Hydrogeology and simulation of ground-water flow at Arnold Air Force Base, Coffee and Franklin counties, Tennessee

Science.gov (United States)

Haugh, C.J.; Mahoney, E.N.

1994-01-01

The U.S. Air Force at Arnold Air Force Base (AAFB), in Coffee and Franklin Counties, Tennessee, is investigating ground-water contamination in selected areas of the base. This report documents the results of a comprehensive investigation of the regional hydrogeology of the AAFB area. Three aquifers within the Highland Rim aquifer system, the shallow aquifer, the Manchester aquifer, and the Fort Payne aquifer, have been identified in the study area. Of these, the Manchester aquifer is the primary source of water for domestic use. Drilling and water- quality data indicate that the Chattanooga Shale is an effective confining unit, isolating the Highland Rim aquifer system from the deeper, upper Central Basin aquifer system. A regional ground-water divide, approximately coinciding with the Duck River-Elk River drainage divide, underlies AAFB and runs from southwest to northeast. The general direction of most ground-water flow is to the north- west or to the northwest or to the southeast from the divide towards tributary streams that drain the area. Recharge estimates range from 4 to 11 inches per year. Digital computer modeling was used to simulate and provide a better understanding of the ground-water flow system. The model indicates that most of the ground-water flow occurs in the shallow and Manchester aquifers. The model was most sensitive to increases in hydraulic conductivity and changes in recharge rates. Particle-tracking analysis from selected sites of ground-water contamination indicates a potential for contami- nants to be transported beyond the boundary of AAFB.

Evaluation of Pre- and Post- Redevelopment Groundwater Chemical Analyses from LM Monitoring Wells

International Nuclear Information System (INIS)

Kamp, Susan; Dayvault, Jalena

2016-01-01

This report documents the efforts and analyses conducted for the Applied Studies and Technology (AS&T) Ancillary Work Plan (AWP) project titled Evaluation of Pre- and Post- Redevelopment Groundwater Sample Laboratory Analyses from Selected LM Groundwater Monitoring Wells. This effort entailed compiling an inventory of nearly 500 previous well redevelopment events at 16 U.S. Department of Energy Office of Legacy Management (LM) sites, searching the literature for impacts of well redevelopment on groundwater sample quality, and-the focus of this report-evaluating the impacts of well redevelopment on field measurements and sample analytical results. Study Catalyst Monitoring well redevelopment, the surging or high-volume pumping of a well to loosen and remove accumulated sediment and biological build-up from a well, is considered an element of monitoring well maintenance that is implemented periodically during the lifetime of the well to mitigate its gradual deterioration. Well redevelopment has been conducted fairly routinely at a few LM sites in the western United States (e.g., the Grand Junction office site and the Gunnison processing site in Colorado), but at most other sites in this region it is not a routine practice. Also, until recently (2014-2015), there had been no specific criteria for implementing well redevelopment, and documentation of redevelopment events has been inconsistent. A catalyst for this evaluation was the self-identification of these inconsistencies by the Legacy Management Support contractor. As a result, in early 2015 Environmental Monitoring Operations (EMO) staff began collecting and documenting additional field measurements during well redevelopment events. In late 2015, AS&T staff undertook an independent internal evaluation of EMO's well redevelopment records and corresponding pre- and post-well-redevelopment groundwater analytical results. Study Findings Although literature discussions parallel the prevailing industry

Evaluation of Pre- and Post- Redevelopment Groundwater Chemical Analyses from LM Monitoring Wells

Energy Technology Data Exchange (ETDEWEB)

Kamp, Susan [Navarro Reserch and Engineering, Oak Ridge, TN (United States); Dayvault, Jalena [US Department of Energy, Washington, DC (United States). Office of Legacy Management

2016-05-01

This report documents the efforts and analyses conducted for the Applied Studies and Technology (AS&T) Ancillary Work Plan (AWP) project titled Evaluation of Pre- and Post- Redevelopment Groundwater Sample Laboratory Analyses from Selected LM Groundwater Monitoring Wells. This effort entailed compiling an inventory of nearly 500 previous well redevelopment events at 16 U.S. Department of Energy Office of Legacy Management (LM) sites, searching the literature for impacts of well redevelopment on groundwater sample quality, and—the focus of this report—evaluating the impacts of well redevelopment on field measurements and sample analytical results. Study Catalyst Monitoring well redevelopment, the surging or high-volume pumping of a well to loosen and remove accumulated sediment and biological build-up from a well, is considered an element of monitoring well maintenance that is implemented periodically during the lifetime of the well to mitigate its gradual deterioration. Well redevelopment has been conducted fairly routinely at a few LM sites in the western United States (e.g., the Grand Junction office site and the Gunnison processing site in Colorado), but at most other sites in this region it is not a routine practice. Also, until recently (2014–2015), there had been no specific criteria for implementing well redevelopment, and documentation of redevelopment events has been inconsistent. A catalyst for this evaluation was the self-identification of these inconsistencies by the Legacy Management Support contractor. As a result, in early 2015 Environmental Monitoring Operations (EMO) staff began collecting and documenting additional field measurements during well redevelopment events. In late 2015, AS&T staff undertook an independent internal evaluation of EMO's well redevelopment records and corresponding pre- and post-well-redevelopment groundwater analytical results. Study Findings Although literature discussions parallel the prevailing industry

Demonstrating practical application of soil and groundwater clean-up and recovery technologies at natural gas processing facilities: Bioventing, air sparging and wetlands remediation

International Nuclear Information System (INIS)

Moore, B.

1996-01-01

This issue of the project newsletter described the nature of bioventing, air sparging and wetland remediation. It reviewed their effectiveness in remediating hydrocarbon contaminated soil above the groundwater surface. Bioventing was described as an effective, low cost treatment in which air is pumped below ground to stimulate indigenous bacteria. The bacteria then use the oxygen to consume the hydrocarbons, converting them to CO 2 and water. Air sparging involves the injection of air below the groundwater surface. As the air rises, hydrocarbons are stripped from the contaminated soil and water. The advantage of air sparging is that it cleans contaminated soil and water from below the groundwater surface. Hydrocarbon contamination of wetlands was described as fairly common. Conventional remediation methods of excavation, trenching, and bellholes to remove contamination often cause extreme harm to the ecosystem. Recent experimental evidence suggests that wetlands may be capable of attenuating contaminated water through natural processes. Four hydrocarbon contaminated wetlands in Alberta are currently under study. Results to date show that peat's high organic content promotes sorption and biodegradation and that some crude oil spills can been resolved by natural processes. It was suggested that assuming peat is present, a good clean-up approach may be to contain the contaminant source, monitor the lateral and vertical extent of contamination, and wait for natural processes to resolve the problem. 3 figs

Oxidation of graphites for core support post in air at high temperatures

International Nuclear Information System (INIS)

Imai, Hisashi; Fujii, Kimio; Kurosawa, Takeshi

1982-07-01

Oxidation reactions of candidate graphites for core support post with atmospheric air were studied in a temperature range between 550 0 C and 1000 0 C. The reaction rates, temperature dependence of the rates and distribution of bulk density in the oxidized graphites were measured and the characters obtained were compared between the brand of graphites. On the basis of the experimental results, dimension and strength of the post after corrosion with air, which might be introduced in rupture accident of primary coolant tube, were discussed. In the case of IG-11 graphite, it was proved that the strength of post is still sufficient even 100 hours after the beginning of the accident and that, however, it is necessary to insert more deeply the post against graphite blocks. (author)

Air bubble migration is a random event post embryo transfer.

Science.gov (United States)

Confino, E; Zhang, J; Risquez, F

2007-06-01

Air bubble location following embryo transfer (ET) is the presumable placement spot of embryos. The purpose of this study was to document endometrial air bubble position and migration following embryo transfer. Multicenter prospective case study. Eighty-eight embryo transfers were performed under abdominal ultrasound guidance in two countries by two authors. A single or double air bubble was loaded with the embryos using a soft, coaxial, end opened catheters. The embryos were slowly injected 10-20 mm from the fundus. Air bubble position was recorded immediately, 30 minutes later and when the patient stood up. Bubble marker location analysis revealed a random distribution without visible gravity effect when the patients stood up. The bubble markers demonstrated splitting, moving in all directions and dispersion. Air bubbles move and split frequently post ET with the patient in the horizontal position, suggestive of active uterine contractions. Bubble migration analysis supports a rather random movement of the bubbles and possibly the embryos. Standing up changed somewhat bubble configuration and distribution in the uterine cavity. Gravity related bubble motion was uncommon, suggesting that horizontal rest post ET may not be necessary. This report challenges the common belief that a very accurate ultrasound guided embryo placement is mandatory. The very random bubble movement observed in this two-center study suggests that a large "window" of embryo placement maybe present.

Effect of sample digestion, air filter contamination, and post-adsorption on the analysis of trace elements in air particulate matter

International Nuclear Information System (INIS)

Yang, Xiao Jin; Wan, Pingyu; Foley, Roy

2012-01-01

Inductively coupled plasma atomic emission spectrometry and inductively coupled plasma MS are the major analytical tools for trace elements in environmental matrices, however, the underestimate of certain trace elements in analysis of air particulate matter by these two techniques has long been observed. This has been attributed to incomplete sample digestion. Here, we demonstrate that the combined effects of sample digestion, air filter impurities, and post-adsorption of the analytes contribute to the interference of the analysis. Particular attention should be paid to post-adsorption of analytes onto air filters after acid digestion. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Effect of sample digestion, air filter contamination, and post-adsorption on the analysis of trace elements in air particulate matter

Energy Technology Data Exchange (ETDEWEB)

Yang, Xiao Jin [Department of Environment and Climate Change, Environmental Forensic and Analytical Science Section, New South Wales (Australia); Department of Applied Chemistry, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing (China); Wan, Pingyu [Department of Applied Chemistry, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing (China); Foley, Roy [Department of Environment and Climate Change, Environmental Forensic and Analytical Science Section, New South Wales (Australia)

2012-11-15

Inductively coupled plasma atomic emission spectrometry and inductively coupled plasma MS are the major analytical tools for trace elements in environmental matrices, however, the underestimate of certain trace elements in analysis of air particulate matter by these two techniques has long been observed. This has been attributed to incomplete sample digestion. Here, we demonstrate that the combined effects of sample digestion, air filter impurities, and post-adsorption of the analytes contribute to the interference of the analysis. Particular attention should be paid to post-adsorption of analytes onto air filters after acid digestion. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Risk for intracranial pressure increase related to enclosed air in post-craniotomy patients during air ambulance transport: a retrospective cohort study with simulation.

Science.gov (United States)

Brändström, Helge; Sundelin, Anna; Hoseason, Daniela; Sundström, Nina; Birgander, Richard; Johansson, Göran; Winsö, Ola; Koskinen, Lars-Owe; Haney, Michael

2017-05-12

Post-craniotomy intracranial air can be present in patients scheduled for air ambulance transport to their home hospital. We aimed to assess risk for in-flight intracranial pressure (ICP) increases related to observed intracranial air volumes, hypothetical sea level pre-transport ICP, and different potential flight levels and cabin pressures. A cohort of consecutive subdural hematoma evacuation patients from one University Medical Centre was assessed with post-operative intracranial air volume measurements by computed tomography. Intracranial pressure changes related to estimated intracranial air volume effects of changing atmospheric pressure (simulating flight and cabin pressure changes up to 8000 ft) were simulated using an established model for intracranial pressure and volume relations. Approximately one third of the cohort had post-operative intracranial air. Of these, approximately one third had intracranial air volumes less than 11 ml. The simulation estimated that the expected changes in intracranial pressure during 'flight' would not result in intracranial hypertension. For intracranial air volumes above 11 ml, the simulation suggested that it was possible that intracranial hypertension could develop 'inflight' related to cabin pressure drop. Depending on the pre-flight intracranial pressure and air volume, this could occur quite early during the assent phase in the flight profile. DISCUSSION: These findings support the idea that there should be radiographic verification of the presence or absence of intracranial air after craniotomy for patients planned for long distance air transport. Very small amounts of air are clinically inconsequential. Otherwise, air transport with maintained ground-level cabin pressure should be a priority for these patients.

Mercury isotope fractionation during transfer from post-desulfurized seawater to air.

Science.gov (United States)

Huang, Shuyuan; Lin, Kunning; Yuan, Dongxing; Gao, Yaqin; Sun, Lumin

2016-12-15

Samples of dissolved gaseous mercury (DGM) in the post-desulfurized seawater discharged from a coal-fired power plant together with samples of gaseous elemental mercury (GEM) over the post-desulfurized seawater surface were collected and analyzed to study the mercury isotope fractionation during transfer from post-desulfurized seawater to air. Experimental results showed that when DGM in the seawater was converted to GEM in the air, the δ 202 Hg and Δ 199 Hg values were changed, ranging from -2.98 to -0.04‰ and from -0.31 to 0.64‰, respectively. Aeration played a key role in accelerating the transformation of DGM to GEM, and resulted in light mercury isotopes being more likely to be enriched in the GEM. The ratio Δ 199 Hg/Δ 201 Hg was 1.626 in all samples, suggesting that mercury mass independent fractionation occurred owing to the nuclear volume effect during the transformation. In addition, mass independent fractionation of mercury even isotopes was found in the GEM above the post-desulfurized seawater surface in the aeration pool. Copyright © 2016 Elsevier Ltd. All rights reserved.

Correlation between geology and radon levels in groundwater, soil and indoor air in Bhilangana Valley, Garhwal Himalaya, India

International Nuclear Information System (INIS)

Choubey, V.M.; Ramola, R.C.

1997-01-01

Radon concentrations were measured in soil, air and groundwater in Bhilangana Valley, Garhwal Himalaya, India by using an LR-115 plastic track detector and radon emanometer. Radon concentrations were found to vary from 1 KBq/m 3 to 57 KBq/m 3 in soil, 5 Bq/l to 887 Bq/l in water and 95 Bq/m 3 to 208 Bq/m 3 in air. The recorded values are quite high due to associated uranium mineralization in the area. Radon concentration was also found to depend on the tectonic structure and geology of the area. (orig.)

Final Record of Decision for the South Post Impact Area and Area of Contamination 41 Groundwater and Areas of Contamination 25, 26, and 27

National Research Council Canada - National Science Library

1996-01-01

.... This Record of Decision (ROD) addresses AOCs 25 (the Explosives Ordnance Disposal (EOD) Range), 26 (Zulu Ranges), and 27 (Hotel Range) and a subset of the groundwater within the South Post Impact Area...

Comparative study of urban development and groundwater condition in coastal areas of Buenos Aires, Argentina

Science.gov (United States)

Rodrigues Capítulo, Leandro; Carretero, Silvina C.; Kruse, Eduardo E.

2017-08-01

The geomorphological evolution of a sand-dune barrier in Buenos Aires, Argentina, is analyzed as a factor regulating the fresh groundwater reserves available. The impact of geomorphological evolution and the consequences for the social and economic development of two coastal areas are assessed. This is one of the most important tourist destinations in the country; for study purposes, it was divided into a northern sector and a southern sector. In the southern sector, the exploitable groundwater is associated with the Holocene and upper Pleistocene geomorphological evolution, which generated three interrelated aquifer units, constituting a system whose useful thickness reaches at least 45 m. In contrast, the northern sector is restricted to two Holocene aquifer units, whose total thickness is on the order of 12 m. The morphological characteristics and the occurrence of the largest fresh groundwater reserves in the southern sector are indicators of better conditions for economic growth, which is mainly reflected on the expansion of real estate ventures. The relationships of transmissivity vs area of real estate ventures (Arev), and total water consumption vs Arev, are indicators for the sustainable management of the water resources. The approach chosen may be used by decision makers in other regions to assess the feasibility of future tourism projects on the basis of the availability of water resources associated with geomorphological features.

The nitrate contents in the groundwater in the south end of Buenos Aires conurbation

International Nuclear Information System (INIS)

Carol, E.

2004-01-01

The study area is in the south end of Buenos Aires outskirts. The population is of 42000 inhabitants, from which 69% is supplied of water by means of domiciliary wells. The water for human consumption is located in Pampeano and Puelches aquifers, which form a series of semi-free aquifers of the multi-layer type that are hydraulically connected. The aim of this work was to analyze the nitrate content in the groundwater (Pampeano and Puelches aquifers) and to evaluate the pollution type. The percentage of wells that overcome the range 40-50 mg/l of nitrates was 34% for Pampeano aquifer and 36% for Puelches aquifer. Results obtained for the Pampeano aquifer suggest that the pollution would be produced by a pseudo diffuse process associated to septic wells. Meanwhile, in the Puelches aquifer, the same process of pseudo diffuse pollution would be produced but in this case its origin would be caused by the water migration with nitrates from the Pampeano aquifer. Results mentioned in this work make evident the deterioration process of groundwater, where the pollution would be related to the anthropic activity, coming principally from the urban zone [es

Hydrogeochemical analysis and evaluation of groundwater in the reclaimed small basin of Abu Mina, Egypt

Science.gov (United States)

Salem, Zenhom E.; Atwia, Mohamed G.; El-Horiny, Mohamed M.

2015-12-01

Agricultural reclamation activities during the last few decades in the Western Nile Delta have led to great changes in the groundwater levels and quality. In Egypt, changing the desert land into agricultural land has been done using transferred Nile water (through irrigation canal systems) or/and groundwater. This research investigates the hydrogeochemical changes accompanying the reclamation processes in the small basin of Abu Mina, which is part of the Western Nile Delta region. In summer 2008, 23 groundwater samples were collected and groundwater levels were measured in 40 observation wells. Comparing the groundwater data of the pre-reclamation (1974) and the post-reclamation (2008) periods, groundwater seems to have been subjected to many changes: rise in water level, modification of the flow system, improvement of water quality, and addition of new salts through dissolution processes. Generally, Abu Mina basin is subdivided into two areas, recharge and discharge. The dissolution and mixing were recognized in the recharge areas, while the groundwater of the discharge region carries the signature of the diluted pre-reclamation groundwater. The salts of soil and aquifer deposits play an important role in the salt content of the post and pre-reclamation groundwater. NaCl was the predominant water type in the pre-reclamation groundwater, while CaSO4, NaCl and MgSO4 are the common chemical facies in the post-reclamation groundwater. The post-reclamation groundwater mostly indicates mixing between the pre-reclamation groundwater and the infiltrated freshwater with addition of some ions due to interaction with soil and sediments.

Air quality in developing world disaster and conflict zones--the case of post-earthquake Haiti.

Science.gov (United States)

Davis, Mary E; Rappaport, Ann

2014-10-15

Data on air quality are remarkably limited in the poorest of the world's countries. This is especially true for post-conflict and disaster zones, where international relief efforts focus largely on more salient public health challenges such as water and sanitation, infectious diseases, and housing. Using post-earthquake Haiti as the example case, this commentary explores air quality challenges in the developing world, highlighting concerns related to infrastructure damage from post-conflict and disaster settings. We contend that there is a growing and presently unmet need for further research and attention from the global health community to address these issues. Copyright © 2014 Elsevier B.V. All rights reserved.

Shallow bedrock limits groundwater seepage-based headwater climate refugia

Science.gov (United States)

Briggs, Martin A.; Lane, John W.; Snyder, Craig D.; White, Eric A.; Johnson, Zachary; Nelms, David L.; Hitt, Nathaniel P.

2018-01-01

Groundwater/surface-water exchanges in streams are inexorably linked to adjacent aquifer dynamics. As surface-water temperatures continue to increase with climate warming, refugia created by groundwater connectivity is expected to enable cold water fish species to survive. The shallow alluvial aquifers that source groundwater seepage to headwater streams, however, may also be sensitive to seasonal and long-term air temperature dynamics. Depth to bedrock can directly influence shallow aquifer flow and thermal sensitivity, but is typically ill-defined along the stream corridor in steep mountain catchments. We employ rapid, cost-effective passive seismic measurements to evaluate the variable thickness of the shallow colluvial and alluvial aquifer sediments along a headwater stream supporting cold water-dependent brook trout (Salvelinus fontinalis) in Shenandoah National Park, VA, USA. Using a mean depth to bedrock of 2.6 m, numerical models predicted strong sensitivity of shallow aquifer temperature to the downward propagation of surface heat. The annual temperature dynamics (annual signal amplitude attenuation and phase shift) of potential seepage sourced from the shallow modeled aquifer were compared to several years of paired observed stream and air temperature records. Annual stream water temperature patterns were found to lag local air temperature by ∼8–19 d along the stream corridor, indicating that thermal exchange between the stream and shallow groundwater is spatially variable. Locations with greater annual signal phase lag were also associated with locally increased amplitude attenuation, further suggestion of year-round buffering of channel water temperature by groundwater seepage. Numerical models of shallow groundwater temperature that incorporate regional expected climate warming trends indicate that the summer cooling capacity of this groundwater seepage will be reduced over time, and lower-elevation stream sections may no longer serve as larger

A Discrete-Event Simulation Model for Evaluating Air Force Reusable Military Launch Vehicle Post-Landing Operations

National Research Council Canada - National Science Library

Martindale, Michael

2006-01-01

The purpose of this research was to develop a discrete-event computer simulation model of the post-landing vehicle recoveoperations to allow the Air Force Research Laboratory, Air Vehicles Directorate...

1997 Comprehensive TNX Area Annual Groundwater and Effectiveness Monitoring Report

International Nuclear Information System (INIS)

Chase, J.

1998-04-01

Shallow groundwater beneath the TNX Area at the Savannah River Site (SRS) has been contaminated with chlorinated volatile organic compounds (CVOCs) such as trichloroethylene (TCE) and carbon tetrachloride. In November 1994, an Interim Record of Decision (IROD) was agreed to and signed by the U. S. Department of Energy (DOE), the Environmental Protection Agency (EPA), and the South Carolina Department of Health ampersand Environmental Control (SCDHEC). The Interim Record of Decision requires the installation of a hybrid groundwater corrective action (HGCA) to stabilize the plume of groundwater contamination and remove CVOCs dissolved in the groundwater. The hybrid groundwater corrective action included a recovery well network, purge water management facility, air stripper, and an airlift recirculation well. The recirculation well was dropped pursuant to a test that indicated it to be ineffective at the TNX Area. Consequently, the groundwater corrective action was changed from a hybrid to a single action, pump-and-treat approach. The Interim Action (IA) T-1 air stripper system began operation on September 16, 1996. a comprehensive groundwater monitoring program was initiated to measure the effectiveness of the system. As of December 31, 1997, the system has treated 32 million gallons of contaminated groundwater removed 32 pounds of TCE. The recovery well network created a 'capture zone' that stabilized the plume of contaminated groundwater

1997 Comprehensive TNX Area Annual Groundwater and Effectiveness Monitoring Report

Energy Technology Data Exchange (ETDEWEB)

Chase, J.

1998-04-01

Shallow groundwater beneath the TNX Area at the Savannah River Site (SRS) has been contaminated with chlorinated volatile organic compounds (CVOCs) such as trichloroethylene (TCE) and carbon tetrachloride. In November 1994, an Interim Record of Decision (IROD) was agreed to and signed by the U. S. Department of Energy (DOE), the Environmental Protection Agency (EPA), and the South Carolina Department of Health {ampersand} Environmental Control (SCDHEC). The Interim Record of Decision requires the installation of a hybrid groundwater corrective action (HGCA) to stabilize the plume of groundwater contamination and remove CVOCs dissolved in the groundwater. The hybrid groundwater corrective action included a recovery well network, purge water management facility, air stripper, and an airlift recirculation well. The recirculation well was dropped pursuant to a test that indicated it to be ineffective at the TNX Area. Consequently, the groundwater corrective action was changed from a hybrid to a single action, pump-and-treat approach. The Interim Action (IA) T-1 air stripper system began operation on September 16, 1996. a comprehensive groundwater monitoring program was initiated to measure the effectiveness of the system. As of December 31, 1997, the system has treated 32 million gallons of contaminated groundwater removed 32 pounds of TCE. The recovery well network created a `capture zone` that stabilized the plume of contaminated groundwater.

Curriculum Evolution at Air Command and Staff College in the Post-Cold War Era

Science.gov (United States)

Donovan, William Robert, II.

2010-01-01

This qualitative study used a historical research method to eliminate the gap in the historical knowledge of Air Command and Staff College (ACSC) curriculum evolution in the post-Cold War era. This study is the only known analysis of the forces that influenced the ACSC curriculum and the rationale behind curricular change at ACSC in the post-Cold…

Geochemical Assessment of Groundwater in the Peri-urban Environment of Buenos Aires, Argentina

Science.gov (United States)

Gallardo, A.

2014-12-01

Groundwater pollution is a major concern in peri-urban environments. Thus, water quality is being investigated at several domestic wells in Brandsen, 70 km south of Buenos Aires, Argentina. To present, about 20 water sources were sampled in orchards and small farms of the area. There is limited data about the wells construction, although collected information suggests that groundwater is derived from the superficial sandy loams of the Pampean Aquifer. Samples were analysed for major inorganic elements using ion chromatography and ICP-MS. Titration was used to estimate alkalinity. Physical characteristics (EC, pH, temperature) were measured on site. Results show that groundwater pH ranges from 6.5 to 7.8, with a specific conductance of 180 to 255 mS/m. A peak of 360 mS/m in one horticultural parcel is associated to local NO3- concentrations up to 140 mg/L. This value exceeds the maximum recommendations set by the WHO (50 mg/L). Considering that fertilizer inputs in that property are negligible, the high levels of NO3- might be attributed to effluents from a neighbour septic tank. An increase in NO3- (>150mg/L) was also detected in two conventional farms. This increase correlates to elevated SO42- concentrations (>300 mg/L) suggesting thus, fertilizers percolation into the saturated zone. The leaching of these fluids might be exacerbated by irrigation during new planting, and accumulations of fertilizer-solids in the root zones from previous seasons. Chloride concentrations average ~90 mg/L and would not pose a threat to health at the moment. Its main origin would be related to connate waters in the loam matrix, although some anthropogenic inputs might occur in the previously described farms. In general, the rest of the analysed elements fall within acceptable levels for drinking purposes as well. Nevertheless, further work is still necessary to better define the fate of the potential harmful elements and assess seasonal variations in water quality.

Well Construction Details, Groundwater Elevations, and Figures for the Tijeras Arroyo Groundwater Area at Sandia National Laboratories, New Mexico

Energy Technology Data Exchange (ETDEWEB)

Copland, John R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2017-01-01

This Sandia National Laboratories / New Mexico (SNL/NM) submittal contains groundwater information that the United States Geological Survey (USGS) has requested. The USGS will use the information to assist Kirtland Air Force Base (KAFB) in its ongoing groundwater studies. The information in this submittal contains well-construction details and groundwater-elevation data for monitoring wells that SNL/NM has installed. Relevant well-construction data from other government agencies are also summarized. This submittal contains four data tables and three figures. Information in the tables has been used by SNL/NM to prepare groundwater compliance reports that have previously incorporated the three figures. The figures depict the potentiometric surface for the Perched Groundwater System, the potentiometric surface for the Regional Aquifer, and a Conceptual Site Model for the vicinity of Tijeras Arroyo in the northern portion of KAFB.

Paleoclimatic information from deuterium and oxygen-18 in C-14 dated North Saharian groundwaters; groundwater formation in the past

International Nuclear Information System (INIS)

Sonntag, C.; Muennich, K.O.; Junghans, C.

1978-01-01

A statistical presentation of C-14 groundwater ages for various regions of the Northern Sahara reflects the alternating sequence of humid and arid periods in the late Pleistocene and Holocene. Groundwaters older than 20000 y B.P. are found all over the Sahara. Isoline-presentation of the Continental Effect in deuterium and oxygen-18 of Saharian groundwater is similar to the one in modern European groundwater. This similarity proves the Western Drift influence when in the past winter rains were sufficient for groundwater formation in the Sahara (great pluvial). The postpluvial humid phases of the Sahara during the Holocene were probably of decreasing importance from west to east. The lower deuterium excess d = delta D - 8 x delta 18 O observed in old Saharian groundwaters is interpreted to be due to a lower moisture deficit of the air over the ocean during the last ice-age. Extremely high D- and O-18 contents of modern groundwater in the Sahel zone south of the Sahara are probably due to summer rain originating from tropical rain forest evapotranspiration. (orig.) [de

Ground-water data, 1969-77, Vandenberg Air Force Base area, Santa Barbara County, California

Science.gov (United States)

Lamb, Charles E.

1980-01-01

The water supply for Vandenberg Air Force Base is obtained from wells in the Lompoc Plain, San Antonio Valley, and Lompoc Terrace groundwater basins. Metered pumpage during the period 1969-77 from the Lompoc Plain decreased from a high of 3,670 acre-feet in 1969 to a low of 2,441 acre-feet in 1977, while pumpage from the San Antonio Valley increased from a low of 1 ,020 acre-feet in 1969 to a high of 1,829 acre-feet in 1977. Pumpage from the Lompoc Terrace has remained relatively constant and was 187 acre-feet in 1977. In the Barka Slough area of the San Antonio Valley, water levels in four shallow wells declined during 1976 and 1977. Water levels in observation wells in the two aquifers of the Lompoc Terrace ground-water basin fluctuated during the period, but show no long term trends. Chemical analyses or field determinations of temperature and specific conductance were made of 219 water samples collected from 53 wells. In the Lompoc Plain the dissolved-solids concentration in all water samples was more than 625 milligrams per liter, and in most was more than 1,000 milligrams per liter. The manganese concentration in analyzed samples equaled or exceeded the recommended limit of 50 micrograms per liter for public water supplies. Dissolved-solids concentrations increased with time in water samples from two wells east of the Air Force Base in San Antonio Valley. In the base well-field area, concentrations of dissolved solids ranged from 290 to 566 milligrams per liter. Eight analyses show manganese at or above the recommended limit of 50 milligrams per liter. In the Lompoc Terrace area dissolved-solids concentrations ranged from 470 to 824 milligrams per liter. Five new supply wells, nine observation wells, and two exploratory/observation wells were drilled on the base during the period 1972-77. (USGS)

Formation of the U.S. Air Force Aviator Post Traumatic Stress Disorder Study Group

Science.gov (United States)

2016-11-15

Wood, III, John Heaton, Mark Hubner, Nicole Rhodes 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION... Questionnaire -9 PIQ performance intelligence quotient PTSD post-traumatic stress disorder RPA remotely piloted aircraft USAF U.S. Air Force VIQ verbal intelligence quotient ...Human Performance Wing U.S. Air Force School of Aerospace Medicine Aerospace Medicine Department 2510 Fifth St., Bldg. 840 Wright-Patterson AFB, OH

Groundwater controls on post-fire permafrost thaw: Water and energy balance effects

OpenAIRE

Rocha, Adrian; Mckenzie, Jeffrey; Lamontagne-Halle, Pierrick; Zipper, Samuel

2018-01-01

Fire frequency and severity is increasing in high latitude regions, with large impacts on the water and energy balances. However, the degree to which groundwater flow impacts the permafrost response to fire remains poorly understood and understudied. Here, we use the Anaktuvuk River Fire (Alaska, USA) as an archetypal example to investigate groundwater-permafrost interactions following fire. We identify key thermal and hydrologic parameters controlling permafrost and active layer response to ...

1998 Comprehensive TNX Area Annual Groundwater and Effectiveness Monitoring Report

Energy Technology Data Exchange (ETDEWEB)

Chase, J.

1999-06-02

Shallow groundwater beneath the TNX Area at the Savannah River Site has been contaminated with chlorinated volatile organic compounds such as trichloroethylene and carbon tetrachloride. The Interim Action T-1 Air Stripper System began operation on September 16, 1996. A comprehensive groundwater monitoring program was initiated to measure the effectiveness of the system. The Interim Action is meeting its objectives and is capable of continuing to do so until the final groundwater remedial action is in place.

Geochemical Investigations of Groundwater Stability

International Nuclear Information System (INIS)

Bath, Adrian

2006-05-01

palaeohydrogeological conditions. It is likely that inland areas have had longer durations of post-glacial fresh water infiltration than coastal areas, possibly causing greater degrees of dilution and dispersion of preexisting groundwaters and thus overprinting their hydrochemical and isotopic 'fingerprints'. Lower post-glacial hydraulic gradients relative to inland sites may account for the occurrence of more relict cold-climate water at coastal sites. Some general observations are based on rather thin evidence and therefore speculative. Firstly, it seems that glacial melt water penetrated many hundreds of metres and in some places to at least 1,000 m depth. However the low remaining proportions of melt water and of much older saline Shield water suggest that melt water flux did not fully displace pre-existing groundwaters at these depths. Secondly, where there has been post-glacial infiltration of palaeo-Baltic sea water, the density stratification or compartmentalisation effect coupled with low hydraulic gradient has reduced rates of subsequent fresh water circulation after shoreline recession. There are many uncertainties in interpreting these geochemical indicators in terms of the penetration depths of glacial melt waters and the degree to which they replace preexisting groundwaters, of other aspects of groundwater stability, and of comparisons between inland and coastal groundwater systems. Uncertainties derive partly from the reliability of groundwater samples as being representative of in situ conditions, and partly from the non-uniqueness of interpretative models. Future investigations using these approaches need to improve sampling, to make conjunctive use of geochemical and isotopic indicators which have varying timescales and sensitivities, and to integrate these indicators with palaeohydrogeological modelling to support the development of reliable groundwater flow and solute transport models for Performance Assessment

Geo - hydrological investigations and impact of water harvesting structures on groundwater potential in Anantapur District, Andhra Pradesh, India.

Science.gov (United States)

Suryanarayana, K V; Krishnaiah, S; Khokalay, Murthy Rao V

2010-10-01

In this paper, the data pertaining to the rainfall, its departure from normal, moving mean rainfall, depth of water levels in pre-monsoon and post-monsoon seasons, groundwater availability, groundwater utilization and impact of storage of water in large water bodies are analyzed graphically. The results indicate that the groundwater is over exploited in many places in Anantapur District (India). The groundwater levels found fluctuating, when compared the observations in pre-monsoon and post-monsoon seasons. Hence, it is concluded that the construction of water harvesting structures at suitable locations will have a definite impact on the groundwater potential in Anantapur District.

Mining Environmental Data from a Coupled Modelling System to Examine the Impact of Agricultural Management Practices on Groundwater and Air Quality

Science.gov (United States)

Garcia, V.; Cooter, E. J.; Hayes, B.; Murphy, M. S.; Bash, J. O.

2014-12-01

Excess nitrogen (N) resulting from current agricultural management practices can leach into sources of drinking water as nitrate, increasing human health risks of 'blue baby syndrome', hypertension, and some cancers and birth defects. Nitrogen also enters the atmosphere from land surfaces forming air pollution increasing human health risks of pulmonary and cardio-vascular disease. Characterizing and attributing nitrogen from agricultural management practices is difficult due to the complex and inter-related chemical and biological reactions associated with the nitrogen cascade. Coupled physical process-based models, however, present new opportunities to investigate relationships among environmental variables on new scales; particularly because they link emission sources with meteorology and the pollutant concentration ultimately found in the environment. In this study, we applied a coupled meteorology (NOAA-WRF), agricultural (USDA-EPIC) and air quality modelling system (EPA-CMAQ) to examine the impact of nitrogen inputs from corn production on ecosystem and human health and wellbeing. The coupled system accounts for the nitrogen flux between the land surface and air, and the soil surface and groundwater, providing a unique opportunity to examine the effect of management practices such as type and timing of fertilization, tilling and irrigation on both groundwater and air quality across the conterminous US. In conducting the study, we first determined expected relationships based on literature searches and then identified model variables as direct or surrogate variables. We performed extensive and methodical multi-variate regression modelling and variable selection to examine associations between agricultural management practices and environmental condition. We then applied the regression model to predict and contrast pollution levels between two corn production scenarios (Figure 1). Finally, we applied published health functions (e.g., spina bifida and cardio

Groundwater contaminant plume ranking

International Nuclear Information System (INIS)

1988-08-01

Containment plumes at Uranium Mill Tailings Remedial Action (UMTRA) Project sites were ranked to assist in Subpart B (i.e., restoration requirements of 40 CFR Part 192) compliance strategies for each site, to prioritize aquifer restoration, and to budget future requests and allocations. The rankings roughly estimate hazards to the environment and human health, and thus assist in determining for which sites cleanup, if appropriate, will provide the greatest benefits for funds available. The rankings are based on the scores that were obtained using the US Department of Energy's (DOE) Modified Hazard Ranking System (MHRS). The MHRS and HRS consider and score three hazard modes for a site: migration, fire and explosion, and direct contact. The migration hazard mode score reflects the potential for harm to humans or the environment from migration of a hazardous substance off a site by groundwater, surface water, and air; it is a composite of separate scores for each of these routes. For ranking the containment plumes at UMTRA Project sites, it was assumed that each site had been remediated in compliance with the EPA standards and that relict contaminant plumes were present. Therefore, only the groundwater route was scored, and the surface water and air routes were not considered. Section 2.0 of this document describes the assumptions and procedures used to score the groundwater route, and Section 3.0 provides the resulting scores for each site. 40 tabs

Application of hydrogeology and groundwater-age estimates to assess the travel time of groundwater at the site of a landfill to the Mahomet Aquifer, near Clinton, Illinois

Science.gov (United States)

Kay, Robert T.; Buszka, Paul M.

2016-03-02

sampled by this study. That result indicated that nearly all groundwater sampled from well G53S entered the aquifer as recharge before 1953. Tritium was detected in a trace concentration in one sample from a second monitoring well open to the upper part of the Radnor Till Member (well G07S; 0.11 ± 0.09 tritium units), and not detected in samples collected from two monitoring wells open to a sand deposit in the lower part of the Radnor Till Member, from two samples collected from two monitoring wells open to the Organic Soil unit, and in two samples collected from a production well screened in the middle of the Mahomet aquifer (a groundwater sample and a sequential replicate sample). The lack of tritium in five of the six groundwater samples collected from the shallow permeable units beneath CLU#3 site and the two samples from the one Mahomet aquifer well indicates an absence of post-1952 recharge. Groundwater-flow paths that could contribute post-1952 recharge to the lower part of the Radnor Till Member, the Organic Soil unit, or the Mahomet aquifer at the CLU#3 are not indicated by these data.Hypothetical two-part mixtures of tritium-dead, pre-1953 recharge water and decay-corrected tritium concentrations in post-1952 recharge were computed and compared with tritium analyses in groundwater sampled from monitoring wells at the CLU#3 site to evaluate whether tritium concentrations in groundwater could be represented by mixtures involving some post-1952 recharge. Results from the hypothetical two-part mixtures indicate that groundwater from monitoring well (G53S) was predominantly composed of pre-1953 recharge and that if present, younger, post-1955 recharge, contributed less than 2.5 percent to that sample. The hypothetical two-part mixing results also indicated that very small amounts of post-1952 recharge composing less than about 2.5 percent of the sample volume could not be distinguished in groundwater samples with tritium concentrations less than about 0.15 TU

Preliminary analysis for model development of groundwater evolution in Horonobe area

International Nuclear Information System (INIS)

Yoshida, Yasushi; Yui, Mikazu

2003-03-01

The preliminary analysis for model development of groundwater evolution in Horonobe area was performed with data at D-1, HDB-1 and HDB-2 bore hole where hydrogen / oxygen isotope concentration, mineral property in sedimentary rock and physico-chemical parameters (pH, Eh and ionic concentrations) were measured. As a result of analysis for hydrogen and oxygen isotope concentration, saline water in marine sediment was diluted by the mixing with shallow groundwater and diffusion. And as a result of analysis for a concentration of bicarbonate from the difference of pH values measured between in-situ and under air, the estimated in-situ concentration of bicarbonate differs from that measured under air. And minerals which were assumed to be equilibrium with groundwater were selected by thermodynamic calculation. This report presents the results of preliminary analysis for groundwater evolution by using data derived from D-1, HDB-1 and HDB-2 boring research. In order to establish the model which interprets the groundwater evolution as a next step, data which satisfy the representative in-situ property of groundwater chemistry in Horonobe area are needed. Reliable measurements for physico-chemical parameter and property of minerals in sedimentary rock in dominant layer and at the variety of depth are also needed. (author)

76 FR 77856 - International Mail Price Change for Inbound Air Parcel Post

Science.gov (United States)

2011-12-14

... Commission is noticing a recently-filed Postal Service request to change rates for Inbound Air Parcel Post at....\\2\\ Notice at 2. \\1\\ Notice of the United States Postal Service of Filing Changes in Rates Not of..., 2011 (Notice). \\2\\ See Docket Nos. MC2010-11 and CP2010-11, Request of the United States Postal Service...

Nordic air quality co-benefits from European post-2012 climate policies

International Nuclear Information System (INIS)

Rypdal, Kristin; Rive, Nathan; Astroem, Stefan; Karvosenoja, Niko; Aunan, Kristin; Bak, Jesper L.; Kupiainen, Kaarle; Kukkonen, Jaakko

2007-01-01

Although climate policies target primarily CO 2 , they may indirectly have an impact on air pollutants and thus on air quality. Here we look specifically at the co-benefits of various European post-2012 climate policy scenarios related to air quality in the Nordic region. We analyse how caps on emissions, expansion of the European Union (EU) Emissions Trading System, carbon taxes, and Russian and non-EU Eastern Europe participation after 2012 will influence emissions, air quality, avoided abatement costs, welfare effects, the regional environment and human exposure to particulate matter in the Nordic countries. We find that stricter targets will contribute to reduced emissions of air pollutants, and benefits to ecosystems and human health, which would have required substantial abatement costs if achieved by application of 'end-of-pipe' measures. Due to the assumed use of the flexibility mechanisms, reductions in emissions in the Nordic countries are smaller than in other regions, but the Nordic countries benefit from reductions in emissions in nearby regions. The more sectors that are included in the emissions trading scheme, the greater the emission of air pollutants. If Eastern Europe and Russia were to abandon participation in a climate agreement, the EU and Norway would have to undertake more emission cuts at home in order to meet the same targets. This would benefit ecosystems in southern Scandinavia, but acidification would increase in the north because of increased emissions in Russia

Air quality monitoring of the post-operative recovery room and locations surrounding operating theaters in a medical center in Taiwan.

Directory of Open Access Journals (Sweden)

Chin-Sheng Tang

Full Text Available To prevent surgical site infection (SSI, the airborne microbial concentration in operating theaters must be reduced. The air quality in operating theaters and nearby areas is also important to healthcare workers. Therefore, this study assessed air quality in the post-operative recovery room, locations surrounding the operating theater area, and operating theaters in a medical center. Temperature, relative humidity (RH, and carbon dioxide (CO2, suspended particulate matter (PM, and bacterial concentrations were monitored weekly over one year. Measurement results reveal clear differences in air quality in different operating theater areas. The post-operative recovery room had significantly higher CO2 and bacterial concentrations than other locations. Bacillus spp., Micrococcus spp., and Staphylococcus spp. bacteria often existed in the operating theater area. Furthermore, Acinetobacter spp. was the main pathogen in the post-operative recovery room (18% and traumatic surgery room (8%. The mixed effect models reveal a strong correlation between number of people in a space and high CO2 concentration after adjusting for sampling locations. In conclusion, air quality in the post-operative recovery room and operating theaters warrants attention, and merits long-term surveillance to protect both surgical patients and healthcare workers.

Air quality monitoring of the post-operative recovery room and locations surrounding operating theaters in a medical center in Taiwan.

Science.gov (United States)

Tang, Chin-Sheng; Wan, Gwo-Hwa

2013-01-01

To prevent surgical site infection (SSI), the airborne microbial concentration in operating theaters must be reduced. The air quality in operating theaters and nearby areas is also important to healthcare workers. Therefore, this study assessed air quality in the post-operative recovery room, locations surrounding the operating theater area, and operating theaters in a medical center. Temperature, relative humidity (RH), and carbon dioxide (CO2), suspended particulate matter (PM), and bacterial concentrations were monitored weekly over one year. Measurement results reveal clear differences in air quality in different operating theater areas. The post-operative recovery room had significantly higher CO2 and bacterial concentrations than other locations. Bacillus spp., Micrococcus spp., and Staphylococcus spp. bacteria often existed in the operating theater area. Furthermore, Acinetobacter spp. was the main pathogen in the post-operative recovery room (18%) and traumatic surgery room (8%). The mixed effect models reveal a strong correlation between number of people in a space and high CO2 concentration after adjusting for sampling locations. In conclusion, air quality in the post-operative recovery room and operating theaters warrants attention, and merits long-term surveillance to protect both surgical patients and healthcare workers.

Heavy metal concentration in groundwater from Besant Nagar to Sathankuppam, South Chennai, Tamil Nadu, India

Science.gov (United States)

Sridhar, S. G. D.; Sakthivel, A. M.; Sangunathan, U.; Balasubramanian, M.; Jenefer, S.; Mohamed Rafik, M.; Kanagaraj, G.

2017-12-01

The assessment of groundwater quality is an obligatory pre-requisite to developing countries like India with rural-based economy. Heavy metal concentration in groundwater from Besant Nagar to Sathankuppam, South Chennai was analyzed to assess the acquisition process. The study area has rapid urbanization since few decades, which deteriorated the condition of the aquifer of the area. Totally 30 groundwater samples were collected during pre-monsoon (June 2014) and post-monsoon (January 2015) from the same aquifer to assess the heavy metal concentration in groundwater. Groundwater samples were analyzed for heavy metals such as Fe, Pb, Zn, Cu, Ni, Cr, Co and Mn using atomic absorption spectrophotometry (AAS). Correlation matrix revealed that there is no significant correlation between heavy metals and other parameters during pre-monsoon except EC with Cr but Fe and Zn have good positive correlation during post-monsoon.

Geochemical Investigations of Groundwater Stability

Energy Technology Data Exchange (ETDEWEB)

Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

2006-05-15

local palaeohydrogeological conditions. It is likely that inland areas have had longer durations of post-glacial fresh water infiltration than coastal areas, possibly causing greater degrees of dilution and dispersion of preexisting groundwaters and thus overprinting their hydrochemical and isotopic 'fingerprints'. Lower post-glacial hydraulic gradients relative to inland sites may account for the occurrence of more relict cold-climate water at coastal sites. Some general observations are based on rather thin evidence and therefore speculative. Firstly, it seems that glacial melt water penetrated many hundreds of metres and in some places to at least 1,000 m depth. However the low remaining proportions of melt water and of much older saline Shield water suggest that melt water flux did not fully displace pre-existing groundwaters at these depths. Secondly, where there has been post-glacial infiltration of palaeo-Baltic sea water, the density stratification or compartmentalisation effect coupled with low hydraulic gradient has reduced rates of subsequent fresh water circulation after shoreline recession. There are many uncertainties in interpreting these geochemical indicators in terms of the penetration depths of glacial melt waters and the degree to which they replace preexisting groundwaters, of other aspects of groundwater stability, and of comparisons between inland and coastal groundwater systems. Uncertainties derive partly from the reliability of groundwater samples as being representative of in situ conditions, and partly from the non-uniqueness of interpretative models. Future investigations using these approaches need to improve sampling, to make conjunctive use of geochemical and isotopic indicators which have varying timescales and sensitivities, and to integrate these indicators with palaeohydrogeological modelling to support the development of reliable groundwater flow and solute transport models for Performance Assessment.

Evaluation of groundwater quality and suitability for irrigation and drinking purposes in southwest Punjab, India using hydrochemical approach

Science.gov (United States)

Sharma, Diana Anoubam; Rishi, Madhuri S.; Keesari, Tirumalesh

2017-10-01

Groundwater samples from alluvial aquifers of Bathinda district, southwest Punjab were measured for physicochemical parameters as well as major ion chemistry to evaluate the groundwater suitability for drinking and irrigation purposes and to present the current hydrochemical status of groundwater of this district. Temporal variations were analyzed by comparing the pre- and post-monsoon groundwater chemistry. Most of the samples showed contamination: F- (72 %), Mg2+ (22 %), SO4 2- (28 %), TH (25 %), NO3 - (22 %), HCO3 - (22 %) and TDS (11 %) during pre-monsoon and F- (50 %), Mg2+ (39 %), SO4 2- (22 %), TH (28 %), NO3 - (22 %) and TDS (28 %) during post-monsoon above permissible limits for drinking, while rest of the parameters fall within the limits. Irrigation suitability was checked using sodium absorption ratio (SAR), residual sodium carbonate (RSC), percent sodium (Na%) and permeability index (PI). Most of the samples fall under good to suitable category during pre-monsoon period, but fall under doubtful to unsuitable category during post-monsoon period. Presence of high salt content in groundwater during post-monsoon season reflects leaching of salts present in the unsaturated zone by infiltrating precipitation. Hydrochemical data was interpreted using Piper's trilinear plot and Chadha's plot to understand the various geochemical processes affecting the groundwater quality. The results indicate that the order of cation dominance is Na+ > Mg2+ > Ca2+, while anion dominance is in the order Cl- > HCO3 - > SO4 2-. The geochemistry of groundwater of this district is mainly controlled by the carbonate and silicate mineral dissolution and ion exchange during pre-monsoon and leaching from the salts deposited in vadose zone during post-monsoon. The main sources of contamination are soluble fertilizers and livestock wastes. This study is significant as the surface water resources are limited and the quality and quantity of groundwater are deteriorating with time due to

GEJALA INTRUSI AIR LAUT DI DAERAH PESISIR PADELEGAN, PADEMAWU DAN SEKITARNYA

Directory of Open Access Journals (Sweden)

Wisnu Arya Gemilang

2016-11-01

Full Text Available Sebagian wilayah pesisir Pademawu dan sekitarnya, Pamekasan, dijumpai adanya air tanah payau hingga asin dengan pelamparan yang cukup luas. Tujuan penelitian ini adalah untuk memetakan sebaran air tanah asin hingga payau tersebut, baik pada akuifer dangkal maupun akuifer dalam dan juga untuk mengetahui penyebab keasinan air tanah tersebut. Sebaran air tanah asin dipetakan berdasarkan nilai daya hantar listrik (DHL dengan kriteria tingkat keasinan sebagaimana ditetapkan oleh Panitia Ad Hoc Intrusi Air Asin Jakarta. Sedangkan penyebab keasinan air tanah dianalisa berdasarkan fasies hidrokimia dengan diagram Trilinier Piper. Hasil penelitian menunjukkan bahwa pada akuifer dangkal air tanah agak payau hingga asin dengan nilai DHL > 15.000 µS/cm – 50.000 µS/cm dijumpai pada bagian Selatan Pademawu sepanjang pesisir pantai meliputi Padelegan, Jumiang, Tanjung, Manjungan dan Pademawu Timur. Sedangkan untuk air tanah dalam seluruhnya dalam kondisi tawar dengan nilai DHL < 1500 µS/cm, berada pada bagian Utara dari daerah penelitian meliputi kecamatan Tlanakan, Galis, Pamekasan dan  Larangan. Berdasarkan nilai DHL bahwa daerah bagian Utara penelitian tidak terdeteksi adanya proses penyusupan air laut pada air tanah.INDICATION OF SEA WATER INTRUSION IN COASTAL PADELEGAN, PADEMAWU AREAIn the part of Pademawu coastal areas, Pamekasan, was found brackish groundwater that spreading progressively. The purpose of this study was to map the distribution of salt to brackish groundwater, both in the shallow aquifer and the deep aquifer and also to find out the cause of the salinity of the ground water. Salt groundwater distribution was mapped based on the electrical conductivity (EC with a salinity level criteria as established by Panitia Ad Hoc Intrusi Air Asin Jakarta. While the causes of groundwater salinity were analyzed based on hydrochemical facies with Trilinier Piper diagram. The results showed that the shallow groundwater aquifers slightly brackish to

Remediation of Chlorinated Solvent Plumes Using In-Situ Air Sparging—A 2-D Laboratory Study

Directory of Open Access Journals (Sweden)

Jeffrey A. Adams

2011-06-01

Full Text Available In-situ air sparging has evolved as an innovative technique for soil and groundwater remediation impacted with volatile organic compounds (VOCs, including chlorinated solvents. These may exist as non-aqueous phase liquid (NAPL or dissolved in groundwater. This study assessed: (1 how air injection rate affects the mass removal of dissolved phase contamination, (2 the effect of induced groundwater flow on mass removal and air distribution during air injection, and (3 the effect of initial contaminant concentration on mass removal. Dissolved-phase chlorinated solvents can be effectively removed through the use of air sparging; however, rapid initial rates of contaminant removal are followed by a protracted period of lower removal rates, or a tailing effect. As the air flow rate increases, the rate of contaminant removal also increases, especially during the initial stages of air injection. Increased air injection rates will increase the density of air channel formation, resulting in a larger interfacial mass transfer area through which the dissolved contaminant can partition into the vapor phase. In cases of groundwater flow, increased rates of air injection lessened observed downward contaminant migration effect. The air channel network and increased air saturation reduced relative hydraulic conductivity, resulting in reduced groundwater flow and subsequent downgradient contaminant migration. Finally, when a higher initial TCE concentration was present, a slightly higher mass removal rate was observed due to higher volatilization-induced concentration gradients and subsequent diffusive flux. Once concentrations are reduced, a similar tailing effect occurs.

Performance of air sparging systems -- A review of case studies

International Nuclear Information System (INIS)

Bass, D.H.; Brown, R.A.

1995-01-01

In situ air sparging is a commonly used remediation technology which volatilizes and enhances aerobic biodegradation of contamination in Groundwater and saturated zone soil. Recently, some questions have been raised regarding the effectiveness of air sparging. To address these questions the results of 21 sparging case studies have been compiled to shed light on how well air sparging achieves permanent reduction in groundwater contaminant concentrations. The case studies included both chlorinated solvents and petroleum hydrocarbon contamination, and covered a wide range of soil conditions and sparge system parameters. In each case study, groundwater concentrations were compared before sparging was initiated, just before sparging was terminated, and in the months following shutdown of the sparging system

Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Dixon, Robert A; Lance, P E; Downs, A; Kier, Brian P [EMCON Northwest Inc., Portland, OR (United States)

1994-12-31

Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Dixon, Robert A.; Lance, P.E.; Downs, A.; Kier, Brian P. [EMCON Northwest Inc., Portland, OR (United States)

1993-12-31

Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

Description of work for routine groundwater sampling at the Environmental Restoration Disposal Facility

International Nuclear Information System (INIS)

Ford, B.H.

1996-09-01

This document provides a description of work and field implementation guidance for routine (post-baseline) groundwater monitoring sampling program at the Environmental Restoration Disposal Facility. The purpose of this program is to (1) meet the intent of the applicable or relevant and appropriate requirements; (2) document baseline groundwater conditions; (3) monitor those conditions for change; and (4) allow for modifications to groundwater sampling if required by the leachate management program

Enhancement of corrosion resistance for plasma nitrided AISI 4140 steel by plain air plasma post-oxidizing

Energy Technology Data Exchange (ETDEWEB)

Wu, Jiqiang; Liu, Han; Ye, Xuemei [Jiangsu Key Laboratory of Materials Surface Technology, Changzhou University, Changzhou 213164 (China); Chai, Yating [Materials Research and Education Center, Auburn University, AL 36849 (United States); Hu, Jing, E-mail: jinghoo@126.com [Jiangsu Key Laboratory of Materials Surface Technology, Changzhou University, Changzhou 213164 (China); Materials Research and Education Center, Auburn University, AL 36849 (United States)

2015-05-25

Highlights: • Plain air was primarily used for plasma post-oxidation for AISI 4140 steel. • A thin iron oxide layer composed of Fe{sub 3}O{sub 4} to Fe{sub 2}O{sub 3} was formed on top of the compound layer. • The ratio of Fe{sub 3}O{sub 4} to Fe{sub 2}O{sub 3} was closely related to the post-oxidizing conditions. • Post-oxidizing at 673 K for 60 min brought out highest ratio of Fe{sub 3}O{sub 4} to Fe{sub 2}O{sub 3} and optimum corrosion resistance. - Abstract: Plasma post-oxidizing was conducted immediately after plasma nitriding in the same equipment for AISI 4140 steel, and plain air was used as the oxygen bearing gas. The cross-sectional microstructures of the treated samples were observed by optical metallography and scanning electron microcopy (SEM), and the thickness of compound layer was measured accordingly. The phases were determined by X-ray diffraction (XRD), corrosion resistance was evaluated by electrochemical polarization, and the surface morphology before and after polarization test was also observed by SEM. Meanwhile, standard Gibbs free energy of the oxidation reactions existed in Fe–O system was calculated. The results show that a thin iron oxide layer composed of magnetite (Fe{sub 3}O{sub 4}) and hematite (Fe{sub 2}O{sub 3}) is formed on top of the compound layer during plasma post-oxidizing process, and the ratio of magnetite (Fe{sub 3}O{sub 4}) to hematite (Fe{sub 2}O{sub 3}) is depended on plasma post-oxidizing temperature and time. Highest ratio of Fe{sub 3}O{sub 4} to Fe{sub 2}O{sub 3} is obtained while post-oxidizing at 673 K for 60 min due to lower standard Gibbs free energy and appropriate forming rate for the formation of Fe{sub 3}O{sub 4} at this temperature. The thin oxide layer brings out significant enhancement of corrosion resistance, especially at higher ratios of Fe{sub 3}O{sub 4} to Fe{sub 2}O{sub 3}, due to the dense and adherent characteristic of Fe{sub 3}O{sub 4} oxide. Surface images of the post-oxidizing specimen

Groundwater chemistry of shallow aquifers in the coastal zones of Cochin, India

Digital Repository Service at National Institute of Oceanography (India)

Laluraj, C.M.; Gopinath, G.; DineshKumar, P.K.

Laluraj et al.: Groundwater chemistry of shallow aquifers - 133 - APPLIED ECOLOGY AND ENVIRONMENTAL RESEARCH 3(1): 133-139. http://www.ecology.kee.hu ● ISSN 1589 1623  2005, Penkala Bt., Budapest, Hungary GROUNDWATER CHEMISTRY OF SHALLOW AQUIFERS... post monsoon (November 2003) in the coastal zones of Cochin. Laluraj et al.: Groundwater chemistry of shallow aquifers - 134 - APPLIED ECOLOGY AND ENVIRONMENTAL RESEARCH 3(1): 133-139. http://www.ecology.kee.hu ● ISSN 1589 1623  2005, Penkala...

Determination of radon and uranium in the groundwater of Bangalore city

International Nuclear Information System (INIS)

Somashekar, R.K.; Davis, Deljo; Jeban Singh, M.; Prakash, K.L.; Shivanna, K.

2010-01-01

Groundwater is a precious source of drinking water. Radon and uranium are the naturally occurring radioactive elements in water. The present study attempts to identify the nature of groundwater with respect to the radon and uranium in and around Bangalore city. The radon in groundwater is measured by the integrated instrumental field screening techniques using a radon in air monitor (RAD-7) with attached bubbler. The water after the radon measurement, analysed for the total uranium using ICP- AES. The Radon in water represented in Bq/L and total uranium in μg/L

Groundwater quality assessment of urban Bengaluru using multivariate statistical techniques

Science.gov (United States)

Gulgundi, Mohammad Shahid; Shetty, Amba

2018-03-01

Groundwater quality deterioration due to anthropogenic activities has become a subject of prime concern. The objective of the study was to assess the spatial and temporal variations in groundwater quality and to identify the sources in the western half of the Bengaluru city using multivariate statistical techniques. Water quality index rating was calculated for pre and post monsoon seasons to quantify overall water quality for human consumption. The post-monsoon samples show signs of poor quality in drinking purpose compared to pre-monsoon. Cluster analysis (CA), principal component analysis (PCA) and discriminant analysis (DA) were applied to the groundwater quality data measured on 14 parameters from 67 sites distributed across the city. Hierarchical cluster analysis (CA) grouped the 67 sampling stations into two groups, cluster 1 having high pollution and cluster 2 having lesser pollution. Discriminant analysis (DA) was applied to delineate the most meaningful parameters accounting for temporal and spatial variations in groundwater quality of the study area. Temporal DA identified pH as the most important parameter, which discriminates between water quality in the pre-monsoon and post-monsoon seasons and accounts for 72% seasonal assignation of cases. Spatial DA identified Mg, Cl and NO3 as the three most important parameters discriminating between two clusters and accounting for 89% spatial assignation of cases. Principal component analysis was applied to the dataset obtained from the two clusters, which evolved three factors in each cluster, explaining 85.4 and 84% of the total variance, respectively. Varifactors obtained from principal component analysis showed that groundwater quality variation is mainly explained by dissolution of minerals from rock water interactions in the aquifer, effect of anthropogenic activities and ion exchange processes in water.

Well-construction, water-level, geophysical, and water-quality data for ground-water monitoring wells for Arnold Air Force Base, Tennessee

Science.gov (United States)

Hough, C.J.; Mahoney, E.N.; Robinson, J.A.

1992-01-01

Sixty-five wells were installed at 39 sites in the Arnold Air Force Base area in Coffee and Franklin Counties, Tennessee. The wells were installed to provide information on subsurface lithology, aquifer characteristics, ground-water levels, and ground-water quality. Well depths ranged from 11 to 384 feet. Water-quality samples were collected from 60 wells and analyzed for common inorganic ions, trace metals, and volatile organic compounds. The median dissolved-solids concentrations were 60 milligrams per liter in the shallow aquifer, 48 million gallons per liter in the Manchester aquifer, 1,235 milligrams per liter in the Fort Payne aquifer, and 1,712 milligrams per liter in the upper Central Basin aquifer. Caliper, temperature, natural gamma, electric, neutron porosity, gamma-gamma density, and acoustic velocity borehole-geophysical logs were obtained for the six deep wells completed below the Chattanooga Shale. Petrographic and modal analysis were performed on rock samples from each deep well. These six deep wells provide the first information in the study area on hydraulic head and water quality from below the Chattanooga Shale.

Effect of Pumping on Groundwater Levels: A Case Study

Science.gov (United States)

Sindhu, G.; Vijayachandran, Lekshmi

2018-06-01

Groundwater is a major source for drinking and domestic purposes. Nowadays, extensive pumping has become a major issue of concern since pumping has led to rapid decline in the groundwater table, thus imposing landward gradient, leading to saline water intrusion especially in coastal areas. Groundwater pumping has seen its utmost effect on coastal aquifer systems, where the sea-ward gradient gets disturbed due to anthropogenic influences. Hence, a groundwater flow modelling of an aquifer system is essential for understanding the various hydro-geologic conditions, which can be used to study the responses of the aquifer system with regard to various pumping scenarios. Besides, a model helps to predict the water levels for the future period with respect to changing environment. In this study, a finite element groundwater flow model of a coastal aquifer system at Aakulam, Trivandrum district is developed, calibrated and simulated using the software Finite Element subsurface Flow system (FEFLOW 6.2).This simulated model is then used to predict the groundwater levels for a future 5 year period during pre monsoon and post monsoon season.

Effect of Pumping on Groundwater Levels: A Case Study

Science.gov (United States)

Sindhu, G.; Vijayachandran, Lekshmi

2018-03-01

Groundwater is a major source for drinking and domestic purposes. Nowadays, extensive pumping has become a major issue of concern since pumping has led to rapid decline in the groundwater table, thus imposing landward gradient, leading to saline water intrusion especially in coastal areas. Groundwater pumping has seen its utmost effect on coastal aquifer systems, where the sea-ward gradient gets disturbed due to anthropogenic influences. Hence, a groundwater flow modelling of an aquifer system is essential for understanding the various hydro-geologic conditions, which can be used to study the responses of the aquifer system with regard to various pumping scenarios. Besides, a model helps to predict the water levels for the future period with respect to changing environment. In this study, a finite element groundwater flow model of a coastal aquifer system at Aakulam, Trivandrum district is developed, calibrated and simulated using the software Finite Element subsurface Flow system (FEFLOW 6.2).This simulated model is then used to predict the groundwater levels for a future 5 year period during pre monsoon and post monsoon season.

Full-scale testing and early production results from horizontal air sparging and soil vapor extraction wells remediating jet fuel in soil and groundwater at JFK International Airport, New York

International Nuclear Information System (INIS)

Roth, R.J.; Bianco, P.; Pressly, N.C.

