WorldWideScience

Sample records for groundwater sampling system

  1. Designing an enhanced groundwater sample collection system

    Energy Technology Data Exchange (ETDEWEB)

    Schalla, R.

    1994-10-01

    As part of an ongoing technical support mission to achieve excellence and efficiency in environmental restoration activities at the Laboratory for Energy and Health-Related Research (LEHR), Pacific Northwest Laboratory (PNL) provided guidance on the design and construction of monitoring wells and identified the most suitable type of groundwater sampling pump and accessories for monitoring wells. The goal was to utilize a monitoring well design that would allow for hydrologic testing and reduce turbidity to minimize the impact of sampling. The sampling results of the newly designed monitoring wells were clearly superior to those of the previously installed monitoring wells. The new wells exhibited reduced turbidity, in addition to improved access for instrumentation and hydrologic testing. The variable frequency submersible pump was selected as the best choice for obtaining groundwater samples. The literature references are listed at the end of this report. Despite some initial difficulties, the actual performance of the variable frequency, submersible pump and its accessories was effective in reducing sampling time and labor costs, and its ease of use was preferred over the previously used bladder pumps. The surface seals system, called the Dedicator, proved to be useful accessory to prevent surface contamination while providing easy access for water-level measurements and for connecting the pump. Cost savings resulted from the use of the pre-production pumps (beta units) donated by the manufacturer for the demonstration. However, larger savings resulted from shortened field time due to the ease in using the submersible pumps and the surface seal access system. Proper deployment of the monitoring wells also resulted in cost savings and ensured representative samples.

  2. A downhole passive sampling system to avoid bias and error from groundwater sample handling.

    Science.gov (United States)

    Britt, Sanford L; Parker, Beth L; Cherry, John A

    2010-07-01

    A new downhole groundwater sampler reduces bias and error due to sample handling and exposure while introducing minimal disturbance to natural flow conditions in the formation and well. This "In Situ Sealed", "ISS", or "Snap" sampling device includes removable/lab-ready sample bottles, a sampler device to hold double end-opening sample bottles in an open position, and a line for lowering the sampler system and triggering closure of the bottles downhole. Before deployment, each bottle is set open at both ends to allow flow-through during installation and equilibration downhole. Bottles are triggered to close downhole without well purging; the method is therefore "passive" or "nonpurge". The sample is retrieved in a sealed condition and remains unexposed until analysis. Data from six field studies comparing ISS sampling with traditional methods indicate ISS samples typically yield higher volatile organic compound (VOC) concentrations; in one case, significant chemical-specific differentials between sampling methods were discernible. For arsenic, filtered and unfiltered purge results were negatively and positively biased, respectively, compared to ISS results. Inorganic constituents showed parity with traditional methods. Overall, the ISS is versatile, avoids low VOC recovery bias, and enhances reproducibility while avoiding sampling complexity and purge water disposal.

  3. AUTOMATING GROUNDWATER SAMPLING AT HANFORD

    Energy Technology Data Exchange (ETDEWEB)

    CONNELL CW; HILDEBRAND RD; CONLEY SF; CUNNINGHAM DE

    2009-01-16

    Until this past October, Fluor Hanford managed Hanford's integrated groundwater program for the U.S. Department of Energy (DOE). With the new contract awards at the Site, however, the CH2M HILL Plateau Remediation Company (CHPRC) has assumed responsibility for the groundwater-monitoring programs at the 586-square-mile reservation in southeastern Washington State. These programs are regulated by the Resource Conservation and Recovery Act (RCRA) and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). The purpose of monitoring is to track existing groundwater contamination from past practices, as well as other potential contamination that might originate from RCRA treatment, storage, and disposal (TSD) facilities. An integral part of the groundwater-monitoring program involves taking samples of the groundwater and measuring the water levels in wells scattered across the site. More than 1,200 wells are sampled each year. Historically, field personnel or 'samplers' have been issued pre-printed forms that have information about the well(s) for a particular sampling evolution. This information is taken from the Hanford Well Information System (HWIS) and the Hanford Environmental Information System (HEIS)--official electronic databases. The samplers used these hardcopy forms to document the groundwater samples and well water-levels. After recording the entries in the field, the samplers turned the forms in at the end of the day and the collected information was posted onto a spreadsheet that was then printed and included in a log book. The log book was then used to make manual entries of the new information into the software application(s) for the HEIS and HWIS databases. This is a pilot project for automating this tedious process by providing an electronic tool for automating water-level measurements and groundwater field-sampling activities. The automation will eliminate the manual forms and associated data entry, improve the

  4. High Resolution Hydraulic Profiling and Groundwater Sampling using FLUTe™ System in a Fractured Limestone Setting

    DEFF Research Database (Denmark)

    Janniche, Gry Sander; Christensen, Anders G.; Grosen, Bernt;

    innovative investi-gation methods for characterization of the source zone hydrogeology and contamination, including FLUTe system hydraulic profiling and Water-FLUTe multilevel groundwater sampling, in fractured bryo-zoan limestone bedrock. High resolution hydraulic profiling was conducted in three cored......Characterization of the contaminant source zone architecture and the hydraulics is essential to develop accurate site specific conceptual models, delineate and quantify contaminant mass, perform risk as-sessment, and select and design remediation alternatives. This characterization is particularly...... challeng-ing in deposit types as fractured limestone. The activities of a bulk distribution facility for perchloroe-thene (PCE) and trichloroethene (TCE) at the Naverland site near Copenhagen, Denmark, has resulted in PCE and TCE DNAPL impacts to a fractured clay till and an underlying fractured limestone...

  5. Automated Ground-Water Sampling and Analysis of Hexavalent Chromium using a “Universal” Sampling/Analytical System

    OpenAIRE

    Venedam, Richard J.; Hartman, Mary J.; Hoffman, Dave A.; Scott R. Burge

    2005-01-01

    The capabilities of a “universal platform” for the deployment of analytical sensors in the field for long-term monitoring of environmental contaminants were expanded in this investigation. The platform was previously used to monitor trichloroethene in monitoring wells and at groundwater treatment systems (1,2). The platform was interfaced with chromium (VI) and conductivity analytical systems to monitor shallow wells installed adjacent to the Columbia River at the 100-D Area of the Hanford Si...

  6. Groundwater sampling: Chapter 5

    Science.gov (United States)

    Wang, Qingren; Munoz-Carpena, Rafael; Foster, Adam; Migliaccio, Kati W.; Li, Yuncong; Migliaccio, Kati

    2011-01-01

    About the book: As water quality becomes a leading concern for people and ecosystems worldwide, it must be properly assessed in order to protect water resources for current and future generations. Water Quality Concepts, Sampling, and Analyses supplies practical information for planning, conducting, or evaluating water quality monitoring programs. It presents the latest information and methodologies for water quality policy, regulation, monitoring, field measurement, laboratory analysis, and data analysis. The book addresses water quality issues, water quality regulatory development, monitoring and sampling techniques, best management practices, and laboratory methods related to the water quality of surface and ground waters. It also discusses basic concepts of water chemistry and hydrology related to water sampling and analysis; instrumentation; water quality data analysis; and evaluation and reporting results.

  7. Analysis of s-triazine herbicides in model systems and samples of groundwater by gas and liquid chromatography

    Directory of Open Access Journals (Sweden)

    Kostadinović Ljiljana

    2010-01-01

    Full Text Available In this paper, residues of s-triazine herbicides (Simazine, Atrazine, Amethrine, Promethrine and Azyprothrine have been determined in samples of model systems and real groundwater samples by gas-chromatography and high performance liquid chromatography. S-triazine herbicides were isolated from water samples by chloroform-methanol mixture (1:1, followed by purification of extract on the Al2O3 column. Gas-chromatographic determination the residues of s-triazines is performed on parallel capilar columns ULTRA I and ULTRA II, using specific NP detector. Liquid-chromatographic determination the s-triazines was performed on the column TSK ODS-120 A 5 mm 'LKB', using the mobile phase methanol-water (60:40. Total concentration of s-triazines in samples of Danube water was 3.54 mg dm-3. .

  8. 40 CFR 265.91 - Ground-water monitoring system.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Ground-water monitoring system. 265.91... DISPOSAL FACILITIES Ground-Water Monitoring § 265.91 Ground-water monitoring system. (a) A ground-water monitoring system must be capable of yielding ground-water samples for analysis and must consist of: (1...

  9. Groundwater hydrology instructional system

    Science.gov (United States)

    Schmidt, Ronald G.

    Wright State University, Dayton, Ohio, is preparing for its third cycle of the Interactive Remote Instructional System (IRIS) in groundwater hydrology, beginning January 15, 1986. The first cycle finished with an impressive completion ratio for registered participants, and the second cycle has currently been underway since July. This comprehensive hydrogeology program was originally developed for the Soil Conservation Service (of the U.S. Department of Agriculture) to prepare their personnel for professional practice work. Since its evolution into IRIS, an 80% participant completion rate has been recorded for the first cycle, which is a significant departure from success rates traditionally recorded by correspondence courses. This excellent rate of success is the result of 2 years of refinement and demonstrates the progressive nature of the program. IRIS has met the needs of participants by developing a curriculum that reflects current trends in the groundwater industry and has provided a unique educational approach that ensures maximum interaction between the instructional staff and participants.

  10. Sample size reduction in groundwater surveys via sparse data assimilation

    KAUST Repository

    Hussain, Z.

    2013-04-01

    In this paper, we focus on sparse signal recovery methods for data assimilation in groundwater models. The objective of this work is to exploit the commonly understood spatial sparsity in hydrodynamic models and thereby reduce the number of measurements to image a dynamic groundwater profile. To achieve this we employ a Bayesian compressive sensing framework that lets us adaptively select the next measurement to reduce the estimation error. An extension to the Bayesian compressive sensing framework is also proposed which incorporates the additional model information to estimate system states from even lesser measurements. Instead of using cumulative imaging-like measurements, such as those used in standard compressive sensing, we use sparse binary matrices. This choice of measurements can be interpreted as randomly sampling only a small subset of dug wells at each time step, instead of sampling the entire grid. Therefore, this framework offers groundwater surveyors a significant reduction in surveying effort without compromising the quality of the survey. © 2013 IEEE.

  11. Nevada National Security Site Integrated Groundwater Sampling Plan, Revision 0

    Energy Technology Data Exchange (ETDEWEB)

    Marutzky, Sam; Farnham, Irene

    2014-10-01

    The purpose of the Nevada National Security Site (NNSS) Integrated Sampling Plan (referred to herein as the Plan) is to provide a comprehensive, integrated approach for collecting and analyzing groundwater samples to meet the needs and objectives of the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) Underground Test Area (UGTA) Activity. Implementation of this Plan will provide high-quality data required by the UGTA Activity for ensuring public protection in an efficient and cost-effective manner. The Plan is designed to ensure compliance with the UGTA Quality Assurance Plan (QAP). The Plan’s scope comprises sample collection and analysis requirements relevant to assessing the extent of groundwater contamination from underground nuclear testing. This Plan identifies locations to be sampled by corrective action unit (CAU) and location type, sampling frequencies, sample collection methodologies, and the constituents to be analyzed. In addition, the Plan defines data collection criteria such as well-purging requirements, detection levels, and accuracy requirements; identifies reporting and data management requirements; and provides a process to ensure coordination between NNSS groundwater sampling programs for sampling of interest to UGTA. This Plan does not address compliance with requirements for wells that supply the NNSS public water system or wells involved in a permitted activity.

  12. AUTOMATING GROUNDWATER SAMPLING AT HANFORD THE NEXT STEP

    Energy Technology Data Exchange (ETDEWEB)

    CONNELL CW; CONLEY SF; HILDEBRAND RD; CUNNINGHAM DE; R_D_Doug_Hildebrand@rl.gov; DeVon_E_Cunningham@rl.gov

    2010-01-21

    Historically, the groundwater monitoring activities at the Department of Energy's Hanford Site in southeastern Washington State have been very "people intensive." Approximately 1500 wells are sampled each year by field personnel or "samplers." These individuals have been issued pre-printed forms showing information about the well(s) for a particular sampling evolution. This information is taken from 2 official electronic databases: the Hanford Well information System (HWIS) and the Hanford Environmental Information System (HEIS). The samplers used these hardcopy forms to document the groundwater samples and well water-levels. After recording the entries in the field, the samplers turned the forms in at the end of the day and other personnel posted the collected information onto a spreadsheet that was then printed and included in a log book. The log book was then used to make manual entries of the new information into the software application(s) for the HEIS and HWIS databases. A pilot project for automating this extremely tedious process was lauched in 2008. Initially, the automation was focused on water-level measurements. Now, the effort is being extended to automate the meta-data associated with collecting groundwater samples. The project allowed electronic forms produced in the field by samplers to be used in a work flow process where the data is transferred to the database and electronic form is filed in managed records - thus eliminating manually completed forms. Elimating the manual forms and streamlining the data entry not only improved the accuracy of the information recorded, but also enhanced the efficiency and sampling capacity of field office personnel.

  13. Automated Ground-Water Sampling and Analysis of Hexavalent Chromium using a “Universal” Sampling/Analytical System

    Directory of Open Access Journals (Sweden)

    Richard J. Venedam

    2005-02-01

    Full Text Available The capabilities of a “universal platform” for the deployment of analyticalsensors in the field for long-term monitoring of environmental contaminants were expandedin this investigation. The platform was previously used to monitor trichloroethene inmonitoring wells and at groundwater treatment systems (1,2. The platform was interfacedwith chromium (VI and conductivity analytical systems to monitor shallow wells installedadjacent to the Columbia River at the 100-D Area of the Hanford Site, Washington. Agroundwater plume of hexavalent chromium is discharging into the Columbia River throughthe gravels beds used by spawning salmon. The sampling/analytical platform was deployedfor the purpose of collecting data on subsurface hexavalent chromium concentrations atmore frequent intervals than was possible with the previous sampling and analysis methodsemployed a the Site.

  14. Groundwater and Leachate Monitoring and Sampling at ERDF, CY 2009

    Energy Technology Data Exchange (ETDEWEB)

    R.L. Weiss, B.L. Lawrence, D.W. Woolery

    2010-07-08

    This document reports the findings of the groundwater and leachate monitoring and sampling at the Environmental restoration Disposal Facility for calendar year 2009. The purpose of this annual monitoring report is to evaluate the conditions of and identify trends for groundwater beneath the ERDF and report leachate results in fulfillment of the requirements specified in the ERDF ROD and the ERDF Amended ROD.

  15. A new design of groundwater sampling device and its application

    Institute of Scientific and Technical Information of China (English)

    Yih-Jin Tsai; Ming-Ching T.Kuo

    2005-01-01

    Compounds in the atmosphere contaminate samples of groundwater. An inexpensive and simple method for collecting groundwater samples is developed to prevent contamination when the background concentration of contaminants is high. This new design of groundwater sampling device involves a glass sampling bottle with a Teflon-lined valve at each end. A cleaned and dried sampling bottle was connected to a low flow-rate peristaltic pump with Teflon tubing and was filled with water. No headspace volume was remained in the sampling bottle. The sample bottle was then packed in a PVC bag to prevent the target component from infiltrating into the water sample through the valves. In this study, groundwater was sampled at six wells using both the conventional method and the improved method.The analysis of trichlorofluoromethane(CFC-11 ) concentrations at these six wells indicates that all the groundwater samples obtained by the conventional sampling method were contaminated by CFC-11 from the atmosphere. The improved sampling method greatly eliminated theproblems of contamination, preservation and quantitative analysis of natural water.

  16. Groundwater dating for understanding nitrogen in groundwater systems - Time lag, fate, and detailed flow path ways

    Science.gov (United States)

    Morgenstern, Uwe; Hadfield, John; Stenger, Roland

    2014-05-01

    Nitrate contamination of groundwater is a problem world-wide. Nitrate from land use activities can leach out of the root zone of the crop into the deeper part of the unsaturated zone and ultimately contaminate the underlying groundwater resources. Nitrate travels with the groundwater and then discharges into surface water causing eutrophication of surface water bodies. To understand the source, fate, and future nitrogen loads to ground and surface water bodies, detailed knowledge of the groundwater flow dynamics is essential. Groundwater sampled at monitoring wells or discharges may not yet be in equilibrium with current land use intensity due to the time lag between leaching out of the root zone and arrival at the sampling location. Anoxic groundwater zones can act as nitrate sinks through microbial denitrification. However, the effect of denitrification on overall nitrate fluxes depends on the fraction of the groundwater flowing through such zones. We will show results from volcanic aquifers in the central North Island of New Zealand where age tracers clearly indicate that the groundwater discharges into large sensitive lakes like Lake Taupo and Lake Rotorua are not yet fully realising current land use intensity. The majority of the water discharging into these lakes is decades and up to over hundred years old. Therefore, increases in dairy farming over the last decades are not yet reflected in these old water discharges, but over time these increased nitrate inputs will eventually work their way through the large groundwater systems and increasing N loads to the lakes are to be expected. Anoxic zones are present in some of these aquifers, indicating some denitrification potential, however, age tracer results from nested piezo wells show young groundwater in oxic zones indicating active flow in these zones, while anoxic zones tend to have older water indicating poorer hydraulic conductivity in these zones. Consequently, to evaluate the effect of denitrification

  17. Interpretation of stable isotope, denitrification, and groundwater age data for samples collected from Sandia National Laboratories /New Mexico (SNL/NM) Burn Site Groundwater Area of Concern

    Energy Technology Data Exchange (ETDEWEB)

    Madrid, V. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Singleton, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Visser, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Esser, B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-06-02

    This report combines and summarizes results for two groundwater-sampling events (October 2012 and October/November 2015) from the Sandia National Laboratories/New Mexico (SNL/NM) Burn Site Groundwater (BSG) Area of Concern (AOC) located in the Lurance Canyon Arroyo southeast of Albuquerque, NM in the Manzanita Mountains. The first phase of groundwater sampling occurred in October 2012 including samples from 19 wells at three separate sites that were analyzed by the Environmental Radiochemistry Laboratory at Lawrence Livermore National Laboratory as part of a nitrate Monitored Natural Attenuation (MNA) evaluation. The three sites (BSG, Technical Area-V, and Tijeras Arroyo) are shown on the regional hydrogeologic map and described in the Sandia Annual Groundwater Monitoring Report. The first phase of groundwater sampling included six monitoring wells at the Burn Site, eight monitoring wells at Technical Area-V, and five monitoring wells at Tijeras Arroyo. Each groundwater sample was analyzed using the two specialized analytical methods, age-dating and denitrification suites. In September 2015, a second phase of groundwater sampling took place at the Burn Site including 10 wells sampled and analyzed by the same two analytical suites. Five of the six wells sampled in 2012 were resampled in 2015. This report summarizes results from two sampling events in order to evaluate evidence for in situ denitrification, the average age of the groundwater, and the extent of recent recharge of the bedrock fracture system beneath the BSG AOC.

  18. Expediting Groundwater Sampling at Hanford and Making It Safer - 13158

    Energy Technology Data Exchange (ETDEWEB)

    Connell, Carl W. Jr.; Conley, S.F.; Carr, Jennifer S.; Schatz, Aaron L. [CH2M HILL Plateau Remediation Company, P.O. Box 1600, Richland, WA 99352 (United States); Brown, W.L. [Lockheed Martin Systems Information, P.O. Box 950, Richland, WA 99352 (United States); Hildebrand, R. Douglas [Department of Energy - Richland Operations Office, 825 Jadwin Ave., Richland, WA 99352 (United States)

    2013-07-01

    The CH2M HILL Plateau Remediation Company (CHPRC) manages the groundwater monitoring programs at the Department of Energy's 586-square-mile Hanford site in southeastern Washington state. These programs are regulated by the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), and the Atomic Energy Act (AEA). The purpose of monitoring is to track existing groundwater contamination from past practices, as well as other potential contamination that might originate from RCRA treatment, storage, and disposal (TSD) facilities. An integral part of the groundwater-monitoring program involves taking samples of the groundwater and measuring the water levels in wells scattered across the site. Each year, more than 1,500 wells are accessed for a variety of reasons. Historically, the monitoring activities have been very 'people intensive'. Field personnel or 'samplers' have been issued pre-printed forms showing information about the well(s) for a particular sampling evolution. This information is taken from two official electronic databases: the Hanford Well Information System (HWIS) and the Hanford Environmental Information System (HEIS). The samplers traditionally used these hardcopy forms to document the groundwater samples and well water-levels. After recording the entries in the field, the samplers turned the forms in at the end of the day and other personnel posted the collected information. In Automating Groundwater Sampling at Hanford (HNF-38542-FP Revision 0, Presented at Waste Management 2009 Conference, March 1 - March 5, 2009, Phoenix, AZ), we described the methods, tools, and techniques that would be used in automating the activities associated with measuring water levels. The Field Logging and Electronic Data Gathering (FLEDG) application/database that automates collecting the water-level measurement data has now been implemented at Hanford. In addition to

  19. [Construction of groundwater contamination prevention mapping system].

    Science.gov (United States)

    Wang, Jun-Jie; He, Jiang-Tao; Lu, Yan; Liu, Li-Ya; Zhang, Xiao-Liang

    2012-09-01

    Groundwater contamination prevention mapping is an important component of groundwater contamination geological survey and assessment work, which could provide the basis for making and implementing groundwater contamination prevention planning. A groundwater contamination prevention mapping system was constructed in view of the synthetic consideration on nature perspective derived from groundwater contamination sources and aquifer itself, social-economic perspective, policy perspective derived from outside. During the system construction process, analytic hierarchy process and relevant overlaying principles were used to couple groundwater contamination risk assessment, groundwater value as well as wellhead protection area zoning. Data processing and visualization of mapping results were achieved in the GIS environment. The research on groundwater contamination prevention mapping in Beijing Plain indicated that the final groundwater prevention map was in accordance with the actual conditions and well reflected the priorities of groundwater prevention, which could play a guidance role in designing and implementing further practical prevention and supervision measures. Besides, because of the dynamical properties of the system components, it was suggested to analyze the update frequency of the mapping.

  20. Influence of thermal treatments on radiocarbon dating of groundwater samples

    Science.gov (United States)

    Stanciu, Iuliana Madalina; Sava, Tiberiu Bogdan; Pacesila, Doru Gheorghe; Gaza, Oana; Simion, Corina Anca; Stefan, Bianca Maria; Sava, Gabriela Odilia; Ghita, Dan Gabriel; Mosu, Vasile

    2017-06-01

    Radiocarbon measurements of dissolved inorganic carbon (DIC) in water provides information about the formation of oceanic circulation of the water volumes, the hydrogeological systems, and also valuable information can be gained about the aquifer storage and the degree of containment relative to the surface waters. Radiocarbon dating refers to the determination of small quantities of the naturally occurring carbon 14 in the water, which can be integrated in the groundwater mass through the gaseous CO2, carbonaceous deposits dissolved by water and organic remains. The aim of this study is to investigate the influence of the temperature and pressure over the amount of each isotope of carbon during the sample preparation stage. The first step was to evaporate several underground water samples at 65°C under different conditions until the carbonates were obtained, then the CO2 was extracted with orto-phosphoric acid and transformed to graphite. The second step was to obtain graphite from an untreated water sample. Finally, the samples were measured with the 1MV Cockcroft-Walton Tandetron Accelerator by Accelerator Mass Spectrometry.

  1. Integrated sampling and analytical approach for common groundwater dissolved gases.

    Science.gov (United States)

    McLeish, Kimberley; Ryan, M Cathryn; Chu, Angus

    2007-12-15

    A novel passive gas diffusion sampler (PGDS) combines sampling, storage and direct injection into a single gas chromatograph (GC). The sampler has a 4.5 mL internal volume when deployed, is easy to operate, and eliminates sample-partitioning. The associated GC method analyzes for a large, dynamic sampling range from a single, small volume injection. Dissolved gases were separated on parallel Rt-Molsieve 5A and Rt-Q-PLOT columns and eluted solutes were quantified using a pulse discharge helium ionization detector (PD-HID). The combined sampling and analytical method appears to be less prone to systematic bias than conventional sampling and headspace partitioning and analysis. Total dissolved gas pressure used in tandem with the PGDS improved the accuracy of dissolved gas concentrations. The incorporation of routine measurements of dissolved biogeochemical and permanent gases into groundwater investigations will provide increased insight into chemical and biological processes in groundwater and improve chemical mass balance accuracy.

  2. Expediting Groundwater Sampling at Hanford and Making It Safer

    Energy Technology Data Exchange (ETDEWEB)

    Connell, Carl W. Jr. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Carr, Jennifer S. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Hildebrand, R. Douglas [Department of Energy - Richland Operations Office, Richland, WA (United States); Schatz, Aaron L. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Conley, S. F. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Brown, W. L. [Lockheed Martin Systems Information, Richland, WA (United States)

    2013-01-22

    The CH2M HILL Plateau Remediation Company (CHPRC) manages the groundwatermonitoring programs at the Department of Energy's 586-square-mile Hanford site in southeastern Washington state. These programs are regulated by the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), and the Atomic Energy Act (AEA). The purpose of monitoring is to track existing groundwater contamination from past practices, as well as other potential contamination that might originate from RCRA treatment, storage, and disposal (TSD) facilities. An integral part of the groundwater-monitoring program involves taking samples of the groundwater and measuring the water levels in wells scattered across the site. Each year, more than 1,500 wells are accessed for a variety of reasons.

  3. Propagation of drought through groundwater systems

    NARCIS (Netherlands)

    Peters, E.

    2003-01-01

    Index words: drought, groundwater, simulation, synthetic data, extreme events

    The transformation of droughts as a result of the propagation through groundwater systems is examined by comparing droughts in time

  4. Propagation of drought through groundwater systems

    NARCIS (Netherlands)

    Peters, E.

    2003-01-01

    Index words: drought, groundwater, simulation, synthetic data, extreme events

    The transformation of droughts as a result of the propagation through groundwater systems is examined by comparing droughts in time se

  5. [Groundwater organic pollution source identification technology system research and application].

    Science.gov (United States)

    Wang, Xiao-Hong; Wei, Jia-Hua; Cheng, Zhi-Neng; Liu, Pei-Bin; Ji, Yi-Qun; Zhang, Gan

    2013-02-01

    Groundwater organic pollutions are found in large amount of locations, and the pollutions are widely spread once onset; which is hard to identify and control. The key process to control and govern groundwater pollution is how to control the sources of pollution and reduce the danger to groundwater. This paper introduced typical contaminated sites as an example; then carried out the source identification studies and established groundwater organic pollution source identification system, finally applied the system to the identification of typical contaminated sites. First, grasp the basis of the contaminated sites of geological and hydrogeological conditions; determine the contaminated sites characteristics of pollutants as carbon tetrachloride, from the large numbers of groundwater analysis and test data; then find the solute transport model of contaminated sites and compound-specific isotope techniques. At last, through groundwater solute transport model and compound-specific isotope technology, determine the distribution of the typical site of organic sources of pollution and pollution status; invest identified potential sources of pollution and sample the soil to analysis. It turns out that the results of two identified historical pollution sources and pollutant concentration distribution are reliable. The results provided the basis for treatment of groundwater pollution.

  6. Organic Carbon Fluxes in a Stressed Groundwater System

    Science.gov (United States)

    Baker, A.; Graham, P. W.; Grbich, N.; Chinu, K.; Yu, D.

    2013-12-01

    Dissolved Organic Carbon (DOC) flux in groundwater is poorly understood: influenced by recharge, extraction and surface processes. We reviewed existing datasets for DOC concentration and flux in Australian groundwater systems. In a temperate, semi-arid, Australian research site we measured variations in DOC content during a series of high intensity extraction and recovery events in the surrounding aquifer and abstracted groundwater. Groundwater was abstracted from a fractured basalt / metasediment aquifer overlain by residual soils and flanked by a Quaternary alluvial channel. Groundwater systems included the fractured rock system interconnected with the alluvial aquifer through a leaky aquitard and a perched aquifer held at the soil bedrock interface. Prior to and throughout the test, groundwater samples were collected from wells within the fractured rock, alluvial aquifer and soil bedrock interface and analysed for DOC. Initial DOC concentrations in the upper aquifer were ~2 mg/L, following pumping concentrations increased 36 mg/L (ave) peaking at 72 mg/L. In the lower aquifer initial TOC concentrations were ~1.6 mg/L, during pumping levels increased to 3.98 mg/L (ave) peaking at 14.32 mg/L. Results indicate the fractured rock aquifers ability to recharge was exceeded during intense pumping periods and a larger component of water was drawn from the upper aquifer. This increased the volume of water being drawn through the soil profile and increased DOC content in abstracted groundwater. Hydrological setting, well construction and pumping regime are likely to affect the concentration of DOC within abstracted groundwater. Further attention to abstracted groundwater as a component in terrestrial DOC fluxes is warranted.

  7. Evolution of Unsteady Groundwater Flow Systems

    Science.gov (United States)

    Liang, Xing; Jin, Menggui; Niu, Hong

    2016-04-01

    Natural groundwater flow is usually transient, especially in long time scale. A theoretical approach on unsteady groundwater flow systems was adopted to highlight some of the knowledge gaps in the evolution of groundwater flow systems. The specific consideration was focused on evolution of groundwater flow systems from unsteady to steady under natural and mining conditions. Two analytical solutions were developed, using segregation variable method to calculate the hydraulic head under steady and unsteady flow conditions. The impact of anisotropy ratio, hydraulic conductivity (K) and specific yield (μs) on the flow patterns were analyzed. The results showed that the area of the equal velocity region increased and the penetrating depth of the flow system decreased while the anisotropy ratio (ɛ = °Kx-/Kz--) increased. Stagnant zones were found in the flow field where the directions of streamlines were opposite. These stagnant zones moved up when the horizontal hydraulic conductivity increased. The results of the study on transient flow indicated a positive impact on hydraulic head with an increase of hydraulic conductivity, while a negative effect on hydraulic head was observed when the specific yield was enhanced. An unsteady numerical model of groundwater flow systems with annual periodic recharge was developed using MODFLOW. It was observed that the transient groundwater flow patterns were different from that developed in the steady flow under the same recharge intensity. The water table fluctuated when the recharge intensity altered. The monitoring of hydraulic head and concentration migration revealed that the unsteady recharge affected the shallow local flow system more than the deep regional flow system. The groundwater flow systems fluctuated with the action of one or more pumping wells. The comparison of steady and unsteady groundwater flow observation indicated that the unsteady flow patterns cannot be simulated by the steady model when the condition

  8. Evaluation of Groundwater Pollution Nitrogen Fertilizer Using Expert System

    OpenAIRE

    Ta-oun, Mongkon; Daud, Mohamed; Bardaie, Mohd Zohadie

    2017-01-01

    An expert system was used to correlate the availability of nitrogen fertilizer with the vulnerability of groundwater to pollution in Peninsula Malaysia to identify potential groundwater quality problems. The expert system could predict the groundwater pollution potential under several conditions of agricultural activities and exiting environments. Four categories of groundwater pollution potential were identified base on an N-fertilizer groundwater pollution potential index. A groundwater pol...

  9. Groundwater sampling methods using glass wool filtration to trace human enteric viruses in Madison, Wisconsin

    Science.gov (United States)

    Human enteric viruses have been detected in the Madison, Wisconsin deep municipal well system. Earlier projects by the Wisconsin Geological and Natural History Survey (WGNHS) have used glass wool filters to sample groundwater for these viruses directly from the deep municipal wells. Polymerase chain...

  10. 40 CFR 258.53 - Ground-water sampling and analysis requirements.

    Science.gov (United States)

    2010-07-01

    ....53 Ground-water sampling and analysis requirements. (a) The ground-water monitoring program must... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water sampling and analysis requirements. 258.53 Section 258.53 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)...

  11. Groundwater system analysis of south Yishu geosyncline

    Institute of Scientific and Technical Information of China (English)

    DAI Chang-lei; CHI Bao-ming; YI Shu-ping; LI Zhi-jun

    2004-01-01

    South Yishu geosyncline is 50 km southeast of Changchun City of Jilin Province, where an aquifer is thick,surface runoff is abundant and it has potential to develop water resources preferably. By means of system analysis, the authors analyse the structural characteristics, I/O characteristics, function characteristics and boundary and environment characteristics of the groundwater system, so as to search for a way of optimizing water resources arrangement and enhancing water resources'bearing capacity. Based on the analysis results, the authors abstract conceptual model and mathematical model of the groundwater system. The simulation results certify and enrich the knowledge about south Yishu geosyncline.

  12. Vertical Sampling in Recharge Areas Versus Lateral Sampling in Discharge Areas: Assessing the Agricultural Nitrogen Legacy in Groundwater

    Science.gov (United States)

    Gilmore, T. E.; Genereux, D. P.; Solomon, D. K.; Mitasova, H.; Burnette, M.

    2014-12-01

    Agricultural nitrogen (N) is a legacy contaminant often found in shallow groundwater systems. This legacy has commonly been observed using well nests (vertical sampling) in recharge areas, but may also be observed by sampling at points in/beneath a streambed using pushable probes along transects across a channel (lateral sampling). We compared results from two different streambed point sampling approaches and from wells in the recharge area to assess whether the different approaches give fundamentally different pictures of (1) the magnitude of N contamination, (2) historic trends in N contamination, and (3) the extent to which denitrification attenuates nitrate transport through the surficial aquifer. Two different arrangements of streambed points (SP) were used to sample groundwater discharging into a coastal plain stream in North Carolina. In July 2012, a 58 m reach was sampled using closely-spaced lateral transects of SP, revealing high average [NO3-] (808 μM, n=39). In March 2013, transects of SP were widely distributed through a 2.7 km reach that contained the 58 m reach and suggested overall lower [NO3-] (210 μM, n=30), possibly due to variation in land use along the longer study reach. Mean [NO3-] from vertical sampling (2 well nests with 3 wells each) was 296 μM. Groundwater apparent ages from SP in the 58 m and 2.7 km reaches suggested lower recharge [NO3-] (observed [NO3-] plus modeled excess N2) in 0-10 year-old water (1250 μM and 525 μM, respectively), compared to higher recharge [NO3-] from 10-30 years ago (about 1600 μM and 900 μM, respectively). In the wells, [NO3-] was highest (835 μM) in groundwater with apparent age of 12-15 years and declined as apparent age increased, a trend that was consistent with SP in the 2.7 km reach. The 58 m reach suggested elevated recharge [NO3-] (>1100 μM) over a 50-year period. Excess N2 from wells suggested that about 62% of nitrate had been removed via denitrification since recharge, versus 51% and 78

  13. 40 CFR 257.22 - Ground-water monitoring systems.

    Science.gov (United States)

    2010-07-01

    ... operator. When physical obstacles preclude installation of ground-water monitoring wells at the relevant... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water monitoring systems. 257... Waste Disposal Units Ground-Water Monitoring and Corrective Action § 257.22 Ground-water......

  14. Influence of vertical flows in wells on groundwater sampling.

    Science.gov (United States)

    McMillan, Lindsay A; Rivett, Michael O; Tellam, John H; Dumble, Peter; Sharp, Helen

    2014-11-15

    Pumped groundwater sampling evaluations often assume that horizontal head gradients predominate and the sample comprises an average of water quality variation over the well screen interval weighted towards contributing zones of higher hydraulic conductivity (a permeability-weighted sample). However, the pumping rate used during sampling may not always be sufficient to overcome vertical flows in wells driven by ambient vertical head gradients. Such flows are reported in wells with screens between 3 and 10m in length where lower pumping rates are more likely to be used during sampling. Here, numerical flow and particle transport modeling is used to provide insight into the origin of samples under ambient vertical head gradients and under a range of pumping rates. When vertical gradients are present, sample provenance is sensitive to pump intake position, pumping rate and pumping duration. The sample may not be drawn from the whole screen interval even with extended pumping times. Sample bias is present even when the ambient vertical flow in the wellbore is less than the pumping rate. Knowledge of the maximum ambient vertical flow in the well does, however, allow estimation of the pumping rate that will yield a permeability-weighted sample. This rate may be much greater than that recommended for low-flow sampling. In practice at monitored sites, the sampling bias introduced by ambient vertical flows in wells may often be unrecognized or underestimated when drawing conclusions from sampling results. It follows that care should be taken in the interpretation of sampling data if supporting flow investigations have not been undertaken.

  15. Groundwater Systems and Resources in the Ordos Basin, China

    Institute of Scientific and Technical Information of China (English)

    HOU Guangcai; LIANG Yongping; SU Xiaosi; ZHAO Zhenghong; TAO Zhengping; YIN Lihe; YANG Yuncheng; WANG Xiaoyong

    2008-01-01

    The Ordos Basin is.a large-scalesedimentary basin in northwestern China. The hydrostratigraphic units from bottom to top are pre-Cambrian metamorphic rocks, Lower Paleozoic carbonate rocks, Upper Paleozoic to Mesozoic clastic rocks and Cenozoic deposits. The total thickness is up to 6000 m. Three groundwater systems are present in the Ordos Basin, based on the geological settings, I.e. The karst groundwater system, the Cretaceous dastic groundwater system and the Quaternary groundwater system. This paper describes systematically the groundwater flow patterns of each system and overall assessment of groundwater resources.

  16. Groundwater Quality Assessment Based on Geographical Information System and Groundwater Quality Index

    Directory of Open Access Journals (Sweden)

    Zahra Derakhshan

    2015-06-01

    Full Text Available Iran is located in an arid and semi-arid part of the world. Accordingly, the management of the water resources in the country is a priority. In this regard, determining the quality and pollution of surface water and groundwater is very important, especially in areas where groundwater resources are used for drinking. Groundwater quality index (GQI checks the components of the available water with various quality levels. To assess the quality of drinking groundwater of Yazd-Ardakan plain according to GQI in geographical information system (GIS environment, the electrical conductivity, sodium, calcium, magnesium, chlorine, pH, sodium adsorption ratio, bicarbonate, sulfate, potassium, water hardness, and all substances dissolved in the waters of 80 wells were determined. The samples were obtained from Yazd Regional Water Organization from 2005 to 2014. Using this data, the map components were plotted by Kriging geostatistical method. Then, the map of GQI was prepared after normalizing each map component, switching to a rating map, and extracting the weight of each component from the rating map. Based on the GQI index map, the index point which was 87 in 2005 has increased to 81 in 2014. These maps show a decline in groundwater quality from west to the east region. This decline in groundwater quality is due to the existence of Neogene Organizations in the east and geomorphologic unit of the bare epandage pediment in the west. The map removal and single-parameter sensitivity analysis showed that GQI index in Yazd-Ardakan plain is more sensitive to the components of electrical conductivity (EC, total dissolved solids (TDS, and total hardness (TH. Therefore, these components should be monitored more carefully and repeatedly.

  17. Recent developments on field gas extraction and sample preparation methods for radiokrypton dating of groundwater

    Science.gov (United States)

    Yokochi, Reika

    2016-09-01

    Current and foreseen population growths will lead to an increased demand in freshwater, large quantities of which is stored as groundwater. The ventilation age is crucial to the assessment of groundwater resources, complementing the hydrological model approach based on hydrogeological parameters. Ultra-trace radioactive isotopes of Kr (81 Kr and 85 Kr) possess the ideal physical and chemical properties for groundwater dating. The recent advent of atom trap trace analyses (ATTA) has enabled determination of ultra-trace noble gas radioisotope abundances using 5-10 μ L of pure Kr. Anticipated developments will enable ATTA to analyze radiokrypton isotope abundances at high sample throughput, which necessitates simple and efficient sample preparation techniques that are adaptable to various sample chemistries. Recent developments of field gas extraction devices and simple and rapid Kr separation method at the University of Chicago are presented herein. Two field gas extraction devices optimized for different sampling conditions were recently designed and constructed, aiming at operational simplicity and portability. A newly developed Kr purification system enriches Kr by flowing a sample gas through a moderately cooled (138 K) activated charcoal column, followed by a gentle fractionating desorption. This simple process uses a single adsorbent and separates 99% of the bulk atmospheric gases from Kr without significant loss. The subsequent two stages of gas chromatographic separation and a hot Ti sponge getter further purify the Kr-enriched gas. Abundant CH4 necessitates multiple passages through one of the gas chromatographic separation columns. The presented Kr separation system has a demonstrated capability of extracting Kr with > 90% yield and 99% purity within 75 min from 1.2 to 26.8 L STP of atmospheric air with various concentrations of CH4. The apparatuses have successfully been deployed for sampling in the field and purification of groundwater samples.

  18. Groundwater flow processes and mixing in active volcanic systems: the case of Guadalajara (Mexico)

    Science.gov (United States)

    Hernández-Antonio, A.; Mahlknecht, J.; Tamez-Meléndez, C.; Ramos-Leal, J.; Ramírez-Orozco, A.; Parra, R.; Ornelas-Soto, N.; Eastoe, C. J.

    2015-09-01

    Groundwater chemistry and isotopic data from 40 production wells in the Atemajac and Toluquilla valleys, located in and around the Guadalajara metropolitan area, were determined to develop a conceptual model of groundwater flow processes and mixing. Stable water isotopes (δ2H, δ18O) were used to trace hydrological processes and tritium (3H) to evaluate the relative contribution of modern water in samples. Multivariate analysis including cluster analysis and principal component analysis were used to elucidate distribution patterns of constituents and factors controlling groundwater chemistry. Based on this analysis, groundwater was classified into four groups: cold groundwater, hydrothermal groundwater, polluted groundwater and mixed groundwater. Cold groundwater is characterized by low temperature, salinity, and Cl and Na concentrations and is predominantly of Na-HCO3-type. It originates as recharge at "La Primavera" caldera and is found predominantly in wells in the upper Atemajac Valley. Hydrothermal groundwater is characterized by high salinity, temperature, Cl, Na and HCO3, and the presence of minor elements such as Li, Mn and F. It is a mixed-HCO3 type found in wells from Toluquilla Valley and represents regional flow circulation through basaltic and andesitic rocks. Polluted groundwater is characterized by elevated nitrate and sulfate concentrations and is usually derived from urban water cycling and subordinately from agricultural return flow. Mixed groundwaters between cold and hydrothermal components are predominantly found in the lower Atemajac Valley. Twenty-seven groundwater samples contain at least a small fraction of modern water. The application of a multivariate mixing model allowed the mixing proportions of hydrothermal fluids, polluted waters and cold groundwater in sampled water to be evaluated. This study will help local water authorities to identify and dimension groundwater contamination, and act accordingly. It may be broadly applicable to

  19. Heavy metal analysis in groundwater samples by SR-TXRF

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Silvana; Ficaris, Maria [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Civil, Arquitetura e Urbanismo. Dept. de Recursos Hidricos]. E-mail: silvana@fec.unicamp.br; Vives, Ana Elisa S. de [Universidade Metodista de Piracicaba (UNIMEP), Santa Barbara D' Oeste, SP (Brazil). Faculdade de Engenharia, Arquitetura e Urbanismo]. E-mail: aesvives@unimep.br; Zucchi, Orgheda L.A.D. [Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Faculdade de Ciencias Farmaceuticas]. E-mail: olzucchi@fcfrp.usp.br; Nascimento Filho, Virgilio Franco do [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Lab. Instrumentacao Nuclear]. E-mail: virgilio@cena.usp.br

    2005-07-01

    In order to obtain information about levels of heavy metals in groundwater, analysis were carried out on samples from monitoring and supplying wells located in Campinas, Sao Paulo State, Southeastern Brazil. The analytical technique used was Synchrotron Radiation Total Reflection X-Ray Fluorescence (SR-TXRF) and all the measurements were performed at Synchrotron Light Source Laboratory, using a white beam and a Si(Li) detector in total reflection condition. The determined elements were Al, Cr, Mn, Fe, Ni, Cu, Zn, Ba and Pb. The results were compared with the maximum allowed values (MPV) established by the Brazilian Health Department. The detection limits obtained varying from 0.10 up to 8 {mu}g.L{sup -1} were in agreement with the values presented by others analytical techniques. (author)

  20. Groundwater sampling and chemical characterization of the Laxemar deep borehole KLX02

    Energy Technology Data Exchange (ETDEWEB)

    Laaksoharju, M.; Skaarman, C. [GeoPoint AB, Sollentuna (Sweden); Smellie, J. [Conterra AB, Uppsala (Sweden); Nilsson, A.C. [KTH, Stockholm (Sweden)

    1995-02-01

    The Laxemar deep borehole, KLX02 (1705 m depth), located close to the Aespoe Hard Rock Laboratory (HRL), has been investigated. Groundwater sampling was conducted on two occasions and using different methods. The first sampling was taken in the open borehole using the so-called Tube sampler; the second sampling carried out using the SKB-packer equipment to isolate pre-determined borehole sections. Groundwater compositions consist of two distinct groupings; one shallow to intermediate Sodium-Bicarbonate type (Na(Ca,K):HC{sub 3}Cl(SO{sub 4})) to a depth of 1000 m, and the other of deep origin, a calcium-chloride type (Ca-Na(K):Cl-SO{sub 4}(Br)), occurring below 1000 m. The deep brines contain up to 46000 mg of Cl per litre. The influence of borehole activities are seen in the tritium data which record significant tritium down to 1000 m, and even to 1420 m. Mixing modelling shows that water from the 1960`s is the main source for this tritium. The high tritium values in the 1090-1096.2 m section are due to contamination of 1% shallow water from 1960 and 2% of modern shallow water. The upper 800 m of bedrock at Laxemar lies within a groundwater recharge area; the sub-vertical to moderate angled fracture zones facilitate groundwater circulation to considerable depths, at least to 800 m, thus accounting for some of the low saline brackish groundwaters in these conducting fracture zones. Below 1000 m the system is hydraulically and geochemically `closed` such that highly saline brines exist in a near-stagnant environment. 30 refs, 22 figs, 8 tabs.

  1. Groundwater and Leachate Monitoring and Sampling at ERDF, CY 2010

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, R. L.; Lawrence, B. L.

    2011-06-09

    The purpose of this annual monitoring report is to evaluate the conditions of and identify trends for groundwater beneath the ERDF and report leachate results in fulfillment of the requirements specified in the ERDF ROD2 and the ERDF Amended ROD (EPA 1999). The overall objective of the groundwater monitoring program is to determine whether ERDF has impacted the groundwater. This objective is complicated by the fact that the ERDF is situated downgradient of the numerous groundwater contamination plumes originating from the 200 West Area.

  2. Groundwater.

    Science.gov (United States)

    Braids, Olin C.; Gillies, Nola P.

    1978-01-01

    Presents a literature review of groundwater quality covering publications of 1977. This review includes: (1) sources of groundwater contamination; and (2) management of groundwater. A list of 59 references is also presented. (HM)

  3. 40 CFR 257.23 - Ground-water sampling and analysis requirements.

    Science.gov (United States)

    2010-07-01

    ... and analysis requirements. (a) The ground-water monitoring program must include consistent sampling... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water sampling and analysis requirements. 257.23 Section 257.23 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)...

  4. 40 CFR 258.51 - Ground-water monitoring systems.

    Science.gov (United States)

    2010-07-01

    ... preclude installation of ground-water monitoring wells at the relevant point of compliance at existing... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water monitoring systems. 258... CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Ground-Water Monitoring and Corrective Action § 258.51...

  5. Influence of long-term sewage irrigation on the distribution of organochlorine pesticides in soil-groundwater systems.

    Science.gov (United States)

    Zhang, Caixiang; Liao, Xiaoping; Li, Jiale; Xu, Liang; Liu, Ming; Du, Bin; Wang, Yanxin

    2013-07-01

    Serious shortage of water resources is one of the major factors restricting the sustainable development of cropland and pasture land in northern and northwestern China. Although the reuse of wastewater for agricultural irrigation becomes a well established practice in these regions, many contaminants have been also introduced into the soil-groundwater systems such as persistent organochlorine pesticides (OCPs). To study the influence of long-term sewage irrigation on the distribution of OCPs in soil-groundwater systems, the groundwater flow field was investigated and 31 topsoil samples, 9 boreholes, 11 sewage effluents and 34 groundwater samples were collected in Xiaodian, Taiyuan city, one of the largest sewage irrigation districts, China. During sampling, three representative types of regions were considered including effluent-irrigated area, groundwater-irrigated area served as the control field and no-irrigated area as reference "background". The results showed over-exploitation of groundwater had changed the flow field of groundwater and wherever in soil or in groundwater, the concentration of OCPs in effluent-irrigation area presented the highest value, which indicated that the sewage irrigation had a strong influence on the distribution of OCPs in soil-groundwater systems. Principal component analysis for OCPs content in groundwater showed that the major influence factors on the occurrence and distribution of OCPs in groundwater systems attribute to the flow field of groundwater and to the current pesticide use.

  6. Revised conceptualization of the North China Basin groundwater flow system: Groundwater age, heat and flow simulations

    Science.gov (United States)

    Cao, Guoliang; Han, Dongmei; Currell, Matthew J.; Zheng, Chunmiao

    2016-09-01

    Groundwater flow in deep sedimentary basins results from complex evolution processes on geological timescales. Groundwater flow systems conceptualized according to topography and/or groundwater table configuration generally assume a near-equilibrium state with the modern landscape. However, the time to reach such a steady state, and more generally the timescales of groundwater flow system evolution are key considerations for large sedimentary basins. This is true in the North China Basin (NCB), which has been studied for many years due to its importance as a groundwater supply. Despite many years of study, there remain contradictions between the generally accepted conceptual model of regional flow, and environmental tracer data. We seek to reconcile these contractions by conducting simulations of groundwater flow, age and heat transport in a three dimensional model, using an alternative conceptual model, based on geological, thermal, isotope and historical data. We infer flow patterns under modern hydraulic conditions using this new model and present the theoretical maximum groundwater ages under such a flow regime. The model results show that in contrast to previously accepted conceptualizations, most groundwater is discharged in the vicinity of the break-in-slope of topography at the boundary between the piedmont and central plain. Groundwater discharge to the ocean is in contrast small, and in general there are low rates of active flow in the eastern parts of the basin below the central and coastal plain. This conceptualization is more compatible with geochemical and geothermal data than the previous model. Simulated maximum groundwater ages of ∼1 Myrs below the central and coastal plain indicate that residual groundwater may be retained in the deep parts of the basin since being recharged during the last glacial period or earlier. The groundwater flow system has therefore probably not reached a new equilibrium state with modern-day hydraulic conditions. The

  7. Y-12 Groundwater Protection Program Groundwater and Surface Water Sampling and Analysis Plan For Calendar Year 2009

    Energy Technology Data Exchange (ETDEWEB)

    Elvado Environmental LLC

    2008-12-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2009 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2009 will be in accordance with DOE Order 540.1 requirements and the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2009 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation. Modifications to the CY 2009 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan

  8. Groundwater and Leachate Monitoring and Sampling at ERDF, CY 2008

    Energy Technology Data Exchange (ETDEWEB)

    R. L. Weiss; D. W. Woolery

    2009-09-03

    The purpose of this annual monitoring report is to evaluate the conditions of and identify trends for groundwater beneath the ERDF, to report leachate results in fulfillment of the requirements specified in the ERDF ROD and the ERDF Amended ROD.

  9. Performance assessment techniques for groundwater recovery and treatment systems

    Energy Technology Data Exchange (ETDEWEB)

    Kirkpatrick, G.L. [Environmental Resources Management, Inc., Exton, PA (United States)

    1993-03-01

    Groundwater recovery and treatment (pump and treat systems) continue to be the most commonly selected remedial technology for groundwater restoration and protection programs at hazardous waste sites and RCRA facilities nationwide. Implementing a typical groundwater recovery and treatment system includes the initial assessment of groundwater quality, characterizing aquifer hydrodynamics, recovery system design, system installation, testing, permitting, and operation and maintenance. This paper focuses on methods used to assess the long-term efficiency of a pump and treat system. Regulatory agencies and industry alike are sensitive to the need for accurate assessment of the performance and success of groundwater recovery systems for contaminant plume abatement and aquifer restoration. Several assessment methods are available to measure the long-term performance of a groundwater recovery system. This paper presents six assessment techniques: degree of compliance with regulatory agency agreement (Consent Order of Record of Decision), hydraulic demonstration of system performance, contaminant mass recovery calculation, system design and performance comparison, statistical evaluation of groundwater quality and preferably, integration of the assessment methods. Applying specific recovery system assessment methods depends upon the type, amount, and quality of data available. Use of an integrated approach is encouraged to evaluate the success of a groundwater recovery and treatment system. The methods presented in this paper are for engineers and corporate management to use when discussing the effectiveness of groundwater remediation systems with their environmental consultant. In addition, an independent (third party) system evaluation is recommended to be sure that a recovery system operates efficiently and with minimum expense.

  10. Selection of Sampling Pumps Used for Groundwater Monitoring at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Schalla, Ronald; Webber, William D.; Smith, Ronald M.

    2001-11-05

    The variable frequency drive centrifugal submersible pump, Redi-Flo2a made by Grundfosa, was selected for universal application for Hanford Site groundwater monitoring. Specifications for the selected pump and five other pumps were evaluated against current and future Hanford groundwater monitoring performance requirements, and the Redi-Flo2 was selected as the most versatile and applicable for the range of monitoring conditions. The Redi-Flo2 pump distinguished itself from the other pumps considered because of its wide range in output flow rate and its comparatively moderate maintenance and low capital costs. The Redi-Flo2 pump is able to purge a well at a high flow rate and then supply water for sampling at a low flow rate. Groundwater sampling using a low-volume-purging technique (e.g., low flow, minimal purge, no purge, or micropurgea) is planned in the future, eliminating the need for the pump to supply a high-output flow rate. Under those conditions, the Well Wizard bladder pump, manufactured by QED Environmental Systems, Inc., may be the preferred pump because of the lower capital cost.

  11. Data Validation Package May 2016 Groundwater Sampling at the Bluewater, New Mexico, Disposal Site, September 2016

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Dick [Navarro Nevada Environmental Services (NNES), Las Vegas, NV (United States); Tsosie, Bernadette [US Department of Energy, Washington, DC (United States)

    2016-09-01

    Groundwater samples were collected from monitoring wells at the Bluewater, New Mexico, Disposal Site to monitor groundwater contaminants as specified in the 1997 Long-Term Surveillance Plan for the DOE Bluewater (UMTRCA Title II) Disposal Site Near Grants, New Mexico (LTSP). Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location 16(SG).

  12. Recent developments in modeling groundwater systems

    Energy Technology Data Exchange (ETDEWEB)

    Narasimhan, T.N.; Witherspoon, P.A.

    1977-05-20

    This paper reviews the developments in the mathematical modeling of groundwater systems over the past decde. The first part of the paper is devoted to a description of the physics of the different types of problems that are of interest in hydrogeology and a statement of the related initial-boundary-value problems. The various numerical techniques that have been employed to solve the governing equations are discussed in the second part. In the third section a few typical case histories are presented to illustrate the trend of progress that has occurred in the application of mathematical modeling to actual field problems.

  13. Y-12 Groundwater Protection Program Groundwater and Surface water Sampling and Analysis Plan for Calendar Year 2006

    Energy Technology Data Exchange (ETDEWEB)

    N/A

    2006-01-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2006 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2006 will be in accordance with DOE Order 540.1 requirements and the following goals: {sm_bullet} to maintain surveillance of existing and potential groundwater contamination sources; {sm_bullet} to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; {sm_bullet} to identify and characterize long-term trends in groundwater quality at Y-12; and ! to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2006 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation (Figure A.1). Modifications to the CY 2006 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan. The following sections of

  14. Groundwater flow system in the valley of Toluca, Mexico: an assay of natural radionuclide specific activities.

    Science.gov (United States)

    Segovia, N; Tamez, E; Peña, P; Carrillo, J; Acosta, E; Armienta, M A; Iturbe, J L

    1999-03-01

    Natural radionuclides and physicochemical parameters have been evaluated in groundwater samples from boreholes belonging to the drinking water supply system of the Toluca City, Mexico. The results obtained for radon and radium, together with the physicochemical parameters of the studied samples, indicate a fast and efficient recharge pattern. The presence of a local and a regional groundwater flows was also observed. The local flow belongs to shallower water, recognized by its low radon content and dissolved ions, as compared with the regional, deeper groundwater flow with a longer residence time.

  15. A Numerical Study on System Performance of Groundwater Heat Pumps

    Directory of Open Access Journals (Sweden)

    Jin Sang Kim

    2015-12-01

    Full Text Available Groundwater heat pumps have energy saving potential where the groundwater resources are sufficient. System Coefficients of Performance (COPs are measurements of performance of groundwater heat pump systems. In this study, the head and power of submersible pumps, heat pump units, piping, and heat exchangers are expressed as polynomial equations, and these equations are solved numerically to determine the system performance. Regression analysis is used to find the coefficients of the polynomial equations from a catalog of performance data. The cooling and heating capacities of water-to-water heat pumps are determined using Energy Plus. Results show that system performance drops as the water level drops, and the lowest flow rates generally achieve the highest system performance. The system COPs are used to compare the system performance of various system configurations. The groundwater pumping level and temperature provide the greatest effects on the system performance of groundwater heat pumps along with the submersible pumps and heat exchangers. The effects of groundwater pumping levels, groundwater temperatures, and the heat transfer coefficient in heat exchanger on the system performance are given and compared. This analysis needs to be included in the design process of groundwater heat pump systems, possibly with analysis tools that include a wide range of performance data.

  16. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2008

    Energy Technology Data Exchange (ETDEWEB)

    Elvado Environmental LLC

    2007-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2008 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2008 will be in accordance with DOE Order 540.1 requirements and the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2008 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation (Figure A.1). Modifications to the CY 2008 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and

  17. January 2015 Groundwater Sampling at the Gnome-Coach, New Mexico, Site

    Energy Technology Data Exchange (ETDEWEB)

    Findlay, Rick [Navarro Research and Engineering, Oak Ridge, TN (United States); Kautsky, Mark [US Department of Energy, Washington, DC (United States). Office of Legacy Management

    2015-12-01

    Annual sampling was conducted January 27, 2015, to monitor groundwater for potential radionuclide contamination at the Gnome-Coach site in New Mexico. Samples were collected from wells USGS-1, USGS-4, and USGS-8 during this monitoring event. The sampling was performed as specified in the Sampling and Analysis Plan for US. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from well USGS-8 and water levels were measured in all the monitoring wells onsite. Refer to the sample location map for well locations. Samples were analyzed by GEL Laboratories in Charleston, South Carolina. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry, strontium-90, and tritium. The sample from well USGS-1 was analyzed for tritium using the enrichment method to achieve a lower minimum detectable concentration (MDC). Radionuclide contaminants were detected in wells USGS-4 and USGS-8. The detection of radionuclides in these wells was expected because the U.S. Geological Survey conducted a tracer test between these wells in 1963 using the dissolved radionuclides tritium, strontium-90, and cesium-137 as tracers. Radionuclide time-concentration graphs are included in this report for these wells. Analytical data obtained from this and past sampling events are also available in electronic format on the U.S. Department of Energy Office of Legacy Management Geospatial Environmental Mapping System website at http://gems.lm.doe.gov/#site=GNO.

  18. Evolution of Quaternary groundwater system in North China Plain

    Institute of Scientific and Technical Information of China (English)

    张宗祜; 施德鸿; 任福弘; 殷正宙; 孙继朝; 张翠云

    1997-01-01

    The Quaternary groundwater system in the North China Plain is formed mainly through the terrestrial water flow action on the united geological and tectonic backgrounds. The analysis of groundwater dynamic field, simulation of groundwater geochemistry, and the 14C dating and extraction of isotope information have provided more evidence for recognizing and assessing the evolution of groundwater circulation system and studying the past global changes. The exploitation and utilization of groundwater on a large scale and overexploitation have given rise to the decline of regional groundwater level, change of flow field, decrease of water resources and downward movement of saline water body. The water environment has entered a new evolution stage in which it is intensely disturbed by the mankind’s activities.

  19. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2010

    Energy Technology Data Exchange (ETDEWEB)

    Elvado Environmental LLC

    2009-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2010 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2010 will be in accordance with requirements of DOE Order 540.1A and the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2010 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation. Modifications to the CY 2010 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan

  20. Groundwater quality sampling and analysis plan for environmental monitoring in Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-01

    This Sampling and Analysis Plan addresses groundwater quality sampling and analysis activities that will be conducted in support of the Environmental Monitoring Plan for Waste Area Grouping (WAG) 6. WAG 6 is a shallow-burial land disposal facility for low-level radioactive waste at the Oak Ridge National Laboratory, a research facility owned by the US Department of energy and managed by martin Marietta Energy Systems, Inc. (Energy Systems). Groundwater sampling will be conducted by Energy Systems at 45 wells within WAG 6. The samples will be analyzed for various organic, inorganic, and radiological parameters. The information derived from the groundwater quality monitoring, sampling, and analysis will aid in evaluating relative risk associated with contaminants migrating off-WAG, and also will fulfill Resource Conservation and Recovery Act (RCRA) interim permit monitoring requirements. The sampling steps described in this plan are consistent with the steps that have previously been followed by Energy Systems when conducting RCRA sampling.

  1. Groundwater Quality Sampling and Analysis Plan for Environmental Monitoring Waste Area Grouping 6 at Oak Ridge National Laboratory. Environmental Restoration Program

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    This Sampling and Analysis Plan addresses groundwater quality sampling and analysis activities that will be conducted in support of the Environmental Monitoring Plan for Waste Area Grouping (WAG) 6. WAG 6 is a shallow-burial land disposal facility for low-level radioactive waste at the Oak Ridge National Laboratory, a research facility owned by the US Department of Energy and managed by Martin Marietta Energy Systems, Inc. (Energy Systems). Groundwater sampling will be conducted by Energy Systems at 45 wells within WAG 6. The samples will be analyzed for various organic, inorganic, and radiological parameters. The information derived from the groundwater quality monitoring, sampling, and analysis will aid in evaluating relative risk associated with contaminants migrating off-WAG, and also will fulfill Resource Conservation and Recovery Act (RCRA) interim permit monitoring requirements. The sampling steps described in this plan are consistent with the steps that have previously been followed by Energy Systems when conducting RCRA sampling.

  2. Groundwater flow and mixing in a wetland–stream system

    DEFF Research Database (Denmark)

    Karan, Sachin; Engesgaard, Peter Knudegaard; Zibar, Majken Caroline Looms;

    2013-01-01

    We combined electrical resistivity tomography (ERT) on land and in a stream with zone-based hydraulic conductivities (from multi-level slug testing) to investigate the local geological heterogeneity of the deposits in a wetland–stream system. The detailed geology was incorporated into a numerical....... The presented approach of integrating such methods in groundwater–surface water exchange studies, proved efficient to obtain information of the controlling factors....... steady-state groundwater model that was calibrated against average head observations. The model results were tested against groundwater fluxes determined from streambed temperature measurements. Discharge varied up to one order of magnitude across the stream and the model was successful in capturing...... this variability. Water quality analyses from multi-level sampling underneath the streambed and in the wetland showed a stratification in groundwater composition with an aerobic shallow zone with oxygen and nitrate (top ∼3 m) overlying a reduced, anoxic zone. While NO3- concentrations up to 58 mg L−1 were found...

  3. A New Geochemical Reaction Model for Groundwater Systems

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Through a survey of the literature on geology, hydrogeology and hydrogeochemistry, this paper presents a hydrogeochemical model for the groundwater system in a dross-dumping area of the Shandong Aluminium Plant. It is considered that the groundwater-bearing medium is a mineral aggregate and that the interactions between groundwater and the groundwater-bearing medium can be described as a series of geochemical reactions. On that basis, the principle of minimum energy and the equations of mass balance, electron balance and electric neutrality are applied to construct a linear programming mathematical model for the calculation of mass transfer between water and rock with the simplex method.

  4. Understanding similarity of groundwater systems with empirical copulas

    Science.gov (United States)

    Haaf, Ezra; Kumar, Rohini; Samaniego, Luis; Barthel, Roland

    2016-04-01

    Within the classification framework for groundwater systems that aims for identifying similarity of hydrogeological systems and transferring information from a well-observed to an ungauged system (Haaf and Barthel, 2015; Haaf and Barthel, 2016), we propose a copula-based method for describing groundwater-systems similarity. Copulas are an emerging method in hydrological sciences that make it possible to model the dependence structure of two groundwater level time series, independently of the effects of their marginal distributions. This study is based on Samaniego et al. (2010), which described an approach calculating dissimilarity measures from bivariate empirical copula densities of streamflow time series. Subsequently, streamflow is predicted in ungauged basins by transferring properties from similar catchments. The proposed approach is innovative because copula-based similarity has not yet been applied to groundwater systems. Here we estimate the pairwise dependence structure of 600 wells in Southern Germany using 10 years of weekly groundwater level observations. Based on these empirical copulas, dissimilarity measures are estimated, such as the copula's lower- and upper corner cumulated probability, copula-based Spearman's rank correlation - as proposed by Samaniego et al. (2010). For the characterization of groundwater systems, copula-based metrics are compared with dissimilarities obtained from precipitation signals corresponding to the presumed area of influence of each groundwater well. This promising approach provides a new tool for advancing similarity-based classification of groundwater system dynamics. Haaf, E., Barthel, R., 2015. Methods for assessing hydrogeological similarity and for classification of groundwater systems on the regional scale, EGU General Assembly 2015, Vienna, Austria. Haaf, E., Barthel, R., 2016. An approach for classification of hydrogeological systems at the regional scale based on groundwater hydrographs EGU General Assembly

  5. Data validation report for the 100-FR-3 Operable Unit, third round groundwater samples

    Energy Technology Data Exchange (ETDEWEB)

    Ayres, J.M.

    1994-03-31

    Westinghouse-Hanford has requested that a minimum of 20% of the total number of Sample Delivery Groups be validated for the 100-FR-3 operable Unit Third Round Groundwater sampling investigation. Therefore, the data from the chemical analysis of 51 samples from this sampling event and their related quality assurance samples were reviewed and validated to verify that reported sample results were of sufficient quality to support decisions regarding remedial actions performed at this site. The report is broken down into sections for each chemical analysis and radiochemical analysis type. Each section addresses the data package completeness, holding time adherence, instrument calibration and tuning acceptability, blank results, accuracy, precision, system performance, as well as the compound identification and quantitation. In addition, each section has an overall assessment and summary for the data packages reviewed for the particular chemical/radiochemical analyses. Detailed backup information is provided to the reader by SDG No. and sample number. For each data package, a matrix of chemical analyses per sample number is presented, as well as data qualification summaries.

