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Sample records for ground-water samples contained

  1. Magnificent Ground Water Connection. [Sample Activities].

    Science.gov (United States)

    Environmental Protection Agency, Washington, DC.

    Water conservation and usage is an important concept in science. This document, geared specifically to New England, provides many activities for protecting and discussing ground water situations. Sample activities for grades K-6 include: (1) All the Water in the World; (2) The Case of the Disappearing Water; (3) Deep Subjects--Wells and Ground…

  2. Contamination of Ground Water Samples from Well Installations

    DEFF Research Database (Denmark)

    Grøn, Christian; Madsen, Jørgen Øgaard; Simonsen, Y.

    1996-01-01

    Leaching of a plasticizer, N-butylbenzenesulfonamide, from ground water multilevel sampling installations in nylon has been demonstrated. The leaching resulted in concentrations of DOC and apparent AOX, both comparable with those observed in landfill contaminated ground waters. It is concluded th...

  3. 40 CFR 258.53 - Ground-water sampling and analysis requirements.

    Science.gov (United States)

    2010-07-01

    ....53 Ground-water sampling and analysis requirements. (a) The ground-water monitoring program must... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water sampling and analysis requirements. 258.53 Section 258.53 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)...

  4. 40 CFR 257.23 - Ground-water sampling and analysis requirements.

    Science.gov (United States)

    2010-07-01

    ... and analysis requirements. (a) The ground-water monitoring program must include consistent sampling... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water sampling and analysis requirements. 257.23 Section 257.23 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)...

  5. The anti-obesity effect of natural vanadium-containing Jeju ground water.

    Science.gov (United States)

    Park, Seon-Joo; Youn, Cha-Kyung; Hyun, Jin Won; You, Ho Jin

    2013-02-01

    This study investigated the anti-obesity effects of Jeju ground water containing the vanadium components S1 (8.0 ± 0.9 μg/l) and S3 (26.0 ± 2.09 μg/l) on the differentiation of 3 T3-L1 preadipocytes and obesity in mice that were fed a high-fat diet (HFD). The 3 T3-L1 preadipocyte cells were cultured and differentiated in media consisting of Jeju ground water (S1, S3) or deionized water (DW) containing dexamethasone, isobutylmethylxanthine, and insulin. Oil Red O staining showed that lipid accumulation was attenuated in adipocyte cells treated with Jeju ground water. S3 significantly decreased peroxisome-activated receptor γ and CCAAT-enhancer-binding protein α mRNA expression levels, which play major roles in the transcriptional control of adipogenesis, compared to DW. Furthermore, mRNA expression levels of targeted genes, such as adipocyte fatty acid, lipoprotein lipase, and leptin, were decreased by S3 treatment compared with the control group. In mice with HFD-induced obesity, Jeju ground water decreased HFD-induced body weight gain and reduced total cholesterol, triglyceride, and glucose levels in the plasma compared to control mice. Taken together, Jeju ground water inhibits preadipocyte differentiation and adipogenesis in obesity animal models.

  6. METALS IN GROUND WATER: SAMPLING ARTIFACTS AND REPRODUCIBILITY

    Science.gov (United States)

    Field studies evaluated sampling procedures for determination of aqueous inorganic geochemistry and assessment of contaminant transport by colloidal mobility. esearch at three different metal-contaminated sites has shown that 0.45 tm filtration has not removed potentially mobile ...

  7. Gross-beta activity in ground water: natural sources and artifacts of sampling and laboratory analysis

    Science.gov (United States)

    Welch, Alan H.

    1995-01-01

    Gross-beta activity has been used as an indicator of beta-emitting isotopes in water since at least the early 1950s. Originally designed for detection of radioactive releases from nuclear facilities and weapons tests, analysis of gross-beta activity is widely used in studies of naturally occurring radioactivity in ground water. Analyses of about 800 samples from 5 ground-water regions of the United States provide a basis for evaluating the utility of this measurement. The data suggest that measured gross-beta activities are due to (1) long-lived radionuclides in ground water, and (2) ingrowth of beta-emitting radionuclides during holding times between collection of samples and laboratory measurements.Although40K and228Ra appear to be the primary sources of beta activity in ground water, the sum of40K plus228Ra appears to be less than the measured gross-beta activity in most ground-water samples. The difference between the contribution from these radionuclides and gross-beta activity is most pronounced in ground water with gross-beta activities > 10 pCi/L, where these 2 radionuclides account for less than one-half the measured ross-beta activity. One exception is groundwater from the Coastal Plain of New Jersey, where40K plus228Ra generally contribute most of the gross-beta activity. In contrast,40K and228Ra generally contribute most of beta activity in ground water with gross-beta activities measure all beta activity in ground water. Although3H contributes beta activity to some ground water, it is driven from the sample before counting and therefore is not detected by gross-beta measurements. Beta-emitting radionuclides with half-lives shorter than a few days can decay to low values between sampling and counting. Although little is known about concentrations of most short-lived beta-emitting radionuclides in environmental ground water (water unaffected by direct releases from nuclear facilities and weapons tests), their activities are expected to be low.Ingrowth of

  8. Robowell: An automated process for monitoring ground water quality using established sampling protocols

    Science.gov (United States)

    Granato, G.E.; Smith, K.P.

