Michael D

2015-01-01

We report on reversible, light-induced transformations in (CH 3 NH 3 )Pb(Br x I 1- x ) 3 . Photoluminescence (PL) spectra of these perovskites develop a new, red-shifted peak at 1.68 eV that grows in intensity under constant, 1-sun illumination in less than a minute. This is accompanied by an increase in sub-bandgap absorption at ∼1.7 eV, indicating the formation of luminescent trap states. Light soaking causes a splitting of X-ray diffraction (XRD) peaks, suggesting segregation into two crystalline phases. Surprisingly, these photo-induced changes are fully reversible; the XRD patterns and the PL and absorption spectra revert to their initial states after the materials are left for a few minutes in the dark. We speculate that photoexcitation may cause halide segregation into iodide-rich minority and bromide-enriched majority domains, the former acting as a recombination center trap. This instability may limit achievable voltages from some mixed-halide perovskite solar cells and could have implications for the photostability of halide perovskites used in optoelectronics.

On the Boiling Points of the Alkyl Halides.

Science.gov (United States)

Correia, John

1988-01-01

Discusses the variety of explanations in organic chemistry textbooks of a physical property of organic compounds. Focuses on those concepts explaining attractive forces between molecules. Concludes that induction interactions play a major role in alkyl halides and other polar organic molecules and should be given wider exposure in chemistry texts.…

X-ray and γ-ray spectroscopy of solids under pressure

International Nuclear Information System (INIS)

Ingalls, R.L.

1992-01-01

The effort is divided into the following: high pressure transitions (Fe, RbCl), XAFS studies of perovskites under pressure (ReO 3 , high-T c superconductors), studies of XANES of alkali halides, and Moessbauer studies (iron silicate spinel)

Interaction between light and superconductors

Science.gov (United States)

Gilabert, Alain

In the first part of this review article we resume briefly the fundamental aspect of the photon-superconductor interaction. The emphase is focused on the characteristic times and on the phenomenological models (the T*, the μ* models and the model of the kinetics equations) describing the out of equilibrium superconductivity. The experiments made on classical illuminated superconductors especially on tunnel junctions are then reported. In the second part we present the applied aspect of the photon-superconductor interaction. The interaction of the light with the high Tc superconductors is reviewed in the last part. Dans la première partie de cet article de revue, on résume brièvement 1'aspect fondamental de l'action des photons sur les supraconducteurs en s'attachant surtout à rappeler les différents temps caractéristiques de cette interaction et les modèles phénoménologiques (le modèle T*, le modèle μ*, le modèle des équations cinétiques) décrivant la supraconductivité hors équilibre. La seconde partie rappelle les expériences réalisées sur les supraconducteurs classiques illuminés et spécialement les jonctions tunnel ainsi que certaines applications de la supraconductivité hors équilibre comme les liens faibles controllables par des moyens optiques. La dernière partie est consacrée aux nouvelles expériences qui démarrent concernant l'action de la lumière sur les supraconducteurs à hautes températures critiques.

Binuclear trivalent and tetravalent uranium halides and cyanides supported by cyclooctatetraene ligands

International Nuclear Information System (INIS)

Wang, Cong-Zhi; Wu, Qun-Yan; Lan, Jian-Hui; Shi, Wei-Qun; Gibson, John K.

2017-01-01

Although the first organoactinide chloride Cp_3UCl (Cp = η"5-C_5H_5) was synthesized more than 50 years ago, binuclear uranium halides remain very rare in organoactinide chemistry. Herein, a series of binuclear trivalent and tetravalent uranium halides and cyanides with cyclooctatetraene ligands, (COT)_2U_2X_n (COT = η"8-C_8H_8; X=F, Cl, CN; n=2, 4), have been systematically studied using scalar-relativistic density functional theory (DFT). The structures with bridging halide or cyanide ligands were predicted to be the most stable complexes of (COT)_2U_2X_n, and all the complexes show weak antiferromagnetic interactions between the uranium centers. However, for each species, there is no significant uranium-uranium bonding interaction. The bonding between the metal and the ligands shows some degree of covalent character, especially between the metal and terminal halide or cyanide ligands. The U-5f and 6d orbitals are predominantly involved in the metal-ligand bonding. All the (COT)_2U_2X_n species were predicted to be more stable compared to the mononuclear half-sandwich complexes at room temperature in the gas phase such that (COT)_2U_2X_4 might be accessible through the known (COT)_2U complex. The tetravalent derivatives (COT)_2U_2X_4 are more energetically favorable than the trivalent (COT)_2U_2X_2 analogs, which may be attributed to the greater number of strong metal-ligand bonds in the former complexes.

Zeroth order phase transition in a holographic superconductor with single impurity

NARCIS (Netherlands)

Zeng, Hua Bi; Zhang, Hai-Qing

We investigate the single normal impurity effect in a superconductor by the holographic method. When the size of impurity is much smaller than the host superconductor, we can reproduce the Anderson theorem, which states that a conventional s-wave superconductor is robust to a normal (non-magnetic)

Physicochemical properties of mixed phosphorus halides

International Nuclear Information System (INIS)

Sladkov, I.B.; Tugarinova, N.S.

1996-01-01

Certain physicochemical properties (thermodynamic characteristics at boiling point, critical constants, density of liquid on the saturation line) of mixed phosphorus halides (PI 3 , PI 2 F, PIF 2 , PI 2 Cl, PICl 2 , PI 1 Br, PIBr 2 , PIClF, PIBrCl, etc.) are determined by means of approximate methods. Reliability of the results obtained is confirmed by comparison of calculated and experimental data for phosphorus compounds of the same type. 7 refs., 3 figs., 4 tabs

Practical superconductor development for electrical power applications

International Nuclear Information System (INIS)

Goretta, K.C.

1991-10-01

Development of useful high-critical-temperature (high-T c ) superconductors requires synthesis of superconducting compounds; fabrication of wires, tapes, and films from these compounds; production of composite structures that incorporate stabilizers or insulators; and design and testing of efficient components. This report describes technical progress of research and development efforts aimed at producing superconducting components based on the Y-Ba-Cu, Bi-Sr-Ca-Cu, Bi-Pb-Sr-Ca-Cu, and Tl-Ba-Ca-Cu oxides systems. Topics discussed are synthesis and heat treatment of high-T c superconductors, formation of monolithic and composite wires and tapes, superconductor/metal connectors, characterization of structures and superconducting and mechanical properties, and fabrication and properties of thin films. Collaborations with industry and academia are also documented. 10 figs

Quasiparticle Green's function theory of the Josephson effect in chiral p-wave superconductor/diffusive normal metal/chiral p-wave superconductor junctions

NARCIS (Netherlands)

Sawa, Y.; Yokoyama, T.; Tanaka, Y.; Golubov, Alexandre Avraamovitch

2007-01-01

We study the Josephson effect in chiral p-wave superconductor/diffusive normal metal (DN)/chiral p-wave superconductor (CP/DN/CP) junctions using quasiclassical Green's function formalism with proper boundary conditions. The px+ipy-wave symmetry of superconducting order parameter is chosen which is

Superconductors go organic

International Nuclear Information System (INIS)

Singleton, John; Mielke, Charles

2002-01-01

Superconductors made from organic molecules are revealing fascinating new physics and could offer huge technological potential as well. Solid-state physicists are simple people. They believe that basic research is best carried out on chemically simple materials. Traditionally they have focused on inorganic elements, alloys, and other straightforward compounds. This approach has provided some notable successes. For example, any physicist over 35 will remember the huge fuss surrounding the discovery of high-temperature cuprate superconductors in 1986, which led to the infamous 'Woodstock of physics' meeting the following year. Just before the cuprates were discovered, however, an alternative view had begun to emerge. Physical chemists such as Klaus Bechgaard, Peter Day, Gunzi Saito, Viktor Schegolev and Jack Williams were suggesting that the 'simple-materials-are-best' assumption was misplaced. They argued that some of the most exciting studies in solid-state physics can - and should - be attempted on crystalline organic materials. Although chemically complex, such materials are beautifully simple in other ways, and they can, for example, provide much more information about basic phenomena like superconductivity and magnetism than supposedly simple materials. Physicists eventually embraced these materials with enthusiasm, and the number of papers on crystalline organic metals overtook those on the high-temperature cuprate superconductors three years ago. The gap has widened ever since, and the fact that God and a billion years of evolution have produced a processor based on three-dimensional arrays of molecules, rather than silicon or gallium-arsenide chips, is taken as a good omen by those working in the field. (U.K.)

Identifying the genes of unconventional high temperature superconductors.

Science.gov (United States)

Hu, Jiangping

We elucidate a recently emergent framework in unifying the two families of high temperature (high [Formula: see text]) superconductors, cuprates and iron-based superconductors. The unification suggests that the latter is simply the counterpart of the former to realize robust extended s-wave pairing symmetries in a square lattice. The unification identifies that the key ingredients (gene) of high [Formula: see text] superconductors is a quasi two dimensional electronic environment in which the d -orbitals of cations that participate in strong in-plane couplings to the p -orbitals of anions are isolated near Fermi energy. With this gene, the superexchange magnetic interactions mediated by anions could maximize their contributions to superconductivity. Creating the gene requires special arrangements between local electronic structures and crystal lattice structures. The speciality explains why high [Formula: see text] superconductors are so rare. An explicit prediction is made to realize high [Formula: see text] superconductivity in Co/Ni-based materials with a quasi two dimensional hexagonal lattice structure formed by trigonal bipyramidal complexes.

Density of states and tunneling characteristics of layered superconductors

International Nuclear Information System (INIS)

Liu, S.H.; Klemm, R.A.

1993-04-01

We have studied the structure of the density-of-states (DOS) curves and tunneling characteristics of layered superconductors with two distinct layers in a unit cell. In general, the peaks of the DOS curves do not correspond to energy gaps of each layer, but depend on the gaps and the interlayer hopping strengths in a complex manner. This makes the interpretation of tunneling data of layered superconductors much less straightforward than isotropic superconductors. Our simulated tunneling characteristics bear certain resemblance to experimental results

Method and apparatus to trigger superconductors in current limiting devices

Science.gov (United States)

Yuan, Xing; Hazelton, Drew Willard; Walker, Michael Stephen

2004-10-26

A method and apparatus for magnetically triggering a superconductor in a superconducting fault current limiter to transition from a superconducting state to a resistive state. The triggering is achieved by employing current-carrying trigger coil or foil on either or both the inner diameter and outer diameter of a superconductor. The current-carrying coil or foil generates a magnetic field with sufficient strength and the superconductor is disposed within essentially uniform magnetic field region. For superconductor in a tubular-configured form, an additional magnetic field can be generated by placing current-carrying wire or foil inside the tube and along the center axial line.

Effect of transparency on the Josephson junction between D-wave superconductors

International Nuclear Information System (INIS)

Rashedi, G

2008-01-01

In this paper, a dc Josephson junction between two singlet superconductors (d-wave and s-wave) with arbitrary reflection coefficient has been investigated theoretically following the famous paper [Y. Tanaka and S. Kashiwaya 1996 Phys. Rev. B 53, R11957]. For the case of High T c superconductors, the c-axes are parallel to an interface with finite transparency and their ab-planes have a mis-orientation. The effect of transparency and mis-orientation on the currents is studied both analytically and numerically. It is observed that, the current phase relations are totally different from the case of ideal transparent Josephson junctions between d-wave superconductors and two s-wave superconductors. This apparatus can be used to demonstrate d-wave order parameter in High T c superconductors

Tunneling conductance in semiconductor-superconductor hybrid structures

Science.gov (United States)

Stenger, John; Stanescu, Tudor D.

2017-12-01

We study the differential conductance for charge tunneling into a semiconductor wire-superconductor hybrid structure, which is actively investigated as a possible scheme for realizing topological superconductivity and Majorana zero modes. The calculations are done based on a tight-binding model of the heterostructure using both a Blonder-Tinkham-Klapwijk approach and a Keldysh nonequilibrium Green's function method. The dependence of various tunneling conductance features on the coupling strength between the semiconductor and the superconductor, the tunnel barrier height, and temperature is systematically investigated. We find that treating the parent superconductor as an active component of the system, rather than a passive source of Cooper pairs, has qualitative consequences regarding the low-energy behavior of the differential conductance. In particular, the presence of subgap states in the parent superconductor, due to disorder and finite magnetic fields, leads to characteristic particle-hole asymmetric features and to the breakdown of the quantization of the zero-bias peak associated with the presence of Majorana zero modes localized at the ends of the wire. The implications of these findings for the effort toward the realization of Majorana bound states with true non-Abelian properties are discussed.

Chemical Origin of the Stability Difference between Copper(I)- and Silver(I)-Based Halide Double Perovskites.

Science.gov (United States)

Xiao, Zewen; Du, Ke-Zhao; Meng, Weiwei; Mitzi, David B; Yan, Yanfa

2017-09-25

Recently, Cu I - and Ag I -based halide double perovskites have been proposed as promising candidates for overcoming the toxicity and instability issues inherent within the emerging Pb-based halide perovskite absorbers. However, up to date, only Ag I -based halide double perovskites have been experimentally synthesized; there are no reports on successful synthesis of Cu I -based analogues. Here we show that, owing to the much higher energy level for the Cu 3d 10 orbitals than for the Ag 4d 10 orbitals, Cu I atoms energetically favor 4-fold coordination, forming [CuX 4 ] tetrahedra (X=halogen), but not 6-fold coordination as required for [CuX 6 ] octahedra. In contrast, Ag I atoms can have both 6- and 4-fold coordinations. Our density functional theory calculations reveal that the synthesis of Cu I halide double perovskites may instead lead to non-perovskites containing [CuX 4 ] tetrahedra, as confirmed by our material synthesis efforts. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Photovoltaic Rudorffites: Lead-Free Silver Bismuth Halides Alternative to Hybrid Lead Halide Perovskites.

Science.gov (United States)

Turkevych, Ivan; Kazaoui, Said; Ito, Eisuke; Urano, Toshiyuki; Yamada, Koji; Tomiyasu, Hiroshi; Yamagishi, Hideo; Kondo, Michio; Aramaki, Shinji

2017-10-09

Hybrid CPbX 3 (C: Cs, CH 3 NH 3 ; X: Br, I) perovskites possess excellent photovoltaic properties but are highly toxic, which hinders their practical application. Unfortunately, all Pb-free alternatives based on Sn and Ge are extremely unstable. Although stable and non-toxic C 2 ABX 6 double perovskites based on alternating corner-shared AX 6 and BX 6 octahedra (A=Ag, Cu; B=Bi, Sb) are possible, they have indirect and wide band gaps of over 2 eV. However, is it necessary to keep the corner-shared perovskite structure to retain good photovoltaic properties? Here, we demonstrate another family of photovoltaic halides based on edge-shared AX 6 and BX 6 octahedra with the general formula A a B b X x (x=a+3 b) such as Ag 3 BiI 6 , Ag 2 BiI 5 , AgBiI 4 , AgBi 2 I 7 . As perovskites were named after their prototype oxide CaTiO 3 discovered by Lev Perovski, we propose to name these new ABX halides as rudorffites after Walter Rüdorff, who discovered their prototype oxide NaVO 2 . We studied structural and optoelectronic properties of several highly stable and promising Ag-Bi-I photovoltaic rudorffites that feature direct band gaps in the range of 1.79-1.83 eV and demonstrated a proof-of-concept FTO/c-m-TiO 2 /Ag 3 BiI 6 /PTAA/Au (FTO: fluorine-doped tin oxide, PTAA: poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine], c: compact, m: mesoporous) solar cell with photoconversion efficiency of 4.3 %. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Rigid levitation, flux pinning, thermal depinning, and fluctuation in high-Tc superconductors

International Nuclear Information System (INIS)

Brandt, E.H.

1991-01-01

Here, the author shows that the strong velocity-independent frictional force on a levitating superconductor and on any type-II superconductor moving in a homogeneous magnetic field is caused by pinning and depinning of the magnetic flux lines in its interior. Levitation may thus be used to investigate the pinning properties of a superconductor, and friction in a superconductor bearing may be minimized by choosing appropriate materials and geometries

Study of the glass formation of high temperature superconductors

Science.gov (United States)

Ethridge, Edwin C.; Kaukler, William F.; Rolin, Terry

1992-01-01

A number of compositions of ceramic oxide high T(sub c) superconductors were elevated for their glass formation ability by means of rapid thermal analysis during quenching, optical, and electron microscopy of the quenched samples, and with subsequent DSC measurements. Correlations between experimental measurements and the methodical composition changes identified the formulations of superconductors that can easily form glass. The superconducting material was first formed as a glass; then, with subsequent devitrification, it was formed into a bulk crystalline superconductor by a series of processing methods.

Epitaxial heterojunctions of oxide semiconductors and metals on high temperature superconductors

Science.gov (United States)

Vasquez, Richard P. (Inventor); Hunt, Brian D. (Inventor); Foote, Marc C. (Inventor)

1994-01-01

Epitaxial heterojunctions formed between high temperature superconductors and metallic or semiconducting oxide barrier layers are provided. Metallic perovskites such as LaTiO3, CaVO3, and SrVO3 are grown on electron-type high temperature superconductors such as Nd(1.85)Ce(0.15)CuO(4-x). Alternatively, transition metal bronzes of the form A(x)MO(3) are epitaxially grown on electron-type high temperature superconductors. Also, semiconducting oxides of perovskite-related crystal structures such as WO3 are grown on either hole-type or electron-type high temperature superconductors.

Experimental constraints on theories of high Tc superconductors

International Nuclear Information System (INIS)

Little, W.A.

1989-01-01

Recent experiments on the high-T c superconductors have begun to narrow the possible theoretical explanations of the phenomenon. Experimental evidence on the size, structure and symmetry of the charge carriers will be reviewed; evidence for and against strong coupling; and, recent results on a search for direct evidence of magnetic signature in the coupling mechanism will be presented. The authors show how these experiments impose strong constraints on the theories of these superconductors. A new type of experiment is also discussed which appears capable of identifying the true nature of the coupling mechanism if the superconductors prove to be BCS-like in nature

Electronic Raman response in electron-doped cuprate superconductors

International Nuclear Information System (INIS)

Geng Zhihao; Feng Shiping

2012-01-01

The electronic Raman response in the electron-doped cuprate superconductors is studied based on the t-t'-J model. It is shown that although the domelike shape of the doping dependent peak energy in the B 2g symmetry is a common feature for both electron-doped and hole-doped cuprate superconductors, there are pronounced deviations from a cubic response in the B 2g channel and a linear response in the B 2g channel for the electron-doped case in the low energy limit. It is also shown that these pronounced deviations are mainly caused by a nonmonotonic d-wave gap in the electron-doped cuprate superconductors.

Magnetization studies in high temperature and conventional superconductors

International Nuclear Information System (INIS)

Grover, A.K.; Chaddah, P.

1991-01-01

In this paper, the authors state the contemporary view of the physical basis of a celebrated phenomenological model for hard superconductors. The authors highlight the qualitative and general predictions of this model relevant to various magnetic measurements. The authors give prescriptions to correlate data of different experiments with the predictions of the model with the intention of extracting information on material parameters, like J c (H), pinning potential, etc. These prescriptions will be illustrated with the data on both conventional and HTSC superconductors. The correlation of these data with the predictions of the model underscores the similarity in behaviour between the two classes of hard superconductors

Holographic superconductor in the analytic hairy black hole

International Nuclear Information System (INIS)

Myung, Yun Soo; Park, Chanyong

2011-01-01

We study the charged black hole of hyperbolic horizon with scalar hair (charged Martinez-Troncoso-Zanelli: CMTZ black hole) as a model of analytic hairy black hole for holographic superconductor. For this purpose, we investigate the second order phase transition between CMTZ and hyperbolic Reissner-Nordstroem-AdS (HRNAdS) black holes. However, this transition unlikely occurs. As an analytic treatment for holographic superconductor, we develop superconductor in the bulk and superfluidity on the boundary using the CMTZ black hole below the critical temperature. The presence of charge destroys the condensates around the zero temperature, which is in accord with the thermodynamic analysis of the CMTZ black hole.

Chemical stability of high-temperature superconductors

Science.gov (United States)

Bansal, Narottam P.

1992-01-01

A review of the available studies on the chemical stability of the high temperature superconductors (HTS) in various environments was made. The La(1.8)Ba(0.2)CuO4 HTS is unstable in the presence of H2O, CO2, and CO. The YBa2Cu3O(7-x) superconductor is highly susceptible to degradation in different environments, especially water. The La(2-x)Ba(x)CuO4 and Bi-Sr-Ca-Cu-O HTS are relatively less reactive than the YBa2Cu3O(7-x). Processing of YBa2Cu3O(7-x) HTS in purified oxygen, rather than in air, using high purity noncarbon containing starting materials is recommended. Exposure of this HTS to the ambient atmosphere should also be avoided at all stages during processing and storage. Devices and components made out of these oxide superconductors would have to be protected with an impermeable coating of a polymer, glass, or metal to avoid deterioration during use.