  6. Data Validation Package - July 2016 Groundwater Sampling at the Gunnison, Colorado, Disposal Site

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Joshua [USDOE Office of Legacy Management, Washington, DC (United States); Campbell, Sam [Navarro Research and Engineering, Inc., Las Vegas, NV (United States)

    2016-10-25

    Groundwater sampling at the Gunnison, Colorado, Disposal Site is conducted every 5 years to monitor disposal cell performance. During this event, samples were collected from eight monitoring wells as specified in the 1997 Long-Term Surveillance Plan for the Gunnison, Colorado, Disposal Site. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for US Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and­ analysis-plan-us-department-energy-office-legacy-management-sites). Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. A duplicate sample was collected from location 0723. Water levels were measured at all monitoring wells that were sampled and seven additional wells. The analytical data and associated qualifiers can be viewed in environmental database reports and are also available for viewing with dynamic mapping via the GEMS (Geospatial Environmental Mapping System) website at http://gems.lm.doe.gov/#. No issues were identified during the data validation process that require additional action or follow-up.

  7. Pumpage for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents ground-water discharged from the Death Valley regional ground-water flow system (DVRFS) through pumped wells. Pumping from wells in...

  8. Data validation report for the 100-HR-3 Operable Unit, fifth round groundwater samples

    Energy Technology Data Exchange (ETDEWEB)

    Vukelich, S.E. [Kearney (A.T.), Inc., Chicago, IL (United States)

    1994-01-20

    The data from the chemical analysis of 68 samples from the 100-HR-3 Operable Unit Third Quarter 1993 Groundwater Sampling Investigation and their related quality assurance samples were reviewed and validated to verify that reported sample results were of sufficient quality to support decisions regarding remedial actions performed at the site. Sample analysis included inorganics and general chemical parameters. Fifty three samples were validated for radiochemical parameters.

  9. Radionuclides in groundwater flow system understanding

    Science.gov (United States)

    Erőss, Anita; Csondor, Katalin; Horváth, Ákos; Mádl-Szőnyi, Judit; Surbeck, Heinz

    2017-04-01

    Using radionuclides is a novel approach to characterize fluids of groundwater flow systems and understand their mixing. Particularly, in regional discharge areas, where different order flow systems convey waters with different temperature, composition and redox-state to the discharge zone. Radium and uranium are redox-sensitive parameters, which causes fractionation along groundwater flow paths. Discharging waters of regional flow systems are characterized by elevated total dissolved solid content (TDS), temperature and by reducing conditions, and therefore with negligible uranium content, whereas local flow systems have lower TDS and temperature and represent oxidizing environments, and therefore their radium content is low. Due to the short transit time, radon may appear in local systems' discharge, where its source is the soil zone. However, our studies revealed the importance of FeOOH precipitates as local radon sources throughout the adsorption of radium transported by the thermal waters of regional flow systems. These precipitates can form either by direct oxidizing of thermal waters at discharge, or by mixing of waters with different redox state. Therefore elevated radon content often occurs in regional discharge areas as well. This study compares the results of geochemical studies in three thermal karst areas in Hungary, focusing on radionuclides as natural tracers. In the Buda Thermal Karst, the waters of the distinct discharge areas are characterized by different temperature and chemical composition. In the central discharge area both lukewarm (20-35°C, 770-980 mg/l TDS) and thermal waters (40-65°C, 800-1350 mg/l TDS), in the South only thermal water discharge (33-43°C, 1450-1700 mg/l TDS) occur. Radionuclides helped to identify mixing of fluids and to infer the temperature and chemical composition of the end members for the central discharge area. For the southern discharge zone mixing components could not be identified, which suggests different cave

  10. In-situ remediation system for groundwater and soils

    Science.gov (United States)

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1991-01-01

    The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  11. Groundwater detection monitoring system design under conditions of uncertainty

    NARCIS (Netherlands)

    Yenigül, N.B.

    2006-01-01

    Landfills represent a wide-spread and significant threat to groundwater quality. In this thesis a methodology was developed for the design of optimal groundwater moni-toring system design at landfill sites under conditions of uncertainty. First a decision analysis approach was presented for optimal

  12. Is groundwater age the main control for slow turnover of nitrate in a fractured groundwater system?

    Science.gov (United States)

    Osenbrück, Karsten; Schwientek, Marc; Rügner, Hermann; Grathwohl, Peter

    2015-04-01

    Slow transformation processes are known to control the chemical, isotopic, and redox evolution of large-scale aquifers (Edmunds et al., 1982; Katz et al., 1995). However, at the field scale some of the crucial biogeochemical processes governing pollutant turnover and their interrelations with hydrology are poorly understood. Particularly, only little is known about denitrification in fractured rock aquifers. Therefore, the main objective of the presented study is to assess where and how slow turnover of nitrate ans other pollutants in the deeper subsurface take place. The studied fractured and partly karstified aquifer consisting of Triassic black limestones and dolomites is located in the catchment of the Ammer river (ca. 350 km²) close to Tübingen in southern Germany. Near the recharge area, the aquifer is covered by loess allowing intensive agriculture. Further downgradient, the cover consist of a series of mudstones and sandstones of variable permeability. The aquifer is used for drinking water purposes by regional water suppliers. Land-use is dominated by agriculture with arable land covering nearly 50% of the catchment. Over the last years a variety of groundwater samples have been collected from the groundwater system including 6 water supply wells, 4 karstic springs, and 9 monitoring wells in the recharge area. This allowed to identify spatial and temporal patterns of water quality including concentrations of major ions, dissolved organic carbon (DOC), organic pollutants (e.g., pesticides), and environmental isotopes. Groundwater age distributions at most of these locations were derived from tritium, 3He, CFCs and SF6. Groundwaters in the recharge area show high concentrations of nutrients (e.g. 20-51 mg/L of nitrate and 0.2 to 0.05 µg/L of phosphate). Of special concern are disparate nitrate concentrations ranging from below 0.4 to 20 mg/L in water supply wells although screen depths of the production wells are similar. Concentrations of dissolved

  13. Groundwater monitoring programme. A guide for groundwater sampling and analysis. 2. ed.; Grundwasserueberwachungsprogramm. Leitfaden fuer Probenahme und Analytik von Grundwasser

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    Quality assurance guidelines have been developed and introduced in Baden-Wuerttemberg for groundwater monitoring. The contribution contains the fundamentals and technical guides for sampling and measurement of the Baden-Wuerttemberg groundwater monitoring programme, as well as parameter groups and a preliminary assessment of the methods. [German] Bei der Gewinnung von Umweltdaten sind hohe Anforderungen an die Qualitaet der erhobenen Daten zu stellen. Dies trifft in besonderem Masse gerade auch fuer Grundwasseruntersuchungen zu, da hier haeufig Konzentrationen im Bereich der Nachweisgrenze auftreten. Fuer das Grundwassermessnetz Baden-Wuerttemberg sind qualitaetssichernde Regelungen entwickelt und eingefuehrt worden. In der vorliegenden Zusammenstellung sind die Grundsatzpapiere, bzw. Technischen Anleitungen aus dem Grundwasserueberwachungsprogramm Baden-Wuerttemberg fuer die Grundwasserprobennahme sowie zu Messverfahren, Parametergruppen und zur ersten Beurteilung der Messergebnisse enthalten. (orig.)

  14. The Savannah River Site`s groundwater monitoring program: 1990 sampling schedule

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, C.D. [Westinghouse Savannah River Co., Aiken, SC (United States)

    1991-02-07

    This schedule provides a final record of the 1990 sampling schedule for the SRS groundwater monitoring program conducted by the Environmental Protection Department/Environmental Section (EPD/EMS). It includes all the wells monitored by EPD/EMS at SRS during 1990 and identifies the constituents sampled, the sampling frequency, and the reasons for sampling. Sampling requests are incorporated into the schedule throughout the year. Drafts of the schedule are produced and revised quarterly.

  15. Control of Groundwater Remediation Process as Distributed Parameter System

    Directory of Open Access Journals (Sweden)

    Mendel M.

    2014-12-01

    Full Text Available Pollution of groundwater requires the implementation of appropriate solutions which can be deployed for several years. The case of local groundwater contamination and its subsequent spread may result in contamination of drinking water sources or other disasters. This publication aims to design and demonstrate control of pumping wells for a model task of groundwater remediation. The task consists of appropriately spaced soil with input parameters, pumping wells and control system. Model of controlled system is made in the program MODFLOW using the finitedifference method as distributed parameter system. Control problem is solved by DPS Blockset for MATLAB & Simulink.

  16. Microbial degradation of chloroethenes in groundwater systems

    Science.gov (United States)

    Bradley, Paul M.

    The chloroethenes, tetrachloroethene (PCE) and trichloroethene (TCE) are among the most common contaminants detected in groundwater systems. As recently as 1980, the consensus was that chloroethene compounds were not significantly biodegradable in groundwater. Consequently, efforts to remediate chloroethene-contaminated groundwater were limited to largely unsuccessful pump-and-treat attempts. Subsequent investigation revealed that under reducing conditions, aquifer microorganisms can reductively dechlorinate PCE and TCE to the less chlorinated daughter products dichloroethene (DCE) and vinyl chloride (VC). Although recent laboratory studies conducted with halorespiring microorganisms suggest that complete reduction to ethene is possible, in the majority of groundwater systems reductive dechlorination apparently stops at DCE or VC. However, recent investigations conducted with aquifer and stream-bed sediments have demonstrated that microbial oxidation of these reduced daughter products can be significant under anaerobic redox conditions. The combination of reductive dechlorination of PCE and TCE under anaerobic conditions followed by anaerobic microbial oxidation of DCE and VC provides a possible microbial pathway for complete degradation of chloroethene contaminants in groundwater systems. Résumé Les chloroéthanes, tétrachloroéthane (PCE) et trichloroéthane (TCE) sont parmi les polluants les plus communs trouvés dans les aquifères. Depuis les années 1980, on considère que les chloroéthanes ne sont pas significativement biodégradables dans les aquifères. Par conséquent, les efforts pour dépolluer les nappes contaminées par des chloroéthanes se sont limités à des tentatives de pompage-traitement globalement sans succès. Des travaux ultérieurs ont montré que dans des conditions réductrices, des micro-organismes présents dans les aquifères peuvent, par réduction, dégrader les PCE et TCE en composés moins chlorés, comme le dichlor

  17. STATISTICAL INVESTIGATION OF THE GROUNDWATER SYSTEM IN DARB EL-ARBAEIN, SOUTHWESTERN DESERT, EGYPT

    Directory of Open Access Journals (Sweden)

    Kashouty Mohamed El

    2009-12-01

    Full Text Available In Darb El Arbaein, the groundwater is the only water resources. The aquifer system starts from Paleozoic-Mesozoic to Upper Cretaceous sandstone rocks. They overlay the basement rocks and the aquifer is confined. In the present research, the performance of the statistical analyses to classify groundwater samples depending on their chemical characters has been tested. The hydrogeological and hydrogeochemical data of 92 groundwater samples was obtained from the GARPAD authority in northern, central, and southern Darb El Arbaein. A robust classification scheme for partitioning groundwater chemistry into homogeneous groups was an important tool for the characterization of Nubian sandstone aquifer. We test the performance of the many available graphical and statistical methodologies used to classify water samples. R-mode, Q-mode, correlation analysis, and principal component analysis were investigated. All the methods were discussed and compared as to their ability to cluster, ease of use, and ease of interpretation. The correlation investigation clarifies the relationship among the lithology, hydrogeology, and anthropogenic. Factor investigation revealed three factors namely; the evaporation process-agriculturalimpact-lithogenic dissolution, the hydrogeological characteristics of the aquifer system, and the surface meteoric water that rechargethe aquifer system. Two main clusters that subdivided into four sub clusters were identified in groundwater system based on hydrogeological and hydrogeochemical data. They reflect the impact of geomedia, hydrogeology, geographic position, and agricultural wastewater. The groundwater is undersaturated with respect to most selected minerals. The groundwater was supersaturated with respect to iron minerals in northern and southern Darb El Arbaein. The partial pressure of CO2 of the groundwater versus saturation index of calcite shows the gradual change in PCO2 from atmospheric to the present aquifer

  18. Septic Systems Contribution to Phosphorus in Shallow Groundwater: Field-Scale Studies Using Conventional Drainfield Designs

    Science.gov (United States)

    Mechtensimer, Sara

    2017-01-01

    Septic systems can be a potential source of phosphorus (P) in groundwater and contribute to eutrophication in aquatic systems. Our objective was to investigate P transport from two conventional septic systems (drip dispersal and gravel trench) to shallow groundwater. Two new in-situ drainfields (6.1 m long by 0.61 m wide) with a 3.72 m2 infiltrative surface were constructed. The drip dispersal drainfield was constructed by placing 30.5 cm commercial sand on top of natural soil and the gravel trench drainfield was constructed by placing 30.5 cm of gravel on top of 30.5 cm commercial sand and natural soil. Suction cup lysimeters were installed in the drainfields (at 30.5, 61, 106.7 cm below infiltrative surface) and piezometers were installed in the groundwater (>300 cm below infiltrative surface) to capture P dynamics from the continuum of unsaturated to saturated zones in the septic systems. Septic tank effluent (STE), soil-water, and groundwater samples were collected for 64 events (May 2012–Dec 2013) at 2 to 3 days (n = 13), weekly (n = 29), biweekly (n = 17), and monthly (n = 5) intervals. One piezometer was installed up-gradient of the drainfields to monitor background groundwater (n = 15). Samples were analyzed for total P (TP), orthophosphate-P (PO4–P), and other–P (TP—PO4-P). The gravel trench drainfield removed significantly (p300 cm in the groundwater, both systems had similar TP reductions of >97%. After 18 months of STE application, there was no significant increase in groundwater TP concentrations in both systems. We conclude that both drainfield designs are effective at reducing P transport to shallow groundwater. PMID:28107505

  19. Septic Systems Contribution to Phosphorus in Shallow Groundwater: Field-Scale Studies Using Conventional Drainfield Designs.

    Science.gov (United States)

    Mechtensimer, Sara; Toor, Gurpal S

    2017-01-01

    Septic systems can be a potential source of phosphorus (P) in groundwater and contribute to eutrophication in aquatic systems. Our objective was to investigate P transport from two conventional septic systems (drip dispersal and gravel trench) to shallow groundwater. Two new in-situ drainfields (6.1 m long by 0.61 m wide) with a 3.72 m2 infiltrative surface were constructed. The drip dispersal drainfield was constructed by placing 30.5 cm commercial sand on top of natural soil and the gravel trench drainfield was constructed by placing 30.5 cm of gravel on top of 30.5 cm commercial sand and natural soil. Suction cup lysimeters were installed in the drainfields (at 30.5, 61, 106.7 cm below infiltrative surface) and piezometers were installed in the groundwater (>300 cm below infiltrative surface) to capture P dynamics from the continuum of unsaturated to saturated zones in the septic systems. Septic tank effluent (STE), soil-water, and groundwater samples were collected for 64 events (May 2012-Dec 2013) at 2 to 3 days (n = 13), weekly (n = 29), biweekly (n = 17), and monthly (n = 5) intervals. One piezometer was installed up-gradient of the drainfields to monitor background groundwater (n = 15). Samples were analyzed for total P (TP), orthophosphate-P (PO4-P), and other-P (TP-PO4-P). The gravel trench drainfield removed significantly (p300 cm in the groundwater, both systems had similar TP reductions of >97%. After 18 months of STE application, there was no significant increase in groundwater TP concentrations in both systems. We conclude that both drainfield designs are effective at reducing P transport to shallow groundwater.

  20. Interpretation of stable isotope, denitrification, and groundwater age data for samples collected from Sandia National Laboratories /New Mexico (SNL/NM) Burn Site Groundwater Area of Concern

    Energy Technology Data Exchange (ETDEWEB)

    Madrid, V. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Singleton, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Visser, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Esser, B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-06-02

    This report combines and summarizes results for two groundwater-sampling events (October 2012 and October/November 2015) from the Sandia National Laboratories/New Mexico (SNL/NM) Burn Site Groundwater (BSG) Area of Concern (AOC) located in the Lurance Canyon Arroyo southeast of Albuquerque, NM in the Manzanita Mountains. The first phase of groundwater sampling occurred in October 2012 including samples from 19 wells at three separate sites that were analyzed by the Environmental Radiochemistry Laboratory at Lawrence Livermore National Laboratory (LLNL, Madrid et al., 2013) as part of a nitrate Monitored Natural Attenuation (MNA) evaluation. The three sites (BSG, Technical Area-V, and Tijeras Arroyo) are shown on the regional hydrogeologic map (Figure 1) and described in the Sandia Annual Groundwater Monitoring Report (Jackson et al., 2011). The first phase of groundwater sampling included six monitoring wells at the Burn Site, eight monitoring wells at Technical Area-V, and five monitoring wells at Tijeras Arroyo. Each groundwater sample was analyzed using the two specialized analytical methods, age-dating and denitrification suites (Table 1). In September 2015, a second phase of groundwater sampling took place at the Burn Site including 10 wells sampled and analyzed by the same two analytical suites. Five of the six wells sampled in 2012 were resampled in 2015

  1. California GAMA Special Study. Development of a Capability for the Analysis of Krypton-85 in Groundwater Samples

    Energy Technology Data Exchange (ETDEWEB)

    Visser, Ate [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bibby, Richard K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Moran, Jean E. [California State Univ. (CalState), Long Beach, CA (United States); Singleton, Michael J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Esser, Bradley K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-06-01

    A capability for the analysis of krypton-85 (85Kr) in groundwater samples was developed at LLNL. Samples are collected by extracting gas from 2000-4000 L of groundwater at the well, yielding approximately 0.2 cm3 STP krypton. Sample collection takes 1 to 4 hours. Krypton is purified in the laboratory using a combination of molecular sieve and activated charcoal traps, and transferred to a liquid scintillation vial. The 85Kr activity is measured by liquid scintillation on a Quantulus 1220 liquid scintillation counter from PerkinElmer. The detection limit for a typical 0.2 cm3Kr sample size is 11% of the present day activity in air, corresponding to the decay corrected activity in air in 1987. The typical measurement uncertainty is below 10% for recently recharged samples. Six groundwater samples were collected, purified and counted. 85Kr was not detected in any of the samples counted at LLNL. 85Kr was detected by the low level counting laboratory of Bern University in all samples between 1.5 and 6.6 decays per minute per cm3 krypton, corresponding to decay corrected activities in air between 1971 and 1985. The new capability is an excellent complement to tritium-helium, expanding the existing suite of age dating tools available to the GAMA program (35S, 3H/3He, 14C and radiogenic helium). 85Kr can replace 3H/3He in settings where 3H/3He ages are impossible to determine (for example where terrigenic helium overwhelms tritiogenic helium) and provides additional insight into travel time distributions in complex mixed groundwater systems.

  2. Data Validation Package February 2016 Groundwater and Surface Water Sampling at the Tuba City, Arizona, Disposal Site April 2016

    Energy Technology Data Exchange (ETDEWEB)

    Bush, Richard [USDOE Office of Legacy Management, Washington, DC (United States); Lemke, Peter [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-04-01

    The groundwater compliance strategy for the Tuba City, Arizona, Disposal Site is defined in the 1999 Phase I Ground Water Compliance Action Plan for the Tuba City, Arizona, UMTRA Site. Samples are collected and analyzed on a semiannual basis to evaluate the performance of the Phase I remediation system. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). U.S. Environmental Protection Agency (EPA) groundwater standards were exceeded in samples collected from monitoring wells as listed in Table 1. The data from this sampling event are generally consistent with previously obtained values and are acceptable for general use as qualified. Data anomalies are not significant with respect to the known nature and extent of contamination and progress of remedial action at the site. The data from this sampling event will be incorporated into the annual performance evaluation report that will present a comprehensive hydrologic summary and evaluation of groundwater remedial action performance at the Tuba City site through March 2016.

  3. Data Validation Package August 2015 Groundwater and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2015

    Energy Technology Data Exchange (ETDEWEB)

    Bush, Richard [USDOE Office of Legacy Management, Washington, DC (United States); Lemke, Peter [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2015-11-01

    The groundwater compliance strategy for the Tuba City, Arizona, Disposal Site is defined in the 1999 Phase I Ground Water Compliance Action Plan for the Tuba City, Arizona, UMTRA Site. Samples are collected and analyzed on a semiannual basis to evaluate the performance of the Phase I remediation system. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). U.S. Environmental Protection Agency (EPA) groundwater standards were exceeded in samples collected from monitoring wells and extraction wells as listed in Table 1. The data from this sampling event are generally consistent with previously obtained values and are acceptable for general use as qualified. Data anomalies are not significant with respect to the known nature and extent of contamination and progress of remedial action at the site. The data from this sampling event will be incorporated into the annual performance evaluation report that will present a comprehensive hydrologic summary and evaluation of groundwater remedial action performance at the Tuba City site through March 2016.

  4. Y-12 Plant Groundwater Protection Program Groundwater and Surface Water sampling and Analysis Plan for Calendar Year 2000

    Energy Technology Data Exchange (ETDEWEB)

    None

    1999-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2000 at the U.S. Department of Energy (DOE) Y-12 Plant that will be managed by tie Y-12 Plant Groundwater Protection Program (GWPP). Groundwater and surface water monitoring during CY 2000 will be performed in three hydrogeologic regimes at the Y-12 Plant: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of the Y-12 Plant (Figure 1). Groundwater and surface water monitoring performed under the auspices of the Y-12 Plant GWPP during CY 2000 will comply with: Tennessee Department of Environment and Conservation regulations governing detection monitoring at nonhazardous Solid Waste Disposal Facilities (SWDF); and DOE Order 5400.1 surveillance monitoring and exit pathway/perimeter monitoring. Some of the data collected for these monitoring drivers also will be used to meet monitoring requirements of the Integrated Water Quality Program, which is managed by Bechtel Jacobs Company LLC. Data from five wells that are monitored for SWDF purposes in the Chestnut Ridge Regime will be used to comply with requirements specified in the Resource Conservation and Recovery Act post closure permit regarding corrective action monitoring. Modifications to the CY 2000 monitoring program may be necessary during implementation. Changes in regulatory or programmatic requirements may alter the analytes specified for selected monitoring wells, or wells could be added or removed from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 Plant GWPP manager and documented as addenda to this sampling and analysis plan.

  5. Optimization of groundwater sampling approach under various hydrogeological conditions using a numerical simulation model

    Science.gov (United States)

    Qi, Shengqi; Hou, Deyi; Luo, Jian

    2017-09-01

    This study presents a numerical model based on field data to simulate groundwater flow in both the aquifer and the well-bore for the low-flow sampling method and the well-volume sampling method. The numerical model was calibrated to match well with field drawdown, and calculated flow regime in the well was used to predict the variation of dissolved oxygen (DO) concentration during the purging period. The model was then used to analyze sampling representativeness and sampling time. Site characteristics, such as aquifer hydraulic conductivity, and sampling choices, such as purging rate and screen length, were found to be significant determinants of sampling representativeness and required sampling time. Results demonstrated that: (1) DO was the most useful water quality indicator in ensuring groundwater sampling representativeness in comparison with turbidity, pH, specific conductance, oxidation reduction potential (ORP) and temperature; (2) it is not necessary to maintain a drawdown of less than 0.1 m when conducting low flow purging. However, a high purging rate in a low permeability aquifer may result in a dramatic decrease in sampling representativeness after an initial peak; (3) the presence of a short screen length may result in greater drawdown and a longer sampling time for low-flow purging. Overall, the present study suggests that this new numerical model is suitable for describing groundwater flow during the sampling process, and can be used to optimize sampling strategies under various hydrogeological conditions.

  6. A Mars Sample Return Sample Handling System

    Science.gov (United States)

    Wilson, David; Stroker, Carol

    2013-01-01

    We present a sample handling system, a subsystem of the proposed Dragon landed Mars Sample Return (MSR) mission [1], that can return to Earth orbit a significant mass of frozen Mars samples potentially consisting of: rock cores, subsurface drilled rock and ice cuttings, pebble sized rocks, and soil scoops. The sample collection, storage, retrieval and packaging assumptions and concepts in this study are applicable for the NASA's MPPG MSR mission architecture options [2]. Our study assumes a predecessor rover mission collects samples for return to Earth to address questions on: past life, climate change, water history, age dating, understanding Mars interior evolution [3], and, human safety and in-situ resource utilization. Hence the rover will have "integrated priorities for rock sampling" [3] that cover collection of subaqueous or hydrothermal sediments, low-temperature fluidaltered rocks, unaltered igneous rocks, regolith and atmosphere samples. Samples could include: drilled rock cores, alluvial and fluvial deposits, subsurface ice and soils, clays, sulfates, salts including perchlorates, aeolian deposits, and concretions. Thus samples will have a broad range of bulk densities, and require for Earth based analysis where practical: in-situ characterization, management of degradation such as perchlorate deliquescence and volatile release, and contamination management. We propose to adopt a sample container with a set of cups each with a sample from a specific location. We considered two sample cups sizes: (1) a small cup sized for samples matching those submitted to in-situ characterization instruments, and, (2) a larger cup for 100 mm rock cores [4] and pebble sized rocks, thus providing diverse samples and optimizing the MSR sample mass payload fraction for a given payload volume. We minimize sample degradation by keeping them frozen in the MSR payload sample canister using Peltier chip cooling. The cups are sealed by interference fitted heat activated memory

  7. Preserving the distribution of inorganic arsenic species in groundwater and acid mine drainage samples

    Science.gov (United States)

    Bednar, A.J.; Garbarino, J.R.; Ranville, J.F.; Wildeman, T.R.

    2002-01-01

    The distribution of inorganic arsenic species must be preserved in the field to eliminate changes caused by metal oxyhydroxide precipitation, photochemical oxidation, and redox reactions. Arsenic species sorb to iron and manganese oxyhydroxide precipitates, and arsenite can be oxidized to arsenate by photolytically produced free radicals in many sample matrices. Several preservatives were evaluated to minimize metal oxyhydroxide precipitation, such as inorganic acids and ethylenediaminetetraacetic acid (EDTA). EDTA was found to work best for all sample matrices tested. Storing samples in opaque polyethylene bottles eliminated the effects of photochemical reactions. The preservation technique was tested on 71 groundwater and six acid mine drainage samples. Concentrations in groundwater samples reached 720 ??g-As/L for arsenite and 1080 ??g-As/L for arsenate, and acid mine drainage samples reached 13 000 ??g-As/L for arsenite and 3700 ??g-As/L for arsenate. The arsenic species distribution in the samples ranged from 0 to 90% arsenite. The stability of the preservation technique was established by comparing laboratory arsenic speciation results for samples preserved in the field to results for subsamples speciated onsite. Statistical analyses indicated that the difference between arsenite and arsenate concentrations for samples preserved with EDTA in opaque bottles and field speciation results were analytically insignificant. The percentage change in arsenite:arsenate ratios for a preserved acid mine drainage sample and groundwater sample during a 3-month period was -5 and +3%, respectively.

  8. [Hydrogeochemical characteristics of a typical karst groundwater system in Chongqing].

    Science.gov (United States)

    Yang, Ping-Heng; Lu, Bing-Qing; He, Qiu-Fang; Chen, Xue-Bin

    2014-04-01

    The two-year hydrologic process, hydrochemistry, and a portion of deltaD, delta18O of both the surface water at the inlet and the groundwater at the outlet, were investigated to identify the spatial and temporal variations of hydrogeochemistry in the Qingmuguan karst groundwater system. Research results show that there are wet and dry periods in the groundwater system owing to the striking influence of seasonal rainfall. The evolution of the chemical compositions in the groundwater is significantly influenced by the water and rock interaction, anthropogenic activities and rainwater dilution. The variations of the chemical compositions in the groundwater exhibit obvious spatiality and temporality. The deltaD and delta18O of the surface water beneath the local Meteoric Water Line of Chonqing indicate that the surface water is strongly evaporated. Furthermore, the deltaD and delta18O of the surface water are more positive in the dry period than in the wet period, showing a distinct seasonal effect. The deltaD and delta18O of the groundwater are quite stable and much negative compared with those of the surface water, which suggests that the rainwater recharge the groundwater via two pathways, one directly through sinkholes and the other via the vadose zone.

  9. Effect of the extent of well purging on laboratory parameters of groundwater samples

    Science.gov (United States)

    Reka Mathe, Agnes; Kohler, Artur; Kovacs, Jozsef

    2017-04-01

    Chemicals reaching groundwater cause water quality deterioration. Reconnaissance and remediation demands high financial and human resources. Groundwater samples are important sources of information. Representativity of these samples is fundamental to decision making. According to relevant literature the way of sampling and the sampling equipment can affect laboratory concentrations measured in samples. Detailed and systematic research on this field is missing from even international literature. Groundwater sampling procedures are regulated worldwide. Regulations describe how to sample a groundwater monitoring well. The most common element in these regulations is well purging prior to sampling. The aim of purging the well is to avoid taking the sample from the stagnant water instead of from formation water. The stagnant water forms inside and around the well because the well casing provides direct contact with the atmosphere, changing the physico-chemical composition of the well water. Sample from the stagnant water is not representative of the formation water. Regulations regarding the extent of the purging are different. Purging is mostly defined as multiply (3-5) well volumes, and/or reaching stabilization of some purged water parameters (pH, specific conductivity, etc.). There are hints for sampling without purging. To define the necessary extent of the purging repeated pumping is conducted, triplicate samples are taken at the beginning of purging, at one, two and three times well volumes and at parameter stabilization. Triplicate samples are the means to account for laboratory errors. The subsurface is not static, the test is repeated 10 times. Up to now three tests were completed.

  10. Data fusion modeling for groundwater systems

    Science.gov (United States)

    Porter, David W.; Gibbs, Bruce P.; Jones, Walter F.; Huyakorn, Peter S.; Hamm, L. Larry; Flach, Gregory P.

    2000-03-01

    Engineering projects involving hydrogeology are faced with uncertainties because the earth is heterogeneous, and typical data sets are fragmented and disparate. In theory, predictions provided by computer simulations using calibrated models constrained by geological boundaries provide answers to support management decisions, and geostatistical methods quantify safety margins. In practice, current methods are limited by the data types and models that can be included, computational demands, or simplifying assumptions. Data Fusion Modeling (DFM) removes many of the limitations and is capable of providing data integration and model calibration with quantified uncertainty for a variety of hydrological, geological, and geophysical data types and models. The benefits of DFM for waste management, water supply, and geotechnical applications are savings in time and cost through the ability to produce visual models that fill in missing data and predictive numerical models to aid management optimization. DFM has the ability to update field-scale models in real time using PC or workstation systems and is ideally suited for parallel processing implementation. DFM is a spatial state estimation and system identification methodology that uses three sources of information: measured data, physical laws, and statistical models for uncertainty in spatial heterogeneities. What is new in DFM is the solution of the causality problem in the data assimilation Kalman filter methods to achieve computational practicality. The Kalman filter is generalized by introducing information filter methods due to Bierman coupled with a Markov random field representation for spatial variation. A Bayesian penalty function is implemented with Gauss-Newton methods. This leads to a computational problem similar to numerical simulation of the partial differential equations (PDEs) of groundwater. In fact, extensions of PDE solver ideas to break down computations over space form the computational heart of DFM

  11. Budgets and chemical characterization of groundwater for the Diamond Valley flow system, central Nevada, 2011–12

    Science.gov (United States)

    Berger, David L.; Mayers, C. Justin; Garcia, C. Amanda; Buto, Susan G.; Huntington, Jena M.

    2016-07-29

    The Diamond Valley flow system consists of six hydraulically connected hydrographic areas in central Nevada. The general down-gradient order of the areas are southern and northern Monitor Valleys, Antelope Valley, Kobeh Valley, Stevens Basin, and Diamond Valley. Groundwater flow in the Diamond Valley flow system terminates at a large playa in the northern part of Diamond Valley. Concerns relating to continued water-resources development of the flow system resulted in a phased hydrologic investigation that began in 2005 by the U.S. Geological Survey in cooperation with Eureka County. This report presents the culmination of the phased investigation to increase understanding of the groundwater resources of the basin-fill aquifers in the Diamond Valley flow system through evaluations of groundwater chemistry and budgets. Groundwater chemistry was characterized using major ions and stable isotopes from groundwater and precipitation samples. Groundwater budgets accounted for all inflows, outflows, and changes in storage, and were developed for pre-development (pre-1950) and recent (average annual 2011–12) conditions. Major budget components include groundwater discharge by evapotranspiration and groundwater withdrawals; groundwater recharge by precipitation, and interbasin flow; and storage change.

  12. Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

    Science.gov (United States)

    Musgrove, MaryLynn; Beck, Jennifer A.; Paschke, Suzanne; Bauch, Nancy J.; Mashburn, Shana L.

    2014-01-01

    Groundwater resources from alluvial and bedrock aquifers of the Denver Basin are critical for municipal, domestic, and agricultural uses in Colorado along the eastern front of the Rocky Mountains. Rapid and widespread urban development, primarily along the western boundary of the Denver Basin, has approximately doubled the population since about 1970, and much of the population depends on groundwater for water supply. As part of the National Water-Quality Assessment Program, the U.S. Geological Survey conducted groundwater-quality studies during 2003–5 in the Denver Basin aquifer system to characterize water quality of shallow groundwater at the water table and of the bedrock aquifers, which are important drinking-water resources. For the Denver Basin, water-quality constituents of concern for human health or because they might otherwise limit use of water include total dissolved solids, fluoride, sulfate, nitrate, iron, manganese, selenium, radon, uranium, arsenic, pesticides, and volatile organic compounds. For the water-table studies, two monitoring-well networks were installed and sampled beneath agricultural (31 wells) and urban (29 wells) land uses at or just below the water table in either alluvial material or near-surface bedrock. For the bedrock-aquifer studies, domestic- and municipal-supply wells completed in the bedrock aquifers were sampled. The bedrock aquifers, stratigraphically from youngest (shallowest) to oldest (deepest), are the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers. The extensive dataset collected from wells completed in the bedrock aquifers (79 samples) provides the opportunity to evaluate factors and processes affecting water quality and to establish a baseline that can be used to characterize future changes in groundwater quality. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating constituents and tracers. This report discusses spatial and statistical distributions of chemical constituents

  13. Physicochemical Analysis of Selected Groundwater Samples of Amalner Town inJalgaon District, Maharashtra, India

    Directory of Open Access Journals (Sweden)

    V. T. Patil

    2010-01-01

    Full Text Available Physicochemical characteristics of groundwater and municipal water in Amalner town by taking water samples from five different stations. The study was carried out by collecting four groundwater samples (Two open well, two bore well and one municipal water sample during November 2007-February 2008. The results were compared with standards prescribed by WHO and ISI 10500-91. Total 15 parameters were analysed. It was found that the underground water was contaminated at few sampling sites namely Shirud Naka, Cotton Market and Shivaji Nagar. The sampling sites Dekhu road showed physicochemical parameters within the water quality standards and the quality of water is good and it is fit for drinking purpose. The correlation coefficients were calculated for water quality assessment.

  14. Assessment of groundwater quality using geographical information system (GIS), at north-east Cairo, Egypt.

    Science.gov (United States)

    El-Shahat, M F; Sadek, M A; Mostafa, W M; Hagagg, K H

    2016-04-01

    The present investigation has been conducted to delineate the hydrogeochemical and environmental factors that control the water quality of the groundwater resources in the north-east of Cairo. A complementary approach based on hydrogeochemistry and a geographical information system (GIS) based protectability index has been employed for conducting this work. The results from the chemical analysis revealed that the groundwater of the Quaternary aquifer is less saline than that of the Miocene aquifer and the main factors that control the groundwater salinity in the studied area are primarily related to the genesis of the original recharging water modified after by leaching, dissolution, cation exchange, and fertilizer leachate. The computed groundwater quality index (WQI) falls into two categories: fair for almost all the Miocene groundwater samples, while the Quaternary groundwater samples are all have a good quality. The retarded flow and non-replenishment of the Miocene aquifer compared to the renewable active recharge of the Quaternary aquifer can explain this variation of WQI. The index and overlay approach exemplified by the DUPIT index has been used to investigate the protectability of the study aquifers against diffuse pollutants. Three categories (highly protectable less vulnerable, moderately protectable moderately vulnerable and less protectable highly vulnerable) have been determined and areally mapped.

  15. Geochemical modeling of groundwater evolution in a volcanic aquifer system of Kumamoto area, Japan

    Science.gov (United States)

    Hossain, S.; Hosono, T.; Ide, K.; Shimada, J.

    2013-12-01

    Inverse geochemical modeling (PHREEQC) was used to identify the evolution of groundwater in a volcanic aquifer system of Kumamoto area (103 Km2) in southern Japan. The modeling was based on flow paths proposed by different researcher using different techniques, and detailed chemical analysis of groundwater along the flow paths. Potential phases were constrained using general trends in hydrochemical data of groundwater, mineralogical data, and saturation indices data of minerals in groundwater. Hydrochemical data from a total of 180 spring, river and well water samples were used to evaluate water quality and to determine processes that control groundwater chemistry. The samples from the area were classified as recharge zone water (Ca-HCO3 and Ca-SO4 type), lateral flow to discharge zone water (Ca-HCO3 and Na-HCO3 type) and stagnant zone water (Na-Cl type). The inverse geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. The downstream changes in groundwater chemistry could be largely explained by the weathering of plagioclase to kaolinite, with possible contributions from weathering of biotite and pyroxene. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into three categories (1) silicate weathering reactions (2) precipitation of amorphous silica and clay minerals and (3) Cation exchange reactions of Ca2+ to Na+.

  16. Data Validation Package May 2016 Groundwater Sampling at the Lakeview, Oregon, Processing Site August 2016

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Joshua [USDOE Office of Legacy Management, Washington, DC (United States); Hall, Steve [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-08-01

    This biennial event includes sampling five groundwater locations (four monitoring wells and one domestic well) at the Lakeview, Oregon, Processing Site. For this event, the domestic well (location 0543) could not be sampled because no one was in residence during the sampling event (Note: notification was provided to the resident prior to the event). Per Appendix A of the Groundwater Compliance Action Plan, sampling is conducted to monitor groundwater quality on a voluntary basis. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). One duplicate sample was collected from location 0505. Water levels were measured at each sampled monitoring well. The constituents monitored at the Lakeview site are manganese and sulfate. Monitoring locations that exceeded the U.S. Environmental Protection Agency (EPA) Secondary Maximum Contaminant Levels for these constituents are listed in Table 1. Review of time-concentration graphs included in this report indicate that manganese and sulfate concentrations are consistent with historical measurements.

  17. Results of groundwater monitoring and vegetation sampling at Everest, Kansas, in 2009 .

    Energy Technology Data Exchange (ETDEWEB)

    LaFreniere, L. M.; Environmental Science Division

    2010-05-13

    In April 2008, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) conducted groundwater sampling for the analysis of volatile organic compounds (VOCs) in the existing network of monitoring points at Everest, Kansas (Argonne 2008). The objective of the 2008 investigation was to monitor the distribution of carbon tetrachloride contamination in groundwater previously identified in CCC/USDA site characterization and groundwater sampling studies at Everest in 2000-2006 (Argonne 2001, 2003, 2006a,b). The work at Everest is being undertaken on behalf of the CCC/USDA by Argonne National Laboratory, under the oversight of the Kansas Department of Health and Environment (KDHE). The findings of the 2008 investigation were as follows: (1) Measurements of groundwater levels obtained manually and through the use of automatic recorders demonstrated a consistent pattern of groundwater flow - and inferred contaminant migration - to the north-northwest from the former CCC/USDA facility toward the Nigh property, and then west-southwest from the Nigh property toward the intermittent creek that lies west of the former CCC/USDA facility and the Nigh property. (2) The range of concentrations and the areal distribution of carbon tetrachloride identified in the groundwater at Everest in April 2008 were generally consistent with previous results. The results of the 2008 sampling (reflecting the period from 2006 to 2008) and the earlier investigations at Everest (representing the period from 2000 to 2006) show that no significant downgradient extension of the carbon tetrachloride plume occurred from 2000 to 2008. (3) The slow contaminant migration indicated by the monitoring data is qualitatively consistent with the low groundwater flow rates in the Everest aquifer unit estimated previously on the basis of site-specific hydraulic testing (Argonne 2006a,b). (4) The April 2008 and earlier sampling results demonstrate that the limits of the plume have been

  18. Hanford groundwater modeling: statistical methods for evaluating uncertainty and assessing sampling effectiveness

    Energy Technology Data Exchange (ETDEWEB)

    McLaughlin, D.B.

    1979-01-01

    This report is the first in a series of three documents which address the role of uncertainty in the Rockwell Hanford Operations groundwater model development and application program at Hanford Site. Groundwater data collection activities at Hanford are reviewed as they relate to Rockwell groundwater modeling. Methods of applying statistical and probability theory in quantifying the propagation of uncertainty from field measurements to model predictions are discussed. It is shown that measures of model accuracy or uncertainty provided by a statistical analysis can be useful in guiding model development and sampling network design. Recommendations are presented in the areas of model input data needs, parameter estimation data needs, and model verification and variance estimation data needs. 8 figures.

  19. Sampling system and method

    Science.gov (United States)

    Decker, David L.; Lyles, Brad F.; Purcell, Richard G.; Hershey, Ronald Lee

    2013-04-16

    The present disclosure provides an apparatus and method for coupling conduit segments together. A first pump obtains a sample and transmits it through a first conduit to a reservoir accessible by a second pump. The second pump further conducts the sample from the reservoir through a second conduit.

  20. Investigation of geochemical indicators to evaluate the connection between inland and coastal groundwater systems near Kaloko-Honokōhau National Historical Park, Hawai‘i

    Science.gov (United States)

    Tillman, Fred D; Oki, Delwyn S.; Johnson, Adam G.; Barber, Larry B.; Beisner, Kimberly R.

    2014-01-01

    Kaloko-Honokōhau National Historical Park (KAHO) is a coastal sanctuary on the western side of the Island of Hawai‘i that was established in 1978 to preserve, interpret, and perpetuate traditional Native Hawaiian culture and activities. KAHO contains a variety of culturally and ecologically significant water resources and water-related habitat for species that have been declared as threatened or endangered by the U.S. Fish and Wildlife Service, or are candidate threatened or endangered species. These habitats are dependent on coastal unconfined groundwater in a freshwater-lens system. The coastal unconfined-groundwater system is recharged by local infiltration of rainfall but also may receive recharge from an inland groundwater system containing groundwater impounded to high altitudes. The area inland of and near KAHO is being rapidly urbanized and increased groundwater withdrawals from the inland impounded-groundwater system may affect habitat and water quality in KAHO, depending on the extent of connection between the coastal unconfined groundwater and inland impounded-groundwater. An investigation of the geochemistry of surface-water and groundwater samples in and near KAHO was performed to evaluate the presence or absence of a connection between the inland impounded- and coastal unconfined-groundwater systems in the area. Analyses of major ions, selected trace elements, rare-earth elements, and strontium-isotope ratio results from ocean, fishpond, anchialine pool, and groundwater samples were consistent with a linear mixing process between the inland impounded and coastal unconfined-groundwater systems. Stable isotopes of water in many samples from the coastal unconfined-groundwater system require an aggregate recharge altitude that is substantially higher than the boundary between the coastal unconfined and inland impounded systems, a further indication of a hydrologic connection between the two systems. The stable isotope composition of the freshwater

  1. Data Validation Package, December 2015, Groundwater Sampling at the Bluewater, New Mexico, Disposal Site, September 2016

    Energy Technology Data Exchange (ETDEWEB)

    Tsosie, Bernadette [U. S. Department of Energy, Washington, DC (United States). Office of Legacy Management; Johnson, Richard [Navarro Research and Engineering, Oak Ridge, TN (United States)

    2016-09-01

    Groundwater samples were collected from monitoring wells at the Bluewater, New Mexico, Disposal Site to monitor groundwater contaminants as specified in the 1997 Long-Term Surveillance Plan for the DOE Bluewater (UMTRCA Title II) Disposal Site Near Grants, New Mexico (LTSP). Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location HMC-951. Alluvium wells are completed in the alluvial sediments in the former channel of the Rio San Jose, which was covered by basalt lava flows known as the El Malpais, and are identified by the suffix (M). Bedrock wells are completed in the San Andres Limestone/Glorieta Sandstone hydrologic unit (San Andres aquifer) and are identified by the suffix (SG). Wells HMC-951 and OBS-3 are also completed in the San Andres aquifer. The LTSP requires monitoring for molybdenum, selenium, uranium, and polychlorinated biphenyls (PCBs); PCB monitoring occurs only during November sampling events. This event included sampling for an expanded list of analytes to characterize the site aquifers and to support a regional groundwater investigation being conducted by the New Mexico Environment Department.

  2. Comparison of soil solution sampling techniques to assess metal fluxes from contaminated soil to groundwater.

    Science.gov (United States)

    Coutelot, F; Sappin-Didier, V; Keller, C; Atteia, O

    2014-12-01

    The unsaturated zone plays a major role in elemental fluxes in terrestrial ecosystems. A representative chemical analysis of soil pore water is required for the interpretation of soil chemical phenomena and particularly to assess Trace Elements (TEs) mobility. This requires an optimal sampling system to avoid modification of the extracted soil water chemistry and allow for an accurate estimation of solute fluxes. In this paper, the chemical composition of soil solutions sampled by Rhizon® samplers connected to a standard syringe was compared to two other types of suction probes (Rhizon® + vacuum tube and Rhizon® + diverted flow system). We investigated the effects of different vacuum application procedures on concentrations of spiked elements (Cr, As, Zn) mixed as powder into the first 20 cm of 100-cm columns and non-spiked elements (Ca, Na, Mg) concentrations in two types of columns (SiO2 sand and a mixture of kaolinite + SiO2 sand substrates). Rhizon® was installed at different depths. The metals concentrations showed that (i) in sand, peak concentrations cannot be correctly sampled, thus the flux cannot be estimated, and the errors can easily reach a factor 2; (ii) in sand + clay columns, peak concentrations were larger, indicating that they could be sampled but, due to sorption on clay, it was not possible to compare fluxes at different depths. The different samplers tested were not able to reflect the elemental flux to groundwater and, although the Rhizon® + syringe device was more accurate, the best solution remains to be the use of a lysimeter, whose bottom is kept continuously at a suction close to the one existing in the soil.

  3. Passive sampling as a tool for identifying micro-organic compounds in groundwater.

    Science.gov (United States)

    Mali, N; Cerar, S; Koroša, A; Auersperger, P

    2017-03-28

    The paper presents the use of a simple and cost efficient passive sampling device with integrated active carbon with which to test the possibility of determining the presence of micro-organic compounds (MOs) in groundwater and identifying the potential source of pollution as well as the seasonal variability of contamination. Advantage of the passive sampler is to cover a long sampling period by integrating the pollutant concentration over time, and the consequently analytical costs over the monitoring period can be reduced substantially. Passive samplers were installed in 15 boreholes in the Maribor City area in Slovenia, with two sampling campaigns covered a period about one year. At all sampling sites in the first series a total of 103 compounds were detected, and 144 in the second series. Of all detected compounds the 53 most frequently detected were selected for further analysis. These were classified into eight groups based on the type of their source: Pesticides, Halogenated solvents, Non-halogenated solvents, Domestic and personal, Plasticizers and additives, Other industrial, Sterols and Natural compounds. The most frequently detected MO compounds in groundwater were tetrachloroethene and trichloroethene from the Halogenated solvents group. The most frequently detected among the compound's groups were pesticides. Analysis of frequency also showed significant differences between the two sampling series, with less frequent detections in the summer series. For the analysis to determine the origin of contamination three groups of compounds were determined according to type of use: agriculture, urban and industry. Frequency of detection indicates mixed land use in the recharge areas of sampling sites, which makes it difficult to specify the dominant origin of the compound. Passive sampling has proved to be useful tool with which to identify MOs in groundwater and for assessing groundwater quality.

  4. Groundwater systems of the Indian Sub-Continent

    Directory of Open Access Journals (Sweden)

    Abhijit Mukherjee

    2015-09-01

    Full Text Available The Indian Sub-Continent is one of the most densely populated regions of the world, hosting ∼23% of the global population within only ∼3% of the world's land area. It encompasses some of the world's largest fluvial systems in the world (River Brahmaputra, Ganges and Indus Basins, which hosts some of the highest yielding aquifers in the world. The distribution of usable groundwater in the region varies considerably and the continued availability of safe water from many of these aquifers (e.g. Bengal Basin is constrained by the presence of natural contaminants. Further, the trans-boundary nature of the aquifers in the Indian Sub-Continent makes groundwater resource a potentially politically sensitive issue, particularly since this region is the largest user of groundwater resources in the world. Indeed, there is considerable concern regarding dwindling well yield and declining groundwater levels, even for the highly productive aquifers. Though irrigation already accounts for >85% of the total ground water extraction of the region, there is a mounting pressure on aquifers for food security of the region. Highly variable precipitation, hydrogeological conditions and predicted, impending climate change effects provide substantial challenges to groundwater management. The observed presence of natural groundwater contaminants together with the growing demand for irrigated food production and predicted climate change further complicate the development of strategies for using groundwater resources sustainably. We provide an introduction and overview of 11 articles, collated in this special issue, which describe the current condition of vulnerable groundwater resources across the Indian Sub-Continent.

  5. A decision analysis approach for optimal groundwater monitoring system design under uncertainty

    Directory of Open Access Journals (Sweden)

    N. B. Yenigül

    2006-01-01

    Full Text Available Groundwater contamination is the degradation of the natural quality of groundwater as a result of human activity. Landfills are one of the most common human activities threatening the groundwater quality. The objective of the monitoring systems is to detect the contaminant plumes before reaching the regulatory compliance boundary in order to prevent the severe risk to both society and groundwater quality, and also to enable cost-effective counter measures in case of a failure. The detection monitoring problem typically has a multi-objective nature. A multi-objective decision model (called MONIDAM which links a classic decision analysis approach with a stochastic simulation model is applied to determine the optimal groundwater monitoring system given uncertainties due to the hydrogeological conditions and contaminant source characteristics. A Monte Carlo approach is used to incorporate uncertainties. Hydraulic conductivity and the leak location are the random inputs of the simulation model. The design objectives considered in the model are: (1 maximizing the detection probability, (2 minimizing the contaminated area and, (3 minimize the total cost of the monitoring system. The results show that the monitoring systems located close to the source are optimal except for the cases with very high unit installation and sampling cost and/or very cheap unit remediation cost.

  6. Methods to characterize environmental settings of stream and groundwater sampling sites for National Water-Quality Assessment

    Science.gov (United States)

    Nakagaki, Naomi; Hitt, Kerie J.; Price, Curtis V.; Falcone, James A.

    2012-01-01

    Characterization of natural and anthropogenic features that define the environmental settings of sampling sites for streams and groundwater, including drainage basins and groundwater study areas, is an essential component of water-quality and ecological investigations being conducted as part of the U.S. Geological Survey's National Water-Quality Assessment program. Quantitative characterization of environmental settings, combined with physical, chemical, and biological data collected at sampling sites, contributes to understanding the status of, and influences on, water-quality and ecological conditions. To support studies for the National Water-Quality Assessment program, a geographic information system (GIS) was used to develop a standard set of methods to consistently characterize the sites, drainage basins, and groundwater study areas across the nation. This report describes three methods used for characterization-simple overlay, area-weighted areal interpolation, and land-cover-weighted areal interpolation-and their appropriate applications to geographic analyses that have different objectives and data constraints. In addition, this document records the GIS thematic datasets that are used for the Program's national design and data analyses.

  7. Sampling system and method

    Energy Technology Data Exchange (ETDEWEB)

    Decker, David L.; Lyles, Brad F.; Purcell, Richard G.; Hershey, Ronald Lee

    2017-03-07

    In one embodiment, the present disclosure provides an apparatus and method for supporting a tubing bundle during installation or removal. The apparatus includes a clamp for securing the tubing bundle to an external wireline. In various examples, the clamp is external to the tubing bundle or integral with the tubing bundle. According to one method, a tubing bundle and wireline are deployed together and the tubing bundle periodically secured to the wireline using a clamp. In another embodiment, the present disclosure provides an apparatus and method for coupling conduit segments together. A first pump obtains a sample and transmits it through a first conduit to a reservoir accessible by a second pump. The second pump further conducts the sample from the reservoir through a second conduit. In a specific example, one or more clamps are used to connect the first and/or second conduits to an external wireline.

  8. Data Validation Package, June 2016 Groundwater Sampling at the Hallam, Nebraska, Decommissioned Reactor Site, August 2016

    Energy Technology Data Exchange (ETDEWEB)

    Surovchak, Scott [USDOE Office of Legacy Management, Washington, DC (United States); Miller, Michele [Navarro Research and Engineering, Oak Ridge, TN (United States)

    2016-08-01

    The 2008 Long-Term Surveillance Plan [LTSP] for the Decommissioned Hallam Nuclear Power Facility, Hallam, Nebraska (http://www.lm.doe.gov/Hallam/Documents.aspx) requires groundwater monitoring once every 2 years. Seventeen monitoring wells at the Hallam site were sampled during this event as specified in the plan. Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. Water levels were measured at all sampled wells and at two additional wells (6A and 6B) prior to the start of sampling. Additionally, water levels of each sampled well were measured at the beginning of sampling. See Attachment 2, Trip Report, for additional details. Sampling and analysis were conducted as specified in Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and-analysis-plan-us-department- energy-office-legacy-management-sites). Gross alpha and gross beta are the only parameters that were detected at statistically significant concentrations. Time/concentration graphs of the gross alpha and gross beta data are included in Attachment 3, Data Presentation. The gross alpha and gross beta activity concentrations observed are consistent with values previously observed and are attributed to naturally occurring radionuclides (e.g., uranium and uranium decay chain products) in the groundwater.

  9. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2014

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2014 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring is performed by the GWPP during CY 2014 to achieve the following goals: 􀁸 to protect the worker, the public, and the environment; 􀁸 to maintain surveillance of existing and potential groundwater contamination sources; 􀁸 to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; 􀁸 to identify and characterize long-term trends in groundwater quality at Y-12; and 􀁸 to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12.

  10. Determination of Organic Pollutants in Small Samples of Groundwaters by Liquid-Liquid Extraction and Capillary Gas Chromatography

    DEFF Research Database (Denmark)

    Harrison, I.; Leader, R.U.; Higgo, J.J.W.

    1994-01-01

    A method is presented for the determination of 22 organic compounds in polluted groundwaters. The method includes liquid-liquid extraction of the base/neutral organics from small, alkaline groundwater samples, followed by derivatisation and liquid-liquid extraction of phenolic compounds after...

  11. Data Validation Package: April 2016 Groundwater Sampling at the Falls City, Texas, Disposal Site

    Energy Technology Data Exchange (ETDEWEB)

    Jasso, Tashina [USDOE Office of Legacy Management, Washington, DC (United States); Widdop, Michael [Navarro Research and Engineering, Inc., Las Vegas, NV (United States)

    2016-09-29

    Nine groundwater samples were collected at the Falls City, Texas, Disposal Site as specified in the March 2008 Long-Term Surveillance Plan for the US Department of Energy Falls City Uranium Mill Tailings Disposal Site, Falls City, Texas (DOE-LM/1602-2008). Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for US Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). The wells sampled included the cell performance monitoring wells (0709, 0858, 0880, 0906, and 0921) and the groundwater monitoring wells (0862, 0886, 0891, 0924, and 0963). A duplicate sample was collected from location 0891. Water levels were measured at each sampled well. Historically, cell performance monitoring wells 0908 and 0916 have not produced water and were confirmed as dry during this sampling event. These wells are completed above the saturated interval in the formation. Notable observations for time-concentration graphs in this report include: (1) uranium concentrations in well 0891 continue to increase; (2) the uranium concentration in well 0880 is higher than the 2015 value and lower than the 2014 value, and it remains within the range of historical values; and (3) uranium concentrations in the other sampled wells are below 2 mg/L and consistent with previous results.

  12. Passive sampling and analyses of common dissolved fixed gases in groundwater.

    Science.gov (United States)

    Spalding, Brian P; Watson, David B

    2008-05-15

    An in situ passive sampling and gas chromatographic protocol was developed for analysis of the major and several minor fixed gases (He, Ne, H2, N2, O2, CO, CH4, CO2, and N2O) in groundwater. Using argon carrier gas, a HayeSep DB porous polymer phase, and sequential thermal conductivity and reductive gas detectors, the protocol achieved sufficient separation and sensitivity to measure the mixing ratio of all these gases in a single 0.5 mL gas sample collected in situ, stored, transported, and injected using a gastight syringe. Within 4 days of immersion in groundwater, the simple passive in situ sampler, whether initially filled with He or air, attained an equivalent and constant mixing ratio for five of the seven detected gases. The abundant mixing ratio of N2O, averaging 2.6%, indicated that significant denitrification is likely ongoing within groundwater contaminated with uranium, acidity, nitrate, and organic carbon from a group of four closed radioactive wastewater seepage ponds at the Oak Ridge Field Research Center. Over 1000 passive gas samples from 12 monitoring wells averaged 56% CO2, 32.4% N2, 2.6% O2, 2.6% N2O, 0.21% CH4, 0.093% H2, and 0.025% CO with an average recovery of 95 +/- 14% of the injected gas volume.

  13. Sampling and characterisation of groundwater colloids in ONKALO at Olkiluoto, Finland, 2013

    Energy Technology Data Exchange (ETDEWEB)

    Luste, S.; Takala, M.; Manninen, P. [Ramboll Finland Oy, Espoo (Finland)

    2014-06-15

    The purpose of this study was to estimate the concentration of groundwater colloids and to compare the results with the previous ones. The water samples were collected from groundwater stations ONK-PVA1, ONK-PVA5 and ONK-PVA10 in August 2013. The colloid concentrations were determined from scanning electron microscopy (SEM) micrographs taken from the filters in which the groundwater was run through. The particle calculations were performed with computer software ImageJ 1.47. In addition, field flow fractionation (FFF) measurements were performed from the unfiltered water samples. The colloid concentration (diameter 0 - 1 μm) determined by the single particle analysis of SEM micrographs in ONK-PVA1 was 300 μg/l while the colloid concentration in ONK-PVA5 was 30 μg/l and ONK-PVA10 40 μg/l. FFF measurements supported the results of single particle analyses with a difference that an extra peak was found from ONK-PVA1 sample. The peak, which showed no evidence in single particle analyses, was suspected to contain humic substances. (orig.)

  14. Permafrost thaw in a nested groundwater-flow system

    Science.gov (United States)

    McKenzie, Jeffery M.; Voss, Clifford I.

    2013-01-01

    Groundwater flow in cold regions containing permafrost accelerates climate-warming-driven thaw and changes thaw patterns. Simulation analyses of groundwater flow and heat transport with freeze/thaw in typical cold-regions terrain with nested flow indicate that early thaw rate is particularly enhanced by flow, the time when adverse environmental impacts of climate-warming-induced permafrost loss may be severest. For the slowest climate-warming rate predicted by the Intergovernmental Panel on Climate Change (IPCC), once significant groundwater flow begins, thick permafrost layers can vanish in several hundred years, but survive over 1,000 years where flow is minimal. Large-scale thaw depends mostly on the balance of heat advection and conduction in the supra-permafrost zone. Surface-water bodies underlain by open taliks allow slow sub-permafrost flow, with lesser influence on regional thaw. Advection dominance over conduction depends on permeability and topography. Groundwater flow around permafrost and flow through permafrost impact thaw differently; the latter enhances early thaw rate. Air-temperature seasonality also increases early thaw. Hydrogeologic heterogeneity and topography strongly affect thaw rates/patterns. Permafrost controls the groundwater/surface-water-geomorphology system; hence, prediction and mitigation of impacts of thaw on ecology, chemical exports and infrastructure require improved hydrogeology/permafrost characterization and understanding

  15. Biogeochemical dynamics of pollutants in Insitu groundwater remediation systems

    Science.gov (United States)

    Kumar, N.; Millot, R.; Rose, J.; Négrel, P.; Battaglia-Brunnet, F.; Diels, L.

    2010-12-01

    Insitu (bio) remediation of groundwater contaminants has been area of potential research interest in last few decades as the nature of contaminant encountered has also changed drastically. This gives tough challenge to researchers in finding a common solution for all contaminants together in one plume. Redox processes play significant role in pollutant dynamics and mobility in such systems. Arsenic particularly in reduced environments can get transformed into its reduced form (As3+), which is apparently more mobile and highly toxic. Also parallel sulfate reduction can lead to sulfide production and formation of thioarsenic species. On the other hand heavy metals (Zn, Fe, and Cd) in similar conditions will favour more stable metal sulfide precipitation. In the present work, we tested Zero Valent Iron (ZVI) in handling such issues and found promising results. Although it has been well known for contaminants like arsenic and chlorinated compounds but not much explored for heavy metals. Its high available surface area supports precipitation and co -precipitation of contaminants and its highly oxidizing nature and water born hydrogen production helps in stimulation of microbial activities in sediment and groundwater. These sulfate and Iron reducing bacteria can further fix heavy metals as stable metal sulfides by using hydrogen as potential electron donor. In the present study flow through columns (biotic and control) were set up in laboratory to understand the behaviour of contaminants in subsurface environments, also the impact of microbiology on performance of ZVI was studied. These glass columns (30 x 4cm) with intermediate sampling points were monitored over constant temperature (20°C) and continuous groundwater (up)flow at ~1ml/hr throughout the experiment. Simulated groundwater was prepared in laboratory containing sulfate, metals (Zn,Cd) and arsenic (AsV). While chemical and microbial parameters were followed regularly over time, solid phase has been

  16. Ecohydrological Investigations of a Groundwater-Lake System

    DEFF Research Database (Denmark)

    Frandsen, Mette Cristine Schou

    I). •Does dense bottom vegetation affect the small scale hydrology of the lake bed sediment? (Paper 2). •How can natural tracers (δ 18O) be used to quantify the temporal variation in groundwater seepage dynamics? (Paper 3). •Is it possible to combine ecological data of surface water chemistry...... and data on groundwater chemistry to stoichiometrically describe changes in the lake in a historical time frame? (Paper 4). he main conclusions from the study are: •When evaluating the ecology of a groundwater-lake system, both hydrological and biological parameters are needed to accurately describe...... by this. The reasons for the lowered hydraulic conductivity seems to be an combination of the organic content in the sediment (i.e. the roots of the plants) and a vegetation induced entrapment of fine particles in the sediment. Over the course of three years I followed the small scale variation...

  17. Assessment of On-site sanitation system on local groundwater regime in an alluvial aquifer

    Science.gov (United States)

    Quamar, Rafat; Jangam, C.; Veligeti, J.; Chintalapudi, P.; Janipella, R.

    2017-06-01

    The present study is an attempt to study the impact of the On-site sanitation system on the groundwater sources in its vicinity. The study has been undertaken in the Agra city of Yamuna sub-basin. In this context, sampling sites (3 nos) namely Pandav Nagar, Ayodhya Kunj and Laxmi Nagar were selected for sampling. The groundwater samples were analyzed for major cations, anions and faecal coliform. Critical parameters namely chloride, nitrate and Faecal coliform were considered to assess the impact of the On-site sanitation systems. The analytical results shown that except for chloride, most of the samples exceeded the Bureau of Indian Standard limits for drinking water for all the other analyzed parameters, i.e., nitrate and faecal coliform in the first two sites. In Laxmi Nagar, except for faecal coliform, all the samples are below the BIS limits. In all the three sites, faecal coliform was found in majority of the samples. A comparison of present study indicates that the contamination of groundwater in alluvial setting is less as compared to hard rock where On-site sanitation systems have been implemented.

  18. [Groundwater].

    Science.gov (United States)

    González De Posada, Francisco

    2012-01-01

    From the perspective of Hydrogeology, the concept and an introductory general typology of groundwater are established. From the perspective of Geotechnical Engineering works, the physical and mathematical equations of the hydraulics of permeable materials, which are implemented, by electric analogical simulation, to two unique cases of global importance, are considered: the bailing during the construction of the dry dock of the "new shipyard of the Bahia de Cádiz" and the waterproofing of the "Hatillo dam" in the Dominican Republic. From a physical fundamental perspective, the theories which are the subset of "analogical physical theories of Fourier type transport" are related, among which the one constituted by the laws of Adolf Fick in physiology occupies a historic role of some relevance. And finally, as a philosophical abstraction of so much useful mathematical process, the one which is called "the Galilean principle of the mathematical design of the Nature" is dealt with.

  19. Groundwater vulnerability mapping in Guadalajara aquifers system (Western Mexico)

    Science.gov (United States)

    Rizo-Decelis, L. David; Marín, Ana I.; Andreo, Bartolomé

    2016-04-01

    Groundwater vulnerability mapping is a practical tool to implement strategies for land-use planning and sustainable socioeconomic development coherent with groundwater protection. The objective of vulnerability mapping is to identify the most vulnerable zones of catchment areas and to provide criteria for protecting the groundwater used for drinking water supply. The delineation of protection zones in fractured aquifers is a challenging task due to the heterogeneity and anisotropy of hydraulic conductivities, which makes difficult prediction of groundwater flow organization and flow velocities. Different methods of intrinsic groundwater vulnerability mapping were applied in the Atemajac-Toluquilla groundwater body, an aquifers system that covers around 1300 km2. The aquifer supplies the 30% of urban water resources of the metropolitan area of Guadalajara (Mexico), where over 4.6 million people reside. Study area is located in a complex neotectonic active volcanic region in the Santiago River Basin (Western Mexico), which influences the aquifer system underneath the city. Previous works have defined the flow dynamics and identified the origin of recharge. In addition, the mixture of fresh groundwater with hydrothermal and polluted waters have been estimated. Two main aquifers compose the multilayer system. The upper aquifer is unconfined and consists of sediments and pyroclastic materials. Recharge of this aquifer comes from rainwater and ascending vertical fluids from the lower aquifer. The lower aquifer consists of fractured basalts of Pliocene age. Formerly, the main water source has been the upper unit, which is a porous and unconsolidated unit, which acts as a semi-isotropic aquifer. Intense groundwater usage has resulted in lowering the water table in the upper aquifer. Therefore, the current groundwater extraction is carried out from the deeper aquifer and underlying bedrock units, where fracture flow predominates. Pollution indicators have been reported in

  20. Environmental forensics in groundwater coupling passive sampling and high resolution mass spectrometry for screening.