    1999-01-01

    Robowell is an automated process for monitoring selected ground water quality properties and constituents by pumping a well or multilevel sampler. Robowell was developed and tested to provide a cost-effective monitoring system that meets protocols expected for manual sampling. The process uses commercially available electronics, instrumentation, and hardware, so it can be configured to monitor ground water quality using the equipment, purge protocol, and monitoring well design most appropriate for the monitoring site and the contaminants of interest. A Robowell prototype was installed on a sewage treatment plant infiltration bed that overlies a well-studied unconfined sand and gravel aquifer at the Massachusetts Military Reservation, Cape Cod, Massachusetts, during a time when two distinct plumes of constituents were released. The prototype was operated from May 10 to November 13, 1996, and quality-assurance/quality-control measurements demonstrated that the data obtained by the automated method was equivalent to data obtained by manual sampling methods using the same sampling protocols. Water level, specific conductance, pH, water temperature, dissolved oxygen, and dissolved ammonium were monitored by the prototype as the wells were purged according to U.S Geological Survey (USGS) ground water sampling protocols. Remote access to the data record, via phone modem communications, indicated the arrival of each plume over a few days and the subsequent geochemical reactions over the following weeks. Real-time availability of the monitoring record provided the information needed to initiate manual sampling efforts in response to changes in measured ground water quality, which proved the method and characterized the screened portion of the plume in detail through time. The methods and the case study described are presented to document the process for future use.

  9. Demonstration/Validation of the Snap Sampler Passive Ground Water Sampling Device

    Science.gov (United States)

    2011-06-01

    direction, although the direction of groundwater movement locally is influenced by water -supply wells and by groundwater extraction and treatment systems...Validation of the Snap Sampler Passive Ground Water Sampling Device June 2011 i COST & PERFORMANCE REPORT Project: ER-200630 TABLE OF CONTENTS...range of analyte types. These included dissolved and total inorganics (including non-metal anions, metalloids , and metals) and four volatile organic

  10. Determination of natural radioactivity by gross alpha and beta measurements in ground water samples.

    Science.gov (United States)

    Turhan, S; Ozçitak, E; Taşkin, H; Varinlioğlu, A

    2013-06-01

    In this study, the activity concentrations of the gross α and β in ground water samples collected from the different drilled wells in Nevşehir province were measured to assess annual effective dose due to the ingestion of the water samples. Nevşehir province is one of the major cities of Cappadocia Region which is a popular tourist destination as it has many areas with unique geological, historic, and cultural features. Sampling and measurements were carried out in the autumn of 2011 and the spring of 2012. The values of the activity concentrations of the gross α and β measured in the water samples ranged from 80 to 380 mBq L(-1) with a mean of 192 mBq L(-1) and 120-3470 mBq L(-1) with a mean of 579 mBq L(-1) respectively. All values of the gross α were lower than the limit value of 500 mBq L(-1) while two ground water samples were found to have gross β activity concentrations of greater than 1000 mBq L(-1). Therefore two water samples were the subject of further radioisotope-specific analysis. The obtained result indicated that the elevated activity concentrations of the gross β in these water samples are dominated by (40)K activity. Annual effective doses ranged from 0.04 to 0.20 mSv y(-1).

  11. Sampling and analysis for radon-222 dissolved in ground water and surface water

    Science.gov (United States)

    DeWayne, Cecil L.; Gesell, T.F.

    1992-01-01

    Radon-222 is a naturally occurring radioactive gas in the uranium-238 decay series that has traditionally been called, simply, radon. The lung cancer risks associated with the inhalation of radon decay products have been well documented by epidemiological studies on populations of uranium miners. The realization that radon is a public health hazard has raised the need for sampling and analytical guidelines for field personnel. Several sampling and analytical methods are being used to document radon concentrations in ground water and surface water worldwide but no convenient, single set of guidelines is available. Three different sampling and analytical methods - bubbler, liquid scintillation, and field screening - are discussed in this paper. The bubbler and liquid scintillation methods have high accuracy and precision, and small analytical method detection limits of 0.2 and 10 pCi/l (picocuries per liter), respectively. The field screening method generally is used as a qualitative reconnaissance tool.