Towards ferromagnet/superconductor junctions on graphene

International Nuclear Information System (INIS)

Pakkayil, Shijin Babu

2015-01-01

Ever since A. Aspect et al. performed the famous 1982 experiment to prove the violation of Bell's inequality, there have been suggestions to conduct the same experiment in a solid state system. Some of those proposals involve superconductors as the source of entangled electron pair and spin depended interfaces as the optical analogue of polariser/filter. Semiconductors can serve as the best medium for such an experiment due to their long relaxation lengths. So far there are no reports on a ferromagnet/superconductor junctions on a semiconductor even though such junctions has been successfully realised in metallic systems. This thesis reports the successful fabrication of ferromagnet/superconductor junction along with characterising measurements in a perfectly two dimensional zero-gap semiconductor known as graphene. Since it's discovery in 2004, graphene has attracted prodigious interest from both academia and industry due to it's inimitable physical properties: very high mobility, high thermal and electrical conductivity, a high Young's modulus and impermeability. Graphene is also expected to have very long spin relaxation length and high spin life time because of it's low spin orbit coupling. For this reason and since researchers are always looking for novel materials and devices to comply with the high demands for better and faster data storage devices, graphene has emanated as a brand new material system for spin based devices. The very first spin injection and detection in graphene was realised in 2007 and ever since, the focal point of the research has been to improve the spin transport properties. A part of this thesis discusses a new fabrication recipe which has a high yield for successfully contacting graphene with a ferromagnet. A high starting yield for ferromagnetic contacts is a irremissible condition for combining superconducting contacts to the device to fabricate ferromagnet/superconductor junctions. Any fabrication recipe

Towards ferromagnet/superconductor junctions on graphene

Energy Technology Data Exchange (ETDEWEB)

Pakkayil, Shijin Babu

2015-07-01

Ever since A. Aspect et al. performed the famous 1982 experiment to prove the violation of Bell's inequality, there have been suggestions to conduct the same experiment in a solid state system. Some of those proposals involve superconductors as the source of entangled electron pair and spin depended interfaces as the optical analogue of polariser/filter. Semiconductors can serve as the best medium for such an experiment due to their long relaxation lengths. So far there are no reports on a ferromagnet/superconductor junctions on a semiconductor even though such junctions has been successfully realised in metallic systems. This thesis reports the successful fabrication of ferromagnet/superconductor junction along with characterising measurements in a perfectly two dimensional zero-gap semiconductor known as graphene. Since it's discovery in 2004, graphene has attracted prodigious interest from both academia and industry due to it's inimitable physical properties: very high mobility, high thermal and electrical conductivity, a high Young's modulus and impermeability. Graphene is also expected to have very long spin relaxation length and high spin life time because of it's low spin orbit coupling. For this reason and since researchers are always looking for novel materials and devices to comply with the high demands for better and faster data storage devices, graphene has emanated as a brand new material system for spin based devices. The very first spin injection and detection in graphene was realised in 2007 and ever since, the focal point of the research has been to improve the spin transport properties. A part of this thesis discusses a new fabrication recipe which has a high yield for successfully contacting graphene with a ferromagnet. A high starting yield for ferromagnetic contacts is a irremissible condition for combining superconducting contacts to the device to fabricate ferromagnet/superconductor junctions. Any fabrication recipe

Fractional Josephson vortices in two-gap superconductor long Josephson junctions

Science.gov (United States)

Kim, Ju

2014-03-01

We investigated the phase dynamics of long Josephson junctions (LJJ) with two-gap superconductors in the broken time reversal symmetry state. In this LJJ, spatial phase textures (i-solitons) can be excited due to the presence of two condensates and the interband Joesphson effect between them. The presence of a spatial phase texture in each superconductor layer leads to a spatial variation of the critical current density between the superconductor layers. We find that this spatial dependence of the crtitical current density can self-generate magnetic flux in the insulator layer, resulting in Josephson vortices with fractional flux quanta. Similar to the situation in a YBa2 Cu3O7 - x superconductor film grain boundary, the fractionalization of a Josephson vortex arises as a response to either periodic or random excitation of i-solitions. This suggests that magnetic flux measurements may be used to probe i-soliton excitations in multi-gap superconductor LJJs.

Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors

NARCIS (Netherlands)

Pedesseau, Laurent; Sapori, Daniel; Traore, Boubacar; Robles, Roberto; Fang, Hong-Hua; Loi, Maria Antonietta; Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe; Neukirch, Amanda; Tretiak, Sergei; Mohite, Aditya D.; Katan, Claudine; Even, Jacky; Kepenekian, Mikael

2016-01-01

Layered halide hybrid organic inorganic perovskites (HOP) have been the subject of intense investigation before the rise of three-dimensional (3D) HOP and their impressive performance in solar cells. Recently, layered HOP have also been proposed as attractive alternatives for photostable solar cells

Strong Carrier-Phonon Coupling in Lead Halide Perovskite Nanocrystals

NARCIS (Netherlands)

Iaru, Claudiu M; Geuchies, Jaco J|info:eu-repo/dai/nl/370526090; Koenraad, Paul M; Vanmaekelbergh, Daniël|info:eu-repo/dai/nl/304829137; Silov, Andrei Yu

2017-01-01

We highlight the importance of carrier-phonon coupling in inorganic lead halide perovskite nanocrystals. The low-temperature photoluminescence (PL) spectrum of CsPbBr3 has been investigated under a nonresonant and a nonstandard, quasi-resonant excitation scheme, and phonon replicas of the main PL

Homocoupling of aryl halides in flow: Space integration of lithiation and FeCl3 promoted homocoupling

Directory of Open Access Journals (Sweden)

Aiichiro Nagaki

2011-08-01

Full Text Available The use of FeCl3 resulted in a fast homocoupling of aryllithiums, and this enabled its integration with the halogen–lithium exchange reaction of aryl halides in a flow microreactor. This system allows the homocoupling of two aryl halides bearing electrophilic functional groups, such as CN and NO2, in under a minute.

Modeling of superconductors based on the timedependent Ginsburg-Landau equations

Science.gov (United States)

Grishakov, K. S.; Degtyarenko, P. N.; Degtyarenko, N. N.; Elesin, V. F.; Kruglov, V. S.

2009-11-01

Results of modeling of superconductor magnetization process based on a numerical solution of the timedependent Ginsburg-Landau equations are presented. Methods of grid approximation of the equations and method of finite elements are used. Two-dimensional patterns of changes in the order parameter and supercurrent distribution in superconductors are calculated and visualized. The main results are in agreement with the well-known representations for type I and II superconductors.

Self-trapped holes in alkali silver halide crystals

International Nuclear Information System (INIS)

Awano, T.; Ikezawa, M.; Matsuyama, T.

1995-01-01

γ-Ray irradiation at 77 K induces defects in M 2 AgX 3 (M=Rb, K and NH 4 ; X=Br and I) crystals. The irradiation induces self-trapped holes of the form of I 0 in the case of alkali silver iodides, and (halogen) 2 - and (halogen) 0 in the case of ammonium silver halides. The (halogen) 0 is weakly coupled with the nearest alkali metal ion or ammonium ion. It is able to be denoted as RbI + , KI + , NH 4 I + or NH 4 Br + . The directions of hole distribution of (halogen) 2 - and (halogen) 0 were different in each case of the alkali silver iodides, ammonium silver halides and mixed crystal of them. The (halogen) 0 decayed at 160 K in annealing process. The (halogen) 2 - was converted into another form of (halogen) 2 - at 250 K and this decayed at 310 K. A formation of metallic layers was observed on the crystal surface parallel with the c-plane of (NH 4 ) 2 AgI 3 irradiated at room temperature. (author)

Large polarons in lead halide perovskites

OpenAIRE

Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan; Joshi, Prakriti P.; Mosconi, Edoardo; Jones, Skyler C.; De Angelis, Filippo; Zhu, X.-Y.

2017-01-01

Lead halide perovskites show marked defect tolerance responsible for their excellent optoelectronic properties. These properties might be explained by the formation of large polarons, but how they are formed and whether organic cations are essential remain open questions. We provide a direct time domain view of large polaron formation in single-crystal lead bromide perovskites CH3NH3PbBr3 and CsPbBr3. We found that large polaron forms predominantly from the deformation of the PbBr3 ? framewor...

Charge and spin transport in mesoscopic superconductors

Directory of Open Access Journals (Sweden)

M. J. Wolf

2014-02-01

Full Text Available Background: Non-equilibrium charge transport in superconductors has been investigated intensely in the 1970s and 1980s, mostly in the vicinity of the critical temperature. Much less attention has been paid to low temperatures and the role of the quasiparticle spin.Results: We report here on nonlocal transport in superconductor hybrid structures at very low temperatures. By comparing the nonlocal conductance obtained by using ferromagnetic and normal-metal detectors, we discriminate charge and spin degrees of freedom. We observe spin injection and long-range transport of pure, chargeless spin currents in the regime of large Zeeman splitting. We elucidate charge and spin transport by comparison to theoretical models.Conclusion: The observed long-range chargeless spin transport opens a new path to manipulate and utilize the quasiparticle spin in superconductor nanostructures.

Atomic hydrogen effects on high-Tc superconductors

International Nuclear Information System (INIS)

Frantskevich, N.V.; Ulyashin, A.G.; Alifanov, A.V.; Stepanenko, A.V.; Fedotova, V.V.

1999-01-01

The atomic hydrogen effects on the properties of bulk high-temperature superconductors were investigated. It is shown that the insertion of the atomic hydrogen into the bulk of these materials from a DC plasma leads to the increase of the critical current density J c for YBaCuO(123) as well as for BiSrCaCuO(2223) high-temperature superconductors. It is found that the hydrogenation of the He implanted samples with following annealing leads to the optically detected blistering on the surface. It means that the textured thin subsurface layers of high-temperature superconductors can be formed by this method. The improvement of superconductivity by atomic hydrogen can be explained by the passivation of dangling bonds and defects on grain boundaries of these materials

Halide peroxidase in tissues that interact with bacteria in the host squid Euprymna scolopes.

Science.gov (United States)

Small, A L; McFall-Ngai, M J

1999-03-15

An enzyme with similarities to myeloperoxidase, the antimicrobial halide peroxidase in mammalian neutrophils, occurs abundantly in the light organ tissue of Euprymna scolopes, a squid that maintains a beneficial association with the luminous bacterium Vibrio fischeri. Using three independent assays typically applied to the analysis of halide peroxidase enzymes, we directly compared the activity of the squid enzyme with that of human myeloperoxidase. One of these methods, the diethanolamine assay, confirmed that the squid peroxidase requires halide ions for its activity. The identification of a halide peroxidase in a cooperative bacterial association suggested that this type of enzyme can function not only to control pathogens, but also to modulate the interactions of host animals with their beneficial partners. To determine whether the squid peroxidase functions under both circumstances, we examined its distribution in a variety of host tissues, including those that typically interact with bacteria and those that do not. Tissues interacting with bacteria included those that have specific cooperative associations with bacteria (i.e., the light organ and accessory nidamental gland) and those that have transient nonspecific interactions with bacteria (i.e., the gills, which clear the cephalopod circulatory system of invading microorganisms). These bacteria-associated tissues were compared with the eye, digestive gland, white body, and ink-producing tissues, which do not typically interact directly with bacteria. Peroxidase enzyme assays, immunocytochemical localization, and DNA-RNA hybridizations showed that the halide-dependent peroxidase is consistently expressed in high concentration in tissues that interact bacteria. Elevated levels of the peroxidase were also found in the ink-producing tissues, which are known to have enzymatic pathways associated with antimicrobial activity. Taken together, these data suggest that the host uses a common biochemical response to

Five-fold way to new high Tc superconductors

Indian Academy of Sciences (India)

Discovery of high c superconductivity in La2−BaCuO4 by Bednorz and Muller in 1986 was a breakthrough in the 75-year long search for new superconductors. Since then new high c superconductors, not involving copper, have also been discovered. Superconductivity in cuprates also inspired resonating valence ...

Forces and energy dissipation in inhomogeneous non-equilibrium superconductors

International Nuclear Information System (INIS)

Poluehktov, Yu.M.; Slezov, V.V.

1987-01-01

The phenomenological theory of volume forces and dissipation processes in inhomogeneous non-equilibrium superconductors near temperature transition from the normal to superconducting state is constructed. The approach is based on application of dynamic equations of superconductivity formulated on the basis of the Lagrangian formalism. These equations are generalized the Ginzburg-Landau theory in the nonstationary non-equilibrium case for ''foul'' superconductors. The value estimations of volume forces arising in inhomogeneities during relaxation of an order parameter and when the electrical field is penetrated into the superconductor, are given

Binuclear trivalent and tetravalent uranium halides and cyanides supported by cyclooctatetraene ligands

Energy Technology Data Exchange (ETDEWEB)

Wang, Cong-Zhi; Wu, Qun-Yan; Lan, Jian-Hui; Shi, Wei-Qun [Chinese Academy of Sciences, Beijing (China). Laboratory of Nuclear Energy Chemistry and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety; Chai, Zhi-Fang [Chinese Academy of Sciences, Beijing (China). Laboratory of Nuclear Energy Chemistry and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety; Soochow Univ., Suzhou (China). School of Radiological and Interdisciplinary Sciences (RAD-X); Gibson, John K. [Lawrence Berkeley National Laboratory, CA (United States). Chemical Sciences Division

2017-03-01

Although the first organoactinide chloride Cp{sub 3}UCl (Cp = η{sup 5}-C{sub 5}H{sub 5}) was synthesized more than 50 years ago, binuclear uranium halides remain very rare in organoactinide chemistry. Herein, a series of binuclear trivalent and tetravalent uranium halides and cyanides with cyclooctatetraene ligands, (COT){sub 2}U{sub 2}X{sub n} (COT = η{sup 8}-C{sub 8}H{sub 8}; X=F, Cl, CN; n=2, 4), have been systematically studied using scalar-relativistic density functional theory (DFT). The structures with bridging halide or cyanide ligands were predicted to be the most stable complexes of (COT){sub 2}U{sub 2}X{sub n}, and all the complexes show weak antiferromagnetic interactions between the uranium centers. However, for each species, there is no significant uranium-uranium bonding interaction. The bonding between the metal and the ligands shows some degree of covalent character, especially between the metal and terminal halide or cyanide ligands. The U-5f and 6d orbitals are predominantly involved in the metal-ligand bonding. All the (COT){sub 2}U{sub 2}X{sub n} species were predicted to be more stable compared to the mononuclear half-sandwich complexes at room temperature in the gas phase such that (COT){sub 2}U{sub 2}X{sub 4} might be accessible through the known (COT){sub 2}U complex. The tetravalent derivatives (COT){sub 2}U{sub 2}X{sub 4} are more energetically favorable than the trivalent (COT){sub 2}U{sub 2}X{sub 2} analogs, which may be attributed to the greater number of strong metal-ligand bonds in the former complexes.

Searching for superconductors with high critical temperature

Energy Technology Data Exchange (ETDEWEB)

Chao, C

1977-08-18

Critical temperature of superconductors can be and must be raised so that their range of application can be broadened. It was estimated that, in 3 to 5 years, superconductor electric generators might be used in nuclear submarines and/or other applications where the requirements of small volume and light weight are critical. The BCS theory was recapitulated. Possible methods of achieving higher critical temperature were proposed and discussed.

Empirical formula for the parameters of metallic monovalent halides ...

African Journals Online (AJOL)

By collating the data on melting properties and transport coefficients obtained from various experiments and theories for certain halides of monovalent metals, allinclusive linear relationship has been fashioned out. This expression holds between the change in entropy and volume on melting; it is approximately obeyed by ...

Spectroscopy on metal-halide lamps under varying gravity conditions

NARCIS (Netherlands)

Flikweert, A.J.

2008-01-01

Worldwide, 20% of all electricity is used for lighting. For this reason, efficient lamps are economically and ecologically important. High intensity discharge (HID) lamps are efficient lamps. The most common HID lamp these days is the metal-halide (MH) lamp. MH lamps have a good colour rendering

Dislocation unpinning model of acoustic emission from alkali halide ...

Indian Academy of Sciences (India)

AE) from alkali halide crystals. Equations are derived for the strain dependence of the transient AE pulse rate, peak value of the AE pulse rate and the total number of AE pulse emitted. It is found that the AE pulse rate should be maximum for a ...

Halide Perovskites: New Science or ``only'' future Energy Converters?

Science.gov (United States)

Cahen, David

Over the years many new ideas and systems for photovoltaic, PV, solar to electrical energy conversion have been explored, but only a few have really impacted PV's role as a more sustainable, environmentally less problematic and safer source of electrical power than fossil or nuclear fuel-based generation. Will Halide Perovskites, HaPs, be able to join the very select group of commercial PV options? To try to address this question, we put Halide Perovskite(HaP) cells in perspective with respect to other PV cells. Doing so also allows to identify fundamental scientific issues that can be important for PV and beyond. What remains to be seen is if those issues lead to new science or scientific insights or additional use of existing models. Being more specific is problematic, given the fact that this will be 4 months after writing this abstract. Israel National Nano-initiative, Weizmann Institute of Science's Alternative sustainable Energy Research Initiative; Israel Ministries of -Science and of -Infrastructure, Energy & Water.

Double Charged Surface Layers in Lead Halide Perovskite Crystals

KAUST Repository

Sarmah, Smritakshi P.

2017-02-01

Understanding defect chemistry, particularly ion migration, and its significant effect on the surface’s optical and electronic properties is one of the major challenges impeding the development of hybrid perovskite-based devices. Here, using both experimental and theoretical approaches, we demonstrated that the surface layers of the perovskite crystals may acquire a high concentration of positively charged vacancies with the complementary negatively charged halide ions pushed to the surface. This charge separation near the surface generates an electric field that can induce an increase of optical band gap in the surface layers relative to the bulk. We found that the charge separation, electric field, and the amplitude of shift in the bandgap strongly depend on the halides and organic moieties of perovskite crystals. Our findings reveal the peculiarity of surface effects that are currently limiting the applications of perovskite crystals and more importantly explain their origins, thus enabling viable surface passivation strategies to remediate them.

Aluminum Pitting Corrosion in Halide Media: A Quantum Model and Empirical Evidence

Science.gov (United States)

Lashgari, Mohsen; Kianpour, Effat; Mohammadi, Esmaeil

2013-12-01

The phenomenon of localized damage of aluminum oxide surface in the presence of halide anions was scrutinized at an atomistic level, through the cluster approach and density functional theory. The phenomenon was also investigated empirically through Tafel polarization plots and scanning electron microscopy. A distinct behavior witnessed in the fluoride medium was justified through the hard-soft acid-base principle. The atomistic investigations revealed the greatest potency for chloride entrance into the metal oxide lattice and rationalized to the severity of damage. The interaction of halide anions with the oxide surface causing some displacements on the position of Al atoms provides a mechanistic insight of the phenomenon.

The nature of dynamic disorder in lead halide perovskite crystals (Conference Presentation)

Science.gov (United States)

Yaffe, Omer; Guo, Yinsheng; Hull, Trevor; Stoumpos, Costas; Tan, Liang Z.; Egger, David A.; Zheng, Fan; Szpak, Guilherme; Semonin, Octavi E.; Beecher, Alexander N.; Heinz, Tony F.; Kronik, Leeor; Rappe, Andrew M.; Kanatzidis, Mercouri G.; Owen, Jonathan S.; Pimenta, Marcos A.; Brus, Louis E.

2016-09-01

We combine low frequency Raman scattering measurements with first-principles molecular dynamics (MD) to study the nature of dynamic disorder in hybrid lead-halide perovskite crystals. We conduct a comparative study between a hybrid (CH3NH3PbBr3) and an all-inorganic lead-halide perovskite (CsPbBr3). Both are of the general ABX3 perovskite formula, and have a similar band gap and structural phase sequence, orthorhombic at low temperature, changing first to tetragonal and then to cubic symmetry as temperature increases. In the high temperature phases, we find that both compounds show a pronounced Raman quasi-elastic central peak, indicating that both are dynamically disordered.

Organometallic halide perovskite single crystals having low deffect density and methods of preparation thereof

KAUST Repository

Bakr, Osman M.

2016-02-18

The present disclosure presents a method of making a single crystal organometallic halide perovskites, with the formula: AMX3, wherein A is an organic cation, M is selected from the group consisting of: Pb, Sn, Cu, Ni, Co, Fe, Mn, Pd, Cd, Ge, and Eu, and X is a halide. The method comprises the use of two reservoirs containing different precursors and allowing the vapor diffusion from one reservoir to the other one. A solar cell comprising said crystal is also disclosed.

Hybrid crystals of cuprates and iron-based superconductors

Science.gov (United States)

Xia, Dai; Cong-Cong, Le; Xian-Xin, Wu; Jiang-Ping, Hu

2016-07-01

We propose two possible new compounds, Ba2CuO2Fe2As2 and K2CuO2Fe2Se2, which hybridize the building blocks of two high temperature superconductors, cuprates and iron-based superconductors. These compounds consist of square CuO2 layers and antifluorite-type Fe2 X 2 (X = As, Se) layers separated by Ba/K. The calculations of binding energies and phonon spectra indicate that they are dynamically stable, which ensures that they may be experimentally synthesized. The Fermi surfaces and electronic structures of the two compounds inherit the characteristics of both cuprates and iron-based superconductors. These compounds can be superconductors with intriguing physical properties to help to determine the pairing mechanisms of high T c superconductivity. Project supported by the National Basic Research Program of China (Grant No. 2015CB921300), the National Natural Science Foundation of China (Grant Nos. 1190020 and 11334012), and the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No. XDB07000000).

Normal zone soliton in large composite superconductors

International Nuclear Information System (INIS)

Kupferman, R.; Mints, R.G.; Ben-Jacob, E.

1992-01-01

The study of normal zone of finite size (normal domains) in superconductors, has been continuously a subject of interest in the field of applied superconductivity. It was shown that in homogeneous superconductors normal domains are always unstable, so that if a normal domain nucleates, it will either expand or shrink. While testing the stability of large cryostable composite superconductors, a new phenomena was found, the existence of stable propagating normal solitons. The formation of these propagating domains was shown to be a result of the high Joule power generated in the superconductor during the relatively long process of current redistribution between the superconductor and the stabilizer. Theoretical studies were performed in investigate the propagation of normal domains in large composite super conductors in the cryostable regime. Huang and Eyssa performed numerical calculations simulating the diffusion of heat and current redistribution in the conductor, and showed the existence of stable propagating normal domains. They compared the velocity of normal domain propagation with the experimental data, obtaining a reasonable agreement. Dresner presented an analytical method to solve this problem if the time dependence of the Joule power is given. He performed explicit calculations of normal domain velocity assuming that the Joule power decays exponentially during the process of current redistribution. In this paper, the authors propose a system of two one-dimensional diffusion equations describing the dynamics of the temperature and the current density distributions along the conductor. Numerical simulations of the equations reconfirm the existence of propagating domains in the cryostable regime, while an analytical investigation supplies an explicit formula for the velocity of the normal domain

Cuprous halides semiconductors as a new means for highly efficient light-emitting diodes

Science.gov (United States)

Ahn, Doyeol; Park, Seoung-Hwan

2016-01-01

In group-III nitrides in use for white light-emitting diodes (LEDs), optical gain, measure of luminous efficiency, is very low owing to the built-in electrostatic fields, low exciton binding energy, and high-density misfit dislocations due to lattice-mismatched substrates. Cuprous halides I-VII semiconductors, on the other hand, have negligible built-in field, large exciton binding energies and close lattice matched to silicon substrates. Recent experimental studies have shown that the luminescence of I-VII CuCl grown on Si is three orders larger than that of GaN at room temperature. Here we report yet unexplored potential of cuprous halides systems by investigating the optical gain of CuCl/CuI quantum wells. It is found that the optical gain and the luminescence are much larger than that of group III-nitrides due to large exciton binding energy and vanishing electrostatic fields. We expect that these findings will open up the way toward highly efficient cuprous halides based LEDs compatible to Si technology. PMID:26880097

Infrared Dielectric Screening Determines the Low Exciton Binding Energy of Metal-Halide Perovskites.