    Science.gov (United States)

    Soulier, Coralie; Coureau, Charlotte; Togola, Anne

    2016-09-01

    One of the difficulties encountered when monitoring groundwater quality is low and fluctuating concentration levels and complex mixtures of micropollutants, including emerging substances or transformation products. Combining passive sampling techniques with analysis by high resolution mass spectrometry (HRMS) should improve environmental metrology. Passive samplers accumulate compounds during exposure, which improves the detection of organic compounds and integrates pollution fluctuations. The Polar Organic Chemical Integrative Sampler (POCIS) were used in this study to sequester polar to semi-polar compounds. The methodology described here improves our knowledge of environmental pollution by highlighting and identifying pertinent compounds to be monitored in groundwater. The advantage of combining these two approaches is demonstrated on two different sites impacted by agricultural and/or urban pollution sources where groundwater was sampled for several months. Grab and passive sampling were done and analyzed by liquid chromatography coupled to a hybrid quadrupole time-of-flight mass spectrometer (LC-QTOF). Various data processing approaches were used (target, suspect and non-target screening). Target screening was based on research from compounds listed in a homemade database and suspect screening used a database compiled using literature data. The non-target screening was done using statistical tools such as principal components analysis (PCA) with direct connections between original chromatograms and ion intensity. Trend plots were used to highlight relevant compounds for their identification. The advantage of using POCIS to improve screening of polar organic compounds was demonstrated. Compounds undetected in water samples were detected with these tools. The subsequent data processing identified sentinel molecules, molecular clusters as compounds never revealed in these sampling sites, and molecular fingerprints. Samples were compared and multidimensional

  1. Strontium isotope geochemistry of groundwater affected by human activities in Nandong underground river system, China

    Energy Technology Data Exchange (ETDEWEB)

    Jiang Yongjun, E-mail: jiangjyj@swu.edu.cn [School of Geographical Sciences, Southwest University, Chongqing 400715 (China)] [Institute of Karst Environment and Rock Desertification Rehabilitation, Chongqing 400715 (China)

    2011-03-15

    Research highlights: {yields} Spatio-temporal variations of Sr concentrations and Sr isotopic composition of groundwater were investigated in a karst underground river system. {yields} Agricultural fertilizers and sewage effluents significantly modified the natural Sr isotopic signature of karst groundwater. {yields} Sr in the carbonate aquifers was relatively non-radiogenic, with low Sr concentrations, while anthropogenic Sr correlated with agricultural fertilizers and sewage effluents was relatively radiogenic, with higher Sr concentrations. {yields} {sup 87}Sr/{sup 86}Sr ratios can provide key information for natural and anthropogenic sources in karst groundwater. - Abstract: The Nandong Underground River System (NURS) is located in a typical karst area dominated by agriculture in SE Yunnan Province, China. Groundwater plays an important role in the social and economical development in the area. The effects of human activities (agriculture and sewage effluents) on the Sr isotope geochemistry were investigated in the NURS. Seventy-two representative groundwater samples, which were collected from different aquifers (calcite and dolomite), under varying land-use types, both in summer and winter, showed significant spatial differences and slight seasonal variations in Sr concentrations and {sup 87}Sr/{sup 86}Sr ratios. Agricultural fertilizers and sewage effluents significantly modified the natural {sup 87}Sr/{sup 86}Sr ratios signature of groundwater that was otherwise dominated by water-rock interaction. Three major sources of Sr could be distinguished by {sup 87}Sr/{sup 86}Sr ratios and Sr concentrations in karst groundwater. Two sources of Sr are the Triassic calcite and dolomite aquifers, where waters have low Sr concentrations (0.1-0.2 mg/L) and low {sup 87}Sr/{sup 86}Sr ratios (0.7075-0.7080 and 0.7080-0.7100, respectively); the third source is anthropogenic Sr from agricultural fertilizers and sewage effluents with waters affected having radiogenic {sup 87

  2. An experiment in representative ground-water sampling for water- quality analysis

    Science.gov (United States)

    Huntzinger, T.L.; Stullken, L.E.

    1988-01-01

    Obtaining a sample of groundwater that accurately represents the concentration of a chemical constituent in an aquifer is an important aspect of groundwater-quality studies. Varying aquifer and constituent properties may cause chemical constituents to move within selectively separate parts of the aquifer. An experiment was conducted in an agricultural region in south-central Kansas to address questions related to representative sample collection. Concentrations of selected constituents in samples taken from observation wells completed in the upper part of the aquifer were compared to concentrations in samples taken from irrigation wells to determine if there was a significant difference. Water in all wells sampled was a calcium bicarbonate type with more than 200 mg/L hardness and about 200 mg/L alkalinity. Sodium concentrations were also quite large (about 40 mg/L). There was a significant difference in the nitrite-plus-nitrate concentrations between samples from observation and irrigation wells. The median concentration of nitrite plus nitrate in water from observation wells was 5.7 mg/L compared to 3.4 mg/L in water from irrigation wells. The differences in concentrations of calcium, magnesium, and sodium (larger in water from irrigation wells) were significant at the 78% confidence level but not at the 97% confidence level. Concentrations of the herbicide, atrazine, were less than the detection limit of 0.1 micrograms/L in all but one well. (USGS)

  3. Data Validation Package - June 2015 Groundwater and Surface Water Sampling at the Green River, Utah, Disposal Site

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Joshua [USDOE Office of Legacy Management, Washington, DC (United States); Price, Jeffrey [Navarro Research and Engineering, Inc., Las Vegas, NV (United States)

    2015-08-01

    Groundwater samples were collected during the 2015 sampling event from point-of-compliance (POC) wells 0171, 0173, 0176, 0179, 0181, and 0813 to monitor the disposition of contaminants in the middle sandstone unit of the Cedar Mountain Formation. Groundwater samples also were collected from alluvium monitoring wells 0188, 0189, 0192, 0194, and 0707, and basal sandstone monitoring wells 0182, 0184, 0185, and 0588 as a best management practice. Surface locations 0846 and 0847 were sampled to monitor for degradation of water quality in the backwater area of Brown’s Wash and in the Green River immediately downstream of Brown’s Wash. The Green River location 0801 is upstream from the site and is sampled to determine background-threshold values (BTVs). Sampling and analyses were conducted as specified in Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and- analysis-plan-us-department-energy-office-legacy-management-sites). Water levels were measured at each sampled well. The analytical data and associated qualifiers can be viewed in environmental database reports and are also available for viewing with dynamic mapping via the GEMS (Geospatial Environmental Mapping System) website at http://gems.lm.doe.gov/#. All six POC wells are completed in the middle sandstone unit of the Cedar Mountain Formation and are monitored to measure contaminant concentrations for comparison to proposed alternate concentration limits (ACLs), as provided in Table 1. Contaminant concentrations in the POC wells remain below their respective ACLs.

  4. Geographical Information System Techniques for Evaluation of Groundwater Quality

    Directory of Open Access Journals (Sweden)

    Shahram Ashraf

    2011-01-01

    Full Text Available Problem statement: The present paper tries to assess groundwater suitability for irrigation purpose in Damghan plain (5400 ha. Approach: Twenty four water samples were collected from the active wells. Parameters such as Electrical Conductivity (EC, pH, Total Dissolved Solids (TDS, were recorded in the field and major anions and cations (Ca2+, Mg2+, K+, Na+, CO32-, HCO3-, Cl-, SO42- and NO3- were analyzed in the laboratory. The data of water wells were imported into the GIS software and the different water quality maps were produced using point data. Then Suitability index of groundwater quality determined by overlaying of water quality maps. Results: Suitability index values revealed that the ground water in Amin Abad, Abdi, Abd Abad, Nasr Abad and parts of Shams Abad villages of study area had "Suitable" quality with the suitability index range between 75-100 and therefore can be used for irrigation usage. Suitability index of the groundwater in Hasnie, Gani Abad and parts of Shams Abad villages were "Moderate" quality with the range between 35-70 and Abas Abad, Abir Abad and Shaman villages had "unsuitable" quality and cannot be used for irrigation purposes. In respect of all evaluating criteria, villages of study areas that had "Suitable" and Moderate quality could safely be used for longterm irrigation purposes. Conclusion: The present study demonstrated high efficiency for GIS to analyze complex spatial data and groundwater quality suitability.

  5. Numerical simulation of groundwater flow in the Columbia Plateau Regional Aquifer System, Idaho, Oregon, and Washington

    Science.gov (United States)

    Ely, D. Matthew; Burns, Erick R.; Morgan, David S.; Vaccaro, John J.

    2014-01-01

    A three-dimensional numerical model of groundwater flow was constructed for the Columbia Plateau Regional Aquifer System (CPRAS), Idaho, Oregon, and Washington, to evaluate and test the conceptual model of the system and to evaluate groundwater availability. The model described in this report can be used as a tool by water-resource managers and other stakeholders to quantitatively evaluate proposed alternative management strategies and assess the long‑term availability of groundwater. The numerical simulation of groundwater flow in the CPRAS was completed with support from the Groundwater Resources Program of the U.S. Geological Survey Office of Groundwater.

  6. Wells provide a distorted view of life in the aquifer: implications for sampling, monitoring and assessment of groundwater ecosystems

    Science.gov (United States)

    Korbel, Kathryn; Chariton, Anthony; Stephenson, Sarah; Greenfield, Paul; Hose, Grant C.

    2017-01-01

    When compared to surface ecosystems, groundwater sampling has unique constraints, including limited access to ecosystems through wells. In order to monitor groundwater, a detailed understanding of groundwater biota and what biological sampling of wells truly reflects, is paramount. This study aims to address this uncertainty, comparing the composition of biota in groundwater wells prior to and after purging, with samples collected prior to purging reflecting a potentially artificial environment and samples collected after purging representing the surrounding aquifer. This study uses DNA community profiling (metabarcoding) of 16S rDNA and 18S rDNA, combined with traditional stygofauna sampling methods, to characterise groundwater biota from four catchments within eastern Australia. Aquifer waters were dominated by Archaea and bacteria (e.g. Nitrosopumilales) that are often associated with nitrification processes, and contained a greater proportion of bacteria (e.g. Anaerolineales) associated with fermenting processes compared to well waters. In contrast, unpurged wells contained greater proportions of pathogenic bacteria and bacteria often associated with denitrification processes. In terms of eukaryotes, the abundances of copepods, syncarids and oligochaetes and total abundances of stygofauna were greater in wells than aquifers. These findings highlight the need to consider sampling requirements when completing groundwater ecology surveys. PMID:28102290

  7. Data Validation Package May 2016 Groundwater Sampling at the Sherwood, Washington, Disposal Site August 2016

    Energy Technology Data Exchange (ETDEWEB)

    Kreie, Ken [USDOE Office of Legacy Management, Washington, DC (United States); Traub, David [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-08-04

    The 2001 Long-Term Surveillance Plan (LTSP) for the US. Department of Energy Sherwood Project (UMI'RCA Title II) Reclamation Cell, Wellpinit, Washington, does not require groundwater compliance monitoring at the Sherwood site. However, the LTSP stipulates limited groundwater monitoring for chloride and sulfate (designated indicator parameters) and total dissolved solids (TDS) as a best management practice. Samples were collected from the background well, MW-2B, and the two downgradient wells, MW-4 and MW-10, in accordance with the LTSP. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for US. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). Water levels were measured in all wells prior to sampling and in four piezometers completed in the tailings dam. Time-concentration graphs included in this report indicate that the chloride, sulfate, and TDS concentrations are consistent with historical measurements. The concentrations of chloride and sulfate are well below the State of Washington water quality criteria value of 250 milligrams per liter (mg/L) for both parameters.

  8. Distributed parallel computing in stochastic modeling of groundwater systems.

    Science.gov (United States)

    Dong, Yanhui; Li, Guomin; Xu, Haizhen

    2013-03-01

    Stochastic modeling is a rapidly evolving, popular approach to the study of the uncertainty and heterogeneity of groundwater systems. However, the use of Monte Carlo-type simulations to solve practical groundwater problems often encounters computational bottlenecks that hinder the acquisition of meaningful results. To improve the computational efficiency, a system that combines stochastic model generation with MODFLOW-related programs and distributed parallel processing is investigated. The distributed computing framework, called the Java Parallel Processing Framework, is integrated into the system to allow the batch processing of stochastic models in distributed and parallel systems. As an example, the system is applied to the stochastic delineation of well capture zones in the Pinggu Basin in Beijing. Through the use of 50 processing threads on a cluster with 10 multicore nodes, the execution times of 500 realizations are reduced to 3% compared with those of a serial execution. Through this application, the system demonstrates its potential in solving difficult computational problems in practical stochastic modeling. © 2012, The Author(s). Groundwater © 2012, National Ground Water Association.

  9. Molecular analysis of microbial community in a groundwater sample polluted by landfill leachate and seawater

    Institute of Scientific and Technical Information of China (English)

    TIAN Yang-jie; YANG Hong; WU Xiu-juan; LI Dao-tang

    2005-01-01

    Seashore landfill aquifers are environments of special physicochemical conditions (high organic load and high salinity), and microbes in leachate-polluted aquifers play a significant role for intrinsic bioremediation. In order to characterize microbial diversity and look for clues on the relationship between microbial community structure and hydrochemistry, a culture-independent examination of a typical groundwater sample obtained from a seashore landfill was conducted by sequence analysis of 16S rDNA clone library. Two sets of universal 16S rDNA primers were used to amplify DNA extracted from the groundwater so that problems arising from primer efficiency and specificity could be reduced. Of 74 clones randomly selected from the libraries, 30 contained unique sequences whose analysis showed that the majority of them belonged to bacteria (95.9%), with Proteobacteria (63.5%) being the dominant division. One archaeal sequence and one eukaryotic sequence were found as well. Bacterial sequences belonging to the following phylogenic groups were identified: Bacteroidetes (20.3%), β, γ, δ and ε-subdivisions of Proteobacteria (47.3%, 9.5%, 5.4% and 1.3%, respectively), Firmicutes (1.4%), Actinobacteria (2.7%), Cyanobacteria (2.7%). The percentages of Proteobacteria and Bacteroides in seawater were greater than those in the groundwater from a non-seashore landfill, indicating a possible influence of seawater. Quite a few sequences had close relatives in marine or hypersaline environments. Many sequences showed affiliations with microbes involved in anaerobic fermentation. The remarkable abundance of sequences related to (per)chlorate-reducing bacteria (C1RB) in the groundwater was significant and worthy of further study.

  10. Subregions of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the subregions of the transient ground-water flow model of the Death Valley regional ground-water flow system (DVRFS). Subregions are...

  11. Environmental impacts of open loop geothermal system on groundwater

    Science.gov (United States)

    Kwon, Koo-Sang; Park, Youngyun; Yun, Sang Woong; Lee, Jin-Yong

    2013-04-01

    Application of renewable energies such as sunlight, wind, rain, tides, waves and geothermal heat has gradually increased to reduce emission of CO2 which is supplied from combustion of fossil fuel. The geothermal energy of various renewable energies has benefit to be used to cooling and heating systems and has good energy efficiency compared with other renewable energies. However, open loop system of geothermal heat pump system has possibility that various environmental problems are induced because the system directly uses groundwater to exchange heat. This study was performed to collect data from many documents such as papers and reports and to summarize environmental impacts for application of open loop system. The environmental impacts are classified into change of hydrogeological factors such as water temperature, redox condition, EC, change of microbial species, well contamination and depletion of groundwater. The change of hydrogeological factors can induce new geological processes such as dissolution and precipitation of some minerals. For examples, increase of water temperature can change pH and Eh. These variations can change saturation index of some minerals. Therefore, dissolution and precipitation of some minerals such as quartz and carbonate species and compounds including Fe and Mn can induce a collapse and a clogging of well. The well contamination and depletion of groundwater can reduce available groundwater resources. These environmental impacts will be different in each region because hydrogeological properties and scale, operation period and kind of the system. Therefore, appropriate responses will be considered for each environmental impact. Also, sufficient study will be conducted to reduce the environmental impacts and to improve geothermal energy efficiency during the period that a open loop system is operated. This work was supported by the Energy Efficiency and Resources of the Korea Institute of Energy Technology Evaluation and Planning

  12. Data Validation Package - June 2016 Groundwater and Surface Water Sampling at the Green River, Utah, Disposal Site

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Joshua [USDOE Office of Legacy Management, Washington, DC (United States); Price, Jeffrey [Navarro Research and Engineering, Inc., Las Vegas, NV (United States)

    2016-10-10

    This event included annual sampling of groundwater and surface water locations at the Green River, Utah, Disposal Site. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for US. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lrnldownloads/sampling-and- analysis-plan-us-department-energy-office-legacy-management-sites). Samples were collected from 15 monitoring wells and two surface locations at the disposal site as specified in the draft 2011 Ground Water Compliance Action Plan for the Green River, Utah, Disposal Site. Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. A duplicate sample was collected from location 0179. One equipment blank was collected during this sampling event. Water levels were measured at all monitoring wells that were sampled. See Attachment 2, Trip Reports for additional details. The analytical data and associated qualifiers can be viewed in environmental database reports and are also available for viewing with dynamic mapping via the GEMS (Geospatial Environmental Mapping System) website at http://gems.lm.doe.gov/#. No issues were identified during the data validation process that requires additional action or follow-up.

  13. Death Valley regional groundwater flow system, Nevada and California-Hydrogeologic framework and transient groundwater flow model

    Science.gov (United States)

    : Belcher, Wayne R.; Sweetkind, Donald S.

    2010-01-01

    A numerical three-dimensional (3D) transient groundwater flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the groundwater flow system and previous less extensive groundwater flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect groundwater flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley regional groundwater flow system (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the groundwater flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural groundwater discharge occurring through evapotranspiration (ET) and spring flow; the history of groundwater pumping from 1913 through 1998; groundwater recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were provided

  14. Investigations of groundwater system and simulation of regional groundwater flow for North Penn Area 7 Superfund site, Montgomery County, Pennsylvania

    Science.gov (United States)

    Senior, Lisa A.; Goode, Daniel J.

    2013-01-01

    by USGS at the site and results from other studies support, and are consistent with, a conceptual model of a layered leaky aquifer where the dip of the beds has a strong control on hydraulic connections in the groundwater system. Connections within and (or) parallel to bedding tend to be greater than across bedding. Transmissivities of aquifer intervals isolated by packers ranged over three orders of magnitude [from about 2.8 to 2,290 square feet per day (ft2/d) or 0.26 to 213 square meters per day (m2/d)], did not appear to differ much by mapped geologic unit, but showed some relation to depth being relatively smaller in the shallowest and deepest intervals (0 to 50 ft and more than 250 ft below land surface, respectively) compared to the intermediate depth intervals (50 to 250 ft below land surface) tested. Transmissivities estimated from multiple-observation well aquifer tests ranged from about 700 to 2,300 ft2/d (65 to 214 m2/d). Results of chemical analyses of water from isolated intervals or monitoring wells open to short sections of the aquifer show vertical differences in concentrations; chloride and silica concentrations generally were greater in shallow intervals than in deeper intervals. Chloride concentrations greater than 100 milligrams per liter (mg/L), combined with distinctive chloride/bromide ratios, indicate a different source of chloride in the western part of North Penn Area 7 than elsewhere in the site. Groundwater flow at a regional scale under steady-state conditions was simulated by use of a numerical model (MODFLOW-2000) for North Penn Area 7 with different layers representing saprolite/highly weathered rock near the surface and unweathered competent bedrock. The sedimentary formations that underlie the study area were modeled using dipping model layers for intermediate and deep zones of unweathered, fractured rock. Horizontal cell model size was 100 meters (m) by 100 meters (328 ft by 328 ft), and model layer thickness ranged from 6 m (19

  15. Evaluation of Background Mercury Concentrations in the SRS Groundwater System

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B.B.

    1999-03-03

    Mercury analyses associated with the A-01 Outfall have highlighted the importance of developing an understanding of mercury in the Savannah River Site groundwater system and associated surface water streams. This activity is critical based upon the fact that the EPA Ambient Water Quality Criteria (AWQC) for this constituent is 0.012mg/L, a level that is well below conventional detection limits of 0.1 to 0.2 mg/L. A first step in this process is obtained by utilizing the existing investment in groundwater mercury concentrations (20,242 records) maintained in the SRS geographical information management system (GIMS) database. Careful use of these data provides a technically defensible initial estimate for total recoverable mercury in background and contaminated SRS wells.

  16. The Influence of Pumping on Observed Bacterial Counts in Groundwater Samples: Implications for Sampling Protocol and Water Quality Interpretation

    Science.gov (United States)

    Kozuskanich, J.; Novakowski, K.; Anderson, B.

    2008-12-01

    Drinking water quality has become an important issue in Ontario following the events in Walkerton in 2000. Many rural communities are reliant on private groundwater wells for drinking water, and it is the responsibility of the owner to have the water tested to make sure it is safe for human consumption. Homeowners can usually take a sample to the local health unit for total coliform and E. Coli analysis at no charge to determine if the water supply is being tainted by surface water or fecal matter, both of which could indicate the potential for negative impacts on human health. However, is the sample coming out of the tap representative of what is going on the aquifer? The goal of this study is to observe how bacterial counts may vary during the course of well pumping, and how those changing results influence the assessment of water quality. Multiple tests were conducted in bedrock monitoring wells to examine the influence of pumping rate and pumped volume on observed counts of total coliform, E. Coli, fecal streptococcus, fecal coliform and heterotrophic plate count. Bacterial samples were collected frequently during the course of continuous purging events lasting up to 8 hours. Typical field parameters (temperature, salinity, pH, dissolved oxygen and ORP) were also continuously monitored during the course of each test. Common practice in groundwater studies is to wait until these parameters have stabilized or three well volumes have been removed prior to sampling, to ensure the sample is taken from new water entering the well from the aquifer, rather than the original water stored in the borehole prior to the test. In general, most bacterial counts were low, but did go above the drinking water standard of 0 counts/100mL (total coliform and E. Coli) at times during the tests. Results show the greatest variability in the observed bacterial counts at the onset of pumping prior to the removal of three well volumes. Samples taken after the removal of three well

  17. Physico-Chemical Analysis of Selected Groundwater Samples of Inkollu Mandal, Prakasam District, Andhra Pradesh, India

    Directory of Open Access Journals (Sweden)

    G. Arun Kumar

    2015-04-01

    Full Text Available Physico-chemical parameters of groundwater quality based on Physic-chemical parameters at Inkollu mandal, Prakasam district, Andhra Pradesh, India have been taken up to evaluate its suitability for Drinking purpose. Nine ground water samples were collected from different places of Inkollu mandal of Prakasam district. The quality analysis has been made through the pH, EC, TDS, Total Hardness, Sodium, Potassium, Calcium, Magnesium, Chloride, Sulphate, Nitrate, Fluoride and Iron. By observing the results, it was shown that the parameters from the water samples were compared with WHO (World Health Organization and BIS (Bureau of Indian Standards, USPH (United state Public health for ground water .The results revealed that some parameters were in high concentration and quality of the potable water has deteriorated to a large extent at some sampling locations.

  18. Effective groundwater modeling of the data-poor Nubian Aquifer System (Chad, Egypt, Libya, Sudan) - use of parsimony and 81Kr-based groundwater ages (Invited)

    Science.gov (United States)

    Voss, C. I.; Soliman, S. M.; Aggarwal, P. K.

    2013-12-01

    Important information for management of large aquifer systems can be obtained via a parsimonious approach to groundwater modeling, in part, employing isotope-interpreted groundwater ages. ';Parsimonious' modeling implies active avoidance of overly-complex representations when constructing models. This approach is essential for evaluation of aquifer systems that lack informative hydrogeologic databases. Even in the most remote aquifers, despite lack of typical data, groundwater ages can be interpreted from isotope samples at only a few downstream locations. These samples incorporate hydrogeologic information from the entire upstream groundwater flowpath; thus, interpreted ages are among the most-effective information sources for groundwater model development. This approach is applied to the world's largest non-renewable aquifer, the transboundary Nubian Aquifer System (NAS) of Chad, Egypt, Libya and Sudan. In the NAS countries, water availability is a critical problem and NAS can reliably serve as a water supply for an extended future period. However, there are national concerns about transboundary impacts of water use by neighbors. These concerns include excessive depletion of shared groundwater by individual countries and the spread of water-table drawdown across borders, where neighboring country near-border shallow wells and oases may dry. Development of a parsimonious groundwater flow model, based on limited available NAS hydrogeologic data and on 81Kr groundwater ages below oases in Egypt, is a key step in providing a technical basis for international discussion concerning management of this non-renewable water resource. Simply-structured model analyses, undertaken as part of an IAEA/UNDP/GEF project, show that although the main transboundary issue is indeed drawdown crossing national boundaries, given the large scale of NAS and its plausible ranges of aquifer parameter values, the magnitude of transboundary drawdown will likely be small and may not be a

  19. Death Valley regional ground-water flow system, Nevada and California -- hydrogeologic framework and transient ground-water flow model

    Science.gov (United States)

    : Belcher, Wayne R.

    2004-01-01

    A numerical three-dimensional (3D) transient ground-water flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the ground-water flow system and previous less extensive ground-water flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect ground-water flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley Regional Ground-Water Flow System (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the ground-water flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural ground-water discharge occurring through evapotranspiration and spring flow; the history of ground-water pumping from 1913 through 1998; ground-water recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were

  20. Conjunctive management of multi-reservoir network system and groundwater system

    Science.gov (United States)

    Mani, A.; Tsai, F. T. C.

    2015-12-01

    This study develops a successive mixed-integer linear fractional programming (successive MILFP) method to conjunctively manage water resources provided by a multi-reservoir network system and a groundwater system. The conjunctive management objectives are to maximize groundwater withdrawals and maximize reservoir storages while satisfying water demands and raising groundwater level to a target level. The decision variables in the management problem are reservoir releases and spills, network flows and groundwater pumping rates. Using the fractional programming approach, the objective function is defined as a ratio of total groundwater withdraws to total reservoir storage deficits from the maximum storages. Maximizing this ratio function tends to maximizing groundwater use and minimizing surface water use. This study introduces a conditional constraint on groundwater head in order to sustain aquifers from overpumping: if current groundwater level is less than a target level, groundwater head at the next time period has to be raised; otherwise, it is allowed to decrease up to a certain extent. This conditional constraint is formulated into a set of mixed binary nonlinear constraints and results in a mixed-integer nonlinear fractional programming (MINLFP) problem. To solve the MINLFP problem, we first use the response matrix approach to linearize groundwater head with respect to pumping rate and reduce the problem to an MILFP problem. Using the Charnes-Cooper transformation, the MILFP is transformed to an equivalent mixed-integer linear programming (MILP). The solution of the MILP is successively updated by updating the response matrix in every iteration. The study uses IBM CPLEX to solve the MILP problem. The methodology is applied to water resources management in northern Louisiana. This conjunctive management approach aims to recover the declining groundwater level of the stressed Sparta aquifer by using surface water from a network of four reservoirs as an

  1. Purification and Detection of 39Ar in Groundwater Samples via Low-Level Counting

    Science.gov (United States)

    Mace, E. K.; Aalseth, C.; Brandenberger, J. M.; Humble, P.; Panisko, M.; Seifert, A.; Williams, R. M.

    2015-12-01

    Argon-39 can be used as a radiotracer to age-date groundwater aquifers to study recharge rates and to better understand the mean residence time, or age distributions, of groundwater. Argon-39 (with a half-life of 269 years) is created in the atmosphere by cosmic rays interacting with argon in the air (primarily 40Ar). The use of 39Ar as a radiotracer fills a gap in the age dating range which is currently covered by 3H/3He or 85Kr (1000 years); 39Ar fills the intermediate time scale range from 50-1000 years where the previously established radiotracers are not adequate. We will introduce the process for purifying and detecting 39Ar in ground water using ultra-low-background proportional counters (ULBPCs) at the shallow underground laboratory at Pacific Northwest National Laboratory. Argon-39 is detected through direct beta counting using ULBPCs loaded with a mixture of geologic argon (extracted from a carbon dioxide well with no measureable 39Ar activity) and methane, which enhances the sensitivity for 39Ar measurements. The ULBPCs have been shown to have a background count rate of 148 counts per day (cpd) in the energy range 3-400 keV when filled with 10 atm of P-10 counting gas (90% geologic Ar, 10% CH4). Initial demonstration samples were collected from groundwater aquifers in Fresno, California supported by the United States Geological Survey (USGS). A discussion of the sampling technique to degas the water from these wells and to then purify it for counting will be presented. In order to quantify the 39Ar contribution in the groundwater samples, the ULBPCs were characterized to determine two components: 1) the detector efficiency to modern levels of 39Ar, and 2) the remaining detector background (using geologic sourced argon which is free from 39Ar - no measureable 39Ar activity). These characterization results will be presented along with a discussion of the quantification of the 39Ar age of the demonstration measurements.

  2. Discharge areas for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents discharge areas in the Death Valley regional ground-water flow system (DVRFS) transient model. Natural ground-water discharge occurs...

  3. Material-property zones used in the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Zones in this data set represent spatially contiguous areas that influence ground-water flow in the Death Valley regional ground-water flow system (DVRFS), an...

  4. Material-property zones used in the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Zones in this data set represent spatially contiguous areas that influence ground-water flow in the Death Valley regional ground-water flow system (DVRFS), an...

  5. Discharge areas for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents discharge areas in the Death Valley regional ground-water flow system (DVRFS) transient model. Natural ground-water discharge...

  6. The 3D simulation and optimized management model of groundwater systems based on ecoenvironmental water demand

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Through the study of mutual process between groundwater systems and eco-environmental water demand, the eco-environmental water demand is brought into groundwater systems model as the important water consumption item and unification of groundwater's economic, environmental and ecological functions were taken into account. Based on eco-environmental water demand at Da'an in Jilin province, a three-dimensional simulation and optimized management model of groundwater systems was established. All water balance components of groundwater systems in 1998 and 1999 were simulated with this model and the best optimal exploitation scheme of groundwater systems in 2000 was determined, so that groundwater resource was efficiently utilized and good economic, ecologic and social benefits were obtained.

  7. Determination of Organic Pollutants in Small Samples of Groundwaters by Liquid-Liquid Extraction and Capillary Gas Chromatography

    DEFF Research Database (Denmark)

    Harrison, I.; Leader, R.U.; Higgo, J.J.W.;

    1994-01-01

    A method is presented for the determination of 22 organic compounds in polluted groundwaters. The method includes liquid-liquid extraction of the base/neutral organics from small, alkaline groundwater samples, followed by derivatisation and liquid-liquid extraction of phenolic compounds after...... neutralisation. The extracts were analysed by capillary gas chromatography. Dual detection by flame Ionisation and electron capture was used to reduce analysis time....

  8. Geochemistry and the understanding of ground-water systems

    Science.gov (United States)

    Glynn, Pierre D.; Plummer, L. Niel

    2005-03-01

    Geochemistry has contributed significantly to the understanding of ground-water systems over the last 50 years. Historic advances include development of the hydrochemical facies concept, application of equilibrium theory, investigation of redox processes, and radiocarbon dating. Other hydrochemical concepts, tools, and techniques have helped elucidate mechanisms of flow and transport in ground-water systems, and have helped unlock an archive of paleoenvironmental information. Hydrochemical and isotopic information can be used to interpret the origin and mode of ground-water recharge, refine estimates of time scales of recharge and ground-water flow, decipher reactive processes, provide paleohydrological information, and calibrate ground-water flow models. Progress needs to be made in obtaining representative samples. Improvements are needed in the interpretation of the information obtained, and in the construction and interpretation of numerical models utilizing hydrochemical data. The best approach will ensure an optimized iterative process between field data collection and analysis, interpretation, and the application of forward, inverse, and statistical modeling tools. Advances are anticipated from microbiological investigations, the characterization of natural organics, isotopic fingerprinting, applications of dissolved gas measurements, and the fields of reaction kinetics and coupled processes. A thermodynamic perspective is offered that could facilitate the comparison and understanding of the multiple physical, chemical, and biological processes affecting ground-water systems. La géochimie a contribué de façon importante à la compréhension des systèmes d'eaux souterraines pendant les 50 dernières années. Les avancées ont portées sur le développement du concept des faciès hydrochimiques, sur l'application de la théorie des équilibres, l'étude des processus d'oxydoréduction, et sur la datation au radiocarbone. D'autres concepts, outils et

  9. A review of single-sample-based models and other approaches for radiocarbon dating of dissolved inorganic carbon in groundwater

    Science.gov (United States)

    Han, L. F; Plummer, Niel

    2016-01-01

    13C values.In contrast to the single-sample-based models, the extended Gonfiantini & Zuppi model (Gonfiantini and Zuppi, 2003; Han et al., 2014) is a statistical approach. This approach can be used to estimate 14C ages when a curved relationship between the 14C and 13C values of the DIC data is observed. In addition to estimation of groundwater ages, the relationship between 14C and δ13C data can be used to interpret hydrogeological characteristics of the aquifer, e.g. estimating apparent rates of geochemical reactions and revealing the complexity of the geochemical environment, and identify samples that are not affected by the same set of reactions/processes as the rest of the dataset. The investigated water samples may have a wide range of ages, and for waters with very low values of 14C, the model based on statistics may give more reliable age estimates than those obtained from single-sample-based models. In the extended Gonfiantini & Zuppi model, a representative system-wide value of the initial 14C content is derived from the 14C and δ13C data of DIC and can differ from that used in single-sample-based models. Therefore, the extended Gonfiantini & Zuppi model usually avoids the effect of modern water components which might retain ‘bomb’ pulse signatures.The geochemical mass-balance approach constructs an adjustment model that accounts for all the geochemical reactions known to occur along an aquifer flow path (Plummer et al., 1983; Wigley et al., 1978; Plummer et al., 1994; Plummer and Glynn, 2013), and includes, in addition to DIC, dissolved organic carbon (DOC) and methane (CH4). If sufficient chemical, mineralogical and isotopic data are available, the geochemical mass-balance method can yield the most accurate estimates of the adjusted radiocarbon age. The main limitation of this approach is that complete information is necessary on chemical, mineralogical and isotopic data and these data are often limited.Failure to recognize the limitations and

  10. Antibiotic resistance patterns of Escherichia coli strains isolated from surface water and groundwater samples in a pig production area

    Directory of Open Access Journals (Sweden)

    Roger Neto Schneider

    2009-09-01

    Full Text Available The use of antibiotics, so excessive and indiscriminate in intensive animal production, has triggered an increase in the number of resistant microorganisms which can be transported to aquatic environments. The aim of this study was to determine the profile of the antimicrobial resistance of samples of Escherichia coli isolated from groundwater and surface water in a region of pig breeding. Through the test of antimicrobial susceptibility, we analyzed 205 strains of E. coli. A high rate of resistance to cefaclor was observed, both in surface water (51.9% and groundwater (62.9%, while all samples were sensitive to amikacin. The percentages of multi-resistant samples were 25.96% and 26.73% in surface water and groundwater, respectively, while 19.23% and 13.86% were sensitive to all antibiotics tested. It was determined that the rate of multiple antibiotic resistance (MAR was 0.164 for surface water and 0.184 for groundwater. No significant differences were found in the profile of the antimicrobial resistance in strains of E. coli isolated in surface water and groundwater, but the index MAR calculated in certain points of groundwater may offer a potential risk of transmission of resistant genes.

  11. Dynamic groundwater monitoring networks: a manageable method for reviewing sampling frequency.

    Science.gov (United States)

    Moreau-Fournier, Magali F; Daughney, Christopher J

    2012-12-01

    Optimization of a water quality network through a change in sampling frequency is the only way to increase cost-efficiency without any reduction in the robustness of the data. Existing techniques define optimal sampling frequency based on analysis of historical data from the monitoring network under investigation. Their application to a large network comprised of many sites and many monitored parameters is both technical and challenging. This paper presents a simple non-parametric method for reviewing sampling frequency that is consistent with highly censored environmental data and oriented towards reduction of sampling frequency as a cost-saving measure. Based on simple descriptive statistics, the method is applicable to large networks with long time series and many monitored parameters. The method also provides metrics for interpretation of newly collected data, which enables identification of sites for which a future change in sampling frequency may be necessary, ensuring that the monitoring network is both current and adaptive. Application of this method to the New Zealand National Groundwater Monitoring Programme indicates that reduction of sampling frequency at any site would result in a significant loss of information. This paper also discusses the potential for reducing analysis frequency as an alternative to reduction of sampling frequency.

  12. Groundwater flow dynamics in the complex aquifer system of Gidabo River Basin (Ethiopian Rift): a multi-proxy approach

    Science.gov (United States)

    Mechal, Abraham; Birk, Steffen; Dietzel, Martin; Leis, Albrecht; Winkler, Gerfried; Mogessie, Aberra; Kebede, Seifu

    2017-03-01

    Hydrochemical and isotope data in conjunction with hydraulic head and spring discharge observations were used to characterize the regional groundwater flow dynamics and the role of the tectonic setting in the Gidabo River Basin, Ethiopian Rift. Both groundwater levels and hydrochemical and isotopic data indicate groundwater flow from the major recharge area in the highland and escarpment into deep rift floor aquifers, suggesting a deep regional flow system can be distinguished from the shallow local aquifers. The δ18O and δ2H values of deep thermal (≥30 °C) groundwater are depleted relative to the shallow (floor. Based on the δ18O values, the thermal groundwater is found to be recharged in the highland around 2,600 m a.s.l. and on average mixed with a proportion of 30 % shallow groundwater. While most groundwater samples display diluted solutions, δ13C data of dissolved inorganic carbon reveal that locally the thermal groundwater near fault zones is loaded with mantle CO2, which enhances silicate weathering and leads to anomalously high total dissolved solids (2,000-2,320 mg/l) and fluoride concentrations (6-15 mg/l) exceeding the recommended guideline value. The faults are generally found to act as complex conduit leaky barrier systems favoring vertical mixing processes. Normal faults dipping to the west appear to facilitate movement of groundwater into deeper aquifers and towards the rift floor, whereas those dipping to the east tend to act as leaky barriers perpendicular to the fault but enable preferential flow parallel to the fault plane.

  13. Golan Heights Groundwater Systems: Separation By REE+Y And Stable Isotopes

    Science.gov (United States)

    Siebert, C.; Geyer, S.; Knoeller, K.; Roediger, T.; Weise, S.; Dulski, P.; Moeller, P.; Guttman, J.

    2008-12-01

    In a semi-arid to arid country like Israel, all freshwater resources are under (over-) utilization. Particularly, the Golan Heights rank as one of the most important extraction areas of groundwater of good quality and quantity. Additionally the mountain range feed to a high degree the most important freshwater reservoir of Israel, the Sea of Galilee. Hence, knowing the sources and characters of the Golan Heights groundwater systems is an instantaneous demand regarding sustainable management and protection. Within the "German-Israeli-Jordanian-Palestinian Joint Research Program for the Sustainable Utilisation of Aquifer Systems", hundreds of water samples were taken from all over the Jordan-Dead Sea rift-system to understand groundwater flow-systems and salinisation. For that purpose, each sample was analysed for major and minor ions, rare earth elements including yttrium (REY) and stable isotopes of water (d18O, d2H). The REY distribution in groundwater is established during infiltration by the first water-rock interaction and consequently reflects the leachable components of sediments and rocks of the recharge area. In well- developed flow-systems, REY are adsorbed onto pore surfaces are in equilibrium with the percolating groundwater, even if the lithology changes (e.g. inter-aquifer flow). Thus, groundwater sampled from wells and springs still show the REY distribution pattern established in the recharge area. Since high temperatures do not occur in Golan Heights, d2H and d18O are less controlled by water-rock interaction than by climatic and geomorphological factors at the time of replenishment. Applying the REY signature as a grouping criterion of groundwaters, d18O vs. d2H plots yield a new dimension in interpreting isotope data. The combined use of hydrochemical and isotopic methods enabled us to contain the areas of replenishment and the flow-paths of all investigated groundwater in the Golan Heights. Despite location, salinity or temperature of spring or

  14. Chemical variability of groundwater samples collected from a coal seam gas exploration well, Maramarua, New Zealand.

    Science.gov (United States)

    Taulis, Mauricio; Milke, Mark

    2013-03-01

    A pilot study has produced 31 groundwater samples from a coal seam gas (CSG) exploration well located in Maramarua, New Zealand. This paper describes sources of CSG water chemistry variations, and makes sampling and analytical recommendations to minimize these variations. The hydrochemical character of these samples is studied using factor analysis, geochemical modelling, and a sparging experiment. Factor analysis unveils carbon dioxide (CO(2)) degassing as the principal cause of sample variation (about 33%). Geochemical modelling corroborates these results and identifies minor precipitation of carbonate minerals with degassing. The sparging experiment confirms the effect of CO(2) degassing by showing a steady rise in pH while maintaining constant alkalinity. Factor analysis correlates variations in the major ion composition (about 17%) to changes in the pumping regime and to aquifer chemistry variations due to cation exchange reactions with argillaceous minerals. An effective CSG water sampling program can be put into practice by measuring pH at the wellhead and alkalinity at the laboratory; these data can later be used to calculate the carbonate speciation at the time the sample was collected. In addition, TDS variations can be reduced considerably if a correct drying temperature of 180 °C is consistently implemented.

  15. Detection of Septic System Waste in the Groundwaters of Southern California Using Emerging Contaminants and Isotopic Tracers

    Science.gov (United States)

    Huang, W.; Conkle, J.; Sickman, J. O.; Lucero, D.; Pang, F.; Gan, J.

    2011-12-01

    In California, groundwater supplies 30-40% of the State's water and in rapidly growing regions like the Inland Empire, groundwater makes up 80-90% of the municipal water supply. However, anthropogenic contamination could adversely affect groundwater quality and thereby reduce available supplies. Appropriate tracers are needed to identify groundwater contamination and protect human health. Stable isotopes δ15N and δ 18O offer unique information about the importance of nitrate sources and processes affecting nitrate in aquifers. We investigated the influence of septic systems on groundwater quality in and around the city of Beaumont, CA during 2010-11. Groundwater samples were collected from 38 active wells and 10 surface water sites in the region (urban and natural streams, agricultural drainage and groundwater recharge basins supplied by the California State Water Project). Stable isotopes and pharmaceuticals and personal care products (PPCPs) were analyzed for all the water samples. The variations of δ15N and δ 18O of nitrate were 2 - 21 per mil and -4 - 9 per mil respectively. δ15N-NO3 values greater than 10 per mil have been associated with nitrate inputs from sewage and animal waste, but in the Beaumont wells, PPCP concentrations were at or below the detection limit in most wells with high isotope ratios. We also observed a strong linear relationship between δ15N and δ 18O of nitrate (slope of~ 0.5) in the vast majority of our samples including those with high isotope ratios. Our results suggest that denitrification was widespread in the Beaumont aquifer and strongly affected the isotope composition of nitrate. In some wells, PPCPs (carbamazepine, sulfamethoxazole, primidone, meprobamate and diuron) and isotope measurements indicated inputs from human waste, but these sites were affected primarily by local waste-water treatment plant effluent. A mixing model was developed using multiple tracers to determine sources and contributions of groundwater

  16. Intrinsic and Extrinsic Chemical and Isotopic Tracers for Characterization Of Groundwater Systems

    Energy Technology Data Exchange (ETDEWEB)

    Moran, J E; Singleton, M J; Carle, S F; Esser, B K

    2007-09-13

    In many regions, three dimensional characterization of the groundwater regime is limited by coarse well spacing or borehole lithologic logs of low quality. However, regulatory requirements for drinking water or site remediation may require collection of extensive chemical and water quality data from existing wells. Similarly, for wells installed in the distant past, lithologic logs may not be available, but the wells can be sampled for chemical and isotopic constituents. In these situations, a thorough analysis of trends in chemical and isotopic constituents can be a key component in characterizing the regional groundwater system. On a basin or subbasin scale, especially in areas of intensive groundwater management where artificial recharge is important, introduction of an extrinsic tracer can provide a robust picture of groundwater flow. Dissolved gases are particularly good tracers since a large volume of water can be tagged, there are no real or perceived health risks associated with the tracer, and a very large dynamic range allows detection of a small amount of tagged water in well discharge. Recent applications of the application of extrinsic tracers, used in concert with intrinsic chemical and isotopic tracers, demonstrate the power of chemical analyses in interpreting regional subsurface flow regimes.

  17. Spatio-temporal impact of climate change on the groundwater system

    Directory of Open Access Journals (Sweden)

    J. Dams

    2011-11-01

    Full Text Available Given the importance of groundwater for food production and drinking water supply, but also for the survival of groundwater dependent terrestrial ecosystems (GWDTEs it is essential to assess the impact of climate change on this freshwater resource. In this paper we study with high temporal and spatial resolution the impact of 28 climate change scenarios on the groundwater system of a lowland catchment in Belgium. Our results show for the scenario period 2070–2101 compared with the reference period 1960–1991, a change in annual groundwater recharge between −20% and +7%. On average annual groundwater recharge decreases 7%. Seasonally, in most scenarios the recharge increases during winter but decreases during summer. The altered recharge patterns cause the groundwater level to decrease significantly from September to January. On average the groundwater level decreases about 7 cm with a standard deviation between the scenarios of 5 cm. Groundwater levels in interfluves and upstream areas are more sensitive to climate change than groundwater levels in the river valley. Groundwater discharge to GWDTEs is expected to decrease during late summer and autumn as much as 10%, though the discharge remains at reference-period level during winter and early spring. As GWDTEs are strongly influenced by temporal dynamics of the groundwater system, close monitoring of groundwater and implementation of adaptive management measures are required to prevent ecological loss.

  18. Spatio-temporal impact of climate change on the groundwater system

    Directory of Open Access Journals (Sweden)

    J. Dams

    2012-05-01

    Full Text Available Given the importance of groundwater for food production and drinking water supply, but also for the survival of groundwater dependent terrestrial ecosystems (GWDTEs it is essential to assess the impact of climate change on this freshwater resource. In this paper we study with high temporal and spatial resolution the impact of 28 climate change scenarios on the groundwater system of a lowland catchment in Belgium. Our results show for the scenario period 2070–2101 compared with the reference period 1960–1991, a change in annual groundwater recharge between −20% and +7%. On average annual groundwater recharge decreases 7%. In most scenarios the recharge increases during winter but decreases during summer. The altered recharge patterns cause the groundwater level to decrease significantly from September to January. On average the groundwater level decreases about 7 cm with a standard deviation between the scenarios of 5 cm. Groundwater levels in interfluves and upstream areas are more sensitive to climate change than groundwater levels in the river valley. Groundwater discharge to GWDTEs is expected to decrease during late summer and autumn as much as 10%, though the discharge remains at reference-period level during winter and early spring. As GWDTEs are strongly influenced by temporal dynamics of the groundwater system, close monitoring of groundwater and implementation of adaptive management measures are required to prevent ecological loss.

  19. An Integrated Approach on Groundwater Flow and Heat/Solute Transport for Sustainable Groundwater Source Heat Pump (GWHP) System Operation

    Science.gov (United States)

    Park, D. K.; Bae, G. O.; Joun, W.; Park, B. H.; Park, J.; Park, I.; Lee, K. K.

    2015-12-01

    The GWHP system uses a stable temperature of groundwater for cooling and heating in buildings and thus has been known as one of the most energy-saving and cost-efficient renewable energy techniques. A GWHP facility was installed at an island located at the confluence of North Han and South Han rivers, Korea. Because of well-developed alluvium, the aquifer is suitable for application of this system, extracting and injecting a large amount of groundwater. However, the numerical experiments under various operational conditions showed that it could be vulnerable to thermal interference due to the highly permeable gravel layer, as a preferential path of thermal plume migration, and limited space for well installation. Thus, regional groundwater flow must be an important factor of consideration for the efficient operation under these conditions but was found to be not simple in this site. While the groundwater level in this site totally depends on the river stage control of Paldang dam, the direction and velocity of the regional groundwater flow, observed using the colloidal borescope, have been changed hour by hour with the combined flows of both the rivers. During the pumping and injection tests, the water discharges in Cheongpyeong dam affected their respective results. Moreover, the measured NO3-N concentrations might imply the effect of agricultural activities around the facility on the groundwater quality along the regional flow. It is obvious that the extraction and injection of groundwater during the facility operation will affect the fate of the agricultural contaminants. Particularly, the gravel layer must also be a main path for contaminant migration. The simulations for contaminant transport during the facility operation showed that the operation strategy for only thermal efficiency could be unsafe and unstable in respect of groundwater quality. All these results concluded that the integrated approach on groundwater flow and heat/solute transport is necessary

  20. Data Validation Package, April and June 2016 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing Site, October 2016

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Joshua [U. S. Department of Energy, Washington, DC (United States). Office of Legacy Management; Campbell, Sam [Navarro Research and Engineering, Oak Ridge, TN (United States)

    2016-10-01

    This event included annual sampling of groundwater and surface water locations at the Gunnison, Colorado, Processing Site. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for US Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and­ analysis-plan-us-department-energy-office-legacy-management-sites). Samples were collected from 28 monitoring wells, three domestic wells, and six surface locations in April at the processing site as specified in the draft 2010 Ground Water Compliance Action Plan for the Gunnison, Colorado, Processing Site. Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. Domestic wells 0476 and 0477 were sampled in June because the homes were unoccupied in April, and the wells were not in use. Duplicate samples were collected from locations 0126, 0477, and 0780. One equipment blank was collected during this sampling event. Water levels were measured at all monitoring wells that were sampled. See Attachment 2, Trip Reports for additional details. The analytical data and associated qualifiers can be viewed in environmental database reports and are also available for viewing with dynamic mapping via the GEMS (Geospatial Environmental Mapping System) website at http://gems.lm.doe.gov/#. No issues were identified during the data validation process that requires additional action or follow-up. An assessment of anomalous data is included in Attachment 3. Interpretation and presentation of results, including an assessment ofthe natural flushing compliance strategy, will be reported in the upcoming 2016 Verification Monitoring Report. U.S.

  1. Supplemental Assessment of the Y-12 Groundwater Protection Program Using Monitoring and Remediation Optimization System Software

    Energy Technology Data Exchange (ETDEWEB)

    Elvado Environmental LLC; GSI Environmental LLC

    2009-01-01

    A supplemental quantitative assessment of the Groundwater Protection Program (GWPP) at the Y-12 National Security Complex (Y-12) in Oak Ridge, TN was performed using the Monitoring and Remediation Optimization System (MAROS) software. This application was previously used as part of a similar quantitative assessment of the GWPP completed in December 2005, hereafter referenced as the 'baseline' MAROS assessment (BWXT Y-12 L.L.C. [BWXT] 2005). The MAROS software contains modules that apply statistical analysis techniques to an existing GWPP analytical database in conjunction with hydrogeologic factors, regulatory framework, and the location of potential receptors, to recommend an improved groundwater monitoring network and optimum sampling frequency for individual monitoring locations. The goal of this supplemental MAROS assessment of the Y-12 GWPP is to review and update monitoring network optimization recommendations resulting from the 2005 baseline report using data collected through December 2007. The supplemental MAROS assessment is based on the findings of the baseline MAROS assessment and includes only the groundwater sampling locations (wells and natural springs) currently granted 'Active' status in accordance with the Y-12 GWPP Monitoring Optimization Plan (MOP). The results of the baseline MAROS assessment provided technical rationale regarding the 'Active' status designations defined in the MOP (BWXT 2006). One objective of the current report is to provide a quantitative review of data collected from Active but infrequently sampled wells to confirm concentrations at these locations. This supplemental MAROS assessment does not include the extensive qualitative evaluations similar to those presented in the baseline report.

  2. Nutrient sampling slam: high resolution surface-water sampling in streams reveals patterns in groundwater chemistry and flow paths

    Science.gov (United States)

    The groundwater–surface water interface (GSWI), consisting of shallow groundwater adjacent to stream channels, is a hot spot for nitrogen removal processes, a storage zone for other solutes, and a target for restoration activities. Characterizing groundwater-surface water intera...

  3. Transport of Nitrogen and Phosphorus from Onsite Wastewater Treatment Systems to Shallow Groundwater

    Science.gov (United States)

    Toor, G.

    2014-12-01

    The knowledge about the nutrients transport from the vadose zone of onsite wastewater treatment systems (commonly called septic systems) is crucial to protect groundwater quality as 25% of US population uses septic systems to discharge household wastewater. For example, our preliminary data showed that about 47% of applied water was recovered at 60-cm below drainfield of septic systems. This implies that contaminants present in wastewater, if not attenuated in the vadose zone, can be transported to shallow groundwater. This presentation will focus on the biophysical and hydrologic controls on the transport of nitrogen (N) and phosphorus (P) from the vadose of two conventional (drip dispersal, gravel trench) and an advanced (with aerobic and anaerobic medias) system. These systems were constructed using two rows of drip pipe (37 emitters/mound) placed 0.3 m apart in the center of 6 m x 0.6 m drainfield. Each system received 120 L of wastewater per day. During 20-month period (May 2012 to December 2013), soil-water samples were collected from the vadose zone using suction cup lysimeters installed at 0.30, 0.60, and 1.05 m depth and groundwater samples were collected from piezometers installed at 3-3.30 m depth below the drainfield. A complimentary 1-year study using smaller drainfields (0.5 m long, 0.9 m wide, 0.9 m high) was conducted to obtain better insights in the vadose zone. A variety of instruments (multi-probe sensors, suction cup lysimeters, piezometers, tensiometers) were installed in the vadose zones. Results showed that nitrification controlled N evolution in drainfield and subsequent transport of N plumes (>10 mg/L) into groundwater. Most of the wastewater applied soluble inorganic P (>10 mg/L) was quickly attenuated in the drainfield due to fixation (sorption, precipitation) in the vadose zone (advanced system was extremely effective as it removed >95% N from wastewater, but was less effective at removing P. This presentation will conclude with

  4. Simulation of the regional groundwater-flow system of the Menominee Indian Reservation, Wisconsin

    Science.gov (United States)

    Juckem, Paul F.; Dunning, Charles P.

    2015-01-01

    A regional, two-dimensional, steady-state groundwater-flow model was developed to simulate the groundwater-flow system and groundwater/surface-water interactions within the Menominee Indian Reservation. The model was developed by the U.S. Geological Survey (USGS), in cooperation with the Menominee Indian Tribe of Wisconsin, to contribute to the fundamental understanding of the region’s hydrogeology. The objectives of the regional model were to improve understanding of the groundwater-flow system, including groundwater/surface-water interactions, and to develop a tool suitable for evaluating the effects of potential regional water-management programs. The computer code GFLOW was used because of the ease with which the model can simulate groundwater/surface-water interactions, provide a framework for simulating regional groundwater-flow systems, and be refined in a stepwise fashion to incorporate new data and simulate groundwater-flow patterns at multiple scales. Simulations made with the regional model reproduce groundwater levels and stream base flows representative of recent conditions (1970–2013) and illustrate groundwater-flow patterns with maps of (1) the simulated water table and groundwater-flow directions, (2) probabilistic areas contributing recharge to high-capacity pumped wells, and (3) estimation of the extent of infiltrated wastewater from treatment lagoons.

  5. Stygoregions – a promising approach to a bioregional classification of groundwater systems

    Science.gov (United States)

    Stein, Heide; Griebler, Christian; Berkhoff, Sven; Matzke, Dirk; Fuchs, Andreas; Hahn, Hans Jürgen

    2012-01-01

    Linked to diverse biological processes, groundwater ecosystems deliver essential services to mankind, the most important of which is the provision of drinking water. In contrast to surface waters, ecological aspects of groundwater systems are ignored by the current European Union and national legislation. Groundwater management and protection measures refer exclusively to its good physicochemical and quantitative status. Current initiatives in developing ecologically sound integrative assessment schemes by taking groundwater fauna into account depend on the initial classification of subsurface bioregions. In a large scale survey, the regional and biogeographical distribution patterns of groundwater dwelling invertebrates were examined for many parts of Germany. Following an exploratory approach, our results underline that the distribution patterns of invertebrates in groundwater are not in accordance with any existing bioregional classification system established for surface habitats. In consequence, we propose to develope a new classification scheme for groundwater ecosystems based on stygoregions. PMID:22993698

  6. Data Validation Package May 2015, Groundwater Sampling at the Shoal, Nevada, Site

    Energy Technology Data Exchange (ETDEWEB)

    Findlay, Rick [Navarro Research and Engineering, Oak Ridge, TN (United States); Kautsky, Mark [US Department of Energy, Washington, DC (United States). Office of Legacy Management

    2016-03-01

    The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Shoal, Nevada, Site (Shoal) in May 2015. Groundwater samples were collected from wells MV-1, MV-2, MV-3, MV-4, MV-5, H-3, HC-1, HC-2d, HC-3, HC-4, HC-5, HC-6, HC-7, HC-8, and HS-1. Sampling was conducted as specified in the Sampling and Analysis Plan for US. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and-analysis-plan-us-department-energy­ office-legacy-management-sites). Monitoring wells MV-1, MV-2, MV-3, MV-4, MV-5, HC-2d, HC-4, HC-5, HC-7, HC-8, and HS-1 were purged prior to sampling using dedicated submersible pumps. At least one well casing volume was removed, and field parameters (temperature, pH, and specific conductance) were allowed to stabilize before samples were collected. Samples were collected from wells H-3, HC-1, HC-3, and HC-6 using a depth-specific bailer because these wells are not completed with dedicated submersible pumps. Samples were submitted under Requisition Index Number (RIN) 15057042 to ALS Laboratory Group in Fort Collins, Colorado, for the determination of bromide, gross alpha, gross beta, tritium, uranium isotopes, and total uranium (by mass); and under RIN 15057043 to the University of Arizona for the determination of carbon-14 and iodine-129. A duplicate sample from location MV-2 was included with RIN 15057042. The laboratory results from the 2015 sampling event are consistent with those of previous years with the exception of sample results from well HC-4. This well continues to be the only well with tritium concentrations above the laboratory’s minimum detectable concentration which is attributed to the wells proximity to the nuclear detonation. The tritium concentration (731 picocuries per liter [pCi/L]) is consistent with past results and is below the U.S. Environmental Protection Agency's (EPA) maximum contaminant level (MCL) of 20,000 p

  7. New insights into nitrate dynamics in a karst groundwater system gained from in situ high-frequency optical sensor measurements

    Science.gov (United States)

    Opsahl, S. P.; Musgrove, M.; Slattery, R. N.

    2017-03-01

    urbanized area of the aquifer. Changes in specific conductance were observed at both sites during groundwater recharge, and a significant correlation between specific conductance and nitrate (correlation coefficient [R] = 0.455) was evident at the urban site where large (3-fold) changes in nitrate occurred. Nitrate concentrations and specific conductance measured during a depth profile indicated that the water column was generally homogeneous as expected for this karst environment, but changes were observed in the most productive zone of the aquifer that might indicate some heterogeneity within the complex network of flow paths. Resolving the timing and magnitude of changes and characterizing fine-scale vertical differences would not be possible using conventional sampling techniques. The patterns observed in situ provided new insight into the dynamic nature of nitrate in a karst groundwater system.

  8. A Guide for Using the Transient Ground-Water Flow Model of the Death Valley Regional Ground-Water Flow System, Nevada and California

    Energy Technology Data Exchange (ETDEWEB)

    Joan B. Blainey; Claudia C. Faunt, and Mary C. Hill

    2006-05-16

    This report is a guide for executing numerical simulations with the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California using the U.S. Geological Survey modular finite-difference ground-water flow model, MODFLOW-2000. Model inputs, including observations of hydraulic head, discharge, and boundary flows, are summarized. Modification of the DVRFS transient ground-water model is discussed for two common uses of the Death Valley regional ground-water flow system model: predictive pumping scenarios that extend beyond the end of the model simulation period (1998), and model simulations with only steady-state conditions.

  9. Handbook: Collecting Groundwater Samples from Monitoring Wells in Frenchman Flat, CAU 98

    Energy Technology Data Exchange (ETDEWEB)

    Chapman, Jenny [Desert Research Inst. (DRI), Reno, NV (United States); Lyles, Brad [Desert Research Inst. (DRI), Reno, NV (United States); Cooper, Clay [Desert Research Inst. (DRI), Reno, NV (United States); Hershey, Ron [Desert Research Inst. (DRI), Reno, NV (United States); Healey, John [Desert Research Inst. (DRI), Reno, NV (United States)

    2015-06-01

    Frenchman Flat basin on the Nevada National Security Site (NNSS) contains Corrective Action Unit (CAU) 98, which is comprised of ten underground nuclear test locations. Environmental management of these test locations is part of the Underground Test Area (UGTA) Activity conducted by the U.S. Department of Energy (DOE) under the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended) with the U.S. Department of Defense (DOD) and the State of Nevada. A Corrective Action Decision Document (CADD)/Corrective Action Plan (CAP) has been approved for CAU 98 (DOE, 2011). The CADD/CAP reports on the Corrective Action Investigation that was conducted for the CAU, which included characterization and modeling. It also presents the recommended corrective actions to address the objective of protecting human health and the environment. The recommended corrective action alternative is “Closure in Place with Modeling, Monitoring, and Institutional Controls.” The role of monitoring is to verify that Contaminants of Concern (COCs) have not exceeded the Safe Drinking Water Act (SDWA) limits (Code of Federal Regulations, 2014) at the regulatory boundary, to ensure that institutional controls are adequate, and to monitor for changed conditions that could affect the closure conditions. The long-term closure monitoring program will be planned and implemented as part of the Closure Report stage after activities specified in the CADD/CAP are complete. Groundwater at the NNSS has been monitored for decades through a variety of programs. Current activities were recently consolidated in an NNSS Integrated Sampling Plan (DOE, 2014). Although monitoring directed by the plan is not intended to meet the FFACO long-term monitoring requirements for a CAU (which will be defined in the Closure Report), the objective to ensure public health protection is similar. It is expected that data collected in accordance with the plan will support the transition to long-term monitoring at each

  10. Outline of the integrated simulation system (GEOMASS system) to evaluate groundwater flow and application to groundwater simulation in the Tono area

    Energy Technology Data Exchange (ETDEWEB)

    Inaba, Kaoru; Saegusa, Hiromitsu [Japan Nuclear Cycle Development Inst., Toki, Gifu (Japan). Tono Geoscience Center

    2003-03-01

    The Tono Geoscience Center (TGC) has been developing the GEOMASS system since 1997 to evaluate the groundwater flow at depth in a rock mass. The system provides an integrated simulation system environment for both model development and groundwater flow simulations. The integrated simulation system allows users to use resources efficiently. The system also allows users to make rapid improvement of their models as data increases. Also, it is possible to perform more realistic groundwater flow simulations due to the capability of modeling the rock mass as a continuum with discrete hydro-structural features in the rock. TGC tested the operation and usefulness of the GEOMASS system by applying to groundwater flow simulations in the Tono area, Gifu Prefecture. TGC confirmed that the system is very useful for complex geological models and multiple modeling. (author)

  11. Applicability and methodology of determining sustainable yield in groundwater systems

    Science.gov (United States)

    Kalf, Frans R. P.; Woolley, Donald R.

    2005-03-01

    There is currently a need for a review of the definition and methodology of determining sustainable yield. The reasons are: (1) current definitions and concepts are ambiguous and non-physically based so cannot be used for quantitative application, (2) there is a need to eliminate varying interpretations and misinterpretations and provide a sound basis for application, (3) the notion that all groundwater systems either are or can be made to be sustainable is invalid, (4) often there are an excessive number of factors bound up in the definition that are not easily quantifiable, (5) there is often confusion between production facility optimal yield and basin sustainable yield, (6) in many semi-arid and arid environments groundwater systems cannot be sensibly developed using a sustained yield policy particularly where ecological constraints are applied. Derivation of sustainable yield using conservation of mass principles leads to expressions for basin sustainable, partial (non-sustainable) mining and total (non-sustainable) mining yields that can be readily determined using numerical modelling methods and selected on the basis of applied constraints. For some cases there has to be recognition that the groundwater resource is not renewable and its use cannot therefore be sustainable. In these cases, its destiny should be the best equitable use. producciones sostenibles en cuenca, minado parcial (no sostenible) y total (no sostenible) que pueden determinarse fácilmente utilizando métodos de modelos numéricos y seleccionados en base a restricciones aplicadas. En algunos casos tiene que reconocerse que el recurso de agua subterránea no es renovable y que por lo tanto su uso no puede ser sostenible. En estos casos su destino debe de ser el uso más equitativo.

  12. Identifying key parameters to differentiate groundwater flow systems using multifactorial analysis

    Science.gov (United States)

    Menció, Anna; Folch, Albert; Mas-Pla, Josep

    2012-11-01

    SummaryMultivariate techniques are useful in hydrogeological studies to reduce the complexity of large-scale data sets, and provide more understandable insight into the system hydrology. In this study, principal component analysis (PCA) has been used as an exploratory method to identify the key parameters that define distinct flow systems in the Selva basin (NE Spain). In this statistical analysis, all the information obtained in hydrogeological studies (that is, hydrochemical and isotopic data, but also potentiometric data) is used. Additionally, cluster analysis, based on PCA results, allows the associations between samples to be identified, and thus, corroborates the occurrence of different groundwater fluxes. PCA and cluster analysis reveal that two main groundwater flow systems exist in the Selva basin, each with distinct hydrochemical, isotopic, and potentiometric features. Regional groundwater fluxes are associated with high F- contents, and confined aquifer layers; while local fluxes are linked to nitrate polluted unconfined aquifers with a different recharge rates. In agreement with previous hydrogeological studies, these statistical methods stand as valid screening tools to highlight the fingerprint variables that can be used as indicators to facilitate further, more arduous, analytical approaches and a feasible interpretation of the whole data set.

