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Sample records for group ia metal

  1. Estimating Type Ia Supernova Metallicities Using Neural Networks

    Science.gov (United States)

    Villar, V. Ashley

    2017-01-01

    Normal Type Ia supernovae (SNe) can be used as standardizable candles because their progenitors, white dwarfs, are a fairly homogenous class of objects. However, intrinsic variability in these events arise from a number of factors, including metallicity. Recent studies have investigated the effects of metallicity on Type Ia SNe observables from both a theoretical approach, by tuning model metallicity to analyze spectral features, and an observational approach, by studying the effect of host metallicity on light curves. In this work, we take a new, data-driven approach to the problem. Inspired by the success of neural networks in the field of image processing, we aim to estimate the metallicities of Type Ia SNe progenitors from their near-maximum spectra using feed-forward neural networks. We first collect a sample of near-maximum Type Ia SNe spectra from the literature to be smoothed and down-sampled. We then estimate the metallicities of the SNe hosts using the B-band magnitudes. We build a multilayer perceptron to generate a model that takes as input the down-sampled spectra and returns a scalar metallicity. Finally, we discuss basic considerations to be taken when working with spectral (as opposed to image) data using neural networks.

  2. On silicon group elements ejected by supernovae type IA

    Energy Technology Data Exchange (ETDEWEB)

    De, Soma; Timmes, F. X. [School of Earth and Space Exploration, Arizona State University, Tempe, AZ (United States); Brown, Edward F. [Joint Institute for Nuclear Astrophysics, University of Notre Dame, IN 46556 (United States); Calder, Alan C. [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY (United States); Townsley, Dean M. [Department of Physics and Astronomy, The University of Alabama, Tuscaloosa, AL (United States); Athanassiadou, Themis [Swiss National Supercomputing Centre, Via Trevano 131, 6900 Lugano (Switzerland); Chamulak, David A. [Physics Division, Argonne National Laboratory, Argonne, IL (United States); Hawley, Wendy [Laboratoire d' Astrophysique de Marseille, Marseille cedex 13 F-13388 (France); Jack, Dennis, E-mail: somad@asu.edu [Departamento de Astronomía, Universidad de Guanajuato, Apartado Postal 144, 36000 Guanajuato (Mexico)

    2014-06-01

    There is evidence that the peak brightness of a Type Ia supernova is affected by the electron fraction Y {sub e} at the time of the explosion. The electron fraction is set by the aboriginal composition of the white dwarf and the reactions that occur during the pre-explosive convective burning. To date, determining the makeup of the white dwarf progenitor has relied on indirect proxies, such as the average metallicity of the host stellar population. In this paper, we present analytical calculations supporting the idea that the electron fraction of the progenitor systematically influences the nucleosynthesis of silicon group ejecta in Type Ia supernovae. In particular, we suggest the abundances generated in quasi-nuclear statistical equilibrium are preserved during the subsequent freeze-out. This allows potential recovery of Y {sub e} at explosion from the abundances recovered from an observed spectra. We show that measurement of {sup 28}Si, {sup 32}S, {sup 40}Ca, and {sup 54}Fe abundances can be used to construct Y {sub e} in the silicon-rich regions of the supernovae. If these four abundances are determined exactly, they are sufficient to recover Y {sub e} to 6%. This is because these isotopes dominate the composition of silicon-rich material and iron-rich material in quasi-nuclear statistical equilibrium. Analytical analysis shows the {sup 28}Si abundance is insensitive to Y {sub e}, the {sup 32}S abundance has a nearly linear trend with Y {sub e}, and the {sup 40}Ca abundance has a nearly quadratic trend with Y {sub e}. We verify these trends with post-processing of one-dimensional models and show that these trends are reflected in the model's synthetic spectra.

  3. XPS spectra and electronic structure of Group IA sulfates

    Energy Technology Data Exchange (ETDEWEB)

    Wahlqvist, M. [Department of Chemistry, Inorganic Chemistry, Umea University, S-901 87 Umea (Sweden); Shchukarev, A. [Department of Chemistry, Inorganic Chemistry, Umea University, S-901 87 Umea (Sweden)], E-mail: andrei.shchukarev@chem.umu.se

    2007-05-15

    The results of systematic XPS measurements of Group IA (H, Li, Na, K, Rb and Cs) sulfates together with NaHSO{sub 4}, KHSO{sub 4} and (NH{sub 4}){sub 2}SO{sub 4} are presented. The experiments on the alkali metal salts were preformed on ground powders at both liquid nitrogen and room temperatures; concentrated sulfuric acid was measured as a fast-frozen liquid drop. Spectra from grounded and floated samples were compared, and no significant difference relating to charging effects was observed. The influence of grinding on surface chemistry of the powders is described. Such a mechanical activation produces mainly monohydrates on the surface of all sulfates. In the case of Na{sub 2}SO{sub 4}, an additional NaHSO{sub 4} surface phase seems to form that is not stable in vacuum even at liquid nitrogen temperatures. It was found that the binding energies (O 1s and S 2p) of sulfate ion decrease down the group. The shifts are discussed and related to ionicity of the metal-sulfate bond. The structure of XPS valence band spectra is in good agreement with cluster calculations of SO{sub 4}{sup 2-} and HSO{sub 4}{sup -} [A.A. Audi, P.M.A. Sherwood, Surf. Interface Anal. 29 (2000) 265]. While the energies of bisulfate bands are not influenced by the cation (H{sup +}, Na{sup +} or K{sup +}), the sulfate ones experience an increase in bond ionicity and demonstrate the same binding energy shifts as the core levels.

  4. Type Ia Supernovae Keep Memory of their Progenitor Metallicity

    Science.gov (United States)

    Piersanti, Luciano; Bravo, Eduardo; Cristallo, Sergio; Domínguez, Inmaculada; Straniero, Oscar; Tornambé, Amedeo; Martínez-Pinedo, Gabriel

    2017-02-01

    The ultimate understanding of SNe Ia diversity is one of the most urgent issues to exploit thermonuclear explosions of accreted White Dwarfs (WDs) as cosmological yardsticks. In particular, we investigate the impact of the progenitor system metallicity on the physical and chemical properties of the WD at the explosion epoch. We analyze the evolution of CO WDs through the accretion and simmering phases by using evolutionary models based on time-dependent convective mixing and an extended nuclear network including the most important electron captures, beta decays, and URCA processes. We find that, due to URCA processes and electron-captures, the neutron excess and density at which the thermal runaway occurs are substantially larger than previously claimed. Moreover, we find that the higher the progenitor metallicity, the larger the neutron excess variation during the accretion and simmering phases and the higher the central density and the convective velocity at the explosion. Hence, the simmering phase acts as an amplifier of the differences existing in SNe Ia progenitors. When applying our results to the neutron excess estimated for the Tycho and Kepler young supernova remnants, we derive that the metallicity of the progenitors should be in the range Z=0.030{--}0.032, close to the average metallicity value of the thin disk of the Milky Way. As the amount of {}56{Ni} produced in the explosion depends on the neutron excess and central density at the thermal runaway, our results suggest that the light curve properties depend on the progenitor metallicity.

  5. On Measuring the Metallicity of Supernovae Type Ia Progenitors

    CERN Document Server

    Miles, Broxton J; Townsley, Dean M; Timmes, F X; Jackson, Aaron P; Calder, Alan C; Brown, Edward F

    2015-01-01

    In Type Ia Supernovae (\\sneia), the relative abundances of chemical elements are affected by the neutron excess in the composition of the progenitor white dwarf. Since these products leave signatures in the spectra near maximum light, spectral features may be used to constrain the composition of the progenitor. We calculate the nucleosynthetic yields for three \\snia simulations for a wide range of progenitor metallicities, and calculate synthetic light curves and spectra to explore correlations between progenitor metallicity and the strength of spectral features. We use two 2D simulations of the deflagration-detonation-transition scenario with different $^{56}$Ni yields and the W7 simulation to control for differences between explosion models and total yields. While the overall yields of intermediate mass elements (16 $<$ A $\\leq$ 40) differ between the three cases, trends in the yields are similar. With increasing metallicity, $^{28}$Si yields remain nearly constant, $^{40}$Ca yields decline, and Ti and $...

  6. Type Ia and II supernovae contributions to the metal enrichment in intra-cluster medium observed with Suzaku

    CERN Document Server

    Sato, Kosuke; Matsushita, Kyoko; Ishisaki, Yoshitaka; Yamasaki, Noriko Y; Ishida, Manabu; Ohashi, Takaya

    2007-01-01

    We studied the properties of the intra-cluster medium (ICM) in two clusters of galaxies (AWM 7 and Abell 1060) and two groups (HCG 62 and NGC 507) with the X-ray Observatory Suzaku. Based on spatially resolved energy spectra, we measured for the first time precise cumulative ICM metal masses within 0.1 and ~0.3 r_{180}. Comparing our results with supernova nucleosynthesis models, the number ratio of type II (SNe II) to type Ia (SNe Ia) is estimated to be ~3.5, assuming the metal mass in the ICM is represented by the sum of products synthesized in SNe Ia and SNe II. Normalized by the K-band luminosities of present galaxies, and including the metals in stars, the integrated number of past SNe II explosions is estimated to be close to or somewhat higher than the star formation rate determined from Hubble Deep Field observations.

  7. Grouping Normal Type Ia Supernovae by UV to Optical Color Differences

    CERN Document Server

    Milne, Peter A; Roming, Peter W A; Bufano, Filomena; Gehrels, Neil

    2013-01-01

    Observations of many SNe Ia with the UVOT instrument on the Swift satellite has revealed that there exists order to the differences in the UV-OPT colors of normal SNe. We examine UV-OPT color curves for 25 SNe Ia, dividing them into 4 groups, finding that ~1/3 of these SNe Ia have bluer UV-OPT colors than the larger group, with these "NUV-blue" SNe Ia 0.4 mag bluer than the "NUV-red" SNe Ia in u-v. Another group of events feature colors similar to NUV-red SNe Ia in the u-v to uvw1-v colors, but similar to the NUV-blue SNe Ia in the uvm2-v color. We name these events "MUV-blue". The last group initially has colors similar to NUV-red SNe Ia, but with color curves that feature more modest changes than the larger NUV-red group. These "irregular" events are comprised of all the NUV-red events with the broadest optical peaks, which leads us to consider this minor group a subset of the NUV-red group. When so separated and the accounting is made for the rapid time evolution of the UV-OPT colors, we find that the scat...

  8. ON THE DEPENDENCE OF TYPE Ia SNe LUMINOSITIES ON THE METALLICITY OF THEIR HOST GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Moreno-Raya, Manuel E.; Mollá, Mercedes [Dpto.de Investigación Básica, C.I.E.M.A.T., Avda. Complutense 40, E-28040 Madrid (Spain); López-Sánchez, Ángel R. [Australian Astronomical Observatory, P.O. Box 915, North Ryde, NSW 1670 (Australia); Galbany, Lluís [Millennium Institute of Astrophysics MAS, Nuncio Monseñor Sótero Sanz 100, Providencia, 7500011 Santiago (Chile); Vílchez, José Manuel [Instituto de Astrofísica de Andalucía (CSIC), Apdo. 3004, E-18080 Granada (Spain); Rosell, Aurelio Carnero [Observatório Nacional, and LIneA Laboratório Interinstitucional de e-Astronomia, Rua Gal. José Cristino 77 Rio de Janeiro, RJ 20921-400 (Brazil); Domínguez, Inmaculada, E-mail: manuelemilio.moreno@ciemat.es [Departamento de Física Teórica y del Cosmos, Universidad de Granada, E-18071 Granada (Spain)

    2016-02-10

    The metallicity of the progenitor system producing a type Ia supernova (SN Ia) could play a role in its maximum luminosity, as suggested by theoretical predictions. We present an observational study to investigate if such a relationship exists. Using the 4.2 m William Herschel Telescope (WHT) we have obtained intermediate-resolution spectroscopy data of a sample of 28 local galaxies hosting SNe Ia, for which distances have been derived using methods independent of those based on SN Ia parameters. From the emission lines observed in their optical spectra, we derived the gas-phase oxygen abundance in the region where each SN Ia exploded. Our data show a trend, with an 80% of chance not being due to random fluctuation, between SNe Ia absolute magnitudes and the oxygen abundances of the host galaxies, in the sense that luminosities tend to be higher for galaxies with lower metallicities. This result seems likely to be in agreement with both the theoretically expected behavior and with other observational results. This dependence M{sub B}–Z might induce systematic errors when it is not considered when deriving SNe Ia luminosities and then using them to derive cosmological distances.

  9. EnviroAtlas - Des Moines, IA - Ecosystem Services by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset presents environmental benefits of the urban forest in 312 block groups in Des Moines, IA. Carbon attributes, temperature reduction,...

  10. Grouping normal type Ia supernovae by UV to optical color differences

    Energy Technology Data Exchange (ETDEWEB)

    Milne, Peter A. [University of Arizona, Steward Observatory, 933 North Cherry Avenue, Tucson, AZ 85719 (United States); Brown, Peter J. [George P. and Cynthia Woods Mitchell Institute for Fundamental Physics and Astronomy, Texas A. and M. University, Department of Physics and Astronomy, 4242 TAMU, College Station, TX 77843 (United States); Roming, Peter W. A. [Space Science and Engineering Division, Southwest Research Corporation, P.O. Drawer 28510, San Antonio, TX 78228-0510 (United States); Bufano, Filomena [Universidad Andres Bello, Departmento de Cincias Fisicas, Avda. Republica 220, Santiago (Chile); Gehrels, Neil, E-mail: pbrown@physics.tamu.edu [NASA-Goddard Space Flight Center, Astrophysics Science Division, Codes 660.1 and 662, Greenbelt, MD 20771 (United States)

    2013-12-10

    Observations of many Type Ia supernovae (SNe Ia) for multiple epochs per object with the Swift Ultraviolet Optical Telescope instrument have revealed that there exists order to the differences in the UV-optical colors of optically normal supernovae (SNe). We examine UV-optical color curves for 23 SNe Ia, dividing the SNe into four groups, and find that roughly one-third of 'NUV-blue' SNe Ia have bluer UV-optical colors than the larger 'NUV-red' group. Two minor groups are recognized, 'MUV-blue' and 'irregular' SNe Ia. While we conclude that the latter group is a subset of the NUV-red group, containing the SNe with the broadest optical peaks, we conclude that the 'MUV-blue' group is a distinct group. Separating into the groups and accounting for the time evolution of the UV-optical colors lowers the scatter in two NUV-optical colors (e.g., u – v and uvw1 – v) to the level of the scatter in b – v. This finding is promising for extending the cosmological utilization of SNe Ia into the NUV. We generate spectrophotometry of 33 SNe Ia and determine the correct grouping for each. We argue that there is a fundamental spectral difference in the 2900-3500 Å wavelength range, a region suggested to be dominated by absorption from iron-peak elements. The NUV-blue SNe Ia feature less absorption than the NUV-red SNe Ia. We show that all NUV-blue SNe Ia in this sample also show evidence of unburned carbon in optical spectra, whereas only one NUV-red SN Ia features that absorption line. Every NUV-blue event also exhibits a low gradient of the Si II λ6355 absorption feature. Many NUV-red events also exhibit a low gradient, perhaps suggestive that NUV-blue events are a subset of the larger low-velocity gradient group.

  11. On the dependence of the type Ia SNe luminosities on the metallicity of their host galaxies

    CERN Document Server

    Moreno-Raya, Manuel E; López-Sánchez, Ángel R; Galbany, Lluís; Vílchez, José; Carnero, Aurelio; Domínguez, Inma

    2015-01-01

    The metallicity of the progenitor system producing a type Ia supernova (SN Ia) could play a role in its maximum luminosity, as suggested by theoretical predictions. We present an observational study to investigate if such a relationship there exists. Using the 4.2m WHT we have obtained intermediate-resolution spectroscopy data of a sample of 28 local galaxies hosting SNe Ia, for which distances have been derived using methods independent to those based on the own SN Ia parameters. From the emission lines observed in their optical spectrum, we derived the gas-phase oxygen abundance in the region where each SN Ia exploded. Our data show a trend, with a 80% of chance not to be due to random fluctuation, between SNe Ia absolute magnitudes and the oxygen abundances of the host galaxies, in the sense that luminosities tend to be higher for galaxies with lower metallicities. This result seems like to be in agreement with both the theoretically expected behavior, and with other observational results. This dependence ...

  12. METALLICITY DIFFERENCES IN TYPE Ia SUPERNOVA PROGENITORS INFERRED FROM ULTRAVIOLET SPECTRA

    Energy Technology Data Exchange (ETDEWEB)

    Foley, Ryan J.; Kirshner, Robert P. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2013-05-20

    Two ''twin'' Type Ia supernovae (SNe Ia), SNe 2011by and 2011fe, have extremely similar optical light-curve shapes, colors, and spectra, yet have different ultraviolet (UV) continua as measured in Hubble Space Telescope spectra and measurably different peak luminosities. We attribute the difference in the UV continua to significantly different progenitor metallicities. This is the first robust detection of different metallicities for SN Ia progenitors. Theoretical reasoning suggests that differences in metallicity also lead to differences in luminosity. SNe Ia with higher progenitor metallicities have lower {sup 56}Ni yields and lower luminosities for the same light-curve shape. SNe 2011by and 2011fe have different peak luminosities ({Delta}M{sub V} Almost-Equal-To 0.6 mag), which correspond to different {sup 56}Ni yields: M{sub 11fe}({sup 56}Ni) / M{sub 11by}({sup 56}Ni) = 1.7{sup +0.7}{sub -0.5}. From theoretical models that account for different neutron-to-proton ratios in progenitors, the differences in {sup 56}Ni yields for SNe 2011by and 2011fe imply that their progenitor stars were above and below solar metallicity, respectively. Although we can distinguish progenitor metallicities in a qualitative way from UV data, the quantitative interpretation in terms of abundances is limited by the present state of theoretical models.

  13. On Measuring the Metallicity of a Type Ia Supernova’s Progenitor

    Science.gov (United States)

    Miles, Broxton J.; van Rossum, Daniel R.; Townsley, Dean M.; Timmes, F. X.; Jackson, Aaron P.; Calder, Alan C.; Brown, Edward F.

    2016-06-01

    In Type Ia Supernovae (SNe Ia) the relative abundances of chemical elements are affected by the neutron excess in the composition of the progenitor white dwarf. Since these products leave signatures in the spectra near maximum light, spectral features may be used to constrain the composition of the progenitor. We calculate the nucleosynthetic yields for three SN Ia simulations, assuming single degenerate, Chandrasekhar-mass progenitors, for a wide range of progenitor metallicities, and calculate synthetic light curves and spectra to explore correlations between progenitor metallicity and the strength of spectral features. We use two two-dimensional simulations of the deflagration-detonation-transition scenario with different 56Ni yields and the W7 simulation to control for differences between explosion models and total yields. While the overall yields of intermediate-mass elements (16 days post-explosion that appear to deepen with progenitor metallicity: a Ti feature around 4200 Å and an Fe feature around 5200 Å. In all three simulations, their pseudo equivalent widths show a systematic trend with progenitor metallicity. This suggests that these two features may allow for differentiation among progenitor metallicities of observed SNe Ia and potentially help to reduce the intrinsic Hubble scatter.

  14. EnviroAtlas - Woodbine, IA - Ecosystem Services by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset presents environmental benefits of the urban forest in 1 block group in Woodbine, Iowa. Carbon attributes, temperature reduction, pollution...

  15. EnviroAtlas - Woodbine, IA - Park Access by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the block group population that is within and beyond an easy walking distance (500m) of a park entrance. Park entrances were included...

  16. EnviroAtlas - Woodbine, IA - Land Cover by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the percentage of each block group that is classified as impervious, forest, and green space. Forest is combination of trees and...

  17. EnviroAtlas - Des Moines, IA - Demographics by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset is a summary of key demographic groups for the EnviroAtlas community. This dataset was produced by the US EPA to support research and online...

  18. Excitability changes of ankle extensor group Ia and Ib fibers during fictive locomotion in the cat.

    Science.gov (United States)

    Dueñas, S H; Rudomin, P

    1988-01-01

    The present study examines the modulation of gastrocnemius-soleus (GS) monosynaptic reflexes as well as the intraspinal threshold changes of GS group I primary afferent terminals ending in the intermediate and motor nuclei during fictive locomotion in high decerebrate cats. The amplitude of the monosynaptic reflexes (MSR's) evoked in the medial gastrocnemius by stimulation of the lateral gastrocnemius nerve was increased during the extensor (E) phase, decreased during the flexion (F) phase of the step cycle and remained transiently increased after spontaneous episodes of fictive stepping. The intraspinal threshold of populations and of single group Ia GS afferent fibers ending in the motor pool, as well as of single Ia and Ib fibers ending in the intermediate nucleus, showed a sustained reduction during the episodes of fictive locomotion with superimposed cyclic changes in phase with the step cycle. During fictive walking and trotting the reduction of the intraspinal threshold of both Ia and Ib fiber terminals was maximal during the middle or late portion of the F-phase. During fictive gallop elicited by stimulation of the superficial peroneus nerve, the decrease in the intraspinal threshold of the Ia afferent fibers occurred however in phase with the activity of the GS motoneurons. During episodes of fictive locomotion slow, sustained negative DC potential shifts lasting tents of seconds, reflecting an increase in the extracellular potassium concentration were recorded at the base of the dorsal horn and in the intermediate nucleus. The present findings support the existence of tonic and phasic depolarization of the intraspinal terminals of GS group Ia and Ib primary afferents during spontaneous fictive locomotion. It is suggested that accumulation of potassium ions in the extracellular space contributes mainly to the sustained depolarization of group I fibers. The phasic depolarization would be mostly due to the activation of specific sets of interneurons and may

  19. Grouped exposed metal heaters

    Energy Technology Data Exchange (ETDEWEB)

    Vinegar, Harold J [Bellaire, TX; Coit, William George [Bellaire, TX; Griffin, Peter Terry [Brixham, GB; Hamilton, Paul Taylor [Houston, TX; Hsu, Chia-Fu [Granada Hills, CA; Mason, Stanley Leroy [Allen, TX; Samuel, Allan James [Kular Lumpar, ML; Watkins, Ronnie Wade [Cypress, TX

    2012-07-31

    A system for treating a hydrocarbon containing formation is described. The system includes two or more groups of elongated heaters. The group includes two or more heaters placed in two or more openings in the formation. The heaters in the group are electrically coupled below the surface of the formation. The openings include at least partially uncased wellbores in a hydrocarbon layer of the formation. The groups are electrically configured such that current flow through the formation between at least two groups is inhibited. The heaters are configured to provide heat to the formation.

  20. Grouped exposed metal heaters

    Energy Technology Data Exchange (ETDEWEB)

    Vinegar, Harold J. (Bellaire, TX); Coit, William George (Bellaire, TX); Griffin, Peter Terry (Brixham, GB); Hamilton, Paul Taylor (Houston, TX); Hsu, Chia-Fu (Granada Hills, CA); Mason, Stanley Leroy (Allen, TX); Samuel, Allan James (Kular Lumpar, MY); Watkins, Ronnie Wade (Cypress, TX)

    2010-11-09

    A system for treating a hydrocarbon containing formation is described. The system includes two or more groups of elongated heaters. The group includes two or more heaters placed in two or more openings in the formation. The heaters in the group are electrically coupled below the surface of the formation. The openings include at least partially uncased wellbores in a hydrocarbon layer of the formation. The groups are electrically configured such that current flow through the formation between at least two groups is inhibited. The heaters are configured to provide heat to the formation.

  1. Group Ia afferents contribute to short-latency interlimb reflexes in the human biceps femoris muscle

    DEFF Research Database (Denmark)

    Stevenson, Andrew James Thomas; Kamavuako, Ernest Nlandu; Geertsen, Svend Sparre

    2017-01-01

    and velocity of the iKnee rotations. Methods 11 seated participants (mean age: 25 ± 5 years) performed a voluntary isometric knee extension with the ipsilateral leg and contralateral knee flexion to 10% of maximum voluntary contraction (MVC). A mechanical actuator (MTS-Systems Corporation) imposed i...... amplitudes (4 vs. 8°) at the same 150°/s velocity (p’s > 0.08). Conclusion Because fast conducting group Ia muscle spindle afferents are sensitive to changes in muscle stretch velocity, while group II spindle afferents are sensitive to changes in amplitude (Grey et al., JPhysiol., 2001; Matthews, Trends...... Neurosci., 1991), group Ia velocity sensitive muscle spindle afferents likely contribute to the short-latency crossed spinal reflexes in the cBF muscle following iKnee joint rotations. This supports the findings for the short-latency crossed responses in the human soleus muscle (Stubbs & Mrachacz...

  2. The effect of progenitor age and metallicity on luminosity and 56Ni yield in Type Ia supernovae

    CERN Document Server

    Howell, D A; Brown, E F; Conley, A; Le Borgne, D; Hsiao, E Y; Astier, Pierre; Balam, D; Balland, C; Basa, S; Carlberg, R G; Fouchez, D; Guy, J; Hardin, D; Hook, I M; Pain, R; Perrett, K; Pritchet, C J; Regnault, N; Baumont, S; Du, J Le; Lidman, C; Perlmutter, S; Suzuki, N; Walker, E S; Wheeler, J C

    2008-01-01

    Timmes, Brown & Truran found that metallicity variations could theoretically account for a 25% variation in the mass of 56Ni synthesized in Type Ia supernovae (SNe Ia), and thus account for a large fraction of the scatter in observed SN Ia luminosities. Higher-metallicity progenitors are more neutron-rich, producing more stable burning products relative to radioactive 56Ni. We develop a new method for estimating bolometric luminosity and 56Ni yield in SNe Ia and use it to test the theory with data from the Supernova Legacy Survey. We find that the average 56Ni yield does drop in SNe Ia from high metallicity environments, but the theory can only account for 7%--10% of the dispersion in SN Ia 56Ni mass, and thus luminosity. This is because the effect is dominant at metallicities significantly above solar, whereas we find that SN hosts have predominantly subsolar or only moderately above-solar metallicities. We also show that allowing for changes in O/Fe with the metallicity [Fe/H] does not have a major effe...

  3. Platinum Group Metals New Material

    Institute of Scientific and Technical Information of China (English)

    XIE Ming; ZHANG Jiankang; WANG Saibei; HU Jieqiong; LIU Manmen; CHEN Yongtai; ZHANG Jiming; YANG Youcai; YANG Yunfeng; ZHANG Guoquan

    2012-01-01

    Platinum group metals (PGM) include six elements,namely Pt,Pd,Rh,Ir,Os and Ru.PGM and their alloys are the important fundamental materials for modern industry and national defense construction,they have special physical and chemical properties,widely used in metallurgy,chemical,electric,electronic,information,energy,environmental protection,aviation,aerospace,navigation and other high technology industry.Platinum group metals and their alloys,which have good plasticity and processability,can be processed to electrical contact materials,resistance materials,solder,electronic paste,temperature-measurement materials,elastic materials,magnetic materials and high temperature structural materials.

  4. [Fruit consumption in a group of teenagers from Iaşi].

    Science.gov (United States)

    Albul, Adriana; Rada, Cornelia; Albu, M; Indrei, L L

    2009-01-01

    A goal for the national nutritional education program is represented by the increase of fruit consumption. Using specially designed questionaries a group of 127 teenagers from two different Iaşi high schools provided date related to thei daily fruit intake. Almost 40% of the teenagers use fresh fruits as part of their breakfast and a greater number use them as snacks (57.5%) or dessert (80.5%), with statistically insignificant differences between the two high schools. The fruit intake is adequate in the studied group and the programs that promote certain food habits must take into account the existing situation.

  5. Constraining the Single-degenerate Channel of Type Ia Supernovae with Stable Iron-group Elements in SNR 3C 397

    Science.gov (United States)

    Dave, Pranav; Kashyap, Rahul; Fisher, Robert; Timmes, Frank; Townsley, Dean; Byrohl, Chris

    2017-05-01

    Recent Suzaku X-ray spectra of supernova remnant (SNR) 3C 397 indicate enhanced stable iron group element abundances of Ni, Mn, Cr, and Fe. Seeking to address key questions about the progenitor and explosion mechanism of 3C 397, we compute nucleosynthetic yields from a suite of multidimensional hydrodynamics models in the near-Chandrasekhar-mass, single-degenerate paradigm for Type Ia supernovae (SNe Ia). Varying the progenitor white dwarf (WD) internal structure, composition, ignition, and explosion mechanism, we find that the best match to the observed iron peak elements of 3C 397 are dense (central density ≥6 × 109 g cm-3), low-carbon WDs that undergo a weak, centrally ignited deflagration, followed by a subsequent detonation. The amount of 56Ni produced is consistent with a normal or bright normal SNe Ia. A pure deflagration of a centrally ignited, low central density (≃2 × 109 g cm-3) progenitor WD, frequently considered in the literature, is also found to produce good agreement with 3C 397 nucleosynthetic yields, but leads to a subluminous SN Ia event, in conflict with X-ray line width data. Additionally, in contrast to prior work that suggested a large supersolar metallicity for the WD progenitor for SNR 3C 397, we find satisfactory agreement for solar- and subsolar-metallicity progenitors. We discuss a range of implications our results have for the single-degenerate channel.

  6. Constraining anisotropy of the universe from different groups of type-Ia supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Zhe; Li, Xin [Chinese Academy of Sciences, Institute of High Energy Physics, Beijing (China); Chinese Academy of Sciences, Theoretical Physics Center for Science Facilities, Beijing (China); Lin, Hai-Nan; Wang, Sai [Chinese Academy of Sciences, Institute of High Energy Physics, Beijing (China)

    2014-03-15

    Recently released Planck data and other astronomical observations show that the universe may be anisotropic on large scales. Inspired by this, anisotropic cosmological models have been proposed. We note that the Finsler-Randers spacetime provides an appropriate framework for the anisotropic cosmology. By adding an arbitrary 1-form to the Friedmann-Robertson-Walker line element, a privileged axis in the universe is picked out. The distance-redshift relation is modified to be direction-dependent. We wish that the anisotropic cosmological model may be tested crossly by independent observations. Type-Ia supernovae (SNe Ia) calibrated from four different light curve fitters are used to constrain the possible anisotropy of the universe. The magnitudes of anisotropy are all between 2-5 %, but the systematic uncertainty cannot be excluded. The directions of the privileged axis seem to differ from each other. The statistical significance is not high enough to make a convincing conclusion. Nevertheless, the 1σ contours in the (l,b) plane obtained from four groups of SNe Ia have an overlap, centering at (l,b) ∼ (170 , 0 ). Monte Carlo simulation shows that the anisotropy is unlikely to be caused by the selection effect. (orig.)

  7. Using the local gas-phase oxygen abundances to explore a metallicity-dependence in SNe Ia luminosities

    CERN Document Server

    Moreno-Raya, M E; Molla, M; Galbany, L; Vilchez, J M; Carnero, A

    2016-01-01

    We present an analysis of the gas-phase oxygen abundances of a sample of 28 galaxies in the local Universe (z < 0.02) hosting Type Ia Supernovae (SNe Ia). The data were obtained with the 4.2m William Herschel Telescope (WHT). We derive local oxygen abundances for the regions where the SNe Ia exploded by calculating oxygen gradients through each galaxy (when possible) or assuming the oxygen abundance of the closest HII region. The sample selection only considered galaxies for which distances not based on the the SN Ia method are available. Then, we use a principal component analysis to study the dependence of the absolute magnitudes on the color of the SN Ia, the oxygen abundances of the region where they exploded, and the stretch of the SN light curve. We demonstrate that our previous result suggesting a metallicity-dependence on the SN Ia luminosity for not-reddened SNe Ia (Moreno-Raya et al. 2016) can be extended to our whole sample. These results reinforce the need of including a metallicity proxy, such...

  8. THE FUNDAMENTAL METALLICITY RELATION REDUCES TYPE Ia SN HUBBLE RESIDUALS MORE THAN HOST MASS ALONE

    Energy Technology Data Exchange (ETDEWEB)

    Hayden, Brian T.; Garnavich, Peter M. [Department of Physics, University of Notre Dame, 225 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Gupta, Ravi R.; Sako, Masao [Department of Physics and Astronomy, University of Pennsylvania, 209 South 33rd Street, Philadelphia, PA 19104 (United States); Mannucci, Filippo [Istituto Nazionale di Astrofisica, Osservatorio Astrofisico di Arcetri, Largo E Fermi 5, I-50125 Firenze (Italy); Nichol, Robert C. [Institute of Cosmology and Gravitation, Portsmouth University, Dennis Sciama Building, Po1 3FX Portsmouth (United Kingdom)

    2013-02-20

    Type Ia supernova Hubble residuals have been shown to correlate with host galaxy mass, imposing a major obstacle for their use in measuring dark energy properties. Here, we calibrate the fundamental metallicity relation (FMR) of Mannucci et al. for host mass and star formation rates measured from broadband colors alone. We apply the FMR to the large number of hosts from the SDSS-II sample of Gupta et al. and find that the scatter in the Hubble residuals is significantly reduced when compared with using only stellar mass (or the mass-metallicity relation) as a fit parameter. Our calibration of the FMR is restricted to only star-forming galaxies and in the Hubble residual calculation we include only hosts with log(SFR) > - 2. Our results strongly suggest that metallicity is the underlying source of the correlation between Hubble residuals and host galaxy mass. Since the FMR is nearly constant between z = 2 and the present, use of the FMR along with light-curve width and color should provide a robust distance measurement method that minimizes systematic errors.

  9. Effects of leg muscle tendon vibration on group Ia and group II reflex responses to stance perturbation in humans

    Science.gov (United States)

    Bove, Marco; Nardone, Antonio; Schieppati, Marco

    2003-01-01

    Stretching the soleus (Sol) muscle during sudden toe-up rotations of the supporting platform in a standing subject evokes a short-latency response (SLR) and a medium-latency response (MLR). The aim of the present investigation was to further explore the afferent and spinal pathways mediating the SLR and MLR in lower limb muscles by means of tendon vibration. In seven subjects, toe-up or toe-down rotations were performed under: (1) control, (2) continuous bilateral vibration at 90 Hz of Achilles' tendon or tibialis anterior (TA) tendon, and (3) post-vibration conditions. Sol and TA background EMG activity and reflex responses were bilaterally recorded and analysed. Toe-up rotations induced SLRs and MLRs in Sol at average latencies of 40 and 66 ms, respectively. During vibration, the latency of both responses increased by about 2 ms. The area of the SLR significantly decreased during vibration, regardless of the underlying background activity, and almost returned to control value post-vibration. The area of Sol MLR was less influenced by vibration than SLR, the reduction being negligible with relatively high background activity. However, contrary to SLR, MLR was even more reduced post-vibration. Toe-down rotations induced no SLR in the TA, while a MLR was evoked at about 81 ms. The area of TA MLR decreased slightly during vibration but much more post-vibration. SLRs and MLRs were differently affected by changing the vibration frequency to 30 Hz: vibration had a negligible effect on the SLR, but still produced a significant effect on the MLR. The independence from the background EMG of the inhibitory effect of vibration upon the SLR suggests that vibration removes a constant amount of the Ia afferent input. This can be accounted for by either presynaptic inhibition of group Ia fibres or a ‘busy-line' phenomenon. The differential effect of vibration on SLRs and MLRs is compatible with the notions that spindle primaries have a higher sensitivity to vibration than

  10. Effects of leg muscle tendon vibration on group Ia and group II reflex responses to stance perturbation in humans.

    Science.gov (United States)

    Bove, Marco; Nardone, Antonio; Schieppati, Marco

    2003-07-15

    Stretching the soleus (Sol) muscle during sudden toe-up rotations of the supporting platform in a standing subject evokes a short-latency response (SLR) and a medium-latency response (MLR). The aim of the present investigation was to further explore the afferent and spinal pathways mediating the SLR and MLR in lower limb muscles by means of tendon vibration. In seven subjects, toe-up or toe-down rotations were performed under: (1) control, (2) continuous bilateral vibration at 90 Hz of Achilles' tendon or tibialis anterior (TA) tendon, and (3) post-vibration conditions. Sol and TA background EMG activity and reflex responses were bilaterally recorded and analysed. Toe-up rotations induced SLRs and MLRs in Sol at average latencies of 40 and 66 ms, respectively. During vibration, the latency of both responses increased by about 2 ms. The area of the SLR significantly decreased during vibration, regardless of the underlying background activity, and almost returned to control value post-vibration. The area of Sol MLR was less influenced by vibration than SLR, the reduction being negligible with relatively high background activity. However, contrary to SLR, MLR was even more reduced post-vibration. Toe-down rotations induced no SLR in the TA, while a MLR was evoked at about 81 ms. The area of TA MLR decreased slightly during vibration but much more post-vibration. SLRs and MLRs were differently affected by changing the vibration frequency to 30 Hz: vibration had a negligible effect on the SLR, but still produced a significant effect on the MLR. The independence from the background EMG of the inhibitory effect of vibration upon the SLR suggests that vibration removes a constant amount of the Ia afferent input. This can be accounted for by either presynaptic inhibition of group Ia fibres or a 'busy-line' phenomenon. The differential effect of vibration on SLRs and MLRs is compatible with the notions that spindle primaries have a higher sensitivity to vibration than

  11. Immobilization induces changes in presynaptic control of group Ia afferents in healthy humans

    DEFF Research Database (Denmark)

    Jensen, Jesper Lundbye; Nielsen, Jens Bo

    2008-01-01

    maximal voluntary plantar- and dorsiflexion torque (MVC) was significantly reduced and the maximal SOL H-reflex amplitude increased with no changes in Mmax. Decreased presynaptic inhibition of the Ia afferents likely contributed to the increase of the H-reflex size, since we observed a significant...

  12. Metallicity of the Fossil Group NGC 1550 Observed with Suzaku

    Science.gov (United States)

    Sato, Kosuke; Kawaharada, Madoka; Nakazawa, Kazuhiro; Matsushita, Kyoko; Ishisaki, Yoshitaka; Yamasaki, Noriko Y.; Ohashi, Takaya

    2010-12-01

    We studied the temperature and metal abundance distributions of the intra-cluster medium (ICM) in a group of galaxies, NGC 1550, observed with Suzaku. NGC 1550 is classified as a fossil group, which has few bright member galaxies, except for the central galaxy. Thus, such a type of galaxy is important to investigate how metals are enriched to the ICM. With the Suzaku XIS instrument, we directly measured not only the Si, S, and Fe lines, but also the O and Mg lines, and obtained those abundances to an outer region of ˜0.5r180 for the first time, and confirmed that the metals in the ICM of such a fossil group are indeed extending to a large radius. We found steeper gradients for the Mg, Si, S, and Fe abundances, while O showed an almost flat abundance distribution. Abundance ratios of α-elements to Fe were similar to those of the other groups and poor clusters. We calculated the number ratio of type II to type Ia supernovae for the ICM enrichment to be 2.9±0.5 within 0.1r180; the value is consistent with those for the other groups and poor clusters observed with Suzaku. We also calculated the metal mass-to-light ratios (MLRs) for Fe, O, and Mg with the B-band and K-band luminosities of the member galaxies of NGC 1550. The derived MLRs are comparable to those of the NGC 5044 group in the r region, while those of NGC 1550 are slightly higher than those of NGC 5044 in the outer region.

  13. Constraining anisotropy of the universe from different groups of type-Ia supernovae

    CERN Document Server

    Chang, Zhe; Lin, Hai-Nan; Wang, Sai

    2014-01-01

    Recent released Planck data and other astronomical observations show that the universe may be anisotropic on large scales. Inspired by this, anisotropic cosmological models have been proposed. We note that the Finsler-Randers spacetime provides an appropriate framework for the anisotropic cosmology. By adding an arbitrary 1-form to the Friedmann-Robertson-Walker (FRW) line element, a privileged axis in the universe is picked out. The distance-redshift relation is modified to be direction-dependent. We wish that the anisotropic cosmological model may be tested crossly by independent observations. Type-Ia supernovae (SNe Ia) calibrated from four different light curve fitters are used to constrain possible anisotropy of the universe. The magnitudes of anisotropy are all between 2% --- 5%, but the systematic uncertainty cannot be excluded. The directions of privileged axis seem to differ from each other. The statistical significance is not high enough to make a convincing conclusion. Nevertheless, the $1\\sigma$ c...

  14. Evolution of 3-9 M(circle dot) Stars for Z = 0.0001--0.03 and Metallicity Effects on Type Ia Supernovae

    CERN Document Server

    Umeda, H; Yamaoka, H; Wanajo, S; Umeda, Hideyuki; Nomoto, Ken'ichi; Yamaoka, Hitoshi; Wanajo, Shinya

    1999-01-01

    Recent observations have revealed that Type Ia supernovae (SNe Ia) are not perfect standard candles but show some variations in their absolute magnitudes, light curve shapes, and spectra. The C/O ratio in the SNe Ia progenitors (C-O white dwarfs) may be related to this variation. However previous works on the stellar evolution do not clearly show how the C/O ratio varies depending on the stellar initial conditions. In this work, we investigate the effects of stellar mass ($M$) and metallicity ($Z$) on the C/O ratio and its distribution in the C-O white dwarfs by calculating stellar evolution from the main-sequence through the end of the second dredge-up for $M=3-9 M_\\odot$ and $Z=0.001-0.03$. We find that the total carbon mass fraction just before SN Ia explosion varies in the range 0.36 -- 0.5. We also calculate the metallicity dependence of the main-sequence-mass range of the SN Ia progenitor white dwarfs. Our results show that the maximum main-sequence mass to form C-O white dwarfs decreases significantly ...

  15. EnviroAtlas - Woodbine, IA - Residents with Potential Window Views of Trees by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the total block group population and the percentage of the block group population that has little access to potential window views of...

  16. EnviroAtlas - Woodbine, IA - Residents with Potential Window Views of Water by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the block group population and the percentage of the block group population that has potential views of water bodies. A potential...

  17. EnviroAtlas - Des Moines, IA - Potential Window Views of Water by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the block group population and the percentage of the block group population that has potential views of water bodies. A potential...

  18. Effects of stimulation of group I afferents from flexor muscles on heterosynaptic facilitation of monosynaptic reflexes produced by Ia and descending inputs: a test for presynaptic inhibition.

    Science.gov (United States)

    Rudomin, P; Jiménez, I; Enriquez, M

    1991-01-01

    1. In the chloralose anesthetized cat, conditioning stimulation of group I flexor afferents depresses the monosynaptic potentials generated by Ia afferents in single spinal motoneurons or in populations of motoneurons without affecting the monosynaptic potentials produced by stimulation of descending fibers in the ipsilateral ventromedial fasciculus (VMF). 2. Heterosynaptic facilitation of monosynaptic reflexes was used to test changes in the presynaptic effectiveness of excitatory inputs with direct connections with motoneurons. We found that the heterosynaptic facilitation of Ia origin was reduced by conditioning stimulation of group I afferents from flexors, without affecting the heterosynaptic facilitation produced by stimulation of the VMF. 3. These results confirm and expand previous observations showing that the synaptic effectiveness of descending fibers synapsing with motoneurons is not subjected to a presynaptic control mechanism of the type acting on Ia fiber terminals, and provide further basis for the use of changes in heterosynaptic facilitation of monosynaptic reflexes of Ia origin as an estimate of changes in presynaptic inhibition of Ia fibers (Hultborn et al. 1987a).

  19. EnviroAtlas - Woodbine, IA - BenMAP Results by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset demonstrates the effect of changes in pollution concentration on local populations in 1 block group in Woodbine, Iowa. The US EPA's...

  20. EnviroAtlas - Woodbine, IA - Greenspace Around Schools by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas data set shows the number of schools in each block group in the EnviroAtlas community boundary as well as the number of schools where less than 25%...

  1. EnviroAtlas - Woodbine, IA - Historic Places by Census Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset portrays the total number of historic places located within each Census Block Group (CBG). The historic places data were compiled from the...

  2. EnviroAtlas - Des Moines, IA - Park Access by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the block group population that is within and beyond an easy walking distance (500m) of a park entrance. Park entrances were included...

  3. EnviroAtlas - Des Moines, IA - Greenspace Around Schools by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas data set shows the number of schools in each block group in the EnviroAtlas community boundary as well as the number of schools where less than 25%...

  4. EnviroAtlas - Des Moines, IA - Historic Places by Census Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset portrays the total number of historic places located within each Census Block Group (CBG). The historic places data were compiled from the...

  5. EnviroAtlas - Des Moines, IA - BenMAP Results by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset demonstrates the effect of changes in pollution concentration on local populations in 312 block groups in Des Moines, Iowa. The US EPA's...

  6. EnviroAtlas - Des Moines, IA - Land Cover by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the percentage of each block group that is classified as impervious, forest, green space, and agriculture. Forest is defined as...

  7. Homochiral helical metal-organic frameworks of group 1 metals.

    Science.gov (United States)

    Reger, Daniel L; Leitner, Andrew; Smith, Mark D; Tran, T Thao; Halasyamani, P Shiv

    2013-09-01

    The reactions of (S)-2-(1,8-naphthalimido)propanoic acid (HL(ala)) and (S)-2-(1,8-naphthalimido)-3-hydroxypropanoic acid (HL(ser)), protonated forms of ligands that contain a carboxylate donor group, an enantiopure chiral center, and a 1,8-naphthalimide π···π stacking supramolecular tecton and in the case of HL(ser) an alcohol functional group, with the appropriate alkali metal hydroxide followed by a variety of crystallization methods leads to the formation of crystalline K(L(ala))(MeOH) (1), K(L(ala))(H2O) (2), Na(L(ala))(H2O) (3), KL(ser) (4), CsL(ser) (5), and CsL(ala) (6). Each of these new complexes has a solid state structure based on six-coordinate metals linked into homochiral helical rod secondary building unit (SBU) central cores. In addition to the bonding of the carboxylate and solvent (in the case of L(ser) the ligand alcohol) to the metals, both oxygens on the 1,8-naphthalimide act as donor groups. One naphthalimide oxygen bonds to the same helical rod SBU as the carboxylate group of that ligand forming a chelate ring. The other naphthalimide oxygen bonds to adjacent SBUs. In complexes 1-3, this inter-rod link has a square arrangement bonding four other rods forming a three-dimensional enantiopure metal-organic framework (MOF) structure, whereas in 4-6 this link has a linear arrangement bonding two other rods forming a two-dimensional, sheet structure. In the latter case, the third dimension is supported exclusively by interdigitated π···π stacking interactions of the naphthalimide supramolecular tecton, forming enantiopure supramolecular MOF solids. Compounds 1-3 lose the coordinated solvent when heating above 100 °C. For 1, the polycrystalline powder reverts to 1 only by recrystallization from methanol, whereas compounds 2 and 3 undergo gas/solid, single-crystal to single-crystal transformations to form dehydrated compounds 2* and 3*, and rehydration occurs when crystals of these new complexes are left out in air. The reversible single

  8. Intrinsic thermoelectric power of group VB metals

    Directory of Open Access Journals (Sweden)

    Gunadhor Singh Okram

    2012-03-01

    Full Text Available We have reinvestigated the thermopower of group VB metals in polycrystalline forms in the temperature range of 6-300K, taking into account the critical nature of the sample surface and heat treatment especially for niobium. Strikingly small magnitude, negative sign, phonon drag dip and superconductivity not reported previously were observed in surface-cleaned single crystalline Nb. However, while thermopower magnitudes are small, mixed signs were found in the polycrystalline V, Nb and Ta samples. These properties were therefore interpreted as their intrinsic properties and were briefly discussed taking into account of the existing theory by fitting also the data that give the Fermi energies of 10.94 eV, 5.08 eV and 1.86eV, respectively.

  9. Selective laser extraction of the Pt group metals

    Energy Technology Data Exchange (ETDEWEB)

    Fadeeva, S.; Krynetsky, B.; Prokhorov, A.; Zhidkov, A. [General Physics Institute, Russian Academy of Science, Moscow (Russian Federation)

    1995-11-15

    The interest to the platinum-group metals extraction from solutions, especially industry waste, is stimulated by their extraordinary chemical inert. The traditional chemical methods of the extraction are uneffective. Have been investigated process of the extraction of metal Pt-group from acid solutions. Discussed processes reduction of noble metals by resonance laser action.

  10. Development of radioactive platinum group metal catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H.S.; Kim, Y.S.; Kim, Y.E. [and others

    1999-03-01

    The fission product nuclides generated during the irradiation of reactor fuel include many useful elements, among them platinum group metals such as ruthenium, rhodium and palladium which are of great industrial importance, occur rarely in nature and are highly valuable. In this research, the authors reviewed various PGM recovery methods. Recovery of palladium from seven-component simulated waste solutions was conducted by selective precipitation method. The recovery yield was more than 99.5% and the purity of the product was more than 99%. Wet-proof catalyst was prepared with the recovered palladium. The specific surface area of the catalyst support was more than 400m{sup 2}/g.The content of palladium impregnated on the support was 1 to 10 wt. %. Hydrogen isotope exchange efficiency of more than 93% to equilibrium with small amount of the catalyst was obtained. It was turned out possible to consider using such palladium or other very low active PGM materials in applications where its activity is unimportant as in nuclear industries. (author). 86 refs., 44 tabs., 88 figs.

  11. Development of radioactive platinum group metal catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H.S.; Kim, Y.S.; Kim, Y.E. [and others

    1999-03-01

    The fission product nuclides generated during the irradiation of reactor fuel include many useful elements, among them platinum group metals such as ruthenium, rhodium and palladium which are of great industrial importance, occur rarely in nature and are highly valuable. In this research, the authors reviewed various PGM recovery methods. Recovery of palladium from seven-component simulated waste solutions was conducted by selective precipitation method. The recovery yield was more than 99.5% and the purity of the product was more than 99%. Wet-proof catalyst was prepared with the recovered palladium. The specific surface area of the catalyst support was more than 400m{sup 2}/g.The content of palladium impregnated on the support was 1 to 10 wt. %. Hydrogen isotope exchange efficiency of more than 93% to equilibrium with small amount of the catalyst was obtained. It was turned out possible to consider using such palladium or other very low active PGM materials in applications where its activity is unimportant as in nuclear industries. (author). 86 refs., 44 tabs., 88 figs.

  12. Signal transmission from motor axons to group Ia muscle spindle afferents: frequency responses and second-order non-linearities.

    Science.gov (United States)

    Windhorst, U; Kokkoroyiannis, T; Laouris, Y; Meyer-Lohmann, J

    1994-03-01

    Spinal recurrent inhibition via Renshaw cells and proprioceptive feedback via skeletal muscle and muscle spindle afferents have been hypothesized to constitute a compound feedback system [Windhorst (1989) Afferent Control of Posture and Locomotion; Windhorst (1993) Robots and Biological Systems--Towards a New Bionics]. To assess their detailed functions, it is necessary to know their dynamic characteristics. Previously we have extensively described the properties of signal transmission from motor axons to Renshaw cells using random motor axon stimulation and data analysis methods based thereupon. Using the same methods, we here compare these properties, in the cat, with those between motor axons and group Ia muscle spindle afferents in terms of frequency responses and nonlinear features. The frequency responses depend on the mean rate (carrier rate) of activation of motor axons and on the strength of coupling between motor units and spindles. In general, they are those of a second-order low-pass system with a cut-off at fairly low frequencies. This contrasts with the dynamics of motor axon-Renshaw cell couplings which are those of a much broader band-pass with its peak in the range of c. 2-15 Hz [Christakos (1987) Neuroscience 23, 613-623]. The second-order non-linearities in motor unit-muscle spindle signal lines are much more diverse than those in motor axon-Renshaw cell couplings. Although the average strength of response declines with mean stimulus rate in both subsystems, there is no systematic relationship between the amount of non-linearity and the average response in the former, whilst there is in the latter. The qualitative appearance of motor unit-muscle spindle non-linearities was complicated as was the average response to motor unit twitches. Thus, whilst Renshaw cells appear to dynamically reflect motor output rather faithfully, muscle spindles seem to signal local muscle fibre length changes and their dynamics. This would be consistent with the

  13. Exhaust system having a gold-platinum group metal catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Ragle, Christie Susan [Havana, IL; Silver, Ronald G [Peoria, IL; Zemskova, Svetlana Mikhailovna [Edelstein, IL; Eckstein, Colleen J [Metamora, IL

    2011-12-06

    A method of providing an exhaust treatment device is disclosed. The method includes applying a catalyst including gold and a platinum group metal to a particulate filter. The concentration of the gold and the platinum group metal is sufficient to enable oxidation of carbon monoxide and nitric oxide.

  14. Concentration of heavy metals in tissues of green turtles (Chelonia mydas sampled in the Cananéia estuary, Brazil

    Directory of Open Access Journals (Sweden)

    Edison Barbieri

    2009-09-01

    Full Text Available Thirty specimens (15 adults and 15 juveniles of Chelonia mydas found in the Cananéia estuary in the state of São Paulo on the southeastern Brazilian coast between January 2005 and September 2006, were analyzed The concentrations of Cd, Cu, Pb, Mn and Ni in liver and kidney samples of adult and juvenile green turtles were determined by Flame Atomic Absorption Spectrophotometry.The average Cd concentration found in adult livers (0.57µg.g-1 was significantly higher than that in juveniles (0.279µg.g-1. Cu concentrations were significantly higher in the liver than in the kidney, and significantly higher in adults (39.9µg.g-1 than in juveniles (20.7µg.g-1 Average Mn concentrations in liver and kidney did not differ between adults (4.32 and 4.17µg.g-1 and juveniles (4.81 and 3.82µg.g-1, whereas Ni concentrations in adults (0.28 and 0.19µg.g-1, respectively were significantly higher than in juveniles (0.13 and 0.089µg.g-1, respectively. Pb concentrations in liver were significantly higher in adults (0.37µg.g-1 than in juveniles (0.06µg.g-1. The concentrations of essential trace elements in Chelonia mydas were generally comparable to values reported in other, similar studies. With respect to non-essential metals (Cd, Pb and Ni, Chelonia mydas presented lower values than those reported for their northern Atlantic counterparts.Analisou-se 30 espécimes (15 adultos e 15 juvenis de Chelonia mydas encontradas no estuário de Cananéia, Estado de São Paulo, região sudeste, durante o período de janeiro de 2005 a setembro de 2006. Foram determinados no fígado e rins de adultos e juvenis de C. mydas os seguintes metais: Cd, Cu, Pb, Mn e Ni, através de Espectrofotometria de Absorção Atômica. Verificou-se que as concentrações médias de Cd no fígado de adultos (0,957µg.g-1 foram significativamente diferentes em relação a dos juvenis (0,279µg.g-1. As concentrações médias de Cu no fígado de C. mydas foram diferentes em relação ao rim

  15. Defining Photometric Peculiar Type Ia Supernovae

    CERN Document Server

    Gonzalez-Gaitan, S; Pignata, G; Forster, F; Gutierrez, C P; Bufano, F; Galbany, L; Folatelli, G; Phillips, M M; Hamuy, M; Anderson, J P; de Jaeger, T

    2014-01-01

    We present a new photometric identification technique for SN 1991bg-like type Ia supernovae (SNe Ia), i.e. objects with light-curve characteristics such as later primary maxima and absence of secondary peak in redder filters. This method is capable of selecting out this sub-group from the normal type Ia population. Furthermore, we find that recently identified peculiar sub-types such as SNe Iax and super-Chandrasekhar SNe Ia have similar photometric characteristics as 91bg-like SNe Ia, namely the absence of secondary maxima and shoulders at longer wavelengths, and can also be classified with our technique. The similarity of these different SN Ia sub-groups perhaps suggests common physical conditions. This typing methodology permits the photometric identification of peculiar SNe Ia in large up-coming wide field surveys either to study them further or to obtain a pure sample of normal SNe Ia for cosmological studies.

  16. Defining photometric peculiar type Ia supernovae

    Energy Technology Data Exchange (ETDEWEB)

    González-Gaitán, S.; Pignata, G.; Förster, F.; Gutiérrez, C. P.; Bufano, F.; Galbany, L.; Hamuy, M.; De Jaeger, T. [Millennium Institute of Astrophysics, Casilla 36-D, Santiago (Chile); Hsiao, E. Y.; Phillips, M. M. [Carnegie Observatories, Las Campanas Observatory, Casilla 601, La Serena (Chile); Folatelli, G. [Kavli Institute for the Physics and Mathematics of the Universe, the University of Tokyo, Kashiwa 277-8583 (Kavli IPMU, WPI) (Japan); Anderson, J. P., E-mail: sgonzale@das.uchile.cl [European Southern Observatory, Alonso de Córdova 3107, Casilla 19, Santiago (Chile)

    2014-11-10

    We present a new photometric identification technique for SN 1991bg-like type Ia supernovae (SNe Ia), i.e., objects with light curve characteristics such as later primary maxima and the absence of a secondary peak in redder filters. This method is capable of selecting this sub-group from the normal type Ia population. Furthermore, we find that recently identified peculiar sub-types such as SNe Iax and super-Chandrasekhar SNe Ia have photometric characteristics similar to 91bg-like SNe Ia, namely, the absence of secondary maxima and shoulders at longer wavelengths, and can also be classified with our technique. The similarity of these different SN Ia sub-groups perhaps suggests common physical conditions. This typing methodology permits the photometric identification of peculiar SNe Ia in large upcoming wide-field surveys either to study them further or to obtain a pure sample of normal SNe Ia for cosmological studies.

  17. Choirs H I galaxy groups: The metallicity of dwarf galaxies

    Energy Technology Data Exchange (ETDEWEB)

    Sweet, Sarah M.; Drinkwater, Michael J. [School of Mathematics and Physics, University of Queensland, Qld 4072 (Australia); Meurer, Gerhardt; Bekki, Kenji [School of Physics, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009 (Australia); Dopita, Michael A.; Nicholls, David C. [Research School of Astronomy and Astrophysics, Australian National University, Cotter Road, Weston ACT 2611 (Australia); Kilborn, Virginia, E-mail: sarah@sarahsweet.com.au [Swinburne University of Technology, Mail number H30, PO Box 218, Hawthorn, Victoria 3122 (Australia)

    2014-02-10

    We present a recalibration of the luminosity-metallicity relation for gas-rich, star-forming dwarfs to magnitudes as faint as M{sub R} ∼ –13. We use the Dopita et al. metallicity calibrations to calibrate the relation for all the data in this analysis. In metallicity-luminosity space, we find two subpopulations within a sample of high-confidence Sloan Digital Sky Survey (SDSS) DR8 star-forming galaxies: 52% are metal-rich giants and 48% are metal-medium galaxies. Metal-rich dwarfs classified as tidal dwarf galaxy (TDG) candidates in the literature are typically of metallicity 12 + log(O/H) = 8.70 ± 0.05, while SDSS dwarfs fainter than M{sub R} = –16 have a mean metallicity of 12 + log(O/H) = 8.28 ± 0.10, regardless of their luminosity, indicating that there is an approximate floor to the metallicity of low-luminosity galaxies. Our hydrodynamical simulations predict that TDGs should have metallicities elevated above the normal luminosity-metallicity relation. Metallicity can therefore be a useful diagnostic for identifying TDG candidate populations in the absence of tidal tails. At magnitudes brighter than M{sub R} ∼ –16, our sample of 53 star-forming galaxies in 9 H I gas-rich groups is consistent with the normal relation defined by the SDSS sample. At fainter magnitudes, there is an increase in dispersion of the metallicity of our sample, suggestive of a wide range of H I content and environment. In our sample, we identify three (16% of dwarfs) strong TDG candidates (12 + log(O/H) > 8.6) and four (21%) very metal-poor dwarfs (12 + log(O/H) < 8.0), which are likely gas-rich dwarfs with recently ignited star formation.

  18. Testing the role of SNe Ia for Galactic chemical evolution of p-nuclei with 2D models and with s-process seeds at different metallicities

    CERN Document Server

    Travaglio, C; Rauscher, T; Ropeke, F K; Hillebrandt, W

    2014-01-01

    The bulk of p isotopes is created in the 'gamma processes' mainly by sequences of photodisintegrations and beta decays in explosive conditions in Type Ia supernovae (SNIa) or in core collapse supernovae (ccSN). The contribution of different stellar sources to the observed distribution of p-nuclei in the Solar System is still under debate. We explore single degenerate Type Ia supernovae in the framework of two-dimensional SNIa delayed-detonation explosion models. Travaglio et al. (2011, TRV11) discussed the sensitivity of p-nuclei production to different SNIa models, i.e. delayed detonations of different strength, deflagrations, and the dependence on selected s-process seed distributions. Here we present a detailed study of p-process nucleosynthesis occuring in SNIa with s-process seeds at different metallicities. Based on the delayed-detonation model DDT-a of TRV11, we analyze the dependence of p-nucleosynthesis on the s-seed distribution obtained from different strengths of the 13C-pocket. Using a Galactic c...

  19. Reactivity of Metal e B (Boro in the Estuarine System of Cananéia –Iguapé (South Coast of São Paulo, Brazil

    Directory of Open Access Journals (Sweden)

    Vitor Rossi Victor

    2012-12-01

    Full Text Available Dissolved elements reactivity in water column directly influences their chemical and toxic behavior, and in their bioavailability, therefore, in their environmental profile in estuarine systems, important for their great biological productivity and location in zones with potential anthropic impacts. In this context, this study evaluated the behavior of metals (Ba, Fe, Li, Mn and Zn and  the semimetal B throughout the estuarine mixture in the Estuarine System of Cananéia-Iguape. It was observed that B and Li presented conservative behavior as they are not reactive, Ba, Fe and Zn presented not conservative behavior with removal in low salinities, and Mn presented mixed behavior, with addition in low salinities and approximately conservative behavior in high salinities.

  20. PAD and PAH response patterns of group Ia- and Ib-fibers to cutaneous and descending inputs in the cat spinal cord.

    Science.gov (United States)

    Rudomin, P; Solodkin, M; Jiménez, I

    1986-10-01

    The characteristics of the primary afferent depolarization (PAD) of Ia- and Ib-fibers generated by segmental and descending inputs have been analyzed in the spinal cord of anesthetized cats. The PAD was inferred from the changes produced by conditioning inputs on the intraspinal stimulus current required to produce a constant antidromic firing of single group I afferent fibers from the gastrocnemius (GS) or posterior biceps and semitendinosus (PBSt) nerves. Group I GS and PBSt fibers ending in the intermediate nucleus could be classified in three different types according to their PAD patterns in response to stimulation of cutaneous nerves and of descending fibers. In one set of group I fibers stimulation of cutaneous nerves and of the ipsilateral brain stem reticular formation, or the contralateral red nucleus, produced no PAD, but was able to inhibit the PAD generated by stimulation of group I fibers from flexors (type A PAD pattern). PBSt nerve fibers with this PAD pattern had peripheral thresholds and conduction velocities between 1.01 and 1.56 times threshold and 76.3 to 118 m/s, respectively. A second set of group I fibers was found to be depolarized by cutaneous nerves as well as by stimulation of rubrospinal and reticulospinal fibers (type B PAD pattern). The peripheral thresholds and conduction velocities of PBSt afferent fibers with a type B PAD pattern were of 1.66-2.03 times threshold and 71-83 m/s, respectively. We found a third set of group I fibers that were also depolarized by reticulospinal and rubrospinal inputs, but not by cutaneous nerves that instead inhibited the PAD elicited by group I volleys in flexor nerves (type C PAD pattern). All PBSt afferent fibers with a type C PAD pattern, with the exception of two, had peripheral thresholds and velocities between 1.46 and 2.16 times threshold and between 72 and 89 m/s, respectively. Stimulation of the Deiter's nucleus was found to depolarize the intraspinal terminals of a small fraction of group I

  1. [Congenital disorder of glycosylation type Ia (CDG Ia) - underdiagnosed entity?].

    Science.gov (United States)

    Sätilä, Heli; Kuusela, Anna-Leena; Pietilä, Kati; Niinikoski, Harri; Keskinen, Päivi

    2016-01-01

    Congenital disorders of glycosylation (CDG) are a relatively recently identified group of multisystem disorders caused by defective glycosylation of N-glycosylated proteins. They mainly involve the central and peripheral nervous system, but other organ systems are involved as well. Type CDG Ia accounts for over 80% of cases, characterized by decreased activity of the enzyme phosphomannomutase caused by mutations in chromosome 16 PMM2 gene. Treatment of CDG Ia remains symptomatic.

  2. EnviroAtlas - Des Moines, IA - Residents with Minimal Potential Window Views of Trees by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the total block group population and the percentage of the block group population that has little access to potential window views of...

  3. The Number of Positive Pelvic Lymph Nodes and Multiple Groups of Pelvic Lymph Node Metastasis Influence Prognosis in Stage IA-IIB Cervical Squamous Cell Carcinoma

    Directory of Open Access Journals (Sweden)

    Yu Liu

    2015-01-01

    Full Text Available Background: Pelvic lymph node metastasis (LNM is an important prognostic factor in cervical cancer. Cervical squamous cell carcinoma accounts for approximately 75-80% of all cervical cancers. Analyses of the effects of the number of positive lymph nodes (LNs, unilateral versus bilateral pelvic LNM and a single group versus multiple groups of pelvic LNM on survival and recurrence of cervical squamous cell carcinoma are still lacking. The study aimed to analyze the effects of the number of positive pelvic LNs and a single group versus multiple groups of pelvic LNM on survival and recurrence. Methods: We performed a retrospective review of 296 patients diagnosed with Stage IA-IIB cervical squamous cell carcinoma who received extensive/sub-extensive hysterectomy with pelvic lymphadenectomy/pelvic LN sampling at Peking University People′s Hospital from November 2004 to July 2013. Ten clinicopathological variables were evaluated as risk factors for pelvic LNM: Age at diagnosis, gravidity, clinical stage, histological grade, tumor diameter, lymph-vascular space involvement (LVSI, depth of cervical stromal invasion, uterine invasion, parametrial invasion, and neoadjuvant chemotherapy. Results: The incidence of pelvic LNM was 20.27% (60/296 cases. Pelvic LNM (P = 0.00 was significantly correlated with recurrence. Pelvic LNM (P = 0.00, the number of positive pelvic LNs (P = 0.04 and a single group versus multiple groups of pelvic LNM (P = 0.03 had a significant influence on survival. Multivariate analysis revealed that LVSI (P = 0.00, depth of cervical stromal invasion (P = 0.00 and parametrial invasion (P = 0.03 were independently associated with pelvic LNM. Conclusions: Patients with pelvic LNM had a higher recurrence rate and poor survival outcomes. Furthermore, more than 2 positive pelvic LNs and multiple groups of pelvic LNM appeared to identify patients with worse survival outcomes in node-positive IA-IIB cervical squamous cell carcinoma. LVSI

  4. Recent strikes in South Africa’s platinum-group metal mines: effects upon world platinum-group metal supplies

    Science.gov (United States)

    Yager, Thomas R.; Soto-Viruet, Yadira; Barry, James J.

    2012-01-01

    The recent labor disputes over wages and working conditions that have affected South Africa’s three leading platinum-group metal (PGM) producers have affected an industry already plagued by market pressures and labor unrest and raised the specter of constraints in the world’s supply of these metals. Although low demand for these metals in 2011 and 2012 helped to offset production losses of recent years, and particularly those losses caused by the strikes in 2012, a prolonged resumption of strikes could cause severe shortages of iridium, platinum, rhodium, ruthenium, and, to a lesser extent, palladium.

  5. TESTING THE ROLE OF SNe Ia FOR GALACTIC CHEMICAL EVOLUTION OF p-NUCLEI WITH TWO-DIMENSIONAL MODELS AND WITH s-PROCESS SEEDS AT DIFFERENT METALLICITIES

    Energy Technology Data Exchange (ETDEWEB)

    Travaglio, C. [INAF, Astrophysical Observatory Turin, Strada Osservatorio 20, I-10025 Pino Torinese (Turin), Italy B2FH Association, Turin (Italy); Gallino, R. [Dipartimento di Fisica, Università di Torino, Via P. Giuria 1, I-10125 Turin (Italy); Rauscher, T. [Centre for Astrophysics Research, School of Physics, Astronomy and Mathematics, University of Hertfordshire, Hatfield AL10 9AB (United Kingdom); Röpke, F. K. [Universität Würzburg, Am Hubland, D-97074 Würzburg (Germany); Hillebrandt, W., E-mail: travaglio@oato.inaf.it, E-mail: claudia.travaglio@b2fh.org [Max-Planck-Institut für Astrophysik, Karl-Schwarzschild-Str. 1, D-85748 Garching bei München (Germany)

    2015-01-20

    The bulk of p isotopes is created in the ''gamma processes'' mainly by sequences of photodisintegrations and beta decays in explosive conditions in Type Ia supernovae (SNIa) or in core collapse supernovae (ccSN). The contribution of different stellar sources to the observed distribution of p-nuclei in the solar system is still under debate. We explore single degenerate Type Ia supernovae in the framework of two-dimensional SNIa delayed-detonation explosion models. Travaglio et al. discussed the sensitivity of p-nuclei production to different SNIa models, i.e., delayed detonations of different strength, deflagrations, and the dependence on selected s-process seed distributions. Here we present a detailed study of p-process nucleosynthesis occurring in SNIa with s-process seeds at different metallicities. Based on the delayed-detonation model DDT-a of TRV11, we analyze the dependence of p-nucleosynthesis on the s-seed distribution obtained from different strengths of the {sup 13}C pocket. We also demonstrate that {sup 208}Pb seed alone changes the p-nuclei production considerably. The heavy-s seeds (140 ≤A < 208) contribute with about 30%-40% to the total light-p nuclei production up to {sup 132}Ba (with the exception of {sup 94}Mo and {sup 130}Ba, to which the heavy-s seeds contribute with about 15% only). Using a Galactic chemical evolution code from Travaglio et al., we study the contribution of SNIa to the solar stable p-nuclei. We find that explosions of Chandrasekhar-mass single degenerate systems produce a large amount of p-nuclei in our Galaxy, both in the range of light (A ≤ 120) and heavy p-nuclei, at almost flat average production factors (within a factor of about three). We discussed in details p-isotopes such as {sup 94}Mo with a behavior diverging from the average, which we attribute to uncertainties in the nuclear data or in SNIa modeling. Li et al. find that about 70% of all SNeIa are normal events. If these are explained in

  6. Keck Observations of the Young Metal-Poor Host Galaxy of the Super-Chandrasekhar-Mass Type Ia Supernova SN 2007if

    CERN Document Server

    Childress, M; Aragon, C; Antilogus, P; Bailey, S; Baltay, C; Bongard, S; Buton, C; Canto, A; Chotard, N; Copin, Y; Fakhouri, H K; Gangler, E; Kerschhaggl, M; Kowalski, M; Hsiao, E Y; Loken, S; Nugent, P; Paech, K; Pain, R; Pecontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Runge, K; Scalzo, R; Thomas, R C; Smadja, G; Tao, C; Weaver, B A; Wu, C

    2011-01-01

    We present Keck LRIS spectroscopy and $g$-band photometry of the metal-poor, low-luminosity host galaxy of the super-Chandrasekhar mass Type Ia supernova SN 2007if. Deep imaging of the host reveals its apparent magnitude to be $m_g=23.15\\pm0.06$, which at the spectroscopically-measured redshift of $z_{helio}=0.07450\\pm0.00015$ corresponds to an absolute magnitude of $M_g=-14.45\\pm0.06$. Galaxy $g-r$ color constrains the mass-to-light ratio, giving a host stellar mass estimate of $\\log(M_*/M_\\odot)=7.32\\pm0.17$. Balmer absorption in the stellar continuum, along with the strength of the 4000\\AA\\ break, constrain the age of the dominant starburst in the galaxy to be $t_\\mathrm{burst}=123^{+165}_{-77}$ Myr, corresponding to a main-sequence turn-off mass of $M/M_\\odot=4.6^{+2.6}_{-1.4}$. Using the R$_{23}$ method of calculating metallicity from the fluxes of strong emission lines, we determine the host oxygen abundance to be $12+\\log(O/H)_\\mathrm{KK04}=8.01\\pm0.09$, significantly lower than any previously reported...