Science.gov (United States)

Umari, Paolo; Mosconi, Edoardo; De Angelis, Filippo

2018-02-01

The performance of lead-halide perovskites in optoelectronic devices is due to a unique combination of factors, including highly efficient generation, transport, and collection of photogenerated charge carriers. The mechanism behind efficient charge generation in lead-halide perovskites is still largely unknown. Here, we investigate the factors that influence the exciton binding energy (E b ) in a series of metal-halide perovskites using accurate first-principles calculations based on solution of the Bethe-Salpeter equation, coupled to ab initio molecular dynamics simulations. We find that E b is strongly modulated by screening from low-energy phonons, which account for a factor ∼2 E b reduction, while dynamic disorder and rotational motion of the organic cations play a minor role. We calculate E b = 15 meV for MAPbI 3 , in excellent agreement with recent experimental estimates. We then explore how different material combinations (e.g., replacing Pb → Pb:Sn→ Sn; and MA → FA → Cs) may lead to different E b values and highlight the mechanisms underlying E b tuning.

Third-order elastic moduli for alkali-halide crystals possessing the sodium chloride structure

International Nuclear Information System (INIS)

Ray, U.

2010-01-01

The values of third-order elastic moduli for alkali halides, having NaCl-type crystal structure are calculated according to the Born-Mayer potential model, considering the repulsive interactions up to the second nearest neighbours and calculating the values of the potential parameters for each crystal, independently, from the compressibility data. This work presents the first published account of the calculation of the third-order elastic moduli taking the actual value of the potential parameter unlike the earlier works. Third-order elastic constants have been computed for alkali halides at 0 and 300 K. The results of the third-order elastic constants are compared with the available experimental and theoretical data. Very good agreement between experimental and theoretical third-order elastic constant data (except C 123 ) is found. We have also computed the values of the pressure derivatives of second-order elastic constants and Anderson-Grueneisen parameter for alkali halides, which agree reasonably well with the experimental values, indicating the satisfactory nature of our computed data for third-order elastic constants.

Three-dimensional Majorana fermions in chiral superconductors.

Science.gov (United States)

Kozii, Vladyslav; Venderbos, Jörn W F; Fu, Liang

2016-12-01

Using a systematic symmetry and topology analysis, we establish that three-dimensional chiral superconductors with strong spin-orbit coupling and odd-parity pairing generically host low-energy nodal quasiparticles that are spin-nondegenerate and realize Majorana fermions in three dimensions. By examining all types of chiral Cooper pairs with total angular momentum J formed by Bloch electrons with angular momentum j in crystals, we obtain a comprehensive classification of gapless Majorana quasiparticles in terms of energy-momentum relation and location on the Fermi surface. We show that the existence of bulk Majorana fermions in the vicinity of spin-selective point nodes is rooted in the nonunitary nature of chiral pairing in spin-orbit-coupled superconductors. We address experimental signatures of Majorana fermions and find that the nuclear magnetic resonance spin relaxation rate is significantly suppressed for nuclear spins polarized along the nodal direction as a consequence of the spin-selective Majorana nature of nodal quasiparticles. Furthermore, Majorana nodes in the bulk have nontrivial topology and imply the presence of Majorana bound states on the surface, which form arcs in momentum space. We conclude by proposing the heavy fermion superconductor PrOs 4 Sb 12 and related materials as promising candidates for nonunitary chiral superconductors hosting three-dimensional Majorana fermions.

Anomalous Josephson Effect between Even-and Odd-Frequency Superconductors

NARCIS (Netherlands)

Tanaka, Yukio; Golubov, Alexandre Avraamovitch; Kashiwaya, Satoshi; Ueda, Masahito

2007-01-01

We demonstrate that, contrary to standard wisdom, the lowest-order Josephson coupling is possible between odd- and even-frequency superconductors. The origin of this effect is the induced odd- (even-)frequency pairing component at the interface of bulk even- (odd-)frequency superconductors. The

Creation of point defects in superconductors. A short review

International Nuclear Information System (INIS)

Quere, Yves; Rullier-Albenque, Florence.

1981-11-01

Many experiments have been published concerning the radiation damage in superconductors, but relatively few about the mechanisms of defect creation. A short review is presented of what is known on point defect creation in superconductors either by cold-work or by irradiation

Aluminium stabilized Nb$-3$/Sn superconductors

International Nuclear Information System (INIS)

Thoener, M.; Krauth, H.; Rudolph, J.; Szulczyk, A.

1988-01-01

Composite superconductors made of reacted Nb 3 Sn stabilized with high purity Al were produced. Two methods were tested. The first involved soft soldering a Cu clad aluminum tape to the Nb 3 Sn conductor. In the second method the conductor, cable or monolith, was coextruded with the aluminum. Results obtained from using both methods indicated that mechanically reinforcing materials can be easily introduced into superconductors. Tests were conducted to determine magnetoresistance, electric contact resistance, yield strength, Young modulus, critical current, and other properties of the composites. Strengthening with Duratherm during coextrusion was also evaluated

Stress and strain effects on the properties of composite superconductors

International Nuclear Information System (INIS)

Welch, D.O.

1982-01-01

Practical superconductors for use in the production of high magnetic fields are generally in the form of composites of filaments of superconducting material embedded in a matrix of normally conducting material. Lorentz forces which arise during magnet operation are examples of sources of external stress, while internal stresses can arise during the fabrication of the composite superconductor, primarily due to differential thermal contraction between different materials in the composite. The properties of superconducting compounds are often sensitive functions of the elastic strain state in the compound; consequently there is a strong coupling between the mechanical and electrical properties of composite superconductors. The basic features of this phenomenon will be illustrated by a discussion of the properties of simple composite superconductors

Inhibition of mild steel corrosion in acidic medium using synthetic and naturally occurring polymers and synergistic halide additives

Energy Technology Data Exchange (ETDEWEB)

Umoren, S.A. [Department of Chemistry, Faculty of Science, University of Uyo, P.M.B 1017 Uyo (Nigeria)], E-mail: saviourumoren@yahoo.com; Ogbobe, O.; Igwe, I.O. [Department of Polymer and Textile Engineering, School of Engineering and Engineering Technology, Federal University of Technology, P.M.B. 1526 Owerri (Nigeria); Ebenso, E.E. [Department of Chemistry and Chemical Technology, National University of Lesotho, P. O. Roma180, Lesotho (South Africa)

2008-07-15

The corrosion inhibition of mild steel in H{sub 2}SO{sub 4} in the presence of gum arabic (GA) (naturally occurring polymer) and polyethylene glycol (PEG) (synthetic polymer) was studied using weight loss, hydrogen evolution and thermometric methods at 30-60 deg. C. PEG was found to be a better inhibitor for mild steel corrosion in acidic medium than GA. The effect of addition of halides (KCl, KBr and KI) was also studied. Results obtained showed that inhibition efficiency (I%) increased with increase in GA and PEG concentration, addition of halides and with increase in temperature. Increase in inhibition efficiency (I%) and degree of surface coverage ({theta}) was found to follow the trend Cl{sup -} < Br{sup -} < I{sup -} which indicates that the radii and electronegativity of the halide ions play a significant role in the adsorption process. GA and PEG alone and in combination with halides were found to obey Temkin adsorption isotherm. Phenomenon of chemical adsorption is proposed from the trend of inhibition efficiency with temperature and values {delta}G{sub ads}{sup 0} obtained. The synergism parameter, S{sub I} evaluated is found to be greater than unity indicating that the enhanced inhibition efficiency caused by the addition of halides is only due to synergism.

Preparation of gold microparticles using halide ions in bulk block copolymer phases via photoreduction

International Nuclear Information System (INIS)

Cha, Sang-Ho; Kim, Ki-Hyun; Lee, Won-Ki; Lee, Jong-Chan

2009-01-01

Gold microparticles were prepared from the gold salt in the solid bulk phase of a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) block copolymer via a photoreduction process in the presence of halide ions. The shapes and sizes of the gold microparticles were found to be dependent on the types and amount of halide ions as well as the types of cations used due to the combined effects of the adsorption power and oxidative dissolution ability of the additives on gold surfaces. Gold nanorods were obtained when poly(ethylene oxide) was used instead of the block copolymer. This suggests that the poly(propylene oxide) (PPO) parts in the block copolymer are essential for the formation of gold microparticles, even though the degree of the direct interaction between the PPO blocks and gold salt is not significant. - Graphical abstract: Gold microparticles were successfully prepared using halide ions as additives in the polymeric bulk phase via photoreduction with the glow lamp irradiation.

A phenomenological approach to high Tc oxide superconductors

International Nuclear Information System (INIS)

Chela-Flores, J.; Das, M.P.; Saif, A.G.

1987-06-01

Oxide superconductors are described in terms of macroscopic wave functions Ψ and Φ corresponding, respectively, to electron pairs of the superconducting and insulating states. In terms of the total free energy of the system, including the effect of interaction, we discuss the electrodynamic responses of the oxide superconductors in relation with the experiments to data. (author). 10 refs

Coherent and correlated spin transport in nanoscale superconductors

Energy Technology Data Exchange (ETDEWEB)

Morten, Jan Petter

2008-03-15

Motivated by the desire for better understanding of nano electronic systems, we theoretically study the conductance and noise characteristics of current flow between superconductors, ferromagnets, and normal-metals. Such nano structures can reveal information about superconductor proximity effects, spin-relaxation processes, and spintronic effects with potential applications for different areas of mesoscopic physics. We employ the quasiclassical theory of superconductivity in the Keldysh formalism, and calculate the nonequilibrium transport of spin and charge using various approaches like the circuit theory of quantum transport and full counting statistics. For two of the studied structures, we have been able to compare our theory to experimental data and obtain good agreement. Transport and relaxation of spin polarized current in superconductors is governed by energy-dependent transport coefficients and spin-flip rates which are determined by quantum interference effects. We calculate the resulting temperature-dependent spin flow in ferromagnet-superconductor devices. Experimental data for spin accumulation and spin relaxation in a superconducting nano wire is in agreement with the theory, and allows for a spin-flip spectroscopy that determines the dominant mechanism for spin-flip relaxation in the studied samples. A ferromagnet precessing under resonance conditions can give rise to pure spin current injection into superconductors. We find that the absorbed spin current is measurable as a temperature dependent Gilbert damping, which we calculate and compare to experimental data. Crossed Andreev reflection denotes superconducting pairing of electrons flowing from different normal-metal or ferromagnet terminals into a superconductor. We calculate the nonlocal currents resulting from this process in competition with direct electron transport between the normal-metal terminals. We take dephasing into account, and study the nonlocal current when the types of contact in

Demixing in a metal halide lamp, results from modeling

NARCIS (Netherlands)

Beks, M.L.; Hartgers, A.; Mullen, van der J.J.A.M.; Veldhuizen, van E.M.

2005-01-01

Metal Halide (MH) lamps are high pressure discharge devices, containing a complex chemical mixture, to emit light on a broad spectrum while maintaining good efficacies. Lamps of this type were first exhibited by General Electric at the 1964 World Fair in New York [1]. They typically consist of an

Crystal growth, structure and phase studies on gold halides

NARCIS (Netherlands)

Janssen, Eugenius Maria Wilhelmus Janssen

1977-01-01

Only very corrosive substances attack gold, the most noble metal. In this study the reactivity and the phase diagrams of gold with the halogens chlorine, bromine and iodine have been investigated. owing to the noble behaviour of gold, its halides are sensitive to heat; on heating they decompose into

Growth and Characterization of PDMS-Stamped Halide Perovskite Single Microcrystals

NARCIS (Netherlands)

Khoram, P.; Brittman, S.; Dzik, W.I.; Reek, J.N.H.; Garneett, E.C.

2016-01-01

Recently, halide perovskites have attracted considerable attention for optoelectronic applications, but further progress in this field requires a thorough understanding of the fundamental properties of these materials. Studying perovskites in their single-crystalline form provides a model system for

Magnetic excitations in iron chalcogenide superconductors.

Science.gov (United States)

Kotegawa, Hisashi; Fujita, Masaki

2012-10-01

Nuclear magnetic resonance and neutron scattering experiments in iron chalcogenide superconductors are reviewed to make a survey of the magnetic excitations in FeSe, FeSe 1- x Te x and alkali-metal-doped A x Fe 2- y Se 2 ( A = K, Rb, Cs, etc). In FeSe, the intimate relationship between the spin fluctuations and superconductivity can be seen universally for the variations in the off-stoichiometry, the Co-substitution and applied pressure. The isovalent compound FeTe has a magnetic ordering with different wave vector from that of other Fe-based magnetic materials. The transition temperature T c of FeSe increases with Te substitution in FeSe 1- x Te x with small x , and decreases in the vicinity of the end member FeTe. The spin fluctuations are drastically modified by the Te substitution. In the vicinity of the end member FeTe, the low-energy part of the spin fluctuation is dominated by the wave vector of the ordered phase of FeTe; however, the reduction of T c shows that it does not support superconductivity. The presence of same wave vector as that of other Fe-based superconductors in FeSe 1- x Te x and the observation of the resonance mode demonstrate that FeSe 1- x Te x belongs to the same group as most of other Fe-based superconductors in the entire range of x , where superconductivity is mediated by the spin fluctuations whose wave vector is the same as the nesting vector between the hole pockets and the electron pockets. On the other hand, the spin fluctuations differ for alkali-metal-doped A x Fe 2- y Se 2 and FeSe or other Fe-based superconductors in their wave vector and strength in the low-energy part, most likely because of the different Fermi surfaces. The resonance mode with different wave vector suggests that A x Fe 2- y Se 2 has an exceptional superconducting symmetry among Fe-based superconductors.

Synergistic effect of halide ions on the corrosion inhibition of aluminium in H2SO4 using 2-acetylphenothiazine

International Nuclear Information System (INIS)

Ebenso, E.E.

2003-01-01

The corrosion inhibition of aluminium in H 2 SO 4 in the presence of 2-acetylphenothiazine (2APTZ) at temperature range of 30-60 deg. C was studied using the weight loss and thermometric techniques. The effect of addition of halides (KCl, KBr, KI) is also reported. The inhibition efficiency (I, %) increased with increase in concentration of 2APTZ. The addition of the halides increased the inhibition efficiency to a considerable extent. The temperature increased the corrosion rate and inhibition efficiency in the range 30-60 deg. C in the absence and presence of the inhibitor and halides. Phenomenon of chemical adsorption is proposed. Flory-Huggins adsorption isotherm equation was obeyed at all the concentrations studied. The decrease in inhibition efficiency (and surface coverage values) was found to be in the order I - >Br - >Cl - which clearly indicates that the radii and the electronegativity of halides play a significant role in the adsorption process. All the data acquired reveal that 2APTZ acts as an inhibitor in the acid environment from the two techniques used. The synergistic effect of 2APTZ and halide ions is discussed

Modeling the basic superconductor thermodynamical-statistical characteristics

International Nuclear Information System (INIS)

Palenskis, V.; Maknys, K.

1999-01-01

In accordance with the Landau second-order phase transition and other thermodynamical-statistical relations for superconductors, and using the energy gap as an order parameter in the electron free energy presentation, the fundamental characteristics of electrons, such as the free energy, the total energy, the energy gap, the entropy, and the heat capacity dependences on temperature were obtained. The obtained modeling results, in principle, well reflect the basic low- and high-temperature superconductor characteristics

Stability of magnetic tip/superconductor levitation systems

International Nuclear Information System (INIS)

Alqadi, M. K.

2015-01-01

The vertical stability of a magnetic tip over a superconducting material is investigated by using the critical state and the frozen image models. The analytical expressions of the stiffness and the vibration frequency about the equilibrium position are derived in term of the geometrical parameters of the magnet/superconductor system. It is found that the stability of the system depends on the shape of the superconductor as well as its thickness. (paper)

EDITORIAL: The electromagnetic properties of iron-based superconductors The electromagnetic properties of iron-based superconductors

Science.gov (United States)

Prozorov, Ruslan; Gurevich, Alex; Luke, Graeme

2010-05-01

Iron-based superconductors, discovered just a few years ago, are members of a diverse family of pnictides and chalcogenides which may potentially contain hundreds of superconducting compounds. The unconventional, multiband superconductivity in these materials most likely emerges from the quintessential magnetic Fe ions. Along with many similarities to the high-Tc cuprates, the proximity of antiferromagnetism to superconductivity in these semi-metallic materials has attracted much attention. The massive effort aimed at understanding superconductivity in the high-Tc cuprates has stimulated the development of numerous state-of-the-art experimental techniques, improved crystal growth methods and a variety of new theoretical insights. These tools and models were already available and readily applied to the new iron-based superconductors for which lots of high quality new results are being reported literally every day. The current special section represents only a snapshot of these extensive studies performed in the second half of 2009, less than two years after the discovery of 26 K superconductivity in the LaFeAsO compound. The range of various experiments is impressive and this issue is mostly focused on the electromagnetic properties of these iron-based materials. The electromagnetic response is sensitive to the microscopic electronic behavior and therefore can be used to probe the mechanism of superconductivity. On the other hand, it is the electromagnetic response that determines many possible applications of these superconductors, particularly given their extremely high upper critical fields. At this point it is already quite clear that the iron-based superconductors cannot unambiguously fit into any known type of superconductor class and have been placed in one of their own. The metallic ground state of the parent compounds is different from the insulating state of the cuprates and generally exhibits a lower electromagnetic anisotropy. However, similar to the

Processing and characterization of ceramic superconductor/polymer composites

International Nuclear Information System (INIS)

Kander, R.G.; Namboodri, S.L.

1993-01-01

One way to more easily process a brittle high-temperature ceramic superconductor into a useful structure is to combine it with a polymer to form a composite material. Processing of polymer-based composites into complex shapes is well established and relatively easy when compared with traditional ceramic processing unit operations. In addition, incorporating a ceramic superconductor into a polymer matrix can improve mechanical performance as compared with a monolithic ceramic. Finally, because ceramic superconductors are susceptible to attack by moisture, a polymer-based composite structure can also provide protection from deleterious environmental effects. This paper focuses on the processing and subsequent characterization of ceramic superconductor/polymer composites designed primarily for electromagnetic shielding and diamagnetic applications. YBa 2 Cu 3 O 7-x [YBCO] ceramic superconductor is combined with poly(methyl methacrylate) [PMMA] to form novel composite structures. Composite structures have been molded with both a discontinuous superconducting phase (i.e., ceramic particulate reinforced polymers) and with a continuous superconducting phase (i.e., polymer infiltrated porous ceramics). Characterization of these composite structures includes the determination of diamagnetic strength, electromagnetic shielding effectiveness, mechanical performance, and environmental resistance. The goal of this program is to produce a composite structure with increased mechanical integrity and environmental resistance at liquid nitrogen temperatures without compromising the electromagnetic shielding and diamagnetic properties of the superconducting phase. Composites structures of this type are potentially useful in numerous magnetic applications including electromagnetic shielding, magnetic sensors, energy storage, magnetic levitation, and motor windings

Theoretical studies of unconventional superconductors

Energy Technology Data Exchange (ETDEWEB)

Groensleth, Martin Sigurd

2008-07-01

This thesis presents four research papers. In the first three papers we have derived analytical results for the transport properties in unconventional superconductors and ferromagnetic systems with multiple broken symmetries. In Paper I and parts of Paper II we have studied tunneling transport between two non-unitary ferromagnetic spin-triplet superconductors, and found a novel interplay between ferromagnetism and superconductivity manifested in the Josephson effect as a spin- and charge-current in the absence of an applied voltage across the junction. The critical amplitudes of these currents can be adjusted by the relative magnetization direction on each side of the junction. Furthermore, in Paper II, we have found a way of controlling a spin-current between two ferromagnets with spin-orbit coupling. Paper III considers a junction consisting of a ferromagnet and a non-unitary ferromagnetic superconductor, and we show that the conductance spectra contains detailed information about the superconducting gaps and pairing symmetry of the Cooper-pairs. In the last paper we present a Monte Carlo study of an effective Hamiltonian describing orbital currents in the CuO2 layers of high-temperature superconductive cuprates. The model features two intrinsically anisotropic Ising models, coupled through an anisotropic next-nearest neighbor interaction, and an Ashkin-Teller nearest neighbor fourth order coupling. We have studied the specific heat anomaly, as well as the anomaly in the staggered magnetization associated with the orbital currents and its susceptibility. We have found that in a limited parameter regime, the specific heat anomaly is substantially suppressed, while the susceptibility has a non-analytical peak across the order-disorder transition. The model is therefore a candidate for describing the breakup of hidden order when crossing the pseudo-gap line on the under-doped side in the phase diagram of high-temperature superconductors. (Author) 64 refs., figs

Voltage fluctuations in granular superconductors in the perpendicular configuration

International Nuclear Information System (INIS)

Gerashchenko, O V

2003-01-01

The spectral density of voltage fluctuations in granular YBa 2 Cu 3 O 7-δ superconductors in the perpendicular configuration has been studied in the flux flow mode. It has been found that, in this case, the 1/f-voltage noise observed depends weakly on temperature and is associated with motion of a magnetic flux in the superconductor. A comparison of the data obtained with the results of previous measurements in parallel configuration has shown that voltage noise is produced by a single common source, which is presumably associated with self-organization of the critical state in granular superconductors

Application of superconductors to motors, generators, and transmission lines

International Nuclear Information System (INIS)

Kirtley, J.L.

1989-01-01

Superconductors are of interest to the designers of electric power equipment because they can carry current without loss, currents that are large enough to make very intense magnetic fields. This means that superconductors, used in suitable applications, can make electric power equipment smaller, lighter, more efficient, and perhaps with better dynamic response. Two specific applications are considered here: electric machinery (motors and generators) and transmission lines. The so-called high-T c superconductors will have beneficial impact on motors, generators, and transmission lines only if conductors with sufficient mechanical properties and current-carrying capabilities can be developed

Spontaneous Hall effect in a chiral p-wave superconductor

Science.gov (United States)

Furusaki, Akira; Matsumoto, Masashige; Sigrist, Manfred

2001-08-01

In a chiral superconductor with broken time-reversal symmetry a ``spontaneous Hall effect'' may be observed. We analyze this phenomenon by taking into account the surface properties of a chiral superconductor. We identify two main contributions to the spontaneous Hall effect. One contribution originates from the Bernoulli (or Lorentz) force due to spontaneous currents running along the surfaces of the superconductor. The other contribution has a topological origin and is related to the intrinsic angular momentum of Cooper pairs. The latter can be described in terms of a Chern-Simons-like term in the low-energy field theory of the superconductor and has some similarities with the quantum Hall effect. The spontaneous Hall effect in a chiral superconductor is, however, nonuniversal. Our analysis is based on three approaches to the problem: a self-consistent solution of the Bogoliubov-de Gennes equation, a generalized Ginzburg-Landau theory, and a hydrodynamic formulation. All three methods consistently lead to the same conclusion that the spontaneous Hall resistance of a two-dimensional superconducting Hall bar is of order h/(ekFλ)2, where kF is the Fermi wave vector and λ is the London penetration depth; the Hall resistance is substantially suppressed from a quantum unit of resistance. Experimental issues in measuring this effect are briefly discussed.