  13. Data Validation Package, December 2015, Groundwater and Surface Water Sampling at the Monument Valley, Arizona, Processing Site March 2016

    Energy Technology Data Exchange (ETDEWEB)

    Tyrrell, Evan [Navarro Research and Engineering, Inc., Oak Ridge, NV (United States); Denny, Angelita [USDOE Office of Legacy Management, Washington, DC (United States)

    2016-03-23

    Fifty-two groundwater samples and one surface water sample were collected at the Monument Valley, Arizona, Processing Site to monitor groundwater contaminants for evaluating the effectiveness of the proposed compliance strategy as specified in the 1999 Final Site Observational Work Plan for the UMTRA Project Site at Monument Valley, Arizona. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and-analysis-plan-us-department- energy-office-legacy-management-sites). Samples were collected for metals, anions, nitrate + nitrite as N, and ammonia as N analyses at all locations.

  14. Assessing the vulnerability of a karst groundwater system to contamination by pharmaceuticals

    Science.gov (United States)

    Einsiedl, Florian; Radke, Michael

    2010-05-01

    Contamination of drinking water supplies is a serious problem and a potential threat to public health. Organic micropollutants such as pharmaceuticals and personal care products are identified as an environmental risk and concern has been raised about their environmental presence and fate. These compounds are present in effluents of wastewater treatment plants (WWTPs) in concentrations of up to several µg/L, and they have frequently been detected in surface waters and groundwater systems. A popular method for wastewater disposal in karst areas is the injection of wastewater into open sinkholes. Subsequently, the wastewater infiltrates rapidly along conduits and through the fractured karst aquifer. This is a major contributing factor to the contamination of karst aquifers. To address the vulnerability of such systems against relatively mobile organic micropollutants, we investigated the occurrence of two pharmaceuticals (diclofenac, ibuprofen) in combination with the groundwater heterogeneity and flow pathways in the aquifer. Groundwater samples and effluents of three WWTPs were repeatedly collected during a field campaign in the Franconian Alb karst system which is located in southern Germany. These results were coupled with hydrogeological investigations such as tracer tests, application of environmental isotopes (3H), and modeling. The results of this study demonstrated that (i) both pharmaceuticals are mobile in the karst aquifer and thus represent a risk for contamination of karst water, (ii) the transport of pharmaceuticals in the fractured system with mean transit times of some years affects the karst groundwater contamination, and (iii) long-term wastewater injection containing organic micropollutants into karst ecosystems may contribute to water quality deterioration over years.

  15. Sampling and characterisation of groundwater colloids in ONKALO at Olkiluoto, Finland, 2011

    Energy Technology Data Exchange (ETDEWEB)

    Takala, M.; Ojala, S.; Jarvinen, E.; Manninen, P. [Ramboll Finland Oy, Espoo (Finland)

    2012-11-15

    The purpose of this study was to estimate the concentration of colloids and composition of the colloid phase on the basis of the water chemistry results of filtered and unfiltered water samples and to compare the results with the previous ones. The water samples were collected from groundwater stations ONK-PVA1 and ONK-PVA3 in October 2011. The colloid concentrations were determined from scanning electron microscopy (SEM) micrographs taken from the filters. The change in the water chemistry due to filtration was also analysed. The decrease of element concentrations due to filtration would possibly reflect the composition of the colloid phase. Because the concentration of the colloids is very low, two parallel water samples were analysed five times with an Inductively Coupled Plasma - Mass Spectrometry (ICP-MS) analyser so that the chemical differences between the filtered and unfiltered water could be evaluated. The colloid concentration in ONK-PVA1, determined by the single particle analysis of SEM micrographs, was 6 {mu}g/l while the colloid concentration in ONK-PVA3 was 7 {mu}g/l. The colloid phase composition could not be reliably determined due to the low colloid concentration. (orig.)

  16. Groundwater withdrawal rates from the Ozark Plateaus aquifer system, 1900 to 2010

    Science.gov (United States)

    Knierim, Katherine J.; Nottmeier, Anna M.; Worland, Scott C.; Westerman, Drew A.; Clark, Brian R.

    2016-01-01

    Groundwater is an often overlooked freshwater resource compared to surface water, but groundwater is used widely across the United States, especially during periods of drought. If groundwater models can successfully simulate past conditions, they may be used to evaluate potential future pumping scenarios or climate conditions, thus providing a valuable planning tool for water-resource managers. Quantifying the groundwater-use component for a groundwater model is a vital but often challenging endeavor. This dataset includes groundwater withdrawal rates modeled for the Ozark Plateaus aquifer system (Ozark system) from 1900 to 2010 by groundwater model cell (2.6 square kilometers) for five water-use divisions—agriculture (including irrigation and aquaculture), livestock, public supply (including municipal and rural water districts), and non-agriculture (including thermoelectric power generation, mining, commercial, and industrial)—and by country for domestic (self-supplied) use. Two child items are included with the dataset: “Domestic groundwater withdrawal rates from the Ozark Plateaus aquifer system, 1900 to 2010” and “Public supply, non-agriculture, livestock, and agriculture groundwater withdrawal rates from the Ozark Plateaus aquifer system, 1900 to 2010”. The Ozark system is located in the central United States and is composed of interbedded Cambrian to Pennsylvanian clastic and carbonate lithologies. In stratigraphic order, the Ozark system includes the Basement confining unit, St. Francois aquifer, St. Francois confining unit, Ozark aquifer, Ozark confining unit, Springfield Plateau aquifer, and Western Interior Plains confining system. Generally, the lower portion of the Ozark aquifer is the primary source of groundwater across much of Missouri and the Springfield Plateau aquifer is used across northern Arkansas. A full description of the methods used to model groundwater withdrawal rates from the Ozark system are available in Knierim et al., IN

  17. Geochemical Characterization of Groundwater in a Volcanic System

    Directory of Open Access Journals (Sweden)

    Carmelo Bellia

    2015-06-01

    Full Text Available A geochemical investigation was undertaken at Mt. Etna Volcano to better define groundwater characteristics of its aquifers. Results indicate that the Na–Mg ± Ca–HCO3− ± (SO42− or Cl− type accounts for more than 80% of the groundwater composition in the volcano. The remaining 20% is characterized by elevated Ca2+. Waters along coastal areas are enriched in SO42− or Cl−, mainly due to mixing with seawater and anthropogenic effects. The majority of the samples showed values between −4‰ to −9‰ for δ18O and −19‰ to −53‰ for δ2H, suggesting that precipitation is the predominant source of recharge to the aquifers, especially in the west of the study area. The analysis of δ13C and pCO2 shows values 1 to 3 times higher than those expected for waters in equilibrium with the atmosphere, suggesting a partial gas contribution from deep sources. The diffusion of gasses is likely to be controlled by tectonic structures in the volcano. The ascent of deep brines is also reflected in the CO2 enrichment (up to 2.2 bars and enriched δ2H/δ18O compositions observed in the salt mounts of Paternò.

  18. Groundwater flow processes and mixing in active volcanic systems: the case of Guadalajara (Mexico

    Directory of Open Access Journals (Sweden)

    A. Hernández-Antonio

    2015-02-01

    Full Text Available Groundwater chemistry and isotopic data from 40 production wells in the Atemajac and Toluquilla Valleys, located in and around the Guadalajara metropolitan area, were determined to develop a conceptual model of groundwater flow processes and mixing. Multivariate analysis including cluster analysis and principal component analysis were used to elucidate distribution patterns of constituents and factors controlling groundwater chemistry. Based on this analysis, groundwater was classified into four groups: cold groundwater, hydrothermal water, polluted groundwater and mixed groundwater. Cold groundwater is characterized by low temperature, salinity, and Cl and Na concentrations and is predominantly of Na-HCO3 type. It originates as recharge at Primavera caldera and is found predominantly in wells in the upper Atemajac Valley. Hydrothermal water is characterized by high salinity, temperature, Cl, Na, HCO3, and the presence of minor elements such as Li, Mn and F. It is a mixed HCO3 type found in wells from Toluquilla Valley and represents regional flow circulation through basaltic and andesitic rocks. Polluted groundwater is characterized by elevated nitrate and sulfate concentrations and is usually derived from urban water cycling and subordinately from agricultural practices. Mixed groundwaters between cold and hydrothermal components are predominantly found in the lower Atemajac Valley. Tritium method elucidated that practically all of the sampled groundwater contains at least a small fraction of modern water. The multivariate mixing model M3 indicates that the proportion of hydrothermal fluids in sampled well water is between 13 (local groundwater and 87% (hydrothermal water, and the proportion of polluted water in wells ranges from 0 to 63%. This study may help local water authorities to identify and quantify groundwater contamination and act accordingly.

  19. Numerical simulation of groundwater flow for the Yakima River basin aquifer system, Washington

    Science.gov (United States)

    Ely, D.M.; Bachmann, M.P.; Vaccaro, J.J.

    2011-01-01

    A regional, three-dimensional, transient numerical model of groundwater flow was constructed for the Yakima River basin aquifer system to better understand the groundwater-flow system and its relation to surface-water resources. The model described in this report can be used as a tool by water-management agencies and other stakeholders to quantitatively evaluate proposed alternative management strategies that consider the interrelation between groundwater availability and surface-water resources.

  20. Assessing the relative bioavailability of DOC in regional groundwater systems

    Science.gov (United States)

    Chapelle, Francis H.; Bradley, Paul M.; Journey, Celeste; McMahon, Peter B.

    2013-01-01

    It has been hypothesized that the degree to which a hyperbolic relationship exists between concentrations of dissolved organic carbon (DOC) and dissolved oxygen (DO) in groundwater may indicate the relative bioavailability of DOC. This hypothesis was examined for 73 different regional aquifers of the United States using 7745 analyses of groundwater compiled by the National Water Assessment (NAWQA) program of the U.S. Geological Survey. The relative reaction quotient (RRQ), a measure of the curvature of DOC concentrations plotted versus DO concentrations and regressed to a decaying hyperbolic equation, was used to assess the relative bioavailability of DOC. For the basalt aquifer of Oahu, Hawaii, RRQ values were low (0.0013 mM−2), reflecting a nearly random relationship between DOC and DO concentrations. In contrast, on the island of Maui, treated sewage effluent injected into a portion of the basalt aquifer resulted in pronounced hyperbolic DOC-DO behavior and a higher RRQ (142 mM−2). RRQ values for the 73 aquifers correlated positively with mean concentrations of ammonia, dissolved iron, and manganese, and correlated negatively with mean pH. This indicates that greater RRQ values are associated with greater concentrations of the final products of microbial reduction reactions. RRQ values and DOC concentrations were negatively correlated with the thickness of the unsaturated zone (UNST) and depth to the top of the screened interval. Finally, RRQ values were positively correlated with mean annual precipitation (MAP), and the highest observed RRQ values were associated with aquifers receiving MAP rates ranging between 900 and 1300 mm/year. These results are uniformly consistent with the hypothesis that the hyperbolic behavior of DOC-DO plots, as quantified by the RRQ metric, can be an indicator of relative DOC bioavailability in groundwater systems.

  1. Data from exploratory sampling of groundwater in selected oil and gas areas of coastal Los Angeles County and Kern and Kings Counties in southern San Joaquin Valley, 2014–15: California oil, gas, and groundwater project

    Science.gov (United States)

    Dillon, David B.; Davis, Tracy A.; Landon, Matthew K.; Land, Michael T.; Wright, Michael T.; Kulongoski, Justin T.

    2016-12-09

    Exploratory sampling of groundwater in coastal Los Angeles County and Kern and Kings Counties of the southern San Joaquin Valley was done by the U.S. Geological Survey from September 2014 through January 2015 as part of the California State Water Resources Control Board’s Water Quality in Areas of Oil and Gas Production Regional Groundwater Monitoring Program. The Regional Groundwater Monitoring Program was established in response to the California Senate Bill 4 of 2013 mandating that the California State Water Resources Control Board design and implement a groundwater-monitoring program to assess potential effects of well-stimulation treatments on groundwater resources in California. The U.S. Geological Survey is in cooperation with the California State Water Resources Control Board to collaboratively implement the Regional Groundwater Monitoring Program through the California Oil, Gas, and Groundwater Project.Many researchers have documented the utility of different suites of chemical tracers for evaluating the effects of oil and gas development on groundwater quality. The purpose of this exploratory sampling effort was to determine whether tracers reported in the literature could be used effectively in California. This reconnaissance effort was not designed to assess the effects of oil and gas on groundwater quality in the sampled areas. A suite of water-quality indicators and geochemical tracers were sampled at groundwater sites in selected areas that have extensive oil and gas development. Groundwater samples were collected from a total of 51 wells, including 37 monitoring wells at 17 multiple-well monitoring sites in coastal Los Angeles County and 5 monitoring wells and 9 water-production wells in southern San Joaquin Valley, primarily in Kern and Kings Counties.Groundwater samples were analyzed for field water-quality indicators; organic constituents, including volatile and semi-volatile organic compounds and dissolved organic carbon indicators; naturally

  2. Data Validation Package December 2015 Groundwater Sampling at the Ambrosia Lake, New Mexico, Disposal Site March 2016

    Energy Technology Data Exchange (ETDEWEB)

    Tsosie, Bernadette [USDOE Office of Legacy Management, Washington, DC (United States); Johnson, Dick [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-03-01

    The Long-Term Surveillance Plan for the Ambrosia Lake, New Mexico, Disposal Site does not require groundwater monitoring because groundwater in the uppermost aquifer is of limited use, and supplemental standards have been applied to the aquifer. However, at the request of the New Mexico Environment Department, the U.S. Department of Energy conducts annual monitoring at three locations: monitoring wells 0409, 0675, and 0678. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for US. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). Monitoring Well 0409 was not sampled during this event because it was dry. Water levels were measured at each sampled well. One duplicate sample was collected from location 0675. Groundwater samples from the two sampled wells were analyzed for the constituents listed in Table 1. Time-concentration graphs for selected analytes are included in this report. At well 0675, the duplicate results for total dissolved solids and for most metals (magnesium, molybdenum, potassium, selenium, sodium, and uranium) were outside acceptance criteria, which may indicate non-homogeneous conditions at this location. November 2014 results for molybdenum and uranium at well 0675 also were outside acceptance criteria. The well condition will be evaluated prior to the next sampling event.

  3. A research on grey numerical imitation and modeling of groundwater seepage system

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Based on grey set, grey numbers and their operation properties, the grey numerical model of groundwater seepage system was set up for the first time, the whole grey solving method of the model was given and it was proved that the common solving method of the model was only a special case of the grey solving methods. At the same time, the grey solving method was compared widely with common solving method, classical numerical method. The study shows that the grey solving method is better in depicting the procedure of transporting grey data of groundwater system. On the basis of the theoretical study, two basic kinds of cases about groundwater seepage were selected: the prediction of pit yield and the evaluation of groundwater resources on a groundwater basin. In the cases, systematical analyses were made for generalization and greylization of the hydrogeologic conditions, setting up of the grey model, identification and correction of the model as well as its prediction and evaluation. It was pointed out that when the grey numerical model is used to predict pit yield, the upper limit of the “grey band” of groundwater level cannot be higher than planed safe groundwater level, when evaluating the groundwater resource, the lower limit of the “grey band” of groundwater level cannot be lower than controlled level of groundwater.

  4. Fate of human viruses in groundwater recharge systems

    Energy Technology Data Exchange (ETDEWEB)

    Vaughn, J.M.; Landry, E.F.

    1980-03-01

    The overall objective of this research program was to determine the ability of a well-managed tertiary effluent-recharge system to return virologically acceptable water to the groundwater aquifer. The study assessed the quality of waters renovated by indigenous recharge operations and investigated a number of virus-soil interrelationships. The elucidation of the interactions led to the establishment of basin operating criteria for optimizing virus removal. Raw influents, chlorinated tertiary effluents, and renovated wastewater from the aquifer directly beneath a uniquely designed recharge test basin were assayed on a weekly basis for the presence of human enteroviruses and coliform bacteria. High concentrations of viruses were routinely isolated from influents but were isolated only on four occasions from tertiary-treated sewage effluents. In spite of the high quality effluent being recharged, viruses were isolated from the groundwater observation well, indicating their ability to penetrate the unsaturated zone. Results of poliovirus seeding experiments carried out in the test basin clearly indicated the need to operate recharge basins at low (e.g. 1 cm/h) infiltration rates in areas having soil types similar to those found at the study site. The method selected for reducing the test basin infiltration rate involved clogging the basin surface with settled organic material from highly turbid effluent. Alternative methods for slowing infiltration rates are discussed in the text.

  5. Ecohydrological Investigations of a Groundwater-Lake System

    DEFF Research Database (Denmark)

    Frandsen, Mette Cristine Schou

    are very dynamic systems on a spatial scale. Variability in meteorology can lead to variability in the hydrology, and in some cases ignite transient effects that are temporally distinct and difficult to capture. •To some extend the lakes acts as sentinel for all the in and out-puts to the system as well...... I). •Does dense bottom vegetation affect the small scale hydrology of the lake bed sediment? (Paper 2). •How can natural tracers (δ 18O) be used to quantify the temporal variation in groundwater seepage dynamics? (Paper 3). •Is it possible to combine ecological data of surface water chemistry...... by this. The reasons for the lowered hydraulic conductivity seems to be an combination of the organic content in the sediment (i.e. the roots of the plants) and a vegetation induced entrapment of fine particles in the sediment. Over the course of three years I followed the small scale variation...

  6. Modeling Reactive Transport in Coupled Groundwater-Conduit Systems

    Science.gov (United States)

    Spiessl, S. M.; Sauter, M.; Zheng, C.; Viswanathan, H. S.

    2002-05-01

    Modeling reactive transport in coupled groundwater-conduit systems requires consideration of two transport time scales in the flow and transport models. Consider for example a subsurface mine consisting of a network of highly conductive shafts, drifts or ventilation raises (i.e., conduits) within the considerably less permeable ore material (i.e., matrix). In the conduits, potential contaminants can travel much more rapidly than in the background aquifer (matrix). Since conduits cannot necessarily be regarded as a continuum, double continuum models are only of limited use for simulation of contaminant transport in such coupled groundwater-conduit systems. This study utilizes a "hybrid" flow and transport model in which contaminants can in essence be transported at a slower time scale in the matrix and at a faster time scale in the conduits. The hybrid flow model uses an approach developed by Clemens et al. (1996), which is based on the modelling of flow in a discrete pipe network, coupled to a continuum representing the low-permeability inter-conduit matrix blocks. Laminar or turbulent flow can be simulated in the different pipes depending on the flow conditions in the model domain. The three-dimensional finite-difference groundwater flow model MODFLOW (Harbaugh and McDonald, 1996) is used to simulate flow in the continuum. Contaminant transport within the matrix is simulated with a continuum approach using the three-dimensional multi-species solute transport model MT3DMS (Zheng and Wang, 1999), while that in the conduit system is simulated with a one-dimensional advective transport model. As a first step for reactive transport modeling in such systems, only equilibrium reactions among multiple species are considered by coupling the hybrid transport model to a geochemical speciation package. An idealized mine network developed by Viswanathan and Sauter (2001) is used as a test problem in this study. The numerical experiment is based on reference date collected from

  7. Data Validation Package, July 2016 Groundwater Sampling at the Shirley Basin South, Wyoming, Disposal Site November 2016

    Energy Technology Data Exchange (ETDEWEB)

    Frazier, William [USDOE Office of Legacy Management, Washington, DC (United States); Price, Jeffrey [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-11-01

    Sampling Period: July 14-15, 2016 The 2004 Long-Term Surveillance Plan for the Shirley Basin South (UMTRCA Title II) Disposal Site, Carbon County, Wyoming, requires annual monitoring to verify continued compliance with the pertinent alternate concentration limits (ACLs) and Wyoming Class III (livestock use) groundwater protection standards. Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. Point-of-compliance (POC) wells 19-DC, 5-DC, and 5-SC, and monitoring wells 10-DC, 110-DC, 112-DC, 113-DC, 40-SC, 54-SC, 100-SC, 102-SC, and K.G.S.#3 were sampled. POC well 51-SC and downgradient well 101-SC were dry at the time of sampling. The water level was measured at each sampled well. See Attachment 2, Trip Report for additional details. Sampling and analyses were conducted in accordance with the Sampling and Analysis Plan for the U S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated, http://energy.gov/lm/downloads/sampling-and­ analysis-plan-us-department-energy-office-legacy-management-sites). ACLs are approved for cadmium, chromium, lead, nickel, radium-226, radium-228, selenium, thorium-230, and uranium in site groundwater. Time-concentration graphs of the contaminants of concern in POC wells are included in Attachment 3, Data Presentation. The only ACL exceedance in a POC well was radium-228 in well 5-DC where the concentration was 30.7 picocuries per liter (pCi/L), exceeding the ACL of 25.7 pCi/L. Concentrations of sulfate and total dissolved solids continue to exceed their respective Wyoming Class III groundwater protection standards for livestock use in wells 5-DC, 5-SC, and 54-SC as they have done throughout the sampling history; however, there is no livestock use of the water from these aquifers at the site, and no constituent concentrations exceed groundwater protection standards at the wells near the site boundary.

  8. Do septic systems contribute micropollutants and their transformation products to shallow groundwater?

    Science.gov (United States)

    Septic systems may contribute micropollutants to shallow groundwater and surface water. We constructed two in situ conventional drainfields (drip dispersal and gravel trench) and an advanced drainfield of septic systems to investigate the fate and transport of micropollutants to shallow groundwater....

  9. Effects of climate change on coastal groundwater systems: A modeling study in the Netherlands

    NARCIS (Netherlands)

    Oude Essink, Gualbert; Van Baaren, Esther S.; De Louw, Perry G.B.

    2010-01-01

    Climate change in combination with increased anthropogenic activities will affect coastal groundwater systems throughout the world. In this paper, we focus on a coastal groundwater system that is already threatened by a relatively high seawater level: the low‐lying Dutch Delta. Nearly one third of

  10. Concentrations of hormones, pharmaceuticals and other micropollutants in groundwater affected by septic systems in New England and New York

    Science.gov (United States)

    Phillips, Patrick J.; Schubert, Christopher E.; Argue, Denise M.; Fisher, Irene J.; Furlong, Edward T.; Foreman, William T.; Gray, James L.; Chalmers, Ann T.

    2015-01-01

    Septic-system discharges can be an important source of micropollutants (including pharmaceuticals and endocrine active compounds) to adjacent groundwater and surface water systems. Groundwater samples were collected from well networks tapping glacial till in New England (NE) and sandy surficial aquifer New York (NY) during one sampling round in 2011. The NE network assesses the effect of a single large septic system that receives discharge from an extended health care facility for the elderly. The NY network assesses the effect of many small septic systems used seasonally on a densely populated portion of Fire Island. The data collected from these two networks indicate that hydrogeologic and demographic factors affect micropollutant concentrations in these systems.

  11. Data Validation Package October 2016 Groundwater and Surface Water Sampling at the Monticello, Utah, Disposal and Processing Sites January 2017

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Jason [USDOE Office of Legacy Management (LM), Washington, DC (United States); Smith, Fred [Navarro Research and Engineering, Inc., Grand Junction, CO (United States)

    2017-02-01

    Sampling Period: October 10–12, 2016. This semiannual event includes sampling groundwater and surface water at the Monticello Disposal and Processing Sites. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated) and Program Directive MNT-2016-01. Samples were collected from 54 of 64 planned locations (16 of 17 former mill site wells, 15 of 18 downgradient wells, 7 of 9 downgradient permeable reactive barrier wells, 3 of 3 bedrock wells, 4 of 7 seeps and wetlands, and 9 of 10 surface water locations).

  12. Advances in Dynamic Transport of Organic Contaminants in Karst Groundwater Systems

    Science.gov (United States)

    Padilla, I. Y.; Vesper, D.; Alshawabkeh, A.; Hellweger, F.

    2011-12-01

    Karst groundwater systems develop in soluble rocks such as limestone, and are characterized by high permeability and well-developed conduit porosity. These systems provide important freshwater resources for human consumption and ecological integrity of streams, wetlands, and coastal zones. The same characteristics that make karst aquifers highly productive make them highly vulnerable to contamination. As a result, karst aquifers serve as an important route for contaminants exposure to humans and wildlife. Transport of organic contaminants in karst ground-water occurs in complex pathways influenced by the flow mechanism predominating in the aquifer: conduit-flow dominated systems tend to convey solutes rapidly through the system to a discharge point without much attenuation; diffuse-flow systems, on the other hand, can cause significant solute retardation and slow movement. These two mechanisms represent end members of a wide spectrum of conditions found in karst areas, and often a combination of conduit- and diffuse-flow mechanisms is encountered, where both flow mechanisms can control the fate and transport of contaminants. This is the case in the carbonate aquifers of northern Puerto Rico. This work addresses advances made on the characterization of fate and transport processes in karst ground-water systems characterized by variable conduit and/or diffusion dominated flow under high- and low-flow conditions. It involves laboratory-scale physical modeling and field-scale sampling and historical analysis of contaminant distribution. Statistical analysis of solute transport in Geo-Hydrobed physical models shows the heterogeneous character of transport dynamics in karstic units, and its variability under different flow regimes. Field-work analysis of chlorinated volatile organic compounds and phthalates indicates a large capacity of the karst systems to store and transmit contaminants. This work is part of the program "Puerto Rico Testsite for Exploring Contamination

  13. Automated Monitoring System for Waste Disposal Sites and Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    S. E. Rawlinson

    2003-03-01

    A proposal submitted to the U.S. Department of Energy (DOE), Office of Science and Technology, Accelerated Site Technology Deployment (ASTD) program to deploy an automated monitoring system for waste disposal sites and groundwater, herein referred to as the ''Automated Monitoring System,'' was funded in fiscal year (FY) 2002. This two-year project included three parts: (1) deployment of cellular telephone modems on existing dataloggers, (2) development of a data management system, and (3) development of Internet accessibility. The proposed concept was initially (in FY 2002) to deploy cellular telephone modems on existing dataloggers and partially develop the data management system at the Nevada Test Site (NTS). This initial effort included both Bechtel Nevada (BN) and the Desert Research Institute (DRI). The following year (FY 2003), cellular modems were to be similarly deployed at Sandia National Laboratories (SNL) and Los Alamos National Laboratory (LANL), and the early data management system developed at the NTS was to be brought to those locations for site-specific development and use. Also in FY 2003, additional site-specific development of the complete system was to be conducted at the NTS. To complete the project, certain data, depending on site-specific conditions or restrictions involving distribution of data, were to made available through the Internet via the DRI/Western Region Climate Center (WRCC) WEABASE platform. If the complete project had been implemented, the system schematic would have looked like the figure on the following page.

  14. The Maryland Coastal Plain Aquifer Information System: A GIS-based tool for assessing groundwater resources

    Science.gov (United States)

    Andreasen, David C.; Nardi, Mark R.; Staley, Andrew W.; Achmad, Grufron; Grace, John W.

    2016-01-01

    Groundwater is the source of drinking water for ∼1.4 million people in the Coastal Plain Province of Maryland (USA). In addition, groundwater is essential for commercial, industrial, and agricultural uses. Approximately 0.757 × 109 L d–1 (200 million gallons/d) were withdrawn in 2010. As a result of decades of withdrawals from the coastal plain confined aquifers, groundwater levels have declined by as much as 70 m (230 ft) from estimated prepumping levels. Other issues posing challenges to long-term groundwater sustainability include degraded water quality from both man-made and natural sources, reduced stream base flow, land subsidence, and changing recharge patterns (drought) caused by climate change. In Maryland, groundwater supply is managed primarily by the Maryland Department of the Environment, which seeks to balance reasonable use of the resource with long-term sustainability. The chief goal of groundwater management in Maryland is to ensure safe and adequate supplies for all current and future users through the implementation of appropriate usage, planning, and conservation policies. To assist in that effort, the geographic information system (GIS)–based Maryland Coastal Plain Aquifer Information System was developed as a tool to help water managers access and visualize groundwater data for use in the evaluation of groundwater allocation and use permits. The system, contained within an ESRI ArcMap desktop environment, includes both interpreted and basic data for 16 aquifers and 14 confining units. Data map layers include aquifer and ­confining unit layer surfaces, aquifer extents, borehole information, hydraulic properties, time-series groundwater-level data, well records, and geophysical and lithologic logs. The aquifer and confining unit layer surfaces were generated specifically for the GIS system. The system also contains select groundwater-quality data and map layers that quantify groundwater and surface-water withdrawals. The aquifer

  15. Relation of streams, lakes, and wetlands to groundwater flow systems

    Science.gov (United States)

    Winter, Thomas C.

    Surface-water bodies are integral parts of groundwater flow systems. Groundwater interacts with surface water in nearly all landscapes, ranging from small streams, lakes, and wetlands in headwater areas to major river valleys and seacoasts. Although it generally is assumed that topographically high areas are groundwater recharge areas and topographically low areas are groundwater discharge areas, this is true primarily for regional flow systems. The superposition of local flow systems associated with surface-water bodies on this regional framework results in complex interactions between groundwater and surface water in all landscapes, regardless of regional topographic position. Hydrologic processes associated with the surface-water bodies themselves, such as seasonally high surface-water levels and evaporation and transpiration of groundwater from around the perimeter of surface-water bodies, are a major cause of the complex and seasonally dynamic groundwater flow fields associated with surface water. These processes have been documented at research sites in glacial, dune, coastal, mantled karst, and riverine terrains. Résumé Les eaux de surface sont parties intégrantes des systèmes aquifères. Les eaux souterraines interagissent avec les eaux de surface dans presque tous les types d'environnements, depuis les petits ruisseaux, les lacs et les zones humides jusqu'aux bassins versants des vallées des grands fleuves et aux lignes de côte. Il est en général admis que les zones topographiquement hautes sont des lieux de recharge des aquifères et les zones basses des lieux de décharge, ce qui est le cas des grands systèmes aquifères régionaux. La superposition de systèmes locaux, associés à des eaux de surface, à l'organisation régionale d'écoulements souterrains résulte d'interactions complexes entre les eaux souterraines et les eaux de surface dans tous les environnements, quelle que soit la situation topographique régionale. Les processus

  16. Development of dual-source hybrid heat pump system using groundwater and air

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Yujin; Ooka, Ryozo [Cw403 Institute of Industry Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan); Shiba, Yoshiro [Zeneral Heatpump Industry Co., Ltd., Nagoya 459-8001 (Japan)

    2010-06-15

    To achieve high heat pump efficiency, groundwater heat pump (GWHP) system uses groundwater, which is relatively stable AT temperature compared with outdoor air, as a heat source. However, it is difficult to meet annual heating and cooling loads using only groundwater as a heat source. In order to optimize the operation method of GWHP systems, it is necessary to develop a system utilizing both groundwater and air sources according to the building load conditions. Furthermore, during intermediate seasons (such as spring and autumn) with reduced heating and cooling loads, GWHP system is less efficient than air source heat pump (ASHP) system according to temperature conditions. In order to more efficiently use GWHP systems, it is necessary to develop a system which utilizes both groundwater and air sources according to temperature conditions and building loads. This research has developed a GWHP system that employs a hybrid heat pump system with groundwater wells using dual groundwater and air heat sources. In this paper, the annual performance of the developed system has been calculated, and several case studies have been conducted on the effect of introduction location, refrigerant and pumping rate. Furthermore, the coefficient of system performance and the effects on underground environments have been evaluated by real-scale experiment using two wells. (author)

  17. Handbook: Collecting Groundwater Samples from Monitoring Wells in Frenchman Flat, CAU 98

    Energy Technology Data Exchange (ETDEWEB)

    Chapman, Jenny [Desert Research Inst. (DRI), Reno, NV (United States); Lyles, Brad [Desert Research Inst. (DRI), Reno, NV (United States); Cooper, Clay [Desert Research Inst. (DRI), Reno, NV (United States); Hershey, Ron [Desert Research Inst. (DRI), Reno, NV (United States); Healey, John [Desert Research Inst. (DRI), Reno, NV (United States)

    2015-06-01

    Frenchman Flat basin on the Nevada National Security Site (NNSS) contains Corrective Action Unit (CAU) 98, which is comprised of ten underground nuclear test locations. Environmental management of these test locations is part of the Underground Test Area (UGTA) Activity conducted by the U.S. Department of Energy (DOE) under the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended) with the U.S. Department of Defense (DOD) and the State of Nevada. A Corrective Action Decision Document (CADD)/Corrective Action Plan (CAP) has been approved for CAU 98 (DOE, 2011). The CADD/CAP reports on the Corrective Action Investigation that was conducted for the CAU, which included characterization and modeling. It also presents the recommended corrective actions to address the objective of protecting human health and the environment. The recommended corrective action alternative is “Closure in Place with Modeling, Monitoring, and Institutional Controls.” The role of monitoring is to verify that Contaminants of Concern (COCs) have not exceeded the Safe Drinking Water Act (SDWA) limits (Code of Federal Regulations, 2014) at the regulatory boundary, to ensure that institutional controls are adequate, and to monitor for changed conditions that could affect the closure conditions. The long-term closure monitoring program will be planned and implemented as part of the Closure Report stage after activities specified in the CADD/CAP are complete. Groundwater at the NNSS has been monitored for decades through a variety of programs. Current activities were recently consolidated in an NNSS Integrated Sampling Plan (DOE, 2014). Although monitoring directed by the plan is not intended to meet the FFACO long-term monitoring requirements for a CAU (which will be defined in the Closure Report), the objective to ensure public health protection is similar. It is expected that data collected in accordance with the plan will support the transition to long-term monitoring at each

  18. Contamination of Groundwater Systems in the US and Canada by Enteric Pathogens, 1990–2013: A Review and Pooled-Analysis

    Science.gov (United States)

    Hynds, Paul Dylan; Thomas, M. Kate; Pintar, Katarina Dorothy Milena

    2014-01-01

    Background Up to 150 million North Americans currently use a groundwater system as their principal drinking water source. These systems are a potential source of exposure to enteric pathogens, contributing to the burden of waterborne disease. Waterborne disease outbreaks have been associated with US and Canadian groundwater systems over the past two decades. However, to date, this literature has not been reviewed in a comprehensive manner. Methods and Principal Findings A combined review and pooled-analysis approach was used to investigate groundwater contamination in Canada and the US from 1990 to 2013; fifty-five studies met eligibility criteria. Four study types were identified. It was found that study location affects study design, sample rate and studied pathogen category. Approximately 15% (316/2210) of samples from Canadian and US groundwater sources were positive for enteric pathogens, with no difference observed based on system type. Knowledge gaps exist, particularly in exposure assessment for attributing disease to groundwater supplies. Furthermore, there is a lack of consistency in risk factor reporting (local hydrogeology, well type, well use, etc). The widespread use of fecal indicator organisms in reported studies does not inform the assessment of human health risks associated with groundwater supplies. Conclusions This review illustrates how groundwater study design and location are critical for subsequent data interpretation and use. Knowledge gaps exist related to data on bacterial, viral and protozoan pathogen prevalence in Canadian and US groundwater systems, as well as a need for standardized approaches for reporting study design and results. Fecal indicators are examined as a surrogate for health risk assessments; caution is advised in their widespread use. Study findings may be useful during suspected waterborne outbreaks linked with a groundwater supply to identify the likely etiological agent and potential transport pathway. PMID:24806545

  19. A city scale study on the effects of intensive groundwater heat pump systems on heavy metal contents in groundwater.

    Science.gov (United States)

    García-Gil, Alejandro; Epting, Jannis; Garrido, Eduardo; Vázquez-Suñé, Enric; Lázaro, Jesús Mateo; Sánchez Navarro, José Ángel; Huggenberger, P; Calvo, Miguel Ángel Marazuela

    2016-12-01

    As a result of the increasing use of shallow geothermal resources, hydraulic, thermal and chemical impacts affecting groundwater quality can be observed with ever increasing frequency (Possemiers et al., 2014). To overcome the uncertainty associated with chemical impacts, a city scale study on the effects of intensive geothermal resource use by groundwater heat pump systems on groundwater quality, with special emphasis on heavy metal contents was performed. Statistical analysis of geochemical data obtained from several field campaigns has allowed studying the spatiotemporal relationship between temperature anomalies in the aquifer and trace element composition of groundwater. The relationship between temperature and the concentrations of trace elements resulted in weak correlations, indicating that temperature changes are not the driving factor in enhancing heavy metal contaminations. Regression models established for these correlations showed a very low reactivity or response of heavy metal contents to temperature changes. The change rates of heavy metal contents with respect to temperature changes obtained indicate a low risk of exceeding quality threshold values by means of the exploitation regimes used, neither producing nor enhancing contamination significantly. However, modification of pH, redox potential, electrical conductivity, dissolved oxygen and alkalinity correlated with the concentrations of heavy metals. In this case, the change rates of heavy metal contents are higher, with a greater risk of exceeding threshold values. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. Modelling groundwater systems: Understanding and improving groundwater quantity and quality management

    NARCIS (Netherlands)

    Ebrahim, G.Y.

    2013-01-01

    Groundwater is one of the most important natural resources. It is the principal source of drinking water in rural and many urban cities, and widely used for irrigation in most arid and semi-arid countries. However, recently it has become apparent that many human activities are negatively impacting b

  1. Documentation of a groundwater flow model developed to assess groundwater availability in the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to North Carolina

    Science.gov (United States)

    Masterson, John P.; Pope, Jason P.; Fienen, Michael N.; Monti, Jr., Jack; Nardi, Mark R.; Finkelstein, Jason S.

    2016-08-31

    The U.S. Geological Survey developed a groundwater flow model for the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to northeastern North Carolina as part of a detailed assessment of the groundwater availability of the area and included an evaluation of how these resources have changed over time from stresses related to human uses and climate trends. The assessment was necessary because of the substantial dependency on groundwater for agricultural, industrial, and municipal needs in this area.

  2. Development of a decision support system for groundwater pollution assessment

    NARCIS (Netherlands)

    Kukuric, N.

    1999-01-01

    Computers have become the main tooi used in groundwater management. Computer software has been developed for storage, processing and presentation of information on groundwater pollution problems. Continuing demands for more efficiënt handling of information have resulted in increasing integration of

  3. Pathogen transport in groundwater systems: contrasts with traditional solute transport

    Science.gov (United States)

    Hunt, Randall J.; Johnson, William P.

    2017-06-01

    Water quality affects many aspects of water availability, from precluding use to societal perceptions of fit-for-purpose. Pathogen source and transport processes are drivers of water quality because they have been responsible for numerous outbreaks resulting in large economic losses due to illness and, in some cases, loss of life. Outbreaks result from very small exposure (e.g., less than 20 viruses) from very strong sources (e.g., trillions of viruses shed by a single infected individual). Thus, unlike solute contaminants, an acute exposure to a very small amount of contaminated water can cause immediate adverse health effects. Similarly, pathogens are larger than solutes. Thus, interactions with surfaces and settling become important even as processes important for solutes such as diffusion become less important. These differences are articulated in "Colloid Filtration Theory", a separate branch of pore-scale transport. Consequently, understanding pathogen processes requires changes in how groundwater systems are typically characterized, where the focus is on the leading edges of plumes and preferential flow paths, even if such features move only a very small fraction of the aquifer flow. Moreover, the relatively short survival times of pathogens in the subsurface require greater attention to very fast (<10 year) flow paths. By better understanding the differences between pathogen and solute transport mechanisms discussed here, a more encompassing view of water quality and source water protection is attained. With this more holistic view and theoretical understanding, better evaluations can be made regarding drinking water vulnerability and the relation between groundwater and human health.

  4. Pathogen transport in groundwater systems: contrasts with traditional solute transport

    Science.gov (United States)

    Hunt, Randall J.; Johnson, William P.

    2016-12-01

    Water quality affects many aspects of water availability, from precluding use to societal perceptions of fit-for-purpose. Pathogen source and transport processes are drivers of water quality because they have been responsible for numerous outbreaks resulting in large economic losses due to illness and, in some cases, loss of life. Outbreaks result from very small exposure (e.g., less than 20 viruses) from very strong sources (e.g., trillions of viruses shed by a single infected individual). Thus, unlike solute contaminants, an acute exposure to a very small amount of contaminated water can cause immediate adverse health effects. Similarly, pathogens are larger than solutes. Thus, interactions with surfaces and settling become important even as processes important for solutes such as diffusion become less important. These differences are articulated in "Colloid Filtration Theory", a separate branch of pore-scale transport. Consequently, understanding pathogen processes requires changes in how groundwater systems are typically characterized, where the focus is on the leading edges of plumes and preferential flow paths, even if such features move only a very small fraction of the aquifer flow. Moreover, the relatively short survival times of pathogens in the subsurface require greater attention to very fast (<10 year) flow paths. By better understanding the differences between pathogen and solute transport mechanisms discussed here, a more encompassing view of water quality and source water protection is attained. With this more holistic view and theoretical understanding, better evaluations can be made regarding drinking water vulnerability and the relation between groundwater and human health.

  5. Groundwater impact on geothermal systems; Impacto del agua subterranea en los sistemas geotermicos

    Energy Technology Data Exchange (ETDEWEB)

    Katzenbach, R.; Wagner, I. M.

    2009-07-01

    Thermal behavior of geothermal systems is influenced by the presence and the velocity of the groundwater. The impact has to be accounted for during the dimensioning as well as during the construction. it is shown that the impact on the interference with neigh bored installation has to be controlled, especially in case of groundwater flow. (Author) 9 refs.

  6. Effects of a constructed wetland and pond system upon shallow groundwater quality

    Science.gov (United States)

    Ying Ouyang

    2013-01-01

    Constructed wetland (CW) and constructed pond (CP) are commonly utilized for removal of excess nutrients and certain pollutants from stormwater. This study characterized shallow groundwater quality for pre- and post-CW and CP system conditions using data from monitoring wells. Results showed that the average concentrations of groundwater phosphorus (P) decreased from...

  7. Geochemical impacts of groundwater heat pump systems in an urban alluvial aquifer with evaporitic bedrock

    Energy Technology Data Exchange (ETDEWEB)

    Garrido Schneider, Eduardo A. [Geological Survey of Spain (IGME), C/ Manuel Lasala no. 44, 9B, 50006 Zaragoza (Spain); García-Gil, Alejandro, E-mail: agargil@unizar.es [Department of Earth Sciences, University of Zaragoza, C/ Pedro Cerbuna 12, 50009 Zaragoza (Spain); GHS, Institute of Environmental Assessment & Water Research (IDAEA), CSIC, Jordi Girona 18–26, 08034 Barcelona (Spain); Vázquez-Suñè, Enric [GHS, Institute of Environmental Assessment & Water Research (IDAEA), CSIC, Jordi Girona 18–26, 08034 Barcelona (Spain); Sánchez-Navarro, José Á. [Department of Earth Sciences, University of Zaragoza, C/ Pedro Cerbuna 12, 50009 Zaragoza (Spain)

    2016-02-15

    In the last decade, there has been an extensive use of shallow geothermal exploitations in urban environments. Although the thermal interference between exploitations has been recently studied, there is a lack of knowledge regarding the geochemical impacts of those systems on the aquifers where they are installed. Groundwater flow line scale and well-doublet scale research work has been conducted at city scale to quantify the geochemical interaction of shallow geothermal exploitations with the environment. A comprehensive analysis was conducted on data obtained from a monitoring network specifically designed to control and develop aquifer policies related to thermal management of the aquifer. The geochemical impacts were evaluated from a thermodynamic point of view by means of saturation index (SI) calculations with respect to the different mineral species considered in the system. The results obtained indicate limited geochemical interaction with the urban environment in most of the situations. However, there are some cases where the interaction of the groundwater heat pump installations with the evaporitic bedrock resulted in the total disablement of the exploitation system operation wells. The application of the tool proposed proved to be pragmatic in the evaluation of geochemical impacts. Injection of water into the aquifer can trigger an important bedrock gypsum and halite dissolution process that is partly responsible for scaling in well casing pipes and collapse of the terrain in the vicinity of injection wells. - Highlights: • We studied geochemical impacts of groundwater heat pump systems. • We have sampled a monitoring network in an energetically exploited urban aquifer. • A limited geochemical interaction has been found in most of the exploitations. • Reinjection into the aquifer produces an important bedrock gypsum dissolution. • Scaling in well casing pipes and collapse of the terrain have been observed.

  8. Data Validation Package - April and July 2015 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing Site

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Joshua [Dept. of Energy (DOE), Washington, DC (United States). Office of Legacy Management; Campbell, Sam [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-02-01

    This event included annual sampling of groundwater and surface water locations at the Gunnison, Colorado, Processing Site. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites. Samples were collected from 28 monitoring wells, three domestic wells, and six surface locations in April at the processing site as specified in the 2010 Ground Water Compliance Action Plan for the Gunnison, Colorado, Processing Site. Domestic wells 0476 and 0477 were sampled in July because the homes were unoccupied in April, and the wells were not in use. Duplicate samples were collected from locations 0113, 0248, and 0477. One equipment blank was collected during this sampling event. Water levels were measured at all monitoring wells that were sampled. No issues were identified during the data validation process that requires additional action or follow-up.

  9. Badger Army Ammunition Plant groundwater data management system

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, J.P. [Olin Corp., Baraboo, WI (United States). Badger Army Ammunition Plant

    1994-12-31

    At the Badger Army Ammunition Plant (Badger), there are currently over 200 wells that are monitored on a quarterly basis. Badger has had three active production periods since its construction in 1942. During these periods, various nitrocellulose based propellants were produced including single base artillery propellants were produced including single base artillery propellant, double base rocket propellant and BALL POWDER{reg_sign} propellant. Intermediate materials used in the manufacture of these propellants were also produced, including nitroglycerine, and sulfuric and nitric acids. To meet the challenge of managing the data in-house, a groundwater data management system (GDMS) was developed. Although such systems are commercially available, they were not able to provide the specific capabilities necessary for data management and reporting at Badger. The GDMS not only provides the routine database capabilities of data sorts and queries, but has provided an automated data reporting system as well. The reporting function alone has significantly reduced the time and efforts that would normally be associated with this task. Since the GDMS was developed at Badger, the program can be continually adapted to site specific needs. Future planned modifications include automated reconciliation, improved transfer of data to graphics software, and statistical analysis and interpretation of the data.

  10. Investigation of total and hexavalent chromium in filtered and unfiltered groundwater samples at the Tucson International Airport Superfund Site

    Science.gov (United States)

    Tillman, Fred; McCleskey, R. Blaine; Hermosillo, Edyth

    2016-01-01

    Potential health effects from hexavalent chromium in groundwater have recently become a concern to regulators at the Tucson International Airport Area Superfund site. In 2016, the U.S. Geological Survey sampled 46 wells in the area to characterize the nature and extent of chromium in groundwater, to understand what proportion of total chromium is in the hexavalent state, and to determine if substantial differences are present between filtered and unfiltered chromium concentrations. Results indicate detectable chromium concentrations in all wells, over 75 % of total chromium is in the hexavalent state in a majority of wells, and filtered and unfiltered results differ substantially in only a few high-turbidity total chromium samples.

  11. Numerical modeling of geothermal groundwater flow in karst aquifer system in eastern Weibei, Shaanxi Province, China

    Institute of Scientific and Technical Information of China (English)

    LI Ming; LI GuoMin; YANG Liao; DANG XueYa; ZHAO ChunHu; HOU GuangCai; ZHANG MaoSheng

    2007-01-01

    The quantitative assessment of geothermal water resources is important to the exploitation and utilization of geothermal resources. In the geothermal water systems the density of groundwater changes with the temperature, therefore the variations in hydraulic heads and temperatures are very complicated. A three-dimensional density-dependent model coupling the groundwater flow and heat transport is established and used to simulate the geothermal water flow in the karst aquifers in eastern Weibei,Shaanxi Province, China. The multilayered karst aquifer system in the study area is cut by some major faults which control the regional groundwater flow. In order to calibrate and simulate the effect of the major faults, each fault is discretized as a belt of elements with special hydrological parameters in the numerical model. The groundwater dating data are used to be integrated with the groundwater flow pattern and calibrate the model. Simulation results show that the calculated hydraulic heads and temperature fit with the observed data well.

  12. Onsite wastewater system nitrogen contributions to groundwater in coastal North Carolina.

    Science.gov (United States)

    Humphrey, C P; O'Driscoll, M A; Deal, N E; Lindbo, D L; Thieme, S C; Zarate-Bermudez, M A

    2013-12-01

    The objective of the study described in this article was to evaluate the nitrogen contributions from two onsite wastewater systems (sites 1 and 2) to groundwater and adjacent surface waters in coastal Beaufort County, North Carolina. Groundwater levels and water quality parameters including total nitrogen, nitrogen species, temperature, and pH were monitored from October 2009 to May 2010. Nitrogen was also tested in groundwater from deeper irrigation or drinking water wells from the two sites and six additional neighboring residences. Mean total nitrogen concentrations in groundwater beneath onsite wastewater systems 1 and 2 were 34.3 +/- 16.7 mg/L and 12.2 +/- 2.9 mg/L, respectively, and significantly higher than background groundwater concentrations (Groundwater in the deeper wells appeared not to be influenced by the onsite systems. Groundwater nitrogen concentrations typically decreased with distance down-gradient from the systems, but were still elevated relative to background conditions more than 15 m from the systems and near the estuary. This was a pioneering effort to better understand the link of onsite systems, the fate of nitrogen in the environment, and public health.

  13. Boundary of the area contributing flow to the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the boundary of the area contributing ground-water flow to the Death Valley regional ground-water flow-system (DVRFS) model domain. The...

  14. Boundary of the area contributing flow to the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the boundary of the area contributing ground-water flow to the Death Valley regional ground-water flow-system (DVRFS) model domain....

  15. Sustainable groundwater management system based on the regional hydrological cycle in the warm humid country, Japan

    Science.gov (United States)

    Shimada, J.; Crest Kumamoto Groundwater Team

    2011-12-01

    The increase of precipitation variability with the global warming and the rapid population growth lead to the shortage of water resources on a global scale. Groundwater bocome attracted as a relatively stable water resource because of its larger reservoir and a longer residence time. As our country belongs to a warm humid climate with much precipitation and a steep topography, the regional hydrological cycle is extremely active. Surface water could be taken easily and was often used to a water supply until now, but recently groundwater is taking the place of surface water because of the stability of water supply. While in our hydro-climatic condition, the sustainable use of groundwater is possible under the appropriative management, that is, groundwater pumping rate does not exceed the recharge rate in a basin. For the sustainable use of groundwater resources, this project aims to develop new technologies relating to the quantity and quality aspects of groundwater resources. For the precise understanding of groundwater flow system, new technologies will be developed, like frequency changeable electric resistivity exploration method to evaluate an aquifer structure. There are many problems about groundwater quality including nitrate-nitrogen contamination and toxic substances from the domestic and industrial waste disposals. It is necessary to understand the production mechanism to prevent groundwater contamination and the degradation process of nitrate-nitrogen contamination to improve the water quality. Therefore this project will develop new technologies including the reduction of NO3=N and natural toxic substances loads before groundwater recharge, the on-site removal of contaminants from aquifers, and simple and effective equipment to improve groundwater quality after pumping. Furthermore, this project will also develop a new biological monitoring technique for local groundwater users to notice the contamination at a glance; change colar fish by specific ion

  16. Scaling of flow and transport behavior in heterogeneous groundwater systems

    Science.gov (United States)

    Scheibe, Timothy; Yabusaki, Steven

    1998-11-01

    Three-dimensional numerical simulations using a detailed synthetic hydraulic conductivity field developed from geological considerations provide insight into the scaling of subsurface flow and transport processes. Flow and advective transport in the highly resolved heterogeneous field were modeled using massively parallel computers, providing a realistic baseline for evaluation of the impacts of parameter scaling. Upscaling of hydraulic conductivity was performed at a variety of scales using a flexible power law averaging technique. A series of tests were performed to determine the effects of varying the scaling exponent on a number of metrics of flow and transport behavior. Flow and transport simulation on high-performance computers and three-dimensional scientific visualization combine to form a powerful tool for gaining insight into the behavior of complex heterogeneous systems. Many quantitative groundwater models utilize upscaled hydraulic conductivity parameters, either implicitly or explicitly. These parameters are designed to reproduce the bulk flow characteristics at the grid or field scale while not requiring detailed quantification of local-scale conductivity variations. An example from applied groundwater modeling is the common practice of calibrating grid-scale model hydraulic conductivity or transmissivity parameters so as to approximate observed hydraulic head and boundary flux values. Such parameterizations, perhaps with a bulk dispersivity imposed, are then sometimes used to predict transport of reactive or non-reactive solutes. However, this work demonstrates that those parameters that lead to the best upscaling for hydraulic conductivity and head do not necessarily correspond to the best upscaling for prediction of a variety of transport behaviors. This result reflects the fact that transport is strongly impacted by the existence and connectedness of extreme-valued hydraulic conductivities, in contrast to bulk flow which depends more strongly on

  17. Nitrate removal from groundwater driven by electricity generation and heterotrophic denitrification in a bioelectrochemical system.

    Science.gov (United States)

    Tong, Yiran; He, Zhen

    2013-11-15

    This research aims to develop a new approach for in situ nitrate removal from groundwater by using a bioelectrochemical system (BES). The BES employs bioelectricity generated from organic compounds to drive nitrate moving from groundwater into the anode and reduces nitrate to nitrogen gas by heterotrophic denitrification. This laboratory study of a bench-scale BES demonstrated effective nitrate removal from both synthetic and actual groundwater. It was found that applying an electrical potential improved the nitrate removal and the highest nitrate removal rate of 208.2 ± 13.3g NO3(-)-Nm(-3) d(-1) was achieved at 0.8 V. Although the open circuit condition (no electricity generation) still resulted in a nitrate removal rate of 158.5 ± 4.2 gm(-3) d(-1) due to ion exchange, electricity production could inhibit ion exchange and prevent introducing other undesired ions into groundwater. The nitrate removal rate exhibited a linear relationship with the initial nitrate concentration in groundwater. The BES produced a higher current density of 33.4 Am(-3) and a higher total coulomb of 244.7 ± 9.1C from the actual groundwater than the synthetic groundwater, likely because other ions in the actual groundwater promoted ion movement to assist electricity generation. Further development of this BES will need to address several key challenges in anode feeding solution, ion competition, and long-term stability.

  18. Net infiltration of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Recharge in the Death Valley regional ground-water flow system (DVRFS) was estimated from net infiltration simulated by Hevesi and others (2003) using a...

  19. Examining the impacts of increased corn production on groundwater quality using a coupled modeling system

    Science.gov (United States)

    This study demonstrates the value of a coupled chemical transport modeling system for investigating groundwater nitrate contamination responses associated with nitrogen (N) fertilizer application and increased corn production. The coupled Community Multiscale Air Quality Bidirect...

  20. Hydrogeologic map of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital dataset represents the surface hydrogeology of an approximately 45,000 square-kilometer area of the Death Valley regional ground-water flow system...

  1. Study area boundary for the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents the Death Valley regional ground-water flow system (DVRFS) study area which encompasses approximately 100,000-square kilometers in...

  2. Groundwater Discharge Area for the Diamond Valley Flow System, Central Nevada

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These data were created as part of a hydrologic study to characterize groundwater budgets and water quality in the Diamond Valley Flow System (DVFS), central Nevada....

  3. Water Well Locations - MO 2010 Public Water System Wells 20 Year Groundwater Distance (SHP)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This shapefile represents the estimated distance groundwater around some public water system (PWS) wells will travel in a twenty-year period. See process description.

  4. Study area boundary for the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents the Death Valley regional ground-water flow system (DVRFS) study area which encompasses approximately 100,000-square kilometers in...

  5. Evapotranspiration Units for the Diamond Valley Flow System Groundwater Discharge Area, Central Nevada, 2010

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These data were created as part of a hydrologic study to characterize groundwater budgets and water quality in the Diamond Valley Flow System (DVFS), central Nevada....

  6. Simulation of the Groundwater-Flow System in Pierce, Polk, and St. Croix Counties, Wisconsin

    Science.gov (United States)

    Juckem, Paul F.

    2009-01-01

    Groundwater is the sole source of residential water supply in Pierce, Polk, and St. Croix Counties, Wisconsin. A regional three-dimensional groundwater-flow model and three associated demonstration inset models were developed to simulate the groundwater-flow systems in the three-county area. The models were developed by the U.S. Geological Survey in cooperation with the three county governments. The objectives of the regional model of Pierce, Polk, and St. Croix Counties were to improve understanding of the groundwaterflow system and to develop a tool suitable for evaluating the effects of potential water-management programs. The regional groundwater-flow model described in this report simulates the major hydrogeologic features of the modeled area, including bedrock and surficial aquifers, groundwater/surface-water interactions, and groundwater withdrawals from high-capacity wells. Results from the regional model indicate that about 82 percent of groundwater in the three counties is from recharge within the counties; 15 percent is from surface-water sources, consisting primarily of recirculated groundwater seepage in areas with abrupt surface-water-level changes, such as near waterfalls, dams, and the downgradient side of reservoirs and lakes; and 4 percent is from inflow across the county boundaries. Groundwater flow out of the counties is to streams (85 percent), outflow across county boundaries (14 percent), and pumping wells (1 percent). These results demonstrate that the primary source of groundwater withdrawn by pumping wells is water that recharges within the counties and would otherwise discharge to local streams and lakes. Under current conditions, the St. Croix and Mississippi Rivers are groundwater discharge locations (gaining reaches) and appear to function as 'fully penetrating' hydraulic boundaries such that groundwater does not cross between Wisconsin and Minnesota beneath them. Being hydraulic boundaries, however, they can change in response to

  7. Potential groundwater sampling sites for installation of a well network for long-term monitoring of agricultural chemicals in the High Plains Aquifer, Colorado

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These data are in support of report DS 456 (Arnold and others, 2009). This dataset includes 90 potential groundwater sampling sites randomly generated using...

  8. Evaluation of groundwater chemistry and its impact on drinking and irrigation water quality in the eastern part of the Central Arabian graben and trough system, Saudi Arabia

    Science.gov (United States)

    Zaidi, Faisal K.; Mogren, Saad; Mukhopadhyay, Manoj; Ibrahim, Elkhedr

    2016-08-01

    The present study deals with the assessment of groundwater with respect to the main hydrological processes controlling its chemistry and its subsequent impact on groundwater quality for drinking and irrigation purposes in the eastern part of the Central Arabian graben and trough system. Groundwater samples were collected from 73 bore wells tapping the Cretaceous Biyadh and Wasia sandstone aquifers. The main groundwater facies in the area belong to the mixed Casbnd Mgsbnd SO4/Cl type and the SO4sbnd Cl type. Prolonged rock water interaction has resulted in high TDS (average of 2131 mg/l) and high EC (average of 2725 μS/cm) of the groundwater. The average nitrate (56.38 mg/l) value in the area is higher than the WHO prescribed limits of 50 mg/l in drinking water and is attributed to agricultural activities. The Drinking Water Quality Index (DWQI) shows that 33% of the water samples fall within the excellent to good category whereas the remaining samples fall in the poor to unsuitable for drinking category. In terms of Sodium Adsorption Ratio (SAR), Sodium percentage (Na %) and Residual Sodium Carbonate (RSC) the groundwater is suitable for irrigation however the high salinity values can adversely affect the plant physiology.

  9. Evaluation of the quality of groundwater sampling: Experience derived from radioactive waste disposal programmes in Sweden and Finland during 1980-1992

    Energy Technology Data Exchange (ETDEWEB)

    Smellie, J.A.T. [Conterra AB, Uppsala (Sweden); Laaksoharju, M. [Intera, Solletuna (Sweden); Snellman, M.V. [Posiva Oy, Helsinki (Finland); Ruotsalainen, P.H. [Fintact Oy, (Finland)

    1999-09-01

    Existing Finnish and Swedish hydrogeochemical field data from the 1980s and the early 1990s have been closely examined in the light of other influencing activities, such as geology and hydrology, which form an integral part of site-specific investigations. The report has considered data relating to the monitoring of groundwater chemical trends and groundwater sampling and analysis. These data have been used to simulate the effects of important parameters on groundwater quality and representativeness, to generate recommendations to improve the standard of hydrogeochemical sampling and analyses, and to discuss these results in the broader context of future site-specific investigations. (orig.)

  10. Data Validation Package April 2016 Groundwater and Surface Water Sampling at the Monticello, Utah, Disposal and Processing Sites August 2016

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Jason [USDOE Office of Legacy Management, Washington, DC (United States); Smith, Fred [Navarro Research and Engineering, Oak Ridge, TN (United States)

    2016-08-01

    This semiannual event includes sampling groundwater and surface water at the Monticello Disposal and Processing Sites. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated) and Program Directive MNT-2016-01. Complete sample sets were collected from 42 of 48 planned locations (9 of 9 former mill site wells, 13 of 13 downgradient wells, 7 of 9 downgradient permeable reactive barrier wells, 4 of 7 seeps and wetlands, and 9 of 10 surface water locations). Planned monitoring locations are shown in Attachment 1, Sampling and Analysis Work Order. Locations R6-M3, SW00-01, Seep 1, Seep 2, and Seep 5 were not sampled due to insufficient water availability. A partial sample was collected at location R4-M3 due to insufficient water. All samples from the permeable reactive barrier wells were filtered as specified in the program directive. Duplicate samples were collected from surface water location Sorenson and from monitoring wells 92-07 and RlO-Ml. Water levels were measured at all sampled wells and an additional set of wells. See Attachment2, Trip Report for additional details. The contaminants of concern (COCs) for the Monticello sites are arsenic, manganese, molybdenum, nitrate+ nitrite as nitrogen (nitrate+ nitrite as N), selenium, uranium, and vanadium. Locations with COCs that exceeded remediation goals are listed in Table 1 and Table 2. Time-concentration graphs of the COCs for all groundwater and surface water locations are included in Attachment 3, Data Presentation. An assessment of anomalous data is included in Attachment 4.

  11. A GIS-Enabled, Michigan-Specific, Hierarchical Groundwater Modeling and Visualization System

    Science.gov (United States)

    Liu, Q.; Li, S.; Mandle, R.; Simard, A.; Fisher, B.; Brown, E.; Ross, S.

    2005-12-01

    Efficient management of groundwater resources relies on a comprehensive database that represents the characteristics of the natural groundwater system as well as analysis and modeling tools to describe the impacts of decision alternatives. Many agencies in Michigan have spent several years compiling expensive and comprehensive surface water and groundwater inventories and other related spatial data that describe their respective areas of responsibility. However, most often this wealth of descriptive data has only been utilized for basic mapping purposes. The benefits from analyzing these data, using GIS analysis functions or externally developed analysis models or programs, has yet to be systematically realized. In this talk, we present a comprehensive software environment that allows Michigan groundwater resources managers and frontline professionals to make more effective use of the available data and improve their ability to manage and protect groundwater resources, address potential conflicts, design cleanup schemes, and prioritize investigation activities. In particular, we take advantage of the Interactive Ground Water (IGW) modeling system and convert it to a customized software environment specifically for analyzing, modeling, and visualizing the Michigan statewide groundwater database. The resulting Michigan IGW modeling system (IGW-M) is completely window-based, fully interactive, and seamlessly integrated with a GIS mapping engine. The system operates in real-time (on the fly) providing dynamic, hierarchical mapping, modeling, spatial analysis, and visualization. Specifically, IGW-M allows water resources and environmental professionals in Michigan to: * Access and utilize the extensive data from the statewide groundwater database, interactively manipulate GIS objects, and display and query the associated data and attributes; * Analyze and model the statewide groundwater database, interactively convert GIS objects into numerical model features

  12. Conceptual model and numerical simulation of the groundwater-flow system of Bainbridge Island, Washington

    Science.gov (United States)

    Frans, Lonna M.; Bachmann, Matthew P.; Sumioka, Steve S.; Olsen, Theresa D.

    2011-01-01

    Groundwater is the sole source of drinking water for the population of Bainbridge Island. Increased use of groundwater supplies on Bainbridge Island as the population has grown over time has created concern about the quantity of water available and whether saltwater intrusion will occur as groundwater usage increases. A groundwater-flow model was developed to aid in the understanding of the groundwater system and the effects of groundwater development alternatives on the water resources of Bainbridge Island. Bainbridge Island is underlain by unconsolidated deposits of glacial and nonglacial origin. The surficial geologic units and the deposits at depth were differentiated into aquifers and confining units on the basis of areal extent and general water-bearing characteristics. Eleven principal hydrogeologic units are recognized in the study area and form the basis of the groundwater-flow model. A transient variable-density groundwater-flow model of Bainbridge Island and the surrounding area was developed to simulate current (2008) groundwater conditions. The model was calibrated to water levels measured during 2007 and 2008 using parameter estimation (PEST) to minimize the weighted differences or residuals between simulated and measured hydraulic head. The calibrated model was used to make some general observations of the groundwater system in 2008. Total flow through the groundwater system was about 31,000 acre-ft/ yr. The recharge to the groundwater system was from precipitation and septic-system returns. Groundwater flow to Bainbridge Island accounted for about 1,000 acre-ft/ yr or slightly more than 5 percent of the recharge amounts. Groundwater discharge was predominately to streams, lakes, springs, and seepage faces (16,000 acre-ft/yr) and directly to marine waters (10,000 acre-ft/yr). Total groundwater withdrawals in 2008 were slightly more than 6 percent (2,000 acre-ft/yr) of the total flow. The calibrated model was used to simulate predevelopment conditions

  13. Sampling-interval-dependent stability for linear sampled-data systems with non-uniform sampling

    Science.gov (United States)

    Shao, Hanyong; Lam, James; Feng, Zhiguang

    2016-09-01

    This paper is concerned with the sampling-interval-dependent stability of linear sampled-data systems with non-uniform sampling. A new Lyapunov-like functional is constructed to derive sampling-interval-dependent stability results. The Lyapunov-like functional has three features. First, it depends on time explicitly. Second, it may be discontinuous at the sampling instants. Third, it is not required to be positive definite between sampling instants. Moreover, the new Lyapunov-like functional can make use of the information fully of the sampled-data system, including that of both ends of the sampling interval. By making a new proposition for the Lyapunov-like functional, a sampling-interval-dependent stability criterion with reduced conservatism is derived. The new sampling-interval-dependent stability criterion is further extended to linear sampled-data systems with polytopic uncertainties. Finally, examples are given to illustrate the reduced conservatism of the stability criteria.