  7. Cervical Cancer Stage IA

    Science.gov (United States)

    ... hyphen, e.g. -historical Searches are case-insensitive Cervical Cancer Stage IA Add to My Pictures View /Download : ... 1500x1200 View Download Large: 3000x2400 View Download Title: Cervical Cancer Stage IA Description: Stage IA1 and IA2 cervical ...

  8. Dipicolinate complexes of main group metals with hydrazinium cation

    Indian Academy of Sciences (India)

    K Saravanan; S Govindarajan

    2002-02-01

    Some new coordination complexes of hydrazinium main group metal dipicolinate hydrates of formulae (N2H5)2M(dip)2.H2O (where, M =Ca, Sr, Ba or Pb and = 0, 2, 4 and 3 respectively and dip = dipicolinate), N2H5Bi(dip)2.3H2O and (N2H5)3Bi(dip)3.4H2O have been prepared and characterized by physico-chemical techniques. The infrared spectra of the complexes reveal the presence of tridentate dipicolinate dianions and non-coordinating hydrazinium cations. Conductance measurements show that the mono, di and trihydrazinium complexes behave as 1:1, 2:1 and 3:1 electrolytes respectively, in aqueous solution. Thermal decomposition studies show that these compounds lose water followed by endothermic decomposition of hydrazine to give respective metal hydrogendipicolinate intermediates, which further decompose exothermically to the final product of either metal carbonates (Ca, Sr, Ba and Pb) or metal oxycarbonates (Bi). The coordination numbers around the metal ions differ from compound to compound. The various coordination numbers exhibited by these metals are six (Ca), seven (Ba), eight (Sr) and nine (Pb and Bi). In all the complexes the above coordination number is attained by tridentate dipicolinate dianions and water molecules. The X-ray diffraction patterns of these compounds differ from one another suggesting that they are not isomorphous.

  9. Effect of Platinum Group Metal Doping in Magnesium Diboride Wires

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Alexiou, Aikaterini; Namazkar, Shahla

    2016-01-01

    The effect of some platinum group metals(PGM = Rh, Pd, and Pt) on the microstructure and critical current density of Cu/Nb-sheathed MgB2 wires has been studied using Mg1-x PGMxB2 powders with low doping levels. It was found that Pt and Pd do not enter the MgB2 lattice and have only limited....... The results are discussed in comparison with previous investigations using other transition metals for doping on the Mg site....

  10. Chemical Reactivity Perspective into the Group 2B Metals Halides.

    Science.gov (United States)

    Özen, Alimet Sema; Akdeniz, Zehra

    2016-06-30

    Chemical reactivity descriptors within the conceptual density functional theory can be used to understand the nature of the interactions between two monomers of the Group 2B metal halides. This information might be valuable in the development of adequate force law parameters for simulations in the liquid state. In this study, MX2 monomers and dimers, where M = Zn, Cd, Hg and X = F, Cl, Br, I, were investigated in terms of chemical reactivity descriptors. Relativistic effects were taken into account using the effective core potential (ECP) approach. Correlations were produced between global and local reactivity descriptors and dimerization energies. Results presented in this work represent the first systematic investigation of Group 2B metal halides in the literature from a combined point of view of both relativistic effects and chemical reactivity descriptors. Steric effects were found to be responsible for the deviation from the chemical reactivity principles. They were introduced into the chemical reactivity descriptors such as local softness.

  11. Platinum group metal nitrides and carbides: synthesis, properties and simulation

    Energy Technology Data Exchange (ETDEWEB)

    Ivanovskii, Alexander L [Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg (Russian Federation)

    2009-04-30

    Experimental and theoretical data on new compounds, nitrides and carbides of the platinum group 4d and 5d metals (ruthenium, rhodium, palladium, osmium, iridium, platinum), published over the past five years are summarized. The extreme mechanical properties of platinoid nitrides and carbides, i.e., their high strength and low compressibility, are noted. The prospects of further studies and the scope of application of these compounds are discussed.

  12. Zwitterionic Group VIII transition metal initiators supported by olefin ligands

    Science.gov (United States)

    Bazan, Guillermo C.; Chen, Yaofeng

    2011-10-25

    A zwitterionic Group VIII transition metal complex containing the simple and relatively small 3-(arylimino)-but-1-en-2-olato ligand that catalyzes the formation of polypropylene and high molecular weight polyethylene. A novel feature of this catalyst is that the active species is stabilized by a chelated olefin adduct. The present invention also provides methods of polymerizing olefin monomers using zwitterionic catalysts, particularly polypropylene and high molecular weight polyethylene.

  13. Mineral resource of the month: platinum group metals

    Science.gov (United States)

    Loferski, Patricia J.

    2010-01-01

    The article focuses on platinum group metals (PGMs) and their properties. According to the author, PGMs, which include iridium, osmium, palladium, platinum, rhodium, and ruthenium, are among the rarest mineral commodities in the Earth's crust. PGMs are primarily used as catalytic converters that clean harmful exhaust from vehicle engines. They are also used in the chemical industry as catalysts in the production of nitric acid and in the petroleum refining industry.

  14. The anti-inflammatory activity of standard aqueous stem bark extract of Mangifera indica L. as evident in inhibition of Group IA sPLA2.

    Science.gov (United States)

    Dhananjaya, Bhadrapura Lakkappa; Shivalingaiah, Sudharshan

    2016-03-01

    The standard aqueous stem bark extract is consumed as herbal drink and used in the pharmaceutical formulations to treat patients suffering from various disease conditions in Cuba. This study was carried out to evaluate the modulatory effect of standard aqueous bark extract of M. indica on Group IA sPLA2. M. indica extract, dose dependently inhibited the GIA sPLA2 (NN-XIa-PLA2) activity with an IC50 value 8.1 µg/ml. M. indica extract effectively inhibited the indirect hemolytic activity up to 98% at ~40 µg/ml concentration and at various concentrations (0-50 µg/ml), it dose dependently inhibited the edema formation. When examined as a function of increased substrate and calcium concentration, there was no relieve of inhibitory effect on the GIA sPLA2. Furthermore, the inhibition was irreversible as evidenced from binding studies. It is observed that the aqueous extract ofM. indica effectively inhibits sPLA2 and it is associated inflammatory activities, which substantiate their anti-inflammatory properties. The mode of inhibition could be due to direct interaction of components present in the extract, with sPLA2 enzyme. Further studies on understanding the principal constituents, responsible for the anti-inflammatory activity would be interesting to develop this into potent anti-inflammatory agent.

  15. The anti-inflammatory activity of standard aqueous stem bark extract of Mangifera indica L. as evident in inhibition of Group IA sPLA2

    Directory of Open Access Journals (Sweden)

    BHADRAPURA LAKKAPPA DHANANJAYA

    2016-03-01

    Full Text Available ABSTRACT The standard aqueous stem bark extract is consumed as herbal drink and used in the pharmaceutical formulations to treat patients suffering from various disease conditions in Cuba. This study was carried out to evaluate the modulatory effect of standard aqueous bark extract of M. indica on Group IA sPLA2. M. indica extract, dose dependently inhibited the GIA sPLA2 (NN-XIa-PLA2 activity with an IC50 value 8.1 µg/ml. M. indica extract effectively inhibited the indirect hemolytic activity up to 98% at ~40 µg/ml concentration and at various concentrations (0-50 µg/ml, it dose dependently inhibited the edema formation. When examined as a function of increased substrate and calcium concentration, there was no relieve of inhibitory effect on the GIA sPLA2. Furthermore, the inhibition was irreversible as evidenced from binding studies. It is observed that the aqueous extract ofM. indica effectively inhibits sPLA2 and it is associated inflammatory activities, which substantiate their anti-inflammatory properties. The mode of inhibition could be due to direct interaction of components present in the extract, with sPLA2 enzyme. Further studies on understanding the principal constituents, responsible for the anti-inflammatory activity would be interesting to develop this into potent anti-inflammatory agent.

  16. Integrated Assessment of forest bioenergy systems in Mediterranean basin areas: The case of Catalonia and the use of participatory IA-focus groups

    Energy Technology Data Exchange (ETDEWEB)

    Puy, Neus; Tabara, David; Bartroli Almera, Jordi [Institute of Environmental Sciences and Technology (ICTA), Autonomous University of Barcelona, Edifici Cn - Campus de la UAB, 08193 Bellaterra (Cerdanyola del Valles), Barcelona, Catalonia (Spain); Bartroli Molins, Jordi [Department of Chemistry, Autonomous University of Barcelona, Edifici Cn - Campus de la UAB, 08193 Bellaterra (Cerdanyola del Valles), Barcelona, Catalonia (Spain); Rieradevall, Joan [Chemical Engineering Department, Autonomous University of Barcelona, Edifici Cn - Campus de la UAB, 08193 Bellaterra (Cerdanyola del Valles), Barcelona, Catalonia (Spain)

    2008-06-15

    The present paper applies and adapts the methodology of integrated assessment focus groups (IA-FGs) in order to understand and analyse the enhancing factors, as well as the constraints which drive or limit the take-off and development of sustainable forest biomass energy systems in a selected large forested area of the Mediterranean basin. Our study provides both quantitative and qualitative data from Catalonia, Northeast Spain. We provide historical trends in forest expansion; an assessment of technological, socio-economic and ecological options of forest management; and plausible scenarios of its future evolution. Results show that while the opportunities and stakes are high, in Mediterranean countries, specific socio-ecologic factors need to be taken into account if forest biomass is to contribute decisively to securing renewable sources of energy in Europe, integrating landscape planning with resource policies or mitigating climate change. Among these key factors identified are property regimes, low productivity of Mediterranean forests and weak institutional capacity. Other elements such as logistics and supply difficulties and the lack of economic profitability of forest products constitute limitations identified in the implementation of bioenergy systems. Technological solutions alone, while important, are insufficient to ensure a prominent role of Southern Europe forest biomass management in the climate, landscape and sustainability energy policy challenge. (author)

  17. Heavy main-group iodometallates hybridized by alkali metal via 1,10-Phenanthroline-5,6-dione

    Indian Academy of Sciences (India)

    Mengfan Yin; Gengxing Cai; Peng Wang; Xihui Chao; Jibo Liu; Haohong Li; Zhirong Chen

    2015-09-01

    Alkali metals were introduced into heavy main-group iodometallates to get two new IA/IVAheterometallic frameworks [PbI3K(pdon)(H2O)2] (1) and {[Pb3I9K2(pdon)2(H3O)]·H2O} (2) (pdon=1,10-phenanthroline-5,6-dione), which were obtained as single phases by hydrothermal method at different pH values. Compounds 1 and 2 are three-dimensional heterometallic frameworks constructed from the linkage of pdon ligand between iodometallate chains and potassium oxides/iodide clusters. Specially, these two heterometallic frameworks exhibit broadened absorption bands at 700 and 750 nm compared with those of bulk PbI2 and pdon ligand. The band gap of 2 is wider than that of 1, which is due to the absence of · · · interaction in 2. Their thermal stabilities are also discussed.

  18. The Local Hosts of Type Ia Supernovae

    CERN Document Server

    Neill, James D; Howell, D Andy; Conley, Alex; Seibert, Mark; Martin, D Christopher; Barlow, Tom A; Foster, Karl; Friedman, Peter G; Morrissey, Patrick; Neff, Susan G; Schiminovich, David; Wyder, Ted K; Bianchi, Luciana; Donas, José; Heckman, Timothy M; Lee, Young-Wook; Madore, Barry F; Milliard, Bruno; Rich, R Michael; Szalay, A S

    2009-01-01

    We use multi-wavelength, matched aperture, integrated photometry from GALEX, SDSS and the RC3 to estimate the physical properties of 166 nearby galaxies hosting 168 well-observed Type Ia supernovae (SNe Ia). Our data corroborate well-known features that have been seen in other SN Ia samples. Specifically, hosts with active star formation produce brighter and slower SNe Ia on average, and hosts with luminosity-weighted ages older than 1 Gyr produce on average more faint, fast and fewer bright, slow SNe Ia than younger hosts. New results include that in our sample, the faintest and fastest SNe Ia occur only in galaxies exceeding a stellar mass threshhold of ~10^10 M_sun, indicating that their progenitors must arise in populations that are older and/or more metal rich than the general SN Ia population. A low host extinction sub-sample hints at a residual trend in peak luminosity with host age, after correcting for light-curve shape, giving the appearance that older hosts produce less-extincted SNe Ia on average....

  19. Tests of Environmental Effects on SN Ia Production

    Science.gov (United States)

    Strolger, Louis-Gregory; van Dyk, Schuyler; Wolff, Schuyler; Campbell, Lachlan; Sadler, Suzanna; Pease, April

    2011-02-01

    The largely unknown type Ia supernova mechanism remains one of the largest sources of possible systematic uncertainty in achieving precise measures of dark energy. The host galaxy environments of SNe Ia provide our best opportunity for constraining the mechanism(s) of the SN Ia progenitor system, i.e., the stars involved, the incubation times, and the sensitivity of SNe Ia to changes in the local gas-phase metallicity. The latter can affect the luminosity of the resultant Ia event, and possibly the success in ultimately yielding a SN Ia event. We seek to solidify possible environmental trends in SN Ia rates from direct measures of host galaxy properties, using the sample collected by the Nearby Galaxies Supernova Search project. This study will uncover which has the greatest influence on SN Ia production efficiency: parent population age, rate of star-formation, or metallicity. Here, we propose to continue our analysis using the Mayall 4m + RCSP to obtain broad SEDs, R_23 metallicities, and star formation rates for 18 of the 25 remaining host galaxies (all z≤0.15) from the NGSS sample (20 targets were obtained in the 2010 semesters). These data will be combined with the remaining sample to be completed in the 2011B semester. The sample will provide a validity test of the mostly indirect trends being established for SNe Ia from the LOSS, SDSS, SNfactory and other surveys, and ultimately steer future investigations towards more precise SN Ia cosmology.

  20. Modeling platinum group metal complexes in aqueous solution.

    Science.gov (United States)

    Lienke, A; Klatt, G; Robinson, D J; Koch, K R; Naidoo, K J

    2001-05-07

    We construct force fields suited for the study of three platinum group metals (PGM) as chloranions in aqueous solution from quantum chemical computations and report experimental data. Density functional theory (DFT) using the local density approximation (LDA), as well as extended basis sets that incorporate relativistic corrections for the transition metal atoms, has been used to obtain equilibrium geometries, harmonic vibrational frequencies, and atomic charges for the complexes. We found that DFT calculations of [PtCl(6)](2-).3H(2)O, [PdCl(4)](2-).2H(2)O, and [RhCl(6)](3-).3H(2)O water clusters compared well with molecular mechanics (MM) calculations using the specific force field developed here. The force field performed equally well in condensed phase simulations. A 500 ps molecular dynamics (MD) simulation of [PtCl(6)](2-) in water was used to study the structure of the solvation shell around the anion. The resulting data were compared to an experimental radial distribution function derived from X-ray diffraction experiments. We found the calculated pair correlation functions (PCF) for hexachloroplatinate to be in good agreement with experiment and were able to use the simulation results to identify and resolve two water-anion peaks in the experimental spectrum.

  1. TYPE Ia SUPERNOVA CARBON FOOTPRINTS

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, R. C.; Nugent, P. [Computational Cosmology Center, Computational Research Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road MS 50B-4206, Berkeley, CA 94611 (United States); Aldering, G.; Aragon, C.; Bailey, S.; Childress, M.; Fakhouri, H. K.; Hsiao, E. Y.; Loken, S. [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Antilogus, P.; Bongard, S.; Canto, A. [Laboratoire de Physique Nucleaire et des Hautes Energies, Universite Pierre et Marie Curie Paris 6, Universite Paris Diderot Paris 7, CNRS-IN2P3, 4 place Jussieu, 75252 Paris Cedex 05 (France); Baltay, C. [Department of Physics, Yale University, New Haven, CT 06250-8121 (United States); Buton, C.; Kerschhaggl, M.; Kowalski, M.; Paech, K. [Physikalisches Institut, Universitaet Bonn, Nussallee 12, 53115 Bonn (Germany); Chotard, N.; Copin, Y.; Gangler, E. [Universite de Lyon, F-69622 Lyon (France); and others

    2011-12-10

    We present convincing evidence of unburned carbon at photospheric velocities in new observations of five Type Ia supernovae (SNe Ia) obtained by the Nearby Supernova Factory. These SNe are identified by examining 346 spectra from 124 SNe obtained before +2.5 days relative to maximum. Detections are based on the presence of relatively strong C II {lambda}6580 absorption 'notches' in multiple spectra of each SN, aided by automated fitting with the SYNAPPS code. Four of the five SNe in question are otherwise spectroscopically unremarkable, with ions and ejection velocities typical of SNe Ia, but spectra of the fifth exhibit high-velocity (v > 20, 000 km s{sup -1}) Si II and Ca II features. On the other hand, the light curve properties are preferentially grouped, strongly suggesting a connection between carbon-positivity and broadband light curve/color behavior: three of the five have relatively narrow light curves but also blue colors and a fourth may be a dust-reddened member of this family. Accounting for signal to noise and phase, we estimate that 22{sup +10}{sub -6%} of SNe Ia exhibit spectroscopic C II signatures as late as -5 days with respect to maximum. We place these new objects in the context of previously recognized carbon-positive SNe Ia and consider reasonable scenarios seeking to explain a physical connection between light curve properties and the presence of photospheric carbon. We also examine the detailed evolution of the detected carbon signatures and the surrounding wavelength regions to shed light on the distribution of carbon in the ejecta. Our ability to reconstruct the C II {lambda}6580 feature in detail under the assumption of purely spherical symmetry casts doubt on a 'carbon blobs' hypothesis, but does not rule out all asymmetric models. A low volume filling factor for carbon, combined with line-of-sight effects, seems unlikely to explain the scarcity of detected carbon in SNe Ia by itself.

  2. Peruvian perovskite Between Transition-metal to PGM/PlatinumGroupMetal Catalytic Fusion

    Science.gov (United States)

    Maksoed, Wh-

    2016-11-01

    Strongly correlated electronic materials made of simple building blocks, such as a transition-metal ion in an octahedral oxygen cage forming a perovskite structure- Dagotto & Tokura for examples are the high-temperature superconductivity & the CMR/Colossal Magnetoresistance . Helium-4 denotes from LC Case,ScD: "Catalytic Fusion of Deuterium into Helium-4"- 1998 dealt with gaseous D2- "contacted with a supported metallic catalyst at superatmospheric pressure". The catalyst is a platinum-group metal, at about 0.5% - 1% by weight, on activated C. Accompanies Stephen J Geier, 2010 quotes "transition metal complexes", the Energy thus produced is enormous, and because the deuterium is very cheap in the form of heavy water (less than US 1/g), the fuel cost is very low (<<1 %/KwH). "The oceans contain enough deuterium to satisfy the Earth's energy needs for many millions of year" to keep "maria"/Latin name of seas &Deuteronomy to be eternally preserves. Heartfelt Gratitudes to HE. Mr. Prof. Ir. HANDOJO.

  3. X-ray characterization of platinum group metal catalysts

    Science.gov (United States)

    Peterson, Eric J.

    Platinum group metals (PGMs) are used extensively as catalysts, employed in several sectors of the world energy economy. Fuel cells employing PGM catalysts show promise as power sources in the proposed hydrogen economy, using alcohols as hydrogen storage media. Currently, the most economically important application for PGMs is for the mitigation of emissions from internal combustion engines via catalytic converters. In all applications, efficient use of these expensive metals to fabricate robust catalysts is of the utmost importance. Understanding the catalyst structure/property relationship is the key to the improvement of existing catalysts and the discovery of new catalysts. For example, catalyst particle size can have profound effects on catalyst activity, as in the case of gold nanoparticles. Catalyst particle size control and stability is also important for the efficient use of PGM metals and catalyst deactivation prevention. The challenge is to identify and characterize structural features and determine if and how these features may relate to catalytic properties. The ultimate goal is to simultaneously measure catalyst structural characteristics and catalytic properties under operando conditions, unambiguously establishing the structure/property link. X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are important techniques used for the characterization of PGM catalysts. Microstructural information such as crystallite size, as small as ~ 1 nm, and microstrain can be obtained from Bragg diffraction peak shapes in X-ray diffraction patterns, and long range crystal structure information is found in the intensities and positions of these peaks. In contrast, X-ray absorption spectroscopy provides information about the chemical state and local structure of selected atoms. From the average nearest neighbor coordination numbers, crystallite sizes can also be inferred, with particularly high sensitivity in the sub-nm size range. Electron microscopy

  4. Molecular early main group metal hydrides : synthetic challenge, structures and applications

    NARCIS (Netherlands)

    Harder, Sjoerd

    2012-01-01

    Within the general area of early main group metal chemistry, the controlled synthesis of well-defined metal hydride complexes is a rapidly developing research field. As group 1 and 2 metal complexes are generally highly dynamic and lattice energies for their [MH](infinity) and [MH2](infinity) salts

  5. Molecular early main group metal hydrides : synthetic challenge, structures and applications

    NARCIS (Netherlands)

    Harder, Sjoerd

    2012-01-01

    Within the general area of early main group metal chemistry, the controlled synthesis of well-defined metal hydride complexes is a rapidly developing research field. As group 1 and 2 metal complexes are generally highly dynamic and lattice energies for their [MH](infinity) and [MH2](infinity) salts

  6. Pyrometallurgical Recovery of Platinum Group Metals from Spent Catalysts

    Science.gov (United States)

    Peng, Zhiwei; Li, Zhizhong; Lin, Xiaolong; Tang, Huimin; Ye, Lei; Ma, Yutian; Rao, Mingjun; Zhang, Yuanbo; Li, Guanghui; Jiang, Tao

    2017-09-01

    As an important secondary resource with abundant platinum group metals (PGMs), spent catalysts demand recycling for both economic and environmental benefits. This article reviews the main pyrometallurgical processes for PGM recovery from spent catalysts. Existing processes, including smelting, vaporization, and sintering processes, are discussed based in part on a review of the physiochemical characteristics of PGMs in spent catalysts. The smelting technology, which produces a PGM-containing alloy, is significantly influenced by the addition of various collectors, such as lead, copper, iron, matte, or printed circuit board (PCB), considering their chemical affinities for PGMs. The vaporization process can recover PGMs in vapor form at low temperatures (250-700°C), but it suffers high corrosion and potential environmental and health risks as a result of involvement of the hazardous gases, mainly Cl2 and CO. The sintering process serves as a reforming means for recycling of the spent catalysts by in situ reduction of their oxidized PGMs components. Among these processes, the smelting process seems more promising although its overall performance can be further improved by seeking a suitable target-oriented collector and flux, together with proper pretreatment and process intensification using an external field.

  7. Synthesis of Group IVB Metals Oxicarbides by Carboreduction Reactions

    Directory of Open Access Journals (Sweden)

    A.D. Mazzoni

    2002-10-01

    Full Text Available The metals of the group IV B (Ti, Zr, Hf present a series of carbides and oxicarbides with scientific and technological interest. Many of these compounds belong to the subsystem "MO - MC" of the pseudoternary "MO - MN - MC" system (where M = Ti, Zr or Hf. In this work carboreduction reactions of TiO2 and ZrO2 were performed in argon atmosphere, using temperatures from 1250° to 1650° and reaction times of 120 min. The oxicarbides obtained were in the range TiC0.16O0.84 to TiC0.73O0.27 and ZrC0.46O0.54 to ZrC0.90O0.10. respectively. The reaction products were characterized by X-ray diffraction (XRD, with the calculation of their cell constants by means of the Rietveld method. Scanning Electron Microscopy (SEM was used in the characterization of powdered materials. Additionally, the carborreduction reaction was followed by weight loss.

  8. Platinum group metal recovery and catalyst manufacturing process

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H. S.; Kim, Y. S.; Yoo, J. H.; Lee, H. S.; Ahn, D. H.; Kim, K. R.; Lee, S. H.; Paek, S. W.; Kang, H. S.

    1998-03-01

    The fission product nuclides generated during the irradiation of reactor fuel include many useful elements, among them platinum group metal such as ruthenium, rhodium and palladium which are of great industrial importance, occur rarely in nature and are highly valuable. In this research, the authors reviewed various PGM recovery methods. Recovery of palladium from seven-component simulated waste solution was conducted by selective precipitation method. The recovery yield was more than 99.5% and the purity of the product was more than 99%. Wet-proof catalyst was prepared with the recovered palladium. The specific surface area of the catalyst support was more than 400 m{sup 2}/g. The content of palladium impregnated on the support was 10 wt.%. Hydrogen isotope exchange efficiency of 93 % to equilibrium with small amount of the catalyst was obtained. It was turned out possible to consider using such palladium or other very low active PGM materials in applications where its actively is unimportant as in nuclear industries. (author). 63 refs., 38 tabs., 36 figs.

  9. Molecular early main group metal hydrides: synthetic challenge, structures and applications.

    Science.gov (United States)

    Harder, Sjoerd

    2012-11-25

    Within the general area of early main group metal chemistry, the controlled synthesis of well-defined metal hydride complexes is a rapidly developing research field. As group 1 and 2 metal complexes are generally highly dynamic and lattice energies for their [MH](∞) and [MH(2)](∞) salts are high, the synthesis of well-defined soluble hydride complexes is an obvious challenge. Access to molecular early main group metal hydrides, however, is rewarding: these hydrocarbon-soluble metal hydrides are highly reactive, have found use in early main group metal catalysis and are potentially also valuable molecular model systems for polar metal hydrides as a hydrogen storage material. The article focusses specifically on alkali and alkaline-earth metal hydride complexes and discusses the synthetic challenge, molecular structures, reactivity and applications.

  10. Asymptomatic prospective and retrospective cohorts with metal-on-metal hip arthroplasty indicate acquired lymphocyte reactivity varies with metal ion levels on a group basis.

    Science.gov (United States)

    Hallab, Nadim J; Caicedo, Marco; McAllister, Kyron; Skipor, Anastasia; Amstutz, Harlan; Jacobs, Joshua J

    2013-02-01

    Some tissues from metal-on-metal (MoM) hip arthroplasty revisions have shown evidence of adaptive-immune reactivity (i.e., excessive peri-implant lymphocyte infiltration/activation). We hypothesized that, prior to symptoms, some people with MoM hip arthroplasty will develop quantifiable metal-induced lymphocyte reactivity responses related to peripheral metal ion levels. We tested three cohorts (Group 1: n = 21 prospective longitudinal MoM hip arthroplasty; Group 2: n = 17 retrospective MoM hip arthroplasty; and Group 3: n = 20 controls without implants). We compared implant position, metal-ion release, and immuno-reactivity. MoM cohorts had elevated (p Group 1:1.2 ppb Co, 1.5 ppb Cr; Group 2: 3.4 ppb Co, 5.4 ppb Cr; Group 3: 0.01 ppb Co, 0.1 ppb Cr). However, only after 1-4 years post-op did 56% of Group 1 develop metal-reactivity (vs. 5% pre-op, metal-LTT, SI > 2), compared with 76% of Group 2, and 15% of Group 3 controls (patch testing was a poor diagnostic indicator with only 1/21 Group 1 positive). Higher cup-abduction angles (50° vs. 40°) in Group 1 were associated with higher serum Cr (p Group-1 participants (p Group 1 participants. Our results showed that lymphocyte reactivity to metals can develop within the first 1-4 years after MoM arthroplasty in asymptomatic patients and lags increases in metal ion levels. This increased metal reactivity was more prevalent in those individuals with extreme cup angles and higher amounts of circulating metal. Copyright © 2012 Orthopaedic Research Society.

  11. Multinuclear group 4 catalysis: olefin polymerization pathways modified by strong metal-metal cooperative effects.

    Science.gov (United States)

    McInnis, Jennifer P; Delferro, Massimiliano; Marks, Tobin J

    2014-08-19

    homogeneous and heterogeneous systems, macromolecules with dramatically altered properties, and large-scale industrial processes. It is noteworthy that many metalloenzymes employ multiple active centers operating in close synergistic proximity to achieve high activity and selectivity. Such enzymes were the inspiration for the research discussed in this Account, focused on the properties of multimetallic olefin polymerization catalysts. Here we discuss how modifications in organic ligand architecture, metal···metal proximity, and cocatalyst can dramatically modify polyolefin molecular weight, branch structure, and selectively for olefinic comonomer enchainment. We first discuss bimetallic catalysts with identical group 4 metal centers and then heterobimetallic systems with either group 4 or groups 4 + 6 catalytic centers. We compare and contrast the polymerization properties of the bimetallic catalysts with their monometallic analogues, highlighting marked cooperative enchainment effects and unusual polymeric products possible via the proximate catalytic centers. Such multinuclear olefin polymerization catalysts exhibit the following distinctive features: (1) unprecedented levels of polyolefin branching; (2) enhanced enchainment selectivity for linear and encumbered α-olefin comonomers; (3) enhanced polyolefin tacticity and molecular weight; (4) unusual 1,2-insertion regiochemistry for styrenic monomers; (5) modified chain transfer kinetics, such as M-polymer β-hydride transfer to the metal or incoming monomer; (6) LLDPE synthesis with a single binuclear catalyst and ethylene.

  12. Tests of Environmental Effects on Type Ia Supernova Production

    Science.gov (United States)

    Sadler, Suzanna M.; Strolger, L.; Wolff, S.

    2011-01-01

    The host galaxy environments of type Ia supernovae (SNe Ia) provide our best opportunity for constraining the mechanism(s) of the SN Ia progenitor system, i.e., the stars involved, the incubation times, and the sensitivity of SNe Ia to changes in the local gas-phase metallicity. The latter can affect the luminosity of the resultant event, and possibly the success in ultimately yielding a SN Ia. We seek to solidify possible environmental trends in SN Ia rates from direct measures of host galaxy properties, using the sample collected by the Nearby Galaxies Supernova Search project. This study will uncover which has the greatest influence on SN Ia production efficiency: parent population age, rate of star-formation, or metallicity. Here, we will show some preliminary results from SSP model fitting (of age and [Fe/H]) to a selection of hosts obtained thus far from this study. The complete sample will provide a validity test of the mostly indirect trends being established for SNe Ia from the LOSS, SDSS, SNfactory and other surveys, and may ultimately steer future investigations towards more precise SN Ia cosmology.

  13. The platinum group metals in Younger Dryas Horizons are terrestrial

    Science.gov (United States)

    Wu, Y.; Wikes, E.; Kennett, J.; West, A.; Sharma, M.

    2009-12-01

    The Younger Dryas (YD) event, which began 12,900 years ago, was a period of abrupt and rapid cooling in the Northern Hemisphere whose primary cause remains unclear. The prevalent postulated mechanism is a temporary shutdown of the thermohaline circulation following the breakup of an ice dam in North America. Firestone et al. (2007) proposed that the cooling was triggered by multiple cometary airbursts and/or impacts that engendered enormous environmental changes and disrupted the thermohaline circulation. The evidence in support for this hypothesis is a black layer in North America and in Europe marking the YD boundary containing charcoal, soot, carbon spherules and glass-like carbon suggesting extensive and intense forest fires. This layer is also enriched in magnetic grains high in iridium, magnetic microspherules, fullerenes containing extraterrestrial He-3, and nanodiamonds. Whereas the nanodiamonds could be produced in an impact or arrive with the impactor, the cometary burst/impact hypothesis remains highly controversial as the YD horizon lacks important impact markers such as craters, breccias, tektites and shocked minerals. Firestone et al. (2007) contend that bulk of Ir found at the YD boundary is associated with magnetic grains. The key issue is whether this Ir is meteorite derived. We used Ir and Os concentrations and Os isotopes to investigate the provenance of the platinum group metals in the YD horizon. The bulk sediment samples from a number of North American YD sites (Blackwater Draw, Murray Springs, Gainey, Sheriden Cave, and Myrtle Beach) and a site in Europe (Lommel) do not show any traces of meteorite derived Os and Ir. The [Os] = 2 to 45 pg/g in these sediments and the 187Os/188Os ratios are similar to the upper continental crustal values (~1.3), much higher than those in meteorites (0.13). Higher [Os] is observed in Blackwater Draw (= 194 pg/g). However, the Os/Ir ratio in Blackwater Draw is 5 (not 1 as expected for a meteorite) and 187Os/188

  14. METALLICITY DISTRIBUTION FUNCTIONS OF FOUR LOCAL GROUP DWARF GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Ross, Teresa L.; Holtzman, Jon [Department of Astronomy, New Mexico State University, P.O. Box 30001, MSC 4500, Las Cruces, NM 88003-8001 (United States); Saha, Abhijit [NOAO, 950 Cherry Avenue, Tucson, AZ 85726-6732 (United States); Anthony-Twarog, Barbara J., E-mail: rosst@nmsu.edu, E-mail: holtz@nmsu.edu, E-mail: bjat@ku.edu [Department of Physics and Astronomy, University of Kansas, Lawrence, KS 66045-7582 (United States)

    2015-06-15

    We present stellar metallicities in Leo I, Leo II, IC 1613, and Phoenix dwarf galaxies derived from medium (F390M) and broad (F555W, F814W) band photometry using the Wide Field Camera 3 instrument on board the Hubble Space Telescope. We measured metallicity distribution functions (MDFs) in two ways, (1) matching stars to isochrones in color–color diagrams and (2) solving for the best linear combination of synthetic populations to match the observed color–color diagram. The synthetic technique reduces the effect of photometric scatter and produces MDFs 30%–50% narrower than the MDFs produced from individually matched stars. We fit the synthetic and individual MDFs to analytical chemical evolution models (CEMs) to quantify the enrichment and the effect of gas flows within the galaxies. Additionally, we measure stellar metallicity gradients in Leo I and II. For IC 1613 and Phoenix our data do not have the radial extent to confirm a metallicity gradient for either galaxy. We find the MDF of Leo I (dwarf spheroidal) to be very peaked with a steep metal-rich cutoff and an extended metal-poor tail, while Leo II (dwarf spheroidal), Phoenix (dwarf transition), and IC 1613 (dwarf irregular) have wider, less peaked MDFs than Leo I. A simple CEM is not the best fit for any of our galaxies; therefore we also fit the “Best Accretion Model” of Lynden-Bell. For Leo II, IC 1613, and Phoenix we find similar accretion parameters for the CEM even though they all have different effective yields, masses, star formation histories, and morphologies. We suggest that the dynamical history of a galaxy is reflected in the MDF, where broad MDFs are seen in galaxies that have chemically evolved in relative isolation and narrowly peaked MDFs are seen in galaxies that have experienced more complicated dynamical interactions concurrent with their chemical evolution.

  15. Metallicities and kinematics for dwarf spheroidals in the local group

    NARCIS (Netherlands)

    Battaglia, G.; Tolstoy, E.; Helmi, A.; Irwin, M.; Randich, S; Pasquini, L

    2006-01-01

    We present the first results of Call triplet observations from VLT/FLAMES for Sculptor, Fornax and Sextans dSphs. For each galaxy, we obtained accurate velocity and metallicity measurements for hundreds of stars out to and beyond the tidal radius. In each case, we find clear evidence for the presenc

  16. Metallicity Distribution Functions of Four Local Group dwarf galaxies

    CERN Document Server

    Ross, Teresa L; Saha, Abhijit; Anthony-Twarog, Barbara J

    2015-01-01

    We present stellar metallicities in Leo I, Leo II, IC 1613, and Phoenix dwarf galaxies derived from medium (F390M) and broad (F555W, F814W) band photometry using the Wide Field Camera 3 (WFC3) instrument aboard the Hubble Space Telescope. We measured metallicity distribution functions (MDFs) in two ways, 1) matching stars to isochrones in color-color diagrams, and 2) solving for the best linear combination of synthetic populations to match the observed color-color diagram. The synthetic technique reduces the effect of photometric scatter, and produces MDFs 30-50 % narrower than the MDFs produced from individually matched stars. We fit the synthetic and individual MDFs to analytical chemical evolution models (CEM) to quantify the enrichment and the effect of gas flows within the galaxies. Additionally, we measure stellar metallicity gradients in Leo I and II. For IC 1613 and Phoenix our data do not have the radial extent to confirm a metallicity gradient for either galaxy. We find the MDF of Leo I (dwarf spher...

  17. Type Ia Supernova Carbon Footprints

    CERN Document Server

    Thomas, R C; Aragon, C; Antilogus, P; Bailey, S; Baltay, C; Bongard, S; Buton, C; Canto, A; Childress, M; Chotard, N; Copin, Y; Fakhouri, H K; Gangler, E; Hsiao, E Y; Kerschhaggl, M; Kowalski, M; Loken, S; Nugent, P; Paech, K; Pain, R; Pecontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Rigault, M; Rubin, D; Runge, K; Scalzo, R; Smadja, G; Tao, C; Weaver, B A; Wu, C; Brown, P J; Milne, P A

    2011-01-01

    We present convincing evidence of unburned carbon at photospheric velocities in new observations of 5 Type Ia supernovae (SNe Ia) obtained by the Nearby Supernova Factory. These SNe are identified by examining 346 spectra from 124 SNe obtained before +2.5 d relative to maximum. Detections are based on the presence of relatively strong C II 6580 absorption "notches" in multiple spectra of each SN, aided by automated fitting with the SYNAPPS code. Four of the 5 SNe in question are otherwise spectroscopically unremarkable, with ions and ejection velocities typical of SNe Ia, but spectra of the fifth exhibits high-velocity (v > 20,000 km/s) Si II and Ca II features. On the other hand, the light curve properties are preferentially grouped, strongly suggesting a connection between carbon-positivity and broad band light curve/color behavior: Three of the 5 have relatively narrow light curves but also blue colors, and a fourth may be a dust-reddened member of this family. Accounting for signal-to-noise and phase, we ...

  18. Merging white dwarfs and Type Ia supernovae

    Science.gov (United States)

    Yungelson, L. R.; Kuranov, A. G.

    2017-01-01

    Using population synthesis, we study a double-degenerate (DD) scenario for Type Ia supernovae (SNe Ia), aiming to estimate the maximum possible contribution to the rate of SNe from this scenario and the dependence of the delay-time distribution (DTD) on it. We make an extreme assumption that all mergers of super-Chandrasekhar pairs of CO white dwarfs (WDs) and mergers of CO WDs more massive than 0.47 M⊙ with hybrid or helium WDs more massive than 0.37 M⊙ produce SNe Ia. The models are parametrized by the product of the common envelope efficiency and the parameter of binding energy of stellar envelopes, αce λ, which we vary between 0.25 and 2. The best agreement with observations is obtained for αce λ = 2. A substantial contribution to the rate of SNe Ia is provided by the pairs with a hybrid WD. The estimated Galactic rate of SNe Ia is 6.5 × 10-3 yr-1 (for the mass of the bulge and thin disc equal to 7.2 × 1010 M⊙), which is comparable to the observational estimate (5.4 ± 0.12) × 10-3 yr-1. The model DTD for 1 ≤ t ≤ 8 Gyr satisfactorily fits the DTD for SNe Ia in the field galaxies (Maoz, Mannucci & Brandt). For this epoch, the model DTD is ∝t-1.64. At earlier and later epochs, our DTD has a deficit of events, as in other studies. Marginal agreement with the observational DTD is achieved even if only CO+CO WDs with M1 ≥ 0.8 M⊙ and M2 ≥ 0.6 M⊙ produce SNe Ia. A better agreement of observed and modelled DTD may be obtained if tidal effects are weaker than assumed and/or the metallicity of the population is much lower than solar.

  19. Oxidation of Group 8 transition-Metal Hydrides and Ionic Hydrogenation of Ketones and Aldehydes

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Kjell-Tore

    1996-08-01

    Transition-metal hydrides have received considerable attention during the last decades because of their unusual reactivity and their potential as homogeneous catalysts for hydrogenation and other reactions of organic substrates. An important class of catalytic processes where transition-metal hydrides are involved is the homogeneous hydrogenation of alkenes, alkynes, ketones, aldehydes, arenes and nitro compounds. This thesis studies the oxidation of Group 8 transition-metal hydrides and the ionic hydrogenation of ketones and aldehydes.

  20. IA, I AM

    DEFF Research Database (Denmark)

    Munk, Timme Bisgaard; Mørk, Kristian

    2004-01-01

    Hvad er informationsarkitektur? Mørk & Munk gennemgår de forskellige metaforiske konstruktioner af begrebet og kommer med deres helt egen selvstændige definition. Informationsarkitektur er en samtale, strukturation, en klassifikationskamp og et konceptuelt blend. Læs hvorfor i dette working paper...... om et af de meste centrale begreber videnssamfundet. For nu er vi alle informationsarkitekter: IA, I AM....

  1. Arbuscular mycorrhizal fungal phylogenetic groups differ in affecting host plants along heavy metal levels.

    Science.gov (United States)

    He, Lei; Yang, Haishui; Yu, Zhenxing; Tang, Jianjun; Xu, Ligen; Chen, Xin

    2014-10-01

    Arbuscular mycorrhizal fungi (AMF) are important components of soil microbial communities, and play important role in plant growth. However, the effects of AMF phylogenetic groups (Glomeraceae and non-Glomeraceae) on host plant under various heavy metal levels are not clear. Here we conducted a meta-analysis to compare symbiotic relationship between AMF phylogenetic groups (Glomeraceae and non-Glomeraceae) and host plant functional groups (herbs vs. trees, and non-legumes vs. legumes) at three heavy metal levels. In the meta-analysis, we calculate the effect size (ln(RR)) by taking the natural logarithm of the response ratio of inoculated to non-inoculated shoot biomass from each study. We found that the effect size of Glomeraceae increased, but the effect size of non-Glomeraceae decreased under high level of heavy metal compared to low level. According to the effect size, both Glomeraceae and non-Glomeraceae promoted host plant growth, but had different effects under various heavy metal levels. Glomeraceae provided more benefit to host plants than non-Glomeraceae did under heavy metal condition, while non-Glomeraceae provided more benefit to host plants than Glomeraceae did under no heavy metal. AMF phylogenetic groups also differed in promoting plant functional groups under various heavy metal levels. Interacting with Glomeraceae, herbs and legumes grew better than trees and non-legumes did under high heavy metal level, while trees and legumes grew better than herbs and non-legumes did under medium heavy metal level. Interacting with non-Glomeraceae, herbs and legumes grew better than trees and non-legumes did under no heavy metal. We suggested that the combination of legume with Glomeraceae could be a useful way in the remediation of heavy metal polluted environment.

  2. Rates and progenitors of type Ia supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Wood-Vasey, William Michael [Univ. of California, Berkeley, CA (United States)

    2004-01-01

    The remarkable uniformity of Type Ia supernovae has allowed astronomers to use them as distance indicators to measure the properties and expansion history of the Universe. However, Type Ia supernovae exhibit intrinsic variation in both their spectra and observed brightness. The brightness variations have been approximately corrected by various methods, but there remain intrinsic variations that limit the statistical power of current and future observations of distant supernovae for cosmological purposes. There may be systematic effects in this residual variation that evolve with redshift and thus limit the cosmological power of SN Ia luminosity-distance experiments. To reduce these systematic uncertainties, we need a deeper understanding of the observed variations in Type Ia supernovae. Toward this end, the Nearby Supernova Factory has been designed to discover hundreds of Type Ia supernovae in a systematic and automated fashion and study them in detail. This project will observe these supernovae spectrophotometrically to provide the homogeneous high-quality data set necessary to improve the understanding and calibration of these vital cosmological yardsticks. From 1998 to 2003, in collaboration with the Near-Earth Asteroid Tracking group at the Jet Propulsion Laboratory, a systematic and automated searching program was conceived and executed using the computing facilities at Lawrence Berkeley National Laboratory and the National Energy Research Supercomputing Center. An automated search had never been attempted on this scale. A number of planned future large supernovae projects are predicated on the ability to find supernovae quickly, reliably, and efficiently in large datasets. A prototype run of the SNfactory search pipeline conducted from 2002 to 2003 discovered 83 SNe at a final rate of 12 SNe/month. A large, homogeneous search of this scale offers an excellent opportunity to measure the rate of Type Ia supernovae. This thesis presents a new method for

  3. Type Ia supernovae: Progenitors and evolution with redshift

    Science.gov (United States)

    Nomoto, Ken'ichi; Umeda, Hideyuki; Kobayashi, Chiaki; Hachisu, Izumi; Kato, Mariko; Tsujimoto, Takuji

    2000-06-01

    Relatively uniform light curves and spectral evolution of Type Ia supernovae(SNe Ia) have led to the use of SNe Ia as a ``standard candle'' to determine cosmological parameters. Whether a statistically significant value of the cosmological constant can be obtained depends on whether the peak luminosities of SNe Ia are sufficiently free from the effects of cosmic and galactic evolutions. Here we first review the single degenerate scenario for the Chandrasekhar mass white dwarf (WD) models of SNe Ia. We identify the progenitor's evolution and population with two channels: (1) the WD+RG (red-giant) and (2) the WD+MS (near main-sequence He-rich star) channels. In these channels, the strong wind from accreting WDs plays a key role, which yields important age and metallicity effects on the evolution. We then address the questions whether the nature of SNe Ia depends systematically on environmental properties such as metallicity and age of the progenitor system and whether significant evolutionary effects exist. We suggest that the variation of the carbon mass fraction X(C) in the C+O WD (or the variation of the initial WD mass) causes the diversity of the brightness of SNe Ia. This model can explain the observed dependences of SNe Ia brightness on the galaxy types and the distance from the galactic center. Finally, applying the metallicity effect on the evolution of SN Ia progenitors, we make a prediction of the cosmic supernova rate history as a composite of the supernova rates in different types of galaxies. .

  4. The core-degenerate scenario for the progenitors of Type Ia supernovae

    Science.gov (United States)

    Wang, B.; Zhou, W.-H.; Zuo, Z.-Y.; Li, Y.-B.; Luo, X.; Zhang, J.-J.; Liu, D.-D.; Wu, C.-Y.

    2017-02-01

    The origin of the progenitors of Type Ia supernovae (SNe Ia) is still uncertain. The core-degenerate (CD) scenario has been proposed as an alternative way for the production of SNe Ia. In this scenario, SNe Ia are formed at the final stage of common-envelope evolution from a merger of a carbon-oxygen white dwarf (CO WD) with the CO core of an asymptotic giant branch companion. However, the birthrates of SNe Ia from this scenario are still not well determined. In this work, we performed a detailed investigation on the CD scenario based on a binary population synthesis approach. The SN Ia delay times from this scenario are basically in the range of 90-2500 Myr, mainly contributing to the observed SNe Ia with short and intermediate delay times, although this scenario can also produce some old SNe Ia. Meanwhile, our work indicates that the Galactic birthrates of SNe Ia from this scenario are not more than 20 per cent of total SNe Ia due to more careful treatment of mass transfer. Although the SN Ia birthrates in this work are lower than those in Ilkov & Soker, the CD scenario cannot be ruled out as a viable mechanism for the formation of SNe Ia. Especially, SNe Ia with circumstellar material from this scenario contribute to 0.7-10 per cent of total SNe Ia, which means that the CD scenario can reproduce the observed birthrates of SNe Ia like PTF 11kx. We also found that SNe Ia happen systemically earlier for a high value of metallicity and their birthrates increase with metallicity.

  5. Structurally defined allyl compounds of main group metals: coordination and reactivity.

    Science.gov (United States)

    Lichtenberg, Crispin; Okuda, Jun

    2013-05-10

    Organometallic allyl compounds are important as allylation reagents in organic synthesis, as polymerization catalysts, and as volatile metal precursors in material science. Whereas the allyl chemistry of synthetically relevant transition metals such as palladium and of the lanthanoids is well-established, that of main group metals has been lagging behind. Recent progress on allyl complexes of Groups 1, 2, and 12-16 now provides a more complete picture. This is based on a fundamental understanding of metal-allyl bonding interactions in solution and in the solid state. Furthermore, reactivity trends have been rationalized and new types of allyl-specific reactivity patterns have been uncovered. Key features include 1) the exploitation of the different types of metal-allyl bonding (highly ionic to predominantly covalent), 2) the use of synergistic effects in heterobimetallic compounds, and 3) the adjustment of Lewis acidity by variation of the charge of allyl compounds.

  6. Friction behavior of members of the platinum metals group with gold

    Science.gov (United States)

    Buckley, D. H.

    1975-01-01

    The adhesion and friction behavior of the platinum metals group was examined with clean surfaces and surfaces selectively contaminated with oxygen, vinyl chloride (C2H3Cl), and methyl mercaptan (CH3SH). A pin or disk specimen configuration was used with the pin being a single crystal of gold of the (111) orientation and with the platinum metal disks also being single crystals of the (111) or (0001) orientation. Loads applied ranged from 1 to 10 g and a sliding velocity of 0.7 mm/min was employed. Results indicate adhesion and transfer of gold to all of the platinum metals. Despite this observation friction differences existed among the metals in the group. These differences are related to surface chemical activity. Adsorption of various friction reducing species was selective. With some adsorbates present strong adhesive forces between metals were still observed.

  7. Progenitors of type Ia supernovae

    CERN Document Server

    Maeda, Keiichi

    2016-01-01

    Natures of progenitors of type Ia Supernovae (SNe Ia) have not yet been clarified. There has been long and intensive discussion on whether the so-called single degenerate (SD) scenario or the double degenerate (DD) scenario, or anything else, could explain a major population of SNe Ia, but the conclusion has not yet been reached. With rapidly increasing observational data and new theoretical ideas, the field of studying the SN Ia progenitors has been quickly developing, and various new insights have been obtained in recent years. This article aims at providing a summary of the current situation regarding the SN Ia progenitors, both in theory and observations. It seems difficult to explain the emerging diversity seen in observations of SNe Ia by a single population, and we emphasize that it is important to clarify links between different progenitor scenarios and different sub-classes of SNe Ia.

  8. Optimizing IA-64 performance

    CERN Document Server

    Jarp, S

    2001-01-01

    Examines key features of the Itanium processor architecture and microarchitecture. The Itanium, originally known as the IA-64, is a 64-bit processor designed by Hewlett-Packard and Intel. In addition to the obvious performance gains that 64-bit addressing brings, the Itanium also supports performance-enhancing techniques such as predication, speculation, rotating registers, a wide parallel execution core, high clock speed, fast bus architecture, multiple execution units, and the like. Moreover, the Itanium is designed from the ground up around parallelism and uses a new kind of instruction set based on the Explicit Parallel Instruction Computing (EPIC) specification, which allows the processing of Windows-based and UNIX- based applications, among other features. Operating-system support for the IA-64 has been announced for 64-bit Windows, HP-UX, varieties of Linux, and AIX 51. The author shows how to achieve optimal code generation by a compiler or generate optimized sequences ofIA-64 assembly code to ensure ...

  9. A search for metal-poor stars pre-enriched by pair-instability supernovae I.A pilot study for target selection from Sloan Digital Sky Survey

    Institute of Scientific and Technical Information of China (English)

    Jing Ren; Norbert Christlieb; Gang Zhao

    2012-01-01

    We report on a pilot study on identifying metal-poor stars pre-enriched by Pair-Instability Supernovae (PISNe).Very massive,first generation (Population Ⅲ) stars (140 M⊙ ≤ M ≤ 260 M⊙) end their lives as PISNe,which have been predicted by theories,but no relics of PISNe have been observed yet.Among the distinct characteristics of the yields of PISNe,as predicted by theoretical calculations,are a strong odd-even effect,and a strong overabundance of Ca with respect to iron and the solar ratio.We use the latter characteristic to identify metal-poor stars in the Galactic halo that have been pre-enriched by PISNe,by comparing metallicites derived from strong,co-added Fe lines detected in low-resolution (i.e.,R = λ/Δλ ~ 2000) spectra of the Sloan Digital Sky Survey (SDSS),with metallicities determined by the SDSS Stellar Parameters Pipeline (SSPP).The latter are based on the strength of the Ca Ⅱ K line and assumptions on the Ca/Fe abundance ratio.Stars are selected as candidates if their metallicity derived from Fe lines is significantly lower than the SSPP metallicities.In a sample of 12 300 stars for which SDSS spectroscopy is available,we have identified 18 candidate stars.Higher resolution and signal-to-noise ratio spectra of these candidates are being obtained with the Very Large Telescope of the European Southern Observatory and the XSHOOTER spectrograph,to determine their abundance patterns,and to verify our selection method.We plan to apply our method to the database of several million stellar spectra to be acquired with the Guo Shou Jing Telescope (LAMOST) in the next five years.

  10. Finding Distances to Type Ia Supernovae

    Science.gov (United States)

    Kohler, Susanna

    2016-03-01

    Type Ia supernovae are known as standard candles due to their consistency, allowing us to measure distances based on their brightness. But what if these explosions arent quite as consistent as we thought? Due scientific diligence requires careful checks, so a recent study investigates whether the metallicity of a supernovas environment affects the peak luminosity of the explosion.Metallicity Dependence?Type Ia supernovae are incredibly powerful tools for determining distances in our universe. Because these supernovae are formed by white dwarfs that explode when they reach a uniform accreted mass, the supernova peak luminosity is thought to be very consistent. This consistency allows these supernovae to be used as standard candles to measure distances to their host galaxies.But what if that peak luminosity is affected by a factor that we havent taken into account? Theorists have proposed that the luminosities of Type Ia supernovae might depend on the metallicity of their environments with high-metallicity environments suppressing supernova luminosities. If this is true, then we could be systematically mis-measuring cosmological distances using these supernovae.Testing AbundancesSupernova brightnesses vs. the metallicity of their environments. Low-metallicity supernovae (blue shading) and high-metallicity supernovae (red shading) have an average magnitude difference of ~0.14. [Adapted from Moreno-Raya et al. 2016]A team led by Manuel Moreno-Raya, of the Center for Energy, Environment and Technology (CIEMAT) in Spain, has observed 28 Type Ia supernovae in an effort to test for such a metallicity dependence. These supernovae each have independent distance measurements (e.g., from Cepheids or the Tully-Fisher relation).Moreno-Raya and collaborators used spectra from the 4.2-m William Herschel Telescope to estimate oxygen abundances in the region where each of these supernovae exploded. They then used these measurements to determine if metallicity of the local region

  11. Hydrothermal synthesis of platinum-group-metal nanoparticles by using HEPES as a reductant and stabilizer.

    Science.gov (United States)

    So, Man-Ho; Ho, Chi-Ming; Chen, Rong; Che, Chi-Ming

    2010-06-01

    Platinum-group-metal (Ru, Os, Rh, Ir, Pd and Pt) nanoparticles are synthesized in an aqueous buffer solution of 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid (HEPES) (200 mM, pH 7.4) under hydrothermal conditions (180 degrees C). Monodispersed (monodispersity: 11-15%) metal nanoparticles were obtained with an average particle size of less than 5 nm (Ru: 1.8+/-0.2, Os: 1.6+/-0.2, Rh: 4.5+/-0.5, Ir: 2.0+/-0.3, Pd: 3.8+/-0.4, Pt: 1.9+/-0.2 nm). The size, monodispersity, and stability of the as-obtained metal nanoparticles were affected by the HEPES concentration, pH of the HEPES buffer solution, and reaction temperature. HEPES with two tertiary amines (piperazine groups) and terminal hydroxyl groups can act as a reductant and stabilizer. The HEPES molecules can bind to the surface of metal nanoparticles to prevent metal nanoparticles from aggregation. These platinum-group-metal nanoparticles could be deposited onto the surface of graphite, which catalyzed the aerobic oxidation of alcohols to aldehydes.

  12. A metric space for type Ia supernova spectra

    CERN Document Server

    Sasdelli, Michele; Aldering, G; Antilogus, P; Aragon, C; Bailey, S; Baltay, C; Benitez-Herrera, S; Bongard, S; Buton, C; Canto, A; Cellier-Holzem, F; Chen, J; Childress, M; Chotard, N; Copin, Y; Fakhouri, H K; Feindt, U; Fink, M; Fleury, M; Fouchez, D; Gangler, E; Guy, J; Ishida, E E O; Kim, A G; Kowalski, M; Kromer, M; Lombardo, S; Mazzali, P A; Nordin, J; Pain, R; Pécontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Rigault, M; Runge, K; Saunders, C; Scalzo, R; Smadja, G; Suzuki, N; Tao, C; Taubenberger, S; Thomas, R C; Tilquin, A; Weaver, B A

    2014-01-01

    We develop a new framework for use in exploring Type Ia Supernova (SN Ia) spectra. Combining Principal Component Analysis (PCA) and Partial Least Square analysis (PLS) we are able to establish correlations between the Principal Components (PCs) and spectroscopic/photometric SNe Ia features. The technique was applied to ~120 supernova and ~800 spectra from the Nearby Supernova Factory. The ability of PCA to group together SNe Ia with similar spectral features, already explored in previous studies, is greatly enhanced by two important modifications: (1) the initial data matrix is built using derivatives of spectra over the wavelength, which increases the weight of weak lines and discards extinction, and (2) we extract time evolution information through the use of entire spectral sequences concatenated in each line of the input data matrix. These allow us to define a stable PC parameter space which can be used to characterize synthetic SN Ia spectra by means of real SN features. Using PLS, we demonstrate that th...

  13. How SN Ia host-galaxy properties affect cosmological parameters

    CERN Document Server

    Campbell, H; Gilmore, G

    2016-01-01

    We present a systematic study of the relationship between Type Ia Supernova (SN Ia) properties, and the characteristics of their host galaxies, using a sample of 581 SNe Ia from the full Sloan Digital Sky Survey II (SDSS-II) SN Survey. We also investigate the effects of this on the cosmological constraints derived from SNe~Ia. Compared to previous studies, our sample is larger by a factor of $>4$, and covers a substantially larger redshift range (up to z~0.5), which is directly applicable to the volume of cosmological interest. We measure a significant correlation (>5\\sigma) between the host-galaxy stellar-mass and the SN~Ia Hubble Residuals (HR). We find a weak correlation (1.4\\sigma) between the host-galaxy metallicity as measured from emission lines in the spectra, and the SN~Ia HR. We also find evidence that the slope of the correlation between host-galaxy mass and HR is -0.11 $\\mathrm{mag}/\\mathrm{log}(\\mathrm{M}_{\\mathrm{host}}/\\mathrm{M}_{\\odot})$ steeper in lower metallicity galaxies. We test the effe...

  14. Type Ia Supernova Progenitors, Environmental Effects and Cosmic Supernova Rates

    CERN Document Server

    Nomoto, K; Hachisu, I; Kato, M; Kobayashi, C; Tsujimoto, T; Nomoto, Ken'ichi; Umeda, Hideyuki; Hachisu, Izumi; Kato, Mariko; Kobayashi, Chiaki; Tsujimoto, Takuji

    1999-01-01

    Relatively uniform light curves and spectral evolution of Type Ia supernovae (SNe Ia) have led to the use of SNe Ia as a ``standard candle'' to determine cosmological parameters, such as the Hubble constant, the density parameter, and the cosmological constant. Whether a statistically significant value of the cosmological constant can be obtained depends on whether the peak luminosities of SNe Ia are sufficiently free from the effects of cosmic and galactic evolutions. Here we first review the single degenerate scenario for the Chandrasekhar mass white dwarf (WD) models of SNe Ia. We identify the progenitor's evolution and population with two channels: (1) the WD+RG (red-giant) and (2) the WD+MS (near main-sequence He-rich star) channels. In these channels, the strong wind from accreting white dwarfs plays a key role, which yields important age and metallicity effects on the evolution. We then address the questions whether the nature of SNe Ia depends systematically on environmental properties such as metalli...

  15. EnviroAtlas - Des Moines, IA - Atlas Area Boundary

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the boundary of the Des Moines, IA EnviroAtlas Community. It represents the outside edge of all the block groups included in the...

  16. The oldest and most metal-poor stars in the APOSTLE Local Group simulations

    Science.gov (United States)

    Starkenburg, Else; Oman, Kyle A.; Navarro, Julio F.; Crain, Robert A.; Fattahi, Azadeh; Frenk, Carlos S.; Sawala, Till; Schaye, Joop

    2017-02-01

    We examine the spatial distribution of the oldest and most metal-poor stellar populations of Milky Way-sized galaxies using the A Project Of Simulating The Local Environment (APOSTLE) cosmological hydrodynamical simulations of the Local Group. In agreement with earlier work, we find strong radial gradients in the fraction of the oldest (tform stars, both of which increase outwards. The most metal-poor stars form over an extended period of time; half of them form after z = 5.3, and the last 10 per cent after z = 2.8. The age of the metal-poor stellar population also shows significant variation with environment; a high fraction of them are old in the galaxy's central regions and an even higher fraction in some individual dwarf galaxies, with substantial scatter from dwarf to dwarf. We investigate the dependence of these results on the assumptions made for metal mixing. Overall, over half of the stars that belong to both the oldest and most metal-poor population are found outside the solar circle. Somewhat counter-intuitively, we find that dwarf galaxies with a large fraction of metal-poor stars that are very old are systems where metal-poor stars are relatively rare, but where a substantial old population is present. Our results provide guidance for interpreting the results of surveys designed to hunt for the earliest and most pristine stellar component of our Milky Way.

  17. Mechanical, thermal and laser damage threshold analyses of II group metal complexes of thiourea

    Energy Technology Data Exchange (ETDEWEB)

    Dhanuskodi, S., E-mail: dhanus2k3@yahoo.com [School of Physics, Bharathidasan University, Tiruchirappalli 620 024, Tamil Nadu (India); Sabari Girisun, T.C. [School of Physics, Bharathidasan University, Tiruchirappalli 620 024, Tamil Nadu (India); Department of Physics, Bishop Heber College, Tiruchirappalli 620 017, Tamil Nadu (India); Bhagavannarayana, G. [Material Characterization Division, National Physical laboratory, New Delhi 110 012 (India); Uma, S.; Phillip, J. [Sophisticated Test and Instrumentation Center, Cochin University of Science and Technology, Cochin 682 022 (India)

    2011-04-15

    Research highlights: {yields} The role of the Group II metal ions in improving the stability is discussed. {yields} BTCC has a higher heat capacity than BTZC. {yields} Elastic stiffness is found to be higher for BTCC than BTZC. {yields} Microscopy studies confirm the damage is due to thermo-chemical ablation. {yields} BTCC has a higher laser damage threshold than BTZC. - Abstract: Single crystals of thiourea metal complexes with selected Group II metal ions, Zinc and Cadmium, have been grown by solvent evaporation technique. The crystals grown are bisthiourea zinc chloride (BTZC) and bisthiourea cadmium chloride (BTCC). Following an improved photopyroelectric technique, the thermal transport properties have been determined. It is found that BTCC has a higher heat capacity (304.09 J kg{sup -1} K{sup -1}) than BTZC (255.24 J kg{sup -1} K{sup -1}), and hence BTCC has better thermal stability. Vicker's microhardness measurements reveal that these materials have reverse indentation size effect and belong to the category of soft materials. Elastic stiffness is found to be higher for BTCC (1.57 GPa) than BTZC (0.76 GPa). The roles of the Group II metal ions in improving the mechanical and thermal stability of the metal complexes are discussed. Multi-shot laser damage studies on these materials reveal that BTCC has a higher laser damage threshold (15 GW cm{sup -2}) than BTZC (6 GW cm{sup -2}).

  18. HOST GALAXY PROPERTIES AND HUBBLE RESIDUALS OF TYPE Ia SUPERNOVAE FROM THE NEARBY SUPERNOVA FACTORY

    Energy Technology Data Exchange (ETDEWEB)

    Childress, M.; Aldering, G.; Aragon, C.; Bailey, S.; Fakhouri, H. K.; Hsiao, E. Y.; Kim, A. G.; Loken, S. [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Antilogus, P.; Bongard, S.; Canto, A.; Cellier-Holzem, F.; Guy, J. [Laboratoire de Physique Nucleaire et des Hautes Energies, Universite Pierre et Marie Curie Paris 6, Universite Paris Diderot Paris 7, CNRS-IN2P3, 4 place Jussieu, F-75252 Paris Cedex 05 (France); Baltay, C. [Department of Physics, Yale University, New Haven, CT 06250-8121 (United States); Buton, C.; Kerschhaggl, M.; Kowalski, M. [Physikalisches Institut, Universitaet Bonn, Nussallee 12, D-53115 Bonn (Germany); Chotard, N.; Copin, Y.; Gangler, E. [Universite de Lyon, F-69622, Lyon (France); Universite de Lyon 1, Villeurbanne (France); CNRS/IN2P3, Institut de Physique Nucleaire de Lyon (France); and others

    2013-06-20

    We examine the relationship between Type Ia supernova (SN Ia) Hubble residuals and the properties of their host galaxies using a sample of 115 SNe Ia from the Nearby Supernova Factory. We use host galaxy stellar masses and specific star formation rates fitted from photometry for all hosts, as well as gas-phase metallicities for a subset of 69 star-forming (non-active galactic nucleus) hosts, to show that the SN Ia Hubble residuals correlate with each of these host properties. With these data we find new evidence for a correlation between SN Ia intrinsic color and host metallicity. When we combine our data with those of other published SN Ia surveys, we find the difference between mean SN Ia brightnesses in low- and high-mass hosts is 0.077 {+-} 0.014 mag. When viewed in narrow (0.2 dex) bins of host stellar mass, the data reveal apparent plateaus of Hubble residuals at high and low host masses with a rapid transition over a short mass range (9.8 {<=} log (M{sub *}/M{sub Sun }) {<=} 10.4). Although metallicity has been a favored interpretation for the origin of the Hubble residual trend with host mass, we illustrate how dust in star-forming galaxies and mean SN Ia progenitor age both evolve along the galaxy mass sequence, thereby presenting equally viable explanations for some or all of the observed SN Ia host bias.

  19. PREPARATION OF POLYMER MICROSPHERES WITH PYRIDYL GROUP AND THEIR STABILIZED GOLD METALLIC COLLOIDS

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Narrow disperse poly(ethyleneglycol dimethacrylate-co-4-vinylpyridine) (poly(EGDMA-co-4-VPy)) microspheres were prepared by distillation-precipitation copolymerization of ethyleneglycol dimethacrylate (EGDMA) and 4-vinylpyridine (4-VPy) with 2,2'-azobisisobutyronitrile (AIBN) as initiator in neat acetonitrile. The polymer microspheres containing pyridyl group were then utilized as stabilizer for gold metallic colloids with the diameter around 7 nm, which were prepared by the in situ reduction of gold chloride trihydrate with sodium borohydride through the coordination of the pyridyl group on the gel layer and surface of the microsphere with the gold metallic nano-particles. The catalytic properties of the pyridyl-functionalized microsphere-stabilized gold metallic colloids and the behavior of the stabilized-catalyst for the recycling were investigated with reduction of 4-nitrophenol to 4-aminophenol as a model reaction.

  20. Aromatic H/D Exchange Reaction Catalyzed by Groups 5 and 6 Metal Chlorides

    Institute of Scientific and Technical Information of China (English)

    郭巧霞; 申宝剑; 郭海卿; 高桥保

    2005-01-01

    Groups 5 and 6 metal chlorides such as MoCl5, WCI6, NbCl5 and TaCl5 were found to be simple and very efficientcatalysts for the aromatic H/D exchange reactions. Compared with other metal chlorides such as ZnCl2, SnCl4 and TiCl4, groups 5 and 6 metal chlorides showed better catalytic activity in the H/D exchange reaction of naphthalene with C6D6. Deuteration of anthracene using MoC15 as a catalyst proceeded within 24 h at room temperature. Other aromatic compounds such as toluene, diphenylmethane and 1,1,2-triphenylethane were also deuterated smoothly in C6D6 within 24 h at room temperature.

  1. Group 3 metal stilbene complexes: Synthesis, reactivity, and electronic structure studies

    OpenAIRE

    Huang, W.; Abukhalil, PM; Khan, SI; Diaconescu, PL

    2014-01-01

    Group 3 metal (E)-stilbene complexes supported by a ferrocene diamide ligand were synthesized and characterized. Reactivity studies showed that they behave similar to analogous naphthalene complexes. Experimental and computational results indicated that the double bond was reduced and not a phenyl ring, in contrast to a previously reported uranium (E)-stilbene complex. © the Partner Organisations 2014.

  2. Lattice-Inversion Embedded-Atom-Method Interatomic Potentials for Group-VA Transition Metals

    Institute of Scientific and Technical Information of China (English)

    袁晓俭; 陈难先; 申江

    2011-01-01

    The lattice-inversion embedded-atom-method (LI-EAM) interatomic potential we developed previously [J. Phys.: Condens. Matter 22 (2010) 375503] is extended to group- VA transition metals (V, Nb and Ta). It is found that considering interatomic interactions up to appropriate-distance-neighbor atoms is crucial to constructing accurate EAM potentials, especially for the prediction of surface energy. The LI-EAM interatomic potentials for group-VA transition metals are successfully built by considering interatomic interactions up to the fifth neighbor atoms. These angular-independent potentials drastically promote the accuracy of the predicted surface energies, which match the experimental resuits well.%The lattice-inversion embedded-atom-method(LI-EAM)interatomic potential we developed previously[J.Phys.:Condens.Matter 22(2010)375503]is extended to group-VA transition metals(V,Nb and Ta).It is found that considering interatomic interactions up to appropriate-distance-neighbor atoms is crucial to constructing accurate EAM potentials,especially for the prediction of surface energy.The LI-EAM interatomic potentials for group-VA transition metals are successfully built by considering interatomic interactions up to the fifth neighbor atoms.These angular-independent potentials drastically promote the accuracy of the predicted surface energies,which match the experimental results well.

  3. Using amino acids for the chromatofocusing of metal ions on silica with bonded tetraethylenepentamine groups

    Science.gov (United States)

    Ivanov, A. V.

    2014-09-01

    Amino acid-based eluents are used for the chromatofocusing of metal ions on Tetren-SiO2 chelating sorbent (silica with bonded tetraethylenepentamine groups) for the first time. The smoothest quasilinear pH gradients form for eluents based on glutamic and aspartic acids. The separation of Mn2+, Cr3+, Co2+, Ni2+, and Cu2+ is achieved.

  4. Xinjiang Nonferrous Metals Group Achieved Annual Sales Revenue of RMB 50 Billion

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>Xinjiang Nonferrous Metals Group has officially presented the following ideas for development in the 12th Five-Year Plan period: "take effective measures such as resource integration, scale expansion, capital operation and technological innovation, etc. to boost the

  5. Pediatróia

    OpenAIRE

    Carmona da Mota, Henrique

    2014-01-01

    Os pediatras deram-se conta que tinham perdido o seu “ponto da situação”, o seu “estado da arte”, a sua rainha, a estrela polar por que se guiavam. Na lufa-lufa do trabalho diário não lhe tinham dado a atenção indispensável e ela teria ido para o outro lado do mar Egeu.Decidiram ir lá buscá-la; todos colaboraram na organização da empresa e, tendo sacrificado aos deuses e escolhido o dia fasto, rumaram a Tróia. Nem todos que alguns espartanos teriam que ficar para assegurar a defesa das suas c...

  6. Coulombic amino group-metal bonding: adsorption of adenine on Cu110.

    Science.gov (United States)

    Preuss, M; Schmidt, W G; Bechstedt, F

    2005-06-17

    The interaction between molecular amino groups and metal surfaces is analyzed from first-principles calculations using the adsorption of adenine on Cu110 as a model case. The amino group nitrogens are found to adsorb on top of the surface copper atoms. However, the bonding clearly cannot be explained in terms of covalent interactions. Instead, we find it to be largely determined by mutual polarization and Coulomb interaction between substrate and adsorbate.

  7. Investigation of complexing ability of ionites with various groups to some heavy and transition metal ions

    Directory of Open Access Journals (Sweden)

    Yedil Yergozhin

    2013-05-01

    Full Text Available The physico-chemical and complexing properties of the sorbent based on chloromethylated styrene and divinylbenzene copolymer with nicotinamide groups and copolymers based on metacryloilaminobenzene acids with 2-methyl-5-vinylpyridineisomers are studied. By potentiometric titration method the constant of polyelectrolytes functional groups ionization, the composition and strength of the resulting complexes with ions of some heavy and transition metals are determined.

