WorldWideScience

Sample records for groundwater remediation technology

  1. Remediation Technology for Contaminated Groundwater

    Science.gov (United States)

    Bioremediation is the most commonly selected technology for remediation of ground water at Superfund sites in the USA. The next most common technology is Chemical treatment, followed by Air Sparging, and followed by Permeable Reactive Barriers. This presentation reviews the the...

  2. ALTERNATIVE REMEDIATION TECHNOLOGY STUDY FOR GROUNDWATER TREATMENT AT 200-PO-1 OPERABLE UNIT AT HANFORD SITE

    Energy Technology Data Exchange (ETDEWEB)

    DADO MA

    2008-07-31

    This study focuses on the remediation methods and technologies applicable for use at 200-PO-I Groundwater Operable Unit (OU) at the Hanford Site. The 200-PO-I Groundwater au requires groundwater remediation because of the existence of contaminants of potential concern (COPC). A screening was conducted on alternative technologies and methods of remediation to determine which show the most potential for remediation of groundwater contaminants. The possible technologies were screened to determine which would be suggested for further study and which were not applicable for groundwater remediation. COPCs determined by the Hanford Site groundwater monitoring were grouped into categories based on properties linking them by remediation methods applicable to each COPC group. The screening considered the following criteria. (1) Determine if the suggested method or technology can be used for the specific contaminants found in groundwater and if the technology can be applied at the 200-PO-I Groundwater au, based on physical characteristics such as geology and depth to groundwater. (2) Evaluate screened technologies based on testing and development stages, effectiveness, implementability, cost, and time. This report documents the results of an intern research project conducted by Mathew Dado for Central Plateau Remediation in the Soil and Groundwater Remediation Project. The study was conducted under the technical supervision of Gloria Cummins and management supervision of Theresa Bergman and Becky Austin.

  3. Development and applications of groundwater remediation technologies in the USA

    Science.gov (United States)

    Barcelona, Michael J.

    2005-03-01

    The future of the development and application of groundwater remediation technologies will unfold in an atmosphere of heightened public concern and attention. Cleanup policy will undergo incremental change towards more comprehensive efforts which account for the impact of remediation on nearby resources. Newly discovered contaminants will cause the re-examination of "mature" technologies since they may be persistent, mobile and difficult to treat in-situ. Evaluations of the effectiveness of remedial technologies will eventually include by-product formation, geochemical consequences and sustainability. Long-term field trials of remedial technologies alone can provide the data necessary to support claims of effectiveness. Dans le futur, le développement et les applications des technologies de traitement des eaux souterraines seront déroulés en tenant compte de l'inquiétude et l'attention croissante de l'opinion publique. La politique de nettoyage va subir un changement vers des efforts plus compréhensifs qui prendront en compte l'impact du traitement sur les ressources voisines. Les nouveaux contaminants seront persistants, mobiles et difficile de traiter in situ; par conséquence ils vont provoquer la reexamination des technologies consacrées. L'évaluation de l'efficacité des technologies de traitement doit considérer l'apparition des produits secondaires ainsi que les conséquences géochimiques et le développement durable. Seulement les essais in situ, pendant des longues périodes sur les technologies peuvent fournir les éléments nécessaires pour démontrer leur efficacité. El futuro del desarrollo y de la aplicación de las tecnologías para la recuperación del agua subterránea, se revelará en una atmósfera de gran atención e interés público elevado. La política de limpieza sufrirá un cambio adicional hacia esfuerzos más tangibles, los cuales incluyan el impacto de la recuperación en los recursos circundantes. Los contaminantes

  4. A Sustainability Assessment Methodology for Prioritizing the Technologies of Groundwater Contamination Remediation

    DEFF Research Database (Denmark)

    An, Da; Xi, Beidou; Wang, Yue

    2016-01-01

    More and more groundwater has 23 been polluted recently, and technologies for groundwater contamination remediation are of vital importance; however, it is usually difficult for the users to select the most suitable technology among multiple alternatives. In order to address this, this study aims...... at developing a sustainability assessment framework for prioritizing the technologies for groundwater contamination remediation by combining the concept of sustainability and multi-criteria decision making (MCDM) method. A criterion system which consists of six criteria in three aspects has been proposed...... for sustainability assessment of technologies for groundwater contamination remediation, and a novel MCDM method by combining the logarithmic fuzzy preference programming based fuzzy analytic hierarchy process and the improved ELECTRE method has been developed for prioritizing the alternatives. In order...

  5. Solutions Remediate Contaminated Groundwater

    Science.gov (United States)

    2010-01-01

    During the Apollo Program, NASA workers used chlorinated solvents to clean rocket engine components at launch sites. These solvents, known as dense non-aqueous phase liquids, had contaminated launch facilities to the point of near-irreparability. Dr. Jacqueline Quinn and Dr. Kathleen Brooks Loftin of Kennedy Space Center partnered with researchers from the University of Central Florida's chemistry and engineering programs to develop technology capable of remediating the area without great cost or further environmental damage. They called the new invention Emulsified Zero-Valent Iron (EZVI). The groundwater remediation compound is cleaning up polluted areas all around the world and is, to date, NASA's most licensed technology.

  6. Use of iron-based technologies in contaminated land and groundwater remediation: A review

    Energy Technology Data Exchange (ETDEWEB)

    Cundy, Andrew B. [School of Environment and Technology, University of Brighton, Lewes Road, Brighton BN2 4GJ (United Kingdom)], E-mail: A.Cundy@brighton.ac.uk; Hopkinson, Laurence [School of Environment and Technology, University of Brighton, Lewes Road, Brighton BN2 4GJ (United Kingdom); Whitby, Raymond L.D. [School of Pharmacy and Biomolecular Sciences, University of Brighton, Lewes Road, Brighton BN2 4GJ (United Kingdom)

    2008-08-01

    Reactions involving iron play a major role in the environmental cycling of a wide range of important organic, inorganic and radioactive contaminants. Consequently, a range of environmental clean-up technologies have been proposed or developed which utilise iron chemistry to remediate contaminated land and surface and subsurface waters, e.g. the use of injected zero zero-valent iron nanoparticles to remediate organic contaminant plumes; the generation of iron oxyhydroxide-based substrates for arsenic removal from contaminated waters; etc. This paper reviews some of the latest iron-based technologies in contaminated land and groundwater remediation, their current state of development, and their potential applications and limitations.

  7. Bioaugmentation for Groundwater Remediation

    Science.gov (United States)

    2010-02-01

    emulsified vegetable oil EX extraction well FRTR Federal Remediation Technologies Roundtable gpm gallon per minute GSA General Services Administration...logic controller PRB permeable reactive barrier PVC polyvinyl chloride ACRONYMS AND ABBREVIATIONS (continued) viii qPCR quantitative...situ growth of DHC and degradation of target contaminants. A slow-release carbon source, such as emulsified vegetable oil (EVO) is often utilized with

  8. Assessing the Life Cycle Impact of Four Groundwater Remediation Technologies: P&T, EIB, PRB, and ISM

    Science.gov (United States)

    Hou, D.; Al-Tabbaa, A.

    2012-12-01

    As sustainable remediation draws attention from both industry and academia, there is growing interest in evaluating the environmental sustainability of various environmental remediation technologies. This study aims at assessing four groundwater remediation technologies from a life cycle impact perspective: pump and treat (P&T), enhanced in-situ bioremediation (EIB), permeable reactive barrier (PRB), and in-situ soil mixing (ISM). The technologies were compared under a variety of scenarios, with site location, plume dimension, hydrology, and chemistry and geochemistry parameters changing in a wide range. This life cycle assessment (LCA) has chosen chlorinated ethylene as the study subject because chlorinated solvents are the most prevalent organic contaminants in soil and groundwater. The USEPA TRACI method was used in the life cycle impact assessment (LCIA). A multi-criteria decision analysis (MCDA) score is used to rank the four remediation technologies. The assessment results indicated that P&T tended to have the highest life cycle impact under most scenarios. The other three technologies can all be the most desired technology (with lowest life cycle impact), under different distributional, hydrogeological, and chemical conditions: PRB was the most desired when treatment zone was long, hydraulic gradient or hydraulic conductivity was low, or contaminants degraded fast in the reactive media; ISM became the most desirable when hydraulic gradient or hydraulic conductivity was very high; and EIB was most desirable under most other conditions.

  9. Assessment and remediation of a historical pipeline release : tools, techniques and technologies applied to in-situ/ex-situ soil and groundwater remediation

    Energy Technology Data Exchange (ETDEWEB)

    Reid, N. [EBA Engineering Consultants Ltd., Calgary, AB (Canada); Kohlsmith, B. [Kinder Morgan Canada Inc., Calgary, AB (Canada)

    2008-07-01

    Tools, techniques, and technologies applied to in-situ/ex-situ soil and groundwater remediation were presented as part of an assessment and remediation of a historical pipeline release. The presentation discussed the initial assessment, as well as a discussion of remediation of hydrophobic soils, re-assessment, site specific criteria, a remediation trial involving bioventing and chemical oxidation, and a full scale remediation. The pipeline release occurred in the summer of 1977. The event was followed by a complete surface remediation with a significant amount of topsoil being removed and replaced. In 2004, a landowner complained of poor crop growth in four patches near the area of the historical spill. An initial assessment was undertaken and several photographs were presented. It was concluded that a comprehensive assessment set the base for a careful staged approach to the remediation of the site including the establishment of site specific criteria. The process was made possible with a high level of communication between all stakeholders. In addition, the most appropriate solution for the site was realized. figs.

  10. Remedies proposed for China's groundwater problems

    Science.gov (United States)

    Loaiciga, Hugo A.

    Groundwater experts and hydrologists from China and 10 other nations recently gathered in Beijing to exchange state-of-the-art scientific and technological knowledge on groundwater hydrology, modeling, remediation, and management. The participants also reviewed groundwater environmental conditions in China, identified key problems, and made recommendations to help guide the nation's groundwater policy.The Regional Workshop on Ground Water Contamination, held from July 31 to August 4, 1995, was the fifth of a series of regional workshops sponsored by the Scientific Committee on Problems of the Environment of the United Nations Environmental Program. Earlier workshops were held in Thailand (1991), Costa Rica (1993), the Czech Republic (1994), and Australia (1994).

  11. Life cycle assessment of soil and groundwater remediation technologies: literature review

    DEFF Research Database (Denmark)

    Lemming, Gitte; Hauschild, Michael Zwicky; Bjerg, Poul Løgstrup

    2010-01-01

    Background, aim, and scope Life cycle assessment (LCA) is becoming an increasingly widespread tool in support systems for environmental decision-making regarding the cleanup of contaminated sites. In this study, the use of LCA to compare the environmental impacts of different remediation...... and scope definition and the applied impact assessment. The studies differ in their basic approach since some are prospective with focus on decision support while others are retrospective aiming at a more detailed assessment of a completed remediation project. Literature review The literature review showed...... scenarios in terms of their associated environmental burden. Main features An overview of the assessed remediation technologies and contaminant types covered in the literature is presented. The LCA methodologies of the 12 reviewed studies were compared and discussed with special focus on their goal...

  12. Implementing heterogeneous catalytic dechlorination technology for remediating TCE-contaminated groundwater.

    Science.gov (United States)

    Davie, Matthew G; Cheng, Hefa; Hopkins, Gary D; Lebron, Carmen A; Reinhard, Martin

    2008-12-01

    To transition catalytic reductive dechlorination (CRD) into practice, it is necessary to demonstrate the effectiveness, robustness, and economic competitiveness of CRD-based treatment systems. A CRD system scaled up from previous laboratory studies was tested for remediating groundwater contaminated with 500-1200 microg L(-1) trichloroethylene (TCE) at Edwards Air Force Base (AFB), California. Groundwater was pumped from a treatment well at 2 gal min(-1), amended with hydrogen to 0.35 mg L(-1) and contacted for 2.3 min with 20 kg eggshell-coated Pd on alumina beads (2% Pd by wt) packed in a fixed-bed reactor, and then returned to the aquifer. Operation was continuous for 23 h followed a 1 h regeneration cycle. After regeneration, TCE removal was 99.8% for 4 to 9 h and then declined to 98.3% due to catalyst deactivation. The observed catalyst deactivation was tentatively attributed to formation of sulfidic compounds; modeling of catalyst deactivation kinetics suggests the presence of sulfidic species equivalent to 2-4 mg L(-1) hydrogen sulfide in the reactor water. Over the more than 100 day demonstration period, TCE concentrations in the treated groundwater were reduced by >99% to an average concentration of 4.1 microg L(-1). The results demonstrate CRD as a viable treatment alternative technically and economically competitive with activated carbon adsorption and other conventional physicochemical treatmenttechnologies.

  13. Evaluation of Groundwater Remediation Technologies Based on Fuzzy Multi-Criteria Decision Analysis Approaches

    Directory of Open Access Journals (Sweden)

    Hao Wang

    2017-06-01

    Full Text Available Petroleum is an essential resource for the development of society and its production is huge. There is a great risk of leakage of oil during production, refining, and transportation. After entering the environment, the oil pollutants will be a great threat to the environment and may endanger human health. Therefore, it is very important to remediate oil pollution in the subsurface. However, it is necessary to choose the appropriate remediation technology. In this paper, 18 technologies are evaluated through constructing a parameter matrix with each technology and seven performance indicators, and a comprehensive analysis model is presented. In this model, four MCDA methods are used. They are SWA (Simple Weighted Addition Method, WP (Weighted Product Method, CGT (Cooperative Game Theory, and TOPSIS (Technique for Order Preference by Similarity to Ideal Solution. Mean ranking and Borda ranking methods are used to integrate the results of SWA, WP, CGT, and TOPSIS. Then two selection priorities of each method (mean ranking and Borda ranking are obtained. The model is proposed to help decide the best choice of remediation technologies. It can effectively reduce contingency, subjectivity, one-sidedness of the traditional methods and provide scientific reference for effective decision-making.

  14. The option to abandon : Stimulating innovative, groundwater remediation technologies characterized by technologies and uncertainty

    NARCIS (Netherlands)

    Compernolle, T.; van Passel, S.; Huisman, K.J.M.; Kort, P.M.

    2014-01-01

    Many studies on technology adoption demonstrate that uncertainty leads to a postponement of investments by integrating a wait option in the economic analysis. The aim of this study however is to demonstrate how the investment in new technologies can be stimulated by integrating an option to abandon.

  15. EFFECT OF GROUND-WATER REMEDIATION ACTIVITIES ON INDIGENOUS MICROFLORA

    Science.gov (United States)

    The United States Environmental Protection Agency (EPA), working with the Interagency DNAPL Consortium, completed an independent evaluation of microbial responses to ground-water remediation technology demonstrations at Launch Pad 34 at Cape Canaveral Air Station in Brevard Count...

  16. Detection and Remediation of Groundwater Pollution

    Institute of Scientific and Technical Information of China (English)

    王杰

    2016-01-01

    Groundwater is an important part of the water cycle and is also widely used as sources of drinking water. With the increasing de?velopment of groundwater exploitation, the pollution is becoming more and more serious. This paper talks about the main research direc?tions of groundwater pollution, the detection, the remediation and some conclusions.

  17. Groundwater Contamination: DOD Uses and Develops a Range of Remediation Technologies to Clean Up Military Sites

    Science.gov (United States)

    2005-06-01

    DNAPL dense nonaqueous phase liquids DOD Department of Defense EPA Environmental Protection Agency ESTCP Environmental Security Technology Certification...copper, lead, mercury , selenium, silver, and zinc. eIncludes, but is not limited to, oxygen-bearing chemicals that can be added to fuel to bring...technology is applicable to both dense and light nonaqueous phase liquids ( DNAPL and LNAPL).3 Benefits of enhanced recovery approaches include the

  18. Waste minimization in the remediation of contaminated sites: using the oil belt skimmer technology for the removal of heavy hydrocarbons from groundwater.

    Science.gov (United States)

    De Gisi, Sabino; Notarnicola, Michele

    2016-12-01

    Modern society increasingly requires achieving the goal of remediation and at the same time minimizing the waste to be disposed. Although the pump and treat is a consolidated technology option for the decontamination of groundwater polluted by heavy hydrocarbons, it generates an excessive amount of waste (typically, dangerous). With the intent of reducing such waste, our study is concerned with the verification of the oil belt skimmer technology for the decontamination of a heavy hydrocarbon-polluted groundwater. For this purpose, several tests at laboratory scale and full-scale experimentations with duration greater than 1 year were carried out. The obtained results showed the feasibility of the investigated technology for groundwater decontamination in the cases where the water mobility (of the aquifer) was low and in the presence of oil thicknesses greater than 2 cm. The heavy hydrocarbon recovery capacities were in the range of 33.3-85.5 l/h with the best performances in the cases of supernatant thickness ≥2 cm and pumping of the water table in such a way that the oil acquires a higher mobility in the aquifer. Moreover, the recovery capacity was found to be dependent on the rainfall pattern as well as on the groundwater fluctuation. Compared to the pump-and-treat system, the investigated technology allowed reducing by 98.7 % the amount of waste to be disposed suggesting the use in presence of high thickness of the oils. Finally, in a view of system optimization, treatment trains based on the combination of the oil belt skimmer technology and the pump-and-treat system should be carefully assessed.

  19. LCA of Soil and Groundwater Remediation

    DEFF Research Database (Denmark)

    Søndergaard, Gitte Lemming; Owsianiak, Mikolaj

    2017-01-01

    Today, there is increasing interest in applying LCA to support decision-makers in contaminated site management. In this chapter, we introduce remediation technologies and associated environmental impacts, present an overview of literature findings on LCA applied to remediation technologies and pr...

  20. Remediation Technology Collaboration Development

    Science.gov (United States)

    Mahoney, John; Olsen, Wade

    2010-01-01

    This slide presentation reviews programs at NASA aimed at development at Remediation Technology development for removal of environmental pollutants from NASA sites. This is challenging because there are many sites with different environments, and various jurisdictions and regulations. There are also multiple contaminants. There must be different approaches based on location and type of contamination. There are other challenges: such as costs, increased need for resources and the amount of resources available, and a regulatory environment that is increasing.

  1. Remediation of Groundwater Contaminated by Nuclear Waste

    Science.gov (United States)

    Parker, Jack; Palumbo, Anthony

    2008-07-01

    A Workshop on Accelerating Development of Practical Field-Scale Bioremediation Models; An Online Meeting, 23 January to 20 February 2008; A Web-based workshop sponsored by the U.S. Department of Energy Environmental Remediation Sciences Program (DOE/ERSP) was organized in early 2008 to assess the state of the science and knowledge gaps associated with the use of computer models to facilitate remediation of groundwater contaminated by wastes from Cold War era nuclear weapons development and production. Microbially mediated biological reactions offer a potentially efficient means to treat these sites, but considerable uncertainty exists in the coupled biological, chemical, and physical processes and their mathematical representation.

  2. Remediation Technologies Eliminate Contaminants

    Science.gov (United States)

    2012-01-01

    groundwater tainted by chlorinated solvents once used to clean rocket engine components. The award-winning innovation (Spinoff 2010) is now NASA s most licensed technology to date. PCBs in paint presented a new challenge. Removing the launch stand for recycling proved a difficult operation; the toxic paint had to be fully stripped from the steel structure, a lengthy and costly process that required the stripped paint to be treated before disposal. Noting the lack of efficient, environmentally friendly options for dealing with PCBs, Quinn and her colleagues developed the Activated Metal Treatment System (AMTS). AMTS is a paste consisting of a solvent solution containing microscale particles of activated zero-valent metal. When applied to a painted surface, the paste extracts and degrades the PCBs into benign byproducts while leaving the paint on the structure. This provides a superior alternative to other methods for PCB remediation, such as stripping the paint or incinerating the structure, which prevents reuse and can release volatized PCBs into the air. Since its development, AMTS has proven to be a valuable solution for removing PCBs from paint, caulking, and various insulation and filler materials in older buildings, naval ships, and former munitions facilities where the presence of PCBs interferes with methods for removing trace explosive materials. Miles of potentially toxic caulking join sections of runways at airports. Any of these materials installed before 1979 potentially contain PCBs, Quinn says. "This is not just a NASA problem," she says. "It s a global problem."

  3. Sustainable Remediation for Enhanced NAPL Recovery from Groundwater

    Science.gov (United States)

    Javaher, M.

    2012-12-01

    Sustainable remediation relates to the achievement of balance between environmental, social, and economic elements throughout the remedial lifecycle. A significant contributor to this balance is the use of green and sustainable technologies which minimize environmental impacts, while maximizing social and economic benefits of remedial implementation. To this end, a patented mobile vapor energy generation (VEG) technology has been developed targeting variable applications, including onsite soil remediation for unrestricted reuse and enhanced non-aqueous phase liquid (NAPL) recover at the water table. At the core of the mobile VEG technology is a compact, high efficiency vapor generator, which utilizes recycled water and propane within an entirely enclosed system to generate steam as high as 1100°F. Operating within a fully enclosed system and capturing all heat that is generated within this portable system, the VEG technology eliminates all emissions to the atmosphere and yields an undetected carbon footprint with resulting carbon dioxide concentrations that are below ambient levels. Introduction of the steam to the subsurface via existing wells results in a desired change in the NAPL viscosity and the interfacial tension at the soil, water, NAPL interface; in turn, this results in mobilization and capture of the otherwise trapped, weathered NAPL. Approved by the California Air Resources Control Board (and underlying Air Quality Management Districts) and applied in California's San Joaquin Valley, in-well heating of NAPLs trapped at the water table using the VEG technology has proven as effective as electrical resistivity heating (ERH) in changing the viscosity of and mobilizing NAPLs in groundwater in support of recovery, but has achieved these results while minimizing the remedial carbon footprint by 90%, reducing energy use by 99%, and reducing remedial costs by more than 95%. NAPL recovery using VEG has also allowed for completion of source removal historically

  4. Groundwater remediation optimization using artificial neural networks

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, L. L., LLNL

    1998-05-01

    One continuing point of research in optimizing groundwater quality management is reduction of computational burden which is particularly limiting in field-scale applications. Often evaluation of a single pumping strategy, i.e. one call to the groundwater flow and transport model (GFTM) may take several hours on a reasonably fast workstation. For computational flexibility and efficiency, optimal groundwater remediation design at Lawrence Livermore National Laboratory (LLNL) has relied on artificial neural networks (ANNS) trained to approximate the outcome of 2-D field-scale, finite difference/finite element GFTMs. The search itself has been directed primarily by the genetic algorithm (GA) or the simulated annealing (SA) algorithm. This approach has advantages of (1) up to a million fold increase in speed of remediation pattern assessment during the searches and sensitivity analyses for the 2-D LLNL work, (2) freedom from sequential runs of the GFTM (enables workstation farming), and (3) recycling of the knowledge base (i.e. runs of the GFTM necessary to train the ANNS). Reviewed here are the background and motivation for such work, recent applications, and continuing issues of research.

  5. [Simulation on remediation of benzene contaminated groundwater by air sparging].

    Science.gov (United States)

    Fan, Yan-Ling; Jiang, Lin; Zhang, Dan; Zhong, Mao-Sheng; Jia, Xiao-Yang

    2012-11-01

    Air sparging (AS) is one of the in situ remedial technologies which are used in groundwater remediation for pollutions with volatile organic compounds (VOCs). At present, the field design of air sparging system was mainly based on experience due to the lack of field data. In order to obtain rational design parameters, the TMVOC module in the Petrasim software package, combined with field test results on a coking plant in Beijing, is used to optimize the design parameters and simulate the remediation process. The pilot test showed that the optimal injection rate was 23.2 m3 x h(-1), while the optimal radius of influence (ROI) was 5 m. The simulation results revealed that the pressure response simulated by the model matched well with the field test results, which indicated a good representation of the simulation. The optimization results indicated that the optimal injection location was at the bottom of the aquifer. Furthermore, simulated at the optimized injection location, the optimal injection rate was 20 m3 x h(-1), which was in accordance with the field test result. Besides, 3 m was the optimal ROI, less than the field test results, and the main reason was that field test reflected the flow behavior at the upper space of groundwater and unsaturated area, in which the width of flow increased rapidly, and became bigger than the actual one. With the above optimized operation parameters, in addition to the hydro-geological parameters measured on site, the model simulation result revealed that 90 days were needed to remediate the benzene from 371 000 microg x L(-1) to 1 microg x L(-1) for the site, and that the opeation model in which the injection wells were progressively turned off once the groundwater around them was "clean" was better than the one in which all the wells were kept operating throughout the remediation process.

  6. Groundwater remediation from the past to the future: A bibliometric analysis.

    Science.gov (United States)

    Zhang, Shu; Mao, Guozhu; Crittenden, John; Liu, Xi; Du, Huibin

    2017-08-01

    Groundwater is an important component of terrestrial ecosystems and plays a role in geochemical cycling. Groundwater is also used for agricultural irrigation and for the domestic supply of drinking water in most nations. However, groundwater contamination has led to many research efforts on groundwater remediation technologies and strategies. This study evaluated a total of 5486 groundwater remediation-related publications from 1995 to 2015 using bibliometric technology and social network analysis, to provide a quantitative analysis and a global view on the current research trend and future research directions. Our results underline a strong research interest and an urgent need to remediate groundwater pollution due to the increasing number of both groundwater contamination and remediation publications. In the past two decades, the United States (U.S.) published 41.1% of the papers and it was the core country of the international collaboration network, cooperating with the other 19 most productive countries. Besides the active international collaboration, the funding agencies also played positive roles to foster the science and technology publications. With respect to the analysis of the distribution of funding agencies, the National Science Foundation of China sponsored most of the groundwater remediation research. We also identified the most productive journals, Environmental Science and Technology and Journal of Contaminant Hydrology, which published 334 and 259 scientific articles (including research articles and reviews) over the past 20 years, respectively. In addition to journal publications, a patent analysis was performed to show the impact of intellectual property protection on journal publications. Three major remediation technologies, including chemical oxidation, biodegradation and adsorption, have received increasing interest in both journal publication and patent development. Our results provide a valuable reference and global overview to identify

  7. In Situ Remediation Integrated Program: Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-01

    The In Situ Remediation Integrated Program (ISR IP) was instituted out of recognition that in situ remediation could fulfill three important criteria: significant cost reduction of cleanup by eliminating or minimizing excavation, transportation, and disposal of wastes; reduced health impacts on workers and the public by minimizing exposure to wastes during excavation and processing; and remediation of inaccessible sites, including: deep subsurfaces, in, under, and around buildings. Buried waste, contaminated soils and groundwater, and containerized wastes are all candidates for in situ remediation. Contaminants include radioactive wastes, volatile and non-volatile organics, heavy metals, nitrates, and explosive materials. The ISR IP intends to facilitate development of in situ remediation technologies for hazardous, radioactive, and mixed wastes in soils, groundwater, and storage tanks. Near-term focus is on containment of the wastes, with treatment receiving greater effort in future years. ISR IP is an applied research and development program broadly addressing known DOE environmental restoration needs. Analysis of a sample of 334 representative sites by the Office of Environmental Restoration has shown how many sites are amenable to in situ remediation: containment--243 sites; manipulation--244 sites; bioremediation--154 sites; and physical/chemical methods--236 sites. This needs assessment is focused on near-term restoration problems (FY93--FY99). Many other remediations will be required in the next century. The major focus of the ISR EP is on the long term development of permanent solutions to these problems. Current needs for interim actions to protect human health and the environment are also being addressed.

  8. Sulfate Reduction in Groundwater: Characterization and Applications for Remediation

    Energy Technology Data Exchange (ETDEWEB)

    Miao, Z.; Brusseau, M. L.; Carroll, Kenneth C.; Carreon-Diazconti, C.; Johnson, B.

    2012-06-01

    Sulfate is ubiquitous in groundwater, with both natural and anthropogenic sources. Sulfate reduction reactions play a significant role in mediating redox conditions and biogeochemical processes for subsurface systems. They also serve as the basis for innovative in-situ methods for groundwater remediation. An overview of sulfate reduction in subsurface environments is provided, with a specific focus on implications for groundwater remediation. A case study presenting the results of a pilot-scale ethanol injection test illustrates the advantages and difficulties associated with the use of electron-donor amendments for sulfate remediation.

  9. Summary of the NATO/CCMS Conference The Demonstration of Remedial Action Technologies for Contaminated Land and GroundWater

    Science.gov (United States)

    The problem of contamination to land and groundwa- ter from improper handling of hazardous materials/ waste is faced by all countries. Also, the need for reliable, cost-effective technologies to address this problem at contaminated sites exists throughout the world. Many countrie...

  10. Remediation of Groundwater Contaminated with Organics and Radionuclides - An Innovative Approach Eases Traditional Hurdles

    Energy Technology Data Exchange (ETDEWEB)

    Scott, J.; Case, N.; Coltman, K.

    2003-02-25

    Traditional approaches to the remediation of contaminated groundwater, such as pump-and-treat, have been used for many years for the treatment of groundwater contaminated with various organics. However the treatment of groundwater contaminated with organics and radionuclides has been considerably more challenging. Safety and Ecology Corporation (SEC) was recently faced with these challenges while designing a remediation system for the remediation of TCE-contaminated groundwater and soil at the RMI Extrusion Plant in Ashtabula, OH. Under contract with RMI Environmental Services (RMIES), SEC teamed with Regenesis, Inc. to design, implement, and execute a bioremediation system to remove TCE and associated organics from groundwater and soil that was also contaminated with uranium and technetium. The SEC-Regenesis system involved the injection of Hydrogen Release Compound (HRC), a natural attenuation accelerant that has been patented, designed, and produced by Regenesis, to stimulate the reductive dechlorination and remediation of chlorinated organics in subsurface environments. The compound was injected using direct-push Geoprobe rods over a specially designed grid system through the zone of contaminated groundwater. The innovative approach eliminated the need to extract contaminated groundwater and bypassed the restrictive limitations listed above. The system has been in operation for roughly six months and has begun to show considerable success at dechlorinating and remediating the TCE plume and in reducing the radionuclides into insoluble precipitants. The paper will provide an overview of the design, installation, and initial operation phase of the project, focusing on how traditional design challenges of remediating radiologically contaminated groundwater were overcome. The following topics will be specifically covered: a description of the mechanics of the HRC technology; an assessment of the applicability of the HRC technology to contaminated groundwater plumes

  11. Cost Effective, Ultra Sensitive Groundwater Monitoring for Site Remediation and Management: Standard Operating Procedures with QA/QC

    Science.gov (United States)

    2015-05-01

    GUIDANCE DOCUMENT Cost-Effective, Ultra-Sensitive Groundwater Monitoring for Site Remediation and Management: Standard Operating Procedures... Groundwater Monitoring for Site Remediation and Management 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Halden, R.U., Roll, I.B. 5d...DEPLOYMENT WORK As with any groundwater sampling method, the decision to apply the IS2 technology is based on the site characteristics and the type

  12. In-situ remediation system for groundwater and soils

    Science.gov (United States)

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1991-01-01

    The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  13. Application of natural resource valuation concepts for development of sustainable remediation plans for groundwater.

    Science.gov (United States)

    Connor, John A; Paquette, Shawn; McHugh, Thomas; Gie, Elaine; Hemingway, Mark; Bianchi, Gino

    2017-04-07

    This paper explores the application of natural resource assessment and valuation procedures as a tool for developing groundwater remediation strategies that achieve the objectives for health and environmental protection, in balance with considerations of economic viability and conservation of natural resources. The natural resource assessment process, as applied under U.S. and international guidelines, entails characterization of groundwater contamination in terms of the pre-existing beneficial services of the impacted resource, the loss of these services caused by the contamination, and the measures and associated costs necessary to restore or replace the lost services. Under many regulatory programs, groundwater remediation objectives assume that the impacted groundwater may be used as a primary source of drinking water in the future, even if not presently in use. In combination with a regulatory preference for removal or treatment technologies, this assumed exposure, while protective of human health, can drive the remedy selection process toward remedies that may not be protective of the groundwater resource itself or of the other natural resources (energy, materials, chemicals, etc.) that may be consumed in the remediation effort. To achieve the same health and environmental protection goals under a sustainable remediation framework, natural resource assessment methods can be applied to restore the lost services and preserve the intact services of the groundwater so as to protect both current and future users of that resource. In this paper, we provide practical guidelines for use of natural resource assessment procedures in the remedy selection process and present a case study demonstrating the use of these protocols for development of sustainable remediation strategies. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

  14. Scientific Opportunity to Reduce Risk in Groundwater and Soil Remediation

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, Eric M.; Freshley, Mark D.; Hubbard, Susan S.; Looney, Brian B.; Zachara, John M.; Liang, Liyuan; Lesmes, D.; Chamberlain, G. M.; Skubal, Karen L.; Adams, V.; Denham, Miles E.; Wellman, Dawn M.

    2009-08-25

    In this report, we start by examining previous efforts at linking science and DOE EM research with cleanup activities. Many of these efforts were initiated by creating science and technology roadmaps. A recurring feature of successfully implementing these roadmaps into EM applied research efforts and successful cleanup is the focus on integration. Such integration takes many forms, ranging from combining information generated by various scientific disciplines, to providing technical expertise to facilitate successful application of novel technology, to bringing the resources and creativity of many to address the common goal of moving EM cleanup forward. Successful projects identify and focus research efforts on addressing the problems and challenges that are causing “failure” in actual cleanup activities. In this way, basic and applied science resources are used strategically to address the particular unknowns that are barriers to cleanup. The brief descriptions of the Office of Science basic (Environmental Remediation Science Program [ERSP]) and EM’s applied (Groundwater and Soil Remediation Program) research programs in subsurface science provide context to the five “crosscutting” themes that have been developed in this strategic planning effort. To address these challenges and opportunities, a tiered systematic approach is proposed that leverages basic science investments with new applied research investments from the DOE Office of Engineering and Technology within the framework of the identified basic science and applied research crosscutting themes. These themes are evident in the initial portfolio of initiatives in the EM groundwater and soil cleanup multi-year program plan. As stated in a companion document for tank waste processing (Bredt et al. 2008), in addition to achieving its mission, DOE EM is experiencing a fundamental shift in philosophy from driving to closure to enabling the long-term needs of DOE and the nation.

  15. Nodal failure index approach to groundwater remediation design

    Science.gov (United States)

    Lee, J.; Reeves, H.W.; Dowding, C.H.

    2008-01-01

    Computer simulations often are used to design and to optimize groundwater remediation systems. We present a new computationally efficient approach that calculates the reliability of remedial design at every location in a model domain with a single simulation. The estimated reliability and other model information are used to select a best remedial option for given site conditions, conceptual model, and available data. To evaluate design performance, we introduce the nodal failure index (NFI) to determine the number of nodal locations at which the probability of success is below the design requirement. The strength of the NFI approach is that selected areas of interest can be specified for analysis and the best remedial design determined for this target region. An example application of the NFI approach using a hypothetical model shows how the spatial distribution of reliability can be used for a decision support system in groundwater remediation design. ?? 2008 ASCE.

  16. Laboratory Research into Permeable Reactive Barriers for Groundwater Remediation

    Institute of Scientific and Technical Information of China (English)

    Anthony Adzomani; Jun Dong; Yan Jin

    2003-01-01

    Permeable Reactive Barriers (PRB) is a new technology for groundwater pollution remediation. Contaminants are converted into harmless by products in situ as the polluted water passes through a reactive wall. Experimental results demonstrate how reactive media can be used to remove contaminants from polluted water by laying the reactive wall across the flow direction of the water. The most comprehensively studied and applied reactive barrier type uses granulated Zero Valent Iron (ZVI) particles. In this process elemental iron provides a reducing environment which makes reductive dechlorination of chlorinated organic compounds feasible or changes redox sensitive metals, so that they are immobilized by a precipitation reaction. A reactive wall column which is made up of ZVI, sand and zeolite has shown the highest contaminant removal capacity compared to the other two which have different components. The potentials of ZVI, zeolite and Powdered Activated Carbon (PAC) to remove contaminants are due to their different physico-chemical proper-ties which make them to "sorb"metal contaminants. The results of this experiment show that PRB technology is an efficient method for the treatment of leachate-contaminated groundwater.

  17. Advances in Groundwater Remediation: Achieving Effective In Situ Delivery of Chemical Oxidants and Amendments

    DEFF Research Database (Denmark)

    Siegrist, Robert L.; Crimi, Michelle; Broholm, Mette Martina

    2012-01-01

    Contamination of soil and groundwater by organic chemicals represents a major environmental problem in urban areas throughout the United States and other industrialized nations. In situ chemical oxidation (ISCO) has emerged as one of several viable methods for remediation of organically contamina...... delivery of treatment fl uids, with an emphasis on chemical oxidants and amendments, which can help achieve cleanup goals and protect groundwater and associated drinking water resources.......Contamination of soil and groundwater by organic chemicals represents a major environmental problem in urban areas throughout the United States and other industrialized nations. In situ chemical oxidation (ISCO) has emerged as one of several viable methods for remediation of organically...... ) delivered into the subsurface using injection wells, probes, or other techniques. A continuing challenge for ISCO, as well as other in situ remediation technologies, is how to achieve in situ delivery and obtain simultaneous contact between treatment fl uids, such as oxidants and amendments, and the target...

  18. Carbon Nanotube Based Groundwater Remediation: The Case of Trichloroethylene

    OpenAIRE

    Kshitij C. Jha; Zhuonan Liu; Hema Vijwani; Mallikarjuna Nadagouda; Mukhopadhyay, Sharmila M.; Mesfin Tsige

    2016-01-01

    Adsorption of chlorinated organic contaminants (COCs) on carbon nanotubes (CNTs) has been gaining ground as a remedial platform for groundwater treatment. Applications depend on our mechanistic understanding of COC adsorption on CNTs. This paper lays out the nature of competing interactions at play in hybrid, membrane, and pure CNT based systems and presents results with the perspective of existing gaps in design strategies. First, current remediation approaches to trichloroethylene (TCE), th...

  19. Remediation of groundwater contaminated with DNAPLs by biodegradable oil emulsion.

    Science.gov (United States)

    Lee, Young-Chul; Kwon, Tae-Soon; Yang, Jung-Seok; Yang, Ji-Won

    2007-02-01

    Emulsion-based remediation with biodegradable vegetable oils was investigated as an alternative technology for the treatment of subsurface DNAPLs (dense non-aqueous phase liquids) such as TCE (trichloroethylene) and PCE (perchloroethylene). Corn and olive oil emulsions obtained by homogenization at 8000rpm for 15min were used. The emulsion droplets prepared with corn and olive oil gave a similar size distribution (1-10microm) and almost all of initially injected oil, >90%, remained in a dispersed state. In batch experiments, 2% (v/v) oil emulsion could adsorb up to 11,000ppm of TCE or 18,000ppm of PCE without creating a free phase. Results of one-dimensional column flushing studies indicated that contaminants with high aqueous solubility could be efficiently removed by flushing with vegetable oil emulsions. Removal efficiencies exceeded 98% for TCE and PCE with both corn and olive oil emulsions. The results of this study show that flushing with biodegradable oil emulsion can be used for the remediation of groundwater contaminated by DNAPLs.

  20. ELECTROCHEMICAL REMEDIATION TECHNOLOGIES (ECRTS) DEMONSTRATION BULLETIN

    Science.gov (United States)

    The ElectroChemical Remediation Technologies (ECRTs) process was developed by P2-Soil Remediation, Inc. P-2 Soil Remediation, Inc. formed a partnership with Weiss Associates and ElectroPetroleum, Inc. to apply the technology to contaminated sites. The ECRTs process was evaluated ...

  1. Historical hydronuclear testing: Characterization and remediation technologies

    Energy Technology Data Exchange (ETDEWEB)

    Shaulis, L.; Wilson, G.; Jacobson, R.

    1997-09-01

    This report examines the most current literature and information available on characterization and remediation technologies that could be used on the Nevada Test Site (NTS) historical hydronuclear test areas. Historical hydronuclear tests use high explosives and a small amount of plutonium. The explosion scatters plutonium within a contained subsurface environment. There is currently a need to characterize these test areas to determine the spatial extent of plutonium in the subsurface and whether geohydrologic processes are transporting the plutonium away from the event site. Three technologies were identified to assist in the characterization of the sites. These technologies are the Pipe Explorer{trademark}, cone penetrometer, and drilling. If the characterization results indicate that remediation is needed, three remediation technologies were identified that should be appropriate, namely: capping or sealing the surface, in situ grouting, and in situ vitrification. Capping the surface would prevent vertical infiltration of water into the soil column, but would not restrict lateral movement of vadose zone water. Both the in situ grouting and vitrification techniques would attempt to immobilize the radioactive contaminants to restrict or prevent leaching of the radioactive contaminants into the groundwater. In situ grouting uses penetrometers or boreholes to inject the soil below the contaminant zone with low permeability grout. In situ vitrification melts the soil containing contaminants into a solid block. This technique would provide a significantly longer contaminant immobilization, but some research and development would be required to re-engineer existing systems for use at deep soil depths. Currently, equipment can only handle shallow depth vitrification. After existing documentation on the historical hydronuclear tests have been reviewed and the sites have been visited, more specific recommendations will be made.

  2. Control of Groundwater Remediation Process as Distributed Parameter System

    Directory of Open Access Journals (Sweden)

    Mendel M.

    2014-12-01

    Full Text Available Pollution of groundwater requires the implementation of appropriate solutions which can be deployed for several years. The case of local groundwater contamination and its subsequent spread may result in contamination of drinking water sources or other disasters. This publication aims to design and demonstrate control of pumping wells for a model task of groundwater remediation. The task consists of appropriately spaced soil with input parameters, pumping wells and control system. Model of controlled system is made in the program MODFLOW using the finitedifference method as distributed parameter system. Control problem is solved by DPS Blockset for MATLAB & Simulink.

  3. Remediation alternatives for low-level herbicide contaminated groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Conger, R.M. [BASF Corp., Geismar, LA (United States)

    1995-10-01

    In early 1995, an evaluation of alternatives for remediation of a shallow groundwater plume containing low-levels of an organic herbicide was conducted at BASF Corporation, a petrochemical facility located in Ascension Parish, Louisiana. The contaminated site is located on an undeveloped portion of property within 1/4 mile of the east bank of the Mississippi River near the community of Geismar. Environmental assessment data indicated that about two acres of the thirty acre site had been contaminated from past waste management practices with the herbicide bentazon. Shallow soils and groundwater between 5 to 15 feet in depth were affected. Maximum concentrations of bentazon in groundwater were less than seven parts per million. To identify potentially feasible remediation alternatives, the environmental assessment data, available research, and cost effectiveness were reviewed. After consideration of a preliminary list of alternatives, only two potentially feasible alternatives could be identified. Groundwater pumping, the most commonly used remediation alternative, followed by carbon adsorption treatment was identified as was a new innovative alternative known as vegetative transpiration. This alternative relies on the natural transpiration processes of vegetation to bioremediate organic contaminants. Advantages identified during screening suggest that the transpiration method could be the best remediation alternative to address both economic and environmental factors. An experiment to test critical factors of the vegetatived transpiration alternative with bentazon was recommended before a final decision on feasibility can be made.

  4. Development of an Expanded, High Reliability Cost and Performance Database for In Situ Remediation Technologies

    Science.gov (United States)

    2016-03-01

    large investment in groundwater remediation technologies more effective, end-users need quantitative, accurate, and reliable performance and cost ... technologies . The overall objective of this work was to develop a comprehensive remediation performance and cost database. N/A U U U UU 42 Travis...end-users need quantitative, accurate, and reliable performance and cost data for commonly used remediation technologies . While the data from an

  5. Carbon Nanotube Based Groundwater Remediation: The Case of Trichloroethylene.

    Science.gov (United States)

    Jha, Kshitij C; Liu, Zhuonan; Vijwani, Hema; Nadagouda, Mallikarjuna; Mukhopadhyay, Sharmila M; Tsige, Mesfin

    2016-07-21

    Adsorption of chlorinated organic contaminants (COCs) on carbon nanotubes (CNTs) has been gaining ground as a remedial platform for groundwater treatment. Applications depend on our mechanistic understanding of COC adsorption on CNTs. This paper lays out the nature of competing interactions at play in hybrid, membrane, and pure CNT based systems and presents results with the perspective of existing gaps in design strategies. First, current remediation approaches to trichloroethylene (TCE), the most ubiquitous of the COCs, is presented along with examination of forces contributing to adsorption of analogous contaminants at the molecular level. Second, we present results on TCE adsorption and remediation on pure and hybrid CNT systems with a stress on the specific nature of substrate and molecular architecture that would contribute to competitive adsorption. The delineation of intermolecular interactions that contribute to efficient remediation is needed for custom, scalable field design of purification systems for a wide range of contaminants.

  6. Carbon Nanotube Based Groundwater Remediation: The Case of Trichloroethylene

    Directory of Open Access Journals (Sweden)

    Kshitij C. Jha

    2016-07-01

    Full Text Available Adsorption of chlorinated organic contaminants (COCs on carbon nanotubes (CNTs has been gaining ground as a remedial platform for groundwater treatment. Applications depend on our mechanistic understanding of COC adsorption on CNTs. This paper lays out the nature of competing interactions at play in hybrid, membrane, and pure CNT based systems and presents results with the perspective of existing gaps in design strategies. First, current remediation approaches to trichloroethylene (TCE, the most ubiquitous of the COCs, is presented along with examination of forces contributing to adsorption of analogous contaminants at the molecular level. Second, we present results on TCE adsorption and remediation on pure and hybrid CNT systems with a stress on the specific nature of substrate and molecular architecture that would contribute to competitive adsorption. The delineation of intermolecular interactions that contribute to efficient remediation is needed for custom, scalable field design of purification systems for a wide range of contaminants.

  7. Effect of heterogeneity on enhanced reductive dechlorination: Analysis of remediation efficiency and groundwater acidification

    Science.gov (United States)

    Brovelli, A.; Lacroix, E.; Robinson, C. E.; Gerhard, J.; Holliger, C.; Barry, D. A.

    2011-12-01

    Enhanced reductive dehalogenation is an attractive in situ treatment technology for chlorinated contaminants. The process includes two acid-forming microbial reactions: fermentation of an organic substrate resulting in short-chain fatty acids, and dehalogenation resulting in hydrochloric acid. The accumulation of acids and the resulting drop of groundwater pH are controlled by the mass and distribution of chlorinated solvents in the source zone, type of electron donor, alternative terminal electron acceptors available and presence of soil mineral phases able to buffer the pH (such as carbonates). Groundwater acidification may reduce or halt microbial activity, and thus dehalogenation, significantly increasing the time and costs required to remediate the aquifer. In previous work a detailed geochemical and groundwater flow simulator able to model the fermentation-dechlorination reactions and associated pH change was developed. The model accounts for the main processes influencing microbial activity and groundwater pH, including the groundwater composition, the electron donor used and soil mineral phase interactions. In this study, the model was applied to investigate how spatial variability occurring at the field scale affects dechlorination rates, groundwater pH and ultimately the remediation efficiency. Numerical simulations were conducted to examine the influence of heterogeneous hydraulic conductivity on the distribution of the injected, fermentable substrate and on the accumulation/dilution of the acidic products of reductive dehalogenation. The influence of the geometry of the DNAPL source zone was studied, as well as the spatial distribution of soil minerals. The results of this study showed that the heterogeneous distribution of the soil properties have a potentially large effect on the remediation efficiency. For examples, zones of high hydraulic conductivity can prevent the accumulation of acids and alleviate the problem of groundwater acidification. The

  8. Groundwater Remediation in a Floodplain Aquifer at Shiprock, New Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Dave [Navarro Research and Engineering; Miller, David [Navarro Research and Engineering; Kautsky, Mark [U. S. Department of Energy, Office of Legacy Management; Dander, David [Navarro Research and Engineering; Nofchissey, Joni [Navajo Nation Division of Natural Resources

    2016-03-06

    A uranium- and vanadium-ore-processing mill operated from 1954 to 1968 within the Navajo Nation near Shiprock, New Mexico. By September 1986, all tailings and structures on the former mill property were encapsulated in a disposal cell built on top of two existing tailings piles on the Shiprock site (the site) [1]. Local groundwater was contaminated by multiple inorganic constituents as a result of the milling operations. The U.S. Department of Energy (DOE) took over management of the site in 1978 as part of the Uranium Mill Tailings Remedial Action (UMTRA) Project. The DOE Office of Legacy Management currently manages ongoing activities at the former mill facility, including groundwater remediation. Remediation activities are designed primarily to reduce the concentrations and total plume mass of the mill-related contaminants sulfate, uranium, and nitrate. In addition to contaminating groundwater in alluvial and bedrock sediments directly below the mill site, ore processing led to contamination of a nearby floodplain bordering the San Juan River. Groundwater in a shallow alluvial aquifer beneath the floodplain is strongly influenced by the morphology of the river channel as well as changing flows in the river, which provides drainage for regional runoff from the San Juan Mountains of Colorado. As part of a recent study of the floodplain hydrology, a revised conceptual model was developed for the alluvial aquifer along with an updated status of contaminant plumes that have been impacted by more than 10 years of groundwater pumping for site remediation purposes. Several findings from the recent study will be discussed here.

  9. Arsenic in the groundwater: Occurrence, toxicological activities, and remedies.

    Science.gov (United States)

    Jha, S K; Mishra, V K; Damodaran, T; Sharma, D K; Kumar, Parveen

    2017-04-03

    Arsenic (As) contamination in groundwater has become a geo-environmental as well as a toxicological problem across the globe affecting more than 100-million people in nearly 21 countries with its associated disease "arsenicosis." Arsenic poisoning may lead to fatal skin and internal cancers. In present review, an attempt has been made to generate awareness among the readers about various sources of occurrence of arsenic, its geochemistry and speciation, mobilization, metabolism, genotoxicity, and toxicological exposure on humans. The article also emphasizes the possible remedies for combating the problem. The knowledge of these facts may help to work on some workable remedial measure.

  10. Fort Ord Groundwater Remediation Studies, 2002 - 2005

    Science.gov (United States)

    2006-08-01

    water Velocity at OU 1, Former Fort Ord, California. Su, G.W., B.M. Freifeld , C.M. Oldenburg, P.D. Jordan and P.F. Daley. 2005. Lawrence Berkeley...138. Oldenburg, C. M., P. F. Daley, B. M. Freifeld , J. Hinds, and P. D. Jordan, 2002. Three- Dimensional Groundwater Flow, Aquifer Response, and...U.S. Geological Survey Contract Number 1434-95-C-40232, 29 pp. Su, G.W., B.M. Freifeld , C.M. Oldenburg, P.D. Jordan, and P.F. Daley, 2005. Data

  11. Remediation of TCE-contaminated groundwater using nanocatalyst and bacteria.

    Science.gov (United States)

    Kang, Ser Ku; Seo, Hyunhee; Sun, Eunyoung; Kim, Inseon; Roh, Yul

    2011-08-01

    The objective of this study was to develop and evaluate the remediation of trichloroethene (TCE)-contaminated groundwater using both a nanocatalyst (bio-Zn-magnetite) and bacterium (similar to Clostridium quinii) in anoxic environments. Of the 7 nanocatalysts tested, bio-Zn-magnetite showed the highest TCE dechlorination efficiency, with an average of ca. 90% within 8 days in a batch experiment. The column tests confirmed that the application of bio-Zn-magnetite in combination with the bacterium achieved high degradation efficiency (ca. 90%) of TCE within 5 days compared to the nanocatalyst only, which degraded only 30% of the TCE. These results suggest that the application of a nanocatalyst and the bacterium have potential for the remediation of TCE-contaminated groundwater in subsurface environments.

  12. PRB技术处理垃圾渗滤液污染地下水的应用研究%Study on Application of PRB Technology in Situ Remediation of Groundwater Polluted by Landfill Leachate

    Institute of Scientific and Technical Information of China (English)

    张先斌; 施永生; 张磊

    2011-01-01

    With the continuous development of urbanization,generation of leachate from more and more domestic garbage led to groundwater pollution increasingly significant. Four kinds of permeable reactive barrier (PRB) were designed by using iron powder,modified coal cinder, bentonite, activated carbon,zeolite,quartz sand and their mixtures as reaction medium,for studying the feasibility and the efficiency of PRB technology in remediation of groundwater polluted by landfill leachate. The results indicated that the CODCr removal rate was 85. 7%~91. 9%,which showed that PRB technology was an efficient method for the treatment of groundwater polluted by landfill leachate,and yet was expected to be further explored.%随着城市化的不断发展,生活垃圾渗滤液污染地下水的问题越来越突出,污染地下水的修复研究迫在眉睫.以铁粉、改性煤渣、膨润土、活性炭、沸石、石英砂及其混合物为反应介质,设计了4种地下可渗透反应墙(PRB),对PRB技术处理垃圾渗滤液污染地下水的可行性和有效性进行了实验模拟研究.结果表明:CODCr的去除率为85.7%~91.9%,PRB技术处理垃圾渗滤液污染地下水有一定的可行性,但有待继续深入研究.

  13. Progress Toward Cleanup of Operable Unit 1 Groundwater at the US DOE Mound, Ohio, Site: Success of a Phase-Combined Remedy – 15310

    Energy Technology Data Exchange (ETDEWEB)

    Hooten, Gwendolyn [U.S. Department of Energy, Harrison, OH (United States). Office of Legacy Management; Cato, Rebecca [Stoller Newport News Nuclear Inc., Weldon Spring, MS (United States); Looney, Brian [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Huntsman, Brent [Terran Corporation, Beavercreek, OH (United States)

    2015-03-01

    Operable Unit 1 (OU-1) soil and groundwater have been affected by volatile organic compounds (VOC) Present groundwater remedy is collection, treatment, and disposal (pump and treat [P&T]) Several combinations of technologies were used to address soil and groundwater contamination Monitored natural attenuation (MNA) is a viable alternative Majority of source term has been excavated VOC concentrations in groundwater have decreased Attenuation mechanisms have been observed in the subsurface at OU-1

  14. Y-12 Plant Remedial Action technology logic diagram. Volume I: Technology evaluation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-09-01

    The Y-12 Plant Remedial Action Program addresses remediation of the contaminated groundwater, surface water and soil in the following areas located on the Oak Ridge Reservation: Chestnut Ridge, Bear Creek Valley, the Upper and Lower East Fork Popular Creek Watersheds, CAPCA 1, which includes several areas in which remediation has been completed, and CAPCA 2, which includes dense nonaqueous phase liquid wells and a storage facility. There are many facilities within these areas that are contaminated by uranium, mercury, organics, and other materials. This Technology Logic Diagram identifies possible remediation technologies that can be applied to the soil, water, and contaminants for characterization, treatment, and waste management technology options are supplemented by identification of possible robotics or automation technologies. These would facilitate the cleanup effort by improving safety, of remediation, improving the final remediation product, or decreasing the remediation cost. The Technology Logic Diagram was prepared by a diverse group of more than 35 scientists and engineers from across the Oak Ridge Reservation. Most are specialists in the areas of their contributions. 22 refs., 25 tabs.

  15. INDEPENDENT REVIEW OF THE X-701B GROUNDWATER REMEDY, PORTSMOUTH, OHIO: TECHNICAL EVALUATION AND RECOMMENDATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B.; Eddy-Dilek, C.; Costanza, J.; Rossabi, J.; Early, T.; Skubal, K.; Magnuson, C.

    2008-12-15

    The Department of Energy Portsmouth Paducah Project Office requested assistance from Department of Energy Office of Environmental Management (EM-22) to provide independent technical experts to evaluate past and ongoing remedial activities at the Portsmouth facility that were completed to address TCE contamination associated with the X-701B groundwater plume and to make recommendations for future efforts. The Independent Technical Review team was provided with a detailed and specific charter. The charter requested that the technical team first review the past and current activities completed for the X-701B groundwater remedy for trichloroethene (TCE) in accordance with a Decision Document that was issued by Ohio EPA on December 8, 2003 and a Work Plan that was approved by Ohio EPA on September 22, 2006. The remedy for X-701B divides the activities into four phases: Phase I - Initial Source Area Treatment, Phase II - Expanded Source Area Treatment, Phase III - Evaluation and Reporting, and Phase IV - Downgradient Remediation and Confirmation of Source Area Treatment. Phase I of the remedy was completed during FY2006, and DOE has now completed six oxidant injection events within Phase II. The Independent Technical Review team was asked to evaluate Phase II activities, including soil and groundwater results, and to determine whether or not the criteria that were defined in the Work Plan for the Phase II end point had been met. The following criteria are defined in the Work Plan as an acceptable Phase II end point: (1) Groundwater samples from the identified source area monitoring wells have concentrations below the Preliminary Remediation Goal (PRG) for TCE in groundwater, or (2) The remedy is no longer effective in removing TCE mass from the source area. In addition, the charter specifies that if the Review Team determines that the Phase II endpoint has not been reached, then the team should address the following issues: (1) If additional injection events are

  16. The Effect of Flow on Pollution and Remediation in Groundwater

    Institute of Scientific and Technical Information of China (English)

    Moiwo J. Paul

    2003-01-01

    Flow, solute transport and pollution remediation through attenuation in unconsolidated porous media were investigated in this study. The variables used in the investigation include soil texture, porosity, topography and hydraulic conductivity. The study revealed that hydraulic conductivity is highly dependent on soil texture, porosity and topography.Hydraulic conductivity was noted to have a controlling influence on groundwater flow and residence time, and the degree of natural attenuation in hydrogeologic systems. Contaminant transport simulated with the MODFLOW Model revealed dominance of advective transport of contaminants in unconsolidated porous media. However, attenuation through sorption (linear isotherm equilibrium controlled) and reaction (first-order irreversible decay) also retarded contaminant plume migration. Thus natural attenuation was found to be highly feasible in clay formations due to low hydraulic conductivity and long groundwater residence times. Though natural attenuation processes including dispersion, diffusion, dilution, mixing, volatilization and biodegradation were not investigated for in this paper, it is shown to be a sound remediation technique of contaminated ground water due to its capacity to destroy or transform contaminants or at least retard their flow.

  17. Sustainable in-well vapor stripping: A design, analytical model, and pilot study for groundwater remediation.

    Science.gov (United States)

    Sutton, Patrick T; Ginn, Timothy R

    2014-12-15

    A sustainable in-well vapor stripping system is designed as a cost-effective alternative for remediation of shallow chlorinated solvent groundwater plumes. A solar-powered air compressor is used to inject air bubbles into a monitoring well to strip volatile organic compounds from a liquid to vapor phase while simultaneously inducing groundwater circulation around the well screen. An analytical model of the remediation process is developed to estimate contaminant mass flow and removal rates. The model was calibrated based on a one-day pilot study conducted in an existing monitoring well at a former dry cleaning site. According to the model, induced groundwater circulation at the study site increased the contaminant mass flow rate into the well by approximately two orders of magnitude relative to ambient conditions. Modeled estimates for 5h of pulsed air injection per day at the pilot study site indicated that the average effluent concentrations of dissolved tetrachloroethylene and trichloroethylene can be reduced by over 90% relative to the ambient concentrations. The results indicate that the system could be used cost-effectively as either a single- or multi-well point technology to substantially reduce the mass of dissolved chlorinated solvents in groundwater. Copyright © 2014 Elsevier B.V. All rights reserved.

  18. Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

    Energy Technology Data Exchange (ETDEWEB)

    Dixon, Robert A.; Lance, P.E.; Downs, A.; Kier, Brian P. [EMCON Northwest Inc., Portland, OR (United States)

    1993-12-31

    Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

  19. A co-metabolic approach to groundwater remediation

    Energy Technology Data Exchange (ETDEWEB)

    Palumbo, A.V.; Boerman, P.A.; Strandberg, G.W.; Donaldson, T.L.; Jennings, H.L.; Lucero, A.J.; Herbes, S.E. (Oak Ridge National Lab., TN (United States)); Phelps, T.J.; White, D.C. (Tennessee Univ., Knoxville, TN (United States). Inst. for Applied Microbiology)

    1991-01-01

    In support of the US Department of Energy's (DOE) Integrated Demonstration (Cleanup of Organics in Soils and Groundwater at Non-arid Sites) at the Savannah River Site (SRS), Oak Ridge National Laboratory (ORNL) and the University of Tennessee (UT) are involved in demonstrations of the use of methanotrophs in bioreactors for remediation of contaminated groundwater. In preparation for a field demonstration at ORNL's K-25 Site in Oak Ridge, Tennessee, ORNL is conducting batch experiments, is operating a number of bench-scale bioreactors, has designed pretreatment systems, and has modified a field-scale bioreactor provided by the Air Force Engineering and Services Center for use at the site. UT is operating bench-scale bioreactors with the goal of determining the stability of a trichloroethylene-degrading methanotrophic consortia during shifts in operating conditions (e.g. pH, nutrient inputs, and contaminant mixtures). These activities are all aimed at providing the knowledge base necessary for successful treatment of contaminated groundwater at the SRS and K-25 sites as well as other DOE sites. 18 refs., 1 fig. , 1 tab.

  20. Environmental Remediation Technologies Derived from Space Industry Research

    Science.gov (United States)

    Quinn, Jacqueline; Sauser, Brian; Helminger, Andrew

    2004-01-01

    Beginning in the 1950s and 1960s, an abundance of effort and initiative was focused on propelling the space industry outward for planetary exploration and habitation. During these early years, the push to take space science to new levels indirectly contributed to the evolution of another science field that would not fully surface until the early 1980s, environmental remediation. This field is associated with the remediation or cleanup of environmental resources such as groundwater, soil, and sediment. Because the space-exploration initiative began prior to the establishment of the U.S. Environmental Protection Agency (EPA) in December of 1970, many NASA Centers as well as space-related support contractors allowed for the release of spent chemicals into the environment. Subsequently, these land owners have been directed by the EPA to responsibly initiate cleanup of their impacted sites. This paper will focus on the processes and lessons learned with the development, testing, and commercialization initiatives associated with four remediation technologies. The technologies include installation techniques for permeable reactive barriers (PRBs), the use of ultrasound to improve long-term performance of PRBs, emulsified zero-valent iron for product-level solvent degradation, and emulsion technologies for application to metal and polychlorinated biphenyl contaminated media. Details of the paper cover technology research, evaluation, and testing; contracts and grants; and technology transfer strategies including patenting, marketing, and licensing.

  1. REMEDIATION OF NITRATE-CONTAMINATED GROUNDWATER USING A BIOBARRIER

    Energy Technology Data Exchange (ETDEWEB)

    B. STRIETELMEIER; M. ESPINOSA

    2001-01-01

    A biobarrier system has been developed for use in remediating shallow alluvial groundwater. This barrier is made from highly porous materials that are relatively long-lasting, carbon-based (to supply a limiting nutrient in nitrate destruction, in most cases), extremely inexpensive, and easy to replace. In a series of laboratory studies, we have determined the effectiveness of this barrier at destroying nitrate and perchlorate in groundwater from Mortandad Canyon at Los Alamos National Laboratory (LANL). This groundwater was obtained from a monitoring well, MCO-5, which is located in the flowpath of the discharge waters from the LANL Radioactive Liquid Waste Treatment Facility (RLWTF). Water with elevated nitrate levels was discharged from this plant for many years. Recently, the nitrate levels have been brought under the discharge limits. However, the historical discharge has resulted in a nitrate plume in the alluvial groundwater in this canyon. The LANL Multi-Barrier project was initiated in 1999 to develop a system of barriers that would prevent the transport of radionuclides, metals, colloids and other contaminants, including nitrate and perchlorate, further down the canyon in order to protect populations down-gradient. The biobarrier will be part of this Multi-Barrier system. We have demonstrated the destruction of nitrate at levels up to 6.5-9.7 mM nitrate (400-600 mg/L), and that of perchlorate at levels of about 4.3 {micro}M perchlorate (350 ppb). We have quantified the populations of microorganisms present in the biofilm that develops on the biobarrier. The results of this research will be discussed along with other potential applications of this system.

  2. REMEDIATION OF NITRATE-CONTAMINATED GROUNDWATER USING A BIOBARRIER

    Energy Technology Data Exchange (ETDEWEB)

    B. STRIETELMEIR; ET AL

    2000-12-01

    A biobarrier system has been developed for use in remediating shallow alluvial groundwater. This barrier is made from highly porous materials that are relatively long-lasting, carbon-based (to supply a limiting nutrient in nitrate destruction, in most cases), and extremely inexpensive and easy to emplace. In a series of laboratory studies, we have determined the effectiveness of this barrier at destroying nitrate and perchlorate in groundwater from Mortandad Canyon at Los Alamos National Laboratory (LANL). This groundwater was obtained from a monitoring well, MCO-5, which is located in the flowpath of the discharge waters from the LANL Radioactive Liquid Waste Treatment Facility (RLWTF). Water with elevated nitrate levels has been discharged from this plant for many years, until recently when the nitrate levels have been brought under the discharge limits. However, the historical discharge has resulted in a nitrate plume in the alluvial groundwater in this canyon. The LANL Multi-Barrier project was initiated this past year to develop a system of barriers that would prevent the transport of radionuclides, metals, colloids and other contaminants, including nitrate and perchlorate, further down the canyon in order to protect populations down-gradient. The biobarrier. will be part of this Multi-Barrier system. We have demonstrated the destruction of nitrate at levels up to 6.5-9.7 mhl nitrate (400-600 mg/L), and that of perchlorate at levels of about 4.3 {micro}M perchlorate (350 ppb). We have quantified the populations of microorganisms present in the biofilm that develops on the biobarrier. The results of this research will be discussed along with other potential applications of this system.

  3. Electrical imaging of subsurface nanoparticle propagation for in-situ groundwater remediation

    Science.gov (United States)

    Flores Orozco, Adrián; Gallistl, Jakob; Schmid, Doris; Micic Batka, Vesna; Bücker, Matthias; Hofmann, Thilo

    2017-04-01

    Application of nanoparticles has emerged as a promising in situ remediation technology for the remediation of contaminated groundwater, particularly for areas difficult to access by other remediation techniques. The performance of nanoparticle injections, as a foremost step within this technology, is usually assessed through the geochemical analysis of soil and groundwater samples. This approach is not well suited for a real-time monitoring, and often suffers from a poor spatio-temporal resolution and only provides information from areas close to the sampling points. To overcome these limitations we propose the application of non-invasive Induced Polarization (IP) imaging, a geophysical method that provides information on the electrical properties of the subsurface. The analysis of temporal changes in the electrical images allows tracking the propagation of the injected nanoparticle suspension and detection of the induced bio-geochemical changes in the subsurface. Here, we present IP monitoring results for data collected during the injection of Nano-Goethite particles (NGP) used for simulation of biodegradation of a BTEX plume (i.e., benzene, toluene, ethylbenzene, and xylene) at the Spolchemie II site, CZ. Frequency-domain IP measurements were collected parallel to the groundwater flow direction and centred on the NGP injection point. Pre-injection imaging results revealed high electrical conductivities (> 10 S/m) and negligible polarization effects in the BTEX-contaminated part of the saturated zone (below 5 m depth). The apparently contradictory observation - BTEX compounds are poor electrical conductors - can be explained by the release of carbonic acids (a metabolic by-product of the biodegradation of hydrocarbons), which leads to an increase of the electrical conductivity. Post-injection images revealed a significant decrease (> 50%) of the electrical conductivity, with even larger changes in the proximity of the injection points, most likely due to the

  4. ELECTROCHEMICAL REMEDIATION TECHNOLOGIES (ECRTS) - IN SITU REMEDIATION OF CONTAMINATED MARINE SEDIMENTS

    Science.gov (United States)

    This Innovative Technology Evaulation Report summarizes the results of the evaluation of the Electrochemical Remediation Technologies (ECRTs) process, developed by P2-Soil Remediation, Inc. (in partnership with Weiss Associates and Electro-Petroleum, Inc.). This evaluation was co...

  5. System description for DART (Decision Analysis for Remediation Technologies)

    Energy Technology Data Exchange (ETDEWEB)

    Nonte, J.; Bolander, T.; Nickelson, D.; Nielson, R.; Richardson, J.; Sebo, D.

