WorldWideScience

Sample records for group metal flows

  1. Group Flow and Group Genius

    Science.gov (United States)

    Sawyer, Keith

    2015-01-01

    Keith Sawyer views the spontaneous collaboration of group creativity and improvisation actions as "group flow," which organizations can use to function at optimum levels. Sawyer establishes ideal conditions for group flow: group goals, close listening, complete concentration, being in control, blending egos, equal participation, knowing…

  2. Optimised Renormalisation Group Flows

    CERN Document Server

    Litim, Daniel F

    2001-01-01

    Exact renormalisation group (ERG) flows interpolate between a microscopic or classical theory and the corresponding macroscopic or quantum effective theory. For most problems of physical interest, the efficiency of the ERG is constrained due to unavoidable approximations. Approximate solutions of ERG flows depend spuriously on the regularisation scheme which is determined by a regulator function. This is similar to the spurious dependence on the ultraviolet regularisation known from perturbative QCD. Providing a good control over approximated ERG flows is at the root for reliable physical predictions. We explain why the convergence of approximate solutions towards the physical theory is optimised by appropriate choices of the regulator. We study specific optimised regulators for bosonic and fermionic fields and compare the optimised ERG flows with generic ones. This is done up to second order in the derivative expansion at both vanishing and non-vanishing temperature. An optimised flow for a ``proper-time ren...

  3. Alkali metals and group IIA metals

    International Nuclear Information System (INIS)

    Fenton, D.E.

    1987-01-01

    This chapter on the coordination complexes of the alkali metals of group IIA starts with a historical perspective of their chemistry, from simple monodentate ligands, metal-β-diketonates to the macrocyclic polyethers which act as ligands to the alkali and akaline earth metals. Other macrocyclic ligands include quarterenes, calixarenes, porphyrins, phthalocyanines and chlorophylls. A section on the naturally occurring ionophores and carboxylic ionophores is included. (UK)

  4. Conceptualizing Group Flow: A Framework

    Science.gov (United States)

    Duncan, Jana; West, Richard E.

    2018-01-01

    This literature review discusses the similarities in main themes between Csikszentmihályi theory of individual flow and Sawyer theory of group flow, and compares Sawyer's theory with existing concepts in the literature on group work both in education and business. Because much creativity and innovation occurs within groups, understanding group…

  5. FLIT: Flowing LIquid metal Torus

    Science.gov (United States)

    Kolemen, Egemen; Majeski, Richard; Maingi, Rajesh; Hvasta, Michael

    2017-10-01

    The design and construction of FLIT, Flowing LIquid Torus, at PPPL is presented. FLIT focuses on a liquid metal divertor system suitable for implementation and testing in present-day fusion systems, such as NSTX-U. It is designed as a proof-of-concept fast-flowing liquid metal divertor that can handle heat flux of 10 MW/m2 without an additional cooling system. The 72 cm wide by 107 cm tall torus system consisting of 12 rectangular coils that give 1 Tesla magnetic field in the center and it can operate for greater than 10 seconds at this field. Initially, 30 gallons Galinstan (Ga-In-Sn) will be recirculated using 6 jxB pumps and flow velocities of up to 10 m/s will be achieved on the fully annular divertor plate. FLIT is designed as a flexible machine that will allow experimental testing of various liquid metal injection techniques, study of flow instabilities, and their control in order to prove the feasibility of liquid metal divertor concept for fusion reactors. FLIT: Flowing LIquid metal Torus. This work is supported by the US DOE Contract No. DE-AC02-09CH11466.

  6. Liquid metal Flow Meter - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Andersen, C.; Hoogendoom, S.; Hudson, B.; Prince, J.; Teichert, K.; Wood, J.; Chase, K.

    2007-01-30

    Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

  7. Mechanisms of current flow in metal-semiconductor ohmic contacts

    International Nuclear Information System (INIS)

    Blank, T. V.; Gol'dberg, Yu. A.

    2007-01-01

    Published data on the properties of metal-semiconductor ohmic contacts and mechanisms of current flow in these contacts (thermionic emission, field emission, thermal-field emission, and also current flow through metal shunts) are reviewed. Theoretical dependences of the resistance of an ohmic contact on temperature and the charge-carrier concentration in a semiconductor were compared with experimental data on ohmic contacts to II-VI semiconductors (ZnSe, ZnO), III-V semiconductors (GaN, AlN, InN, GaAs, GaP, InP), Group IV semiconductors (SiC, diamond), and alloys of these semiconductors. In ohmic contacts based on lightly doped semiconductors, the main mechanism of current flow is thermionic emission with the metal-semiconductor potential barrier height equal to 0.1-0.2 eV. In ohmic contacts based on heavily doped semiconductors, the current flow is effected owing to the field emission, while the metal-semiconductor potential barrier height is equal to 0.3-0.5 eV. In alloyed In contacts to GaP and GaN, a mechanism of current flow that is not characteristic of Schottky diodes (current flow through metal shunts formed by deposition of metal atoms onto dislocations or other imperfections in semiconductors) is observed

  8. Sinuous Flow in Cutting of Metals

    Science.gov (United States)

    Yeung, Ho; Viswanathan, Koushik; Udupa, Anirudh; Mahato, Anirban; Chandrasekar, Srinivasan

    2017-11-01

    Using in situ high-speed imaging, we unveil details of a highly unsteady plastic flow mode in the cutting of annealed and highly strain-hardening metals. This mesoscopic flow mode, termed sinuous flow, is characterized by repeated material folding, large rotation, and energy dissipation. Sinuous flow effects a very large shape transformation, with local strains of ten or more, and results in a characteristic mushroomlike surface morphology that is quite distinct from the well-known morphologies of metal-cutting chips. Importantly, the attributes of this unsteady flow are also fundamentally different from other well-established unsteady plastic flows in large-strain deformation, like adiabatic shear bands. The nucleation and development of sinuous flow, its dependence on material properties, and its manifestation across material systems are demonstrated. Plastic buckling and grain-scale heterogeneity are found to play key roles in triggering this flow at surfaces. Implications for modeling and understanding flow stability in large-strain plastic deformation, surface quality, and preparation of near-strain-free surfaces by cutting are discussed. The results point to the inadequacy of the widely used shear-zone models, even for ductile metals.

  9. Liquid metal flow measurement by neutron radiography

    International Nuclear Information System (INIS)

    Takenaka, N.; Ono, A.; Matsubayashi, M.; Tsuruno, A.

    1996-01-01

    Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd 3 ) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.)

  10. Flow balancing in liquid metal blankets

    International Nuclear Information System (INIS)

    Tillack, M.S.; Morley, N.B.

    1995-01-01

    Non-uniform flow distribution between parallel channels is one of the most serious concerns for self-cooled liquid metal blankets with electrically insulated walls. We show that uncertainties in flow distribution can be dramatically reduced by relatively simple design modifications. Several design features which impose flow uniformity by electrically coupling parallel channels are surveyed. Basic mechanisms for ''flow balancing'' are described, and a particular self-regulating concept using discrete passive electrodes is proposed for the US ITER advanced blanket concept. Scoping calculations suggest that this simple technique can be very powerful in equalizing the flow, even with massive insulator failures in individual channels. More detailed analyses and experimental verification will be required to demonstrate this concept for ITER. (orig.)

  11. Metal Flow in Friction Stir Welding

    Science.gov (United States)

    Nunes, Arthur C., Jr.

    2006-01-01

    The plastic deformation field in Friction Stir Welding (FSW) is compared to that in metal cutting. A shear surface around the FSW tool analogous to the metal cutting shear plane is identified and comprises the basis of the "rotating plug" flow field model and the "wiping" model of tool interaction with weld metal. Within the context of these models: The FSW shear rate is estimated to be comparable to metal cutting shear rates. The effect of tool geometry on the FSW shear surface is discussed and related to published torque measurements. Various FS W structural features are explained, including a difference in structure of bimetallic welds when alloys on the advancing and retreating sides of the weld seam are exchanged. The joining mechanism and critical parameters of the FSW process are made clear.

  12. Derivative expansion and renormalisation group flows

    CERN Document Server

    Litim, Daniel F

    2001-01-01

    We study the convergence of the derivative expansion for flow equations. The convergence strongly depends on the choice for the infrared regularisation. Based on the structure of the flow, we explain why optimised regulators lead to better physical predictions. This is applied to O(N)-symmetric real scalar field theories in 3d, where critical exponents are computed for all N. In comparison to the sharp cut-off regulator, an optimised flow improves the leading order result up to 10%. An analogous reasoning is employed for a proper time renormalisation group. We compare our results with those obtained by other methods.

  13. On renormalization group flow in matrix model

    International Nuclear Information System (INIS)

    Gao, H.B.

    1992-10-01

    The renormalization group flow recently found by Brezin and Zinn-Justin by integrating out redundant entries of the (N+1)x(N+1) Hermitian random matrix is studied. By introducing explicitly the RG flow parameter, and adding suitable counter terms to the matrix potential of the one matrix model, we deduce some interesting properties of the RG trajectories. In particular, the string equation for the general massive model interpolating between the UV and IR fixed points turns out to be a consequence of RG flow. An ambiguity in the UV region of the RG trajectory is remarked to be related to the large order behaviour of the one matrix model. (author). 7 refs

  14. Liquid metal coolant flow rate regulation

    International Nuclear Information System (INIS)

    Vitkovskij, I.V.; Glukhikh, V.A.; Kirillov, I.R.; Smirnov, A.M.

    1981-01-01

    Some aspects of fast reactor and experimental bench operation related to liquid metal flow rate regulation are considered. Requirements to the devices for the flow rate regulation are formulated. A new type of these devices namely magnetohydrodynamic (MHD) throttles is described. Structural peculiarities of MHD throttles of different types are described as well. It is noted that the MHD throttles with a screw channel have the best energy mass indices. On the basis of the comparison of the MHD throttles with mechanical valves it is concluded that the MHD throttles described are useful for regulating the flow rates of any working media. Smoothness and accuracy of the flow rate regulation by the throttles are determined by the electric control circuit and may be practically anyone. The total coefficient of hydraulic losses in the throttle channel in the absence of a magnetic field is ten and more times lesser than in completely open mechanical valve. Electromagnetic time constant of the MHD throttles does not exceed several tenths of a second [ru

  15. Intrinsic thermoelectric power of group VB metals

    Directory of Open Access Journals (Sweden)

    Gunadhor Singh Okram

    2012-03-01

    Full Text Available We have reinvestigated the thermopower of group VB metals in polycrystalline forms in the temperature range of 6-300K, taking into account the critical nature of the sample surface and heat treatment especially for niobium. Strikingly small magnitude, negative sign, phonon drag dip and superconductivity not reported previously were observed in surface-cleaned single crystalline Nb. However, while thermopower magnitudes are small, mixed signs were found in the polycrystalline V, Nb and Ta samples. These properties were therefore interpreted as their intrinsic properties and were briefly discussed taking into account of the existing theory by fitting also the data that give the Fermi energies of 10.94 eV, 5.08 eV and 1.86eV, respectively.

  16. Renormalization group flows and continual Lie algebras

    International Nuclear Information System (INIS)

    Bakas, Ioannis

    2003-01-01

    We study the renormalization group flows of two-dimensional metrics in sigma models using the one-loop beta functions, and demonstrate that they provide a continual analogue of the Toda field equations in conformally flat coordinates. In this algebraic setting, the logarithm of the world-sheet length scale, t, is interpreted as Dynkin parameter on the root system of a novel continual Lie algebra, denoted by (d/dt;1), with anti-symmetric Cartan kernel K(t,t') = δ'(t-t'); as such, it coincides with the Cartan matrix of the superalgebra sl(N vertical bar N+1) in the large-N limit. The resulting Toda field equation is a non-linear generalization of the heat equation, which is integrable in target space and shares the same dissipative properties in time, t. We provide the general solution of the renormalization group flows in terms of free fields, via Baecklund transformations, and present some simple examples that illustrate the validity of their formal power series expansion in terms of algebraic data. We study in detail the sausage model that arises as geometric deformation of the O(3) sigma model, and give a new interpretation to its ultra-violet limit by gluing together two copies of Witten's two-dimensional black hole in the asymptotic region. We also provide some new solutions that describe the renormalization group flow of negatively curved spaces in different patches, which look like a cane in the infra-red region. Finally, we revisit the transition of a flat cone C/Z n to the plane, as another special solution, and note that tachyon condensation in closed string theory exhibits a hidden relation to the infinite dimensional algebra (d/dt;1) in the regime of gravity. Its exponential growth holds the key for the construction of conserved currents and their systematic interpretation in string theory, but they still remain unknown. (author)

  17. Capillary Flow of Liquid Metals in Brazing

    Science.gov (United States)

    Dehsara, Mohammad

    Capillary flow is driven or controlled by capillary forces, exerted at the triple line where the fluid phases meet the solid boundary. Phase field (PF) models naturally accommodate diffusive triple line motion with variable contact angle, thus allowing for the no-slip boundary condition without the stress singularities. Moreover, they are uniquely suited for modeling of topological discontinuities which often arise during capillary flows. In this study, we consider diffusive triple line motion within two PF models: the compositionally compressible (CC) and the incompressible (IC) models. We derive the IC model as a systematic approximation to the CC model, based on a suitable choice of continuum velocity field. The CC model, applied to the fluids of dissimilar mass densities, exhibits a computational instability at the triple line. The IC model perfectly represents the analytic equilibria. We develop the parameter identification procedure and show that the triple line kinetics can be well represented by the IC model's diffusive boundary condition. The IC model is first tested by benchmarking the phase-field and experimental kinetics of water, and silicone oil spreading over the glass plates in which two systems do not interact with the substrate. Then, two high-temperature physical settings involving spreading of the molten Al-Si alloy: one over a rough wetting substrate, the other over a non-wetting substrate are modeled in a T-joint structure which is a typical geometric configuration for many brazing and soldering applications. Surface roughness directly influences the spreading of the molten metal by causing break-ups of the liquid film and trapping the liquid away from the joint. In the early stages of capillary flow over non-wetting surface, the melting and flow are concurrent, so that the kinetics of wetting is strongly affected by the variations in effective viscosity of the partially molten metal. We define adequate time-dependent functions for the

  18. Development of radioactive platinum group metal catalysts

    International Nuclear Information System (INIS)

    Chung, H.S.; Kim, Y.S.; Kim, Y.E.

    1999-03-01

    The fission product nuclides generated during the irradiation of reactor fuel include many useful elements, among them platinum group metals such as ruthenium, rhodium and palladium which are of great industrial importance, occur rarely in nature and are highly valuable. In this research, the authors reviewed various PGM recovery methods. Recovery of palladium from seven-component simulated waste solutions was conducted by selective precipitation method. The recovery yield was more than 99.5% and the purity of the product was more than 99%. Wet-proof catalyst was prepared with the recovered palladium. The specific surface area of the catalyst support was more than 400m 2 /g. The content of palladium impregnated on the support was 1 to 10 wt. %. Hydrogen isotope exchange efficiency of more than 93% to equilibrium with small amount of the catalyst was obtained. It was turned out possible to consider using such palladium or other very low active PGM materials in applications where its activity is unimportant as in nuclear industries. (author). 86 refs., 44 tabs., 88 figs

  19. Development of radioactive platinum group metal catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H.S.; Kim, Y.S.; Kim, Y.E. [and others

    1999-03-01

    The fission product nuclides generated during the irradiation of reactor fuel include many useful elements, among them platinum group metals such as ruthenium, rhodium and palladium which are of great industrial importance, occur rarely in nature and are highly valuable. In this research, the authors reviewed various PGM recovery methods. Recovery of palladium from seven-component simulated waste solutions was conducted by selective precipitation method. The recovery yield was more than 99.5% and the purity of the product was more than 99%. Wet-proof catalyst was prepared with the recovered palladium. The specific surface area of the catalyst support was more than 400m{sup 2}/g.The content of palladium impregnated on the support was 1 to 10 wt. %. Hydrogen isotope exchange efficiency of more than 93% to equilibrium with small amount of the catalyst was obtained. It was turned out possible to consider using such palladium or other very low active PGM materials in applications where its activity is unimportant as in nuclear industries. (author). 86 refs., 44 tabs., 88 figs.

  20. Half-sandwich pentamethylcyclopentadienyl group 9 metal ...

    Indian Academy of Sciences (India)

    453 and LS-174) revealed low anti-proliferative activity. Replacement of substituted pyridine ligand in complexes such as picolinic acid exhibits better DNA binding affinity and cytotoxicity.7–10. Till now, a few reports are available for metal com-.

  1. A metal-free organic-inorganic aqueous flow battery

    Energy Technology Data Exchange (ETDEWEB)

    Huskinson, B; Marshak, MP; Suh, C; Er, S; Gerhardt, MR; Galvin, CJ; Chen, XD; Aspuru-Guzik, A; Gordon, RG; Aziz, MJ

    2014-01-08

    As the fraction of electricity generation from intermittent renewable sources-such as solar or wind-grows, the ability to store large amounts of electrical energy is of increasing importance. Solid-electrode batteries maintain discharge at peak power for far too short a time to fully regulate wind or solar power output(1,2). In contrast, flow batteries can independently scale the power (electrode area) and energy (arbitrarily large storage volume) components of the system by maintaining all of the electro-active species in fluid form(3-5). Wide-scale utilization of flow batteries is, however, limited by the abundance and cost of these materials, particularly those using redox-active metals and precious-metal electrocatalysts(6,7). Here we describe a class of energy storage materials that exploits the favourable chemical and electro-chemical properties of a family of molecules known as quinones. The example we demonstrate is ametal-free flow battery based on the redox chemistry of 9,10-anthraquinone-2,7-disulphonic acid (AQDS). AQDS undergoes extremely rapid and reversible two-electron two-proton reduction on a glassy carbon electrode in sulphuric acid. An aqueous flow battery with inexpensive carbon electrodes, combining the quinone/hydroquinone couple with the Br-2/Br- redox couple, yields a peak galvanic power density exceeding 0.6 W cm(-2) at 1.3 A cm(-2). Cycling of this quinone-bromide flow battery showed >99 per cent storage capacity retention per cycle. The organic anthraquinone species can be synthesized from inexpensive commodity chemicals(8). This organic approach permits tuning of important properties such as the reduction potential and solubility by adding functional groups: for example, we demonstrate that the addition of two hydroxy groups to AQDS increases the open circuit potential of the cell by 11% and we describe a pathway for further increases in cell voltage. The use of p-aromatic redox-active organic molecules instead of redox-active metals

  2. Heat transfer characteristics of alkali metals flowing across tube banks

    International Nuclear Information System (INIS)

    Sugiyama, K.; Ishiguro, R.; Kojima, Y.; Kanaoka, H.

    2004-01-01

    For the purpose of getting heat transfer coefficients of alkali metals flowing across tube banks at an acceptable level, we propose to use an inviscid-irrotational flow model, which is based on our flow visualization experiment. We show that the heat transfer coefficients obtained for the condition where only the test rod is heated in tube banks considerably differ from those obtained for the condition where all the rods are heated, because of interference between thick thermal boundary layers of alkali metals. We also confirm that the analytical values obtained by this flow model are in a reasonable agreement with experimental values. (author)

  3. Borides of the group 1 metals of the periodic system

    International Nuclear Information System (INIS)

    Samsonov, G.V.; Serebryakova, T.I.; Neronov, V.A.

    1975-01-01

    The borides of alkali metals (lithium, sodium, potassium) and the metals of a copper subgroup (copper, silver, gold) are described. Consideration is given to the crystalline structure and state diagrams of the metal systems within the first group of the Periodic Table with boron. Existence, formation conditions and physico-chemical properties of binary boride phases are characterized. Conclusion is made as to the absence of interaction between boron and silver. Information on the interaction between gold and boron is scanty and conflicting. Methods are described suitable for the production of the borides of the metals within the first group of the Periodic Table [ru

  4. Flow visualization through metal enclosures with neutron radiography

    International Nuclear Information System (INIS)

    Cimbala, J.M.; Sathianathan, D.; Cosgrove, S.A.

    1989-01-01

    Many practical fluid flow problems involve flow inside metal shrouds (valves, combustors, boilers, turbomachinery, etc.) where visual access is not available. For flows under extreme pressure or heat, glass or transparent plastic can not be used; a flow visualization technique which permits visualization through metal containers is needed in these cases. Since neutrons can penetrate metal casings, neutron radiography has been developed for application to fluid flow visualization. This technique involves imaging of neutron opaque tracer materials, such as solid or fluid particles or streaklines, as they convect in neutron transparent ambient fluids. Surface flow visualization is also possible by using neutron opaque tufts. An extension of the surface tuft technique has also been developed, enabling the visualization of flow a patterns away from solid surfaces. This paper presents a summary of the various flow visualization techniques developed in the authors' laboratory, along with examples which illustrate how these techniques may be applied to practical fluid flow problems. These include flow over a circular cylinder, the recirculation pattern formed by a jet exhausting into a tank, and the flow pattern inside a rotating automotive torque converter

  5. Environmental challenges of anthropogenic metals flows and cycles

    DEFF Research Database (Denmark)

    van der Voet, Ester; Salminen, Reijo; Eckelman, Matthew

    This report from the UNEP-hosted International Resource Panel, Environmental Risk and Challenges of Anthropogenic Metals Flows and Cycles, gives a clear picture of the potential environmental impacts of metals at different stages of the life-cycle while linking with other areas of resource use...

  6. Interaction of terbium group metal oxides with carbon

    International Nuclear Information System (INIS)

    Vodop'yanov, A.G.; Baranov, S.V.; Kozhevnikov, G.N.

    1990-01-01

    Mechanism of carbothermal reduction of terbium group metals from oxides is investigated using thermodynamic and kinetic analyses. Interaction of metal oxides with carbon covers dissociation of metal oxides and reduction by carbon monoxide, which contribution into general reduction depends on CO pressure. Temperatures of reaction beginning for batch initial components at P=1.3x10 -4 and P CO =0.1 MPa and of formation of oxycarbide melts are determined

  7. Fluid Flow Behaviour under Different Gases and Flow Rate during Gas Metal Arc Welding

    OpenAIRE

    Jaison Peter

    2013-01-01

    Gas metal arc welding (GMAW) is a highly efficient and fast process for fabricating high quality weld. High quality welds are fabricated by proper selection of consumable includes gas and filler metals. The optimum flow rate of gas will ensure the proper quality of weld. In this project, a fluid flow behavior of different flow rate is modeled and the change quality will be studied.

  8. Phosphors containing boron and metals of Group IIIA and IIIB

    Science.gov (United States)

    Setlur, Anant Achyut; Srivastava, Alok Mani; Comanzo, Holly Ann; Manivannan, Venkatesan

    2006-10-31

    A phosphor comprises: (a) at least a first metal selected from the group consisting of yttrium and elements of lanthanide series other than europium; (b) at least a second metal selected from the group consisting of aluminum, gallium, indium, and scandium; (c) boron; and (d) europium. The phosphor is used in light source that comprises a UV radiation source to convert UV radiation to visible light.

  9. Renormalization group flow of the Higgs potential.

    Science.gov (United States)

    Gies, Holger; Sondenheimer, René

    2018-03-06

    We summarize results for local and global properties of the effective potential for the Higgs boson obtained from the functional renormalization group, which allows one to describe the effective potential as a function of both scalar field amplitude and renormalization group scale. This sheds light onto the limitations of standard estimates which rely on the identification of the two scales and helps in clarifying the origin of a possible property of meta-stability of the Higgs potential. We demonstrate that the inclusion of higher-dimensional operators induced by an underlying theory at a high scale (GUT or Planck scale) can relax the conventional lower bound on the Higgs mass derived from the criterion of absolute stability.This article is part of the Theo Murphy meeting issue 'Higgs cosmology'. © 2018 The Author(s).

  10. Mechanical annealing in the flow of supercooled metallic liquid

    International Nuclear Information System (INIS)

    Zhang, Meng; Dai, Lan Hong; Liu, Lin

    2014-01-01

    Flow induced structural evolution in a supercooled metallic liquid Vit106a (Zr 58.5 Cu 15.6 Al 10.3 Ni 12.8 Nb 2.8 , at. %) was investigated via uni-axial compression combined with differential scanning calorimeter (DSC). Compression tests at strain rates covering the transition from Newtonian flow to non-Newtonian flow and at the same strain rate 2 × 10 −1 s −1 to different strains were performed at the end of glass transition (T g-end  = 703 K). The relaxation enthalpies measured by DSC indicate that the samples underwent non-Newtonian flow contain more free volume than the thermally annealed sample (703 K, 4 min), while the samples underwent Newtonian flow contain less, namely, the free volume of supercooled metallic liquids increases in non-Newtonian flow, while decreases in Newtonian flow. The oscillated variation of the relaxation enthalpies of the samples deformed at the same strain rate 2 × 10 −1 s −1 to different strains confirms that the decrease of free volume was caused by flow stress, i.e., “mechanical annealing.” Micro-hardness tests were also performed to show a similar structural evolution tendency. Based on the obtained results, the stress-temperature scaling in the glass transition of metallic glasses are supported experimentally, as stress plays a role similar to temperature in the creation and annihilation of free volume. In addition, a widening perspective angle on the glass transition of metallic glasses by exploring the 3-dimensional stress-temperature-enthalpy phase diagram is presented. The implications of the observed mechanical annealing effect on the amorphous structure and the work-hardening mechanism of metallic glasses are elucidated based on atomic level stress model

  11. Liquid metal flow control by DC electromagnetic pumps

    International Nuclear Information System (INIS)

    Borges, Eduardo Madeira; Braz Filho, Francisco Antonio; Guimaraes, Lamartine Nogueira Frutuoso

    2006-01-01

    The cooling system of high-density thermal power requires fluids of high thermal conductivity, such as liquid metals. Electromagnetic pumps can be used to liquid metal fluid flow control in cooling circuits. The operation of electromagnetic pumps used to flow control is based on Lorentz force. This force can be achieved by magnetic field and electric current interaction, controlled by external independent power supplies. This work presents the electromagnetic pump operational principles, the IEAv development scheme and the BEMC-1 simulation code. The theoretical results of BEMC-1 simulation are compared to electromagnetic pump operation experimental data, validating the BEMC-1 code. This code is used to evaluate the DC electromagnetic pump performance applied to Mercury flow control and others liquid metal such as Sodium, Lead and Bismuth, used in nuclear fast reactors. (author)

  12. A geometrical interpretation of renormalisation group flow

    International Nuclear Information System (INIS)

    Dolan, B.P.

    1993-05-01

    The renormalisation group (RG) equation in D-dimensional Euclidean space, R D , is analysed from a geometrical point of view. A general form of the RG equation is derived which is applicable to composite operators as well tensor operators (on R D ) which may depend on the Euclidean metric. It is argued that physical N-point amplitudes should be interpreted as rank N co-variant tensors on the space of couplings, G, and that the RG equation can be viewed as an equation for Lie transport on G with respect to the vector field generated by the β-functions of the theory. In one sense it is nothing more than the definition of a Lie derivative. The source of the anomalous dimensions can be interpreted as being due to the change of the basis vectors on G under Lie transport. The RG equation acts as a bridge between Euclidean space and coupling constant space in that the effect on amplitudes of a diffeomorphism of R D (that of dilations) is completely equivalent to a diffeomorphism of G generated by the β-functions of the theory. A form of the RG equation for operators is also given. These ideas are developed in detail for the example of massive λΦ 4 theory in 4 dimensions. (orig.)

  13. Metal flows of the circumgalactic medium, and the metal budget in galactic haloes

    Science.gov (United States)

    Muratov, Alexander L.; Kereš, Dušan; Faucher-Giguère, Claude-André; Hopkins, Philip F.; Ma, Xiangcheng; Anglés-Alcázar, Daniel; Chan, T. K.; Torrey, Paul; Hafen, Zachary H.; Quataert, Eliot; Murray, Norman

    2017-07-01

    We present an analysis of the flow of metals through the circumgalactic medium (CGM) in the Feedback in Realistic Environments (FIRE) simulations of galaxy formation, ranging from isolated dwarfs to L* galaxies. We find that nearly all metals produced in high-redshift galaxies are carried out in winds that reach 0.25Rvir. When measured at 0.25Rvir the metallicity of outflows is slightly higher than the interstellar medium (ISM) metallicity. Many metals thus reside in the CGM. Cooling and recycling from this reservoir determine the metal budget in the ISM. The outflowing metal flux decreases by a factor of ˜2-5 between 0.25Rvir and Rvir. Furthermore, outflow metallicity is typically lower at Rvir owing to dilution of the remaining outflow by metal-poor material swept up from the CGM. The inflow metallicity at Rvir is generally low, but outflow and inflow metallicities are similar in the inner halo. At low redshift, massive galaxies no longer generate outflows that reach the CGM, causing a divergence in CGM and ISM metallicity. Dwarf galaxies continue to generate outflows, although they preferentially retain metal ejecta. In all but the least massive galaxy considered, a majority of the metals are within the halo at z = 0. We measure the fraction of metals in CGM, ISM and stars, and quantify the thermal state of CGM metals in each halo. The total amount of metals in the low-redshift CGM of two simulated L* galaxies is consistent with estimates from the Cosmic Origin Spectrograph haloes survey, while for the other two it appears to be lower.

  14. Recycling of platinum group metals from the automotive catalysts

    International Nuclear Information System (INIS)

    Benevit, Mariana; Petter, Patricia Melo Halmenschlager; Veit, Hugo Marcelo

    2014-01-01

    Currently it is very important to use alternative sources of raw material for obtaining metals, avoiding the traditional mining. This work aims to characterize and evaluate the recoverability of platinum group metals present in automotive catalysts. Thus, the catalysts were divided into two groups: the first was catalysts used in 1.0 cars and the second was catalyst used in 2.0 cars. DRX and FRX techniques and chemical analysis performed by ICP/OES was used to characterized these materials. The results showed that there is a significant amount of platinum group elements in catalyst waste, which can be separated and reused. In the next step, hydro and pyrometallurgical routes, for metals extraction from catalyst waste, will be studied. (author)

  15. The architecture of metal coordination groups in proteins.

    Science.gov (United States)

    Harding, Marjorie M

    2004-05-01

    A set of tables is presented and a survey given of the architecture of metal coordination groups in a representative set of protein structures from the Protein Data Bank [Bernstein et al. (1977), J. Mol. Biol. 112, 535-542; Berman et al. (2000), Nucleic Acids Res. 28, 235-242]. The structures have been determined to a resolution of 2.5 A or better; the metals considered are Ca, Mg, Mn, Fe, Cu, Zn, Na and K, with particular emphasis on Ca and Zn and the exclusion of haem groups and Fe/S clusters; the proteins are a representative set in which none has more than 30% sequence identity with any other. In them the metal is coordinated by several donor groups from different amino-acid residues in the protein chain and often also by water or other small molecules. The tables, for approximately 600 metal coordination groups, include information on the conformations of the protein chain in the region around the metal and reliability indicators. They illustrate the wide variety of coordination numbers, chelate-loop sizes and other properties and the different characteristics of different metals. They show that glycine has a particular significance in the position adjacent to a donor residue, especially in Ca coordination groups. They also show that metal coordination does not appear to lead to significant distortions of the torsion angles phi, psi from their normally allowed values. Very few metal coordination groups occur more than once in the representative set and when they do they are usually related in fold and function; they have similar but not necessarily identical conformations. However, individual chelate loops, for example Zn(-C-X-X'-C-), in which both cysteines are coordinated to Zn through S, and X and X' are any amino acids, are repeated frequently in many different and unrelated proteins. Not all chelate loops with the same composition have the same conformation, but for smaller loops there are usually one or two strongly preferred and well defined

  16. Recent strikes in South Africa’s platinum-group metal mines: effects upon world platinum-group metal supplies

    Science.gov (United States)

    Yager, Thomas R.; Soto-Viruet, Yadira; Barry, James J.

    2012-01-01

    The recent labor disputes over wages and working conditions that have affected South Africa’s three leading platinum-group metal (PGM) producers have affected an industry already plagued by market pressures and labor unrest and raised the specter of constraints in the world’s supply of these metals. Although low demand for these metals in 2011 and 2012 helped to offset production losses of recent years, and particularly those losses caused by the strikes in 2012, a prolonged resumption of strikes could cause severe shortages of iridium, platinum, rhodium, ruthenium, and, to a lesser extent, palladium.

  17. Renormalization group coupling flow of SU(3) gauge theory

    OpenAIRE

    QCDTARO Collaboration

    1998-01-01

    We present our new results on the renormalization group coupling flow obtained i n 3 dimensional coupling space $(\\beta_{11},\\beta_{12},\\beta_{twist})$. The value of $\\beta_{twist}$ turns out to be small and the coupling flow projected on $(\\beta_{11},\\beta_{12})$ plane is very similar with the previous result obtained in the 2 dimensional coupling space.

  18. Combustion of metal agglomerates in a solid rocket core flow

    Science.gov (United States)

    Maggi, Filippo; Dossi, Stefano; DeLuca, Luigi T.

    2013-12-01

    The need for access to space may require the use of solid propellants. High thrust and density are appealing features for different applications, spanning from boosting phase to other service applications (separation, de-orbiting, orbit insertion). Aluminum is widely used as a fuel in composite solid rocket motors because metal oxidation increases enthalpy release in combustion chamber and grants higher specific impulse. Combustion process of metal particles is complex and involves aggregation, agglomeration and evolution of reacting particulate inside the core flow of the rocket. It is always stated that residence time should be enough in order to grant complete metal oxidation but agglomerate initial size, rocket grain geometry, burning rate, and other factors have to be reconsidered. New space missions may not require large rocket systems and metal combustion efficiency becomes potentially a key issue to understand whether solid propulsion embodies a viable solution or liquid/hybrid systems are better. A simple model for metal combustion is set up in this paper. Metal particles are represented as single drops trailed by the core flow and reacted according to Beckstead's model. The fluid dynamics is inviscid, incompressible, 1D. The paper presents parametric computations on ideal single-size particles as well as on experimental agglomerate populations as a function of operating rocket conditions and geometries.

  19. Irreversibility of world-sheet renormalization group flow

    International Nuclear Information System (INIS)

    Oliynyk, T.; Suneeta, V.; Woolgar, E.

    2005-01-01

    We demonstrate the irreversibility of a wide class of world-sheet renormalization group (RG) flows to first order in α ' in string theory. Our techniques draw on the mathematics of Ricci flows, adapted to asymptotically flat target manifolds. In the case of somewhere-negative scalar curvature (of the target space), we give a proof by constructing an entropy that increases monotonically along the flow, based on Perelman's Ricci flow entropy. One consequence is the absence of periodic solutions, and we are able to give a second, direct proof of this. If the scalar curvature is everywhere positive, we instead construct a regularized volume to provide an entropy for the flow. Our results are, in a sense, the analogue of Zamolodchikov's c-theorem for world-sheet RG flows on noncompact spacetimes (though our entropy is not the Zamolodchikov C-function)

  20. Bioaccumulation of platinum group metals in dolphins, Stenella sp ...

    African Journals Online (AJOL)

    Platinum group metals (PGMs) concentrations were measured in the tissues= of dolphins (Stenella sp.) caught along the Ghanaian coastline. Tissues from specimens caught by fishermen from Dixcove, western Ghana, were analysed in 2006 for palladium (Pd), platinum (Pt) and rhodium (Rh) using the Neutron Activation ...

  1. Group 4 Metal Complexes of Chelating Cyclopentadienyl-ketimide Ligands

    Czech Academy of Sciences Publication Activity Database

    Večeřa, M.; Varga, Vojtěch; Císařová, I.; Pinkas, Jiří; Kucharczyk, P.; Sedlařík, V.; Lamač, Martin

    2016-01-01

    Roč. 35, č. 5 (2016), s. 785-798 ISSN 0276-7333 R&D Projects: GA ČR(CZ) GA14-08531S; GA MŠk(CZ) LO1504 Institutional support: RVO:61388955 Keywords : group 4 metal complexes * cyclopentadienyl-ketimide ligands * metallocenes Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.862, year: 2016

  2. METALLICITY DISTRIBUTION FUNCTIONS OF FOUR LOCAL GROUP DWARF GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Ross, Teresa L.; Holtzman, Jon [Department of Astronomy, New Mexico State University, P.O. Box 30001, MSC 4500, Las Cruces, NM 88003-8001 (United States); Saha, Abhijit [NOAO, 950 Cherry Avenue, Tucson, AZ 85726-6732 (United States); Anthony-Twarog, Barbara J., E-mail: rosst@nmsu.edu, E-mail: holtz@nmsu.edu, E-mail: bjat@ku.edu [Department of Physics and Astronomy, University of Kansas, Lawrence, KS 66045-7582 (United States)

    2015-06-15

    We present stellar metallicities in Leo I, Leo II, IC 1613, and Phoenix dwarf galaxies derived from medium (F390M) and broad (F555W, F814W) band photometry using the Wide Field Camera 3 instrument on board the Hubble Space Telescope. We measured metallicity distribution functions (MDFs) in two ways, (1) matching stars to isochrones in color–color diagrams and (2) solving for the best linear combination of synthetic populations to match the observed color–color diagram. The synthetic technique reduces the effect of photometric scatter and produces MDFs 30%–50% narrower than the MDFs produced from individually matched stars. We fit the synthetic and individual MDFs to analytical chemical evolution models (CEMs) to quantify the enrichment and the effect of gas flows within the galaxies. Additionally, we measure stellar metallicity gradients in Leo I and II. For IC 1613 and Phoenix our data do not have the radial extent to confirm a metallicity gradient for either galaxy. We find the MDF of Leo I (dwarf spheroidal) to be very peaked with a steep metal-rich cutoff and an extended metal-poor tail, while Leo II (dwarf spheroidal), Phoenix (dwarf transition), and IC 1613 (dwarf irregular) have wider, less peaked MDFs than Leo I. A simple CEM is not the best fit for any of our galaxies; therefore we also fit the “Best Accretion Model” of Lynden-Bell. For Leo II, IC 1613, and Phoenix we find similar accretion parameters for the CEM even though they all have different effective yields, masses, star formation histories, and morphologies. We suggest that the dynamical history of a galaxy is reflected in the MDF, where broad MDFs are seen in galaxies that have chemically evolved in relative isolation and narrowly peaked MDFs are seen in galaxies that have experienced more complicated dynamical interactions concurrent with their chemical evolution.

  3. Revealing flow behaviors of metallic glass based on activation of flow units

    Energy Technology Data Exchange (ETDEWEB)

    Ge, T. P.; Wang, W. H.; Bai, H. Y., E-mail: hybai@iphy.ac.cn [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2016-05-28

    Atomic level flow plays a critical role in the mechanical behavior of metallic glass (MG) while the connection between the flow and the heterogeneous microstructure of the glass remains unclear. We describe the heterogeneity of MGs as the elastic matrix with “inclusions” of nano-scale liquid-like flow units, and the plastic flow behavior of MGs is considered to be accommodated by the flow units. We show that the model can explain the various deformation behaviors, the transformation from inhomogeneous deformation to homogeneous flow upon strain rate or temperature, and the deformation map in MGs, which might provide insights into the flow mechanisms in glasses and inspiration for improving the plasticity of MGs.

  4. Dual-plane ultrasound flow measurements in liquid metals

    International Nuclear Information System (INIS)

    Büttner, Lars; Nauber, Richard; Burger, Markus; Czarske, Jürgen; Räbiger, Dirk; Franke, Sven; Eckert, Sven

    2013-01-01

    An ultrasound measurement system for dual-plane, two-component flow velocity measurements especially in opaque liquids is presented. Present-day techniques for measuring local flow structures in opaque liquids disclose considerable drawbacks concerning line-wise measurement of single ultrasound probes. For studying time-varying flow patterns, conventional ultrasound techniques are either limited by time-consuming mechanical traversing or by the sequential operation of single probes. The measurement system presented within this paper employs four transducer arrays with a total of 100 single elements which allows for flow mapping without mechanical traversing. A high frame rate of several 10 Hz has been achieved due to an efficient parallelization scheme using time-division multiplexing realized by a microcontroller-based electronic switching matrix. The functionality and capability of the measurement system are demonstrated on a liquid metal flow at room temperature inside a cube driven by a rotating magnetic field (RMF). For the first time, the primary and the secondary flow have been studied in detail and simultaneously using a configuration with two crossed measurement planes. The experimental data confirm predictions made by numeric simulation. After a sudden switching on of the RMF, inertial oscillations of the secondary flow were observed by means of a time-resolved measurement with a frame rate of 3.4 Hz. The experiments demonstrate that the presented measurement system is able to investigate complex and transient flow structures in opaque liquids. Due to its ability to study the temporal evolution of local flow structures, the measurement system could provide considerable progress for fluid dynamics research, in particular for applications in the food industry or liquid metal technologies. (paper)

  5. Dual-plane ultrasound flow measurements in liquid metals

    Science.gov (United States)

    Büttner, Lars; Nauber, Richard; Burger, Markus; Räbiger, Dirk; Franke, Sven; Eckert, Sven; Czarske, Jürgen

    2013-05-01

    An ultrasound measurement system for dual-plane, two-component flow velocity measurements especially in opaque liquids is presented. Present-day techniques for measuring local flow structures in opaque liquids disclose considerable drawbacks concerning line-wise measurement of single ultrasound probes. For studying time-varying flow patterns, conventional ultrasound techniques are either limited by time-consuming mechanical traversing or by the sequential operation of single probes. The measurement system presented within this paper employs four transducer arrays with a total of 100 single elements which allows for flow mapping without mechanical traversing. A high frame rate of several 10 Hz has been achieved due to an efficient parallelization scheme using time-division multiplexing realized by a microcontroller-based electronic switching matrix. The functionality and capability of the measurement system are demonstrated on a liquid metal flow at room temperature inside a cube driven by a rotating magnetic field (RMF). For the first time, the primary and the secondary flow have been studied in detail and simultaneously using a configuration with two crossed measurement planes. The experimental data confirm predictions made by numeric simulation. After a sudden switching on of the RMF, inertial oscillations of the secondary flow were observed by means of a time-resolved measurement with a frame rate of 3.4 Hz. The experiments demonstrate that the presented measurement system is able to investigate complex and transient flow structures in opaque liquids. Due to its ability to study the temporal evolution of local flow structures, the measurement system could provide considerable progress for fluid dynamics research, in particular for applications in the food industry or liquid metal technologies.

  6. Thermochemical Properties of Group IVB and VB Transition Metal Alloys with Platinum Group Metals: Acid - Stabilization.

    Science.gov (United States)

    Cima, Michael John

    Solid-state galvanic cell measurements and oxide equilibration experiments are used to derive thermochemical quantities for a variety of acid-base stabilized alloys such as Nb-Pd, Nb-Rh, Ti-Pd, and Ti-Rh. The experiments have effectively resulted in the titration of palladium by niobium metal. The excess partial molar Gibbs energy of niobium at infinite dilution was determined to be -62 kcal/mole at 1000^circ C and the Gibbs energy of formation of {rm NbPd}_{3.55} is -42 kcal/mole. These results and those for the other systems are used to assess the importance of crystal field effects in the context of the generalized Lewis acid-base theory.

  7. Surface flow in severe plastic deformation of metals by sliding

    International Nuclear Information System (INIS)

    Mahato, A; Yeung, H; Chandrasekar, S; Guo, Y

    2014-01-01

    An in situ study of flow in severe plastic deformation (SPD) of surfaces by sliding is described. The model system – a hard wedge sliding against a metal surface – is representative of surface conditioning processes typical of manufacturing, and sliding wear. By combining high speed imaging and image analysis, important characteristics of unconstrained plastic flow inherent to this system are highlighted. These characteristics include development of large plastic strains on the surface and in the subsurface by laminar type flow, unusual fluid-like flow with vortex formation and surface folding, and defect and particle generation. Preferred conditions, as well as undesirable regimes, for surface SPD are demarcated. Implications for surface conditioning in manufacturing, modeling of surface deformation and wear are discussed

  8. Renormalization-group flows and charge transmutation in string theory

    International Nuclear Information System (INIS)

    Orlando, D.; Petropoulos, P.M.; Sfetsos, K.

    2006-01-01

    We analyze the behaviour of heterotic squashed-Wess-Zumino-Witten backgrounds under renormalization-group flow. The flows we consider are driven by perturbation creating extra gauge fluxes. We show how the conformal point acts as an attractor from both the target-space and world-sheet points of view. We also address the question of instabilities created by the presence of closed time-like curves in string backgrounds. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  9. Local microstructure and flow stress in deformed metals

    DEFF Research Database (Denmark)

    Zhang, Xiaodan; Hansen, Niels; Nielsen, Chris Valentin

    2017-01-01

    The microstructure and flow stress of metals are related through many well-known strength-structure relationships based on structural parameters, where grain size and dislocation density are examples. In heterogeneous structures, the local stress and strain are important as they will affect...... the bulk properties. A microstructural method is presented which allows the local stress in a deformed metal to be estimated based on microstructural parameters determined by an EBSD analysis. These parameters are the average spacing of deformation introduced boundaries and the fraction of high angle...... boundaries. The method is demonstrated for two heterogeneous structures: (i) a gradient (sub)surface structure in steel deformed by shot peening; (ii) a heterogeneous structure introduced by friction between a tool and a workpiece of aluminum. Flow stress data are calculated based on the microstructural...

  10. Flow-induced elastic anisotropy of metallic glasses

    International Nuclear Information System (INIS)

    Sun, Y.H.; Concustell, A.; Carpenter, M.A.; Qiao, J.C.; Rayment, A.W.; Greer, A.L.

    2016-01-01

    As-cast bulk metallic glasses are isotropic, but anisotropy can be induced by thermomechanical treatments. For example, the diffraction halo in the structure function S(Q) observed in transmission becomes elliptical (rather than circular) after creep in uniaxial tension or compression. Published studies associate this with frozen-in anelastic strain and bond-orientational anisotropy. Results so far are inconsistent on whether viscoplastic flow of metallic glasses can induce anisotropy. Preliminary diffraction data suggest that the anisotropy, if any, is very low, while measurements of the elastic properties suggest that there is induced anisotropy, opposite in sign to that due to anelastic strain. We study three bulk metallic glasses, Ce 65 Al 10 Cu 20 Co 5 , La 55 Ni 10 Al 35 , and Pd 40 Ni 30 Cu 10 P 20 . By using resonant ultrasound spectroscopy to determine the full elasticity tensor, the effects of relaxation and rejuvenation can be reliably separated from uniaxial anisotropy (of either sign). The effects of viscoplastic flow in tension are reported for the first time. We find that viscoplastic flow of bulk metallic glasses, particularly in tension, can induce significant anisotropy that is distinct from that associated with frozen-in anelastic strain. The conditions for inducing such anisotropy are explored in terms of the Weissenberg number (ratio of relaxation times for primary relaxation and for shear strain rate). There is a clear need for further work to characterize the structural origins of flow-induced anisotropy and to explore the prospects for improved mechanical and other properties through induced anisotropy.

  11. Effect of Platinum Group Metal Doping in Magnesium Diboride Wires

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Alexiou, Aikaterini; Namazkar, Shahla

    2016-01-01

    The effect of some platinum group metals(PGM = Rh, Pd, and Pt) on the microstructure and critical current density of Cu/Nb-sheathed MgB2 wires has been studied using Mg1-x PGMxB2 powders with low doping levels. It was found that Pt and Pd do not enter the MgB2 lattice and have only limited influe...

  12. Platinum group metal nitrides and carbides: synthesis, properties and simulation

    International Nuclear Information System (INIS)

    Ivanovskii, Alexander L

    2009-01-01

    Experimental and theoretical data on new compounds, nitrides and carbides of the platinum group 4d and 5d metals (ruthenium, rhodium, palladium, osmium, iridium, platinum), published over the past five years are summarized. The extreme mechanical properties of platinoid nitrides and carbides, i.e., their high strength and low compressibility, are noted. The prospects of further studies and the scope of application of these compounds are discussed.

  13. Can renormalization group flow end in a Big Mess?

    International Nuclear Information System (INIS)

    Morozov, Alexei; Niemi, Antti J.

    2003-01-01

    The field theoretical renormalization group equations have many common features with the equations of dynamical systems. In particular, the manner how Callan-Symanzik equation ensures the independence of a theory from its subtraction point is reminiscent of self-similarity in autonomous flows towards attractors. Motivated by such analogies we propose that besides isolated fixed points, the couplings in a renormalizable field theory may also flow towards more general, even fractal attractors. This could lead to Big Mess scenarios in applications to multiphase systems, from spin-glasses and neural networks to fundamental string (M?) theory. We consider various general aspects of such chaotic flows. We argue that they pose no obvious contradictions with the known properties of effective actions, the existence of dissipative Lyapunov functions, and even the strong version of the c-theorem. We also explain the difficulties encountered when constructing effective actions with chaotic renormalization group flows and observe that they have many common virtues with realistic field theory effective actions. We conclude that if chaotic renormalization group flows are to be excluded, conceptually novel no-go theorems must be developed

  14. Peruvian perovskite Between Transition-metal to PGM/PlatinumGroupMetal Catalytic Fusion

    Science.gov (United States)

    Maksoed, Wh-

    2016-11-01

    Strongly correlated electronic materials made of simple building blocks, such as a transition-metal ion in an octahedral oxygen cage forming a perovskite structure- Dagotto & Tokura for examples are the high-temperature superconductivity & the CMR/Colossal Magnetoresistance . Helium-4 denotes from LC Case,ScD: "Catalytic Fusion of Deuterium into Helium-4"- 1998 dealt with gaseous D2- "contacted with a supported metallic catalyst at superatmospheric pressure". The catalyst is a platinum-group metal, at about 0.5% - 1% by weight, on activated C. Accompanies Stephen J Geier, 2010 quotes "transition metal complexes", the Energy thus produced is enormous, and because the deuterium is very cheap in the form of heavy water (less than US 1/g), the fuel cost is very low (seas &Deuteronomy to be eternally preserves. Heartfelt Gratitudes to HE. Mr. Prof. Ir. HANDOJO.

  15. Regulation of liquid metal coolant flow rate in experimental loops

    International Nuclear Information System (INIS)

    Kozlov, F.A.; Laptev, G.I.

    1987-01-01

    The possibility to use the VRT-2, RPA-T and R 133 analog temperature regulators for the automated regulation of liquid metal flow rate in the experimental loops for investigations on sodium and sodium-potassium alloy technology is considered. The RPA-T device is shown to be the most convenient one; it is characterized by the following parameters: measuring modulus transfer coefficient is 500; the range of regulating modulus proportionality factor variation - 0.3 - 50; the range of the regulating modulus intergrating time constant variation - 5 - 500 s

  16. Flow characteristics of metallic powder grains for additive manufacturing

    Directory of Open Access Journals (Sweden)

    Peters Bernhard

    2017-01-01

    Full Text Available Directed energy deposition technologies for additive manufacturing such as laser selective melting (SLM or electron beam melting (EBM is a fast growing technique mainly due to its flexibility in product design. However, the process is a complex interaction of multi-physics on multiple length scales that are still not entirely understood. A particular challenging task are the flow characteristics of metallic powder ejected as jets from a nozzle and shielded by an inert turbulent gas flow. Therefore, the objective is to describe numerically the complex interaction between turbulent flow and powder grains. In order to include both several physical processes and length scales an Euler-Lagrange technology is applied. Within this framework powder is treated by the Discrete-Element-Method, while gas flow is described by Euler approaches as found in classical Computational Fluid Dynamics (CFD. The described method succeeded in delivering more accuracy and consistency than a standard approach based on the volume averaging technique and therefore, is suited for the solution of problems within an engineering framework.

  17. Recycling Potentials of Critical Metals-Analyzing Secondary Flows from Selected Applications

    Directory of Open Access Journals (Sweden)

    Till Zimmermann

    2014-03-01

    Full Text Available Metal mobilization in general, as well as the number of metals used in products to increase performance and provide sometimes unique functionalities, has increased steadily in the past decades. Materials, such as indium, gallium, platinum group metals (PGM, and rare earths (RE, are used ever more frequently in high-tech applications and their criticality as a function of economic importance and supply risks has been highlighted in various studies. Nevertheless, recycling rates are often below one percent. Against this background, secondary flows of critical metals from three different end-of-life products up to 2020 are modeled and losses along the products’ end-of-life (EOL chain are identified. Two established applications of PGM and RE–industrial catalysts and thermal barrier coatings–and CIGS photovoltaic cells as a relatively new product have been analyzed. In addition to a quantification of future EOL flows, the analysis showed that a relatively well working recycling system exists for PGM-bearing catalysts, while a complete loss of critical metals occurs for the other applications. The reasons include a lack of economic incentives, technologically caused material dissipation and other technological challenges.

  18. Magnetohydrodynamic pressure drop and flow balancing of liquid metal flow in a prototypic fusion blanket manifold

    Science.gov (United States)

    Rhodes, Tyler J.; Smolentsev, Sergey; Abdou, Mohamed

    2018-05-01

    Understanding magnetohydrodynamic (MHD) phenomena associated with the flow of electrically conducting fluids in complex geometry ducts subject to a strong magnetic field is required to effectively design liquid metal (LM) blankets for fusion reactors. Particularly, accurately predicting the 3D MHD pressure drop and flow distribution is important. To investigate these topics, we simulate a LM MHD flow through an electrically non-conducting prototypic manifold for a wide range of flow and geometry parameters using a 3D MHD solver, HyPerComp incompressible MHD solver for arbitrary geometry. The reference manifold geometry consists of a rectangular feeding duct which suddenly expands such that the duct thickness in the magnetic field direction abruptly increases by a factor rexp. Downstream of the sudden expansion, the LM is distributed into several parallel channels. As a first step in qualifying the flow, a magnitude of the curl of the induced Lorentz force was used to distinguish between inviscid, irrotational core flows and boundary and internal shear layers where inertia and/or viscous forces are important. Scaling laws have been obtained which characterize the 3D MHD pressure drop and flow balancing as a function of the flow parameters and the manifold geometry. Associated Hartmann and Reynolds numbers in the computations were ˜103 and ˜101-103, respectively, while rexp was varied from 4 to 12. An accurate model for the pressure drop was developed for the first time for inertial-electromagnetic and viscous-electromagnetic regimes based on 96 computed cases. Analysis shows that flow balance can be improved by lengthening the distance between the manifold inlet and the entrances of the parallel channels by utilizing the effect of flow transitioning to a quasi-two-dimensional state in the expansion region of the manifold.

  19. Kohn Anomaly and Phase Stability in Group VB Transition Metals

    Directory of Open Access Journals (Sweden)

    Alexander Landa

    2018-03-01

    Full Text Available In the periodic table, only a few pure metals exhibit lattice or magnetic instabilities associated with Fermi surface nesting, the classical examples being α-U and Cr. Whereas α-U displays a strong Kohn anomaly in the phonon spectrum that ultimately leads to the formation of charge density waves (CDWs, Cr is known for its nesting-induced spin density waves (SDWs. Recently, it has become clear that a pronounced Kohn anomaly and the corresponding softening in the elastic constants is also the key factor that controls structural transformations and mechanical properties in compressed group VB metals—materials with relatively high superconducting critical temperatures. This article reviews the current understanding of the structural and mechanical behavior of these metals under pressure with an introduction to the concept of the Kohn anomaly and how it is related to the important concept of Peierls instability. We review both experimental and theoretical results showing different manifestations of the Kohn anomaly in the transverse acoustic phonon mode TA (ξ00 in V, Nb, and Ta. Specifically, in V the anomaly triggers a structural transition to a rhombohedral phase, whereas in Nb and Ta it leads to an anomalous reduction in yield strength.

  20. Dual Solutions for Nonlinear Flow Using Lie Group Analysis.

    Directory of Open Access Journals (Sweden)

    Muhammad Awais

    Full Text Available `The aim of this analysis is to investigate the existence of the dual solutions for magnetohydrodynamic (MHD flow of an upper-convected Maxwell (UCM fluid over a porous shrinking wall. We have employed the Lie group analysis for the simplification of the nonlinear differential system and computed the absolute invariants explicitly. An efficient numerical technique namely the shooting method has been employed for the constructions of solutions. Dual solutions are computed for velocity profile of an upper-convected Maxwell (UCM fluid flow. Plots reflecting the impact of dual solutions for the variations of Deborah number, Hartman number, wall mass transfer are presented and analyzed. Streamlines are also plotted for the wall mass transfer effects when suction and blowing situations are considered.

  1. Measurement of Liquid-Metal Two-Phase Flow with a Dynamic Neutron Radiography

    International Nuclear Information System (INIS)

    Cha, J. E.; Lim, I. C.; Kim, H. R.; Kim, C. M.; Nam, H. Y.; Saito, Y.

    2005-01-01

    The dynamic neutron radiography(DNR) has complementary characteristics to X-ray radiography and is suitable to visualization and measurement of a multi-phase flow research in a metallic duct and liquid metal flow. The flow-field information of liquid metal system is very important for the safety analysis of fast breeder reactor and the design of the spallation target of accelerator driven system. A DNR technique was applied to visualize the flow field in the gas-liquid metal two-phase flow with the HANARO-beam facility. The lead bismuth eutectic and the nitrogen gas were used to construct the two-phase flow field in the natural circulation U-channel. The two-phase flow images in the riser were taken at various combinations of the liquid flow and gas flow with high frame-rate neutron radiography at 1000 fps

  2. Flow induced vibrations in liquid metal fast breeder reactors

    International Nuclear Information System (INIS)

    1989-01-01

    Flow induced vibrations are well known phenomena in industry. Engineers have to estimate their destructive effects on structures. In the nuclear industry, flow induced vibrations are assessed early in the design process, and the results are incorporated in the design procedures. In many cases, model testing is used to supplement the design process to ensure that detrimental behaviour due to flow induced vibrations will not occur in the component in question. While these procedures attempt to minimize the probability of adverse performance of the various components, there is a problem in the extrapolation of analytical design techniques and/or model testing to actual plant operation. Therefore, sodium tests or vibrational measurements of components in the reactor system are used to provide additional assurance. This report is a general survey of experimental and calculational methods in this area of structural mechanics. The report is addressed to specialists and institutions in industrialized and developing countries who are responsible for the design and operation of liquid metal fast breeder reactors. 92 refs, 90 figs, 8 tabs

  3. Metal cluster compounds - chemistry and importance; clusters containing isolated main group element atoms, large metal cluster compounds, cluster fluxionality

    International Nuclear Information System (INIS)

    Walther, B.

    1988-01-01

    This part of the review on metal cluster compounds deals with clusters containing isolated main group element atoms, with high nuclearity clusters and metal cluster fluxionality. It will be obvious that main group element atoms strongly influence the geometry, stability and reactivity of the clusters. High nuclearity clusters are of interest in there own due to the diversity of the structures adopted, but their intermediate position between molecules and the metallic state makes them a fascinating research object too. These both sites of the metal cluster chemistry as well as the frequently observed ligand and core fluxionality are related to the cluster metal and surface analogy. (author)

  4. Simulation of Flow Pattern around Inclined Bridge Group Pier using FLOW-3D Software

    Directory of Open Access Journals (Sweden)

    Malihesadat Jafari

    2017-03-01

    Full Text Available Introduction: Bridges are certainly one of the most important structures but costly service elements in a transport system. The bridges are very required to access the damaged areas in emergency situations such as floods and earthquakes. Scour around the foundations of bridge piers exposed to the flowing water than can destroy the bridge itself is a subject of major concern. Flow pattern is known as responsible for all changes in stream bed. Any obstacle in the channel can form new flow patterns causing additional shear stress exerted on the bed than the equilibrium condition of the absence of the obstacle. Appropriate shaping of flow pattern and proper selecting of pier geometry and the location of bridge piers can be one of the proper methods in reduction of scour amount which is the main subject of the present study. Materials and Methods: Inclined bridge group pier is a type of bridges with modern geometry based on development in building technology of structures. Many of these bridges have been built all around the world and the 8th bridge built crossing the Karun River in Ahvaz is a sample of the Iranian ones considered in this research. Hydrodynamic behavior of flow is investigated around the inclined bridge group pier settled on foundation using the FLOW-3D numerical model. Inclined bridge group pier investigated in this study, includes two rectangular piers which are 2.5 cm long and 3.5 cm wide and set in an angle of 28 degree on rectangular foundation which is 16 cm long and 10 cm wide and installed in three different foundation levels namely at, above and below the bed levels. The physical model of prototype pier considered in this study was constructed to the scale of 1:190 of the Ahvaz 8th bridge. In order to verify the accuracy of the numerical model, velocity data obtained from image processing technique were used. Results and Discussion: Due to non- linearity and interactions between various phenomena involved, flow pattern

  5. Organodioxygen complexes of some group 4B metal ions

    International Nuclear Information System (INIS)

    Tarafder, M.T.H.; Akhter Hossain; Gino Mariotto

    2003-09-01

    Organodioxygen complexes of some group 4B metal ions, viz., zirconium(IV), tin(IV) and lead(II) containing monodentate, bidentate and tridentate ligands were synthesized and characterized. The complexes have the compositions of [Zr(O)(O 2 )2C 5 H 5 N.H 2 O], [Zr(O)(O 2 - ) 2 .2OPPh 3 ], [Sn(O 2 )(C 9 H 6 NO) 2 ], [Sn(0 2 ) 2 .(CH 2 ) 2 (NH 2 ) 2 ], [Pb(O 2 - )(C 5 H 5 N) 2 NO 3 ], [Pb(O 2 )(C 8 H 6 NOH)], [Pb(O 2 - )(det)NO 3 ] and [PbO 2 - ) (C 5 H 4 NCOOH)NO 3 .H 2 O]. Because of apparent linearity of M- O 2 grouping, the V 1 (O-O) stretching modes were only Raman active, giving bands at 810- 841 cm 1 for the peroxo complexes (1, 3, ,4 and 6), while the bands in the superoxo complexes (2, 5, 7 and 8) appeared at 1020- 1100 cm -1 . The peroxo complex of Zr(IV) containing monodentate ligands were found to oxidize trans-stilbene to trans-stilbene oxide under stoichiometric conditions. The organoperoxo complexes of tin and lead were insensitive to oxidative processes. (author)

  6. The synthesis and properties of some organometallic compounds containing group IV (Ge, Sn)-group II (Zn, Cd) metal---metal bonds

    NARCIS (Netherlands)

    Des Tombe, F.J.A.; Kerk, G.J.M. van der; Creemers, H.M.J.C.; Carey, N.A.D.; Noltes, J.G.

    1972-01-01

    The reactions of triphenylgermane and triphenyltin hydride with coordinatively saturated organozinc or organocadmium compounds give organometallic complexes containing Group IV (Ge, Sn)-Group II(Zn, Cd) metal---metal bonds. The 2,2′-bipyridine complexes show solvent-dependent charge-transfer

  7. Sulfide precipitation method of separating uranium from Group II and Group III metal ions

    International Nuclear Information System (INIS)

    Sundar, P.S.

    1977-01-01

    Uranium is separated from analytical Group II and Group III metal ions in an aqueous liquor containing uranyl ions. The liquor is extracted with a non-interfering, water-immiscible, organic solvent containing a reagent which will react with the uranyl ions to form a complex soluble in the solvent. If the liquor is acidic, the solvent is washed with water. Then to the solvent is added an aqueous solution containing about 0.5 to 1.0 mole per liter of (NH 4 ) 2 CO 3 or NH 4 HCO 3 ions and sufficient sulfide ions to precipitate the metal ions as sulfides. The solvent and the aqueous solution are separated and the sulfides filtered from the aqueous solution. The ammonium-uranyl-tricarbonate in the aqueous solution can then be precipitated by increasing the concentration of (NH 4 ) 2 CO 3 or NH 4 HCO 3 ions to about 1.5 to 2.5 moles per liter. The precipitate is filtered and calcined to obtain U 3 O 8 or UO 2 . 21 claims, 1 figure

  8. Exploring liquid metal plasma facing component (PFC) concepts-Liquid metal film flow behavior under fusion relevant magnetic fields

    International Nuclear Information System (INIS)

    Narula, M.; Abdou, M.A.; Ying, A.; Morley, N.B.; Ni, M.; Miraghaie, R.; Burris, J.

    2006-01-01

    The use of fast moving liquid metal streams or 'liquid walls' as a plasma contact surface is a very attractive option and has been looked upon with considerable interest over the past several years, both by the plasma physics and fusion engineering programs. Flowing liquid walls provide an ever replenishing contact surface to the plasma, leading to very effective particle pumping and surface heat flux removal. A key feasibility issue for flowing liquid metal plasma facing component (PFC) systems, pertains to their magnetohydrodynamic (MHD) behavior under the spatially varying magnetic field environment, typical of a fusion device. MHD forces hinder the development of a smooth and controllable liquid metal flow needed for PFC applications. The present study builds up on the ongoing research effort at UCLA, directed towards providing qualitative and quantitative data on liquid metal free surface flow behavior under fusion relevant magnetic fields

  9. Continuous Polyol Synthesis of Metal and Metal Oxide Nanoparticles Using a Segmented Flow Tubular Reactor (SFTR

    Directory of Open Access Journals (Sweden)

    Andrea Testino

    2015-06-01

    Full Text Available Over the last years a new type of tubular plug flow reactor, the segmented flow tubular reactor (SFTR, has proven its versatility and robustness through the water-based synthesis of precipitates as varied as CaCO3, BaTiO3, Mn(1−xNixC2O4·2H2O, YBa oxalates, copper oxalate, ZnS, ZnO, iron oxides, and TiO2 produced with a high powder quality (phase composition, particle size, and shape and high reproducibility. The SFTR has been developed to overcome the classical problems of powder production scale-up from batch processes, which are mainly linked with mass and heat transfer. Recently, the SFTR concept has been further developed and applied for the synthesis of metals, metal oxides, and salts in form of nano- or micro-particles in organic solvents. This has been done by increasing the working temperature and modifying the particle carrying solvent. In this paper we summarize the experimental results for four materials prepared according to the polyol synthesis route combined with the SFTR. CeO2, Ni, Ag, and Ca3(PO42 nanoparticles (NPs can be obtained with a production rate of about 1–10 g per h. The production was carried out for several hours with constant product quality. These findings further corroborate the reliability and versatility of the SFTR for high throughput powder production.

  10. Synthesis of Group IVB Metals Oxicarbides by Carboreduction Reactions

    Directory of Open Access Journals (Sweden)

    A.D. Mazzoni

    2002-10-01

    Full Text Available The metals of the group IV B (Ti, Zr, Hf present a series of carbides and oxicarbides with scientific and technological interest. Many of these compounds belong to the subsystem "MO - MC" of the pseudoternary "MO - MN - MC" system (where M = Ti, Zr or Hf. In this work carboreduction reactions of TiO2 and ZrO2 were performed in argon atmosphere, using temperatures from 1250° to 1650° and reaction times of 120 min. The oxicarbides obtained were in the range TiC0.16O0.84 to TiC0.73O0.27 and ZrC0.46O0.54 to ZrC0.90O0.10. respectively. The reaction products were characterized by X-ray diffraction (XRD, with the calculation of their cell constants by means of the Rietveld method. Scanning Electron Microscopy (SEM was used in the characterization of powdered materials. Additionally, the carborreduction reaction was followed by weight loss.

  11. Platinum group metal recovery and catalyst manufacturing process

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H. S.; Kim, Y. S.; Yoo, J. H.; Lee, H. S.; Ahn, D. H.; Kim, K. R.; Lee, S. H.; Paek, S. W.; Kang, H. S.

    1998-03-01

    The fission product nuclides generated during the irradiation of reactor fuel include many useful elements, among them platinum group metal such as ruthenium, rhodium and palladium which are of great industrial importance, occur rarely in nature and are highly valuable. In this research, the authors reviewed various PGM recovery methods. Recovery of palladium from seven-component simulated waste solution was conducted by selective precipitation method. The recovery yield was more than 99.5% and the purity of the product was more than 99%. Wet-proof catalyst was prepared with the recovered palladium. The specific surface area of the catalyst support was more than 400 m{sup 2}/g. The content of palladium impregnated on the support was 10 wt.%. Hydrogen isotope exchange efficiency of 93 % to equilibrium with small amount of the catalyst was obtained. It was turned out possible to consider using such palladium or other very low active PGM materials in applications where its actively is unimportant as in nuclear industries. (author). 63 refs., 38 tabs., 36 figs.

  12. Synthesis of graphite intercalation compound of group VI metals and uranium hexafluorides

    International Nuclear Information System (INIS)

    Fukui, Toshihiro; Hagiwara, Rika; Ema, Keiko; Ito, Yasuhiko

    1993-01-01

    Systematic investigations were made on the synthesis of graphite intercalation compounds of group VI transition metals (W and Mo) and uranium hexafluorides. The reactions were performed by interacting liquid or gaseous metal hexafluorides with or without elemental fluorine at ambient temperature. The degree of intercalation of these metal fluorides depends on the formation enthalpy of fluorometallate anion from the original metal hexafluoride, as has been found for other intercalation reactions of metal fluorides. (author)

  13. Aromatic polyetherketones and polyethersulfones containing 6 group metals

    International Nuclear Information System (INIS)

    Agapov, V.M.; Salazkin, S.N.; Sergeev, V.A.; Komarova, L.I.; Petrovskij, P.V.

    1991-01-01

    Molybdenum- and tungsten-containing polyaryleneetherketones and polyaryleneethersulfones were prepared by the method of chemical modification. Metal content in the polymers constitutes from 0.7 to 12 mass %. The structure of the metal-containing polymers prepared was studied by the methods of 1 H and 13 C NMR and IR spectroscopy. Their properties were analyzed

  14. Photoacidic and Photobasic Behavior of Transition Metal Compounds with Carboxylic Acid Group(s)

    Energy Technology Data Exchange (ETDEWEB)

    O’Donnell, Ryan M. [Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States; Sampaio, Renato N. [Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States; Li, Guocan [Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States; Johansson, Patrik G. [Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States; Ward, Cassandra L. [Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States; Meyer, Gerald J. [Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States

    2016-03-10

    Excited state proton transfer studies of six Ru polypyridyl compounds with carboxylic acid/carboxylate group(s) revealed that some were photoacids and some were photobases. The compounds [RuII(btfmb)2(LL)]2+, [RuII(dtb)2(LL)]2+, and [RuII(bpy)2(LL)]2+, where bpy is 2,2'-bipyridine, btfmb is 4,4'-(CF3)2-bpy, and dtb is 4,4'-((CH3)3C)2-bpy, and LL is either dcb = 4,4'-(CO2H)2-bpy or mcb = 4-(CO2H),4'-(CO2Et)-2,2'-bpy, were synthesized and characterized. The compounds exhibited intense metal-to-ligand charge-transfer (MLCT) absorption bands in the visible region and room temperature photoluminescence (PL) with long τ > 100 ns excited state lifetimes. The mcb compounds had very similar ground state pKa’s of 2.31 ± 0.07, and their characterization enabled accurate determination of the two pKa values for the commonly utilized dcb ligand, pKa1 = 2.1 ± 0.1 and pKa2 = 3.0 ± 0.2. Compounds with the btfmb ligand were photoacidic, and the other compounds were photobasic. Transient absorption spectra indicated that btfmb compounds displayed a [RuIII(btfmb–)L2]2+* localized excited state and a [RuIII(dcb–)L2]2+* formulation for all the other excited states. Time dependent PL spectral shifts provided the first kinetic data for excited state proton transfer in a transition metal compound. PL titrations, thermochemical cycles, and kinetic analysis (for the mcb compounds) provided self-consistent pKa* values. The ability to make a single ionizable group photobasic or photoacidic through ligand design was unprecedented and was understood based on the orientation of the lowest-lying MLCT excited state dipole relative to the ligand that contained the carboxylic acid group(s).