1996-01-01

Jet fuel contaminated soil and groundwater contaminated at the International Arrivals Building (IAB) of the JFK International Airport in Jamaica, New York, are being remediated using soil vapor extraction (SVE) and air sparging (AS). The areal extent of the contaminated soil is estimated to be 70 acres and the volume of contaminated groundwater is estimated to be 2.3 million gallons. The remediation uses approximately 13,000 feet of horizontal SVE (HSVE) wells and 7,000 feet of horizontal AS (HAS) wells. The design of the HSVE and HAS wells was based on a pilot study followed by a full-scale test. In addition to the horizontal wells, 28 vertical AS wells and 15 vertical SVE wells are used. Three areas are being remediated, thus, three separate treatment systems have been installed. The SVE and AS wells are operated continuously while groundwater will be intermittently extracted at each HAS well, treated by liquid phase activated carbon and discharged into stormwater collection sewerage. Vapors extracted by the SVE wells are treated by vapor phase activated carbon and discharged into ambient air. The duration of the remediation is anticipated to be between two and three years before soil and groundwater are remediated to New York State cleanup criteria for the site. Based on the monitoring data for the first two months of operation, approximately 14,600 lbs. of vapor phase VOCs have been extracted. Analyses show that the majority of the VOCs are branched alkanes, branched alkenes, cyclohexane and methylated cyclohexanes

Liquid effluent retention facility final-status groundwater monitoring plan

International Nuclear Information System (INIS)

Sweeney, M.D.; Chou, C.J.; Bjornstad, B.N.

1997-09-01

The following sections describe the groundwater-monitoring program for the Liquid Effluent Retention Facility (LERF). The LERF is regulated under the Resource Conservation and Recovery Act of 1976 (RCRA). The LERF is included in the open-quotes Dangerous Waste Portion of the Resource Conservation and Recovery Act Permit for the Treatment, Storage, and Disposal of Dangerous Waste, Permit WA890008967close quotes, (referred to herein as the Permit) (Ecology 1994) and is subject to final-status requirements for groundwater monitoring (WAC 173-303-645). This document describes a RCRA/WAC groundwater detection-monitoring program for groundwater in the uppermost aquifer system at the LERF. This plan describes the LERF monitoring network, constituent list, sampling schedule, statistical methods, and sampling and analysis protocols that will be employed for the LERF. This plan will be used to meet the groundwater monitoring requirements from the time the LERF becomes part of the Permit and through the post-closure care period, until certification of final closure

Environmental Sciences Division Groundwater Program Office

International Nuclear Information System (INIS)

1993-01-01

This first edition of the Martin Marietta Energy Systems, Inc., (Energy Systems) Groundwater Program Annual Report summarizes the work carried out by the Energy Systems GWPO for fiscal year (FY) 1993. This introductory section describes the GWPO's staffing, organization, and funding sources. The GWPO is responsible for coordination and oversight for all components of the groundwater program at the three Oak Ridge facilities [ORNL, the Oak Ridge Y-12 Plant, and the Oak Ridge K-25 Site], and the PGDP and PORTS, respectively. Several years ago, Energy systems senior management recognized that the manner in which groundwater activities were conducted at the five facilities could result in unnecessary duplication of effort, inadequate technical input to decisions related to groundwater issues, and could create a perception within the regulatory agencies of a confusing and inconsistent approach to groundwater issues at the different facilities. Extensive interactions among management from Environmental Compliance, Environmental Restoration (ER), Environmental Sciences Division, Environmental Safety and Health, and the five facilities ultimately led to development of a net technical umbrella organization for groundwater. On April 25, 1991, the GWPO was authorized to be set up within ORNL thereby establishing a central coordinating office that would develop a consistent technical and administrative direction for the groundwater programs of all facilities and result in compliance with all relevant U.S. Environmental Protection Agency (EPA) regulations such as RCRA and Comprehensive Environmental Restoration, Compensation and Liability Act (CERCLA) as well as U.S. Department of Energy (DOE) regulations and orders. For example, DOE Order 5400.1, issued on November 9, 1988, called for each DOE facility to develop an environmental monitoring program for all media (e.g., air, surface water, and groundwater)

Soil and groundwater VOCs contamination: How can electrical geophysical measurements help assess post-bioremediation state?

Science.gov (United States)

Kessouri, P.; Johnson, T. C.; Day-Lewis, F. D.; Slater, L. D.; Ntarlagiannis, D.; Johnson, C. D.

2016-12-01

The former Brandywine MD (Maryland, USA) Defense Reutilization and Marketing Office (DRMO) was designated a hazardous waste Superfund site in 1999. The site was used as a storage area for waste and excess government equipment generated by several U.S. Navy and U.S. Air Force installations, leading to soil and groundwater contamination by volatile organic compounds (VOCs). Active bioremediation through anaerobic reductive dehalogenation was used to treat the groundwater and the aquifer unconsolidated materials in 2008, with electrical geophysical measurements employed to track amendment injections. Eight years later, we used spectral induced polarization (SIP) and time domain induced polarization (TDIP) on 2D surface lines and borehole electrical arrays to assess the long term impact of active remediation on physicochemical properties of the subsurface. Within the aquifer, the treated zone is more electrically conductive, and the phase shift describing the polarization effects is higher than in the untreated zone. Bulk conductivity and phase shift are also locally elevated close to the treatment injection well, possibly due to biogeochemical transformations associated with prolonged bacterial activity. Observed SIP variations could be explained by the presence of biofilms coating the pore space and/or by-products of the chemical reactions catalyzed by the bacterial activity (e.g. iron sulfide precipitation). To investigate these possibilities, we conducted complementary well logging measurements (magnetic susceptibility [MS], nuclear magnetic resonance [NMR], gamma-ray) using 5 boreholes installed at both treated and untreated locations of the site. We also collected water and soil samples on which we conducted microbiological and chemical analyses, along with geophysical observations (SIP, MS and NMR), in the laboratory. These measurements provide further insights into the physicochemical transformations in the subsurface resulting from the treatment and highlight

A Realistic Human Exposure Assessment of Indoor Radon released from Groundwater

International Nuclear Information System (INIS)

Yu, Dong Han; Han, Moon Hee

2002-01-01

The work presents a realistic human exposure assessment of indoor radon released from groundwater in a house. At first, a two-compartment model is developed to describe the generation and transfer of radon in indoor air from groundwater. The model is used to estimate radon concentrations profile of indoor air in a house using by showering, washing clothes, and flushing toilets. Then, the study performs an uncertainty analysis of model input parameters to quantify the uncertainty in radon concentration profile. In order to estimate a daily internal dose of a specific tissue group in an adult through the inhalation of such indoor radon, a PBPK(Physiologically-Based Pharmaco-Kinetic) model is developed. Combining indoor radon profile and PBPK model is used to a realistic human assessment for such exposure. The results obtained from this study would be used to the evaluation of human risk by inhalation associated with the indoor radon released from groundwater

Sustainable in-well vapor stripping: A design, analytical model, and pilot study for groundwater remediation

Science.gov (United States)

Sutton, Patrick T.; Ginn, Timothy R.

2014-12-01

A sustainable in-well vapor stripping system is designed as a cost-effective alternative for remediation of shallow chlorinated solvent groundwater plumes. A solar-powered air compressor is used to inject air bubbles into a monitoring well to strip volatile organic compounds from a liquid to vapor phase while simultaneously inducing groundwater circulation around the well screen. An analytical model of the remediation process is developed to estimate contaminant mass flow and removal rates. The model was calibrated based on a one-day pilot study conducted in an existing monitoring well at a former dry cleaning site. According to the model, induced groundwater circulation at the study site increased the contaminant mass flow rate into the well by approximately two orders of magnitude relative to ambient conditions. Modeled estimates for 5 h of pulsed air injection per day at the pilot study site indicated that the average effluent concentrations of dissolved tetrachloroethylene and trichloroethylene can be reduced by over 90% relative to the ambient concentrations. The results indicate that the system could be used cost-effectively as either a single- or multi-well point technology to substantially reduce the mass of dissolved chlorinated solvents in groundwater.

Study of Seasonal Variation in Groundwater Quality of Sagar City (India by Principal Component Analysis

Directory of Open Access Journals (Sweden)

Hemant Pathak

2011-01-01

Full Text Available Groundwater is one of the major resources of the drinking water in Sagar city (India.. In this study 15 sampling station were selected for the investigations on 14 chemical parameters. The work was carried out during different months of the pre-monsoon, monsoon and post-monsoon seasons in June 2009 to June 2010. The multivariate statistics such as principal component and cluster analysis were applied to the datasets to investigate seasonal variations in groundwater quality. Principal axis factoring has been used to observe the mode of association of parameters and their interrelationships, for evaluating water quality. Average value of BOD, COD, ammonia and iron was high during entire study period. Elevated values of BOD and ammonia in monsoon, slightly more value of BOD in post-monsoon, BOD, ammonia and iron in pre-monsoon period reflected contribution on temporal effect on groundwater. Results of principal component analysis evinced that all the parameters equally and significantly contribute to groundwater quality variations. Factor 1 and factor 2 analysis revealed the DO value deteriorate due to organic load (BOD/Ammonia in different seasons. Hierarchical cluster analysis grouped 15 stations into four clusters in monsoon, five clusters in post-monsoon and five clusters in pre-monsoon with similar water quality features. Clustered group at monsoon, post-monsoon and pre-monsoon consisted one station exhibiting significant spatial variation in physicochemical composition. The anthropogenic nitrogenous species, as fallout from modernization activities. The study indicated that the groundwater sufficiently well oxygenated and nutrient-rich in study places.

Phosphate interference during in situ treatment for arsenic in groundwater.

Science.gov (United States)

Brunsting, Joseph H; McBean, Edward A

2014-01-01

Contamination of groundwater by arsenic is a problem in many areas of the world, particularly in West Bengal (India) and Bangladesh, where reducing conditions in groundwater are the cause. In situ treatment is a novel approach wherein, by introduction of dissolved oxygen (DO), advantages over other treatment methods can be achieved through simplicity, not using chemicals, and not requiring disposal of arsenic-rich wastes. A lab-scale test of in situ treatment by air sparging, using a solution with approximately 5.3 mg L(-1) ferrous iron and 200 μg L(-1) arsenate, showed removal of arsenate in the range of 59%. A significant obstacle exists, however, due to the interference of phosphate since phosphate competes for adsorption sites on oxidized iron precipitates. A lab-scale test including 0.5 mg L(-1) phosphate showed negligible removal of arsenate. In situ treatment by air sparging demonstrates considerable promise for removal of arsenic from groundwater where iron is present in considerable quantities and phosphates are low.

Impact of storm water on groundwater quality below retention/detention basins.

Science.gov (United States)

Zubair, Arif; Hussain, Asif; Farooq, Mohammed A; Abbasi, Haq Nawaz

2010-03-01

Groundwater from 33 monitoring of peripheral wells of Karachi, Pakistan were evaluated in terms of pre- and post-monsoon seasons to find out the impact of storm water infiltration, as storm water infiltration by retention basin receives urban runoff water from the nearby areas. This may increase the risk of groundwater contamination for heavy metals, where the soil is sandy and water table is shallow. Concentration of dissolved oxygen is significantly low in groundwater beneath detention basin during pre-monsoon season, which effected the concentration of zinc and iron. The models of trace metals shown in basin groundwater reflect the land use served by the basins, while it differed from background concentration as storm water releases high concentration of certain trace metals such as copper and cadmium. Recharge by storm water infiltration decreases the concentration and detection frequency of iron, lead, and zinc in background groundwater; however, the study does not point a considerable risk for groundwater contamination due to storm water infiltration.

Earthquakes trigger the loss of groundwater biodiversity

Science.gov (United States)

Galassi, Diana M. P.; Lombardo, Paola; Fiasca, Barbara; di Cioccio, Alessia; di Lorenzo, Tiziana; Petitta, Marco; di Carlo, Piero

2014-09-01

Earthquakes are among the most destructive natural events. The 6 April 2009, 6.3-Mw earthquake in L'Aquila (Italy) markedly altered the karstic Gran Sasso Aquifer (GSA) hydrogeology and geochemistry. The GSA groundwater invertebrate community is mainly comprised of small-bodied, colourless, blind microcrustaceans. We compared abiotic and biotic data from two pre-earthquake and one post-earthquake complete but non-contiguous hydrological years to investigate the effects of the 2009 earthquake on the dominant copepod component of the obligate groundwater fauna. Our results suggest that the massive earthquake-induced aquifer strain biotriggered a flushing of groundwater fauna, with a dramatic decrease in subterranean species abundance. Population turnover rates appeared to have crashed, no longer replenishing the long-standing communities from aquifer fractures, and the aquifer became almost totally deprived of animal life. Groundwater communities are notorious for their low resilience. Therefore, any major disturbance that negatively impacts survival or reproduction may lead to local extinction of species, most of them being the only survivors of phylogenetic lineages extinct at the Earth surface. Given the ecological key role played by the subterranean fauna as decomposers of organic matter and ``ecosystem engineers'', we urge more detailed, long-term studies on the effect of major disturbances to groundwater ecosystems.

State and market in post-reform Brazilian air transportation

Directory of Open Access Journals (Sweden)

Cristiano Fonseca Monteiro

2009-10-01

Full Text Available The changes that have taken place in Brazilian air transportation following the cycle of “market reforms” have turned this sector into an object of growing interest. This interest, in turn, has led to the emergence of a broad literature on the subject, characterized by the emphasis on an agenda of liberalization and the critique of State activism. The goal of the present article is to promote a confrontation between the different interpretations that have been made, incorporating the contributions of approaches inspired in Economic Sociology and in institutionalist analyses in order to draw attention to the importance that political variables, and the State in particular, have for economic performance. The post-reform context is characterized by an initial moment of greater State activism regarding air transportation, through re-initiation of stricter regulatory mechanisms and the re-opening of channels of dialog between state actors and firms. This is followed by a second moment in which state activism is abandoned, at the same time that the sector demonstrates expressive rates of growth, pushing it beyond its existing capacity and flight support infrastructure. This culminated in the episode known as the “apagão aéreo” (aerial black out Analysis of testimonies of state and private sector actors regarding the “blackout” enables us to identify the flaws in the responsible state apparatus as one of the factors that led to the “blackout”. Our conclusions draw attention to the importance of taking political factors into consideration, and particularly the role of the State, in the development of air transportation in Brazil. Keywords: commercial aviation, politics and economics, regulation, Economic Sociology, Historical Institutionalism.

Groundwater quality deterioration as a result of anthropogenic organic air pollution

International Nuclear Information System (INIS)

Renner, I.; Schleyer, R.; Muehlhausen, D.

1990-01-01

For monitoring the atmospherical depositions of organic materials in soil and in particular groundwater, we measured in rain water, soil seepage water and groundwater from four measuring stations in hessian forest areas the AOX sum parameter (organic halogen compounds which can be adsorbed) and numerous single compounds, above all chlorinated hydrocarbons. Anthropogenic organic pollutants are found in all precipitations. Their concentrations are clearly increased as compared to the open land. Of special importance are the atmospherical reaction products of the primary emissions, for example trichloroacetic acid. In analogy to inorganic pollutants, organic pollutant depositions affect above all poorly protected water-bearing strata with thin topsoil layers with a low capacity for adsorption and buffering. Harmful concentrations may be reached here in some cases. (orig.) [de

Toxic fluoride and arsenic contaminated groundwater in the Lahore and Kasur districts, Punjab, Pakistan and possible contaminant sources

International Nuclear Information System (INIS)

Farooqi, Abida; Masuda, Harue; Firdous, Nousheen

2007-01-01

The present study is the first attempt to put forward possible sources of As, F - and SO 4 2- contaminated groundwater in the Kalalanwala area, Punjab, Pakistan. Five rainwater and 24 groundwater samples from three different depths were analyzed. Shallow groundwater from 24 to 27 m depth contained high F - (2.47-21.1 mg/L), while the groundwater samples from the deeper depth were free from fluoride contamination. All groundwater samples contained high As (32-1900 μg/L), in excess of WHO drinking water standards. The SO 4 2- ranges from 110 to 1550 mg/L. δ 34 S data indicate three sources for SO 4 2- air pollutants (5.5-5.7 per mille ), fertilizers (4.8 per mille ), and household waste (7.0 per mille ). Our important finding is the presence of SO 4 2- , As and F - in rainwater, indicating the contribution of these elements from air pollution. We propose that pollutants originate, in part, from coal combusted at brick factories and were mobilized promotionally by the alkaline nature of the local groundwater. - Simultaneous As and F - contamination of groundwater and possible pollutant sources are discussed

Radon as a natural geochemical tracer for study of groundwater discharge into lakes

International Nuclear Information System (INIS)

Schmidt, Axel

2008-01-01

In the presented work the suitability of the naturally occurring radioactive noble gas isotope radon-222 for qualitative and quantitative description of groundwater discharge into lakes was studied. Basis of these investigations was the development of two innovative techniques for the on-site determination of radon in water. In the ex-situ radon measurement procedure, water from the source concerned is taken up in an exchange cell used for this purpose. Inside this cell, the radon dissolved in water is transferred via diffusion into a closed counter-flow of air and subsequently detected by a radon-in-air monitor. Where the in-situ radon determination is concerned, a module composed of a semipermeable membrane is introduced into a water column. Subsequently, the radon dissolved in the water body diffuses through the membrane into the corresponding air flow, by means of which it is transferred into a radon-in-air monitor and is detected. Combination of the developed mobile radon extraction techniques with a suitable and portable radon monitor allow the detection of radon-222 with sufficient accuracy (smaller 20 %) in groundwater as well as in surface waters, i.e., within a broad range of concentrations. Radon-222 was subsequently used to characterize groundwater discharge into a meromictic and a dimictic lake, i.e. two types of lake basically distinct from each other with respect to their water circulation properties were investigated. The use of the noble gas isotope radon-222 as a geochemical tracer makes the application of on-site detection techniques possible and that this in turn permits a rapid, reliable, and cost-effective assessment of groundwater discharge rates into lake water bodies

Radon as a natural geochemical tracer for study of groundwater discharge into lakes

Energy Technology Data Exchange (ETDEWEB)

Schmidt, Axel

2008-06-27

In the presented work the suitability of the naturally occurring radioactive noble gas isotope radon-222 for qualitative and quantitative description of groundwater discharge into lakes was studied. Basis of these investigations was the development of two innovative techniques for the on-site determination of radon in water. In the ex-situ radon measurement procedure, water from the source concerned is taken up in an exchange cell used for this purpose. Inside this cell, the radon dissolved in water is transferred via diffusion into a closed counter-flow of air and subsequently detected by a radon-in-air monitor. Where the in-situ radon determination is concerned, a module composed of a semipermeable membrane is introduced into a water column. Subsequently, the radon dissolved in the water body diffuses through the membrane into the corresponding air flow, by means of which it is transferred into a radon-in-air monitor and is detected. Combination of the developed mobile radon extraction techniques with a suitable and portable radon monitor allow the detection of radon-222 with sufficient accuracy (smaller 20 %) in groundwater as well as in surface waters, i.e., within a broad range of concentrations. Radon-222 was subsequently used to characterize groundwater discharge into a meromictic and a dimictic lake, i.e. two types of lake basically distinct from each other with respect to their water circulation properties were investigated. The use of the noble gas isotope radon-222 as a geochemical tracer makes the application of on-site detection techniques possible and that this in turn permits a rapid, reliable, and cost-effective assessment of groundwater discharge rates into lake water bodies.

Use of Cometabolic Air Sparging to Remediate Chloroethene-Contaminated Groundwater Aquifers

National Research Council Canada - National Science Library

Magar, Victor

2001-01-01

...) process at the McClellan National Test Site, California. The purpose of the demonstration was to evaluate the effectiveness of and costs associated with CAS for removal of chlorinated aromatic hydrocarbons (CAHs) from groundwater...

Groundwater Quality Improvement by Using Aeration and Filtration Methods

OpenAIRE

Nik N. Nik Daud; Nur H. Izehar; B. Yusuf; Thamer A. Mohamed; A. Ahsan

2013-01-01

An experiment was conducted using two aeration methods (water-into-air and air-into-water) and followed by filtration processes using manganese greensand material. The properties of groundwater such as pH, dissolved oxygen, turbidity and heavy metal concentration (iron and manganese) will be assessed. The objectives of this study are i) to determine the effective aeration method and ii) to assess the effectiveness of manganese greensand as filter media in removing iron an...

Brackish groundwater in the United States

Science.gov (United States)

Stanton, Jennifer S.; Anning, David W.; Brown, Craig J.; Moore, Richard B.; McGuire, Virginia L.; Qi, Sharon L.; Harris, Alta C.; Dennehy, Kevin F.; McMahon, Peter B.; Degnan, James R.; Böhlke, John Karl

2017-04-05

in the United States. Previously published digital data relating to brackish groundwater resources were limited to a small number of State- and regional-level studies. Data sources for this assessment ranged from single publications to large datasets and from local studies to national assessments. Geochemical data included concentrations of dissolved solids, major ions, trace elements, nutrients, and radionuclides as well as physical properties of the water (pH, temperature, and specific conductance). Additionally, the database provides selected well information (location, yield, depth, and contributing aquifer) necessary for evaluating the water resource.The assessment was divided into national-, regional-, and aquifer-scale analyses. National-scale analyses included evaluation of the three-dimensional distribution of observed dissolved-solids concentrations in groundwater, the three-dimensional probability of brackish groundwater occurrence, and the geochemical characteristics of saline (greater than or equal to 1,000 mg/L of dissolved solids) groundwater resources. Regional-scale analyses included a summary of the percentage of observed grid cell volume in the region that was occupied by brackish groundwater within the mixture of air, water, and rock for multiple depth intervals. Aquifer-scale analyses focused primarily on four regions that contained the largest amounts of observed brackish groundwater and included a generalized description of hydrogeologic characteristics from previously published work; the distribution of dissolved-solids concentrations; considerations for developing brackish groundwater resources, including a summary of other chemical characteristics that may limit the use of brackish groundwater and the ability of sampled wells producing brackish groundwater to yield useful amounts of water; and the amount of saline groundwater being used in 2010.

Potentiometric surfaces of the Arnold Engineering Development Complex Area, Arnold Air Force Base, Tennessee, May and September 2011

Science.gov (United States)

Haugh, Connor J.; Robinson, John A.

2016-01-29

Arnold Air Force Base occupies about 40,000 acres in Coffee and Franklin Counties, Tennessee. The primary mission of Arnold Air Force Base is to provide risk-reduction information in the development of aerospace products through test and evaluation. This mission is achieved in part through test facilities at Arnold Engineering Development Complex (AEDC), which occupies about 4,000 acres in the center of Arnold Air Force Base. Arnold Air Force Base is underlain by gravel and limestone aquifers, the most productive of which is the Manchester aquifer. Several volatile organic compounds, primarily chlorinated solvents, have been identified in the groundwater at Arnold Air Force Base. In 2011, the U.S. Geological Survey, in cooperation with the U.S. Air Force, Arnold Air Force Base, completed a study of groundwater flow focused on the Arnold Engineering Development Complex area. The Arnold Engineering Development Complex area is of particular concern because within this area (1) chlorinated solvents have been identified in the groundwater, (2) the aquifers are dewatered around below-grade test facilities, and (3) there is a regional groundwater divide.

Evaluation of human health risk from in situ recovery uranium mining, pre-and post-mining, and post-restoration

Energy Technology Data Exchange (ETDEWEB)

Ruedig, E.; Bhattacharyya, A.; Borch, T.; Johnson, T. [Colorado State University (United States); Till, J. [Risk Assessment Corporation (United States)

2014-07-01

In the United States, the restoration of in situ recovery (ISR) uranium mines is aimed at returning sites to pre-mining conditions. While this may seem an appropriate goal, little or no scientific information is available to justify utilizing baseline conditions for regulatory compliance. The chemical and radiological contaminants monitored for restoration compliance have not been evaluated to ensure they are proper indicators of the mitigation of risk. Pre-mining aquifers do not meet minimum United States drinking water standards, and must have an aquifer exemption in place prior to mining. Under these conditions, returning groundwater to near the original concentrations of contaminants may be unnecessary. Post-mining groundwater is also unlikely to meet standards for drinking water, but may be depleted in at least some toxic species as a result of the mining process. Here, we examine the risk to representative person from the personal use of groundwater sourced from an Uranium ISR mine. Water samples were collected from Cameco Resource's Smith Ranch-Highlands ISR Uranium mine near Casper, Wyoming, USA. Samples were acquired pre-mining, post-mining, and post-restoration. Concentrations of heavy metals and radionuclides were assessed by appropriate analytical techniques (e.g., mass spectroscopy or alpha spectroscopy) and these concentrations were used to estimate human health risk for three exposure scenarios: a scenario with high exposure, a scenario with medium exposure, and a scenario with low exposure. A simple biosphere transport model was constructed for each scenario to estimate the risk to humans from the use of contaminated waters for subsistence-related activities. Chemical and radiological risks were harmonized according to the United States Environmental Protection Agency's guidance for superfund sites. Each exposure scenario and its subsequent risk were evaluated individually for pre-mining, post-mining, and post-restoration aquifer waters

Ground-water hydrology and simulation of ground-water flow at Operable Unit 3 and surrounding region, U.S. Naval Air Station, Jacksonville, Florida

Science.gov (United States)

Davis, J.H.

1998-01-01

The Naval Air Station, Jacksonville (herein referred to as the Station), occupies 3,800 acres adjacent to the St. Johns River in Duval County, Florida. Operable Unit 3 (OU3) occupies 134 acres on the eastern side of the Station and has been used for industrial and commercial purposes since World War II. Ground water contaminated by chlorinated organic compounds has been detected in the surficial aquifer at OU3. The U.S. Navy and U.S. Geological Survey (USGS) conducted a cooperative hydrologic study to evaluate the potential for ground water discharge to the neighboring St. Johns River. A ground-water flow model, previously developed for the area, was recalibrated for use in this study. At the Station, the surficial aquifer is exposed at land surface and forms the uppermost permeable unit. The aquifer ranges in thickness from 30 to 100 feet and consists of unconsolidated silty sands interbedded with local beds of clay. The low-permeability clays of the Hawthorn Group form the base of the aquifer. The USGS previously conducted a ground-water investigation at the Station that included the development and calibration of a 1-layer regional ground-water flow model. For this investigation, the regional model was recalibrated using additional data collected after the original calibration. The recalibrated model was then used to establish the boundaries for a smaller subregional model roughly centered on OU3. Within the subregional model, the surficial aquifer is composed of distinct upper and intermediate layers. The upper layer extends from land surface to a depth of approximately 15 feet below sea level; the intermediate layer extends from the upper layer down to the top of the Hawthorn Group. In the northern and central parts of OU3, the upper and intermediate layers are separated by a low-permeability clay layer. Horizontal hydraulic conductivities in the upper layer, determined from aquifer tests, range from 0.19 to 3.8 feet per day. The horizontal hydraulic

Impacts of the 2013 Extreme Flood in Northeast China on Regional Groundwater Depth and Quality

Directory of Open Access Journals (Sweden)

Xihua Wang

2015-08-01

Full Text Available Flooding’s impact on shallow groundwater is not well investigated. In this study, we analyzed changes in the depth and quality of a regional shallow aquifer in the 10.9 × 104 km2 Sanjiang Plain, Northeast China, following a large flood in the summer of 2013. Pre- (2008–2012 and post-flood records on groundwater table depth and groundwater chemistry were gathered from 20 wells across the region. Spatial variability of groundwater recharge after the flood was assessed and the changes in groundwater quality in the post-flood period were determined. The study found a considerable increase in the groundwater table after the 2013 summer flood across the region, with the largest (3.20 m and fastest (0.80 m·s−1 rising height occurring in western Sanjiang Plain. The rising height and velocity gradually declined from the west to the east of the plain. For the entire region, we estimated an average recharge height of 1.24 m for the four flood months (June to September of 2013. Furthermore, we found that the extreme flood reduced nitrate (NO3− and chloride (Cl− concentrations and electrical conductivity (EC in shallow groundwater in the areas that were close to rivers, but increased NO3− and Cl− concentrations and EC in the areas that were under intensive agricultural practices. As the region’s groundwater storage and quality have been declining due to the rapidly increasing rice cultivation, this study shows that floods should be managed as water resources to ease the local water shortage as well as shallow groundwater pollution.

Hydrogeochemical characterization of groundwater of peninsular Indian region using multivariate statistical techniques

Science.gov (United States)

Jacintha, T. German Amali; Rawat, Kishan Singh; Mishra, Anoop; Singh, Sudhir Kumar

2017-10-01

Groundwater quality of Chennai, Tamil Nadu (India) has been assessed during different seasons of year 2012. Three physical (pH, EC, and TDS) and four chemical parameters (Ca2+, Cl-, TH, Mg2+ and SO4 2-) from 18 bore wells were assessed. The results showed that pH of majority of groundwater samples indicates a slightly basic condition (7.99post-monsoon and 8.35pre-monsoon). TH was slightly hard [322.11 mg/lpre-monsoon, 299.37 mg/lpost-monsoon but lies under World Health Organization (WHO) upper limit]. EC, TDS, Ca2+ and Mg2+ concentrations were under WHO permissible limit during post-monsoon (1503.42 μS/cm, 1009.37, 66.58 and 32.42 mg/l respectively) and pre-monsoon (1371.58 μS/cm, 946.84, 71.79 and 34.79 mg/l, respectively). EC shows a good correlation with SO4 2- ( R 2 = 0.59pre-monsoon, 0.77post-monsoon) which indicates that SO4 2- plays a major role in EC of ground water of bore wells. SO4 2- has also showed positive correlations with TDS ( R 2 = 0.84pre-monsoon, 0.95post-monsoon) and TH ( R 2 = 0.70pre-monsoon, 0.75post-monsoon). The principal component analysis (PCA)/factor analysis (FA) was carried out; Factor1 explains 59.154 and 69.278 % of the total variance during pre- and post-monsoon, respectively, with a strong positive loading on Ca2+, Mg2+, SO4 2-, TDS and a negative loading on pH. Factor2 accounts for 13.94 and 14.22 % of the total variance during pre- and post-monsoon, respectively, and was characterized by strong positive loading of only pH and poor/negative loading of EC, Ca2+, Mg2+, SO4 2-, TDS and TH during pre- and post-monsoon. We recommend routine monitoring and thorough treatment before consumption. Further, this study has demonstrated the effectiveness of PCA/FA to assess the hydrogeochemical processes governing the groundwater chemistry in the area.

Characterizing Normal Groundwater Chemistry in Hawaii

Science.gov (United States)

Tachera, D.; Lautze, N. C.; Thomas, D. M.; Whittier, R. B.; Frazer, L. N.

2017-12-01

Hawaii is dependent on groundwater resources, yet how water moves through the subsurface is not well understood in many locations across the state. As marine air moves across the islands water evaporates from the ocean, along with trace amounts of sea-salt ions, and interacts with the anthropogenic and volcanic aerosols (e.g. sulfuric acid, ammonium sulfate, HCl), creating a slightly more acidic rain. When this rain falls, it has a chemical signature distinctive of past processes. As this precipitation infiltrates through soil it may pick up another distinctive chemical signature associated with land use and degree of soil development, and as it flows through the underlying geology, its chemistry is influenced by the host rock. We are currently conducting an investigation of groundwater chemistry in selected aquifer areas of Hawaii, having diverse land use, land cover, and soil development conditions, in an effort to investigate and document what may be considered a "normal" water chemistry for an area. Through this effort, we believe we better assess anomalies due to contamination events, hydrothermal alteration, and other processes; and we can use this information to better understand groundwater flow direction. The project has compiled a large amount of precipitation, soil, and groundwater chemistry data in the three focus areas distributed across in the State of Hawaii. Statistical analyses of these data sets will be performed in an effort to determine what is "normal" and what is anomalous chemistry for a given area. Where possible, results will be used to trace groundwater flow paths. Methods and preliminary results will be presented.

A pilot study for the extraction and treatment of groundwater from a manufactured gas plant site. Final report

International Nuclear Information System (INIS)

1997-12-01

This report describes a pilot study involving treatment of contaminated groundwater at a former manufactured gas plant site on the eastern seaboard of the US. The work was performed in order to provide the design basis for a full-scale groundwater extraction and treatment system at the site, as well as to develop a generic approach to selection of groundwater treatment sequences at other MGP sites. It included three main components: hydrogeologic investigations, bench-scale treatability studies, and pilot-scale treatability studies. Technologies evaluated in bench-scale work included gravity settling, filtration, and dissolved air flotation (DAF) for primary treatment of nonaqueous phase materials; biological degradation, air stripping, and carbon adsorption for secondary treatment of dissolved organics; and carbon adsorption as tertiary treatment of remaining dissolved contaminants. Pilot-scale studies focused on collecting system performance data fore three distinct levels of contamination. Two treatment trains were evaluated. One consisted of DAF, fluidized-bed biotreatment, and filtration plus carbon adsorption; the other used the same steps except to substitute air stripping for fluidized bed treatment. The final effluents produced by both treatment sequences were similar and demonstrated complete treatment of the groundwater. Besides detailing system design and performance for the treatability studies, the report includes an analysis of groundwater treatment applications to MGP sites in general, including a discussion of capital and operating costs

Subsidence due to Excessive Groundwater Withdrawal in the San Joaquin Valley, California

Science.gov (United States)

Corbett, F.; Harter, T.; Sneed, M.

2011-12-01

Francis Corbett1, Thomas Harter1 and Michelle Sneed2 1Department of Land Air and Water Resources, University of California, Davis. 2U.S. Geological Survey Western Remote Sensing and Visualization Center, Sacramento. Abstract: Groundwater development within the Central Valley of California began approximately a century ago. Water was needed to supplement limited surface water supplies for the burgeoning population and agricultural industries, especially within the arid but fertile San Joaquin Valley. Groundwater levels have recovered only partially during wet years from drought-induced lows creating long-term groundwater storage overdraft. Surface water deliveries from Federal and State sources led to a partial alleviation of these pressure head declines from the late 1960s. However, in recent decades, surface water deliveries have declined owing to increasing environmental pressures, whilst water demands have remained steady. Today, a large portion of the San Joaquin Valley population, and especially agriculture, rely upon groundwater. Groundwater levels are again rapidly declining except in wet years. There is significant concern that subsidence due to groundwater withdrawal, first observed at a large scale in the middle 20th century, will resume as groundwater resources continue to be depleted. Previous subsidence has led to problems such as infrastructure damage and flooding. To provide a support tool for groundwater management on a naval air station in the southern San Joaquin Valley (Tulare Lake Basin), a one-dimensional MODFLOW subsidence model covering the period 1925 to 2010 was developed incorporating extensive reconstruction of historical subsidence and water level data from various sources. The stratigraphy used for model input was interpreted from geophysical logs and well completion reports. Gaining good quality data proved problematic, and often values needed to be estimated. In part, this was due to the historical lack of awareness/understanding of

Indicative effects of climate change on groundwater levels in Estonian raised bogs over 50 years

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E. Lode

2017-08-01

Full Text Available Analyses of 50-year (1962–2011 monthly air temperature and precipitation data indicated substantial climate change in the locations of two raised bogs (Linnusaare and Männikjärve in central-east Estonia. During recent years the cross-year winter air temperature increased by 1.7 ºC, while the cold-season precipitation increased by 4 mm. The fluctuation amplitude of temperature and precipitation values decreased. Snow depth proved to be the most sensitive variable to winter warming, followed by groundwater levels together with mean and maximum soil frosts. Long-term groundwater levels on the domes of the bogs and in the forested/treed lagg areas were 0.3−0.4 m and 0.4−0.8 m below the soil surface, respectively. Warming caused changes in groundwater level amplitude of 3−22 cm in the bog domes and 3−14 cm in the forested lagg zones. The lowest groundwater levels in ridge-pool ecotopes at Männikjärve rose by 6−10 cm (i.e. these ecotopes became wetter; but the incidence of low groundwater levels increased in most ecotopes, indicating a more general trend towards drier conditions in the bog.

Dissolution of unirradiated UO2 fuel in synthetic groundwater. Final report (1996-1998)

International Nuclear Information System (INIS)

Ollila, K.

1999-05-01

This study was a part of the EU R and D programme 1994-1998: Nuclear Fission Safety, entitled 'Source term for performance assessment of spent fuel as a waste form'. The research carried out at VTT Chemical Technology was focused on the effects of granitic groundwater composition and redox conditions on UO 2 solubility and dissolution mechanisms. The synthetic groundwater compositions simulated deep granitic fresh and saline groundwaters, and the effects of the near-field material, bentonite, on very saline groundwater. Additionally, the Spanish granite/bentonite water was used. The redox conditions (Eh), which are obviously the most important factors that influence on UO 2 solubility under the disposal conditions of spent fuel, varied from strongly oxidising (air-saturated), anaerobic (N 2 , O 2 2 , low Eh). The objective of the air-saturated dissolution experiments was to yield the maximum solution concentrations of U, and information on the formation of secondary phases that control the concentrations, with different groundwater compositions. The static batch solubility experiments of long duration (up to 1-2 years) were performed using unirradiated UO 2 pellets and powder. Under anaerobic and reducing conditions, the solubilities were also approached from oversaturation. The results of the oxic, air-saturated dissolution experiments with UO 2 powder showed that the increase in the salinity ( -5 M, were at the level of the theoretical solubility of schoepite or another uranyl oxide hydrate, e.g. becquerelite (possibly Na-polyuranate). The higher alkalinity of the fresh (Allard) composition increased the aqueous U concentration. Only some kind of oxidised U-phase (U 3 O 8 -UO 3 ) was identified with XRD when studying possible secondary phases after the contact time of one year with all groundwater compositions. Longer contact times are needed to identify secondary phases predicted by modelling (EQ3/6). In the anoxic dissolution experiments with UO 2 pellets, the

Groundwater resources in Uruguay: Importance and present use

International Nuclear Information System (INIS)

Montano J; Gagliardi, S; Montano, M.

2005-01-01

Traditionally the use of the water resources in Uruguay was based on the exploitation of surface waters due to the great density of the hydrographic network. The intensive use of the groundwater resources began after 1950, mainly for supplying small towns the country, nowadays this practice covers the 70% of the country. Basically, this evolution was a consequence of the lower cost of the groundwater, its availability and good quality. Since 1980 the use of the groundwater has been intensified even more, mainly with the purpose of satisfying different demands like vegetable plantation irrigation either in the open air or in the entrance of cholera to the country during the 1990 decade trough a program for supplying water to small communities in the frontier area. In addition, it is marked out the use of thermal and flowing aquifers belonging to the Guarani Aquifer System as water suppliers for thermal spas and hotels in a reduced area, eventhough having a great hydric potencial whose exploitation yields one of the major foreing currency entrance because of regional tourism. Moreover, it can be stated that Uruguay do not present an important groundwater weath because of regional tourism. Moreover, it can be stated that Uruguay do not present an important groundwater weath because the 65% of its aquifers are fisurated and the others are pourous with diverse potentiality.

GRASP [GRound-Water Adjunct Sensitivity Program]: A computer code to perform post-SWENT [simulator for water, energy, and nuclide transport] adjoint sensitivity analysis of steady-state ground-water flow: Technical report

International Nuclear Information System (INIS)

Wilson, J.L.; RamaRao, B.S.; McNeish, J.A.

1986-11-01

GRASP (GRound-Water Adjunct Senstivity Program) computes measures of the behavior of a ground-water system and the system's performance for waste isolation, and estimates the sensitivities of these measures to system parameters. The computed measures are referred to as ''performance measures'' and include weighted squared deviations of computed and observed pressures or heads, local Darcy velocity components and magnitudes, boundary fluxes, and travel distance and time along travel paths. The sensitivities are computed by the adjoint method and are exact derivatives of the performance measures with respect to the parameters for the modeled system, taken about the assumed parameter values. GRASP presumes steady-state, saturated grondwater flow, and post-processes the results of a multidimensional (1-D, 2-D, 3-D) finite-difference flow code. This document describes the mathematical basis for the model, the algorithms and solution techniques used, and the computer code design. The implementation of GRASP is verified with simple one- and two-dimensional flow problems, for which analytical expressions of performance measures and sensitivities are derived. The linkage between GRASP and multidimensional finite-difference flow codes is described. This document also contains a detailed user's manual. The use of GRASP to evaluate nuclear waste disposal issues has been emphasized throughout the report. The performance measures and their sensitivities can be employed to assist in directing data collection programs, expedite model calibration, and objectively determine the sensitivity of projected system performance to parameters

A co-metabolic approach to groundwater remediation

International Nuclear Information System (INIS)

Palumbo, A.V.; Boerman, P.A.; Herbes, S.E.; White, D.C.; Strandberg, G.W.; Donaldson, T.L.; Lucero, A.J.; Jennings, H.L.; Phelps, T.J.; White, D.C.

1991-01-01

In support of the US Department of Energy's (DOE) Integrated Demonstration (Cleanup of Organics in Soils and Groundwater at Non-arid Sites) at the Savannah River Site (SRS), Oak Ridge National Laboratory (ORNL) and the University of Tennessee (UT) are involved in demonstrations of the use of methanotrophs in bioreactors for remediation of contaminated groundwater. In preparation for a field demonstration at ORNL's K-25 Site in Oak Ridge, Tennessee, ORNL is conducting batch experiments, is operating a number of bench-scale bioreactors, has designed pretreatment systems, and has modified a field-scale bioreactor provided by the Air Force Engineering and Services Center for use at the site. UT is operating benchscale bioreactors with the goal of determining the stability of a trichloroethylene-degrading methanotrophic consortia during shifts in operating conditions (e.g. pH, nutrient inputs, and contaminant mixtures). These activities are all aimed at providing the knowledge base necessary for successful treatment of contaminated groundwater at the SRS and K-25 sites as well as other DOE sites

A co-metabolic approach to groundwater remediation

International Nuclear Information System (INIS)

Palumbo, A.V.; Boerman, P.A.; Strandberg, G.W.; Donaldson, T.L.; Jennings, H.L.; Lucero, A.J.; Herbes, S.E.; Phelps, T.J.; White, D.C.

1991-01-01

In support of the US Department of Energy's (DOE) Integrated Demonstration (Cleanup of Organics in Soils and Groundwater at Non-arid Sites) at the Savannah River Site (SRS), Oak Ridge National Laboratory (ORNL) and the University of Tennessee (UT) are involved in demonstrations of the use of methanotrophs in bioreactors for remediation of contaminated groundwater. In preparation for a field demonstration at ORNL's K-25 Site in Oak Ridge, Tennessee, ORNL is conducting batch experiments, is operating a number of bench-scale bioreactors, has designed pretreatment systems, and has modified a field-scale bioreactor provided by the Air Force Engineering and Services Center for use at the site. UT is operating bench-scale bioreactors with the goal of determining the stability of a trichloroethylene-degrading methanotrophic consortia during shifts in operating conditions (e.g. pH, nutrient inputs, and contaminant mixtures). These activities are all aimed at providing the knowledge base necessary for successful treatment of contaminated groundwater at the SRS and K-25 sites as well as other DOE sites. 18 refs., 1 fig. , 1 tab

Heavy metal contamination and its indexing approach for groundwater of Goa mining region, India

Science.gov (United States)

Singh, Gurdeep; Kamal, Rakesh Kant

2017-06-01

The objective of the study is to reveal the seasonal variations in the groundwater quality with respect to heavy metal contamination. To get the extent of the heavy metals contamination, groundwater samples were collected from 45 different locations in and around Goa mining area during the monsoon and post-monsoon seasons. The concentration of heavy metals, such as lead, copper, manganese, zinc, cadmium, iron, and chromium, were determined using atomic absorption spectrophotometer. Most of the samples were found within limit except for Fe content during the monsoon season at two sampling locations which is above desirable limit, i.e., 300 µg/L as per Indian drinking water standard. The data generated were used to calculate the heavy metal pollution index (HPI) for groundwater. The mean values of HPI were 1.5 in the monsoon season and 2.1 in the post-monsoon season, and these values are well below the critical index limit of 100.

Analysis of krypton-85 and krypton-81 in a few liters of air.

Science.gov (United States)

Tu, Le-Yi; Yang, Guo-Min; Cheng, Cun-Feng; Liu, Gu-Liang; Zhang, Xiang-Yang; Hu, Shui-Ming

2014-04-15

Long-lived radioactive krypton isotopes, (81)Kr (t1/2 = 229,000 year) and (85)Kr (t1/2 = 10.76 year), are ideal tracers. (81)Kr is cosmogenic and can be used for dating groundwater beyond the (14)C age. (85)Kr is a fission product and can be applied in atmospheric studies, nuclear safety inspections, and dating young groundwater. It has long been a challenge to analyze radio-krypton in small samples, in which the total number of such isotopes can be as low as 1 × 10(5). This work presents a system developed to analyze (81)Kr and (85)Kr from a few liters of air samples. A separation system based on cryogenic distillation and gas chromatographic separation is used to extract krypton gas with an efficiency of over 90% from air samples of 1-50 L. (85)Kr/Kr and (81)Kr/Kr ratios in krypton gases are determined from single-atom counting using a laser-based atom trap. In order to test the performance of the system, we have analyzed various samples collected from ambient air and extracted from groundwater, with a minimum size of 1 L. The system can be applied to analyze (81)Kr and (85)Kr in environmental samples including air, groundwater, and ices.

Phase 1 remediation of jet fuel contaminated soil and groundwater at JFK International Airport using dual phase extraction and bioventing

International Nuclear Information System (INIS)

Roth, R.; Bianco, P. Rizzo, M.

1995-01-01

Soil and groundwater contaminated with jet fuel at Terminal One of the JFK International Airport in New York have been remediated using dual phase extraction (DPE) and bioventing. Two areas were remediated using 51 DPE wells and 20 air sparging/air injection wells. The total area remediated by the DPE wells is estimated to be 4.8 acres. Groundwater was extracted to recover nonaqueous phase and aqueous phase jet fuel from the shallow aquifer and treated above ground by the following processes; oil/water separation, iron-oxidation, flocculation, sedimentation, filtration, air stripping and liquid-phase granular activated carbon (LPGAC) adsorption. The extracted vapors were treated by vapor-phase granular activated carbon (VPGAC) adsorption in one area, and catalytic oxidation and VPGAC adsorption in another area. After 6 months of remediation, approximately 5,490 lbs. of volatile organic compounds (VOCs) were removed by soil vapor extraction (SVE), 109,650 lbs. of petroleum hydrocarbons were removed from the extracted groundwater, and 60,550 lbs. of petroleum hydrocarbons were biologically oxidized by subsurface microorganisms. Of these three mechanisms, the rate of petroleum hydrocarbon removal was the highest for biological oxidation in one area and by groundwater extraction in another area

Simulation of ground-water flow and land subsidence in the Antelope Valley ground-water basin, California

Science.gov (United States)

Leighton, David A.; Phillips, Steven P.

2003-01-01

ground-water development have eliminated the natural sources of discharge, and pumping for agricultural and urban uses have become the primary source of discharge from the ground-water system. Infiltration of return flows from agricultural irrigation has become an important source of recharge to the aquifer system. The ground-water flow model of the basin was discretized horizontally into a grid of 43 rows and 60 columns of square cells 1 mile on a side, and vertically into three layers representing the upper, middle, and lower aquifers. Faults that were thought to act as horizontal-flow barriers were simulated in the model. The model was calibrated to simulate steady-state conditions, represented by 1915 water levels and transient-state conditions during 1915-95 using water-level and subsidence data. Initial estimates of the aquifer-system properties and stresses were obtained from a previously published numerical model of the Antelope Valley ground-water basin; estimates also were obtained from recently collected hydrologic data and from results of simulations of ground-water flow and land subsidence models of the Edwards Air Force Base area. Some of these initial estimates were modified during model calibration. Ground-water pumpage for agriculture was estimated on the basis of irrigated crop acreage and crop consumptive-use data. Pumpage for public supply, which is metered, was compiled and entered into a database used for this study. Estimated annual pumpage peaked at 395,000 acre-feet (acre-ft) in 1952 and then declined because of declining agricultural production. Recharge from irrigation-return flows was estimated to be 30 percent of agricultural pumpage; the irrigation-return flows were simulated as recharge to the regional water table 10 years following application at land surface. The annual quantity of natural recharge initially was based on estimates from previous studies. During model calibration, natural recharge was reduced from the initial

PHYSICAL AND CHEMICAL CHARACTERISTICS INTERPRETATION FOR GROUNDWATER QUALITY ASSESSMENT IN THE COASTAL AREA, NORTH KELANTAN, MALAYSIA (Interpretasi Karakterisasi Fisika dan Kimia Untuk Penilaian Kualitas Airtanah di Area Pesisir, Kelantan Utara, Malaysia

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Nur Islami

2015-11-01

Full Text Available ABSTRACT Physical and chemical groundwater interpretation has been done in order to characterize and assess its associated problem in the coastal area, North Kelantan, Malaysia. A total of thirty three groundwater samples that consisted of sixteen groundwater samples were collected directly from existing well and together with seventeen groundwater data obtained from government agency, were used in this study. The depth of groundwater sample was varied from the shallow (3.5 m to the deeper (130 m aquifer. The physical groundwater characteristics were measured directly at the site just after the groundwater collected. The chemical content of the groundwater sample were analysed using Ion Chromatography (IC and Inductively Coupled Plasma (ICP. Finally the data was presented and interpreted using the bivariate and piper diagram to improve interpretation and analysis of the whole data. Analysis result of the groundwater sample indicates that the shallow aquifer can be categorized as fresh water. In the zone with marine soil deposit, chloride and sulphate concentration tend to be higher in the water sample. However, the concentration of water sample is still within the accepted limit for human consumption. In places with relatively higher usage of chemical fertilizer, the groundwater sample exhibits higher nitrate concentration more than limit of safe for human consumption (>45 mg/L. K, Ca, Mg and Na content have a positive correlation with chloride concentration in deeper aquifer, indicating that the ions are derived from the same source of saline waters. The relationship between Cl/HCO3 ratios and chloride also shows that the fresh groundwater and seawater mixing in aquifer, and the samples with lower ratios can be categorized as fresh waters. In the shallow aquifer most ions exhibit a poor correlation to chloride indicating that such ions are derived from a different source. ABSTRAK Interpretasi karakter fisika dan kimia air tanah telah dilakukan

INDOOR AIR CONCENTRATION UNIT CONVERSIONS

Science.gov (United States)

Migration of volatile chemicals from the subsurface into overlying buildings is called vapor intrusion (VI). Volatile organic chemicals in contaminated soils or groundwater can emit vapors, which can migrate through subsurface soils and may enter the indoor air of overlying buil...

Halon-1301, a new Groundwater Age Tracer

Science.gov (United States)

Beyer, Monique; van der Raaij, Rob; Morgenstern, Uwe; Jackson, Bethanna

2015-04-01

Groundwater dating is an important tool to assess groundwater resources in regards to direction and time scale of groundwater flow and recharge and to assess contamination risks and manage remediation. To infer groundwater age information, a combination of different environmental tracers, such as tritium and SF6, are commonly used. However ambiguous age interpretations are often faced, due to a limited set of available tracers and limitations of each tracer method when applied alone. There is a need for additional, complementary groundwater age tracers. We recently discovered that Halon-1301, a water soluble and entirely anthropogenic gaseous substance, may be a promising candidate [Beyer et al, 2014]. Halon-1301 can be determined along with SF6, SF5CF3 and CFC-12 in groundwater using a gas chromatography setup with attached electron capture detector developed by Busenberg and Plummer [2008]. Halon-1301 has not been assessed in groundwater. This study assesses the behaviour of Halon-1301 in water and its suitability as a groundwater age tracer. We determined Halon-1301 in 17 groundwater and various modern (river) waters sites located in 3 different groundwater systems in the Wellington Region, New Zealand. These waters have been previously dated with tritium, CFC-12, CFC-11 and SF6 with mean residence times ranging from 0.5 to over 100 years. The waters range from oxic to anoxic and some show evidence of CFC contamination or degradation. This allows us to assess the different properties affecting the suitability of Halon-1301 as groundwater age tracer, such as its conservativeness in water and local contamination potential. The samples are analysed for Halon-1301 and SF6simultaneously, which allows identification of issues commonly faced when using gaseous tracers such as contamination with modern air during sampling. Overall we found in the assessed groundwater samples Halon-1301 is a feasible new groundwater tracer. No sample indicated significantly elevated

Water-carbon Links in a Tropical Forest: How Interbasin Groundwater Flow Affects Carbon Fluxes and Ecosystem Carbon Budgets

Energy Technology Data Exchange (ETDEWEB)

Genereux, David [North Carolina State Univ., Raleigh, NC (United States); Osburn, Christopher [North Carolina State Univ., Raleigh, NC (United States); Oberbauer, Steven [Florida Intl Univ., Miami, FL (United States); Oviedo Vargas, Diana [North Carolina State Univ., Raleigh, NC (United States); Dierick, Diego [Florida Intl Univ., Miami, FL (United States)

2017-03-27

This report covers the outcomes from a quantitative, interdisciplinary field investigation of how carbon fluxes and budgets in a lowland tropical rainforest are affected by the discharge of old regional groundwater into streams, springs, and wetlands in the forest. The work was carried out in a lowland rainforest of Costa Rica, at La Selva Biological Station. The research shows that discharge of regional groundwater high in dissolved carbon dioxide represents a significant input of carbon to the rainforest "from below", an input that is on average larger than the carbon input "from above" from the atmosphere. A stream receiving discharge of regional groundwater had greatly elevated emissions of carbon dioxide (but not methane) to the overlying air, and elevated downstream export of carbon from its watershed with stream flow. The emission of deep geological carbon dioxide from stream water elevates the carbon dioxide concentrations in air above the streams. Carbon-14 tracing revealed the presence of geological carbon in the leaves and stems of some riparian plants near streams that receive inputs of regional groundwater. Also, discharge of regional groundwater is responsible for input of dissolved organic matter with distinctive chemistry to rainforest streams and wetlands. The discharge of regional groundwater in lowland surface waters has a major impact on the carbon cycle in this and likely other tropical and non-tropical forests.

Recommended Henry’s Law Constants for Non-Groundwater Pathways Models in GoldSim

Energy Technology Data Exchange (ETDEWEB)

Dyer, J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-06-20

This memorandum documents the source and numerical value of Henry’s law constants for volatile radionuclides of interest used in the non-groundwater (air and radon) pathways models for the 2018 E-Area Performance Assessment.

Analysis of the potential contamination risk of groundwater resources circulating in areas with anthropogenic activities

Directory of Open Access Journals (Sweden)

M. Spizzico

2005-01-01

Full Text Available The area investigated is located in the province of Brindisi (Italy. It is a generally flat area separated from the nearby carbonatic plateau of the Murgia by quite indistinct and high fault scarps. As regards the geological features, carbonatic basement rocks and post-cretaceous terrains made up of calabrian calcarenites and middle-upper Pleistocenic marine terraced deposits can be distinguished. In the examined area there are two different hydrogeological environments. The first is represented by deep groundwater, the main groundwater resource in Apulia. The second hydrogeological environment, now of lesser importance than the deep aquifer in terms of size and use, is made up of some small shallow groundwater systems situated in post-calabrian sands and located in the eastern area. During some sampling cycles carried out in the studied area, water was withdrawn from both the deep aquifer and from the shallow groundwater. For every sample, the necessary parameters were determined for the physical and chemical characterisation of two different hydrogeological environments. Moreover, some chemical parameters indicating anthropogenic activities were determined. Analysis of the aerial distribution of the measured parameters has shown some main areas subject to different conditions of contamination risk, in accordance with the hydrogeological and geological features of the investigated area. In the south-eastern part of the investigated area, the important action performed by the surface aquifer for protecting the deep groundwater from contamination of anthropogenic origin is clear. On the other hand, in the shallow groundwater, areas of nitrate and nitrite contamination have been identified, which result from the extensive use of fertilizers.

Analysis of groundwater from deep boreholes in Gideaa

International Nuclear Information System (INIS)

Laurent, S.

1983-03-01

Groundwaters from two boreholes in granitic rock at an ivestigation site in Gideaa has been sampled and analysed. This is part of a larger program of geological, geophysical and hydrogeological investigations aimed at finding a suitable site for a high level radioactive waste respository. Five water-bearing levels in each borehole down to the deepest at about 500 m in the first and about 600 m in the second borehole were selected. Prior to sampling, the waterbearing level is isolated between packer sleeves. The water is then pumped to the surface where sensitive parameters such as redox potential, pH, sulphide and oxygen content are measured electrochemically on the flowing water in a system isolated from the air. Water, filter and gas samples are sent to several laboratories for further analysis. The present report is a presentation of the groundwater analysis. The reliability of the results is discussed but there is no evaluation relation to geology and hydrogeology. This report presents the basic results from the groundwater analyses to be further evaluated by experts in different fields. (Forf)

Assessment of natural attenuation of ground-water contamination at sites FT03, LF13, and WP14/LF15, Dover Air Force Base, Delaware

Science.gov (United States)

Barbaro, Jeffrey R.

2002-01-01

Water-quality, aquifer-sediment, and hydro-logic data were used to assess the effectiveness of natural attenuation of ground-water contamination at Fire Training Area Three, the Rubble Area Landfill, the Liquid Waste Disposal Landfill, and the Receiver Station Landfill in the East Management Unit of Dover Air Force Base, Delaware. These sites, which are contaminated with chlorinated solvents and fuel hydrocarbons, are under-going long-term monitoring to determine if natural attenuation continues to sufficiently reduce contaminant concentrations to meet regulatory requirements. This report is the first assessment of the effectiveness of natural attenuation at these sites since long-term monitoring began in 1999, and follows a preliminary investigation done in 1995?96. This assessment was done by the U.S. Geological Survey in cooperation with the U.S. Air Force.Since 1995?96, additional information has been collected and used in the current assessment. The conclusions in this report are based primarily on ground-water samples collected from January through March 2000. Previous analytical results from selected wells, available geologic and geo-physical well logs, and newly acquired information such as sediment organic-carbon measurements, hydraulic-conductivity measurements determined from slug tests on wells in the natural attenuation study area, and water-level measurements from surficial-aquifer wells also were used in this assessment. This information was used to: (1) calculate retardation factors and estimate contaminant migration velocities, (2) improve estimates of ground-water flow directions and inferred contaminant migration pathways, (3) better define the areal extent of contamination and the proximity of contaminants to discharge areas and the Base boundary, (4) develop a better under-standing of the vertical variability of contaminant concentrations and redox conditions, (5) evaluate the effects of temporal changes on concentrations in the plumes and

Explanation of significant differences for the TNX groundwater operable unit

International Nuclear Information System (INIS)

Palmer, E.R.

1997-01-01

This Explanation of Significant Differences (ESD) is being issued by the Department of Energy (DOE), the lead agency for the Savannah River Site (SRS), with concurrence by the Environmental Protection Agency-Region IV (EPA) and South Carolina Department of Health and Environmental Control (SCDHEC) to announce changes in the interim remediation strategy selected for the TNX Groundwater Operable Unit. The TNX Area is located adjacent to the Savannah River in the southwestern portion of SRS. The remedy selected in the Interim Record of Decision (IROD) to achieve the interim action goals was the Hybrid Groundwater Corrective Action (HGCA). The HGCA consisted of a recirculation well system and an air stripper with a series of groundwater extraction wells. The original remediation strategy needs to be modified because the recirculation well system was determined to be ineffective in this area due to geological factors and the nature of the contamination

Deciphering groundwater quality for irrigation and domestic purposes - a case study in Suri I and II blocks, Birbhum District, West Bengal, India

Science.gov (United States)

Das, Shreya; Nag, S. K.

2015-07-01

Assessment of the hydrochemical characteristics of water and aquifer hydraulic properties is important for groundwater planning and management in the study area. It is not only the basic need for human existence but also a vital input for all development activities. The present hydro-geochemical study of groundwater samples from the Suri I and II blocks of Birbhum district, West Bengal (23.76 ∘-23.99 ∘N; 87.42 ∘-87.64 ∘E) was carried out to assess their suitability for agricultural, domestic and drinking purposes. For this study, samples were collected from 26 locations during the post-monsoon and pre-monsoon sessions spanning over 2012 and 2013. Groundwater samples were analyzed for their physical and chemical properties using standard laboratory methods. Physical and chemical parameters of groundwater such as pH, electrical conductivity, total dissolved solids, Na, K, Ca, Mg, Fe, Cl, HCO3, SO4 and F were determined. Various water quality indices like SAR, SSP, PI, RSC, MAR and KR have been calculated for each water sample to identify the irrigational suitability standard. According to most of these parameters, the groundwater has been found to be well to moderately suitable for irrigation. In the post-monsoon session exceptionally high RSC values for around 80% samples indicate an alkaline hazard to the soil. The ion balance histogram for post-monsoon indicates undesirable ion balance values according to fresh water standards whereas in pre-monsoon, the samples show good ion balance in water. For determination of the drinking suitability standard of groundwater, three parameters have been considered - total hardness (TH), Piper's trilinear diagram and water quality index study. Groundwater of the present study area has been found to be moderately-hard to hard during both sampling sessions and hence poses no health risk which could arise due to excess consumption of calcium or magnesium. Hydrogeochemical facies in the form of Piper's trilinear diagram plot

Simulation of regional-scale groundwater flow in the Azul River basin, Buenos Aires Province, Argentina

Science.gov (United States)

Varni, Marcelo R.; Usunoff, Eduardo J.

A three-dimensional modular model (MODFLOW) was used to simulate groundwater flow in the Azul River basin, Buenos Aires Province, Argentina, in order to assess the correctness of the conceptual model of the hydrogeological system. Simulated heads satisfactorily match observed heads in the regional water-table aquifer. Model results indicate that: (1) groundwater recharge is not uniform throughout the region but is best represented by three recharge rates, decreasing downgradient, similar to the distribution of soils and geomorphological characteristics; and (2) evapotranspiration rates are larger than previous estimates, which were made by using the Thornthwaite-Mather method. Evapotranspiration rates estimated by MODFLOW agree with results of independent studies of the region. Model results closely match historical surface-flow records, thereby suggesting that the model description of the aquifer-river relationship is correct. Résumé Un modèle modulaire tridimensionnel (MODFLOW) a été utilisé pour simuler les écoulements souterrains dans le bassin de la rivière Azul (Province de Buenos Aires, Argentine), dans le but d'évaluer la justesse du modèle conceptuel du système hydrogéologique. La piézométrie simulée s'ajuste de façon satisfaisante à celle observée pour l'ensemble de la nappe. Les résultats du modèle indiquent que: (1) la recharge de la nappe n'est pas uniforme sur toute la région, mais qu'elle est mieux approchée par trois valeurs différentes, décroissant vers l'aval-gradient, en suivant la même distribution que les sols et les caractéristiques géomorphologiques et (2) l'évapotranspiration est nettement plus importante que prévu initialement à partir de la méthode de Thornthwaite-Mather. Les valeurs d'évapotranspiration fournies par MODFLOW concordent bien avec les résultats d'autres études portant sur la région. Les résultats du modèle reproduisent convenablement les chroniques de débit des écoulements de surface

Groundwater quota versus tiered groundwater pricing : two cases of groundwater management in north-west China

NARCIS (Netherlands)

Aarnoudse, Eefje; Qu, Wei; Bluemling, B.; Herzfeld, Thomas

2017-01-01

Difficulties in monitoring groundwater extraction cause groundwater regulations to fail worldwide. In two counties in north-west China local water authorities have installed smart card machines to monitor and regulate farmers’ groundwater use. Data from a household survey and in-depth interviews are

Comparison of a Conceptual Groundwater Model and Physically Based Groundwater Mode

Science.gov (United States)

Yang, J.; Zammit, C.; Griffiths, J.; Moore, C.; Woods, R. A.

2017-12-01

Groundwater is a vital resource for human activities including agricultural practice and urban water demand. Hydrologic modelling is an important way to study groundwater recharge, movement and discharge, and its response to both human activity and climate change. To understand the groundwater hydrologic processes nationally in New Zealand, we have developed a conceptually based groundwater flow model, which is fully integrated into a national surface-water model (TopNet), and able to simulate groundwater recharge, movement, and interaction with surface water. To demonstrate the capability of this groundwater model (TopNet-GW), we applied the model to an irrigated area with water shortage and pollution problems in the upper Ruamahanga catchment in Great Wellington Region, New Zealand, and compared its performance with a physically-based groundwater model (MODFLOW). The comparison includes river flow at flow gauging sites, and interaction between groundwater and river. Results showed that the TopNet-GW produced similar flow and groundwater interaction patterns as the MODFLOW model, but took less computation time. This shows the conceptually-based groundwater model has the potential to simulate national groundwater process, and could be used as a surrogate for the more physically based model.