    1997-09-01

    DART is a computer aided system populated with influence models to determine quantitative benefits derived by matching requirements and technologies. The DART database is populated with data from over 900 DOE sites from 10 Field Offices. These sites are either source terms, such as buried waste pits, or soil or groundwater contaminated plumes. The data, traceable to published documents, consists of site-specific data (contaminants, area, volume, depth, size, remedial action dates, site preferred remedial option), problems (e.g., offsite contaminant plume), and Site Technology Coordinating Group (STCG) need statements (also contained in the Ten-Year Plan). DART uses this data to calculate and derive site priorities, risk rankings, and site specific technology requirements. DART is also populated with over 900 industry and DOE SCFA technologies. Technology capabilities can be used to match technologies to waste sites based on the technology`s capability to meet site requirements and constraints. Queries may be used to access, sort, roll-up, and rank site data. Data roll-ups may be graphically displayed.

  6. Independent Technical Review of the X-740 Groundwater Remedy, Portsmouth, Ohio: Technical Evaluation and Recommendations

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B.; Rhia, B.; Jackson, D.; Eddy-Dilek, C.

    2010-04-30

    Two major remedial campaigns have been applied to a plume of trichloroethene (TCE) contaminated groundwater near the former X-740 facility at the Portsmouth Gaseous Diffusion Plant in Piketon Ohio. The two selected technologies, phytoremediation using a stand of hybrid poplar trees from 1999-2007 and in situ chemical oxidation using modified Fenton's Reagent from 2008-2009, have proven ineffective in achieving remedial action objectives (RAOs). The 'poor' performance of these technologies is a direct result of site specific conditions and the local contaminant hydrogeology. Key among these challenges is the highly heterogeneous subsurface geology with a thin contaminated aquifer zone (the Gallia) - the behavior of the contamination in the Gallia is currently dominated by slow release of TCE from the clay of the overlying Minford formation, from the sandstone of the underlying Berea formation, and from clayey layers within the Gallia itself. In response to the remediation challenges for the X-740 plume, the Portsmouth team (including the US Department of Energy (DOE), the site contractor (CDM), and the Ohio Environmental Protection Agency (OEPA)) is evaluating the feasibility of remediation at this site and identifying specific alternatives that are well matched to site conditions and that would maximize the potential for achieving RAOs. To support this evaluation, the DOE Office of Groundwater and Soil Remediation (EM-32) assembled a team of experts to serve as a resource and provide input and recommendations to Portsmouth. Despite the challenging site conditions and the failure of the previous two remediation campaigns to adequately move the site toward RAOs, the review team was unanimous in the conclusion that an effective combination of cost effective technologies can be identified. Further, the team expressed optimism that RAOs can be achieved if realistic timeframes are accepted by all parties. The initial efforts of the review team focused on

  7. A Fuzzy Simulation-Based Optimization Approach for Groundwater Remediation Design at Contaminated Aquifers

    Directory of Open Access Journals (Sweden)

    A. L. Yang

    2012-01-01

    Full Text Available A fuzzy simulation-based optimization approach (FSOA is developed for identifying optimal design of a benzene-contaminated groundwater remediation system under uncertainty. FSOA integrates remediation processes (i.e., biodegradation and pump-and-treat, fuzzy simulation, and fuzzy-mean-value-based optimization technique into a general management framework. This approach offers the advantages of (1 considering an integrated remediation alternative, (2 handling simulation and optimization problems under uncertainty, and (3 providing a direct linkage between remediation strategies and remediation performance through proxy models. The results demonstrate that optimal remediation alternatives can be obtained to mitigate benzene concentration to satisfy environmental standards with a minimum system cost.

  8. GROUNDWATER RADIOIODINE: PREVALENCE, BIOGEOCHEMISTRY, AND POTENTIAL REMEDIAL APPROACHES

    Energy Technology Data Exchange (ETDEWEB)

    Denham, M.; Kaplan, D.; Yeager, C.

    2009-09-23

    former Yucca Mountain disposal facilities. The objectives of this report are to: (1) compile the background information necessary to understand behavior of {sup 129}I in the environment, (2) discuss sustainable remediation approaches to {sup 129}I contaminated groundwater, and (3) identify areas of research that will facilitate remediation of {sup 129}I contaminated areas on DOE sites. Lines of scientific inquiry that would significantly advance the goals of basic and applied research programs for accelerating {sup 129}I environmental remediation and reducing uncertainty associated with disposal of {sup 129}I waste are: (1) Evaluation of amendments or other treatment systems that can sequester subsurface groundwater {sup 129}I. (2) Develop analytical techniques for measurement of total {sup 129}I that eliminate the necessity of collecting and shipping large samples of groundwater. (3) Develop and evaluate ways to manipulate areas with organic-rich soil, such as wetlands, to maximize {sup 129}I sorption, minimizing releases during anoxic conditions. (4) Develop analytical techniques that can identify the various {sup 129}I species in the subsurface aqueous and solid phases at ambient concentrations and under ambient conditions. (5) Identify the mechanisms and factors controlling iodine-natural organic matter interactions at appropriate environmental concentrations. (6) Understand the biological processes that transform iodine species throughout different compartments of subsurface waste sites and the role that these processes have on {sup 129}I flux.

  9. Remediation technologies for oil-contaminated sediments.

    Science.gov (United States)

    Agarwal, Ashutosh; Liu, Yu

    2015-12-30

    Oil-contaminated sediments pose serious environmental hazards for both aquatic and terrestrial ecosystems. Innovative and environmentally compatible technologies are urgently required to remove oil-contaminated sediments. In this paper, various physical, chemical and biological technologies are investigated for the remediation of oil-contaminated sediments such as flotation and washing, coal agglomeration, thermal desorption, ultrasonic desorption, bioremediation, chemical oxidation and extraction using ionic liquids. The basic principles of these technologies as well as their advantages and disadvantages for practical application have been discussed. A combination of two or more technologies is expected to provide an innovative solution that is economical, eco-friendly and adaptable.

  10. 棕地地下水污染修复技术筛选方法研究——以某废弃化工厂污染场地为例%Screening process of brownfield site groundwater remedial technologies:a case study of an abandoned chemical factory contaminated site

    Institute of Scientific and Technical Information of China (English)

    李玮; 王明玉; 韩占涛; 张敏; 刘丽雅

    2016-01-01

    科学合理的地下水污染修复技术筛选方法对于有效修复受污染地下水体、节约修复工程成本、保护地下水资源、维护生态系统安全和人体健康具有重要意义.以某化工厂遗址早期排污渗坑为目标污染源,在结合水文地质勘查和地下水人体健康风险评价的基础上确定场地受污染地下水修复目标污染物,根据污染物迁移性、降解性、人体健康风险等指标及抽出处理、化学修复、生物修复、渗透反应格栅等地下水污染修复技术特点,使用偏好顺序结构评估法(PROMETHEE)进行修复技术筛选.结果显示,该场地地下水中主要污染物为1,2-二氯乙烷、1,4-二氯苯等有机污染物,其中1,2-二氯乙烷在呼吸吸入条件下的最大致癌风险达9.54×10-7.化学清除、监测自然衰减等四项技术适用于该场地地下水1,2-二氯乙烷修复,化学清除法综合排序分值最高,而在成本优先控制条件下,监测自然衰减技术更为适宜.研究对于我国场地地下水污染调查评估及修复工作具有积极的参考意义.%Scientific and reasonable screening method of groundwater pollution remediation technologies is of great importance to efficient remediate the polluted groundwater,saving remediation program cost and groundwater resource and ecology and human health protection.Considered as a target pollution source,hydrological survey combined with groundwater pollution human health risk were conducted in a discarded chemical factory site with a drain contamination pool,and PROMETHEE method was used to screen efficient technologies for local groundwater pollution remediation based on pollutants characteristics such as migration,degradation and human health risk,and technologies applicability analysis among pump & treat,chemical reduction,bioremediation and permeable reactive barriers,etc.Study results suggested that local groundwater was polluted by organic pollutants such as 1,2-DCA

  11. Stochastic goal programming based groundwater remediation management under human-health-risk uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    Li, Jing; He, Li, E-mail: li.he@ncepu.edu.cn; Lu, Hongwei; Fan, Xing

    2014-08-30

    Highlights: • We propose an integrated optimal groundwater remediation design approach. • The approach can address stochasticity in carcinogenic risks. • Goal programming is used to make the system approaching to ideal operation and remediation effects. • The uncertainty in slope factor is evaluated under different confidence levels. • Optimal strategies are obtained to support remediation design under uncertainty. - Abstract: An optimal design approach for groundwater remediation is developed through incorporating numerical simulation, health risk assessment, uncertainty analysis and nonlinear optimization within a general framework. Stochastic analysis and goal programming are introduced into the framework to handle uncertainties in real-world groundwater remediation systems. Carcinogenic risks associated with remediation actions are further evaluated at four confidence levels. The differences between ideal and predicted constraints are minimized by goal programming. The approach is then applied to a contaminated site in western Canada for creating a set of optimal remediation strategies. Results from the case study indicate that factors including environmental standards, health risks and technical requirements mutually affected and restricted themselves. Stochastic uncertainty existed in the entire process of remediation optimization, which should to be taken into consideration in groundwater remediation design.

  12. Treatability Study of In Situ Technologies for Remediation of Hexavalent Chromium in Groundwater at the Puchack Well Field Superfund Site, New Jersey

    Energy Technology Data Exchange (ETDEWEB)

    Vermeul, Vince R.; Szecsody, Jim E.; Truex, Michael J.; Burns, Carolyn A.; Girvin, Donald C.; Phillips, Jerry L.; Devary, Brooks J.; Fischer, Ashley E.; Li, Shu-Mei W.

    2006-11-13

    This treatability study was conducted by Pacific Northwest National Laboratory (PNNL), at the request of the U. S. Environmental Protection Agency (EPA) Region 2, to evaluate the feasibility of using in situ treatment technologies for chromate reduction and immobilization at the Puchack Well Field Superfund Site in Pennsauken Township, New Jersey. In addition to in situ reductive treatments, which included the evaluation of both abiotic and biotic reduction of Puchack aquifer sediments, natural attenuation mechanisms were evaluated (i.e., chromate adsorption and reduction). Chromate exhibited typical anionic adsorption behavior, with greater adsorption at lower pH, at lower chromate concentration, and at lower concentrations of other competing anions. In particular, sulfate (at 50 mg/L) suppressed chromate adsorption by up to 50%. Chromate adsorption was not influenced by inorganic colloids.

  13. Sustainability appraisal tools for soil and groundwater remediation: how is the choice of remediation alternative influenced by different sets of sustainability indicators and tool structures?

    Science.gov (United States)

    Beames, Alistair; Broekx, Steven; Lookman, Richard; Touchant, Kaat; Seuntjens, Piet

    2014-02-01

    The state-of-the-science in sustainability assessment of soil and groundwater remediation is evaluated with the application of four decision support systems (DSSs) to a large-scale brownfield revitalization case study. The DSSs were used to perform sustainability appraisals of four technically feasible remediation alternatives proposed for the site. The first stage of the review compares the scope of each tool's sustainability indicators, how these indicators are measured and how the tools differ in terms of standardization and weighting procedures. The second stage of the review compares the outputs from the tools and determines the key factors that result in differing results between tools. The evaluation of indicator sets and tool structures explains why the tools generate differing results. Not all crucial impact areas, as identified by sustainable remediation forums, are thoroughly considered by the tools, particularly with regard to the social and economic aspects of sustainability. Variations in boundary conditions defined between technologies, produce distorted environmental impact results, especially when in-situ and ex-situ technologies are compared. The review draws attention to the need for end users to be aware of which aspects of sustainability are considered, how the aspects are measured and how all aspects are ultimately balanced in the evaluation of potential remediation strategies. Existing tools can be improved by considering different technologies within the same boundary conditions and by expanding indicator sets to include indicators deemed to be relevant by remediation forums. © 2013.

  14. Use of LCA as decision support for the selection of remedial strategies for remediation of contaminated soil and groundwater

    DEFF Research Database (Denmark)

    Lemming, Gitte; Hauschild, Michael Zwicky; Bjerg, Poul Løgstrup

    little attention in established life cycle impact assessment methodologies. Often groundwater is included in a general freshwater compartment, is simply disregarded, or is only functioning as a sink for contaminant emissions. When applying LCA for decision support for contaminated site remediation...

  15. FY-95 technology catalog. Technology development for buried waste remediation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    The US Department of Energy`s (DOE) Buried Waste Integrated Demonstration (BWID) program, which is now part of the Landfill Stabilization Focus Area (LSFA), supports applied research, development, demonstration, and evaluation of a multitude of advanced technologies dealing with underground radioactive and hazardous waste remediation. These innovative technologies are being developed as part of integrated comprehensive remediation systems for the effective and efficient remediation of buried waste sites throughout the DOE complex. These efforts are identified and coordinated in support of Environmental Restoration (EM-40) and Waste Management (EM-30) needs and objectives. Sponsored by the DOE Office of Technology Development (EM-50), BWID and LSFA work with universities and private industry to develop technologies that are being transferred to the private sector for use nationally and internationally. This report contains the details of the purpose, logic, and methodology used to develop and demonstrate DOE buried waste remediation technologies. It also provides a catalog of technologies and capabilities with development status for potential users. Past FY-92 through FY-94 technology testing, field trials, and demonstrations are summarized. Continuing and new FY-95 technology demonstrations also are described.

  16. Bioremediation: a genuine technology to remediate radionuclides from the environment.

    Science.gov (United States)

    Prakash, Dhan; Gabani, Prashant; Chandel, Anuj K; Ronen, Zeev; Singh, Om V

    2013-07-01

    Radionuclides in the environment are a major human and environmental health concern. Like the Chernobyl disaster of 1986, the Fukushima Daiichi nuclear disaster in 2011 is once again causing damage to the environment: a large quantity of radioactive waste is being generated and dumped into the environment, and if the general population is exposed to it, may cause serious life-threatening disorders. Bioremediation has been viewed as the ecologically responsible alternative to environmentally destructive physical remediation. Microorganisms carry endogenous genetic, biochemical and physiological properties that make them ideal agents for pollutant remediation in soil and groundwater. Attempts have been made to develop native or genetically engineered (GE) microbes for the remediation of environmental contaminants including radionuclides. Microorganism-mediated bioremediation can affect the solubility, bioavailability and mobility of radionuclides. Therefore, we aim to unveil the microbial-mediated mechanisms for biotransformation of radionuclides under various environmental conditions as developing strategies for waste management of radionuclides. A discussion follows of '-omics'-integrated genomics and proteomics technologies, which can be used to trace the genes and proteins of interest in a given microorganism towards a cell-free bioremediation strategy. © 2013 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  17. Biogeochemical dynamics of pollutants in Insitu groundwater remediation systems

    Science.gov (United States)

    Kumar, N.; Millot, R.; Rose, J.; Négrel, P.; Battaglia-Brunnet, F.; Diels, L.

    2010-12-01

    Insitu (bio) remediation of groundwater contaminants has been area of potential research interest in last few decades as the nature of contaminant encountered has also changed drastically. This gives tough challenge to researchers in finding a common solution for all contaminants together in one plume. Redox processes play significant role in pollutant dynamics and mobility in such systems. Arsenic particularly in reduced environments can get transformed into its reduced form (As3+), which is apparently more mobile and highly toxic. Also parallel sulfate reduction can lead to sulfide production and formation of thioarsenic species. On the other hand heavy metals (Zn, Fe, and Cd) in similar conditions will favour more stable metal sulfide precipitation. In the present work, we tested Zero Valent Iron (ZVI) in handling such issues and found promising results. Although it has been well known for contaminants like arsenic and chlorinated compounds but not much explored for heavy metals. Its high available surface area supports precipitation and co -precipitation of contaminants and its highly oxidizing nature and water born hydrogen production helps in stimulation of microbial activities in sediment and groundwater. These sulfate and Iron reducing bacteria can further fix heavy metals as stable metal sulfides by using hydrogen as potential electron donor. In the present study flow through columns (biotic and control) were set up in laboratory to understand the behaviour of contaminants in subsurface environments, also the impact of microbiology on performance of ZVI was studied. These glass columns (30 x 4cm) with intermediate sampling points were monitored over constant temperature (20°C) and continuous groundwater (up)flow at ~1ml/hr throughout the experiment. Simulated groundwater was prepared in laboratory containing sulfate, metals (Zn,Cd) and arsenic (AsV). While chemical and microbial parameters were followed regularly over time, solid phase has been

  18. INDEPENDENT REVIEW OF THE X-701B GROUNDWATER REMEDY, PORTSMOUTH, OHIO: TECHNICAL EVALUATION AND RECOMMENDATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B.; Eddy-Dilek, C.; Costanza, J.; Rossabi, J.; Early, T.; Skubal, K.; Magnuson, C.

    2008-12-15

    The Department of Energy Portsmouth Paducah Project Office requested assistance from Department of Energy Office of Environmental Management (EM-22) to provide independent technical experts to evaluate past and ongoing remedial activities at the Portsmouth facility that were completed to address TCE contamination associated with the X-701B groundwater plume and to make recommendations for future efforts. The Independent Technical Review team was provided with a detailed and specific charter. The charter requested that the technical team first review the past and current activities completed for the X-701B groundwater remedy for trichloroethene (TCE) in accordance with a Decision Document that was issued by Ohio EPA on December 8, 2003 and a Work Plan that was approved by Ohio EPA on September 22, 2006. The remedy for X-701B divides the activities into four phases: Phase I - Initial Source Area Treatment, Phase II - Expanded Source Area Treatment, Phase III - Evaluation and Reporting, and Phase IV - Downgradient Remediation and Confirmation of Source Area Treatment. Phase I of the remedy was completed during FY2006, and DOE has now completed six oxidant injection events within Phase II. The Independent Technical Review team was asked to evaluate Phase II activities, including soil and groundwater results, and to determine whether or not the criteria that were defined in the Work Plan for the Phase II end point had been met. The following criteria are defined in the Work Plan as an acceptable Phase II end point: (1) Groundwater samples from the identified source area monitoring wells have concentrations below the Preliminary Remediation Goal (PRG) for TCE in groundwater, or (2) The remedy is no longer effective in removing TCE mass from the source area. In addition, the charter specifies that if the Review Team determines that the Phase II endpoint has not been reached, then the team should address the following issues: (1) If additional injection events are

  19. A Case Study of Using Zero-Valent Iron Nanoparticles for Groundwater Remediation

    Science.gov (United States)

    Xiong, Z.; Kaback, D.; Bennett, P. J.

    2011-12-01

    Zero-valent iron nanoparticle (nZVI) is a promising technology for rapid in situ remediation of numerous contaminants, including chlorinated solvents, in groundwater and soil. Because of the high specific surface area of nZVI particles, this technology achieves treatment rates that are significantly faster than micron-scale and granular ZVI. However, a key technical challenge facing this technology involves agglomeration of nZVI particles. To improve nZVI mobility/deliverability and reactivity, an innovative method was recently developed using a low-cost and bio-degradable organic polymer as a stabilizer. This nZVI stabilization strategy offers unique advantages including: (1) the organic polymer is cost-effective and "green" (completely bio-compatible), (2) the organic polymer is highly effective in stabilizing nZVI particles; and (3) the stabilizer is applied during particle preparation, making nZVI particles more stable. Through a funding from the U.S. Air Force Center for Engineering and the Environment (AFCEE), AMEC performed a field study to test the effectiveness of this innovative technology for degradation of chlorinated solvents in groundwater at a military site. Laboratory treatability tests were conducted using groundwater samples collected from the test site and results indicated that trichloroethene (main groundwater contaminant at the site) was completely degraded within four hours by nZVI particles. In March and May 2011, two rounds of nZVI injection were performed at the test site. Approximately 700 gallons of nZVI suspension with palladium as a catalyst were successfully prepared in the field and injected into the subsurface. Before injection, membrane filters with a pore size of 450 nm were used to check the nZVI particle size and it was observed that >85% of nZVI particles were passed through the filter based on total iron measurement, indicating particle size of nZVI particles were observed in a monitoring well located 5 feet downgradient from

  20. High Resolution Site Characterization as key element for proper design and cost estimation of groundwater remediation

    Directory of Open Access Journals (Sweden)

    Pieter Dijkshoorn

    2014-12-01

    Full Text Available Substantial amounts of money are spent each year on cleaning up ground water contaminations that were caused by historical industrial site activities. Too often, however, remedial objectives are not achieved within the anticipated time frame. Moreover, remedial budgets which were estimated prior to the start of remediation turn out to be largely insufficient to meet the remedial objectives. This situation, very common, creates significant troubles for all the stakeholders involved in the remediation project. The reason for not meeting remedial regulatory closure criteria or exceeding remedial budgets is often due to an incomplete conceptual site model. Having conducted high resolution site characterization programs at numerous sites where remediation was previously conducted, ERM has found several recurring themes: • Missed source areas and plumes; • Inadequate understanding of source area and plume architectures (i.e., three-dimensional contaminant distribution; • Inadequate understanding of the effects of site (hydrogeologic conditions on the ability to access contamination (i.e., via remedial additive injections of groundwater/soil gas extraction. This paper explains why remediations often fail and what the alternatives to prevent these failures (and exceeding remedial budgets are. More specifically, it focuses on alternative investigation methods and approaches that help to get to a more complete (high resolution conceptual site model. This more complete conceptual site model in return helps a more focused remedial design with a higher remedial efficiency. As a minimum, it will take away a lot of (financial uncertainty during the decision making when selecting a remedial alternative. Contaminants that have a greater density then water are known to have a greater complexity in terms of both investigation as well as remediation. Therefore, they will be the main focus of this paper.

  1. The Resilience of Groundwater Remediation System in Response to Changing Conditions

    Science.gov (United States)

    Hou, D.

    2016-12-01

    Anthropogenic activities have caused the contamination of groundwater resources at many locations. In an effort to protect human health and prevent further spreading of groundwater contamination, remediation systems have been or will be built at hundreds of thousands of sites. While the short term effectiveness has been the focus of past research and practice, the long-term effectiveness is increasingly scrutinized. When assessing the long-term effectiveness of groundwater remediation systems, it is important to examine how existing remediation systems respond to changing geophysical (e.g. climate change) and social (e.g. improved living standard and changing development needs) conditions. The resilience of remediation strategies, or their potential to adapt to future changes, is a critical sustainability consideration. We intend to examine the resilience of groundwater remediation systems in response to changing conditions. Among others, we explore the effects of sea level rise and changing hydroclimatic conditions on the life cycle impact of phytoremediation and bioremediation systems. The study was conducted in the San Francisco Bay area, where thousands of contaminated sites are located in an area that may be affected by sea level rise and changing hydroclimatic conditions.

  2. 铁矿物催化氧化技术在水处理中的应用%Use of catalytic oxidation technology of iron-oxide minerals in groundwater remediation

    Institute of Scientific and Technical Information of China (English)

    李婷婷; 刘贵权; 刘菲; 陈家玮

    2012-01-01

    The safe utilization of water resources is a problem of much concern because there are many organic pollutants in ground-water. Traditional water treatment process for the removal of persistent organic pollutants shows unsatisfing effect. In recent years, the use of natural iron-bearing minerals as catalysts is a promising technique for the remediation of ground water and industrial effluents. This review summarizes the recent application of iron-bearing minerals, clay-supported minerals and nano- scale minerals as active catalysts with hydrogen peroxide for ground-water remediation. The status of problems and development is also discussed in this paper. Studies have shown that these iron-bearing minerals used in pollutants removal are very attractive for their low cost, abundance, and environmental benign characteristics in the earth's crust; nevertheless, the influence of the natural organic matters, the uncertainties of the health impacts and the environmental fete of these particles deserve further investigation before their widespread application.%广泛存在于地下水中的各种有机污染物严重影响着水资源的安全利用,常见的水处理工艺对持久性有机污染物去除效果不够理想.近年来,天然含铁矿物作为催化剂,催化过氧化氢的化学治理方法对各种有机污染物去除效果显著.概述近年来主要含铁矿物、负载型矿物和纳米矿物材料催化过氧化氢在地下水有机污染去除中的应用,探讨了该领域的发展现状和存在问题,并对其应用前景进行展望.认为天然矿物材料具有成本低、在地壳中含量高、环境友好等特点,可用于多种有机污染物的去除与降解.但处理过程中,天然有机质的作用、纳米矿物材料的毒性和地球化学归宿问题应该做进一步研究.

  3. 地下水硝酸盐污染阻断与修复技术及装备研究年度进展报告%Annual Progress Report of Research on Control and Remediation Technology and Equipment of Groundwater Nitrate Pollution

    Institute of Scientific and Technical Information of China (English)

    姜永海

    2016-01-01

    产出方面,目前,课题组申请专利5项,获得授权专利两项,提出创新技术两项,投稿学术论文6篇,其中SCI论文3篇。%Currently, the progress of study goes well,the target is basic reasonable, the job of research is carried out smoothly according to the plan, parts of study have already developed in advance. Two typical demonstrate place were chosen, one is MSW landfill which is located in Shunyi County in Beijing, the other one is breeding base in Haiyan County in Zhejiang province. At the two research bases, information collecting,hydrogeological investigation,monitoring wells building, water quality monitoring, slug and infiltration testing, all of these already have been finished, and hydrogeological parameter have been achieved. These results can be used in the design of engineering demonstration. On the basis of a great deal of laboratory data, theoretical basis are built about the remediation technology of the pollution of nitrate in groundwater, which was based of the research background of engineering demonstration field. Three kinds of remediation materials developed, including activated carbon material, slow-releasing material of oxidation and biochemical integrated material. Two innovative scientific remediation technology are studied. One is unfilled PRB in situ remediation technology of groundwater pollution, which is proposed basing deeper groundwater pollution in in the north. The remediation technology has advantages of low investment, simple process flow and low cost. The multi semi-in situ remediation of groundwater system is a new groundwater remediation technology which is researched and developed through our research. The system integrated the Wetland treatment technology, Permeable reactive barriers technology and groundwater well irrigation technology as a whole. The advantages of this system are lower cost of construction and operation, easy construction, small disturbance to the groundwater environment

  4. New Pump and Treat Facility Remedial Action Work Plan for Test Area North (TAN) Final Groundwater Remediation, Operable Unit 1-07B

    Energy Technology Data Exchange (ETDEWEB)

    D. Vandel

    2003-09-01

    This remedial action work plan identifies the approach and requirements for implementing the medical zone remedial action for Test Area North, Operable Unit 1-07B, at the Idaho National Engineering and Environmental Laboratory (INEEL). This plan details management approach for the construction and operation of the New Pump and Treat Facility. As identified in the remedial design/remedial action scope of work, a separate remedial design/remedial action work plan will be prepared for each remedial component of the Operable Unit 1-07B remedial action. This work plan was originally prepared as an early implementation of the final Phase C remediation. At that time, The Phase C implementation strategy was to use this document as the overall Phase C Work Plan and was to be revised to include the remedial actions for the other remedial zones (hotspot and distal zones). After the completion of Record of Decision Amendment: Technical Support Facility Injection Well (TSF-05) and Surrounding Groundwater Contamination (TSF-23) and Miscellaneous No Action Sites, Final Remedial Action, it was determined that each remedial zone would have it own stand-alone remedial action work plan. Revision 1 of this document converts this document to a stand-alone remedial action plan specific to the implementation of the New Pump and Treat Facility used for plume remediation within the medical zone of the OU 1-07B contaminated plume.

  5. Deicing/Propylene Glycol (PG) Microbial Remediation Technology

    Science.gov (United States)

    2011-05-01

    Deicing /Propylene Glycol (PG) Microbial Remediation Technology Environment, Energy Security, & Sustainability (E2S2) Symposium & Exhibition Ernest N...DATES COVERED 00-00-2011 to 00-00-2011 4. TITLE AND SUBTITLE Deicing /Propylene Glycol (PG) Microbial Remediation Technology 5a. CONTRACT...Issues C. PG Remediation Project D. Summary E. Questions 2 3 Background • Aircraft deicing fluids (ADF) work planes fly in the winter o Military

  6. Viscosity-Modification to Improve Remediation Efficiencies within Heterogeneous Contaminated Groundwater Aquifers: Laboratory and Field-Scale Evaluation

    Science.gov (United States)

    Silva, J. A.; Crimi, M.

    2013-12-01

    A key challenge in in situ groundwater remediation practice is achieving efficient contact between the injected remedial fluid and the target contamination in the presence of subsurface permeability heterogeneities. Even apparently small permeability contrasts can affect the delivery and subsurface distribution of injected remedial fluids, as a result of preferential flows, and reduce treatment effectiveness as a result of bypassing of contaminated media of lower permeability. Viscosity-modification is a technique that can be used to mitigate the effects of permeability heterogeneity and improve the delivery and distribution of remediation fluids during subsurface injection. Viscosity-modification involves increasing the viscosity of the injected fluid, and modifying the fluids rheological character in some cases. The increased viscosity provides a reduced fluid mobility condition within higher permeability media that, in turn, enhances the penetration of fluids into adjacent lower permeability media, improving the overall sweep efficiency within heterogeneous geomedia. Herein, we present the results of laboratory (two-dimensional flow tank) and numerical experiments that were designed to critically evaluate the utility of viscosity-modification for groundwater remediation application. Specifically, we will address the benefits and limitations of the approach and highlight the effect of system variables on the degree sweep efficiency improvement achievable. We also present the results of a recently completed Environmental Security Technology Certification Program (ESTCP) technology validation project in which viscosity-modification was applied to permanganate in situ chemical oxidation. Site selection criteria, implementation design considerations, and the long-term effects of viscosity-modified fluid treatments will be discussed.

  7. Y-12 Plant remedial action Technology Logic Diagram: Volume 3, Technology evaluation data sheets: Part A, Remedial action

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-09-01

    The Y-12 Plant Remedial Action Technology Logic Diagram (TLD) was developed to provide a decision-support tool that relates environmental restoration (ER) problems at the Y-12 Plant to potential technologies that can remediate these problems. The TLD identifies the research, development, demonstration, testing, and evaluation needed for sufficient development of these technologies to allow for technology transfer and application to remedial action (RA) activities. The TLD consists of three volumes. Volume 1 contains an overview of the TLD, an explanation of the program-specific responsibilities, a review of identified technologies, and the rankings of remedial technologies. Volume 2 contains the logic linkages among environmental management goals, environmental problems and the various technologies that have the potential to solve these problems. Volume 3 contains the TLD data sheets. This report is Part A of Volume 3 and contains the Remedial Action section.

  8. Nitrate Remediation of Soil and Groundwater Using Phytoremediation: Transfer of Nitrogen Containing Compounds from the Subsurface to Surface Vegetation

    Science.gov (United States)

    Nelson, Sheldon

    2013-04-01

    Nitrate Remediation of Soil and Groundwater Using Phytoremediation: Transfer of Nitrogen Containing Compounds from the Subsurface to Surface Vegetation Sheldon Nelson Chevron Energy Technology Company 6001 Bollinger Canyon Road San Ramon, California 94583 snne@chevron.com The basic concept of using a plant-based remedial approach (phytoremediation) for nitrogen containing compounds is the incorporation and transformation of the inorganic nitrogen from the soil and/or groundwater (nitrate, ammonium) into plant biomass, thereby removing the constituent from the subsurface. There is a general preference in many plants for the ammonium nitrogen form during the early growth stage, with the uptake and accumulation of nitrate often increasing as the plant matures. The synthesis process refers to the variety of biochemical mechanisms that use ammonium or nitrate compounds to primarily form plant proteins, and to a lesser extent other nitrogen containing organic compounds. The shallow soil at the former warehouse facility test site is impacted primarily by elevated concentrations of nitrate, with a minimal presence of ammonium. Dissolved nitrate (NO3-) is the primary dissolved nitrogen compound in on-site groundwater, historically reaching concentrations of 1000 mg/L. The initial phases of the project consisted of the installation of approximately 1750 trees, planted in 10-foot centers in the areas impacted by nitrate and ammonia in the shallow soil and groundwater. As of the most recent groundwater analytical data, dissolved nitrate reductions of 40% to 96% have been observed in monitor wells located both within, and immediately downgradient of the planted area. In summary, an evaluation of time series groundwater analytical data from the initial planted groves suggests that the trees are an effective means of transfering nitrogen compounds from the subsurface to overlying vegetation. The mechanism of concentration reduction may be the uptake of residual nitrate from the

  9. Development of a Groundwater Transport Simulation Tool for Remedial Process Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Ivarson, Kristine A.; Hanson, James P.; Tonkin, M.; Miller, Charles W.; Baker, S.

    2015-01-14

    The groundwater remedy for hexavalent chromium at the Hanford Site includes operation of five large pump-and-treat systems along the Columbia River. The systems at the 100-HR-3 and 100-KR-4 groundwater operable units treat a total of about 9,840 liters per minute (2,600 gallons per minute) of groundwater to remove hexavalent chromium, and cover an area of nearly 26 square kilometers (10 square miles). The pump-and-treat systems result in large scale manipulation of groundwater flow direction, velocities, and most importantly, the contaminant plumes. Tracking of the plumes and predicting needed system modifications is part of the remedial process optimization, and is a continual process with the goal of reducing costs and shortening the timeframe to achieve the cleanup goals. While most of the initial system evaluations are conducted by assessing performance (e.g., reduction in contaminant concentration in groundwater and changes in inferred plume size), changes to the well field are often recommended. To determine the placement for new wells, well realignments, and modifications to pumping rates, it is important to be able to predict resultant plume changes. In smaller systems, it may be effective to make small scale changes periodically and adjust modifications based on groundwater monitoring results. Due to the expansive nature of the remediation systems at Hanford, however, additional tools were needed to predict the plume reactions to system changes. A computer simulation tool was developed to support pumping rate recommendations for optimization of large pump-and-treat groundwater remedy systems. This tool, called the Pumping Optimization Model, or POM, is based on a 1-layer derivation of a multi-layer contaminant transport model using MODFLOW and MT3D.

  10. Petroleum contaminated ground-water: Remediation using activated carbon.

    OpenAIRE

    2006-01-01

    Ground-water contamination resulting from the leakage of crude oil and refined petroleum products during extraction and processing operations is a serious and a growing environmental problem in Nigeria. Consequently, a study of the use of activated carbon (AC) in the clean up was undertaken with the aim of reducing the water contamination to a more acceptable level. In the experiments described, crude-oil contamination of ground water was simulated under laboratory conditions using ground-wat...

  11. Guidelines for active spreading during in situ chemical oxidation to remediate contaminated groundwater

    Science.gov (United States)

    The effectiveness of in situ chemical oxidation to remediate contaminated aquifers depends on the extent and duration of contact between the injected treatment chemical and the groundwater contaminant (the reactants). Techniques that inject and extract in the aquifer to ‘ac...

  12. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation

    NARCIS (Netherlands)

    De Biase, C.; Carminati, A.; Oswald, S.E.; Thullner, M.

    2013-01-01

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile l

  13. Grand challenge problems in environmental modeling and remediation: groundwater contaminant transport

    Energy Technology Data Exchange (ETDEWEB)

    Todd Arbogast; Steve Bryant; Clint N. Dawson; Mary F. Wheeler

    1998-08-31

    This report describes briefly the work of the Center for Subsurface Modeling (CSM) of the University of Texas at Austin (and Rice University prior to September 1995) on the Partnership in Computational Sciences Consortium (PICS) project entitled Grand Challenge Problems in Environmental Modeling and Remediation: Groundwater Contaminant Transport.

  14. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation

    NARCIS (Netherlands)

    De Biase, C.; Carminati, A.; Oswald, S.E.; Thullner, M.

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile

  15. New Pump and Treat Facility Remedial Action Work Plan for Test Area North (TAN) Final Groundwater Remediation, Operable Unit 1-07B

    Energy Technology Data Exchange (ETDEWEB)

    L. O. Nelson

    2003-09-01

    This operations and maintenance plan supports the New Pump and Treat Facility (NPTF) remedial action work plan and identifies the approach and requirements for the operations and maintenance activities specific to the final medical zone treatment remedy. The NPTF provides the treatment system necessary to remediate the medical zone portion of the OU 1-07B contaminated groundwater plume. Design and construction of the New Pump and Treat Facility is addressed in the NPTF remedial action work plan. The scope of this operation and maintenance plan includes facility operations and maintenance, remedy five-year reviews, and the final operations and maintenance report for the NPTF.

  16. In Situ Remediation Integrated Program: Evaluation and assessment of containment technology

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, M.A.; Fayer, M.J.

    1994-06-01

    Containment technology refers to a broad range of methods that are used to contain waste or contaminated groundwater and to keep uncontaminated water from entering a waste site. The U.S. Department of Energy`s (DOE) Office of Technology Development has instituted the In Situ Remediation Integrated Program (ISRIP) to advance the state-of-the-art of innovative technologies that contain or treat, in situ, contaminated media such as soil and groundwater, to the point of demonstration and to broaden the applicability of these technologies to the widely varying site remediation requirements throughout the DOE complex. The information provided here is an overview of the state-of-the-art of containment technology and includes a discussion of ongoing development projects; identifies the technical gaps; discusses the priorities for resolution of the technical gaps; and identifies the site parameters affecting the application of a specific containment method. The containment technology described in this document cover surface caps; vertical barriers such as slurry walls, grout curtains, sheet pilings, frozen soil barriers, and vitrified barriers; horizontal barriers; sorbent barriers; and gravel layers/curtains. Within DOE, containment technology could be used to prevent water infiltration into buried waste; to provide for long-term containment of pits, trenches, and buried waste sites; for the interim containment of leaking underground storage tanks and piping; for the removal of contaminants from groundwater to prevent contamination from migrating off-site; and as an interim measure to prevent the further migration of contamination during the application of an in situ treatment technology such as soil flushing. The ultimate goal is the implementation of containment technology at DOE sites as a cost-effective, efficient, and safe choice for environmental remediation and restoration activities.

  17. Feasibility of phyto remediation of common soil and groundwater pollutants

    DEFF Research Database (Denmark)

    Trapp, Stefan; Rein, Arno; Clausen, Lauge Peter Westergaard

    his report is the D eliverable D 4.3 and was done within the Timbre project WP4. It introduces into the various clean - up techniques that apply plants, evaluates the feasibility of phytoremediation of common soil and groundwater pollutants, and the knowle dge collected for this purpose was applied...

  18. USE OF A UNIQUE BIOBARRIER TO REMEDIATE NITRATE AND PERCHLORATE IN GROUNDWATER

    Energy Technology Data Exchange (ETDEWEB)

    Strietelmeier, E. A. (Elizabeth A.); Espinosa, Melissa L. (Melissa L.); Adams, J. D. (Joshua D. ); Leonard, P. A. (Patricia A.); Hodge, E. M. (Evangeline M.)

    2001-01-01

    Research was conducted to evaluate a multiple-layer system of volcanic rock, limestone, Apatite mineral and a 'biobarrier' to impede migration of radionuclides, metals and colloids through shallow alluvial groundwater, while simultaneously destroying contaminants such as nitrate and perchlorate. The 'bio' portion of this Multi-Barrier system uses highly porous, slowly degradable, carbon-based material (pecan shells) that serves as an energy source and supports the growth of indigenous microbial populations capable of destroying biodegradable compounds. The studies, using elevated nitrate concentrations in groundwater, have demonstrated reduction from levels of 6.5-9.7 mM nitrate (400-600 mg/L) to below discharge limits (0.16 mM nitrate). Perchlorate levels of 4.3 {micro}M (350 {micro}g/L) were also greatly reduced. Elevated levels of nitrate in drinking water are a public health concern, particularly for infants and adults susceptible to gastric cancer. Primary sources of contamination include feedlots, agriculture (fertilization), septic systems, mining and nuclear operations. A major source of perchlorate contamination in water is ammonium perchlorate from manufacture/use of rocket propellants. Perchlorate, recently identified as an EPA contaminant of concern, may affect thyroid function and cause tumor formation. A biobarrier used to support the growth of microbial populations (i.e. a biofilm) is a viable and inexpensive tool for cleaning contaminated groundwater. Aquatic ecosystems and human populations worldwide are affected by contaminated water supplies. One of the most frequent contaminants is nitrate. Remediation of nitrate in groundwater and drinking water by biodegradation is a natural solution to this problem. Microbial processes play an extremely important role in in situ groundwater treatment technologies. The assumption of carbon limitation is the basis for addition of carbon-based substrates to a system in the development of

  19. Optimizing the Environmental Performance of In Situ Thermal Remediation Technologies Using Life Cycle Assessment

    DEFF Research Database (Denmark)

    Lemming, Gitte; Nielsen, Steffen G.; Weber, Klaus

    2013-01-01

    to 75%. Moreover, a number of technology-specific improvements were identified, for instance by the substitution of stainless steel types in wells, heaters, and liners used in thermal conduction heating, thus reducing the nickel consumption by 45%. The combined effect of introducing all the suggested......In situ thermal remediation technologies provide efficient and reliable cleanup of contaminated soil and groundwater, but at a high cost of environmental impacts and resource depletion due to the large amounts of energy and materials consumed. This study provides a detailed investigation of four...... in situ thermal remediation technologies (steam enhanced extraction, thermal conduction heating, electrical resistance heating, and radio frequency heating) in order to (1) compare the life-cycle environmental impacts and resource consumption associated with each thermal technology, and (2) identify...

  20. Demonstration test and evaluation of ultraviolet/ultraviolet catalyzed peroxide oxidation for groundwater remediation at Oak Ridge K-25 Site

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-12-31

    In the UItraviolet/Ultraviolet Catalyzed Groundwater Remediation program, W.J. Schafer Associates, Inc. (WJSA) demonstrated, tested and evaluated a new ultraviolet (UV) lamp integrated with an existing commercial technology employing UV catalyzed peroxide oxidation to destroy organics in groundwater at an Oak Ridge K-25 site. The existing commercial technology is the perox-pure{trademark} process of Peroxidation Systems Incorporated (PSI) that employs standard UV lamp technology to catalyze H{sub 2}O{sub 2} into OH radicals, which attack many organic molecules. In comparison to classical technologies for remediation of groundwater contaminated with organics, the perox-pure{trademark} process not only is cost effective but also reduces contaminants to harmless by-products instead of transferring the contaminants from one medium to another (such as in activated carbon or air stripping). Although the perox-pure{trademark} process is cost effective against many organics, it is not effective for some organic contaminants of interest to DOE such as TCA, which has the highest concentration of the organics at the K-25 test site. Contaminants such as TCA are treated more readily by direct photolysis using short wavelength UV light. WJSA has been developing a unique UV lamp which is very efficient in the short UV wavelength region. Consequently, combining this UV lamp with the perox-pure{trademark} process results in a means for treating essentially all organic contaminants. In the program reported here, the new UV lamp lifetime was improved and the lamp integrated into a PSI demonstration trailer. Even though this UV lamp operated at less than optimum power and UV efficiency, the destruction rate for the TCA was more than double that of the commercial unit. An optimized UV lamp may double again the destruction rate; i.e., a factor of four greater than the commercial system.

  1. Optimal groundwater remediation using artificial neural networks and the genetic algorithm

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, Leah L. [Stanford Univ., CA (United States)

    1992-08-01

    An innovative computational approach for the optimization of groundwater remediation is presented which uses artificial neural networks (ANNs) and the genetic algorithm (GA). In this approach, the ANN is trained to predict an aspect of the outcome of a flow and transport simulation. Then the GA searches through realizations or patterns of pumping and uses the trained network to predict the outcome of the realizations. This approach has advantages of parallel processing of the groundwater simulations and the ability to ``recycle`` or reuse the base of knowledge formed by these simulations. These advantages offer reduction of computational burden of the groundwater simulations relative to a more conventional approach which uses nonlinear programming (NLP) with a quasi-newtonian search. Also the modular nature of this approach facilitates substitution of different groundwater simulation models.

  2. Optimal design of active spreading systems to remediate sorbing groundwater contaminants in situ

    Science.gov (United States)

    Piscopo, Amy N.; Neupauer, Roseanna M.; Kasprzyk, Joseph R.

    2016-07-01

    The effectiveness of in situ remediation to treat contaminated aquifers is limited by the degree of contact between the injected treatment chemical and the groundwater contaminant. In this study, candidate designs that actively spread the treatment chemical into the contaminant are generated using a multi-objective evolutionary algorithm. Design parameters pertaining to the amount of treatment chemical and the duration and rate of its injection are optimized according to objectives established for the remediation - maximizing contaminant degradation while minimizing energy and material requirements. Because groundwater contaminants have different reaction and sorption properties that influence their ability to be degraded with in situ remediation, optimization was conducted for six different combinations of reaction rate coefficients and sorption rates constants to represent remediation of the common groundwater contaminants, trichloroethene, tetrachloroethene, and toluene, using the treatment chemical, permanganate. Results indicate that active spreading for contaminants with low reaction rate coefficients should be conducted by using greater amounts of treatment chemical mass and longer injection durations relative to contaminants with high reaction rate coefficients. For contaminants with slow sorption or contaminants in heterogeneous aquifers, two different design strategies are acceptable - one that injects high concentrations of treatment chemical mass over a short duration or one that injects lower concentrations of treatment chemical mass over a long duration. Thus, decision-makers can select a strategy according to their preference for material or energy use. Finally, for scenarios with high ambient groundwater velocities, the injection rate used for active spreading should be high enough for the groundwater divide to encompass the entire contaminant plume.

  3. Innovative reactive barrier technologies for regional contaminated groundwater

    NARCIS (Netherlands)

    Merkel, P.; Weiβ, H.; Teutsch, G.; Rijnaarts, H.H.M.

    2000-01-01

    At many industrial sites inadequate waste disposal, leakages and war damages have led to severe groundwater contamination on a regional scale. Standard hydraulic groundwater remediation methods, such as pump-and-treat, in most cases do not lead to satisfactory results, due to the persistence of orga

  4. Innovative reactive barrier technologies for regional contaminated groundwater

    NARCIS (Netherlands)

    Merkel, P.; Weiβ, H.; Teutsch, G.; Rijnaarts, H.H.M.

    2000-01-01

    At many industrial sites inadequate waste disposal, leakages and war damages have led to severe groundwater contamination on a regional scale. Standard hydraulic groundwater remediation methods, such as pump-and-treat, in most cases do not lead to satisfactory results, due to the persistence of

  5. DEMONSTRATION OF ELECTROCHEMICAL REMEDIATION TECHNOLOGIES-INDUCED COMPLEXATION

    Energy Technology Data Exchange (ETDEWEB)

    Barry L. Burks

    2002-12-01

    The Project Team is submitting this Topical Report on the results of its bench-scale demonstration of ElectroChemical Remediation Technologies (ECRTs) and in particular the Induced Complexation (ECRTs-IC) process for remediation of mercury contaminated soils at DOE Complex sites. ECRTs is an innovative, in-situ, geophysically based soil remediation technology with over 50 successful commercial site applications involving remediation of over two million metric tons of contaminated soils. ECRTs-IC has been successfully used to remediate 220 cu m of mercury-contaminated sediments in the Union Canal, Scotland. In that operation, ECRTs-IC reduced sediment total mercury levels from an average of 243 mg/kg to 6 mg/kg in 26 days of operation. The clean up objective was to achieve an average total mercury level in the sediment of 20 mg/kg.

  6. Groundwater remediation and the cost effectiveness of phytoremediation.

    Science.gov (United States)

    Compernolle, T; Van Passel, S; Weyens, N; Vangronsveld, J; Lebbe, L; Thewys, T

    2012-10-01

    In 1999, phytoremediation was applied at the site of a Belgian car factory to contain two BTEX plumes. This case study evaluates the cost effectiveness of phytoremediation compared to other remediation options, applying a tailored approach for economic evaluation. Generally, when phytoremediation is addressed as being cost effective, the cost effectiveness is only determined on an average basis. This study however, demonstrates that an incremental analysis may provide a more nuanced conclusion. When the cost effectiveness is calculated on an average basis, in this particular case, the no containment strategy (natural attenuation) has the lowest cost per unit mass removed and hence, should be preferred. However, when the cost effectiveness is determined incrementally, no containment should only be preferred if the value of removing an extra gram of contaminant mass is lower than 320 euros. Otherwise, a permeable reactive barrier should be adopted. A similar analysis is provided for the effect determined on the basis of remediation time. Phytoremediation is preferred compared to 'no containment' if reaching the objective one year earlier is worth 7 000 euros.

  7. MULTI-OBJECTIVE OPTIMAL DESIGN OF GROUNDWATER REMEDIATION SYSTEMS: APPLICATION OF THE NICHED PARETO GENETIC ALGORITHM (NPGA). (R826614)

    Science.gov (United States)

    A multiobjective optimization algorithm is applied to a groundwater quality management problem involving remediation by pump-and-treat (PAT). The multiobjective optimization framework uses the niched Pareto genetic algorithm (NPGA) and is applied to simultaneously minimize the...

  8. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    Energy Technology Data Exchange (ETDEWEB)

    Borden, R.C.; Cherry, R.S.

    2000-09-30

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced {approximately}7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe{reg_sign} rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The

  9. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    Energy Technology Data Exchange (ETDEWEB)

    Borden, R. E.; Cherry, Robert Stephen

    2000-09-01

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced ~7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe® rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The system was tested in a

  10. Behavior of solid carbon sources for biological denitrification in groundwater remediation.

    Science.gov (United States)

    Zhang, Jianmei; Feng, Chuanping; Hong, Siqi; Hao, Huiling; Yang, Yingnan

    2012-01-01

    The present study was conducted to compare the behavior of wheat straw, sawdust and biodegradable plastic (BP) as potential carbon sources for denitrification in groundwater remediation. The results showed that a greater amount of nitrogen compounds were released from wheat straw and sawdust than from BP in leaching experiments. In batch experiments, BP showed higher nitrate removal efficiency and longer service life than wheat straw and sawdust, which illustrated that BP is the most appropriate carbon source for stimulation of denitrification activity. In column experiments, BP was able to support complete denitrification at influent nitrate concentrations of 50, 60, 70, 80, and 90 mg NO(3)(-)-N/L, showing corresponding denitrification rates of 0.12, 0.14, 0.17, 0.19, and 0.22 mg NO(3)(-)-N.L(-1).d(-1).g(-1), respectively. These findings indicate that BP is applicable for use as a carbon source for nitrate-polluted groundwater remediation.

  11. Applicability of petroleum horizontal drilling technology to hazardous waste site characterization and remediation

    Energy Technology Data Exchange (ETDEWEB)

    Goranson, C.

    1992-09-01

    Horizontal wells have the potential to become an important tool for use in characterization, remediation and monitoring operations at hazardous waste disposal, chemical manufacturing, refining and other sites where subsurface pollution may develop from operations or spills. Subsurface pollution of groundwater aquifers can occur at these sites by leakage of surface disposal ponds, surface storage tanks, underground storage tanks (UST), subsurface pipelines or leakage from surface operations. Characterization and remediation of aquifers at or near these sites requires drilling operations that are typically shallow, less than 500-feet in depth. Due to the shallow nature of polluted aquifers, waste site subsurface geologic formations frequently consist of unconsolidated materials. Fractured, jointed and/or layered high compressive strength formations or compacted caliche type formations can also be encountered. Some formations are unsaturated and have pore spaces that are only partially filled with water. Completely saturated underpressured aquifers may be encountered in areas where the static ground water levels are well below the ground surface. Each of these subsurface conditions can complicate the drilling and completion of wells needed for monitoring, characterization and remediation activities. This report describes some of the equipment that is available from petroleum drilling operations that has direct application to groundwater characterization and remediation activities. A brief discussion of petroleum directional and horizontal well drilling methodologies is given to allow the reader to gain an understanding of the equipment needed to drill and complete horizontal wells. Equipment used in river crossing drilling technology is also discussed. The final portion of this report is a description of the drilling equipment available and how it can be applied to groundwater characterization and remediation activities.

  12. Groundwater Remediation and Alternate Energy at White Sands Test Facility

    Science.gov (United States)

    Fischer, Holger

    2008-01-01

    White Sands Test Facility Core Capabilities: a) Remote Hazardous Testing of Reactive, Explosive, and Toxic Materials and Fluids; b) Hypergolic Fluids Materials and Systems Testing; c) Oxygen Materials and System Testing; d) Hypervelocity Impact Testing; e)Flight Hardware Processing; and e) Propulsion Testing. There is no impact to any drinking water well. Includes public wells and the NASA supply well. There is no public exposure. Groundwater is several hundred feet below ground. No air or surface water exposure. Plume is moving very slowly to the west. Plume Front Treatment system will stop this westward movement. NASA performs on-going monitoring. More than 200 wells and zones are routinely sampled. Approx. 850 samples are obtained monthly and analyzed for over 300 different hazardous chemicals.

  13. Determination of ecologically vital groundwaters at selected sites in the Formerly Utilized Sites Remedial Action Program

    Energy Technology Data Exchange (ETDEWEB)

    Vinikour, W.S.; Yin, S.C.L.

    1989-08-01

    The US Department of Energy is classifying groundwaters at sites in its Formerly Utilized Sites Remedial Action Program (FUSRAP). Of particular concern is the potential presence of groundwaters that are highly vulnerable to contamination and that are either (1) irreplaceable sources of drinking water or (2) ecologically vital. Conditions at nine FUSRAP sites were evaluated to determine if ecologically vital groundwaters are present. The sites evaluated were Wayne Interim Storage Site, Maywood Interim Storage Site, and Middlesex Sampling Plant in New Jersey; Ashland 2 Site, Seaway Industrial Park, Colonie Interim storage Site, and Niagara Falls Storage Site in New York; and the St. Louis Airport Site and Hazelwood Interim Storage Site in Missouri. The analyses indicated that groundwaters are vulnerable to contamination at all but two of the sites -- the Ashland 2 and Seaway Industrial Park sites in New York. Groundwater discharge points were identified within a 2-mile radius (i.e., the classification review area) of all of the sites. No ecologically vital groundwater areas exist in the vicinities of any of the nine FUSRAP sites evaluated. 35 refs., 17 figs.

  14. A calcite permeable reactive barrier for the remediation of Fluoride from spent potliner (SPL) contaminated groundwater

    DEFF Research Database (Denmark)

    Turner, B.D.; Binning, Philip John; Sloan, S.W.

    2008-01-01

    The use of calcite (CaCO3) as a substrate for a permeable reactive barrier (PRB) for removing fluoride from contaminated groundwater is proposed and is illustrated by application to groundwater contaminated by spent potliner leachate (SPL), a waste derived from the aluminium smelting process....... The paper focuses on two issues in the implementation of calcite permeable reactive barriers for remediating fluoride contaminated water: the impact of the groundwater chemical matrix and CO2 addition on fluoride removal. Column tests comparing pure NaF solutions, synthetic SPL solutions, and actual SPL...... leachate indicate that the complex chemical matrix of the SPL leachate can impact fluoride removal significantly. For SPL contaminant mixtures, fluoride removal is initially less than expected from idealized, pure, solutions. However, with time, the effect of other contaminants on fluoride removal...

  15. Broom fibre PRB for heavy metals groundwater remediation

    Science.gov (United States)

    Molinari, A.; Troisi, S.; Fallico, C.; Paparella, A.; Straface, S.

    2009-04-01

    Soil contamination by heavy metal and, though it, of groundwater represent a serious alteration of original geochemical levels owing to various human activities as: particular industrial processes and their non-correct treatment emission, urban traffic, use of phytosanitary product and mineral fertilizer. Heavy metals are genotoxic contaminants who can be found by environmental matrix analysis or by examination of the genetic damage inducted, after exposition, to sentry organism. In this last case we use a relative quantitation of the gene expression monitoring the mitochondrial oxidative metabolism hepatopancreas's gene of the organism used by bioindicator. This test is based on consideration that the hepatopancreas is the first internal organ affected by heavy metals or any other pollutant that the organism is exposed. In this work, the organism used by bioindicator to evalutate the pollutant contamination of waste water is Danio rerio (Zebrafish) that is a little tropical fish of 2-3 cm, native on asiatic south-east rivers. This organism has a large use in scientific field because its genoma is almost completely mapped and, above all, because the congenital gene cause in human, if it was mutated in zebrafish, similar damage or almost similar mutation that happens in human being so you can develop a dose - response curve. To do this, after prepared a cadmium solution with a concentration 10 times the Italian normative limit, the organisms have been put in the aquarium to recreate the optimal condition to survival of zebrafish observed by continuous monitoring by web-cam. After one month exposition, that we took little by little sample fish to analyzing, for different exposition time, the hepatopancreas's fish. First results shows considerable variation of the gene expression by interested gene in mitochondrial oxidative metabolism compared to control, highlighting the mutagenity caused by heavy metals on Danio rerio's hepatopancreas and, mutatis mutandis, also in

  16. Factors Governing the Performance of Bauxite for Fluoride Remediation of Groundwater.

    Science.gov (United States)

    Cherukumilli, Katya; Delaire, Caroline; Amrose, Susan; Gadgil, Ashok J

    2017-02-21

    Globally, 200 million people drink groundwater contaminated with fluoride concentrations exceeding the World Health Organization's recommended level (WHO-MCL = 1.5 mg F(-)/L). This study investigates the use of minimally processed (dried/milled) bauxite ore as an inexpensive adsorbent for remediating fluoride-contaminated groundwater in resource-constrained areas. Adsorption experiments in synthetic groundwater using bauxites from Guinea, Ghana, U.S., and India as single-use batch dispersive media demonstrated that doses of ∼10-23 g/L could effectively remediate 10 mg F(-)/L. To elucidate factors governing fluoride removal, bauxites were characterized using X-ray fluorescence, X-ray diffraction, gas-sorption analysis, and adsorption isotherms/envelopes. All ores contained gibbsite, had comparable surface areas (∼14-17 m(2)/g), had similar intrinsic affinities and capacities for fluoride, and did not leach harmful ions into product water. Fluoride uptake on bauxite -primarily through ion-exchange- was strongly pH-dependent, with highest removal occurring at pH 5.0-6.0. Dissolution of CaCO3, present in trace amounts in India bauxite, significantly hindered fluoride removal by increasing solution pH. We also showed that fluoride remediation with the best-performing Guinea bauxite was ∼23-33 times less expensive than with activated alumina. Overall, our results suggest that bauxite could be an affordable fluoride-remediation adsorbent with the potential to improve access to drinking water for millions living in developing countries.

  17. 三氯乙烯和四氯乙烯在土壤和地下水中的污染及修复技术%Contaminations and Remediation Technologies of Trichloroethylene and Perchloroethylene in the Soil and Groundwater: A Review

    Institute of Scientific and Technical Information of China (English)

    张凤君; 王斯佳; 马慧; 吕聪; 王禹博

    2012-01-01

    三氯乙烯和四氯乙烯在工农业生产中被广泛使用,由于其不合理的处置和相对持久性特征,使其成为地下水和土壤中分布最为广泛的污染物之一.因其具有挥发性、毒性和致癌性,受到了国内外的广泛关注.通过查阅国内外资料,本文较为系统地总结了三氯乙烯和四氯乙烯污染的来源、危害和污染现状,述评了修复三氯乙烯和四氯乙烯污染的物理方法、化学方法和生物方法,其中物理方法包括曝气法和活性炭吸附法等,化学方法包括化学氧化法和化学还原法等,生物方法包括微生物修复技术和檀物修复技术.同时对三氯乙烯和四氯乙烯的污染修复技术的发展趋势进行了展望,认为微生物修复技术、纳米双金属颗粒技术和光催化氧化技术具有很好的应用前景,建议加强这三项技术的研究和应用.%Due to their widespread use, unreasonable disposal, and their persistency in the subsurface environment, chlorinated ethenes have become one of the most commonly contaminants in groundwater and soils,. Since they are volatile, toxic, and carcinogenic, they have been widely concerned. Based on the literature review, the sources, hazards, and pollution of chlorinated ethenes are summarized. Furthermore, the remediation technologies of chlorinated ethenes, such as physical, biological, and chemical methods are concluded. Physical methods include aeration and activated carbon adsorption, chemical methods include chemical oxidation and chemical reduction, and biological methods include bioremediation and phytoremediation. Moreover, the development trends of TCE and PCE remediation technologies are looked ahead, and the microbial remediation, nano-metal particles, and photocatalytic oxidation technology are appreciated, and it is recommended that researches and applications of these three areas should be strengthened.

  18. Combined nano-biotechnology for in-situ remediation of mixed contamination of groundwater by hexavalent chromium and chlorinated solvents.

    Science.gov (United States)

    Němeček, Jan; Pokorný, Petr; Lhotský, Ondřej; Knytl, Vladislav; Najmanová, Petra; Steinová, Jana; Černík, Miroslav; Filipová, Alena; Filip, Jan; Cajthaml, Tomáš

    2016-09-01

    The present report describes a 13month pilot remediation study that consists of a combination of Cr(VI) (4.4 to 57mg/l) geofixation and dechlorination of chlorinated ethenes (400 to 6526μg/l), achieved by the sequential use of nanoscale zerovalent iron (nZVI) particles and in situ biotic reduction supported by whey injection. The remediation process was monitored using numerous techniques, including physical-chemical analyses and molecular biology approaches which enabled both the characterization of the mechanisms involved in pollutant transformation and the description of the overall background processes of the treatment. The results revealed that nZVI was efficient toward Cr(VI) by itself and completely removed it from the groundwater (LOQ 0.05mg/l) and the subsequent application of whey resulted in a high removal of chlorinated ethenes (97 to 99%). The persistence of the reducing conditions, even after the depletion of the organic substrates, indicated a complementarity between nZVI and the whey phases in the combined technology as the subsequent application of whey phase partially assisted the microbial regeneration of the spent nZVI by promoting its reduction into Fe(II), which further supported remediation conditions at the site. Illumina sequencing and the detection of functional vcrA and bvcA genes documented a development in the reducing microbes (iron-reducing, sulfate-reducing and chlororespiring bacteria) that benefited under the conditions of the site and that was probably responsible for the high dechlorination and/or Cr(VI) reduction. The results of this study demonstrate the feasibility and high efficiency of the combined nano-biotechnological approach of nZVI and whey application in-situ for the removal of Cr(VI) and chlorinated ethenes from the groundwater of the contaminated site.

  19. Sour gas plant remediation technology research and demonstration project, Task 7.53. Topical report, January--December 1993

    Energy Technology Data Exchange (ETDEWEB)

    Stepan, D.J.; Kuehnel, V.; Schmit, C.R.

    1994-02-01

    Recognizing the potential impacts of sour gas plant operations on the subsurface environment, the Canadian Association of Petroleum Producers (CAPP) and Environment Canada initiated a multiphase study focusing on research related to the development and demonstration of remedial technologies for soil and groundwater contamination at these facilities. Research performed under this project was designed to supplement and be coordinated with research activities being conducted at an operational sour gas plant located in Rocky Mountain House, Alberta, Canada. These research tasks included hydrogeological site characterization, subsurface contaminant characterization, ex situ treatment of groundwater, and subsurface remediation of residual contamination in the unsaturated zone. Ex situ treatment of groundwater included evaluations of air stripping, steam stripping, advanced oxidation, and biological treatment, as well as the development of an artificial freeze crystallization process. Soil vapor extraction was evaluated as a technique to address residual contamination in the unsaturated zone.

  20. Radioactive Tank Waste Remediation Focus Area. Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    In February 1991, DOE`s Office of Technology Development created the Underground Storage Tank Integrated Demonstration (UST-ID), to develop technologies for tank remediation. Tank remediation across the DOE Complex has been driven by Federal Facility Compliance Agreements with individual sites. In 1994, the DOE Office of Environmental Management created the High Level Waste Tank Remediation Focus Area (TFA; of which UST-ID is now a part) to better integrate and coordinate tank waste remediation technology development efforts. The mission of both organizations is the same: to focus the development, testing, and evaluation of remediation technologies within a system architecture to characterize, retrieve, treat, concentrate, and dispose of radioactive waste stored in USTs at DOE facilities. The ultimate goal is to provide safe and cost-effective solutions that are acceptable to both the public and regulators. The TFA has focused on four DOE locations: the Hanford Site in Richland, Washington, the Idaho National Engineering Laboratory (INEL) near Idaho Falls, Idaho, the Oak Ridge Reservation in Oak Ridge, Tennessee, and the Savannah River Site (SRS) in Aiken, South Carolina.

  1. Coupling of zero valent iron and biobarriers for remediation of trichloroethylene in groundwater

    Institute of Scientific and Technical Information of China (English)

    Mullika Teerakun; Alissara Reungsang; Chien-Jung Lin; Chih-Hsiang Liao

    2011-01-01

    This study attempted to construct a three series barrier system to treat high concentrations of trichloroethylene (TCE; 500 mg/L) in synthetic groundwater. The system consisted of three reactive barriers using iron fillings as an iron-based barrier in the first column,sugarcane bagasse mixed with anaerobic sludge as an anaerobic barrier in the second column, and a biofilm coated on oxygen carbon inducer releasing material as an aerobic barrier in the third column. In order to evaluate the extent of removal of TCE and its metabolites in the aquifer down gradient of the barrier system, a fourth column filled with sand was applied. Residence time of the system was investigated by a bromide tracer test. The results showed that residence time in the column system of the control set and experimental set were 23.62 and 29.99 days, respectively. The efficiency of the three series barrier system in removing TCE was approximately 84% in which the removal efficiency of TCE by the iron filling barrier, anaerobic barrier and aerobic barrier were 42%, 16% and 25%,respectively. cis-Dichloroethylene (cis-DCE), vinyl chloride (VC), ethylene and chloride ions were observed as metabolites following TCE degradation. The presence of chloride ions in the effluent from the column system indicated the degradation of TCE. However,cis-DCE and VC were not fully degraded by the proposed barrier system which suggested that another remediation technology after the barrier treatment such as air sparging and adsorption by activated carbon should be conducted.

  2. Acceleration of groundwater remediation by deep sweeps and vortex ejections induced by rapidly pulsed pumping

    Science.gov (United States)

    Kahler, David M.; Kabala, Zbigniew J.

    2016-05-01

    One key limiting factor to groundwater remediation is contaminant sequestered in pores whose contents do not mix well with the bulk flow. Mixing between well-connected (pores whose volume is flushed as water flows through the aquifer) and poorly connected pores (pores whose volume does not exchange readily when water flows through the aquifer) is of primary concern. Under steady flow, contaminants are effectively trapped in the poorly connected pores and are transferred only by molecular diffusion. This slow mixing process between pore types is a bottleneck to remediation. We present a novel rapidly pulsed pumping method that increases the mixing between these pore types. We do it in the context of pump-and-treat remediation because it is the most common remediation practice. In rapidly pulsed pumping, the increase in flow causes a deep sweep, which pushes the flow into poorly connected pores and sweeps out sequestered contaminants. The decrease in flow causes a vortex ejection, which causes the vortex within the poorly connected pore to emerge with contaminant. These actions are modeled with computational fluid mechanics to elucidate the individual mechanisms and determine how they function and interact. Cleanup of single and multiple poorly connected pore systems were simulated and show the acceleration possible. This technique can decrease the time and cost needed to remediate contaminated aquifers, which in the United States has been estimated to exceed $1 trillion. Since our rapidly pulsed pumping method enhances mixing between well-connected and poorly connected pores, it can be applied to other remediation schemes such as in situ methods.

  3. Groundwater Sustainability through a Novel Dewatering Technology

    Science.gov (United States)

    Jin, Y.; Holzbecher, E.; Ebneth, S.