  12. Quality of nutrient data from streams and ground water sampled during water years 1992-2001

    Science.gov (United States)

    Mueller, David K.; Titus, Cindy J.

    2005-01-01

    Proper interpretation of water-quality data requires consideration of the effects that bias and variability might have on measured constituent concentrations. In this report, methods are described to estimate the bias due to contamination of samples in the field or laboratory and the variability due to sample collection, processing, shipment, and analysis. Contamination can adversely affect interpretation of measured concentrations in comparison to standards or criteria. Variability can affect interpretation of small differences between individual measurements or mean concentrations. Contamination and variability are determined for nutrient data from quality-control samples (field blanks and replicates) collected as part of the National Water-Quality Assessment (NAWQA) Program during water years 1992-2001. Statistical methods are used to estimate the likelihood of contamination and variability in all samples. Results are presented for five nutrient analytes from stream samples and four nutrient analytes from ground-water samples. Ammonia contamination can add at least 0.04 milligram per liter in up to 5 percent of all samples. This could account for more than 22 percent of measured concentrations at the low range of aquatic-life criteria (0.18 milligram per liter). Orthophosphate contamination, at least 0.019 milligram per liter in up to 5 percent of all samples, could account for more than 38 percent of measured concentrations at the limit to avoid eutrophication (0.05 milligram per liter). Nitrite-plus-nitrate and Kjeldahl nitrogen contamination is less than 0.4 milligram per liter in 99 percent of all samples; thus there is no significant effect on measured concentrations of environmental significance. Sampling variability has little or no effect on reported concentrations of ammonia, nitrite-plus-nitrate, orthophosphate, or total phosphorus sampled after 1998. The potential errors due to sampling variability are greater for the Kjeldahl nitrogen analytes and

  13. Determination of uranium concentration in ground water samples of Northern Greece

    Directory of Open Access Journals (Sweden)

    Pashalidis I.

    2012-04-01

    Full Text Available The activity concentration of 238U and 234U has been determined in groundwater samples of hot springs and deep wells from the region of Northern Greece. The analysis was performed by alpha spectroscopy after pre-concentration and separation of uranium by cation exchange (Chelex 100 resin and finally its electro-deposition on stainless steel discs. The uranium concentration in deep wells and springs varies strongly between 0.15 and 7.66 μg l−1. Generally the springs present higher uranium concentration than the deep wells, except of the Apol-lonia spring, which has shown the lowest value of 0.15 mg l−1. 238U and 234U activity concentration ranged between 1.8–95.3 mBq l−1 and 1.7–160.1 mBq l−1, respectively. The obtained isotopic ratio 234U/238U varies between 0.95 and 1.74 which means that the two isotopes are not in radioactive equilibrium. The highest 234U/238U activity ratio values correspond to the Langada springs, indicating most probably old-type waters. On the other hand, ground waters from wells with relatively low uranium activity concentration and low 234U/238U isotopic ratios, point to the presence of younger waters with a stronger contribution of a local recharge component to the groundwater.

  14. ASSESSMENT OF PHYSICO-CHEMICAL STATUS OF GROUND WATER SAMPLES OF PARBHANI DISTRICT (M.S., INDIA

    Directory of Open Access Journals (Sweden)

    D.A. Dhale et al.

    2012-05-01

    Full Text Available Ground water is the most preferred water source in recent day. Once believed to be safe from pollution as it is available many strata below the surface, is now provided to be prone to pollution by many researchers across the world. The contamination of ground water may be due to improper disposal of domestic and industrial west water. A study was carried out to assess the ground water quality of Parbhani District, one of the most important agro plantation areas of Maharashtra State (India. The present work was undertaken to assess the ground water quality and discus the potability of ground water by collecting data of physio-chemical characters of ground water. The study was carried out in years 2007 by selecting 10 spots, situated in Parbhani District. Nineteen water quality parameters of water of all sites were estimated following standard methods and procedures of sampling and estimation. Comparison of estimated values with W.H.O. The physio-chemical parameter such as Temperature, colour, odour, pH, electrical conductivity (EC, total dissolved solids (TDS, turbidity, total hardness (TH, calcium (Ca++, magnesium (Mg++, total alkalinity (TA, bicarbonate (HCO3-, sodium (Na+, potassium (K+, chloride (Cl-, fluoride (F- nitrate (NO-3 and sulphate (SO--4 were studied. Variations in these values were observed. The sampling point S6 and S7 showed high total hardness content indicating the need of some treatment for minimization of the parameters. Other sites water under investigation was found physicochemical parameters within the water quality standards and the quality of water is good and it is fit for drinking purpose.