Dissolution of unirradiated UO{sub 2} fuel in synthetic groundwater. Final report (1996-1998)

Energy Technology Data Exchange (ETDEWEB)

Ollila, K. [VTT Chemical Technology, Espoo (Finland)

1999-05-01

This study was a part of the EU R and D programme 1994-1998: Nuclear Fission Safety, entitled `Source term for performance assessment of spent fuel as a waste form`. The research carried out at VTT Chemical Technology was focused on the effects of granitic groundwater composition and redox conditions on UO{sub 2} solubility and dissolution mechanisms. The synthetic groundwater compositions simulated deep granitic fresh and saline groundwaters, and the effects of the near-field material, bentonite, on very saline groundwater. Additionally, the Spanish granite/bentonite water was used. The redox conditions (Eh), which are obviously the most important factors that influence on UO{sub 2} solubility under the disposal conditions of spent fuel, varied from strongly oxidising (air-saturated), anaerobic (N{sub 2}, O{sub 2} < l ppm) to reducing (N{sub 2}, low Eh). The objective of the air-saturated dissolution experiments was to yield the maximum solution concentrations of U, and information on the formation of secondary phases that control the concentrations, with different groundwater compositions. The static batch solubility experiments of long duration (up to 1-2 years) were performed using unirradiated UO{sub 2} pellets and powder. Under anaerobic and reducing conditions, the solubilities were also approached from oversaturation. The results of the oxic, air-saturated dissolution experiments with UO{sub 2} powder showed that the increase in the salinity (< 1.7 M) had a minor effect on the measured steady-state concentrations of U. The concentrations, (1.2 ...2.5) x 10{sup -5} M, were at the level of the theoretical solubility of schoepite or another uranyl oxide hydrate, e.g. becquerelite (possibly Na-polyuranate). The higher alkalinity of the fresh (Allard) composition increased the aqueous U concentration. Only some kind of oxidised U-phase (U{sub 3}O{sub 8}-UO{sub 3}) was identified with XRD when studying possible secondary phases after the contact time of one year

Simulation of Groundwater Flow, Denpasar-Tabanan Groundwater Basin, Bali Province

Directory of Open Access Journals (Sweden)

Heryadi Tirtomihardjo

2014-06-01

Full Text Available DOI: 10.17014/ijog.v6i3.123Due to the complex structure of the aquifer systems and its hydrogeological units related with the space in which groundwater occurs, groundwater flows were calculated in three-dimensional method (3D Calculation. The geometrical descritization and iteration procedures were based on an integrated finite difference method. In this paper, all figures and graphs represent the results of the calibrated model. Hence, the model results were simulated by using the actual input data which were calibrated during the simulation runs. Groundwater flow simulation of the model area of the Denpasar-Tabanan Groundwater Basin (Denpasar-Tabanan GB comprises steady state run, transient runs using groundwater abstraction in the period of 1989 (Qabs-1989 and period of 2009 (Qabs-2009, and prognosis run as well. Simulation results show, in general, the differences of calculated groundwater heads and observed groundwater heads at steady and transient states (Qabs-1989 and Qabs-2009 are relatively small. So, the groundwater heads situation simulated by the prognosis run (scenario Qabs-2012 are considerably valid and can properly be used for controlling the plan of groundwater utilization in Denpasar-Tabanan GB.

ZONASI POTENSI PENCEMARAN AIR TANAH PADA TERAS SUNGAI CODE YOGYAKARTA (Zoning The Potential Groundwater Pollution at Code River Terrace, Yogyakarta

Directory of Open Access Journals (Sweden)

Frista Yorhanita

2001-08-01

Full Text Available ABSTRAK Tujuan penelitian ini ialah untuk membuktikan bahwa biomassa Fusarium sp dapat mereduksi Cr(VI, dan biomassa Aspergillus niger dapat digunakan untuk mengambil ion krom dari larutan. Fusarium.sp ditumbuhkan pada media cair kentang dekftosa cair, ditambah K2Cr2O7 atau sludge limbah penyamakan kulit. Selanjutnya diamati perubahan warnanya, bila terjadi perubahan warna dan oranye ke ungu atau tak berwarna maka telah terjadi reduksi krom valensi VI menjadi krom valensi Ill. Aspergillus niger ditumbuhkan pada media Potato dectrose agar (PDA padat, dipindahkan ke media cair yang bensi bakto pepton, bakto dektrose dan srukronutrien. Produksi biomassa dilakukan pada labu erlenmeyer; setelah 5 hari dipanen dan dibuat bubuk. Bubuk ini digunakan untuk mengambil krom dari larutan. Hasil penelitian menunjukkan bahwa biomassa Fusarium sp dapat digunakan untuk mengambil krom dan larutan yang.mengandung KrCrrO, atau sludge limbah penyamakan kulit. Waktu inkubasi yang lebih lama meningkatkan absorbsi krom oleh biomassa Fascrium sp. Fusarium sp mampu mereduksi Cr(VI menjadi Cr(Iii. Biomassa Aspergillus niger dapat digunakan untuk mengambil krom dari larutan. Hasil terbaik diperoleh pada konsentrasi awal 100 mg/I, pada pH 2,0, berat biomassa 0,1 g, dan waktu kontak 12 jam, yaitu 96,23% untuk Cr(II| dan96,3 % untuk Cr(VI. Fusarium sp. dan A. niger dapat digunakan sebagai bioremediator dalam penanganan limbah penyamakan kulit secara biologi.   ABSTRACT The study area of this research was parts of the code river terraces, Yogyakarta. The aims of this research were as follows: (1 to determine the part of the code river terrace which has potential groundwater pollution; (2 to assess the natural physical factors (aquifer materials, depth of groundwater table, and the groundwater flow distance and the non-natural physical factors of environmental sanitation (houses density, population density, horizontal distance between pollution source and well, and the number

Estimating Groundwater Development area in Jianan Plain using Standardized Groundwater Index

Science.gov (United States)

Yu, Chang Hsiang; Haw, Lee Cheng

2017-04-01

Taiwan has been facing severe water crises in recent years owing to the effects of extreme weather conditions. Changes in precipitation patterns have also made the drought phenomenon increasingly prominent, which has indirectly affected groundwater recharge. Hence, in the present study, long-term monitoring data were collected from the study area of the Jianan plain. The standardized groundwater index (SGI) and was then used to analyse the region's drought characteristics. To analyse the groundwater level by using SGI, making SGI180 groundwater level be the medium water crises, and SGI360 groundwater level be the extreme water crises. Through the different water crises signal in SGI180 and SGI360, we divide groundwater in Jianan plain into two sections. Thereby the water crises indicators establishing groundwater level standard line in Jianan Plain, then using the groundwater level standard line to find the study area where could be groundwater development area in Jianan plain. Taking into account relatively more water scarcity in dry season, so the study screen out another emergency backup groundwater development area, but the long-term groundwater development area is still as a priority development area. After finding suitable locations, groundwater modeling systems(GMS) software is used to simulate our sites to evaluate development volume. Finally, the result of study will help the government to grasp the water shortage situation immediately and solve the problem of water resources deployment.

Learning Large Lessons: The Evolving Roles of Ground Power and Air Power in the Post-Cold War Era. Executive Summary

National Research Council Canada - National Science Library

Johnson, David E

2007-01-01

U.S. post-Cold War military operations have witnessed a shift in the relative roles of ground power and air power in war fighting, but the joint war fighting potential of this shift is not being fully realized...

Use of Sodium Dithionite as Part of a More Efficient Groundwater Restoration Method Following In-situ Recovery of Uranium at the Smith-Ranch Highland Site in Wyoming

Science.gov (United States)

Harris, R.; Reimus, P. W.; Ware, D.; Williams, K.; Chu, D.; Perkins, G.; Migdissov, A. A.; Bonwell, C.

2017-12-01

Uranium is primarily mined for nuclear power production using an aqueous extraction technique called in-situ recovery (ISR). ISR can pollute groundwater with residual uranium and other heavy metals. Reverse osmosis and groundwater sweep are currently used to restore groundwater after ISR mining, but are not permanent solutions. Sodium dithionite is being tested as part of a method to more permanently restore groundwater after ISR mining at the Smith-Ranch Highland site in Wyoming. Sodium dithionite is a chemical reductant that can reduce sediments that were oxidized during ISR. The reduced sediments can reduce soluble uranium (VI) in the groundwater to insoluble uranium (IV). Laboratory studies that use sodium dithionite to treat sediments and waters from the site may help predict how it will behave during a field deployment. An aqueous batch experiment showed that sodium dithionite reduced uranium in post-mined untreated groundwater from 38 ppm to less than 1 ppm after 1 day. A sediment reduction batch experiment showed that sodium dithionite-treated sediments were capable of reducing uranium in post-mined untreated groundwater from 38 ppm to 2 ppm after 7 days. One column experiment is showing post-mined sodium dithionite-treated sediments are capable of reducing uranium in post-mined groundwater for over 30 pore volumes past the initial injection. While these results are promising for field deployments of sodium dithionite, another column experiment with sodium dithionite-treated sediments containing uranium rich organic matter is showing net production of uranium instead of uranium uptake. Sodium dithionite appears to liberate uranium from the organic matter. Another sediment reduction experiment is being conducted to further investigate this hypothesis. These experiments are helping guide plans for field deployments of sodium dithionite at uranium ISR mining sites.

Quantifying effects of climate change on the snowmelt-dominated groundwater resources of northern New England

Science.gov (United States)

Dudley, Robert W.; Hodgkins, Glenn A.; Shanley, James B.; Mack, Thomas J.

2010-01-01

Recent U.S. Geological Survey (USGS) climate studies in New England have shown substantial evidence of hydrologic changes during the last 100 years, including trends toward earlier snowmelt runoff, decreasing occurrence of river ice, and decreasing winter snowpack. These studies are being expanded to include investigation of trends in groundwater levels and fluctuations. Groundwater is an important drinking-water source throughout northern New England (Maine, New Hampshire, and Vermont). The USGS is currently investigating whether or not groundwater recharge from snowmelt and precipitation exhibits historical trends. In addition to trend-testing, groundwater resources also will be analyzed by relating groundwater-level changes to the large year-to-year variability in weather conditions. Introduction The USGS has documented many seasonal climate-related changes in the northeastern United States that have occurred during the last 30 to 150 years. These changes include earlier snowmelt runoff in the late winter and early spring, decreasing duration of ice on rivers and lakes, decreasing ratio of snowfall to total precipitation, and denser and thinner late-winter snowpack. All of these changes are consistent with warming winter and spring air temperatures (Dudley and Hodgkins, 2002; Hodgkins and others, 2002; Huntington and others, 2004; Hodgkins and others, 2005; Hodgkins and Dudley, 2006a; Hodgkins and Dudley, 2006b). Climate-model projections for the Northeast indicate air-temperature warming, earlier snowmelt runoff, increases in annual evaporation, and decreased low streamflows (Hayhoe and others, 2007). The contribution and timing of spring snowmelt to groundwater recharge is particularly important to groundwater resources in the northeastern United States where aquifers typically consist of thin sediments overlying crystalline bedrock with relatively little storage capacity (Mack, 2009). Following spring recharge, groundwater slowly flows into streams throughout

Relationships between air-tightness and its influencing factors of post-2006 new-build dwellings in the UK

Energy Technology Data Exchange (ETDEWEB)

Pan, Wei [School of Architecture, Design and Environment, University of Plymouth, Drake Circus, Plymouth, PL4 8AA (United Kingdom)

2010-11-15

Addressing air leakage of dwellings is important to improving energy efficiency and thermal comfort. This paper reports on the air permeability test results of 287 post-2006 new-build dwellings in the UK. The paper explores the relationships between air-tightness and its influencing factors including build method, dwelling type, management context, design target, season, number of significant penetrations, and envelope and floor area. One-way ANOVA analysis was utilised to compare means of air permeability in relation to the individual factors, and two- and three-way ANOVA analyses were applied for examining the interactions between them. The air-tightness of the dwellings averaged 5.97 m{sup 3}/(h m{sup 2}) at 50 Pa, which has improved from UK historic data. Dwellings built using precast concrete panels were significantly air-tighter than those built using timber frame, whilst those masonry and reinforced concrete frame dwellings were most leaky. Greater extent of innovative practice and 'self-build' procurement led to achieving superior air-tightness. Interaction was observed between 'build method' and 'dwelling type' and between 'dwelling type' and 'management context'. A modest positive correlation was noticed between air permeability and design target, which became weak in relation to the number of significant penetrations and envelope area. Applying the linear regression technique a predictive model is developed for estimating air permeability of dwellings. This model integrates the influencing factors and their significant interactions. The findings should contribute to future research in predicting impacts of controlling the influencing factors on achieving air-tightness of dwellings more consistently. (author)

Local climate change induced by groundwater overexploitation in a high Andean arid watershed, Laguna Lagunillas basin, northern Chile

Science.gov (United States)

Scheihing, Konstantin; Tröger, Uwe

2018-05-01

The Laguna Lagunillas basin in the arid Andes of northern Chile exhibits a shallow aquifer and is exposed to extreme air temperature variations from 20 to -25 °C. Between 1991 and 2012, groundwater levels in the Pampa Lagunillas aquifer fell from near-surface to 15 m below ground level (bgl) due to severe overexploitation. In the same period, local mean monthly minimum temperatures started a declining trend, dropping by 3-8 °C relative to a nearby reference station. Meanwhile, mean monthly maximum summer temperatures shifted abruptly upwards by 2.7 °C on average in around 1996. The observed air temperature downturns and upturns are in accordance with detected anomalies in land-surface temperature imagery. Two major factors may be causing the local climate change. One is related to a water-table decline below the evaporative energy potential extinction depth of 2 m bgl, which causes an up-heating of the bare soil surface and, in turn, influences the lower atmosphere. At the same time, the removal of near-surface groundwater reduces the thermal conductivity of the upper sedimentary layer, which consequently diminishes the heat exchange between the aquifer (constant heat source of 10 °C) and the lower atmosphere during nights, leading to a severe dropping of minimum air temperatures. The observed critical water-level drawdown was 2-3 m bgl. Future and existing water-production projects in arid high Andean basins with shallow groundwater should avoid a decline of near-surface groundwater below 2 m bgl and take groundwater-climate interactions into account when identifying and monitoring potential environmental impacts.

Groundwater flow modelling of periods with temperate climate conditions - Forsmark

Energy Technology Data Exchange (ETDEWEB)

Joyce, Steven; Simpson, Trevor; Hartley, Lee; Applegate, David; Hoek, Jaap; Jackson, Peter; Swan, David (Serco Technical Consulting Services (United Kingdom)); Marsic, Niko (Kemakta Konsult AB (Sweden)); Follin, Sven (SF GeoLogic AB (Sweden))

2010-11-15

As a part of the license application for a final repository for spent nuclear fuel at Forsmark, the Swedish Nuclear Fuel and Waste Management Company (SKB) has undertaken a series of groundwater flow modelling studies. These represent time periods with different climate conditions and the simulations carried out contribute to the overall evaluation of the repository design and long-term radiological safety. This report concerns the modelling of a repository at the Forsmark site during temperate conditions; i.e. from post-closure and throughout the temperate period up until the receding shoreline leaves the modelling domain at around 12,000 AD. The collation and implementation of onsite hydrogeological and hydrogeochemical data from previous reports are used in the construction of a hydrogeological base case (reference case conceptualisation) and then in an examination of various areas of uncertainty within the current understanding by a series of model variants. The hydrogeological base case models at three different scales, 'repository', 'site' and 'regional', make use of continuous porous medium (CPM), equivalent continuous porous medium (ECPM) and discrete fracture network (DFN) models. The use of hydrogeological models allow for the investigation of the groundwater flow from a deep disposal facility to the biosphere and for the calculation of performance measures that will provide an input to the site performance assessment. The focus of the study described in this report has been to perform numerical simulations of the hydrogeological system from post-closure and throughout the temperate period. Besides providing quantitative results for the immediate temperate period following post-closure, these results are also intended to give a qualitative indication of the evolution of the groundwater system during future temperate periods within an ongoing cycle of glacial/inter-glacial events

Assessing groundwater policy with coupled economic-groundwater hydrologic modeling

Science.gov (United States)

Mulligan, Kevin B.; Brown, Casey; Yang, Yi-Chen E.; Ahlfeld, David P.

2014-03-01

This study explores groundwater management policies and the effect of modeling assumptions on the projected performance of those policies. The study compares an optimal economic allocation for groundwater use subject to streamflow constraints, achieved by a central planner with perfect foresight, with a uniform tax on groundwater use and a uniform quota on groundwater use. The policies are compared with two modeling approaches, the Optimal Control Model (OCM) and the Multi-Agent System Simulation (MASS). The economic decision models are coupled with a physically based representation of the aquifer using a calibrated MODFLOW groundwater model. The results indicate that uniformly applied policies perform poorly when simulated with more realistic, heterogeneous, myopic, and self-interested agents. In particular, the effects of the physical heterogeneity of the basin and the agents undercut the perceived benefits of policy instruments assessed with simple, single-cell groundwater modeling. This study demonstrates the results of coupling realistic hydrogeology and human behavior models to assess groundwater management policies. The Republican River Basin, which overlies a portion of the Ogallala aquifer in the High Plains of the United States, is used as a case study for this analysis.

Monitoring and Assessing Groundwater Impacts on Vegetation Health in Groundwater Dependent Ecosystems

Science.gov (United States)

Rohde, M. M.; Ulrich, C.; Howard, J.; Sweet, S.

2017-12-01

Sustainable groundwater management is important for preserving our economy, society, and environment. Groundwater supports important habitat throughout California, by providing a reliable source of water for these Groundwater Dependent Ecosystems (GDEs). Groundwater is particularly important in California since it supplies an additional source of water during the dry summer months and periods of drought. The drought and unsustainable pumping practices have, in some areas, lowered groundwater levels causing undesirable results to ecosystems. The Sustainable Groundwater Management Act requires local agencies to avoid undesirable results in the future, but the location and vulnerabilities of the ecosystems that depend on groundwater and interconnected surface water is often poorly understood. This presentation will feature results from a research study conducted by The Nature Conservancy and Lawrence Berkeley National Laboratory that investigated how changes in groundwater availability along an interconnected surface water body can impact the overall health of GDEs. This study was conducted in California's Central Valley along the Cosumnes River, and situated at the boundary of a high and a medium groundwater basin: South American Basin (Sacramento Hydrologic Region) and Cosumnes Basin (San Joaquin Hydrologic Region). By employing geophysical methodology (electrical resistivity tomography) in this study, spatial changes in groundwater availability were determined under groundwater-dependent vegetation. Vegetation survey data were also applied to this study to develop ecosystem health indicators for groundwater-dependent vegetation. Health indicators for groundwater-dependent vegetation were found to directly correlate with groundwater availability, such that greater availability to groundwater resulted in healthier vegetation. This study provides a case study example on how to use hydrological and biological data for setting appropriate minimum thresholds and

Computation of groundwater resources and recharge in Chithar River Basin, South India.

Science.gov (United States)

Subramani, T; Babu, Savithri; Elango, L

2013-01-01

Groundwater recharge and available groundwater resources in Chithar River basin, Tamil Nadu, India spread over an area of 1,722 km(2) have been estimated by considering various hydrological, geological, and hydrogeological parameters, such as rainfall infiltration, drainage, geomorphic units, land use, rock types, depth of weathered and fractured zones, nature of soil, water level fluctuation, saturated thickness of aquifer, and groundwater abstraction. The digital ground elevation models indicate that the regional slope of the basin is towards east. The Proterozoic (Post-Archaean) basement of the study area consists of quartzite, calc-granulite, crystalline limestone, charnockite, and biotite gneiss with or without garnet. Three major soil types were identified namely, black cotton, deep red, and red sandy soils. The rainfall intensity gradually decreases from west to east. Groundwater occurs under water table conditions in the weathered zone and fluctuates between 0 and 25 m. The water table gains maximum during January after northeast monsoon and attains low during October. Groundwater abstraction for domestic/stock and irrigational needs in Chithar River basin has been estimated as 148.84 MCM (million m(3)). Groundwater recharge due to monsoon rainfall infiltration has been estimated as 170.05 MCM based on the water level rise during monsoon period. It is also estimated as 173.9 MCM using rainfall infiltration factor. An amount of 53.8 MCM of water is contributed to groundwater from surface water bodies. Recharge of groundwater due to return flow from irrigation has been computed as 147.6 MCM. The static groundwater reserve in Chithar River basin is estimated as 466.66 MCM and the dynamic reserve is about 187.7 MCM. In the present scenario, the aquifer is under safe condition for extraction of groundwater for domestic and irrigation purposes. If the existing water bodies are maintained properly, the extraction rate can be increased in future about 10% to 15%.

Phytoremediation of 1,4-dioxane-containing recovered groundwater.

Science.gov (United States)

Ferro, Ari M; Kennedy, Jean; LaRue, James C

2013-01-01

The results of a pilot-scale phytoremediation study are reported in this paper. Small plots of trees established on a closed municipal waste landfill site were irrigated with recovered groundwater containing 1,4-dioxane (dioxane) and other volatile organic compounds (VOCs). The plots were managed to minimize the leaching of irrigation water, and leaching was quantified by the use of bromide tracer. Results indicated that the dioxane (2.5 microg/L) was effectively removed, probably via phytovolatilization, and that a full-scale phytoremediation system could be used. A system is now in place at the site in which the recovered groundwater can be treated using two different approaches. A physical treatment system (PTS) will be used during the winter months, and a 12 ha phytoremediation system (stands of coniferous trees) will be used during the growing season. The PTS removes VOCs using an air-stripper, and destroys dioxane using a photo-catalytic oxidation process. Treated water will be routed to the local sewer system. The phytoremediation system, located on the landfill, will be irrigated with effluent from the PTS air-stripper containing dioxane. Seasonal use of the phytoremediation system will reduce reliance on the photo-catalytic oxidation process that is extremely energy consumptive and expensive to operate.

Metropol: A computer code for the simulation of transport of contaminants with groundwater

International Nuclear Information System (INIS)

Sauter, F.J.; Hassanizadeh, S.M.; Leijnse, A.; Glasbergen, P.; Slot, A.F.M.

1990-01-01

In this report a description is given of the computer code Metropol. This code simulates the three-dimensional flow of groundwater with varying density and the simultaneous transport of contaminants in low concentration and is based on the finite element method. The basic equations for groundwater flow and transport are described as well as the mathematical techniques used to solve these equations. Pre-processing facilities for mesh generation and post-processing facilities such as particle tracking are also discussed. This work was part of the Community Mirage project Second phase, research area Calculation tools

Carbon-14 dating of groundwater under Christchurch, 1976 samples

International Nuclear Information System (INIS)

Stewart, M.K.; Brenninkmeijer, C.A.M.; Brown, L.J.

1986-06-01

Four samples of groundwater from deep aquifers under Christchurch have been analysed for carbon-14, tritium, oxygen-18 and chemical contents. Interpretation of the carbon-14 results requires two steps, (1) correction of the measured 14 C values for input of dead ( 14 C-free) carbon underground (indicating that the measured values of 80 PMC* should be increased to about 120 PMC), and (2) determination of water residence times for given flow models of the groundwater system. Interpretation of tritium results involves step 2 only. Three models are considered, of which the third is considered most appropriate to Christchurch. In this model, the 14 C and T results indicate that a small proportion of young water (post-1954) mixes with a larger proportion of older water (probably at least several hundred years). The oxygen-18 content indicates that recharge is mainly from the Waimakariri River and possibly from rainfall and streams near the foothills of the Canterbury Plains. Other aspect of the groundwater flow under Christchurch are discussed

Groundwater sustainability strategies

Science.gov (United States)

Gleeson, Tom; VanderSteen, Jonathan; Sophocleous, Marios A.; Taniguchi, Makoto; Alley, William M.; Allen, Diana M.; Zhou, Yangxiao

2010-01-01

Groundwater extraction has facilitated significant social development and economic growth, enhanced food security and alleviated drought in many farming regions. But groundwater development has also depressed water tables, degraded ecosystems and led to the deterioration of groundwater quality, as well as to conflict among water users. The effects are not evenly spread. In some areas of India, for example, groundwater depletion has preferentially affected the poor. Importantly, groundwater in some aquifers is renewed slowly, over decades to millennia, and coupled climate–aquifer models predict that the flux and/or timing of recharge to many aquifers will change under future climate scenarios. Here we argue that communities need to set multigenerational goals if groundwater is to be managed sustainably.

Technetium and neptunium reactions in basalt/groundwater systems

International Nuclear Information System (INIS)

Meyer, R.E.; Arnold, W.D.; Kelmers, A.D.; Kessler, J.H.; Clark, R.J.; Johnson, J.S. Jr.; Young, G.C.; Case, F.I.; Westmoreland, C.G.

1985-01-01

Sorption isotherms and apparent concentration limits for Tc(VII) and Np(V) for a variety of groundwater/basalt systems were determined using Grande Ronde basalt samples representative of the Hanford Site candidate high-level waste repository. Under oxic redox conditions (air present), little or no sorption of technetium was observed; neptunium exhibited low to moderate sorption ratios. Under anoxic redox conditions (oxygen-free), low to moderate sorption of technetium was often observed, but the extent of sorption was highly dependent upon the groundwater composition and the method of pretreatment (if any) of the basalt. Sorption isotherms for technetium under reducing redox conditions (hydrazine added) indicate an apparent concentration limit of approximately 10 -6 mol/l Tc. No apparent concentration limit was found for neptunium for concentrations in groundwater up to 10 -6 mol/l and 8 x 10 -7 mol/l under oxic and reducing (hydrazine added) redox conditions, respectively. Valence control and valence analysis experiments suggest that the sorption or precipitation of Tc and Np from groundwater in the presence of basalt may result from a heterogeneous reaction occurring on the surface of the basalt. One of the critical factors of this reduction reaction appears to be the accessibility of the reactive ferrous iron component of the basalt. The laboratory simulation of groundwater redox conditions representative of the repository environment through the use of solution phase redox reagents is of questionable validity, and information obtained by such experimental methods may not be defensible for site performance assessment calculations. Anoxic experiments conducted in an argon-filled glove box appear better suited for the laboratory simulation of in situ redox conditions. 15 references, 6 figures

Technetium and neptunium reactions in basalt/groundwater systems

International Nuclear Information System (INIS)

Meyer, R.E.; Arnold, W.D.; Kelmers, A.D.; Kessler, J.H.; Clark, R.J.; Johnson, J.S. Jr.; Young, G.C.; Case, F.I.; Westmoreland, C.G.; Florida State Univ., Tallahassee)

1984-01-01

Sorption isotherms and apparent concentration limits for Tc(VII) and Np(V) for a variety of groundwater/basalt systems were determined using Grande Ronde basalt samples representative of the Hanford Site candidate high-level waste repository. Under oxic redox conditions (air present), little or no sorption of technetium was observed; neptunium exhibited low to moderate sorption ratios. Under anoxic redox conditions (oxygen-free), low to moderate sorption of technetium was often observed, but the extent of sorption was highly dependent upon the groundwater composition and the method of pretreatment (if any) of the basalt. Sorption isotherms for technetium under reducing redox conditions (hydrazine added) indicate an apparent concentration limit of approximately 10 -6 mol/L Tc. No apparent concentration limit was found for neptunium for concentrations in groundwater up to approx. 10 -6 mol/L and 8 x 10 -7 mol/L under oxic and reducing (hydrazine added) redox conditions, respectively. Valence control and valence analysis experiments suggest that the sorption or precipitation of Tc and Np from groundwater in the presence of basalt may result from a heterogeneous reaction occurring on the surface of the basalt. One of the critical factors of this reduction reaction appears to be the accessibility of the reactive ferrous iron component of the basalt. The laboratory simulation of groundwater redox conditions representative of the repository environment through the use of solution phase redox reagents is of questionable validity, and information obtained by such experimental methods may not be defensible for site performance assessment calculations. Anoxic experiments conducted in an argon-filled glove box appear better suited for the laboratory simulation of in situ redox conditions. 15 refs., 6 tabs

Groundwater-surface water interaction

International Nuclear Information System (INIS)

White, P.A.; Clausen, B.; Hunt, B.; Cameron, S.; Weir, J.J.

2001-01-01

This chapter discusses natural and modified interactions between groundwater and surface water. Theory on recharge to groundwater from rivers is introduced, and the relative importance of groundwater recharge from rivers is illustrated with an example from the Ngaruroro River, Hawke's Bay. Some of the techniques used to identify and measure recharge to groundwater from gravel-bed rivers will be outlined, with examples from the Ngaruroro River, where the recharge reach is relatively well defined, and from the Rakaia River, where it is poorly defined. Groundwater recharged from rivers can have characteristic chemical and isotopic signatures, as shown by Waimakariri River water in the Christchurch-West Melton groundwater system. The incorporation of groundwater-river interaction in a regional groundwater flow model is outlined for the Waimea Plains, and relationships between river scour and groundwater recharge are examined for the Waimakariri River. Springs are the result of natural discharge from groundwater systems and are important water sources. The interactions between groundwater systems, springs, and river flow for the Avon River in New Zealand will be outlined. The theory of depletion of stream flow by groundwater pumpage will be introduced with a case study from Canterbury, and salt-water intrusion into groundwater systems with examples from Nelson and Christchurch. The theory of artificial recharge to groundwater systems is introduced with a case study from Hawke's Bay. Wetlands are important to flora, and the relationship of the wetland environment to groundwater hydrology will be discussed, with an example from the South Taupo wetland. (author). 56 refs., 25 figs., 3 tabs

Examining the impacts of increased corn production on groundwater quality using a coupled modeling system

Science.gov (United States)

This study demonstrates the value of a coupled chemical transport modeling system for investigating groundwater nitrate contamination responses associated with nitrogen (N) fertilizer application and increased corn production. The coupled Community Multiscale Air Quality Bidirect...

Baseline groundwater chemistry characterization in an area of future Marcellus shale gas development

Science.gov (United States)

Eisenhauer, P.; Zegre, N.; Edwards, P. J.; Strager, M.

2012-12-01

The recent increase in development of the Marcellus shale formation for natural gas in the mid-Atlantic can be attributed to advances in unconventional extraction methods, namely hydraulic fracturing, a process that uses water to pressurize and fracture relatively impermeable shale layers to release natural gas. In West Virginia, the Department of Energy estimates 95 to 105 trillion cubic feet (TCF) of expected ultimately recovery (EUR) of natural gas for this formation. With increased development of the Marcellus shale formation comes concerns for the potential of contamination to groundwater resources that serve as primary potable water sources for many rural communities. However, the impacts of this practice on water resources are poorly understood because of the lack of controlled pre versus post-drilling experiments attributed to the rapid development of this resource. To address the knowledge gaps of the potential impacts of Marcellus shale development on groundwater resources, a pre versus post-drilling study has been initiated by the USFS Fernow Experimental Forest in the Monongahela National Forest. Drilling is expected to start at three locations within the next year. Pre-drilling water samples were collected and analyzed from two groundwater wells, a shallow spring, a nearby lake, and river to characterize background water chemistry and identify potential end-members. Geochemical analysis includes major ions, methane, δ13C-CH4, δ2H-CH4, 226Radium, and δ13C-DIC. In addition, a GIS-based conceptual ground water flow model was developed to identify possible interactions between shallow groundwater and natural gas wells given gas well construction failure. This model is used to guide management decisions regarding groundwater resources in an area of increasing shale gas development.

Artificial Post mining lakes - a challenge for the integration in natural hydrography and river basin management

Science.gov (United States)

Fleischhammel, Petra; Schoenheinz, Dagmar; Grünewald, Uwe

2010-05-01

In terms of the European Water Framework Directive (WFD), post mining lakes are artificial water bodies (AWB). The sustainable integration of post mining lakes in the groundwater and surface water landscape and their consideration in river basin management plans have to be linked with various (geo)hydrological, hydro(geo)chemical, technological and socioeconomic issues. The Lower Lusatian lignite mining district in eastern Germany is part of the major river basins of river Elbe and river Oder. Regionally, the mining area is situated in the sub-basins of river Spree and Schwarze Elster. After the cessation of mining activities and thereby of the artificially created groundwater drawdown in numerous mining pits, a large number of post mining lakes are evolving as consequence of natural groundwater table recovery. The lakes' designated uses vary from water reservoirs to landscape, recreation or fish farming lakes. Groundwater raise is not only substantial for the lake filling, but also for the area rehabilitation and a largely self regulated water balance in post mining landscapes. Since the groundwater flow through soil and dump sites being affected by the former mining activities, groundwater experiences various changes in its hydrochemical properties as e.g. mineralization and acidification. Consequently, downstream located groundwater fed running and standing water bodies will be affected too. Respective the European Water Framework Directive, artificial post mining lakes are not allowed to cause significant adverse impacts on the good ecological status/potential of downstream groundwater and surface water bodies. The high sulphate concentrations of groundwater fed mining lakes which reach partly more than 1,000 mg/l are e.g. damaging concrete constructures in downstream water bodies thereby representing threats for hydraulic facilities and drinking water supply. Due to small amounts of nutrients, the lakes are characterised by oligo¬trophic to slightly

Climate reconstruction from borehole temperatures influenced by groundwater flow

Science.gov (United States)

Kurylyk, B.; Irvine, D. J.; Tang, W.; Carey, S. K.; Ferguson, G. A. G.; Beltrami, H.; Bense, V.; McKenzie, J. M.; Taniguchi, M.

2017-12-01

Borehole climatology offers advantages over other climate reconstruction methods because further calibration steps are not required and heat is a ubiquitous subsurface property that can be measured from terrestrial boreholes. The basic theory underlying borehole climatology is that past surface air temperature signals are reflected in the ground surface temperature history and archived in subsurface temperature-depth profiles. High frequency surface temperature signals are attenuated in the shallow subsurface, whereas low frequency signals can be propagated to great depths. A limitation of analytical techniques to reconstruct climate signals from temperature profiles is that they generally require that heat flow be limited to conduction. Advection due to groundwater flow can thermally `contaminate' boreholes and result in temperature profiles being rejected for regional climate reconstructions. Although groundwater flow and climate change can result in contrasting or superimposed thermal disturbances, groundwater flow will not typically remove climate change signals in a subsurface thermal profile. Thus, climate reconstruction is still possible in the presence of groundwater flow if heat advection is accommodated in the conceptual and mathematical models. In this study, we derive a new analytical solution for reconstructing surface temperature history from borehole thermal profiles influenced by vertical groundwater flow. The boundary condition for the solution is composed of any number of sequential `ramps', i.e. periods with linear warming or cooling rates, during the instrumented and pre-observational periods. The boundary condition generation and analytical temperature modeling is conducted in a simple computer program. The method is applied to reconstruct climate in Winnipeg, Canada and Tokyo, Japan using temperature profiles recorded in hydrogeologically active environments. The results demonstrate that thermal disturbances due to groundwater flow and climate

Groundwater quality in a mining activity area (The Bierzo Basin-Leon)

International Nuclear Information System (INIS)

Losa, A. de la; Moreno, L.; Nunez, I.

2010-01-01

The Bierzo Basin presents large coal mining structures without restore where the air exposition of metallic sulphurs could become a source of heavy metal pollution and acification of waters. This paper presents the results of a research focused on groundwater quality affected by the mining activity. A sampling campaign of both ground and surface waters was carried out. Altogether, 37 sampling points has been selected including 26 springs, 7 shallow wells for agricultural use and 4 river water samples, all of them directly or indirectly connected to groundwater. The interpretation of results is based on the multivariate analysis application. Sulphate is the dominant anion in both water types, and it is related, in most cases, to oxidation of sulphurs, widely represented in the study area. However, the main conclusion is that surface water and groundwater samples have no high abnormal contents of heavy metals due to the induced alteration by mining activity. (Author) 15 refs.

Passive sampling and analyses of common dissolved fixed gases in groundwater

International Nuclear Information System (INIS)

Spalding, Brian Patrick; Watson, David B.

2008-01-01

An in situ passive sampler and gas chromatographic protocol for analysis of the major and several minor fixed gases in groundwater was developed. A gas-tight syringe, mated to a short length of silicone tubing, was equilibrated with dissolved gases in groundwater by immersing in monitoring wells and was used to transport and to inject a 0.5 mL gas sample into a gas chromatograph. Using Ar carrier gas, a HaySep DB porous polymer phase, and sequential thermal conductivity and reductive gas detectors allowed good sensitivity for He, Ne, H2, N2, O2, CO, CH4, CO2, and N2O. Within 4 days of immersion in groundwater, samplers initially filled with either He or air attained the same and constant gas composition at an Oak Ridge, Tennessee, site heavily impacted by uranium, acidity, and nitrate. Between June 2006 and July 2007, 12 permanent groundwater wells were used to test the passive samplers in groundwater contaminated by a group of four closed radioactive wastewater seepage ponds; over a thousand passive gas samples from these wells averaged 56% CO2, 32.4% N2, 2.5% O2, 2.5% N2O, 0.20% CH4, 0.096% H2, and 0.023% CO with an average recovery of 95 14% of the injected gas volume

Investigation of ground-water contamination at a drainage ditch, Installation Restoration Site 4, Naval Air Station Corpus Christi, Corpus Christi, Texas, 2005–06

Science.gov (United States)

Vroblesky, Don A.; Casey, Clifton C.

2007-01-01

The U.S. Geological Survey, in cooperation with the Naval Facilities Engineering Command Southeast, used newly developed sampling methods to investigate ground-water contamination by chlorobenzenes beneath a drainage ditch on the southwestern side of Installation Restoration Site 4, Naval Air Station Corpus Christi, Corpus Christi, Texas, during 2005-06. The drainage ditch, which is a potential receptor for ground-water contaminants from Installation Restoration Site 4, intermittently discharges water to Corpus Christi Bay. This report uses data from a new type of pore-water sampler developed for this investigation and other methods to examine the subsurface contamination beneath the drainage ditch. Analysis of ground water from the samplers indicated that chlorobenzenes (maximum detected concentration of 160 micrograms per liter) are present in the ground water beneath the ditch. The concentrations of dissolved oxygen in the samples (less than 0.05-0.4 milligram per liter) showed that the ground water beneath and near the ditch is anaerobic, indicating that substantial chlorobenzene biodegradation in the aquifer beneath the ditch is unlikely. Probable alternative mechanisms of chlorobenzene removal in the ground water beneath the drainage ditch include sorption onto the organic-rich sediment and contaminant depletion by cattails through uptake, sorption, and localized soil aeration.

Geochemical and isotopic determination of deep groundwater contributions and salinity to the shallow groundwater and surface water systems, Mesilla Basin, New Mexico, Texas, and Mexico

Science.gov (United States)

Robertson, A.; Carroll, K. C.; Kubicki, C.; Purtshert, R.

2017-12-01

The Mesilla Basin/Conejos-Médanos aquifer system, extending from southern New Mexico to Chihuahua, Mexico, is a priority transboundary aquifer under the 2006 United States­-Mexico Transboundary Aquifer Assessment Act. Declining water levels, deteriorating water quality, and increasing groundwater use by municipal, industrial, and agricultural users on both sides of the international border raise concerns about long-term aquifer sustainability. Relative contributions of present-day and "paleo" recharge to sustainable fresh groundwater yields has not been determined and evidence suggests that a large source of salinity at the distal end of the Mesilla Basin is saline discharge from deep groundwater flow. The magnitude and distribution of those deep saline flow paths are not determined. The contribution of deep groundwater to discharge and salinity in the shallow groundwater and surface water of the Mesilla Basin will be determined by collecting discrete groundwater samples and analyzing for aqueous geochemical and isotopic tracers, as well as the radioisotopes of argon and krypton. Analytes include major ions, trace elements, the stable isotopes of water, strontium and boron isotopes, uranium isotopes, the carbon isotopes of dissolved inorganic carbon, noble gas concentrations and helium isotope ratios. Dissolved gases are extracted and captured from groundwater wells using membrane contactors in a process known as ultra-trace sampling. Gas samples are analyzed for radioisotope ratios of krypton by the ATTA method and argon by low-level counting. Effectiveness of the ultra-trace sampling device and method was evaluated by comparing results of tritium concentrations to the krypton-85 content. Good agreement between the analyses, especially in samples with undetectable tritium, indicates that the ultra-trace procedure is effective and confirms that introduction of atmospheric air has not occurred. The geochemistry data indicate a complex system of geochemical

Groundwater flow and transport modelling during the temperate period for the SR-Can assessment. Forsmark area - version 1.2

Energy Technology Data Exchange (ETDEWEB)

Hartley, Lee; Hoch, Andrew; Jackson, Peter; Joyce, Steve; McCarthy, Rachel; Rodwell, William; Swift, Ben [Serco Assurance, Harwell (United Kingdom); Marsic, Niko [Kemakta Konsult AB, Stockholm (Sweden)

2006-12-15

The focus of the study described in this report has been to perform numerical simulations of the geosphere from post-closure and throughout the temperate period up until the beginning of the next permafrost period around 9,000 AD. Together with providing quantitative results for the immediate temperate period following post-closure, these results are also intended to give a qualitative indication of the evolution of the groundwater system during future temperate periods within an ongoing cycle of glacial/inter-glacial events. Additional calculations were performed to assess the impact of the effects of gas and heat generation in the repository on groundwater flow.

Groundwater flow and transport modelling during the temperate period for the SR-Can assessment. Forsmark area - version 1.2

International Nuclear Information System (INIS)

Hartley, Lee; Hoch, Andrew; Jackson, Peter; Joyce, Steve; McCarthy, Rachel; Rodwell, William; Swift, Ben; Marsic, Niko

2006-12-01

The focus of the study described in this report has been to perform numerical simulations of the geosphere from post-closure and throughout the temperate period up until the beginning of the next permafrost period around 9,000 AD. Together with providing quantitative results for the immediate temperate period following post-closure, these results are also intended to give a qualitative indication of the evolution of the groundwater system during future temperate periods within an ongoing cycle of glacial/inter-glacial events. Additional calculations were performed to assess the impact of the effects of gas and heat generation in the repository on groundwater flow

An open loop equilibrator for continuous monitoring of radon at the groundwater-surface water interface

International Nuclear Information System (INIS)

Kil Yong Lee; Yoon Yeol Yoon; Soo Young Cho; Eunhee Lee; Sang-Ho Moon; Dong-Chan Koh; Kyoochul Ha; Yongcheol Kim; Kyung-Seok Ko

2015-01-01

A continuous monitoring system (CMS) using an open loop equilibrator for assessment of 222 Rn at the groundwater-surface water interface was developed and tested. For the characterization and validation of the system, three air loops (open loop, closed loop, and open bubble loop) were tested in relation to high and precise count rates, rapid response, and equilibration of radon. The water and air stream is fed to the equilibrator by an experimental setup with a commercial submersible water pump and the internal pump with built-in radon-in-air detector. Efficiency calibration of the CMS is done by simultaneous determination of a groundwater sample using liquid scintillation counting, and the RAD7 accessories RAD-H 2 O, BigBottle RAD-H 2 O. The higher count rates are provided by the closed loop. However, the open loop with bubbler (open bubble loop) provides the best precision count rates, rapid response, and equilibration time. The CMS allows radon determination in discrete water samples as well as continuous water streams. (author)

DOE groundwater protection strategy

International Nuclear Information System (INIS)

Lichtman, S.

1988-01-01

EH is developing a DOE-wide Groundwater Quality Protection Strategy to express DOE's commitment to the protection of groundwater quality at or near its facilities. This strategy responds to a September 1986 recommendation of the General Accounting Office. It builds on EPA's August 1984 Ground-Water Protection Strategy, which establishes a classification system designed to protect groundwater according to its value and vulnerability. The purposes of DOE's strategy are to highlight groundwater protection as part of current DOE programs and future Departmental planning, to guide DOE managers in developing site-specific groundwater protection practices where DOE has discretion, and to guide DOE's approach to negotiations with EPA/states where regulatory processes apply to groundwater protection at Departmental facilities. The strategy calls for the prevention of groundwater contamination and the cleanup of groundwater commensurate with its usefulness. It would require long-term groundwater protection with reliance on physical rather than institutional control methods. The strategy provides guidance on providing long-term protection of groundwater resources; standards for new remedial actions;guidance on establishing points of compliance; requirements for establishing classification review area; and general guidance on obtaining variances, where applicable, from regulatory requirements. It also outlines management tools to implement this strategy

Site scale groundwater flow in Haestholmen

International Nuclear Information System (INIS)

Loefman, J.

1999-05-01

Groundwater flow modelling on the site scale has been an essential part of site investigation work carried out at different locations since 1986. The objective of the modelling has been to provide results that characterise the groundwater flow conditions deep in the bedrock. The main result quantities can be used for evaluation of the investigation sites and of the preconditions for safe final disposal - of spent nuclear fuel. This study represents the groundwater flow modelling at Haestholmen, and it comprises the transient flow analysis taking into account the effects of density variations and the repository as well as the post-glacial land uplift. The analysis is performed by means of numerical finite element simulation of coupled and transient groundwater flow and solute transport carried out up to 10000 years into the future. This work provides also the results for the site-specific data needs for the block scale groundwater flow modelling at Haestholmen. Conceptually the fractured bedrock is divided into hydraulic units: the planar fracture zones and the remaining part of the bedrock. The equivalent-continuum (EC) model is applied so that each hydraulic unit is treated as a homogeneous and isotropic continuum with representative average characteristics. All the fracture zones are modelled explicitly and represented by two-dimensional finite elements. A site-specific simulation model for groundwater flow and solute transport is developed on the basis of the latest hydrogeological and hydrogeochemical field investigations at Haestholmen. The present topography together with a mathematical model describing the land uplift at the Haestholmen area are employed as a boundary condition at the surface of the model. The overall flow pattern is mostly controlled by the local variations in the topography and by the highly transmissive fracture zones. Near the surface the flow spreads out to offshore and to the lower areas of topography in all directions away from

Contribution of waterborne radon to home air quality

International Nuclear Information System (INIS)

Deb, A.K.

1994-01-01

Radon-222 is a member of the uranium decay chain and is formed from the decay of radium-226. Radon and its decay products emit alpha particles during the decay process. If radon is inhaled, alpha particles emitted from inhaled radon and its daughters increase the risk of lung cancer. Radon is soluble in water; thus when radon comes in contact with groundwater it dissolves. The radon concentration in groundwater may range from 100 pCi/L to 1,000,000 pCi/L. When water with a high radon level is used in the home, radon is released from the water to the air and thus can increase indoor air radon concentration. Considering the estimated health risk from radon in public water supply systems, EPA has proposed a maximum contaminant level (MCL) of 300 pCi/L for radon in public drinking water supplies. To address the health risks of radon in water and the proposed regulations, the American Water Works Association Research Foundation (AWWARF) initiated a study to determine the contribution of waterborne radon to radon levels in indoor household air

Preliminary study on the corrosion behavior of carbon steel in Horonobe groundwater environment

International Nuclear Information System (INIS)

Taniguchi, Naoki; Kogawa, Noritaka; Maeda, Kazuto

2006-08-01

It is necessary to understand the corrosion behavior of candidate overpack materials to plan the in-situ engineered barrier test at underground laboratory constructing at Horonobe and to design the overpacks suitable to Horonobe environment. The preliminary corrosion tests of carbon steel which is a candidate material for overpacks were carried out using artificial groundwater and actual groundwater sampled at Horonobe. As the results of anodic polarization experiments, the anodic polarization curves of carbon steel in buffer material were active dissolution type, and the corrosion type of carbon steel in Horonobe groundwater environment was expected to be general corrosion. The results of immersion test under air equilibrium condition showed that the degrees of corrosion localization were not exceeded the data obtained in previous studies. The trend of corrosion rates in buffer material under anaerobic condition were similar to the data obtained in previous studies. Based on the experimental results, it was confirmed that the corrosion assessment model and assumed corrosion rate in second progress report (H12 report) can be applied to the assessment for Horonobe groundwater condition. (author)

Residence times and mixing of water in river banks: implications for recharge and groundwater - surface water exchange

Science.gov (United States)

Unland, N. P.; Cartwright, I.; Cendón, D. I.; Chisari, R.

2014-02-01

The residence time of groundwater within 50 m of the Tambo River, South East Australia, has been estimated through the combined use of 3H and 14C. Groundwater residence times increase towards the Tambo River which implies a gaining river system and not increasing bank storage with proximity to the Tambo River. Major ion concentrations and δ2H and δ18O values of bank water also indicate that bank infiltration does not significantly impact groundwater chemistry under baseflow and post-flood conditions, suggesting that the gaining nature of the river may be driving the return of bank storage water back into the Tambo River within days of peak flood conditions. The covariance between 3H and 14C indicates the leakage and mixing between old (~17 200 yr) groundwater from a semi-confined aquifer and younger groundwater (bank storage, as rapid pressure propagation into the semi-confined aquifer during flooding will minimise bank infiltration. This study illustrates the complex nature of river groundwater interactions and the potential downfall in assuming simple or idealised conditions when conducting hydrogeological studies.

Numerical simulation of groundwater flow in LILW Repository site:I. Groundwater flow modeling

Energy Technology Data Exchange (ETDEWEB)

Park, Koung Woo; Ji, Sung Hoon; Kim, Chun Soo; Kim, Kyoung Su [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Kim, Ji Yeon [Korea Hydro and Nuclear Power Co. Ltd., Seoul (Korea, Republic of)

2008-12-15

Based on the site characterization works in a low and intermediate level waste (LILW) repository site, the numerical simulations for groundwater flow were carried out in order to understand the groundwater flow system of repository site. To accomplish the groundwater flow modeling in the repository site, the discrete fracture network (DFN) model was constructed using the characteristics of fracture zones and background fractures. At result, the total 10 different hydraulic conductivity(K) fields were obtained from DFN model stochastically and K distributions of constructed mesh were inputted into the 10 cases of groundwater flow simulations in FEFLOW. From the total 10 numerical simulation results, the simulated groundwater levels were strongly governed by topography and the groundwater fluxes were governed by locally existed high permeable fracture zones in repository depth. Especially, the groundwater table was predicted to have several tens meters below the groundwater table compared with the undisturbed condition around disposal silo after construction of underground facilities. After closure of disposal facilities, the groundwater level would be almost recovered within 1 year and have a tendency to keep a steady state of groundwater level in 2 year.

Estimation of Heavy Metal Contamination in Groundwater and Development of a Heavy Metal Pollution Index by Using GIS Technique.

Science.gov (United States)

Tiwari, Ashwani Kumar; Singh, Prasoon Kumar; Singh, Abhay Kumar; De Maio, Marina

2016-04-01

Heavy metal (Al, As, Ba, Cr, Cu, Fe, Mn, Ni, Se and Zn) concentration in sixty-six groundwater samples of the West Bokaro coalfield were analyzed using inductively coupled plasma-mass spectroscopy for determination of seasonal fluctuation, source apportionment and heavy metal pollution index (HPI). Metal concentrations were found higher in the pre-monsoon season as compared to the post-monsoon season. Geographic information system (GIS) tool was attributed to study the metals risk in groundwater of the West Bokaro coalfield. The results show that 94 % of water samples were found as low class and 6 % of water samples were in medium class in the post-monsoon season. However, 79 % of water samples were found in low class, 18 % in medium class and 3 % in high class in the pre-monsoon season. The HPI values were below the critical pollution index value of 100. The concentrations of Al, Fe, Mn, and Ni are exceeding the desirable limits in many groundwater samples in both seasons.

Effects and control of long-range transboundary air pollution. Report prepared within the framework of the Convention on Long-range Transboundary Air Pollution

International Nuclear Information System (INIS)

1995-01-01

This eleventh volume of the series of Air Pollution Studies, published under the auspices of the Executive Body for the Convention on Long-range Transboundary Air Pollution, contains the documents reviewed and approved for publication at the twelfth session of the Executive Body held at Geneva from 28 November to 1 December 1994. Part one focuses on the possible impact of acid deposition on the quality of groundwater in the ECE region. The objective of this report is to present an updated review of available knowledge on the possible impact of deposition of sulphur and nitrogen compounds on the status of groundwater, including a brief survey of recent research results in this field. It updates an earlier report on the effects of air pollutants on groundwater, prepared within the Convention (EB.AIR/WG.1/R.9). Part two is an executive summary of the 1993 Report on the Forest Condition in Europe (Forest Condition in Europe. Results of the 1993 Survey. 1994 Report, EC-UN/ECE, Brussels, Geneva, 1994). The report describes the results of both the national and the transnational surveys which are conducted annually within the International Cooperative Programme on the Assessment and Monitoring of Air Pollution Effects on Forests (ICP Forests) of the United Nations Economic Commission for Europe (ECE) and under European Community Council Regulation (EEC) 3528/86 on the protection of the Community's Forests against Atmospheric Pollution. Part three is a summary report on the options for further reduction of nitrogen oxide emissions from road heavy-duty vehicles (HDVs). This report is primarily focused on reduction options for road HDVs, but some of the technical measures reviewed can, however, also be applied to some non-road diesel engines, such as machinery in construction, agriculture or forestry

Physicochemical quality evaluation of groundwater and development of drinking water quality index for Araniar River Basin, Tamil Nadu, India.

Science.gov (United States)

Jasmin, I; Mallikarjuna, P

2014-02-01

Groundwater is the most important natural resource which cannot be optimally used and sustained unless its quality is properly assessed. In the present study, the spatial and temporal variations in physicochemical quality parameters of groundwater of Araniar River Basin, India were analyzed to determine its suitability for drinking purpose through development of drinking water quality index (DWQI) maps of the post- and pre-monsoon periods. The suitability for drinking purpose was evaluated by comparing the physicochemical parameters of groundwater in the study area with drinking water standards prescribed by the World Health Organization (WHO) and Bureau of Indian Standards (BIS). Interpretation of physicochemical data revealed that groundwater in the basin was slightly alkaline. The cations such as sodium (Na(+)) and potassium (K(+)) and anions such as bicarbonate (HCO3 (-)) and chloride (Cl(-)) exceeded the permissible limits of drinking water standards (WHO and BIS) in certain pockets in the northeastern part of the basin during the pre-monsoon period. The higher total dissolved solids (TDS) concentration was observed in the northeastern part of the basin, and the parameters such as calcium (Ca(2+)), magnesium (Mg(2+)), sulfate (SO4 (2-)), nitrate (NO3 (-)), and fluoride (F(-)) were within the limits in both the seasons. The hydrogeochemical evaluation of groundwater of the basin demonstrated with the Piper trilinear diagram indicated that the groundwater samples of the area were of Ca(2+)-Mg(2+)-Cl(-)-SO4 (2-), Ca(2+)-Mg(2+)-HCO3 (-) and Na(+)-K(+)-Cl(-)-SO4 (2-) types during the post-monsoon period and Ca(2+)-Mg(2+)-Cl(-)-SO4 (2-), Na(+)-K(+)-Cl(-)-SO4 (2-) and Ca(2+)-Mg(2+)-HCO3 (-) types during the pre-monsoon period. The DWQI maps for the basin revealed that 90.24 and 73.46% of the basin area possess good quality drinking water during the post- and pre-monsoon seasons, respectively.

Delineation of groundwater development potential zones in parts of marginal Ganga Alluvial Plain in South Bihar, Eastern India.

Science.gov (United States)

Saha, Dipankar; Dhar, Y R; Vittala, S S

2010-06-01

A part of the Gangetic Alluvial Plain covering 2,228 km(2), in the state of Bihar, is studied for demarcating groundwater development potential zones. The area is mainly agrarian and experiencing intensive groundwater draft to the tune of 0.12 million cubic metre per square kilometres per year from the Quaternary marginal alluvial deposits, unconformably overlain northerly sloping Precambrian bedrock. Multiparametric data on groundwater comprising water level, hydraulic gradient (pre- and post-monsoon), aquifer thickness, permeability, suitability of groundwater for drinking and irrigation and groundwater resources vs. draft are spatially analysed and integrated on a Geographical Information System platform to generate thematic layers. By integrating these layers, three zones have been delineated based on groundwater development potential. It is inferred that about 48% of the area covering northern part has high development potential, while medium and low development potential category covers 41% of the area. Further increase in groundwater extraction is not recommended for an area of 173 km(2), affected by over-exploitation. The replenishable groundwater resource available for further extraction has been estimated. The development potential enhances towards north with increase in thickness of sediments. Local deviations are due to variation of-(1) cumulative thickness of aquifers, (2) deeper water level resulting from localised heavy groundwater extraction and (3) aquifer permeability.

Isotopic characteristic of meteoric water and groundwater in Ahaggar massif (central Sahara)

International Nuclear Information System (INIS)

Saighi, O.; Michelot, J.L.; Filly, A.

2001-01-01

The mean contents of both oxygen-18 and deuterium in precipitation from the Ahaggar massif (central Sahara) are: δ 18 O = -3 per mille and 2 H = -15 per mille. The heterogeneity in meteoric events and the great scattering of these isotopic contents can be ascribed to the origins and the histories of air masses. The main contribution comes from the inflow of the Guinean monsoon during summer months. During winter, the N/W winds, arriving in the area from the Moroccan coast, provide some rains. The deuterium excess of these precipitation are up to +10 per mille, indicating that the air masses generating these rains are supplied by the recycling of the continental air moisture. Groundwater resources are produced in some little phreatic aquifers, which are recharged by sporadic wadi floods. Aquifer zones that are the most favourable are located in the valleys and occur as three overlying levels of unequal importance: the alluvial aquifer, the weathered zone of the underlying substratum and the deep aquifer of fissured basement. The alluvial aquifer contain weakly mineralised water (0.3 g/l). Their stable isotopes contents (δ 18 O∼ -2.7 per mille) and 14 C activity of them (> 100 pmc) are comparable to present meteoric water, allowing modern meteoric waters to be identified. The weathered zone groundwater's are more mineralised (0.8 g/l) and its isotopic contents (δ 18 O∼ -4.2 per mille) and intermediate radiocarbon activity, prove their old water component. The basement's groundwater are more mineralised (> 1 g/l) and their very depleted isotopic contents (δ 18 O∼ -9 per mille) diverge clearly from the present precipitation. Furthermore, the absence of 3 H and 14 C activity of them, prove an old heritage, resulting from recharge during the last humid episode of the Holocene. (author)

Air - water temperature relationships in the trout streams of southeastern Minnesota’s carbonate - sandstone landscape

Science.gov (United States)

Krider, Lori A.; Magner, Joseph A.; Perry, Jim; Vondracek, Bruce C.; Ferrington, Leonard C.

2013-01-01

Carbonate-sandstone geology in southeastern Minnesota creates a heterogeneous landscape of springs, seeps, and sinkholes that supply groundwater into streams. Air temperatures are effective predictors of water temperature in surface-water dominated streams. However, no published work investigates the relationship between air and water temperatures in groundwater-fed streams (GWFS) across watersheds. We used simple linear regressions to examine weekly air-water temperature relationships for 40 GWFS in southeastern Minnesota. A 40-stream, composite linear regression model has a slope of 0.38, an intercept of 6.63, and R2 of 0.83. The regression models for GWFS have lower slopes and higher intercepts in comparison to surface-water dominated streams. Regression models for streams with high R2 values offer promise for use as predictive tools for future climate conditions. Climate change is expected to alter the thermal regime of groundwater-fed systems, but will do so at a slower rate than surface-water dominated systems. A regression model of intercept vs. slope can be used to identify streams for which water temperatures are more meteorologically than groundwater controlled, and thus more vulnerable to climate change. Such relationships can be used to guide restoration vs. management strategies to protect trout streams.

Exploring Hydrofluorocarbons as Groundwater Age Tracers (Invited)

Science.gov (United States)

Haase, K. B.; Busenberg, E.; Plummer, L. N.; Casile, G.; Sanford, W. E.

2013-12-01

Groundwater dating tracers are an essential tool for analyzing hydrologic conditions in groundwater systems. Commonly used tracers for dating post-1940's groundwater include sulfur hexafluoride (SF6), chlorofluorocarbons (CFCs), 3H-3He, and other isotopic tracers (85Kr, δ2H and δ18O isotopes, etc.). Each tracer carries a corresponding set of advantages and limitations imposed by field, analytical, and interpretive methods. Increasing the number available tracers is appealing, particularly if they possess inert chemical properties and unique temporal emission histories from other tracers. Atmospherically derived halogenated trace gases continue to hold untapped potential for new tracers, as they are generally inert and their emission histories are well documented. SF5CF3, and CFC-13 were previously shown to have application as dating tracers, though their low mixing ratios and low solubility require large amounts of water to be degassed for their quantification. Two related groups of compounds, hydrochlorofluorocarbons (HCFCs) and hydrofluorocarbons (HFCs) are hypothesized to be potential age tracers, having similar mixing ratios to the CFCs and relatively high solubility. However, these compounds yield gas chromatography electron capture detector (GC-ECD) responses that are 10-2 -10-5 less than CFC-12, making purge and trap or field stripping GC-ECD approaches impractical. Therefore, in order to use dissolved HCFCs and HFCs as age tracers, different approaches are needed. To solve this problem, we developed an analytical method that uses an atomic emission detector (GC-AED) in place of an ECD to detect fluorinated compounds. In contrast to the ECD, the AED is a universally sensitive, highly linear, elementally specific detector. The new GC-AED system is being used to measure chlorodifluoromethane (HCFC-22), 1,1,1,2-tetrafluoroethane (HFC-134a), and other fluorinated compounds in one liter water samples to study their potential as age dating tracers. HCFC-22 is a

Features of groundwater pollution and its relation to overexploitation of groundwater in Shijiazhuang city

International Nuclear Information System (INIS)

Guo Yonghai; Wang Zhiming; Liu Shufen; Li Ping

2005-01-01

The groundwater pollution in Shijiazhuang city is characterized by an excess of some components and parameters over permitted values. The main pollutants are originated from the city sewage which is quite typical for groundwater pollution in many cities of China. On the basis of agonizingly features of groundwater pollution, the relationship between the groundwater pollution and the groundwater overexploitation is discussed in this paper, and the mechanism of intensifying the pollution by overexploitation has been revealed. Finally, it is proposed that the overexploitation of groundwater is an important inducing factor leading to the groundwater pollution in cities. (authors)

Suburban heat island effect in groundwater energy utilisation in Nordic climate - case study

Science.gov (United States)

Arola, Teppo

2017-04-01

significantly. Similarly groundwater cooling potential decrease but groundwater still constitutes an effective cooling energy reservoir because groundwater temperatures remain below air temperatures during the summer and the COP for cooling is extremely high. In Asko site SUHI effect has been recognised from the beginning of the project. Energy and economical calculations are based on anthropogenic influence to ground temperatures. More research, i.e. detailed groundwater thermogeological modelling, is needed to design the multi well ATES system based on elevated groundwater temperatures.

Identification of manganese as a toxicant in a groundwater treatment system: Addressing naturally occurring toxicants

International Nuclear Information System (INIS)

Goodfellow, W. Jr.; Sohn, V.; Richey, M.; Yost, J.