    2012-12-01

    Groundwater plays a key role in the hydrologic cycle and ecosystem balances. Over the past decades, groundwater is intensively extracted in order to keep construction or mining sites dry. For the latter purpose the pumped water is usually discharged into a nearby surface water body or injected into an aquifer distant from the abstraction sites. As a result, aquifers are depleted and the local eco-system is disrupted as a consequence of falling groundwater tables. Given ongoing pressure on aquifer from abstraction sites, it is vital to bring up adequate attention on groundwater conservation. We demonstrate a novel technique, Düsensauginfiltration (DSI, translated as 'nozzel-suction-infiltration'), which avoids water conveyance but still lowers the groundwater table locally. The method combines abstraction of groundwater at the upper part of the aquifer with injection in the same borehole, but at a greater depth. Hence no water is withdrawn from the system. The method is already used practically in Germany, Netherlands, and China, however, it is not yet fully scientifically understood and evaluated. Currently, two tests sites in Germany, for single and multi well respectively, are selected, at which the DSI technology is currently examined. The project is cooperated with a leading dewatering company (Hoelscher Wasserbau GmbH) and funded by Deutsche Bundesstiftung Umwelt (DBU). To provide the basic principle of the method, we present numerical models solving the differential equation, which is derived from Darcy's Law and mass conservation, describing groundwater flow. We set up stationary numerical models in 2D (vertical cross section for single well case) and 3D (multi well case and/or when ambient groundwater flow is considered) using COMSOL Multiphysics. Since our model region only involves the saturated part of the unconfined aquifer, the numerical model solves a free boundary problem using hydraulic pressure as unknown variable. Two physical modes are included

  4. ZVI-Clay remediation of a chlorinated solvent source zone, Skuldelev, Denmark: 2. Groundwater contaminant mass discharge reduction

    DEFF Research Database (Denmark)

    Fjordbøge, Annika Sidelmann; Lange, Ida Vedel; Bjerg, Poul Løgstrup;

    2012-01-01

    The impact of source mass depletion on the down-gradient contaminant mass discharge was monitored for a 19-month period as a part of a field demonstration of the ZVI-Clay soil mixing remediation technology. Groundwater samples were collected from conventional monitoring wells (120 samples......) and a dense network of multilevel samplers (640 samples). The hydraulic gradient and conductivity were determined. Depletion of the contaminant source is described in the companion paper (Fjordbøge et al., 2012). Field data showed four distinct phases for PCE mass discharge: (1) baseline conditions, (2......) initial rapid reduction, (3) temporary increase, and (4) slow long-term reduction. Numerical modeling was utilized to develop a conceptual understanding of the four phases and to identify the governing processes. The initial rapid reduction of mass discharge was a result of the changed hydraulic...

  5. Comparison of surrogate models with different methods in groundwater remediation process

    Indian Academy of Sciences (India)

    Jiannan Luo; Wenxi Lu

    2014-10-01

    Surrogate modelling is an effective tool for reducing computational burden of simulation optimization. In this article, polynomial regression (PR), radial basis function artificial neural network (RBFANN), and kriging methods were compared for building surrogate models of a multiphase flow simulation model in a simplified nitrobenzene contaminated aquifer remediation problem. In the model accuracy analysis process, a 10-fold cross validation method was adopted to evaluate the approximation accuracy of the three surrogate models. The results demonstrated that: RBFANN surrogate model and kriging surrogate model had acceptable approximation accuracy, and further that kriging model’s approximation accuracy was slightly higher than RBFANN model. However, the PR model demonstrated unacceptably poor approximation accuracy. Therefore, the RBFANN and kriging surrogates were selected and used in the optimization process to identify the most cost-effective remediation strategy at a nitrobenzene-contaminated site. The optimal remediation costs obtained with the two surrogate-based optimization models were similar, and had similar computational burden. These two surrogate-based optimization models are efficient tools for optimal groundwater remediation strategy identification.

  6. Natural Attenuation Software (NAS): A computer program for estimating remediation times of contaminated groundwater

    Science.gov (United States)

    Mendez, E.; Widdowson, M.; Brauner, S.; Chapelle, F.; Casey, C.; ,

    2004-01-01

    This paper describes the development and application of a modeling system called Natural Attenuation Software (NAS). NAS was designed as a screening tool to estimate times of remediation (TORs), associated with monitored natural attenuation (MNA), to lower groundwater contaminant concentrations to regulatory limits. Natural attenuation processes that NAS models include advection, dispersion, sorption, biodegradation, and non-aqueous phase liquid (NAPL) dissolution. This paper discusses the three main interactive components of NAS: 1) estimation of the target source concentration required for a plume extent to contract to regulatory limits, 2) estimation of the time required for NAFL contaminants in the source area to attenuate to a predetermined target source concentration, and 3) estimation of the time required for a plume extent to contract to regulatory limits after source reduction. The model's capability is illustrated by results from a case study at a MNA site, where NAS time of remediation estimates compared well with observed monitoring data over multiple years.

  7. Quantifying reduction in ecological risk in Penrhyn Estuary, Sydney, Australia, following groundwater remediation.

    Science.gov (United States)

    Hunt, James; Birch, Gavin; Warne, Michael

    2012-01-01

    The environmental risk associated with discharge of contaminated groundwater containing a complex mixture of at least 14 volatile chlorinated hydrocarbons (VCHs) to Penrhyn Estuary, Sydney, Australia has previously been assessed. That probabilistic ecological risk assessment (ERA) was undertaken using surface water monitoring data from 2004 to 2005. Subsequently, in 2006, a groundwater remediation system was installed and commissioned to prevent further discharge of VCHs into the estuary. The present study assessed the ecological risk posed to the estuary after 2006 to evaluate the success of the remediation system. The ERA was undertaken using toxicity data derived from direct toxicity assessment (DTA) of preremediation contaminated groundwater using indigenous species, exposure data from surface water monitoring between 2007 and 2008 and the joint probability curve (JPC) methodology. The risk posed was measured in 4 zones of the entire site: source area (2), tributary (2), the inner estuary and outer estuary at high, low, and a combination of high and low tides. In the 2 source areas, risk decreased by over 2 and over 1 orders of magnitude to maximum values of less than 0.5%. In 1 estuary, risk decreased by over 1 order of magnitude, from a maximum of 36% to a maximum of 2.3%. At the other tributary and both the inner and outer estuaries, the risk decreased to less than 1%, regardless of the tide. This analysis revealed that the remediation system was very effective and that the standard level of protection required for slightly to moderately affected ecosystems (95% of species) by the Australian and New Zealand Guidelines for Fresh and Marine Water Quality was met postremediation.

  8. Addendum to the East Tennessee Technology Park Site-Wide Residual Contamination Remedial Investigation Work Plan Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    SAIC

    2011-04-01

    The East Tennessee Technology Park Site-Wide Residual Contamination Remedial Investigation Work Plan (DOE 2004) describes the planned fieldwork to support the remedial investigation (RI) for residual contamination at the East Tennessee Technology Park (ETTP) not addressed in previous Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) decisions. This Addendum describes activities that will be conducted to gather additional information in Zone 1 of the ETTP for groundwater, surface water, and sediments. This Addendum has been developed from agreements reached in meetings held on June 23, 2010, August 25, 2010, October 13, 2010, November 13, 2010, December 1, 2010, and January 13, 2011, with representatives of the U. S. Department of Energy (DOE), U. S. Environmental Protection Agency (EPA), and Tennessee Department of Environment and Conservation (TDEC). Based on historical to recent groundwater data for ETTP and the previously completed Sitewide Remedial Investigation for the ETTP (DOE 2007a), the following six areas of concern have been identified that exhibit groundwater contamination downgradient of these areas above state of Tennessee and EPA drinking water maximum contaminant levels (MCLs): (1) K-720 Fly Ash Pile, (2) K-770 Scrap Yard, (3) Duct Island, (4) K-1085 Firehouse Burn/J.A. Jones Maintenance Area, (5) Contractor's Spoil Area (CSA), and (6) Former K-1070-A Burial Ground. The paper presents a brief summary of the history of the areas, the general conceptual models for the observed groundwater contamination, and the data gaps identified.

  9. Data and Model Uncertainties associated with Biogeochemical Groundwater Remediation and their impact on Decision Analysis

    Science.gov (United States)

    Pandey, S.; Vesselinov, V. V.; O'Malley, D.; Karra, S.; Hansen, S. K.

    2016-12-01

    Models and data are used to characterize the extent of contamination and remediation, both of which are dependent upon the complex interplay of processes ranging from geochemical reactions, microbial metabolism, and pore-scale mixing to heterogeneous flow and external forcings. Characterization is wrought with important uncertainties related to the model itself (e.g. conceptualization, model implementation, parameter values) and the data used for model calibration (e.g. sparsity, measurement errors). This research consists of two primary components: (1) Developing numerical models that incorporate the complex hydrogeology and biogeochemistry that drive groundwater contamination and remediation; (2) Utilizing novel techniques for data/model-based analyses (such as parameter calibration and uncertainty quantification) to aid in decision support for optimal uncertainty reduction related to characterization and remediation of contaminated sites. The reactive transport models are developed using PFLOTRAN and are capable of simulating a wide range of biogeochemical and hydrologic conditions that affect the migration and remediation of groundwater contaminants under diverse field conditions. Data/model-based analyses are achieved using MADS, which utilizes Bayesian methods and Information Gap theory to address the data/model uncertainties discussed above. We also use these tools to evaluate different models, which vary in complexity, in order to weigh and rank models based on model accuracy (in representation of existing observations), model parsimony (everything else being equal, models with smaller number of model parameters are preferred), and model robustness (related to model predictions of unknown future states). These analyses are carried out on synthetic problems, but are directly related to real-world problems; for example, the modeled processes and data inputs are consistent with the conditions at the Los Alamos National Laboratory contamination sites (RDX and

  10. Optimal Design of Groundwater Remediation Problems under Uncertainty Using Probabilistic Multi-objective Evolutionary Technique

    Science.gov (United States)

    Yang, Y.; Wu, J.

    2011-12-01

    The previous work in the field of multi-objective optimization under uncertainty has concerned with the probabilistic multi-objective algorithm itself, how to effectively evaluate an estimate of uncertain objectives and identify a set of reliable Pareto optimal solutions. However, the design of a robust and reliable groundwater remediation system encounters major difficulties owing to the inherent uncertainty of hydrogeological parameters such as hydraulic conductivity (K). Thus, we need to make reduction of uncertainty associated with the site characteristics of the contaminated aquifers. In this study, we first use the Sequential Gaussian Simulation (SGSIM) to generate 1000 conditional realizations of lnK based on the sampled conditioning data acquired by field test. It is worthwhile to note that the cost for field test often weighs heavily upon the remediation cost and must thus be taken into account in the tradeoff between the solution reliability and remedial cost optimality. In this situation, we perform Monte Carlo simulation to make an uncertainty analysis of lnK realizations associated with the different number of conditioning data points. The results indicate that the uncertainty of the site characteristics and the contaminant concentration output from transport model is decreasing and then tends toward stabilization with the increase of conditioning data. This study presents a probabilistic multi-objective evolutionary algorithm (PMOEA) that integrates noisy genetic algorithm (NGA) and probabilistic multi-objective genetic algorithm (MOGA). The evident difference between deterministic MOGA and probabilistic MOGA is the use of probabilistic Pareto domination ranking and niche technique to ensure that each solution found is most reliable and robust. The proposed algorithm is then evaluated through a synthetic pump-and-treat (PAT) groundwater remediation test case. The 1000 lnK realizations generated by SGSIM with appropriate number of conditioning data (30

  11. Particulate Pyrite Autotrophic Denitrification (PPAD) for Remediation of Nitrate-contaminated Groundwater

    Science.gov (United States)

    Tong, S.; Rodriguez-Gonzalez, L. C.; Henderson, M.; Feng, C.; Ergas, S. J.

    2015-12-01

    The rapid movement of human civilization towards urbanization, industrialization, and increased agricultural activities has introduced a large amount of nitrate into groundwater. Nitrate is a toxic substance discharged from groundwater to rivers and leads to decreased dissolved oxygen and eutrophication. For this experiment, an electron donor is needed to convert nitrate into non-toxic nitrogen gas. Pyrite is one of the most abundant minerals in the earth's crust making it an ideal candidate as an electron donor. The overall goal of this research was to investigate the potential for pyrite to be utilized as an electron donor for autotrophic denitrification of nitrate-contaminated groundwater. Batch studies of particulate pyrite autotrophic denitrification (PPAD) of synthetic groundwater (100 mg NO3--N L-1) were set up with varying biomass concentration, pyrite dose, and pyrite particle size. Reactors were seeded with mixed liquor volatile suspended solids (VSS) from a biological nitrogen removal wastewater treatment facility. PPAD using small pyrite particles (treatment and promoted the utilization of pyrite in the field of environmental remediation.

  12. National conference on environmental remediation science and technology: Abstracts

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    This conference was held September 8--10, 1998 in Greensboro, North Carolina. The purpose of this conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on methods and site characterization technologies for environmental monitoring and remedial action planning of hazardous materials. This report contains the abstracts of sixty-one papers presented at the conference.

  13. TREATMENT TECHNOLOGY FOR REMEDIATION OF WOOD PRESERVING SITES: OVERVIEW

    Science.gov (United States)

    This is the first in a series of five articles describing the applicability, performance and cost of technologies for the remediation of contaminated soil and water at wood preserving sites. Site-specific treatability studies conducted under the supervision of the USEPA NRMRL fro...

  14. A Risk Analysis of Remediation Technologies for a DOE Facility

    Science.gov (United States)

    1998-03-01

    The Department of Energy is responsible for selecting a remediation technology to cleanup the Waste Area Group (WAG) 6 site at the Paducah Gaseous ... Diffusion Plant (PGDP) in Kentucky. WAG 6 is contaminated with an uncertain amount of trichloroethylene (TCE) and technetium-99 (Tc-99). Selecting a

  15. A simulation-based fuzzy chance-constrained programming model for optimal groundwater remediation under uncertainty

    Science.gov (United States)

    He, L.; Huang, G. H.; Lu, H. W.

    2008-12-01

    In this study a simulation-based fuzzy chance-constrained programming (SFCCP) model is developed based on possibility theory. The model is solved through an indirect search approach which integrates fuzzy simulation, artificial neural network and simulated annealing techniques. This approach has the advantages of: (1) handling simulation and optimization problems under uncertainty associated with fuzzy parameters, (2) providing additional information (i.e. possibility of constraint satisfaction) indicating that how likely one can believe the decision results, (3) alleviating computational burdens in the optimization process, and (4) reducing the chances of being trapped in local optima. The model is applied to a petroleum-contaminated aquifer located in western Canada for supporting the optimal design of groundwater remediation systems. The model solutions provide optimal groundwater pumping rates for the 3, 5 and 10 years of pumping schemes. It is observed that the uncertainty significantly affects the remediation strategies. To mitigate such impacts, additional cost is required either for increased pumping rate or for reinforced site characterization.

  16. Environmental restoration: Integrating hydraulic control of groundwater, innovative contaminant removal technologies and wetlands restoration--A case study at SRS

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, C.M.; Serkiz, S.M.; Adams, J.; Welty, M. (Westinghouse Savannah River Co., Aiken, SC (United States))

    1992-01-01

    The groundwater remediation program at the F and H Seepage Basins, Savannah River Sits (SRS) is a case study of the integration of various environmental restoration technologies at a single waste site. Hydraulic control measures are being designed to mitigate the discharge of groundwater plumes to surface water. One of the primary constituents of the plumes is tritium. An extraction and reinjection scenario is being designed to keep the tritium in circulation in the shallow groundwater, until it can naturally decay. This will be accomplished by extracting groundwater downgradient of the waste sites, treatment, and reinjection of the tritiated water into the water table upgradient of the basins. Innovative in-situ technologies, including electrolytic migration, are being field tested at the site to augment the pump-treat-reinject system. The in-situ technologies target removal of contaminants which are relatively immobile, yet represent long term risks to human health and the environment. Wetland restoration is an integral part of the F and H remediation program. Both in-situ treatment of the groundwater discharging the wetlands to adjust the pH, and replacement of water loss due to the groundwater extraction program ar being considered. Toxicity studies indicate that drought and the effects of low pH groundwater discharge have been factors in observed tree mortality in wetlands near the waste sites.

  17. Mobility of Nanoscale and Microscale iron for groundwater remediation: experiments and modelling

    Science.gov (United States)

    Tosco, T.; Gastone, F.; Sethi, R.

    2012-12-01

    Colloidal suspensions of zerovalent iron micro- and nanoparticles (MZVI and NZVI) have been studied in recent years for in-situ groundwater remediation. Thanks to their small size, MZVI and NZVI can be dispersed in aqueous suspensions and directly injected into the subsurface, for a targeted treatment of contamination plumes and even sources. However, colloidal dispersions of such particles are not stable in pure water, due to fast aggregation (for NZVI) and gravitational sedimentation (for MZVI). Viscous, environmentally friendly fluids (guar gum and xanthan gum solutions), which exhibit shear thinning rheological properties, were found to be effective in improving colloidal stability, thus greatly improving handling and injectability (1-3). The present work reports laboratory tests and numerical modelling concerning the mobility of MZVI and NZVI viscous suspensions in porous media. The efficacy of xanthan and guar gum was investigated in column transport tests, performed injecting highly concentrated iron suspensions (20 g/L), dispersed in xanthan gum (3g/L) and guar gum (3-6 g/l) solutions. Particle breakthrough curves and concentration profiles were monitored by magnetic susceptibility measurements. Pressure drop at column ends was also continuously monitored. The tests proved that green polymers can greatly improve both colloidal stability and mobility of the particles. Their use is fundamental in particular for MZVI, which cannot be transported nor even dispersed in pure water. A numerical model for NZVI and NZVI transport in porous media was then developed (E-MNM1D, Enhanced Micro-and Nanoparticle transport Model in porous media in 1D geometry) (4). Due to the high concentration of the particles and to the non-Newtonian rheology of the carrier fluid, hydrodynamic parameters, fluid properties and concentration of deposed and suspended particles are mutually influenced. The rheological properties of the suspensions are accounted for through a variable

  18. Monitoring and remediation technologies of organochlorine pesticides in drainage water

    Directory of Open Access Journals (Sweden)

    Ismail Ahmed

    2015-03-01

    Full Text Available This study was carried out to monitor the presence of organochlorine in drainage water in Kafr-El-Sheikh Governorate, Egypt. Furthermore, to evaluate the efficiencies of different remediation techniques (advanced oxidation processes [AOPs] and bioremediation for removing the most frequently detected compound (lindane in drainage water. The results showed the presence of several organochlorine pesticides in all sampling sites. Lindane was detected with high frequency relative to other detected organochlorine in drainage water. Nano photo-Fenton like reagent was the most effective treatment for lindane removal in drainage water. Bioremediation of lindane by effective microorganisms (EMs removed 100% of the lindane initial concentration. There is no remaining toxicity in lindane contaminated-water after remediation on treated rats relative to control with respect to histopathological changes in liver and kidney. Advanced oxidation processes especially with nanomaterials and bioremediation using effective microorganisms can be regarded as safe and effective remediation technologies of lindane in water.

  19. ENGINEERING BULLETIN: SEPARATION/CONCENTRATION TECHNOLOGY ALTERNATIVES FOR THE REMEDIATION OF PESTICIDE-CONTAMINATED SOIL

    Science.gov (United States)

    Pesticide contamination includes a wide variety of compounds and may result from manufacturing improper storage, handling, disposal; or agricultural processes. It can occur in soil and can lead to secondary contamination of groundwater. Remediation of pesticide-contaminated soils...

  20. Permeable reactive barriers for the remediation of groundwater in a mining area: results for a pilot-scale project

    Science.gov (United States)

    Martinez-Sanchez, Maria Jose; Perez-Sirvent, Carmen; Garcia-Lorenzo, Maria Luz; Martinez-Lopez, Salvadora; Perez-Espinosa, Victor; Gonzalez-Ciudad, Eva; Belen Martinez-Martinez, Lucia; Hernandez, Carmen; Molina-Ruiz, Jose

    2017-04-01

    The Sierra Minera of Cartagena-La Union is located in the Region of Murcia, Southeast of Spain. This zone presents high levels of heavy metals due to natural, geogenic reasons. In addition, the prolonged mining activity, and subsequent abandonment of farms, has had consequences on the environment, including severe affectation of the groundwater in the area. To remediate this situation, the Permeable Reactive Barrier (PRB) technology was assayed, which required in addition to the hydro-geological study of the zone, a careful optimization study for the design and construction of PRBs. For such a purpose a pilot-scale project was developed, and this communication reports some of the most relevant findings obtained after a four-years monitorization period. The selected reactive material for the PRBs was limestone filler. The filler is a waste material produced in many factories in the zone. These residues have good adsorption properties, high alkalinity, low cost and high availability, which make them suitable for use in remediation. The PRB was constituted by a 50% limestone filler and 50% sand, a proportion optimized by means of independent batch experiments. A layer of gravel was placed at the top, and on it a layer of natural soil. The barrier was designed in the form of a continuous trench, because the level of the contaminated groundwater was not very deep. In this way, the barrier could be prepared with standard excavation equipment. Parallel to the barrier, 6 wells where arranged downstream for sample collection. The pH and conductivity of the samples was measured directly in situ, and the content of Zn, Cd, Cu, Fe, and Pb were analyzed in the laboratory. All the samples collected after the PRB was constructed had basic pH values between 7.5 and 8. The conductivity was between 5 and 11 mS / cm except for the well 4, which had a value of 3.70 mS / cm. The concentration values of trace elements were below the detection limit (atomic absorption measurement) in

  1. In situ Remediation of Petroleum Contaminated Groundwater by Permeable Reactive Barrier with Hydrothermal Palygorskite as Medium

    Institute of Scientific and Technical Information of China (English)

    ZHANG Sheng-yu; ZHANG Yu-ling; SU Xiao-si; ZHANG Ying

    2013-01-01

    The permeable reactive barrier(PRB) has proven to be a cost-effective technique to remediate the petroleum contaminated groundwater at a northeast field site in China.In this study,the geology,hydrogeology and contamination characterization of the field site were investigated and the natural hydrothermal palygorskite was chosen as a reactive medium.Furthermore,the adsorption of the total petroleum hydrocarbons(TPH) in the groundwater onto hydrothermal palygorskite and the adsorption kinetics were investigated.The results indicate that the removal rates of TPH,benzene,naphthalene and phenantharene could all reach up to 90% by hydrothermal palygorskite with a diameter of 0.25-2.00 mm that had been thermally pretreated at 140 ℃.The adsorption of TPH onto hydrothermal palygorskite after pretreatment followed a pseudo-second-order kinetic model and a Langmuir adsorption isotherm,suggesting that the theoretic adsorption capacity of hydrothermal palygorskite for adsorbate could be 4.2 g/g.Scanning electron microscopy(SEM),infrared spectroscopy(IR),X-ray diffraction(XRD) and X-ray fluorescence spectroscopy(XRF) were carried out to analyze the adsorption mechanism.The results reveal that hydrothermal palygorskite is a fibrous silicate mineral enriched in Mg and A1 with large surface area and porosity.The dense cluster acicular and fibrous crystal of hydrothermal palygorskite,and its effect polar group —OH played an important role in the physical and chemical adsorption processes of it for contaminants.This study has demonstrated hydrothermal palygorskite is a reliable reactive medium for in situ remediation of petroleum contaminated groundwater at field sites.

  2. Agar agar-stabilized milled zerovalent iron particles for in situ groundwater remediation

    Energy Technology Data Exchange (ETDEWEB)

    Velimirovic, Milica; Schmid, Doris; Wagner, Stephan; Micić, Vesna; Kammer, Frank von der; Hofmann, Thilo, E-mail: thilo.hofmann@univie.ac.at

    2016-09-01

    Submicron-scale milled zerovalent iron (milled ZVI) particles produced by grinding macroscopic raw materials could provide a cost-effective alternative to nanoscale zerovalent iron (nZVI) particles for in situ degradation of chlorinated aliphatic hydrocarbons in groundwater. However, the aggregation and settling of bare milled ZVI particles from suspension presents a significant obstacle to their in situ application for groundwater remediation. In our investigations we reduced the rapid aggregation and settling rate of bare milled ZVI particles from suspension by stabilization with a “green” agar agar polymer. The transport potential of stabilized milled ZVI particle suspensions in a diverse array of natural heterogeneous porous media was evaluated in a series of well-controlled laboratory column experiments. The impact of agar agar on trichloroethene (TCE) removal by milled ZVI particles was assessed in laboratory-scale batch reactors. The use of agar agar significantly enhanced the transport of milled ZVI particles in all of the investigated porous media. Reactivity tests showed that the agar agar-stabilized milled ZVI particles were reactive towards TCE, but that their reactivity was an order of magnitude less than that of bare, non-stabilized milled ZVI particles. Our results suggest that milled ZVI particles could be used as an alternative to nZVI particles as their potential for emplacement into contaminated zone, their reactivity, and expected longevity are beneficial for in situ groundwater remediation. - Highlights: • Rapid aggregation and sedimentation were observed in bare milled ZVI particles. • Agar agar improved the stability of milled ZVI particle suspensions. • Agar agar enhanced the transport of milled ZVI particles in heterogeneous sands. • Agar agar reduced the reactivity of milled ZVI particles towards TCE.

  3. Supplemental Assessment of the Y-12 Groundwater Protection Program Using Monitoring and Remediation Optimization System Software

    Energy Technology Data Exchange (ETDEWEB)

    Elvado Environmental LLC; GSI Environmental LLC

    2009-01-01

    A supplemental quantitative assessment of the Groundwater Protection Program (GWPP) at the Y-12 National Security Complex (Y-12) in Oak Ridge, TN was performed using the Monitoring and Remediation Optimization System (MAROS) software. This application was previously used as part of a similar quantitative assessment of the GWPP completed in December 2005, hereafter referenced as the 'baseline' MAROS assessment (BWXT Y-12 L.L.C. [BWXT] 2005). The MAROS software contains modules that apply statistical analysis techniques to an existing GWPP analytical database in conjunction with hydrogeologic factors, regulatory framework, and the location of potential receptors, to recommend an improved groundwater monitoring network and optimum sampling frequency for individual monitoring locations. The goal of this supplemental MAROS assessment of the Y-12 GWPP is to review and update monitoring network optimization recommendations resulting from the 2005 baseline report using data collected through December 2007. The supplemental MAROS assessment is based on the findings of the baseline MAROS assessment and includes only the groundwater sampling locations (wells and natural springs) currently granted 'Active' status in accordance with the Y-12 GWPP Monitoring Optimization Plan (MOP). The results of the baseline MAROS assessment provided technical rationale regarding the 'Active' status designations defined in the MOP (BWXT 2006). One objective of the current report is to provide a quantitative review of data collected from Active but infrequently sampled wells to confirm concentrations at these locations. This supplemental MAROS assessment does not include the extensive qualitative evaluations similar to those presented in the baseline report.

  4. Subsurface Transport Behavior of Micro-Nano Bubbles and Potential Applications for Groundwater Remediation

    Directory of Open Access Journals (Sweden)

    Hengzhen Li

    2013-12-01

    Full Text Available Micro-nano bubbles (MNBs are tiny bubbles with diameters on the order of micrometers and nanometers, showing great potential in environmental remediation. However, the application is only in the beginning stages and remains to be intensively studied. In order to explore the possible use of MNBs in groundwater contaminant removal, this study focuses on the transport of MNBs in porous media and dissolution processes. The bubble diameter distribution was obtained under different conditions by a laser particle analyzer. The permeability of MNB water through sand was compared with that of air-free water. Moreover, the mass transfer features of dissolved oxygen in water with MNBs were studied. The results show that the bubble diameter distribution is influenced by the surfactant concentration in the water. The existence of MNBs in pore water has no impact on the hydraulic conductivity of sand. Furthermore, the dissolved oxygen (DO in water is greatly increased by the MNBs, which will predictably improve the aerobic bioremediation of groundwater. The results are meaningful and instructive in the further study of MNB research and applications in groundwater bioremediation.

  5. Emerging Technologies for Environmental Remediation: Integrating Data and Judgment.

    Science.gov (United States)

    Bates, Matthew E; Grieger, Khara D; Trump, Benjamin D; Keisler, Jeffrey M; Plourde, Kenton J; Linkov, Igor

    2016-01-01

    Emerging technologies present significant challenges to researchers, decision-makers, industry professionals, and other stakeholder groups due to the lack of quantitative risk, benefit, and cost data associated with their use. Multi-criteria decision analysis (MCDA) can support early decisions for emerging technologies when data is too sparse or uncertain for traditional risk assessment. It does this by integrating expert judgment with available quantitative and qualitative inputs across multiple criteria to provide relative technology scores. Here, an MCDA framework provides preliminary insights on the suitability of emerging technologies for environmental remediation by comparing nanotechnology and synthetic biology to conventional remediation methods. Subject matter experts provided judgments regarding the importance of criteria used in the evaluations and scored the technologies with respect to those criteria. The results indicate that synthetic biology may be preferred over nanotechnology and conventional methods for high expected benefits and low deployment costs but that conventional technology may be preferred over emerging technologies for reduced risks and development costs. In the absence of field data regarding the risks, benefits, and costs of emerging technologies, structuring evidence-based expert judgment through a weighted hierarchy of topical questions may be helpful to inform preliminary risk governance and guide emerging technology development and policy.

  6. Cost studies of thermally enhanced in situ soil remediation technologies

    Energy Technology Data Exchange (ETDEWEB)

    Bremser, J.; Booth, S.R.

    1996-05-01

    This report describes five thermally enhanced technologies that may be used to remediate contaminated soil and water resources. The standard methods of treating these contaminated areas are Soil Vapor Extraction (SVE), Excavate & Treat (E&T), and Pump & Treat (P&T). Depending on the conditions at a given site, one or more of these conventional alternatives may be employed; however, several new thermally enhanced technologies for soil decontamination are emerging. These technologies are still in demonstration programs which generally are showing great success at achieving the expected remediation results. The cost savings reported in this work assume that the technologies will ultimately perform as anticipated by their developers in a normal environmental restoration work environment. The five technologies analyzed in this report are Low Frequency Heating (LF or Ohmic, both 3 and 6 phase AC), Dynamic Underground Stripping (DUS), Radio Frequency Heating (RF), Radio Frequency Heating using Dipole Antennae (RFD), and Thermally Enhanced Vapor Extraction System (TEVES). In all of these technologies the introduction of heat to the formation raises vapor pressures accelerating contaminant evaporation rates and increases soil permeability raising diffusion rates of contaminants. The physical process enhancements resulting from temperature elevations permit a greater percentage of volatile organic compound (VOC) or semi- volatile organic compound (SVOC) contaminants to be driven out of the soils for treatment or capture in a much shorter time period. This report presents the results of cost-comparative studies between these new thermally enhanced technologies and the conventional technologies, as applied to five specific scenarios.

  7. Remediation of Nitrate-contaminated Groundwater by a Mixture of Iron and Activated Carbon

    Science.gov (United States)

    Huang, Guoxin; Liu, Fei; Jin, Aifang; Qin, Xiaopeng

    2010-11-01

    Nitrate contamination in groundwater has become a major environmental and health problem worldwide. The aim of the present study is to remediate groundwater contaminated by nitrate and develop potential reactive materials to be used in PRBs (Permeable Reactive Barriers). A new approach was proposed for abiotic groundwater remediation by reactive materials of iron chips and granular activated carbon particles. Batch tests were conducted and remediation mechanisms were discussed. The results show that nitrate decreases from 86.31 to 33.79 mgṡL-1 under the conditions of near neutral pH and reaction time of 1h. The combination of iron chips and activated carbon particles is cost-effective and suitable for further use as denitrification media in PRBs. Nitrogen species don't change significantly with the further increase in reaction time (>1 h). The iron-activated carbon-water-nitrate system tends to be steady-state. Small amounts of ammonium and nitrite (0.033-0.039 and 0.14-3.54 mgṡL-1, respectively) appear at reaction time from 0 h to 5 h. There is no substantial accumulation of nitrogen products in the system. The removal rate of nitrate only reaches 16.11% by sole iron chips at reaction time of 5 h, while 63.57% by the mixture of iron chips and activated carbon particles. There is significantly synergistic and promotive effect of mixing the two different types of materials on nitrate treatment. Fe/C ratio (1/1.5-1/2.5) doesn't cause dramatically different residual nitrate concentrations (24.09-26.70 mgṡL-1). Nitrate can't be limitlessly decreased with decreasing Fe/C ratio. The concomitant occurrences of chemical reduction, galvanic cell reaction, electrophoretic accumulation, chemical coagulation, and physical adsorption are all responsible for the overall nitrate removal by iron allied with activated carbon. To accurately quantify various nitrogen species, further studies on adsorption mechanisms of nitrite and nitrate are needed.

  8. Purification of contaminated groundwater by membrane technology

    Energy Technology Data Exchange (ETDEWEB)

    Youn, In Soo; Chung, Chin Ki; Kim, Byoung Gon [Korea Institute of Geology Mining and Materials, Taejon (Korea, Republic of)

    1996-12-01

    The objective of this study is to apply the membrane separation technology to the purification of contaminated ground water in Korea. Under this scope, the purification was aimed to the drinking water level. The scale of the membrane system was chosen to a small filtration plant for local clean water supplies and/or heavy purifiers for buildings and public uses. The actual conditions of ground water contamination in Korea was surveyed to determine the major components to remove under the drinking water requirements. To set up a hybrid process with membrane methods, conventional purification methods were also investigated for the comparison purpose. The research results are summarized as follows : 1) Contamination of the groundwater in Korea has been found to be widespread across the country. The major contaminant were nitrate, bacteria, and organic chlorides. Some solvents and heavy metals are also supposed to exist in the ground water of industrial complexes, cities, and abandoned mines. 2) The purification methods currently used in public filtration plants appear not to be enough for new contaminants from recent industrial expanding. The advanced purification technologies generally adopted for this problem have been found to be unsuitable due to their very complicated design and operation, and lack of confidence in the purification performance. 3) The reverse osmosis tested with FilmTec FT30 membrane was found to remove nitrate ions in water with over 90 % efficiency. 4) The suitable membrane process for the contaminated groundwater in Korea has been found to be the treatments composed of activated carbon, microfiltration, reverse osmosis or ultrafiltration, and disinfection. The activated carbon treatment could be omitted for the water of low organic contaminants. The microfiltration and the reverse osmosis treatments stand for the conventional methods of filtration plants and the advanced methods for hardly removable components, respectively. It is recommended

  9. Technology needs for environmental restoration remedial action

    Energy Technology Data Exchange (ETDEWEB)

    Watson, J.S.

    1992-11-01

    This report summarizes the current view of the most important technology needs for the US Department of Energy (DOE) facilities operated by Martin Marietta Energy Systems, Inc. These facilities are the Oak Ridge National Laboratory, the Oak Ridge K-25 Site, the Oak Ridge Y-12 Plant, the Paducah Gaseous Diffusion Plant, and the Portsmouth Gaseous Diffusion Plant. The sources of information used in this assessment were a survey of selected representatives of the Environmental Restoration (ER) programs at each facility, results from a questionnaire distributed by Geotech CWM, Inc., for DOE, and associated discussions with individuals from each facility. This is not a final assessment, but a brief look at an ongoing assessment; the needs will change as the plans for restoration change and, it is hoped, as some technical problems are solved through successful development programs.

  10. REMOVAL OF ADDED NITRATE IN COTTON BURR COMPOST, MULCH COMPOST, AND PEAT: MECHANISMS AND POTENTIAL USE FOR GROUNDWATER NITRATE REMEDIATION

    Science.gov (United States)

    We conducted batch tests on the nature and kinetics of removal of added nitrate in cotton burr compost, mulch compost, and sphagnum peat that may be potentially used in a permeable reactive barrier (PRB) for groundwater nitrate remediation. A rigorous steam autoclaving protocol (...

  11. REMOVAL OF ADDED NITRATE IN COTTON BURR COMPOST, MULCH COMPOST, AND PEAT: MECHANISMS AND POTENTIAL USE FOR GROUNDWATER NITRATE REMEDIATION

    Science.gov (United States)

    We conducted batch tests on the nature and kinetics of removal of added nitrate in cotton burr compost, mulch compost, and sphagnum peat that may be potentially used in a permeable reactive barrier (PRB) for groundwater nitrate remediation. A rigorous steam autoclaving protocol (...

  12. Developing technology of remediation of oil-contaminated soils

    OpenAIRE

    Shevchyk, Lesya; Romaniuk, Olga

    2013-01-01

    Abstract ? The results of developing technologies for cleaning of soils from oil pollution on the example of Boryslav are shown. The prospects of tree species for the remediation of oil-contaminated soils are studied. The best results of cleaning oil contaminated soils with the application of Hippophae rhamnoides L. plants were obtained. It is a promising measure for restoring the oil-contaminated soils, attractive both from environmental and economical point of view.

  13. Development of Enhanced Remedial Techniques for Petroleum Fuel and Related Contaminants in Soil and Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Paul Fallgren

    2009-02-10

    Western Research Institute (WRI) in conjunction with Earth Tech and the U.S. Department of Energy (DOE) was to identify proper sites with soils and/or groundwater contaminated by petroleum constituents and MTBE. Biodegradation rates would have been quantitatively assessed in both laboratory and field tests to achieve the optimal destruction of contaminants of concern. WRI and Earth Tech identified a site contaminated with high concentrations of methanol associated with petroleum hydrocarbons. The site was assessed and a remediation project plan was prepared; however, the site was soon acquired by a new company. An agreement between Earth Tech, WRI, and the new site owners could not be reached; therefore, a work was performed to identify a new project site. Task 33 was terminated and the available funding was redeployed to other Tasks after receiving approval from the U.S. DOE task manager.

  14. Sealable joint steel sheet piling for groundwater control and remediation: Case histories

    Energy Technology Data Exchange (ETDEWEB)

    Smyth, D. [Univ. of Waterloo (Canada); Jowett, R. [Waterloo Barrier Inc., Rockwood, Ontario (Canada); Gamble, M. [C3 Environmental, Breslau, Ontario (Canada)

    1997-12-31

    The Waterloo Barrier{trademark} steel sheet piling (patents pending) incorporates a cavity at each interlocking joint that is flushed clean and injected with sealant after the piles have been driven into the ground to form a vertical cutoff wall. The installation and sealing procedures allow for a high degree of quality assurance and control. Bulk wall hydraulic conductivities of 10{sup -8} to 10{sup -10} cm/sec have been demonstrated at field installations. Recent case histories are presented in which Waterloo Barrier{trademark} cutoff walls are used to prevent off-site migration of contaminated groundwater or soil gases to adjacent property and waterways. Full enclosures to isolate DNAPL source zones or portions of contaminated aquifers for pilot-scale remediation testing will also be described. Monitoring data will be used to demonstrate the effectiveness of the Waterloo Barrier{trademark} in these applications.

  15. Remediation of subsurface and groundwater contamination with uranium from fuel fabrication facilities at Hanau (Germany)

    Energy Technology Data Exchange (ETDEWEB)

    Nitzsche, Olaf; Thierfeldt, Stefan [Brenk Systemplanung GmbH, Aachen (Germany); Hummel, Lothar [TUV Sud AG, Munchen (Germany)

    2013-07-01

    This paper presents aspects of site decommissioning and clearance of a former fuel fabrication facility (development and production of fuel assemblies for research reactors and HTR) at Hanau (Germany). The main pathways for environmental contamination were deposition on soil surface and topsoil and pollution of deep soil and the aquifer by waste water channel leakage. Soil excavation could be done by classical excavator techniques. An effective removal of material from the saturated zone was possible by using advanced drilling techniques. A large amount of demolished building structure and excavated soil had to be classified. Therefore the use of conveyor detector was necessary. Nearly 100000 Mg of material (excavated soil and demolished building material) were disposed of at an underground mine. A remaining volume of 700 m{sup 3} was classified as radioactive waste. Site clearance started in 2006. Groundwater remediation and monitoring is still ongoing, but has already provided excellent results by reducing the remaining Uranium considerably. (authors)

  16. Effects of gentle remediation technologies on soil biological and biochemical activities - a review.

    Science.gov (United States)

    Marschner, B.; Haag, R.; Renella, G.

    2009-04-01

    Remediation technologies for contaminated sites are generally designed to reduce risks for human health, groundwater or plant quality. While some drastic remediation measures such as soil excavation, thermal treatment or soil washing eliminate or strongly reduce soil life, in-situ treatments involving plants or immobilizing additives may also restore soil functionality by establishing or promoting a well structured and active community of soil organisms. Biological parameters that are sensitive to contaminants and other pedo-environmental conditions and which contribute to biogeochemical nutrient cycles, can be used as synthetic indicators of the progress and also the efficiency of given remediation approaches. Data from long-term studies on re-vegetated mine spoils show that biological and biochemical activity is enhanced with increasing plant density and diversity. Among the soil amendments, most measures that introduce organic matter or alkalinity to the contaminated soils also improve microbial or faunal parameters. Only few amendments, such as phosphates and chelators have deleterious effects on soil biota. In this review, soil microbial biomass and the activity of the enzymes phosphatase and arylsulphatase are identified as suitable and sensitive biological indicators for soil health. The results and future research needs are are summarized.

  17. Laboratory Validation of Passive Flow Focusing of Horizontal Wells for in Situ Groundwater Remediation

    Science.gov (United States)

    DiMarco, A.; Crimi, M.; Holsen, T.; Bellona, C.; Kumarage, P.; Divine, C.; O'Fallon, T.

    2014-12-01

    A new concept for in situgroundwater remediation was recently developed where drilled horizontal wells filled with granular treatment media are installed in the direction of groundwater flow. Due to the differences in hydraulic conductivity (K) of the media in the well and the surrounding aquifer, groundwater is "focused" into the well and treated (Figure 1). Initial computer simulations demonstrate that the horizontal well will have a substantial capture zone making this a viable and appealing remediation strategy. In this work, a laboratory scale model was constructed to validate the computer simulations and determine the expected capture zone of a horizontal well under a range of hydraulic conductivity differentials. We have built a physical model to replicate a horizontal well in a confined aquifer. The model is constructed inside a 55-gallon drum packed with sand and water is pumped into the bottom of the drum and flows upward through the system. Within the aquifer, we installed a 1" screened well packed with lime-soda beads. To define the capture zone, we placed manometers in the aquifer. Finally, a constant head is applied to the system (Figure 2 and 3). Initial tests have shown that the 1" well with a hydraulic conductivity 65 times greater than the surrounding aquifer (kwell= 1.3 cm/sec vs. kaquifer= 0.02cm/sec) will capture a significant percentage (over 80% in some configurations) of the water applied to the system. A tracer test has shown that the water velocity in the well is substantially higher than the aquifer. Manometer readings confirm the flowfield effects of the well and these data are being used to calibrate numerical models. The presentation will focus on the observed behavior of the physical model under varying applied head and hydraulic conductivities and discuss the potential design implications for full-scale application.

  18. Bioslurping technology applications at Naval fuel remediation sites

    Energy Technology Data Exchange (ETDEWEB)

    Hoeppel, R.; Goetz, F. [Naval Facilities Engineering Service Center, Port Hueneme, CA (United States); Zwick, T.; Kittel, J. [Battelle Memorial Inst., Columbus, OH (United States); Julio, S.D. [California State Univ., Northridge, CA (United States)

    1996-12-01

    Bioventing accelerates the biodegradation of both high and low volatility fuels immobilized in the vadose zone by satisfying the high oxygen demand of in situ microorganisms through forced aeration of subsurface soils. However, many Naval field sites have light non-aqueous phase liquid (LNAPL) residing at and above the groundwater table. In such cases biodegradation of the LNAPL may be a very slow process because bioemulsification and bioavailability are impeded. Bioslurper systems are designed to recover LNAPL via vacuum-assisted pumping, while simultaneously promoting the remediation of vadose zone soil contamination via bioventing. Bioslurping has been ongoing at NAS Fallon, Nevada, for over three years and was initiated at Marine Corps Base Hawaii last summer. The sites have low volatility JP-5 jet fuel on the groundwater table in low to medium permeability soils. An arid bioventing site at Twentynine Palms, CA, appears to be moisture limited. Subsurface irrigation of the 190 ft vadose zone has increased mixed fuel biodegradation rates about 10-fold but wetting the contaminated zone has been a slow process.

  19. Cost-Effective, Ultra-Sensitive Groundwater Monitoring for Site Remediation and Management

    Science.gov (United States)

    2015-08-01

    research stage, the IS2 is similar in 12 price to other practices and can be expected to improve in cost-effectiveness if brought to market . 13 1.0...M., & Puls, R. W. (1993). Passive sampling of groundwater monitoring wells without purging: multilevel well chemistry and tracer disappearance...sgrp/GWRep10/start.htm. USEPA. (2004). Cleaning Up the Nation’s Waste Sites: Markets and Technology Trends. Washington, DC. Verreydt, G., Bronders

  20. Potential remediation approach for uranium-contaminated groundwaters through potassium uranyl vanadate precipitation

    Energy Technology Data Exchange (ETDEWEB)

    Tokunaga, T.K.; Kim, Y.; Wan, J.

    2009-06-01

    Methods for remediating groundwaters contaminated with uranium (U) through precipitation under oxidizing conditions are needed because bioreduction-based approaches require indefinite supply of electron donor. Although strategies based on precipitation of some phosphate minerals within the (meta)autunite group have been considered for this purpose, thermodynamic calculations for K- and Ca-uranyl phopsphates, meta-ankoleite and autunite, predict that U concentrations will exceed the Maximum Contaminant Level (MCL = 0.13 {micro}M for U) at any pH and pCO{sub 2}, unless phosphate is maintained at much higher concentrations than the sub-{micro}M levels typically found in groundwaters. We hypothesized that potassium uranyl vanadate will control U(VI) concentrations below regulatory levels in slightly acidic to neutral solutions based on thermodynamic data available for carnotite, K{sub 2}(UO{sub 2}){sub 2}V{sub 2}O8. The calculations indicate that maintaining U concentrations below the MCL through precipitation of carnotite will be sustainable in some oxidizing waters having pH in the range of 5.5 to 7, even when dissolution of this solid phase becomes the sole supply of sub-{micro}M levels of V. Batch experiments were conducted in solutions at pH 6.0 and 7.8, chosen because of their very different predicted extents of U(VI) removal. Conditions were identified where U concentrations dropped below its MCL within 1 to 5 days of contact with oxidizing solutions containing 0.2 to 10 mM K, and 0.1 to 20 {micro}M V(V). This method may also have application in extracting (mining) U and V from groundwaters where they both occur at elevated concentrations.

  1. Multi-Objective Optimization with Function Approximation Including Application to Computationally Expensive Groundwater Remediation Design

    Science.gov (United States)

    Akhtar, T.; Shoemaker, C. A.

    2009-12-01

    Water Resources design decisions frequently entail trade-offs between conflicting objectives, for instance cost minimization and contaminant(s) concentration minimization. Multi-objective optimization methods (including those based on evolutionary methods) typically require a very large number of simulations to find a solution. Many groundwater remediation problems are modeled by computationally intensive systems of Partial Differential Equations and simulations. Hence it is desirable that these models are calibrated via algorithms that require less number of simulations. A new strategy called Gap Optimized Multi-Objective Optimization using Response Surfaces (GOMORS) is proposed for multi-objective optimization of computationally expensive problems. A multi-objective management framework is devised to analyze the trade-offs between conflicting objectives. We will present applications to test functions and to a groundwater contamination problem. The pumping rates at different well locations and management periods are the decision variables, and cost and contaminant concentration are the objectives to be minimized. The optimization strategy is iterative and makes use of Radial Basic Functions to develop response surfaces as an approximation of the computationally expensive objectives. A novel method called the Gap Optimization method is introduced. The gap optimization method incorporates use of a multi-objective evolutionary optimization (MOEA) method that is applied to select the next point for expensive evaluation and consequent improvement of the surrogate model. In order to provide sound alternatives to the decision makers, the evaluation point selection procedure strives to ensure that the final trade-off curve generated from the algorithm is close to the true Pareto front and includes a diverse set of solutions. After the final iteration, a set of candidate solutions is selected via the iterative Gap Optimization procedure and the last MOEA iteration, and

  2. Oak Ridge National Laboratory Technology Logic Diagram. Volume 2, Technology Logic Diagram: Part B, Remedial Action

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    The Oak Ridge National Laboratory Technology Logic Diagram (TLD) was developed to provide a decision support tool that relates environmental restoration (ER) and waste management (WM) problems at Oak Ridge National Laboratory (ORNL) to potential technologies that can remediate these problems. The TLD identifies the research, development, demonstration, testing, and evaluation needed to develop these technologies to a state that allows technology transfer and application to decontamination and decommissioning (D&D), remedial action (RA), and WM activities. The TLD consists of three fundamentally separate volumes: Vol. 1 (Technology Evaluation), Vol. 2 (Technology Logic Diagram), and Vol. 3 (Technology Evaluation Data Sheets). Part A of Vols. 1. and 2 focuses on D&D. Part B of Vols. 1 and 2 focuses on the RA of contaminated facilities. Part C of Vols. 1 and 2 focuses on WM. Each part of Vol. 1 contains an overview of the TLD, an explanation of the program-specific responsibilities, a review of identified technologies, and the rankings of remedial technologies. Volume 2 (Pts. A, B, and C) contains the logic linkages among EM goals, environmental problems, and the various technologies that have the potential to solve these problems. Volume 3 (Pts. A, B, and C) contains the TLD data sheets. Remedial action is the focus of Vol. 2, Pt. B, which has been divided into the three necessary subelements of the RA: characterization, RA, and robotics and automation. Each of these sections address general ORNL problems, which are then broken down by problem area/constituents and linked to potential remedial technologies. The diagrams also contain summary information about a technology`s status, its science and technology needs, and its implementation needs.

  3. Contaminant plumes containment and remediation focus area. Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    EM has established a new approach to managing environmental technology research and development in critical areas of interest to DOE. The Contaminant Plumes Containment and Remediation (Plumes) Focus Area is one of five areas targeted to implement the new approach, actively involving representatives from basic research, technology implementation, and regulatory communities in setting objectives and evaluating results. This document presents an overview of current EM activities within the Plumes Focus Area to describe to the appropriate organizations the current thrust of the program and developing input for its future direction. The Plumes Focus Area is developing remediation technologies that address environmental problems associated with certain priority contaminants found at DOE sites, including radionuclides, heavy metals, and dense non-aqueous phase liquids (DNAPLs). Technologies for cleaning up contaminants of concern to both DOE and other federal agencies, such as volatile organic compounds (VOCs), polychlorinated biphenyls (PCBs), and other organics and inorganic compounds, will be developed by leveraging resources in cooperation with industry and interagency programs.

  4. Simulation–optimization model for groundwater contamination remediation using meshfree point collocation method and particle swarm optimization

    Indian Academy of Sciences (India)

    Mategaonkar Meenal; T I Eldho

    2012-06-01

    Remediation of the groundwater contamination problem is a tedious, time consuming and expensive process. Pump and treat (PAT) is one of the commonly used techniques for groundwater remediation in which the contaminated groundwater is pumped, treated and put back to the aquifer system or other sources. Developing simulation-optimization (S/O) model proved to be very useful in the design process of an effective PAT system. Simulation models help in predicting the spatial and temporal variation of the contamination plume while optimization models help in minimizing the cost of pumping. Generally, grid or mesh based models such as Finite Difference Method (FDM) or Finite Element Methods (FEM) is used for the groundwater flow and transport simulation. But it is found that grid/mesh generation is a time consuming process. Therefore, recently Meshfree (MFree) based numerical models are developed to avoid this difficulty of meshing and remeshing. MFree Point Collocation Method (PCM) is a simple meshfree method used for the simulation of coupled groundwater flow and contaminant transport. For groundwater optimization problems, even though number of methods such as linear programming, nonlinear programming, etc. are available, evolutionary algorithm based techniques such as genetic algorithm (GA) and particle swarm optimization (PSO) are found to be very effective. In this paper, a simulation model using MFree PCM for confined groundwater flow and transport and a PSO based single objective optimization model are developed and coupled to get an effective S/O model for groundwater remediation using PAT. The S/O model based on PCM and PSO is applied for a polluted hypothetical confined aquifer and its performance is compared with Finite Element Method–Binary Coded Genetic Algorithm (FEM–GA) model. It is found that both the models are in good agreement with each other showing the applicability of the present approach. The PCM–PSO based S/O model is simple and more

  5. A master-slave parallel hybrid multi-objective evolutionary algorithm for groundwater remediation design under general hydrogeological conditions

    Science.gov (United States)

    Wu, J.; Yang, Y.; Luo, Q.; Wu, J.

    2012-12-01

    This study presents a new hybrid multi-objective evolutionary algorithm, the niched Pareto tabu search combined with a genetic algorithm (NPTSGA), whereby the global search ability of niched Pareto tabu search (NPTS) is improved by the diversification of candidate solutions arose from the evolving nondominated sorting genetic algorithm II (NSGA-II) population. Also, the NPTSGA coupled with the commonly used groundwater flow and transport codes, MODFLOW and MT3DMS, is developed for multi-objective optimal design of groundwater remediation systems. The proposed methodology is then applied to a large-scale field groundwater remediation system for cleanup of large trichloroethylene (TCE) plume at the Massachusetts Military Reservation (MMR) in Cape Cod, Massachusetts. Furthermore, a master-slave (MS) parallelization scheme based on the Message Passing Interface (MPI) is incorporated into the NPTSGA to implement objective function evaluations in distributed processor environment, which can greatly improve the efficiency of the NPTSGA in finding Pareto-optimal solutions to the real-world application. This study shows that the MS parallel NPTSGA in comparison with the original NPTS and NSGA-II can balance the tradeoff between diversity and optimality of solutions during the search process and is an efficient and effective tool for optimizing the multi-objective design of groundwater remediation systems under complicated hydrogeologic conditions.

  6. Possible Applications of Soil Remediation Technologies in Latvia

    Science.gov (United States)

    Burlakovs, Juris; Vircavs, Magnuss

    2011-01-01

    Increasing public concern about deleterious effects of contamination on the environment and human health has led to legislative actions aimed at controlling and regulating the emission of potential contaminants into the environment, but there is still a plethora of territories historically contaminated with different contaminants within the territory of Latvia. The purpose of the present study is to give an overview of the formerly and presently contaminated areas and give some recommendations for remediation. 242 first category contaminated territories (the contamination exceeds the acceptable normative 10 times or more) are mentioned in the National Register of Contaminated Territories, a lot of them are known as contaminated with hazardous contaminants such as heavy metals, oil products, organic compounds and other contaminants in different amounts and concentrations. An overview of soil contamination in Latvia is provided, the planned and recommended research, as well as the planned remediation in pilot case studies, are described, giving a review of the historical contamination situation and of applications of the planned remediation technologies.

  7. Acoustic Cavitation: A Potential Remediation Technology for On-Site Elimination of Perfluorinated Contaminants

    Science.gov (United States)

    Vecitis, C. D.; Cheng, J.; Park, H.; Hoffmann, M. R.

    2006-12-01

    Perfluorinated chemicals are emerging as globally ubiquitous contaminants which are recalcitrant to the conventional remediation techniques of adsorption and chemical oxidation. The release of these chemicals to the environment occurs from specific sites such as manufacturing plants, fire-fighting foams at airports and contaminated landfills. Even though these compounds are widely recognized as potentially hazardous, disposal regulations have been limited due to the ineffectiveness of current pump and treat technologies towards these species. We have shown that ultrasonically induced acoustic cavitation can effectively mineralize aqueous perfluorinated acid and sulfonate species by in situ pyrolysis and chemical oxidation at the lab and pilot scale. Efficiency has been tested on a variety of matrices such as tap water, groundwater and landfill pump-out with VOC content being the major detriment towards remediation. Advanced oxidation by the simultaneously application of ozone and ultrasound seems to partially eliminate this barrier by enhancing the rate of VOC mineralization. Application of this technology to a contaminated field site and the obstacles of scaling to such a degree are discussed.

  8. POSTCLOSURE GROUNDWATER REMEDIATION AND MONITORING AT THE SANITARY LANDFILL, SAVANNAH RIVER SITE TRANSITIONING TO MONITORED NATURAL ATTENUATION

    Energy Technology Data Exchange (ETDEWEB)

    Ross, J; Walt Kubilius, W; Thomas Kmetz, T; D Noffsinger, D; Karen M Adams, K

    2006-11-17

    Resource Conservation and Recovery Act (RCRA) requirements for hazardous waste facilities include 30 years of post-closure monitoring. The use of an objective-based monitoring strategy allows for a significant reduction in the amount of groundwater monitoring required, as the groundwater remediation transitions from an active biosparging system to monitored natural attenuation. The lifecycle of groundwater activities at the landfill has progressed from detection monitoring and plume characterization, to active groundwater remediation, and now to monitored natural attenuation and postclosure monitoring. Thus, the objectives of the groundwater monitoring have changed accordingly. Characterization monitoring evaluated what biogeochemical natural attenuation processes were occurring and determined that elevated levels of radium were naturally occurring. Process monitoring of the biosparging system required comprehensive sampling network up- and down-gradient of the horizontal wells to verify its effectiveness. Currently, the scope of monitoring and reporting can be significantly reduced as the objective is to demonstrate that the alternate concentration limits (ACL) are being met at the point of compliance wells and the maximum contaminant level (MCL) is being met at the surface water point of exposure. The proposed reduction is estimated to save about $2M over the course of the remaining 25 years of postclosure monitoring.

  9. Air-Based Remediation Workshop - Section 8 Air-Based Remediation Technology Selection Logic

    Science.gov (United States)

    Pursuant to the EPA-AIT Implementing Arrangement 7 for Technical Environmental Collaboration, Activity 11 "Remediation of Contaminated Sites," the USEPA Office of International Affairs Organized a Forced Air Remediation Workshop in Taipei to deliver expert training to the Environ...

  10. Implications of Fe/Pd Bimetallic Nanoparticles Immobilized on Adsorptive Activated Carbon for the Remediation of Groundwater and Sediment Contaminated with PCBs

    Science.gov (United States)

    In order to respond to the current limitations and challenges in remediating groundwater and sediment contaminated with polychlorinated biphenyls (PCBs), we have recently developed a new strategy, integration of the physical adsorption of PCBs with their electrochemical dechlori...

  11. Implications of Fe/Pd Bimetallic Nanoparticles Immobilized on Adsorptive Activated Carbon for the Remediation of Groundwater and Sediment Contaminated with PCBs

    Science.gov (United States)

    In order to respond to the current limitations and challenges in remediating groundwater and sediment contaminated with polychlorinated biphenyls (PCBs), we have recently developed a new strategy, integration of the physical adsorption of PCBs with their electrochemical dechlori...

  12. Assessing Environmental Sustainability of Remediation Technologies in a Life Cycle Perspective is Not So Easy

    DEFF Research Database (Denmark)

    Owsianiak, Mikolaj; Lemming, Gitte; Hauschild, Michael Zwicky

    2013-01-01

    Integrating sustainability into remediation projects has attracted attention from remediation practitioners, and life cycle assessment (LCA) is becoming a popular tool to address the environmental dimension. The total number of studies has reached 31 since the first framework for LCA of site...... about the environmental sustainability of remediation technologies....

  13. ICS-UNIDO - Promoting sustainable POPs disposal and remediation technologies

    Energy Technology Data Exchange (ETDEWEB)

    Zinovyev, S.; Lodolo, A.; Miertus, S. [ICS-UNIDO, Trieste (Italy)

    2004-09-15

    It is well known that a significant stock of polychlorinated hazards, including POP and PTS, has been produced and is stored nowadays or dispersed in the environment in many of Developing Countries and Countries with Economies in Transition. The obsolete industrial processes, giving rise to formation of dioxins, as well as former/current POP production/use (e.g. PCBs), coupled with uncontrolled use of polychlorinated pesticides in agriculture and improper storage of POP stockpiles have rendered vast territories in these countries highly contaminated and raised urgent issues of disposal of hazards and remediation of territories. The International Centre for Science and High Technology (ICS), www.ics.trieste.it, is an autonomous institution within the legal framework of the United Nations Industrial Development Organization (UNIDO) promoting a global programme on environmental protection, sustainable chemistry, catalysis, and clean technologies. An important part of its work programme is focused on the promotion of new technologies which can be helpful for the reduction of the formation of POPs (like dioxins and furans) in incineration processes and in obsolete technologies used in some industrial processes. Another hot issue is to promote safe technologies for the destruction of PCBs and polychlorinated pesticides. Particular efforts of ICS-UNIDO are directed towards the transfer of clean technologies to developing/transition countries. ICS-UNIDO, through its initiatives, seeks to establish a dialogue with local administrative, research, NGO, and industrial bodies in order to adopt sustainable technologies for POP disposal and management of contaminated sites.

  14. ELECTROCHEMICAL REMEDIATION OF ARSENIC-CONTAMINATED GROUNDWATER — RESULTS OF PROTOTYPE FIELD TESTS IN BANGLADESH

    Energy Technology Data Exchange (ETDEWEB)

    Kowolik, K; Addy, S.E.A.; Gadgil, A.

    2009-01-01

    According to the World Health Organization (WHO), more than 50 million people in Bangladesh drink arsenic-laden water, making it the largest case of mass poisoning in human history. Many methods of arsenic removal (mostly using chemical adsorbents) have been studied, but most of these are too expensive and impractical to be implemented in poor countries such as Bangladesh. This project investigates ElectroChemical Arsenic Remediation (ECAR) as an affordable means of removing arsenic. Experiments were performed on site in Bangladesh using a prototype termed “sushi”. This device consists of carbon steel sheets that serve as electrodes wrapped into a cylinder, separated by plastic mesh and surrounded by a tube-like container that serves as a holding cell in which the water is treated electrochemically. During the electrochemical process, current is applied to both electrodes causing iron to oxidize to various forms of iron (hydr)oxides. These species bind to arsenic(V) with very high affi nity. ECAR also has the advantage that As(III), the more toxic form of arsenic, oxidizes to As(V) in situ. Only As(V) is known to complex with iron (hydr)oxides. One of the main objectives of this research is to demonstrate the ability of the new prototype to reduce arsenic concentrations in Bangladesh groundwater from >200 ppb to below the WHO limit of 10 ppb. In addition, varying fl ow rate and dosage and the effect on arsenic removal was investigated. Experiments showed that ECAR reduced Bangladeshi water with an initial arsenic concentration as high as 250 ppb to below 10 ppb. ECAR proved to be effective at dosages as high as 810 Coulombs/Liter (C/L) and as low as 386 C/L (current 1 A, voltage 12 V). These results are encouraging and provide great promise that ECAR is an effi cient method in the remediation of arsenic from contaminated groundwater. A preliminary investigation of arsenic removal trends with varying Coulombic dosage, complexation time and fi ltration methods is

  15. Optimization of Remediation Conditions using Vadose Zone Monitoring Technology

    Science.gov (United States)

    Dahan, O.; Mandelbaum, R.; Ronen, Z.

    2010-12-01

    Success of in-situ bio-remediation of the vadose zone depends mainly on the ability to change and control hydrological, physical and chemical conditions of subsurface. These manipulations enables the development of specific, indigenous, pollutants degrading bacteria or set the environmental conditions for seeded bacteria. As such, the remediation efficiency is dependent on the ability to implement optimal hydraulic and chemical conditions in deep sections of the vadose zone. Enhanced bioremediation of the vadose zone is achieved under field conditions through infiltration of water enriched with chemical additives. Yet, water percolation and solute transport in unsaturated conditions is a complex process and application of water with specific chemical conditions near land surface dose not necessarily result in promoting of desired chemical and hydraulic conditions in deeper sections of the vadose zone. A newly developed vadose-zone monitoring system (VMS) allows continuous monitoring of the hydrological and chemical properties of the percolating water along deep sections of the vadose zone. Implementation of the VMS at sites that undergoes active remediation provides real time information on the chemical and hydrological conditions in the vadose zone as the remediation process progresses. Manipulating subsurface conditions for optimal biodegradation of hydrocarbons is demonstrated through enhanced bio-remediation of the vadose zone at a site that has been contaminated with gasoline products in Tel Aviv. The vadose zone at the site is composed of 6 m clay layer overlying a sandy formation extending to the water table at depth of 20 m bls. The upper 5 m of contaminated soil were removed for ex-situ treatment, and the remaining 15 m vadose zone is treated in-situ through enhanced bioremedaition. Underground drip irrigation system was installed below the surface on the bottom of the excavation. Oxygen and nutrients releasing powder (EHCO, Adventus) was spread below the

  16. Network environmental analysis based ecological risk assessment of a naphthalene-contaminated groundwater ecosystem under varying remedial schemes

    Science.gov (United States)

    Wang, Zheng; He, Li; Lu, Hongwei; Ren, Lixia; Xu, Zongda

    2016-12-01

    Many of the existing ecological risk studies for groundwater ecosystems paid little attention to either small-scale regions (e.g., an industrial contamination site) or ignored anthropogenic activities (e.g., site remediation). This study presented a network environmental analysis based ecological risk assessment (ERA) framework to a naphthalene-contaminated groundwater remediation site. In the ERA, four components (vegetation, herbivore, soil micro-organism and carnivore) were selected, which are directly or indirectly exposed to the contaminated groundwater ecosystem. By incorporating both direct and indirect ecosystem interactions, the risk conditions of the whole ecosystem and its components were quantified and illustrated in the case study. Results indicate that despite there being no input risks for herbivores and carnivores, the respective integral risks increase to 0.0492 and 0.0410. For soil micro-organisms, 58.8% of the integral risk comes from the input risk, while the other 41.2% of the integral risk comes from the direct risk. Therefore, the risk flow within the components is a non-negligible risk origination for soil micro-organisms. However, the integral risk for vegetation was similar to the input risk, indicating no direct risk. The integral risk at the 5-year point after remediation was the highest for the four components. This risk then decreased at the 10-year point, and then again increased. Results from the sensitivity analysis also suggest that the proposed framework is robust enough to avoid disturbance by parameter uncertainty.

  17. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation.

    Science.gov (United States)

    De Biase, Cecilia; Carminati, Andrea; Oswald, Sascha E; Thullner, Martin

    2013-11-01

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile losses to the atmosphere. Especially for (potentially) toxic VOCs, the latter needs to be minimized to limit atmospheric emissions. In this study, numerical simulation was used to investigate quantitatively the removal of volatile organic compounds in two pilot-scale water treatment systems: an unplanted vertical flow filter and a planted one, which could also be called a vertical flow constructed wetland, both used for the treatment of contaminated groundwater. These systems were intermittently loaded with contaminated water containing benzene and MTBE as main VOCs. The highly dynamic but permanently unsaturated conditions in the porous medium facilitated aerobic biodegradation but could lead to volatile emissions of the contaminants. Experimental data from porous material analyses, flow rate measurements, solute tracer and gas tracer test, as well as contaminant concentration measurements at the boundaries of the systems were used to constrain a numerical reactive transport modeling approach. Numerical simulations considered unsaturated water flow, transport of species in the aqueous and the gas phase as well as aerobic degradation processes, which made it possible to quantify the rates of biodegradation and volatile emissions and calculating their contribution to total contaminant removal. A range of degradation rates was determined using experimental results of both systems under two operation modes and validated by field data obtained at different operation modes applied to the filters. For both filters, simulations and experimental data point to high biodegradation rates, if the flow filters have had time to build up their removal capacity. For this case volatile

  18. SAFETY IMPROVES DRAMATICALLY IN FLUOR HANFORD SOIL AND GROUNDWATER REMEDIATION PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    GERBER MS

    2007-12-05

    This paper describes dramatic improvements in the safety record of the Soil and Groundwater Remediation Project (SGRP) at the Hanford Site in southeast Washington state over the past four years. During a period of enormous growth in project work and scope, contractor Fluor Hanford reduced injuries, accidents, and other safety-related incidents and enhanced a safety culture that earned the SGRP Star Status in the Department of Energy's (DOE's) Voluntary Protection Program (VPP) in 2007. This paper outlines the complex and multi-faceted work of Fluor Hanford's SGRP and details the steps taken by the project's Field Operations and Safety organizations to improve safety. Holding field safety meetings and walkdowns, broadening safety inspections, organizing employee safety councils, intensively flowing down safety requirements to subcontractors, and adopting other methods to achieve remarkable improvement in safety are discussed. The roles of management, labor and subcontractors are detailed. Finally, SGRP's safety improvements are discussed within the context of overall safety enhancements made by Fluor Hanford in the company's 11 years of managing nuclear waste cleanup at the Hanford Site.