Interaction between fractional Josephson vortices in multi-gap superconductor tunnel junctions

Science.gov (United States)

Kim, Ju H.

In a long Josephson junction (LJJ) with two-band superconductors, fractionalization of Josephson vortices (fluxons) can occur in the broken time reversal symmetry state when spatial phase textures (i-solitons) are excited. Excitation of i-solitons in each superconductor layer of the junction, arising due to the presence of two condensates and the interband Josephson effect, leads to spatial variation of the critical current density between the superconductor layers. Similar to the situation in a YBa2 Cu3O7 - x superconductor film grain boundary, this spatial dependence of the crtitical current density can self-generate magnetic flux in the insulator layer, resulting in fractional fluxons with large and small fraction of flux quantum. Similar to fluxons in one-band superconductor LJJ, these fractional fluxons are found to interact with each other. The interaction between large and small fractional fluxons determines the size of a fluxon which includes two (one large and one small) fractional fluxons. We discuss the nature of interaction between fractional fluxons and suggest that i-soliton excitations in multi-gap superconductor LJJs may be probed by using magnetic flux measurements.

Trap-Free Hot Carrier Relaxation in Lead–Halide Perovskite Films

KAUST Repository

Bretschneider, Simon A.; Laquai, Fré dé ric; Bonn, Mischa

2017-01-01

Photovoltaic devices that employ lead-halide perovskites as photoactive materials exhibit power conversion efficiencies of 22%. One of the potential routes to go beyond the current efficiencies is to extract charge carriers that carry excess energy, that is, nonrelaxed or

Trap-Free Hot Carrier Relaxation in Lead–Halide Perovskite Films

KAUST Repository

Bretschneider, Simon A.

2017-05-08

Photovoltaic devices that employ lead-halide perovskites as photoactive materials exhibit power conversion efficiencies of 22%. One of the potential routes to go beyond the current efficiencies is to extract charge carriers that carry excess energy, that is, nonrelaxed or

High Temperature Superconductor Resonator Detectors

Data.gov (United States)

National Aeronautics and Space Administration — High Temperature Superconductor (HTS) infrared detectors were studied for years but never matured sufficiently for infusion into instruments. Several recent...

ASM Inaugural Lecture 2009: High temperature superconductors: Materials, mechanisms and applications

International Nuclear Information System (INIS)

Roslan Abdul Shukor

2009-01-01

A surprising variety of new superconducting materials has been discovered in recent years. Many compounds with light elements such as fullerenes, oxides, borides, nitrides, some organic materials and also heavy fermions have been found to superconductor at various temperatures. Hitherto, superconductors have proven to be highly varied in composition but elusive and mysterious. The juxtaposition of superconductivity and magnetism at the nano scale in some of these new materials has paved the way to a rich and exciting new field in condensed matter and materials research. An overview of superconductor research in Malaysian institutions is presented in this paper. Some of the new superconducting materials and their possible mechanisms, conventional and exotic, are presented. The possible role of lattice vibrations in the mechanisms of high temperature superconductivity and the study of this via acoustic methods are discussed. Frozen flux superconductors in a nano magnet-superconductor hybrid system are also discussed. (author)

Halides of BET-TTF: novel hydrated molecular metals

Energy Technology Data Exchange (ETDEWEB)

Laukhina, E.; Ribera, E.; Vidal-Gancedo, J.; Canadell, E.; Veciana, J.; Rovira, C. [Universidad Autonoma de Barcelona, Bellaterra (Spain). Inst. de Ciencia de Materials; Khasanov, S.; Zorina, L.; Shibaeva, R. [Rossijskaya Akademiya Nauk, Chernogolovka (Russian Federation). Inst. Fiziki Tverdogo Tela; Laukhin, V. [Inst. of Problems of Chemical Physics, RAS, Chernogolovka (Russian Federation); Honold, M.; Nam, M.-S.; Singleton, J. [Clarendon Lab., Univ. of Oxford (United Kingdom)

2000-01-07

A hint of superconducting transition has been observed for the first time in a cation radical salt derived from bisethylenethio-tetrathiafulvalene (BET-TTF), the salt (BET-TTF){sub 2}Br.3H{sub 2}O. Here the synthesis, X-ray structure, and physical properties of two hydrated halides of BET-TTF that are isostructural and present stable metallic properties are described. (orig.)

Coherent diffusive transport mediated by Andreev reflections at V=Δ/e in a mesoscopic superconductor/semiconductor/superconductor junction

International Nuclear Information System (INIS)

Kutchinsky, J.; Taboryski, R.; Kuhn, O.; So/rensen, C.B.; Lindelof, P.E.; Kristensen, A.; Hansen, J.B.; Jacobsen, C.S.; Skov, J.L.

1997-01-01

We present experiments revealing a singularity in the coherent current across a superconductor/semiconductor/superconductor (SSmS) junction at the bias voltage corresponding to the superconducting energy gap V=Δ/e. The SSmS structure consists of highly doped GaAs with superconducting electrodes of aluminum configured as an interferometer. The phase-coherent component of the current is probed as the amplitude of h/2e vs magnetic-field oscillations in the differential resistance of the interferometer. copyright 1997 The American Physical Society

The Electrical and Optical Properties of Organometal Halide Perovskites Relevant to Optoelectronic Performance

KAUST Repository

Adinolfi, Valerio

2017-10-12

Organometal halide perovskites are under intense study for use in optoelectronics. Methylammonium and formamidinium lead iodide show impressive performance as photovoltaic materials; a premise that has spurred investigations into light-emitting devices and photodetectors. Herein, the optical and electrical material properties of organometal halide perovskites are reviewed. An overview is given on how the material composition and morphology are tied to these properties, and how these properties ultimately affect device performance. Material attributes and techniques used to estimate them are analyzed for different perovskite materials, with a particular focus on the bandgap, mobility, diffusion length, carrier lifetime, and trap-state density.

Building up an electrocatalytic activity scale of cathode materials for organic halide reductions

International Nuclear Information System (INIS)

Bellomunno, C.; Bonanomi, D.; Falciola, L.; Longhi, M.; Mussini, P.R.; Doubova, L.M.; Di Silvestro, G.

2005-01-01

A wide investigation on the electrochemical activity of four model organic bromides has been carried out in acetonitrile on nine cathodes of widely different affinity for halide anions (Pt, Zn, Hg, Sn, Bi, Pb, Au, Cu, Ag), and the electrocatalytic activities of the latter have been evaluated with respect to three possible inert reference cathode materials, i.e. glassy carbon, boron-doped diamond, and fluorinated boron-doped diamond. A general electrocatalytic activity scale for the process is proposed, with a discussion on its modulation by the configuration of the reacting molecule, and its connection with thermodynamic parameters accounting for halide adsorption

Oxygen diffusion in cuprate superconductors

Energy Technology Data Exchange (ETDEWEB)

Routbort, J.L.; Rothman, S.J.

1995-01-01

Superconducting properties of the cuprate superconductors depend on the oxygen content of the material; the diffusion of oxygen is thus an important process in the fabrication and application of these materials. This article reviews studies of the diffusion of oxygen in La{sub 2}{sub {minus}}{sub {times}}Sr{sub {times}}CuO{sub 4}, YBa{sub 2}Cu{sub 3}O{sub 7}{sub {minus}}{delta}, YBa{sub 2}Cu{sub 4}O{sub 8}, and the Bi{sub 2}Sr{sub 2}Ca{sub n}{sub {minus}}{sub 1}Cu{sub n}O{sub 2}{sub +}{sub 4} (n = 1, and 2) superconductors, and attempt to elucidate the atomic mechanisms responsible.

High-Tc ferroelectrics and superconductors

International Nuclear Information System (INIS)

Muller, K.A.

1990-01-01

The meaning of the title refers to transition temperatures T c in ferroelectrics (FE) and superconductors (S). The highest T c 's in either field are observed in oxides: 1770 K in the ferroelectric La 2 TiO 7 and 125 K in the superconductor Tl 2 Ca 2 Cu 3 O 10 . Therefore, the question can be asked whether the observed high T c 's in oxide FE and S are a pure coincidence or whether there may be an underlying reason for it. This question is addressed first by recalling recent advances concerning anharmonic FE-properties and then by reviewing S-findings in the new compounds related to these properties

Neutron Depolarization in Superconductors

Science.gov (United States)

Zhuchenko, N. K.

1995-04-01

The dependences of neutron depolarization on applied magnetic field are deduced along the magnetization hysteresis loop in terms of the Bean model of the critical state. The depolarization in uniaxial superconductors with the reversible magnetization, including uniaxial magnetic superconductors, is also considered. A strong depolarization is expected if the neutrons travel along the vortex lines. On calcule la dépendance en champ magnétique de la dépolarisation des neutrons le long du cycle d'hystérésis en termes du modèle critique de Bean. On considère aussi la dépolarisation dans les supraconducteurs uniaxiaux en fonction de l'aimantation réversible, y compris pour les supraconducteurs magnétiques. On attend une forte dépolarisation si les neutrons se propagent le long des vortex.

Microstructural factors influencing critical-current densities of high-temperature superconductors

International Nuclear Information System (INIS)

Suenaga, M.

1992-01-01

Microstructural defects are the primary determining factors for the values of critical current densities in superconductors. A review is made to assess, (1) what would be the maximum achievable critical-current density in the oxide superconductors if nearly ideal pinning sites were introduced? and (2) what types of pinning defects are currently introduced in these superconductors and how effective are these in pinning the vortices? Only the case where the applied field is parallel to the c-axis is considered here

Focusing and guiding intense electron beams by a superconductor tube

International Nuclear Information System (INIS)

Roth, P.

1996-01-01

An intense electron beam travelling axially through the opening of a superconductor tube was studied. Model calculations showed that the beam is focused by the superconductor tube when the space-charge effect of the beam electrons is compensated. The tube functions as a lens for electrons injected parallel to the tube axis and also for electrons having a small initial radial velocity component. The electron trajectories were computed, and the focal length of the superconductor tube was estimated. (author). 2 figs., 6 refs

Focusing and guiding intense electron beams by a superconductor tube

Energy Technology Data Exchange (ETDEWEB)

Roth, P

1997-12-31

An intense electron beam travelling axially through the opening of a superconductor tube was studied. Model calculations showed that the beam is focused by the superconductor tube when the space-charge effect of the beam electrons is compensated. The tube functions as a lens for electrons injected parallel to the tube axis and also for electrons having a small initial radial velocity component. The electron trajectories were computed, and the focal length of the superconductor tube was estimated. (author). 2 figs., 6 refs.

Demixing in a metal halide lamp, results from modelling

NARCIS (Netherlands)

Beks, M.L.; Hartgers, A.; Mullen, van der J.J.A.M.

2006-01-01

Convection and diffusion in the discharge region of a metal halide lamp is studied using a computer model built with the plasma modeling package Plasimo. A model lamp contg. mercury and sodium iodide is studied. The effects of the total lamp pressure on the degree of segregation of the light

Fullerenes doped with metal halides

International Nuclear Information System (INIS)

Martin, T.P.; Heinebrodt, M.; Naeher, U.; Goehlich, H.; Lange, T.; Schaber, H.

1993-01-01

The cage-like structure of fullerenes is a challenge to every experimental to put something inside - to dope the fullerenes. In fact, the research team that first identified C 60 as a football-like molecule quickly succeeded in trapping metal atoms inside and in shrinking the cage around this atom by photofragmentation. In this paper we report the results of ''shrink-wrapping'' the fullerenes around metal halide molecules. Of special interest is the critical size (the minimum number of carbon atoms) that can still enclose the dopant. A rough model for the space available inside a carbon cage gives good agreement with the measured shrinking limits. (author). 8 refs, 6 figs

Iron halide mediated atom transfer radical polymerization of methyl methacrylate with N-Alkyl-2-pyridylmethanimine as the ligand

NARCIS (Netherlands)

Zhang, H.; Schubert, U.S.

2004-01-01

The controlled atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) catalyzed by iron halide/N-(n-hexyl)-2-pyridylmethanimine (NHPMI) is described. The ethyl 2-bromoisobutyrate (EBIB)-initiated ATRP with [MMA]0/[EBIB]0/[iron halide]0/[NHPMI]0 = 150/1/1/2 was better controlled in

Exploring FeSe-based superconductors by liquid ammonia method

International Nuclear Information System (INIS)

Ying Tian-Ping; Wang Gang; Jin Shi-Feng; Shen Shi-Jie; Zhang Han; Zhou Ting-Ting; Lai Xiao-Fang; Wang Wan-Yan; Chen Xiao-Long

2013-01-01

Our recent progress on the preparation of a series of new FeSe-based superconductors and the clarification of SC phases in potassium-intercalated iron selenides are reviewed here. By the liquid ammonia method, metals Li, Na, Ca, Sr, Ba, Eu, and Yb are intercalated in between FeSe layers and form superconductors with transition temperatures of 30 K∼46 K, which cannot be obtained by high-temperature routes. In the potassium-intercalated iron selenides, we demonstrate that at least two SC phases exist, K x Fe 2 Se 2 (NH 3 ) y (x ≈ 0.3 and 0.6), determined mainly by the concentration of potassium. NH 3 has little, if any, effect on superconductivity, but plays an important role in stabilizing the structures. All these results provide a new starting point for studying the intrinsic properties of this family of superconductors, especially for their particular electronic structures. (topical review - iron-based high temperature superconductors)

World-record current in the MgB2 superconductor

CERN Multimedia

Antonella Del Rosso

2014-01-01

In the framework of the High-Luminosity LHC project, experts from the CERN Superconductors team recently obtained a world-record current of 20 kA at 24 K in an electrical transmission line consisting of two 20-metre long cables made of Magnesium Diboride (MgB2) superconductor. This result makes the use of such technology a viable solution for long-distance power transportation.   The 20-metre long electrical transmission line containing the two 20 kA MgB2 cables. “The test is an important step in the development of cold electrical power transmission systems based on the use of MgB2,” says Amalia Ballarino, head of the Superconductors and Superconducting Devices section in the Magnet, Superconductors and Cryostat group of the Technology Department, and initiator of this project. “The cables and associated technologies were designed, developed and tested at CERN. The superconducting wire is the result of a long R&D effort that started ...

Theoretical modeling of critical temperature increase in metamaterial superconductors

Science.gov (United States)

Smolyaninov, Igor; Smolyaninova, Vera

Recent experiments have demonstrated that the metamaterial approach is capable of drastic increase of the critical temperature Tc of epsilon near zero (ENZ) metamaterial superconductors. For example, tripling of the critical temperature has been observed in Al-Al2O3 ENZ core-shell metamaterials. Here, we perform theoretical modelling of Tc increase in metamaterial superconductors based on the Maxwell-Garnett approximation of their dielectric response function. Good agreement is demonstrated between theoretical modelling and experimental results in both aluminum and tin-based metamaterials. Taking advantage of the demonstrated success of this model, the critical temperature of hypothetic niobium, MgB2 and H2S-based metamaterial superconductors is evaluated. The MgB2-based metamaterial superconductors are projected to reach the liquid nitrogen temperature range. In the case of an H2S-based metamaterial Tc appears to reach 250 K. This work was supported in part by NSF Grant DMR-1104676 and the School of Emerging Technologies at Towson University.

Ceramic high temperature superconductor levitating motor with laser commutator

International Nuclear Information System (INIS)

Roslan Abd Shukor; Lee Keng Heong

1996-01-01

The design of a magnetically levitating motor using a ceramic high temperature superconductor with laser commutator is discussed. A YBa sub 2 Cu sub 3 O sub 7-δ high temperature superconductor with 25 mm diameter and 6 mm thickness is used to levitate a Nd-Fe-B magnet (19.0 mm diameter and 4.8 mm thickness) which is attached symmetrically to a 150 mm long graphite rod. A smaller magnet (5.5 mm diameter and 2.0 mm thickness) is attached at each end of the rod with the appropriate poles arrangements. A suitable laser beam chopper is used to optically drive a solenoid which repels the smaller magnets thus driving the motor. A simple and efficient liquid nitrogen supply system is designed to cool the superconductor. The stability of the bearing is provided by the flux pinning in this type-II superconductor. Some characteristics of the motor are discussed

Superconductor Digital-RF Receiver Systems

Science.gov (United States)

Mukhanov, Oleg A.; Kirichenko, Dmitri; Vernik, Igor V.; Filippov, Timur V.; Kirichenko, Alexander; Webber, Robert; Dotsenko, Vladimir; Talalaevskii, Andrei; Tang, Jia Cao; Sahu, Anubhav; Shevchenko, Pavel; Miller, Robert; Kaplan, Steven B.; Sarwana, Saad; Gupta, Deepnarayan

Digital superconductor electronics has been experiencing rapid maturation with the emergence of smaller-scale, lower-cost communications applications which became the major technology drivers. These applications are primarily in the area of wireless communications, radar, and surveillance as well as in imaging and sensor systems. In these areas, the fundamental advantages of superconductivity translate into system benefits through novel Digital-RF architectures with direct digitization of wide band, high frequency radio frequency (RF) signals. At the same time the availability of relatively small 4K cryocoolers has lowered the foremost market barrier for cryogenically-cooled digital electronic systems. Recently, we have achieved a major breakthrough in the development, demonstration, and successful delivery of the cryocooled superconductor digital-RF receivers directly digitizing signals in a broad range from kilohertz to gigahertz. These essentially hybrid-technology systems combine a variety of superconductor and semiconductor technologies packaged with two-stage commercial cryocoolers: cryogenic Nb mixed-signal and digital circuits based on Rapid Single Flux Quantum (RSFQ) technology, room-temperature amplifiers, FPGA processing and control circuitry. The demonstrated cryocooled digital-RF systems are the world's first and fastest directly digitizing receivers operating with live satellite signals in X-band and performing signal acquisition in HF to L-band at ˜30GHz clock frequencies.

Contact spectroscopy of high-temperature superconductors. Review

International Nuclear Information System (INIS)

Yanson, I.K.

1991-01-01

We have attempted to systematize the research of high temperature superconductors by means of tunneling and point-contact spectroscopy. The theoretical grounds of the methods are briefly described. The deviations of current-voltage characteristics from ordinary superconductors are considered. The properties of point contacts with direct energy gap measurfements and the fine structure of derivatives of i(v) curves at the overlap energies are reviewed for the high-T c La 2-x Sr x CuO 4 materials

Correction of magnetization sextupole in one-meter long dipole magnets using passing superconductor

International Nuclear Information System (INIS)

Green, M.A.; Althaus, R.F.; Barale, P.J.; Benjegerdes, R.W.; Gilbert, W.S.; Green, M.I.; Scanlan, R.M.

1990-03-01

The generation of higher multipoles due to the magnetization of the superconductor in the dipoles of the SSC is a problem during injection of the beam into the machine. The use of passive superconductor was proposed some years ago to correct the magnetization sextupole in the dipole magnet. This paper presents the LBL test results in which the magnetization sextupole was greatly reduced in two one-meter long dipole magnets by the use of passive superconductor mounted on the magnet bore tube. The magnetization sextupole was reduced a factor of five on one magnet and a factor of eight on the other magnet using this technique. Magnetization decapole was also reduced by the passive superconductor. The passive superconductor method of correction also reduced the temperature dependence of the magnetization multipoles. In addition, the drift in the magnetization sextupole due to flux creep was also reduced. Passive superconductor correction appears to be a promising method of correcting out the effects of superconductor magnetization in SSC dipoles and quadrupoles. 10 refs., 6 figs

Effect of halide-mixing on the switching behaviors of organic-inorganic hybrid perovskite memory

Science.gov (United States)

Hwang, Bohee; Gu, Chungwan; Lee, Donghwa; Lee, Jang-Sik

2017-03-01

Mixed halide perovskite materials are actively researched for solar cells with high efficiency. Their hysteresis which originates from the movement of defects make perovskite a candidate for resistive switching memory devices. We demonstrate the resistive switching device based on mixed-halide organic-inorganic hybrid perovskite CH3NH3PbI3-xBrx (x = 0, 1, 2, 3). Solvent engineering is used to deposit the homogeneous CH3NH3PbI3-xBrx layer on the indium-tin oxide-coated glass substrates. The memory device based on CH3NH3PbI3-xBrx exhibits write endurance and long retention, which indicate reproducible and reliable memory properties. According to the increase in Br contents in CH3NH3PbI3-xBrx the set electric field required to make the device from low resistance state to high resistance state decreases. This result is in accord with the theoretical calculation of migration barriers, that is the barrier to ionic migration in perovskites is found to be lower for Br- (0.23 eV) than for I- (0.29-0.30 eV). The resistive switching may be the result of halide vacancy defects and formation of conductive filaments under electric field in the mixed perovskite layer. It is observed that enhancement in operating voltage can be achieved by controlling the halide contents in the film.

Charge transport through superconductor/Anderson-insulator interfaces

International Nuclear Information System (INIS)

Frydman, A.; Ovadyahu, Z.

1997-01-01

We report on a study of charge transport through superconductor-insulator-superconductor and normal metal endash insulator endash superconductor structures (SIS and NIS junctions, respectively) where the insulator is of the Anderson type. Devices which are characterized by a junction resistance larger than 10 kΩ show behavior which is typical of Giaever tunnel junctions. In structures having smaller resistance, several peculiar features are observed. In the SIS junctions, Josephson coupling is detected over distances much larger then the typical insulator localization length. In addition, a series of resistance peaks appears at voltages of 2Δ/n, where Δ is the superconducting gap. The NIS Junctions exhibit a large resistance dip at subgap bias. We discuss possible interpretations of these findings and suggest that they may result from the presence of high transmission channels through the barrier region. copyright 1997 The American Physical Society

Isotope and multiband effects in layered superconductors.

Science.gov (United States)

Bussmann-Holder, Annette; Keller, Hugo

2012-06-13

In this review we consider three classes of superconductors, namely cuprate superconductors, MgB(2) and the new Fe based superconductors. All of these three systems are layered materials and multiband compounds. Their pairing mechanisms are under discussion with the exception of MgB(2), which is widely accepted to be a 'conventional' electron-phonon interaction mediated superconductor, but extending the Bardeen-Cooper-Schrieffer (BCS) theory to account for multiband effects. Cuprates and Fe based superconductors have higher superconducting transition temperatures and more complex structures. Superconductivity is doping dependent in these material classes unlike in MgB(2) which, as a pure compound, has the highest values of T(c) and a rapid suppression of superconductivity with doping takes place. In all three material classes isotope effects have been observed, including exotic ones in the cuprates, and controversial ones in the Fe based materials. Before the area of high-temperature superconductivity, isotope effects on T(c) were the signature for phonon mediated superconductivity-even when deviations from the BCS value to smaller values were observed. Since the discovery of high T(c) materials this is no longer evident since competing mechanisms might exist and other mediating pairing interactions are discussed which are of purely electronic origin. In this work we will compare the three different material classes and especially discuss the experimentally observed isotope effects of all three systems and present a rather general analysis of them. Furthermore, we will concentrate on multiband signatures which are not generally accepted in cuprates even though they are manifest in various experiments, the evidence for those in MgB(2), and indications for them in the Fe based compounds. Mostly we will consider experimental data, but when possible also discuss theoretical models which are suited to explain the data.