1995-01-01

Effluent from a groundwater remediation system at a bulk oil storage and distribution terminal has been chronically toxic to Ceriodaphnia dubia. The remediation system was designed in response to a hydrocarbon plume in the area of the terminal. The remediation system consists of a series of groundwater recovery wells and groundwater intercept trench systems with groundwater treatment and phased-separated hydrocarbon recovery systems. The groundwater treatment and petroleum recovery systems consist of oil/water separators, product recovery tanks, air strippers, filters, and carbon adsorption units. The characteristics of this effluent are low total suspended solids, total dissolved solids, and hardness concentrations as well as meeting stringent NPDES permit requirements for lead, copper, zinc, mercury, total petroleum hydrocarbons, and BTEX. Additional priority pollutant evaluations revealed no compounds of concern. Performance of a Toxicity identification Evaluation (TIE) indicated that manganese was the principle toxicant in the effluent. Manganese is a naturally occurring constituent in this groundwater source and is not added to the treatment system. This paper will present the results of the TIE with a discussion of treatability/control options for manganese control at this facility. Recommendations for addressing naturally occurring toxicants that are not a result of the facility's operations will also be presented

Groundwater dating by means of isotopes

International Nuclear Information System (INIS)

Johansson, Barbro

1980-08-01

A short review is given of method for dating old groundwater by isotopetechniques. The carbon-14 method is then treated in detail; Carbon dioxide, released by root respiration of plants, and by decomposition of organic matter in the soil, is dissolved in soil water. The production of carbon dioxide in the root zone is high and the 14 C/ 12 C ratio is therefore assumed to be the same as in the plants. The residence time of water in the groundwater zone may then be computed, according to the laws of radioactive decay. No attempts have been made to compute the changes in the carbon-14 content of the soil air due to weathering. To do this, one would need to consider diffusion of gaseous carbon dioxide into and out of the soil. The amount of carbon entering the water through weathering in the groundwater zone may be compute if certain assumptions are made. To know if these assumptions are valid for the water of a special area, detailed knowledge about the area is required. In this report, an attempt is made to follow the changes in the composition of the water as the water moves through the ground. The differentiated equilibrium equations of the carbon dioxide system and the ionic balance are used for the calculations. It is assumed that when calcite is present in the ground, weathering of other minerals may be neglected. In order to test its usefulness, the method has been tried on groundwater from a borehole in Kraakemaala, Sweden. The results are very much dependent on the values of some of the parameters used in the calculations. The σ 13 C values especially have a great influence on the calculated age. As long as additional information on conditions at different depth remains unavailable, it seems impossible to determine the age of water with any accuracy. Only a range, which sometimes embraces several thousand years, can be given. A good aid to a better estimate of the age would be obtained if samples of water along a flow path were available. One way to get such

A Regional Groundwater Observatory to Enhance Analysis and Management of Water Resources

Science.gov (United States)

Yoder, A. M.; Maples, S.; Hatch, N. R.; Fogg, G. E.

2017-12-01

Timely, effective management of groundwater often does not happen because timely information on the state of the groundwater system is seldom available. A groundwater observatory for monitoring real-time groundwater level fluctuations is being developed in the American-Cosumnes groundwater system of Sacramento County, California. The observatory records the consequences of complex interplay between pumpage, recharge, drought, and floods in the context of a heterogeneous stratigraphic framework that has been extensively characterized with more than 1,100 well logs. Preliminary results show increases in recharge caused by removal of flood control levees to allow more frequent floodplain inundation as well as consequences of the 2012-16 drought followed by the wet winter of 2016-17. Comparison of recharge rates pre- and post-levee breach restoration show significant increases in recharge, despite the presence of fine-grained floodplain soils. Estimated total recharge corresponded closely with the frequency and magnitude of flood events in any given water year. The lowest value calculated for estimated recharge was from 2012-2013, 490 +/- 220 ac-ft (0.65 +/- 0.29 ac-ft per acre). The highest estimated recharge value calculated was for the 2015-2016 water year and was 3180 +/- 1430 ac-ft (2.83 +/- 1.27 ac-ft per acre). These preliminary numbers will be updated with more comprehensive estimates based on a full analysis of the 2016-17 data. The increase in data transfer efficiency afforded by the observatory can be widely used by the many parties reliant on Central Valley groundwater and can serve as a model for real-time data collection in support of California's Sustainable Groundwater Management Act, passed in 2014.

Work plan for the Oak Ridge National Laboratory groundwater program: Continuous groundwater collection

International Nuclear Information System (INIS)

1995-08-01

The continuous collection of groundwater data is a basic and necessary part of Lockeheed Martin Energy Systems' ORNL Environmental Restoration Area-Wide Groundwater Program. Continuous groundwater data consist primarily of continually recorded groundwater levels, and in some instances, specific conductivity, pH, and/or temperature measurements. These data will be collected throughout the ORNL site. This Work Plan (WP) addresses technical objectives, equipment requirements, procedures, documentation requirements, and technical instructions for the acquisition of the continuous groundwater data. Intent of this WP is to provide an approved document that meets all the necessary requirements while retaining the flexibility necessary to effectively address ORNL's groundwater problems

Prediction of uranium and technetium sorption during titration of contaminated acidic groundwater

Energy Technology Data Exchange (ETDEWEB)

Zhang Fan, E-mail: zhangfan@itpcas.ac.cn [Institute of Tibetan Plateau Research, Chinese Academy of Sciences, 18 Shuangqing Road, P.O. Box 2871, Beijing 100085 (China); Parker, Jack C. [Department of Civil and Environmental Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Brooks, Scott C.; Watson, David B. [Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6038 (United States); Jardine, Philip M. [Biosystems Engineering and Soil Science Department, University of Tennessee, Knoxville, TN 37996 (United States); Gu, Baohua [Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6038 (United States)

2010-06-15

This study investigates uranium and technetium sorption onto aluminum and iron hydroxides during titration of acidic groundwater. The contaminated groundwater exhibits oxic conditions with high concentrations of NO{sub 3}{sup -}, SO{sub 4}{sup 2-}, U, Tc, and various metal cations. More than 90% of U and Tc was removed from the aqueous phase as Al and Fe precipitated above pH 5.5, but was partially resolublized at higher pH values. An equilibrium hydrolysis and precipitation reaction model adequately described variations in aqueous concentrations of metal cations. An anion exchange reaction model was incorporated to simulate sulfate, U and Tc sorption onto variably charged (pH-dependent) Al and Fe hydroxides. Modeling results indicate that competitive sorption/desorption on mixed mineral phases needs to be considered to adequately predict U and Tc mobility. The model could be useful for future studies of the speciation of U, Tc and co-existing ions during pre- and post-groundwater treatment practices.

Y-12 Plant Groundwater Protection Program: Groundwater and surface water sampling and analysis plan for Calendar Year 1998

International Nuclear Information System (INIS)

1997-09-01

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 1998 at the Department of Energy (DOE) Y-12 Plant. These monitoring activities are managed by the Y-12 Plant Environmental Compliance Organization through the Y-12 Plant Groundwater Protection Program (GWPP). Groundwater and surface water monitoring during CY 1998 will be performed in three hydrogeologic regimes at the Y-12 Plant: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located within Bear Creek Valley, and the Chestnut Ridge Regime is located south of the Y-12 Plant. Groundwater and surface water monitoring will be performed during CY 1998 to comply with: (1) requirements specified in Resource Conservation and Recover Act (RCRA) post-closure permits regarding RCRA corrective action monitoring and RCRA detection monitoring; (2) Tennessee Department of Environment and Conservation regulations governing detection monitoring at nonhazardous solid waste management facilities; and (3) DOE Order 5400.1 surveillance monitoring and exit pathway monitoring. Data from some of the sampling locations in each regime will be used to meet the requirements of more than one of the monitoring drivers listed above. Modifications to the CY 1998 monitoring program may be necessary during implementation. For example, changes in regulatory requirements may alter the parameters specified for selected monitoring wells, or wells could be removed from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 Plant GWPP manager and documented as addenda to this sampling and analysis plan

Y-12 Plant Groundwater Protection Program Groundwater and Surface Water sampling and Analysis Plan for Calendar Year 2000

International Nuclear Information System (INIS)

1999-01-01

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2000 at the U.S. Department of Energy (DOE) Y-12 Plant that will be managed by tie Y-12 Plant Groundwater Protection Program (GWPP). Groundwater and surface water monitoring during CY 2000 will be performed in three hydrogeologic regimes at the Y-12 Plant: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of the Y-12 Plant (Figure 1). Groundwater and surface water monitoring performed under the auspices of the Y-12 Plant GWPP during CY 2000 will comply with: Tennessee Department of Environment and Conservation regulations governing detection monitoring at nonhazardous Solid Waste Disposal Facilities (SWDF); and DOE Order 5400.1 surveillance monitoring and exit pathway/perimeter monitoring. Some of the data collected for these monitoring drivers also will be used to meet monitoring requirements of the Integrated Water Quality Program, which is managed by Bechtel Jacobs Company LLC. Data from five wells that are monitored for SWDF purposes in the Chestnut Ridge Regime will be used to comply with requirements specified in the Resource Conservation and Recovery Act post closure permit regarding corrective action monitoring. Modifications to the CY 2000 monitoring program may be necessary during implementation. Changes in regulatory or programmatic requirements may alter the analytes specified for selected monitoring wells, or wells could be added or removed from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 Plant GWPP manager and documented as addenda to this sampling and analysis plan

Hydrochemical and Isotopic Investigation of Groundwater in the Hammamet-Nabeul Aquifer System, North-Eastern Tunisia

Energy Technology Data Exchange (ETDEWEB)

Ben Moussa, A.; Zouari, K. [Laboratory of Radio-Analysis and Environment, ENIS, Sfax (Tunisia); Kurttas, T. [Isotope Hydrology Section, International Atomic Energy Agency, Vienna (Austria)

2013-07-15

The combination of major element geochemistry, stable ({delta}{sup 18}O, {delta}{sup 2}H) and radioactive ({sup 3}H, {sup 14}C) isotopes has provided a comprehensive understanding of the natural and anthropogenic processes that control groundwater mineralization as well as the sources of different groundwater bodies within the Hammamet-Nabeul unconfined aquifer (Cap Bon peninsula, northeastern Tunisia). The geochemical examination shows the dominance of Na-Cl and Ca-SO{sub 4} water types resulting from the dissolution of halite and gypsum, the dedolomitization and the cation exchange process. Additionally, the return flow process in relation with the long term flood irrigation practice contributes to the mineralization by producing high amounts of nitrate. The stable isotope signatures reveal the existence of two groundwater groups. The non-evaporated groundwaters with relatively depleted contents, reflecting recharge at higher altitudes; and evaporated groundwaters with enriched contents highlighting the influence of return flow of irrigation waters. Tritium contents in these two groups provide evidence of the presence of pre- 1950 and post-1960 recharge periods. Carbon-14 activities in shallow wells, in spite of their contamination by organic {sup 14}C, confirm the recent origin of the groundwaters in the study area. (author)

Groundwater quality assessment plan for single-shell tank waste management Area U at the Hanford Site

International Nuclear Information System (INIS)

FN Hodges; CJ Chou

2000-01-01

Waste Management Area U (WMA U) includes the U Tank Farm, is currently regulated under RCRA interim-status regulations, and is scheduled for closure probably post-2030. Groundwater monitoring has been under an evaluation program that compared general contaminant indicator parameters from downgradient wells to background values established from upgradient wells. One of the indicator parameters, specific conductance, exceeded its background value in one downgradient well triggering a change from detection monitoring to a groundwater quality assessment program. The objective of the first phase of this assessment program is to determine whether the increased concentrations of nitrate and chromium in groundwater are from WMA U or from an upgradient source. Based on the results of the first determination, if WMA U is not the source of contamination, then the site will revert to detection monitoring. If WMA U is the source, then a second part of the groundwater quality assessment plan will be prepared to define the rate and extent of migration of contaminants in the groundwater and their concentrations

River-groundwater connectivity in a karst system, Wellington, New South Wales, Australia

Science.gov (United States)

Keshavarzi, Mohammadreza; Baker, Andy; Kelly, Bryce F. J.; Andersen, Martin S.

2017-03-01

The characterization of river-aquifer connectivity in karst environments is difficult due to the presence of conduits and caves. This work demonstrates how geophysical imaging combined with hydrogeological data can improve the conceptualization of surface-water and groundwater interactions in karst terrains. The objective of this study is to understand the association between the Bell River and karst-alluvial aquifer at Wellington, Australia. River and groundwater levels were continuously monitored, and electrical resistivity imaging and water quality surveys conducted. Two-dimensional resistivity imaging mapped the transition between the alluvium and karst. This is important for highlighting the proximity of the saturated alluvial sediments to the water-filled caves and conduits. In the unsaturated zone the resistivity imaging differentiated between air- and sediment-filled karst features, and in the saturated zone it mapped the location of possible water- and sediment-filled caves. Groundwater levels are dynamic and respond quickly to changes in the river stage, implying that there is a strong hydraulic connection, and that the river is losing and recharging the adjacent aquifer. Groundwater extractions (1,370 ML, megalitres, annually) from the alluvial aquifer can cause the groundwater level to fall by as much as 1.5 m in a year. However, when the Bell River flows after significant rainfall in the upper catchment, river-leakage rapidly recharges the alluvial and karst aquifers. This work demonstrates that in complex hydrogeological settings, the combined use of geophysical imaging, hydrograph analysis and geochemical measurements provide insights on the local karst hydrology and groundwater processes, which will enable better water-resource and karst management.

Groundwater sustainability and groundwater/surface-water interaction in arid Dunhuang Basin, northwest China

Science.gov (United States)

Lin, Jingjing; Ma, Rui; Hu, Yalu; Sun, Ziyong; Wang, Yanxin; McCarter, Colin P. R.

2018-03-01

The Dunhuang Basin, a typical inland basin in northwestern China, suffers a net loss of groundwater and the occasional disappearance of the Crescent Lake. Within this region, the groundwater/surface-water interactions are important for the sustainability of the groundwater resources. A three-dimensional transient groundwater flow model was established and calibrated using MODFLOW 2000, which was used to predict changes to these interactions once a water diversion project is completed. The simulated results indicate that introducing water from outside of the basin into the Shule and Danghe rivers could reverse the negative groundwater balance in the Basin. River-water/groundwater interactions control the groundwater hydrology, where river leakage to the groundwater in the Basin will increase from 3,114 × 104 m3/year in 2017 to 11,875 × 104 m3/year in 2021, and to 17,039 × 104 m3/year in 2036. In comparison, groundwater discharge to the rivers will decrease from 3277 × 104 m3/year in 2017 to 1857 × 104 m3/year in 2021, and to 510 × 104 m3/year by 2036; thus, the hydrology will switch from groundwater discharge to groundwater recharge after implementing the water diversion project. The simulation indicates that the increased net river infiltration due to the water diversion project will raise the water table and then effectively increasing the water level of the Crescent Lake, as the lake level is contiguous with the water table. However, the regional phreatic evaporation will be enhanced, which may intensify soil salinization in the Dunhuang Basin. These results can guide the water allocation scheme for the water diversion project to alleviate groundwater depletion and mitigate geo-environmental problem.

California GAMA Special Study. Development of a Capability for the Analysis of Krypton-85 in Groundwater Samples

Energy Technology Data Exchange (ETDEWEB)

Visser, Ate [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bibby, Richard K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Moran, Jean E. [California State Univ. (CalState), Long Beach, CA (United States); Singleton, Michael J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Esser, Bradley K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2015-06-01

A capability for the analysis of krypton-85 (⁸⁵Kr) in groundwater samples was developed at LLNL. Samples are collected by extracting gas from 2000-4000 L of groundwater at the well, yielding approximately 0.2 cm³ STP krypton. Sample collection takes 1 to 4 hours. Krypton is purified in the laboratory using a combination of molecular sieve and activated charcoal traps, and transferred to a liquid scintillation vial. The ⁸⁵Kr activity is measured by liquid scintillation on a Quantulus 1220 liquid scintillation counter from PerkinElmer. The detection limit for a typical 0.2 cm³Kr sample size is 11% of the present day activity in air, corresponding to the decay corrected activity in air in 1987. The typical measurement uncertainty is below 10% for recently recharged samples. Six groundwater samples were collected, purified and counted. ⁸⁵Kr was not detected in any of the samples counted at LLNL. ⁸⁵Kr was detected by the low level counting laboratory of Bern University in all samples between 1.5 and 6.6 decays per minute per cm³ krypton, corresponding to decay corrected activities in air between 1971 and 1985. The new capability is an excellent complement to tritium-helium, expanding the existing suite of age dating tools available to the GAMA program (³⁵S, ³H/³He, ¹⁴C and radiogenic helium). ⁸⁵Kr can replace ³H/³He in settings where ³H/³He ages are impossible to determine (for example where terrigenic helium overwhelms tritiogenic helium) and provides additional insight into travel time distributions in complex mixed groundwater systems.

Packaging of Post Acclimatized Somatic Embryogenesis Cocoa Plantlet (Theobroma cacao L.

Directory of Open Access Journals (Sweden)

Soedarsianto Soedarsianto

2009-05-01

Full Text Available Clonal plants that produced by somatic embryogenesis technique is one of the best choice to produce supperior clonal cacao (Theobroma cacao L. planting materials. The somatic embryogenesis technique is a possible way for massive propagation, the outcome is true to type plants, the architecture similarity that the seedlings but there is not segregation like seedlings plants. At present mass production started of plantlets production until post-acclimatized plantlets of somatic embryogenesis cocoa was done at Indonesian Coffee and Cocoa Research Institute. Distribution system of the planting materials to whole areas in form of as up-rooted post-acclimatized plantlet. Some problems identified to reduce probability of decreasing viability of up-rooted post-acclimatized plantlets and one of them is extreme internal water deficit. This research investigate of the influece storage condition (air tight and non-air tight and box storage (mica plastic and cardboardbox. The first experiment result show, there is no significant different between mica plastic and cardboard box usage for storage of post-acclimatized cocoa pantlet. Viability of up-rooted post acclimatized cocoa plantlet influenced exactly by air tight and non-air tight storage condition. Air tight storage condition have better viability of up-rooted post acclimatised (81,58% than non-air tight storage condition (65,00%. Leaf sanasence on air tight storage condition (10,33% lower than non-air tight storage (32,58%. There is not significantly on volume storage per plantlet between 4.416 cm3 and 12.600 cm3. Relationship between fallen leaves and cocoa planlet viability follow negative linear correlation y = -1,4719x + 104,88 (R2 = 0,9772. The second experiment treatment showed that maximal storage periode of post cclimatized cocoa plantlet just until 6 days stored (97% and not significant with 3 days one. Viability of post acclimatized cocoa plantlet decreased after 6 days storage period

Site scale groundwater flow in Olkiluoto

International Nuclear Information System (INIS)

Loefman, J.

1999-03-01

Groundwater flow modelling on the site scale has been an essential part of site investigation work carried out at different locations since 1986. The objective of the modelling has been to provide results that characterise the groundwater flow conditions deep in the bedrock. The main result quantities can be used for evaluation of the investigation sites and of the preconditions for safe final disposal of spent nuclear fuel. This study represents the latest modelling effort at Olkiluoto (Finland), and it comprises the transient flow analysis taking into account the effects of density variations and the repository as well as the post-glacial land uplift. The analysis is performed by means of numerical finite element simulation of coupled and transient groundwater flow and solute transport carried out up to 10000 years into the future. This work provides also the results for the site-specific data needs for the block scale groundwater flow modelling at Olkiluoto. Conceptually the fractured bedrock is divided into hydraulic units: the planar fracture zones and the remaining part of the bedrock. The equivalent-continuum (EC) model is applied so that each hydraulic unit is treated as a homogeneous and isotropic continuum with representative average characteristics. All the fracture zones are modelled explicitly and represented by two-dimensional finite elements. A site-specific simulation model for groundwater flow and solute transport is developed on the basis of the latest hydrogeological and hydrogeochemical field investigations at Olkiluoto. The present groundwater table and topography together with a mathematical model describing the land uplift at the Olkiluoto area are employed as a boundary condition at the surface of the model. The overall flow pattern is mostly controlled by the local variations in the topography. Below the island of Olkiluoto the flow direction is mostly downwards, while near the shoreline and below the sea water flows horizontally and

Site scale groundwater flow in Haestholmen

Energy Technology Data Exchange (ETDEWEB)

Loefman, J. [VTT Energy, Espoo (Finland)

1999-05-01

Groundwater flow modelling on the site scale has been an essential part of site investigation work carried out at different locations since 1986. The objective of the modelling has been to provide results that characterise the groundwater flow conditions deep in the bedrock. The main result quantities can be used for evaluation of the investigation sites and of the preconditions for safe final disposal - of spent nuclear fuel. This study represents the groundwater flow modelling at Haestholmen, and it comprises the transient flow analysis taking into account the effects of density variations and the repository as well as the post-glacial land uplift. The analysis is performed by means of numerical finite element simulation of coupled and transient groundwater flow and solute transport carried out up to 10000 years into the future. This work provides also the results for the site-specific data needs for the block scale groundwater flow modelling at Haestholmen. Conceptually the fractured bedrock is divided into hydraulic units: the planar fracture zones and the remaining part of the bedrock. The equivalent-continuum (EC) model is applied so that each hydraulic unit is treated as a homogeneous and isotropic continuum with representative average characteristics. All the fracture zones are modelled explicitly and represented by two-dimensional finite elements. A site-specific simulation model for groundwater flow and solute transport is developed on the basis of the latest hydrogeological and hydrogeochemical field investigations at Haestholmen. The present topography together with a mathematical model describing the land uplift at the Haestholmen area are employed as a boundary condition at the surface of the model. The overall flow pattern is mostly controlled by the local variations in the topography and by the highly transmissive fracture zones. Near the surface the flow spreads out to offshore and to the lower areas of topography in all directions away from

Site scale groundwater flow in Olkiluoto

Energy Technology Data Exchange (ETDEWEB)

Loefman, J. [VTT Energy, Espoo (Finland)

1999-03-01

Groundwater flow modelling on the site scale has been an essential part of site investigation work carried out at different locations since 1986. The objective of the modelling has been to provide results that characterise the groundwater flow conditions deep in the bedrock. The main result quantities can be used for evaluation of the investigation sites and of the preconditions for safe final disposal of spent nuclear fuel. This study represents the latest modelling effort at Olkiluoto (Finland), and it comprises the transient flow analysis taking into account the effects of density variations and the repository as well as the post-glacial land uplift. The analysis is performed by means of numerical finite element simulation of coupled and transient groundwater flow and solute transport carried out up to 10000 years into the future. This work provides also the results for the site-specific data needs for the block scale groundwater flow modelling at Olkiluoto. Conceptually the fractured bedrock is divided into hydraulic units: the planar fracture zones and the remaining part of the bedrock. The equivalent-continuum (EC) model is applied so that each hydraulic unit is treated as a homogeneous and isotropic continuum with representative average characteristics. All the fracture zones are modelled explicitly and represented by two-dimensional finite elements. A site-specific simulation model for groundwater flow and solute transport is developed on the basis of the latest hydrogeological and hydrogeochemical field investigations at Olkiluoto. The present groundwater table and topography together with a mathematical model describing the land uplift at the Olkiluoto area are employed as a boundary condition at the surface of the model. The overall flow pattern is mostly controlled by the local variations in the topography. Below the island of Olkiluoto the flow direction is mostly downwards, while near the shoreline and below the sea water flows horizontally and

An early warning system for groundwater pollution based on the assessment of groundwater pollution risks.

Science.gov (United States)

Zhang, Weihong.; Zhao, Yongsheng; Hong, Mei; Guo, Xiaodong

2009-04-01

Groundwater pollution usually is complex and concealed, remediation of which is difficult, high cost, time-consuming, and ineffective. An early warning system for groundwater pollution is needed that detects groundwater quality problems and gets the information necessary to make sound decisions before massive groundwater quality degradation occurs. Groundwater pollution early warning were performed by considering comprehensively the current groundwater quality, groundwater quality varying trend and groundwater pollution risk . The map of the basic quality of the groundwater was obtained by fuzzy comprehensive evaluation or BP neural network evaluation. Based on multi-annual groundwater monitoring datasets, Water quality state in sometime of the future was forecasted using time-sequenced analyzing methods. Water quality varying trend was analyzed by Spearman's rank correlative coefficient.The relative risk map of groundwater pollution was estimated through a procedure that identifies, cell by cell,the values of three factors, that is inherent vulnerability, load risk of pollution source and contamination hazard. DRASTIC method was used to assess inherent vulnerability of aquifer. Load risk of pollution source was analyzed based on the potential of contamination and pollution degree. Assessment index of load risk of pollution source which involves the variety of pollution source, quantity of contaminants, releasing potential of pollutants, and distance were determined. The load risks of all sources considered by GIS overlay technology. Early warning model of groundwater pollution combined with ComGIS technology organically, the regional groundwater pollution early-warning information system was developed, and applied it into Qiqiha'er groundwater early warning. It can be used to evaluate current water quality, to forecast water quality changing trend, and to analyze space-time influencing range of groundwater quality by natural process and human activities. Keywords

Assessing regional groundwater stress for nations using multiple data sources with the groundwater footprint

International Nuclear Information System (INIS)

Gleeson, Tom; Wada, Yoshihide

2013-01-01

Groundwater is a critical resource for agricultural production, ecosystems, drinking water and industry, yet groundwater depletion is accelerating, especially in a number of agriculturally important regions. Assessing the stress of groundwater resources is crucial for science-based policy and management, yet water stress assessments have often neglected groundwater and used single data sources, which may underestimate the uncertainty of the assessment. We consistently analyze and interpret groundwater stress across whole nations using multiple data sources for the first time. We focus on two nations with the highest national groundwater abstraction rates in the world, the United States and India, and use the recently developed groundwater footprint and multiple datasets of groundwater recharge and withdrawal derived from hydrologic models and data synthesis. A minority of aquifers, mostly with known groundwater depletion, show groundwater stress regardless of the input dataset. The majority of aquifers are not stressed with any input data while less than a third are stressed for some input data. In both countries groundwater stress affects agriculturally important regions. In the United States, groundwater stress impacts a lower proportion of the national area and population, and is focused in regions with lower population and water well density compared to India. Importantly, the results indicate that the uncertainty is generally greater between datasets than within datasets and that much of the uncertainty is due to recharge estimates. Assessment of groundwater stress consistently across a nation and assessment of uncertainty using multiple datasets are critical for the development of a science-based rationale for policy and management, especially with regard to where and to what extent to focus limited research and management resources. (letter)

Saline groundwater in crystalline bedrock

International Nuclear Information System (INIS)

Lampen, P.

1992-11-01

The State-of-art report describes research made on deep saline groundwaters and brines found in crystalline bedrock, mainly in site studies for nuclear waste disposal. The occurrence, definitions and classifications of saline groundwaters are reviewed with a special emphasis on the different theories concerning the origins of saline groundwaters. Studies of the saline groundwaters in Finland and Sweden have been reviewed more thoroughly. Also the mixing of different bodies of groundwaters, observations of the contact of saline groundwaters and permafrost, and the geochemical modelling of saline groundwaters as well as the future trends of research have been discussed. (orig.)

Thermal Removal of Tritium from Concrete and Soil to Reduce Groundwater Impacts - 13197

Energy Technology Data Exchange (ETDEWEB)

Jackson, Dennis G. [Savannah River National Laboratory, Building 773-42A, Aiken, South Carolina 29808 (United States); Blount, Gerald C. [Savannah River Nuclear Solutions (United States); Wells, Leslie H.; Cardoso, Joao E.; Kmetz, Thomas F.; Reed, Misty L. [U.S Department of Energy-Savannah River Site (United States)

2013-07-01

Legacy heavy-water moderator operations at the Savannah River Site (SRS) have resulted in the contamination of equipment pads, building slabs, and surrounding soil with tritium. At the time of discovery the tritium had impacted the shallow (< 3-m) groundwater at the facility. While tritium was present in the groundwater, characterization efforts determined that a significant source remained in a concrete slab at the surface and within the associated vadose zone soils. To prevent continued long-term impacts to the shallow groundwater a CERCLA non-time critical removal action for these source materials was conducted to reduce the leaching of tritium from the vadose zone soils and concrete slabs. In order to minimize transportation and disposal costs, an on-site thermal treatment process was designed, tested, and implemented. The on-site treatment consisted of thermal detritiation of the concrete rubble and soil. During this process concrete rubble was heated to a temperature of 815 deg. C (1,500 deg. F) resulting in the dehydration and removal of water bound tritium. During heating, tritium contaminated soil was used to provide thermal insulation during which it's temperature exceeded 100 deg. C (212 deg. F), causing drying and removal of tritium. The thermal treatment process volatiles the water bound tritium and releases it to the atmosphere. The released tritium was considered insignificant based upon Clean Air Act Compliance Package (CAP88) analysis and did not exceed exposure thresholds. A treatability study evaluated the effectiveness of this thermal configuration and viability as a decontamination method for tritium in concrete and soil materials. Post treatment sampling confirmed the effectiveness at reducing tritium to acceptable waste site specific levels. With American Recovery and Reinvestment Act (ARRA) funding three additional treatment cells were assembled utilizing commercial heating equipment and common construction materials. This provided a

Identification of Green Rust in Groundwater

DEFF Research Database (Denmark)

Christiansen, Bo C.; Balic Zunic, Tonci; Dideriksen, Knud

2009-01-01

to air. In this paper, we present a sampling method for capturing green rust so it is not oxidized. We then we used the method to identify the compound in a groundwater sample taken below the water table from fractures in granite. X-ray diffraction patterns were weak, but clearly identical to those......Green rust, a family of Fe(II),Fe(III) layered double hydroxides, is believed to be present in environments close to the Fe(II)/Fe(III) transition zone. Attempts to identify members of this family in nature have proven difficult because the material is oxidized after only a few minutes exposure...

Field demonstration of ex situ biological treatability of contaminated groundwater at the Strachan gas plant

International Nuclear Information System (INIS)

Kurz, M.D.; Stepan, D.J.

1997-03-01

A multi-phase study was conducted to deal with the issues of groundwater and soil contamination by sour gas processing plants in Alberta. Phase One consisted of a review of all soil and groundwater monitoring data submitted to Alberta Environment by sour gas plants in accordance with the Canadian Clean Water Act. The current phase involves the development, evaluation and demonstration of selected remediation technologies to address subsurface contamination of sediments and groundwater at sour gas treatment plants with special attention to the presence of natural gas condensate in the subsurface. Results are presented from a pilot-scale biological treatability test that was performed at the Gulf Strachan Natural Gas Processing Plant in Rocky Mountain House, Alberta, where contaminated groundwater from the plant was being pumped to the surface through many recovery wells to control contaminant migration. The recovered groundwater was directed to a pump-and-treat system that consisted of oil-water separation, iron removal, hardness removal, and air stripping, before being reinjected. The pilot-scale biological treatability testing was conducted to evaluate process stability in treating groundwater without pretreatment for iron and hardness reduction and to evaluate the removal of organic contaminants. Results of a groundwater characterization analysis are discussed. Chemical characteristics of the groundwater at the Strachan Gas Plant showed that an ex situ remediation technology would address the dissolved volatile and semi-volatile organic contamination from natural gas condensates, as well as the nitrogenous compounds resulting from the use of amine-based process chemicals. 4 refs., 5 tabs., 4 figs

Cost and Performance Report - Use of Cometabolic Air Sparging to Remediate Chloroethene-Contaminated Groundwater Aquifers

National Research Council Canada - National Science Library

Magar, Victor

2001-01-01

...) process at the McClellan National Test Site, California. The purpose of the demonstration was to evaluate the effectiveness of and costs associated with CAS for removal of chlorinated aromatic hydrocarbons (CAHs) from groundwater...

Spatial distribution of uranium in groundwater around proposed NPP site at Kovvada Andhra Pradesh

International Nuclear Information System (INIS)

Sahoo, S.K.; Lenka, P.; Patra, A.C.; Tripathi, R.M.; Rama Rao, D.; Yungndhar, M.; Vinod Kumar, A.

2018-01-01

Uranium is the basic nuclear fuel of the present nuclear power programme. To meet the demand of electrical energy, it is proposed for establishment of two atomic power stations (2 x 1000 MW LWR) at Kovvada, Ranasthalam mandal of Srikakulam district of Andhra Pradesh. It is mandatory to generate the prevailing baseline levels of natural and manmade radionuclides along with conventional water and air quality parameters of the site. Under the baseline study, a comprehensive groundwater quality of the site is taken to establish the radionuclide levels in ground water samples of the coastal site. Natural radiation and radioactivity is a present in all the ecosystems naturally. Uranium is a naturally occurring low specific activity radionuclide present in the rock since the inception of the earth. Groundwater interact with the host rocks and the wet weathering process facilitate the solubility of uranium in groundwater. The physiochemical characteristics of the host rock and groundwater influence the leachability of uranium from rock to water and the contact time, temperature, salinity are also few influencing parameters. In the present study, an attempt has been made to study the spatial distribution of uranium in groundwater around the proposed NPP site at Kovvada, Andhra Pradesh

Removal of both dissolved and particulate iron from groundwater

OpenAIRE

H. van Dijk; H. Leijssen; L. Rietveld; A. Abrahamse; K. Teunissen

2008-01-01

Iron is the primary source for discolouration problems in the drinking water distribution system. The removal of iron from groundwater is a common treatment step in the production of drinking water. Even when clear water meets the drinking water standards, the water quality in the distribution system can deteriorate due to settling of iron (hydroxide) particles or post-treatment flocculation of dissolved iron. Therefore it is important to remove dissolved and particulate iron to a large exten...

Natural recharge of groundwater captured in the hilly area of Kinshasa: Hydrochemical and isotopic approaches

International Nuclear Information System (INIS)

Mabiala, M.P.; Nlandu, W.J.; Ndembo, L.J.

2005-01-01

The stable isotopic content of daily precipitation sampled at Mount Amba (CGEA) shows large variations principally due to climatic conditions during rain events and to the type of air masses, which generaed the precipitation. The isotopic values of groundwater suggest, throughout the study zone, a rapid and easy recharge of the aquifers by direct infiltration precipitation. In some places, isotopic enrichment content could be attributed to evaporation processes during precipation. Groundwater is generally of chloride and sodium type. They are chemically good for drinking water, but localised high concentrations in nitrates indicate a risk of pollution of the aquifer.

Groundwater management for pollution control: a case study for oil shale mining in Northeast Estonia

International Nuclear Information System (INIS)

Erg, K.; Raukas, A.

2001-01-01

In Estonia oil shale is produced by underground and surface mining. The excavation methods used cause serious damage to the environment, especially to the topography, which hampers the further use of the mined-out areas. The oil shale mining has a serious impact on the environment also due to the pollution of surface and groundwater by polluted mine drainage waters, lowering of groundwater level, changing of soil properties and high air pollution rate. Decline in mining activities and the introduction of new technologies together with economic measures has improved the situation but much should be done during coming years. (author)

Threats and opportunities for post-closure development in dolomitic ...

African Journals Online (AJOL)

Mining-related impacts such as large-scale land degradation associated with dewatering of karstic aquifers and widespread pollution of surface water and groundwater systems are discussed. Based on this, potential threats and opportunities for post-mining scenarios are identified in a series of 3 papers. Part 1 of this series ...

Field experiment on excess air formation in the riverbank of Danube

International Nuclear Information System (INIS)

Palcsu, L.; Major, Z.; Aeschbach-Hertig, W.

2007-01-01

Complete text of publication follows. Excess air is a contribution to the gases dissolved in groundwater in addition to the solubility equilibrium component, formed by partial or total dissolution of air trapped during water level rises in the unsaturated zone. The amount of excess air can be quite large, mainly if the water level increase is significant. The first aim of this field experiment carried out in September 2007 during a flood (Fig. 1/b) occurred along the Danube River has been to demonstrate that the excess air formation can be detected and studied under natural conditions when the groundwater level is rising. The study site is located in the riverbank of Danube River, the dug-well is at around 30 m from the riverbed (Fig. 1/a). The whole area is composed of fluvial sand. Separated water samples can be taken from the sampling tubes. Each sampling tube represents a certain depth. The horizontal groundwater flow velocity is supposed to be around 10 m/day (or at least this magnitude), that of course depends on the level difference between Danube and the groundwater. Helium and neon concentrations have been measured from the water samples. What we can see from these noble gas data is a probable correlation between groundwater level and excess noble gas concentrations. He and Ne are correlating providing evidence that the excess components are of same origin. However, the helium excess is usually larger than that of neon that means there has to be non atmospheric components of helium, such as terrigenic and tritiogenic. The R/Ra ratios are generally higher than one clearly showing tritiogenic 3 He in the water. Having a look at Fig. 1/b-c, it can be observed that there is a relatively good relation between groundwater rising and the excesses of the noble gases. From this sampling campaign, we can conclude that this kind of field experiment does make sense. Further noble gases have to be measured, and more information has to be gained regarding to the local

Drivers and Effects of Groundwater-Surface Water Interaction in the Karstic Lower Flint River Basin, Southwestern Georgia, USA

Science.gov (United States)

Rugel, K.; Golladay, S. W.; Jackson, C. R.; Rasmussen, T. C.; Dowd, J. F.; Mcdowell, R. J.

2017-12-01

Groundwater provides the majority of global water resources for domestic and agricultural usage while contributing vital surface water baseflows which support healthy aquatic ecosystems. Understanding the extent and magnitude of hydrologic connectivity between groundwater and surface water components in karst watersheds is essential to the prudent management of these hydraulically-interactive systems. We examined groundwater and surface water connectivity between the Upper Floridan Aquifer (UFA) and streams in the Lower Flint River Basin (LFRB) in southwestern Georgia where development of agricultural irrigation intensified over the past 30 years. An analysis of USGS streamflow data for the pre- and post-irrigation period showed summer baseflows in some Lower Flint River tributaries were reduced by an order of magnitude in the post-irrigation period, reiterating the strong hydraulic connection between these streams and the underlying aquifer. Large and fine-scale monitoring of calcium, nitrate, specific conductance and stable isotopes (δ18O and δD) on 50 km of Ichawaynochaway Creek, a major tributary of the Lower Flint, detected discrete groundwater-surface water flow paths which accounted for 42% of total groundwater contributions in the 50 km study reach. This presentation will highlight a new analysis using the metadata EPA Reach File (1) and comparing stream reach and instream bedrock joint azimuths with stream geochemical results from previous field study. Our findings suggested that reaches with NNW bearing may be more likely to display enhanced groundwater-surface water connectivity. Our results show that local heterogeneity can significantly affect water budgets and quality within these watersheds, making the use of geomorphological stream attributes a valuable tool to water resource management for the prediction and protection of vulnerable regions of hydrologic connectivity in karst catchments.

Calendar year 1996 annual groundwater monitoring report for the Chestnut Ridge Hydrogeologic Regime at the U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

International Nuclear Information System (INIS)

1997-02-01

This annual monitoring report contains groundwater and surface water monitoring data obtained in the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) during calendar year (CY) 1996. The Chestnut Ridge Regime encompasses a section of Chestnut Ridge west of Scarboro Road and east of an unnamed drainage feature southwest of the US Department of Energy (DOE) Oak Ridge Y-12 Plant (unless otherwise noted, directions are in reference to the Y-12 Plant administrative grid). The Chestnut Ridge Regime contains several sites used for management of hazardous and nonhazardous wastes associated with plant operations. Groundwater and surface water quality monitoring associated with these waste management sites is performed under the auspices of the Y-12 Plant Groundwater Protection Program (GWPP). Included in this annual monitoring report are the groundwater monitoring data obtained in compliance with the Resource Conservation and Recovery Act (RCRA) Post-Closure Permit for the Chestnut Ridge Regime (post-closure permit) issued by the Tennessee Department of Environment and Conservation (TDEC) in June 1996. Besides the signed certification statement and the RCRA facility information summarized below, condition II.C.6 of the post-closure permit requires annual reporting of groundwater monitoring activities, inclusive of the analytical data and results of applicable data evaluations, performed at three RCRA hazardous waste treatment, storage, or disposal (TSD) units: the Chestnut Ridge Sediment Disposal Basin (Sediment Disposal Basin), the Chestnut Ridge Security Pits (Security Pits), and Kerr Hollow Quarry

Surface-groundwater interactions in hard rocks in Sardon Catchment of western Spain: an integrated modeling approach

Science.gov (United States)

Hassan, S.M. Tanvir; Lubczynski, Maciek W.; Niswonger, Richard G.; Zhongbo, Su

2014-01-01

The structural and hydrological complexity of hard rock systems (HRSs) affects dynamics of surface–groundwater interactions. These complexities are not well described or understood by hydrogeologists because simplified analyses typically are used to study HRSs. A transient, integrated hydrologic model (IHM) GSFLOW (Groundwater and Surface water FLOW) was calibrated and post-audited using 18 years of daily groundwater head and stream discharge data to evaluate the surface–groundwater interactions in semi-arid, ∼80 km2 granitic Sardon hilly catchment in Spain characterized by shallow water table conditions, relatively low storage, dense drainage networks and frequent, high intensity rainfall. The following hydrological observations for the Sardon Catchment, and more generally for HRSs were made: (i) significant bi-directional vertical flows occur between surface water and groundwater throughout the HRSs; (ii) relatively large groundwater recharge represents 16% of precipitation (P, 562 mm.y−1) and large groundwater exfiltration (∼11% of P) results in short groundwater flow paths due to a dense network of streams, low permeability and hilly topographic relief; deep, long groundwater flow paths constitute a smaller component of the water budget (∼1% of P); quite high groundwater evapotranspiration (∼5% of P and ∼7% of total evapotranspiration); low permeability and shallow soils are the main reasons for relatively large components of Hortonian flow and interflow (15% and 11% of P, respectively); (iii) the majority of drainage from the catchment leaves as surface water; (iv) declining 18 years trend (4.44 mm.y−1) of groundwater storage; and (v) large spatio-temporal variability of water fluxes. This IHM study of HRSs provides greater understanding of these relatively unknown hydrologic systems that are widespread throughout the world and are important for water resources in many regions.

Proposed modifications to the RCRA post-closure permit for the Bear Creek Hydrogeologic Regime at the US Department of Energy Y-12 Plant, Oak Ridge, Tennessee

International Nuclear Information System (INIS)

1997-05-01

This report presents proposed modifications to several conditions of the Resource Conservation and Recovery Act (RCRA) Post-Closure Permit (PCP) for the Bear Creek Hydrogeologic Regime (BCHR). These permit conditions define the requirements for RCRA post-closure corrective action groundwater monitoring at the S-3 Ponds, the Oil Landfarm, and the Bear Creek Burial Grounds (units A, C-West, and Walk-in Pits). Modification of these PCP conditions is requested to: (1) clarify the planned integration of RCRA post-closure corrective action groundwater monitoring with the monitoring program to be established in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Record of Decision (ROD) for the Bear Creek Valley (BCV) Watershed, (2) revise several of the current technical requirements for groundwater monitoring based on implementation of the RCRA post-closure corrective action monitoring program during 1996, and (3) update applicable technical procedures with revised versions recently issued by the Y-12 Plant Groundwater Protection Program (GWPP). With these modifications, the Y-12 Plant will continue to meet the full intent of all regulatory obligations for post-closure care of these facilities. Section 2.0 provides the technical justification for each proposed permit modification. The proposed changes to permit language are provided in Section 3.0 (S-3 Ponds), Section 4.0 (Oil Landfarm), and Section 5.0 (Bear Creek Burial Grounds). Sections 6.0 and 7.0 reference updated and revised procedures for groundwater sampling, and monitoring well plugging and abandonment, respectively. Appendix A includes all proposed revisions to the PCP Attachments

Proposed modifications to the RCRA post-closure permit for the Bear Creek Hydrogeologic Regime at the US Department of Energy Y-12 Plant, Oak Ridge, Tennessee

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-05-01

This report presents proposed modifications to several conditions of the Resource Conservation and Recovery Act (RCRA) Post-Closure Permit (PCP) for the Bear Creek Hydrogeologic Regime (BCHR). These permit conditions define the requirements for RCRA post-closure corrective action groundwater monitoring at the S-3 Ponds, the Oil Landfarm, and the Bear Creek Burial Grounds (units A, C-West, and Walk-in Pits). Modification of these PCP conditions is requested to: (1) clarify the planned integration of RCRA post-closure corrective action groundwater monitoring with the monitoring program to be established in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Record of Decision (ROD) for the Bear Creek Valley (BCV) Watershed, (2) revise several of the current technical requirements for groundwater monitoring based on implementation of the RCRA post-closure corrective action monitoring program during 1996, and (3) update applicable technical procedures with revised versions recently issued by the Y-12 Plant Groundwater Protection Program (GWPP). With these modifications, the Y-12 Plant will continue to meet the full intent of all regulatory obligations for post-closure care of these facilities. Section 2.0 provides the technical justification for each proposed permit modification. The proposed changes to permit language are provided in Section 3.0 (S-3 Ponds), Section 4.0 (Oil Landfarm), and Section 5.0 (Bear Creek Burial Grounds). Sections 6.0 and 7.0 reference updated and revised procedures for groundwater sampling, and monitoring well plugging and abandonment, respectively. Appendix A includes all proposed revisions to the PCP Attachments.

Calendar Year 1997 Annual Groundwater Monitoring Report For The Upper East Fork Poplar Creek Hydrogeologic Regime At The U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

Energy Technology Data Exchange (ETDEWEB)

Jones, S.B.

1998-02-01

This report contains the groundwater monitoring data obtained during calendar year (CY) 1997 in compliance with the Resource Conservation Wd Recovery Act (RCRA) post-closure permit (PCP) for the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) at the U.S. Department of Energy (DOE) Y-12 Plant in Oak Ridge, Tennessee. Issued by the Tennessee Department of Environment and Conservation (TDEC), the PCP defines the RCRA post-closure corrective action monitoring requirements for the portion of the groundwater contaminant plume that has migrated into the East Fork Regime ftom the S-3 Ponds, a closed RCW-regulated former surface impoundment located in Bear Creek Valley near the west end of the Y-12 Plant. In addition to the RCIL4 post-closure corrective action monitoring results, this report contains the groundwater and surface water monitoring data obtained during CY 1997 to fulfill requirements of DOE Order 5400.1.

Eielson Air Force Base operable unit 2 and other areas record of decision

International Nuclear Information System (INIS)

Lewis, R.E.; Smith, R.M.

1994-10-01

This decision document presents the selected remedial actions and no action decisions for Operable Unit 2 (OU2) at Eielson Air Force Base (AFB), Alaska, chosen in accordance with state and federal regulations. This document also presents the decision that no further action is required for 21 other source areas at Eielson AFB. This decision is based on the administrative record file for this site. OU2 addresses sites contaminated by leaks and spills of fuels. Soils contaminated with petroleum products occur at or near the source of contamination. Contaminated subsurface soil and groundwater occur in plumes on the top of a shallow groundwater table that fluctuates seasonally. These sites pose a risk to human health and the environment because of ingestion, inhalation, and dermal contact with contaminated groundwater. The purpose of this response is to prevent current or future exposure to the contaminated groundwater, to reduce further contaminant migration into the groundwater, and to remediate groundwater

Global depletion of groundwater resources

NARCIS (Netherlands)

Wada, Y.; Beek, L.P.H. van; van Kempen, C.M.; Reckman, J.W.T.M.; Vasak, S.; Bierkens, M.F.P.

2010-01-01

In regions with frequent water stress and large aquifer systems groundwater is often used as an additional water source. If groundwater abstraction exceeds the natural groundwater recharge for extensive areas and long times, overexploitation or persistent groundwater depletion occurs. Here we

Distribution of Isotopic and Environmental Tracers in Groundwater, Northern Ada County, Southwestern Idaho

Science.gov (United States)

Adkins, Candice B.; Bartolino, James R.

2010-01-01

Residents of northern Ada County, Idaho, depend on groundwater for domestic and agricultural uses. The population of this area is growing rapidly and groundwater resources must be understood for future water-resource management. The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, used a suite of isotopic and environmental tracers to gain a better understanding of groundwater ages, recharge sources, and flowpaths in northern Ada County. Thirteen wells were sampled between September and October 2009 for field parameters, major anions and cations, nutrients, oxygen and hydrogen isotopes, tritium, radiocarbon, chlorofluorocarbons, and dissolved gasses. Well depths ranged from 30 to 580 feet below land surface. Wells were grouped together based on their depth and geographic location into the following four categories: shallow aquifer, intermediate/deep aquifer, Willow Creek aquifer, and Dry Creek aquifer. Major cations and anions indicated calcium-bicarbonate and sodium-bicarbonate water types in the study area. Oxygen and hydrogen isotopes carried an oxygen-18 excess signature, possibly indicating recharge from evaporated sources or water-rock interactions in the subsurface. Chlorofluorocarbons detected modern (post-1940s) recharge in every well sampled; tritium data indicated modern water (post-1951) in seven, predominantly shallow wells. Nutrient concentrations tended to be greater in wells signaling recent recharge based on groundwater age dating, thus confirming the presence of recent recharge in these wells. Corrected radiocarbon results generated estimated residence times from modern to 5,100 years before present. Residence time tended to increase with depth, as confirmed by all three age-tracers. The disagreement among residence times indicates that samples were well-mixed and that the sampled aquifers contain a mixture of young and old recharge. Due to a lack of data, no conclusions about sources of recharge could be drawn

Chronic groundwater decline: A multi-decadal analysis of groundwater trends under extreme climate cycles

Science.gov (United States)

Le Brocque, Andrew F.; Kath, Jarrod; Reardon-Smith, Kathryn

2018-06-01

Chronic groundwater decline is a concern in many of the world's major agricultural areas. However, a general lack of accurate long-term in situ measurement of groundwater depth and analysis of trends prevents understanding of the dynamics of these systems at landscape scales. This is particularly worrying in the context of future climate uncertainties. This study examines long-term groundwater responses to climate variability in a major agricultural production landscape in southern Queensland, Australia. Based on records for 381 groundwater bores, we used a modified Mann-Kendall non-parametric test and Sen's slope estimator to determine groundwater trends across a 26-year period (1989-2015) and in distinct wet and dry climatic phases. Comparison of trends between climatic phases showed groundwater level recovery during wet phases was insufficient to offset the decline in groundwater level from the previous dry phase. Across the entire 26-year sampling period, groundwater bore levels (all bores) showed an overall significant declining trend (p 0.05). Spatially, both declining and rising bores were highly clustered. We conclude that over 1989-2015 there is a significant net decline in groundwater levels driven by a smaller subset of highly responsive bores in high irrigation areas within the catchment. Despite a number of targeted policy interventions, chronic groundwater decline remains evident in the catchment. We argue that this is likely to continue and to occur more widely under potential climate change and that policy makers, groundwater users and managers need to engage in planning to ensure the sustainability of this vital resource.

Groundwater quality assessment for domestic and agriculture purposes in Puducherry region

Science.gov (United States)

Sridharan, M.; Senthil Nathan, D.

2017-11-01

Totally about 174 groundwater samples have been collected during pre-monsoon and post-monsoon season to study the suitability for domestic and agriculture purposes along the coastal aquifers of Puducherry region. Parameters such as pH, total dissolved solids (TDS), electrical conductivity (EC), sodium (Na), potassium (K), calcium (Ca), magnesium (Mg), bicarbonate (HCO3), chloride (Cl) and sulfate (SO4) were analyzed to assess the suitability of groundwater for domestic purposes. Sodium adsorption ratio (SAR), magnesium adsorption ratio (MAR), residual sodium bicarbonate (RSC), soluble sodium percentage (Na%), permeability index (PI) and chlorinity index were assessed for irrigation purposes. The higher concentration of ions such as Na, Ca, Cl and So4 indicates seawater intrusion, mineral dissolution, intense agricultural practices and improper sewage disposal. The level of EC, TDS and hardness in the water samples indicates that maximum of them are suitable for drinking and domestic purposes. The parameters such as SAR, Na%, PI, MAR and Chlorinity index indicates that majority of water sample are very good to moderately suitable for agriculture. In pre-monsoon, RSC of about 5.7% of samples was higher which when used for a longer time alter the soil properties and reduce crop production. Wilcox diagram suggests that water samples are of medium saline to low sodium type indicating that groundwater is suitable for irrigation. Temporal variation of groundwater quality shows significant increasing trend in EC, TDS and ions like Mg, K and Cl in the last decade, mainly due to anthropogenic activities with little geogenic impact in the quality of groundwater.

Assessment of groundwater quality in Kashipur Block, Purulia district, West Bengal

Science.gov (United States)

Kundu, Anindita; Nag, S. K.

2018-03-01

Hydrogeochemical investigation of groundwater resources of Kashipur Block, Purulia district, West Bengal has been carried out to assess the water quality for domestic and irrigation uses. Twenty groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids, hardness, major anions (CO3 2-, HCO3 -, Cl-, SO4 2-, F-) and cations (Ca2+, Mg2+, Fe2+, Na+, K+). Study results reveal that the groundwater of the area is mostly acidic in nature. The trend amongst average ionic concentrations of cations and anions is Mg2+ > Ca2+ > Na+ > Fe2+ > K+ and Cl- > HCO3 - > CO3 2- > SO4 2- > F- respectively during the post monsoon whereas the trend for cations and anions are Mg2+ > Ca2+> Na+ > K+ > Fe and Cl- > HCO3 - > SO4 2- > F- > CO3 - in pre monsoon session, respectively. To explore the ionic toxicity of the study area, the derived parameters like sodium adsorption ratio, soluble sodium percentage, residual sodium carbonate, magnesium adsorption ratio, Kelly's ratio and permeability index were calculated. The hydro geochemical data suggest that weathering of rock forming minerals along with secondary contributions from agricultural and anthropogenic sources are mainly controlling the groundwater composition of Kashipur Block, Purulia District. According to piper diagram, water samples of most of the area of the block are fresh water and in some areas sulphate rich throughout the year. All samples are distributed to central rock dominance category. Groundwater chemistry of this block is mainly controlled by the interaction existing between the litho units and the percolating water into the subsurface domain. However, the groundwater quality and suitability of this study area can be termed as good to moderate with a few exceptions which have been encountered on a local scale.

Proposed modifications to the RCRA post-closure permit for the Chestnut Ridge Hydrogeologic Regime at the U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

International Nuclear Information System (INIS)

1997-05-01

This report presents proposed modifications to several conditions of the Resource Conservation and Recovery Act (RCRA) Post-Closure Permit (PCP) for the Chestnut Ridge Hydrogeologic Regime (CRHR) (permit number TNHW-088, EPA ID No. TN3 89 009 0001). These permit conditions define the requirements for RCRA post-closure detection groundwater monitoring at the Chestnut Ridge Sediment Disposal Basin (CRSDB) and Kerr Hollow Quarry (KHQ), and RCRA post-closure corrective action groundwater monitoring at the Chestnut Ridge Security Pits (CRSPs). Modification of these PCP conditions is requested to: (1) clarify the planned integration of RCRA post-closure corrective action groundwater monitoring at the CRSPs with the monitoring program to be established in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) record of decision (ROD), (2) revise several of the current technical requirements for groundwater monitoring based on implementation of the RCRA monitoring programs during 1996, (3) replace several of the technical procedures included in the PCP with updated versions recently issued by the Y-12 Plant Groundwater Protection Program (GWPP), and (4) correct inaccurate regulatory citations and references to permit conditions and permit attachments. With these modifications, the Y- 12 Plant will continue to meet the full intent of all regulatory obligations for post-closure care of these facilities. Section 2 provides the technical justification for each proposed permit modification. Section 3.0 contains proposed changes to Section II of the PCP. Modifications to site-specific permit conditions are presented in Section 4.0 (CRSDB), Section 5.0 (CRSPs), and Section 6.0 (KHQ). Sections 7.0 and 8.0 reference updated and revised procedures for groundwater sampling, and monitoring well plugging and abandonment, respectively. Appendix A includes all proposed revisions to the permit attachments

Proposed modifications to the RCRA post-closure permit for the Chestnut Ridge Hydrogeologic Regime at the U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-05-01

This report presents proposed modifications to several conditions of the Resource Conservation and Recovery Act (RCRA) Post-Closure Permit (PCP) for the Chestnut Ridge Hydrogeologic Regime (CRHR) (permit number TNHW-088, EPA ID No. TN3 89 009 0001). These permit conditions define the requirements for RCRA post-closure detection groundwater monitoring at the Chestnut Ridge Sediment Disposal Basin (CRSDB) and Kerr Hollow Quarry (KHQ), and RCRA post-closure corrective action groundwater monitoring at the Chestnut Ridge Security Pits (CRSPs). Modification of these PCP conditions is requested to: (1) clarify the planned integration of RCRA post-closure corrective action groundwater monitoring at the CRSPs with the monitoring program to be established in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) record of decision (ROD), (2) revise several of the current technical requirements for groundwater monitoring based on implementation of the RCRA monitoring programs during 1996, (3) replace several of the technical procedures included in the PCP with updated versions recently issued by the Y-12 Plant Groundwater Protection Program (GWPP), and (4) correct inaccurate regulatory citations and references to permit conditions and permit attachments. With these modifications, the Y- 12 Plant will continue to meet the full intent of all regulatory obligations for post-closure care of these facilities. Section 2 provides the technical justification for each proposed permit modification. Section 3.0 contains proposed changes to Section II of the PCP. Modifications to site-specific permit conditions are presented in Section 4.0 (CRSDB), Section 5.0 (CRSPs), and Section 6.0 (KHQ). Sections 7.0 and 8.0 reference updated and revised procedures for groundwater sampling, and monitoring well plugging and abandonment, respectively. Appendix A includes all proposed revisions to the permit attachments.

Groundwater reorganization in the Floridan aquifer following Holocene sea-level rise

Science.gov (United States)

Morrissey, Sheila K.; Clark, Jordan F.; Bennett, Michael; Richardson, Emily; Stute, Martin

2010-10-01

Sea-level fluctuations, particularly those associated with glacial-interglacial cycles, can have profound impacts on the flow and circulation of coastal groundwater: the water found at present in many coastal aquifers may have been recharged during the last glacial period, when sea level was over 100m lower than present, and thus is not in equilibrium with present recharge conditions. Here we show that the geochemistry of the groundwater found in the Floridan Aquifer System in south Florida is best explained by a reorganization of groundwater flow following the sea-level rise at the end of the Last Glacial Maximum approximately 18,000 years ago. We find that the geochemistry of the fresh water found in the upper aquifers at present is consistent with recharge from meteoric water during the last glacial period. The lower aquifer, however, consists of post-sea-level-rise salt water that is most similar to that of the Straits of Florida, though with some dilution from the residual fresh water from the last glacial period circulation. We therefore suggest that during the last glacial period, the entire Floridan Aquifer System was recharged with meteoric waters. After sea level rose, the increased hydraulic head reduced the velocity of the groundwater flow. This velocity reduction trapped the fresh water in the upper aquifers and initiated saltwater circulation in the lower aquifer.

KAJIAN SPASIAL KUALITAS AIR TANAH BEBAS BERDASARKAN KEDALAM MUKA AIR TANAH: STUDI KASUS DI DATARAN ALUVIAL DAS PEMALI KABUPATEN BREBES (Spatial Study of the Quality of Free Groundwater Based on the Surface Depth of Groundwater at an Alluvial Land

Directory of Open Access Journals (Sweden)

Siti Sundari Miswadi

2009-07-01

kadarnya melebihi NAB. Kedalaman MAT yang menunjukkan kualitas air cukup baik sesuai analisis adalah pada kedalaman di atas 8,51 meter dan antara 5,80-6,70 meter.   ABSTRACT Most of the alluvial areas of Pemali River Basin (DAS in Brebes district are onion, soybean, cassava, and chili farm production centre. Besides, the area is also known for duck husbandry producing eggs, and it is developed fast. The agriculture and husbandry are mostly met in the residential area, whereas the activities use fertilizer and pesticides and also produce cattle waste which, of course, will contaminate people’s wells. Since the clean water service of the Municipal Waterworks (PDAM has not reach all of the Pemali River Basin (DAS, especially in alluvial residential area, so for cooking, drinking, bathing, washing and other needs, the people make well with various depth, without concerning the right well making and health requirements. The purpose of the research is to map the quality of free ground water based on the depth of water ground surface in the Pemali DAS alluvial area. The method used is analyzing the quality of the free ground water laboratorically, and the result is plotted to 30 sample points in the map of groundwater surface depth divided into 11 classes. The result of the research shows that there are 10 parameters of water quality which content over the Limit Edge Value (NAB, they are, TDS, DHL, Organochlorine, Carbamat, Alkalinity, COD, BOD, Coliform Total, waste Coliform, and pH, whether the NO3-, NO2-, SO4=, Ca2+, phosphate, and muddiness parameter generally have content below NAB in all depth. Seen from some of the sample points which parameter amount has content over the NAB,  the 0.37-3.98 meters ground water surface depth has eight parameters which over the NAB, then 0.10-0.36 meter depth with five parameters, and 3.99-8.50 meters with four parameters which over the NAB. Based on the parameter amount of each sample point, so in 0.37-1.27 meters MAT depth there are

Simulating groundwater-induced sewer flooding

Science.gov (United States)

Mijic, A.; Mansour, M.; Stanic, M.; Jackson, C. R.

2016-12-01

During the last decade, Chalk catchments of southern England experienced severe groundwater flooding. High groundwater levels resulted in the groundwater ingress into the sewer network that led to restricted toilet use and the overflow of diluted, but untreated sewage to road surfaces, rivers and water courses. In response to these events the water and sewerage company Thames Water Utilities Ltd (TWUL) had to allocate significant funds to mitigate the impacts. It was estimated that approximately £19m was spent responding to the extreme wet weather of 2013-14, along with the use of a fleet of over 100 tankers. However, the magnitude of the event was so large that these efforts could not stop the discharge of sewage to the environment. This work presents the analysis of the risk of groundwater-induced sewer flooding within the Chalk catchment of the River Lambourn, Berkshire. A spatially distributed groundwater model was used to assess historic groundwater flood risk and the potential impacts of changes in future climate. We then linked this model to an urban groundwater model to enable us to simulate groundwater-sewer interaction in detail. The modelling setup was used to identify relationships between infiltration into sewers and groundwater levels at specific points on TWUL's sewer network, and to estimate historic and future groundwater flood risk, and how this varies across the catchment. The study showed the significance of understanding the impact of groundwater on the urban water systems, and producing information that can inform a water company's response to groundwater flood risk, their decision making process and their asset management planning. However, the knowledge gained through integrated modelling of groundwater-sewer interactions has highlighted limitations of existing approaches for the simulation of these coupled systems. We conclude this work with number of recommendations about how to improve such hydrological/sewer analysis.

Factors affecting hydrocarbon removal by air stripping

International Nuclear Information System (INIS)

McFarland, W.E.

1992-01-01

This paper includes an overview of the theory of air stripping design considerations and the factors affecting stripper performance. Effects of temperature, contaminant characteristics, stripping tower geometry and air/water ratios on removal performance are discussed. The discussion includes treatment of groundwater contaminated with petroleum hydrocarbons and chlorinated solvents such as TCE and PCE. Control of VOC emissions from air strippers has become a major concern in recent years, due to more stringent restrictions on air quality in many areas. This paper includes an overview of available technology to control air emissions (including activated carbon adsorption, catalytic oxidation and steam stripping) and the effects of air emission control on overall efficiency of the treatment process. The paper includes an overview of the relative performance of various packing materials for air strippers and explains the relative advantages and disadvantages of comparative packing materials. Field conditions affecting selection of packing materials are also discussed. Practical guidelines for the design of air stripping systems are presented, as well as actual case studies of full-scale air stripping projects

Coastal Zone Hazards Related to Groundwater-Surface Water Interactions and Groundwater Flooding

Science.gov (United States)

Kontar, Y. A.; Ozorovich, Y. R.; Salokhiddinov, A. T.