  15. Comparison of Pumped and Diffusion Sampling Methods to Monitor Concentrations of Perchlorate and Explosive Compounds in Ground Water, Camp Edwards, Cape Cod, Massachusetts, 2004-05

    Science.gov (United States)

    LeBlanc, Denis R.; Vroblesky, Don A.

    2008-01-01

    Laboratory and field tests were conducted at Camp Edwards on the Massachusetts Military Reservation on Cape Cod to examine the utility of passive diffusion sampling for long-term monitoring of concentrations of perchlorate and explosive compounds in ground water. The diffusion samplers were constructed of 1-inch-diameter rigid, porous polyethylene tubing. The results of laboratory tests in which diffusion samplers were submerged in containers filled with ground water containing perchlorate, RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), and HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) indicate that concentrations inside the diffusion samplers equilibrated with concentrations in the containers within the 19-day-long test period. Field tests of the diffusion samplers were conducted in 15 wells constructed of 2- or 2.5-inch-diameter polyvinyl chloride pipe with 10-foot-long slotted screens. Concentrations of perchlorate, RDX, and HMX in the diffusion samplers placed in the wells for 42 to 52 days were compared to concentrations in samples collected by low-flow pumped sampling from 53 days before to 109 days after retrieval of the diffusion samples. The results of the field tests indicate generally good agreement between the pumped and diffusion samples for concentrations of perchlorate, RDX, and HMX. The concentration differences indicate no systematic bias related to contaminant type or concentration levels.

  16. Ground water in Oklahoma

    Science.gov (United States)

    Leonard, A.R.

    1960-01-01

    estimated that about one-third of the water used in the State in 1956, or 400,000 acre-feet, came from ground-water sources. In 1957, 71 percent of the irrigation water used in the State came from underground sources, and ground water was used for irrigation in 57 of the State's 77 counties. More than 300 of the towns and cities of the State obtain all their municipal water supplies from ground water. The major ground-water reservoirs, or aquifers, of Oklahoma may be classed in four general groups: (1) semiconsolidated sand and gravel underlying the High Plains, (2) unconsolidated alluvial deposits of sand and gravel along streams and adjacent to valleys, (3) sandstone aquifers, and (4) limestone aquifers, including, for the purpose of this generalized breakdown, dolomite and gypsum. The locations of these major aquifers are shown on figure 1. Areas on that map do not correspond exactly to outcrops, but are the areas where the formations contain significant quantities of potable water. Near their edges rock formations may be cut through by streams or they may be too thin to contain much water. On the other hand, some formations contain fresh ground water for many miles downdip from their outcrop areas, where wells must first penetrate overlying rocks to reach them. (available as photostat copy only)

  17. GROUND WATER MONITORING AND SAMPLING: MULTI-LEVEL VERSUS TRADITIONAL METHODS – WHAT’S WHAT?

    Science.gov (United States)

    Recent studies have been conducted to evaluate different sampling techniques for determining VOC concentrations in groundwater. Samples were obtained using multi-level and traditional sampling techniques in three monitoring wells at the Raymark Superfund site in Stratford, CT. Ve...

  18. Chemical analyses of ground-water samples from the Rio Grande Valley in the vicinity of Albuquerque, New Mexico, October 1993 through January 1994

    Science.gov (United States)

    Wilkins, D.W.; Schlottmann, J.L.; Ferree, D.M.

    1996-01-01

    A study was conducted to investigate general ground-water- quality conditions and contaminant locations in the Rio Grande Valley in the vicinity of Albuquerque, New Mexico. Water samples from 36 observation wells in 12 well nests were analyzed. The well nests are located along three roads near the Rio Grande--two well nests near Paseo del Norte, five well nests near Monta?o Road, and five well nests near Rio Bravo Boulevard. The water samples were collected from October 19, 1993, through January 18, 1994. Water-quality types by major-ion composition were calcium bicarbonate (found in most samples), sodium sulfate, calcium sulfate, and calcium sulfate chloride. Nutrients were detected in all but one sample. Ammonia was detected in 34 samples, nitrite in 4 samples, and nitrate in 17 samples. Orthophosphate was detected in 31 samples. Organic carbon was detected in all samples collected. The trace elements arsenic and barium were detected in all samples and zinc in 31 samples. Fourteen samples contained detectable copper. Cadmium was detected in one sample, chromium in two samples, lead in four samples, and selenium in two samples. Mercury and silver were not detected.

  19. An experiment in representative ground-water sampling for water- quality analysis

    Science.gov (United States)

    Huntzinger, T.L.; Stullken, L.E.