  15. Metal droplet erosion and shielding plasma layer under plasma flows typical of transient processes in tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Martynenko, Yu. V., E-mail: Martynenko-YV@nrcki.ru [National Research Nuclear University “MEPhI” (Russian Federation)

    2017-03-15

    It is shown that the shielding plasma layer and metal droplet erosion in tokamaks are closely interrelated, because shielding plasma forms from the evaporated metal droplets, while droplet erosion is caused by the shielding plasma flow over the melted metal surface. Analysis of experimental data and theoretical models of these processes is presented.

  16. Damage mechanisms and metallic materials development in multiphase flow

    International Nuclear Information System (INIS)

    Zheng, Yugui; Liu, Wei; Yao, Zhiming; Ke, Wei

    2002-01-01

    The investigation on the synergistic effects among corrosion, slurry erosion and cavitation erosion has special significance for hydraulic turbines operated in Yangtze River and Yellow River where the high concentration solid particles exist in water. Two typical metallic materials i.e. Cr-Mn-N stainless steel and Ni-Ti shapememory-alloy, and two typical materials used for hydraulic turbines 20SiMn and 0Cr13Ni5Mo as compared materials were selected in order to investigate the roles of work-hardening ability and martensitic transformation as well as pseudoelastics in damage mechanism in multiphase flow. Both modified rotating disk rig and ultrasonic vibration facility were used to simulate the possible damage mechanism of materials in multiphase flow. The effects of corrosion on cavitation erosion were investigated through adding 3wt% NaCl. The degradation mechanism was analyzed by electrochemical test, SEM observation, hardness and roughness measurement. The results showed that there was a strong synergistic interaction among electrochemical corrosion, slurry erosion and cavitation erosion for 20SiMn in liquid-solid two-phase medium. In contrast, corrosion played little role for 0Cr13Ni5Mo. Cr-Mn-N stainless steel with high Mn content showed better resistance to cavitation erosion and slurry erosion than 0Cr13Ni5Mo, which was mainly due to its good work-hardening ability as well as strain-induced martensite transformation. The cavitation micro-cracks for Cr-Mn-N stainless steel were parallel to the specimen surface in contrast with 0Cr13Ni5Mo whose micro-cracks were perpendicular to the surface. Ni-Ti alloy with pseudoelasticity showed excellent resistance to combined interaction of cavitation erosion and slurry erosion

  17. Assessment of Electromagnetic Stirrer Agitated Liquid Metal Flows by Dynamic Neutron Radiography

    Science.gov (United States)

    Ščepanskis, Mihails; Sarma, Mārtiņš; Vontobel, Peter; Trtik, Pavel; Thomsen, Knud; Jakovičs, Andris; Beinerts, Toms

    2017-04-01

    This paper presents qualitative and quantitative characterization of two-phase liquid metal flows agitated by the stirrer on rotating permanent magnets. The stirrer was designed to fulfill various eddy flows, which may have different rates of solid particle entrapment from the liquid surface and their homogenization. The flow was characterized by visualization of the tailored tracer particles by means of dynamic neutron radiography, an experimental method well suited for liquid metal flows due to low opacity of some metals for neutrons. The rather high temporal resolution of the image acquisition (32 Hz image acquisition rate) allows for the quantitative investigation of the flows up to 30 cm/s using neutron particle image velocimetry. In situ visualization of the two-phase liquid metal flow is also demonstrated.

  18. Renormalization group flow of scalar models in gravity

    International Nuclear Information System (INIS)

    Guarnieri, Filippo

    2014-01-01

    In this Ph.D. thesis we study the issue of renormalizability of gravitation in the context of the renormalization group (RG), employing both perturbative and non-perturbative techniques. In particular, we focus on different gravitational models and approximations in which a central role is played by a scalar degree of freedom, since their RG flow is easier to analyze. We restrict our interest in particular to two quantum gravity approaches that have gained a lot of attention recently, namely the asymptotic safety scenario for gravity and the Horava-Lifshitz quantum gravity. In the so-called asymptotic safety conjecture the high energy regime of gravity is controlled by a non-Gaussian fixed point which ensures non-perturbative renormalizability and finiteness of the correlation functions. We then investigate the existence of such a non trivial fixed point using the functional renormalization group, a continuum version of the non-perturbative Wilson's renormalization group. In particular we quantize the sole conformal degree of freedom, which is an approximation that has been shown to lead to a qualitatively correct picture. The question of the existence of a non-Gaussian fixed point in an infinite-dimensional parameter space, that is for a generic f(R) theory, cannot however be studied using such a conformally reduced model. Hence we study it by quantizing a dynamically equivalent scalar-tensor theory, i.e. a generic Brans-Dicke theory with ω=0 in the local potential approximation. Finally, we investigate, using a perturbative RG scheme, the asymptotic freedom of the Horava-Lifshitz gravity, that is an approach based on the emergence of an anisotropy between space and time which lifts the Newton's constant to a marginal coupling and explicitly preserves unitarity. In particular we evaluate the one-loop correction in 2+1 dimensions quantizing only the conformal degree of freedom.

  19. Urban Metal Flows - A Case Study of Stockholm. Review and Conclusions

    International Nuclear Information System (INIS)

    Bergbaeck, B.; Johansson, K.; Mohlander, U.

    2001-01-01

    Metals have rapidly accumulated in the anthroposphere, especially in urban areas, indicating possible environmental and resource problems. Here, Stockholm City was chosen for a case study of urban metal flows, i.e. metal inflow to, metals in the stock of,and metal outflow from the anthroposphere to the biosphere. The metal stock of Stockholm is large and still growing. The large amounts of metals in the solid waste fraction totally dominate the outflow from the city. For major parts of the stock, the emissions from goods in use are negligible. There are, however,goods applications corresponding to significant emissions: e.g. the traffic sector (Cu, Zn, Cr, Ni, Pb), the tapwater system (Cu), roofs/fronts or other metal surfaces (Cu, Zn). Today's known metal flows from the anthroposphere of Stockholm to the biosphere and sewage sludge are quantitatively dominated by Zn(34 ton y -1 ) and Cu (14 ton y -1 ). Historical and present emissions have resulted in high metal concentrations in sediments (especially Cd, Hg and Pb, but also Cu and Zn), groundwater (Cu, Hg) and in soils (Hg, Cu, Pb). At present the annual median concentrations are below the Swedish limits for metals in sewage sludge, even if the safety margins are small for Cd, Hg and to some extent Cu. The flows of Cu and Zn to Stockholm soils are high with a significant accumulation indicating an environmental impact in a longer time perspective.High levels of metals in surface sediments in the water environments reflects an ongoing input where these metals are transported from known (Cu, Zn) and or partly unknown (Cd, Hg, Pb) sources. In future urban areas, monitoring of metal flows must be performed both in the anthroposphere and the biospherein order to have a pro active approach to urban environmental problems and to get prompt answers to measures taken

  20. Flow-by-flow chemical stratigraphy and evolution of thirteen Serra Geral Group basalt flows from Vista Alegre, southernmost Brazil

    Directory of Open Access Journals (Sweden)

    Viter M Pinto

    2011-06-01

    Full Text Available The geochemical characterization of thirteen Serra Geral Group flows in the Vista Alegre region (RS-SC, southern Brazil, displays the homogeneous basaltic composition near 50 wt.% SiO2. Each of the five basal flows (Pitanga-type, high-Ti/Y ~600, TiO2 > 3 wt.% and eight upper flows (Paranapanema-type, medium Ti/Y ~400, TiO2 > 2 wt.% can be identified from their chemical composition; sets of flows have parallel variation in chemical composition. The flow-by-flowcorrelation in four sections shows the horizontal position of the flows in three profiles and an approximately 200-m downdrop of the Itapiranga block with respect to the Frederico Westphalen block. The world-class amethyst geode mineralization and the systematic presence of native copper in the basalts make the correlation of great geological and economic significance.A caracterização geoquímica de treze derrames do Grupo Serra Geral na região de Vista Alegre (RS e SC, sul do Brasil, exibe uma composição basáltica homogênea próxima a 50% de SiO2. Os cinco derrames basais são classificados quimicamente como tipo Pitanga (alto Ti/Y ~600 e TiO2 > 3 em peso percentual, os demais oito derrames possuem médio Ti/Y ~400 com TiO2 ~2.5 em peso percentual, sendo classificados como magma tipo Paranapanema. Cada derrame pode ser identificado através de sua composição química e correlacionado, com variação paralela entre os perfis estudados. A correlação derrame a derrame nos quatro perfis demonstra uma posição horizontal em três perfis e um rejeito vertical de aproximadamente 200 m do bloco Itapiranga em relação ao bloco Frederico Westphalen. A presença de jazidas de ametista em geodos e a sistemática ocorrência de cobre nativo nos basaltos da região tornam a correlação de grande significado geológico e econômico.

  1. Stability of surface plastic flow in large strain deformation of metals

    Science.gov (United States)

    Viswanathan, Koushik; Udapa, Anirduh; Sagapuram, Dinakar; Mann, James; Chandrasekar, Srinivasan

    We examine large-strain unconstrained simple shear deformation in metals using a model two-dimensional cutting system and high-speed in situ imaging. The nature of the deformation mode is shown to be a function of the initial microstructure state of the metal and the deformation geometry. For annealed metals, which exhibit large ductility and strain hardening capacity, the commonly assumed laminar flow mode is inherently unstable. Instead, the imposed shear is accommodated by a highly rotational flow-sinuous flow-with vortex-like components and large-amplitude folding on the mesoscale. Sinuous flow is triggered by a plastic instability on the material surface ahead of the primary region of shear. On the other hand, when the material is extensively strain-hardened prior to shear, laminar flow again becomes unstable giving way to shear banding. The existence of these flow modes is established by stability analysis of laminar flow. The role of the initial microstructure state in determining the change in stability from laminar to sinuous / shear-banded flows in metals is elucidated. The implications for cutting, forming and wear processes for metals, and to surface plasticity phenomena such as mechanochemical Rehbinder effects are discussed.

  2. Toxic metals in WEEE: Characterization and substance flow analysis in waste treatment processes

    Energy Technology Data Exchange (ETDEWEB)

    Oguchi, Masahiro, E-mail: oguchi.masahiro@nies.go.jp; Sakanakura, Hirofumi; Terazono, Atsushi

    2013-10-01

    Waste electrical and electronic equipment (WEEE) has received extensive attention as a secondary source of metals. Because WEEE also contains toxic substances such as heavy metals, appropriate management of these substances is important in the recycling and treatment of WEEE. As a basis for discussion toward better management of WEEE, this study characterizes various types of WEEE in terms of toxic metal contents. The fate of various metals contained in WEEE, including toxic metals, was also investigated in actual waste treatment processes. Cathode-ray tube televisions showed the highest concentration and the largest total amount of toxic metals such as Ba, Pb, and Sb, so appropriate recycling and disposal of these televisions would greatly contribute to better management of toxic metals in WEEE. A future challenge is the management of toxic metals in mid-sized items such as audio/visual and ICT equipment because even though the concentrations were not high in these items, the total amount of toxic metals contained in them is not negligible. In the case of Japan, such mid-sized WEEE items as well as small electronic items are subject to municipal solid waste treatment. A case study showed that a landfill was the main destination of toxic metals contained in those items in the current treatment systems. The case study also showed that changes in the flows of toxic metals will occur when treatment processes are modified to emphasize resource recovery. Because the flow changes might lead to an increase in the amount of toxic metals released to the environment, the flows of toxic metals and the materials targeted for resource recovery should be considered simultaneously. - Highlights: ► Appropriate management of toxic metals contained in WEEE is important during recycling and treatment of WEEE. ► CRT TVs contain large amount of toxic metals with high concentration and thus appropriate management is highly important. ► Mid-sized equipment is a future target for

  3. Contact-free measurement of the flow field of a liquid metal inside a closed container

    OpenAIRE

    Heinicke Christiane

    2014-01-01

    The measurement of flow velocities inside metal melts is particularly challenging. Due to the high temperatures of the melts it is impossible to employ measurement techniques that require either mechanical contact with the melt or are only adaptable to translucent fluids. In the past years a number of electromagnetic techniques have been developed that allows a contact-free measurement of volume flows. One of these techniques is the so-called Lorentz Force Velocimetry (LFV) in which the metal...

  4. Heavy metal accumulation in a flow restricted, tropical estuary

    Digital Repository Service at National Institute of Oceanography (India)

    Balachandran, K.K.; Laluraj, C.M.; Nair, M.; Joseph, T.; Sheeba, P.; Venugopal, P.

    Levels of heavy metals (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn), organic carbon content and textural characteristics in the surficial sediments of Cochin estuary (SW coast of India) and adjacent coast are presented. Anthropogenic inputs from...

  5. International workshop on measuring techniques for liquid metal flows (MTLM). Abstracts

    Energy Technology Data Exchange (ETDEWEB)

    Gerbeth, G; Eckert, S [eds.

    1999-11-01

    The international workshop on 'Measuring techniques in liquid metal flows' (MTLM workshop) was organised in frame of the Dresden 'Innovationskolleg Magnetofluiddynamik'. The subject of the MTLM workshop was limited to methods to determine physical flow quantities such as velocity, pressure, void fraction, inclusion properties, crystallisation fronts etc. The present proceedings contain abstracts and viewgraphs of the oral presentations. During the last decades numerical simulations have become an important tool in industry and research to study the structure of flows and the properties of heat and mass transfer. However, in case of liquid metal flows there exists a significant problem to validate the codes with experimental data due to the lack of available measuring techniques. Due to the material properties (opaque, hot, chemical aggressive) the measurement of flow quantities is much more delicate in liquid metals compared to ordinary water flows. The generalisation of results obtained by means of water models to real liquid metal flows has often to be considered as difficult due to the problems to meet the actual values of n0n-dimensional flow parameters (Re, Pr, Gr, Ha, etc.). Moreover, a strong need has to be noted to make measuring techniques available tomonitor and to control flow processes in real industrial facilities. The objectives of the MTLM workshop were to: Review of existing information on a available techniques and experiences about the use in liquid metal flows, initiate a discussion between developers and potential users with respect to the actual need of information about the flow structure as well as the capabilities of existing and developing measuring techniques. Explore opportunities for co-operative R and D projects to expedite new developments and results, to share expertise and resources. (orig.)

  6. International workshop on measuring techniques for liquid metal flows (MTLM). Abstracts

    Energy Technology Data Exchange (ETDEWEB)

    Gerbeth, G.; Eckert, S. [eds.

    1999-11-01

    The international workshop on 'Measuring techniques in liquid metal flows' (MTLM workshop) was organised in frame of the Dresden 'Innovationskolleg Magnetofluiddynamik'. The subject of the MTLM workshop was limited to methods to determine physical flow quantities such as velocity, pressure, void fraction, inclusion properties, crystallisation fronts etc. The present proceedings contain abstracts and viewgraphs of the oral presentations. During the last decades numerical simulations have become an important tool in industry and research to study the structure of flows and the properties of heat and mass transfer. However, in case of liquid metal flows there exists a significant problem to validate the codes with experimental data due to the lack of available measuring techniques. Due to the material properties (opaque, hot, chemical aggressive) the measurement of flow quantities is much more delicate in liquid metals compared to ordinary water flows. The generalisation of results obtained by means of water models to real liquid metal flows has often to be considered as difficult due to the problems to meet the actual values of n0n-dimensional flow parameters (Re, Pr, Gr, Ha, etc.). Moreover, a strong need has to be noted to make measuring techniques available tomonitor and to control flow processes in real industrial facilities. The objectives of the MTLM workshop were to: Review of existing information on a available techniques and experiences about the use in liquid metal flows, initiate a discussion between developers and potential users with respect to the actual need of information about the flow structure as well as the capabilities of existing and developing measuring techniques. Explore opportunities for co-operative R and D projects to expedite new developments and results, to share expertise and resources. (orig.)

  7. Anthraquinone with Tailored Structure for Nonaqueous Metal-Organic Redox Flow Battery

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Wei; Xu, Wu; Cosimbescu, Lelia; Choi, Daiwon; Li, Liyu; Yang, Zhenguo

    2012-06-08

    A nonaqueous, hybrid metal-organic redox flow battery based on tailored anthraquinone structure is demonstrated to have an energy efficiency of {approx}82% and a specific discharge energy density similar to aqueous redox flow batteries, which is due to the significantly improved solubility of anthraquinone in supporting electrolytes.

  8. Anthraquinone with tailored structure for a nonaqueous metal-organic redox flow battery.

    Science.gov (United States)

    Wang, Wei; Xu, Wu; Cosimbescu, Lelia; Choi, Daiwon; Li, Liyu; Yang, Zhenguo

    2012-07-07

    A nonaqueous, hybrid metal-organic redox flow battery based on tailored anthraquinone structure is demonstrated to have an energy efficiency of ~82% and a specific discharge energy density similar to those of aqueous redox flow batteries, which is due to the significantly improved solubility of anthraquinone in supporting electrolytes.

  9. Flow patterns from metallic vascular endoprostheses: in vitro results

    Energy Technology Data Exchange (ETDEWEB)

    Mueller-Huelsbeck, S.; Grimm, J.; Jahnke, T.; Haeselbarth, G.; Heller, M. [Dept. of Radiology, University Hospital, Kiel (Germany)

    2001-05-01

    The aim of this study was to determine flow characteristics and pressure gradients of different balloon- and self-expandable stents in an in vitro flow-model. Seven vascular stents (Bridge, Cragg, Memotherm, Palmaz PS 784, Sinus, Symphony, Wallstent), equal in length (60 mm) and diameter (10 mm), were deployed in a closed flow model. The inner diameter of the tube measured 9 mm. Flow at 1.5 and 6 l/min was applied. Flow patterns were visualized by anionic particles illuminated with two helium-neon lasers. Late laminary flow characteristics and pre- /post-stent pressure gradients were determined in either expanded stent, 25 and 50 % tube stenosis. Stent implantation induced a decrease of laminary flow when compared with an unstented tube with and without concentric 25 % stenosis (p < 0.01) at all flow rates and an increase of pressure gradients when compared with an unstented tube for a flow rate of 6 l/min and all stenoses (p < 0.01). At 1.5 l/min most stents revealed no significant change of pressure gradient, the highest gradient measured 4.0 mmHg. Sinus permitted maximum (expanded: 82.1 % and 76.9 % at 25 % stenosis at 1.5 l/min; p < 0.01) and Palmaz minimum of laminary flow at all flow rates and stenoses (70.2 and 52.4 % at 25 % stenosis at 1.5 l/min; p < 0.01). At 6 l/min, when completely expanded, Sinus is equal to Bridge and Memotherm; in 25 % stenosis Sinus is equal to Bridge, Memotherm, and additionally to Cragg and Wall. None of the endoprostheses revealed laminary flow at 50 % stenosis. Inadequate stent deployment bears the risk of creating less laminary flow and pressure gradients. Since flow disturbances and pressure gradients may influence neointimal hyperplasia, stent design and completeness of stent expansion are important factors regarding the appearance of thrombus formation and postinterventional restenosis. (orig.)

  10. Flow-accelerated corrosion characteristics of galvanically coupled dissimilar metals

    International Nuclear Information System (INIS)

    Choi, Yoon Seok; Kim, Jnng Gu

    2001-01-01

    Flow accelerated galvanic corrosion characteristics of a carbon steel coupled to stainless steel were investigated in deaerated alkaline-chloride solutions as a function of flow velocities, pH and temperatures. The electrochemical properties of specimens were investigated by potentiodynamic test and galvanic corrosion test using RCE(Rotating Cylinder Electrode). Carbon steel showed active behavior in the deaerated alkaline-chloride solution. The galvanic current density of carbon steel increased with increasing flow velocity and temperature, but decreased with increasing pH. Flow velocity had a small effect on the galvanic current density at 25 deg. C, whereas the flow velocity increased galvanic current density significantly at 50 .deg. C and 75 .deg. C. This might be due to the increased solubility of magnetite at the higher temperatures

  11. Oxidation of Group 8 transition-Metal Hydrides and Ionic Hydrogenation of Ketones and Aldehydes

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Kjell-Tore

    1996-08-01

    Transition-metal hydrides have received considerable attention during the last decades because of their unusual reactivity and their potential as homogeneous catalysts for hydrogenation and other reactions of organic substrates. An important class of catalytic processes where transition-metal hydrides are involved is the homogeneous hydrogenation of alkenes, alkynes, ketones, aldehydes, arenes and nitro compounds. This thesis studies the oxidation of Group 8 transition-metal hydrides and the ionic hydrogenation of ketones and aldehydes.

  12. Transition from steady to periodic liquid-metal magnetohydrodynamic flow in a sliding electrical contact

    Science.gov (United States)

    Talmage, Gita; Walker, John S.; Brown, Samuel H.; Sondergaard, Neal A.

    1993-09-01

    In homopolar motors and generators, large dc electric currents pass through the sliding electrical contacts between rotating copper disks (rotors) and static copper surfaces shrouding the rotor tips (stators). A liquid metal in the small radial gap between the rotor tip and concentric stator surface can provide a low-resistance, low-drag electrical contact. Since there is a strong magnetic field in the region of the electrical contacts, there are large electromagnetic body forces on the liquid metal. The primary, azimuthal motion consists of simple Couette flow, plus an electromagnetically driven flow with large extremes of the azimuthal velocity near the rotor corners. The secondary flow involves the radial and axial velocity components, is driven by the centrifugal force associated with the primary flow, and is opposed by the electromagnetic body force, so that the circulation varies inversely as the square of the magnetic-field strength. Three flow regimes are identified as the angular velocity Ω of the rotor is increased. For small Ω, the primary flow is decoupled from the secondary flow. As Ω increases, the secondary flow begins to convect the azimuthal-velocity peaks radially outward, which in turn changes the centrifugal force driving the secondary flow. At some critical value of Ω, the flow becomes periodic through the coupling of the primary and secondary flows. The azimuthal-velocity peaks begin to move radially in and out with an accompanying oscillation in the secondary-flow strength.

  13. Renormalization group flow of entanglement entropy on spheres

    Energy Technology Data Exchange (ETDEWEB)

    Ben-Ami, Omer; Carmi, Dean [Raymond and Beverly Sackler Faculty of Exact Sciences School of Physics and Astronomy,Tel-Aviv University, Ramat-Aviv 69978 (Israel); Smolkin, Michael [Center for Theoretical Physics and Department of Physics,University of California, Berkeley, CA 94720 (United States)

    2015-08-12

    We explore entanglement entropy of a cap-like region for a generic quantum field theory residing in the Bunch-Davies vacuum on de Sitter space. Entanglement entropy in our setup is identical with the thermal entropy in the static patch of de Sitter, and we derive a simple relation between the vacuum expectation value of the energy-momentum tensor trace and the RG flow of entanglement entropy. In particular, renormalization of the bare couplings and logarithmic divergence of the entanglement entropy are interrelated in our setup. We confirm our findings by recovering known universal contributions for a free field theory deformed by a mass operator as well as obtain correct universal behaviour at the fixed points. Simple examples of entanglement entropy flows are elaborated in d=2,3,4. In three dimensions we find that while the renormalized entanglement entropy is stationary at the fixed points, it is not monotonic. We provide a computational evidence that the universal ‘area law’ for a conformally coupled scalar is different from the known result in the literature, and argue that this difference survives in the limit of flat space. Finally, we carry out the spectral decomposition of entanglement entropy flow and discuss its application to the F-theorem.

  14. Vibration-accelerated activation of flow units in a Pd-based bulk metallic glass

    Energy Technology Data Exchange (ETDEWEB)

    Li, Ning, E-mail: hslining@mail.hust.edu.cn [School of Materials Science and Engineering, and State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074 (China); Liu, Ze [Department of Engineering Mechanics, School of Civil Engineering, Wuhan University, Wuhan 430072 (China); Wang, Xinyun [School of Materials Science and Engineering, and State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074 (China); Zhang, Meng [Institute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632 (China)

    2017-04-24

    Controlled activation of flow units and in-situ characterization of mechanical properties in metallic glasses are facing challenges thus far. Here, vibrational loading is introduced through nanoscale dynamic mechanical analysis technique to probe vibration-accelerated atomic level flow that plays a crucial role in the mechanical behavior of metallic glasses. The intriguing finding is that high vibrational frequency induces deep indentation depth, prominent pop-in events on load–depth curves and low storage modulus, exhibiting a vibration-facilitated activation of flow units in Pd{sub 40}Cu{sub 30}Ni{sub 10}P{sub 20} metallic glass. Theoretical analysis revealed that vibration-moderated activation time-scale accelerate the activation of flow units and responsible for the above scenario.

  15. The questions of liquid metal two-phase flow modelling in the FBR core channels

    International Nuclear Information System (INIS)

    Martsiniouk, D.Ye.; Sorokin, A.P.

    2000-01-01

    The two-fluid model representation for calculations of two-phase flow characteristics in the FBR fuel pin bundles with liquid metal cooling is presented and analysed. Two conservation equations systems of the mass, momentum and energy have been written for each phase. Components accounted the mass-, momentum- and heat transfer throughout the interface occur in the macro-field equations after the averaging procedure realisation. The pattern map and correlations for two-fluid model in vertical liquid metal flows are presented. The description of processes interphase mass- and heat exchange and interphase friction is determined by the two-phase flow regime. The opportunity of the liquid metal two-phase flow regime definition is analysed. (author)

  16. High-energy-density, aqueous, metal-polyiodide redox flow batteries

    Science.gov (United States)

    Li, Bin; Nie, Zimin; Wang, Wei; Liu, Jun; Sprenkle, Vincent L.

    2017-08-29

    Improved metal-based redox flow batteries (RFBs) can utilize a metal and a divalent cation of the metal (M.sup.2+) as an active redox couple for a first electrode and electrolyte, respectively, in a first half-cell. For example, the metal can be Zn. The RFBs can also utilize a second electrolyte having I.sup.-, anions of I.sub.x (for x.gtoreq.3), or both in an aqueous solution, wherein the I.sup.- and the anions of I.sub.x (for x.gtoreq.3) compose an active redox couple in a second half-cell.

  17. Effect of electromagnetic coupling on MHD flow in the manifold of fusion liquid metal blanket

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Hongli, E-mail: hlchen1@ustc.edu.cn; Meng, Zi; Feng, Jingchao; He, Qingyun

    2014-10-15

    In fusion liquid metal (LM) blanket, magnetohydrodynamics (MHD) effects will dominate the flow patterns and the heat transfer characteristics of the liquid metal flow. Manifold is a key component in LM blanket in charge of distributing or collecting the liquid metal coolant. In this region, the complex three dimensional MHD phenomena will be occurred, and the velocity, pressure and flow rate distributions may be dramatically influenced. One important aspect is the electromagnetic coupling effect resulting from an exchange of electric currents between two neighboring fluid domains that can lead to modifications of flow distribution and pressure drop compared to that in electrical separated channels. Understanding the electromagnetic coupling effect in manifold is necessary to optimize the liquid metal blanket design. In this work, a numerical study was carried out to investigate the effect of electromagnetic coupling on MHD flow in a manifold region. The typical manifold geometry in LM blanket was considered, a rectangular supply duct entering a rectangular expansion area, finally feeding into 3 rectangular parallel channels. This paper investigated the effect of electromagnetic coupling on MHD flow in a manifold region. Different electromagnetic coupling modes with different combinations of electrical conductivity of walls were studied numerically. The flow distribution and pressure drop of these modes have been evaluated.

  18. On the renormalization group flow in two dimensional superconformal models

    International Nuclear Information System (INIS)

    Ahn, Changrim; Stanishkov, Marian

    2014-01-01

    We extend the results on the RG flow in the next to leading order to the case of the supersymmetric minimal models SM p for p≫1. We explain how to compute the NS and Ramond fields conformal blocks in the leading order in 1/p and follow the renormalization scheme proposed in [1]. As a result we obtained the anomalous dimensions of certain NS and Ramond fields. It turns out that the linear combination expressing the infrared limit of these fields in term of the IR theory SM p−2 is exactly the same as those of the nonsupersymmetric minimal theory

  19. Investigations of radiochemical methods for the platinum group metals for NAA

    International Nuclear Information System (INIS)

    Tredoux, M.

    A radiochemical procedure for the determination of the platinum group metals and gold is outlined in this report. The sample is irradiated, treated with acids and passed through anion-exchange columns before being determined by gamma spectrometry

  20. Liquid metal flows in insulating elements of self-cooled blankets

    International Nuclear Information System (INIS)

    Molokov, S.

    1995-01-01

    Liquid metal flows in insulating rectangular ducts in strong magnetic fields are considered with reference to poloidal concepts of self-cooled blankets. Although the major part of the flow in poloidal blanket concepts is close to being fully developed, manifolds, expansions, contractions, elbows, etc., which are necessary elements in blanket designs, cause three-dimensional effects. The present investigation demonstrates the flow pattern in basic insulating geometries for actual and more advanced liquid metal blanket concepts and discusses the ways to avoid pressure losses caused by flow redistribution. Flows in several geometries, such as symmetric and non-symmetric 180 turns with and without manifolds, sharp and linear expansions with and without manifolds, etc., have been considered. They demonstrate the attractiveness of poloidal concepts of liquid metal blankets, since they guarantee uniform conditions for heat transfer. If changes in the duct cross-section occur in the plane perpendicular to the magnetic field (ideally a coolant should always flow in the radial-poloidal plane), the disturbances are local and the slug velocity profile is reached roughly at a distance equivalent to one duct width from the manifolds, expansions, etc. The effects of inertia in these flows are unimportant for the determination of the pressure drop and velocity profiles in the core of the flow but may favour heat transfer characteristics via instabilities and strongly anisotropic turbulence. (orig.)

  1. Melt cationic and anionic composition effect on titanium group metal corrosion in halogenides of alkali earths

    International Nuclear Information System (INIS)

    Tkhaj, V.; Kovalik, O.Yu.; Dikunov, Yu.G.; P'yankova, S.P.

    1997-01-01

    A study was made on interaction of titanium group metals with melts of chlorides and chloride-fluorides of alkaline earth metals and magnesium. It was revealed that the rate of metal corrosion increased from BaCl 2 2 2 2 in chloride series. It is explained by amplification of oxidation activity of salt cation in the series: Ba 2+ 2+ 2+ 2+ . It was also determined that corrosion rate of titanium exceeded the one of zirconium and hafnium, became reducing power of titanium was the highest in the given group

  2. Fine-grained entanglement loss along renormalization-group flows

    International Nuclear Information System (INIS)

    Latorre, J.I.; Rico, E.; Luetken, C.A.; Vidal, G.

    2005-01-01

    We explore entanglement loss along renormalization group trajectories as a basic quantum information property underlying their irreversibility. This analysis is carried out for the quantum Ising chain as a transverse magnetic field is changed. We consider the ground-state entanglement between a large block of spins and the rest of the chain. Entanglement loss is seen to follow from a rigid reordering, satisfying the majorization relation, of the eigenvalues of the reduced density matrix for the spin block. More generally, our results indicate that it may be possible to prove the irreversibility along renormalization group trajectories from the properties of the vacuum only, without need to study the whole Hamiltonian

  3. Investment cash flow sensitivity and financing constraints : New evidence from Indian business group firms

    NARCIS (Netherlands)

    George, R.; Kabir, Mohammed Rezaul; Qian, J.

    2011-01-01

    A controversy exists on the use of the investment–cash flow sensitivity as a measure of financing constraints of firms.Were-examine this controversy by analyzing firms affiliated to Indian business groups. We find a strong investment–cash flow sensitivity for both group-affiliated and independent

  4. Platinum-group metals from nuclear reactions as a possible resource

    International Nuclear Information System (INIS)

    Jensen, G.A.

    1985-03-01

    Spent nuclear fuels contain significant quantities of three of the platinum-group metals (ruthenium, rhodium, and palladium), and a related element technetium, which is nearly absent in nature. Applications for ruthenium, rhodium, and palladium are well established. Since the supply of these and other platinum metals is largely from foreign sources, they are considered strategic materials. Existing and future spent nuclear fuels contain quantities of these platinum metals that exceed the United States reserve base. Technetium has properties similar to platinum metals and has unique, useful properties of its own. The technical feasibility of recovering and using fission product platinum metals (and technetium) extensively in industry depends on: thoroughly decontaminating platinum-group metals from all other radioactive materials in the waste stream; separating platinum-group metals from one another in very high purity; using applications where appropriate control of the residual radioactivity is possible; and whether or not the United States will recover or process spent fuel prior to repository storage. If the radioactivity must be removed, isotope separation or long term storage to allow decay of the contained radioisotopes may be possible. 7 figs., 7 tabs

  5. Demonstrating electromagnetic control of free-surface, liquid-metal flows relevant to fusion reactors

    Science.gov (United States)

    Hvasta, M. G.; Kolemen, E.; Fisher, A. E.; Ji, H.

    2018-01-01

    Plasma-facing components (PFC’s) made from solid materials may not be able to withstand the large heat and particle fluxes that will be produced within next-generation fusion reactors. To address the shortcomings of solid PFC’s, a variety of liquid-metal (LM) PFC concepts have been proposed. Many of the suggested LM-PFC designs rely on electromagnetic restraint (Lorentz force) to keep free-surface, liquid-metal flows adhered to the interior surfaces of a fusion reactor. However, there is very little, if any, experimental data demonstrating that free-surface, LM-PFC’s can actually be electromagnetically controlled. Therefore, in this study, electrical currents were injected into a free-surface liquid-metal that was flowing through a uniform magnetic field. The resultant Lorentz force generated within the liquid-metal affected the velocity and depth of the flow in a controllable manner that closely matched theoretical predictions. These results show the promise of electromagnetic control for LM-PFC’s and suggest that electromagnetic control could be further developed to adjust liquid-metal nozzle output, prevent splashing within a tokamak, and alter heat transfer properties for a wide-range of liquid-metal systems.

  6. Ecuador to withdraw from OPEC; group to maintain present flow

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper reports that the Organization of Petroleum Exporting Countries, which has agreed to maintain its present combined production of 24.2 million b/d of oil in the fourth quarter, will soon see the first pullout of a member. The 13 member group will shrink to 12, probably in November, when Ecuador withdraws. Ecuador President Sixto Duran Ballen issued notice of the pullout Sept. 17, a little more than 1 month after he took office. Ecuador, strapped for cash, wants to save OPEC membership dues reported to be $2-3 million/year. It plans to remain an associate member, although it wasn't immediately clear what that means. No other countries are regarded as associate members

  7. Three-dimensional MHD [magnetohydrodynamic] flows in rectangular ducts of liquid-metal-cooled blankets

    International Nuclear Information System (INIS)

    Hua, T.Q.; Walker, J.S.; Picologlou, B.F.; Reed, C.B.

    1988-07-01

    Magnetohydrodynamic flows of liquid metals in rectangular ducts with thin conducting walls in the presence of strong nonuniform transverse magnetic fields are examined. The interaction parameter and Hartmann number are assumed to be large, whereas the magnetic Reynolds number is assumed to be small. Under these assumptions, viscous and inertial effects are confined in very thin boundary layers adjacent to the walls. A significant fraction of the fluid flow is concentrated in the boundary layers adjacent to the side walls which are parallel to the magnetic field. This paper describes the analysis and numerical methods for obtaining 3-D solutions for flow parameters outside these layers, without solving explicitly for the layers themselves. Numerical solutions are presented for cases which are relevant to the flows of liquid metals in fusion reactor blankets. Experimental results obtained from the ALEX experiments at Argonne National Laboratory are used to validate the numerical code. In general, the agreement is excellent. 5 refs., 14 figs

  8. On Parameters Affecting Metal Flow and Friction in the Double Cup Extrusion Test

    DEFF Research Database (Denmark)

    Tan, Xincai; Bay, Niels; Zhang, Wenqi

    1998-01-01

    in numerical simulations often involve strain hardening because friction is expressed as a function of the flow stress or the flow shear stress. The double cup extrusion test is considered to be one of the process tests for determination of friction. In this test, varying heights of the upper and lower cups...... model with constant absolute value excluding the influence of strain hardening on friction was adopted in FEM simulations, in order to more clearly study the individual influence of strain hardening and friction on the metal flow (upper and lower cup height ratio) without interference between the two...... parameters. The predicted results show a good agreement with the experimental data. The influence of material strain hardening. friction and tool geometry on the metal flow in the test has been investigated. By comparisons of the cup height ratio as a function of the punch travel estimated by experiments...

  9. A working group`s conclusion on site specific flow and transport modelling

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, J. [Golder Associates AB (Sweden); Ahokas, H. [Fintact Oy, Helsinki (Finland); Koskinen, L.; Poteri, A. [VTT Energy, Espoo (Finland); Niemi, A. [Royal Inst. of Technology, Stockholm (Sweden). Hydraulic Engineering; Hautojaervi, A. [Posiva Oy, Helsinki (Finland)

    1998-03-01

    This document suggests a strategy plan for groundwater flow and transport modelling to be used in the site specific performance assessment analysis of spent nuclear fuel disposal to be used for the site selection planned by the year 2000. Considering suggested general regulations in Finland, as well as suggested regulations in Sweden and the approach taken in recent safety assessment exercises conducted in these countries, it is clear that in such an analysis, in addition to showing that the proposed repository is safe, there exist needs to strengthen the link between field data, groundwater flow modelling and derivation of safety assessment parameters, and needs to assess uncertainty and variability. The suggested strategy plan builds on an evaluation of different approaches to modelling the groundwater flow in crystalline basement rock, the abundance of data collected in the site investigation programme in Finland, and the modelling methodology developed in the programme so far. It is suggested to model the whole system using nested models, where larger scale models provide the boundary conditions for the smaller ones 62 refs.

  10. Gallium-Based Room-Temperature Liquid Metals: Actuation and Manipulation of Droplets and Flows

    Directory of Open Access Journals (Sweden)

    Leily Majidi

    2017-08-01

    Full Text Available Gallium-based room-temperature liquid metals possess extremely valuable properties, such as low toxicity, low vapor pressure, and high thermal and electrical conductivity enabling them to become suitable substitutes for mercury and beyond in wide range of applications. When exposed to air, a native oxide layer forms on the surface of gallium-based liquid metals which mechanically stabilizes the liquid. By removing or reconstructing the oxide skin, shape and state of liquid metal droplets and flows can be manipulated/actuated desirably. This can occur manually or in the presence/absence of a magnetic/electric field. These methods lead to numerous useful applications such as soft electronics, reconfigurable devices, and soft robots. In this mini-review, we summarize the most recent progresses achieved on liquid metal droplet generation and actuation of gallium-based liquid metals with/without an external force.

  11. Flow analysis of metals in a municipal solid waste management system

    International Nuclear Information System (INIS)

    Jung, C.H.; Matsuto, T.; Tanaka, N.

    2006-01-01

    This study aimed to identify the metal flow in a municipal solid waste (MSW) management system. Outputs of a resource recovery facility, refuse derived fuel (RDF) production facility, carbonization facility, plastics liquefaction facility, composting facility, and bio-gasification facility were analyzed for metal content and leaching concentration. In terms of metal content, bulky and incombustible waste had the highest values. Char from a carbonization facility, which treats household waste, had a higher metal content than MSW incinerator bottom ash. A leaching test revealed that Cd and Pb in char and Pb in RDF production residue exceeded the Japanese regulatory criteria for landfilling, so special attention should be paid to final disposal of these substances. By multiplying metal content and the generation rate of outputs, the metal content of input waste to each facility was estimated. For most metals except Cr, the total contribution ratio of paper/textile/plastics, bulky waste, and incombustible waste was over 80%. Approximately 30% of Cr originated from plastic packaging. Finally, several MSW management scenarios showed that most metals are transferred to landfills and the leaching potential of metals to the environment is quite small

  12. Thermodynamic characteristics of viscous flow activation in aqueous solutions of alkali metal iodides

    International Nuclear Information System (INIS)

    Renskij, I.A.; Rudnitskaya, A.A.; Fialkov, Yu.A.

    2003-01-01

    The Gibbs activation energy of the viscous flow of the alkali metal iodides aqueous solutions MI (M = Li, Na, K, Cs) and from its temperature dependence - the enthalpy and entropy of this process are calculated by the Eyring modified equation. The kinetic compensation effects, related to the viscous flow of the unbound water and to the ion-hydrate complexes are established. The relative contribution of the enthalpy and entropy constituents for these solution components is analyzed [ru

  13. Liquid metal flow in a finite-length cylinder with a rotating magnetic field

    International Nuclear Information System (INIS)

    Gelfgat, Yu.M.; Gorbunov, L.A.; Kolevzon, V.

    1993-01-01

    A liquid metal flow induced by a rotating magnetic field in a cylindrical container of finite height was investigated experimentally. It was demonstrated that the flow in a rotating magnetic field is similar to geophysical flows: the fluid rotates uniformly with depth and the Ekman layer exists at the container bottom. Near the vertical wall the flow is depicted in the form of a confined jet whose thickness determines the instability onset in a rotating magnetic field. It was shown that the critical Reynolds number can be found by using the jet velocity u 0 for Re cr =u 2 0 /ν∂u/∂r. The effect of frequency of a magnetic field on the fluid flow was also studied. An approximate theoretical model is presented for describing the fluid flow in a uniform rotating magnetic field. (orig.)

  14. Erosion of the 4-6- and 8 group transition metals under intense laser radiation

    International Nuclear Information System (INIS)

    Samsonov, G.V.; Verkhoturov, A.D.; Roshchina, A.I.; Vasil'ev, A.V.; Klimenko, V.P.

    1976-01-01

    The erosion resistance is studied of transition metals of Groups 4-6 and 8 at laser emission of approximately 6x1O 7 W/cm 2 . It is shown that as the emission power increases from 10 6 to 6x10 7 W/cm 2 the erosion values show an increase over tenfold without any subsequent filling of the craters. The growth of the metallic erosion is largely caused by a greater crater diameter. The erosion resistance of metals enhances in the following series: Ti-Zr-Co-Ni-Fe, Hf-V-Nb-Mo-Cr-Ta-W-Cu

  15. Structural Mimics of the [Fe]-Hydrogenase: A Complete Set for Group VIII Metals.

    Science.gov (United States)

    Barik, Chandan Kr; Ganguly, Rakesh; Li, Yongxin; Leong, Weng Kee

    2018-06-18

    A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C 5 H 4 N)(CO) 2 (2-S-C 5 H 4 N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand.

  16. Investigation of low-frequency-oscillating water flow in metal foam with 10 pores per inch

    Science.gov (United States)

    Bağcı, Ö.; Arbak, A.; De Paepe, M.; Dukhan, N.

    2018-01-01

    In this study, oscillating water flow in metal foam with open cells is investigated experimentally. The metal foam sample has a porosity of 88% and 10 pores. The water was oscillated in the test section with three frequencies between 0.116 Hz and 0.348 Hz, which are considered low for water oscillation, and three flow displacements ranging between 74.35 mm and 111.53 mm. The combinations of frequencies of displacements were studied for their impacts of dimensional and non-dimensional pressure loss quantities. To this purpose, friction factor was correlated as a function of kinetic Reynolds number. The same metal foam sample was studied by exposing it to steady-state water flow to investigate its permeability and drag coefficient in low-velocity flow regimes. The friction factor distribution for oscillating flow was found to be over that found for steady state. The outcomes of the study are important for studying heat transfer under the same flow conditions.

  17. Fourier analysis of cerebrospinal fluid flow velocities: MR imaging study. The Scandinavian Flow Group

    DEFF Research Database (Denmark)

    Thomsen, C; Ståhlberg, F; Stubgaard, M

    1990-01-01

    images. The phase information in the resultant image was converted to flow velocity with a calibration curve with the slope 26.5 radian.m-1.sec. The velocity versus time function was Fourier transformed and a continuous curve was fitted to the measured data with use of the first three harmonics...

  18. Annotated bibliography for liquid metal surface tensions of groups III-A, IV-A, and V-A metals

    International Nuclear Information System (INIS)

    Murtha, M.J.; Burnet, G.

    1976-04-01

    An annotated bibliography has been prepared which includes summaries of 82 publications dating from 1920 and dealing with the measurement of the surface tensions of Groups III-A, IV-A, and V-A metals in the liquid state. The bibliography is organized by key element investigated, and contains a tabulation of correlations for surface tension as a function of temperature. A brief discussion dealing with variables and methods has been included

  19. Slip-line field analysis of metal flow during two dimensional forging

    International Nuclear Information System (INIS)

    Fenton, R.G.; Khataan, H.A.

    1981-01-01

    A method of computation and a computer software package were developed for solving problems of two dimensional plastic flow between symmetrical dies of any specified shape. The load required to initiate plastic flow, the stress and velocity distributions in the plastic region of the metal, and the pressure distribution acting on the die are determined. The method can be used to solve any symmetrical plane strain flow problem regardless of the complexity of the die. The accurate solution obtained by this efficient method can provide valuable help to forging die designers. (Author) [pt

  20. Numerical modelling of microscopic lubricant flow in sheet metal forming. Application to plane strip drawing

    DEFF Research Database (Denmark)

    Carretta, Y.; Boman, R.; Bech, Jakob Ilsted

    2017-01-01

    This paper presents a numerical investigation of microscopic lubricant flows from the cavities to the plateaus of the surface roughness of metal sheets during forming processes. This phenomenon, called micro-plasto-hydrodynamic (MPH) lubrication, was observed experimentally in various situations...

  1. Nusselt number for turbulent flow of liquid metal in circular ducts

    International Nuclear Information System (INIS)

    Fernandez y Fernandez, E.; Carajilescov, P.

    1982-07-01

    The forced convection heat transfer in turbulent flow of liquid metals in ducts, is analyzed. An analogy between moment and heat at wall surface, is developed for determining one heat transfer coeficient in friction of friction coeficient. (E.G.) [pt

  2. Semi-empirical model for heat transfer coefficient in liquid metal turbulent flow

    International Nuclear Information System (INIS)

    Fernandez y Fernandez, E.; Carajilescov, P.

    1982-01-01

    The heat transfer by forced convection in a metal liquid turbulent flow for circular ducts is analyzed. An analogy between the momentum and heat in the wall surface, is determined, aiming to determine an expression for heat transfer coefficient in function of the friction coefficient. (E.G.) [pt

  3. Butterfly valve with metal seals controls flow of hydrogen from cryogenic through high temperatures

    Science.gov (United States)

    Johnson, L. D.

    1967-01-01

    Butterfly valve with metal seals operates over a temperature range of minus 423 degrees to plus 440 degrees F with hydrogen as a medium and in a radiation environment. Media flow is controlled by an internal butterfly disk which is rotated by an actuation shaft.

  4. Flow channel shape optimum design for hydroformed metal bipolar plate in PEM fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Linfa; Lai, Xinmin; Liu, Dong' an; Hu, Peng [State Key Laboratory of Mechanical System and Vibration, Shanghai Jiao Tong University, Shanghai 200240 (China); Ni, Jun [Department of Mechanical Engineering and Applied Mechanics, University of Michigan, Ann Arbor, MI 48109 (United States)

    2008-03-15

    Bipolar plate is one of the most important and costliest components of polymer electrolyte membrane (PEM) fuel cells. Micro-hydroforming is a promising process to reduce the manufacturing cost of PEM fuel cell bipolar plates made of metal sheets. As for hydroformed bipolar plates, the main defect is the rupture because of the thinning of metal sheet during the forming process. The flow channel section decides whether high quality hydroformed bipolar plates can be successively achieved or not. Meanwhile, it is also the key factor that is related with the reaction efficiency of the fuel cell stacks. In order to obtain the optimum flow channel section design prior the experimental campaign, some key geometric dimensions (channel depth, channel width, rib width and transition radius) of flow channel section, which are related with both reaction efficiency and formability, are extracted and parameterized as the design variables. By design of experiments (DOE) methods and an adoptive simulated annealing (ASA) optimization method, an optimization model of flow channel section design for hydroformed metal bipolar plate is proposed. Optimization results show that the optimum dimension values for channel depth, channel width, rib width and transition radius are 0.5, 1.0, 1. 6 and 0.5 mm, respectively with the highest reaction efficiency (79%) and the acceptable formability (1.0). Consequently, their use would lead to improved fuel cell efficiency for low cost hydroformed metal bipolar plates. (author)

  5. Simplified computational simulation of liquid metal behaviour in turbulent flow with heat transfer

    International Nuclear Information System (INIS)

    Costa, E.B. da.

    1992-09-01

    The present work selected the available bibliography equations and empirical relationships to the development of a computer code to obtain the turbulent velocity and temperature profiles in liquid metal tube flow with heat generation. The computer code is applied to a standard problem and the results are considered satisfactory, at least from the viewpoint of qualitative behaviour. (author). 50 refs, 21 figs, 3 tabs

  6. Free surface modeling of contacting solid metal flows employing the ALE formulation

    NARCIS (Netherlands)

    van der Stelt, A.A.; Bor, Teunis Cornelis; Geijselaers, Hubertus J.M.; Akkerman, Remko; Huetink, Han; Merklein, M.; Hagenah, H.

    2012-01-01

    In this paper, a numerical problem with contacting solid metal flows is presented and solved with an arbitrary Lagrangian-Eulerian (ALE) finite element method. The problem consists of two domains which mechanically interact with each other. For this simulation a new free surface boundary condition

  7. Development of two-group interfacial area transport equation for confined flow-2. Model evaluation

    International Nuclear Information System (INIS)

    Sun, Xiaodong; Kim, Seungjin; Ishii, Mamoru; Beus, Stephen G.

    2003-01-01

    The bubble interaction mechanisms have been analytically modeled in the first paper of this series to provide mechanistic constitutive relations for the two-group interfacial area transport equation (IATE), which was proposed to dynamically solve the interfacial area concentration in the two-fluid model. This paper presents the evaluation approach and results of the two-group IATE based on available experimental data obtained in confined flow, namely, 11 data sets in or near bubbly flow and 13 sets in cap-turbulent and churn-turbulent flow. The two-group IATE is evaluated in steady state, one-dimensional form. Also, since the experiments were performed under adiabatic, air-water two-phase flow conditions, the phase change effect is omitted in the evaluation. To account for the inter-group bubble transport, the void fraction transport equation for Group-2 bubbles is also used to predict the void fraction for Group-2 bubbles. Agreement between the data and the model predictions is reasonably good and the average relative difference for the total interfacial area concentration between the 24 data sets and predictions is within 7%. The model evaluation demonstrates the capability of the two-group IATE focused on the current confined flow to predict the interfacial area concentration over a wide range of flow regimes. (author)

  8. Fully developed liquid-metal flow in multiple rectangular ducts in a strong uniform magnetic field

    International Nuclear Information System (INIS)

    Molokov, S.

    1993-01-01

    Fully developed liquid-metal flow in a straight rectangular duct with thin conducting walls is investigated. The duct is divided into a number of rectangular channels by electrically conducting dividing walls. A strong uniform magnetic field is applied parallel to the outer side walls and dividing walls and perpendicular to the top and the bottom walls. The analysis of the flow is performed by means of matched asymptotics at large values of the Hartmann number M. The asymptotic solution obtained is valid for arbitrary wall conductance ratio of the side walls and dividing walls, provided the top and bottom walls are much better conductors than the Hartmann layers. The influence of the Hartmann number, wall conductance ratio, number of channels and duct geometry on pressure losses and flow distribution is investigated. If the Hartmann number is high, the volume flux is carried by the core, occupying the bulk of the fluid and by thin layers with thickness of order M -1/2 . In some of the layers, however, the flow is reversed. As the number of channels increases the flow in the channels close to the centre approaches a Hartmann-type flow with no jets at the side walls. Estimation of pressure-drop increase in radial ducts of a self-cooled liquid-metal blanket with respect to flow in a single duct with walls of the same wall conductance ratio gives an upper limit of 30%. (author). 13 refs., 10 figs., 1 tab

  9. Thermal structure and flow patterns around Seychelles group of Islands (Indian Ocean) during austral autumn

    Digital Repository Service at National Institute of Oceanography (India)

    Vethamony, P.; RameshBabu, V.; RameshKumar, M.R.

    Properties of thermal structure in the upper 750 m around the Seychelles group of islands in the Indian Ocean, based on Expendable Bathythermograph (XBT) data collected in March 1984, are presented along with the inferred flow patterns...

  10. Study on surface wave characteristics of free surface flow of liquid metal lithium for IFMIF

    International Nuclear Information System (INIS)

    Hoashi, Eiji; Sugiura, Hirokazu; Yoshihashi-Suzuki, Sachiko; Yamaoka, Nobuo; Horiike, Hiroshi; Kanemura, Takuji; Kondo, Hiroo

    2011-01-01

    The international fusion materials irradiation facility (IFMIF) presents an intense neutron source to develop fusion reactor materials. The free surface flow of a liquid metal Lithium (Li) is planned as a target irradiated by two deuteron beams to generate intense neutrons and it is thus important to obtain knowledge of the surface wave characteristic for the safety and the efficiency of system in the IFMIF. We have been studying on surface wave characteristics experimentally using the liquid metal Li circulation facility at Osaka University and numerically using computational fluid dynamics (CFD) code, FLUENT. This paper reports the results of the surface fluctuation, the wave height and the surface velocity in the free surface flow of the liquid metal Li examined experimentally and numerically. In the experiment, an electro-contact probe apparatus was used to obtain the surface fluctuation and the wave height, and a high speed video was used to measure the surface velocity. We resulted in knowledge of the surface wave growth mechanism. On the other hand, a CFD simulation was also conducted to obtain information on the relation of the free surface with the inner flow. In the simulation, the model included from a two-staged contraction nozzle to a flow channel with a free surface flow region and simulation results were compared with the experimental data. (author)

  11. NUMERICAL SIMULATION OF METAL MELT FLOWS IN MOLD CAVITY WITH CERAMIC POROUS MEDIA

    Directory of Open Access Journals (Sweden)

    Changchun Dong

    2016-05-01

    Full Text Available Process modeling of metal melt flow in porous media plays an important role in casting of metal matrix composites. In this work, a mathematical model of the metal melt flow in preform ceramic particles was used to simulate the flow behavior in a mold cavity. The effects of fluid viscosity and permeability (mainly affected by porosity of ceramic preforms on the flow behavior were analyzed. The results indicate that ceramic porous media have a significant effect on the flow behavior by contributing to a low filling velocity and sharp pressure drop in the cavity. The pressure drop has a linear relationship with the fluid velocity, and a nonlinear relationship with porosity. When the porosity is relatively small, the pressure drop is extremely large. When porosity exceeds a certain value, the pressure drop is independent of porosity. The relationship between viscosity and porosity is described, and it is shown that the critical porosity changes when the viscosity of the melt changes. However, due to the limited viscosity change, the critical porosity changes by less than 0.043.

  12. Computed Tomography 3-D Imaging of the Metal Deformation Flow Path in Friction Stir Welding

    Science.gov (United States)

    Schneider, Judy; Beshears, Ronald; Nunes, Arthur C., Jr.

    2005-01-01

    In friction stir welding (FSW), a rotating threaded pin tool is inserted into a weld seam and literally stirs the edges of the seam together. To determine optimal processing parameters for producing a defect free weld, a better understanding of the resulting metal deformation flow path is required. Marker studies are the principal method of studying the metal deformation flow path around the FSW pin tool. In our study, we have used computed tomography (CT) scans to reveal the flow pattern of a lead wire embedded in a FSW weld seam. At the welding temperature of aluminum, the lead becomes molten and is carried with the macro-flow of the weld metal. By using CT images, a 3-dimensional (3D) image of the lead flow pattern can be reconstructed. CT imaging was found to be a convenient and comprehensive way of collecting and displaying tracer data. It marks an advance over previous more tedious and ambiguous radiographic/metallographic data collection methods.

  13. Continuous metal scavenging and coupling to one-pot copper-catalyzed azide-alkyne cycloaddition click reaction in flow

    NARCIS (Netherlands)

    Vural - Gursel, Dr. Iris; Aldiansyah, Ferry; Wang, Qi; Noël, Timothy; Hessel, Volker

    2015-01-01

    Increasing usage of catalytic chemistry calls for efficient removal of metal traces. This paper describes the development and optimization of a scavenger-based extraction in flow to remove metal catalysts. It enables liquid-liquid extraction with slug flow and phase separation with a porous

  14. Plastic flow produced by single ion impacts on metals

    International Nuclear Information System (INIS)

    Birtcher, R. C.

    1998-01-01

    Single ion impacts have been observed using in situ transmission electron microscopy and video recording with a time resolution of 33 milliseconds. Gold was irradiated at 50 K and room temperature. Single ion impacts produce holes, modify existing holes, and extrude material into the initial specimen hole and holes formed by other ion impacts. The same behavior is observed at both temperatures. At both temperatures, ion impacts result in craters and ejected material. Ion impacts produce more small craters than large ones for all ion masses, while heavier mass ions produce more and larger craters than lighter mass ions. This comparison is affected by the ion energy. As the energy of an ion is increased, the probability for deposition near the surface decreases and fewer craters are formed. For a given ion mass, crater production depends on the probability for displacement cascade production in the near surface region. Crater and holes are stable at room temperature, however, ion impacts near an existing crater may cause flow of material into the crater either reshaping or annihilating it. Holes and craters result from the explosive outflow of material from the molten zone of near-surface cascades. The outflow may take the form of molten material, a solid lid or an ejected particle. The surface is a major perturbation on displacement cascades resulting from ion impacts

  15. Combined Lorentz force and ultrasound Doppler velocimetry in a vertical convection liquid metal flow

    Science.gov (United States)

    Zürner, Till; Vogt, Tobias; Resagk, Christian; Eckert, Sven; Schumacher, Jörg

    2017-11-01

    We report experimental studies on turbulent vertical convection flow in the liquid metal alloy gallium-indium-tin. Flow measurements were conducted by a combined use of local Lorentz force velocimetry (LLFV) and ultrasound Doppler velocimetry (UDV). It is known that the forced convection flow in a duct generates a force on the LLFV magnet system, that grows proportional to the flow velocity. We show that for the slower flow of natural convection LLFV retains this linear dependence in the range of micronewtons. Furthermore experimental results on the scaling of heat and momentum transport with the thermal driving are presented. The results cover a range of Rayleigh numbers 3 ×105 Deutsche Forschungsgemeinschaft under Grant No. GRK 1567.

  16. Two-group interfacial area concentration correlations of two-phase flows in large diameter pipes

    International Nuclear Information System (INIS)

    Shen, Xiuzhong; Hibiki, Takashi

    2015-01-01

    The reliable empirical correlations and models are one of the important ways to predict the interfacial area concentration (IAC) in two-phase flows. However, up to now, no correlation or model is available for the prediction of the IAC in the two-phase flows in large diameter pipes. This study collected an IAC experimental database of two-phase flows taken under various flow conditions in large diameter pipes and presented a systematic way to predict the IAC for two-phase flows from bubbly, cap-bubbly to churn flow in large diameter pipes by categorizing bubbles into two groups (group-1: spherical and distorted bubble, group-2: cap bubble). Correlations were developed to predict the group-1 void fraction from the void fraction of all bubble. The IAC contribution from group-1 bubbles was modeled by using the dominant parameters of group-1 bubble void fraction and Reynolds number based on the parameter-dependent analysis of Hibiki and Ishii (2001, 2002) using one-dimensional bubble number density and interfacial area transport equations. A new drift velocity correlation for two-phase flow with large cap bubbles in large diameter pipes was derived in this study. By comparing the newly-derived drift velocity correlation with the existing drift velocity correlation of Kataoka and Ishii (1987) for large diameter pipes and using the characteristics of the representative bubbles among the group 2 bubbles, we developed the model of IAC and bubble size for group 2 cap bubbles. The developed models for estimating the IAC are compared with the entire collected database. A reasonable agreement was obtained with average relative errors of ±28.1%, ±54.4% and ±29.6% for group 1, group 2 and all bubbles respectively. (author)

  17. Time-dependent liquid metal flows with free convection and free surfaces

    International Nuclear Information System (INIS)

    McClelland, M.A.

    1990-11-01

    A finite element analysis is given for time-dependent liquid metal flows with free convection and free surfaces. Consideration is given to a two-dimensional shallow trough with vertical walls maintained at different temperatures. The spatial formulation incorporates mixed Lagrangian approximations to the velocity, pressure, temperature, and interface position. The time integration method is performed using the Trapezoid Rule with step-size control. The Galerkin method is employed to reduce the problem to a set of nonlinear algebraic equations which are solved with the Newton-Raphson method. Calculations are performed for conditions relevant to the electron beam vaporization of refractory metals. The Prandtl number is 0.015, and Grashof numbers are in the transition region between laminar and turbulent flow. The results reveal the effects of flow intensity, surface-tension gradients, and mesh and time-step refinement

  18. Real life experimental determination of platinum group metals content in automotive catalytic converters

    Science.gov (United States)

    Yakoumis, I.; Moschovi, A. M.; Giannopoulou, I.; Panias, D.

    2018-03-01

    The real life experimental protocol for the preparation of spent automobile catalyst samples for elemental analysis is thoroughly described in the following study. Collection, sorting and dismantling, homogenization and sample preparation for X-Ray fluorescence spectroscopy and Atomic Adsorption Spectroscopy combined with Inductive coupled plasma mass spectrometry are discussed in detail for both ceramic and metallic spent catalysts. The concentrations of Platinum Group Metals (PGMs) in spent catalytic converters are presented based on typical consignments of recycled converters (more than 45,000 pieces) from the Greek Market. The conclusions clearly denoted commercial metallic catalytic foil contains higher PGMs loading than ceramic honeycombs. On the other hand, the total PGMs loading in spent ceramic catalytic converters has been found higher than the corresponding value for the metallic ones.

  19. Contact-free measurement of the flow field of a liquid metal inside a closed container

    Directory of Open Access Journals (Sweden)

    Heinicke Christiane

    2014-03-01

    Full Text Available The measurement of flow velocities inside metal melts is particularly challenging. Due to the high temperatures of the melts it is impossible to employ measurement techniques that require either mechanical contact with the melt or are only adaptable to translucent fluids. In the past years a number of electromagnetic techniques have been developed that allows a contact-free measurement of volume flows. One of these techniques is the so-called Lorentz Force Velocimetry (LFV in which the metal flow is exposed to an external, permanent magnetic field. The interaction between the metal and the magnet not only leads to a force on the fluid, but also on the magnet. The force can be measured and is proportional to the velocity of the melt. Moreover, by using a small permanent magnet it is possible to resolve spatial structures inside the flow.We will demonstrate this using a model experiment that has been investigated with different reference techniques previously. The experimental setup is a cylindrical vessel filled with a eutectic alloy which is liquid at room temperature. The liquid metal can be set into motion by means of a propeller at the top of the liquid. Depending on the direction of rotation of the propeller, the flow inside the vessel takes on different states. Beside the vessel, we place a Lorentz Force Flowmeter (LFF equipped with a small permanent magnet. By measuring the force on the magnet at different positions and different rotation speeds, we demonstrate that we can qualitatively and quantitatively reconstruct the flow field inside the vessel.

  20. Saturation flow mathematical model based on multiple combinations of lane groups

    Energy Technology Data Exchange (ETDEWEB)

    Racila, L.

    2016-07-01

    The ideal value of the traffic stream that can pass through an intersection is known as the saturation flow rate per hour on vehicle green time. The saturation flow is important in the understanding of the traffic light cycle and from there the understanding the Level of Service. The paper wishes to evaluate through a series of applied mathematical methods the effect of different lane grouping and critical lane group concept on the saturation flow rate. The importance of this method is that it creates a base for a signalized intersections timing plan. (Author)

  1. Grouping and trapping of evaporating droplets in an oscillating gas flow

    International Nuclear Information System (INIS)

    Katoshevski, David; Shakked, Tal; Sazhin, Sergei S.; Crua, Cyril; Heikal, Morgan R.

    2008-01-01

    A new approach to the analysis of droplet grouping in an oscillating gas flow is suggested. This is based on the investigation of droplet trajectories in the frame of reference moving with the phase velocity of the wave. Although the equations involved are relatively simple, the analysis shows distinctive characteristics of grouping and non-grouping cases. In the case of grouping, droplet trajectories converge to the points for which the ratio of flow velocity in this frame of reference and the amplitude of flow oscillations is less than 1, and the cosine of the arc sine of this ratio is positive. In the case of non-grouping, droplet trajectories in this frame of reference oscillate around the translational velocity close to the velocity of flow in the same frame of reference. The effect of droplet size on the grouping pattern is investigated. It has been pointed out that for the smaller droplets much more stable grouping is observed. The effect of droplet evaporation is studied in the limiting case when the contribution of the heat-up period can be ignored. It is shown that evaporation can lead to droplet grouping even in the case when the non-evaporating droplets are not grouped. This is related to the reduction in droplet diameter during the evaporation process. Coupling between gas and droplets is shown to decrease the grouping tendency. A qualitative agreement between predictions of the model and in-house experimental observations referring to Diesel engine sprays has been demonstrated

  2. Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals

    Science.gov (United States)

    Tobolkina, Elena A.; Skripnikova, Tatiana A.; Starikova, Anna A.; Shumilova, Galina I.; Pendin, Andrey A.

    2018-01-01

    Demetallation of metalloporphyrin molecules is one of the essential degradation reactions in photosynthesis. The effect of metalloporphyrin nature on removal of central metals from tetraphenylporphyrin complexes based on lanthanide group metals (Dy, Er, Lu, Ho) has been studied. pH values, at which the metal ions leave the metalloporphyrin complex were established using two-phase spectrophotometric titration with potentiometric pH-control. The pH values decrease with the increase of atomic numbers of lanthanide groups, as well as with increase of 4f-electrons. The reaction of an extra ligand exchange for the hydroxide ion was studied. For Dy-, Er- and Ho-tetraphenylporphyrin complexes one particle of extra ligand coordinates with one porphyrin complex. A complex with dimeric particles can be formed for the system of Lu-tetraphenylporphyrin. Constants of the ion exchange reactions were calculated.

  3. A Hybrid Metaheuristic Approach for Minimizing the Total Flow Time in A Flow Shop Sequence Dependent Group Scheduling Problem

    Directory of Open Access Journals (Sweden)

    Antonio Costa

    2014-07-01

    Full Text Available Production processes in Cellular Manufacturing Systems (CMS often involve groups of parts sharing the same technological requirements in terms of tooling and setup. The issue of scheduling such parts through a flow-shop production layout is known as the Flow-Shop Group Scheduling (FSGS problem or, whether setup times are sequence-dependent, the Flow-Shop Sequence-Dependent Group Scheduling (FSDGS problem. This paper addresses the FSDGS issue, proposing a hybrid metaheuristic procedure integrating features from Genetic Algorithms (GAs and Biased Random Sampling (BRS search techniques with the aim of minimizing the total flow time, i.e., the sum of completion times of all jobs. A well-known benchmark of test cases, entailing problems with two, three, and six machines, is employed for both tuning the relevant parameters of the developed procedure and assessing its performances against two metaheuristic algorithms recently presented by literature. The obtained results and a properly arranged ANOVA analysis highlight the superiority of the proposed approach in tackling the scheduling problem under investigation.

  4. Liquid metal magnetohydrodynamic flows in manifolds of dual coolant lead lithium blankets

    Energy Technology Data Exchange (ETDEWEB)

    Mistrangelo, C., E-mail: chiara.mistrangelo@kit.edu; Bühler, L.

    2014-10-15

    Highlights: • MHD flows in model geometries of DCLL blanket manifolds. • Study of velocity, pressure distributions and flow partitioning in parallel ducts. • Flow partitioning affected by 3D MHD pressure drop and velocity distribution in the expanding zone. • Reduced pressure drop in a continuous expansion compared to a sudden expansion. - Abstract: An attractive blanket concept for a fusion reactor is the dual coolant lead lithium (DCLL) blanket where reduced activation steel is used as structural material and a lead lithium alloy serves both to produce tritium and to remove the heat in the breeder zone. Helium is employed to cool the first wall and the blanket structure. Some critical issues for the feasibility of this blanket concept are related to complex induced electric currents and 3D magnetohydrodynamic (MHD) phenomena that occur in distributing and collecting liquid metal manifolds. They can result in large pressure drop and undesirable flow imbalance in parallel poloidal ducts forming blanket modules. In the present paper liquid metal MHD flows are studied for different design options of a DCLL blanket manifold with the aim of identifying possible sources of flow imbalance and to predict velocity and pressure distributions.

  5. Activation analysis for platinum in gold and metals of the platinum group through 199Au

    International Nuclear Information System (INIS)

    Foerster, H.

    1976-01-01

    Platinum was determined in gold and in metals of the platinum group through 199 Au by activation analysis. The matrix was separated at the end of irradiation before the daughter nuclide was formed. Gold was separated by extraction with MIBK from 1

  6. Infrared multiple photon dissociation spectroscopy of group I and group II metal complexes with Boc-hydroxylamine.

    Science.gov (United States)

    Dain, Ryan P; Gresham, Gary; Groenewold, Gary S; Steill, Jeffrey D; Oomens, Jos; Van Stipdonk, Michael J

    2013-08-30

    Hydroxamates are essential growth factors for some microbes, acting primarily as siderophores that solubilize iron for transport into a cell. Here we determined the intrinsic structure of 1:1 complexes between Boc-protected hydroxylamine and group I ([M(L)](+)) and group II ([M(L-H)](+)) cations, where M and L are the cation and ligand, respectively, which are convenient models for the functional unit of hydroxamate siderphores. The relevant complex ions were generated by electrospray ionization (ESI) and isolated and stored in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Infrared spectra of the isolated complexes were collected by monitoring (infrared) photodissociation yield as a function of photon energy. Experimental spectra were then compared to those predicted by density functional theory (DFT) calculations. The infrared multiple photon dissociation (IRMPD) spectra collected are in good agreement with those predicted to be lowest-energy by DFT. The spectra for the group I complexes contain six resolved absorptions that can be attributed to amide I and II type and hydroxylamine N-OH vibrations. Similar absorptions are observed for the group II cation complexes, with shifts of the amide I and amide II vibrations due to the change in structure with deprotonation of the hydroxylamine group. IRMPD spectroscopy unequivocally shows that the intrinsic binding mode for the group I cations involves the O atoms of the amide carbonyl and hydroxylamine groups of Boc-hydroxylamine. A similar binding mode is preferred for the group II cations, except that in this case the metal ion is coordinated by the O atom of the deprotonated hydroxylamine group. Copyright © 2013 John Wiley & Sons, Ltd.

  7. Viscous surface flow induced on Ti-based bulk metallic glass by heavy ion irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Kun [Key Laboratory of Microgravity (National Microgravity Laboratory), Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190 (China); Hu, Zheng [Key Laboratory of Microgravity (National Microgravity Laboratory), Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190 (China); Science and Technology on Vehicle Transmission Laboratory, China North Vehicle Research Institute, Beijing 100072 (China); Li, Fengjiang [Key Laboratory of Microgravity (National Microgravity Laboratory), Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190 (China); Wei, Bingchen, E-mail: weibc@imech.ac.cn [Key Laboratory of Microgravity (National Microgravity Laboratory), Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190 (China)

    2016-12-30

    Highlights: • Obvious smoothing and roughening phases on the Ti-based MG surface resulted, which correspond respectively to the normal and off-normal incidence angles. • Atomic force microscopy confirms two types of periodic ripples distributed evenly over the rough surface. • The irradiation-induced viscosity of MG is about 4×10{sup 12} Pa·s, which accords with the theoretical prediction for metallic glasses close to glass transition temperature. • Surface-confined viscous flow plays a dominant quantitative role, which is due to radiation-induced softening of the low-viscosity surface layer. - Abstract: Ti-based bulk metallic glass was irradiated by a 20 MeV Cl{sup 4+} ion beam under liquid-nitrogen cooling, which produced remarkable surface smoothing and roughening that respectively correspond to normal and off-normal incidence angles of irradiation. Atomic force microscopy confirms two types of periodic ripples distributed evenly over the rough glass surface. In terms of mechanism, irradiation-induced viscosity agrees with the theoretical prediction for metallic glasses near glass transition temperature. Here, a model is introduced, based on relaxation of confined viscous flow with a thin liquid-like layer, that explains both surface smoothing and ripple formation. This study demonstrates that bulk metallic glass has high morphological instability and low viscosity under ion irradiation, which assets can pave new paths for metallic glass applications.