2009-12-01

Worldwide, as many as half a million people have died in natural and man-made disasters since the turn of the 21st century (Wirtz, 2008). Further, natural and man-made hazards can lead to extreme financial losses (Elsner et al, 2009). Hazards, hydrological and geophysical risk analysis related to groundwater-surface water interactions and groundwater flooding have been to a large extent under-emphasized for coastal zone applications either due to economical limitations or underestimation of its significance. This is particularly true for tsunamis creating salt water intrusion to coastal aquifers, even though most tsunami hazard assessments have in the past relied on scenario or deterministic type models (Geist and Parsons, 2006), and to increasing mineralization of potable water because of intensive water diversions and also the abundance of highly toxic pollutants (mainly pesticides) in water, air and food, which contribute to the deterioration of the coastal population's health (Glantz, 2007). In the wake of pressing environmental and economic issues, it is of prime importance for the scientific community to shed light onto the great efforts by hydrologists and geophysicists to quantify conceptual uncertainties and to provide quality assurances of potential coastal zone hazard evaluation and prediction. This paper proposes consideration of two case studies which are important and significant for future development and essential for feasibility studies of hazards in the coastal zone. The territory of the Aral Sea Region in Central Asia is known as an ecological disaster coastal zone (Zavialov, 2005). It is now obvious that, in order to provide reasonable living conditions to the coastal zone population, it is first of all necessary to drastically improve the quality of the water dedicated to human needs. Due to their intensive pollution by industrial wastes and by drainage waters from irrigated fields, the Syr Darya and Amu Darya rivers can no longer be considered

Groundwater flow modelling of periods with temperate climate conditions - Laxemar

International Nuclear Information System (INIS)

Joyce, Steven; Simpson, Trevor; Hartley, Lee; Applegate, David; Hoek, Jaap; Jackson, Peter; Roberts, David; Swan, David; Gylling, Bjoern; Marsic, Niko; Rhen, Ingvar

2010-12-01

As a part of the license application for a final repository for spent nuclear fuel at Forsmark, the Swedish Nuclear Fuel and Waste Management Company (SKB) has undertaken a series of groundwater flow modelling studies. These represent time periods with different hydraulic conditions and the simulations carried out contribute to the overall evaluation of the repository design and long-term radiological safety. This report concerns the modelling of a repository at the Laxemar-Simpevarp site during temperate climate conditions as a comparison to corresponding modelling carried out for Forsmark /Joyce et al. 2010/. The collation and implementation of onsite hydrogeological and hydrogeochemical data from previous reports are used in the construction of a Hydrogeological base case (reference case conceptualisation) and then an examination of various areas of uncertainty within the current understanding by a series of model variants. The Hydrogeological base case models at three different scales, 'repository', 'site' and 'regional' make use of a discrete fracture network (DFN) and equivalent continuous porous medium (ECPM) models. The use of hydrogeological models allow for the investigation of the groundwater flow from a deep disposal facility to the biosphere and for the calculation of performance measures that will provide an input to the site performance assessment. The focus of the study described in this report has been to perform numerical simulations of the hydrogeological system from post-closure and throughout the temperate period up until the receding shoreline leaves the modelling domain at around 15,000 AD. Besides providing quantitative results for the immediate temperate period following post-closure, these results are also intended to give a qualitative indication of the evolution of the groundwater system during future temperate periods within an ongoing cycle of glacial/inter-glacial events

Groundwater flow modelling of periods with temperate climate conditions - Laxemar

Energy Technology Data Exchange (ETDEWEB)

Joyce, Steven; Simpson, Trevor; Hartley, Lee; Applegate, David; Hoek, Jaap; Jackson, Peter; Roberts, David; Swan, David (Serco Technical Consulting Services (United Kingdom)); Gylling, Bjoern; Marsic, Niko (Kemakta Konsult AB, Stockholm (Sweden)); Rhen, Ingvar (SWECO Environment AB, Falun (Sweden))

2010-12-15

As a part of the license application for a final repository for spent nuclear fuel at Forsmark, the Swedish Nuclear Fuel and Waste Management Company (SKB) has undertaken a series of groundwater flow modelling studies. These represent time periods with different hydraulic conditions and the simulations carried out contribute to the overall evaluation of the repository design and long-term radiological safety. This report concerns the modelling of a repository at the Laxemar-Simpevarp site during temperate climate conditions as a comparison to corresponding modelling carried out for Forsmark /Joyce et al. 2010/. The collation and implementation of onsite hydrogeological and hydrogeochemical data from previous reports are used in the construction of a Hydrogeological base case (reference case conceptualisation) and then an examination of various areas of uncertainty within the current understanding by a series of model variants. The Hydrogeological base case models at three different scales, 'repository', 'site' and 'regional' make use of a discrete fracture network (DFN) and equivalent continuous porous medium (ECPM) models. The use of hydrogeological models allow for the investigation of the groundwater flow from a deep disposal facility to the biosphere and for the calculation of performance measures that will provide an input to the site performance assessment. The focus of the study described in this report has been to perform numerical simulations of the hydrogeological system from post-closure and throughout the temperate period up until the receding shoreline leaves the modelling domain at around 15,000 AD. Besides providing quantitative results for the immediate temperate period following post-closure, these results are also intended to give a qualitative indication of the evolution of the groundwater system during future temperate periods within an ongoing cycle of glacial/inter-glacial events

Groundwater Managment Districts

Data.gov (United States)

Kansas Data Access and Support Center — This dataset outlines the location of the five Groundwater Management Districts in Kansas. GMDs are locally formed and elected boards for regional groundwater...

Apparent 85Kr ages of groundwater within the Royal watershed, Maine, USA.

Science.gov (United States)

Sidle, W C

2006-01-01

Specific 85Kr activity is mapped from 264 domestic and municipal wells sampled during 2002-2004 in the Royal watershed (361 km2), Maine. Gas samples are collected at 20 m, 40 m, and > 50 m interval depths within the unconfined aquifers. Gas extraction for 85Kr from wells is obtained directly via a wellhead methodology avoiding conventional collection of large sample volumes. Atmospheric 85Kr input to the recharge environment is estimated at 1.27 Bq m(-3) by time-series analyses of weighted monthly precipitation (2001-2004). Numerical simulation of Kr gas transport through the variable unsaturated zones to the water table suggests up to 12-year time lags locally, thus biasing the 85Kr groundwater ages. Apparent 85Kr ages suggest that approximately 70% of groundwater near 20 m depth was recharged less than 30 years BP (2004). Mass-age transport modeling suggests that post mid-1950s recharge penetrates to part of the basin's floor and that older groundwater seeps from the underlying fractured bedrock may occur.

Calandar year 1996 annual groundwater monitoring report for the Bear Creek Hydrogeologic Regime at the US Department of Energy Y-12 Plant, Oak Ridge, Tennessee

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-02-01

This annual monitoring report contains groundwater and surface water monitoring data obtained in the Bear Creek Hydrogeologic Regime (Bear Creek Regime) during calendar year (CY) 1996. The Bear Creek Regime encompasses a portion of Bear Creek Valley (BCV) west of the U.S. Department of Energy (DOE) Oak Ridge Y-12 Plant (unless otherwise noted, directions are in reference to the Y-12 Plant administrative grid) that contains several sites used for management of hazardous and nonhazardous wastes associated with plant operations. Groundwater and surface water quality monitoring in the Bear Creek Regime is performed under the auspices of the Y-12 Plant Groundwater Protection Program (GWPP). This report contains the information and monitoring data required under the Resource Conservation and Recovery Act (RCRA) Post-Closure Permit for the Bear Creek Hydrogeologic Regime (post-closure permit), as modified and issued by the Tennessee Department of Environment and Conservation (TDEC) in September 1995 (permit no. TNHW-087). In addition to the signed certification statement and the RCRA facility information summarized below, permit condition II.C.6 requires the annual monitoring report to address groundwater monitoring activities at the three RCRA Hazardous Waste Disposal Units (HWDUs) in the Bear Creek Regime that are in post-closure corrective action status (the S-3 Site, the Oil Landfarm, and the Bear Creek Burial Grounds/Walk-In Pits).

Prospects for Groundwater Drought Termination in the UK in 2017-18

Science.gov (United States)

Parry, S.; McKenzie, A.; Prudhomme, C.; Wilby, R.; Wood, P.

2017-12-01

The recovery of groundwater levels towards the end of a drought can lag behind surface water stores such as reservoirs or snowpack - as was the case for California in 2016/17. Groundwater replenishment is an important precursor to the ending of water restrictions, and an improved understanding of the range of plausible groundwater recovery scenarios would be useful for a range of stakeholders, including water managers, farmers and businesses. A method for characterising drought termination in hydrological data is applied systematically here to long time series of groundwater levels (some from the mid-1800s) for the UK. This analysis capitalises on the comprehensive perspective of post-drought recovery in the historical record to provide various outlooks of recovery in groundwater levels over seasonal to multi-year timeframes and to better understand how present conditions are likely to evolve. Rainfall deficiencies in the UK since summer 2016 limited replenishment during the 2016/17 winter recharge season. As a consequence, groundwater levels in south-east England were notably below normal in summer 2017. The possibility of an abrupt termination as occurred in 2012 can already be excluded, and extrapolating recent patterns suggests that very gradual recoveries may be underway. At many sites, normal conditions are not expected to return during 2017, and later still for sites in less responsive aquifers. This is supported by the multi-year drought durations typically found in the historical record, much more prolonged than those observed during the currently developing event. The rainfall rates that have driven historical drought termination events are also assessed for their likelihood across a range of timeframes and start months. Overall results underline the importance of the typical recharge season during the wetter winter half-year in averting multi-year groundwater drought events that would threaten water resources in the populous south-east of the UK. The

Analysis of groundwater from deep boreholes in Svartboberget

International Nuclear Information System (INIS)

Laurent, S.

1983-06-01

Groundwater from two boreholes in granitic rock at an investigation site in Svartboberget has been sampled and analysed. This is part of a larger program of geological, geophysical and hydrogeological investigations aimed at finding a suitable site for a high level radioactive waste repository. Four water-bearing levels in each borehole down to the deepest at about 600m were selected. Prior to sampling, the water-bearing level is isolated between packer sleeves. The water is then pumped to the surface where sensitive parameters such as redox potential, pH, sulphide and oxygen content are measured electrochemically on the flowing water in a system isolated from the air. Water, filter and gas samples are sent to several laboratories for further analysis. The present report is a presentation of the results of the groundwater analyses. The reliability of the results is discussed but there is no evaluation in relation to geology and hydrogeology. This report presents the basic results from the groundeater analyses to be further evaluated by experts in different fields. (author)

Effects of Post-Pyrolysis Air Oxidation of Biomass Chars on Adsorption of Neutral and Ionizable Compounds.

Science.gov (United States)

Xiao, Feng; Pignatello, Joseph J

2016-06-21

This study was conducted to understand the effects of thermal air oxidation of biomass chars experienced during formation or production on their adsorptive properties toward various compounds, including five neutral nonpolar and polar compounds and seven weak acids and bases (pKa = 3-5.2) selected from among industrial chemicals and the triazine and phenoxyacetic acid herbicide classes. Post-pyrolysis air oxidation (PPAO) at 400 °C of anoxically prepared wood and pecan shell chars for up to 40 min enhanced the mass-normalized adsorption at pH ∼ 7.4 of all test compounds, especially the weak acids and bases, by up to 100-fold. Both general and specific effects were identified. The general effect results from "reaming" of pores by the oxidative removal of pore wall matter and/or tarry deposits generated during the pyrolysis step. Reaming creates new surface area and enlarges nanopores, which helps relieve steric hindrance to adsorption. The specific effect results from creation of new acidic functionality that provides sites for the formation of very strong, charge-assisted hydrogen bonds (CAHB) with solutes having comparable pKa. The CAHB hypothesis was supported by competition experiments and the finding that weak acid anion adsorption increased with surface carboxyl content, despite electrostatic repulsion from the growing negative charge. The results provide insight into the effects of air oxidation on pollutant retention.

A new separation and treatment method for soil and groundwater restoration

Energy Technology Data Exchange (ETDEWEB)

Hitchens, G.D. [Lynntech, Inc., College Station, TX (United States)

1997-10-01

Soil and groundwater contamination by organic compounds is a widespread environmental pollution problem. In many cases, contaminated soil is excavated and transported to a landfill or is incinerated to remove contaminants. These remediation practices are expensive, environmentally disruptive, require extensive permitting, and only move contamination from one location to another. Onsite and in situ treatment techniques offer a safer, more cost-effective, and permanent solution. Many soil and groundwater contaminants are highly volatile, enabling the use of methods such as in situ vacuum extraction and air injection for their removal. However, these methods are often difficult to use because of slow volatilization rates and the lack of effective methods to treat the extracted hazardous material. This Phase I Small Business Innovation Research program focuses on developing an in situ soil and groundwater remediation technique that is effective against volatile as well as nonvolatile compounds and that will shorten treatment times. The technique forms the basis of a new catalytic process to degrade extracted contaminants onsite. Key hardware elements on which the new technique is based have been proven in preliminary research. The method has a high potential for public and regulatory acceptance because of its low environment impact.

A new separation and treatment method for soil and groundwater restoration

International Nuclear Information System (INIS)

Hitchens, G.D.

1997-01-01

Soil and groundwater contamination by organic compounds is a widespread environmental pollution problem. In many cases, contaminated soil is excavated and transported to a landfill or is incinerated to remove contaminants. These remediation practices are expensive, environmentally disruptive, require extensive permitting, and only move contamination from one location to another. Onsite and in situ treatment techniques offer a safer, more cost-effective, and permanent solution. Many soil and groundwater contaminants are highly volatile, enabling the use of methods such as in situ vacuum extraction and air injection for their removal. However, these methods are often difficult to use because of slow volatilization rates and the lack of effective methods to treat the extracted hazardous material. This Phase I Small Business Innovation Research program focuses on developing an in situ soil and groundwater remediation technique that is effective against volatile as well as nonvolatile compounds and that will shorten treatment times. The technique forms the basis of a new catalytic process to degrade extracted contaminants onsite. Key hardware elements on which the new technique is based have been proven in preliminary research. The method has a high potential for public and regulatory acceptance because of its low environment impact

Understanding groundwater - students' pre-conceptions and conceptual change by a theory-guided multimedia learning program

Science.gov (United States)

Unterbruner, U.; Hilberg, S.; Schiffl, I.

2015-11-01

Groundwater is a crucial topic in education for sustainable development. Nevertheless, international studies with students of different ages have shown that the basic hydrogeological concept of groundwater defined as water within porous and permeable rocks is not an established everyday notion. Building upon international research a multimedia learning program ("Between the raincloud and the tap") was developed. Insights from the fields of conceptual change research, multimedia research, and the Model of Educational Reconstruction were specifically implemented. Two studies were conducted with Austrian pupils (7th grade) and teacher training students from the fields of biology and geography in order to ascertain the effectiveness of the learning program. Using a quasi-experimental research design, the participants' conceptions and knowledge regarding groundwater were determined in a pre- and post-test. The pupils and students greatly profited from independently working through the learning software. Their knowledge of groundwater increased significantly compared to the control group and there was a highly significant increase in the number of scientifically correct notions of groundwater. The acceptance of the program was also generally very high. The results speak for the fact that theory-guided multimedia learning programs can play an important role in the transfer of research results into the classroom, particularly in science education.

Residence times and mixing of water in river banks: implications for recharge and groundwater-surface water exchange

Science.gov (United States)

Unland, N. P.; Cartwright, I.; Cendón, D. I.; Chisari, R.

2014-12-01

Bank exchange processes within 50 m of the Tambo River, southeast Australia, have been investigated through the combined use of 3H and 14C. Groundwater residence times increase towards the Tambo River, which suggests the absence of significant bank storage. Major ion concentrations and δ2H and δ18O values of bank water also indicate that bank infiltration does not significantly impact groundwater chemistry under baseflow and post-flood conditions, suggesting that the gaining nature of the river may be driving the return of bank storage water back into the Tambo River within days of peak flood conditions. The covariance between 3H and 14C indicates the leakage and mixing between old (~17 200 years) groundwater from a semi-confined aquifer and younger groundwater (bank infiltration. Furthermore, the more saline deeper groundwater likely controls the geochemistry of water in the river bank, minimising the chemical impact that bank infiltration has in this setting. These processes, coupled with the strongly gaining nature of the Tambo River are likely to be the factors reducing the chemical impact of bank storage in this setting. This study illustrates the complex nature of river groundwater interactions and the potential downfall in assuming simple or idealised conditions when conducting hydrogeological studies.

200-ZP-1 phase II and III IRM groundwater pump and treat site safety plan

International Nuclear Information System (INIS)

St. John, C.H.

1996-07-01

This safety plan covers operations, maintenance, and support activities related to the 200-ZP-1 Phase II and III Ground Water Pump- and-Treat Facility. The purpose of the facility is to extract carbon tetrachloride contaminated groundwater underlying the ZP-1 Operable Unit; separate the contaminant from the groundwater; and reintroduce the treated water to the aquifer. An air stripping methodology is employed to convert volatile organics to a vapor phase for absorption onto granular activated carbon. The automated process incorporates a variety of process and safety features that shut down the process system in the event that process or safety parameters are exceeded or compromised

Considering groundwater use to improve the assessment of groundwater pumping for irrigation in North Africa

Science.gov (United States)

Massuel, Sylvain; Amichi, Farida; Ameur, Fatah; Calvez, Roger; Jenhaoui, Zakia; Bouarfa, Sami; Kuper, Marcel; Habaieb, Hamadi; Hartani, Tarik; Hammani, Ali

2017-09-01

Groundwater resources in semi-arid areas and especially in the Mediterranean face a growing demand for irrigated agriculture and, to a lesser extent, for domestic uses. Consequently, groundwater reserves are affected and water-table drops are widely observed. This leads to strong constraints on groundwater access for farmers, while managers worry about the future evolution of the water resources. A common problem for building proper groundwater management plans is the difficulty in assessing individual groundwater withdrawals at regional scale. Predicting future trends of these groundwater withdrawals is even more challenging. The basic question is how to assess the water budget variables and their evolution when they are deeply linked to human activities, themselves driven by countless factors (access to natural resources, public policies, market, etc.). This study provides some possible answers by focusing on the assessment of groundwater withdrawals for irrigated agriculture at three sites in North Africa (Morocco, Tunisia and Algeria). Efforts were made to understand the different features that influence irrigation practices, and an adaptive user-oriented methodology was used to monitor groundwater withdrawals. For each site, different key factors affecting the regional groundwater abstraction and its past evolution were identified by involving farmers' knowledge. Factors such as farmer access to land and groundwater or development of public infrastructures (electrical distribution network) are crucial to decode the results of well inventories and assess the regional groundwater abstraction and its future trend. This leads one to look with caution at the number of wells cited in the literature, which could be oversimplified.

An investigation on groundwater recovery rate within sub sea floor tunnels at closed coal mines

International Nuclear Information System (INIS)

Nakata, Eiji; Suenaga, Hiroshi; Oyama, Takahiro; Nomura, Tokisada; Ichihara, Yoshihisa

2008-01-01

The groundwater recovery rate investigated at the closed coal mines extended within sub sea floor tunnels. The Ikeshima and the Taiheiyo coal mine companies exploited the deep coal-bearing strata beneath the ocean. Ikeshima coal mine, excavated S.L. -650m to 6km offshore from Ikeshima island, was closed at November 2002, and Taiheiyo coal mine, excavated S.L. -720m to 9km offshore from Hokkaido, was stopped to excavate from the deep area at January 2003. After closing and stopping of development, we began the investigation of the groundwater recovery rate at both coal mines. The groundwater level of Ikeshima coal mine raised +405m per 1.8 years at the main shaft. The permeability coefficient estimated between 10 - 8 m /s and 10 -6 m/s to use the water recovery rate at the shaft. Otherwise, at Taiheiyo coal mine, we measured the air pressure in tubes used by 3.5km 2.5km, and 1.5km length 2mm diameters tubes to estimate the groundwater recovery level at the 3.2km offshore plug site. Groundwater didn't reach 4.7km (1.5+3.2km) area until November 2004. There were breakdown of shotcleate and rock mass from the roof of tunnel at 5.3km from offshore line. In this paper, we try to show the groundwater recovery rate of these sub sea floor collieries. (author)

Tracing and quantifying groundwater inflow into lakes using a simple method for radon-222 analysis

Directory of Open Access Journals (Sweden)

T. Kluge

2007-09-01

Full Text Available Due to its high activities in groundwater, the radionuclide ²²²Rn is a sensitive natural tracer to detect and quantify groundwater inflow into lakes, provided the comparatively low activities in the lakes can be measured accurately. Here we present a simple method for radon measurements in the low-level range down to 3 Bq m⁻³, appropriate for groundwater-influenced lakes, together with a concept to derive inflow rates from the radon budget in lakes. The analytical method is based on a commercially available radon detector and combines the advantages of established procedures with regard to efficient sampling and sensitive analysis. Large volume (12 l water samples are taken in the field and analyzed in the laboratory by equilibration with a closed air loop and alpha spectrometry of radon in the gas phase. After successful laboratory tests, the method has been applied to a small dredging lake without surface in- or outflow in order to estimate the groundwater contribution to the hydrological budget. The inflow rate calculated from a ²²²Rn balance for the lake is around 530 m³ per day, which is comparable to the results of previous studies. In addition to the inflow rate, the vertical and horizontal radon distribution in the lake provides information on the spatial distribution of groundwater inflow to the lake. The simple measurement and sampling technique encourages further use of radon to examine groundwater-lake water interaction.

3D modeling of groundwater heat transport in the shallow Westliches Leibnitzer Feld aquifer, Austria

Science.gov (United States)

Rock, Gerhard; Kupfersberger, Hans

2018-02-01

For the shallow Westliches Leibnitzer feld aquifer (45 km2) we applied the recently developed methodology by Kupfersberger et al. (2017a) to derive the thermal upper boundary for a 3D heat transport model from observed air temperatures. We distinguished between land uses of grass and agriculture, sealed surfaces, forest and water bodies. To represent the heat flux from heated buildings and the mixture between different land surfaces in urban areas we ran the 1D vertical heat conduction module SoilTemp which is coupled to the heat transport model (using FEFLOW) on a time step basis. Over a simulation period of 23 years the comparison between measured and observed groundwater temperatures yielded NSE values ranging from 0.41 to 0.92 including readings at different depths. The model results showed that the thermal input signals lead to distinctly different vertical groundwater temperature distributions. To overcome the influence of specific warm or cold years we introduced the computation of an annual averaged groundwater temperature profile. With respect to the use of groundwater cooling or heating facilities we evaluated the application of vertically averaged statistical groundwater temperature distributions compared to the use of temperature distributions at selected dates. We concluded that the heat transport model serves well as an aquifer scale management tool to optimize the use of the shallow subsurface for thermal purposes and to analyze the impacts of corresponding measures on groundwater temperatures.

Assessment of ground-water contamination from a leaking underground storage tank at a defense supply center near Richmond, Virginia

International Nuclear Information System (INIS)

Powell, J.D.; Wright, W.G.

1990-01-01

During 1988-89, 24 wells were installed in the vicinity of the post-exchange gasoline station on the Defense General Supply Center, near Richmond, Virginia, to collect and analyze groundwater samples for the presence of gasoline contamination from a leaking underground storage tank. Concentrations of total petroleum hydrocarbons and benzene were as high as 8.2 mg/L and 9,000 microg/L, respectively, in water from wells in the immediate vicinity of the former leaking tank, and benzene concentrations were as high as 2,300 microg/L in a well 600 ft down gradient from the gasoline station. Groundwater flow rate are estimated to be about 60 to 80 ft/yr; on the basis of these flow rates, the contaminants may have been introduced into the groundwater as long as 7-10 yrs ago. Groundwater might infiltrate a subsurface storm sewer, where the sewer is below the water table, and discharge into a nearby stream. Preliminary risk assessment for the site identified no potential human receptors to the groundwater contamination because there were no groundwater users identified in the area. Remediation might be appropriate if exposure of future potential users is concern. Alternatives discussed for remediation of groundwater contamination in the upper aquifer at the PX Service Station include no-action, soil vapor extraction, and groundwater pumping and treatment alternatives

Groundwater management based on monitoring of land subsidence and groundwater levels in the Kanto Groundwater Basin, Central Japan

Science.gov (United States)

Furuno, K.; Kagawa, A.; Kazaoka, O.; Kusuda, T.; Nirei, H.

2015-11-01

Over 40 million people live on and exploit the groundwater resources of the Kanto Plain. The Plain encompasses metropolitan Tokyo and much of Chiba Prefecture. Useable groundwater extends to the base of the Kanto Plain, some 2500 to 3000 m below sea level. Much of the Kanto Plain surface is at sea level. By the early 1970s, with increasing urbanization and industrial expansion, local overdraft of groundwater resources caused major ground subsidence and damage to commercial and residential structures as well as to local and regional infrastructure. Parts of the lowlands around Tokyo subsided to 4.0 m below sea level; particularly affected were the suburbs of Funabashi and Gyotoku in western Chiba. In the southern Kanto Plain, regulations, mainly by local government and later by regional agencies, led to installation of about 500 monitoring wells and almost 5000 bench marks by the 1990's. Many of them are still working with new monitoring system. Long-term monitoring is important. The monitoring systems are costly, but the resulting data provide continuous measurement of the "health" of the Kanto Groundwater Basin, and thus permit sustainable use of the groundwater resource.

Groundwater Availability Within the Salton Sea Basin Final Report

Energy Technology Data Exchange (ETDEWEB)

Tompson, A; Demir, Z; Moran, J; Mason, D; Wagoner, J; Kollet, S; Mansoor, K; McKereghan, P

2008-01-11

It is widely recognized that increasing demands for water in Southern California are being affected by actions to reduce and redirect the amount of water imported from the Colorado River. In the Imperial Valley region, for example, import reductions will not only affect agricultural users but also could produce significant collateral impacts on the level and quality of water in the Salton Sea, its regional ecology, or even the long term air quality in the greater basin. The notion of using groundwater in the Imperial Valley as an additional source for agricultural or domestic needs, energy production, or Salton Sea restoration efforts, so as to offset reductions in imported water, is not a new concept. Even though it has been discussed recently (e.g., LLNL, 2002), the idea goes back, in part, to several studies performed by the US Department of Interior and other agencies that have indicated that there may be substantial, usable amounts of groundwater in some portions of the Imperial Valley. It has been estimated, for example, that between 1.1 and 3 billion acre-feet (AF) of groundwater lie within the extended, deep basin underlying the valley and Salton Sea region, even though much of it may be unrecoverable or too poor in its quality (Imperial County, 1997). This is a significant volume with respect to the total annual precipitation volume received in California, whose average is close to 200 million (or 0.2 billion) AF per year (DWR, 1998), and especially with respect to the total annual precipitation received in the Salton Sea watershed itself, which we estimate (Appendix A) to be approximately 2.5 million acre feet (MAF) per year. Clearly, a thorough appraisal of the groundwater resources in the Imperial Valley and Salton Sea region--i.e., an assessment of their overall physical availability--will be needed to determine how they can be used and managed to suit new or redirected demands in the region. Development of an improved or updated groundwater assessment

Radiological characterisation and radon equilibrium factor in the outdoor air of a post-industrial urban area

International Nuclear Information System (INIS)

Rozas, S.; Idoeta, R.; Alegría, N.; Herranz, M.

2016-01-01

of determining activity concentrations for each naturally occurring radionuclide and the equilibrium factor in the outdoor air. - Highlights: • A yearlong full radiological picture of a post-industrial area's air is shown. • The method considers isotopes collection, ingrowth and decay during sampling. • The method is based on early and delayed gamma measurements after sampling. • Past industries' committed impact on the air radiological quality is assessed. • Influence of environmental parameters on equilibrium factor is analysed.

Effect of Monsoon on spatio-temporal variation of groundwater chemistry and stable isotopic signatures: insights for concomitant arsenic mobilization in West Bengal, India

Science.gov (United States)

Majumder, S.; Datta, S.; Nath, B.; Neidhardt, H.; Roman-Ross, G.; Berner, Z.; Hidalgo, M.; Chatterjee, D.; Sarkar, S.

2017-12-01

Large-scale groundwater abstraction was hypothesized to be one of the important factors controlling release and distribution of arsenic (As) in aquifers of Bengal Basin. In this study, we studied the groundwater/surface water geochemistry of two different geomorphic domains within the Chakdaha Block, West Bengal, to identify potential influences of groundwater withdrawal on the hydrochemical evolution of the aquifer. This has been done as a function of different water inputs (monsoon rain, irrigation and downward percolation from surface water impoundments) to the groundwater system and associated As mobilization. A low-land flood plain (with relatively more reducing aquifer) and a natural levee (less reducing aquifer) have been chosen for this purpose. The stable isotopic signatures of oxygen (δ18O) and hydrogen (δ2H) falls sub-parallel to the Global Meteoric Water Line (GMWL), with precipitation and subsequent evaporation seems to be the major controlling factor on the water isotopic composition. This shows a contribution of evaporation influenced water, derived from various surface water bodies, pointing at large-scale groundwater withdrawal helping drawdown of the evaporated surface water. In case of flood plain wells, the stable isotope composition and the Cl/Br molar ratio in local groundwater have revealed vertical recharge within the flood plain area to be the major recharge process, especially during the post-monsoon season. However, both evaporation and vertical mixing are visibly controlling the groundwater recharge in the natural levee area. A possible inflow of organic carbon to the aquifer during the monsoonal recharge process is noticeable, with an increase in dissolved organic carbon (DOC) concentration from 1.33 to 6.29 mg/L on passing from pre- to post-monsoon season. Concomitant increase in AsT, Fe(II) and HCO3- during the post monsoon season, being more pronounced in the flood plain samples, indicates a possible initial episode of reductive

Geochemical investigation of groundwater in the Tono area, Japan. Chemical characteristics and groundwater evolution

International Nuclear Information System (INIS)

Iwatsuki, Teruki; Hama, Katsuhiro; Yoshida, Hidekazu

1997-01-01

Geochemical investigations form an important part of the R and D program at the Tono study site, central Japan. Detailed geological structure and groundwater chemistry have been studied to understand the geochemical environment in the sedimentary and crystalline rocks distributed in this area. The chemical evolution of the groundwater in the sedimentary rocks is characterized with the variation in Na + , Ca 2+ and HCO 3 - concentrations, and ion exchange and dissolution of calcite are dominant reactions in the evolution of groundwater. Geological investigation shows that a fracture system of crystalline rock can be classified into:intact zone, moderately fractured zone and intensely fractured zone, according to the frequency and the width of fractures and fractured zones. The groundwater in the intact and fractured zones of crystalline rock are characterized by Na + -Ca 2+ -HCO 3 - or Na + -HCO 3 - dominated water, and Na + -Ca 2+ -Fe 2+ -HCO 3 - dominated water. The chemical evolution of groundwater is, generally, controlled by water-rock interaction between plagioclase, iron minerals and groundwater. The groundwater at depth of G.L.-186m in the crystalline rock at the Tono area is characterized by the mixture between the oxidized surface water and the reduced groundwater. The investigation based on correlation between geological structures and groundwater chemistry can be applied to understand the geochemical environment in deep crystalline rock, and will support the development of a realistic hydrogeochemical model. (author)

Paleo-channel deposition of natural uranium at a US Air Force landfill

International Nuclear Information System (INIS)

Young, Carl; Weismann, Joseph; Caputo, Daniel

2007-01-01

Available in abstract form only. Full text of publication follows: The US Air Force sought to identify the source of radionuclides that were detected in groundwater surrounding a closed solid waste landfill at the former Lowry Air Force Base in Denver, Colorado, USA. Gross alpha, gross beta, and uranium levels in groundwater were thought to exceed US drinking water standards and down-gradient concentrations exceeded up-gradient concentrations. Our study has concluded that the elevated radionuclide concentrations are due to naturally-occurring uranium in the regional watershed and that the uranium is being released from paleo-channel sediments beneath the site. Groundwater samples were collected from monitor wells, surface water and sediments over four consecutive quarters. A list of 23 radionuclides was developed for analysis based on historical landfill records. Concentrations of major ions and metals and standard geochemical parameters were analyzed. The only radionuclide found to be above regulatory standards was uranium. A search of regional records shows that uranium is abundant in the upstream drainage basin. Analysis of uranium isotopic ratios shows that the uranium has not been processed for enrichment nor is it depleted uranium. There is however slight enrichment in the U-234:U- 238 activity ratio, which is consistent with uranium that has undergone aqueous transport. Comparison of up-gradient versus down-gradient uranium concentrations in groundwater confirms that higher uranium concentrations are found in the down-gradient wells. The US drinking water standard of 30 μg/L for uranium was exceeded in some of the up-gradient wells and in most of the down-gradient wells. Several lines of evidence indicate that natural uranium occurring in streams has been preferentially deposited in paleo-channel sediments beneath the site, and that the paleo-channel deposits are causing the increased uranium concentrations in down-gradient groundwater compared to up

Groundwater recharge, circulation and geochemical evolution in the source region of the Blue Nile River, Ethiopia

International Nuclear Information System (INIS)

Kebede, Seifu; Travi, Yves; Alemayehu, Tamiru; Ayenew, Tenalem

2005-01-01

Geochemical and environmental isotope data were used to gain the first regional picture of groundwater recharge, circulation and its hydrochemical evolution in the upper Blue Nile River basin of Ethiopia. Q-mode statistical cluster analysis (HCA) was used to classify water into objective groups and to conduct inverse geochemical modeling among the groups. Two major structurally deformed regions with distinct groundwater circulation and evolution history were identified. These are the Lake Tana Graben (LTG) and the Yerer Tullu Wellel Volcanic Lineament Zone (YTVL). Silicate hydrolysis accompanied by CO 2 influx from deeper sources plays a major role in groundwater chemical evolution of the high TDS Na-HCO 3 type thermal groundwaters of these two regions. In the basaltic plateau outside these two zones, groundwater recharge takes place rapidly through fractured basalts, groundwater flow paths are short and they are characterized by low TDS and are Ca-Mg-HCO 3 type waters. Despite the high altitude (mean altitude ∼2500 masl) and the relatively low mean annual air temperature (18 deg. C) of the region compared to Sahelian Africa, there is no commensurate depletion in δ 18 O compositions of groundwaters of the Ethiopian Plateau. Generally the highland areas north and east of the basin are characterized by relatively depleted δ 18 O groundwaters. Altitudinal depletion of δ 18 O is 0.1%o/100 m. The meteoric waters of the Blue Nile River basin have higher d-excess compared to the meteoric waters of the Ethiopian Rift and that of its White Nile sister basin which emerges from the equatorial lakes region. The geochemically evolved groundwaters of the YTVL and LTG are relatively isotopically depleted when compared to the present day meteoric waters reflecting recharge under colder climate and their high altitude

Groundwater recharge, circulation and geochemical evolution in the source region of the Blue Nile River, Ethiopia

Energy Technology Data Exchange (ETDEWEB)

Kebede, Seifu [Laboratory of Hydrogeology, University of Avignon, 33 Rue Louis Pasteur, 84000 Avignon (France) and Department of Geology and Geophysics, Addis Ababa University, P.O. Box 1176, Addis Ababa (Ethiopia)]. E-mail: seifu.kebede@univ-avignon.fr; Travi, Yves [Laboratory of Hydrogeology, University of Avignon, 33 Rue Louis Pasteur, 84000 Avignon (France); Alemayehu, Tamiru [Department of Geology and Geophysics, Addis Ababa University, P.O. Box 1176, Addis Ababa (Ethiopia); Ayenew, Tenalem [Department of Geology and Geophysics, Addis Ababa University, P.O. Box 1176, Addis Ababa (Ethiopia)

2005-09-15

Geochemical and environmental isotope data were used to gain the first regional picture of groundwater recharge, circulation and its hydrochemical evolution in the upper Blue Nile River basin of Ethiopia. Q-mode statistical cluster analysis (HCA) was used to classify water into objective groups and to conduct inverse geochemical modeling among the groups. Two major structurally deformed regions with distinct groundwater circulation and evolution history were identified. These are the Lake Tana Graben (LTG) and the Yerer Tullu Wellel Volcanic Lineament Zone (YTVL). Silicate hydrolysis accompanied by CO{sub 2} influx from deeper sources plays a major role in groundwater chemical evolution of the high TDS Na-HCO {sub 3} type thermal groundwaters of these two regions. In the basaltic plateau outside these two zones, groundwater recharge takes place rapidly through fractured basalts, groundwater flow paths are short and they are characterized by low TDS and are Ca-Mg-HCO {sub 3} type waters. Despite the high altitude (mean altitude {approx}2500 masl) and the relatively low mean annual air temperature (18 deg. C) of the region compared to Sahelian Africa, there is no commensurate depletion in {delta} {sup 18}O compositions of groundwaters of the Ethiopian Plateau. Generally the highland areas north and east of the basin are characterized by relatively depleted {delta} {sup 18}O groundwaters. Altitudinal depletion of {delta} {sup 18}O is 0.1%o/100 m. The meteoric waters of the Blue Nile River basin have higher d-excess compared to the meteoric waters of the Ethiopian Rift and that of its White Nile sister basin which emerges from the equatorial lakes region. The geochemically evolved groundwaters of the YTVL and LTG are relatively isotopically depleted when compared to the present day meteoric waters reflecting recharge under colder climate and their high altitude.

Modeling the effects of the variability of temperature-related dynamic viscosity on the thermal-affected zone of groundwater heat-pump systems

Science.gov (United States)

Lo Russo, Stefano; Taddia, Glenda; Cerino Abdin, Elena

2018-01-01

Thermal perturbation in the subsurface produced in an open-loop groundwater heat pump (GWHP) plant is a complex transport phenomenon affected by several factors, including the exploited aquifer's hydrogeological and thermal characteristics, well construction features, and the temporal dynamics of the plant's groundwater abstraction and reinjection system. Hydraulic conductivity has a major influence on heat transport because plume propagation, which occurs primarily through advection, tends to degrade following conductive heat transport and convection within moving water. Hydraulic conductivity is, in turn, influenced by water reinjection because the dynamic viscosity of groundwater varies with temperature. This paper reports on a computational analysis conducted using FEFLOW software to quantify how the thermal-affected zone (TAZ) is influenced by the variation in dynamic viscosity due to reinjected groundwater in a well-doublet scheme. The modeling results demonstrate non-negligible groundwater dynamic-viscosity variation that affects thermal plume propagation in the aquifer. This influence on TAZ calculation was enhanced for aquifers with high intrinsic permeability and/or substantial temperature differences between abstracted and post-heat-pump-reinjected groundwater.

Revised conceptualization of the North China Basin groundwater flow system: Groundwater age, heat and flow simulations

Science.gov (United States)

Cao, Guoliang; Han, Dongmei; Currell, Matthew J.; Zheng, Chunmiao

2016-09-01

Groundwater flow in deep sedimentary basins results from complex evolution processes on geological timescales. Groundwater flow systems conceptualized according to topography and/or groundwater table configuration generally assume a near-equilibrium state with the modern landscape. However, the time to reach such a steady state, and more generally the timescales of groundwater flow system evolution are key considerations for large sedimentary basins. This is true in the North China Basin (NCB), which has been studied for many years due to its importance as a groundwater supply. Despite many years of study, there remain contradictions between the generally accepted conceptual model of regional flow, and environmental tracer data. We seek to reconcile these contractions by conducting simulations of groundwater flow, age and heat transport in a three dimensional model, using an alternative conceptual model, based on geological, thermal, isotope and historical data. We infer flow patterns under modern hydraulic conditions using this new model and present the theoretical maximum groundwater ages under such a flow regime. The model results show that in contrast to previously accepted conceptualizations, most groundwater is discharged in the vicinity of the break-in-slope of topography at the boundary between the piedmont and central plain. Groundwater discharge to the ocean is in contrast small, and in general there are low rates of active flow in the eastern parts of the basin below the central and coastal plain. This conceptualization is more compatible with geochemical and geothermal data than the previous model. Simulated maximum groundwater ages of ∼1 Myrs below the central and coastal plain indicate that residual groundwater may be retained in the deep parts of the basin since being recharged during the last glacial period or earlier. The groundwater flow system has therefore probably not reached a new equilibrium state with modern-day hydraulic conditions. The

Hanford Sitewide Groundwater Remediation Strategy

International Nuclear Information System (INIS)

Knepp, A.J.; Isaacs, J.D.

1997-09-01

This document fulfills the requirements of the Hanford Federal Facility Agreement and Consent Order, Milestone M-13-81, to develop a concise statement of strategy that describe show the Hanford Site groundwater remediation will be accomplished. The strategy addresses objectives and goals, prioritization of activities, and technical approaches for groundwater cleanup. The strategy establishes that the overall goal of groundwater remediation on the Hanford Site is to restore groundwater to its beneficial uses in terms of protecting human health and the environment, and its use as a natural resource. The Hanford Future Site Uses Working Group established two categories for groundwater commensurate with various proposed landuses: (1) restricted use or access to groundwater in the Central Plateau and in a buffer zone surrounding it and (2) unrestricted use or access to groundwater for all other areas. In recognition of the Hanford Future Site Uses Working Group and public values, the strategy establishes that the sitewide approach to groundwater cleanup is to remediate the major plumes found in the reactor areas that enter the Columbia River and to contain the spread and reduce the mass of the major plumes found in the Central Plateau

Technical approach to groundwater restoration

International Nuclear Information System (INIS)

1993-01-01

The Technical Approach to Groundwater Restoration (TAGR) provides general technical guidance to implement the groundwater restoration phase of the Uranium Mill Tailings Remedial Action (UMTRA) Project. The TAGR includes a brief overview of the surface remediation and groundwater restoration phases of the UMTRA Project and describes the regulatory requirements, the National Environmental Policy Act (NEPA) process, and regulatory compliance. A section on program strategy discusses program optimization, the role of risk assessment, the observational approach, strategies for meeting groundwater cleanup standards, and remedial action decision-making. A section on data requirements for groundwater restoration evaluates the data quality objectives (DQO) and minimum data required to implement the options and comply with the standards. A section on sits implementation explores the development of a conceptual site model, approaches to site characterization, development of remedial action alternatives, selection of the groundwater restoration method, and remedial design and implementation in the context of site-specific documentation in the site observational work plan (SOWP) and the remedial action plan (RAP). Finally, the TAGR elaborates on groundwater monitoring necessary to evaluate compliance with the groundwater cleanup standards and protection of human health and the environment, and outlines licensing procedures

Investigation of the groundwater composition at potential radioactive waste disposal sites in Sweden

International Nuclear Information System (INIS)

Wikberg, P.T.

1984-02-01

Within an investigation program of sites suitable for an underground repository for spent nuclear fuel the groundwater has been characterized. Until now seven areas have been investigated. The groundwater has been pumped up from several isolated sections at depth of 100 m to 600 m in boreholes in each area. Each test section has been pumped continuously for at least two weeks. During the pumping period the water was characterized in the field and sampled for later analysis. Most of the characterized waters are non saline and the concentration of the different constituents varies within a rather narrow interval. Saline waters with much higher concentrations of chloride, sulphate, sodium and calcium have been encountered. The groundwater characterization includes field monitoring of the physico-chemical parameters pH, redox potential, free sulphide concentration, dissolved oxygen concentration and conductivity. These parameters are measured in a flow through cell where the water passes before coming in contact with the air. The redox potential measurements have been successful. A new equipment for measurements in the sampling section has been constructed. Preliminary tests have given very promising results

Subsurface Transport Behavior of Micro-Nano Bubbles and Potential Applications for Groundwater Remediation

Directory of Open Access Journals (Sweden)

Hengzhen Li

2013-12-01

Full Text Available Micro-nano bubbles (MNBs are tiny bubbles with diameters on the order of micrometers and nanometers, showing great potential in environmental remediation. However, the application is only in the beginning stages and remains to be intensively studied. In order to explore the possible use of MNBs in groundwater contaminant removal, this study focuses on the transport of MNBs in porous media and dissolution processes. The bubble diameter distribution was obtained under different conditions by a laser particle analyzer. The permeability of MNB water through sand was compared with that of air-free water. Moreover, the mass transfer features of dissolved oxygen in water with MNBs were studied. The results show that the bubble diameter distribution is influenced by the surfactant concentration in the water. The existence of MNBs in pore water has no impact on the hydraulic conductivity of sand. Furthermore, the dissolved oxygen (DO in water is greatly increased by the MNBs, which will predictably improve the aerobic bioremediation of groundwater. The results are meaningful and instructive in the further study of MNB research and applications in groundwater bioremediation.

A method of groundwater quality assessment based on fuzzy network-CANFIS and geographic information system (GIS)

Science.gov (United States)

Gholami, V.; Khaleghi, M. R.; Sebghati, M.

2017-11-01

The process of water quality testing is money/time-consuming, quite important and difficult stage for routine measurements. Therefore, use of models has become commonplace in simulating water quality. In this study, the coactive neuro-fuzzy inference system (CANFIS) was used to simulate groundwater quality. Further, geographic information system (GIS) was used as the pre-processor and post-processor tool to demonstrate spatial variation of groundwater quality. All important factors were quantified and groundwater quality index (GWQI) was developed. The proposed model was trained and validated by taking a case study of Mazandaran Plain located in northern part of Iran. The factors affecting groundwater quality were the input variables for the simulation, whereas GWQI index was the output. The developed model was validated to simulate groundwater quality. Network validation was performed via comparison between the estimated and actual GWQI values. In GIS, the study area was separated to raster format in the pixel dimensions of 1 km and also by incorporation of input data layers of the Fuzzy Network-CANFIS model; the geo-referenced layers of the effective factors in groundwater quality were earned. Therefore, numeric values of each pixel with geographical coordinates were entered to the Fuzzy Network-CANFIS model and thus simulation of groundwater quality was accessed in the study area. Finally, the simulated GWQI indices using the Fuzzy Network-CANFIS model were entered into GIS, and hence groundwater quality map (raster layer) based on the results of the network simulation was earned. The study's results confirm the high efficiency of incorporation of neuro-fuzzy techniques and GIS. It is also worth noting that the general quality of the groundwater in the most studied plain is fairly low.

Compliance Groundwater Monitoring of Nonpoint Sources - Emerging Approaches

Science.gov (United States)

Harter, T.

2008-12-01

Groundwater monitoring networks are typically designed for regulatory compliance of discharges from industrial sites. There, the quality of first encountered (shallow-most) groundwater is of key importance. Network design criteria have been developed for purposes of determining whether an actual or potential, permitted or incidental waste discharge has had or will have a degrading effect on groundwater quality. The fundamental underlying paradigm is that such discharge (if it occurs) will form a distinct contamination plume. Networks that guide (post-contamination) mitigation efforts are designed to capture the shape and dynamics of existing, finite-scale plumes. In general, these networks extend over areas less than one to ten hectare. In recent years, regulatory programs such as the EU Nitrate Directive and the U.S. Clean Water Act have forced regulatory agencies to also control groundwater contamination from non-incidental, recharging, non-point sources, particularly agricultural sources (fertilizer, pesticides, animal waste application, biosolids application). Sources and contamination from these sources can stretch over several tens, hundreds, or even thousands of square kilometers with no distinct plumes. A key question in implementing monitoring programs at the local, regional, and national level is, whether groundwater monitoring can be effectively used as a landowner compliance tool, as is currently done at point-source sites. We compare the efficiency of such traditional site-specific compliance networks in nonpoint source regulation with various designs of regional nonpoint source monitoring networks that could be used for compliance monitoring. We discuss advantages and disadvantages of the site vs. regional monitoring approaches with respect to effectively protecting groundwater resources impacted by nonpoint sources: Site-networks provide a tool to enforce compliance by an individual landowner. But the nonpoint source character of the contamination

TREATABILITY TEST FOR REMOVING TECHNETIUM-99 FROM 200-ZP-1 GROUNDWATER HANFORD SITE

Energy Technology Data Exchange (ETDEWEB)

PETERSEN SW; TORTOSO AC; ELLIOTT WS; BYRNES ME

2007-11-29

The 200-ZP-1 Groundwater Operable Unit (OU) is one of two groundwater OUs located within the 200 West groundwater aggregate area of the Hanford Site. The primary risk-driving contaminants within the 200-ZP-1 OU include carbon tetrachloride and technetium-99 (Tc-99). A pump-and-treat system for this OU was initially installed in 1995 to control the 0.002 kg/m{sup 3} (2000 {micro}g/L) contour of the carbon tetrachloride plume. Carbon tetrachloride is removed from groundwater with the assistance of an air-stripping tower. Ten extraction wells and three injection wells operate at a combined rate of approximately 0.017m{sup 3}/s (17.03 L/s). In 2005, groundwater from two of the extraction wells (299-W15-765 and 299-W15-44) began to show concentrations greater than twice the maximum contaminant level (MCL) of Tc-99 (33,309 beq/m{sup 3} or 900 pCi/L). The Tc-99 groundwater concentrations from all ten of the extraction wells when mixed were more than one-half of the MCL and were slowly increasing. If concentrations continued to rise and the water remained untreated for Tc-99, there was concern that the water re-injected into the aquifer could exceed the MCL standard. Multiple treatment technologies were reviewed for selectively removing Tc-99 from the groundwater. Of the treatment technologies, only ion exchange was determined to be highly selective, commercially available, and relatively low in cost. Through research funded by the U.S. Department of Energy, the ion-exchange resin Purolite{reg_sign} A-530E was found to successfully remove Tc-99 from groundwater, even in the presence of competing anions. For this and other reasons, Purolite{reg_sign} A-530E ion exchange resin was selected for treatability testing. The treatability test required installing resin columns on the discharge lines from extraction wells 299-W15-765 and 299-W15-44. Preliminary test results have concluded that the Purolite{reg_sign} A-530E resin is effective at removing Tc-99 from groundwater to

Approaches to groundwater travel time

International Nuclear Information System (INIS)

Kaplan, P.; Klavetter, E.; Peters, R.

1989-01-01

One of the objectives of performance assessment for the Yucca Mountain Project is to estimate the groundwater travel time at Yucca Mountain, Nevada, to determine whether the site complies with the criteria specified in the Code of Federal Regulations, Title 10 CFR 60.113 (a). The numerical standard for performance in these criteria is based on the groundwater travel time along the fastest path of likely radionuclide transport from the disturbed zone to the accessible environment. The concept of groundwater travel time as proposed in the regulations, does not have a unique mathematical statement. The purpose of this paper is to discuss the ambiguities associated with the regulatory specification of groundwater travel time, two different interpretations of groundwater travel time, and the effect of the two interpretations on estimates of the groundwater travel time

Monsoonal influence on variation of hydrochemistry and isotopic signatures: Implications for associated arsenic release in groundwater

Science.gov (United States)

Majumder, Santanu; Datta, Saugata; Nath, Bibhash; Neidhardt, Harald; Sarkar, Simita; Roman-Ross, Gabriela; Berner, Zsolt; Hidalgo, Manuela; Chatterjee, Debankur; Chatterjee, Debashis

2016-04-01

The present study examines the groundwater and surface water geochemistry of two different geomorphic domains within the Chakdaha block, West Bengal, in an attempt to decipher potential influences of groundwater abstraction on the hydrochemical evolution of the aquifer, the effect of different water inputs (monsoon rain, irrigation and downward percolation from surface water impoundments) to the groundwater system and concomitant As release. A low-land flood plain and a natural levee have been selected for this purpose. Although the stable isotopic signatures of oxygen (δ18O) and hydrogen (δ2H) are largely controlled by local precipitation, the isotopic composition falls sub-parallel to the Global Meteoric Water Line (GMWL). The Cl/Br molar ratio indicates vertical recharge into the wells within the flood plain area, especially during the post-monsoon season, while influences of both evaporation and vertical mixing are visible within the natural levee wells. Increase in mean DOC concentrations (from 1.33 to 6.29 mg/L), from pre- to post-monsoon season, indicates possible inflow of organic carbon to the aquifer during the monsoonal recharge. Concomitant increase in AsT, Fe(II) and HCO3- highlights a possible initial episode of reductive dissolution of As-rich Fe-oxyhydroxides. The subsequent sharp increase in the mean As(III) proportions (by 223%), particularly in the flood plain samples during the post-monsoon season, which is accompanied by a slight increase in mean AsT (7%) may refer to anaerobic microbial degradation of DOC coupled with the reduction of As(V) to As(III) without triggering additional As release from the aquifer sediments.

Groundwater Discharge of Legacy Nitrogen to River Networks: Linking Regional Groundwater Models to Streambed Groundwater-Surface Water Exchange and Nitrogen Processing

Science.gov (United States)

Barclay, J. R.; Helton, A. M.; Briggs, M. A.; Starn, J. J.; Hunt, A.

2017-12-01

Despite years of management, excess nitrogen (N) is a pervasive problem in many aquatic ecosystems. More than half of surface water in the United States is derived from groundwater, and widespread N contamination in aquifers from decades of watershed N inputs suggest legacy N discharging from groundwater may contribute to contemporary N pollution problems in surface waters. Legacy N loads to streams and rivers are controlled by both regional scale flow paths and fine-scale processes that drive N transformations, such as groundwater-surface water exchange across steep redox gradients that occur at stream bed interfaces. Adequately incorporating these disparate scales is a challenge, but it is essential to understanding legacy N transport and making informed management decisions. We developed a regional groundwater flow model for the Farmington River, a HUC-8 basin that drains to the Long Island Sound, a coastal estuary that suffers from elevated N loads despite decades of management, to understand broad patterns of regional transport. To evaluate and refine the regional model, we used thermal infrared imagery paired with vertical temperature profiling to estimate groundwater discharge at the streambed interface. We also analyzed discharging groundwater for multiple N species to quantify fine scale patterns of N loading and transformation via denitrification at the streambed interface. Integrating regional and local estimates of groundwater discharge of legacy N to river networks should improve our ability to predict spatiotemporal patterns of legacy N loading to and transformation within surface waters.

Technical framework for groundwater restoration

International Nuclear Information System (INIS)

1991-04-01

This document provides the technical framework for groundwater restoration under Phase II of the Uranium Mill Tailings Remedial Action (UMTRA) Project. A preliminary management plan for Phase II has been set forth in a companion document titled ''Preplanning Guidance Document for Groundwater Restoration''. General principles of site characterization for groundwater restoration, restoration methods, and treatment are discussed in this document to provide an overview of standard technical approaches to groundwater restoration

Chemical and radiochemical characteristics of groundwater in the Culebra Dolomite, southeastern New Mexico

International Nuclear Information System (INIS)

Chapmen, J.B.

1988-03-01

The nation's first geologic repository for radioactive waste is being excavated in southeastern New Mexico at the Waste Isolation Pilot Plant (WIPP). Post-closure radioactive release scenarios from WIPP often involve hydrologic transport of radionuclides through the overlying Rustler Formation, in the Culebra Dolomite Member. The Environmental Evaluation Group (EEG) has conducted an investigation of the chemistry of culebra groundwater. Analysis revealed the following: salinities in Culebra groundwater generally increase from west to east; a Na-Cl type water dominates over most of the sampled area with a Ca-SO 4 type occurring in the southern to southwestern area; exclusive of the low-salinity southern area, most wells located on the same general flow path have similar ion ratios; dissolved uranium content in Culebra groundwater is relatively high, with marked disequilibrium between U-238 and U-234 activities; Ra-226 and Ra-228 are sometimes present in relatively large amounts; Th-228 was detected in samples from 5 wells; and Cs-137 was detected in several samples. 39 refs., 21 figs., 2 tabs

Integrated groundwater data management

Science.gov (United States)

Fitch, Peter; Brodaric, Boyan; Stenson, Matt; Booth, Nathaniel; Jakeman, Anthony J.; Barreteau, Olivier; Hunt, Randall J.; Rinaudo, Jean-Daniel; Ross, Andrew

2016-01-01

The goal of a data manager is to ensure that data is safely stored, adequately described, discoverable and easily accessible. However, to keep pace with the evolution of groundwater studies in the last decade, the associated data and data management requirements have changed significantly. In particular, there is a growing recognition that management questions cannot be adequately answered by single discipline studies. This has led a push towards the paradigm of integrated modeling, where diverse parts of the hydrological cycle and its human connections are included. This chapter describes groundwater data management practices, and reviews the current state of the art with enterprise groundwater database management systems. It also includes discussion on commonly used data management models, detailing typical data management lifecycles. We discuss the growing use of web services and open standards such as GWML and WaterML2.0 to exchange groundwater information and knowledge, and the need for national data networks. We also discuss cross-jurisdictional interoperability issues, based on our experience sharing groundwater data across the US/Canadian border. Lastly, we present some future trends relating to groundwater data management.

Groundwater: from mystery to management

International Nuclear Information System (INIS)

Narasimhan, T N

2009-01-01

Groundwater has been used for domestic and irrigation needs from time immemorial. Yet its nature and occurrence have always possessed a certain mystery because water below the land surface is invisible and relatively inaccessible. The influence of this mystery lingers in some tenets that govern groundwater law. With the birth of modern geology during the late nineteenth century, groundwater science became recognized in its own right. Over the past two centuries, groundwater has lost its shroud of mystery, and its scientific understanding has gradually grown hand-in-hand with its development for human use. Groundwater is a component of the hydrological cycle, vital for human sustenance. Its annual renewability from precipitation is limited, and its chemical quality is vulnerable to degradation by human action. In many parts of the world, groundwater extraction is known to greatly exceed its renewability. Consequently, its rational management to benefit present and future generations is a matter of deep concern for many nations. Groundwater management is a challenging venture, requiring an integration of scientific knowledge with communal will to adapt to constraints of a finite common resource. As scientists and policy makers grapple with the tasks of groundwater management, it is instructive to reflect on the evolution of groundwater knowledge from its initial phase of demystification at the beginning of the nineteenth century, through successive phases of technological conquest, scientific integration, discovery of unintended consequences and the present recognition of an imperative for judicious management. The following retrospective provides a broad context for unifying the technical contributions that make up this focus issue on groundwater resources, climate and vulnerability.

Dynamics of Agricultural Groundwater Extraction

NARCIS (Netherlands)

Hellegers, P.J.G.J.; Zilberman, D.; Ierland, van E.C.

2001-01-01

Agricultural shallow groundwater extraction can result in desiccation of neighbouring nature reserves and degradation of groundwater quality in the Netherlands, whereas both externalities are often not considered when agricultural groundwater extraction patterns are being determined. A model is

Groundwater protection management program plan

International Nuclear Information System (INIS)

1992-06-01

US Department of Energy (DOE) Order 5400.1 requires the establishment of a groundwater protection management program to ensure compliance with DOE requirements and applicable Federal, state, and local laws and regulations. The Uranium Mill Tailings Remedial Action (UMTRA) Project Office has prepared a ''Groundwater Protection Management Program Plan'' (groundwater protection plan) of sufficient scope and detail to reflect the program's significance and address the seven activities required in DOE Order 5400.1, Chapter 3, for special program planning. The groundwater protection plan highlights the methods designed to preserve, protect, and monitor groundwater resources at UMTRA Project processing and disposal sites. The plan includes an overview of the remedial action status at the 24 designated processing sites and identifies project technical guidance documents and site-specific documents for the UMTRA groundwater protection management program. In addition, the groundwater protection plan addresses the general information required to develop a water resources protection strategy at the permanent disposal sites. Finally, the plan describes ongoing activities that are in various stages of development at UMTRA sites (long-term care at disposal sites and groundwater restoration at processing sites). This plan will be reviewed annually and updated every 3 years in accordance with DOE Order 5400.1

Groundwater monitoring of an open-pit limestone quarry: groundwater characteristics, evolution and their connections to rock slopes.

Science.gov (United States)

Eang, Khy Eam; Igarashi, Toshifumi; Fujinaga, Ryota; Kondo, Megumi; Tabelin, Carlito Baltazar

2018-03-06

Groundwater flow and its geochemical evolution in mines are important not only in the study of contaminant migration but also in the effective planning of excavation. The effects of groundwater on the stability of rock slopes and other mine constructions especially in limestone quarries are crucial because calcite, the major mineral component of limestone, is moderately soluble in water. In this study, evolution of groundwater in a limestone quarry located in Chichibu city was monitored to understand the geochemical processes occurring within the rock strata of the quarry and changes in the chemistry of groundwater, which suggests zones of deformations that may affect the stability of rock slopes. There are three distinct geological formations in the quarry: limestone layer, interbedded layer of limestone and slaty greenstone, and slaty greenstone layer as basement rock. Although the hydrochemical facies of all groundwater samples were Ca-HCO 3 type water, changes in the geochemical properties of groundwater from the three geological formations were observed. In particular, significant changes in the chemical properties of several groundwater samples along the interbedded layer were observed, which could be attributed to the mixing of groundwater from the limestone and slaty greenstone layers. On the rainy day, the concentrations of Ca 2+ and HCO 3 - in the groundwater fluctuated notably, and the groundwater flowing along the interbedded layer was dominated by groundwater from the limestone layer. These suggest that groundwater along the interbedded layer may affect the stability of rock slopes.

Approaches to groundwater travel time

International Nuclear Information System (INIS)

Kaplan, P.; Klavetter, E.; Peters, R.

1989-01-01

One of the objectives of performance assessment for the Yucca Mountain Project is to estimate the groundwater travel time at Yucca Mountain, Nevada, to determine whether the site complies with the criteria specified in the Code of Federal Regulations. The numerical standard for performance in these criteria is based on the groundwater travel time along the fastest path of likely radionuclide transport from the disturbed zone to the accessible environment. The concept of groundwater travel time, as proposed in the regulations, does not have a unique mathematical statement. The purpose of this paper is to discuss (1) the ambiguities associated with the regulatory specification of groundwater travel time, (2) two different interpretations of groundwater travel time, and (3) the effect of the two interpretations on estimates of the groundwater travel time. 3 refs., 2 figs., 2 tabs

Why is the Groundwater Level Rising? A Case Study Using HARTT to Simulate Groundwater Level Dynamic.

Science.gov (United States)

Yihdego, Yohannes; Danis, Cara; Paffard, Andrew

2017-12-01

  Groundwater from a shallow unconfined aquifer at a site in coastal New South Wales has been causing recent water logging issues. A trend of rising groundwater level has been anecdotally observed over the last 10 years. It was not clear whether the changes in groundwater levels were solely natural variations within the groundwater system or whether human interference was driving the level up. Time series topographic images revealed significant surrounding land use changes and human modification to the environment of the groundwater catchment. A statistical model utilising HARTT (multiple linear regression hydrograph analysis method) simulated the groundwater level dynamics at five key monitoring locations and successfully showed a trend of rising groundwater level. Utilising hydrogeological input from field investigations, the model successfully simulated the rise in the water table over time to the present day levels, whilst taking into consideration rainfall and land changes. The underlying geological/land conditions were found to be just as significant as the impact of climate variation. The correlation coefficient for the monitoring bores (MB), excluding MB4, show that the groundwater level fluctuation can be explained by the climate variable (rainfall) with the lag time between the atypical rainfall and groundwater level ranging from 4 to 7 months. The low R2 value for MB4 indicates that there are factors missing in the model which are primarily related to human interference. The elevated groundwater levels in the affected area are the result of long term cumulative land use changes, instigated by humans, which have directly resulted in detrimental changes to the groundwater aquifer properties.

ECOLO-HOUSE in the heavy snow-fall region. Ground-water and wasted-wood become resources by utilizing storage-tank; Yukiguni ECOLO-HOUSE. Chikunetsuso wo riyoshita chikasui oyobi mokushitsu gomi no shigenka

Energy Technology Data Exchange (ETDEWEB)

Umemiya, H; Fukumuro, S [Yamagata University, Yamagata (Japan)

1997-11-25

This paper reports living comfort in summer by operating a groundwater utilization system using a hot water storage tank and a floor air conditioning system. The groundwater utilization system is a system for room cooling by using groundwater and for supplying water for living use. The system operates as follows: groundwater is passed through a coil-type heat exchanger having pipes each 100 m long laid in parallel for a total length of 200 m, the heat exchanger being installed in a hot water storage tank; the water is used to cool water in the storage tank in summer; and the water is warmed up in the storage tank in winter, further heated by an oil boiler to be used as hot water for cooking and bathing. In the floor air conditioning system, cold water in the water storage tank (warm water in winter) is pumped up by a circulation pump, and passed through the floor air conditioning circuit having a pipe with a total length of 400 m at a flow rate of 14 liters per minute. The system is of a closed circuit in which the water is re-heated by a wood burning boiler in winter and returned to the hot water storage tank. The amount of supplied cold heat from groundwater to the hot water tank obtained on a daily average is 90W. About 20% of the monthly cumulative cold heat amount dissipated from the floor circuit is the monthly cumulative cold heat amount supplied from the groundwater circuit to the hot water storage tank. 1 ref., 10 figs., 1 tab.

A national environmental/energy workforce assessment. Post-secondary education profile: air. Final report on phase 2

International Nuclear Information System (INIS)

1978-12-01

This study is one of 16 volumes aggregating data on representative environmental education offerings in the United States at post-secondary education institutions and in the private sector of the economy. Structured around on-site interviews, the study describes the institutions' education programs--their program structure, representative course offerings, faculty structure, and program requirements. In addition, the study provides information on the employment history of graduates. Designed as Phase II of a three-phase program, the study presents the information on schools with emphasis on air pollution. The study is an overview. It doesn't include all environmental programs in the United States, and it makes no attempt to evaluate the program offerings

Groundwater heat pump performance improvement with pre-coolers and pump modification: Final report for the 1985-86 SOMED (School of Mines and Energy Development) project year

Energy Technology Data Exchange (ETDEWEB)

Kavanaugh, S.

1986-09-30

Improved performance of groundwater heat pumps can be realized with a more effective and efficient utilization of the thermal properties of shallow groundwater. These systems circulate water from aquifers through water source heat pumps to achieved high efficiencies and capacities. This project concludes that a 10 to 15 percent cooling performance improvement can be realized by pre-cooling the room air with the 55/sup 0/ to 67/sup 0/F groundwater available in large portions of the Southeast. Proper design of these pre-coolers eliminates unnecessary auxiliary energy requirements. The efficiency of the overall system can be further improved with modifications to current methods of water circulation system design. Pressure requirements are minimized by maintaining a low unit inlet pressure (8 psig maximum), removing unnecessary loop restrictions and injection below the water table. Standard submersible water pumps exceed the resulting required size for residential groundwater heat pumps. Simple modifications can be made by the manufacturer to correct this problem. The result is an overall 15 to 40 percent performance improvement over high efficiency air source heat pumps with a simple payback of between 0 to 10 years in most cases.