    1988-01-01

    Obtaining a sample of groundwater that accurately represents the concentration of a chemical constituent in an aquifer is an important aspect of groundwater-quality studies. Varying aquifer and constituent properties may cause chemical constituents to move within selectively separate parts of the aquifer. An experiment was conducted in an agricultural region in south-central Kansas to address questions related to representative sample collection. Concentrations of selected constituents in samples taken from observation wells completed in the upper part of the aquifer were compared to concentrations in samples taken from irrigation wells to determine if there was a significant difference. Water in all wells sampled was a calcium bicarbonate type with more than 200 mg/L hardness and about 200 mg/L alkalinity. Sodium concentrations were also quite large (about 40 mg/L). There was a significant difference in the nitrite-plus-nitrate concentrations between samples from observation and irrigation wells. The median concentration of nitrite plus nitrate in water from observation wells was 5.7 mg/L compared to 3.4 mg/L in water from irrigation wells. The differences in concentrations of calcium, magnesium, and sodium (larger in water from irrigation wells) were significant at the 78% confidence level but not at the 97% confidence level. Concentrations of the herbicide, atrazine, were less than the detection limit of 0.1 micrograms/L in all but one well. (USGS)

  20. DETERMINATION OF CHLOROPHENOLS, NITROPHENOLS, AND METHYLPHENOLS IN GROUND-WATER SAMPLES USING HIGH PERFORMANCE LIQUID CHROMATOGRAPHY

    Science.gov (United States)

    A high performance liquid chromatography (HPLC) method was developed to quantitatively determine phenolic compounds and their isomers in aqueous samples. The HPLC method can analyze a mixture of 15 contaminants in the same analytical run with an analysis time of 25 minutes. The...

  1. Evaluation of the Snap Sampler for Sampling Ground Water Monitoring Wells for Inorganic Analytes

    Science.gov (United States)

    2008-12-01

    screen, as does low-flow sampling (Robin and Gillham 1987; Powell and Puls 1993). Most research to date ( Michalski 1989; Gillham et al. 1985; Robin and...Fernando. 1991. A review of arsenic(III) in groundwater. Critical Reviews in Environmental Control 21:1–39. Michalski , M. 1989. Application of

  2. Evaluation of the Snap Sampler for Sampling Ground Water Monitoring Wells for VOCs and Explosives

    Science.gov (United States)

    2007-08-01

    23 Table 4. Results from the holding- time study with...the opposite order. First Holding- Time Study for VOCs The purpose of this study was to determine whether analyte concentra- tions of samples... Study for VOCs The procedure for this study was the same as for the previous holding- time study except that that the Snap Samplers were equilibrated

  3. PHYSICO-CHEMICAL ANALYSIS OF SELECTED GROUND WATER SAMPLES OF RURAL AREAS OF JAIPUR, RAJASTHAN

    Directory of Open Access Journals (Sweden)

    Priyanka Dhingra

    2014-12-01

    Full Text Available The aim of present study was to assess the status of the groundwater in rural areas of Jaipur city. People on globe are under tremendous threat due to undesired changes in the physical, chemical and biological characteristics of air, water and soil. Due to increased population, urbanization, industrialization, use of fertilizers water is highly polluted with different harmful contaminants Natural water resources are being contaminated due to weathering of rocks and leaching of soil, mining processing etc. It is necessary that quality of drinking water should be checked at regular time interval to prevent various water born diseases. In present analysis physico-chemical parameter of drinking water viz. pH, hardness, TDS, residual chlorine, dissolved oxygen, electrical conductivity, Free CO2 have been analyzed. Drinking water quality of 8 villages of Amber District Jaipur, Rajasthan was analyzed to identify the nature and quality of water. The drinking water samples were collected in clean polythene one liter cans and subjected for analysis in laboratory. The main objective of the present paper is to aware people of concerned area about the water quality and concerned health hazards.

  4. Ground water and energy

    Energy Technology Data Exchange (ETDEWEB)

    1980-11-01

    This national workshop on ground water and energy was conceived by the US Department of Energy's Office of Environmental Assessments. Generally, OEA needed to know what data are available on ground water, what information is still needed, and how DOE can best utilize what has already been learned. The workshop focussed on three areas: (1) ground water supply; (2) conflicts and barriers to ground water use; and (3) alternatives or solutions to the various issues relating to ground water. (ACR)

  5. Changes in sample collection and analytical techniques and effects on retrospective comparability of low-level concentrations of trace elements in ground water

    Science.gov (United States)

    Ivahnenko, T.; Szabo, Z.; Gibs, J.