  14. Data Validation Package October 2015 Groundwater and Surface Water Sampling at the Monticello, Utah, Processing Site January 2016

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Jason [U.S. Dept. of Energy, Washington, DC (United States). Office of Legacy Management; Smith, Fred [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-01-21

    Sampling Period: October 12–14, 2015. This semiannual event includes sampling groundwater and surface water at the Monticello Mill Tailings Site. Sampling and analyses were conducted as specified in the 2004 Monticello Mill Tailings Site Operable Unit III Post-Record of Decision Monitoring Plan, Draft Final and Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). Samples were collected from 52 of 61 planned locations (15 of 17 former mill site wells, 17 of 18 downgradient wells, 9 of 9 downgradient permeable reactive barrier wells, 2 of 7 seeps and wetlands, and 9 of 10 surface water locations). Locations MW00-07, Seep 1, Seep 2, Seep 3, Seep 5, Seep 6, SW00-01, T01-13, and T01-19 were not sampled because of insufficient water availability. All samples were filtered as specified in the monitoring plan. Duplicate samples were collected from surface water location W3-04 and from monitoring wells 82-08, 92-09, and 92-10. Water levels were measured at all but one sampled well and an additional set of wells. The contaminants of concern (COCs) for the Monticello Mill Tailings Site are arsenic, manganese, molybdenum, nitrate + nitrite as nitrogen (nitrate + nitrite as N), selenium, uranium, and vanadium. Time-concentration graphs of the COCs for all groundwater and surface water locations are included in this report. Locations with COCs that exceeded remediation goals are listed.

  15. Water sample-collection and distribution system

    Science.gov (United States)

    Brooks, R. R.

    1978-01-01

    Collection and distribution system samples water from six designated stations, filtered if desired, and delivers it to various analytical sensors. System may be controlled by Water Monitoring Data Acquisition System or operated manually.

  16. Complex groundwater flow systems as traveling agent models

    CERN Document Server

    López-Corona, Oliver; Escolero, Oscar; González, Tomás; Morales-Casique, Eric

    2014-01-01

    Analyzing field data from pumping tests, we show that as with many other natural phenomena, groundwater flow exhibits a complex dynamics described by 1/f power spectrum. This result is theoretically studied within an agent perspective. Using a traveling agent model, we prove that this statistical behavior emerges when the medium is complex. Some heuristic reasoning is provided to justify both spatial and dynamic complexity, as the result of the superposition of an infinite number of stochastic processes. Even more, we show that this implies that non-Kolmogorovian probability is needed for its study, and provide a set of new partial differential equations for groundwater flow.

  17. Distribution of 36Cl in the Yoro River Basin, Central Japan, and Its Relation to the Residence Time of the Regional Groundwater Flow System

    Directory of Open Access Journals (Sweden)

    Akihiko Kondoh

    2011-01-01

    Full Text Available This study investigates the potential of 36Cl in tracing young groundwater with residence times of up to ~50 years. Groundwater samples were obtained from 16 irrigation wells in paddy fields located within an upland–lowland system in the Yoro River basin, Central Japan. The 36Cl/Cl ratios were in the range of 17 to 362 × 10−15. Among the samples with higher Cl− concentrations (>10 mg/L, two samples showed high nitrate concentrations as well (>30 mg/L. Except for these samples, the distribution of 36Cl in groundwater was essentially consistent with previous tritium concentration data measured in 1982 and 1994, considering the time that has elapsed since these earlier measurements were performed. 36Cl/Cl values were less than 30 × 10−15 in lowland areas, with higher values in and around upland areas. The results indicate longer residence times in the regional groundwater flow system (>50 years than those estimated in previous studies, especially in the area west of the Yoro River. The results demonstrate the ability of 36Cl to trace young groundwater flow, particularly because high values of bomb-derived 36Cl/Cl are easily discriminated from pre-bomb water with low 36Cl/Cl values. Because of its very long half-life (3.01 × 105 years, 36Cl remains even after tritium is no longer available.

  18. Climate impact on groundwater systems: the past is the key to the future

    Science.gov (United States)

    van der Ploeg, Martine; Cendón, Dioni; Haldorsen, Sylvi; Chen, Jinyao; Gurdak, Jason; Tujchneider, Ofelia; Vaikmäe, Rein; Purtschert, Roland; Chkir Ben Jemâa, Najiba

    2013-04-01

    Groundwater is a significant part of the global hydrological cycle and supplies fresh drinking water to almost half of the world's population. While groundwater supplies are buffered against short-term effects of climate variability, they can be impacted over longer time scales through changes in precipitation, ,evaporation, recharge rate, melting of glaciers or permafrost, vegetation, and land-use. Moreover, uncontrolled groundwater extraction has and will lead to irreversible depletion of fresh water resources in many areas. The impact of climate variability and groundwater extraction on the resilience of groundwater systems is still not fully understood (Green et al. 2011). Groundwater stores environmental and climatic information acquired during the recharge process, which integrates different signals, like recharge temperature, origin of precipitation, and dissolved constituents. This information can be used to estimate palaeo recharge temperatures, palaeo atmospheric dynamics and residence time of groundwater within the aquifer (Stute et al. 1995, Clark and Fritz 1997, Collon et al. 2000, Edmunds et al. 2003, Cartwright et al. 2007, Kreuzer et al. 2009, Currell et al. 2010, Raidla et al. 2012, Salem et al. 2012). The climatic signals incorporated by groundwater during recharge have the potential to provide a regionally integrated proxy of climatic variations at the time of recharge. Groundwater palaeoclimate information is affected by diffusion-dispersion processes (Davison and Airey, 1982) and/or water-rock interaction (Clark and Fritz, 1997), making palaeoclimate information deduced from groundwater inherently a low resolution record. While the signal resolution can be limited, recharge follows major climatic events, and more importantly, shows how those aquifers and their associated recharge varies under climatic forcing. While the characterization of groundwater resources, surface-groundwater interactions and their link to the global water cycle are an

  19. Horizontal flow barriers for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital dataset defines the surface traces of regional features simulated as horizontal flow barriers in the Death Valley regional ground-water flow system...

  20. Altitudes of the top of model layers for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the altitudes of the tops of 16 model layers simulated in the Death Valley regional ground-water flow system (DVRFS) transient flow...

  1. Horizontal flow barriers for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital dataset defines the surface traces of regional features simulated as horizontal flow barriers in the Death Valley regional ground-water flow system...

  2. [Study on geochemical susceptivity of groundwater system in representative karstic regions].

    Science.gov (United States)

    He, Shou-yang; Zhu, Li-jun; Dong, Zhi-fen; Zhang, Yi; Yu, Xiao-hong

    2010-05-01

    We investigated geochemical susceptivity of groundwater in representative karst groundwater system. The results indicated that Ca2+ and Mg2+, correlative the average values of geochemical susceptivity index (GSI) were 0.73 and 0.19; HCO3- and SO4(2-), interrelated the average values of geochemical susceptivity index were 0.92 and 0.37, are the principal cations and anions in karstic groundwater system, respectively. And the major elements are obviously characterized by the geochemical susceptivity. The rank order of geochemical susceptivity for major elements in study region is HCO3- > Ca2+ > SO4(2+) > Mg2+ > Cl- > Na+ > NO3- > K+. The susceptive regions of groundwater system were zoned by the geochemical susceptivity index of HCO3- (GSI(HCO3-)), which classified as GSI(HCO3-) 1 is high-susceptivity zone, respectively. The groundwater systems in high-susceptivity zone may become as a collected and genetic room for pollutants. Furthermore, both continual or active exchange and mutual recharge between surface water and groundwater in high-susceptivity zones might induce intersectant pollution and serious cycle.

  3. Multimedia Environmental Pollutant Assessment System (MEPAS{reg_sign}): Groundwater pathway formulations

    Energy Technology Data Exchange (ETDEWEB)

    Whelan, G.; McDonald, J.P. [Pacific Northwest National Lab., Richland, WA (United States); Sato, C. [Idaho State Univ., Pocatello, ID (United States)

    1996-06-01

    This report describes the mathematical formulations used for contaminant fate and transport in the groundwater pathway of the Multimedia Environmental Pollutant Assessment System (MEPAS). It is one in a series of reports that collectively describe the components of MEPAS. The groundwater component of the MEPAS methodology models solute transport through the groundwater environment (i.e., partially saturated and saturated zones). Specifically, this component provides estimates of groundwater contaminant fluxes at various transporting medium interfaces (e.g., water table or aquifer/river interface) and contaminant concentrations at withdrawal wells. Contaminant fluxes at transporting medium interfaces represent boundary conditions for the next medium in which contaminant migration and fate is to be simulated (e.g., groundwater contamination entering a surface-water environment). Contaminant concentrations at withdrawal wells provide contaminant levels for the exposure assessment component of MEPAS. A schematic diagram illustrating the groundwater environment is presented. The migration and fate of contaminants through the groundwater environment are described by the three-dimensional, advective-dispersive equation for solute transport. The results are based on semianalytical solutions (i.e., solutions that require numerical integration) that are well established in the scientific literature. To increase computational efficiency, limits of integration are also identified.

  4. Extreme Environment Sampling System Deployment Mechanism Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Future Venus or Comet mission architectures may feature robotic sampling systems comprised of a Sampling Tool and Deployment Mechanism. Since 2005, Honeybee has been...

  5. Data Validation Package May and June 2015 Groundwater and Surface Water Sampling at the Bluewater, New Mexico, Disposal Site, August 2015

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Dick [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States); Tsosie, Bernadette [US Department of Energy, Washington, DC (United States)

    2015-08-01

    Groundwater samples were collected from monitoring wells at the Bluewater, New Mexico, Disposal Site to monitor groundwater contaminants as specified in the 1997 Long-Term Surveillance Plan for the DOE Bluewater (UMTRCA Title II) Disposal Site Near Grants, New Mexico (LTSP). Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). Duplicate samples were collected from locations 14(SG) and 21(M). Sampling originally scheduled for the week of May 11, 2015 was interrupted by heavy rainfall and later completed in June.

  6. A multitracer approach for characterizing interactions between shallow groundwater and the hydrothermal system in the Norris Geyser Basin area, Yellowstone National Park

    Science.gov (United States)

    Gardner, W.P.; Susong, D.D.; Solomon, D.K.; Heasler, H.P.

    2011-01-01

    Multiple environmental tracers are used to investigate age distribution, evolution, and mixing in local- to regional-scale groundwater circulation around the Norris Geyser Basin area in Yellowstone National Park. Springs ranging in temperature from 3??C to 90??C in the Norris Geyser Basin area were sampled for stable isotopes of hydrogen and oxygen, major and minor element chemistry, dissolved chlorofluorocarbons, and tritium. Groundwater near Norris Geyser Basin is comprised of two distinct systems: a shallow, cool water system and a deep, high-temperature hydrothermal system. These two end-member systems mix to create springs with intermediate temperature and composition. Using multiple tracers from a large number of springs, it is possible constrain the distribution of possible flow paths and refine conceptual models of groundwater circulation in and around a large, complex hydrothermal system. Copyright 2011 by the American Geophysical Union.

  7. Management of the Arsenic Groundwater System Lagunera - MEXICO

    Science.gov (United States)

    Boochs, P. W.; Billib, M.; Aparicio, J.; Gutierrez, C.

    2007-05-01

    Arsenic in drinking water is considered one of the most important environmental causes of cancer mortality in the world. Groundwater resources of the Comarca Lagunera region (Northern Mexico), which represents the main source of drinking water for more than 2 million people in the area, show arsenic concentrations ranging from 5 to 750 micro g/l. Large areas have concentrations quite above the Mexican standard of 25 micro g/l for human use and consumption. The aquifer is overexploited and the groundwater levels at the central part of the aquifer are drawn down more than 100 m in less than 50 years. The drawdown provoked the dissolution and migration of the geogenic existing arsenic within the aquifer. The presence of arsenic has been related to several potential sources. It was found out, that the main source is geothermal activity, less mining and the use of arsenical pesticides. The process of the geneses of the arsenic pollution implicates, that the highest content is on the bottom of the aquifer. Data analysis showed, that arsenic concentration is correlated to the age of the groundwater. "Older" water has higher arsenic content than "younger" water and the oldest water can be found at the bottom of the aquifer. Before 1950 the groundwater level in the Comarca Lagunera was close to the surface and there were only dug and shallow wells with low groundwater abstraction. The water was pumped from the upper parts of the aquifer and because this was "young" water it had low arsenic content. Then after 1950 a lot of wells, mainly for irrigation, were built and in 2002 there were 2350 active wells with an abstraction of about 1088 Mio cbm/year. In consequence to this the groundwater level decreased extraordinary. More and more "older" water was pumped and the arsenic content increased. Furthermore at the beginning of 1960 the river Nazas was canalized and lined, so that the natural groundwater recharge by infiltration from the river was stopped. By this way, the

  8. Is artificial recharge promoting microbial activity and biodegradation processes in groundwater systems?

    Science.gov (United States)

    Barba Ferrer, Carme; Folch, Albert; Gaju, Núria; Martínez-Alonso, Maira; Carrasquilla, Marc; Grau-Martínez, Alba; Sanchez-Vila, Xavier

    2016-04-01

    Managed Artificial Recharge (MAR) represents a strategic tool for managing water resources, especially during scarce periods. On one hand, it can increase water stored in aquifers and extract it when weather conditions do not permit exclusive exploitation of surface resources. On the other, it allows improve water quality due the processes occurring into the soil whereas water crosses vadose zone. Barcelona (Catalonia, Spain) conurbation is suffering significant quantitative and qualitative groundwater disturbances. For this reason, Sant Vicenç MAR system, constituted by a sedimentation and an infiltration pond, was constructed in 2009 as the strategic water management infrastructure. Compared with other MAR facilities, this infiltration pond has a reactive bed formed by organic compost and local material. The objective is to promote different redox states allowing more and different degradation of chemical compounds than regular MAR systems. In previous studies in the site, physical and hydrochemical parameters demonstrated that there was indeed a degradation of different pollutants. However, to go a step further understanding the different biogeochemical processes and the related degradation processes occurring in the system, we studied the existing microbial communities. So, molecular techniques were applied in water and soil samples in two different scenarios; the first one, when the system was fully operating and the second when the system was not operating during some months. We have specifically compared microbial diversity and richness indexes and both cluster dendrograms obtained from DGGEs analysis made in each sampling campaign.

  9. Fungi from a Groundwater-Fed Drinking Water Supply System in Brazil.

    Science.gov (United States)

    Oliveira, Helena M B; Santos, Cledir; Paterson, R Russell M; Gusmão, Norma B; Lima, Nelson

    2016-03-09

    Filamentous fungi in drinking water distribution systems are known to (a) block water pipes; (b) cause organoleptic biodeterioration; (c) act as pathogens or allergens and (d) cause mycotoxin contamination. Yeasts might also cause problems. This study describes the occurrence of several fungal species in a water distribution system supplied by groundwater in Recife-Pernambuco, Brazil. Water samples were collected from four sampling sites from which fungi were recovered by membrane filtration. The numbers in all sampling sites ranged from 5 to 207 colony forming units (CFU)/100 mL with a mean value of 53 CFU/100 mL. In total, 859 isolates were identified morphologically, with Aspergillus and Penicillium the most representative genera (37% and 25% respectively), followed by Trichoderma and Fusarium (9% each), Curvularia (5%) and finally the species Pestalotiopsis karstenii (2%). Ramichloridium and Leptodontium were isolated and are black yeasts, a group that include emergent pathogens. The drinking water system in Recife may play a role in fungal dissemination, including opportunistic pathogens.

  10. A remotely operated, field deployable tritium analysis system for surface and groundwater measurement

    Energy Technology Data Exchange (ETDEWEB)

    Cable, P.R.; Hofstetter, K.J.; Beals, D.M.; Jones, J.D.; Collins, S.L. [Westinghouse Savannah River Co., Aiken, SC (United States); Noakes, J.E.; Spaulding, J.D.; Neary, M.P. [Center for Applied Isotope Studies, Athens, GA (United States); Peterson, R. [Sampling Systems, Inc., Old Ocean, TX (United States)

    1996-12-31

    A prototype system for the remote, in situ analysis of tritium in surface and ground waters has been developed at the Savannah River Site through the combined efforts of university, private industry, and government laboratory personnel under a project funded by the DOE/OTD. Using automated liquid scintillation counting techniques, the Field Deployable Tritium Analysis System (FDTAS) has been shown in laboratory and limited field tests to have sufficient sensitivity to measure tritium in water samples at environmental levels (10 Bq/L [{approximately}300 pCi/L] for a 100-minute count) on a near-real time basis. These limits are well below the EPA drinking water standard for tritium at 740 Bq/L (1) and lower than the normal upstream Savannah River tritium concentration of {approximately}40 Bq/L (2). The FDTAS consists of a fixed volume sampler (50 mL), an on-line water purification system, and a stop-flow liquid scintillation counter for detecting tritium in the purified sample. All operations are controlled and monitored by a remote computer using standard telephone line modem communications. The FDTAS offers a cost-effective alternative to the expensive and time-consuming methods of field sample collection and laboratory analyses for tritium in contaminated groundwater.

  11. Hydrogeochemical and stable isotope data of groundwater of a multi-aquifer system: Northern Gafsa basin - Central Tunisia

    Science.gov (United States)

    Mokadem, Naziha; Demdoum, Abedslem; Hamed, Younes; Bouri, Salem; Hadji, Rihab; Boyce, Adrian; Laouar, Rabah; Sâad, Abedaziz

    2016-02-01

    The hydrodynamic of the multi-aquifer system (the Continental Intercalaire " C.I " and the Complex Terminal " C.T ") of the North Gafsa basin is largely determined by tectonics (Tebessa - Gafsa fault). The composition of groundwater is controlled by complex reactions at gas-liquid-solid "mineralogical composition of associated rocks" interfaces, which depend on the natural surrounding and potential anthropogenic impact. The hydrochemical data (major ion geochemistry) indicate that these groundwaters are characterized by the dominance a Ca-Mg-HCO3/SO4 and Na-Cl-NO3 water types. Geochemical pattern is mainly controlled by the dissolution of halite, gypsum and/or anhydrite as well as by the incongruent dissolution of carbonate minerals. The pH of these samples range from 6.54 to 8.89, supporting the conclusion that the H2CO3/HCO3 couple control pH buffering. Oxygen-18 (δ18O‰SMOW) and deuterium (dD‰SMOW) isotopic data show the exchange between the groundwater and the rock (water-rock interaction) and the evaporation effect. The isotopic content of the boreholes waters is of mixed Mediterranean - Atlantic origin and is opposite to the quantity of rainwater distribution, both in space and time in the study area. This is due to its geographical situation in the southern and south-western of the Mediterranean Sea and between the Atlas area and the Sahara Platform. The concentrations of the isotopic composition of the groundwater are significantly higher than the rainwater. This is indicative of the dissolution of salts and other processes modifying the rainwater geochemical composition during infiltration into the vadose zone. The hydraulic interconnection of these components of the system has led to the evolution of these interesting groundwater types.

  12. Status Report on the Microbial Characterization of Halite and Groundwater Samples from the WIPP

    Energy Technology Data Exchange (ETDEWEB)

    Swanson, Juliet S. [Los Alamos National Laboratory; Reed, Donald T. [Los Alamos National Laboratory; Ams, David A. [Los Alamos National Laboratory; Norden, Diana [Ohio State University; Simmons, Karen A. [Los Alamos National Laboratory

    2012-07-10

    This report summarizes the progress made in the ongoing task of characterizing the microbial community structures within the WIPP repository and in surrounding groundwaters. Through cultivation and DNA-based identification, the potential activity of these organisms is being inferred, thus leading to a better understanding of their impact on WIPP performance. Members of the three biological domains - Bacteria, Archaea, and Eukarya (in this case, Fungi) - that are associated with WIPP halite have been identified. Thus far, their activity has been limited to aerobic respiration; anaerobic incubations are underway. WIPP halite constitutes the near-field microbial environment. We expect that microbial activity in this setting will proceed from aerobic respiration, through nitrate reduction to focus on sulfate reduction. This is also the current WIPP performance assessment (PA) position. Sulfate reduction can occur at extremely high ionic strengths, and sulfate is available in WIPP brines and in the anhydrite interbeds. The role of methanogenesis in the WIPP remains unclear, due to both energetic constraints imposed by a high-salt environment and substrate selectivity, and it is no longer considered in PA. Archaea identified in WIPP halite thus far fall exclusively within the family Halobacteriaceae. These include Halobacterium noricense, cultivated from both low- and high-salt media, and a Halorubrum-like species. The former has also been detected in other salt mines worldwide; the latter likely constitutes a new species. Little is known of its function, but it was prevalent in experiments investigating the biodegradation of organic complexing agents in WIPP brines. Bacterial signatures associated with WIPP halite include members of the phylum Proteobacteria - Halomonas, Pelomonas, Limnobacter, and Chromohalobacter - but only the latter has been isolated. Also detected and cultivated were Salinicoccus and Nesterenkonia spp. Fungi were also isolated from halite. Although

  13. Aquifer-Circulating Water Curtain Cultivation System To Recover Groundwater Level And Temperature

    Science.gov (United States)

    Kim, Y.; Ko, K.; Chon, C.; Oh, S.

    2011-12-01

    Groundwater temperature, which generally ranges 14 to 16 degree of Celsius all year long, can be said to be 'constant' compared to the amplitude of daily variation of air temperature or surface water. Water curtain cultivating method utilizes this 'constant' groundwater temperature to warm up the inside of greenhouse during winter night by splash groundwater on the roof of inner greenhouse. The area of water curtain cultivation system have increased up to 107.5 square kilometers as of 2006 since when it is first introduced to South Korea in 1984. Groundwater shortage problem became a great issue in a concentrated water curtain cultivation area because the pumped and splashed groundwater is abandoned to nearby stream and natural recharge rate is reduced by greenhouses. The amount of groundwater use for water curtain cultivation system in South Korea is calculated to be 587 million cubic meters which is 35% of national agricultural use of groundwater. A new water curtain cultivation system coupled with aquifer circulating of the splashed groundwater and greenhouse roof-top rainwater harvesting is developed and applied to field site in Nonsan-si, Chungnam province to minimize groundwater shortage problem and recover groundwater level. The aquifer circulating water curtain cultivation system is consist of a pumping well and a injection well of 80 m deep, groundwater transfer and splashing system, recovery tank and rainwater collecting waterway. The distance between injection and pumping well is 15 m and an observation well is installed in the middle of the wells. To characterize hydrogeological properties of this site, hydraulic test such as pumping tests and tracer tests with dye tracer, thermal tracer and ion tracer. Once the integrated system is constructed in this site, hydraulic head in all the wells and temperature of air, recovery tank and groundwater in all the wells are monitored during the operation for 3months in winter season. Hydraulic test and tracer

  14. An expert system supporting decision making process for sustainable groundwater use in main alluvial aquifers in Slovenia

    Science.gov (United States)

    Souvent, Petra; Vižintin, Goran; Celarc, Sašo; Čenčur Curk, Barbara

    2016-04-01

    The expert decision support system for groundwater management in the shallow alluvial aquifers was developed to assist the decision makers to quantify available groundwater for a given alluvial aquifer and provide additional information about quantity of groundwater available for water rights licensing. The system links numerical groundwater flow models with the water permits and concessions databases in a complex decision support system. Six regional stand-alone groundwater models are used in the process of the assessment of groundwater quantitative status as well as for assessing availability of groundwater resources during the period of maximum water consumption and minimum groundwater recharge. Model runs have been realized in a steady state and are calibrated to a medium-low hydrological field conditions, because water quantities for all already granted as well as to-be granted water rights have to be ensured in any time for several years. The major goal of the expert decision support system is therefore to provide control mechanisms in order to verify the water rights licensing for the sustainable use of groundwater resources. The system enables that the water quantity data from water permits and concessions in conjunction with the results of numerical groundwater modeling are used in the managing process of granting new water rights to users in terms of their long-term access to groundwater (sufficient quantity of groundwater) and in relation to the water rights of other users (co-impact of groundwater pumping). Also, groundwater access must be managed in such a way that it does not cause unacceptable local impacts (pumping must not lower the water level for more than 2/3 of water body in the medium-low hydrological conditions).

  15. Simulation of Groundwater Flow in the Coastal Plain Aquifer System of Virginia

    Science.gov (United States)

    Heywood, Charles E.; Pope, Jason P.

    2009-01-01

    The groundwater model documented in this report simulates the transient evolution of water levels in the aquifers and confining units of the Virginia Coastal Plain and adjacent portions of Maryland and North Carolina since 1890. Groundwater withdrawals have lowered water levels in Virginia Coastal Plain aquifers and have resulted in drawdown in the Potomac aquifer exceeding 200 feet in some areas. The discovery of the Chesapeake Bay impact crater and a revised conceptualization of the Potomac aquifer are two major changes to the hydrogeologic framework that have been incorporated into the groundwater model. The spatial scale of the model was selected on the basis of the primary function of the model of assessing the regional water-level responses of the confined aquifers beneath the Coastal Plain. The local horizontal groundwater flow through the surficial aquifer is not intended to be accurately simulated. Representation of recharge, evapotranspiration, and interaction with surface-water features, such as major rivers, lakes, the Chesapeake Bay, and the Atlantic Ocean, enable simulation of shallow flow-system details that influence locations of recharge to and discharge from the deeper confined flow system. The increased density of groundwater associated with the transition from fresh to salty groundwater near the Atlantic Ocean affects regional groundwater flow and was simulated with the Variable Density Flow Process of SEAWAT (a U.S. Geological Survey program for simulation of three-dimensional variable-density groundwater flow and transport). The groundwater density distribution was generated by a separate 108,000-year simulation of Pleistocene freshwater flushing around the Chesapeake Bay impact crater during transient sea-level changes. Specified-flux boundaries simulate increasing groundwater underflow out of the model domain into Maryland and minor underflow from the Piedmont Province into the model domain. Reported withdrawals accounted for approximately

  16. Groundwater-flow model for the Wood River Valley aquifer system, south-central Idaho

    Science.gov (United States)

    Fisher, Jason C.; Bartolino, James R.; Wylie, Allan H.; Sukow, Jennifer; McVay, Michael

    2016-06-27

    A three-dimensional numerical model of groundwater flow was developed for the Wood River Valley (WRV) aquifer system, Idaho, to evaluate groundwater and surface-water availability at the regional scale. This mountain valley is located in Blaine County and has a drainage area of about 2,300 square kilometers (888 square miles). The model described in this report can serve as a tool for water-rights administration and water-resource management and planning. The model was completed with support from the Idaho Department of Water Resources, and is part of an ongoing U.S. Geological Survey effort to characterize the groundwater resources of the WRV. A highly reproducible approach was taken for constructing the WRV groundwater-flow model. The collection of datasets, source code, and processing instructions used to construct and analyze the model was distributed as an R statistical-computing and graphics package.

  17. Ground-water system, estimation of aquifer hydraulic properties, and effects of pumping on ground-water flow in Triassic sedimentary rocks in and near Lansdale, Pennsylvania

    Science.gov (United States)

    Senior, Lisa A.; Goode, Daniel J.

    1999-01-01

    Ground water in Triassic-age sedimentary fractured-rock aquifers in the area of Lansdale, Pa., is used as drinking water and for industrial supply. In 1979, ground water in the Lansdale area was found to be contaminated with trichloroethylene, tetrachloroethylene, and other man-made organic compounds, and in 1989, the area was placed on the U.S. Environmental Protection Agency's (USEPA) National Priority List as the North Penn Area 6 site. To assist the USEPA in the hydrogeological assessment of the site, the U.S. Geological Survey began a study in 1995 to describe the ground-water system and to determine the effects of changes in the well pumping patterns on the direction of ground-water flow in the Lansdale area. This determination is based on hydrologic and geophysical data collected from 1995-98 and on results of the simulation of the regional ground-water-flow system by use of a numerical model.Correlation of natural-gamma logs indicate that the sedimentary rock beds strike generally northeast and dip at angles less than 30 degrees to the northwest. The ground-water system is confined or semi-confined, even at shallow depths; depth to bedrock commonly is less than 20 feet (6 meters); and depth to water commonly is about 15 to 60 feet (5 to 18 meters) below land surface. Single-well, aquifer-interval-isolation (packer) tests indicate that vertical permeability of the sedimentary rocks is low. Multiple-well aquifer tests indicate that the system is heterogeneous and that flow appears primarily in discrete zones parallel to bedding. Preferred horizontal flow along strike was not observed in the aquifer tests for wells open to the pumped interval. Water levels in wells that are open to the pumped interval, as projected along the dipping stratigraphy, are drawn down more than water levels in wells that do not intersect the pumped interval. A regional potentiometric map based on measured water levels indicates that ground water flows from Lansdale towards discharge

  18. Installation-Restoration Program Stage 3. McClellan AFB, California. Remedial investigation/feasibility study ground-water sampling and analysis program, January through March 1989 data summary. Final report, January-March 1989

    Energy Technology Data Exchange (ETDEWEB)

    1989-06-19

    This Data Summary presents the results of ground-water sampling activities conducted on and in the vicinity of McClellan Air Force Base from the sampling period of January through March, 1989. Concentrations of purgeable halocarbons and aromatic compounds detected in 336 wells 26 monitoring wells are located on base in Area A, B, C, D, and adjacent on-base areas and off-base in the Northwest and Southwest areas. There was no detected increase in the areal extent of contaminated ground-water, nor was there any increase in the depth that contaminated ground-water was detected. The Area D extraction system is effectively operating to change hydraulic gradients, so groundwater in Area D flows toward the extraction wells. Contaminant concentrations have decreased in Area D deep zone monitoring wells. Samples from three middle-zone monitoring wells located in Area D also show decreases in contaminant concentration during this sampling period. Decreasing contaminant concentrations have stabilized in shallow zone monitoring wells located off-base, west of Area D.

  19. 78 FR 36633 - National Automotive Sampling System

    Science.gov (United States)

    2013-06-18

    ... National Highway Traffic Safety Administration National Automotive Sampling System AGENCY: National Highway Traffic Safety Administration (NHTSA), Department of the Transportation (DOT). ACTION: Notice of public... regarding vehicle design and traffic safety. The NASS system currently has two components: the...

  20. Study of the water-rock interaction in Tsengwenshi groundwater system (southern Taiwan) using BCR sequential extraction procedure

    Science.gov (United States)

    Teng, J. Y.

    2012-04-01

    The heavy metals in groundwater seriously risk the human wealth, agriculture and the aquaculture, especially, if the water is the major source of daily use. Generally, in spite of anthropogenic source, the heavy metals in groundwater are released during water-rock interaction. However, there are many mineral phases being capable of releasing heavy metals. It would need a sequential extraction procedure to identify the source mineral phase in the aquifer. In addition, the geochemical reactions after the release of heavy metals are also important to modify the concentrations. In this study, the rare earth elements are used to be a natural tracer for this purpose. The study area, Tsengwenshi watershed in southern Taiwan, is an alluvial fan with all kinds of land uses and is notorious of arsenic contamination. The groundwaters sampled in this study show that arsenic is enriched in deep aquifer (depth>150m), which is composed of sediments deposited in the last glacial period (18 ka). Based on this conceptual model, the results of BCR sequential extraction procedure are categorized into shallow aquifer (depthheavy metals in two groups can be subsequently obtained to take account of extensive water-rock interaction in the groundwater system. The results show that arsenic and other heavy metals are mostly binding with Fe-Mn oxides. To compare the ratios between deep and shallow aquifers for all heavy metals, the pattern of groundwaters does not show the similar type with those of extracted phases from soils. It is believed that the released heavy metals were strongly modified by the geochemical reactions during the transportation in the groundwater system. In addition, the analysis results of the rare earth elements demonstrates that almost all groundwaters with high arsenic do not have Ce negative anomaly; and, on the contrary, those with low arsenic are generally characterized by strong negative anomaly. Generally, the Ce negative anomaly is a prominent indicator of

  1. Planetary Sample Caching System Design Options

    Science.gov (United States)

    Collins, Curtis; Younse, Paulo; Backes, Paul

    2009-01-01

    Potential Mars Sample Return missions would aspire to collect small core and regolith samples using a rover with a sample acquisition tool and sample caching system. Samples would need to be stored in individual sealed tubes in a canister that could be transfered to a Mars ascent vehicle and returned to Earth. A sample handling, encapsulation and containerization system (SHEC) has been developed as part of an integrated system for acquiring and storing core samples for application to future potential MSR and other potential sample return missions. Requirements and design options for the SHEC system were studied and a recommended design concept developed. Two families of solutions were explored: 1)transfer of a raw sample from the tool to the SHEC subsystem and 2)transfer of a tube containing the sample to the SHEC subsystem. The recommended design utilizes sample tool bit change out as the mechanism for transferring tubes to and samples in tubes from the tool. The SHEC subsystem design, called the Bit Changeout Caching(BiCC) design, is intended for operations on a MER class rover.

  2. Using isotopic, hydrogeochemical-tracer and temperature data to characterize recharge and flow paths in a complex karst groundwater flow system in northern China

    Science.gov (United States)

    Sun, Ziyong; Ma, Rui; Wang, Yanxin; Ma, Teng; Liu, Yunde

    2016-09-01

    Isotopic and hydrogeochemical analysis, combined with temperature investigation, was conducted to characterize the flow system in the carbonate aquifer at Taiyuan, northern China. The previous division of karst subsystems in Taiyuan, i.e. the Xishan (XMK), Dongshan (DMK) and Beishan (BMK) mountain systems, were also examined. The measured δD, δ 18O and 3He/4He in water indicate that both thermal and cold groundwaters have a meteoric origin rather than deep crustal origin. Age dating using 3H and 14C shows that groundwater samples from discharge zones along faults located at the margin of mountains in the XMK and DMK are a mixture of paleometeoric thermal waters and younger cold waters from local flow systems. 14C data suggest that the average age was about 10,000 years and 4,000 years for thermal and cold groundwater in discharge zones, respectively. Based on the data of temperature, water solute chemical properties, 14C, δ 34SSO4, 87Sr/86Sr and δ 18O, different flow paths in the XMK and DMK were distinguished. Shallow groundwater passes through the upper Ordovician formations, producing younger waters at the discharge zone (low temperature and ionic concentration and enriched D and 18O). Deep groundwater flows through the lower Ordovician and Cambrian formations, producing older waters at the discharge zone (high ionic concentration and temperature and depleted D and 18O). At the margin of mountains, groundwater in deep systems flows vertically up along faults and mixes with groundwater from shallow flow systems. By contrast, only a single flow system through the entire Cambrian to Ordovician formations occurs in the BMK.

  3. Modelling climate change effects on a dutch coastal groundwater system using airborne electromagnetic measurements

    NARCIS (Netherlands)

    Faneca S̀anchez, M.; Gunnink, J.L.; Baaren, E.S. van; Oude Essink, G.H.P.; Siemon, B.; Auken, E.; Elderhorst, W.; Louw, P.G.B. de

    2012-01-01

    The forecast of climate change effects on the groundwater system in coastal areas is of key importance for policy makers. The Dutch water system has been deeply studied because of its complex system of low-lying areas, dunes, land won to the sea and dikes, but nowadays large efforts are still being

  4. Integrated assessment of sources, chemical stressors and stream quality along a groundwater fed stream system

    Science.gov (United States)

    Løgstrup Bjerg, Poul; Sonne, Anne T.; Rønde, Vinni; McKnight, Ursula S.

    2016-04-01

    Streams are impacted by significant contamination at the catchment scale, as they are often locations of multiple chemical stressor inputs. The European Water Framework Directive requires EU member states to ensure good chemical and ecological status of surface water bodies by 2027. This requires monitoring of stream water quality, comparison with environmental quality standards (EQS) and assessment of ecological status. However, the achievement of good status of stream water also requires a strong focus on contaminant sources, pathways and links to stream water impacts, so source management and remedial measures can be implemented. Fate and impacts of different contaminant groups are governed by different processes and are dependent on the origin (geogenic, anthropogenic), source type (point or diffuse) and pathway of the contaminant. To address this issue, we identified contaminant sources and chemical stressors on a groundwater-fed stream to quantify the contaminant discharges, link the chemical impact and stream water quality and assess the main chemical risk drivers in the stream system potentially driving ecological impact. The study was conducted in the 8 m wide Grindsted stream (Denmark) along a 16 km stream stretch that is potentially impacted by two contaminated sites (Grindsted Factory site, Grindsted Landfill), fish farms, waste water discharges, and diffuse sources from agriculture and urban areas. Water samples from the stream and the hyporheic zone as well as bed sediment samples were collected during three campaigns in 2012 and 2014. Data for xenobiotic organic groundwater contaminants, pesticides, heavy metals, general water chemistry, physical conditions and stream flow were collected. The measured chemical concentrations were converted to toxic units (TU) based on the 48h acute toxicity tests with D. magna. The results show a substantial impact of the Grindsted Factory site at a specific stretch of the stream. The groundwater plume caused

  5. 40 CFR 1065.805 - Sampling system.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Sampling system. 1065.805 Section 1065.805 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Testing With Oxygenated Fuels § 1065.805 Sampling system. (a) Dilute...

  6. Systems and methods for sample analysis

    Energy Technology Data Exchange (ETDEWEB)

    Cooks, Robert Graham; Li, Guangtao; Li, Xin; Ouyang, Zheng

    2015-10-20

    The invention generally relates to systems and methods for sample analysis. In certain embodiments, the invention provides a system for analyzing a sample that includes a probe including a material connected to a high voltage source, a device for generating a heated gas, and a mass analyzer.

  7. Classification as a generic tool for characterising status and changes of regional scale groundwater systems

    Science.gov (United States)

    Barthel, Roland; Haaf, Ezra

    2016-04-01

    Regional hydrogeology is becoming increasingly important, but at the same time, scientifically sound, universal solutions for typical groundwater problems encountered on the regional scale are hard to find. While managers, decision-makers and state agencies operating on regional and national levels have always shown a strong interest in regional scale hydrogeology, researchers from academia tend to avoid the subject, focusing instead on local scales. Additionally, hydrogeology has always had a tendency to regard every problem as unique to its own site- and problem-specific context. Regional scale hydrogeology is therefore pragmatic rather than aiming at developing generic methodology (Barthel, 2014; Barthel and Banzhaf, 2016). One of the main challenges encountered on the regional scale in hydrogeology is the extreme heterogeneity that generally increases with the size of the studied area - paired with relative data scarcity. Even in well-monitored regions of the world, groundwater observations are usually clustered, leaving large areas without any direct data. However, there are many good reasons for assessing the status and predicting the behavior of groundwater systems under conditions of global change even for those areas and aquifers without observations. This is typically done by using rather coarsely discretized and / or poorly parameterized numerical models, or by using very simplistic conceptual hydrological models that do not take into account the complex three-dimensional geological setup. Numerical models heavily rely on local data and are resource-demanding. Conceptual hydrological models only deliver reliable information on groundwater if the geology is extremely simple. In this contribution, we present an approach to derive statistically relevant information for un-monitored areas, making use of existing information from similar localities that are or have been monitored. The approach combines site-specific knowledge with conceptual assumptions on

  8. Forsmark site investigation. Hydrochemical monitoring of groundwaters and surface waters. Results from water sampling in the Forsmark area, January-December 2009

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Ann-Chatrin (ed.); Berg, Cecilia; Harrstroem, Johan; Joensson, Stig; Thur, Pernilla (Geosigma AB (Sweden)); Borgiel, Micke; Qvarfordt, Susanne (Sveriges Vattenekologer AB (Sweden))

    2010-09-15

    The fifth year (2009) of hydrochemical monitoring of groundwaters, surface waters and precipitation in Forsmark is documented in the report. The hydrochemical monitoring programme 2009 included water sampling from: - percussion- and core boreholes equipped with installations for long-term pressure monitoring, tracer tests and water sampling in packed off borehole sections, sampling and analysis performed twice (spring and autumn), - near surface groundwaters (sampling four times a year), - private wells (once per year in October), - surface waters (eleven sampling occasions per year). Due to the somewhat different performance of the hydrogeochemical monitoring of the deep groundwaters during the autumn 2009 compared to previous years, some new findings and knowledge were obtained: 1) Removal of water volumes corresponding to three to five times the volume of the borehole section (the routine procedure) is seldom enough to obtain a complete exchange of the water present in the borehole section when the pumping starts. 2) It is likely that the elevated sulphide concentrations observed in the monitoring programme /1/ is due to contamination from initial water present in the borehole sections when the pumping starts. This water may have a very high sulphide concentration. Dirty water in tubes and in stand pipes may also contribute to the enhanced sulphide concentration. 3) Plug flow calculations will be introduced in the future as a new routine procedure to estimate the water volumes to be removed, in order to exchange the section water volume, prior to groundwater sampling in delimited borehole sections. During the autumn sampling, sample series of five samples per sampling location were collected during continuous pumping in thirteen selected borehole sections. Furthermore, special efforts were put on cleaning of stand pipes and exchange of water prior to sampling. The analytical protocol was rather extensive and included sulphide and uranium analyses for each sample

  9. Noble gas signatures in the Island of Maui, Hawaii: Characterizing groundwater sources in fractured systems

    Science.gov (United States)

    Niu, Yi; Castro, M. Clara; Hall, Chris M.; Gingerich, Stephen B.; Scholl, Martha A.; Warrier, Rohit B.

    2017-01-01

    Uneven distribution of rainfall and freshwater scarcity in populated areas in the Island of Maui, Hawaii, renders water resources management a challenge in this complex and ill-defined hydrological system. A previous study in the Galapagos Islands suggests that noble gas temperatures (NGTs) record seasonality in that fractured, rapid infiltration groundwater system rather than the commonly observed mean annual air temperature (MAAT) in sedimentary systems where infiltration is slower thus, providing information on recharge sources and potential flow paths. Here we report noble gas results from the basal aquifer, springs, and rainwater in Maui to explore the potential for noble gases in characterizing this type of complex fractured hydrologic systems. Most samples display a mass-dependent depletion pattern with respect to surface conditions consistent with previous observations both in the Galapagos Islands and Michigan rainwater. Basal aquifer and rainwater noble gas patterns are similar and suggest direct, fast recharge from precipitation to the basal aquifer. In contrast, multiple springs, representative of perched aquifers, display highly variable noble gas concentrations suggesting recharge from a variety of sources. The distinct noble gas patterns for the basal aquifer and springs suggest that basal and perched aquifers are separate entities. Maui rainwater displays high apparent NGTs, incompatible with surface conditions, pointing either to an origin at high altitudes with the presence of ice or an ice-like source of undetermined origin. Overall, noble gas signatures in Maui reflect the source of recharge rather than the expected altitude/temperature relationship commonly observed in sedimentary systems.

  10. Geochemical properties of groundwater used to geothermal cooling and heating system

    Science.gov (United States)

    Kim, Namju; Park, Youngyun; Lee, Jin-Yong

    2013-04-01

    Recently, geothermal cooling and heating system has been used in many countries to reduce emission of greenhouse gases such as water vapour and carbon dioxide (CO2). Especially, CO2 is emitted from combustion of fossil fuel used for cooling and heating of buildings. Therefore, many countries make an effort to reduce amount of CO2 emitted from use of fossil fuel. The geothermal cooling and heating system is good to reduce amount of CO2. Especially, open loop geothermal system shows good thermal efficiency. However, groundwater contaminations will be considered because groundwater is directly used in open loop geothermal system. This study was performed to examine chemical and isotope compositions of groundwater used in open loop geothermal system and to evaluate influence of the system on groundwater using hydrochemical modeling program (preequc). Water temperature of well used in the system (GH) and well around the system (GB) ranged from 8.4 to 17.0 ° and from 15.1 to 18.0 °, respectively. The water temperature in GH was lower than that in GB because of heating mode of the system. Also, EC in GH and GB showed significant difference. The variation trend of EC was different at each site where the system was installed. These results mean that main factors controlling EC in GH was not the system. Generally, EC of groundwater was influenced by water-rock interaction. However, DO and Eh hardly showed significant difference. The operation period of the system observed in this study was short than 5 years. Therefore, influence of the open loop geothermal system on groundwater did not shown significantly. However, while Fe2+ and Mn2+ were not observed in GB, these components were measured in GH. The concentrations of Fe2+ and Mn2+ in GH ranged from 0.02 to 0.14 mg/L and from 0.03 to 0.18 mg/L, respectively. These results mean that redox conditions of GH were changed by the system little by little. In this study, influence of the open loop geothermal system on groundwater

  11. Pathways of sulfate and hydrogen sulfide transformations in a BTEX- contaminated groundwater system

    DEFF Research Database (Denmark)

    Einsiedl, Florian; Anneser, B.; Griebler, C.

    2010-01-01

    of groundwater demands an improved understanding of the efficiency and limitations of microbially driven reactions on the degradation of pollutants in contaminated groundwater systems. In this context stable isotope approaches represent a powerful tool to evaluate and elucidate biogeochemical processes...... in complex environmental systems. As a result, compound specific stable isotope signatures in various sulfur species were determined in a tar-oil contaminated site and were linked to the microbial community distribution in the aquifer. The goal of the study was to reach an integrated understanding of sulfur...... cycling processes in contaminated aquifers relative to their importance for the biodegradation. The results show that sulfur cycling is an important process driving microbial degradation of contaminants in porous groundwater systems. For the anoxic plume core it appears that elemental sulfur is a key...

  12. Groundwater level monitoring sampling and analysis plan for environmental monitoring in Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1994-04-01

    This Sampling and Analysis Plan addresses groundwater level monitoring activities that will be conducted in support of the Environmental Monitoring Plan for Waste Area Grouping (WAG) 6. WAG 6 is a shallow-burial land disposal facility for low-level radioactive waste at the Oak Ridge National Laboratory, a research facility owned by the US Department of Energy and managed by Martin Marietta Energy Systems, Inc. Groundwater level monitoring will be conducted at 129 sites within the WAG. All of the sites will be manually monitored on a semiannual basis. Forty-five of the 128 wells, plus one site in White Oak Lake, will also be equipped with automatic water level monitoring equipment. The 46 sites are divided into three groups. One group will be equipped for continuous monitoring of water level, conductivity, and temperature. The other two groups will be equipped for continuous monitoring of water level only. The equipment will be rotated between the two groups. The data collected from the water level monitoring will be used to support determination of the contaminant flux at WAG 6.

  13. April 2012 Groundwater and Surface Water Sampling at the Salmon, Mississippi, Site (Data Validation Package)

    Energy Technology Data Exchange (ETDEWEB)

    None

    2012-10-12

    Sampling and analysis were conducted on April 16-19, 2012, as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office Of Legacy Management Sites (LMS/PLN/S04351, continually updated). Duplicate samples were collected from locations SA1-1-H, HMH-5R, SA3-4-H, SA1-2-H, Pond W of GZ, and SA5-4-4. One trip blank was collected during this sampling event.

  14. Simulation of a Complex Groundwater System and an Application

    Science.gov (United States)

    Premchitt, Jerasak; Das Gupta, Ashim

    1981-06-01

    A hydrologic model of an extensive groundwater basin was developed for the study of land subsidence due to deep well pumping in Bangkok, Thailand. It is a quasi-three-dimensional flow model with relevant modifications to suit the hydrogeologic situations in the problem area. The troublesome effect of yield from aquitard is discarded, while the field information on subsurface strata is fully utilized to establish a realistic model. The subsurface is considered to be a single hydraulically connected body stratified into model layers for convenience in the simulation. Pumping can be imposed at any depth, and discharge rates can be arbitrary. Any number of model layers can be incorporated, with coupling being provided through the leakage flux. The power and flexibility of the model is demonstrated in the simulation of groundwater flow regime in the Lower Central Plain of Thailand for a time period of 45 years. At first the model is calibrated with available field measurements in the past, and it is then extended for the prediction of future situations. The model represents the actual field situation. The mathematical process is simple, and it would require less computing effort than the equivalent full three-dimensional model or the quasi-three-dimensional model with one-dimensional elements to represent aquitards.

  15. Results of soil, ground-water, surface-water, and streambed-sediment sampling at Air Force Plane 85, Columbus, Ohio, 1996

    Science.gov (United States)

    Parnell, J.M.

    1997-01-01

    The U.S. Geological Survey (USGS), in cooperation with Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, prepared the Surface- and Ground- Water Monitoring Work Plan for Air Force Plant 85 (AFP 85 or Plant), Columbus, Ohio, under the Air Force Installation Restoration Program to characterize any ground-water, surface-water, and soil contamination that may exist at AFP 85. The USGS began the study in November 1996. The Plant was divided into nine sampling areas, which included some previously investi gated study sites. The investigation activities included the collection and presentation of data taken during drilling and water-quality sampling. Data collection focused on the saturated and unsatur ated zones and surface water. Twenty-three soil borings were completed. Ten monitoring wells (six existing wells and four newly constructed monitoring wells) were selected for water-quality sam pling. Surface-water and streambed-sediment sampling locations were chosen to monitor flow onto and off of the Plant. Seven sites were sampled for both surface-water and streambed-sediment quality. This report presents data on the selected inorganic and organic constituents in soil, ground water, surface water, and streambed sediments at AFP 85. The methods of data collection and anal ysis also are included. Knowledge of the geologic and hydrologic setting could aid Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, and its governing regulatory agencies in future remediation studies.

  16. Sampling system for in vivo ultrasound images

    DEFF Research Database (Denmark)

    Jensen, Jorgen Arendt; Mathorne, Jan

    1991-01-01

    Newly developed algorithms for processing medical ultrasound images use the high frequency sampled transducer signal. This paper describes demands imposed on a sampling system suitable for acquiring such data and gives details about a prototype constructed. It acquires full clinical images...

  17. Modular microfluidic system for biological sample preparation

    Energy Technology Data Exchange (ETDEWEB)

    Rose, Klint A.; Mariella, Jr., Raymond P.; Bailey, Christopher G.; Ness, Kevin Dean

    2015-09-29

    A reconfigurable modular microfluidic system for preparation of a biological sample including a series of reconfigurable modules for automated sample preparation adapted to selectively include a) a microfluidic acoustic focusing filter module, b) a dielectrophoresis bacteria filter module, c) a dielectrophoresis virus filter module, d) an isotachophoresis nucleic acid filter module, e) a lyses module, and f) an isotachophoresis-based nucleic acid filter.

  18. A Comet Surface Sample Return System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Phase II investigation will focus on the development of spacecraft systems required to obtain a sample from the nucleus of a comet, hermetically seal...

  19. A Comet Surface Sample Return System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Phase I investigation will focus on the development of spacecraft systems required to obtain a sample from the nucleus of a comet, hermetically seal the...

  20. 77 FR 37471 - National Automotive Sampling System

    Science.gov (United States)

    2012-06-21

    ... National Highway Traffic Safety Administration National Automotive Sampling System AGENCY: National Highway Traffic Safety Administration (NHTSA), Department of Transportation (DOT). ACTION: Notice and request for... make informed regulatory, program, and policy decisions regarding vehicle design and traffic...

  1. GeoLab Sample Handling System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Develop  a robotic sample handling/ manipulator system for the GeoLab glovebox. This work leverages from earlier GeoLab work and a 2012 collaboration with a...

  2. Rotary Mode Core Sample System availability improvement

    Energy Technology Data Exchange (ETDEWEB)

    Jenkins, W.W.; Bennett, K.L.; Potter, J.D. [Westinghouse Hanford Co., Richland, WA (United States); Cross, B.T.; Burkes, J.M.; Rogers, A.C. [Southwest Research Institute (United States)

    1995-02-28

    The Rotary Mode Core Sample System (RMCSS) is used to obtain stratified samples of the waste deposits in single-shell and double-shell waste tanks at the Hanford Site. The samples are used to characterize the waste in support of ongoing and future waste remediation efforts. Four sampling trucks have been developed to obtain these samples. Truck I was the first in operation and is currently being used to obtain samples where the push mode is appropriate (i.e., no rotation of drill). Truck 2 is similar to truck 1, except for added safety features, and is in operation to obtain samples using either a push mode or rotary drill mode. Trucks 3 and 4 are now being fabricated to be essentially identical to truck 2.

  3. Quantifying changes in water use and groundwater availability in a megacity using novel integrated systems modeling

    Science.gov (United States)

    Hyndman, D. W.; Xu, T.; Deines, J. M.; Cao, G.; Nagelkirk, R.; Viña, A.; McConnell, W.; Basso, B.; Kendall, A. D.; Li, S.; Luo, L.; Lupi, F.; Ma, D.; Winkler, J. A.; Yang, W.; Zheng, C.; Liu, J.

    2017-08-01

    Water sustainability in megacities is a growing challenge with far-reaching effects. Addressing sustainability requires an integrated, multidisciplinary approach able to capture interactions among hydrology, population growth, and socioeconomic factors and to reflect changes due to climate variability and land use. We developed a new systems modeling framework to quantify the influence of changes in land use, crop growth, and urbanization on groundwater storage for Beijing, China. This framework was then used to understand and quantify causes of observed decreases in groundwater storage from 1993 to 2006, revealing that the expansion of Beijing's urban areas at the expense of croplands has enhanced recharge while reducing water lost to evapotranspiration, partially ameliorating groundwater declines. The results demonstrate the efficacy of such a systems approach to quantify the impacts of changes in climate and land use on water sustainability for megacities, while providing a quantitative framework to improve mitigation and adaptation strategies that can help address future water challenges.

  4. Steady-state numerical groundwater flow model of the Great Basin carbonate and alluvial aquifer system

    Science.gov (United States)

    Brooks, Lynette E.; Masbruch, Melissa D.; Sweetkind, Donald S.; Buto, Susan G.

    2014-01-01

    This report describes the construction, calibration, evaluation, and results of a steady-state numerical groundwater flow model of the Great Basin carbonate and alluvial aquifer system that was developed as part of the U.S. Geological Survey National Water Census Initiative to evaluate the nation’s groundwater availability. The study area spans 110,000 square miles across five states. The numerical model uses MODFLOW-2005, and incorporates and tests complex hydrogeologic and hydrologic elements of a conceptual understanding of an interconnected groundwater system throughout the region, including mountains, basins, consolidated rocks, and basin fill. The level of discretization in this model has not been previously available throughout the study area.

  5. Groundwater quality of the Gulf Coast aquifer system, Houston, Texas, 2010

    Science.gov (United States)

    Oden, Jeannette H.; Brown, Dexter W.; Oden, Timothy D.

    2011-01-01

    During March–December 2010, the U.S. Geological Survey, in cooperation with the city of Houston, collected source-water samples from 60 municipal supply wells in the Houston area. These data were collected as part of an ongoing study to determine concentrations, spatial extent, and associated geochemical conditions that might be conducive for mobility and transport of selected naturally occurring contaminants (selected trace elements and radionuclides) in the Gulf Coast aquifer system in the Houston area. In the summers of 2007 and 2008, a reconnaissance-level survey of these constituents in untreated water from 28 municipal supply wells was completed in the Houston area. Included in this report are the complete analytical results for 47 of the 60 samples collected in 2010—those results which were received from the laboratories and reviewed by the authors as of December 31, 2010. All of the wells sampled were screened in the Gulf Coast aquifer system; 22 were screened entirely in the Evangeline aquifer, and the remaining 25 wells contained screened intervals that intersected both Evangeline and Chicot aquifers. The data documented in this report were collected as part of an ongoing study to characterize source-water-quality conditions in untreated groundwater prior to drinking-water treatment. An evaluation of contaminant occurrence in source water provides background information regarding the presence of a contaminant in the environment. Because source-water samples were collected prior to any treatment or blending that potentially could alter contaminant concentrations, the water-quality results documented by this report represent the quality of the source water, not the quality of finished drinking water provided to the public.

  6. Data Validation Package August 2015 Groundwater Sampling at the Grand Junction, Colorado, Disposal Site October 2015

    Energy Technology Data Exchange (ETDEWEB)

    Frazier, William [USDOE Office of Legacy Management (LM), Washington, DC (United States); Baur, Gary [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2015-11-03

    The 1998 Interim Long-Term Surveillance Plan for the Cheney Disposal Site Near Grand Junction, Colorado, requires annual monitoring to assess the performance of the disposal cell. Monitoring wells 0731, 0732 and 0733 were sampled as specified in the plan. Sampling and analyses were conducted in accordance with Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites.

  7. Applying a System Dynamics Approach for Modeling Groundwater Dynamics to Depletion under Different Economical and Climate Change Scenarios

    Directory of Open Access Journals (Sweden)

    Hamid Balali

    2015-09-01

    Full Text Available In the recent decades, due to many different factors, including climate change effects towards be warming and lower precipitation, as well as some structural policies such as more intensive harvesting of groundwater and low price of irrigation water, the level of groundwater has decreased in most plains of Iran. The objective of this study is to model groundwater dynamics to depletion under different economic policies and climate change by using a system dynamics approach. For this purpose a dynamic hydro-economic model which simultaneously simulates the farmer’s economic behavior, groundwater aquifer dynamics, studied area climatology factors and government economical policies related to groundwater, is developed using STELLA 10.0.6. The vulnerability of groundwater balance is forecasted under three scenarios of climate including the Dry, Nor and Wet and also, different scenarios of irrigation water and energy pricing policies. Results show that implementation of some economic policies on irrigation water and energy pricing can significantly affect on groundwater exploitation and its volume balance. By increasing of irrigation water price along with energy price, exploitation of groundwater will improve, in so far as in scenarios S15 and S16, studied area’s aquifer groundwater balance is positive at the end of planning horizon, even in Dry condition of precipitation. Also, results indicate that climate change can affect groundwater recharge. It can generally be expected that increases in precipitation would produce greater aquifer recharge rates.

  8. The Resilience of Groundwater Remediation System in Response to Changing Conditions

    Science.gov (United States)

    Hou, D.

    2016-12-01

    Anthropogenic activities have caused the contamination of groundwater resources at many locations. In an effort to protect human health and prevent further spreading of groundwater contamination, remediation systems have been or will be built at hundreds of thousands of sites. While the short term effectiveness has been the focus of past research and practice, the long-term effectiveness is increasingly scrutinized. When assessing the long-term effectiveness of groundwater remediation systems, it is important to examine how existing remediation systems respond to changing geophysical (e.g. climate change) and social (e.g. improved living standard and changing development needs) conditions. The resilience of remediation strategies, or their potential to adapt to future changes, is a critical sustainability consideration. We intend to examine the resilience of groundwater remediation systems in response to changing conditions. Among others, we explore the effects of sea level rise and changing hydroclimatic conditions on the life cycle impact of phytoremediation and bioremediation systems. The study was conducted in the San Francisco Bay area, where thousands of contaminated sites are located in an area that may be affected by sea level rise and changing hydroclimatic conditions.

  9. An innovative artificial recharge system to enhance groundwater storage in basaltic terrain: example from Maharashtra, India

    Science.gov (United States)

    Bhusari, Vijay; Katpatal, Y. B.; Kundal, Pradeep

    2016-08-01

    The management of groundwater poses challenges in basaltic terrain as its availability is not uniform due to the absence of primary porosity. Indiscriminate excessive withdrawal from shallow as well as deep aquifers for meeting increased demand can be higher than natural recharge, causing imbalance in demand and supply and leading to a scarcity condition. An innovative artificial recharge system has been conceived and implemented to augment the groundwater sources at the villages of Saoli and Sastabad in Wardha district of Maharashtra, India. The scheme involves resectioning of a stream bed to achieve a reverse gradient, building a subsurface dam to arrest subsurface flow, and installation of recharge shafts to recharge the deeper aquifers. The paper focuses on analysis of hydrogeological parameters like porosity, specific yield and transmissivity, and on temporal groundwater status. Results indicate that after the construction of the artificial recharge system, a rise of 0.8-2.8 m was recorded in the pre- and post-monsoon groundwater levels in 12 dug wells in the study area; an increase in the yield was also noticed which solved the drinking water and irrigation problems. Spatial analysis was performed using a geographic information system to demarcate the area of influence of the recharge system due to increase in yields of the wells. The study demonstrates efficacy, technical viability and applicability of an innovative artificial recharge system constructed in an area of basaltic terrain prone to water scarcity.

  10. Groundwater flow systems in the great Aletsch glacier region (Valais, Switzerland)

    Science.gov (United States)

    Alpiger, Andrea; Loew, Simon

    2014-05-01

    Groundwater flow systems in Alpine areas are often complex and challenging to investigate due to special topographic and climatic conditions governing groundwater recharge and bedrock flow. Studies seeking to characterize high-alpine groundwater systems remain rare, but are of high interest, e.g. for water supply, hydropower systems, traffic tunnels or rock slope deformation and landslide hazards. The goal of this study is to better understand the current and past groundwater flow systems of the UNESCO World Heritage mountain ridge separating the great Aletsch glacier and the Rhone valley, considering climatic and glacier fluctuations during the Lateglacial and Holocene periods. This ridge is crossed by a hydropower bypass drift (Riederhornstollen) and is composed of fractured crystalline rocks overlain by various types of landslides and glacial deposits. Surface hydrology observations (fracture properties, groundwater seepage, spring lines and physico-chemical parameters) and hydropower drift inflow measurements contributed to the characterization of bedrock hydraulic conductivities and preferential groundwater pathways. Basic conceptual hydrogeological models were tested with observed drift inflows and the occurrence of springs using free-surface, variably saturated, vertical 2D groundwater flow models (using the code SEEP/W from GeoStudio 2007). Already simple two-layer models, representing profile sections orthogonal to the mountain ridge, provided useful results. Simulations show that differences in the occurrence of springs on each side of the mountain ridge are likely caused by the occurrence of glacial till (generating perched groundwater), the deep-seated sagging landslide mass, faults and asymmetric ridge topography, which together force the main groundwater flow direction to be oriented towards the Rhone valley, even from beyond the mountain ridge. Surprisingly, the most important springs (those with high discharge rates) are located at high elevations

  11. Groundwater Parameters and Flow Systems Near Oak Ridge National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Moore, G.K.

    1989-01-01

    Precipitation near Oak Ridge National Laboratory (ORNL) averages 132 cm/yr. About 76 cm/yr of water is consumed by evapotranspiration. The natural streamflow, which averages 56 cm/yr of water, consists of overland flow (about 21 cm/yr) from water bodies, wetlands, and impervious areas of groundwater discharge (about 35 cm/yr of water). Groundwater occurs in a stormflow zone that extends from the land surface to a depth of 0.3-2 m and in shallow and deeper aquifers that extend from the water table to the base of fresh water. in the stormflow zone, most water flows through macropores and mesopores, which have a volumetric porosity of about 0.002. In the vadose zone and below the water table, water flows through fractures that have a volumetric porosity in the range 1 x 10{sup -5} to 0.02. Water inflow occurs by precipitation and infiltration. infiltration that exceeds the soil water deficit forms a perched water table in the stormflow zone at the level where infiltration rate exceeds vertical hydraulic conductivity. Some water percolates down to the water table but the majority flows downslope to the streams. Recharge of the shallow aquifer is only about 3.2 cm/yr of water or 5.7% of streamflow. Most of the water that recharges the shallow aquifer is discharged by evapotranspiration above the water table. The remainder is discharged at springs and streams where the water table is within the stormflow zone. Digital models that permit unsaturated conditions and transient flows may be more appropriate than steady-state models of saturated flow for the ORNL area.

  12. Hydrochemical characterization and pollution sources identification of groundwater in Salawusu aquifer system of Ordos Basin, China.

    Science.gov (United States)

    Yang, Qingchun; Wang, Luchen; Ma, Hongyun; Yu, Kun; Martín, Jordi Delgado

    2016-09-01

    Ordos Basin is located in an arid and semi-arid region of northwestern China, which is the most important energy source bases in China. Salawusu Formation (Q3 s) is one of the most important aquifer systems of Ordos Basin, which is adjacent to Jurassic coalfield areas. A large-scale exploitation of Jurassic coal resources over ten years results in series of influences to the coal minerals, such as exposed to the oxidation process and dissolution into the groundwater due to the precipitation infiltration. Therefore, how these processes impact groundwater quality is of great concerns. In this paper, the descriptive statistical method, Piper trilinear diagram, ratios of major ions and canonical correspondence analysis are employed to investigate the hydrochemical evolution, determine the possible sources of pollution processes, and assess the controls on groundwater compositions using the monitored data in 2004 and 2014 (before and after large-scale coal mining). Results showed that long-term exploration of coal resources do not result in serious groundwater pollution. The hydrochemical types changed from HCO3(-)-CO3(2-) facies to SO4(2-)-Cl facies during 10 years. Groundwater hardness, nitrate and sulfate pollution were identified in 2014, which was most likely caused by agricultural activities. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Contribution of the Multi Attribute Value Theory to conflict resolution in groundwater management. Application to the Mancha Oriental groundwater system, Spain

    Science.gov (United States)

    Apperl, B.; Andreu, J.; Karjalainen, T. P.; Pulido-Velazquez, M.