  8. Liquid-metal pin-fin pressure drop by correlation in cross flow

    International Nuclear Information System (INIS)

    Wang, Zhibi; Kuzay, T.M.; Assoufid, L.

    1994-01-01

    The pin-fin configuration is widely used as a heat transfer enhancement method in high-heat-flux applications. Recently, the pin-fin design with liquid-metal coolant was also applied to synchrotron-radiation beamline devices. This paper investigates the pressure drop in a pin-post design beamline mirror with liquid gallium as the coolant. Because the pin-post configuration is a relatively new concept, information in literature about pin-post mirrors or crystals is rare, and information about the pressure drop in pin-post mirrors with liquid metal as the coolant is even more sparse. Due to this the authors considered the cross flow in cylinder-array geometry, which is very similar to that of the pin-post, to examine the pressure drop correlation with liquid metals over pin fins. The cross flow of fluid with various fluid characteristics or properties through a tube bank was studied so that the results can be scaled to the pin-fin geometry with liquid metal as the coolant. Study lead to two major variables to influence the pressure drop: fluid properties, viscosity and density, and the relative length of the posts. Correlation of the pressure drop between long and short posts and the prediction of the pressure drop of liquid metal in the pin-post mirror and comparison with an existing experiment are addressed

  9. Investigation of complexing ability of ionites with various groups to some heavy and transition metal ions

    Directory of Open Access Journals (Sweden)

    Yedil Yergozhin

    2013-05-01

    Full Text Available The physico-chemical and complexing properties of the sorbent based on chloromethylated styrene and divinylbenzene copolymer with nicotinamide groups and copolymers based on metacryloilaminobenzene acids with 2-methyl-5-vinylpyridineisomers are studied. By potentiometric titration method the constant of polyelectrolytes functional groups ionization, the composition and strength of the resulting complexes with ions of some heavy and transition metals are determined.

  10. Measurements of time-dependent liquid-metal magnetohydrodynamic flows in a flat rectangular duct

    International Nuclear Information System (INIS)

    Buehler, L.; Horanyi, S.

    2009-01-01

    In the helium-cooled lead lithium (HCLL) blanket, which has been chosen as a reference concept for a liquid-metal breeding blanket to be tested in ITER, the heat is removed by helium cooled plates aligned with the strong toroidal magnetic field that confines the fusion plasma. The liquid breeder lead lithium circulates through gaps of rectangular cross-section between the cooling plates to transport the generated tritium towards external extraction facilities. Under the action of the strong magnetic field, liquid metal flows in conducting rectangular ducts exhibit jet-like velocity profiles in the thin boundary layers near the side walls, which are parallel to the magnetic field like the cooling plates in HCLL blankets. The velocity in these side layers may exceed several times the mean velocity in the duct and it is known that these layers become unstable for sufficiently high Reynolds numbers. The present paper summarizes experimental results for such unstable time-dependent flows in strong magnetic fields, which have been obtained in the MEKKA liquid metal laboratory of the Forschungszentrum Karlsruhe. In particular, spatial and temporal scales of perturbation patterns are identified. The results suggest that the flow between cooling plates in a HCLL blanket is laminar and stable. The observed time-dependent flow behavior appears at larger velocities so that the present results are more relevant for applications in dual coolant concepts where high-velocity jets have been predicted along side walls.

  11. Effect of functionalization of boron nitride flakes by main group metal clusters on their optoelectronic properties

    Science.gov (United States)

    Chakraborty, Debdutta; Chattaraj, Pratim Kumar

    2017-10-01

    The possibility of functionalizing boron nitride flakes (BNFs) with some selected main group metal clusters, viz. OLi4, NLi5, CLi6, BLI7 and Al12Be, has been analyzed with the aid of density functional theory (DFT) based computations. Thermochemical as well as energetic considerations suggest that all the metal clusters interact with the BNF moiety in a favorable fashion. As a result of functionalization, the static (first) hyperpolarizability (β ) values of the metal cluster supported BNF moieties increase quite significantly as compared to that in the case of pristine BNF. Time dependent DFT analysis reveals that the metal clusters can lower the transition energies associated with the dominant electronic transitions quite significantly thereby enabling the metal cluster supported BNF moieties to exhibit significant non-linear optical activity. Moreover, the studied systems demonstrate broad band absorption capability spanning the UV-visible as well as infra-red domains. Energy decomposition analysis reveals that the electrostatic interactions principally stabilize the metal cluster supported BNF moieties.

  12. Optimization of the uniformity of a metal flow during continuous extrusion by the Conform method

    Science.gov (United States)

    Lyubanova, A. Sh.; Gorokhov, Yu. V.; Solopko, I. V.; Ziborov, A. Yu.

    2010-03-01

    The scheme of plastic deformation of a billet in a container is considered as part of continuous extrusion by the Conform method. A mathematical model of the motion of a viscoplastic Bingham liquid is used to determine the metal velocity distribution in the plastic-deformation zone. As a result, the optimum angle between the longitudinal axes of the die and container is estimated. This angle is found to be one of the main factors affecting the nonuniformity of deformation when a metal flows into the die. The calculated results are compared to experimental data.

  13. Magnetic liquid metal two-phase flow research. Phase 1. Final report

    International Nuclear Information System (INIS)

    Graves, R.D.

    1983-04-01

    The Phase I research demonstrates the feasibility of the magnetic liquid metal (MLM) two-phase flow concept. A dispersion analysis is presented based on a complete set of two-phase-flow equations augmented to include stresses due to magnetic polarization of the fluid. The analysis shows that the stability of the MLM two-phase flow is determined by the magnetic Mach number, the slip ratio, geometry of the flow relative to the applied magnetic field, and by the voidage dependence of the interfacial forces. Results of a set of experiments concerned with magnetic effects on the dynamics of single bubble motion in an aqueous-based, viscous, conducting magnetic fluid are presented. Predictions in the theoretical literature are qualitatively verified using a bench-top experimental apparatus. In particular, applied magnetic fields are seen to lead to reduced bubble size at fixed generating orifice pressure

  14. High-energy redox-flow batteries with hybrid metal foam electrodes.

    Science.gov (United States)

    Park, Min-Sik; Lee, Nam-Jin; Lee, Seung-Wook; Kim, Ki Jae; Oh, Duk-Jin; Kim, Young-Jun

    2014-07-09

    A nonaqueous redox-flow battery employing [Co(bpy)3](+/2+) and [Fe(bpy)3](2+/3+) redox couples is proposed for use in large-scale energy-storage applications. We successfully demonstrate a redox-flow battery with a practical operating voltage of over 2.1 V and an energy efficiency of 85% through a rational cell design. By utilizing carbon-coated Ni-FeCrAl and Cu metal foam electrodes, the electrochemical reactivity and stability of the nonaqueous redox-flow battery can be considerably enhanced. Our approach intoduces a more efficient conversion of chemical energy into electrical energy and enhances long-term cell durability. The cell exhibits an outstanding cyclic performance of more than 300 cycles without any significant loss of energy efficiency. Considering the increasing demands for efficient energy storage, our achievement provides insight into a possible development pathway for nonaqueous redox-flow batteries with high energy densities.

  15. Inductive flow meter for measuring the speed of flow and gas volume contained in a flow of liquid metal

    International Nuclear Information System (INIS)

    Mueller, S.

    1980-01-01

    The speed of flow of the sodium is measured in two closely adjacent flow crossections using pairs of electrodes in the field of two disc-shaped permanent magnets made of AlNiCo 450, by means of measurements of running time of speed fluctuations. The result of the measurement is independent of the temperature of the sensor and the temperature of the sodium. The same arrangement makes it possible to determine the proportion by volume of the fission gas in sodium with a limiting freequency of several kHz. (DG) [de

  16. Numerical Simulation of Multiphase Magnetohydrodynamic Flow and Deformation of Electrolyte-Metal Interface in Aluminum Electrolysis Cells

    Science.gov (United States)

    Hua, Jinsong; Rudshaug, Magne; Droste, Christian; Jorgensen, Robert; Giskeodegard, Nils-Haavard

    2018-06-01

    A computational fluid dynamics based multiphase magnetohydrodynamic (MHD) flow model for simulating the melt flow and bath-metal interface deformation in realistic aluminum reduction cells is presented. The model accounts for the complex physics of the MHD problem in aluminum reduction cells by coupling two immiscible fluids, electromagnetic field, Lorentz force, flow turbulence, and complex cell geometry with large length scale. Especially, the deformation of bath-metal interface is tracked directly in the simulation, and the condition of constant anode-cathode distance (ACD) is maintained by moving anode bottom dynamically with the deforming bath-metal interface. The metal pad deformation and melt flow predicted by the current model are compared to the predictions using a simplified model where the bath-metal interface is assumed flat. The effects of the induced electric current due to fluid flow and the magnetic field due to the interior cell current on the metal pad deformation and melt flow are investigated. The presented model extends the conventional simplified box model by including detailed cell geometry such as the ledge profile and all channels (side, central, and cross-channels). The simulations show the model sensitivity to different side ledge profiles and the cross-channel width by comparing the predicted melt flow and metal pad heaving. In addition, the model dependencies upon the reduction cell operation conditions such as ACD, current distribution on cathode surface and open/closed channel top, are discussed.

  17. Regulation of the flow rate of liquid-metal coolants on experimental stands

    International Nuclear Information System (INIS)

    Kozlov, F.A.; Laptev, G.I.

    1988-01-01

    Systems for automatic regulation of the flow rate of alkali metals, based on the series ENIV, VIN, and TsLIN three-phase electromagnetic pumps with a pumping rate of 0.5-200 m 3 per hour, were evaluated. The stability of each system was investigated by the method of undamped oscillations. The possibility of employing the analog temperature regulators VRT-2, RPA-T, and R113 was assessed. The functions performed by the most suitable automatic regulation unit, the RPA-T, were described. The limiting period of flow rate oscillations with a maximum gain of the RPA-T in alkali metal regulation systems equaled about 0.5 sec and the minimum integration time of the RPA-T was an order of magnitude longer than the optimal interval. Use of the systems on experimental stands enabled raising the quality of the studies and expanding the zone of servicing of the facilities by the same personnel

  18. Decoding flow unit evolution upon annealing from fracture morphology in metallic glasses

    Energy Technology Data Exchange (ETDEWEB)

    Gao, M., E-mail: gaomeng10@hotmail.com; Cao, X.F.; Ding, D.W.; Wang, B.B.; Wang, W.H., E-mail: whw@iphy.ac.cn

    2017-02-16

    The intrinsic correlation between the fracture morphology evolution and the structural heterogeneity of flow units in a typical Zr{sub 52.5}Ti{sub 5}Cu{sub 17.9}Ni{sub 14.6}Al{sub 10} (vit105) metallic glass (MG) upon annealing was investigated. By systematically tuning the annealing time at temperature below the glass transition temperature, a series of dimple-like fracture morphology were obtained, which is the unique fingerprint-like pattern for every annealing state. Based on the structural relaxation model of flow units, the evolution of the typical dimple sizes, the largest and smallest dimple size, with annealing were well fitted. Then the evolution of flow unit density was estimated from the fracture morphology evolution, which displays the same evolution trend with that measured from thermal relaxation. A stochastic dynamic model considering the interaction of activated flow units was proposed to analyze the effect of the initial flow unit density and the flow unit interaction intensity on the dynamic evolution of dimple distribution. Our work may provide a novel scheme to investigate the structural fingerprint information on flow units from fracture morphology, and enlighten the microscopic structural origin of the ductile-to-brittle transition during structural relaxation in MGs.

  19. Dynamic Flow-through Methods for Metal Fractionation in Environmental Solid Samples

    DEFF Research Database (Denmark)

    Miró, Manuel; Hansen, Elo Harald; Petersen, Roongrat

    occurring processes always take place under dynamic conditions, recent trends have been focused on the development of alternative flow-through dynamic methods aimed at mimicking environmental events more correctly than their classical extraction counterparts. In this lecture particular emphasis is paid......Accummulation of metal ions in different compartments of the biosphere and their possible mobilization under changing environmental conditions induce a pertubation of the ecosystem and may cause adverse health effects. Nowadays, it is widely recognized that the information on total content...... the ecotoxicological significance of metal ions in solid environmental samples. The background of end-over-end fractionation for releasing metal species bound to particular soil phases is initially discussed, its relevant features and limitations being thoroughly described. However, taking into account that naturally...

  20. Electromagnetic device for confining a liquid metal and regulating the flow rate

    International Nuclear Information System (INIS)

    Garnier, Marcel; Moreau, R.J.

    1977-01-01

    The description is given of a device for confining a liquid metal jet, characterized in that it comprises in combination, at the jet outlet nozzle, (a) means for producing a high pressure in the jet composed of a coil around the nozzle and located on its outlet, in combination with facilities for passing a high frequency alternating current through the coil and (b) means for suppressing this high pressure. It is stated that this device has many uses, particularly for allowing the use of a relatively large diameter orifice, hence not subject to the risk of clogging, in order to produce a jet with a relatively small diameter. This invention particularly concerns the application of this device for regulating a flow of liquid metal at an outlet orifice located at the lower end of a receptacle containing this liquid metal [fr

  1. Research on geometrical model and mechanism for metal deformation based on plastic flow

    International Nuclear Information System (INIS)

    An, H P; Li, X; Rui, Z Y

    2015-01-01

    Starting with general conditions of metal plastic deformation, it analyses the relation between the percentage spread and geometric parameters of a forming body with typical machining process are studied. A geometrical model of deforming metal is set up according to the characteristic of a flowing metal particle. Starting from experimental results, the effect of technological parameters and friction between workpiece and dies on plastic deformation of a material were studied and a slippage deformation model of mass points within the material was proposed. Finally, the computing methods for strain and deformation energy and temperature rise are derived from homogeneous deformation. The results can be used to select technical parameters and compute physical quantities such as strain, deformation energy, and temperature rise. (paper)

  2. Supramolecular assembly of group 11 phosphorescent metal complexes for chemosensors of alcohol derivatives

    Science.gov (United States)

    Lintang, H. O.; Ghazalli, N. F.; Yuliati, L.

    2018-04-01

    We report on systematic study on vapochromic sensing of ethanol by using phosphorescent trinuclear metal pyrazolate complexes with supramolecular assembly of weak intermolecular metal-metal interactions using 4-(3,5-dimethoxybenzyl)-3,5-dimethyl pyrazole ligand (1) and group 11 metal ions (Cu(I), Ag(I), Au(I)). Upon excitation at 284, the resulting complexes showed emission bands with a peak centered at 616, 473 and 612 nm for 2(Cu), 2(Ag) and 2(Au), respectively. Chemosensor 2(Cu) showed positive response to ethanol vapors in 5 mins by blue-shifting its emission band from 616 to 555 nm and emitting bright orange to green. Otherwise 2(Au) gave shifting from its emission band centered at 612 to 587 nm with Δλ of 25 nm (41%) and color changes from red-orange to light green-orange while 2(Ag) showed quenching in its original emission intensity at 473 nm in 40% with color changes from dark green to less emissive. These results demonstrate that sensing capability of chemosensor 2(Cu) with suitable molecular design of ligand and metal ion in the complex is due to the formation of a weak intermolecular hydrogen bonding interaction of O atom at the methoxy of the benzyl ring with the OH of the vapors at the outside of the molecules.

  3. Preparation and Characterization of Styrene Bearing Diethanolamine Side Group, Styrene Copolymer Systems, and Their Metal Complexes

    Directory of Open Access Journals (Sweden)

    Aslışah Açıkses

    2018-01-01

    Full Text Available The two copolymer systems of styrene bearing diethanol amine side group and styrene were prepared by free radical polymerization method at 60°C in presence of 1,4-dioxane as solvent and AIBN as initiator. Their metal complexes were prepared by reaction of the copolymer used as ligand P(DEAMSt-co-StL′′ and Ni(II and Co(II metal ions, which was carried out in presence of ethanol and NaOH at 65°C for 48 h in pH = 7.5. The structures of the copolymers used as ligand and metal complexes were identified by FT-IR, 1H-NMR spectra, and elemental analysis. The properties of the copolymers used as ligand and metal complexes were characterized by SEM-EDX, AAS, DSC, TGA, and DTA techniques. Then, the electrical properties of the copolymers and metal complexes were examined as a function of the temperature and frequency, and the activation energies (Ea were estimated with conductivity measurements.

  4. Report on generation IV technical working group 3 : liquid metal reactors

    International Nuclear Information System (INIS)

    Lineberry, M. J.; Rosen, S. L.; Sagayama, Y.

    2002-01-01

    This paper reports on the first round of R and D roadmap activities of the Generation IV (Gen IV) Technical Working Group (TWG) 3, on liquid metal-cooled reactors. Liquid metal coolants give rise to fast spectrum systems, and thus the reactor systems considered in this TWG are all fast reactors. Gas-cooled fast reactors are considered in the context of TWG 2. As is noted in other Gen IV papers, this first round activity is termed ''screening for potential'', and includes collecting the most complete set of liquid metal reactor/fuel cycle system concepts possible and evaluating the concepts against the Gen IV principles and goals. Those concepts or concept groups that meet the Gen IV principles and which are deemed to have reasonable potential to meet the Gen IV goals will pass to the next round of evaluation. Although we sometimes use the terms ''reactor'' or ''reactor system'' by themselves, the scope of the investigation by TWG 3 includes not only the reactor systems, but very importantly the closed fuel recycle system inevitably required by fast reactors. The response to the DOE Request for Information (RFI) on liquid metal reactor/fuel cycle systems from principal investigators, laboratories, corporations, and other institutions, was robust and gratifying. Thirty three liquid metal concept descriptions, from eight different countries, were ultimately received. The variation in the scope, depth, and completeness of the responses created a significant challenge for the group, but the TWG made a very significant effort not to screen out concepts early in the process

  5. A study of new rare-earth metal group-13 chalcohalides. Structures, chemistry, and optical properties

    International Nuclear Information System (INIS)

    Dorhout, P.K.; Van Calcar, P.M.

    1998-01-01

    Full text: Several new quaternary compounds from the rare-earth metal group-13 chalcohalide family have been prepared from alkaline earth halide flux reactions of binary and elemental starting materials. One compound, for example, Ca 2 La 6G a 2 S 1 4 , crystallizes as needles in an hexagonal cell while another, more disordered structure, La 11 Ga 19 Cl 6 S 42 , crystallizes as monoclinic plates. The former is a condensed structure with channels that contain the alkaline earth element while the latter forms a layered structure containing rare-earth halide clusters within interlayer galleries. These compounds are new members of a family of rare-earth metal main-group chalcogenides which show promise as electroluminescent materials. Structural and spectroscopic studies of these and related compounds will be discussed

  6. Fluid Flow and Mixing Induced by AC Continuous Electrowetting of Liquid Metal Droplet

    Directory of Open Access Journals (Sweden)

    Qingming Hu

    2017-04-01

    Full Text Available In this work, we proposed a novel design of a microfluidic mixer utilizing the amplified Marangoni chaotic advection induced by alternating current (AC continuous electrowetting of a metal droplet situated in electrolyte solution, due to the linear and quadratic voltage-dependence of flow velocity at small or large voltages, respectively. Unlike previous researchers exploiting the unidirectional surface stress with direct current (DC bias at droplet/medium interface for pumping of electrolytes where the resulting flow rate is linearly proportional to the field intensity, dominance of another kind of dipolar flow pattern caused by local Marangoni stress at the drop surface in a sufficiently intense AC electric field is demonstrated by both theoretical analysis and experimental observation, which exhibits a quadratic growth trend as a function of the applied voltage. The dipolar shear stress merely appears at larger voltages and greatly enhances the mixing performance by inducing chaotic advection between the neighboring laminar flow. The mixer design developed herein, on the basis of amplified Marangoni chaotic advection around a liquid metal droplet at larger AC voltages, has great potential for chemical reaction and microelectromechanical systems (MEMS actuator applications because of generating high-throughput and excellent mixing performance at the same time.

  7. Computer Tomography 3-D Imaging of the Metal Deformation Flow Path in Friction Stir Welding

    Science.gov (United States)

    Schneider, Judy; Beshears, Ronald; Nunes, Arthur C., Jr.

    2004-01-01

    In friction stir welding, a rotating threaded pin tool is inserted into a weld seam and literally stirs the edges of the seam together. This solid-state technique has been successfully used in the joining of materials that are difficult to fusion weld such as aluminum alloys. To determine optimal processing parameters for producing a defect free weld, a better understanding of the resulting metal deformation flow path is required. Marker studies are the principal method of studying the metal deformation flow path around the FSW pin tool. In our study, we have used computed tomography (CT) scans to reveal the flow pattern of a lead wire embedded in a FSW weld seam. At the welding temperature of aluminum, the lead becomes molten and thus tracks the aluminum deformation flow paths in a unique 3-dimensional manner. CT scanning is a convenient and comprehensive way of collecting and displaying tracer data. It marks an advance over previous more tedious and ambiguous radiographic/metallographic data collection methods.

  8. Point dipole as a magnetic obstacle in liquid metal duct flow

    Science.gov (United States)

    Tympel, Saskia; Boeck, Thomas; Krasnov, Dmitry; Schumacher, Jörg

    2011-11-01

    Lorentz force velocimetry is a new contactless technique to measure the velocities of hot and agressive conductiong liquids. The measurement of the Lorentz force on the magnet is highly sensitive to the velocity profile that is influenced by the magnetic field. Thus the knowlegde of the flow transformation and the influence of an inhomogeneous local magnetic field on liquid metal flow is essential for obtaining velocity information from the measured forces. We consider liquid metal flow in a square duct with electrically insulating walls under the influence of a magnetic point dipole using three-dimensional direct numerical simulations with a finite-difference method. The dipole acts as a magnetic obstacle. A wide range of parameters affects the created wake. In this canonical setting, we study the modification of the flow for different Hartmann and Reynolds numbers. We observe a strong dependence of the magnetic obstacle effect and the corresponding Lorentz force on the orientation of the dipole as well as on its position. The authors acknowledge the support of the Deutsche Forschungsgemeinschaft.

  9. Performance analysis of a membrane humidifier containing porous metal foam as flow distributor in a PEM fuel cell system

    International Nuclear Information System (INIS)

    Afshari, Ebrahim; Baharlou Houreh, Nasser

    2014-01-01

    Highlights: • Three metal foam configurations for the membrane humidifier are introduced. • The performances of the humidifiers containing metal foam are investigated. • A 3D CFD model is developed to compare the introduced humidifiers with one another. • Using metal foam at dry side has no positive effect on the humidifier performance. - Abstract: Using metal foam as flow distributor in membrane humidifier for proton exchange membrane (PEM) fuel cell system has some unique characteristics like more water transfer, low manufacturing complexity and low cost compared to the conventional flow channel plate. Metal foam can be applied at wet side or dry side or both sides of a humidifier. The three-dimensional CFD models are developed to investigate the performance of the above mentioned meanwhile compare them with the conventional humidifier. This model consists of a set of coupled equations including conservations of mass, momentum, species and energy for all regions of the humidifier. The results indicate that with the metal foam installed at wet side and both sides, water recovery ratio and dew point at dry side outlet are more than that of the conventional humidifier, indicating a better humidifier performance; while using metal foam at dry side has no positive effect on humidifier performance. At dry side mass flow rates higher than 10 mgr/s pressure drop in humidifier containing metal foam at wet side is lower than that of the conventional humidifier. As the mass flow rate increases from 9 to 15 mgr/s humidifier containing metal foam at wet side has better performance, while at mass flow rates lower than 9 mgr/s, the humidifier containing metal foam at both sides has better performance. At dry side inlet temperatures lower than 303 K, humidifier containing metal foam at wet side has better performance and at temperatures higher than 303 K, humidifier containing metal foam at both sides has better performance

  10. Automated installation for atomic emission determination of gold, silver and platinum group metals

    International Nuclear Information System (INIS)

    Zayakina, S.B.; Anoshin, G.N.; Gerasimov, P.A.; Smirnov, A.V.

    1999-01-01

    An automated installation for the direct atomic emission determination of silver, gold and platinum-group metals (Ru) in geological and geochemical materials with software for automated data acquisition and handling is designed and developed. The installation consists of a DFS-458 diffraction spectrograph, a MAES-10 multichannel analyzer of emission spectra, and a dual-jet plasmatron. A library of spectral lines of almost all elements excited in the dual-jet plasmatron is complied [ru

  11. Metal release behavior of surface oxidized stainless steels into flowing high temperature pure water

    International Nuclear Information System (INIS)

    Fujiwara, Kazuo; Tomari, Haruo; Nakayama, Takenori; Shimogori, Kazutoshi; Ishigure, Kenkichi; Matsuura, Chihiro; Fujita, Norihiko; Ono, Shoichi.

    1987-01-01

    In order to clarify the effect of oxidation treatment of Type 304 SS on the inhibition of metal release into high temperature pure water, metal release rate of individual alloying element into flowing deionized water containing 50 ppb dissolved oxygen was measured as the function of exposure time on representative specimens oxidized in air and steam. The behavior of metal release was also discussed in relation to the structure of surface films. Among the alloying elements the amount of Fe ion, Cr ion and Fe crud in high temperature pure water tended to saturate with the exposure time and that of Ni ion and Co ion tended to increase monotonously with the exposure time for all specimens tested. And the treatment of steam-oxidation was the most effective to decrease the metal release of alloying elements and the treatment by air-oxidation also decreased the metal release. These tendencies were confirmed to correlate well with the structure of the surface films as it was in the results in the static autoclave test. (author)

  12. Performance model of metallic concentric tube recuperator with counter flow arrangement

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Harshdeep [HIET, Department of Mechanical Engineering, Ghaziabad, Uttar Pradesh (India); Kumar, Anoop; Goel, Varun [NIT, Department of Mechanical Engineering, Hamirpur, Himachal Pradesh (India)

    2010-03-15

    A performance model for counter flow arrangement in concentric tube recuperator that can be used to utilize the waste heat in the temperature range of 900-1,400 C is presented. The arrangement consists of metallic tubular inner and outer concentric shell with a small annular gap between two concentric shells. Flue gases pass through the inner shell while air passes through the annular gap in the reverse direction (counter flow arrangement). The height of the recuperator is divided into elements and an energy balance is performed on each elemental height. Results give necessary information about surface, gas and air temperature distribution, and the influence of operating conditions on recuperator performance. The recuperative effectiveness is found to be increased with increasing inlet gas temperature and decreased with increasing fuel flow rate. The present model accounts for all heat transfer processes pertinent to a counterflow radiation recuperator and provide a valuable tool for performance considerations. (orig.)

  13. Liquid-metal flow in a rectangular duct with a non-uniform magnetic field

    International Nuclear Information System (INIS)

    Walker, J.S.

    1986-04-01

    This paper treats liquid-metal flow in rectangular ducts with thin conducting walls. A transverse magnetic field changes from a uniform strength upstream to a weaker uniform strength downstream. The Hartmann number and the interaction parameter are assumed to be large, while the magnetic Reynolds number is assumed to be small. If the magnetic field changes gradually over a long duct length, the velocity and pressure are nearly uniform in each cross section and the flow differs slightly from locally fully developed flow. If the magnetic field changes more abruptly over a shorter duct length, the velocity and pressure are much larger near the walls parallel to the magnetic field than in the central part of duct. Solutions for the pressure drops due to the magnetic field change are presented

  14. Visualization of two-phase flow in metallic pipes using neutron radiographic technique

    International Nuclear Information System (INIS)

    Luiz, L.C.; Crispim, V.R.

    2007-01-01

    The study of two-phase flow is a matter of great interest both for the engineering and oil industries. The production of oil and natural gas involves the transportation of fluids in their liquid and gaseous states, respectively, to the processing plant for refinement. The forecasting of two-phase flow in oil pipes is of the utmost important yet an extremely difficult task. With the development of the electronic imaging system, installed in J-9 irradiation channel of the IEN/CNEN Argonauta Reactor, it is possible to visualize the different types of two phase air-water flows in small-diameter metallic pipes. After developing the captured image the liquid-gas drift flux correlation as well as the void fraction in relation to the injected air outflow for a fixed water outflow can be obtained. (author)

  15. An investigation of flow properties of metal matrix composites suspensions for injection molding

    International Nuclear Information System (INIS)

    Ahmad, F.; Bevis, M.J.

    1997-01-01

    Flow properties of metal matrix composites suspensions have significant effects on the fibre orientation during mould filling. The results presented in this paper relate to the flow properties of aluminium powder and glass fibres compounded into a sacrificial thermoplastics binder. For this purpose, a range of aluminium compounds and aluminium composite suspensions were investigated over a wide shear rate range expected to occur during injection mould process. Aluminium composites wee prepared by substituting glass fibres for aluminium in aluminium compound. Aluminium composite containing a maximum critical volume fraction of fibres which did not exhibit an increase n viscosity was determined. The effect of temperature on the flow behaviour of aluminium composite was also investigated. (author)

  16. Scale-invariant feature extraction of neural network and renormalization group flow

    Science.gov (United States)

    Iso, Satoshi; Shiba, Shotaro; Yokoo, Sumito

    2018-05-01

    Theoretical understanding of how a deep neural network (DNN) extracts features from input images is still unclear, but it is widely believed that the extraction is performed hierarchically through a process of coarse graining. It reminds us of the basic renormalization group (RG) concept in statistical physics. In order to explore possible relations between DNN and RG, we use the restricted Boltzmann machine (RBM) applied to an Ising model and construct a flow of model parameters (in particular, temperature) generated by the RBM. We show that the unsupervised RBM trained by spin configurations at various temperatures from T =0 to T =6 generates a flow along which the temperature approaches the critical value Tc=2.2 7 . This behavior is the opposite of the typical RG flow of the Ising model. By analyzing various properties of the weight matrices of the trained RBM, we discuss why it flows towards Tc and how the RBM learns to extract features of spin configurations.

  17. Renormalization-group flow of the effective action of cosmological large-scale structures

    CERN Document Server

    Floerchinger, Stefan

    2017-01-01

    Following an approach of Matarrese and Pietroni, we derive the functional renormalization group (RG) flow of the effective action of cosmological large-scale structures. Perturbative solutions of this RG flow equation are shown to be consistent with standard cosmological perturbation theory. Non-perturbative approximate solutions can be obtained by truncating the a priori infinite set of possible effective actions to a finite subspace. Using for the truncated effective action a form dictated by dissipative fluid dynamics, we derive RG flow equations for the scale dependence of the effective viscosity and sound velocity of non-interacting dark matter, and we solve them numerically. Physically, the effective viscosity and sound velocity account for the interactions of long-wavelength fluctuations with the spectrum of smaller-scale perturbations. We find that the RG flow exhibits an attractor behaviour in the IR that significantly reduces the dependence of the effective viscosity and sound velocity on the input ...

  18. Carbide-forming groups IVB-VIB metals: a new territory in the periodic table for CVD growth of graphene.

    Science.gov (United States)

    Zou, Zhiyu; Fu, Lei; Song, Xiuju; Zhang, Yanfeng; Liu, Zhongfan

    2014-07-09

    Early transition metals, especially groups IVB-VIB metals, can form stable carbides, which are known to exhibit excellent "noble-metal-like" catalytic activities. We demonstrate herein the applications of groups IVB-VIB metals in graphene growth using atmospheric pressure chemical vapor deposition technique. Similar to the extensively studied Cu, Ni, and noble metals, these transition-metal foils facilitate the catalytic growth of single- to few-layer graphene. The most attractive advantage over the existing catalysts is their perfect control of layer thickness and uniformity with highly flexible experimental conditions by in situ converting the dissolved carbons into stable carbides to fully suppress the upward segregation/precipitation effect. The growth performance of graphene on these transition metals can be well explained by the periodic physicochemical properties of elements. Our work has disclosed a new territory of catalysts in the periodic table for graphene growth and is expected to trigger more interest in graphene research.

  19. Synthesis of methyl acetate from dimethyl ether using group VIII metal salts of phosphotungstic acid

    Energy Technology Data Exchange (ETDEWEB)

    Sardesai, A.; Lee, S.; Tartamella, T.

    2002-04-01

    Dimethyl ether (DME) can be produced much more efficiently in a single-stage, liquid-phase process from natural gas-based syngas as compared to the conventional process via dehydration of methanol. This process, based on dual catalysts slurried in inert oil, alleviates the chemical equilibrium limitation governing the methanol synthesis reaction and concurrently improves per-pass syngas conversion and reactor productivity. The potential, therefore, for production of methyl acetate via dimethyl ether carbonylation is of industrial importance. In the present study, conversion of dimethyl ether and carbon monoxide to methyl acetate is investigated over a variety of group VIII metal-substituted phosphotungstic acid salts. Experimental results of this catalytic reaction using rhodium, iridium, ruthenium, and palladium catalysts are evaluated and compared in terms of selectivity toward methyl acetate. The effects of active metal, support types, multiple metal loading, and feed conditions on carbonylation activity of DME are examined. Iridium metal substituted phosphotungstic acid supported on Davisil type 643 (pore size 150 A, surface area 279 m{sup 2}/g, mesh size 230-425) silica gel shows the highest activity for DME carbonylation. (author)

  20. Removal of platinum group metals contained in molten glass using copper

    International Nuclear Information System (INIS)

    Uruga, Kazuyoshi; Sawada, Kayo; Arita, Yuji; Enokida, Youichi; Yamamoto, Ichiro

    2007-01-01

    Removal of platinum group metals (PGMs) such as Pd, Ru, and RuO 2 from molten glass by using various amounts of liquid Cu was done as a basic study on a new vitrification process for a high-level radio-active waste. We prepared two types of borosilicate glasses containing PGMs and Cu, respectively. These glasses were mixed together and heated at 1,473 K for 4h in Ar atmosphere. More than 95% of Pd were removed as a spherical metal button composed of Pd-Cu alloy when Cu was added in an amount 0.5 times the weight of Pd. Nearly 95% of Ru was also removed as a spherical button with 2.5-5 times as much Cu addition as Ru in weight. Ruthenium oxide was reduced to metallic Ru by a reaction with Cu in the molten glass. The removal fraction was increased by increasing the amount of Cu and reached 63% when Cu addition was 7.5 times as much as RuO 2 in weight. By addition of Si as a reducing agent, nearly 90% of Pd and Ru were removed with Cu and Si metal composites even under O 2 :Ar=20:80 (v/v) condition. (author)

  1. WITNESSING GAS MIXING IN THE METAL DISTRIBUTION OF THE HICKSON COMPACT GROUP HCG 31

    International Nuclear Information System (INIS)

    Torres-Flores, S.; Alfaro-Cuello, M.; De Oliveira, C. Mendes; Amram, P.; Carrasco, E. R.; De Mello, D. F.

    2015-01-01

    We present for the first time direct evidence that in a merger of disk galaxies, the pre-existing central metallicities will mix as a result of gas being transported in the merger interface region along the line that joins the two coalescing nuclei. This is shown using detailed two-dimensional kinematics as well as metallicity measurements for the nearby ongoing merger in the center of the compact group HCG 31. We focus on the emission line gas, which is extensive in the system. The two coalescing cores display similar oxygen abundances. While in between the two nuclei, the metallicity changes smoothly from one nucleus to the other indicating a mix of metals in this region, which is confirmed by the high-resolution Hα kinematics (R = 45,900). This nearby system is especially important because it involves the merging of two fairly low-mass and clumpy galaxies (LMC-like galaxies), making it an important system for comparison with high-redshift galaxies

  2. WITNESSING GAS MIXING IN THE METAL DISTRIBUTION OF THE HICKSON COMPACT GROUP HCG 31

    Energy Technology Data Exchange (ETDEWEB)

    Torres-Flores, S.; Alfaro-Cuello, M. [Departamento de Física, Universidad de La Serena, Av. Cisternas 1200, La Serena (Chile); De Oliveira, C. Mendes [Instituto de Astronomia, Geofísica e Ciências Atmosféricas da Universidade de São Paulo, Cidade Universitária, CEP:05508-900, São Paulo, SP (Brazil); Amram, P. [Aix Marseille Université, CNRS, LAM (Laboratoire d' Astrophysique de Marseille) UMR 7326, F-13388, Marseille (France); Carrasco, E. R. [Gemini Observatory/AURA, Southern Operations Center, Casilla 603, La Serena (Chile); De Mello, D. F., E-mail: storres@dfuls.cl [Catholic University of America, Washington, DC 20064 (United States)

    2015-01-01

    We present for the first time direct evidence that in a merger of disk galaxies, the pre-existing central metallicities will mix as a result of gas being transported in the merger interface region along the line that joins the two coalescing nuclei. This is shown using detailed two-dimensional kinematics as well as metallicity measurements for the nearby ongoing merger in the center of the compact group HCG 31. We focus on the emission line gas, which is extensive in the system. The two coalescing cores display similar oxygen abundances. While in between the two nuclei, the metallicity changes smoothly from one nucleus to the other indicating a mix of metals in this region, which is confirmed by the high-resolution Hα kinematics (R = 45,900). This nearby system is especially important because it involves the merging of two fairly low-mass and clumpy galaxies (LMC-like galaxies), making it an important system for comparison with high-redshift galaxies.

  3. Influences of viscous losses and end effects on liquid metal flow in electromagnetic pumps

    International Nuclear Information System (INIS)

    Kim, Hee Reyoung; Seo, Joon Ho; Hong, Sang Hee; Cho, Su won; Nam, Ho Yun; Cho, Man

    1996-01-01

    Analyses of the viscous and end effects on electromagnetic (EM) pumps of annular linear induction type for the sodium coolant circulation in Liquid Metal Fast Breeder Reactors have been carried out based on the MHD laminar flow analysis and the electromagnetic field theory. A one-dimensional MHD analysis for the liquid metal flowing through an annular channel has been performed on the basis of a simplified model of equivalent current sheets instead of three-phase currents in the discrete primary windings. The calculations show that the developed pressure difference resulted from electromagnetic and viscous forces in the liquid metal is expressed in terms of the slip, and that the viscous loss effects are negligible compared with electromagnetic driving forces except in the low-slip region where the pumps operate with very high flow velocities comparable with the synchronous velocity of the electromagnetic fields, which is not applicable to the practical EM pumps. A two-dimensional electromagnetic field analysis based on an equivalent current sheet model has found the vector potentials in closed form by means of the Fourier transform method. The resultant magnetic fields and driving forces exerted on the liquid metal reveal that the end effects due to finiteness of the pump length are formidable. In addition, a two-dimensional numerical analysis for vector potentials has been performed by the SOR iterative method on a realistic EM pump model with discretely-distributed currents in the primary windings. The numerical computations for the distributions of magnetic fields and developed pressure differences along the pump axial length also show considerable end effects at both inlet and outlet ends, especially at high flow velocities. Calculations of each magnetic force contribution indicate that the end effects are originated from the magnetic force caused by the induced current (υxB) generated by the liquid metal movement across the magnetic field rather than the one

  4. Metal flow of a tailor-welded blank in deep drawing process

    Science.gov (United States)

    Yan, Qi; Guo, Ruiquan

    2005-01-01

    Tailor welded blanks were used in the automotive industry to consolidate parts, reduce weight, and increase safety. In recent years, this technology was developing rapidly in China. In Chinese car models, tailor welded blanks had been applied in a lot of automobile parts such as rail, door inner, bumper, floor panel, etc. Concerns on the properties of tailor welded blanks had become more and more important for automobile industry. A lot of research had shown that the strength of the welded seam was higher than that of the base metal, such that the weld failure in the aspect of strength was not a critical issue. However, formability of tailor welded blanks in the stamping process was complex. Among them, the metal flow of tailor welded blanks in the stamping process must be investigated thoroughly in order to reduce the scrap rate during the stamping process in automobile factories. In this paper, the behavior of metal flow for tailor welded blanks made by the laser welding process with two types of different thickness combinations were studied in the deep drawing process. Simulations and experiment verification of the movement of weld line for tailor welded blanks were discussed in detail. Results showed that the control on the movement of welded seam during stamping process by taking some measures in the aspect of blank holder was effective.

  5. Effects of flow regime and flooding on heavy metal availability in sediment and soil of a dynamic river system

    NARCIS (Netherlands)

    Poot, A.; Gillissen, F.; Koelmans, A.A.

    2007-01-01

    The acid volatile sulphide (AVS) and simultaneously extracted metals (¿SEM) method is increasingly used for risk assessment of toxic metals. In this study, we assessed spatial and temporal variations of AVS and ¿SEM in river sediments and floodplain soils, addressing influence of flow regime and

  6. Synthesis of Hydrophilic Sulfur-Containing Adsorbents for Noble Metals Having Thiocarbonyl Group Based on a Methacrylate Bearing Dithiocarbonate Moieties

    Directory of Open Access Journals (Sweden)

    Haruki Kinemuchi

    2018-01-01

    Full Text Available Novel hydrophilic sulfur-containing adsorbents for noble metals were prepared by the radical terpolymerization of a methacrylate bearing dithiocarbonate moieties (DTCMMA, hydrophilic monomers, and a cross-linker. The resulting adsorbents efficiently and selectively adsorbed noble metals (Au, Ag, and Pd from various multielement aqueous solutions at room temperature owing to the thiocarbonyl group having high affinity toward noble metals. The metal adsorption by the adsorbents was proceeded by simple mixing followed by filtration. The noble metal selectivity of the adsorbent obtained from DTCMMA and N-isopropylacrylamide was higher than that of the adsorbent obtained from DTCMMA and N,N-dimethylacrylamide due to the lower nonspecific adsorption.

  7. Highly Fluorescent Group 13 Metal Complexes with Cyclic, Aromatic Hydroxamic Acid Ligands

    Energy Technology Data Exchange (ETDEWEB)

    Seitz, Michael; Moore, Evan G.; Raymond, Kenneth N.

    2008-02-11

    The neutral complexes of two ligands based on the 1-oxo-2-hydroxy-isoquinoline (1,2-HOIQO) motif with group 13 metals (Al, Ga, In) show bright blue-violet luminescence in organic solvents. The corresponding transition can be attributed to ligand-centered singlet emission, characterized by a small Stokes shifts of only a few nm combined with lifetimes in the range between 1-3 ns. The fluorescence efficiency is high, with quantum yields of up to 37% in benzene solution. The crystal structure of one of the indium(III) complexes (trigonal space group R-3, a = b = 13.0384(15) {angstrom}, c = 32.870(8) {angstrom}, ? = {beta} = 90{sup o}, {gamma} = 120{sup o}, V = 4839.3(14) {angstrom}{sup 3}, Z = 6) shows a six-coordinate geometry around the indium center which is close to trigonal-prismatic, with a twist angle between the two trigonal faces of 20.7{sup o}. Time-dependent density functional theory (TD-DFT) calculations (Al and Ga: B3LYP/6-31G(d)); In: B3LYP/LANL2DZ of the fac and mer isomers with one of the two ligands indicate that there is no clear preference for either one of the isomeric forms of the metal complexes. In addition, the metal centers do not have a significant influence on the electronic structure, and as a consequence, on the predominant intraligand optical transitions.

  8. Cycloadditions to Epoxides Catalyzed by GroupIII-V Transition-Metal Complexes

    KAUST Repository

    D'Elia, Valerio

    2015-05-25

    Complexes of groupIII-V transition metals are gaining increasing importance as Lewis acid catalysts for the cycloaddition of dipolarophiles to epoxides. This review examines the latest reports, including homogeneous and heterogeneous applications. The pivotal step for the cycloaddition reactions is the ring opening of the epoxide following activation by the Lewis acid. Two modes of cleavage (C-C versus C-O) have been identified depending primarily on the substitution pattern of the epoxide, with lesser influence observed from the Lewis acid employed. The widely studied cycloaddition of CO2 to epoxides to afford cyclic carbonates (C-O bond cleavage) has been scrutinized in terms of catalytic efficiency and reaction mechanism, showing that unsophisticated complexes of groupIII-V transition metals are excellent molecular catalysts. These metals have been incorporated, as well, in highly performing, recyclable heterogeneous catalysts. Cycloadditions to epoxides with other dipolarophiles (alkynes, imines, indoles) have been conducted with scandium triflate with remarkable performances (C-C bond cleavage). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Cycloadditions to Epoxides Catalyzed by GroupIII-V Transition-Metal Complexes

    KAUST Repository

    D'Elia, Valerio; Pelletier, Jeremie; Basset, Jean-Marie

    2015-01-01

    Complexes of groupIII-V transition metals are gaining increasing importance as Lewis acid catalysts for the cycloaddition of dipolarophiles to epoxides. This review examines the latest reports, including homogeneous and heterogeneous applications. The pivotal step for the cycloaddition reactions is the ring opening of the epoxide following activation by the Lewis acid. Two modes of cleavage (C-C versus C-O) have been identified depending primarily on the substitution pattern of the epoxide, with lesser influence observed from the Lewis acid employed. The widely studied cycloaddition of CO2 to epoxides to afford cyclic carbonates (C-O bond cleavage) has been scrutinized in terms of catalytic efficiency and reaction mechanism, showing that unsophisticated complexes of groupIII-V transition metals are excellent molecular catalysts. These metals have been incorporated, as well, in highly performing, recyclable heterogeneous catalysts. Cycloadditions to epoxides with other dipolarophiles (alkynes, imines, indoles) have been conducted with scandium triflate with remarkable performances (C-C bond cleavage). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Homogeneous viscous flow behavior of a Cu–Zr based bulk metallic glass composites

    International Nuclear Information System (INIS)

    Zhang, X.Y.; Yuan, Z.Z.; Feng, X.L.; Cui, L.Z.; Li, D.X.

    2015-01-01

    In this paper, Cu 40 Zr 44 Ag 8 Al 8 bulk metallic glass composites (BMGCs) consisting of various volume fraction of nanocrystals embedded in the amorphous matrix was synthesized by controlled annealing treatment of an as-cast BMGCs. The high temperature compression behaviors of the BMGCs were characterized in the supercooled liquid region. Results show that the flow stresses keep increasing after an initial decrease with extension of the annealing time. With annealing the values of activation volume V act is determined to be increasing from 283.6216 Ǻ 3 to 305.553 Ǻ 3 , suggesting that the jump of atoms is a cooperative process during the high-temperature deformation. Flow behavior of the BMGCs annealed for less than 8 min transform from Newtonian to non-Newtonian dependant on the stain rate and can be successively fitted by the visco-plasticity model. Fitting results indicate that deformation behaviors of these samples are governed by homogeneous flow of the amorphous matrix and indeed determined by the viscosities in the Newtonian flow stage. However, the BMGCs annealed for 8 min exhibit a non-Newtonian flow over the entire compression process and fail to be fitted by the visco-plasticity model. Micrographs of the sample reflect an impinged structure, indicating that high temperature deformation behavior of the BMGCs with high volume fractions of particles is indeed controlled by that of a backbone of particles

  11. Effect of thermodiffusion on the fluid flow, heat transfer, and solidification of molten metal alloys

    Directory of Open Access Journals (Sweden)

    E. Jafar-Salehi

    2016-03-01

    Full Text Available In this paper, a transient Finite Element (FE method has been employed to solve the transport equations to investigate the heat transfer and fluid flow and the effect of thermodiffusion on vertical solidification of a binary molten metal alloy, forming a rod. The binary system considered in this study is SnBi composed of 65% Sn and 35% Bi subjected to bottom cooling. It is found that the flow of molten metal at the boundary of the mushy region plays an important role in the shape and geometry of the zone. The presence of thermodiffusion shows considerable difference in the composition of the solidified rod, compared with the one without considering the effect of thermodiffusion. Thermodiffusion also causes a faster solidification and a more uniform concentration distribution. The results of this study may be extended to similar binary and multicomponent systems in which a temperature gradient exists and the Soret coefficient is large enough so as to affect the fluid flow and concentration of the species.

  12. Numerical simulation of turbulent liquid metal flows in plane channels and annuli

    International Nuclear Information System (INIS)

    Groetzbach, G.

    1980-06-01

    The method of direct numerical simulation is used to study heat transfer and statistical data for fully developed turbulent liquid metal flows in plane channels and annuli. Subgrid scale models using one transport equation account for the high wave-number turbulence not resolved by the finite difference grid. A special subgrid-scale heat flux model is deduced together with an approximative theory to calculate all model coefficients. This model can be applied on the total Peclet number range of technical liquid metal flows. Especially it can be used for very small Peclet numbers, where the results are independent on model parameters. A verification of the numerical results for liquid sodium and mercury flows is undertaken by the Nusselt number in plane channels and radial temperature and eddy conductivity profiles for annuli. The numerically determined Nusselt numbers for annuli indicate that many empirical correlations overestimate the influence of the ratio of radii. The numerical results for the eddy conductivity profiles may be used to remove these problems. The statistical properties of the simulated temperature fluctuations are within the wide scatter-band of experimental data. The numerical results give reasonable heat flux correlation coefficients which depend only weakly on the problem marking parameters. (orig.) [de

  13. Non-Newtonian plastic flow of a Ni-Si-B metallic glass at low stresses

    International Nuclear Information System (INIS)

    Csach, K.; Fursova, Y.V.; Khonik, V.A.; Ocelik, V.

    1998-01-01

    The problem of the rheological behavior of metallic glasses (MGs) is quite important both from theoretical and practical viewpoints. Early experiments carried out on MGs at temperatures T > 300 K using low shear stress levels revealed plastic flow to be Newtonian while measurements at relative high shear stresses (more than 200 to 400 MPa, depending on temperature, thermal prehistory of samples and chemical composition) indicated a non-linear behavior with 1 < m < 12. Numerous investigations performed later both on as-cast and relaxed MGs of various chemical compositions using a number of testing methods (tensile creep, tensile and bend stress relaxation) showed that a transition from Newtonian behavior at low stresses to a non-linear flow at high stresses was observed. At present, such a situation is considered to be generally accepted. The authors performed precise creep measurements of a Ni-Si-B metallic glass. The results obtained indicate that plastic flow in this case at low tensile stress (12 le σ le 307 MPa) is clearly non-Newtonian and, consequently, the viscosity is stress dependent

  14. Determination of platinum group metals by ICP-AES in environmental samples after preconcentration

    International Nuclear Information System (INIS)

    Vlasankova, R.; Sommer, L.

    1999-01-01

    Platinum group metal (PGM) may have toxic properties and their presence in the environment represent danger for human health. With the introduction of automobile catalytic converters containing PGM, the emission of these noble metals into atmosphere has increased. Platinum, palladium and rhodium are used in this catalytic converters to decrease toxic emissions of carbon monoxide, unburnt hydrocarbons and nitrogen oxides in vehicles exhaust gases. These catalysts are mobile sources of PGM into the environment. Thus, increased platinum concentrations have been found in various objects of environment because of the massive introduction of such catalytic converters are present. The preconcentration and separation of PGM and their determination by ICP-AES in environmental samples are described

  15. Release of metal ions from fixed orthodontic appliance: an in vitro study in continuous flow system.

    Science.gov (United States)

    Mikulewicz, Marcin; Chojnacka, Katarzyna; Wołowiec, Paulina

    2014-01-01

    To evaluate the release of metal ions from fixed orthodontic appliances. A new system for in vitro testing of dental materials was constructed and consisted of a thermostatic glass reactor that enabled immersion of the studied material. Experimental conditions reflected the human oral cavity, with a temperature of 37°C and a saliva flow rate of 0.5mL/min. The simulated fixed orthodontic appliance made of stainless steel was evaluated. Sampling was performed at several time points during the 28-day study, and the metal ion concentration was determined by inductively coupled plasma optical emission spectrometry. The total mass of released metal ions from the appliance during 4 weeks of the experiment was as follows nickel 18.7 μg, chromium 5.47 μg, copper 31.3 μg. The estimated doses of nickel, chromium, and copper determined by extrapolation of experimental data released during the treatment period were far below the toxic dose to humans. This shows that orthodontic treatment might not be a significant source of exposure to these metal ions.

  16. Risk analysis on heavy metal contamination in sediments of rivers flowing into Nansi Lake.

    Science.gov (United States)

    Cao, Qingqing; Song, Ying; Zhang, Yiran; Wang, Renqing; Liu, Jian

    2017-12-01

    In order to understand the risk of heavy metals in sediments of the rivers flowing into Nansi Lake, 36 surface sediments were sampled from six rivers and seven heavy metals (Cr, Cu, Ni, Zn, As, Pb, and Cd) were determined. Potential ecological risk index (RI) of the six rivers showed significant differences: Xinxue River, Jiehe River, and Guangfu River were at medium potential risk, whereas the risk of Chengguo River was the lowest. Jiehe River, Xuesha River, and Jiangji River were meeting the medium potential risk at river mouths. Geo-accumulation index (I geo ) of the seven heavy metals revealed that the contamination of Cu and Cd was more serious than most other metals in the studied areas, whereas Cr in most sites of our study was not polluted. Moreover, correlation cluster analysis demonstrated that the contamination of Cu, Ni, and Zn in six rivers was mainly caused by local emissions, whereas that of As, Pb, and Cd might come from the external inputs in different forms. Consequently, the contamination of Cu and Cd and the potential risk in Xinxue River, Jiehe River, and Guangfu River as well as the local emissions should be given more attention to safeguard the water quality of Nansi Lake and the East Route Project of South to North Water Transfer.

  17. Freezing controlled penetration of molten metals flowing through stainless steel tubes

    International Nuclear Information System (INIS)

    Sienicki, J.J.; Spencer, B.W.; Vetter, D.L.; Wesel, R.H.

    1985-01-01

    The freezing controlled penetration potential of molten metals flowing within stainless steel structure is important to the safety assessment of hypothetical severe accidents in liquid metal reactors. A series of scoping experiments has been performed in which molten stainless steel and nickel at various initial temperatures and driving pressures were injected downward and upward into 6.4 and 3.3 mm ID stainless steel tubes filled with argon gas and initially at room temperature. In all tests, there was no evidence that the solid tube wall was wetted by the molten metals. The penetration phenomena are markedly different for downward versus upward injections. The dependency upon tube orientation is explained in terms of the absence of wetting. Complete plugs were formed in all experiments halting the continued injection of melt. Calculations with a fluid dynamics/heat transfer computer code show that the injected masses limited by plugging are consistent with freezing through the growth of a stable solidified layer (crust) of metal upon the solid tube wall. 23 refs., 5 figs., 2 tabs

  18. One-group interfacial area transport in vertical air-water bubbly flow

    International Nuclear Information System (INIS)

    Wu, Q.; Kim, S.; Ishii, M.; Beus, S.G.

    1997-01-01

    In the two-fluid model for two-phase flows, interfacial area concentration is one of the most important closure relations that should be obtained from careful mechanistic modeling. The objective of this study is to develop a one-group interfacial area transport equation together with the modeling of the source and sink terms due to bubble breakage and coalescence. For bubble coalescence, two mechanisms are considered to be dominant in vertical two-phase bubbly flow. These are the random collisions between bubbles due to turbulence in the flow field, and the wake entrainment process due to the relative motion of the bubbles in the wake region of a seeding bubble. For bubble breakup, the impact of turbulent eddies is considered. These phenomena are modeled individually, resulting in a one-group interfacial area concentration transport equation with certain parameters to be determined from experimental data. Compared to the measured axial distribution of the interfacial area concentration under various flow conditions, these parameters are obtained for the reduced one-group, one-dimensional transport equation. The results indicate that the proposed models for bubble breakup and coalescence are appropriate

  19. MHD and heat transfer benchmark problems for liquid metal flow in rectangular ducts

    International Nuclear Information System (INIS)

    Sidorenkov, S.I.; Hua, T.Q.; Araseki, H.

    1994-01-01

    Liquid metal cooling systems of a self-cooled blanket in a tokamak reactor will likely include channels of rectangular cross section where liquid metal is circulated in the presence of strong magnetic fields. MHD pressure drop, velocity distribution and heat transfer characteristics are important issues in the engineering design considerations. Computer codes for the reliable solution of three-dimensional MHD flow problems are needed for fusion relevant conditions. Argonne National Laboratory and The Efremov Institute have jointly defined several benchmark problems for code validation. The problems, described in this paper, are based on two series of rectangular duct experiments conducted at ANL; one of the series is a joint ANL/Efremov experiment. The geometries consist of variation of aspect ratio and wall thickness (thus wall conductance ratio). The transverse magnetic fields are uniform and nonuniform in the axial direction

  20. Overview of flow studies for recycling metal commodities in the United States

    Science.gov (United States)

    Sibley, Scott F.

    2011-01-01

    Metal supply consists of primary material from a mining operation and secondary material, which is composed of new and old scrap. Recycling, which is the use of secondary material, can contribute significantly to metal production, sometimes accounting for more than 50 percent of raw material supply. From 2001 to 2011, U.S. Geological Survey (USGS) scientists studied 26 metals to ascertain the status and magnitude of their recycling industries. The results were published in chapters A-Z of USGS Circular 1196, entitled, "Flow Studies for Recycling Metal Commodities in the United States." These metals were aluminum (chapter W), antimony (Q), beryllium (P), cadmium (O), chromium (C), cobalt (M), columbium (niobium) (I), copper (X), germanium (V), gold (A), iron and steel (G), lead (F), magnesium (E), manganese (H), mercury (U), molybdenum (L), nickel (Z), platinum (B), selenium (T), silver (N), tantalum (J), tin (K), titanium (Y), tungsten (R), vanadium (S), and zinc (D). Each metal commodity was assigned to a single year: chapters A-M have recycling data for 1998; chapters N-R and U-W have data for 2000, and chapters S, T, and X-Z have data for 2004. This 27th chapter of Circular 1196 is called AA; it includes salient data from each study described in chapters A-Z, along with an analysis of overall trends of metals recycling in the United States during 1998 through 2004 and additional up-to-date reviews of selected metal recycling industries from 1991 through 2008. In the United States for these metals in 1998, 2000, and 2004 (each metal commodity assigned to a single year), 84 million metric tons (Mt) of old scrap was generated. Unrecovered old scrap totaled 43 Mt (about 51 percent of old scrap generated, OSG), old scrap consumed was 38 Mt (about 45 percent of OSG), and net old scrap exports were 3.3 Mt (about 4 percent of OSG). Therefore, there was significant potential for increased recovery from scrap. The total old scrap supply was 88 Mt, and the overall new

  1. Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks

    Science.gov (United States)

    Rubio-Martinez, Marta; Batten, Michael P.; Polyzos, Anastasios; Carey, Keri-Constanti; Mardel, James I.; Lim, Kok-Seng; Hill, Matthew R.

    2014-01-01

    Further deployment of Metal-Organic Frameworks in applied settings requires their ready preparation at scale. Expansion of typical batch processes can lead to unsuccessful or low quality synthesis for some systems. Here we report how continuous flow chemistry can be adapted as a versatile route to a range of MOFs, by emulating conditions of lab-scale batch synthesis. This delivers ready synthesis of three different MOFs, with surface areas that closely match theoretical maxima, with production rates of 60 g/h at extremely high space-time yields. PMID:24962145

  2. Liquid metal flow in a large-radius elbow with a uniform magnetic fluid

    International Nuclear Information System (INIS)

    Moon, T.J.; Walker, J.S.

    1988-07-01

    This paper treats the liquid-metal flow in an elbow between two straight, rectangular ducts. There is a uniform magnetic field in the plane of the elbow. The duct has thin, electrically conducting walls. The Hartmann number and the interaction parameter are assumed to be large, while the magnetic Reynolds number is assumed to be small. Solutions for the velocity at each cross section of the elbow and for the pressure drop due to three-dimensional effects are presented. 10 refs., 5 figs

  3. Atomistic Origin of Rate-Dependent Serrated Plastic Flow in Metallic Glasses

    Directory of Open Access Journals (Sweden)

    Yao YG

    2008-01-01

    Full Text Available Abstract Nanoindentation simulations on a binary metallic glass were performed under various strain rates by using molecular dynamics. The rate-dependent serrated plastic flow was clearly observed, and the spatiotemporal behavior of its underlying irreversible atomic rearrangement was probed. Our findings clearly validate that the serration is a temporally inhomogeneous characteristic of such rearrangements and not directly dependent on the resultant shear-banding spatiality. The unique spatiotemporal distribution of shear banding during nanoindentation is highlighted in terms of the potential energy landscape (PEL theory.

  4. Understanding hydrogen sorption in a metal-organic framework with open-metal sites and amide functional groups

    KAUST Repository

    Pham, Tony T.

    2013-05-09

    Grand canonical Monte Carlo (GCMC) studies of the mechanism of hydrogen sorption in an rht-MOF known as Cu-TPBTM are presented. The MOF is a decorated/substituted isostructural analogue to the unembellished rht-MOF, PCN-61, that was studied previously [ Forrest, K. A.J. Phys. Chem. C 2012, 116, 15538-15549. ]. The simulations were performed using three different hydrogen potentials of increasing complexity. Simulated hydrogen sorption isotherms and calculated isosteric heat of adsorption, Qst, values were in excellent agreement with the reported experimental data for only a polarizable model in one of four experimentally observed crystal structure configurations. The study demonstrates the ability of modeling to distinguish the differential sorption of distinct strucures; one configuration is found to be dominant due to favorable interactions with substrates. In addition, it was discovered that the presence of polar amide groups had a significant effect on the electrostatics of the Cu2+ ions and directs the low-pressure physisorption of hydrogen in the MOF. This is in contrast to what was observed in PCN-61, where an exterior copper ion had a higher relative charge and was the favored loading site. This tunability of the electrostatics of the copper ions via chemical substitution on the MOF framework can be explained by the presence of the negatively charged oxygen atom of the amide group that causes the interior Cu2+ ion to exhibit a higher positive charge through an inductive effect. Further, control simulations, taking advantage of the flexibility afforded by theoretical modeling, include artificially modified charges for both Cu2+ ions chosen equal to or with a higher charge on the exterior Cu2+ ion. This choice resulted in distinctly different hydrogen sorption characteristics in Cu-TPBTM with no direct sorption on the open-metal sites. Thus, this study demonstrates both the tunable nature of MOF platforms and the possibility for rational design of sorption

  5. Semicontinuity of 4d N=2 spectrum under renormalization group flow

    International Nuclear Information System (INIS)

    Xie, Dan; Yau, Shing-Tung

    2016-01-01

    We study renormalization group flow of four dimensional N=2 SCFTs defined by isolated hypersurface three-fold singularities. We define the spectrum of N=2 theory as the set of scaling dimensions of the parameters on the Coulomb branch, which include Coulomb branch moduli, mass parameters and coupling constants. We prove that the spectrum of those theories is semicontinous under the RG flow on the Coulomb branch using the mathematical result about the singularity spectra under deformation. The semicontinuity behavior of N=2 spectrum implies a theorem under relevant and Coulomb branch moduli deformation, the absence of dangerous irrelevant deformations and can be taken as the necessary condition for the ending point of a RG flow. This behavior is also true for (c,c) ring deformation of two dimensional Landau-Ginzburg model with (2,2) supersymmetry.

  6. Continuous-Flow Monolithic Silica Microreactors with Arenesulphonic Acid Groups: Structure–Catalytic Activity Relationships

    Directory of Open Access Journals (Sweden)

    Agnieszka Ciemięga

    2017-08-01

    Full Text Available The performance of monolithic silica microreactors activated with sulphonic acid groups and a packed bed reactor with Amberlyst 15 resin were compared in the esterification of acetic acid with n-butanol. The monolithic microreactors were made of single silica rods with complex pore architecture, differing in the size of mesopores, and in particular, flow-through macropores which significantly affected the flow characteristic of the continuous system. The highest ester productivity of 105.2 mol·molH+−1·h−1 was achieved in microreactor M1 with the largest porosity, characterized by a total pore volume of 4 cm3·g−1, mesopores with 20 nm diameter, and large flow-through macropores 30–50 μm in size. The strong impact of the permeability of the monoliths on a reaction kinetics was shown.

  7. Tensile flow stress of ceramic particle-reinforced metal in the presence of particle cracking

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, R. [Ecole Polytechnique Federale de Lausanne (EPFL), Laboratory for Mechanical Metallurgy, CH-1015 Lausanne (Switzerland); Rossoll, A. [Ecole Polytechnique Federale de Lausanne (EPFL), Laboratory for Mechanical Metallurgy, CH-1015 Lausanne (Switzerland)], E-mail: andreas.rossoll@epfl.ch; Weber, L. [Ecole Polytechnique Federale de Lausanne (EPFL), Laboratory for Mechanical Metallurgy, CH-1015 Lausanne (Switzerland); Bourke, M.A.M. [Los Alamos National Laboratory (LANL), LANSCE-12, P.O. Box 1663, MS H805, Los Alamos, NM 87545 (United States); Dunand, D.C. [Northwestern University, Department of Materials Science and Engineering, Evanston, IL 60208 (United States); Mortensen, A. [Ecole Polytechnique Federale de Lausanne (EPFL), Laboratory for Mechanical Metallurgy, CH-1015 Lausanne (Switzerland)

    2008-10-15

    A simplified model is proposed to quantify the effect of damage in the form of particle cracking on the elastic and plastic behaviour of particle-reinforced metal matrix composites under uniaxial tensile loading: cracked particles are simply replaced, in a mean-field model, with as much matrix. Pure aluminium reinforced with 44 vol.% alumina particles, tested in tension and unloaded at periodic plastic deformations, is analysed by neutron diffraction during each reloading elastic step, at 30%, 50%, 70% and 90% of the tensile flow stress. The data give the evolution of the elastic matrix strains in the composite and also measure the progress of internal damage by particle cracking. The test gives (i) the evolution of the in situ matrix flow stress, and (ii) the evolution of load partitioning during elastic deformation with increasing composite damage. Predictions of the present model compare favourably with relevant results in the literature, and with results from the present neutron diffraction experiments.

  8. Amplification of hot electron flow by the surface plasmon effect on metal–insulator–metal nanodiodes

    International Nuclear Information System (INIS)

    Lee, Changhwan; Nedrygailov, Ievgen I; Keun Lee, Young; Lee, Hyosun; Young Park, Jeong; Ahn, Changui; Jeon, Seokwoo

    2015-01-01

    Au–TiO_2–Ti nanodiodes with a metal–insulator–metal structure were used to probe hot electron flows generated upon photon absorption. Hot electrons, generated when light is absorbed in the Au electrode of the nanodiode, can travel across the TiO_2, leading to a photocurrent. Here, we demonstrate amplification of the hot electron flow by (1) localized surface plasmon resonance on plasmonic nanostructures fabricated by annealing the Au–TiO_2–Ti nanodiodes, and (2) reducing the thickness of the TiO_2. We show a correlation between changes in the morphology of the Au electrodes caused by annealing and amplification of the photocurrent. Based on the exponential dependence of the photocurrent on TiO_2 thickness, the transport mechanism for the hot electrons across the nanodiodes is proposed. (paper)

  9. Tensile flow stress of ceramic particle-reinforced metal in the presence of particle cracking

    International Nuclear Information System (INIS)

    Mueller, R.; Rossoll, A.; Weber, L.; Bourke, M.A.M.; Dunand, D.C.; Mortensen, A.

    2008-01-01

    A simplified model is proposed to quantify the effect of damage in the form of particle cracking on the elastic and plastic behaviour of particle-reinforced metal matrix composites under uniaxial tensile loading: cracked particles are simply replaced, in a mean-field model, with as much matrix. Pure aluminium reinforced with 44 vol.% alumina particles, tested in tension and unloaded at periodic plastic deformations, is analysed by neutron diffraction during each reloading elastic step, at 30%, 50%, 70% and 90% of the tensile flow stress. The data give the evolution of the elastic matrix strains in the composite and also measure the progress of internal damage by particle cracking. The test gives (i) the evolution of the in situ matrix flow stress, and (ii) the evolution of load partitioning during elastic deformation with increasing composite damage. Predictions of the present model compare favourably with relevant results in the literature, and with results from the present neutron diffraction experiments

  10. Electron momentum spectroscopy of the group I and Il metal and oxides

    International Nuclear Information System (INIS)

    Ford, M.J.; Dorsett, H.E.; Sashin, V.A.; Bolorizadeh, M.A.; Mikajlo, E.A.; Soule de Bas, B.; Nixon, K.L.; Coleman, V.A.