    2001-01-01

    Ground-water sampling techniques were modified to reduce random low-level contamination during collection of filtered water samples for determination of trace-element concentrations. The modified sampling techniques were first used in New Jersey by the US Geological Survey in 1994 along with inductively coupled plasma-mass spectrometry (ICP-MS) analysis to determine the concentrations of 18 trace elements at the one microgram-per-liter (μg/L) level in the oxic water of the unconfined sand and gravel Kirkwood-Cohansey aquifer system. The revised technique tested included a combination of the following: collection of samples (1) with flow rates of about 2L per minute, (2) through acid-washed single-use disposable tubing and (3) a single-use disposable 0.45-μm pore size capsule filter, (4) contained within portable glove boxes, (5) in a dedicated clean sampling van, (6) only after turbidity stabilized at values less than 2 nephelometric turbidity units (NTU), when possible. Quality-assurance data, obtained from equipment blanks and split samples, indicated that trace element concentrations, with the exception of iron, chromium, aluminum, and zinc, measured in the samples collected in 1994 were not subject to random contamination at 1μg/L.Results from samples collected in 1994 were compared to those from samples collected in 1991 from the same 12 PVC-cased observation wells using the available sampling and analytical techniques at that time. Concentrations of copper, lead, manganese and zinc were statistically significantly lower in samples collected in 1994 than in 1991. Sampling techniques used in 1994 likely provided trace-element data that represented concentrations in the aquifer with less bias than data from 1991 when samples were collected without the same degree of attention to sample handling.

  6. 40 CFR 265.91 - Ground-water monitoring system.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Ground-water monitoring system. 265.91... DISPOSAL FACILITIES Ground-Water Monitoring § 265.91 Ground-water monitoring system. (a) A ground-water monitoring system must be capable of yielding ground-water samples for analysis and must consist of: (1...

  7. Radon-222 in the ground water of Chester County, Pennsylvania

    Science.gov (United States)

    Senior, Lisa A.

    1998-01-01

    Radon-222 concentrations in ground water in 31 geologic units in Chester County, Pa., were measured in 665 samples collected from 534 wells from 1986 to 1997. Chester County is underlain by schists, gneisses, quartzites, carbonates, sandstones, shales, and other rocks of the Piedmont Physiographic Province. On average, radon concentration was measured in water from one well per 1.4 square miles, throughout the 759 square-mile county, although the distribution of wells was not even areally or among geologic units. The median concentration of radon-222 in ground water from the 534 wells was 1,400 pCi/L (picocuries per liter). About 89 percent of the wells sampled contained radon-222 at concentrations greater than 300 pCi/L, and about 11 percent of the wells sampled contained radon-222 at concentrations greater than 5,000 pCi/L. The highest concentration measured was 53,000 pCi/L. Of the geologic units sampled, the median radon-222 concentration in ground water was greatest (4,400 pCi/L) in the Peters Creek Schist, the second most areally extensive formation in the county. Signifi- cant differences in the radon-222 concentrations in ground water among geologic units were observed. Generally, concentrations in ground water in schists, quartzites, and gneisses were greater than in ground water in anorthosite, carbonates, and ultramafic rocks. The distribution of radon-222 in ground water is related to the distribution of uranium in aquifer materials of the various rock types. Temporal variability in radon-222 concentrations in ground water does not appear to be greater than about a factor of two for most (75 percent) of wells sampled more than once but was observed to range up to almost a factor of three in water from one well. In water samples from this well, seasonal variations were observed; the maximum concentrations were measured in the fall and the minimum in the spring.

  8. Results of soil, ground-water, surface-water, and streambed-sediment sampling at Air Force Plane 85, Columbus, Ohio, 1996

    Science.gov (United States)

    Parnell, J.M.

    1997-01-01

    The U.S. Geological Survey (USGS), in cooperation with Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, prepared the Surface- and Ground- Water Monitoring Work Plan for Air Force Plant 85 (AFP 85 or Plant), Columbus, Ohio, under the Air Force Installation Restoration Program to characterize any ground-water, surface-water, and soil contamination that may exist at AFP 85. The USGS began the study in November 1996. The Plant was divided into nine sampling areas, which included some previously investi gated study sites. The investigation activities included the collection and presentation of data taken during drilling and water-quality sampling. Data collection focused on the saturated and unsatur ated zones and surface water. Twenty-three soil borings were completed. Ten monitoring wells (six existing wells and four newly constructed monitoring wells) were selected for water-quality sam pling. Surface-water and streambed-sediment sampling locations were chosen to monitor flow onto and off of the Plant. Seven sites were sampled for both surface-water and streambed-sediment quality. This report presents data on the selected inorganic and organic constituents in soil, ground water, surface water, and streambed sediments at AFP 85. The methods of data collection and anal ysis also are included. Knowledge of the geologic and hydrologic setting could aid Aeronautical Systems Center, Environmental Management Directorate, Restoration Division, and its governing regulatory agencies in future remediation studies.