  19. Necessary and Sufficient Standards Closure Process pilot: F- and H-Area groundwater remediation

    Energy Technology Data Exchange (ETDEWEB)

    Bullington, M.

    1995-09-25

    The DOE Standards Committee`s Necessary and Sufficient (N and S) Standards Closure Process was piloted at SRS on the F- and H- Area Seepage Basins Groundwater Remediation Project. For this existing Environmental Restoration project, the set of N and S standards for design and safety documentation were identified, independently confirmed and approved. Implementation of these standards on the project can lead to a $2.8 Million cost savings on the design, construction/installation, and safety documentation scope of $18 Million. These savings were primarily from site design of power distribution and piping for the water treatment units. Also contributing to the savings were a more appropriate level of safety documentation and the alternate ``commercial`` bids made by vendors in response to a request for proposals for water treatment units. The use of the N and S Process on an ER activity, details on the cost savings, lessons learned and recommendations for broader implementation of the N and S Process are described herein.

  20. Assessment of Carbon Tetrachloride Groundwater Transport in Support of the Hanford Carbon Tetrachloride Innovative Technology Demonstration Program

    Energy Technology Data Exchange (ETDEWEB)

    Truex, Michael J.; Murray, Christopher J.; Cole, Charles R.; Cameron, Richard J.; Johnson, Michael D.; Skeen, Rodney S.; Johnson, Christian D.

    2001-07-13

    Groundwater modeling was performed in support of the Hanford Carbon Tetrachloride Innovative Treatment Remediation Demonstration (ITRD) Program. The ITRD program is facilitated by Sandia National Laboratory for the Department of Energy Office of Science and Technology. This report was prepared to document the results of the modeling effort and facilitate discussion of characterization and remediation options for the carbon tetrachloride plume among the ITRD participants. As a first step toward implementation of innovative technologies for remediation of the carbon tetrachloride (CT) plume underlying the 200-West Area, this modeling was performed to provide an indication of the potential impact of the CT source on the compliance boundary approximately 5000 m distant. The primary results of the modeling bracket the amount of CT source that will most likely result in compliance/non-compliance at the boundary and the relative influence of the various modeling parameters.

  1. ANNUAL REPORT FOR THE FINAL GROUNDWATER REMEDIATION, TEST AREA NORTH, OPERABLE UNIT 1-07B, FISCAL YEAR 2009

    Energy Technology Data Exchange (ETDEWEB)

    FORSYTHE, HOWARD S

    2010-04-14

    This Annual Report presents the data and evaluates the progress of the three-component remedy implemented for remediation of groundwater contamination at Test Area North, Operable Unit 1-07B, at the Idaho National Laboratory Site. Overall, each component is achieving progress toward the goal of total plume remediation. In situ bioremediation operations in the hot spot continue to operate as planned. Progress toward the remedy objectives is being made, as evidenced by continued reduction in the amount of accessible residual source and decreases in downgradient contaminant flux, with the exception of TAN-28. The injection strategy is maintaining effective anaerobic reductive dechlorination conditions, as evidenced by complete degradation of trichloroethene and ethene production in the biologically active wells. In the medial zone, the New Pump and Treat Facility operated in standby mode. Trichloroethene concentrations in the medial zone wells are significantly lower than the historically defined concentration range of 1,000 to 20,000 μg/L. The trichloroethene concentrations in TAN-33, TAN-36, and TAN-44 continue to be below 200 μg/L. Monitoring in the distal zone wells outside and downgradient of the plume boundary demonstrate that some plume expansion has occurred, but less than the amount allowed in the Record of Decision Amendment. Additional data need to be collected for wells in the monitored natural attenuation part of the plume to confirm that the monitored natural attenuation part of the remedy is proceeding as predicted in the modeling.

  2. Method for screening prevention and control measures and technologies based on groundwater pollution intensity assessment.

    Science.gov (United States)

    Li, Juan; Yang, Yang; Huan, Huan; Li, Mingxiao; Xi, Beidou; Lv, Ningqing; Wu, Yi; Xie, Yiwen; Li, Xiang; Yang, Jinjin

    2016-05-01

    This paper presents a system for determining the evaluation and gradation indices of groundwater pollution intensity (GPI). Considering the characteristics of the vadose zone and pollution sources, the system decides which anti-seepage measures should be implemented at the contaminated site. The pollution sources hazards (PSH) and groundwater intrinsic vulnerability (GIV) are graded by the revised Nemerow Pollution Index and an improved DRTAS model, respectively. GPI is evaluated and graded by a double-sided multi-factor coupling model, which is constructed by the matrix method. The contaminated sites are categorized as prior, ordinary, or common sites. From the GPI results, we develop guiding principles for preventing and removing pollution sources, procedural interruption and remediation, and end treatment and monitoring. Thus, we can select appropriate prevention and control technologies (PCT). To screen the technological schemes and optimize the traditional analytical hierarchy process (AHP), we adopt the technique for order preference by the similarity to ideal solution (TOPSIS) method. Our GPI approach and PCT screening are applied to three types of pollution sites: the refuse dump of a rare earth mine development project (a potential pollution source), a chromium slag dump, and a landfill (existing pollution sources). These three sites are identified as ordinary, prior, and ordinary sites, respectively. The anti-seepage materials at the refuse dump should perform as effectively as a 1.5-m-thick clay bed. The chromium slag dump should be preferentially treated by soil flushing and in situ chemical remediation. The landfill should be treated by natural attenuation technology. The proposed PCT screening approach was compared with conventional screening methods results at the three sites and proved feasible and effective. The proposed method can provide technical support for the monitoring and management of groundwater pollution in China. Copyright © 2015

  3. [Groundwater organic pollution source identification technology system research and application].

    Science.gov (United States)

    Wang, Xiao-Hong; Wei, Jia-Hua; Cheng, Zhi-Neng; Liu, Pei-Bin; Ji, Yi-Qun; Zhang, Gan

    2013-02-01

    Groundwater organic pollutions are found in large amount of locations, and the pollutions are widely spread once onset; which is hard to identify and control. The key process to control and govern groundwater pollution is how to control the sources of pollution and reduce the danger to groundwater. This paper introduced typical contaminated sites as an example; then carried out the source identification studies and established groundwater organic pollution source identification system, finally applied the system to the identification of typical contaminated sites. First, grasp the basis of the contaminated sites of geological and hydrogeological conditions; determine the contaminated sites characteristics of pollutants as carbon tetrachloride, from the large numbers of groundwater analysis and test data; then find the solute transport model of contaminated sites and compound-specific isotope techniques. At last, through groundwater solute transport model and compound-specific isotope technology, determine the distribution of the typical site of organic sources of pollution and pollution status; invest identified potential sources of pollution and sample the soil to analysis. It turns out that the results of two identified historical pollution sources and pollutant concentration distribution are reliable. The results provided the basis for treatment of groundwater pollution.

  4. Study on Obstacles to Continuous Cropping of Vegetables and Soil Remediation Technology

    Institute of Scientific and Technical Information of China (English)

    Pingsheng FAN; Gang CHEN; Deli XU; Weimin FENG; Yuyu LU; Anqin GUAN

    2016-01-01

    Firstly,this paper analyzes the cause of obstacles to continuous cropping of vegetables,and then introduces the soil ecological remediation technology used for overcoming obstacles to continuous cropping of vegetables. Finally,this paper analyzes the effect of applying soil ecological remediation technology in overcoming obstacles to continuous cropping of vegetables.

  5. Development Of A New Redox-Active Porous Material For Groundwater Remediation

    Science.gov (United States)

    Zhuang, Y.; White, M.; Fialips, C. I.

    2008-12-01

    Laboratory experiments have shown that reducing iron in smectites promotes the degradation of various redox sensitive organics, including nitroaromatics and chlorinated compounds. Fe-bearing smectites have however never been used in the design of permeable reactive barriers (PRBs) for groundwater remediation. One basic requirement when designing PRBs is to keep their permeability equal to or higher than that of the surrounding aquifer materials to avoid affecting groundwater flow. Smectite clays are very low permeability materials and, when physically mixed with permeable materials, such as sand, clay particles can migrate and clog up pores, resulting in a progressive loss in permeability. In this study, we are developing a novel Fe-bearing clay-material suitable for permeable water treatment systems, including PRBs. Fe-smectite particles are tightly attached to the surface of sand grains using polyvinyl alcohol (PVA). To identify optimum procedures, we are studying the relationships between the size and texture of the sand grains, the clay/PVA and clay/sand ratio, the quality and extent of clay coverage, the stability of the clay-coated sand to changes in pH and redox conditions, and its hydraulic properties before and after iron reduction. The best clay coatings have been obtained using the most angular sands with rough surfaces and medium grain sizes (0.3-0.6mm). An optimum coating of 61.5 mg clay/g sand was obtained using the nontronite Nau- 2. The clay-coated sand is stable when pH is below 7 (no detachment of the clay particles). For pH higher than 7, a maximum of 14% of the clay-coating is detaching when the sample is not disturbed, and 28% if shaken. XRD analyses of the clay-coated sand also show that the coated smectite retains its swelling properties (d-spacing at 17.1Å after ethylene glycol treatment). The clay-coated sand is also stable to changes in redox conditions, with less than 15% detachment after 4h of treatment with sodium dithionite at 25

  6. Tank waste remediation system integrated technology plan. Revision 2

    Energy Technology Data Exchange (ETDEWEB)

    Eaton, B.; Ignatov, A.; Johnson, S.; Mann, M.; Morasch, L.; Ortiz, S.; Novak, P. [eds.] [Pacific Northwest Lab., Richland, WA (United States)

    1995-02-28

    The Hanford Site, located in southeastern Washington State, is operated by the US Department of Energy (DOE) and its contractors. Starting in 1943, Hanford supported fabrication of reactor fuel elements, operation of production reactors, processing of irradiated fuel to separate and extract plutonium and uranium, and preparation of plutonium metal. Processes used to recover plutonium and uranium from irradiated fuel and to recover radionuclides from tank waste, plus miscellaneous sources resulted in the legacy of approximately 227,000 m{sup 3} (60 million gallons) of high-level radioactive waste, currently in storage. This waste is currently stored in 177 large underground storage tanks, 28 of which have two steel walls and are called double-shell tanks (DSTs) an 149 of which are called single-shell tanks (SSTs). Much of the high-heat-emitting nuclides (strontium-90 and cesium-137) has been extracted from the tank waste, converted to solid, and placed in capsules, most of which are stored onsite in water-filled basins. DOE established the Tank Waste Remediation System (TWRS) program in 1991. The TWRS program mission is to store, treat, immobilize and dispose, or prepare for disposal, the Hanford tank waste in an environmentally sound, safe, and cost-effective manner. Technology will need to be developed or improved to meet the TWRS program mission. The Integrated Technology Plan (ITP) is the high-level consensus plan that documents all TWRS technology activities for the life of the program.

  7. Method for screening prevention and control measures and technologies based on groundwater pollution intensity assessment

    Energy Technology Data Exchange (ETDEWEB)

    Li, Juan, E-mail: lijuan@craes.org.cn [College of Water Sciences, Beijing Normal University, Beijing 100875 (China); Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Beijing, 100012 (China); Yang, Yang [College of Environment, Beijing Normal University, Beijing 100875 (China); Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Beijing, 100012 (China); Huan, Huan; Li, Mingxiao [Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Beijing, 100012 (China); Xi, Beidou, E-mail: xibd413@yeah.net [Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Beijing, 100012 (China); Lanzhou Jiaotong University, Lanzhou 730070 (China); Lv, Ningqing [Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Beijing, 100012 (China); Wu, Yi [Guizhou Academy of Environmental Science and Designing, Guizhou 550000 (China); Xie, Yiwen, E-mail: qin3201@126.com [School of Chemical and Environmental Engineering, Dongguan University of Technology, Dongguan, 523808 (China); Li, Xiang; Yang, Jinjin [Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Beijing, 100012 (China)

    2016-05-01

    This paper presents a system for determining the evaluation and gradation indices of groundwater pollution intensity (GPI). Considering the characteristics of the vadose zone and pollution sources, the system decides which anti-seepage measures should be implemented at the contaminated site. The pollution sources hazards (PSH) and groundwater intrinsic vulnerability (GIV) are graded by the revised Nemerow Pollution Index and an improved DRTAS model, respectively. GPI is evaluated and graded by a double-sided multi-factor coupling model, which is constructed by the matrix method. The contaminated sites are categorized as prior, ordinary, or common sites. From the GPI results, we develop guiding principles for preventing and removing pollution sources, procedural interruption and remediation, and end treatment and monitoring. Thus, we can select appropriate prevention and control technologies (PCT). To screen the technological schemes and optimize the traditional analytical hierarchy process (AHP), we adopt the technique for order preference by the similarity to ideal solution (TOPSIS) method. Our GPI approach and PCT screening are applied to three types of pollution sites: the refuse dump of a rare earth mine development project (a potential pollution source), a chromium slag dump, and a landfill (existing pollution sources). These three sites are identified as ordinary, prior, and ordinary sites, respectively. The anti-seepage materials at the refuse dump should perform as effectively as a 1.5-m-thick clay bed. The chromium slag dump should be preferentially treated by soil flushing and in situ chemical remediation. The landfill should be treated by natural attenuation technology. The proposed PCT screening approach was compared with conventional screening methods results at the three sites and proved feasible and effective. The proposed method can provide technical support for the monitoring and management of groundwater pollution in China. - Highlights: • An

  8. Natural Oxidant Demand Variability, Potential Controls, and Implications for in Situ, Oxidation-Based Remediation of Contaminated Groundwater

    Science.gov (United States)

    Dettmer, A.; Cruz, S.; Dungan, B.; Holguin, F. O.; Ulery, A. L.; Hunter, B.; Carroll, K. C.

    2014-12-01

    Naturally occurring reduced species associated with subsurface materials can impose a significant natural oxidant demand (NOD), which is the bulk consumption of oxidants by soil water, minerals, and organic matter. Although injection of oxidants has been used for chemical transformation of organic contaminants, NOD represents a challenge for the in-situ delivery of oxidants as a remediation alternative. Co-injection of complexation agents with oxidants has been proposed to facilitate the delivery of oxidants for in situ chemical oxidation remediation of contaminated groundwater. This study investigates variability of NOD for different oxidants and sediments. The effect of the addition of various complexation agents, including EDTA, tween 80, hydroxypropyl-beta-cyclodextrin (HPCD), humic acid, and four generations of poly(amidoamine) (PAMAM) dendrimers, on the NOD was also examined. NOD was measured for a clay loam (collected from Air Force Plant 44 in Tucson, AZ). Varying amounts of biosolids were mixed with subsamples of the clay loam to create three additional reference soils in order to study the effect of organic matter and other soil characteristics on the NOD. Bench-scale laboratory experiments were conducted to determine the NOD for various oxidants, using the four soils, and replicated with and without various delivery agents. Measured NOD showed variability for each soil and oxidant composition. Additionally, significant differences were observed in NOD with the addition of delivery agents. The results support the elucidation of potential controls over NOD and have implications for in situ, oxidation-based remediation of contaminated groundwater.

  9. Remedial investigation work plan for the Groundwater Operable Unit at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-01

    This Remedial Investigation (RI) Work Plan has been developed as part of the US Department of Energy`s (DOE`s) investigation of the Groundwater Operable Unit (GWOU) at Oak Ridge National Laboratory (ORNL) located near Oak Ridge, Tennessee. The first iteration of the GWOU RI Work Plan is intended to serve as a strategy document to guide the ORNL GWOU RI. The Work Plan provides a rationale and organization for groundwater data acquisition, monitoring, and remedial actions to be performed during implementation of environmental restoration activities associated with the ORNL GWOU. It Is important to note that the RI Work Plan for the ORNL GWOU is not a prototypical work plan. The RI will be conducted using annual work plans to manage the work activities, and task reports will be used to document the results of the investigations. Sampling and analysis results will be compiled and reported annually with a review of data relative to risk (screening level risk assessment review) for groundwater. This Work Plan outlines the overall strategy for the RI and defines tasks which are to be conducted during the initial phase of investigation. This plan is presented with the understanding that more specific addenda to the plan will follow.

  10. Using radon-222 as indicator for the evaluation of the efficiency of groundwater remediation by in situ air sparging.

    Science.gov (United States)

    Schubert, Michael; Schmidt, Axel; Müller, Kai; Weiss, Holger

    2011-02-01

    A common approach for remediation of groundwater contamination with volatile organic compounds (VOCs) is contaminant stripping by means of in situ air sparging (IAS). For VOC stripping, pressurized air is injected into the contaminated groundwater volume, followed by the extraction of the contaminant-loaded exhaust gas from the vadose soil zone and its immediate on-site treatment. Progress assessment of such remediation measure necessitates information (i) on the spatial range of the IAS influence and (ii) on temporal variations of the IAS efficiency. In the present study it was shown that the naturally occurring noble gas radon can be used as suitable environmental tracer for achieving the related spatial and temporal information. Due to the distinct water/air partitioning behaviour of radon and due to its straightforward on-site detectability, the radon distribution pattern in the groundwater can be used as appropriate measure for assessing the progression of an IAS measure as a function of space and time. The presented paper discusses both the theoretical background of the approach and the results of an IAS treatment accomplished at a VOC contaminated site lasting six months, during which radon was applied as efficiency indicator.

  11. Decontamination Technologies, Task 3, Urban Remediation and Response Project

    Energy Technology Data Exchange (ETDEWEB)

    Heiser,J.; Sullivan, T.

    2009-06-30

    In the aftermath of a Radiological Dispersal Device (RDD, also known as a dirty bomb) it will be necessary to remediate the site including building exteriors and interiors, equipment, pavement, vehicles, personal items etc. Remediation will remove or reduce radioactive contamination from the area using a combination of removing and disposing of many assets (including possible demolition of buildings), decontaminating and returning to service other assets, and fixing in place or leaving in place contamination that is deemed 'acceptable'. The later will require setting acceptable dose standards, which will require negotiation with all involved parties and a balance of risk and cost to benefit. To accomplish the first two, disposal or decontamination, a combination of technologies will be deployed that can be loosely classified as: Decontamination; Equipment removal and size reduction; and Demolition. This report will deal only with the decontamination technologies that will be used to return assets to service or to reduce waste disposal. It will not discuss demolition, size reduction or removal technologies or equipment (e.g., backhoe mounted rams, rock splitter, paving breakers and chipping hammers, etc.). As defined by the DOE (1994), decontamination is removal of radiological contamination from the surfaces of facilities and equipment. Expertise in this field comes primarily from the operation and decommissioning of DOE and commercial nuclear facilities as well as a small amount of ongoing research and development closely related to RDD decontamination. Information related to decontamination of fields, buildings, and public spaces resulting from the Goiania and Chernobyl incidents were also reviewed and provide some meaningful insight into decontamination at major urban areas. In order to proceed with decontamination, the item being processed needs to have an intrinsic value that exceeds the cost of the cleaning and justifies the exposure of any workers

  12. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    Energy Technology Data Exchange (ETDEWEB)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  13. Y-12 Plant remedial action Technology Logic Diagram: Volume 3, Technology evaluation data sheets: Part B, Characterization; robotics/automation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-09-01

    The Y-12 Plant Remedial Action Technology Logic Diagram (TLD) was developed to provide a decision-support tool that relates environmental restoration (ER) problems at the Y-12 Plant to potential technologies that can remediate theses problems. The TLD identifies the research, development, demonstration, testing, and evaluation needed for sufficient development of these technologies to allow for technology transfer and application to remedial action (RA) activities. The TLD consists of three volumes. Volume 1 contains an overview of the TLD, an explanation of the program-specific responsibilities, a review of identified technologies, and the rankings of remedial technologies. Volume 2 contains the logic linkages among environmental management goals, environmental problems, and the various technologies that have the potential to solve these problems. Volume 3 contains the TLD data sheets. This report is Part B of Volume 3 and contains the Characterization and Robotics/Automation sections.

  14. Oxygen Release Materials for Petroleum- Contaminated Groundwater Remediation%释氧材料修复地下水石油烃污染研究进展

    Institute of Scientific and Technical Information of China (English)

    张锁雷; 邓皓; 李月华

    2012-01-01

    石油烃对土壤和地下水的污染不断被重视,释氧材料作为一种强化生物修复技术正日益受到关注.文章介绍了释氧材料的发展史,阐述修复场地条件、地下水化学环境和材料释氧速率控制对修复效果的影响,并对该技术的发展进行了展望.%Petroleum hydrocarbon pollutions to soil and groundwater catch increasing attention and oxygen release materials as an enhanced bioremediation technology are a growing concern. This paper introduces the history of oxygen release materials and discusses the repair site conditions and the influence of groundwater chemical environment and the control of material oxygen release rate on the remediation effect. Moreover, it prospects the development of the technology.

  15. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    Energy Technology Data Exchange (ETDEWEB)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  16. [Research on the Screening Method of Soil Remediation Technology at Contaminated Sites and Its Application].

    Science.gov (United States)

    Bai, Li-ping; Luo, Yun; Liu, Li; Zhou, You-ya; Yan, Zeng-guang; Li, Fa-sheng

    2015-11-01

    Soil remediation technology screening is an important procedure in the supervision of contaminated sites. The efficiency and costs of contaminated site remediation will be directly affected by the applicability of soil remediation technology. The influencing factors include characteristics of contaminants, site conditions, remediation time and costs should be considered to determine the most applicable remediation technology. The remediation technology screening was commonly evaluated by the experienced expert in China, which limited the promotion and application of the decision making method. Based on the supervision requirements of contaminated sites and the research status at home and abroad, the screening method includes preliminary screening and explicit evaluation was suggested in this paper. The screening index system was constructed, and the extension theory was used to divide the technology grade. The extension theory could solve the problem of human interference in the evaluation process and index value assignment. A chromium residue contaminated site in China was selected as the study area, and the applicable remediation technologies were suggested by the screening method. The research results could provide a scientific and technological support for the supervision and management of contaminated sites in China.

  17. A comprehensive guide of remediation technologies for oil contaminated soil - Present works and future directions.

    Science.gov (United States)

    Lim, Mee Wei; Lau, Ee Von; Poh, Phaik Eong

    2016-08-15

    Oil spills result in negative impacts on the environment, economy and society. Due to tidal and waves actions, the oil spillage affects the shorelines by adhering to the soil, making it difficult for immediate cleaning of the soil. As shoreline clean-up is the most costly component of a response operation, there is a need for effective oil remediation technologies. This paper provides a review on the remediation technologies for soil contaminated with various types of oil, including diesel, crude oil, petroleum, lubricating oil, bitumen and bunker oil. The methods discussed include solvent extraction, bioremediation, phytoremediation, chemical oxidation, electrokinetic remediation, thermal technologies, ultrasonication, flotation and integrated remediation technologies. Each of these technologies was discussed, and associated with their advantages, disadvantages, advancements and future work in detail. Nonetheless, it is important to note that no single remediation technology is considered the best solution for the remediation of oil contaminated soil. This review provides a comprehensive literature on the various remediation technologies studied in the removal of different oil types from soil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Horizontal directional drilling: a green and sustainable technology for site remediation.

    Science.gov (United States)

    Lubrecht, Michael D

    2012-03-06

    Sustainability has become an important factor in the selection of remedies to clean up contaminated sites. Horizontal directional drilling (HDD) is a relatively new drilling technology that has been successfully adapted to site remediation. In addition to the benefits that HDD provides for the logistics of site cleanup, it also delivers sustainability advantages, compared to alternative construction methods.

  19. Grand challenge problems in environmental modeling and remediation: Groundwater contaminant transport. Final project report 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-04-01

    The over-reaching goal of the Groundwater Grand Challenge component of the Partnership in Computational Science (PICS) was to develop and establish the massively parallel approach for the description of groundwater flow and transport and to address the problem of uncertainties in the data and its interpretation. This necessitated the development of innovative algorithms and the implementation of massively parallel computational tools to provide a suite of simulators for groundwater flow and transport in heterogeneous media. This report summarizes the activities and deliverables of the Groundwater Grand Challenge project funded through the High Performance Computing grand challenge program of the Department of Energy from 1995 through 1997.

  20. On-site and in situ remediation technologies applicable to petroleum hydrocarbon contaminated sites in the Antarctic and Arctic

    Directory of Open Access Journals (Sweden)

    Danielle Camenzuli

    2015-09-01

    Full Text Available Petroleum hydrocarbon contaminated sites, associated with the contemporary and legacy effects of human activities, remain a serious environmental problem in the Antarctic and Arctic. The management of contaminated sites in these regions is often confounded by the logistical, environmental, legislative and financial challenges associated with operating in polar environments. In response to the need for efficient and safe methods for managing contaminated sites, several technologies have been adapted for on-site or in situ application in these regions. This article reviews six technologies which are currently being adapted or developed for the remediation of petroleum hydrocarbon contaminated sites in the Antarctic and Arctic. Bioremediation, landfarming, biopiles, phytoremediation, electrokinetic remediation and permeable reactive barriers are reviewed and discussed with respect to their advantages, limitations and potential for the long-term management of soil and groundwater contaminated with petroleum hydrocarbons in the Antarctic and Arctic. Although these technologies demonstrate potential for application in the Antarctic and Arctic, their effectiveness is dependent on site-specific factors including terrain, soil moisture and temperature, freeze–thaw processes and the indigenous microbial population. The importance of detailed site assessment prior to on-site or in situ implementation is emphasized, and it is argued that coupling of technologies represents one strategy for effective, long-term management of petroleum hydrocarbon contaminated sites in the Antarctic and Arctic.

  1. Sustainable exposure prevention through innovative detection and remediation technologies from the NIEHS Superfund Research Program.

    Science.gov (United States)

    Henry, Heather F; Suk, William A

    2017-03-01

    Innovative devices and tools for exposure assessment and remediation play an integral role in preventing exposure to hazardous substances. New solutions for detecting and remediating organic, inorganic, and mixtures of contaminants can improve public health as a means of primary prevention. Using a public health prevention model, detection and remediation technologies contribute to primary prevention as tools to identify areas of high risk (e.g. contamination hotspots), to recognize hazards (bioassay tests), and to prevent exposure through contaminant cleanups. Primary prevention success is ultimately governed by the widespread acceptance of the prevention tool. And, in like fashion, detection and remediation technologies must convey technical and sustainability advantages to be adopted for use. Hence, sustainability - economic, environmental, and societal - drives innovation in detection and remediation technology. The National Institute of Health (NIH) National Institute of Environmental Health Sciences (NIEHS) Superfund Research Program (SRP) is mandated to advance innovative detection, remediation, and toxicity screening technology development through grants to universities and small businesses. SRP recognizes the importance of fast, accurate, robust, and advanced detection technologies that allow for portable real-time, on-site characterization, monitoring, and assessment of contaminant concentration and/or toxicity. Advances in non-targeted screening, biological-based assays, passive sampling devices (PSDs), sophisticated modeling approaches, and precision-based analytical tools are making it easier to quickly identify hazardous "hotspots" and, therefore, prevent exposures. Innovation in sustainable remediation uses a variety of approaches: in situ remediation; harnessing the natural catalytic properties of biological processes (such as bioremediation and phytotechnologies); and application of novel materials science (such as nanotechnology, advanced

  2. Engineering Issue: Technology Alternatives for the Remediation of PCB Contaminated Soils and Sediments

    Science.gov (United States)

    The U.S. Environmental Protection Agency (EPA) Engineering Issue papers are a series of documents that summarize the available information on specific contaminates, selected treatment and site remediation technologies, and related issues. This Engineering Issue paper is intended...

  3. Demonstration test and evaluation of Ultraviolet/Ultraviolet Catalyzed Peroxide Oxidation for Groundwater Remediation at Oak Ridge K-25 Site. Final report [March 16, 1993--March 16, 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-01

    We demonstrated, tested and evaluated a new ultraviolet (UV) lamp integrated with an existing commercial technology employing UV catalyzed peroxide oxidation to destroy organics in groundwater at an Oak Ridge K-25 site. The existing commercial technology is the perox-pure{trademark} process of Peroxidation Systems Incorporated (PSI) that employs standard UV lamp technology to catalyze H{sub 2}O{sub 2} into OH radicals, which attack many organic molecules. In comparison to classical technologies for remediation of groundwater contaminated with organics, the perox-pure{trademark} process not only is cost effective but also reduces contaminants to harmless by-products instead of transferring the contaminants from one medium to another. Although the perox-pure{trademark} process is cost effective against many organics, it is not effective for some organic contaminants of interest to DOE such as TCA, which has the highest concentration of the organics at the K-25 test site. Contaminants such as TCA are treated more readily by direct photolysis using short wavelength UV light. WJSA has been developing a unique UV lamp which is very efficient in the short UV wavelength region. Consequently, combining this UV lamp with the perox-pure{trademark} process results in a means for treating essentially all organic contaminants. In the program reported here, the new UV lamp lifetime was improved and the lamp integrated into a PSI demonstration trailer. Even though this UV lamp operated at less than optimum power and UV efficiency, the destruction rate for the highest concentration organic (TCA) was more than double that of the commercial unit. An optimized UV lamp may double again the destruction rate; i.e., a factor of four greater than the commercial system. The demonstration at K-25 included tests with (1) the commercial PSI system, (2) the new UV lamp-based system and (3) the commercial PSI and new UV lamp systems in series.

  4. Applications of Nano Reactive Materials in Remediation of Persistence Organic Pollutants in Sediments and Groundwater - Presentation

    Science.gov (United States)

    Remediation of sediments and water contaminated hydrophobic organic chemicals (HOCs) such as polychlorinated biphenyls (PCBs) remains a scientific and technical challenge. PCBs-contaminated sediments are ubiquitous despite the production and use of PCBs was banned in 1979 due to...

  5. Remediation of groundwater contaminated with MTBE and benzene: the potential of vertical-flow soil filter systems

    NARCIS (Netherlands)

    Afferden, M. van; Rahman, K.Z.; Mosig, P.; De Biase, C.; Thullner, M.; Oswald, S.E.; Müller, R.A.

    2011-01-01

    Field investigations on the treatment of MTBE and benzene from contaminated groundwater in pilot or full-scale constructed wetlands are lacking hugely. The aim of this study was to develop a biological treatment technology that can be operated in an economic, reliable and robust mode over a long per

  6. Remediation of groundwater contaminated with MTBE and benzene: the potential of vertical-flow soil filter systems

    NARCIS (Netherlands)

    Afferden, M. van; Rahman, K.Z.; Mosig, P.; De Biase, C.; Thullner, M.; Oswald, S.E.; Müller, R.A.

    2011-01-01

    Field investigations on the treatment of MTBE and benzene from contaminated groundwater in pilot or full-scale constructed wetlands are lacking hugely. The aim of this study was to develop a biological treatment technology that can be operated in an economic, reliable and robust mode over a long

  7. Rhizofiltration using sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) to remediate uranium contaminated groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Minhee, E-mail: heelee@pknu.ac.kr [Department of Environmental Geosciences, Pukyong National University, 599-1 Daeyondong, Namgu, Busan 608-737 (Korea, Republic of); Yang, Minjune [Department of Environmental Geosciences, Pukyong National University, 599-1 Daeyondong, Namgu, Busan 608-737 (Korea, Republic of)

    2010-01-15

    The uranium removal efficiencies of rhizofiltration in the remediation of groundwater were investigated in lab-scale experiments. Sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) were cultivated and an artificially uranium contaminated solution and three genuine groundwater samples were used in the experiments. More than 80% of the initial uranium in solution and genuine groundwater, respectively, was removed within 24 h by using sunflower and the residual uranium concentration of the treated water was lower than 30 {mu}g/L (USEPA drinking water limit). For bean, the uranium removal efficiency of the rhizofiltration was roughly 60-80%. The maximum uranium removal via rhizofiltration for the two plant cultivars occurred at pH 3-5 of solution and their uranium removal efficiencies exceeded 90%. The lab-scale continuous rhizofiltration clean-up system delivered over 99% uranium removal efficiency, and the results of SEM and EDS analyses indicated that most uranium accumulated in the roots of plants. The present results suggested that the uranium removal capacity of two plants evaluated in the clean-up system was about 25 mg/kg of wet plant mass. Notably, the removal capacity of the root parts only was more than 500 mg/kg.

  8. Rhizofiltration using sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) to remediate uranium contaminated groundwater.

    Science.gov (United States)

    Lee, Minhee; Yang, Minjune

    2010-01-15

    The uranium removal efficiencies of rhizofiltration in the remediation of groundwater were investigated in lab-scale experiments. Sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) were cultivated and an artificially uranium contaminated solution and three genuine groundwater samples were used in the experiments. More than 80% of the initial uranium in solution and genuine groundwater, respectively, was removed within 24h by using sunflower and the residual uranium concentration of the treated water was lower than 30 microg/L (USEPA drinking water limit). For bean, the uranium removal efficiency of the rhizofiltration was roughly 60-80%. The maximum uranium removal via rhizofiltration for the two plant cultivars occurred at pH 3-5 of solution and their uranium removal efficiencies exceeded 90%. The lab-scale continuous rhizofiltration clean-up system delivered over 99% uranium removal efficiency, and the results of SEM and EDS analyses indicated that most uranium accumulated in the roots of plants. The present results suggested that the uranium removal capacity of two plants evaluated in the clean-up system was about 25mg/kg of wet plant mass. Notably, the removal capacity of the root parts only was more than 500 mg/kg.

  9. Examples of Department of Energy Successes for Remediation of Contaminated Groundwater: Permeable Reactive Barrier and Dynamic Underground Stripping ASTD Projects

    Energy Technology Data Exchange (ETDEWEB)

    Purdy, C.; Gerdes, K.; Aljayoushi, J.; Kaback, D.; Ivory, T.

    2002-02-27

    Since 1998, the Department of Energy's (DOE) Office of Environmental Management has funded the Accelerated Site Technology Deployment (ASTD) Program to expedite deployment of alternative technologies that can save time and money for the environmental cleanup at DOE sites across the nation. The ASTD program has accelerated more than one hundred deployments of new technologies under 76 projects that focus on a broad spectrum of EM problems. More than 25 environmental restoration projects have been initiated to solve the following types of problems: characterization of the subsurface using chemical, radiological, geophysical, and statistical methods; treatment of groundwater contaminated with DNAPLs, metals, or radionuclides; and other projects such as landfill covers, purge water management systems, and treatment of explosives-contaminated soils. One of the major goals of the ASTD Program is to deploy a new technology or process at multiple DOE sites. ASTD projects are encouraged to identify subsequent deployments at other sites. Some of the projects that have successfully deployed technologies at multiple sites focusing on cleanup of contaminated groundwater include: Permeable Reactive Barriers (Monticello, Rocky Flats, and Kansas City), treating uranium and organics in groundwater; and Dynamic Underground Stripping (Portsmouth, and Savannah River), thermally treating DNAPL source zones. Each year more and more new technologies and approaches are being used at DOE sites due to the ASTD program. DOE sites are sharing their successes and communicating lessons learned so that the new technologies can replace the baseline or standard approaches at DOE sites, thus expediting cleanup and saving money.

  10. Bioslurping technology applications at naval middle distillate fuel remediation sites

    Energy Technology Data Exchange (ETDEWEB)

    Hoeppel, R.E.; Goetz, F.E. [Naval Facilities Engineering Services Center, Port Hueneme, CA (United States); Kittel, J.A.; Hinchee, R.E.; Abbott, J.E. [Battelle Columbus, OH (United States)

    1995-12-31

    Bioslurping technology, a combination of bioventing and vacuum-enhanced free-product recovery of light, nonaqueous-phase liquid (LNAPL), has been employed at Fallon Naval Air Station, Nevada, for over 2 years and was initiated at Marine Corps Base Hawaii and a radar station near Hofn, Iceland. These sites have low-volatility fuels on the groundwater table in low- to medium-permeability soils. LNAPL recovery rates from 48 wells in silty fine sand to clay loam profiles at Fallon have ranged from 57 to 227 L/day with an average of 170 L/day at 10 to 30 cm of mercury vacuum. Mass discharge from the bioslurper system for LNAPL and vapor averaged 97% and 2.7%, respectively, with an average soil gas extraction rate of 0.024 m{sup 3}/min. Based on periodic soil gas analyses from 90 isolated soil gas sampling points in the vadose zone of the treatment plot, bioslurping appeared to satisfy O{sub 2} limitations i the contaminated soil profile. Despite no apparent O{sub 2} limitations in the contaminated soil profile. Despite no apparent O{sub 2} limitation for fuel biodegradation, low oxygen utilization rates were observed while performing in situ respiration tests following system shutdown. Preliminary in situ respirometry, soil gas, laboratory microcosm, stable carbon isotope, and soil characterization data indicate that both a low fuel surface area to volume ratio and bacterial cell damage may be involved in the observed low LNAPL bioemulsification and biodegradation rates.

  11. In Situ Remediation Integrated Program, Evaluation and assessment of containment technology

    Energy Technology Data Exchange (ETDEWEB)

    Gerber, M.A.; Fayer, M.J.

    1994-04-01

    The In Situ Remediation Integrated Program (ISRIP) was established by the US Department of Energy (DOE) to advance the state-of-the art of innovative in situ remediation technologies to the point of demonstration and to broaden the applicability of these technologies to the widely varying site remediation requirements throughout the DOE complex. This program complements similar ongoing integrated demonstration programs being conducted at several DOE sites. The ISRIP has been conducting baseline assessments on in situ technologies to support program planning. Pacific Northwest Laboratory conducted an assessment and evaluation of subsurface containment barrier technology in support of ISRIP`s Containment Technology Subprogram. This report summarizes the results of that activity and provides a recommendation for priortizing areas in which additional research and development is needed to advance the technology to the point of demonstration in support of DOE`s site restoration activities.

  12. Groundwater storage change detection using micro-gravimetric technology

    Science.gov (United States)

    El-Diasty, Mohammed

    2016-06-01

    In this paper, new perspectives and developments in applying a ground-based micro-gravimetric method to detect groundwater storage change in Waterloo Moraine are investigated. Four epochs of gravity survey were conducted using absolute gravimeter (FG5), two relative gravity meters (CG5) and two geodetic global positioning systems (GPS) in the Waterloo Moraine in May and August of 2010 and 2011, respectively. Data were processed using the parametric least-squares method and integrated with geological and hydrological studies. The gravity differences between May and August for 2010 and 2011 epochs were inverted to provide the estimated total water storage changes. Changes in soil water content obtained from land surface models of Ecological Assimilation of Land and Climate Observations (EALCO) and the Global Land Data Assimilation System (GLDAS) program were employed to estimate the groundwater storage change. The ratios between the estimated groundwater storage changes and measured water table changes (specific yields) were determined at a local monitoring well located in the survey area. The results showed that the estimates of specific yields between May and August of 2010 and 2011 were consistent at a significant confidence level and are also within the range of the specific yield from geological and hydrological studies. Therefore, the micro-gravimetric (absolute and relative gravity meters) technology has demonstrated the great potential in detecting groundwater storage change and specific yield for local scale aquifers such as Waterloo Moraine.

  13. Remediation approaches for polycyclic aromatic hydrocarbons (PAHs) contaminated soils: Technological constraints, emerging trends and future directions.

    Science.gov (United States)

    Kuppusamy, Saranya; Thavamani, Palanisami; Venkateswarlu, Kadiyala; Lee, Yong Bok; Naidu, Ravi; Megharaj, Mallavarapu

    2017-02-01

    For more than a decade, the primary focus of environmental experts has been to adopt risk-based management approaches to cleanup PAH polluted sites that pose potentially destructive ecological consequences. This focus had led to the development of several physical, chemical, thermal and biological technologies that are widely implementable. Established remedial options available for treating PAH contaminated soils are incineration, thermal conduction, solvent extraction/soil washing, chemical oxidation, bioaugmentation, biostimulation, phytoremediation, composting/biopiles and bioreactors. Integrating physico-chemical and biological technologies is also widely practiced for better cleanup of PAH contaminated soils. Electrokinetic remediation, vermiremediation and biocatalyst assisted remediation are still at the development stage. Though several treatment methods to remediate PAH polluted soils currently exist, a comprehensive overview of all the available remediation technologies to date is necessary so that the right technology for field-level success is chosen. The objective of this review is to provide a critical overview in this respect, focusing only on the treatment options available for field soils and ignoring the spiked ones. The authors also propose the development of novel multifunctional green and sustainable systems like mixed cell culture system, biosurfactant flushing, transgenic approaches and nanoremediation in order to overcome the existing soil- contaminant- and microbial-associated technological limitations in tackling high molecular weight PAHs. The ultimate objective is to ensure the successful remediation of long-term PAH contaminated soils.

  14. Ground-water flow and the possible effects of remedial actions at J-Field, Aberdeen Proving Ground, Maryland

    Science.gov (United States)

    Hughes, W.B.

    1995-01-01

    J-Field, located in the Edgewood Area of Aberdeen Proving Ground, Md, has been used since World War II to test and dispose of explosives, chemical warfare agents, and industrial chemicals resulting in ground-water, surface-water, and soil contami- nation. The U.S. Geological Survey finite-difference model was used to better understand ground-water flow at the site and to simulate the effects of remedial actions. A surficial aquifer and a confined aquifer were simulated with the model. A confining unit separates these units and is represented by leakance between the layers. The area modeled is 3.65 mi2; the model was constructed with a variably spaced 40 X 38 grid. The horizontal and lower boundaries of the model are all no-flow boundaries. Steady-state conditions were used. Ground water at the areas under investigation flows from disposal pit areas toward discharge areas in adjacent estuaries or wetlands. Simulations indicate that capping disposal areas with an impermeable cover effectively slows advective ground water flow by 0.7 to 0.5 times. Barriers to lateral ground-water flow were simulated and effectively prevented the movement of ground water toward discharge areas. Extraction wells were simulated as a way to contain ground-water contamination and to extract ground water for treatment. Two wells pumping 5 gallons per minute each at the toxic-materials disposal area and a single well pumping 2.5 gallons per minute at the riot-control-agent disposal area effectively contained contamination at these sites. A combi- nation of barriers to horizontal flow east and south of the toxic-materials disposal area, and a single extraction well pumping at 5 gallons per minute can extract contaminated ground water and prevent pumpage of marsh water.

  15. Groundwater.

    Science.gov (United States)

    Braids, Olin C.; Gillies, Nola P.

    1978-01-01

    Presents a literature review of groundwater quality covering publications of 1977. This review includes: (1) sources of groundwater contamination; and (2) management of groundwater. A list of 59 references is also presented. (HM)

  16. New Pump and Treat Facility Remedial Action Work Plan For Test Area North Final Groundwater Remediation, Operable Unit 1-07B

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, L. O.

    2007-06-12

    This remedial action work plan identifies the approach and requirements for implementing the medial zone remedial action for Test Area North, Operable Unit 1-07B, at the Idaho National Laboratory. This plan details the management approach for the construction and operation of the New Pump and Treat Facility (NPTF). As identified in the remediatial design/remedial action scope of work, a separate remedial design/remedial action work plan will be prepared for each remedial component of the Operable Unit 1-07B remedial action.

  17. Clay slurry and engineered soils as containment technologies for remediation of contaminated sites

    Energy Technology Data Exchange (ETDEWEB)

    Williams, J.R. [Reclamation Technology, Inc., Athens, GA (United States); Dudka, S.; Miller, W.P. [Univ. of Georgia, Athens, GA (United States); Johnson, D.O. [Argonne National Lab., IL (United States)

    1997-12-31

    Clay Slurry and Engineered Soils are containment technologies for remediation of waste disposal sites where leaching, groundwater plumes and surface runoff of contaminants are serious ecological hazards to adjacent environments. This technology is a patent-pending process which involves the use of conditioned clay materials mixed with sand and water to form a readily pourable suspension, a clay slurry, which is either placed into a trench barrier system or allowed to de-water to create Engineered Soils. The Engineered Soil forms a layer impervious to water and air, therefore by inhibiting both water and oxygen from penetrating through the soil the material. This material can be installed in layers and as a vertical barrier to create a surface barrier containment system. The clay percentage in the clay slurry and Engineered Soils varies depending on site characteristics and desired performance standards. For example Engineered Soils with 1-2% of clay (dry wt.) had a hydraulic conductivity (K) of 10{sup -8} to 10{sup -1} cm/sec. Tests of tailing materials from a kyanite and pyrite mine showed that the clay slurry was effective not only in reducing the permeability of the treated tailings, but also in decreasing their acidity due to the inherent alkalinity of the clay. The untreated tailings had pH values in the range of 2.4 - 3.1; whereas, the effluent from clay and tailings mixtures had pH values in a slightly alkaline range (7.7-7.9). Pug-mills and high volume slurry pumps can be readily adapted for use in constructing and placing caps and creating Engineered Soils. Moreover, material on site or from a local sand supply can be used to create clay slurries and engineered soils. Clay materials used in cap construction are likewise readily available commercially. As a result, the clay slurry system is very cost effective compared to other capping systems, including the commonly used High Density Polyethylene (HDPE) liner systems.

  18. Heating Unsaturated Sediments Using Solar Energy to Enhance Passive Sediment Remediation Technologies

    Science.gov (United States)

    Rossman, A.

    2002-12-01

    Sediment heating has been shown to enhance passive sediment remediation technologies such as bioremediation and barometric pumping (passive soil venting). Sediment heating raises the slow remediation rates that often limit the widespread use of these technologies. In bioremediation applications, a 10 degree C increase in subsurface temperature is expected to double the microbial activity, and thus the remediation rate. The removal rate of tetracholorethylene (PCE - a common subsurface contaminant) by passive soil vapor extraction is expected to nearly double in low-permeable sediments when the subsurface is heated 10 degree C from ambient temperatures due to an increased vapor pressure in the PCE. When the sediment is heated using renewable energy sources, these thermally enhanced remediation technologies can be environmentally benign alternatives to conventional remediation techniques that rely on large external energy inputs. The thermally enhanced passive technologies may be particularly useful for remediating unsaturated, low-permeable lenses that are troublesome to most conventional remediation technologies such as conventional soil vapor extraction and co-solvent flushes. The main objective of this work was to quantify subsurface sediment heating using a solar powered heat injection well. To do this, a pilot sediment heating system was installed in Vermont and high resolution meteorological and sediment temperature data were collected using a stand-alone data acquisition system. Unsaturated, silty sediments were heated in-situ by converting the direct and indirect solar energy available at the surface to heat energy in the subsurface using stand-alone renewable energy sources and a resistive element heat injection well. The heat injection well was powered by a 600-W passively tracking photovoltaic (PV) array and a small 1.2-m swept area wind turbine. It is envisioned that the heat injection well would be placed directly into an area of high subsurface

  19. Source zone remediation by zero valent iron technologies

    DEFF Research Database (Denmark)

    Fjordbøge, Annika Sidelmann

    , most of them are limited by subsurface heterogeneities and/or the risk of inadvertent DNAPL displacement during field application. This thesis presents the results of an investigation of the potential for remediation of chlorinated solvent source zones by emerging zero valent iron (ZVI) based...

  20. A TOOL FOR STRATEGIC TARGET SETTING ON DEVELOPMENT AND IMPROVEMENT OF REMEDIATION TECHNOLOGIES

    Science.gov (United States)

    Inoue, Yasushi; Katayama, Arata

    A tool for strategic development and improvement of remediation technologies was proposed to set a target specification by applying the RNSOIL, an evaluation index of remediation technologies for contaminated soil. Under the scenario of agricultural site contamination with dieldrin and its remediation, improving items and the target values of the bioremediation using charcoal material (charcoal bioremediation), as a developing technology, were determined. The development target was that the RNSOIL value of charcoal bioremediation fell below that of high temperature thermal desorption as a competing technology. Sensitivity assessments of the RNSOIL selected a remediation period and an incubation volume for bacterial growth and settlement in the charcoal as improving properties. Risk assessment and life cycle inventory analysis was introduced to determine a human health risk due to contaminant, and a total cost of remediation or a CO2 emission accompanied with remediation, as evaluating factors of RNSOIL, respectively. Assessment based on the RNSOIL was able to show clearly improving items for achieving the target or items with great effect for improvement.

  1. Engaging with residents' perceived risks and benefits about technologies as a way of resolving remediation dilemmas.

    Science.gov (United States)

    Prior, Jason; Rai, Tapan

    2017-12-01

    In recent decades the diversity of remediation technologies has increased significantly, with the breadth of technologies ranging from dig and dump to emergent technologies like phytoremediation and nanoremediation. The benefits of these technologies to the environment and human health are believed to be substantial. However, they also potentially constitute risks. Whilst there is a growing body of knowledge about the risks and benefits of these technologies from the perspective of experts, little is known about how residents perceive the risks and benefits of the application of these technologies to address contaminants in their local environment. This absence of knowledge poses a challenge to remediation practitioners and policy makers who are increasingly seeking to engage these affected local residents in choosing technology applications. Building on broader research into the perceived benefits and risks of technologies, and data from a telephone survey of 2009 residents living near 13 contaminated sites in Australia, regression analysis of closed-ended survey questions and coding of open-ended questions are combined to identify the main predictors of resident's perceived levels of risk and benefit to resident's health and to their local environment from remediation technologies. This research identifies a range of factors associated with the residents' physical context, their engagement with institutions during remediation processes, and the technologies which are associated with residents' level of perceived risk and benefit for human health and the local environment. The analysis found that bioremediation technologies were perceived as less risky and more beneficial than chemical, thermal and physical technologies. The paper also supports broader technology research that reports an inverse correlation between levels of perceived risks and benefits. In addition, the paper reveals the types of risks and benefits to human health and the local environment that

  2. Environmental- and health-risk-induced remediation design for benzene-contaminated groundwater under parameter uncertainty: a case study in Western Canada.

    Science.gov (United States)

    Fan, X; He, L; Lu, H W; Li, J

    2014-09-01

    This study proposes an environmental- and health-risk-induced remediation design approach for benzene-contaminated groundwater. It involves exposure frequency and intake rates that are important but difficult to be exactly quantified as breakthrough point. Flexible health-risk control is considered in the simulation and optimization work. The proposed approach is then applied to a petroleum-contaminated site in western Canada. Different situations about remediation durations, public concerns, and satisfactory degrees are addressed by the approach. The relationship between environmental standards and health-risk limits is analyzed, in association with their effect on remediation costs. Insights of three uncertain factors (i.e. exposure frequency, intake rate and health-risk threshold) for the remediation system are also explored, on a basis of understanding their impacts on health risk as well as their importance order. The case study results show that (1) nature attenuation plays a more important role in long-term remediation scheme than the pump-and-treat system; (2) carcinogenic risks have greater impact on total pumping rates than environmental standards for long-term remediation; (3) intake rates are the second important factor affecting the remediation system's performance, followed by exposure frequency; (4) the 10-year remediation scheme is the most robust choice when environmental and health-risk concerns are not well quantified. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. REDUCED PERMEABILITY IN GROUNDWATER REMEDIATION SYSTEMS: ROLE OF MOBILIZED COLLOIDS AND INJECTED CHEMICALS

    Science.gov (United States)

    The success of pump-and-treat or in situ remediation of contaminated aquifers depends in part on the ability to maintain the permeability of the aquifer, withdrawal wells, and delivery systems at a reasonable cost while moving significant quantities of water. We have considered o...

  4. Advances In Groundwater Remediation: Achieving Effective In Situ Delivery Of Chemical Oxidants And Amendments

    DEFF Research Database (Denmark)

    Siegrist, Robert L.; Crimi, Michelle; McCray, John E.

    Contamination of soil and groundwater by organic chemicals represents a major environmental problem in urban areas throughout the United States and other industrialized nations. Over many decades a wide variety of toxic organic chemicals have intentionally or accidentally been released into the s......Contamination of soil and groundwater by organic chemicals represents a major environmental problem in urban areas throughout the United States and other industrialized nations. Over many decades a wide variety of toxic organic chemicals have intentionally or accidentally been released...

  5. Ground-water flow and the potential effects of remediation at Graces Quarters, Aberdeen Proving Ground, Maryland

    Science.gov (United States)

    Tenbus, F.J.; Fleck, W.B.

    1996-01-01

    Ground water in the east-central part of Graces Quarters, a former open-air chemical-agent test facility at Aberdeen Proving Ground, Maryland, is contaminated with chlorinated volatile organic compounds. The U.S. Geological Survey's finite- difference model was used to help understand ground-water flow and simulate the effects of alternative remedial actions to clean up the ground water. Scenarios to simulate unstressed conditions and three extraction well con- figurations were used to compare alternative remedial actions on the contaminant plume. The scenarios indicate that contaminants could migrate from their present location to wetland areas within 10 years under unstressed conditions. Pumping 7 gal/min (gallons per minute) from one well upgradient of the plume will not result in containment or removal of the highest contaminant concentrations. Pumping 7 gal/min from three wells along the central axis of the plume should result in containment and removal of dissolved contami- nants, as should pumping 7 gal/min from three wells at the leading edge of the plume while injecting 7 gal/min back into an upgradient well.

  6. Column test-based optimization of the permeable reactive barrier (PRB) technique for remediating groundwater contaminated by landfill leachates

    Science.gov (United States)

    Zhou, Dan; Li, Yan; Zhang, Yinbo; Zhang, Chang; Li, Xiongfei; Chen, Zhiliang; Huang, Junyi; Li, Xia; Flores, Giancarlo; Kamon, Masashi

    2014-11-01

    We investigated the optimum composition of permeable reactive barrier (PRB) materials for remediating groundwater heavily contaminated by landfill leachate, in column tests using various mixtures of zero-valent iron (ZVI), zeolite (Zeo) and activated carbon (AC) with 0.01-0.25, 3.0-5.0 and 0.7-1.0 mm grain sizes, respectively. The main contributors to the removal of organic/inorganic contaminants were ZVI and AC, and the optimum weight ratio of the three PRB materials for removing the contaminants and maintaining adequate hydraulic conductivity was found to be 5:1:4. Average reductions in chemical oxygen demand (COD) and contents of total nitrogen (TN), ammonium, Ni, Pb and 16 polycyclic aromatic hydrocarbons (PAHs) from test samples using this mixture were 55.8%, 70.8%, 89.2%, 70.7%, 92.7% and 94.2%, respectively. We also developed a systematic method for estimating the minimum required thickness and longevity of the PRB materials. A ≥ 309.6 cm layer with the optimum composition is needed for satisfactory longevity, defined here as meeting the Grade III criteria (the Chinese National Bureau of Standards: GB/T14848/93) for in situ treatment of the sampled groundwater for ≥ 10 years.

  7. Genetic associations as indices of nitrogen cycling rates in an aerobic denitrification biofilter used for groundwater remediation.

    Science.gov (United States)

    Zhang, Yan; Ji, Guodong; Wang, Rongjing

    2015-10-01

    An aerobic denitrification biofilter (ADB) for groundwater remediation was developed with high removal efficiencies (total nitrogen (TN): 82.3-95.8%; NO3(-)-N: 93.2-98.2%). Nitrate (NO3(-)-N) transformation rates stabilized between 21.0 and 23.4 g/(m(3) h), whereas nitrite (NO2(-)-N) and ammonium (NH4(+)-N) transformation rates remained less than 6.0 g/(m(3) h) as the dissolved oxygen (DO) level increased from 1.0 mg/L to 6.0 mg/L. Nitric oxide (NO) and nitrous oxide (N2O) accumulated with great fluctuations (NO: 0-1.6×10(-3) g/(m(3) h); N2O: 0.1-1.1g/(m(3)h)) throughout the experiment. This study suggested that gene associations reflect quantitative relationships with aerobic denitrification rates and can provide useful information regarding aerobic denitrification processes in groundwater. Especially, the qnorB/nosZ ratio acts as the main driver for NO3(-)-N and NH4(+)-N transformation, while the qnorB/nosZ ratio followed by the (nirS+nirK)/nosZ ratio serve a dominant role in the accumulation of N2O and NO. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Monitoring the injection of microscale zerovalent iron particles for groundwater remediation by means of complex electrical conductivity imaging.

    Science.gov (United States)

    Flores Orozco, Adrián; Velimirovic, Milica; Tosco, Tiziana; Kemna, Andreas; Sapion, Hans; Klaas, Norbert; Sethi, Rajandrea; Bastiaens, Leen

    2015-05-01

    The injection of microscale zerovalent iron (mZVI) particles for groundwater remediation has received much interest in recent years. However, to date, monitoring of mZVI particle injection is based on chemical analysis of groundwater and soil samples and thus might be limited in its spatiotemporal resolution. To overcome this deficiency, in this study, we investigate the application of complex electrical conductivity imaging, a geophysical method, to monitor the high-pressure injection of mZVI in a field-scale application. The resulting electrical images revealed an increase in the induced electrical polarization (∼20%), upon delivery of ZVI into the targeted area, due to the accumulation of metallic surfaces at which the polarization takes place. Furthermore, larger changes (>50%) occurred in shallow sediments, a few meters away from the injection, suggesting the migration of particles through preferential flowpaths. Correlation of the electrical response and geochemical data, in particular the analysis of recovered cores from drilling after the injection, confirmed the migration of particles (and stabilizing solution) to shallow areas through fractures formed during the injection. Hence, our results demonstrate the suitability of the complex conductivity imaging method to monitor the transport of mZVI during subsurface amendment in quasi real-time.

  9. Test/QA Plan for Verification of Nitrate Sensors for Groundwater Remediation Monitoring

    Science.gov (United States)

    A submersible nitrate sensor is capable of collecting in-situ measurements of dissolved nitrate concentrations in groundwater. Although several types of nitrate sensors currently exist, this verification test will focus on submersible sensors equipped with a nitrate-specific ion...

  10. COMPREHENSIVE INTRODUCTION TO THE TECHNOLOGY OF GROUNDWATER MODELING AND OPTIMAL MANAGEMENT

    Institute of Scientific and Technical Information of China (English)

    武强; 田宝霖; 胡社荣; 金玉洁; 孙卫东; 田开铭

    1995-01-01

    Three numeric simulston and optimal managernent models on groundwater resources are introduced m this paper. These models stand for the present developing levels on the technology of groundwater modeling.and optimal management in China, and show the practical application situations of the technology. Each of the technology of unique characteristics and purposes. According to the tests of the practical engineering, these models have played a very important role in solving the difficult problems of groundwater resources.

  11. Feasibility study for remedial action for the groundwater operable units at the chemical plant area and the ordnance works area, Weldon Spring, Missouri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-15

    The U.S. Department of Energy (DOE) and the U.S. Department of Army (DA) are conducting an evaluation to identify the appropriate response action to address groundwater contamination at the Weldon Spring Chemical Plant (WSCP) and the Weldon Spring Ordnance Works (WSOW), respectively. The two areas are located in St. Charles County, about 48 km (30 rni) west of St. Louis. The groundwater operable unit (GWOU) at the WSCP is one of four operable units being evaluated by DOE as part of the Weldon Spring Site Remedial Action Project (WSSRAP). The groundwater operable unit at the WSOW is being evaluated by the DA as Operable Unit 2 (OU2); soil and pipeline contamination are being managed under Operable Unit 1 (OU1). Remedial activities at the WSCP and the WSOW are being conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). Consistent with DOE policy, National Environmental Policy Act (NEPA) values have been incorporated into the CERCLA process. A remedial investigation/feasibility study (RI/FS) work plan summarizing initial site conditions and providing site hydrogeological and exposure models was published in August of 1995 (DOE 1995). The remedial investigation (RI) and baseline risk assessment (BRA) have also recently been completed. The RI (DOE and DA 1998b) discusses in detail the nature, extent, fate, and transport of groundwater and spring water contamination. The BRA (DOE and DA 1998a) is a combined baseline assessment of potential human health and ecological impacts and provides the estimated potential health risks and ecological impacts associated with groundwater and springwater contamination if no remedial action were taken. This feasibility study (FS) has been prepared to evaluate potential options for addressing groundwater contamination at the WSCP and the WSOW. A brief description of the history and environmental setting of the sites is presented in Section 1.1, key information relative to the

  12. Enhancement of stability of various nZVI suspensions used in groundwater remediation with environmentally friendly organic stabilizers

    Science.gov (United States)

    Schmid, Doris; Wagner, Stephan; Velimirović, Milica; Laumann, Susanne; Micić, Vesna; Hofmann, Thilo

    2014-05-01

    The use of nanoscale zero-valent iron (nZVI) particles for in situ remediation of polluted soil and groundwater has been shown as one of the most promising techniques [1]. The success of this technology depends on the mobility, reactivity, and longevity of nZVI particles. The mobility of nZVI particles depends on the properties of the single particles, stability of the particle suspension, and the aquifer material [1,2]. In order to enhance the mobility of nZVI, the mobility-decisive properties of the nZVI particles in suspension such as concentration, size distribution, surface charge, and sedimentation rate have to be investigated and optimized. Previous studies showed that pristine nZVI particles aggregate rapidly in water, reducing the particles radius of influence after injection [3]. In order to prevent aggregation and sedimentation of the nZVI particles, and consequently improve the stability of nZVI suspension and therefore the mobility of the nZVI particles, surface stabilizers can be used to provide electrostatic repulsion and steric or electrosteric stabilization [3,4]. The objective of this lab-scale study is to investigate the potential for enhancing the stability of different nZVI suspensions by means of environmentally friendly organic stabilizers, including carboxymethyl cellulose, pectin, alginate, xanthan, and guar gum. The different nZVI particles used included pristine and polyacrylic acid-coated nZVI particles provided in suspension (Nanofer 25 and Nanofer 25S, respectively, NANOIRON s.r.o., Czech Republic), air-stable nZVI particles (Nanofer Star, (NANOIRON s.r.o., Czech Republic), and milled iron flakes (UVR-FIA, Germany). In order to study the enhancement of nZVI stability (1 g L-1 total iron) different concentrations of organic stabilizers (1-20 wt.%) were applied in these nZVI suspensions. Each nZVI suspension was freshly prepared and treated for 10 minutes with Ultra-Turrax (15 000 rpm) and 10 minutes ultrasonic bath prior to

  13. Remediation of DNAPLs in Low Permeability Soils. Innovative Technology Summary Report

    Energy Technology Data Exchange (ETDEWEB)

    None

    2000-09-01

    Dense, non-aqueous phase liquid (DNAPL) compounds like trichloroethene (TCE) and perchloroethene (PCE) are prevalent at U. S. Department of Energy (DOE), other government, and industrial sites. Their widespread presence in low permeability media (LPM) poses severe challenges for assessment of their behavior and implementation of effective remediation technologies. Most remedial methods that involve fluid flow perform poorly in LPM. Hydraulic fracturing can improve the performance of remediation methods such as vapor extraction, free-product recovery, soil flushing, steam stripping, bioremediation, bioventing, and air sparging in LPM by enhancing formation permeability through the creation of fractures filled with high-permeability materials, such as sand. Hydraulic fracturing can improve the performance of other remediation methods such as oxidation, reductive dechlorination, and bioaugmentation by enhancing delivery of reactive agents to the subsurface. Hydraulic fractures are typically created using a 2-in. steel casing and a drive point pushed into the subsurface by a pneumatic hammer. Hydraulic fracturing has been widely used for more than 50 years to stimulate the yield of wells recovering oil from rock at great depth and has recently been shown to stimulate the yield of wells recovering contaminated liquids and vapors from LPM at shallow depths. Hydraulic fracturing is an enabling technology for improving the performance of some remedial methods and is a key element in the implementation of other methods. This document contains information on the above-mentioned technology, including description, applicability, cost, and performance data.

  14. Remediation of Groundwater Polluted by Aromatic Compounds by Means of Adsorption

    Directory of Open Access Journals (Sweden)

    Silvana Canzano

    2014-07-01

    Full Text Available In this work, an experimental and modeling analysis of the adsorption of four aromatic compounds (i.e., toluene, naphthalene, o-xylene and ethylbenzene onto a commercial activated carbon is carried out. The aim is to assess the suitability of the adsorption process for the treatment of polluted groundwater, also when a multiple contamination is detected. Batch adsorption tests from simulated polluted groundwater are performed in single-compound systems and in two binary systems (i.e., toluene + naphthalene and o-xylene + ethylbenzene, at constant temperature (20 °C and pH (7. Experimental results in single-compound systems reveal that all of the analytes are significantly adsorbed on the tested activated carbon. In particular, toluene and naphthalene adsorption capacities are the highest and of similar value, while for o-xylene and ethylbenzene, the performances are lower. The adsorption of these compounds seems to be influenced by a combined effect of several parameters, such as hydrophobicity, molecule size, structure of the molecule, etc. Experimental results in binary systems show a different behavior of the two systems, which confirms their complexity and explains the interest in these complex adsorption systems. In particular, toluene and naphthalene are mutually competitive, while in the case of o-xylene + ethylbenzene, only the former undergoes competitive effects. The analysis of the entire experimental data set is integrated with a dedicated modeling analysis using the extended Langmuir model. For both single-compound and binary systems, this model provides acceptable results, in particular for low equilibrium concentrations, like those more commonly found in groundwater, and for the compounds involved in adsorptive competitive effects.

  15. Evaluation of the effectiveness of different methods for the remediation of contaminated groundwater by determining the petroleum hydrocarbon content

    Energy Technology Data Exchange (ETDEWEB)

    Voyevoda, Maryna; Geyer, Wolfgang; Mothes, Sibylle [Department of Analytical Chemistry, UFZ, Helmholtz Centre for Environmental Research - UFZ, Leipzig (Germany); Mosig, Peter [Centre for Environmental Biotechnology, UFZ, Helmholtz Centre for Environmental Research - UFZ, Leipzig (Germany); Seeger, Eva M. [Department of Environmental Biotechnology, UFZ, Helmholtz Centre for Environmental Research - UFZ, Leipzig (Germany)

    2012-08-15

    The effectiveness of different remediation procedures for decreasing the amount of TPH (total petroleum hydrocarbons) in contaminated groundwater was evaluated at the site of a former refinery. The investigations were carried out on samples taken from several gravel based HSSF (horizontal subsurface flow) constructed wetlands (CW) which differed in relation to their filter material additives (no additive, charcoal, and ferric oxides additives) and examined the potential effect of these additives on the overall treatment efficiency. Samples of the following gravel based HSSF CW were investigated. No filter additive (system A), 0.1% activated carbon (system B), 0.5% iron(III) hydroxide (system C), and the reference (system D). Systems A-C were planted with common reed (Phragmites australis), whereas system D remained unplanted. In addition, the influence of seasonal conditions on the reduction of these hydrocarbons and the correlation between the amounts of TPH and BTEX (benzene, toluene, ethylbenzene, and xylene isomers), on the one hand, and methyl tert-butyl ether, on the other, was investigated. The study was carried out by using a modified GC-FID approach and multivariate methods. The investigations carried out in the first year of operation demonstrated that the effectiveness of the petroleum hydrocarbon removal was highest and reached a level of 93 {+-} 3.5% when HSSF filters with activated carbon as a filter additive were used. This remediation method allowed the petroleum hydrocarbon content to be reduced independently of seasonal conditions. The correlation between the reduction of TPH and BTEX was found to be R = 0.8824. Using this correlation coefficient, the time-consuming determination of the BTEX content was no longer necessary. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  16. Remedial actions: A discussion of technological, regulatory and construction issues

    Energy Technology Data Exchange (ETDEWEB)

    Manrod, W.E.; Miller, R.A.; Barton, W.D. III; Pierce, T.J. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Engineering Div.

    1989-11-01

    The Oak Ridge Reservation consists of approximately 35,252 acres located in the Ridge and Valley Province of the Appalachian Mountains in Eastern Tennessee. Three Department of Energy facilities are located on the Reservation: the Y-12 Plant, the Oak Ridge Gaseous Diffusion Plant and the Oak Ridge National Laboratory. The plants have, over the years, disposed of low-level and mixed waste in various areas on the reservation principally with shallow land burial. A discussion is presented of some of the actions to remediate and close areas used for disposal of waste in the past. Current or planned activities for waste disposal and storage are also discussed. Closures completed to date have complied with Resource Conservation and Recovery Act Regulations. The new approach for disposal and storage has adopted ideas that have been successfully used by the French to dispose of low-level waste, as well as, improved on older shallow burial disposal techniques.