    2014-09-01

    The implementation of the EU Water Framework Directive demands participatory water resource management approaches. Decision making in groundwater quantity and quality management is complex because of the existence of many independent actors, heterogeneous stakeholder interests, multiple objectives, different potential policies, and uncertain outcomes. Conflicting stakeholder interests have been often identified as an impediment to the realization and success of water regulations and policies. The management of complex groundwater systems requires clarifying stakeholders' positions (identifying stakeholders preferences and values), improving transparency with respect to outcomes of alternatives, and moving the discussion from the selection of alternatives towards definition of fundamental objectives (value-thinking approach), what facilitates negotiation. The aims of the study are to analyse the potential of the multi attribute value theory for conflict resolution in groundwater management and to evaluate the benefit of stakeholder incorporation in the different stages of the planning process to find an overall satisfying solution for groundwater management. The research was conducted in the Mancha Oriental groundwater system (Spain), subject to an intensive use of groundwater for irrigation. A complex set of objectives and attributes were defined, and the management alternatives were created by a combination of different fundamental actions, considering different implementation stages and future changes in water resources availability. Interviews were conducted with representative stakeholder groups using an interactive platform, showing simultaneously the consequences of changes of preferences to the alternative ranking. Results show that the acceptation of alternatives depends strongly on the combination of measures and the implementation stages. Uncertainties of the results were notable but did not influence heavily on the alternative ranking. The expected

  14. Contribution of the multi-attribute value theory to conflict resolution in groundwater management - application to the Mancha Oriental groundwater system, Spain

    Science.gov (United States)

    Apperl, B.; Pulido-Velazquez, M.; Andreu, J.; Karjalainen, T. P.

    2015-03-01

    The implementation of the EU Water Framework Directive demands participatory water resource management approaches. Decision making in groundwater quantity and quality management is complex because of the existence of many independent actors, heterogeneous stakeholder interests, multiple objectives, different potential policies, and uncertain outcomes. Conflicting stakeholder interests have often been identified as an impediment to the realisation and success of water regulations and policies. The management of complex groundwater systems requires the clarification of stakeholders' positions (identifying stakeholder preferences and values), improving transparency with respect to outcomes of alternatives, and moving the discussion from the selection of alternatives towards the definition of fundamental objectives (value-thinking approach), which facilitates negotiation. The aims of the study are to analyse the potential of the multi-attribute value theory for conflict resolution in groundwater management and to evaluate the benefit of stakeholder incorporation into the different stages of the planning process, to find an overall satisfying solution for groundwater management. The research was conducted in the Mancha Oriental groundwater system (Spain), subject to intensive use of groundwater for irrigation. A complex set of objectives and attributes was defined, and the management alternatives were created by a combination of different fundamental actions, considering different implementation stages and future changes in water resource availability. Interviews were conducted with representative stakeholder groups using an interactive platform, showing simultaneously the consequences of changes in preferences to the alternative ranking. Results show that the approval of alternatives depends strongly on the combination of measures and the implementation stages. Uncertainties in the results were notable, but did not influence the alternative ranking heavily. The

  15. Contribution of the Multi Attribute Value Theory to conflict resolution in groundwater management. Application to the Mancha Oriental groundwater system, Spain

    Directory of Open Access Journals (Sweden)

    B. Apperl

    2014-09-01

    Full Text Available The implementation of the EU Water Framework Directive demands participatory water resource management approaches. Decision making in groundwater quantity and quality management is complex because of the existence of many independent actors, heterogeneous stakeholder interests, multiple objectives, different potential policies, and uncertain outcomes. Conflicting stakeholder interests have been often identified as an impediment to the realization and success of water regulations and policies. The management of complex groundwater systems requires clarifying stakeholders' positions (identifying stakeholders preferences and values, improving transparency with respect to outcomes of alternatives, and moving the discussion from the selection of alternatives towards definition of fundamental objectives (value-thinking approach, what facilitates negotiation. The aims of the study are to analyse the potential of the multi attribute value theory for conflict resolution in groundwater management and to evaluate the benefit of stakeholder incorporation in the different stages of the planning process to find an overall satisfying solution for groundwater management. The research was conducted in the Mancha Oriental groundwater system (Spain, subject to an intensive use of groundwater for irrigation. A complex set of objectives and attributes were defined, and the management alternatives were created by a combination of different fundamental actions, considering different implementation stages and future changes in water resources availability. Interviews were conducted with representative stakeholder groups using an interactive platform, showing simultaneously the consequences of changes of preferences to the alternative ranking. Results show that the acceptation of alternatives depends strongly on the combination of measures and the implementation stages. Uncertainties of the results were notable but did not influence heavily on the alternative ranking

  16. Estimation of groundwater recharge in sedimentary rock aquifer systems in the Oti basin of Gushiegu District, Northern Ghana

    Science.gov (United States)

    Afrifa, George Yamoah; Sakyi, Patrick Asamoah; Chegbeleh, Larry Pax

    2017-07-01

    Sustainable development and the management of groundwater resources for optimal socio-economic development constitutes one of the most effective strategies for mitigating the effects of climate change in rural areas where poverty is a critical cause of environmental damage. This research assessed groundwater recharge and its spatial and temporal variations in Gushiegu District in the Northern Region of Ghana, where groundwater is the main source of water supply for most uses. Isotopic data of precipitation and groundwater were used to infer the origin of groundwater and the possible relationship between groundwater and surface water in the partially metamorphosed sedimentary aquifer system in the study area. Though the data do not significantly establish strong relation between groundwater and surface water, the study suggests that groundwater in the area is of meteoric origin. However, the data also indicate significant enrichment of the heavy isotopes (18O and 2H) in groundwater relative to rainwater in the area. The Chloride Mass Balance (CMB) and Water Table Fluctuations (WTF) techniques were used to quantitatively estimate the groundwater recharge in the area. The results suggest groundwater recharge in a range of 13.9 mm/y - 218 mm/y, with an average of 89 mm/yr, representing about 1.4%-21.8% (average 8.9%) of the annual precipitation in the area. There is no clearly defined trend in the temporal variations of groundwater recharge in the area, but the spatial variations are discussed in relation to the underlying lithologies. The results suggest that the fraction of precipitation that reaches the saturated zone as groundwater recharge is largely controlled by the vertical hydraulic conductivities of the material of the unsaturated zone. The vertical hydraulic conductivity coupled with humidity variations in the area modulates the vertical infiltration and percolation of precipitation.

  17. Groundwater quality in the Northern Atlantic Coastal Plain aquifer system, eastern United States

    Science.gov (United States)

    Lindsey, Bruce; Belitz, Kenneth

    2017-01-19

    Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water. The Northern Atlantic Coastal Plain aquifer system constitutes one of the important areas being evaluated. One or more inorganic constituents with human-health benchmarks were detected at high concentrations in about 15 percent of the study area and at moderate concentrations in about 17 percent. Organic constituents were not detected at high concentrations in the study area.

  18. Site investigation SFR. Fracture mineralogy and geochemistry of borehole sections sampled for groundwater chemistry and Eh. Results from boreholes KFR01, KFR08, KFR10, KFR19, KFR7A and KFR105

    Energy Technology Data Exchange (ETDEWEB)

    Sandstroem, Bjoern (WSP Sverige AB (Sweden)); Tullborg, Eva-Lena (Terralogica AB, Grabo (Sweden))

    2011-01-15

    This report is part of the complementary site investigations for the future expansion of SFR. The report presents the results obtained during a detailed mineralogical and geochemical study of fracture minerals in drill cores from borehole section sampled for groundwater chemistry and where downhole Eh measurements have been performed. The groundwater redox system comprises not only the water, but also the bedrock/fracture mineral system in contact with this water. It is thus important to gain knowledge of the solid phases in contact with the groundwater, i.e. the fracture minerals. The samples studied for mineralogy and geochemistry, here reported, were selected to represent the fracture surfaces in contact with the groundwater in the sampled borehole sections and will give input to the hydrogeochemical model (SFR SDM). The mineralogy was determined using SEM-EDS and XRD and the geochemistry of fracture filling material was analysed by ICP-AES and ICP-QMS. The most common fracture minerals in the samples are mixed layer clay (smectite-illite), illite, chlorite, calcite, quartz, adularia and albite. Other minerals identified in the borehole sections include laumontite, pyrite, barite, chalcopyrite, hematite, Fe-oxyhydroxide, muscovite, REE-carbonate, allanite, biotite, asphaltite, galena, sphalerite, arsenopyrite, uranium phosphate, uranium silicate, Y-Ca silicate, monazite, xenotime, harmotome and fluorite. There are no major differences between the fracture mineralogy of the investigated borehole sections from SFR and the fracture mineralogy of the Forsmark site investigation area. The four fracture mineral generations distinguished within the Forsmark site investigation are also found at SFR. However, some differences have been observed: 1) Barite and uranium minerals are more common in the SFR fractures, 2) clay minerals like mixed layer illite-smectite and illite dominates in contrast to Forsmark where corrensite is by far the most common clay mineral and, 3

  19. Effects of sea-level rise on barrier island groundwater system dynamics: ecohydrological implications

    Science.gov (United States)

    Masterson, John P.; Fienen, Michael N.; Thieler, E. Robert; Gesch, Dean B.; Gutierrez, Benjamin T.; Plant, Nathaniel G.

    2014-01-01

    We used a numerical model to investigate how a barrier island groundwater system responds to increases of up to 60 cm in sea level. We found that a sea-level rise of 20 cm leads to substantial changes in the depth of the water table and the extent and depth of saltwater intrusion, which are key determinants in the establishment, distribution and succession of vegetation assemblages and habitat suitability in barrier islands ecosystems. In our simulations, increases in water-table height in areas with a shallow depth to water (or thin vadose zone) resulted in extensive groundwater inundation of land surface and a thinning of the underlying freshwater lens. We demonstrated the interdependence of the groundwater response to island morphology by evaluating changes at three sites. This interdependence can have a profound effect on ecosystem composition in these fragile coastal landscapes under long-term changing climatic conditions.

  20. June 2012 Groundwater Sampling at the Central Nevada Test Area (Data Validation Package)

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-03-01

    The U.S. Department of Energy Office of Legacy Management conducted annual sampling at the Central Nevada Test Area (CNTA) on June 26-27, 2012, in accordance with the 2004 Correction Action Decision Document/Corrective Action Plan for Corrective Action Unit 443: Central Nevada Test Area (CNTA)-Subsurface and the addendum to the "Corrective Action Decision Document/Corrective Action Plan" completed in 2008. Sampling and analysis were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351), continually updated).

  1. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    Energy Technology Data Exchange (ETDEWEB)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  2. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation

    NARCIS (Netherlands)

    De Biase, C.; Carminati, A.; Oswald, S.E.; Thullner, M.

    2013-01-01

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile l

  3. Lockheed Martin Energy Systems, Inc., Groundwater Program Office. Annual report for fiscal year 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-09-30

    This edition of the Lockheed Martin Energy Systems, Inc., (Energy Systems) Groundwater Program Annual Report summarizes the work carried out by the Energy Systems Groundwater Program Office (GWPO) for fiscal year (FY) 1994. The GWPO is responsible for coordination and oversight for all components of the groundwater programs at the three Oak Ridge facilities [Oak Ridge National Laboratory (ORNL), the Oak Ridge Y-12 Plant, and the Oak Ridge K-25 Site], as well as the Paducah and Portsmouth Gaseous Diffusion Plants (PGDP and PORTS, respectively.) This report describes the administrative framework of the GWPO including staffing, organization, and funding sources. In addition, summaries are provided of activities involving the Technical Support staff at the five facilities. Finally, the results of basic investigations designed to improve our understanding of the major processes governing groundwater flow and contaminant migration on the Oak Ridge Reservation (ORR) are reported. These investigations are conducted as part of the Oak Ridge Reservation Hydrology and Geology Studies (ORRHAGS) program. The relevance of these studies to the overall remediation responsibilities of Energy Systems is discussed.

  4. Transport of reactive carriers and contaminants in groundwater systems : a dynamic competitive happening

    NARCIS (Netherlands)

    Weerd, van de H.

    2000-01-01

    Transport of contaminants constitutes a potential threat for public health and ecosystems. One of the potential pathways for contaminant transport in groundwater systems is transport adsorbed to carriers (colloidal particles, large molecules). Figure 1 shows a detail of a

  5. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation

    NARCIS (Netherlands)

    De Biase, C.; Carminati, A.; Oswald, S.E.; Thullner, M.

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile

  6. Transport of reactive carriers and contaminants in groundwater systems : a dynamic competitive happening

    NARCIS (Netherlands)

    Weerd, van de H.

    2000-01-01

    Transport of contaminants constitutes a potential threat for public health and ecosystems. One of the potential pathways for contaminant transport in groundwater systems is transport adsorbed to carriers (colloidal particles, large molecules). Figure 1 shows a detail of a grou

  7. Sampling and analysis plan for the site characterization of the waste area Grouping 1 groundwater operable unit at Oak Ridge National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-11-01

    Waste Area Grouping (WAG) 1 at Oak Ridge National Laboratory (ORNL) includes all of the former ORNL radioisotope research, production, and maintenance facilities; former waste management areas; and some former administrative buildings. Site operations have contaminated groundwater, principally with radiological contamination. An extensive network of underground pipelines and utilities have contributed to the dispersal of contaminants to a known extent. In addition, karst geology, numerous spills, and pipeline leaks, together with the long and varied history of activities at specific facilities at ORNL, complicate contaminant migration-pathway analysis and source identification. To evaluate the extent of contamination, site characterization activity will include semiannual and annual groundwater sampling, as well as monthly water level measurements (both manual and continuous) at WAG 1. This sampling and analysis plan provides the methods and procedures to conduct site characterization for the Phase 1 Remedial Investigation of the WAG 1 Groundwater Operable Unit.

  8. Spatial Prediction and Optimized Sampling Design for Sodium Concentration in Groundwater.

    Science.gov (United States)

    Zahid, Erum; Hussain, Ijaz; Spöck, Gunter; Faisal, Muhammad; Shabbir, Javid; M AbdEl-Salam, Nasser; Hussain, Tajammal

    Sodium is an integral part of water, and its excessive amount in drinking water causes high blood pressure and hypertension. In the present paper, spatial distribution of sodium concentration in drinking water is modeled and optimized sampling designs for selecting sampling locations is calculated for three divisions in Punjab, Pakistan. Universal kriging and Bayesian universal kriging are used to predict the sodium concentrations. Spatial simulated annealing is used to generate optimized sampling designs. Different estimation methods (i.e., maximum likelihood, restricted maximum likelihood, ordinary least squares, and weighted least squares) are used to estimate the parameters of the variogram model (i.e, exponential, Gaussian, spherical and cubic). It is concluded that Bayesian universal kriging fits better than universal kriging. It is also observed that the universal kriging predictor provides minimum mean universal kriging variance for both adding and deleting locations during sampling design.

  9. Determination of submicrogram-per-liter concentrations of caffeine in surface water and groundwater samples by solid-phase extraction and liquid chromatography

    Science.gov (United States)

    Burkhardt, M.R.; Soliven, P.P.; Werner, S.L.; Vaught, D.G.

    1999-01-01

    A method for determining submicrogram-per-liter concentrations of caffeine in surface water and groundwater samples has been developed. Caffeine is extracted from a 1 L water sample with a 0.5 g graphitized carbon-based solid-phase cartridge, eluted with methylene chloride-methanol (80 + 20, v/v), and analyzed by liquid chromatography with photodiode-array detection. The single-operator method detection limit for organic-free water samples was 0.02 ??g/L. Mean recoveries and relative standard deviations were 93 ?? 13% for organicfree water samples fortified at 0.04 ??g/L and 84 ?? 4% for laboratory reagent spikes fortified at 0.5 ??g/L. Environmental concentrations of caffeine ranged from 0.003 to 1.44 ??g/L in surface water samples and from 0.01 to 0.08 ??g/L in groundwater samples.

  10. Data Validation Package August 2015 Groundwater Sampling at the Grand Junction, Colorado, Disposal Site October 2015

    Energy Technology Data Exchange (ETDEWEB)

    Frazier, William [U.S. Dept. of Energy, Washington, DC (United States). Office of Legacy Management; Baur, Gary [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2015-11-03

    Sampling Period: August 4, 2015. The 1998 Interim Long-Term Surveillance Plan for the Cheney Disposal Site Near Grand Junction, Colorado, requires annual monitoring to assess the performance of the disposal cell. Monitoring wells 0731, 0732, and 0733 were sampled as specified in the plan. Sampling and analyses were conducted in accordance with Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). The water level was measured at each sampled well. The water level in well 0733, located in the disposal cell, is lower than water levels in adjacent wells 0731 and 0732, indicating a hydraulic gradient toward the disposal cell. Results from this sampling event were generally consistent with results from the past as shown in the attached concentration-versus-time graphs. There have been no large changes in contaminant concentration observed over the last several years with the following exception. The uranium concentration in well 0733 has been trending upward since 2003. High uranium concentrations are expected in this well because it is located in the disposal cell. The selenium concentrations observed in wells 0731 and 0732 are elevated when compared to the disposal cell 0733. Wells 0731 and 0732 are completed at the alluvium/Mancos contact; here, elevated selenium concentrations are expected due to contributions from the Mancos shale.

  11. The groundwater buffering effect on heat waves and precipitation: coupled groundwater-atmosphere simulations over Europe and North America with a WRF-LEAFHYDRO system.

    Science.gov (United States)

    Miguez-Macho, Gonzalo; Gómez, Breogán; Regueiro-Sanfiz, Sabela; Georgescu, Matei

    2016-04-01

    We present coupled atmosphere-hydrology simulations with the WRF regional climate model and the LEAFHYDRO LSM, including groundwater dynamics. Simulations are carried out for the coupled system for the growing season (February to October) over Europe at 2.5km resolution over land and 20km over the atmosphere. Initial conditions for the land surface, groundwater and rivers are from 10 year off-line simulations, performed continuously over the same domain and period, forced by atmospheric data from the Earth2Observe FP7 project. We show that the presence of a shallow water table over portions of the European continent enhances evapotranspiration in dry periods under increasing atmospheric demand. The impact of the coupling between groundwater and the soil vegetation system on land surface fluxes results in decreases in air temperature and an increase in low level mixing ratios, which under certain convective regimes induces more precipitation. We illustrate for the heat wave of 2003 that models that do not include this groundwater buffering effect may enhance significantly the intensity of such temperature extreme cases. The effect on precipitation is mostly seen over inland areas where warm season convection is important. We show with results of additional simulations over North America, where summer convection over the interior of the continent is very relevant, that the effect of groundwater-enhanced evapotranspiration may have a sizeable impact on climate at the global scale.

  12. Genesis and transport of hexavalent chromium in the system ophiolitic rocks - groundwater

    Science.gov (United States)

    Shchegolikhina, Anastasia; Guadagnini, Laura; Guadagnini, Alberto

    2015-04-01

    Our study aims at contributing to the quantification and characterization of chromium transport processes from host rocks and soil matrices to groundwater. We focus on dissolved hexavalent chromium detected in groundwaters of geological regions with ophiolitic rocks (ophiolites and serpentinites) inclusions due to its critical ecological impact. (Oze et al., 2004). Despite the large number of analyses on the occurrence of high concentrations of hazardous hexavalent chromium ions in natural waters, only few studies were performed with the objective of identifying and investigating the geochemical reactions which could occur in the natural system rock - groundwater - dissolved chromium (Fantoni et al., 2002, Stephen and James, 2004, Lelli et al., 2013). In this context, there is a need for integration of results obtained from diverse studies in various regions and settings to improve our knowledge repository. Our theoretical analyses are grounded and driven by practical scenarios detected in subsurface reservoirs exploited for civil and industrial use located in the Emilia-Romagna region (Italy). Available experimental datasets are complemented with data from other international regional-scale settings (Altay mountains region, Russia). Modeling of chromium transformation and migration particularly includes characterization of the multispecies geochemical system. A key aspect of our study is the analysis of the complex competitive sorption processes governing heavy metal evolution in groundwater. The results of the research allow assessing the critical qualitative features of the mechanisms of hexavalent chromium ion mobilization from host rocks and soils and the ensuing transformation and migration to groundwater under the influence of diverse environmental factors. The study is then complemented by the quantification of the main sources of uncertainty associated with prediction of heavy metal contamination levels in the groundwater system explored. Fantoni, D

  13. Predicting groundwater flow system discharge in the river network at the watershed scale

    Science.gov (United States)

    Caruso, Alice; Ridolfi, Luca; Boano, Fulvio

    2016-04-01

    The interaction between rivers and aquifers affects the quality and the quantity of surface and subsurface water since it plays a crucial role for solute transport, nutrient cycling and microbial transformations. The groundwater-surface water interface, better known as hyporheic zone, has a functional significance for the biogeochemical and ecological conditions of the fluvial ecosystem since it controls the flux of groundwater solutes discharging into rivers, and vice versa. The hyporheic processes are affected by the complex surrounding aquifer because the groundwater flow system obstructs the penetration of stream water into the sediments. The impact of large-scale stream-aquifer interactions on small scale exchange has generally been analyzed at local scales of a river reach, or even smaller. However, a complete comprehension of how hyporheic fluxes are affected by the groundwater system at watershed scale is still missing. Evaluating this influence is fundamental to predict the consequences of hyporheic exchange on water quality and stream ecology. In order to better understand the actual structure of hyporheic exchange along the river network, we firstly examine the role of basin topography complexity in controlling river-aquifer interactions. To reach this target, we focus on the analysis of surface-subsurface water exchange at the watershed scale, taking into account the river-aquifer interactions induced by landscape topography. By way of a mathematical model, we aim to improve the estimation of the role of large scale hydraulic gradients on hyporheic exchange. The potential of the method is demonstrated by the analysis of a benchmark case's study, which shows how the topographic conformation influences the stream-aquifer interaction and induces a substantial spatial variability of the groundwater discharge even among adjacent reaches along the stream. The vertical exchange velocity along the river evidences a lack of autocorrelation. Both the groundwater

  14. Reducing the predictive uncertainty associated with groundwater management decision-making in the Perth regional aquifer system of Western Australia

    Science.gov (United States)

    Siade, A. J.

    2015-12-01

    The Perth Regional Aquifer Model (PRAMS) framework has been used for about a decade now to evaluate the potential anthropogenic impacts associated with management decisions that affect Perth's groundwater resources. A great wealth of data, expertise and numerical analysis have gone into the development of PRAMS over the years. However, there has been little quantitative work conducted on systemically addressing the uncertainty in the model's structure and predictions. PRAMS is designed to make a variety of regional and local-scale predictions and, both the nature and magnitude of the uncertainty associated with these predictions can vary significantly. A primary prediction to be addressed using the PRAMS framework, will be the effects of various deep-aquifer groundwater management scenarios on both the environmental and social concerns surrounding the superficial aquifer, which supports sensitive wetlands, and the negative impacts of seawater intrusion into the deep aquifers. A particular model-structure component that greatly affects the predictions associated with deep-aquifer groundwater extraction is the characterization of the local fault structure, i.e., whether or not faults are acting as barriers to groundwater flow. Therefore, uncertainty in fault characterization can subsequently lead to significant predictive uncertainty. However, new observation data can be obtained to reduce this uncertainty. In this study, an experimental design methodology is employed to optimally acquire new observations of state in such a way as to maximize the information obtained about the hydraulic properties of faults. Various information criteria are employed to develop optimal locations of new observation wells. The A-optimality criterion was found to be the most effective for comparing sampling strategies given the design assumptions, which include the parameter sets employed, hydraulic forcing, temporal considerations, and the use of the existing observation network. A

  15. Sampling Instruction: Investigation of Hexavalent Chromium Flux to Groundwater at the 100-C-7:1 Excavation Site

    Energy Technology Data Exchange (ETDEWEB)

    Truex, Michael J.; Vermeul, Vincent R.

    2012-05-01

    Several types of data are needed to assess the flux of Cr(VI) from the excavation into the groundwater. As described in this plan, these data include (1) temporal Cr(VI) data in the shallow groundwater beneath the pit; (2) hydrologic data to interpret groundwater flow and contaminant transport; (3) hydraulic gradient data; and (4) as a contingency action if necessary, vertical profiling of Cr(VI) concentrations in the shallow aquifer beyond the depth possible with aquifer tubes.

  16. Chloride in Groundwater and Surface Water in Areas Underlain by the Glacial Aquifer System, Northern United States

    Science.gov (United States)

    Mullaney, John R.; Lorenz, David L.; Arntson, Alan D.

    2009-01-01

    A study of chloride in groundwater and surface water was conducted for the glacial aquifer system of the northern United States in forested, agricultural, and urban areas by analyzing data collected for the National Water-Quality Assessment Program from 1991 to 2004. Groundwater-quality data from a sampling of 1,329 wells in 19 states were analyzed. Chloride concentrations were greater than the secondary maximum contaminant level established by the U.S. Environmental Protection Agency of 250 milligrams per liter in 2.5 percent of samples from 797 shallow monitoring wells and in 1.7 percent of samples from 532 drinking-water supply wells. Water samples from shallow monitoring wells in urban areas had the largest concentration of chloride, followed by water samples from agricultural and forested areas (medians of 46, 12, and 2.9 milligrams per liter, respectively). An analysis of chloride:bromide ratios, by mass, and chloride concentrations compared to binary mixing curves for dilute groundwater, halite, sewage and animal waste, potassium chloride fertilizer, basin brines, seawater, and landfill leachate in samples from monitoring wells indicated multiple sources of chloride in samples from wells in urban areas and agricultural areas. Water from shallow monitoring wells in urban areas had the largest chloride:bromide ratio, and samples with chloride:bromide ratios greater than 1,000 and chloride concentrations greater than 100 milligrams per liter were dominated by halite; however, the samples commonly contained mixtures that indicated input from sewage or animal waste. Chloride:bromide ratios were significantly larger in samples from public-supply drinking-water wells than from private drinking-water wells, and ratios were significantly larger in all drinking-water wells in eastern and central regions of the glacial aquifer system than in west-central and western regions of the glacial aquifer system. Surface-water-quality data collected regularly during varying

  17. Simulated groundwater flow paths, travel time, and advective transport of nitrogen in the Kirkwood-Cohansey aquifer system, Barnegat Bay–Little Egg Harbor Watershed, New Jersey

    Science.gov (United States)

    Voronin, Lois M.; Cauller, Stephen J.

    2017-07-31

    Elevated concentrations of nitrogen in groundwater that discharges to surface-water bodies can degrade surface-water quality and habitats in the New Jersey Coastal Plain. An analysis of groundwater flow in the Kirkwood-Cohansey aquifer system and deeper confined aquifers that underlie the Barnegat Bay–Little Egg Harbor (BB-LEH) watershed and estuary was conducted by using groundwater-flow simulation, in conjunction with a particle-tracking routine, to provide estimates of groundwater flow paths and travel times to streams and the BB-LEH estuary.Water-quality data from the Ambient Groundwater Quality Monitoring Network, a long-term monitoring network of wells distributed throughout New Jersey, were used to estimate the initial nitrogen concentration in recharge for five different land-use classes—agricultural cropland or pasture, agricultural orchard or vineyard, urban non-residential, urban residential, and undeveloped. Land use at the point of recharge within the watershed was determined using a geographic information system (GIS). Flow path starting locations were plotted on land-use maps for 1930, 1973, 1986, 1997, and 2002. Information on the land use at the time and location of recharge, time of travel to the discharge location, and the point of discharge were determined for each simulated flow path. Particle-tracking analysis provided the link from the point of recharge, along the particle flow path, to the point of discharge, and the particle travel time. The travel time of each simulated particle established the recharge year. Land use during the year of recharge was used to define the nitrogen concentration associated with each flow path. The recharge-weighted average nitrogen concentration for all flow paths that discharge to the Toms River upstream from streamflow-gaging station 01408500 or to the BB-LEH estuary was calculated.Groundwater input into the Barnegat Bay–Little Egg Harbor estuary from two main sources— indirect discharge from base

  18. Sample collection system for gel electrophoresis

    Science.gov (United States)

    Olivares, Jose A.; Stark, Peter C.; Dunbar, John M.; Hill, Karen K.; Kuske, Cheryl R.; Roybal, Gustavo

    2004-09-21

    An automatic sample collection system for use with an electrophoretic slab gel system is presented. The collection system can be used with a slab gel have one or more lanes. A detector is used to detect particle bands on the slab gel within a detection zone. Such detectors may use a laser to excite fluorescently labeled particles. The fluorescent light emitted from the excited particles is transmitted to low-level light detection electronics. Upon the detection of a particle of interest within the detection zone, a syringe pump is activated, sending a stream of buffer solution across the lane of the slab gel. The buffer solution collects the sample of interest and carries it through a collection port into a sample collection vial.

  19. Characterization of the shallow groundwater system in an alpine watershed: Handcart Gulch, Colorado, USA

    Science.gov (United States)

    Kahn, K.G.; Ge, S.; Caine, J.S.; Manning, A.

    2008-01-01

    Water-table elevation measurements and aquifer parameter estimates are rare in alpine settings because few wells exist in these environments. Alpine groundwater systems may be a primary source of recharge to regional groundwater flow systems. Handcart Gulch is an alpine watershed in Colorado, USA comprised of highly fractured Proterozoic metamorphic and igneous rocks with wells completed to various depths. Primary study objectives include determining hydrologic properties of shallow bedrock and surficial materials, developing a watershed water budget, and testing the consistency of measured hydrologic properties and water budget by constructing a simple model incorporating groundwater and surface water for water year 2005. Water enters the study area as precipitation and exits as discharge in the trunk stream or potential recharge for the deeper aquifer. Surficial infiltration rates ranged from 0.1-6.2??0-5 m/s. Discharge was estimated at 1.28??10-3 km3. Numerical modeling analysis of single-well aquifer tests predicted lower specific storage in crystalline bedrock than in ferricrete and colluvial material (6.7??10-5-2.10??0-3 l/m). Hydraulic conductivity in crystalline bedrock was significantly lower than in colluvial and alluvial material (4.3??10-9 -2.0??10-4 m/s). Water budget results suggest that during normal precipitation and temperatures water is available to recharge the deeper groundwater flow system. ?? Springer-Verlag 2007.

  20. DETERMINATION OF CHLOROPHENOLS, NITROPHENOLS, AND METHYLPHENOLS IN GROUND-WATER SAMPLES USING HIGH PERFORMANCE LIQUID CHROMATOGRAPHY

    Science.gov (United States)

    A high performance liquid chromatography (HPLC) method was developed to quantitatively determine phenolic compounds and their isomers in aqueous samples. The HPLC method can analyze a mixture of 15 contaminants in the same analytical run with an analysis time of 25 minutes. The...

  1. Groundwater-quality data in 12 GAMA study units: Results from the 2006–10 initial sampling period and the 2008–13 trend sampling period, California GAMA Priority Basin Project

    Science.gov (United States)

    Mathany, Timothy M.

    2017-03-09

    The Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) program was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey in cooperation with the California State Water Resources Control Board. From 2004 through 2012, the GAMA-PBP collected samples and assessed the quality of groundwater resources that supply public drinking water in 35 study units across the State. Selected sites in each study unit were sampled again approximately 3 years after initial sampling as part of an assessment of temporal trends in water quality by the GAMA-PBP. Twelve of the study units, initially sampled during 2006–11 (initial sampling period) and sampled a second time during 2008–13 (trend sampling period) to assess temporal trends, are the subject of this report.The initial sampling was designed to provide a spatially unbiased assessment of the quality of untreated groundwater used for public water supplies in the 12 study units. In these study units, 550 sampling sites were selected by using a spatially distributed, randomized, grid-based method to provide spatially unbiased representation of the areas assessed (grid sites, also called “status sites”). After the initial sampling period, 76 of the previously sampled status sites (approximately 10 percent in each study unit) were randomly selected for trend sampling (“trend sites”). The 12 study units sampled both during the initial sampling and during the trend sampling period were distributed among 6 hydrogeologic provinces: Coastal (Northern and Southern), Transverse Ranges and Selected Peninsular Ranges, Klamath, Modoc Plateau and Cascades, and Sierra Nevada Hydrogeologic Provinces. For the purposes of this trend report, the six hydrogeologic provinces were grouped into two hydrogeologic regions based on location: Coastal and Mountain.The groundwater samples were analyzed for a number of synthetic organic

  2. Potential structural barriers to ground-water flow, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital dataset defines the surface traces of regional geologic structures designated as potential ground-water flow barriers in an approximately 45,000...

  3. Potential structural barriers to ground-water flow, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital dataset defines the surface traces of regional geologic structures designated as potential ground-water flow barriers in an approximately 45,000...

  4. 234U/238U isotope data from groundwater and solid-phase leachate samples near Tuba City Open Dump, Tuba City, Arizona

    Science.gov (United States)

    Johnson, Raymond H.; Horton, Robert J.; Otton, James K.; Ketterer, Michael K.

    2012-01-01

    This report releases 234U/238U isotope data, expressed as activity ratios, and uranium concentration data from analyses completed at Northern Arizona University for groundwater and solid-phase leachate samples that were collected in and around Tuba City Open Dump, Tuba City, Arizona, in 2008.

  5. Design and evaluation of a field study on the contamination of selected volatile organic compounds and wastewater-indicator compounds in blanks and groundwater samples

    Science.gov (United States)

    Thiros, Susan A.; Bender, David A.; Mueller, David K.; Rose, Donna L.; Olsen, Lisa D.; Martin, Jeffrey D.; Bernard, Bruce; Zogorski, John S.

    2011-01-01

    The Field Contamination Study (FCS) was designed to determine the field processes that tend to result in clean field blanks and to identify potential sources of contamination to blanks collected in the field from selected volatile organic compounds (VOCs) and wastewater-indicator compounds (WICs). The VOCs and WICs analyzed in the FCS were detected in blanks collected by the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program during 1996-2008 and 2002-08, respectively. To minimize the number of variables, the study required ordering of supplies just before sampling, storage of supplies and equipment in clean areas, and use of adequate amounts of purge-and-trap volatile-grade methanol and volatile pesticide-grade blank water (VPBW) to clean sampling equipment and to collect field blanks. Blanks and groundwater samples were collected during 2008-09 at 16 sites, which were a mix of water-supply and monitoring wells, located in 9 States. Five different sample types were collected for the FCS at each site: (1) a source-solution blank collected at the USGS National Water Quality Laboratory (NWQL) using laboratory-purged VPBW, (2) source-solution blanks collected in the field using laboratory-purged VPBW, (3) source-solution blanks collected in the field using field-purged VPBW, (4) a field blank collected using field-purged VPBW, and (5) a groundwater sample collected from a well. The source-solution blank and field-blank analyses were used to identify, quantify, and document extrinsic contamination and to help determine the sources and causes of data-quality problems that can affect groundwater samples. Concentrations of compounds detected in FCS analyses were quantified and results were stored in the USGS National Water Information System database after meeting rigorous identification and quantification criteria. The study also utilized information provided by laboratory analysts about evidence indicating the presence of selected compounds

  6. "Groundwater ages" of the Lake Chad multi-layer aquifers system inferred from 14C and 36Cl data

    Science.gov (United States)

    Bouchez, Camille; Deschamps, Pierre; Goncalves, Julio; Hamelin, Bruno; Seidel, Jean-Luc; Doumnang, Jean-Claude

    2014-05-01

    Assessment of recharge, paleo-recharge and groundwater residence time of aquifer systems of the Sahel is pivotal for a sustainable management of this vulnerable resource. Due to its stratified aquifer system, the Lake Chad Basin (LCB) offers the opportunity to assess recharge processes over time and to link climate and hydrology in the Sahel. Located in north-central Africa at the fringe between the Sahel and the Sahara, the lake Chad basin (LCB) is an endorheic basin of 2,5.106 km2. With a monsoon climate, the majority of the rainfall occurs in the southern one third of the basin, the Chari/Logone River system transporting about 90% of the runoff generated within the drainage basin. A complex multi-layer aquifer system is located in the central part of the LCB. The Quaternary unconfined aquifer, covering 500 000 km2, is characterized by the occurrence of poorly understood piezometric depressions. Artesian groundwaters are found in the Plio-Pleistocene lacustrine and deltaic sedimentary aquifers (early Pliocene and Continental Terminal). The present-day lake is in hydraulic contact with the Quaternary Aquifer, but during past megalake phases, most of the Quaternary aquifer was submerged and may experience major recharge events. To identify active recharge area and assess groundwater dynamics, one hundred surface and groundwater samples of all layers have been collected over the southern part of the LCB. Major and trace elements have been analyzed. Measurements of 36Cl have been carried out at CEREGE, on the French 5 MV AMS National Facility ASTER and 14C activities have been analyzed for 17 samples on the French AMS ARTEMIS. Additionally, the stable isotopic composition was measured on the artesian aquifer samples. In the Quaternary aquifer, results show a large scatter with waters having very different isotopic and geochemical signature. In its southern part and in the vicinity of the surface waters, groundwaters are predominantly Ca-Mg-HCO3 type waters with very

  7. Overview of groundwater sources and water-supply systems, and associated microbial pollution, in Finland, Norway and Iceland

    Science.gov (United States)

    Kløve, Bjørn; Kvitsand, Hanne Margrethe Lund; Pitkänen, Tarja; Gunnarsdottir, Maria J.; Gaut, Sylvi; Gardarsson, Sigurdur M.; Rossi, Pekka M.; Miettinen, Ilkka

    2017-06-01

    The characteristics of groundwater systems and groundwater contamination in Finland, Norway and Iceland are presented, as they relate to outbreaks of disease. Disparities among the Nordic countries in the approach to providing safe drinking water from groundwater are discussed, and recommendations are given for the future. Groundwater recharge is typically high in autumn or winter months or after snowmelt in the coldest regions. Most inland aquifers are unconfined and therefore vulnerable to pollution, but they are often without much anthropogenic influence and the water quality is good. In coastal zones, previously emplaced marine sediments may confine and protect aquifers to some extent. However, the water quality in these aquifers is highly variable, as the coastal regions are also most influenced by agriculture, sea-water intrusion and urban settlements resulting in challenging conditions for water abstraction and supply. Groundwater is typically extracted from Quaternary deposits for small and medium municipalities, from bedrock for single households, and from surface water for the largest cities, except for Iceland, which relies almost entirely on groundwater for public supply. Managed aquifer recharge, with or without prior water treatment, is widely used in Finland to extend present groundwater resources. Especially at small utilities, groundwater is often supplied without treatment. Despite generally good water quality, microbial contamination has occurred, principally by norovirus and Campylobacter, with larger outbreaks resulting from sewage contamination, cross-connections into drinking water supplies, heavy rainfall events, and ingress of polluted surface water to groundwater.

  8. Overview of groundwater sources and water-supply systems, and associated microbial pollution, in Finland, Norway and Iceland

    Science.gov (United States)

    Kløve, Bjørn; Kvitsand, Hanne Margrethe Lund; Pitkänen, Tarja; Gunnarsdottir, Maria J.; Gaut, Sylvi; Gardarsson, Sigurdur M.; Rossi, Pekka M.; Miettinen, Ilkka

    2017-03-01

    The characteristics of groundwater systems and groundwater contamination in Finland, Norway and Iceland are presented, as they relate to outbreaks of disease. Disparities among the Nordic countries in the approach to providing safe drinking water from groundwater are discussed, and recommendations are given for the future. Groundwater recharge is typically high in autumn or winter months or after snowmelt in the coldest regions. Most inland aquifers are unconfined and therefore vulnerable to pollution, but they are often without much anthropogenic influence and the water quality is good. In coastal zones, previously emplaced marine sediments may confine and protect aquifers to some extent. However, the water quality in these aquifers is highly variable, as the coastal regions are also most influenced by agriculture, sea-water intrusion and urban settlements resulting in challenging conditions for water abstraction and supply. Groundwater is typically extracted from Quaternary deposits for small and medium municipalities, from bedrock for single households, and from surface water for the largest cities, except for Iceland, which relies almost entirely on groundwater for public supply. Managed aquifer recharge, with or without prior water treatment, is widely used in Finland to extend present groundwater resources. Especially at small utilities, groundwater is often supplied without treatment. Despite generally good water quality, microbial contamination has occurred, principally by norovirus and Campylobacter, with larger outbreaks resulting from sewage contamination, cross-connections into drinking water supplies, heavy rainfall events, and ingress of polluted surface water to groundwater.

  9. Improved aquifer characterization and the optimization of the design of brackish groundwater desalination systems

    KAUST Repository

    Malivaa, Robert G.

    2011-07-01

    Many water scarce regions possess brackish-water resources that can be desalted to provide alternative water supplies. Brackish groundwater desalination by reverse osmosis (RO) is less expensive than seawater systems because of reduced energy and pretreatment requirements and lesser volumes of concentrate that require disposal. Development of brackish groundwater wellfields include the same hydraulic issues that affect conventional freshwater wellfields. Managing well interference and prevention of adverse impacts such as land subsidence are important concerns. RO systems are designed to treat water whose composition falls within a system-specific envelope of salinities and ion concentrations. A fundamental requirement for the design of brackish groundwater RO systems is prediction of the produced water chemistry at both the start of pumping and after 10-20 years of operation. Density-dependent solute-transport modeling is thus an integral component of the design of brackish groundwater RO systems. The accuracy of groundwater models is dependent upon the quality of the hydrogeological data upon which they are based. Key elements of the aquifer characterization are the determination of the three-dimensional distribution of salinity within the aquifer and the evaluation of aquifer heterogeneity with respect to hydraulic conductivity. It is necessary to know from where in a pumped aquifer (or aquifer zone) water is being produced and the contribution of vertical flow to the produced water. Unexpected, excessive vertical migration (up-coning) of waters that are more saline has adversely impacted some RO systems because the salinity of the water delivered to the system exceeded the system design parameters. Improved aquifer characterization is possible using advanced geophysical techniques, which can, in turn, lead to more accurate solute-transport models. Advanced borehole geophysical logs, such as nuclear magnetic resonance, were run as part of the exploratory test

  10. Distribution of atrazine in a crop-soil-groundwater system at Baiyangdian Lake area in China

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, the concentration distribution and environmentalfate of atrazine in a crop-soil-groundwater system at Baiyangdian Lake area of North China were studied. The concentration of the herbicide in spatial and vertical soils, and in roots, stem, leaf, corncob and kernel of corn, and in groundwater were measured by HPLC. The results showed that the variation of spatial concentration of atrazine in soil can be described by first-order kinetics equation which has a half-life of 360 days and a rate constant of 0.0019d-1. The vertical variation of atrazine concentration with soil depth follows the exponential decay law. After 120 days following atrazine application, the mass distributions of this herbicide in crop-soil-groundwater system are 71% in soil, 20% in groundwater and 1% in crop respectively, and 8% due to loss by degradation or often removal processes. The order of atrazine concentration in every part of corn crop is in roots>in corncob>in kernel of corn>in leaf.

  11. Estimation of radon concentration in soil and groundwater samples of Northern Rajasthan, India

    Directory of Open Access Journals (Sweden)

    Sudhir Mittal

    2016-04-01

    Full Text Available In the present investigation, analysis of radon concentration in 20 water and soil samples collected from different locations of Bikaner and Jhunjhunu districts of Rajasthan, India has been carried out by using RAD7 an electronic Radon detector. The measured radon concentration in water samples lies in the range from 0.50 to 22 Bq l−1 with the mean value of 4.42 Bq l−1, which lies within the safe limit from 4 to 40 Bq l−1 recommended by United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR, 2008. The total annual effective dose estimated due to radon concentration in water ranges from 1.37 to 60.06 μSV y−1 with the mean value of 12.08 μSV y−1, which is lower than the safe limit 0.1 mSv y−1 as set by World Health Organization (WHO, 2004 and European Council (EU, 1998. Radon measurement in soil samples varies from 941 to 10,050 Bq m−3 with the mean value of 4561 Bq m−3, which lies within the range reported by other investigators. It was observed that the soil and water of Bikaner and Jhunjhunu districts are suitable for drinking and construction purpose without posing any health hazard.

  12. A Comprehensive Software System for Interactive, Real-time, Visual 3D Deterministic and Stochastic Groundwater Modeling

    Science.gov (United States)

    Li, S.

    2002-05-01

    Taking advantage of the recent developments in groundwater modeling research and computer, image and graphics processing, and objected oriented programming technologies, Dr. Li and his research group have recently developed a comprehensive software system for unified deterministic and stochastic groundwater modeling. Characterized by a new real-time modeling paradigm and improved computational algorithms, the software simulates 3D unsteady flow and reactive transport in general groundwater formations subject to both systematic and "randomly" varying stresses and geological and chemical heterogeneity. The software system has following distinct features and capabilities: Interactive simulation and real time visualization and animation of flow in response to deterministic as well as stochastic stresses. Interactive, visual, and real time particle tracking, random walk, and reactive plume modeling in both systematically and randomly fluctuating flow. Interactive statistical inference, scattered data interpolation, regression, and ordinary and universal Kriging, conditional and unconditional simulation. Real-time, visual and parallel conditional flow and transport simulations. Interactive water and contaminant mass balance analysis and visual and real-time flux update. Interactive, visual, and real time monitoring of head and flux hydrographs and concentration breakthroughs. Real-time modeling and visualization of aquifer transition from confined to unconfined to partially de-saturated or completely dry and rewetting Simultaneous and embedded subscale models, automatic and real-time regional to local data extraction; Multiple subscale flow and transport models Real-time modeling of steady and transient vertical flow patterns on multiple arbitrarily-shaped cross-sections and simultaneous visualization of aquifer stratigraphy, properties, hydrological features (rivers, lakes, wetlands, wells, drains, surface seeps), and dynamically adjusted surface flooding area

  13. Research about the Control of Geological Structure on Karst Groundwater system in Zhangfang, Beijing,China.

    Science.gov (United States)

    Qiao, X.

    2015-12-01

    Carbonate formations are intensively distributed throughout Zhangfang, fangshan, in West Mountain area in Beijing. Karst groundwater exits among the geological fracture network which is characterized by the different arrangements and levels in different types of fracture networks and structures. The influence of the tectonic environment on the dynamic change rule and the enrichment regulation of karst system is significant for the exploitation and protection of karst groundwater resources. From the control function of fault and fracture point of view, based on the developmental and distribution pattern of multi-episodic tectonism, this study analyzed fractures in the three-fold structural units characterized by NE-NW and NS trends and discussed the influence of multi-episodic tectonism on the groundwater flow system and rich water zones. The results showed that the geological fracture underwent two episodes of tectonism, thrusting nappe in the Jurassic and extension in the Cretaceous. The overprint of two episodes resulted in a number of faults with high hydraulic conductivity, which serve as conduits. The superiority joints groups are in the NE and NW directions, with conjugated characteristics. The high-angle or vertical dips directly benefit infiltration. The fractures in the intersection areas have formed groundwater runoff channels and strong space, controlling water-rich zones such as Baidai, Ganchi-Changgou and Gaozhuang-Shiwo. Magmatic rock and the aquiclude also contribute to the rich water zones and the location of springs, all of which have important significance for water supply. Keywords: system of Karst groundwater, geological structure, fracture network, hydrogeological flow field, Zhangfang karst area

  14. Screening of sustainable groundwater sources for integration into a regional drought-prone water supply system

    Directory of Open Access Journals (Sweden)

    H. Lucas

    2009-07-01

    Full Text Available This paper reports on the qualitative and quantitative screening of groundwater sources for integration into the public water supply system of the Algarve, Portugal. The results are employed in a decision support system currently under development for an integrated water resources management scheme in the region. Such a scheme is crucial for several reasons, including the extreme seasonal and annual variations in rainfall, the effect of climate change on more frequent and long-lasting droughts, the continuously increasing water demand and the high risk of a single-source water supply policy. The latter was revealed during the severe drought of 2004 and 2005, when surface reservoirs were depleted and the regional water demand could not be met, despite the drilling of emergency wells.

    For screening and selection, quantitative criteria are based on aquifer properties and well yields, whereas qualitative criteria are defined by water quality indices. These reflect the well's degree of violation of drinking water standards for different sets of variables, including toxicity parameters, nitrate and chloride, iron and manganese and microbiological parameters. Results indicate the current availability of at least 1100 l s−1 of high quality groundwater (55% of the regional demand, requiring only disinfection (900 l s−1 or basic treatment, prior to human consumption. These groundwater withdrawals are sustainable when compared to mean annual recharge, considering that at least 40% is preserved for ecological demands. A more accurate and comprehensive analysis of sustainability is performed with the help of steady-state and transient groundwater flow simulations, which account for aquifer geometry, boundary conditions, recharge and discharge rates, pumping activity and seasonality. They permit an advanced analysis of present and future scenarios and show that increasing water demands and decreasing rainfall will make

  15. Screening of sustainable groundwater sources for integration into a regional drought-prone water supply system

    Directory of Open Access Journals (Sweden)

    T. Y. Stigter

    2009-01-01

    Full Text Available This paper reports on the qualitative and quantitative screening of groundwater sources for integration into the public water supply system of the Algarve, Portugal. The results are employed in a decision support system currently under development for an integrated water resources management scheme in the region. Such a scheme is crucial for several reasons, including the extreme seasonal and annual variations in rainfall, the effect of climate change on more frequent and long-lasting droughts, the continuously increasing water demand and the high risk of a single-source water supply policy. The latter was revealed during the severe drought of 2004 and 2005, when surface reservoirs were depleted and the regional water demand could not be met, despite the drilling of emergency wells.

    For screening and selection, quantitative criteria are based on aquifer properties and well yields, whereas qualitative criteria are defined by water quality indices. These reflect the well's degree of violation of drinking water standards for different sets of variables, including toxicity parameters, nitrate and chloride, iron and manganese and microbiological parameters. Results indicate the current availability of at least 1100 l s−1 of high quality groundwater (55% of the regional demand, requiring only disinfection (900 l s−1 or basic treatment, prior to human consumption. These groundwater withdrawals are sustainable when compared to mean annual recharge, considering that at least 40% is preserved for ecological demands. A more accurate and comprehensive analysis of sustainability is performed with the help of steady-state and transient groundwater flow simulations, which account for aquifer geometry, boundary conditions, recharge and discharge rates, pumping activity and seasonality. They permit an advanced analysis of present and future scenarios and show that increasing water demands and decreasing rainfall will make

  16. Simulation of groundwater flow in the glacial aquifer system of northeastern Wisconsin with variable model complexity

    Science.gov (United States)

    Juckem, Paul F.; Clark, Brian R.; Feinstein, Daniel T.

    2017-05-04

    The U.S. Geological Survey, National Water-Quality Assessment seeks to map estimated intrinsic susceptibility of the glacial aquifer system of the conterminous United States. Improved understanding of the hydrogeologic characteristics that explain spatial patterns of intrinsic susceptibility, commonly inferred from estimates of groundwater age distributions, is sought so that methods used for the estimation process are properly equipped. An important step beyond identifying relevant hydrogeologic datasets, such as glacial geology maps, is to evaluate how incorporation of these resources into process-based models using differing levels of detail could affect resulting simulations of groundwater age distributions and, thus, estimates of intrinsic susceptibility.This report describes the construction and calibration of three groundwater-flow models of northeastern Wisconsin that were developed with differing levels of complexity to provide a framework for subsequent evaluations of the effects of process-based model complexity on estimations of groundwater age distributions for withdrawal wells and streams. Preliminary assessments, which focused on the effects of model complexity on simulated water levels and base flows in the glacial aquifer system, illustrate that simulation of vertical gradients using multiple model layers improves simulated heads more in low-permeability units than in high-permeability units. Moreover, simulation of heterogeneous hydraulic conductivity fields in coarse-grained and some fine-grained glacial materials produced a larger improvement in simulated water levels in the glacial aquifer system compared with simulation of uniform hydraulic conductivity within zones. The relation between base flows and model complexity was less clear; however, the relation generally seemed to follow a similar pattern as water levels. Although increased model complexity resulted in improved calibrations, future application of the models using simulated particle

  17. Screening of sustainable groundwater sources for integration into a regional drought-prone water supply system

    Science.gov (United States)

    Stigter, T. Y.; Monteiro, J. P.; Nunes, L. M.; Vieira, J.; Cunha, M. C.; Ribeiro, L.; Nascimento, J.; Lucas, H.

    2009-07-01

    This paper reports on the qualitative and quantitative screening of groundwater sources for integration into the public water supply system of the Algarve, Portugal. The results are employed in a decision support system currently under development for an integrated water resources management scheme in the region. Such a scheme is crucial for several reasons, including the extreme seasonal and annual variations in rainfall, the effect of climate change on more frequent and long-lasting droughts, the continuously increasing water demand and the high risk of a single-source water supply policy. The latter was revealed during the severe drought of 2004 and 2005, when surface reservoirs were depleted and the regional water demand could not be met, despite the drilling of emergency wells. For screening and selection, quantitative criteria are based on aquifer properties and well yields, whereas qualitative criteria are defined by water quality indices. These reflect the well's degree of violation of drinking water standards for different sets of variables, including toxicity parameters, nitrate and chloride, iron and manganese and microbiological parameters. Results indicate the current availability of at least 1100 l s-1 of high quality groundwater (55% of the regional demand), requiring only disinfection (900 l s-1) or basic treatment, prior to human consumption. These groundwater withdrawals are sustainable when compared to mean annual recharge, considering that at least 40% is preserved for ecological demands. A more accurate and comprehensive analysis of sustainability is performed with the help of steady-state and transient groundwater flow simulations, which account for aquifer geometry, boundary conditions, recharge and discharge rates, pumping activity and seasonality. They permit an advanced analysis of present and future scenarios and show that increasing water demands and decreasing rainfall will make the water supply system extremely vulnerable, with a high

  18. Modeling Multiple Stresses Placed Upon A Groundwater System In A Semi-Arid Brackish Environment

    Science.gov (United States)

    Toll, M.; Salameh, E.; Sauter, M.

    2008-12-01

    In semi-arid areas groundwater systems are frequently not sufficiently characterized hydrogeologically and long term data records are generally not available. Long-term time series are necessary, however to design future groundwater abstraction scenarios or to predict the influence of future climate change effects on groundwater resources. To overcome these problems an integrated approach for the provision of a reliable database based on sparse and fuzzy data is proposed. This integrated approach is demonstrated in the lowermost area of the Jordan Valley. The Jordan Valley is part of the Jordan Dead Sea Wadi Araba Rift Valley, which extends from the Red Sea to lake Tiberias and beyond with a major 107 km sinistral strike-slip fault between the Arabian plate to the east and the northeastern part of the African plate to the west. Due to extensional forces a topographic depression was formed. As a result of an arid environment it is filled with evaporites, lacustrine sediments, and clastic fluvial components. A subtropical climate with hot, dry summers and mild humid winters with low amounts of rainfall provide excellent farming conditions. Therefore the Jordan Valley is considered as the food basket of Jordan and is used intensively for agriculture. As a result hundreds of shallow wells were drilled and large amounts of groundwater were abstracted since groundwater is the major source for irrigation. Consequently groundwater quality decreased rapidly since the sixties and signs of overpumping and an increase in soil salinity could clearly be seen. In order to achieve a sustainable state of water resources and to quantify the impact of climate change on water resources a proper assessment of the groundwater resources as well as their quality is a prerequisite. In order to sufficiently describe the complex hydrogeologic flow system an integrated approach, combining geological, geophysical, hydrogeological, historical, and chemical methods was chosen. The aquifer

  19. Improved Understanding of Sources of Variability in Groundwater Sampling for Long-Term Monitoring Programs

    Science.gov (United States)

    2013-02-01

    Lab Sample ID: 600-44501-11 Acetone 1100 RL 1000 ug/L 8260B Total/ NA200 MDL 200 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Benzene 8260B...8260B Total/ NA200 MDL 22 Analyte Result Qualifier Unit Dil Fac D Method Prep Type Trichloroethene - DL 8260B Total/NA1100 200 ug/L 20036 cis-1,2...L 8260B Total/ NA200 MDL 200 Benzene 8260B Total/NA7100 200 ug/L 20016 Chlorobenzene 8260B Total/NA2200 200 ug/L 20024 Chloroform 8260B Total/NA57 J

  20. Application of the freeze-dried bioluminescent bioreporter Pseudomonas putida mt-2 KG1206 to the biomonitoring of groundwater samples from monitoring wells near gasoline leakage sites.

    Science.gov (United States)

    Ko, Kyung-Seok; Kong, In Chul

    2017-02-01

    This study examined the applicability of a freeze-dried bioluminescent bioreporter, Pseudomonas putida mt-2 KG1206 (called KG1206), to the biomonitoring of groundwater samples. Samples were collected from the monitoring wells of gas station tanks or old pipeline leakage sites in Korea. In general, the freeze-dried strain in the presence of pure inducer chemicals showed low bioluminescence activity and a different activity order compared with that of the subcultured strain. The effects of KNO3 as a bioluminescence stimulant were observed on the pure inducers and groundwater samples. The stimulation rates varied according to the type of inducers and samples, ranging from 2.2 to 20.5 times (for pure inducers) and from 1.1 to 11 times (for groundwater samples) the total bioluminescence of the control. No considerable correlations were observed between the bioluminescence intensity of the freeze-dried strain and the inducer concentrations in the samples (R (2) < 0.1344). However, samples without a high methyl tertiary butyl ether (MTBE) level and those from the gas station leakage site showed reasonable correlations with the bioluminescence activity with R (2) values of 0.3551 and 0.4131, respectively. These results highlight the potential of using freeze-dried bioluminescent bacteria as a rapid, simple, and portable tool for the preliminary biomonitoring of specific pollutants at contaminated sites.

  1. Effects of climate change on groundwater: observed and forecasted trends on Italian systems

    Science.gov (United States)

    Doveri, Marco; Menichini, Matia; Provenzale, Antonello; Scozzari, Andrea

    2017-04-01

    Groundwater represents the main source of water supply at global level. In Italy, as well as in most European countries, water needs are mainly covered by groundwater exploitation. The reliance on this resource is continuously growing, given the key role that groundwater plays for mitigating the climate change/variability and for addressing the significant increase in the global water demand. Despite this, and unlike surface waters, groundwater bodies have not been widely studied, and there is a general paucity of quantitative information, especially in relation to climate change. Although groundwater systems are more resilient to climate change than surface waters, they are affected both directly and indirectly. The estimation of the entity of these effects is mandatory for a reliable management of this crucial resource. The analysis of hydro-meteorological data over a few decades highlights that also the Italian territory is experiencing a change of the climate regime. Besides the increase of mean annual temperature, observed in particular since the early 1980s, longer and more frequent drought periods have been registered, as well as an increase of extreme events characterized by heavy rainfall. It is also noticeable a decrease in total rainfall, that is much more evident in the period from January to June. In addition to the reduced yearly inputs from precipitation, such trends determine also a lower snow accumulation and earlier snow melt in mountain areas, a general increase of evapotranspiration rates and an increased runoff fraction of the effective rainfall amount. As flood hydrographs of several major Italian rivers (e.g., Po, Brenta and Arno rivers) confirm, evident effects concern surface water resources. The main observed phenomena consist in the decline of mean annual discharge, the increase of extreme events with high discharge concentrated in short periods, and longer and earlier periods of low base flow. Impacts on groundwater recharge are not well

  2. Ground-water hydraulics, regional flow, and ground-water development of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama

    Science.gov (United States)

    Bush, Peter W.; Johnston, Richard H.

    1988-01-01

    The Floridan aquifer system is one of the major sources of groundwater supplies in the United States. This productive aquifer system underlies all of Florida, southeast Georgia, and small parts of adjoining Alabama and South Carolina, for a total area of about 100,000 square miles. About 3 billion gallons of water per day were withdrawn from the aquifer system in 1980, and in many areas the Floridan is the sole source of freshwater.

  3. Harpoon-based sample Acquisition System

    Science.gov (United States)

    Bernal, Javier; Nuth, Joseph; Wegel, Donald

    2012-02-01

    Acquiring information about the composition of comets, asteroids, and other near Earth objects is very important because they may contain the primordial ooze of the solar system and the origins of life on Earth. Sending a spacecraft is the obvious answer, but once it gets there it needs to collect and analyze samples. Conceptually, a drill or a shovel would work, but both require something extra to anchor it to the comet, adding to the cost and complexity of the spacecraft. Since comets and asteroids are very low gravity objects, drilling becomes a problem. If you do not provide a grappling mechanism, the drill would push the spacecraft off the surface. Harpoons have been proposed as grappling mechanisms in the past and are currently flying on missions such as ROSETTA. We propose to use a hollow, core sampling harpoon, to act as the anchoring mechanism as well as the sample collecting device. By combining these two functions, mass is reduced, more samples can be collected and the spacecraft can carry more propellant. Although challenging, returning the collected samples to Earth allows them to be analyzed in laboratories with much greater detail than possible on a spacecraft. Also, bringing the samples back to Earth allows future generations to study them.

  4. Plan for proposed aquifer hydraulic testing and groundwater sampling at Everest, Kansas, in January-February 2006.

    Energy Technology Data Exchange (ETDEWEB)

    LaFreniere, L. M.; Environmental Science Division

    2006-01-31

    On September 8-9, 2005, representatives of the Kansas Department of Health and Environment (KDHE), the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA), and Argonne National Laboratory met at the KDHE's offices in Topeka to review the status of the CCC/USDA's environmental activities in Kansas. A key CCC/USDA goal for this meeting was to obtain KDHE input on the selection of possible remedial approaches to be examined as part of the Corrective Action Study (CAS) for this site. As a result of the September meeting, the KDHE recommended several additional activities for the Everest site, to further assist in selecting and evaluating remedial alternatives for the CAS. The requested actions included the following: (1) Construction of several additional interpretive cross sections to improve the depiction of the hydrogeologic characteristics affecting groundwater and contaminant movement along the apparent main plume migration pathway to the north-northwest of the former CCC/USDA facility, and in the vicinity of the Nigh property. (2) Identification of potential locations for several additional monitoring wells, to better constrain the apparent western and northwestern margins of the existing groundwater plume. (3) Development of technical recommendations for a stepwise pumping study of the Everest aquifer unit in the area near and to the north of the Nigh property. On October 21, 2005, Argonne issued a brief Cross Section Analysis (Argonne 2006a) addressing these concerns, on behalf of the CCC/USDA. This report includes the following: (1) Preliminary recommendations for the siting of three new monitoring wells, at locations identified by the KDHE. Argonne also suggested, however, that the installation and sampling of these wells be deferred until after completion of the CAS evaluation. (2) A proposed strategy for testing of the Everest aquifer unit near the Nigh property, involving initial test pumping of the former Nigh domestic

  5. Modelling Urban diffuse pollution in groundwater

    Science.gov (United States)

    Jato, Musa; Smith, Martin; Cundy, Andrew

    2017-04-01

    Diffuse urban pollution of surface and ground waters is a growing concern in many cities and towns. Traffic-derived pollutants such as salts, heavy metals and polycyclic aromatic hydrocarbons (PAHs) may wash off road surfaces in soluble or particulate forms which later drain through soils and drainage systems into surface waters and groundwater. In Brighton, about 90% of drinking water supply comes from groundwater (derived from the Brighton Chalk block). In common with many groundwater sources the Chalk aquifer has been relatively extensively monitored and assessed for diffuse rural contaminants such as nitrate, but knowledge on the extent of contamination from road run-off is currently lacking. This project examines the transfer of traffic-derived contaminants from the road surface to the Chalk aquifer, via urban drainage systems. A transect of five boreholes have been sampled on a monthly basis and groundwater samples analysed to examine the concentrations of key, mainly road run-off derived, hydrocarbon and heavy metal contaminants in groundwater across the Brighton area. Trace concentrations of heavy metals and phenols have been observed in groundwater. Electrical conductivity changes in groundwater have also been used to assess local changes in ionic strength which may be associated with road-derived contaminants. This has been supplemented by systematic water and sediment sampling from urban gully pots, with further sampling planned from drainage and settlement ponds adjacent to major roads, to examine initial road to drainage system transport of major contaminants.

  6. Alpine Groundwater - Pristine Aquifers Under Threat?

    Science.gov (United States)

    Schneider, P.; Lange, A.