  9. [Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio]. Volume 3, Sampling and analysis plan (SAP): Phase 1, Task 4, Field Investigation: Draft

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    In April 1990, Wright-Patterson Air Force Base (WPAFB), initiated an investigation to evaluate a potential Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) removal action to prevent, to the extent practicable, the offsite migration of contaminated ground water from WPAFB. WPAFB retained the services of the Environmental Management Operations (EMO) and its principle subcontractor, International Technology Corporation (IT) to complete Phase 1 of the environmental investigation of ground-water contamination at WPAFB. Phase 1 of the investigation involves the short-term evaluation and potential design for a program to remove ground-water contamination that appears to be migrating across the western boundary of Area C, and across the northern boundary of Area B along Springfield Pike. Primarily, Task 4 of Phase 1 focuses on collection of information at the Area C and Springfield Pike boundaries of WPAFB. This Sampling and Analysis Plan (SAP) has been prepared to assist in completion of the Task 4 field investigation and is comprised of the Quality Assurance Project Plan (QAPP) and the Field Sampling Plan (FSP).

  10. Determination of pharmaceutical compounds in surface- and ground-water samples by solid-phase extraction and high-performance liquid chromatography-electrospray ionization mass spectrometry

    Science.gov (United States)

    Cahill, J.D.; Furlong, E.T.; Burkhardt, M.R.; Kolpin, D.; Anderson, L.G.

    2004-01-01

    Commonly used prescription and over-the-counter pharmaceuticals are possibly present in surface- and ground-water samples at ambient concentrations less than 1 μg/L. In this report, the performance characteristics of a combined solid-phase extraction isolation and high-performance liquid chromatography–electrospray ionization mass spectrometry (HPLC–ESI-MS) analytical procedure for routine determination of the presence and concentration of human-health pharmaceuticals are described. This method was developed and used in a recent national reconnaissance of pharmaceuticals in USA surface waters. The selection of pharmaceuticals evaluated for this method was based on usage estimates, resulting in a method that contains compounds from diverse chemical classes, which presents challenges and compromises when applied as a single routine analysis. The method performed well for the majority of the 22 pharmaceuticals evaluated, with recoveries greater than 60% for 12 pharmaceuticals. The recoveries of angiotensin-converting enzyme inhibitors, a histamine (H2) receptor antagonist, and antihypoglycemic compound classes were less than 50%, but were retained in the method to provide information describing the potential presence of these compounds in environmental samples and to indicate evidence of possible matrix enhancing effects. Long-term recoveries, evaluated from reagent-water fortifications processed over 2 years, were similar to initial method performance. Method detection limits averaged 0.022 μg/L, sufficient for expected ambient concentrations. Compound-dependent matrix effects on HPLC/ESI-MS analysis, including enhancement and suppression of ionization, were observed as a 20–30% increase in measured concentrations for three compounds and greater than 50% increase for two compounds. Changing internal standard and more frequent ESI source maintenance minimized matrix effects. Application of the method in the national survey demonstrates that several

  11. Modeled ground water age distributions

    Science.gov (United States)

    Woolfenden, Linda R.; Ginn, Timothy R.

    2009-01-01

    The age of ground water in any given sample is a distributed quantity representing distributed provenance (in space and time) of the water. Conventional analysis of tracers such as unstable isotopes or anthropogenic chemical species gives discrete or binary measures of the presence of water of a given age. Modeled ground water age distributions provide a continuous measure of contributions from different recharge sources to aquifers. A numerical solution of the ground water age equation of Ginn (1999) was tested both on a hypothetical simplified one-dimensional flow system and under real world conditions. Results from these simulations yield the first continuous distributions of ground water age using this model. Complete age distributions as a function of one and two space dimensions were obtained from both numerical experiments. Simulations in the test problem produced mean ages that were consistent with the expected value at the end of the model domain for all dispersivity values tested, although the mean ages for the two highest dispersivity values deviated slightly from the expected value. Mean ages in the dispersionless case also were consistent with the expected mean ages throughout the physical model domain. Simulations under real world conditions for three dispersivity values resulted in decreasing mean age with increasing dispersivity. This likely is a consequence of an edge effect. However, simulations for all three dispersivity values tested were mass balanced and stable demonstrating that the solution of the ground water age equation can provide estimates of water mass density distributions over age under real world conditions.

  12. Pesticides in Ground Water

    DEFF Research Database (Denmark)

    Bjerg, Poul Løgstrup

    1996-01-01

    Review af: Jack E. Barbash & Elizabeth A. Resek (1996). Pesticides in Ground Water. Distribution trends and governing factors. Ann Arbor Press, Inc. Chelsea, Michigan. pp 588.......Review af: Jack E. Barbash & Elizabeth A. Resek (1996). Pesticides in Ground Water. Distribution trends and governing factors. Ann Arbor Press, Inc. Chelsea, Michigan. pp 588....