  8. The oldest and most metal poor stars in the APOSTLE Local Group simulations

    CERN Document Server

    Starkenburg, Else; Navarro, Julio F; Crain, Robert A; Fattahi, Azadeh; Frenk, Carlos S; Sawala, Till; Schaye, Joop

    2016-01-01

    We examine the spatial distribution of the oldest and most metal poor stellar populations of Milky Way-sized galaxies using the APOSTLE cosmological hydrodynamical simulations of the Local Group. In agreement with earlier work, we find strong radial gradients in the fraction of the oldest (tform < 0.8 Gyr) and most metal poor ([Fe/H]< -2.5) stars, both of which increase outwards. The most metal poor stars form over an extended period of time; half of them form after z = 5.3, and the last 10% after z = 2.8. The age of the metal poor stellar population also shows significant variation with environment; a high fraction of them are old in the galaxy's central regions and an even higher fraction in some individual dwarf galaxies, with substantial scatter from dwarf to dwarf. Overall, over half of the stars that belong to both the oldest and most metal-poor population are found outside the solar circle. Somewhat counter-intuitively, we find that dwarf galaxies with a large fraction of metal poor stars that ar...

  9. Effect of functionalization of boron nitride flakes by main group metal clusters on their optoelectronic properties

    Science.gov (United States)

    Chakraborty, Debdutta; Chattaraj, Pratim Kumar

    2017-10-01

    The possibility of functionalizing boron nitride flakes (BNFs) with some selected main group metal clusters, viz. OLi4, NLi5, CLi6, BLI7 and Al12Be, has been analyzed with the aid of density functional theory (DFT) based computations. Thermochemical as well as energetic considerations suggest that all the metal clusters interact with the BNF moiety in a favorable fashion. As a result of functionalization, the static (first) hyperpolarizability (β ) values of the metal cluster supported BNF moieties increase quite significantly as compared to that in the case of pristine BNF. Time dependent DFT analysis reveals that the metal clusters can lower the transition energies associated with the dominant electronic transitions quite significantly thereby enabling the metal cluster supported BNF moieties to exhibit significant non-linear optical activity. Moreover, the studied systems demonstrate broad band absorption capability spanning the UV–visible as well as infra-red domains. Energy decomposition analysis reveals that the electrostatic interactions principally stabilize the metal cluster supported BNF moieties.

  10. Unmetallated and metallated phthalocyanines bearing oxadiazole groups: Synthesis, photophysical and photochemical studies

    Energy Technology Data Exchange (ETDEWEB)

    Nas, Asiye [Department of Chemistry, Karadeniz Technical University, 61080 Trabzon (Turkey); Kantekin, Halit, E-mail: halit@ktu.edu.tr [Department of Chemistry, Karadeniz Technical University, 61080 Trabzon (Turkey); Durmuş, Mahmut [Gebze Institute of Technology, Department of Chemistry, PO Box 141, Gebze, 41400 Kocaeli (Turkey); Gümrükçüoğlu, Nurhan [Department of Chemistry, Karadeniz Technical University, 61080 Trabzon (Turkey)

    2014-10-15

    Unmetallated (4) and metallated (zinc(II), cobalt(II), lead(II)) phthalocyanines (5–7) carrying four 4-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenoxy) groups on the peripheral positions were synthesized by cyclotetramerization of 4-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenoxy)phthalonitrile (3) in the presence of corresponding metal salts (zinc(II) acetate, cobalt(II) chloride, lead(II) oxide) for metallated and without any metal for unmetallated phthalocyanines. The obtained organo-soluble phthalocyanines were characterized by infrared, electronic absorption, nuclear magnetic resonance and mass spectral techniques and elemental analysis as well. The photophysical and photochemical properties of newly synthesized tetra-substituted unmetallated (4), zinc(II) (5) and lead(II) (7) phthalocyanines were reported in N,N-dimetilformamid (DMF). The synthesized phthalocyanine compound 6 was not evaluated for photophysical and photochemical studies due to open shell and paramagnetic behavior of cobalt(II) metal ions in the phthalocyanine cavity. - Highlights: • Synthesis of unmetallated and metallated phthalocyanines. • Photophysical and photochemical properties of tetra-substituted phthalocyanines. • Characterization of organosoluble phthalocyanines by several spectral techniques.

  11. Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes.

    Science.gov (United States)

    Maity, Ayan; Teets, Thomas S

    2016-08-10

    This Review highlights stoichiometric reactions and elementary steps of catalytic reactions involving cooperative participation of transition-metal hydrides and main group Lewis acids. Included are reactions where the transition-metal hydride acts as a reactant as well as transformations that form the metal hydride as a product. This Review is divided by reaction type, illustrating the diverse roles that Lewis acids can play in mediating transformations involving transition-metal hydrides as either reactants or products. We begin with a discussion of reactions where metal hydrides form direct adducts with Lewis acids, elaborating the structure and dynamics of the products of these reactions. The bulk of this Review focuses on reactions where the transition metal and Lewis acid act in cooperation, and includes sections on carbonyl reduction, H2 activation, and hydride elimination reactions, all of which can be promoted by Lewis acids. Also included is a section on Lewis acid-base secondary coordination sphere interactions, which can influence the reactivity of hydrides. Work from the past 50 years is included, but the majority of this Review focuses on research from the past decade, with the intent of showcasing the rapid emergence of this field and the potential for further development into the future.

  12. 30 CFR 57.22601 - Blasting from the surface (I-A mines).

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Blasting from the surface (I-A mines). 57.22601... Standards for Methane in Metal and Nonmetal Mines Explosives § 57.22601 Blasting from the surface (I-A mines... blast area and through at least one atmospheric monitoring sensor. (b) After blasting, if the...

  13. A 3D analysis of the metal distribution in the compact group of galaxies HCG 31

    Science.gov (United States)

    Torres-Flores, Sergio; Mendes de Oliveira, Claudia; Alfaro-Cuello, Mayte; Rodrigo Carrasco, Eleazar; de Mello, Duilia; Amram, Philippe

    2015-02-01

    We present new Gemini/GMOS integral field unit observations of the central region of the merging compact group of galaxies HCG 31. Using this data set, we derive the oxygen abundances for the merging galaxies HCG 31A and HCG 31C. We found a smooth metallicity gradient between the nuclei of these galaxies, suggesting a mixing of metals between these objects. These results are confirmed by high-resolution Fabry-Perot data, from which we infer that gas is flowing between HCG 31A and HCG 31C.

  14. Reviews of Metallurgical Technology to Recovery Platinum Group Metals from Secondary Resource in China

    Institute of Scientific and Technical Information of China (English)

    GUO Junmei; HE Xiaotang; WANG Huan; WU Xilong; ZHAO Yu; LI Yong; LI Kun; HAN Shouli

    2012-01-01

    China is extremely poor in mineral resources of Platinum Group Metals (PGMs),productive output of PGMs from mineral resource is 2.5 tons per year.At the same time,China is the biggest PGMs consumption country in the world,the mineral resource of PGMs is critical shortage,it shows the importance of recycling the secondary resource of PGMs.Sino-Platinum Metals Resource (Yimen) Co.,Ltd.is the leader in recycling of PGMs from secondary resource,and has made outstanding contributions to China PGMs secondary resources recycling.This article elucidates the current situation of secondary resources recovery and development of metallurgical technology for PGMs.

  15. The diversity of Type Ia Supernovae: evidence for systematics?

    CERN Document Server

    Benetti, S; Mazzali, P A; Turatto, M; Altavilla, G; Bufano, F; Elias-Rosa, N; Kotak, R; Pignata, G; Salvo, M; Stanishev, V

    2004-01-01

    The photometric and spectroscopic properties of 26 well observed Type Ia Supernovae (SNeIa) were analyzed with the aim to explore SNIa diversity. The sample includes (Branch-)normal SNe as well as extreme events like SNe 1991T and 1991bg, while the truly peculiar SNIa, SN2000cx and SN2002cx are not included in our sample . A statistical treatment reveals the existence of three different groups. The first group (FAINT) consists of faint SNeIa similar to SN1991bg, with low expansion velocities and rapid evolution of SiII velocity. A second group consists of ``normal'' SNeIa, also with high temporal velocity gradient (HVG), but with brighter mean absolute magnitude =-19.3 and higher expansion velocities than the FAINT SNe. The third group includes both ``normal'' and SN1991T-like SNeIa: these SNe populate a narrow strip in the SiII velocity evolution plot, with a small velocity gradient (SVG), but have absolute magnitudes similar to HVGs. While the FAINT and HVG SNeIa together seem to define a relation between R...

  16. Cosmic Supernova Rate History and Type Ia Supernova Progenitors

    OpenAIRE

    Kobayashi, Chiaki; Nomoto, Ken'ichi; Tsujimoto, Takuji

    2001-01-01

    Adopting a single degenerate scenario for Type Ia supernova progenitors with the metallicity effect, we make a prediction of the cosmic supernova rate history as a composite of the supernova rates in spiral and elliptical galaxies, and compare with the recent observational data up to z ~ 0.55.

  17. Neutronization During Carbon Simmering In Type Ia Supernova Progenitors

    Science.gov (United States)

    Martínez-Rodríguez, Héctor; Piro, Anthony L.; Schwab, Josiah; Badenes, Carles

    2016-07-01

    When a Type Ia supernova (SN Ia) progenitor first ignites carbon in its core, it undergoes ˜103-104 years of convective burning prior to the onset of thermonuclear runaway. This carbon simmering phase is important for setting the thermal profile and composition of the white dwarf. Using the MESA stellar evolution code, we follow this convective burning and examine the production of neutron-rich isotopes. The neutron content of the SN fuel has important consequences for the ensuing nucleosynthesis, and in particular, for the production of secondary Fe-peak nuclei like Mn and stable Ni. These elements have been observed in the X-ray spectra of SN remnants like Tycho, Kepler, and 3C 397, and their yields can provide valuable insights into the physics of SNe Ia and the properties of their progenitors. We find that weak reactions during simmering can at most generate a neutron excess of ≈ 3 × 10-4. This is ≈ 70% lower than that found in previous studies that do not take the full density and temperature profile of the simmering region into account. Our results imply that the progenitor metallicity is the main contributor to the neutron excess in SN Ia fuel for Z ≳ 1/3 Z ⊙. Alternatively, at lower metallicities, this neutron excess provides a floor that should be present in any centrally-ignited SN Ia scenario.

  18. NGC 6845: metallicity gradients and star formation in a complex compact group

    CERN Document Server

    Olave-Rojas, D; Carrasco, E R; de Oliveira, C Mendes; de Mello, D F; Scarano, S

    2015-01-01

    We have obtained Gemini/GMOS spectra of 28 regions located across the interacting group NGC 6845, spanning from the inner regions of the four major galaxies (NGC 6845A, B, C, D) to the tidal tails of NGC 6845A. All regions in the tails are star-forming objects with ages younger than 10 Myr. We derived the gas-phase metallicity gradients across NGC 6845A and its two tails and we find that these are shallower than those for isolated galaxies. NGC 6845A has a gas-phase oxygen central metallicity of \\mbox{12+log(O/H)$\\sim$8.5} and a flat gas-phase metallicity gradient ($\\beta$=0.002$\\pm$0.004 dex kpc$^{-1}$) out to $\\sim$4 $\\times$ R$_{25}$ (to the end of the longest tidal tail). Considering the mass-metallicity relation, the central region of NGC 6845A displays a lower oxygen abundance than the expected for its mass. Taking into account this fact and considering the flat oxygen distribution measured along the eastern tidal tail, we suggest that an interaction event has produced a dilution in the central metallic...

  19. Probing the bonding of CO to heteronuclear group 4 metal-nickel clusters by photoelectron spectroscopy.

    Science.gov (United States)

    Zou, Jinghan; Xie, Hua; Yuan, Qinqin; Zhang, Jumei; Dai, Dongxu; Fan, Hongjun; Tang, Zichao; Jiang, Ling

    2017-04-12

    A series of heterobinuclear group 4 metal-nickel carbonyls MNi(CO)n(-) (M = Ti, Zr, Hf; n = 3-7) has been generated via a laser vaporization supersonic cluster source and characterized by mass-selected photoelectron velocity-map imaging spectroscopy. Quantum chemical calculations have been carried out to elucidate the geometric and electronic structures and support the spectral assignments. The n = 3 cluster is determined to be capable of simultaneously accommodating three different types of CO bonds (i.e., side-on-bonded, bridging, and terminal modes), resulting in a MNi[η(2)(μ2-C, O)](μ-CO)(CO)(-) structure, which represents the smallest metal carbonyl with the involvement of all the main modes of metal-CO coordination to date. The building block of three bridging CO molecules is favored at n = 4, the structure of which persists up to n = 7. The additional CO ligands are bonded terminally to the metal atoms. The present findings provide important new insight into the structure and bonding mechanisms of CO molecules with heteronuclear transition metals, which would have important implications for understanding chemisorbed CO molecules on alloy surfaces.

  20. High-temperature mass spectrometry - Vaporization of group 4-B metal carbides. [using Knudsen effusion

    Science.gov (United States)

    Stearns, C. A.; Kohl, F. J.

    1974-01-01

    The high temperature vaporization of the metal-carbon systems TiC, ZrC, HfC, and ThC was studied by the Knudsen effusion - mass spectrometric method. For each system the metal dicarbide and tetracarbide molecular species were identified in the gas phase. Relative ion currents of the carbides and metals were measured as a function of temperature. Second- and third-law methods were used to determine enthalpies. Maximum values were established for the dissociation energies of the metal monocarbide molecules TiC, ZrC, HfC, and ThC. Thermodynamic functions used in the calculations are discussed in terms of assumed molecular structures and electronic contributions to the partition functions. The trends shown by the dissociation energies of the carbides of Group 4B are compared with those of neighboring groups and discussed in relation to the corresponding oxides and chemical bonding. The high temperature molecular beam inlet system and double focusing mass spectrometer are described.

  1. Standardization of type Ia supernovae

    CERN Document Server

    Coelho, Rodrigo C V; Reis, Ribamar R R; Siffert, Beatriz B

    2014-01-01

    Type Ia supernovae (SNe Ia) have been intensively investigated due to its great homogeneity and high luminosity, which make it possible to use them as standardizable candles for the determination of cosmological parameters. In 2011, the physics Nobel prize was awarded for the discovery of the accelerating expansion of the Universe through observations of distant supernovae. This is a pedagogical article, aimed at those starting their study of that subject, in which we dwell on some topics related to the analysis of SNe Ia and their use in luminosity distance estimators. Here we investigate their spectral properties and light curve standardization, paying careful attention to the fundamental quantities directly related to the SNe Ia observables. Finally, we describe our own step-by-step implementation of a classical light curve fi?tter, the stretch, applying it to real data from the Carnegie Supernova Project.

  2. Xinjiang Nonferrous Metal Group is Developing on Low-cost Expanding

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>Xinjiang Xinxin Mining Industry Co.,Ltd., whose shareholder is Xinjiang Nonferrous Metal Group,issued a report through the Stock Exchange of Hong Kong Limited,or SEHK, that the company had made a 542.25 million yuan takeover of Yakesi Resources Develop- ment Co.,Ltd.and Hami Jubao Resource De- velopment Co.,Ltd.,the biggest copper nickel exploitation company in Hami area.This is the largest scale takeover since Xinxin became a

  3. Retention of heavy metals by carboxyl functional groups of biochars in small arms range soil.

    Science.gov (United States)

    Uchimiya, Minori; Bannon, Desmond I; Wartelle, Lynda H

    2012-02-22

    Long-term effectiveness of biochar for heavy metal stabilization depends upon biochar's sorptive property and recalcitrance in soil. To understand the role of carboxyl functional groups on heavy metal stabilization, cottonseed hull biochar and flax shive steam-activated biochar having a low O/C ratio (0.04-0.06) and high fixed carbon content (~80% dry weight basis) were oxidized using concentrated H(2)SO(4)/HNO(3) and 30% HNO(3). Oxidized and unoxidized biochars were characterized for O/C ratio, total acidity, pH, moisture, ash, volatile matter, and fixed carbon contents, Brunauer-Emmett-Teller surface area, and attenuated total reflectance Fourier transform infrared spectral features. Characterized biochars were amended (2%, 5%, 10%, and 20% in grams of biochar per gram of soil) on a sandy, slightly acidic (pH 6.27) heavy metal contaminated small arms range soil fraction (carbon (0.518%) and low cation exchange capacity (0.95 cmol(c) kg(-1)). Oxidized biochars rich in carboxyl functional groups exhibited significantly greater Pb, Cu, and Zn stabilization ability compared to unoxidized biochars, especially in pH 4.9 acetate buffer (standard solution for the toxicity characteristic leaching procedure). Oppositely, only oxidized biochars caused desorption of Sb, indicating a counteracting impact of carboxyl functional groups on the solubility of anions and cations. The results suggested that appropriate selection of biochar oxidant will produce recalcitrant biochars rich in carboxyl functional groups for a long-term heavy metal stabilization strategy in contaminated soils.

  4. Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands

    NARCIS (Netherlands)

    Cabon, Y.; Kleijn, H.; Siegler, M. A.; Spek, A.L.; Klein Gebbink, R.J.M.; Deelman, B.J.

    2010-01-01

    The reaction of tin dichloride with catalytically-relevant group 10 metal precursors [M(Cl)(X)(2-PyPPh2)2] (M = Ni, Pd, Pt; 2-PyPPh2 = 2-pyridyldiphenylphosphine; X = Cl, Me) provides easy access to unprecedented cationic dichlorostannylene complexes [M(X)(2-PyPPh2)2(SnCl2)]+ where the M–Sn bond is

  5. Comparison between alkalimetal and group 11 transition metal halide and hydride tetramers: molecular structure and bonding.

    Science.gov (United States)

    El-Hamdi, Majid; Solà, Miquel; Frenking, Gernot; Poater, Jordi

    2013-08-22

    A comparison between alkalimetal (M = Li, Na, K, and Rb) and group 11 transition metal (M = Cu, Ag, and Au) (MX)4 tetramers with X = H, F, Cl, Br, and I has been carried out by means of the Amsterdam Density Functional software using density functional theory at the BP86/QZ4P level of theory and including relativistic effects through the ZORA approximation. We have obtained that, in the case of alkalimetals, the cubic isomer of Td geometry is more stable than the ring structure with D4h symmetry, whereas in the case of group 11 transition metal tetramers, the isomer with D4h symmetry (or D2d symmetry) is more stable than the Td form. To better understand the results obtained we have made energy decomposition analyses of the tetramerization energies. The results show that in alkalimetal halide and hydride tetramers, the cubic geometry is the most stable because the larger Pauli repulsion energies are compensated by the attractive electrostatic and orbital interaction terms. In the case of group 11 transition metal tetramers, the D4h/D2d geometry is more stable than the Td one due to the reduction of electrostatic stabilization and the dominant effect of the Pauli repulsion.

  6. Carbide-forming groups IVB-VIB metals: a new territory in the periodic table for CVD growth of graphene.

    Science.gov (United States)

    Zou, Zhiyu; Fu, Lei; Song, Xiuju; Zhang, Yanfeng; Liu, Zhongfan

    2014-07-09

    Early transition metals, especially groups IVB-VIB metals, can form stable carbides, which are known to exhibit excellent "noble-metal-like" catalytic activities. We demonstrate herein the applications of groups IVB-VIB metals in graphene growth using atmospheric pressure chemical vapor deposition technique. Similar to the extensively studied Cu, Ni, and noble metals, these transition-metal foils facilitate the catalytic growth of single- to few-layer graphene. The most attractive advantage over the existing catalysts is their perfect control of layer thickness and uniformity with highly flexible experimental conditions by in situ converting the dissolved carbons into stable carbides to fully suppress the upward segregation/precipitation effect. The growth performance of graphene on these transition metals can be well explained by the periodic physicochemical properties of elements. Our work has disclosed a new territory of catalysts in the periodic table for graphene growth and is expected to trigger more interest in graphene research.

  7. WITNESSING GAS MIXING IN THE METAL DISTRIBUTION OF THE HICKSON COMPACT GROUP HCG 31

    Energy Technology Data Exchange (ETDEWEB)

    Torres-Flores, S.; Alfaro-Cuello, M. [Departamento de Física, Universidad de La Serena, Av. Cisternas 1200, La Serena (Chile); De Oliveira, C. Mendes [Instituto de Astronomia, Geofísica e Ciências Atmosféricas da Universidade de São Paulo, Cidade Universitária, CEP:05508-900, São Paulo, SP (Brazil); Amram, P. [Aix Marseille Université, CNRS, LAM (Laboratoire d' Astrophysique de Marseille) UMR 7326, F-13388, Marseille (France); Carrasco, E. R. [Gemini Observatory/AURA, Southern Operations Center, Casilla 603, La Serena (Chile); De Mello, D. F., E-mail: storres@dfuls.cl [Catholic University of America, Washington, DC 20064 (United States)

    2015-01-01

    We present for the first time direct evidence that in a merger of disk galaxies, the pre-existing central metallicities will mix as a result of gas being transported in the merger interface region along the line that joins the two coalescing nuclei. This is shown using detailed two-dimensional kinematics as well as metallicity measurements for the nearby ongoing merger in the center of the compact group HCG 31. We focus on the emission line gas, which is extensive in the system. The two coalescing cores display similar oxygen abundances. While in between the two nuclei, the metallicity changes smoothly from one nucleus to the other indicating a mix of metals in this region, which is confirmed by the high-resolution Hα kinematics (R = 45,900). This nearby system is especially important because it involves the merging of two fairly low-mass and clumpy galaxies (LMC-like galaxies), making it an important system for comparison with high-redshift galaxies.

  8. Energetics of small clusters of group IB metals (Cu, Ag, and Au) adsorbed on graphene

    Science.gov (United States)

    Kaur, Gagandeep; Gupta, Shuchi; Dharamvir, Keya

    2013-06-01

    The 2D structure of graphene maximizes the interaction of adsorbate on the layer. Many experiments have been devised to form stable metallic clusters of different sizes. We study the structure and binding energies of group IB clusters Mn (M=Au, Ag, Cu n=1, 3) adsorbed on graphene using Gupta potential [1] (for M-M interaction) and Lennard-Jones potential [2] (for metal-carbon interaction). The total energy of the system has been obtained by placing each of Mn cluster a certain distance above the graphene sheet at various positions and in various orientations. The minimized energy configurations, for all Mn clusters, lie above the center of a hexagon and parallel to the graphene sheet. Binding energy per atom for Ag and Cu metal clusters are less than those of respective Au indicating the lower stability of Ag/Cu metal-graphene system. Using various energy barriers, we can calculate the energy required to move small cluster from one position of minimum energy to another on graphene.

  9. Type Ia Supernova Properties as a Function of the Distance to the Host Galaxy in the SDSS-II SN Survey

    Energy Technology Data Exchange (ETDEWEB)

    Galbany, Lluis [Institut de Fisica d' Altes Energies (IFAE), Barcelona (Spain); et al.

    2012-08-20

    We use type-Ia supernovae (SNe Ia) discovered by the SDSS-II SN Survey to search for dependencies between SN Ia properties and the projected distance to the host galaxy center, using the distance as a proxy for local galaxy properties (local star-formation rate, local metallicity, etc.). The sample consists of almost 200 spectroscopically or photometrically confirmed SNe Ia at redshifts below 0.25. The sample is split into two groups depending on the morphology of the host galaxy. We fit light-curves using both MLCS2k2 and SALT2, and determine color (AV, c) and light-curve shape (delta, x1) parameters for each SN Ia, as well as its residual in the Hubble diagram. We then correlate these parameters with both the physical and the normalized distances to the center of the host galaxy and look for trends in the mean values and scatters of these parameters with increasing distance. The most significant (at the 4-sigma level) finding is that the average fitted AV from MLCS2k2 and c from SALT2 decrease with the projected distance for SNe Ia in spiral galaxies. We also find indications that SNe in elliptical galaxies tend to have narrower light-curves if they explode at larger distances, although this may be due to selection effects in our sample. We do not find strong correlations between the residuals of the distance moduli with respect to the Hubble flow and the galactocentric distances, which indicates a limited correlation between SN magnitudes after standardization and local host metallicity.

  10. Cycloadditions to Epoxides Catalyzed by GroupIII-V Transition-Metal Complexes

    KAUST Repository

    D'Elia, Valerio

    2015-05-25

    Complexes of groupIII-V transition metals are gaining increasing importance as Lewis acid catalysts for the cycloaddition of dipolarophiles to epoxides. This review examines the latest reports, including homogeneous and heterogeneous applications. The pivotal step for the cycloaddition reactions is the ring opening of the epoxide following activation by the Lewis acid. Two modes of cleavage (C-C versus C-O) have been identified depending primarily on the substitution pattern of the epoxide, with lesser influence observed from the Lewis acid employed. The widely studied cycloaddition of CO2 to epoxides to afford cyclic carbonates (C-O bond cleavage) has been scrutinized in terms of catalytic efficiency and reaction mechanism, showing that unsophisticated complexes of groupIII-V transition metals are excellent molecular catalysts. These metals have been incorporated, as well, in highly performing, recyclable heterogeneous catalysts. Cycloadditions to epoxides with other dipolarophiles (alkynes, imines, indoles) have been conducted with scandium triflate with remarkable performances (C-C bond cleavage). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Highly Fluorescent Group 13 Metal Complexes with Cyclic, Aromatic Hydroxamic Acid Ligands

    Energy Technology Data Exchange (ETDEWEB)

    Seitz, Michael; Moore, Evan G.; Raymond, Kenneth N.

    2008-02-11

    The neutral complexes of two ligands based on the 1-oxo-2-hydroxy-isoquinoline (1,2-HOIQO) motif with group 13 metals (Al, Ga, In) show bright blue-violet luminescence in organic solvents. The corresponding transition can be attributed to ligand-centered singlet emission, characterized by a small Stokes shifts of only a few nm combined with lifetimes in the range between 1-3 ns. The fluorescence efficiency is high, with quantum yields of up to 37% in benzene solution. The crystal structure of one of the indium(III) complexes (trigonal space group R-3, a = b = 13.0384(15) {angstrom}, c = 32.870(8) {angstrom}, ? = {beta} = 90{sup o}, {gamma} = 120{sup o}, V = 4839.3(14) {angstrom}{sup 3}, Z = 6) shows a six-coordinate geometry around the indium center which is close to trigonal-prismatic, with a twist angle between the two trigonal faces of 20.7{sup o}. Time-dependent density functional theory (TD-DFT) calculations (Al and Ga: B3LYP/6-31G(d)); In: B3LYP/LANL2DZ of the fac and mer isomers with one of the two ligands indicate that there is no clear preference for either one of the isomeric forms of the metal complexes. In addition, the metal centers do not have a significant influence on the electronic structure, and as a consequence, on the predominant intraligand optical transitions.

  12. ALLOYING-DRIVEN PHASE STABILITY IN GROUP-VB TRANSITION METALS UNDER COMPRESSION

    Energy Technology Data Exchange (ETDEWEB)

    Landa, A; Soderlind, P

    2011-04-11

    The change in phase stability of Group-VB (V, Nb, and Ta) transition metals due to pressure and alloying is explored by means of first-principles electronic-structure calculations. It is shown that under compression stabilization or destabilization of the ground-state body-centered cubic (bcc) phase of the metal is mainly dictated by the band-structure energy that correlates well with the position of the Kohn anomaly in the transverse acoustic phonon mode. The predicted position of the Kohn anomaly in V, Nb, and Ta is found to be in a good agreement with data from the inelastic x-ray or neutron scattering measurements. In the case of alloying the change in phase stability is defined by the interplay between the band-structure and Madelung energies. We show that band-structure effects determine phase stability when a particular Group-VB metal is alloyed with its nearest neighbors within the same d-transition series: the neighbor with less and more d electrons destabilize and stabilize the bcc phase, respectively. When V is alloyed with neighbors of a higher (4d- or 5d-) transition series, both electrostatic Madelung and band-structure energies stabilize the body-centered-cubic phase. The opposite effect (destabilization) happens when Nb or Ta is alloyed with neighbors of the 3d-transition series.

  13. 30 CFR 57.22401 - Underground retorts (I-A and I-B mines).

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground retorts (I-A and I-B mines). 57... METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Safety Standards for Methane in Metal and Nonmetal Mines Underground Retorts § 57.22401...

  14. The two metallicity groups of the globular cluster M22: a chemical perspective

    CERN Document Server

    Marino, A F; Kraft, R P; Wallerstein, G; Norris, J E; Da Costa, G; Milone, A P; Ivans, I I; Gonzalez, G; Fulbright, J P; Hilker, M; Piotto, G; Zoccali, M; Stetson, P B

    2011-01-01

    We present a detailed chemical composition analysis of 35 red giant stars in the globular cluster M22. High resolution spectra for this study were obtained at five observatories, and analyzed in a uniform manner. We have determined abundances of representative light proton-capture, alpha, Fe-peak and neutron-capture element groups. Our aim is to better understand the peculiar chemical enrichment history of this cluster, in which two stellar groups are characterized by a different content in iron, neutron capture elements Y, Zr and Ba, and alpha element Ca. The principal results of this study are: (i) substantial star-to-star metallicity scatter (-2.0<[Fe/H]<-1.6); (ii) enhancement of s-process/r-process neutron-capture abundance ratios in a fraction of giants, positively correlated with metallicity; (iii) sharp separation between the s-process rich and s-process poor groups by [La/Eu] ratio; (iv) possible increase of [Cu/Fe] ratios with increasing [Fe/H], suggesting that this element also has a signific...

  15. Understanding hydrogen sorption in a metal-organic framework with open-metal sites and amide functional groups

    KAUST Repository

    Pham, Tony T.

    2013-05-09

    Grand canonical Monte Carlo (GCMC) studies of the mechanism of hydrogen sorption in an rht-MOF known as Cu-TPBTM are presented. The MOF is a decorated/substituted isostructural analogue to the unembellished rht-MOF, PCN-61, that was studied previously [ Forrest, K. A.J. Phys. Chem. C 2012, 116, 15538-15549. ]. The simulations were performed using three different hydrogen potentials of increasing complexity. Simulated hydrogen sorption isotherms and calculated isosteric heat of adsorption, Qst, values were in excellent agreement with the reported experimental data for only a polarizable model in one of four experimentally observed crystal structure configurations. The study demonstrates the ability of modeling to distinguish the differential sorption of distinct strucures; one configuration is found to be dominant due to favorable interactions with substrates. In addition, it was discovered that the presence of polar amide groups had a significant effect on the electrostatics of the Cu2+ ions and directs the low-pressure physisorption of hydrogen in the MOF. This is in contrast to what was observed in PCN-61, where an exterior copper ion had a higher relative charge and was the favored loading site. This tunability of the electrostatics of the copper ions via chemical substitution on the MOF framework can be explained by the presence of the negatively charged oxygen atom of the amide group that causes the interior Cu2+ ion to exhibit a higher positive charge through an inductive effect. Further, control simulations, taking advantage of the flexibility afforded by theoretical modeling, include artificially modified charges for both Cu2+ ions chosen equal to or with a higher charge on the exterior Cu2+ ion. This choice resulted in distinctly different hydrogen sorption characteristics in Cu-TPBTM with no direct sorption on the open-metal sites. Thus, this study demonstrates both the tunable nature of MOF platforms and the possibility for rational design of sorption

  16. sEcad and EGF Levels Increased in Urine of Non-ferrous Metal Workers and Medium of Uroepithelial Cell Line Treated by Arsenic.

    Science.gov (United States)

    Liu, Jieyu; Jin, Peiyu; Liu, Shengnan; Wang, Fei; Wang, Xiaoyan; Yang, Li; Xi, Shuhua

    2017-08-17

    Inorganic arsenic (iAs) is a carcinogen and could increase the risks of bladder, lung, and skin cancer. Mining and smelting of non-ferrous metals are common occupational arsenic exposures. In this study, 125 individuals working in non-ferrous metal smelting plants were separated into two groups according to urinary total arsenic (TAs) levels: group 1, TAs ferrous metal plants and are closely associated with urinary iAs concentration. The results suggested that sEcad and EGF may potentially be preclinical prognostic factors of bladder injury and early detection in arsenic exposure individuals.

  17. Progenitors of Supernovae Type Ia

    CERN Document Server

    Toonen, S; Bours, M; Zwart, S Portegies; Claeys, J; Mennekens, N; Ruiter, A

    2013-01-01

    Despite the significance of Type Ia supernovae (SNeIa) in many fields in astrophysics, SNeIa lack a theoretical explanation. The standard scenarios involve thermonuclear explosions of carbon/oxygen white dwarfs approaching the Chandrasekhar mass; either by accretion from a companion or by a merger of two white dwarfs. We investigate the contribution from both channels to the SNIa rate with the binary population synthesis (BPS) code SeBa in order to constrain binary processes such as the mass retention efficiency of WD accretion and common envelope evolution. We determine the theoretical rates and delay time distribution of SNIa progenitors and in particular study how assumptions affect the predicted rates.

  18. Leaching platinum-group metals in a sulfuric acid/chloride solution

    Science.gov (United States)

    Mahmoud, M. H. H.

    2003-04-01

    A leaching process was established based on the ability of platinum-group metals to form stable chloro-complexes in acidic chloride solutions. Industrial catalyst losses were examined for the recovery of platinum, palladium, and rhodium by leaching with a mixture of sulfuric acid and sodium chloride to avoid using aqua regia or autoclave conditions. Extraction of platinum and rhodium in 60% H2SO4 at 135°C steadily increased with increasing NaCl concentrations reaching 95% and 85%, respectively, at 0.1 M NaCl after two hours. By comparison, palladium was dissolved more quickly but also reached 85% under the same conditions. Extraction of each metal increased with temperatures up to 125°C but plateaued at higher temperatures. Similar behavior was observed with increasing H2SO4 concentrations up to 60%. More than 99% extraction of each metal was obtained after ten hours using 0.1 M NaCl and 60% H2SO4 at 125°C.

  19. Host Galaxy Properties and Hubble Residuals of Type Ia Supernovae from the Nearby Supernova Factory

    CERN Document Server

    Childress, M J; Antilogus, P; Aragon, C; Bailey, S; Baltay, C; Bongard, S; Buton, C; Canto, A; Cellier-Holzem, F; Chotard, N; Copin, Y; Fakhouri, H K; Gangler, E; Guy, J; Hsiao, E Y; Kerschhaggl, M; Kim, A G; Kowalski, M; Loken, S; Nugent, P; Paech, K; Pain, R; Pecontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Rigault, M; Runge, K; Scalzo, R; Smadja, G; Tao, C; Thomas, R C; Weaver, B A; Wu, C

    2013-01-01

    We examine the relationship between Type Ia Supernova (SN Ia) Hubble residuals and the properties of their host galaxies using a sample of 115 SNe Ia from the Nearby Supernova Factory (SNfactory). We use host galaxy stellar masses and specific star-formation rates fitted from photometry for all hosts, as well as gas-phase metallicities for a subset of 69 star-forming (non-AGN) hosts, to show that the SN Ia Hubble residuals correlate with each of these host properties. With these data we find new evidence for a correlation between SN Ia intrinsic color and host metallicity. When we combine our data with those of other published SN Ia surveys, we find the difference between mean SN Ia brightnesses in low and high mass hosts is 0.077 +- 0.014 mag. When viewed in narrow (0.2 dex) bins of host stellar mass, the data reveal apparent plateaus of Hubble residuals at high and low host masses with a rapid transition over a short mass range (9.8 <= log(M_*/M_Sun) <= 10.4). Although metallicity has been a favored i...

  20. Dust around Type Ia supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Lifan

    2005-10-20

    An explanation is given of the low value of R lambda triple bond A lambda/E(B - V), the ratio of absolute to selective extinction deduced from Type Ia supernova observations. The idea involves scattering by dust clouds located in the circumstellar environment, or at the highest velocity shells of the supernova ejecta. The scattered light tends to reduce the effective R lambda in the optical, but has an opposite effect in the ultraviolet. The presence of circumstellar dust can be tested by ultraviolet to near infrared observations and by multi-epoch spectropolarimetry of SNe Ia.

  1. Extrinsic Hardening of Superhard Tungsten Tetraboride Alloys with Group 4 Transition Metals.

    Science.gov (United States)

    Akopov, Georgiy; Yeung, Michael T; Turner, Christopher L; Mohammadi, Reza; Kaner, Richard B

    2016-05-04

    Alloys of tungsten tetraboride (WB4) with the group 4 transition metals, titanium (Ti), zirconium (Zr), and hafnium (Hf), of different concentrations (0-50 at. % on a metals basis) were synthesized by arc-melting in order to study their mechanical properties. The phase composition and purity of the as-synthesized samples were confirmed using powder X-ray diffraction (PXRD) and energy dispersive X-ray spectroscopy (EDS). The solubility limit as determined by PXRD is 20 at. % for Ti, 10 at. % for Zr, and 8 at. % for Hf. Vickers indentation measurements of WB4 alloys with 8 at. % Ti, 8 at. % Zr, and 6 at. % Hf gave hardness values, Hv, of 50.9 ± 2.2, 55.9 ± 2.7 and 51.6 ± 2.8 GPa, respectively, compared to 43.3 GPa for pure WB4 under an applied load of 0.49 N. Each of the aforementioned compositions are considered superhard (Hv > 40 GPa), likely due to extrinsic hardening that plays a key role in these superhard metal borides. Furthermore, these materials exhibit a significantly reduced indentation size effect, which can be seen in the plateauing hardness values for the W1-xZrxB4 alloy. In addition, W0.92Zr0.08B4, a product of spinoidal decomposition, possesses nanostructured grains and enhanced grain hardening. The hardness of W0.92Zr0.08B4 is 34.7 ± 0.65 GPa under an applied load of 4.9 N, the highest value obtained for any superhard metal at this relatively high loading. In addition, the WB4 alloys with Ti, Zr, and Hf showed a substantially increased oxidation resistance up to ∼460 °C, ∼510 °C, and ∼490 °C, respectively, compared to ∼400 °C for pure WB4.

  2. Witnessing Gas Mixing in the Metal Distribution of the Hickson Compact Group HCG 31

    Science.gov (United States)

    Torres-Flores, S.; Mendes de Oliveira, C.; Amram, P.; Alfaro-Cuello, M.; Carrasco, E. R.; de Mello, D. F.

    2015-01-01

    We present for the first time direct evidence that in a merger of disk galaxies, the pre-existing central metallicities will mix as a result of gas being transported in the merger interface region along the line that joins the two coalescing nuclei. This is shown using detailed two-dimensional kinematics as well as metallicity measurements for the nearby ongoing merger in the center of the compact group HCG 31. We focus on the emission line gas, which is extensive in the system. The two coalescing cores display similar oxygen abundances. While in between the two nuclei, the metallicity changes smoothly from one nucleus to the other indicating a mix of metals in this region, which is confirmed by the high-resolution Hα kinematics (R = 45,900). This nearby system is especially important because it involves the merging of two fairly low-mass and clumpy galaxies (LMC-like galaxies), making it an important system for comparison with high-redshift galaxies. Based on observations obtained at the Gemini Observatory, which is operated by the Association of Universities for Research in Astronomy, Inc., under a cooperative agreement with the NSF on behalf of the Gemini partnership: the National Science Foundation (United States), the Science and Technology Facilities Council (United Kingdom), the National Research Council (Canada), CONICYT (Chile), the Australian Research Council (Australia), Ministério da Ciência e Tecnologia (Brazil) and Ministerio de Ciencia, Tecnología e Innovación Productiva (Argentina) - Observing run: GS-2012B-Q-60.

  3. The Host Galaxies of Type Ia Supernovae Discovered by the Palomar Transient Factory

    Science.gov (United States)

    Pan, Y.-C.; Sullivan, M.; McGuire, K.; Hook, I. M.; Nugent, P. E.; Howell, D. A.; Arcavi, I.; Botyanszki, J.; Cenko, Stephen Bradley; DeRose, J.

    2013-01-01

    We present spectroscopic observations of the host galaxies of 82 low-redshift type Ia supernovae (SNe Ia) discovered by the Palomar Transient Factory (PTF). We determine star-formation rates, gas-phase stellar metallicities, and stellar masses and ages of these objects. As expected, strong correlations between the SN Ia light-curve width (stretch) and the host age mass metallicity are found: fainter, faster-declining events tend to be hosted by older massive metal-rich galaxies. There is some evidence that redder SNe Ia explode in higher metallicity galaxies, but we found no relation between the SN colour and host galaxy extinction based on the Balmer decrement, suggesting that the colour variation of these SNe does not primarily arise from this source. SNe Ia in higher-mass metallicity galaxies also appear brighter after stretch colour corrections than their counterparts in lower mass hosts, and the stronger correlation is with gas-phase metallicity suggesting this may be the more important variable. We also compared the host stellar mass distribution to that in galaxy targeted SN surveys and the high-redshift untargeted Supernova Legacy Survey (SNLS). SNLS has many more low mass galaxies, while the targeted searches have fewer. This can be explained by an evolution in the galaxy stellar mass function, coupled with a SN delay-time distribution proportional to t1. Finally, we found no significant difference in the mass--metallicity relation of our SN Ia hosts compared to field galaxies, suggesting any metallicity effect on the SN Ia rate is small.

  4. Detailed Iron-Group Abundances in a Very Metal-Poor Main Sequence Turnoff Star

    Science.gov (United States)

    Sneden, Chris; Roederer, Ian U.; Boesgaard, Ann M.; Lawler, James E.; Den Hartog, Elizabeth; Cowan, John J.; Sobeck, Jennifer

    2017-01-01

    We have obtained Keck HIRES and HST STIS high resolution, high signal-to-noise spectra of the very metal-poor ([Fe/H] ~ -2.9) main-sequence turnoff star BD+03 740. A detailed chemical composition analysis based on synthetic spectrum computations has been conducted. Our initial focus has been on the iron-group elements in the Z = 21-28 range. This study takes advantage of recent improvements in neutral and ionzied species transition data for all of these elements except Sc (Z = 21) by the Wisconsin atomic physics group (see a companion presentation on Cr II at this meeting). Several metal-poor abundance surveys have concluded that there are large overabundances of Co and underabundances of Cr with respect to Fe for stars with [Fe/H] synthesis in the Galaxy.This work has been supported by HST STScI Program GO-14232; and NSF grants AST-1211585 and AST-1616040 to CS; AST-1516182 to JEL and EDH; NASA grant NNX16AE96G to JEL

  5. HIGHLY REFRACTORY CRUCIBLES OF STABILIZED ZIRCONIA FOR INDUCTION MELTING OF THE PLATINUM GROUP METALS, FABRICATED BY VIBROCASTING

    Directory of Open Access Journals (Sweden)

    V. V. Primachenko

    2012-01-01

    Full Text Available As the result of the studies at PJSC « UKRNIIO them. A.S.Berezhnogo» the technology and commercial production of crucibles from stabilized zirconia for the smelting of platinum group metals are develop

  6. Oxidative addition of disulfide/diselenide to group 10 metal(0) and in situ functionalization to form neutral thiasalen/selenasalen group 10 metal(II) complexes.

    Science.gov (United States)

    Dutta, Pradip Kr; Asatkar, Ashish K; Zade, Sanjio S; Panda, Snigdha

    2014-01-28

    Three components, one pot synthesis of thiasalen/selenasalen Ni(II), Pd(II) and Pt(II) complexes, 14-19, by the oxidative addition of S-S/Se-Se bond of bis(o-formylphenyl)disulfide/-diselenide to Ni(0), Pd(0) and Pt(0) followed by in situ Schiff base formation with ethylenediamine is reported. S-S or Se-Se bonds were cleaved and coordinated to the metal center as thiolate (ArS(-)) or selenolate (ArSe(-)) while the formal oxidation state of metal centers was changed from '0' to '+2'. The disulfide/diselenide reacted with zero-valent metals at room temperature to give only the monometallic complexes. All complexes (except Pd-thiolate complex 15) were studied by single crystal X-ray crystallography and revealed the square planar geometry around metal centers.

  7. The 'grey' assessment practice of IA screening

    DEFF Research Database (Denmark)

    Bidstrup, Morten

    2017-01-01

    ’ in Denmark. This article explores the prevalence, influence and applied rationale of grey IA. Through a questionnaire, data was collected from 121 IA practitioners working within the fields of environmental impact assessment and strategic environmental assessment. It was found that grey IA is a common......Research focusing on the practices surrounding screening in Impact Assessment (IA) is limited. Yet, it has been found that development proposals sometimes are adjusted through an informal dialog with IA practitioners prior to or during screening. Such practice is often referred to as ‘grey IA...... practice, which influences the outcomes of formal screening procedures through consideration of impacts on neighbours and spatial zones of protection. Grey IA is to some extent motivated by the opportunity to save the resources required for full-scale IA, but an additional ‘green’ rationale also exists...

  8. IAS 12 needs methodical approach

    NARCIS (Netherlands)

    Hafkenscheid, R.P.F.M.; Janssen, C.M.L.

    2009-01-01

    The article describes a methodology used to establish the expected value of uncertain tax positions. The Project Update on Income Taxes released by the International Accounting Standards Board (IASB) in September 2008 aims to reduce the differences between IAS 12 Income Taxes and the SFAS 109 Accoun

  9. Thermal Balance of the Magneto-Hydro-Dynamic Pump for Recovery of Platinum Group Metals from Spent Auto Catalysts

    Directory of Open Access Journals (Sweden)

    Gil S.

    2016-03-01

    Full Text Available Every new car should be equipped with the catalyst, which limits the amount of harmful chemical compounds such as NOx, CH and CO emitted to the air. Auto catalyst consists of the ceramic or metallic carrier, on which is the layer with Platinum Group Metals playing catalytic role. There are many methods using for recovery those valuable metals from spent auto catalyst, however evry of those methods have some limitations. Proces described in the article is the modified method of metal collector, which used magnetohydrodynamic pump. Rotary electromagnetic field generates in the liquid metal rotary current, which as a consequence washing out the PGM metals from the ceramic carriers. Considering the possibilities of commercialization of the described method, the energy balance was made. From that balance the energetic efficiency of the unit was determined and the analysis of the temperature distribution was shown thermographycally.

  10. Constraints on intragroup stellar mass from hostless Type Ia supernova

    CERN Document Server

    McGee, Sean L

    2009-01-01

    We probe the diffuse stellar mass in a sample of 1401 low redshift galaxy groups (10E13 - 10E14 Msun/h) by examining the rate of hostless Type Ia supernova (SNe Ia) within the groups. We correlate the sample of confirmed SNe Ia from the SDSS supernova survey with the positions of our galaxy groups, as well as with the resolved galaxies within them. We find that 19 of the 59 SNe Ia within the group sample have no detectable host galaxy, with another three ambiguous instances. This gives a robust upper limit that a maximum of 2.69% +1.58%/-1.34% of the group's total mass arises from diffuse stars in the intragroup medium. After correcting for a contribution from ``prompt'' SNe occurring within galaxies, and including a contribution from those which arise in dwarf galaxies below our photometric limit, we find that only 1.32% +0.78%/-0.70% of the group's total mass is likely in the form of diffuse stellar mass. Combining this result with the galaxy stellar mass functions of Yang et al., we find that 47% +16%/-15%...

  11. Ultraviolet diversity of Type Ia Supernovae

    DEFF Research Database (Denmark)

    Foley, Ryan J.; Pan, Yen-Chen; Brown, P.;

    2016-01-01

    Ultraviolet (UV) observations of Type Ia supernovae (SNe Ia) probe the outermost layers of the explosion, and UV spectra of SNe Ia are expected to be extremely sensitive to differences in progenitor composition and the details of the explosion. Here, we present the first study of a sample of high...

  12. Pregnancies in glycogen storage disease type Ia

    NARCIS (Netherlands)

    Martens, Danielle H. J.; Rake, Jan Peter; Schwarz, Martin; Ullrich, Kurt; Weinstein, David A.; Merkel, Martin; Sauer, Pieter J. J.; Smit, G. Peter A.

    2008-01-01

    OBJECTIVE: Reports on pregnancies in women with glycogen storage disease type Ia (GSD-Ia) are scarce. Because of improved life expectancy, pregnancy is becoming an important issue. We describe 15 pregnancies by focusing on dietary treatment, biochemical parameters, and GSD-Ia complications. STUDY DE

  13. Tunable magneto-optical effects in hole-doped group-IIIA metal-monochalcogenide monolayers

    Science.gov (United States)

    Feng, Wanxiang; Guo, Guang-Yu; Yao, Yugui

    2017-03-01

    Because of unusual properties and fascinating prospects for next-generation device applications, two-dimensional (2D) materials have attracted enormous attention since graphene was discovered in 2004. Among the 2D materials beyond graphene, group-IIIA metal-monochalcogenide (MX) monolayers (MLs), are receiving increasing interests because their excellent applications on electronics and optoelectronics. Recently, ferromagnetism and half-metallicity have been predicted in hole-doped GaS and GaSe MLs, which promise exciting potentials for semiconductor spintronics. Detection and measurement of spontaneous magnetization in these 2D materials will be essential for their spintronic applications. The magneto-optical (MO) effects not only are a powerful probe of magnetism in 2D materials but also have valuable applications in high-density data-storage technology. Furthermore, anomalous Hall effect is not only an ideal transport probe of itinerant magnetism but also of considerable current interest because of its topological nature. Here we perform a systematic first-principles density functional study on the MO Kerr and Faraday effects as well as such important magnetic and transport properties as magneto-crystalline anisotropy energy (MAE) and anomalous Hall conductivity (AHC) of all hole-doped MX (M = Ga, In; X = S, Se, Te) MLs. In this paper, we report the following important findings: (a) gate-tunable MO effects in MX MLs in a broad range of hole concentration; (b) large Kerr and Faraday rotation angles with Kerr angles comparable to well-known MO 3d-transition-metal multilayers and Faraday angles being among the largest ones reported; (c) tunable MAE and large AHC, making MX MLs suitable for magnetic memory devices current-driven via spin-transfer torque and also promising materials for magnetic field nanosensors with high sensitivity. Superior MO characteristics, together with the other interesting properties, would make MX MLs an excellent family of 2D materials for

  14. Electron-energy-loss spectroscopy on group-III nitrides and transition- metal oxides

    CERN Document Server

    Niessner, W

    2000-01-01

    A main topic represent electron-energy-loss spectroscopy (EELS) studies of the group-III nitrides AlN, GaN, InN, as well as their mixing systems Al sub x Ga sub 1 sub - sub x N, In sub x Ga sub 1 sub - sub x N. In EELS measurements with excitation energies above 1 keV clear collective excitations in AlN at 21 eV and in GaN at 15 eV were observed. In the mixing system Al sub x Ga sub 1 sub - sub x M a 2-mode behaviour is observed. Up to x=0.2 a GaN-like excitation remains preserved, while from x=0.44 the eigenfrequency of a AlN-like resonance shifts continuously. With vanadium dioxide a d sup 1 transition metal oxide was studied, which passes at 68 C a semiconductor-metal transition. In the EELS valence band spectra beside band transitions from the O2p subsigma and O2p subpi band an intense signal with a loss energy of 1 eV occurs. EELS studies on W- and F-doped VO sub 2 show, that it deals with a band transition from the V3d into the pd subpi band. EELS studies were for the first time also performed at lead t...

  15. Host Galaxies of Type Ia Supernovae from the Nearby Supernova Factory

    Science.gov (United States)

    Childress, M.; Aldering, G.; Antilogus, P.; Aragon, C.; Bailey, S.; Baltay, C.; Bongard, S.; Buton, C.; Canto, A.; Cellier-Holzem, F.; Chotard, N.; Copin, Y.; Fakhouri, H. K.; Gangler, E.; Guy, J.; Hsiao, E. Y.; Kerschhaggl, M.; Kim, A. G.; Kowalski, M.; Loken, S.; Nugent, P.; Paech, K.; Pain, R.; Pecontal, E.; Pereira, R.; Perlmutter, S.; Rabinowitz, D.; Rigault, M.; Runge, K.; Scalzo, R.; Smadja, G.; Tao, C.; Thomas, R. C.; Weaver, B. A.; Wu, C.

    2013-06-01

    We present photometric and spectroscopic observations of galaxies hosting Type Ia supernovae (SNe Ia) observed by the Nearby Supernova Factory. Combining Galaxy Evolution Explorer (GALEX) UV data with optical and near-infrared photometry, we employ stellar population synthesis techniques to measure SN Ia host galaxy stellar masses, star formation rates (SFRs), and reddening due to dust. We reinforce the key role of GALEX UV data in deriving accurate estimates of galaxy SFRs and dust extinction. Optical spectra of SN Ia host galaxies are fitted simultaneously for their stellar continua and emission lines fluxes, from which we derive high-precision redshifts, gas-phase metallicities, and Hα-based SFRs. With these data we show that SN Ia host galaxies present tight agreement with the fiducial galaxy mass-metallicity relation from Sloan Digital Sky Survey (SDSS) for stellar masses log(M */M ⊙) > 8.5 where the relation is well defined. The star formation activity of SN Ia host galaxies is consistent with a sample of comparable SDSS field galaxies, though this comparison is limited by systematic uncertainties in SFR measurements. Our analysis indicates that SN Ia host galaxies are, on average, typical representatives of normal field galaxies.

  16. HOST GALAXIES OF TYPE Ia SUPERNOVAE FROM THE NEARBY SUPERNOVA FACTORY

    Energy Technology Data Exchange (ETDEWEB)

    Childress, M.; Aldering, G.; Aragon, C.; Bailey, S.; Fakhouri, H. K.; Hsiao, E. Y.; Kim, A. G.; Loken, S. [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Antilogus, P.; Bongard, S.; Canto, A.; Cellier-Holzem, F.; Guy, J. [Laboratoire de Physique Nucleaire et des Hautes Energies, Universite Pierre et Marie Curie Paris 6, Universite Paris Diderot Paris 7, CNRS-IN2P3, 4 place Jussieu, F-75252 Paris Cedex 05 (France); Baltay, C. [Department of Physics, Yale University, New Haven, CT 06250-8121 (United States); Buton, C.; Kerschhaggl, M.; Kowalski, M. [Physikalisches Institut, Universitaet Bonn, Nussallee 12, D-53115 Bonn (Germany); Chotard, N.; Copin, Y.; Gangler, E. [Universite de Lyon, F-69622, Lyon (France); Universite de Lyon 1, Villeurbanne (France); CNRS/IN2P3, Institut de Physique Nucleaire de Lyon (France); and others

    2013-06-20

    We present photometric and spectroscopic observations of galaxies hosting Type Ia supernovae (SNe Ia) observed by the Nearby Supernova Factory. Combining Galaxy Evolution Explorer (GALEX) UV data with optical and near-infrared photometry, we employ stellar population synthesis techniques to measure SN Ia host galaxy stellar masses, star formation rates (SFRs), and reddening due to dust. We reinforce the key role of GALEX UV data in deriving accurate estimates of galaxy SFRs and dust extinction. Optical spectra of SN Ia host galaxies are fitted simultaneously for their stellar continua and emission lines fluxes, from which we derive high-precision redshifts, gas-phase metallicities, and H{alpha}-based SFRs. With these data we show that SN Ia host galaxies present tight agreement with the fiducial galaxy mass-metallicity relation from Sloan Digital Sky Survey (SDSS) for stellar masses log(M{sub *}/M{sub Sun }) > 8.5 where the relation is well defined. The star formation activity of SN Ia host galaxies is consistent with a sample of comparable SDSS field galaxies, though this comparison is limited by systematic uncertainties in SFR measurements. Our analysis indicates that SN Ia host galaxies are, on average, typical representatives of normal field galaxies.

  17. Stimuli-Responsive Metal-Organic Frameworks with Photoswitchable Azobenzene Side Groups.

    Science.gov (United States)

    Kanj, Anemar Bruno; Müller, Kai; Heinke, Lars

    2017-07-31

    Metal-organic frameworks (MOFs) are nanoporous, crystalline hybrid materials, which enable various functionalities by incorporating functional organic molecules. By using organic linker molecules that possess photoswitchable azobenzene side groups, the remote control over certain properties was introduced to MOFs. Different MOF materials in the form of powders and thin films have been used to demonstrate the photoswitching. The applications of these stimuli-responsive nanoporous solids range from switching the adsorption capacity of various gases over remote-controlled release of guest molecules to continuously tunable membrane separation of molecular mixtures. A particular focus of this review is the effect of the azobenzene photoswitching on the host-guest interaction, enabling smart applications of the material. Steric hindrance, which may suppress the photoswitching in some MOF structures, is also discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. HM+ and HM+-He (M = Group 2 metal): Chemical or physical interactions?

    Science.gov (United States)

    Harris, Joe P.; Dodson, Hannah; Breckenridge, W. H.; Wright, Timothy G.

    2014-09-01

    We investigate the HM+-He complexes (M = Group 2 metal) using quantum chemistry. Equilibrium geometries are linear for M = Be and Mg, and bent for M = Ca-Ra; the explanation for this lies in the differing nature of the highest occupied molecular orbitals in the two sets of complexes. The difference primarily occurs as a result of the formation of the H-M+ bond, and so the HM+ diatomics are also studied as part of the present work. The position of the He atom in the complexes is largely determined by the form of the electron density. HM+…He binding energies are obtained and are surprisingly high for a helium complex. The HBe+…He value is almost 3000 cm-1, which is high enough to suspect contributions from chemical bonding. This is explored by examining the natural orbital density and by population analyses.

  19. Materials design by evolutionary optimization of functional groups in metal-organic frameworks.

    Science.gov (United States)

    Collins, Sean P; Daff, Thomas D; Piotrkowski, Sarah S; Woo, Tom K

    2016-11-01

    A genetic algorithm that efficiently optimizes a desired physical or functional property in metal-organic frameworks (MOFs) by evolving the functional groups within the pores has been developed. The approach has been used to optimize the CO2 uptake capacity of 141 experimentally characterized MOFs under conditions relevant for postcombustion CO2 capture. A total search space of 1.65 trillion structures was screened, and 1035 derivatives of 23 different parent MOFs were identified as having exceptional CO2 uptakes of >3.0 mmol/g (at 0.15 atm and 298 K). Many well-known MOF platforms were optimized, with some, such as MIL-47, having their CO2 adsorption increase by more than 400%. The structures of the high-performing MOFs are provided as potential targets for synthesis.

  20. Explorations of new selenites of the group IIIA and IVA metals

    Science.gov (United States)

    Kong, Fang; Li, Pei-Xin; Zhang, Su-Yun; Mao, Jiang-Gao

    2012-06-01

    Systematic explorations of new phases in the GaIII/InIII/GeIV-SeIV-O systems by hydrothermal syntheses or solid-state reactions at high-temperature led to six new ternary compounds, namely, M2Se2O7 (M=Ga 1, In 2), M(OH)(SeO3) (M=Ga 3, In 4), α-Ge(SeO3)25 and β-Ge(SeO3)26. Ga2Se2O71 displays a 3D open framework composed of 2D gallium oxide layers being further bridged and capped by SeO3 groups. In2Se2O72 features a 3D indium oxide framework formed by corner- and edge- sharing InO6 octahedra with SeO3 groups attached on the cavities and the 8-member ring tunnels of the structure. The isostructural of M(OH)(SeO3) (M=Ga 3, In 4) exhibit a 2D metal selenite layer composed of 1D edge-sharing MO6 octahedral chains that are interconnected by SeO3 groups. α-Ge(SeO3)2 (P21/n) 5 displays a 3D open framework with 1D 8-member ring tunnels along the a-axis while β-Ge(SeO3)2 (Pa-3) 6 exhibits a condensed 3D network.

  1. Multiconfiguration pair-density functional theory: barrier heights and main group and transition metal energetics.

    Science.gov (United States)

    Carlson, Rebecca K; Li Manni, Giovanni; Sonnenberger, Andrew L; Truhlar, Donald G; Gagliardi, Laura

    2015-01-13

    Kohn-Sham density functional theory, resting on the representation of the electronic density and kinetic energy by a single Slater determinant, has revolutionized chemistry, but for open-shell systems, the Kohn-Sham Slater determinant has the wrong symmetry properties as compared to an accurate wave function. We have recently proposed a theory, called multiconfiguration pair-density functional theory (MC-PDFT), in which the electronic kinetic energy and classical Coulomb energy are calculated from a multiconfiguration wave function with the correct symmetry properties, and the rest of the energy is calculated from a density functional, called the on-top density functional, that depends on the density and the on-top pair density calculated from this wave function. We also proposed a simple way to approximate the on-top density functional by translation of Kohn-Sham exchange-correlation functionals. The method is much less expensive than other post-SCF methods for calculating the dynamical correlation energy starting with a multiconfiguration self-consistent-field wave function as the reference wave function, and initial tests of the theory were quite encouraging. Here, we provide a broader test of the theory by applying it to bond energies of main-group molecules and transition metal complexes, barrier heights and reaction energies for diverse chemical reactions, proton affinities, and the water dimerization energy. Averaged over 56 data points, the mean unsigned error is 3.2 kcal/mol for MC-PDFT, as compared to 6.9 kcal/mol for Kohn-Sham theory with a comparable density functional. MC-PDFT is more accurate on average than complete active space second-order perturbation theory (CASPT2) for main-group small-molecule bond energies, alkyl bond dissociation energies, transition-metal-ligand bond energies, proton affinities, and the water dimerization energy.

  2. Surface chemistry of the atomic layer deposition of metals and group III oxides

    Science.gov (United States)

    Goldstein, David Nathan

    Atomic Layer Deposition (ALD) is a thin-film growth technique offering precise control of film thickness and the ability to coat high-aspect-ratio features such as trenches and nanopowders. Unlike other film growth techniques, ALD does not require harsh processing conditions and is not limited by line-of-sight deposition. Emerging applications for ALD materials include semiconductor devices, gas sensors, and water-diffusion barriers. The chemistry behind ALD involves understanding how the precursors interact with surfaces to deposit the desired material. All ALD precursors need to be stable on the substrate to ensure self-limiting behavior yet reactive enough to be easily removed with the second reagent. Recent precursor development has provided many volatile organometallic compounds for most of the periodic table. As the number of precursors increases, proper precursor choice becomes crucial. This is because the film properties, growth rates, and growth temperature vary widely between the precursors. Many of the above traits can be predicted with knowledge of the precursor reaction mechanisms. This thesis aims to link surface reaction mechanisms to observed growth and nucleation trends in metal and oxide ALD systems. The first portion of this thesis explores the mechanisms of two ALD oxide systems. First, I examine the mechanism of ALD alumina with ozone. Ozone is used as an oxidant in the semiconductor industry because the deposited Al 2O3 films possess better insulating properties and ozone is easier to purge from a vacuum system. FT-IR analysis reveals a complicated array of surface intermediates such as formate, carbonate, and methoxy groups that form during Al2O3 growth with ozone. Next, a new method to deposit thin films of Ga2O3 is introduced. Gallium oxide is a transparent conducting oxide that needs expensive solid precursors to be deposited by ALD. I show that trimethylgallium is a good high-temperature ALD precursor that deposits films of Ga2O 3 with

  3. Asymmetric partitioning of metals among cluster anions and cations generated via laser ablation of mixed aluminum/Group 6 transition metal targets.

    Science.gov (United States)

    Waller, Sarah E; Mann, Jennifer E; Jarrold, Caroline Chick

    2013-02-28

    While high-power laser ablation of metal alloys indiscriminately produces gas-phase atomic ions in proportion to the abundance of the various metals in the alloy, gas-phase ions produced by moderate-power laser ablation sources coupled with molecular beams are formed by more complicated mechanisms. A mass spectrometric study that directly compares the mass distributions of cluster anions and cations generated from laser ablation of pure aluminum, an aluminum/molybdenum mixed target, and an aluminum/tungsten mixed target is detailed. Mass spectra of anionic species generated from the mixed targets showed that both tungsten and molybdenum were in higher abundance in the negatively charged species than in the target material. Mass spectra of the cationic species showed primarily Al(+) and aluminum oxide and hydroxide cluster cations. No molybdenum- or tungsten-containing cluster cations were definitively assigned. The asymmetric distribution of aluminum and Group 6 transition metals in cation and anion cluster composition is attributed to the low ionization energy of atomic aluminum and aluminum suboxide clusters. In addition, the propensity of both molybdenum and tungsten to form metal oxide cluster anions under the same conditions that favor metallic aluminum cluster anions is attributed to differences in the optical properties of the surface oxide that is present in the metal powders used to prepare the ablation targets. Mechanisms of mixed metal oxide clusters are considered.

  4. Metal-free annulation of arenes with 2-aminopyridine derivatives: the methyl group as a traceless non-chelating directing group.

    Science.gov (United States)

    Manna, Srimanta; Matcha, Kiran; Antonchick, Andrey P

    2014-07-28

    A novel annulation reaction between 2-aminopyridine derivatives and arenes under metal-free conditions is described. The presented intermolecular transformation provided straightforward access to the important pyrido[1,2-a]benzimidazole scaffold under mild reaction conditions. The unprecedented application of the methyl group of methylbenzenes as a traceless, non-chelating, and highly regioselective directing group is reported. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. 30 CFR 57.22211 - Air flow (I-A mines).

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Air flow (I-A mines). 57.22211 Section 57.22211... Methane in Metal and Nonmetal Mines Ventilation § 57.22211 Air flow (I-A mines). The average air velocity... openings nearest the face, shall be at least 40 feet per minute. The velocity of air ventilating each...

  6. Bibliography of the technical literature of the Materials Joining Group, Metals and Ceramics Division, 1951 through June 1987

    Energy Technology Data Exchange (ETDEWEB)

    David, S.A.; Goodwin, G.M.; Gardner, K. (comps.)

    1987-08-01

    This document contains a listing of the written scientific information originating in the Materials Joining Group (formerly the Welding and Brazing Group), Metals and Ceramics Division, Oak Ridge National Laboratory during 1951 through June 1987. It is a registry of about 400 documents as nearly as possible in the order in which they were issued.

  7. Functionalization of metal-organic frameworks through the postsynthetic transformation of olefin side groups.

    Science.gov (United States)

    Hindelang, Konrad; Kronast, Alexander; Vagin, Sergei I; Rieger, Bernhard

    2013-06-17

    For the first time, the adaptability of the C=C double bond as a versatile precursor for the postsynthetic modification (PSM) of microporous materials was extensively investigated and evaluated. Therefore, an olefin-tagged 4,4'-bipyridine linker was synthesized and successfully introduced as pillar linker within a 9,10-triptycenedicarboxylate (TDC) zinc paddle-wheel metal-organic framework (MOF) through microwave-assisted synthesis. Different reactions, predominately used in organic chemistry, were tested, leading to the development of new postsynthetic reactions for the functionalization of solid materials. The postsynthetic oxidation of the olefin side groups applying osmium tetroxide (OsO₄) as a catalyst led to the formation of a microporous material with free vicinal diol functionalities. The epoxidation with dimethyldioxirane (DMDO) enabled the synthesis of epoxy-functionalized MOFs. In addition to that, reaction procedures for a postsynthetic hydroboration with borane dimethyl sulfide as well as a photoinduced thiol-ene click reaction with ethyl mercaptan were developed. For all of these PSMs, yields of more than 90% were obtained, entirely maintaining the crystallinity of the MOFs. Since the direct introduction of the corresponding groups by means of pre-synthetic approaches is hardly possible, these new PSMs are useful tools for the functionalization of porous solids towards applications such as selective adsorption, separation, and catalysis.

  8. Comparison of the interactions in the rare gas hydride and Group 2 metal hydride anions.

    Science.gov (United States)

    Harris, Joe P; Manship, Daniel R; Breckenridge, W H; Wright, Timothy G

    2014-02-28

    We study both the rare gas hydride anions, RG-H(-) (RG = He-Rn) and Group 2 (Group IIa) metal hydride anions, MIIaH(-) (MIIa = Be-Ra), calculating potential energy curves at the CCSD(T) level with augmented quadruple and quintuple basis sets, and extrapolating the results to the basis set limit. We report spectroscopic parameters obtained from these curves; additionally, we study the Be-He complex. While the RG-H(-) and Be-He species are weakly bound, we show that, as with the previously studied BeH(-) and MgH(-) species, the other MIIaH(-) species are strongly bound, despite the interactions nominally also being between two closed shell species: M(ns(2)) and H(-)(1s(2)). We gain insight into the interactions using contour plots of the electron density changes and population analyses. For both series, the calculated dissociation energy is significantly less than the ion/induced-dipole attraction term, confirming that electron repulsion is important in these species; this effect is more dramatic for the MIIaH(-) species than for RG-H(-). Our analyses lead us to conclude that the stronger interaction in the case of the MIIaH(-) species arises from sp and spd hybridization, which allows electron density on the MIIa atom to move away from the incoming H(-).

  9. Bibliography of the technical literature of the Materials Joining Group, Metals and Ceramics Division, 1951--June 1989

    Energy Technology Data Exchange (ETDEWEB)

    David, S.A.; Goodwin, G.M.; Gardner, K. (comps.)

    1989-10-01

    This document contains a listing of the written scientific information originating in the Materials Joining (formerly the Welding and Brazing Group), Metals and Ceramics Division, Oak Ridge National Laboratory during 1951 through June 1989. This registry of documents is as much as possible, in the order of issue date. A complete cross-referenced listing of the technical literature of the Metals and Ceramics Division is also available.

  10. An Analysis of Department of Defense Instruction 8500.2 'Information Assurance (IA) Implementation.'

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, Philip LaRoche

    2012-01-01

    The Department of Defense (DoD) provides its standard for information assurance in its Instruction 8500.2, dated February 6, 2003. This Instruction lists 157 'IA Controls' for nine 'baseline IA levels.' Aside from distinguishing IA Controls that call for elevated levels of 'robustness' and grouping the IA Controls into eight 'subject areas' 8500.2 does not examine the nature of this set of controls, determining, for example, which controls do not vary in robustness, how this set of controls compares with other such sets, or even which controls are required for all nine baseline IA levels. This report analyzes (1) the IA Controls, (2) the subject areas, and (3) the Baseline IA levels. For example, this report notes that there are only 109 core IA Controls (which this report refers to as 'ICGs'), that 43 of these core IA Controls apply without variation to all nine baseline IA levels and that an additional 31 apply with variations. This report maps the IA Controls of 8500.2 to the controls in NIST 800-53 and ITGI's CoBIT. The result of this analysis and mapping, as shown in this report, serves as a companion to 8500.2. (An electronic spreadsheet accompanies this report.)

  11. Direct intermolecular force measurements between functional groups and individual metallic or semiconducting single-walled carbon nanotubes.

    Science.gov (United States)

    Thong, Ya Xuan; Poon, Yin Fun; Chen, Tzu-Yin; Li, Lain-Jong; Chan-Park, Mary B

    2014-02-26

    Many electronic applications of single-walled carbon nanotubes (SWNTs) require electronic homogeneity in order to maximally exploit their outstanding properties. Non-covalent separation is attractive as it is scalable and results in minimal alteration of nanotube properties. However, fundamental understanding of the metallicity-dependence of functional group interactions with nanotubes is still lacking; this lack is compounded by the absence of methods to directly measure these interactions. Herein, a novel technology platform based on a recently developed atomic force microscopy (AFM) mode is reported which directly quantifies the adhesion forces between a chosen functional group and individual nanotubes of known metallicity, permitting comparisons between different metallicity. These results unambiguously show that this technology platform is able to discriminate the subtle adhesion force differences of a chosen functional group with pure metallic as opposed to pure semiconducting nanotubes. This new method provides a route towards rapid advances in understanding of non-covalent interactions of large libraries of compounds with nanotubes of varying metallicity and diameter; presenting a superior tool to assist the discovery of more effective metallicity-based SWNT separation agents.

  12. Dark Matter Ignition of Type Ia Supernovae.

    Science.gov (United States)

    Bramante, Joseph

    2015-10-02

    Recent studies of low redshift type Ia supernovae (SN Ia) indicate that half explode from less than Chandrasekhar mass white dwarfs, implying ignition must proceed from something besides the canonical criticality of Chandrasekhar mass SN Ia progenitors. We show that 1-100 PeV mass asymmetric dark matter, with imminently detectable nucleon scattering interactions, can accumulate to the point of self-gravitation in a white dwarf and collapse, shedding gravitational potential energy by scattering off nuclei, thereby heating the white dwarf and igniting the flame front that precedes SN Ia. We combine data on SN Ia masses with data on the ages of SN Ia-adjacent stars. This combination reveals a 2.8σ inverse correlation between SN Ia masses and ignition ages, which could result from increased capture of dark matter in 1.4 vs 1.1 solar mass white dwarfs. Future studies of SN Ia in galactic centers will provide additional tests of dark-matter-induced type Ia ignition. Remarkably, both bosonic and fermionic SN Ia-igniting dark matter also resolve the missing pulsar problem by forming black holes in ≳10  Myr old pulsars at the center of the Milky Way.