  17. Biochar- and phosphate-induced immobilization of heavy metals in contaminated soil and water: implication on simultaneous remediation of contaminated soil and groundwater.

    Science.gov (United States)

    Liang, Yuan; Cao, Xinde; Zhao, Ling; Arellano, Eduardo

    2014-03-01

    Long-term wastewater irrigation or solid waste disposal has resulted in the heavy metal contamination in both soil and groundwater. It is often separately implemented for remediation of contaminated soil or groundwater at a specific site. The main objective of this study was to demonstrate the hypothesis of simultaneous remediation of both heavy metal contaminated soil and groundwater by integrating the chemical immobilization and pump-and-treat methods. To accomplish the objective, three experiments were conducted, i.e., an incubation experiment was first conducted to determine how dairy-manure-derived biochar and phosphate rock tailing induced immobilization of Cd in the Cd-contaminated soils; second, a batch sorption experiment was carried out to determine whether the pre-amended contaminated soil still had the ability to retain Pb, Zn and Cd from aqueous solution. BCR sequential extraction as well as XRD and SEM analysis were conducted to explore the possible retention mechanism; and last, a laboratory-scale model test was undertaken by leaching the Pb, Zn, and Cd contaminated groundwater through the pre-amended contaminated soils to demonstrate how the heavy metals in both contaminated soil and groundwater were simultaneously retained and immobilized. The incubation experiment showed that the phosphate biochar were effective in immobilizing soil Cd with Cd concentration in TCLP (toxicity characteristics leaching procedure) extract reduced by 19.6 % and 13.7 %, respectively. The batch sorption experiment revealed that the pre-amended soil still had ability to retain Pb, Zn, and Cd from aqueous solution. The phosphate-induced metal retention was mainly due to the metal-phosphate precipitation, while both sorption and precipitation were responsible for the metal stabilization in the biochar amendment. The laboratory-scale test demonstrated that the soil amended with phosphate removed groundwater Pb, Zn, and Cd by 96.4 %, 44.6 %, and 49.2 %, respectively, and the

  18. Technology of groundwater reservoir construction in goafs of shallow coalfields

    Institute of Scientific and Technical Information of China (English)

    MA Li-qiang; ZHANG Dong-sheng; LI Xiang; FAN Gang-wei; ZHAO Yong-feng

    2009-01-01

    In exploiting shallow coal resources in western China, conservation of water resources is often subjugated to considera-tions of safety and production in coal mines. In order to maintain a sustainable development in the Shenfu-Dongsheng coalfield, we propose a technology of constructing groundwater reservoirs in goals in shallow coalfields to protect fragile ecological environ-ments. Given the premise of safe production, we selected an appropriate goal as the site for constructing a groundwater reservoir and used a mine water recharge technique in combination with other related techniques for effective water conservation. Then fil-tering and purification techniques were used to purify the mine water given the physical and chemical properties of mine water and its filling material, ,thereby greatly reducing suspended matter, calcium and other harmful ions in the water. With the potential of widely application, the research result has been successfully applied in the Daliuta coal mine, to great economic and ecological effect. Therefore, this achievement provides a new way for mine water conservation in shallow coal resources in western China.

  19. Remediation of the Highland Drive South Ravine, Port Hope, Ontario: Contaminated Groundwater Discharge Management Using Permeable Reactive Barriers and Contaminated Sediment Removal - 13447

    Energy Technology Data Exchange (ETDEWEB)

    Smyth, David; Roos, Gillian [Golder Associates Ltd., 2390 Argentia Road, Mississauga, ON L5N 5Z7 (Canada); Ferguson Jones, Andrea [MMM Group Ltd., 100 Commerce Valley Drive West, Thornhill, ON L3T 0A1 (Canada); Case, Glenn [AECL Port Hope Area Initiative Management Office, 115 Toronto Road, Port Hope, ON L1A 3S4 (Canada); Yule, Adam [Public Works and Government Services Canada, 4900 Yonge Street, 11th Floor, Toronto, ON, M2N 6A6 (Canada)

    2013-07-01

    The Highland Drive South Ravine (HDSR) is the discharge area for groundwater originating from the Highland Drive Landfill, the Pine Street North Extension (PSNE) roadbed parts of the Highland Drive roadbed and the PSNE Consolidation Site that contain historical low-level radioactive waste (LLRW). The contaminant plume from these LLRW sites contains elevated concentrations of uranium and arsenic and discharges with groundwater to shallow soils in a wet discharge area within the ravine, and directly to Hunt's Pond and Highland Drive South Creek, which are immediately to the south of the wet discharge area. Remediation and environmental management plans for HDSR have been developed within the framework of the Port Hope Project and the Port Hope Area Initiative. The LLRW sites will be fully remediated by excavation and relocation to a new Long-Term Waste Management Facility (LTWMF) as part of the Port Hope Project. It is projected, however, that the groundwater contaminant plume between the remediated LLRW sites and HDSR will persist for several hundreds of years. At the HDSR, sediment remediation within Hunt's Ponds and Highland Drive South Creek, excavation of the existing and placement of clean fill will be undertaken to remove current accumulations of solid-phase uranium and arsenic associated with the upper 0.75 m of soil in the wet discharge area, and permeable reactive barriers (PRBs) will be used for in situ treatment of contaminated groundwater to prevent the ongoing discharge of uranium and arsenic to the area in HDSR where shallow soil excavation and replacement has been undertaken. Bench-scale testing using groundwater from HDSR has confirmed excellent treatment characteristics for both uranium and arsenic using permeable reactive mixtures containing granular zero-valent iron (ZVI). A sequence of three PRBs containing ZVI and sand in backfilled trenches has been designed to intercept the groundwater flow system prior to its discharge to the ground

  20. Remedial investigation work plan for Bear Creek Valley Operable Unit 4 (shallow groundwater in Bear Creek Valley) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1993-07-01

    To effectively evaluate the cumulative impact of releases from multiple sources of contamination, a structured approach has been adopted for Oak Ridge Reservation (ORR) based on studies of the groundwater and surface water separate from studies of the sources. Based on the realization of the complexity of the hydrogeologic regime of the ORR, together with the fact that there are numerous sources contributing to groundwater contamination within a geographical area, it was agreed that more timely investigations, at perhaps less cost, could be achieved by separating the sources of contamination from the groundwater and surface water for investigation and remediation. The result will be more immediate attention [Records of Decision (RODs) for interim measures or removal actions] for the source Operable Units (OUs) while longer-term remediation investigations continue for the hydrogeologic regimes, which are labeled as integrator OUs. This remedial investigation work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to the unit. Taking advantage of the historical data base and ongoing monitoring activities and applying the observational approach to focus data gathering activities will allow the feasibility study to evaluate all probable or likely alternatives.

  1. Remedial Investigation work plan for Bear Creek Valley Operable Unit 4 (shallow groundwater in Bear Creek Valley) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    To effectively evaluate the cumulative impact of releases from multiple sources of contamination, a structured approach has been adopted for Oak Ridge Reservation (ORR) based on studies of the groundwater and surface water separate from studies of the sources. Based on the realization of the complexity of the hydrogeologic regime of the ORR, together with the fact that there are numerous sources contributing to groundwater contamination within a geographical area, it was agreed that more timely investigations, at perhaps less cost, could be achieved by separating the sources of contamination from the groundwater and surface water for investigation and remediation. The result will be more immediate attention [Records of Decision (RODS) for interim measures or removal actions] for the source Operable Units (OUs) while longer-term remediation investigations continue for the hydrogeologic regime`s, which are labeled as integrator OUs. This Remedial Investigation work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to the unit. Taking advantage of the historical data base and ongoing monitoring activities and applying the observational approach to focus data gathering activities will allow the Feasibility Study to evaluate all probable or likely alternatives.

  2. Soil and Sediment remediation, mechanisms, technologies and applications

    NARCIS (Netherlands)

    Lens, P.N.L.; Grotenhuis, J.T.C.; Malina, G.; Tabak, H.H.

    2005-01-01

    Technologies for the treatment of soils and sediments in-situ (landfarming, bioscreens, bioventing, nutrient injection, phytoremediation) and ex-situ (landfarming, bio-heap treatment, soil suspension reactor) will be discussed. The microbiological, process technological and socio-economical aspects

  3. Soil and Sediment remediation, mechanisms, technologies and applications

    NARCIS (Netherlands)

    Lens, P.N.L.; Grotenhuis, J.T.C.; Malina, G.; Tabak, H.H.

    2005-01-01

    Technologies for the treatment of soils and sediments in-situ (landfarming, bioscreens, bioventing, nutrient injection, phytoremediation) and ex-situ (landfarming, bio-heap treatment, soil suspension reactor) will be discussed. The microbiological, process technological and socio-economical aspects

  4. Groundwater remediation engineering--Study on the flow distribution of air sparging using acetylene

    Institute of Scientific and Technical Information of China (English)

    ZHENG Yan-mei; ZHANG Ying; HUANG Guo-qiang; JIANG Bin; LI Xin-gang

    2005-01-01

    Air sparging(AS) is an emerging method to remove VOCs from saturated soils and groundwater. Air sparging performance highly depends on the air distribution resulting in the aquifer. In order to study gas flow characterization, a two-dimensional experimental chamber was designed and installed. In addition, the method by using acetylene as the tracer to directly image the gas distribution results of AS process has been put forward. Experiments were performed with different injected gas flow rates. The gas flow patterns were found to depend significantly on the injected gas flow rate, and the characterization of gas flow distributions in porous media was very different from the acetylene tracing study. Lower and higher gas flow rates generally yield more irregular in shape and less effective gas distributions.

  5. Scale-up on electrokinetic remediation: Engineering and technological parameters.

    Science.gov (United States)

    López-Vizcaíno, Rubén; Navarro, Vicente; León, María J; Risco, Carolina; Rodrigo, Manuel A; Sáez, Cristina; Cañizares, Pablo

    2016-09-05

    This study analyses the effect of the scale-up of electrokinetic remediation (EKR) processes in natural soils. A procedure is proposed to prepare soils based on a compacting process to obtaining soils with similar moisture content and density to those found in real soils in the field. The soil used here was from a region with a high agrarian activity (Mora, Spain). The scale-up study was performed in two installations at different scales: a mock-up pilot scale (0.175m(3)) and a prototype with a scale that was very similar to a real application (16m(3)). The electrode configuration selected consisted of rows of graphite electrodes facing each other located in electrolyte wells. The discharge of 20mg of 2,4-dichlorophenoxyacetic acid [2,4-D] per kg of dry soil was treated by applying an electric potential gradient of 1Vcm(-1). An increase in scale was observed to directly influence the amount of energy supplied to the soil being treated. As a result, electroosmotic and electromigration flows and electric heating are more intense than in smaller-scale tests (24%, 1% and 25%, respectively respect to the values in prototype). In addition, possible leaks were evaluated by conducting a watertightness test and quantifying evaporation losses. Copyright © 2016 Elsevier B.V. All rights reserved.

  6. In situ bioremediation of nitrate and perchlorate in vadose zone soil for groundwater protection using gaseous electron donor injection technology.

    Science.gov (United States)

    Evans, Patrick J; Trute, Mary M

    2006-12-01

    When present in the vadose zone, potentially toxic nitrate and perchlorate anions can be persistent sources of groundwater contamination. Gaseous electron donor injection technology (GEDIT), an anaerobic variation of petroleum hydrocarbon bioventing, involves injecting electron donor gases, such as hydrogen or ethyl acetate, into the vadose zone, to stimulate biodegradation of nitrate and perchlorate. Laboratory microcosm studies demonstrated that hydrogen and ethanol promoted nitrate and perchlorate reduction in vadose zone soil and that moisture content was an important factor. Column studies demonstrated that transport of particular electron donors varied significantly; ethyl acetate and butyraldehyde were transported more rapidly than butyl acetate and ethanol. Nitrate removal in the column studies, up to 100%, was best promoted by ethyl acetate. Up to 39% perchlorate removal was achieved with ethanol and was limited by insufficient incubation time. The results demonstrate that GEDIT is a promising remediation technology warranting further validation.

  7. Application of Electro-Fenton Technology to Remediation of Polluted Effluents by Self-Sustaining Process

    OpenAIRE

    Maria Ángeles Fernández de Dios; Olaia Iglesias; Marta Pazos; Maria Ángeles Sanromán

    2014-01-01

    The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel c...

  8. Chlorinated volatile organic compounds (Cl-VOCs) in environment - sources, potential human health impacts, and current remediation technologies.

    Science.gov (United States)

    Huang, Binbin; Lei, Chao; Wei, Chaohai; Zeng, Guangming

    2014-10-01

    Chlorinated volatile organic compounds (Cl-VOCs), including polychloromethanes, polychloroethanes and polychloroethylenes, are widely used as solvents, degreasing agents and a variety of commercial products. These compounds belong to a group of ubiquitous contaminants that can be found in contaminated soil, air and any kind of fluvial mediums such as groundwater, rivers and lakes. This review presents a summary of the research concerning the production levels and sources of Cl-VOCs, their potential impacts on human health as well as state-of-the-art remediation technologies. Important sources of Cl-VOCs principally include the emissions from industrial processes, the consumption of Cl-VOC-containing products, the disinfection process, as well as improper storage and disposal methods. Human exposure to Cl-VOCs can occur through different routes, including ingestion, inhalation and dermal contact. The toxicological impacts of these compounds have been carefully assessed, and the results demonstrate the potential associations of cancer incidence with exposure to Cl-VOCs. Most Cl-VOCs thus have been listed as priority pollutants by the Ministry of Environmental Protection (MEP) of China, Environmental Protection Agency of the U.S. (U.S. EPA) and European Commission (EC), and are under close monitor and strict control. Yet, more efforts will be put into the epidemiological studies for the risk of human exposure to Cl-VOCs and the exposure level measurements in contaminated sites in the future. State-of-the-art remediation technologies for Cl-VOCs employ non-destructive methods and destructive methods (e.g. thermal incineration, phytoremediation, biodegradation, advanced oxidation processes (AOPs) and reductive dechlorination), whose advantages, drawbacks and future developments are thoroughly discussed in the later sections.

  9. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Appendix B of Attachment 3: Groundwater hydrology report, Attachment 4: Water resources protection strategy, Final

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-01

    Attachment 3 Groundwater Hydrology Report describes the hydrogeology, water quality, and water resources at the processing site and Dry Flats disposal site. The Hydrological Services calculations contained in Appendix A of Attachment 3, are presented in a separate report. Attachment 4 Water Resources Protection Strategy describes how the remedial action will be in compliance with the proposed EPA groundwater standards.

  10. [Mixture Leaching Remediation Technology of Arsenic Contaminated Soil].

    Science.gov (United States)

    Chen, Xun-feng; Li, Xiao-ming; Chen, Can; Yang, Qi; Deng, Lin-jing; Xie, Wei-qiang; Zhong, Yui; Huang, Bin; Yang, Wei-qiang; Zhang, Zhi-bei

    2016-03-15

    Soil contamination of arsenic pollution has become a severely environmental issue, while soil leaching is an efficient method for remediation of arsenic-contaminated soil. In this study, batch tests were primarily conducted to select optimal mixture leaching combination. Firstly, five conventional reagents were selected and combined with each other. Secondly, the fractions were analyzed before and after the tests. Finally, to explore the feasibility of mixed leaching, three soils with different arsenic pollution levels were used to compare the leaching effect. Comparing with one-step washing, the two-step sequential washing with different reagents increased the arsenic removal efficiency. These results showed that the mixture of 4 h 0.5 mol · L⁻¹ NaOH + 4 h 0.1 mol · L⁻¹ EDTA was found to be practicable, which could enhance the removal rate of arsenic from 66.67% to 91.83%, and the concentration of arsenic in soil was decreased from 186 mg · kg⁻¹ to 15.2 mg · kg⁻¹. Furthermore, the results indicated that the distribution of fractions of arsenic in soil changed apparently after mixture leaching. Leaching process could significantly reduce the available contents of arsenic in soil. Moreover, the mixture of 0.5 mol · L⁻¹ NaOH + 0.1 mol L⁻¹ EDTA could well decrease the arsenic concentration in aluminum-type soils, while the mixture of 0.5 mol · L⁻¹ OX + 0.5 mol · L⁻¹ NaOH could well decrease the arsenic concentration in iron-type soils.

  11. Mercury Remediation Technology Development for Lower East Fork Poplar Creek - FY 2015 Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Mark J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Brooks, Scott C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Mathews, Teresa J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Mayes, Melanie [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Johs, Alexander [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Watson, David B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Poteat, Monica D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Smith, John [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Mehlhorn, Tonia [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Lester, Brian [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Morris, Jesse [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Lowe, Kenneth [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division; Dickson, Johnbull O. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Eller, Virginia [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); DeRolph, Christopher R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division

    2016-04-01

    Mercury remediation is a high priority for the US Department of Energy (DOE) Oak Ridge Office of Environmental Management (OREM) because of large historical losses of mercury within buildings and to soils and surface waters at the Y-12 National Security Complex (Y-12). Because of the extent of mercury losses and the complexities of mercury transport and fate in the downstream environment, the success of conventional options for mercury remediation in lower East Fork Poplar Creek (EFPC) is uncertain. A phased, adaptive management approach to remediation of surface water includes mercury treatment actions at Y-12 in the short-term and research and technology development (TD) to evaluate longer-term solutions in the downstream environment (US Department of Energy 2014b).

  12. Field Demonstration of Propane Biosparging for In Situ Remediation of N-Nitrosodimethylamine (NDMA) in Groundwater

    Science.gov (United States)

    2015-12-01

    Battelle, 2001). In addition to its many advantages, the technology may have some disadvantages . For example, successful application of the technology...For C2, rates of propane, oxygen, and NDMA degradation generally increased with time, likely due to growth of biomass within the columns...propane (C3H8) to oxygen (O2) for complete oxidation of propane to carbon dioxide (CO2; not accounting for microbial biomass incorporation of C) is

  13. Remediation of TCE-contaminated groundwater using acid/BOF slag enhanced chemical oxidation.

    Science.gov (United States)

    Tsai, T T; Kao, C M; Wang, J Y

    2011-04-01

    The objective of this study was to evaluate the potential of applying acid/H(2)O(2)/basic oxygen furnace slag (BOF slag) and acid/S(2)O(8)(2-)/BOF slag systems to enhance the chemical oxidation of trichloroethylene (TCE)-contaminated groundwater. Results from the bench-scale study indicate that TCE oxidation via the Fenton-like oxidation process can be enhanced with the addition of BOF slag at low pH (pH=2-5.2) and neutral (pH=7.1) conditions. Because the BOF slag has iron abundant properties (14% of FeO and 6% of Fe(2)O(3)), it can be sustainably reused for the supplement of iron minerals during the Fenton-like or persulfate oxidation processes. Results indicate that higher TCE removal efficiency (84%) was obtained with the addition of inorganic acid for the activation of Fenton-like reaction compared with the experiments with organic acids addition (with efficiency of 10-15% lower) (BOF slag=10gL(-1); initial pH=5.2). This could be due to the fact that organic acids would compete with TCE for available oxidants. Results also indicate that the pH value had a linear correlation with the observed first-order decay constant of TCE, and thus, lower pH caused a higher TCE oxidation rate.

  14. Comparison of granular activated carbon and macroreticular synthetic adsorbents for groundwater remediation

    Energy Technology Data Exchange (ETDEWEB)

    Musterman, J.L.; Boero, V.J. [Eckenfelder Inc., Nashville, TN (United States). Wastewater Management Division; Plantz, D.A. [Rohm and Haas Co., Spring House, PA (United States)

    1995-12-31

    An evaluation of Calgon F-400 and Ambersorb 563 and 572 and XAD-4 resins for removal of VOCs from an activated sludge treated groundwater was performed using continuous flow reactors. Breakthrough and EBCT-ST curves were developed and the capacities of the adsorbents were determined. Comparison of the performance of the adsorbents indicated that: (1) Ambersorb 563 resin provided greater VOC adsorption capacity and run-time to breakthrough than Ambersorb 572 and XAD-4 resins or the F-400 GAC. (2) Ambersorb 563 resin could also be operated at three times the surface loading rate of the GAC system resulting in smaller equipment size. (3) The Ambersorb 563 resin showed negligible TOC removal despite a high specificity for the target organic analytes. A cost analysis indicated that the installed cost for a 6.31 L/s Ambersorb 563 resin system was 2.8 times the cost of a F-400 GAC system. The annual operating cost however, was four times lower and the total present worth was $549,000 less.

  15. Experimental Design for One Dimensional Electrolytic Reactive Barrier for Remediation of Munition Constituent in Groundwater

    Science.gov (United States)

    Gent, David B.; Wani, Altaf; Alshawabkeh, Akram N.

    2012-01-01

    A combination of direct electrochemical reduction and in-situ alkaline hydrolysis has been proposed to decompose energetic contaminants such as 1,3,5-Trinitroperhydro- 1,3,5-triazine and 2,4,6-Trinitrotoluene (RDX) in deep aquifers. This process utilizes natural groundwater convection to carry hydroxide produced by an upstream cathode to remove the contaminant at the cathode as well as in the pore water downstream as it migrates toward the anode. Laboratory evaluation incorporated fundamental principles of column design coupled with reactive contaminant modeling including electrokinetics transport. Batch and horizontal sand-packed column experiments included both alkaline hydrolysis and electrochemical treatment to determine RDX decomposition reaction rate coefficients. The sand packed columns simulated flow through a contaminated aquifer with a seepage velocity of 30.5 cm/day. Techniques to monitor and record the transient electric potential, hydroxide transport and contaminant concentration within the column were developed. The average reaction rate coefficients for both the alkaline batch (0.0487 hr−1) and sand column (0.0466 hr−1) experiments estimated the distance between the cathode and anode required to decompose 0.5 mg/L RDX to the USEPA drinking water lifetime Health Advisory level of 0.002 mg/L to be 145 and 152 cm. PMID:23472044

  16. Experimental Design for One Dimensional Electrolytic Reactive Barrier for Remediation of Munition Constituent in Groundwater.

    Science.gov (United States)

    Gent, David B; Wani, Altaf; Alshawabkeh, Akram N

    2012-12-30

    A combination of direct electrochemical reduction and in-situ alkaline hydrolysis has been proposed to decompose energetic contaminants such as 1,3,5-Trinitroperhydro- 1,3,5-triazine and 2,4,6-Trinitrotoluene (RDX) in deep aquifers. This process utilizes natural groundwater convection to carry hydroxide produced by an upstream cathode to remove the contaminant at the cathode as well as in the pore water downstream as it migrates toward the anode. Laboratory evaluation incorporated fundamental principles of column design coupled with reactive contaminant modeling including electrokinetics transport. Batch and horizontal sand-packed column experiments included both alkaline hydrolysis and electrochemical treatment to determine RDX decomposition reaction rate coefficients. The sand packed columns simulated flow through a contaminated aquifer with a seepage velocity of 30.5 cm/day. Techniques to monitor and record the transient electric potential, hydroxide transport and contaminant concentration within the column were developed. The average reaction rate coefficients for both the alkaline batch (0.0487 hr(-1)) and sand column (0.0466 hr(-1)) experiments estimated the distance between the cathode and anode required to decompose 0.5 mg/L RDX to the USEPA drinking water lifetime Health Advisory level of 0.002 mg/L to be 145 and 152 cm.

  17. Remediation of oil-contaminated soil using the CLEANSOIL technology

    Science.gov (United States)

    Zakharchenko, A. V.; Korzhov, Yu. V.; Lapshina, E. D.; Kul'Kov, M. G.; Yarkov, D. M.; Khoroshev, D. I.

    2011-04-01

    Approbation data of the innovative CLEANSOIL technology of soil purification after oil pollution are given. Drainage pipes filled with an adsorbent with microorganisms placed in the soil are used. It is revealed that the content of hydrocarbons under the technological constructions (metal columns and reservoirs) rises in comparison with the open oil-polluted areas. It is shown that the oil is destroyed quicker under the constructions versus in the open areas. The microorganisms better assimilate the n-alkanes with C14 chains than the C32-40 hydrocarbons. The application of a combined technology based on the sorption and reduction of the hydrocarbons by microorganisms makes it possible to quickly reduce the soil pollution by oil products without the soil cover's disturbance.

  18. A novel phytoremediation technology shown to remediate petroleum hydrocarbons from soils in situ

    Energy Technology Data Exchange (ETDEWEB)

    Huang, X.D.; Yu, X.M.; Gerhardt, K.; Glick, B.; Greenberg, B [Waterloo Environmental Biotechnology Inc., Hamilton, ON (Canada); Waterloo Univ., ON (Canada). Dept. of Biology

    2009-04-01

    This article described a newly developed, advanced microbe-enhanced phytoremediation system that can be used to remediate lands polluted by hydrocarbons, salts and metals. The technology uses 3 complementary processes to achieve effective remediation of strongly bound persistent organic pollutants (POPs) from soil. The remediation process involves physical soil treatment, photochemical photooxidation, microbial remediation and growth of plants treated with plant growth promoting rhizobacteria (PGPR). The PGPR-enhanced phytoremediation system (PEPS) alleviates plant stress and increases biodegradation activities, thereby accelerating plant growth in the presence of POPs or poor soils. The PEPS has been used successfully to remove petroleum hydrocarbons (PHCs) from impacted soils in situ at several sites across Canada. Studies have shown that the PHCs are degraded in the rhizosphere. This article also presented a summary of the work conducted at 3 sites in Alberta. It took only 2 years to remediate the 3 sites to levels required for site closure under Alberta Tier 1 guidelines. It was concluded that PEPS is equally effective for total PHC and Fraction 3 CCME hydrocarbons. 1 tab., 3 figs.

  19. Identification of phreatophytic groundwater dependent ecosystems using geospatial technologies

    Science.gov (United States)

    Perez Hoyos, Isabel Cristina

    The protection of groundwater dependent ecosystems (GDEs) is increasingly being recognized as an essential aspect for the sustainable management and allocation of water resources. Ecosystem services are crucial for human well-being and for a variety of flora and fauna. However, the conservation of GDEs is only possible if knowledge about their location and extent is available. Several studies have focused on the identification of GDEs at specific locations using ground-based measurements. However, recent progress in technologies such as remote sensing and their integration with geographic information systems (GIS) has provided alternative ways to map GDEs at much larger spatial extents. This study is concerned with the discovery of patterns in geospatial data sets using data mining techniques for mapping phreatophytic GDEs in the United States at 1 km spatial resolution. A methodology to identify the probability of an ecosystem to be groundwater dependent is developed. Probabilities are obtained by modeling the relationship between the known locations of GDEs and main factors influencing groundwater dependency, namely water table depth (WTD) and aridity index (AI). A methodology is proposed to predict WTD at 1 km spatial resolution using relevant geospatial data sets calibrated with WTD observations. An ensemble learning algorithm called random forest (RF) is used in order to model the distribution of groundwater in three study areas: Nevada, California, and Washington, as well as in the entire United States. RF regression performance is compared with a single regression tree (RT). The comparison is based on contrasting training error, true prediction error, and variable importance estimates of both methods. Additionally, remote sensing variables are omitted from the process of fitting the RF model to the data to evaluate the deterioration in the model performance when these variables are not used as an input. Research results suggest that although the prediction

  20. Natural Remediation at Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, C. M.; Van Pelt, R.

    2002-02-25

    Natural remediation is a general term that includes any technology or strategy that takes advantage of natural processes to remediate a contaminated media to a condition that is protective of human health and the environment. Natural remediation techniques are often passive and minimally disruptive to the environment. They are generally implemented in conjunction with traditional remedial solutions for source control (i.e., capping, stabilization, removal, soil vapor extraction, etc.). Natural remediation techniques being employed at Savannah River Site (SRS) include enhanced bio-remediation, monitored natural attenuation, and phytoremediation. Enhanced bio-remediation involves making nutrients available and conditions favorable for microbial growth. With proper precautions and feeding, the naturally existing microbes flourish and consume the contaminants. Case studies of enhanced bio-remediation include surface soils contaminated with PCBs and pesticides, and Volatile Organic Compound (VOC) contamination in both the vadose zone and groundwater. Monitored natural attenuation (MNA) has been selected as the preferred alternative for groundwater clean up at several SRS waste units. Successful implementation of MNA has been based on demonstration that sources have been controlled, groundwater modeling that indicates that plumes will not expand or reach surface water discharge points at levels that exceed regulatory limits, and continued monitoring. Phytoremediation is being successfully utilized at several SRS waste units. Phytoremediation involves using plants and vegetation to uptake, break down, or manage contaminants in groundwater or soils. Case studies at SRS include managing groundwater plumes of tritium and VOCs with pine trees that are native to the area. Significant decreases in tritium discharge to a site stream have been realized in one phytoremediation project. Studies of other vegetation types, methods of application, and other target contaminants are

  1. Phosphate-Based Mineralization of Arsenic in Contaminated Soil: A Potential Remediation Method for Soil and Groundwater

    Science.gov (United States)

    Neupane, G.; Donahoe, R. J.

    2009-12-01

    Soil arsenic contamination resulting from the use of arsenical compounds is a widespread environmental problem. A phosphate-based remediation method which has the potential to immobilize arsenic in both oxidizing and reducing subsurface systems is under laboratory investigation. Although phosphate treatments have been reported to be effective in removal of arsenic from contaminated water, its use in contaminated soils has not been tested. This study aims to (1) determine the competitive adsorption/desorption of arsenate and phosphate at surfaces of ferric hydroxide coated sand in the absence or presence of calcium ions, and (2) develop a method of arsenic fixation which involves phosphoric acid flushing of arsenic from contaminated soil and precipitation of arsenic as apatite-like phases. Ferric hydroxide is a significant arsenic sequestering constituent in soil. Phosphate competes with arsenate for adsorption sites on the ferric hydroxide surface. Batch adsorption experiments conducted using ferric hydroxide coated sand have indicated similar pH-controlled adsorption mechanisms for both arsenate and phosphate. The data obtained from the adsorption experiments is being used to guide the development of a phosphate-based method for soil and groundwater arsenic remediation. Batch experiments were performed using 3g of contaminated soil in contact with 45 ml of treatment fluid (a dilute phosphoric acid and calcium hydroxide solution). Solution samples were collected at 24, 72, 144, 312, and 384 hours, with continuous agitation at 200 rpm. Solution concentrations of phosphorus and calcium generally decreased with time and were primarily controlled by pH. It has been experimentally demonstrated that solution arsenic concentrations can be lowered by maintaining high pH with adequate calcium supply. A batch experiment conducted at pH > 11, using 1 kg of soil in contact with 1 liter of 0.25% H3PO4, precipitated a white material giving an XRD signature indicative of brushite

  2. Bioremediation, an environmental remediation technology for the bioeconomy.

    Science.gov (United States)

    Gillespie, Iain M M; Philp, Jim C

    2013-06-01

    Bioremediation differs from other industrial biotechnologies in that, although bioremediation contractors must profit from the activity, the primary driver is regulatory compliance rather than manufacturing profit. It is an attractive technology in the context of a bioeconomy but currently has limitations at the field scale. Ecogenomics techniques may address some of these limitations, but a further challenge would be acceptance of these techniques by regulators.

  3. Decision support tools for evaluation and selection of technologies for soil remediation and disposal of halogenated waste

    Energy Technology Data Exchange (ETDEWEB)

    Khelifi, O.; Zinovyev, S.; Lodolo, A.; Vranes, S.; Miertus, S. [ICS-UNIDO, Trieste (Italy)

    2004-09-15

    One of the most justified demands in abating the pollution created by polychlorinated substances is the remediation of contaminated sites, mainly soil remediation, which is also the most complex technical task in removing pollution because of the necessity to process huge quantities of matrix and to account for numerous side factors. The commercial technologies are usually based on rather direct and simplified but also secure processes, which often approach remediation in a general way, where different types of pollutants can be decontaminated at the same time by each technology. A number of different soil remediation technologies are nowadays available and the continuous competition among environmental service companies and technology developers generates a further increase in the clean-up options. The demand for decision support tools that could help decision makers in selecting the most appropriate technology for the specific contaminated site has consequently increased. These decision support tools (DST) are designed to help decision makers (site owners, local community representatives, environmentalists, regulators, etc.) to assess available technologies and preliminarily select the preferred remedial options. The analysis for the identification of the most suitable options in the DST is based on technical, economic, environmental, and social criteria. These criteria are ranked by all parties involved in the decision process to determine their relative importance for a particular remediation project. The aim of the present paper is to present the new approach for building decision support tool to evaluate different technologies for remediation and disposal of halogenated waste.

  4. In Situ Chemical Oxidation for Remediation of Contaminated Groundwater. Frequently Asked Questions

    Science.gov (United States)

    2010-03-01

    peroxide − Most contaminants are amenable including chlorocarbons, fuel hydrocarbons, pesticides , PAHs  Permanganate − Chloroethenes and PAHs...alternative endpoints such as: 1) transition from active treatment (e.g., ISCO) to a more passive technology like MNA or in situ bioremediation , 2

  5. Evaluating In Situ Treatment Technologies for Buried Mixed Waste Remediation at the INEEL

    Energy Technology Data Exchange (ETDEWEB)

    Jorgensen, Douglas Kay; Nickelson, David Frank; Nickelson, Reva Anne; Farnsworth, Richard Kent; Jessmore, James Joseph

    1999-03-01

    Mixed radioactive and hazardous wastes were buried at the Department of Energy’s Idaho National Engineering and Environmental Laboratory (INEEL) Subsurface Disposal Area from 1952 to 1969. To begin the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remediation process for the Subsurface Disposal Area, the Environmental Protection Agency (EPA) added the INEEL to its National Priorities List in 1989. DOE’s Office of Environmental Restoration is planning several CERCLA treatability studies of remedial technologies that will be evaluated for potential remediation of the buried waste in the Subsurface Disposal Area. This paper discusses the in situ treatability studies that will be performed, including in situ vitrification, in situ grouting, and in situ thermal desorption. The in situ treatability studies will be conducted on simulated and actual buried wastes at the INEEL in 1999 and 2000. Results from the treatability studies will provide substantial information on the feasibility, implementability, and cost of applying these technologies to the INEEL Subsurface Disposal Area. In addition, much of the treatability study data will be applicable to buried waste site remediation efforts across the DOE complex.

  6. Emerging Technologies and Techniques for Wide Area Radiological Survey and Remediation

    Energy Technology Data Exchange (ETDEWEB)

    Sutton, M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Zhao, P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-03-24

    Technologies to survey and decontaminate wide-area contamination and process the subsequent radioactive waste have been developed and implemented following the Chernobyl nuclear power plant release and the breach of a radiological source resulting in contamination in Goiania, Brazil. These civilian examples of radioactive material releases provided some of the first examples of urban radiological remediation. Many emerging technologies have recently been developed and demonstrated in Japan following the release of radioactive cesium isotopes (Cs-134 and Cs-137) from the Fukushima Dai-ichi nuclear power plant in 2011. Information on technologies reported by several Japanese government agencies, such as the Japan Atomic Energy Agency (JAEA), the Ministry of the Environment (MOE) and the National Institute for Environmental Science (NIES), together with academic institutions and industry are summarized and compared to recently developed, deployed and available technologies in the United States. The technologies and techniques presented in this report may be deployed in response to a wide area contamination event in the United States. In some cases, additional research and testing is needed to adequately validate the technology effectiveness over wide areas. Survey techniques can be deployed on the ground or from the air, allowing a range of coverage rates and sensitivities. Survey technologies also include those useful in measuring decontamination progress and mapping contamination. Decontamination technologies and techniques range from non-destructive (e.g., high pressure washing) and minimally destructive (plowing), to fully destructive (surface removal or demolition). Waste minimization techniques can greatly impact the long-term environmental consequences and cost following remediation efforts. Recommendations on technical improvements to address technology gaps are presented together with observations on remediation in Japan.

  7. Genealogy Remediated

    DEFF Research Database (Denmark)

    Marselis, Randi

    2007-01-01

    Genealogical websites are becoming an increasingly popular genre on the Web. This chapter will examine how remediation is used creatively in the construction of family history. While remediation of different kinds of old memory materials is essential in genealogy, digital technology opens new...... and technological competences, which helps to anchor the owner within the genealogical community....

  8. IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS - ACTIVE CAPPING TECHNOLOGY

    Energy Technology Data Exchange (ETDEWEB)

    Knox, A.; Roberts, J.; Paller, M.; Reible, D.

    2010-09-02

    Active capping is a relatively new approach for treating contaminated sediments. It involves applying chemically reactive amendments to the sediment surface. The main role of active caps is to stabilize contaminants in contaminated sediments, lower the bioavailable pool of contaminants, and reduce the release of contaminants to the water column. Metals are common contaminants in many marine and fresh water environments as a result of industrial and military activities. The mobile, soluble forms of metals are generally considered toxic. Induced chemical precipitation of these metals can shift toxic metals from the aqueous phase to a solid, precipitated phase which is often less bioavailable. This approach can be achieved through application of sequestering agents such as rock phosphates, organoclays, zeolites, clay minerals, and biopolymers (e.g., chitosan) in active capping technology. Active capping holds great potential for a more permanent solution that avoids residual risks resulting from contaminant migration through the cap or breaching of the cap. In addition to identifying superior active capping agents, research is needed to optimize application techniques, application rates, and amendment combinations that maximize sequestration of contaminants. A selected set of active capping treatment technologies has been demonstrated at a few sites, including a field demonstration at the Savannah River Site, Aiken, SC. This demonstration has provided useful information on the effects of sequestering agents on metal immobilization, bioavailability, toxicity, and resistance to mechanical disturbance.

  9. Remedial investigation concept plan for the groundwater operable units at the chemical plant area and the ordnance works area, Weldon Spring, Missouri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-15

    The U.S. Department of Energy (DOE) and the U.S. Department of the Army (DA) are conducting cleanup activities at two properties--the DOE chemical plant area and the DA ordnance works area (the latter includes the training area)--located in the Weldon Spring area in St. Charles County, Missouri. These areas are on the National Priorities List (NPL), and cleanup activities at both areas are conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended. DOE and DA are conducting a joint remedial investigation (RI) and baseline risk assessment (BRA) as part of the remedial investigation/feasibility study (RI/FS) for the groundwater operable units for the two areas. This joint effort will optimize further data collection and interpretation efforts and facilitate overall remedial decision making since the aquifer of concern is common to both areas. A Work Plan issued jointly in 1995 by DOE and the DA discusses the results of investigations completed at the time of preparation of the report. The investigations were necessary to provide an understanding of the groundwater system beneath the chemical plant area and the ordnance works area. The Work Plan also identifies additional data requirements for verification of the evaluation presented.

  10. Technology needs for environmental restoration remedial action. Environmental Restoration Program

    Energy Technology Data Exchange (ETDEWEB)

    Watson, J.S.

    1992-11-01

    This report summarizes the current view of the most important technology needs for the US Department of Energy (DOE) facilities operated by Martin Marietta Energy Systems, Inc. These facilities are the Oak Ridge National Laboratory, the Oak Ridge K-25 Site, the Oak Ridge Y-12 Plant, the Paducah Gaseous Diffusion Plant, and the Portsmouth Gaseous Diffusion Plant. The sources of information used in this assessment were a survey of selected representatives of the Environmental Restoration (ER) programs at each facility, results from a questionnaire distributed by Geotech CWM, Inc., for DOE, and associated discussions with individuals from each facility. This is not a final assessment, but a brief look at an ongoing assessment; the needs will change as the plans for restoration change and, it is hoped, as some technical problems are solved through successful development programs.

  11. Anthropology and decision making about chronic technological disasters: Mixed waste remediation on the Oak Ridge Reservation

    Energy Technology Data Exchange (ETDEWEB)

    Wolfe, A.K.; Schweitzer, M.

    1996-12-31

    This paper discusses two related case studies of decision making about the remediation of mixed (hazardous and radioactive) wastes on the Oak Ridge Reservation in Tennessee. The three goals of the paper are to (1) place current decision-making efforts in the varied and evolving social, political, regulatory, economic, and technological contexts in which they occur; (2) present definitions and attributes of {open_quotes}successful{close_quotes} environmental decision making from the perspectives of key constituency groups that participate in decision making; and (3) discuss the role of anthropology in addressing environmental decision making. Environmental decision making about remediation is extraordinarily complex, involving human health and ecological risks; uncertainties about risks, technological ability to clean up, the financial costs of clean up; multiple and sometimes conflicting regulations; social equity and justice considerations; and decreasing budgets. Anthropological theories and methods can contribute to better understanding and, potentially, to better decision making.

  12. Towards successful bioaugmentation with entrapped cells as a soil remediation technology

    DEFF Research Database (Denmark)

    Owsianiak, Mikolaj; Dechesne, Arnaud; Binning, Philip John

    2010-01-01

    Soil remediation technologies are proposed that rely on inoculation with degrading microorganisms entrapped in protective carriers. A mathematical model developed to model entrapped cell bioaugmentation describes the 3-D diffusion-driven mass transfer of benzoate, and its mineralization by Pseudo......Soil remediation technologies are proposed that rely on inoculation with degrading microorganisms entrapped in protective carriers. A mathematical model developed to model entrapped cell bioaugmentation describes the 3-D diffusion-driven mass transfer of benzoate, and its mineralization...... saturation 7%) and agree satisfactory well with model predictions. In contrast, much larger mineralization rates are measured for wet conditions (water saturation of 68%). This discrepancy originates from extensive cell dispersal, not accounted for in the model, which occurs in wet conditions...

  13. TANK FARM REMEDIATION TECHNOLOGY DEVELOPMENT PROJECT AN EXERCISE IN TECHNICAL & REGULATORY COLLABORATION

    Energy Technology Data Exchange (ETDEWEB)

    JARAYSI, M.N.

    2007-01-08

    The Tank Farm Remediation Technology Development Project at the Hanford Site focuses on waste storage tanks, pipelines and associated ancillary equipment that are part of the C-200 single-shell tank (SST) farm system located in the C Tank Farm. The purpose of the project is to obtain information on the implementation of a variety of closure activities and to answer questions on technical, operational and regulatory issues associated with closure.

  14. Environmental life-cycle comparisons of two polychlorinated biphenyl remediation technologies: incineration and base catalyzed decomposition.

    Science.gov (United States)

    Hu, Xintao; Zhu, Jianxin; Ding, Qiong

    2011-07-15

    Remediation action is critical for the management of polychlorinated biphenyl (PCB) contaminated sites. Dozens of remediation technologies developed internationally could be divided in two general categories incineration and non-incineration. In this paper, life cycle assessment (LCA) was carried out to study the environmental impacts of these two kinds of remediation technologies in selected PCB contaminated sites, where Infrared High Temperature Incineration (IHTI) and Base Catalyzed Decomposition (BCD) were selected as representatives of incineration and non-incineration. A combined midpoint/damage approach was adopted by using SimaPro 7.2 and IMPACTA2002+ to assess the human toxicity, ecotoxicity, climate change impact, and resource consumption from the five subsystems of IHTI and BCD technologies, respectively. It was found that the major environmental impacts through the whole lifecycle arose from energy consumption in both IHTI and BCD processes. For IHTI, primary and secondary combustion subsystem contributes more than 50% of midpoint impacts concerning with carcinogens, respiratory inorganics, respiratory organics, terrestrial ecotoxity, terrestrial acidification/eutrophication and global warming. In BCD process, the rotary kiln reactor subsystem presents the highest contribution to almost all the midpoint impacts including global warming, non-renewable energy, non-carcinogens, terrestrial ecotoxity and respiratory inorganics. In the view of midpoint impacts, the characterization values for global warming from IHTI and BCD were about 432.35 and 38.5 kg CO(2)-eq per ton PCB-containing soils, respectively. LCA results showed that the single score of BCD environmental impact was 1468.97 Pt while IHTI's score is 2785.15 Pt, which indicates BCD potentially has a lower environmental impact than IHTI technology in the PCB contaminated soil remediation process.

  15. Hydrogeloogic characterization of fractured rock formations: A guide for groundwater remediators

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, A.J.B.

    1995-10-01

    A field site was developed in the foothills of the Sierra Nevada, California to develop and test a multi-disciplinary approach to the characterization of ground water flow and transport in fractured rocks. Nine boreholes were drilled into the granitic bedrock, and a wide variety of new and traditional subsurface characterization tools were implemented. The hydrogeologic structure and properties of the field site were deduced by integrating results from the various geologic, geophysical, hydrologic, and other investigative methods. The findings of this work are synthesized into this report, which is structured in a guidebook format. The applications of the new and traditional technologies, suggestions on how best to use, integrate, and analyze field data, and comparisons of the shortcoming and benefits of the different methods are presented.

  16. Biosurfactant technology for remediation of cadmium and lead contaminated soils.

    Science.gov (United States)

    Juwarkar, Asha A; Nair, Anupa; Dubey, Kirti V; Singh, S K; Devotta, Sukumar

    2007-08-01

    This research focuses on column experiments conducted to evaluate the potential of environmentally compatible rhamnolipid biosurfactant produced by Pseudomonas aeruginosa strain BS2 to remove heavy metals (Cd and Pb) from artificially contaminated soil. Results have shown that di-rhamnolipid removes not only the leachable or available fraction of Cd and Pb but also the bound metals as compared to tap water which removed the mobile fraction only. Washing of contaminated soil with tap water revealed that approximately 2.7% of Cd and 9.8% of Pb in contaminated soil was in freely available or weakly bound forms whereas washing with rhamnolipid removed 92% of Cd and 88% of Pb after 36 h of leaching. This indicated that di-rhamnolipid selectively favours mobilization of metals in the order of Cd>Pb. Biosurfactant specificity observed towards specific metal will help in preferential elution of specific contaminant using di-rhamnolipid. It was further observed that pH of the leachates collected from heavy metal contaminated soil column treated with di-rhamnolipid solution was low (6.60-6.78) as compared to that of leachates from heavy metal contaminated soil column treated with tap water (pH 6.90-7.25), which showed high dissolution of metal species from the contaminated soil and effective leaching of metals with treatment with biosurfactant. The microbial population of the contaminated soil was increased after removal of metals by biosurfactant indicating the decrease of toxicity of metals to soil microflora. This study shows that biosurfactant technology can be an effective and nondestructive method for bioremediation of cadmium and lead contaminated soil.

  17. ARCTIC FOUNDATIONS, INC. FREEZE BARRIER TECHNOLOGY; INNOVATIVE TECHNOLOGY EVALUATION REPORT

    Science.gov (United States)

    Arctic Foundations, Inc. (AFI), of Anchorage, Alaska has developed a freeze barrier technology designed to prevent the migration of contaminants in groundwater by completely isolating contaminant source areas until appropriate remediation techniques can be applied. With this tech...

  18. Photovoltaic power for remote site remediation

    Energy Technology Data Exchange (ETDEWEB)

    Torr, S.; Jensen, E.; Dingman, C.; Brewster, M.L. [Komex International Ltd., Calgary, AB (Canada)

    2003-07-01

    This paper described how photovoltaic solar power and remediation technologies can be integrated to remediate salt and hydrocarbon contaminated soils at remote sites. The integrated method can be applied in a variety of situations, such as groundwater extraction, reverse osmosis treatment, soil vapour extraction, and a solar mobile power station. The simplicity of the designs, the maximization of system efficiency, and minimization of operation and maintenance requirements ensure the success of the systems. The remedial goals combined with the applied technology, help in determining whether the photovoltaic powered systems should operate on an intermittent or continual basis. Higher system outputs are normally obtained with continual operation, but they also yield increased design complexity and inefficiencies. The authors stated that as the technology of photovoltaic power evolves, efficiencies and costs will improve, thereby increasing its progressive use as a renewable energy source for remote sites remediation. 2 refs., 1 tab.

  19. Soil washing as a potential remediation technology for contaminated DOE sites

    Energy Technology Data Exchange (ETDEWEB)

    Devgun, J.S.; Beskid, N.J. [Argonne National Lab., IL (United States); Natsis, M.E. [Princeton Univ., NJ (United States); Walker, J.S. [USDOE, Washington, DC (United States)

    1993-03-01

    Frequently detected contaminants at US Department of Energy (DOE) sites include radionuclides, heavy metals, and chlorinated hydrocarbons. Remediation of these sites requires application of several technologies used in concert with each other, because no single technology is universally applicable. Special situations, such as mixed waste, generally require innovative technology development. This paper, however, focuses on contaminated soils, for which soil washing and vitrification technologies appear to have wide ranging application potential. Because the volumes of contaminated soils around the DOE complex are so large, soil washing can offer a potentially inexpensive way to effect remediation or to attain waste volume reduction. As costs for disposal of low-level and mixed wastes continue to rise, it is likely that volume-reduction techniques and in-situ containment techniques will become increasingly important. This paper reviews the status of the soil washing technology, examines the systems that are currently available, and discusses the potential application of this technology to some DOE sites, with a focus on radionuclide contamination and, primarily, uranium-contaminated soils

  20. Soil washing as a potential remediation technology for contaminated DOE sites

    Energy Technology Data Exchange (ETDEWEB)

    Devgun, J.S.; Beskid, N.J. (Argonne National Lab., IL (United States)); Natsis, M.E. (Princeton Univ., NJ (United States)); Walker, J.S. (USDOE, Washington, DC (United States))

    1993-01-01

    Frequently detected contaminants at US Department of Energy (DOE) sites include radionuclides, heavy metals, and chlorinated hydrocarbons. Remediation of these sites requires application of several technologies used in concert with each other, because no single technology is universally applicable. Special situations, such as mixed waste, generally require innovative technology development. This paper, however, focuses on contaminated soils, for which soil washing and vitrification technologies appear to have wide ranging application potential. Because the volumes of contaminated soils around the DOE complex are so large, soil washing can offer a potentially inexpensive way to effect remediation or to attain waste volume reduction. As costs for disposal of low-level and mixed wastes continue to rise, it is likely that volume-reduction techniques and in-situ containment techniques will become increasingly important. This paper reviews the status of the soil washing technology, examines the systems that are currently available, and discusses the potential application of this technology to some DOE sites, with a focus on radionuclide contamination and, primarily, uranium-contaminated soils

  1. Reference Guide to Non-combustion Technologies for Remediation of Persistent Organic Pollutants in Soil, Second Edition - 2010

    Science.gov (United States)

    This report is the second edition of the U.S. Environmental Protection Agency's (US EPA's) 2005 report and provides a high level summary of information on the applicability of existing and emerging noncombustion technologies for the remediation of...

  2. Oak Ridge National Laboratory Technology Logic Diagram. Volume 3, Technology evaluation data sheets: Part B, Dismantlement, Remedial action

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    The Oak Ridge National Laboratory Technology Logic Diagram (TLD) was developed to provide a decision support tool that relates environmental restoration (ER) and waste management (WM) problems at Oak Ridge National Laboratory (ORNL) to potential technologies that can remediate these problems. The TLD identifies the research, development, demonstration testing, and evaluation needed to develop these technologies to a state that allows technology transfer and application to decontamination and decommissioning (D&D), remedial action (RA), and WM activities. The TLD consists of three fundamentally separate volumes: Vol. 1, Technology Evaluation; Vol. 2, Technology Logic Diagram and Vol. 3, Technology EvaLuation Data Sheets. Part A of Vols. 1 and 2 focuses on RA. Part B of Vols. 1 and 2 focuses on the D&D of contaminated facilities. Part C of Vols. 1 and 2 focuses on WM. Each part of Vol. 1 contains an overview of the TM, an explanation of the problems facing the volume-specific program, a review of identified technologies, and rankings of technologies applicable to the site. Volume 2 (Pts. A. B. and C) contains the logic linkages among EM goals, environmental problems, and the various technologies that have the potential to solve these problems. Volume 3 (Pts. A. B, and C) contains the TLD data sheets. This volume provides the technology evaluation data sheets (TEDS) for ER/WM activities (D&D, RA and WM) that are referenced by a TEDS code number in Vol. 2 of the TLD. Each of these sheets represents a single logic trace across the TLD. These sheets contain more detail than is given for the technologies in Vol. 2.

  3. DEPARTMENT OF ENERGY SOIL AND GROUNDWATER SCIENCE AND TECHNOLOGY NEEDS, PLANS AND INITIATIVES

    Energy Technology Data Exchange (ETDEWEB)

    Aylward, B; V. ADAMS, V; G. M. CHAMBERLAIN, G; T. L. STEWART, T

    2007-12-12

    This paper presents the process used by the Department of Energy (DOE) Environmental Management (EM) Program to collect and prioritize DOE soil and groundwater site science and technology needs, develop and document strategic plans within the EM Engineering and Technology Roadmap, and establish specific program and project initiatives for inclusion in the EM Multi-Year Program Plan. The paper also presents brief summaries of the goals and objectives for the established soil and groundwater initiatives.

  4. Design requirements for ERD and ISCO: How close and how fast to achieve an effective remediation?

    DEFF Research Database (Denmark)

    Chambon, Julie Claire Claudia; Lemming, Gitte; Manoli, Gabriele

    2011-01-01

    Clayey tills contaminated with chlorinated solvents are a threat to groundwater and are difficult to remediate. Full scale Enhanced Reductive Dechlorination (ERD) and In-Situ Chemical Oxidation (ISCO) are promising remediation technologies for such sites, but the delivery of reactants is challeng...

  5. DOE underground storage tank waste remediation chemical processing hazards. Part I: Technology dictionary

    Energy Technology Data Exchange (ETDEWEB)

    DeMuth, S.F.

    1996-10-01

    This document has been prepared to aid in the development of Regulating guidelines for the Privatization of Hanford underground storage tank waste remediation. The document has been prepared it two parts to facilitate their preparation. Part II is the primary focus of this effort in that it describes the technical basis for established and potential chemical processing hazards associated with Underground Storage Tank (UST) nuclear waste remediation across the DOE complex. The established hazards involve those at Sites for which Safety Analysis Reviews (SARs) have already been prepared. Potential hazards are those involving technologies currently being developed for future applications. Part I of this document outlines the scope of Part II by briefly describing the established and potential technologies. In addition to providing the scope, Part I can be used as a technical introduction and bibliography for Regulatory personnel new to the UST waste remediation, and in particular Privatization effort. Part II of this document is not intended to provide examples of a SAR Hazards Analysis, but rather provide an intelligence gathering source for Regulatory personnel who must eventually evaluate the Privatization SAR Hazards Analysis.

  6. Thermal Treatment of Hydrocarbon-Impacted Soils: A Review of Technology Innovation for Sustainable Remediation

    Directory of Open Access Journals (Sweden)

    Julia E. Vidonish

    2016-12-01

    Full Text Available Thermal treatment technologies hold an important niche in the remediation of hydrocarbon-contaminated soils and sediments due to their ability to quickly and reliably meet cleanup standards. However, sustained high temperature can be energy intensive and can damage soil properties. Despite the broad applicability and prevalence of thermal remediation, little work has been done to improve the environmental compatibility and sustainability of these technologies. We review several common thermal treatment technologies for hydrocarbon-contaminated soils, assess their potential environmental impacts, and propose frameworks for sustainable and low-impact deployment based on a holistic consideration of energy and water requirements, ecosystem ecology, and soil science. There is no universally appropriate thermal treatment technology. Rather, the appropriate choice depends on the contamination scenario (including the type of hydrocarbons present and on site-specific considerations such as soil properties, water availability, and the heat sensitivity of contaminated soils. Overall, the convergence of treatment process engineering with soil science, ecosystem ecology, and plant biology research is essential to fill critical knowledge gaps and improve both the removal efficiency and sustainability of thermal technologies.

  7. Can nitrate contaminated groundwater be remediated by optimizing flood irrigation rate with high nitrate water in a desert oasis using the WHCNS model?

    Science.gov (United States)

    Liang, Hao; Qi, Zhiming; Hu, Kelin; Prasher, Shiv O; Zhang, Yuanpei

    2016-10-01

    Nitrate contamination of groundwater is an environmental concern in intensively cultivated desert oases where this polluted groundwater is in turn used as a major irrigation water resource. However, nitrate fluxes from root zone to groundwater are difficult to monitor in this complex system. The objectives of this study were to validate and apply the WHCNS (soil Water Heat Carbon Nitrogen Simulator) model to simulate water drainage and nitrate leaching under different irrigation and nitrogen (N) management practices, and to assess the utilization of groundwater nitrate as an approach to remediate nitrate contaminated groundwater while maintain crop yield. A two-year field experiment was conducted in a corn field irrigated with high nitrate groundwater (20 mg N L(-1)) in Alxa, Inner Mongolia, China. The experiment consisted of two irrigation treatments (Istd, standard, 750 mm per season; Icsv, conservation, 570 mm per season) factorially combined with two N fertilization treatments (Nstd, standard, 138 kg ha(-1); Ncsv, conservation, 92 kg ha(-1)). The validated results showed that the WHCNS model simulated values of crop dry matter, yield, soil water content and soil N concentration in soil profile all agreed well with the observed values. Compared to the standard water management (Istd), the simulated drainage and nitrate leaching decreased about 65% and 59%, respectively, under the conservation water management (Icsv). Nearly 55% of input N was lost by leaching under the IstdNstd and IstdNcsv treatments, compared to only 26% under the IcsvNstd and IcsvNcsv treatments. Simulations with more than 240 scenarios combing different levels of irrigation and fertilization indicated that irrigation was the main reason leading to the high risk of nitrate leaching, and the nitrate in irrigation groundwater can be best utilized without corn yield loss when the total irrigation was reduced from the current 750 mm to 491 mm. This reduced irrigation rate facilitated

  8. Risk-based systems analysis of emerging high-level waste tank remediation technologies. Volume 2: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Peters, B.B.; Cameron, R.J.; McCormack, W.D. [Enserch Environmental Corp., Richland, WA (United States)

    1994-08-01

    The objective of DOE`s Radioactive Waste Tank Remediation Technology Focus Area is to identify and develop new technologies that will reduce the risk and/or cost of remediating DOE underground waste storage tanks and tank contents. There are, however, many more technology investment opportunities than the current budget can support. Current technology development selection methods evaluate new technologies in isolation from other components of an overall tank waste remediation system. This report describes a System Analysis Model developed under the US Department of Energy (DOE) Office of Technology Development (OTD) Underground Storage Tank-Integrated Demonstration (UST-ID) program. The report identifies the project objectives and provides a description of the model. Development of the first ``demonstration`` version of this model and a trial application have been completed and the results are presented. This model will continue to evolve as it undergoes additional user review and testing.

  9. Environmental summary of the F- and H-area seepage basins groundwater remediation project, Savannah River site

    Energy Technology Data Exchange (ETDEWEB)

    Friday, G.P.

    1997-12-31

    This report summarizes the results of nearly 70 investigations of the baseline environment, describes the remedial action, and identifies constituents of interest that pose potential risk to human health and the environment. It also proposes an approach for evaluating the effectiveness of the remedial action.

  10. [Recent advance in solidification/stabilization technology for the remediation of heavy metals-contaminated soil].

    Science.gov (United States)

    Hao, Han-zhou; Chen, Tong-bin; Jin, Meng-gui; Lei, Mei; Liu, Cheng-wu; Zu, Wen-pu; Huang, Li-mi

    2011-03-01

    Remediation of heavy metals-contaminated soil is still a difficulty and a hotspot of international research projects. At present, the technologies commonly adopted for the remediation of contaminated sites mainly include excavation, solidification/stabilization (S/S), soil washing, soil vapor extraction (SVE), thermal treatment, and bioremediation. Based on the S/S technical guidelines of Unite State Environmental Protection Agency (EPA) and United Kingdom Environment Agency (EA) and the domestic and foreign patents, this paper introduced the concepts of S/S and its development status at home and abroad, and discussed its future development directions. Solidification refers to a process that binds contaminated media with a reagent, changing the media's physical properties via increasing its compressive strength, decreasing its permeability, and encapsulating the contaminants to form a solid material. Stabilization refers to the process that involves a chemical reaction which reduces the leachability of a waste, chemically immobilizes the waste and reduces its solubility, making the waste become less harmful or less mobile. S/S technology includes cement solidification, lime pozzolanic solidification, plastic materials stabilization, vitrification, and regent-based stabilization. Stabilization (or immobilization) treatment processes convert contaminants to less mobile forms through chemical or thermal interactions. In stabilization technology, the aim of adding agents is to change the soil physical and chemical properties through pH control technology, redox potential technology, precipitation techniques, adsorption technology, and ion-exchange technology that change the existing forms of heavy metals in soil, and thus, reduce the heavy metals bioavailability and mobility. This review also discussed the S/S evaluation methods, highlighted the need to enhance S/S technology in the molecular bonding, soil polymers, and formulation of China's S/S technical guidelines.

  11. SITE TECHNOLOGY CAPSULE: NOVOCS EVALUATION AT NAS NORTH ISLAND

    Science.gov (United States)

    This is a SITE Technology Capsule. The MACTEC, Inc. (MACTEC), NoVOCs(TM) in-well volatile organic compounds (VOC) stripping technology is an in-situ groundwater remediation technology designed for the cleanup of groundwater contaminated with VOCs. The NoVOCs(TM) technology was ev...

  12. Bioaugmentation for Groundwater Remediation

    Science.gov (United States)

    2010-02-01

    fermentation , cells in the fermentation broth were concentrated by passing the broth over a custom-built cell concentrator constructed with 6...2A and 2B, the finished fermentation broth can contain relatively high concentrations of volatile fatty acids that can be co- injected with the...injection permit applications. More importantly, some fermentation broths may contain residual levels of chlorinated solvents or daughter products such

  13. Groundwater Monitoring Plan for the Reactor Technology Complex Operable Unit 2-13

    Energy Technology Data Exchange (ETDEWEB)

    Richard P. Wells

    2007-03-23

    This Groundwater Monitoring Plan describes the objectives, activities, and assessments that will be performed to support the on-going groundwater monitoring requirements at the Reactor Technology Complex, formerly the Test Reactor Area (TRA). The requirements for groundwater monitoring were stipulated in the Final Record of Decision for Test Reactor Area, Operable Unit 2-13, signed in December 1997. The monitoring requirements were modified by the First Five-Year Review Report for the Test Reactor Area, Operable Unit 2-13, at the Idaho National Engineering and Environmental Laboratory to focus on those contaminants of concern that warrant continued surveillance, including chromium, tritium, strontium-90, and cobalt-60. Based upon recommendations provided in the Annual Groundwater Monitoring Status Report for 2006, the groundwater monitoring frequency was reduced to annually from twice a year.

  14. Assessment of technologies for hazardous waste site remediation: Non-treatment technologies and pilot scale facility implementation -- excavation -- storage technology -- safety analysis and review statement. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, H.R.; Overbey, W.K. Jr.; Koperna, G.J. Jr.

    1994-02-01

    The purpose of this study is to assess the state-of-the-art of excavation technology as related to environmental remediation applications. A further purpose is to determine which of the excavation technologies reviewed could be used by the US Corp of Engineers in remediating contaminated soil to be excavated in the near future for construction of a new Lock and Dam at Winfield, WV. The study is designed to identify excavation methodologies and equipment which can be used at any environmental remediation site but more specifically at the Winfield site on the Kanawha River in Putnam County, West Virginia. A technical approach was determined whereby a functional analysis was prepared to determine the functions to be conducted during the excavation phase of the remediation operations. A number of excavation technologies were identified from the literature. A set of screening criteria was developed that would examine the utility and ranking of the technologies with respect to the operations that needed to be conducted at the Winfield site. These criteria were performance, reliability, implementability, environmental safety, public health, and legal and regulatory compliance. The Loose Bulk excavation technology was ranked as the best technology applicable to the Winfield site. The literature was also examined to determine the success of various methods of controlling fugitive dust. Depending upon any changes in the results of chemical analyses, or prior remediation of the VOCs from the vadose zone, consideration should be given to testing a new ``Pneumatic Excavator`` which removes the VOCs liberated during the excavation process as they outgas from the soil. This equipment however would not be needed on locations with low levels of VOC emissions.

  15. The Application of Nano-Sized Zero-Valent Iron for In Situ Remediation of Chlorinated Ethylenes in Groundwater: A Field Case Study.

    Science.gov (United States)

    Lacina, Petr; Dvorak, Vojtech; Vodickova, Eva; Barson, Prokop; Kalivoda, Josef; Goold, Scott

    2015-04-01

    In this paper, the authors present the pilot in situ application of nano zero-valent iron (nZVI) for effective remediation of groundwater in an industrial area contaminated by chlorinated ethylenes (CEs), which create a significant group of global environmental contaminants. This work covers the entire 1-year remediation process, including systematic laboratory tests and field application techniques for nZVI. The application was carried out in the area of a metal fabrication industrial facility in the Czech Republic. Contamination of CEs in this area is a consequence of old ecological loads. The entire remediation process contained the following steps: monitoring of the area, selection of the most relevant hot spot, selection of the most appropriate application borehole, systematic laboratory tests, application of nZVI, and postapplication monitoring. Ten kilograms of nZVI were applied as a water suspension into the selected borehole. Significant decreases in concentrations of selected contaminants were observed in the first month after application. The reaction in the borehole was completed within approximately 5 to 6 months after the application and during this period almost 50% elimination of contamination was achieved.

  16. Evaluation of Bioaugmentation with Entrapped Degrading Cells as a Soil Remediation Technology

    DEFF Research Database (Denmark)

    Owsianiak, Mikolaj; Dechesne, Arnaud; Binning, Philip John

    2010-01-01

    Soil augmentation with microbial degraders immobilized on carriers is evaluated as a potential remediation technology using a mathematical model that includes degradation within spatially distributed carriers and diffusion or advectiondispersion as contaminant mass transfer mechanisms. The total...... to determine whether the spatially distributed model is required. Results show that field scale applications of immobilized degraders will be limited by the amount of carriers required to reach acceptable degradation rates....... degraders have low intrinsic degradation rates and that only limited carrier to soil volume ratios are practically feasible, bioaugmented soils are characterized by low effective degradation ratesandcanbeconsidered fully mixed. A simple exponential model is then sufficient to predict biodegradation...

  17. Salinity Impacts of the Indian Ocean Tsunami on Groundwater and Local Water Supply - Lessons Learned from Integrated Research and Support to Remediation

    Science.gov (United States)

    Villholth, K. G.; Vithanage, M.; Goswami, R. R.; Jeyakumar, P.; Manamperi, S.

    2008-05-01

    Huge devastation and human tragedy followed the Dec. 26, 2004 tsunami in the Indian Ocean. Sri Lanka was one of the hardest hit, with an estimated death toll of 31,000 people. Of immediate concern after the catastrophic event was the destruction of the traditional water supply system based on private shallow open wells in the rural and semi-urban areas of the coastal belt. Practically all wells within the reach of the flooding waves (up to a couple of km's inland) were inundated and filled with saltwater and contaminated with solid matter, pathogens, and other unknown chemicals, leaving the water unfit for drinking. It was estimated early on that the tsunami waves contaminated more than 50,000 wells in coastal Sri Lanka. This initial figure is highly underestimated, however, as the present research found that the total number of affected wells was more in the range of half a million. The total number of people affected by disruption in well water supply could have been in the range of 2.5 million. The present paper summarizes the outcomes and experiences gained from comprehensive research, collaboration and support work in eastern Sri Lanka related to the impact of the tsunami on groundwater, particularly with respect to salinity, and the destruction and rehabilitation of the local water supply systems. The area in focus was characterized by sandy, shallow, unconfined aquifers bounded by seawater and inland brackish lagoons and representative of the hydro-geological, climatic, demographic and land use setting on the east coast of Sri Lanka. Field monitoring investigations in shallow domestic wells showed that the salinity imprint of the tsunami on groundwater and water supply were detectable up to 1.5 years after the event. Field results also indicated that the well cleaning efforts which were quickly resorted to as part of the emergency and remediation activities were not efficient in terms of reducing salinity impacts. Rainfall was the most significant and

  18. Remediation of petroleum hydrocarbon-contaminated sites by DNA diagnosis-based bioslurping technology.

    Science.gov (United States)

    Kim, Seungjin; Krajmalnik-Brown, Rosa; Kim, Jong-Oh; Chung, Jinwook

    2014-11-01

    The application of effective remediation technologies can benefit from adequate preliminary testing, such as in lab-scale and Pilot-scale systems. Bioremediation technologies have demonstrated tremendous potential with regards to cost, but they cannot be used for all contaminated sites due to limitations in biological activity. The purpose of this study was to develop a DNA diagnostic method that reduces the time to select contaminated sites that are good candidates for bioremediation. We applied an oligonucleotide microarray method to detect and monitor genes that lead to aliphatic and aromatic degradation. Further, the bioremediation of a contaminated site, selected based on the results of the genetic diagnostic method, was achieved successfully by applying bioslurping in field tests. This gene-based diagnostic technique is a powerful tool to evaluate the potential for bioremediation in petroleum hydrocarbon contaminated soil.