Weak links in high critical temperature superconductors

Science.gov (United States)

Tafuri, Francesco; Kirtley, John R.

2005-11-01

The traditional distinction between tunnel and highly transmissive barriers does not currently hold for high critical temperature superconducting Josephson junctions, both because of complicated materials issues and the intrinsic properties of high temperature superconductors (HTS). An intermediate regime, typical of both artificial superconductor-barrier-superconductor structures and of grain boundaries, spans several orders of magnitude in the critical current density and specific resistivity. The physics taking place at HTS surfaces and interfaces is rich, primarily because of phenomena associated with d-wave order parameter (OP) symmetry. These phenomena include Andreev bound states, the presence of the second harmonic in the critical current versus phase relation, a doubly degenerate state, time reversal symmetry breaking and the possible presence of an imaginary component of the OP. All these effects are regulated by a series of transport mechanisms, whose rules of interplay and relative activation are unknown. Some transport mechanisms probably have common roots, which are not completely clear and possibly related to the intrinsic nature of high-TC superconductivity. The d-wave OP symmetry gives unique properties to HTS weak links, which do not have any analogy with systems based on other superconductors. Even if the HTS structures are not optimal, compared with low critical temperature superconductor Josephson junctions, the state of the art allows the realization of weak links with unexpectedly high quality quantum properties, which open interesting perspectives for the future. The observation of macroscopic quantum tunnelling and the qubit proposals represent significant achievements in this direction. In this review we attempt to encompass all the above aspects, attached to a solid experimental basis of junction concepts and basic properties, along with a flexible phenomenological background, which collects ideas on the Josephson effect in the presence

Weak links in high critical temperature superconductors

International Nuclear Information System (INIS)

Tafuri, Francesco; Kirtley, John R

2005-01-01

The traditional distinction between tunnel and highly transmissive barriers does not currently hold for high critical temperature superconducting Josephson junctions, both because of complicated materials issues and the intrinsic properties of high temperature superconductors (HTS). An intermediate regime, typical of both artificial superconductor-barrier-superconductor structures and of grain boundaries, spans several orders of magnitude in the critical current density and specific resistivity. The physics taking place at HTS surfaces and interfaces is rich, primarily because of phenomena associated with d-wave order parameter (OP) symmetry. These phenomena include Andreev bound states, the presence of the second harmonic in the critical current versus phase relation, a doubly degenerate state, time reversal symmetry breaking and the possible presence of an imaginary component of the OP. All these effects are regulated by a series of transport mechanisms, whose rules of interplay and relative activation are unknown. Some transport mechanisms probably have common roots, which are not completely clear and possibly related to the intrinsic nature of high-T C superconductivity. The d-wave OP symmetry gives unique properties to HTS weak links, which do not have any analogy with systems based on other superconductors. Even if the HTS structures are not optimal, compared with low critical temperature superconductor Josephson junctions, the state of the art allows the realization of weak links with unexpectedly high quality quantum properties, which open interesting perspectives for the future. The observation of macroscopic quantum tunnelling and the qubit proposals represent significant achievements in this direction. In this review we attempt to encompass all the above aspects, attached to a solid experimental basis of junction concepts and basic properties, along with a flexible phenomenological background, which collects ideas on the Josephson effect in the presence

Solution enthalpies of alkali metal halides in water and heavy water mixtures with dimethyl sulfoxide

International Nuclear Information System (INIS)

Egorov, G.I.

1994-01-01

Solution enthalpies of CsF, LiCl, NaI, CsI and some other halides of alkali metals and tetrabutylammonium have been measured by the method of calorimetry. Standard solution enthalpies of all alkali metals (except rubidium) halides in water and heavy water mixtures with dimethylsulfoxide at 298.15 K have been calculated. Isotopic effects in solvation enthalpy of the electrolytes mentioned in aqueous solutions of dimethylsulfoxide have been discussed. 29 refs., 2 figs., 4 tabs

Barium halide nanocrystals in fluorozirconate based glass ceramics for scintillation application

Energy Technology Data Exchange (ETDEWEB)

Selling, J.

2007-07-01

Europium (Eu)-activated barium halide nanocrystals in fluorozirconate based glass ceramics represent a promising class of Xray scintillators. The scintillation in these glass ceramics is mainly caused by the emission of divalent Eu incorporated in hexagonal BaCl{sub 2} nanocrystals which are formed in the glass matrix upon appropriate annealing. Experiments with cerium (Ce)-activated fluorozironate glass ceramics showed that Ce is an interesting alternative. In order to get a better understanding of the scintillation mechanism in Eu- or Ce-activated barium halide nanocrystals, an investigation of the processes in the corresponding bulk material is essential. The objective of this thesis is the investigation of undoped, Eu-, and Ce-doped barium halides by X-ray excited luminescence (XL), pulse height, and scintillation decay spectra. That will help to figure out which of these crystals has the most promising scintillation properties and would be the best nanoparticles for the glass ceramics. Furthermore, alternative dopants like samarium (Sm) and manganese (Mn) were also investigated. Besides the above-mentioned optical investigation electron paramagnetic resonance (EPR) and Moessbauer measurements were carried out in order to complete the picture of Eu-doped barium halides. The EPR data of Eu-doped BaI{sub 2} is anticipated to yield more information about the crystal field and crystal structure that will help to understand the charge carrier process during the scintillation process. The main focus of the Moessbauer investigations was set on the Eu-doped fluorochlorozirconate glass ceramics. The results of this investigation should help to improve the glass ceramics. The Eu{sup 2+}/Eu{sup 3+} ratio in the glass ceramics should be determined and optimize favor of the Eu{sup 2+}. We also want to distinguish between Eu{sup 2+} in the glass matrix and Eu{sup 2+} in the nanocrystals. For a better understanding of Moessbauer spectroscopy on Eu also measurements on Eu in a

Barium halide nanocrystals in fluorozirconate based glass ceramics for scintillation application

International Nuclear Information System (INIS)

Selling, J.

2007-01-01

Europium (Eu)-activated barium halide nanocrystals in fluorozirconate based glass ceramics represent a promising class of Xray scintillators. The scintillation in these glass ceramics is mainly caused by the emission of divalent Eu incorporated in hexagonal BaCl 2 nanocrystals which are formed in the glass matrix upon appropriate annealing. Experiments with cerium (Ce)-activated fluorozironate glass ceramics showed that Ce is an interesting alternative. In order to get a better understanding of the scintillation mechanism in Eu- or Ce-activated barium halide nanocrystals, an investigation of the processes in the corresponding bulk material is essential. The objective of this thesis is the investigation of undoped, Eu-, and Ce-doped barium halides by X-ray excited luminescence (XL), pulse height, and scintillation decay spectra. That will help to figure out which of these crystals has the most promising scintillation properties and would be the best nanoparticles for the glass ceramics. Furthermore, alternative dopants like samarium (Sm) and manganese (Mn) were also investigated. Besides the above-mentioned optical investigation electron paramagnetic resonance (EPR) and Moessbauer measurements were carried out in order to complete the picture of Eu-doped barium halides. The EPR data of Eu-doped BaI 2 is anticipated to yield more information about the crystal field and crystal structure that will help to understand the charge carrier process during the scintillation process. The main focus of the Moessbauer investigations was set on the Eu-doped fluorochlorozirconate glass ceramics. The results of this investigation should help to improve the glass ceramics. The Eu 2+ /Eu 3+ ratio in the glass ceramics should be determined and optimize favor of the Eu 2+ . We also want to distinguish between Eu 2+ in the glass matrix and Eu 2+ in the nanocrystals. For a better understanding of Moessbauer spectroscopy on Eu also measurements on Eu in a CaF 2 host lattice were carried

On the Josephson effect between superconductors in singlet and triplet spin-pairing states

International Nuclear Information System (INIS)

Pals, J.A.; Haeringen, W. van

1977-01-01

An expression is derived for the Josephson current between two weakly coupled superconductors of which one or both have pairs in a spin-triplet state. It is shown that there can be no Josephson effect up to second order in the transition matrix elements between a superconductor with spin-triplet pairs and one with spin-singlet pairs if the coupling between the two superconductors can be described with a spin-conserving tunnel hamiltonian. This is shown to offer a possibility to investigate experimentally whether a particular superconductor has spin-triplet pairs by coupling it weakly to a well-known spin-singlet pairing superconductor. (Auth.)

American superconductor technology to help CERN to explore the mysteries of matter company's high temperature superconductor wire to be used in CERN's Large Hadron Collider

CERN Multimedia

2003-01-01

American Superconductor Corporation has been selected by CERN, to provide 14,000 meters of high temperature superconductor (HTS) wire for current lead devices that will be used in CERN's Large Hadron Collider (1 page).

Metal Halide Perovskite Polycrystalline Films Exhibiting Properties of Single Crystals

NARCIS (Netherlands)

Brenes, Roberto; Guo, D.; Osherov, Anna; Noel, Nakita K.; Eames, Christopher; Hutter, E.M.; Pathak, Sandeep K.; Niroui, Farnaz; Friend, Richard H.; Islam, M. Saiful; Snaith, Henry J.; Bulović, Vladimir; Savenije, T.J.; Stranks, Samuel D.

2017-01-01

Metal halide perovskites are generating enormous excitement for use in solar cells and light-emission applications, but devices still show substantial non-radiative losses. Here, we show that by combining light and atmospheric treatments, we can increase the internal luminescence quantum

Ceramic high-temperature superconductors

International Nuclear Information System (INIS)

Marquart, R.

1989-01-01

The contribution presents an overview treatment of the structure of the new superconductors (YBa 2 Cu 3 O 7-x ). Methods of powder production and processing technology are described, with current development projects by Dornier being taken into consideration. (orig.) [de

Irradiation damage in superconductors

International Nuclear Information System (INIS)

Quere, Y.

1989-01-01

Most superconductors are quite sensitive to irradiation defects. Critical temperatures may be depressed, critical currents may be increased, by irradiation, but other behaviours may be encountered. In compounds, the sublattice in which defects are created is of significant importance. 24 refs

Melting and liquid structure of polyvalent metal halides

International Nuclear Information System (INIS)

Tosi, M.P.

1992-08-01

A short review is given of recent progress in determining and understanding liquid structure types and melting mechanisms for halides of polyvalent metals. The nature of the preferred local coordination for the polyvalent metal ion in the melt can usually be ascertained from data on liquid mixtures with halogen-donating alkali halides. The stability of these local coordination states and the connectivity that arises between them in the approach to the pure melt determines the character of its short-range and possible medium-range order. A broad classification of structural and melting behaviours can be given on the basis of measured melting parameters and transport coefficients for many compounds, in combination with the available diffraction data on the liquid structure of several compounds. Correlations have been shown to exist with a simple indicator of the nature of the chemical bond and also with appropriate parameters of ionic models, wherever the latter are usefully applicable for semiquantitative calculations of liquid structure. Consequences on the mechanisms for valence electron localization in solutions of metallic elements into strongly structured molten salts are also briefly discussed. (author). 46 refs, 4 figs, 2 tabs

In silico optimization of critical currents in superconductors

Energy Technology Data Exchange (ETDEWEB)

Kimmel, Gregory; Sadovskyy, Ivan A.; Glatz, Andreas

2017-07-01

For many technological applications of superconductors the performance of a material is determined by the highest current it can carry losslessly-the critical current. In turn, the critical current can be controlled by adding nonsuperconducting defects in the superconductor matrix. Here we report on systematic comparison of different local and global optimization strategies to predict optimal structures of pinning centers leading to the highest possible critical currents. We demonstrate performance of these methods for a superconductor with randomly placed spherical, elliptical, and columnar defects.

Advanced technologies related to a high temperature superconductor for small laboratory experiments

International Nuclear Information System (INIS)

Ogawa, Yuichi; Mito, Toshiyuki; Yanagi, Nagato

2006-01-01

Advanced technologies related to a high temperature superconductor materials and small refrigerator are reviewed. Mini-RT/RT-1 is designed and constructed as a plasma examination device. The element technology of low temperature apparatus, the results of performance tests and application examples are explained. The superconductors such as Bi 2 Sr 2 CaCu 2 O 8 (Bi-2212) for the low temperature phase, Bi 2 Sr 2 Ca 2 Cu 3 O 10 (Bi-2223) for the high temperature phase, and YBa 2 Cu 3 O y (YBCO or Y123) are described. Advanced 4K-Giford-Mcmahon (GM) refrigerator on the market put superconductor coil made of low temperature superconductor metals to practical use and extends its application field. Small laboratory is able to experiment on the high temperature superconductor materials. (S.Y.)

Mechanoluminescence response to the plastic flow of coloured alkali halide crystals

International Nuclear Information System (INIS)

Chandra, B.P.; Bagri, A.K.; Chandra, V.K.

2010-01-01

The present paper reports the luminescence induced by plastic deformation of coloured alkali halide crystals using pressure steps. When pressure is applied onto a γ-irradiated alkali halide crystal, then initially the mechanoluminescence (ML) intensity increases with time, attains a peak value and later on it decreases with time. The ML of diminished intensity also appears during the release of applied pressure. The intensity I m corresponding to the peak of ML intensity versus time curve and the total ML intensity I T increase with increase in value of the applied pressure. The time t m corresponding to the ML peak slightly decreases with the applied pressure. After t m , initially the ML intensity decreases at a fast rate and later on it decreases at a slow rate. The decay time of the fast decrease in the ML intensity is equal to the pinning time of dislocations and the decay time for the slow decrease of ML intensity is equal to the diffusion time of holes towards the F-centres. The ML intensity increases with the density of F-centres and it is optimum for a particular temperature of the crystals. The ML spectra of coloured alkali halide crystals are similar to the thermoluminescence and afterglow spectra. The peak ML intensity and the total ML intensity increase drastically with the applied pressure following power law, whereby the pressure dependence of the ML intensity is related to the work-hardening exponent of the crystals. The ML also appears during the release of the applied pressure because of the movement of dislocation segments and movements of dislocation lines blocked under pressed condition. On the basis of the model based on the mechanical interaction between dislocation and F-centres, expressions are derived for the ML intensity, which are able to explain different characteristics of the ML. From the measurements of the plastico ML induced by the application of loads on γ-irradiated alkali halide crystals, the pinning time of dislocations

Manganese-Catalyzed Cross-Coupling of Aryl Halides and Grignard Reagents by a Radical Mechanism

DEFF Research Database (Denmark)

Antonacci, Giuseppe; Ahlburg, Andreas; Fristrup, Peter

2017-01-01

The substrate scope and the mechanism have been investigated for the MnCl2-catalyzed cross-coupling reaction between aryl halides and Grignard reagents. The transformation proceeds rapidly and in good yield when the aryl halide component is an aryl chloride containing a cyano or an ester group....... Two radical-clock experiments were carried out, and in both cases an intermediate aryl radical was successfully trapped. The cross-coupling reaction is therefore believed to proceed by an SRN1 mechanism, with a triorganomanganate complex serving as the most likely nucleophile and single-electron donor...

The electronic structure of the F-center in alkali-halides-The Bethe cluster - lattice

International Nuclear Information System (INIS)

Queiroz, S.L.A. de.

1977-07-01

The electronic structure of the F-center in alkali-halides with the NaCl structure has been studied using the Bethe Cluster lattice method. The central cluster has been taken as constituted by the vacancy and the nearest- and second-neighbors to it, respectively cations and anions. The optical transitions have been calculated and compared to experimental data on the location of the peak of the F-absorption band. The agreement obtained indicates that this method may be used to study properties of this defect in alkali halides. (Author) [pt

Reaction between aminoalkyl radicals and akyl halides: Dehalogenation by electron transfer?

Science.gov (United States)

Lalevée, J.; Fouassier, J. P.; Blanchard, N.; Ingold, K. U.

2011-07-01

Aminoalkyl radicals, such as Et2NCrad HCH3, have low oxidation potentials and are therefore powerful reducing agents. We have found that Et2NCrad HCH3 reacts with CCl4 and CBr4 in di-tert-butyl peroxide with bimolecular rate constants (measured by LFP) close, or equal, to the diffusion-controlled limit. For the less reactive halide, CH2Br2, the reaction rate is increased substantially by the addition of acetonitrile as a co-solvent. It is tentatively concluded that these reactions occur by electron-transfer from the aminoalkyl to the organohalide with formation of the iminium ion, Et2N+dbnd CHCH3 (NMR detection), halide ion and a halomethyl radical, e.g., rad CCl3 and rad CHCl2 (ESR, spin-trapping detection).

Workshop on accelerator magnet superconductors. Proceedings

International Nuclear Information System (INIS)

2004-01-01

The workshop on accelerator magnet superconductors has gathered 102 registered participants from research laboratories, universities and industry. 8 European companies, active in superconducting materials and cables were present. This workshop has been organized to deal with the status of the world research and development on superconducting materials and cables for high field magnets (B > 10 T). The workshop has also reviewed the status of high temperature superconductors and transmission line cables for potential use in low field superconducting magnets for injectors and beam transfer lines, as well as cables for pulsed magnets that might be used in future hadron colliders or injectors

Workshop on accelerator magnet superconductors. Proceedings

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-07-01

The workshop on accelerator magnet superconductors has gathered 102 registered participants from research laboratories, universities and industry. 8 European companies, active in superconducting materials and cables were present. This workshop has been organized to deal with the status of the world research and development on superconducting materials and cables for high field magnets (B > 10 T). The workshop has also reviewed the status of high temperature superconductors and transmission line cables for potential use in low field superconducting magnets for injectors and beam transfer lines, as well as cables for pulsed magnets that might be used in future hadron colliders or injectors.

Hybrid Lead Halide Perovskites for Ultrasensitive Photoactive Switching in Terahertz Metamaterial Devices.

Science.gov (United States)

Manjappa, Manukumara; Srivastava, Yogesh Kumar; Solanki, Ankur; Kumar, Abhishek; Sum, Tze Chien; Singh, Ranjan

2017-08-01

The recent meteoric rise in the field of photovoltaics with the discovery of highly efficient solar-cell devices is inspired by solution-processed organic-inorganic lead halide perovskites that exhibit unprecedented light-to-electricity conversion efficiencies. The stunning performance of perovskites is attributed to their strong photoresponsive properties that are thoroughly utilized in designing excellent perovskite solar cells, light-emitting diodes, infrared lasers, and ultrafast photodetectors. However, optoelectronic application of halide perovskites in realizing highly efficient subwavelength photonic devices has remained a challenge. Here, the remarkable photoconductivity of organic-inorganic lead halide perovskites is exploited to demonstrate a hybrid perovskite-metamaterial device that shows extremely low power photoswitching of the metamaterial resonances in the terahertz part of the electromagnetic spectrum. Furthermore, a signature of a coupled phonon-metamaterial resonance is observed at higher pump powers, where the Fano resonance amplitude is extremely weak. In addition, a low threshold, dynamic control of the highly confined electric field intensity is also observed in the system, which could tremendously benefit the new generation of subwavelength photonic devices as active sensors, low threshold optically controlled lasers, and active nonlinear devices with enhanced functionalities in the infrared, optical, and the terahertz parts of the electromagnetic spectrum. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

High-temperature superconductors in application - fight for the top

International Nuclear Information System (INIS)

Anon.

1990-01-01

For the superconductor market two-digit growth rates are predicted until after the year 2000. The decrosslinking of the high temperature superconductors initiated a worldwide race for first applications. The report considers the situation of raw materials and the application potentials in the USA, Japan and Western Europe. (orig.) [de

Iron chalcogenide superconductors at high magnetic fields

Science.gov (United States)

Lei, Hechang; Wang, Kefeng; Hu, Rongwei; Ryu, Hyejin; Abeykoon, Milinda; Bozin, Emil S; Petrovic, Cedomir

2012-01-01

Iron chalcogenide superconductors have become one of the most investigated superconducting materials in recent years due to high upper critical fields, competing interactions and complex electronic and magnetic phase diagrams. The structural complexity, defects and atomic site occupancies significantly affect the normal and superconducting states in these compounds. In this work we review the vortex behavior, critical current density and high magnetic field pair-breaking mechanism in iron chalcogenide superconductors. We also point to relevant structural features and normal-state properties. PMID:27877518

Surface impedance of superconductors in wide frequency ranges for wake field calculations

International Nuclear Information System (INIS)

Davidovskii, V.G.

2006-01-01

The problem of the surface impedance of superconductors in wide frequency ranges for calculations of wake fields, generated by bunches of charged particles moving axially inside a metallic vacuum chambers, is solved. The case of specular electron reflection at the superconductor surface is considered. The expression for the surface impedance of superconductors suitable for numerical computation is derived [ru

Open questions in the magnetic behaviour of high-temperature superconductors

International Nuclear Information System (INIS)

Cohen, L.F.; Jensen, Henrik Jeldtoft

1997-01-01

A principally experimental review of vortex behaviour in high-temperature superconductors is presented. The reader is first introduced to the basic concepts needed to understand the magnetic properties of type II superconductors. The concepts of vortex melting, the vortex glass, vortex creep, etc are also discussed briefly. The bulk part of the review relates the theoretical predictions proposed for the vortex system in high temperature superconductors to experimental findings. The review ends with an attempt to direct the reader to those areas which still require further clarification. (author)

Vortices and nanostructured superconductors

CERN Document Server

2017-01-01

This book provides expert coverage of modern and novel aspects of the study of vortex matter, dynamics, and pinning in nanostructured and multi-component superconductors. Vortex matter in superconducting materials is a field of enormous beauty and intellectual challenge, which began with the theoretical prediction of vortices by A. Abrikosov (Nobel Laureate). Vortices, vortex dynamics, and pinning are key features in many of today’s human endeavors: from the huge superconducting accelerating magnets and detectors at the Large Hadron Collider at CERN, which opened new windows of knowledge on the universe, to the tiny superconducting transceivers using Rapid Single Flux Quanta, which have opened a revolutionary means of communication. In recent years, two new features have added to the intrinsic beauty and complexity of the subject: nanostructured/nanoengineered superconductors, and the discovery of a range of new materials showing multi-component (multi-gap) superconductivity. In this book, leading researche...