Effects of intensive urbanization on the intrusion of shallow groundwater into deep groundwater: Examples from Bangkok and Jakarta

International Nuclear Information System (INIS)

Onodera, Shin-ichi; Saito, Mitsuyo; Sawano, Misa; Hosono, Takahiro; Taniguchi, Makoto; Shimada, Jun; Umezawa, Yu; Lubis, Rachmat Fajar; Buapeng, Somkid; Delinom, Robert

2008-01-01

Asian megacities have severe pollution problems in both coastal and urban areas. In addition, the groundwater potential has decreased and land subsidence has occurred because of intensive groundwater pumping in urban areas. To prevent the adverse effects of urbanization on groundwater quality, it is necessary to confirm the changes in groundwater flow and contaminant transport caused by urbanization. We examined the effects of urbanization on contaminant transport in groundwater. The research areas were located around Bangkok, Thailand, and akarta, Indonesia, cities with populations of approximately 8 and 12 million, respectively. Each metropolitan city is located on a river delta and is adjacent to a bay. We measured the water level and collected water samples at boreholes at multiple depths (100 to 200 m) in 2004 and 2006 in Bangkok and Jakarta, respectively. The current hydraulic potential is below sea level in both cities because of prior excess abstraction of groundwater. As a result, the direction of groundwater flow is now downward in the coastal area. The Cl - concentration and δ 18 O distributions in groundwater suggest that the decline in hydraulic potential has caused the intrusion of seawater and shallow groundwater into deep groundwater. Concentrations of Mn and NO3 - -N in groundwater suggest the intrusion of these contaminants from shallow to deep aquifers with downward groundwater flow and implies an accumulation of contaminants in deep aquifers. Therefore, it is important to recognize the possibility of future contaminant transport with the discharge of deep groundwater into the sea after the recovery of groundwater potential in the coastal areas

Hanford groundwater scenario studies

International Nuclear Information System (INIS)

Arnett, R.C.; Gephart, R.E.; Deju, R.A.; Cole, C.R.; Ahlstrom, S.W.

1977-05-01

This report documents the results of two Hanford groundwater scenario studies. The first study examines the hydrologic impact of increased groundwater recharge resulting from agricultural development in the Cold Creek Valley located west of the Hanford Reservation. The second study involves recovering liquid radioactive waste which has leaked into the groundwater flow system from a hypothetical buried tank containing high-level radioactive waste. The predictive and control capacity of the onsite Hanford modeling technology is used to evaluate both scenarios. The results of the first study indicate that Cold Creek Valley irrigationis unlikely to cause significant changes in the water table underlying the high-level waste areas or in the movement of radionuclides already in the groundwater. The hypothetical tank leak study showed that an active response (in this case waste recovery) can be modeled and is a possible alternative to passive monitoring of radionuclide movement in the unlikely event that high-level waste is introduced into the groundwater

Ground-water travel time

International Nuclear Information System (INIS)

Bentley, H.; Grisak, G.

1985-01-01

The Containment and Isolation Working Group considered issues related to the postclosure behavior of repositories in crystalline rock. This working group was further divided into subgroups to consider the progress since the 1978 GAIN Symposium and identify research needs in the individual areas of regional ground-water flow, ground-water travel time, fractional release, and cumulative release. The analysis and findings of the Ground-Water Travel Time Subgroup are presented

Regional ground-water system

International Nuclear Information System (INIS)

Long, J.

1985-01-01

The Containment and Isolation Working Group considered issues related to the postclosure behavior of repositories in crystalline rock. This working group was further divided into subgroups to consider the progress since the 1978 GAIN Symposium and identify research needs in the individual areas of regional ground-water flow, ground-water travel time, fractional release, and cumulative release. The analysis and findings of the Ground-Water Regime Subgroup are presented

Geostatistical analysis of groundwater chemistry in Japan. Evaluation of the base case groundwater data set

Energy Technology Data Exchange (ETDEWEB)

Salter, P.F.; Apted, M.J. [Monitor Scientific LLC, Denver, CO (United States); Sasamoto, Hiroshi; Yui, Mikazu

1999-05-01

The groundwater chemistry is one of important geological environment for performance assessment of high level radioactive disposal system. This report describes the results of geostatistical analysis of groundwater chemistry in Japan. Over 15,000 separate groundwater analyses have been collected of deep Japanese groundwaters for the purpose of evaluating the range of geochemical conditions for geological radioactive waste repositories in Japan. The significance to issues such as radioelement solubility limits, sorption, corrosion of overpack, behavior of compacted clay buffers, and many other factors involved in safety assessment. It is important therefore, that a small, but representative set of groundwater types be identified so that defensible models and data for generic repository performance assessment can be established. Principal component analysis (PCA) is used to categorize representative deep groundwater types from this extensive data set. PCA is a multi-variate statistical analysis technique, similar to factor analysis or eigenvector analysis, designed to provide the best possible resolution of the variability within multi-variate data sets. PCA allows the graphical inspection of the most important similarities (clustering) and differences among samples, based on simultaneous consideration of all variables in the dataset, in a low dimensionality plot. It also allows the analyst to determine the reasons behind any pattern that is observed. In this study, PCA has been aided by hierarchical cluster analysis (HCA), in which statistical indices of similarity among multiple samples are used to distinguish distinct clusters of samples. HCA allows the natural, a priori, grouping of data into clusters showing similar attributes and is graphically represented in a dendrogram Pirouette is the multivariate statistical software package used to conduct the PCA and HCA for the Japanese groundwater dataset. An audit of the initial 15,000 sample dataset on the basis of

Groundwater Assessment Platform

OpenAIRE

Podgorski, Joel; Berg, Michael

2018-01-01

The Groundwater Assessment Platform is a free, interactive online GIS platform for the mapping, sharing and statistical modeling of groundwater quality data. The modeling allows users to take advantage of publicly available global datasets of various environmental parameters to produce prediction maps of their contaminant of interest.

Eielson Air Force Base Operable Unit 2 baseline risk assessment

Energy Technology Data Exchange (ETDEWEB)

Lewis, R.E.; Jarvis, T.T.; Jarvis, M.R.; Whelan, G.

1994-10-01

Operable Unit 2 at Eielson Air Force Base (AFB) near Fairbanks, is one of several operable units characterized by petroleum, oil, and lubricant contamination, and by the presence of organic products floating at the water table, as a result of Air Force operations since the 1940s. The base is approximately 19,270 acres in size, and comprises the areas for military operations and a residential neighborhood for military dependents. Within Operable Unit 2, there are seven source areas. These source areas were grouped together primarily because of the contaminants released and hence are not necessarily in geographical proximity. Source area ST10 includes a surface water body (Hardfill Lake) next to a fuel spill area. The primary constituents of concern for human health include benzene, toluene, ethylbenzene, and xylenes (BTEX). Monitored data showed these volatile constituents to be present in groundwater wells. The data also showed an elevated level of trace metals in groundwater.

Global scale groundwater flow model

Science.gov (United States)

Sutanudjaja, Edwin; de Graaf, Inge; van Beek, Ludovicus; Bierkens, Marc

2013-04-01

As the world's largest accessible source of freshwater, groundwater plays vital role in satisfying the basic needs of human society. It serves as a primary source of drinking water and supplies water for agricultural and industrial activities. During times of drought, groundwater sustains water flows in streams, rivers, lakes and wetlands, and thus supports ecosystem habitat and biodiversity, while its large natural storage provides a buffer against water shortages. Yet, the current generation of global scale hydrological models does not include a groundwater flow component that is a crucial part of the hydrological cycle and allows the simulation of groundwater head dynamics. In this study we present a steady-state MODFLOW (McDonald and Harbaugh, 1988) groundwater model on the global scale at 5 arc-minutes resolution. Aquifer schematization and properties of this groundwater model were developed from available global lithological model (e.g. Dürr et al., 2005; Gleeson et al., 2010; Hartmann and Moorsdorff, in press). We force the groundwtaer model with the output from the large-scale hydrological model PCR-GLOBWB (van Beek et al., 2011), specifically the long term net groundwater recharge and average surface water levels derived from routed channel discharge. We validated calculated groundwater heads and depths with available head observations, from different regions, including the North and South America and Western Europe. Our results show that it is feasible to build a relatively simple global scale groundwater model using existing information, and estimate water table depths within acceptable accuracy in many parts of the world.

Automated Groundwater Screening

International Nuclear Information System (INIS)

Taylor, Glenn A.; Collard, Leonard B.

2005-01-01

The Automated Intruder Analysis has been extended to include an Automated Ground Water Screening option. This option screens 825 radionuclides while rigorously applying the National Council on Radiation Protection (NCRP) methodology. An extension to that methodology is presented to give a more realistic screening factor for those radionuclides which have significant daughters. The extension has the promise of reducing the number of radionuclides which must be tracked by the customer. By combining the Automated Intruder Analysis with the Automated Groundwater Screening a consistent set of assumptions and databases is used. A method is proposed to eliminate trigger values by performing rigorous calculation of the screening factor thereby reducing the number of radionuclides sent to further analysis. Using the same problem definitions as in previous groundwater screenings, the automated groundwater screening found one additional nuclide, Ge-68, which failed the screening. It also found that 18 of the 57 radionuclides contained in NCRP Table 3.1 failed the screening. This report describes the automated groundwater screening computer application

A primary study on finding hot groundwater using infrared remote sensing

Science.gov (United States)

Qiao, Y.; Wu, Q.

Hot groundwater is a kind of valuable natural resources to be explored utilized. Shanxi Province, located in the eastern Loess Plateau of China, is rich in geothermal resources, most of which was found in irrigation well drilling or geological survey. Basic study is weak. Now new developed Remote Sensing technique provides geothermal study with an advanced way. Air-RS information of thermal infrared and dada from thermal channel of Meteorological Landset AVHRR has been used widely. A thermal infrared channel (TM6) was installed in the U. S. second Landset, Its resolving power of space is as high as 120 m, 10 times more t an one ofh AVHRR. A Landset earth recourses launched by China and Brazil (CBERS-1) in 1999, including a spectrum of thermal infrared. It is paid a great interested and attention to survey geothermal resources using thermal infrared. This article is a brief introduction of finding hot groundwater with on the bases of differences of thermal radiation of objects reflected by thermal infrared in the Landset, and treated with HIS colors changes. This study provides an advanced way widely used to exploit hot groundwater and to promote the development of tourism and geothermal medical in China.

Isotope hydrology: Investigating groundwater contamination

International Nuclear Information System (INIS)

Dubinchuk, V.; Froehlich, K.; Gonfiantini, R.

1989-01-01

Groundwater quality has worsened in many regions, with sometimes serious consequences. Decontaminating groundwater is an extremely slow process, and sometimes impossible, because of the generally long residence time of the water in most geological formations. Major causes of contamination are poor groundwater management (often dictated by immediate social needs) and the lack of regulations and control over the use and disposal of contaminants. These types of problems have prompted an increasing demand for investigations directed at gaining insight into the behaviour of contaminants in the hydrological cycle. Major objectives are to prevent pollution and degradation of groundwater resources, or, if contamination already has occurred, to identify its origin so that remedies can be proposed. Environmental isotopes have proved to be a powerful tool for groundwater pollution studies. The IAEA has had a co-ordinated research programme since 1987 on the application of nuclear techniques to determine the transport of contaminants in groundwater. An isotope hydrology project is being launched within the framework of the IAEA's regional co-operative programme in Latin America (known as ARCAL). Main objectives are the application of environmental isotopes to problems of groundwater assessment and contamination in Latin America. In 1989, another co-ordinated research programme is planned under which isotopic and other tracers will be used for the validation of mathematical models in groundwater transport studies

Assessment of hydro-geochemistry and groundwater quality of Rajshahi City in Bangladesh

Science.gov (United States)

Mostafa, M. G.; Uddin, S. M. Helal; Haque, A. B. M. H.

2017-12-01

The study was carried out to understand the hydro-geochemistry and ground water quality in the Rajshahi City of Bangladesh. A total of 240 groundwater samples were collected in 2 years, i.e., 2009 and 2010 covering the pre-monsoon, monsoon and post-monsoon seasons. Aquifer soil samples were collected from 30 locations during the monsoon in 2000. All the samples were analyzed for various physicochemical parameters according to standard methods of analysis, these includes pH, electrical conductivity, total dissolved solids, total hardness, and total alkalinity, major cations such as Na+, K+, Ca2+, Mg2+, and Fe2+, major anions such as HCO3 -, NO3 -, Cl-, and SO4 2- and heavy metals such as Mn, Zn, Cu, As, Cd and Pb. The results illustrated that the groundwater was slightly acidic to neutral in nature, total hardness observed in all samples fall under the hard to a very hard category. The bicarbonate and calcium concentration in the groundwater exceeded the permissible limits may be due to the dissolution of calcite. The concentration of calcium, iron, manganese, arsenic and lead were far above the permissible limit in most of the shallow tube well samples. The study found that the major hydrochemical facies was identified to be calcium-bicarbonate-type (CaHCO3). A higher concentration of metals including Fe, Mn, As and Pb was found indicating various health hazards. The rock-water interaction was the major geochemical process controlling the chemistry of groundwater in the study area. The study results revealed that the quality of the groundwater in Rajshahi City area was of great concern and not suitable for human consumption without adequate treatment.

Interactive effects of ambient acidity and salinity on thyroid function during acidic and post-acidic acclimation of air-breathing fish (Anabas testudineus Bloch).

Science.gov (United States)

Peter, M C Subhash; Rejitha, V

2011-11-01

The interactive effects of ambient acidity and salinity on thyroid function are less understood in fish particularly in air-breathing fish. We, therefore, examined the thyroid function particularly the osmotic and metabolic competences of freshwater (FW) and salinity-adapted (SA; 20 ppt) air-breathing fish (Anabas testudineus) during acidic and post-acidic acclimation, i.e., during the exposure of fish to either acidified water (pH 4.2 and 5.2) for 48 h or clean water for 96 h after pre-exposure. A substantial rise in plasma T(4) occurred after acidic exposure of both FW and SA fish. Similarly, increased plasma T(3) and T(4) were found in FW fish kept for post-acidic acclimation and these suggest an involvement of THs in short-term acidic and post-acidic acclimation. Water acidification produced significant hyperglycaemia and hyperuremia in FW fish but not in SA fish. The SA fish when kept for post-acclimation, however, produced a significant hypouremia. In both FW and SA fish, gill Na(+), K(+)-ATPase activity decreased but kidney Na(+), K(+)-ATPase activity increased upon acidic acclimation. During post-acidic acclimation, gill Na(+), K(+)-ATPase activity of the FW fish showed a rise while decreasing its activity in the SA fish. Similarly, post-acidic acclimation reduced the Na(+), K(+)-ATPase activity of intestine but elevated its activity in the liver of SA fish. A higher tolerance of the SA fish to water acidification was evident in these fish as they showed tight plasma and tissue mineral status due to the ability of this fish to counteract the ion loss. In contrast, FW fish showed more sensitivity to water acidification as they loose more ions in that medium. The positive correlations of plasma THs with many tested metabolic and hydromineral indices of both FW and SA fish and also with water pH further confirm the involvement of THs in acidic and post-acidic acclimation in these fish. We conclude that thyroid function of this fish is more sensitive to

Calculation of groundwater travel time

International Nuclear Information System (INIS)

Arnett, R.C.; Sagar, B.; Baca, R.G.

1984-12-01

Pre-waste-emplacement groundwater travel time is one indicator of the isolation capability of the geologic system surrounding a repository. Two distinct modeling approaches exist for prediction of groundwater flow paths and travel times from the repository location to the designated accessible environment boundary. These two approaches are: (1) the deterministic approach which calculates a single value prediction of groundwater travel time based on average values for input parameters and (2) the stochastic approach which yields a distribution of possible groundwater travel times as a function of the nature and magnitude of uncertainties in the model inputs. The purposes of this report are to (1) document the theoretical (i.e., mathematical) basis used to calculate groundwater pathlines and travel times in a basalt system, (2) outline limitations and ranges of applicability of the deterministic modeling approach, and (3) explain the motivation for the use of the stochastic modeling approach currently being used to predict groundwater pathlines and travel times for the Hanford Site. Example calculations of groundwater travel times are presented to highlight and compare the differences between the deterministic and stochastic modeling approaches. 28 refs

Investigation of heat flux processes governing the increase of groundwater temperatures beneath cities

Science.gov (United States)

Bayer, P.; Menberg, K.; Zhu, K.; Blum, P.

2012-12-01

In the subsurface of many cities there are widespread and persistent thermal anomalies. These so-called subsurface urban heat islands (UHIs), which also stimulate warming of urban aquifers, are triggered by various processes. Possible heat sources are basements of buildings, leakage of sewage systems, buried district heating networks, re-injection of cooling water and solar irradiation on paved surfaces. In the current study, the reported groundwater temperatures in several Central European cities, such as Berlin, Cologne (Germany) and Zurich (Switzerland) are compared. Available data sets are supplemented by temperature measurements and depth profiles in observation wells. Trend analyses are conducted with time series of groundwater temperatures, and three-dimensional groundwater temperature maps are provided. In all investigated cities, pronounced positive temperature anomalies are present. The distribution of groundwater temperatures appears to be spatially and temporally highly variable. Apparently, the increased heat input into the urban subsurface is controlled by very local and site-specific parameters. In the long-run, the combination of various heat sources results in an extensive temperature increase. In many cases, the maximum temperature elevation is found close to the city center. Regional groundwater temperature differences between the city center and the rural background are up to 5 °C, with local hot spots of even more pronounced anomalies. Particular heat sources, like cooling water injections or case-specific underground constructions, can cause local temperatures > 20 °C in the subsurface. Examination of the long-term variations in isotherm maps shows that temperatures have increased by about 1 °C in the city, as well as in the rural background areas over the last decades. This increase could be reproduced with trend analysis of temperature data gathered from several groundwater wells. Comparison between groundwater and air temperatures in the

Kuwaiti dolocrete: petrology, geochemistry and groundwater origin

Science.gov (United States)

El-Sayed, M. I.; Fairchild, I. J.; Spiro, B.

1991-09-01

Near-surface sediments in southern Kuwait show extensive development of duricrusts. The host materials are siliciclastic sandstones of the post-Eocene Kuwait Group. Inland, the duricrusts are dominantly pedogenic calcrete (with some silcrete and gypcrete), whereas within 10-20 km of the coast, dolomite is the dominant duricrust mineral. Both these dolocretes and the inland calcretes display a similar maturation sequence in which carbonate-rich nodules develop and coalesce, carbonate progressively replacing and displacing detrital grains. The dolomite of the dolocretes forms mosaics of crystals typically 10-70 μm in size, varying from simple rhombs to spherulites. An intermediate morphology, named artichoke dolomite from its appearance in SEM, is particularly abundant. Authigenic palygorskite is associated with the dolomite. Dissolution of cores or zones within dolomite crystals has occurred. Calcite is present as sparry crystals (always post-dating dolomite) and is the expected precipitate from present-day soil and groundwaters. Chemical analyses of dolomite show highly negative values of δ13C (- to - 10.7‰ PDB) and δ18O varying from + 0.6 to + 3.3‰ PDB. The oxygen isotope values are interpreted as reflecting evaporation of a marine-based fluid. Manganese values of around 1000 ppm show that this fluid was reducing. Strontium data show variability reflecting mineral-fluid reactions. The general absence of metastable carbonates and presence of zoning in dolomite crystals suggests that meteoric dilution of seawater also occurred. Given that the duricrusts lack biogenic features, the light carbon isotope values are taken to indicate oxidation of seeping hydrocarbons. The dolocretes are interpreted as groundwater precipitates near the water table of a brackish water body formed at a time of higher relative sea level than today.

Nirex 97 an assessment of the post-closure performance of a deep waste repository at Sellafield. Volume 3; the groundwater pathway

International Nuclear Information System (INIS)

Baker, A.; Chambers, A.; Jackson, C.

1997-01-01

United Kingdom Nirex Limited ('Nirex') is responsible for providing and managing facilities for the safe disposal of intermediate and certain low-level radioactive waste (ILW and LLW respectively). Government policy is that the preferred disposal route for such wastes is a deep geological repository. The repository concept aims to use a combination of natural and engineered barriers to achieve the necessary degree of long-term isolation and containment of the radioactive wastes. Since 1987, Nirex has carried out an extensive technical programme directed at the science of safe disposal. The work comprises a research programme into the long-term performance of waste forms and the engineered and natural barriers, including the characterisation of candidate geological settings to assess their suitability to host a deep waste repository ('DWR'). Between mid-1991 and March 1997 the geological characterisation programme was concentrated on establishing the suitability, or otherwise, of a candidate site at Sellafield, West Cumbria. In July 1994, as part of a detailed site investigation programme, Nirex applied for planning permission to develop an underground Rock Characterisation Facility (RCF) at Longlands Farm near Sellafield. This application was rejected by the planning authority and Nirex's appeal against that decision led to a local planning inquiry which ran from September 1995 until February 1996. In line with the Inspector's Report, in March 1997 the Nirex appeal was dismissed by the Secretary of State for the Environment. The Company's response to that decision, and its readiness to contribute to the new government's review of the way forward, are described in the Nirex Annual Report for 1996-97. This report - Nirex 97 - is founded on the understanding developed through the Nirex technical programme. It reports the outcome of an assessment of the post-closure safety performance, over hundreds of thousands of years, of a repository system located in a potential

Calendar Year 1997 Annual Groundwater Monitoring Report For The Chestnut Ridge Hydrogeologic Regime At The U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

Energy Technology Data Exchange (ETDEWEB)

Jones, S.B.

1998-02-01

This report contains the groundwater monitoring data obtained during calendar year (CY) 1997 in compliance with the Resource Conservation and Recovery Act (RCRA) post-closure permit (PCP) for the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). In July 1997, the Tennessee Department of Environment and Conservation (TDEC) approved modifications to several of the permit conditions that address RCRA pow-closure corrective action groundwater monitoring at the Chestnut Ridge Security Pits (Security Pits), and RCIU4 post-closure detection groundwater monitoring at the Chestnut Ridge Sediment Disposal Basin (Sediment Disposal Basin) and Kerr Hollow Quarry. This report has been prepared in accordance with these modified permit requirements. Also included in this report are the groundwater and surface water monitoring data obtained during CY 1997 for the purposes ofi (1) detection monitoring at nonhazardous solid waste disposal facilities (SWDFS) in accordance with operating permits and applicable regulations, (2) monitoring in accordance with Comprehensive Environmental Response, Compensation, and Recove~ Act Records of Decision (now pefiormed under the Integrated Water Quality Program for the Oak Ridge Reservation), and (3) monitoring needed to comply with U.S. Department of Energy Order 5400.1.

Hydrodynamic analysis of the interaction of two operating groundwater sources, case study: Groundwater supply of Bečej

Directory of Open Access Journals (Sweden)

Polomčić Dušan M.

2014-01-01

Full Text Available The existing groundwater source 'Vodokanal' for the public water supply of Bečej city in Serbia tapping groundwater from three water-bearing horizons over 15 wells with summary capacity of 100 l/s. Near the public water source of Bečej exists groundwater source 'Soja Protein' for industry with current capacity of 12 l/s which tapped same horizons. In the coming period is planned to increase summary capacity of this groundwater source up to 57 l/s. Also, the increase of summary city's source capacity is planned for 50 l/s in the next few years. That is means an increase of groundwater abstraction for an additional 84 % from the same water-bearing horizons. Application of hydrodynamic modeling, based on numerical method of finite difference will show the impact of increasing the total capacity of the source 'Soja Protein' on the groundwater level in groundwater source 'Vodokanal' and effects of additional decrease in groundwater levels, in all three water-bearing horizons, on the wells of the 'Vodokanala' groundwater source due to operation of industrial source. It was done 7 variant solutions of the extensions of groundwater sources and are their effects for a period of 10 years with the aim of the sustainable management of groundwater.

Air-cushioning in impact problems

KAUST Repository

Moore, M. R.; Ockendon, J. R.; Oliver, J. M.

2013-01-01

This paper concerns the displacement potential formulation of the post-impact influence of an air-cushioning layer on the 2D impact of a liquid half-space by a rigid body. The liquid and air are both ideal and incompressible and attention

Groundwater hydrochemistry,Variation of Arsenic and Monsoonal influence : An explanation regarding release mechanism assisted by isotopic signatures

Science.gov (United States)

Chatterjee, Debashis

2017-04-01

The investigation examines the groundwater and surface water geochemistry of two different geomorphics in West Bengal. During investigation, several key factors are taken into account e.g. potential influences of groundwater abstraction on the hydrochemical evolution of the aquifer, the effect of different water inputs (monsoon rain, irrigation and downward percolation from surface water impoundments) to the groundwater system and accompanying As release. A natural levee and low-land flood plain have been chosen for said investigation. The results reveal that the stable isotopic signatures of oxygen (d18O) and hydrogen (d2H) are governed by local precipitation, the isotopic composition falls sub-parallel to the Global Meteoric Water Line (GMWL). The Cl/Br molar ratio indicates vertical recharge into the wells within the flood plain area, notably during the post-monsoon season, while influences of both evaporation and vertical mixing are visible within the natural levee wells. The important finding is the increasing mean DOC concentrations (from 1.33 to 6.29 mg/L), from pre- to post-monsoon season, which is indicative of possible inflow of organic carbon to the aquifer during the monsoonal recharge. This suggests the subsequent increase in AsT, Fe(II) and HCO3 highlighting a possible initial episode of reductive dissolution of As-rich Fe-oxyhydroxides. The abrupt increase in the mean As(III) proportions (by 223%), notably in the flood plain samples during the post-monsoon season. This is attended by a slight increase in mean AsT (7%). This may refer to anaerobic microbial degradation of DOC coupled with the reduction of As(V) to As(III) without resulting in additional As release from the aquifer sediments.

Air Force Civil Engineer, Volume 10, Number 1, Spring 2002

Science.gov (United States)

2002-01-01

gone into the 823rd Expeditionary RED HORSE Squadron�s military construction (MILCON) funded ramp project at Al Udeid Air Base, Qatar , and the main...AE W P ub lic A ff ai rs an Air Base RED HORSE builds MILCON project in Qatar SSgt Chuck Risinger, 823rd RHS, operates a slip form paver March 24...and were not designed to limit or contain the migration of lead into the environ- ment and sub-surface groundwater aquifers . An estimated 2,000

Automating Groundwater Sampling At Hanford, The Next Step

International Nuclear Information System (INIS)

Connell, C.W.; Conley, S.F.; Hildebrand, R.D.; Cunningham, D.E.

2010-01-01

Historically, the groundwater monitoring activities at the Department of Energy's Hanford Site in southeastern Washington State have been very 'people intensive.' Approximately 1500 wells are sampled each year by field personnel or 'samplers.' These individuals have been issued pre-printed forms showing information about the well(s) for a particular sampling evolution. This information is taken from 2 official electronic databases: the Hanford Well information System (HWIS) and the Hanford Environmental Information System (HEIS). The samplers used these hardcopy forms to document the groundwater samples and well water-levels. After recording the entries in the field, the samplers turned the forms in at the end of the day and other personnel posted the collected information onto a spreadsheet that was then printed and included in a log book. The log book was then used to make manual entries of the new information into the software application(s) for the HEIS and HWIS databases. A pilot project for automating this extremely tedious process was lauched in 2008. Initially, the automation was focused on water-level measurements. Now, the effort is being extended to automate the meta-data associated with collecting groundwater samples. The project allowed electronic forms produced in the field by samplers to be used in a work flow process where the data is transferred to the database and electronic form is filed in managed records - thus eliminating manually completed forms. Elimating the manual forms and streamlining the data entry not only improved the accuracy of the information recorded, but also enhanced the efficiency and sampling capacity of field office personnel.

Natural radionuclides in groundwaters

International Nuclear Information System (INIS)

Laul, J.C.

1990-01-01

The U-234 and Th-230 radionuclides are highly retarded by factors of 10 4 to 10 5 in basalt groundwater (Hanford) and briny groundwaters from Texas and geothermal brine from the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na + and Cl - ions and RaCl 2 is soluble in brines. Pb-210 is soluble in SSGF brine, probably as a chloride complex. The U-234/Th-230 ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. 19 refs., 3 figs

Microbiology of Olkiluoto groundwater. Results and interpretations 2007

International Nuclear Information System (INIS)

Pedersen, K.; Arlinger, J.; Eriksson, S.; Hallbeck, M.; Johansson, J.; Jaegevall, S.; Karlsson, L.

2008-09-01

was deemed important to start researching the prevalence of microbes, present in Olkiluoto groundwater and ONKALO slime, having the ability to produce complexing agents. The total amount of gas was found to increase with depth, as was the case in previous years. There was great variability in total gas volume over depth down to a depth of approximately 300 m, consistent with the results from 2005-2006. Three different methods were used to analyse the groundwater samples: TNC returns cell numbers, adenosine triphosphate (ATP) returns a measure of biomass, and cultivation returns a measure of microbe diversity and numbers. The outputs of these independent methods were found to correlate. ATP and TNC have previously been shown to correlate, but the demonstration of correlation between ATP and most probable number (MPN) cultivations is new and supports the quality of the MPN results. Adding a quantitative polymerase chain reaction (Q-PCR) method to groundwater investigations, combined with isolating and characterizing cultivable microorganisms from the highest dilutions of the MPN tubes, will reveal specific details about the diversity and activity of the studied populations. Q-PCR methods were successfully developed in 2007. A schematic model of the processes ongoing in the ONKALO slime has been postulated. Formaldehyde and other organic compounds from the grout additions and the methane promote the growth of methanotrophs and aerobic and iron-reducing microbes in the ONKALO slime. Oxygen can be derived from the air and ferric iron from iron oxides. Methanogens, located deep within the ONKALO slime where oxygen is depleted, produce methane as a final decomposition step after the organic carbon sources added with the grouting are degraded by the aerobic microbes. Sulphide is produced via sulphate reduction and precipitates with ferrous iron forming iron sulphide, which subsequently is converted to sulphuric acid in contact with air, causing pit corrosion of concrete. The

Groundwater monitoring systems and groundwater quality in the administrative district of Detmold (North Rhine-Westphalia)

International Nuclear Information System (INIS)

Grabau, J.

1994-01-01

Two groundwater monitoring systems for areas of different dimensions in the administrative district of Detmold are introduced. Firstly, the monitoring of groundwater and untreated water by the Water Conservation and Waste Disposal Authority (Amt fuer Wasser- und Abfallwirtschaft) in Minden and secondly, the monitoring of groundwater and drinking water by the Water Resources Board (Wasserschutzamt) in Bielefeld. Different approaches and methods are required for the description of groundwater quality on a regional and a local basis, respectively, i.e. for the monitoring of a whole region and the monitoring of parts of such a region. The properties of groundwater in areas of different dimensions are analysed and described by means of an extensive database and with the help of (geo)statistical methods of analysis. Existing hydrochemical data have only limited value as evidence of groundwater properties in the dimensional units ''region'' and ''small investigation area''. They often do not meet the requirements of correct mathematical statistical methods. (orig.)

Geologic and hydrologic data for the municipal solid waste landfill facility, U.S. Army Air Defense Artillery Center and Fort Bliss, El Paso County, Texas

Science.gov (United States)

Abeyta, Cynthia G.; Frenzel, P.F.

1999-01-01

Geologic and hydrologic data for the Municipal Solid Waste Landfill Facility on the U.S. Army Air Defense Artillery Center and Fort Bliss in El Paso County, Texas, were collected by the U.S. Geological Survey in cooperation with the U.S. Department of the Army. The 106.03-acre landfill has been in operation since January 1974. The landfill contains household refuse, Post solid wastes, bulky items, grass and tree trimmings from family housing, refuse from litter cans, construction debris, classified waste (dry), dead animals, asbestos, and empty oil cans. The depth of the filled areas is about 30 feet and the cover, consisting of locally derived material, is 2 to 3 feet thick. Geologic and hydrologic data were collected at or adjacent to the landfill during (1) drilling of 10 30- to 31-foot boreholes that were completed with gas-monitoring probes, (2) drilling of a 59-foot borehole, (3) drilling of a 355-foot borehole that was completed as a ground-water monitoring well, and (4) in situ measurements made on the landfill cover. After completion, the gas- monitoring probes were monitored on a quarterly basis (1 year total) for gases generated by the landfill. Water samples were collected from the ground-water monitoring well for chemical analysis. Data collection is divided into two elements: geologic data and hydrologic data. Geologic data include lithologic descriptions of cores and cuttings, geophysical logs, soil- gas and ambient-air analyses, and chemical analyses of soil. Hydrologic data include physical properties, total organic carbon, and pH of soil and sediment samples; soil-water chloride and soil-moisture analyses; physical properties of the landfill cover; measurements of depth to ground water; and ground-water chemical analyses. Interpretation of data is not included in this report.

Current Status of Groundwater Monitoring Networks in Korea

OpenAIRE

Jin-Yong Lee; Kideok D. Kwon

2016-01-01

Korea has been operating groundwater monitoring systems since 1996 as the Groundwater Act enacted in 1994 enforces nationwide monitoring. Currently, there are six main groundwater monitoring networks operated by different government ministries with different purposes: National Groundwater Monitoring Network (NGMN), Groundwater Quality Monitoring Network (GQMN), Seawater Intrusion Monitoring Network (SIMN), Rural Groundwater Monitoring Network (RGMN), Subsidiary Groundwater Monitoring Network ...

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Cecil Field Naval Air Station, Jacksonville, Florida

Science.gov (United States)

Halford, K.J.

1998-01-01

As part of the Installation Restoration Program, Cecil Field Naval Air Station, Jacksonville, Florida, is considering remedialaction alternatives to control the possible movement of contaminants from sites that may discharge to the surface. This requires a quantifiable understanding of ground-water flow through the surficial aquifer system and how the system will respond to any future stresses. The geologic units of interest in the study area consist of sediments of Holocene to Miocene age that extend from land surface to the base of the Hawthorn Group. The hydrogeology within the study area was determined from gamma-ray and geologists? logs. Ground-water flow through the surficial aquifer system was simulated with a seven-layer, finite-difference model that extended vertically from the water table to the top of the Upper Floridan aquifer. Results from the calibrated model were based on a long-term recharge rate of 6 inches per year, which fell in the range of 4 to 10 inches per year, estimated using stream hydrograph separation methods. More than 80 percent of ground-water flow circulates within the surficial-sand aquifer, which indicates that most contaminant movement also can be expected to move through the surficial-sand aquifer alone. The surficial-sand aquifer is the uppermost unit of the surficial aquifer system. Particle-tracking results showed that the distances of most flow paths were 1,500 feet or less from a given site to its discharge point. For an assumed effective porosity of 20 percent, typical traveltimes are 40 years or less. At all of the sites investigated, particles released 10 feet below the water table had shorter traveltimes than those released 40 feet below the water table. Traveltimes from contaminated sites to their point of discharge ranged from 2 to 300 years. The contributing areas of the domestic supply wells are not very extensive. The shortest traveltimes for particles to reach the domestic supply wells from their respective

Groundwater use in Pakistan: opportunities and limitations

International Nuclear Information System (INIS)

Bhutta, M.N.

2005-01-01

Groundwater potential in the Indus Basin is mainly due to recharge from irrigation system, rivers and rainfall. Its quality and quantity varies spatially and temporally. However, the potential is linked with the surface water supplies. Irrigated agriculture is the major user of groundwater. Annual recharge to groundwater in the basin is estimated as 68 MAF. But 50 percent of the area has marginal to hazardous groundwater quality. Existing annual groundwater pumpage is estimated as 45 MAF (55 BCM). More than 13 MAF mainly of groundwater is lost as non-beneficial ET losses. Groundwater contributes 35 percent of total agricultural water requirements in the country. Annual cropping intensities have increased from 70% to 150% due to groundwater use. Increase in crop yield due to groundwater use has been observed 150-200. percent. Total investment on private tube wells has been made more than Rs.25.0 billion. In the areas where farmers are depending more on groundwater. mining of groundwater has been observed. Population pressure, inadequate supply of canal water and development of cheap local tub well technology have encouraged farmers to invest in the groundwater development. Deterioration of groundwater has also been observed due to excessive exploitation. The available information about the private tube wells is insufficient for different areas. Although during the past decade the growth of tube wells was tremendous but was not reflected accordingly in the statistics. Monitoring of groundwater quality is not done systematically and adequately. It is very difficult to manage a resource for which adequate information is not available. The present scenario of groundwater use is not sustainable and therefore certain measures are needed to be taken. It is recommended to. have a systematic monitoring of groundwater. For the sustainable use of groundwater, it is recommended to manage the demand of water i.e. grow more crops with less water. To achieve high productivity of

Environmental Assessment Preparation for Air Force Test Mission in the 21st Century: Upgrade and Improve the Test Capability at the Edwards Air Force Base California Test Complex

Science.gov (United States)

2015-04-01

National Ambient Air Quality Standards NAGPRA Native American Graves Protection and Repatriation Act NDMA N-Nitrosodimethylamine NEPA National...parts of OUs 1, 2, 5/10, 6, and 8. Groundwater contamination in the form of solvent, perchlorate, petroleum, nitrate, and N- Nitrosodimethylamine ( NDMA

Tracing the factors responsible for arsenic enrichment in groundwater of the middle Gangetic Plain, India: a source identification perspective.

Science.gov (United States)

Kumar, Pankaj; Kumar, Manish; Ramanathan, A L; Tsujimura, Maki

2010-04-01

Arsenic contamination in groundwater is of increasing concern because of its high toxicity and widespread occurrence. This study is an effort to trace the factors responsible for arsenic enrichment in groundwater of the middle Gangetic Plain of India through major ion chemistry, arsenic speciation, sediment grain-size analyses, and multivariate statistical techniques. The study focuses on the distinction between the contributions of natural weathering and anthropogenic inputs of arsenic with its spatial distribution and seasonal variations in the plain of the state Bihar of India. Thirty-six groundwater and one sediment core samples were collected in the pre-monsoon and post-monsoon seasons. Various graphical plots and statistical analysis were carried out using chemical data to enable hydrochemical evaluation of the aquifer system based on the ionic constituents, water types, hydrochemical facies, and factors controlling groundwater quality. Results suggest that the groundwater is characterized by slightly alkaline pH with moderate to strong reducing nature. The general trend of various ions was found to be Ca(2+) > Na(+) > Mg(2+) > K(+) > NH(4) (+); and HCO(3) (-) > Cl(-) > SO(4) (2-) > NO(3) (-) > PO(4) (3-) > F(-) in both seasons. Spatial and temporal variations showed a slightly higher arsenic concentration in the pre-monsoon period (118 microg/L) than in the post-monsoon period (114 microg/L). Results of correlation analyses indicate that arsenic contamination is strongly associated with high concentrations of Fe, PO(4) (3-), and NH(4) (+) but relatively low Mn concentrations. Further, the enrichment of arsenic is more prevalent in the proximity of the Ganges River, indicating that fluvial input is the main source of arsenic. Grain size analyses of sediment core samples revealed clay (fine-grained) strata between 4.5 and 7.5 m deep that govern the vertical distribution of arsenic. The weathering of carbonate and silicate minerals along with surface-groundwater

Estimation of groundwater residence time and evaluation of geomorphological processes using cosmogenic and terrigenic radionuclides and isotopes of noble gases

International Nuclear Information System (INIS)

Mahara, Yasunori; Ohta, Tomoko; Igarashi, Toshifumi

2013-01-01

In this paper, the estimation of groundwater residence time and geomorphological changing processes are discussed by focusing on isotopes of noble gases and radionuclides with a long half-life as an environmental tracer. Noble gases and radionuclides are produced in the atmospheric air and terrestrial rocks by spallation and various muon reactions during cosmic rays irradiation. Groundwater dating and geomorphological changing are estimated from changes in the number of atoms of cosmogenic and terrigenic nuclides in groundwater and terrestrial rock. The main tools of groundwater dating are combination of the dissolved helium and tritium (half-life T 1/2 =12.3 y) for younger groundwater less than 60 years of residence time, and of the dissolved helium and 36 Cl (T 1/2 =3.01 x 10 5 y) for older groundwater over million years. On the other hand, the main tools on the geomorphological changes are the estimation of exposure time using cosmogenic radionuclides ( 10 Be(half-life T 1/2 =1.6 x 10 6 y), 14 C (T 1/2 =5730 y), 26 Al (T 1/2 =7.16 x 10 5 y) and 36 Cl) and cosmogenic stable noble gases ( 3 He and 21 Ne) produced in rock. (author)

Comparative study on change in groundwaters of rural and urban areas in Korea: effects of climate change

Science.gov (United States)

Yun, Sang Woong; Seul Kim, Ye; Kim, Dong Hyun; Kim, Ho Chul; Shin, Min Cheol; Park, Jae Yong; Kim, Heejung; Lee, Jin-Yong

2013-04-01

Groundwater occupies a considerable proportion of the world's water resources and is affected by climate change. It is important to understand how water budget responds to future precipitation variability for sustainable management of groundwater resources. In order to evaluate the effects of climate change on groundwater resources in the future, it is necessary to not only collect field data but also predict groundwater change using some groundwater numerical modelling. In this study, a relevant climate change scenario (RCP 4.5) was adopted and Visual MODFLOW was used as a main tool for predicting water budget. The predicted precipitation and air temperature data were obtained from Climate Change Information Center (CCIC) of Korea. By using the data on the scenario from 2011 to 2100, the future water budget was calculated using groundwater numerical modelling for both Wonju (WJ: urban area) and Yanggu (YG: rural area) of Gangwon Province in Korea. The model calibration was done by the groundwater level measured at 10 monitoring wells. For the numerical prediction, the groundwater recharge (WJ: 10.1%, YG: 13.3%) was estimated using watertable fluctuation (WTF) method and a concept of threshold precipitation (WJ: 240.5 mm, YG: 363.8 mm) was applied. Consequently, the water levels in both Wonju and Yanggu showed gradually increasing trends and ranged from 3.0 to 10.8 m, from 0.5 to 1.8 m in 2100, respectively. Under annual precipitation fluctuation on the scenario (2011-2100), water budget IN-OUT value (-0.87~1.07 m3/day) in Wonju city gradually increases while that (-0.73~0.46 m3/day) of Yanggu county does not. However, its annual difference is enlarged with year for both areas. The results indicate that securing groundwater resource and its management will be difficult because of frequent annual change of the groundwater storage. This work was supported by Science High School R&E program (No. C1008804-01-01) and the National Research Foundation of Korea (NRF) grant

Response of groundwater level and surface-water/groundwater interaction to climate variability: Clarence-Moreton Basin, Australia

Science.gov (United States)

Cui, Tao; Raiber, Matthias; Pagendam, Dan; Gilfedder, Mat; Rassam, David

2018-03-01

Understanding the response of groundwater levels in alluvial and sedimentary basin aquifers to climatic variability and human water-resource developments is a key step in many hydrogeological investigations. This study presents an analysis of groundwater response to climate variability from 2000 to 2012 in the Queensland part of the sedimentary Clarence-Moreton Basin, Australia. It contributes to the baseline hydrogeological understanding by identifying the primary groundwater flow pattern, water-level response to climate extremes, and the resulting dynamics of surface-water/groundwater interaction. Groundwater-level measurements from thousands of bores over several decades were analysed using Kriging and nonparametric trend analysis, together with a newly developed three-dimensional geological model. Groundwater-level contours suggest that groundwater flow in the shallow aquifers shows local variations in the close vicinity of streams, notwithstanding general conformance with topographic relief. The trend analysis reveals that climate variability can be quickly reflected in the shallow aquifers of the Clarence-Moreton Basin although the alluvial aquifers have a quicker rainfall response than the sedimentary bedrock formations. The Lockyer Valley alluvium represents the most sensitively responding alluvium in the area, with the highest declining (-0.7 m/year) and ascending (2.1 m/year) Sen's slope rates during and after the drought period, respectively. Different surface-water/groundwater interaction characteristics were observed in different catchments by studying groundwater-level fluctuations along hydrogeologic cross-sections. The findings of this study lay a foundation for future water-resource management in the study area.

Modeling groundwater age using tritium and groundwater mineralization processes - Morondava sedimentary basin, Southwestern Madagascar

International Nuclear Information System (INIS)

RAMAROSON, V.

2007-01-01

The tritium method in the lumped parameter approach was used for groundwater dating in the Morondava sedimentary basin, Southwestern Madagascar. Tritium data were interpreted by the dispersion model. The modeling results, with P D values between 0.05 and 0.7, show that shallow groundwater age is ranging from 17 to 56 years. Different types of chemical composition were determined for these shallow ground waters, among others, Ca-HCO 3 , Ca-Na-HCO 3 , Ca-Na-Mg-HCO 3 , Ca-K-HCO 3 -NO 3 -SO 4 , Na-Cl, or Ca-Na-Mg-Cl. Likewise, deeper ground waters show various chemical type such as Ca-Na-HCO 3 , Ca-Mg-Na H CO 3 , Ca-Na-Mg-HCO 3 , Ca-Na-Mg-HCO 3 -Cl-SO 4 , Ca-Mg-HCO 3 , Na-Ca-Mg-HCO 3 -SO 4 -Cl, Na-Cl-HCO 3 or Na-HCO 3 -Cl. To evaluate the geochemical processes, the NETPATH inverse geochemical modeling type was implemented. The modeling results show that silicate minerals dissolution , including olivine, plagioclase, and pyroxene is more important than calcite or dolomite dissolution, for both shallow and deeper groundwater . In the Southern part of the study area, while halite dissolution is likely to be the source of shallow groundwater chloride concentration rise, the mineral precipitation seems to be responsible for less chloride content in deeper groundwater. Besides, ion exchange contributes to the variations of major cations concentrations in groundwater. The major difference between shallow and deep groundwater mineralization process lies in the leaching of marine aerosols deposits by local precipitation, rapidly infiltrated through the sandy formation and giving marine chemical signature to shallow groundwater [fr

Comparison of three field screening techniques for delineating petroleum hydrocarbon plumes in groundwater at a site in the southern Carson Desert, Nevada

International Nuclear Information System (INIS)

Smuin, D.R.

1993-01-01

Three types of field screening techniques used in the characterization of potentially contaminated sites at Naval Air Station Fallon, Nevada, are compared. The methods and results for each technique are presented. The three techniques include soil-gas surveys, electromagnetic geophysical surveys, and groundwater test hole screening. Initial screening at the first study site included two soil-gas surveys and electromagnetic geophysical studies. These screening methods identified I areas of contamination; however, results were inconclusive. Therefore groundwater test hole screening was performed. Groundwater screening consisted of auger drilling down to the shallow alluvial aquifer. Groundwater samples were collected from the open drill hole with a bailer. On-site head-space analyses for volatile organic compounds (VOCS) were performed using a portable gas chromatograph (GC). Five areas of floating petroleum hydrocarbon product were identified along with the overall dissolved contaminant plume boundaries. Well placement was re-evaluated, and well sites were relocated based on the screening information. The most effective technique for identification of petroleum hydrocarbon-contaminant plumes was groundwater test hole screening. Groundwater screening was subsequently performed at 19 other sites. A total of 450 test holes were analyzed resulting in the delineation of six plumes

Groundwater Level Monitoring using Levelogger and the Importance of Long-Term Groundwater Level Data

International Nuclear Information System (INIS)

Nazran Harun; Ahmad Hasnulhadi Che Kamaruddin

2016-01-01

This review paper is focused on groundwater level monitoring using levelogger and the importance of long-term groundwater level data. The levelogger provides an inexpensive and convenient method to measure level, temperature and conductivity all in one probe. It can provide real time view as data is being recorded by the connected data logger. Water-level measurements from observation wells are the principal source of information about the hydrologic stresses acting on aquifers and how these stresses affect ground-water recharge, storage, and discharge. Long-term and systematic measurements of water levels provide essential data needed to evaluate changes in the resource over time to develop ground-water models, forecast trends and monitor the effectiveness of groundwater management. A significant advantage of this method of data collection and reporting are the groundwater level data can be updated real time. The accessibility of water level data is greatly enhanced by the Geographic Information System (GIS) to visually illustrate the locations of observation wells relative to relevant topographic, geologic, or hydrologic features. GIS and internet greatly enhance the capability for retrieval and transmittal of water-level data to potential users. (author)

The availability of unmanned air vehicles: a post-case study

NARCIS (Netherlands)

Smith, M.A.J.; Dekker, R.; Kos, J.; Hontelez, J.A.M.

2001-01-01

An Unmanned Air Vehicle (UAV) is an unmanned, remotely controlled, small air vehicle. It has an important role in antisurface warfare. This implies over-the-horizon detection, classification, targeting and battle damage assessment. To perform these tasks several UAVs are needed to assist or

Groundwater environmental capacity and its evaluation index.

Science.gov (United States)

Xing, Li Ting; Wu, Qiang; Ye, Chun He; Ye, Nan

2010-10-01

To date, no unified and acknowledged definition or well-developed evaluation index system of groundwater environment capacity can be found in the academia at home or abroad. The article explores the meaning of water environment capacity, and analyzes the environmental effects caused by the exploitation of groundwater resources. This research defines groundwater environmental capacity as a critical value in terms of time and space, according to which the groundwater system responds to the external influences within certain goal constraint. On the basis of observing the principles of being scientific, dominant, measurable, and applicable, six level 1 evaluation indexes and 11 constraint factors are established. Taking Jinan spring region for a case study, this research will adopt groundwater level and spring flow as constraint factors, and the allowable groundwater yield as the critical value of groundwater environmental capacity, prove the dynamic changeability and its indicating function of groundwater environmental capacity through calculation, and finally point out the development trends of researches on groundwater environmental capacity.

Quantifying shallow and deep groundwater inputs to rivers with groundwater dating in hydrological observatories.

Science.gov (United States)

Aquilina, Luc; Marçais, Jean; Gauvain, Alexandre; Kolbe, Tamara; de Dreuzy, Jean-Raynald; Labasque, Thierry; Abbott, Benjamin W.; Vergnaud, Virginie; Chatton, Eliot; Thomas, Zahra; Ruiz, Laurent; Bour, Olivier; Pinay, Gilles

2017-04-01

River water derives in part from groundwater—water that has spent some time in the subsurface (e.g. soil, unsaturated zone, saturated zone). However, because groundwater residence times vary from months to millennia, determining the proportion of shallow and deep groundwater contribution can be challenging. Groundwater dating with anthropogenic gases and natural geochemical tracers can decipher the origin of groundwater contribution to rivers, particularly when repeat samplings are carried out in different hydrological conditions. Here, we present two different applications of this approach from three hydrological observatories (H+ hydrogeological network; Aghrys and Armorique observatories) in western France, all these observatories belonging to the OZCAR national network. We carried out a regional investigation of mean groundwater ages in hard rock aquifers in Brittany, using long-term chronicles from hydrological observatories and regional monitoring sites. We determined the mean residence-time (RT) and annual renewal rate (RR) of four compartments of these aquifers: the direct contribution of a very young water component (i.e. RT less than 1-2 yr), the upper variably saturated zone (RR 27-33%), the weathered layer (RR 1.8-2.1%) and the fractured zone (RR 0.1%). From these values and a nitrate chronicle, we were able to determine the respective contributions of each compartment to the largest river in Brittany, the Vilaine, which drains 30% of the region. We found that the deep fractured compartment with very slow renewal times contributed to 25-45% of river water in winter and 30-60% in summer. The very young water which includes direct precipitation and soil fluxes constituted 40-65% of the winter river water (Aquilina et al., 2012). To complement these estimates, we investigated the relationship between dissolved silica and groundwater age in the Armorique hydrological observatory in northern Brittany. We computed the silica concentration expected along the

Natural radionuclides in groundwaters

International Nuclear Information System (INIS)

Laul, J.C.

1992-01-01

The 234 U and 230 Th radionuclides are highly retarded by factors of 10 4 to 10 5 in basalt groundwater (Hanford) and briny groundwaters from Texas, and geothermal brine form the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na + and Cl - ions, and RaCl 2 is soluble in brines. 210 Pb is soluble in SSGF brine, probably as a chloride complex. The 234 U/ 230 Th ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. (author) 19 refs.; 3 figs

Death Valley regional groundwater flow system, Nevada and California-Hydrogeologic framework and transient groundwater flow model

Science.gov (United States)

Belcher, Wayne R.; Sweetkind, Donald S.

2010-01-01

A numerical three-dimensional (3D) transient groundwater flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the groundwater flow system and previous less extensive groundwater flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect groundwater flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley regional groundwater flow system (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the groundwater flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural groundwater discharge occurring through evapotranspiration (ET) and spring flow; the history of groundwater pumping from 1913 through 1998; groundwater recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were provided

Oxidation of volatile organic vapours in air by solid potassium permanganate

NARCIS (Netherlands)

Mahmoodlu, M.G.; Hartog, N.; Hassanizadeh, S.M.; Raoof, A.

2013-01-01

Volatile organic compounds (VOCs) may frequently contaminate groundwater and pose threat to human health when migrating into the unsaturated soil zone and upward to the indoor air. The kinetic of chemical oxidation has been investigated widely for dissolved VOCs in the saturated zone. But, so far

SR-Site - sulphide content in the groundwater at Forsmark

Energy Technology Data Exchange (ETDEWEB)

Tullborg, E-L (Terralogica (Sweden)); Smellie, J (Conterra (Sweden)); Nilsson, A-Ch (Geosigma (Sweden)); Gimeno, M J; Auque, LF (Univ. of Zaragoza (Spain)); Bruchert, V (Stockholms Universitet (Sweden)); Molinero, J (Amphos21 (Spain))

2010-12-15

Sulphide concentrations in groundwater play a key role in the long-term reliability of the metal canisters containing the radioactive waste within a disposal facility for nuclear waste. This is because sulphide in the groundwaters circulating in the vicinity of the deposition tunnels can react with copper in the canisters causing corrosion and therefore reducing their expected lifetime; in a worst case scenario erosion of the bentonite buffer material will expose the canister more rapidly to the fracture groundwater.Sulphide in the groundwater is predominantly microbially produced and thereby controlled by the content of oxidised sulphur sources, organics (carbon sources), reductants (mainly Fe(II), DOC, H{sub 2} and CH{sub 4}), and also flow and mixing of different groundwater types. In addition, achieved saturation in respect to amorphous Fe-monosulphide will control the possible maximum values and will also limit the Fe2+ and S2- values in the groundwater. The aim of this report is to assess realistic, representative and reliable sulphide groundwater concentrations at present conditions in Forsmark and also to evaluate possible changes during different climatic conditions covering the repository operation period (some tens to hundreds of years), post closure conditions (some thousand of years) and the proceeding temperate period (some tens of thousands of years) which may be extended due to enhanced greenhouse effects etc. It is expected that this period will be followed by the onset of the next glaciation during which periglacial (permafrost), glacial and postglacial conditions may succeed each other. To achieve these aims, an evaluation is performed of all the sulphide-related data reported from the Forsmark site investigations /Laaksoharju et al. 2008/ and later monitoring campaigns, all of which are stored in the Sicada database. This evaluation shows that values from the Complete Chemical Characterisation (CCC) sampling are usually lower than those measured

SR-Site - sulphide content in the groundwater at Forsmark

International Nuclear Information System (INIS)

Tullborg, E-L; Smellie, J; Nilsson, A-Ch; Gimeno, M J; Auque, LF; Bruchert, V; Molinero, J

2010-12-01

Sulphide concentrations in groundwater play a key role in the long-term reliability of the metal canisters containing the radioactive waste within a disposal facility for nuclear waste. This is because sulphide in the groundwaters circulating in the vicinity of the deposition tunnels can react with copper in the canisters causing corrosion and therefore reducing their expected lifetime; in a worst case scenario erosion of the bentonite buffer material will expose the canister more rapidly to the fracture groundwater.Sulphide in the groundwater is predominantly microbially produced and thereby controlled by the content of oxidised sulphur sources, organics (carbon sources), reductants (mainly Fe(II), DOC, H 2 and CH 4 ), and also flow and mixing of different groundwater types. In addition, achieved saturation in respect to amorphous Fe-monosulphide will control the possible maximum values and will also limit the Fe 2+ and S 2- values in the groundwater. The aim of this report is to assess realistic, representative and reliable sulphide groundwater concentrations at present conditions in Forsmark and also to evaluate possible changes during different climatic conditions covering the repository operation period (some tens to hundreds of years), post closure conditions (some thousand of years) and the proceeding temperate period (some tens of thousands of years) which may be extended due to enhanced greenhouse effects etc. It is expected that this period will be followed by the onset of the next glaciation during which periglacial (permafrost), glacial and postglacial conditions may succeed each other. To achieve these aims, an evaluation is performed of all the sulphide-related data reported from the Forsmark site investigations /Laaksoharju et al. 2008/ and later monitoring campaigns, all of which are stored in the Sicada database. This evaluation shows that values from the Complete Chemical Characterisation (CCC) sampling are usually lower than those measured during

The Impact of Post Harvest Agricultural Crop Residue Fires on Volatile Organic Compounds and Formation of Secondary Air Pollutants in the N.W. Indo-Gangetic Plain

Science.gov (United States)

Sinha, V.; Chandra, P.; Kumar, V.; Sarkar, C.

2015-12-01

The N.W. Indo-Gangetic Plain (IGP) is an agriculturally and demographically important region of the world. Every year during the post harvest months of April-May and October-November, large scale open burning of wheat straw and paddy straw occurs in the region impairing the regional air quality and resulting in air pollution episodes. Here, using online in-situ measurements from the IISER Mohali Atmospheric Chemistry Facility (Sinha et al., Atmos Chem Phys, 2014), which is located at a regionally representative suburban site in the agricultural state of Punjab, India, we investigated the effects of this activity on gas phase chemistry. The online data pertaining to the pre harvest and post harvest paddy residue fires in 2012, 2013 and 2014 were analyzed to understand the effect of this anthropogenic activity on atmospheric chemistry and regional air quality with respect to health relevant VOCs such as benzenoids and isocyanic acid and trace gases such as ozone and carbon monoxide. These compounds showed marked increases (factor of 2-3 times higher) in their concentrations which correlated with the biomass combustion tracers such as acetonitrile. Emissions from the paddy residue fires did not result in significant enhancement of ambient ozone in 2012 but instead sustained hourly daytime ozone concentrations at ~ 50 ppb during the late post monsoon season, despite decreases in solar radiation and temperature. Results of such massive perturbations to ambient chemical composition, reactivity and formation of secondary pollutants and its implications for human health will be presented in this paper.

Compendium of ordinances for groundwater protection

Energy Technology Data Exchange (ETDEWEB)

1990-08-01

Groundwater is an extremely important resource in the Tennessee Valley. Nearly two-thirds of the Tennessee Valley's residents rely, at least in part, on groundwater supplies for drinking water. In rural areas, approximately ninety-five percent of residents rely on groundwater for domestic supplies. Population growth and economic development increase the volume and kinds of wastes requiring disposal which can lead to groundwater contamination. In addition to disposal which can lead to groundwater contamination. In addition to disposal problems associated with increases in conventional wastewater and solid waste, technological advancements in recent decades have resulted in new chemicals and increased usage in agriculture, industry, and the home. Unfortunately, there has not been comparable progress in identifying the potential long-term effects of these chemicals, in managing them to prevent contamination of groundwater, or in developing treatment technologies for removing them from water once contamination has occurred. The challenge facing residence of the Tennessee Valley is to manage growth and economic and technological development in ways that will avoid polluting the groundwater resource. Once groundwater has been contaminated, cleanup is almost always very costly and is sometimes impractical or technically infeasible. Therefore, prevention of contamination -- not remedial treatment--is the key to continued availability of usable groundwater. This document discusses regulations to aid in this prevention.

Modeling Effects of Groundwater Basin Closure, and Reversal of Closure, on Groundwater Quality

Science.gov (United States)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2017-12-01

Population growth, the expansion of agriculture, and climate uncertainties have accelerated groundwater pumping and overdraft in aquifers worldwide. In many agricultural basins, a water budget may be stable or not in overdraft, yet disconnected ground and surface water bodies can contribute to the formation of a "closed" basin, where water principally exits the basin as evapotranspiration. Although decreasing water quality associated with increases in Total Dissolved Solids (TDS) have been documented in aquifers across the United States in the past half century, connections between water quality declines and significant changes in hydrologic budgets leading to closed basin formation remain poorly understood. Preliminary results from an analysis with a regional-scale mixing model of the Tulare Lake Basin in California indicate that groundwater salinization resulting from open to closed basin conversion can operate on a decades-to-century long time scale. The only way to reverse groundwater salinization caused by basin closure is to refill the basin and change the hydrologic budget sufficiently for natural groundwater discharge to resume. 3D flow and transport modeling, including the effects of heterogeneity based on a hydrostratigraphic facies model, is used to explore rates and time scales of groundwater salinization and its reversal under different water and land management scenarios. The modeling is also used to ascertain the extent to which local and regional heterogeneity need to be included in order to appropriately upscale the advection-dispersion equation in a basin scale groundwater quality management model. Results imply that persistent managed aquifer recharge may slow groundwater salinization, and complete reversal may be possible at sufficiently high water tables.

Well-Construction, Water-Level, and Water-Quality Data for Ground-Water Monitoring Wells for the J4 Hydrogeologic Study, Arnold Air Force Base, Tennessee

National Research Council Canada - National Science Library

Haugh, Connor J

1996-01-01

...) in Coffee County, Tennessee. The wells ranged from 28 to 289 feet deep and were installed to provide information on subsurface lithology, aquifer characteristics, ground-water levels, and ground-water quality...

Comparison of groundwater residence time using isotope techniques and numerical groundwater flow model in Gneissic Terrain, Korea

International Nuclear Information System (INIS)

Bae, D.S.; Kim, C.S.; Koh, Y.K.; Kim, K.S.; Song, M.Y.

1997-01-01

The prediction of groundwater flow affecting the migration of radionuclides is an important component of the performance assessment of radioactive waste disposal. Groundwater flow in fractured rock mass is controlled by fracture networks, transmissivity and hydraulic gradient. Furthermore the scale-dependent and anisotropic properties of hydraulic parameters are resulted mainly from irregular patterns of fracture system, which are very complex to evaluate properly with the current techniques available. For the purpose of characterizing a groundwater flow in fractured rock mass, the discrete fracture network (DFN) concept is available on the basis of assumptions of groundwater flowing only along fractures and flowpaths in rock mass formed by interconnected fractures. To increase the reliability of assessment in groundwater flow phenomena, numerical groundwater flow model and isotopic techniques were applied. Fracture mapping, borehole acoustic scanning were performed to identify conductive fractures in gneissic terrane. Tracer techniques, using deuterium, oxygen-18 and tritium were applied to evaluate the recharge area and groundwater residence time

The origin of groundwater composition in the Pampeano Aquifer underlying the Del Azul Creek basin, Argentina

International Nuclear Information System (INIS)

Zabala, M.E.; Manzano, M.; Vives, L.