    2014-12-01

    Glacier and permafrost retreat are prominent climate change indicators. However, the characteristics of climate and hydrology in mountain areas remain poorly understood relative to lowland areas. Specifically, not much is known about alpine groundwater, its recharge and water quality variations, as these remote reservoirs are rarely monitored. As global temperatures rise, glaciers and permafrost will continue to retreat forming new sediment deposits and changing infiltration conditions in high alpine terrain. Climate change impacts the hydro-chemical composition of alpine waters, accelerates weathering processes, and potentially triggers mobilization of pollutants. Accordingly, we monitored groundwater quantity and quality parameters of an alpine porous aquifer near the Tiefenbach glacier in the Gotthard Massif in Switzerland. The goal of this research was to assess quality and seasonal storage dynamics of groundwater above the timberline (2000 m). To translate hydrological science into an ecosystem service context, we focused on four attributes: Water quantity: observations of groundwater level fluctuations combined with analysis of contributing water sources based on stable isotope analysis to give a quantitative understanding of origin and amount of water, Water quality: groundwater level, groundwater temperature and electrical conductivity were used as proxies for sampling of hydro-chemical parameters with automated water samplers during primary groundwater recharge periods (snowmelt and rainfall events), Location: Alpine terrain above the timberline, especially recharge into/out of an alpine porous aquifer at a pro-glacial floodplain and Date of annual melt (albedo effect) and timing of flow (snow- and icemelt from May to September) and groundwater recharge during the growing season. The study found that the summer groundwater temperatures depend on the date of annual melt and are more sensitive to climate forcing than lowland groundwater temperatures

  7. Regional Groundwater Processes and Flow Dynamics from Age Tracer Data

    Science.gov (United States)

    Morgenstern, Uwe; Stewart, Mike K.; Matthews, Abby

    2016-04-01

    Age tracers are now used in New Zealand on regional scales for quantifying the impact and lag time of land use and climate change on the quantity and quality of available groundwater resources within the framework of the National Policy Statement for Freshwater Management 2014. Age tracers provide measurable information on the dynamics of groundwater systems and reaction rates (e.g. denitrification), essential for conceptualising the regional groundwater - surface water system and informing the development of land use and groundwater flow and transport models. In the Horizons Region of New Zealand, around 200 wells have tracer data available, including tritium, SF6, CFCs, 2H, 18O, Ar, N2, CH4 and radon. Well depths range from shallower wells in gravel aquifers in the Horowhenua and Tararua districts, and deeper wells in the aquifers between Palmerston North and Wanganui. Most of the groundwater samples around and north of the Manawatu River west of the Tararua ranges are extremely old (>100 years), even from relatively shallow wells, indicating that these groundwaters are relatively disconnected from fresh surface recharge. The groundwater wells in the Horowhenua tap into a considerably younger groundwater reservoir with groundwater mean residence time (MRT) of 10 - 40 years. Groundwater along the eastern side of the Tararua and Ruahine ranges is significantly younger, typically groundwater recharge rates, as deduced from groundwater depth and MRT, are extremely low in the central coastal area, consistent with confined groundwater systems, or with upwelling of old groundwater close to the coast. Very low vertical recharge rates along the Manawatu River west of the Manawatu Gorge indicate upwelling groundwater conditions in this area, implying groundwater discharge into the river is more likely here than loss of river water into the groundwater system. High recharge rates observed at several wells in the Horowhenua area and in the area east of the Tararua and

  8. Model reduction in coupled groundwater-surface water systems - potentials and limitations of the applied proper orthogonal decomposition (POD) method

    Science.gov (United States)

    Gosses, Moritz; Moore, Catherine; Wöhling, Thomas

    2016-04-01

    The complexity of many groundwater-surface water models often results in long model run times even on today's computer systems. This becomes even more problematic in combination with the necessity of (many) repeated model runs for parameter estimation and later model purposes like predictive uncertainty analysis or monitoring network optimization. Model complexity reduction is a promising approach to reduce the computational effort of physically-based models. Its impact on the conservation of uncertainty as determined by the (more) complex model is not well known, though. A potential under-estimation of predictive uncertainty has, however, a significant impact on model applications such as model-based monitoring network optimization. Can we use model reduction techniques to significantly reduce run times of highly complex groundwater models and yet estimate accurate uncertainty levels? Our planned research project hopes to assess this question and apply model reduction to non-linear groundwater systems. Several encouraging model simplification methods have been developed in recent years. To analyze their respective performance, we will choose three different model reduction methods and apply them to both synthetic and real-world test cases to benchmark their computational efficiency and prediction accuracy. The three methods for benchmarking will be proper orthogonal decomposition (POD) (following Siade et al. 2010), the eigenmodel method (Sahuquillo et al. 1983) and inversion-based upscaling (Doherty and Christensen, 2011). In a further step, efficient model reduction methods for application to non-linear groundwater-surface water systems will be developed and applied to monitoring network optimization. In a first step we present here one variant of the implementation and benchmarking of the POD method. POD reduces model complexity by working in a subspace of the model matrices resulting from spatial discretization with the same significant eigenvalue spectrum

  9. Ammonia-oxidizing bacteria and archaea in groundwater treatment and drinking water distribution systems.

    Science.gov (United States)

    van der Wielen, Paul W J J; Voost, Stefan; van der Kooij, Dick

    2009-07-01

    The ammonia-oxidizing prokaryote (AOP) community in three groundwater treatment plants and connected distribution systems was analyzed by quantitative real-time PCR and sequence analysis targeting the amoA gene of ammonia-oxidizing bacteria (AOB) and archaea (AOA). Results demonstrated that AOB and AOA numbers increased during biological filtration of ammonia-rich anoxic groundwater, and AOP were responsible for ammonium removal during treatment. In one of the treatment trains at plant C, ammonia removal correlated significantly with AOA numbers but not with AOB numbers. Thus, AOA were responsible for ammonia removal in water treatment at one of the studied plants. Furthermore, an observed negative correlation between the dissolved organic carbon (DOC) concentration in the water and AOA numbers suggests that high DOC levels might reduce growth of AOA. AOP entered the distribution system in numbers ranging from 1.5 x 10(3) to 6.5 x 10(4) AOPs ml(-1). These numbers did not change during transport in the distribution system despite the absence of a disinfectant residual. Thus, inactive AOP biomass does not seem to be degraded by heterotrophic microorganisms in the distribution system. We conclude from our results that AOA can be commonly present in distribution systems and groundwater treatment, where they can be responsible for the removal of ammonia.

  10. Ground-water flow and quality in Wisconsin's shallow aquifer system

    Science.gov (United States)

    Kammerer, P.A.

    1995-01-01

    The areal concentration distribution of commonmineral constituents and properties of ground water in Wisconsin's shallow aquifer system are described in this report. Maps depicting the water quality and the altitude of the water table are included. The shallow aquifer system in Wisconsin, composed of unconsolidated sand and gravel and shallow bedrock, is the source of most potable ground-water supplies in the State. Most ground water in the shallow aquifer system moves in local flow systems, but it interacts with regional flow systems in some areas.

  11. Forsmark site investigation. Hydrochemical monitoring of groundwaters and surface waters. Results from water sampling in the Forsmark area, January-December 2009

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Ann-Chatrin (ed.); Berg, Cecilia; Harrstroem, Johan; Joensson, Stig; Thur, Pernilla (Geosigma AB (Sweden)); Borgiel, Micke; Qvarfordt, Susanne (Sveriges Vattenekologer AB (Sweden))

    2010-09-15

    The fifth year (2009) of hydrochemical monitoring of groundwaters, surface waters and precipitation in Forsmark is documented in the report. The hydrochemical monitoring programme 2009 included water sampling from: - percussion- and core boreholes equipped with installations for long-term pressure monitoring, tracer tests and water sampling in packed off borehole sections, sampling and analysis performed twice (spring and autumn), - near surface groundwaters (sampling four times a year), - private wells (once per year in October), - surface waters (eleven sampling occasions per year). Due to the somewhat different performance of the hydrogeochemical monitoring of the deep groundwaters during the autumn 2009 compared to previous years, some new findings and knowledge were obtained: 1) Removal of water volumes corresponding to three to five times the volume of the borehole section (the routine procedure) is seldom enough to obtain a complete exchange of the water present in the borehole section when the pumping starts. 2) It is likely that the elevated sulphide concentrations observed in the monitoring programme /1/ is due to contamination from initial water present in the borehole sections when the pumping starts. This water may have a very high sulphide concentration. Dirty water in tubes and in stand pipes may also contribute to the enhanced sulphide concentration. 3) Plug flow calculations will be introduced in the future as a new routine procedure to estimate the water volumes to be removed, in order to exchange the section water volume, prior to groundwater sampling in delimited borehole sections. During the autumn sampling, sample series of five samples per sampling location were collected during continuous pumping in thirteen selected borehole sections. Furthermore, special efforts were put on cleaning of stand pipes and exchange of water prior to sampling. The analytical protocol was rather extensive and included sulphide and uranium analyses for each sample

  12. GROUNDWATER QUALITY EVALUATION OF PERMANENT PRESERVATION AREAS (GUARANI AQUIFER SYSTEM - GAS, RIO PARDO HYDROGRAPHICAL BASIN, RS, BRAZIL

    Directory of Open Access Journals (Sweden)

    Adilson Ben da Costa

    2010-06-01

    Full Text Available The aim of this research was to evaluate the quality of groundwater in areas of permanent preservation (Guarani Aquifer System – GAS in the Rio Pardo Hydrographical Basin, RS, Brazil, using physical, chemical and microbiological variables, based on resolution no. 396/2008 of the National Council on the Environment - CONAMA. Nine sampling points were distributed throughout the basin, where groundwater was classified as the major ions through the Piper diagram. The results indicated that most of the wells evaluated were classified in Class 4, accounting for water uses less restrictive. However, it should be considered that the aquifers are characterize by different geological conditions, having intrinsical physical, chemical and biological variables with hydrogeochemical variations, requiring that their quality levels are often based on these characteristics, as noted in diagram Piper, where the samples P1, P2, P3, P5 and P9 were classified as calcium bicarbonate, the waters of the points P4, P6, P7 as sodium bicarbonate and P8 as sulfated. It was found that the quality of water from wells with depths less than 6 m are becoming more vulnerable due to anthropogenic activities, as showing by the concentration of nitrate, total and thermotolerant coliforms, while the quality of water from deeper wells basically depends on their hydrogeological and hydrogeochemical characteristics based on the concentration of sodium and sulfate variables. However, they also showed contamination by human activities, mainly by the nitrate variable.

  13. Standard sample supply system; Hyojun shiryo kyokyu system

    Energy Technology Data Exchange (ETDEWEB)

    Osaka, S. [Center for Coal Utilization Japan, Tokyo (Japan)

    1997-03-20

    More than 20 universities and research institutes participate in the study of developing basic technology of coal utilization, and the `Standard sample supply system` prepares, keeps and supplys standard samples so that common samples can be used in the study. Coal samples of 50 to 100 will be prepared for 5 years. A coal sample is about 160 kg. The samples are collected from coal yards of big consumers such as power stations, etc. and coal suppliers. How to smash and keep coal are also described. Main facilities and machinery and their specification are given. Each standard sample is analyzed by means of the coal and ash analysis method of JIS and the data are distributed. The items of the analysis are shown in table. A database system will be prepared by the end of 1996. 2 figs., 2 tabs.

  14. Mobile Variable Depth Sampling System Design Study

    Energy Technology Data Exchange (ETDEWEB)

    BOGER, R.M.

    2000-08-25

    A design study is presented for a mobile, variable depth sampling system (MVDSS) that will support the treatment and immobilization of Hanford LAW and HLW. The sampler can be deployed in a 4-inch tank riser and has a design that is based on requirements identified in the Level 2 Specification (latest revision). The waste feed sequence for the MVDSS is based on Phase 1, Case 3S6 waste feed sequence. Technical information is also presented that supports the design study.

  15. EUGRIS: ''European Substainable Land and Groundwater Management Information System''

    Energy Technology Data Exchange (ETDEWEB)

    Frauenstein, J. [Federal Environmental Agency (UBA), Berlin (Germany)

    2003-07-01

    The presentation outlines and Accompanying Measure with the FP 5 to develop an web based EUropean Sustainable Land and GRoundwater Management Information System information system (EUGRIS). The management of contaminated land and groundwater requires an interdisciplinary approach and a considerable amount of supporting technical information and knowledge. EUGRIS will provide a generally available comprehensive and overarching information and innovation resource, to support both research and practical contaminated land and groundwater management. EUGRI is a gateway to provide a 'one stop shop' for information provided by research projects, legislation, standards, best practice and other technical guidance and policy/regulatory publications from the EC, participating Member and Accession States and from various international networks dealing with groundwater and land management issues. Different types of user can access information through different windows according to their needs. EUGRIS will provide its visitors with summary information (digests) and links to sources of more detailed and/or original information in a scaleable holistic and contexturally meaningful way. EUGRIS is being built in three stages: the design of the information system, the development of its software implementation, and the population of the system with information. The presentation is focussed on the concept of the development of the information system with the individual work packages. In the second part of the lecture in particular the work procedures are presented for the content wise replenishment by EUGRIS. The data collation for the proven pilot countries and the production of a European research data base, which opens contents and results of European-wide locked and current projects, form the emphasis thereby. (orig.)

  16. Identifying three-dimensional nested groundwater flow systems in a Tóthian basin

    Science.gov (United States)

    Wang, Xu-Sheng; Wan, Li; Jiang, Xiao-Wei; Li, Hailong; Zhou, Yangxiao; Wang, Junzhi; Ji, Xiaohui

    2017-10-01

    Nested groundwater flow systems have been revealed in Tóth's theory as the structural property of basin-scale groundwater circulation but were only well known with two-dimensional (2D) profile models. The method of searching special streamlines across stagnation points for partitioning flow systems, which has been successfully applied in the 2D models, has never been implemented for three-dimensional (3D) Tóthian basins because of the difficulty in solving the dual stream functions. Alternatively, a new method is developed to investigate 3D nested groundwater flow systems without determination of stagnation points. Connective indices are defined to quantify the connection between individual recharge and discharge zones along streamlines. Groundwater circulation cells (GWCCs) are identified according to the distribution of the connective indices and then grouped into local, intermediate and regional flow systems. This method requires existing solution of the flow velocity vector and is implemented via particle tracking technique. It is applied in a hypothetical 3D Tóthian basin with an analytical solution of the flow field and in a real-world basin with a numerical modeling approach. Different spatial patterns of flow systems compared to 2D profile models are found. The outcrops boundaries of GWCCs on water table may significantly deviate from and are not parallel to the nearby water table divides. Topological network is proposed to represent the linked recharge-discharge zones through closed and open GWCCs. Sensitivity analysis indicates that the development of GWCCs depends on the basin geometry, hydraulic parameters and water table shape.

  17. Deep Groundwater Circulation within Crystalline Basement Rocks and the Role of Hydrologic Windows in the Formation of the Truth or Consequences, New Mexico Low-Temperature Geothermal System

    Science.gov (United States)

    Pepin, J.; Person, M. A.; Phillips, F. M.; Kelley, S.; Timmons, S.; Owens, L.; Witcher, J. C.; Gable, C. W.

    2014-12-01

    Hot Springs are common in amagmatic settings, but the mechanisms of heating are often obscure. We have investigated the origin of the Truth or Consequences, New Mexico low-temperature (~ 41 °C) hot springs in the southern Rio Grande rift. We tested two mechanisms that could account for the geothermal anomaly. The first scenario is that the anomaly is the result of lateral forced convection associated with a gently-dipping carbonate aquifer. The second scenario is that high permeability of crystalline basement rocks permits circulation of groundwater down to depths of 8 km prior to discharging in Truth or Consequences. To test these hypotheses, we constructed a two-dimensional hydrothermal model of the region using FEMOC. Model parameters were constrained by calibrating to measured temperatures, specific discharge rates and groundwater residence times. We collected 16 temperature profiles, 11 geochemistry samples and 6 carbon-14 samples within the study area. The geothermal waters are Na+/Cl- dominated and have apparent groundwater ages ranging from 5,500 to 11,500 years. Hot Springs geochemistry is consistent with water/rock interaction in a silicate geothermal reservoir, rather than a carbonate system. Peclet-number analysis of temperature profiles suggests specific discharge rates beneath Truth or Consequences range from 2 to 4 m/year. Geothermometry indicates maximum reservoir temperatures are around 167 °C. We were able to reasonably reproduce observed measurements using the permeable-basement scenario (10-12 m2). The carbonate-aquifer scenario failed to match observations. Our findings imply that the Truth or Consequences geothermal system formed as a result of deep groundwater circulation within permeable crystalline basement rocks. Focused geothermal discharge is the result of localized faulting, which has created a hydrologic window through a regional confining unit. In tectonically active areas, deep groundwater circulation within fractured crystalline

  18. Groundwater Flow Systems and Their Response to Climate Change: A Need for a Water-System View Approach

    Directory of Open Access Journals (Sweden)

    Joel J. Carrillo-Rivera

    2012-01-01

    Full Text Available Problem statement: The interest in early hydrogeological studies was the aquifer unit, as it is the physical media that stores and permits groundwater transfers from the recharge zone to the discharge zone, making groundwater available to boreholes for water extraction. Approach: Recently, the aquifer concept has been complemented by the groundwater flow system theory, where groundwater may be defined by local, intermediate and regional flow systems. This implies that groundwater may travel from one aquifer unit to another aquifer unit (or more located above or below the former. Water in a local flow system takes months or several years to travel from the recharge to the discharge zone. These flows usually transfer the best natural quality water, so a reduction in precipitation would lessen recharge and diminish stored water, making them more vulnerable to contamination and variability in climatic conditions. Thus, there is a need to define local flows and to enhance actions to protect them from contamination and inefficient extraction. Results: In contrast to local flows, intermediate and regional flows travel from a region, or country, into another, with their recharge processes usually taking place in a zone located far away from the discharge zone (natural or by boreholes. There is a need of groundwater flow systems evaluation by means of an integrated wide system-view analysis of partial evidence represented by surface (soil and vegetation covers as well as hydraulic, isotopic and chemical groundwater characterization in the related geological media where the depth of actual basement rock is paramount as well as discharge areas. The flow system definition may assist in extraction management strategies to control related issues as subsidence, obtained the water quality change, desiccation of springs and water bodies, soil erosion, flooding response, contamination processes in recharge areas, among others; many of which could be efficiently

  19. Characterizing the interaction of groundwater and surface water in the karst aquifer of Fangshan, Beijing (China)

    Science.gov (United States)

    Chu, Haibo; Wei, Jiahua; Wang, Rong; Xin, Baodong

    2016-12-01

    Correct understanding of groundwater/surface-water (GW-SW) interaction in karst systems is of greatest importance for managing the water resources. A typical karst region, Fangshan in northern China, was selected as a case study. Groundwater levels and hydrochemistry analyses, together with isotope data based on hydrogeological field investigations, were used to assess the GW-SW interaction. Chemistry data reveal that water type and the concentration of cations in the groundwater are consistent with those of the surface water. Stable isotope ratios of all samples are close to the local meteoric water line, and the 3H concentrations of surface water and groundwater samples are close to that of rainfall, so isotopes also confirm that karst groundwater is recharged by rainfall. Cross-correlation analysis reveals that rainfall leads to a rise in groundwater level with a lag time of 2 months and groundwater exploitation leads to a fall within 1 month. Spectral analysis also reveals that groundwater level, groundwater exploitation and rainfall have significantly similar response periods, indicating their possible inter-relationship. Furthermore, a multiple nonlinear regression model indicates that groundwater level can be negatively correlated with groundwater exploitation, and positively correlated with rainfall. The overall results revealed that groundwater level has a close correlation with groundwater exploitation and rainfall, and they are indicative of a close hydraulic connection and interaction between surface water and groundwater in this karst system.

  20. Characterizing the interaction of groundwater and surface water in the karst aquifer of Fangshan, Beijing (China)

    Science.gov (United States)

    Chu, Haibo; Wei, Jiahua; Wang, Rong; Xin, Baodong

    2017-03-01

    Correct understanding of groundwater/surface-water (GW-SW) interaction in karst systems is of greatest importance for managing the water resources. A typical karst region, Fangshan in northern China, was selected as a case study. Groundwater levels and hydrochemistry analyses, together with isotope data based on hydrogeological field investigations, were used to assess the GW-SW interaction. Chemistry data reveal that water type and the concentration of cations in the groundwater are consistent with those of the surface water. Stable isotope ratios of all samples are close to the local meteoric water line, and the 3H concentrations of surface water and groundwater samples are close to that of rainfall, so isotopes also confirm that karst groundwater is recharged by rainfall. Cross-correlation analysis reveals that rainfall leads to a rise in groundwater level with a lag time of 2 months and groundwater exploitation leads to a fall within 1 month. Spectral analysis also reveals that groundwater level, groundwater exploitation and rainfall have significantly similar response periods, indicating their possible inter-relationship. Furthermore, a multiple nonlinear regression model indicates that groundwater level can be negatively correlated with groundwater exploitation, and positively correlated with rainfall. The overall results revealed that groundwater level has a close correlation with groundwater exploitation and rainfall, and they are indicative of a close hydraulic connection and interaction between surface water and groundwater in this karst system.

  1. Recovery data for surface water, groundwater and lab reagent samples analyzed by the USGS National Water Quality Laboratory schedule 2437, water years 2013-15

    Science.gov (United States)

    Shoda, Megan E.; Nowell, Lisa H.; Bexfield, Laura M.; Sandstrom, Mark W.; Stone, Wesley W.

    2017-01-01

    Analytical recovery is the concentration of an analyte measured in a water-quality sample expressed as a percentage of the known concentration added to the sample (Mueller and others, 2015). Analytical recovery (hereafter referred to as “recovery”) can be used to understand method bias and variability and to assess the temporal changes in a method over time (Martin and others, 2009). This data set includes two tables: one table of field spike recovery data and one table of lab reagent spike recovery data. The table of field spike recovery data includes results from paired environmental and spike samples collected by the National Water Quality Program, National Water-Quality Assessment (NAWQA) Project in surface water and groundwater. These samples were collected as part of the NAWQA Project’s National Water Quality Network: Rivers and Streams assessment, Regional Stream Quality Assessment studies and in multiple groundwater networks following standard practices (Mueller and others, 1997).  This table includes environmental and spike water-quality sample data stored in the USGS National Water Information System (NWIS) database (https://dx.doi.org/10.5066/F7P55KJN). Concentrations of pesticides in spike samples, while stored in the NWIS database, are not publically available. The calculation of recovery based on these field sample data is outlined in Mueller and others (2015). Lab reagent spikes are pesticide-free reagent water spiked with a known concentration of pesticide. Lab reagent spikes are prepared in the lab and their recovery can be directly measured. The table of lab reagent spike data contains quality control sample information stored in the USGS National Water Quality Laboratory (NWQL) database. Both tables include fields for data-quality indicators that are described in the data processing steps of this metadata file. These tables were developed in order to support a USGS Scientific Investigations Report with the working title

  2. Artificial groundwater recharge as integral part of a water resources system in a humid environment

    Science.gov (United States)

    Kupfersberger, Hans; Stadler, Hermann

    2010-05-01

    In Graz, Austria, artificial groundwater recharge has been operated as an integral part of the drinking water supply system for more than thirty years. About 180 l/s of high quality water from pristine creeks (i.e. no pre-treatment necessary) are infiltrated via sand and lawn basins and infiltration trenches into two phreatic aquifers to sustain the extraction of approximately 400 l/s. The remaining third of drinking water for roughly 300.000 people is provided by a remote supply line from the East alpine karst region Hochschwab. By this threefold model the water supply system is less vulnerable to external conditions. In the early 1980's the infiltration devices were also designed as a hydraulic barrier against riverbank infiltration from the river Mur, which at that time showed seriously impaired water quality due to upstream paper mills. This resulted into high iron and manganese groundwater concentrations which lead to clogging of the pumping wells. These problems have been eliminated in the meantime due to the onsite purification of paper mill effluents and the construction of many waste water treatment plants. The recharge system has recently been thoroughly examined to optimize the operation of groundwater recharge and to provide a basis for further extension. The investigations included (i) field experiments and laboratory analyses to improve the trade off between infiltration rate and elimination capacities of the sand filter basins' top layer, (ii) numerical groundwater modelling to compute the recovery rate of the recharged water, the composition of the origin of the pumped water, emergency scenarios due to the failure of system parts, the transient capture zones of the withdrawal wells and the coordination of recharge and withdrawal and (iii) development of an online monitoring setup combined with a decision support system to guarantee reliable functioning of the entire structure. Additionally, the depreciation, maintenance and operation costs of the

  3. Combining hydrologic and groundwater modelling to characterize a regional aquifer system within a rift setting (Gidabo River Basin, Main Ethiopian Rift)

    Science.gov (United States)

    Birk, Steffen; Mechal, Abraham; Wagner, Thomas; Dietzel, Martin; Leis, Albrecht; Winkler, Gerfried; Mogessie, Aberra

    2016-04-01

    The development of groundwater resources within the Ethiopian Rift is complicated by the strong physiographic contrasts between the rift floor and the highland and by the manifold hydrogeological setting composed of volcanic rocks of different type and age that are intersected by numerous faults. Hydrogeochemical and isotope data from various regions within the Ethiopian Rift suggest that the aquifers within the semi-arid rift floor receive a significant contribution of groundwater flow from the humid highland. For example, the major ion composition of groundwater samples from Gidabo River Basin (3302 km²) in the southern part of the Main Ethiopian Rift reveals a mixing trend from the highland toward the rift floor; moreover, the stable isotopes of water, deuterium and O-18, of the rift-floor samples indicate a component recharged in the highland. This work aims to assess if the hydrological and hydrogeological data available for Gidabo River Basin is consistent with these findings and to characterize the regional aquifer system within the rift setting. For this purpose, a two-step approach is employed: First, the semi-distributed hydrological model SWAT is used to obtain an estimate of the spatial and temporal distribution of groundwater recharge within the watershed; second, the numerical groundwater flow model MODFLOW is employed to infer aquifer properties and groundwater flow components. The hydrological model was calibrated and validated using discharge data from three stream gauging stations within the watershed (Mechal et al., Journal of Hydrology: Regional Studies, 2015, doi:10.1016/j.ejrh.2015.09.001). The resulting recharge distribution exhibits a strong decrease from the highland, where the mean annual recharge amounts to several hundred millimetres, to the rift floor, where annual recharge largely is around 100 mm and below. Using this recharge distribution as input, a two-dimensional steady-state groundwater flow model was calibrated to hydraulic

  4. Temporal Dynamics of In-Field Bioreactor Populations Reflect the Groundwater System and Respond Predictably to Perturbation.

    Science.gov (United States)

    King, Andrew J; Preheim, Sarah P; Bailey, Kathryn L; Robeson, Michael S; Roy Chowdhury, Taniya; Crable, Bryan R; Hurt, Richard A; Mehlhorn, Tonia; Lowe, Kenneth A; Phelps, Tommy J; Palumbo, Anthony V; Brandt, Craig C; Brown, Steven D; Podar, Mircea; Zhang, Ping; Lancaster, W Andrew; Poole, Farris; Watson, David B; W Fields, Matthew; Chandonia, John-Marc; Alm, Eric J; Zhou, Jizhong; Adams, Michael W W; Hazen, Terry C; Arkin, Adam P; Elias, Dwayne A

    2017-02-10

    Temporal variability complicates testing the influences of environmental variability on microbial community structure and thus function. An in-field bioreactor system was developed to assess oxic versus anoxic manipulations on in situ groundwater communities. Each sample was sequenced (16S SSU rRNA genes, average 10,000 reads), and biogeochemical parameters are monitored by quantifying 53 metals, 12 organic acids, 14 anions, and 3 sugars. Changes in dissolved oxygen (DO), pH, and other variables were similar across bioreactors. Sequencing revealed a complex community that fluctuated in-step with the groundwater community and responded to DO. This also directly influenced the pH, and so the biotic impacts of DO and pH shifts are correlated. A null model demonstrated that bioreactor communities were driven in part not only by experimental conditions but also by stochastic variability and did not accurately capture alterations in diversity during perturbations. We identified two groups of abundant OTUs important to this system; one was abundant in high DO and pH and contained heterotrophs and oxidizers of iron, nitrite, and ammonium, whereas the other was abundant in low DO with the capability to reduce nitrate. In-field bioreactors are a powerful tool for capturing natural microbial community responses to alterations in geochemical factors beyond the bulk phase.

  5. Arsenic contamination of the soil-wheat system irrigated with high arsenic groundwater in the Hetao Basin, Inner Mongolia, China.

    Science.gov (United States)

    Tong, Junting; Guo, Huaming; Wei, Chao

    2014-10-15

    As one of the most important crop in the world, wheat (Triticum aestivum L.) was irrigated with low As water and high As water. However, little is known about As cycling in the soil-wheat-water system. Two wheat fields (site G and site Y), irrigated with high dissolved As (178 μg L(-1)) groundwater and low dissolved As (8.2 μg L(-1)) surface water, respectively, were systematically sampled in the Hetao Basin, including irrigation water, soils and plants. The annual As (including dissolved As and suspended As) input per m(2) was estimated at 140 and 36.7 mg in site G and site Y, respectively. Topsoils of site G contained relatively higher As content (average 18.8 mg kg(-1)) than those of site Y (13.8 mg kg(-1)). Arsenic content of wheat grains in site G is systematically higher than in the site Y, which were positively correlated with non-specifically sorbed-As and amorphous Fe/Al oxide-bound As in topsoils. Arsenic-contaminated groundwater led to As accumulation in irrigated soils and the increase in As bioavailability, and subsequently resulted in the increase in As content of wheat grain. It suggested that less problematic water resources should be used for wheat irrigation in order to avoid As accumulation in the soil-plant system. Copyright © 2014 Elsevier B.V. All rights reserved.

  6. MODFLOW-USG model of groundwater flow in the Wood River Valley aquifer system in Blaine County, Idaho

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — A three-dimensional numerical groundwater flow model (MODFLOW-USG) was developed for the Wood River Valley (WRV) aquifer system, south-central Idaho, to evaluate...

  7. Summer Mean Enhanced Vegetation Index for the Diamond Valley Flow System Groundwater Discharge Area, Central Nevada, 2010

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These data were created as part of a hydrologic study to characterize groundwater budgets and water quality in the Diamond Valley Flow System (DVFS), central Nevada....

  8. The fluoride in the groundwater of Guarani Aquifer System: the origin associated with black shales of Paraná Basin

    Science.gov (United States)

    Kern, M. L.; Vieiro, A. P.; Machado, G.

    2008-09-01

    This work presents petrological and geochemical results of the black shales interval from Permian and Devonian strata of the Paraná Basin, Brazil and its relationships with fluoride of groundwater from Guarani Aquifer System. The Guarani Aquifer, located in South Brazil, Uruguay, Paraguay and Argentine, presents contents of fluoride higher than the Brazilian accepted potability limits. Several hypotheses have been presented for the origin of the fluoride in the groundwater of the Guarani Aquifer. Microcrystalline fluorite was registered in black shales of Ponta Grossa and Irati formations from Paraná Basin. The results shown in this work suggest that fluoride present in groundwater of Guarani Aquifer can be originated in deeper groundwater that circulates in Ponta Grossa and Irati formations. The interaction of the groundwater coming from deeper black shales with the groundwater-bearing Aquifer Guarani System occurs through regional fragile structures (faults and fractures) that constitute excellent hydraulic connectors between the two sedimentary packages. The microcrystalline fluorite registered in Ponta Grossa and Irati Formations can be dissolved promoting fluoride enrichment in groundwater of these black shales and Guarani Aquifer System.

  9. Automated system for monitoring groundwater levels at an experimental low-level waste disposal site

    Energy Technology Data Exchange (ETDEWEB)

    Newbold, J.D.; Bogle, M.A.

    1984-06-01

    One of the major problems with disposing of low-level solid wastes in the eastern United States is the potential for water-waste interactions and leachate migration. To monitor groundwater fluctuations and the frequency with which groundwater comes into contact with a group of experimental trenches, work at Oak Ridge National Laboratory's Engineered Test Facility (ETF) has employed a network of water level recorders that feed information from 15 on-site wells to a centralized data recording system. The purpose of this report is to describe the monitoring system being used and to document the computer programs that have been developed to process the data. Included in this report are data based on more than 2 years of water level information for ETF wells 1 through 12 and more than 6 months of data from all 15 wells. The data thus reflect both long-term trends as well as a large number of short-term responses to individual storm events. The system was designed to meet the specific needs of the ETF, but the hardware and computer routines have generic application to a variety of groundwater monitoring situations. 5 references.

  10. Groundwater availability of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

    Science.gov (United States)

    Vaccaro, J.J.; Kahle, S.C.; Ely, D.M.; Burns, E.R.; Snyder, D.T.; Haynes, J.V.; Olsen, T.D.; Welch, W.B.; Morgan, D.S.

    2015-09-22

    The Columbia Plateau Regional Aquifer System (CPRAS) covers about 44,000 square miles of southeastern Washington, northeastern Oregon, and western Idaho. The area supports a $6-billion per year agricultural industry, leading the Nation in production of apples, hops, and eight other commodities. Groundwater pumpage and surface-water diversions supply water to croplands that account for about 5 percent of the Nation’s irrigated lands. Groundwater also is the primary source of drinking water for the more than 1.3 million people in the study area. Increasing competitive demands for water for municipal, fisheries/ecosystems, agricultural, domestic, hydropower, and recreational uses must be met by additional groundwater withdrawals and (or) by changes in the way water resources are allocated and used throughout the hydrologic system. As of 2014, most surface-water resources in the study area were either over allocated or fully appropriated, especially during the dry summer season. In response to continued competition for water, numerous water-management activities and concerns have gained prominence: water conservation, conjunctive use, artificial recharge, hydrologic implications of land-use change, pumpage effects on streamflow, and effects of climate variability and change. An integrated understanding of the hydrologic system is important in order to implement effective water-resource management strategies that address these concerns.

  11. Multi-Sensor Aerosol Products Sampling System

    Science.gov (United States)

    Petrenko, M.; Ichoku, C.; Leptoukh, G.

    2011-01-01

    Global and local properties of atmospheric aerosols have been extensively observed and measured using both spaceborne and ground-based instruments, especially during the last decade. Unique properties retrieved by the different instruments contribute to an unprecedented availability of the most complete set of complimentary aerosol measurements ever acquired. However, some of these measurements remain underutilized, largely due to the complexities involved in analyzing them synergistically. To characterize the inconsistencies and bridge the gap that exists between the sensors, we have established a Multi-sensor Aerosol Products Sampling System (MAPSS), which consistently samples and generates the spatial statistics (mean, standard deviation, direction and rate of spatial variation, and spatial correlation coefficient) of aerosol products from multiple spacebome sensors, including MODIS (on Terra and Aqua), MISR, OMI, POLDER, CALIOP, and SeaWiFS. Samples of satellite aerosol products are extracted over Aerosol Robotic Network (AERONET) locations as well as over other locations of interest such as those with available ground-based aerosol observations. In this way, MAPSS enables a direct cross-characterization and data integration between Level-2 aerosol observations from multiple sensors. In addition, the available well-characterized co-located ground-based data provides the basis for the integrated validation of these products. This paper explains the sampling methodology and concepts used in MAPSS, and demonstrates specific examples of using MAPSS for an integrated analysis of multiple aerosol products.

  12. Evolution of the groundwater system under the impacts of human activities in middle reaches of Heihe River Basin (Northwest China) from 1985 to 2013

    Science.gov (United States)

    Mi, Lina; Xiao, Honglang; Zhang, Jianming; Yin, Zhenliang; Shen, Yongping

    2016-06-01

    Investigation of the evolution of the groundwater system and its mechanisms is critical to the sustainable management of water in river basins. Temporal and spatial distributions and characteristics of groundwater have undergone a tremendous change with the intensity of human activities in the middle reaches of the Heihe River Basin (HRB), the second largest arid inland river basin in northwestern China. Based on groundwater observation data, hydrogeological data, meteorological data and irrigation statistical data, combined with geostatistical analyses and groundwater storage estimation, the basin-scaled evolution of the groundwater levels and storage (from 1985 to 2013) were investigated. The results showed that the unbalanced allocation of water sources and expanded cropland by policy-based human activities resulted in the over-abstraction of groundwater, which induced a general decrease in the water table and groundwater storage. The groundwater level has generally fallen from 4.92 to 11.49 m from 1985 to 2013, especially in the upper and middle parts of the alluvial fan (zone I), and reached a maximum depth of 17.41 m. The total groundwater storage decreased by 177.52 × 108 m3; zone I accounted for about 94.7 % of the total decrease. The groundwater balance was disrupted and the groundwater system was in a severe negative balance; it was noted that the groundwater/surface-water interaction was also deeply affected. It is essential to develop a rational plan for integration and management of surface water and groundwater resources in the HRB.

  13. Statistical robustness of machine-learning estimates for characterizing a groundwater-surface water system, Southland, New Zealand

    Science.gov (United States)

    Friedel, M. J.; Daughney, C.

    2016-12-01

    The development of a successful surface-groundwater management strategy depends on the quality of data provided for analysis. This study evaluates the statistical robustness when using a modified self-organizing map (MSOM) technique to estimate missing values for three hypersurface models: synoptic groundwater-surface water hydrochemistry, time-series of groundwater-surface water hydrochemistry, and mixed-survey (combination of groundwater-surface water hydrochemistry and lithologies) hydrostratigraphic unit data. These models of increasing complexity are developed and validated based on observations from the Southland region of New Zealand. In each case, the estimation method is sufficiently robust to cope with groundwater-surface water hydrochemistry vagaries due to sample size and extreme data insufficiency, even when >80% of the data are missing. The estimation of surface water hydrochemistry time series values enabled the evaluation of seasonal variation, and the imputation of lithologies facilitated the evaluation of hydrostratigraphic controls on groundwater-surface water interaction. The robust statistical results for groundwater-surface water models of increasing data complexity provide justification to apply the MSOM technique in other regions of New Zealand and abroad.

  14. Comparison of Analytic Hierarchy Process, Catastrophe and Entropy techniques for evaluating groundwater prospect of hard-rock aquifer systems

    Science.gov (United States)

    Jenifer, M. Annie; Jha, Madan K.

    2017-05-01

    Groundwater is a treasured underground resource, which plays a central role in sustainable water management. However, it being hidden and dynamic in nature, its sustainable development and management calls for precise quantification of this precious resource at an appropriate scale. This study demonstrates the efficacy of three GIS-based multi-criteria decision analysis (MCDA) techniques, viz., Analytic Hierarchy Process (AHP), Catastrophe and Entropy in evaluating groundwater potential through a case study in hard-rock aquifer systems. Using satellite imagery and relevant field data, eight thematic layers (rainfall, land slope, drainage density, soil, lineament density, geology, proximity to surface water bodies and elevation) of the factors having significant influence on groundwater occurrence were prepared. These thematic layers and their features were assigned suitable weights based on the conceptual frameworks of AHP, Catastrophe and Entropy techniques and then they were integrated in the GIS environment to generate an integrated raster layer depicting groundwater potential index of the study area. The three groundwater prospect maps thus yielded by these MCDA techniques were verified using a novel approach (concept of 'Dynamic Groundwater Potential'). The validation results revealed that the groundwater potential predicted by the AHP technique has a pronounced accuracy of 87% compared to the Catastrophe (46% accuracy) and Entropy techniques (51% accuracy). It is concluded that the AHP technique is the most reliable for the assessment of groundwater resources followed by the Entropy method. The developed groundwater potential maps can serve as a scientific guideline for the cost-effective siting of wells and the effective planning of groundwater development at a catchment or basin scale.

  15. Quantitative sustainability and qualitative concerns in an irrigations system using recycled water to supplement limited groundwater supply

    Science.gov (United States)

    Gowing, John; Alataway, Abed

    2013-04-01

    Sustainability of irrigation in a country facing water scarcity depends upon adoption of best management practices to deliver 'more crop per drop' together with use of recycled waste-water from urban sewage systems. Saudi Arabia is a country facing extreme water scarcity and in this paper we report on research conducted at an extensive irrigation system where a concerted effort over several years has been devoted to achieving a high level of water productivity. Al-Ahsa oasis is located about 60 km inland from the Persian Gulf and has been inhabited since prehistoric times, due to the abundance of water in an otherwise arid region. It is one of the largest oases in the world with 12,000 hectares of irrigated land and more than 2 million palm trees. Historically the oasis was watered by over 60 artesian springs, but water is now pumped from the aquifer. To supplement this groundwater source, treated waste-water reuse has been practiced since 1992 and now comprises 30% of total supply. In addition, a comparable amount of agricultural drainage water is collected and recycled, so that the 'first-use' water represents only 40% of total irrigation supply. While this re-use system permits sustained irrigation with greatly reduced groundwater abstraction, there is a potential down-side in that fertilizers and contaminants applied with irrigation water move through the soil and return to the irrigation supply enhancing the risk for human and animal health. We investigated this problem using E coli and helminth eggs as indicators of human health risk. We sampled each of the three sources which are delivered separately to the head of the main irrigation canal where they are blended. The groundwater was free from E coli and helminths and the treated wastewater source was generally within designated quality standards. The recycled drainage water was delivered untreated into the canal system and was found to be contaminated with both E coli and helminths above acceptable

  16. Groundwater quality in the Southeastern Coastal Plain aquifer system, southeastern United States

    Science.gov (United States)

    Barlow, Jeannie; Lindsey, Bruce; Belitz, Kenneth

    2017-01-19

    Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water. The Southeastern Coastal Plain aquifer system constitutes one of the important areas being evaluated. One or more inorganic constituents with human-health benchmarks were detected at high concentrations in about 6 percent of the study area and at moderate concentrations in about 13 percent. One or more organic constituents with human-health benchmarks were detected at moderate concentrations in about 3 percent of the study area.

  17. Groundwater quality in the Coastal Lowlands aquifer system, south-central United States

    Science.gov (United States)

    Barlow, Jeannie R.B.; Belitz, Kenneth

    2017-01-19

    Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water. The Coastal Lowlands aquifer system constitutes one of the important areas being evaluated. One or more inorganic constituents with human-health benchmarks were detected at high concentrations in about 12 percent of the study area and at moderate concentrations in about 18 percent. Organic constituents were not detected at high or moderate concentrations in the study area.

  18. Groundwater Characteristic and Fresh Water Supplying System of the East Slope Merapi Volcano

    Directory of Open Access Journals (Sweden)

    Yuli Priyana

    2004-01-01

    The result of the study shows that the quality of groundwater in every morphological unit is good enough, but in general the contents of element Ca, Mg, N03, CI, SO4, HCO3 shows that the lower the region is, the higher the content of the element . But if it is seen from the depth of its groundwater, so that the fluvial volcanic plain is the shallowest, then the fluvial volcanic foot plain and the last the volcanic foot area. Supplying system of fresh water, which derived from the dominant of well water, is especially used in morphological unit in fluvial "volcanic foot plain. The spring water is used by the population in the morphological unit in volcanic foot plain and then in morphological unit of fluvial volcanic foot plain. The population uses much rainwater in the morphological unit of volcanic foot plain.

  19. An update of the Death Valley regional groundwater flow system transient model, Nevada and California

    Science.gov (United States)

    Belcher, Wayne R.; Sweetkind, Donald S.; Faunt, Claudia C.; Pavelko, Michael T.; Hill, Mary C.

    2017-01-19

    Since the original publication of the Death Valley regional groundwater flow system (DVRFS) numerical model in 2004, more information on the regional groundwater flow system in the form of new data and interpretations has been compiled. Cooperators such as the Bureau of Land Management, National Park Service, U.S. Fish and Wildlife Service, the Department of Energy, and Nye County, Nevada, recognized a need to update the existing regional numerical model to maintain its viability as a groundwater management tool for regional stakeholders. The existing DVRFS numerical flow model was converted to MODFLOW-2005, updated with the latest available data, and recalibrated. Five main data sets were revised: (1) recharge from precipitation varying in time and space, (2) pumping data, (3) water-level observations, (4) an updated regional potentiometric map, and (5) a revision to the digital hydrogeologic framework model.The resulting DVRFS version 2.0 (v. 2.0) numerical flow model simulates groundwater flow conditions for the Death Valley region from 1913 to 2003 to correspond to the time frame for the most recently published (2008) water-use data. The DVRFS v 2.0 model was calibrated by using the Tikhonov regularization functionality in the parameter estimation and predictive uncertainty software PEST. In order to assess the accuracy of the numerical flow model in simulating regional flow, the fit of simulated to target values (consisting of hydraulic heads and flows, including evapotranspiration and spring discharge, flow across the model boundary, and interbasin flow; the regional water budget; values of parameter estimates; and sensitivities) was evaluated. This evaluation showed that DVRFS v. 2.0 simulates conditions similar to DVRFS v. 1.0. Comparisons of the target values with simulated values also indicate that they match reasonably well and in some cases (boundary flows and discharge) significantly better than in DVRFS v. 1.0.

  20. Final work plan : targeted groundwater sampling and monitoring well installation for potential site reclassification at Barnes, Kansas.

    Energy Technology Data Exchange (ETDEWEB)

    LaFreniere, L. M.

    2006-07-11

    This ''Work Plan'' outlines the scope of work for a targeted groundwater sampling investigation and monitoring well installation at Barnes, Kansas. This activity is being conducted at the request of the Kansas Department of Health and Environment (KDHE), in accordance with the intergovernmental agreement between the KDHE and the Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA). Data resulting from the proposed work will be used to determine the hydraulic gradient near the former CCC/USDA facility, delineate the downgradient carbon tetrachloride plume, and determine additional monitoring requirements at Barnes. The overall goal is to establish criteria for monitoring leading to potential site reclassification. The proposed work will be performed on behalf of the CCC/USDA by the Environmental Science Division of Argonne National Laboratory. Argonne is a nonprofit, multidisciplinary research center operated by the University of Chicago for the U.S. Department of Energy (DOE). The Farm Service Agency of the USDA has entered into an interagency agreement with DOE, under which Argonne provides technical assistance with environmental site characterization and remediation at former CCC/USDA grain storage facilities. Argonne issued a ''Master Work Plan'' (Argonne 2002) to provide general guidance for all investigations at former CCC/USDA facilities in Kansas. The ''Master Work Plan'', approved by the KDHE, contains the materials common to investigations at all locations in Kansas. This document must be consulted for the complete details of plans for this work associated with the former CCC/USDA facility at Barnes.

  1. Connotation and denotation of the groundwater system%地下水系统的内涵与外延

    Institute of Scientific and Technical Information of China (English)

    王晓明; 贾晓鹏; 曹永国; 王秀辉

    2013-01-01

    On the basis of introducing general system theory and method, this paper analyzes the limitation of clas-sic groundwater aquifer system and groundwater flow system in their meaning and content. The concepts of groundwater aquifer system and the groundwater flow system manifest more the integrity and overall view of the system theory, and do not reflect the basic idea and method of the system theory. In view of this, the paper gives a reasonable groundwater system concept which can more conform to general system theory concept, so as to rede-fine the connotation and research content of groundwater system, therefore enriching and developing the ground-water system theory.%  在介绍一般系统论思想与方法的基础上,分析了经典的地下水含水系统与地下水流动系统在内涵与研究内容上的局限性。地下水含水系统和地下水流动系统的概念更多的体现了系统论中整体性和全局性的观点,并没有体现系统论的基本思想与方法。鉴此,给出了更符合一般系统论系统概念的地下水系统概念,以重新界定地下水系统的内涵与研究内容,从而丰富与发展地下水系统理论。

  2. Sampled data systems passivity and discrete port-Hamiltonian systems

    NARCIS (Netherlands)

    Stramigioli, Stefano; Secchi, Cristian; Schaft, van der Arjan J.; Fantuzzi, Cesare

    2005-01-01

    In this paper, we present a novel way to approach the interconnection of a continuous and a discrete time physical system first presented in [1][2] [3]. This is done in a way which preserves passivity of the coupled system independently of the sampling time T. This strategy can be used both in the f

  3. A method of groundwater quality assessment based on fuzzy network-CANFIS and geographic information system (GIS)

    Science.gov (United States)

    Gholami, V.; Khaleghi, M. R.; Sebghati, M.

    2016-12-01

    The process of water quality testing is money/time-consuming, quite important and difficult stage for routine measurements. Therefore, use of models has become commonplace in simulating water quality. In this study, the coactive neuro-fuzzy inference system (CANFIS) was used to simulate groundwater quality. Further, geographic information system (GIS) was used as the pre-processor and post-processor tool to demonstrate spatial variation of groundwater quality. All important factors were quantified and groundwater quality index (GWQI) was developed. The proposed model was trained and validated by taking a case study of Mazandaran Plain located in northern part of Iran. The factors affecting groundwater quality were the input variables for the simulation, whereas GWQI index was the output. The developed model was validated to simulate groundwater quality. Network validation was performed via comparison between the estimated and actual GWQI values. In GIS, the study area was separated to raster format in the pixel dimensions of 1 km and also by incorporation of input data layers of the Fuzzy Network-CANFIS model; the geo-referenced layers of the effective factors in groundwater quality were earned. Therefore, numeric values of each pixel with geographical coordinates were entered to the Fuzzy Network-CANFIS model and thus simulation of groundwater quality was accessed in the study area. Finally, the simulated GWQI indices using the Fuzzy Network-CANFIS model were entered into GIS, and hence groundwater quality map (raster layer) based on the results of the network simulation was earned. The study's results confirm the high efficiency of incorporation of neuro-fuzzy techniques and GIS. It is also worth noting that the general quality of the groundwater in the most studied plain is fairly low.

  4. Interaction between shallow groundwater, saline surface water and nutrient discharge in a seasonal estuary: the Swan-Canning system

    Science.gov (United States)

    Linderfelt, William R.; Turner, Jeffrey V.

    2001-09-01

    The Swan and Canning Rivers converge to form an estuary that is seasonally forced by wet winter and dry summer conditions. The estuary is also tidally forced due to its contact with the Indian Ocean. The perception that the occurrence of nuisance algal blooms has increased in frequency and severity in recent years has prompted the present investigation into the interaction of the shallow groundwater system with the Swan-Canning Estuary. The extent to which this interaction contributes to nutrient delivery to the river is a focus of the work.Groundwater interaction with the upper reaches of the Swan River is shown to occur at three length scales: (i) the scale of the river-bed sediments (i.e. 1000 m). Two-dimensional groundwater flow modelling in plan covering the regionally advected groundwater flow domain of the upper Swan River Estuary from the Causeway to Guildford shows that there is a net groundwater discharge to the Swan River of groundwater discharge of about 80 000 m3/day, or about 29 million m3/year. Between 1987 and 1996, the average surface tributary inflow to the Swan River was about 460 million m3/year. Thus groundwater discharge contributed approximately 6% of the total annual river flow. This percentage is clearly small in comparison to the total river flow. However, in the six months from November to April in summer, tributary flow into the Swan River declines sharply to an average total of approximately 12 million m3. Groundwater discharge during this six-month period is approximately 14 million m3 or about 55% of the surface tributary flow, and thus groundwater is a significant component of the total inflow to the Swan-Canning Estuary during this period. Nutrient concentrations, particularly ammonium, within the sediment pore fluids underlying the river are very high relative to concentrations in the river, such that groundwater discharge rates of this magnitude are capable of introducing significant nutrient loadings to the river. The nitrogen

  5. Groundwater Flow Model of Göksu Delta Coastal Aquifer System

    Science.gov (United States)

    Erdem Dokuz, Uǧur; Çelik, Mehmet; Arslan, Şebnem; Engin, Hilal

    2016-04-01

    Like many other coastal areas, Göksu Delta (Mersin-Silifke, Southern Turkey) is a preferred place for human settlement especially due to its productive farmlands and water resources. The water dependent ecosystem in Göksu delta hosts about 332 different plant species and 328 different bird species besides serving for human use. Göksu Delta has been declared as Special Environmental Protection Zone, Wildlife Protection Area, and RAMSAR Convention for Wetlands of International Importance area. Unfortunately, rising population, agricultural and industrial activities cause degradation of water resources both by means of quality and quantity. This problem also exists for other wetlands around the world. It is necessary to prepare water management plans by taking global warming issues into account to protect water resources for next generations. To achieve this, the most efficient tool is to come up with groundwater management strategies by constructing groundwater flow models. By this aim, groundwater modeling studies were carried out for Göksu Delta coastal aquifer system. As a first and most important step in all groundwater modeling studies, geological and hydrogeological settings of the study area have been investigated. Göksu Delta, like many other deltaic environments, has a complex structure because it was formed with the sediments transported by Göksu River throughout the Quaternary period and shaped throughout the transgression-regression periods. Both due to this complex structure and the lack of observation wells penetrating deep enough to give an idea of the total thickness of the delta, it was impossible to reveal out the hydrogeological setting in a correct manner. Therefore, six wells were drilled to construct the conceptual hydrogeological model of Göksu Delta coastal aquifer system. On the basis of drilling studies and slug tests that were conducted along Göksu Delta, hydrostratigraphic units of the delta system have been obtained. According to

  6. The activity concentrations of 222Rn and corresponding health risk in groundwater samples from basement and sandstone aquifer; the correlation to physicochemical parameters

    Science.gov (United States)

    Abdurabu, Wedad Ali; Ramli, Ahmad Termizi; Saleh, Muneer Aziz; Heryansyah, Arien

    2016-10-01

    This study aims to evaluate the activity concentrations of 222Rn and to assess the corresponding health risk in groundwater samples obtained in Juban District, Ad Dali' Governorate, Yemen. The measurements were performed by RAD 7 radon detector manufactured by DURRIDGE COMPANY Inc. The activity concentrations of 222Rn ranged from 1.0±0.2 Bq l-1 to 896.0±0.8 Bq l-1. 57% of the groundwater samples were above the US Environmental Protection Agency (USEPA) recommended value for Rn in water. Induced coupled plasma mass spectrometry (ICP-MS) was used to determine the concentrations of uranium in groundwater samples. The measured concentration of U ranged from 0.33±0.01 μg l-1 to 24.6±0.6 μg l-1. The results were comparable to internationally recommended values. The highest concentration of U and 222Rn were found to be in the basement aquifer, while the lowest concentrations of both radionuclides were in the sandstone aquifer. High concentrations of Rn are found along fault zones. The relationship between the activity concentration of 222Rn, concentration of U and physicochemical parameters were investigated. The results showed a very strong relationship between activity concentrations of 222Rn with concentrations of U and the salinity of water.

  7. Groundwater status and trends for the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

    Science.gov (United States)

    Burns, Erick R.; Snyder, Daniel T.; Haynes, Jonathan V.; Waibel, Michael S.

    2012-01-01

    Well information and groundwater-level measurements for the Columbia Plateau Regional Aquifer System in Washington, Oregon, and Idaho, were compiled from data provided by the U.S. Geological Survey and seven other organizations. From the full set of about 60,000 wells and 450,000 water-level measurements a subset of 761 wells within the aquifers of the Columbia River Basalt Group (CRBG) then was used to develop a simple linear groundwater-level trend map for 1968–2009. The mean of the trends was a decline of 1.9 feet per year (ft/yr), with 72 percent of the water levels in wells declining. Rates of declines greater than 1.0 ft/yr were measured in 50 percent of wells, declines greater than 2.0 ft/yr in 38 percent of wells, declines greater than 4.0 ft/yr in 29 percent of wells, and declines greater than 8.0 ft/yr in 4 percent of wells. Water-level data were used to identify groups of wells with similar hydraulic heads and temporal trends to delineate areas of overall similar groundwater conditions. Discontinuities in hydraulic head between well groups were used to help infer the presence of barriers to groundwater flow such as changes in lithology or the occurrence of folds and faults. In areas without flow barriers, dissimilarities in response of well groups over time resulted from the formation of groundwater mounds caused by recharge from irrigation or regions of decline caused by pumping. The areas of focus for this analysis included the Umatilla area, Oregon, and the Palouse Slope/eastern Yakima Fold Belt in the Columbia Basin Ground Water Management Area (GWMA) consisting of Adams, Franklin, Grant, and Lincoln Counties, Washington. In the Umatilla area, water levels from 286 wells were used to identify multiple areas of high hydraulic gradient that indicate vertical and horizontal barriers to groundwater flow. These barriers divide the groundwater-flow system into several compartments with varying degrees of interconnection. Horizontal flow barriers commonly

  8. Hydrological and geochemical processes constraining groundwater salinity in wetland areas related to evaporitic (karst) systems. A case study from Southern Spain

    Science.gov (United States)

    Gil-Márquez, J. M.; Barberá, J. A.; Andreo, B.; Mudarra, M.

    2017-01-01

    Chemical and isotopic evolution of groundwater in an evaporite karst plateau (including wetland areas and saline to hyper-saline springs) located at S Spain was studied. Physicochemical parameters, major ions and stable isotopes were analyzed in rain, brine spring, wetland and leakage water samples, from which the most common mineral saturation indexes were computed and geochemical and isotopic modelling were performed. Results show an apparent relationship between the elevation of brine springs and their water mineralization, indicating that drainage at higher altitude may be associated to gravity-driven flows, since brackish groundwater is isotopically fractionated due to evaporation. On the other hand, the lower altitude springs could drain deeper flows with longer residence time, resulting in highly mineralized and warmer (briny) groundwater. The dissolution of halite and gypsum has proved to be the main geochemical processes, which are favored by the great ionic strength of groundwater. Calcite precipitation occurs in brackish waters draining wetlands, being boosted by common ion effect (when CaSO4 waters are present) and solute concentration caused by evaporation. Modelling results strongly support the hypothesis that most of the selected springs geochemically evolve in a common (S-N) flowpath. The methods used in this research contribute to a better understanding of the hydrogeological processes occurring in the studied evaporitic system, but also in equivalent hydrological environments worldwide.

  9. Multimedia model of atrazine in plant-soil-groundwater system with a fugacity approach.

    Science.gov (United States)

    Ye, C M; Lei, Z F; Wang, X J; Gong, A J; Zheng, H H

    2001-10-01

    The application of atrazine in China during the last ten years has led to some environmental problems. In this paper, the multimedia model of atrazine in soil-plant-groundwater system at Baiyangdian Lake area in Northern China was established using a fugacity approach, and verified with observed values. The model involved 7 environmental compartments which are air, groundwater, soil, corn roots, corn stem, corn leaf and kernel of corn. The results showed that the relative errors between calculated and observed values have a mean value of 24.7%, the highest value is 48% and the lowest value is 1.4%. All these values indicated that this multimedia model can be used to simulate the environmental fate of atrazine. Both the calculated and observed values of concentrations of atrazine in plant compartments are in the following order: in corn roots > in corn stem > in kernel of corn > in corn leaf, it exhibited a good regularity. The prediction results indicated that concentrations of atrazine in the groundwater and kernel of corn will override the limitation of 3 micrograms/L and 0.05 mg/kg respectively.

  10. Using Decision Support System to Find Suitable Sites for Groundwater Artificial Recharge

    Science.gov (United States)

    Ghasemian, D.; Winter, C. L.; Kheirkhah Zarkesh, M. M.; Moradi, H. R.

    2014-12-01

    Some parts of Iran are considered as one of the driest regions of the world, where water is a limiting factor for lasting life therefore using seasonal floodwaters is very important in these arid regions. On the other hand, special attention has been paid to artificial groundwater recharge in these regions. Floodwater spreading on the permeable terrain is one of the flood control and utilization methods. Determination of appropriate site for water spreading is one of the most important stages of this project. Parameters considered in the selection of groundwater artificial recharge locations are diverse and complex. These factors consist of earth sciences (geology, geomorphology and soils), hydrology (runoff, sediment yield, infiltration and groundwater conditions) and socio-economic aspects (irrigated agriculture, flood damage mitigation, environment, job creation and so on). Hence, decision making depends on criteria of diverse nature. The goal of this study is defining a Decision Support System for floodwater site selection in Shahriary area. Four main criteria were selected in this research which are floodwater characters, infiltration, water applications and flood damage. In order to determine the weight of factors, Analytical Hierarchy Process was used. The results showed that soil texture and floodwater volume of infiltration are the most important factors. After providing output maps which had been defined in five scenarios, Kappa Index was used to evaluate the model. Based on the obtained results, the maps showed an acceptable agreement with control zones.

  11. A research on grey numerical imitation and modeling of groundwater seepage system

    Institute of Scientific and Technical Information of China (English)

    WU; Qiang

    2001-01-01

    [1]Jiao Jiujiu, Grey hydrogeologic system analysis and time series model, Survey Science and Technology (in Chinese), 1987,(10): 39-43.[2]Li Shuwen, Wang Baolai, Xiao Guoqiang, A compound model of grey and periodic scrape and its application in groundwater prediction, Journal of Hebei Institute of Architectural Science & Technology (in Chinese), 1992, (3): 246-251.[3]Wang Qingyin, Li Shuwen, Grey distributed parameter model and groundwater analog, Journal of Hebei Institute of Architectural Science & Technology (in Chinese), 1992, (3): 66-70.[4]Guo Chunqing, Xia Riyuan, Liu Zhenglin, Gray Systematic Theory and Methodological Study of Krast Groundwater Resources Evaluation (in Chinese), Beijing: Geological Publishing House, 1993, 3-60.[5]Wang Qingyin, Liu Kaidi, The Mathematical Method of Grey Systematic Theory and Its Application (in Chinese), Chengdu: Publishing House of Southwestern China University of Communication, 1990, 23-27.[6]Wang Qingyin, Wu Heqing, The concept of grey number and its property, in Proceedings of NAFIPS98, USA, 1998,45-49.[7]Givoli, D., Doukhovni, I., Finite element programming approach for contact problems with geometrical nonlinearity, Computers and Structures, 1996, (8): 31-41.[8]Li Shuwen, Wang Zhiqiang, Wu Qiang, The superiority of storage-centered finite element method in solving seepage problem, Coal Geology and Exploration (in Chinese), 1999, (5): 46-49.

  12. Ground-Water Availability Assessment for the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

    Science.gov (United States)

    ,

    2008-01-01

    The U.S. Geological Survey (USGS) is assessing the availability and use of the Nation's water resources to gain a clearer understanding of the status of our water resources and the land-use, water-use, and climatic trends that affect them. The goal of the National assessment is to improve our ability to forecast water availability for future economic and environmental uses. Assessments will be completed for regional aquifer systems across the Nation to help characterize how much water we have now, how water availability is changing, and how much water we can expect to have in the future (Reilly and others, 2008). Water availability is a function of many factors, including the quantity and quality of water, and the laws, regulations, economics, and environmental factors that control its use. The focus of the Columbia Plateau regional ground-water availability assessment is to improve fundamental knowledge of the ground-water balance of the region, including the flows, storage, and ground-water use by humans. An improved quantitative understanding of the region's water balance not only provides key information about water quantity, but also can serve as a fundamental basis for many analyses of water quality and ecosystem health.

  13. Geographical Information System based assessment of spatiotemporal characteristics of groundwater quality of upland sub-watersheds of Meenachil River, parts of Western Ghats, Kottayam District, Kerala, India

    Science.gov (United States)

    Vijith, H.; Satheesh, R.

    2007-09-01

    Hydrogeochemistry of groundwater in upland sub-watersheds of Meenachil river, parts of Western Ghats, Kottayam, Kerala, India was used to assess the quality of groundwater for determining its suitability for drinking and agricultural purposes. The study area is dominated by rocks of Archaean age, and Charnonckite is dominated over other rocks. Rubber plantation dominated over other types of the vegetation in the area. Though the study area receives heavy rainfall, it frequently faces water scarcity as well as water quality problems. Hence, a Geographical Information System (GIS) based assessment of spatiotemporal behaviour of groundwater quality has been carried out in the region. Twenty-eight water samples were collected from different wells and analysed for major chemical constituents both in monsoon and post-monsoon seasons to determine the quality variation. Physical and chemical parameters of groundwater such as pH, dissolved oxygen (DO), total hardness (TH), chloride (Cl), nitrate (NO3) and phosphate (PO4) were determined. A surface map was prepared in the ArcGIS 8.3 (spatial analyst module) to assess the quality in terms of spatial variation, and it showed that the high and low regions of water quality varied spatially during the study period. The influence of lithology over the quality of groundwater is negligible in this region because majority of the area comes under single lithology, i.e. charnockite, and it was found that the extensive use of fertilizers and pesticides in the rubber, tea and other agricultural practices influenced the groundwater quality of the region. According to the overall assessment of the basin, all the parameters analysed are below the desirable limits of WHO and Indian standards for drinking water. Hence, considering the pH, the groundwater in the study area is not suitable for drinking but can be used for irrigation, industrial and domestic purposes. The spatial analysis of groundwater quality patterns of the study area shows

  14. Sample Return Systems for Extreme Environments Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Since the Apollo era, sample return missions have been primarily limited to asteroid sampling. More comprehensive sampling could yield critical information on the...

  15. Fingerprinting groundwater salinity sources in the Gulf Coast Aquifer System, USA

    Science.gov (United States)

    Chowdhury, Ali H.; Scanlon, Bridget R.; Reedy, Robert C.; Young, Steve

    2017-07-01

    Understanding groundwater salinity sources in the Gulf Coast Aquifer System (GCAS) is a critical issue due to depletion of fresh groundwater and concerns for potential seawater intrusion. The study objective was to assess sources of groundwater salinity in the GCAS using ˜1,400 chemical analyses and ˜90 isotopic analyses along nine well transects in the Texas Gulf Coast, USA. Salinity increases from northeast (median total dissolved solids (TDS) 340 mg/L) to southwest (median TDS 1,160 mg/L), which inversely correlates with the precipitation distribution pattern (1,370- 600 mm/yr, respectively). Molar Cl/Br ratios (median 540-600), depleted δ2H and δ18O (-24.7‰, -4.5‰) relative to seawater (Cl/Br ˜655 and δ2H, δ18O 0‰, 0‰, respectively), and elevated 36Cl/Cl ratios (˜100), suggest precipitation enriched with marine aerosols as the dominant salinity source. Mass balance estimates suggest that marine aerosols could adequately explain salt loading over the large expanse of the GCAS. Evapotranspiration enrichment to the southwest is supported by elevated chloride concentrations in soil profiles and higher δ18O. Secondary salinity sources include dissolution of salt domes or upwelling brines from geopressured zones along growth faults, mainly near the coast in the northeast. The regional extent and large quantities of brackish water have the potential to support moderate-sized desalination plants in this location. These results have important implications for groundwater management, suggesting a current lack of regional seawater intrusion and a suitable source of relatively low TDS water for desalination.

  16. A model for Ischia hydrothermal system: Evidences from the chemistry of thermal groundwaters

    Science.gov (United States)

    Di Napoli, R.; Aiuppa, A.; Bellomo, S.; Brusca, L.; D'Alessandro, W.; Candela, E. Gagliano; Longo, M.; Pecoraino, G.; Valenza, M.

    2009-10-01

    Ischia volcano, in Central Italy, has long been known for its copious surface hydrothermal manifestations, signs of a pervasive circulation of hot fluids in the subsurface. Because of the significant chemical heterogeneity of fumarolic gas discharges and hot spring discharges, evidences of a complex hydrothermal setting, a definite model of fluid circulation at depth is currently unavailable, in spite of the several previous efforts. Here, we report on the chemical and isotopic composition of 120 groundwater samples, collected during several sampling surveys from 2002 to 2007. The acquired data suggest that the composition of surface manifestations reflect contributions from meteoric water, sea water, and thermal fluids rising from two distinct hydrothermal reservoir, with equilibrium temperatures of respectively ~ 150 °C and ~ 270 °C, and depths of 150-300 m and > 300 m (but possibly > 1000 m). We also make use of an isotopic characterization of the dissolved gas phase in thermal waters to demonstrate that the Ischia hydrothermal system is currently supplied by a deep-rising gas component (DGC), characterized by CO 2 ~ 97.7 ± 1.2 vol.% (on a water-free basis), δ13C CO2 = - 3.51 ± 0.9‰, and helium isotopic ratio of about 3.5 Ra ( 3He/ 4He ratio normalized to the air ratio, Ra), likely magmatic in origin. An assessment of the thermal budget for Ischia hydrothermal system is also presented, in the attempt to derive a first estimate of the size and rate of degassing of the magmatic reservoir feeding the gas emissions. We calculate that a heat flow of about 153-222 MW presently drives hydrothermal circulation on the island, which we suggest is supplied in convective form (e.g., by the ascent of a high- T magmatic vapour phase) by complete degassing of 2.2-3.3 · 10 7 m 3 yr - 1 of trachytic magma (with ~ 2.1 wt.% dissolved H 2O content). If extrapolated to entire period of quiescence lasting since the Arso eruption in 1302 A.D., this volume corresponds to 1

  17. First step to understand the importance of new deep aquifer pumping regime in groundwater system in a developing country, Kwale, Kenya.