  19. Fiscal Year 2009 Annual Report for Operable Unit 3-14, Tank Farm Soil and INTEC Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Forsythe, Howard S.

    2010-04-10

    This annual report summarizes maintenance, monitoring, and inspection activities performed to implement the selected remedy for Waste Area Group 3, Operable Unit 3-14, Tank Farm soil and groundwater at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory Site. Results from monitoring perched water and groundwater at the Idaho Nuclear Technology and Engineering Center are also presented.

  20. [Groundwater].

    Science.gov (United States)

    González De Posada, Francisco

    2012-01-01

    From the perspective of Hydrogeology, the concept and an introductory general typology of groundwater are established. From the perspective of Geotechnical Engineering works, the physical and mathematical equations of the hydraulics of permeable materials, which are implemented, by electric analogical simulation, to two unique cases of global importance, are considered: the bailing during the construction of the dry dock of the "new shipyard of the Bahia de Cádiz" and the waterproofing of the "Hatillo dam" in the Dominican Republic. From a physical fundamental perspective, the theories which are the subset of "analogical physical theories of Fourier type transport" are related, among which the one constituted by the laws of Adolf Fick in physiology occupies a historic role of some relevance. And finally, as a philosophical abstraction of so much useful mathematical process, the one which is called "the Galilean principle of the mathematical design of the Nature" is dealt with.

  1. Can Homeopathic Arsenic Remedy Combat Arsenic Poisoning in Humans Exposed to Groundwater Arsenic Contamination?: A Preliminary Report on First Human Trial

    Directory of Open Access Journals (Sweden)

    Anisur Rahman Khuda-Bukhsh

    2005-01-01

    Full Text Available Groundwater arsenic (As has affected millions of people globally distributed over 20 countries. In parts of West Bengal (India and Bangladesh alone, over 100 million people are at risk, but supply of As-free water is grossly inadequate. Attempts to remove As by using orthodox medicines have mostly been unsuccessful. A potentized homeopathic remedy, Arsenicum Album-30, was administered to a group of As affected people and thereafter the As contents in their urine and blood were periodically determined. The activities of various toxicity marker enzymes and compounds in the blood, namely aspartate amino transferase, alanine amino transferase, acid phosphatase, alkaline phosphatase, lipid peroxidation and reduced glutathione, were also periodically monitored up to 3 months. The results are highly encouraging and suggest that the drug can alleviate As poisoning in humans.

  2. Long term fluctuations of groundwater mine pollution in a sulfide mining district with dry Mediterranean climate: Implications for water resources management and remediation.

    Science.gov (United States)

    Caraballo, Manuel A; Macías, Francisco; Nieto, José Miguel; Ayora, Carlos

    2016-01-01

    Water resources management and restoration strategies, and subsequently ecological and human life quality, are highly influenced by the presence of short and long term cycles affecting the intensity of a targeted pollution. On this respect, a typical acid mine drainage (AMD) groundwater from a sulfide mining district with dry Mediterranean climate (Iberian Pyrite Belt, SW Spain) was studied to unravel the effect of long term weather changes in water flow rate and metal pollutants concentration. Three well differentiated polluting stages were observed and the specific geochemical, mineralogical and hydrological processes involved (pyrite and enclosing rocks dissolution, evaporitic salts precipitation-redisolution and pluviometric long term fluctuations) were discussed. Evidencing the importance of including longer background monitoring stage in AMD management and restoration strategies, the present study strongly advise a minimum 5-years period of AMD continuous monitoring previous to the design of any AMD remediation system in regions with dry Mediterranean climate. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Hybrid life cycle assessment comparison of colloidal silica and cement grouted soil barrier remediation technologies.

    Science.gov (United States)

    Gallagher, Patricia M; Spatari, Sabrina; Cucura, Jeffrey

    2013-04-15

    Site remediation involves balancing numerous costs and benefits but often neglects the environmental impacts over the entire project life cycle. Life cycle assessment (LCA) offers a framework for inclusion of global environmental "systems-level" decision metrics in combination with technological and cost analysis. We compare colloidal silica (CS) and cement grouted soil barrier remediation technologies for soils affected by low level radionuclides at a U.S. Superfund site using hybrid LCA methods. CS is a new, high performance grouting material installed using permeation grouting techniques. Cement, a more traditional grouting material, is typically installed using jet grouting techniques. Life cycle impacts were evaluated using the US EPA TRACI 2 model. Results show the highest life cycle environmental impacts for the CS barrier occur during materials production and transportation to the site. In general, the life cycle impacts for the cement barrier were dominated by materials production; however, in the extreme scenario the life cycle impacts were dominated by truck transportation of spoils to a distant, off-site radioactive waste facility. It is only in the extreme scenario tested in which soils are transported by truck (Option 2) that spoils waste transport dominates LCIA results. Life cycle environmental impacts for both grout barriers were most sensitive to resource input requirements for manufacturing volumes and transportation. Uncertainty associated with the efficacy of new technology such as CS over its required design life indicates that barrier replacement could increase its life cycle environmental impact above that of the cement barrier. Copyright © 2013 Elsevier B.V. All rights reserved.

  4. Work plan for the remedial investigation/feasibility study for the groundwater operable units at the Chemical Plant Area and the Ordnance Works Area, Weldon Spring, Missouri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    US Department of Energy (DOE) and the US Army Corps of Engineers (CE) are conducting cleanup activities at two properties, the chemical plant area and the ordnance works area, located adjacent to one another in St. Charles County, Missouri. In accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended, DOE and CE are evaluating conditions and potential responses at the chemical plant area and at the ordnance works area, respectively, to address groundwater and surface water contamination. This work plan provides a comprehensive evaluation of areas that are relevant to the (GWOUs) of both the chemical plant and the ordnance works area. Following areas or media are addressed in this work plan: groundwater beneath the chemical plant area (including designated vicinity properties described in Section 5 of the RI for the chemical plant area [DOE 1992d]) and beneath the ordnance works area; surface water and sediment at selected springs, including Burgermeister Spring. The organization of this work plan is as follows: Chapter 1 discusses the objectives for conducting the evaluation, including a summary of relevant site information and overall environmental compliance activities to be undertaken; Chapter 2 presents a history and a description of the site and areas addressed within the GWOUs, along with currently available data; Chapter 3 presents a preliminary evaluation of areas included in the GWOUs, which is based on information given in Section 2, and discusses data requirements; Chapter 4 presents rationale for data collection or characterization activities to be carried out in the remedial investigation (RI) phase, along with brief summaries of supporting documents ancillary to this work plan; Chapter 5 discusses the activities planned for GWOUs under each of the 14 tasks for an remedial (RI/FS); Chapter 6 presents proposed schedules for RI/FS for the GWOUS; and Chapter 7 explains the project management structure.

  5. Potential applications of surface active compounds by Gordonia sp. strain BS29 in soil remediation technologies.

    Science.gov (United States)

    Franzetti, Andrea; Caredda, Paolo; Ruggeri, Claudio; La Colla, Paolo; Tamburini, Elena; Papacchini, Maddalena; Bestetti, Giuseppina

    2009-05-01

    A wide range of structurally different surface active compounds (SACs) is synthesised by many prokaryotic and eukaryotic microorganisms. Due to their properties, microbial SACs have been exploited in environmental remediation techniques. From a diesel-contaminated soil, we isolated the Gordonia sp. strain BS29 which extensively grows on aliphatic hydrocarbons and produces two different types of SACs: extracellular bioemulsans and cell-bound biosurfactants. The aim of this work was to evaluate the potential applications of the strain BS29 and its SACs in the following environmental technologies: bioremediation of soils contaminated by aliphatic and aromatic hydrocarbons, and washing of soils contaminated by crude oil, polycyclic aromatic hydrocarbons (PAHs) and heavy metals. Microcosm bioremediation experiments were carried out with soils contaminated by aliphatic hydrocarbons or PAHs, while batch soil washing experiments were carried out with soils contaminated by crude oil, PAHs or heavy metals. Bioremediation results showed that the BS29 bioemulsans are able to slightly enhance the biodegradation of recalcitrant branched hydrocarbons. On the other hand, we obtained the best results in soil washing of hydrocarbons. The BS29 bioemulsans effectively remove crude oil and PAHs from soil. Particularly, crude oil removal by BS29 bioemulsans is comparable to the rhamnolipid one in the same experimental conditions showing that the BS29 bioemulsans are promising washing agents for remediation of hydrocarbon-contaminated soils.

  6. Smouldering Remediation (STAR) Technology: Field Pilot Tests and First Full Scale Application

    Science.gov (United States)

    Gerhard, J.; Kinsman, L.; Torero, J. L.

    2015-12-01

    STAR (Self-sustaining Treatment for Active Remediation) is an innovative remediation technology based on the principles of smoldering combustion where the contaminants are the fuel. The self-sustaining aspect means that a single, local ignition event can result in many days of contaminant destruction in situ. Presented research to date has focused on bench scale experiments, numerical modelling and process understanding. Presented here is the maturation of the in situ technology, including three field pilot tests and a full-scale implementation to treat coal tar-impacted soils. The first pilot determined a Radius of Influence (ROI) for a single ignition of approximately eight feet with an average propagation rate of the reaction of approximately one foot per day. TPH concentrations in soils were reduced from 10,000 milligrams per kilogram to a few hundred milligrams per kilogram. The second pilot was conducted in an area of significant void spaces created through the anthropogenic deposition of clay bricks and tiles. The void spaces led to pre-mature termination of the combustion reaction, limiting ROI and the effectiveness of the technology in this setting. The third case study involved the pilot testing, design, and full-scale implementation of STAR at a 37-acre former chemical manufacturing facility. Three phases of pilot testing were conducted within two hydrogeologic units at the site (i.e., surficial fill and deep alluvial sand units). Pilot testing within the fill demonstrated self-sustained coal tar destruction rates in excess of 800 kg/day supported through air injection at a single well. Deep sand unit testing (twenty-five feet below the water table) resulted in the treatment of a targeted six-foot layer of impacted fine sands to a radial distance of approximately twelve feet. These results (and additional parameters) were used to develop a full-scale STAR design consisting of approximately 1500 surficial fill ignition points and 500 deep sand ignition

  7. Remediation of actual groundwater polluted with nitrate by the catalytic reduction over copper-palladium supported on active carbon

    OpenAIRE

    Wang, Yi; Sakamoto, Yoshinori; Kamiya, Yuichi

    2009-01-01

    Catalytic reduction of nitrate (NO3-) in groundwater over a Cu-Pd catalyst supported on active carbon was investigated in a gas-liquid co-current flow system at 298 K. Although Cu-Pd/active carbon, in which the Cu/Pd molar ratio was more than 0.66, showed high activity, high selectivity for the formation of N2 and N2O (98%), and high durability for the reduction of 100 ppm NO3- in distilled water, the catalytic performance decreased during the reduction of NO3- in groundwater. The catalyst al...

  8. Injectable silica-permanganate gel as a slow-release MnO4(-) source for groundwater remediation: rheological properties and release dynamics.

    Science.gov (United States)

    Yang, S; Oostrom, M; Truex, M J; Li, G; Zhong, L

    2016-02-01

    Injectable slow-release permanganate gels (ISRPGs), formed by mixing aqueous KMnO4 solution with fumed silica powders, may have potential applications in remediating chlorinated solvent plumes in groundwater. A series of batch, column, and two-dimensional (2-D) flow cell experiments has been completed to characterize the ISRPG and study the release of permanganate (MnO4(-)) under a variety of conditions. The experiments have provided information on ISRPG rheology, MnO4(-) release dynamics and distribution in porous media, and trichloroethene (TCE) destruction by the ISRPG-released oxidant. The gel possesses shear thinning characteristics, resulting in a relatively low viscosity during mixing, and facilitating subsurface injection and distribution. Batch tests clearly showed that MnO4(-) diffused out from the ISRPG into water. During this process, the gel did not dissolve or disperse into water, but rather maintained its initial shape. Column experiments demonstrated that MnO4(-) release from the ISRPG lasted considerably longer than that from an aqueous solution. In addition, due to the longer release duration, TCE destruction by ISRPG-released MnO4(-) was considerably more effective than that when MnO4(-) was delivered using aqueous solution injection. In the 2-D flow cell experiments, it was demonstrated that ISRPGs released a long-lasting, low-concentration MnO4(-) plume potentially sufficient for sustainable remediation in aquifers.

  9. Alternative technologies for remediation of technogenic barrens in the Kola Subarctic

    Science.gov (United States)

    Koptsik, G. N.; Koptsik, S. V.; Smirnova, I. E.

    2016-11-01

    The efficiency of remediation of technogenic barrens under the reduction of air pollutant emissions from the Severonikel smelter in the Kola Subarctic is determined largely by the soil state and the technology applied. The covering of the contaminated soils with artificially made material based on organomineral substrates and the following liming and fertilization promoted a sharp and long-term reduction of acidity, decrease in the biological availability of heavy metals, increase in the supply with nutrients, and improvement of the life state of willow and birch plantations. The effect of economically more profitable chemo-phytostabilization is short-term; it requires constant maintenance. Under the current production and a high level of soil contamination, repeated measures are required to optimize the soil reaction, supply with nutrients, and to correct the availability of heavy metals in the soils based on the results of continuous monitoring

  10. Applicability and modelling of nanofiltration and reverse osmosis for remediation of groundwater polluted with pesticides and pesticide transformation products

    DEFF Research Database (Denmark)

    Madsen, Henrik Tækker; Søgaard, Erik Gydesen

    2014-01-01

    The main body of research on pesticide removal with membranes has looked at pesticides used for pest control, but during transport from surface to groundwater aquifers, pesticides are transformed. Therefore the real polluting compounds are often transformation products, and this vastly increases ...

  11. Prediction of Groundwater Quality Down-gradient of In Situ Permeable Treatment Barriers and Fully-remediated Source Zones

    Science.gov (United States)

    2008-09-01

    About - 9975 ft on the Vertical Axis. Axis Units are [ft] and Elevations are in [ft above mean sea-level]. 31 4.3.3 Groundwater Quality Changes...ND-Non Detect; "--" No Sample Collected 9651 9975 9651 10011 9602 10034 DS33 DS 31 DS 30 9975 10034 9642 9642 DS 30 Repeat DS33 Well G- 6

  12. Field Tests of “In-Situ” Remediation of Groundwater From Dissolved Mercury Utilizing Sulfate Reducing Bacteria

    Science.gov (United States)

    Field tests of biologically active filters have been conducted at groundwater mercury pollution site in Pavlodar, Kazakhstan. The biofilters represented cultures of sulfate-reducing bacteria (SRB) immobilized on claydite imbedded in wells drilled down to basalt clay layer (14-17 ...

  13. Incorporation of Fixed Installation Costs into Optimization of Groundwater Remediation with a New Efficient Surrogate Nonlinear Mixed Integer Optimization Algorithm

    Science.gov (United States)

    Shoemaker, Christine; Wan, Ying

    2016-04-01

    Optimization of nonlinear water resources management issues which have a mixture of fixed (e.g. construction cost for a well) and variable (e.g. cost per gallon of water pumped) costs has been not well addressed because prior algorithms for the resulting nonlinear mixed integer problems have required many groundwater simulations (with different configurations of decision variable), especially when the solution space is multimodal. In particular heuristic methods like genetic algorithms have often been used in the water resources area, but they require so many groundwater simulations that only small systems have been solved. Hence there is a need to have a method that reduces the number of expensive groundwater simulations. A recently published algorithm for nonlinear mixed integer programming using surrogates was shown in this study to greatly reduce the computational effort for obtaining accurate answers to problems involving fixed costs for well construction as well as variable costs for pumping because of a substantial reduction in the number of groundwater simulations required to obtain an accurate answer. Results are presented for a US EPA hazardous waste site. The nonlinear mixed integer surrogate algorithm is general and can be used on other problems arising in hydrology with open source codes in Matlab and python ("pySOT" in Bitbucket).

  14. Remediation Technologies for Marine Oil Spills: A Critical Review and Comparative Analysis

    Directory of Open Access Journals (Sweden)

    D. Dave

    2011-01-01

    Full Text Available Problem statement: Anthropogenic activities pollute the oceans with oil through land run off, vessels accidents, periodic tanker discharges and bilge discharges. Oil spills are environmental disasters that impact human, plants and wild life including birds, fish and mammals. Approach: In this study, the International Guidelines for Preventing Oils Spills and Response to Disasters were reviewed and the characteristics of oil spills were discussed. The advantages and disadvantages of various oil spill response methods were evaluated. A comparative analysis were performed on the currently available remediation technologies using 10 evaluation criteria that included cost, efficiency, time, impact on wild life, reliability, level of difficulty, oil recovery, weather, effect on physical/chemical characteristics of oil and the need for further treatment. The advantages and disadvantages of each response method were used to determine the score assigned to that method. Results: There are many government regualtions for individual countries that serve as prevention mesures for oil spills in the offshore environment. They have to do with the design of equipment and machinery used in the offshore environment and performing the necessary safety inspections. The primary objectives of response to oil spill are: to prevent the spill from moving onto shore, reduce the impact on marine life and speed the degradation of any unrecovered oil. There are several physical, chemical, thermal and biological remediation technologies for oil spills including booms, skimmers, sorbents, dispersants, in-situ burning and bioremediation. Each technique has its advantages and disadvantages and the choice of a particular technique will depend on: type of oil, physical, biological and economical characteristics of the spill, location, weather and sea conditions, amount spilled and rate of spillage, depth of water column, time of the year and effectiveness of technique. Coclusion

  15. Identifying Effective Policy and Technologic Reforms for Sustainable Groundwater Management in Oman

    Science.gov (United States)

    Madani, K.; Zekri, S.; Karimi, A.

    2014-12-01

    Oman has gone through three decades of efforts aimed at addressing groundwater over-pumping and the consequent seawater intrusion. Example of measures adopted by the government since the 1990's include a vast subsidy program of irrigation modernization, a freeze on drilling new wells, delimitation of several no-drill zones, a crop substitution program, re-use of treated wastewater and construction of recharge dams. With no major success through these measures, the government laid the ground for water quotas by creating a new regulation in 1995. Nevertheless, groundwater quotas have not been enforced to date due to the high implementation and monitoring costs of traditional flow meters. This presentation discusses how sustainable groundwater management can be secured in Oman using a suit of policy and technologic reforms at a reasonable economic, political and practical cost. Data collected from farms with smart meters and low-cost wireless smart irrigation systems have been used to propose sustainable groundwater withdrawal strategies for Oman using a detailed hydro-economic model that couples a MODFLOW-SEAWAT model of the coastal aquifers with a dynamic profit maximization model. The hydro-economic optimization model was flexible to be run both as a social planner model to maximize the social welfare in the region, and as an agent-based model to capture the behavior of farmers interested in maximizing their profits independently. This flexibility helped capturing the trade-off between the optimality of the social planner solution developed at the system's level and its practicality (stability) with respect to the concerns and behaviors of the profit-maximizing farmers. The idetified promising policy and technolgical reforms for Oman include strict enforcement of groundwater quotas, smart metering, changing crop mixes, improving irrigation technologies, and revising geographical distribution of the farming activities. The presentation will discuss how different

  16. Geospatial Technologies for Groundwater Management in Aurangabad City

    Directory of Open Access Journals (Sweden)

    Manisha R.Mundhe

    2014-11-01

    Full Text Available The Aurangabad City is located in the heart of Maharashtra State an urban center of the Deccan sub-region. The water provided by the Aurangabad Municipal Corporation (AMC is not sufficient for the use of citizen. In this study, we have only considered the water resources available in the different area only in the Aurangabad city.All resources are mapped on the Google map/Google earth using KML platform. The Groundwater resources available in the Aurangabadare mapped in Google earth and detail availability of the water is provided. These ground water resources are divided into different Zones according to the availability of the water in that particular location. The spatial data of the available water resources according tothe area are mapped with all detail of the water available such as usage and different sources available along with their property so it's convenient for analysis the spatial data.

  17. PIMS(trademark): Remediation of Soil and Groundwater Contaminated With Metals. PIMS Remediation of Soil Contaminated with Lead at Camp Stanley Storage Activity, TX

    Science.gov (United States)

    2003-08-01

    epa.gov Federal Regulator Sonny Rayos Corrective Action Section Texas Commission on Environmental Quality MC-127, PO Box 13087 Austin, TX 78741-3087...Treatment Technology Brian K. Murphy, Environmental Officer, Camp Stanley Storage Activity, TX Mark Peterson, Parsons, Inc. Honolulu, HI Sonny Rayos

  18. ARCTIC FOUNDATIONS, INC. FREEZE BARRIER SYSTEM - SITE TECHNOLOGY CAPSULE

    Science.gov (United States)

    Arctic Foundations, Inc. (AFI), of Anchorage, Alaska has developed a freeze barrier technology designed to prevent the migration of contaminants in groundwater by completely isolating contaminant source areas until appropriate remediation techniques can be applied. With this tec...

  19. Compendium of ordinances for groundwater protection

    Energy Technology Data Exchange (ETDEWEB)

    1990-08-01

    Groundwater is an extremely important resource in the Tennessee Valley. Nearly two-thirds of the Tennessee Valley's residents rely, at least in part, on groundwater supplies for drinking water. In rural areas, approximately ninety-five percent of residents rely on groundwater for domestic supplies. Population growth and economic development increase the volume and kinds of wastes requiring disposal which can lead to groundwater contamination. In addition to disposal which can lead to groundwater contamination. In addition to disposal problems associated with increases in conventional wastewater and solid waste, technological advancements in recent decades have resulted in new chemicals and increased usage in agriculture, industry, and the home. Unfortunately, there has not been comparable progress in identifying the potential long-term effects of these chemicals, in managing them to prevent contamination of groundwater, or in developing treatment technologies for removing them from water once contamination has occurred. The challenge facing residence of the Tennessee Valley is to manage growth and economic and technological development in ways that will avoid polluting the groundwater resource. Once groundwater has been contaminated, cleanup is almost always very costly and is sometimes impractical or technically infeasible. Therefore, prevention of contamination -- not remedial treatment--is the key to continued availability of usable groundwater. This document discusses regulations to aid in this prevention.

  20. The Gunite Tanks Remediation Project at Oak Ridge National Laboratory; Successful Integration & Deployment of Technologies Results in Remediated Underground Storage Tanks

    Energy Technology Data Exchange (ETDEWEB)

    Billingsley, K.; Bolling, D.

    2002-02-27

    This paper presents an overview of the underground technologies deployed during the cleanup of nine large underground storage tanks (USTs) that contained residual radioactive sludge, liquid low-level waste (LLLW), and other debris. The Gunite Tanks Remediation Project at Oak Ridge National Laboratory (ORNL) was successfully completed in 2001, ending with the stabilization of the USTs and the cleanup of the South Tank Farm. This U.S. Department of Energy (DOE) project was the first of its kind completed in the United States of America. The Project integrated robotic and remotely operated technologies into an effective tank waste retrieval system that safely retrieved more than 348 m3 (92,000 gal) of radioactive sludge and 3.15E+15 Bq (85,000 Ci) of radioactive contamination from the tanks. The Project successfully transferred over 2,385 m3 (630,000 gal) of waste slurry to ORNL's active tank waste management system. The project team avoided over $120 Million in costs and shortened the original baseline schedule by over 10 years. Completing the Gunite Tanks Remediation Project eliminated the risks posed by the aging USTs and the waste they contained, and avoid the $400,000 annual costs associated with maintaining and monitoring the tanks.

  1. BioKonversion technology recovers, remediates and reuses waste and hydrocarbons from oil drilling

    Energy Technology Data Exchange (ETDEWEB)

    Topf, A.

    2008-01-15

    Houston-based Nopal Group has developed a solution to dispose of oilfield waste in a safe and cost-effective manner. The company is actively engaged in a large-scale project to remediate a 400-hectare site on the Aspheron Peninsula in Azerbaijan. The site is currently regarded as the most polluted place in the world after a century of oil extraction with little regard for the surrounding environment. The Nopal Group will use its patented BioKonversion technology, which cleanses the soil of hydrocarbons in a two-part process using a large machine known as the Green Machine. Several pipelines will need to be relocated, and ancient drilling rigs that have been there as long as 100 years will have to be dealt with. The cleanup cost has been estimated at between $20 million to $40 million, and will take between 18 and 36 months, depending on how deep into the ground the machines have to dig for hydrocarbons. The 90-foot by 40-foot machine processes drill cuttings, contaminated soil and drill fluids by first separating the dirt from the liquid hydrocarbons, which can be recycled or refined for resale. The remaining dirt, which still contains 3 to 7 percent oil, is then placed into a centrifuge and mixed with a heating agent and other elements, including naturally oleophilic kenaf powder. The process micronizes and absorbs hydrocarbons. Once the process is finished, the hydrocarbons are immediately non-detectable and non-leachable. The leftover benign dirt can be used as landfill cover, or mixed with road aggregate. BioKonversion can also be adapted for use on oil rigs. This article demonstrated that the process has clear advantages over traditional oilfield remediation methods such as land farming. Opportunities exist to utilize the process in Venezuela and Kuwait. 1 fig.

  2. Phytostabilization of Mine Tailings in Arid and Semiarid Environments—An Emerging Remediation Technology

    Science.gov (United States)

    Mendez, Monica O.; Maier, Raina M.

    2008-01-01

    Objective Unreclaimed mine tailings sites are a worldwide problem, with thousands of unvegetated, exposed tailings piles presenting a source of contamination for nearby communities. Tailings disposal sites in arid and semiarid environments are especially subject to eolian dispersion and water erosion. Phytostabilization, the use of plants for in situ stabilization of tailings and metal contaminants, is a feasible alternative to costly remediation practices. In this review we emphasize considerations for phytostabilization of mine tailings in arid and semiarid environments, as well as issues impeding its long-term success. Data sources We reviewed literature addressing mine closures and revegetation of mine tailings, along with publications evaluating plant ecology, microbial ecology, and soil properties of mine tailings. Data extraction Data were extracted from peer-reviewed articles and books identified in Web of Science and Agricola databases, and publications available through the U.S. Department of Agriculture, U.S. Environmental Protection Agency, and the United Nations Environment Programme. Data synthesis Harsh climatic conditions in arid and semiarid environments along with the innate properties of mine tailings require specific considerations. Plants suitable for phytostabilization must be native, be drought-, salt-, and metal-tolerant, and should limit shoot metal accumulation. Factors for evaluating metal accumulation and toxicity issues are presented. Also reviewed are aspects of implementing phytostabilization, including plant growth stage, amendments, irrigation, and evaluation. Conclusions Phytostabilization of mine tailings is a promising remedial technology but requires further research to identify factors affecting its long-term success by expanding knowledge of suitable plant species and mine tailings chemistry in ongoing field trials. PMID:18335091

  3. A Fundamental study of remedial technology development to prevent stress corrosion cracking of steam generator tubing

    Energy Technology Data Exchange (ETDEWEB)

    Park, In Gyu; Lee, Chang Soon [Sunmoon University, Asan (Korea)

    1998-04-01

    Most of the PWR Steam generators with tubes in Alloy 600 alloy are affected by Stress Corrosion Cracking, such as PWSCC(Primary Water Stress Corrosion Cracking) and ODSCC(Outside Diameter Stress Corrosion Cracking). This study was undertaken to establish the background for remedial technology development to prevent SCC. in the report are included the following topics: (1) General: (i) water chemistry related factors, (ii) Pourbaix(Potential-pH) Diagram, (iii) polarization plot, (iv) corrosion mode of Alloy 600, 690, and 800, (v) IGA/SCC growth rate, (vi) material suspetibility of IGA/SCC, (vii) carbon solubility of Alloy 600 (2) Microstructures of Alloy 600 MA, Alloy 600 TT, Alloy 600 SEN Alloy 690 TT(Optical, SEM, and TEM) (3) Influencing factors for PWSCC initiation rate of Alloy 600: (i) microstructure, (ii) water chemistry(B, Li), (iii) temperature, (iv) plastic deformation, (v) stress relief annealing (4) Influencing factors for PWSCC growth rate of Alloy 600: (i) water chemistry(B, Li), (ii) Scott Model, (iii) intergranular carbide, (iv) temperature, (v) hold time (5) Laboratory conditions for ODSCC initiation rate: 1% NaOH, 316 deg C; 1% NaOH, 343 deg C; 50% NaOH, 288 deg C; 10% NaOH, 302 deg C; 10% NaOH, 316 deg C; 50% NaOH, 343 deg C (6) Sludge effects for ODSCC initiation rate: CuO, Cr{sub 2}O{sub 3}, Fe{sub 3}O{sub 4} (7) Influencing factors for PWSCC growth rate of Alloy 600: (i) Caustic concentration effect, (ii) carbonate addition effect (8) Sulfate corrosion: (i) sulfate ratio and pH effect, (ii) wastage rate of Alloy 600 and Alloy 690 (9) Crevice corrosion: (i) experimental setup for crevice corrosion, (ii) organic effect, (iii) (Na{sub 2}SO{sub 4} + NaOH) effect (10) Remedial measures for SCC: (i) Inhibitors, (ii) ZnO effect. (author). 30 refs., 174 figs., 51 tabs.

  4. Electrokinetic-Fenton technology for the remediation of hydrocarbons historically polluted sites.

    Science.gov (United States)

    Sandu, Ciprian; Popescu, Marius; Rosales, Emilio; Bocos, Elvira; Pazos, Marta; Lazar, Gabriel; Sanromán, M Angeles

    2016-08-01

    The feasibility of the electrokinetic-Fenton technology coupled with surfactants in the treatment of real historically hydrocarbons polluted soils has been studied. The characterisation of these soils from Spain and Romania was performed and identified as diesel and diesel-motor oil spillages, respectively. Moreover, the ageing of the spillages produced by the soil contamination was estimated showing the historical pollution of the sites (around 11 and 20 years for Romanian and Spanish soils, respectively). An ex-situ electrochemical treatment was performed to evaluate the adequacy of surfactants for the degradation of the hydrocarbons present in the soils. It was found an enhancement in the solubilisation and removal of TPHs with percentages increasing from 25.7 to 81.8% by the presence of Tween 80 for Spanish soil and from 15.1% to 71.6% for Triton X100 in Romanian soil. Therefore, the viability of coupling enhanced electrokinetic and Fenton remediation was evaluated through a simulated in-situ treatment at laboratory scale. The results demonstrated that the addition of the selected surfactants improved the solubilisation of the hydrocarbons and influenced the electroosmotic flow with a slight decrease. The efficiency of the treatment increased for both considered soil samples and a significant degradation level of the hydrocarbons compounds was observed. Buffering of pH coupled with the addition of a complexing agent showed to be important in the treatment process, facilitating the conditions for the degradation reactions that take place into the soil matrix. The results demonstrated the effectiveness of the selected techniques for remediation of the investigated soils. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Study on shallow groundwater information extraction technology based on multi-spectral data and spatial data

    Institute of Scientific and Technical Information of China (English)

    YU DeHao; DENG ZhengDong; LONG Fan; GUAN HongJun; WANG DaQing; GOU YiZheng

    2009-01-01

    Aimed at solving the difficulties, such as low efficiency and limited exploration range encountered in finding groundwater with the traditional methods, a new method was presented by using remote sensing technology in this paper. Based on multi-spectral data (ETM data) and spatial data (SRTM data),a forecasting model was built to produce a probability rating map for finding shallow groundwater in the arid and semi-arid areas. According to investigations, a conclusion is drawn that the results of the model are satisfied, which have been testified by the later geophysical exploration and drilling. Thus,the model can serve as a guide for finding groundwater in the arid and semi-arid regions.

  6. Study on shallow groundwater information extraction technology based on multi-spectral data and spatial data

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Aimed at solving the difficulties,such as low efficiency and limited exploration range encountered in finding groundwater with the traditional methods,a new method was presented by using remote sensing technology in this paper.Based on multi-spectral data(ETM data) and spatial data(SRTM data),a forecasting model was built to produce a probability rating map for finding shallow groundwater in the arid and semi-arid areas.According to investigations,a conclusion is drawn that the results of the model are satisfied,which have been testified by the later geophysical exploration and drilling.Thus,the model can serve as a guide for finding groundwater in the arid and semi-arid regions.

  7. Ground-water, surface-water, and bottom-sediment contamination in the O-field area, Aberdeen Proving Ground, Maryland, and the possible effects of selected remedial actions on ground water

    Science.gov (United States)

    Vroblesky, Don A.; Lorah, Michelle M.; Oliveros, James P.

    1995-01-01

    Disposal of munitions and chemical-warfare substances has introduced inorganic and organic contaminants to the ground water, surface water, and bottom sediment at O-Field, in the Edgewood area of Aberdeen Proving Ground, Maryland. Contaminants include chloride, arsenic, transition metals, chlorinated aliphatic hydrocarbons, aromatic compounds, and organosulfur and organophosphorus compounds. The hydrologic effects of several remedial actions were estimated by use of a ground-water-flow model. The remedial actions examined were an impermeable covering, encapsulation, subsurface barriers, a ground-water drain, pumping of wells to manage water levels or to remove contaminated ground water for treatment, and no action.

  8. Application of electro-Fenton technology to remediation of polluted effluents by self-sustaining process.

    Science.gov (United States)

    Fernández de Dios, Maria Ángeles; Iglesias, Olaia; Pazos, Marta; Sanromán, Maria Ángeles

    2014-01-01

    The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel cells (MFCs) were designed in order to supply electricity to electro-Fenton processes and to achieve high treatment efficiency at low cost. Initially, the effect of key parameters on the MFC power generation was evaluated. Afterwards, the degradation of Reactive Black 5 dye and phenanthrene was evaluated in an electro-Fenton reactor, containing iron-enriched zeolite as catalyst, using the electricity supplied by the MFC. Near complete dye decolourization and 78% of phenanthrene degradation were reached after 90 min and 30 h, respectively. Furthermore, preliminary reusability tests of the developed catalyst showed high degradation levels for successive cycles. The results permit concluding that the integrated system is adequate to achieve high treatment efficiency with low electrical consumption.

  9. Application of Electro-Fenton Technology to Remediation of Polluted Effluents by Self-Sustaining Process

    Directory of Open Access Journals (Sweden)

    Maria Ángeles Fernández de Dios

    2014-01-01

    Full Text Available The applicability of electro-Fenton technology to remediation of wastewater contaminated by several organic pollutants such as dyes and polycyclic aromatic hydrocarbons has been evaluated using iron-enriched zeolite as heterogeneous catalyst. The electro-Fenton technology is an advanced oxidation process that is efficient for the degradation of organic pollutants, but it suffers from the high operating costs due to the need for power investment. For this reason, in this study microbial fuel cells (MFCs were designed in order to supply electricity to electro-Fenton processes and to achieve high treatment efficiency at low cost. Initially, the effect of key parameters on the MFC power generation was evaluated. Afterwards, the degradation of Reactive Black 5 dye and phenanthrene was evaluated in an electro-Fenton reactor, containing iron-enriched zeolite as catalyst, using the electricity supplied by the MFC. Near complete dye decolourization and 78% of phenanthrene degradation were reached after 90 min and 30 h, respectively. Furthermore, preliminary reusability tests of the developed catalyst showed high degradation levels for successive cycles. The results permit concluding that the integrated system is adequate to achieve high treatment efficiency with low electrical consumption.

  10. Remediation trials for hydrocarbon-contaminated sludge from a soil washing process: evaluation of bioremediation technologies.

    Science.gov (United States)

    Frutos, F J García; Pérez, R; Escolano, O; Rubio, A; Gimeno, A; Fernandez, M D; Carbonell, G; Perucha, C; Laguna, J

    2012-01-15

    The usual fate of highly contaminated fine products (silt-clay fractions) from soil washing plants is disposal in a dump or thermal destruction (organic contaminants), with consequent environmental impacts. Alternative treatments for these fractions with the aim of on-site reuse are needed. Therefore, the feasibility of two technologies, slurry bioremediation and landfarming, has been studied for the treatment of sludge samples with a total petroleum hydrocarbon (TPH) content of 2243 mg/kg collected from a soil washing plant. The treatability studies were performed at the laboratory and pilot-real scales. The bioslurry assays yielded a TPH reduction efficiency of 57% and 65% in 28 days at the laboratory and pilot scale, respectively. In the landfarming assays, a TPH reduction of 85% in six months was obtained at laboratory scale and 42% in three months for the bioremediation performed in the full-scale. The efficiency of these processes was evaluated by ecotoxicity assessments. The toxic effects in the initial sludge sample were very low for most measured parameters. After the remediation treatments, a decrease in toxic effects was observed in earthworm survival and in carbon mineralisation. The results showed the applicability of two well known bioremediation technologies on these residues, this being a novelty.

  11. Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project) Quality Assurance Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    Fix, N. J.

    2008-02-20

    The scope of the Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project) is to provide technical and integration support to Fluor Hanford, Inc., including operable unit investigations at 300-FF-5 and other groundwater operable units, strategic integration, technical integration and assessments, remediation decision support, and science and technology. This Quality Assurance Management Plan provides the quality assurance requirements and processes that will be followed by the Fluor Hanford, Inc. Groundwater and Technical Integration Support (Master Project).

  12. Remediation of trichloroethylene-contaminated soils by star technology using vegetable oil smoldering

    OpenAIRE

    Salman, Madiha; Gerhard, Jason I.; Major, David W.; Pironi, Paolo; Hadden, Rory

    2015-01-01

    Self-sustaining treatment for active remediation (STAR) is an innovative soil remediation approach based on smoldering combustion that has been demonstrated to effectively destroy complex hydrocarbon nonaqueous phase liquids (NAPLs) with minimal energy input. This is the first study to explore the smoldering remediation of sand contaminated by a volatile NAPL (trichloroethylene, TCE) and the first to consider utilizing vegetable oil as supplemental fuel for STAR. Thirty laboratory-scale exper...

  13. Nuclear facility decommissioning and site remedial actions: A selected bibliography, Volume 18. Part 1B: Citations with abstracts, sections 10 through 16

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    This bibliography contains 3,638 citations with abstracts of documents relevant to environmental restoration, nuclear facility decontamination and decommissioning (D and D), uranium mill tailings management, and site remedial actions. The bibliography contains scientific, technical, financial, and regulatory information that pertains to DOE environmental restoration programs. The citations are separated by topic into 16 sections, including (1) DOE Environmental Restoration Program; (2) DOE D and D Program; (3) Nuclear Facilities Decommissioning; (4) DOE Formerly Utilized sites Remedial Action Program; (5) NORM-Contaminated Site Restoration; (6) DOE Uranium Mill Tailings Remedial Action Project; (7) Uranium Mill Tailings Management; (8) DOE Site-Wide Remedial Actions; (9) DOE Onsite Remedial Action Projects; (10) Contaminated Site Remedial Actions; (11) DOE Underground Storage Tank Remediation; (12) DOE Technology Development, Demonstration, and Evaluation; (13) Soil Remediation; (14) Groundwater Remediation; (15) Environmental Measurements, Analysis, and Decision-Making; and (16) Environmental Management Issues.

  14. Nuclear facility decommissioning and site remedial actions: A selected bibliography, Volume 18. Part 1A: Citations with abstracts, sections 1 through 9

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    This bibliography contains 3,638 citations with abstracts of documents relevant to environmental restoration, nuclear facility decontamination and decommissioning (D and D), uranium mill tailings management, and site remedial actions. The bibliography contains scientific, technical, financial, and regulatory information that pertains to DOE environmental restoration programs. The citations are separated by topic into 16 sections, including (1) DOE Environmental Restoration program; (2) DOE D and D Program; (3) Nuclear Facilities Decommissioning; (4) DOE Formerly Utilized Sites Remedial Action Program; (5) NORM-Contaminated Site Restoration; (6) DOE Uranium Mill Tailings Remedial Action Project; (7) Uranium Mill Tailings Management; (8) DOE Site-Wide Remedial Actions; (9) DOE Onsite Remedial Action Projects; (10) Contaminated Site Remedial Actions; (11) DOE Underground Storage Tank Remediation; (12) DOE Technology Development, Demonstration, and Evaluation; (13) Soil Remediation; (14) Groundwater Remediation; (15) Environmental Measurements, Analysis, and Decision-Making; and (16) Environmental Management Issues.

  15. Petroleum hydrocarbon contaminated sites: a review of investigation and remediation regulations and processes

    Energy Technology Data Exchange (ETDEWEB)

    Epelbaum, Michel; Claudio, Jair R. [Bureau Veritas do Brasil Sociedade Classificadora e Certificadora Ltda., Sao Paulo, SP (Brazil)

    1993-12-31

    This paper discusses alternatives on remediation of petroleum hydrocarbon contaminated sites which include groundwater remediation techniques and soil remediation techniques. Finally, the work points out some trends of sites remediation in Brazil and abroad. 6 refs., 1 fig., 7 tabs.

  16. Coupling of bio-PRB and enclosed in-well aeration system for remediation of nitrobenzene and aniline in groundwater.

    Science.gov (United States)

    Liu, Na; Ding, Feng; Wang, Liu; Liu, Peng; Yu, Xiaolong; Ye, Kang

    2016-05-01

    A laboratory-scale bio-permeable reactive barrier (bio-PRB) was constructed and combined with enclosed in-well aeration system to treat nitrobenzene (NB) and aniline (AN) in groundwater. Batch-style experiments were first conducted to evaluate the effectiveness of NB and AN degradation, using suspension (free cells) of degrading consortium and immobilized consortium by a mixture of perlite and peat. The NB and AN were completely degraded in 4 mg L(-1) when the aeration system was applied into the bio-PRB system. The NB and AN were effectively removed when the aeration system was functional in the bio-PRB. The removal efficiency decreased when the aeration system malfunctioned for 20 days, thus indicating that DO was an important factor for the degradation of NB and AN. The regain of NB and AN removal after the malfunction indicates the robustness of degradation consortium. No original organics and new formed by-products were observed in the effluent. The results indicate that NB and AN in groundwater can be completely mineralized in a bio-PRB equipped with enclosed in-well aeration system and filled with perlite and peat attached with degrading consortium.

  17. Innovative uses of LIDAR technology to assist in the remediation of former coal mine sites

    Energy Technology Data Exchange (ETDEWEB)

    Macleod, G. [Conestoga-Rovers and Associates, Sydney, NS (Canada)

    2010-07-01

    In this study, LIDAR data were used to construct precise topographic digital elevation maps (DEMs) in order to identify potential sites for mine water discharges from the Sydney coalfield in Nova Scotia (NS). LIDAR technology was used to assist in remediation activities at the site by producing location and elevation data to define the surface of the earth and the heights of above-ground features. An analysis of the LIDAR DEMs showed subsidence features that were not observed using traditional aerial photography methods. Features included areas of subsidence over shallow mine workings, depressions over former shafts, and evidence of bootleg mines near seam outcrops. The study showed that preferential subsidence creates topographic differences that can be detected using DEMs. Mine pillars can be detected over mines at depths of more than 25 meters. The DEMs also detected former mine shafts by identifying slight ground depressions formed over back-filled shafts. The DEMs were also able to detect bootleg pits as shallow as 0.5 meters. The pits can provide areas for the migration of acid mine water. 3 refs., 5 figs.

  18. High quality coal extraction and environmental remediation of fine coal refuse ponds using advanced cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Mohanty, M.K.; Patwardhan, A. [Department of Mining Engineering, Southern Illinois University-Carbondale, Carbondale, Illinois (United States)

    1998-07-01

    A vast number of coal refuse ponds represent a significant economical resource base that are also considered to be environmentally harmful. Significant amounts of cleanable fine coal generally exist in the refuse ponds due to the inability of conventional technologies to effectively separate the fine coal from the associated gangue particles. In addition, acid generation, generally a result of pyrite oxidation, has potential to adversely affect the surrounding environment. An integrated processing strategy of simultaneously recovering high quality coal and pyrite-rich products from the treatment of a coal refuse pond slurry has been successfully evaluated using an advanced physical cleaning circuit. A clean coal product having ash and pyritic sulfur contents of 10.1% and 0.41% was recovered with a mass yield of nearly 49%. In addition, a pyrite-rich product containing nearly 83% of the coal pyrite particles present in the refuse pond material was generated for neutralization purposes for the environmental remediation of the slurry pond. 4 refs.

  19. Computational Enzymology and Organophosphorus Degrading Enzymes: Promising Approaches Toward Remediation Technologies of Warfare Agents and Pesticides.

    Science.gov (United States)

    Ramalho, Teodorico C; de Castro, Alexandre A; Silva, Daniela R; Silva, Maria Cristina; Franca, Tanos C C; Bennion, Brian J; Kuca, Kamil

    2016-01-01

    The re-emergence of chemical weapons as a global threat in hands of terrorist groups, together with an increasing number of pesticides intoxications and environmental contaminations worldwide, has called the attention of the scientific community for the need of improvement in the technologies for detoxification of organophosphorus (OP) compounds. A compelling strategy is the use of bioremediation by enzymes that are able to hydrolyze these molecules to harmless chemical species. Several enzymes have been studied and engineered for this purpose. However, their mechanisms of action are not well understood. Theoretical investigations may help elucidate important aspects of these mechanisms and help in the development of more efficient bio-remediators. In this review, we point out the major contributions of computational methodologies applied to enzyme based detoxification of OPs. Furthermore, we highlight the use of PTE, PON, DFP, and BuChE as enzymes used in OP detoxification process and how computational tools such as molecular docking, molecular dynamics simulations and combined quantum mechanical/molecular mechanics have and will continue to contribute to this very important area of research.

  20. Innovative fossil fuel fired vitrification technology for soil remediation. Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    Vortec has successfully completed Phase 1 of the ``Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation`` program. The Combustion and Melting System (CMS) has processed 7000 pounds of material representative of contaminated soil that is found at DOE sites. The soil was spiked with Resource Conservation and Recovery Act (RCRA) metals surrogates, an organic contaminant, and a surrogate radionuclide. The samples taken during the tests confirmed that virtually all of the radionuclide was retained in the glass and that it did not leach to the environment-as confirmed by both ANS 16.1 and Toxicity Characteristic Leaching Procedure (TCLP) testing. The organic contaminant, anthracene, was destroyed during the test with a Destruction and Removal Efficiency (DRE) of at least 99.99%. RCRA metal surrogates, that were in the vitrified product, were retained and did not leach to the environment as confirmed by the TCLP testing. Semi-volatile RCRA metal surrogates were captured by the Air Pollution Control (APC) system, and data on the amount of metal oxide particulate and the chemical composition of the particulate were established for use in the Phase 2 APC subsystem design.

  1. Assessment of Corrosion Characteristics and Development of Remedial Technologies in Nuclear Materials

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hong Pyo; Kim, J. S.; Lim, Y. S. (and others)

    2007-04-15

    In general, materials having superior resistance to corrosion are used for main components and structures in nuclear power plants (NPPs) to improve their safety. During long-term operations in the high temperature and pressure environment, however, localized-corrosion related degradations occur frequently in those materials, leading to unexpected shutdown of the plants. The unexpected shutdowns may lower the operating efficiency of the power generation and expand the repair period, which results in a huge economical loss. Moreover, since the damages may cause a leakage of the primary coolant that brings about a contamination by radioactive substances, the corrosion related degradations of structural materials have become a menace to the safety of NPPs. The steam generator tubes forming a boundary between the primary and secondary sides of NPPs are one of the main components that are most damaged by corrosion. Therefore, it is strongly required to verify the degradation mechanisms of Alloy 182 and Alloy 600 materials used in the steam generator tubes and primary systems, to establish remedial techniques for the degradations, to manage the damages, and to develop techniques for the extension of the plant's life. In this study, (1) the assessment techniques of corrosion damages were improved and the database of the obtained results were established. (2) The basic technologies of the management of corrosion damages were developed for the practical use. (3) The fundamental technologies for inhibition and repair of corrosion damages were also developed. The results of this project are applicable to the assessment, failure analysis and life estimation of the materials against corrosion damages. The assessment data obtained in this work are available for the technical references of the corrosion failures of components in NPPs during operation. Furthermore, it is applicable to establish materials design requirements, to establish the optimum operation condition and to

  2. Colloidal activated carbon for in-situ groundwater remediation--Transport characteristics and adsorption of organic compounds in water-saturated sediment columns.

    Science.gov (United States)

    Georgi, Anett; Schierz, Ariette; Mackenzie, Katrin; Kopinke, Frank-Dieter

    2015-08-01

    Colloidal activated carbon can be considered as a versatile adsorbent and carrier material for in-situ groundwater remediation. In analogy to other nanoremediation approaches, activated carbon colloids (ACC) can be injected into the subsurface as aqueous suspensions. Deposition of ACC on the sediment creates a sorption barrier against further spreading of hydrophobic pollutants. This study deals with the optimization of ACC and their suspensions with a focus on suspension stability, ACC mobility in saturated porous media and sorption efficiency towards organic contaminants. ACC with an appropriate particle size range (d50=0.8μm) were obtained from a commercial powdered activated carbon product by means of wet-grinding. Among the various methods tested for stabilization of ACC suspensions, addition of humic acid (HA) and carboxymethyl cellulose (CMC) showed the best results. Due to electrosteric stabilization by adsorption of CMC, suspensions remained stable even at high ACC concentrations (11gL(-1)) and conditions typical of very hard water (5mM divalent cations). Furthermore, CMC-stabilized ACC showed high mobility in a water-saturated sandy sediment column (filter coefficient λ=0.2m(-1)). Such mobility is a pre-requisite for in-situ installation of sorption or reaction barriers by simple injection-well or direct-push application of ACC suspensions. Column experiments with organic model compounds proved the efficacy of ACC deposits on sediment for contaminant adsorption and retardation under flow-through conditions.

  3. Application of a long-lasting colloidal substrate with pH and hydrogen sulfide control capabilities to remediate TCE-contaminated groundwater.

    Science.gov (United States)

    Sheu, Y T; Chen, S C; Chien, C C; Chen, C C; Kao, C M

    2015-03-02

    A long-lasting emulsified colloidal substrate (LECS) was developed for continuous carbon and nanoscale zero-valent iron (nZVI) release to remediate trichloroethylene (TCE)-contaminated groundwater under reductive dechlorinating conditions. The developed LECS contained nZVI, vegetable oil, surfactants (Simple Green™ and lecithin), molasses, lactate, and minerals. An emulsification study was performed to evaluate the globule droplet size and stability of LECS. The results show that a stable oil-in-water emulsion with uniformly small droplets (0.7 μm) was produced, which could continuously release the primary substrates. The emulsified solution could serve as the dispensing agent, and nZVI particles (with diameter 100-200 nm) were distributed in the emulsion evenly without aggregation. Microcosm results showed that the LECS caused a rapid increase in the total organic carbon concentration (up to 488 mg/L), and reductive dechlorination of TCE was significantly enhanced. Up to 99% of TCE (with initial concentration of 7.4 mg/L) was removed after 130 days of operation. Acidification was prevented by the production of hydroxide ion by the oxidation of nZVI. The formation of iron sulfide reduced the odor from produced hydrogen sulfide. Microbial analyses reveal that dechlorinating bacteria existed in soils, which might contribute to TCE dechlorination.

  4. Field Test Report: Preliminary Aquifer Test Characterization Results for Well 299-W15-225: Supporting Phase I of the 200-ZP-1 Groundwater Operable Unit Remedial Design

    Energy Technology Data Exchange (ETDEWEB)

    Spane, Frank A.; Newcomer, Darrell R.

    2009-09-23

    This report examines the hydrologic test results for both local vertical profile characterization and large-scale hydrologic tests associated with a new extraction well (well 299-W15-225) that was constructed during FY2009 for inclusion within the future 200-West Area Groundwater Treatment System that is scheduled to go on-line at the end of FY2011. To facilitate the analysis of the large-scale hydrologic test performed at newly constructed extraction well 299-W15-225 (C7017; also referred to as EW-1 in some planning documents), the existing 200-ZP-1 interim pump-and-treat system was completely shut-down ~1 month before the performance of the large-scale hydrologic test. Specifically, this report 1) applies recently developed methods for removing barometric pressure fluctuations from well water-level measurements to enhance the detection of hydrologic test and pump-and-treat system effects at selected monitor wells, 2) analyzes the barometric-corrected well water-level responses for a preliminary determination of large-scale hydraulic properties, and 3) provides an assessment of the vertical distribution of hydraulic conductivity in the vicinity of newly constructed extraction well 299-W15-225. The hydrologic characterization approach presented in this report is expected to have universal application for meeting the characterization needs at other remedial action sites located within unconfined and confined aquifer systems.

  5. Corrective measures evaluation work plan : Technical Area V Groundwater : revision 0.

    Energy Technology Data Exchange (ETDEWEB)

    Lebow, Patrick S.; Dettmers, Dana L.; Hall, Kevin A.

    2004-12-01

    This document, which is prepared as directed by the Compliance Order on Consent (COOC) issued by the New Mexico Environment Department, identifies and outlines a process to evaluate remedial alternatives to identify a corrective measure for the Sandia National Laboratories/New Mexico Technical Area (TA)-V Groundwater. The COOC provides guidance for implementation of a Corrective Measures Evaluation (CME) for the TA-V Groundwater. This Work Plan documents an initial screening of remedial technologies and presents a list of possible remedial alternatives for those technologies that passed the screening. This Work Plan outlines the methods for evaluating these remedial alternatives and describes possible site-specific evaluation activities necessary to estimate remedy effectiveness and cost. These methods will be reported in the CME Report. This Work Plan outlines the CME Report, including key components and a description of the corrective measures process.

  6. Remedy Evaluation Framework for Inorganic, Non-Volatile Contaminants in the Vadose Zone

    Energy Technology Data Exchange (ETDEWEB)

    Truex, Michael J.; Carroll, Kenneth C.

    2013-05-01

    Contaminants in the vadose zone may act as a potential long-term source of groundwater contamination and need to be considered in remedy evaluations. In many cases, remediation decisions for the vadose zone will need to be made all or in part based on projected impacts to groundwater. Because there are significant natural attenuation processes inherent in vadose zone contaminant transport, remediation in the vadose zone to protect groundwater is functionally a combination of natural attenuation and use of other remediation techniques, as needed, to mitigate contaminant flux to groundwater. Attenuation processes include both hydrobiogeochemical processes that serve to retain contaminants within porous media and physical processes that mitigate the rate of water flux. In particular, the physical processes controlling fluid flow in the vadose zone are quite different and generally have a more significant attenuation impact on contaminant transport relative to those within the groundwater system. A remedy evaluation framework is presented herein that uses an adaptation of the established EPA Monitored Natural Attenuation (MNA) evaluation approach and a conceptual model based approach focused on identifying and quantifying features and processes that control contaminant flux through the vadose zone. A key concept for this framework is to recognize that MNA will comprise some portion of all remedies in the vadose zone. Thus, structuring evaluation of vadose zone waste sites to use an MNA-based approach provides information necessary to either select MNA as the remedy, if appropriate, or to quantify how much additional attenuation would need to be induced by a remedial action (e.g., technologies considered in a feasibility study) to augment the natural attenuation processes and meet groundwater protection goals.

  7. Evaluation and Screening of Remedial Technologies for Uranium at the 300-FF-5 Operable Unit, Hanford Site, Washington

    Energy Technology Data Exchange (ETDEWEB)

    Nimmons, Michael J.

    2007-08-01

    Pacific Northwest National Laboratory (PNNL) is presently conducting a re-evaluation of remedies addressing persistent dissolved uranium concentrations in the upper aquifer under the 300 Area of the Hanford Site in southeastern Washington State. This work is being conducted as a Phase III feasibility study for the 300-FF-5 Operable Unit on behalf of the U.S. Department of Energy. As part of the feasibility study process, a comprehensive inventory of candidate remedial technologies was conducted by PNNL. This report documents the identification and screening of candidate technologies. The screening evaluation was conducted in accordance with guidance and processes specified by U.S. Environmental Protection Agency regulations associated with implementation of the Comprehensive Environmental Response, Compensation, and Liability Act process.

  8. Record of Decision Tank Farm Soil and INTEC Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    L. S. Cahn

    2007-05-01

    This decision document presents the selected remedy for Operable Unit (OU) 3-14 tank farm soil and groundwater at the Idaho Nuclear Technology and Engineering Center (INTEC), which is located on the Idaho National Laboratory (INL) Site. The tank farm was initially evaluated in the OU 3-13 Record of Decision (ROD), and it was determined that additional information was needed to make a final decision. Additional information has been obtained on the nature and extent of contamination in the tank farm and on the impact of groundwater. The selected remedy was chosen in accordance with the Comprehensive Environmental Response, Liability and Compensation Act of 1980 (CERCLA) (42 USC 9601 et seq.), as amended by the Superfund Amendments and Reauthorization Act of 1986 (Public Law 99-499) and the National Oil and Hazardous Substances Pollution Contingency Plan (40 CFR 300). The selected remedy is intended to be the final action for tank far soil and groundwater at INTEC.

  9. A review on the geoenvironmental and geoecological integrated technology for environmental remediation in Vietnam: approaches, contributions, challenges and perspectives

    Science.gov (United States)

    Trong Nhuan, Mai; Hoang Ha, Nguyen Thi; Hoai, Ta Thi; Dang Quy, Tran

    2017-06-01

    Geoenvironmental and geoecological integrated technology (GGIT) is a cost-effective and environment-friendly technology that encompasses the applications of earth science principles and functions of geological environment and ecosystems to assimilate and minimize the spread of pollutants, to enhance the sorption capacity and environmental remediation. On the basis of the integrated approaches such as system, anthropogenic activities - ecosystem - environment interaction, effectiveness and feasibility, GGIT has provided significant applications in Vietnam such as waste containment and remediation and environmental protection. The results of a pilot scale using iron mine drainage sludge and common reed (Phragmites australis) for wastewater treatment in a Pb-Zn mine in northern Vietnam indicated the effective and potential application of GGIT. However, GGIT has many challenges in limited funding conditions, constraints in the initial development of GGIT, incomplete transfer to users, and quantitative assessment of pollutant cleanup by natural environments and ecosystems. Environmental pollution quote, impacts to exposed organisms, increasing demands for application of low-cost technologies, the availability of potential sorbents, indigenous plants, and ecosystems for environmental remediation, and collaboration will promote development, contribution, and implementation of GGIT applications in Vietnam.

  10. DESCRIPTION OF MODELING ANALYSES IN SUPPORT OF THE 200-ZP-1 REMEDIAL DESIGN/REMEDIAL ACTION

    Energy Technology Data Exchange (ETDEWEB)

    VONGARGEN BH

    2009-11-03

    The Feasibility Study/or the 200-ZP-1 Groundwater Operable Unit (DOE/RL-2007-28) and the Proposed Plan/or Remediation of the 200-ZP-1 Groundwater Operable Unit (DOE/RL-2007-33) describe the use of groundwater pump-and-treat technology for the 200-ZP-1 Groundwater Operable Unit (OU) as part of an expanded groundwater remedy. During fiscal year 2008 (FY08), a groundwater flow and contaminant transport (flow and transport) model was developed to support remedy design decisions at the 200-ZP-1 OU. This model was developed because the size and influence of the proposed 200-ZP-1 groundwater pump-and-treat remedy will have a larger areal extent than the current interim remedy, and modeling is required to provide estimates of influent concentrations and contaminant mass removal rates to support the design of the aboveground treatment train. The 200 West Area Pre-Conceptual Design/or Final Extraction/Injection Well Network: Modeling Analyses (DOE/RL-2008-56) documents the development of the first version of the MODFLOW/MT3DMS model of the Hanford Site's Central Plateau, as well as the initial application of that model to simulate a potential well field for the 200-ZP-1 remedy (considering only the contaminants carbon tetrachloride and technetium-99). This document focuses on the use of the flow and transport model to identify suitable extraction and injection well locations as part of the 200 West Area 200-ZP-1 Pump-and-Treat Remedial Design/Remedial Action Work Plan (DOEIRL-2008-78). Currently, the model has been developed to the extent necessary to provide approximate results and to lay a foundation for the design basis concentrations that are required in support of the remedial design/remediation action (RD/RA) work plan. The discussion in this document includes the following: (1) Assignment of flow and transport parameters for the model; (2) Definition of initial conditions for the transport model for each simulated contaminant of concern (COC) (i.e., carbon

  11. Adapting Advances in Remediation Science to Long-Term Surveillance

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Dave [S.M. Stoller Corporation

    2006-03-01

    Several facets of groundwater remediation stand to gain from the advances made during recent years in disciplines that contribute to remediation science. Engineered remedies designed to aggressively remove subsurface contamination should benefit from this progress, and more passive cleanup methods and the long-term monitoring of such passive approaches may benefit equally well if not more. The U.S. Department of Energy Office of Legacy Management (LM) has adopted a strategic plan that is designed to take advantage of technological improvements in the monitoring and assessment of both active and passive groundwater remedies. Flexible adaptation of new technologies, as they become available, to long-term surveillance at LM sites is expected to reduce site stewardship costs while ensuring the future protection of human health and the environment. Some of the technologies are expected to come from government initiatives that focus on the needs of subsurface monitoring. Additional progress in monitoring science will likely result from continual improvements in our understanding of contaminant fate-and-transport processes in the groundwater and the vadose zone.

  12. Corrective measures evaluation work plan : Tijeras Arroyo Groundwater : revision 0.

    Energy Technology Data Exchange (ETDEWEB)

    Wymore, Ryan A.; Collins, Sue S.; Skelly, Michael Francis; Koelsch, Michael C.

    2004-12-01

    This document, which is prepared as directed by the Compliance Order on Consent (COOC) issued by the New Mexico Environment Department, outlines a process to evaluate remedial alternatives to identify a corrective measure for the Sandia National Laboratories Tijeras Arroyo Groundwater (TAG). The COOC provides guidance for implementation of a Corrective Measures Evaluation (CME) for TAG. This Work Plan documents an initial screening of remedial technologies and presents a list of possible remedial alternatives for those technologies that passed the screening. This Work Plan outlines the methods for evaluating these remedial alternatives and describes possible site-specific evaluation activities necessary to estimate remedy effectiveness and cost. These methods will be reported in the CME Report. This Work Plan outlines the CME Report, including key components and a description of the corrective measures process.

  13. 土壤汞污染及其修复技术%Soil Mercury Pollution and Its Remediation Technology

    Institute of Scientific and Technical Information of China (English)

    何姗姗; 李薇; 卢晗

    2016-01-01

    The main factors that caused the increase of the concentration of mercury in soil and the main factors affected the migration of mercury in soil were summarized. The main remediation technology and its application in controlling soil mercury pollution were reviewed. Focus on soil washing technology, stabilization/solidification technology, thermal treatment technology and bioremediation technology. The improvement measures of soil mercury remediation technology should be further studied. Promote the method of local conditions. Different treatments for different soils.%总结了导致土壤中汞浓度增加的来源,以及影响土壤中汞迁移的主要因素,这些因素对评价和优化修复技术是至关重要的。回顾了主要修复技术及其在控制土壤汞污染方面的应用。重点关注土壤淋洗技术,稳定化/固化技术,热处理技术和生物修复技术。应进一步对土壤汞修复技术的改进措施进行研究,提倡因地制宜的修复方法。

  14. Resistivity and self-potential tomography applied to groundwater remediation and contaminant plumes: Sandbox and field experiments

    Science.gov (United States)

    Mao, D.; Revil, A.; Hort, R. D.; Munakata-Marr, J.; Atekwana, E. A.; Kulessa, B.

    2015-11-01

    Geophysical methods can be used to remotely characterize contaminated sites and monitor in situ enhanced remediation processes. We have conducted one sandbox experiment and one contaminated field investigation to show the robustness of electrical resistivity tomography and self-potential (SP) tomography for these applications. In the sandbox experiment, we injected permanganate in a trichloroethylene (TCE)-contaminated environment under a constant hydraulic gradient. Inverted resistivity tomograms are able to track the evolution of the permanganate plume in agreement with visual observations made on the side of the tank. Self-potential measurements were also performed at the surface of the sandbox using non-polarizing Ag-AgCl electrodes. These data were inverted to obtain the source density distribution with and without the resistivity information. A compact horizontal dipole source located at the front of the plume was obtained from the inversion of these self-potential data. This current dipole may be related to the redox reaction occurring between TCE and permanganate and the strong concentration gradient at the front of the plume. We demonstrate that time-lapse self-potential signals can be used to track the kinetics of an advecting oxidizer plume with acceptable accuracy and, if needed, in real time, but are unable to completely resolve the shape of the plume. In the field investigation, a 3D resistivity tomography is used to characterize an organic contaminant plume (resistive domain) and an overlying zone of solid waste materials (conductive domain). After removing the influence of the streaming potential, the identified source current density had a magnitude of 0.5 A m-2. The strong source current density may be attributed to charge movement between the neighboring zones that encourage abiotic and microbially enhanced reduction and oxidation reactions. In both cases, the self-potential source current density is located in the area of strong resistivity

  15. Performance assessment techniques for groundwater recovery and treatment systems

    Energy Technology Data Exchange (ETDEWEB)

    Kirkpatrick, G.L. [Environmental Resources Management, Inc., Exton, PA (United States)

    1993-03-01

    Groundwater recovery and treatment (pump and treat systems) continue to be the most commonly selected remedial technology for groundwater restoration and protection programs at hazardous waste sites and RCRA facilities nationwide. Implementing a typical groundwater recovery and treatment system includes the initial assessment of groundwater quality, characterizing aquifer hydrodynamics, recovery system design, system installation, testing, permitting, and operation and maintenance. This paper focuses on methods used to assess the long-term efficiency of a pump and treat system. Regulatory agencies and industry alike are sensitive to the need for accurate assessment of the performance and success of groundwater recovery systems for contaminant plume abatement and aquifer restoration. Several assessment methods are available to measure the long-term performance of a groundwater recovery system. This paper presents six assessment techniques: degree of compliance with regulatory agency agreement (Consent Order of Record of Decision), hydraulic demonstration of system performance, contaminant mass recovery calculation, system design and performance comparison, statistical evaluation of groundwater quality and preferably, integration of the assessment methods. Applying specific recovery system assessment methods depends upon the type, amount, and quality of data available. Use of an integrated approach is encouraged to evaluate the success of a groundwater recovery and treatment system. The methods presented in this paper are for engineers and corporate management to use when discussing the effectiveness of groundwater remediation systems with their environmental consultant. In addition, an independent (third party) system evaluation is recommended to be sure that a recovery system operates efficiently and with minimum expense.