  13. The Changing Fractions of Type Ia Supernova NUV-Optical Subclasses with Redshift

    CERN Document Server

    Milne, Peter A; Brown, Peter J; Narayan, Gautham

    2014-01-01

    UV and optical photometry of Type Ia supernovae (SNe Ia) at low redshift have revealed the existence of two distinct color groups, NUV-red and NUV-blue events. The color curves differ primarily by an offset, with the NUV-blue u- color curves bluer than the NUV-red curves by 0.4 mag. For a sample of 23 low-z SNe~Ia observed with Swift, the NUV-red group dominates by a ratio of 2:1. We compare rest-frame UV/optical spectrophotometry of intermediate and high-z SNe Ia with UVOT photometry and HST spectrophotometry of low-z SNe Ia, finding that the same two color groups exist at higher-z, but with the NUV-blue events as the dominant group. Within each red/blue group, we do not detect any offset in color for different redshifts, providing insight into how SN~Ia UV emission evolves with redshift. Through spectral comparisons of SNe~Ia with similar peak widths and phase, we explore the wavelength range that produces the UV/OPT color differences. We show that the ejecta velocity of NUV-red SNe is larger than that of N...

  14. No Evidence of Genotoxic Damage in a Group of Patients with Titanium Dental Implants and Different Metal Restorations in the Oral Cavity.

    Science.gov (United States)

    Camacho-Alonso, Fabio; Sánchez-Siles, Mariano; Gilbel-del Águila, Osmundo

    2015-08-01

    Titanium is the most widely used metal in implant dentistry. In spite of its biocompatibility, when it is released into the oral environment, it can have local negative biological effects. The aims of this study were to detect the concentration of metal ions in patients with dental implants, to evaluate whether or not their release might be influenced by the presence of other metals, and to assay whether these ions might provoke genotoxic damage in oral mucosa cells. One hundred five patients with a total of 180 dental implants were included. The sample was divided into seven groups (n = 15 per group). Group 1 consisted of patients with metal-porcelain fixed crowns on dental implants; Group 2, patients with metal-porcelain fixed crowns on teeth; Group 3, patients with dental amalgams; Group 4, patients with metal-porcelain fixed crowns on dental implants and metal-porcelain fixed crowns on teeth; Group 5, patients with metal-porcelain fixed crowns on dental implants and dental amalgams; and Group 6, patients with metal-porcelain fixed crowns on dental implants, metal-porcelain fixed crowns on teeth, and dental amalgams. Group 7 was the control group, without any dental treatment. The concentration of metal ions was detected using inductively coupled plasma mass spectrometry; genotoxicity was measured using the buccal micronucleus cytome assay protocol. Group 5 displayed the highest concentration of metal ions in parts per billion (Ti, Co, Ni, Zn, Pd, Sn, and Pb). Group 6 was characterized by the highest presence of Hg. No signs of genotoxic damage were found in any of the study groups. Patients with titanium dental implants combined with other metal restorations presented higher concentrations of metal ions, but no genotoxic damage was observed in oral mucosal epithelial cells. © 2013 Wiley Periodicals, Inc.

  15. Synthesising carbo-nitrides of some d-group transition metals using a solar furnace at PSA

    OpenAIRE

    Shohoji, Nobumitsu; Oliveira, F. A. Costa; Rosa, Luís Guerra; Fernandes, Jorge Cruz; Magalhães, Teresa; Coelho, Manuel Caldeira; Rodriguez,José; Canadas, Inmaculada; Ramos, Carlos; Martinez, Diego

    2013-01-01

    Carbo-nitride synthesis was undertaken using a solar furnace at PSA in flowing N2/Ar gas mixture under total pressure 1 atm and processing temperature T = 1600ºC for some d-group transition elements (Ti; Zr, V, Nb, Mo, W) starting from 1.5G/M (graphite/metal powder mixture with mole ratio 1.5:1) compact to ensure co-presence of free carbon with the reaction product. Clear X-ray diffraction (XRD) evidence of formation of carbo-nitride was detected for Ti (IVa group metal) showing higher N cont...

  16. Activity targets for nanostructured platinum-group-metal-free catalysts in hydroxide exchange membrane fuel cells

    Science.gov (United States)

    Setzler, Brian P.; Zhuang, Zhongbin; Wittkopf, Jarrid A.; Yan, Yushan

    2016-12-01

    Fuel cells are the zero-emission automotive power source that best preserves the advantages of gasoline automobiles: low upfront cost, long driving range and fast refuelling. To make fuel-cell cars a reality, the US Department of Energy has set a fuel cell system cost target of US$30 kW-1 in the long-term, which equates to US$2,400 per vehicle, excluding several major powertrain components (in comparison, a basic, but complete, internal combustion engine system costs approximately US$3,000). To date, most research for automotive applications has focused on proton exchange membrane fuel cells (PEMFCs), because these systems have demonstrated the highest power density. Recently, however, an alternative technology, hydroxide exchange membrane fuel cells (HEMFCs), has gained significant attention, because of the possibility to use stable platinum-group-metal-free catalysts, with inherent, long-term cost advantages. In this Perspective, we discuss the cost profile of PEMFCs and the advantages offered by HEMFCs. In particular, we discuss catalyst development needs for HEMFCs and set catalyst activity targets to achieve performance parity with state-of-the-art automotive PEMFCs. Meeting these targets requires careful optimization of nanostructures to pack high surface areas into a small volume, while maintaining high area-specific activity and favourable pore-transport properties.

  17. Alkali Metal Cation Affinities of Anionic Main Group-Element Hydrides Across the Periodic Table.

    Science.gov (United States)

    Boughlala, Zakaria; Fonseca Guerra, Célia; Bickelhaupt, F Matthias

    2017-08-05

    We have carried out an extensive exploration of gas-phase alkali metal cation affinities (AMCA) of archetypal anionic bases across the periodic system using relativistic density functional theory at ZORA-BP86/QZ4P//ZORA-BP86/TZ2P. AMCA values of all bases were computed for the lithium, sodium, potassium, rubidium and cesium cations and compared with the corresponding proton affinities (PA). One purpose of this work is to provide an intrinsically consistent set of values of the 298 K AMCAs of all anionic (XHn-1(-) ) constituted by main group-element hydrides of groups 14-17 along the periods 2-6. In particular, we wish to establish the trend in affinity for a cation as the latter varies from proton to, and along, the alkali cations. Our main purpose is to understand these trends in terms of the underlying bonding mechanism using Kohn-Sham molecular orbital theory together with a quantitative bond energy decomposition analyses (EDA). © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Activity targets for nanostructured platinum-group-metal-free catalysts in hydroxide exchange membrane fuel cells.

    Science.gov (United States)

    Setzler, Brian P; Zhuang, Zhongbin; Wittkopf, Jarrid A; Yan, Yushan

    2016-12-06

    Fuel cells are the zero-emission automotive power source that best preserves the advantages of gasoline automobiles: low upfront cost, long driving range and fast refuelling. To make fuel-cell cars a reality, the US Department of Energy has set a fuel cell system cost target of US$30 kW(-1) in the long-term, which equates to US$2,400 per vehicle, excluding several major powertrain components (in comparison, a basic, but complete, internal combustion engine system costs approximately US$3,000). To date, most research for automotive applications has focused on proton exchange membrane fuel cells (PEMFCs), because these systems have demonstrated the highest power density. Recently, however, an alternative technology, hydroxide exchange membrane fuel cells (HEMFCs), has gained significant attention, because of the possibility to use stable platinum-group-metal-free catalysts, with inherent, long-term cost advantages. In this Perspective, we discuss the cost profile of PEMFCs and the advantages offered by HEMFCs. In particular, we discuss catalyst development needs for HEMFCs and set catalyst activity targets to achieve performance parity with state-of-the-art automotive PEMFCs. Meeting these targets requires careful optimization of nanostructures to pack high surface areas into a small volume, while maintaining high area-specific activity and favourable pore-transport properties.

  19. Iron-Group Abundances in the Metal-Poor Main Sequence Turnoff Star HD~84937

    CERN Document Server

    Sneden, Christopher; Kobayashi, Chiaki; Pignatari, Marco; Lawler, James E; Hartog, Elizabeth A Den; Wood, Michael P

    2015-01-01

    We have derived new very accurate abundances of the Fe-group elements Sc through Zn (Z = 21-30) in the bright main-sequence turnoff star HD 84937, based on high-resolution spectra covering the visible and ultraviolet spectral regions. New or recent laboratory transition data for 14 species of seven elements have been used. Abundances from more than 600 lines of non-Fe species have been combined with about 550 Fe lines in HD 84937 to yield abundance ratios of high precision. The abundances have been determined from both neutral and ionized transitions, which generally are in agreement with each other. We find no substantial departures from standard LTE Saha ionization balance in this [Fe/H] = -2.32 star. Noteworthy among the abundances are: [Co/Fe] = 0.14 and [Cu/Fe] = -0.83, in agreement with past studies abundance trends in this and other low metallicity stars; and = 0.31, which has not been noted previously. A detailed examination of scandium, titanium, and vanadium abundances in large-sample spectroscopic...

  20. The Utilization of Amide Groups To Expand and Functionalize Metal-Organic Frameworks Simultaneously.

    Science.gov (United States)

    Lu, Zhiyong; Bai, Junfeng; Hang, Cheng; Meng, Fei; Liu, Wenlong; Pan, Yi; You, Xiaozeng

    2016-04-25

    A new stepwise ligand-elongation strategy by amide spacers is utilized to prepare isoreticularly high-porous metal-organic frameworks (MOFs), namely, quasi-mesoporous [Cu2 (PDBAD)(H2 O)]n (H4 PDBAD=5,5'-((4,4'-((pyridine-3,5-dicarbonyl)bis(azanediyl))bis(benzoyl))bis(azanediyl))diisophthalic acid; NJU-Bai22: NJU-Bai for Nanjing University Bai's group), and mesoporous [Cu2 (PABAD)(H2 O)]n (H4 PABAD=5,5'-((4,4'-((4,4'-((pyridine-3,5-dicarbonyl)bis(azanediyl))bis(benzoyl))bis (azanediyl))bis(benzoyl))bis(azanediyl))diisophthalic acid; NJU-Bai23). Compared with the prototypical MOF of [Cu2 (PDAD)(H2 O)]n (H4 PDAD=5,5'-(pyridine-3,5-dicarbonyl)bis(azanediyl)diisophthalic acid; NJU-Bai21, also termed as PCN-124), both MOFs exhibit almost the same CO2 adsorption enthalpy and CO2 selectivity values, and better capacity for CO2 storage under high pressure; these results make them promising candidate materials for CO2 capture and sequestration. Interestingly, this new method, in comparison with traditional strategies of using phenyl or triple-bond spacers, is easier and cheaper, resulting in a better ability to retain high CO2 affinity and selectivity in MOFs with large pores and high CO2 storage capacity. Additionally, it may lead to the high thermal stability of the MOFs and also their tolerance to water, which is related to the balance between the density of functional groups and pore sizes. Therefore, this strategy could provide new opportunities to explore more functionalized mesoporous MOFs with high performance. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Type Ia supernova science 2010-2020

    CERN Document Server

    Howell, D A; Della Valle, M; Nugent, P E; Perlmutter, S; Marion, G H; Krisciunas, K; Badenes, C; Mazzali, P; Aldering, G; Antilogus, P; Baron, E; Becker, A; Baltay, C; Benetti, S; Blondin, S; Branch, D; Brown, E F; Deustua, S; Ealet, A; Ellis, Richard S; Fouchez, D; Freedman, W; Gal-Yam, A; Jha, S; Kasen, D; Kessler, R; Kim, A G; Leonard, D C; Li, W; Livio, M; Maoz, D; Mannucci, F; Matheson, T; Neill, J D; Nomoto, K; Panagia, N; Perrett, K; Phillips, M; Poznanski, D; Quimby, R; Rest, A; Riess, A; Sako, M; Soderberg, A M; Strolger, L; Thomas, R; Turatto, M; van Dyk, S; Wood-Vasey, W M

    2009-01-01

    In the next decade Type Ia supernovae (SNe Ia) will be used to test theories predicting changes in the Dark Energy equation of state with time. Ultimately this requires a dedicated space mission like JDEM. SNe Ia are mature cosmological probes --- their limitations are well characterized, and a path to improvement is clear. Dominant systematic errors include photometric calibration, selection effects, reddening, and population-dependent differences. Building on past lessons, well-controlled new surveys are poised to make strides in these areas: the Palomar Transient Factory, Skymapper, La Silla QUEST, Pan-STARRS, the Dark Energy Survey, LSST, and JDEM. They will obviate historical calibrations and selection biases, and allow comparisons via large subsamples. Some systematics follow from our ignorance of SN Ia progenitors, which there is hope of determining with SN Ia rate studies from 0Ia regulate galactic and cluster chemical evolution, inform stellar evolution, and are ...

  2. Type Ia supernovae: explosions and progenitors

    Science.gov (United States)

    Kerzendorf, Wolfgang Eitel

    2011-08-01

    Supernovae are the brightest explosions in the universe. Supernovae in our Galaxy, rare and happening only every few centuries, have probably been observed since the beginnings of mankind. At first they were interpreted as religious omens but in the last half millennium they have increasingly been used to study the cosmos and our place in it. Tycho Brahe deduced from his observations of the famous supernova in 1572, that the stars, in contrast to the widely believe Aristotelian doctrine, were not immutable. More than 400 years after Tycho made his paradigm changing discovery using SN 1572, and some 60 years after supernovae had been identified as distant dying stars, two teams changed the view of the world again using supernovae. The found that the Universe was accelerating in its expansion, a conclusion that could most easily be explained if more than 70% of the Universe was some previously un-identified form of matter now often referred to as `Dark Energy'. Beyond their prominent role as tools to gauge our place in the Universe, supernovae themselves have been studied well over the past 75 years. We now know that there are two main physical causes of these cataclysmic events. One of these channels is the collapse of the core of a massive star. The observationally motivated classes Type II, Type Ib and Type Ic have been attributed to these events. This thesis, however is dedicated to the second group of supernovae, the thermonuclear explosions of degenerate carbon and oxygen rich material and lacking hydrogen - called Type Ia supernovae (SNe Ia). White dwarf stars are formed at the end of a typical star's life when nuclear burning ceases in the core, the outer envelope is ejected, with the degenerate core typically cooling for eternity. Theory predicts that such stars will self ignite when close to 1.38 Msun (called the Chandrasekhar Mass). Most stars however leave white dwarfs with 0.6 Msun, and no star leaves a remnant as heavy as 1.38 M! sun, which suggests

  3. European freshwater VHSV genotype Ia isolates divide into two distinct subpopulations

    DEFF Research Database (Denmark)

    Kahns, Søren; Skall, Helle Frank; Kaas, Rolf Sommer;

    2012-01-01

    Viral haemorrhagic septicaemia (VHS), caused by the novirhabdovirus VHSV, often leads to significant economic losses to European rainbow trout production. The virus isolates are divided into 4 distinct genotypes with additional subgroups including sublineage Ia, isolates of which are the main...... detected in Denmark since January 2009. Full-length G-genes of all Danish VHSV isolates that were submitted for diagnostic analyses in the period 2004−2009 were sequenced and analysed. All 58 Danish isolates from rainbow trout grouped with sublineage Ia isolates. Furthermore, VHSV isolates from infected...... Danish freshwater catchments appear to have evolved into a distinct clade within sublineage Ia, herein designated clade Ia-1, whereas trout isolates originating from other continental European countries cluster in another distinct clade, designated clade Ia-2. In addition, phylogenetic analyses indicate...

  4. Gonorréia Gonorrhea

    Directory of Open Access Journals (Sweden)

    Gerson Oliveira Penna

    2000-10-01

    Full Text Available A gonorréia é uma infecção bacteriana freqüente, causada pela Neisseria gonorrhoeae, um diplococo Gram-negativo de transmissão quase que exclusiva através de contato sexual ou perinatal. Primariamente afeta membranas mucosas do trato genital inferior, e mais raramente, as mucosas do reto, orofaringe e conjuntiva. A infecção genital ascendente na mulher leva a uma complicação séria, a salpingite aguda, uma das principais causas de infertilidade feminina. A partir dos anos 90, deu-se início a um novo tempo no que se refere a descobertas sobre a patogenia da gonorréia e seu agente etiológico. O controle da gonorréia tem sido difícil na maioria das populações, e essa permanece um exemplo da influência que os fatores sociais, comportamentais e demográficos exercem na epidemiologia de uma doença infecciosa. O manejo da gonorréia e de outras doenças sexualmente transmissíveis requer tanto o tratamento do paciente e de seu parceiro sexual como medidas de saúde pública para interromper a transmissão da infecção e evitar complicações a longo prazo.Gonorrhea is a common bacterial infection caused by Neisseria gonorrhoeae, a Gram-negative diplococcus that is transmitted almost exclusively by sexual contact or perinatally. It primarily affects the mucous membranes of the lower genital tract and less frequently those of the rectum, oropharynx, and conjunctivae. Ascending genital infection in women leads to the predominant complication, acute salpingitis, one of the most common causes of female infertility in the world. Since the 1990s, a remarkable surge of information ensued regarding the pathogenesis of gonorrhea and its agent. Gonorrohea has proven difficult to control in most populations and remains a prime example of the influence that social, behavioral, and demographic factors can have on the epidemiology of an infectious disease. The management of gonorrhea and other sexually transmitted infections requires both

  5. Defect-Induced Optoelectronic Response in Single-layer Group-VI Transition-Metal Dichalcogenides

    Science.gov (United States)

    Chow, Philippe K.

    The ever-evolving symbiosis between mankind and nanoelectronics-driven technology pushes the limits of its constituent materials, largely due to the dominance of undesirable hetero-interfacial physiochemical behavior at the few-nanometer length scale, which dominates over bulk material characteristics. Driven by such instabilities, research into two-dimensional (2D) van der Waals-layered materials (e.g. graphene, transition metal dichalcogenides (TMDCs), boron nitride), which have characteristically inert surface chemistry, has virtually exploded over the past few years. The discovery of an indirect- to direct-gap conversion in semiconducting group-VI TMDCs (e.g. MoS2) upon thinning to a single atomic layer provided the critical link between metallic and insulating 2D materials. While proof-of-concept demonstrations of single-layer TMDC-based devices for visible-range photodetection, light-emission and solar energy conversion have showed promising results, the exciting qualities are downplayed by poorly-understood defectinduced photocarrier traps, limiting the best-achieved external quantum efficiencies to approximately ~1%. This thesis explores the behavior of defects in atomically-thin TMDC layers in response to optical stimuli using a combination of steady-state photoluminescence, reflectance and Raman spectroscopy at room-temperature. By systematically varying the defect density using plasma-irradiation techniques, an unprecedented room-temperature defect-induced monolayer PL feature was discovered. High-resolution transmission electron microscopy correlated the defect-induced PL with plasma-generation of sulfur vacancy defects while reflectance measurements indicate defect-induced sub-bandgap light absorption. Excitation intensity-dependent PL measurements and exciton rate modeling further help elucidate the origin of the defect-induced PL response and highlights the role of non-radiative recombination on exciton conversion processes. The results in this

  6. Data of evolutionary structure change: 1C7IA-1P0IA [Confc[Archive

    Lifescience Database Archive (English)

    Full Text Available 1C7IA-1P0IA 1C7I 1P0I A A THQIVTTQYGKVKGT--TE--NGVHKWKGIPYAKPPVGQ...GPFGFMHLSSFDEAYSDNLGLLDQAAALKWVRENISAFGGDPDNVTVFGESAGGMSIAALLAMPAAKGLFQKAIMESGAS----RTMTKEQAASTAAAFLQVLGINES...QLDRLHTVAAEDLLKA-----ADQLRIAE-----KENIFQLFFQPALDPKTLPEEPEKSIAEGAASGIPLLIGTTRDEGYF...TLELPFVFGNLDELERMAKAEITDEVKQLSHTIQSAWTTFAKTGNPST---EAVNWPAYHEESRETVILDS-EITIENDPESEKRQKLF------ --IIIA...WNPNTDLSEDCLYLNVWIPAPKPKNATVLIWIYGGGFQTGTSSLHVYDGKFLARVERVIVVSMNYRVGALGFLALPG-NPEAPGNMGLFDQQLALQWVQKNIAAFGGN

  7. EARLY-TYPE HOST GALAXIES OF TYPE Ia SUPERNOVAE. I. EVIDENCE FOR DOWNSIZING

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Yijung; Kim, Young-Lo; Lim, Dongwook; Chung, Chul; Lee, Young-Wook, E-mail: ywlee2@yonsei.ac.kr [Center for Galaxy Evolution Research and Department of Astronomy, Yonsei University, Seoul 03722 (Korea, Republic of)

    2016-03-15

    Type Ia supernova (SN Ia) cosmology provides the most direct evidence for the presence of dark energy. This result is based on the assumption that the lookback time evolution of SN Ia luminosity, after light curve corrections, would be negligible. Recent studies show, however, that the Hubble residual (HR) of SN Ia is correlated with the mass and morphology of host galaxies, implying the possible dependence of SN Ia luminosity on host galaxy properties. In order to investigate this more directly, we have initiated a spectroscopic survey for early-type host galaxies, for which population age and metallicity can be more reliably determined from the absorption lines. In this first paper of the series, we present here the results from high signal-to-noise ratio (≳100 per pixel) spectra for 27 nearby host galaxies in the southern hemisphere. For the first time in host galaxy studies, we find a significant (∼3.9σ) correlation between host galaxy mass (velocity dispersion) and population age, which is consistent with the “downsizing” trend among non-host early-type galaxies. This result is rather insensitive to the choice of population synthesis models. Since we find no correlation with metallicity, our result suggests that stellar population age is mainly responsible for the relation between host mass and HR. If confirmed, this would imply that the luminosity evolution plays a major role in the systematic uncertainties of SN Ia cosmology.

  8. Host Galaxies of Type Ia Supernovae from the Nearby Supernova Factory

    CERN Document Server

    Childress, M J; Antilogus, P; Aragon, C; Bailey, S; Baltay, C; Bongard, S; Buton, C; Canto, A; Cellier-Holzem, F; Chotard, N; Copin, Y; Fakhouri, H K; Gangler, E; Guy, J; Hsiao, E Y; Kerschhaggl, M; Kim, A G; Kowalski, M; Loken, S; Nugent, P; Paech, K; Pain, R; Pecontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Rigault, M; Runge, K; Scalzo, R; Smadja, G; Tao, C; Thomas, R C; Weaver, B A; Wu, C

    2013-01-01

    We present photometric and spectroscopic observations of galaxies hosting Type Ia supernovae (SNe Ia) observed by the Nearby Supernova Factory (SNfactory). Combining GALEX UV data with optical and near infrared photometry, we employ stellar population synthesis techniques to measure SN Ia host galaxy stellar masses, star-formation rates (SFRs), and reddening due to dust. We reinforce the key role of GALEX UV data in deriving accurate estimates of galaxy SFRs and dust extinction. Optical spectra of SN Ia host galaxies are fitted simultaneously for their stellar continua and emission lines fluxes, from which we derive high precision redshifts, gas-phase metallicities, and Halpha-based SFRs. With these data we show that SN Ia host galaxies present tight agreement with the fiducial galaxy mass-metallicity relation from SDSS for stellar masses log(M_*/M_Sun)>8.5 where the relation is well-defined. The star-formation activity of SN Ia host galaxies is consistent with a sample of comparable SDSS field galaxies, thou...

  9. Frequency of islet cell autoantibodies (IA-2 and GAD in young Brazilian type 1 diabetes patients

    Directory of Open Access Journals (Sweden)

    V.C. Pardini

    1999-10-01

    Full Text Available Type 1 diabetes, as an autoimmune disease, presents several islet cell-specific autoantibodies such as islet cell antibody (ICA, anti-insulin, anti-glutamic acid decarboxylase (GAD and the antibody (Ab against tyrosine phosphatase (PTP-like protein known as ICA-512 (IA-2. In order to determine the frequency of the anti-GAD and anti-IA-2 autoantibodies in Brazilian type 1 diabetes patients we studied 35 diabetes mellitus (DM type 1 patients with recent-onset disease (£12 months and 37 type 1 diabetes patients with long-duration diabetes (>12 months who were compared to 12 children with normal fasting glucose. Anti-GAD65 and anti-IA-2 autoantibodies were detected with commercial immunoprecipitation assays. The frequency of positive results in recent-onset DM type 1 patients was 80.0% for GADAb, 62.9% for IA-2Ab and 82.9% for GADAb and/or IA-2Ab. The long-duration type 1 diabetes subjects presented frequencies of 54.1% for GADAb and IA-2Ab, and 67.5% for GAD and/or IA-2 antibodies. The control group showed no positive cases. Anti-GAD and IA-2 assays showed a high frequency of positivity in these Brazilian type 1 diabetes patients, who presented the same prevalence as a Caucasian population.

  10. Bayesian Analysis of Type Ia Supernova Data

    Institute of Scientific and Technical Information of China (English)

    王晓峰; 周旭; 李宗伟; 陈黎

    2003-01-01

    Recently, the distances to type Ia supernova (SN Ia) at z ~ 0.5 have been measured with the motivation of estimating cosmological parameters. However, different sleuthing techniques tend to give inconsistent measurements for SN Ia distances (~0.3 mag), which significantly affects the determination of cosmological parameters.A Bayesian "hyper-parameter" procedure is used to analyse jointly the current SN Ia data, which considers the relative weights of different datasets. For a flat Universe, the combining analysis yields ΩM = 0.20 ± 0.07.

  11. [Search of heavy metals biosorbents among yeasts of different taxonomic groups].

    Science.gov (United States)

    Lozovaia, O G; Kasatkina, T P; Podgorskiĭ, V S

    2004-01-01

    The use of microbial cells as heavy metal biosorbents is a potential alternative for the existing methods of the environment treatment for pollution by these metals. Yeast may be successfully used in the metals sorption. An agar-plate screening method was used for rapid isolation of metal-accumulating strains of yeast and preliminary estimation of their biosorption capacity. The capacity to accumulate heavy metals, such as copper, zinc, lead, chrome and cobalt was estimated in 68 pigmented and pigmentless yeast strains isolated from different sources. The best capacity of copper and zinc accumulation was shown by pink-coloured Rhodotorula mucilaginosa, Rhodotorula aurantiaca, Rhodotorula glutinis and pigmentless strains of the yeast Candida krusei, Williopsis california.

  12. The Absolute Magnitudes of Type Ia Supernovae in the Ultraviolet

    Science.gov (United States)

    Brown, Peter J.; Roming, Peter W. A.; Milne, Peter; Bufano, Filomena; Ciardullo, Robin; Elias-Rosa, Nancy; Filippenko, Alexei V.; Foley, Ryan J.; Gehrels, Neil; Gronwall, Caryl; Hicken, Malcolm; Holland, Stephen T.; Hoversten, Erik A.; Immler, Stefan; Kirshner, Robert P.; Li, Weidong; Mazzali, Paolo; Phillips, Mark M.; Pritchard, Tyler; Still, Martin; Turatto, Massimo; Vanden Berk, Daniel

    2010-10-01

    We examine the absolute magnitudes and light-curve shapes of 14 nearby (redshift z = 0.004-0.027) Type Ia supernovae (SNe Ia) observed in the ultraviolet (UV) with the Swift Ultraviolet/Optical Telescope. Colors and absolute magnitudes are calculated using both a standard Milky Way extinction law and one for the Large Magellanic Cloud that has been modified by circumstellar scattering. We find very different behavior in the near-UV filters (uvw1 rc covering ~2600-3300 Å after removing optical light, and u ≈ 3000-4000 Å) compared to a mid-UV filter (uvm2 ≈2000-2400 Å). The uvw1 rc - b colors show a scatter of ~0.3 mag while uvm2-b scatters by nearly 0.9 mag. Similarly, while the scatter in colors between neighboring filters is small in the optical and somewhat larger in the near-UV, the large scatter in the uvm2 - uvw1 colors implies significantly larger spectral variability below 2600 Å. We find that in the near-UV the absolute magnitudes at peak brightness of normal SNe Ia in our sample are correlated with the optical decay rate with a scatter of 0.4 mag, comparable to that found for the optical in our sample. However, in the mid-UV the scatter is larger, ~1 mag, possibly indicating differences in metallicity. We find no strong correlation between either the UV light-curve shapes or the UV colors and the UV absolute magnitudes. With larger samples, the UV luminosity might be useful as an additional constraint to help determine distance, extinction, and metallicity in order to improve the utility of SNe Ia as standardized candles.

  13. Cubic nitrides of the sixth group of transition metals formed by nitrogen ion irradiation during metal condensation

    Energy Technology Data Exchange (ETDEWEB)

    Ensinger, W. [Augsburg Univ. (Germany). Inst. fuer Physik; Kiuchi, M. [Osaka National Research Institute, Midorigaoka 1-8-31, Ikeda, Osaka 563 (Japan)

    1996-10-01

    Nitrogen-containing phases of chromium, molybdenum and tungsten were formed by evaporation of the metal under simultaneous nitrogen ion irradiation. With gradually increasing ion irradiation intensity, chromium forms initially Cr and Cr{sub 2}N phase mixtures, then additionally CrN appears, and at the highest intensities pure CrN films are formed. Molybdenum also forms pure nitride MoN under intense ion bombardment. However, in this case two different crystal structures are found, the stable hexagonal phase and the metastable cubic high-temperature phase. The latter is favoured under intense ion irradiation. In the case of tungsten, even at the highest intensities, only phase mixtures of W and W{sub 2}N were formed. These observed differences can be explained by the low reactivity of these metals towards nitrogen and the low chemical stability of the nitrides, particularly of WN. The metastable high-temperature structure of MoN is formed under the particular conditions of ion bombardment with rapid energy dissipation. (orig.)

  14. EnviroAtlas - Des Moines, IA - EnviroAtlas Community Boundary

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the boundary of the Des Moines, IA EnviroAtlas Community. It represents the outside edge of all the block groups included in the...

  15. Modifications of chemical functional groups of Pandanus amaryllifolius Roxb and its effect towards biosorption of heavy metals

    Science.gov (United States)

    Abdullah, Mohd. Zamri; Ismail, Siti Salwa

    2015-07-01

    The utilization of non-living biomass as an alternative biosorbent for heavy metal removal has gain a tremendous consideration through the years. Pandanus amaryllifolius Roxb or pandan leaves, which is widely used as food additives in the South East Asia region, has been selected for its viability in the said effort due to the presence of chemical functional groups on its cellular network that enables the sorption to occur. In order to elucidate the possible mechanisms participated during the heavy metal removal process, the biosorbent undergone a series of modification techniques to alter the chemical functional groups present on its constituent. From the outcome of the chemically-modified biosorbent being subjected to the contact with metal cations, nitrogen- and oxygen-containing groups present on the biosorbent are believed to be responsible for the metal uptake to occur through complexation mechanism. Modifying amine groups causes 14% reduction of Cu(II) uptake, whereas removing protein element increases the uptake to 26% as compared to the unmodified biosorbent. Also, scanning electron micrographs further suggested that the adsorption mechanism could perform in parallel, as attributed to the evidence of porous structure throughout the biosorbent fibrous nature.

  16. Modifications of chemical functional groups of Pandanus amaryllifolius Roxb and its effect towards biosorption of heavy metals

    Energy Technology Data Exchange (ETDEWEB)

    Abdullah, Mohd Zamri, E-mail: zamriab@petronas.com.my; Ismail, Siti Salwa [Chemical Engineering Department, Universiti Teknologi PETRONAS, 31750 Bandar Seri Iskandar, Perak (Malaysia)

    2015-07-22

    The utilization of non-living biomass as an alternative biosorbent for heavy metal removal has gain a tremendous consideration through the years. Pandanus amaryllifolius Roxb or pandan leaves, which is widely used as food additives in the South East Asia region, has been selected for its viability in the said effort due to the presence of chemical functional groups on its cellular network that enables the sorption to occur. In order to elucidate the possible mechanisms participated during the heavy metal removal process, the biosorbent undergone a series of modification techniques to alter the chemical functional groups present on its constituent. From the outcome of the chemically-modified biosorbent being subjected to the contact with metal cations, nitrogen- and oxygen-containing groups present on the biosorbent are believed to be responsible for the metal uptake to occur through complexation mechanism. Modifying amine groups causes 14% reduction of Cu(II) uptake, whereas removing protein element increases the uptake to 26% as compared to the unmodified biosorbent. Also, scanning electron micrographs further suggested that the adsorption mechanism could perform in parallel, as attributed to the evidence of porous structure throughout the biosorbent fibrous nature.

  17. History of the IAS-Society and the IAS-conferences

    NARCIS (Netherlands)

    Hertzberger, B.; Kanade, T.; Groen, F.

    2017-01-01

    This paper describes the development of the IAS-Society and the trends in the Intelligent Autonomous Systems conferences. The first IAS conference was held in 1986 and was the first conference on this topic. The Society, founded in 1994, laid the basis for the organization of the IAS conferences. Th

  18. History of the IAS-Society and the IAS-conferences

    NARCIS (Netherlands)

    Hertzberger, B.; Kanade, T.; Groen, F.

    This paper describes the development of the IAS-Society and the trends in the Intelligent Autonomous Systems conferences. The first IAS conference was held in 1986 and was the first conference on this topic. The Society, founded in 1994, laid the basis for the organization of the IAS conferences.

  19. Ionization of the group 3 metals La, Y and Sc in H2---O2---Ar flames

    Science.gov (United States)

    Patterson, Patricia M.; Goodings, John M.

    1995-09-01

    Four pairs of premixed, fuel-rich/fuel-lean (FR/FL; equivalence ratio [Phi] = 1.5/0.75). H2---O2---Ar flames at four temperatures in the range 1900-2425 K, all at atmospheric pressure, were doped with about 10-6 mole fraction of the group 3 metals La, Y and Sc using atomizer techniques. The metals produce solid particles in the flames and gaseous metallic species. The latter include free metallic atoms, A, near the flame reaction zone, but only the monoxide AO and the oxide-hydroxide OAOH further downstream at equilibrium; the [OAOH]/[AO] ratio varies in FR/FL flames. Metallic ions (produce AO+; further downstream, the ionization level is sustained by the thermal (collisional) ionization of AO to produce AO+ and/or the chemi-ionization of OAOH with H to produce A(OH)2+. The ions AO+, A(OH)2+ and higher hydrates are all rapidly equilibrated by three-body association reactions with water. Ions are lost by dissociative electron-ion recombination of A(OH)2+ and possibly higher hydrates. The chemical ionization of the metallic species by H3O+ was investigated by adding a small quantity of CH4 to the flames. The ion chemistry is discussed in detail. An estimate of the bond dissociation energy D0°(OLa---OH) = 408 ± 40 kJ mol-1 (4.23 ± 0.41 eV) was obtained.

  20. Capacitance of the double electrical layer on the copper-group metals in molten alkali metal halides

    Science.gov (United States)

    Kirillova, E. V.; Stepanov, V. P.

    2016-08-01

    The electrochemical impedance is measured to study the capacitance of the double electrical layer of metallic Au, Ag, and Cu as a function of potential and temperature in nine molten salts, namely, the chlorides, bromides, and iodides of sodium, potassium, and cesium. The C- E curve of a gold electrode has an additional minimum in the anodic branch. This minimum for silver is less pronounced and is only observed at low ac signal frequencies in cesium halides. The additional minimum is not detected for copper in any salt under study. This phenomenon is explained on the assumption that the adsorption of halide anions on a positively charged electrode surface has a predominantly chemical rather than an electrostatic character. The specific adsorption in this case is accompanied by charge transfer through the interface and the formation of an adsorbent-adsorbate covalent bond.

  1. Electrochemical sensors and devices for heavy metals assay in water: the French groups' contribution

    National Research Council Canada - National Science Library

    Pujol, Luca; Evrard, David; Groenen-Serrano, Karine; Freyssinier, Mathilde; Ruffien-Cizsak, Audrey; Gros, Pierre

    2014-01-01

    A great challenge in the area of heavy metal trace detection is the development of electrochemical techniques and devices which are user-friendly, robust, selective, with low detection limits and allowing fast analyses...

  2. Ion mobility studies of carbohydrates as group I adducts: isomer specific collisional cross section dependence on metal ion radius.

    Science.gov (United States)

    Huang, Yuting; Dodds, Eric D

    2013-10-15

    Carbohydrates play numerous critical roles in biological systems. Characterization of oligosaccharide structures is essential to a complete understanding of their functions in biological processes; nevertheless, their structural determination remains challenging in part due to isomerism. Ion mobility spectrometry provides the means to resolve gas phase ions on the basis of their shape-to-charge ratios, thus providing significant potential for separation and differentiation of carbohydrate isomers. Here, we report on the determination of collisional cross sections for four groups of isomeric carbohydrates (including five isomeric disaccharides, four isomeric trisaccharides, two isomeric pentasaccharides, and two isomeric hexasaccharides) as their group I metal ion adducts (i.e., [M + Li](+), [M + Na](+), [M + K](+), [M + Rb](+), and [M + Cs](+)). In all, 65 collisional cross sections were measured, the great majority of which have not been previously reported. As anticipated, the collisional cross sections of the carbohydrate metal ion adducts generally increase with increasing metal ion radius; however, the collisional cross sections were found to scale with the group I cation size in isomer specific manners. Such measurements are of substantial analytical value, as they illustrate how the selection of charge carrier influences carbohydrate ion mobility determinations. For example, certain pairs of isomeric carbohydrates assume unique collisional cross sections upon binding one metal ion, but not another. On the whole, these data suggest a role for the charge carrier as a probe of carbohydrate structure and thus have significant implications for the continued development and application of ion mobility spectrometry for the distinction and resolution of isomeric carbohydrates.

  3. Intelligent Autonomous Systems 11: IAS-11

    NARCIS (Netherlands)

    Christensen, H.I.; Groen, F.; Petriu, E.

    2010-01-01

    This volume contains the proceedings of the eleventh International Conference on Intelligent Autonomous Systems (IAS-11) at the University of Ottawa in Canada. As ever, the purpose of the IAS conference is to bring together leading international researchers with an interest in all aspects of the

  4. Calculating the melting curves by the thermodynamic data matching method: Platinum-group refractory metals (Ru, Os, and Ir)

    Science.gov (United States)

    Kulyamina, E. Yu.; Zitserman, V. Yu.; Fokin, L. R.

    2017-01-01

    A technique for reconstructing thermal properties, including the melting curve, of refractory metals based on the use of experimental data on caloric properties available up to the melting point and some regularities of the Debye-Grüneisen theory has been proposed. The calculation result is the consistent system of high-temperature thermal data, including the thermal expansion coefficient, solid-phase density, and volume jump upon melting. This technique was tried-out on refractory platinum-group metals based on experimental data on the enthalpy of the metals and confirmed by consistency with a thermodynamic calculation using shock-wave experiments and results obtained by the quantum molecular dynamics method.

  5. Carbon-rich dust production in metal-poor galaxies in the Local Group

    CERN Document Server

    Sloan, G C; Lagadec, E; van Loon, J Th; Kraemer, K E; McDonald, I; Groenewegen, M A T; Wood, P R; Bernard-Salas, J; Zijlstra, A A

    2012-01-01

    We have observed a sample of 19 carbon stars in the Sculptor, Carina, Fornax, and Leo I dwarf spheroidal galaxies with the Infrared Spectrograph on the Spitzer Space Telescope. The spectra show significant quantities of dust around the carbon stars in Sculptor, Fornax, and Leo I, but little in Carina. Previous comparisons of carbon stars with similar pulsation properties in the Galaxy and the Magellanic Clouds revealed no evidence that metallicity affected the production of dust by carbon stars. However, the more metal-poor stars in the current sample appear to be generating less dust. These data extend two known trends to lower metallicities. In more metal-poor samples, the SiC dust emission weakens, while the acetylene absorption strengthens. The bolometric magnitudes and infrared spectral properties of the carbon stars in Fornax are consistent with metallicities more similar to carbon stars in the Magellanic Clouds than in the other dwarf spheroidals in our sample. A study of the carbon budget in these sta...

  6. Twin Supernova Studies with SNe Ia from SNfactory

    Science.gov (United States)

    Fakhouri, Hannah; Aldering, G.; Aragon, C.; Hsiao, E.; Loken, S.; Nugent, P.; Perlmutter, S.; Runge, K.; Thomas, R. C.; Antilogous, P.; Bongard, S.; Canto, A.; Pain, R.; Wu, C.; Chotard, N.; Copin, Y.; Gangler, E.; Pereira, R.; Smadja, G.; Pecontal, E.; Baltay, C.; Rabinowitz, D.; Scalzo, R.; Buton, C.; Kerschhaggl, M.; Kowalski, M.; Paech, K.; Tao, C.

    2011-01-01

    We present a study of twin supernovae with spectrophotometric timeseries of nearby Type Ia supernova from the Nearby Supernova Factory (Aldering, et al. 2002). One advantage of "twins” is they offer the best opportunity for having objects with the same intrinsic luminosities and colors, ostensibly leaving only extrinsic factors such as dust to explain any observed differences in brightness and color. Using well-sampled timeseries data for over 100 nearby Hubble-flow SNe Ia, we study the impact of dust on the brightness differences of SN Ia twins in order to improve the standardization of these standardizable candles that have been and will continue to be a primary tool in the determination of cosmological parameters. Specifically we are able to solve for the relative extinction and RV needed to bring the twins into near-perfect agreement. We will present a study of the resulting distribution of RV. In searching for twin supernovae we have found groups of SNe, again differing only by a dust law that accounts for the brightness differences. These groups allow us to look for similarities in subsets of SNe and explore spectrophotometric differences from group to group.

  7. Electrochemical sensors and devices for heavy metals assay in water: the French groups' contribution

    Directory of Open Access Journals (Sweden)

    Luca ePUJOL

    2014-04-01

    Full Text Available A great challenge in the area of heavy metal trace detection is the development of electrochemical techniques and devices which are user-friendly, robust, selective, with low detection limits and allowing fast analyses. This review presents the major contribution of the French scientific academic community in the field of electrochemical sensors and electroanalytical methods within the last 20 years. From the well-known polarography to the up-to-date generation of functionalized interfaces, the different strategies dedicated to analytical performances improvement are exposed: stripping voltammetry, solid mercury-free electrode, ion selective sensor, carbon based materials, chemically modified electrodes, nano-structured surfaces. The paper particularly emphasizes their advantages and limits face to the last Water Frame Directive devoted to the Environmental Quality Standards for heavy metals. Recent trends on trace metal speciation as well as on automatic on line monitoring devices are also evoked.

  8. Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Du, Guodong [Iowa State Univ., Ames, IA (United States)

    2003-01-01

    In this work, the first examples of group 4 metalloporphyrin 1,2-diolato complexes were synthesized through a number of strategies. In general, treatment of imido metalloporphyrin complexes, (TTP)M=NR, (M = Ti, Zr, Hf), with vicinal diols led to the formation of a series of diolato complexes. Alternatively, the chelating pinacolate complexes could be prepared by metathesis of (TTP)MCl2 (M = Ti, Hf) with disodium pinacolate. These complexes were found to undergo C-C cleavage reactions to produce organic carbonyl compounds. For titanium porphyrins, treatment of a titanium(II) alkyne adduct, (TTP)Ti(η2-PhC≡CPh), with aromatic aldehydes or aryl ketones resulted in reductive coupling of the carbonyl groups to produce the corresponding diolato complexes. Aliphatic aldehydes or ketones were not reactive towards (TTP)Ti(η2-PhC≡CPh). However, these carbonyl compounds could be incorporated into a diolato complex on reaction with a reactive precursor, (TTP)Ti[O(Ph)2C(Ph)2O] to provide unsymmetrical diolato complexes via cross coupling reactions. In addition, an enediolato complex (TTP)Ti(OCPhCPhO) was obtained from the reaction of (TTP)Ti(η2-PhC≡CPh) with benzoin. Titanium porphyrin diolato complexes were found to be intermediates in the (TTP)Ti=O-catalyzed cleavage reactions of vicinal diols, in which atmospheric oxygen was the oxidant. Furthermore, (TTP)Ti=O was capable of catalyzing the oxidation of benzyl alcohol and α-hydroxy ketones to benzaldehyde and α-diketones, respectively. Other high valent metalloporphyrin complexes also can catalyze the oxidative diol cleavage and the benzyl alcohol oxidation reactions with dioxygen. A comparison of Ti(IV) and Sn(IV) porphyrin chemistry was undertaken. While chelated diolato complexes were invariably obtained for titanium porphyrins on treatment with 1,2-diols, the reaction of vicinal diols with tin porphyrins gave a number of products, including mono

  9. Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Guodong Du

    2004-12-19

    In this work, the first examples of group 4 metalloporphyrin 1,2-diolato complexes were synthesized through a number of strategies. In general, treatment of imido metalloporphyrin complexes, (TTP)M=NR, (M = Ti, Zr, Hf), with vicinal diols led to the formation of a series of diolato complexes. Alternatively, the chelating pinacolate complexes could be prepared by metathesis of (TTP)MCl{sub 2} (M = Ti, Hf) with disodium pinacolate. These complexes were found to undergo C-C cleavage reactions to produce organic carbonyl compounds. For titanium porphyrins, treatment of a titanium(II) alkyne adduct, (TTP)Ti({eta}{sup 2}-PhC{triple_bond}CPh), with aromatic aldehydes or aryl ketones resulted in reductive coupling of the carbonyl groups to produce the corresponding diolato complexes. Aliphatic aldehydes or ketones were not reactive towards (TTP)Ti({eta}{sup 2}-PhC{triple_bond}CPh). However, these carbonyl compounds could be incorporated into a diolato complex on reaction with a reactive precursor, (TTP)Ti[O(Ph){sub 2}C(Ph){sub 2}O] to provide unsymmetrical diolato complexes via cross coupling reactions. In addition, an enediolato complex (TTP)Ti(OCPhCPhO) was obtained from the reaction of (TTP)Ti({eta}{sup 2}-PhC{triple_bond}CPh) with benzoin. Titanium porphyrin diolato complexes were found to be intermediates in the (TTP)Ti=O-catalyzed cleavage reactions of vicinal diols, in which atmospheric oxygen was the oxidant. Furthermore, (TTP)Ti=O was capable of catalyzing the oxidation of benzyl alcohol and {alpha}-hydroxy ketones to benzaldehyde and {alpha}-diketones, respectively. Other high valent metalloporphyrin complexes also can catalyze the oxidative diol cleavage and the benzyl alcohol oxidation reactions with dioxygen. A comparison of Ti(IV) and Sn(IV) porphyrin chemistry was undertaken. While chelated diolato complexes were invariably obtained for titanium porphyrins on treatment with 1,2-diols, the reaction of vicinal diols with tin porphyrins gave a number of

  10. Global exploration and production capacity for platinum-group metals from 1995 through 2015

    Science.gov (United States)

    Wilburn, David R.

    2012-01-01

    Platinum-group metals (PGMs) are required in a variety of commercial, industrial, and military applications for many existing and emerging technologies, yet the United States is highly dependent on foreign sources of PGMs. Information on global exploration for PGMs since 1995 has been used in this study as a basis for identifying locations where the industry has determined that exploration has provided data sufficient to warrant development of a new mine or expansion of an existing operation or where a significant increase in capacity for PGMs is anticipated by 2015. Discussions include an overview of the industry and the selected sites, factors affecting mineral supply, and circumstances leading to the development of mineral properties with the potential to affect mineral supply. Of the 52 sites or regional operations that were considered in this analysis, 16 sites were producing before 1995, 28 sites commenced production from 1995 through 2010, and 8 sites were expected to begin production from 2011 through 2015 if development plans came to fruition. The United States imports PGMs primarily from Canada, Russia, South Africa, and Zimbabwe to meet increasing demand for these materials in a variety of specialized and high-tech applications. Feed sources of PGMs are changing in South Africa and Russia, which together accounted for about 89 percent of platinum production and 82 percent of palladium production in 2009. A greater amount of South African PGM capacity is likely to come from deeper, higher cost Upper Group Reef seam 2 deposits and deposits in the Eastern Bushveld area. Future Russian PGM capacity is likely to come from ore zones with generally lower PGM content and different platinum-to-palladium ratios than the nickel-rich ore that dominated PGM supply in the 1990s. Because PGM supply from Canada and Russia is derived as a byproduct of copper and nickel mining, the PGM supply from these countries is influenced by economic, environmental, political, and

  11. Global exploration and production capacity for platinum-group metals from 1995 through 2015

    Science.gov (United States)

    Wilburn, David R.

    2012-01-01

    Platinum-group metals (PGMs) are required in a variety of commercial, industrial, and military applications for many existing and emerging technologies, yet the United States is highly dependent on foreign sources of PGMs. Information on global exploration for PGMs since 1995 has been used in this study as a basis for identifying locations where the industry has determined that exploration has provided data sufficient to warrant development of a new mine or expansion of an existing operation or where a significant increase in capacity for PGMs is anticipated by 2015. Discussions include an overview of the industry and the selected sites, factors affecting mineral supply, and circumstances leading to the development of mineral properties with the potential to affect mineral supply. Of the 52 sites or regional operations that were considered in this analysis, 16 sites were producing before 1995, 28 sites commenced production from 1995 through 2010, and 8 sites were expected to begin production from 2011 through 2015 if development plans came to fruition. The United States imports PGMs primarily from Canada, Russia, South Africa, and Zimbabwe to meet increasing demand for these materials in a variety of specialized and high-tech applications. Feed sources of PGMs are changing in South Africa and Russia, which together accounted for about 89 percent of platinum production and 82 percent of palladium production in 2009. A greater amount of South African PGM capacity is likely to come from deeper, higher cost Upper Group Reef seam 2 deposits and deposits in the Eastern Bushveld area. Future Russian PGM capacity is likely to come from ore zones with generally lower PGM content and different platinum-to-palladium ratios than the nickel-rich ore that dominated PGM supply in the 1990s. Because PGM supply from Canada and Russia is derived as a byproduct of copper and nickel mining, the PGM supply from these countries is influenced by economic, environmental, political, and

  12. Isotope exchange of indoles with D/sub 2/O over group VIII metals

    Energy Technology Data Exchange (ETDEWEB)

    Karakhanov, E.A.; Dedov, A.G.; Kurts, A.L.; Luzikov, Yu.N.

    1981-08-01

    Results of H - D exchange between indole and its methyl derivatives and D/sub 2/O over metallic Pt, Rh, and Pd are reported. The composition of the reaction mixture after the isotopic exchange was determined by mass spectrometry. The order of reactivity of the metals was Pt>Pd>Rh. It was determined that it was only the heterocycle ..pi..-electron system that interacts with the surface and mainly the hydrogens at C/sub 2/ and C/sub 3/ that undergo exchange and not those bonded to the N. (BLM)

  13. Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

    KAUST Repository

    Despagnet-Ayoub, Emmanuelle

    2013-05-24

    Attempts to install a tridentate aniline-NHC-phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene-early- transition-metal chemistry. © 2013 American Chemical Society.

  14. Evaluating Systematic Dependencies of Type Ia Supernovae: The Influence of Progenitor Ne22 Content on Dynamics

    CERN Document Server

    Townsley, Dean M; Calder, Alan C; Chamulak, David A; Brown, Edward F; Timmes, F X

    2009-01-01

    We present a theoretical framework for formal study of systematic effects in Supernovae Type Ia (SN Ia) that utilizes 2-d simulations to implement a form of the deflagration-detonation transition (DDT) explosion scenario. The framework is developed from a randomized initial condition that leads to a sample of simulated SN Ia whose Ni56 masses have a similar average and range to those observed, and have many other modestly realistic features such as the velocity extent of intermediate mass elements. The intended purpose is to enable statistically well-defined studies of both physical and theoretical parameters of the SN Ia explosion simulation. We present here a thorough description of the outcome of the SN Ia explosions produced by our current simulations. A first application of this framework is utilized to study the dependence of the SN Ia on the Ne22 content, which is known to be directly influenced by the progenitor stellar population's metallicity. Our study is very specifically tailored to measure how t...

  15. The Dependence of Type Ia Supernova Luminosities on their Host Galaxies

    CERN Document Server

    Sullivan, M; Howell, D A; Neill, J D; Astier, P; Balland, C; Basa, S; Carlberg, R G; Fouchez, D; Guy, J; Hardin, D; Hook, I M; Pain, R; Palanque-Delabrouille, N; Perrett, K M; Pritchet, C J; Regnault, N; Rich, J; Ruhlmann-Kleider, V; Baumont, S; Hsiao, E; Kronborg, T; Lidman, C; Perlmutter, S; Walker, E S

    2010-01-01

    (Abridged) Precision cosmology with Type Ia supernovae (SNe Ia) makes use of the fact that SN Ia luminosities depend on their light-curve shapes and colours. Using Supernova Legacy Survey (SNLS) and other data, we show that there is an additional dependence on the global characteristics of their host galaxies: events of the same light-curve shape and colour are, on average, 0.08mag (~4.0sigma) brighter in massive host galaxies (presumably metal-rich) and galaxies with low specific star-formation rates (sSFR). SNe Ia in galaxies with a low sSFR also have a smaller slope ("beta") between their luminosities and colours with ~2.7sigma significance, and a smaller scatter on SN Ia Hubble diagrams (at 95% confidence), though the significance of these effects is dependent on the reddest SNe. SN Ia colours are similar between low-mass and high-mass hosts, leading us to interpret their luminosity differences as an intrinsic property of the SNe and not of some external factor such as dust. If the host stellar mass is in...

  16. Phosphine and phosphine oxide groups in metal-organic frameworks detected by P K-edge XAS.

    Science.gov (United States)

    Morel, F L; Pin, S; Huthwelker, T; Ranocchiari, M; van Bokhoven, J A

    2015-02-07

    Phosphine metal-organic frameworks (P-MOFs) are crystalline porous coordination polymers that contain phosphorus functional groups within their pores. We present the use of X-ray absorption spectroscopy (XAS) at the P K-edge to determine the phosphine to phosphine oxide ratio in two P-MOFs with MIL-101 topology. The phosphorus oxidation state is of particular interest as it strongly influences the coordination affinity of these materials for transition metals. This method can determine the oxidation state of phosphorus even when the material contains paramagnetic nuclei, differently from NMR spectroscopy. We observed that phosphine in LSK-15 accounts for 72 ± 4% of the total phosphorus groups and that LSK-12 contains only phosphine oxide.

  17. The progenitors of supernovae Type Ia

    Science.gov (United States)

    Toonen, Silvia

    2014-09-01

    Despite the significance of Type Ia supernovae (SNeIa) in many fields in astrophysics, SNeIa lack a theoretical explanation. SNeIa are generally thought to be thermonuclear explosions of carbon/oxygen (CO) white dwarfs (WDs). The canonical scenarios involve white dwarfs reaching the Chandrasekhar mass, either by accretion from a non-degenerate companion (single-degenerate channel, SD) or by a merger of two CO WDs (double-degenerate channel, DD). The study of SNeIa progenitors is a very active field of research for binary population synthesis (BPS) studies. The strength of the BPS approach is to study the effect of uncertainties in binary evolution on the macroscopic properties of a binary population, in order to constrain binary evolutionary processes. I will discuss the expected SNeIa rate from the BPS approach and the uncertainties in their progenitor evolution, and compare with current observations. I will also discuss the results of the POPCORN project in which four BPS codes were compared to better understand the differences in the predicted SNeIa rate of the SD channel. The goal of this project is to investigate whether differences in the simulated populations are due to numerical effects or whether they can be explained by differences in the input physics. I will show which assumptions in BPS codes affect the results most and hence should be studied in more detail.

  18. Ultraviolet Diversity of Type Ia Supernovae

    CERN Document Server

    Foley, Ryan J; Brown, P; Filippenko, A V; Fox, O D; Hillebrandt, W; Kirshner, R P; Marion, G H; Milne, P A; Parrent, J T; Pignata, G; Stritzinger, M D

    2016-01-01

    Ultraviolet (UV) observations of Type Ia supernovae (SNe Ia) probe the outermost layers of the explosion, and UV spectra of SNe Ia are expected to be extremely sensitive to differences in progenitor composition and the details of the explosion. Here we present the first study of a sample of high signal-to-noise ratio SN Ia spectra that extend blueward of 2900 A. We focus on spectra taken within 5 days of maximum brightness. Our sample of ten SNe Ia spans the majority of the parameter space of SN Ia optical diversity. We find that SNe Ia have significantly more diversity in the UV than in the optical, with the spectral variance continuing to increase with decreasing wavelengths until at least 1800 A (the limit of our data). The majority of the UV variance correlates with optical light-curve shape, while there are no obvious and unique correlations between spectral shape and either ejecta velocity or host-galaxy morphology. Using light-curve shape as the primary variable, we create a UV spectral model for SNe I...

  19. Constraining cosmological parameter with SN Ia

    Science.gov (United States)

    Indra Putri, A. N.; Wulandari, H. R. Tri

    2016-11-01

    A type I supemovae (SN Ia) is an exploding white dwarf, whose mass exceeds Chandrasekar limit (1.44 solar mass). If a white dwarf is in a binary system, it may accrete matter from the companion, resulting in an excess mass that cannot be balanced by the pressure of degenerated electrons in the core. SNe Ia are highly luminous objects, that they are visible from very high distances. After some corrections (stretch (s), colour (c), K-corrections, etc.), the variations in the light curves of SNe Ia can be suppressed to be no more than 10%. Their high luminosity and almost uniform intrinsic brightness at the peak light, i.e. MB ∼ -19, make SNe Ia ideal standard candle. Because of their visibility from large distances, SNe Ia can be employed as a cosmological measuring tool. It was analysis of SNe Ia data that indicated for the first time, that the universe is not only expanding, but also accelerating. This work analyzed a compilation of SNe Ia data to determine several cosmological parameters (H0, Ωm, Ωa, and w). It can be concluded from the analysis, that our universe is a flat, dark energy dominated universe, and that the cosmological constant A is a suitable candidate for dark energy.

  20. Luminosity distributions of Type Ia Supernovae

    CERN Document Server

    Ashall, Chris; Sasdelli, Michele; Prentice, Simon

    2016-01-01

    We have assembled a dataset of 165 low redshift, $z<$0.06, publicly available type Ia supernovae (SNe Ia). We produce maximum light magnitude ($M_{B}$ and $M_{V}$) distributions of SNe Ia to explore the diversity of parameter space that they can fill. Before correction for host galaxy extinction we find that the mean $M_{B}$ and $M_{V}$ of SNe Ia are $-18.58\\pm0.07$mag and $-18.72\\pm0.05$mag respectively. Host galaxy extinction is corrected using a new method based on the SN spectrum. After correction, the mean values of $M_{B}$ and $M_{V}$ of SNe Ia are $-19.10\\pm0.06$ and $-19.10\\pm0.05$mag respectively. After correction for host galaxy extinction, `normal' SNeIa ($\\Delta m_{15}(B)<1.6$mag) fill a larger parameter space in the Width-Luminosity Relation (WLR) than previously suggested, and there is evidence for luminous SNe Ia with large $\\Delta m_{15}(B)$. We find a bimodal distribution in $\\Delta m_{15}(B)$, with a pronounced lack of transitional events at $\\Delta m_{15}(B)$=1.6 mag. We confirm that ...

  1. The synthesis and characterization of organometallic copolymers with Mn-Re binuclear transition-metal group in the side chain

    Institute of Scientific and Technical Information of China (English)

    XU; Zhi; FENG; Gang; BAI; Zhifeng; MA; Yongqiang; CHANG; Weixing; LI; Jing

    2006-01-01

    Novel organometallic copolymers with Mn-Re binuclear transition-metal groups in the side chain are synthesized and characterized. The structure and properties of the copolymers are characterized by GPC, DSC, TG, NMR, FT-IR, UV-Vis spectra and elemental analysis. The glass transition temperature and UV-Vis spectra properties of these three organometallic copolymers are found to be different from the normal polystyrene. New synthetic strategy for the synthesis of organometallic copolymer is developed.

  2. Competitive platinum-group-metal (PGM) supply from the Eastern Limb, Bushveld Complex: Geological, mining and mineral economic aspects

    CSIR Research Space (South Africa)

    McGill, JE

    2011-08-01

    Full Text Available -GROUP-METAL (PGM) SUPPLY FROM THE EASTERN LIMB, BUSHVELD COMPLEX: GEOLOGICAL, MINING, AND MINERAL ECONOMIC ASPECTS Dr. Jeannette E. McGill & Prof. Murray W. Hitzman ACKNOWLEDGEMENTS ? COUNCIL FOR SCIENTIFIC AND INDUSTRIAL RESEARCH (CSIR) ? Centre for Mining... Innovation ? Office of Graduate Studies, Fogarty Endowment ? Mr. VISHNU PILLAY (EXECUTIVE HEAD: JV?S ? Anglo Platinum) ? ACADEMIC ADVISORS Prof. Murray Hitzman (Economic Geology); Dr. Hugh Miller (Mining Engineering); Prof. Rodderick Eggert (Mineral...

  3. Development of Novel Non-Pt Group Metal Electrocatalysts for PEM Fuel Cell Applications

    Energy Technology Data Exchange (ETDEWEB)

    Mukerjee, Sanjeev [Northeastern Univ., Boston, MA (United States). Dept. of Chemistry and Chemical Biology; Atanassov, Plamen [Univ. of New Mexico, Albuquerque, NM (United States); Barton, Scott [Michigan State Univ., East Lansing, MI (United States); Dale, Nilesh [Nissan Technical Center North America (NTCNA), Farmington Hills, MI (United States); Halevi, Bar [Pajarito Powder LLC, Albuquerque, NM (United States)

    2016-01-04

    The objective of this multi-institutional effort was to comprehensively pursue the goal of eliminating noble metal (Pt group metals, PGM) from the cathodic oxygen reduction reaction (ORR) electrode thereby providing a quantum leap in lowering the overall PGM loading in a polymer electrolyte fuel cell (PEMFC). The overall project scope encompassed (a) comprehensive materials discovery effort, (b) a concomitant effort to scale up these materials with very high ( ±5%) reproducibility, both intra and inter, (c) understanding mass transport in porous medium both in gas diffusion and micro-porous layers for enhanced areal activity, (d) understanding mechanistic aspects of active site structure and ORR electrocatalytic pathway. Overall project milestones and metrics were (a) first phase effort based on performance in oxygen where the project’s Go/No-Go decision point milestone of 100 mA/cm2 at 0.8 V (internal resistance-free, iR-free) at 80°C, pure H2/O2, with 1.5 bar total pressure was met. Subsequently, the principle objectives were to (a) transition the project from H2/O2 to H2/Air with slated target of exceeding 30 mA/cm2 @ 0.8 V, 2.5 bar total pressure and an end of the project target of 1 A/cm2 @ 0.4 V (same total pressure), both under 100% relative humidity. The target for catalyst material scale up was to achieve 100 g batch size at the end of the program. This scale up target had a quality control milestone of less than 5% variation of activity measured with H2/Air (2.5 bar total pressure) at 0.8 V. In addition, the project also aimed at arriving at a unified understanding of the nature of active sites in these catalysts as well as some preliminary understanding of the mechanistic pathway. Also addressed is the development of an integrated method for determination of mass transport parameters using a combination of Helox experiments and modeling of the gas

  4. Infrared Light Curves of Type Ia Supernovae

    Science.gov (United States)

    Friedman, Andrew Samuel

    2012-05-01

    This thesis presents the CfAIR2 data set, which includes over 4000 near-Infrared (NIR) JHK8-band measurements of 104 Type Ia Supernovae (SN Ia) observed from 2005-2011 using PAIRITEL, the 1.3-m Peters Automated InfraRed Imaging TELescope at the Fred Lawrence Whipple Observatory (FLWO) on Mount Hopkins, Arizona. While the discovery of dark energy and most subsequent supernova cosmology has been performed using optical and Ultraviolet wavelength observations of SN Ia, a growing body of evidence suggests that NIR SN Ia observations will be crucial for future cosmological studies. Whereas SN Ia observed at optical wavelengths have been shown to be excellent standardizeable candles, using empirical correlations between luminosity, light curve shape, and color, the CfAIR2 data set strengthens the evidence that SN Ia at NIR wavelengths are essentially standard candles, even without correction for light-curve shape or for reddening. CfAIR2 was obtained as part of the CfA Supernova Program, an ongoing multi-wavelength follow-up effort at FLWO designed to observe high-quality, densely sampled light curves and spectra of hundreds of low-redshift SN Ia. CfAIR2 is the largest homogeneously observed and processed NIR data set of its kind to date, nearly tripling the number of individual JHK8-band observations and nearly doubling the set of SN Ia with published NIR light curves in the literature. Matched only by the recently published Carnegie Supernova Project sample, CfAIR2 complements the large and growing set of low-redshift optical and NIR SN Ia observations obtained by the CfA and other programs, making this data set a unique and particularly valuable local universe anchor for future supernova cosmology.

  5. 22nd IAS Meeting of Sedimentology

    Institute of Scientific and Technical Information of China (English)

    DavorPavelic; IgorVlahovic; JosipHalamic

    2004-01-01

    The 22nd IAS Meeting of Sedimentology was held in the Convention Centre of the Grand Hotel Adriatic, in a small touristic town Opatija, located on the eastern Adriatic coast where Central Europe and the Mediterranean meet. It was the second IAS Meeting held in Croatia--the first one, 4th IAS Regional Meeting of Sedimentology, was held in Split in 1983. The Meeting in Opatija was organized by the Institute of Geology (Zagreb) and the Croatian Geological Society. The sponsor was Ministry of Science and Technology of the Reoublic of Croatia.

  6. SNe Ia as a cosmological probe

    CERN Document Server

    Meng, Xiangcun; Han, Zhanwen

    2015-01-01

    Type Ia supernovae luminosities can be corrected to render them useful as standard candles able to probe the expansion history of the universe. This technique was successful applied to discover the present acceleration of the universe. As the number of SNe Ia observed at high redshift increases and analysis techniques are perfected, people aim to use this technique to probe the equation of state of the dark energy. Nevertheless, the nature of SNe Ia progenitors remains controversial and concerns persist about possible evolution effects that may be larger and harder to characterize than the more obvious statistical uncertainties.

  7. THE FIRST MAXIMUM-LIGHT ULTRAVIOLET THROUGH NEAR-INFRARED SPECTRUM OF A TYPE Ia SUPERNOVA

    Energy Technology Data Exchange (ETDEWEB)

    Foley, Ryan J.; Marion, G. Howie; Challis, Peter; Kirshner, Robert P.; Berta, Zachory K. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Kromer, Markus; Taubenberger, Stefan; Hillebrandt, Wolfgang; Roepke, Friedrich K.; Ciaraldi-Schoolmann, Franco; Seitenzahl, Ivo R. [Max-Planck-Institut fuer Astrophysik, Karl-Schwarzschild-Strasse 1, D-85748 Garching bei Muenchen (Germany); Pignata, Giuliano [Departamento de Ciencias Fisicas, Universidad Andres Bello, Avda. Republica 252, Santiago (Chile); Stritzinger, Maximilian D. [Department of Physics and Astronomy, Aarhus University, Ny Munkegade, DK-8000 Aarhus C (Denmark); Filippenko, Alexei V.; Li Weidong; Silverman, Jeffrey M. [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States); Folatelli, Gaston [Kavli Institute for the Physics and Mathematics of the Universe (Kavli IPMU, WPI), Todai Institutes for Advanced Study, University of Tokyo, Kashiwa 277-8583 (Japan); Hsiao, Eric Y.; Morrell, Nidia I. [Carnegie Observatories, Las Campanas Observatory, La Serena (Chile); Simcoe, Robert A., E-mail: rfoley@cfa.harvard.edu [MIT-Kavli Institute for Astrophysics and Space Research, 77 Massachusetts Avenue, 37-664D Cambridge, MA 02139 (United States); and others

    2012-07-01

    We present the first maximum-light ultraviolet (UV) through near-infrared (NIR) Type Ia supernova (SN Ia) spectrum. This spectrum of SN 2011iv was obtained nearly simultaneously by the Hubble Space Telescope at UV/optical wavelengths and the Magellan Baade telescope at NIR wavelengths. These data provide the opportunity to examine the entire maximum-light SN Ia spectral energy distribution. Since the UV region of an SN Ia spectrum is extremely sensitive to the composition of the outer layers of the explosion, which are transparent at longer wavelengths, this unprecedented spectrum can provide strong constraints on the composition of the SN ejecta, and similarly the SN explosion and progenitor system. SN 2011iv is spectroscopically normal, but has a relatively fast decline ({Delta}m{sub 15}(B) = 1.69 {+-} 0.05 mag). We compare SN 2011iv to other SNe Ia with UV spectra near maximum light and examine trends between UV spectral properties, light-curve shape, and ejecta velocity. We tentatively find that SNe with similar light-curve shapes but different ejecta velocities have similar UV spectra, while those with similar ejecta velocities but different light-curve shapes have very different UV spectra. Through a comparison with explosion models, we find that both a solar-metallicity W7 and a zero-metallicity delayed-detonation model provide a reasonable fit to the spectrum of SN 2011iv from the UV to the NIR.

  8. The single degenerate channel for the progenitor of type Ia supernovae

    CERN Document Server

    Meng, Xiangcun; Han, Zhanwen

    2008-01-01

    We have carried out a detailed study of the single-degenerate channel for the progenitors of type Ia supernovae (SNe Ia). In the model, a carbon-oxygen white dwarf (CO WD) accretes hydrogen-rich material from an unevolved or a slightly evolved non-degenerate companion to increase its mass to Chandrasekhar mass limit. Incorporating the prescription of \\cite{HAC99a} for the accretion efficiency into Eggleton's stellar evolution code and assuming that the prescription is valid for all metallicities, we performed binary stellar evolution calculations for more than 25,000 close WD binary systems with various metallicities. The initial parameter spaces for SNe Ia are presented in an orbital period-secondary mass ($\\log P_{\\rm i}, M_{\\rm 2}^{\\rm i}$) plane for each $Z$. Adopting the results above, we studied the birth rate of SNe Ia for various $Z$ via binary population synthesis. From the study, we see that for a high $Z$, SNe Ia occur systemically earlier and the peak value of the birth rate is larger if a single ...

  9. SNe Ia host galaxy properties from Sloan Digital Sky Survey-II spectroscopy

    CERN Document Server

    Johansson, Jonas; Pforr, Janine; Maraston, Claudia; Nichol, Robert C; Smith, Mathew; Lampeitl, Hubert; Beifiori, Alessandra; Gupta, Ravi R; Schneider, Donald P

    2012-01-01

    We study the stellar populations of SNe Ia host galaxies using SDSS-II spectroscopy. We focus on the relationships of SNe Ia properties with stellar velocity dispersion and the stellar population parameters age, metallicity and element abundance ratios derived by fitting absorption line indices to stellar population models. We concentrate on a sub-sample of 84 SNe Ia from the SDSS-II Supernova Survey. In agreement with previous findings, we find that SALT2 stretch factor values show the strongest dependence on stellar population age. Hence, SNe Ia peak-luminosity is closely related to the age of the stellar progenitor systems, where more luminous SNe Ia appear in younger stellar populations. We find no statistically significant trends in the Hubble residual with any of the stellar population parameters studied, including age and metallicity contrary to the literature, as well as with stellar velocity dispersion. Moreover, we find that the method of stellar mass derivation is affecting the Hubble residual-mass...

  10. Metal Organic Frameworks as Solid Catalysts in Condensation Reactions of Carbonyl Groups

    OpenAIRE

    Dhakshina Moorthy, Amarajothi; Opanasenko, Maksym; Cejka, Jirí; García Gómez, Hermenegildo

    2013-01-01

    This review summarizes the use of metal organic frameworks (MOFs) as solid catalysts for condensation reactions. After an introductory section, in which condensation reactions are generally presented, a list of the MOFs employed as condensation catalyst is given. The main part of the present review is organized according to the use of MOFs as solid acids, solid bases or as bi-functional solids containing both acid and basic sites. Throughout the review, the emphasis has been made on discussin...