    2002-01-01

    Full text: The group I and Il metals and oxides are relatively simple condensed phase systems that are easily accessible to theoretical studies. For this reason they have been the subject of a number of studies using a range of theoretical techniques. Calculated electronic band structures have traditionally been compared with optical, X-ray and photo emissions measurements. While these techniques provide excellent data for testing theoretical predictions they generally probe certain aspects of the electronic structure, such as special point energies or densities of states, or require considerable theoretical input for their interpretation. In this paper we present our electron momentum spectroscopy (EMS) measurements for the lighter group Il metals and oxides and group I oxides. EMS can measure directly the full band dispersions and intensities and provides a sensitive test of theoretical predictions. We compare our measurements with Hartree-Fock (HF) and density functional theory (DFT) calculations carried out within the linear combination of atomic orbitals approximation. As expected HF significantly overestimates the bandwidths and bandgaps. DFT gives reasonable overall agreement, albeit with slight overestimation of bandwidths for the oxides. The intensity distribution for the oxides show a systematic difference from all the calculations which cannot easily be explained by experimental effects such as multiple scattering in the target. This work was funded by the Australian Research Council and Flinders University. EA Mikajlo and K L Nixon acknowledge receipt of SENRAC and Ferry scholarships respectively

  11. Investigation of heat transfer in liquid-metal flows under fusion-reactor conditions

    Energy Technology Data Exchange (ETDEWEB)

    Poddubnyi, I. I., E-mail: poddubnyyii@nikiet.ru [Joint Stock Company Dollezhal Research and Development Institute of Power Engineering (JSC NIKIET) (Russian Federation); Pyatnitskaya, N. Yu.; Razuvanov, N. G.; Sviridov, V. G.; Sviridov, E. V. [Russian Academy of Science, Joint Institute of High Temperatures (Russian Federation); Leshukov, A. Yu. [Joint Stock Company Dollezhal Research and Development Institute of Power Engineering (JSC NIKIET) (Russian Federation); Aleskovskiy, K. V. [National Research University Moscow Power Engineering Institute (MPEI) (Russian Federation); Obukhov, D. M. [Joint Stock Company Efremov Institute of Electrophysical Apparatus (Russian Federation)

    2016-12-15

    The effect discovered in studying a downward liquid-metal flow in vertical pipe and in a channel of rectangular cross section in, respectively, a transverse and a coplanar magnetic field is analyzed. In test blanket modules (TBM), which are prototypes of a blanket for a demonstration fusion reactor (DEMO) and which are intended for experimental investigations at the International Thermonuclear Experimental Reactor (ITER), liquid metals are assumed to fulfil simultaneously the functions of (i) a tritium breeder, (ii) a coolant, and (iii) neutron moderator and multiplier. This approach to testing experimentally design solutions is motivated by plans to employ, in the majority of the currently developed DEMO blanket projects, liquid metals pumped through pipes and/or rectangular channels in a transvers magnetic field. At the present time, experiments that would directly simulate liquid-metal flows under conditions of ITER TBM and/or DEMO blanket operation (irradiation with thermonuclear neutrons, a cyclic temperature regime, and a magnetic-field strength of about 4 to 10 T) are not implementable for want of equipment that could reproduce simultaneously the aforementioned effects exerted by thermonuclear plasmas. This is the reason why use is made of an iterative approach to experimentally estimating the performance of design solutions for liquid-metal channels via simulating one or simultaneously two of the aforementioned factors. Therefore, the investigations reported in the present article are of considerable topical interest. The respective experiments were performed on the basis of the mercury magneto hydrodynamic (MHD) loop that is included in the structure of the MPEI—JIHT MHD experimental facility. Temperature fields were measured under conditions of two- and one-sided heating, and data on averaged-temperature fields, distributions of the wall temperature, and statistical fluctuation features were obtained. A substantial effect of counter thermo gravitational

  12. Behaviour of heavy metals during the thermal conversion of sawdust in an entrained flow reactor

    Energy Technology Data Exchange (ETDEWEB)

    Klensch, S.; Reimert, R. [Engler-Bunte-Inst., Bereich Gas, Erdoel und Kohle, Univ. Karlsruhe, Karlsruhe (Germany)

    1999-07-01

    Since its utilization is nearly CO{sub 2}-neutral, biomass represents a major alternative energy carrier in comparison with fossil fuels in CO{sub 2} reduction scenarios frequently discussed. Decentral generation of power and heat in medium sized plants could develop as a preferred application in future. During thermal conversion (gasification and combustion) of biomass the inorganic matter including the heavy metals will be found in the solid residues, i. e. slags and ashes, and in very low concentrations in the product gas (fuel or flue gas). The ashes should be returned to the forests and the agricultural areas respectively to avoid the use of industrial fertilizers. However, for this purpose the heavy metal concentrations of ashes may not exceed specific limit values, otherwise the returned ashes can lead to harmful effects on the ecological system. In awareness of this problem, in Austria some limit values for the concentrations of Cd, Cr, Cu, Ni, Pb and Zn in returned ashes are valid since 1997. No danger for the environment can be expected by slags containing heavy metals. The heavy metals are fixed environmentally neutral in the glass matrix as has been proven for coal and for residue gasification many times. Dividing the total of the residues into such two streams (returned ash and slag) avoids the disposal of the ashes. The heavy metal behaviour during the thermal conversion of sawdust was investigated in a bench scale plant. In essence, the plant consists of an entrained flow reactor (length of reaction zone: 2,500 mm; inner diameter: 70 mm) and a candle barrier filter with 6 rigid ceramic filter elements (DIA-Schumalith 10-20). The biomass flow rate is as high as 6 kg/h and the operating pressure is about 0.12 MPa. Experimental results show the influences of the conversion temperature (1100 - 1300 C), of the dedusting temperature (350 - 800 C), and of the gas atmosphere (reducing, oxidising) on the heavy metal concentrations of the slag and of the fly

  13. Identification of dominant flow structures in rapidly rotating convection of liquid metals using Dynamic Mode Decomposition

    Science.gov (United States)

    Horn, S.; Schmid, P. J.; Aurnou, J. M.

    2016-12-01

    The Earth's metal core acts as a dynamo whose efficiency in generating and maintaining the magnetic field is essentially determined by the rotation rate and the convective motions occurring in its outer liquid part. For the description of the primary physics in the outer core the idealized system of rotating Rayleigh-Bénard convection is often invoked, with the majority of studies considering only working fluids with Prandtl numbers of Pr ≳ 1. However, liquid metals are characterized by distinctly smaller Prandtl numbers which in turn result in an inherently different type of convection. Here, we will present results from direct numerical simulations of rapidly rotating convection in a fluid with Pr ≈ 0.025 in cylindrical containers and Ekman numbers as low as 5 × 10-6. In this system, the Coriolis force is the source of two types of inertial modes, the so-called wall modes, that also exist at moderate Prandtl numbers, and cylinder-filling oscillatory modes, that are a unique feature of small Prandtl number convection. The obtained flow fields were analyzed using the Dynamic Mode Decomposition (DMD). This technique allows to extract and identify the structures that govern the dynamics of the system as well as their corresponding frequencies. We have investigated both the regime where the flow is purely oscillatory and the regime where wall modes and oscillatory modes co-exist. In the purely oscillatory regime, high and low frequency oscillatory modes characterize the flow. When both types of modes are present, the DMD reveals that the wall-attached modes dominate the flow dynamics. They precess with a relatively low frequency in retrograde direction. Nonetheless, also in this case, high frequency oscillations have a significant contribution.

  14. Room-Temperature Synthesis of Transition Metal Clusters and Main Group Polycations from Ionic Liquids

    OpenAIRE

    Ahmed, Ejaz

    2011-01-01

    Main group polycations and transition metal clusters had traditionally been synthesized via high-temperature routes by performing reactions in melts or by CTR, at room-temperature or lower temperature by using so-called superacid solvents, and at room-temperature in benzene–GaX3 media. Considering the major problems associated with higher temperature routes (e.g. long annealing time, risk of product decomposition, and low yield) and taking into account the toxicity of benzene and liquid SO2 i...

  15. Surface layers in the 4A group metals with implanted silicon ions

    International Nuclear Information System (INIS)

    Kovneristyj, Yu.K.; Vavilova, V.V.; Krasnopevtsev, V.V.; Galkin, L.N.; Kudyshev, A.N.; Klechkovskaya, V.V.

    1987-01-01

    A study was made on the change of structure and phase composition of fine near the surface layers of 4A group metals (Hf, Zr, Ti) during ion Si implantation and successive thermal annealing at elevated temperatures. Implantation of Si + ions with 30 or 16 keV energy in Ti, Zr and Hf at room temperature results to amorphization of metal surface layer. The surface hafnium and titanium layer with implanted Si atoms due to interaction with residual atmosphere of oxygen turns during annealing at 870 K to amorphous solid solution of HfO 2m or TiO 2 with Si, preventing further metal oxidation; layers of amorphous alloy are characterized by thermal stability up to 1270 K. Oxidation of the surface amorphous layer in residual oxygen atmosphere and its crystallization in ZrO 2 take place in result of Zr annealing with implanted Si ions at temperature not exceeding 870 K. Similar phenomena are observed in the case of hafnium with implanted oxygen ions or small dose of silicon ions. Thermal stability of amorphous layers produced during ion implantation of Si in Ti, Zr and Hf corresponds to scale resistance of monolithic alloys in Ti-Si, Zr-Si and Hf-Si systems

  16. Analysis of heavy metal flow in the river Przemsza, Katowice region, using macrophytes

    Energy Technology Data Exchange (ETDEWEB)

    Lewander, M.

    1995-06-01

    The river Przemsza, in southern Poland, was investigated with the aim to determine the flow of Cd, Pb and Zn between the submerged macrophytes Potamogeton pectinatus and Myriophyllum verticillatum, sediment and water, and to find out if a pollution gradient was present along the investigated part of the river. In order to determine the uptake of heavy metals from water and sediment macrophytes were planted in pots along the river, in unpolluted and polluted sediment during six weeks in the summer of 1993. After harvesting the plants were dried, wet digested and analysed by atomic absorption spectrophotometry. Parallel in situ experiments and outdoor experiments in sealed jars were performed. No significant decreased pollution gradient in the sediment or the macrophytes content could be detected. However, the water concentration of Zn decreased slightly along the gradient and in both experiments Pb concentration in the water also decreased. The concentrations of metals in the plants and sediments were probably depending on local stream conditions as well as increasing organic content. The study suggests that the macrophytes took up metals both from water and sediment. The unpolluted sediment accumulated Pb and Zn in both experiments, while Cd was accumulated in the in situ experiment. Metal concentration in the polluted sediment decreased during the study period, either due to plant uptake or loss to the water. Metals lost from the polluted sediment to the water were taken up by the plant shoots. Lead mainly accumulated in the roots while Zn accumulated in the plant shoots, and Cd was distributed almost equally between shoots and roots. 18 refs, 2 figs, 6 tabs

  17. Holography as a highly efficient renormalization group flow. I. Rephrasing gravity

    Science.gov (United States)

    Behr, Nicolas; Kuperstein, Stanislav; Mukhopadhyay, Ayan

    2016-07-01

    We investigate how the holographic correspondence can be reformulated as a generalization of Wilsonian renormalization group (RG) flow in a strongly interacting large-N quantum field theory. We first define a highly efficient RG flow as one in which the Ward identities related to local conservation of energy, momentum and charges preserve the same form at each scale. To achieve this, it is necessary to redefine the background metric and external sources at each scale as functionals of the effective single-trace operators. These redefinitions also absorb the contributions of the multitrace operators to these effective Ward identities. Thus, the background metric and external sources become effectively dynamical, reproducing the dual classical gravity equations in one higher dimension. Here, we focus on reconstructing the pure gravity sector as a highly efficient RG flow of the energy-momentum tensor operator, leaving the explicit constructive field theory approach for generating such RG flows to the second part of the work. We show that special symmetries of the highly efficient RG flows carry information through which we can decode the gauge fixing of bulk diffeomorphisms in the corresponding gravity equations. We also show that the highly efficient RG flow which reproduces a given classical gravity theory in a given gauge is unique provided the endpoint can be transformed to a nonrelativistic fixed point with a finite number of parameters under a universal rescaling. The results obtained here are used in the second part of this work, where we do an explicit field-theoretic construction of the RG flow and obtain the dual classical gravity theory.

  18. Ideal flow theory for the double - shearing model as a basis for metal forming design

    Science.gov (United States)

    Alexandrov, S.; Trung, N. T.

    2018-02-01

    In the case of Tresca’ solids (i.e. solids obeying the Tresca yield criterion and its associated flow rule) ideal flows have been defined elsewhere as solenoidal smooth deformations in which an eigenvector field associated everywhere with the greatest principal stress (and strain rate) is fixed in the material. Under such conditions all material elements undergo paths of minimum plastic work, a condition which is often advantageous for metal forming processes. Therefore, the ideal flow theory is used as the basis of a procedure for the preliminary design of such processes. The present paper extends the theory of stationary planar ideal flow to pressure dependent materials obeying the double shearing model and the double slip and rotation model. It is shown that the original problem of plasticity reduces to a purely geometric problem. The corresponding system of equations is hyperbolic. The characteristic relations are integrated in elementary functions. In regions where one family of characteristics is straight, mapping between the principal lines and Cartesian coordinates is determined by linear ordinary differential equations. An illustrative example is provided.

  19. Flow of liquid metals with a transversely applied magnetic field, (8)

    International Nuclear Information System (INIS)

    Arai, Shigeki; Tomita, Yukio; Sudou, Kouzou

    1977-01-01

    As one of the researches of liquid metal flow in transversely applied magnetic field concerning the flow in MHD pipes, the influences of the electrical property of channel side walls, aspect ratio, Reynolds number and Hartmann number on laminar and transition flows investigated experimentally are reported in this paper. Mercury flowed in the rectangular ducts, one of which was made with four insulated walls, and another with insulated top and bottom walls and two conductive side walls, with the aspect ratio varying from 8 to 1/8, in the region of relatively low Hartmann number and Reynolds number. The facility, procedure and results of the experiment are explained, and many experimental curves showing the relations among pipe friction coefficient, Hartmann number, Reynolds number, aspect ratio and the property of walls are given. The experimental results show that the Hartmann effect and the aspect ratio effect are evident as the magnetic field is intensified, but the influence by the electric property of walls is little, and three shapes of the curves representing the relation of friction coefficient and Reynolds number are confirmed by this experiment. (auth.)

  20. Numerical simulation of liquid-metal-flows in radial-toroidal-radial bends

    International Nuclear Information System (INIS)

    Molokov, S.; Buehler, L.

    1993-09-01

    Magnetohydrodynamic flows in a U-bend and right-angle bend are considered with reference to the radial-toroidal-radial concept of a self-cooled liquid-metal blanket. The ducts composing bends have rectangular cross-section. The applied magnetic field is aligned with the toroidal duct and perpendicular to the radial ones. At high Hartmann number the flow region is divided into cores and boundary layers of different types. The magnetohydrodynamic equations are reduced to a system of partial differential equations governing wall electric potentials and the core pressure. The system is solved numerically by two different methods. The first method is iterative with iteration between wall potential and the core pressure. The second method is a general one for the solution of the core flow equations in curvilinear coordinates generated by channel geometry and magnetic field orientation. Results obtained are in good agreement. They show, that the 3D-pressure drop of MHD flows in a U-bend is not a critical issue for blanket applications. (orig./HP) [de

  1. Numerical analysis of liquid metal MHD flows through circular pipes based on a fully developed modeling

    International Nuclear Information System (INIS)

    Zhang, Xiujie; Pan, Chuanjie; Xu, Zengyu

    2013-01-01

    Highlights: ► 2D MHD code based on a fully developed modeling is developed and validated by Samad analytical results. ► The results of MHD effect of liquid metal through circular pipes at high Hartmann numbers are given. ► M type velocity profile is observed for MHD circular pipe flow at high wall conductance ratio condition. ► Non-uniform wall electrical conductivity leads to high jet velocity in Robert layers. -- Abstract: Magnetohydrodynamics (MHD) laminar flows through circular pipes are studied in this paper by numerical simulation under the conditions of Hartmann numbers from 18 to 10000. The code is developed based on a fully developed modeling and validated by Samad's analytical solution and Chang's asymptotic results. After the code validation, numerical simulation is extended to high Hartmann number for MHD circular pipe flows with conducting walls, and numerical results such as velocity distribution and MHD pressure gradient are obtained. Typical M-type velocity is observed but there is not such a big velocity jet as that of MHD rectangular duct flows even under the conditions of high Hartmann numbers and big wall conductance ratio. The over speed region in Robert layers becomes smaller when Hartmann numbers increase. When Hartmann number is fixed and wall conductance ratios change, the dimensionless velocity is through one point which is in agreement with Samad's results, the locus of maximum value of velocity jet is same and effects of wall conductance ratio only on the maximum value of velocity jet. In case of Robert walls are treated as insulating and Hartmann walls as conducting for circular pipe MHD flows, there is big velocity jet like as MHD rectangular duct flows of Hunt's case 2

  2. Korea advanced liquid metal reactor development - Development of measuring techniques of the sodium two-phase flow

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Moo Hwan; Cha, Jae Eun [Pohang University of Science and Technology, Pohang (Korea)

    2000-04-01

    The technology which models and measures the behavior of bubble in liquid sodium is very important to insure the safety of the liquid metal reactor. In this research, we designed/ manufactured each part and loop of experimental facility for sodium two phase flow, and applied a few possible methods, measured characteristic of two phase flow such as bubbly flow. A air-water loop similar to sodium loop on each measuring condition was designed/manufactured. This air-water loop was utilized to acquire many informations which were necessary in designing the two phase flow of sodium and manufacturing experimental facility. Before the manufacture of a electromagnetic flow meter for sodium, the experiment using each electromagnetic flow mete was developed and the air-water loop was performed to understand flow characteristics. Experiments for observing the signal characteristics of flow were performed by flowing two phase mixture into the electromagnetic flow mete. From these experiments, the electromagnetic flow meter was designed and constructed by virtual electrode, its signal processing circuit and micro electro magnet. It was developed to be applicable to low conductivity fluid very successfully. By this experiment with the electromagnetic flow meter, we observed that the flow signal was very different according to void fraction in two phase flow and that probability density function which was made by statistical signal treatment is also different according to flow patterns. From this result, we confirmed that the electromagnetic flow meter could be used to understand the parameters of two phase flow of sodium. By this study, the experimental facility for two phase flow of sodium was constricted. Also the new electromagnetic flow meter was designed/manufactured, and experimental apparatus for two phase flow of air-water. Finally, this study will be a basic tool for measurement of two phase flow of sodium. As the fundamental technique for the applications of sodium at

  3. Exploratory studies of flowing liquid metal divertor options for fusion-relevant magnetic fields in the MTOR facility

    International Nuclear Information System (INIS)

    Ying, A.Y.; Abdou, M.A.; Morley, N.; Sketchley, T.; Woolley, R.; Burris, J.; Kaita, R.; Fogarty, P.; Huang, H.; Lao, X.; Narula, M.; Smolentsev, S.; Ulrickson, M.

    2004-01-01

    This paper reports on experimental findings on liquid metal (LM) free surface flows crossing complex magnetic fields. The experiments involve jet and film flows using GaInSn and are conducted at the UCLA MTOR facility. The goal of this study is to understand the magnetohydrodynamics (MHD) features associated with such a free surface flow in a fusion-relevant magnetic field environment, and determine what LM free surface flow option is most suitable for lithium divertor particle pumping and surface heat removal applications in a near-term experimental plasma device, such as NSTX. Experimental findings indicate that a steady transverse magnetic field, even with gradients typical of NSTX outer divertor conditions, stabilizes a LM jet flow--reducing turbulent disturbances and delaying jet breakup. Important insights into the MHD behavior of liquid metal films under NSTX-like environments are also presented. It is possible to establish an uphill liquid metal film flow on a conducting substrate, although the MHD drag experienced by the flow could be strong and cause the flow to pile-up under simulated NSTX magnetic field conditions. The magnetic field changes the turbulent film flow so that wave structures range from 2D column-type surface disturbances at regions of high magnetic field, to ordinary hydrodynamic turbulence wave structures at regions of low field strength at the outboard. Plans for future work are also presented

  4. Modulation of individual steps in group I intron catalysis by a peripheral metal ion.

    Science.gov (United States)

    Forconi, Marcello; Piccirilli, Joseph A; Herschlag, Daniel

    2007-10-01

    Enzymes are complex macromolecules that catalyze chemical reactions at their active sites. Important information about catalytic interactions is commonly gathered by perturbation or mutation of active site residues that directly contact substrates. However, active sites are engaged in intricate networks of interactions within the overall structure of the macromolecule, and there is a growing body of evidence about the importance of peripheral interactions in the precise structural organization of the active site. Here, we use functional studies, in conjunction with published structural information, to determine the effect of perturbation of a peripheral metal ion binding site on catalysis in a well-characterized catalytic RNA, the Tetrahymena thermophila group I ribozyme. We perturbed the metal ion binding site by site-specifically introducing a phosphorothioate substitution in the ribozyme's backbone, replacing the native ligands (the pro-R (P) oxygen atoms at positions 307 and 308) with sulfur atoms. Our data reveal that these perturbations affect several reaction steps, including the chemical step, despite the absence of direct contacts of this metal ion with the atoms involved in the chemical transformation. As structural probing with hydroxyl radicals did not reveal significant change in the three-dimensional structure upon phosphorothioate substitution, the effects are likely transmitted through local, rather subtle conformational rearrangements. Addition of Cd(2+), a thiophilic metal ion, rescues some reaction steps but has deleterious effects on other steps. These results suggest that native interactions in the active site may have been aligned by the naturally occurring peripheral residues and interactions to optimize the overall catalytic cycle.

  5. Low temperature hydrogenolysis of waxes to diesel range gasoline and light alkanes: Comparison of catalytic properties of group 4, 5 and 6 metal hydrides supported on silica-alumina

    KAUST Repository

    Norsic, Sébastien

    2012-01-01

    A series of metal hydrides (M = Zr, Hf, Ta, W) supported on silica-alumina were studied for the first time in hydrogenolysis of light alkanes in a continuous flow reactor. It was found that there is a difference in the reaction mechanism between d 0 metal hydrides of group 4 and d 0 ↔ d 2 metal hydrides of group 5 and group 6. Furthermore, the potential application of these catalysts has been demonstrated by the transformation of Fischer-Tropsch wax in a reactive distillation set-up into typical gasoline and diesel molecules in high selectivity (up to 86 wt%). Current results show that the group 4 metal hydrides have a promising yield toward liquid fuels.

  6. Experiments and numerical modeling of fast flowing liquid metal thin films under spatially varying magnetic field conditions

    Science.gov (United States)

    Narula, Manmeet Singh

    Innovative concepts using fast flowing thin films of liquid metals (like lithium) have been proposed for the protection of the divertor surface in magnetic fusion devices. However, concerns exist about the possibility of establishing the required flow of liquid metal thin films because of the presence of strong magnetic fields which can cause flow disrupting MHD effects. A plan is underway to design liquid lithium based divertor protection concepts for NSTX, a small spherical torus experiment at Princeton. Of these, a promising concept is the use of modularized fast flowing liquid lithium film zones, as the divertor (called the NSTX liquid surface module concept or NSTX LSM). The dynamic response of the liquid metal film flow in a spatially varying magnetic field configuration is still unknown and it is suspected that some unpredicted effects might be lurking. The primary goal of the research work being reported in this dissertation is to provide qualitative and quantitative information on the liquid metal film flow dynamics under spatially varying magnetic field conditions, typical of the divertor region of a magnetic fusion device. The liquid metal film flow dynamics have been studied through a synergic experimental and numerical modeling effort. The Magneto Thermofluid Omnibus Research (MTOR) facility at UCLA has been used to design several experiments to study the MHD interaction of liquid gallium films under a scaled NSTX outboard divertor magnetic field environment. A 3D multi-material, free surface MHD modeling capability is under development in collaboration with HyPerComp Inc., an SBIR vendor. This numerical code called HIMAG provides a unique capability to model the equations of incompressible MHD with a free surface. Some parts of this modeling capability have been developed in this research work, in the form of subroutines for HIMAG. Extensive code debugging and benchmarking exercise has also been carried out. Finally, HIMAG has been used to study the

  7. Stocks, Flows, and Distribution of Critical Metals in Embedded Electronics in Passenger Vehicles.

    Science.gov (United States)

    Restrepo, Eliette; Løvik, Amund N; Wäger, Patrick; Widmer, Rolf; Lonka, Radek; Müller, Daniel B

    2017-02-07

    One of the major applications of critical metals (CMs) is in electrical and electronic equipment (EEE), which is increasingly embedded in other products, notably passenger vehicles. However, recycling strategies for future CM quantities in end-of-life vehicles (ELVs) are poorly understood, mainly due to a limited understating of the complexity of automotive embedded EEE. We introduce a harmonization of the network structure of automotive electronics that enables a comprehensive quantification of CMs in all embedded EEE in a vehicle. This network is combined with a material flow analysis along the vehicle lifecycle in Switzerland to quantify the stocks and flows of Ag, Au, Pd, Ru, Dy, La, Nd, and Co in automotive embedded EEE. In vehicles in use, we calculated 5 -2 +3 t precious metals in controllers embedded in all vehicle types and 220 -60 +90 t rare earth elements (REE); found mainly in five electric motors: alternator, starter, radiator-fan and electronic power steering motor embedded in conventional passenger vehicles and drive motor/generator embedded in hybrid and electric vehicles. Dismantling these devices before ELV shredding, as well as postshredder treatment of automobile shredder residue may increase the recovery of CMs from ELVs. Environmental and economic implications of such recycling strategies must be considered.

  8. Liquid metal heat transfer in heat exchangers under low flow rate conditions

    International Nuclear Information System (INIS)

    Mochizuki, Hiroyasu

    2015-01-01

    The present paper describes the liquid metal heat transfer in heat exchangers under low flow rate conditions. Measured data from some experiments indicate that heat transfer coefficients of liquid metals at very low Péclet number are much lower than what are predicted by the well-known empirical relations. The cause of this phenomenon was not fully understood for many years. In the present study, one countercurrent-type heat exchanger is analyzed using three, separated countercurrent heat exchanger models: one is a heat exchanger model in the tube bank region, while the upper and lower plena are modeled as two heat exchangers with a single heat transfer tube. In all three heat exchangers, the same empirical correlation is used in the heat transfer calculation on the tube and the shell sides. The Nusselt number, as a function of the Péclet number, calculated from measured temperature and flow rate data in a 50 MW experimental facility was correctly reproduced by the calculation result, when the calculated result is processed in the same way as the experiment. Finally, it is clarified that the deviation is a superficial phenomenon which is caused by the heat transfer in the plena of the heat exchanger. (author)

  9. Characteristics of a plasma flow field produced by a metal array bridge foil explosion

    Science.gov (United States)

    Junying, WU; Long, WANG; Yase, LI; Lijun, YANG; Manzoor, SULTAN; Lang, CHEN

    2018-07-01

    To improve the energy utilization efficiency of metal bridge foil explosion, and increase the function range of plasmas, array bridge foil explosion experiments with different structures were performed. A Schlieren photographic measurement system with a double-pulse laser source was used to observe the flow field of a bridge foil explosion. The evolution laws of plasmas and shock waves generated by array bridge foil explosions of different structures were analyzed and compared. A multi-phase flow calculation model was established to simulate the electrical exploding process of a metal bridge foil. The plasma equation of state was determined by considering the effect of the changing number of particles and Coulomb interaction on the pressure and internal energy. The ionization degree of the plasma was calculated via the Saha–Eggert equation assuming conditions of local thermal equilibrium. The exploding process of array bridge foils was simulated, and the superposition processes of plasma beams were analyzed. The variation and distribution laws of the density, temperature, pressure, and other important parameters were obtained. The results show that the array bridge foil has a larger plasma jet diameter than the single bridge foil for an equal total area of the bridge foil. We also found that the temperature, pressure, and density of the plasma jet’s center region sharply increase because of the superposition of plasma beams.

  10. Dansyl-naphthalimide dyads as molecular probes: effect of spacer group on metal ion binding properties.

    Science.gov (United States)

    Shankar, Balaraman H; Ramaiah, Danaboyina

    2011-11-17

    Interaction of a few dansyl-naphthalimide conjugates 1a-e linked through polymethylene spacer groups with various metal ions was investigated through absorption, fluorescence, NMR, isothermal calorimetric (ITC), and laser flash photolysis techniques. The characteristic feature of these dyads is that they exhibit competing singlet-singlet energy transfer (SSET) and photoinduced electron transfer (PET) processes, both of which decrease with the increase in spacer length. Depending on the spacer group, these dyads interact selectively with divalent Cu(2+) and Zn(2+) ions, as compared to other mono- and divalent metal ions. Jobs plot analysis showed that these dyads form 2:3 complexes with Cu(2+) ions, while 1:1 complexes were observed with Zn(2+) ions. The association constants for the Zn(2+) and Cu(2+) complexes were determined and are found to be in the order 10(3)-10(5) M(-1). Irrespective of the length of the spacer group, these dyads interestingly act as fluorescence ratiometric molecular probes for Cu(2+) ions by altering the emission intensity of both dansyl and naphthalimide chromophores. In contrast, only the fluorescence intensity of the naphthalimide chromophore of the lower homologues (n = 1-3) was altered by Zn(2+) ions. (1)H NMR and ITC measurements confirmed the involvement of both sulfonamide and dimethylamine groups in the complexation with Cu(2+) ions, while only the latter group was involved with Zn(2+) ions. Laser excitation of the dyads 1a-e showed formation of a transient absorption which can be attributed to the radical cation of the naphthalimide chromophore, whereas only the triplet excited state of the dyads 1a-e was observed in the presence of Cu(2+) ions. Uniquely, the complexation of 1a-e with Cu(2+) ions affects both PET and SSET processes, while only the PET process was partially inhibited by Zn(2+) ions in the lower homologues (n = 1-3) and the higher homologues exhibited negligible changes in their emission properties. Our results

  11. HIGHLY REFRACTORY CRUCIBLES OF STABILIZED ZIRCONIA FOR INDUCTION MELTING OF THE PLATINUM GROUP METALS, FABRICATED BY VIBROCASTING

    Directory of Open Access Journals (Sweden)

    V. V. Primachenko

    2012-01-01

    Full Text Available As the result of the studies at PJSC « UKRNIIO them. A.S.Berezhnogo» the technology and commercial production of crucibles from stabilized zirconia for the smelting of platinum group metals are develop

  12. HIGHLY REFRACTORY CRUCIBLES OF STABILIZED ZIRCONIA FOR INDUCTION MELTING OF THE PLATINUM GROUP METALS, FABRICATED BY VIBROCASTING

    OpenAIRE

    V. V. Primachenko; V. V. Martynenko; I. G. Szulik; I. A. Kushchenko

    2012-01-01

    As the result of the studies at PJSC « UKRNIIO them. A.S.Berezhnogo» the technology and commercial production of crucibles from stabilized zirconia for the smelting of platinum group metals are develop

  13. Initial liquid metal magnetohydrodynamic thin film flow experiments in the MeGA-loop facility at UCLA

    International Nuclear Information System (INIS)

    Morley, N.B.; Gaizer, A.A.; Tillack, M.S.; Abdou, M.A.

    1995-01-01

    Free surface thin film flows of liquid metal were investigated experimentally in the presence of a coplanar magnetic field. This investigation was performed in a new magnetohydrodynamic (MHD) flow facility, the MeGA-loop, utilizing a low melting temperature lead-bismuth alloy as the working metal. Owing to the relatively low magnetic field produced by the present field coil system, the ordinary hydrodynamic and low MHD interaction regimes only were investigated. At the high flow speeds necessary for self cooling, the importance of a well designed and constructed channel becomes obvious. Partial MHD drag, increasing the film height, is observed as Haβ 2 becomes greater than unity. MHD laminarization of the turbulent film flows is observed when Haβ/Re>0.002, but fully laminar flow was not reached. Suggestions for facility upgrades to achieve greater MHD interaction are presented in the context of these initial results. (orig.)

  14. Passive cooling system for liquid metal cooled nuclear reactors with backup coolant flow path

    International Nuclear Information System (INIS)

    Hunsbedt, A.; Boardman, C.E.

    1993-01-01

    A dual passive cooling system for liquid metal cooled nuclear fission reactors is described, comprising the combination of: a reactor vessel for containing a pool of liquid metal coolant with a core of heat generating fissionable fuel substantially submerged therein, a side wall of the reactor vessel forming an innermost first partition; a containment vessel substantially surrounding the reactor vessel in spaced apart relation having a side wall forming a second partition; a first baffle cylinder substantially encircling the containment vessel in spaced apart relation having an encircling wall forming a third partition; a guard vessel substantially surrounding the containment vessel and first baffle cylinder in spaced apart relation having a side wall forming a forth partition; a sliding seal at the top of the guard vessel edge to isolate the dual cooling system air streams; a second baffle cylinder substantially encircling the guard vessel in spaced part relationship having an encircling wan forming a fifth partition; a concrete silo substantially surrounding the guard vessel and the second baffle cylinder in spaced apart relation providing a sixth partition; a first fluid coolant circulating flow course open to the ambient atmosphere for circulating air coolant comprising at lent one down comer duct having an opening to the atmosphere in an upper area thereof and making fluid communication with the space between the guard vessel and the first baffle cylinder and at least one riser duct having an opening to the atmosphere in the upper area thereof and making fluid communication with the space between the first baffle cylinder and the containment vessel whereby cooling fluid air can flow from the atmosphere down through the down comer duct and space between the forth and third partitions and up through the space between the third and second partition and the riser duct then out into the atmosphere; and a second fluid coolant circulating flow

  15. Effect of heavy metal on survival of certain groups of indigenous soil ...

    African Journals Online (AJOL)

    Heavy metal pollution of soil is known to adversely effect microbial activities at elevated concentration. However, response of indigenous soil bacterial population to added heavy metal and metal combinations is poorly understood. In the present study salts of heavy metals like Cu, Cd, Cr, Hg, Mn, Ni, Pb and Zn were added ...

  16. Metal-Free Aqueous Flow Battery with Novel Ultrafiltered Lignin as Electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Mukhopadhyay, Alolika [Department of Mechanical and Industrial Engineering, Northeastern University, 360 Huntington Avenue, 334 Snell Engineering, Boston, Massachusetts 02115, United States; Hamel, Jonathan [Department of Mechanical and Industrial Engineering, Northeastern University, 360 Huntington Avenue, 334 Snell Engineering, Boston, Massachusetts 02115, United States; Katahira, Rui [National Renewable Energy Laboratory, Denver West Parkway, Golden, Colorado 80401, United States; Zhu, Hongli [Department of Mechanical and Industrial Engineering, Northeastern University, 360 Huntington Avenue, 334 Snell Engineering, Boston, Massachusetts 02115, United States

    2018-03-05

    As the number of generation sources from intermittent renewable technologies on the electric grid increases, the need for large-scale energy storage devices is becoming essential to ensure grid stability. Flow batteries offer numerous advantages over conventional sealed batteries for grid storage. In this work, for the first time, we investigated lignin, the second most abundant wood derived biopolymer, as an anolyte for the aqueous flow battery. Lignosulfonate, a water-soluble derivative of lignin, is environmentally benign, low cost and abundant as it is obtained from the byproduct of paper and biofuel manufacturing. The lignosulfonate utilizes the redox chemistry of quinone to store energy and undergoes a reversible redox reaction. Here, we paired lignosulfonate with Br2/Br-, and the full cell runs efficiently with high power density. Also, the large and complex molecular structure of lignin considerably reduces the electrolytic crossover, which ensures very high capacity retention. The flowcell was able to achieve current densities of up to 20 mA/cm2 and charge polarization resistance of 15 ohm cm2. This technology presents a unique opportunity for a low-cost, metal-free flow battery capable of large-scale sustainable energy storage.

  17. Water growth on metals and oxides: binding, dissociation and role of hydroxyl groups

    Energy Technology Data Exchange (ETDEWEB)

    Salmeron, M.; Bluhm, H.; Tatarkhanov, M.; Ketteler, G.; Shimizu, T.K.; Mugarza, A.; Deng, Xingyi; Herranz, T.; Yamamoto, S.; Nilsson, A.

    2008-09-01

    The authors discuss the role of the presence of dangling H bonds from water or from surface hydroxyl species on the wetting behavior of surfaces. Using Scanning Tunneling and Atomic Force Microscopies, and Photoelectron Spectroscopy, they have examined a variety of surfaces, including mica, oxides, and pure metals. They find that in all cases, the availability of free, dangling H-bonds at the surface is crucial for the subsequent growth of wetting water films. In the case of mica electrostatic forces and H-bonding to surface O atoms determine the water orientation in the first layer and also in subsequent layers with a strong influence in its wetting characteristics. In the case of oxides like TiO{sub 2}, Cu{sub 2}O, SiO{sub 2} and Al{sub 2}O{sub 3}, surface hydroxyls form readily on defects upon exposure to water vapor and help nucleate the subsequent growth of molecular water films. On pure metals, such as Pt, Pd, and Ru, the structure of the first water layer and whether or not it exhibits dangling H bonds is again crucial. Dangling H-bonds are provided by molecules with their plane oriented vertically, or by OH groups formed by the partial dissociation of water. By tying the two II atoms of the water molecules into strong H-bonds with pre-adsorbed O on Ru can also quench the wettability of the surface.

  18. Influence of platinum group metal-free catalyst synthesis on microbial fuel cell performance

    Science.gov (United States)

    Santoro, Carlo; Rojas-Carbonell, Santiago; Awais, Roxanne; Gokhale, Rohan; Kodali, Mounika; Serov, Alexey; Artyushkova, Kateryna; Atanassov, Plamen

    2018-01-01

    Platinum group metal-free (PGM-free) ORR catalysts from the Fe-N-C family were synthesized using sacrificial support method (SSM) technique. Six experimental steps were used during the synthesis: 1) mixing the precursor, the metal salt, and the silica template; 2) first pyrolysis in hydrogen rich atmosphere; 3) ball milling; 4) etching the silica template using harsh acids environment; 5) the second pyrolysis in ammonia rich atmosphere; 6) final ball milling. Three independent batches were fabricated following the same procedure. The effect of each synthetic parameters on the surface chemistry and the electrocatalytic performance in neutral media was studied. Rotating ring disk electrode (RRDE) experiment showed an increase in half wave potential and limiting current after the pyrolysis steps. The additional improvement was observed after etching and performing the second pyrolysis. A similar trend was seen in microbial fuel cells (MFCs), in which the power output increased from 167 ± 2 μW cm-2 to 214 ± 5 μW cm-2. X-ray Photoelectron Spectroscopy (XPS) was used to evaluate surface chemistry of catalysts obtained after each synthetic step. The changes in chemical composition were directly correlated with the improvements in performance. We report outstanding reproducibility in both composition and performance among the three different batches.

  19. Materials flow analysis of neodymium, status of rare earth metal in the Republic of Korea.

    Science.gov (United States)

    Swain, Basudev; Kang, Leeseung; Mishra, Chinmayee; Ahn, JoongWoo; Hong, Hyun Seon

    2015-11-01

    Materials flow analysis of neodymium, status of rare earth elements (REEs) in the Republic of Korea has been investigated. Information from various resources like the Korean Ministry of Environment, Korea international trade association, United Nations Commodity Trade Statistics Database and from individual industry were collected and analyzed for materials flow analysis of neodymium. Demand of neodymium in the Republic of Korea for the year 2010 was 409.5 tons out of which the majority of neodymium, i.e., 68.41% was consumed by domestic electronics industry followed by medical appliances manufacturing (13.36%). The Republic Korea is one of the biggest consumer and leading exporter of these industrial products, absolutely depends on import of neodymium, as the country is lacking natural resources. The Republic of Korea has imported 325.9 tons of neodymium permanent magnet and 79.5 tons of neodymium containing equipment parts mainly for electronics, medical appliances, and heavy/light vehicles manufacturing industry. Out of which 95.4 tons of neodymium permanent magnet get exported as an intermediate product and 140.6 tons of neodymium in the form of consumable products get exported. Worldwide the neodymium is at the high end of supply chain critical metal because of increasing demand, scarcity and irreplaceable for technological application. To bring back the neodymium to supply stream the recycling of end of life neodymium-bearing waste can be a feasible option. Out of total domestic consumption, only 21.9 tons of neodymium have been collected and subsequently recycled. From material flow analysis, the requirement for an efficient recycling system and element-wise material flow management for these REEs in the Republic of Korea were realized and recommended. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. On salting in effect of the second group metal rhodanides on aqueous-amine solutions

    International Nuclear Information System (INIS)

    Krupatkin, I.L.; Ostrovskaya, E.M.; Vorob'eva, L.D.; Kamyshnikova, G.V.

    1978-01-01

    The ''salting in'' effect of rhodanides of Group 2 metals (magnesium, calcium, strontium, barium) on aqueous-amine solutions (water-aniline, and water-o-toluidine systems) is studied. The solubility in these systems has been determined by the isothermal method at 25 deg C. Compositions of the co-existing liquid phases have been determined by refractometry. The phase diagrams of water-aniline-rhodanide of magnesium, calcium and strontium systems have the same qualitative view. These rhodanides ''salt in'' the water-aniline system so strongly that the systems are completely homogenized. According to the decreasing homogenization effect on the water-aniline and water-o-toluidine systems the salts may be arranged into the following series Mg(NCS) 2 >Ca(NCS) 2 >Sr(NCS) 2 >Ba(NCS) 2 . The ''salting in'. effect is weaker in the water-o-toluidine system rather than in the water-aniline one

  1. High Performance Platinum Group Metal Free Membrane Electrode Assemblies through Control of Interfacial Processes

    Energy Technology Data Exchange (ETDEWEB)

    Ayers, Katherine [Proton Energy Systems, Wallingford, CT (United States); Capuano, Christopher [Proton Energy Systems, Wallingford, CT (United States); Atanassov, Plamen [Univ. of New Mexico, Albuquerque, NM (United States); Mukerjee, Sanjeev [Northeastern Univ., Boston, MA (United States); Hickner, Michael [Pennsylvania State Univ., University Park, PA (United States)

    2017-11-29

    The quantitative goal of this project was to produce a high-performance anion exchange membrane water electrolyzer (AEM-WE) completely free of platinum group metals (PGMs), which could operate for at least 500 hours with less than 50 microV/hour degradation, at 500 mA/cm2. To achieve this goal, work focused on the optimization of electrocatalyst conductivity, with dispersion and utilization in the membrane electrode assembly (MEA) improved through refinement of deposition techniques. Critical factors were also explored with significant work undertaken by Northeastern University to further understand catalyst-membrane-ionomer interfaces and how they differ from liquid electrolyte. Water management and optimal cell operational parameters were established through the design, fabrication, and test of a new test station at Proton specific for AEM evaluation. Additionally, AEM material stability and robustness at high potentials and gas evolution conditions were advanced at Penn State.

  2. Assessment of Typical Heavy Metals in Human Hair of Different Age Groups and Foodstuffs in Beijing, China.

    Science.gov (United States)

    Liang, Gang; Pan, Ligang; Liu, Xinhui

    2017-08-14

    Human hair of different age groups and foodstuff samples were collected in Beijing, China. The concerned metals-Cd, Cr, Pb, As, and Hg-were analyzed, and the metal levels in relation to age, gender, and dietary intake were further assessed. Results showed the highest level of the metals was shown by Pb, with an average concentration of 1.557 ± 0.779 mg/kg, followed by Cr (0.782 ± 0.394), Hg (0.284 ± 0.094), As (0.127 ± 0.078), and Cd (0.071 ± 0.032), following a decreasing order of Pb > Cr > Hg > As > Cd, which were all below the upper limit of normal values in China. The heavy metal concentrations varied greatly among different age groups, and higher concentrations for Cd, Cr, Pb, and As appeared in female hair, whereas higher Hg concentration were found in male hair, suggesting that age and gender were not crucial factors for assessing metal concentrations in human hair. The ingestion of cereals and vegetables were the main route by which heavy metals in the environment create hazardous health effects for local inhabitants, but the estimated metal intakes through food consumption were all lower than the proposed limit of Provisional Tolerable Weekly Intake (PTWI), indicating that heavy metals posed no health risks for the inhabitants. Furthermore, little relationship was found between metal intakes and the corresponding metal levels in hair. Nevertheless, the results of this study can be used to analyze the internal heavy metal burden in the resident population of Beijing area and can also serve as reference for further studies.

  3. Multiconfiguration pair-density functional theory: barrier heights and main group and transition metal energetics.

    Science.gov (United States)

    Carlson, Rebecca K; Li Manni, Giovanni; Sonnenberger, Andrew L; Truhlar, Donald G; Gagliardi, Laura

    2015-01-13

    Kohn-Sham density functional theory, resting on the representation of the electronic density and kinetic energy by a single Slater determinant, has revolutionized chemistry, but for open-shell systems, the Kohn-Sham Slater determinant has the wrong symmetry properties as compared to an accurate wave function. We have recently proposed a theory, called multiconfiguration pair-density functional theory (MC-PDFT), in which the electronic kinetic energy and classical Coulomb energy are calculated from a multiconfiguration wave function with the correct symmetry properties, and the rest of the energy is calculated from a density functional, called the on-top density functional, that depends on the density and the on-top pair density calculated from this wave function. We also proposed a simple way to approximate the on-top density functional by translation of Kohn-Sham exchange-correlation functionals. The method is much less expensive than other post-SCF methods for calculating the dynamical correlation energy starting with a multiconfiguration self-consistent-field wave function as the reference wave function, and initial tests of the theory were quite encouraging. Here, we provide a broader test of the theory by applying it to bond energies of main-group molecules and transition metal complexes, barrier heights and reaction energies for diverse chemical reactions, proton affinities, and the water dimerization energy. Averaged over 56 data points, the mean unsigned error is 3.2 kcal/mol for MC-PDFT, as compared to 6.9 kcal/mol for Kohn-Sham theory with a comparable density functional. MC-PDFT is more accurate on average than complete active space second-order perturbation theory (CASPT2) for main-group small-molecule bond energies, alkyl bond dissociation energies, transition-metal-ligand bond energies, proton affinities, and the water dimerization energy.

  4. Investigations in anhydrous liquid ammonia. Reaction of group 2, 4, 5, 11 metal and actinoids compounds

    International Nuclear Information System (INIS)

    Woidy, Patrick

    2014-01-01

    compounds led to the characterization of pentaammine complexes of the dioxidouranium cation which also was shown to form di-, tetra- or octanuclear networks via oxygen bridges. In the tetra- and octanuclear compounds, penta- and hexavalent uranyl cations seem to be present in one compound. The reactions of TiCl 3 and UF 4 and the reaction of Cs[UO 2 (NO 3 ) 3 ] and CuF 2 , yielded the new compounds [UF(NH 3 ) 8 ]Cl 3 . 3,5 NH 3 and Cs[UO 2 F 3 (NH 3 ) 2 ], respectively. Both compounds demonstrated on the one hand the possibility of the exchange of halides and on the other hand the ability to accept fluoride ions. Additionally, a new method for the synthesis of uranyl chloride is presented. Experiments regarding the solubility of metal halides of group 2, 4, and 5 of the periodic table yielded the ammonia complexes of [Ca(NH 3 ) 8 ]X 2 (X = Br and I), [Ti(NH 3 ) 8 ]Cl 3 . 6 NH 3 , and mer-[VF 3 (NH 3 ) 3 ]. Instead of the expected tetragonal antiprism for the eightfold coordinated Ca 2+ ion, a coordination polyhedron best described as a twofold capped trigonal prism and for the Ti 3+ ion an untypical eightfold coordination can be observed. Characterization of the novel compounds was carried out by single crystal and powder X-ray diffraction, infrared and Raman spectroscopy, thermogravimetry and mass spectrometry.

  5. A study on prediction of metal loss by flow-accelerated corrosion in the CANDU NPP secondary piping systems

    International Nuclear Information System (INIS)

    Shim, S. H.; Song, J. S.; Yoon, K. B.; Hwang, K. M.; Jin, T. E.; Lee, S. H.; Kim, W. S.

    2001-01-01

    Flow-Accelerated Corrosion(FAC) is a phenomenon that results in metal loss from piping, vessels, and equipment made of carbon steel. FAC occurs only under certain conditions of flow, chemistry, geometry, and material. Unfortunately, those conditions are in much of the high-energy piping in nuclear and fossil-fueled power plants. Also, for domestic NPP secondary pipings whose operating time become longer, more evidences of FAC have been reported. The authors are studying on FAC management using CHECWORKS, computer code developed by EPRI. This paper is on the prediction results of metal loss by FAC in the one of CANDU type NPP secondary piping systems

  6. Liquid-metal flow through a thin-walled elbow in a plane perpendicular to a uniform magnetic field

    International Nuclear Information System (INIS)

    Walker, J.S.

    1986-04-01

    This paper presents analytical solutions for the liquid-metal flow through two straight pipes connected by a smooth elbow with the same inside radius. The pipes and the elbow lie in a plane which is perpendicular to a uniform, applied magnetic field. The strength of the magnetic field is assumed to be sufficiently strong that inertial and viscous effects are negligible. This assumption is appropriate for the liquid-lithium flow in the blanket of a magnetic confinement fusion reactor, such as a tokamak. The pipes and the elbow have thin metal walls

  7. Measurements of the asymmetric dynamic sheath around a pulse biased sphere immersed in flowing metal plasma

    International Nuclear Information System (INIS)

    Wu Hongchen; Anders, Andre

    2008-01-01

    A long-probe technique was utilized to record the expansion and retreat of the dynamic sheath around a spherical substrate immersed in pulsed cathode arc metal plasma. Positively biased, long cylindrical probes were placed on the side and downstream of a negatively pulsed biased stainless steel sphere of 1 in. (25.4 mm) diameter. The amplitude and width of the negative high voltage pulses (HVPs) were 2 kV, 5 kV, 10 kV, and 2 μs, 4 μs, 10 μs, respectively. The variation of the probe (electron) current during the HVP is a direct measure for the sheath expansion and retreat. Maximum sheath sizes were determined for the different parameters of the HVP. The expected rarefaction zone behind the biased sphere (wake) due to the fast plasma flow was clearly established and quantified.

  8. Measurements of the asymmetric dynamic sheath around a pulse biased sphere immersed in flowing metal plasma

    Science.gov (United States)

    Wu, Hongchen; Anders, André

    2008-08-01

    A long-probe technique was utilized to record the expansion and retreat of the dynamic sheath around a spherical substrate immersed in pulsed cathode arc metal plasma. Positively biased, long cylindrical probes were placed on the side and downstream of a negatively pulsed biased stainless steel sphere of 1 in. (25.4 mm) diameter. The amplitude and width of the negative high voltage pulses (HVPs) were 2 kV, 5 kV, 10 kV, and 2 µs, 4 µs, 10 µs, respectively. The variation of the probe (electron) current during the HVP is a direct measure for the sheath expansion and retreat. Maximum sheath sizes were determined for the different parameters of the HVP. The expected rarefaction zone behind the biased sphere (wake) due to the fast plasma flow was clearly established and quantified.

  9. Experimental study of an electromagnetic flow meter for liquid metals based on torque measurement during pumping process

    International Nuclear Information System (INIS)

    Dubovikova, N; Kolesnikov, Y; Karcher, Ch

    2015-01-01

    This paper presents a detailed experimental study on an electromagnetic flow measurement technique to measure the flow rate of liquid metals. The experimental setup consists of a contactless electromagnetic pump with a torque sensor mounted on the pump shaft. The electromagnetic pump is composed of two rotating steel discs having embedded permanent magnets with alternating poles. The rotation of the discs creates a travelling sinusoidal magnetic field and eddy currents within the liquid metal. The metal is contained inside the duct located between the discs of the pump. The interaction of the magnetic field and the induced eddy currents generates an electromagnetic Lorentz force providing the pumping effect. The flow rate is proportional to this force. The torque sensor measures the moment of the discs due to the Lorentz force, which is converted to a flow rate value. We name the method Lorentz torque velocimetry (LTV). The full calibration procedure and experimental investigation of the LTV are described. The method can be used as a non-contact flow rate control technique for liquid metals. (paper)

  10. Analysis of material flow in metal forming processes by using computer simulation and experiment with model material

    International Nuclear Information System (INIS)

    Kim, Heon Young; Kim, Dong Won

    1993-01-01

    The objective of the present study is to analyze material flow in the metal forming processes by using computer simulation and experiment with model material, plasticine. A UBET program is developed to analyze the bulk flow behaviour of various metal forming problems. The elemental strain-hardening effect is considered in an incremental manner and the element system is automatically regenerated at every deforming step in the program. The material flow behaviour in closed-die forging process with rib-web type cavity are analyzed by UBET and elastic-plastic finite element method, and verified by experiments with plasticine. There were good agreements between simulation and experiment. The effect of corner rounding on material flow behavior is investigated in the analysis of backward extrusion with square die. Flat punch indentation process is simulated by UBET, and the results are compared with that of elastic-plastic finite element method. (Author)

  11. Explorations of new selenites of the group IIIA and IVA metals

    International Nuclear Information System (INIS)

    Kong Fang; Li Peicin; Zhang Suyun; Mao Jianggao

    2012-01-01

    Systematic explorations of new phases in the Ga III /In III /Ge IV –Se IV –O systems by hydrothermal syntheses or solid-state reactions at high-temperature led to six new ternary compounds, namely, M 2 Se 2 O 7 (M=Ga 1, In 2), M(OH)(SeO 3 ) (M=Ga 3, In 4), α-Ge(SeO 3 ) 2 5 and β-Ge(SeO 3 ) 2 6. Ga 2 Se 2 O 7 1 displays a 3D open framework composed of 2D gallium oxide layers being further bridged and capped by SeO 3 groups. In 2 Se 2 O 7 2 features a 3D indium oxide framework formed by corner- and edge- sharing InO 6 octahedra with SeO 3 groups attached on the cavities and the 8-member ring tunnels of the structure. The isostructural of M(OH)(SeO 3 ) (M=Ga 3, In 4) exhibit a 2D metal selenite layer composed of 1D edge-sharing MO 6 octahedral chains that are interconnected by SeO 3 groups. α-Ge(SeO 3 ) 2 (P2 1 /n) 5 displays a 3D open framework with 1D 8-member ring tunnels along the a-axis while β-Ge(SeO 3 ) 2 (Pa-3) 6 exhibits a condensed 3D network. - Graphical abstract: Highlights: ► Up to now, selenites of the group IIIA and IVA metals are still rare. ► Hydrothermal or solid state reactions yielded six new compounds in this system. ► They are M 2 Se 2 O 7 (M=Ga, In), M(OH)(SeO 3 ) (M=Ga, In), α-Ge(SeO 3 ) 2 and β-Ge(SeO 3 ) 2 . ► They exhibit four different 3D and one 2D structural types. ► α-Ge(SeO 3 ) 2 and β-Ge(SeO 3 ) 2 represent the first examples of germanium selenites.

  12. Numerical simulations of air–water cap-bubbly flows using two-group interfacial area transport equation

    International Nuclear Information System (INIS)

    Wang, Xia; Sun, Xiaodong

    2014-01-01

    Highlights: • Two-group interfacial area transport equation was implemented into a three-field two-fluid model in Fluent. • Numerical model was developed for cap-bubbly flows in a narrow rectangular flow channel. • Numerical simulations were performed for cap-bubbly flows with uniform void inlets and with central peaked void inlets. • Code simulations showed a significant improve over the conventional two-fluid model. - Abstract: Knowledge of cap-bubbly flows is of great interest due to its role in understanding of the flow regime transition from bubbly to slug or churn-turbulent flows. One of the key characteristics of such flows is the existence of bubbles in different sizes and shapes associated with their distinctive dynamic natures. This important feature is, however, generally not well captured by many available two-phase flow modeling approaches. In this study, a modified two-fluid model, namely a three-field, two-fluid model, is proposed. In this model, bubbles are categorized into two groups, i.e., spherical/distorted bubbles as Group-1 while cap/churn-turbulent bubbles as Group-2. A two-group interfacial area transport equation (IATE) is implemented to describe dynamic changes of interfacial structure in each bubble group, resulting from intra- and inter-group interactions and phase changes due to evaporation and condensation. Attention is also paid to appropriate constitutive relations of the interfacial transfers due to mechanical and thermal non-equilibrium between the different fields. The proposed three-field, two-fluid model is used to predict the phase distributions of adiabatic air–water flows in a confined rectangular duct. Good agreement between the simulation results from the proposed model and relevant experimental data indicates that the proposed model is promising as an improved computational tool for two-phase cap-bubbly flow simulations in rectangular flow ducts

  13. Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling

    Energy Technology Data Exchange (ETDEWEB)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng, E-mail: shends@zju.edu.cn

    2013-10-15

    Highlights: • Cu, Zn, Pb, and Ni are enriched in bottom ash from WEEE dismantling residues. • The heavy metal residual fraction restricts transfer in the incinerator. • Pre-treatment to remove heavy metals from WEEE residues would reduce emissions. -- Abstract: The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (T{sub Cd} = 69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required.

  14. Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling

    International Nuclear Information System (INIS)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng

    2013-01-01

    Highlights: • Cu, Zn, Pb, and Ni are enriched in bottom ash from WEEE dismantling residues. • The heavy metal residual fraction restricts transfer in the incinerator. • Pre-treatment to remove heavy metals from WEEE residues would reduce emissions. -- Abstract: The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (T Cd = 69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required

  15. Comparison of catchment grouping methods for flow duration curve estimation at ungauged sites in France

    Directory of Open Access Journals (Sweden)

    E. Sauquet

    2011-08-01

    Full Text Available The study aims at estimating flow duration curves (FDC at ungauged sites in France and quantifying the associated uncertainties using a large dataset of 1080 FDCs. The interpolation procedure focuses here on 15 percentiles standardised by the mean annual flow, which is assumed to be known at each site. In particular, this paper discusses the impact of different catchment grouping procedures on the estimation of percentiles by regional regression models.

    In a first step, five parsimonious FDC parametric models are tested to approximate FDCs at gauged sites. The results show that the model based on the expansion of Empirical Orthogonal Functions (EOF outperforms the other tested models. In the EOF model, each FDC is interpreted as a linear combination of regional amplitude functions with spatially variable weighting factors corresponding to the parameters of the model. In this approach, only one amplitude function is required to obtain a satisfactory fit with most of the observed curves. Thus, the considered model requires only two parameters to be applicable at ungauged locations.

    Secondly, homogeneous regions are derived according to hydrological response, on the one hand, and geological, climatic and topographic characteristics on the other hand. Hydrological similarity is assessed through two simple indicators: the concavity index (IC representing the shape of the dimensionless FDC and the seasonality ratio (SR, which is the ratio of summer and winter median flows. These variables are used as homogeneity criteria in three different methods for grouping catchments: (i according to an a priori classification of French Hydro-EcoRegions (HERs, (ii by applying regression tree clustering and (iii by using neighbourhoods obtained by canonical correlation analysis.

    Finally, considering all the data, and subsequently for each group obtained through the tested grouping techniques, we derive regression models between

  16. Analysis of gas-liquid metal two-phase flows using a reactor safety analysis code SIMMER-III

    International Nuclear Information System (INIS)

    Suzuki, Tohru; Tobita, Yoshiharu; Kondo, Satoru; Saito, Yasushi; Mishima, Kaichiro

    2003-01-01

    SIMMER-III, a safety analysis code for liquid-metal fast reactors (LMFRs), includes a momentum exchange model based on conventional correlations for ordinary gas-liquid flows, such as an air-water system. From the viewpoint of safety evaluation of core disruptive accidents (CDAs) in LMFRs, we need to confirm that the code can predict the two-phase flow behaviors with high liquid-to-gas density ratios formed during a CDA. In the present study, the momentum exchange model of SIMMER-III was assessed and improved using experimental data of two-phase flows containing liquid metal, on which fundamental information, such as bubble shapes, void fractions and velocity fields, has been lacking. It was found that the original SIMMER-III can suitably represent high liquid-to-gas density ratio flows including ellipsoidal bubbles as seen in lower gas fluxes. In addition, the employment of Kataoka-Ishii's correlation has improved the accuracy of SIMMER-III for gas-liquid metal flows with cap-shape bubbles as identified in higher gas fluxes. Moreover, a new procedure, in which an appropriate drag coefficient can be automatically selected according to bubble shape, was developed. Through this work, the reliability and the precision of SIMMER-III have been much raised with regard to bubbly flows for various liquid-to-gas density ratios

  17. Rapid response sensor to monitor the temperature and flow of liquid metals

    International Nuclear Information System (INIS)

    McCann, J.D.

    1980-01-01

    Two forms of a sensor capable of simultaneously monitoring the temperature and flow of liquid metal coolants within a reactor are described. They operate by measuring the coupling impedances between the sensor and the surrounding electrically conductive coolant. Since the system utilises electrical rather than thermal properties, the response to perturbations is rapid, typically displaying the changed conditions within a few milliseconds. The first form of the sensor was designed to operate whilst protected by a thick walled service tube positioned in the reactor coolant. Providing bends in the tube had a radius greater than 70 cm, the sensor could be removed for inspection and maintenance if necessary. The second sensor was fitted inside a streamlined NaK proof capsule. This was inserted directly into the coolant outlet stream of a fuel pin assembly in the Dounreay Fast Reactor. In this form the sensor successfully monitored flow, entrained gas and temperature excursions during the final operating cycle of D.F.R. (author)

  18. Numerical Investigation of magnetohydrodynamic flow through Sudden expansion pipes in Liquid Metal Blankets

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Jingchao; He, Qingyun; Chen, Hongli, E-mail: hlchen1@ustc.edu.cn; Ye, Minyou

    2016-11-01

    In fusion liquid metal blanket, sudden expansions and sudden contractions are very common geometries. Changing of the cross-section causes 3-D magnetohydrodynamic (MHD) effects, which will affect the flow pattern, current distribution and pressure drop. In this paper the numerical code based on OpenFOAM platform developed by University of Science and Technology of China was used to investigate and optimize the sudden expansion pipe. The code has been validated by the recommended benchmark cases including Shercliff, Hunt, ALEX experiments (rectangular duct and round pipe) and KIT experiment cases. The obtained numerical results agreed well with those of all the benchmark cases. Previous and valuable analytical and experimental works have been done by L. Buhler, et. el. Based on these works, in the present paper, further investigation of different expansion lengths between the upstream pipe and downstream pipe at high Hartmann number and Reynolds number were conducted. Besides, different expansion ratios with a specific expansion length were conducted. The numerical results showed that with the increasing of expansion length, the 3D MHD effects gradually weakened. Especially, the 3D pressure drop decreases with the increasing of expansion length. Whereas, the expansion ratio factor shows no obvious influences on the total MHD pressure drop but greatly influence the local pressure distribution. These numerical simulations can be used to evaluate the MHD flow inside the expansion and contraction pipes.

  19. Redox-Flow Batteries: From Metals to Organic Redox-Active Materials.

    Science.gov (United States)

    Winsberg, Jan; Hagemann, Tino; Janoschka, Tobias; Hager, Martin D; Schubert, Ulrich S

    2017-01-16

    Research on redox-flow batteries (RFBs) is currently experiencing a significant upturn, stimulated by the growing need to store increasing quantities of sustainably generated electrical energy. RFBs are promising candidates for the creation of smart grids, particularly when combined with photovoltaics and wind farms. To achieve the goal of "green", safe, and cost-efficient energy storage, research has shifted from metal-based materials to organic active materials in recent years. This Review presents an overview of various flow-battery systems. Relevant studies concerning their history are discussed as well as their development over the last few years from the classical inorganic, to organic/inorganic, to RFBs with organic redox-active cathode and anode materials. Available technologies are analyzed in terms of their technical, economic, and environmental aspects; the advantages and limitations of these systems are also discussed. Further technological challenges and prospective research possibilities are highlighted. © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  20. Group Analysis of Free Convection Flow of a Magnetic Nanofluid with Chemical Reaction

    Directory of Open Access Journals (Sweden)

    Md. Jashim Uddin

    2015-01-01

    Full Text Available A theoretical study of two-dimensional magnetohydrodynamics viscous incompressible free convective boundary layer flow of an electrically conducting, chemically reacting nanofluid from a convectively heated permeable vertical surface is presented. Scaling group of transformations is used in the governing equations and the boundary conditions to determine absolute invariants. A third-order ordinary differential equation which corresponds to momentum conservation and two second-order ordinary differential equations which correspond to energy and nanoparticle volume fraction (species conservation are derived. Our (group analysis indicates that, for the similarity solution, the convective heat transfer coefficient and mass transfer velocity are proportional to x-1/4 whilst the reaction rate is proportional to x-1/2, where x is the axial distance from the leading edge of the plate. The effects of the relevant controlling parameters on the dimensionless velocity, temperature, and nanoparticle volume fraction are examined. The accuracy of the technique we have used was tested by performing comparisons with the results of published work and the results were found to be in good agreement. The present computations indicate that the flow is accelerated and temperature enhanced whereas nanoparticle volume fractions are decreased with increasing order of chemical reaction. Furthermore the flow is strongly decelerated, whereas the nanoparticle volume fraction and temperature are enhanced with increasing magnetic field parameter. Increasing convection-conduction parameter increases velocity and temperatures but has a weak influence on nanoparticle volume fraction distribution. The present study demonstrates the thermal enhancement achieved with nanofluids and also magnetic fields and is of relevance to nanomaterials processing.

  1. Steady nanofluid flow with variable fluid possessions over a linearly extending surface: A Lie group exploration

    Directory of Open Access Journals (Sweden)

    Kalidas Das

    2018-03-01

    Full Text Available The temperament of stream characteristic, heat and mass transfer of MHD forced convective flow over a linearly expanding porous medium has been scrutinized in the progress exploration. The germane possessions of the liquid like viscosity along with thermal conductivity are believed to be variable in nature, directly influenced by the temperature of flow. As soon as gaining the system of leading equations of the stream, Lie symmetric group transformations have been employed to come across the fitting parallel conversions to alter the central PDEs into a suit of ODEs. The renovated system of ODE with appropriate boundary conditions is numerically solved with the assistance of illustrative software MAPLE 17. The consequences of the relevant factors of the system have been exemplified through charts and graphs. An analogous qualified survey has been prepared among present inquiry and subsisting reads and achieved an admirable accord between them. The variable viscosity parameter has more significant effect on nanofluid velocity than regular fluid and temporal profile as well as nanoparticle concentration is also influenced with variable viscosity. Keywords: Nanofluid, Stretching sheet, Variable viscosity, Variable thermal conductivity, Lie symmetry group

  2. A renormalization group scaling analysis for compressible two-phase flow

    International Nuclear Information System (INIS)

    Chen, Y.; Deng, Y.; Glimm, J.; Li, G.; Zhang, Q.; Sharp, D.H.

    1993-01-01

    Computational solutions to the Rayleigh--Taylor fluid mixing problem, as modeled by the two-fluid two-dimensional Euler equations, are presented. Data from these solutions are analyzed from the point of view of Reynolds averaged equations, using scaling laws derived from a renormalization group analysis. The computations, carried out with the front tracking method on an Intel iPSC/860, are highly resolved and statistical convergence of ensemble averages is achieved. The computations are consistent with the experimentally observed growth rates for nearly incompressible flows. The dynamics of the interior portion of the mixing zone is simplified by the use of scaling variables. The size of the mixing zone suggests fixed-point behavior. The profile of statistical quantities within the mixing zone exhibit self-similarity under fixed-point scaling to a limited degree. The effect of compressibility is also examined. It is found that, for even moderate compressibility, the growth rates fail to satisfy universal scaling, and moreover, increase significantly with increasing compressibility. The growth rates predicted from a renormalization group fixed-point model are in a reasonable agreement with the results of the exact numerical simulations, even for flows outside of the incompressible limit

  3. Boosting Chemical Stability, Catalytic Activity, and Enantioselectivity of Metal-Organic Frameworks for Batch and Flow Reactions.

    Science.gov (United States)

    Chen, Xu; Jiang, Hong; Hou, Bang; Gong, Wei; Liu, Yan; Cui, Yong

    2017-09-27

    A key challenge in heterogeneous catalysis is the design and synthesis of heterogeneous catalysts featuring high catalytic activity, selectivity, and recyclability. Here we demonstrate that high-performance heterogeneous asymmetric catalysts can be engineered from a metal-organic framework (MOF) platform by using a ligand design strategy. Three porous chiral MOFs with the framework formula [Mn 2 L(H 2 O) 2 ] are prepared from enantiopure phosphono-carboxylate ligands of 1,1'-biphenol that are functionalized with 3,5-bis(trifluoromethyl)-, bismethyl-, and bisfluoro-phenyl substituents at the 3,3'-position. For the first time, we show that not only chemical stability but also catalytic activity and stereoselectivity of the MOFs can be tuned by modifying the ligand structures. Particularly, the MOF incorporated with -CF 3 groups on the pore walls exhibits enhanced tolerance to water, weak acid, and base compared with the MOFs with -F and -Me groups. Under both batch and flow reaction systems, the CF 3 -containing MOF demonstrated excellent reactivity, selectivity, and recyclability, affording high yields and enantioselectivities for alkylations of indoles and pyrrole with a range of ketoesters or nitroalkenes. In contrast, the corresponding homogeneous catalysts gave low enantioselectivity in catalyzing the tested reactions.

  4. Bibliography of the technical literature of the Materials Joining Group, Metals and Ceramics Division, 1951 through June 1987

    International Nuclear Information System (INIS)

    David, S.A.; Goodwin, G.M.; Gardner, K.

    1987-08-01

    This document contains a listing of the written scientific information originating in the Materials Joining Group (formerly the Welding and Brazing Group), Metals and Ceramics Division, Oak Ridge National Laboratory during 1951 through June 1987. It is a registry of about 400 documents as nearly as possible in the order in which they were issued

  5. Survey of studies on the flow and heat transfer of two-component, two-phase flow of liquid metal in magnetic field

    International Nuclear Information System (INIS)

    Kumamaru, Hiroshige

    1980-01-01

    Brief review of the studies on the flow and heat transfer of two-component, two-phase flow of liquid metal in magnetic field is presented. R.J. Thome measured the distribution of void rate, slip ratio and pressure loss for the two-phase flow of NaK-N 2 under vertical magnetic field. The void rate distribution became even and the slip ratio increased with the increasing magnetic field. The experimental results of pressure loss was compared with the calculation by an equation derived from the homogeneous flow model. R.G. Owen et al. made the analytical studies of the MHD friction loss of two phase flow. Michiyoshi et al. made experimental studies on the hydrodynamic local properties of Hg-Ar two-phase flow of slug region in a vertically ascending tube under magnetic field, and Kimi et al. also made studies on the heat transfer of Hg-Ar flow under magnetic field. Saito et al. measured the slip ratio and pressure loss of NaK-N 2 flow. As a whole, it can be said that the average void rate decreases, and its distribution becomes even under magnetic field. The slip ratio increases, and the friction loss factor becomes nearly one. It was hard to make clear the heat transfer characteristics. (Kato, T.)

  6. Distribution of rare-earth (Y, La, Ce) and other heavy metals in the profiles of the podzolic soil group

    Science.gov (United States)

    Vodyanitskii, Yu. N.; Goryachkin, S. V.; Savichev, A. T.

    2011-05-01

    Along with Fe and Al, many heavy metals (Mn, Cr, Zn, Cu, and Ni) show a markedly pronounced eluvial-illuvial redistribution in the profiles of soils of the podzolic group. The intensity of the redistribution of the bulk forms of these metals is comparable with that of Fe and exceeds that of Al. Although the podzolic soils are depleted of rare-earth metals, the latter respond readily to soil podzolization. The inactive participation of Al is explained by an insignificant portion of the active reaction-capable fraction. Podzolization does not influence the profile distribution of Sr and Ba. The leaching degree of heavy metals such as Mn, Cr, Zn, Ni, and Zr is noticeably higher in the sandy podzols than in the loamy podzolic soils. Leaching of heavy metals from the podzolic horizons is of geochemical importance, whereas the depletion of metals participating in plant nutrition and biota development is of ecological importance. The leaching of heavy metals is related to the destruction of clay particles in the heavy-textured podzolic soils; the effect of the soil acidity on the leaching of heavy metals is less significant.

  7. Slow and stopped light in active gain composite materials of metal nanoparticles. Ultralarge group index-bandwidth product predicted

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kwang-Hyon; Choe, Song-Hyok [Institute of Lasers, State Academy of Sciences, Unjong District, Pyongyang (Korea, Democratic People' s Republic of)

    2017-08-15

    Chip-compatible slow light devices with large group index-bandwidth products and low losses are of great interest in the community of modern photonics. In this work, active gain materials containing metal nanoparticles are proposed as the slow and stopped light materials. Gain-assisted high field enhancement in metal nanoparticles and the resultant strong dispersion lead to such phenomena. From the Maxwell-Garnett model, it is revealed that the metal nanocomposite exhibits the infinitely large group index when the gain of the host medium and the filling factor of metal nanoparticles satisfy a critical condition. For the gain of the host above the critical value, one can observe slowing down effect with amplification of light pulses. Significantly large group index-bandwidth products, which vary from a few to several thousand or even infinity depending on the gain value of the host medium, have been numerically predicted in active silica glasses containing spheroidal metal nanoparticles, as examples. The proposed scheme inherently provides the widely varying operating spectral range by changing the aspect ratio of metal nanoparticles and chip-compatibility with low cost. (copyright 2017 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Formation of a vortex flow at the laser cutting of sheet metal with low pressure of assisting gas

    Energy Technology Data Exchange (ETDEWEB)

    Kovalev, O B; Yudin, P V; Zaitsev, A V [Khristianovich' s Institute of Theoretical and Applied Mechanics, Russian Academy of Sciences, Siberian Branch, Novosibirsk (Russian Federation)], E-mail: kovalev@itam.nsc.ru

    2008-08-07

    Specific features of subsonic jet gas flows in narrow channels geometrically similar to the laser cut are studied experimentally and theoretically. Such flows are visualized by a technique based on prior application of a viscous liquid film onto the side walls of the channel made of transparent glass. The gas flow inside the channel induces a liquid flow on the glass wall in the form of extremely small filaments, which coincide with the streamlines of the gas flow. Filming of these filaments by a CCD camera allows one to capture the specific features of these gas-dynamic flows. Mathematical modelling of the dynamics of a viscous compressible heat-conducting gas was performed by solving full three-dimensional Navier-Stokes equations. Numerical calculations and experiments reveal vortex structures in the flow at the entrance and exit of the channel, which may directly affect the surface quality in real gas-laser cutting of metals. The largest vortex, which arises at the channel exit, collects and accumulates the liquid flowing down the channel walls. Jet flows are generated by sonic nozzles with conical or cylindrical exit sections or by a double coaxial nozzle. The double nozzle includes the central conical nozzle and the side concentric nozzle, which allows additional side injection of the gas to be organized. The study with the double nozzle shows that the vortices disappear as the pressure in the external nozzle is increased, and a stable vortex-free attached gas flow is formed.