  16. 25 Years Of Environmental Remediation In The General Separations Area Of The Savannah River Site: Lessons Learned About What Worked And What Did Not Work In Soil And Groundwater Cleanup

    Energy Technology Data Exchange (ETDEWEB)

    Blount, Gerald [Savannah River Nuclear Solutions (SRNS), Aiken, SC (United States); Thibault, Jeffrey [Savannah River Nuclear Solutions (SRNS), Aiken, SC (United States); Millings, Margaret [Savannah River Nuclear Solutions (SRNS), Aiken, SC (United States); Prater, Phil [Savannah River Site (SRS), Aiken, SC (United States)

    2015-03-16

    The Savannah River Site (SRS) is owned and administered by the US Department of Energy (DOE). SRS covers an area of approximately 900 square kilometers. The General Separation Area (GSA) is located roughly in the center of the SRS and includes: radioactive material chemical separations facilities, radioactive waste tank farms, a variety of radioactive seepage basins, and the radioactive waste burial grounds. Radioactive wastes were disposed in the GSA from the mid-1950s through the mid-1990s. Radioactive operations at the F Canyon began in 1954; radioactive operations at H Canyon began in 1955. Waste water disposition to the F and H Seepage Basins began soon after operations started in the canyons. The Old Radioactive Waste Burial Ground (ORWBG) began operations in 1952 to manage solid waste that could be radioactive from all the site operations, and ceased receiving waste in 1972. The Mixed Waste Management Facility (MWMF) and Low Level Radioactive Waste Disposal Facility (LLRWDF) received radioactive solid waste from 1969 until 1995. Environmental legislation enacted in the 1970s, 1980s, and 1990s led to changes in waste management and environmental cleanup practices at SRS. The US Congress passed the Clean Air Act in 1970, and the Clean Water Act in 1972; the Resource Conservation and Recovery Act (RCRA) was enacted in 1976; the Comprehensive Environmental Response Compensation, and Liability Act (CERCLA) was enacted by Congress in 1980; the Federal Facilities Compliance Act (FFCA) was signed into law in 1992. Environmental remediation at the SRS essentially began with a 1987 Settlement Agreement between the SRS and the State of South Carolina (under the South Carolina Department of Health and Environmental Control - SCDHEC), which recognized linkage between many SRS waste management facilities and RCRA. The SRS manages several of the larger groundwater remedial activities under RCRA for facilities recognized early on as environmental problems. All subsequent

  17. Oak Ridge K-25 Site Technology Logic Diagram. Volume 3, Technology evaluation data sheets; Part B, Remedial action, robotics/automation, waste management

    Energy Technology Data Exchange (ETDEWEB)

    Fellows, R.L. [ed.

    1993-02-26

    The Oak Ridge K-25 Technology Logic Diagram (TLD), a decision support tool for the K-25 Site, was developed to provide a planning document that relates environmental restoration (ER) and waste management (WN) problems at the Oak Ridge K-25 Site. The TLD technique identifies the research necessary to develop these technologies to a state that allows for technology transfer and application to waste management, remediation, decontamination, and decommissioning activities. The TLD consists of four separate volumes-Vol. 1, Vol. 2, Vol. 3A, and Vol. 3B. Volume 1 provides introductory and overview information about the TLD. Volume 2 contains logic diagrams. Volume 3 has been divided into two separate volumes to facilitate handling and use. This volume 3 B provides the Technology Evaluation Data Sheets (TEDS) for ER/WM activities (Remedial Action Robotics and Automation, Waste Management) that are referenced by a TEDS code number in Vol. 2 of the TLD. Each of these sheets represents a single logic trace across the TLD. These sheets contain more detail than each technology in Vol. 2. The TEDS are arranged alphanumerically by the TEDS code number in the upper right corner of each data sheet. Volume 3 can be used in two ways: (1) technologies that are identified from Vol. 2 can be referenced directly in Vol. 3 by using the TEDS codes, and (2) technologies and general technology areas (alternatives) can be located in the index in the front of this volume.

  18. The Soils and Groundwater – EM-20 S&T Roadmap Quality Assurance Project Plan

    Energy Technology Data Exchange (ETDEWEB)

    Fix, N. J.

    2008-02-11

    The Soils and Groundwater – EM-20 Science and Technology Roadmap Project is a U.S. Department of Energy, Office of Environmental Management-funded initiative designed to develop new methods, strategies and technology for characterizing, modeling, remediating, and monitoring soils and groundwater contaminated with metals, radionuclides, and chlorinated organics. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by EM-20 Roadmap Project staff.

  19. Laboratory {open_quotes}proof of principle{close_quotes} investigation for the acoustically enhanced remediation technology

    Energy Technology Data Exchange (ETDEWEB)

    Iovenitti, J.L.; Spencer, J.W. Jr.; Hill, D.G. [Weiss Associates, Emergyville, CA (United States)] [and others

    1995-10-01

    Weiss Associates is conducting a three phase program investigating the systematics of using acoustic excitation fields (AEFs) to enhance the in-situ remediation of contaminated soil and ground water under both saturated and unsaturated conditions: Phase I - Laboratory Scale Parametric Investigation; Phase II - Technology Scaling Study; and Phase III - Large Scale Field Tests. Phase I, the subject of this paper, consisted primarily of a laboratory proof of principle investigation. The field deployment and engineering viability of acoustically enhanced remediation (AER) technology was also examined. Phase II is a technology scaling study addressing the scale up between laboratory size samples on the order of inches, and the data required for field scale testing, on the order of hundreds of feet. Phase III will consist of field scale testing at an non-industrialized, non-contaminated site and at a contaminated site to validate the technology. Summarized herein are the results of the Phase I {open_quotes}proof-of-principle{close_quotes} investigation, and recommendations for Phase H. A general overview of AER technology along with the plan for the Phase I investigation was presented.

  20. Remediation of trichloroethylene-contaminated soils by star technology using vegetable oil smoldering.

    Science.gov (United States)

    Salman, Madiha; Gerhard, Jason I; Major, David W; Pironi, Paolo; Hadden, Rory

    2015-03-21

    Self-sustaining treatment for active remediation (STAR) is an innovative soil remediation approach based on smoldering combustion that has been demonstrated to effectively destroy complex hydrocarbon nonaqueous phase liquids (NAPLs) with minimal energy input. This is the first study to explore the smoldering remediation of sand contaminated by a volatile NAPL (trichloroethylene, TCE) and the first to consider utilizing vegetable oil as supplemental fuel for STAR. Thirty laboratory-scale experiments were conducted to evaluate the relationship between key outcomes (TCE destruction, rate of remediation) to initial conditions (vegetable oil type, oil: TCE mass ratio, neat versus emulsified oils). Several vegetable oils and emulsified vegetable oil formulations were shown to support remediation of TCE via self-sustaining smoldering. A minimum concentration of 14,000 mg/kg canola oil was found to treat sand exhibiting up to 80,000 mg/kg TCE. On average, 75% of the TCE mass was removed due to volatilization. This proof-of-concept study suggests that injection and smoldering of vegetable oil may provide a new alternative for driving volatile contaminants to traditional vapour extraction systems without supplying substantial external energy.

  1. The CHPRC Groundwater and Technical Integration Support (Master Project) Quality Assurance Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    Fix, N. J.

    2009-04-03

    The scope of the CH2M Hill Plateau Remediation Company, LLC (CHPRC) Groundwater and Technical Integration Support (Master Project) is for Pacific Northwest National Laboratory staff to provide technical and integration support to CHPRC. This work includes conducting investigations at the 300-FF-5 Operable Unit and other groundwater operable units, and providing strategic integration, technical integration and assessments, remediation decision support, and science and technology. The projects under this Master Project will be defined and included within the Master Project throughout the fiscal year, and will be incorporated into the Master Project Plan. This Quality Assurance Management Plan provides the quality assurance requirements and processes that will be followed by the CHPRC Groundwater and Technical Integration Support (Master Project) and all releases associated with the CHPRC Soil and Groundwater Remediation Project. The plan is designed to be used exclusively by project staff.

  2. Field Demonstration of Propane Biosparging for In Situ Remediation of NNitrosodimethylamine (NDMA) in Groundwater. Cost and Performance Report

    Science.gov (United States)

    2015-12-30

    disadvantages . For example, successful application of the technology requires the presence of propane oxidizing bacteria that can degrade the target...ratio of oxygen (O2) to propane (C3H8) for complete oxidation of propane to carbon dioxide (CO2; not accounting for microbial biomass incorporation...fluidization pump, an influent distribution system and effluent/ biomass collection system, two biomass separators, 7,100 lbs of carbon media (coconut shell

  3. Ammonium-nitrogen-contaminated groundwater remediation by a sequential three-zone permeable reactive barrier (multibarrier) with oxygen-releasing compound (ORC)/clinoptilolite/spongy iron: column studies.

    Science.gov (United States)

    Huang, Guoxin; Liu, Fei; Yang, Yingzhao; Kong, Xiangke; Li, Shengpin; Zhang, Ying; Cao, Dejun

    2015-03-01

    A novel sequential permeable reactive barrier (multibarrier), composed of oxygen-releasing compound (ORC)/clinoptilolite/spongy iron zones in series, was proposed for ammonium-nitrogen-contaminated groundwater remediation. Column experiments were performed to: (1) evaluate the overall NH4(+)-N removal performance of the proposed multibarrier, (2) investigate nitrogen transformation in the three zones, (3) determine the reaction front progress, and (4) explore cleanup mechanisms for inorganic nitrogens. The results showed that NH4 (+)-N percent removal by the multibarrier increased up to 90.43 % after 21 pore volumes (PVs) at the influent dissolved oxygen of 0.68∼2.45 mg/L and pH of 6.76∼7.42. NH4(+)-N of 4.06∼10.49 mg/L was depleted and NOx(-)-N (i.e., NO3 (-)-N + NO2(-)-N) of 4.26∼9.63 mg/L was formed before 98 PVs in the ORC zone. NH4(+)-N of ≤4.76 mg/L was eliminated in the clinoptilolite zone. NOx(-)-N of 10.44∼12.80 mg/L was lost before 21 PVs in the spongy iron zone. The clinoptilolite zone length should be reduced to 30 cm. Microbial nitrification played a dominant role in NH4(+)-N removal in the ORC zone. Ion exchange was majorly responsible for NH4(+)-N elimination in the clinoptilolite zone. Chemical reduction and hydrogenotrophic denitrification both contributed to NOx(-)-N transformation, but the chemical reduction capacity decreased after 21 PVs in the spongy iron.

  4. Heat-activated persulfate oxidation of PFOA, 6:2 fluorotelomer sulfonate, and PFOS under conditions suitable for in-situ groundwater remediation.

    Science.gov (United States)

    Park, Saerom; Lee, Linda S; Medina, Victor F; Zull, Aaron; Waisner, Scott

    2016-02-01

    PFOA (perfluorooctanoic acid) oxidation (0.121-6.04 μM) by heat-activated persulfate was evaluated at 20-60 °C with 4.2-84 mM [Formula: see text] and in the presence of soluble fuel components to assess feasibility for in-situ remediation of groundwater. 6:2 fluorotelomer sulfonic acid/sulfonate (6:2 FTSA) and PFOS (perfluorooctanesulfonic acid) persulfate oxidation was also evaluated in a subset of conditions given their co-occurrence at many sites. High performance liquid chromatography electron spray tandem mass spectrometry was used for organic analysis and fluoride was measured using a fluoride-specific electrode. PFOA pseudo-1st order transformation rates (k1,PFOA) increased with increasing temperature (half-lives from 0.1 to 7 d for 60 to 30 °C) sequentially removing CF2 groups ('unzipping') to shorter chain perfluoroalkyl carboxylic acids (PFCAs) and F(-). At 50 °C, a 5-fold increase in [Formula: see text] led to a 5-fold increase in k1,PFOA after which self-scavenging by sulfate radicals decreased the relative rate of increase with more [Formula: see text] . Benzene, toluene, ethylbenzene and xylene did not affect k1,PFOA even at 40 times higher molar concentrations than PFOA. A modeling approach to explore pathways strongly supported that for 6:2 FTSA, both the ethyl linkage and CF2-CH2 bond of 6:2 FTSA oxidize simultaneously, resulting in a ratio of ∼25/75 PFHpA/PFHxA. The effectiveness of heat-activated [Formula: see text] on PFOA oxidation was reduced in a soil slurry; therefore, repeated persulfate injections are required to efficiently achieve complete oxidation in the field. However, PFOS remained unaltered even at higher activation temperatures, thus limiting the sole use of heat-activated persulfate for perfluoroalkyl substances removal in the field.

  5. Environmental remediation and conversion of carbon dioxide (CO(2)) into useful green products by accelerated carbonation technology.

    Science.gov (United States)

    Lim, Mihee; Han, Gi-Chun; Ahn, Ji-Whan; You, Kwang-Suk

    2010-01-01

    This paper reviews the application of carbonation technology to the environmental industry as a way of reducing carbon dioxide (CO(2)), a green house gas, including the presentation of related projects of our research group. An alternative technology to very slow natural carbonation is the co-called 'accelerated carbonation', which completes its fast reaction within few hours by using pure CO(2). Carbonation technology is widely applied to solidify or stabilize solid combustion residues from municipal solid wastes, paper mill wastes, etc. and contaminated soils, and to manufacture precipitated calcium carbonate (PCC). Carbonated products can be utilized as aggregates in the concrete industry and as alkaline fillers in the paper (or recycled paper) making industry. The quantity of captured CO(2) in carbonated products can be evaluated by measuring mass loss of heated samples by thermo-gravimetric (TG) analysis. The industrial carbonation technology could contribute to both reduction of CO(2) emissions and environmental remediation.

  6. Environmental Remediation and Conversion of Carbon Dioxide (CO2 into Useful Green Products by Accelerated Carbonation Technology

    Directory of Open Access Journals (Sweden)

    Kwang-Suk You

    2010-01-01

    Full Text Available This paper reviews the application of carbonation technology to the environmental industry as a way of reducing carbon dioxide (CO2, a green house gas, including the presentation of related projects of our research group. An alternative technology to very slow natural carbonation is the co-called ‘accelerated carbonation’, which completes its fast reaction within few hours by using pure CO2. Carbonation technology is widely applied to solidify or stabilize solid combustion residues from municipal solid wastes, paper mill wastes, etc. and contaminated soils, and to manufacture precipitated calcium carbonate (PCC. Carbonated products can be utilized as aggregates in the concrete industry and as alkaline fillers in the paper (or recycled paper making industry. The quantity of captured CO2 in carbonated products can be evaluated by measuring mass loss of heated samples by thermo-gravimetric (TG analysis. The industrial carbonation technology could contribute to both reduction of CO2 emissions and environmental remediation.

  7. Pumping through porous hydrophobic/oleophilic materials: an alternative technology for oil spill remediation.

    Science.gov (United States)

    Ge, Jin; Ye, Yin-Dong; Yao, Hong-Bin; Zhu, Xi; Wang, Xu; Wu, Liang; Wang, Jin-Long; Ding, Hang; Yong, Ni; He, Ling-Hui; Yu, Shu-Hong

    2014-04-01

    Recently, porous hydrophobic/oleophilic materials (PHOMs) have been shown to be the most promising candidates for cleaning up oil spills; however, due to their limited absorption capacity, a large quantity of PHOMs would be consumed in oil spill remediation, causing serious economic problems. In addition, the complicated and time-consuming process of oil recovery from these sorbents is also an obstacle to their practical application. To solve the above problems, we apply external pumping on PHOMs to realize the continuous collection of oil spills in situ from the water surface with high speed and efficiency. Based on this novel design, oil/water separation and oil collection can be simultaneously achieved in the remediation of oil spills, and the oil sorption capacity is no longer limited to the volume and weight of the sorption material. This novel external pumping technique may bring PHOMs a step closer to practical application in oil spill remediation.

  8. MGP remediation using thermal desorption: emerging technology yields a permanent solution

    Energy Technology Data Exchange (ETDEWEB)

    Umfleet, D.E.; Bachman, S.A.; Highland, E. [Barr Engineering Company, Ann Arbor, MI (United States)

    1997-12-01

    An investigation of a former manufactured gas plant (MGP) at the site for Northwestern Public Service`s new operations buildings uncovered evidence of MGP residuals in the moist, clay-rich soils. On site-thermal desorption was selected as the remedial method. A low-temperature, counter-flow, direct-fired rotary desorber heats soils up to 1200{degree}F to volatilize organic fractions. Soils containing polyaromatic hydrocarbon (PAH) compounds were excavated, treated effectively, and reused at the site as backfill. For the approximately 47,000 tons of soil processed, remediation costs were 82 dollars per ton. Site-specific factors affecting project costs included the volume of soil treated, soil type and condition, inclement weather, and market conditions. Soils were treated to below state-approved performance criterion, and remediation of the site was completed just 18 months after the project began. 1 fig., 2 tabs.

  9. Re-injection accelerates groundwater clean up at Fernald, Fluor Fernald, Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Dave Brettschneider; William Hertel; Ken Broberg

    2000-09-29

    A successful one year long, field scale demonstration of the use of groundwater re-infection at Fernald was recently completed bringing DOE one step closer to achieving an accelerated site remediation (DOE 2000). The demonstration marks the end of a several year effort to evaluate whether: re-injection could be conducted efficiently at Fernald, and if the approved aquifer remedy at Fernald would benefit by incorporating re-infection. Evaluation of re-injection technology involved not only technical considerations, but also participation and cooperation of regulators and stakeholders. The demonstration was considered to be unique in that it was integrated into the design of the current approved aquifer remedy and utilized the existing remediation infrastructure. Information collected during the demonstration indicated that re-injection wells could be operated efficiently at Fernald and that the current approved groundwater remedy should be modified to include the use of re-injection.

  10. Simulation of groundwater drainage into a tunnel in fractured rock and numerical analysis of leakage remediation, Romeriksporten tunnel, Norway

    Science.gov (United States)

    Kitterød, N.-O.; Colleuille, H.; Wong, W. K.; Pedersen, T. S.

    2000-09-01

    Standard geostatistical methods for simulation of heterogeneity were applied to the Romeriksporten tunnel in Norway, where water was leaking through high-permeable fracture zones into the tunnel while it was under construction, causing drainage problems on the surface. After the tunnel was completed, artificial infiltration of water into wells drilled from the tunnel was implemented to control the leakage. Synthetic heterogeneity was generated at a scale sufficiently small to simulate the effects of remedial actions that were proposed to control the leakage. The flow field depends on the variance of permeabilities and the covariance model used to generate the heterogeneity. Flow channeling is the most important flow mechanism if the variance of the permeability field is large compared to the expected value. This condition makes the tunnel leakage difficult to control. The main effects of permeability changes due to sealing injection are simulated by a simple perturbation of the log-normal probability density function of the permeability. If flow channeling is the major transport mechanism of water into the tunnel, implementation of artificial infiltration of water to control the leakage requires previous chemical-sealing injection to be successful. Résumé. Des méthodes géostatistiques standard ont été employées pour simuler l'hétérogénéité des zones de fractures à fortes perméabilitées dans lesquelles, au cours de la construction du tunnel ferroviaire de Romeriksporten (Norvège), l'eau s'est écoulée, causant des problèmes de drainage en surface. Quand les travaux ont été terminés, l'injection d'eau dans des puits forés à partir du tunnel a été réalisée pour contrôler ces infiltrations. Une hétérogénéité synthétique a été créée à une échelle suffisamment petite pour simuler les effets de l'injection d'eau. Le champ des écoulements dépend de la variance des perméabilités et de la covariance du modèle utilisé pour g

  11. Monitored Natural Attenuation as a Remediation Strategy for Nuclear Power Plant Applications

    Science.gov (United States)

    Kim, K.; Bushart, S.

    2009-12-01

    A NRC Information Notice (IN 2006-13) was produced to inform holders of nuclear operating licenses “of the occurrence of radioactive contamination of ground water at multiple facilities due to undetected leakage from facility structures, systems, or components (SSCs) that contain or transport radioactive fluids” so that they could consider actions, as appropriate, to avoid similar problems. To reinforce their commitment to environmental stewardship the nuclear energy industry has committed to improving management of situations that have the potential to lead to the inadvertent release of radioactive fluids. This Industry Groundwater Protection Initiative, finalized in June 2007 as [NEI 07-07], calls for implementation and improvement of on-site groundwater monitoring programs and enhanced communications with stakeholders and regulators about situations related to inadvertent releases. EPRI developed its Groundwater Protection Program to provide the nuclear energy industry with the technical support needed to implement the Industry Groundwater Initiative. An objective of the EPRI Groundwater Protection Program is to provide the nuclear industry with technically sound guidance for implementing and enhancing on-site groundwater monitoring programs. EPRI, in collaboration with the EPRI Groundwater Protection Committee of utility members, developed the EPRI Groundwater Protection Guidelines for Nuclear Power Plants (EPRI Report 1015118, November 2007), which provides site-specific guidance for implementing a technically sound groundwater monitoring program. The guidance applies a graded approach for nuclear plants to tailor a technically effective and cost efficient groundwater monitoring program to the site’s hydrogeology and risk for groundwater contamination. As part of the Groundwater Protection Program, EPRI is also investigating innovative remediation technologies for addressing low-level radioactive contamination in soils and groundwater at nuclear power

  12. 污染土壤修复技术的探讨%An analysis of Several Remediation Technologies of the Contaminated soils

    Institute of Scientific and Technical Information of China (English)

    金一凡; 周连杰; 杰克; 叶旭明

    2012-01-01

    污染土壤修复技术目前广泛应用的是生物、换土、固化及淋洗修复技术等,对前3种修复技术在处理污染土壤的效果和过程上进行分析和对比,其结果表明都存在着优缺点.通过对污染土壤淋洗技术的定义及分类的了解和与前3种修复技术的比较,并在此基础上产生了移动式异位淋洗修复技术介绍了它的工艺流程及各机械装置的作用,通过对照原有的污染土壤淋洗修复技术,其表明移动式异位淋洗修复技术具有可移动性、修复效率高等特点,具有很大的工程应用价值.%Most commonly used remediation technologies for soil contamination include bioremediation technology,soil replacement remediation technology and solidification technology at present. Through analysis and comparison, the disadvantages of these three remediation technologies were listed. The drip washing technology of contaminated soil was defined and classified. On this basis, a mobile drip washing remediation technology for contaminated soils was developed. The function of each mechanical device in drip washing technological process was introduced. By comparing the original drip washing remediation technology of contaminated soils, a conclusion was drawed that mobile drip washing remediation technology of contaminated soils has mobility and high efficiency characteristics and has a great application value.

  13. In situ remediation of petroleum hydrocarbon contaminated groundwater using a novel biobarrier%新型生物反应墙原位修复石油烃污染地下水

    Institute of Scientific and Technical Information of China (English)

    马会强; 张兰英; 张洪林; 李爽

    2011-01-01

    A novel biobarrier, whose reaction media consist of functional microbes, peat and coarse sand, is tested in laboratory to study the effect and the related mechanism in remediation of petroleum hydrocarbon contaminated groundwater. The results show that the removal efficiency for BTEX, naphthalene hydrocarbons and phenanthrene are 83. 6% ~ 99. 85%, in which 71. 23% ~ 99. 71% contaminants are removed at the first half part of biobarrier. The peat and functional microbes function steadily in contaminant sorption and biodegradation. 32.63%~77.98% BTEX and 97.14%~99.81% target PAHs are absorbed by peat and 18. 96% ~ 50. 98% BTEX and almost all of the peat-absorbed petroleum hydrocarbon contaminants are degraded by microbes. Contaminant biodegradation can efficiently prolong the sorption life of peat barrier, and the efficient nutrients supply from peat to functional microbes can maintain the biomass at a relatively high level in the biobarrier, i.e. about 3.46× 106~6.16× 109 per gram dry media. Therefore, the novel biobarrier technology can be efficiently used in in-situ remediation of petroleum hydrocarbon contaminated groundwater.%以功能微生物、泥炭和粗砂为填充介质设计新型生物反应墙,研究了反应墙对地下水中石油烃污染物的修复效果与机理.结果表明:运行期内生物反应墙修复效果良好,苯系物、萘系物及菲去除率为83.6%~99.85%,其中71.23%~99.71%在墙体前半部分被去除.泥炭介质和功能微生物能够稳定发挥对污染物的吸附与降解功能,32.63%~77.98%的BTEX和97.14%~99.81%的目标PAHs被泥炭吸附去除;18.96%~50.98%的BTEX和已吸附于泥炭上的大部分石油烃污染物均显示被生物降解.微生物对污染物的降解可有效延长泥炭的吸附寿命,泥炭对功能微生物的营养供给可使反应墙内长期保持较高的功能微生物数量,每克干介质约含有3.46×106~6.16×109个.因此新型生物

  14. Army Green and Sustainable Remediation: Policy and Implementation

    Science.gov (United States)

    2010-06-15

    with caustic soda • More than 112,000 cubic yards of soil treated using alkaline hydrolysis • Total TNT/DNT mass removed is more than 75 tons...system • In-situ pilot study using bacteria to treat perchlorate in groundwater • Targeted species removal and use of native plants and grass seed...pump-and-treat technologies Aerial view of the Seneca Army Depot June 2010Army Green and Sustainable Remediation 13 Volunteer Army Ammunition Plant

  15. The farst paper for the control and insitu remediation of groundwater contaminated with organic contaminats%地下水有机污染控制及就地恢复技术研究进展(一)

    Institute of Scientific and Technical Information of China (English)

    钟佐燊

    2001-01-01

    本文是关于地下水有机污染控制及其就地恢复技术研究进展概况的第一篇文章,文中介绍抽出-处理系统、水力隔离系统、生物通风及曝气技术的研究进展。%The paper is first paper for the control and in situ remediation of groundwater contaminated with organic contaminants. The content of paper present advances for pump-and-treat systems,hydrodynamic isolation systems,bioventing, and air sparging.

  16. Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume One - Main Text and Appendices A and B

    Energy Technology Data Exchange (ETDEWEB)

    Cline, S.R.; Denton, D.L.; Giaquinto, J.M.; McCracken, M.K.; Starr, R.C.

    1999-04-01

    The laboratory investigation was performed to evaluate the feasibility of utilizing in situ chemical oxidation for remediating the secondary source of groundwater contaminants at the Idaho National Engineering and Environmental Laboratory (INEEL) Test Area North (TAN) Site. The study involved trichloroethene (TCE) contaminated media (groundwater, soil, and sludge) from TAN. The effectiveness of the selected oxidant, potassium permanganate (KMn0(sub4)), was evaluated at multiple oxidant and contaminant concentrations. Experiments were performed to determine the oxidant demand of each medium and the rate of TCE oxidation. The experiments were performed under highly controlled conditions (gas-tight reactors, constant 12C temperature). Multiple parameter were monitored over time including MN0(sub 4) and TCE concentrations and pH.

  17. Phytoremediation, a sustainable remediation technology? II: Economic assessment of CO2 abatement through the use of phytoremediation crops for renewable energy production

    OpenAIRE

    Witters, N.; Mendelsohn, R; Van Passel, S.; Van Slycken, S.; Weyens, N.; Schreurs, E.; Meers, E.; Tack, F.; Vanheusden, B.; Vangronsveld, J.

    2012-01-01

    Phytoremediation could be a sustainable remediation alternative for conventional remediation technologies. However, its implementation on a commercial scale remains disappointing. To emphasize its sustainability, this paper examines whether and how the potential economic benefit of CO2 abatement for different crops used for phytoremediation or sustainable land management purposes could promote phytotechnologies. Our analysis is based on a case study in the Campine region, where agricultural s...

  18. Simulated flow of groundwater and brine from a flooded salt mine in Livingston County, New York, and effects of remedial pumping on an overlying aquifer

    Science.gov (United States)

    Yager, Richard M.; Miller, Todd S.; Kappel, William M.; Misut, Paul E.; Langevin, Christian D.; Parkhurst, David L.; deVries, M. Peter

    2012-01-01

    began a brine-mitigation project that entailed pumping five wells finished in limestone and shale units within the collapse areas to alter the flow gradient and thereby prevent further movement of brine and saline water into the LCA. The pumped brine was routed to an onsite desalination plant. At the same time, the U.S. Geological Survey (USGS) began a study in cooperation with the New York State Office of the Attorney General to construct numerical models to analyze the groundwater chemistry and delineate the directions of flow. Specific objectives of the study were to: * Assess the sources of salinity within the collapse area and identify the factors that control the movement and mixing of freshwater, saline waters from fracture zones, and brine; * Evaluate the likelihood that the pumping will induce anhydrite dissolution and lead to continued land subsidence; * Construct variable-density groundwater flow models to predict the effect of remedial pumping on salinity within the LCA; * Evaluate the effectiveness of remedial pumping in preventing the movement of saline water into the LCA; and * Predict the extent of brine migration 8 years after a hypothetical shutdown of all pumping in 2008. This report (1) summarizes the hydrogeologic setting and effects of mine flooding, (2) describes the geochemical and variable-density model simulations and their principal results, (3) discusses the implications of (a) continued pumping and desalination to protect the LCA and (b) a full shutdown of pumping after 2008, and (4) suggests further research that could lead to refinement of model predictions. Additional information may be found in Yager and others (2001 and 2009). These reports can be accessed at http://pubs.usgs.gov/pp/pp1611/ and http://pubs.usgs.gov/pp/pp1767/, respectively. A summary of simulation results can be accessed at http://ny.water.usgs.gov/projects/Coram/seawat/seawat.html.

  19. Targeting low-arsenic groundwater with mobile-phone technology in Araihazar, Bangladesh.

    Science.gov (United States)

    van Geen, A; Trevisani, M; Immel, J; Jakariya, Md; Osman, N; Cheng, Z; Gelman, A; Ahmed, K M

    2006-09-01

    The Bangladesh Arsenic Mitigation and Water Supply Program (BAMWSP) has compiled field-kit measurements of the arsenic content of groundwater for nearly five million wells. By comparing the spatial distribution of arsenic inferred from these field-kit measurements with geo-referenced laboratory data in a portion of Araihazar upazila, it is shown here that the BAMWSP data could be used for targeting safe aquifers for the installation of community wells in many villages of Bangladesh. Recent experiences with mobile-phone technology to access and update the BAMWSP data in the field are also described. It is shown that the technology, without guaranteeing success, could optimize interventions by guiding the choice of the drilling method that is likely to reach a safe aquifer and identifying those villages where exploratory drilling is needed.

  20. Improving Risk Governance of Emerging Technologies through Public Engagement: The Neglected Case of Nano-Remediation?

    DEFF Research Database (Denmark)

    Grieger, Khara Deanne; Wickson, Fern; Andersen, Henning Boje

    2012-01-01

    assessment. This paper therefore carries out a literature review to capture and analyse how governance strategies have focused on public engagement for NT and how such engagement relates to processes of risk analysis. To further investigate these issues, we focus on a specific NT application as a case study......: the use of nanoparticles for environmental remediation (nano-remediation). Through our review and analysis we find that the main approaches to incorporating public engagement into governance strategies have been the generation of a better understanding of public perceptions of NT and the setting......While public engagement is internationally considered to be crucial for successful governance of nanotechnologies (NT), it has not necessarily been clear what the relationship is (or should be) between these engagement efforts and the more traditional governance practice of scientific risk...

  1. Remediation of PCB contaminated soils in the Canadian Arctic: excavation and surface PRB technology.

    Science.gov (United States)

    Kalinovich, Indra; Rutter, Allison; Poland, John S; Cairns, Graham; Rowe, R Kerry

    2008-12-15

    The site BAF-5 is located on the summit of Resolution Island, Nunavut, just southeast of Baffin Island at 61 degrees 35'N and 60 degrees 40'W. The site was part of a North American military defense system established in the 1950s that became heavily contaminated with PCBs during and subsequent, its operational years. Remediation through excavation of the PCB contaminated soil at Resolution Island began in 1999 and at its completion in 2006 approximately 5 tonnes of pure PCBs in approximately 20,000 m3 of soil were remediated. Remediation strategies were based on both quantity of soil and level of contamination in the soil. Excavation removed 96% of the PCB contaminated soil on site. In 2003, a surface funnel-and-gate permeable reactive barrier was design and constructed to treat the remaining contamination left in rock crevices and inaccessible areas of the site. Excavation had destabilized contaminated soil in the area, enabling contaminant migration through erosion and runoff pathways. The barrier was designed to maximize sedimentation through settling ponds. This bulk removal enabled the treatment of highly contaminated fines and water through a permeable gate. The increased sediment loading during excavation required both modifications to the funnel and a shift to a more permeable, granular system. Granulated activated charcoal was chosen for its ability to both act as a particle retention filter and adsorptive filter. The reduction in mass of PCB and volume of soils trapped by the funnel of the barrier indicate that soils are re-stabilizing. In 2007, nonwoven geotextiles were re-introduced back into the filtration system as fine filtering could be achieved without clogging. Monitoring sites downstream indicate that the barrier system is effective. This paper describes the field progress of PCB remediation at Resolution Island.

  2. Remediation Technologies for Environmental Projects in the United States Military: Part 1

    Science.gov (United States)

    1997-09-01

    remediation method is appropriate for sites contaminated with dense non-aqueous phase liquids ( DNAPLs ), metals, or semi-volatile organic compounds. If the... Mercury (mm Hg). Bioventing Fuel, BTEX, or THC hydrocarbon contamination (i.e.. non-halogenated hydrocarbon) in the vadose zone; - Soil gas...thorougly fractured bedrock. Capping DNAPL . sesnivolatile, or metal/inorganic contamination in the vadose zone; - Area of capping contamination less than 24

  3. Oil Spill Remediation Using Magnetic Particles: An Experiment in Environmental Technology

    Science.gov (United States)

    Orbell, John D.; Godhino, Leroy; Bigger, Stephen W.; Nguyen, Thi Man; Ngeh, Lawrence N.

    1997-12-01

    A simple experiment is described in which the potential of commercially available steel pellets coated with polyethylene (PE) or poly(vinylchloride) (PVC) to remediate an oil spill is demonstrated. Polymer-coated particles are weighed, immersed in oil, magnetically harvested and the remaining oil is weighed in order to enable students to quantitatively investigate the adsorption process. The possibility of recycling the beads and reclaiming the oil is also demonstrated.

  4. 25 Years Of Environmental Remediation In The General Separations Area Of The Savannah River Site: Lessons Learned About What Worked And What Did Not Work In Soil And Groundwater Cleanup

    Energy Technology Data Exchange (ETDEWEB)

    Blount, Gerald [Savannah River Nuclear Solutions (SRNS), Aiken, SC (United States); Thibault, Jeffrey [Savannah River Nuclear Solutions (SRNS), Aiken, SC (United States); Millings, Margaret [Savannah River Nuclear Solutions (SRNS), Aiken, SC (United States); Prater, Phil [Savannah River Site (SRS), Aiken, SC (United States)

    2015-03-16

    The Savannah River Site (SRS) is owned and administered by the US Department of Energy (DOE). SRS covers an area of approximately 900 square kilometers. The General Separation Area (GSA) is located roughly in the center of the SRS and includes: radioactive material chemical separations facilities, radioactive waste tank farms, a variety of radioactive seepage basins, and the radioactive waste burial grounds. Radioactive wastes were disposed in the GSA from the mid-1950s through the mid-1990s. Radioactive operations at the F Canyon began in 1954; radioactive operations at H Canyon began in 1955. Waste water disposition to the F and H Seepage Basins began soon after operations started in the canyons. The Old Radioactive Waste Burial Ground (ORWBG) began operations in 1952 to manage solid waste that could be radioactive from all the site operations, and ceased receiving waste in 1972. The Mixed Waste Management Facility (MWMF) and Low Level Radioactive Waste Disposal Facility (LLRWDF) received radioactive solid waste from 1969 until 1995. Environmental legislation enacted in the 1970s, 1980s, and 1990s led to changes in waste management and environmental cleanup practices at SRS. The US Congress passed the Clean Air Act in 1970, and the Clean Water Act in 1972; the Resource Conservation and Recovery Act (RCRA) was enacted in 1976; the Comprehensive Environmental Response Compensation, and Liability Act (CERCLA) was enacted by Congress in 1980; the Federal Facilities Compliance Act (FFCA) was signed into law in 1992. Environmental remediation at the SRS essentially began with a 1987 Settlement Agreement between the SRS and the State of South Carolina (under the South Carolina Department of Health and Environmental Control - SCDHEC), which recognized linkage between many SRS waste management facilities and RCRA. The SRS manages several of the larger groundwater remedial activities under RCRA for facilities recognized early on as environmental problems. All subsequent

  5. Indoor simulation of BPRB remediating atrazine contaminated groundwater%室内模拟BPRB修复阿特拉津污染地下水

    Institute of Scientific and Technical Information of China (English)

    朱博麟; 邱华; 李海军; 毕海涛; 刘娜

    2012-01-01

    The study designed an innovative bio permeable reactive barrier (BPRB) , filled with PPVA bioactive materials which immobilized atrazine degradation bacteria(Pseudomonas W4) , consisting of two parts. The former was filled with peat-PPVA and sand ( V/V = 1:1), constantly releasing C, P; the latter was filled with perlite-PPVA and sand ( V/V = 1:1) , consuming C, P released from peat. The oxygen supply was continuous air aeration in wells installed within BPRB and the DO concentration in BPRB was more than 3 mg/L. BPRB simulated slot had been running for 140 days, total inflow was 1 213. 6 L, total removal of atrazine was 19. 35 ± 1, 00 g, and there was no atrazine detected in effluent. With the absence of auxiliary C, P source, BPRB can stably remediate atrazine contaminated groundwater for a long term.%设计了新型生物可渗透反应墙(BPRB)用于处理被污染的地下水.以阿特拉津为污染物,装填固定有阿特拉津降解菌(Pseudomonas W4)的磷酸化聚乙烯醇(PPVA)生物活性材料介质,前半部分以草炭土- PPVA/砂子为填料,以长期稳定地释放C、P;后半部分以珍珠岩- PPVA/砂子为填料,消耗草炭土- PPVA释放的C、P.选择V( PPVA生物活性材料)∶V(砂子)=1∶1的比例安装BPRB.在BPRB内设置曝气井,供氧方式为连续空气曝气,整个BPRB内DO质量浓度大于3 mg/L.BPRB模拟槽共运行140 d,累计进水1 213.6 L,共去除阿特拉津(19.35±1.00)g,出水中始终未检出阿特拉津.试验结果表明,在不额外添加碳源、磷源的条件下,BPRB能够长期稳定修复阿特拉津污染地下水.

  6. Microbial Repopulation Following In Situ STAR Remediation

    Science.gov (United States)

    Gerhard, J.; Overbeeke, G.; Edwards, E.; Lomheim, L.; Grant, G.

    2016-12-01

    STAR (Self-sustaining Treatment for Active Remediation) is an emerging remediation technology that employs a self-sustaining smouldering reaction to destroy nonaqueous phase liquids (NAPLs) in the subsurface. The reaction front travels outwards from an ignition well at approximately 0.5 per day and subjects the soil to temperatures of 400°C-1000°C. The objectives of this work were to monitor re-saturation of the soil over time and quantify the microbial repopulation of the treated zone. STAR is currently being applied as a full scale, in situ remedy for coal tar beneath a former creosol manufacturing facility in New Jersey, USA. This study analyzed soil cores taken at regular intervals following STAR treatment, allowing time for groundwater to re-infiltrate and for microbial populations to potentially reestablish. Soil and groundwater were analyzed for total number of microorganisms via quantitative Polymerase Chain Reaction (qPCR), as well as microbial diversity via amplicon sequencing. Results demonstrate that microbes rapidly repopulated over a 2 month period to 106 gene copies/g of soil. However, concentrations in the treated zone did not rise above this concentration over 6 months post-STAR, indicating a low carrying capacity of the treated soil. To examine the system in more detail and consider the effects of bio-stimulation, a bench top column study using site soil and artificial groundwater explored the rate at which STAR-treated soil is repopulated with naturally occurring microorganisms in the presence and absence of lactate and a terminal electron acceptor. Results demonstrated that biostimulation did not increase the carrying capacity of the STAR treated sol, but rather shifted the microbial community to reflect the TEA provided, in this case, promoting sulfate reducers. Overall, the work illustrates that microbial populations in STAR treated soil do recover via groundwater infiltration but robust communities will take time to naturally establish.

  7. Linking deposit morphology and clogging in subsurface remediation: Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Mays, David C. [University of Colorado Denver

    2013-12-11

    Groundwater is a crucial resource for water supply, especially in arid and semiarid areas of the United States west of the 100th meridian. Accordingly, remediation of contaminated groundwater is an important application of science and technology, particularly for the U.S. Department of Energy (DOE), which oversees a number of groundwater remediation sites from Cold War era mining. Groundwater remediation is complex, because it depends on identifying, locating, and treating contaminants in the subsurface, where remediation reactions depend on interacting geological, hydrological, geochemical, and microbiological factors. Within this context, permeability is a fundamental concept, because it controls the rates and pathways of groundwater flow. Colloid science is intimately related to permeability, because when colloids are present (particles with equivalent diameters between 1 nanometer and 10 micrometers), changes in hydrological or geochemical conditions can trigger a detrimental reduction in permeability called clogging. Accordingly, clogging is a major concern in groundwater remediation. Several lines of evidence suggest that clogging by colloids depends on (1) colloid deposition, and (2) deposit morphology, that is, the structure of colloid deposits, which can be quantified as a fractal dimension. This report describes research, performed under a 2-year, exploratory grant from the DOE’s Subsurface Biogeochemical Research (SBR) program. This research employed a novel laboratory technique to simultaneously measure flow, colloid deposition, deposit morphology, and permeability in a flow cell, and also collected field samples from wells at the DOE’s Old Rifle remediation site. Field results indicate that suspended solids at the Old Rifle site have fractal structures. Laboratory results indicate that clogging is associated with colloid deposits with smaller fractal dimensions, in accordance with previous studies on initially clean granular media. Preliminary

  8. DETERMINATION OF THE GROUND-WATER LEVEL BY MODERN NON-DISTRUCTIVE METHODS (GPR TECHNOLOGY

    Directory of Open Access Journals (Sweden)

    I. C. NICU

    2011-03-01

    Full Text Available Determination of the ground-water level by modern non-dis¬tructive methods (ground-penetrating radar technology. Ground Penetrating Radar (GPR is now a well-accepted geophysical technique, which unfortunately in our country its less used. Historically, the development of GPR comes from the use of radio echosounding to determine ice thickness and it was only a short step to enlarge the domain of research such as permafrost, geological investigation (bedrock, sedimentology, environmental assessment and hydrogeophysical studies (under-ground water location, soil water content. The GPR method measures the travel time of electromagnetic impulses in subsurface materials. An impulse radar system radiates repetitive electromagnetic impulses into the soil. A bandwidth antenna is usually placed in close proximity and electromagnetic coupled to the ground surface. It detects and measures the depth of reflecting discontinuities in subsurface soils and other earth materials to within a few centimeters depending of antenna frequency. For over 30 years, GPR has been used extensively for hydropedological investigations. Our research aims to determine the groundwater to estimate the degree of evolution of hydro-geomorphological processes.

  9. The Remediation Technology and Remediation Practice of Heavy Metals-Contaminated Soil%重金属污染土壤修复技术及其修复实践

    Institute of Scientific and Technical Information of China (English)

    黄益宗; 郝晓伟; 雷鸣; 铁柏清

    2013-01-01

    近年来我国重金属污染事件频发,严重影响广大群众的身体健康,土壤重金属污染与防治成为人们关注的环境问题之一.作者结合多年的工作经验,综述了近年来国内外有关重金属污染土壤修复技术的研究进展,包括物理/化学修复技术、生物修复技术和农业生态修复技术等,对每种技术的基本修复原理、技术特点和应用范围进行了讨论.同时,对国内外典型的重金属污染土壤修复工程实践进行了介绍,以期为重金属污染土壤的修复提供借鉴和参考.%In recent years heavy metal pollution incidents happened frequently in our country, and they had serious impact on human health. How to control heavy metals-contaminated soil becomes one of the noted environmental problems. The present paper aims to provide a critical review on the remediation technology of soils contaminated by heavy metals, including physical / chemical remediation, bioremediation and agricultural ecological restoration technologies, and each kind of technology's remedial principle, technical characteristics and application range are discussed. At the same time, the domestic and foreign typical remediation practices of heavy metals-contaminated soil are introduced, in order to provide the reference for the remediation of heavy metals-contaminated soil in China.

  10. Biological Remediation of Soil: An Overview of Global Market and Available Technologies

    Science.gov (United States)

    Singh, Ajay; Kuhad, Ramesh C.; Ward, Owen P.

    Due to a wide range of industrial and agricultural activities, a high number of chemical contaminants is released into the environment, causing a significant concern regarding potential toxicity, carcinogenicity, and potential for bioaccumulation in living systems of various chemicals in soil. Although microbial activity in soil accounts for most of the degradation of organic contaminants, chemical and physical mechanisms can also provide significant transformation pathways for these compounds. The specific remediation processes that have been applied to clean up contaminated sites include natural attenuation, landfarming, biopiling or composting, contained slurry bioreactor, bioventing, soil vapor extraction, thermal desorption, incineration, soil washing and land filling (USEPA 2004).

  11. Groundwater Quality Deterioration due to Municipal Solid Waste Dumping Practices

    Science.gov (United States)

    Parameswari, Kaliyaperumal; Karunakaran, Krishnasamy

    2011-07-01

    Groundwater is the major source of drinking water in both urban and rural India. The demand for water has increased over the years and this has led to water scarcity. The scarcity situation, especially in urban areas, is aggravated by the problem of water pollution or contamination by solid waste dumping. In many urban centers in India, the quality of groundwater is getting severely affected because of the widespread pollution, due to the discharge of untreated waste water in water bodies and leachate from the unscientific disposal of solid wastes. It is necessary to realize the importance of groundwater and preserve its quality through careful monitoring and remediation. This study focuses on the magnitude of groundwater pollution due to improper solid waste dumping practices prevailing in the southern part of the Chennai Metropolitan Area. The Perungudi dumpsite, a solid waste dumping site in the periphery of Chennai city, India, has been chosen for this study. The chemical characteristic of solid waste and leachate has been studied, and the groundwater samples from various locations around the dumpsite were collected and analyzed. Samples were analyzed for pH, electrical conductivity, total dissolved solids, chlorides, sulfate, calcium, magnesium, total hardness, sodium, potassium, BOD, and COD. Heavy metals such as lead, iron, and zinc have been analyzed. The study reveals that most of the groundwater samples do not conform to drinking water quality standards. The study also indicates that groundwater remediation techniques and proper groundwater quality monitoring on a regular basis are of utmost importance in the study area. A few in-situ groundwater remediation technologies have been suggested to improve the present water quality.

  12. A Review of Advances in the Identification and Characterization of Groundwater Dependent Ecosystems Using Geospatial Technologies

    Directory of Open Access Journals (Sweden)

    Isabel C. Pérez Hoyos

    2016-03-01

    Full Text Available Groundwater Dependent Ecosystem (GDE protection is increasingly being recognized as essential for the sustainable management and allocation of water resources. GDE services are crucial for human well-being and for a variety of flora and fauna. However, the conservation of GDEs is only possible if knowledge about their location and extent is available. Several studies have focused on the identification of GDEs at specific locations using ground-based measurements. However, recent progress in remote sensing technologies and their integration with Geographic Information Systems (GIS has provided alternative ways to map GDEs at a much larger spatial extent. This paper presents a review of the geospatial methods that have been used to map and delineate GDEs at spatial different extents. Additionally, a summary of the satellite sensors useful for identification of GDEs and the integration of remote sensing data with ground-based measurements in the process of mapping GDEs is presented.

  13. Harnessing microbial gene pools to remediate persistent organic pollutants using genetically modified plants--a viable technology?

    Science.gov (United States)

    Rylott, Elizabeth L; Johnston, Emily J; Bruce, Neil C

    2015-11-01

    It has been 14 years since the international community came together to legislate the Stockholm Convention on Persistent Organic Pollutants (POPs), restricting the production and use of specific chemicals that were found to be environmentally stable, often bioaccumulating, with long-term toxic effects. Efforts are continuing to remove these pollutants from the environment. While incineration and chemical treatment can be successful, these methods require the removal of tonnes of soil, at high cost, and are damaging to soil structure and microbial communities. The engineering of plants for in situ POP remediation has had highly promising results, and could be a more environmentally-friendly alternative. This review discusses the characterization of POP-degrading bacterial pathways, and how the genes responsible have been harnessed using genetic modification (GM) to introduce these same abilities into plants. Recent advances in multi-gene cloning, genome editing technologies and expression in monocot species are accelerating progress with remediation-applicable species. Examples include plants developed to degrade 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), trichloroethylene (TCE), and polychlorinated biphenyls (PCBs). However, the costs and timescales needed to gain regulatory approval, along with continued public opposition, are considerable. The benefits and challenges in this rapidly developing and promising field are discussed. © The Author 2015. Published by Oxford University Press on behalf of the Society for Experimental Biology. All rights reserved. For permissions, please email: journals.permissions@oup.com.

  14. Assessing soil and groundwater contamination in a metropolitan redevelopment project.

    Science.gov (United States)

    Yun, Junki; Lee, Ju Young; Khim, Jeehyeong; Ji, Won Hyun

    2013-08-01

    The purpose of this study was to assess contaminated soil and groundwater for the urban redevelopment of a rapid transit railway and a new mega-shopping area. Contaminated soil and groundwater may interfere with the progress of this project, and residents and shoppers may be exposed to human health risks. The study area has been remediated after application of first remediation technologies. Of the entire area, several sites were still contaminated by waste materials and petroleum. For zinc (Zn) contamination, high Zn concentrations were detected because waste materials were disposed in the entire area. For petroleum contamination, high total petroleum hydrocarbon (TPH) and hydrocarbon degrading microbe concentrations were observed at the depth of 7 m because the underground petroleum storage tank had previously been located at this site. Correlation results suggest that TPH (soil) concentration is still related with TPH (groundwater) concentration. The relationship is taken into account in the Spearman coefficient (α).

  15. Modified endophytes for improving phyto remediation and mixed contaminations of heavy metals (Ni) and organic contaminants (Toluene)

    Energy Technology Data Exchange (ETDEWEB)

    Weyens, N.; Barac, T.; Lelie, D. van der; Taghavi, S.; Vangronsveld, J.

    2009-07-01

    Phytoremediation is a promising technology for the remediation of soils and groundwater contaminated with heavy metals and organic pollutants. However, large-scale application of phytoremediation faces a number of obstacles including the levels of pollutants tolerated by the plant, the bioavailability of the contaminants and, in some cases, the evapotranspiration of volatile organic pollutants. (Author)

  16. EPA-developed, patented technologies related to water monitoring and remediation that are available for licensing

    Data.gov (United States)

    U.S. Environmental Protection Agency — Under the Federal Technology Transfer Act (FTTA), Federal Agencies can patent inventions developed during the course of research. These technologies can then be...

  17. Technology for site remediation: availability, needs and opportunities for R and D at SCK/CEN

    Energy Technology Data Exchange (ETDEWEB)

    Collard, G.

    1996-09-18

    Considerable experience has been gained over the past years in the use of control and treatment technologies, applied to contaminated sites and environments. Although available technologies are adequate in many cases, it is recognized that many technologies are too costly or inadequate to address the multitude of contaminant problems. This insight has led national and international organizations as well as private organizations and universities to sponsor environment technology programmes to address technology needs. The United States Department of Energy for example has initiated an aggressive environmental technology development programme and the Commission of the European Union is sponsoring environmental technology development. An overview is given of innovative and emerging technologies that may become important. Opportunities for SCK/CEN in research, development, and demonstration programmes are outlined.

  18. Remediation of water pollution caused by pharmaceutical residues based on electrochemical separation and degradation technologies: a review.

    Science.gov (United States)

    Sirés, Ignasi; Brillas, Enric

    2012-04-01

    In the last years, the decontamination and disinfection of waters by means of direct or integrated electrochemical processes are being considered as a very appealing alternative due to the significant improvement of the electrode materials and the coupling with low-cost renewable energy sources. Many electrochemical technologies are currently available for the remediation of waters contaminated by refractory organic pollutants such as pharmaceutical micropollutants, whose presence in the environment has become a matter of major concern. Recent reviews have focused on the removal of pharmaceutical residues upon the application of other important methods like ozonation and advanced oxidation processes. Here, we present an overview on the electrochemical methods devised for the treatment of pharmaceutical residues from both, synthetic solutions and real pharmaceutical wastewaters. Electrochemical separation technologies such as membrane technologies, electrocoagulation and internal micro-electrolysis, which only isolate the pollutants from water, are firstly introduced. The fundamentals and experimental set-ups involved in technologies that allow the degradation of pharmaceuticals, like anodic oxidation, electro-oxidation with active chlorine, electro-Fenton, photoelectro-Fenton and photoelectrocatalysis among others, are further discussed. Progress on the promising solar photoelectro-Fenton process devised and further developed in our laboratory is especially highlighted and documented. The abatement of total organic carbon or reduction of chemical oxygen demand from contaminated waters allows the comparison between the different methods and materials. The routes for the degradation of the some pharmaceuticals are also presented. Copyright © 2011 Elsevier Ltd. All rights reserved.

  19. ACTIVE CAPPING TECHNOLOGY - NEW APPROACHES FOR IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Knox, A.; Paller, M.; Roberts, J.

    2012-02-13

    This study evaluated pilot-scale active caps composed of apatite, organoclay, biopolymers, and sand for the remediation of metal-contaminated sediments. The active caps were constructed in Steel Creek, at the Savannah River Site near Aiken, South Carolina. Monitoring was conducted for 12 months. Effectiveness of the caps was based on an evaluation of contaminant bioavailability, resistance to erosion, and impacts on benthic organisms. Active caps lowered metal bioavailability in the sediment during the one-year test period. Biopolymers reduced sediment suspension during cap construction, increased the pool of carbon, and lowered the release of metals. This field validation showed that active caps can effectively treat contaminants by changing their speciation, and that caps can be constructed to include more than one type of amendment to achieve multiple goals.

  20. BIOREGIS software platform based on GIS technology to support in-situ remediation of petroleum contaminated sites. Case study: razvad - dambovita county, Romania

    Energy Technology Data Exchange (ETDEWEB)

    Anicai, Ovidiu [Institute for Computers - ITC SA, Bucharest (Romania); Anicai, Liana [PSV COMPANY SA, Direction of Research, Bucharest (Romania)

    2011-12-15

    With a need for the management of petroleum contaminated sites on Romanian territory, an experimental software platform involving ESRI-ArcGIS technologies (BIOREGIS) is presented in this study. The BIOREGIS platform is aimed to: (i) Build the structure of relational, standardized databases to store spatial and textual characteristic information on polluted sites for further risk analysis and planning of remediation actions, (ii) improve the pollution risk assessment methodology for Romanian petroleum contaminated sites and its informatics implementation, and (iii) develop and operate the software platform for pollution risk based management involving GIS/remote sensing technologies and remediation activities. The operation of BIOREGIS has been tested for a pilot contaminated area situated at Razvad - Dambovita County, which has been subjected to in situ remediation procedures involving both bioremediation and electrokinetic processes. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  1. Hanford Site Groundwater Monitoring for Fiscal Year 2000

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2001-03-01

    This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 2000 on the U.S. Department of Energy's Hanford Site, Washington. The most extensive contaminant plumes are tritium, iodine-129, and nitrate, which all had multiple sources and are very mobile in groundwater. Carbon tetrachloride and associated organic constituents form a relatively large plume beneath the central part of the Site. Hexavalent chromium is present in smaller plumes beneath the reactor areas along the river and beneath the central part of the site. Strontium-90 exceeds standards beneath each of the reactor areas, and technetium-99 and uranium are present in the 200 Areas. RCRA groundwater monitoring continued during fiscal year 2000. Vadose zone monitoring, characterization, remediation, and several technical demonstrations were conducted in fiscal year 2000. Soil gas monitoring at the 618-11 burial ground provided a preliminary indication of the location of tritium in the vadose zone and in groundwater. Groundwater modeling efforts focused on 1) identifying and characterizing major uncertainties in the current conceptual model and 2) performing a transient inverse calibration of the existing site-wide model. Specific model applications were conducted in support of the Hanford Site carbon tetrachloride Innovative Treatment Remediation Technology; to support the performance assessment of the Immobilized Low-Activity Waste Disposal Facility; and in development of the System Assessment Capability, which is intended to predict cumulative site-wide effects from all significant Hanford Site contaminants.

  2. In Situ Remediation Integrated Program: FY 1994 program summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-04-01

    The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment technologies. Buried waste, contaminated soils and groundwater, and containerized waste are all candidates for in situ remediation. Contaminants include radioactive waste, volatile and nonvolatile organics, heavy metals, nitrates, and explosive materials.

  3. Radio Frequency Heating for Soil Remediation.

    Science.gov (United States)

    Price, Stephen L; Kasevich, Raymond S; Johnson, Mark A; Wiberg, Dan; Marley, Michael C

    1999-02-01

    Radio frequency heating (RFH) is a technology that increases the cost-effectiveness of a variety of site remediation technologies by accelerating the rate of contaminant removal. Heating makes the physical, chemical, and biological properties of materials such as contaminants, soil, and groundwater more amenable to remediation. RFH brings controlled heating to the subsurface, enhancing the removal of contaminants by soil vapor extraction (SVE), groundwater aeration (air sparging), bioremediation, and product recovery. The results presented are from a bench-scale study and a field demonstration that both used RFH to enhance the performance of SVE. The bench-scale study performed on PCE-contaminated soil revealed an increase, by a factor of 8, in the removal rate when RFH was used to heat soil to 90 °C. The application of RFH for a three-week period at a former gasoline station near St. Paul, MN, resulted in raising the ambient soil temperature from 8 °C to 100 °C in the immediate vicinity of the RFH applicator and to 40 °C 1.5 m (5 ft) away. Most significantly, the use of an integrated RFH/SVE system achieved an overall 50% reduction in gasoline range organics (GRO) in soil over a two- to three-month period. The discussion includes applications of RFH for enhancing bioremediation and product recovery.

  4. Applications of Ecological Engineering Remedies for Uranium Processing Sites, USA

    Energy Technology Data Exchange (ETDEWEB)

    Waugh, William [Navarro Research and Engineering

    2016-05-23

    The U.S. Department of Energy (USDOE) is responsible for remediation of environmental contamination and long-term stewardship of sites associated with the legacy of nuclear weapons production during the Cold War in the United States. Protection of human health and the environment will be required for hundreds or even thousands of years at many legacy sites. USDOE continually evaluates and applies advances in science and technology to improve the effectiveness and sustainability of surface and groundwater remedies (USDOE 2011). This paper is a synopsis of ecological engineering applications that USDOE is evaluating to assess the effectiveness of remedies at former uranium processing sites in the southwestern United States. Ecological engineering remedies are predicated on the concept that natural ecological processes at legacy sites, once understood, can be beneficially enhanced or manipulated. Advances in tools for characterizing key processes and for monitoring remedy performance are demonstrating potential. We present test cases for four ecological engineering remedies that may be candidates for international applications.

  5. Advances in environmental remediation technologies for trichloroethylene pollution%三氯乙烯环境污染修复技术研究进展

    Institute of Scientific and Technical Information of China (English)

    钱翌; 岳飞飞; 褚衍洋

    2012-01-01

    三氯乙烯(TCE)是一种挥发性的有机溶剂,具有较强的环境毒性,对人体有很大危害,被列为"优先控制化合物"及"疑似致癌物质".近年来,许多研究者采用各类技术对TCE的降解进行了系统研究,并取得一定成效,为TCE环境污染的修复提供了多种方法.本文综述了物理修复、化学修复、植物修复及微生物修复等TCE原位修复方法的原理、效能、优缺点及各方法的影响因素,并展望了今后TCE修复技术的发展趋势.%Trichloroethylene(TCE) is a volatile organic solvent with strong environmental toxicity.Identified to be seriously harmful to human bodies,it has been classified as "priority-controlled compounds" and "suspected carcinogens".Recently,various technologies for TCE degradation have been systematically studied,with successful outcomes.They provide a variety of methods for environmental remediation for TCE pollutions.This paper reviews the mechanism,performance,and Pro/Con of several in situ remediation technologies,listed as physical remediation,chemical remediation,phytoremediation,and microbial remediation.An outlook on developing trend of TCE remediation technologies is also proposed.

  6. IN SITU AND EX SITU BIODEGRADATION TECHNOLOGIES FOR REMEDIATION OF CONTAMINATED SITES [ENGINEERING ISSUE)

    Science.gov (United States)

    Bioremediation is a grouping of technologies that use microbiota (typically, heterotrophic bacteria and fungi) to degrade or transform hazardous contaminants to materials such as carbon dioxide, water, inorganic salts, microbial biomass, and other byproducts that may be less haza...

  7. INEEL Subsurface Disposal Area CERCLA-based Decision Analysis for Technology Screening and Remedial Alternative Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Parnell, G. S.; Kloeber, Jr. J.; Westphal, D; Fung, V.; Richardson, John Grant

    2000-03-01

    A CERCLA-based decision analysis methodology for alternative evaluation and technology screening has been developed for application at the Idaho National Engineering and Environmental Laboratory WAG 7 OU13/14 Subsurface Disposal Area (SDA). Quantitative value functions derived from CERCLA balancing criteria in cooperation with State and Federal regulators are presented. A weighted criteria hierarchy is also summarized that relates individual value function numerical values to an overall score for a specific technology alternative.

  8. Remediation Technology of Contaminated Areas with Organochlorines: A Preliminary Evaluation Seeking Potential Applications on the Site of Street Capua, Santo André - SP

    Directory of Open Access Journals (Sweden)

    Mauro Silva Ruiz

    2012-12-01

    Full Text Available This paper is aimed to analyze the use of remediation technologies for areas contaminated with organochlorine based on a literature review and discussions with specialists. The remediation technologies analyzed were bioremediation, phytoremediation, nanotechnology, chemical oxidation, and thermal desorption. The purpose is to identify and compare “key problems” for each of these technologies envisaging the use of one or more of these them f or the remediation of the Capua Street site in Santo André, SP. Four databases were used in the preliminary literature review: Scopus, SciELO, Web of Science, and Science Direct. A survey questionnaire was designed to gather information on publications of scientific papers and patents, specific uses of these technologies by companies, and cases of application. Since the quality of the data and information obtained from this questionnaire application was not satisfactory, a new research approach for complementing them was undertaken. For this purpose, the Web of Science was selected as the most adequate data basis to carry out this second survey. However, it was realized that even for this database - that is reference for evaluating academic institutions, researchers and maturity of technologies – bias coming from the original data source can affect the survey results. Moreover, as the number of keywords used in the research consisted of generic terms for each technology, it can also be assumed that if some authors have used very specific terms, a small amount of work published by them would possibly have been misrepresented in the final result.

  9. Column Experiments of Smouldering Combustion as a Remediation Technology for NAPL Source Zones

    Science.gov (United States)

    Pironi, P.; Switzer, C.; Rein, G.; Torero, J. L.; Gerhard, J. I.

    2008-12-01

    Smouldering combustion is an innovative approach that has significant potential for the remediation of industrial sites contaminated by non-aqueous phase liquids (NAPLs). Many common liquid contaminants, including coal tar, solvents, oils and petrochemicals are combustible and release significant amounts of heat when burned. Smouldering combustion is the flameless burning of a condensed fuel that derives heat from surface oxidation reactions. Gerhard et al., 2006 (Eos Trans., 87(52), Fall Meeting Suppl. H24A) presented proof-of-concept experiments demonstrating that NAPLs embedded in a porous medium may be effectively destroyed via smouldering. Based upon that work, it was hypothesized that the process can be self- sustaining, such that, a short duration energy input (i.e., ignition) at a single location is sufficient to generate a reaction that propagates itself through the NAPL source zone until the NAPL is eliminated, provided that enough air is injected into the soil. In this work, this hypothesis is proven via column experiments at the intermediate bench scale (~ 30 cm) utilizing coal tar-contaminated quartz sands. Over 30 such experiments examine the sensitivity of NAPL smouldering to a series of fluid-media system variables and engineering control parameters, including contaminant type, NAPL saturation, water saturation, porous media type and air injection rate. Diagnostic techniques employed to characterize the results include temperature mapping, off-gas analysis (via FTIR), heat front mapping via digital imaging, and pre- and post-treatment soil analysis. The derived relationships between the manipulated system variables and experimental results are providing understanding of the mechanisms controlling the ignition and propagation of liquid smouldering. Such insight is necessary for the ongoing design of both ex situ and in situ pilot applications.

  10. TECHNICAL EVALUATION OF REMEDIATION TECHNOLOGIES FOR PLUTONIUM-CONTAMINATED SOILS AT THE NEVADA TEST SITE (NTS)

    Energy Technology Data Exchange (ETDEWEB)

    Steve Hoeffner

    2003-12-31

    The Clemson Environmental Technologies Laboratory (CETL) was contracted by the National Energy Technology Center to evaluate technologies that might be used to reduce the volume of plutonium-contaminated soil at the Nevada Test Site. The project has been systematically approached. A thorough review and summary was completed for: (1) The NTS soil geological, geochemical and physical characteristics; (2) The characteristics and chemical form of the plutonium that is in these soils; (3) Previous volume reduction technologies that have been attempted on the NTS soils; (4) Vendors with technology that may be applicable; and (5) Related needs at other DOE sites. Soils from the Nevada Test Site were collected and delivered to the CETL. Soils were characterized for Pu-239/240, Am-241 and gross alpha. In addition, wet sieving and the subsequent characterization were performed on soils before and after attrition scrubbing to determine the particle size distribution and the distribution of Pu-239/240 and gross alpha as a function of particle size. Sequential extraction was performed on untreated soil to provide information about how tightly bound the plutonium was to the soil. Magnetic separation was performed to determine if this could be useful as part of a treatment approach. Using the information obtained from these reviews, three vendors were selected to demonstration their volume reduction technologies at the CETL. Two of the three technologies, bioremediation and soil washing, met the performance criteria. Both were able to significantly reduce the concentration plutonium in the soil from around 1100 pCi/g to 200 pCi/g or less with a volume reduction of around 95%, well over the target 70%. These results are especially encouraging because they indicate significant improvement over that obtained in these earlier pilot and field studies. Additional studies are recommended.

  11. Reactant Carrier Microfoam Technology for In-Situ Remediation of Radionuclide and Metallic Contaminants in Deep Vadose Zone

    Energy Technology Data Exchange (ETDEWEB)

    Mattigod, Shas V.; Zhong, Lirong; Jansik, Danielle P.; Foote, Martin; Hart, Andrea T.; Wellman, Dawn M.

    2010-07-01

    The U.S. Department of Energy (DOE) is currently developing advanced remedial technologies for addressing metal and radionuclide (Cr, Tc, and U) contamination in deep vadose zone environments. One of the transformational technology alternatives being considered by the DOE Office of Environmental Management, is the use of Reactant Carrier Microfoams (RCM) as a minimally invasive method for delivery and emplacement of reagents for in-situ immobilization of contaminants. Penetration of low permeability zones deep within the subsurface for Enhance Oil Recovery (EOR) has been well-established. Use of surfactant foams have also been explored for mobilizing DNAPL from sediments. So far, the concept of using RCM for immobilizing labile metal and long-lived radionuclide contaminants in the deep vadose zone has not been explored. We, at the Pacific Northwest National Laboratory (PNNL), conducted studies to develop stable foams as a means to deliver reductive and/or precipitating reactants to the deep subsurface. To test the feasibility of this approach, we developed a preliminary foam formulation consisting of a mixture of an anionic and a nonionic surfactant with a reactant consisting of a 9:1 blend of tripoly- and orthophosphate. The MSE Technology Applications, Inc (MSE) in collaboration with PNNL, conducted a scale-up test to evaluate the efficacy of this reactant carrier foam for in-situ immobilization of U containing sediment zones in a heterogenous sediment matrix. The data indicated that successful immobilization of U contamination is feasible using specifically tailored reactant carrier foam injection technology. Studies are continuing for developing more robust optimized RCM for highly mobile contaminants such as Cr (VI), Tc (VII) in the deep vadose zone.

  12. Remedial Action Plan and site design for stabilization of the inactive uranium mill tailings site at Durango, Colorado: Attachment 3, Groundwater hydrology report. Revised final report

    Energy Technology Data Exchange (ETDEWEB)

    1991-12-01

    The US Environmental Protection Agency (EPA) has established health and environmental protection regulations to correct and prevent groundwater contamination resulting from processing activities at inactive uranium milling sites. According to the Uranium Mill Tailings Radiation Control Act of 1978, (UMTRCA) the US Department of Energy (DOE) is responsible for assessing the inactive uranium processing sites. The DOE has determined this assessment shall include information on hydrogeologic site characterization. The water resources protection strategy that describes how the proposed action will comply with the EPA groundwater protection standards is presented in Attachment 4. Site characterization activities discussed in this section include: Characterization of the hydrogeologic environment; characterization of existing groundwater quality; definition of physical and chemical characteristics of the potential contaminant source; and description of local water resources.