    Science.gov (United States)

    Ferrer, Nuria; Folch, Albert; Lane, Mike; Thomas, Mike; Sasaka, Willie; Wara, Calvince; Banje, Said; Olago, Dan; Katuva, Jacob; Thomson, Patrick; Hope, Rob

    2016-04-01

    level and its quality either. So, in order to define the system and start to understand the different complex interactions, we present the initial results of the first complete water sampling field campaign (September 2015). Water isotope data and major ions were analyzed from 78 shallow and deep wells and surface water spread around study area. This field survey has been useful to understand the recharge, discharge areas and groundwater quality of deep aquifer system and which will have an important role for sustainable water management in the of Kwale area. Acknowledgements The research is primarily supported under the NERC/ESRC/DFID Unlocking the Potential of Groundwater for the Poor (UPGro) as a Catalyst Grant (NE/L001950/1) with work extending until 2019 as a Consortium Grant (NE/M008894/1), see http://www.upgro.org. Data for the paper will be publicly posted on the National Geoscience Data Centre and the UK Data Archive under the terms of the UPGro data management agreement.

  18. A studies on characteristics of groundwater system in discontinuous rockmass for evaluation of safety on disposal site of radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Yeong Hoon; Han, Jeong Sang; Kim, Kyu Sang; Shin, Hyeon Joon; Lee, Chee Hyeong [Yonsei Univ., Seoul (Korea, Republic of)

    1997-07-15

    This study contains the development of numerical model of groundwater system and its application for the evaluation of safety in disposal site of radioactive waste. Through the identification of hydraulic properties, characteristics of discontinuity and selection of discontinuity model around LPG underground storage facility, the application of continuum model and discrete fracture network model was evaluated for the analysis of groundwater flow and solute transport.

  19. Three-dimensional hydrostratigraphical modelling to support evaluation of recharge and saltwater intrusion in a coastal groundwater system in Vietnam

    OpenAIRE

    2014-01-01

    Saltwater intrusion is generally related to seawater-level rise or induced intrusion due to excessive groundwater extraction in coastal aquifers. However, the hydrogeological heterogeneity of the subsurface plays an important role in (non-)intrusion as well. Local hydrogeological conditions for recharge and saltwater intrusion are studied in a coastal groundwater system in Vietnam where geological formations exhibit highly heterogeneous lithologies. A three-dimensional (3D) hydrostratigraphic...

  20. Chemical analyses of ground-water samples from the Rio Grande Valley in the vicinity of Albuquerque, New Mexico, October 1993 through January 1994

    Science.gov (United States)

    Wilkins, D.W.; Schlottmann, J.L.; Ferree, D.M.

    1996-01-01

    A study was conducted to investigate general ground-water- quality conditions and contaminant locations in the Rio Grande Valley in the vicinity of Albuquerque, New Mexico. Water samples from 36 observation wells in 12 well nests were analyzed. The well nests are located along three roads near the Rio Grande--two well nests near Paseo del Norte, five well nests near Monta?o Road, and five well nests near Rio Bravo Boulevard. The water samples were collected from October 19, 1993, through January 18, 1994. Water-quality types by major-ion composition were calcium bicarbonate (found in most samples), sodium sulfate, calcium sulfate, and calcium sulfate chloride. Nutrients were detected in all but one sample. Ammonia was detected in 34 samples, nitrite in 4 samples, and nitrate in 17 samples. Orthophosphate was detected in 31 samples. Organic carbon was detected in all samples collected. The trace elements arsenic and barium were detected in all samples and zinc in 31 samples. Fourteen samples contained detectable copper. Cadmium was detected in one sample, chromium in two samples, lead in four samples, and selenium in two samples. Mercury and silver were not detected.

  1. Human virus and microbial indicator occurrence in public-supply groundwater systems: meta-analysis of 12 international studies

    Science.gov (United States)

    Fout, G. Shay; Borchardt, Mark A.; Kieke, Burney A.; Karim, Mohammad R.

    2017-06-01

    Groundwater quality is often evaluated using microbial indicators. This study examines data from 12 international groundwater studies (conducted 1992-2013) of 718 public drinking-water systems located in a range of hydrogeological settings. Focus was on testing the value of indicator organisms for identifying virus-contaminated wells. One or more indicators and viruses were present in 37 and 15% of 2,273 samples and 44 and 27% of 746 wells, respectively. Escherichia coli ( E. coli) and somatic coliphage are 7-9 times more likely to be associated with culturable virus-positive samples when the indicator is present versus when it is absent, while F-specific and somatic coliphages are 8-9 times more likely to be associated with culturable virus-positive wells. However, single indicators are only marginally associated with viruses detected by molecular methods, and all microbial indicators have low sensitivity and positive predictive values for virus occurrence, whether by culturable or molecular assays, i.e., indicators are often absent when viruses are present and the indicators have a high false-positive rate. Wells were divided into three susceptibility subsets based on presence of (1) total coliform bacteria or (2) multiple indicators, or (3) location of wells in karst, fractured bedrock, or gravel/cobble settings. Better associations of some indicators with viruses were observed for (1) and (3). Findings indicate the best indicators are E. coli or somatic coliphage, although both indicators may underestimate virus occurrence. Repeat sampling for indicators improves evaluation of the potential for viral contamination in a well.

  2. Migration of infiltrated NH4 and NO3 in a soil and groundwater system simulated by a soil tank

    Institute of Scientific and Technical Information of China (English)

    WANG Chao; WANG Pei-Fang

    2008-01-01

    The infiltration of water contaminants into soil and groundwater systems can greatly affect the quality of groundwater.A laboratory-designed large soil tank with periodic and continuous infiltration models,respectively,was used to simulate the migration of the contaminants NHa and NO3 in a soil and groundwater system,including unsaturated and saturated zones.The unsaturated soil zone had a significant effect on removing NH4 and NO3 infiltrated from the surface water.The patterns of breakthrough curves of NH4 and NO3 in the unsaturated zone were related to the infiltration time.A short infiltration time resulted in a single sharp peak in the breakthrough curve,while a long infiltration time led to a plateau curve.When NHa and NO3 migrated from the unsaturated zone to the saturated zone,an interfacial retardation was formed,resulting in an increased contaminant concentration on the interface.Under the influence of horizontal groundwater movement,the infiltrated contaminants formed a contamination-prone area downstream.As the contaminants migrated downstream,their concentrations were significantly reduced.Under the same infiltration concentration,the concentration of NO3 was greater than that of NH4 at every corresponding cross-section in the soil and groundwater tank,suggesting that the removal efficiency of NH4 was greater than that of NO3 in the soil and groundwater system.

  3. Global depletion of groundwater resources

    NARCIS (Netherlands)

    Wada, Y.; Beek, L.P.H. van; van Kempen, C.M.; Reckman, J.W.T.M.; Vasak, S.; Bierkens, M.F.P.

    2010-01-01

    In regions with frequent water stress and large aquifer systems groundwater is often used as an additional water source. If groundwater abstraction exceeds the natural groundwater recharge for extensive areas and long times, overexploitation or persistent groundwater depletion occurs. Here we provid

  4. Analysis of groundwater dynamics in the complex aquifer system of Kazan Trona, Turkey, using environmental tracers and noble gases

    Science.gov (United States)

    Arslan, Sebnem; Yazicigil, Hasan; Stute, Martin; Schlosser, Peter; Smethie, William M.

    2015-02-01

    The Eocene deposits of Kazan Basin in Turkey contain a rare trona mineral which is planned to be extracted by solution mining. The complex flow dynamics and mixing mechanisms as noted from previous hydraulic and hydrochemical data need to be augmented with environmental tracer and noble gas data to develop a conceptual model of the system for the assessment of the impacts of the mining and to develop sustainable groundwater management policies throughout the area. The tracers used include the stable isotopes of water (δ2H, δ18O), δ13C and 14C of dissolved inorganic carbon (DIC), tritium (3H), the chlorofluorocarbons CFC-11 and CFC-12, and the noble gases He and Ne. The system studied consists of three aquifers: shallow, middle, and deep. CFC data indicate modern recharge in the shallow system. The estimates of ages through 14C dating for the deeper aquifer system are up to 34,000 years. Helium concentrations cover a wide range of values from 5 × 10-8 to 1.5 × 10-5 cm3 STP/g. 3He/4He ratios vary from 0.09RA to 1.29RA (where RA is the atmospheric 3He/4He ratio of 1.384 × 10-6), the highest found in water from the shallow aquifer. Mantle-derived 3He is present in some of the samples indicating upward groundwater movement, possibly along a NE-SW-striking fault-like feature in the basin.

  5. Comparison of no-purge and pumped sampling methods for monitoring concentrations of ordnance-related compounds in groundwater, Camp Edwards, Massachusetts Military Reservation, Cape Cod, Massachusetts, 2009-2010

    Science.gov (United States)

    Savoie, Jennifer G.; LeBlanc, Denis R.

    2012-01-01

    and the small variations were unlikely to affect the utility of the various sampling methods. The grab sampler was selected for additional tests in 29 of the 36 monitoring wells used during the study. Concentrations of ClO4-, RDX, HMX, and other minor explosive compounds in water samples collected by using a 1-liter grab sampler and low-flow pumped sampling were in close agreement in field tests in the 29 wells. A statistical analysis based on the sign test indicated that there was no bias in the concentration differences between the methods. There also was no evidence for a systematic bias in concentration differences between the methods related to location of the monitoring wells laterally or vertically in the groundwater-flow system. Field tests in five wells also demonstrated that sample collection by using a 2-liter grab sampler and sequential bailing with the 1-liter grab sampler were options for obtaining sufficient sample volume for replicate and spiked quality assurance and control samples. The evidence from the field tests supports the conclusion that diffusion sampling with the rigid porous polyethylene and regenerated-cellulose membranes and grab sampling with the polyethylene-film samplers provide comparable data on the concentrations of ordnance-related compounds in groundwater at the MMR to that obtained by low-flow pumped sampling. These sampling methods are useful methods for monitoring these compounds at the MMR and in similar hydrogeologic environments.

  6. Assessment of groundwater availability in the Northern Atlantic Coastal Plain aquifer system From Long Island, New York, to North Carolina

    Science.gov (United States)

    Masterson, John P.; Pope, Jason P.; Fienen, Michael N.; Monti, Jr., Jack; Nardi, Mark R.; Finkelstein, Jason S.

    2016-08-31

    Executive SummaryThe U.S. Geological Survey began a multiyear regional assessment of groundwater availability in the Northern Atlantic Coastal Plain (NACP) aquifer system in 2010 as part of its ongoing regional assessments of groundwater availability of the principal aquifers of the Nation. The goals of this national assessment are to document effects of human activities on water levels and groundwater storage, explore climate variability effects on the regional water budget, and provide consistent and integrated information that is useful to those who use and manage the groundwater resource. As part of this nationwide assessment, the USGS evaluated available groundwater resources within the NACP aquifer system from Long Island, New York, to northeastern North Carolina.The northern Atlantic Coastal Plain physiographic province depends heavily on groundwater to meet agricultural, industrial, and municipal needs. The groundwater assessment of the NACP aquifer system included an evaluation of how water use has changed over time; this evaluation primarily used groundwater budgets and development of a numerical modeling tool to assess system responses to stresses from future human uses and climate trends.This assessment focused on multiple spatial and temporal scales to examine changes in groundwater pumping, storage, and water levels. The regional scale provides a broad view of the sources and demands on the system with time. The sub-regional scale provides an evaluation of the differing response of the aquifer system across geographic areas allowing for closer examination of the interaction between different aquifers and confining units and the changes in these interactions under pumping and recharge conditions in 2013 and hydrologic stresses as much as 45 years in the future. By focusing on multiple scales, water-resource managers may utilize this study to understand system response to changes as they affect the system as a whole.The NACP aquifer system extends from

  7. Uncertainty quantification of surface-water/groundwater exchange estimates in large wetland systems using Python

    Science.gov (United States)

    Hughes, J. D.; Metz, P. A.

    2014-12-01

    Most watershed studies include observation-based water budget analyses to develop first-order estimates of significant flow terms. Surface-water/groundwater (SWGW) exchange is typically assumed to be equal to the residual of the sum of inflows and outflows in a watershed. These estimates of SWGW exchange, however, are highly uncertain as a result of the propagation of uncertainty inherent in the calculation or processing of the other terms of the water budget, such as stage-area-volume relations, and uncertainties associated with land-cover based evapotranspiration (ET) rate estimates. Furthermore, the uncertainty of estimated SWGW exchanges can be magnified in large wetland systems that transition from dry to wet during wet periods. Although it is well understood that observation-based estimates of SWGW exchange are uncertain it is uncommon for the uncertainty of these estimates to be directly quantified. High-level programming languages like Python can greatly reduce the effort required to (1) quantify the uncertainty of estimated SWGW exchange in large wetland systems and (2) evaluate how different approaches for partitioning land-cover data in a watershed may affect the water-budget uncertainty. We have used Python with the Numpy, Scipy.stats, and pyDOE packages to implement an unconstrained Monte Carlo approach with Latin Hypercube sampling to quantify the uncertainty of monthly estimates of SWGW exchange in the Floral City watershed of the Tsala Apopka wetland system in west-central Florida, USA. Possible sources of uncertainty in the water budget analysis include rainfall, ET, canal discharge, and land/bathymetric surface elevations. Each of these input variables was assigned a probability distribution based on observation error or spanning the range of probable values. The Monte Carlo integration process exposes the uncertainties in land-cover based ET rate estimates as the dominant contributor to the uncertainty in SWGW exchange estimates. We will discuss

  8. Subtask 1.15-Passive Diffusion Sample Bags Made from Expanded Polytetrafluorethylene (ePTFE) to Measure VOC Concentrations in Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Barry W. Botnen

    2006-08-01

    With laboratory testing of expanded polytetrafluoroethylene (ePTFE) membranes complete, collected data support that volatile organic compound (VOC) molecules will readily diffuse across ePTFE membranes. Membrane samples, supplied by BHA Technologies (GE Osmonics), were tested to determine diffusion rates for VOCs in groundwater. Tests were conducted using membranes with two different pore sizes, with and without thermally laminated spun bond backing, and multiple concentrations of contaminated groundwater. Results suggest that typical residence times associated with traditional samplers constructed of polyethylene (2 weeks) can be reduced by 1 week using ePTFE membranes (reducing project costs) and that VOCs will diffuse more readily at lower temperatures (2.2-3.3 C) across ePTFE materials.

  9. Development of a numerical model to simulate groundwater flow in the shallow aquifer system of Assateague Island, Maryland and Virginia

    Science.gov (United States)

    Masterson, John P.; Fienen, Michael N.; Gesch, Dean B.; Carlson, Carl S.

    2013-01-01

    A three-dimensional groundwater-flow model was developed for Assateague Island in eastern Maryland and Virginia to simulate both groundwater flow and solute (salt) transport to evaluate the groundwater system response to sea-level rise. The model was constructed using geologic and spatial information to represent the island geometry, boundaries, and physical properties and was calibrated using an inverse modeling parameter-estimation technique. An initial transient solute-transport simulation was used to establish the freshwater-saltwater boundary for a final calibrated steady-state model of groundwater flow. This model was developed as part of an ongoing investigation by the U.S. Geological Survey Climate and Land Use Change Research and Development Program to improve capabilities for predicting potential climate-change effects and provide the necessary tools for adaptation and mitigation of potentially adverse impacts.

  10. Hydrogeological Framework Model for Dhaka Regional Groundwater Flow System (DGFS), Bangladesh

    Science.gov (United States)

    Firoz, Abm; Marandi, Andres; Schüth, Christoph; Ribbe, Lars

    2017-04-01

    The hydrogeology of the Dhaka Regional Groundwater Flow System (DGFS) is located in central Bangladesh, consisting of sediment accumulates from the Ganges and Brahmaputra Meghna (GBM) river systems. The DGFS system is stratigraphically and structurally complex and subjected to a variety of structural disruption. These sediment deposits form a complex, three-dimensional (3D) framework that can be subdivided into aquifers and confining units on the basis of their ability to store and transmit water. The aquifer systems in this region are geologically controlled and depend on the sedimentary characteristics of the depositional environment and related parameters. More than 20 years of ground-water flow modeling of the DGFS has produced a succession of models that represent the regional hydrogeology and groundwater flow system. However, incorporation of a geologic framework in the models with different geologic data sets or subsurface interpretation is often missing. Therefore, such incorporation of geological and sedimentological information within the modeling framework could increase model calibration. The separate geological structure of the Dhaka region is studied yet detailed spatial and depth variables of geological and sedimentological information is still not evident in the hydrogeological framework. In this background, the objective of the paper is therefore to incorporate the geological information into the hydrogeological framework model and advance the approach of hydrogeology for the DGFS. We have used the concept of the Hydrogeologic Unit (HGU) - the sediment and deposits formation of the hydrostratigraphic framework for a groundwater flow system. The quaternary sedimentation processes of DGFS were subdivided into different cycles based on sea-level changes and Carbon-14 dating. The subdivisions are called 1a, 1b, 2 and 3 which correspond to high stand fluvial sequences (10-0 ka BP), Transgressive Tract/ low stand (20-10 ka BP), pre lows stand deposits

  11. Simulation of large-scale soil water systems using groundwater data and satellite based soil moisture

    Science.gov (United States)

    Kreye, Phillip; Meon, Günter

    2016-04-01

    Complex concepts for the physically correct depiction of dominant processes in the hydrosphere are increasingly at the forefront of hydrological modelling. Many scientific issues in hydrological modelling demand for additional system variables besides a simulation of runoff only, such as groundwater recharge or soil moisture conditions. Models that include soil water simulations are either very simplified or require a high number of parameters. Against this backdrop there is a heightened demand of observations to be used to calibrate the model. A reasonable integration of groundwater data or remote sensing data in calibration procedures as well as the identifiability of physically plausible sets of parameters is subject to research in the field of hydrology. Since this data is often combined with conceptual models, the given interfaces are not suitable for such demands. Furthermore, the application of automated optimisation procedures is generally associated with conceptual models, whose (fast) computing times allow many iterations of the optimisation in an acceptable time frame. One of the main aims of this study is to reduce the discrepancy between scientific and practical applications in the field of hydrological modelling. Therefore, the soil model DYVESOM (DYnamic VEgetation SOil Model) was developed as one of the primary components of the hydrological modelling system PANTA RHEI. DYVESOMs structure provides the required interfaces for the calibrations made at runoff, satellite based soil moisture and groundwater level. The model considers spatial and temporal differentiated feedback of the development of the vegetation on the soil system. In addition, small scale heterogeneities of soil properties (subgrid-variability) are parameterized by variation of van Genuchten parameters depending on distribution functions. Different sets of parameters are operated simultaneously while interacting with each other. The developed soil model is innovative regarding concept

  12. Numerical simulation of the groundwater-flow system of the Kitsap Peninsula, west-central Washington

    Science.gov (United States)

    Frans, Lonna M.; Olsen, Theresa D.

    2016-05-05

    ,905 acre-ft/yr (7 percent of total simulated inflow). Simulated outflow from the model primarily was through discharge to streams, lakes, springs, seeps, and Puget Sound (594,595 acre-ft/yr; 95 percent of total simulated outflow excluding changes in storage) and through withdrawals from wells (30,761 acre-ft/yr; 5 percent of total simulated outflow excluding changes in storage).Six scenarios were formulated with input from project stakeholders and were simulated using the calibrated model to provide representative examples of how the model could be used to evaluate the effects on water levels and stream baseflows of potential changes in groundwater withdrawals, in consumptive use, and in recharge. These included simulations of a steady-state system, no-pumping and return flows, 15-percent increase in current withdrawals in all wells, 80-percent decrease in outdoor water to simulate effects of conservation efforts, 15-percent decrease in recharge from precipitation to simulate a drought, and particle tracking to determine flow paths.Changes in water-level altitudes and baseflow amounts vary depending on the stress applied to the system in these various scenarios. Reducing recharge by 15 percent between 2005 and 2012 had the largest effect, with water-level altitudes declining throughout the model domain and baseflow amounts decreasing by as much as 18 percent compared to baseline conditions. Changes in pumping volumes had a smaller effect on the model. Removing all pumping and resulting return flows caused increased water-level altitudes in many areas and increased baseflow amounts of between 1 and 3 percent.

  13. Concentration comparison of selected constituents between groundwater samples collected within the Missouri River alluvial aquifer using purge and pump and grab-sampling methods, near the city of Independence, Missouri, 2013

    Science.gov (United States)

    Krempa, Heather M.

    2015-10-29

    The U.S. Geological Survey, in cooperation with the City of Independence, Missouri, Water Department, has historically collected water-quality samples using the purge and pump method (hereafter referred to as pump method) to identify potential contamination in groundwater supply wells within the Independence well field. If grab sample results are comparable to the pump method, grab samplers may reduce time, labor, and overall cost. This study was designed to compare constituent concentrations between samples collected within the Independence well field using the pump method and the grab method.

  14. Hydrogeologic evaluation and numerical simulation of the Death Valley regional ground-water flow system, Nevada and California

    Energy Technology Data Exchange (ETDEWEB)

    D`Agnese, F.A.; Faunt, C.C.; Turner, A.K.; Hill, M.C.

    1997-12-31

    Yucca Mountain is being studied as a potential site for a high-level radioactive waste repository. In cooperation with the U.S. Department of Energy, the U.S. Geological Survey is evaluating the geologic and hydrologic characteristics of the ground-water system. The study area covers approximately 100,000 square kilometers between lat 35{degrees}N., long 115{degrees}W and lat 38{degrees}N., long 118{degrees}W and encompasses the Death Valley regional ground-water flow system. Hydrology in the region is a result of both the and climatic conditions and the complex described as dominated by interbasinal flow and may be conceptualized as having two main components: a series of relatively shallow and localized flow paths that are superimposed on deeper regional flow paths. A significant component of the regional ground-water flow is through a thick Paleozoic carbonate rock sequence. Throughout the regional flow system, ground-water flow is probably controlled by extensive and prevalent structural features that result from regional faulting and fracturing. Hydrogeologic investigations over a large and hydrogeologically complex area impose severe demands on data management. This study utilized geographic information systems and geoscientific information systems to develop, store, manipulate, and analyze regional hydrogeologic data sets describing various components of the ground-water flow system.

  15. Potential corrosivity of untreated groundwater in the United States

    Science.gov (United States)

    Belitz, Kenneth; Jurgens, Bryant C.; Johnson, Tyler D.

    2016-07-12

    Corrosive groundwater, if untreated, can dissolve lead and other metals from pipes and other components in water distribution systems. Two indicators of potential corrosivity—the Langelier Saturation Index (LSI) and the Potential to Promote Galvanic Corrosion (PPGC)—were used to identify which areas in the United States might be more susceptible to elevated concentrations of metals in household drinking water and which areas might be less susceptible. On the basis of the LSI, about one-third of the samples collected from about 21,000 groundwater sites are classified as potentially corrosive. On the basis of the PPGC, about two-thirds of the samples collected from about 27,000 groundwater sites are classified as moderate PPGC, and about one-tenth as high PPGC. Potentially corrosive groundwater occurs in all 50 states and the District of Columbia.National maps have been prepared to identify the occurrence of potentially corrosive groundwater in the 50 states and the District of Columbia. Eleven states and the District of Columbia were classified as having a very high prevalence of potentially corrosive groundwater, 14 states as having a high prevalence of potentially corrosive groundwater, 19 states as having a moderate prevalence of potentially corrosive groundwater, and 6 states as having a low prevalence of potentially corrosive groundwater. These findings have the greatest implication for people dependent on untreated groundwater for drinking water, such as the 44 million people that are self-supplied and depend on domestic wells or springs for their water supply.

  16. Aerobot Sampling and Handling System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Honeybee Robotics proposes to: ?Derive and document the functional and technical requirements for Aerobot surface sampling and sample handling across a range of...

  17. Study of groundwater vulnerability to pollution using the DRASTIC method coupled with a geographic information system (GIS): application to groundwater Beni Amir, Morocco

    Science.gov (United States)

    Knouz, Najat; Boudhar, Abdelghani; Bachaoui, El Mostafa

    2016-04-01

    Fresh water is the condition of all life on Earth for its vital role in the survival of living beings and in the social, economic and technological development. The Groundwater, as the surface water, is increasingly threatened by agricultural and industrial pollution. In this respect, the groundwater vulnerability assessment to pollution is a very valuable tool for resource protection, management of its quality and uses it in a sustainable way. The main objective of this study is the evaluation of groundwater vulnerability to pollution of the study area, Beni Amir, located in the first irrigated perimeter of Morocco, Tadla, using the DRASTIC method (depth to water, net recharge, aquifer media, soil media, Topography, impact of Vadose zone and hydraulic conductivity), and assessing the impact of each parameter on the DRASTIC vulnerability index by a sensitivity analysis. This study also highlights the role of geographic information systems (GIS) in assessing vulnerability. The Vulnerability index is calculated as the sum of product of ratings and weights assigned to each of the parameter DRASTIC. The results revealed four vulnerability classes, 7% of the study area has a high vulnerability, 31% are moderately vulnerable, 57% have a low vulnerability and 5% are of very low vulnerability.

  18. Organic Contaminants in Riverine and Groundwater Systems: Aspects of the Anthropogenic Contribution

    Science.gov (United States)

    Schwarzbauer, Jan

    This book summarizes a selection of organic-geochemical investigations, which deal with the characterization and environmental behaviour of organic contaminations of German river and groundwater systems. The aim is to resume and present an overview of comprehensive current research activities, which have been published diversely in specialised scientific journals and, are therefore not easily available in a concise and clearly arranged way. Important topics include comprehensive non-target screening as well as isotope analysis of contaminants in water and sediments, detailed characterisation of bound residues, recording river ine pollution histories and an extensive application of the anthropogenic marker approach.

  19. Sampling Theory of Food Safety System

    OpenAIRE

    LI, Bing; Chen, Guohua; Zhu, Ning

    2009-01-01

    We introduce the stratified sampling method, and put forward theoretical unbiased estimation of stratified sampling program, as well as the model and statistics of experimental design test. We also discuss the establishment of dietary exposure model, pollutant distribution model, and risk evaluation model. Finally, we present some methods for sampling design in China.

  20. Sampling Theory of Food Safety System

    OpenAIRE

    Li, Bing; Chen, Guohua; Zhu, Ning

    2009-01-01

    We introduce the stratified sampling method, and put forward theoretical unbiased estimation of stratified sampling program, as well as the model and statistics of experimental design test. We also discuss the establishment of dietary exposure model, pollutant distribution model, and risk evaluation model. Finally, we present some methods for sampling design in China.

  1. Determination of aluminium in groundwater samples by GF-AAS, ICP-AES, ICP-MS and modelling of inorganic aluminium complexes.

    Science.gov (United States)

    Frankowski, Marcin; Zioła-Frankowska, Anetta; Kurzyca, Iwona; Novotný, Karel; Vaculovič, Tomas; Kanický, Viktor; Siepak, Marcin; Siepak, Jerzy

    2011-11-01

    The paper presents the results of aluminium determinations in ground water samples of the Miocene aquifer from the area of the city of Poznań (Poland). The determined aluminium content amounted from aluminium determinations were performed using three analytical techniques: graphite furnace atomic absorption spectrometry (GF-AAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The results of aluminium determinations in groundwater samples for particular analytical techniques were compared. The results were used to identify the ascent of ground water from the Mesozoic aquifer to the Miocene aquifer in the area of the fault graben. Using the Mineql+ program, the modelling of the occurrence of aluminium and the following aluminium complexes: hydroxy, with fluorides and sulphates was performed. The paper presents the results of aluminium determinations in ground water using different analytical techniques as well as the chemical modelling in the Mineql+ program, which was performed for the first time and which enabled the identification of aluminium complexes in the investigated samples. The study confirms the occurrence of aluminium hydroxy complexes and aluminium fluoride complexes in the analysed groundwater samples. Despite the dominance of sulphates and organic matter in the sample, major participation of the complexes with these ligands was not stated based on the modelling.

  2. An interdisciplinary approach for groundwater management in area contaminated by fluoride in East African Rift System

    Science.gov (United States)

    Da Pelo, Stefania; Melis, M. Teresa; Dessì, Francesco; Pistis, Marco; Funedda, Antonio; Oggiano, Giacomo; Carletti, Alberto; Soler Gil, Albert; Barbieri, Manuela; Pittalis, Daniele; Ghiglieri, Giorgio

    2017-04-01

    Groundwater is the main source of fresh water supply for most of the rural communities in Africa (approximately 75% of Africans has confidence in groundwater as their major source of drinking water). Many African countries has affected by high fluoride concentration in groundwater (up to 90 mg/L), generating the contamination of waters, soils and food, in particular in the eastern part of the continent. It seems that fluoride concentration is linked to geology of the Rift Valley: geogenic occurrence of fluoride is often connected to supergenic enrichment due to the weathering of alkaline volcanic rocks, fumaric gases and presence of thermal waters. The H2020 project FLOWERED (de-FLuoridation technologies for imprOving quality of WatEr and agRo-animal products along the East African Rift Valley in the context of aDaptation to climate change) wish to address environmental and health (human and animal) issues associated to the fluoride contamination in the African Rift Valley, in particular in three case study area located in Ethiopia, Tanzania and Kenya. FLOWERED aims to develop an integrated, sustainable and participative water and agriculture management at a cross-boundary catchment scale through a strong interdisciplinary research approach. It implies knowledge of geology, hydrogeology, mineralogy, geochemistry, agronomy, crop and animal sciences, engineering, technological sciences, data management and software design, economics and communication. The proposed approach is based on a detailed knowledge of the hydrogeological setting, with the identification and mapping of the specific geological conditions of water contamination and its relation with the different land uses. The East African Rift System (EARS) groundwater circulation and storage, today already poorly understood, is characterized by a complex arrangement of aquifers. It depends on the type of porosity and permeability created during and after the rock formation, and is strongly conditioned by the

  3. Structure and application of an interface program between a geographic-information system and a ground-water flow model

    Science.gov (United States)

    Van Metre, P.C.

    1990-01-01

    A computer-program interface between a geographic-information system and a groundwater flow model links two unrelated software systems for use in developing the flow models. The interface program allows the modeler to compile and manage geographic components of a groundwater model within the geographic information system. A significant savings of time and effort is realized in developing, calibrating, and displaying the groundwater flow model. Four major guidelines were followed in developing the interface program: (1) no changes to the groundwater flow model code were to be made; (2) a data structure was to be designed within the geographic information system that follows the same basic data structure as the groundwater flow model; (3) the interface program was to be flexible enough to support all basic data options available within the model; and (4) the interface program was to be as efficient as possible in terms of computer time used and online-storage space needed. Because some programs in the interface are written in control-program language, the interface will run only on a computer with the PRIMOS operating system. (USGS)

  4. Simulation of Partially Saturated - Saturated Flow in the Caspar Creek E-Road Groundwater System

    Science.gov (United States)

    Fisher, J.; Fisher, J.

    2001-12-01

    Over the past decade, the U.S. Forest Service has monitored the subsurface hillslope flow of the E-Road swale. The swale is located in the Caspar Creek watershed near Fort Bragg, California. In hydrologic year 1990 a logging road was built across the middle section of the hillslope followed by a total clearcut of the area during the following year. Development of the logging road has resulted in a large build up of subsurface waters upslope of the road. The increase in pore pressures behind the road is of major concern for slope stability and road failure. A conceptual model is developed to describe the movement of water within the E-Road groundwater system. The two-dimensional SUTRA model is used to describe both saturated and partially saturated flow within the system. SUTRA utilizes a finite element and integrated finite difference method to approximate the governing equation for flow. The model appears to reproduce the uniquely different frequency responses within the E-Road groundwater system. A comparison of simulated and historical piezometric responses demonstrates the model's inability to reproduce historical drainage rates. The low rates of simulated drainage are attributed to the absence of pipeflow within the model. Finally, road consolidation is associated with increased water pressures beneath the road bed.

  5. Geochemical impacts of groundwater heat pump systems in an urban alluvial aquifer with evaporitic bedrock.

    Science.gov (United States)

    Garrido Schneider, Eduardo A; García-Gil, Alejandro; Vázquez-Suñè, Enric; Sánchez-Navarro, José Á

    2016-02-15

    In the last decade, there has been an extensive use of shallow geothermal exploitations in urban environments. Although the thermal interference between exploitations has been recently studied, there is a lack of knowledge regarding the geochemical impacts of those systems on the aquifers where they are installed. Groundwater flow line scale and well-doublet scale research work has been conducted at city scale to quantify the geochemical interaction of shallow geothermal exploitations with the environment. A comprehensive analysis was conducted on data obtained from a monitoring network specifically designed to control and develop aquifer policies related to thermal management of the aquifer. The geochemical impacts were evaluated from a thermodynamic point of view by means of saturation index (SI) calculations with respect to the different mineral species considered in the system. The results obtained indicate limited geochemical interaction with the urban environment in most of the situations. However, there are some cases where the interaction of the groundwater heat pump installations with the evaporitic bedrock resulted in the total disablement of the exploitation system operation wells. The application of the tool proposed proved to be pragmatic in the evaluation of geochemical impacts. Injection of water into the aquifer can trigger an important bedrock gypsum and halite dissolution process that is partly responsible for scaling in well casing pipes and collapse of the terrain in the vicinity of injection wells. Copyright © 2015 Elsevier B.V. All rights reserved.

  6. Documentation of a groundwater flow model developed to assess groundwater availability in the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to North Carolina

    Science.gov (United States)

    Masterson, John P.; Pope, Jason P.; Fienen, Michael N.; Monti, Jr., Jack; Nardi, Mark R.; Finkelstein, Jason S.

    2016-08-31

    The U.S. Geological Survey developed a groundwater flow model for the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to northeastern North Carolina as part of a detailed assessment of the groundwater availability of the area and included an evaluation of how these resources have changed over time from stresses related to human uses and climate trends. The assessment was necessary because of the substantial dependency on groundwater for agricultural, industrial, and municipal needs in this area.The three-dimensional, groundwater flow model developed for this investigation used the numerical code MODFLOW–NWT to represent changes in groundwater pumping and aquifer recharge from predevelopment (before 1900) to future conditions, from 1900 to 2058. The model was constructed using existing hydrogeologic and geospatial information to represent the aquifer system geometry, boundaries, and hydraulic properties of the 19 separate regional aquifers and confining units within the Northern Atlantic Coastal Plain aquifer system and was calibrated using an inverse modeling parameter-estimation (PEST) technique.The parameter estimation process was achieved through history matching, using observations of heads and flows for both steady-state and transient conditions. A total of 8,868 annual water-level observations from 644 wells from 1986 to 2008 were combined into 29 water-level observation groups that were chosen to focus the history matching on specific hydrogeologic units in geographic areas in which distinct geologic and hydrologic conditions were observed. In addition to absolute water-level elevations, the water-level differences between individual measurements were also included in the parameter estimation process to remove the systematic bias caused by missing hydrologic stresses prior to 1986. The total average residual of –1.7 feet was normally distributed for all head groups, indicating minimal bias. The average absolute residual value

  7. Flow system boundary by D'Agnese and others (1997) for the Death Valley regional ground-water flow system study, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the flow-system boundary encompassing the regional ground-water flow model by D'Agnese and others (1997). The boundary encompasses an...

  8. Quantitative analysis of saltwater-freshwater relationships in groundwater systems-A historical perspective

    Science.gov (United States)

    Reilly, T.E.; Goodman, A.S.

    1985-01-01

    Although much progress has been made toward the mathematical description of saltwater-freshwater relationships in groundwater systems since the late 19th century, the advective and dispersive mechanisms involved are still incompletely understood. This article documents the major historical advances in this subject and summarizes the major direction of current studies. From the time of Badon Ghyben and Herzberg, it has been recognized that density is important in mathematically describing saltwater-freshwater systems. Other mechanisms, such as hydrodynamic dispersion, were identified later and are still not fully understood. Quantitative analysis of a saltwater-freshwater system attempts to mathematically describe the physical system and the important mechanisms using reasonable simplifications and assumptions. This paper, in developing the history of quantitative analysis discusses many of these simplifications and assumptions and their effect on describing and understanding the phenomenon. ?? 1985.

  9. CONTROL CHAOS IN TRANSITION SYSTEM USING SAMPLED-DATA FEEDBACK

    Institute of Scientific and Technical Information of China (English)

    陆君安; 谢进; 吕金虎; 陈士华

    2003-01-01

    The method for controlling chaotic transition system was investigated using sampled-data. The output of chaotic transition system was sampled at a given sampling rate,then the sampled output was used by a feedbacks subsystem to construct a control signal for controlling chaotic transition system to the origin. Numerical simulations are presented to show the effectiveness and feasibility of the developed controller.

  10. Curricular Design for Intelligent Systems in Geosciences Using Urban Groundwater Studies.

    Science.gov (United States)

    Cabral-Cano, E.; Pierce, S. A.; Fuentes-Pineda, G.; Arora, R.

    2016-12-01

    Geosciences research frequently focuses on process-centered phenomena, studying combinations of physical, geological, chemical, biological, ecological, and anthropogenic factors. These interconnected Earth systems can be best understood through the use of digital tools that should be documented as workflows. To develop intelligent systems, it is important that geoscientists and computing and information sciences experts collaborate to: (1) develop a basic understanding of the geosciences and computing and information sciences disciplines so that the problem and solution approach are clear to all stakeholders, and (2) implement the desired intelligent system with a short turnaround time. However, these interactions and techniques are seldom covered in traditional Earth Sciences curricula. We have developed an exchange course on Intelligent Systems for Geosciences to support workforce development and build capacity to facilitate skill-development at the undergraduate student-level. The first version of this course was offered jointly by the University of Texas at Austin and the Universidad Nacional Autónoma de México as an intensive, study-abroad summer course. Content included: basic Linux introduction, shell scripting and high performance computing, data management, experts systems, field data collection exercises and basics of machine learning. Additionally, student teams were tasked to develop a term projects that centered on applications of Intelligent Systems applied to urban and karst groundwater systems. Projects included expert system and reusable workflow development for subsidence hazard analysis in Celaya, Mexico, a classification model to analyze land use change over a 30 Year Period in Austin, Texas, big data processing and decision support for central Texas groundwater case studies and 3D mapping with point cloud processing at three Texas field sites. We will share experiences and pedagogical insights to improve future versions of this course.

  11. Data Validation Package November 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites February 2016

    Energy Technology Data Exchange (ETDEWEB)

    Bush, Richard [USDOE Office of Legacy Management, Washington, DC (United States); Lemke, Peter [Navarro Research and Engineering, Inc., Oak Ridge, TN (United States)

    2016-02-01

    Water samples were collected from 36 locations at New Rifle and Old Rifle, Colorado, Processing Sites. Duplicate samples were collected from New Rifle locations 0659 and 0855, and Old Rifle location 0304. One equipment blank was collected after decontamination of non-dedicated equipment used to collect one surface water sample. Sampling and analyses were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). New Rifle Site Samples were collected at the New Rifle site from 16 monitoring wells and 7 surface locations in compliance with the December 2008 Groundwater Compliance Action Plan [GCAP] for the New Rifle, Colorado, Processing Site (LMS/RFN/S01920), with one exception: New Rifle location 0635 could not be sampled because it was inaccessible; a fence installed by the Colorado Department of Transportation prevents access to this location. DOE is currently negotiating access with the Colorado Department of Transportation. Analytes measured at the New Rifle site included contaminants of concern (COCs) (arsenic, molybdenum, nitrate + nitrite as nitrogen, selenium, uranium, and vanadium) ammonia as nitrogen, major cations, and major anions. Field measurements of total alkalinity, oxidation- reduction potential, pH, specific conductance, turbidity, and temperature were made at each location, and the water level was measured at each sampled well. A proposed alternate concentration limit (ACL) for vanadium of 50 milligrams per liter (mg/L), specific to the compliance (POC) wells (RFN-0217, -0659, -0664, and -0669) is included in the New Rifle GCAP. Vanadium concentrations in the POC wells were below the proposed ACL as shown in the time-concentration graphs in the Data Presentation section (Attachment 2). Time-concentration graphs from all other locations sampled are also included in Attachment 2. Sampling location RFN-0195 was misidentified for the June/August 2014

  12. A Modular Computer Code for Simulating Reactive Multi-Species Transport in 3-Dimensional Groundwater Systems

    Energy Technology Data Exchange (ETDEWEB)

    TP Clement

    1999-06-24

    RT3DV1 (Reactive Transport in 3-Dimensions) is computer code that solves the coupled partial differential equations that describe reactive-flow and transport of multiple mobile and/or immobile species in three-dimensional saturated groundwater systems. RT3D is a generalized multi-species version of the US Environmental Protection Agency (EPA) transport code, MT3D (Zheng, 1990). The current version of RT3D uses the advection and dispersion solvers from the DOD-1.5 (1997) version of MT3D. As with MT3D, RT3D also requires the groundwater flow code MODFLOW for computing spatial and temporal variations in groundwater head distribution. The RT3D code was originally developed to support the contaminant transport modeling efforts at natural attenuation demonstration sites. As a research tool, RT3D has also been used to model several laboratory and pilot-scale active bioremediation experiments. The performance of RT3D has been validated by comparing the code results against various numerical and analytical solutions. The code is currently being used to model field-scale natural attenuation at multiple sites. The RT3D code is unique in that it includes an implicit reaction solver that makes the code sufficiently flexible for simulating various types of chemical and microbial reaction kinetics. RT3D V1.0 supports seven pre-programmed reaction modules that can be used to simulate different types of reactive contaminants including benzene-toluene-xylene mixtures (BTEX), and chlorinated solvents such as tetrachloroethene (PCE) and trichloroethene (TCE). In addition, RT3D has a user-defined reaction option that can be used to simulate any other types of user-specified reactive transport systems. This report describes the mathematical details of the RT3D computer code and its input/output data structure. It is assumed that the user is familiar with the basics of groundwater flow and contaminant transport mechanics. In addition, RT3D users are expected to have some experience in

  13. 2,4-D abatement from groundwater samples by photo-Fenton processes at circumneutral pH using naturally iron present. Effect of inorganic ions.

    Science.gov (United States)

    Gutiérrez-Zapata, Héctor M; Rojas, Karen L; Sanabria, Janeth; Rengifo-Herrera, Julián Andrés

    2017-03-01

    This study evaluated, at laboratory scale, if the using iron naturally present (0.3 mg L(-1)) and adding 10 mg L(-1) of hydrogen peroxide was effective to remove 24.3 mgL(-1) of 2,4-dichlorophenoxyacetic acid (2,4-D) from groundwater samples by simulated solar irradiation (global intensity = 300 W m(-2)). Under these conditions, the degradation of 2,4-D reached 75.2 % and the apparition of its main oxidation byproduct 2,4-dichlorophenol (DCP) was observed. On the other hand, pH exhibited an increasing from 7.0 to 8.3 during the experiment. Experiments using Milli-Q water at pH 7.0, iron, and H2O2 concentrations of 0.3 and 10 mg L(-1), respectively, were carried out in order to study the effect of ions such as carbonate species, phosphate, and fluoride in typical concentrations often found in groundwater. Ion concentrations were combined by using a factorial experimental design 2(3). Results showed that carbonates and fluoride did not produce a detrimental effect on the 2,4-D degradation, while phosphate inhibited the process. In this case, the pH increased also from 7.0 to 7.95 and 8.99. Effect of parameters such as pH, iron concentration, and hydrogen peroxide concentration on the 2,4-D degradation by the photo-Fenton process in groundwater was evaluated by using a factorial experimental design 2(3). Results showed that the pH was the main parameter affecting the process. This study shows for the first time that using the photo-Fenton process at circumneutral pH and iron naturally present seems to be a promising process to remove pesticides from groundwater.

  14. The impact on climate of groundwater induced soil moisture memory : a study with a fully coupled WRF-LEAFHYDRO system

    Science.gov (United States)

    Miguez-Macho, Gonzalo; Gómez, Breogán; Martínez-de la Torre, Alberto

    2014-05-01

    Groundwater dynamics and its interactions with the land-atmosphere system are increasingly being taking into consideration in climate and ecosystem modeling studies. A shallow water table slows down drainage and affects soil moisture and potentially evapotranspiration (ET) and climate, particularly in water-limited environments. Our area of interest, the Iberian Peninsula, with a typical Mediterranean climate of dry growing season, is one of such regions where ET is largely constrained by water availability. We investigate how the induced memory on soil moisture by groundwater affects spring precipitation and summer temperatures there using a fully coupled WRF-LEAFHYDRO system. The LEAFHYDRO Land Surface Model includes groundwater dynamics with a realistic water table validated with hundreds of observations over Spain and Portugal. We perform two sets of long-term offline simulations, with and without groundwater forced by ERA-Interim and detailed precipitation analyses for the Iberian Peninsula. The corresponding fully coupled simulations with the Weather Research and Forecasting model (WRF), using exactly the same grid, take initial conditions from the off-line simulations at the end of the winter and are run for spring and summer, when we expect the impact of ET on climate to be largest. After a dry winter, in the run with groundwater soils are considerably wetter in regions with shallow water table and WRF results indicate that during spring the impact on precipitation can be sizeable when synoptic conditions are favorable for convection. Increased ET in the summer due also to more moisture availability in the run with groundwater leads in general to cooler temperatures. These preliminary results highlight the important role of groundwater on climate and the advantages of a fully coupled hydrology-atmospheric modeling system.

  15. Summary of inorganic compositional data for groundwater, soil-water, and surface-water samples collected at the Headgate Draw subsurface drip irrigation site, Johnson County, Wyoming

    Science.gov (United States)

    Geboy, Nicholas J.; Engle, Mark A.; Schroeder, Karl T.; Zupancic, John W.

    2011-01-01

    As part of a 5-year project on the impact of subsurface drip irrigation (SDI) application of coalbed-methane (CBM) produced waters, water samples were collected from the Headgate Draw SDI site in the Powder River Basin, Wyoming, USA. This research is part of a larger study to understand short- and long-term impacts on both soil and water quality from the beneficial use of CBM waters to grow forage crops through use of SDI. This document provides a summary of the context, sampling methodology, and quality assurance and quality control documentation of samples collected prior to and over the first year of SDI operation at the site (May 2008-October 2009). This report contains an associated database containing inorganic compositional data, water-quality criteria parameters, and calculated geochemical parameters for samples of groundwater, soil water, surface water, treated CBM waters, and as-received CBM waters collected at the Headgate Draw SDI site.

  16. Summary of Inorganic Compositional Data for Groundwater, Soil-Water, and Surface-Water Samples at the Headgate Draw Subsurface Drip Irrigation Site

    Energy Technology Data Exchange (ETDEWEB)

    Geboy, Nicholas J.; Engle, Mark A.; Schroeder, Karl T.; Zupanic, John W.

    2007-01-01

    As part of a 5-year project on the impact of subsurface drip irrigation (SDI) application of coalbed-methane (CBM) produced waters, water samples were collected from the Headgate Draw SDI site in the Powder River Basin, Wyoming, USA. This research is part of a larger study to understand short- and long-term impacts on both soil and water quality from the beneficial use of CBM waters to grow forage crops through use of SDI. This document provides a summary of the context, sampling methodology, and quality assurance and quality control documentation of samples collected prior to and over the first year of SDI operation at the site (May 2008-October 2009). This report contains an associated database containing inorganic compositional data, water-quality criteria parameters, and calculated geochemical parameters for samples of groundwater, soil water, surface water, treated CBM waters, and as-received CBM waters collected at the Headgate Draw SDI site.

  17. Hydrogeology and simulation of groundwater flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system, Texas, 1891-2009

    Science.gov (United States)

    Kasmarek, Mark C.

    2012-01-01

    In cooperation with the Harris–Galveston Subsidence District, Fort Bend Subsidence District, and Lone Star Groundwater Conservation District, the U.S. Geological Survey developed and calibrated the Houston Area Groundwater Model (HAGM), which simulates groundwater flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system in Texas from predevelopment (before 1891) through 2009. Withdrawal of groundwater since development of the aquifer system has resulted in potentiometric surface (hydraulic head, or head) declines in the Gulf Coast aquifer system and land-surface subsidence (primarily in the Houston area) from depressurization and compaction of clay layers interbedded in the aquifer sediments.

  18. A Geology Sampling System for Small Bodies

    Science.gov (United States)

    Naids, Adam J.; Hood, Anthony D.; Abell, Paul; Graff, Trevor; Buffington, Jesse

    2016-01-01

    Human exploration of microgravity bodies is being investigated as a precursor to a Mars surface mission. Asteroids, comets, dwarf planets, and the moons of Mars all fall into this microgravity category and some are being discussed as potential mission targets. Obtaining geological samples for return to Earth will be a major objective for any mission to a small body. Currently, the knowledge base for geology sampling in microgravity is in its infancy. Humans interacting with non-engineered surfaces in microgravity environment pose unique challenges. In preparation for such missions a team at the NASA Johnson Space Center has been working to gain experience on how to safely obtain numerous sample types in such an environment. This paper describes the type of samples the science community is interested in, highlights notable prototype work, and discusses an integrated geology sampling solution.

  19. A Geology Sampling System for Microgravity Bodies

    Science.gov (United States)

    Hood, Anthony; Naids, Adam

    2016-01-01

    Human exploration of microgravity bodies is being investigated as a precursor to a Mars surface mission. Asteroids, comets, dwarf planets, and the moons of Mars all fall into this microgravity category and some are been discussed as potential mission targets. Obtaining geological samples for return to Earth will be a major objective for any mission to a microgravity body. Currently the knowledge base for geology sampling in microgravity is in its infancy. Humans interacting with non-engineered surfaces in microgravity environment pose unique challenges. In preparation for such missions a team at the NASA Johnson Space Center has been working to gain experience on how to safely obtain numerous sample types in such an environment. This paper describes the type of samples the science community is interested in, highlights notable prototype work, and discusses an integrated geology sampling solution.

  20. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation.

    Science.gov (United States)

    De Biase, Cecilia; Carminati, Andrea; Oswald, Sascha E; Thullner, Martin

    2013-11-01

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile losses to the atmosphere. Especially for (potentially) toxic VOCs, the latter needs to be minimized to limit atmospheric emissions. In this study, numerical simulation was used to investigate quantitatively the removal of volatile organic compounds in two pilot-scale water treatment systems: an unplanted vertical flow filter and a planted one, which could also be called a vertical flow constructed wetland, both used for the treatment of contaminated groundwater. These systems were intermittently loaded with contaminated water containing benzene and MTBE as main VOCs. The highly dynamic but permanently unsaturated conditions in the porous medium facilitated aerobic biodegradation but could lead to volatile emissions of the contaminants. Experimental data from porous material analyses, flow rate measurements, solute tracer and gas tracer test, as well as contaminant concentration measurements at the boundaries of the systems were used to constrain a numerical reactive transport modeling approach. Numerical simulations considered unsaturated water flow, transport of species in the aqueous and the gas phase as well as aerobic degradation processes, which made it possible to quantify the rates of biodegradation and volatile emissions and calculating their contribution to total contaminant removal. A range of degradation rates was determined using experimental results of both systems under two operation modes and validated by field data obtained at different operation modes applied to the filters. For both filters, simulations and experimental data point to high biodegradation rates, if the flow filters have had time to build up their removal capacity. For this case volatile

  1. Chemical characteristics of surface systems in the Forsmark area. Visualisation and statistical evaluation of data from surface water, precipitation, shallow groundwater, and regolith

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-02-15

    The Swedish Nuclear Fuel and Waste management Co (SKB) initiated site investigations for a deep repository for spent nuclear fuel at two different sites in Sweden, Forsmark and Oskarshamn, in 2002. This report evaluates the results from chemical investigations of the surface system in the Forsmark area during the period November 2002 - March 2005. The evaluation includes data from surface waters (lakes, streams and the sea), precipitation, shallow groundwater and regolith (till, soil, peat, sediments and biota) in the area. Results from surface waters are not presented in this report since these were treated in a recently published report. The main focus of the study is to visualize the vast amount of data collected hitherto in the site investigations, and to give a chemical characterisation of the investigated media at the site. The results will be used to support the site descriptive models, which in turn are used for safety assessment studies and for the environmental impact assessment. The data used consist of water chemical composition in lakes, streams, coastal sites, and in precipitation, predominantly sampled on a monthly basis, and in groundwater from soil tubes and wells, sampled up to four times per year. Moreover, regolith data includes information on the chemical composition of till, soil, sediment and vegetation samples from the area. The characterisations include all measured chemical parameters, i.e. major and minor constituents, trace elements, nutrients, isotopes and radio nuclides, as well as field measured parameters. The evaluation of data from each medium has been divided into the following parts: Characterisation of individual sampling sites, and comparisons within and among sampling sites as well as comparisons with local, regional and national reference data; Analysis of time trends and seasonal variation (for shallow groundwater); Exploration of relationships among the various chemical parameters. For all investigated parameters, the

  2. Groundwater Nitrate Contamination Risk Assessment: A Comparison of Parametric Systems and Simulation Modelling

    Directory of Open Access Journals (Sweden)

    Dario Sacco

    2007-01-01

    Full Text Available Groundwater nitrate contamination is a source of rising concern that has been faced through the introduction of several regulations in different countries. However the methodologies used in the definition of Nitrate Vulnerable Zones are not included in the regulations. The aim of this work was to compare different methodologies, used to asses groundwater nitrate contamination risks, based on parametric systems or simulation modelling. The work was carried out in Piedmont, Italy, in an area characterised by intensive animal husbandry, high N load, a shallow water table and a coarse type of sub-soil sediments. Only N loads from agricultural non-point sources were considered. Different methodologies with different level of information have been compared to determine the groundwater nitrate contamination risk assessment: N load, IPNOA index, the intrinsic contamination risk from nitrates, leached N and N concentration of the soil solution estimated by the simulation model. The good correlation between the IPNOA index and the intrinsic nitrate contamination risk revealed that the parameters that describe the soil in this area did not lead to a different classification of the parcels. The intrinsic nitrate contamination risk was greatly influenced by N fertilisation, however the effect of the soils increased the variability in comparison to the IPNOA index. The leached N and N concentration in the leaching were closely correlated. The dilution effect of percolated water was almost negligible. Both methodologies were slightly correlated to the N fertilisation and the two indexes. The correlations related to the intrinsic nitrate contamination risk was higher than those related to IPNOA, and this means that the effect of taking into account soil parameters increases the correlation to the prediction of the simulation model.

  3. A conceptual hydrogeologic model for the hydrogeologic framework, geochemistry, and groundwater-flow system of the Edwards-Trinity and related aquifers in the Pecos County region, Texas

    Science.gov (United States)

    Thomas, Jonathan V.; Stanton, Gregory P.; Bumgarner, Johnathan R.; Pearson, Daniel K.; Teeple, Andrew; Houston, Natalie A.; Payne, Jason; Musgrove, MaryLynn

    2013-01-01

    The Edwards-Trinity aquifer is a vital groundwater resource for agricultural, industrial, and municipal uses in the Trans-Pecos region of west Texas. A conceptual model of the hydrogeologic framework, geochemistry, and groundwater-flow system in the 4,700 square-mile study area was developed by the U.S. Geological Survey (USGS) in cooperation with the Middle Pecos Groundwater Conservation District, Pecos County, City of Fort Stockton, Brewster County, and Pecos County Water Control and Improvement District No. 1. The model was developed to gain a better understanding of the groundwater system and to establish a scientific foundation for resource-management decisions. Data and information were collected or obtained from various sources to develop the model. Lithologic information obtained from well reports and geophysical data were used to describe the hydrostratigraphy and structural features of the groundwater system, and aquifer-test data were used to estimate aquifer hydraulic properties. Groundwater-quality data were used to evaluate groundwater-flow paths, water and rock interaction, aquifer interaction, and the mixing of water from different sources. Groundwater-level data also were used to evaluate aquifer interaction as well as to develop a potentiometric-surface map, delineate regional groundwater divides, and describe regional groundwater-flow paths.

  4. A generalized solution for groundwater head fluctuation in a tidal leaky aquifer system

    Indian Academy of Sciences (India)

    Mo-Hsiung Chuang; Hund-Der Yeh

    2011-12-01

    A new analytical solution is developed for describing groundwater level fluctuations in a coupled leaky confined aquifer system which consists of an unconfined aquifer, confined aquifer, and an aquitard in between. The aquifer system has a tidal boundary at the seashore, a no flow boundary at remote inland side, and a confined aquifer extending under the sea and terminated with an outlet-capping. This new solution has shown to be a generalisation of most existing analytical solutions for a tidal aquifer system which includes single confined and leaky confined aquifers. In addition, the solution is used to explore the influences of the dimensionless leakance of the outlet-capping, the dimensionless hydraulic diffusivities, and the leakages of the inland and offshore aquitards on the head responses in the leaky confined aquifer.

  5. A biotic Fe0-H2O system for nitrobenzene removal from groundwater

    DEFF Research Database (Denmark)

    Wu, Jinhua; Yin, Weizhao; Gu, Jingjing;

    2013-01-01

    Batch experiment was conducted to evaluate the capability of a biotic Fe0-H2O for nitrobenzene (NB) removal from groundwater. In this study, iron dosage was 0.25gL-1 throughout the whole experiment and the Fe0-H2O system was amended with 180mgL-1 VSS of mixed culture. The biotic system was tested...... at low concentrations (50mgL-1 as COD) of organic substrates (e.g., ethanol, glucose and sodium acetate) and different concentrations of sulfate, nitrate and dissolved oxygen. The bio-iron system exhibited higher NB removal rate and more AN production. The increasing order of efficiency of tested......), and nitrate showed more significant suppression on NB removal as compared to sulfate. AN elimination occurred during both sulfate-reducing and nitrate-reducing processes and microorganisms got extra reduction capacity from the degradation of AN to reduce nitrate and sulfate, causing the mineralization of NB...

  6. Simulated potentiometric surface contours at end of simulation (1998) in model layer 1 of the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These contours represent the simulated potentiometric surface at the end of simulation (1998) in model layer 1 of the Death Valley regional ground-water flow system...

  7. Simulated potentiometric surface contours at end of simulation (1998) in model layer 16 of the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These contours represent the simulated potentiometric surface at the end of simulation (1998) in model layer 16 of the Death Valley regional ground-water flow system...

  8. Simulated potentiometric surface contours at end of simulation (1998) in model layer 1 of the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These contours represent the simulated potentiometric surface at the end of simulation (1998) in model layer 1 of the Death Valley regional ground-water flow system...

  9. An Aquifer Storage and Recovery system with reclaimed wastewater to preserve native groundwater resources in El Paso, Texas.

    Science.gov (United States)

    Sheng, Zhuping

    2005-06-01

    The traditional concept of Aquifer Storage and Recovery (ASR) has been emphasized and extensively applied for water resources conservation in arid and semi-arid regions using groundwater systems as introduced in Pyne's book titled Groundwater Recharge and Wells. This paper extends the ASR concept to an integrated level in which either treated or untreated surface water or reclaimed wastewater is stored in a suitable aquifer through a system of spreading basins, infiltration galleries and recharge wells; and part or all of the stored water is recovered through production wells, dual function recharge wells, or by streams receiving increased discharge from the surrounding recharged aquifer as needed. In this paper, the author uses the El Paso Water Utilities (EPWU) ASR system for injection of reclaimed wastewater into the Hueco Bolson aquifer as an example to address challenges and resolutions faced during the design and operation of an ASR system under a new ASR system definition. This new ASR system concept consists of four subsystems: source water, storage space-aquifer, recharge facilities and recovery facilities. Even though facing challenges, this system has successfully recharged approximately 74.7 million cubic meters (19.7 billion gallons) of reclaimed wastewater into the Hueco Bolson aquifer through 10 recharge wells in the last 18 years. This ASR system has served dual purposes: reuse of reclaimed wastewater to preserve native groundwater, and restoration of groundwater by artificial recharge of reclaimed wastewater into the Hueco Bolson aquifer.

  10. Sample Return Systems for Extreme Environments Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In Phase I we were able to demonstrate that sample return missions utilizing high velocity penetrators (0.1- 1 km/s) could provide substantial new capabilities for...

  11. Model grid and infiltration values for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the model grid and infiltration values simulated in the transient ground-water flow model of the Death Valley regional ground-water...

  12. Boundary of the ground-water flow model by IT Corporation (1996), for the Death Valley regional ground-water flow system study, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the boundary of the steady-state ground-water flow model built by IT Corporation (1996). The regional, 20-layer ground-water flow...

  13. Model grid and infiltration values for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the model grid and infiltration values simulated in the transient ground-water flow model of the Death Valley regional ground-water...

  14. Apparatus and method for time-integrated, active sampling of contaminants in fluids demonstrated by monitoring of hexavalent chromium in groundwater.

    Science.gov (United States)

    Roll, Isaac B; Driver, Erin M; Halden, Rolf U

    2016-06-15

    Annual U.S. expenditures of $2B for site characterization invite the development of new technologies to improve data quality while reducing costs and minimizing uncertainty in groundwater monitoring. This work presents a new instrument for time-integrated sampling of environmental fluids using in situ solid-phase extraction (SPE). The In Situ Sampler (IS2) is an automated submersible device capable of extracting dissolved contaminants from water (100s-1000smL) over extended periods (hours to weeks), retaining the analytes, and rejecting the processed fluid. A field demonstration of the IS2 revealed 28-day average concentration of hexavalent chromium in a shallow aquifer affected by tidal stresses via sampling of groundwater as both liquid and sorbed composite samples, each obtained in triplicate. In situ SPE exhibited 75±6% recovery and an 8-fold improvement in reporting limit. Relative to use of conventional methods (100%), beneficial characteristics of the device and method included minimal hazardous material generation (2%), transportation cost (10%), and associated carbon footprint (2%). The IS2 is compatible with commercial SPE resins and standard extraction methods, and has been certified for more general use (i.e., inorganics and organics) by the Environmental Security Technology Certification Program (ESTCP) of the U.S. Department of Defense.

  15. Design and testing of a process-based groundwater vulnerability assessment (P-GWAVA) system for predicting concentrations of agrichemicals in groundwater across the United States

    Science.gov (United States)

    Barbash, Jack E; Voss, Frank D.

    2016-03-29

    Efforts to assess the likelihood of groundwater contamination from surface-derived compounds have spanned more than three decades. Relatively few of these assessments, however, have involved the use of process-based simulations of contaminant transport and fate in the subsurface, or compared the predictions from such models with measured data—especially over regional to national scales. To address this need, a process-based groundwater vulnerability assessment (P-GWAVA) system was constructed to use transport-and-fate simulations to predict the concentration of any surface-derived compound at a specified depth in the vadose zone anywhere in the conterminous United States. The system was then used to simulate the concentrations of selected agrichemicals in the vadose zone beneath agricultural areas in multiple locations across the conterminous United States. The simulated concentrations were compared with measured concentrations of the compounds detected in shallow groundwater (that is, groundwater drawn from within a depth of 6.3 ± 0.5 meters [mean ± 95 percent confidence interval] below the water table) in more than 1,400 locations across the United States. The results from these comparisons were used to select the simulation approaches that led to the closest agreement between the simulated and the measured concentrations.The P-GWAVA system uses computer simulations that account for a broader range of the hydrologic, physical, biological and chemical phenomena known to control the transport and fate of solutes in the subsurface than has been accounted for by any other vulnerability assessment over regional to national scales. Such phenomena include preferential transport and the influences of temperature, soil properties, and depth on the partitioning, transport, and transformation of pesticides in the subsurface. Published methods and detailed soil property data are used to estimate a wide range of model input parameters for each site, including surface

  16. Groundwater quality in the alluvial aquifer system of northwest India: New evidence of the extent of anthropogenic and geogenic contamination.

    Science.gov (United States)

    Lapworth, D J; Krishan, G; MacDonald, A M; Rao, M S

    2017-12-01

    Groundwater depletion has been widely studied in northwest India, but water quality concerns are still poorly constrained. In this study, we explore the hydrochemistry of the top 160m of the aquifer system, through detailed field studies in the Bist-Doab region, considering both anthropogenic and geogenic controls. A detailed comparison is made between sites dominated by urban and agricultural landuse. Salinity, nitrate, chloride and lead concentrations are significantly higher in the shallow (0-50m) groundwater system due to surface anthropogenic contaminant loading from agricultural and urban sources. The widespread occurrence of oxic groundwater within the aquifer system means that denitrification potential is limited and also enhances the mobility of selenium and uranium in groundwater. Geogenic trace elements (e.g. As, Se, F), are generally found at concentrations below WHO guideline drinking water values, however elevated U concentrations (50-70μg/L) are found within the deeper part of the aquifer and shallow urban aquifers associated with higher bicarbonate waters. Higher concentration of Se (10-40μg/L) are found exclusively in the shallow groundwater system where Se is mobilised from soils and transported to depth in the shallow aquifer due to the prevailing oxidising aquifer conditions. New evidence from a range of environmental tracers shows elevated concentrations of anthropogenic contaminants in the deeper part of the aquifer (50-160m deep) and demonstrates vulnerability to vertical migration of contaminants. Continued intensive groundwater abstraction from >100m deep means that water quality risks to the deep aquifer system need to be considered together with water quantity constraints. Copyright © 2017. Published by Elsevier B.V.

  17. Performance of in-situ soil and groundwater treatment systems at McClellan Air Force Base