  11. Group III alcohol dehydrogenase from Pectobacterium atrosepticum: insights into enzymatic activity and organization of the metal ion-containing region.

    Science.gov (United States)

    Elleuche, Skander; Fodor, Krisztian; von der Heyde, Amélie; Klippel, Barbara; Wilmanns, Matthias; Antranikian, Garabed

    2014-05-01

    NAD(P)(+)-dependent alcohol dehydrogenases (ADH) are widely distributed in all phyla. These proteins can be assigned to three nonhomologous groups of isozymes, with group III being highly diverse with regards to catalytic activity and primary structure. Members of group III ADHs share a conserved stretch of amino acid residues important for cofactor binding and metal ion coordination, while sequence identities for complete proteins are highly diverse (90 %). A putative group III ADH PaYqhD has been identified in BLAST analysis from the plant pathogenic enterobacterium Pectobacterium atrosepticum. The PaYqhD gene was expressed in the heterologous host Escherichia coli, and the recombinant protein was purified in a two-step purification procedure to homogeneity indicating an obligate dimerization of monomers. Four conserved amino acid residues involved in metal ion coordination were substituted with alanine, and their importance for catalytic activity was confirmed by circular dichroism spectrum determination, in vitro, and growth experiments. PaYqhD exhibits optimal activity at 40 °C with short carbon chain aldehyde compounds and NADPH as cofactor indicating the enzyme to be an aldehyde reductase. No oxidative activities towards alcoholic compounds were detectable. EDTA completely inhibited catalytic activity and was fully restored by the addition of Co(2+). Activity measurements together with sequence alignments and structure analysis confirmed that PaYqhD belongs to the butanol dehydrogenase-like enzymes within group III of ADHs.

  12. The Oldest Stars of the Extremely Metal-Poor Local Group Dwarf Irregular Galaxy Leo A

    CERN Document Server

    Schulte-Ladbeck, R E; Drozdovsky, I O; Greggio, L; Crone, M M; Schulte-Ladbeck, Regina E.; Hopp, Ulrich; Drozdovsky, Igor O.; Greggio, Laura; Crone, Mary M.

    2002-01-01

    We present deep Hubble Space Telescope single-star photometry of Leo A in B, V, and I. Our new field of view is offset from the centrally located field observed by Tolstoy et al. (1998) in order to expose the halo population of this galaxy. We report the detection of metal-poor red horizontal branch stars, which demonstrate that Leo A is not a young galaxy. In fact, Leo A is as least as old as metal-poor Galactic Globular Clusters which exhibit red horizontal branches, and are considered to have a minimum age of about 9 Gyr. We discuss the distance to Leo A, and perform an extensive comparison of the data with stellar isochrones. For a distance modulus of 24.5, the data are better than 50% complete down to absolute magnitudes of 2 or more. We can easily identify stars with metallicities between 0.0001 and 0.0004, and ages between about 5 and 10 Gyr, in their post-main-sequence phases, but lack the detection of main-sequence turnoffs which would provide unambiguous proof of ancient (>10 Gyr) stellar generation...

  13. Bioengineered human IAS reconstructs with functional and molecular properties similar to intact IAS

    OpenAIRE

    Singh, Jagmohan; Rattan, Satish

    2012-01-01

    Because of its critical importance in rectoanal incontinence, we determined the feasibility to reconstruct internal anal sphincter (IAS) from human IAS smooth muscle cells (SMCs) with functional and molecular attributes similar to the intact sphincter. The reconstructs were developed using SMCs from the circular smooth muscle layer of the human IAS, grown in smooth muscle differentiation media under sterile conditions in Sylgard-coated tissue culture plates with central Sylgard posts. The bas...

  14. A review of type Ia supernova spectra

    CERN Document Server

    Parrent, J; Parthasarathy, M

    2014-01-01

    SN 2011fe was the nearest and best-observed type Ia supernova in a generation, and brought previous incomplete datasets into sharp contrast with the detailed new data. In retrospect, documenting spectroscopic behaviors of type Ia supernovae has been more often limited by sparse and incomplete temporal sampling than by consequences of signal-to-noise ratios, telluric features, or small sample sizes. As a result, type Ia supernovae have been primarily studied insofar as parameters discretized by relative epochs and incomplete temporal snapshots near maximum light. Here we discuss a necessary next step toward consistently modeling and directly measuring spectroscopic observables of type Ia supernova spectra. In addition, we analyze current spectroscopic data in the parameter space defined by empirical metrics, which will be relevant even after progenitors are observed and detailed models are refined.

  15. Improvements to type Ia supernova models

    Science.gov (United States)

    Saunders, Clare M.

    Type Ia Supernovae provided the first strong evidence of dark energy and are still an important tool for measuring the accelerated expansion of the universe. However, future improvements will be limited by systematic uncertainties in our use of Type Ia supernovae as standard candles. Using Type Ia supernovae for cosmology relies on our ability to standardize their absolute magnitudes, but this relies on imperfect models of supernova spectra time series. This thesis is focused on using data from the Nearby Supernova Factory both to understand current sources of uncertainty in standardizing Type Ia supernovae and to develop techniques that can be used to limit uncertainty in future analyses. (Abstract shortened by ProQuest.).

  16. Differential effects of (-)-baclofen on Ia and descending monosynaptic EPSPs.

    Science.gov (United States)

    Jiménez, I; Rudomin, P; Enriquez, M

    1991-01-01

    1. In cats anesthetized with alpha-chloralose, population synaptic responses of motoneurons produced by stimulation of group I afferents were recorded from ventral roots with a sucrose gap or extracellularly from the motor pool. These responses were depressed, and often abolished, following the intravenous injection of 1-3 mg/kg of (-)-baclofen, a presumed GABAb agonist. 2. The monosynaptic population responses of motoneurons produced by stimulation of the ipsilateral ventromedial funiculus (VMF), the bulbar reticular formation or the vestibular nucleus, were also depressed following the administration of (-)-baclofen, but to a lesser degree than responses produced by stimulation of group I fibers. 3. Depression of the synaptic actions of Ia and of descending fibers following the administration of (-)-baclofen occurred without significant changes in the presynaptic volley recorded from the cord dorsum. However, in 3/4 experiments the intraspinally recorded Ia terminal potential was reduced following the injection of (-)-baclofen. The VMF terminal potentials were also depressed, but to a lesser degree. 4. Intracellular recordings from spinal motoneurons indicate that the (-)-baclofen-induced depression of the monosynaptic Ia- and VMF-EPSPs occurred without important changes in the time course of EPSP decay. This suggests that with the amounts used, postsynaptic changes were not contributing significantly to the EPSP depression. 5. It is suggested that (-)-baclofen depresses synaptic transmission probably by activation of GABAb receptors located at the intraspinal terminations of Ia and descending fibers. The lower sensitivity of VMF actions to (-)-baclofen would be accounted for by a relatively low density of baclofen receptors in descending fiber terminals.

  17. Close binary white dwarfs and supernovae IA

    Directory of Open Access Journals (Sweden)

    R. Napiwotzki

    2004-01-01

    Full Text Available Informamos sobre el estado actual de los \\surveys" de velocidades radiales para binarias de enanas blancas (degeneradas dobles - DDs incluyendo SPY (Exploraci on ESO de progenitoras de supernovas Ia que recien- temente se llevaron a cabo en el VLT. Una amplia muestra de DDs nos permitir a poner fuertes restricciones sobre las fases evolutivas de los sistemas progenitores de binarias cercanas y tambi en llevar a cabo pruebas observacionales del escenario DD para supernovas de tipo Ia.

  18. [Synthesis and luminescent spectral characteristics of porphyrin complexes with platinum group metals].

    Science.gov (United States)

    Rumiantseva, V D; Ivanovskaia, N P; Konovalenko, L I; Tsukanov, S V; Mironov, A F; Osin, N S

    2008-01-01

    The synthesis of natural and synthetic porphyrin complexes with Pt, Pd, Rh, and Ru is reported. Their electronic absorption spectra, phosphorescence spectra, and lifetimes at room temperature both in the presence and in the absence of oxygen were studied. It has been shown that the variation of the nature of the central metal atom and of the substituents in pyrrole and phenyl rings allows the obtaining of metalloporphyrins with various phosphorescence excitation and phosphorescing emission spectra at room temperature. The English version of the paper: Russian Journal of Bioorganic Chemistry, 2008, vol. 34, no. 2; see also http://www.maik.ru.

  19. Type Ia Supernovae: Colors, Rates, and Progenitors

    CERN Document Server

    Heringer, Epson; Kezwer, Jason; Graham, Melissa L; Sand, David; Bildfell, Chris

    2016-01-01

    The rate of type Ia supernovae (SNe Ia) in a galaxy depends not only on stellar mass, but also on star formation history. Here we show that two simple observational quantities ($g-r$ or $u-r$ host galaxy color, and $r$-band luminosity), coupled with an assumed delay time distribution (the rate of SNe Ia as a function of time for an instantaneous burst of star formation), are sufficient to accurately determine a galaxy's SN Ia rate, with very little sensitivity to the precise details of the star formation history. Using this result, we compare observed and predicted color distributions of SN Ia hosts for the MENeaCS cluster supernova survey, and for the SDSS Stripe 82 supernova survey. The observations are consistent with a continuous delay time distribution (DTD), without any cutoff. For old progenitor systems the power-law slope for the DTD is found to be $-1.50 ^{+0.19} _{-0.15}$. This result favours the double degenerate scenario for SN Ia, though other interpretations are possible. We find that the late-t...

  20. Circulation of Tc Ia discrete type unit Trypanosoma cruzi in Yucatan Mexico.

    Science.gov (United States)

    Monteón, Victor; Triana-Chávez, Omar; Mejía-Jaramillo, Ana; Pennignton, Pamela; Ramos-Ligonio, Ángel; Acosta, Karla; Lopez, Ruth

    2016-06-01

    The etiologic agent Trypanosoma cruzi (Tc) has been grouped into six discrete type units (DTU I-VI); within DTU-I exists four subgroups defined Ia-Id. In Colombia, the genotype Ia is associated with human infection and domiciliated Rhodnius vector. In the Yucatan Peninsula of Mexico, the main vector involved in T. cruzi transmission is Triatoma dimidiata predominantly via sylvatic and peridomiciliated cycles. In this study, multiple sequence analysis of mini-exon intergenic regions of T. cruzi isolates obtained from T. dimidiata in the Yucatan Peninsula of Mexico revealed they belonged to Tc Ia DTU along with two additional Mexican strains located 1,570 km away from Yucatan. In conclusion Tc Ia circulates in the Yucatan peninsula in T. dimidiata vector and likewise in the northwest region of Mexico.

  1. Transition metal ferrocenyl dithiocarbamates functionalized dye-sensitized solar cells with hydroxy as an anchoring group

    Science.gov (United States)

    Yadav, Reena; Waghadkar, Yogesh; Kociok-Köhn, Gabriele; Kumar, Abhinav; Rane, Sunit B.; Chauhan, Ratna

    2016-12-01

    Three new transition-metal dithiocarbamates involving ferrocene (Fc), namely [Co(FcCH2EtOHdtc)3] (Co), [M(FcCH2EtOHdtc)2] M = Ni (Ni), Cu (Cu) (EtOHdtc = N-ethanol dithiocarbamate), have been synthesized and characterized by microanalyses, FTIR, 1H and 13C NMR spectroscopies and single crystal X-ray diffraction technique. The peak broadening in the 1H spectrum of the copper complex indicates the paramagnetic behavior of this compound. The observed single quasi-reversible cyclic voltammograms for the complexes indicate the stabilization of a metal center (except copper) other than Fe in their characteristic oxidation state. These complexes have been used as photo-sensitizer in dye-sensitized solar cells which indicates that Co displays the best photosensitization property with an overall conversion efficiency of 3.25 ± 0.04%. The low cell efficiency of Ni and Cu complexes may be due to slow regeneration of the dye by iodine/iodide redox couple followed by charge injection into TiO2.

  2. The Oldest Stars of the Extremely Metal-Poor Local Group Dwarf Irregular Galaxy Leo A

    Science.gov (United States)

    Schulte-Ladbeck, Regina E.; Hopp, Ulrich; Drozdovsky, Igor O.; Greggio, Laura; Crone, Mary M.

    2002-08-01

    We present deep Hubble Space Telescope (HST) single-star photometry of Leo A in B, V, and I. Our new field of view is offset from the centrally located field observed by Tolstoy et al. in order to expose the halo population of this galaxy. We report the detection of metal-poor red horizontal branch stars, which demonstrate that Leo A is not a young galaxy. In fact, Leo A is as least as old as metal-poor Galactic Globular Clusters that exhibit red horizontal branches and are considered to have a minimum age of about 9 Gyr. We discuss the distance to Leo A and perform an extensive comparison of the data with stellar isochrones. For a distance modulus of 24.5, the data are better than 50% complete down to absolute magnitudes of 2 or more. We can easily identify stars with metallicities between 0.0001 and 0.0004, and ages between about 5 and 10 Gyr, in their post-main-sequence phases, but we lack the detection of main-sequence turnoffs that would provide unambiguous proof of ancient (>10 Gyr) stellar generations. Blue horizontal branch stars are above the detection limits but difficult to distinguish from young stars with similar colors and magnitudes. Synthetic color-magnitude diagrams show it is possible to populate the blue horizontal branch in the halo of Leo A. The models also suggest ~50% of the total astrated mass in our pointing to be attributed to an ancient (>10 Gyr) stellar population. We conclude that Leo A started to form stars at least about 9 Gyr ago. Leo A exhibits an extremely low oxygen abundance, only 3% of solar, in its ionized interstellar medium. The existence of old stars in this very oxygen-deficient galaxy illustrates that a low oxygen abundance does not preclude a history of early star formation. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555.

  3. SN 2002cx The Most Peculiar Known Type Ia Supernova

    CERN Document Server

    Li, W; Chornock, R; Berger, E; Berlind, P; Calkins, M L; Challis, P M; Fassnacht, C D; Jha, S; Kirshner, R P; Matheson, T; Sargent, W L W; Simcoe, R A; Smith, G H; Squires, G; Li, Weidong; Filippenko, Alexei V.; Chornock, Ryan; Berger, Edo; Berlind, Perry; Calkins, Michael L.; Challis, Peter; Fassnacht, Chris; Jha, Saurabh; Kirshner, Robert P.; Matheson, Thomas; Sargent, Wallace L. W.; Simcoe, Robert A.; Smith, Graeme H.; Squires, Gordon

    2003-01-01

    We present photometric and spectroscopic observations of supernova (SN) 2002cx, which reveal it to be unique among all observed type Ia supernovae (SNe Ia). SN 2002cx exhibits a SN 1991T-like premaximum spectrum, a SN 1991bg-like luminosity, and expansion velocities roughly half those of normal SNe Ia. Photometrically, SN 2002cx has a broad peak in the $R$ band and a plateau phase in the $I$ band, and slow late-time decline. The $(B - V)$ color evolution is nearly normal, but the $(V - R)$ and $(V - I)$ colors are very red. Early-time spectra of SN 2002cx evolve very quickly and are dominated by lines from Fe-group elements; features from intermediate-mass elements (Ca, S, Si) are weak or absent. Mysterious emission lines are observed around 7000 \\AA\\ at about 3 weeks after maximum brightness. The nebular spectrum of SN 2002cx is also unique, consisting of narrow iron and cobalt lines. The observations of SN 2002cx are inconsistent with the observed spectral/photometric sequence, and provide a major challenge...

  4. SYNTHESES, CHARACTERIZATION AND ETHYLENE POLYMERIZATION OF HALF-SANDWICH GROUP IV METAL COMPLEXES WITH TRIDENTATE [O,N,S] LIGANDS

    Institute of Scientific and Technical Information of China (English)

    Ya-lin Qiao; Ping Hu; Guo-xin Jin

    2013-01-01

    A series of half-sandwich groupmetal complexes with tridentate monoanionic phenoxy-imine arylsulfide[O-NS] ligand [2-But4-Me-6-((2-(SC6H5)C6H4N =CHC6H2O)]-(La) and dianionic phenoxy-amine arylsulfide [O-N-S]ligand [2-Bu'4-Me-6-((2-(SC6H5)C6H4N-CH2C6H2O)]2-(Lb) have been synthesized and characterized.Lb was obtained easily in high yield by reduction of ligand La with excess LiAlH4 in cool diethyl ether.Half-sandwich Groupmetal complexes CpTi[O-NS]C12 (1a),CpZr[O-NS]C12 (1b),CpTi[O-N-S]C1 (2a),CpZr[O-N-S]C1 (2b) and Cp*Zr[O-N-S]Cl (2c)were synthesized by the reactions of La and Lb with CpTiCl3,CpZrCl3 and Cp*ZrCl3,and characterized by IR,1H-NMR,13C-NMR and elemental analysis.In addition,an X-ray structure analysis was performed on ligand Lb.The title Group Ⅳ half-sandwich bearing tridentate [O,N,S] ligands show good catalytic activities for ethylene polymerization in the presence of methylaluminoxane (MAO) as co-catalyst up to 1.58 × 107 g-PE·mol-Zr-1·h-1.The good catalytic activities can be maintained even at high temperatures such as 100 ℃ exhibiting the excellent thermal stability for these half-sandwich metal pre-catalysts.

  5. Selections from 2015: Two Kinds of Type Ia Supernovae

    Science.gov (United States)

    Kohler, Susanna

    2015-03-01

    Editors Note:In these last two weeks of 2015, well be looking at a few selections from among the most-downloaded paperspublished in AAS journals this year. The usual posting schedule will resume after the AAS winter meeting.The Changing Fractions of Type Ia Supernova NUVOptical Subclasses with RedshiftPublished April2015Main takeaway:A team of scientists led by Peter Milne (University of Arizona) used ultraviolet observations from the Swift spacecraft to determine that type Ia supernovae, stellar explosions previously thought to all belong in the same class, actually fall into two subgroups: those that are slightly redder in NUV wavelengths and those that are slightly bluer.Plot of the percentage of supernovae that are NUV-blue (rather than NUV-red), as a function of redshift. NUV-blue supernovae dominate at higher redshifts. [Milne et al. 2015]Why its interesting:It turns out that the fraction of supernovae in each of these two groups is redshift-dependent. At low redshifts (i.e., nearby), the population of type Ia supernovae is dominated by NUV-red supernovae. At high redshifts (i.e., far away), the population is dominated by NUV-blue supernovae. Since cosmological distances are measured using Type Ia supernovae as standard candles, the fact that weve been modeling these supernovae all the same way (rather than treating them as two separate subclasses) means we may have been systematically misinterpreting distances.What this means for the universes expansion:This seemingly simple discovery carries hefty repercussions in fact, our estimates of the expansion rate of the universe may be incorrect! The authors believe that if we correct for this error, well find that the universe is not expanding as quickly as we thought.CitationPeter A. Milne et al 2015 ApJ 803 20. doi:10.1088/0004-637X/803/1/20

  6. A Robust Metal-Organic Framework Combining Open Metal Sites and Polar Groups for Methane Purification and CO2 /Fluorocarbon Capture.

    Science.gov (United States)

    Chen, Cheng-Xia; Zheng, Shao-Ping; Wei, Zhang-Wen; Cao, Chen-Chen; Wang, Hai-Ping; Wang, Dawei; Jiang, Ji-Jun; Fenske, Dieter; Su, Cheng-Yong

    2017-03-23

    A 3D porous perchlorinated metal-organic framework (MOF), LIFM-26, featuring dual functionality, that is, functional polar groups and open metal sites, has been synthesized using perchlorinated linear dicarboxylate to link trigonal prismatic Fe3 (μ3 -O) units. LIFM-26 exhibits good thermal and chemical stability, and possesses high porosity with a BET surface area of 1513 m(2)  g(-1) , compared with isoreticular MOF-235 and Fe3 O(F4 BDC)3 (H2 O)3 (F4 BDC=2,3,5,6-tetrafluorobenzene-1,4-dicarboxylate). Most strikingly, LIFM-26 features good gas sorption/separation performance at 298 K and 1 atm with IAST selectivity values reaching up to 36, 93, 23, 11, 46, and 202 for CO2 /CH4 , CO2 /N2 , C2 H4 /CH4 , C2 H6 /CH4 , C3 H8 /CH4 , and R22/N2 (R22=CHClF2 ), respectively, showing potential for use in biogas/natural gas purification and CO2 /R22 capture. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. IUPAC-NIST Solubility Data Series. 85. Transition and 12-14 Main Group Metals, Lanthanide, Actinide, and Ammonium Halates

    Science.gov (United States)

    Miyamoto, Hiroshi

    2008-06-01

    This paper is the fourth and final volume in the halate solubility series. The solubility data for halates of transition metals, lanthanides, actinides, ammonium, and metallic elements of the main groups 12-14 are reviewed. Where appropriate, binary, ternary, and multicomponent systems are critically evaluated. Most of the solubility results were obtained in water or aqueous solutions of electrolytes. The solubility in organic solvents and aqueous-organic solvent mixtures is also collected in this volume. All these data were critically examined for their reliability. The best values were selected on the basis of critical evaluations and presented in tabular form. Fitting equations and graphical plots are also provided. When numerical data were not reported in an original publication, they were read out from figures and digitized by the compilers. The quantities, units, and symbols used in this volume are in accord with IUPAC recommendations. We always reported the original data and, if necessary, transferred them into the IUPAC recommended units and symbols. The literature on the solubility data was researched through 2002. The halates of these metals play a role in industrial processes. For example, some halates are essential as catalysts, heat stabilizers, and blanching reagents for manufacturing polymer products such as textiles and resins. Some iodates are used in pyrotechnic compounds for weather modification and colored smoke generation. The nonlinear halate crystals are important in construction of optical devices.

  8. Verifying the Cosmological Utility of Type Ia Supernovae: Implications of a Dispersion in the Ultraviolet Spectra

    Energy Technology Data Exchange (ETDEWEB)

    Nugent, Peter E; Ellis, R.S.; Sullivan, M.; Nugent, P.E.; Howell, D.A.; Gal-Yam, A.; Astier, P.; Balam, D.; Balland, C.; Basa, S.; Carlberg, R.; Conley, A.; Fouchez, D.; Guy, J.; Hardin, D.; Hook, I.; Pain, R.; Perrett, K.; Pritchet, C.J.; Regnault, N.

    2008-02-28

    We analyze the mean rest-frame ultraviolet (UV) spectrum of Type Ia Supernovae (SNe) and its dispersion using high signal-to-noise ratio Keck-I/LRIS-B spectroscopy for a sample of 36 events at intermediate redshift (z=0.5) discovered by the Canada-France-Hawaii Telescope Supernova Legacy Survey (SNLS). We introduce a new method for removing host galaxy contamination in our spectra, exploiting the comprehensive photometric coverage of the SNLS SNe and their host galaxies, thereby providing the first quantitative view of the UV spectral properties of a large sample of distant SNe Ia. Although the mean SN Ia spectrum has not evolved significantly over the past 40percent of cosmic history, precise evolutionary constraints are limited by the absence of a comparable sample of high-quality local spectra. The mean UV spectrum of our z~;;=0.5 SNe Ia and its dispersion is tabulated for use in future applications. Within the high-redshift sample, we discover significant UV spectral variations and exclude dust extinction as the primary cause by examining trends with the optical SN color. Although progenitor metallicity may drive some of these trends, the variations we see are much larger than predicted in recent models and do not follow expected patterns. An interesting new result is a variation seen in the wavelength of selected UV features with phase. We also demonstrate systematic differences in the SN Ia spectral features with SN light curve width in both the UV and the optical. We show that these intrinsic variations could represent a statistical limitation in the future use of high-redshift SNe Ia for precision cosmology. We conclude that further detailed studies are needed, both locally and at moderate redshift where the rest-frame UV can be studied precisely, in order that future missions can confidently be planned to fully exploit SNe Ia as cosmological probes.

  9. Catalysis by alkali and alkaline-earth metal ions in nucleophilic attack of methoxide ion on crown ethers bearing an intra-annular acetoxy group

    NARCIS (Netherlands)

    Cacciapaglia, Roberta; Lucente, Silvia; Mandolini, Luigi; Doorn, van Arie R.; Reinhoudt, David N.; Verboom, Willem

    1989-01-01

    Rates of reaction of methoxide ion with crown ethers bearing an intra-annular acetoxy group are markedly enhanced by alkali and alkaline-earth metal bromides as a result of much stronger interactions of the metal ions with transition states than with reactants. Rates of reactions of methoxide ion w

  10. Complexes of bis(cyclopentadienyl)hydridorhenium with group-II metal halides

    Energy Technology Data Exchange (ETDEWEB)

    Ishchenko, V.M.; Arkhireeva, T.M.; Bulychev, B.M.; Soloveichik, G.L.; Nikolaeva, S.N.

    1986-11-01

    It has been shown that the interaction of bis(cyclopentadienyl)hydridorhenium (Cp/sub 2/ReH, where Cp = eta/sup 5 -/C/sub 5/H/sub 5/) with the halides of zinc, cadmium, beryllium, and magnesium in diethyl ether results in the formation of complex compounds with the general formula Cp/sub 2/ReH MHal/sub 2/. The replacement of ether by tetrahydrofuran in the case of zinc derivatives gives monosolvates with the formula Cp/sub 2/ReH x ZnHal/sub 2/ x THF (Hal = Br, I). On the basis of data from IR and PMR spectroscopy it has been concluded that the bonding of the metal-containing fragments in these complexes is realized either as a result of an Re :..-->.. M donor-acceptor interaction (the complexes with ZnHal/sub 2/ and CdI/sub 2/) or as a result of the formation of a mixed bond (the complexes with BeCl/sub 2/ and MgHal/sub 2/).

  11. OB stars at the lowest Local Group metallicity: GTC-OSIRIS observations of Sextans A

    CERN Document Server

    Camacho, I; Herrero, A; Simón-Díaz, S

    2016-01-01

    Our aim is to find and classify OB stars in Sextans A, to later determine accurate stellar parameters of these blue massive stars in this low metallicity region $(Z \\sim 0.1 \\rm Z_{\\odot})$. Using UBV photometry, the reddening-free index Q and GALEX imaging, we built a list of blue massive star candidates in Sextans A. We obtained low resolution (R $\\sim$ 1000) GTC-OSIRIS spectra for a fraction of them and carried out spectral classification. For the confirmed O-stars we derive preliminary stellar parameters. The target selection criteria and observations were successful and have produced the first spectroscopic atlas of OB-type stars in Sextans A. From the whole sample of 18 observed stars, 12 were classified as early OB-types, including 5 O-stars. The radial velocities of all target stars are in agreement with their Sextans A membership, although three of them show significant deviations. We determined the stellar parameters of the O-type stars using the stellar atmosphere code FASTWIND, and revisited the s...

  12. Structure and Function of APH(4)-Ia, a Hygromycin B Resistance Enzyme

    Energy Technology Data Exchange (ETDEWEB)

    Stogios, Peter J.; Shakya, Tushar; Evdokimova, Elena; Savchenko, Alexei; Wright, Gerard D. (Toronto); (McMaster U.)

    2011-11-18

    The aminoglycoside phosphotransferase (APH) APH(4)-Ia is one of two enzymes responsible for bacterial resistance to the atypical aminoglycoside antibiotic hygromycin B (hygB). The crystal structure of APH(4)-Ia enzyme was solved in complex with hygB at 1.95 {angstrom} resolution. The APH(4)-Ia structure adapts a general two-lobe architecture shared by other APH enzymes and eukaryotic kinases, with the active site located at the interdomain cavity. The enzyme forms an extended hydrogen bond network with hygB primarily through polar and acidic side chain groups. Individual alanine substitutions of seven residues involved in hygB binding did not have significant effect on APH(4)-Ia enzymatic activity, indicating that the binding affinity is spread across a distributed network. hygB appeared as the only substrate recognized by APH(4)-Ia among the panel of 14 aminoglycoside compounds. Analysis of the active site architecture and the interaction with the hygB molecule demonstrated several unique features supporting such restricted substrate specificity. Primarily the APH(4)-Ia substrate-binding site contains a cluster of hydrophobic residues that provides a complementary surface to the twisted structure of the substrate. Similar to APH(2{double_prime}) enzymes, the APH(4)-Ia is able to utilize either ATP or GTP for phosphoryl transfer. The defined structural features of APH(4)-Ia interactions with hygB and the promiscuity in regard to ATP or GTP binding could be exploited for the design of novel aminoglycoside antibiotics or inhibitors of this enzyme.

  13. Type Ia Supernovae and the Hubble Constant

    CERN Document Server

    Branch, D

    1998-01-01

    The focus of this review is the work that has been done during the 1990s on using Type Ia supernovae (SNe Ia) to measure the Hubble constant ($H_0$). SNe Ia are well suited for measuring $H_0$. A straightforward maximum-light color criterion can weed out the minority of observed events that are either intrinsically subluminous or substantially extinguished by dust, leaving a majority subsample that has observational absolute-magnitude dispersions of less than $\\sigma_{obs}(M_B) \\simeq \\sigma_{obs}(M_V) \\simeq 0.3$ mag. Correlations between absolute magnitude and one or more distance-independent SN Ia or parent-galaxy observables can be used to further standardize the absolute magnitudes to better than 0.2 mag. The absolute magnitudes can be calibrated in two independent ways --- empirically, using Cepheid-based distances to parent galaxies of SNe Ia, and physically, by light curve and spectrum fitting. At present the empirical and physical calibrations are in agreement at $M_B \\simeq M_V \\simeq -19.4$ or -19....

  14. The Spectroscopic Diversity of Type Ia Supernovae

    CERN Document Server

    Blondin, S; Kirshner, R P; Mandel, K S; Berlind, P; Calkins, M; Challis, P; Garnavich, P M; Jha, S W; Modjaz, M; Riess, A G; Schmidt, B P

    2012-01-01

    We present 2603 spectra of 462 nearby Type Ia supernovae (SN Ia) obtained during 1993-2008 through the Center for Astrophysics Supernova Program. Most of the spectra were obtained with the FAST spectrograph at the FLWO 1.5m telescope and reduced in a consistent manner, making data set well suited for studies of SN Ia spectroscopic diversity. We study the spectroscopic and photometric properties of SN Ia as a function of spectroscopic class using the classification schemes of Branch et al. and Wang et al. The width-luminosity relation appears to be steeper for SN Ia with broader lines. Based on the evolution of the characteristic Si II 6355 line, we propose improved methods for measuring velocity gradients, revealing a larger range than previously suspected, from ~0 to ~400 km/s/day considering the instantaneous velocity decline rate at maximum light. We find a weaker and less significant correlation between Si II velocity and intrinsic B-V color at maximum light than reported by Foley et al., owing to a more ...

  15. The Peak Luminosity of Type Ia Supernovae and its Implications for the Cosmic Expansion Rate

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Supernovae of type Ia (SNe Ia) are confirmed to be the best distance indicators to derive the cosmic expansion rate. The dispersion of their peak lumi nosity at optical bands (BVI) is approximate to 0.13 mag, after taking into account the effects of the second parameters (i,e., the initial decline rate △m15(B) and (B - V) color at maximum light). The local calibrations from HST indicate an absolute magnitude of 19.48 ± 0.08 mag (in V band) for SNe Ia in spiral galaxies. The current expansion rate, H0, is found to be 63.6 ± 1.8 (random) ±5.7 (system-atic) kms-1 Mpc-1. This value will decrease by 3% when the metallicity effect on the cepheid distances is considered. In addition, a marginal local outward flow of 4.0 ± 4.5% within the velocity-distance of 7 000 km s-1 can be inferred from SNe Ia for the Einstein-de Sitter universe; however, this outward flow is only 2.2 ± 4.4% for an accelerating expansion universe (which is supported by high-z SNe Ia).

  16. Early-type Host Galaxies of Type Ia Supernovae. I. Evidence for Downsizing

    CERN Document Server

    Kang, Yijung; Lim, Dongwook; Chung, Chul; Lee, Young-Wook

    2016-01-01

    Type Ia supernova (SN Ia) cosmology provides the most direct evidence for the presence of dark energy. This result is based on the assumption that the look-back time evolution of SN Ia luminosity, after light-curve corrections, would be negligible. Recent studies show, however, that the Hubble residual (HR) of SN Ia is correlated with the mass and morphology of host galaxies, implying the possible dependence of SN Ia luminosity on host galaxy properties. In order to investigate this more directly, we have initiated spectroscopic survey for the early-type host galaxies, for which population age and metallicity can be more reliably determined from the absorption lines. As the first paper of the series, here we present the results from high signal-to-noise ratio (>100 per pixel) spectra for 27 nearby host galaxies in the southern hemisphere. For the first time in host galaxy studies, we find a significant (~3.9sigma) correlation between host galaxy mass (velocity dispersion) and population age, which is consiste...

  17. Control by Preynaptic Correlation: a mechanism affecting information transmission from Ia fibers to motoneurons.

    Science.gov (United States)

    Rudomin, P; Burke, R E; Núñez, R; Madrid, J; Dutton, H

    1975-03-01

    1. In the unanesthetized spinal cord of the cat, simultaneous intracellular recordings were made from two motoneurons belonging to the gastronemius motor nucleus. 2. Supramaximal iterative stimulation of small branches of the gastrocnemius nerve produced monosynaptic EPSPs (Ia EPSPs) of varying amplitude superimposed on a fluctuating base line. 3. In most cases the variance of the motoneuron membrane potential was increased above base-line levels with a time course approximately matching the Ia EPSP. This suggests that Ia EPSP fluctuations are greater than can be accounted for by the base-line fluctuations alone. 4. For a given series of Ia EPSPs, the smaller responses in the series had about the same decay phase as the larger EPSPs, suggesting that most of the Ia EPSP fluctuations were not due to systematic changes in postsynaptic conductances produced by ongoing activity, but rather to a presynaptic mechanism. 5. Simultaneous recording from two motoneurons showed that base-line fluctuations were positively correlated. In most cases, however, there was an additional increased correlation above base-line levels resembling the time course of the Ia EPSPs, indicating positive correlation between EPSP fluctuations which is attributed to a presynaptic mechanism. 6. Conditioning volleys to group I muscle afferents or to low-threshold cutaneous afferents reduced the variance of the Ia EPSPs and also their correlation in motoneuron pairs, often without changing the mean Ia EPSPs. 7. It is concluded that, in the unanesthetized spinal cord, in addition to the random process which governs transmitter release intrinsic to a given synaptic terminal, there is another stochastic process affecting, in a correlated manner, transmitter release in large sets of Ia synaptic terminals. Most likely, the correlation in transmitter release is achieved by membrane potential fluctuations imposed on the Ia terminal arborizations by ongoing activity of the segmental mechanism mediating

  18. First determination of the levels of platinum group metals in Manta birostris (manta ray) caught along the Ghanaian coastline.

    Science.gov (United States)

    Essumang, D K

    2010-06-01

    Tissues from Manta birostris caught by fishermen from Dixcove in the western part of Ghana were analyzed for their Platinum, palladium and rhodium concentrations (PGM). The use of chondrichthyan fish has permitted the study of trace levels of Platinum group metals (PGMs) which have travelled very far into the sea. The analysis showed that Ghana's coastline is fairly polluted with these platinum group metals (PGMs). PGM concentration in manta ray recorded a range of (0.15-0.85) microg/g for Pt, (0.033-0.67) microg/g for Pd and (0.007-0.145) microg/g for Rh. Comparing these values to the UK dietary intake of 0.2 microg/day for Pt and Rh and 1.0 microg/day for Pd, its indicates that the values obtained from the analysis for Pt was above the required level. This is the first study to show the accumulation of PGM in chondrichthyan fish, although the sources of this pollution are not clear as manta birostris is migratory and therefore need to be investigated further. The presence of the PGM is very significant, since manta ray meat is consumed in Ghana. This may presents a health risk, due to a possible accumulation of PGMs in humans.

  19. Catalytic co-pyrolysis of peat and polymeric wastes in the presence of iron sub-group metal chlorides

    Energy Technology Data Exchange (ETDEWEB)

    Sulman, E.M.; Kosivtsov, Y.Y.; Lugovoy, Y.V. [Tver Technical University, Tver (Russian Federation)

    2008-07-01

    The purpose of this investigation is the study of activity of iron sub-group metal chlorides in co-processing of peat and polymeric wastes by low-temperature catalytic pyrolysis method. Iron sub-group metal chlorides in concentration varied from 1 to 10% (wt) were used as the catalysts of pyrolysis. The process was conducted in fixed bed reactor in inert gaseous atmosphere at the temperature interval of 350-550{sup o}C. All the investigated catalysts were found to promote the increase of liquid fraction mass and the decrease of solid carbon-containing residue mass up to 10-30%. Cobalt catalyst revealed the highest selectivity with respect to liquid products formation. The use of the catalysts in low-temperature peat and polymeric wastes pyrolysis process was found to favour the increase gaseous products volume up to 20-50% as well as unsaturated hydrocarbons volume in 1.2 folds in comparison to uncatalysed process. 9 refs., 3 figs., 2 tabs.

  20. Strategic and tactical determinants for South African platinum-group-metals supply

    CSIR Research Space (South Africa)

    McGill, JE

    2011-11-01

    Full Text Available for competitive future supply being derived from the eastern limb. 1 Introduction The mineral resources sector displays a careful balancing act between operation specific tactics designed to maximize shareholder returns; and overarching industry...-related strategies employed by various entities including country governments, global interest groups, and multi-national head offices. This balancing act of short-term business tactics juxtaposed along-side long-run strategic intent of the extraction sector...

  1. Removal of transition metals from dilute aqueous solution by carboxylic acid group containing absorbent polymers

    Science.gov (United States)

    A new carboxylic acid group containing resin with cation exchange capacity, 12.67 meq/g has been used to remove Cu2+, Co2+ and Ni2+ ions from dilute aqueous solution. The resin has Cu2+, Co2+ and Ni2+ removal capacity, 216 mg/g, 154 mg/g and 180 mg/g, respectively. The selectivity of the resin to ...

  2. Structure and property of metal melt Ⅱ—Evolution of atomic clusters in the not high temperature range above liquidus

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Based on the theory of micro-inhomogeneity of liquid metal,a calculation model is established for the quantitative description of the structural information of metal melts.Only by thermophysical property parameters and basic structural parameters of solid metal,can this model produce the main information of melt structure,including the relative concentration of active atoms,size of atomic clusters and number of short-range order atoms.Based on this model,the main structural information of Al and Ni melts in the not high range above the liquidus is calculated,with results in good agreement with experimental values.Besides,analyzed is the influence of superheating temperature and atomic number on the melt structural information of the first (IA) and second main group (IIA) elements.With temperature increasing,melt structural information regularly changes for both IA and IIA elements.With the atomic number increasing,melt structural information of IA elements changes regularly,for the crystal structures of the IA elements are all of bcc lattice type.However,no notable regular change of melt structural information for IIA elements has been found,mainly because the lattice type of IIA elements is of hcp-fcc-bcc transition.The present work presents an effective way for better understanding metal melt structure and for forecasting the change of the physical property of metal melts.

  3. IAS 41 Agriculture: Fair Value Accounting

    Directory of Open Access Journals (Sweden)

    Viorel Lefter

    2007-05-01

    Full Text Available Issuing this standard that had to be applied for the first time for the financial statements started after 1.01.2003 meant a change of direction from two points of view: on one hand, through IAS 41 was issued for the first time an extensive standard typical for this sector and, on the other hand, for the first time were included in the income statement, independently from the sales transactions, incomes from variations of the fair value of an asset. Because of this last aspect, IAS 41 can be considered an important standard, because it represents the starting point of a consistent transition from the purchase cost principle towards a fair value accounting. IASC has dedicated to the thematic field of agriculture a specific standard, because this economic branch has a great importance for the developing countries. On the other hand, IAS 41 is also applied for the agricultural activities of the enterprises from other sectors.

  4. New approaches to SNe Ia progenitors

    CERN Document Server

    Ruiz-Lapuente, Pilar

    2014-01-01

    Although Type Ia supernovae (SNe Ia) are a major tool in cosmology and play a key role in the chemical evolution of galaxies, the nature of their progenitor systems (apart from the fact that they must be close binaries containing at least one white dwarf) remains largely unknown. In the last decade, considerable efforts have been made, both observationally and theoretically, to solve this problem. Observations have, however, revealed a previously unsuspected variety of events, ranging from very underluminous outbursts to clearly overluminous ones, and spanning a range well outside the peak luminosity--decline rate of the light curve relationship, used to make calibrated candles of the SNe Ia. On the theoretical side, new explosion scenarios, such as violent mergings of pairs of white dwarfs, have been explored. We review those recent developments, emphasizing the new observational findings, but also trying to tie them to the different scenarios and explosion mechanisms proposed thus far.

  5. Tratamento das cefaléias Treatment of headaches

    Directory of Open Access Journals (Sweden)

    José Luiz Dias Gherpelli

    2002-08-01

    Full Text Available Objetivo: realizar revisão bibliográfica sobre o tema tratamento da cefaléia na infância e adolescência. Fontes dos dados: revisão bibliográfica através do banco de dados Medline, utilizando os termos: cefaléia, enxaqueca ou migrânea, infância ou adolescência e tratamento, no período de 1966 a 2001, excluindo artigos de revisão e registros de casos. Foram selecionados artigos científicos que relataram estudos sobre a eficácia da terapêutica farmacológica e não farmacológica no tratamento das cefaléias primárias. Síntese dos dados: foram encontrados 104 artigos científicos, sendo selecionados aqueles que relataram estudos do tipo caso-controle, ou droga versus placebo, cegos ou abertos, e que estudassem crianças ou adolescentes. Conclusões: é digna de nota a pobreza de estudos controlados sobre o tema na faixa etária pediátrica, apesar da importância que as cefaléias primárias apresentam na prática clínica. Apenas algumas drogas foram estudadas de forma cientificamente adequada e, mesmo assim, o número de estudos é pequeno. Tanto o tratamento da crise álgica aguda quanto a profilaxia da cefaléia foram abordados.Objective: to perform a bibliographic review about headache treatment in childhood and adolescence. Sources: articles were searched through Medline database using the terms: migraine, or headache, childhood, or adolescence, and treatment, during the period between 1966 and 2001. Review articles and case reports were excluded. Only articles dealing with pharmacological, and non-pharmacological treatment of primary headaches were selected. Summary of the findings: a total of 104 articles were found; only those reporting results of the case-control studies, or drug vs. placebo, either blind, or open, and that included children, or adolescents were selected. Conclusions: only a few controlled studies about the headache treatment were found in the pediatric age group, although primary headaches are

  6. Bioengineered human IAS reconstructs with functional and molecular properties similar to intact IAS.

    Science.gov (United States)

    Singh, Jagmohan; Rattan, Satish

    2012-09-15

    Because of its critical importance in rectoanal incontinence, we determined the feasibility to reconstruct internal anal sphincter (IAS) from human IAS smooth muscle cells (SMCs) with functional and molecular attributes similar to the intact sphincter. The reconstructs were developed using SMCs from the circular smooth muscle layer of the human IAS, grown in smooth muscle differentiation media under sterile conditions in Sylgard-coated tissue culture plates with central Sylgard posts. The basal tone in the reconstructs and its changes were recorded following 0 Ca(2+), KCl, bethanechol, isoproterenol, protein kinase C (PKC) activator phorbol 12,13-dibutyrate, and Rho kinase (ROCK) and PKC inhibitors Y-27632 and Gö-6850, respectively. Western blot (WB), immunofluorescence (IF), and immunocytochemical (IC) analyses were also performed. The reconstructs developed spontaneous tone (0.68 ± 0.26 mN). Bethanechol (a muscarinic agonist) and K(+) depolarization produced contraction, whereas isoproterenol (β-adrenoceptor agonist) and Y-27632 produced a concentration-dependent decrease in the tone. Maximal decrease in basal tone with Y-27632 and Gö-6850 (each 10(-5) M) was 80.45 ± 3.29 and 17.76 ± 3.50%, respectively. WB data with the IAS constructs' SMCs revealed higher levels of RhoA/ROCK, protein kinase C-potentiated inhibitor or inhibitory phosphoprotein for myosin phosphatase (CPI-17), phospho-CPI-17, MYPT1, and 20-kDa myosin light chain vs. rectal smooth muscle. WB, IF, and IC studies of original SMCs and redispersed from the reconstructs for the relative distribution of different signal transduction proteins confirmed the feasibility of reconstruction of IAS with functional properties similar to intact IAS and demonstrated the development of myogenic tone with critical dependence on RhoA/ROCK. We conclude that it is feasible to bioengineer IAS constructs using human IAS SMCs that behave like intact IAS.

  7. Lead-chromium carbonyl complexes incorporated with group 8 metals: synthesis, reactivity, and theoretical calculations.

    Science.gov (United States)

    Shieh, Minghuey; Chu, Yen-Yi; Hsu, Miao-Hsing; Ke, Wei-Ming; Lin, Chien-Nan

    2011-01-17

    The trichromium-lead complex [Pb{Cr(CO)5}3](2-) (1) was isolated from the reaction of PbCl2 and Cr(CO)6 in a KOH/MeOH solution, and the new mixed chromium-iron-lead complex [Pb{Cr(CO)5}{Fe(CO)4}2](2-) (3) was synthesized from the reaction of PbCl2 and Cr(CO)6 in a KOH/MeOH solution followed by the addition of Fe(CO)5. X-ray crystallography showed that 3 consisted of a central Pb atom bound in a trigonal-planar environment to two Fe(CO)4 and one Cr(CO)5 fragments. When complex 1 reacted with 1.5 equiv of Mn(CO)5Br, the Cr(CO)4-bridged dimeric lead-chromium carbonyl complex [Pb2Br2Cr4(CO)18](2-) (4) was produced. However, a similar reaction of 3 or the isostructural triiron-lead complex [Pb{Fe(CO)4}3](2-) (2) with Mn(CO)5Br in MeCN led to the formation of the Fe3Pb2-based trigonal-bipyramidal complexes [Fe3(CO)9{PbCr(CO)5}2](2-) (6) and [Fe3(CO)9{PbFe(CO)4}2](2-) (5), respectively. On the other hand, the Ru3Pb2-based trigonal-bipyramidal complex [Ru3(CO)9{PbCr(CO)5}2](2-) (7) was obtained directly from the reaction of PbCl2, Cr(CO)6, and Ru3(CO)12 in a KOH/MeOH solution. X-ray crystallography showed that 5 and 6 each had an Fe3Pb2 trigonal-bipyramidal core geometry, with three Fe(CO)3 groups occupying the equatorial positions and two PbFe(CO)4 or PbCr(CO)5 units in the axial positions, while 7 displayed a Ru3Pb2 trigonal-bipyramidal geometry with three equatorial Ru(CO)3 groups and two axial PbCr(CO)5 units. The complexes 3-7 were characterized spectroscopically, and their nature, formation, and electrochemistry were further examined by molecular orbital calculations at the B3LYP level of density functional theory.

  8. Testing the Standardizability of Type Ia Supernovae with the Cepheid Distance of a Twin Supernova

    Science.gov (United States)

    Foley, Ryan

    2014-10-01

    Having nearly identical optical light-curve shapes, colors, and spectra, SN 2011by and 2011fe are "twin" Type Ia supernovae (SN Ia). As such, these "standardizable candles" should have identical luminosities. But using independent distance measurements to these SN, their peak luminosity differs by 0.6 mag --- significantly larger than the typical scatter amongst all SN Ia. Differences in their UV spectra indicate that the SN have different metallicities, which could account for the luminosity difference. On the other hand, the distance to SN 2011by, from a Tully-Fisher measurement, may be wrong. We propose to measure a Cepheid distance to SN 2011by to determine if metallicity or an imprecise measurement is causing this large difference.The implications are far reaching for SN cosmology. If the current distance is correct, changing progenitor metallicity could cause large distance biases with redshift. If the distance is revised to bring SN 2011by in line with SN 2011fe, we will infer that metallicity differences are not a large bias for SN cosmology.In the latter case, these data will also provide an additional SN with which we can measure the Hubble constant. Since the number of SN calibrators (only 8 published) limits the precision of our measurement of the Hubble constant, these observations can have a large impact on this measurement.

  9. EnviroAtlas - Woodbine, IA - Near Road Block Group Summary

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset addresses the tree buffer along heavily traveled roads. The roads are interstates, arterials, and collectors within the EnviroAtlas...

  10. Planetary nebulae: the universal mass-metallicity relation for Local Group dwarf galaxies and the chemistry of NGC 205

    CERN Document Server

    Gonçalves, D R; Teodorescu, Ana M; Carneiro, Carolina M

    2014-01-01

    Here we study 16 planetary nebulae (PNe) in the dwarf irregular galaxy NGC 205 by using GMOS@Gemini spectra to derive their physical and chemical parameters. The chemical patterns and evolutionary tracks for 14 of our PNe suggest that there are no type I PNe among them. These PNe have an average oxygen abundance of 12+log(O/H)=8.08$\\pm$0.28, progenitor masses of 2-2.5M$_{\\odot}$ and thus were born ~1.0-1.7Gyr ago. Our results are in good agreement with previous PN studies in NGC 205. The present 12+log(O/H) is combined with our previous works and with the literature to study the PN metallicity trends of the Local Group (LG) dwarf galaxies, in an effort to establish the PN luminosity- and mass-metallicity relations (LZR and MZR) for the LG dwarf irregulars (dIrrs) and dwarf spheroidals (dSphs). Previous attempts to obtain such relations failed to provide correct conclusions because were based on limited samples (Richer & McCall 1995; Gon\\c{c}calves et al. 2007). As far as we are able to compare stellar wit...

  11. Assessing Economic Modulation of Future Critical Materials Use: The Case of Automotive-Related Platinum Group Metals.

    Science.gov (United States)

    Zhang, Jingshu; Everson, Mark P; Wallington, Timothy J; Field, Frank R; Roth, Richard; Kirchain, Randolph E

    2016-07-19

    Platinum-group metals (PGMs) are technological and economic enablers of many industrial processes. This important role, coupled with their limited geographic availability, has led to PGMs being labeled as "critical materials". Studies of future PGM flows have focused on trends within material flows or macroeconomic indicators. We complement the previous work by introducing a novel technoeconomic model of substitution among PGMs within the automotive sector (the largest user of PGMs) reflecting the rational response of firms to changing prices. The results from the model support previous conclusions that PGM use is likely to grow, in some cases strongly, by 2030 (approximately 45% for Pd and 5% for Pt), driven by the increasing sales of automobiles. The model also indicates that PGM-demand growth will be significantly influenced by the future Pt-to-Pd price ratio, with swings of Pt and Pd demand of as much as 25% if the future price ratio shifts higher or lower even if it stays within the historic range. Fortunately, automotive catalysts are one of the more effectively recycled metals. As such, with proper policy support, recycling can serve to meet some of this growing demand.

  12. Buried Volume Analysis for Propene Polymerization Catalysis Promoted by Group 4 Metals: a Tool for Molecular Mass Prediction

    KAUST Repository

    Falivene, Laura

    2015-10-02

    A comparison of the steric properties of homogeneous single site catalysts for propene polymerization using the percentage of buried volume (%VBur) as molecular descriptor is reported. The %VBur calculated on the neutral precursors of the active species seems to be a reliable tool to explain several experimental data related to the propene insertion and to the monomer chain transfer. Interestingly, a linear correlation between the buried volume calculated for a large set of neutral precursors and the energetic difference between propagation and termination steps calculated by DFT methods is found for Group 4 metal catalysts. The “master curves” derived for Ti, Zr and Hf confirm not only that the %VBur is an appropriate molecular descriptor for the systems considered but also that it could be used as tool for a large computational screening of new ligands.

  13. Electrochemically Smart Bimetallic Materials Featuring Group 11 Metals: In-situ Conductive Network Generation and Its Impact on Cell Capacity

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, Esther [Stony Brook Univ., NY (United States)

    2016-11-30

    Our results for this program “Electrochemically smart bimetallic materials featuring Group 11 metals: in-situ conductive matrix generation and its impact on battery capacity, power and reversibility” have been highly successful: 1) we demonstrated material structures which generated in-situ conductive networks through electrochemical activation with increases in conductivity up to 10,000 fold, 2) we pioneered in situ analytical methodology to map the cathodes at several stages of discharge through the use of Energy Dispersive X-ray Diffraction (EDXRD) to elucidate the kinetic dependence of the conductive network formation, and 3) we successfully designed synthetic methodology for direct control of material properties including crystallite size and surface area which showed significant impact on electrochemical behavior.

  14. Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal-Organic Framework with Functional Groups.

    Science.gov (United States)

    Park, Jihye; Feng, Dawei; Zhou, Hong-Cai

    2015-09-16

    A facile preparation of a mesoporous Cr-MOF, PCN-333(Cr) with functional group, has been demonstrated through a dual exchange strategy, involving a sequential ligand exchange and metal metathesis process. After optimization of the exchange system, the functionalized PCN-333(Cr), N3-PCN-333(Cr) shows well maintained crystallinity, porosity, as well as much improved chemical stability. Because of the exceptionally large pores (∼5.5 nm) in PCN-333(Cr), a secondary functional moiety, Zn-TEPP with a size of 18 Å × 18 Å, has been successfully clicked into the framework. In this article, we have also analyzed kinetics and thermodynamics during dual exchange process, showing our attempts to interpret the exchange event in the PCN-333. Our findings not only provide a highly stable mesoporous Cr-MOF platform for expanding MOF-based applications, but also suggest a route to functionalized Cr-MOF which may have not been achievable through conventional approaches.

  15. Penerapan PSAK Adopsi IAS 41 Agriculture

    Directory of Open Access Journals (Sweden)

    Stefanus Ariyanto

    2014-05-01

    Full Text Available This study aims to determine whether the application of PSAK adopted from IAS 41: Agriculture should be applied to State-Owned Enterprises, especially the plantation SOE. So that the SOE financial information produced becomes more useful for decision-making. Furthermore, this study wants to answer what benefits can be obtained from the implementation of this standard on the plantation-based SOE. The main characteristic of IAS is the use of fair value model for biological assets owned by the agriculture-based entity. The use of this model raises a lot of controversy, primarily, associated with relevant quality and reliability of the information it produces. Research used qualitative method with data collection through literature study, survey, interview, and observation. Survey and interview were divided into two major parts, which were: on the compilers of financial statements and the stakeholders. From this study it can be concluded that the PSAK based on IAS 41 have not to be implemented yet in the near future due to IAS 41 will undergo quite significant revision. Currently, the State-Owned Enterprises could use the PSAK plantation SOE that has been issued.

  16. 75 FR 11582 - IOWA Disaster # IA-00023

    Science.gov (United States)

    2010-03-11

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION IOWA Disaster IA-00023 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  17. 78 FR 28939 - Iowa Disaster #IA-00050

    Science.gov (United States)

    2013-05-16

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00050 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  18. 78 FR 36010 - Iowa Disaster #IA-00052

    Science.gov (United States)

    2013-06-14

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00052 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  19. 76 FR 66768 - Iowa Disaster #IA-00033

    Science.gov (United States)

    2011-10-27

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00033 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for the State of Iowa...

  20. 75 FR 51507 - Iowa Disaster #IA-00024

    Science.gov (United States)

    2010-08-20

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00024 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for the State of Iowa...

  1. 75 FR 53006 - Iowa Disaster #IA-00026

    Science.gov (United States)

    2010-08-30

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00026 AGENCY: U.S. Small Business Administration. ACTION: Amendment 2. SUMMARY: This is an amendment of the Presidential declaration of a major disaster for Public Assistance Only...

  2. 76 FR 55721 - Iowa Disaster #IA-00038

    Science.gov (United States)

    2011-09-08

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00038 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  3. 76 FR 54522 - Iowa Disaster #IA-00037

    Science.gov (United States)

    2011-09-01

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00037 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  4. 76 FR 54521 - Iowa Disaster #IA-00036

    Science.gov (United States)

    2011-09-01

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00036 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major ] disaster for Public Assistance Only for...

  5. 76 FR 29284 - Iowa Disaster #IA-00031

    Science.gov (United States)

    2011-05-20

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00031 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  6. 76 FR 27738 - Iowa Disaster #IA-00030

    Science.gov (United States)

    2011-05-12

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00030 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a notice of an Administrative declaration of a disaster for the State of Iowa dated...

  7. 78 FR 42147 - Iowa Disaster #IA-00054

    Science.gov (United States)

    2013-07-15

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00054 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance only for...

  8. 75 FR 45681 - Iowa Disaster #IA-00025

    Science.gov (United States)

    2010-08-03

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00025 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  9. 75 FR 47035 - Iowa Disaster # IA-00026

    Science.gov (United States)

    2010-08-04

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00026 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance only for...

  10. 76 FR 52042 - Iowa Disaster #IA-00035

    Science.gov (United States)

    2011-08-19

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00035 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a notice of an Administrative declaration of a disaster for the State of Iowa Dated....

  11. 75 FR 10329 - Iowa Disaster #IA-00022

    Science.gov (United States)

    2010-03-05

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Iowa Disaster IA-00022 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This is a Notice of the Presidential declaration of a major disaster for Public Assistance Only for...

  12. Single Degenerate Progenitors of Type Ia Supernovae

    Science.gov (United States)

    Bours, Madelon; Toonen, Silvia; Nelemans, Gijs

    2013-01-01

    There is a general agreement that Type Ia supernovae correspond to the thermonuclear runaway of a white dwarf (WD) in a compact binary. The details of these progenitor systems are still unclear. Using the population synthesis code SeBa and several assumption for the WD retention efficiency, we estimate the delay times and supernova rates for the single degenerate scenario.

  13. 78 FR 48762 - Iowa Disaster #IA-00053

    Science.gov (United States)

    2013-08-09

    ... ADMINISTRATION Iowa Disaster IA-00053 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY: This...: Submit completed loan applications to: U.S. Small Business Administration, Processing and Disbursement... of Disaster Assistance, U.S. Small Business Administration, 409 3rd Street SW., Suite...

  14. Probing Cosmological Isotropy With Type IA Supernovae

    CERN Document Server

    Bengaly, C A P; Alcaniz, J S

    2015-01-01

    We investigate the validity of the Cosmological Principle by mapping the cosmological parameters $H_0$ and $q_0$ through the celestial sphere. In our analysis, performed in a low-redshift regime to follow a model-independent approach, we use two compilations of type Ia Supernovae (SNe Ia), namely the Union2.1 and the JLA datasets. Firstly, we show that the angular distributions for both SNe Ia datasets are statistically anisotropic at high confidence level ($p$-value $<$ 0.0001), in particular the JLA sample. Then we find that the cosmic expansion and acceleration are mainly of dipolar type, with maximal anisotropic expansion [acceleration] pointing towards $(l,b) \\simeq (326^{\\circ},12^{\\circ})$ [$(l,b) \\simeq (174^{\\circ},27^{\\circ})$], and $(l,b) \\simeq (58^{\\circ},-60^{\\circ})$ [$(l,b) \\simeq (225^{\\circ},51^{\\circ})$] for the Union2.1 and JLA data, respectively. Secondly, we use a geometrical method to test the hypothesis that the non-uniformly distributed SNe Ia events could introduce anisotropic imp...

  15. Merging white dwarfs and SN Ia

    CERN Document Server

    Yungelson, L R

    2016-01-01

    Using population synthesis, we study a double-degenerate (DD) scenario for SNe Ia, aiming to estimate the maximum possible contribution to the rate of SNe from this scenario and the dependence of the delay-time distribution (DTD) on it. We make an extreme assumption that all mergers of super-Chandrasekhar pairs of CO white dwarfs (WDs) and mergers of CO WDs more massive than 0.47 $M_\\odot$ with hybrid or helium WDs more massive than 0.37$M_\\odot$ produce SNe Ia. The models are parametrized by the product of the common envelope efficiency and the parameter of binding energy of stellar envelopes $\\alpha_{ce}\\lambda$, which we vary between 0.25 and 2. The best agreement with observations is obtained for $\\alpha_{ce}\\lambda$=2. A substantial contribution to the rate of SNe Ia is provided by the pairs with a hybrid WD. The estimated Galactic rate of SNe Ia is $6.5 10^{-3}$ per yr (for the mass of the bulge and thin disk equal to $7.2 10^{10} M_\\odot$), which is comparable to the observational estimate $(5.4\\pm0.12...

  16. IAS 17 Leases - A Closer Look

    OpenAIRE

    Muthupandian, K S

    2009-01-01

    The International Accounting Standards Committee issued the the International Accounting Standard 17, Leases. The objective of IAS 17 is to prescribe, for lessees and lessors, the appropriate accounting treatment and disclosures to apply in relation to leases. This article presents a closer look of standard (objective, scope, definitions, accounting treatment, recognition, presentation and disclosures).

  17. Contamination from gold and platinum-group metals mining in the Gulf of Darién, Colombia

    Science.gov (United States)

    Vasquez-Bedoya, L.; Palacio Baena, J.

    2013-12-01

    Gulf of Darién, triangular southernmost extension of the Caribbean Sea, bounded by Panama on the southwest and by Colombia on the southeast and east. The Gulf is made up of 17 municipalities in the department of Choco and Antioquia. The Gulf of Darién is a geostrategic region, rich in biodiversity, known for its natural resources of minerals, oil, lumber as well as its water and fertile land. The Darién also acts as the bridge between South America and Central America and has access to the Pacific Ocean and the Caribbean Sea. The economy in the region is based mainly on agribusinesses, tourism and mining activities, mainly the 'mining of gold and platinum-group metals'. In our study we determined the degree of trace element contamination in estuarine sediment samples originated from mining activities and municipal waste water discharges of effluents on the gulf of Darién. . Surface samples were taken from 17 locations through the entire Gulf. Grain size, Corg, Ag, Al, Ca , Cr, Cu, Fe, Mg, Mn, Na, Ni, Pb and Zn concentrations were analyzed, and enrichment factors (EF) as well as geo-accumulation indices (Igeo) were calculated. Concentrations of Pb, Zn, Ni, Cu and Cr show levels that are consistent with those typically found in urbanized marine environments. EF and Igeo values revealed that the Gulf is extremely contaminated with Ag and moderately contaminated with Cr and Zn. The sources of Cr, Ag, Hg and Zn are associated with the development of mining activities in the Atrato River basin. The observed enrichment of Ag may be explained as a residue of the extraction of gold and platinum-group metals.

  18. Structure, bonding and energetics of N-heterocyclic carbene (NHC) stabilized low oxidation state group 2 (Be, Mg, Ca, Sr and Ba) metal complexes: A theoretical study

    Indian Academy of Sciences (India)

    Ashim Baishya; V Rao Mundlapati; Sharanappa Nembenna; Himansu S Biswal

    2014-11-01

    A series of N-heterocyclic carbene stabilized low oxidation state group 2 metal halide and hydrides with metal-metal bonds ([L(X) M-M(X) L]; L = NHC ((CHNH)2C:), M = Be, Mg, Ca, Sr and Ba, and X = Cl or H) has been studied by computational methods. The main objective of this study is to predict whether it is possible to stabilize neutral ligated low oxidation state alkaline-earth metal complexes with metal-metal bonds. The homolytic metal-metal Bond Dissociation Energy (BDE) calculation, Natural Bond Orbital (NBO) and Energy Decomposition Analyses (EDA) on density functional theory (DFT) optimized [L(X)M-M(X)L] complexes revealed that they are as stable as their -diketiminate, guanidinate and -diimine counterparts. The optimized structures of the complexes are in trans-linear geometries. The bond order analyses such as Wiberg Bond Indices (WBI) and Fuzzi Bond Order (FBO) confirm the existence of single bond between two metal atoms, and it is covalent in nature.

  19. IA-2及IA-2β与1型糖尿病

    Institute of Scientific and Technical Information of China (English)

    宗阳; 罗敏

    2000-01-01

    IA-2和IA-2β是近年来发现的两种重要胰岛细胞自身抗原,是引发1型糖尿病胰岛自身免疫反应的重要因素.针对两者的自身抗体存在于半数以上的新诊1型糖尿病患者血清中.IA-2、IA-2β及其抗体检测在1型糖尿病的发病机制研究、诊断、预测和早期防治中具有重要作用.

  20. Metal distributions out to 0.5 r {sub 180} in the intracluster medium of four galaxy groups observed with Suzaku

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, Toru; Matsushita, Kyoko; Sato, Kosuke, E-mail: j1213703@ed.tus.ac.jp, E-mail: matusita@rs.kagu.tus.ac.jp [Department of Physics, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601 (Japan)

    2014-01-20

    We studied the distributions of metal abundances and metal-mass-to-light ratios in the intracluster medium (ICM) of four galaxy groups, MKW 4, HCG 62, the NGC 1550 group, and the NGC 5044 group, out to ∼0.5 r {sub 180} observed with Suzaku. The iron abundance decreases with radius and is about 0.2-0.4 solar beyond 0.1 r {sub 180}. At a given radius in units of r {sub 180}, the iron abundance in the ICM of the four galaxy groups was consistent with or smaller than those of clusters of galaxies. The Mg/Fe and Si/Fe ratios in the ICM are nearly constant at the solar ratio out to 0.5 r {sub 180}. We also studied systematic uncertainties in the derived metal abundances, comparing the results from two versions of atomic data for astrophysicists (ATOMDB) and single- and two-temperature model fits. Since the metals have been synthesized in galaxies, we collected K-band luminosities of galaxies from the Two Micron All Sky Survey catalog and calculated the integrated iron-mass-to-light-ratios (IMLR), or the ratios of the iron mass in the ICM to light from stars in galaxies. The groups with smaller gas-mass-to-light ratios have smaller IMLR values and the IMLR is inversely correlated with the entropy excess. Based on these abundance features, we discussed the past history of metal enrichment processes in groups of galaxies.

  1. Color excesses of type Ia supernovae from the single-degenerate channel model

    Institute of Scientific and Technical Information of China (English)

    Xiang-Cun Meng; Xue-Fei Chen; Zhan-Wen Han; Wu-Ming Yang

    2009-01-01

    The single degenerate model is the most widely accepted progenitor model of type Ia supernovae (SNe Ia),in which a carbon-oxygen white dwarf (CO WD) accretes hydrogen-rich material from a main sequence or a slightly evolved star (WD+MS) to increase its mass,and explodes when its mass approaches the Chandrasekhar mass limit.During the mass transfer phase between the two components,an optically thick wind may occur and the material lost as wind may exist as circumstellar material (CSM).Searching for the CSM around a progenitor star is helpful for discriminating different progenitor models of SNe Ia.In addition,the CSM is a source of color excess.The purpose of this paper is to study the color excess produced from the single-degenerate progenitor model with an optically thick wind,and reproduce the distribution of color excesses of SNe Ia.Meng et al.systemically carried out binary evolution calculations of the WD +MS systems for various metallicities and showed the parameters of the systems before Roche lobe overflow and at the moment of supernova explosion in Meng & Yang.With the results of Meng et al.,we calculate the color excesses of SNe Ia at maximum light via a simple analytic method.We reproduce the distribution of color excesses of SNe Ia by our binary population synthesis approach if the velocity of the optically thick wind is taken to be an order of magnitude of 10kin s~(-1).However,if the wind velocity is larger than 100km s~(-1),the reproduction is bad.

  2. Early observations of the nearby Type Ia supernova SN 2015F

    Science.gov (United States)

    Cartier, R.; Sullivan, M.; Firth, R. E.; Pignata, G.; Mazzali, P.; Maguire, K.; Childress, M. J.; Arcavi, I.; Ashall, C.; Bassett, B.; Crawford, S. M.; Frohmaier, C.; Galbany, L.; Gal-Yam, A.; Hosseinzadeh, G.; Howell, D. A.; Inserra, C.; Johansson, J.; Kasai, E. K.; McCully, C.; Prajs, S.; Prentice, S.; Schulze, S.; Smartt, S. J.; Smith, K. W.; Smith, M.; Valenti, S.; Young, D. R.

    2017-02-01

    We present photometry and time series spectroscopy of the nearby Type Ia supernova (SN Ia) SN 2015F over -16 d to +80 d relative to maximum light, obtained as part of the Public ESO Spectroscopic Survey of Transient Objects. SN 2015F is a slightly sub-luminous SN Ia with a decline rate of Δm15(B) = 1.35 ± 0.03 mag, placing it in the region between normal and SN 1991bg-like events. Our densely sampled photometric data place tight constraints on the epoch of first light and form of the early-time light curve. The spectra exhibit photospheric C II λ6580 absorption until -4 days, and high-velocity Ca II is particularly strong at 14 000 km s-1, suggesting mixing in the outermost layers of the SN ejecta. Although unusual in SN Ia spectra, including V II in the modelling significantly improves the spectral fits. Intriguingly, we detect an absorption feature at ˜6800 Å that persists until maximum light. Our favoured explanation for this line is photospheric Al II, which has never been claimed before in SNe Ia, although detached high-velocity C II material could also be responsible. In both cases, the absorbing material seems to be confined to a relatively narrow region in velocity space. The nucleosynthesis of detectable amounts of Al II would argue against a low-metallicity white dwarf progenitor. We also show that this 6800 Å feature is weakly present in other normal SN Ia events and common in the SN 1991bg-like sub-class.

  3. Correlations Between Hubble Residuals and Local Stellar Populations of Type Ia Supernovae

    Science.gov (United States)

    Rose, Benjamin; Garnavich, Peter M.

    2017-01-01

    There appears to be correlations between SN Ia Hubble diagram residuals and host galaxy mass, metallicity, and star formation history. An uncorrected bias may produce a systematic offset in cosmological measurements. Rigault et al. (2013) found that the local environment can correlate with Hubble residuals and possibly impact precision Hubble Constant measurements. Global properties are the luminosity average of local environments, therefore the properties of local environments may hold stronger correlations than their global counterparts. We analyze host galaxies from the SDSS-II survey using both ground-based and Hubble Space Telescope imaging. We generate local stellar environmental properties by selecting a best fit Flexible Stellar Population Synthesis model that matches the SDSS Scene Modeling data. The derived properties, such as metallicity, stellar age, and star formation history, are then compared to the SN Ia's Hubble residual in the search for correlations.

  4. 75 FR 37292 - Amendment of Class E Airspace; Cherokee, IA

    Science.gov (United States)

    2010-06-29

    ... Cherokee, IA. Decommissioning of the Pilot Rock non-directional beacon (NDB) at Cherokee County Regional Airport, Cherokee, IA has made this action necessary to enhance the safety and management of Instrument... Federal Aviation Administration 14 CFR Part 71 Amendment of Class E Airspace; Cherokee, IA AGENCY:...

  5. 76 FR 73501 - Amendment of Class E Airspace; Carroll, IA

    Science.gov (United States)

    2011-11-29

    ... Carroll, IA. Decommissioning of the Carroll non-directional beacon (NDB) at Arthur N. Neu Airport, Carroll, IA, has made this action necessary to enhance the safety and management of Instrument Flight Rule... Federal Aviation Administration 14 CFR Part 71 Amendment of Class E Airspace; Carroll, IA AGENCY:...

  6. Expression of I-A and I-E,C region-coded Ia antigens on functional B cell subpopulations.

    Science.gov (United States)

    Frelinger, J A; Hibbler, F J; Hill, S W

    1978-12-01

    Ia antigens from specific subregions have been examined on functional B cell populations. Expression of both I-A and I-E,C region antigens was demonstrated on cells required for both lipopolysaccharide mitogenesis and polyclonal activation. Similar I-A and I-E,C subregion expression was found on cells required for response to the T-independent antigen, polyvinylpyrrolidone. TNP-specific IgM and hen egg lysozyme-specific IgG plaque-forming cells also express I-A and I-E,C region antigens. No evidence was found for an Ia- population responsive in the systems tested. Further, no evidence of preferential expression of I-A or I-E,C region antigens was observed in any system examined. Therefore, it appears that B cells express both I-A and I-E,C region-coded Ia antigens.