  9. Recycling of platinum group metals from the automotive catalysts; Reciclagem de metais do grupo da platina proveniente de catalisadores automotivos

    Energy Technology Data Exchange (ETDEWEB)

    Benevit, Mariana; Petter, Patricia Melo Halmenschlager; Veit, Hugo Marcelo, E-mail: patymhp@yahoo.com.br [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Faculdade de Engenharia. Departamento de Materiais

    2014-07-01

    Currently it is very important to use alternative sources of raw material for obtaining metals, avoiding the traditional mining. This work aims to characterize and evaluate the recoverability of platinum group metals present in automotive catalysts. Thus, the catalysts were divided into two groups: the first was catalysts used in 1.0 cars and the second was catalyst used in 2.0 cars. DRX and FRX techniques and chemical analysis performed by ICP/OES was used to characterized these materials. The results showed that there is a significant amount of platinum group elements in catalyst waste, which can be separated and reused. In the next step, hydro and pyrometallurgical routes, for metals extraction from catalyst waste, will be studied. (author)

  10. Platinum-group elements and gold in base metal sulfides, platinum-group minerals, and Re-Os isotope compositions of the Uitkomst complex, South Africa

    Czech Academy of Sciences Publication Activity Database

    Trubač, Jakub; Ackerman, Lukáš; Gauert, Ch.; Ďurišová, Jana; Hrstka, Tomáš

    2018-01-01

    Roč. 113, č. 2 (2018), s. 439-461 ISSN 0361-0128 R&D Projects: GA ČR GA13-15390S Institutional support: RVO:67985831 Keywords : binary alloys * copper compounds * economic geology * gold * iridium * isotopes * ore deposits * osmium * palladium * platinum * platinum metals * pyrites * Rhenium * rhenium alloys * ruthenium * solid solutions * sulfur compounds * crustal materials * mass-balance calculations * massive sulfides * mineralized zone * monosulfide solid solutions * platinum group elements * platinum group elements (PGEs) * platinum group minerals Subject RIV: DB - Geology ; Mineralogy; AC - Archeology, Anthropology, Ethnology (ARUB-Q) OBOR OECD: Geology; Archaeology (ARUB-Q) Impact factor: 2.519, year: 2016

  11. Design and Development of a Continuous-Flow Countercurrent Metal Extraction System to Remove Heavy Metals from Contaminated Soils

    National Research Council Canada - National Science Library

    Neale, Christopher M. U

    1997-01-01

    .... The research focused on eight contaminated soils from Army installations and the metal extraction capabilities of eight extracting agents including HNO3, HCI, fluorosilicic acid, citric acid, EDTA, DTPA, NTA, and NaOH...

  12. Charge-flow structures as polymeric early-warning fire alarm devices. M.S. Thesis; [metal oxide semiconductors

    Science.gov (United States)

    Sechen, C. M.; Senturia, S. D.

    1977-01-01

    The charge-flow transistor (CFT) and its applications for fire detection and gas sensing were investigated. The utility of various thin film polymers as possible sensing materials was determined. One polymer, PAPA, showed promise as a relative humidity sensor; two others, PFI and PSB, were found to be particularly suitable for fire detection. The behavior of the charge-flow capacitor, which is basically a parallel-plate capacitor with a polymer-filled gap in the metallic tip electrode, was successfully modeled as an RC transmission line. Prototype charge-flow transistors were fabricated and tested. The effective threshold voltage of this metal oxide semiconductor was found to be dependent on whether surface or bulk conduction in the thin film was dominant. Fire tests with a PFI-coated CFT indicate good sensitivity to smouldering fires.

  13. From here to criticality: Renormalization group flow between two conformal field theories

    International Nuclear Information System (INIS)

    Leaf-Herrmann, W.A.

    1993-01-01

    Using non-perturbative techniques, we study the renormalization group trajectory between two conformal field theories. Specifically, we investigate a perturbation of the A 3 superconformal minimal model such that in the infrared limit the theory flows to the A 2 model. The correlation functions in the topological sector of the theory are computed numerically along the trajectory, and these results are compared to the expected asymptotic behavior. Excellent agreement is found, and the characteristic features of the infrared theory, including the central charge and the normalized operator product expansion coefficients, are obtained. We also review and discuss some aspects of the geometrical description of N=2 supersymmetric quantum field theories recently uncovered by Cecotti and Vafa. (orig.)

  14. Infrared multiple photon dissociation spectroscopy of group I and group II metal complexes with Boc-hydroxylamine

    NARCIS (Netherlands)

    Dain, R.P.; Gresham, G.; Groenewold, G.S.; Steill, J.D.; Oomens, J.; van Stipdonk, M.J.

    2013-01-01

    RATIONALE: Hydroxamates are essential growth factors for some microbes, acting primarily as siderophores that solubilize iron for transport into a cell. Here we determined the intrinsic structure of 1:1 complexes between Boc-protected hydroxylamine and group I ([M(L)](+)) and group II ([M(L-H)](+))

  15. Direct alcohol fuel cells: Increasing platinum performance by modification with sp-group metals

    Science.gov (United States)

    Figueiredo, Marta C.; Sorsa, Olli; Doan, Nguyet; Pohjalainen, Elina; Hildebrand, Helga; Schmuki, Patrik; Wilson, Benjamin P.; Kallio, Tanja

    2015-02-01

    By using sp group metals as modifiers, the catalytic properties of Pt can be improved toward alcohols oxidation. In this work we report the performance increase of direct alcohol fuel cells (DAFC) fuelled with ethanol or 2-propanol with platinum based anode electrodes modified with Bi and Sb adatoms. For example, by simply adding Sb to the Pt/C based anode ink during membrane electrode assembly fabrication of a direct ethanol fuel cell (DEFC) its performance is improved three-fold, with more than 100 mV increase in the open circuit potential. For the fuel cell fuelled with 2-propanol high power densities are obtained at very high potentials with these catalyst materials suggesting a great improvement for practical applications. Particularly in the case of Pt/C-Bi, the improvement is such that within 0.6 V (from 0.7 to 0.1 V) the power densities are between 7 and 9 mW/cm2. The results obtained with these catalysts are in the same range as those obtained with other bimetallic catalysts comprising of PtRu and PtSn, which are currently considered to be the best for these type of fuel cells and that are obtained by more complicated (and consequently more expensive) methods.

  16. Enhanced Dissolution of Platinum Group Metals Using Electroless Iron Deposition Pretreatment

    Science.gov (United States)

    Taninouchi, Yu-ki; Okabe, Toru H.

    2017-12-01

    In order to develop a new method for efficiently recovering platinum group metals (PGMs) from catalyst scraps, the authors investigated an efficient dissolution process where the material was pretreated by electroless Fe deposition. When Rh-loaded alumina powder was kept in aqua regia at 313 K (40 °C) for 30 to 60 minutes, the Rh hardly dissolved. Meanwhile, after electroless Fe plating using a bath containing sodium borohydride and potassium sodium tartrate as the reducing and complexing agents, respectively, approximately 60 pct of Rh was extracted by aqua regia at 313 K (40 °C) after 30 minutes. Furthermore, when heat treatment was performed at 1200 K (927 °C) for 60 minutes in vacuum after electroless plating, the extraction of Rh approached 100 pct for the same leaching conditions. The authors also confirmed that the Fe deposition pretreatment enhanced the dissolution of Pt and Pd. These results indicate that an effective and environmentally friendly process for the separation and extraction of PGMs from catalyst scraps can be developed utilizing this Fe deposition pretreatment.

  17. Activity targets for nanostructured platinum-group-metal-free catalysts in hydroxide exchange membrane fuel cells

    Science.gov (United States)

    Setzler, Brian P.; Zhuang, Zhongbin; Wittkopf, Jarrid A.; Yan, Yushan

    2016-12-01

    Fuel cells are the zero-emission automotive power source that best preserves the advantages of gasoline automobiles: low upfront cost, long driving range and fast refuelling. To make fuel-cell cars a reality, the US Department of Energy has set a fuel cell system cost target of US$30 kW-1 in the long-term, which equates to US$2,400 per vehicle, excluding several major powertrain components (in comparison, a basic, but complete, internal combustion engine system costs approximately US$3,000). To date, most research for automotive applications has focused on proton exchange membrane fuel cells (PEMFCs), because these systems have demonstrated the highest power density. Recently, however, an alternative technology, hydroxide exchange membrane fuel cells (HEMFCs), has gained significant attention, because of the possibility to use stable platinum-group-metal-free catalysts, with inherent, long-term cost advantages. In this Perspective, we discuss the cost profile of PEMFCs and the advantages offered by HEMFCs. In particular, we discuss catalyst development needs for HEMFCs and set catalyst activity targets to achieve performance parity with state-of-the-art automotive PEMFCs. Meeting these targets requires careful optimization of nanostructures to pack high surface areas into a small volume, while maintaining high area-specific activity and favourable pore-transport properties.

  18. Chemical reactions on platinum-group metal surfaces studied by synchrotron-radiation-based spectroscopy

    International Nuclear Information System (INIS)

    Kondoh, Hiroshi; Nakai, Ikuyo; Nagasaka, Masanari; Amemiya, Kenta; Ohta, Toshiaki

    2009-01-01

    A new version of synchrotron-radiation-based x-ray spectroscopy, wave-length-dispersive near-edge x-ray absorption fine structure (dispersive-NEXAFS), and fast x-ray photoelectron spectroscopy have been applied to mechanistic studies on several surface catalytic reactions on platinum-group-metal surfaces. In this review, our approach using above techniques to understand the reaction mechanism and actual application studies on three well-known catalytic surface reactions, CO oxidation on Pt(111) and Pd(111), NO reduction on Rh(111), and H 2 O formation on Pt(111), are introduced. Spectroscopic monitoring of the progress of the surface reactions enabled us to detect reaction intermediates and analyze the reaction kinetics quantitatively which provides information on reaction order, rate constant, pre-exponential factor, activation energy and etc. Such quantitative analyses combined with scanning tunneling microscopy and kinetic Monte Carlo simulations revealed significant contribution of the adsorbate configurations and their dynamic changes to the reaction mechanisms of the above fundamental catalytic surface reactions. (author)

  19. Recovery of Platinum Group Metals from Spent Catalysts Using Iron Chloride Vapor Treatment

    Science.gov (United States)

    Taninouchi, Yu-ki; Okabe, Toru H.

    2018-05-01

    The recovery of platinum group metals (PGMs) from spent automobile catalysts is a difficult process because of their relatively low contents in the scrap. In this study, to improve the efficiency of the existing recycling techniques, a novel physical concentration method involving treatment with FeCl2 vapor has been examined. The reactions occurring between typical catalyst components and FeCl2 vapor are discussed from the thermodynamic point of view, and the validity of the proposed technique was experimentally verified. The obtained results indicate that the vapor treatment at around 1200 K (927 °C) can effectively alloy PGMs (Pt, Pd, and Rh) with Fe, resulting in the formation of a ferromagnetic alloy. It was also confirmed that cordierite and alumina (the major catalyst components) remained unreacted after the vapor treatment, while ceria species were converted into oxychlorides. The samples simulating the automobile catalyst were also subjected to magnetic separation after the treatment with FeCl2 vapor; as a result, PGMs were successfully extracted and concentrated in the form of a magnetic powder. Thus, the FeCl2 vapor treatment followed by magnetic separation can be utilized for recovering PGMs directly from spent catalysts as an effective pretreatment for the currently used recycling methods.

  20. Alkali Metal Cation Affinities of Anionic Main Group-Element Hydrides Across the Periodic Table.

    Science.gov (United States)

    Boughlala, Zakaria; Fonseca Guerra, Célia; Bickelhaupt, F Matthias

    2017-10-05

    We have carried out an extensive exploration of gas-phase alkali metal cation affinities (AMCA) of archetypal anionic bases across the periodic system using relativistic density functional theory at ZORA-BP86/QZ4P//ZORA-BP86/TZ2P. AMCA values of all bases were computed for the lithium, sodium, potassium, rubidium and cesium cations and compared with the corresponding proton affinities (PA). One purpose of this work is to provide an intrinsically consistent set of values of the 298 K AMCAs of all anionic (XH n-1 - ) constituted by main group-element hydrides of groups 14-17 along the periods 2-6. In particular, we wish to establish the trend in affinity for a cation as the latter varies from proton to, and along, the alkali cations. Our main purpose is to understand these trends in terms of the underlying bonding mechanism using Kohn-Sham molecular orbital theory together with a quantitative bond energy decomposition analyses (EDA). © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Development of two-group interfacial area transport equation for confined flow-1. Modeling of bubble interactions

    International Nuclear Information System (INIS)

    Sun, Xiaodong; Kim, Seungjin; Ishii, Mamoru; Beus, Stephen G.

    2003-01-01

    This paper presents the modeling of bubble interaction mechanisms in the two-group interfacial area transport equation (IATE) for confined gas-liquid two-phase flow. The transport equation is applicable to bubbly, cap-turbulent, and churn-turbulent flow regimes. In the two-group IATE, bubbles are categorized into two groups: spherical/distorted bubbles as Group 1 and cap/slug/churn-turbulent bubbles as Group 2. Thus, two sets of equations are used to describe the generation and destruction rates of bubble number density, void fraction, and interfacial area concentration for the two groups of bubbles due to bubble expansion and compression, coalescence and disintegration, and phase change. Five major bubble interaction mechanisms are identified for the gas-liquid two-phase flow of interest, and are analytically modeled as the source/sink terms for the transport equations based on certain assumptions for the confined flow. These models include both intra-group (within a certain group) and inter-group (between two groups) bubble interactions. The comparisons of the prediction by the one-dimensional two-group IATE with experimental data are presented in the second paper of this series. (author)

  2. Metal toxicity affects predatory stream invertebrates less than other functional feeding groups

    International Nuclear Information System (INIS)

    Liess, Matthias; Gerner, Nadine V.; Kefford, Ben J.

    2017-01-01

    Ecosystem effects of heavy metals need to be identified for a retrospective risk assessment, and potential impacts need to be predicted for a prospective risk assessment. In this study, we established a strong correlation between the toxic pressure of dissolved metals and invertebrate species. We compiled available data from a wide geographical range of Australian streams that were contaminated with heavy metals [mainly copper (Cu) and zinc (Zn)] and the corresponding invertebrate communities. Heavy metal toxicity is positively related to the proportion of predators within the invertebrate community, represented by the predator ratio , with an effect threshold range of 2.6 μg/L - 26 μg/L for Cu and 62 μg/L - 617 μg/L for Zn. These effect concentrations are in the ranges of the concentrations identified in model ecosystems and other field investigations and are just above the existing guideline limits. Heavy metals also affects the taxa richness negatively. Other community measures, such as the evenness, number of EPT (Ephemeroptera, Plecoptera, and Trichoptera) taxa, SPEcies At Risk (SPEAR) pesticides or SPEAR salinity were relatively poorly correlated with heavy metal toxicity in the streams. Therefore, we suggest applying the predator ratio within the community as a starting point for an indicator of the dissolved metal toxicity, the SPEAR metals . - Highlights: • Data on dissolved metals and invertebrates were compiled for a wide geographical range. • Heavy metal toxicity was strongly related to the predator ratio. • Ecologically relevant thresholds identified for Cu and Zn were above the guideline limits. - Increasing metal toxicity for Cu and Zn in streams could be related to an increasing predator ratio within the invertebrate community.

  3. Liquid metal flows in manifolds and expansions of insulating rectangular ducts in the plane perpendicular to a strong magnetic field

    International Nuclear Information System (INIS)

    Molokov, S.

    1994-01-01

    It is demonstrated the flow pattern in basic insulating 3-D geometries for the actual and for more advanced liquid-metal blanket concepts and discussed the ways to avoid pressure losses caused by flow redistribution. Flows in several geometries, such as symmetric and non-symmetric 180 turns with and without manifolds, sharp elbows, sharp and linear expansions with and without manifolds, T-junction, etc., have been calculated. They demonstrate high reliability of poloidal concepts of liquid-metal blankets, since they guarantee uniform conditions for heat transfer. If changes of the duct cross-section occur in the plane perpendicular to the magnetic field (ideally a coolant should flow always in the radial-poloidal plane) the disturbances are local and the slug velocity profile is reached roughly at the distance equivalent to one duct width from the manifolds, expansions, etc. The effects of inertia in these flows are unimportant for the determination of the pressure drop and mean velocity profiles in the core of the flow but may favour heat transfer characteristics via instabilities and strongly anisotropic turbulence. (orig./HP) [de

  4. Numerical and experimental modeling of liquid metal thin film flows in a quasi-coplanar magentic field

    Energy Technology Data Exchange (ETDEWEB)

    Morley, Neil B. [Univ. of California, Los Angeles, CA (United States)

    1994-01-01

    Liquid metal film protection of plasma-facing surfaces in fusion reactors is proposed in an effort to counter the adverse effects of high heat and particle fluxes from the burning plasma. Concerns still exist about establishing the required flow in presence of strong magnetic fields and plasma momentum flux typical of a reactor environment. In this work, the flow behavior of the film is examined under such conditions. Analysis of MHD equations as they apply to liquid metal flows with a free surface in the fully-developed limit was undertaken. Solution yields data for velocity profiles and uniform film heights vs key design parameters (channel size, magnetic field magnitude/orientation, channel slope, wall conductivity). These results are compared to previous models to determine accuracy of simplifying assumptions, in particular Hartmann averaging of films along {rvec B}. Effect of a plasma momentum flux on the thin films is also analyzed. The plasma momentum is strong enough in the cases examined to seriously upset the film, especially for lighter elements like Li. Ga performed much better and its possible use is bolstered by calculations. In an experiment in the MeGA-loop MHD facility, coplanar, wide film flow was found to be little affected by the magnetic field due to the elongated nature of the film. Both MHD drag and partial laminarization are observed, supporting the fully- developed film model predictions of the onset of MHD drag and duct flow estimations for flow laminarization.

  5. Numerical and experimental modeling of liquid metal thin film flows in a quasi-coplanar magentic field

    International Nuclear Information System (INIS)

    Morley, N.B.

    1994-01-01

    Liquid metal film protection of plasma-facing surfaces in fusion reactors is proposed in an effort to counter the adverse effects of high heat and particle fluxes from the burning plasma. Concerns still exist about establishing the required flow in presence of strong magnetic fields and plasma momentum flux typical of a reactor environment. In this work, the flow behavior of the film is examined under such conditions. Analysis of MHD equations as they apply to liquid metal flows with a free surface in the fully-developed limit was undertaken. Solution yields data for velocity profiles and uniform film heights vs key design parameters (channel size, magnetic field magnitude/orientation, channel slope, wall conductivity). These results are compared to previous models to determine accuracy of simplifying assumptions, in particular Hartmann averaging of films along rvec B. Effect of a plasma momentum flux on the thin films is also analyzed. The plasma momentum is strong enough in the cases examined to seriously upset the film, especially for lighter elements like Li. Ga performed much better and its possible use is bolstered by calculations. In an experiment in the MeGA-loop MHD facility, coplanar, wide film flow was found to be little affected by the magnetic field due to the elongated nature of the film. Both MHD drag and partial laminarization are observed, supporting the fully- developed film model predictions of the onset of MHD drag and duct flow estimations for flow laminarization

  6. Gas flow rate and powder flow rate effect on properties of laser metal deposited Ti6Al4V

    CSIR Research Space (South Africa)

    Pityana, S

    2013-03-01

    Full Text Available . The powder flow rate and the gas flow rate were varied to study their effect on the physical, metallurgical and mechanical properties of the deposits. The physical properties studied are: the track width, the track height and the deposit weight...

  7. High-Speed Synchrotron X-ray Imaging Studies of the Ultrasound Shockwave and Enhanced Flow during Metal Solidification Processes

    Science.gov (United States)

    Tan, Dongyue; Lee, Tung Lik; Khong, Jia Chuan; Connolley, Thomas; Fezzaa, Kamel; Mi, Jiawei

    2015-07-01

    The highly dynamic behavior of ultrasonic bubble implosion in liquid metal, the multiphase liquid metal flow containing bubbles and particles, and the interaction between ultrasonic waves and semisolid phases during solidification of metal were studied in situ using the complementary ultrafast and high-speed synchrotron X-ray imaging facilities housed, respectively, at the Advanced Photon Source, Argonne National Laboratory, US, and Diamond Light Source, UK. Real-time ultrafast X-ray imaging of 135,780 frames per second revealed that ultrasonic bubble implosion in a liquid Bi-8 wt pctZn alloy can occur in a single wave period (30 kHz), and the effective region affected by the shockwave at implosion was 3.5 times the original bubble diameter. Furthermore, ultrasound bubbles in liquid metal move faster than the primary particles, and the velocity of bubbles is 70 ~ 100 pct higher than that of the primary particles present in the same locations close to the sonotrode. Ultrasound waves can very effectively create a strong swirling flow in a semisolid melt in less than one second. The energetic flow can detach solid particles from the liquid-solid interface and redistribute them back into the bulk liquid very effectively.

  8. Synthesis, characterization, vibrational spectroscopy, and factor group analysis of partially metal-doped phosphate materials

    Science.gov (United States)

    Sronsri, Chuchai; Boonchom, Banjong

    2018-04-01

    A simple precipitating method was used to synthesize effectively a partially metal-doped phosphate hydrate (Mn0.9Mg0.1HPO4·3H2O), whereas the thermal decomposition process of the above hydrate precursor was used to obtain Mn1.8Mg0.2P2O7 and LiMn0.9Mg0.1PO4 compounds under different conditions. To separate the overlapping thermal decomposition peak, a deconvolution technique was used, and the separated peak was applied to calculate the water content. The factor group splitting analysis was used to exemplify their vibrational spectra obtained from normal vibrations of HPO42-, H2O, P2O74- and PO43- functional groups. Further, the deconvoluted bending mode of water was clearly observed. Mn0.9Mg0.1HPO4·3H2O was observed in the orthorhombic crystal system with the space group of Pbca (D2h15). The formula units per unit cell were found to be eight (Z = 8), and the site symmetric type of HPO42- was observed as Cs. For the HPO42- unit, the correlation filed splitting analysis of type C3v - Cs - D2h15 was calculated and had 96 internal modes, whereas H2O in the above hydrate was symbolized as C2v - Cs - D2h15 and had 24 modes. The symbol C2v - Cs - C2h3 was used for the correlation filed splitting analysis of P2O74- in Mn1.8Mg0.2P2O7 (monoclinic, C2/m (C2h3), Z = 2, and 42 modes). Finally, the symbol Td - Cs - D2h16 was used for the correlation filed splitting analysis of PO43- in LiMn0.9Mg0.1PO4 (orthorhombic, Pnma (D2h16), Z = 4, and 36 modes).

  9. Multiplicity dependence of matrix-induced frequency shifts for atomic transitions of the group 12 metals in rare gas solids

    International Nuclear Information System (INIS)

    Laursen, S.L.; Cartland, H.E.

    1991-01-01

    Atomic resonances of the group 12 metal atoms, Hg, Cd, and Zn, undergo frequency shifts from the gas phase atomic line when trapped in rare gas matrices of Ar, Kr, and Xe at 12 K. As expected, the shifts are approximately linear in polarizability of the rare gas, but the slope of this line depends on whether the transition in question is 1 P 1 left-arrow 1 S 0 or 3 P 1 left-arrow 1 S 0 . Thus the matrix-induced frequency shift is dependent on the singlet or triplet nature of the excited state as well as on the matrix material. This dependence on multiplicity is discussed in terms of interactions between the excited-state atomic orbitals and the matrix. The results are compared to matrix studies of other metals and to related gas-phase work on diatomic van der Waals complexes of group 12 metals with rare gases

  10. Flow measurement and thrust estimation of a vibrating ionic polymer metal composite

    International Nuclear Information System (INIS)

    Chae, Woojin; Cha, Youngsu; Peterson, Sean D; Porfiri, Maurizio

    2015-01-01

    Ionic polymer metal composites (IPMCs) are an emerging class of soft active materials that are finding growing application as underwater propulsors for miniature biomimetic swimmers. Understanding the hydrodynamics generated by an IPMC vibrating under water is central to the design of such biomimetic swimmers. In this paper, we propose the use of time-resolved particle image velocimetry to detail the fluid kinematics and kinetics in the vicinity of an IPMC vibrating along its fundamental structural mode. The reconstructed pressure field is ultimately used to estimate the thrust produced by the IPMC. The vibration frequency is systematically varied to elucidate the role of the Reynolds number on the flow physics and the thrust production. Experimental results indicate the formation and shedding of vortical structures from the IPMC tip during its vibration. Vorticity shedding is sustained by the pressure gradients along each side of the IPMC, which are most severe in the vicinity of the tip. The mean thrust is found to robustly increase with the Reynolds number, closely following a power law that has been derived from direct three-dimensional numerical simulations. A reduced order distributed model is proposed to describe IPMC underwater vibration and estimate thrust production, offering insight into the physics of underwater propulsion and aiding in the design of IPMC-based propulsors. (paper)

  11. Experimental study on flow characteristics of a vertically falling film flow of liquid metal NaK in a transverse magnetic field

    International Nuclear Information System (INIS)

    Li Fengchen; Serizawa, Akimi

    2004-01-01

    Experimental study was carried out on the characteristics of a vertically falling film flow of liquid metal sodium-potassium alloy (NaK-78) in a vertical square duct in the presence of a transverse magnetic field. The magnitude of the applied magnetic field was up to 0.7 T. The Reynolds number, defined by the hydraulic diameter based on the wetted perimeter length and the liquid average velocity, ranged from 8.0x10 3 to 3.0x10 4 . The free surfaces of the falling film flows in both a stainless steel and an acrylic resin channels were visualized. The instantaneous film thickness of the falling film flow in the acrylic resin channel was then measured by means of the ultrasonic transmission technique. Magnetohydrodynamic (MHD) effects on the characteristics of the falling film flow were investigated by the visualization and the statistical analysis of the measured film thickness. It was found that the falling liquid NaK film was thickened and the flow was stabilized remarkably by a strong transverse magnetic field. A bifurcation of the film was recovered by the applied magnetic field. The turbulence of the flow was substantially suppressed

  12. Computational and experimental studies of the flow field near the beam entrance window of a liquid metal target

    International Nuclear Information System (INIS)

    Geža, Vadims; Milenković, Rade Ž.; Kapulla, Ralf; Dementjevs, Sergejs; Jakovičs, Andris; Wohlmuther, Michael

    2014-01-01

    Highlights: • Water model of liquid metal target for validation of CFD models was built. • PIV measurements showed flow features in the region near beam entrance window. • The zones with high turbulence kinetic energy were distinguished. • Reasonable agreement between modeling and PIV data was obtained. - Abstract: After the first world liquid metal target has been successfully operated at the SINQ facility at the Paul Scherrer Institut (PSI) for 6 months. The idea of having a reliable target with a bypass flow for cooling the beam entrance window, but with the bypass flow not driven by a separate pump, was examined within the project called LIMETS (Liquid Metal Target for SINQ). In designing of liquid metal targets, turbulence modelling is of high importance due to lack in methods for measuring the spatial distribution of flow and turbulence characteristics. In this study, validation of different turbulence models were performed in water model with hemispherical geometry using particle image velocimetry (PIV) technique. Two components of water flow velocity in plexiglas container with inner radius of 88 mm were measured in different cross sections, with the velocities varying from 1 to 10 m/s. Numerical calculations using large eddy simulation (LES) approach and Reynolds averaged Navier–Stokes (RANS) models were carried out to validate their applicability and study performance issues. Mean velocity and turbulence kinetic energy data were used for comparison of PIV and calculation results. Reasonable agreement was obtained for mean velocity data, with some discrepancies due to the limited length of the inlet tube. However, several discrepancies in turbulence characteristics were found in numerical results, especially in RANS model calculations

  13. Modifications of chemical functional groups of Pandanus amaryllifolius Roxb and its effect towards biosorption of heavy metals

    International Nuclear Information System (INIS)

    Abdullah, Mohd Zamri; Ismail, Siti Salwa

    2015-01-01

    The utilization of non-living biomass as an alternative biosorbent for heavy metal removal has gain a tremendous consideration through the years. Pandanus amaryllifolius Roxb or pandan leaves, which is widely used as food additives in the South East Asia region, has been selected for its viability in the said effort due to the presence of chemical functional groups on its cellular network that enables the sorption to occur. In order to elucidate the possible mechanisms participated during the heavy metal removal process, the biosorbent undergone a series of modification techniques to alter the chemical functional groups present on its constituent. From the outcome of the chemically-modified biosorbent being subjected to the contact with metal cations, nitrogen- and oxygen-containing groups present on the biosorbent are believed to be responsible for the metal uptake to occur through complexation mechanism. Modifying amine groups causes 14% reduction of Cu(II) uptake, whereas removing protein element increases the uptake to 26% as compared to the unmodified biosorbent. Also, scanning electron micrographs further suggested that the adsorption mechanism could perform in parallel, as attributed to the evidence of porous structure throughout the biosorbent fibrous nature

  14. Modifications of chemical functional groups of Pandanus amaryllifolius Roxb and its effect towards biosorption of heavy metals

    Energy Technology Data Exchange (ETDEWEB)

    Abdullah, Mohd Zamri, E-mail: zamriab@petronas.com.my; Ismail, Siti Salwa [Chemical Engineering Department, Universiti Teknologi PETRONAS, 31750 Bandar Seri Iskandar, Perak (Malaysia)

    2015-07-22

    The utilization of non-living biomass as an alternative biosorbent for heavy metal removal has gain a tremendous consideration through the years. Pandanus amaryllifolius Roxb or pandan leaves, which is widely used as food additives in the South East Asia region, has been selected for its viability in the said effort due to the presence of chemical functional groups on its cellular network that enables the sorption to occur. In order to elucidate the possible mechanisms participated during the heavy metal removal process, the biosorbent undergone a series of modification techniques to alter the chemical functional groups present on its constituent. From the outcome of the chemically-modified biosorbent being subjected to the contact with metal cations, nitrogen- and oxygen-containing groups present on the biosorbent are believed to be responsible for the metal uptake to occur through complexation mechanism. Modifying amine groups causes 14% reduction of Cu(II) uptake, whereas removing protein element increases the uptake to 26% as compared to the unmodified biosorbent. Also, scanning electron micrographs further suggested that the adsorption mechanism could perform in parallel, as attributed to the evidence of porous structure throughout the biosorbent fibrous nature.

  15. Core fracture analysis applied to ground water flow systems: Chickamauga Group, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    Bittner, E.; Dreier, R.B.

    1989-01-01

    The objective of this study is to correlate hydrologic properties with detailed geologic fabrics and to investigate the influence of a complex geologic setting on ground water systems. The Chickamauga Group (CH) located in Bethel Valley on the DOE Oak Ridge Reservation is comprised of limestones and interbedded shales. Five core holes (CH 1-5), oriented across strike, provide a cross section of the CH and were mapped for fracture density, orientation and cross-cutting relationships as well as lithologic variations. Correlation of structural and lithologic features with downhole geophysical logs and hydraulic conductivity values shows a relationship between lithology, fracture density and increased permeability in an otherwise low-permeability environment. Structures identified as influential in enhancing hydraulic conductivity include contractional bedding plane and tectonic stylolites and extensional fractures. Three sets of extensional fractures are indicated by cross-cutting relationships and various degrees of veining. Hydraulic conductivity values (K) for the five wells indicate two ground water flow systems in the valley. A shallow system (up to 150 feet deep) shows a range in K from 10E-4 centimeters per second to 10E-6 centimeters per second. Shallow horizons show more open fractures than are observed at depth, and these fractures appear to control the enhanced K in the shallow system. A subhorizontal interface that is not defined by pre-existing structures or a stratigraphic horizon separates the two flow systems. The deeper system ranges in K values from 10E-9 centimeters per second to 10E-5 centimeters per second. The higher K values at depth correspond to increased fracture density at lithologic contacts, zones of tectonic stylolitization and partially veined extension fractures. 11 refs., 11 figs., 2 tabs

  16. Preparation of New Adsorbent Containing Hydroxamic Acid Groups by Electron Beam-Induced Grafting for Metal Ion Adsorption

    International Nuclear Information System (INIS)

    Suwanmala, Phiriyatorn; Hoshina, Hiroyuki; Seko, Noriaki; Tamada, Masao

    2007-08-01

    Full text: A new adsorbent containing hydroxamic acid groups was synthesized by electron beam-induced graft copolymerization of methyl acrylate (MA) onto nonwoven fabric composed of polyethylene-coated polypropylene fiber. Conversion of ester groups of the grafted copolymer into the hydroxamic groups was performed by treatment with an alkaline solution of hydroxylamine (HA). Adsorbent containing hydroxamic acid groups can adsorb 99% of UO2 2+ , 98% of V5+, 97% of Pb2+ and 96% of Al3+ at pH, 5, 4, 6, and 4, respectively, after coming into contact with 100 ppb metal solution for 24 h

  17. Teaching - methodical and research center of hydrogen power engineering and platinum group metals in the former Soviet Union countries

    International Nuclear Information System (INIS)

    Evdokimov, A.A; Sigov, A.S; Shinkarenko, V.V.

    2005-01-01

    Full text: Teaching - Methodical and Research Center (TMRC) 'Sokolinaja Gora' is founded in order to provide methodical-information and scientific support of institutes of higher education in the field of hydrogen power engineering and platinum group metals in Russia and in the countries of the Former Soviet union. It is independent association of creative communities of scientist of higher educational specialists. The main directions of the Center activity are: 1. Teaching-methodological support and development of teaching in the field of hydrogen power engineering and platinum group metals in Russia in the countries of the Former Soviet Union. Themes of teaching includes the basic of safe using of hydrogen technologies and devices, ecological, economic and law aspects of new hydrogen power engineering, transition to which in 21 century is one of the central problems of mankind survival; 2. Organizing of joint researches by independent creative communities of scientists in the field of hydrogen power engineering and platinum group metal; 3. Independent scientific examination, which is made by Advisory Committee of High Technologies consisting of representatives of the countries of Former Soviet Union, which are standing participants of an Annual International Symposia 'Hydrogen Power Engineering and Platinum Group Metals in the Former Soviet Union Countries'. Structure of the Center: 1. Center of strategic development in the field of high technologies; 2. Scientific Research Institute of Hydrogen Power Engineering and Platinum Group Metals; 3. Teaching-Methodical Association in specialization 'Hydrogen Power Engineering and economics' and hydrogen wide spread training; 4. Media Center 'Hydrogen Power Engineering and Platinum Group Metals', 5. Organizational Center; 6. Administrative Center. The Center will be established step-by-step in 2005-2010 on the basis of the following programs: Teaching-methodological program. On the basis of this program it is planned to

  18. Nanoindentation study on the characteristic of shear transformation zone in a Pd-based bulk metallic glass during serrated flow

    Science.gov (United States)

    Liao, G. K.; Long, Z. L.; Zhao, M. S. Z.; Peng, L.; Chai, W.; Ping, Z. H.

    2018-04-01

    This paper presents the research on the evolution of shear transformation zone (STZ) in a Pd-based bulk metallic glass (BMG) during serrated flow under nanoindentation. A novel method of estimating the STZ volume through statistical analysis of the serrated flow behavior was proposed for the first time. Based on the proposed method, the STZ volume of the studied BMG at various peak loads have been systematically investigated. The results indicate that the measured STZ volumes are in good agreement with that documented in literature, and the STZ size exhibits an increasing trend during indentation. Moreover, the correlation between the serrated flow dynamics and the STZ activation has also been evaluated. It is found that the STZ activation can promote the formation of self-organized critical (SOC) state during serrated flow.

  19. η5 and η6 - cyclic π-perimeter hydrocarbon platinum group metal ...

    Indian Academy of Sciences (India)

    The SMART20 software was used for data acquisition. ... were undertaken with the SAINT20 software. Structures ..... the change in electron density around the metal centre. .... request@ccdc.cam.ac.uk, or by contacting The Cambridge.

  20. An induction-based magnetohydrodynamic 3D code for finite magnetic Reynolds number liquid-metal flows in fusion blankets

    International Nuclear Information System (INIS)

    Kawczynski, Charlie; Smolentsev, Sergey; Abdou, Mohamed

    2016-01-01

    Highlights: • A new induction-based magnetohydrodynamic code was developed using a finite difference method. • The code was benchmarked against purely hydrodynamic and MHD flows for low and finite magnetic Reynolds number. • Possible applications of the new code include liquid-metal MHD flows in the breeder blanket during unsteady events in the plasma. - Abstract: Most numerical analysis performed in the past for MHD flows in liquid-metal blankets were based on the assumption of low magnetic Reynolds number and involved numerical codes that utilized electric potential as the main electromagnetic variable. One limitation of this approach is that such codes cannot be applied to truly unsteady processes, for example, MHD flows of liquid-metal breeder/coolant during unsteady events in plasma, such as major plasma disruptions, edge-localized modes and vertical displacements, when changes in plasmas occur at millisecond timescales. Our newly developed code MOONS (Magnetohydrodynamic Object-Oriented Numerical Solver) uses the magnetic field as the main electromagnetic variable to relax the limitations of the low magnetic Reynolds number approximation for more realistic fusion reactor environments. The new code, written in Fortran, implements a 3D finite-difference method and is capable of simulating multi-material domains. The constrained transport method was implemented to evolve the magnetic field in time and assure that the magnetic field remains solenoidal within machine accuracy at every time step. Various verification tests have been performed including purely hydrodynamic flows and MHD flows at low and finite magnetic Reynolds numbers. Test results have demonstrated very good accuracy against known analytic solutions and other numerical data.

  1. An induction-based magnetohydrodynamic 3D code for finite magnetic Reynolds number liquid-metal flows in fusion blankets

    Energy Technology Data Exchange (ETDEWEB)

    Kawczynski, Charlie; Smolentsev, Sergey, E-mail: sergey@fusion.ucla.edu; Abdou, Mohamed

    2016-11-01

    Highlights: • A new induction-based magnetohydrodynamic code was developed using a finite difference method. • The code was benchmarked against purely hydrodynamic and MHD flows for low and finite magnetic Reynolds number. • Possible applications of the new code include liquid-metal MHD flows in the breeder blanket during unsteady events in the plasma. - Abstract: Most numerical analysis performed in the past for MHD flows in liquid-metal blankets were based on the assumption of low magnetic Reynolds number and involved numerical codes that utilized electric potential as the main electromagnetic variable. One limitation of this approach is that such codes cannot be applied to truly unsteady processes, for example, MHD flows of liquid-metal breeder/coolant during unsteady events in plasma, such as major plasma disruptions, edge-localized modes and vertical displacements, when changes in plasmas occur at millisecond timescales. Our newly developed code MOONS (Magnetohydrodynamic Object-Oriented Numerical Solver) uses the magnetic field as the main electromagnetic variable to relax the limitations of the low magnetic Reynolds number approximation for more realistic fusion reactor environments. The new code, written in Fortran, implements a 3D finite-difference method and is capable of simulating multi-material domains. The constrained transport method was implemented to evolve the magnetic field in time and assure that the magnetic field remains solenoidal within machine accuracy at every time step. Various verification tests have been performed including purely hydrodynamic flows and MHD flows at low and finite magnetic Reynolds numbers. Test results have demonstrated very good accuracy against known analytic solutions and other numerical data.

  2. Liquid Metal Transformers

    OpenAIRE

    Sheng, Lei; Zhang, Jie; Liu, Jing

    2014-01-01

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series...

  3. Fate of heavy metals in vertical subsurface flow constructed wetlands treating secondary treated petroleum refinery wastewater in Kaduna, Nigeria.

    Science.gov (United States)

    Mustapha, Hassana Ibrahim; van Bruggen, J J A; Lens, P N L

    2018-01-02

    This study examined the performance of pilot-scale vertical subsurface flow constructed wetlands (VSF-CWs) planted with three indigenous plants, i.e. Typha latifolia, Cyperus alternifolius, and Cynodon dactylon, in removing heavy metals from secondary treated refinery wastewater under tropical conditions. The T. latifolia-planted VSF-CW had the best heavy metal removal performance, followed by the Cyperus alternifolius-planted VSF-CW and then the Cynodon dactylon-planted VSF-CW. The data indicated that Cu, Cr, Zn, Pb, Cd, and Fe were accumulated in the plants at all the three VSF-CWs. However, the accumulation of the heavy metals in the plants accounted for only a rather small fraction (0.09-16%) of the overall heavy metal removal by the wetlands. The plant roots accumulated the highest amount of heavy metals, followed by the leaves, and then the stem. Cr and Fe were mainly retained in the roots of T. latifolia, Cyperus alternifolius, and Cynodon dactylon (TF < 1), meaning that Cr and Fe were only partially transported to the leaves of these plants. This study showed that VSF-CWs planted with T. latifolia, Cyperus Alternifolius, and Cynodon dactylon can be used for the large-scale removal of heavy metals from secondary refinery wastewater.

  4. Ion mobility studies of carbohydrates as group I adducts: isomer specific collisional cross section dependence on metal ion radius.

    Science.gov (United States)

    Huang, Yuting; Dodds, Eric D

    2013-10-15

    Carbohydrates play numerous critical roles in biological systems. Characterization of oligosaccharide structures is essential to a complete understanding of their functions in biological processes; nevertheless, their structural determination remains challenging in part due to isomerism. Ion mobility spectrometry provides the means to resolve gas phase ions on the basis of their shape-to-charge ratios, thus providing significant potential for separation and differentiation of carbohydrate isomers. Here, we report on the determination of collisional cross sections for four groups of isomeric carbohydrates (including five isomeric disaccharides, four isomeric trisaccharides, two isomeric pentasaccharides, and two isomeric hexasaccharides) as their group I metal ion adducts (i.e., [M + Li](+), [M + Na](+), [M + K](+), [M + Rb](+), and [M + Cs](+)). In all, 65 collisional cross sections were measured, the great majority of which have not been previously reported. As anticipated, the collisional cross sections of the carbohydrate metal ion adducts generally increase with increasing metal ion radius; however, the collisional cross sections were found to scale with the group I cation size in isomer specific manners. Such measurements are of substantial analytical value, as they illustrate how the selection of charge carrier influences carbohydrate ion mobility determinations. For example, certain pairs of isomeric carbohydrates assume unique collisional cross sections upon binding one metal ion, but not another. On the whole, these data suggest a role for the charge carrier as a probe of carbohydrate structure and thus have significant implications for the continued development and application of ion mobility spectrometry for the distinction and resolution of isomeric carbohydrates.

  5. Metal temperature monitoring in corrosive gases at high temperature and high thermal flows; Monitoreo de temperaturas de metal en gases corrosivos a alta temperatura y altos flujos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Huerta Espino, Mario; Martinez Flores, Marco Antonio; Martinez Villafane, Alberto; Porcayo Calderon, Jesus; Gomez Guzman, Roberto; Reyes Cervantes, Fernando [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1990-12-31

    The direct measurement of metal temperatures during operation in superheater, reheater, and water wall tubes in zones exposed to high thermal flows is of great interest for the operation and analysis of the correct functioning of a steam generator. The operation temperature measurement of these zones differs very much of the monitored temperature in headers in the dead chamber, since the temperature measured in this zone is the steam temperature that does not reflect the one detected in the gas zone. For this reason, the thermocouples implant in gas zones will detect the real metal temperature and the incidence that some operation variables might have on it (Martinez et al., (1990). [Espanol] La medicion directa de temperaturas de metal durante operacion en tubos de sobrecalentador, recalentador y pared de agua en zonas expuestas a altos flujos termicos es de gran interes para la operacion y analisis del buen funcionamiento de un generador de vapor. La medicion de la temperatura de operacion de estas zonas, difiere mucho de la temperatura monitoreada en cabezales en zona de camara muerta, ya que la temperatura registrada en esta zona es la de vapor que no es un reflejo de la detectada en zona de gases. Por esta razon, la implantacion de termopares en zona de gases detectara la temperatura de metal real y la incidencia que algunas variables de operacion tengan sobre esta (Martinez et al., 1990).

  6. Metal temperature monitoring in corrosive gases at high temperature and high thermal flows; Monitoreo de temperaturas de metal en gases corrosivos a alta temperatura y altos flujos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Huerta Espino, Mario; Martinez Flores, Marco Antonio; Martinez Villafane, Alberto; Porcayo Calderon, Jesus; Gomez Guzman, Roberto; Reyes Cervantes, Fernando [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1991-12-31

    The direct measurement of metal temperatures during operation in superheater, reheater, and water wall tubes in zones exposed to high thermal flows is of great interest for the operation and analysis of the correct functioning of a steam generator. The operation temperature measurement of these zones differs very much of the monitored temperature in headers in the dead chamber, since the temperature measured in this zone is the steam temperature that does not reflect the one detected in the gas zone. For this reason, the thermocouples implant in gas zones will detect the real metal temperature and the incidence that some operation variables might have on it (Martinez et al., (1990). [Espanol] La medicion directa de temperaturas de metal durante operacion en tubos de sobrecalentador, recalentador y pared de agua en zonas expuestas a altos flujos termicos es de gran interes para la operacion y analisis del buen funcionamiento de un generador de vapor. La medicion de la temperatura de operacion de estas zonas, difiere mucho de la temperatura monitoreada en cabezales en zona de camara muerta, ya que la temperatura registrada en esta zona es la de vapor que no es un reflejo de la detectada en zona de gases. Por esta razon, la implantacion de termopares en zona de gases detectara la temperatura de metal real y la incidencia que algunas variables de operacion tengan sobre esta (Martinez et al., 1990).

  7. Understanding hydrogen sorption in a metal-organic framework with open-metal sites and amide functional groups

    KAUST Repository

    Pham, Tony T.; Forrest, Katherine A.; Nugent, Patrick S.; Belmabkhout, Youssef; Luebke, Ryan; Eddaoudi, Mohamed; Zaworotko, Michael J.; Space, Brian

    2013-01-01

    of the copper ions via chemical substitution on the MOF framework can be explained by the presence of the negatively charged oxygen atom of the amide group that causes the interior Cu2+ ion to exhibit a higher positive charge through an inductive effect. Further

  8. Characterization of binding and mobility of metals and xenobiotics in continuous flow and soil biosystems

    International Nuclear Information System (INIS)

    Sunovska, A.

    2016-01-01

    The main aim of the dissertation thesis was to contribute to development of analytical tools and approaches application in characterization of binding and mobility of heavy metals and organic compounds (xenobiotics) in continuous flow and soil biosystems. Within the solution of this aim, a wide range of analytical methods (gamma-spectrometry, UV-VIS spectrophotometry, AAS, X-ray fluorescence spectrometry, ion chromatography, and stripping volt-amperometry) and approaches (mathematical modelling - methods of nonlinear regression and in silico prediction modelling; chemometrics and statistical analysis of the data; single-step extraction methods, and lysimetry) were applied. In the first step of thesis solution, alternative sorbents of biological origin (biomass of microalgae, freshwater mosses, and waste biomass of hop) were obtained and physico-chemically characterized mainly in order to prediction of sorption capacities of Cd and synthetic dyes thioflavine T (TT), malachite green (MG) or methylene blue (MB) removal from single component or binary aqueous solutions and under conditions of batch or continuous flow systems. For these purposes, mathematical models of adsorption isotherms and models originated from chromatographic separation methods by application of methods of nonlinear regression analysis were used. In the second part of the work, methods of multivariate analysis in the evaluation of processes of synthetic dyes TT and MB binding in terms of the finding of relationships between sorption-desorption variables describing the stability of the bond and parameters defining the physic-chemical properties of river sediments and the environment of real or model waters were applied. In the last part of the work, a special laboratory lysimeter system was designed and applied within the soil biosystem defined by: soil additive (SA) derived from sewage sludge representing the source of microelements Zn and Cu <-> agriculturally used soil <-> soil solution <-> root

  9. Characterization of binding and mobility of metals and xenobiotics in continuous flow and soil biosystems

    International Nuclear Information System (INIS)

    Sunovska, A.

    2016-01-01

    The main aim of the dissertation thesis was to contribute to development of analytical tools and approaches application in characterization of binding and mobility of heavy metals and organic compounds (xenobiotics) in continuous flow and soil biosystems. Within the solution of this aim, a wide range of analytical methods (gamma-spectrometry, UV-VIS spectrophotometry, AAS, X-ray fluorescence spectrometry, ion chromatography, and stripping volt-amperometry) and approaches (mathematical modelling - methods of nonlinear regression and in silico prediction modelling; chemometrics and statistical analysis of the data; single-step extraction methods, and lysimetry) were applied. In the first step of thesis solution, alternative sorbents of biological origin (biomass of microalgae, freshwater mosses, and waste biomass of hop) were obtained and physico-chemically characterized mainly in order to prediction of sorption capacities of Cd and synthetic dyes thioflavine T (TT), malachite green (MG) or methylene blue (MB) removal from single component or binary aqueous solutions and under conditions of batch or continuous flow systems. For these purposes, mathematical models of adsorption isotherms and models originated from chromatographic separation methods by application of methods of nonlinear regression analysis were used. In the second part of the work, methods of multivariate analysis in the evaluation of processes of synthetic dyes TT and MB binding in terms of the finding of relationships between sorption-desorption variables describing the stability of the bond and parameters defining the physic-chemical properties of river sediments and the environment of real or model waters were applied. In the last part of the work, a special laboratory lysimeter system was designed and applied within the soil biosystem defined by: soil additive (SA) derived from sewage sludge representing the source of microelements Zn and Cu agriculturally used soil soil solution root system of

  10. Renormalization Group Flows from Holography-Supersymmetry and a c-Theorem

    CERN Document Server

    Freedman, D.Z.; Pilch, K.; Warner, N.P.

    1999-01-01

    We obtain first order equations that determine a supersymmetric kink solution in five-dimensional N=8 gauged supergravity. The kink interpolates between an exterior anti-de Sitter region with maximal supersymmetry and an interior anti-de Sitter region with one quarter of the maximal supersymmetry. One eighth of supersymmetry is preserved by the kink as a whole. We interpret it as describing the renormalization group flow in N=4 super-Yang-Mills theory broken to an N=1 theory by the addition of a mass term for one of the three adjoint chiral superfields. A detailed correspondence is obtained between fields of bulk supergravity in the interior anti-de Sitter region and composite operators of the infrared field theory. We also point out that the truncation used to find the reduced symmetry critical point can be extended to obtain a new N=4 gauged supergravity theory holographically dual to a sector of N=2 gauge theories based on quiver diagrams. We consider more general kink geometries and construct a c-function...

  11. Thermal convection in a toroidal duct of a liquid metal blanket. Part II. Effect of axial mean flow

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xuan, E-mail: xuanz@umich.edu; Zikanov, Oleg

    2017-03-15

    Highlights: • 2D convection flow develops with internal heating and strong axial magnetic field. • The flow is strongly modified by the buoyancy force associated with growing T{sub m}. • Thermal convection is suppressed at high Gr. • High temperature difference between top and bottom walls is expected at high Gr. - Abstract: The work continues the exploration of the effect of thermal convection on flows in toroidal ducts of a liquid metal blanket. This time we consider the effect of the mean flow along the duct and of the associated heat transfer diverting the heat deposited by captured neutrons. Numerical simulations are conducted for a model system with two-dimensional (streamwise-uniform) fully developed flow, purely toroidal magnetic field, and perfectly electrically and thermally insulating walls. Realistically high Grashof (up to 10{sup 11}) and Reynolds (up to 10{sup 6}) numbers are used. It is found that the flow develops thermal convection in the transverse plane at moderate Grashof numbers. At large Grashof numbers, the flow is dominated by the top-bottom asymmetry of the streamwise velocity and stable stratification of temperature, which are caused by the buoyancy force due to the mean temperature growing along the duct. This leads to suppression of thermal convection, weak mixing, and substantial gradients of wall temperature. Further analysis based on more realistic models is suggested.

  12. Investigations on the enrichment behaviour of toxic heavy metals in the mass flows of a coal power station

    International Nuclear Information System (INIS)

    Biehusen, U.

    1980-01-01

    In the present work solid sample material from a coal power plant has been analyzed, and by means of establishing a mass balance and calculating enrichment factors the question of how the heavy-metals having entered the power plant via the coal are distributed over the individual mass flows leaving the plant has been explained. Radioactive substances that get into the plant with the uranium and thorium contained in the coal have been considered in the same way. (orig./EF) [de

  13. Improved oxidation resistance of group VB refractory metals by Al+ ion implantation

    International Nuclear Information System (INIS)

    Hampikian, J.M.

    1996-01-01

    Aluminum ion implantation of vanadium, niobium, and tantalum improved the metals' oxidation resistances at 500 C and 735 C. Implanted vanadium oxidized only to one-third the extent of unimplanted vanadium when exposed at 500 C to air. The oxidative weight gains of implanted niobium and tantalum proved negligible when measured at 500 C and for times sufficient to fully convert the untreated metals to their pentoxides. At 735 C, implantation of vanadium only slightly retarded its oxidation, while oxidative weight gains of niobium and tantalum were reduced by factors of 3 or more. Implanted niobium exhibited weight gain in direct proportion to oxidation time squared at 735 C. Microstructural examination of the metals implanted with selected fluences of the 180 kV aluminum ions showed the following. The solubility limit of aluminum is extended by implantation, the body centered cubic (bcc) phases being retained to ∼60 at. pct Al in all three metals. The highest fluence investigated, 2.4 x 10 22 ions/m 2 , produced an ∼400-nm layer of VAl 3 beneath the surface of vanadium, and ∼300-nm layers of an amorphous phase containing ∼70 at. pct Al beneath the niobium and tantalum surfaces. All three metals, implanted to this fluence and annealed at 600 C, contained tri-aluminides, intermetallic compounds known for their oxidation resistances. Specimens implanted to this fluence were thus selected for the oxidation measurements

  14. Synthesis and characterization of group V metal carbide and nitride catalysts

    Science.gov (United States)

    Kwon, Heock-Hoi

    1998-11-01

    Group V transition metal carbides and nitrides were prepared via the temperature programmed reaction (TPR) of corresponding oxides with NHsb3 or a CHsb4/Hsb2 mixture. Except for the tantalum compounds, phase-pure carbides and nitrides were prepared. The vanadium carbides and nitrides were the most active and selective catalysts. Therefore the principal focus of the research was the preparation, characterization, and evaluation of high surface area vanadium nitride catalysts. A series of vanadium nitrides with surface areas up to 60 msp2/g was prepared. Thermal gravimetric analysis coupled with x-ray diffraction and scanning electron microscopy indicated that the solid-state reaction proceeded by the sequential reduction of Vsb2Osb5 to VOsb{0.9} and concluded with the topotactic substitution of nitrogen for oxygen in VOsb{0.9}. The transformation of Vsb2Osb5 to VN was pseudomorphic. An experimental design was executed to determine effects of the heating rates and space velocities on the VN microstructures. The heating rates had minor effects on the surface areas and pore size distributions; however, increasing the space velocity significantly increased the surface area. The materials were mostly mesoporous. Oxygen chemisorption on the vanadium nitrides scaled linearly with the surface area. The corresponding O/Vsbsurface ratio was ≈0.6. The vanadium nitrides were active for butane activation and pyridine hydrodenitrogenation. During butane activation, their selectivities towards dehydrogenation products were as high as 98%. The major product in pyridine hydrodenitrogenation was pentane. The reaction rates increased almost linearly with the surface area suggesting that these reactions were structure insensitive. The vanadium nitrides were not active for crotonaldehyde hydrogenation; however, they catalyzed an interesting ring formation reaction that produced methylbenzaldehyde and xylene from crotonaldehyde. A new method was demonstrated for the production of very

  15. Laminated exfoliated graphite composite-metal compositions for fuel cell flow field plate or bipolar plate applications

    Science.gov (United States)

    Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z

    2014-05-20

    An electrically conductive laminate composition for fuel cell flow field plate or bipolar plate applications. The laminate composition comprises at least a thin metal sheet having two opposed exterior surfaces and a first exfoliated graphite composite sheet bonded to the first of the two exterior surfaces of the metal sheet wherein the exfoliated graphite composite sheet comprises: (a) expanded or exfoliated graphite and (b) a binder or matrix material to bond the expanded graphite for forming a cohered sheet, wherein the binder or matrix material is between 3% and 60% by weight based on the total weight of the first exfoliated graphite composite sheet. Preferably, the first exfoliated graphite composite sheet further comprises particles of non-expandable graphite or carbon in the amount of between 3% and 60% by weight based on the total weight of the non-expandable particles and the expanded graphite. Further preferably, the laminate comprises a second exfoliated graphite composite sheet bonded to the second surface of the metal sheet to form a three-layer laminate. Surface flow channels and other desired geometric features can be built onto the exterior surfaces of the laminate to form a flow field plate or bipolar plate. The resulting laminate has an exceptionally high thickness-direction conductivity and excellent resistance to gas permeation.

  16. Vibration of a group of circular cylinders subjected to fluid flow

    International Nuclear Information System (INIS)

    Chen, S.

    1981-01-01

    Many structural and mechanical components consist of multiple circular cylinders, such as heat exchanger tubes and nuclear fuel bundles. These components are subjected to fluid flow. The fluid flow represents a source of energy that can induce and sustain vibration. The fluid moving with vibrating structures has an important effect on the dynamic characteristics of the structure. The objective of this paper is to review the dynamics of multiple circular cylinders in stationary fluid, parallel flow and cross flow, and to present general design guides to avoid detrimental vibration and instability. 77 refs

  17. Blood group antigen studies using CdTe quantum dots and flow cytometry

    Directory of Open Access Journals (Sweden)

    Cabral Filho PE

    2015-07-01

    Full Text Available Paulo E Cabral Filho,1 Maria IA Pereira,1 Heloise P Fernandes,2 Andre A de Thomaz,3 Carlos L Cesar,3 Beate S Santos,4 Maria L Barjas-Castro,2 Adriana Fontes1 1Departamento de Biofísica e Radiobiologia, Universidade Federal de Pernambuco, Recife, Pernambuco, 2Centro de Hematologia e Hemoterapia, Universidade Estadual de Campinas, Instituto Nacional de Ciência e Tecnologia do Sangue, Campinas, São Paulo, 3Departamento de Eletrônica Quântica, Instituto de Física Gleb Wataghin, Universidade Estadual de Campinas, Campinas, São Paulo, 4Departamento de Ciências Farmacêuticas, Universidade Federal de Pernambuco, Recife, PE, Brazil Abstract: New methods of analysis involving semiconductor nanocrystals (quantum dots [QDs] as fluorescent probes have been highlighted in life science. QDs present some advantages when compared to organic dyes, such as size-tunable emission spectra, broad absorption bands, and principally exceptional resistance to photobleaching. Methods applying QDs can be simple, not laborious, and can present high sensibility, allowing biomolecule identification and quantification with high specificity. In this context, the aim of this work was to apply dual-color CdTe QDs to quantify red blood cell (RBC antigen expression on cell surface by flow cytometric analysis. QDs were conjugated to anti-A or anti-B monoclonal antibodies, as well as to the anti-H (Ulex europaeus I lectin, to investigate RBCs of A1, B, A1B, O, A2, and Aweak donors. Bioconjugates were capable of distinguishing the different expressions of RBC antigens, both by labeling efficiency and by flow cytometry histogram profile. Furthermore, results showed that RBCs from Aweak donors present fewer amounts of A antigens and higher amounts of H, when compared to A1 RBCs. In the A group, the amount of A antigens decreased as A1 > A3 > AX = Ael, while H antigens were AX = Ael > A1. Bioconjugates presented stability and remained active for at least 6 months. In conclusion

  18. A bulk localized state and new holographic renormalization group flow in 3D spin-3 gravity

    Science.gov (United States)

    Nakayama, Ryuichi; Suzuki, Tomotaka

    2018-04-01

    We construct a localized state of a scalar field in 3D spin-3 gravity. 3D spin-3 gravity is thought to be holographically dual to W3-extended CFT on a boundary at infinity. It is known that while W3 algebra is a nonlinear algebra, in the limit of large central charge c a linear finite-dimensional subalgebra generated by Wn (n = 0,±1,±2) and Ln (n = 0,±1) is singled out. The localized state is constructed in terms of these generators. To write down an equation of motion for a scalar field which is satisfied by this localized state, it is necessary to introduce new variables for an internal space α±, β±, γ, in addition to ordinary coordinates x± and y. The higher-dimensional space, which combines the bulk space-time with the “internal space,” which is an analog of superspace in supersymmetric theory, is introduced. The “physical bulk space-time” is a 3D hypersurface with constant α±, β± and γ embedded in this space. We will work in Poincaré coordinates of AdS space and consider W-quasi-primary operators Φh(x+) with a conformal weight h in the boundary and study two and three point functions of W-quasi-primary operators transformed as eix+L‑1heβ+W‑1hΦh(0)e‑β+W‑1he‑ix+L‑1h. Here, Lnh and Wnh are sl(3,R) generators in the hyperbolic basis for Poincaré coordinates. It is shown that in the β+ →∞ limit, the conformal weight changes to a new value h‧ = h/2. This may be regarded as a Renormalization Group (RG) flow. It is argued that this RG flow will be triggered by terms ΔS ∝ β+W ‑1h + β‑W¯ ‑1h added to the action.

  19. Electrochemical sensors and devices for heavy metals assay in water: the French groups' contribution

    Directory of Open Access Journals (Sweden)

    Luca ePUJOL

    2014-04-01

    Full Text Available A great challenge in the area of heavy metal trace detection is the development of electrochemical techniques and devices which are user-friendly, robust, selective, with low detection limits and allowing fast analyses. This review presents the major contribution of the French scientific academic community in the field of electrochemical sensors and electroanalytical methods within the last 20 years. From the well-known polarography to the up-to-date generation of functionalized interfaces, the different strategies dedicated to analytical performances improvement are exposed: stripping voltammetry, solid mercury-free electrode, ion selective sensor, carbon based materials, chemically modified electrodes, nano-structured surfaces. The paper particularly emphasizes their advantages and limits face to the last Water Frame Directive devoted to the Environmental Quality Standards for heavy metals. Recent trends on trace metal speciation as well as on automatic on line monitoring devices are also evoked.

  20. Architecture and emplacement of flood basalt flow fields: case studies from the Columbia River Basalt Group, NW USA

    Science.gov (United States)

    Vye-Brown, C.; Self, S.; Barry, T. L.

    2013-03-01

    The physical features and morphologies of collections of lava bodies emplaced during single eruptions (known as flow fields) can be used to understand flood basalt emplacement mechanisms. Characteristics and internal features of lava lobes and whole flow field morphologies result from the forward propagation, radial spread, and cooling of individual lobes and are used as a tool to understand the architecture of extensive flood basalt lavas. The features of three flood basalt flow fields from the Columbia River Basalt Group are presented, including the Palouse Falls flow field, a small (8,890 km2, ˜190 km3) unit by common flood basalt proportions, and visualized in three dimensions. The architecture of the Palouse Falls flow field is compared to the complex Ginkgo and more extensive Sand Hollow flow fields to investigate the degree to which simple emplacement models represent the style, as well as the spatial and temporal developments, of flow fields. Evidence from each flow field supports emplacement by inflation as the predominant mechanism producing thick lobes. Inflation enables existing lobes to transmit lava to form new lobes, thus extending the advance and spread of lava flow fields. Minimum emplacement timescales calculated for each flow field are 19.3 years for Palouse Falls, 8.3 years for Ginkgo, and 16.9 years for Sand Hollow. Simple flow fields can be traced from vent to distal areas and an emplacement sequence visualized, but those with multiple-layered lobes present a degree of complexity that make lava pathways and emplacement sequences more difficult to identify.

  1. Protecting group and switchable pore-discriminating adsorption properties of a hydrophilic-hydrophobic metal-organic framework.

    Science.gov (United States)

    Mohideen, M Infas H; Xiao, Bo; Wheatley, Paul S; McKinlay, Alistair C; Li, Yang; Slawin, Alexandra M Z; Aldous, David W; Cessford, Naomi F; Düren, Tina; Zhao, Xuebo; Gill, Rachel; Thomas, K Mark; Griffin, John M; Ashbrook, Sharon E; Morris, Russell E

    2011-04-01

    Formed by linking metals or metal clusters through organic linkers, metal-organic frameworks are a class of solids with structural and chemical properties that mark them out as candidates for many emerging gas storage, separation, catalysis and biomedical applications. Important features of these materials include their high porosity and their flexibility in response to chemical or physical stimuli. Here, a copper-based metal-organic framework has been prepared in which the starting linker (benzene-1,3,5-tricarboxylic acid) undergoes selective monoesterification during synthesis to produce a solid with two different channel systems, lined by hydrophilic and hydrophobic surfaces, respectively. The material reacts differently to gases or vapours of dissimilar chemistry, some stimulating subtle framework flexibility or showing kinetic adsorption effects. Adsorption can be switched between the two channels by judicious choice of the conditions. The monoesterified linker is recoverable in quantitative yield, demonstrating possible uses of metal-organic frameworks in molecular synthetic chemistry as 'protecting groups' to accomplish selective transformations that are difficult using standard chemistry techniques.

  2. Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Du, Guodong [Iowa State Univ., Ames, IA (United States)

    2003-01-01

    In this work, the first examples of group 4 metalloporphyrin 1,2-diolato complexes were synthesized through a number of strategies. In general, treatment of imido metalloporphyrin complexes, (TTP)M=NR, (M = Ti, Zr, Hf), with vicinal diols led to the formation of a series of diolato complexes. Alternatively, the chelating pinacolate complexes could be prepared by metathesis of (TTP)MCl2 (M = Ti, Hf) with disodium pinacolate. These complexes were found to undergo C-C cleavage reactions to produce organic carbonyl compounds. For titanium porphyrins, treatment of a titanium(II) alkyne adduct, (TTP)Ti(η2-PhC≡CPh), with aromatic aldehydes or aryl ketones resulted in reductive coupling of the carbonyl groups to produce the corresponding diolato complexes. Aliphatic aldehydes or ketones were not reactive towards (TTP)Ti(η2-PhC≡CPh). However, these carbonyl compounds could be incorporated into a diolato complex on reaction with a reactive precursor, (TTP)Ti[O(Ph)2C(Ph)2O] to provide unsymmetrical diolato complexes via cross coupling reactions. In addition, an enediolato complex (TTP)Ti(OCPhCPhO) was obtained from the reaction of (TTP)Ti(η2-PhC≡CPh) with benzoin. Titanium porphyrin diolato complexes were found to be intermediates in the (TTP)Ti=O-catalyzed cleavage reactions of vicinal diols, in which atmospheric oxygen was the oxidant. Furthermore, (TTP)Ti=O was capable of catalyzing the oxidation of benzyl alcohol and α-hydroxy ketones to benzaldehyde and α-diketones, respectively. Other high valent metalloporphyrin complexes also can catalyze the oxidative diol cleavage and the benzyl alcohol oxidation reactions with dioxygen. A comparison of Ti(IV) and Sn(IV) porphyrin chemistry was undertaken. While chelated diolato complexes were invariably obtained for titanium porphyrins on treatment with 1,2-diols, the reaction of vicinal diols with tin porphyrins gave a number of products, including mono

  3. Global exploration and production capacity for platinum-group metals from 1995 through 2015

    Science.gov (United States)

    Wilburn, David R.

    2012-01-01

    Platinum-group metals (PGMs) are required in a variety of commercial, industrial, and military applications for many existing and emerging technologies, yet the United States is highly dependent on foreign sources of PGMs. Information on global exploration for PGMs since 1995 has been used in this study as a basis for identifying locations where the industry has determined that exploration has provided data sufficient to warrant development of a new mine or expansion of an existing operation or where a significant increase in capacity for PGMs is anticipated by 2015. Discussions include an overview of the industry and the selected sites, factors affecting mineral supply, and circumstances leading to the development of mineral properties with the potential to affect mineral supply. Of the 52 sites or regional operations that were considered in this analysis, 16 sites were producing before 1995, 28 sites commenced production from 1995 through 2010, and 8 sites were expected to begin production from 2011 through 2015 if development plans came to fruition. The United States imports PGMs primarily from Canada, Russia, South Africa, and Zimbabwe to meet increasing demand for these materials in a variety of specialized and high-tech applications. Feed sources of PGMs are changing in South Africa and Russia, which together accounted for about 89 percent of platinum production and 82 percent of palladium production in 2009. A greater amount of South African PGM capacity is likely to come from deeper, higher cost Upper Group Reef seam 2 deposits and deposits in the Eastern Bushveld area. Future Russian PGM capacity is likely to come from ore zones with generally lower PGM content and different platinum-to-palladium ratios than the nickel-rich ore that dominated PGM supply in the 1990s. Because PGM supply from Canada and Russia is derived as a byproduct of copper and nickel mining, the PGM supply from these countries is influenced by economic, environmental, political, and

  4. Calibration of the Flow in the Test Section of the Research Wind Tunnel at DST Group

    Science.gov (United States)

    2015-10-01

    of research projects, including the prediction of the performance of gas - turbine engines under conditions of pulsating flow , parametric studies of...the tunnel. The calibration data are presented and analysed and explanations of flow behaviour are given. 2. Mean-Velocity Measurements 2.1...

  5. Metals in environmental media: A study of trace and platinum group ...

    African Journals Online (AJOL)

    A detailed study has been conducted to determine the contamination of Thohoyandou roadside soils, vegetation, sewage and river waters by Zn, Cu, Cr, Pb, Cd, Fe, Pt and Pd. The study further investigated the correlation between these trace metals in roadside soils and vegetation in order to infer the potential impacts of ...

  6. Soil microbial activity, mycelial lengths and physiological groups of bacteria in a heavy metal polluted area

    Energy Technology Data Exchange (ETDEWEB)

    Nordgren, A; Kauri, T; Baeaeth, E; Soederstroem, B

    1986-01-01

    The biological effects of heavy metal contamination of coniferous forest soils were studied in the A/sub 01//A/sub 02/ layer around a primary smelter in Northern Sweden. Soil concentrations of 17 elements were determined. Smelter-emitted heavy metals were 5 to 75 times higher in the plot closest to the smelter compared with background levels. Despite emission of sulfur no decrease in pH was found. Bacteria producing acid from maltose, cellobiose, arabinose or xylose and bacteria hydrolyzing starch, pectin, xyland or cellulose decreased 8- to 11-fold due to the soil contamination. Chitin hydrolyzers were 5 times less abundant at the most polluted site compared with background levels. Soil respiration rate and urease activity decreased by about a factor of 4, but phosphatase activity and mycelial lengths were unaffected by the soil contamination. Soil bacteria showed a sigmoidal response to the log of metal concentration in the soil and were affected at a lower pollution level than the other biological variables in the study. A multivariate analysis (partial least squares) showed that soil metal contamination and soil pH were the two environmental factors influencing the soil microorganisms.