Band Gap Tuning and Defect Tolerance of Atomically Thin Two- Dimensional Organic-Inorganic Halide Perovskites

OpenAIRE

Pandey, Mohnish; Jacobsen, Karsten Wedel; Thygesen, Kristian Sommer

2016-01-01

Organic−inorganic halide perovskites have proven highly successful for photovoltaics but suffer from low stability, which deteriorates their performance over time. Recent experiments have demonstrated that low dimensional phases of the hybrid perovskites may exhibit improved stability. Here we report first-principles calculations for isolated monolayers of the organometallic halide perovskites (C4H9NH3)2MX2Y2, where M = Pb, Ge, Sn and X,Y = Cl, Br, I. The band gaps computed using the GLLB-SC ...

Sequential One-Pot Ruthenium-Catalyzed Azide−Alkyne Cycloaddition from Primary Alkyl Halides and Sodium Azide

KAUST Repository

Johansson, Johan R.

2011-04-01

An experimentally simple sequential one-pot RuAAC reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields starting from an alkyl halide, sodium azide, and an alkyne, is reported. The organic azide is formed in situ by treating the primary alkyl halide with sodium azide in DMA under microwave heating. Subsequent addition of [RuClCp*(PPh 3) 2] and the alkyne yielded the desired cycloaddition product after further microwave irradiation. © 2011 American Chemical Society.

Photographing magnetic fields in superconductors

International Nuclear Information System (INIS)

Harrison, R.B.; Wright, L.S.

Magneto-optic techniques coupled with high-speed photography are being used to study the destruction of superconductivity by a magnetic field. The phenomenon of superconductivity will be introduced with emphasis placed on the properties of type I and type II superconductors in a magnetic field. The Faraday effect and its application to the study of the penetration of magnetic fields into these superconductors will be described; the relative effectiveness of some types of paramagnetic glass will be demonstrated. A number of cinefilms will be shown to illustrate the versatility of the magneto-optic method for observing flux motion and patterns. The analysis of data obtained from a high speed film (10,200 fps) of a flux jump in Nb-Zr will be presented and discussed

High-Temperature Cuprate Superconductors Experiment, Theory, and Applications

CERN Document Server

Plakida, Nikolay Maksimilianovich

2010-01-01

High-Temperature Cuprate Superconductors provides an up-to-date and comprehensive review of the properties of these fascinating materials. The essential properties of high-temperature cuprate superconductors are reviewed on the background of their theoretical interpretation. The experimental results for structural, magnetic, thermal, electric, optical and lattice properties of various cuprate superconductors are presented with respect to relevant theoretical models. A critical comparison of various theoretical models involving strong electron correlations, antiferromagnetic spin fluctuations, phonons and excitons provides a background for understanding of the mechanism of high-temperature superconductivity. Recent achievements in their applications are also reviewed. A large number of illustrations and tables gives valuable information for specialists. A text-book level presentation with formulation of a general theory of strong-coupling superconductivity will help students and researches to consolidate their...

Effect of spontaneous decay of superconductor quasiparticles in the tunneling density of states

International Nuclear Information System (INIS)

Coffey, D.

1993-01-01

Superconductivity has been successfully described with either the Landau-Ginzburg theory of second order phase transitions or with strong-coupling versions of the original BCS theory for almost fifty years. Recent tunneling and photoemission data on the cuprate oxide superconductors may now provide evidence of corrections to the mean field approximation. It has been shown by Zasadzinski et al. that there is a dip at eV ≅ 3Δ 0 in the SIS tunneling conductance, which is the derivative of the current across a superconductor-insulator-superconductor junction with respect to the applied voltage, for a set of cuprate superconductors whose T c 's range from 5.5K to 100K. Recently L. Coffey and I proposed an explanation of this feature in terms of the spontaneous decay of mean field quasiparticles. We showed that corrections to the mean field approximation for a superconductor lead to different frequency thresholds for spontaneous quasiparticle decay with different superconductor order parameter symmetries. These effects lead to features in the superconductor density of states and in the SIS tunneling conductance and provide experimental evidence of d-wave symmetry for the superconductor order parameter in the cuprates. I discuss model and also evidence of quasiparticle decay in ARPES data on Bi 2 Sr 2 CaCu 2 O 8

Topological insulators/superconductors: Potential future electronic materials

International Nuclear Information System (INIS)

Hor, Y. S.

2014-01-01

A new material called topological insulator has been discovered and becomes one of the fastest growing field in condensed matter physics. Topological insulator is a new quantum phase of matter which has Dirac-like conductivity on its surface, but bulk insulator through its interior. It is considered a challenging problem for the surface transport measurements because of dominant internal conductance due to imperfections of the existing crystals of topological insulators. By a proper method, the internal bulk conduction can be suppressed in a topological insulator, and permit the detection of the surface currents which is necessary for future fault-tolerant quantum computing applications. Doped topological insulators have depicted a large variety of bulk physical properties ranging from magnetic to superconducting behaviors. By chemical doping, a TI can change into a bulk superconductor. Nb x Bi 2 Se 3 is shown to be a superconductor with T c ∼ 3.2 K, which could be a potential candidate for a topological superconductor

Yu-Shiba-Rusinov states in phase-biased superconductor-quantum dot-superconductor junctions

DEFF Research Database (Denmark)

Kirsanskas, Gediminas; Goldstein, Moshe; Flensberg, Karsten

2015-01-01

supercurrent, and the differential conductance as measured by a normal-metal tunnel probe. In absence of a phase difference only one linear combination of the superconductor lead electrons couples to the spin, which gives a single YSR state. With finite phase difference, however, it is effectively a two...

Electrochemical investigations of high-Tc superconductors - low-temperature electrochemistry

International Nuclear Information System (INIS)

Lorenz, W.J.

1992-01-01

This research report presents a summary of results obtained by electrochemical investigations of high-Tc superconductors at room temperature and below the critical temperature (Tc). The studies were to reveal the behaviour of the ceramic superconducting materials at the interface between superconductor and ionic conductor. (MM) With 4 tabs., 8 figs [de

Analisa Teknis Pemakaian Kombinasi Lampu Metal Halide Dan Led Sebagai Pemikat Ikan Pada Kapal Pukat Cincin (Purse Seine Dan Pengaruhnya Terhadap Konsumsi Bahan Bakar Genset

Directory of Open Access Journals (Sweden)

Septian Ragil Wibisono

2017-01-01

Full Text Available Saat ini lampu Metal Halide dipakai sebagai pemikat ikan  oleh nelayan Purse Seine. Peggunaan lampu tersebut memerlukan daya Genset yang besar karena satu lampu Metal Halide berdaya 1500 Watt. Semakin banyak lampu Metal Halide yang digunakan semakin besar pula konsumsi bahan bakar Genset. Dalam upaya penghematan energi bahan bakar maka digunakan lampu LED sebagai alternatif pemikat ikan. Lampu LED dikenal sebagai lampu yang hemat energi. Penelitian ini ditujukan untuk mengetahui dan membandingkan konsumsi bahan bakar Genset saat menggunakan kombinasi lampu Metal Halide dan LED. Penelitian ini dilakukan dengan mengambil data konsumsi bahan bakar Genset untuk menyalakan sejumlah lampu Metal Halide dan lampu LED, kemudian dilakukan analisa regresi untuk mendapatkan model persaamaan konsumsi bahan bakar Genset. Selanjutnya dilakukan ekstrapolasi untuk memprediksi konsumsi bahan bakar saat Genset dengan jumlah lampu tertentu. Hasilnya dengan besar fluks cahaya yang hampir sama, saat penggunaan 6 lampu Metal Halide konsumsi bahan bakar sebesar 13.606,03 liter, dan saat menggunakan kombinasi lampu 1 Metal Halide dan 25 lampu LED konsumsi bahan bakar sebesar 13.255,63 liter, yang artinya terjadi penghematan bahan bakar sebesar 2,58%.

Kinetic equations in dirty superconductors

International Nuclear Information System (INIS)

Kraehenbuehl, Y.

1981-01-01

Kinetic equations for superconductors in the dirty limit are derived using a method developed for superfluid systems, which allows a systematic expansion in small parameters; exact charge conservation is obeyed. (orig.)

Finding New Perovskite Halides via Machine learning

Directory of Open Access Journals (Sweden)

Ghanshyam ePilania

2016-04-01

Full Text Available Advanced materials with improved properties have the potential to fuel future technological advancements. However, identification and discovery of these optimal materials for a specific application is a non-trivial task, because of the vastness of the chemical search space with enormous compositional and configurational degrees of freedom. Materials informatics provides an efficient approach towards rational design of new materials, via learning from known data to make decisions on new and previously unexplored compounds in an accelerated manner. Here, we demonstrate the power and utility of such statistical learning (or machine learning via building a support vector machine (SVM based classifier that uses elemental features (or descriptors to predict the formability of a given ABX3 halide composition (where A and B represent monovalent and divalent cations, respectively, and X is F, Cl, Br or I anion in the perovskite crystal structure. The classification model is built by learning from a dataset of 181 experimentally known ABX3 compounds. After exploring a wide range of features, we identify ionic radii, tolerance factor and octahedral factor to be the most important factors for the classification, suggesting that steric and geometric packing effects govern the stability of these halides. The trained and validated models then predict, with a high degree of confidence, several novel ABX3 compositions with perovskite crystal structure.

Finding New Perovskite Halides via Machine learning

Science.gov (United States)

Pilania, Ghanshyam; Balachandran, Prasanna V.; Kim, Chiho; Lookman, Turab

2016-04-01

Advanced materials with improved properties have the potential to fuel future technological advancements. However, identification and discovery of these optimal materials for a specific application is a non-trivial task, because of the vastness of the chemical search space with enormous compositional and configurational degrees of freedom. Materials informatics provides an efficient approach towards rational design of new materials, via learning from known data to make decisions on new and previously unexplored compounds in an accelerated manner. Here, we demonstrate the power and utility of such statistical learning (or machine learning) via building a support vector machine (SVM) based classifier that uses elemental features (or descriptors) to predict the formability of a given ABX3 halide composition (where A and B represent monovalent and divalent cations, respectively, and X is F, Cl, Br or I anion) in the perovskite crystal structure. The classification model is built by learning from a dataset of 181 experimentally known ABX3 compounds. After exploring a wide range of features, we identify ionic radii, tolerance factor and octahedral factor to be the most important factors for the classification, suggesting that steric and geometric packing effects govern the stability of these halides. The trained and validated models then predict, with a high degree of confidence, several novel ABX3 compositions with perovskite crystal structure.

Conformational isomerism in mixed-ligand complexes of 2,2'-bipyridine and triphenylphosphine with copper(I) halides

International Nuclear Information System (INIS)

Barron, P.F.; Engelhardt, L.M.; Healy, P.C.; Kildea, J.D.; White, A.H.

1988-01-01

Mixed-ligand complexes of triphenylphosphine and 2,2'-bipyridine and copper(I) halides have been synthesized. The 31 P NMR spectra of the complexes were measured and are reported along with data for complete structural characterization of the complexes. The results indicate a novel dichotomy of conformational isomers to be present in the chloride lattice. The Cu-P bond length was found to not vary with different halides. 8 refs., 4 figs., 6 tabs

THERMODYNAMICS OF MICELLE FORMATION BY 1-METHYL-4-ALKYLPYRIDINIUM HALIDES

NARCIS (Netherlands)

BIJMA, K; ENGBERTS, JBFN; HAANDRIKMAN, G; VANOS, NM; BLANDAMER, MJ; BUTT, MD; CULLIS, PM

This paper reports enthalpies of micellization for a series of 1-methyl-4-alkylpyridinium halide surfactants at 303.2 K with different lengths and degrees of branching of the 4-alkyl chain and different sizes of counterions using two microcalorimeters (LKB 2277 and Omega Microcal). The standard

Chemistry of gaseous lower-valent actinide halides. Technical progress report

International Nuclear Information System (INIS)

Hildenbrand, D.L.

1984-01-01

Objective is to provide thermochemical data for key actinide halide and oxyhalide systems. Progress is reported on bond dissociation energies of gaseous ThCl 4 , ThCl 3 , ThCl 2 , and ThCl; bond dissociation energies of ruthenium fluorides; and mass spectroscopy of UF 6

Students' Understanding of Alkyl Halide Reactions in Undergraduate Organic Chemistry

Science.gov (United States)

Cruz-Ramirez de Arellano, Daniel

2013-01-01

Organic chemistry is an essential subject for many undergraduate students completing degrees in science, engineering, and pre-professional programs. However, students often struggle with the concepts and skills required to successfully solve organic chemistry exercises. Since alkyl halides are traditionally the first functional group that is…

Quantum Monte Carlo simulations for high-Tc superconductors

International Nuclear Information System (INIS)

Muramatsu, A.; Dopf, G.; Wagner, J.; Dieterich, P.; Hanke, W.

1992-01-01

Quantum Monte Carlo simulations for a multi-band model of high-Tc superconductors are reviewed with special emphasis on the comparison of different observabels with experiments. It is shown that a give parameter set of the three-band Hubbard model leads to a consistent description of normal-state propteries as well as pairing correlation function for the copper-oxide superconductors as a function of doping and temperature. (orig.)

Magnetic irreversibility in granular superconductors: ac susceptibility study

International Nuclear Information System (INIS)

Perez, F.; Obradors, X.; Fontcuberta, J.; Vallet, M.; Gonzalez-Calbet, J.

1991-01-01

Ac susceptibility measurements of a ceramic weak-coupled superconductor in very low ac fields (2mG, 111Hz) are reported. We present evidence for the observation of the magnetic irreversibility following a ZFC-FC thermal cycling by means of ac susceptibilty measurements. It is shown that this technique also reflect local magnetic field effects in granular superconductors, as previously suggested in microwave surface resistance and I-V characteristics. (orig.)

Exotic magnetic states in Pauli-limited superconductors.

Science.gov (United States)

Kenzelmann, M

2017-03-01

Magnetism and superconductivity compete or interact in complex and intricate ways. Here we review the special case where novel magnetic phenomena appear due to superconductivity, but do not exist without it. Such states have recently been identified in unconventional superconductors. They are different from the mere coexistence of magnetic order and superconductivity in conventional superconductors, or from competing magnetic and superconducting phases in many materials. We describe the recent progress in the study of such exotic magnetic phases, and articulate the many open questions in this field.

Critical de Broglie wavelength in superconductors

Science.gov (United States)

Talantsev, E. F.

2018-03-01

There are growing numbers of experimental evidences that the self-field critical currents, Jc(sf,T), are a new instructive tool to investigate fundamental properties of superconductors ranging from atomically thin films [M. Liao et al., Nat. Phys. 6 (2018), https://doi.org/10.1038/s41567-017-0031-6; E. F. Talantsev et al., 2D Mater. 4 (2017) 025072; A. Fete et al., Appl. Phys. Lett. 109 (2016) 192601] to millimeter-scale samples [E. F. Talantsev et al., Sci. Rep. 7 (2017) 10010]. The basic empirical equation which quantitatively accurately described experimental Jc(sf,T) was proposed by Talantsev and Tallon [Nat. Commun. 6 (2015) 7820] and it was the relevant critical field (i.e. thermodynamic field, Bc, for type-I and lower critical field, Bc1, for type-II superconductors) divided by the London penetration depth, λL. In this paper, we report new findings relating to this empirical equation. It is that the critical wavelength of the de Broglie wave, λdB,c, of the superconducting charge carrier which within a numerical pre-factor is equal to the largest of two characteristic lengths of Ginzburg-Landau theory, i.e. the coherence length, ξ, for type-I superconductors or the London penetration depth, λL, for type-II superconductors. We also formulate a microscopic criterion for the onset of dissipative transport current flow: ps ṡ 2ṡλL ln(1+2ṡ(λL ξ )) ≥ 1 2 ṡ ( h 2π), where ps is the charge carrier momentum, h is Planck’s constant and the inequality sign “ <” is reserved for the dissipation-free flow.

Halide salts accelerate degradation of high explosives by zerovalent iron

International Nuclear Information System (INIS)

Kim, Jong Sung; Shea, Patrick J.; Yang, Jae E.; Kim, Jang-Eok

2007-01-01

Zerovalent iron (Fe 0 , ZVI) has drawn great interest as an inexpensive and effective material to promote the degradation of environmental contaminants. A focus of ZVI research is to increase degradation kinetics and overcome passivation for long-term remediation. Halide ions promote corrosion, which can increase and sustain ZVI reactivity. Adding chloride or bromide salts with Fe 0 (1% w/v) greatly enhanced TNT, RDX, and HMX degradation rates in aqueous solution. Adding Cl or Br salts after 24 h also restored ZVI reactivity, resulting in complete degradation within 8 h. These observations may be attributed to removal of the passivating oxide layer and pitting corrosion of the iron. While the relative increase in degradation rate by Cl - and Br - was similar, TNT degraded faster than RDX and HMX. HMX was most difficult to remove using ZVI alone but ZVI remained effective after five HMX reseeding cycles when Br - was present in solution. - The addition of halide ions promotes the degradation of high explosives by zerovalent iron

Pressure effect on iron based superconductors

International Nuclear Information System (INIS)

Arumugam, S.; Kanagaraj, M.

2011-01-01

A tuning of macroscopic thermo dynamical parameters such as temperature, pressure and volume play a crucial role in strongly correlated electron systems especially high T c superconductors, which leads to increasing conductivity as well as effective way of reducing intrinsic magnetic moments. Application of chemical and external pressure exhibits significant increases of critical temperature of recently discovered iron pnictides and chalcogenides superconductors. In this present report, we have investigated hydrostatic pressure effects on resistivity and magnetization of some 1111 type based oxypnictide superconductors such as Co doped CeFeAsO, La 0.8 Th 0.2 FeAsO, Ce 0.6 Y 0.4 FeAsO 0.8 F 0.2 and Yb doped CeFeAsO systems respectively. The initially applied pressure increases the T c and its down to lower value when beyond increasing pressure also has been observed and pressure effects on crystal structure were also discussed. From that all the obtained results reveal that controlling of magnetic instability and structure distortion at higher pressure is a dominant way to further developing of T c of these new ferropnictides compounds. (author)

[Gamma scattering in condensed matter with high intensity Moessbauer radiation

International Nuclear Information System (INIS)

1992-01-01

This report discusses: quasielastic scattering studies on glycerol; gamma-ray scattering from alkali halides; lattice dynamics in metals; Moessbauer neutron scattering, x-ray diffraction, and macroscopic studies of high T c superconductors containing tungsten; NiAl scattering studies; and atomic interference factors and nuclear Casimir effect

Some thermodynamical properties of normal (or ferromagnetic) metal / superconductor heterojunctions

International Nuclear Information System (INIS)

Cayssol, Jerome

2003-01-01

We have investigated the orbital magnetism of a ballistic hybrid normal-superconductor ring. We have obtained the flux dependent excitation spectrum for arbitrary normal and superconductor lengths. We have introduced a new method to evaluate the current harmonics. We have described the cross-over from the, 'h/eh/e-periodic persistent current to the', h/2e-periodic Josephson current. In a second study, we have calculated the effect of intrinsic ordinary reflexion on the Josephson current in a ballistic superconductor-ferromagnetic-superconductor. The spectrum is strongly modified by gap openings but the current and the 0-π transition are only slightly modified up to very high spin polarisation. In a third study, we analyse the contain of some solutions of Usadel equation. The standard perturbation theory dressed by cooperons enables us to interpret those solutions in terms of diffusive paths connecting Andreev reflexion events. (author) [fr

The design of high-Tc superconductors - Room-temperature superconductivity?

International Nuclear Information System (INIS)

Tallon, J.L.; Storey, J.G.; Mallett, B.

2012-01-01

This year is the centennial of the discovery of superconductivity and the 25th anniversary of the discovery of high-T c superconductors (HTS). Though we still do not fully understand how HTS work, the basic rules of design can be determined from studying their systematics. We know what to do to increase T c and, more importantly, what to do to increase critical current density J c . This in turn lays down a challenge for the chemist. Can the ideal design be synthesized? More importantly, what are the limits? Can one make a room-temperature superconductor? In fact fluctuations place strict constraints on this objective and provide important guidelines for the design of the ideal superconductor.

Computer modelling of high-temperature superconductors using an A-V formulation

Energy Technology Data Exchange (ETDEWEB)

Ruiz-Alonso, D; Coombs, T; Campbell, A M [Cambridge University Engineering Department, Trumpington Street, Cambridge, CB2 1PZ (United Kingdom)

2004-05-01

Numerical methods for calculating the current and field distribution in high-temperature superconductors under non-uniform time-varying fields are being investigated. The highly non-linear behaviour of superconductors makes them difficult to analyse and computationally expensive. This non-linear behaviour is often accounted for through a non-linear E-J constitutive law. This paper proposes a fast method based on the finite element method to solve 2D and axially symmetric problems that contain superconducting materials. An E-J power law together with an A-V formulation is used to calculate the induction of currents in the superconductor due to time-varying external magnetic fields or forced transport current. Experimental data of a magnet-above-superconductor system is obtained in order to validate the model. In the experimental set-up a magnet is brought towards a superconducting puck at different speed rates and is also vibrated on top of it. The force between the magnet and the superconductor is measured and is found to vary with both time and frequency of excitation.

Computer modelling of high-temperature superconductors using an A-V formulation

International Nuclear Information System (INIS)

Ruiz-Alonso, D; Coombs, T; Campbell, A M

2004-01-01

Numerical methods for calculating the current and field distribution in high-temperature superconductors under non-uniform time-varying fields are being investigated. The highly non-linear behaviour of superconductors makes them difficult to analyse and computationally expensive. This non-linear behaviour is often accounted for through a non-linear E-J constitutive law. This paper proposes a fast method based on the finite element method to solve 2D and axially symmetric problems that contain superconducting materials. An E-J power law together with an A-V formulation is used to calculate the induction of currents in the superconductor due to time-varying external magnetic fields or forced transport current. Experimental data of a magnet-above-superconductor system is obtained in order to validate the model. In the experimental set-up a magnet is brought towards a superconducting puck at different speed rates and is also vibrated on top of it. The force between the magnet and the superconductor is measured and is found to vary with both time and frequency of excitation

Vortex-antivortex patterns in mesoscopic superconductors

International Nuclear Information System (INIS)

Teniers, Gerd; Moshchalkov, V.V.; Chibotaru, L.F.; Ceulemans, Arnout

2003-01-01

We have studied the nucleation of superconductivity in mesoscopic structures of different shape (triangle, square and rectangle). This was made possible by using an analytical gauge transformation for the vector potential A which gives A n =0 for the normal component along the boundary line of the rectangle. As a consequence the superconductor-vacuum boundary condition reduces to the Neumann boundary condition. By solving the linearized Ginzburg-Landau equation with this boundary condition we have determined the field-temperature superconducting phase boundary and the corresponding vortex patterns. The comparison of these patterns for different structures demonstrates that the critical parameters of a superconductor can be manipulated and fine-tuned through nanostructuring

Unconventional superconductivity in heavy fermionic and high-Tc superconductors

International Nuclear Information System (INIS)

Volovik, G.E.