  7. European freshwater VHSV genotype Ia isolates divide into two distinct subpopulations.

    Science.gov (United States)

    Kahns, S; Skall, H F; Kaas, R S; Korsholm, H; Bang Jensen, B; Jonstrup, S P; Dodge, M J; Einer-Jensen, K; Stone, D; Olesen, N J

    2012-05-15

    Viral haemorrhagic septicaemia (VHS), caused by the novirhabdovirus VHSV, often leads to significant economic losses to European rainbow trout production. The virus isolates are divided into 4 distinct genotypes with additional subgroups including sublineage Ia, isolates of which are the main source of outbreaks in European rainbow trout farming. A significant portion of Danish rainbow trout farms have been considered endemically infected with VHSV since the first disease outbreak was observed in the 1950s. However, following a series of sanitary programs starting in 1965, VHSV has not been detected in Denmark since January 2009. Full-length G-genes of all Danish VHSV isolates that were submitted for diagnostic analyses in the period 2004-2009 were sequenced and analysed. All 58 Danish isolates from rainbow trout grouped with sublineage Ia isolates. Furthermore, VHSV isolates from infected Danish freshwater catchments appear to have evolved into a distinct clade within sublineage Ia, herein designated clade Ia-1, whereas trout isolates originating from other continental European countries cluster in another distinct clade, designated clade Ia-2. In addition, phylogenetic analyses indicate that VHSV Ia-1 strains have caused a few outbreaks in Germany and the UK. It is likely that viruses have been transmitted from infected site(s) out of the Danish environment, although a direct transmission pathway has not been identified. Furthermore, VHSV Ia-2 isolates seem to have been transmitted to Denmark at least once. Interestingly, one viral isolate possibly persisted in a Danish watershed for nearly 4 yr without detection whereas other subclades of VHSV isolates appear to have been eliminated, probably because of implemented eradication procedures.

  8. Reddened, Redshifted, or Intrinsically Red? Understanding Near-ultraviolet Colors of Type Ia Supernovae

    Science.gov (United States)

    Brown, Peter J.; Landez, Nancy J.; Milne, Peter A.; Stritzinger, Maximilian D.

    2017-02-01

    The intrinsic colors of Type Ia supernovae (SNe Ia) are important to understanding their use as cosmological standard candles. Understanding the effects of reddening and redshift on the observed colors are complicated and dependent on the intrinsic spectrum, the filter curves, and the wavelength dependence of reddening. We present ultraviolet and optical data of a growing sample of SNe Ia observed with the Ultraviolet/Optical Telescope on the Swift spacecraft and use this sample to re-examine the near-UV (NUV) colors of SNe Ia. We find that a small amount of reddening (E(B ‑ V) = 0.2 mag) could account for the difference between groups designated as NUV-blue and NUV-red, and a moderate amount of reddening (E(B ‑ V) = 0.5 mag) could account for the whole NUV-optical differences. The reddening scenario, however, is inconsistent with the mid-UV colors and color evolution. The effect of redshift alone only accounts for part of the variation. Using a spectral template of SN2011fe, we can forward model the effects of redshift and reddening and directly compare those with the observed colors. We find that some SNe are consistent with reddened versions of SN2011fe, but most SNe Ia are much redder in the uvw1 ‑ v color than SN2011fe reddened to the same b ‑ v color. The absolute magnitudes show that two out of five NUV-blue SNe Ia are blue because their near-UV luminosity is high, and the other three are optically fainter. We also show that SN 2011fe is not a “normal” SN Ia in the UV, but has colors placing it at the blue extreme of our sample.

  9. PTF10ops - a subluminous, normal-width lightcurve Type Ia supernova in the middle of nowhere

    CERN Document Server

    Maguire, Kate; Thomas, Rollin C; Nugent, Peter E; Howell, D Andrew; Gal-Yam, Avishay; Arcavi, Iair; Ben-Ami, Sagi; Blake, Sarah; Botyanszki, Janos; Buton, Clement; Cooke, Jeffery; Ellis, Richard S; Hook, Isobel M; Kasliwal, Mansi M; Pan, Yen-Chen; Pereira, Rui; Podsiadlowski, Philipp; Sternberg, Assaf; Suzuki, Nao; Xu, Dong; Yaron, Ofer; Bloom, Joshua S; Cenko, S Bradley; Kulkarni, Shrinivas R; Law, Nicholas; Ofek, Eran O; Poznanski, Dovi; Quimby, Robert M

    2011-01-01

    PTF10ops is a Type Ia supernova (SN Ia), whose lightcurve and spectral properties place it outside the current SN Ia subtype classifications. Its spectra display the characteristic lines of subluminous SNe Ia, but it has a normal-width lightcurve with a long rise-time, typical of normal luminosity SNe Ia. The early-time optical spectra of PTF10ops were modelled using a spectral fitting code and found to have all the lines typically seen in subluminous SNe Ia, without the need to invoke more uncommon elements. The host galaxy environment of PTF10ops is also unusual with no galaxy detected at the position of the SN down to an absolute limiting magnitude of r \\geq -12.0 mag, but a very massive galaxy is present at a separation of ~148 kpc and at the same redshift as suggested by the SN spectral features. The progenitor of PTF10ops is most likely a very old star, possibly in a low metallicity environment, which affects its explosion mechanism and observational characteristics. PTF10ops does not easily fit into an...

  10. Synthesis and characterization of norfloxacin-transition metal complexes (group 11, IB): Spectroscopic, thermal, kinetic measurements and biological activity

    Science.gov (United States)

    Refat, Moamen S.

    2007-12-01

    The investigation of the new structures of Ag(I), Cu(II) and Au(III) complexes, [Ag 2(Nor) 2](NO 3) 2, [Cu(Nor) 2(H 2O) 2]SO 4·5H 2O and [Au(Nor) 2 (H 2O) 2]Cl 3 (where, Nor = norfloxacin) was done during the reaction of silver(I), copper(II) and gold(III) ions with norfloxacin drug ligand. Elemental analysis of CHN, infrared, electronic, 1H NMR and mass spectra, as well as thermo gravimetric analysis (TG and DTG) and conductivity measurements have been used to characterize the isolated complexes. The powder XRD studies confirm the amorphous nature of the complexes. The norfloxacin ligand is coordinated to Ag(I) and Au(III) ions as a neutral monodentate chelating through the N atom of piperidyl ring, but the copper(II) complex is coordinated through the carbonyl oxygen atom (quinolone group) and the oxygen atom of the carboxylic group. The norfloxacin and their metal complexes have been biologically tested, which resulted in norfloxacin complexes showing moderate activity against the gram positive and gram negative bacteria as well as against fungi.

  11. Development of “Functional Groups in Molecules” Models For Fundamental Science Curriculum

    Directory of Open Access Journals (Sweden)

    Kowit KITTIWUTTHISAKDI

    2007-06-01

    Full Text Available In order to teach quantum concepts to primary school students, new molecular models have been developed to better visualize a few typical molecules. Both computer and physical molecular models particularly those displaying functional groups were created from Atoms in Molecules (AIM theory. The surface of each model was calculated from 0.01 atomic unit (au electron density surface of the molecule. MORPHY was used to calculate an inter-atomic surface (IAS, and several software programs such as Gaussian, VMD, Points2Polys, and Vizx3D were utilized to create three dimensional models. Different functional groups were colored, and connections between the functional groups were shown by IAS. The final physical molecular models were prepared by a rapid prototype machine at Thailand National Metal and Materials Technology Center (MTEC.

  12. Novel relationship between hydroxyl radical initiation and surface group of ceramic honeycomb supported metals for the catalytic ozonation of nitrobenzene in aqueous solution.

    Science.gov (United States)

    Zhao, Lei; Sun, Zhizhong; Ma, Jun

    2009-06-01

    Comparative experiments have been performed to investigate the degradation efficiency of nitrobenzene and the removal efficiency of TOC in aqueous solution bythe processes of ceramic honeycomb supported different metals (Fe, Ni, and Zn) catalytic ozonation, indicating that the modification with metals can enhance the activity of ceramic honeycomb for the catalytic ozonation of nitrobenzene, and the loading percentage of metal and the metallicity respectively presents a positive influence on the degradation of nitrobenzene. The degradation efficiency of nitrobenzene is determined by the initiation of hydroxyl radical (*OH) according to a good linear correlation in all the processes of modified ceramic honeycomb catalytic ozonation at the different loading percentages of metals. The modification of ceramic honeycomb with metals results in the conversion of the pH at the point of zero charge (pHpzc) and the evolution of surface groups. Divergence from the conventional phenomenon, the enhancement mechanism of ozone decomposition on the modified ceramic honeycomb with metals is proposed due to the basic attractive forces of electrostatic forces or/and hydrogen bonding. Consequently, a novel relationship between the initiation of *OH and the surface-OH2+ group on the modified catalyst is established based on the synergetic effect between homogeneous and heterogeneous reaction systems.

  13. Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in Ni(II) coordination chemistry: the case of PO3F(2-) group.

    Science.gov (United States)

    Dermitzaki, Despina; Raptopoulou, Catherine P; Psycharis, Vassilis; Escuer, Albert; Perlepes, Spyros P; Stamatatos, Theocharis C

    2014-10-21

    The initial 'accidental', metal ion-assisted hydrolysis of PF6(-) to PO3F(2-) has been evolved in a systematic investigation of the bridging affinity of the latter group in Ni(II)/oximate chemistry; mono-, di- and trinuclear complexes have been prepared and confirmed both the rich reactivity of PO3F(2-) and its potential for further use as bridging ligand in high-nuclearity 3d-metal cluster chemistry.

  14. 75 FR 16067 - Designation for the Champaign, IL; Emmett, MI; Davenport, IA; Enid, OK; Keokuk, IA; Marshall, MI...

    Science.gov (United States)

    2010-03-31

    ... Register (74 FR 45803), GIPSA requested applications for designation to provide official services in the...; Davenport, IA; Enid, OK; Keokuk, IA; Marshall, MI; and Omaha, NE Areas AGENCY: Grain Inspection, Packers and.... Detroit Emmett, MI (810-395-2105) 4/1/2010 3/31/2013 Eastern Iowa Davenport, IA (563-322-7149). 4/1/2010...

  15. High-performance ab initio density matrix renormalization group method: Applicability to large-scale multireference problems for metal compounds

    Science.gov (United States)

    Kurashige, Yuki; Yanai, Takeshi

    2009-06-01

    This article presents an efficient and parallelized implementation of the density matrix renormalization group (DMRG) algorithm for quantum chemistry calculations. The DMRG method as a large-scale multireference electronic structure model is by nature particularly efficient for one-dimensionally correlated systems, while the present development is oriented toward applications for polynuclear transition metal compounds, in which the macroscopic one-dimensional structure of electron correlation is absent. A straightforward extension of the DMRG algorithm is proposed with further improvements and aggressive optimizations to allow its application with large multireference active space, which is often demanded for metal compound calculations. Special efficiency is achieved by making better use of sparsity and symmetry in the operator and wave function representations. By accomplishing computationally intensive DMRG calculations, the authors have found that a large number of renormalized basis states are required to represent high entanglement of the electron correlation for metal compound applications, and it is crucial to adopt auxiliary perturbative correction to the projected density matrix during the DMRG sweep optimization in order to attain proper convergence to the solution. Potential energy curve calculations for the Cr2 molecule near the known equilibrium precisely predicted the full configuration interaction energies with a correlation space of 24 electrons in 30 orbitals [denoted by (24e,30o)]. The energies are demonstrated to be accurate to 0.6mEh (the error from the extrapolated best value) when as many as 10 000 renormalized basis states are employed for the left and right DMRG block representations. The relative energy curves for [Cu2O2]2+ along the isomerization coordinate were obtained from DMRG and other correlated calculations, for which a fairly large orbital space (32e,62o) is modeled as a full correlation space. The DMRG prediction nearly overlaps

  16. Dissociation potential curves of low-lying states in transition metal hydrides. 3. Hydrides of groups 6 and 7.

    Science.gov (United States)

    Koseki, Shiro; Matsushita, Takeshi; Gordon, Mark S

    2006-02-23

    The dissociation curves of low-lying spin-mixed states in monohydrides of groups 6 and 7 were calculated by using an effective core potential (ECP) approach. This approach is based on the multiconfiguration self-consistent field (MCSCF) method, followed by first-order configuration interaction (FOCI) calculations, in which the method employs an ECP basis set proposed by Stevens and co-workers (SBKJC) augmented by a set of polarization functions. Spin-orbit coupling (SOC) effects are estimated within the one-electron approximation by using effective nuclear charges, since SOC splittings obtained with the full Breit-Pauli Hamitonian are underestimated when ECP basis sets are used. The ground states of group 6 hydrides have Omega = (1)/(2)(X(6)Sigma(+)(1/2)), where Omega is the z component of the total angular momentum quantum number. Although the ground states of group 7 hydrides have Omega = 0(+), their main adiabatic components are different; the ground state in MnH originates from the lowest (7)Sigma(+), while in TcH and ReH the main component of the ground state is the lowest (5)Sigma(+). The present paper reports a comprehensive set of theoretical results including the dissociation energies, equilibrium distances, electronic transition energies, harmonic frequencies, anharmonicities, and rotational constants for several low-lying spin-mixed states in these hydrides. Transition dipole moments were also computed among the spin-mixed states and large peak positions of electronic transitions are suggested theoretically for these hydrides. The periodic trends of physical properties of metal hydrides are discussed, based on the results reported in this and other recent studies.

  17. DFT study on the mechanism of water-assisted dihydrogen elimination in group 6 octahedral metal hydride complexes.

    Science.gov (United States)

    Sandhya, K S; Suresh, Cherumuttathu H

    2012-08-28

    The reaction of water with octahedral bis-, tris- and tetrakis-(phosphine)tungsten, (phosphine)molybdenum and (phosphine)chromium complexes has been studied using B3LYP/def2-TZVPP level of DFT to elucidate dissociative, associative and hydride migratory insertion mechanisms for hydrogen elimination. In the dissociative mechanism, phosphine dissociation requires 19.3-28.5 kcal mol(-1) of energy. The phosphine-water ligand exchange is endergonic due to poor coordination ability of water to group 6 metals (binding energy 8.8-15.5 kcal mol(-1)). The ligand exchange leads to intermolecular M-H···H(2)O dihydrogen interaction and facilitates dihydrogen elimination (G(act) = 6.8-15.5 kcal mol(-1)). In the associative mechanism, a water molecule in the first solvation shell interacts with the M-H bond through a dihydrogen bond (interaction energy 2.7-4.0 kcal mol(-1)) and leads to the elimination of H(2) by forming a hydroxide complex. Compared to the dissociative mechanism, G(act) of associative mechanisms are ~22 kcal mol(-1) higher. In the hydride migratory insertion mechanism, the hydride ligand shifts to the CO ligand (G(act) = 25.4-30.4 kcal mol(-1)) to afford a formyl complex and subsequently the H-H bond coupling occurs between formyl and water ligand (G(act) = 2.8-4.4 kcal mol(-1)). In many cases, the migratory insertion mechanism can simultaneously operate with the dissociative mechanism as a minor pathway, whereas owing to high G(act) value, the associative mechanism can be described as inactive in the reaction. The general argument that dihydrogen elimination is preceded by the formation of a dihydrogen intermediate is not applicable for the systems studied herein as the most favoured dissociative mechanism does not pass through such an intermediate. On the other hand, irrespective of the mechanisms, dihydrogen elimination invariably occurs with the formation of a dihydrogen bonded transition state. Our results also suggest that group 6 octahedral metal

  18. Birthrates and delay times of Type Ia supernovae

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Type Ia supernovae (SNe Ia) play an important role in diverse areas of astrophysics, from the chemical evolution of galaxies to observational cosmology. However, the nature of the progenitors of SNe Ia is still unclear. In this paper, according to a detailed binary population synthesis study, we obtained SN Ia birthrates and delay times from different progenitor models, and compared them with observations. We find that the Galactic SN Ia birthrate from the double-degenerate (DD) model is close to those inferred from observations, while the birthrate from the single-degenerate (SD) model accounts for only about 1/2-2/3 of the observations. If a single starburst is assumed, the distribution of the delay times of SNe Ia from the SD model is a weak bimodality, where the WD + He channel contributes to the SNe Ia with delay times shorter than 100 Myr, and the WD + MS and WD + RG channels to those with age longer than 1 Gyr.

  19. Coréia aguda na gravidez

    Directory of Open Access Journals (Sweden)

    Walter C. Pereira

    1967-12-01

    Full Text Available São apresentados doze casos de coréia aguda observados entre 150.000 gestantes (1/12.500. A maioria dos surtos ocorreu no segundo trimestre da primeira gravidez. A duração média dos sintomas foi de três meses, não tendo sido registrado caso algum de óbito materno. Todos os partos foram espontâneos e normais. Houve apenas um óbito fetal conseqüente a choque hemorrágico. São tecidas considerações a propósito dos aspectos clínico, laboratorial e prognóstico da coréia gravídica, sendo focalizado mais pormenorizadamente o problema fisiopatogênico dessa afecção.

  20. First principles study of structural, electronic and elastic properties of group IB metal nitrides TMN{sub x} (TM = Cu, Ag and Au: x = 1, 2)

    Energy Technology Data Exchange (ETDEWEB)

    Rajeswarapalanichamy, R., E-mail: rrpalanichamy@gmail.com [Department of Physics, N.M.S.S.V.N College, Madurai, Tamil Nadu 625 019 (India); Priyanga, G. Sudha; Murugan, A.; Santhosh, M.; Cinthia, A. Jemmy [Department of Physics, N.M.S.S.V.N College, Madurai, Tamil Nadu 625 019 (India); Kanagaprabha, S. [Department of Physics, Kamaraj College, Tuticorin, Tamil Nadu 628 003 (India); Iyakutti, K. [Department of Physics and Nanotechnology, SRM University, Chennai, Tamil Nadu 603 203 (India)

    2013-12-15

    Highlights: •Electronic, structural and elastic properties of group IB nitrides are investigated. •A pressure induced structural phase transition is predicted under high pressure. •Electronic structure reveals that these materials exhibit metallic behavior. •Computed elastic moduli obey traditional mechanical stability condition. •The Debye temperature values are computed for Group IB metal mono and di-nitrides. -- Abstract: The structural, electronic and elastic properties of group IB transition metal nitrides (TMN{sub x}: TM = Cu, Ag, Au and x = 1, 2) are investigated by first principles calculation using the Vienna ab initio simulation package. The lattice constants, cohesive energy, bulk modulus, band structures and the density of states are obtained. The calculated lattice parameters are in good agreement with the available results. The electronic structure reveals that these materials exhibit metallic behaviour. A pressure-induced structural phase transition from NaCl to CsCl phase in AgN at 6 GPa, NaCl to ZB phase in AuN at 34.2 GPa and ZB to NaCl phase in CuN at 36.2 GPa is observed. In group IB metal di-nitrides, CaF{sub 2} to AlB{sub 2} phase transition is predicted. The computed elastic constants indicate that these nitrides are mechanically stable at ambient pressure. The calculated Debye temperature values are in good agreement with experimental and other theoretical results.

  1. Verifying the Cosmological Utility of Type Ia Supernovae: Implications of a Dispersion in the Ultraviolet Spectra

    CERN Document Server

    Ellis, Richard S; Nugent, P E; Howell, D A; Gal-Yam, A; Astier, Pierre; Balam, D; Balland, C; Basa, S; Carlberg, R G; Conley, A; Fouchez, D; Guy, J; Hardin, D; Hook, I; Pain, R; Perrett, K; Pritchet, C J; Regnault, N

    2007-01-01

    We analyze the mean rest-frame ultraviolet (UV) spectrum of Type Ia Supernovae (SNe Ia) and its dispersion using high signal-to-noise Keck-I/LRIS-B spectroscopy for a sample of 36 events at intermediate redshift (z=0.5) discovered by the Canada-France-Hawaii Telescope Supernova Legacy Survey (SNLS). We introduce a new method for removing host galaxy contamination in our spectra, exploiting the comprehensive photometric coverage of the SNLS SNe and their host galaxies, thereby providing the first quantitative view of the UV spectral properties of a large sample of distant SNe Ia. Although the mean SN Ia spectrum has not evolved significantly over the past 40% of cosmic history, precise evolutionary constraints are limited by the absence of a comparable sample of high quality local spectra. Within the high-redshift sample, we discover significant UV spectral variations and exclude dust extinction as the primary cause by examining trends with the optical SN color. Although progenitor metallicity may drive some o...

  2. Single degenerate supernova type Ia progenitors

    CERN Document Server

    Bours, M C P; Nelemans, G

    2013-01-01

    There is general agreement that supernovae Ia correspond to the thermonuclear runaway of a white dwarf that is part of a compact binary, but the details of the progenitor systems are still unknown and much debated. One of the proposed progenitor theories is the single-degenerate channel in which a white dwarf accretes from a companion, grows in mass, reaches a critical mass limit, and is then consumed after thermonuclear runaway sets in. However, there are major disagreements about the theoretical delay time distribution and the corresponding time-integrated supernova Ia rate from this channel. We investigate whether the differences are due to the uncertainty in the common envelope phase and the fraction of transferred mass that is retained by the white dwarf. This so-called retention efficiency may have a strong influence on the final amount and timing of supernovae Ia. Using the population synthesis code SeBa, we simulated large numbers of binaries for various assumptions on common envelopes and retention e...

  3. New mutation type in pseudohypoparathyroidism type Ia.

    Science.gov (United States)

    Fernandez-Rebollo, Eduardo; Barrio, Raquel; Pérez-Nanclares, Gustavo; Carcavilla, Atilano; Garin, Intza; Castaño, Luis; de Nanclares, Guiomar Pérez

    2008-11-01

    The GNAS gene encodes the alpha-subunit of the stimulatory G proteins, which play a crucial role in intracellular signal transduction of peptide and neurotransmitter receptors. Heterozygous inactivating maternally inherited mutations of GNAS (including translation initiation mutations, amino acid substitutions, nonsense mutations, splice site mutations and small insertions or deletions) lead to a phenotype in which Albright hereditary osteodystrophy is associated with pseudohypoparathyroidism type Ia. We sought to identify the molecular defect in a patient who was thought to have PHP-Ia. The GNAS gene of a 5-year-old boy with brachydactily, mental retardation, pseudohypoparathyroidism and congenital hypothyroidism was investigated. We found a heterozygous inversion of exon 2 and part of intron 1 of de novo origin. Molecular studies of cDNA from blood RNA demonstrated that both the normal and the mutant variants were stable and that new splice-sites were generated. This report demonstrates the first evidence for an inversion at the GNAS gene responsible of pseudohypoparathyroidism type Ia.

  4. Shock Breakout from Type Ia Supernova

    CERN Document Server

    Piro, Anthony L; Weinberg, Nevin N

    2009-01-01

    The mode of explosive burning in Type Ia SNe remains an outstanding problem. It is generally thought to begin as a subsonic deflagration, but this may transition into a supersonic detonation (the DDT). We argue that this transition leads to a breakout shock, which would provide the first unambiguous evidence that DDTs occur. Its main features are a hard X-ray flash (~20 keV) lasting ~0.01 s with a total radiated energy of ~10^{40} ergs, followed by a cooling tail. This creates a distinct feature in the visual light curve, which is separate from the nickel decay. This cooling tail has a maximum absolute visual magnitude of M_V = -9 to -10 at approximately 1 day, which depends most sensitively on the white dwarf radius at the time of the DDT. As the thermal diffusion wave moves in, the composition of these surface layers may be imprinted as spectral features, which would help to discern between SN Ia progenitor models. Since this feature should accompany every SNe Ia, future deep surveys (e.g., m=24) will see i...

  5. The Carnegie Supernova Project: Intrinsic Colors of Type Ia Supernovae

    CERN Document Server

    Burns, Christopher R; Phillips, M M; Hsiao, E Y; Contreras, Carlos; Persson, S E; Folatelli, Gaston; Boldt, Luis; Campillay, Abdo; Catellón, Sergio; Freedman, Wendy L; Madore, Barry F; Morrell, Nidia; Salgado, Francisco; Suntzeff, Nicholas B

    2014-01-01

    We present an updated analysis of the intrinsic colors of SNe Ia using the latest data release of the Carnegie Supernova Project. We introduce a new light-curve parameter very similar to stretch that is better suited for fast-declining events, and find that these peculiar types can be seen as extensions to the population of "normal" SNe Ia. With a larger number of objects, an updated fit to the Lira relation is presented along with evidence for a dependence on the late-time slope of the B-V color-curves with stretch and color. Using the full wavelength range from u to H band, we place constraints on the reddening law for the sample as a whole and also for individual events/hosts based solely on the observed colors. The photometric data continue to favor low values of Rv, though with large variations from event to event, indicating an intrinsic distribution. We confirm the findings of other groups that there appears to be a correlation between the derived reddening law, Rv, and the color excess, E(B-V), such t...

  6. Adsorption of group 1b metal ions on Galena: Effects on half-cell potential and photovoltage

    Science.gov (United States)

    Kunze, O. A.

    The conditions at the solid-liquid interface play a crucial role in the flotation of minerals. These conditions are susceptible to a variety of influences, a detailed knowledge of which is important in extractive metallurgy. In this study, effects on the electrode potential and the surface photovoltage of galena as a result of the adsorption of group 1b metal ions were investigated. Significant differences in the effects of copper, silver and gold could be observed. Copper, even at very low concentration, was found to affect the rest potential markedly (> 100 mV for 1 ppm Cu 2+) and to quench the surface photovoltage. These experimental observations led us to propose a qualitative electrostatic-electrochemical model of the galena-electrolyte interface during copper-ion adsorption. According to this model, copper ions on galena can be present and act in two different modes: (a) as surface states in conjunction with the galena surface and; (b) as a constituent of copper sulphide formed on that surface. Silver produced a similar change in potential but no quenching action on the photovoltage was observed. Gold was found to have less influence on the electrode potential. The appearance of a slow photovoltage of opposite polarity to the original surface photovoltage indicates the formation of a surface layer with high lying metastable acceptor levels.

  7. First-Principles Momentum Dependent Local Ansatz Approach to the Ground-State Properties of Iron-Group Transition Metals

    Science.gov (United States)

    Kakehashi, Yoshiro; Chandra, Sumal

    2016-08-01

    The ground-state properties of iron-group transition metals from Sc to Cu have been investigated on the basis of the first-principles momentum dependent local ansatz (MLA) theory. Correlation energy gain is found to show large values for Mn and Fe: 0.090 Ry (Mn) and 0.094 Ry (Fe). The Hund-rule coupling energies are found to be 3000 K (Fe), 1400 K (Co), and 300 K (Ni). It is suggested that these values can resolve the inconsistency in magnetic energy between the density functional theory and the first-principles dynamical coherent potential approximation theory at finite temperatures. Charge fluctuations are shown to be suppressed by the intra-orbital correlations and inter-orbital charge-charge correlations, so that they show nearly constant values from V to Fe: 1.57 (V and Cr), 1.52 (Mn), and 1.44 (Fe), which are roughly twice as large as those obtained by the d band model. The amplitudes of local moments are enhanced by the intra-orbital and inter-orbital spin-spin correlations and show large values for Mn and Fe: 2.87 (Mn) and 2.58 (Fe). These values are in good agreement with the experimental values estimated from the effective Bohr magneton number and the inner core photoemission data.

  8. First-Principles Momentum Dependent Local Ansatz Approach to the Momentum Distribution Function in Iron-Group Transition Metals

    Science.gov (United States)

    Kakehashi, Yoshiro; Chandra, Sumal

    2017-03-01

    The momentum distribution function (MDF) bands of iron-group transition metals from Sc to Cu have been investigated on the basis of the first-principles momentum dependent local ansatz wavefunction method. It is found that the MDF for d electrons show a strong momentum dependence and a large deviation from the Fermi-Dirac distribution function along high-symmetry lines of the first Brillouin zone, while the sp electrons behave as independent electrons. In particular, the deviation in bcc Fe (fcc Ni) is shown to be enhanced by the narrow eg (t2g) bands with flat dispersion in the vicinity of the Fermi level. Mass enhancement factors (MEF) calculated from the jump on the Fermi surface are also shown to be momentum dependent. Large mass enhancements of Mn and Fe are found to be caused by spin fluctuations due to d electrons, while that for Ni is mainly caused by charge fluctuations. Calculated MEF are consistent with electronic specific heat data as well as recent angle resolved photoemission spectroscopy data.

  9. Putting an ultrahigh concentration of amine groups into a metal-organic framework for CO2 capture at low pressures.

    Science.gov (United States)

    Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang; Li, Xu-Yu; Xu, Yan-Tong; Tang, Minni; Rui, Zebao; Ji, Hongbing; Zhang, Jie-Peng; Chen, Xiao-Ming

    2016-10-19

    Tremendous efforts have been devoted to increasing the CO2 capture performance of porous materials, especially for low CO2 concentration environments. Here, we report that hydrazine can be used as a diamine short enough to functionalize the small-pore metal-organic framework [Mg2(dobdc)] (H4dobdc = 2,5-dihydroxyl-1,4-benzenedicarboxylic acid). By virtue of the ultrahigh concentration of free amine groups (6.01 mmol g(-1) or 7.08 mmol cm(-3)) capable of reversible carbamic acid formation, the new material [Mg2(dobdc)(N2H4)1.8] achieves a series of new records for CO2 capture, such as single-component isotherm uptakes of 3.89 mmol g(-1) or 4.58 mmol cm(-3) at the atmospheric CO2 concentration of 0.4 mbar at 298 K and 1.04 mmol g(-1) or 1.22 mmol cm(-3) at 328 K, as well as more than a 4.2 mmol g(-1) or 4.9 mmol cm(-3) adsorption/desorption working capacity under dynamic mixed-gas conditions with CO2 concentrations similar to those in flue gases and ambient air.

  10. Batch leaching tests of motherboards to assess environmental contamination by bromine, platinum group elements and other selected heavy metals.

    Science.gov (United States)

    Almeida, César; Grosselli, Melina; González, Patricia; Martínez, Dante; Gil, Raúl

    2016-02-01

    In this study, a batch leaching test was executed to evaluate the toxicity associated with chemicals contained in motherboards. The leaching solutions used were distilled water, nitric acid, acetic acid and synthetic acid rain solution. A total of 21 elements including Ag, As, Au, Br, Cd, Co, Cr, Cu, Hf, Ir, Mn, Ni, Os, Pb, Pd, Pt, Rd, Rh, Se, U and Zn were analyzed. In this study, the pH values of all the leachates fell within the range of 2.33-4.88. The highest concentrations of metals were obtained from the acid rain solution, whilst the maximum value of bromine was achieved with solution of acetic acid. Appreciable concentrations of platinum group elements were detected with concentrations around 3.45, 1.43, 1.21 and 22.19 µg L(-1) for Ir, Pd, Pt and Rh, respectively. The different leaching of the motherboards revealed the predominant presence of the toxic substances in the leached from the e-waste.

  11. Benchmark Calculations of Energetic Properties of Groups 4 and 6 Transition Metal Oxide Nanoclusters Including Comparison to Density Functional Theory

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Zongtang; Both, Johan; Li, Shenggang; Yue, Shuwen; Aprà, Edoardo; Keçeli, Murat; Wagner, Albert F.; Dixon, David A.

    2016-08-09

    The heats of formation and the normalized clustering energies (NCEs) for the group 4 and group 6 transition metal oxide (TMO) trimers and tetramers have been calculated by the Feller-Peterson-Dixon (FPD) method. The heats of formation predicted by the FPD method do not differ much from those previously derived from the NCEs at the CCSD(T)/aT level except for the CrO3 nanoclusters. New and improved heats of formation for Cr3O9 and Cr4O12 were obtained using PW91 orbitals instead of Hartree-Fock (HF) orbitals. Diffuse functions are necessary to predict accurate heats of formation. The fluoride affinities (FAs) are calculated with the CCSD(T) method. The relative energies (REs) of different isomers, NCEs, electron affinities (EAs), and FAs of (MO2)n ( M = Ti, Zr, Hf, n = 1 – 4 ) and (MO3)n ( M = Cr, Mo, W, n = 1 – 3) clusters have been benchmarked with 55 exchange-correlation DFT functionals including both pure and hybrid types. The absolute errors of the DFT results are mostly less than ±10 kcal/mol for the NCEs and the EAs, and less than ±15 kcal/mol for the FAs. Hybrid functionals usually perform better than the pure functionals for the REs and NCEs. The performance of the two types of functionals in predicting EAs and FAs is comparable. The B1B95 and PBE1PBE functionals provide reliable energetic properties for most isomers. Long range corrected pure functionals usually give poor FAs. The standard deviation of the absolute error is always close to the mean errors and the probability distributions of the DFT errors are often not Gaussian (normal). The breadth of the distribution of errors and the maximum probability are dependent on the energy property and the isomer.

  12. Optical Identification of Cepheids in 19 Host Galaxies of Type Ia Supernovae and NGC 4258 with the Hubble Space Telescope

    CERN Document Server

    Hoffmann, Samantha L; Riess, Adam G; Yuan, Wenlong; Casertano, Stefano; Filippenko, Alexei V; Tucker, Brad E; Chornock, Ryan; Silverman, Jeffrey M; Welch, Douglas L; Goobar, Ariel; Amanullah, Rahman

    2016-01-01

    We present results of an optical search for Cepheid variable stars using the Hubble Space Telescope (HST) in 19 hosts of Type Ia supernovae (SNe Ia) and the maser-host galaxy NGC 4258, conducted as part of the SH0ES project (Supernovae and H0 for the Equation of State of dark energy). The targets include 9 newly imaged SN Ia hosts using a novel strategy based on a long-pass filter that minimizes the number of HST orbits required to detect and accurately determine Cepheid properties. We carried out a homogeneous reduction and analysis of all observations, including new universal variability searches in all SN Ia hosts, that yielded a total of 2200 variables with well-defined selection criteria -- the largest such sample identified outside the Local Group. These objects are used in a companion paper to determine the local value of H0 with a total uncertainty of 2.4%.

  13. Bridging the gap between ionic liquids and molten salts: group 1 metal salts of the bistriflamide anion in the gas phase.

    Science.gov (United States)

    Leal, João P; da Piedade, Manuel E Minas; Canongia Lopes, José N; Tomaszowska, Alina A; Esperança, José M S S; Rebelo, Luís Paulo N; Seddon, Kenneth R

    2009-03-19

    Fourier transform ion cyclotron resonance mass spectrometry experiments showed that liquid Group 1 metal salts of the bistriflamide anion undergoing reduced-pressure distillation exhibit a remarkable behavior that is in transition between that of the vapor-liquid equilibrium characteristics of aprotic ionic liquids and that of the Group 1 metal halides: the unperturbed vapors resemble those of aprotic ionic liquids, in the sense that they are essentially composed of discrete ion pairs. However, the formation of large aggregates through a succession of ion-molecule reactions is closer to what might be expected for Group 1 metal halides. Similar experiments were also carried out with bis{(trifluoromethyl)sulfonyl}amine to investigate the effect of H(+), which despite being the smallest Group 1 cation, is generally regarded as a nonmetal species. In this case, instead of the complex ion-molecule reaction pattern found for the vapors of Group 1 metal salts, an equilibrium similar to those observed for aprotic ionic liquids was observed.

  14. Neuropsychiatric manifestations of alkali metal deficiency and excess

    Energy Technology Data Exchange (ETDEWEB)

    Yung, C.Y.

    1984-01-01

    The alkali metals from the Group IA of the periodic table (lithium, sodium, potassium, rubidium, cesium and francium) are reviewed. The neuropsychiatric aspects of alkali metal deficiencies and excesses (intoxications) are described. Emphasis was placed on lithium due to its clinical uses. The signs and symptoms of these conditions are characterized by features of an organic brain syndrome with delirium and encephalopathy prevailing. There are no clinically distinctive features that could be reliably used for diagnoses. Sodium and potassium are two essential alkali metals in man. Lithium is used as therapeutic agent in bipolar affective disorders. Rubidium has been investigated for its antidepressant effect in a group of psychiatric disorders. Cesium is under laboratory investigation for its role in carcinogenesis and in depressive illness. Very little is known of francium due to its great instability for experimental study.

  15. The flotation of Roşia Poieni copper ore in column machine, with non-polar oils addition

    Directory of Open Access Journals (Sweden)

    Ciocani V.

    2005-11-01

    Full Text Available The most important natural resource of copper in Romania is the ore deposit of Roşia Poieni. At present, the utilization of Roşia Poieni poorphyry copper ore is possible by extraction in quarry of the mass ore and mineral processing into a technological flux with modest results for the value of metal recovery in concentrate 70-72 % and an average contents of 16,5 % Cu. Our researches were directed to studies regarding test and utilisation of special procedure of flotation – addition of the non-polar oil – applied to advanced grinding ore with column type machines.

  16. Probing Interaction Between Platinum Group Metal (PGM) and Non-PGM Support Through Surface Characterization and Device Performance

    Science.gov (United States)

    Saha, Shibely

    High cost and limited abundance of Platinum (Pt) have hindered effective commercialization of Proton Exchange Membrane Fuel Cell and Electrolyzer. Efforts have been undertaken to reduce precious group metal (PGM) requirement for these devices without compromising the activity of the catalyst by using transition metal carbides (TMC) as non-PGM support thanks to their similar electronic and geometric structures as Pt. In this work Mo2C was selected as non-PGM support and Pt was used as the PGM of interest. We hypothesize that the hollow nanotube morphology of Mo2C support combined with Pt nano particles deposited on it via atomic layer deposition (ALD) technique would allow increased interaction between them which may increase the activity of Pt and Mo2C as well as maximize the Pt active surface area. Specifically, a rotary ALD equipment was used to grow Pt particles from atomic level to 2--3 nanometers by simply adjusting number of ALD cycles in order to probe the interaction between the deposited Pt nanoparticles and Mo2C nanotube support. Interaction between the Pt and Mo2 C was analyzed via surface characterization and electrochemical characterization. Interaction between Pt and Mo2C arises due to the lattice mismatch between Pt and Mo2C as well as electron migration between them. Lattice spacing analysis using high resolution transmission electron microscopy (HRTEM) images, combined with Pt binding energy shift in XPS results, clearly showed strong bonding between Pt nanoparticles and the Mo2C nanotube support in all the resultant Pt/Mo2C samples. We postulate that this strong interaction is responsible for the significantly enhanced durability observed in our constant potential electrolysis (CPE) and accelerated degradation testing (ADT). Of the three samples from different ALD cycles (15, 50 and 100), Mo2C nanotubes modified by 50 (1.07 wt% Pt loading) and 100 cycles (4.4 wt% Pt) of Pt deposition, showed higher HER and HOR activity per Pt mass than commercial

  17. CfA Nearby Supernova Ia Light Curves

    Science.gov (United States)

    Hicken, Malcolm; Berlind, P.; Blondin, S.; Calkins, M.; Challis, P.; Esquerdo, G.; Everett, M.; Fernandez, J.; Jha, S.; Kirshner, R. P.; Latham, D.; Modjaz, M.; Rest, A.; Wood-Vasey, M.

    2007-12-01

    Type Ia supernovae (SN Ia) are central in measuring the accelerated expansion of the Universe and the properties of the underlying dark energy. Nearby SN Ia are compared with distant ones to establish the history of cosmic expansion. In fact, current efforts in SN Ia cosmology are constrained by the limited number of well-observed nearby SN Ia. A significantly improved sample of nearby SN Ia, fully covering the space of Ia properties, is needed to maximize the utility of high-redshift SN Ia. Our ongoing project at the CfA has collected such a set of 170 SN Ia. We have used the FLWO 1.2m telescope. About half of our objects were observed in UBVRI with the 4Shooter camera and have an average of 10 epochs each while the other half was taken in UBVr'i' with the Keplercam instrument and have an average of 17 epochs each. We have now reduced this sample of over 25000 images and present calibrated light curves of these SN Ia along with an analysis of their properties. The CfA Supernova program is supported in part by the National Science Foundation through grant AST-0606772 to Harvard University.

  18. Group 1 and group 2 metal complexes supported by a bidentate bulky iminopyrrolyl ligand: synthesis, structural diversity, and ε-caprolactone polymerization study.

    Science.gov (United States)

    Kottalanka, Ravi K; Harinath, A; Rej, Supriya; Panda, Tarun K

    2015-12-14

    We report here a series of alkali and alkaline earth metal complexes, each with a bulky iminopyrrolyl ligand [2-(Ph3CN=CH)C4H3NH] (1-H) moiety in their coordination sphere, synthesized using either alkane elimination or silylamine elimination methods or the salt metathesis route. The lithium salt of molecular composition [Li(2-(Ph3CN=CH)C4H3N)(THF)2] (2) was prepared using the alkane elimination method, and the silylamine elimination method was used to synthesize the dimeric sodium and tetra-nuclear potassium salts of composition [(2-(Ph3CN=CH)C4H3N)Na(THF)]2 (3) and [(2-(Ph3CN=CH)C4H3N)K(THF)0.5]4 (4) respectively. The magnesium complex of composition [(THF)2Mg(CH2Ph){2-(Ph3CN=CH)C4H3N}] (5) was synthesized through the alkane elimination method, in which [Mg(CH2Ph)2(OEt2)2] was treated with the bulky iminopyrrole ligand 1-H in 1 : 1 molar ratio, whereas the bis(iminopyrrolyl)magnesium complex [(THF)2Mg{2-(Ph3CN=CH)C4H3N}2] (6) was isolated using the salt metathesis route. The heavier alkaline earth metal complexes of the general formula {(THF)nM(2-(Ph3CN=CH)C4H3N)2} [M = Ca (7), Sr (8), and n = 2; M = Ba (9), n = 3] were prepared in pure form using two synthetic methods: in the first method, the bulky iminopyrrole ligand 1-H was directly treated with the alkaline earth metal precursor [M{N(SiMe3)2}2(THF)n] (where M = Ca, Sr and Ba) in 2 : 1 molar ratio in THF solvent at ambient temperature. The complexes 7-9 were also obtained using the salt metathesis reaction, which involves the treatment of the potassium salt (4) with the corresponding metal diiodides MI2 (M = Ca, Sr and Ba) in 2 : 1 molar ratio in THF solvent. The molecular structures of all the metal complexes (1-H, 2-9) in the solid state were established through single-crystal X-ray diffraction analysis. The complexes 5-9 were tested as catalysts for the ring-opening polymerization of ε-caprolactone. High activity was observed in the heavier alkaline earth metal complexes 7-9, with a very

  19. Chiral Sulfur Functional Groups as Definers of the Chirality at the Metal in Ir- and Rh-Half Sandwich Complexes: A Combined CD-X-ray Study.

    Science.gov (United States)

    Sierra, Miguel A; de la Torre, Maria C; Fernandez de la Pradilla, Roberto; Viso, Alma; Frutos, Maria; Avello, Marta G; Velado, Marina; Gornitzka, Heinz; Hemmert, Catherine

    2017-07-27

    Mesoionic carbenes (MIC) derived from triazolium salts containing chiral sulfoxide or sulfoximine functional groups lead to enantiopure chiral-at-metal Ir(III) and Rh(III) half-sandwich complexes, through the sequence MIC complexation-C-H aromatic activation. The process is efficient and totally diastereoselective in the formation of enantiopure five membered metallacycles. The use of the enantiomers of the sulfur chiral groups allows to prepare complexes having opposite configurations at the metal. Complete retention of the configuration at the metal center is observed during the formation of cationic Ir(III) complexes and upon insertion of alkynes into the Ir(III)-C bond, as demonstrated by a combined Circular Dichroism (CD)-X-ray study. These results point to vicinal assisted SN-like processes. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. The Regularities of Phase and Structural Transformation in Binary Titanium Alloys with Metals of IV—VIII Groups of the Periodic Table

    National Research Council Canada - National Science Library

    Dobromyslov, A V

    2008-01-01

    Martensitic β→α′(α″) and β→ω transformation in a series of Ti-base alloys with transition metals of groups IV-VIII have been investigated using the techniques of X-ray diffraction, optical and transmission electron microscopy...

  1. Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

    KAUST Repository

    Wang, Xiufang

    2017-01-01

    A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

  2. Spectroscopy of twelve Type Ia supernovae at intermediate redshift

    CERN Document Server

    Balland, C; Pain, R; Walton, N A; Amanullah, R; Astier, Pierre; Ellis, Richard S; Fabbro, S; Goobar, A; Hardin, D; Hook, I M; Irwin, M J; McMahon, R M; Mendez, J M; Ruiz-Lapuente, P; Sainton, G; Schahmaneche, K; Stanishev, V

    2005-01-01

    We present spectra of twelve Type Ia supernovae obtained in 1999 at the William Herschel Telescope and the Nordic Optical Telescope during a search for Type Ia supernovae (SN Ia) at intermediate redshift. The spectra range from z=0.178 to z=0.493, including five high signal-to-noise ratio SN Ia spectra in the still largely unexplored range 0.15 < z < 0.3. Most of the spectra were obtained before or around restframe B-band maximum light. None of them shows the peculiar spectral features found in low-redshift over- or under-luminous SN Ia. Expansion velocities of characteristic spectral absorption features such as SiII at 6355 angs., SII at 5640 angs. and CaII at 3945 angs. are found consistent with their low-z SN Ia counterparts.

  3. The chemistry of the most metal-rich damped Lyman $\\alpha$ systems at z$\\sim2$ II. Context with the Local Group

    CERN Document Server

    Berg, Trystyn A M; Prochaska, J Xavier; Venn, Kim A; Dessauges-Zavadsky, Miroslava

    2015-01-01

    Using our sample of the most metal-rich damped Lyman $\\alpha$ systems (DLAs) at z$\\sim2$, and two literature compilations of chemical abundances in 341 DLAs and 2818 stars, we present an analysis of the chemical composition of DLAs in the context of the Local Group. The metal-rich sample of DLAs at z$\\sim2$ probes metallicities as high as the Galactic disc and the most metal-rich dwarf spheroidals (dSphs), permitting an analysis of many elements typically observed in DLAs (Fe, Zn, Cr, Mn, Si, and S) in comparison to stellar abundances observed in the Galaxy and its satellites (in particular dSphs). Our main conclusions are: (1) non-solar [Zn/Fe] abundances in metal-poor Galactic stars and in dSphs over the full metallicity range probed by DLAs, suggest that Zn is not a simple proxy for Fe in DLAs and therefore not a suitable indicator of dust depletion. After correcting for dust depletion, the majority of DLAs have subsolar [Zn/Fe] similar to dSphs; (2) at [Fe/H]$\\sim-0.5$, a constant [Mn/Fe]$\\sim-0.5$ and ne...

  4. Evaluation of status of trace and toxic metals in biological samples (scalp hair, blood, and urine) of normal and anemic children of two age groups.

    Science.gov (United States)

    Shah, Faheem; Kazi, Tasneem Gul; Afridi, Hassan Imran; Kazi, Naveed; Baig, Jameel Ahmed; Shah, Abdul Qadir; Khan, Sumaira; Kolachi, Nida Fatima; Wadhwa, Sham Kumar

    2011-06-01

    Anemia affects a substantial portion of the world's population, provoking severe health problems as well as important economic losses to the region in which this condition is found. This study was designed to compare the levels of essential trace and toxic elements in scalp hair, blood, and urine samples of anemic children (n = 132) with age range 1-5 and 6-10 years of both genders. For a comparative study, 134 non-anemic age- and sex-matched children as control subjects, residing in the same city, were selected. The metals in the biological samples were measured by flame atomic absorption spectrophotometry/electrothermal atomic absorption spectrometry prior to microwave-assisted acid digestion. The proposed method was validated using certified reference samples of hair, blood, and urine. The results indicated significantly lower levels of iron, copper, and zinc in the biological samples as compared to the control children of both genders (p = 0.01-0.008). The mean values of lead and cadmium were significantly high in all three biological samples of anemic children as compared to non-anemic children of both age groups (p = 0.005-0.001). The ratios of essential metal to toxic metals in the biological samples of anemic children of both age groups were significantly lower than that of controls. Deficiency of essential trace metals and high level of toxic metals may play a role in the development of anemia in the subjects under study.

  5. Constraining Cosmic Evolution of Type Ia Supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Foley, Ryan J.; Filippenko, Alexei V.; Aguilera, C.; Becker, A.C.; Blondin, S.; Challis, P.; Clocchiatti, A.; Covarrubias, R.; Davis, T.M.; Garnavich, P.M.; Jha, S.; Kirshner, R.P.; Krisciunas, K.; Leibundgut, B.; Li, W.; Matheson, T.; Miceli, A.; Miknaitis, G.; Pignata, G.; Rest, A.; Riess, A.G.; /UC, Berkeley, Astron. Dept. /Cerro-Tololo InterAmerican Obs. /Washington U., Seattle, Astron. Dept. /Harvard-Smithsonian Ctr. Astrophys. /Chile U., Catolica /Bohr Inst. /Notre Dame U. /KIPAC, Menlo Park /Texas A-M /European Southern Observ. /NOAO, Tucson /Fermilab /Chile U., Santiago /Harvard U., Phys. Dept. /Baltimore, Space Telescope Sci. /Johns Hopkins U. /Res. Sch. Astron. Astrophys., Weston Creek /Stockholm U. /Hawaii U. /Illinois U., Urbana, Astron. Dept.

    2008-02-13

    We present the first large-scale effort of creating composite spectra of high-redshift type Ia supernovae (SNe Ia) and comparing them to low-redshift counterparts. Through the ESSENCE project, we have obtained 107 spectra of 88 high-redshift SNe Ia with excellent light-curve information. In addition, we have obtained 397 spectra of low-redshift SNe through a multiple-decade effort at Lick and Keck Observatories, and we have used 45 ultraviolet spectra obtained by HST/IUE. The low-redshift spectra act as a control sample when comparing to the ESSENCE spectra. In all instances, the ESSENCE and Lick composite spectra appear very similar. The addition of galaxy light to the Lick composite spectra allows a nearly perfect match of the overall spectral-energy distribution with the ESSENCE composite spectra, indicating that the high-redshift SNe are more contaminated with host-galaxy light than their low-redshift counterparts. This is caused by observing objects at all redshifts with similar slit widths, which corresponds to different projected distances. After correcting for the galaxy-light contamination, subtle differences in the spectra remain. We have estimated the systematic errors when using current spectral templates for K-corrections to be {approx}0.02 mag. The variance in the composite spectra give an estimate of the intrinsic variance in low-redshift maximum-light SN spectra of {approx}3% in the optical and growing toward the ultraviolet. The difference between the maximum-light low and high-redshift spectra constrain SN evolution between our samples to be < 10% in the rest-frame optical.

  6. Type Ia Supernovae and the discovery of the Cosmic Acceleration

    CERN Document Server

    Clocchiatti, Alejandro

    2011-01-01

    I present a review of the research and analysis paths that converged to make Type Ia SNe the most mature cosmological distance estimator of the present time. The narrative starts with the first works in the early decades of the 20th century and finishes with the more recent results. The review was written by a member of the High Z Supernova Search Team, the international group of astronomers that discovered Cosmic Acceleration in 1998. This result, confirmed by the Supernova Cosmology Project in 1999, received an impressive string of recognition culminating with the current Nobel prize in Physics. The review is presented thinking of physicists with a strong interest in Cosmology, who might have pondered why was that, after decades of not being able to agree upon the rate of cosmic expansion, astronomers were so quick to concur on cosmic acceleration.

  7. The Implementation of IAS 16 and IAS 41 at Andrew Peller Limited

    Science.gov (United States)

    Lapointe-Antunes, Pascale; Moore, James

    2013-01-01

    This case asks students to play the role of Doug Grodeckie, Manager of Financial Reporting at Andrew Peller Limited (APL). Doug was asked to prepare a report analyzing Andrew Peller Limited's current tangible long-lived assets disclosures and making recommendations on how best to comply with International Accounting Standard (IAS) 16 Property,…

  8. Radiogenic p-isotopes from type Ia supernova, nuclear physics uncertainties, and galactic chemical evolution compared with values in primitive meteorites

    Energy Technology Data Exchange (ETDEWEB)

    Travaglio, C. [INAF—Astrophysical Observatory Turin, Strada Osservatorio 20, I-10025 Pino Torinese (Turin) (Italy); Gallino, R. [B2FH Association, I-10025 Pino Torinese (Turin) (Italy); Rauscher, T. [Centre for Astrophysics Research, School of Physics, Astronomy and Mathematics, University of Hertfordshire, Hatfield AL10 9AB (United Kingdom); Dauphas, N. [Origins Laboratory, Department of the Geophysical Sciences and Enrico Fermi Institute, The University of Chicago, Chicago, IL 60637 (United States); Röpke, F. K. [Universität Würzburg, Am Hubland, D-97074 Würzburg (Germany); Hillebrandt, W., E-mail: travaglio@oato.inaf.it, E-mail: claudia.travaglio@b2fh.org [Max-Planck-Institut für Astrophysik, Karl-Schwarzschild-Str. 1, D-85748 Garching bei München (Germany)

    2014-11-10

    The nucleosynthesis of proton-rich isotopes is calculated for multi-dimensional Chandrasekhar-mass models of Type Ia supernovae (SNe Ia) with different metallicities. The predicted abundances of the short-lived radioactive isotopes {sup 92}Nb, {sup 97,} {sup 98}Tc, and {sup 146}Sm are given in this framework. The abundance seeds are obtained by calculating s-process nucleosynthesis in the material accreted onto a carbon-oxygen white dwarf from a binary companion. A fine grid of s-seeds at different metallicities and {sup 13}C-pocket efficiencies is considered. A galactic chemical evolution model is used to predict the contribution of SN Ia to the solar system p-nuclei composition measured in meteorites. Nuclear physics uncertainties are critical to determine the role of SNe Ia in the production of {sup 92}Nb and {sup 146}Sm. We find that, if standard Chandrasekhar-mass SNe Ia are at least 50% of all SN Ia, they are strong candidates for reproducing the radiogenic p-process signature observed in meteorites.

  9. Search for Type Ia supernova NUV-optical subclasses

    Science.gov (United States)

    Cinabro, David; Scolnic, Daniel; Kessler, Richard; Li, Ashley; Miller, Jake

    2017-04-01

    In response to a recently reported observation of evidence for two classes of Type Ia supernovae (SNe Ia) distinguished by their brightness in the rest-frame near-ultraviolet (NUV), we search for the phenomenon in publicly available light-curve data. We use the SNANA supernova analysis package to simulate SN Ia light curves in the Sloan Digital Sky Survey (SDSS) Supernova Search and the Supernova Legacy Survey (SNLS) with a model of two distinct ultraviolet classes of SNe Ia and a conventional model with a single broad distribution of SN-Ia ultraviolet brightnesses. We compare simulated distributions of rest-frame colours with these two models to those observed in 158 SNe Ia in the SDSS and SNLS data. The SNLS sample of 99 SNe Ia is in clearly better agreement with a model with one class of SN Ia light curves and shows no evidence for distinct NUV sub-classes. The SDSS sample of 59 SNe Ia with poorer colour resolution does not distinguish between the two models.

  10. Search For Type Ia Supernova NUV-Optical Subclasses

    CERN Document Server

    Cinabro, David; Kessler, Richard; Li, Ashley; Miller, Jake

    2016-01-01

    In response to a recently reported observation of evidence for two classes of Type Ia Supernovae (SNe Ia) distinguished by their brightness in the rest-frame near ultraviolet (NUV), we search for the phenomenon in publicly available light-curve data. We use the SNANA supernova analysis package to simulate SN Ia-light curves in the Sloan Digital Sky Survey Supernova Search (SDSS) and the Supernova Legacy Survey (SNLS) with a model of two distinct ultraviolet classes of SNe Ia and a conventional model with a single broad distribution of SN-Ia ultraviolet brightnesses. We compare simulated distributions of rest-frame colors with these two models to those observed in 158 SNe Ia in the SDSS and SNLS data. The SNLS sample of 99 SNe Ia is in clearly better agreement with a model with one class of SN Ia light curves and shows no evidence for distinct NUV sub-classes. The SDSS sample of 59 SNe Ia with poorer color resolution does not distinguish between the two models.

  11. SNe Ia: Can Chandrasekhar Mass Explosions Reproduce the Observed Zoo?

    CERN Document Server

    Baron, E

    2014-01-01

    The question of the nature of the progenitor of Type Ia supernovae (SNe Ia) is important both for our detailed understanding of stellar evolution and for their use as cosmological probes of the dark energy. Much of the basic features of SNe Ia can be understood directly from the nuclear physics, a fact which Gerry would have appreciated. We present an overview of the current observational and theoretical situation and show that it not incompatible with most SNe Ia being the results of thermonuclear explosions near the Chandrasekhar mass.

  12. Near-Infrared Properties of Type Ia Supernovae

    Science.gov (United States)

    Phillips, M. M.

    2012-02-01

    The photometric properties of Type Ia supernovae (SNe Ia) in the near-infrared as garnered from observations made over the last 30 years are reviewed. During this period, light curves for more than 120 nearby SNe Ia have been published, revealing considerable homogeneity but also some fascinating differences. These data have confirmed that, for all but the fastest declining objects, SNe Ia are essentially perfect standard candles in the near-infrared, displaying only a slight dependence of peak luminosity on decline rate and color.

  13. Ages of Type Ia Supernovae Over Cosmic Time

    CERN Document Server

    Childress, Michael J; Zahid, H Jabran

    2014-01-01

    We derive empirical models for galaxy mass assembly histories, and convolve these with theoretical delay time distribution (DTD) models for Type Ia supernovae (SNe Ia) to derive the distribution of progenitor ages for all SNe Ia occurring at a given epoch of cosmic time. In actively star-forming galaxies, the progression of the star formation rate is shallower than a $t^{-1}$ SN Ia DTD, so mean SN Ia ages peak at the DTD peak in all star-forming galaxies at all epochs of cosmic history. In passive galaxies which have ceased star formation through some quenching process, the SN Ia age distribution peaks at the quenching epoch, which in passive galaxies evolves in redshift to track the past epoch of major star formation. Our models reproduce the SN Ia rate evolution in redshift, the relationship between SN Ia stretch and host mass, and the distribution of SN Ia host masses in a manner qualitatively consistent with observations. Our model naturally predicts that low-mass galaxies tend to be actively star-forming...

  14. Analytical Expressions For Light-curves of Supernovae Type Ia

    CERN Document Server

    Dado, Shlomo

    2013-01-01

    A simple analytical model is used to derive the main properties of supernovae type Ia (SNe Ia), which are produced by the thermonuclear explosion of accreting C-O white dwarfs that cross the Chandrasekhar mass limit. The few underlying physical assumptions of the model yield analytical expressions that reproduce quite well the observed bolometric light-curves of SNe Ia and the empirical brighter-slower and brighter-bluer relationships that were used to standardize SNe Ia for their use as distance indicators, which led to the discovery of the accelerating expansion of the universe.

  15. Synthesis and Molecular Structure of A Bimetallic Salen Complex Containing Zn and La: A Disordered Nitrate Group Dancing between Two Metal Centers

    Institute of Scientific and Technical Information of China (English)

    Leon Dyers Jr; Donald Van Derveer; Xiu R Bu

    2005-01-01

    A new bimetallic complex containing Zn and La was prepared from a salen ligand possessing methoxyl groups at the 3, 3'-positions. The structural feature is that one of nitrate groups is disordered and displaced between two metal centers. Crystal system: Triclinic space group:P-1, Z=2. a=0.82714(17) nm, b=1.3484(3) (1) nm, and c=1.3898(3) (1) nm, α=79.89(3)°, β=76.67(3)°, and γ=72.43(3)°. V=1.428.6(5) nm3, Dx=1.812 g·cm-3. (Δρ)max=1.510×10-3 enm3, (Δρ)min=-1.503×10-3 enm3. Accordingly, two water molecules occupy the metal centers in the apical positions via the syn-geometry.

  16. Evidence for a metal-thiolate intermediate in alkyl group transfer from epoxypropane to coenzyme M and cooperative metal ion binding in epoxyalkane:CoM transferase.

    Science.gov (United States)

    Boyd, Jeffrey M; Ensign, Scott A

    2005-10-04

    Epoxyalkane:coenzyme M transferase (EaCoMT) catalyzes the nucleophilic addition of coenzyme M (CoM, 2-mercaptoethanesulfonic acid) to epoxypropane forming 2-hydroxypropyl-CoM. The biochemical properties of EaCoMT suggest that the enzyme belongs to the family of alkyltransferase enzymes for which Zn plays a role in activating an organic thiol substrate for nucleophilic attack on an alkyl-donating substrate. The enzyme has a hexameric (alpha(6)) structure with one zinc atom per subunit. In the present work M(2+) binding and the role of Zn(2+) in EaCoMT have been established through a combination of biochemical, calorimetric, and spectroscopic techniques. A variety of metal ions, including Zn(2+), Co(2+), Cd(2+), and Ni(2+), were capable of activating a Zn-deficient "apo" form of EaCoMT, affording enzymes with various levels of activity. Titration of Co(2+) into apo-EaCoMT resulted in UV-visible spectroscopic changes consistent with the formation of a tetrahedral Co(2+) binding site, with coordination of bound Co(2+) to two thiolate ligands. Quantification of UV-visible spectral changes upon Co(2+) titration into apo-EaCoMT demonstrated that EaCoMT binds Co(2+) cooperatively at six interacting sites. Isothermal titration calorimetric studies of Co(2+) and Zn(2+) binding to EaCoMT also showed cooperativity for metal ion binding among six sites. The addition of CoM to Co(2+)-substituted EaCoMT resulted in UV-visible spectral changes indicative of formation of a new thiol-Co(2+) bond. Co(2+)-substituted EaCoMT exhibited a unique Co(2+) EPR spectrum, and this spectrum was perturbed significantly upon addition of CoM. The presence of a divalent metal ion was required for the release of protons from CoM upon binding to EaCoMT, with Zn(2+), Co(2+), and Cd(2+) each facilitating proton release. The divalent metal ion of EaCoMT is proposed to play a key role in the coordination and deprotonation of CoM, possibly through formation of a metal-thiolate that is activated for attack

  17. An Approach to Information Architecture(IA)%信息构建(Information Architecture,IA)探析

    Institute of Scientific and Technical Information of China (English)

    荣毅虹; 梁战平

    2003-01-01

    本文以Internet发展为背景,分前网络时期和网络时期两个阶段对IA进行了考察,提出了狭义IA(书本IA、网站IA)和广义IA,并对其含义、内容和作用进行了探讨和论述.

  18. The Distant Type Ia Supernova Rate

    Science.gov (United States)

    Pain, R.; Fabbro, S.; Sullivan, M.; Ellis, R. S.; Aldering, G.; Astier, P.; Deustua, S. E.; Fruchter, A. S.; Goldhaber, G.; Goobar, A.; Groom, D. E.; Hardin, D.; Hook, I. M.; Howell, D. A.; Irwin, M. J.; Kim, A. G.; Kim, M. Y.; Knop, R. A.; Lee, J. C.; Perlmutter, S.; Ruiz-Lapuente, P.; Schahmaneche, K.; Schaefer, B.; Walton, N. A.

    2002-05-28

    We present a measurement of the rate of distant Type Ia supernovae derived using 4 large subsets of data from the Supernova Cosmology Project. Within this fiducial sample, which surveyed about 12 square degrees, thirty-eight supernovae were detected at redshifts 0.25--0.85. In a spatially flat cosmological model consistent with the results obtained by the Supernova Cosmology Project, we derive a rest-frame Type Ia supernova rate at a mean red shift z {approx_equal} 0.55 of 1.53 {sub -0.25}{sub -0.31}{sup 0.28}{sup 0.32} x 10{sup -4} h{sup 3} Mpc{sup -3} yr{sup -1} or 0.58{sub -0.09}{sub -0.09}{sup +0.10}{sup +0.10} h{sup 2} SNu(1 SNu = 1 supernova per century per 10{sup 10} L{sub B}sun), where the first uncertainty is statistical and the second includes systematic effects. The dependence of the rate on the assumed cosmological parameters is studied and the redshift dependence of the rate per unit comoving volume is contrasted with local estimates in the context of possible cosmic star formation histories and progenitor models.

  19. Neutronization and Energetics of Type Ia Supernovae

    Science.gov (United States)

    Seitenzahl, I. R.; Peng, F.; Townsley, D. M.; Calder, A. C.

    2005-12-01

    Type Ia supernovae are critical distance indicators for cosmology. The lightcurves are powered by the decay of radioactive nickel and cobalt isotopes. The amount of nickel produced in the supernova event depends on the detailed trajectories of the hydrodynamic evolution of the explosion. A key ingredient in numerical simulations of the deflagration phase of Type Ia supernovae is the nuclear flame model. A realistic model must accurately describe the nuclear energy released, the timescale on which the energy release occurs, and the changes in composition that constitute the burning. Once the flame has passed, the hot products of the burning constitute a nuclear statistical equilibrium (NSE) abundance distribution. Since the NSE abundances, and hence derived quantities such as the mean binding energy per nucleon, are functions of the density, temperature and electron fraction, it is important to continuously adjust the NSE state of the ashes during the hydrodynamic evolution of the star. Weak interactions influence the energetics and evolution via the change in degeneracy pressure due to captured electrons, the energy losses carried away by neutrinos, and the readjustment of the NSE state following a change in the electron fraction. We have developed a NSE-based model, which implements these features for a hydrodynamical evolution code.

  20. Dark matter ignition of type Ia supernovae

    CERN Document Server

    Bramante, Joseph

    2015-01-01

    Recent studies of low redshift type Ia supernovae (SNIa) indicate that half explode from less than Chandrasekhar mass white dwarfs, implying ignition must proceed from something besides the canonical criticality of Chandrasekhar mass SNIa progenitors. We show that $0.1-10$ PeV mass asymmetric dark matter, with imminently detectable nucleon scattering interactions, can accumulate to the point of self-gravitation in a white dwarf and collapse, shedding gravitational potential energy by scattering off nuclei, thereby heating the white dwarf and igniting the flame front that precedes SNIa. We combine data on SNIa masses with data on the ages of SNIa-adjacent stars. This combination reveals a $ 3 \\sigma$ inverse correlation between SNIa masses and ignition ages, which could result from increased capture of dark matter in 1.4 versus 1.1 solar mass white dwarfs. Future studies of SNIa in galactic centers will provide additional tests of dark-matter-induced type Ia ignition. Remarkably, both bosonic and fermionic SNI...

  1. The distant Type Ia supernova rate

    CERN Document Server

    Pain, R; Sullivan, M; Ellis, Richard S; Aldering, G; Astier, Pierre; Duestua, S E; Fruchter, A S; Goldhaber, Gerson; Goobar, A; Groom, D E; Hardin, D; Hook, I M; Howell, D A; Irwin, M J; Kim, A G; Kim, M Y; Knop, R A; Lee, J C; Lidman, C E; McMahon, R G; Nugent, P; Panagia, N; Pennypacker, C R; Perlmutter, S; Ruiz-Lapuente, P; Schahmaneche, K; Schaefer, B; Walton, N A

    2001-01-01

    We present a measurement of the rate of distant Type Ia supernovae derived using 4 large subsets of data from the Supernova Cosmology Project. Within this fiducial sample, which surveyed about 12 square degrees, thirty-eight supernovae were detected at redshifts 0.25--0.85. In a spatially-flat cosmological model consistent with the results obtained by the Supernova Cosmology Project, we derive a rest-frame Type Ia supernova rate at a mean redshift $z\\simeq0.55$ of $1.53 {^{+0.28}_{-0.25}} {^{+0.32}_{-0.31}} 10^{-4} h^3 {\\rm Mpc}^{-3} {\\rm yr}^{-1}$ or $0.58 {^{+0.10}_{-0.09}} {^{+0.10}_{-0.09}} h^2 {\\rm SNu}$ (1 SNu = 1 supernova per century per $10^{10}$\\Lbsun), where the first uncertainty is statistical and the second includes systematic effects. The dependence of the rate on the assumed cosmological parameters is studied and the redshift dependence of the rate per unit comoving volume is contrasted with local estimates in the context of possible cosmic star formation histories and progenitor models.

  2. THE GEOMORPHOSITES OF ROŞIA MONTANĂ

    Directory of Open Access Journals (Sweden)

    Maria-Adina Jurj

    2016-06-01

    Full Text Available The geomorphosites of Roșia Montană. The volcanic relief of the Roșia Montană mining area is characterised by a significant number of geomorphosites, represented especially by necks and dykes, such as: Cârnic, Orlea, Jig-Văidoaia, Lety etc. Another category of geomorphosites is represented by those with hydrographic features, namely the ponds created for mining purposes since Roman period. We identified a number of 14 geomorphosites; 9 of these are the results of the Neogene volcanic activity, and 5 are the ponds which appeared as an indirect consequence of the volcanic specific of the area. The geomorphosites created by the volcanic activity have also a significant archaeological, historical and cultural value, due to the valuable mining galleries and another evidences of this ancient activity. Among all the geomorphosites of the area, the most important one is Cârnic Massif which has a complex system of underground mining galleries, some of them belonging to Roman period. We consider that capitalization through touristic activities of these landforms is the best utilization in terms of ecological, cultural and economic perspectives.

  3. Tamm plasmon-polariton with negative group velocity induced by a negative index meta-material capping layer at metal-Bragg reflector interface.

    Science.gov (United States)

    Liu, Cunding; Kong, Mingdong; Li, Bincheng

    2014-05-05

    Influence of a negative refractive index meta-material (NIM) capping layer on properties of Tamm plasmon-polariton at the interface of metal-Bragg reflector structure is investigated. Conditions for excitation of the plasmon-polariton is determined from reflectivity mapping calculation and analyzed with cavity mode theory. For specific thicknesses of capping layers, Tamm plasmon-polariton with negative group velocity is revealed in a wide region of frequency. Different from backward optical propagation induced by negative effective-group-refractive-index in dispersive media, negative group velocity of Tamm plasmon-polariton results from opposite signs of cross-section-integrated field energy and Poynting vector.

  4. Effect of the ortho-hydroxy group of salicylaldehyde in the A3 coupling reaction: A metal-catalyst-free synthesis of propargylamine

    Directory of Open Access Journals (Sweden)

    Sujit Ghosh

    2017-03-01

    Full Text Available The synthesis of propargylamines via A3 coupling mostly under metal-catalyzed procedures is well known. This work invented an unprecedented effect of salicylaldehyde, one of the A3 coupling partners, which could lead to the formation of propargylamine, an important pharmaceutical building block, in the absence of any metal catalyst and under mild conditions. The role of the hydroxy group in ortho position of salicylaldehyde has been explored, which presumably activates the Csp–H bond of the terminal alkyne leading to the formation of propargylamines in good to excellent yields, thus negating the function of the metal catalyst. This observation is hitherto unknown, tested for a variety of salicylaldehyde, amine and acetylene, established as a general protocol, and is believed to be of interest for synthetic chemists from green chemistry.

  5. Encapsulation of hydride by molecular main group metal clusters: manipulating the source and coordination sphere of the interstitial ion.

    Science.gov (United States)

    Boss, Sally R; Coles, Martyn P; Eyre-Brook, Vicki; García, Felipe; Haigh, Robert; Hitchcock, Peter B; McPartlin, Mary; Morey, James V; Naka, Hiroshi; Raithby, Paul R; Sparkes, Hazel A; Tate, Christopher W; Wheatley, Andrew E H

    2006-12-21

    The sequential treatment of Lewis acids with N,N'-bidentate ligands and thereafter with ButLi has afforded a series of hydride-encapsulating alkali metal polyhedra. While the use of Me3Al in conjunction with Ph(2-C5H4N)NH gives Ph(2-C5H4N)NAlMe2 and this reacts with MeLi in thf to yield the simple 'ate complex Ph(2-C5H4N)NAlMe3Li.thf, the employment of an organolithium substrate capable of beta-hydride elimination redirects the reaction significantly. Whereas the use of ButLi has previously yielded a main group interstitial hydride in which H- exhibits micro6-coordination, it is shown here that variability in the coordination sphere of the encapsulated hydride may be induced by manipulation of the organic ligand. Reaction of (c-C6H11)(2-C5H4N)NH with Me3Al/ButLi yields [{(c-C6H11)(2-C5H4N)N}6HLi8]+[(But2AlMe2)2Li]-, which is best viewed as incorporating only linear di-coordination of the hydride ion. The guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) in conjunction with Me2Zn/ButLi yields the micro8-hydride [(hpp)6HLi8]+[But3Zn]-.0.5PhMe. Formation of the micro8-hydride [(hpp)6HLi8]+[ButBEt3]- is revealed by employment of the system Et3B/ButLi. A new and potentially versatile route to interstitial hydrides of this class is revealed by synthesis of the mixed borohydride-lithium hydride species [(hpp)6HLi8]+[Et3BH]- and [(hpp)6HLi8]+[(Et3B)2H]- through the direct combination of hppLi with Et3BHLi.