2015-01-01

The Pampean plain is the most productive region in Argentina. The Pampeano Aquifer beneath the Pampean plain is used mostly for drinking water. The study area is the sector of the Pampeano Aquifer underlying the Del Azul Creek basin, in Buenos Aires province. The main objective is to characterize the chemical and isotopic compositions of groundwater and their origin on a regional scale. The methodology used involved the identification and characterization of potential sources of solutes, the study of rain water and groundwater chemical and isotopic characteristics to deduce processes, the development of a hydrogeochemical conceptual model, and its validation by hydrogeochemical modelling with PHREEQC. Groundwater samples come mostly from a two-depth monitoring network of the “Dr. Eduardo J. Usunoff” Large Plains Hydrology Institute (IHLLA). Groundwater salinity increases from SW to NE, where groundwater is saline. In the upper basin groundwater is of the HCO 3 -Ca type, in the middle basin it is HCO 3 -Na, and in the lower basin it is ClSO 4 –NaCa and Cl–Na. The main processes incorporating solutes to groundwater during recharge in the upper basin are rain water evaporation, dissolution of CO 2 , calcite, dolomite, silica, and anorthite; cationic exchange with Na release and Ca and Mg uptake, and clay precipitation. The main processes modifying groundwater chemistry along horizontal flow at 30 m depth from the upper to the lower basin are cationic exchange, dissolution of silica and anorthite, and clay precipitation. The origin of salinity in the middle and lower basin is secular evaporation in a naturally endorheic area. In the upper and middle basins there is agricultural pollution. In the lower basin the main pollution source is human liquid and solid wastes. Vertical infiltration through the boreholes annular space during the yearly flooding stages is probably the pollution mechanism of the samples at 30 m depth. - Highlights: • The work studies the

The origin of groundwater composition in the Pampeano Aquifer underlying the Del Azul Creek basin, Argentina

Energy Technology Data Exchange (ETDEWEB)

Zabala, M.E., E-mail: mzabala@faa.unicen.edu.ar [Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Av. Rivadavia 1917, C1033AAJ Ciudad Autónoma de Buenos Aires (Argentina); Instituto de Hidrología de Llanuras “Dr. Eduardo J. Usunoff”, Av. República Italia 780, 7300 Azul, Provincia Buenos Aires (Argentina); Manzano, M., E-mail: marisol.manzano@upct.es [Escuela de Ingeniería de Caminos, Canales y Puertos y de Ingeniería de Minas, Universidad Politécnica de Cartagena, P° de Alfonso XIII 52, E-30203 Cartagena (Spain); Vives, L., E-mail: lvives@faa.unicen.edu.ar [Instituto de Hidrología de Llanuras “Dr. Eduardo J. Usunoff”, Av. República Italia 780, 7300 Azul, Provincia Buenos Aires (Argentina)

2015-06-15

The Pampean plain is the most productive region in Argentina. The Pampeano Aquifer beneath the Pampean plain is used mostly for drinking water. The study area is the sector of the Pampeano Aquifer underlying the Del Azul Creek basin, in Buenos Aires province. The main objective is to characterize the chemical and isotopic compositions of groundwater and their origin on a regional scale. The methodology used involved the identification and characterization of potential sources of solutes, the study of rain water and groundwater chemical and isotopic characteristics to deduce processes, the development of a hydrogeochemical conceptual model, and its validation by hydrogeochemical modelling with PHREEQC. Groundwater samples come mostly from a two-depth monitoring network of the “Dr. Eduardo J. Usunoff” Large Plains Hydrology Institute (IHLLA). Groundwater salinity increases from SW to NE, where groundwater is saline. In the upper basin groundwater is of the HCO{sub 3}-Ca type, in the middle basin it is HCO{sub 3}-Na, and in the lower basin it is ClSO{sub 4}–NaCa and Cl–Na. The main processes incorporating solutes to groundwater during recharge in the upper basin are rain water evaporation, dissolution of CO{sub 2}, calcite, dolomite, silica, and anorthite; cationic exchange with Na release and Ca and Mg uptake, and clay precipitation. The main processes modifying groundwater chemistry along horizontal flow at 30 m depth from the upper to the lower basin are cationic exchange, dissolution of silica and anorthite, and clay precipitation. The origin of salinity in the middle and lower basin is secular evaporation in a naturally endorheic area. In the upper and middle basins there is agricultural pollution. In the lower basin the main pollution source is human liquid and solid wastes. Vertical infiltration through the boreholes annular space during the yearly flooding stages is probably the pollution mechanism of the samples at 30 m depth. - Highlights: • The

GROUND WATER ASSESSMENT IN AGRICULTURAL AREA, CASE STUDY FROM MACHANG-MALAYSIA (Penilaian Air Tanah di Daerah Pertanian, Studi Kasus di Machang Malaysia

Directory of Open Access Journals (Sweden)

Nur Islami

2010-11-01

Full Text Available ABSTRACT The study area is located in Machang, North Kelantan - Malaysia. The North Kelantan plain is covered with Quaternary sediments overlying granite bedrock. The drainage system is dendritic with the main river flowing into the South China Sea. Hydrogeochemical method was used to study groundwater of shallow aquifer characters within the area. Based on water samples analysis collected from the study area, it can be deduced that the cations and anions concentration are good for domestic use except in the southern region which the nitrate concentration is higher (more than 20 mg/l compared to the northern region (relatively zero. The areas that possibly possess nitrate-contaminated groundwater have been mapped along with groundwater flow patterns. The southern and middle part of the study area has an east to west groundwater flow pattern, making it impossible for contaminated water from the southern region to enter the northern area, despite in the northern area has lower elevation. ABSTRAK Lokasi area studi adalah berada di Machang, Kelantan Utara – Malaysia. Dataran tanah wilayah Kelantan Utara dilapisi oleh batuan Sedimen Kuarter yang mana batuan granit sebagai batuan dasar. Sistem pengairan adalah berbentuk jaringan dendritik dengan sungai utama mengalir ke Laut Cina Selatan. Metoda hydrogeochemical digunakan untuk mempelajari karakter air tanah dari akuifer dangkal untuk keseluruhan area studi. Berdasarkan pada analisa air yang diperoleh dari area studi, dapat disimpulkan bahwa konsentrasi kation dan anion baik digunakan untuk kehidupan sehari hari kecuali air tanah di area sebelah selatan yang mana kandungan nitratnya tinggi (lebih dari 20 mg/l dibandingkan di area sebelah utara (hampir tidak ada kandungan nitrat. Area yang memungkinkan memiliki konsentrasi nitrat pada air tanah dipetakan dengan kombinasi pola aliran air tanah. Pola aliran air tanah di area belahan selatan dan bagian tengah adalah dari timur ke barat yang mana tidak

Isotope characteristics of groundwater in Beishan area

International Nuclear Information System (INIS)

Guo Yonghai; Liu Shufen; Lu Chuanhe

2004-01-01

Using the isotope techniques, the authors studied the origin, evolution and circulation of the groundwater in the potential site of China's high-level waste repository. The results indicate that both deep groundwater and shallow groundwater are mainly recharged by modern and local precipitation, and the deep groundwater in the site area is of meteoric origin. The shallow groundwater is mainly recharged by modern and local precipitation, and the deep groundwater originates from regional precipitation at higher elevation, or might be derived from the precipitation during the geological period of lower temperature. It is also known from the study that the deep underground is a system of very low-permeability where the groundwater flow rates are very low. (author)

Water Resources and Groundwater in a Glaciated Andean Watershed (Cordillera Blanca, Peru)

Science.gov (United States)

McKenzie, J. M.; Gordon, R.; Baraer, M.; Lautz, L.; Mark, B. G.; Wigmore, O.; Chavez, D.; Aubry-Wake, C.

2014-12-01

It is estimated that almost 400 million people live in watersheds where glaciers provide at least 10% of the runoff, yet many questions remain regarding the impact of climate change and glacier recession on water resources derived from these high mountain watersheds. We present research from the Cordillera Blanca, Peru, an area with the highest density of glaciers in the tropics. While glacier meltwater buffers stream discharge throughout the range, groundwater is a major component of dry season runoff, contributing up to 50-70% of outflow in some tributaries. In order to predict future changes to water resources it is critical to understand how groundwater can offset future hydrologic stress by maintaining stream baseflow, including recharge mechanisms, subsurface pathways, storage, and net fluxes to rivers. We present a synthesis of results based on hydrologic modeling, drilling/piezometers, geophysics, and artificial and natural hydrologic tracers. Our findings show that 'pampas', low-relief mountain valleys, are critical for baseflow generation by storing groundwater on interannual timescales. Pampas have a total area of ~65 km2 and are comprised of unconsolidated glacial, talus, lacustrine and wetland (bofedales) deposits. The valleys commonly have buried talus aquifers that are overlain by low permeability, glaciolacustrine deposits. Glaciofluvial outwash deposits and small wetlands also act as unconfined aquifers. These groundwater systems appear to be primarily recharged by wet season precipitation, and at higher elevations also by glacial meltwater. Additionally a ubiquitous feature in the valleys are springs, often located at the base of talus deposits, which generate a large hydrologic flux within the hydrologic systems. While glaciers are the most visible and vulnerable component of the Andean waterscape, we argue that it is crucial to understand the complete mountain hydrologic cycle, including groundwater, in order to understand the ongoing

Water use and groundwater contamination

International Nuclear Information System (INIS)

Elton, J.J.; Livingstone, B.

1998-01-01

A general review of the groundwater resources in Saskatchewan and their vulnerability to contamination was provided. In particular, the use of water and the effects on water by the oil and gas industry in Saskatchewan were discussed. It was suggested that public concerns over scarcity and contamination of water are gradually changing perceptions about Canada's abundance of water. Saskatchewan's surface water covers 12 per cent of the province. About 90 per cent of the rural populations and 80 per cent of municipalities depend on groundwater supplies. Regulations affecting oil and gas operations that could affect water resources have become more stringent. Techniques used in the detection and monitoring of groundwater affected by salt and petroleum hydrocarbons were described. Electromagnetic surveys are used in detecting salt-affected soils and groundwater. Laboratory analysis of chloride concentrations are needed to define actual chloride concentrations in groundwater. Wells and barriers can be installed to control and recover chloride plumes. Deep well injection and reverse osmosis are other methods, but there is no cheap or simple treatment or disposal method for salt-impacted groundwater. Spills or leaks of petroleum hydrocarbons from various sources can also lead to contamination of groundwater. Various assessment and remediation methods are described. Although there is no scarcity of techniques, all of them are difficult, costly, and may take several years to complete. 11 refs., 1 tab

Characterization of colloids in groundwater

International Nuclear Information System (INIS)

Kim, J.I.; Buckau, G.; Klenze, R.

1987-07-01

Natural colloids in the Gorleben aquifer systems have been investigated as for their chemical composition, quantification and size distribution. Humic substances appear to be the major organic materials in these groundwaters, generating humic colloids which are analysed to be humic acid (and fulvic acid) loaded with a large number of trace heavy metal ions. These metal ions include natural homologues of actinides and some fission products in trivalent, tetravalent and hexavalent state. Concentrations of trivalent and tetravalent heavy metal ions are linearly correlated with the dissolved organic carbon (DDC) concentration in different groundwaters. The DOC is found to be present as humic colloids. The Am 3+ ions introduced in such a groundwater readily undergo the generation of its pseudocolloids through sorption or ion exchange reactions with humic colloids. The chemical behaviour of Am(III), being similar to the trivalent metal ions, e.g. Fe 3+ , REE etc. found in natural colloids, has been investigated by laser induced photoacoustic spectroscopy (LPAS). Groundwaters from Ispra, Markham Clinton and Felslabor Grimsel. Bidistilled water and one of Gorleben groundwaters, Gohy 1011, are taken for the purpose of comparison. This groundwater contains the least amount of natural colloids of all Gorleben groundwaters hitherto investigated. An indirect quantification is made by comparison of the LPAS results with experiment from Latex solution. (orig./IRB)

Is groundwater discharge a significant source of carbon dioxide in North Creek, NSW, Australia?

Science.gov (United States)

Atkins, M. L.; Santos, I. R.; Ruiz-Halpern, S.

2012-12-01

Dissolved carbon dioxide is enriched in groundwater. However, the contribution of groundwater discharge as a source of CO2 to freshwater ecosystems, estuaries and coastal waters is poorly understood. CO2 evasion from waterbodies has been considered a significant contributor to the global carbon cycle. We assessed for radon (natural groundwater tracer), pCO2 and other parameters in the tidal North Creek in northern NSW, Australia. Once a natural wetland area, the floodplain has been extensively drained for agricultural and residential development. A 16km high resolution spatial survey revealed increasing radon (up to 17.3 dpm L-1) and pCO2 (up to 11151 μatm) concentration in the upstream direction. Allocated 24-h time series experiments were performed at two fixed sites downstream and upstream. Creek water was continuously pumped into a shower head equilibrator. A Licor-7000 and RAD7 monitor were connected in series in a closed air loop system incorporating the showerhead exchanger to measure pCO2 and radon at 10 minute intervals. Under normal hydrological conditions, radon (17.5 - 58.7 dpm L-1) and pCO2 (3031 - 14880 μatm) concentrations were high. Upstream measurements demonstrated a strong correlation between pCO2 and radon (r2 = 0.81, n = 142, p standard deviation and median flux for the three time series deployments were 167 mmol m-2 d-1, 44 mmol m-2 d-1 and 154 mmol m-2 d-1 respectively, rendering this aquatic system a major pathway of CO2 to the atmosphere. Our observations imply that groundwater discharge drove CO2 dynamics at the upstream site while mangrove respiration drove CO2 at the downstream site. Overall, groundwater discharge accounted for at least 32% of surface water in North Creek. Our observations demonstrate that groundwater seepage is an important factor driving CO2 supersaturation in this coastal creek. Groundwater should be accounted for in CO2 budgets in coastal waters.

Status of ground-water resources at U.S. Navy Support Facility, Diego Garcia; summary of hydrologic and climatic data, January 1994 through September 1996

Science.gov (United States)

Torikai, J.D.

1996-01-01

This report describes the status of ground-water resources at U.S. Navy Support Facility, Diego Garcia. Data presented are from January 1994 through September 1996, with a focus on data from July through September 1996 (third quarter of 1996). A complete database of ground-water withdrawals and chloride-concentration records since 1985 is maintained by the U.S. Geological Survey. Total rainfall for the period July through September 1996 was 8.94 inches, which is 60 percent less than the mean rainfall of 22.23 inches for the period July through September. July and August are part of the annual dry season, while September is the start of the annual wet season. Ground-water withdrawal during July through September 1996 averaged 1,038,300 gallons per day. Withdrawal for the same 3 months in 1995 averaged 888,500 gallons per day. Ground-water withdrawals have steadily increased since about April 1995. At the end of September 1996, the chloride concentration of water from the elevated tanks at Cantonment and Air Operations were 68 and 150 milligrams per liter, respectively. The chloride concentration from all five production areas increased throughout the third quarter of 1996, and started the upward trend in about April 1995. Chloride concentration of ground water in monitoring wells at Cantonment and Air Operations also increased throughout the third quarter of 1996, with the largest increases from water in the deepest monitoring wells. Chloride concentrations have not been at this level since the dry season of 1994. A fuel-pipeline leak at Air Operations in May 1991 decreased total islandwide withdrawals by 15 percent. This lost pumping capacity is being offset by increased pumpage at Cantonment. Six wells do not contribute to the water supply because they are being used to hydraulically divert fuel migration away from water-supply wells by a program of ground-water withdrawal and injection.

Groundwater pollution: Are we monitoring appropriate parameters ...

African Journals Online (AJOL)

Groundwater pollution is a worldwide phenomenon with potentially disastrous consequences. Prevention of pollution is the ideal approach. However, in practice groundwater quality monitoring is the main tool for timely detection of pollutants and protection of groundwater resources. Monitoring groundwater quality is a ...

Status of ground-water resources at U.S. Navy Support Facility, Diego Garcia; summary of hydrologic and climatic data, January 1994 through March 1996

Science.gov (United States)

Torikai, J.D.

1996-01-01

This report describes the status of ground-water resources at U.S. Navy Support Facility, Diego Garcia. Data presented are from January 1994 through March 1996, with a focus on data from January through March 1996 (first quarter of 1996). A complete database of ground-water withdrawals and chloride-concentration records since 1985 is maintained by the U.S. Geological Survey. Cumulative rainfall for January through March 1996 was about 30 inches, which is 9 percent less than the mean cumulative rainfall of about 33 inches for January through March. The period January through February is the end of the annual wet season, while March marks the start of the annual dry season. Ground-water withdrawal during January through March 1996 averaged 970,300 gallons per day. Withdrawal for the same 3 months in 1995 averaged 894,600 gallons per day. With- drawal patterns during the first quarter of 1996 did not change significantly since 1991, with the Cantonment and Air Operations areas supplying about 99 percent of total islandwide pumpage. At the end of March 1996, the chloride concentration of water from the elevated tanks at Cantonment and Air Operations were 47 and 80 milligrams per liter, respectively. The chloride data from all five production areas showed no significant upward or downward trends throughout the first quarter of 1996. Potable levels of chloride concentrations have been maintained by adjusting individual pumping rates, and also because of the absence of long-term droughts. Chloride concentration of ground water in monitoring wells at Cantonment and Air Operations also showed no significant trends throughout the first quarter of 1996. Chloride concentrations have been about the same since the last quarter of 1995. A fuel-pipeline leak at Air Operations in May 1991 decreased total islandwide withdrawals by 15 percent. This lost pumping capacity is being offset by increased pumpage at Cantonment. Six wells do not contribute to the water supply because they

Status of ground-water resources at U.S. Navy Support Facility, Diego Garcia; summary of hydrologic and climatic data, January 1994 through June 1996

Science.gov (United States)

Torikai, J.D.

1996-01-01

This report describes the status of ground-water resources at U.S. Navy Support Facility, Diego Garcia. Data presented are from January 1994 through June 1996, with a focus on data from April through June 1996 (second quarter of 1996). A complete database of ground-water withdrawals and chloride-concentration records since 1985 is maintained by the U.S. Geological Survey. Cumulative rainfall for April through June 1996 was 22.64 inches, which is 12 percent more than the mean cumulative rainfall of 20.21 inches for April through June. The period April through June is part of the annual dry season. Ground-water withdrawal during April through June 1996 averaged 1,048,000 gallons per day. Withdrawal for the same 3 months in 1995 averaged 833,700 gallons per day. Withdrawal patterns during the second quarter of 1996 did not change significantly since 1991, with the Cantonment and Air Operations areas supplying about 99 percent of total islandwide pumpage. At the end of June 1996, the chloride concentration of water from the elevated tanks at Cantonment and Air Operations were 52 and 80 milligrams per liter, respectively. The chloride data from all five production areas showed no significant upward or downward trends throughout the second quarter of 1996. Potable levels of chloride concentrations have been maintained by adjusting individual pumping rates, and also because of the absence of long-term droughts. Chloride concentration of ground water in monitoring wells at Cantonment and Air Operations also showed no significant trends throughout the second quarter of 1996. Chloride concentrations have been about the same since the last quarter of 1995. A fuel-pipeline leak at Air Operations in May 1991 decreased total islandwide withdrawals by 15 percent. This lost pumping capacity is being offset by increased pumpage at Cantonment. Six wells do not contribute to the water supply because they are being used to hydraulically divert fuel migration away from water

Quantifying anthropogenic contributions to century-scale groundwater salinity changes, San Joaquin Valley, California, USA

Science.gov (United States)

Hansen, Jeffrey; Jurgens, Bryant; Fram, Miranda S.

2018-01-01

Total dissolved solids (TDS) concentrations in groundwater tapped for beneficial uses (drinking water, irrigation, freshwater industrial) have increased on average by about 100 mg/L over the last 100 years in the San Joaquin Valley, California (SJV). During this period land use in the SJV changed from natural vegetation and dryland agriculture to dominantly irrigated agriculture with growing urban areas. Century-scale salinity trends were evaluated by comparing TDS concentrations and major ion compositions of groundwater from wells sampled in 1910 (Historic) to data from wells sampled in 1993-2015 (Modern). TDS concentrations in subregions of the SJV, the southern (SSJV), western (WSJV), northeastern (NESJV), and southeastern (SESJV) were calculated using a cell-declustering method. TDS concentrations increased in all regions, with the greatest increases found in the SSJV and SESJV. Evaluation of the Modern data from the NESJV and SESJV found higher TDS concentrations in recently recharged (post-1950) groundwater from shallow (soil amendments combined. Bicarbonate showed the greatest increase among major ions, resulting from enhanced silicate weathering due to recharge of irrigation water enriched in CO2 during the growing season. The results of this study demonstrate that large anthropogenic changes to the hydrologic regime, like massive development of irrigated agriculture in semi-arid areas like the SJV, can cause large changes in groundwater quality on a regional scale.

Calendar Year 2016 Annual Groundwater Monitoring Report.

Energy Technology Data Exchange (ETDEWEB)

Copland, John R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jackson, Timmie Okchumpulla [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Li, Jun [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Mitchell, Michael Marquand [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Skelly, Michael [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2017-06-01

Sandia National Laboratories, New Mexico (SNL/NM) is a government-owned/contractoroperated laboratory. National Technology and Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International, Inc., manages and operates SNL/NM for the U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA). The DOE/NNSA Sandia Field Office administers the contract and oversees contractor operations at the site. Two types of groundwater surveillance monitoring are conducted at SNL/NM: (1) on a site-wide basis as part of the SNL/NM Long-Term Stewardship (LTS) Program’s Groundwater Monitoring Program (GMP) Groundwater Surveillance Task and (2) on a site-specific groundwater monitoring at LTS/Environmental Restoration (ER) Operations sites with ongoing groundwater investigations. This Annual Groundwater Monitoring Report summarizes data collected during groundwater monitoring events conducted at GMP locations and at the following SNL/NM sites through December 31, 2016: Burn Site Groundwater Area of Concern (AOC); Chemical Waste Landfill; Mixed Waste Landfill; Technical Area-V Groundwater AOC; and the Tijeras Arroyo Groundwater AOC. Environmental monitoring and surveillance programs are required by the New Mexico Environment Department (NMED) and DOE Order 436.1, Departmental Sustainability, and DOE Order 231.1B, Environment, Safety, and Health Reporting.

Calendar Year 2007 Resource Conservation and Recovery Act Annual Monitoring Report for the U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee - RCRA Post-Closure Permit Nos. TNHW-113, TNHW-116, and TNHW-128

Energy Technology Data Exchange (ETDEWEB)

Elvado Environmental

2008-02-01

This report contains groundwater quality monitoring data obtained during calendar year (CY) 2007 at the following hazardous waste treatment, storage, and disposal (TSD) units located at the US Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) in Oak Ridge, Tennessee; this S-3 Site, Oil Landfarm, Bear Creek Burial Grounds/Walk-In Pits (BCBG/WIP), Eastern S-3 Site Plume, Chestnut Ridge Security Pits (CRSP), Chestnut Ridge Sediment Disposal Baste (CRSDB), few Hollow Quarry (KHQ), and East Chestnut Ridge Waste Pile (ECRWP). Hit monitoring data were obtained in accordance with the applicable Resource Conservation and Recovery Act of 1976 (RCRA) hazardous waste post-closure permit (PCP). The Tennessee Department of Environment and Conservation (TDEC) - Division of Solid Waste Management issued the PCPs to define the requirements for RCRA post-closure inspection, maintenance, and groundwater monitoring at the specified TSD units located within the Bear Creek Hydrogeologic Regime (PCP no. TNHW-116), Upper East Fork Poplar Creek Hydrogeologic Regime (PCP no. TNHW-113), and Chestnut Ridge Hydrogeologic Regime (PCP no. TNHW-128). Each PCP requires the Submittal of an annual RCRA groundwater monitoring report containing the groundwater sampling information and analytical results obtained at each applicable TSD unit during the preceding CY, along with an evaluation of groundwater low rates and directions and the analytical results for specified RCRA groundwater target compounds; this report is the RCRA annual groundwater monitoring report for CY 2007. The RCRA post-closure groundwater monitoring requirements specified in the above-referenced PCP for the Chestnut Ridge Regime replace those defined in the previous PCP (permit no. TNHW-088), which expired on September 18, 2005, but remained effective until the TDEC issued the new PCP in September 2006. The new PCP defines site-specific groundwater sampling and analysis requirements for the

A high-resolution global-scale groundwater model

Science.gov (United States)

de Graaf, I. E. M.; Sutanudjaja, E. H.; van Beek, L. P. H.; Bierkens, M. F. P.

2015-02-01

Groundwater is the world's largest accessible source of fresh water. It plays a vital role in satisfying basic needs for drinking water, agriculture and industrial activities. During times of drought groundwater sustains baseflow to rivers and wetlands, thereby supporting ecosystems. Most global-scale hydrological models (GHMs) do not include a groundwater flow component, mainly due to lack of geohydrological data at the global scale. For the simulation of lateral flow and groundwater head dynamics, a realistic physical representation of the groundwater system is needed, especially for GHMs that run at finer resolutions. In this study we present a global-scale groundwater model (run at 6' resolution) using MODFLOW to construct an equilibrium water table at its natural state as the result of long-term climatic forcing. The used aquifer schematization and properties are based on available global data sets of lithology and transmissivities combined with the estimated thickness of an upper, unconfined aquifer. This model is forced with outputs from the land-surface PCRaster Global Water Balance (PCR-GLOBWB) model, specifically net recharge and surface water levels. A sensitivity analysis, in which the model was run with various parameter settings, showed that variation in saturated conductivity has the largest impact on the groundwater levels simulated. Validation with observed groundwater heads showed that groundwater heads are reasonably well simulated for many regions of the world, especially for sediment basins (R2 = 0.95). The simulated regional-scale groundwater patterns and flow paths demonstrate the relevance of lateral groundwater flow in GHMs. Inter-basin groundwater flows can be a significant part of a basin's water budget and help to sustain river baseflows, especially during droughts. Also, water availability of larger aquifer systems can be positively affected by additional recharge from inter-basin groundwater flows.

Mapping groundwater quality in the Netherlands

NARCIS (Netherlands)

Pebesma, Edzer Jan

1996-01-01

Groundwater quality is the suitability of groundwater for a certain purpose (e.g. for human consumption), and is mostly determined by its chemical composition. Pollution from agricultural and industrial origin threatens the groundwater quality in the Netherlands. Locally, this pollution is

NORTH CAROLINA GROUNDWATER RECHARGE RATES 1994

Science.gov (United States)

North Carolina Groundwater Recharge Rates, from Heath, R.C., 1994, Ground-water recharge in North Carolina: North Carolina State University, as prepared for the NC Department of Environment, Health and Natural Resources (NC DEHNR) Division of Enviromental Management Groundwater S...

Groundwater Quality Assessment Based on Geographical Information System and Groundwater Quality Index

Directory of Open Access Journals (Sweden)

Zahra Derakhshan

2015-06-01

Full Text Available Iran is located in an arid and semi-arid part of the world. Accordingly, the management of the water resources in the country is a priority. In this regard, determining the quality and pollution of surface water and groundwater is very important, especially in areas where groundwater resources are used for drinking. Groundwater quality index (GQI checks the components of the available water with various quality levels. To assess the quality of drinking groundwater of Yazd-Ardakan plain according to GQI in geographical information system (GIS environment, the electrical conductivity, sodium, calcium, magnesium, chlorine, pH, sodium adsorption ratio, bicarbonate, sulfate, potassium, water hardness, and all substances dissolved in the waters of 80 wells were determined. The samples were obtained from Yazd Regional Water Organization from 2005 to 2014. Using this data, the map components were plotted by Kriging geostatistical method. Then, the map of GQI was prepared after normalizing each map component, switching to a rating map, and extracting the weight of each component from the rating map. Based on the GQI index map, the index point which was 87 in 2005 has increased to 81 in 2014. These maps show a decline in groundwater quality from west to the east region. This decline in groundwater quality is due to the existence of Neogene Organizations in the east and geomorphologic unit of the bare epandage pediment in the west. The map removal and single-parameter sensitivity analysis showed that GQI index in Yazd-Ardakan plain is more sensitive to the components of electrical conductivity (EC, total dissolved solids (TDS, and total hardness (TH. Therefore, these components should be monitored more carefully and repeatedly.

GROUNDWATER PROTECTION MANAGEMENT PROGRAM DESCRIPTION.

Energy Technology Data Exchange (ETDEWEB)

PAQUETTE,D.E.; BENNETT,D.B.; DORSCH,W.R.; GOODE,G.A.; LEE,R.J.; KLAUS,K.; HOWE,R.F.; GEIGER,K.

2002-05-31

THE DEPARTMENT OF ENERGY ORDER 5400.1, GENERAL ENVIRONMENTAL PROTECTION PROGRAM, REQUIRES THE DEVELOPMENT AND IMPLEMENTATION OF A GROUNDWATER PROTECTION PROGRAM. THE BNL GROUNDWATER PROTECTION MANAGEMENT PROGRAM DESCRIPTION PROVIDES AN OVERVIEW OF HOW THE LABORATORY ENSURES THAT PLANS FOR GROUNDWATER PROTECTION, MONITORING, AND RESTORATION ARE FULLY DEFINED, INTEGRATED, AND MANAGED IN A COST EFFECTIVE MANNER THAT IS CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS.

Understanding groundwater - students' pre-conceptions and conceptual change by means of a theory-guided multimedia learning program

Science.gov (United States)

Unterbruner, Ulrike; Hilberg, Sylke; Schiffl, Iris

2016-06-01

Education on the subject of groundwater is crucial for sustainability. Nevertheless, international studies with students across different age groups have shown that the basic hydrogeological concept of groundwater defined as water within porous and permeable rocks is not an established everyday notion. Drawing from international research, a multimedia learning program Zwischen Regenwolke und Wasserhahn (between the rain cloud and the tap) was developed, which incorporates specific insights from the fields of conceptual change research, multimedia research, and the model of educational reconstruction. The effectiveness of the learning program was ascertained by means of two studies with Austrian seventh grade pupils as well as teacher-training students from the fields of biology and geography in order to ascertain the effectiveness of the learning program. Using a quasi-experimental research design, the participants' conceptions and knowledge of groundwater were determined in a pre- and post-test. The pupils and students greatly benefitted from working through the learning software independently. Their knowledge of groundwater increased significantly compared to the control group and there was a highly significant increase in the number of scientifically correct notions of groundwater. The acceptance of the program was also generally very high. The results indicate that theory-guided multimedia learning programs can play an important role in the transfer of research results to classroom settings, especially in science education.

Analysis of 1997–2008 groundwater level changes in the upper Deschutes Basin, Central Oregon

Science.gov (United States)

Gannett, Marshall W.; Lite, Kenneth E.

2013-01-01

Groundwater-level monitoring in the upper Deschutes Basin of central Oregon from 1997 to 2008 shows water-level declines in some places that are larger than might be expected from climate variations alone, raising questions regarding the influence of groundwater pumping, canal lining (which decreases recharge), and other human influences. Between the mid-1990s and mid-2000s, water levels in the central part of the basin near Redmond steadily declined as much as 14 feet. Water levels in the Cascade Range, in contrast, rose more than 20 feet from the mid-1990s to about 2000, and then declined into the mid-2000s, with little or no net change. An existing U.S. Geological Survey regional groundwater-flow model was used to gain insights into groundwater-level changes from 1997 to 2008, and to determine the relative influence of climate, groundwater pumping, and irrigation canal lining on observed water-level trends. To utilize the model, input datasets had to be extended to include post-1997 changes in groundwater pumping, changes in recharge from precipitation, irrigation canal leakage, and deep percolation of applied irrigation water (also known as on-farm loss). Mean annual groundwater recharge from precipitation during the 1999–2008 period was 25 percent less than during the 1979–88 period because of drying climate conditions. This decrease in groundwater recharge is consistent with measured decreases in streamflow and discharge to springs. For example, the mean annual discharge of Fall River, which is a spring-fed stream, decreased 12 percent between the 1979–88 and 1999–2008 periods. Between the mid-1990s and late 2000s, groundwater pumping for public-supply and irrigation uses increased from about 32,500 to 52,000 acre-feet per year, partially because of population growth. Between 1997 and 2008, the rate of recharge from leaking irrigation canals decreased by about 58,000 acre-feet per year as a result of lining and piping of canals. Decreases in recharge

The role of groundwater in the effect of climatic warming on stream habitat of brook trout

International Nuclear Information System (INIS)

Meisner, J.D.

1990-01-01

Freshwater fisheries are linked to climate through the variables of water temperature, water quality and water quantity. These three ecosystem linkages provide a basis for assessments of potential impacts of climate change on fisheries resources. A characteristic of fisheries resources, whether it be the size or distribution of fish populations, or a measure of yield, which can be related to climate through one or more of these linkages, is a useful tool with which to forecast the effects of climate change. A stream population of brook trout is a coldwater fisheries resource that is linked to climate by groundwater. Stream dwelling brook trout at low altitudes rely heavily on groundwater discharge in summer to maintain low stream temperature. Groundwater temperature tracks mean annual air temperature due to the insulative effect of the lower troposphere on the surface of the earth. The effect of elevated groundwater temperature on the stream habitat of brook trout was investigated in two brook trout streams north of Toronto, Ontario, with an energy balance stream temperature model, calibrated to both streams to simulate maximum water temperature observed in the brook trout zones. Simulated maximum summer temperatures from the Goddard Institute for Space Studies scenario reduced the brook trout zones by up to 42%. 17 refs., 2 figs

Water infiltration in an aquifer recharge basin affected by temperature and air entrapment

OpenAIRE

Loizeau Sébastien; Rossier Yvan; Gaudet Jean-Paul; Refloch Aurore; Besnard Katia; Angulo-Jaramillo Rafael; Lassabatere Laurent

2017-01-01

Artificial basins are used to recharge groundwater and protect water pumping fields. In these basins, infiltration rates are monitored to detect any decrease in water infiltration in relation with clogging. However, miss-estimations of infiltration rate may result from neglecting the effects of water temperature change and air-entrapment. This study aims to investigate the effect of temperature and air entrapment on water infiltration at the basin scale by conducting successive infiltration c...

Building groundwater modeling capacity in Mongolia

Science.gov (United States)

Valder, Joshua F.; Carter, Janet M.; Anderson, Mark T.; Davis, Kyle W.; Haynes, Michelle A.; Dorjsuren Dechinlhundev,

2016-06-16

Ulaanbaatar, the capital city of Mongolia (fig. 1), is dependent on groundwater for its municipal and industrial water supply. The population of Mongolia is about 3 million people, with about one-half the population residing in or near Ulaanbaatar (World Population Review, 2016). Groundwater is drawn from a network of shallow wells in an alluvial aquifer along the Tuul River. Evidence indicates that current water use may not be sustainable from existing water sources, especially when factoring the projected water demand from a rapidly growing urban population (Ministry of Environment and Green Development, 2013). In response, the Government of Mongolia Ministry of Environment, Green Development, and Tourism (MEGDT) and the Freshwater Institute, Mongolia, requested technical assistance on groundwater modeling through the U.S. Army Corps of Engineers (USACE) to the U.S. Geological Survey (USGS). Scientists from the USGS and USACE provided two workshops in 2015 to Mongolian hydrology experts on basic principles of groundwater modeling using the USGS groundwater modeling program MODFLOW-2005 (Harbaugh, 2005). The purpose of the workshops was to bring together representatives from the Government of Mongolia, local universities, technical experts, and other key stakeholders to build in-country capacity in hydrogeology and groundwater modeling.A preliminary steady-state groundwater-flow model was developed as part of the workshops to demonstrate groundwater modeling techniques to simulate groundwater conditions in alluvial deposits along the Tuul River in the vicinity of Ulaanbaatar. ModelMuse (Winston, 2009) was used as the graphical user interface for MODFLOW for training purposes during the workshops. Basic and advanced groundwater modeling concepts included in the workshops were groundwater principles; estimating hydraulic properties; developing model grids, data sets, and MODFLOW input files; and viewing and evaluating MODFLOW output files. A key to success was

Isolation and identification of Trichoderma harzianum from groundwater: An effective biosorbent for defluoridation of groundwater.

Science.gov (United States)

Koshle, Shalini; Mahesh, S; Swamy, S Nanjunda

2016-01-01

The ability of non-viable form of Trichoderma harzianum, isolated from fluoride rich groundwater, was investigated as biosorbent for defluoridation of groundwater. Biosorption experiments were carried out at laboratory scale for removal of fluoride from groundwater. Significant effect of operational parameters on fluoride biosorption using Trichoderma harzianum as biosorbent was evaluated by varying operational parameters such as: initial fluoride concentration (2-8 mgl(-1)), biosorbent dose (0.4-1.6g/100ml), groundwater pH (6-10), temperature (30-50 degrees C) and biosorption time (30-120 min). The fluoride adsorption isotherms were modeled by Langmuir and Freundlich isotherms. Our result showed that fluoride biosorption, significantly increased with increase in groundwater pH, biosorbent dose, temperature and biosorption time, whereas increase in initial fluoride concentration reduced fluoride removal. The fluoride biosorption was rapid and maximum fluoride uptake was attained with 1.6g 100ml(-1) biosorbent within 60 min. Optimal pH 10 and temperature 50 degrees C gave maximum defluoridation efficiency. Freundlich isotherm fits well for defluoridation of groundwater using Trichoderma harzianum as biosorbent which indicated that biosorbent surface sites were heterogeneous in nature and fitted into heterogeneous site binding model.

H-Area Seepage Basins groundwater monitoring report -- third and fourth quarters 1993

International Nuclear Information System (INIS)

Butler, C.T.

1994-03-01

During the second half of 1993, the groundwater at the H-Area Seepage Basins (HASB) was monitored in compliance with the September 30, 1992, modification of South Carolina Hazardous Waste Permit SC1-890-008-989. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B post-closure care permit application for the H-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1990. Beginning first quarter 1993, the HASB's Groundwater Protection Standard (GWPS), established in Appendix 3D-A of the cited permit, became the standard for comparison. Historically as well as currently, nitrate, nonvolatile beta, and tritium have been among the primary constituents to exceed standards. Other radionuclides and hazardous constitutents also exceeded the GWPS in the groundwater at the HASB (notably aluminum, iodine-129, strontium-90, technetium-99, and zinc) during the second half of 1993. Elevated constituents were found primarily in Aquifer Zone 2B 2 and in the upper portion of Aquifer Zone 2B 1 . However, constituents exceeding standards also occurred in several wells screened in the lower portion of Aquifer Zone 2B 1 and Aquifer Unit 2A. Isoconcentration/isoactivity maps include in this report indicate both the concentration/activity and extent of the primary contaminants in each of the three hydrostratigraphic units during the second half of 1993. Water-level maps indicate that the groundwater flow rates and directions at the HASB have remained relatively constant since the basins ceased to be active in 1988

The origin of groundwater composition in the Pampeano Aquifer underlying the Del Azul Creek basin, Argentina.

Science.gov (United States)

Zabala, M E; Manzano, M; Vives, L

2015-06-15

The Pampean plain is the most productive region in Argentina. The Pampeano Aquifer beneath the Pampean plain is used mostly for drinking water. The study area is the sector of the Pampeano Aquifer underlying the Del Azul Creek basin, in Buenos Aires province. The main objective is to characterize the chemical and isotopic compositions of groundwater and their origin on a regional scale. The methodology used involved the identification and characterization of potential sources of solutes, the study of rain water and groundwater chemical and isotopic characteristics to deduce processes, the development of a hydrogeochemical conceptual model, and its validation by hydrogeochemical modelling with PHREEQC. Groundwater samples come mostly from a two-depth monitoring network of the "Dr. Eduardo J. Usunoff" Large Plains Hydrology Institute (IHLLA). Groundwater salinity increases from SW to NE, where groundwater is saline. In the upper basin groundwater is of the HCO3-Ca type, in the middle basin it is HCO3-Na, and in the lower basin it is ClSO4-NaCa and Cl-Na. The main processes incorporating solutes to groundwater during recharge in the upper basin are rain water evaporation, dissolution of CO2, calcite, dolomite, silica, and anorthite; cationic exchange with Na release and Ca and Mg uptake, and clay precipitation. The main processes modifying groundwater chemistry along horizontal flow at 30 m depth from the upper to the lower basin are cationic exchange, dissolution of silica and anorthite, and clay precipitation. The origin of salinity in the middle and lower basin is secular evaporation in a naturally endorheic area. In the upper and middle basins there is agricultural pollution. In the lower basin the main pollution source is human liquid and solid wastes. Vertical infiltration through the boreholes annular space during the yearly flooding stages is probably the pollution mechanism of the samples at 30 m depth. Copyright © 2015 Elsevier B.V. All rights reserved.

HANFORD GROUNDWATER REMEDIATION

Energy Technology Data Exchange (ETDEWEB)

CHARBONEAU, B; THOMPSON, M; WILDE, R.; FORD, B.; GERBER, M.S.

2006-02-01

By 1990 nearly 50 years of producing plutonium put approximately 1.70E + 12 liters (450 billion gallons) of liquid wastes into the soil of the 1,518-square kilometer (586-square mile) Hanford Site in southeast Washington State. The liquid releases consisted of chemicals used in laboratory experiments, manufacturing and rinsing uranium fuel, dissolving that fuel after irradiation in Hanford's nuclear reactors, and in liquefying plutonium scraps needed to feed other plutonium-processing operations. Chemicals were also added to the water used to cool Hanford's reactors to prevent corrosion in the reactor tubes. In addition, water and acid rinses were used to clean plutonium deposits from piping in Hanford's large radiochemical facilities. All of these chemicals became contaminated with radionuclides. As Hanford raced to help win World War II, and then raced to produce materials for the Cold War, these radioactive liquid wastes were released to the Site's sandy soils. Early scientific experiments seemed to show that the most highly radioactive components of these liquids would bind to the soil just below the surface of the land, thus posing no threat to groundwater. Other experiments predicted that the water containing most radionuclides would take hundreds of years to seep into groundwater, decaying (or losing) most of its radioactivity before reaching the groundwater or subsequently flowing into the Columbia River, although it was known that some contaminants like tritium would move quickly. Evidence today, however, shows that many contaminants have reached the Site's groundwater and the Columbia River, with more on its way. Over 259 square kilometers (100 square miles) of groundwater at Hanford have contaminant levels above drinking-water standards. Also key to successfully cleaning up the Site is providing information resources and public-involvement opportunities to Hanford's stakeholders. This large, passionate, diverse, and

Monitoring probe for groundwater flow

Science.gov (United States)

Looney, B.B.; Ballard, S.

1994-08-23

A monitoring probe for detecting groundwater migration is disclosed. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow. 4 figs.

Simulation–optimization model for groundwater contamination ...

Indian Academy of Sciences (India)

used techniques for groundwater remediation in which the contaminated groundwater is pumped ... ing the affected groundwater aquifer down to some drinking water standard. Several .... For simplicity, rectangular support domain is used in this study. Figure 1 ..... For PAT remediation system, decision variables include the.

State space modeling of groundwater fluctuations

NARCIS (Netherlands)

Berendrecht, W.L.

2004-01-01

Groundwater plays an important role in both urban and rural areas. It is therefore essential to monitor groundwater fluctuations. However, data that becomes available need to be analyzed further in order to extract specific information on the groundwater system. Until recently, simple linear time

Air sparging/high vacuum extraction to remove chlorinated solvents in groundwater and soil

International Nuclear Information System (INIS)

Phelan, J.M.; Gilliat, M.D.

1998-01-01

An air sparging and high vacuum extraction was installed as an alternative to a containment pump and treat system to reduce the long-term remediation schedule. The site is located at the DOE Mound facility in Miamisburg, Ohio, just south of Dayton. The air sparging system consists of 23 wells interspersed between 17 soil vapor extraction wells. The SVE system has extracted about 1,500 lbs of VOCs in five months. The air sparging system operated for about 6 weeks before shutdown due to suspected biochemical fouling. Technical data are presented on the operating characteristics of the system

Controlling groundwater pumping online.

Science.gov (United States)

Zekri, Slim

2009-08-01

Groundwater over-pumping is a major problem in several countries around the globe. Since controlling groundwater pumping through water flow meters is hardly feasible, the surrogate is to control electricity usage. This paper presents a framework to restrict groundwater pumping by implementing an annual individual electricity quota without interfering with the electricity pricing policy. The system could be monitored online through prepaid electricity meters. This provides low transaction costs of individual monitoring of users compared to the prohibitive costs of water flow metering and monitoring. The public groundwater managers' intervention is thus required to determine the water and electricity quota and watch the electricity use online. The proposed framework opens the door to the establishment of formal groundwater markets among users at very low transaction costs. A cost-benefit analysis over a 25-year period is used to evaluate the cost of non-action and compare it to the prepaid electricity quota framework in the Batinah coastal area of Oman. Results show that the damage cost to the community, if no active policy is implemented, amounts to (-$288) million. On the other hand, the implementation of a prepaid electricity quota with an online management system would result in a net present benefit of $199 million.

Radioecological aspects in artificial groundwater recharge

Energy Technology Data Exchange (ETDEWEB)

Matthess, G [Kiel Univ. (Germany, F.R.). Geologisch-Palaeontologisches Inst. und Museum; Neumayr, V [Institut fuer Wasser-, Boden- und Lufthygiene, Frankfurt am Main (Germany, F.R.)

1980-01-01

In increasing extent surface waters, especially those of rivers and streams, are contaminated by radionuclides. Therefore it is necessary to investigate the possibility of impairment of the quality of artificially recharged groundwater and drinking water by radionuclides. Hazards for man are possible by drinking water, that was affected by waste and during exposition to air, as well as indirectly by irrigation water and the food chain. In a model calculation using realistic conditions the order of magnitude of these hazards for man by incorporation of radioactively contaminated artificially recharged drinking water are to be assessed. Here the parameters are discussed which must be considered in such an assessment. The model includes the use of river water for artificial recharge. All models and assessments assume the most unfavourable preconditions, which may lead to an impact to man.

Mapping and quantifying groundwater inflows to Deep Creek (Maribyrnong catchment, SE Australia) using 222Rn, implications for protecting groundwater-dependant ecosystems

International Nuclear Information System (INIS)

Cartwright, Ian; Gilfedder, Benjamin

2015-01-01

Highlights: • Groundwater inflows in a chain-of-ponds river quantified. • Groundwater inflow vs. discharge relationship determined using Rn. • First long-term continuous Rn monitoring in a river indicates temporal changes to groundwater inflows. • Application to protection of groundwater-dependant ecosystems. - Abstract: Understanding groundwater inflows to rivers is important in managing connected groundwater and surface water systems and for protecting groundwater-dependant ecosystems. This study defines the distribution of gaining reaches and estimates groundwater inflows to a 62 km long section of Deep Creek (Maribyrnong catchment, Australia) using 222 Rn. During summer months, Deep Creek ceases to flow and comprises a chain of ponds that δ 18 O and δ 2 H values, major ion concentrations, and 222 Rn activities imply are groundwater fed. During the period where the river flows, the relative contribution of groundwater inflows to total river discharge ranges from ∼14% at high flow conditions to ∼100% at low flows. That the predicted groundwater inflows account for all of the increase in discharge at low flow conditions lends confidence to the mass balance calculations. Near-continuous 27 week 222 Rn monitoring at one location in the middle of the catchment confirms the inverse correlation between river discharge and relative groundwater inflows, and also implies that there are limited bank return flows. Variations in groundwater inflows are related to geology and topography. High groundwater inflows occur where the river is at the edge of its floodplain, adjacent to hills composed of basement rocks, or flowing through steep incised valleys. Understanding the distribution of groundwater inflows and quantifying the contribution of groundwater to Deep Creek is important for managing and protecting the surface water resources, which support the endangered Yarra pygmy perch

Kalahari groundwaters: Their hydrogen, carbon and oxygen isotopes

International Nuclear Information System (INIS)

Mazor, E.; Verhagen, B.T.; Sellschop, J.P.F.; Robins, N.S.; Hutton, L.G.

1974-01-01

Tritium and 14 C measurements have revealed several cases of post-nuclear bomb-test rain recharge of local groundwaters, along with values indicating recharge over larger, yet hydrologically active, time scales. In general, recharge seems to follow rain distribution in being more intense in the northern rather than in the southern Kalahari. Initial δ 13 C values vary over a wide range and reveal some correlation to pH and chemical composition of the water. They cannot be used to correct for fossil carbon dilution in 14 C-age calculations. Radiocarbon-deduced ages range from recent to 30,000 years. Stable hydrogen and oxygen isotopes indicate recharge from direct rain infiltration. (author)

Transfer of European Approach to Groundwater Monitoring in China

Science.gov (United States)

Zhou, Y.

2007-12-01

Major groundwater development in North China has been a key factor in the huge economic growth and the achievement of self sufficiency in food production. Groundwater accounts for more than 70 percent of urban water supply and provides important source of irrigation water during dry period. This has however caused continuous groundwater level decline and many associated problems: hundreds of thousands of dry wells, dry river beds, land subsidence, seawater intrusion and groundwater quality deterioration. Groundwater levels in the shallow unconfined aquifers have fallen 10m up to 50m, at an average rate of 1m/year. In the deep confined aquifers groundwater levels have commonly fallen 30m up to 90m, at an average rate of 3 to 5m/year. Furthermore, elevated nitrate concentrations have been found in shallow groundwater in large scale. Pesticides have been detected in vulnerable aquifers. Urgent actions are necessary for aquifer recovery and mitigating groundwater pollution. Groundwater quantity and quality monitoring plays a very important role in formulating cost-effective groundwater protection strategies. In 2000 European Union initiated a Water Framework Directive (2000/60/EC) to protect all waters in Europe. The objective is to achieve good water and ecological status by 2015 cross all member states. The Directive requires monitoring surface and groundwater in all river basins. A guidance document for monitoring was developed and published in 2003. Groundwater monitoring programs are distinguished into groundwater level monitoring and groundwater quality monitoring. Groundwater quality monitoring is further divided into surveillance monitoring and operational monitoring. The monitoring guidance specifies key principles for the design and operation of monitoring networks. A Sino-Dutch cooperation project was developed to transfer European approach to groundwater monitoring in China. The project aims at building a China Groundwater Information Centre. Case studies

Current Status of Groundwater Monitoring Networks in Korea

Directory of Open Access Journals (Sweden)

Jin-Yong Lee

2016-04-01

Full Text Available Korea has been operating groundwater monitoring systems since 1996 as the Groundwater Act enacted in 1994 enforces nationwide monitoring. Currently, there are six main groundwater monitoring networks operated by different government ministries with different purposes: National Groundwater Monitoring Network (NGMN, Groundwater Quality Monitoring Network (GQMN, Seawater Intrusion Monitoring Network (SIMN, Rural Groundwater Monitoring Network (RGMN, Subsidiary Groundwater Monitoring Network (SGMN, and Drinking Water Monitoring Network (DWMN. The Networks have a total of over 3500 monitoring wells and the majority of them are now equipped with automatic data loggers and remote terminal units. Most of the monitoring data are available to the public through internet websites. These Networks have provided scientific data for designing groundwater management plans and contributed to securing the groundwater resource particularly for recent prolonged drought seasons. Each Network, however, utilizes its own well-specifications, probes, and telecommunication protocols with minimal communication with other Networks, and thus duplicate installations of monitoring wells are not uncommon among different Networks. This mini-review introduces the current regulations and the Groundwater Monitoring Networks operated in Korea and provides some suggestions to improve the sustainability of the current groundwater monitoring system in Korea.

Groundwater residence times in Shenandoah National Park, Blue Ridge Mountains, Virginia, USA: A multi-tracer approach

Science.gov (United States)

Plummer, Niel; Busenberg, E.; Böhlke, J.K.; Nelms, D.L.; Michel, R.L.; Schlosser, P.

2001-01-01

Chemical and isotopic properties of water discharging from springs and wells in Shenandoah National Park (SNP), near the crest of the Blue Ridge Mountains, VA, USA were monitored to obtain information on groundwater residence times. Investigated time scales included seasonal (wet season, April, 1996; dry season, August–September, 1997), monthly (March through September, 1999) and hourly (30-min interval recording of specific conductance and temperature, March, 1999 through February, 2000). Multiple environmental tracers, including tritium/helium-3 (3H/3He), chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), sulfur-35 (35S), and stable isotopes (δ18O and δ2H) of water, were used to estimate the residence times of shallow groundwater discharging from 34 springs and 15 wells. The most reliable ages of water from springs appear to be based on SF6 and 3H/3He, with most ages in the range of 0–3 years. This range is consistent with apparent ages estimated from concentrations of CFCs; however, CFC-based ages have large uncertainties owing to the post-1995 leveling-off of the CFC atmospheric growth curves. Somewhat higher apparent ages are indicated by 35S (>1.5 years) and seasonal variation of δ18O (mean residence time of 5 years) for spring discharge. The higher ages indicated by the 35S and δ18O data reflect travel times through the unsaturated zone and, in the case of 35S, possible sorption and exchange of S with soils or biomass. In springs sampled in April, 1996, apparent ages derived from the 3H/3He data (median age of 0.2 years) are lower than those obtained from SF6 (median age of 4.3 years), and in contrast to median ages from 3H/3He (0.3 years) and SF6 (0.7 years) obtained during the late summer dry season of 1997. Monthly samples from 1999 at four springs in SNP had SF6apparent ages of only 1.2 to 2.5±0.8 years, and were consistent with the 1997 SF6 data. Water from springs has low excess air (0–1 cm3 kg−1) and N2–Ar temperatures that vary

Ecology and living conditions of groundwater fauna

Energy Technology Data Exchange (ETDEWEB)

Thulin, Barbara [Geo Innova AB (Sweden); Hahn, Hans Juergen [Arbeitsgruppe Grundwasseroekologie, Univ. of Koblenz-Landau (Germany)

2008-09-15

This report presents the current state of ecological knowledge and applied research relating to groundwater. A conceptual picture is given of groundwater fauna occurrence in regard to Swedish environmental conditions. Interpretation features for groundwater fauna and applications are outlined. Groundwater is one of the largest and oldest limnic habitats populated by a rich and diverse fauna. Both very old species and species occurring naturally in brackish or salt water can be found in groundwater. Groundwater ecosystems are heterotrophic; the fauna depends on imports from the surface. Most species are meiofauna, 0.3-1 mm. The food chain of groundwater fauna is the same as for relatives in surface water and salt water. Smaller animals graze biofilms and detritus, larger animals act facutatively as predators. A difference is that stygobiotic fauna has become highly adapted to its living space and tolerates very long periods without food. Oxygen is a limiting factor, but groundwater fauna tolerates periods with low oxygen concentrations, even anoxic conditions. For longer periods of time a minimum oxygen requirement of 1 mg/l should be fulfilled. Geographic features such as Quaternary glaciation and very old Pliocene river systems are important for distribution patterns on a large spatial scale, but aquifer characteristics are important on a landscape scale. Area diversity is often comparable to surface water diversity. However, site diversity is low in groundwater. Site specific hydrological exchange on a geological facies level inside the aquifer, e.g. porous, fractured and karstic aquifers as well as the hyporheic zone, controls distribution patterns of groundwater fauna. For a better understanding of controlling factors indicator values are suggested. Different adequate sampling methods are available. They are representative for the aquifer, but a suitable number of monitoring wells is required. The existence of groundwater fauna in Sweden is considered as very

Ecology and living conditions of groundwater fauna

International Nuclear Information System (INIS)

Thulin, Barbara; Hahn, Hans Juergen

2008-09-01

This report presents the current state of ecological knowledge and applied research relating to groundwater. A conceptual picture is given of groundwater fauna occurrence in regard to Swedish environmental conditions. Interpretation features for groundwater fauna and applications are outlined. Groundwater is one of the largest and oldest limnic habitats populated by a rich and diverse fauna. Both very old species and species occurring naturally in brackish or salt water can be found in groundwater. Groundwater ecosystems are heterotrophic; the fauna depends on imports from the surface. Most species are meiofauna, 0.3-1 mm. The food chain of groundwater fauna is the same as for relatives in surface water and salt water. Smaller animals graze biofilms and detritus, larger animals act facutatively as predators. A difference is that stygobiotic fauna has become highly adapted to its living space and tolerates very long periods without food. Oxygen is a limiting factor, but groundwater fauna tolerates periods with low oxygen concentrations, even anoxic conditions. For longer periods of time a minimum oxygen requirement of 1 mg/l should be fulfilled. Geographic features such as Quaternary glaciation and very old Pliocene river systems are important for distribution patterns on a large spatial scale, but aquifer characteristics are important on a landscape scale. Area diversity is often comparable to surface water diversity. However, site diversity is low in groundwater. Site specific hydrological exchange on a geological facies level inside the aquifer, e.g. porous, fractured and karstic aquifers as well as the hyporheic zone, controls distribution patterns of groundwater fauna. For a better understanding of controlling factors indicator values are suggested. Different adequate sampling methods are available. They are representative for the aquifer, but a suitable number of monitoring wells is required. The existence of groundwater fauna in Sweden is considered as very

Chemical and isotopic properties of groundwater along the coastal plain of the aqaba gulf, (EG)

International Nuclear Information System (INIS)

Awad, M.A.A

1999-01-01

Isotopic and hydrochemical studies were undertaken along the coastal plain of aqaba gulf in taba, dahab and sharm El-Sheikh to ascertain the role of precipitation (via floods), local water and sea water intrusion as replenishment sources for available groundwater resources in these areas. From the isotopic point of view, it can be concluded that groundwater in nuweiba wells appears to have been recharged from continental and mediterranean participation, while in dahab wells and sharm El-Sheikh Nubian well, recent precipitation via monsoonal air masses which comes from indian ocean plays a considerable role in recharging of these wells. In Taba wells, seepage of partly evaporated flood water represents the main source of their recharge. The fractured nature of the studied area has an effect on the occurrence of groundwater. The variation in chemical water type is due to leaching of terrestrial salts and impact of marine faces (i.e. evaporites and sea spray). Sea water intrusion via over pumping and/ or during tide and ebb duration shows an affect-to some extent-on the chemical composition of some localized wells. Construction of meteorological stations in scattered sites all over sinai is necessary to collect rainwater and floods samples periodically, to study the modification of the isotopic composition of rainwater by processes which occur before groundwater recharge using environmental isotopes

Assessment of groundwater contamination risk using hazard quantification, a modified DRASTIC model and groundwater value, Beijing Plain, China.

Science.gov (United States)

Wang, Junjie; He, Jiangtao; Chen, Honghan

2012-08-15

Groundwater contamination risk assessment is an effective tool for groundwater management. Most existing risk assessment methods only consider the basic contamination process based upon evaluations of hazards and aquifer vulnerability. In view of groundwater exploitation potentiality, including the value of contamination-threatened groundwater could provide relatively objective and targeted results to aid in decision making. This study describes a groundwater contamination risk assessment method that integrates hazards, intrinsic vulnerability and groundwater value. The hazard harmfulness was evaluated by quantifying contaminant properties and infiltrating contaminant load, the intrinsic aquifer vulnerability was evaluated using a modified DRASTIC model and the groundwater value was evaluated based on groundwater quality and aquifer storage. Two groundwater contamination risk maps were produced by combining the above factors: a basic risk map and a value-weighted risk map. The basic risk map was produced by overlaying the hazard map and the intrinsic vulnerability map. The value-weighted risk map was produced by overlaying the basic risk map and the groundwater value map. Relevant validation was completed by contaminant distributions and site investigation. Using Beijing Plain, China, as an example, thematic maps of the three factors and the two risks were generated. The thematic maps suggested that landfills, gas stations and oil depots, and industrial areas were the most harmful potential contamination sources. The western and northern parts of the plain were the most vulnerable areas and had the highest groundwater value. Additionally, both the basic and value-weighted risk classes in the western and northern parts of the plain were the highest, indicating that these regions should deserve the priority of concern. Thematic maps should be updated regularly because of the dynamic characteristics of hazards. Subjectivity and validation means in assessing the

STRATEGIC ISSUES GROUNDWATER EXTRACTION MANAGEMENT IN RUSSIA

Directory of Open Access Journals (Sweden)

Ekaterina I. Golovina

2017-05-01

Full Text Available Water is a key component of our environment; it is a renewable, limited and vulnerable natural resource, which provides economic, social, and environmental well-being of the population. The most promising source of drinking water supply is groundwater usage. Drinking and industrial groundwater is one of the most important components of the groundwater mineral resource base in the Russian Federation. Modern system of groundwater extraction management and state regulation is currently imperfect and has definite disadvantages, among them - lack of control over natural resources by the state, an old system of tax rates for the use of groundwater, commercialization stage of licensing, the budget deficit, which is passed on other spheres of the national economy. This article provides general information about the state of groundwater production and supply in Russia, negative trends of groundwater usage, some actions for the improvement in the system of groundwater’s fund management are suggested. The most important amendments of the law “About mineral resources” are overviewed, effects of these changes are revealed and recommendations for future groundwater extraction regulation are given.

Assessment and uncertainty analysis of groundwater risk.

Science.gov (United States)

Li, Fawen; Zhu, Jingzhao; Deng, Xiyuan; Zhao, Yong; Li, Shaofei

2018-01-01

Groundwater with relatively stable quantity and quality is commonly used by human being. However, as the over-mining of groundwater, problems such as groundwater funnel, land subsidence and salt water intrusion have emerged. In order to avoid further deterioration of hydrogeological problems in over-mining regions, it is necessary to conduct the assessment of groundwater risk. In this paper, risks of shallow and deep groundwater in the water intake area of the South-to-North Water Transfer Project in Tianjin, China, were evaluated. Firstly, two sets of four-level evaluation index system were constructed based on the different characteristics of shallow and deep groundwater. Secondly, based on the normalized factor values and the synthetic weights, the risk values of shallow and deep groundwater were calculated. Lastly, the uncertainty of groundwater risk assessment was analyzed by indicator kriging method. The results meet the decision maker's demand for risk information, and overcome previous risk assessment results expressed in the form of deterministic point estimations, which ignore the uncertainty of risk assessment. Copyright © 2017 Elsevier Inc. All rights reserved.

Trend Analyses of Nitrate in Danish Groundwater

DEFF Research Database (Denmark)

Hansen, B.; Thorling, L.; Dalgaard, Tommy

2012-01-01

This presentation assesses the long-term development in the oxic groundwater nitrate concentration and nitrogen (N) loss due to intensive farming in Denmark. Firstly, up to 20-year time-series from the national groundwater monitoring network enable a statistically systematic analysis of distribut......This presentation assesses the long-term development in the oxic groundwater nitrate concentration and nitrogen (N) loss due to intensive farming in Denmark. Firstly, up to 20-year time-series from the national groundwater monitoring network enable a statistically systematic analysis...... of distribution, trends and trend reversals in the groundwater nitrate concentration. Secondly, knowledge about the N surplus in Danish agriculture since 1950 is used as an indicator of the potential loss of N. Thirdly, groundwater recharge CFC (Chlorofluorocarbon) age determination allows linking of the first...... two dataset. The development in the nitrate concentration of oxic groundwater clearly mirrors the development in the national agricultural N surplus, and a corresponding trend reversal is found in groundwater. Regulation and technical improvements in the intensive farming in Denmark have succeeded...

The study of using earth tide response of groundwater level and rainfall recharge to identify groundwater aquifer

Science.gov (United States)

Huang, W. J.; Hsu, C. H.; Chang, L. C.; Chiang, C. J.; Wang, Y. S.; Lu, W. C.

2017-12-01

Hydrogeological framework is the most important basis for groundwater analysis and simulation. Conventionally, the core drill is a most commonly adopted skill to acquire the core's data with the help of other research methods to artificially determine the result. Now, with the established groundwater station network, there are a lot of groundwater level information available. Groundwater level is an integrated presentation of the hydrogeological framework and the external pumping and recharge system. Therefore, how to identify the hydrogeological framework from a large number of groundwater level data is an important subject. In this study, the frequency analysis method and rainfall recharge mechanism were used to identify the aquifer where the groundwater level's response frequency and amplitude react to the earth tide. As the earth tide change originates from the gravity caused by the paths of sun and moon, it leads to soil stress and strain changes, which further affects the groundwater level. The scale of groundwater level's change varies with the influence of aquifer pressure systems such as confined or unconfined aquifers. This method has been applied to the identification of aquifers in the Cho-Shui River Alluvial Fan. The results of the identification are compared to the records of core drill and they both are quite consistent. It is shown that the identification methods developed in this study can considerably contribute to the identification of hydrogeological framework.

ESTIMASI ALIRAN AIR LINDI TPA BANTAR GEBANG BEKASI MENGGUNAKAN METODA SP

Directory of Open Access Journals (Sweden)

Syamsu Rosid

2012-02-01

Full Text Available Air lindi merupakan limbah sampah organik yang biasanya diproduksi dari sampah rumah tangga. Pencemaran air tanah (groundwater oleh air lindi menjadi ancaman yang serius bagi masyarakat. Penduduk Bantar Gebang, Bekasi merasa terancam kehidupannya dengan adanya tempat pembuangan akhir (TPA sampah yang dikirim dari DKI Jakarta. Beberapa penduduk di sekitar TPA mengeluhkan bahwa air sumurnya agak bau dan tidak lagi terasa segar. Untuk mengetahui seperti apa polusi air lindi yang terjadi, ke arah mana dan sudah sejauh mana sebarannya, dan memetakan daerah resiko tinggi terkena polusi maka telah dilakukan pengukuran geolistrik metoda self potential (SP di sebelah Tenggara dan Selatan daerah TPA Bantar Gebang, Bekasi. Dari data SP diketahui bahwa aliran air tanah bawah permukaan di daerah tersebut berarah Selatan ke Utara. Meskipun lokasi TPA berada di Utara daerah penelitian, limbah air lindi diduga telah mencemari air tanah bawah permukaan hingga radius ratusan meter dari lokasi TPA. Penyebaran air limbah ini  diperkirakan melalui proses osmosis, mekanisme kapilaritas dan proses elektrokinetik.   Kata kunci: air lindi, metoda SP, TPA Bantar Gebang.