  13. Phase I Field Test Results of an Innovative DNAPL Remediation Technology: The Hydrophobic Lance

    Energy Technology Data Exchange (ETDEWEB)

    Tuck, D.M.

    1999-01-28

    An innovative technology for recovery of pure phase DNAPL was deployed in the subsurface near the M-Area Settling Basin, continuing the support of the A/M Area Ground Water Corrective Action Program (per Part B requirements). This technology, the Hydrophobic Lance, operates by placing a neutral/hydrophobic surface (Teflon) in contact with the DNAPL. This changes the in situ conditions experienced by the DNAPL, allowing it to selectively drain into a sump from which it can be pumped. Collection of even small amounts of DNAPL can save years of pump-and-treat operation because of the generally low solubility of DNAPL components.

  14. PHYTOREMEDIATION OF GROUNDWATER AT AIR FORCE PLANT 4, CARSWELL, TEXAS - INNOVATIVE TECHNOLOGY EVALUATION REPORT

    Science.gov (United States)

    Over 600 Cottonwood trees were planted over a shallow groundwater plume in an attempt to detoxify the trichloroethylene (TCE) in a groundwater plume at a former Air Force facility. Two planting techniques were used: rooted stock about two years old, and 18 inch cuttings were inst...

  15. PHYTOREMEDIATION OF GROUNDWATER AT AIR FORCE PLANT 4, CARSWELL, TEXAS - INNOVATIVE TECHNOLOGY EVALUATION REPORT

    Science.gov (United States)

    Over 600 Cottonwood trees were planted over a shallow groundwater plume in an attempt to detoxify the trichloroethylene (TCE) in a groundwater plume at a former Air Force facility. Two planting techniques were used: rooted stock about two years old, and 18 inch cuttings were inst...

  16. Injectable Silica–Permanganate Gel as a Slow-Release MnO4- Source for Groundwater Remediation. Rheological Properties and Release Dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Shuo; Oostrom, Martinus; Truex, Michael J.; Li, G.; Zhong, Lirong

    2016-01-12

    Injectable slow-release permanganate gel (ISRPG), formed by mixing KMnO4 solution with fumed silica powder, may have a potential application in remediating chlorinated solvent plumes in groundwater. A series of batch, column, and flow cell experiments has been completed to test the gel behavior under a variety of conditions. The experiments have provided information on ISRPG rheology, permanganate (MnO4- ) release dynamics and distribution, and trichloroethene (TCE) degradation by ISRPG-released oxidant. The gel possesses remarkable shear thinning characteristics, resulting in a relative low viscosity during mixing, and facilitating its subsurface injection and distribution. Batch tests revealed that MnO4- was diffused out from ISRPG into water while the gel did not dissolve or disperse into water but maintained its initial shape. Column experiments showed that MnO4- release from ISRPG lasted considerably longer than the release from aqueous solution. TCE degradation by ISRPG-released MnO4- was much more effective than that when MnO4- was delivered using aqueous solution injection. In two-dimensional flow cell experiments, it was demonstrated that ISRPG slowly released a long-lasting low concentration MnO4- plume sufficient for remediation and sustainable in an aquifer for a long period of time.

  17. REMOVAL OF ADDED NITRATE IN THE SINGLE, BINARY, AND TERNARY SYSTEMS OF COTTON BURR COMPOST, ZEROVALENT IRON, AND SEDIMENT: IMPLICATIONS FOR GROUNDWATER NITRATE REMEDIATION USING PERMEABLE REACTIVE BARRIERS

    Science.gov (United States)

    Recent research has shown that carbonaceous solid materials and zerovalent iron (Fe0) may potentially be used as media in permeable reactive barriers (PRBs) to degrade groundwater nitrate via heterotrophic denitrification in the solid carbon system, and via abiotic reduction and ...

  18. REMOVAL OF ADDED NITRATE IN THE SINGLE, BINARY, AND TERNARY SYSTEMS OF COTTON BURR COMPOST, ZEROVALENT IRON, AND SEDIMENT: IMPLICATIONS FOR GROUNDWATER NITRATE REMEDIATION USING PERMEABLE REACTIVE BARRIERS

    Science.gov (United States)

    Recent research has shown that carbonaceous solid materials and zerovalent iron (Fe0) may potentially be used as media in permeable reactive barriers (PRBs) to degrade groundwater nitrate via heterotrophic denitrification in the solid carbon system, and via abiotic reduction and ...

  19. Mining the waste: prospecting valuable residues optimising processes with modern technology sustainably remediating legacy sites

    OpenAIRE

    Lemière, Bruno

    2012-01-01

    International audience; Prospecting valuable residuesAbandoned waste from closed mines or past operations may contain profitably recoverable commodities:-when the market price of the commodity increased significantly since mine closure,-when processing technology improved significantly since mine closure,-when another commodity present in the ore was not recovered and thus sent to waste, because it was not of commercial value at the time. This is especially relevant for some high-tech element...

  20. Smart technologies for detecting animal welfare status and delivering health remedies for rangeland systems.

    Science.gov (United States)

    Rutter, S M

    2014-04-01

    Although the emerging field of precision livestock farming (PLF) is predominantly associated with intensive animal production, there is increasing interest in applying smart technologies in extensive rangeland systems. Precision livestock farming technologies bring the possibility of closely monitoring the behaviour, liveweight and other parameters of individual animals in free-ranging systems. 'Virtual fencing', ideally based on positive reinforcement, i.e. rewarding animals for moving in a specified direction, has the potential to gently guide foraging livestock towards areas of vegetation identified by remote sensing. As well as reducing hunger, this could be integrated with weather forecasting to help ensure that animals are automatically directed to areas with appropriate shelter when adverse weather is forecast. The system could also direct animals towards handling facilities when required, reducing the fear and distress associated with being mustered. The integration of the various data collected by such a 'virtual shepherd' system should be able to rapidly detect disease and injury, and sick animals could then be automatically shepherded to an enclosure for treatment. In general, rangeland livestock already have the freedom to express normal behaviour, but PLF technologies could facilitate this. By bringing levels of monitoring and control normally associated with intensive production to rangeland systems, PLF has the potential, with appropriate adoption, to enhance the capacity of rangeland livestock production systems to meet key areas of welfare concern highlighted by the Five Freedoms.

  1. 300 Area Treatability Test: Laboratory Development of Polyphosphate Remediation Technology for In Situ Treatment of Uranium Contamination in the Vadose Zone and Capillary Fringe

    Energy Technology Data Exchange (ETDEWEB)

    Wellman, Dawn M.; Pierce, Eric M.; Bacon, Diana H.; Oostrom, Martinus; Gunderson, Katie M.; Webb, Samuel M.; Bovaird, Chase C.; Cordova, Elsa A.; Clayton, Eric T.; Parker, Kent E.; Ermi, Ruby M.; Baum, Steven R.; Vermeul, Vincent R.; Fruchter, Jonathan S.

    2008-09-30

    This report presents results from bench-scale treatability studies conducted under site-specific conditions to optimize the polyphosphate amendment for implementation of a field-scale technology demonstration to stabilize uranium within the 300 Area vadose and smear zones of the Hanford Site. The general treatability testing approach consisted of conducting studies with site sediment and under site conditions, to develop an effective chemical formulation and infiltration approach for the polyphosphate amendment under site conditions. Laboratory-scale dynamic column tests were used to 1) quantify the retardation of polyphosphate and its degradation products as a function of water content, 2) determine the rate of polyphosphate degradation under unsaturated conditions, 3) develop an understanding of the mechanism of autunite formation via the reaction of solid phase calcite-bound uranium and aqueous polyphosphate remediation technology, 4) develop an understanding of the transformation mechanism, the identity of secondary phases, and the kinetics of the reaction between uranyl-carbonate and -silicate minerals with the polyphosphate remedy under solubility-limiting conditions, and 5) quantify the extent and rate of uranium released and immobilized based on the infiltration rate of the polyphosphate remedy and the effect of and periodic wet-dry cycling on the efficacy of polyphosphate remediation for uranium in the vadose zone and smear zone.

  2. Technology Survey to Support Revision to the Remedial Investigation/Feasibility Study Work Plan for the 200­-SW­-2 Operable Unit at the U.S. Department of Energy’s Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Truex, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Johnson, Christian D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Nimmons, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2007-09-01

    A survey of technologies was conducted to provide information for a Data Quality Objectives process being conducted to support revision of the Remedial Investigation/Feasibility Study Work Plan for the 200-SW-2 Operable Unit. The technology survey considered remediation and characterization technologies. This effort was conducted to address, in part, comments on the previous version of the Remedial Investigation/Feasibility Study Work Plan for the 200-SW-2 Operable Unit as documented in 200­SW­1 and 200­SW­2 Collaborative Workshops-Agreement, Completion Matrix, and Supporting Documentation. By providing a thorough survey of remediation and characterization options, this report is intended to enable the subsequent data quality objectives and work plan revision processes to consider the full range of potential alternatives for planning of the Remedial Investigation/Feasibility Study activities.

  3. Field demonstration of rapid turnaround, multilevel groundwater screening

    Energy Technology Data Exchange (ETDEWEB)

    Tingle, A.R. [Analysas Corp., Oak Ridge, TN (United States); Baker, L. [Automated Sciences Group, Inc., Oak Ridge, TN (United States); Long, D.D. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Hazardous Waste Remedial Actions Program; Miracle, M. [Advanced Sciences, Inc., Oak Ridge, TN (United States)

    1994-09-01

    A combined technology approach to rapidly characterizing source area and downgradient groundwater associated with a past fuel spill has been field tested. The purpose of this investigation was to determine the presence and extent of fuel-related compounds or indications of their biodegradation in groundwater. The distance from the source area to be investigated was established by calculating the potential extent of a plume based only on groundwater flow velocities. To accomplish this objective, commercially available technologies were combined and used to rapidly assess the source area and downgradient groundwater associated with the fuel discharge. The source of contamination that was investigated overlies glacial sand and gravel outwash deposits. Historical data suggest that from 1955 to 1970 as many as 1 to 6 million pi of aviation gasoline (AVGAS) were god at the study area. Although the remedial investigation (RI) for this study area indicated fuel-related groundwater contamination at the source area, fuel-related contamination was not detected in downgradient monitoring wells. Rapid horizontal groundwater velocities and the 24-year time span from the last reported spill farther suggest that a plume of contaminated groundwater could extend several thousand feet downgradient. The lack of contamination downgradient from the source suggests two possibilities: (1) monitoring wells installed during the RI did not intersect the plume or (2) fuel-related compounds had naturally degraded.

  4. [Remedial action plan for the codisposal and stabilization of the Monument Valley and Mexican Hat uranium mill tailings at Mexican Hat, Utah]. Appendix F, Groundwater hydrology calculations

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-12-31

    This document contains the ground water hydrology calculations for the remedial action plan for the codisposal and stabilization of uranium mill tailings at Mexican Hat, Utah. Included are calculations for the following: slug test analyses for monitor wells, analyses of packer tests, hydraulic gradients and ground water velocities, volume of released water, aquifer pumping test analysis, slug test analysis to determine hydraulic conductivity, and gradient calculations.

  5. Conceptual design and experiments of electrochemistry-flushing technology for the remediation of historically Cr(Ⅵ)-contaminated soil.

    Science.gov (United States)

    Li, Dong; Sun, Delin; Hu, Siyang; Hu, Jing; Yuan, Xingzhong

    2016-02-01

    A conceptual design and experiments, electrochemistry-flushing (E-flushing), using electrochemistry to enhance flushing efficiency for the remediation of Cr(Ⅵ)-contaminated soil is presented. The rector contained three compartments vertically superposed. The upper was airtight cathode compartment containing an iron-cathode. The middle was soil layer. The bottom was anode compartment containing an iron-anode and connected to a container by circulation pumps. H2 and OH(-) ions were produced at cathode. H2 increased the gas pressure in cathode compartment and drove flushing solution into soil layer forming flushing process. OH(-) ions entered into soil layer by eletromigration and hydraulic flow to enhance the desorption of Cr(Ⅵ). High potential gradient was applied to accelerate the electromigration of desorbed Cr(Ⅵ) ions and produced joule heat to increase soil temperature to enhance Cr(Ⅵ) desorption. In anode compartment, Fe(2+) ions produced at iron-anode reduced the desorbed Cr(Ⅵ) into Cr(3+) ions, which reacted with OH(-) ions forming Cr(OH)3. Experimental results show that Cr(Ⅵ) removal efficiency of E-flushing experiments was more than double of flushing experiments and reached the maximum of removal efficiency determined by desorption kinetics. All electrochemistry processes were positively used in E-flushing technology.

  6. PRB groundwater remediation technology review%地下水污染修复中的PRB技术研究

    Institute of Scientific and Technical Information of China (English)

    熊雪萍; 李福林; 陈学群

    2010-01-01

    PRB--渗透反应墙技术是近年来广泛应用的一种地下水污染修复技术.文中介绍了其基本概念、基本原理、结构类型、安装要素和主要材料选取.该技术在我国具有良好的应用前景.

  7. Simulation for the development of the continuous groundwater flow measurement technology

    Science.gov (United States)

    Kobayashi, Kaoru; Kumagai, Koki; Fujima, Ritsuko; Chikahisa, Hiroshi

    The flow of groundwater varies with time due to rainfall, atmospheric pressure change, tidal change, melting of snow during seasonal change, underground construction works etc. Therefore, to increase the precision of assessing in-situ groundwater flow characteristics, it is important to measure continuously the direction and velocity of the flow, in addition to obtaining accurate data for the afore mentioned environmental changes. The first part of this paper describes the development of a new device for measuring the direction and velocity of groundwater flow. The device was composed of a unique floating sensor with a hinge end at the bottom, which enabled continuous measurement of groundwater flow based on image data processing technique. In the second part, discussion is focused on clarifying the optimum cross-section shape and the behavior of the float sensor in saltwater and freshwater using numerical analysis.

  8. Biological remediation of petroleum hydrocarbons from a refinery's soil : comparison of different technologies

    Energy Technology Data Exchange (ETDEWEB)

    Nazare Couto, M.; Vasconcelos, T.S.D. [CIMAR/CIIMAR, Porto (Portugal)

    2007-07-01

    This presentation discussed bioremediation methods used at a refinery in Portugal with a high distillation capacity. The aim of the project was to develop a method for restoring contaminated sites using rhizoremediation and bio-augmentation. Hydrocarbon molecules were tightly sorbed to the soil particles at the refinery. Plants used in the bioremediation project included Scirpus maritimus and Juncus maritimus, as well as Cortoaderia selloana taken from an estuary near the refinery. Tests were conducted both with, and without the use of microorganisms. Commercial bio-augmentation products were used. Plant growth was evaluated for a period of 64 days. It was concluded that the technology is cheaper than many traditional methods of treating hydrocarbon-contaminated soils. tabs., figs.

  9. Remedial Measures for Counterbalancing the After Effects of Green Revolution on the Georesources of Groundwater, Land and Soil in Haryana, India

    Science.gov (United States)

    Sharma, A.; Lunkad, S. K.

    2008-05-01

    In Haryana, one of the wheat granaries of India where water resources have depleted to a critical level (1050 m3 /year/person), groundwater alone has 53% share in the irrigation, the remaining 47% comes from canal system of glacier-fed rivers, viz., Yamuna and Satluj originating from Himalayas. The Green Revolution (1971-1990, intensive phase) enabled this small state to become an agro-economic state in northern alluvial plains of India. Though occupying 1.3 % geographical area and containing 2% of the population of India, it produces country's 13% wheat and about 3% quality rice besides other cereals, oil seeds, sugarcane and cotton. However, Haryana paid a heavy price for the impressive agricultural development- one-third of the irrigated land is salinity affected, water level declined by 3-12 m in twelve of its nineteen districts and excessive nitrate levels in the groundwater (114-1800 mg/l) have rendered the groundwater non-potable in many areas. Groundwater in the arid western Haryana is mostly saline (TDS > 4000 mg/l) and irrational canal irrigation has paradoxically raised the water-table by 3-9m in seven districts causing waterlogging over 2346 km2 land of which 251 km2 is fully waterlogged. In the land use pattern 131,000 ha prime cultivable land (about 3% of the total) has been lost to urbanization jeopardizing the FOOD SECURITY. One possible way to arrest the degradation of groundwater and soil, is to switch to dryland farming. This would involve change in the irrigation method as well as proper selection and rotation of food crops like barley, sorghum, maize, different types of beans (pulses) and oil seeds like groundnut, sunflower, mustard, etc. and restricted use of chemical fertilizers and pesticides. Dryland farming could go hand in hand with the plantation of fruit trees, grasses and medicinal plants suitable to this agro-climatic zone, and animal husbandry. The same considerations also hold good to the adjoining eastern Rajasthan.

  10. Blind Inlet as a Possible Technology for the Remediation of Phosphorus from Surface Runoff

    Science.gov (United States)

    Sturmlechner, M.; Wu, X.; Livingston, S.; Klik, A.; Huang, C. H.

    2015-12-01

    Phosphorus (P) is an essential element for plant life, but too much P in runoff water can cause eutrophication and harmful algal blooms. Hence, mitigation of agricultural P losses into the water cycle is a very important issue. In-stream P treatment is difficult to implement because the large amount of storm runoff needs to be treated in short durations. In this research, we evaluated the potential to use blind inlet as an in-field P treatment technology. A box system was built to simulate hydrological and chemical processes occurring in a blind inlet. Current blind inlets, which are already installed in the field, use a bed of limestone with a sand/pea gravel layer on the top. In this study, steel slags has been tested, which has a very high P sorption potential, as the filter media through a series of adsorption and desorption experiments. The P mass balance results are compared with the limestone material used in current blind inlet construction. The total mass of P which was absorbed by the limestone was 14 % of the P input into the system whereas 26 % P was absorbed by the steel slags. Therefore the steel slags show potential to sequester dissolved P. Additional research is on-going to come up with a design criteria for field implementation.

  11. Dispersion modeling to compare alternative technologies for odor remediation at swine facilities.

    Science.gov (United States)

    Schiffman, Susan S; Graham, Brevick G; Williams, C Mike

    2008-09-01

    The effectiveness of 18 alternative technologies for reducing odor dispersion at and beyond the boundary of swine facilities was assessed in conjunction with an initiative sponsored through agreements between the Attorney General of North Carolina and Smithfield Foods, Premium Standard Farms, and Frontline Farmers. The trajectory and spatial distribution of odor emitted at each facility were modeled at 200 and 400 m downwind from each site under two meteorological conditions (daytime and nighttime) using a Eulerian-Lagrangian model. To predict the dispersion of odor downwind, the geographical area containing the odorant sources at each facility was partitioned into 10-m2 grids on the basis of satellite photographs and architectural drawings. Relative odorant concentrations were assigned to each grid point on the basis of intensity measurements made by the trained odor panel at each facility using a 9-point rating scale. The results of the modeling indicated that odor did not extend significantly beyond 400 m downwind of any of the test sites during the daytime when the layer of air above the earth's surface is usually turbulent. However, modeling indicated that odor from all full-scale farms extended beyond 400 m onto neighboring property in the evenings when deep surface cooling through long-wave radiation to space produces a stable (nocturnal) boundary layer. The results also indicated that swine housing, independent of waste management type, plays a significant role in odor downwind, as do odor sources of moderate to moderately high intensity that emanate from a large surface area such as a lagoon. Human odor assessments were utilized for modeling rather than instrument measurements of volatile organic compounds (VOCs), hydrogen sulfide, ammonia, or particulates less than 10 microm in diameter (PM10) because these physical measurements obtained simultaneously with human panel ratings were not found to accurately predict human odor intensity in the field.

  12. Survey of subsurface treatment technologies for environmental restoration sites at Sandia National Laboratories, New Mexico.

    Energy Technology Data Exchange (ETDEWEB)

    McGrath, Lucas K.; Ho, Clifford Kuofei; Wright, Jerome L.

    2003-08-01

    This report provides a survey of remediation and treatment technologies for contaminants of concern at environmental restoration (ER) sites at Sandia National Laboratories, New Mexico. The sites that were evaluated include the Tijeras Arroyo Groundwater, Technical Area V, and Canyons sites. The primary contaminants of concern at these sites include trichloroethylene (TCE), tetrachloroethylene (PCE), and nitrate in groundwater. Due to the low contaminant concentrations (close to regulatory limits) and significant depths to groundwater ({approx}500 feet) at these sites, few in-situ remediation technologies are applicable. The most applicable treatment technologies include monitored natural attenuation and enhanced bioremediation/denitrification to reduce the concentrations of TCE, PCE, and nitrate in the groundwater. Stripping technologies to remove chlorinated solvents and other volatile organic compounds from the vadose zone can also be implemented, if needed.

  13. EVALUATION OF THOR MINERALIZED WASTE FORMS FOR THE DOE ADVANCED REMEDIATION TECHNOLOGIES PHASE 2 PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, C.; Jantzen, C.

    2012-02-02

    , sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product, which is one of the objectives of this current study, is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. FBSR testing of a Hanford LAW simulant and a WTP-SW simulant at the pilot scale was performed by THOR Treatment Technologies, LLC at Hazen Research Inc. in April/May 2008. The Hanford LAW simulant was the Rassat 68 tank blend and the target concentrations for the LAW was increased by a factor of 10 for Sb, As, Ag, Cd, and Tl; 100 for Ba and Re (Tc surrogate); 1,000 for I; and 254,902 for Cs based on discussions with the DOE field office and the environmental regulators and an evaluation of the Hanford Tank Waste Envelopes A, B, and C. It was determined through the evaluation of the actual tank waste metals concentrations that some metal levels were not sufficient to achieve reliable detection in the off-gas sampling. Therefore, the identified metals concentrations were increased in the Rassat simulant processed by TTT at HRI to ensure detection and enable calculation of system removal efficiencies, product retention efficiencies, and mass balance closure without regard to potential results of those determinations or impacts on product durability response such as Toxicity Characteristic Leach Procedure (TCLP). A WTP-SW simulant based on melter off-gas analyses from Vitreous State Laboratory (VSL) was also tested at HRI in the 15-inch diameter Engineering Scale Test Demonstration (ESTD) dual reformer at HRI in 2008. The target concentrations for the Resource Conservation and Recovery Act (RCRA) metals were increased by 16X for Se, 29X for

  14. EVALUATION OF THOR MINERALIZED WASTE FORMS FOR THE DOE ADVANCED REMEDIATION TECHNOLOGIES PHASE 2 PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, C.; Jantzen, C.

    2012-02-02

    , sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product, which is one of the objectives of this current study, is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. FBSR testing of a Hanford LAW simulant and a WTP-SW simulant at the pilot scale was performed by THOR Treatment Technologies, LLC at Hazen Research Inc. in April/May 2008. The Hanford LAW simulant was the Rassat 68 tank blend and the target concentrations for the LAW was increased by a factor of 10 for Sb, As, Ag, Cd, and Tl; 100 for Ba and Re (Tc surrogate); 1,000 for I; and 254,902 for Cs based on discussions with the DOE field office and the environmental regulators and an evaluation of the Hanford Tank Waste Envelopes A, B, and C. It was determined through the evaluation of the actual tank waste metals concentrations that some metal levels were not sufficient to achieve reliable detection in the off-gas sampling. Therefore, the identified metals concentrations were increased in the Rassat simulant processed by TTT at HRI to ensure detection and enable calculation of system removal efficiencies, product retention efficiencies, and mass balance closure without regard to potential results of those determinations or impacts on product durability response such as Toxicity Characteristic Leach Procedure (TCLP). A WTP-SW simulant based on melter off-gas analyses from Vitreous State Laboratory (VSL) was also tested at HRI in the 15-inch diameter Engineering Scale Test Demonstration (ESTD) dual reformer at HRI in 2008. The target concentrations for the Resource Conservation and Recovery Act (RCRA) metals were increased by 16X for Se, 29X for

  15. Deciphering groundwater potential zones in hard rock terrain using geospatial technology.

    Science.gov (United States)

    Dar, Imran A; Sankar, K; Dar, Mithas A

    2011-02-01

    Remote sensing and geographical information system (GIS) has become one of the leading tools in the field of groundwater research, which helps in assessing, monitoring, and conserving groundwater resources. This paper mainly deals with the integrated approach of remote sensing and GIS to delineate groundwater potential zones in hard rock terrain. Digitized vector maps pertaining to chosen parameters, viz. geomorphology, geology, land use/land cover, lineament, relief, and drainage, were converted to raster data using 23 m×23 m grid cell size. Moreover, curvature of the study area was also considered while manipulating the spatial data. The raster maps of these parameters were assigned to their respective theme weight and class weights. The individual theme weight was multiplied by its respective class weight and then all the raster thematic layers were aggregated in a linear combination equation in Arc Map GIS Raster Calculator module. Moreover, the weighted layers were statistically modeled to get the areal extent of groundwater prospects with respect to each thematic layer. The final result depicts the favorable prospective zones in the study area and can be helpful in better planning and management of groundwater resources especially in hard rock terrains.

  16. Geothermal energy plants. Technologies and risk of soil and groundwater pollution; Jordvarmeanlaeg. Teknologier og risiko for jord- og grundvandsforurening

    Energy Technology Data Exchange (ETDEWEB)

    Villumsen, B. (COWI A/S, Kgs. Lyngby (Denmark))

    2008-07-01

    Ground source heat systems utilise the natural heat in the ground to heat houses and domestic hot water. The technology is energy-saving and can therefore contribute to the targets of reducing Denmark's CO{sub 2} emissions. All else being equal, a ground source heat system containing chemicals poses a potential contamination risk to soil and groundwater. Therefore a permit is required when installing a ground source heat system, and the general regulations for implementing the system etc. combined with the municipality's administrative procedures for the area must ensure sufficient protection of the groundwater. This project only deals with the heat exchanging system, which is the part of the ground source heat system which involves risk of soil and groundwater contamination. The aim of the project is to procure an overall updated knowledge base about the different types of ground source heat systems and the contamination risk associated with them. The project also reviews how disadvantages can be managed or minimized. (au)

  17. A process for containment removal and waste volume reduction to remediate groundwater containing certain radionuclides, toxic metals and organics. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Buckley, L.P.; Killey, D.R.W.; Vijayan, S.; Wong, P.C.F. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.

    1992-09-01

    A project to remove groundwater contaminants by an improved treatment process was performed during 1990 October--1992 March by Atomic Energy of Canada Limited for the United States Department of Energy, managed by Argonne National Laboratory. The goal was to generate high-quality effluent while minimizing secondary waste volume. Two effluent target levels, within an order of magnitude, or less than the US Drinking Water Limit, were set to judge the process effectiveness. The program employed mixed waste feeds containing cadmium, uranium, lead, iron, calcium, strontium-85-90, cesium-137, benzene and trichlorethylene in simulated and actual groundwater and soil leachate solutions. A combination of process steps consisting of sequential chemical conditioning, cross-flow microfiltration and dewatering by low temperature-evaporation, or filter pressing were effective for the treatment of mixed waste having diverse physico-chemical properties. A simplified single-stage version of the process was implemented to treat ground and surface waters contaminated with strontium-90 at the Chalk River Laboratories site. Effluent targets and project goals were met successfully.

  18. Slow-release Permanganate Gel (SRP-G) for Groundwater Remediation: Spreading, Gelation, and Release in Porous and Low-Permeability Media

    Science.gov (United States)

    Lee, E. S.; Hastings, J.; Kim, Y.

    2015-12-01

    Dense nonaqueous phase liquids (DNAPLs) like trichloroethylene (TCE) serve as the most common form of groundwater pollution in the world. Pore-plugging by the solid oxidation product MnO2 and limited lateral dispersion of the oxidant are two common problems with existing in-situ chemical oxidation (ISCO) schemes that could be alleviated through the development of a delayed gelation method for oxidant delivery. The objective of the current study was to further develop and optimize slow-release permanganate gel (SRP-G), a solution comprising colloidal silica and KMnO4, as a novel low-cost treatment option for large and dilute TCE plumes in groundwater. Batch tests showed that gelation could be delayed through manipulation of KMnO4 concentration, pH, and silica particle size of the SRP-G solution. In flow-through columns and flow-tanks filled with saturated sands, silica concentration had little effect on the gelation lag stage and release rate, but increasing silica concentration was associated with increasing release duration. When compared to a pure KMnO4 solution, visual observations and [MnO4-] measurements from flow tank tests demonstrated that the SRP-G prolonged the release duration and enhanced lateral spreading of the oxidant.

  19. The Present Situation and Countermeasures of Groundwater Contamination in Japan

    OpenAIRE

    Shindo, Shizuo; Tang, Changyuan

    1997-01-01

    [ABSTRACT] Since 1982, thousands of groundwater pollution cases have been found in Japan. In order to improve the groundwater quality, Japan has developed strategies for protection of groundwater. In this paper, authors try to explain the present of groundwater use, groundwater pollution and remediation methods in Japan. From the results shown in this paper, it can be found that groundwater pollution problem has become very serious in Japan. Even many efforts have been made to improve the sit...

  20. Experimental Research on PRB Reaction Medium in Remediation of Nitrate Contaminated Groundwater%PRB反应介质修复地下水中硝酸盐的试验研究

    Institute of Scientific and Technical Information of China (English)

    袁玉英; 李福林; 陈学群; 管清花; 杨丽原

    2011-01-01

    Taking groundwater of Qianhang in Jiaozhou City for an example, six kinds of PRB reactors are designed by selecting iron powder, active carbon, sawdust and its mixtures as reaction medium. The influence of reaction medium on the nitrate degradation rate and environment is discussed to find a cheap and efficient material for nitrate degradation of groundwater. The results show that the PRB technology is effective for nitrate degradation of groundwater; zero-valent I-ron, active carbon and sawdust have a certain adsorptive effect on nitrate; when PRB reactor contains zero-valent iron, it can remove more than 90% of nitrate.%以胶州前转地下水为例,选用铁粉、活性炭、锯末及其混合物为反应介质,设计6种PRB反应器,探讨了反应介质对硝酸盐降解速率及对环境的影响,以寻求一种廉价而高效的降解地下水中硝酸盐的材料.结果表明,采用PRB技术降低地下水硝酸盐浓度是可行的.零价铁、活性炭、锯末均对硝酸盐有去除作用,当PRB反应器中含有铁粉时能将硝酸盐氮去除90%以上.

  1. Critical review of decision support tools for sustainability assessment of site remediation options.

    Science.gov (United States)

    Huysegoms, Lies; Cappuyns, Valérie

    2017-07-01

    In Europe alone, there are more than 2,5 million potentially contaminated sites of which 14% are expected to require remediation. Contaminated soil and groundwater can cause damage to human health as well as to valuable ecosystems. Globally more attention has been paid to this problem of soil contamination in the past decades. For example, more than 58 000 sites have been remediated in Europe between 2006 and 2011. Together with this increase in remediation projects there has been a surge in the development of new remediation technologies and decision support tools to be able to match every site and its specific characteristics to the best possible remediation alternative. In the past years the development of decision support tools (DST) has evolved in a more sustainable direction. Several DSTs added the claim not only to denote effective or technologically and economically feasible remediation alternatives but also to point out the more or most sustainable remediation alternatives. These trends in the evaluation of site remediation options left users with a confusing clew of possibly applicable tools to assist them in decision making for contaminated site remediation. This review provides a structured overview on the extent decision support tools for contaminated site remediation, that claim to assist in choosing the most sustainable remediation alternative, actually include the different elements of sustainability proposed in our assessment framework. The review contains an in-depth analysis of thirteen tools specifically developed to assess the sustainability of site remediation alternatives. This analysis is based on six criteria derived from the definition of sustainable development of the Brundtland report. The six criteria were concretized by using the three pillars of sustainability, applied to site remediation according to the SuRF-UK framework, two criteria derived from Life Cycle Assessment and Cost-Benefit Analysis, and an 'User friendly' criterion

  2. Nitrate contamination of groundwater and its countermeasures

    Energy Technology Data Exchange (ETDEWEB)

    Mitamura, Hisayoshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2003-03-01

    The inevitable increases of food production and energy consumption with an increase in world population become main causes of an increase of nitrate load to the environment. Although nitrogen is essential for the growth of animal and plant as a constituent element of protein, excessive nitrate load to the environment contaminates groundwater resources used as drinking water and leads to seriously adverse effects on the health of man and livestock. In order to clarify the problem of nitrate contamination of groundwater and search a new trend of technology development from the viewpoint of environment remediation and protection, the present paper has reviewed adverse effects of nitrate on human health, the actual state of nitrogen cycle, several kinds of nitrate sources, measures for reducing nitrate level, etc. (author)

  3. Challenges in subsurface in situ remediation of chlorinated solvents

    DEFF Research Database (Denmark)

    Broholm, Mette Martina; Fjordbøge, Annika Sidelmann; Christiansen, Camilla Maymann

    2014-01-01

    Chlorinated solvent source zones in the subsurface pose a continuous threat to groundwater quality at many sites worldwide. In situ remediation of these sites is particularly challenging in heterogeneous fractured media and where the solvents are present as DNAPL. In situ remediation by chemical...... as well as biological degradation of chlorinated solvents is a contact sport and requires direct contact between the contaminant and the reactants and/or degrading microorganisms. In fractured geologic media, where contaminants have spread to the low permeability matrix by diffusion, the contact between......-clay mixing for contact; hydrophobic and/or mobile nano-reactants targeting DNAPL. The complexity of the technologies varies greatly and the current level of implementation ranges from multiple full scale applications to bench scale testing. However, the basic degradation reaction involved is usually well...

  4. 零价纳米铁在修复受污染地下水中的最新进展%Recent Progress of Application of Nanoscale Zero-valent Iron in Remediation of Contaminated Groundwater

    Institute of Scientific and Technical Information of China (English)

    钱雅洁; 周雪飞; 张亚雷

    2012-01-01

    To solve the problems existing in remediation of contaminated groundwater using nanoscale zero-valent iron (nZVI) such as aggregation, low migration and aging, some new progresses in this field were introduced in this paper in detail including modified nZVI and its effect on degradation of pollutants as well as different factors else. In addition, the degradation of recalcitrant organic pollutants by nZVI was summarized. And then the degradation of some special materials such as emerging pollutants, pharmaceuticals and personal care products (PPCPs) was prospected.%本文针对零价纳米铁(nZVI)在修复受污染地下水中存在的易于团聚、迁移性低及易于老化等问题,详细介绍了近年在这些问题研究上的最新进展,包括材料的改性,改性材料对污染物降解的效果及研究中不同因素的影响等。并就nZVI对难降解复杂有机污染物的降解进行了总结,在此基础上展望了nZVI对一类新兴污染物,药品和个人护理用品(PPCPs)的降解。

  5. Drivers and applications of integrated clean-up technologies for surfactant-enhanced remediation of environments contaminated with polycyclic aromatic hydrocarbons (PAHs).

    Science.gov (United States)

    Liang, Xujun; Guo, Chuling; Liao, Changjun; Liu, Shasha; Wick, Lukas Y; Peng, Dan; Yi, Xiaoyun; Lu, Guining; Yin, Hua; Lin, Zhang; Dang, Zhi

    2017-06-01

    Surfactant-enhanced remediation (SER) is considered as a promising and efficient remediation approach. This review summarizes and discusses main drivers on the application of SER in removing polycyclic aromatic hydrocarbons (PAHs) from contaminated soil and water. The effect of PAH-PAH interactions on SER efficiency is, for the first time, illustrated in an SER review. Interactions between mixed PAHs could enhance, decrease, or have no impact on surfactants' solubilization power towards PAHs, thus affecting the optimal usage of surfactants for SER. Although SER can transfer PAHs from soil/non-aqueous phase liquids to the aqueous phase, the harmful impact of PAHs still exists. To decrease the level of PAHs in SER solutions, a series of SER-based integrated cleanup technologies have been developed including surfactant-enhanced bioremediation (SEBR), surfactant-enhanced phytoremediation (SEPR) and SER-advanced oxidation processes (SER-AOPs). In this review, the general considerations and corresponding applications of the integrated cleanup technologies are summarized and discussed. Compared with SER-AOPs, SEBR and SEPR need less operation cost, yet require more treatment time. To successfully achieve the field application of surfactant-based technologies, massive production of the cost-effective green surfactants (i.e. biosurfactants) and comprehensive evaluation of the drivers and the global cost of SER-based cleanup technologies need to be performed in the future. Copyright © 2017. Published by Elsevier Ltd.

  6. Regionally contaminated aquifers--toxicological relevance and remediation options (Bitterfeld case study).

    Science.gov (United States)

    Heidrich, Susanne; Schirmer, Mario; Weiss, Holger; Wycisk, Peter; Grossmann, Jochen; Kaschl, Arno

    2004-12-15

    Large-scale contaminated megasites like Bitterfeld in eastern Germany are characterized by a regional contamination of soil, surface water and groundwater as a result of a long and varied history of chemical production. While the contaminants in soils and sediments mostly represent a localized problem, pollutants in groundwater may spread to uncontaminated areas and endanger receptors like surface water and drinking water wells according to the site-specific hydrologic regime. From the toxicological point of view, the contaminants at the Bitterfeld megasite represent a dangerous cocktail of various harmful substances coming from a multitude of sources. Appropriate remediation techniques must be able to remedy the specific problems arising from hot spot areas within the megasite in addition to preventing a further extension of the contaminated zone towards uncontaminated compartments. Therefore, a combination of specifically designed remediation technologies based on the pump and treat-principle with in situ technologies, such as reactive walls and monitored/enhanced natural attenuation, is necessary to efficiently address the miscellaneous challenges at this megasite. In this paper, the currently known contaminant distribution, the associated problems for human health and the environment and possible remediation strategies are presented for the Bitterfeld megasite.

  7. Microorganisms in heavy metal bioremediation: strategies for applying microbial-community engineering to remediate soils

    Directory of Open Access Journals (Sweden)

    Jennifer L. Wood

    2016-06-01

    Full Text Available The remediation of heavy-metal-contaminated soils is essential as heavy metals persist and do not degrade in the environment. Remediating heavy-metal-contaminated soils requires metals to be mobilized for extraction whilst, at the same time, employing strategies to avoid mobilized metals leaching into ground-water or aquatic systems. Phytoextraction is a bioremediation strategy that extracts heavy metals from soils by sequestration in plant tissues and is currently the predominant bioremediation strategy investigated for remediating heavy-metal-contaminated soils. Although the efficiency of phytoextraction remains a limiting feature of the technology, there are numerous reports that soil microorganisms can improve rates of heavy metal extraction.This review highlights the unique challenges faced when remediating heavy-metal-contaminated soils as compared to static aquatic systems and suggests new strategies for using microorganisms to improve phytoextraction. We compare how microorganisms are used in soil bioremediation (i.e. phytoextraction and water bioremediation processes, discussing how the engineering of microbial communities, used in water remediation, could be applied to phytoextraction. We briefly outline possible approaches for the engineering of soil communities to improve phytoextraction either by mobilizing metals in the rhizosphere of the plant or by promoting plant growth to increase the root-surface area available for uptake of heavy metals. We highlight the technological advances that make this research direction possible and how these technologies could be employed in future research.

  8. Innovative fossil fuel fired vitrification technology for soil remediation. Volume 1, Phase 1: Annual report, September 28, 1992--August 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-01

    Vortex has successfully completed Phase 1 of the ``Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation`` program with the Department of Energy (DOE) Morgantown Energy Technology Center (METC). The Combustion and Melting System (CMS) has processed 7000 pounds of material representative of contaminated soil that is found at DOE sites. The soil was spiked with Resource Conversation and Recovery Act (RCRA) metals surrogates, an organic contaminant, and a surrogate radionuclide. The samples taken during the tests confirmed that virtually all of the radionuclide was retained in the glass and that it did not leach to the environment. The organic contaminant, anthracene, was destroyed during the test with a Destruction and Removal Efficiency (DRE) of at least 99.99%. RCRA metal surrogates, that were in the vitrified product, were retained and will not leach to the environment--as confirmed by the TCLP testing. Semi-volatile RCRA metal surrogates were captured by the Air Pollution Control (APC) system, and data on the amount of metal oxide particulate and the chemical composition of the particulate were established for use in the Phase 2 APC system design. This topical report will present a summary of the activities conducted during Phase 1 of the ``Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation`` program. The report includes the detail technical data generated during the experimental program and the design and cost data for the preliminary Phase 2 plant.

  9. Assessment of TVOC and Odor in the Remediation Site of Contaminated Soil and Groundwater Using Electronic Nose%基于电子鼻土壤与地下水污染修复现场TVOC和恶臭的评估

    Institute of Scientific and Technical Information of China (English)

    田秀英; 蔡强; 刘锐; 张永明

    2013-01-01

    According to the conditions of a contaminated soil and groundwater remediation site in Shanghai, the self-built electronic nose was applied to detect VOCs and odor of previously remedied soil and groundwater, remedying soil and groundwater, and the air above and around the site. Combining the formula of TPI and OPI, the value of each point was got and was shown in figures. Results showed:① Comparing the determination results of previously remedied with remedying contaminated soil and groundwater, the concentration of TVOC and odor was overall declined. The result was consistent with the fact. The detection result of electronic nose was proved to be right; ② In the remediation process of soil and groundwater, the volatilization of VOCs and odor was inflected by temperature and works of crushing, adding medicine and turning the soil on time. The concentration showed a trend of overall decline with stage rising, so the electronic noses can be used for dynamic monitoring of the whole remediation process; ③ Combined with the GIS, the electronic noses can preliminary assess space pollution situation caused by the remediation of contaminated soil and groundwater and the influence on the residence in the surrounding region. However, further study on the refined classification of the impact degree is needed.%根据上海某土壤与地下水污染修复现场情况,应用自主研发的电子鼻系统(iSA-M1)分别对未修复及修复过程中的土壤和地下水、修复场地上空及周边空气中的VOCs和恶臭类气体进行检测.结合前期研究所得TPI和OPI公式,求得各点的值,并将其用图表示.结果表明:①修复后TVOC和恶臭的浓度总体呈下降趋势;②在土壤和地下水修复过程中,VOCs和恶臭的挥发受气象要素和作业的影响,其浓度在总体下降的过程中伴随着阶段性上升现象;③结合GIS技术,电子鼻能初步用于评估土壤和地下水修复现场造成的空间污染情况及对周围

  10. ENVIRONMENTAL TECHNOLOGY VERIFICATION REPORT; GROUNDWATER SAMPLING TECHNOLOGIES; W.L. GORE AND ASSOCIATES, INC., GORE-SORBER WATER QUALITY MONITORING

    Science.gov (United States)

    The U.S. Environmental Protection Agency (EPA) has created the Environmental Technology Verification Program (ETV) to facilitate the deployment of innovative or improved environmental technologies through performance verification and dissemination of information. The goal of the...

  11. Nuclear facility decommissioning and site remedial actions: A selected bibliography, Vol. 18. Part 2. Indexes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    This bibliography contains 3638 citations with abstracts of documents relevant to environmental restoration, nuclear facility decontamination and decommissioning (D&D), uranium mill tailings management, and site remedial actions. This report is the eighteenth in a series of bibliographies prepared annually for the U.S. Department of Energy (DOE) Office of Environmental Restoration. Citations to foreign and domestic literature of all types - technical reports, progress reports, journal articles, symposia proceedings, theses, books, patents, legislation, and research project descriptions - have been included in Part 1 of the report. The bibliography contains scientific, technical, financial, and regulatory information that pertains to DOE environmental restoration programs. The citations are separated by topic into 16 sections, including (1) DOE Environmental Restoration Program; (2) DOE D&D Program; (3) Nuclear Facilities Decommissioning; (4) DOE Formerly Utilized Sites Remedial Action Programs; (5) NORM-Contaminated Site Restoration; (6) DOE Uranium Mill Tailings Remedial Action Project; (7) Uranium Mill Tailings Management; (8) DOE Site-Wide Remedial Actions; (9) DOE Onsite Remedial Action Projects; (10) Contaminated Site Remedial Actions; (11) DOE Underground Storage Tank Remediation; (12) DOE Technology Development, Demonstration, and Evaluations; (13) Soil Remediation; (14) Groundwater Remediation; (15) Environmental Measurements, Analysis, and Decision-Making; and (16) Environmental Management Issues. Within the 16 sections, the citations are sorted by geographic location. If a geographic location is not specified, the citations are sorted according to the document title. In Part 2 of the report, indexes are provided for author, author affiliation, selected title phrase, selected title word, publication description, geographic location, and keyword.

  12. CENTRAL PLATEAU REMEDIATION

    Energy Technology Data Exchange (ETDEWEB)

    ROMINE, L.D.

    2006-02-01

    A systematic approach to closure planning is being implemented at the Hanford Site's Central Plateau to help achieve the goal of closure by the year 2035. The overall objective of Central Plateau remediation is to protect human health and the environment from the significant quantity of contaminated material that resulted from decades of plutonium production in support of the nation's defense. This goal will be achieved either by removing contaminants or placing the residual contaminated materials in a secure configuration that minimizes further migration to the groundwater and reduces the potential for inadvertent intrusion into contaminated sites. The approach to Central Plateau cleanup used three key concepts--closure zones, closure elements, and closure process steps--to create an organized picture of actions required to complete remediation. These actions were merged with logic ties, constraints, and required resources to produce an integrated time-phased schedule and cost profile for Central Plateau closure. Programmatic risks associated with implementation of Central Plateau closure were identified and analyzed. Actions to mitigate the most significant risks are underway while high priority remediation projects continue to make progress.

  13. Complexity of Groundwater Contaminants at DOE Sites

    Energy Technology Data Exchange (ETDEWEB)

    Hazen, T.C.; Faybishenko, B.; Jordan, P.

    2010-12-03

    The U.S. Department of Energy (DOE) is responsible for the remediation and long-term stewardship of one of the world's largest groundwater contamination portfolios, with a significant number of plumes containing various contaminants, and considerable total mass and activity. As of 1999, the DOE's Office of Environmental Management was responsible for remediation, waste management, or nuclear materials and facility stabilization at 144 sites in 31 states and one U.S. territory, out of which 109 sites were expected to require long-term stewardship. Currently, 19 DOE sites are on the National Priority List. The total number of contaminated plumes on DOE lands is estimated to be 10,000. However, a significant number of DOE sites have not yet been fully characterized. The most prevalent contaminated media are groundwater and soil, although contaminated sediment, sludge, and surface water also are present. Groundwater, soil, and sediment contamination are present at 72% of all DOE sites. A proper characterization of the contaminant inventory at DOE sites is critical for accomplishing one of the primary DOE missions -- planning basic research to understand the complex physical, chemical, and biological properties of contaminated sites. Note that the definitions of the terms 'site' and 'facility' may differ from one publication to another. In this report, the terms 'site,' 'facility' or 'installation' are used to identify a contiguous land area within the borders of a property, which may contain more than one plume. The term 'plume' is used here to indicate an individual area of contamination, which can be small or large. Even though several publications and databases contain information on groundwater contamination and remediation technologies, no statistical analyses of the contaminant inventory at DOE sites has been prepared since the 1992 report by Riley and Zachara. The DOE Groundwater Data Base

  14. Complexity of Groundwater Contaminants at DOE Sites

    Energy Technology Data Exchange (ETDEWEB)

    Hazen, T.C.; Faybishenko, B.; Jordan, P.

    2010-12-03

    The U.S. Department of Energy (DOE) is responsible for the remediation and long-term stewardship of one of the world's largest groundwater contamination portfolios, with a significant number of plumes containing various contaminants, and considerable total mass and activity. As of 1999, the DOE's Office of Environmental Management was responsible for remediation, waste management, or nuclear materials and facility stabilization at 144 sites in 31 states and one U.S. territory, out of which 109 sites were expected to require long-term stewardship. Currently, 19 DOE sites are on the National Priority List. The total number of contaminated plumes on DOE lands is estimated to be 10,000. However, a significant number of DOE sites have not yet been fully characterized. The most prevalent contaminated media are groundwater and soil, although contaminated sediment, sludge, and surface water also are present. Groundwater, soil, and sediment contamination are present at 72% of all DOE sites. A proper characterization of the contaminant inventory at DOE sites is critical for accomplishing one of the primary DOE missions -- planning basic research to understand the complex physical, chemical, and biological properties of contaminated sites. Note that the definitions of the terms 'site' and 'facility' may differ from one publication to another. In this report, the terms 'site,' 'facility' or 'installation' are used to identify a contiguous land area within the borders of a property, which may contain more than one plume. The term 'plume' is used here to indicate an individual area of contamination, which can be small or large. Even though several publications and databases contain information on groundwater contamination and remediation technologies, no statistical analyses of the contaminant inventory at DOE sites has been prepared since the 1992 report by Riley and Zachara. The DOE Groundwater Data Base

  15. Nanoscale Metallic Iron for Environmental Remediation: Prospects and Limitations

    CERN Document Server

    Noubactep, Chicgoua; Crane, Richard; 10.1007/s11270-011-0951-1

    2012-01-01

    The amendment of the subsurface with nanoscale metallic iron particles (nano-Fe0) has been discussed in the literature as an efficient in situ technology for groundwater remediation. However, the introduction of this technology was controversial and its efficiency has never been univocally established. This unsatisfying situation has motivated this communication whose objective was a comprehensive discussion of the intrinsic reactivity of nano-Fe0 based on the contemporary knowledge on the mechanism of contaminant removal by Fe0 and a mathematical model. It is showed that due to limitations of the mass transfer of nano-Fe0 to contaminants, available concepts cannot explain the success of nano-Fe0 injection for in situ groundwater remediation. It is recommended to test the possibility of introducing nano-Fe0 to initiate the formation of roll-fronts which propagation would induce the reductive transformation of both dissolved and adsorbed contaminants. Within a roll-front, FeII from nano-Fe0 is the reducing age...

  16. Nuclear facility decommissioning and site remedial actions: A selected bibliography, Volume 13: Part 1, Main text

    Energy Technology Data Exchange (ETDEWEB)

    Goins, L.F.; Webb, J.R.; Cravens, C.D.; Mallory, P.K.

    1992-09-01

    This publication contains 1035 abstracted references on environmental restoration, nuclear facility decommissioning, uranium mill tailings management, and site remedial actions. These citations constitute the thirteenth in a series of reports prepared annually for the US Department of Energy (DOE) Environmental Restoration programs. Citations to foreign and domestic literature of all types. There are 13 major sections of the publication, including: (1) DOE Decontamination and Decommissioning Program; (2) Nuclear Facilities Decommissioning; (3) DOE Formerly Utilized Sites Remedial Action Program; (4) DOE Uranium Mill Tailings Remedial Action Project; (5) Uranium Mill Tailings Management; (6) DOE Environmental Restoration Program; (7) DOE Site-Specific Remedial Actions; (8) Contaminated Site Restoration; (9) Remediation of Contaminated Soil and Groundwater; (10) Environmental Data Measurements, Management, and Evaluation; (11) Remedial Action Assessment and Decision-Making; (12) Technology Development and Evaluation; and (13) Environmental and Waste Management Issues. Bibliographic references are arranged in nine subject categories by geographic location and then alphabetically by first author, corporate affiliation, or publication title. Indexes are provided for author, corporate affiliation, title word, publication description, geographic location, subject category, and key word.

  17. Features and Remediation technologies of Pollution in Lead - Zinc Mining Areas of China%我国铅锌矿污染特点及修复技术

    Institute of Scientific and Technical Information of China (English)

    梁桂莲; 钱建平; 张力

    2011-01-01

    我国铅锌矿污染的一般特点是:多元素复合污染;污染元素赋存形式复杂;常叠加化学药剂的污染;重金属污染具有隐蔽性、累积性及不可逆性;部分矿山伴生放射性污染等。针对铅锌矿区的不同污染特点,目前常用的污染修复方法有:电动修复法、合磷物质修复法和植物修复法等。电动修复法适宜于低渗透性污染土壤的修复,具有修复时间短、修复彻底、不会引入环境有害物质等优点。含磷物质是一种廉价有效的重金属污染土壤修复剂,可针对土壤重金属污染的实际状况施以不同类型的含磷化合物以降低有效态重金属的含量。超富集植物修复则具有操作技术简单、成本低%The pollution of the lead- zinc mining areas in China is characterized by combined multi - element pollution, complex existing forms of contaminating elements, generally combined with the chemical agents pollution, the concealment, accumulation and irreversibility of heavy metal pollution, accompanying radioactive contamination in some mines, and so on. The com- mon methods of pollution remediation include electrokinetic re mediation; contaminated soil remediation using phosphorus - containing substances and phytoremediation in lead - zinc miningareas. Electrokinetic remediation is suitable for low permeability polluted soil, and has many advantages such as short repairing time, complete effect, without introduction of harmful substances into the environment. Phosphorus - containing substances are cheap and effective agent for the remediation of heavy metal - contaminated soil. Different types of phosphorus compounds can be reduced the content of available heavy metals in soil according to contaminated situation. The remediation of heavy metal - contaminated soil by hyper accumulator plants, is a promising technology, which has the advantages of simple,low cost, less environmental disturbance and being suitable

  18. Remediation in Situ of Hydrocarbons by Combined Treatment in a Contaminated Alluvial Soil due to an Accidental Spill of LNAPL

    Directory of Open Access Journals (Sweden)

    Ettore Trulli

    2016-10-01

    Full Text Available Soil contamination represents an environmental issue which has become extremely important in the last decades due to the diffusion of industrial activities. Accidents during transport of dangerous materials and fuels may cause severe pollution. The present paper describes the criteria of the actions which were operated to remediate the potential risk and observed negative effects on groundwater and soil originating from an accidental spill of diesel fuel from a tank truck. With the aim to evaluate the quality of the involved environmental matrices in the “emergency” phase, in the following “safety” operation and during the remediation action, a specific survey on hydrocarbons, light and heavy, was carried out in the sand deposits soil. Elaboration of collected data allows us to observe the movement of pollutants in the unsaturated soil. The remediation action was finalized to improve the groundwater and soil quality. The former was treated by a so called “pump and treat” system coupled with air sparging. A train of three different technologies was applied to the unsaturated soil in a sequential process: soil vapour extraction, bioventing and enhanced bioremediation. Results showed that the application of sequential remediation treatments allowed us to obtain a state of quality in unsaturated soil and groundwater as required by Italian law.

  19. The Columbia River Protection Supplemental Technologies Quality Assurance Project Plan

    Energy Technology Data Exchange (ETDEWEB)

    Fix, N. J.

    2008-03-12

    Pacific Northwest National Laboratory researchers are working on the Columbia River Protection Supplemental Technologies Project. This project is a U. S. Department of Energy, Office of Environmental Management-funded initiative designed to develop new methods, strategies, and technologies for characterizing, modeling, remediating, and monitoring soils and groundwater contaminated with metals, radionuclides, and chlorinated organics. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by the Technologies Project staff.

  20. Role of natural attenuation, phytoremediation and hybrid technologies in the remediation of a refinery soil with old/recent petroleum hydrocarbons contamination.

    Science.gov (United States)

    Couto, Maria Nazaré P F S; Pinto, Dorabela; Basto, M Clara P; Vasconcelos, Teresa S D

    2012-09-01

    Within a search for a biological remediation technology to remove petroleum hydrocarbons (PHC) from a contaminated soil from a refinery, the potential of monitored natural attenuation (MNA) was compared with the use of transplants of Cortaderia selloana both in the absence and in the presence of soil amendments. After 31 months of experiments, MNA was effective in removing most of the recent PHC contamination (50% of the initial total contamination) at 5-20 cm depth. The presence of weathered contamination explains the existence of an established community of PHC degraders, as can be inferred by the most probable number technique. C. selloana, in its turn, showed capacity to mobilize the most recalcitrant fraction of PHC to its roots, nevertheless masking its remediation capacity. The use of a hybrid technology (C. selloana together with treatments with a surfactant and a bioaugmentation product) improved the removal of PHC at 15-20 cm depth, the presence of C. selloana facilitating the migration of additives into the deeper layers of soil, which can be considered a secondary but positive role of the plant. In the surface soil layer, which was exposed to both microorganisms and the atmosphere, a further 20% of weathered PHC contamination disappeared (70% total removal) as a result of photo- and chemical degradation. Periodic revolving of the soil, like tillage, to expose all the contaminated soil to the atmosphere will therefore be a reliable option for reducing the contamination of the refinery soil if conditions (space and equipment) permit this operation.

  1. Remediation and its effect represented on long term monitoring data at a chlorinated ethenes contaminated site, Wonju, Korea

    Science.gov (United States)

    Lee, Seong-Sun; Lee, Seung Hyun; Lee, Kang-Kun

    2016-04-01

    A research for the contamination of chlorinated ethenes such as trichloroethylene (TCE) at an industrial complex, Wonju, Korea, was carried out based on 17 rounds of groundwater quality data collection from 2009 to 2015. Remediation technologies such as soil vapor extraction, soil flushing, biostimulation, and pump-and-treat have been applied to eliminate the contaminant sources of trichloroethylene (TCE) and to prevent the migration of TCE plume from remediation target zones to groundwater discharge area like a stream. The remediation efficiency according to the remedial actions was evaluated by tracing a time-series of plume evaluation and temporal mass discharge at three transects (Source, Transect-1, Transect-2) which was assigned along the groundwater flow path. Also, based on long term monitoring data, dissolved TCE concentration and mass of residual TCE in the initial stage of disposal were estimated to evaluate the efficiency of in situ remediation. The results of temporal and spatial monitoring before remedial actions showed that a TCE plume originating from main and local source zones continues to be discharged to a stream. However, from the end of intensive remedial actions from 2012 to 2013, the aqueous concentrations of TCE plume present at and around the main source areas decreased significantly. Especially, during the intensive remediation period, the early average mass discharge (26.58 g/day) at source transect was decreased to average 4.99 g/day. Estimated initial dissolved concentration and residual mass of TCE in the initial stage of disposal decreased rapidly after an intensive remedial action in 2013 and it is expected to be continuously decreased from the end of remedial actions to 2020. This study demonstrates that long term monitoring data are useful in assessing the effectiveness of remedial actions at chlorinated ethenes contaminated site. Acknowledgements This project is supported by the Korea Ministry of Environment under "The GAIA

  2. On-site and in situ remediation technologies applicable to metal-contaminated sites in Antarctica and the Arctic: a review

    Directory of Open Access Journals (Sweden)

    Danielle Camenzuli

    2013-12-01

    Full Text Available Effective management of contaminated land requires a sound understanding of site geology, chemistry and biology. This is particularly the case for Antarctica and the Arctic, which function using different legislative frameworks to those of industrialized, temperate environments and are logistically challenging environments to operate in. This paper reviews seven remediation technologies currently used, or demonstrating potential for on-site or in situ use at metal-contaminated sites in polar environments, namely permeable reactive barriers (PRB, chemical fixation, bioremediation, phytoremediation, electrokinetic separation, land capping, and pump and treat systems. The technologies reviewed are discussed in terms of their advantages, limitations and overall potential for the management of metal-contaminated sites in Antarctica and the Arctic. This review demonstrates that several of the reviewed technologies show potential for on-site or in situ usage in Antarctica and the Arctic. Of the reviewed technologies, chemical fixation and PRB are particularly promising technologies for metal-contaminated sites in polar environments. However, further research and relevant field trials are required before these technologies can be considered proven techniques.

  3. Construction of Peat Biobarrier to Remediate Petroleum Hydrocarbon Contaminated Groundwater%泥炭生物反应墙构建及修复地下水中石油烃

    Institute of Scientific and Technical Information of China (English)

    马会强; 张兰英; 张洪林; 李爽

    2011-01-01

    为有效修复地下水中溶解态石油烃污染物,在研究填充介质配比基础上,分别利用低温石油烃降解菌-泥炭-粗砂和泥炭-粗砂构建了泥炭生物反应墙和泥炭反应墙,考察了反应墙对地下水中BTEX、PAHs的修复效果.结果表明,泥炭与粗砂最适体积比为20:80,此时墙体渗透系数为1.17×10-4m/s,有效空隙率为7.5%;泥炭反应墙对BTEX去除率为32.63%~79.15%,吸附寿命为50~55 d,吸附能力大小为二甲苯>乙苯≈甲苯>苯,出水萘、α-甲基萘、β-甲基萘和菲浓度均低于2.85 μg/L;泥炭生物反应墙对BTEX、PAHs修复效果良好,去除率分别为83.6%~97.83%、97.48%~99.85%,微生物降解作用明显,BTEX降解率为75.66%~90.16%.研究表明,泥炭生物反应墙内污染物去除过程为泥炭吸附和微生物降解,泥炭对石油烃特别是多环芳烃具有很强的吸附能力,生物降解能有效延长泥炭对污染物的吸附寿命.%In order to effectively remediate the dissolved petroleum hydrocarbon contaminants in aquifer,low temperature hydrocarbon degrading bacteria-peat-coarse sand and peat-coarse sand were adopted respectively to construct peat biobarrier and peat barrier. And the ratio of packing media, the removal efficiency of BTEX and PAHs were investigated through barriers in remediation of petroleum hydrocarbon contaminated groundwater. It is found that the hydraulic conductivity and available porosity of mixed media were 1.17× 10-4 m/s, 7.5% respectively when peat and coarse sand at the optimum volume ratio of 20:80.For peat barrier, the removal rates of BTEX were 32. 63%-79.15%, sorption life was 50-55d, sorption capacity of peat barrier to BTEX was xylene > ethylbenzene≈toluene> benzene, effluent concentration of naphthalene, α-methylnaphthalene, β-methylnaphthalene and phenanthrene were all below 2.85μg/L. The removal efficiency for BTEX, PAHs were 83.6%-97.83%, 97.48%-99.85% through remediation by

  4. Plant-based remediation processes

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Dharmendra Kumar (ed.) [Belgian Nuclear Research Centre (SCK.CEN), Mol (Belgium). Radiological Impact and Performance Assessment Division

    2013-11-01

    A valuable source of information for scientists in the field of environmental pollution and remediation. Describes the latest biotechnological methods for the treatment of contaminated soils. Includes case studies and protocols. Phytoremediation is an emerging technology that employs higher plants for the clean-up of contaminated environments. Basic and applied research have unequivocally demonstrated that selected plant species possess the genetic potential to accumulate, degrade, metabolize and immobilize a wide range of contaminants. The main focus of this volume is on the recent advances of technologies using green plants for remediation of various metals and metalloids. Topics include biomonitoring of heavy metal pollution, amendments of higher uptake of toxic metals, transport of heavy metals in plants, and toxicity mechanisms. Further chapters discuss agro-technological methods for minimizing pollution while improving soil quality, transgenic approaches to heavy metal remediation and present protocols for metal remediation via in vitro root cultures.

  5. Co-occurrence of arsenic and fluoride in groundwater of semi-arid regions in Latin America: genesis, mobility and remediation.

    Science.gov (United States)

    Alarcón-Herrera, María Teresa; Bundschuh, Jochen; Nath, Bibhash; Nicolli, Hugo B; Gutierrez, Melida; Reyes-Gomez, Victor M; Nuñez, Daniel; Martín-Dominguez, Ignacio R; Sracek, Ondra

    2013-11-15

    Several million people around the world are currently exposed to excessive amounts of arsenic (As) and fluoride (F) in their drinking water. Although the individual toxic effects of As and F have been analyzed, there are few studies addressing their co-occurrences and water treatment options. Several studies conducted in arid and semi-arid regions of Latin America show that the co-occurrences of As and F in drinking water are linked to the volcaniclastic particles in the loess or alluvium, alkaline pH, and limited recharge. The As and F contamination results from water-rock interactions and may be accelerated by geothermal and mining activities, as well as by aquifer over-exploitation. These types of contamination are particularly pronounced in arid and semi-arid regions, where high As concentrations often show a direct relationship with high F concentrations. Enrichment of F is generally related to fluorite dissolution and it is also associated with high Cl, Br, and V concentrations. The methods of As and F removal, such as chemical precipitation followed by filtration and reverse osmosis, are currently being used at different scales and scenarios in Latin America. Although such technologies are available in Latin America, it is still urgent to develop technologies and methods capable of monitoring and removing both of these contaminants simultaneously from drinking water, with a particular focus towards small-scale rural operations.

  6. Electroosmosis remediation of DNAPLS in low permeability soils

    Energy Technology Data Exchange (ETDEWEB)

    Ho, S V. [Monsanto Company, St. Louis, MO (United States)

    1996-08-01

    Electroosmosis is the movement of water through a soil matrix induced by a direct current (DC) electric field. The technique has been used since the 1930s for dewatering and stabilizing fine-grained soils. More recently, electroosmosis has been considered as an in-situ method for soil remediation in which water is injected into the soil at the anode region to flush the contaminants to the cathode side for further treatment or disposal. The major advantage of electroosmosis is its inherent ability to move water uniformly through clayey, silty soils at 100 to 1000 times faster than attainable by hydraulic means, and with very low energy usage. Drawbacks of electroosmosis as a stand-alone technology include slow speed, reliance on solubilizing the contaminants into the groundwater for removal, potentially an unstable process for long term operation, and necessary additional treatment and disposal of the collected liquid. Possible remediation applications of electroosmosis for DNAPLs would be primarily in the removal of residual DNAPLs in the soil pores by electroosmotic flushing. The future of electroosmosis as a broad remedial method lies in how well it can be coupled with complementary technologies. Examples include combining electroosmosis with vacuum extraction, with surfactant usage to deal with non-aqueous phase liquids (NAPLs) through enhanced solubilization or mobilization, with permeability enhancing methods (hydrofracturing, pneumatic fracturing, etc.) to create recovery zones, and with in-situ degradation zones to eliminate aboveground treatment. 33 refs., 1 fig., 1 tab.

  7. In situ groundwater bioremediation

    Energy Technology Data Exchange (ETDEWEB)

    Hazen, Terry C.

    2009-02-01

    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  8. A field study of advanced municipal wastewater treatment technology for artificial groundwater recharge

    Institute of Scientific and Technical Information of China (English)

    PI Yun-zheng; WANG Jian-long

    2006-01-01

    Field studies were conducted to investigate the advanced treatment of the municipal secondary effluent and a subsequent artificial groundwater recharge at Gaobeidian Wastewater Treatment Plant, Beijing. To improve the secondary effluent quality, the combined process of powdered activated carbon adsorption, flocculation and rapid sand filtration was applied, which could remove about 40% dissolved organic carbon (DOC) and 70% adsorbable organic halogens. The results of liquid size exclusion chromatography indicate that in the adsorption unit the removed organic fiaction was mainly low molecular weight compounds. The fiactions removed by the flocculation unit were polysaccharides and high molecular weight compounds. The retention of water in summer in the open recharge basins resulted in a growth of algae. Consequently, DOC increased in the polysaccharide and high molecular weight humic substances fiaction. The majority of the DOC removal during soil passage took place in the unsaturated area.A limited reduction of DOC was observed in the aquifer zone.

  9. STUDY ON BIODEGRADATION TECHNOLOGY APPLICATION IN BULK IN THE REMEDIATION OF SOILS CONTAMINATED WITH POLYCYCLIC AROMATIC HYDROCARBONS

    Directory of Open Access Journals (Sweden)

    Irina Ramona PECINGINĂ

    2015-05-01

    Full Text Available Biodecontaminare methods are based on biodegradation in the subsurface presence of microorganisms capable of degrading most of carbonaceous organic pollutants and much of inorganic pollutants. Biodegradation in bulk meet that principle biological decontamination several ways. These methods are intended solely for solids, and is often used for on-site remediation of soils contaminated with organic products. Station bioremediation ensure reducing the harmfulness of residues from oil exploitation activities considered hazardous, using a bioremediation process. Bioremediation process will lead to reduction of oil content and thus reducing the hazard of waste.

  10. Salmon Site Remedial Investigation Report, Main Body

    Energy Technology Data Exchange (ETDEWEB)