1989-01-01

Splitting of the superconducting transition and glass spectrum in heavy fermion companies and oxide superconductors are discussed. The multicomponent order parameter leads to splitting of transition due to magnetic field, impurities, orthorhombic distortion, etc... Linear specific heat in oxide superconductors may be explained in terms of the Fermi-surface arising in superconducting state if interband is pairing strong enough

Localized superconductors

International Nuclear Information System (INIS)

Ma, M.; Lee, P.A.

1985-01-01

We study the effects of Anderson localization on superconductivity by using a Bardeen-Cooper-Schrieffer (BCS)-type trial wave function which pairs electrons in exact time-reversed eigenstates of the single-particle Hamiltonian. Within this approximation, and neglecting localization effects on the effective Coulomb repulsion and the electron-phonon coupling, we find that superconductivity persists below the mobility edge. In fact, Anderson's theorem is valid in the localized phase as long as rhoΔ 0 L/sup d/ > 1 (rho is the density of states averaged over +- Δ 0 of the Fermi energy, Δ 0 the BCS gap parameter, and L the localization length). Hence the gap order parameter Δ(r) remains uniform in space at the BCS value Δ 0 . The superfluid density and response to electromagnetic perturbations, however, show marked differences from the ''dirty superconductor'' regime. For rhoΔ 0 L/sup d/ < 1, Δ(r) fluctuates spatially and eventually drops to zero. In the limit when states are site localized, the system crosses over into the ''Anderson negative-U glass.'' Considerations beyond the trial wave-function approximation will speed up the destruction of superconductivity. The superconductor formed from localized states has the property that its quasiparticle excitations are also localized. Such excitations can be probed by observing the normal current in a tunneling junction

Exciton-relaxation dynamics in lead halides

International Nuclear Information System (INIS)

Iwanaga, Masanobu; Hayashi, Tetsusuke

2003-01-01

We survey recent comprehensive studies of exciton relaxation in the crystals of lead halides. The luminescence and electron-spin-resonance studies have revealed that excitons in lead bromide spontaneously dissociate and both electrons and holes get self-trapped individually. Similar relaxation has been also clarified in lead chloride. The electron-hole separation is ascribed to repulsive correlation via acoustic phonons. Besides, on the basis of the temperature profiles of self-trapped states, we discuss the origin of luminescence components which are mainly induced under one-photon excitation into the exciton band in lead fluoride, lead chloride, and lead bromide

Plasmonic characterization of photo-induced silver nanoparticles extracted from silver halide based TEM film

Energy Technology Data Exchange (ETDEWEB)

Sudheer,, E-mail: sudheer@rrcat.gov.in; Tiwari, P.; Rai, V. N.; Srivastava, A. K. [Indus Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology Indore, Madhya Pradesh 452013 (India); Varshney, G. K. [Laser Bio-medical Applications & Instrumentation Division, Raja Ramanna Centre for Advanced Technology Indore, Madhya Pradesh 452013 (India)

2016-05-23

The plasmonic responses of silver nanoparticles extracted from silver halide based electron microscope film are investigated. Photo-reduction process is carried out to convert the silver halide grains into the metallic silver. The centrifuge technique is used for separating the silver nanoparticles from the residual solution. Morphological study performed by field emission scanning electron microscope (FESEM) shows that all the nanoparticles have an average diameter of ~120 nm with a high degree of mono dispersion in size. The localized surface plasmon resonance (LSPR) absorption peak at ~537 nm confirms the presence of large size silver nanoparticles.

Studies on advanced superconductors for fusion device. Pt. 2. Metallic superconductors other than Nb{sub 3}Sn

Energy Technology Data Exchange (ETDEWEB)

Tachikawa, K.; Yamamoto, J.; Mito, T. [eds.

1997-03-01

A comprehensive report on the present status of the development of Nb{sub 3}Sn superconductors was published as the NIFS-MEMO-20 in March, 1996 (Part 1 of this report series). The second report of this study covers various progress so far achieved in the research and development on advanced metallic superconductors other than Nb{sub 3}Sn. Among different A15 crystal-type compounds, Nb{sub 3}Al has been fabricated into cables with large current-carrying capacity for fusion device referring its smaller sensitivity to mechanical strain than Nb{sub 3}Sn. Other high-field A15 superconductors, e.g. V{sub 3}Ga, Nb{sub 3}Ge and Nb{sub 3}(Al,Ge), have been also fabricated through different novel processes as promising alternatives to Nb{sub 3}Sn conductors. Meanwhile, B1 crystal-type NbN and C15 crystal-type V{sub 2}(Hf,Zr) high-field superconductors are characterized by their excellent tolerance to mechanical strain and neutron irradiation. Chevrel-type PbMo{sub 6}S{sub 8} compound has gained much interests due to its extremely high upper critical field. In addition, this report includes the recent progress in ultra-fine filamentary NbTi wires for AC use, and that in NbTi/Cu magnetic shields necessary in the application of high magnetic field. The data on the decay of radioactivity in a variety of metals relating to fusion superconducting magnet are also attached as appendices. We hope that this report might contribute substantially as a useful reference for the planning of fusion apparatus of next generation as well as that of other future superconducting devices. (author)

Boundary conditions in Ginsburg Landau theory and critical temperature of high-T superconductors

Science.gov (United States)

Lykov, A. N.

2008-06-01

New mixed boundary conditions to the Ginsburg-Landau equations are found to limit the critical temperature ( T) of high- T superconductors. Moreover, the value of the pseudogap in these superconductors can be explained by using the method. As a result, the macroscopic approach is proposed to increase T of cuprate superconductors.

Meissner effect in diffusive normal metal/d-wave superconductor junctions

NARCIS (Netherlands)

Yokoyama, Takehito; Tanaka, Yukio; Golubov, Alexandre Avraamovitch; Inoue, Jun-ichiro; Asano, Yasuhiro

2005-01-01

The Meissner effect in diffusive normal metal/insulator/d-wave superconductor junctions is studied theoretically in the framework of the Usadel equation under the generalized boundary condition. The effect of midgap Andreev resonant states (MARS) formed at the interface of d-wave superconductor is

Magnetic flux distributions in chiral helimagnet/superconductor bilayers

Energy Technology Data Exchange (ETDEWEB)

Kato, Masaru, E-mail: kato@ms.osakafu-u.ac.jp [Department of Mathematical Sciences, Osaka Prefecture University, 1-1, Gakuencho, Nakaku, Sakai, Osaka 599-8531 (Japan); Fukui, Saoto [Department of Mathematical Sciences, Osaka Prefecture University, 1-1, Gakuencho, Nakaku, Sakai, Osaka 599-8531 (Japan); Sato, Osamu [Osaka Prefecture University College of Technology, 26-12, Saiwaicho, Neyagawa, Osaka 572-8572 (Japan); Togawa, Yoshihiko [Department of Physics and Electronics, Osaka Prefecture University, 1-1, Gakuencho, Nakaku, Sakai, Osaka 599-8531 (Japan)

2017-02-15

Highlights: • Vortex states in a chiral helimagnet/superconductor bilayer are investigated. • Vortex and anti-vortex appears depending on strength of helimagnet. • Vortex is elongated under a gradient field. • Vortices form a undulated triangular lattice. - Abstarct: Vortex states in a chiral helimagnet/superconductor bilayer are investigated numerically, using the Ginzburg–Landau equations with the finite element method. In this bilayer, effect of the chiral helimagnet on the superconductor is taken as an external field. Magnetic field distribution can be controlled by an applied field to the bilayer. It is shown that a single vortex in a gradient field is elongated along the field gradient. In zero applied field, there are up- and down vortices which are parallel or antiparallel to the z-axis, respectively. But increasing the applied field, down-vortices disappear and up-vortices form undulated triangular lattices.

High-temperature cuprate superconductors. Experiment, theory, and applications

International Nuclear Information System (INIS)

Plakida, Nikolay

2010-01-01

High-Temperature Cuprate Superconductors provides an up-to-date and comprehensive review of the properties of these fascinating materials. The essential properties of high-temperature cuprate superconductors are reviewed on the background of their theoretical interpretation. The experimental results for structural, magnetic, thermal, electric, optical and lattice properties of various cuprate superconductors are presented with respect to relevant theoretical models. A critical comparison of various theoretical models involving strong electron correlations, antiferromagnetic spin fluctuations, phonons and excitons provides a background for understanding of the mechanism of high-temperature superconductivity. Recent achievements in their applications are also reviewed. A large number of illustrations and tables gives valuable information for specialists. A text-book level presentation with formulation of a general theory of strong-coupling superconductivity will help students and researches to consolidate their knowledge of this remarkable class of materials. (orig.)

Workshop on Accelerator Magnet Superconductors, Design and Optimization

CERN Document Server

WAMSDO Workshop

2009-01-01

This report contains the proceedings of the CARE-HHH-AMT Workshop on Accelerator Magnet Superconductors, Design and Optimization (WAMSDO) held at CERN from 19 to 23 May 2008. The needs in terms of superconducting magnets for the accelerator projects were discussed, mainly for the LHC interaction regions and injector upgrades, and for the GSI FAIR complex. The first part of the workshop focused on the development of superconductor and cables, i.e., low-loss Nb-Ti cables, Nb$_{3}$Sn and high-temperature superconductors. An industry session summarized the actual plans and status of the activities in the main European industries. Then, a worldwide status of the high field magnets programme was presented. A special session was devoted to fast cycled magnets, including FAIR facilities and LHC injector upgrades. A final session focused on the optimization methods and numerical tools for magnet design.

THz detectors using surface Josephson plasma waves in layered superconductors

International Nuclear Information System (INIS)

Savel'ev, Sergey; Yampol'skii, Valery; Nori, Franco

2006-01-01

We describe a proposal for THz detectors based on the excitation of surface waves, in layered superconductors, at frequencies lower than the Josephson plasma frequency ω J . These waves propagate along the vacuum-superconductor interface and are attenuated in both transverse directions out of the surface (i.e., towards the superconductor and towards the vacuum). The surface Josephson plasma waves are also important for the complete suppression of the specular reflection from a sample (Wood's anomalies, used for gratings) and produce a huge enhancement of the wave absorption, which can be used for the detection of THz waves

White-Light Emission from Layered Halide Perovskites.

Science.gov (United States)

Smith, Matthew D; Karunadasa, Hemamala I

2018-03-20

With nearly 20% of global electricity consumed by lighting, more efficient illumination sources can enable massive energy savings. However, effectively creating the high-quality white light required for indoor illumination remains a challenge. To accurately represent color, the illumination source must provide photons with all the energies visible to our eye. Such a broad emission is difficult to achieve from a single material. In commercial white-light sources, one or more light-emitting diodes, coated by one or more phosphors, yield a combined emission that appears white. However, combining emitters leads to changes in the emission color over time due to the unequal degradation rates of the emitters and efficiency losses due to overlapping absorption and emission energies of the different components. A single material that emits broadband white light (a continuous emission spanning 400-700 nm) would obviate these problems. In 2014, we described broadband white-light emission upon near-UV excitation from three new layered perovskites. To date, nine white-light-emitting perovskites have been reported by us and others, making this a burgeoning field of study. This Account outlines our work on understanding how a bulk material, with no obvious emissive sites, can emit every color of the visible spectrum. Although the initial discoveries were fortuitous, our understanding of the emission mechanism and identification of structural parameters that correlate with the broad emission have now positioned us to design white-light emitters. Layered hybrid halide perovskites feature anionic layers of corner-sharing metal-halide octahedra partitioned by organic cations. The narrow, room-temperature photoluminescence of lead-halide perovskites has been studied for several decades, and attributed to the radiative recombination of free excitons (excited electron-hole pairs). We proposed that the broad white emission we observed primarily stems from exciton self-trapping. Here, the

Flux Pinning in Superconductors

CERN Document Server

Matsushita, Teruo

2007-01-01

The book covers the flux pinning mechanisms and properties and the electromagnetic phenomena caused by the flux pinning common for metallic, high-Tc and MgB2 superconductors. The condensation energy interaction known for normal precipitates or grain boundaries and the kinetic energy interaction proposed for artificial Nb pins in Nb-Ti, etc., are introduced for the pinning mechanism. Summation theories to derive the critical current density are discussed in detail. Irreversible magnetization and AC loss caused by the flux pinning are also discussed. The loss originally stems from the ohmic dissipation of normal electrons in the normal core driven by the electric field induced by the flux motion. The readers will learn why the resultant loss is of hysteresis type in spite of such mechanism. The influence of the flux pinning on the vortex phase diagram in high Tc superconductors is discussed, and the dependencies of the irreversibility field are also described on other quantities such as anisotropy of supercondu...

Proximity effects and Josephson currents in ferromagnet. Spin-triplet superconductors junctions

International Nuclear Information System (INIS)

Terrade, Damien

2015-01-01

Spin-triplet superconductivity, first attached to the description of 3 He, is now generally considered to also occur in heavy-fermions compounds and in perovskite ruthenium oxide Sr 2 RuO 4 . The latter material is especially interesting since many experiments show strong evidences for a unitary chiral spin-triplet state. Moreover, the recent fabrication of thin heterostructures made of ferromagnetic SrRuO 3 on the top of Sr 2 RuO 4 strongly encourages new theoretical studies on the interplay between spin-triplet superconductor and ferromagnet in similar fashion to spin-singlet superconductors. Using an extended tight-binding Hamiltonian to model the superconductor, we discuss in this thesis the specific proximity effects of such interface by solving self-consistently the Bogoliubov-De Gennes equations on two- and three-dimensional lattices in the ballistic limit. We obtain the spatial profile of the superconducting order parameters at the interface as well as the spin-polarisation and the current across the Josephson junctions. In contrast to heterostructures made of spin-singlet superconductor, we show that the physical properties at the interface are not only controlled by the strength of the magnetization inside the ferromagnet but also by its orientation due to the existence of a finite pair spin projection of the spin-triplet Cooper pairs. We analyse in the first part the spin-polarisation and the Gibbs free energy at the three-dimensional ferromagnet-chiral spin-triplet superconductor interface. Then, the second part of the thesis is dedicated to the study of the Josephson junctions made of a chiral spin-triplet superconductor and a ferromagnetic barrier. More precisely, we analyse the existence of 0-π state transitions in two- and three-dimensional junctions with respect to the strength and the orientation of the magnetization. Finally, we study the proximity effects at the interface of helical spin-triplet superconductors. They differ from the chiral

A simple model to estimate the optimal doping of p - Type oxide superconductors

Directory of Open Access Journals (Sweden)

Adir Moysés Luiz

2008-12-01

Full Text Available Oxygen doping of superconductors is discussed. Doping high-Tc superconductors with oxygen seems to be more efficient than other doping procedures. Using the assumption of double valence fluctuations, we present a simple model to estimate the optimal doping of p-type oxide superconductors. The experimental values of oxygen content for optimal doping of the most important p-type oxide superconductors can be accounted for adequately using this simple model. We expect that our simple model will encourage further experimental and theoretical researches in superconducting materials.

Electrochemical treatment of an oxide material, application to superconductors, and obtained superconductors

International Nuclear Information System (INIS)

Grenier, J.C.; Pouchard, M.; Wattiaux, A.

1991-01-01

The present invention describes the electrochemical treatment of a superconductor oxide so as to modify its stoichiometry. These materials comprise in their anionic lattice oxygenated and hydrogenated species. These treated materials are prepared by an electrochemical process in which the oxide is an electrode in a liquid electrolysis. 3 refs., 3 figs

London limit for lattice model of superconductor

International Nuclear Information System (INIS)

Ktitorov, S.A.

2004-01-01

The phenomenological approach to the strong-bond superconductor, which is based on the Ginzburg-Landau equation in the London limit, is considered. The effect of the crystalline lattice discreteness on the superconductors electromagnetic properties is studied. The classic problems on the critical current and magnetic field penetration are studied within the frames of the lattice model for thin superconducting films. The dependence of the superconducting current on the thin film order parameter is obtained. The critical current dependence on the degree of deviation from the continual approximation is calculated [ru

The critical current of superconductors: an historical review

International Nuclear Information System (INIS)

Dew-Hughes, D.

2001-01-01

The most important practical characteristic of a superconductor is its critical current density. This article traces the history, both of the experimental discoveries and of the development of the theoretical ideas that have lead to the understanding of those factors that control critical current densities. These include Silsbee's hypothesis, the Meissner effect, London, Ginsburg-Landau and Abrikosov theories, flux pinning and the critical state, and the control of texture in high temperature superconductors

Characteristic features of the exotic superconductors: A summary

International Nuclear Information System (INIS)

Brandow, B.

1997-09-01

The authors summarize the results of a comprehensive examination of the characteristic features of the exotic superconductors, the superconductors so-labelled by Uemura and co-workers. In both the electronic and the crystal-chemistry properties, they find anomalous features which appear to be universal for these materials, as well as other features which are clearly not universal but common enough to be considered typical for these materials. Some implications of these anomalies are discussed

Superconductor fluxoid logic

International Nuclear Information System (INIS)

Andronov, A.A.; Kurin, V.V.; Levichev, M.Yu.; Ryndyk, D.A.; Vostokov, V.I.

1993-01-01

In recent years there has been much interest in superconductor logical devices. Our paper is devoted to the analysis of some new possibilities in this field. The main problems here are: minimization of time of logical operations and reducing of device scale. Josephson systems are quite appropriate for this purpose because of small size, short characteristic time and also small energy losses. Two different types of Josephson logic have been investigated during last years. The first type is based on hysteretic V-A characteristic of a single Josephson junction. Superconducting and resistive (with nonzero voltage) states are considered as logical zero and logical unit. The second one - rapid single flux quantum logic, has been developed recently and is based on SQUID-like bistability. Different logical states are the states with different number of magnetic flux quanta inside closed superconducting contour. Information is represented by voltage pulses with fixed ''area'' (∫ V(t)/dt). This pulses are generated when logical state of SQUID-like elementary cell changes. The fundamental role of magnetic flux quantization in this type of logic leads to the necessity of large enough self-inductance of superconductor contour and thus to limitations on minimal device dimensions. (orig.)

Low-Temperature Synthesis Routes to Intermetallic Superconductors

Energy Technology Data Exchange (ETDEWEB)

Schaak, Raymond E

2008-01-08

Over the past few years, our group has gained expertise at developing low-temperature solution-based synthetic pathways to complex nanoscale solids, with particular emphasis on nanocrystalline intermetallic compounds. Our synthetic capabilities are providing tools to reproducibly generate intermetallic nanostructures with simultaneous control over crystal structure, composition, and morphology. This DOE-funded project aims to expand these capabilities to intermetallic superconductors. This could represent an important addition to the tools that are available for the synthesis and processing of intermetallic superconductors, which traditionally utilize high-temperature, high-pressure, thin film, or gas-phase vacuum deposition methods. Our current knowledge of intermetallic superconductors suggests that significant enhancements could result from the inherent benefits of low-temperature solution synthesis, e.g. metastable phase formation, control over nanoscale morphology to facilitate size-dependent property studies, robust and inexpensive processability, low-temperature annealing and consolidation, and impurity incorporation (for doping, stoichiometry control, flux pinning, and improving the critical fields). Our focus is on understanding the superconducting properties as a function of synthetic route, crystal structure, crystallite size, and morphology, and developing the synthetic tools necessary to accomplish this. This research program can currently be divided into two classes of superconducting materials: intermetallics (transition metal/post transition metal) and metal carbides/borides. Both involve the development and exploitation of low-temperature synthesis routes followed by detailed characterization of structures and properties, with the goal of understanding how the synthetic pathways influence key superconducting properties of selected target materials. Because of the low-temperature methods used to synthesize them and the nanocrystalline morphologies

Proposal of Magnetic Circuit using Magnetic Shielding with Bulk-Type High Tc Superconductors

Science.gov (United States)

Fukuoka, Katsuhiro; Hashimoto, Mitsuo; Tomita, Masaru; Murakami, Masato

Recently, bulk-type high Tc superconductors having a characteristic of critical current density over 104 A/cm2 in liquid nitrogen temperature (77K) on 1T, can be produced. They are promising for many practical applications such as a magnetic bearing, a magnetic levitation, a flywheel, a magnetic shielding and others. In this research, we propose a magnetic circuit that is able to use for the magnetic shield of plural superconductors as an application of bulk-type high Tc superconductors. It is a closed magnetic circuit by means of a toroidal core. Characteristics of the magnetic circuit surrounded with superconductors are evaluated and the possibility is examined. As the magnetic circuit of the ferrite core is surrounded with superconductors, the magnetic flux is shielded even if it leaked from the ferrite core.

Numerical analysis of thermally actuated magnets for magnetization of superconductors

Energy Technology Data Exchange (ETDEWEB)

Li Quan; Yan Yu; Rawlings, Colin; Coombs, Tim, E-mail: ql229@cam.ac.u [EPEC Superconductivity Group, Engineering Department, University of Cambridge, Trumpington Street. Cambridge, CB2 1PZ (United Kingdom)

2010-06-01

Superconductors, such as YBCO bulks, have extremely high potential magnetic flux densities, comparing to rare earth magnets. Therefore, the magnetization of superconductors has attracted broad attention and contribution from both academic research and industry. In this paper, a novel technique is proposed to magnetize superconductors. Unusually, instead of using high magnetic fields and pulses, repeatedly magnetic waves with strength of as low as rare earth magnets are applied. These magnetic waves, generated by thermally controlling a Gadolinium (Gd) bulk with a rare earth magnet underneath, travel over the flat surface of a YBCO bulk and get trapped little by little. Thus, a very small magnetic field can be used to build up a very large magnetic field. In this paper, the modelling results of thermally actuated magnetic waves are presented showing how to transfer sequentially applied thermal pulses into magnetic waves. The experiment results of the magnetization of YBCO bulk are also presented to demonstrate how superconductors are progressively magnetized by small magnetic field

Antiferromagnetism and its origin in iron-based superconductors (Review Article)

International Nuclear Information System (INIS)

Ding, Ming-Cui; Zhang, Yu-Zhong; Lin, Hai-Qing

2014-01-01

In iron-based superconductors, unravelling the origin of the antiferromagnetism is a crucial step towards understanding the high-T c superconductivity as it is widely believed that the magnetic fluctuations play important roles in the formation of the Cooper pairs. Therefore, in this paper, we will briefly review experimental results related to the antiferromagnetic state in iron-based superconductors and focus on a review of the theoretical investigations which show applicability of the itinerant scenario to the observed antiferromagnetism and corresponding phase transitions in various families of the iron-based superconductors. A proposal of coupling between frustrated and un frustrated bands for understanding the reduced magnetic moment typically observed in iron pnictides is also reviewed. While all the above theoretical investigations do not rule out a possible existence of localized electrons in iron-based superconductors, these results strongly indicate a close relation between itinerant electrons and the magnetically ordered state and point out the importance of taking into account the orbital degrees of freedom.