  6. Protecting group and switchable pore-discriminating adsorption properties of a hydrophilic-hydrophobic metal-organic framework

    Science.gov (United States)

    Mohideen, M. Infas H.; Xiao, Bo; Wheatley, Paul S.; McKinlay, Alistair C.; Li, Yang; Slawin, Alexandra M. Z.; Aldous, David W.; Cessford, Naomi F.; Düren, Tina; Zhao, Xuebo; Gill, Rachel; Thomas, K. Mark; Griffin, John M.; Ashbrook, Sharon E.; Morris, Russell E.

    2011-04-01

    Formed by linking metals or metal clusters through organic linkers, metal-organic frameworks are a class of solids with structural and chemical properties that mark them out as candidates for many emerging gas storage, separation, catalysis and biomedical applications. Important features of these materials include their high porosity and their flexibility in response to chemical or physical stimuli. Here, a copper-based metal-organic framework has been prepared in which the starting linker (benzene-1,3,5-tricarboxylic acid) undergoes selective monoesterification during synthesis to produce a solid with two different channel systems, lined by hydrophilic and hydrophobic surfaces, respectively. The material reacts differently to gases or vapours of dissimilar chemistry, some stimulating subtle framework flexibility or showing kinetic adsorption effects. Adsorption can be switched between the two channels by judicious choice of the conditions. The monoesterified linker is recoverable in quantitative yield, demonstrating possible uses of metal-organic frameworks in molecular synthetic chemistry as ‘protecting groups’ to accomplish selective transformations that are difficult using standard chemistry techniques.

  7. Ten Months of Observations of the Possible Super-Chandrasekhar Mass Type Ia Supernova 2009dc

    CERN Document Server

    Silverman, Jeffrey M; Li, Weidong; Filippenko, Alexei V; Miller, Adam A; Poznanski, Dovi

    2010-01-01

    In this paper, we present and analyse optical photometry and spectra of the extremely luminous and slowly evolving Type Ia supernova (SN Ia) 2009dc, and offer evidence that it is a super-Chandrasekhar mass (SC) SN Ia and thus had a SC white dwarf (WD) progenitor. Optical spectra of SN 2007if, a similar object, are also shown. SN 2009dc had one of the most slowly evolving light curves ever observed for a SN Ia, with a rise time of ~23 days and Delta m_15(B) = 0.72 mag. We calculate a lower limit to the peak bolometric luminosity of ~2.1e43 erg/s, though the actual value is likely ~60% larger. Optical spectra of SN 2009dc and SN 2007if obtained near maximum brightness exhibit strong CII features (indicative of a significant amount of unburned material), and the post-maximum spectra are dominated by iron-group elements. All of our spectra of SN 2009dc and SN 2007if also show low expansion velocities. The high luminosity and low expansion velocities of SN 2009dc lead us to derive a possible WD progenitor mass of ...

  8. Type Ia Supernova Colors and Ejecta Velocities: Hierarchical Bayesian Regression with Non-Gaussian Distributions

    CERN Document Server

    Mandel, Kaisey S; Kirshner, Robert P

    2014-01-01

    We investigate the correlations between the peak intrinsic colors of Type Ia supernovae (SN Ia) and their expansion velocities at maximum light, measured from the Si II 6355 A spectral feature. We construct a new hierarchical Bayesian regression model and Gibbs sampler to estimate the dependence of the intrinsic colors of a SN Ia on its ejecta velocity, while accounting for the random effects of intrinsic scatter, measurement error, and reddening by host galaxy dust. The method is applied to the apparent color data from BVRI light curves and Si II velocity data for 79 nearby SN Ia. Comparison of the apparent color distributions of high velocity (HV) and normal velocity (NV) supernovae reveals significant discrepancies in B-V and B-R, but not other colors. Hence, they are likely due to intrinsic color differences originating in the B-band, rather than dust reddening. The mean intrinsic B-V and B-R color differences between HV and NV groups are 0.06 +/- 0.02 and 0.09 +/- 0.02 mag, respectively. Under a linear m...

  9. Supernova 2010ev: A reddened high velocity gradient type Ia supernova

    CERN Document Server

    Gutiérrez, Claudia P; Folatelli, Gastón; Pignata, Giuliano; Anderson, Joseph P; Hamuy, Mario; Morrell, Nidia; Stritzinger, Maximilian; Taubenberger, Stefan; Bufano, Filomena; Olivares, Felipe E; Haislip, Joshua B; Reichart, Daniel E

    2016-01-01

    Aims. We present and study the spectroscopic and photometric evolution of the type Ia supernova (SN Ia) 2010ev. Methods. We obtain and analyze multi-band optical light curves and optical-near-infrared spectroscopy at low and medium resolution spanning from -7 days to +300 days from the B-band maximum. Results. A photometric analysis shows that SN 2010ev is a SN Ia of normal brightness with a light curve shape of $\\Delta m_{15}(B)=1.12 \\pm 0.02$ and a stretch s = $0.94 \\pm 0.01$ suffering significant reddening. From photometric and spectroscopic analysis, we deduce a color excess of $E(B - V) = 0.25 \\pm 0.05$ and a reddening law of $R_v = 1.54 \\pm 0.65$. Spectroscopically, SN 2010ev belongs to the broad-line SN Ia group, showing stronger than average Si II {\\lambda}6355 absorption features. We also find that SN 2010ev is a high-velocity gradient SN, with a value of $164 \\pm 7$ km s$^{-1}$ d$^{-1}$. The photometric and spectral comparison with other supernovae shows that SN 2010ev has similar colors and velocit...

  10. Measuring cosmic bulk flows with Type Ia Supernovae from the Nearby Supernova Factory

    CERN Document Server

    Feindt, U; Kowalski, M; Aldering, G; Antilogus, P; Aragon, C; Bailey, S; Baltay, C; Bongard, S; Buton, C; Canto, A; Cellier-Holzem, F; Childress, M; Chotard, N; Copin, Y; Fakhouri, H K; Gangler, E; Guy, J; Kim, A; Nugent, P; Nordin, J; Paech, K; Pain, R; Pecontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Rigault, M; Runge, K; Saunders, C; Scalzo, R; Smadja, G; Tao, C; Thomas, R C; Weaver, B A; Wu, C

    2013-01-01

    Context. Our Local Group of galaxies appears to be moving relative to the Cosmic Microwave Background with the source of the peculiar motion still uncertain. While in the past this has been studied mostly using galaxies as distance indicators, the weight of type Ia supernovae (SNe Ia) has increased recently with the continuously improving statistics of available low-redshift supernovae. Aims. We measured the bulk flow in the nearby universe (0.015 < z < 0.1) using 117 SNe Ia observed by the Nearby Supernova Factory, as well as the Union2 compilation of SN Ia data already in the literature. Methods. The bulk flow velocity was determined from SN data binned in redshift shells by including a coherent motion (dipole) in a cosmological fit. Additionally, a method of spatially smoothing the Hubble residuals was used to verify the results of the dipole fit. To constrain the location and mass of a potential mass concentration (e.g. the Shapley Supercluster) responsible for the peculiar motion, we fit a Hubble l...

  11. Vibrational spectra of bis(dmit) complexes of main group metals: IR, Raman and ab initio calculations

    OpenAIRE

    Ferreira,Glaucio B.; Nadia M. Comerlato; Wardell, James L.; Hollauer,Eduardo

    2004-01-01

    This work reports a theoretical-experimental investigation of the infrared/Raman vibrational spectra of several metal 1,3-dithole-2-thione-4,5-dithiolate (dmit) complexes; [NEt4]2[Zn(dmit)2], [NEt4][Sb(dmit)2] and [NEt4][Bi(dmit)2]. IR/Raman spectra of all the solids and the solution IR spectrum of [NEt4]2[Zn(dmit)2] were recorded from 4000 to 100 cm-1. Two regions were clearly identified: below 380 cm-1, the modes presented significant metal-ligand contributions, and above, the modes indicat...

  12. 5.9-keV Mn K-shell X-ray luminosity from the decay of 55Fe in Type Ia supernova models

    Science.gov (United States)

    Seitenzahl, I. R.; Summa, A.; Krauß, F.; Sim, S. A.; Diehl, R.; Elsässer, D.; Fink, M.; Hillebrandt, W.; Kromer, M.; Maeda, K.; Mannheim, K.; Pakmor, R.; Röpke, F. K.; Ruiter, A. J.; Wilms, J.

    2015-02-01

    We show that the X-ray line flux of the Mn Kα line at 5.9 keV from the decay of 55Fe is a promising diagnostic to distinguish between Type Ia supernova (SN Ia) explosion models. Using radiation transport calculations, we compute the line flux for two three-dimensional explosion models: a near-Chandrasekhar mass delayed detonation and a violent merger of two (1.1 and 0.9 M⊙) white dwarfs. Both models are based on solar metallicity zero-age main-sequence progenitors. Due to explosive nuclear burning at higher density, the delayed-detonation model synthesizes ˜3.5 times more radioactive 55Fe than the merger model. As a result, we find that the peak Mn Kα line flux of the delayed-detonation model exceeds that of the merger model by a factor of ˜4.5. Since in both models the 5.9-keV X-ray flux peaks five to six years after the explosion, a single measurement of the X-ray line emission at this time can place a constraint on the explosion physics that is complementary to those derived from earlier phase optical spectra or light curves. We perform detector simulations of current and future X-ray telescopes to investigate the possibilities of detecting the X-ray line at 5.9 keV. Of the currently existing telescopes, XMM-Newton/pn is the best instrument for close (≲1-2 Mpc), non-background limited SNe Ia because of its large effective area. Due to its low instrumental background, Chandra/ACIS is currently the best choice for SNe Ia at distances above ˜2 Mpc. For the delayed-detonation scenario, a line detection is feasible with Chandra up to ˜3 Mpc for an exposure time of 106 s. We find that it should be possible with currently existing X-ray instruments (with exposure times ≲5 × 105 s) to detect both of our models at sufficiently high S/N to distinguish between them for hypothetical events within the Local Group. The prospects for detection will be better with future missions. For example, the proposed Athena/X-IFU instrument could detect our delayed

  13. UBVRI Light Curves of 44 Type Ia Supernovae

    NARCIS (Netherlands)

    Jha, Saurabh; Groot, Paul J.

    2006-01-01

    We present UBVRI photometry of 44 Type Ia supernovae (SNe Ia) observed from 1997 to 2001 as part of a continuing monitoring campaign at the Fred Lawrence Whipple Observatory of the Harvard-Smithsonian Center for Astrophysics. The data set comprises 2190 observations and is the largest homogeneously

  14. The Connection between IAS/IFRS and Social Responsibility

    Directory of Open Access Journals (Sweden)

    Stefano AMELIO

    2016-05-01

    Full Text Available The aim of the paper is to evaluate the degree of social responsibility arising from the statement of comprehensive income prepared according to IAS/IFRS, to demonstrate whether the values obtained from prospects and from the calculation of the indicators are sufficient to analyze the Company's performance from the perspective of social responsibility and sustainable value or not. In order to achieve the objective of harmonization, the European Union adopted the IAS/IFRS developed by the International Accounting Standards Board (IASB. The research is divided into two sections and the approach used is mainly theoretical and qualitative. In the first part, the financial statements to be prepared according to IAS 1 and IAS 7 and, in particular, the so called statement of profit or loss and other comprehensive income for the period are analyzed by underling the function of the same and by presenting some financial performance indicators. Then, the research highlights how these values obtained are not useful to communicate the company's strategy in terms of social responsibility and sustainable value. In the second part the analyses exposes the concept of social balance. According to the social responsibility view the IAS/IFRS financial statements should be accompanied by the social balance. It becomes crucial to complete the set of financial statements stated from IAS 1 with a social balance as well as the same IAS 1 contemplates. For this reason it is possible to say that the connection between IAS/IFRS and social responsibility is weak.

  15. Autologous peptides constitutively occupy the antigen binding site on Ia

    DEFF Research Database (Denmark)

    Buus, S; Sette, A; Colon, S M;

    1988-01-01

    Low molecular weight material associated with affinity-purified class II major histocompatibility complex (MHC) molecules of mouse (Ia) had the expected properties of peptides bound to the antigen binding site of Ia. Thus, the low molecular weight material derived from the I-Ad isotype...

  16. 77 FR 66067 - Amendment of Class E Airspace; Boone, IA

    Science.gov (United States)

    2012-11-01

    ... Administration 14 CFR Part 71 Amendment of Class E Airspace; Boone, IA AGENCY: Federal Aviation Administration (FAA), DOT. ACTION: Final rule. SUMMARY: This action amends Class E airspace at Boone, IA... necessary for standard instrument approach procedures and for the safety and management of Instrument...

  17. 77 FR 68682 - Amendment of Class E Airspace; Guthrie, IA

    Science.gov (United States)

    2012-11-16

    ... Federal Aviation Administration 14 CFR Part 71 Amendment of Class E Airspace; Guthrie, IA AGENCY: Federal... Guthrie, IA. Decommissioning of the Guthrie Center non-directional radio beacon (NDB) at Guthrie County... safety and management of Instrument Flight Rule (IFR) operations at the airport. Geographic...

  18. Spectroscopic Properties of Star-Forming Host Galaxies and Type Ia Supernova Hubble Residuals in a Nearly Unbiased Sample

    Energy Technology Data Exchange (ETDEWEB)

    D' Andrea, Chris B. [Univ. of Pennsylvania, Philadelphia, PA (United States); et al.

    2011-12-20

    We examine the correlation between supernova host galaxy properties and their residuals on the Hubble diagram. We use supernovae discovered during the Sloan Digital Sky Survey II - Supernova Survey, and focus on objects at a redshift of z < 0.15, where the selection effects of the survey are known to yield a complete Type Ia supernova sample. To minimize the bias in our analysis with respect to measured host-galaxy properties, spectra were obtained for nearly all hosts, spanning a range in magnitude of -23 < M_r < -17. In contrast to previous works that use photometric estimates of host mass as a proxy for global metallicity, we analyze host-galaxy spectra to obtain gas-phase metallicities and star-formation rates from host galaxies with active star formation. From a final sample of ~ 40 emission-line galaxies, we find that light-curve corrected Type Ia supernovae are ~ 0.1 magnitudes brighter in high-metallicity hosts than in low-metallicity hosts. We also find a significant (> 3{\\sigma}) correlation between the Hubble residuals of Type Ia supernovae and the specific star-formation rate of the host galaxy. We comment on the importance of supernova/host-galaxy correlations as a source of systematic bias in future deep supernova surveys.

  19. Preparation of magnetic metal organic frameworks adsorbent modified with mercapto groups for the extraction and analysis of lead in food samples by flame atomic absorption spectrometry.

    Science.gov (United States)

    Wang, Yang; Chen, Huanhuan; Tang, Jie; Ye, Guiqin; Ge, Huali; Hu, Xiaoya

    2015-08-15

    A novel magnetic metal organic frameworks adsorbent modified with mercapto groups was synthesized and developed for extraction and spectrophotometric determination of trace lead. The adsorbent was characterized by Fourier transforms infrared spectrometer, X-ray diffraction, scanning electron microscopy and vibrating sample magnetometry. The results indicated the adsorbents exhibited high adsorption capacities for lead due to the chelation mechanism between metal cations and mercapto groups. Meanwhile, the lead sorption onto the adsorbents could be easily separated from aqueous solution using a magnetic separation method. Under the optimal conditions, a linear calibration curve in the range from 1 to 20 μg L(-1) was achieved with an enrichment factor of 100. The limits of detection and quantitation for lead were found to be 0.29 and 0.97 μg L(-1), respectively. The developed method was successfully applied to the determination of trace amounts of lead in food samples and certified reference material with satisfactory results.

  20. Intermediate-band Photometry of Type Ia Supernovae

    CERN Document Server

    Wang, X; Zhang, T; Li, Z; Wang, Xiaofeng; Zhou, Xu; Zhang, Tianmeng; Li, Zongwei

    2004-01-01

    We present optical light curves of five Type Ia supernovae (2002er, 2002fk, 2003cg, 2003du, 2003fk). The photometric observations were performed in a set of intermediate-band filters. SNe 2002er, 2003du appear to be normal SN Ia events with similar light curve shapes, while SN 2003kf shows the behavior of a brighter SN Ia with slower decline rate after maximum. The light curves of SN 2003cg is unusual; they show a fast rise and dramatic decline near maximum and do not display secondary peak at longer wavelengths during 15-30 days after maximum light. This suggests that SN 2003cg is likely to be an intrinsically subluminous, 91bg-like SN Ia. Exploration of SN Ia feature lines through intermediate-band photometry is briefly discussed.

  1. Theoretical considerations about implementation of IAS 41 in Romania

    Directory of Open Access Journals (Sweden)

    Liliana FELEAGĂ

    2012-02-01

    Full Text Available Although agriculture is an important part of the world economy, accounting in agriculture still has many shortcomings. The adoption of IAS 41 „Agricuture” has tried to improve this situation and increase the comparability of financial statements of entities in the agricultural sector. Although controversial, IAS 41 is the first step of a consistent transition to fair value assessment in the agricultural sector. The objective of our work is the analysis of IAS 41 and current accounting agricultural situation in Romania. Accounting regulations in Romania are in accordance with European directives and, in many respects, converged with IFRS referential. Provisions of IAS 41, however, are not reflected directly in Romanian regulations. With the increase of forest land transactions and foreign investments in animal farms, it is expected that recognition and measurement of biological assets under IAS 41 to become a necessity.

  2. Type Ia Supernova Remnants: Shaping by Iron Bullets

    CERN Document Server

    Tsebrenko, Danny

    2015-01-01

    Using 2D numerical hydrodynamical simulations of type Ia supernova remnants (SNR Ia) we show that iron clumps few times denser than the rest of the SN ejecta might form protrusions in an otherwise spherical SNR. Such protrusions exist in some SNR Ia, e.g., SNR 1885 and Tycho. Iron clumps are expected to form in the deflagration to detonation explosion model. In SNR Ia where there are two opposite protrusions, termed ears, such as Kepler's SNR and SNR G1.9+0.3, our scenario implies that the dense clumps, or iron bullets, were formed along an axis. Such a preferred axis can result from a rotating white dwarf progenitor. If our claim holds, this offers an important clue to the SN Ia explosion scenario.

  3. Human Ia-like antigens in non-lymphoid organs.

    Science.gov (United States)

    Koyama, K; Fukunishi, T; Barcos, M; Tanigaki, N; Pressman, D

    1979-01-01

    Human Ia-like antigens in liver and kidney were shown by the immunofluorescence assay to be present mostly in the endothelial-mesenchymal cells of these organs. The parenchymal cells apparently contained no human Ia-like antigens. The antigens in liver and kidney were purified and shown to have the same subunit structure as human Ia-like antigens of cultured B-lymphoid cells. The human Ia-like antigens in non-lymphoid organs, not only in liver and kidney but also in testis, heart, muscle and brain, carried all the xenoantigenic characteristics of human Ia-like antigens expressed on lymphoid cells of B-cell lineage. Images Figure 1 PMID:389786

  4. Adiponectin levels correlate with the severity of hypertriglyceridaemia in glycogen storage disease Ia

    NARCIS (Netherlands)

    Bandsma, R. H. J.; Smit, G. P. A.; Reijngoud, D. -J.; Kuipers, F.

    2009-01-01

    Glycogen storage disease type Ia (GSD Ia) is characterized by severe hypercholesterolaemia and hypertriglyceridaemia. Little is known about the aetiology of the hyperlipidaemia in GSD Ia. Adipokines play an important regulatory role in lipid metabolism. We investigated whether adipokine concentratio

  5. Anastilosis Virtual de Felipéia

    Directory of Open Access Journals (Sweden)

    Hélio Costa Lima

    2011-04-01

    Full Text Available This text is about a virtual anastylosis of Felipéia, capital of Paraíba, the first city founded in Brazil under the Spanish Crown in 1585, during the Iberic Union. Recently, infographics resources enabled the reconstruction, with great precision, of the old city’s ground plans from Dutch maps from 1634-37, and establish the first hypothesis of a tridimensional configuration of the city. Now, measuring and studies are being done to make possible a piece by piece virtual anastylosis of the buildings and, after that, a tridimensional virtual reconstruction of the historical city, which will enable virtual walkabouts on the streets, squares and buildings.

  6. Type Ia Supernova Explosion: Gravitationally Confined Detonation

    CERN Document Server

    Plewa, T; Lamb, D

    2004-01-01

    We present a new mechanism for Type Ia supernova explosions in massive white dwarfs. The proposed scenario follows from relaxing the assumption of symmetry in the model and involves a detonation created in an unconfined environment. The explosion begins with an essentially central ignition of stellar material initiating a deflagration. This deflagration results in the formation of a buoyantly-driven bubble of hot material that reaches the stellar surface at supersonic speeds. The bubble breakout forms a strong pressure wave that laterally accelerates fuel-rich outer stellar layers. This material, confined by gravity to the white dwarf, races along the stellar surface and is focused at the location opposite to the point of the bubble breakout. These streams of nuclear fuel carry enough mass and energy to trigger a detonation just above the stellar surface. The flow conditions at that moment support a detonation that will incinerate the white dwarf and result in an energetic explosion. The stellar expansion fol...

  7. Type Ia supernovae and the DD scenario

    CERN Document Server

    Isern, J; Lorén-Aguilar, P

    2011-01-01

    Type Ia supernovae are thought to be the outcome of the thermonuclear explosion of a white dwarf in a close binary system. Two possible scenarios, not necessarily incompatible, have been advanced. One assumes a white dwarf that accretes matter from a nondegenerate companion (the single degenerate scenario), the other assumes two white dwarfs that merge as a consequence of the emission of gravitational waves (the double degenerate scenario). The delay time distribution of star formation bursts strongly suggests that the DD scenario should be responsible of the late time explosions, but this contradicts the common wisdom that the outcome of the merging of two white dwarfs is an accretion induced collapse to a neutron star. In this contribution we review some of the most controversial issues of this problem.

  8. Phases of a Type Ia supernova explosion

    CERN Document Server

    Niemeyer, J C

    1998-01-01

    In the framework of the Chandrasekhar mass white dwarf model for Type Ia supernovae, various stages of the explosion are described in terms of the burning regimes of the thermonuclear flame front. In the early flamelet regime following the ``smoldering'' phase prior to the explosion, the flame is sufficiently thin and fast to remain laminar on small scales. As the white dwarf density declines, the thermal flame structure becomes subject to penetration by turbulent eddies, and it enters the ``distributed burning'' regime. A specific control parameter for this transition is proposed. Furthermore, we outline an argument for the coincidence of the transition between burning regimes with the onset of a deflagration-detonation-transition (DDT) in the late phase of the explosion.

  9. 3IA Conference (3IA’2011)

    CERN Document Server

    Miaoulis, Georgios; Intelligent Computer Graphics 2011

    2012-01-01

    In Computer Graphics, the use of intelligent techniques started more recently than in other research areas. However, during these last two decades, the use of intelligent Computer Graphics techniques is growing up year after year and more and more interesting techniques are presented in this area.   The purpose of this volume is to present current work of the Intelligent Computer Graphics community, a community growing up year after year. This volume is a kind of continuation of the previously published Springer volumes “Artificial Intelligence Techniques for Computer Graphics” (2008), “Intelligent Computer Graphics 2009” (2009) and “Intelligent Computer Graphics 2010” (2010).   This volume contains selected extended papers from the last 3IA Conference (3IA’2011), which has been held in Athens (Greece) in May 2011. This year papers are particularly exciting and concern areas like virtual reality, artificial life, data visualization, games, global illumination, point cloud modelling, declarativ...

  10. Versatile structures of group 13 metal halide complexes with 4,4'-bipy: from 1D coordination polymers to 2D and 3D metal-organic frameworks.

    Science.gov (United States)

    Sevastianova, Tatiana N; Bodensteiner, Michael; Maulieva, Albina F; Davydova, Elena I; Virovets, Alexander V; Peresypkina, Eugenia V; Balázs, Gábor; Graßl, Christian; Seidl, Michael; Scheer, Manfred; Frenking, Gernot; Berezovskaya, Ekaterina A; Kazakov, Igor V; Khoroshilova, Olesya V; Timoshkin, Alexey Y

    2015-12-21

    A systematic structural study of complexes formed by aluminium and gallium trihalides with 4,4'-bipyridine (bipy) in 2 : 1, 1 : 1, and 1 : 2 stoichiometric ratios has been performed. Molecular structures of 11 complexes in the solid state have been determined for the first time. Complexes of 2 : 1 composition are molecular, while complexes of 1 : 1 composition form metal-organic frameworks of different kinds: an ionic 3D network (three interpenetrated lvt nets for AlCl3bipy), an ionic 2D network for AlBr3bipy and GaBr3bipy and a 1D coordination polymer in the case of GaCl3bipy. Thus, the nature of the Lewis acid plays a critical role in the structural type of the complex in the solid state. Incorporation of excess bipy molecules into (GaCl3bipy)∞ (formation of crystallosolvate) leads to an unprecedented change of the molecular structure from a non-ionic 1D coordination polymer to an ionic 2D metal organic framework [GaCl2bipy2](+)[GaCl4](-)·2bipy. As indicated by the temperature-dependent XRD study, removal of bipy by heating in a vacuum restores the non-ionic 1D structure. Quantum chemical computations for simple cluster model systems (up to eight Al and Ga atoms) reveal that ionic forms are slightly favourable, although the energy differences between the ionic and non-ionic structures are not large. These theoretical predictions are in good agreement with experimental findings. Thus, even relatively simple cluster models may be used to indicate the structural preferences in the solid state. Both experimental and computational IR frequency shifts of the in-plane ring bending mode of bipy upon complexation correlate well with the M-N bond distances in the complexes.

  11. The luminosity of supernovae of type Ia from TRGB distances and the value of H_0

    CERN Document Server

    Tammann, G A

    2012-01-01

    Distances from the tip of the red-giant branch (TRGB) in the halo Population of galaxies - calibrated through RR Lyr stars as well as tied to Hipparcos parallaxes and further supported by stellar models - are used to determine the luminosity of six nearby type Ia supernovae (SN 2011fe, 2007sr, 1998bu, 1989B, 1972E, and 1937C). The result is M_V^corr = -19.41 +/- 0.05. If this value is applied to 62 SNe Ia with 3000< v < 20,000 km/s a large-scale value of the Hubble constant follows of H_0 = 64.0 +/- 1.6 +/- 2.0. The SN HST Project gave H_0 = 62.3 +/- 1.3 +/- 5.0 from ten Cepheid-calibrated SNe Ia (Sandage et al. 2006). The agreement of young Population I (Cepheids) and old, metal-poor Population II (TRGB) distance indicators is satisfactory. The combined weighted result is H_0 = 63.7 +/- 2.3 (i.e. +/-3.6%). The result can also be reconciled with WMAP5 data (Reid et al. 2010).

  12. 78 FR 13015 - Designation for the Sandusky, MI; Davenport, IA; Enid, OK; Keokuk, IA; Marshall, MI; and Omaha...

    Science.gov (United States)

    2013-02-26

    ... the September 13, 2012 Federal Register (77 FR 56608), GIPSA requested applications for designation to... Grain Inspection, Packers and Stockyards Administration Designation for the Sandusky, MI; Davenport, IA; Enid, OK; Keokuk, IA; Marshall, MI; and Omaha, NE Areas AGENCY: Grain Inspection, Packers...

  13. Exploring the spectroscopic diversity of Type Ia supernovae with DRACULA: a machine learning approach

    Science.gov (United States)

    Sasdelli, M.; Ishida, E. E. O.; Vilalta, R.; Aguena, M.; Busti, V. C.; Camacho, H.; Trindade, A. M. M.; Gieseke, F.; de Souza, R. S.; Fantaye, Y. T.; Mazzali, P. A.

    2016-09-01

    The existence of multiple subclasses of Type Ia supernovae (SNe Ia) has been the subject of great debate in the last decade. One major challenge inevitably met when trying to infer the existence of one or more subclasses is the time consuming, and subjective, process of subclass definition. In this work, we show how machine learning tools facilitate identification of subtypes of SNe Ia through the establishment of a hierarchical group structure in the continuous space of spectral diversity formed by these objects. Using deep learning, we were capable of performing such identification in a four-dimensional feature space (+1 for time evolution), while the standard principal component analysis barely achieves similar results using 15 principal components. This is evidence that the progenitor system and the explosion mechanism can be described by a small number of initial physical parameters. As a proof of concept, we show that our results are in close agreement with a previously suggested classification scheme and that our proposed method can grasp the main spectral features behind the definition of such subtypes. This allows the confirmation of the velocity of lines as a first-order effect in the determination of SN Ia subtypes, followed by 91bg-like events. Given the expected data deluge in the forthcoming years, our proposed approach is essential to allow a quick and statistically coherent identification of SNe Ia subtypes (and outliers). All tools used in this work were made publicly available in the PYTHON package Dimensionality Reduction And Clustering for Unsupervised Learning in Astronomy (DRACULA) and can be found within COINtoolbox (https://github.com/COINtoolbox/DRACULA).

  14. TYPE Ia SUPERNOVA COLORS AND EJECTA VELOCITIES: HIERARCHICAL BAYESIAN REGRESSION WITH NON-GAUSSIAN DISTRIBUTIONS

    Energy Technology Data Exchange (ETDEWEB)

    Mandel, Kaisey S.; Kirshner, Robert P. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Foley, Ryan J., E-mail: kmandel@cfa.harvard.edu [Astronomy Department, University of Illinois at Urbana-Champaign, 1002 West Green Street, Urbana, IL 61801 (United States)

    2014-12-20

    We investigate the statistical dependence of the peak intrinsic colors of Type Ia supernovae (SNe Ia) on their expansion velocities at maximum light, measured from the Si II λ6355 spectral feature. We construct a new hierarchical Bayesian regression model, accounting for the random effects of intrinsic scatter, measurement error, and reddening by host galaxy dust, and implement a Gibbs sampler and deviance information criteria to estimate the correlation. The method is applied to the apparent colors from BVRI light curves and Si II velocity data for 79 nearby SNe Ia. The apparent color distributions of high-velocity (HV) and normal velocity (NV) supernovae exhibit significant discrepancies for B – V and B – R, but not other colors. Hence, they are likely due to intrinsic color differences originating in the B band, rather than dust reddening. The mean intrinsic B – V and B – R color differences between HV and NV groups are 0.06 ± 0.02 and 0.09 ± 0.02 mag, respectively. A linear model finds significant slopes of –0.021 ± 0.006 and –0.030 ± 0.009 mag (10{sup 3} km s{sup –1}){sup –1} for intrinsic B – V and B – R colors versus velocity, respectively. Because the ejecta velocity distribution is skewed toward high velocities, these effects imply non-Gaussian intrinsic color distributions with skewness up to +0.3. Accounting for the intrinsic-color-velocity correlation results in corrections to A{sub V} extinction estimates as large as –0.12 mag for HV SNe Ia and +0.06 mag for NV events. Velocity measurements from SN Ia spectra have the potential to diminish systematic errors from the confounding of intrinsic colors and dust reddening affecting supernova distances.

  15. Half-sandwich pentamethylcyclopentadienyl group 9 metal complexes of 2-aminopyridyl ligands: Synthesis, spectral and molecular study

    Indian Academy of Sciences (India)

    Mahesh Kalidasan; Scott Forbes; Yurij Mozharivskyj; Mohan Rao Kollipara

    2015-06-01

    Thereaction of [Cp*M(-Cl)Cl]2 (M = Rh, Ir) with 2-aminopyridyl based ligands lead to the formation of mononuclear neutral complexes of general formula [Cp*MCl2(L)] {where L1= 2-aminopyridine, L2= 2-amino-3-picoline, L3= 2-amino-3-nirtopyridine, and L4= 2-amino-3-pyridine carboxyaldehyde}. The complexes have been characterized by FT-IR, UV-Vis, 1H-13C NMR and mass spectroscopic methods. X-ray crystallographic studies of the complexes have shown typical piano-stool geometry around the metal centre in which 2-aminopyridyl ligand acts as an N-monodentate ligand and the amino functionality is not involved in metal coordination. The intra/intermolecular arrangement is due to hydrogen bonding.

  16. Ferromagnetism in IV main group element (C and transition metal (Mn doped MgO: A density functional perspective

    Directory of Open Access Journals (Sweden)

    Vinit Sharma

    2011-09-01

    Full Text Available The formation of magnetic moment due to the dopants with p-orbital (d-orbital is named d0 (d − magnetism, where the ion without (with partially filled d states is found to be responsible for the observed magnetic properties. To study the origin of magnetism at a fundamental electronic level in such materials, as a representative case, we theoretically investigate ferromagnetism in MgO doped with transition metal (Mn and non-metal (C. The generalized gradient approximation based first-principles calculations are used to investigate substitutional doping of metal (Mn and non-metal (C, both with and without the presence of neighboring oxygen vacancy sites. Furthermore, the case of co-doping of (Mn, C in MgO system is also investigated. It is observed that the oxygen vacancies do not play a role in tuning the ferromagnetism in presence of Mn dopants, but have a significant influence on total magnetism of the C doped system. In fact, we find that in MgO the d0 magnetism through C doping is curtailed by pairing of the substitutional dopant with naturally occurring O vacancies. On the other hand, in case of (Mn, C co-doped MgO the strong hybridization between the C (2p and the Mn(3d states suggests that co-doping is a promising approach to enhance the ferromagnetic coupling between the nearest-neighboring dopant and host atoms. Therefore, (Mn,C co-doped MgO is expected to be a ferromagnetic semiconductor with long ranged ferromagnetism and high Curie temperature.

  17. Mesomorphism and Optical Properties of Peripherally Substituted Phthalocyanines: Influence of Chain Length, Linking Group and Central Metal Ion

    OpenAIRE

    Sleven, Jurgen

    2002-01-01

    Phthalocyanines form a colourful class of macrocyclic compounds, attracting the attention of many scientists. Some of these compounds – especially the metal containing phthalocyanines – play an important role in industrial activity and in society. Applications for phthalocyanines are found in the fields of non-linear optics, catalysis, electronic (bio)sensors, photovoltaic solar cells, optical data storage, lubricants, photo- and radiosensitizers for treatment of cancer, protein inhibitors … ...

  18. Stellar metallicities beyond the Local Group: the potential of J-band spectroscopy with extremely large telescopes

    CERN Document Server

    Evans, C J; Kudritzki, R -P; Puech, M; Yang, Y; Cuby, J -G; Figer, D F; Lehnert, M D; Morris, S L; Rousset, G

    2010-01-01

    We present simulated J-band spectroscopy of red giants and supergiants with a 42m European Extremely Large Telescope (E-ELT), using tools developed toward the EAGLE Phase A instrument study. The simulated spectra are used to demonstrate the validity of the 1.15-1.22 micron region to recover accurate stellar metallicities from Solar and metal-poor (one tenth Solar) spectral templates. From tests at spectral resolving powers of four and ten thousand, we require continuum signal-to-noise ratios in excess of 50 (per two-pixel resolution element) to recover the input metallicity to within 0.1 dex. We highlight the potential of direct estimates of stellar metallicites (over the range -1<[Fe/H]<0) of red giants with the E-ELT, reaching out to distances of ~5 Mpc for stars near the tip of the red giant branch. The same simulations are also used to illustrate the potential for quantitative spectroscopy of red supergiants beyond the Local Volume to tens of Mpc. Calcium triplet observations in the I-band are also ...

  19. Synthesis and Reactivity of Group 6 Metal Carbonyl Complexes with Bis(pyrazol-1-yl)methanes Modified by the Vinyltin Groups

    Institute of Scientific and Technical Information of China (English)

    WEN,Zhenkang; YANG,Zhi; SONG,Haibin; TANG,Liangfu

    2009-01-01

    Diphenyl(vinyl)stannylbis(3,5-dimethylpyrazol-1-yl)methane and diphenyl(vinyl)stannylbis(3,4,5-trimethyl-pyrazol-1-yl)methane have been synthesized by the reaction of bis(3,5-dimethylpyrazol-1-yl)methyl or bis(3,4,5-trimethylpyrazol-1-yl)methyllithium with diphenyl(vinyl)tin iodide. Treatment of these bis(pyrazol-l-yl)methanes modified by the vinyltin groups with M(CO)5THF (M=Mo and W) in refluxing THF resulted in new heterobimeto allic complexes R3SnCHPz2M(CO)3 (R3Sn represents trivinyltin or diphenyl(vinyl)tin, and Pz represents substituted pyrazol-1-yl), in which a vinyl group bonds to the molybdenum or tungsten atom in η2-fashion to lead to bis(pyrazol-1-yl)methanes acting as a tridentate κ3-(π,N,N) ligand. Reaction of (CH2 = CH)3SnCH(3,5-Me2Pz)2W(CO)3 and Ph2(CH2=CH)SnCH(3,5-Me2Pz)2W(CO)3 with I2 has been investigated. The former gave a complex CH2(3,5-Me2Pz)2W(CO)4, while the latter yielded a four-membered heterometallocyclic complex CH(3,5-Me2Pz)2W(CO)3 I with the loss of the organotin group. Treatment of this four-membered heterometallocyc-lic complex with PhSNa led to the iodide anion replaced by the thiophenolate anion to give a complex CH(3,5-Me2Pz)2W(CO)3SPh.

  20. Experimental observations on noble metal nanonuggets and Fe-Ti oxides, and the transport of platinum group elements in silicate melts

    Science.gov (United States)

    Anenburg, Michael; Mavrogenes, John A.

    2016-11-01

    Platinum group element (PGE) nanonuggets are a nuisance in experimental studies designed to measure solubility or partitioning of noble metals in silicate melts. Instead of treating nanonuggets as experimental artifacts, we studied their behaviour motivated by recent discoveries of PGE nanonuggets in a variety of natural settings. We used an experimental setup consisting of AgPd, Pt or AuPd capsules and Fe(-Ti) oxide-saturated hydrous peralkaline silicate melts to maximise nanonugget production. TABS (Te, As, Bi, Sb, Sn) commonly occur in PGM (platinum group minerals), prompting addition of Bi to our experiments to investigate its properties as well. Three-dimensional optical examination by 100× objective and immersion oil reveals variable colour which correlates with nanonugget size and shape due to plasmon resonance effects. We observe two textural types: (1) intermediate-sized nanonuggets dispersed in the glass and adhering to oxides, and (2) abundant fine nanonuggets dispersed in the glass with coarse euhedral crystals in contact with oxides. Slow cooling removes dispersed nanonuggets and greatly coarsens existing oxide-associated metal crystals. Nanonugget-free halos are commonly observed around oxide grains. All metal phases are composed of major (Ag, Pd) and trace (Pt, Ir, Au) capsule material. Our results show reduction processes, imposed by growing oxides, causing local metal saturation in the oxide rich zones with preferential nucleation on smaller oxide grains. The redox gradient then blocks additional metals from diffusing into oxide rich zones, forming halos. As the entire experimental charge is reduced throughout the run, nanonuggets form in the distal glass. Bismuth contents of metal phases do not depend on Bi2O3 amounts dissolved in the melt. Further PGM crystallisation consumes nanonuggets as feedstock. We conclude that the appearance of metallic PGE phases happens in two stages: first as nanonuggets and then as larger PGM. Once formed

  1. Determination of the Hubble constant, the intrinsic scatter of luminosities of Type Ia SNe, and evidence for non-standard dust in other galaxies

    CERN Document Server

    Wang, X; Pain, R; Wang, L; Zhou, X; Li, Zongwei; Pain, Reynald; Wang, Lifan; Wang, Xiaofeng; Zhou, Xu

    2006-01-01

    A sample of 109 type Ia supernovae (SNe Ia) with recession velocity < 30,000 km s^{-1}, is compiled from published SNe Ia light curves to explore the expansion rate of the local Universe. Based on the color parameter \\Delta C_{12}, we found that the average absorption to reddening ratio for SN Ia host galaxies to be R_{UBVI} = 4.37+/-0.25, 3.33+/-0.11, 2.30+/-0.11, 1.18+/-0.11, which are systematically lower than the standard values in the Milky Way. We investigated the correlations of the intrinsic luminosity with light curve decline rate, color index, and supernova environmental parameters. In particular, we found SNe Ia in E/S0 galaxies to be brighter close to the central region than those in the outer region, which may suggest a possible metallicity effect on SN luminosity. The dependence of SN luminosity on galactic environment disappears after corrections for the extinction and \\Delta C_{12}. The Hubble diagrams constructed using 73 Hubble flow SNe Ia yield a 1-$\\sigma$ scatter of <0.12 mag in BVI...

  2. How to Find Gravitationally Lensed Type Ia Supernovae

    CERN Document Server

    Goldstein, Daniel A

    2016-01-01

    Type Ia supernovae (SNe Ia) that are multiply imaged by gravitational lensing can extend the SN Ia Hubble diagram to very high redshifts ($z\\gtrsim 2$), probe potential SN Ia evolution, and deliver high-precision constraints on $H_0$, $w$, and $\\Omega_m$ via time delays. However, only one, iPTF16geu, has been found to date, and many more are needed to achieve these goals. To increase the multiply imaged SN Ia discovery rate we present a simple algorithm for identifying gravitationally lensed SN Ia candidates in cadenced, wide-field optical imaging surveys. The technique is to look for supernovae that appear to have an elliptical galaxy as their host with an absolute magnitude implied by the host's photometric redshift that is far brighter than the absolute magnitude of a normal SN Ia (the brightest type of supernova found in elliptical galaxies). Importantly, this purely photometric method does not require the ability to resolve the lensed images for discovery. The primary sources of contamination that affect...

  3. K-corrections and spectral templates of Type Ia supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Nugent, Peter E; Hsiao, E.Y.; Conley, A.; Howell, D.A.; Sullivan, M.; Pritchet, C.J.; Carlberg, R.G.; Nugent, P.E.; Phillips, M.M.

    2007-03-20

    With the advent of large dedicated Type Ia supernova (SN Ia) surveys, K-corrections of SNe Ia and their uncertainties have become especially important in the determination of cosmological parameters. While K-corrections are largely driven by SN Ia broadband colors, it is shown here that the diversity in spectral features of SNe Ia can also be important. For an individual observation, the statistical errors from the inhomogeneity in spectral features range from 0.01 (where the observed and rest-frame filters are aligned) to 0.04 (where the observed and rest-frame filters are misaligned). To minimize the systematic errors caused by an assumed SN Ia spectral energy distribution (SED), we outline a prescription for deriving a mean spectral template time series that incorporates a large and heterogeneous sample of observed spectra. We then remove the effects of broadband colors and measure the remaining uncertainties in the K-corrections associated with the diversity in spectral features. Finally, we present a template spectroscopic sequence near maximum light for further improvement on the K-correction estimate. A library of ~;;600 observed spectra of ~;;100 SNe Ia from heterogeneous sources is used for the analysis.

  4. Photometric selection of high-redshift type Ia supernovae

    CERN Document Server

    Sullivan, M; Perrett, K; Nugent, P; Astier, Pierre; Aubourg, E; Balam, D; Basa, S; Carlberg, R; Conley, A; Fabbro, S; Fouchez, D; Guy, J; Hook, I; Lafoux, H; Neill, J D; Pain, R; Palanque-Delabrouille, Nathalie; Pritchet, C; Regnault, N; Rich, J; Taillet, R; Aldering, G; Baumont, S; Bronder, J; Filiol, M; Knop, R; Perlmutter, S; Tao, C

    2005-01-01

    We present a method for selecting high-redshift type Ia supernovae (SNe Ia) located via rolling SN searches. The technique, using both color and magnitude information of events from only 2-3 epochs of multi-band real-time photometry, is able to discriminate between SNe Ia and core collapse SNe. Furthermore, for the SNe Ia, the method accurately predicts the redshift, phase and light-curve parameterization of these events based only on pre-maximum-light data. We demonstrate the effectiveness of the technique on a simulated survey of SNe Ia and core-collapse SNe, where the selection method effectively rejects most core-collapse SNe while retaining SNe Ia. We also apply the selection code to real-time data acquired as part of the Canada-France-Hawaii Telescope Supernova Legacy Survey (SNLS). During the period May 2004 to January 2005 in the SNLS, 440 SN candidates were discovered of which 70 were confirmed spectroscopically as SNe Ia and 15 as core-collapse events. For this test dataset, the selection technique ...

  5. Molecular and ionic-scale chemical mechanisms behind the role of nitrocyl group in the electrochemical removal of heavy metals from sludge

    Science.gov (United States)

    Hasan, S. W.; Ahmed, I.; Housani, A. A.; Giwa, A.

    2016-08-01

    The chemical basis for improved removal rates of toxic heavy metals such as Zn and Cu from wastewater secondary sludge has been demonstrated in this study. Instead of using excess corrosive chemicals as the source of free nitrous acid (FNA) for improved solubility of heavy metals in the sludge (in order to enhance electrokinetics), an optimized use of aqua regia has been proposed as an alternative. Fragments of nitrocyl group originated from aqua regia are responsible for the disruption of biogenic mixed liquor volatile suspended solids (MLVSS) and this disruption resulted in enhanced removal of exposed and oxidized metal ions. A diversity of nitric oxide (NO), peroxy nitrous acid, and peroxy nitroso group are expected to be introduced in the mixed liquor by the aqua regia for enhanced electrochemical treatment. The effects of pectin as a post treatment on the Zn removal from sludge were also presented for the first time. Results revealed 63.6% Cu and 93.7% Zn removal efficiencies, as compared to 49% Cu and 74% Zn removal efficiencies reported in a recent study. Also, 93.3% reduction of time-to-filter (TTF), and 95 mL/g of sludge volume index (SVI) were reported. The total operating cost obtained was USD 1.972/wet ton.

  6. How to Find Gravitationally Lensed Type Ia Supernovae

    Science.gov (United States)

    Goldstein, Daniel A.; Nugent, Peter E.

    2017-01-01

    Type Ia supernovae (SNe Ia) that are multiply imaged by gravitational lensing can extend the SN Ia Hubble diagram to very high redshifts (z ≳ 2), probe potential SN Ia evolution, and deliver high-precision constraints on H0, w, and Ωm via time delays. However, only one, iPTF16geu, has been found to date, and many more are needed to achieve these goals. To increase the multiply imaged SN Ia discovery rate, we present a simple algorithm for identifying gravitationally lensed SN Ia candidates in cadenced, wide-field optical imaging surveys. The technique is to look for supernovae that appear to be hosted by elliptical galaxies, but that have absolute magnitudes implied by the apparent hosts’ photometric redshifts that are far brighter than the absolute magnitudes of normal SNe Ia (the brightest type of supernovae found in elliptical galaxies). Importantly, this purely photometric method does not require the ability to resolve the lensed images for discovery. Active galactic nuclei, the primary sources of contamination that affect the method, can be controlled using catalog cross-matches and color cuts. Highly magnified core-collapse SNe will also be discovered as a byproduct of the method. Using a Monte Carlo simulation, we forecast that the Large Synoptic Survey Telescope can discover up to 500 multiply imaged SNe Ia using this technique in a 10 year z-band search, more than an order of magnitude improvement over previous estimates. We also predict that the Zwicky Transient Facility should find up to 10 multiply imaged SNe Ia using this technique in a 3 year R-band search—despite the fact that this survey will not resolve a single system.

  7. Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Ka King [Iowa State Univ., Ames, IA (United States)

    2013-01-01

    A series of organometallic compounds containing the tris(dimethylsilyl)methyl ligand are described. The potassium carbanions KC(SiHMe2)3 and KC(SiHMe2})3TMEDA are synthesized by deprotonation of the hydrocarbon HC(SiHMe2)3 with potassium benzyl. KC(SiHMe2)3TMEDA crystallizes as a dimer with two types of three-center-two-electron KH- Si interactions. Homoleptic Ln(III) tris(silylalkyl) complexes containing β-SiH groups M{C(SiHMe2)3}3 (Ln = Y, Lu, La) are synthesized from salt elimination of the corresponding lanthanide halide and 3 equiv. of KC(SiHMe2)3. The related reactions with Sc yield bis(silylalkyl) ate-complexes containing either LiCl or KCl. The divalent calcium and ytterbium compounds M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2 or TMEDA) are prepared from MI2 and 2 equiv of KC(SiHMe2)3. The compounds M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2 or TMEDA) and La{C(SiHMe2)3}3 react with 1 equiv of B(C6F5)3 to give 1,3- disilacyclobutane {Me2Si-C(SiHMe2)2}2 and MC(SiHMe2)3HB(C6F5)3L, and La{C(SiHMe2)3}2HB(C6F5)3, respectively. The corresponding reactions of Ln{C(SiHMe2)3}3 (Ln = Y, Lu) give the β-SiH abstraction product [{(Me2HSi)3C}2LnC(SiHMe2)2SiMe2][HB(C6F5)3] (Ln = Y, Lu), but the silene remains associated with the Y or Lu center. The abstraction reactions of M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2or TMEDA) and Ln{C(SiHMe2)3}3 (Ln = Y, Lu, La) and 2 equiv of B(C6

  8. Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Ka King [Iowa State Univ., Ames, IA (United States)

    2013-01-01

    A series of organometallic compounds containing the tris(dimethylsilyl)methyl ligand are described. The potassium carbanions KC(SiHMe2)3 and KC(SiHMe2})3TMEDA are synthesized by deprotonation of the hydrocarbon HC(SiHMe2)3 with potassium benzyl. KC(SiHMe2)3TMEDA crystallizes as a dimer with two types of three-center-two-electron KH- Si interactions. Homoleptic Ln(III) tris(silylalkyl) complexes containing β-SiH groups M{C(SiHMe2)3}3 (Ln = Y, Lu, La) are synthesized from salt elimination of the corresponding lanthanide halide and 3 equiv. of KC(SiHMe2)3. The related reactions with Sc yield bis(silylalkyl) ate-complexes containing either LiCl or KCl. The divalent calcium and ytterbium compounds M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2 or TMEDA) are prepared from MI2 and 2 equiv of KC(SiHMe2)3. The compounds M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2 or TMEDA) and La{C(SiHMe2)3}3 react with 1 equiv of B(C6F5)3 to give 1,3- disilacyclobutane {Me2Si-C(SiHMe2)2}2 and MC(SiHMe2)3HB(C6F5)3L, and La{C(SiHMe2)3}2HB(C6F5)3, respectively. The corresponding reactions of Ln{C(SiHMe2)3}3 (Ln = Y, Lu) give the β-SiH abstraction product [{(Me2HSi)3C}2LnC(SiHMe2)2SiMe2][HB(C6F5)3] (Ln = Y, Lu), but the silene remains associated with the Y or Lu center. The abstraction reactions of M{C(SiHMe2)3}2L (M = Ca, Yb; L = THF2or TMEDA) and Ln{C(SiHMe2)3}3 (Ln = Y, Lu, La) and 2 equiv of B(C6

  9. Synthesis and characterization of near-IR absorbing metal-free and zinc(II phthalocyanines modified with aromatic azo groups

    Directory of Open Access Journals (Sweden)

    Mukaddes Özçeşmeci

    2015-05-01

    Full Text Available Metal-free and zinc(II phthalocyanine complexes bearing peripheral (E-4-((2-hydroxynaphthalen-1-yldiazenyl units have been synthesized. Novel phthalonitrile derivative required for the preparation of phthalocyanine complexes was prepared by coupling 4-aminophthalonitrile and 2-naphthol. The structures of these new compounds were characterized by using elemental analyses, proton nuclear magnetic resonance, fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, fluorescence spectroscopy and mass spectrometry. In the UV-Vis spectra a broad absorption band appears for phthalocyanine complexes at around 450–500 nm resulting from azo-group introduced onto the phthalocyanine ring. The photophysical properties of metal-free and zinc(II phthalocyanines were studied in tetrahydrofuran.

  10. Stable two-channel Kondo fixed point of an SU(3) quantum defect in a metal: renormalization-group analysis and conductance spikes.

    Science.gov (United States)

    Arnold, Michael; Langenbruch, Tobias; Kroha, Johann

    2007-11-02

    We propose a physical realization of the two-channel Kondo (2CK) effect, where a dynamical defect in a metal has a unique ground state and twofold degenerate excited states. In a wide range of parameters the interactions with the electrons renormalize the excited doublet downward below the bare defect ground state, thus stabilizing the 2CK fixed point. In addition to the Kondo temperature T(K) the three-state defect exhibits another low-energy scale, associated with ground-to-excited-state transitions, which can be exponentially smaller than T(K). Using the perturbative nonequilibrium renormalization group we demonstrate that this can provide the long-sought explanation of the sharp conductance spikes observed by Ralph and Buhrman in ultrasmall metallic point contacts.

  11. Constraining cosmic isotropy with type Ia supernovae

    CERN Document Server

    Bengaly,, C A P; Alcaniz, J S

    2016-01-01

    We investigate the validity of the Cosmological Principle by constraining the cosmological parameters $H_0$ and $q_0$ through the celestial sphere. Our analyses are performed in a low-redshift regime in order to follow a model independent approach, using both Union2.1 and JLA Type Ia Supernovae (SNe) compilations. We find that the preferred direction of the $H_0$ parameter in the sky is consistent with the bulk flow motion of our local Universe in the Union2.1 case, while the $q_0$ directional analysis seem to be anti-correlated with the $H_0$ for both data sets. Furthermore, we test the consistency of these results with Monte Carlo (MC) realisations, finding that the anisotropy on both parameters are significant within $2-3\\sigma$ confidence level, albeit we find a significant correlation between the $H_0$ and $q_0$ mapping with the angular distribution of SNe from the JLA compilation. Therefore, we conclude that the detected anisotropies are either of local origin, or induced by the non-uniform celestial co...

  12. Turbulent Oxygen Flames in Type Ia Supernovae

    CERN Document Server

    Aspden, A J; Woosley, S E; 10.1088/0004-637X/730/2/144

    2011-01-01

    In previous studies, we examined turbulence-flame interactions in carbon-burning thermonuclear flames in Type Ia supernovae. In this study, we consider turbulence-flame interactions in the trailing oxygen flames. The two aims of the paper are to examine the response of the inductive oxygen flame to intense levels of turbulence, and to explore the possibility of transition to detonation in the oxygen flame. Scaling arguments analogous to the carbon flames are presented and then compared against three-dimensional simulations for a range of Damk\\"ohler numbers ($\\Da_{16}$) at a fixed Karlovitz number. The simulations suggest that turbulence does not significantly affect the oxygen flame when $\\Da_{16}1$, turbulence enhances heat transfer and drives the propagation of a flame that is {\\em narrower} than the corresponding inductive flame would be. Furthermore, burning under these conditions appears to occur as part of a combined carbon-oxygen turbulent flame with complex compound structure. The simulations do not ...

  13. Early emission from type Ia supernovae

    CERN Document Server

    Rabinak, Itay; Waxman, Eli

    2011-01-01

    A unique feature of deflagration-to-detonation (DDT) white dwarf explosion models of SNe of type Ia is the presence of a strong shock wave propagating through the outer envelope. We consider the early emission expected in such models, which is produced by the expanding shock-heated outer part of the ejecta and precedes the emission driven by radioactive decay. We expand on earlier analyses by considering the modification of the pre-detonation density profile by the weak-shocks generated during the deflagration phase, the time evolution of the opacity, and the deviation of the post-shock equation of state from that obtained for radiation pressure domination. A simple analytic model is presented and shown to provide an acceptable approximation to the results of 1D numerical DDT simulations. Our analysis predicts a thousand second long UV/optical flash with a luminosity of ~1 to 3*1e39 erg/s. Lower luminosity corresponds to faster (turbulent) deflagration velocity. The predicted luminosity of the UV flash is an ...

  14. EARLY EMISSION FROM TYPE Ia SUPERNOVAE

    Energy Technology Data Exchange (ETDEWEB)

    Rabinak, Itay; Waxman, Eli [Department of Particle Physics and Astrophysics, Weizmann Institute of Science, Rehovot 76100 (Israel); Livne, Eli, E-mail: itay.rabinak@weizmann.ac.il [Racah Institute of Physics, Hebrew University, Jerusalem (Israel)

    2012-09-20

    A unique feature of deflagration-to-detonation (DDT) white dwarf explosion models of supernovae of type Ia is the presence of a strong shock wave propagating through the outer envelope. We consider the early emission expected in such models, which is produced by the expanding shock-heated outer part of the ejecta and precedes the emission driven by radioactive decay. We expand on earlier analyses by considering the modification of the pre-detonation density profile by the weak shocks generated during the deflagration phase, the time evolution of the opacity, and the deviation of the post-shock equation of state from that obtained for radiation pressure domination. A simple analytic model is presented and shown to provide an acceptable approximation to the results of one-dimensional numerical DDT simulations. Our analysis predicts a {approx}10{sup 3} s long UV/optical flash with a luminosity of {approx}1 to {approx}3 Multiplication-Sign 10{sup 39} erg s{sup -1}. Lower luminosity corresponds to faster (turbulent) deflagration velocity. The luminosity of the UV flash is predicted to be strongly suppressed at t > t{sub drop} {approx} 1 hr due to the deviation from pure radiation domination.

  15. Star Clusters as Type Ia Supernova Factories

    CERN Document Server

    Shara, M M; Shara, Michael M.; Hurley, Jarrod R.

    2002-01-01

    We find a remarkably enhanced production rate in star clusters (relative to the field) of very short period, massive double-white-dwarf stars and of giant-white dwarf binaries. These results are based on N-body simulations performed with the new GRAPE-6 special purpose hardware and are important in identifying and characterizing the progenitors of type Ia supernovae. The high incidence of very close double-white-dwarf systems is the result of dynamical encounters between (mostly) primordial binaries and other cluster stars. Orbital hardening rapidly drives these degenerate binaries to periods under ~10 hours. Gravitational radiation emission and mergers producing supra-Chandrasekhar objects follow in less than a Hubble time. If most stars are born in clusters then estimates of the double white dwarf merger rates in galaxies (due to cluster dynamical interaction) must be increased more than tenfold. A majority of the Roche lobe overflow giant-white dwarf binaries are not primordial; they are produced in exchan...

  16. Clustering of supernova Ia host galaxies

    CERN Document Server

    Carlberg, R G; Le Borgne, D; Conley, A; Howell, D A; Perrett, K; Astier, Pierre; Balam, D; Balland, C; Basa, S; Hardin, D; Fouchez, D; Guy, J; Hook, I; Pain, R; Pritchet, C J; Regnault, N; Rich, J; Perlmutter, S

    2008-01-01

    For the first time the cross-correlation between type Ia supernova host galaxies and surrounding field galaxies is measured using the Supernova Legacy Survey sample. Over the z=0.2 to 0.9 redshift range we find that supernova hosts are correlated an average of 60% more strongly than similarly selected field galaxies over the 3-100 arcsec range and about a factor of 3 more strongly below 10 arcsec. The correlation errors are empirically established with a jackknife analysis of the four SNLS fields. The hosts are more correlated than the field at a significance of 99% in the fitted amplitude and slope, with the point-by-point difference of the two correlation functions having a reduced $\\chi^2$ for 8 degrees of freedom of 4.3, which has a probability of random occurrence of less than 3x10^{-5}. The correlation angle is 1.5+/-0.5 arcsec, which deprojects to a fixed co-moving correlation length of approximately 6.5+/- 2/h mpc. Weighting the field galaxies with the mass and star formation rate supernova frequencie...

  17. High-velocity Hα Absorption Events in B8 Ia - A2 Ia Supergiant Stars

    Science.gov (United States)

    Morrison, Nancy D.; Markova, N.; Rother, S. J.

    2009-12-01

    Late B- and early A-type supergiants are notorious for the time variability of their Hα line profiles, but the physical cause of the variations is poorly understood. Usually, the line is filled in by emission, and the blue absorption wing does not extend to the terminal wind speed, which is roughly defined by the blue edges of the ultraviolet resonance lines. On rare occasions, however, the blue wing of Hα goes strongly into absorption over a wide velocity range, from the photospheric velocity almost all the way to the terminal wind speed. This phenomenon was first described by Kaufer et al. (1996, A&A, 314, 599), who denoted it by the term, "High-Velocity Absorption Event." In this report, high-resolution spectra from Ritter Observatory will be combined with published spectra to examine the temporal recurrence behavior and strength distribution of high-velocity absorption events and their incidence as a function of stellar parameters for the available sample of stars. All B8- and A0-type, Ia-class, stars in the sample that have been sufficiently well observed, as well as one A2-type star, show the events. However, there is some evidence that hyperluminous stars (luminosity class Ia+) do not show the events. In one of the most extensively observed stars in the sample (Rigel, B8 Ia), there is no clear periodicity in the recurrence times of the events. In addition to the strong events discovered by Kaufer et al. (1996), there is a broad distribution of more frequent, weaker events. Ritter Observatory receives operating support from the National Science Foundation Program for Research and Education with Small Telescopes (PREST) award AST-0440784.

  18. Searching for light echoes due to CSM in SN Ia spectra

    CERN Document Server

    Marino, Sebastián; Förster, Francisco; Folatelli, Gastón; Hamuy, Mario; Hsiao, Eric

    2015-01-01

    We present an analytical model for light echoes (LEs) coming from circumstellar material (CSM) around Type Ia Supernovae (SNe Ia). Using this model we find two spectral signatures at 4100 {\\AA} and 6200 {\\AA} that are useful to identify LEs during the Lira law phase (between 35 and 80 days after maximum light) coming from nearby CSM at distances of 0.01-0.25 pc. We analyze a sample of 89 SNe Ia divided in two groups according to their B-V decline rate during the Lira law phase, and search for LEs from CSM interaction in the group of SNe with steeper slopes by comparing their spectra with our LE model. We find that a model with LEs + pure extinction from interstellar material (ISM) fits better the observed spectra than a pure ISM extinction model that is constant in time, but we find that a decreasing extinction alone explains better the observations without the need of LEs, possibly implying dust sublimation due to the radiation from the SN.

  19. Determination of Stability Constants of Triazole Ligand Carrying Naphthol Group with Heavy Metal Ions in Aqueous Solutions

    Directory of Open Access Journals (Sweden)

    Nurhan Gümrükçüoğlu

    2013-12-01

    Full Text Available Interaction of 4-(2-hydroxy-1-naphthylmethylamino-3-methyl-5-(4-tolyl-4H-1,2,4-triazole with heavy metal cations such as Cu2+, Co2+, Cd2+, Ni2+ and Pb2+ was investigated by using UV-visible spectrophotometric technique. The complex stability constants (Log β were determined in aqueous as well as in methanol: water (1:1 system at 25 ± 0.1°C by Buschmann’s method and Valeur’s methods, respectively. The ligand showed good sensitivity for Co2+ with a linear range of 210-6M to 310-5M.

  20. sup 29 Si magic angle spinning NMR spectra of alkali metal, alkaline earth metal, and rare earth metal ion exchanged Y zeolites

    Energy Technology Data Exchange (ETDEWEB)

    Chao, Kueijung; Chern, Jeryoung (Tsinghua Univ., Taiwan (China))

    1989-02-23

    The variation of the extraframework cation location in groups IA and IIA metals and rare earth metal (RE) Y zeolites as a function of the dehydration and the rehydration is monitored by {sup 29}Si MAS NMR. Unheated hydrated zeolites give similar {sup 29}Si spectra as they present the similar cation distributions. Upon dehydration a high-field shift is observed which correlates with the distortion of bond angles in silicon-oxygen tetrahedra. The line shapes of {sup 29}Si spectra depend on the nature and the location of the exchangeable cations and the occupancy of the different sites in dehydrated and rehydrated states. The correlation between the line shape of {sup 29}Si spectra and the migration of cations from the supercages to the sodalite cages after heating treatment was studied. The results of {sup 29}Si NMR agree with the known structure data.

  1. Observational clues to the progenitors of Type-Ia supernovae

    CERN Document Server

    Maoz, Dan; Nelemans, Gijs

    2013-01-01

    Type-Ia supernovae (SNe Ia) are important distance indicators, element factories, cosmic-ray accelerators, kinetic-energy sources in galaxy evolution, and endpoints of stellar binary evolution. It has long been clear that a SN Ia must be the runaway thermonuclear explosion of a degenerate carbon-oxygen stellar core, most likely a white dwarf (WD). However, the specific progenitor systems of SNe Ia, and the processes that lead to their ignition, have not been identified. Two broad classes of progenitor binary systems have long been considered: single-degenerate (SD), in which a WD gains mass from a non-degenerate star; and double-degenerate (DD), involving the merger of two WDs. New theoretical work has enriched these possibilities with some interesting updates and variants. We review the significant recent observational progress in addressing the progenitor problem. We consider clues that have emerged from the observed properties of the various proposed progenitor populations, from studies of their sites, pre...

  2. CIRCUMSTELLAR ABSORPTION IN DOUBLE DETONATION TYPE Ia SUPERNOVAE

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Ken J. [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Guillochon, James [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Foley, Ryan J., E-mail: kenshen@astro.berkeley.edu [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2013-06-20

    Upon formation, degenerate He core white dwarfs are surrounded by a radiative H-rich layer primarily supported by ideal gas pressure. In this Letter, we examine the effect of this H-rich layer on mass transfer in He+C/O double white dwarf binaries that will eventually merge and possibly yield a Type Ia supernova (SN Ia) in the double detonation scenario. Because its thermal profile and equation of state differ from the underlying He core, the H-rich layer is transferred stably onto the C/O white dwarf prior to the He core's tidal disruption. We find that this material is ejected from the binary system and sweeps up the surrounding interstellar medium hundreds to thousands of years before the SN Ia. The close match between the resulting circumstellar medium profiles and values inferred from recent observations of circumstellar absorption in SNe Ia gives further credence to the resurgent double detonation scenario.

  3. Type Ia supernova explosion mechanism and implications for cosmology

    Science.gov (United States)

    Maeda, K.

    Type Ia Supernovae (SNe Ia) are believed to be thermonuclear explosions of a white dwarf, and are one of the most mature cosmological standardized candles. However, the explosion mechanism has not yet been fully clarified. Furthermore, they show observational diversities which may be a consequence of either the diversity in the explosion physics and/or surrounding environments, an issue yet to be clarified. In this paper, it is argued that an asymmetry in the explosion is likely a generic feature, and that the diversity arising from various viewing angles can be an origin of observational diversities of SNe Ia seen in their spectral features (suspected possible biases in cosmology) and colors (related to the extinction estimate in cosmology). These findings indicate that at least a part of observational diversities are intrinsic, rather than caused by environment effects, and open up a possibility of using SNe Ia as more precise distance indicators than currently employed.

  4. Muudetud IFRS 3 ja IAS 27 / Monika Peetson

    Index Scriptorium Estoniae

    Peetson, Monika, 1976-

    2008-01-01

    Rahvusvahelise Raamatupidamisstandardite Nõukogu poolt välja antud muudetud standarditest IFRS 3 "Äriühendused" ja IAS 27 "Konsolideeritud ja konsolideerimata finantsaruanded" ning nendega kaasnevatest muudatustest

  5. Muudetud IFRS 3 ja IAS 27 / Monika Peetson

    Index Scriptorium Estoniae

    Peetson, Monika, 1976-

    2008-01-01

    Rahvusvahelise Raamatupidamisstandardite Nõukogu poolt välja antud muudetud standarditest IFRS 3 "Äriühendused" ja IAS 27 "Konsolideeritud ja konsolideerimata finantsaruanded" ning nendega kaasnevatest muudatustest

  6. The Connection between IAS/IFRS and Social Responsibility

    National Research Council Canada - National Science Library

    Stefano Amelio

    2016-01-01

      The aim of the paper is to evaluate the degree of social responsibility arising from the statement of comprehensive income prepared according to IAS/IFRS, to demonstrate whether the values obtained...

  7. Circumstellar Shells in Absorption in Type Ia Supernovae

    CERN Document Server

    Borkowski, K J; Reynolds, S P

    2009-01-01

    Progenitors of Type Ia supernovae (SNe) have been predicted to modify their ambient circumstellar (CSM) and interstellar environments through the action of their powerful winds. While there is X-ray and optical evidence for circumstellar interaction in several remnants of Type Ia SNe, widespread evidence for such interaction in Type Ia SNe themselves has been lacking. We consider prospects for detection of CSM shells that have been predicted to be common around Type Ia SNe. Such shells are most easily detected in Na I absorption lines. Variable (declining) absorption is expected to occur soon after the explosion, primarily during the SN rise time, for shells located within 1 - 10 pc of a SN. The distance of the shell from the SN can be determined by measuring the time scale for line variability.

  8. Functional state of rat liver RNA polymerase IA and IB.

    Science.gov (United States)

    Zoncheddu, A; Accomando, R; Pertica, M; Orunesu, M

    1979-01-01

    Phosphocellulose chromatography has been employed to characterize RNA polymerase I present in two different functional states in rat liver cells. The actively transcribing enzyme solubilized from nuclei appears to belong both to the IA and IB classes, whereas the non-transcribing enzyme present in the cytoplasmic fraction has been found to belong only to the IA class. Indirect and direct evidence indicates, however, that in isolated nuclei only the IB form is to be regarded as the physiological form of the enzyme, the IA form arising as a procedural artefact during the extraction process. It may, therefore, be concluded that rat liver IA and IB RNA polymerase are to be strictly regarded as the non-transcribing and transcribing form of the enzyme, respectively.

  9. Screening for CDG type Ia in Joubert syndrome.

    NARCIS (Netherlands)

    Morava, E.; Cser, B.; Karteszi, J.; Huijben, K.M.; Szonyi, L.; Kosztolanyi, G.Y.; Wevers, R.A.

    2004-01-01

    BACKGROUND: The features of Joubert syndrome include hypotonia, ataxia, characteristic neuro-imaging findings, episodic hypoventilation, psychomotor retardation, and abnormal eye movements. Common symptoms in congenital disorders of glycosylation (CDG) type Ia are muscle hypotonia, cerebellar hypopl

  10. The luminosity calibration of SNe Ia: present status.

    Science.gov (United States)

    Tammann, G. A.; Reindl, B.

    Blue supernovae of type Ia (SNe Ia) have become the most important objects in cosmology being of exceptionally uniform luminosity. Used as relative distance indicators they map deviations from pure Hubble flow and determine the cosmological constant Λ. Once their absolute magnitude is determined they provide the best estimate of the large-scale value of the Hubble constant H0. An HST project is reviewed where Cepheid distances are used for the luminosity calibration of SNe Ia. The mean luminosity of 8 SNe Ia is MB(max) = -19.47±0.07, MV(max) = -19.48±0.07, corresponding - after small corrections for second parameters - to H0(cosmic) = 59±5.