  7. Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

    KAUST Repository

    Despagnet-Ayoub, Emmanuelle

    2013-05-24

    Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.

  8. Alkali Metal Cation Affinities of Anionic Main Group-Element Hydrides Across the Periodic Table

    NARCIS (Netherlands)

    Boughlala, Zakaria; Fonseca Guerra, Célia; Bickelhaupt, F. Matthias

    2017-01-01

    We have carried out an extensive exploration of gas-phase alkali metal cation affinities (AMCA) of archetypal anionic bases across the periodic system using relativistic density functional theory at ZORA-BP86/QZ4P//ZORA-BP86/TZ2P. AMCA values of all bases were computed for the lithium, sodium,

  9. Scaling laws, renormalization group flow and the continuum limit in non-compact lattice QED

    International Nuclear Information System (INIS)

    Goeckeler, M.; Horsley, R.; Rakow, P.; Schierholz, G.; Sommer, R.

    1992-01-01

    We investigate the ultra-violet behavior of non-compact lattice QED with light staggered fermions. The main question is whether QED is a non-trivial theory in the continuum limit, and if not, what is its range of validity as a low-energy theory. Perhaps the limited range of validity could offer an explanation of why the fine-structure constant is so small. Non-compact QED undergoes a second-order chiral phase transition at strong coupling, at which the continuum limit can be taken. We examine the phase diagram and the critical behavior of the theory in detail. Moreover, we address the question as to whether QED confines in the chirally broken phase. This is done by investigating the potential between static external charges. We then compute the renormalized charge and derive the Callan-Symanzik β-function in the critical region. No ultra-violet stable zero is found. Instead, we find that the evolution of charge is well described by renormalized perturbation theory, and that the renormalized charge vanishes at the critical point. The consequence is that QED can only be regarded as a cut-off theory. We evaluate the maximum value of the cut-off as a function of the renormalized charge. Next, we compute the masses of fermion-antifermion composite states. The scaling behavior of these masses is well described by an effective action with mean-field critical exponents plus logarithmic corrections. This indicates that also the matter sector of the theory is non-interacting. Finally, we investigate and compare the renormalization group flow of different quantities. Altogether, we find that QED is a valid theory only for samll renormalized charges. (orig.)

  10. Correlation between relaxations and plastic deformation, and elastic model of flow in metallic glasses and glass-forming liquids

    International Nuclear Information System (INIS)

    Wang Weihua

    2011-01-01

    We study the similarity and correlations between relaxations and plastic deformation in metallic glasses (MGs) and MG-forming liquids. It is shown that the microscope plastic events, the initiation and formation of shear bands, and the mechanical yield in MGs where the atomic sites are topologically unstable induced by applied stress, can be treated as the glass to supercooled liquid state transition induced by external shear stress. On the other hand, the glass transition, the primary and secondary relaxations, plastic deformation and yield can be attributed to the free volume increase induced flow, and the flow can be modeled as the activated hopping between the inherent states in the potential energy landscape. We then propose an extended elastic model to describe the flow based on the energy landscape theory. That is, the flow activation energy density is linear proportional to the instantaneous elastic moduli, and the activation energy density ρ E is determined to be a simple expression of ρ E =(10/11)G+(1/11)K. The model indicates that both shear and bulk moduli are critical parameters accounting for both the homogeneous and inhomogeneous flows in MGs and MG-forming liquids. The elastic model is experimentally certified. We show that the elastic perspectives offers a simple scenario for the flow in MGs and MG-forming liquids and are suggestive for understanding the glass transition, plastic deformation, and nature and characteristics of MGs

  11. Expandable and retractable self-rolled structures based on metal/polymer thin film for flow sensing

    Science.gov (United States)

    Zhu, Jianzhong; White, Carl; Saadat, Mehdi; Bart-Smith, Hilary

    2015-11-01

    Most aquatic animals such as fish rely heavily on their ability of detect and respond to ambient flows in order to explore and inhabit various habitats or survive predator-prey encounters. Fish utilize neuromasts in their skin surface and lateral lines in their bodies to align themselves while swimming upstream for migration, avoid obstacles, reduce locomotion cost, and detect flow variations caused by potential predators. In this study, a thin film MEMS sensor analogous to a fish neuromast has been designed for flow sensing. Residual stress arises in many thin film materials during processing. Metal and polymer thin film materials with a significant difference in elastic modular were chosen to form a multiple-layer structure. Upon releasing, the structure rolls into a tube due to mechanical property mismatch. The self-rolled tube can expand or retract, depending on the existence of external force such as flow. An embedded strain sensor detects the deformation of the tube and hence senses the ambient flow. Numerical simulations were conducted to optimize the structural design. Experiments were performed in a flow tank to quantify the performance of the sensor. This research is supported by the Office of Naval Research under the MURI Grant N00014-14-1-0533.

  12. Benchmark exercise for fluid flow simulations in a liquid metal fast reactor fuel assembly

    Energy Technology Data Exchange (ETDEWEB)

    Merzari, E., E-mail: emerzari@anl.gov [Mathematics and Computer Science Division, Argonne National Laboratory, 9700 S. Cass Avenue, Lemont, IL 60439 (United States); Fischer, P. [Mathematics and Computer Science Division, Argonne National Laboratory, 9700 S. Cass Avenue, Lemont, IL 60439 (United States); Yuan, H. [Nuclear Engineering Division, Argonne National Laboratory, Lemont, IL (United States); Van Tichelen, K.; Keijers, S. [SCK-CEN, Boeretang 200, Mol (Belgium); De Ridder, J.; Degroote, J.; Vierendeels, J. [Ghent University, Ghent (Belgium); Doolaard, H.; Gopala, V.R.; Roelofs, F. [NRG, Petten (Netherlands)

    2016-03-15

    Highlights: • A EUROTAM-US INERI consortium has performed a benchmark exercise related to fast reactor assembly simulations. • LES calculations for a wire-wrapped rod bundle are compared with RANS calculations. • Results show good agreement for velocity and cross flows. - Abstract: As part of a U.S. Department of Energy International Nuclear Energy Research Initiative (I-NERI), Argonne National Laboratory (Argonne) is collaborating with the Dutch Nuclear Research and consultancy Group (NRG), the Belgian Nuclear Research Centre (SCK·CEN), and Ghent University (UGent) in Belgium to perform and compare a series of fuel-pin-bundle calculations representative of a fast reactor core. A wire-wrapped fuel bundle is a complex configuration for which little data is available for verification and validation of new simulation tools. UGent and NRG performed their simulations with commercially available computational fluid dynamics (CFD) codes. The high-fidelity Argonne large-eddy simulations were performed with Nek5000, used for CFD in the Simulation-based High-efficiency Advanced Reactor Prototyping (SHARP) suite. SHARP is a versatile tool that is being developed to model the core of a wide variety of reactor types under various scenarios. It is intended both to serve as a surrogate for physical experiments and to provide insight into experimental results. Comparison of the results obtained by the different participants with the reference Nek5000 results shows good agreement, especially for the cross-flow data. The comparison also helps highlight issues with current modeling approaches. The results of the study will be valuable in the design and licensing process of MYRRHA, a flexible fast research reactor under design at SCK·CEN that features wire-wrapped fuel bundles cooled by lead-bismuth eutectic.

  13. Development of Novel Non-Pt Group Metal Electrocatalysts for PEM Fuel Cell Applications

    Energy Technology Data Exchange (ETDEWEB)

    Mukerjee, Sanjeev [Northeastern Univ., Boston, MA (United States). Dept. of Chemistry and Chemical Biology; Atanassov, Plamen [Univ. of New Mexico, Albuquerque, NM (United States); Barton, Scott [Michigan State Univ., East Lansing, MI (United States); Dale, Nilesh [Nissan Technical Center North America (NTCNA), Farmington Hills, MI (United States); Halevi, Bar [Pajarito Powder LLC, Albuquerque, NM (United States)

    2016-01-04

    The objective of this multi-institutional effort was to comprehensively pursue the goal of eliminating noble metal (Pt group metals, PGM) from the cathodic oxygen reduction reaction (ORR) electrode thereby providing a quantum leap in lowering the overall PGM loading in a polymer electrolyte fuel cell (PEMFC). The overall project scope encompassed (a) comprehensive materials discovery effort, (b) a concomitant effort to scale up these materials with very high ( ±5%) reproducibility, both intra and inter, (c) understanding mass transport in porous medium both in gas diffusion and micro-porous layers for enhanced areal activity, (d) understanding mechanistic aspects of active site structure and ORR electrocatalytic pathway. Overall project milestones and metrics were (a) first phase effort based on performance in oxygen where the project’s Go/No-Go decision point milestone of 100 mA/cm2 at 0.8 V (internal resistance-free, iR-free) at 80°C, pure H2/O2, with 1.5 bar total pressure was met. Subsequently, the principle objectives were to (a) transition the project from H2/O2 to H2/Air with slated target of exceeding 30 mA/cm2 @ 0.8 V, 2.5 bar total pressure and an end of the project target of 1 A/cm2 @ 0.4 V (same total pressure), both under 100% relative humidity. The target for catalyst material scale up was to achieve 100 g batch size at the end of the program. This scale up target had a quality control milestone of less than 5% variation of activity measured with H2/Air (2.5 bar total pressure) at 0.8 V. In addition, the project also aimed at arriving at a unified understanding of the nature of active sites in these catalysts as well as some preliminary understanding of the mechanistic pathway. Also addressed is the development of an integrated method for determination of mass transport parameters using a combination of Helox experiments and modeling of the gas

  14. Competitive platinum-group-metal (PGM) supply from the Eastern Limb, Bushveld Complex: Geological, mining and mineral economic aspects

    CSIR Research Space (South Africa)

    McGill, JE

    2011-08-01

    Full Text Available -GROUP-METAL (PGM) SUPPLY FROM THE EASTERN LIMB, BUSHVELD COMPLEX: GEOLOGICAL, MINING, AND MINERAL ECONOMIC ASPECTS Dr. Jeannette E. McGill & Prof. Murray W. Hitzman ACKNOWLEDGEMENTS ? COUNCIL FOR SCIENTIFIC AND INDUSTRIAL RESEARCH (CSIR) ? Centre for Mining... Innovation ? Office of Graduate Studies, Fogarty Endowment ? Mr. VISHNU PILLAY (EXECUTIVE HEAD: JV?S ? Anglo Platinum) ? ACADEMIC ADVISORS Prof. Murray Hitzman (Economic Geology); Dr. Hugh Miller (Mining Engineering); Prof. Rodderick Eggert (Mineral...

  15. Heavy metal adsorptivity of calcium-alginate-modified diethylenetriamine-silica gel and its application to a flow analytical system using flame atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Mori, Masanobu; Suzuki, Toshinobu; Sugita, Tsuyoshi; Nagai, Daisuke; Hirayama, Kazuo; Onozato, Makoto; Itabashi, Hideyuki

    2014-01-01

    Highlights: • Calcium-alginate-modified dien-silica gel adsorbed multivalent metal ions. • Metal ions adsorbed on CaAD were eluted using low acidic concentrations. • Flow system with CaAD-packed column enriched metal concentrations up to 50-fold. - Abstract: This study aimed to evaluate the heavy metal adsorptivity of calcium-alginate-modified diethylenetriamine-silica gel (CaAD) and incorporate this biosorbent into a flow analytical system for heavy metal ions using flame atomic absorption spectrometry (FAAS). The biosorbent was synthesized by electrostatically coating calcium alginate onto diethylenetriamine (dien)-silica gel. Copper ion adsorption tests by a batch method showed that CaAD exhibited a higher adsorption rate compared with other biosorbents despite its low maximum adsorption capacity. Next, CaAD was packed into a 1 mL microcolumn, which was connected to a flow analytical system equipped with an FAAS instrument. The flow system quantitatively adsorbed heavy metals and enriched their concentrations. This quantitative adsorption was achieved for pH 3–4 solutions containing 1.0 × 10 −6 M of heavy metal ions at a flow rate of 5.0 mL min −1 . Furthermore, the metal ions were successfully desorbed from CaAD at low nitric acid concentrations (0.05–0.15 M) than from the polyaminecarboxylic acid chelating resin (Chelex 100). Therefore, CaAD may be considered as a biosorbent that quickly adsorbs and easily desorbs analyte metal ions. In addition, the flow system enhanced the concentrations of heavy metals such as Cu 2+ , Zn 2+ , and Pb 2+ by 50-fold. This new enrichment system successfully performed the separation and determination of Cu 2+ (5.0 × 10 −8 M) and Zn 2+ (5.7 × 10 −8 M) in a river water sample and Pb 2+ (3.8 × 10 −9 M) in a ground water sample

  16. Rationalizing the structural variability of the exocyclic amino groups in nucleobases and their metal complexes: cytosine and adenine.

    Science.gov (United States)

    Fonseca Guerra, Célia; Sanz Miguel, Pablo J; Cebollada, Andrea; Bickelhaupt, F Matthias; Lippert, Bernhard

    2014-07-28

    The exocyclic amino groups of cytosine and adenine nucleobases are normally almost flat, with the N atoms essentially sp(2) hybridized and the lone pair largely delocalized into the heterocyclic rings. However, a change to marked pyramidality of the amino group (N then sp(3) hybridized, lone pair essentially localized at N) occurs during i) involvement of an amino proton in strong hydrogen bonding donor conditions or ii) with monofunctional metal coordination following removal of one of the two protons. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Flow of liquid metals in curved channels under a transversely applied magnetic field, (3)

    International Nuclear Information System (INIS)

    Arai, Shigeki; Tomita, Yukio; Sudou, Kouzou.

    1979-01-01

    With the development of electromagnetic pumps in nuclear, metallurgical and casting industries, investigations of not only laminar flow but also transient and turbulent flows in magnetohydrodynamic (MHD) channels are the matters of much concern. However, it is no exaggeration to say that there was no investigation of transient and turbulent flows in curved MHD channels. In this report, the influences of Reynolds number, Hartmann number, radius of curvature and aspect ratio on the coefficient of friction in transient and turbulent flow channels are discussed. In transient flow region, the curve representing the product of the coefficient of channel friction in curved channels and Reynolds number has no clear transition point in the flow of comparatively small Hartmann number. However, as the intensity of magnetic field is increased, the curve transfers to the transition due to the effect of suppressing secondary flow, and if the magnetic field is further increased, it was found that it approached the crisis-free type transition. In turbulent flow region, the coefficient of channel friction can be expressed approximately by the empirical equation given first in this report. Also the effect of magnetic field on the turbulent flow in curved channels can be explained by using Hartmann effect, turbulence suppression effect, and the effect of suppressing secondary flow based on Lorentz's force. (Wakatsuki, Y.)

  18. Turbulent heat mixing of a heavy liquid metal flow in the MEGAPIE target geometry-The heated jet experiment

    International Nuclear Information System (INIS)

    Stieglitz, Robert; Daubner, Markus; Batta, A.; Lefhalm, C.-H.

    2007-01-01

    The MEGAPIE target installed at the Paul-Scherrer Institute is an example of a spallation target using eutectic liquid lead-bismuth (Pb 45 Bi 55 ) both as coolant and neutron source. An adequate cooling of the target requires a conditioning of the flow, which is realized by a main flow transported in an annular gap downwards, u-turned at a hemispherical shell into a cylindrical riser tube. In order to avoid a stagnation point close to the lowest part of the shell a jet flow is superimposed to the main flow, which is directed towards to the stagnation point and flows tangentially along the shell. The heated jet experiment conducted in the THEADES loop of the KALLA laboratory is nearly 1:1 representation of the lower part of the MEGAPIE target. It is aimed to study the cooling capability of this specific geometry in dependence on the flow rate ratio (Q main /Q jet ) of the main flow (Q main ) to the jet flow (Q jet ). Here, a heated jet is injected into a cold main flow at MEGAPIE relevant flow rate ratios. The liquid metal experiment is accompanied by a water experiment in almost the same geometry to study the momentum field as well as a three-dimensional turbulent numerical fluid dynamic simulation (CFD). Besides a detailed study of the envisaged nominal operation of the MEGAPIE target with Q main /Q jet = 15 deviations from this mode are investigated in the range from 7.5 ≤ Q main /Q jet ≤ 20 in order to give an estimate on the safe operational threshold of the target. The experiment shows that, the flow pattern establishing in this specific design and the turbulence intensity distribution essentially depends on the flow rate ratio (Q main /Q jet ). All Q main /Q jet -ratios investigated exhibit an unstable time dependent behavior. The MEGAPIE design is highly sensitive against changes of this ratio. Mainly three completely different flow patterns were identified. A sufficient cooling of the lower target shell, however, is only ensured if Q main /Q jet ≤ 12

  19. Analysis of liquid metal MHD flow in multiple adjacent ducts using an iterative method to solve the core flow equations

    International Nuclear Information System (INIS)

    McCarthy, K.A.; Abdou, M.A.

    1991-01-01

    A computationally fast and efficient method for analyzing MHD flow at high Hartmann number and interaction parameter is presented and used to analyze a multiple duct geometry. This type of geometry is of practical interest in fusion applications. Because the Hartmann number and interaction parameter are generally large in fusion applications, the inertial and viscous terms in the Navier-Stokes equation can often be neglected in the core flow region, making this equation linear. In addition, because the magnetic fields in a fusion reactor vary slowly and the magnetic Reynolds number is small, the induced magnetic field can be neglected. The resulting equations representing core flow have certain characteristics which make it possible to reduce them to two dimensional without losing the three dimensional characteristics. The method which has been developed is an 'iterative' method. A velocity profile is assumed, then Ohm's law and the current conservation equation are combined and used to solve for the potential distribution in a plane in the fluid, and in a surface in the duct wall. The potential variation along magnetic field lines is checked, and if necessary, the velocities are adjusted. This procedure is repeated until the potentials along field lines vary to within a specified error. The analysis of the multiple duct geometry shows the importance of global effects. The results of two basic cases are presented. In the first, the average velocity in each duct is the same, but the wall conductance ratios of the walls perpendicular to the magnetic field vary from duct to duct. The total pressure drop in the electrically connected ducts was greater than or equal to the total pressure drop in the same ducts electrically isolated. In addition, the velocity profile in the ducts can be significantly affected by the presence of neighboring ducts. (orig./AH)

  20. Modelling chemical abundance distributions for dwarf galaxies in the Local Group: the impact of turbulent metal diffusion

    Science.gov (United States)

    Escala, Ivanna; Wetzel, Andrew; Kirby, Evan N.; Hopkins, Philip F.; Ma, Xiangcheng; Wheeler, Coral; Kereš, Dušan; Faucher-Giguère, Claude-André; Quataert, Eliot

    2018-02-01

    We investigate stellar metallicity distribution functions (MDFs), including Fe and α-element abundances, in dwarf galaxies from the Feedback in Realistic Environment (FIRE) project. We examine both isolated dwarf galaxies and those that are satellites of a Milky Way-mass galaxy. In particular, we study the effects of including a sub-grid turbulent model for the diffusion of metals in gas. Simulations that include diffusion have narrower MDFs and abundance ratio distributions, because diffusion drives individual gas and star particles towards the average metallicity. This effect provides significantly better agreement with observed abundance distributions in dwarf galaxies in the Local Group, including small intrinsic scatter in [α/Fe] versus [Fe/H] of ≲0.1 dex. This small intrinsic scatter arises in our simulations because the interstellar medium in dwarf galaxies is well mixed at nearly all cosmic times, such that stars that form at a given time have similar abundances to ≲0.1 dex. Thus, most of the scatter in abundances at z = 0 arises from redshift evolution and not from instantaneous scatter in the ISM. We find similar MDF widths and intrinsic scatter for satellite and isolated dwarf galaxies, which suggests that environmental effects play a minor role compared with internal chemical evolution in our simulations. Overall, with the inclusion of metal diffusion, our simulations reproduce abundance distribution widths of observed low-mass galaxies, enabling detailed studies of chemical evolution in galaxy formation.

  1. Lipid solubility of the platinum group metals Pt, Pd and Rh in dependence on the presence of complexing agents

    International Nuclear Information System (INIS)

    Zimmermann, Sonja; Menzel, Christoph M.; Stueben, Doris; Taraschewski, Horst; Sures, Bernd

    2003-01-01

    All complexing agents had a significant influence on octanol solubility of PGM. - Investigations on the bioaccumulation of the platinum group metals (PGM) Pt, Pd and Rh in aquatic organisms are of growing interest in environmental research due to the increasing emission of these metals by motor vehicles with catalytic converters. Until now, nothing is known about the possible influence of complexing agents on the bioaccumulation capacity of these precious metals. According to the partition coefficient between 1-octanol and water (P OW ) as a measure of bioaccumulation, in this study a simple shaking method was performed in order to investigate the effects of different complexing agents (L-methionine, thio urea, EDTA, humic substances, bile compounds) on the octanol solubility of the PGM. The results demonstrated a significant influence of all agents used. L-Methionine and thio urea decreased the lipid solubility. In contrast, the presence of EDTA, humic substances and especially bile caused a higher transfer of metals in the octanol phase. For most complexing agents tested, the transfer of Pd to the lipid phase was significantly higher compared with Rh and Pt, except for bile acid where the highest octanol solubility was found for Pt. Recent experimental results on PGM accumulation in zebra mussels confirm a high bioaccumulation of Pd which could be predicted from the lipid solubility

  2. Lipid solubility of the platinum group metals Pt, Pd and Rh in dependence on the presence of complexing agents

    Energy Technology Data Exchange (ETDEWEB)

    Zimmermann, Sonja; Menzel, Christoph M.; Stueben, Doris; Taraschewski, Horst; Sures, Bernd

    2003-07-01

    All complexing agents had a significant influence on octanol solubility of PGM. - Investigations on the bioaccumulation of the platinum group metals (PGM) Pt, Pd and Rh in aquatic organisms are of growing interest in environmental research due to the increasing emission of these metals by motor vehicles with catalytic converters. Until now, nothing is known about the possible influence of complexing agents on the bioaccumulation capacity of these precious metals. According to the partition coefficient between 1-octanol and water (P{sub OW}) as a measure of bioaccumulation, in this study a simple shaking method was performed in order to investigate the effects of different complexing agents (L-methionine, thio urea, EDTA, humic substances, bile compounds) on the octanol solubility of the PGM. The results demonstrated a significant influence of all agents used. L-Methionine and thio urea decreased the lipid solubility. In contrast, the presence of EDTA, humic substances and especially bile caused a higher transfer of metals in the octanol phase. For most complexing agents tested, the transfer of Pd to the lipid phase was significantly higher compared with Rh and Pt, except for bile acid where the highest octanol solubility was found for Pt. Recent experimental results on PGM accumulation in zebra mussels confirm a high bioaccumulation of Pd which could be predicted from the lipid solubility.

  3. High-power spallation target using a heavy liquid metal free surface flow

    International Nuclear Information System (INIS)

    Litfin, K.; Fetzer, J.R.; Batta, A.; Class, A.G.; Wetzel, Th.

    2015-01-01

    A prototype of a heavy liquid metal free surface target as proposed for the multi-purpose hybrid research reactor for high-tech applications in Mol, Belgium, has been set up and experimentally investigated at the Karlsruhe Liquid Metal Laboratory. A stable operation was demonstrated in a wide range of operating conditions and the surface shape was detected and compared with numerical pre-calculations employing Star-CD. Results show a very good agreement of experiment and numerical predictions which is an essential input for other windowless target designs like the META:LIC target for the European Spallation Source. (author)

  4. Flow and Fracture of Bulk Metallic Glass Alloys and their Composites

    International Nuclear Information System (INIS)

    Flores, K M; Suh, D; Howell, R; Asoka-Kumar, P; Dauskardt, R H

    2001-01-01

    The fracture and plastic deformation mechanisms of a Zr-Ti-Ni-Cu-Be bulk metallic glass and a composite utilizing a crystalline reinforcement phase are reviewed. The relationship between stress state, free volume and shear band formation are discussed. Positron annihilation techniques were used to confirm the predicted increase in free volume after plastic straining. Strain localization and failure were examined for a wide range of stress states. Finally, methods for toughening metallic glasses are considered. Significant increases in toughness are demonstrated for a composite bulk metallic glass containing a ductile second phase which stabilizes shear band formation and distributes plastic deformation

  5. Validation of ANSYS CFX for gas and liquid metal flows with conjugate heat transfer within the European project THINS

    Energy Technology Data Exchange (ETDEWEB)

    Papukchiev, A., E-mail: angel.papukchiev@grs.de; Buchholz, S.

    2017-02-15

    Highlights: • ANSYS CFX is validated for gas and liquid metal flows. • L-STAR and TALL-3D experiments are simulated. • Complex flow and heat transfer phenomena are modelled. • Conjugate heat transfer has to be considered in CFD analyses. - Abstract: Within the FP7 European project THINS (Thermal Hydraulics of Innovative Nuclear Systems), numerical tools for the simulation of the thermal-hydraulics of next generation rector systems were developed, applied and validated for innovative coolants. The Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) gGmbH participated in THINS with activities related to the development and validation of computational fluid dynamics (CFD) and coupled System Thermal Hydraulics (STH) – CFD codes. High quality measurements from the L-STAR and TALL-3D experiments were used to assess the numerical results. Two-equation eddy viscosity and scale resolving turbulence models were used in the validation process of ANSYS CFX for gas and liquid metal flows with conjugate heat transfer. This paper provides a brief overview on the main results achieved at GRS within the project.

  6. Fabrication of a polyvinylidene difluoride fiber with a metal core and its application as directional air flow sensor

    Science.gov (United States)

    Bian, Yixiang; Liu, Rongrong; Hui, Shen

    2016-09-01

    We fabricated a sensitive air flow detector that mimic the sensing mechanism found at the tail of some insects. [see Y. Yang, A. Klein, H. Bleckmann and C. Liu, Appl. Phys. Lett. 99(2) (2011); J. J. Heys, T. Gedeon, B. C. Knott and Y. Kim, J. Biomech. 41(5), 977 (2008); J. Tao and X. Yu, Smart Mat. Struct. 21(11) (2012)]. Our bionic airflow sensor uses a polyvinylidene difluoride (PVDF) microfiber with a molybdenum core which we produced with the hot extrusion tensile method. The surface of the fiber is partially coated with conductive silver adhesive that serve as surface electrodes. A third electrode, the metal core is used to polarize polyvinylidene difluoride (PVDF) under the surface electrodes. The cantilever beam structure of the prepared symmetric electrodes of metal core piezoelectric fiber (SMPF) is used as the artificial hair airflow sensor. The surface electrodes are used to measure output voltage. Our theoretical and experimental results show that the SMPF responds fast to air flow changes, the output charge has an exponential correlation with airflow velocity and a cosine relation with the direction of airflow. Our bionic airflow sensor with directional sensing ability can also measure air flow amplitude. [see H. Droogendijk, R. G. P. Sanders and G. J. M. Krijnen, New J. Phys. 15 (2013)]. By using two surface electrodes, our sensing circuit further improves sensitivity.

  7. Immersed transient eddy current flow metering: a calibration-free velocity measurement technique for liquid metals

    Science.gov (United States)

    Krauter, N.; Stefani, F.

    2017-10-01

    Eddy current flow meters are widely used for measuring the flow velocity of electrically conducting fluids. Since the flow induced perturbations of a magnetic field depend both on the geometry and the conductivity of the fluid, extensive calibration is needed to get accurate results. Transient eddy current flow metering has been developed to overcome this problem. It relies on tracking the position of an impressed eddy current system that is moving with the same velocity as the conductive fluid. We present an immersed version of this measurement technique and demonstrate its viability by numerical simulations and a first experimental validation.

  8. Immersed transient eddy current flow metering: a calibration-free velocity measurement technique for liquid metals

    International Nuclear Information System (INIS)

    Krauter, N; Stefani, F

    2017-01-01

    Eddy current flow meters are widely used for measuring the flow velocity of electrically conducting fluids. Since the flow induced perturbations of a magnetic field depend both on the geometry and the conductivity of the fluid, extensive calibration is needed to get accurate results. Transient eddy current flow metering has been developed to overcome this problem. It relies on tracking the position of an impressed eddy current system that is moving with the same velocity as the conductive fluid. We present an immersed version of this measurement technique and demonstrate its viability by numerical simulations and a first experimental validation. (paper)

  9. Components of the Bond Energy in Polar Diatomic Molecules, Radicals, and Ions Formed by Group-1 and Group-2 Metal Atoms.

    Science.gov (United States)

    Yu, Haoyu; Truhlar, Donald G

    2015-07-14

    Although many transition metal complexes are known to have high multireference character, the multireference character of main-group closed-shell singlet diatomic molecules like BeF, CaO, and MgO has been less studied. However, many group-1 and group-2 diatomic molecules do have multireference character, and they provide informative systems for studying multireference character because they are simpler than transition metal compounds. The goal of the present work is to understand these multireference systems better so that, ultimately, we can apply what we learn to more complicated multireference systems and to the design of new exchange-correlation functionals for treating multireference systems more adequately. Fourteen main-group diatomic molecules and one triatomic molecule (including radicals, cations, and anions, as well as neutral closed-shell species) have been studied for this article. Eight of these molecules contain a group-1 element, and six contain a group-2 element. Seven of these molecules are multireference systems, and eight of them are single-reference systems. Fifty-three exchange-correlation functionals of 11 types [local spin-density approximation (LSDA), generalized gradient approximation (GGA), nonseparable gradient approximation (NGA), global-hybrid GGA, meta-GGA, meta-NGA, global-hybrid meta GGA, range-separated hybrid GGA, range-separated hybrid meta-GGA, range-separated hybrid meta-NGA, and DFT augmented with molecular mechanics damped dispersion (DFT-D)] and the Hartree-Fock method have been applied to calculate the bond distance, bond dissociation energy (BDE), and dipole moment of these molecules. All of the calculations are converged to a stable solution by allowing the symmetry of the Slater determinant to be broken. A reliable functional should not only predict an accurate BDE but also predict accurate components of the BDE, so each bond dissociation energy has been decomposed into ionization potential (IP) of the electropositive

  10. Europium-activated phosphors containing oxides of rare-earth and group-IIIB metals and method of making the same

    Science.gov (United States)

    Comanzo, Holly Ann; Setlur, Anant Achyut; Srivastava, Alok Mani; Manivannan, Venkatesan

    2004-07-13

    Europium-activated phosphors comprise oxides of at least a rare-earth metal selected from the group consisting of gadolinium, yttrium, lanthanum, and combinations thereof and at least a Group-IIIB metal selected from the group consisting of aluminum, gallium, indium, and combinations thereof. A method for making such phosphors comprises adding at least a halide of at least one of the selected Group-IIIB metals in a starting mixture. The method further comprises firing the starting mixture in an oxygen-containing atmosphere. The phosphors produced by such a method exhibit improved absorption in the UV wavelength range and improved quantum efficiency.

  11. Determination of platinum group metal catalyst residues in active pharmaceutical ingredients by means of total reflection X-ray spectrometry

    International Nuclear Information System (INIS)

    Marguí, Eva; Queralt, Ignasi; Hidalgo, Manuela

    2013-01-01

    The control of metal catalyst residues (i.e., platinum group metals (PGMs)) in different stages of the manufacturing processes of the active pharmaceutical ingredients (APIs) and, especially, in the final product is crucial. For API specimens, there are strict guidelines to limit the levels of metal residues based on their individual levels of safety concern. For PGMs the concentration limit has been established at 10 mg/kg in the API. Therefore great effort is currently being devoted to the development of new and simple procedures to control metals in pharmaceuticals. In the present work, an analytical methodology based on benchtop total reflection X-ray fluorescence spectrometry (TXRF) has been developed for the rapid and simple determination of some PGM catalyst impurities (Rh, Pd, Ir and Pt) in different types of API samples. An evaluation of different sample treatments (dissolution and digestion of the solid pharmaceutical samples) has been carried out and the developed methodologies have been validated according to the analytical parameters to be considered and acceptance criteria for PGM determination according to the United States Pharmacopeia (USP). Limits of quantification obtained for PGM metals were in the range of 2–4 mg/kg which are satisfactory according to current legislation. From the obtained results it is shown that the developed TXRF method can be implemented in the pharmaceutical industries to increase productivity of the laboratory; offering an interesting and complementary analytical tool to other atomic spectroscopic methods. - Highlights: • A TXRF method for PGM catalyst residue determination in API samples is presented. • Analysis can be performed using 10 μL of the internal standardized dissolved API. • The method is rapid, simple and suitable according to the USP requirements

  12. Transition-metal-doped group-IV monochalcogenides: a combination of two-dimensional triferroics and diluted magnetic semiconductors

    Science.gov (United States)

    Yang, Liu; Wu, Menghao; Yao, Kailun

    2018-05-01

    We report the first-principles evidence of a series of two-dimensional triferroics (ferromagnetic + ferroelectric + ferroelastic), which can be obtained by doping transition-metal ions in group-IV monochalcogenide (SnS, SnSe, GeS, GeSe) monolayers, noting that a ferromagnetic Fe-doped SnS2 monolayer has recently been realized (Li B et al 2017 Nat. Commun. 8 1958). The ferroelectricity, ferroelasticity and ferromagnetism can be coupled and the magnetization direction may be switched upon ferroelectric/ferroelastic switching, rendering electrical writing + magnetic reading possible. They can be also two-dimensional half-metals or diluted magnetic semiconductors, where p/n channels or even multiferroic tunneling junctions can be designed by variation in doping and incorporated into a monolayer wafer.

  13. Dynamic flow-through approaches for metal fractionation in environmentally relevant solid samples

    DEFF Research Database (Denmark)

    Miró, Manuel; Hansen, Elo Harald; Chomchoei, Roongrat

    2005-01-01

    generations of flow-injection analysis. Special attention is also paid to a novel, robust, non-invasive approach for on-site continuous sampling of soil solutions, capitalizing on flow-through microdialysis, which presents itself as an appealing complementary approach to the conventional lysimeter experiments...

  14. Two-way coupled simulation of a flow laden with metallic particulates in overexpanded TIC nozzle

    International Nuclear Information System (INIS)

    Moshfegh, Abouzar; Shams, Mehrzad; Ebrahimi, Reza; Farnia, Mohammad Ali

    2009-01-01

    A simulation of non-reacting dilute gas-solid flow in a truncated ideal contour nozzle with consideration of external stream interactions is performed. The Eulerian-Lagrangian approach involving a two-way momentum and thermal coupling between gas and particles phases is also adopted. Of interests are to investigate the effects of particles diameter and mass flow fraction on the flow pattern, Mach number, pressure and temperature contours and their distributions along the nozzle centerline and wall. The main goal is to determine the separation point quantitatively when the particles characteristics change. Particles sample trajectories are illustrated throughout the flow field and a qualitative discussion on the way that physical properties of the nozzle exit flow and particles trajectories oscillate is prepared. The existence of solid particulates delays the separation prominently in the cases studied. The bigger particles and the higher particles mass flow fractions respectively advance and delay the separation occurrence. The particles trajectories oscillate when they expose to the crisscrossing (or diamond-shape) shock waves generated outside the nozzle to approach the exit jet conditions to the ambient. The simulation code is validated and verified, respectively, against a one-phase 2D convergent-divergent nozzle flow and a two-phase Jet Propulsion Laboratory nozzle flow, and acceptable agreements are achieved.

  15. Group solution for unsteady free-convection flow from a vertical moving plate subjected to constant heat flux

    Science.gov (United States)

    Kassem, M.

    2006-03-01

    The problem of heat and mass transfer in an unsteady free-convection flow over a continuous moving vertical sheet in an ambient fluid is investigated for constant heat flux using the group theoretical method. The nonlinear coupled partial differential equation governing the flow and the boundary conditions are transformed to a system of ordinary differential equations with appropriate boundary conditions. The obtained ordinary differential equations are solved numerically using the shooting method. The effect of Prandlt number on the velocity and temperature of the boundary-layer is plotted in curves. A comparison with previous work is presented.

  16. Metals analysis for emission spectroscopic in the incandescent discharge operated with continuous flow of He to atmospheric pressure

    International Nuclear Information System (INIS)

    Alzate Londono, Hugo

    1990-01-01

    By means of a small power source a glow discharge in generated with he flowing at atmospheric pressure. Into a device situated to some distance from the discharge an aqueous sample of a metallic ion is injected. The device is then gradually moved to the discharge for producing solvent vaporization, charring, atomization, excitation and finally atomic emission of the sample. By emission spectrophotometer the following elements were analyzed: Ag, Cd, Cr, Cu, Hg, K, Na, Pb and Zn. For every one the useful range and the detection limit were established after founding the best operation conditions for the discharge

  17. Development and computational simulation of thermoelectric electromagnetic pumps for controlling the fluid flow in liquid metal cooled space nuclear reactors

    International Nuclear Information System (INIS)

    Borges, E.M.

    1991-01-01

    Thermoelectric Electromagnetic (TEEM) Pumps can be used for controlling the fluid flow in the primary and secondary circuits of liquid metal cooled space nuclear reactor. In order to simulate and to evaluate the pumps performance, in steady-state, the computer program BEMTE has been developed to study the main operational parameters and to determine the system actuation point, for a given reactor operating power. The results for each stage of the program were satisfactory, compared to experimental data. The program shows to be adequate for the design and simulating of direct current electromagnetic pumps. (author)

  18. Optimizing traffic flow efficiency by controlling lane changes: collective, group and user optima

    NARCIS (Netherlands)

    Yao, S.; Knoop, V.L.; van Arem, B.

    2017-01-01

    Lane changes can lead to disturbances in traffic flow, whilst the uneven distribution of traffic over different lanes as a result of lane changes can also lead to instabilities and congestion on one specific lane. Therefore, giving advice on lane change can be beneficial for both individual drivers

  19. Code development for analysis of MHD pressure drop reduction in a liquid metal blanket using insulation technique based on a fully developed flow model

    International Nuclear Information System (INIS)

    Smolentsev, Sergey; Morley, Neil; Abdou, Mohamed

    2005-01-01

    The paper presents details of a new numerical code for analysis of a fully developed MHD flow in a channel of a liquid metal blanket using various insulation techniques. The code has specially been designed for channels with a 'sandwich' structure of several materials with different physical properties. The code includes a finite-volume formulation, automatically generated Hartmann number sensitive meshes, and effective convergence acceleration technique. Tests performed at Ha ∼ 10 4 have showed very good accuracy. As an illustration, two blanket flows have been considered: Pb-17Li flow in a channel with a silicon carbide flow channel insert, and Li flow in a channel with insulating coating

  20. The Oldest Stars of the Extremely Metal-Poor Local Group Dwarf Irregular Galaxy Leo A

    Science.gov (United States)

    Schulte-Ladbeck, Regina E.; Hopp, Ulrich; Drozdovsky, Igor O.; Greggio, Laura; Crone, Mary M.

    2002-08-01

    We present deep Hubble Space Telescope (HST) single-star photometry of Leo A in B, V, and I. Our new field of view is offset from the centrally located field observed by Tolstoy et al. in order to expose the halo population of this galaxy. We report the detection of metal-poor red horizontal branch stars, which demonstrate that Leo A is not a young galaxy. In fact, Leo A is as least as old as metal-poor Galactic Globular Clusters that exhibit red horizontal branches and are considered to have a minimum age of about 9 Gyr. We discuss the distance to Leo A and perform an extensive comparison of the data with stellar isochrones. For a distance modulus of 24.5, the data are better than 50% complete down to absolute magnitudes of 2 or more. We can easily identify stars with metallicities between 0.0001 and 0.0004, and ages between about 5 and 10 Gyr, in their post-main-sequence phases, but we lack the detection of main-sequence turnoffs that would provide unambiguous proof of ancient (>10 Gyr) stellar generations. Blue horizontal branch stars are above the detection limits but difficult to distinguish from young stars with similar colors and magnitudes. Synthetic color-magnitude diagrams show it is possible to populate the blue horizontal branch in the halo of Leo A. The models also suggest ~50% of the total astrated mass in our pointing to be attributed to an ancient (>10 Gyr) stellar population. We conclude that Leo A started to form stars at least about 9 Gyr ago. Leo A exhibits an extremely low oxygen abundance, only 3% of solar, in its ionized interstellar medium. The existence of old stars in this very oxygen-deficient galaxy illustrates that a low oxygen abundance does not preclude a history of early star formation. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555.

  1. Canonical Models of Geophysical and Astrophysical Flows: Turbulent Convection Experiments in Liquid Metals

    Directory of Open Access Journals (Sweden)

    Adolfo Ribeiro

    2015-03-01

    Full Text Available Planets and stars are often capable of generating their own magnetic fields. This occurs through dynamo processes occurring via turbulent convective stirring of their respective molten metal-rich cores and plasma-based convection zones. Present-day numerical models of planetary and stellar dynamo action are not carried out using fluids properties that mimic the essential properties of liquid metals and plasmas (e.g., using fluids with thermal Prandtl numbers Pr < 1 and magnetic Prandtl numbers Pm ≪ 1. Metal dynamo simulations should become possible, though, within the next decade. In order then to understand the turbulent convection phenomena occurring in geophysical or astrophysical fluids and next-generation numerical models thereof, we present here canonical, end-member examples of thermally-driven convection in liquid gallium, first with no magnetic field or rotation present, then with the inclusion of a background magnetic field and then in a rotating system (without an imposed magnetic field. In doing so, we demonstrate the essential behaviors of convecting liquid metals that are necessary for building, as well as benchmarking, accurate, robust models of magnetohydrodynamic processes in Pm ≪  Pr < 1 geophysical and astrophysical systems. Our study results also show strong agreement between laboratory and numerical experiments, demonstrating that high resolution numerical simulations can be made capable of modeling the liquid metal convective turbulence needed in accurate next-generation dynamo models.

  2. Flutter analysis of hybrid metal-composite low aspect ratio trapezoidal wings in supersonic flow

    Directory of Open Access Journals (Sweden)

    Shokrollahi Saeed

    2017-02-01

    Full Text Available An effective 3D supersonic Mach box approach in combination with non-classical hybrid metal-composite plate theory has been used to investigate flutter boundaries of trapezoidal low aspect ratio wings. The wing structure is composed of two main components including aluminum material (in-board section and laminated composite material (out-board section. A global Ritz method is used with simple polynomials being employed as the trial functions. The most important objective of the present research is to study the effect of composite to metal proportion of hybrid wing structure on flutter boundaries in low supersonic regime. In addition, the effect of some important geometrical parameters such as sweep angle, taper ratio and aspect ratio on flutter boundaries were studied. The results obtained by present approach for special cases like pure metallic wings and results for high supersonic regime based on piston theory show a good agreement with those obtained by other investigators.

  3. Analysis of Metal Flow Behavior and Residual Stress Formation of Complex Functional Profiles under High-Speed Cold Roll-Beating

    Directory of Open Access Journals (Sweden)

    Fengkui Cui

    2018-01-01

    Full Text Available To obtain a good surface layer performance of the complex functional profile during the high-speed cold roll-beating forming process, this paper analyzed the metal plastic flow and residual stress-formed mechanism by using a theoretical model of the metal flow and residual stress generation. By using simulation software, the cold roll-beating forming process of a spline shaft was simulated and analyzed. The metal flow and residual stress formation law in the motion were researched. In a practical experiment, the changes in the grains in the spline tooth profile section and the residual stress distribution on the tooth profile were studied. A microcorrespondence relationship was established between the metal plastic flow and the residual stress generation. The conclusions indicate that the rate at which the metal flow decreases changes gradually at different metal layers. The residual stress value is directly related to the plastic flow difference. As the roll-beating speed increases, the uneven degree of plastic deformation at the workpiece surface increases, and the residual stress in the tooth profile is generally greater. At the same roll-beating speed, the rate change trend of the metal flow decreases gradually from the surface to the inner layer and from the dedendum to the addendum. The residual stress distribution on the surface of the tooth profile decreases from the dedendum to the addendum. These findings provide a basis and guidance for the controlled use of residual stress, obtaining better surface layer quality in the high-speed cold roll-beating process of the complex functional profile.

  4. Liquid-Metal/Water Direct Contact Heat Exchange: Flow Visualization, Flow Stability, and Heat Transfer Using Real-Time X-Ray Imaging

    International Nuclear Information System (INIS)

    Abdulla, Sherif H.; Liu Xin; Anderson, Mark H.; Bonazza, Riccardo; Corradini, Michael L.; Cho, Dae; Page, Richard

    2005-01-01

    Advanced reactor system designs are being considered with liquid-metal cooling connected to a steam power cycle. In addition, current reactor safety systems are considering auxiliary cooling schemes that assure ex-vessel debris coolability utilizing direct water injection into molten material pools to achieve core quenching and eventual coolability. The phenomenon common in both applications is direct contact heat exchange. The current study focuses on detailed measurements of liquid-metal/water direct contact heat exchange that is directly applicable to improvements in effective heat transfer in devices that are being considered for both of these purposes.In this study, a test facility was designed at the University of Wisconsin-Madison to map the operating range of liquid-metal/water direct contact heat exchange. The test section (184-cm height, 45.75-cm width, and 10-cm depth) is a rectangular slice of a larger heat exchange device. This apparatus was used not only to provide measurements of integral thermal performance (i.e., volumetric heat transfer coefficient), but also local heat transfer coefficients in a bubbly flow regime with X-ray imaging based on measured parameters such as bubble formation time, bubble rise velocity, and bubble diameters.To determine these local heat transfer coefficients, a complete methodology of the X-ray radiography for two-phase flow measurement has been developed. With this methodology, a high-energy X-ray imaging system is optimized for our heat exchange experiments. With this real-time, large-area, high-energy X-ray imaging system, the two-phase flow was quantitatively visualized. An efficient image processing strategy was developed by combining several optimal digital image-processing algorithms into a software computational tool written in MATLAB called T-XIP. Time-dependent heat transfer-related variables such as bubble volumes and velocities, were determined. Finally, an error analysis associated with these measurements

  5. New Alkali Metal Flow Battery for Terrestrial and Aerospace Energy Storage Applications

    Data.gov (United States)

    National Aeronautics and Space Administration — This seedling task is to develop new lithium-based flow batteries that will provide several fold improvements in specific energy, cost, simplicity and lifetimes,...

  6. Numerical simulation of the heat transfer at cooling a high-temperature metal cylinder by a flow of a gas-liquid medium

    Science.gov (United States)

    Makarov, S. S.; Lipanov, A. M.; Karpov, A. I.

    2017-10-01

    The numerical modeling results for the heat transfer during cooling a metal cylinder by a gas-liquid medium flow in an annular channel are presented. The results are obtained on the basis of the mathematical model of the conjugate heat transfer of the gas-liquid flow and the metal cylinder in a two-dimensional nonstationary formulation accounting for the axisymmetry of the cooling medium flow relative to the cylinder longitudinal axis. To solve the system of differential equations the control volume approach is used. The flow field parameters are calculated by the SIMPLE algorithm. To solve iteratively the systems of linear algebraic equations the Gauss-Seidel method with under-relaxation is used. The results of the numerical simulation are verified by comparing the results of the numerical simulation with the results of the field experiment. The calculation results for the heat transfer parameters at cooling the high-temperature metal cylinder by the gas-liquid flow are obtained with accounting for evaporation. The values of the rate of cooling the cylinder by the laminar flow of the cooling medium are determined. The temperature change intensity for the metal cylinder is analyzed depending on the initial velocity of the liquid flow and the time of the cooling process.

  7. The Neoproterozoic Lavalleja group in Uruguay: geology and base metal deposits

    International Nuclear Information System (INIS)

    Sánchez-Bettucci, L.; Preciozzi, F.; Ramos, V.; Basei, M.

    2003-01-01

    The Lavalleja Group, which is exposed along the Dom Feliciano Belt is located in the southeast of Uruguay and is represented by metavolcano-sedimentary rocks. It is developed during late Proterozoic-Early Paleozoic Brasiliano orogeny. Based on geochemical signature of the rocks of the Lavalleja Group, mainly metagabbros, basic and acidic metavolcanic rocks, a back-arc basin tectonic setting is suggested by Sánchez-Bettucci et al. (2001). The metamorphic grade increases to the southeast, ranging from lower greenschist facies to lower amphibolite facies in the Fuente del Puma and Zanja del Tigre Formations (Sánchez-Bettucci et al., 2001). The non-metamorphic to anchimetamorphic Minas Formation of Sánchez-Bettucci et al. (2001) is a junior synonim of the Arroyo del Soldado Group, previously defined by Gaucher et al. (1996). The metamorphic mineral assemblages correspond to a low-pressure regional metamorphism associated with a high thermal gradient (Sánchez-Bettucci et al., 2001).A compressive deformational event, that probably corresponds to the basin closure of the Lavalleja Group during a continental collision was recognized. The petrology, geochemistry, metamorphism grade, and tectonic setting are consistent with a back-arc basin for the Lavalleja Group (Sánchez-Bettucci et al., 2001)

  8. Numerical study of metal foam heat sinks under uniform impinging flow

    International Nuclear Information System (INIS)

    Andreozzi, A; Bianco, N; Iasiello, M; Naso, V

    2017-01-01

    The ever-increasing demand for performance improvement and miniaturization of electronics has led to a significant generation of waste heat that must be dissipated to ensure a reliable device operation. The miniaturization of the components complicates this task. In fact, reducing the heat transfer area, at the same required heat rate, it is necessary to increase the heat flux, so that the materials operate in a temperature range suitable to its proper functioning. Traditional heat sinks are no longer capable of dissipating the generated heat and innovative approaches are needed to address the emerging thermal management challenges. Recently, heat transfer in open-cell metal foams under an impinging jet has received attention due to the considerable heat transfer potential of combining two cooling technologies: impinging jet and porous medium. This paper presents a numerical study on Finned Metal Foam (FMF) and Metal Foam (MF) heat sinks under impinging air jet cooling. The analysis is carried out by means of the commercial software COMSOL Multiphysics®. The purpose is to analyze the thermal performance of the metal foam heat sink, finned or not, varying its geometric parameters. Results are presented in terms of predicted dissipated heat rate, convective heat transfer coefficient and pressure losses. (paper)

  9. Platinum Group Metal-free Catalysts for Hydrogen Evolution Reaction in Microbial Electrolysis Cells.

    Science.gov (United States)

    Yuan, Heyang; He, Zhen

    2017-07-01

    Hydrogen gas is a green energy carrier with great environmental benefits. Microbial electrolysis cells (MECs) can convert low-grade organic matter to hydrogen gas with low energy consumption and have gained a growing interest in the past decade. Cathode catalysts for the hydrogen evolution reaction (HER) present a major challenge for the development and future applications of MECs. An ideal cathode catalyst should be catalytically active, simple to synthesize, durable in a complex environment, and cost-effective. A variety of noble-metal free catalysts have been developed and investigated for HER in MECs, including Nickel and its alloys, MoS 2 , carbon-based catalysts and biocatalysts. MECs in turn can serve as a research platform to study the durability of the HER catalysts. This personal account has reviewed, analyzed, and discussed those catalysts with an emphasis on synthesis and modification, system performance and potential for practical applications. It is expected to provide insights into the development of HER catalysts towards MEC applications. © 2017 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Metal oxide, Group V-VI chalcogenides and GaN/AlGaN photodetectors

    Science.gov (United States)

    Hasan, Md. Rezaul

    In this work, a simple, low-cost and catalyst free one-step solution processing of onedimensional Sb2S3 nanostructures on polyimide substrates was done. This structure demonstrated its potential application as a photoconductor in the UV and visible regime. Using-field emission scanning electron microscopy (SEM), grazing incidence X-Ray diffraction, Raman spectra and transmission electron microscopy measurements, it was shown that the Sb 2S3 films have high crystallinity, uniform morphology and nearstoichiometric composition. Further, using tauc plot, it was found that the films have a direct bandgap of 1.67 eV. MSM photodetectors, fabricated using these films showed a clear photo response in both UV as well as visible wavelength. These devices showed UV on/off ratio as high as 160 under the light intensity of 30 mW/cm2 and a small rise time and fall time of 44 ms 28 ms respectively. The effect of geometry of metal pad and bonding wire orientation of a multi-channel FET on the coupling of THz radiation was studied. The spatial variation images were taken by raster scan with the resolution of 0.07 mm steps in both x and y directions. An effective gate bias, where the effect of noise is minimum and photoresponse is maximum, was used for imaging. By applying VGS =-2.8V and VDS =380mV, the images were taken for all different combinations of activated bonding wires and metal pads. It was observed that, effect of bonding wire orientation is negligible for the large source pad as the radiation is coupled basically between drain and gate pad. Effect of drain bonding wire on coupling depends on the maximum width or diameter of metal pad and the incoming wavelength. In this work, Position of activated Drain pad and orientation of respective bonding wire defined the image tilting angle. Voltage drop across the shorting metal between drain pads, also played a role in increasing the asymmetry by selectively exciting a certain portion of FET Channels more than the other portion

  11. Visualization and measurement of liquid velocity field of gas-liquid metal two-phase flow using neutron radiography

    International Nuclear Information System (INIS)

    Saito, Yasushi; Suzuki, Tohru; Matsubayashi, Masahito

    2000-01-01

    In a core melt accident of a fast breeder reactor, a possibility of re-criticality is anticipated in the molten fuel-steel mixture pool. One of the mechanisms to suppress the re-criticality is the boiling of steel in the molten fuel-steel mixture pool because of the negative void reactivity effect. To evaluate the reactivity change due to boiling, it is necessary to know the characteristics of gas-liquid two-phase flow in the molten fuel-steel mixture pool. For this purpose, boiling bubbles in a molten fuel-steel mixture pool were simulated by adiabatic gas bubbles in a liquid metal pool to study the basic characteristics of gas-liquid metal two-phase mixture. Visualization of the two-phase mixture and measurements of liquid phase velocity and void fraction were conducted by using neutron radiography and image processing techniques. From these measurements, the basic characteristics of gas-liquid metal two-phase mixture were clarified. (author)

  12. Classification of the Group Invariant Solutions for Contaminant Transport in Saturated Soils under Radial Uniform Water Flows

    Directory of Open Access Journals (Sweden)

    M. M. Potsane

    2014-01-01

    Full Text Available The transport of chemicals through soils to the groundwater or precipitation at the soils surfaces leads to degradation of these resources. Serious consequences may be suffered in the long run. In this paper, we consider macroscopic deterministic models describing contaminant transport in saturated soils under uniform radial water flow backgrounds. The arising convection-dispersion equation given in terms of the stream functions is analyzed using classical Lie point symmetries. A number of exotic Lie point symmetries are admitted. Group invariant solutions are classified according to the elements of the one-dimensional optimal systems. We analyzed the group invariant solutions which satisfy the physical boundary conditions.

  13. The flow stress of high-purity refractory body-centred cubic metals and its modification by atomic defects

    International Nuclear Information System (INIS)

    Seeger, A.

    1995-01-01

    The strong temperature and strain-rate dependence of the flow stress of high-purity refractory body-centred cubic metals has been shown to be an intrinsic property and is usually ascribed to a high Peierls barrier of a o left angle 111 right angle /2 screw dislocations. These barriers are overcome by the formation of kink pairs on the screw dislocations. The paper reports on recent, very complete flow-stress data on ultra-high purity Mo crystals obtained by two different experimental techniques and covering the temperature range 4 K to 460 K. The results are in accord with earlier work of Brunner and Diehl on α-Fe, who showed that below the so-called knee temperature, T K , three regimes in the temperature variation of the flow-stress should be distinguished. Two of them are fully accounted for by the same glide mechanism, namely elementary glide steps on {211} planes. The so-called upper bend separating these two regimes in an inherent feature of the theory of kink-pair formation and does not indicate a change in the glide mechanism. There is, however, strong evidence that the so-called lower bend, separating the range of {211} elementary glide steps from the low-temperature flow-stress regime, is due to a change in the glide mechanism. It is argued that at the lower bend the screw-dislocation cores undergo a ''first-order phase transition'' from a low-temperature configuration that allows glide of a given screw dislocation on any of its three {110} glide planes to a high-temperature configuration that can glide only on one definite {211} plane. Between T K and the lower-bend temperature, T, bcc metals may show the unique phenomena of alloy and irradiation softening. With regard to the latter phenomenon, Brunner and Diehl distinguish between ''primary'' and ''secondary'' softening. It is shown that alloy softening and the ''secondary irradiation softening'' of bcc metals may be explained by an ''overheating'' of the phase transition in the dislocation core. (orig./WL)

  14. A study on the flow-accelerated corrosion characteristics of galvanically coupled dissimilar metals

    International Nuclear Information System (INIS)

    Choi, Yoon Seok; Kim, Jung Gu

    2002-01-01

    The flow-accelerated corrosion characteristics of a carbon steel(CS) coupled to stainless steel(SS) were investigated in deaerated alkaline-chloride solutions with velocities (0, 0.2, 0.4 and 0.6 m/s), pH (8, 9 and 10) and temperatures (25, 50 and 75 .deg. C). The electrochemical properties of specimens were investigated by potentiodynamic test and galvanic corrosion test using RCE (Rotating Cylinder Electrode). CS did not show passive behavior while SS show passive behavior in the alkaline-chloride solution. Galvanic corrosion tests were conducted as a function of flow velocities, pH and temperature. The galvanic current density increases with increasing flow velocity and temperature, but decreased with increasing pH. Flow velocity had a small effect on the galvanic current density at 25 .deg. C, whereas the flow velocity increased galvanic current density significantly at 50 and 75 .deg. C. This might be due to the increased solubility of magnetite at the higher temperature

  15. Determining the selectivity of divalent metal cations for the carboxyl group of alginate hydrogel beads during competitive sorption.

    Science.gov (United States)

    An, Byungryul; Lee, Healim; Lee, Soonjae; Lee, Sang-Hyup; Choi, Jae-Woo

    2015-11-15

    To investigate the competitive sorption of divalent metal ions such as Ca(2+), Cu(2+), Ni(2+), and Pb(2+) on alginate hydrogel beads, batch and column tests were conducted. The concentration of carboxyl group was found to be limited in the preparation of spherical hydrogel beads. From kinetic test results, 80% of sorption was observed within 4h, and equilibrium was attained in 48 h. According to the comparison of the total uptake and release, divalent metal ions were found to stoichiometrically interact with the carboxyl group in the alginate polymer chain. From the Langmuir equation, the maximum capacities of Pb(2+), Cu(2+), and Ni(2+) were calculated to be 1.1, 0.48, and 0.13 mmol/g, respectively. The separation factor (α) values for αPb/Cu, αPb/Ni, and αCu/Ni were 14.0, 98.9, and 7.1, respectively. The sorption capacity of Pb(2+) was not affected by the solution pH; however, the sorption capacities of Cu(2+) and Ni(2+) decreased with increasing solution pH, caused by competition with hydrogen. According to the result from the fixed column test, Pb(2+) exhibited the highest affinity, followed by Cu(2+) and Ni(2+), which is in exact agreement with those of kinetic and isotherm tests. The sorbent could be regenerated using 4% HCl, and the regenerated sorbent exhibited 90% capacity upto 9 cycles. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. The stability boundary of group-III transition metal diboride ScB 2 (0 0 0 1) surfaces

    Science.gov (United States)

    Zhao, Hui; Qin, Na

    2012-01-01

    Experimental observations and theoretical investigations exhibit that a group-IV(V) transition metal diboride (0 0 0 1) surface is terminated with a 1 × 1 TM(B) layer. As to a group-III transition metal diboride, we have investigated the stability boundary of ScB2 (0 0 0 1) surfaces using first principles total energy plane-wave pseudopotential method based on density functional theory. The Mulliken charge population analysis shows that Sc atoms in the second layer cannot provide B atoms in the first layer with sufficient electrons to form a complete graphene-like boron layer. We also found that the charge transfer between the first and the second layer for the B-terminated surface is more than that for Sc-terminated surface. It elucidates the reason that the outermost interlayer spacing contract more strongly in the B-terminated surface than in the Sc-terminated surface. The surface energies of both terminated ScB2 (0 0 0 1) surfaces as a function of the chemical potential of B are also calculated to check the relative stability of the two surface structures.

  17. First determination of the levels of platinum group metals in Manta birostris (manta ray) caught along the Ghanaian coastline.

    Science.gov (United States)

    Essumang, D K

    2010-06-01

    Tissues from Manta birostris caught by fishermen from Dixcove in the western part of Ghana were analyzed for their Platinum, palladium and rhodium concentrations (PGM). The use of chondrichthyan fish has permitted the study of trace levels of Platinum group metals (PGMs) which have travelled very far into the sea. The analysis showed that Ghana's coastline is fairly polluted with these platinum group metals (PGMs). PGM concentration in manta ray recorded a range of (0.15-0.85) microg/g for Pt, (0.033-0.67) microg/g for Pd and (0.007-0.145) microg/g for Rh. Comparing these values to the UK dietary intake of 0.2 microg/day for Pt and Rh and 1.0 microg/day for Pd, its indicates that the values obtained from the analysis for Pt was above the required level. This is the first study to show the accumulation of PGM in chondrichthyan fish, although the sources of this pollution are not clear as manta birostris is migratory and therefore need to be investigated further. The presence of the PGM is very significant, since manta ray meat is consumed in Ghana. This may presents a health risk, due to a possible accumulation of PGMs in humans.

  18. Heat transfer of liquid-metal magnetohydrodynamic flow with internal heat generation

    International Nuclear Information System (INIS)

    Kumamaru, Hiroshige; Kurita, Kazuhisa; Kodama, Satoshi

    2000-01-01

    Numerical calculations on heat transfer of a magnetohydrodynamic (MHD) flow with internal heat generation in a rectangular channel have been performed for the cases of very-large Hartmann numbers, finite wall conductivities and small aspect ratio (i.e. small length ratios of the channel side perpendicular to the applied magnetic field and the side parallel to the field), simulating typical conditions for a fusion-reactor blanket. The Nusselt numbers of the MHD flow in rectangular channels with aspect ratios of 1/10 to 1/40 for Hartmann numbers of ∼5 x 10 5 become ∼10 times higher than those for the corresponding flow under no magnetic field. The Nusselt number becomes higher as the internal heat generation rate increases as far as the heat generation rates in a fusion reactor blanket are considered. (author)

  19. Uptake of traffic-related heavy metals and platinum group elements (PGE) by plants

    Energy Technology Data Exchange (ETDEWEB)

    Schaefer, J.; Hannker, D.; Eckhardt, J.D.; Stueben, D. [Institute of Petrography and Geochemistry, University of Karlsruhe, Karlsruhe (Germany)

    1998-04-23

    The distribution of the platinum group elements (PGE) caused by traffic emissions from autoexhaust catalysts has been determined in soils and different types of plants. The plants (spinach, cress, phacelia, stinging nettle) were cultivated on different soils collected from areas adjacent to a German highway and on uncontaminated sandy and clayey soils. The main result of the experiments was a measurable transfer of PGE from contaminated soil to plants. Following the definition of Sauerbeck (Beurteilung von Schwermetallkontaminationen im Boden. Frankfurt/Main: Dechema-Fachgespraeche, 1989:281-316), Pt, Rh and Pd transfer coefficients are within the range of immobile to moderately mobile elements, such as Cu. The transfer coefficient decreases from Pd>Pt{>=}Rh. Palladium therefore is the most biologically available of this element group

  20. Transient Magnetohydrodynamic Liquid-Metal Flows in a Rectangular Channel with a Moving Conducting Wall

    Science.gov (United States)

    1988-05-01

    use of liquid metals for current collectors in homopolar motors and generators has led to the design of machines of superior performance. The steady...In some applications of homopolar generators it becomes necessary not only to start and stop the machines but also to operate them under oscillating...conditions. This could be the case in an application where a homopolar generator behaves as an extremely high energy capacitor. Therefore, one is

  1. Subsurface flow wetlands for the removal of arsenic and metals from contaminated water

    OpenAIRE

    Lizama Allende, Katherine

    2017-01-01

    The presence of arsenic (As) in aquatic environments is a worldwide concern due to its toxicity and chronic effects. In many cases, the choice of treatment technologies is limited due to the isolated location of the water source and the high cost of conventional treatment technologies. In addition, other pollutants are often found alongside As, such as iron (Fe) and boron (B). Constructed wetlands have shown capability to remove As and metals. However, few experimental studies have been under...

  2. The attachment of metal-chelating groups to proteins: tagging of albumin by diazonium coupling and use of the products as radiopharmaceuticals

    International Nuclear Information System (INIS)

    Leung, C.S.H.; Meares, C.F.; Goodwin, D.A.

    1978-01-01

    The ability to attach firmly chelated metal ions or powerful chelating agents to sites on biological molecules can enhance the utility of a number of physical techniques now used in the study of biological systems. A 'bifunctional' chelating agent, containing both an EDTA group and a diazonium group, has been prepared and coupled to human serum albumin. The extent of labeling under various conditions and the amino-acid sidechains labeled have been investigated. The reaction of protein-bound chelating groups with added metal ions has been studied, with the finding that only about 40-50% of these groups are available to bind metal ions. Proteolysis of the products leads to recovery of full metal-binding capacity. Properties of the products in vivo are discussed. (author)

  3. Using NIF to Test Theories of High-Pressure, High-Rate Plastic Flow in Metals

    Science.gov (United States)

    Rudd, Robert E.; Arsenlis, A.; Cavallo, R. M.; Huntington, C. M.; McNaney, J. M.; Park, H. S.; Powell, P.; Prisbrey, S. T.; Remington, B. A.; Swift, D.; Wehrenberg, C. E.; Yang, L.

    2017-10-01

    Precisely controlled plasmas are playing key roles both as pump and probe in experiments to understand the strength of solid metals at high energy density (HED) conditions. In concert with theoretical advances, these experiments have enabled a predictive capability to model material strength at Mbar pressures and high strain rates. Here we describe multiscale strength models developed for tantalum starting with atomic bonding and extending up through the mobility of individual dislocations, the evolution of dislocation networks and so on until the ultimate material response at the scale of an experiment. Experiments at the National Ignition Facility (NIF) probe strength in metals ramp compressed to 1-8 Mbar. The model is able to predict 1 Mbar experiments without adjustable parameters. The combination of experiment and theory has shown that solid metals can behave significantly differently at HED conditions. We also describe recent studies of lead compressed to 3-5 Mbar. Work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA273.

  4. Microstructural evolution and homogeneous viscous flow behavior of a Cu–Zr based bulk metallic glass composites

    International Nuclear Information System (INIS)

    Zhang, X.Y.; Yuan, Z.Z.; Li, D.X.

    2014-01-01

    Highlights: • Stress–strain behaviors of the BMGCs are strain rate and temperature dependent. • Micro-crystals are compressed to concave polygon in shape and align in line. • Nano-crystals nuclear and aggregate during high temperature deformation. • Deformation behavior is governed by homogeneous flow of the amorphous matrix. - Abstract: The high temperature compression behavior of Cu 40 Zr 44 Ag 8 Al 8 rods with 6 mm in diameter was investigated and compared with the literature data. Microstructure of the as-cast rods were characterized by X-ray diffraction, scanning electron microscopy and high resolution transmission electron microscope in the composites state with microscale Al 3 Zr particles embedded in the amorphous matrix. Deformation results show that the stress–strain behaviors of the bulk metallic glass composites (BMGCs) are strain rate and temperature dependent. In addition, SEM observations reveal that the initially spherical and randomly distributed microscale particles in the amorphous matrix deform to concave polygon in shape and align perpendicular to the load direction during the compression. Meanwhile nano-crystals precipitate continuously from the matrix and aggregate during deformation. Rheological analysis show that the BMGCs exhibit a transition from Newtonian to non-Newtonian in flow behavior dependent on the stain rate. Particles in the amorphous matrix have reinforcement effect on the BMGCs, but the deformation behavior is still dominated by the homogeneous flow of the amorphous matrix phase

  5. Influence of oxygen flow rate on metal-insulator transition of vanadium oxide thin films grown by RF magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Xu; Liu, Xinkun; Li, Haizhu; Huang, Mingju [Henan University, Key Lab of Informational Opto-Electronical Materials and Apparatus, School of Physics and Electronics, Kaifeng (China); Zhang, Angran [South China Normal University, Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, Guangzhou (China)

    2017-03-15

    High-quality vanadium oxide (VO{sub 2}) films have been fabricated on Si (111) substrates by radio frequency (RF) magnetron sputtering deposition method. The sheet resistance of VO{sub 2} has a significant change (close to 5 orders of magnitude) in the process of the metal-insulator phase transition (MIT). The field emission-scanning electron microscope (FE-SEM) results show the grain size of VO{sub 2} thin films is larger with the increase of oxygen flow. The X-ray diffraction (XRD) results indicate the thin films fabricated at different oxygen flow rates grow along the (011) crystalline orientation. As the oxygen flow rate increases from 3 sccm to 6 sccm, the phase transition temperature of the films reduces from 341 to 320 K, the width of the thermal hysteresis loop decreases from 32 to 9 K. The thin films fabricated in the condition of 5 sccm have a high temperature coefficient of resistance (TCR) -3.455%/K with a small resistivity of 2.795 ρ/Ω cm. (orig.)

  6. Mathematical modeling of turbulent stratified flows. Application of liquid metal fast breeders

    Energy Technology Data Exchange (ETDEWEB)

    Villand, M; Grand, D [CEA-Service des Transferts Thermiques, Grenoble (France)

    1983-07-01

    Mathematical model of turbulent stratified flow was proposed under the following assumptions: Newtonian fluid; incompressible fluid; coupling between temperature and momentum fields according to Boussinesq approximation; two-dimensional invariance for translation or rotation; coordinates cartesian or curvilinear. Solutions obtained by the proposed method are presented.

  7. Influence of group II metals on Radium-226 concentration ratios in the native green plum (Buchanania obovata) from the Alligator Rivers Region, Northern Territory, Australia

    International Nuclear Information System (INIS)

    Medley, Peter; Bollhöfer, Andreas

    2016-01-01

    In this study, uptake of Ra from soil, and the influence of group II metals on Ra uptake, into the stones and edible flesh of the fruit of the wild green plum, Buchanania obovata, was investigated. Selective extraction of the exchangeable fraction of the soil samples was undertaken but was not shown to more reliably predict Ra uptake than total soil Ra activity concentration. Comparison of the group II metal to Ca ratios (i.e. Sr/Ca, Ba/Ca, Ra/Ca) in the flesh with exchangeable Ca shows that Ca outcompetes group II metals for root uptake and that the uptake pathway discriminated against group II metals relative to ionic radius, with uptake of Ca > Sr > Ba >> Ra. Flesh and stone analysis showed that movement of group II metals to these components of the plant, after root uptake, was strongly related. This supports the hypothesis that Sr, Ba and Ra are being taken up as analogue elements, and follow the same uptake and translocation pathways, with Ca. Comparison with previously reported data from a native passion fruit supports the use of total soil CRs on natural, undisturbed sites. As exchangeable CRs for Ra reach a saturation value it may be possible to make more precise predictions using selective extraction techniques for contaminated or disturbed sites. - Highlights: • We studied uptake of Ra-226 from soil into Buchanania obovata. • The influence of group II metals (Sr, Ba and Ca) on Ra uptake was investigated. • The exchangeable Ra fraction of the soil was not a more reliable predictor of Ra uptake than total soil Ra. • Ca outcompetes group II metals Sr, Ba and Ra for root uptake. • Uptake discriminated against group II metals relative to ionic radius, with uptake of Ca > Sr > Ba >> Ra.