Numerical analysis of thermally actuated magnets for magnetization of superconductors

International Nuclear Information System (INIS)

Li Quan; Yan Yu; Rawlings, Colin; Coombs, Tim

2010-01-01

Superconductors, such as YBCO bulks, have extremely high potential magnetic flux densities, comparing to rare earth magnets. Therefore, the magnetization of superconductors has attracted broad attention and contribution from both academic research and industry. In this paper, a novel technique is proposed to magnetize superconductors. Unusually, instead of using high magnetic fields and pulses, repeatedly magnetic waves with strength of as low as rare earth magnets are applied. These magnetic waves, generated by thermally controlling a Gadolinium (Gd) bulk with a rare earth magnet underneath, travel over the flat surface of a YBCO bulk and get trapped little by little. Thus, a very small magnetic field can be used to build up a very large magnetic field. In this paper, the modelling results of thermally actuated magnetic waves are presented showing how to transfer sequentially applied thermal pulses into magnetic waves. The experiment results of the magnetization of YBCO bulk are also presented to demonstrate how superconductors are progressively magnetized by small magnetic field

Synergistic effect of halide ions on the corrosion inhibition of aluminium in H{sub 2}SO{sub 4} using 2-acetylphenothiazine

Energy Technology Data Exchange (ETDEWEB)

Ebenso, E.E

2003-03-05

The corrosion inhibition of aluminium in H{sub 2}SO{sub 4} in the presence of 2-acetylphenothiazine (2APTZ) at temperature range of 30-60 deg. C was studied using the weight loss and thermometric techniques. The effect of addition of halides (KCl, KBr, KI) is also reported. The inhibition efficiency (I, %) increased with increase in concentration of 2APTZ. The addition of the halides increased the inhibition efficiency to a considerable extent. The temperature increased the corrosion rate and inhibition efficiency in the range 30-60 deg. C in the absence and presence of the inhibitor and halides. Phenomenon of chemical adsorption is proposed. Flory-Huggins adsorption isotherm equation was obeyed at all the concentrations studied. The decrease in inhibition efficiency (and surface coverage values) was found to be in the order I{sup -}>Br{sup -}>Cl{sup -} which clearly indicates that the radii and the electronegativity of halides play a significant role in the adsorption process. All the data acquired reveal that 2APTZ acts as an inhibitor in the acid environment from the two techniques used. The synergistic effect of 2APTZ and halide ions is discussed.

The Role of Surface Tension in the Crystallization of Metal Halide Perovskites

KAUST Repository

Zhumekenov, Ayan A.; Burlakov, Victor M.; Saidaminov, Makhsud I.; Alofi, Abdulilah; Haque, Mohammed; Turedi, Bekir; Davaasuren, Bambar; Dursun, Ibrahim; Cho, Nam Chul; El-Zohry, Ahmed M.; de Bastiani, Michele; Giugni, Andrea; Torre, Bruno; Di Fabrizio, Enzo M.; Mohammed, Omar F.; Rothenberger, Alexander; Wu, Tao; Goriely, Alain; Bakr, Osman

2017-01-01

The exciting intrinsic properties discovered in single crystals of metal halide perovskites still await their translation into optoelectronic devices. The poor understanding and control of the crystallization process of these materials are current

Josephson junction between two high Tc superconductors with arbitrary transparency of interface

Directory of Open Access Journals (Sweden)

GhR Rashedi

2010-03-01

Full Text Available In this paper, a dc Josephson junction between two singlet superconductors (d-wave and s-wave with arbitrary reflection coefficient has been investigated theoretically. For the case of high Tc superconductors, the c-axes are parallel to an interface with finite transparency and their ab-planes have a mis-orientation. The physics of potential barrier will be demonstrated by a transparency coefficient via which the tunneling will occur. We have solved the nonlocal Eilenberger equations and obtained the corresponding and suitable Green functions analytically. Then, using the obtained Green functions, the current-phase diagrams have been calculated. The effect of the potential barrier and mis-orientation on the currents is studied analytically and numerically. It is observed that, the current phase relations are totally different from the case of ideal transparent Josephson junctions between d-wave superconductors and two s-wave superconductors. This apparatus can be used to demonstrate d-wave order parameter in high Tc superconductors.

Static Test for a Gravitational Force Coupled to Type 2 YBCO Superconductors

Science.gov (United States)

Li, Ning; Noever, David; Robertson, Tony; Koczor, Ron; Brantley, Whitt

1997-01-01

As a Bose condensate, superconductors provide novel conditions for revisiting previously proposed couplings between electromagnetism and gravity. Strong variations in Cooper pair density, large conductivity and low magnetic permeability define superconductive and degenerate condensates without the traditional density limits imposed by the Fermi energy (approx. 10(exp -6) g cc. Recent experiments have reported anomalous weight loss for a test mass suspended above a rotating type II, YBCO superconductor, with the percentage change (0.05 - 2.1 %) independent of the test mass' chemical composition and diamagnetic properties. A variation of 5 parts per 10' was reported above a stationary (non-rotating) superconductor. In experiments using a sensitive gravimeter, bulk YBCO superconductors were stably levitated in a DC magnetic field. Changes in acceleration were measured to be less than 2 parts in 108 of the normal gravitational acceleration. This result puts new limits on the strength and range of the proposed coupling between static superconductors and gravity.

Thermal mechanisms responsible for the irreversible degradation of superconductivity in commercial superconductors

Science.gov (United States)

Romanovskii, V. R.

2017-08-01

Conditions for the irreversible propagation of thermal instabilities in commercial superconductors subjected to intense and soft cooling have been formulated. An analysis has been conducted using two types of the superconductor's I-V characteristics, i.e., an ideal I-V characteristic, which assumes a step superconducting-to-normal transition, and a continuous I-V characteristic, which is described by a power law. The propagation rate of thermal instabilities along the superconducting composite has been determined. Calculations have been made for both subcritical and supercritical values of the current. It has been shown that they propagate along a commercial superconductor in the form of a switching wave. In rapidly cooled commercial superconductors, the steady-state rate of thermal instability propagation in the longitudinal direction can only be positive because there is no region of steady stabilization. It has been proved that, in the case of thermal instability irreversible propagation, the rise in the commercial superconductor temperature is similar to diffusion processes that occur in explosive chain reactions.

Boundary conditions in Ginsburg-Landau theory and critical temperature of high-Tc superconductors

International Nuclear Information System (INIS)

Lykov, A.N.

2008-01-01

New mixed boundary conditions to the Ginsburg-Landau equations are found to limit the critical temperature (T c ) of high-T c superconductors. Moreover, the value of the pseudogap in these superconductors can be explained by using the method. As a result, the macroscopic approach is proposed to increase T c of cuprate superconductors

Postsynthetic Doping of MnCl2 Molecules into Preformed CsPbBr3 Perovskite Nanocrystals via a Halide Exchange-Driven Cation Exchange.

Science.gov (United States)

Huang, Guangguang; Wang, Chunlei; Xu, Shuhong; Zong, Shenfei; Lu, Ju; Wang, Zhuyuan; Lu, Changgui; Cui, Yiping

2017-08-01

Unlike widely used postsynthetic halide exchange for CsPbX 3 (X is halide) perovskite nanocrystals (NCs), cation exchange of Pb is of a great challenge due to the rigid nature of the Pb cationic sublattice. Actually, cation exchange has more potential for rendering NCs with peculiar properties. Herein, a novel halide exchange-driven cation exchange (HEDCE) strategy is developed to prepare dually emitting Mn-doped CsPb(Cl/Br) 3 NCs via postsynthetic replacement of partial Pb in preformed perovskite NCs. The basic idea for HEDCE is that the partial cation exchange of Pb by Mn has a large probability to occur as a concomitant result for opening the rigid halide octahedron structure around Pb during halide exchange. Compared to traditional ionic exchange, HEDCE is featured by proceeding of halide exchange and cation exchange at the same time and lattice site. The time and space requirements make only MnCl 2 molecules (rather than mixture of Mn and Cl ions) capable of doping into perovskite NCs. This special molecular doping nature results in a series of unusual phenomenon, including long reaction time, core-shell structured mid states with triple emission bands, and dopant molecules composition-dependent doping process. As-prepared dual-emitting Mn-doped CsPb(Cl/Br) 3 NCs are available for ratiometric temperature sensing. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Monocrystallomimicry in the aerosols of ammonium and cesium halides

International Nuclear Information System (INIS)

Melikhov, I.V.; Kitova, E.N.; Kozlovskaya, EhD.; Kamenskaya, A.N.; Mikheev, N.B.; Kulyukhin, S.A.

1997-01-01

It is experimentally shown that initial CsI and NH 4 Hal nanocrystals combining into mixed aggregates of polyhedral form (pseudo monocrystals) are formed in the process of cocrystallization of ammonium halide and cesium iodide. The origination and growth of the pseudo monocrystals on the account of successive addition of initial crystals is described by the Fokker-Plank equation [ru

High temperature superconductors applications in telecommunications

Energy Technology Data Exchange (ETDEWEB)

Kumar, A.A.; Li, J.; Zhang, M.F. [Prairie View A& M Univ., Texas (United States)

1994-12-31

The purpose of this paper is twofold: to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices-obvious advantages versus practical difficulties-needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models-a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B)-shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance-conductivity, surface resistance and attenuation constant-will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T{sub c} superconductors.

High temperature superconductors applications in telecommunications

International Nuclear Information System (INIS)

Kumar, A.A.; Li, J.; Zhang, M.F.

1994-01-01

The purpose of this paper is twofold: to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices-obvious advantages versus practical difficulties-needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models-a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B)-shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance-conductivity, surface resistance and attenuation constant-will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T c superconductors

Distribution of local magnetic field of vortex lattice near anisotropic superconductor surface in inclined external fields

International Nuclear Information System (INIS)

Efremova, S.A.; Tsarevskij, S.L.

1997-01-01

Magnetic field distribution in a unit cell of the Abrikosov vortex lattice near the surface of monoaxial anisotropic type-ii superconductors in inclined external magnetic field has been found in the framework of London model for the cases when the symmetry axis is perpendicular and parallel to the superconductor surface interface. Distribution of local magnetic field as a function of the distance from the superconductor interface surface and external field inclination angle has been obtained. Using high-Tc superconductor Y-Ba-Cu-O by way of examples, it has been shown that the study of local magnetic field distribution function, depending on external magnetic field inclination angle towards the superconductor symmetry axis and towards the superconductor surface, can provide important data on anisotropic properties of the superconductor [ru

Line emissions from sonoluminescence in aqueous solutions of halide salts without noble gases

Energy Technology Data Exchange (ETDEWEB)

Liang, Jinfu, E-mail: liang.shi2007@163.com [The Key Laboratory of Modern Acoustics, Ministry of Education, Institution of Acoustics, Nanjing University, Nanjing 210093 (China); School of Physics and Electronic Science, Guizhou Normal University, Guiyang 550001 (China); Chen, Weizhong, E-mail: wzchen@nju.edu.cn [The Key Laboratory of Modern Acoustics, Ministry of Education, Institution of Acoustics, Nanjing University, Nanjing 210093 (China); Zhou, Chao; Cui, Weicheng; Chen, Zhan [The Key Laboratory of Modern Acoustics, Ministry of Education, Institution of Acoustics, Nanjing University, Nanjing 210093 (China)

2015-02-20

Line emissions of trivalent terbium (Tb{sup 3+}) ion were observed from single-bubble sonoluminescence (SL) in an aqueous solution of terbium chloride (TbCl{sub 3}) that contained no noble gas. In addition, sodium (Na) lines were observed in multi-bubble SL in aqueous solutions of various halide salts that contained no noble gas. These observations show that the halide ions, such as Cl{sup −}, Br{sup −}, and I{sup −}, help for line emissions as the noble gases. The intensity of a line emission depends on both the chemical species produced by cavitation bubbles and the temperature of SL bubble that responds to the driving ultrasound pressure. With the increase of driving pressure, some line emissions attached to the continuous spectrum may become increasingly clear, while other line emissions gradually become indistinct. - Highlights: • Line emissions of Tb(III) ions were observed without the presence of noble gases. • The halide ions help to generate a line emission during sonoluminescence. • The intensity of a line emission mainly depends on the bubble's temperature. • The definition of a line emission is related to the temperature of caviation bubble and the kind of host liquid.

Unveiling the Shape Evolution and Halide-Ion-Segregation in Blue-Emitting Formamidinium Lead Halide Perovskite Nanocrystals Using an Automated Microfluidic Platform.

Science.gov (United States)

Lignos, Ioannis; Protesescu, Loredana; Emiroglu, Dilara Börte; Maceiczyk, Richard; Schneider, Simon; Kovalenko, Maksym V; deMello, Andrew J

2018-02-14

Hybrid organic-inorganic perovskites and in particular formamidinium lead halide (FAPbX 3 , X = Cl, Br, I) perovskite nanocrystals (NCs) have shown great promise for their implementation in optoelectronic devices. Specifically, the Br and I counterparts have shown unprecedented photoluminescence properties, including precise wavelength tuning (530-790 nm), narrow emission linewidths (photoluminescence quantum yields (70-90%). However, the controlled formation of blue emitting FAPb(Cl 1-x Br x ) 3 NCs lags behind their green and red counterparts and the mechanism of their formation remains unclear. Herein, we report the formation of FAPb(Cl 1-x Br x ) 3 NCs with stable emission between 440 and 520 nm in a fully automated droplet-based microfluidic reactor and subsequent reaction upscaling in conventional laboratory glassware. The thorough parametric screening allows for the elucidation of parametric zones (FA-to-Pb and Br-to-Cl molar ratios, temperature, and excess oleic acid) for the formation of nanoplatelets and/or NCs. In contrast to CsPb(Cl 1-x Br x ) 3 NCs, based on online parametric screening and offline structural characterization, we demonstrate that the controlled synthesis of Cl-rich perovskites (above 60 at% Cl) with stable emission remains a challenge due to fast segregation of halide ions.

Charge-charge liquid structure factor and the freezing of alkali halides

International Nuclear Information System (INIS)

March, N.H.; Tosi, M.P.

1980-10-01

The peak height of the charge-charge liquid structure factor Ssub(QQ) in molten alkali halides is proposed as a criterion for freezing. Available data on molten alkali chlorides, when extrapolated to the freezing point suggests Ssub(QQ)sup(max) approximately 5. (author)

Temperature measurement of RE123 bulk superconductors on magnetizing process

International Nuclear Information System (INIS)

Yokoyama, K.; Kaneyama, M.; Oka, T.; Fujishiro, H.; Noto, K.

2004-01-01

We study on the magnetization behavior of to magnetize RE123 bulk superconductors to apply it as strong magnets. Through magnetizing process, the temperature of bulk superconductors is raised by pinning loss caused by the magnetic fluxes motion (e.g. flux jump of flux flow), and the trapped field is decreased. This paper presents the measurement of temperature changes of Sm123 bulk superconductors during the exciting process by iteratively magnetizing pulsed-field operation with reducing amplitudes (IMRA) method. Five thermocouples are put on the surface of Sm123 bulk superconductor of 46 mm in diameter. The temperatures at the center, on the growth sector boundary (GSB) line and in the sector region surrounded by GSB's line (inter-GSB region) are monitored. The temperature at a cold stage is also measured. A Hall sensor is attached near the center thermocouple to measure the trapped field. After a bulk superconductor is cooled by the GM type refrigerator until 40 K, iterative pulsed-fields of 2.32-5.42 T are applied by a magnetizing coil. When high magnetic field of 5.42 T is applied, a temperature of bulk superconductor reaches to 72.4 K and the magnetic field distribution has C form with which a part of circle is dented, and then, a trapped field is 2.28 T. When a lower magnetic field of 4.64 T is applied, a maximum temperature is 68.3 K and a trapped field is raised to 2.70 T, and moreover, the distribution becomes round shape like field-cooling method (FC). We showed clearly that heat generation by pinning loss was related to the mechanism of magnetic field capture

Enhancement of critical temperature in fractal metamaterial superconductors

Energy Technology Data Exchange (ETDEWEB)

Smolyaninov, Igor I., E-mail: smoly@umd.edu [Department of Electrical and Computer Engineering, University of Maryland, College Park, MD 20742 (United States); Smolyaninova, Vera N. [Department of Physics Astronomy and Geosciences, Towson University, 8000 York Road, Towson, MD 21252 (United States)

2017-04-15

Fractal metamaterial superconductor geometry has been suggested and analyzed based on the recently developed theoretical description of critical temperature increase in epsilon near zero (ENZ) metamaterial superconductors. Considerable enhancement of critical temperature has been predicted in such materials due to appearance of large number of additional poles in the inverse dielectric response function of the fractal. Our results agree with the recent observation (Fratini et al. Nature 466, 841 (2010)) that fractal defect structure promotes superconductivity.

Classical spins in superconductors

Energy Technology Data Exchange (ETDEWEB)

Shiba, H [Tokyo Univ.; Maki, K

1968-08-01

It is shown that there exists a localized excited state in the energy gap in a superconductor with a classical spin. At finite concentration localized excited states around classical spins form an impurity band. The process of growth of the impurity band and its effects on observable quantities are investigated.

Theory of quantum metal to superconductor transitions in highly conducting systems

Energy Technology Data Exchange (ETDEWEB)

Spivak, B.

2010-04-06

We derive the theory of the quantum (zero temperature) superconductor to metal transition in disordered materials when the resistance of the normal metal near criticality is small compared to the quantum of resistivity. This can occur most readily in situations in which 'Anderson's theorem' does not apply. We explicitly study the transition in superconductor-metal composites, in an swave superconducting film in the presence of a magnetic field, and in a low temperature disordered d-wave superconductor. Near the point of the transition, the distribution of the superconducting order parameter is highly inhomogeneous. To describe this situation we employ a procedure which is similar to that introduced by Mott for description of the temperature dependence of the variable range hopping conduction. As the system approaches the point of the transition from the metal to the superconductor, the conductivity of the system diverges, and the Wiedemann-Franz law is violated. In the case of d-wave (or other exotic) superconductors we predict the existence of (at least) two sequential transitions as a function of increasing disorder: a d-wave to s-wave, and then an s-wave to metal transition.

Fe-vacancy and superconductivity in FeSe-based superconductors

Science.gov (United States)

Wang, C. H.; Chen, T. K.; Chang, C. C.; Lee, Y. C.; Wang, M. J.; Huang, K. C.; Wu, P. M.; Wu, M. K.

2018-06-01

This review summarizes recent advancements in FeSe and related systems. The FeSe and related superconductors are currently receiving considerable attention for the high Tcs observed and for many similar features to the high Tc cuprate superconductors. These similarities suggest that understanding the FeSe based compounds could potentially help our understanding of the cuprates. We shall first review the common features observed in the FeSe-based system. It was found that with a careful control of material synthesizing processes, numerous rich phases have been observed in the FeSe-based system. Detailed studies show that the Fe-vacancy ordered phases found in the FeSe based compounds, which are non-superconducting Mott insulators, are the parent compounds of the superconductors. Superconductivity emerges from the parent phases by disordering the Fe vacancy order, often by a simple annealing treatment. Recent high temperature X-ray diffraction experiments show that the degree of structural distortion associated with the disorder of Fe-vacancy is closely related to volume fraction of the superconductivity observed. These results suggest the strong lattice to spin coupling are important for the occurrence of superconductivity in FeSe based superconductors.

Anomalous Hall effect from vortex motion in high-Tc superconductors

International Nuclear Information System (INIS)

Chen, J.L.; Yang, T.J.

1994-01-01

In this work, the unusual Seebeck effect is taken into consideration in explaining the possible origin of the anomalous Hall effect for high-T c superconductors. Combining Maki's theory of transport entropy and Tinkham's theory of resistive transition, we explain why the anomalous Hall effect can be observed in high-T c superconductors, but is absent in most conventional superconductors. The behavior of ρ xy (H,T) in our theory is qualitatively consistent with experiments. In addition, our theory not only predicts that ρ xy will become positive from ρ xy xy |∝ρ xx 2 in the region of ρ xy xy will diminish with increasing defect concentration

Levitation of a magnet over a flat type II superconductor

International Nuclear Information System (INIS)

Hellman, F.; Gyorgy, E.M.; Johnson, D.W. Jr.; O'Bryan, H.M.; Sherwood, R.C.

1988-01-01

Levitation of a magnet over a type II superconductor where the field at the superconductor exceeds H/sub c/ 1 is described and shown. The penetration and pinning of the flux lines in the superconductor cause the position of the magnet to be stable over a flat disk; a complete Meissner effect would make this position unstable. Furthermore, the observed dependence of the height of levitation on such variables as the thickness of the superconducting disk and the size of the magnet are consistent with a model described in this paper based on the energy cost of flux penetration through vortices and inconsistent with a Meissner effect model

Process for the manufacture of a superconductor with an intermetallic compound

International Nuclear Information System (INIS)

Wilhelm, M.

1980-01-01

A superconductor with a superconducting intermetallic compound consisting of at least two elements can be manufactured by producing a conductor preproduct with a first component containing one element of the compound and a second component consisting of a carrier metal and the remaining element or elements of the alloy containing the compound, and by heat treating the conductor preproduct, so that the compound is formed by the reaction of the element of the first compound with the remaining element or elements of the second compound. In such a superconductor, one tries to increase the effective current density and critical current. The invention states that the heat treatment should be carried out in a hydrogen atmosphere. Superconductors produced by this process can be used for superconductor devices whose magnetic fields have a flux density above 10 Tesla. (orig.) [de

Second-Generation High-Temperature Superconductor Wires for the Electric Power Grid

Science.gov (United States)

Malozemoff, A. P.

2012-08-01

Superconductors offer major advantages for the electric power grid, including high current and power capacity, high efficiency arising from the lossless current flow, and a unique current-limiting functionality arising from a superconductor-to-resistive transition. These advantages can be brought to bear on equipment such as underground power cables, fault current limiters, rotating machinery, transformers, and energy storage. The first round of significant commercial-scale superconductor power-equipment demonstrations, carried out during the past decade, relied on a first-generation high-temperature superconductor (HTS) wire. However, during the past few years, with the recent commercial availability of high-performance second-generation HTS wires, power-equipment demonstrations have increasingly been carried out with these new wires, which bring important advantages. The foundation is being laid for commercial expansion of this important technology into the power grid.