  11. TYPE Ia SUPERNOVAE STRONGLY INTERACTING WITH THEIR CIRCUMSTELLAR MEDIUM

    Energy Technology Data Exchange (ETDEWEB)

    Silverman, Jeffrey M. [Department of Astronomy, University of Texas, Austin, TX 78712-0259 (United States); Nugent, Peter E. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Gal-Yam, Avishay; Arcavi, Iair; Ben-Ami, Sagi [Benoziyo Center for Astrophysics, Weizmann Institute of Science, Rehovot 76100 (Israel); Sullivan, Mark [School of Physics and Astronomy, University of Southampton, Southampton SO17 1BJ (United Kingdom); Howell, D. Andrew; Graham, Melissa L. [Las Cumbres Observatory Global Telescope Network, Goleta, CA 93117 (United States); Filippenko, Alexei V.; Bloom, Joshua S.; Cenko, S. Bradley; Clubb, Kelsey I. [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States); Cao, Yi; Horesh, Assaf; Kulkarni, Shrinivas R. [Cahill Center for Astrophysics, California Institute of Technology, Pasadena, CA 91125 (United States); Chornock, Ryan; Foley, Ryan J. [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138 (United States); Coil, Alison L. [Department of Physics, University of California, San Diego, La Jolla, CA 92093 (United States); Griffith, Christopher V. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Kasliwal, Mansi M., E-mail: jsilverman@astro.as.utexas.edu [Observatories of the Carnegie Institution of Science, Pasadena, CA 91101 (United States); and others

    2013-07-01

    Owing to their utility for measurements of cosmic acceleration, Type Ia supernovae (SNe Ia) are perhaps the best-studied class of SNe, yet the progenitor systems of these explosions largely remain a mystery. A rare subclass of SNe Ia shows evidence of strong interaction with their circumstellar medium (CSM), and in particular, a hydrogen-rich CSM; we refer to them as SNe Ia-CSM. In the first systematic search for such systems, we have identified 16 SNe Ia-CSM, and here we present new spectra of 13 of them. Six SNe Ia-CSM have been well studied previously, three were previously known but are analyzed in depth for the first time here, and seven are new discoveries from the Palomar Transient Factory. The spectra of all SNe Ia-CSM are dominated by H{alpha} emission (with widths of {approx}2000 km s{sup -1}) and exhibit large H{alpha}/H{beta} intensity ratios (perhaps due to collisional excitation of hydrogen via the SN ejecta overtaking slower-moving CSM shells); moreover, they have an almost complete lack of He I emission. They also show possible evidence of dust formation through a decrease in the red wing of H{alpha} 75-100 days past maximum brightness, and nearly all SNe Ia-CSM exhibit strong Na I D absorption from the host galaxy. The absolute magnitudes (uncorrected for host-galaxy extinction) of SNe Ia-CSM are found to be -21.3 mag {<=} M{sub R} {<=} -19 mag, and they also seem to show ultraviolet emission at early times and strong infrared emission at late times (but no detected radio or X-ray emission). Finally, the host galaxies of SNe Ia-CSM are all late-type spirals similar to the Milky Way, or dwarf irregulars like the Large Magellanic Cloud, which implies that these objects come from a relatively young stellar population. This work represents the most detailed analysis of the SN Ia-CSM class to date.

  12. Doping anatase TIO_{2} with group V-b and VI-b transition metal atoms : a hybrid functional first-principles study

    OpenAIRE

    Matsubara, Masahiko; Saniz, Rolando; Partoens, Bart; Lamoen, Dirk

    2017-01-01

    Abstract: We investigate the role of transition metal atoms of group V-b (V, Nb, and Ta) and VI-b (Cr, Mo, and W) as n- or p-type dopants in anatase TiO2 using thermodynamic principles and density functional theory with the HeydScuseriaErnzerhof HSE06 hybrid functional. The HSE06 functional provides a realistic value for the band gap, which ensures a correct classification of dopants as shallow or deep donors or acceptors. Defect formation energies and thermodynamic transition levels are calc...

  13. Constraints on the Progenitors of SNeIa & Implications for the Cosmological Equation of State

    CERN Document Server

    Dominguez, I; Straniero, O

    2001-01-01

    Detailed calculations for the stellar evolution, explosion and light curves have been performed to quantify the influence of the main sequence mass M(MS) and the metallicity of the progenitor on the structure of the exploding WD which are thought to be the progenitors of SNe Ia. In particular,we study the effects of progenitors on the brightness decline relation M(dM_15) which is a corner stone for the use of SNe Ia as cosmological yard-stick.M(MS) has been identified as the decisive factor to change the energetics of the explosion and dominates the variations in the rise-time to decline relation of light curves. M(MS) has little effect on the color index B-V. For similar decline rates dM_15, the flux at maximum brightness relative to the flux on the radioactive tail decreases systematically with M(MS) by about 0.2mag. This change goes along with a reduc- tion of the photospheric expansion velocity $v_{ph}$ by about 2000 km/sec. A change in the central density has the opposite dependency. The metallicity Z af...

  14. Purification and separation of subsets of human Ia molecules by papain digestion.

    Science.gov (United States)

    Tanigaki, N; Tosi, R; Koyama, K; Pressman, D

    1980-01-01

    Papain digestion of human Ia(-like) molecules was performed under various conditions using 125I-labelled preparation of non-ionic-detergent-solubilized Ia antigens of Daudi cells. The products were examined for their allospecificities by a direct binding reaction with human Ia alloantisera. The Daudi Ia preparation is known to contain Ia molecules of DRw6 specificity, an HLA-DR specificity and also Ia molecules of DC1 specificity, a putative non-HLA-DR specificity. Limited papain digestion cleaved off the hydrophobic portion of human Ia molecules and gave smaller sized Ia products. The cleavage did not affect the Ia alloantigenic determinants and occurred much more readily with molecules of DC1 specificity than with molecules of DRw6 specificity. As a consequence, limited papain digestion of the Daudi Ia pool yielded an Ia preparation with DRw6 specificity but lacking DC1 specificity and another Ia preparation which was enriched in DC1 specificity. The limited papain digestion of the Daudi Ia pool followed by gel filtration and LcH affinity chromatography also produced Ia REPARATIONS OF HIGH PURITY. Extensive papain digestion damaged the Ia alloantigenic determinants but the DC1 determinant was much more resistant than the DRw6 determinant. Thus extensive papain digestion yielded an Ia preparation which was relatively rich in DC1 specificity and essentially devoid of DRw6 specificity. PMID:6155328

  15. Levels of Platinum Group Metals in Selected Species (Sarotherodon melanotheron, Chonophorus lateristriga, Macrobrachium vollenhovenii and Crassostrea tulipa in Some Estuaries and Lagoons Along the Coast of Ghana

    Directory of Open Access Journals (Sweden)

    D. K. Essumang

    2010-01-01

    Full Text Available The use of some biota as bioindicators of heavy metal pollution has been demonstrated as particularly adequate due to their capacity of bioconcentration. This study evaluated the levels of platinum group metals (PGMs in some selected species along the coastal belt of Ghana, using the neutron activation analysis (NAA method. The result was processed to evaluate pollution indices in order to map the distribution of the metals in those species in the lagoons and estuaries along the costal belt of Ghana. The analysis showed significant levels of all PGMs in blackchin tilapia (Sarotherodon melanotheron Cichlidae, brown goby (Chonophorus lateristriga Gobiidae, shrimp (Macrobrachium vollenhovenii Palaemonidae, and mangrove oysters (Crassostrea tulipa Ostreidae in the lagoons and river Pra estuary. However, the oysters showed an elevated mean concentration of 0.13 μ/g (dry weight Pd. From the pollution indices, most of the sampling sites registered mean contamination factor (CF values between 1.20 and 3.00 for Pt, Pd, and Rh. The pollution load index (PLI conducted also gave an average pollution index between 0.79 and 2.37, indicating progressive contamination levels. The results revealed that anthropogenic sources, industrial and hospital effluent, etc., together with vehicular emissions, could be the contributing factors to the deposition of PGMs along the Ghanaian coast.

  16. Chelation ion chromatography of alkaline earth and transition metals a using monolithic silica column with bonded N-hydroxyethyliminodiacetic acid functional groups.

    Science.gov (United States)

    McGillicuddy, Nicola; Nesterenko, Ekaterina P; Nesterenko, Pavel N; Jones, Phil; Paull, Brett

    2013-02-08

    A commercially available porous silica monolithic column (Onyx Monolithic Si, 100 mm×4.6 mm I.D.) was 'in-column' covalently functionalised with 2-hydroxyethyliminodiacetic acid (HEIDA) groups, and applied to the simultaneous and rapid separation of alkaline earth and transition metal ions, using high-performance chelation ion chromatography (HPCIC). With a 0.3mM dipicolinic acid (DPA) containing eluent, the baseline separation of various common transition and heavy metal ions and the four alkaline earth metal ions could be achieved in under 14 min with a flow rate of just 0.8 mL/min. Detection was achieved using spectrophotometric detection at 540 nm after post-column reaction (PCR) with 4-(2-pyridylazo)-resorcinol (PAR). Significant effects from variation of eluent nature, concentration and temperature upon selectivity and retention were demonstrated with the new monolithic silica chelating phase. Under optimised conditions (0.165 M LiNO(3) eluent, pH 2.5), peak efficiencies of 54,000, 60,000 and 64,000 N/m, for Zn(2+), Mn(2+) and Cd(2+), respectively, were recorded, far exceeding that previously reported for IDA based chelation ion exchange columns.

  17. Type Ia Supernovae Strongly Interacting with Their Circumstellar Medium

    CERN Document Server

    Silverman, Jeffrey M; Gal-Yam, Avishay; Sullivan, Mark; Howell, D Andrew; Filippenko, Alexei V; Arcavi, Iair; Ben-Ami, Sagi; Bloom, Joshua S; Cenko, S Bradley; Cao, Yi; Chornock, Ryan; Clubb, Kelsey I; Coil, Alison L; Foley, Ryan J; Graham, Melissa L; Griffith, Christopher V; Horesh, Assaf; Kasliwal, Mansi M; Kulkarni, Shrinivas R; Leonard, Douglas C; Li, Weidong; Matheson, Thomas; Miller, Adam A; Modjaz, Maryam; Ofek, Eran O; Pan, Yen-Chen; Perley, Daniel A; Poznanski, Dovi; Quimby, Robert M; Steele, Thea N; Sternberg, Assaf; Xu, Dong; Yaron, Ofer

    2013-01-01

    Owing to their utility for measurements of cosmic acceleration, Type Ia supernovae (SNe) are perhaps the best-studied class of SNe, yet the progenitor systems of these explosions largely remain a mystery. A rare subclass of SNe Ia show evidence of strong interaction with their circumstellar medium (CSM), and in particular, a hydrogen-rich CSM; we refer to them as SNe Ia-CSM. In the first systematic search for such systems, we have identified 16 SNe Ia-CSM, and here we present new spectra of 13 of them. Six SNe Ia-CSM have been well-studied previously, three were previously known but are analyzed in-depth for the first time here, and seven are new discoveries from the Palomar Transient Factory. The spectra of all SNe Ia-CSM are dominated by H{\\alpha} emission (with widths of ~2000 km/s) and exhibit large H{\\alpha}/H{\\beta} intensity ratios (perhaps due to collisional excitation of hydrogen via the SN ejecta overtaking slower-moving CSM shells); moreover, they have an almost complete lack of He I emission. They...

  18. Breaking the color-reddening degeneracy in type Ia supernovae

    CERN Document Server

    Sasdelli, M; Hillebrandt, W; Ashall, C; Mazzali, P A; Prentice, S

    2016-01-01

    A new method to study the intrinsic color and luminosity of type Ia supernovae (SNe Ia) is presented. A metric space built using principal component analysis (PCA) on spectral series SNe Ia between -12.5 and +17.5 days from B maximum is used as a set of predictors. This metric space is built to be insensitive to reddening. Hence, it does not predict the part of color excess due to dust-extinction. At the same time, the rich variability of SN Ia spectra is a good predictor of a large fraction of the intrinsic color variability. Such metric space is a good predictor of the epoch when the maximum in the B-V color curve is reached. Multivariate Partial Least Square (PLS) regression predicts the intrinsic B band light-curve and the intrinsic B-V color curve up to a month after maximum. This allows to study the relation between the light curves of SNe Ia and their spectra. The total-to-selective extinction ratio RV in the host-galaxy of SNe Ia is found, on average, to be consistent with typical Milky-Way values. Th...

  19. Extraction equilibria of various metal picrates with 19-crown-6 between benzene and water. Effect of the extra methylene group on extraction ability and selectivity.

    Science.gov (United States)

    Katsuta, S; Kanazawa, M; Takeda, Y; Ouchi, M

    1999-07-12

    The overall extraction equilibrium constants (K(ex)) of picrates of Li(+), Na(+), K(+), Rb(+), Cs(+), Ag(+), Tl(+), and Sr(2+)with 19-crown-6 (19C6) were determined between benzene and water at 25 degrees C. The K(ex) values were analyzed into the constituent equilibrium constants, i.e. the extraction constant of picric acid, the distribution constant of the crown ether, the formation constant of the metal ion-crown ether complex in water, and the ion-pair extraction constant of the complex cation with the picrate anion. The effects of an extra methylene group of 19C6 on the extraction ability and selectivity are discussed in detail by comparing the constituent equilibrium constants of 19C6 with those of 18-crown-6 (18C6). The K(ex) value of 19C6 for each metal ion is lower than that of 18C6, which is mostly attributed to the higher lipophilicity of 19C6. The extraction ability of 19C6 for the univalent metal ions decreases in the order Tl(+)>K(+)>Rb(+)>Ag(+)>Cs(+)>Na(+)Li(+), which is the same as that observed for 18C6. The difference in logK(ex) between the univalent metals is generally smaller for 19C6 than for 18C6. The extraction selectivity of 19C6 is governed by the selectivity in the ion-pair extraction, whereas that of 18C6 depends on both the selectivities in the ion-pair extraction and in the complexation in water.

  20. Metathesis of carbon dioxide and phenyl isocyanate catalysed by group(IV) metal alkoxides: An experimental and computational study

    Indian Academy of Sciences (India)

    Akshai Kumar; Ashoka G Samuelson

    2011-01-01

    The insertion reactions of zirconium(IV) -butoxide and titanium(IV) -butoxide with a heterocumulene like carbodiimide, carbon dioxide or phenyl isocyanate are compared. Both give an intermediate which carries out metathesis at elevated temperatures by inserting a second heterocumulene in a head-to-head fashion. The intermediate metallacycle extrudes a new heterocumulene, different from the two that have inserted leading to metathesis. As the reaction is reversible, catalytic metathesis is feasible. In stoichiometric reactions heterocumulene insertion, metathesis and metathesis cum insertion products are observed. However, catalytic amounts of the metal alkoxide primarily led to metathesis products. It is shown that zirconium alkoxides promote catalytic metathesis (isocyanates, carbon dioxide) more efficiently than the corresponding titanium alkoxide. The difference in the metathetic activity of these alkoxides has been explained by a computational study using model complexes Ti(OMe)4 (1bTi) and Zr(OMe)4 (1bZr). The computation was carried out at the B3LYP/LANL2DZ level of theory.

  1. Catalytic transformations of fatty acids derivatives for food, oleochemicals and fuels over carbon supported platinum group metals

    Energy Technology Data Exchange (ETDEWEB)

    Simakova, I.

    2010-07-01

    prominent in linoleic acid deoxygenation giving only 3 % conversion of fatty acids in 330 min. The deactivation originated from the formation of C17 aromatic compounds and fatty acid dimers via Diels-Alder reaction. Thus hydrogenation of unsaturated fatty acids can be considered as preliminary chemical modification step in the green diesel production. In this work particular care was taken to strengthen the nano level understanding of the Pd role, in particular metal size effect, in the catalytic hydrogenation and deoxygenation. Pd/C catalysts were synthesized with the same Pd loading and systematically varied metal dispersion via the controllable formation of Pd particles over carbon support surface. The effect of metal dispersion on hydrogenation rate and trans/cis ratio was revealed. An optimum metal dispersion giving the highest decarboxylation reaction rate was observed. In addition to the particle size effect, the impact of mass transfer was elucidated and detail discussions on temperature programmed desorption of CO from the fresh and spent samples was provided. Hydrogenation of vegetable feedstocks was performed in batch and continuous modes, using powdered and granulated Pd/C catalysts correspondingly. One of the main focuses of the work was put on the scale-up of the hydrogenation process. There are several challenges attributed to the scale-up of a chemical process which have to be recognized before progressing to an industrial application. In terms of the high production volumes the logical step is to investigate the performance of hydrogenation as a continuous process. A laboratory study in a continuous fixed bed reactor was performed, giving crucial information about the catalyst long-term stability and catalyst deactivation. Furthermore, the impact of using free fatty acids or triglycerides feedstocks as well as the effect of catalyst particle size and Pd loading were investigated in continuous mode. Finally, the production capacities for different operation

  2. Improvement of oxygen-containing functional groups on olive stones activated carbon by ozone and nitric acid for heavy metals removal from aqueous phase.

    Science.gov (United States)

    Bohli, Thouraya; Ouederni, Abdelmottaleb

    2016-08-01

    Recently, modification of surface structure of activated carbons in order to improve their adsorption performance toward especial pollutants has gained great interest. Oxygen-containing functional groups have been devoted as the main responsible for heavy metal binding on the activated carbon surface; their introduction or enhancement needs specific modification and impregnation methods. In the present work, olive stones activated carbon (COSAC) undergoes surface modifications in gaseous phase using ozone (O3) and in liquid phase using nitric acid (HNO3). The activated carbon samples were characterized using N2 adsorption-desorption isotherm, SEM, pHpzc, FTIR, and Boehm titration. The activated carbon parent (COSAC) has a high surface area of 1194 m(2)/g and shows a predominantly microporous structure. Oxidation treatments with nitric acid and ozone show a decrease in both specific surface area and micropore volumes, whereas these acidic treatments have led to a fixation of high amount of surface oxygen functional groups, thus making the carbon surface more hydrophilic. Activated carbon samples were used as an adsorbent matrix for the removal of Co(II), Ni(II), and Cu(II) heavy metal ions from aqueous solutions. Adsorption isotherms were obtained at 30 °C, and the data are well fitted to the Redlich-Peterson and Langmuir equation. Results show that oxidized COSACs, especially COSAC(HNO3), are capable to remove more Co(II), Cu(II), and Ni(II) from aqueous solution. Nitric acid-oxidized olive stones activated carbon was tested in its ability to remove metal ions from binary systems and results show an important maximum adsorbed amount as compared to single systems.

  3. Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands.

    Science.gov (United States)

    Fernandes, Tiago A; Solařová, Hana; Císařová, Ivana; Uhlík, Filip; Štícha, Martin; Štěpnička, Petr

    2015-02-21

    The reaction of in situ generated 1'-(diphenylphosphino)-1-lithioferrocene with carbamoyl chlorides, ClC(E)NMe2, affords the corresponding (thio)amides, Ph2PfcC(E)NMe2 (E = O (), S (); fc = ferrocene-1,1'-diyl). These compounds as well as their analogues, Ph2PfcC(O)NHMe () and Ph2PfcC(O)NH2 (), prepared from 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) were studied as ligands for the Group 11 metal ions. In the reactions with [Cu(MeCN)4][BF4], the amides give rise to bis-chelate complexes of the type [Cu(L-κ(2)O,P)2][BF4]. Similar products, [Ag(L-κ(2)O,P)2]ClO4, are obtained from silver(i) perchlorate and , or . In contrast, the reaction of AgClO4 with produces a unique molecular dimer [Ag()(ClO4-κO)]2, where the metal centres are bridged by the sulfur atoms of the P,S-chelating thioamides. The reactions of with [AuCl(tht)] (tht = tetrahydrothiophene) afford the expected gold(i)-phosphine complexes, [AuCl(L-κP)], containing uncoordinated (thio)amide moieties. Hemilabile coordination of the phosphinoamide ligands in complexes with the soft Group 11 metal ions is established by the crystal structure of a solvento complex, [Cu(-κ(2)O,P)(-κP)(CHCl3-κCl)][BF4], which was isolated serendipitously during an attempted crystallisation of [Cu(-κ(2)O,P)2][BF4]. All of the compounds are characterised by spectroscopic methods, and the structures of several representatives of both the free phosphinoamides and their complexes are determined by X-ray diffraction analysis and further studied by DFT calculations and cyclic voltammetry.

  4. Insertion of functional groups into a Nd3+ metal-organic framework via single-crystal-to-single-crystal coordinating solvent exchange.

    Science.gov (United States)

    Manos, Manolis J; Kyprianidou, Eleni J; Papaefstathiou, Giannis S; Tasiopoulos, Anastasios J

    2012-06-04

    Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or tune the properties of the materials via the postsynthetic introduction of suitable guest molecules or organic functional groups into their structures. Here, we describe UCY-2, a new flexible Nd(3+) metal-organic framework (MOF), which exhibits a unique capability to undergo a plethora of SCSC transformations with some of them being very uncommon. These structural alterations involve the replacement of coordinating solvent molecules of UCY-2 by terminally ligating solvents and organic ligands with multiple functional groups including -OH, -SH, -NH-, and -NH(2) or their combinations, chelating ligands, anions, and two different organic compounds. The SCSC coordinating solvent exchange is thus demonstrated as a powerful method for the functionalization of MOFs.

  5. Dynamical Mean-Field Theory Plus Numerical Renormalization-Group Study of Spin-Orbital Separation in a Three-Band Hund Metal.

    Science.gov (United States)

    Stadler, K M; Yin, Z P; von Delft, J; Kotliar, G; Weichselbaum, A

    2015-09-25

    We show that the numerical renormalization group is a viable multi-band impurity solver for dynamical mean-field theory (DMFT), offering unprecedented real-frequency spectral resolution at arbitrarily low energies and temperatures. We use it to obtain a numerically exact DMFT solution to the Hund metal problem for a three-band model on a Bethe lattice at 1/3 filling. The ground state is a Fermi liquid. The one-particle spectral function undergoes a coherence-incoherence crossover with increasing temperature, with spectral weight being transferred from low to high energies. Further, it exhibits a strong particle-hole asymmetry. In the incoherent regime, the self-energy displays approximate power-law behavior for positive frequencies only. The spin and orbital spectral functions show "spin-orbital separation": spin screening occurs at much lower energies than orbital screening. The renormalization group flows clearly reveal the relevant physics at all energy scales.

  6. Performance of the TPSS Functional on Predicting Core Level Binding Energies of Main Group Elements Containing Molecules: A Good Choice for Molecules Adsorbed on Metal Surfaces.

    Science.gov (United States)

    Pueyo Bellafont, Noèlia; Viñes, Francesc; Illas, Francesc

    2016-01-12

    Here we explored the performance of Hartree-Fock (HF), Perdew-Burke-Ernzerhof (PBE), and Tao-Perdew-Staroverov-Scuseria (TPSS) functionals in predicting core level 1s binding energies (BEs) and BE shifts (ΔBEs) for a large set of 68 molecules containing a wide variety of functional groups for main group elements B → F and considering up to 185 core levels. A statistical analysis comparing with X-ray photoelectron spectroscopy (XPS) experiments shows that BEs estimations are very accurate, TPSS exhibiting the best performance. Considering ΔBEs, the three methods yield very similar and excellent results, with mean absolute deviations of ∼0.25 eV. When considering relativistic effects, BEs deviations drop approaching experimental values. So, the largest mean percentage deviation is of 0.25% only. Linear trends among experimental and estimated values have been found, gaining offsets with respect to ideality. By adding relativistic effects to offsets, HF and TPSS methods underestimate experimental values by solely 0.11 and 0.05 eV, respectively, well within XPS chemical precision. TPSS is posed as an excellent choice for the characterization, by XPS, of molecules on metal solid substrates, given its suitability in describing metal substrates bonds and atomic and/or molecular orbitals.

  7. STUDENTS’ DECISION STEPS IN META-COGNITIVE LEARNING IN FREE ONLINE GROUPS (METAL-FROG: A Case Study

    Directory of Open Access Journals (Sweden)

    Kinsley Ng SEN FA

    2011-01-01

    Full Text Available What prompts the students to respond in online dialogic discussion? Why some students chose to fall out? This case study through the lens of phenomenography observation attempts to explain the five decision steps of students to respond in Meta-cognitive Learning in Free Online Groups (MetaL-FrOG discussion. It presents a part of a research project by the name of Triarchy Perspective on Meta-cognitive Learning in Free Online Groups. The research setting was online learner community on the platform of Free Online Group web intended for post-graduate students enrolled for the paper Psychology of Learning in Faculty of Education, University Malaya, Malaysia. Preliminary study revealed three factors contributed to MetaL-FrOG success: Motivation, Cognitive Resources and Pro-learning Behaviors. This paper only presents a part of the findings under the Pro-Learning Behaviors Sub-theory. We found striking similarities between the model proposed by Latane & Darley (1971, Five Essential Steps to a Pro-social Response in an Emergency, and our research subject. The model which explains the course of a pro-social decision was borrowed and modified as surrogate theory to explain the online discussion response of the students. The insights help educators to better understand what holds students back from fruitful online peer diologic discussion.

  8. Renormalization Group Approach to the X-Ray Absorption Problem and Application to the Vigman-Finkelshtein Model for Magnetic Impurities in Metals.

    Science.gov (United States)

    Nunes de Oliveira, Luiz

    The renormalization group techniques developed by Wilson for the Kondo problem are applied to three related problems: the absorption of x-rays by metals, the absorption of x-rays by impurities in metals, and the specific heat of dilute magnetic alloys. In the first problem considered, the x-ray absorption problem, the metal is represented by a half-filled conduction band and a deep level representing a core state. The absorption of an x-ray photon excites an electron from this core level to the conduction band creating a core hole whose positive charge interacts with the conduction electrons. The absorption spectrum is, for the first time, calculated in the energy range 10('-10)D ) (omega)(,T)) expression to seven decimal places; the prefactor (mu)(,o) is calculated for the first time. For (omega)-(omega)(,T) (TURNEQ) D, remarkably small deviations (e.g., deviations of 15% for (omega)-(omega)(,T) = .3D) from the Nozieres-De Dominicis power law are found. As a second application of the renormalization group techniques, the x-ray absorption spectrum for the resonant level model for impurities in metals is calculated. In this model, the metal is represented by a half-filled conduction band and the impurity by two levels: a core level from which an electron is excited to the conduction band by the absorption of an x-ray photon, and a resonant level, coupled to the conduction electrons, whose energy is lowered by the interaction with the core hole created by the absorption of the x-ray. In the x-ray absorption process, the resonant level is thus shifted to lower energy. The absorption spectrum approaches a power law in the energy range (omega)-(omega)(,T) >> (GAMMA), where (GAMMA) is the width of the resonant level, and a different power law in the range (omega)-(omega)(,T) body effect found in the spectrum of certain systems having a discrete level coupled to a continuum of energies) is elaborated. The problem of the specific heat of dilute magnetic alloys is attacked

  9. SN 2000cx and SN 2013bh: Extremely Rare, Nearly Twin Type Ia Supernovae

    CERN Document Server

    Silverman, Jeffrey M; Kasliwal, Mansi M; Fox, Ori D; Cao, Yi; Johansson, Joel; Perley, Daniel A; Tal, David; Wheeler, J Craig; Amanullah, Rahman; Arcavi, Iair; Bloom, Joshua S; Gal-Yam, Avishay; Goobar, Ariel; Kulkarni, Shrinivas R; Laher, Russ; Lee, William H; Marion, G H; Nugent, Peter E; Shivvers, Isaac

    2013-01-01

    The Type Ia supernova (SN Ia) SN 2000cx was one of the most peculiar transients ever discovered. While its rise to maximum brightness was typical for a SN Ia, its decline was slower, causing standard light curve fitting algorithms to fail; its spectra indicated a high photospheric temperature. Thirteen years later SN 2013bh (aka iPTF13abc), the first near identical twin of SN 2000cx, was discovered. We obtained optical and near-IR photometry and low-resolution optical spectroscopy of this object from discovery until about 1 month past r-band maximum brightness. The spectra of both objects indicate the presence of iron-group elements (Co II, Ni II, Fe II, Fe III, and high-velocity features [HVFs] of Ti II), intermediate-mass elements (Si II, Si III, and S II), in addition to separate normal velocity features (~12000 km/s) and HVFs (~24000 km/s) of Ca II. Persistent absorption from Fe III and Si III, along with the colour evolution, imply relatively high blackbody temperatures for SNe 2013bh and 2000cx (~12000 ...

  10. Low temperature hydrogenolysis of waxes to diesel range gasoline and light alkanes: Comparison of catalytic properties of group 4, 5 and 6 metal hydrides supported on silica-alumina

    KAUST Repository

    Norsic, Sébastien

    2012-01-01

    A series of metal hydrides (M = Zr, Hf, Ta, W) supported on silica-alumina were studied for the first time in hydrogenolysis of light alkanes in a continuous flow reactor. It was found that there is a difference in the reaction mechanism between d 0 metal hydrides of group 4 and d 0 ↔ d 2 metal hydrides of group 5 and group 6. Furthermore, the potential application of these catalysts has been demonstrated by the transformation of Fischer-Tropsch wax in a reactive distillation set-up into typical gasoline and diesel molecules in high selectivity (up to 86 wt%). Current results show that the group 4 metal hydrides have a promising yield toward liquid fuels.

  11. The Dwarf Starburst Host Galaxy of a Type Ia SN at z = 1.55 from CANDELS

    CERN Document Server

    Frederiksen, Teddy F; Maund, Justyn R; Rodney, Steven A; Riess, Adam G; Dahlen, Tomas; Mobasher, Bahram

    2012-01-01

    We present VLT/X-shooter observations of a high redshift, type Ia supernova host galaxy, discovered with HST/WFC3 as part of the CANDELS Supernova project. The galaxy exhibits strong emission lines of Ly{\\alpha}, [O II], H{\\beta}, [O III], and H{\\alpha} at z = 1.54992(+0.00008-0.00004). From the emission-line fluxes and SED fitting of broad-band photometry we rule out AGN activity and characterize the host galaxy as a young, low mass, metal poor, starburst galaxy with low intrinsic extinction and high Ly{\\alpha} escape fraction. The host galaxy stands out in terms of the star formation, stellar mass, and metallicity compared to its lower redshift counterparts, mainly because of its high specific star-formation rate. If valid for a larger sample of high-redshift SN Ia host galaxies, such changes in the host galaxy properties with redshift are of interest because of the potential impact on the use of SN Ia as standard candles in cosmology.

  12. Influence of metal loading and humic acid functional groups on the complexation behavior of trivalent lanthanides analyzed by CE-ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Kautenburger, Ralf, E-mail: r.kautenburger@mx.uni-saarland.de [Institute of Inorganic Solid State Chemistry, Saarland University, Campus Dudweiler, Am Markt Zeile 3-5, D-66125 Saarbrücken (Germany); Hein, Christina; Sander, Jonas M. [Institute of Inorganic Solid State Chemistry, Saarland University, Campus Dudweiler, Am Markt Zeile 3-5, D-66125 Saarbrücken (Germany); Beck, Horst P. [Institute of Inorganic and Analytical Chemistry and Radiochemistry, Saarland University, Campus Dudweiler, Am Markt Zeile 5, D-66125 Saarbrücken (Germany)

    2014-03-01

    Highlights: • Free and complexed HA-Ln species are separated by CE-ICP-MS. • Weaker and stronger HA-binding sites for Ln-complexation can be detected. • Complexation by original and modified humic acid (HA) with blocked phenolic hydroxyl- and carboxyl-groups is compared. • Stronger HA-binding sites for Ln³⁺ can be assumed as chelating complexes. • Chelates consist of trivalent Ln and a combination of both OH- and COOH-groups. Abstract: The complexation behavior of Aldrich humic acid (AHA) and a modified humic acid (AHA-PB) with blocked phenolic hydroxyl groups for trivalent lanthanides (Ln) is compared, and their influence on the mobility of Ln(III) in an aquifer is analyzed. As speciation technique, capillary electrophoresis (CE) was hyphenated with inductively coupled plasma mass spectrometry (ICP-MS). For metal loading experiments 25 mg L⁻¹ of AHA and different concentrations (c Ln(Eu+Gd)} = 100–6000 μg L⁻¹) of Eu(III) and Gd(III) in 10 mM NaClO₄ at pH 5 were applied. By CE-ICP-MS, three Ln-fractions, assumed to be uncomplexed, weakly and strongly AHA-complexed metal can be detected. For the used Ln/AHA-ratios conservative complex stability constants log βLnAHA decrease from 6.33 (100 μg L⁻¹ Ln³⁺) to 4.31 (6000 μg L⁻¹ Ln³⁺) with growing Ln-content. In order to verify the postulated weaker and stronger humic acid binding sites for trivalent Eu and Gd, a modified AHA with blocked functional groups was used. For these experiments 500 μg L⁻¹ Eu and 25 mg L⁻¹ AHA and AHA-PB in 10 mM NaClO₄ at pH-values ranging from 3 to 10 have been applied. With AHA-PB, where 84% of the phenolic OH-groups and 40% of the COOH-groups were blocked, Eu complexation was significantly lower, especially at the strong binding sites. The log β-values decrease from 6.11 (pH 10) to 5.61 at pH 3 (AHA) and for AHA-PB from 6.01 (pH 7) to 3.94 at pH 3. As a potential consequence, particularly humic acids with a high amount of

  13. Role of the metal cation types around VO4 groups on the nonlinear optical behavior of materials: experimental and theoretical analysis.

    Science.gov (United States)

    Su, Xin; Yang, Zhihua; Han, Guopeng; Wang, Ying; Wen, Ming; Pan, Shilie

    2016-09-28

    In order to explore new NLO crystals with superior performances, it is greatly desirable to understand the intrinsic relationship between the macroscopic optical properties and microscopic structural features in crystals. A novel mechanism for nonlinear optical (NLO) effects of vanadate crystals, Li3VO4, KCd4(VO4)3 and Ca3(VO4)2 with distorted (VO4)(3-) groups, has been investigated. Experiments related to the synthesis and structures were determined. In addition, infrared and UV-Vis-NIR diffuse reflectance spectroscopy, as well as electronic band structure calculations, were performed on the reported materials. A comprehensive analysis for the structure-property relationship is given by combining the experimental measurements, the electronic structure calculations and the SHG-weighted electron density to the linear and NLO properties. It was found that the contribution of the (VO4)(3-) anionic group to the second harmonic generation (SHG) response was the dominant anionic group, which plays a vital role to the SHG effects in Li3VO4, KCd4(VO4)3 and Ca3(VO4)2. It was also concluded that the metal cation types and coordination around VO4 groups, the distorted and parallel oriented VO4 tetrahedron decided the SHG coefficient values.

  14. IA-Automorphisms of Permutational Wreath Products

    Institute of Scientific and Technical Information of China (English)

    John Panagopoulos

    2001-01-01

    Let W be the permutational wreath product of two groups A and B.In this paper, we study the relationship between the semicompleteness of W and the semicompleteness of A and B. In the general case, we give some necessary conditions for the semicompleteness of the group W. In the case of finite groups A and B with A abelian, we give necessary and sufficient conditions under which the group W is semicomplete.

  15. Thematic trip: "Save Roşia MontanÄă"

    Science.gov (United States)

    Eugenia, Marcu

    2015-04-01

    The name Roşia Montană, situated in Transylvania, became well known after a Romanian-Canadian company, Roşia Montană Gold Company (RMGC), obtained the concession license on exploitation for gold and silver minerals in the Roşia Montană area. The project consists of opening the largest surface gold mines in Europe using cyanide, which will include four open pits and a processing plant for gold and silver in The Roşia Valley and a tailings facility with an area of 367 hectares in the Corna Valley. One of the main fears is related to a possible ecological accident like the one in Baia Mare in 2000, when a tailing facility dam break led to cyanide pollution of Tisa and Danube rivers that resulted in the death of 1,200 tons of fish and contamination of water resources for 2 million people. This thematic trip is important for the scientific preparation of students and an opportunity to educate them in the spirit of environmental protection. The training and education of students will require assimilation and understanding, actively and consciously, using the knowledge acquired during the compulsory curriculum and training skills. REASON: The continuous degradation of the environment is a major crisis due to human intervention in nature, and the proposed Roşia Montană mining project will continue this trend. The company proposes to extract gold from mines by using the gold separation technique using cyanide, a process that involves destroying a total area of 16 km² which includes 5 mountains, 7 churches, 11 cemeteries and the ruins of Alburnus Maior Citadel, as well as creating pollution that would last for hundreds of years. The extraction of gold from low-grade ores using cyanide processes was estimated to result in a worldwide emission of 45,300 tons of hydrogen cyanide. Environmental education for a healthy life has children as target group, because they are the trustees and beneficiaries of tomorrow's natural resources and can influence the attitudes of

  16. SPECTROSCOPIC OBSERVATIONS OF SN 2012fr: A LUMINOUS, NORMAL TYPE Ia SUPERNOVA WITH EARLY HIGH-VELOCITY FEATURES AND A LATE VELOCITY PLATEAU

    Energy Technology Data Exchange (ETDEWEB)

    Childress, M. J.; Scalzo, R. A.; Sim, S. A.; Tucker, B. E.; Yuan, F.; Schmidt, B. P. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Cenko, S. B.; Filippenko, A. V. [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States); Silverman, J. M. [Department of Astronomy, University of Texas, Austin, TX 78712-0259 (United States); Contreras, C.; Hsiao, E. Y.; Phillips, M.; Morrell, N. [Las Campanas Observatory, Carnegie Observatories, Casilla 601, La Serena (Chile); Jha, S. W.; McCully, C. [Department of Physics and Astronomy, Rutgers, State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Anderson, J. P.; De Jaeger, T.; Forster, F. [Departamento de Astronomia, Universidad de Chile, Casilla 36-D, Santiago (Chile); Benetti, S. [INAF Osservatorio Astronomico di Padova, Vicolo dell' Osservatorio 5, I-35122 Padova (Italy); Bufano, F., E-mail: mjc@mso.anu.edu.au [Departamento de Ciencias Fisicas, Universidad Andres Bello, Avda. Republica 252, Santiago (Chile); and others

    2013-06-10

    We present 65 optical spectra of the Type Ia SN 2012fr, 33 of which were obtained before maximum light. At early times, SN 2012fr shows clear evidence of a high-velocity feature (HVF) in the Si II {lambda}6355 line that can be cleanly decoupled from the lower velocity ''photospheric'' component. This Si II {lambda}6355 HVF fades by phase -5; subsequently, the photospheric component exhibits a very narrow velocity width and remains at a nearly constant velocity of {approx}12,000 km s{sup -1} until at least five weeks after maximum brightness. The Ca II infrared triplet exhibits similar evidence for both a photospheric component at v Almost-Equal-To 12,000 km s{sup -1} with narrow line width and long velocity plateau, as well as an HVF beginning at v Almost-Equal-To 31,000 km s{sup -1} two weeks before maximum. SN 2012fr resides on the border between the ''shallow silicon'' and ''core-normal'' subclasses in the Branch et al. classification scheme, and on the border between normal and high-velocity Type Ia supernovae (SNe Ia) in the Wang et al. system. Though it is a clear member of the ''low velocity gradient'' group of SNe Ia and exhibits a very slow light-curve decline, it shows key dissimilarities with the overluminous SN 1991T or SN 1999aa subclasses of SNe Ia. SN 2012fr represents a well-observed SN Ia at the luminous end of the normal SN Ia distribution and a key transitional event between nominal spectroscopic subclasses of SNe Ia.

  17. Neutrino event counts from Type Ia supernova models

    Science.gov (United States)

    Nagaraj, Gautam; Scholberg, Kate

    2016-01-01

    Core collapse supernovae (SNe) are widely known to be among the universe's primary neutrino factories, releasing ˜99% of their energy, or ˜1053 ergs, in the form of the tiny leptons. On the other hand, less than 4% of the energy of Type Ia SNe is released via neutrinos, hence making Ia SNe impossible to detect (through neutrino observations) at typical supernova distances. For this reason, neutrino signatures from these explosions have very rarely been modeled. We ran time-sliced fluences from non-oscillation pure deflagration and delayed detonation (DDT) Ia models by Odrzywolek and Plewa (2011) through SNOwGLoBES, a software that calculates event rates and other observed quantities of supernova neutrinos in various detectors. We determined Ia neutrino event rates in Hyper-K, a proposed water Cherenkov detector, JUNO, a scintillator detector under construction, and DUNE, a proposed argon detector, and identified criteria to distinguish between the two models (pure deflagration and DDT) based on data from a real supernova (statistically represented by a Poisson distribution around the expected result). We found that up to distances of 8.00, 1.54, and 2.37 kpc (subject to change based on oscillation effects and modified detector efficiencies), we can discern the explosion mechanism with ≥90% confidence in Hyper-K, JUNO, and DUNE, respectively, thus learning more about Ia progenitors.

  18. Type Ia Supernovae from Merging White Dwarfs I. Prompt Detonations

    CERN Document Server

    Moll, Rainer; Kasen, Daniel; Woosley, Stan

    2013-01-01

    Merging white dwarfs are a possible progenitor of Type Ia supernovae (SNe Ia). While it is not entirely clear if and when an explosion is triggered in such systems, numerical models suggest that a detonation might be initiated before the stars have coalesced to form a single compact object. Here we study such "peri-merger" detonations by means of numerical simulations, modeling the disruption and nucleosynthesis of the stars until the ejecta reach the coasting phase. Synthetic light curves and spectra are generated for comparison with observations. Three models are considered with primary masses 0.96 Msun, 1.06 Msun, and 1.20 Msun. Of these, the 0.96 Msun dwarf merging with an 0.81 Msun companion, with a Ni56 yield of 0.58 Msun, is the most promising candidate for reproducing common SNe Ia. The more massive mergers produce unusually luminous SNe Ia with peak luminosities approaching those attributed to "super-Chandrasekhar" mass SNe Ia. While the synthetic light curves and spectra of some of the models resemb...

  19. Spectroscopy of Type Ia Supernovae by the Carnegie Supernova Project

    CERN Document Server

    Folatelli, Gastón; Phillips, Mark M; Hsiao, Eric; Campillay, Abdo; Contreras, Carlos; Castellón, Sergio; Hamuy, Mario; Krzeminski, Wojtek; Roth, Miguel; Stritzinger, Maximilian; Burns, Christopher R; Freedman, Wendy L; Madore, Barry F; Murphy, David; Persson, S E; Prieto, José L; Suntzeff, Nicholas B; Krisciunas, Kevin; Anderson, Joseph P; Förster, Francisco; Maza, José; Pignata, Giuliano; Rojas, P Andrea; Boldt, Luis; Salgado, Francisco; Wyatt, Pamela; E., Felipe Olivares; Gal-Yam, Avishay; Sako, Masao

    2013-01-01

    This is the first release of optical spectroscopic data of low-redshift Type Ia supernovae (SNe Ia) by the Carnegie Supernova Project including 604 previously unpublished spectra of 93 SNe Ia. The observations cover a range of phases from 12 days before to over 150 days after the time of B-band maximum light. With the addition of 228 near-maximum spectra from the literature we study the diversity among SNe Ia in a quantitative manner. For that purpose, spectroscopic parameters are employed such as expansion velocities from spectral line blueshifts, and pseudo-equivalent widths (pW). The values of those parameters at maximum light are obtained for 78 objects, thus providing a characterization of SNe Ia that may help to improve our understanding of the properties of the exploding systems and the thermonuclear flame propagation. Two objects, namely SNe 2005M and 2006is, stand out from the sample by showing peculiar Si II and S II velocities but otherwise standard velocities for the rest of the ions. We further s...

  20. SN IA in the IR: RAISIN A progress report

    Science.gov (United States)

    Kirshner, Robert P.; The RAISIN TEAM

    2014-01-01

    SN Ia have proven to be a powerful tool for cosmology. Near-IR observations of SN Ia promise even better results because the supernovae are more nearly standard candles at those wavelengths and absorption by dust is diminished by a factor of 4 compared to rest-frame B-band observations. Near IR observations of cosmologically-distant SN Ia discovered with PanSTARRS are underway using the infrared camera on the Hubble Space Telescope (GO-13046). These targets are discovered in the difference images created in the CfA/JHU pipeline, confirmed spectroscopically at the MMT, Magellan, Gemini, or Keck, and inserted in a non-disruptive way into the HST observing schedule for WFC3-IR. We have observed over 20 SN Ia in the range 0.2 color and reddening by dust. Since SN IA behave better in the IR in both these ways, there is reason to expect that this approach will be effective in driving down the systematic errors over time. If we are diligent in building up the size of the sample that is observed in the rest-frame infrared, we can expect more certain knowledge of the properties of dark energy. Unsolved problems include constructing precise K-corrections and firming up the fundamental photometric system in y, J, H, and K, but this approach seems a promising one for the HST era now, JWST soon, and WFIRST in good time.

  1. Type Ia Supernovae, Evolution and the Cosmological Constant

    CERN Document Server

    Drell, P S; Wasserman, I M; Drell, Persis S.; Loredo, Thomas J.; Wasserman, Ira

    2000-01-01

    We explore the possible role of evolution in the analysis of data on SNe Ia at cosmological distances. First, using a variety of simple sleuthing techniques, we find evidence that the properties of the high and low redshift SNe Ia observed so far differ from one another. Next, we examine the effects of including simple phenomenological models for evolution in the analysis. The result is that cosmological models and evolution are highly degenerate with one another, so that the incorporation of even very simple models for evolution makes it virtually impossible to pin down the values of $\\Omega_M$ and cosmological constant, respectively. Moreover, we show that if SNe Ia evolve with time, but evolution is neglected in analyzing data, then, given enough SNe Ia, the analysis hones in on values of $\\Omega_M$ and $\\Omega_\\Lambda$ which are incorrect. Using Bayesian methods, we show that the probability that the cosmological constant is nonzero (rather than zero) is unchanged by the SNe Ia data when one accounts for ...

  2. Cosmological Inference from Host-Selected Type Ia Supernova Samples

    Science.gov (United States)

    Uddin, Syed A.; Mould, Jeremy; Lidman, Chris; Ruhlmann-Kleider, Vanina; Hardin, Delphine

    2017-01-01

    We compare two Type Ia supernova samples that are drawn from a spectroscopically confirmed Type Ia supernova sample: a host-selected sample in which SNe Ia are restricted to those that have a spectroscopic redshift from the host; and a broader, more traditional sample in which the redshift could come from either the SN or the host. The host-selected sample is representative of SN samples that will use the redshift of the host to infer the SN redshift, long after the SN has faded from view. We find that SNe Ia that are selected on the availability of a redshift from the host differ from SNe Ia that are from the broader sample. The former tend to be redder, have narrower light curves, live in more massive hosts, and tend to be at lower redshifts. We find that constraints on the equation of state of dark energy, w, and the matter density, ΩM, remain consistent between these two types of samples. Our results are important for ongoing and future supernova surveys, which unlike previous supernova surveys, will have limited real-time follow-up to spectroscopically classify the SNe they discover. Most of the redshifts in these surveys will come from the hosts.

  3. Using Spectral Flux Ratios to Standardize SN Ia Luminosities

    CERN Document Server

    Bailey, S; Antilogus, P; Aragon, C; Baltay, C; Bongard, S; Buton, C; Childress, M; Chotard, N; Copin, Y; Gangler, E; Loken, S; Nugent, P; Pain, R; Pécontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Rigaudier, G; Runge, K; Scalzo, R; Smadja, G; Swift, H; Tao, C; Thomas, R C; Wu, C

    2009-01-01

    We present a new method to standardize Type Ia supernova (SN Ia) luminosities to ~<0.13 magnitudes using flux ratios from a single flux-calibrated spectrum per SN. Using Nearby Supernova Factory spectrophotomery of 58 SNe Ia, we performed an unbiased search for flux ratios which correlate with SN Ia luminosity. After developing the method and selecting the best ratios from a training sample, we verified the results on a separate validation sample and with data from the literature. We identified multiple flux ratios whose correlations with luminosity are stronger than those of light curve shape and color, previously identified spectral feature ratios, or equivalent width measurements. In particular, the flux ratio R(642/443) = F(642 nm) / F(443 nm) has a correlation of 0.95 with SN Ia absolute magnitudes. Using this single ratio as a correction factor produces a Hubble diagram with a residual scatter standard deviation of 0.125 +- 0.011 mag, compared with 0.161 +- 0.015 mag when fit with the SALT2 light cur...

  4. What sodium absorption lines tell us about type Ia supernovae

    CERN Document Server

    Soker, Noam

    2014-01-01

    We propose that the sodium responsible for the variable Na I D absorption lines in some type Ia supernovae (SN Ia) originate from dust residing at ~1pc from the supernovae. In this Na-from-dust absorption (NaDA) model the process by which the SN Ia peak luminosity releases sodium from dust at ~1pc from the SN is similar to the processes by which solar radiation releases sodium from comet dust when comets approach a distance of ~1AU from the Sun. The dust grains are not sublimated but rather stay intact, and release sodium by photon-stimulated desorption (PSD; or photo-sputtering). We apply the NaDA model to SN 2006X and SN 2007le, and find it to comply better with the observed time variability of the Na I D absorption lines than the Na recombination model. The mass in the dusty shell of the NaDA model is much too high to be accounted for in the single-degenerate scenario for SN Ia. Therefore, the presence of variable Na I D lines in some SN Ia further weakens the already very problematic single-degenerate sce...

  5. SDSS-II Supernova survey. An analysis of the largest sample of type IA supernovae and correlations with host-galaxy spectral properties

    Energy Technology Data Exchange (ETDEWEB)

    Wolf, Rachel C.; D’Andrea, Chris B.; Gupta, Ravi R.; Sako, Masao; Fischer, John A.; Kessler, Rick; Jha, Saurabh W.; March, Marisa C.; Scolnic, Daniel M.; Fischer, Johanna-Laina; Campbell, Heather; Nichol, Robert C.; Olmstead, Matthew D.; Richmond, Michael; Schneider, Donald P.; Smith, Mathew

    2016-04-20

    Using the largest single-survey sample of Type Ia supernovae (SNe Ia) to date, we study the relationship between properties of SNe Ia and those of their host galaxies, focusing primarily on correlations with Hubble residuals (HR). Our sample consists of 345 photometrically-classified or spectroscopicallyconfirmed SNe Ia discovered as part of the SDSS-II Supernova Survey (SDSS-SNS). This analysis utilizes host-galaxy spectroscopy obtained during the SDSS-I/II spectroscopic survey and from an ancillary program on the SDSS-III Baryon Oscillation Spectroscopic Survey (BOSS) that obtained spectra for nearly all host galaxies of SDSS-II SN candidates. In addition, we use photometric hostgalaxy properties from the SDSS-SNS data release (Sako et al. 2014) such as host stellar mass and star-formation rate. We confirm the well-known relation between HR and host-galaxy mass and find a 3.6σ significance of a non-zero linear slope. We also recover correlations between HR and hostgalaxy gas-phase metallicity and specific star-formation rate as they are reported in the literature. With our large dataset, we examine correlations between HR and multiple host-galaxy properties simultaneously and find no evidence of a significant correlation. We also independently analyze our spectroscopically-confirmed and photometrically-classified SNe Ia and comment on the significance of similar combined datasets for future surveys.

  6. Preparation and characterization of novel P(HEA/IA) hydrogels for Cd{sup 2+} ion removal from aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Antić, Katarina M.; Babić, Marija M.; Vuković, Jovana J. Jovašević [Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade (Serbia); Vasiljević-Radović, Dana G. [Institute for Chemistry, Technology and Metallurgy, University of Belgrade, Njegoseva 12, Belgrade (Serbia); Onjia, Antonije E. [Vinca Institute of Nuclear Sciences, University of Belgrade, P.O. Box 522, Belgrade (Serbia); Filipović, Jovanka M. [Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade (Serbia); Tomić, Simonida Lj., E-mail: simonida@tmf.bg.ac.rs [Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade (Serbia)

    2015-05-30

    Highlights: • Hydrogels based on 2-hydroxyethyl acrylate and itaconic acid (P(HEA/IA)) were synthesized. • Cd{sup 2+} ion removal was investigated. • The surface and cross-section of hydrogels were observed by SEM and AFM. • The adsorption kinetics and isotherms of cadmium ions on the hydrogel were studied. • Approximately 95% of the adsorbed cadmium could be recovered by 0.1 M HNO{sub 3} treatment. - Abstract: Series of novel hydrogels based on 2-hydroxyethyl acrylate (HEA) and itaconic acid (IA), P(HEA/IA) copolymers, were prepared by free radical cross-linking copolymerization and investigated as potential adsorbents for Cd{sup 2+} removal from aqueous solution. The hydrogels before and after Cd{sup 2+} adsorption were characterized using FTIR, DSC, SEM/EDX, AFM and DMA analysis. The swelling results showed that these hydrogels are pH and temperature sensitive. In order to evaluate adsorption behavior of samples various factors affecting the Cd{sup 2+} uptake behavior, such as: contact time, temperature, pH, ionic strength, adsorbent weight, competitive ions and initial concentration of the metal ions were investigated. Five adsorption isotherms and two kinetic models were studied. The adsorption behavior can be very well described by the pseudo-second order kinetic model and Langmuir isotherm. Multicomponent adsorption studies revealed that adsorption of cadmium depends on the type of metal ions present in the system. Desorption studies showed that hydrogel can be reused three times with only 15% loss of adsorption capacity. All results indicate that the sample with the highest IA content is the most promising adsorbent for Cd{sup 2+} removal.

  7. Inhibition of Zn(II binding type IA topoisomerases by organomercury compounds and Hg(II.

    Directory of Open Access Journals (Sweden)

    Bokun Cheng

    Full Text Available Type IA topoisomerase activities are essential for resolving DNA topological barriers via an enzyme-mediated transient single strand DNA break. Accumulation of topoisomerase DNA cleavage product can lead to cell death or genomic rearrangement. Many antibacterial and anticancer drugs act as topoisomerase poison inhibitors that form stabilized ternary complexes with the topoisomerase covalent intermediate, so it is desirable to identify such inhibitors for type IA topoisomerases. Here we report that organomercury compounds were identified during a fluorescence based screening of the NIH diversity set of small molecules for topoisomerase inhibitors that can increase the DNA cleavage product of Yersinia pestis topoisomerase I. Inhibition of relaxation activity and accumulation of DNA cleavage product were confirmed for these organomercury compounds in gel based assays of Escherichia coli topoisomerase I. Hg(II, but not As(III, could also target the cysteines that form the multiple Zn(II binding tetra-cysteine motifs found in the C-terminal domains of these bacterial topoisomerase I for relaxation activity inhibition. Mycobacterium tuberculosis topoisomerase I activity is not sensitive to Hg(II or the organomercury compounds due to the absence of the Zn(II binding cysteines. It is significant that the type IA topoisomerases with Zn(II binding domains can still cleave DNA when interfered by Hg(II or organomercury compounds. The Zn(II binding domains found in human Top3α and Top3β may be potential targets of toxic metals and organometallic complexes, with potential consequence on genomic stability and development.

  8. Hubble Residuals of Nearby SN Ia Are Correlated with Host Galaxy Masses

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, Patrick L.; /KIPAC, Menlo Park /SLAC; Hicken, Malcolm; /Harvard-Smithsonian Ctr. Astrophys.; Burke, David L.; /KIPAC, Menlo Park /SLAC; Mandel, Kaisey S.; Kirshner, Robert P.; /Harvard-Smithsonian Ctr. Astrophys.

    2010-05-03

    From Sloan Digital Sky Survey u{prime} g{prime} r{prime} i{prime} z{prime} imaging, we estimate the stellar masses of the host galaxies of 70 low redshift SN Ia (0.015 < z < 0.08) from the hosts absolute luminosities and mass-to-light ratios. These nearby SN were discovered largely by searches targeting luminous galaxies, and we find that their host galaxies are substantially more massive than the hosts of SN discovered by the flux-limited Supernova Legacy Survey. Testing four separate light curve fitters, we detect {approx}2.5{sigma} correlations of Hubble residuals with both host galaxy size and stellar mass, such that SN Ia occurring in physically larger, more massive hosts are {approx}10% brighter after light curve correction. The Hubble residual is the deviation of the inferred distance modulus to the SN, calculated from its apparent luminosity and light curve properties, away from the expected value at the SN redshift. Marginalizing over linear trends in Hubble residuals with light curve parameters shows that the correlations cannot be attributed to a light curve-dependent calibration error. Combining 180 higher-redshift ESSENCE, SNLS, and HigherZ SN with 30 nearby SN whose host masses are less than 10{sup 10.8} M{circle_dot} n a cosmology fit yields 1 + w = 0.22{sub -0.108}{sup +0.152}, while a combination where the 30 nearby SN instead have host masses greater than 10{sup 10.8} M{circle_dot} yields 1 + w = ?0.03{sub -0.143}{sup +0.217}. Progenitor metallicity, stellar population age, and dust extinction correlate with galaxy mass and may be responsible for these systematic effects. Host galaxy measurements will yield improved distances to SN Ia.

  9. Group 11 Metal Compounds with Tripodal Bis(imidazole Thioether Ligands. Applications as Catalysts in the Oxidation of Alkenes and as Antimicrobial Agents

    Directory of Open Access Journals (Sweden)

    Armando Varela-Ramírez

    2011-08-01

    Full Text Available New group 11 metal complexes have been prepared using the previously described tripodal bis(imidazole thioether ligand (N-methyl-4,5-diphenyl-2-imidazolyl2C(OMeC(CH32S(tert-Bu ({BITOMe,StBu}, 2. The pincer ligand offers a N2S donor atom set that can be used to coordinate the group 11 metals in different oxidation states [AuI, AuIII, AgI, CuI and CuII]. Thus the new compounds [Au{BITOMe,StBu}Cl][AuCl4]2 (3, [Au{BITOMe,StBu}Cl] (4, [Ag{BITOMe,StBu}X] (X = OSO2CF3- 5, PF6- 6 and [Cu{BITOMe,StBu}Cl2] (7 have been synthesized from reaction of 2 with the appropriate metal precursors, and characterized in solution. While attempting characterization in the solid state of 3, single crystals of the neutral dinuclear mixed AuIII-AuI species [Au2{BITOMe,S}Cl3] (8 were obtained and its crystal structure was determined by X-ray diffraction studies. The structure shows a AuIII center coordinated to the pincer ligand through one N and the S atom. The soft AuI center coordinates to the ligand through the same S atom that has lost the tert-butyl group, thus becoming a thiolate ligand. The short distance between the AuI-AuIII atoms (3.383 Å may indicate a weak metal-metal interaction. Complexes 2-7 and the previously described CuI compound [Cu{BITOMe,StBu}]PF6 (9 have been evaluated in the oxidation of biphenyl ethylene with tert-butyl hydrogen peroxide (TBHP as the oxidant. Results have shown that the AuI and AgI complexes 4 and 6 (at 10 mol % loading are the more active catalysts in this oxidative cleavage. The antimicrobial activity of compounds 2-5, 7 and 9 against Gram-positive and Gram-negative bacteria and yeast has also been evaluated. The new gold and silver compounds display moderate to high antibacterial activity, while the copper derivatives are mostly inactive. The gold and silver complexes were also potent against fungi. Their cytotoxic properties have been analyzed in vitro utilizing HeLa human cervical carcinoma cells. The compounds displayed a

  10. Group 11 Metal Compounds with Tripodal Bis(imidazole) Thioether Ligands. Applications as Catalysts in the Oxidation of Alkenes and as Antimicrobial Agents.

    Science.gov (United States)

    Liu, Fangwei; Anis, Reema; Hwang, Eunmi; Ovalle, Rafael; Varela-Ramírez, Armando; Aguilera, Renato J; Contel, María

    2011-08-08

    New group 11 metal complexes have been prepared using the previously described tripodal bis(imidazole) thioether ligand (N-methyl-4,5-diphenyl-2-imidazolyl)2C(OMe)C(CH3)2S(tert-Bu) ({BITOMe,StBu}, 2). The pincer ligand offers a N2S donor atom set that can be used to coordinate the group 11 metals in different oxidation states [AuI, AuIII, AgI, CuI and CuII]. Thus the new compounds [Au{BITOMe,StBu}Cl][AuCl4]2 (3), [Au{BITOMe,StBu}Cl] (4), [Ag{BITOMe,StBu}X] (X = OSO2CF3- 5, PF6- 6) and [Cu{BITOMe,StBu}Cl2] (7) have been synthesized from reaction of 2 with the appropriate metal precursors, and characterized in solution. While attempting characterization in the solid state of 3, single crystals of the neutral dinuclear mixed AuIII-AuI species [Au2{BITOMe,S}Cl3] (8) were obtained and its crystal structure was determined by X-ray diffraction studies. The structure shows a AuIII center coordinated to the pincer ligand through one N and the S atom. The soft AuI center coordinates to the ligand through the same S atom that has lost the tert-butyl group, thus becoming a thiolate ligand. The short distance between the AuI-AuIII atoms (3.383 Å) may indicate a weak metal-metal interaction. Complexes 2-7 and the previously described CuI compound [Cu{BITOMe,StBu}]PF6 (9) have been evaluated in the oxidation of biphenyl ethylene with tert-butyl hydrogen peroxide (TBHP) as the oxidant. Results have shown that the AuI and AgI complexes 4 and 6 (at 10 mol % loading) are the more active catalysts in this oxidative cleavage. The antimicrobial activity of compounds 2-5, 7 and 9 against Gram-positive and Gram-negative bacteria and yeast has also been evaluated. The new gold and silver compounds display moderate to high antibacterial activity, while the copper derivatives are mostly inactive. The gold and silver complexes were also potent against fungi. Their cytotoxic properties have been analyzed in vitro utilizing HeLa human cervical carcinoma cells. The compounds displayed a very

  11. Study on separation of platinum group metals from high level liquid waste using macroporous (MOTDGA-TOA)/SiO{sub 2}-P silica-based absorbent

    Energy Technology Data Exchange (ETDEWEB)

    Ito, Tatsuya [Department of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University, Aoba 6-6, Aramaki, Aoba-ku, Sendai, Miyagi 980-8579 (Japan); Japan Atomic Energy Agency, Tokai-mura Naka-gun, Ibarak319-1195 (Japan); Kim, Seong-Yun; Xu, Yuanlai; Hitomi, Keitaro [Cyclotron and Radioisotope Center, Tohoku University, Aoba 6-3, Aramaki, Aoba-ku, Sendai, Miyagi 980-8578 (Japan); Ishii, Keizo [Department of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University, Aoba 6-6, Aramaki, Aoba-ku, Sendai, Miyagi 980-8579 (Japan); Nagaishi, Ryuji; Kimura, Takaumi [Japan Atomic Energy Agency, Tokai-mura Naka-gun, Ibarak319-1195 (Japan)

    2013-07-01

    The recovery of platinum group metals (PGMs) from high level liquid waste (HLLW) by macroporous silica-based adsorbent, (MOTDGA-TOA)/SiO{sub 2}-P has been developed by impregnating two extractants of N,N'-dimethyl-N,N'-di-n-octyl-thio-diglycolamide (MOTDGA) and tri-n-octylamine (TOA) into a silica/polymer composite support (SiO{sub 2}-P). The adsorption of Ru(III), Rh(III) and Pd(II) have been investigated in simulated HLLW by batch method. The adsorbent has shown good uptake property for Pd(II). In addition, the combined use of MOTDGA and TOA improved the adsorption of Ru(III) and Rh(III) better than the individual use of them. The usability of adsorbent in radiation fields was further confirmed by irradiation experiments. The adsorbent remained to have the uptake capability for PGMs over the absorbed dose of 100 kGy, corresponding with one really adsorbed by the adsorbent, and showed good retention capability for Pd(II) even at the absorbed dose of 800 kGy. The chromatographic separation of metal ions was demonstrated with the adsorbent packed column, there is no influence of Re(VII) (instead of Tc) on the excellent separation behavior of Pd(II). (authors)

  12. Ab Initio Research on a New Type of Half-Metallic Double Perovskites, A2CrMO6 (A = IVA Group Elements; M = Mo, Re and W

    Directory of Open Access Journals (Sweden)

    Yun-Ping Liu

    2014-03-01

    Full Text Available The research based on density functional theory was carried out using generalized gradient approximation (GGA for full-structural optimization and the addition of the correlation effect (GGA + U (Coulomb parameter in a double perovskite structure, A2BB’O6. According to the similar valance electrons between IIA(s2 and IVA(p2, IVA group elements instead of alkaline-earth elements settled on the A-site ion position with fixed BB' combinations as CrM (M = Mo, Re and W. The ferrimagnetic half-metallic (HM-FiM properties can be attributed to the p-d hybridization between the Crd-Mp and the double exchange. All the compounds can be half-metallic (HM materials, except Si2CrMoO6, Ge2CrMo and Ge2CrReO6, because the strong-correlation correction should be considered. For M = W, only A = Sn and Pb are possible candidates as HM materials. Nevertheless, an examination of the structural stability is needed, because Si, Ge, Sn and Pb are quite different from Sr. All compounds are stable, except for the Si-based double perovskite structure.

  13. Enhanced Retention of Chelating Reagents in Octadecylsilyl Silica Phase by Interaction with Residual Silanol Groups in Solid Phase Extraction of Divalent Metal Ions.

    Science.gov (United States)

    Ohmuro, Satoshi; Fujii, Kan; Yasui, Takashi; Takada, Kazutake; Yuchi, Akio; Kokusen, Hisao

    2016-01-01

    Solid-phase extraction (SPE) of divalent metal ions with a lipophilic and potentially divalent hexadentate chelating reagent (H2L), with which octadecylsilyl silica (ODS), was impregnated with was studied to gain more insight into and develop the potential of this methodology. This is the first time to demonstrate that this reagent as well as other common nitrogen-containing reagents were retained both by adsorption due to hydrogen bonding between nitrogen atoms of the reagent and residual silanol groups in the ODS phase and by simple distribution into the hydrophobic space. An appreciably large amount of this reagent could be retained by the adsorption mechanism even with a relatively thin loading solution. The divalent metal ions of Mn(2+), Co(2+) and Zn(2+) were extracted as 1:1 neutral complexes ([ML]), while Ni(2+) and Cu(2+) as ion-pairs of 1:1 cationic complex ([MHL](+)) with anion in SPE with H2L. The extractability and selectivity were substantially the same as that in liquid-liquid extraction.

  14. Platinum-group elements in the Eastern Deccan volcanic province and a comparison with platinum metals of the western Deccan

    Indian Academy of Sciences (India)

    James Crocket; Dalim Paul; Trisha Lala

    2013-08-01

    This study is the first detailed investigation of the platinum-group elements (PGE) at the eastern margin of the Deccan volcanic province of India. One of the PGE, osmium, is not included largely because of analytical problems. The study is focused on mafic volcanics and dykes from four areas including Amarkantak, Umaria, Shahdol and Chirimiri. The first two localities represent two lava piles of about 170 and 400 m thickness respectively. In Umaria, 16 flows have been demarcated based on petrography and field studies. The Shahdol samples are basal lava formations overlying Gondwana sediments (Carboniferous) and the Chirimiri samples are dykes. In this study, the western Deccan province is defined as the Western Ghats plus Kutch. On average, the PGE are ∼20% higher in Amarkantak than Umaria and the flows are ∼13% higher in PGE than the dykes. A Zr vs. Pd scattergram found a strong positive correlation for these two elements except for one Umaria sample which indicated severe Pd loss. A comparison of west and east parts of the Deccan volcanic province using primitive mantle normalization showed that higher values prevailed in the western province suite in the Ni-Ir-Ru-Pt region. In contrast, eastern province values dominated in the Pd-Au-Cu region at the ‘Cu’ end of the profiles. A strong dominance of Pd in the eastern Deccan was also of interest. A number of factors, for example, percentage partial melting of the source rock and the temperature and pressure of partial melting strongly influence the character of these profiles. The observed PGE profile characteristics probably result in part from a long distance of subsurface transport of Deccan magma from the western to eastern regions.

  15. Effect of combining the metals of group VI supported on H-ZSM-5 zeolite as catalysts for non-oxidative conversion of natural gas to petrochemicals

    Institute of Scientific and Technical Information of China (English)

    A.K.Aboul-Gheit; A.E.Awadallah

    2009-01-01

    The most prestigious catalyst applied in natural gas (methane) non-oxidative conversion to petrochemicals is 6%Mo/H-ZSM-5.Chromium,molybdenum and tungsten are the group VI metals.Hence,in this work,6%Mo/H-ZSM-5 was correlated with 3%Cr+3%Mo/H-ZSM-5 and 3%W+3%Mo/H-ZSM-5 as catalysts to examine their promoting or inhibiting effects on the various reactions taking place during methane conversion.The catalytic activities of these catalysts were tested in a continuous flow fixed bed reactor at 700℃ and a GHSV of 1500 ml·g-1 ·h-1. Characterization of the catalysts using XRD,TGA and TPD were investigated.XRD and NH3-TPD showed greater interaction between the W-phase and the Bronsted acid sites in the channels of the zeolite than between Cr-phase and the acid sites in the zeolite.

  16. Phenyl Groups Result in the Highest Benzene Storage and Most Efficient Desulfurization in a Series of Isostructural Metal-Organic Frameworks.

    Science.gov (United States)

    He, Wen-Wen; Yang, Guang-Sheng; Tang, Yu-Jia; Li, Shun-Li; Zhang, Shu-Ran; Su, Zhong-Min; Lan, Ya-Qian

    2015-06-26

    A series of isoreticular metal-organic frameworks (MOFs; NENU-511-NENU-514), which all have high surface areas and strong adsorption capacities, have been successfully constructed by using mixed ligands. NENU-513 has the highest benzene capacity of 1687 mg g(-1) at 298 K, which ranks as the top MOF material among those reported up to now. This NENU series has been used for adsorptive desulfurization because of its permanent porosity. The results indicate that this series has a higher adsorptive efficiency in the removal of organosulfur compounds than other MOF materials, especially NENU-511, which has the highest adsorptive efficiency in the ambient atmosphere. This study proves that the design and synthesis of targeted MOFs with higher surface areas and with functional groups present is an efficient method to enhance benzene-storage capacity and the adsorption of organosulfur compounds. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Signatures of A Companion Star in Type Ia Supernovae

    CERN Document Server

    Maeda, Keiichi; Shigeyama, Toshikazu

    2014-01-01

    While type Ia Supernovae (SNe Ia) have been used as precise cosmological distance indicators, their progenitor systems remain unresolved. One of the key questions is if there is a non-degenerate companion star at the time of a thermonuclear explosion of a white dwarf (WD). In this paper, we investigate if an interaction between the SN ejecta and the companion star may result in observable footprints around the maximum brightness and thereafter, by performing multi-dimensional radiation transfer simulations based on hydrodynamic simulations of the interaction. We find that such systems result in variations in various observational characteristics due to different viewing directions, while the predicted behaviors (redder and fainter for the companion direction) are opposite to what were suggested by the previous study. The variations are generally modest and within observed scatters. However, the model predicts trends between some observables different from observationally derived, thus a large sample of SNe Ia...

  18. Type Ia supernovae yielding distances with 3-4% precision

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, Patrick L. [Univ. of California, Berkeley, CA (United States); Filippenko, Alexei V. [Univ. of California, Berkeley, CA (United States); Burke, David L. [SLAC National Accelerator Lab., Menlo Park, CA (United States); Hicken, Malcolm [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA (United States); Ganeshalingam, Mohan [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zheng, Weikang [Univ. of California, Berkeley, CA (United States)

    2015-01-26

    The luminosities of Type Ia supernovae (SN), the thermonuclear explosions of white dwarf stars, vary systematically with their intrinsic color and light-curve decline rate. These relationships have been used to calibrate their luminosities to within ~0.14–0.20 mag from broadband optical light curves, yielding individual distances accurate to ~7–10%. Here we identify a subset of SN Ia that erupt in environments having high ultraviolet surface brightness and star-formation surface density. When we apply a steep model extinction law, these SN can be calibrated to within ~0.065–0.075 mag, corresponding to ~3–4% in distance — the best yet with SN Ia by a substantial margin. The small scatter suggests that variations in only one or two progenitor properties account for their light-curve-width/color/luminosity relation.

  19. Consolidated Financial Statements – in IAS 27 perspective

    Directory of Open Access Journals (Sweden)

    Mihai Deju

    2012-12-01

    Full Text Available The aspects concerning the preparation and publication of the consolidated financial statements have been the subject of the settlement by the Committee for International Accounting Standards (IAS even since 1976 with the publication of IAS 3 “Consolidated financial statements”. Subsequently, the standard has been amended and revised successively, on several occasions. The latest version issued in 2008 includes changes on the accounting of interests that do not control and the loss of control on a subsidiary. The actual version also includes the subsequent amendments resulting from IFRS issued until 31st of December 2010. This paper presents the essential aspects of IAS 27 (the actual version and a practical example of how to elaborate consolidated accounts in accordance with this standard.

  20. K-corrections and extinction corrections for Type Ia supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Nugent, Peter; Kim, Alex; Perlmutter, Saul

    2002-05-21

    The measurement of the cosmological parameters from Type Ia supernovae hinges on our ability to compare nearby and distant supernovae accurately. Here we present an advance on a method for performing generalized K-corrections for Type Ia supernovae which allows us to compare these objects from the UV to near-IR over the redshift range 0 < z < 2. We discuss the errors currently associated with this method and how future data can improve upon it significantly. We also examine the effects of reddening on the K-corrections and the light curves of Type Ia supernovae. Finally, we provide a few examples of how these techniques affect our current understanding of a sample of both nearby and distant supernovae.