Degradation of sucralose in groundwater and implications for age dating contaminated groundwater.

Science.gov (United States)

Robertson, W D; Van Stempvoort, D R; Spoelstra, J; Brown, S J; Schiff, S L

2016-01-01

The artificial sweetener sucralose has been in use in Canada and the US since about 2000 and in the EU since 2003, and is now ubiquitous in sanitary wastewater in many parts of the world. It persists during sewage treatment and in surface water environments and as such, has been suggested as a powerful tracer of wastewater. In this study, longer-term persistence of sucralose was examined in groundwater by undertaking a series of three sampling snapshots of a well constrained wastewater plume in Canada (Long Point septic system) over a 6-year period from 2008 to 2014. A shrinking sucralose plume in 2014, compared to earlier sampling, during this period when sucralose use was likely increasing, provides clear evidence of degradation. However, depletion of sucralose from a mean of 40 μg/L in the proximal plume zone, occurred at a relatively slow rate over a period of several months to several years. Furthermore, examination of septic tank effluent and impacted groundwater at six other sites in Canada, revealed that sucralose was present in all samples of septic tank effluent (6-98 μg/L, n = 32) and in all groundwater samples (0.7-77 μg/L, n = 64). Even though sucralose degradation is noted in the Long Point plume, its ubiquitous presence in the groundwater plumes at all seven sites implies a relatively slow rate of decay in many groundwater septic plume environments. Thus, sucralose has the potential to be used as an indicator of 'recent' wastewater contamination. The presence of sucralose identifies groundwater that was recharged after 2000 in Canada and the US and after 2003 in the EU and many Asian countries. Copyright © 2015 Elsevier Ltd. All rights reserved.

Groundwater age and chemistry, and future nutrient loads for selected Rotorua Lakes catchments

International Nuclear Information System (INIS)

Morgenstern, U.; Reevers, R.R.; Daugney, C.J.; Cameron, S.; Gordon, D.

2005-01-01

since catchment development) of less than 80%. Significant fractions of these groundwaters were therefore recharged before land-use intensification, and these water discharges do not yet reflect the full effect of current land-use practices on the groundwater quality. Further deterioration of water quality must therefore be expected. Age dating of the main groundwater-fed streams in the Lake Rotorua catchment revealed mostly mean residence times between 35 and 130 years. The streams with the oldest water are Waingaehe (127 years), Hamurana (110 years), Awahou (61 years), and Utuhina streams (48 years). Only Ngongotaha Stream has younger water of 16 years mean residence time. Total phosphorus increases with groundwater age, concentration in young groundwater is 20 years. Trends for nitrate (NO 3 , potassium (K) and sulphate (SO 4 ) indicate that these are increased in the young groundwaters as result of land-use intensification. The natural background level of groundwater NO 3 -N is determined from old groundwater (pre-land-use intensification) to 0.14 mg/L, and the current level is determined from young groundwater (post-land-use intensification) to 1.6 mg/L. Therefore, 9% of the current level can be attributed to the natural background, and 91% to land-use impacts. This is an increase in NO 3 by a factor 11. Potassium concentrations indicate a natural background level of 0.6 mg/L and a current level of 3.8 mg/L. About 16% of the current K level is therefore natural background, and 84% is land-use impact, an increase by a factor 6. SO 4 shows a trend of elevated values of 3 mg/L in young waters compared to older water of 1.5 mg/L. Nitrogen loading was calculated from a mass budget for the major streams to Lake Rotorua. Only NO 3 -N, the main N component, was considered. Most of the nutrient flux via surface streams (ca. 90%) is contributed by the western catchment - Hamurana, Awahou, Puarenga, Waiteti, Ngongotaha and Utuhina streams. The total load of NO 3 -N is

Groundwater oxygen isotope anomaly before the M6.6 Tottori earthquake in Southwest Japan.

Science.gov (United States)

Onda, Satoki; Sano, Yuji; Takahata, Naoto; Kagoshima, Takanori; Miyajima, Toshihiro; Shibata, Tomo; Pinti, Daniele L; Lan, Tefang; Kim, Nak Kyu; Kusakabe, Minoru; Nishio, Yoshiro

2018-03-19

Geochemical monitoring of groundwater in seismically-active regions has been carried out since 1970s. Precursors were well documented, but often criticized for anecdotal or fragmentary signals, and for lacking a clear physico-chemical explanation for these anomalies. Here we report - as potential seismic precursor - oxygen isotopic ratio anomalies of +0.24‰ relative to the local background measured in groundwater, a few months before the Tottori earthquake (M 6.6) in Southwest Japan. Samples were deep groundwater located 5 km west of the epicenter, packed in bottles and distributed as drinking water between September 2015 and July 2017, a time frame which covers the pre- and post-event. Small but substantial increase of 0.07‰ was observed soon after the earthquake. Laboratory crushing experiments of aquifer rock aimed to simulating rock deformation under strain and tensile stresses were carried out. Measured helium degassing from the rock and 18 O-shift suggest that the co-seismic oxygen anomalies are directly related to volumetric strain changes. The findings provide a plausible physico-chemical basis to explain geochemical anomalies in water and may be useful in future earthquake prediction research.

Adsorptive Iron Removal from Groundwater

OpenAIRE

Sharma, S.K.

2001-01-01

Iron is commonly present in groundwater worldwide. The presence of iron in the water supply is not harmful to human health, however it is undesirable. Bad taste, discoloration, staining, deposition in the distribution system leading to aftergrowth, and incidences of high turbidity are some of the aesthetic and operational problems associated with iron in water supplies. Iron removal from groundwater is, therefore, a major concern for water supply companies using groundwater sources....

Spatial variability analysis of combining the water quality and groundwater flow model to plan groundwater and surface water management in the Pingtung plain

Science.gov (United States)

Chen, Ching-Fang; Chen, Jui-Sheng; Jang, Cheng-Shin

2014-05-01

As a result of rapid economic growth in the Pingtung Plain, the use of groundwater resources has changed dramatically. The groundwater is quite rich in the Pingtung plain and the most important water sources. During the several decades, a substantial amount of groundwater has been pumped for the drinking, irrigation and aquaculture water supplies. However, because the sustainable use concept of groundwater resources is lack, excessive pumping of groundwater causes the occurrence of serious land subsidence and sea water intrusion. Thus, the management and conservation of groundwater resources in the Pingtung plain are considerably critical. This study aims to assess the conjunct use effect of groundwater and surface water in the Pingtung plain on recharge by reducing the amount of groundwater extraction. The groundwater quality variability and groundwater flow models are combined to spatially analyze potential zones of groundwater used for multi-purpose in the Pingtung Plain. First, multivariate indicator kriging (MVIK) is used to analyze spatial variability of groundwater quality based on drinking, aquaculture and irrigation water quality standards, and probabilistically delineate suitable zones in the study area. Then, the groundwater flow model, Processing MODFLOW (PMWIN), is adopted to simulate groundwater flow. The groundwater flow model must be conducted by the calibration and verification processes, and the regional groundwater recovery is discussed when specified water rights are replaced by surface water in the Pingtung plain. Finally, the most suitable zones of reducing groundwater use are determined for multi-purpose according to combining groundwater quality and quantity. The study results can establish a sound and low-impact management plan of groundwater resources utilization for the multi-purpose groundwater use, and prevent decreasing ground water tables, and the occurrence of land subsidence and sea water intrusion in the Pingtung plain.

Evaluation of an integrated treatment system for MGP site groundwaters

International Nuclear Information System (INIS)

Scheible, O.K.; Grey, G.M.; Maiello, J.A.

1995-01-01

Initially studied at bench scale, process sequences comprising dissolved air flotation (DAF), aerobic biological oxidation, air stripping, filtration, and carbon adsorption were demonstrated at pilot scale at a manufactured gas plant (MGP) site in New Jersey. Benzene, toluene, ethylbenzene, and xylenes (BTEX), and polycyclic aromatic hydrocarbons (PAHs) were the primary organics in the groundwater, ranging from levels of 2 to 8 mg/L and 0.3 to 27 mg/L, respectively; chemical oxygen demand (COD) levels were from 60 to 4,500 mg/L. Significant levels of dense, emulsified, and nonaqueous tars and oils were present in the more highly contaminated waters and were effectively removed by DAF. Carbon-based fluidized-bed biological treatment of the DAF subnatant at COD loadings between 2 and 4 g/L-d yielded effluent-soluble COD levels between 40 and 60 mg/L, with both residual BTEX and PAH concentrations ranging from nondetect levels to 0.1 mg/L. Subsequent polishing by filtration and carbon adsorption resulted in additional COD removal and nondetect levels of volatiles and semivolatiles. Air stripping was effective in lieu of the biological process for both volatile organic compound (VOC) and PAH removal

Model-based assessment of the potential of seasonal aquifer thermal energy storage and recovery as a groundwater ecosystem service for the Brussels-Capital Region

Science.gov (United States)

Anibas, Christian; Huysmans, Marijke

2015-04-01

Urban areas are characterized by their concentrated demand of energy, applying a high pressure on urban ecosystems including atmosphere, soils and groundwater. In the light of global warming, urbanization and an evolving energy system, it is important to know how urbanized areas can contribute to their own energy demands. One option is to use the possibilities aquifers offer as an ecosystem service (BONTE et al., 2011). If used effectively an improvement in air and groundwater quality is achieved. Additionally, the more efficient distribution of the used energy may also lead to a decrease in primary energy consumption (ZUURBIER, 2013). Therefore, investigations of the potential of seasonal aquifer thermal energy storage and recovery (ATES) for the Brussels-Capital Region, Belgium is being conducted. The potential of ATES systems are of special interest for energy demands in high density urban areas because of such infrastructure as office buildings, schools, hospitals and shopping malls. In an open water circuit ATES systems consist of two or more groundwater wells, where in seasonal cycles one subtracts and the other recharges water to the aquifer. Heat pumps use the heat capacity of water for heating or cooling a building. An important limitation of the methodology is the quality of the groundwater used (i.e. precipitation of Fe- or Mn-oxides can decrease the yield). However, ATES systems on the other hand can also improve groundwater quality and groundwater ecosystems. The current knowledge of the potential for ATES systems in the Brussels-Capital Region is based on geological assessments from VITO (2007). The Brussels-Capital Region is divided into a western and eastern section with respect to geology. While the western part has less favorable conditions for ATES, the eastern is composed of the Brussels Sand formation, which is a 20-40 m thick aquifer layer that has the highest potential for ATES systems in the region. By applying groundwater flow and heat

Baseline groundwater model update for p-area groundwater operable unit, NBN

Energy Technology Data Exchange (ETDEWEB)

Ross, J. [Savannah River Site (SRS), Aiken, SC (United States); Amidon, M. [Savannah River Site (SRS), Aiken, SC (United States)

2015-09-01

This report documents the development of a numerical groundwater flow and transport model of the hydrogeologic system of the P-Area Reactor Groundwater Operable Unit at the Savannah River Site (SRS) (Figure 1-1). The P-Area model provides a tool to aid in understanding the hydrologic and geochemical processes that control the development and migration of the current tritium, tetrachloroethene (PCE), and trichloroethene (TCE) plumes in this region.

Isotopes and Sustainability of the Shallow Groundwater System in Spring and Snake Valleys, Eastern White Pine County, Nevada

Science.gov (United States)

Acheampong, S. Y.

2007-12-01

A critical component to managing water resources is understanding the source of ground water that is extracted from a well. Detail information on the source of recharge and the age of groundwater is thus vital for the proper assessment, development, management, and monitoring of the groundwater resources in an area. Great differences in the isotopic composition of groundwater in a basin and the basin precipitation imply that the groundwater in the basin originates from a source outside the basin or is recharged under different climatic conditions. The stable isotopes of oxygen and hydrogen in precipitation were compared with the isotopic composition of water from wells, springs, and creeks to evaluate the source of the shallow groundwater recharge in Spring and Snake Valleys, Nevada, as part of an evaluation of the water resources in the area. Delta deuterium and delta oxygen-18 composition of springs, wells, creeks, and precipitation in Spring and Snake Valleys show that groundwater recharge occurs primarily from winter precipitation in the surrounding mountains. The carbon-14 content of the groundwater ranged from 30 to 95 percent modern carbon (pmc). Twenty two of the thirty samples had carbon-14 values of greater than 50 pmc. The relatively high carbon-14 values suggest that groundwater in the area is recharged by modern precipitation and the waters have rapid travel times. Total dissolved solids content of the samples outside the playa areas are generally low, and suggests that the water has a relatively short travel time between the recharge areas and sample sites. The presence of tritium in some of the springs and wells also indicate that groundwater mixes with post 1952 precipitation. Hydrogen bomb tests which began in 1952 in the northern hemisphere added large amounts of tritium to the atmosphere and reached a peak in 1963. The stable isotopic composition, the high carbon-14 activities, and the presence of tritium, show that the shallow groundwater in

Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada, for Fiscal Year 2014

Energy Technology Data Exchange (ETDEWEB)

Silvas, Alissa J. [Nevada Field Office, Las Vegas, NV (United States)

2015-01-01

This report serves as the combined annual report for post-closure activities for several Corrective Action Units (CAUs). The locations of the sites are shown in Figure 1. This report covers fiscal year 2014 (October 2013–September 2014). The post-closure requirements for these sites are described in Resource Conservation and Recovery Act Permit Number NEV HW0101 and summarized in each CAU-specific section in Section 1.0 of this report. The results of the inspections, a summary of maintenance activities, and an evaluation of monitoring data are presented in this report. Site inspections are conducted semiannually at CAUs 90 and 91 and quarterly at CAUs 92, 110, 111, and 112. Additional inspections are conducted at CAU 92 if precipitation occurs in excess of 0.50 inches (in.) in a 24-hour period and at CAU 111 if precipitation occurs in excess of 1.0 in. in a 24-hour period. Inspections include an evaluation of the condition of the units, including covers, fences, signs, gates, and locks. In addition to visual inspections, soil moisture monitoring, vegetation evaluations, and subsidence surveys are conducted at CAU 110. At CAU 111, soil moisture monitoring, vegetation evaluations, subsidence surveys, direct radiation monitoring, air monitoring, radon flux monitoring, and groundwater monitoring are conducted. The results of the vegetation surveys and an analysis of the soil moisture monitoring data at CAU 110 are presented in this report. Results of additional monitoring at CAU 111 are documented annually in the Nevada National Security Site Waste Management Monitoring Report Area 3 and Area 5 Radioactive Waste Management Sites and in the Nevada National Security Site Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site, which will be prepared in approximately June 2015. All required inspections, maintenance, and monitoring were conducted in accordance with the post-closure requirements of the permit. It is recommended to continue

Groundwater and Terrestrial Water Storage

Science.gov (United States)

Rodell, Matthew; Chambers, Don P.; Famiglietti, James S.

2011-01-01

Most people think of groundwater as a resource, but it is also a useful indicator of climate variability and human impacts on the environment. Groundwater storage varies slowly relative to other non-frozen components of the water cycle, encapsulating long period variations and trends in surface meteorology. On seasonal to interannual timescales, groundwater is as dynamic as soil moisture, and it has been shown that groundwater storage changes have contributed to sea level variations. Groundwater monitoring well measurements are too sporadic and poorly assembled outside of the United States and a few other nations to permit direct global assessment of groundwater variability. However, observational estimates of terrestrial water storage (TWS) variations from the GRACE satellites largely represent groundwater storage variations on an interannual basis, save for high latitude/altitude (dominated by snow and ice) and wet tropical (surface water) regions. A figure maps changes in mean annual TWS from 2009 to 2010, based on GRACE, reflecting hydroclimatic conditions in 2010. Severe droughts impacted Russia and the Amazon, and drier than normal weather also affected the Indochinese peninsula, parts of central and southern Africa, and western Australia. Groundwater depletion continued in northern India, while heavy rains in California helped to replenish aquifers that have been depleted by drought and withdrawals for irrigation, though they are still below normal levels. Droughts in northern Argentina and western China similarly abated. Wet weather raised aquifer levels broadly across western Europe. Rains in eastern Australia caused flooding to the north and helped to mitigate a decade long drought in the south. Significant reductions in TWS seen in the coast of Alaska and the Patagonian Andes represent ongoing glacier melt, not groundwater depletion. Figures plot time series of zonal mean and global GRACE derived non-seasonal TWS anomalies (deviation from the mean of

Groundwater flow and transport modelling during the temperate period for the SR-Can assessment. Laxemar subarea - version 1.2

Energy Technology Data Exchange (ETDEWEB)

Hartley, Lee; Hoch, Andrew; Jackson, Peter; Joyce, Steve; McCarthy, Rachel; Swift, Ben [Serco Assurance, Harwell (United Kingdom); Gylling, Bjoern; Marsic, Niko [Kemakta Konsult AB, Stockholm (Sweden)

2006-12-15

The focus of the study described in this report has been to perform numerical simulations of the geosphere from post-closure and throughout the temperate period up until the beginning of the next permafrost period at around 20,000 AD for the Laxemar area. Together with providing quantitative results for the immediate temperate period following post-closure, these results are also intended to give a qualitative indication of the evolution of the groundwater system during future temperate periods within an ongoing cycle of glacial/inter-glacial events.

Attempt of groundwater dating using the drilled rock core. 1. Development of the rock sampling method for measurement of noble gases dissolved in interstitial water in rock

International Nuclear Information System (INIS)

Mahara, Yasunori

2002-01-01

Groundwater dating in low permeable rock is very difficult and impracticable, because we take a very long time to collect groundwater sample in a borehole and have to invest much fund in production of the in-situ groundwater sampler and in operation of it. If we can directly measure noble gases dissolved in interstitial groundwater in rock core, we have a big merit to estimate groundwater resident time easy. In this study, we designed and produced a high vacuum container to let dissolved noble gases diffuse until reaching in equilibrium, and we made a handling manual of the rock core into the container and a procedure to vacuum out air from the sealed container. We compared data sets of noble gas concentration obtained from rock cores and groundwater sample collected from boreholes in-situ. The measured rocks are pumice-tuff rock, mud rock and hornfels, which have their permeabilities of 10 -6 cm/s, 10 -9 cm/s and 10 -11 cm/s, respectively. Consequently, we evaluated the rock core method is better than the in-situ groundwater sampling method for low permeable rock. (author)

Transitivity System on Air Asia News in the Jakarta Post

OpenAIRE

Rini, Rizka Novita

2015-01-01

Transitivitas adalah alat yang digunakan untuk menemukan makna ideational dalam suatu wacana. Saat awal penulisan makalah ini, berita mengenai kecelakaan pesawat AirAsia QZ8501 yang terjadi pada tanggal 28 Desember 2014, menjadi topik hangat yang sering dibicarakan. Hal ini disebabkan karena kecelakaan tersebut adalah kecelakaan pertama yang terjadi dalam penerbangan AirAsia sejak 2001. Hal itulah yang menjadi penyebab kenapa berita ini dipilih untuk dianalisis. Penelitian ini dimaksudkan unt...

Groundwater Protection Program Calendar Year 1998 Evaluation of Groundwater Quality Data for the Chestnut Ridge Hydrogeologic Regime at the U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

International Nuclear Information System (INIS)

1999-01-01

The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge south of the U.S. Department of Energy (DOE) Y-12 Plant (Figure 1). Groundwater monitoring is performed at several hazardous and nonhazardous waste management facilities located in the regime per the requirements of applicable operating/post closure permits and governing state/federal regulations and guidelines, including DOE Order 5400.1A - General Environmental Protection Program. Applicable provisions of DOE Order 5400.1A require evaluation of available monitoring data with regard to: (1) groundwater quality in areas that are, or could be, affected by Y-12 Plant operations, (2) the quality of surface water and groundwater where contaminants are most likely to migrate beyond the DOE Oak Ridge Reservation (ORR) property line, and (3) long-term trends in groundwater quality at the Y-12 Plant. This report presents the results of these DOE Order 5400.1A evaluations based on available data for the network of monitoring wells and springs in the Chestnut Ridge Regime sampled during calendar year (CY) 1998. The following sections of this report contain relevant background information (Section 2.0); describe the results of the respective data evaluations required under DOE Order 5400.1A (Section 3.0); summarize significant findings of each evaluation (Section 4.0); and list the technical reports and regulatory documents cited for more detailed information (Section 5.0). All of the illustrations (maps and trend graphs) and data summary tables referenced in each section are presented in Appendix A and Appendix B, respectively

Groundwater Protection Program Calendar Year 1998 Evaluation of Groundwater Quality Data for the Chestnut Ridge Hydrogeologic Regime at the U.S. Department of Energy Y-12 Plant, Oak Ridge, Tennessee

Energy Technology Data Exchange (ETDEWEB)

none

1999-09-01

The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge south of the U.S. Department of Energy (DOE) Y-12 Plant (Figure 1). Groundwater monitoring is performed at several hazardous and nonhazardous waste management facilities located in the regime per the requirements of applicable operating/post closure permits and governing state/federal regulations and guidelines, including DOE Order 5400.1A - General Environmental Protection Program. Applicable provisions of DOE Order 5400.1A require evaluation of available monitoring data with regard to: (1) groundwater quality in areas that are, or could be, affected by Y-12 Plant operations, (2) the quality of surface water and groundwater where contaminants are most likely to migrate beyond the DOE Oak Ridge Reservation (ORR) property line, and (3) long-term trends in groundwater quality at the Y-12 Plant. This report presents the results of these DOE Order 5400.1A evaluations based on available data for the network of monitoring wells and springs in the Chestnut Ridge Regime sampled during calendar year (CY) 1998. The following sections of this report contain relevant background information (Section 2.0); describe the results of the respective data evaluations required under DOE Order 5400.1A (Section 3.0); summarize significant findings of each evaluation (Section 4.0); and list the technical reports and regulatory documents cited for more detailed information (Section 5.0). All of the illustrations (maps and trend graphs) and data summary tables referenced in each section are presented in Appendix A and Appendix B, respectively.

Innovative technologies for groundwater cleanup

International Nuclear Information System (INIS)

Yow, J.L. Jr.

1992-09-01

These notes provide a broad overview of current developments in innovative technologies for groundwater cleanup. In this context, groundwater cleanup technologies include site remediation methods that deal with contaminants in ground water or that may move from the vadose zone into ground water. This discussion attempts to emphasize approaches that may be able to achieve significant improvements in groundwater cleanup cost or effectiveness. However, since data for quantitative performance and cost comparisons of new cleanup methods are scarce, preliminary comparisons must be based on the scientific approach used by each method and on the site-specific technical challenges presented by each groundwater contamination situation. A large number of technical alternatives that are now in research, development, and testing can be categorized by the scientific phenomena that they employ and by the site contamination situations that they treat. After reviewing a representative selection of these technologies, one of the new technologies, the Microbial Filter method, is discussed in more detail to highlight a promising in situ groundwater cleanup technology that is now being readied for field testing

Ecophysiological evaluation of tree species for biomonitoring of air quality and identification of air pollution-tolerant species.

Science.gov (United States)

Sen, Abhishek; Khan, Indrani; Kundu, Debajyoti; Das, Kousik; Datta, Jayanta Kumar

2017-06-01

Identification of tree species that can biologically monitor air pollution and can endure air pollution is very much important for a sustainable green belt development around any polluted place. To ascertain the species, ten tree species were selected on the basis of some previous study from the campus of the University of Burdwan and were studied in the pre-monsoon and post-monsoon seasons. The study has been designed to investigate biochemical and physiological activities of selected tree species as the campus is presently exposed to primary air pollutants and their impacts on plant community were observed through the changes in several physical and biochemical constituents of plant leaves. As the plant species continuously exchange different gaseous pollutants in and out of the foliar system and are very sensitive to gaseous pollutants, they serve as bioindicators. Due to air pollution, foliar surface undergoes different structural and functional changes. In the selected plant species, it was observed that the concentration of primary air pollutants, proline content, pH, relative water holding capacity, photosynthetic rate, and respiration rate were higher in the pre-monsoon than the post-monsoon season, whereas the total chlorophyll, ascorbic acid, sugar, and conductivity were higher in the post-monsoon season. From the entire study, it was observed that the concentration of sulfur oxide (SO x ), nitrogen oxide (NO x ), and suspended particulate matter (SPM) all are reduced in the post-monsoon season than the pre-monsoon season. In the pre-monsoon season, SO x , NO x , and SPM do not have any significant correlation with biochemical as well as physiological parameters. SPM shows a negative relationship with chlorophyll 'a' (r = -0.288), chlorophyll 'b' (r = -0.267), and total chlorophyll (r = -0.238). Similarly, chlorophyll a, chlorophyll b, and the total chlorophyll show negative relations with SO x and NO x (p tree species according to their air

Basin F Subregional Groundwater Model

National Research Council Canada - National Science Library

Mazion, Edward

2001-01-01

The groundwater flow system at Rocky Mountain Arsenal (RMA) is complex. To evaluate proposed remedial alternatives, interaction of the local groundwater flow system with the present contamination control systems must be understood...

Groundwater Profession in Transition: Discovery toAdaptation

Energy Technology Data Exchange (ETDEWEB)

Narasimhan, T.N.

2005-04-04

Over the past century and half, groundwater has played an important role in the economic prosperity of the United States. The groundwater profession which has contributed to this prosperity has grown through the contributions of the U.S. and State Geological Surveys,academia, and industry. A century ago, the energies of the profession were channeled towards discovering new sources of groundwater in a largely unexplored land, and exploiting the resources for maximum economic benefit. Experience has since revealed that groundwater systems are finite, and are intimately linked to surface water bodies and the biosphere. A consequence is that aggressive exploitation of groundwater can lead to unacceptable environmental degradation and social cost. At present, the groundwater profession is in a state of transition from one of discovery and exploitation, to one of balancing resource development with avoiding unacceptable damage to the environment. This paper outlines the history of the groundwater profession in the United States since the late nineteenth century, and speculates on what may lie ahead in the near future, as the profession makes the transition from discovering new sources of groundwater to one of better understanding and adapting to nature's constraints.

Y-12 Groundwater Protection Program Groundwater Monitoring Data Compendium, Revision 1

Energy Technology Data Exchange (ETDEWEB)

None

2006-12-01

This document is a compendium of water quality and hydrologic characterization data obtained through December 2005 from the network of groundwater monitoring wells and surface water sampling stations (including springs and building sumps) at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee that have been sampled since January 2003. The primary objectives of this document, hereafter referenced as the Y-12 Groundwater Protection Program (GWPP) Compendium, are to: (1) Serve as a single-source reference for monitoring data that meet the requirements of the Y-12 GWPP, as defined in the Y-12 GWPP Management Plan (BWXT Y-12 L.L.C. [BWXT] 2004); (2) Maintain a detailed analysis and evaluation of the monitoring data for each applicable well, spring, and surface water sampling station, with a focus on results for the primary inorganic, organic, and radiological contaminants in groundwater and surface water at Y-12; and (3) Ensure retention of ''institutional knowledge'' obtained over the long-term (>20-year) history of groundwater and surface water monitoring at Y-12 and the related sources of groundwater and surface water contamination. To achieve these goals, the Y-12 GWPP Compendium brings together salient hydrologic, geologic, geochemical, water-quality, and environmental compliance information that is otherwise disseminated throughout numerous technical documents and reports prepared in support of completed and ongoing environmental contamination assessment, remediation, and monitoring activities performed at Y-12. The following subsections provide background information regarding the overall scope and format of the Y-12 GWPP Compendium and the planned approach for distribution and revision (i.e., administration) of this ''living'' document.

High performance ultraviolet photodetectors with atomic-layer-deposited ZnO films via low-temperature post-annealing in air

Directory of Open Access Journals (Sweden)

Jian Gao

2018-01-01

Full Text Available In this work, we have investigated the effect of low temperature post-annealing in air on atomic-layer-deposited ZnO metal-semiconductor-metal (MSM ultraviolet photodetectors (UV PDs. The results indicate that the post-annealing could reduce the dark-current of the MSM device by ten orders of magnitude; however, it also decreased the photo-current of the UV PD by one order of magnitude. The former could be related to the reduction of oxygen vacancies and the crystallization enhancement of the ZnO film; the latter should be attributed to the reduction of defects in the ZnO film, thus resulting in a smaller decrease in thermionic-field emission tunneling barrier because of reduced holes trapped near the interface. For the post-annealing at 250 oC for 30 min, the dark-current was equal to 5.16×10-11 A, and the ultraviolet-visible rejection ratio approached 1.4×106, and the responsivity was as high as 1.78×103 A/W at 5V. Further, prolonging annealing time at a lower temperature (200 oC also could greatly improve the performance of the UV PD, i.e., 90 min annealing produced a quite large responsivity of 1.30×104 A/W at 5 V while maintaining a very low dark-current (1.42×10-10 A and a large ultraviolet-visible rejection ratio (4.06×105.

Evolution of patterns of regional groundwater flow in southeastern New Mexico: Response to post-Pleistocene changes in climate

International Nuclear Information System (INIS)

Corbet, T.F.

1994-01-01

The Waste Isolation Pilot Plant (WIPP) is a potential repository for transuranic wastes generated by defense programs of the US Department of Energy. The repository site is located 42 km east of the city of Carlsbad, New Mexico in a thick, Permian-age deposit of bedded salt. One consideration in evaluating the performance of the repository is that a future society might inadvertently penetrate the repository with one or more drill holes. Given certain circumstances, these holes could provide a pathway for contaminated brine to move upward into relatively permeable strata located above the bedded salt. There is concern that flowing groundwater could then transport radionuclides laterally to the sub-surface portion of the accessible environment, currently defined by the disposal regulations as the region more than 5 kilometers from the radioactive waste. The simulations presented here are part of a numerical modeling study of the possible impact that a change in climate over the next 10,000 years could have on the pattern of groundwater flow and, consequently, on the migration of radionuclides in strata overlying the repository

Geohydrology and ground-water quality beneath the 300 Area, Hanford Site, Washington

International Nuclear Information System (INIS)

Lindberg, J.W.; Bond, F.W.

1979-06-01

Ground water enters the 300 Area from the northwest, west, and southwest. However, throughout most of the 300 Area, the flow is to the east and southeast. Ground water flows to the northeast only in the southern portion of the 300 Area. Variations in level of the Columbia River affected the ground-water system by altering the level and shape of the 300 Area watertable. Large quantities of process waste water, when warmed during summer months by solar radiation or cooled during winter months by ambient air temperature, influenced the temperature of the ground water. Leaking pipes and the intentional discharge of waste water (or withdrawal of ground water) affected the ground-water system in the 300 Area. Water quality tests of Hanford ground water in and adjacent to the 300 Area showed that in the area of the Process Water Trenches and Sanitary Leaching Trenches, calcium, magnesium, sodium, bicarbonate, and sulfate ions are more dilute, and nitrate and chloride ions are more concentrated than in surrounding areas. Fluoride, uranium, and beta emitters are more concentrated in ground water along the bank of the Columbia River in the central and southern portions of the 300 Area and near the 340 Building. Test wells and routine ground-water sampling are adequate to point out contamination. The variable Thickness Transient (VTT) Model of ground-water flow in the unconfined aquifer underlying the 300 Area has been set up, calibrated, and verified. The Multicomponent Mass Transfer (MMT) Model of distribution of contaminants in the saturated regime under the 300 Area has been set up, calibrated, and tested

Groundwater quality in the Klamath Mountains, California

Science.gov (United States)

Bennett, George L.; Fram, Miranda S.

2014-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The Klamath Mountains constitute one of the study units being evaluated.

Understanding socio-groundwater systems: framework, toolbox, and stakeholders’ efforts for analysis and monitoring groundwater resources

OpenAIRE

López Maldonado, Yolanda Cristina

2018-01-01

Groundwater, the predominant accessible reservoir of freshwater storage on Earth, plays an important role as a human-natural life sustaining resource. In recent decades there has been an increasing concern that human activities are placing too much pressure on the resource, affecting the health of the ecosystem. However, because groundwater it is out of sight, its monitoring on both global and local scales is challenging. In the field of groundwater monitoring, modelling tools have been devel...

The treatment of water-conducting features in groundwater flow and transport modelling of the Borrowdale Volcanic Group in Nirex 97

International Nuclear Information System (INIS)

Jackson, C.P.; Norris, S.; Todman, S.J.; Watson, S.P.

1999-01-01

In the Nirex 97 assessment of the post-closure performance of a repository at Sellafield, the potential repository host rock was the Borrowdale Volcanic Group (BVG). The treatment of water-conducting features in groundwater flow and transport modelling of the BVG is discussed. Groundwater flow in the BVG is predominantly through a subset of the total set of discontinuities - the Flowing Features (FFs). FFs can be identified in core samples by the presence of recent calcite. In boreholes, the FFs are clustered, and the clustering appears to be significant hydro-geologically. However, there is uncertainty about the connectivity of the clusters. A range of models is possible, from the case of isolated clusters to the case where the clusters form a well-connected network. The radiological risk from the repository was determined from radionuclide transport calculations based on the groundwater flow fields obtained from the regional-scale flow calculations. For rocks, such as the BVG, in which groundwater flows predominantly through discontinuities, diffusion into immobile water int the rock matrix between the discontinuities was modelled. Data from the site characterization and research programmes could be used to develop and parameterize groundwater flow and transport models for use in repository performance assessments. (author)

Geochemistry and the Understanding of Groundwater Systems

Science.gov (United States)

Glynn, P. D.; Plummer, L. N.; Weissmann, G. S.; Stute, M.

2009-12-01

Geochemical techniques and concepts have made major contributions to the understanding of groundwater systems. Advances continue to be made through (1) development of measurement and characterization techniques, (2) improvements in computer technology, networks and numerical modeling, (3) investigation of coupled geologic, hydrologic, geochemical and biologic processes, and (4) scaling of individual observations, processes or subsystem models into larger coherent model frameworks. Many applications benefit from progress in these areas, such as: (1) understanding paleoenvironments, in particular paleoclimate, through the use of groundwater archives, (2) assessing the sustainability (recharge and depletion) of groundwater resources, and (3) their vulnerability to contamination, (4) evaluating the capacity and consequences of subsurface waste isolation (e.g. geologic carbon sequestration, nuclear and chemical waste disposal), (5) assessing the potential for mitigation/transformation of anthropogenic contaminants in groundwater systems, and (6) understanding the effect of groundwater lag times in ecosystem-scale responses to natural events, land-use changes, human impacts, and remediation efforts. Obtaining “representative” groundwater samples is difficult and progress in obtaining “representative” samples, or interpreting them, requires new techniques in characterizing groundwater system heterogeneity. Better characterization and simulation of groundwater system heterogeneity (both physical and geochemical) is critical to interpreting the meaning of groundwater “ages”; to understanding and predicting groundwater flow, solute transport, and geochemical evolution; and to quantifying groundwater recharge and discharge processes. Research advances will also come from greater use and progress (1) in the application of environmental tracers to ground water dating and in the analysis of new geochemical tracers (e.g. compound specific isotopic analyses, noble gas

A high resolution global scale groundwater model

Science.gov (United States)

de Graaf, Inge; Sutanudjaja, Edwin; van Beek, Rens; Bierkens, Marc

2014-05-01

As the world's largest accessible source of freshwater, groundwater plays a vital role in satisfying the basic needs of human society. It serves as a primary source of drinking water and supplies water for agricultural and industrial activities. During times of drought, groundwater storage provides a large natural buffer against water shortage and sustains flows to rivers and wetlands, supporting ecosystem habitats and biodiversity. Yet, the current generation of global scale hydrological models (GHMs) do not include a groundwater flow component, although it is a crucial part of the hydrological cycle. Thus, a realistic physical representation of the groundwater system that allows for the simulation of groundwater head dynamics and lateral flows is essential for GHMs that increasingly run at finer resolution. In this study we present a global groundwater model with a resolution of 5 arc-minutes (approximately 10 km at the equator) using MODFLOW (McDonald and Harbaugh, 1988). With this global groundwater model we eventually intend to simulate the changes in the groundwater system over time that result from variations in recharge and abstraction. Aquifer schematization and properties of this groundwater model were developed from available global lithological maps and datasets (Dürr et al., 2005; Gleeson et al., 2010; Hartmann and Moosdorf, 2013), combined with our estimate of aquifer thickness for sedimentary basins. We forced the groundwater model with the output from the global hydrological model PCR-GLOBWB (van Beek et al., 2011), specifically the net groundwater recharge and average surface water levels derived from routed channel discharge. For the parameterization, we relied entirely on available global datasets and did not calibrate the model so that it can equally be expanded to data poor environments. Based on our sensitivity analysis, in which we run the model with various hydrogeological parameter settings, we observed that most variance in groundwater

Air pollution in Boston bars before and after a smoking ban

Directory of Open Access Journals (Sweden)

Hyde James N

2006-10-01

Full Text Available Abstract Background We quantified the air quality benefits of a smoke-free workplace law in Boston Massachusetts, U.S.A., by measuring air pollution from secondhand smoke (SHS in 7 pubs before and after the law, comparing actual ventilation practices to engineering society (ASHRAE recommendations, and assessing SHS levels using health and comfort indices. Methods We performed real-time measurements of respirable particle (RSP air pollution and particulate polycyclic aromatic hydrocarbons (PPAH, in 7 pubs and outdoors in a model-based design yielding air exchange rates for RSP removal. We also assessed ventilation rates from carbon dioxide concentrations. We compared RSP air pollution to the federal Air Quality Index (AQI and the National Ambient Air Quality Standard (NAAQS to assess health risks, and assessed odor and irritation levels using published SHS-RSP thresholds. Results Pre-smoking-ban RSP levels in 6 pubs (one pub with a non-SHS air quality problem was excluded averaged 179 μg/m3, 23 times higher than post-ban levels, which averaged 7.7 μg/m3, exceeding the NAAQS for fine particle pollution (PM2.5 by nearly 4-fold. Pre-smoking ban levels of fine particle air pollution in all 7 of the pubs were in the Unhealthy to Hazardous range of the AQI. In the same 6 pubs, pre-ban indoor carcinogenic PPAH averaged 61.7 ng/m3, nearly 10 times higher than post-ban levels of 6.32 ng/m3. Post-ban particulate air pollution levels were in the Good AQI range, except for 1 venue with a defective gas-fired deep-fat fryer, while post-ban carcinogen levels in all 7 pubs were lower than outdoors. Conclusion During smoking, although pub ventilation rates per occupant were within ASHRAE design parameters for the control of carbon dioxide levels for the number of occupants present, they failed to control SHS carcinogens or RSP. Nonsmokers' SHS odor and irritation sensory thresholds were massively exceeded. Post-ban air pollution measurements showed 90% to 95

Air pollution in Boston bars before and after a smoking ban.

Science.gov (United States)

Repace, James L; Hyde, James N; Brugge, Doug

2006-10-27

We quantified the air quality benefits of a smoke-free workplace law in Boston Massachusetts, U.S.A., by measuring air pollution from secondhand smoke (SHS) in 7 pubs before and after the law, comparing actual ventilation practices to engineering society (ASHRAE) recommendations, and assessing SHS levels using health and comfort indices. We performed real-time measurements of respirable particle (RSP) air pollution and particulate polycyclic aromatic hydrocarbons (PPAH), in 7 pubs and outdoors in a model-based design yielding air exchange rates for RSP removal. We also assessed ventilation rates from carbon dioxide concentrations. We compared RSP air pollution to the federal Air Quality Index (AQI) and the National Ambient Air Quality Standard (NAAQS) to assess health risks, and assessed odor and irritation levels using published SHS-RSP thresholds. Pre-smoking-ban RSP levels in 6 pubs (one pub with a non-SHS air quality problem was excluded) averaged 179 microg/m3, 23 times higher than post-ban levels, which averaged 7.7 microg/m3, exceeding the NAAQS for fine particle pollution (PM2.5) by nearly 4-fold. Pre-smoking ban levels of fine particle air pollution in all 7 of the pubs were in the Unhealthy to Hazardous range of the AQI. In the same 6 pubs, pre-ban indoor carcinogenic PPAH averaged 61.7 ng/m3, nearly 10 times higher than post-ban levels of 6.32 ng/m3. Post-ban particulate air pollution levels were in the Good AQI range, except for 1 venue with a defective gas-fired deep-fat fryer, while post-ban carcinogen levels in all 7 pubs were lower than outdoors. During smoking, although pub ventilation rates per occupant were within ASHRAE design parameters for the control of carbon dioxide levels for the number of occupants present, they failed to control SHS carcinogens or RSP. Nonsmokers' SHS odor and irritation sensory thresholds were massively exceeded. Post-ban air pollution measurements showed 90% to 95% reductions in PPAH and RSP respectively, differing

Investigation and Evaluation of Groundwater Resources of Juxian

Science.gov (United States)

Xinyi, Li; Wanglin, Li; Xiaojiao, Zhang; Deling, Zhu; Huadan, Yan

2018-03-01

The investigation and evaluation of groundwater resources refers to the analysis of groundwater quantity, quality, spatial-temporal property and exploitation status. Based on the collected data and field investigation, the groundwater resources in plain and hilly area of Juxian were calculated by replenishment method, discharge method and comprehensive infiltration coefficient method, and the groundwater quality was analyzed and evaluated. The conclusions are as follows: (1) The amount of groundwater resources is 224.940 million m3/a, including 89.585 million m3/a of plain area and 142.523 million m3/a of hilly area respectively. (2) The allowable yield of groundwater is about 162.948 million m3/a, in which the amounts in the plain area and the hilly area are 74 .585million m3/a and 88.363 million m3/a, respectively. (3) The pH value of groundwater ranges from 6.5∼7.5 and the degree of mineralization of groundwater was lower than 1 g/L at most. In addition, the total hardness varies from 150 mg/L to 450 mg/L in plain area and 300 mg/L to 550 mg/L in hilly area, respectively. The investigation and evaluation of groundwater resources was of great significance in ensuring the sustainable development of groundwater resources, establishing the scheme of groundwater resources exploitation and utilization.

Integrating a Linear Signal Model with Groundwater and Rainfall time-series on the Characteristic Identification of Groundwater Systems

Science.gov (United States)

Chen, Yu-Wen; Wang, Yetmen; Chang, Liang-Cheng

2017-04-01

Groundwater resources play a vital role on regional supply. To avoid irreversible environmental impact such as land subsidence, the characteristic identification of groundwater system is crucial before sustainable management of groundwater resource. This study proposes a signal process approach to identify the character of groundwater systems based on long-time hydrologic observations include groundwater level and rainfall. The study process contains two steps. First, a linear signal model (LSM) is constructed and calibrated to simulate the variation of underground hydrology based on the time series of groundwater levels and rainfall. The mass balance equation of the proposed LSM contains three major terms contain net rate of horizontal exchange, rate of rainfall recharge and rate of pumpage and four parameters are required to calibrate. Because reliable records of pumpage is rare, the time-variant groundwater amplitudes of daily frequency (P ) calculated by STFT are assumed as linear indicators of puamage instead of pumpage records. Time series obtained from 39 observation wells and 50 rainfall stations in and around the study area, Pintung Plain, are paired for model construction. Second, the well-calibrated parameters of the linear signal model can be used to interpret the characteristic of groundwater system. For example, the rainfall recharge coefficient (γ) means the transform ratio between rainfall intention and groundwater level raise. The area around the observation well with higher γ means that the saturated zone here is easily affected by rainfall events and the material of unsaturated zone might be gravel or coarse sand with high infiltration ratio. Considering the spatial distribution of γ, the values of γ decrease from the upstream to the downstream of major rivers and also are correlated to the spatial distribution of grain size of surface soil. Via the time-series of groundwater levels and rainfall, the well-calibrated parameters of LSM have

An approach to delineate the contaminated groundwater in landfill based on Electrical Resistivity Imaging Technique

International Nuclear Information System (INIS)

Nor Dalila Desa; Lakam Mejus; Mohd Tadza Abdul Rahman; Kamarudin Samuding; Roslanzairi Mostapa; Mod Omar Hassan

2010-01-01

Full text: The occurrence of contaminated groundwater can often be recognized by a decrease in formation of resistivity values, since the latter is primarily dependent on the resistivity of the pore water. Landfills can be considered as one of major source of contamination that contributes to air, land and water pollution. Landfills are supposed to have a protective bottom layer (barrier layer) to prevent contaminants from getting into the groundwater that exist almost everywhere underground. However, if there is no layer or if it is cracked, water percolating through landfills produces leachate can make their way down into the groundwater system. In geophysical studies, the various properties of materials on earth are known as the anomaly of the Earth's sub surface. It is important to understand which physical properties are associated with, and effective for, a particular target and geophysical method. This paper reviews the needs of geophysical field for mapping subsurface geology and features occurance. Electrical Resistivity Imaging (ERI) technique has been chosen for it has become one of the promising methods in order to obtain preliminary information of subsurface variance materials based on their physical properties. (author)

Ground-water monitoring under RCRA

International Nuclear Information System (INIS)

Coalgate, J.

1993-11-01

In developing a regulatory strategy for the disposal of hazardous waste under the Resource Conservation and Recovery Act (RCRA), protection of ground-water resources was the primary goal of the Environmental Protection Agency (EPA). EPA's ground-water protection strategy seeks to minimize the potential for hazardous wastes and hazardous constituents in waste placed in land disposel units to migrate into the environment. This is achieved through liquids management (limiting the placement of liquid wastes in or on the land, requiring the use of liners beneath waste, installing leachate collection systems and run-on and run-off controls, and covering wastes at closure). Ground-water monitoring serves to detect any failure in EPA's liquids management strategy so that ground-water contamination can be detected and addressed as soon as possible

Investigating geochemical aspects of managed aquifer recharge by column experiments with alternating desalinated water and groundwater.

Science.gov (United States)

Ronen-Eliraz, Gefen; Russak, Amos; Nitzan, Ido; Guttman, Joseph; Kurtzman, Daniel

2017-01-01

Managed aquifer recharge (MAR) events are occasionally carried out with surplus desalinated seawater that has been post-treated with CaCO 3 in infiltration ponds overlying the northern part of the Israeli Coastal Aquifer. This water's chemical characteristics differ from those of any other water recharged to the aquifer and of the natural groundwater. As the MAR events are short (hours to weeks), the sediment under the infiltration ponds will intermittently host desalinated and natural groundwater. As part of comprehensive research on the influence of those events, column experiments were designed to simulate the alternation of the two water types: post-treated desalinated seawater (PTDES) and natural groundwater (GW). Each experiment included three stages: (i) saturation with GW; (ii) inflow of PTDES; (iii) inflow of GW. Three runs were conducted, each with different sediments extracted from the field and representing a different layer below the infiltration pond: (i) sand (<1% CaCO 3 ), (ii) sand containing 7% CaCO 3 , and (iii) crushed calcareous sandstone (35% CaCO 3 ). The results from all columns showed enrichment of K + and Mg 2+ (up to 0.4meq/L for 20 pore volumes) when PTDES replaced GW, whereas an opposite trend of Ca 2+ depletion (up to 0.5meq/L) was observed only in the columns that contained a high percentage of CaCO 3 . When GW replaced PTDES, depletion of Mg 2+ and K + was noted. The results indicated that adsorption/desorption of cations are the main processes causing the observed enrichment/depletion. It was concluded that the high concentration of Ca 2+ (relative to the total concentration of cations) and the low concentration of Mg 2+ in the PTDES relative to natural GW are the factors controlling the main sediment-water interaction. The enrichment of PTDES with Mg 2+ may be viewed as an additional post-treatment. Copyright © 2016 Elsevier B.V. All rights reserved.

Simulation of the effects of rainfall and groundwater use on historical lake water levels, groundwater levels, and spring flows in central Florida

Science.gov (United States)

O'Reilly, Andrew M.; Roehl, Edwin A.; Conrads, Paul; Daamen, Ruby C.; Petkewich, Matthew D.

2014-01-01

The urbanization of central Florida has progressed substantially in recent decades, and the total population in Lake, Orange, Osceola, Polk, and Seminole Counties more than quadrupled from 1960 to 2010. The Floridan aquifer system is the primary source of water for potable, industrial, and agricultural purposes in central Florida. Despite increases in groundwater withdrawals to meet the demand of population growth, recharge derived by infiltration of rainfall in the well-drained karst terrain of central Florida is the largest component of the long-term water balance of the Floridan aquifer system. To complement existing physics-based groundwater flow models, artificial neural networks and other data-mining techniques were used to simulate historical lake water level, groundwater level, and spring flow at sites throughout the area. Historical data were examined using descriptive statistics, cluster analysis, and other exploratory analysis techniques to assess their suitability for more intensive data-mining analysis. Linear trend analyses of meteorological data collected by the National Oceanic and Atmospheric Administration at 21 sites indicate 67 percent of sites exhibited upward trends in air temperature over at least a 45-year period of record, whereas 76 percent exhibited downward trends in rainfall over at least a 95-year period of record. Likewise, linear trend analyses of hydrologic response data, which have varied periods of record ranging in length from 10 to 79 years, indicate that water levels in lakes (307 sites) were about evenly split between upward and downward trends, whereas water levels in 69 percent of wells (out of 455 sites) and flows in 68 percent of springs (out of 19 sites) exhibited downward trends. Total groundwater use in the study area increased from about 250 million gallons per day (Mgal/d) in 1958 to about 590 Mgal/d in 1980 and remained relatively stable from 1981 to 2008, with a minimum of 559 Mgal/d in 1994 and a maximum of 773

Combining groundwater quality analysis and a numerical flow simulation for spatially establishing utilization strategies for groundwater and surface water in the Pingtung Plain

Science.gov (United States)

Jang, Cheng-Shin; Chen, Ching-Fang; Liang, Ching-Ping; Chen, Jui-Sheng

2016-02-01

Overexploitation of groundwater is a common problem in the Pingtung Plain area of Taiwan, resulting in substantial drawdown of groundwater levels as well as the occurrence of severe seawater intrusion and land subsidence. Measures need to be taken to preserve these valuable groundwater resources. This study seeks to spatially determine the most suitable locations for the use of surface water on this plain instead of extracting groundwater for drinking, irrigation, and aquaculture purposes based on information obtained by combining groundwater quality analysis and a numerical flow simulation assuming the planning of manmade lakes and reservoirs to the increase of water supply. The multivariate indicator kriging method is first used to estimate occurrence probabilities, and to rank townships as suitable or unsuitable for groundwater utilization according to water quality standards for drinking, irrigation, and aquaculture. A numerical model of groundwater flow (MODFLOW) is adopted to quantify the recovery of groundwater levels in townships after model calibration when groundwater for drinking and agricultural demands has been replaced by surface water. Finally, townships with poor groundwater quality and significant increases in groundwater levels in the Pingtung Plain are prioritized for the groundwater conservation planning based on the combined assessment of groundwater quality and quantity. The results of this study indicate that the integration of groundwater quality analysis and the numerical flow simulation is capable of establishing sound strategies for joint groundwater and surface water use. Six southeastern townships are found to be suitable locations for replacing groundwater with surface water from manmade lakes or reservoirs to meet drinking, irrigation, and aquaculture demands.

Groundwater quality in the Sierra Nevada, California

Science.gov (United States)

Fram, Miranda S.; Belitz, Kenneth

2014-01-01

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project (PBP) of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. The Sierra Nevada Regional study unit constitutes one of the study units being evaluated.

A global-scale two-layer transient groundwater model : Development and application to groundwater depletion

NARCIS (Netherlands)

de Graaf, Inge E.M.|info:eu-repo/dai/nl/338038612; van Beek, Rens L.P.H.|info:eu-repo/dai/nl/14749799X; Gleeson, Tom; Moosdorf, Nils; Schmitz, Oliver|info:eu-repo/dai/nl/314003975; Sutanudjaja, Edwin H.|info:eu-repo/dai/nl/314571477; Bierkens, Marc F.P.|info:eu-repo/dai/nl/125022794

2017-01-01

Groundwater is the world's largest accessible source of freshwater to satisfy human water needs. Moreover, groundwater buffers variable precipitation rates over time, thereby effectively sustaining river flows in times of droughts and evaporation in areas with shallow water tables. In this study,

F-Area Seepage Basins groundwater monitoring report -- third and fourth quarters 1993

International Nuclear Information System (INIS)

Butler, C.T.

1994-03-01

During the second half of 1993, the groundwater at the F-Area Seepage Basins (FASB) was monitored in compliance with Module 3, Section C, of South Carolina Hazardous Waste Permit SC1-890-008-989, effective November 2, 1992. The monitoring well network is composed of 87 FSB wells screened in the three hydrostratigraphic units that make up the uppermost aquifer beneath the FASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B post-closure care permit application for the F-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1990. Beginning in the first quarter of 1993, the standard for comparison became the SCDHEC Groundwater Protection Standard (GWPS) specified in the approved F-Area Seepage Basins Part B permit. Currently and historically, gross alpha, nitrate, nonvolatile beta, and tritium are among the primary constituents to exceed standards. Numerous other radionuclides and hazardous constituents also exceeded the GWPS in the groundwater at the FASB during the second half of 1993, notably aluminum, iodine-129, and zinc. The elevated constituents are found primarily in Aquifer Zone 2B 2 and Aquifer Zone 2B 1 wells. However, several Aquifer Unit 2A wells also contain elevated levels of constituents. Isoconcentration/isoactivity maps included in this report indicate both the concentration/activity and extent of the primary contaminants in each of the three hydrostratigraphic units. Water-level maps indicate that the groundwater flow rates and directions at the FASB have remained relatively constant since the basins ceased to be active in 1988

National survey of molecular bacterial diversity of New Zealand groundwater: relationships between biodiversity, groundwater chemistry and aquifer characteristics.

Science.gov (United States)

Sirisena, Kosala A; Daughney, Christopher J; Moreau-Fournier, Magali; Ryan, Ken G; Chambers, Geoffrey K

2013-12-01

Groundwater is a vital component of rural and urban water supplies in New Zealand. Although extensive monitoring of chemical and physical properties is conducted due to the high demand for this valuable resource, current information on its bacterial content is limited. However, bacteria provide an immense contribution to drive the biogeochemical processes in the groundwater ecosystem as in any other ecosystem. Therefore, a proper understanding of bacterial diversity is crucial to assess the effectiveness of groundwater management policies. In this study, we investigated the bacterial community structure in NZ groundwater at a national scale using the terminal restriction fragment length polymorphism (T-RFLP) molecular profiling tool and determined the relationships between bacterial diversity and groundwater chemistry, geological parameters and human impact. Considerable bacterial diversity was present and the community structures were strongly related to groundwater chemistry, and in particular to redox potential and human impact, reflecting their potential influence on determination of bacterial diversity. Further, the mean residence time of groundwater also showed relationships with bacterial community structure. These novel findings pertaining to community composition and its relationships with environmental parameters will provide a strong foundation for qualitative exploration of the bacterial diversity in NZ groundwater in relation to sustainable management of this valuable resource. © 2013 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

Spatial Isotopic Characterization of Slovak Groundwaters

Energy Technology Data Exchange (ETDEWEB)

Povinec, P. P.; Sivo, A.; Breier, R.; Richtarikova, M. [Comenius University, Faculty of Mathematics, Physics and Informatics, Bratislava (Slovakia); Zenisova, Z. [Comenius University, Faculty of Natural Sciences, Bratislava (Slovakia); Aggarwal, P. K.; Araguas Araguas, L. [International Atomic Energy Agency, Isotope Hydrology Section, Vienna (Austria)

2013-07-15

Zitny ostrov (Rye Island) in the south west of Slovakia is the largest groundwater reservoir in Central Europe (about 10 Gm{sup 3}). Groundwater contamination with radionuclides, heavy metals and organic compounds from the Danube River and local industrial and agricultural activities has recently been of great concern. Geostatistical analysis of experimental isotope data has been carried out with the aim of better understanding groundwater dynamics. For this purpose, spatial variations in the distribution of water isotopes and radiocarbon in the groundwater of Zitny ostrov have been evaluated. Subsurface water profiles showed enriched {delta}{sup 18}O levels at around 20 m water depth, and depleted values below 30 m, which are similar to those observed in the Danube River. The core of the subsurface {sup 14}C profiles represents contemporary groundwater with {sup 14}C values above 80 pMc. (author)

Voltammetric determination of arsenic in high iron and manganese groundwaters.

Science.gov (United States)

Gibbon-Walsh, Kristoff; Salaün, Pascal; Uroic, M Kalle; Feldmann, Joerg; McArthur, John M; van den Berg, Constant M G

2011-09-15

Determination of the speciation of arsenic in groundwaters, using cathodic stripping voltammetry (CSV), is severely hampered by high levels of iron and manganese. Experiments showed that the interference is eliminated by addition of EDTA, making it possible to determine the arsenic speciation on-site by CSV. This work presents the CSV method to determine As(III) in high-iron or -manganese groundwaters in the field with only minor sample treatment. The method was field-tested in West-Bengal (India) on a series of groundwater samples. Total arsenic was subsequently determined after acidification to pH 1 by anodic stripping voltammetry (ASV). Comparative measurements by ICP-MS as reference method for total As, and by HPLC for its speciation, were used to corroborate the field data in stored samples. Most of the arsenic (78±0.02%) was found to occur as inorganic As(III) in the freshly collected waters, in accordance with previous studies. The data shows that the modified on-site CSV method for As(III) is a good measure of water contamination with As. The EDTA was also found to be effective in stabilising the arsenic speciation for longterm sample storage at room temperature. Without sample preservation, in water exposed to air and sunlight, the As(III) was found to become oxidised to As(V), and Fe(II) oxidised to Fe(III), removing the As(V) by adsorption on precipitating Fe(III)-hydroxides within a few hours. Copyright © 2011 Elsevier B.V. All rights reserved.

Control of aromatic-waste air streams by soil bioreactors

International Nuclear Information System (INIS)

Miller, D.E.; Canter, L.W.

1991-01-01

Contamination of groundwater resources is a serious environmental problem which is continuing to increase in occurrence in the United States. It has been reported that leaking underground gasoline storage tanks may pose the most serious threat of all sources of groundwater contamination. Gasolines are comprised of a variety of aliphatic and aromatic hydrocarbons. The aromatic portion consists primarily of benzene, toluene, ethylbenzene, and xylenes (BTEX compounds). BTEX compounds are also among the most frequency identified substances at Superfund sites. Pump and treat well systems are the most common and frequently used technique for aquifer restoration. Treatment is often in the form of air stripping to remove the volatile components from the contaminated water. Additionally, soil ventilation processes have been used to remove volatile components from the vadose zone. Both air stripping and soil ventilation produce a waste gas stream containing volatile compounds which is normally treated by carbon adsorption or incineration. Both treatment processes require a substantial capital investment and continual operation and maintenance expenditures. The objective of the study was to examine the potential of using soil bioreactors to treat a waste gas stream produced by air stripping or soil ventilation process. Previous studies have shown that various hydrocarbons can be successfully treated with soils. The study examined the removal of BTEX compounds within soil columns and the influence of soil type, inlet concentration, and inlet flow rate on the removal efficiency

Methane in groundwater from a leaking gas well, Piceance Basin, Colorado, USA

Science.gov (United States)

McMahon, Peter B.; Thomas, Judith C.; Crawford, John T.; Dornblaser, Mark M.; Hunt, Andrew G.

2018-01-01

Site-specific and regional analysis of time-series hydrologic and geochemical data collected from 15 monitoring wells in the Piceance Basin indicated that a leaking gas well contaminated shallow groundwater with thermogenic methane. The gas well was drilled in 1956 and plugged and abandoned in 1990. Chemical and isotopic data showed the thermogenic methane was not from mixing of gas-rich formation water with shallow groundwater or natural migration of a free-gas phase. Water-level and methane-isotopic data, and video logs from a deep monitoring well, indicated that a shale confining layer ~125 m below the zone of contamination was an effective barrier to upward migration of water and gas. The gas well, located 27 m from the contaminated monitoring well, had ~1000 m of uncemented annular space behind production casing that was the likely pathway through which deep gas migrated into the shallow aquifer. Measurements of soil gas near the gas well showed no evidence of methane emissions from the soil to the atmosphere even though methane concentrations in shallow groundwater (16 to 20 mg/L) were above air-saturation levels. Methane degassing from the water table was likely oxidized in the relatively thick unsaturated zone (~18 m), thus rendering the leak undetectable at land surface. Drilling and plugging records for oil and gas wells in Colorado and proxies for depth to groundwater indicated thousands of oil and gas wells were drilled and plugged in the same timeframe as the implicated gas well, and the majority of those wells were in areas with relatively large depths to groundwater. This study represents one of the few detailed subsurface investigations of methane leakage from a plugged and abandoned gas well. As such, it could provide a useful template for prioritizing and assessing potentially leaking wells, particularly in cases where the leakage does not manifest itself at land surface.

Hydrochemistry of urban groundwater, Seoul, Korea: the impact of subway tunnels on groundwater quality.

Science.gov (United States)

Chae, Gi-Tak; Yun, Seong-Taek; Choi, Byoung-Young; Yu, Soon-Young; Jo, Ho-Young; Mayer, Bernhard; Kim, Yun-Jong; Lee, Jin-Yong

2008-10-23

Hydrogeologic and hydrochemical data for subway tunnel seepage waters in Seoul (Republic of Korea) were examined to understand the effect of underground tunnels on the degradation of urban groundwater. A very large quantity of groundwater (up to 63 million m3 year(-1)) is discharged into subway tunnels with a total length of 287 km, resulting in a significant drop of the local groundwater table and the abandonment of groundwater wells. For the tunnel seepage water samples (n = 72) collected from 43 subway stations, at least one parameter among pathogenic microbes (total coliform, heterotrophic bacteria), dissolved Mn and Fe, NH4+, NO3(-), turbidity, and color exceeded the Korean Drinking Water Standards. Locally, tunnel seepage water was enriched in dissolved Mn (avg. 0.70 mg L(-1), max. 5.58 mg L(-1)), in addition to dissolved Fe, NH4+, and pathogenic microbes, likely due to significant inflow of sewage water from broken or leaking sewer pipes. Geochemical modeling of redox reactions was conducted to simulate the characteristic hydrochemistry of subway tunnel seepage. The results show that variations in the reducing conditions occur in urban groundwater, dependent upon the amount of organic matter-rich municipal sewage contaminating the aquifer. The organic matter facilitates the reduction and dissolution of Mn- and Fe-bearing solids in aquifers and/or tunnel construction materials, resulting in the successive increase of dissolved Mn and Fe. The present study clearly demonstrates that locally significant deterioration of urban groundwater is caused by a series of interlinked hydrogeologic and hydrochemical changes induced by underground tunnels.

Hanford Site ground-water monitoring for 1995

International Nuclear Information System (INIS)

Dresel, P.E.; Rieger, J.T.; Webber, W.D.; Thorne, P.D.; Gillespie, B.M.; Luttrell, S.P.; Wurstner, S.K.; Liikala, T.L.

1996-08-01

This report presents the results of the Groundwater Surveillance Project monitoring for calendar year 1995 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that impacted groundwater quality on the site. Monitoring of water levels and groundwater chemistry is performed to track the extent of contamination, to note trends in contaminant concentrations,a nd to identify emerging groundwater quality problems. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of onsite groundwater quality. A three- dimensional, numerical, groundwater model is being developed to improve predictions of contaminant transport. The existing two- dimensional model was applied to predict contaminant flow paths and the impact of changes on site conditions. These activities were supported by limited hydrogeologic characterization. Water level monitoring was performed to evaluate groundwater flow directions, to track changes in water levels, and to relate such changes to evolving disposal practices. Radiological monitoring results indicated that many radioactive contaminants were above US Environmental Protection Agency or State of Washington drinking water standards at the Hanford Site. Nitrate, fluoride, chromium, cyanide, carbon tetrachloride, chloroform, trichloroethylene, and cis-1,2-dichloroethylene were present in groundwater samples at levels above their US EPA or State of Washington maximum contaminant levels