  8. Exploiting flow Injection and sequential injection schemes for trace metal determinations by electrothermal atomic absorption spectrometry

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    Determination of low or trace-level amounts of metals by electrothermal atomic absorption spectrometry (ETAAS) often requires the use of suitable preconcentration and/or separation procedures in order to attain the necessary sensitivity and selectivity. Such schemes are advantageously executed...... by superior performance and versatility. In fact, two approaches are conceivable: The analyte-loaded ion-exchange beads might either be transported directly into the graphite tube where they are pyrolized and the measurand is atomized and quantified; or the loaded beads can be eluted and the eluate forwarded...

  9. Genetic affinity among five different population groups in India reflecting a Y-chromosome gene flow.

    Science.gov (United States)

    Saha, Anjana; Sharma, Swarkar; Bhat, Audesh; Pandit, Awadesh; Bamezai, Ramesh

    2005-01-01

    Four binary polymorphisms and four multiallelic short tandem repeat (STR) loci from the nonrecombining region of the human Y-chromosome were typed in different Indian population groups from Uttar Pradeh (UP), Bihar (BI), Punjab (PUNJ), and Bengal (WB) speaking the Indo-Aryan dialects and from South India (SI) with the root in the Dravidian language. We identified four major haplogroups [(P) 1+, (C and F) 2+, (R1a) 3, (K) 26+] and 114 combinations of Y-STR haplotypes. Analyses of the haplogroups indicated no single origin from any lineage but a result of a conglomeration of different lineages from time to time. The phylogenetic analyses indicate a high degree of population admixture and a greater genetic proximity for the studied population groups when compared with other world populations.

  10. Material and Energy Flows Associated with Select Metals in GREET 2. Molybdenum, Platinum, Zinc, Nickel, Silicon

    Energy Technology Data Exchange (ETDEWEB)

    Benavides, Pahola T. [Argonne National Lab. (ANL), Argonne, IL (United States); Dai, Qiang [Argonne National Lab. (ANL), Argonne, IL (United States); Sullivan, John L. [Argonne National Lab. (ANL), Argonne, IL (United States); Kelly, Jarod C. [Argonne National Lab. (ANL), Argonne, IL (United States); Dunn, Jennifer B. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2015-09-01

    In this work, we analyzed the material and energy consumption from mining to production of molybdenum, platinum, zinc, and nickel. We also analyzed the production of solar- and semiconductor-grade silicon. We described new additions to and expansions of the data in GREET 2. In some cases, we used operating permits and sustainability reports to estimate the material and energy flows for molybdenum, platinum, and nickel, while for zinc and silicon we relied on information provided in the literature.

  11. Novel bacterial gas sensor proteins with transition metal-containing prosthetic groups as active sites.

    Science.gov (United States)

    Aono, Shigetoshi

    2012-04-01

    Gas molecules function as signaling molecules in many biological regulatory systems responsible for transcription, chemotaxis, and other complex physiological processes. Gas sensor proteins play a crucial role in regulating such biological systems in response to gas molecules. New sensor proteins that sense oxygen or nitric oxide have recently been found, and they have been characterized by X-ray crystallographic and/or spectroscopic analysis. It has become clear that the interaction between a prosthetic group and gas molecules triggers dynamic structural changes in the protein backbone when a gas sensor protein senses gas molecules. Gas sensor proteins employ novel mechanisms to trigger conformational changes in the presence of a gas. In gas sensor proteins that have iron-sulfur clusters as active sites, the iron-sulfur clusters undergo structural changes, which trigger a conformational change. Heme-based gas sensor proteins reconstruct hydrogen-bonding networks around the heme and heme-bound ligand. Gas sensor proteins have two functional states, on and off, which are active and inactive, respectively, for subsequent signal transduction in response to their physiological effector molecules. To fully understand the structure-function relationships of gas sensor proteins, it is vital to perform X-ray crystal structure analyses of full-length proteins in both the on and off states.

  12. Spectrophotometric and electrochemical study for metal ion binding of azocalix[4]arene bearing p-ethylester group

    Science.gov (United States)

    Kim, Tae Hyun

    2017-05-01

    The complexation behavior of diazophenylcalix[4]arene bearing para-ethylester group (p-EAC) for alkali, alkaline earth, various heavy and transition metal ions (Li+, Na+, K+, Rb+, Cs+, Mg2 +, Ca2 +, Sr2 +, Ba2 +, Cr3 +, Fe2 +, Co2 +, Ni2 +, Cu2 +, Zn2 +, Pb2 +) was investigated by spectrophotometric and electrochemical methods in CH3CN. p-EAC exhibits decreased absorbance at 353 nm in the presence of Cr3 +, Fe2 +, Pb2 +, and Cu2 +. The spectra of p-EAC showed bathochromic shift in absorption maximum on the addition of Cr3 +, Fe2 +, or Pb2 + with decreasing order of absorbance (Cr3 + > Fe2 + > Pb2 +), and on the other hand, hypsochromic shift on the addition of Cu2 +. This leads to the selective coloration from light green to orange and colorless for Cr3 + and Cu2 + that can be detected by the naked eye, respectively. In electrochemistry experiments, p-EAC also showed two different types of voltammetric changes toward Cr3 +, Fe2 +, or Pb2 +, and toward Cu2 +, whereas no significant changes occurred in the presence of the other metal ions. Nonlinear fitting curve procedure was used to determine a logarithmic value of 5.20, 4.92, 3.54 and 4.80 for the stability constants of the complex of p-EAC with Cr3 +, Fe2 +, Pb2 +, and Cu2 +, respectively.

  13. “Slowing” and “Narrowing” the Flow of Metals for Consumer Goods: Evaluating Opportunities and Barriers

    Directory of Open Access Journals (Sweden)

    Elsa Dominish

    2018-04-01

    Full Text Available Metal resources are essential materials for many consumer products, including vehicles and a wide array of electrical and electronic goods. These metal resources often cause adverse social and environmental impacts from their extraction, supply and disposal, and it is therefore important to increase the sustainability of their production and use. A broad range of strategies and actions to improve the sustainability of resources are increasingly being discussed within the evolving concept of the circular economy. This paper uses this lens to evaluate the opportunities and barriers to improve the sustainability of metals in consumer products in Australia, with a focus on strategies that “slow” and “narrow” material flow loops. We have drawn on Allwood’s characterisation of material efficiency strategies, as they have the potential to reduce the total demand for metals. These strategies target the distribution, sale, and use of products, which have received less research attention compared to the sustainability of mining, production, and recycling, yet it is vitally important for changing patterns of consumption in a circular economy. Specifically, we have considered the strategies of product longevity (life extension, intensity of use, repair, and resale, remanufacturing, component reuse, and using less material for the same product or service (digitisation, servicisation, and light-weighting. Within the Australian context, this paper identifies the strategies that have the greatest opportunity to increase material efficiency for metal-containing products (such as mobility, household appliances, and personal electronics, by evaluating current implementation of these strategies and identifying the material, economic, and social barriers to and opportunities for expanding these strategies. We find that many of these strategies have been successfully implemented for mobility, while applying these strategies to personal electronics remains

  14. Metal contamination budget at the river basin scale: an original Flux-Flow Analysis (F2A for the Seine River

    Directory of Open Access Journals (Sweden)

    L. Lestel

    2007-11-01

    Full Text Available Material flow analysis and environmental contamination analysis are merged into a Flux-Flow analysis (F2A as illustrated for the metal circulation in the Seine River catchment. F2A combines about 30 metal flows in the anthroposphere (14 million people and/or metal fluxes in the environment (atmosphere, soils, and aquatic system originating from two dozens of sources. The nature and quality of data is very heterogeneous going from downscaled national economic statistics to upscaled daily environmental surveys.

    A triple integration is performed: space integration over the catchment (65 000 km2, time integration for the 1950–2000 trend analysed at 5 year resolution, and a conceptual integration resulting in two F2A indicators.

    Despite the various data sources an average metal circulation is established for the 1994–2003 period and illustrated for zinc: (i metal circulation in the anthroposphere is now two orders of magnitude higher than river outputs, (ii long term metal storage, and their potential leaks, in soils, wastedumps and structures is also orders of magnitude higher than present river fluxes. Trend analysis is made through two F2A indicators, the per capita excess load at the river outlet and the leakage ratio (excess fluxes/metal demand. From 1950 to 2000, they both show a ten fold improvement of metal recycling while the metal demand has increased by 2.5 to 5 for Cd, Cu, Cr, Pb and Zn, and the population by 50%.

  15. A revised catalog of CfA galaxy groups in the Virgo/Great Attractor flow field

    Science.gov (United States)

    Nolthenius, Richard

    1993-01-01

    A new identification of groups and clusters in the CfAl Catalog of Huchra, et al. (1983) is presented, using a percolation algorithm to identify density enhancements. The procedure differs from that of the original Geller and Huchra (1983; GH) catalog in several important respects; galaxy distances are calculated from the Virgo-Great Attractor flow model of Faber and Burnstein (1988), the adopted distance linkage criteria is only approx. 1/4 as large as in the Geller and Huchra catalog, the sky link relation is taken from Nolthenius and White (1987), correction for interstellar extinction is included, and 'by-hand' adjustments to group memberships are made in the complex regions of Virgo/Coma I/Ursa Major and Coma/A1367 (to allow for varying group velocity dispersions and to trim unphysical 'spider arms'). Since flow model distances are poorly determined in these same regions, available distances from the IR Tully-Fisher planetary nebula luminosity function and surface brightness resolution methods are adopted if possible.

  16. Various sizes of sliding event bursts in the plastic flow of metallic glasses based on a spatiotemporal dynamic model

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Jingli, E-mail: renjl@zzu.edu.cn, E-mail: g.wang@shu.edu.cn; Chen, Cun [School of Mathematics and Statistics, Zhengzhou University, Zhengzhou 450001 (China); Wang, Gang, E-mail: renjl@zzu.edu.cn, E-mail: g.wang@shu.edu.cn [Laboratory for Microstructures, Shanghai University, Shanghai 200444 (China); Cheung, Wing-Sum [Department of Mathematics, The University of HongKong, HongKong (China); Sun, Baoan; Mattern, Norbert [IFW-dresden, Institute for Complex Materials, P.O. Box 27 01 16, D-01171 Dresden (Germany); Siegmund, Stefan [Department of Mathematics, TU Dresden, D-01062 Dresden (Germany); Eckert, Jürgen [IFW-dresden, Institute for Complex Materials, P.O. Box 27 01 16, D-01171 Dresden (Germany); Institute of Materials Science, TU Dresden, D-01062 Dresden (Germany)

    2014-07-21

    This paper presents a spatiotemporal dynamic model based on the interaction between multiple shear bands in the plastic flow of metallic glasses during compressive deformation. Various sizes of sliding events burst in the plastic deformation as the generation of different scales of shear branches occurred; microscopic creep events and delocalized sliding events were analyzed based on the established model. This paper discusses the spatially uniform solutions and traveling wave solution. The phase space of the spatially uniform system applied in this study reflected the chaotic state of the system at a lower strain rate. Moreover, numerical simulation showed that the microscopic creep events were manifested at a lower strain rate, whereas the delocalized sliding events were manifested at a higher strain rate.

  17. Changes of the corrosion potential of iron in stagnation and flow conditions and their relationship with metal release.

    Science.gov (United States)

    Fabbricino, Massimiliano; Korshin, Gregory V

    2014-10-01

    This study examined the behavior of corrosion potential (Ecorr) of iron exposed to drinking water during episodes of stagnation and flow. These measurements showed that during stagnation episodes, Ecorr values decrease prominently and consistently. This decrease is initially rapid but it becomes slower as the stagnation time increases. During flow episodes, the Ecorr values increase and reach a quasi-steady state. Experiments with varying concentrations of dissolved oxygen showed that the decrease of Ecorr values characteristic for stagnation is likely to be associated with the consumption of dissolved oxygen by the exposed metal. The corrosion potential of iron and its changes during stagnation were sensitive to the concentrations of sulfate and chloride ions. Measurements of iron release showed that both the absolute values of Ecorr measured prior to or after stagnation episodes were well correlated with the logarithms of concentrations of total iron. The slope of this dependence showed that the observed correlations between Ecorr values and Fe concentrations corresponded to the coupling between the oxidant consumption and changes of Fe redox status. These results demonstrate that in situ Ecorr measurements can be a sensitive method with which to ascertain effects of hydrodynamic conditions and short-term variations of water chemistry on metal release and corrosion in drinking water. This approach is valuable practically because Ecorr measurements are precise, can be carried out in situ with any desired time resolution, do not affect the state of exposed surface in any extent and can be carried out with readily available equipment. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Effect of metallic walls on dynamos generated by laminar boundary-driven flow in a spherical domain.

    Science.gov (United States)

    Guervilly, Céline; Wood, Toby S; Brummell, Nicholas H

    2013-11-01

    We present a numerical study of dynamo action in a conducting fluid encased in a metallic spherical shell. Motions in the fluid are driven by differential rotation of the outer metallic shell, which we refer to as "the wall." The two hemispheres of the wall are held in counter-rotation, producing a steady, axisymmetric interior flow consisting of differential rotation and a two-cell meridional circulation with radial inflow in the equatorial plane. From previous studies, this type of flow is known to maintain a stationary equatorial dipole by dynamo action if the magnetic Reynolds number is larger than about 300 and if the outer boundary is electrically insulating. We vary independently the thickness, electrical conductivity, and magnetic permeability of the wall to determine their effect on the dynamo action. The main results are the following: (a) Increasing the conductivity of the wall hinders the dynamo by allowing eddy currents within the wall, which are induced by the relative motion of the equatorial dipole field and the wall. This processes can be viewed as a skin effect or, equivalently, as the tearing apart of the dipole by the differential rotation of the wall, to which the field lines are anchored by high conductivity. (b) Increasing the magnetic permeability of the wall favors dynamo action by constraining the magnetic field lines in the fluid to be normal to the wall, thereby decoupling the fluid from any induction in the wall. (c) Decreasing the wall thickness limits the amplitude of the eddy currents, and is therefore favorable for dynamo action, provided that the wall is thinner than the skin depth. We explicitly demonstrate these effects of the wall properties on the dynamo field by deriving an effective boundary condition in the limit of vanishing wall thickness.

  19. Half-metallicity and electronic structures for carbon-doped group III-nitrides: Calculated with a modified Becke-Johnson potential

    Science.gov (United States)

    Fan, Shuai-wei; Wang, Ri-gao; Xu, Pemg

    2016-09-01

    The electronic structures and magnetism for carbon-doped group III-nitrides are investigated by utilizing the first principle method with the modified Becke-Johnson potential. Calculations show that carbon substituting cations (anions) would induce the group III-nitrides to be paramagnetic metals (half-metallic ferromagnets). Single carbon substituting nitrogen could produce 1.00μB magnetic moment. Electronic structures indicate that the carriers-mediated double-exchange interaction plays a crucial role in forming the ferromagnetism. Based on the mean-field theory, the Curie temperature for carbon-doped group III-nitrides would be above the room temperature. Negative chemical pair interactions imply that carbon dopants tend to form clustering distribution in group III-nitrides. The nitrogen vacancy would make the carbon-doped group III-nitrides lose the half-metallic ferromagnetism.

  20. Electrochemically Smart Bimetallic Materials Featuring Group 11 Metals: In-situ Conductive Network Generation and Its Impact on Cell Capacity

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, Esther [Stony Brook Univ., NY (United States)

    2016-11-30

    Our results for this program “Electrochemically smart bimetallic materials featuring Group 11 metals: in-situ conductive matrix generation and its impact on battery capacity, power and reversibility” have been highly successful: 1) we demonstrated material structures which generated in-situ conductive networks through electrochemical activation with increases in conductivity up to 10,000 fold, 2) we pioneered in situ analytical methodology to map the cathodes at several stages of discharge through the use of Energy Dispersive X-ray Diffraction (EDXRD) to elucidate the kinetic dependence of the conductive network formation, and 3) we successfully designed synthetic methodology for direct control of material properties including crystallite size and surface area which showed significant impact on electrochemical behavior.

  1. Buried Volume Analysis for Propene Polymerization Catalysis Promoted by Group 4 Metals: a Tool for Molecular Mass Prediction

    KAUST Repository

    Falivene, Laura; Cavallo, Luigi; Talarico, Giovanni

    2015-01-01

    A comparison of the steric properties of homogeneous single site catalysts for propene polymerization using the percentage of buried volume (%VBur) as molecular descriptor is reported. The %VBur calculated on the neutral precursors of the active species seems to be a reliable tool to explain several experimental data related to the propene insertion and to the monomer chain transfer. Interestingly, a linear correlation between the buried volume calculated for a large set of neutral precursors and the energetic difference between propagation and termination steps calculated by DFT methods is found for Group 4 metal catalysts. The “master curves” derived for Ti, Zr and Hf confirm not only that the %VBur is an appropriate molecular descriptor for the systems considered but also that it could be used as tool for a large computational screening of new ligands.

  2. Buried Volume Analysis for Propene Polymerization Catalysis Promoted by Group 4 Metals: a Tool for Molecular Mass Prediction

    KAUST Repository

    Falivene, Laura

    2015-10-02

    A comparison of the steric properties of homogeneous single site catalysts for propene polymerization using the percentage of buried volume (%VBur) as molecular descriptor is reported. The %VBur calculated on the neutral precursors of the active species seems to be a reliable tool to explain several experimental data related to the propene insertion and to the monomer chain transfer. Interestingly, a linear correlation between the buried volume calculated for a large set of neutral precursors and the energetic difference between propagation and termination steps calculated by DFT methods is found for Group 4 metal catalysts. The “master curves” derived for Ti, Zr and Hf confirm not only that the %VBur is an appropriate molecular descriptor for the systems considered but also that it could be used as tool for a large computational screening of new ligands.

  3. Group 13 ligand supported heavy-metal complexes: first structural evidence for gallium-lead and gallium-mercury bonds.

    Science.gov (United States)

    Prabusankar, Ganesan; Gemel, Christian; Winter, Manuela; Seidel, Rüdiger W; Fischer, Roland A

    2010-05-25

    Heavy-metal complexes of lead and mercury stabilized by Group 13 ligands were derived from the oxidative addition of Ga(ddp) (ddp=HC(CMeNC(6)H(3)-2,6-iPr(2))(2), 2-diisopropylphenylamino-4-diisopropyl phenylimino-2-pentene) with corresponding metal precursors. The reaction of Me(3)PbCl and Ga(ddp) afforded compound [{(ddp)Ga(Cl)}PbMe(3)] (1) composed of Ga-Pb(IV) bonds. In addition, the monomeric plumbylene-type compound [{(ddp)Ga(OSO(2)CF(3))}(2)Pb(thf)] (2a) with an unsupported Ga-Pb(II)-Ga linkage was obtained by the reaction of [Pb(OSO(2)CF(3))(3)] with Ga(ddp) (2 equiv). Compound 2a falls under the rare example of a discrete plumbylene-type compound supported by a nonclassical ligand. Interesting structural changes were observed when [Pb(OSO(2)CF(3))(3)]2.H(2)O was treated with Ga(ddp) in a 1:2 ratio to yield [{(ddp)Ga(mu-OSO(2)CF(3))}(2)(OH(2))Pb] (2b) at below -10 degrees C. Compound 2b consists of a bent Ga-Pb-Ga backbone with a bridging triflate group between the Ga-Pb bond and a weakly interacting water molecule at the gallium center. Similarly, the reaction of mercury thiolate Hg(SC(6)F(5)) with Ga(ddp) (2 equiv) produced the bimetallic homoleptic compounds anti-[{(ddp)Ga(SC(6)F(5))}(2)Hg] (3a) and gauche-[{(ddp)Ga(SC(6)F(5))}(2)Hg] (3b), respectively, with a linear Ga-Hg-Ga linkage. Compounds 1-3 were structurally characterized and these are the first examples of compounds comprised of Ga-Pb(II), Ga-Pb(IV), and Ga-Hg bonds.

  4. Contamination from gold and platinum-group metals mining in the Gulf of Darién, Colombia

    Science.gov (United States)

    Vasquez-Bedoya, L.; Palacio Baena, J.

    2013-12-01

    Gulf of Darién, triangular southernmost extension of the Caribbean Sea, bounded by Panama on the southwest and by Colombia on the southeast and east. The Gulf is made up of 17 municipalities in the department of Choco and Antioquia. The Gulf of Darién is a geostrategic region, rich in biodiversity, known for its natural resources of minerals, oil, lumber as well as its water and fertile land. The Darién also acts as the bridge between South America and Central America and has access to the Pacific Ocean and the Caribbean Sea. The economy in the region is based mainly on agribusinesses, tourism and mining activities, mainly the 'mining of gold and platinum-group metals'. In our study we determined the degree of trace element contamination in estuarine sediment samples originated from mining activities and municipal waste water discharges of effluents on the gulf of Darién. . Surface samples were taken from 17 locations through the entire Gulf. Grain size, Corg, Ag, Al, Ca , Cr, Cu, Fe, Mg, Mn, Na, Ni, Pb and Zn concentrations were analyzed, and enrichment factors (EF) as well as geo-accumulation indices (Igeo) were calculated. Concentrations of Pb, Zn, Ni, Cu and Cr show levels that are consistent with those typically found in urbanized marine environments. EF and Igeo values revealed that the Gulf is extremely contaminated with Ag and moderately contaminated with Cr and Zn. The sources of Cr, Ag, Hg and Zn are associated with the development of mining activities in the Atrato River basin. The observed enrichment of Ag may be explained as a residue of the extraction of gold and platinum-group metals.

  5. FLOW INJECTION ANALYSIS SYSTEM COUPLED WITH ICP-EOS FOR DETERMINATION OF SOME METALLIC ELEMENTS IN DRINKING WATER

    Directory of Open Access Journals (Sweden)

    Cristina Dinu

    2009-06-01

    Full Text Available The European Drinking Water Directive (98/83/EC, transposed in Romanian Legislation as Low 458/2002, amended by Low 311/2004, imposes the limit of concentration for metallic elements in water intended for human consumption. The toxic metals arsenic and selenium are among these elements and the limit value is 10 μg/L. In the paper there are presented the working conditions for determination of As and Se from drinking water using modern techniques based on the fl ow injection-hydride generation with the inductively coupled plasma atomic emission spectrometry (FIAS-ICP-EOS. The analyses were performed on Optima 5300 DV Perkin Elmer equipment with FIAS 400 Flow Injection System, Perkin Elmer type. For the hydride generation two types of solution were used: 10% (v/v HCl as a carrier solution and 0.2 % NaBH4 in 0.05%NaOH solution as a reducing agent [1]. The treatment step of the samples and standard solutions consisted in reducing with mixed solutions of KI and ascorbic acid in acidic condition (HCl for As and only with HCl and high temperature for Se [2,3]. The paper contains the characteristic parameters of the methods, such as: low detection limit, quantifi cation limit, repeatability, precision, recovery, which were evaluated using Certifi ed Reference Materials for each element.

  6. TOPICAL REVIEW: Nonlinear aspects of the renormalization group flows of Dyson's hierarchical model

    Science.gov (United States)

    Meurice, Y.

    2007-06-01

    We review recent results concerning the renormalization group (RG) transformation of Dyson's hierarchical model (HM). This model can be seen as an approximation of a scalar field theory on a lattice. We introduce the HM and show that its large group of symmetry simplifies drastically the blockspinning procedure. Several equivalent forms of the recursion formula are presented with unified notations. Rigourous and numerical results concerning the recursion formula are summarized. It is pointed out that the recursion formula of the HM is inequivalent to both Wilson's approximate recursion formula and Polchinski's equation in the local potential approximation (despite the very small difference with the exponents of the latter). We draw a comparison between the RG of the HM and functional RG equations in the local potential approximation. The construction of the linear and nonlinear scaling variables is discussed in an operational way. We describe the calculation of non-universal critical amplitudes in terms of the scaling variables of two fixed points. This question appears as a problem of interpolation between these fixed points. Universal amplitude ratios are calculated. We discuss the large-N limit and the complex singularities of the critical potential calculable in this limit. The interpolation between the HM and more conventional lattice models is presented as a symmetry breaking problem. We briefly introduce models with an approximate supersymmetry. One important goal of this review is to present a configuration space counterpart, suitable for lattice formulations, of functional RG equations formulated in momentum space (often called exact RG equations and abbreviated ERGE).

  7. Experimental and numerical investigation of liquid-metal free-surface flows in spallation targets

    Energy Technology Data Exchange (ETDEWEB)

    Batta, A., E-mail: batta@kit.edu [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Class, A.G.; Litfin, K.; Wetzel, Th. [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Moreau, V.; Massidda, L. [CRS4 Centre for Advanced Studies, Research and Development in Sardinia, Polaris, Edificio 1, 09010 Pula, CA (Italy); Thomas, S.; Lakehal, D. [ASCOMP GmbH Zurich, Zurich (Switzerland); Angeli, D.; Losi, G. [DIEF – Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, via Vignolese 905, 41125 Modena (Italy); Mooney, K.G. [University of Massachusetts Amherst, Department of Mechanical and Industrial Engineering, Amherst (United States); Van Tichelen, K. [SCK-CEN, Belgian Nuclear Research Centre, Boeretang 200, 2400 Mol (Belgium)

    2015-08-15

    Highlights: • Experimental study of free surface for lead bismuth eutectic target. • Numerical investigation of free surface of a liquid metal target. • Advanced free surface modelling. - Abstract: Accelerator Driven Systems (ADS) are extensively investigated for the transmutation of high-level nuclear waste within many worldwide research programs. The first advanced design of an ADS system is currently developed in SCK• CEN, Mol, Belgium: the Multi-purpose hYbrid Research Reactor for High-tech Applications (MYRRHA). Many European research programs support the design of MYRRHA. In the framework of the Euratom project ‘Thermal Hydraulics of Innovative nuclear Systems (THINS)’ a liquid-metal free-surface experiment is performed at the Karlsruhe Liquid Metal Laboratory (KALLA) of Karlsruhe Institute of Technology (KIT). The experiment investigates a full-scale model of the concentric free-surface spallation target of MYRRHA using Lead Bismuth Eutectic (LBE) as coolant. In parallel, numerical free surface models are developed and tested which are reviewed in the article. A volume-of-fluid method, a moving mesh model, a free surface model combining the Level-Set method with Large-Eddy Simulation model and a smoothed-particle hydrodynamics approach are investigated. Verification of the tested models is based on the experimental results obtained within the THINS project and on previous water experiments performed at the University Catholic de Louvain (UCL) within the Euratom project ‘EUROpean Research Programme for the TRANSmutation of High Level Nuclear Waste in Accelerator Driven System (EUROTRANS)’. The design of the target enables a high fluid velocity and a stable surface at the beam entry. The purpose of this paper is to present an overview of both experimental and numerical results obtained for free surface target characterization. Without entering in technical details, the status, the major achievements and lessons for the future with respect to

  8. Titanium recycling in the United States in 2004, chap. Y of Sibley, S.F., ed., Flow studies for recycling metal commodities in the United States

    Science.gov (United States)

    Goonan, Thomas G.

    2010-01-01

    As one of a series of reports that describe the recycling of metal commodities in the United States, this report discusses the titanium metal fraction of the titanium economy, which generates and uses titanium metal scrap in its operations. Data for 2004 were selected to demonstrate the titanium flows associated with these operations. This report includes a description of titanium metal supply and demand in the United States to illustrate the extent of titanium recycling and to identify recycling trends. In 2004, U.S. apparent consumption of titanium metal (contained in various titanium-bearing products) was 45,000 metric tons (t) of titanium, which was distributed as follows: 25,000 t of titanium recovered as new scrap, 9,000 t of titanium as titanium metal and titanium alloy products delivered to the U.S. titanium products reservoir, 7,000 t of titanium consumed by steelmaking and other industries, and 4,000 t of titanium contained in unwrought and wrought products exported. Titanium recycling is concentrated within the titanium metals sector of the total titanium market. The titanium market is otherwise dominated by pigment (titanium oxide) products, which generate dissipative losses instead of recyclable scrap. In 2004, scrap (predominantly new scrap) was the source of roughly 54 percent of the titanium metal content of U.S.-produced titanium metal products.

  9. Visualization and measurement of gas-liquid metal two-phase flow with large density difference using thermal neutrons as microscopic probes

    International Nuclear Information System (INIS)

    Saito, Y.; Hibiki, T.; Mishima, K.; Nishihara, H.; Yamamoto, A.; Kanda, K.; Tobita, Y.; Konishi, K.; Matsubayashi, M.

    1998-01-01

    In a core melt accident of a fast breeder reactor there is a possibility of boiling of fuel-steel mixture in the containment pool. In relation to safety evaluation on severe accident, it is indispensable to evaluate the recriticality of melted core. Gas-liquid two-phase flow with a large density difference is formed due to the boiling of fuel-steel mixture. Although the large density difference may affect the basic characteristics of two-phase flow, little work has been performed so far on two-phase flow with large density difference has not been performed well. In this study, visualization and void fraction measurement of gas-liquid metal two-phase flow were performed by using neutron radiography. The effect of the large density difference between gas and liquid phases on the basic flow characteristics of two-phase flow was clarified. (author)

  10. Single phase flow pressure drop and heat transfer in rectangular metallic microchannels

    International Nuclear Information System (INIS)

    Sahar, Amirah M.; Özdemir, Mehmed R.; Fayyadh, Ekhlas M.; Wissink, Jan; Mahmoud, Mohamed M.; Karayiannis, Tassos G.

    2016-01-01

    Numerical simulations were performed using Fluent 14.5 to investigate single phase flow and conjugate heat transfer in copper rectangular microchannels. Two different configurations were simulated: (1) single channel with hydraulic diameter of 0.561 mm and (2) multichannel configuration consisting of inlet and outlet manifolds and 25 channels with hydraulic diameter of 0.409 mm. In the single channel configuration, four numerical models were investigated namely, 2D thin-wall, 3D thin-wall (heated from the bottom), 3D thin-wall (three side heated) and 3D full conjugate models. In the multichannel configuration, only 3D full conjugate model was used. The simulation results of the single channel configuration were validated using experimental data of water as a test fluid while the results of the multichannel configuration were validated using experimental data of R134a refrigerant. In the multichannel configuration, flow distribution among the channels was also investigated. The 3D thin-wall model simulation was conducted at thermal boundary conditions similar to those assumed in the experimental data reduction (uniform heat flux) and showed excellent agreement with the experimental data. However, the results of the 3D full conjugate model demonstrated that there is a significant conjugate effect and the heat flux is not uniformly distributed along the channel resulting in significant deviation compared to the experimental data (more than 50%). Also, the results demonstrated that there is a significant difference between the 3D thin-wall and full conjugate models. The simulation of the multichannel configuration with an inlet manifold having gradual decrease in cross sectional area achieved very reasonable uniform flow distribution among the channels which will provide uniform heat transfer rates across the base of the microchannels.

  11. Fisher's Zeros as the Boundary of Renormalization Group Flows in Complex Coupling Spaces

    International Nuclear Information System (INIS)

    Denbleyker, A.; Du Daping; Liu Yuzhi; Meurice, Y.; Zou Haiyuan

    2010-01-01

    We propose new methods to extend the renormalization group transformation to complex coupling spaces. We argue that Fisher's zeros are located at the boundary of the complex basin of attraction of infrared fixed points. We support this picture with numerical calculations at finite volume for two-dimensional O(N) models in the large-N limit and the hierarchical Ising model. We present numerical evidence that, as the volume increases, the Fisher's zeros of four-dimensional pure gauge SU(2) lattice gauge theory with a Wilson action stabilize at a distance larger than 0.15 from the real axis in the complex β=4/g 2 plane. We discuss the implications for proofs of confinement and searches for nontrivial infrared fixed points in models beyond the standard model.

  12. Effect of gas flow on the selective area growth of gallium nitride via metal organic vapor phase epitaxy

    Science.gov (United States)

    Rodak, L. E.; Kasarla, K. R.; Korakakis, D.

    2007-08-01

    The effect of gas flow on the selective area growth (SAG) of gallium nitride (GaN) grown via metal organic vapor phase epitaxy (MOVPE) has been investigated. In this study, the SAG of GaN was carried out on a silicon dioxide striped pattern along the GaN direction. SAG was initiated with the striped pattern oriented parallel and normal to the incoming gas flow in a horizontal reactor. The orientation of the pattern did not impact cross section of the structure after re-growth as both orientations resulted in similar trapezoidal structures bounded by the (0 0 0 1) and {1 1 2¯ n} facets ( n≈1.7-2.2). However, the growth rates were shown to depend on the orientation of the pattern as the normally oriented samples exhibited enhanced vertical and cross-sectional growth rates compared to the parallel oriented samples. All growths occurred under identical conditions and therefore the difference in growth rates must be attributed to a difference in mass transport of species.

  13. Metal-Organic Frameworks as Highly Active Electrocatalysts for High-Energy Density, Aqueous Zinc-Polyiodide Redox Flow Batteries.

    Science.gov (United States)

    Li, Bin; Liu, Jian; Nie, Zimin; Wang, Wei; Reed, David; Liu, Jun; McGrail, Pete; Sprenkle, Vincent

    2016-07-13

    The new aqueous zinc-polyiodide redox flow battery (RFB) system with highly soluble active materials as well as ambipolar and bifunctional designs demonstrated significantly enhanced energy density, which shows great potential to reduce RFB cost. However, the poor kinetic reversibility and electrochemical activity of the redox reaction of I3(-)/I(-) couples on graphite felts (GFs) electrode can result in low energy efficiency. Two nanoporous metal-organic frameworks (MOFs), MIL-125-NH2 and UiO-66-CH3, that have high surface areas when introduced to GF surfaces accelerated the I3(-)/I(-) redox reaction. The flow cell with MOF-modified GFs serving as a positive electrode showed higher energy efficiency than the pristine GFs; increases of about 6.4% and 2.7% occurred at the current density of 30 mA/cm(2) for MIL-125-NH2 and UiO-66-CH3, respectively. Moreover, UiO-66-CH3 is more promising due to its excellent chemical stability in the weakly acidic electrolyte. This letter highlights a way for MOFs to be used in the field of RFBs.

  14. Heavy Metal Contamination in the Surface Layer of Bottom Sediments in a Flow-Through Lake: A Case Study of Lake Symsar in Northern Poland

    Directory of Open Access Journals (Sweden)

    Angela Kuriata-Potasznik

    2016-08-01

    Full Text Available River-lake systems most often behave as hydrographic units, which undergo complex interactions, especially in the contact zone. One such interaction pertains to the role of a river in the dispersal of trace elements carried into and out of a lake. In this study, we aimed to assess the impact of rivers on the accumulation of heavy metals in bottom sediments of natural lakes comprised in postglacial river-lake systems. The results showed that a river flowing through a lake is a key factor responsible for the input of the majority of available fraction of heavy metals (Zn, Mn, Cd and Ni into the water body and for their accumulation along the flow of river water in the lake. The origin of other accumulated elements were the linear and point sources in catchments. In turn, the Pb content was associated with the location of roads in the direct catchment, while the sediment structure (especially size of fraction and density could have affected the accumulation of Cr and Zn, which indicated correlations between these metals and fine fraction. Our results suggest that lakes act as filters and contribute to the self-purification of water that flows through them. As a result, the content of most metals in lake sediments showed a decrease by approx. 75% between the upstream (inflow and downstream (outflow sections. The increased content of two metals only, such as chromium and cadmium (higher by 2.0 and 2.5 times, respectively, after passing through the lake, was due to the correlation of the metals with fine sand. Both the content and distribution pattern of heavy metals in lake sediments are indicative of the natural response of aquatic ecosystems to environmental stressors, such as pollutant import with river water or climate change. The complex elements creating the water ecosystem of each lake can counteract stress by temporarily removing pollutants such as toxic metals form circulation and depositing them mostly around the delta.

  15. c-function and central charge of the sine-Gordon model from the non-perturbative renormalization group flow

    Directory of Open Access Journals (Sweden)

    V. Bacsó

    2015-12-01

    Full Text Available In this paper we study the c-function of the sine-Gordon model taking explicitly into account the periodicity of the interaction potential. The integration of the c-function along trajectories of the non-perturbative renormalization group flow gives access to the central charges of the model in the fixed points. The results at vanishing frequency β2, where the periodicity does not play a role, are retrieved and the independence on the cutoff regulator for small frequencies is discussed. Our findings show that the central charge obtained integrating the trajectories starting from the repulsive low-frequencies fixed points (β2<8π to the infra-red limit is in good quantitative agreement with the expected Δc=1 result. The behavior of the c-function in the other parts of the flow diagram is also discussed. Finally, we point out that including also higher harmonics in the renormalization group treatment at the level of local potential approximation is not sufficient to give reasonable results, even if the periodicity is taken into account. Rather, incorporating the wave-function renormalization (i.e. going beyond local potential approximation is crucial to get sensible results even when a single frequency is used.

  16. Mathematical Modeling of the Concentrated Energy Flow Effect on Metallic Materials

    Directory of Open Access Journals (Sweden)

    Sergey Konovalov

    2016-12-01

    Full Text Available Numerous processes take place in materials under the action of concentrated energy flows. The most important ones include heating together with the temperature misdistribution throughout the depth, probable vaporization on the surface layer, melting to a definite depth, and hydrodynamic flotation; generation of thermo-elastic waves; dissolution of heterogeneous matrix particles; and formation of nanolayers. The heat-based model is presented in an enthalpy statement involving changes in the boundary conditions, which makes it possible to consider melting and vaporization on the material surface. As a result, a linear dependence of penetration depth vs. energy density has been derived. The model of thermo-elastic wave generation is based on the system of equations on the uncoupled one-dimensional problem of dynamic thermo-elasticity for a layer with the finite thickness. This problem was solved analytically by the symbolic method. It has been revealed for the first time that the generated stress pulse comprises tension and compression zones, which are caused by increases and decreases in temperature on the boundary. The dissolution of alloying elements is modeled on the example of a titanium-carbon system in the process of electron beam action. The mathematical model is proposed to describe it, and a procedure is suggested to solve the problem of carbon distribution in titanium carbide and liquid titanium-carbide solution in terms of the state diagram and temperature changes caused by phase transitions. Carbon concentration vs. spatial values were calculated for various points of time at diverse initial temperatures of the cell. The dependence of carbon particle dissolution on initial temperature and radius of the particle were derived. A hydrodynamic model based on the evolution of Kelvin-Helmholtz instability in shear viscous flows has been proposed to specify the formation of nanostructures in materials subjected to the action of concentrated

  17. Redox‐Flow Batteries: From Metals to Organic Redox‐Active Materials

    Science.gov (United States)

    Winsberg, Jan; Hagemann, Tino; Janoschka, Tobias; Hager, Martin D.

    2016-01-01

    Abstract Research on redox‐flow batteries (RFBs) is currently experiencing a significant upturn, stimulated by the growing need to store increasing quantities of sustainably generated electrical energy. RFBs are promising candidates for the creation of smart grids, particularly when combined with photovoltaics and wind farms. To achieve the goal of “green”, safe, and cost‐efficient energy storage, research has shifted from metal‐based materials to organic active materials in recent years. This Review presents an overview of various flow‐battery systems. Relevant studies concerning their history are discussed as well as their development over the last few years from the classical inorganic, to organic/inorganic, to RFBs with organic redox‐active cathode and anode materials. Available technologies are analyzed in terms of their technical, economic, and environmental aspects; the advantages and limitations of these systems are also discussed. Further technological challenges and prospective research possibilities are highlighted. PMID:28070964

  18. Interaction of ozone with plastic and metallic materials in a dynamic flow system

    Energy Technology Data Exchange (ETDEWEB)

    Altshuller, A P; Wartburg, A F

    1961-01-01

    The loss of ozone in the p.p.h.m. range after passing through or over various plastic and metallic substances has been investigated. The materials used include Teflon, glass, stainless steel, aluminium, polyethylene and polyvinyl tubing, Mylar film, and aluminium foil. Unused Teflon passes ozone without loss. Glass tubing, after a short exposure to ozone, passes ozone without loss. Stainless steel tubing, aluminum tubing or foil and Mylar film must be exposed to ozone in the p.p.h.m. range for several hours before 90% or more of the ozone initially present can be passed through or over these materials. More rapid conditioning to ozone can be achieved by several five to fifteen-minute exposures to about 10 p.p.m. of ozone. Polyethylene and Nalgon tubing even after many hours of exposure to ozone will pass only 75 to 80% of the ozone initially present in the gas stream. Some types of polyvinyl tubing are unsatisfactory for use with ozone irrespective of the amount of exposure to ozone. Flowrates below 1000 c/sup 3//min. will increase losses of ozone. Except for Teflon and glass, materials should not be used in ozone analysis under any circumstances at low flowrates until they are thoroughly conditioned. Results obtained with stainless steel, aluminium and polyethylene indicate that conditioning to ozone once obtained will persist for at least two weeks.

  19. Molecular Basis for Electron Flow Within Metal-and Electrode-Reducing Biofilms

    Energy Technology Data Exchange (ETDEWEB)

    Bond, Daniel R. [Univ. of Minnesota, Minneapolis, MN (United States)

    2016-11-01

    Electrochemical, spectral, genetic, and biochemical techniques were developed to reveal that a diverse suite of redox proteins and structural macromolecules outside the cell work together to move electrons long distances between Geobacter cells to metals and electrodes. In this project, we greatly expanded the known participants in the electron transfer pathway of Geobacter. For example, in addition to well-studied pili, polysaccharides contribute to anchoring, different cytochromes are required under different conditions, strategies change with redox potential, and the localization of these components can change depending on where cells are located in a biofilm. By inventing new electrodes compatible with real-time spectral measurements, we were able to visualize the redox status of biofilms in action, leading to a hypothesis that long-distance electron transfer is ultimately limiting in these systems and redox potentials change within biofilms. The goals of this project were met, as we were able to 1) identify new elements crucial to the expression, assembly and function of the extracellular electron transfer phenotype 2) expand spectral and electrochemical techniques to define the mechanism and route of electron transfer through the matrix, and 3) combine this knowledge to build the next generation of genetic tools for study of this complex process.

  20. Revisiting the Cooling Flow Problem in Galaxies, Groups, and Clusters of Galaxies

    Science.gov (United States)

    McDonald, M.; Gaspari, M.; McNamara, B. R.; Tremblay, G. R.

    2018-05-01

    We present a study of 107 galaxies, groups, and clusters spanning ∼3 orders of magnitude in mass, ∼5 orders of magnitude in central galaxy star formation rate (SFR), ∼4 orders of magnitude in the classical cooling rate ({\\dot{M}}cool}\\equiv {M}gas}(rsample, we measure the ICM cooling rate, {\\dot{M}}cool}, using archival Chandra X-ray data and acquire the SFR and systematic uncertainty in the SFR by combining over 330 estimates from dozens of literature sources. With these data, we estimate the efficiency with which the ICM cools and forms stars, finding {ε }cool}\\equiv {SFR}/{\\dot{M}}cool}=1.4 % +/- 0.4% for systems with {\\dot{M}}cool}> 30 M ⊙ yr‑1. For these systems, we measure a slope in the SFR–{\\dot{M}}cool} relation greater than unity, suggesting that the systems with the strongest cool cores are also cooling more efficiently. We propose that this may be related to, on average, higher black hole accretion rates in the strongest cool cores, which could influence the total amount (saturating near the Eddington rate) and dominant mode (mechanical versus radiative) of feedback. For systems with {\\dot{M}}cool}< 30 M ⊙ yr‑1, we find that the SFR and {\\dot{M}}cool} are uncorrelated and show that this is consistent with star formation being fueled at a low (but dominant) level by recycled ISM gas in these systems. We find an intrinsic log-normal scatter in SFR at a fixed {\\dot{M}}cool} of 0.52 ± 0.06 dex (1σ rms), suggesting that cooling is tightly self-regulated over very long timescales but can vary dramatically on short timescales. There is weak evidence that this scatter may be related to the feedback mechanism, with the scatter being minimized (∼0.4 dex) for systems for which the mechanical feedback power is within a factor of two of the cooling luminosity.

  1. On the relation between the ratio of energy of vaporization to activation energy for flow and physical properties of liquid metals

    International Nuclear Information System (INIS)

    Dutt, N.V.K.; Ravikumar, Y.V.L.; Prasad, D.H.L.

    1993-01-01

    A relation between the ratio of energy of vaporization (Esub(vap) to the activation energy for flow (Esub(vis)) and the ratio of melting point (T m ) to the critical temperature (T c ) has been developed for liquid metals, and is shown to be superior to the examinations from Eyring theory. (author). 12 refs

  2. Simplified computational simulation of liquid metal behaviour in turbulent flow with heat transfer; Simulacao computacional simplificada do comportamento de metais liquidos em escoamento turbulento com transferencia de calor

    Energy Technology Data Exchange (ETDEWEB)

    Costa, E.B. da

    1992-09-01

    The present work selected the available bibliography equations and empirical relationships to the development of a computer code to obtain the turbulent velocity and temperature profiles in liquid metal tube flow with heat generation. The computer code is applied to a standard problem and the results are considered satisfactory, at least from the viewpoint of qualitative behaviour. (author). 50 refs, 21 figs, 3 tabs.

  3. Magnetohydrodynamic flow phenomena

    International Nuclear Information System (INIS)

    Gerbeth, G.; Mutschke, G.; Eckert, S.

    1995-01-01

    The MHD group of the Institute of Safety Research performs basic studies on fluid dynamics and heat/mass transfer in fluids, particularly for electrically conducting fluids (liquid metals) exposed to external magnetic fields (Magnetohydrodynamics - MHD). Such a contactless influence on transport phenomena is of principal importance for a variety of applied problems including safety and design aspects in liquid metal cooled fusion reactors, fast reactors, and chemical systems. Any electrically conducting flow can be influenced without any contact by means of an external electromagnetic field. This, of course, can change the known hydromechanically flow patterns considerably. In the following two examples of such magnetic field influence are presented. (orig.)

  4. Beyond alkyl transfer: Synthesis of main group metal (Mg, Ca, Zn) silyl and tris(oxazolinyl)borato complexes and their stoichiometric and catalytic reactions with borane Lewis acids and carbonyls

    Energy Technology Data Exchange (ETDEWEB)

    Lampland, Nicole Lynn [Iowa State Univ., Ames, IA (United States)

    2015-05-09

    Recently, the fundamental knowledge of main group metal chemistry has grown. This progress is crucial for the further development of main group metal compounds in silicon chemistry and catalysis and for advancing their applications as green alternatives to many rare earth and transition metal compounds. This thesis focuses on reactivity beyond the welldocumented alkyl-transfer applications for main group metals, and it highlights examples of reactions with Lewis acids and the reduction of carbonyls.

  5. Monitoring of cerebral blood flow autoregulation in adults undergoing sevoflurane anesthesia: a prospective cohort study of two age groups.

    Science.gov (United States)

    Goettel, Nicolai; Patet, Camille; Rossi, Ariane; Burkhart, Christoph S; Czosnyka, Marek; Strebel, Stephan P; Steiner, Luzius A

    2016-06-01

    Autoregulation of blood flow is a key feature of the human cerebral vascular system to assure adequate oxygenation and metabolism of the brain under changing physiological conditions. The impact of advanced age and anesthesia on cerebral autoregulation remains unclear. The primary objective of this study was to determine the effect of sevoflurane anesthesia on cerebral autoregulation in two different age groups. This is a follow-up analysis of data acquired in a prospective observational cohort study. One hundred thirty-three patients aged 18-40 and ≥65 years scheduled for major noncardiac surgery under general anesthesia were included. Cerebral autoregulation indices, limits, and ranges were compared in young and elderly patient groups. Forty-nine patients (37 %) aged 18-40 years and 84 patients (63 %) aged ≥65 years were included in the study. Age-adjusted minimum alveolar concentrations of sevoflurane were 0.89 ± 0.07 in young and 0.99 ± 0.14 in older subjects (P blood pressure range of 13.8 ± 9.8 mmHg in young and 10.2 ± 8.6 mmHg in older patients (P = 0.079). The lower limit of autoregulation was 66 ± 12 mmHg and 73 ± 14 mmHg in young and older patients, respectively (P = 0.075). The association between sevoflurane concentrations and autoregulatory capacity was similar in both age groups. Our data suggests that the autoregulatory plateau is shortened in both young and older patients under sevoflurane anesthesia with approximately 1 MAC. Lower and upper limits of cerebral blood flow autoregulation, as well as the autoregulatory range, are not influenced by the age of anesthetized patients. Trial registration ClinicalTrials.gov (NCT00512200).

  6. Effect of pendant group length upon metal ion complexation in acetonitrile by di-ionized calix[4]arenes bearing two dansyl fluorophores.

    Science.gov (United States)

    Ocak, Ummühan; Ocak, Miraç; Shen, Xin; Surowiec, Kazimierz; Bartsch, Richard A

    2009-11-01

    A series of three di-ionizable calix[4]arenes with two pendant dansyl (1-dimethylaminonaphthalene-5-sulfonyl) groups linked to the lower rims was synthesized. Structures of the three ligands were identical except for the length of the spacers which connected the two dansyl groups to the calix[4]arene scaffold. Following conversion of the ligands into their di-ionized di(tetramethylammonium) salts, absorption and emission spectrophotometry were utilized to probe the influence of metal cation (Li+, Na+, K+, Rb+, Cs+, Mg2+, Ca2+, Sr2+, Ba2+, Ag+, Cd2+, Co2+, Fe2+, Hg2+, Mn2+, Pb2+, Zn2+ and Fe3+) complexation in acetonitrile. Upon complexation with these metal cations, emission spectra underwent marked red shifts and quenching of the dansyl group fluorescence for the di-ionized ligand with the shortest spacer. A similar effect was noted for the di-ionized ligand with an intermediate spacer for all of the metal ions, except Ba2+. For the di-ionized ligand with the longest spacer, the metal cations showed different effects on the emission spectrum. Li+, Mg2+, Ca2+ and Ba2+ caused enhancement of emission intensity with a red shift. Other metal cations produce quenching with red shifts in the emission spectra. Transition metal cations interacted strongly with all three di-ionized ligands. In particular, Fe3+ and Hg2+ caused greater than 99% quenching of the dansyl fluorescence in the di-ionized ligands.

  7. Chaotic state to self-organized critical state transition of serrated flow dynamics during brittle-to-ductile transition in metallic glass

    Energy Technology Data Exchange (ETDEWEB)

    Wang, C.; Wang, W. H.; Bai, H. Y., E-mail: hybai@aphy.iphy.ac.cn [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Sun, B. A. [Centre for Advanced Structural Materials, Department of Mechanical and Biomedical Engineering, City University of Hong Kong, Kowloon Tong, Kowloon (Hong Kong)

    2016-02-07

    We study serrated flow dynamics during brittle-to-ductile transition induced by tuning the sample aspect ratio in a Zr-based metallic glass. The statistical analysis reveals that the serrated flow dynamics transforms from a chaotic state characterized by Gaussian-distribution serrations corresponding to stick-slip motion of randomly generated and uncorrelated single shear band and brittle behavior, into a self-organized critical state featured by intermittent scale-free distribution of shear avalanches corresponding to a collective motion of multiple shear bands and ductile behavior. The correlation found between serrated flow dynamics and plastic deformation might shed light on the plastic deformation dynamic and mechanism in metallic glasses.

  8. Investigating the synthesis of ligated metal clusters in solution using a flow reactor and electrospray ionization mass spectrometry.

    Science.gov (United States)

    Olivares, Astrid; Laskin, Julia; Johnson, Grant E

    2014-09-18

    The scalable synthesis of ligated subnanometer metal clusters containing an exact number of atoms is of interest due to the highly size-dependent catalytic, electronic, and optical properties of these species. While significant research has been conducted on the batch preparation of clusters through reduction synthesis in solution, the processes of metal complex reduction as well as cluster nucleation, growth, and postreduction etching are still not well understood. Herein, we demonstrate a prototype temperature-controlled flow reactor for qualitatively studying cluster formation in solution at steady-state conditions. Employing this technique, methanol solutions of a chloro(triphenylphosphine)gold precursor, 1,4-bis(diphenylphosphino)butane capping ligand, and borane-tert-butylamine reducing agent were combined in a mixing tee and introduced into a heated capillary with a known length. In this manner, the temperature dependence of the relative abundance of different ionic reactants, intermediates, and products synthesized in real time was characterized qualitatively using online mass spectrometry. A wide distribution of doubly and triply charged cationic gold clusters was observed as well as smaller singly charged organometallic complexes. The results demonstrate that temperature plays a crucial role in determining the relative population of cationic gold clusters and, in general, that higher temperature promotes the formation of doubly charged clusters and singly charged organometallic complexes while reducing the abundance of triply charged species. Moreover, the distribution of clusters observed at elevated temperatures is found to be consistent with that obtained at longer reaction times at room temperature, thereby demonstrating that heating may be used to access cluster distributions characteristic of different stages of batch reduction synthesis in solution.

  9. Estimates of Lagrangian particle transport by wave groups: forward transport by Stokes drift and backward transport by the return flow

    Science.gov (United States)

    van den Bremer, Ton S.; Taylor, Paul H.

    2014-11-01

    Although the literature has examined Stokes drift, the net Lagrangian transport by particles due to of surface gravity waves, in great detail, the motion of fluid particles transported by surface gravity wave groups has received considerably less attention. In practice nevertheless, the wave field on the open sea often has a group-like structure. The motion of particles is different, as particles at sufficient depth are transported backwards by the Eulerian return current that was first described by Longuet-Higgins & Stewart (1962) and forms an inseparable counterpart of Stokes drift for wave groups ensuring the (irrotational) mass balance holds. We use WKB theory to study the variation of the Lagrangian transport by the return current with depth distinguishing two-dimensional seas, three-dimensional seas, infinite depth and finite depth. We then provide dimensional estimates of the net horizontal Lagrangian transport by the Stokes drift on the one hand and the return flow on the other hand for realistic sea states in all four cases. Finally we propose a simple scaling relationship for the transition depth: the depth above which Lagrangian particles are transported forwards by the Stokes drift and below which such particles are transported backwards by the return current.

  10. ELECTRICAL RESISTANCE IMAGING OF TWO-PHASE FLOW WITH A MESH GROUPING TECHNIQUE BASED ON PARTICLE SWARM OPTIMIZATION

    Directory of Open Access Journals (Sweden)

    BO AN LEE

    2014-02-01

    Full Text Available An electrical resistance tomography (ERT technique combining the particle swarm optimization (PSO algorithm with the Gauss-Newton method is applied to the visualization of two-phase flows. In the ERT, the electrical conductivity distribution, namely the conductivity values of pixels (numerical meshes comprising the domain in the context of a numerical image reconstruction algorithm, is estimated with the known injected currents through the electrodes attached on the domain boundary and the measured potentials on those electrodes. In spite of many favorable characteristics of ERT such as no radiation, low cost, and high temporal resolution compared to other tomography techniques, one of the major drawbacks of ERT is low spatial resolution due to the inherent ill-posedness of conventional image reconstruction algorithms. In fact, the number of known data is much less than that of the unknowns (meshes. Recalling that binary mixtures like two-phase flows consist of only two substances with distinct electrical conductivities, this work adopts the PSO algorithm for mesh grouping to reduce the number of unknowns. In order to verify the enhanced performance of the proposed method, several numerical tests are performed. The comparison between the proposed algorithm and conventional Gauss-Newton method shows significant improvements in the quality of reconstructed images.

  11. Electrical Resistance Imaging of Two-Phase Flow With a Mesh Grouping Technique Based On Particle Swarm Optimization

    International Nuclear Information System (INIS)

    Lee, Bo An; Kim, Bong Seok; Ko, Min Seok; Kim, Kyung Young; Kim, Sin

    2014-01-01

    An electrical resistance tomography (ERT) technique combining the particle swarm optimization (PSO) algorithm with the Gauss-Newton method is applied to the visualization of two-phase flows. In the ERT, the electrical conductivity distribution, namely the conductivity values of pixels (numerical meshes) comprising the domain in the context of a numerical image reconstruction algorithm, is estimated with the known injected currents through the electrodes attached on the domain boundary and the measured potentials on those electrodes. In spite of many favorable characteristics of ERT such as no radiation, low cost, and high temporal resolution compared to other tomography techniques, one of the major drawbacks of ERT is low spatial resolution due to the inherent ill-posedness of conventional image reconstruction algorithms. In fact, the number of known data is much less than that of the unknowns (meshes). Recalling that binary mixtures like two-phase flows consist of only two substances with distinct electrical conductivities, this work adopts the PSO algorithm for mesh grouping to reduce the number of unknowns. In order to verify the enhanced performance of the proposed method, several numerical tests are performed. The comparison between the proposed algorithm and conventional Gauss-Newton method shows significant improvements in the quality of reconstructed images

  12. Lie Group Solution for Free Convective Flow of a Nanofluid Past a Chemically Reacting Horizontal Plate in a Porous Media

    Directory of Open Access Journals (Sweden)

    M. M. Rashidi

    2014-01-01

    Full Text Available The optimal homotopy analysis method (OHAM is employed to investigate the steady laminar incompressible free convective flow of a nanofluid past a chemically reacting upward facing horizontal plate in a porous medium taking into account heat generation/absorption and the thermal slip boundary condition. Using similarity transformations developed by Lie group analysis, the continuity, momentum, energy, and nanoparticle volume fraction equations are transformed into a set of coupled similarity equations. The OHAM solutions are obtained and verified by numerical results using a Runge-Kutta-Fehlberg fourth-fifth order method. The effect of the emerging flow controlling parameters on the dimensionless velocity, temperature, and nanoparticle volume fraction have been presented graphically and discussed. Good agreement is found between analytical and numerical results of the present paper with published results. This close agreement supports our analysis and the accuracy of the numerical computations. This paper also includes a representative set of numerical results for reduced Nusselt and Sherwood numbers in a table for various values of the parameters. It is concluded that the reduced Nusselt number increases with the Lewis number and reaction parameter whist it decreases with the order of the chemical reaction, thermal slip, and generation parameters.

  13. Electrical Resistance Imaging of Two-Phase Flow With a Mesh Grouping Technique Based On Particle Swarm Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Bo An; Kim, Bong Seok; Ko, Min Seok; Kim, Kyung Young; Kim, Sin [Jeju National Univ., Jeju (Korea, Republic of)

    2014-02-15

    An electrical resistance tomography (ERT) technique combining the particle swarm optimization (PSO) algorithm with the Gauss-Newton method is applied to the visualization of two-phase flows. In the ERT, the electrical conductivity distribution, namely the conductivity values of pixels (numerical meshes) comprising the domain in the context of a numerical image reconstruction algorithm, is estimated with the known injected currents through the electrodes attached on the domain boundary and the measured potentials on those electrodes. In spite of many favorable characteristics of ERT such as no radiation, low cost, and high temporal resolution compared to other tomography techniques, one of the major drawbacks of ERT is low spatial resolution due to the inherent ill-posedness of conventional image reconstruction algorithms. In fact, the number of known data is much less than that of the unknowns (meshes). Recalling that binary mixtures like two-phase flows consist of only two substances with distinct electrical conductivities, this work adopts the PSO algorithm for mesh grouping to reduce the number of unknowns. In order to verify the enhanced performance of the proposed method, several numerical tests are performed. The comparison between the proposed algorithm and conventional Gauss-Newton method shows significant improvements in the quality of reconstructed images.

  14. The Determinants of FDI Flows from the EU‐15 to the Visegrad Group Countries – A Panel Gravity Model Approach

    Directory of Open Access Journals (Sweden)

    Liwiusz Wojciechowski

    2013-03-01

    Full Text Available The objective of this paper is to evaluate determinants of the general FDI flow to Visegrad countries and the effect of participation in EMU and EU. It was decided to investigate how augmented Gravity Model of trade allows identifying and evaluating the significance of pull and push factors of FDI. In an empirical analysis of panel data Hausman‐Taylor estimator was used because of the time‐invariant variables presence. While investment decisions regarding the choice of country are determined by the size of the target market, the distance is still a negative factor in creation of FDI volume. Additionally, it was proven that membership in EMU, differences in taxation, historical background, access to the sea and prices stability have significant impact of FDI stock formation in each country belonging to V4. Is was also noted that Poland became a leader of the V4 as well as EU‐12 FDI market sourcing from the old EU Member States. It is necessary to develop an “FDI attracting mechanism” using existing resources. Business regulations and taxation policy as well as main macroeconomic variables which are responsible for the economy standing are also examined as attracting the FDI flow. The originality of this work lies in studying some aspects of FDI inflow into the group of both similar and different countries in economic measures terms.

  15. Renormalization group flows and fixed points for a scalar field in curved space with nonminimal F (ϕ )R coupling

    Science.gov (United States)

    Merzlikin, Boris S.; Shapiro, Ilya L.; Wipf, Andreas; Zanusso, Omar

    2017-12-01

    Using covariant methods, we construct and explore the Wetterich equation for a nonminimal coupling F (ϕ )R of a quantized scalar field to the Ricci scalar of a prescribed curved space. This includes the often considered nonminimal coupling ξ ϕ2R as a special case. We consider the truncations without and with scale- and field-dependent wave-function renormalization in dimensions between four and two. Thereby the main emphasis is on analytic and numerical solutions of the fixed point equations and the behavior in the vicinity of the corresponding fixed points. We determine the nonminimal coupling in the symmetric and spontaneously broken phases with vanishing and nonvanishing average fields, respectively. Using functional perturbative renormalization group methods, we discuss the leading universal contributions to the RG flow below the upper critical dimension d =4 .

  16. A DFT investigation on group 8B transition metal-doped silicon carbide nanotubes for hydrogen storage application

    Science.gov (United States)

    Tabtimsai, Chanukorn; Ruangpornvisuti, Vithaya; Tontapha, Sarawut; Wanno, Banchob

    2018-05-01

    The binding of group 8B transition metal (TMs) on silicon carbide nanotubes (SiCNT) hydrogenated edges and the adsorption of hydrogen molecule on the pristine and TM-doped SiCNTs were investigated using the density functional theory method. The B3LYP/LanL2DZ method was employed in all calculations for the considered structural, adsorption, and electronic properties. The Os atom doping on the SiCNT is found to be the strongest binding. The hydrogen molecule displays a weak interaction with pristine SiCNT, whereas it has a strong interaction with TM-doped SiCNTs in which the Os-doped SiCNT shows the strongest interaction with the hydrogen molecule. The improvement in the adsorption abilities of hydrogen molecule onto TM-doped SiCNTs is due to the protruding structure and the induced charge transfer between TM-doped SiCNT and hydrogen molecule. These observations point out that TM-doped SiCNTs are highly sensitive toward hydrogen molecule. Moreover, the adsorptions of 2-5 hydrogen molecules on TM-doped SiCNT were also investigated. The maximum storage number of hydrogen molecules adsorbed on the first layer of TM-doped SiCNTs is 3 hydrogen molecules. Therefore, TM-doped SiCNTs are suitable to be sensing and storage materials for hydrogen gas.

  17. First-Principles Momentum Dependent Local Ansatz Approach to the Momentum Distribution Function in Iron-Group Transition Metals

    Science.gov (United States)

    Kakehashi, Yoshiro; Chandra, Sumal

    2017-03-01

    The momentum distribution function (MDF) bands of iron-group transition metals from Sc to Cu have been investigated on the basis of the first-principles momentum dependent local ansatz wavefunction method. It is found that the MDF for d electrons show a strong momentum dependence and a large deviation from the Fermi-Dirac distribution function along high-symmetry lines of the first Brillouin zone, while the sp electrons behave as independent electrons. In particular, the deviation in bcc Fe (fcc Ni) is shown to be enhanced by the narrow eg (t2g) bands with flat dispersion in the vicinity of the Fermi level. Mass enhancement factors (MEF) calculated from the jump on the Fermi surface are also shown to be momentum dependent. Large mass enhancements of Mn and Fe are found to be caused by spin fluctuations due to d electrons, while that for Ni is mainly caused by charge fluctuations. Calculated MEF are consistent with electronic specific heat data as well as recent angle resolved photoemission spectroscopy data.

  18. A clinical study to compare between resting and stimulated whole salivary flow rate and pH before and after complete denture placement in different age groups

    Directory of Open Access Journals (Sweden)

    B C Muddugangadhar

    2015-01-01

    Conclusion: Stimulated whole salivary flow rates and pH were significantly higher than resting (unstimulated whole salivary flow rates and pH obtained before, immediately after, and after 2 to 3 months of complete denture placement. No age related variations in whole salivary flow rate and pH were observed in healthy, non-medicated individuals. Clinical Implications: The assessment of salivary flow rate, pH in different age groups is of prognostic value, which is an important aspect to be considered in the practice of removable prosthodontics.

  19. Metallic and antiferromagnetic fixed points from gravity

    Science.gov (United States)

    Paul, Chandrima

    2018-06-01

    We consider SU(2) × U(1) gauge theory coupled to matter field in adjoints and study RG group flow. We constructed Callan-Symanzik equation and subsequent β functions and study the fixed points. We find there are two fixed points, showing metallic and antiferromagnetic behavior. We have shown that metallic phase develops an instability if certain parametric conditions are satisfied.

  20. Role of riverine colloids in macronutrient and metal partitioning and transport, along an upland–lowland land-use continuum, under low-flow conditions

    International Nuclear Information System (INIS)

    Jarvie, H.P.; Neal, C.; Rowland, A.P.; Neal, M.; Morris, P.N.; Lead, J.R.; Lawlor, A.J.; Woods, C.; Vincent, C.; Guyatt, H.; Hockenhull, K.

    2012-01-01

    An assessment is made of the role of riverine colloids in macronutrient (nitrogen, phosphorus and carbon), metal and trace element partitioning and transport, for five rivers in the Ribble and Wyre catchments in north-western England, under baseflow/near-baseflow conditions. Cross-flow ultrafiltration was used to separate colloidal ( 1 kDa) and truly dissolved ( 0.45 μm, suspended) fractions. Of these operationally-defined fractions measured, colloids were generally more important for both macronutrient and metal transport in the upland than in the lowland rivers. The results suggest that organic moieties in truly dissolved form from sewage effluent may have a greater capacity to chelate metals. Organic-rich colloids in the upland moorlands and metal oxide colloidal precipitates in the industrial rivers had a higher capacity for binding metals than the colloidal fractions in the urban and agricultural lowland rivers. Aggregation of these colloids may provide an important mechanism for formation of larger suspended particulates, accounting for a higher degree of metal enrichment in the acid-available particulate fractions of the upland moorland and lowland industrial rivers, than in the lowland agricultural and urban rivers. This mechanism of transfer of contaminants to larger aggregates via colloidal intermediates, known as ‘colloidal pumping’ may also provide a mechanism for particulate P formation and the high proportion of P being transported in the particulate fraction in the uplands. The cross-flow ultrafiltration data also allowed refinement of partition coefficients, by accounting for colloids within the solids phase and replacing the filtered (< 0.45 μm) fraction with the truly dissolved (< 1 kDa) concentrations. These provided a clearer description of the controls on metal and P partitioning along the upland-lowland continuum. -- Highlights: ► Using cross-flow ultrafiltration, we assess the role of colloids in macronutrient and metal partitioning

  1. Probing Interaction Between Platinum Group Metal (PGM) and Non-PGM Support Through Surface Characterization and Device Performance

    Science.gov (United States)

    Saha, Shibely

    High cost and limited abundance of Platinum (Pt) have hindered effective commercialization of Proton Exchange Membrane Fuel Cell and Electrolyzer. Efforts have been undertaken to reduce precious group metal (PGM) requirement for these devices without compromising the activity of the catalyst by using transition metal carbides (TMC) as non-PGM support thanks to their similar electronic and geometric structures as Pt. In this work Mo2C was selected as non-PGM support and Pt was used as the PGM of interest. We hypothesize that the hollow nanotube morphology of Mo2C support combined with Pt nano particles deposited on it via atomic layer deposition (ALD) technique would allow increased interaction between them which may increase the activity of Pt and Mo2C as well as maximize the Pt active surface area. Specifically, a rotary ALD equipment was used to grow Pt particles from atomic level to 2--3 nanometers by simply adjusting number of ALD cycles in order to probe the interaction between the deposited Pt nanoparticles and Mo2C nanotube support. Interaction between the Pt and Mo2 C was analyzed via surface characterization and electrochemical characterization. Interaction between Pt and Mo2C arises due to the lattice mismatch between Pt and Mo2C as well as electron migration between them. Lattice spacing analysis using high resolution transmission electron microscopy (HRTEM) images, combined with Pt binding energy shift in XPS results, clearly showed strong bonding between Pt nanoparticles and the Mo2C nanotube support in all the resultant Pt/Mo2C samples. We postulate that this strong interaction is responsible for the significantly enhanced durability observed in our constant potential electrolysis (CPE) and accelerated degradation testing (ADT). Of the three samples from different ALD cycles (15, 50 and 100), Mo2C nanotubes modified by 50 (1.07 wt% Pt loading) and 100 cycles (4.4 wt% Pt) of Pt deposition, showed higher HER and HOR activity per Pt mass than commercial

  2. Imbalance of the liquid-metal flow and heat extraction in a manifold with sub-channels having locally different eletric conductivity

    International Nuclear Information System (INIS)

    Luo, Yang; Wen, Meimei; Kim, Chang Nyung; Yang, Shangjing

    2017-01-01

    In this study, the characteristics of liquid metal (LM) magnetohydrodynamic (MHD) flow and convective heat transfer in a manifold with three sub-channels having locally different electric conductivity are investigated with the use of commercial code CFX, allowing an imbalance in flow rate among the sub-channels, which can be used for intensive cooling of the region with higher heat load in the blanket. In a manifold with co-flow multiple sub-channels, the electrical current can cross the fluid regions and channel walls, thus influencing the flow distribution in each sub-channel. In the present study, cases with various arrangements of the electric conductivity in different parts of the channel walls are investigated, yielding different distributions of the current and fluid flow in different cases. Here, the mechanism governing the imbalance in mass flow rate among the sub-channels is discussed. The interdependency of the fluid velocity, current and electric potential of LM MHD flows in the three sub-channels are analyzed in detail. The results show that, in the sub-channel surrounded by the walls with lower electric conductivity, higher axial velocity and superior heat extraction can be obtained, with an effective cooling associated with higher velocity, where the higher velocity is closely related to the distribution of the electromotive component of the current in the flow field.

  3. Imbalance of the liquid-metal flow and heat extraction in a manifold with sub-channels having locally different eletric conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Yang; Wen, Meimei [Department of Mechanical Engineering, Graduate School, Kyung Hee University, Yong-in, Kyunggi-do, 446-701 (Korea, Republic of); Kim, Chang Nyung, E-mail: cnkim@khu.ac.kr [Department of Mechanical Engineering, College of Engineering, Kyung Hee University, Yong-in, Kyunggi-do, 446-701 (Korea, Republic of); Yang, Shangjing [Department of Mechanical Engineering, Graduate School, Kyung Hee University, Yong-in, Kyunggi-do, 446-701 (Korea, Republic of)

    2017-04-15

    In this study, the characteristics of liquid metal (LM) magnetohydrodynamic (MHD) flow and convective heat transfer in a manifold with three sub-channels having locally different electric conductivity are investigated with the use of commercial code CFX, allowing an imbalance in flow rate among the sub-channels, which can be used for intensive cooling of the region with higher heat load in the blanket. In a manifold with co-flow multiple sub-channels, the electrical current can cross the fluid regions and channel walls, thus influencing the flow distribution in each sub-channel. In the present study, cases with various arrangements of the electric conductivity in different parts of the channel walls are investigated, yielding different distributions of the current and fluid flow in different cases. Here, the mechanism governing the imbalance in mass flow rate among the sub-channels is discussed. The interdependency of the fluid velocity, current and electric potential of LM MHD flows in the three sub-channels are analyzed in detail. The results show that, in the sub-channel surrounded by the walls with lower electric conductivity, higher axial velocity and superior heat extraction can be obtained, with an effective cooling associated with higher velocity, where the higher velocity is closely related to the distribution of the electromotive component of the current in the flow field.

  4. Separation of Acetylene from Carbon Dioxide and Ethylene by a Water-Stable Microporous Metal-Organic Framework with Aligned Imidazolium Groups inside the Channels.

    Science.gov (United States)

    Lee, Jaechul; Chuah, Chong Yang; Kim, Jaheon; Kim, Youngsuk; Ko, Nakeun; Seo, Younggyu; Kim, Kimoon; Bae, Tae Hyun; Lee, Eunsung

    2018-04-24

    Separation of acetylene from carbon dioxide and ethylene is challenging in view of their similar sizes and physical properties. Metal-organic frameworks (MOFs) in general are strong candidates for these separations owing to the presence of functional pore surfaces that can selectively capture a specific target molecule. Here, we report a novel 3D microporous cationic framework named JCM-1. This structure possesses imidazolium functional groups on the pore surfaces and pyrazolate as a metal binding group, which is well known to form strong metal-to-ligand bonds. The selective sorption of acetylene over carbon dioxide and ethylene in JCM-1 was successfully demonstrated by equilibrium gas adsorption analysis as well as dynamic breakthrough measurement. Furthermore, its excellent hydrolytic stability makes the separation processes highly recyclable without a substantial loss in acetylene uptake capacity. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. The Bolivar Channel Ecosystem of the Galapagos Marine Reserve: Energy flow structure and role of keystone groups

    Science.gov (United States)

    Ruiz, Diego J.; Wolff, Matthias

    2011-08-01

    Oscillation. Most important keystone groups of large relative impact over other system compartments are sharks and marine mammals. In addition, the important role of macro-algae, sea stars and urchins, phytoplankton and barracudas should be emphasized for their great contribution to the trophic flows and biomass of the system.

  6. Elemental analyses of goundwater: demonstrated advantage of low-flow sampling and trace-metal clean techniques over standard techniques

    Science.gov (United States)

    Creasey, C. L.; Flegal, A. R.

    The combined use of both (1) low-flow purging and sampling and (2) trace-metal clean techniques provides more representative measurements of trace-element concentrations in groundwater than results derived with standard techniques. The use of low-flow purging and sampling provides relatively undisturbed groundwater samples that are more representative of in situ conditions, and the use of trace-element clean techniques limits the inadvertent introduction of contaminants during sampling, storage, and analysis. When these techniques are applied, resultant trace-element concentrations are likely to be markedly lower than results based on standard sampling techniques. In a comparison of data derived from contaminated and control groundwater wells at a site in California, USA, trace-element concentrations from this study were 2-1000 times lower than those determined by the conventional techniques used in sampling of the same wells prior to (5months) and subsequent to (1month) the collections for this study. Specifically, the cadmium and chromium concentrations derived using standard sampling techniques exceed the California Maximum Contaminant Levels (MCL), whereas in this investigation concentrations of both of those elements are substantially below their MCLs. Consequently, the combined use of low-flow and trace-metal clean techniques may preclude erroneous reports of trace-element contamination in groundwater. Résumé L'utilisation simultanée de la purge et de l'échantillonnage à faible débit et des techniques sans traces de métaux permet d'obtenir des mesures de concentrations en éléments en traces dans les eaux souterraines plus représentatives que les résultats fournis par les techniques classiques. L'utilisation de la purge et de l'échantillonnage à faible débit donne des échantillons d'eau souterraine relativement peu perturbés qui sont plus représentatifs des conditions in situ, et le recours aux techniques sans éléments en traces limite l

  7. Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

    KAUST Repository

    Wang, Xiufang

    2017-01-01

    A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

  8. Tunable electronic and magnetic properties in germanene by alkali, alkaline-earth, group III and 3d transition metal atom adsorption.

    Science.gov (United States)

    Li, Sheng-shi; Zhang, Chang-wen; Ji, Wei-xiao; Li, Feng; Wang, Pei-ji; Hu, Shu-jun; Yan, Shi-shen; Liu, Yu-shen

    2014-08-14

    We performed first-principles calculations to study the adsorption characteristics of alkali, alkali-earth, group III, and 3d transition-metal (TM) adatoms on germanene. We find that the adsorption of alkali or alkali-earth adatoms on germanene has minimal effects on geometry of germanene. The significant charge transfer from alkali adatoms to germanene leads to metallization of germanene, whereas alkali-earth adatom adsorption, whose interaction is a mixture of ionic and covalent, results in semiconducting behavior with an energy gap of 17-29 meV. For group III adatoms, they also bind germanene with mixed covalent and ionic bonding character. Adsorption characteristics of the transition metals (TMs) are rather complicated, though all TM adsorptions on germanene exhibit strong covalent bonding with germanene. The main contributions to the strong bonding are from the hybridization between the TM 3d and Ge pz orbitals. Depending on the induced-TM type, the adsorbed systems can exhibit metallic, half-metallic, or semiconducting behavior. Also, the variation trends of the dipole moment and work function with the adsorption energy across the different adatoms are discussed. These findings may provide a potential avenue to design new germanene-based devices in nanoelectronics.

  9. Discharge on boiling in a channel: effect of channel geometry on the performance characteristics of determining metals in a liquid flow by atomic emission spectrometry

    International Nuclear Information System (INIS)

    Zuev, B.K.; Yagov, V.V.; Grachev, A.S.

    2006-01-01

    Discharge on boiling in a channel was studied as a new atomization and excitation source for spectrochemical analysis in a flow of electrolyte solutions. The discharge arises between the liquid walls of a vapor lock formed in the channel of a dielectric membrane because of the rapid Joule heating of the liquid in the channel. The effect of channel geometry on the reproducibility of the integrated light intensity was studied. The background radiation spectrum was measured over the range 220-900 nm, and the possibility of determining alkali and alkaline earth metals in a flow was studied. The parameters of linear calibration equations and the detection limits for these metals are given [ru

  10. Two parameters Lie group analysis and numerical solution of unsteady free convective flow of non-Newtonian fluid

    Directory of Open Access Journals (Sweden)

    M.J. Uddin

    2016-09-01

    Full Text Available The two-dimensional unsteady laminar free convective heat and mass transfer fluid flow of a non-Newtonian fluid adjacent to a vertical plate has been analyzed numerically. The two parameters Lie group transformation method that transforms the three independent variables into a single variable is used to transform the continuity, the momentum, the energy and the concentration equations into a set of coupled similarity equations. The transformed equations have been solved by the Runge–Kutta–Fehlberg fourth-fifth order numerical method with shooting technique. Numerical calculations were carried out for the various parameters entering into the problem. The dimensionless velocity, temperature and concentration profiles were shown graphically and the skin friction, heat and mass transfer rates were given in tables. It is found that friction factor and heat transfer (mass transfer rate for methanol are higher (lower than those of hydrogen and water vapor. Friction factor decreases while heat and mass transfer rate increase as the Prandtl number increases. Friction (heat and mass transfer rate factor of Newtonian fluid is higher (lower than the dilatant fluid.

  11. Paleomagnetic correlation of surface and subsurface basaltic lava flows and flow groups in the southern part of the Idaho National Laboratory, Idaho, with paleomagnetic data tables for drill cores

    Science.gov (United States)

    Champion, Duane E.; Hodges, Mary K.V.; Davis, Linda C.; Lanphere, Marvin A.

    2011-01-01

    Paleomagnetic inclination and polarity studies have been conducted on thousands of subcore samples from 51 coreholes located at and near the Idaho National Laboratory. These studies are used to paleomagnetically characterize and correlate successive stratigraphic intervals in each corehole to similar depth intervals in adjacent coreholes. Paleomagnetic results from 83 surface paleomagnetic sites, within and near the INL, are used to correlate these buried lava flow groups to basaltic shield volcanoes still exposed on the surface of the eastern Snake River Plain. Sample handling and demagnetization protocols are described as well as the paleomagnetic data averaging process. Paleomagnetic inclination comparisons between coreholes located only kilometers apart show comparable stratigraphic successions of mean inclination values over tens of meters of depth. At greater distance between coreholes, comparable correlation of mean inclination values is less consistent because flow groups may be missing or additional flow groups may be present and found at different depth intervals. Two shallow intersecting cross-sections, A-A- and B-B- (oriented southwest-northeast and northwest-southeast, respectively), drawn through southwest Idaho National Laboratory coreholes show the corehole to corehole or surface to corehole correlations derived from the paleomagnetic inclination data. From stratigraphic top to bottom, key results included the (1) Quaking Aspen Butte flow group, which erupted from Quaking Aspen Butte southwest of the Idaho National Laboratory, flowed northeast, and has been found in the subsurface in corehole USGS 132; (2) Vent 5206 flow group, which erupted near the southwestern border of the Idaho National Laboratory, flowed north and east, and has been found in the subsurface in coreholes USGS 132, USGS 129, USGS 131, USGS 127, USGS 130, USGS 128, and STF-AQ-01; and (3) Mid Butte flow group, which erupted north of U.S. Highway 20, flowed northwest, and has been

  12. Cellulose bearing Schiff base and carboxylic acid chelating groups: a low cost and green adsorbent for heavy metal ion removal from aqueous solution.

    Science.gov (United States)

    Saravanan, R; Ravikumar, L

    2016-10-01

    Chemically modified cellulose bearing metal binding sites like Schiff base and carboxylic acid groups was synthesized and characterized through Fourier transform infrared and solid state 13 C-nuclear magnetic resonance (NMR) analysis. The chemically modified cellulose (Cell-PA) adsorbent was examined for its metal ion uptake ability for Cu(II) and Pb(II) ions from aqueous solution. Kinetic and isotherm studies were carried out under optimum conditions. Pseudo-second-order kinetics and Langmuir isotherm fit well with the experimental data. Thermodynamic studies were also performed along with adsorption regeneration performance studies. The adsorbent (Cell-PA) shows high potential for the removal of Cu(II) and Pb(II) metal ions, and it shows antibacterial activity towards selected microorganisms.

  13. Comparison of adaptability to heavy metals among crop plants (part 2). Adaptability to zinc group metals-studies on the comparative plant nutrition

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, A; Tadano, T; Muto, K

    1975-01-01

    Eighteen crop species were grown in culture solution having graded levels of Zn, Cd and Hg, and the differences among species in response to these elements were discussed. As the average of all species tested, the metal content of the shoot is Ca > Mn > Zn > Cd > Hg, and the root-to-shoot content ratio is reversed at equivalent levels. These values increase with an increase in the level of respective ions in the culture solution. The metal concentration in the shoot among species does not change significantly with the level of that element. There is a positive correlation among species between Zn and Cd, but Hg shows a different trend. The tolerance to Zn is weak in many species of Gramineae and Curciferae, and strong Solanaceae and Umbelliferae. Many species of Gramineae are very tolerant to high levels of Zn or Cd due to a high excluding power of the roots, but possess a weak tolerance to high Hg levels. Egg-plant, soybean, and pea are susceptible to high levels of all three elements.

  14. Visualization and measurement of gas-liquid metal two-phase flow with large density difference using thermal neutrons as microscopic probes

    International Nuclear Information System (INIS)

    Mishima, K.; Hibiki, T.; Saito, Y.; Nishihara, H.; Tobita, Y.; Konishi, K.; Matsubayashi, M.

    1999-01-01

    In a core melt accident of a fast breeder reactor, there is a possibility of boiling of the fuel-steel mixture in the containment pool. In relation to safety evaluation on severe accident, it is indispensable to evaluate the possibility of re-criticality of melted core. Gas-liquid two-phase flow with a large liquid-to-gas density ratio is formed due to the boiling of fuel-steel mixture. Although it is anticipated that the large density ratio may affect the basic characteristics of two-phase flow, little work has been performed so far on two-phase flow with a large liquid-to-gas density ratio. In this study, visualization and void fraction measurement of gas-liquid metal two-phase flow were performed by using neutron radiography and image processing techniques. Then, the effect of large density difference between gas and liquid phases on the basic flow characteristics of two-phase flow was clarified

  15. A clinical study to compare between resting and stimulated whole salivary flow rate and pH before and after complete denture placement in different age groups.

    Science.gov (United States)

    Muddugangadhar, B C; Sangur, Rajashekar; Rudraprasad, I V; Nandeeshwar, D B; Kumar, B H Dhanya

    2015-01-01

    This study compared the flow rate and pH of resting (unstimulated) and stimulated whole saliva before and after complete denture placement in different age groups. Fifty healthy, non-medicated edentulous individuals of different age groups requiring complete denture prostheses were selected from the outpatient department. The resting (unstimulated) and stimulated whole saliva and pH were measured at three stages i.e., i)Before complete denture placement;ii)Immediately after complete denture placement; andiii)After 2 to 3 months of complete denture placement. Saliva production was stimulated by chewing paraffin wax. pH was determined by using a digital pH meter. Statistically significant differences were seen in resting(unstimulated) and stimulated whole salivary flow rate and pH obtained before, immediately after, and after 2 to 3 months of complete denture placement. No statistically significant differences were found between the different age groups in resting (unstimulated) as well as stimulated whole salivary flow rate and pH. Stimulated whole salivary flow rates and pH were significantly higher than resting (unstimulated) whole salivary flow rates and pH obtained before, immediately after, and after 2 to 3 months of complete denture placement. No age related variations in whole salivary flow rate and pH were observed in healthy, non-medicated individuals. The assessment of salivary flow rate, pH in different age groups is of prognostic value, which is an important aspect to be considered in the practice of removable prosthodontics.

  16. A clinical study to compare between resting and stimulated whole salivary flow rate and pH before and after complete denture placement in different age groups

    Science.gov (United States)

    Muddugangadhar, B. C.; Sangur, Rajashekar; Rudraprasad, I. V.; Nandeeshwar, D. B.; Kumar, B. H. Dhanya

    2015-01-01

    Purpose: This study compared the flow rate and pH of resting (unstimulated) and stimulated whole saliva before and after complete denture placement in different age groups. Materials and Methods: Fifty healthy, non-medicated edentulous individuals of different age groups requiring complete denture prostheses were selected from the outpatient department. The resting (unstimulated) and stimulated whole saliva and pH were measured at three stages i.e., i)Before complete denture placement;ii)Immediately after complete denture placement; andiii)After 2 to 3 months of complete denture placement. Saliva production was stimulated by chewing paraffin wax. pH was determined by using a digital pH meter. Results: Statistically significant differences were seen in resting(unstimulated) and stimulated whole salivary flow rate and pH obtained before, immediately after, and after 2 to 3 months of complete denture placement. No statistically significant differences were found between the different age groups in resting (unstimulated) as well as stimulated whole salivary flow rate and pH. Conclusion: Stimulated whole salivary flow rates and pH were significantly higher than resting (unstimulated) whole salivary flow rates and pH obtained before, immediately after, and after 2 to 3 months of complete denture placement. No age related variations in whole salivary flow rate and pH were observed in healthy, non-medicated individuals. Clinical Implications: The assessment of salivary flow rate, pH in different age groups is of prognostic value, which is an important aspect to be considered in the practice of removable prosthodontics. PMID:26929540

  17. Role of riverine colloids in macronutrient and metal partitioning and transport, along an upland-lowland land-use continuum, under low-flow conditions

    Energy Technology Data Exchange (ETDEWEB)

    Jarvie, H.P., E-mail: hpj@ceh.ac.uk [Centre for Ecology and Hydrology, Maclean Building, Crowmarsh Gifford, Wallingford, OX10 8BB (United Kingdom); Neal, C. [Centre for Ecology and Hydrology, Maclean Building, Crowmarsh Gifford, Wallingford, OX10 8BB (United Kingdom); Rowland, A.P. [Centre for Ecology and Hydrology, Lancaster, Lancaster Environment Centre, Library Avenue, Bailrigg, Lancaster LA1 4AP (United Kingdom); Neal, M.; Morris, P.N. [Centre for Ecology and Hydrology, Maclean Building, Crowmarsh Gifford, Wallingford, OX10 8BB (United Kingdom); Lead, J.R. [School of Geography, Earth and Environmental Science, University of Birmingham, Edgbaston, Birmingham, B15 2TT (United Kingdom); Lawlor, A.J.; Woods, C.; Vincent, C.; Guyatt, H.; Hockenhull, K. [Centre for Ecology and Hydrology, Lancaster, Lancaster Environment Centre, Library Avenue, Bailrigg, Lancaster LA1 4AP (United Kingdom)

    2012-09-15

    An assessment is made of the role of riverine colloids in macronutrient (nitrogen, phosphorus and carbon), metal and trace element partitioning and transport, for five rivers in the Ribble and Wyre catchments in north-western England, under baseflow/near-baseflow conditions. Cross-flow ultrafiltration was used to separate colloidal (< 0.45 Micro-Sign m > 1 kDa) and truly dissolved (< 1 kDa) fractions from river water. Clear patterns were observed, along the upland-lowland land use continuum, in the partitioning and transport of macronutrients and metals between the colloidal, truly dissolved and acid-available particulate (> 0.45 {mu}m, suspended) fractions. Of these operationally-defined fractions measured, colloids were generally more important for both macronutrient and metal transport in the upland than in the lowland rivers. The results suggest that organic moieties in truly dissolved form from sewage effluent may have a greater capacity to chelate metals. Organic-rich colloids in the upland moorlands and metal oxide colloidal precipitates in the industrial rivers had a higher capacity for binding metals than the colloidal fractions in the urban and agricultural lowland rivers. Aggregation of these colloids may provide an important mechanism for formation of larger suspended particulates, accounting for a higher degree of metal enrichment in the acid-available particulate fractions of the upland moorland and lowland industrial rivers, than in the lowland agricultural and urban rivers. This mechanism of transfer of contaminants to larger aggregates via colloidal intermediates, known as 'colloidal pumping' may also provide a mechanism for particulate P formation and the high proportion of P being transported in the particulate fraction in the uplands. The cross-flow ultrafiltration data also allowed refinement of partition coefficients, by accounting for colloids within the solids phase and replacing the filtered (< 0.45 {mu}m) fraction with the truly

  18. Effect of coexistent hydrogen isotopes on tracer diffusion of tritium in alpha phase of group-V metal-hydrogen systems

    International Nuclear Information System (INIS)

    Sakamoto, Kan; Hashizume, Kenichi; Sugisaki, Masayasu

    2009-01-01

    Tracer diffusion coefficients of tritium in the alpha phase of group-V metal-hydrogen systems, α-MH(D)xTy (M=V and Ta; x>>y), were measured in order to clarify the effects of coexistent hydrogen isotopes on the tritium diffusion behavior. The hydrogen concentration dependence of such behavior and the effects of the coexistent hydrogen isotopes (protium and deuterium) were determined. The results obtained in the present (for V and Ta) and previous (for Nb) studies revealed that tritium diffusion was definitely dependent on hydrogen concentration but was not so sensitive to the kind of coexistent hydrogen isotopes. By summarizing those data, it was found that the hydrogen concentration dependence of the tracer diffusion coefficient of tritium in the alpha phase of group-V metals could be roughly expressed by a single empirical curve. (author)

  19. Saliva composition in three selected groups with normal stimulated salivary flow rates, but yet major differences in caries experience and dental erosion.

    Science.gov (United States)

    Bardow, Allan; Lykkeaa, Joan; Qvist, Vibeke; Ekstrand, Kim; Twetman, Svante; Fiehn, Niels-Erik

    2014-08-01

    It was hypothesized that, by comparing matched subjects with major differences in these dental diseases, but yet normal saliva flow rates, it would be possible to obtain data on the effect of saliva composition on dental disease isolated from the effect of the flow rate. Thus, the aim of the study was to compare the major physicochemical characteristics of stimulated whole saliva in three groups of 85 subjects, each with normal saliva flow rates and at least 24 remaining teeth. A group with very little dental disease (healthy), a group with dental erosion (erosion) and a group with very high caries experience (caries) were chosen. Furthermore, the aim was to determine whether differences among groups could also be found on an individual level. Although it was not possible to retrieve three groups whose members were completely identical, the present study points in the direction that, on a group level, subjects with very little dental disease seemed to have a more favorable physicochemical saliva composition with respect to higher calcium, phosphate, bicarbonate, pH, degree of saturation with respect to hydroxyapatite and a lower critical pH (p dental erosion (p dental caries and erosion in single individuals.

  20. The treatment of water-conducting features in groundwater flow and transport modelling of the Borrowdale Volcanic Group in Nirex 97

    International Nuclear Information System (INIS)

    Jackson, C.P.; Norris, S.; Todman, S.J.; Watson, S.P.

    1999-01-01

    In the Nirex 97 assessment of the post-closure performance of a repository at Sellafield, the potential repository host rock was the Borrowdale Volcanic Group (BVG). The treatment of water-conducting features in groundwater flow and transport modelling of the BVG is discussed. Groundwater flow in the BVG is predominantly through a subset of the total set of discontinuities - the Flowing Features (FFs). FFs can be identified in core samples by the presence of recent calcite. In boreholes, the FFs are clustered, and the clustering appears to be significant hydro-geologically. However, there is uncertainty about the connectivity of the clusters. A range of models is possible, from the case of isolated clusters to the case where the clusters form a well-connected network. The radiological risk from the repository was determined from radionuclide transport calculations based on the groundwater flow fields obtained from the regional-scale flow calculations. For rocks, such as the BVG, in which groundwater flows predominantly through discontinuities, diffusion into immobile water int the rock matrix between the discontinuities was modelled. Data from the site characterization and research programmes could be used to develop and parameterize groundwater flow and transport models for use in repository performance assessments. (author)

  1. Convective heat transfer the molten metal pool heated from below and cooled by two-phase flow

    International Nuclear Information System (INIS)

    Cho, J. S.; Suh, K. Y.; Chung, C. H.; Park, R. J.; Kim, S. B.

    1998-01-01

    During a hypothetical servere accident in the nuclear power plant, a molten core material may form stratified fluid layers. These layers may be composed of high temperature molten debris pool and water coolant in the lower plenum of the reactor vessel or in the reactor cavity. This study is concerned with the experimental test and numerical analysis on the heat transfer and solidification of the molten metal pool with overlying coolant with boiling. This work examines the crust formation and the heat transfer characteristics of the molten metal pool immersed in the boiling coolant. The metal pool is heated from the bottom surface and coolant is injected onto the molten metal pool. The simulant molten pool material is tin (Sn) with the melting temperature of 232 .deg. C. Demineralized water is used as the working coolant. Tests were performed under the condition of the bottom surface heating in the test section and the forced convection of the coolant being injected onto the molten metal pool. The constant temperature and constant heat flux conditions are adopted for the bottom heating. The test parameters included the heated bottom surface temperature of the molten metal pool, the input power to the heated bottom surface of the test section, and the coolant injection rate. Numerical analyses were simultaneously performed in a two-dimensional rectangular domain of the molten metal pool to check on the measured data. The numerical program has been developed using the enthalpy method, the finite volume method and the SIMPLER algorithm. The experimental results of the heat transfer show general agreement with the calculated values. In this study, the relationship between the Nusselt number and Rayleigh number in the molten metal pool region was estimated and compared with the dry experiment without coolant nor solidification of the molten metal pool, and with the crust formation experiment with subcooled coolant, and against other correlations. In the experiments, the

  2. A Modified Eyring Equation for Modeling Yield and Flow Stresses of Metals at Strain Rates Ranging from 10−5 to 5 × 104 s−1

    Directory of Open Access Journals (Sweden)

    Ramzi Othman

    2015-01-01

    Full Text Available In several industrial applications, metallic structures are facing impact loads. Therefore, there is an important need for developing constitutive equations which take into account the strain rate sensitivity of their mechanical properties. The Johnson-Cook equation was widely used to model the strain rate sensitivity of metals. However, it implies that the yield and flow stresses are linearly increasing in terms of the logarithm of strain rate. This is only true up to a threshold strain rate. In this work, a three-constant constitutive equation, assuming an apparent activation volume which decreases as the strain rate increases, is applied here for some metals. It is shown that this equation fits well the experimental yield and flow stresses for a very wide range of strain rates, including quasi-static, high, and very high strain rates (from 10−5 to 5 × 104 s−1. This is the first time that a constitutive equation is showed to be able to fit the yield stress over a so large strain rate range while using only three material constants.

  3. Underwater tracking of a moving dipole source using an artificial lateral line: algorithm and experimental validation with ionic polymer–metal composite flow sensors

    International Nuclear Information System (INIS)

    Abdulsadda, Ahmad T; Tan, Xiaobo

    2013-01-01

    Motivated by the lateral line system of fish, arrays of flow sensors have been proposed as a new sensing modality for underwater robots. Existing studies on such artificial lateral lines (ALLs) have been mostly focused on the localization of a fixed underwater vibrating sphere (dipole source). In this paper we examine the problem of tracking a moving dipole source using an ALL system. Based on an analytical model for the moving dipole-generated flow field, we formulate a nonlinear estimation problem that aims to minimize the error between the measured and model-predicted magnitudes of flow velocities at the sensor sites, which is subsequently solved with the Gauss–Newton scheme. A sliding discrete Fourier transform (SDFT) algorithm is proposed to efficiently compute the evolving signal magnitudes based on the flow velocity measurements. Simulation indicates that it is adequate and more computationally efficient to use only the signal magnitudes corresponding to the dipole vibration frequency. Finally, experiments conducted with an artificial lateral line consisting of six ionic polymer–metal composite (IPMC) flow sensors demonstrate that the proposed scheme is able to simultaneously locate the moving dipole and estimate its vibration amplitude and traveling speed with small errors. (paper)

  4. Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy.

    Science.gov (United States)

    Zheng, Jie; Sheng, Wenchao; Zhuang, Zhongbin; Xu, Bingjun; Yan, Yushan

    2016-03-01

    Understanding how pH affects the activity of hydrogen oxidation reaction (HOR) and hydrogen evolution reaction (HER) is key to developing active, stable, and affordable HOR/HER catalysts for hydroxide exchange membrane fuel cells and electrolyzers. A common linear correlation between hydrogen binding energy (HBE) and pH is observed for four supported platinum-group metal catalysts (Pt/C, Ir/C, Pd/C, and Rh/C) over a broad pH range (0 to 13), suggesting that the pH dependence of HBE is metal-independent. A universal correlation between exchange current density and HBE is also observed on the four metals, indicating that they may share the same elementary steps and rate-determining steps and that the HBE is the dominant descriptor for HOR/HER activities. The onset potential of CO stripping on the four metals decreases with pH, indicating a stronger OH adsorption, which provides evidence against the promoting effect of adsorbed OH on HOR/HER.

  5. Heaters to simulate fuel pins for heat transfer tests in single-phase liquid-metal-flow

    International Nuclear Information System (INIS)

    Casal, V.; Graf, E.; Hartmann, W.

    1976-09-01

    The development of heaters for thermal simulation of the fuel elements of liquid metal cooled fast breeder reactors (SNR) is reported. Beginning with the experimental demands various heating methods are discussed for thermodynamic investigations of the heat transfer in liquid metals. Then a preferred heater rod is derived to simulate the fuel pins of a SNR. Finally it is reported on the fabrication and the operation practice. (orig.) [de

  6. Pulse waveform analysis on temporal changes in ocular blood flow due to caffeine intake: a comparative study between habitual and non-habitual groups.

    Science.gov (United States)

    Ismail, Aishah; Bhatti, Mehwish S; Faye, Ibrahima; Lu, Cheng Kai; Laude, Augustinus; Tang, Tong Boon

    2018-06-06

    To evaluate and compare the temporal changes in pulse waveform parameters of ocular blood flow (OBF) between non-habitual and habitual groups due to caffeine intake. This study was conducted on 19 healthy subjects (non-habitual 8; habitual 11), non-smoking and between 21 and 30 years of age. Using laser speckle flowgraphy (LSFG), three areas of optical nerve head were analyzed which are vessel, tissue, and overall, each with ten pulse waveform parameters, namely mean blur rate (MBR), fluctuation, skew, blowout score (BOS), blowout time (BOT), rising rate, falling rate, flow acceleration index (FAI), acceleration time index (ATI), and resistive index (RI). Two-way mixed ANOVA was used to determine the difference between every two groups where p groups in several ocular pulse waveform parameters, namely MBR (overall, vessel, tissue), BOT (overall), rising rate (overall), and falling rate (vessel), all with p group, but not within the habitual group. The temporal changes in parameters MBR (vessel, tissue), skew (overall, vessel), BOT (overall, vessel), rising rate (overall), falling rate (overall, vessel), and FAI (tissue) were significant for both groups (habitual and non-habitual) in response to caffeine intake. The experiment results demonstrated caffeine does modulate OBF significantly and response differently in non-habitual and habitual groups. Among all ten parameters, MBR and BOT were identified as the suitable biomarkers to differentiate between the two groups.

  7. Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Ka King [Iowa State Univ., Ames, IA (United States)

    2013-01-01

    A series of organometallic compounds containing the tris(dimethylsilyl)methyl ligand are described. The potassium carbanions KC(SiHMe2)3 and KC(SiHMe2})3TMEDA are synthesized by deprotonation of the hydrocarbon HC(SiHMe2)3 with potassium benzyl. KC(SiHMe2)3TMEDA crystallizes as a dimer with two types of three-center-two-electron KH- Si interactions. Homoleptic Ln(III) tris(silylalkyl) complexes containing β-SiH groups M{C(SiHMe2)3}3 (Ln = Y, Lu, La) are synthesized from salt elimination of the corresponding lanthanide halide and 3 equiv. of KC(SiHMe2)3. The related reactions with Sc yield bis(silylalkyl) ate-complexes containing either LiCl or KCl. The divalent calcium and ytterbium compounds M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2 or TMEDA) are prepared from MI2 and 2 equiv of KC(SiHMe2)3. The compounds M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2 or TMEDA) and La{C(SiHMe2)3}3 react with 1 equiv of B(C6F5)3 to give 1,3- disilacyclobutane {Me2Si-C(SiHMe2)2}2 and MC(SiHMe2)3HB(C6F5)3L, and La{C(SiHMe2)3}2HB(C6F5)3, respectively. The corresponding reactions of Ln{C(SiHMe2)3}3 (Ln = Y, Lu) give the β-SiH abstraction product [{(Me2HSi)3C}2LnC(SiHMe2)2SiMe2][HB(C6F5)3] (Ln = Y, Lu), but the silene remains associated with the Y or Lu center. The abstraction reactions of M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2or TMEDA) and Ln{C(SiHMe2)3}3 (Ln = Y, Lu, La) and 2 equiv of B(C6

  8. Thin-layer chromatography of ternary complexes of group-IIIA metals with 2-thenoyltrifluoroacetone and 2,2'-bipyridyl on cellulose layer

    Energy Technology Data Exchange (ETDEWEB)

    Chao, H E; Saitoh, K; Suzuki, N [Tohoku Univ., Sendai (Japan). Faculty of Science

    1980-11-11

    Normal phase thin-layer chromatographic behaviour of several ternary complexes of group-IIIA metals with 2-thenoyltrifluoroacetone (TTA) and 2,2'bipyridyl (bpy) has been investigated on cellulose layer. The ternary complexes of lanthanide metals show higher mutual separability than the complexes with TTA alone. Mutual separation of TTA complexes with La(III), Ce(III), Eu(III) or Y(III), Sc(III), Th(IV), and U(VI) has been successfully achieved by two-dimensional TLC, primarily with carbon tetrachloride-benzene (75:25) containing 0.02M TTA, and secondary with carbon tetrachloride-hexane (35:65) containing both 0.02M TTA and 0.02M bpy.

  9. Synthesis and characterization of near-IR absorbing metal-free and zinc(II phthalocyanines modified with aromatic azo groups

    Directory of Open Access Journals (Sweden)

    Mukaddes Özçeşmeci

    2015-05-01

    Full Text Available Metal-free and zinc(II phthalocyanine complexes bearing peripheral (E-4-((2-hydroxynaphthalen-1-yldiazenyl units have been synthesized. Novel phthalonitrile derivative required for the preparation of phthalocyanine complexes was prepared by coupling 4-aminophthalonitrile and 2-naphthol. The structures of these new compounds were characterized by using elemental analyses, proton nuclear magnetic resonance, fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, fluorescence spectroscopy and mass spectrometry. In the UV-Vis spectra a broad absorption band appears for phthalocyanine complexes at around 450–500 nm resulting from azo-group introduced onto the phthalocyanine ring. The photophysical properties of metal-free and zinc(II phthalocyanines were studied in tetrahydrofuran.

  10. Chromosomal rearrangements and gene flow over time in an inter-specific hybrid zone of the Sorex araneus group.

    Science.gov (United States)

    Yannic, G; Basset, P; Hausser, J

    2009-06-01

    Most hybrid zones have existed for hundreds or thousands of years but have generally been observed for only a short time period. Studies extending over periods long enough to track evolutionary changes in the zones or assess the ultimate outcome of hybridization are scarce. Here, we describe the evolution over time of the level of genetic isolation between two karyotypically different species of shrews (Sorex araneus and Sorex antinorii) at a hybrid zone located in the Swiss Alps. We first evaluated hybrid zone movement by contrasting patterns of gene flow and changes in cline parameters (centre and width) using 24 microsatellite loci, between two periods separated by 10 years apart. Additionally, we tested the role of chromosomal rearrangements on gene flow by analysing microsatellite loci located on both rearranged and common chromosomes to both species. We did not detect any movement of the hybrid zone during the period analysed, suggesting that the zone is a typical tension zone. However, the gene flow was significantly lower among the rearranged than the common chromosomes for the second period, whereas the difference was only marginally significant for the first period. This further supports the role of chromosomal rearrangements on gene flow between these taxa.

  11. Is Investment-Cash flow Sensitivity a Good Measure of Financing Constraints? New Evidence from Indian Business Group Firms

    NARCIS (Netherlands)

    George, R.; Kabir, M.R.; Qian, J.

    2005-01-01

    Several studies use the investment - cash flow sensitivity as a measure of financing constraints while some others disagree.The source of this disparity lies mostly in differences in opinion regarding the segregation of severely financially constrained firms from less constrained ones.We examine

  12. Tracing carbon flow from microphytobenthos to major bacterial groups in an intertidal marine sediment by using an in situ

    NARCIS (Netherlands)

    Miyatake, T.; Moerdijk-Poortvliet, T.C.W.; Stal, L.J.; Boschker, H.T.S.

    2014-01-01

    Carbon flow from benthic diatoms to heterotrophic bacterial was traced in an intertidal sediment for 5consecutive days. 13C-labeled bicarbonate was sprayed onto the sediment surface during low tide and 13C-labelincorporation in major carbon pools, intermediate metabolites, and biomarkers were

  13. Feasibility of asymmetric flow field-flow fractionation coupled to ICP-MS for the characterization of wear metal particles and metalloproteins in biofluids from hip replacement patients

    DEFF Research Database (Denmark)

    Löschner, Katrin; Harrington, Chris F.; Kearney, Jacque-Lucca

    2015-01-01

    or other elements, but the current analytical methods used to investigate the processes involved do not provide sufficient information to understand the size or composition of the wear particles generated in vivo. In this qualitative feasibility study, asymmetric flow field-flow fractionation (AF4) coupled...... to ICP-MS was used to confirm the metal–protein associations in the serum samples. Off-line single particle ICP-MS (spICP-MS) analysis was used to confirm the approximate size distribution indicated by AF4 of the wear particles in hip aspirates. In the serum samples, AF4–ICP-MS suggested that Cr...... unidentified compounds; AEC analysis confirmed the Cr results and the association of Co with Alb and a second compound. Enzymatic digestion of the hip aspirate sample, followed by separation using AF4 with detection by UV absorption (280 nm), multi-angle light scattering and ICP-MS, suggested that the sizes...

  14. Sensor for metal detection

    KAUST Repository

    Kodzius, Rimantas

    2014-06-26

    NOVELTY - The sensor has a microfluidic flow channel that is provided with an inlet port, an outlet port, and a detection chamber. The detection chamber is provided with a group of sensing electrodes (4) having a working electrode (8), a counter electrode (9), and a reference electrode (10). A flow sensor is configured to measure flow in the channel. A temperature sensor (6) is configured to measure temperature in the channel (3). An electrical connection is configured to connect the sensor to a sensing device. USE - Sensor for detecting metal such as toxic metal in sample such as clinical sample such as stool, saliva, sputum, bronchial lavage, urine, vaginal swab, nasal swab, biopsy, tissue, tears, breath, blood, serum, plasma, cerebrospinal fluid, peritoneal fluid, pleural fluid, pericardial fluid, joint fluid, and amniotic fluid, water sample, food sample, air sample, and soil sample (all claimed). ADVANTAGE - The sensor for use with the portable analytical instrument is configured for detection of metalsin samples. The sensor can provide the excellent solution for on-site metal detection, including heavy metal detection. The sensors can provide significant advantages in higher throughput, lower cost, at the same time being less labor intensive and less dependent on individual skills. The disposable design of the sensor, the enhanced reliability and repeatability of measurements can be obtained. The sensors can be widely applied in various industries. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a system for detecting metal in sample; and (2) a method for using sensor for detecting metal in sample. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic view of the sensor prototype. Channel (3) Sensing electrodes (4) Temperature sensor (6) Working electrode (8) Counter electrode (9) Reference electrode (10)

  15. Influence of polycrystalline silicon layer on flow through «metal — p-Si» contact

    Directory of Open Access Journals (Sweden)

    Smyntyna V. A.

    2011-11-01

    Full Text Available Based on the results of investigations of charge transport in the "metal — p-Si" contacts with different thickness of polycrystalline p-Si layer the mechanisms of charge transport through such structures are shown. It is established that with increasing thickness of the layer of polycrystalline p-Si current transport mechanism changes from a double injection into the drift-diffusion. This change is due to an increase in the drift current component in the space charge zone of "metal — p-Si" contact, which arises as a result of increased surface density of scattering barriers, which are localized at the boundaries of neighboring silicon polycrystals.

  16. Highly effective synthesis of a cobalt(ii) metal-organic coordination polymer by using continuous flow chemistry.

    Science.gov (United States)

    Gong, Chunhua; Zhang, Junyong; Zeng, Xianghua; Xie, Jingli

    2016-12-20

    The coordination polymer [Co 2 L 4 (H 2 O) 2 ]·CH 3 CN·H 2 O (HL = (E)-2-[2-(4-chlorophenyl)vinyl]-8-hydroxyquinoline) has been achieved with 95% yield by using an Asia flow synthesis system (chip reactor). Compared with the conventional batch-type methods such as diffusion, reflux and solvothermal reactions, higher yielding reactions carried out in a flow reactor have demonstrated that this technique is a powerful strategy to obtain coordination compounds.

  17. Three-dimensional granular model of semi-solid metallic alloys undergoing solidification: Fluid flow and localization of feeding

    International Nuclear Information System (INIS)

    Sistaninia, M.; Phillion, A.B.; Drezet, J.-M.; Rappaz, M.

    2012-01-01

    A three-dimensional (3-D) granular model which simulates fluid flow within solidifying alloys with a globular microstructure, such as that found in grain refined Al alloys, is presented. The model geometry within a representative volume element (RVE) consists of a set of prismatic triangular elements representing the intergranular liquid channels. The pressure field within the liquid channels is calculated using a finite elements (FEs) method assuming a Poiseuille flow within each channel and flow conservation at triple lines. The fluid flow is induced by solidification shrinkage and openings at grain boundaries due to deformation of the coherent solid. The granular model predictions are validated against bulk data calculated with averaging techniques. The results show that a fluid flow simulation of globular semi-solid materials is able to reproduce both a map of the 3-D intergranular pressure and the localization of feeding within the mushy zone. A new hot cracking sensitivity coefficient is then proposed. Based on a mass balance performed over a solidifying isothermal volume element, this coefficient accounts for tensile deformation of the semi-solid domain and for the induced intergranular liquid feeding. The fluid flow model is then used to calculate the pressure drop in the mushy zone during the direct chill casting of aluminum alloy billets. The predicted pressure demonstrates that deep in the mushy zone where the permeability is low the local pressure can be significantly lower than the pressure predicted by averaging techniques.

  18. Remarkable enhancement on elimination reaction of side groups in excimer laser ablation of mixture targets of perylene derivatives with metal powder

    International Nuclear Information System (INIS)

    Nishio, Satoru; Tamura, Kazuyuki; Tsujine, Yukari; Fukao, Tomoko; Nakano, Masayoshi; Matsuzaki, Akiyoshi; Sato, Hiroyasu

    2002-01-01

    Films are deposited on substrates at 20 deg.C by excimer laser ablation (ELA) of mixture targets of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) with metal powder, PTCDA/M (M=Co, Ni, Fe, W, Cu and Ag) using XeCl and ArF beams. Large amount of fragments with ''naked'' perylene skeletons can be produced owing to effective elimination of carboxylic dianhydride groups by ELA of PTCDA/Co both with XeCl and ArF beams under optimized ablation conditions. Elimination reaction of side groups of PTCDA is observed for ELA of the targets with metal powder of the iron group, Co, Fe and Ni, especially remarkable for Co and Fe. The film from PTCDA/Ni consists of small particles with the various diameters ranging from 10 to 100 nm as well as that from PTCDA/Co. Morphology like petal of rose can be seen everywhere for the film from PTCDA/Fe

  19. An automated flow injection system for metal determination by flame atomic absorption spectrometry involving on-line fabric disk sorptive extraction technique.

    Science.gov (United States)

    Anthemidis, A; Kazantzi, V; Samanidou, V; Kabir, A; Furton, K G

    2016-08-15

    A novel flow injection-fabric disk sorptive extraction (FI-FDSE) system was developed for automated determination of trace metals. The platform was based on a minicolumn packed with sol-gel coated fabric media in the form of disks, incorporated into an on-line solid-phase extraction system, coupled with flame atomic absorption spectrometry (FAAS). This configuration provides minor backpressure, resulting in high loading flow rates and shorter analytical cycles. The potentials of this technique were demonstrated for trace lead and cadmium determination in environmental water samples. The applicability of different sol-gel coated FPSE media was investigated. The on-line formed complex of metal with ammonium pyrrolidine dithiocarbamate (APDC) was retained onto the fabric surface and methyl isobutyl ketone (MIBK) was used to elute the analytes prior to atomization. For 90s preconcentration time, enrichment factors of 140 and 38 and detection limits (3σ) of 1.8 and 0.4μgL(-1) were achieved for lead and cadmium determination, respectively, with a sampling frequency of 30h(-1). The accuracy of the proposed method was estimated by analyzing standard reference materials and spiked water samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. Annual trace-metal load estimates and flow-weighted concentrations of cadmium, lead, and zinc in the Spokane River basin, Idaho and Washington, 1999-2004

    Science.gov (United States)

    Donato, Mary M.

    2006-01-01

    Streamflow and trace-metal concentration data collected at 10 locations in the Spokane River basin of northern Idaho and eastern Washington during 1999-2004 were used as input for the U.S. Geological Survey software, LOADEST, to estimate annual loads and mean flow-weighted concentrations of total and dissolved cadmium, lead, and zinc. Cadmium composed less than 1 percent of the total metal load at all stations; lead constituted from 6 to 42 percent of the total load at stations upstream from Coeur d'Alene Lake and from 2 to 4 percent at stations downstream of the lake. Zinc composed more than 90 percent of the total metal load at 6 of the 10 stations examined in this study. Trace-metal loads were lowest at the station on Pine Creek below Amy Gulch, where the mean annual total cadmium load for 1999-2004 was 39 kilograms per year (kg/yr), the mean estimated total lead load was about 1,700 kg/yr, and the mean annual total zinc load was 14,000 kg/yr. The trace-metal loads at stations on North Fork Coeur d'Alene River at Enaville, Ninemile Creek, and Canyon Creek also were relatively low. Trace-metal loads were highest at the station at Coeur d'Alene River near Harrison. The mean annual total cadmium load was 3,400 kg/yr, the mean total lead load was 240,000 kg/yr, and the mean total zinc load was 510,000 kg/yr for 1999-2004. Trace-metal loads at the station at South Fork Coeur d'Alene River near Pinehurst and the three stations on the Spokane River downstream of Coeur d'Alene Lake also were relatively high. Differences in metal loads, particularly lead, between stations upstream and downstream of Coeur d'Alene Lake likely are due to trapping and retention of metals in lakebed sediments. LOADEST software was used to estimate loads for water years 1999-2001 for many of the same sites discussed in this report. Overall, results from this study and those from a previous study are in good agreement. Observed differences between the two studies are attributable to streamflow

  1. Levels of Platinum Group Metals in Selected Species (Sarotherodon melanotheron, Chonophorus lateristriga, Macrobrachium vollenhovenii and Crassostrea tulipa in Some Estuaries and Lagoons Along the Coast of Ghana

    Directory of Open Access Journals (Sweden)

    D. K. Essumang

    2010-01-01

    Full Text Available The use of some biota as bioindicators of heavy metal pollution has been demonstrated as particularly adequate due to their capacity of bioconcentration. This study evaluated the levels of platinum group metals (PGMs in some selected species along the coastal belt of Ghana, using the neutron activation analysis (NAA method. The result was processed to evaluate pollution indices in order to map the distribution of the metals in those species in the lagoons and estuaries along the costal belt of Ghana. The analysis showed significant levels of all PGMs in blackchin tilapia (Sarotherodon melanotheron Cichlidae, brown goby (Chonophorus lateristriga Gobiidae, shrimp (Macrobrachium vollenhovenii Palaemonidae, and mangrove oysters (Crassostrea tulipa Ostreidae in the lagoons and river Pra estuary. However, the oysters showed an elevated mean concentration of 0.13 μ/g (dry weight Pd. From the pollution indices, most of the sampling sites registered mean contamination factor (CF values between 1.20 and 3.00 for Pt, Pd, and Rh. The pollution load index (PLI conducted also gave an average pollution index between 0.79 and 2.37, indicating progressive contamination levels. The results revealed that anthropogenic sources, industrial and hospital effluent, etc., together with vehicular emissions, could be the contributing factors to the deposition of PGMs along the Ghanaian coast.

  2. Chelation of heavy group 2 (radio)metals by p-tert-butylcalix[4]arene-1,3-crown-6 and logK determination via NMR

    Science.gov (United States)

    Bauer, David; Gott, Matthew; Steinbach, Jörg; Mamat, Constantin

    2018-06-01

    A crown-bridged calix[4]arene scaffold was investigated as lead compound for the ligation of heavy alkaline earth metals such as strontium and barium, which appear to be useful for radiopharmaceutical applications in diagnosis as well as in radiotherapy. In particular barium, due to its chemical similarities, could serve as a surrogate for radium, a metal of high radiopharmaceutical interest. The ability of p-tert-butylcalix[4]arene-1,3-crown-6 (1) in particular to chelate cations, such as group 1 and 2 metal ions or ammonium ions is well known. Also, the manifold possibilities of structural modification on the upper- and lower-rim as well as on the crown itself produce properties that may lead to a highly selective and effective chelating agent. In this work, titration experiments of the perchlorate salts of Ba2+, Sr2+ and Pb2+ with ligand 1 were performed to determine their stability constants (logK = 4.7, 4.3, and 3.3, respectively) by 1H NMR measurements in acetonitrile-d3.

  3. Catalytic transformations of fatty acids derivatives for food, oleochemicals and fuels over carbon supported platinum group metals

    Energy Technology Data Exchange (ETDEWEB)

    Simakova, I.

    2010-07-01

    prominent in linoleic acid deoxygenation giving only 3 % conversion of fatty acids in 330 min. The deactivation originated from the formation of C17 aromatic compounds and fatty acid dimers via Diels-Alder reaction. Thus hydrogenation of unsaturated fatty acids can be considered as preliminary chemical modification step in the green diesel production. In this work particular care was taken to strengthen the nano level understanding of the Pd role, in particular metal size effect, in the catalytic hydrogenation and deoxygenation. Pd/C catalysts were synthesized with the same Pd loading and systematically varied metal dispersion via the controllable formation of Pd particles over carbon support surface. The effect of metal dispersion on hydrogenation rate and trans/cis ratio was revealed. An optimum metal dispersion giving the highest decarboxylation reaction rate was observed. In addition to the particle size effect, the impact of mass transfer was elucidated and detail discussions on temperature programmed desorption of CO from the fresh and spent samples was provided. Hydrogenation of vegetable feedstocks was performed in batch and continuous modes, using powdered and granulated Pd/C catalysts correspondingly. One of the main focuses of the work was put on the scale-up of the hydrogenation process. There are several challenges attributed to the scale-up of a chemical process which have to be recognized before progressing to an industrial application. In terms of the high production volumes the logical step is to investigate the performance of hydrogenation as a continuous process. A laboratory study in a continuous fixed bed reactor was performed, giving crucial information about the catalyst long-term stability and catalyst deactivation. Furthermore, the impact of using free fatty acids or triglycerides feedstocks as well as the effect of catalyst particle size and Pd loading were investigated in continuous mode. Finally, the production capacities for different operation

  4. Validation of numerical solvers for liquid metal flow in a complex geometry in the presence of a strong magnetic field

    Science.gov (United States)

    Patel, Anita; Pulugundla, Gautam; Smolentsev, Sergey; Abdou, Mohamed; Bhattacharyay, Rajendraprasad

    2018-04-01

    Following the magnetohydrodynamic (MHD) code validation and verification proposal by Smolentsev et al. (Fusion Eng Des 100:65-72, 2015), we perform code to code and code to experiment comparisons between two computational solvers, FLUIDYN and HIMAG, which are presently considered as two of the prospective CFD tools for fusion blanket applications. In such applications, an electrically conducting breeder/coolant circulates in the blanket ducts in the presence of a strong plasma-confining magnetic field at high Hartmann numbers, it{Ha} (it{Ha}^2 is the ratio between electromagnetic and viscous forces) and high interaction parameters, it{N} (it{N} is the ratio of electromagnetic to inertial forces). The main objective of this paper is to provide the scientific and engineering community with common references to assist fusion researchers in the selection of adequate computational means to be used for blanket design and analysis. As an initial validation case, the two codes are applied to the classic problem of a laminar fully developed MHD flows in a rectangular duct. Both codes demonstrate a very good agreement with the analytical solution for it{Ha} up to 15, 000. To address the capabilities of the two codes to properly resolve complex geometry flows, we consider a case of three-dimensional developing MHD flow in a geometry comprising of a series of interconnected electrically conducting rectangular ducts. The computed electric potential distributions for two flows (Case A) it{Ha}=515, it{N}=3.2 and (Case B) it{Ha}=2059, it{N}=63.8 are in very good agreement with the experimental data, while the comparisons for the MHD pressure drop are still unsatisfactory. To better interpret the observed differences, the obtained numerical data are analyzed against earlier theoretical and experimental studies for flows that involve changes in the relative orientation between the flow and the magnetic field.

  5. Mapping the dark matter in the NGC 5044 group with ROSAT: Evidence for a nearly homogeneous cooling flow with a cooling wake

    Science.gov (United States)

    David, Laurence P.; Jones, Christine; Forman, William; Daines, Stuart

    1994-01-01

    The NGC 5044 group of galaxies was observed by the ROSAT Position Sensitive Proportional Counter (PSPC) for 30 ks during its reduced pointed phase (1991 July). Due to the relatively cool gas temperature in the group (kT = 0.98 +/- 0.02 keV) and the excellent photon statistics (65,000 net counts), we are able to determine precisely a number of fundamental properties of the group within 250 kpc of the central galaxy. In particular, we present model-independent measurements of the total gravitating mass, the temperature and abundance profiles of the gas, and the mass accretion rate. Between 60 and 250 kpc, the gas is nearly isothermal with T varies as r(exp (-0.13 +/- 0.03)). The total gravitating mass of the group can be unambiguously determined from the observed density and temperature profiles of the gas using the equation of hydrostatic equilibrium. Within 250 kpc, the gravitating mass is 1.6 x 10(exp 13) solar mass, yielding a mass-to-light ratio of 130 solar mass/solar luminosity. The baryons (gas and stars) comprise 12% of the total mass within this radius. At small radii, the temperature clearly increases outward and attains a maximum value at 60 kpc. The positive temperature gradient in the center of the group confirms the existence of a cooling flow. The cooling flow region extends well beyond the temperature maximum with a cooling radius between 100 and 150 kpc. There are two distinct regions in the cooling flow separated by the temperature maximum. In the outer region, the gas is nearly isothermal with a unifor m Fe abundance of approximately 80% solar, the flow is nearly homogeneous with dot-M= 20 to 25 solar mass/year, the X-ray contours are spherically symmetric, and rho(sub gas) varies as r(exp -1.6). In the inner region, the temperature profile has a positive gradient, the mass accretion rate decreases rapidly inward, the gas density profile is steeper, and the X-ray image shows some substrucutre. NGC 5044 is offset from the centroid of the outer X

  6. Environmental analysis of heavy metal deposition in a flow-restricted tropical estuary and its adjacent shelf

    Digital Repository Service at National Institute of Oceanography (India)

    Balachandran, K.K.; Laluraj, C.M.; Martin, G.D.; Srinivas, K.; Venugopal, P.

    103m3.d-1, CPCB, 1996). The major polluting industries in the region include fertilizer plant, oil refinery, rare earth processing plant, minerals and rutiles plant, zinc smelter plant, insecticide factory and organic chemical plant. Reclamations... bodies can promote coagulation or co-precipitation of metals under the varying ionic (salinity) condition (Antonio and Prego, 2004). Studies elsewhere have shown that oxides of Fe+3 are bio-available through bacterial mineralization and hence, could...

  7. The large second-harmonic generation of LiCs{sub 2}PO{sub 4} is caused by the metal-cation-centered groups

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Xiyue; Guo, Guo-Cong; Hong, Maochun; Deng, Shuiquan [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter (FJIRSM), Chinese Academy of Sciences (CAS), Fuzhou (China); Whangbo, Myung-Hwan [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter (FJIRSM), Chinese Academy of Sciences (CAS), Fuzhou (China); Department of Chemistry, North Carolina State University, Raleigh, NC (United States)

    2018-04-03

    We evaluated the individual atom contributions to the second harmonic generation (SHG) coefficients of LiCs{sub 2}PO{sub 4} (LCPO) by introducing the partial response functionals on the basis of first principles calculations. The SHG response of LCPO is dominated by the metal-cation-centered groups CsO{sub 6} and LiO{sub 4}, not by the nonmetal-cation-centered groups PO{sub 4} expected from the existing models and theories. The SHG coefficients of LCPO are determined mainly by the occupied orbitals O 2p and Cs 5p as well as by the unoccupied orbitals Cs 5d and Li 2p. For the SHG response of a material, the polarizable atomic orbitals of the occupied and the unoccupied states are both important. (copyright 2018 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Progress in liquid metal fast reactor technology. Proceedings of the 28th meeting of the International Working Group on Fast Reactors

    International Nuclear Information System (INIS)

    1996-04-01

    The key objectives and activities of Member State liquid metal fast reactor (LMFR) programmes are: Demonstration of effective designs; demonstration of system safety; demonstration of economic competitiveness with other power generation systems. The International Working Group on Fast Reactors (IWGFR) at its 1995 meeting observed that while some countries (as a result of static or falling power demand) are reducing the research and development programmes or delaying the commercial deployment of fast reactors, other countries are planning to introduce these reactors and are embarking on their own development programmes. In these circumstances the international exchange of information and experience is of increasing importance. These proceedings contain updated information from long standing members of the IWGFR and new information on the status of LMFR research and development from new members of the Group: Brazil, China, Republic of Kazakhstan and the Republic of Korea. Refs, figs, tabs

  9. Progress in liquid metal fast reactor technology. Proceedings of the 28th meeting of the International Working Group on Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-01

    The key objectives and activities of Member State liquid metal fast reactor (LMFR) programmes are: Demonstration of effective designs; demonstration of system safety; demonstration of economic competitiveness with other power generation systems. The International Working Group on Fast Reactors (IWGFR) at its 1995 meeting observed that while some countries (as a result of static or falling power demand) are reducing the research and development programmes or delaying the commercial deployment of fast reactors, other countries are planning to introduce these reactors and are embarking on their own development programmes. In these circumstances the international exchange of information and experience is of increasing importance. These proceedings contain updated information from long standing members of the IWGFR and new information on the status of LMFR research and development from new members of the Group: Brazil, China, Republic of Kazakhstan and the Republic of Korea. Refs, figs, tabs.

  10. Real-time algorithm for the measurement of liquid metal coolant flow velocity with correlated thermal signals

    International Nuclear Information System (INIS)

    Moazzeni, Taleb; Jiang, Yingtao; Ma, Jian; Li, Ning

    2009-01-01

    One flow meter was developed especially for the environment of high irradiation, pressure, and temperature. The transit time of natural random temperature fluctuation in process, for example nuclear reactor, can be obtained based on the cross-correlation method, which has already been shown that it is capable in situations where no other flow meter can be used. Thereby, the flow rate can be derived in pipe flow if the area of cross-section is known. In practice, the evaluation of the integrals over the measurement time in cross-correlation method will lead errors caused by peak detection from flat cross correlation coefficient distribution or additional peaks. One Auto-Adaptive Impulse Response Function estimation is introduced and significantly narrower peak will be obtained. Fiber optic sensors are advantageous for temperature measurements in the reactor pressure vessels. However, the corrosive coolant (as liquid lead/lead alloy or molten salt coolant) is a barrier of the optic sensor in such application. Thermocouple with grounded stainless steel shielding material would have same life time with structure material in reactor, although thermocouple has relatively slow response. The degradation due to corrosion/erosion will not introduce measurement error or necessary calibration, because only the correlation between signals is taken into consideration during measurements. Experiments conducted in a testing hydraulic facility approved the considerable improvement of accuracy by this new algorithm using thermocouple temperature sensors. (author)

  11. Influence of metal loading and humic acid functional groups on the complexation behavior of trivalent lanthanides analyzed by CE-ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Kautenburger, Ralf, E-mail: r.kautenburger@mx.uni-saarland.de [Institute of Inorganic Solid State Chemistry, Saarland University, Campus Dudweiler, Am Markt Zeile 3-5, D-66125 Saarbrücken (Germany); Hein, Christina; Sander, Jonas M. [Institute of Inorganic Solid State Chemistry, Saarland University, Campus Dudweiler, Am Markt Zeile 3-5, D-66125 Saarbrücken (Germany); Beck, Horst P. [Institute of Inorganic and Analytical Chemistry and Radiochemistry, Saarland University, Campus Dudweiler, Am Markt Zeile 5, D-66125 Saarbrücken (Germany)

    2014-03-01

    Highlights: • Free and complexed HA-Ln species are separated by CE-ICP-MS. • Weaker and stronger HA-binding sites for Ln-complexation can be detected. • Complexation by original and modified humic acid (HA) with blocked phenolic hydroxyl- and carboxyl-groups is compared. • Stronger HA-binding sites for Ln³⁺ can be assumed as chelating complexes. • Chelates consist of trivalent Ln and a combination of both OH- and COOH-groups. Abstract: The complexation behavior of Aldrich humic acid (AHA) and a modified humic acid (AHA-PB) with blocked phenolic hydroxyl groups for trivalent lanthanides (Ln) is compared, and their influence on the mobility of Ln(III) in an aquifer is analyzed. As speciation technique, capillary electrophoresis (CE) was hyphenated with inductively coupled plasma mass spectrometry (ICP-MS). For metal loading experiments 25 mg L⁻¹ of AHA and different concentrations (c Ln(Eu+Gd)} = 100–6000 μg L⁻¹) of Eu(III) and Gd(III) in 10 mM NaClO₄ at pH 5 were applied. By CE-ICP-MS, three Ln-fractions, assumed to be uncomplexed, weakly and strongly AHA-complexed metal can be detected. For the used Ln/AHA-ratios conservative complex stability constants log βLnAHA decrease from 6.33 (100 μg L⁻¹ Ln³⁺) to 4.31 (6000 μg L⁻¹ Ln³⁺) with growing Ln-content. In order to verify the postulated weaker and stronger humic acid binding sites for trivalent Eu and Gd, a modified AHA with blocked functional groups was used. For these experiments 500 μg L⁻¹ Eu and 25 mg L⁻¹ AHA and AHA-PB in 10 mM NaClO₄ at pH-values ranging from 3 to 10 have been applied. With AHA-PB, where 84% of the phenolic OH-groups and 40% of the COOH-groups were blocked, Eu complexation was significantly lower, especially at the strong binding sites. The log β-values decrease from 6.11 (pH 10) to 5.61 at pH 3 (AHA) and for AHA-PB from 6.01 (pH 7) to 3.94 at pH 3. As a potential consequence, particularly humic acids with a high amount of

  12. Metal-organic coordination architectures of tetrazole heterocycle ligands bearing acetate groups: Synthesis, characterization and magnetic properties

    Science.gov (United States)

    Hu, Bo-Wen; Zheng, Xiang-Yu; Ding, Cheng

    2015-12-01

    Two new coordination complexes with tetrazole heterocycle ligands bearing acetate groups, [Co(L)2]n (1) and [Co3(L)4(N3)2·2MeOH]n (2) (L=tetrazole-1-acetate) have been synthesized and structurally characterized. Single crystal structure analysis shows that the cobalt-complex 1 has the 3D 3,6-connected (42.6)2(44.62.88.10)-ant topology. By introducing azide in this system, complex 2 forms the 2D network containing the [Co3] units. And the magnetic properties of 1 and 2 have been studied.

  13. Mechanisms for the reactions of group 10 transition metal complexes with metal-group 14 element bonds, Bbt(Br)E═M(PCy3)2 (E = C, Si, Ge, Sn, Pb; M = Pd and Pt).

    Science.gov (United States)

    Liao, Wei-Hung; Ho, Pei-Yun; Su, Ming-Der

    2013-02-04

    The electronic structures of the Bbt(Br)E═M(PCy(3))(2) (E = C, Si, Ge, Sn, Pb and M = Pt, Pd) complexes and their potential energy surfaces for the formation and water addition reactions were studied using density functional theory (B3LYP/LANL2DZ). The theoretical evidence suggests that the bonding character of the E═M double bond between the six valence-electron Bbt(Br)E: species and the 14 valence-electron (PCy(3))(2)M complexes has a predominantly high s-character. That is, on the basis of the NBO, this theoretical study indicates that the σ-donation from the E element to the M atom prevails. Also, theoretical computations suggest that the relative reactivity decreases in the order: Bbt(Br)C═M(PCy(3))(2) > Bbt(Br)Si═M(PCy(3))(2) > Bbt(Br)Ge═M(PCy(3))(2) > Bbt(Br)Sn═M(PCy(3))(2) > Bbt(Br)Pb═M(PCy(3))(2), irrespective of whether M = Pt or M = Pd is chosen. Namely, the greater the atomic weight of the group 14 atom (E), the larger is the atomic radius of E and the more stable is its Bbt(Br)E═M(PCy(3))(2) doubly bonded species toward chemical reactions. The computational results show good agreement with the available experimental observations. The theoretical results obtained in this work allow a number of predictions to be made.

  14. Red-shifting and blue-shifting OH groups on metal oxide surfaces - towards a unified picture.

    Science.gov (United States)

    Kebede, Getachew G; Mitev, Pavlin D; Briels, Wim J; Hermansson, Kersti

    2018-05-09

    We analyse the OH vibrational signatures of 56 structurally unique water molecules and 34 structurally unique hydroxide ions in thin water films on MgO(001) and CaO(001), using DFT-generated anharmonic potential energy surfaces. We find that the OH stretching frequencies of intact water molecules on the surface are always downshifted with respect to the gas-phase species while the OH- groups are either upshifted or downshifted. Despite these differences, the main characteristics of the frequency shifts for all three types of surface OH groups (OHw, OsH and OHf) can be accounted for by one unified expression involving the in situ electric field from the surrounding environment, and the gas-phase molecular properties of the vibrating species (H2O or OH-). The origin behind the different red- and blueshift behaviour can be traced back to the fact that the molecular dipole moment of a gas-phase water molecule increases when an OH bond is stretched, but the opposite is true for the hydroxide ion. We propose that familiarity with the relations presented here will help surface scientists in the interpretation of vibrational OH spectra for thin water films on ionic crystal surfaces.

  15. Liquid-metal MHD flow in a duct whose cross section changes from a rectangle to a trapezoid, with applications in fusion blanket designs

    International Nuclear Information System (INIS)

    Walker, J.S.

    1986-04-01

    This paper treats the liquid-metal MHD flow in a semi-infinite rectangular duct and a semi-infinite trapezoidal duct, which are connected by a finite-length transition duct. There is a strong, transverse, uniform magnetic field. The walls parallel to the magnetic field (sides) remain parallel, while the walls intersecting the magnetic field are twisted in the transition duct to provide the change in cross sectional shape. The left side has a constant height, while the height of the right side increases or decreases in the transition duct. This geometry gives a skewed velocity profile with a high velocity near the left side, provided the right side is relatively thick. All walls are thin and electrically conducting, but the sides are considerably thicker than the other walls. The application is to fusion-reactor blankets in which a high velocity near the first wall (separating the plasma chamber from the coolant) improves the thermal performance. Junctions of different ducts with walls parallel to the magnetic field are treated for the first time. In expansions, contractions and other geometric transition ducts, as well as in straight ducts with axially varying magnetic fields, the fluid flow and electric currents are concentrated in boundary layers adjacent to the sides and in the side. At a junction with a straight duct with a uniform magnetic field, the flow and current must transfer from the boundary layers adn sides to the core regions. These transfers at junctions play a key role in any three-dimensional flow

  16. Liquid-metal MHD flow in a duct whose cross section changes from a rectangle to a trapezoid, with applications in fusion blanket designs

    Energy Technology Data Exchange (ETDEWEB)

    Walker, J.S.

    1986-04-01

    This paper treats the liquid-metal MHD flow in a semi-infinite rectangular duct and a semi-infinite trapezoidal duct, which are connected by a finite-length transition duct. There is a strong, transverse, uniform magnetic field. The walls parallel to the magnetic field (sides) remain parallel, while the walls intersecting the magnetic field are twisted in the transition duct to provide the change in cross sectional shape. The left side has a constant height, while the height of the right side increases or decreases in the transition duct. This geometry gives a skewed velocity profile with a high velocity near the left side, provided the right side is relatively thick. All walls are thin and electrically conducting, but the sides are considerably thicker than the other walls. The application is to fusion-reactor blankets in which a high velocity near the first wall (separating the plasma chamber from the coolant) improves the thermal performance. Junctions of different ducts with walls parallel to the magnetic field are treated for the first time. In expansions, contractions and other geometric transition ducts, as well as in straight ducts with axially varying magnetic fields, the fluid flow and electric currents are concentrated in boundary layers adjacent to the sides and in the side. At a junction with a straight duct with a uniform magnetic field, the flow and current must transfer from the boundary layers adn sides to the core regions. These transfers at junctions play a key role in any three-dimensional flow.

  17. Magnetohydrodynamic liquid metal flow in arbitrary three-dimensional geometries in strong, non-uniform magnetic fields

    International Nuclear Information System (INIS)

    Buehler, L.

    1993-02-01

    Inductionless magnetohydrodynamic (MHD) flows at high Hartmann numbers are calculated by splitting the whole flow region into an inviscid core and into very thin boundary layers near channel walls. The momentum equations are linearized for high interaction parameters by neglecting inertial terms. These assumptions allow considerable simplifications of the governing equations in all subregions. In the core the general 3D equations are reduced to 2D equations by an analytical integration. The boundary conditions at channel walls are satisfied by the solution of boundary layer equations, leading to 2D equations for charge conservation in the layer. The interior of every arbitrary shaped channel is mapped by a coordinate transformation to a standard volume. The coupled 2D equations are solved numerically on the surface of this standard volume. (orig.)

  18. Migration of a groundwater contaminant plume by stratabound flow in Waste Area Grouping 1 at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    Ketelle, R.H.; Lee, R.R.

    1992-08-01

    The discovery of radiologically contaminated groundwater in core hole CH-8 in the western portion of Waste Area Grouping (WAG) 1 at Oak Ridge National Laboratory (ORNL) prompted a detailed investigation to identify the contaminant plume. Utilizing a working hypothesis of stratabound groundwater flow and contaminant transport, investigators analyzed existing subsurface geologic data to predict the contaminant plume discharge location in first Creek and locations of contaminated groundwater seepage into storm drains. The hypothesis states that differential lithologic/fracture conditions lead to the development of preferred flow and transport pathways, of discrete vertical extent, which may not be coincident with the hydraulic gradient. Leakage out of the stratabound pathway is a minor component of the overall plume configuration

  19. The international INTRAVAL project. Phase 2, working group 1 report. Flow and tracer experiments in unsaturated tuff and soil. Las Cruces trench and Apache Leap tuff studies

    International Nuclear Information System (INIS)

    Nicholson, T.J.; Guzman-Guzman, A.; Hills, R.; Rasmussen, T.C.

    1997-01-01

    The Working Group 1 final report summaries two test case studies, the Las Cruces Trench (LCT), and Apache Leap Tuff Site (ALTS) experiments. The objectives of these two field studies were to evaluate models for water flow and contaminant transport in unsaturated, heterogeneous soils and fractured tuff. The LCT experiments were specifically designed to test various deterministic and stochastic models of water flow and solute transport in heterogeneous, unsaturated soils. Experimental data from the first tow LCT experiments, and detailed field characterisation studies provided information for developing and calibrating the models. Experimental results from the third experiment were held confidential from the modellers, and were used for model comparison. Comparative analyses included: point comparisons of water content; predicted mean behavior for water flow; point comparisons of solute concentrations; and predicted mean behavior for tritium transport. These analyses indicated that no model, whether uniform or heterogeneous, proved superior. Since the INTRAVAL study, however, a new method has been developed for conditioning the hydraulic properties used for flow and transport modelling based on the initial field-measured water content distributions and a set of scale-mean hydraulic parameters. Very good matches between the observed and simulated flow and transport behavior were obtained using the conditioning procedure, without model calibration. The ALTS experiments were designed to evaluate characterisation methods and their associated conceptual models for coupled matrix-fracture continua over a range of scales (i.e., 2.5 centimeter rock samples; 10 centimeter cores; 1 meter block; and 30 meter boreholes). Within these spatial scales, laboratory and field tests were conducted for estimating pneumatic, thermal, hydraulic, and transport property values for different conceptual models. The analyses included testing of current conceptual, mathematical and physical

  20. Measurement and analysis of turbulent liquid metal flow in a high-power spallation neutron source-EURISOL

    CERN Document Server

    Samec, K; Blumenfeld, L; Kharoua, C; Dementjevs, S; Milenkovic, R Z

    2011-01-01

    The European Isotope Separation On-Line (EURISOL) design study completed in 2009 examined means of producing exotic nuclei for fundamental research. One of the critical components identified in the study was a high-power neutron spallation source in which a target material is impacted by a proton beam producing neutrons by a process known as spallation. Due to the high heat power deposition, liquid metal, in this case mercury, is the only viable choice as target material. Complex issues arise from the use of liquid metal. It is characterised by an unusually low Prandtl number and a higher thermal expansivity than conventional fluids. The turbulence structure in LM is thereby affected and still an object of intense research, hampered in part by measurement difficulties. The use of Computational Fluid Dynamics (CFD) allowed a satisfactory design for the neutron source to be found rapidly with little iteration. However it was feared that the development of the boundary layer and associated turbulence would not b...