  13. Pesticides in Ground Water

    DEFF Research Database (Denmark)

    Bjerg, Poul Løgstrup

    1996-01-01

    Review af: Jack E. Barbash & Elizabeth A. Resek (1996). Pesticides in Ground Water. Distribution trends and governing factors. Ann Arbor Press, Inc. Chelsea, Michigan. pp 588.......Review af: Jack E. Barbash & Elizabeth A. Resek (1996). Pesticides in Ground Water. Distribution trends and governing factors. Ann Arbor Press, Inc. Chelsea, Michigan. pp 588....

  14. [Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio]. Volume 3, Appendix A, Draft standard operating procedures and elements: Sampling and Analysis Plan (SAP): Phase 1, Task 4, Field Investigation, Draft

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    This report presents information concerning field procedures employed during the monitoring, well construction, well purging, sampling, and well logging at the Wright-Patterson Air Force Base. Activities were conducted in an effort to evaluate ground water contamination.

  15. Dissolution actuated sample container

    Science.gov (United States)

    Nance, Thomas A.; McCoy, Frank T.

    2013-03-26

    A sample collection vial and process of using a vial is provided. The sample collection vial has an opening secured by a dissolvable plug. When dissolved, liquids may enter into the interior of the collection vial passing along one or more edges of a dissolvable blocking member. As the blocking member is dissolved, a spring actuated closure is directed towards the opening of the vial which, when engaged, secures the vial contents against loss or contamination.

  16. Jeju ground water containing vanadium induced immune activation on splenocytes of low dose γ-rays-irradiated mice.

    Science.gov (United States)

    Ha, Danbee; Joo, Haejin; Ahn, Ginnae; Kim, Min Ju; Bing, So Jin; An, Subin; Kim, Hyunki; Kang, Kyung-goo; Lim, Yoon-Kyu; Jee, Youngheun

    2012-06-01

    Vanadium, an essential micronutrient, has been implicated in controlling diabetes and carcinogenesis and in impeding reactive oxygen species (ROS) generation. γ-ray irradiation triggers DNA damage by inducing ROS production and causes diminution in radiosensitive immunocytes. In this study, we elucidate the immune activation capacities of Jeju water containing vanadium on immunosuppression caused by γ-ray irradiation, and identify its mechanism using various low doses of NaVO(3). We examined the intracellular ROS generation, DNA damage, cell proliferation, population of splenocytes, and cytokine/antibody profiles in irradiated mice drinking Jeju water for 180 days and in non-irradiated and in irradiated splenocytes both of which were treated with NaVO(3). Both Jeju water and 0.245 μM NaVO(3) attenuated the intracellular ROS generation and DNA damage in splenocytes against γ-ray irradiation. Splenocytes were significantly proliferated by the long-term intake of Jeju water and by 0.245 μM NaVO(3) treatment, and the expansion of B cells accounted for the increased number of splenocytes. Also, 0.245 μM NaVO(3) treatment showed the potency to amplify the production of IFN-γ and total IgG in irradiated splenocytes, which correlated with the expansion of B cells. Collectively, Jeju water containing vanadium possesses the immune activation property against damages caused by γ-irradiation.

  17. Characterization of Climax granite ground water

    Energy Technology Data Exchange (ETDEWEB)

    Isherwood, D.; Harrar, J.; Raber, E.

    1982-08-01

    The Climax ground water fails to match the commonly held views regarding the nature of deep granitic ground waters. It is neither dilute nor in equilibrium with the granite. Ground-water samples were taken for chemical analysis from five sites in the fractured Climax granite at the Nevada Test Site. The waters are high in total dissolved solids (1200 to 2160 mg/L) and rich in sodium (56 to 250 mg/L), calcium (114 to 283 mg/L) and sulfate (325 to 1060 mg/L). Two of the samples contained relatively high amounts of uranium (1.8 and 18.5 mg/L), whereas the other three contained uranium below the level of detection (< 0.1 mg/L). The pH is in the neutral range (7.3 to 8.2). The differences in composition between samples (as seen in the wide range of values for the major constituents and total dissolved solids) suggest the samples came from different, independent fracture systems. However, the apparent trend of increasing sodium with depth at the expense of calcium and magnesium suggests a common evolutionary chemical process, if not an interconnected system. The waters appear to be less oxidizing with depth (+ 410 mV at 420 m below the surface vs + 86 mV at 565 m). However, with Eh measurements on only two samples, this correlation is questionable. Isotopic analyses show that the waters are of meteoric origin and that the source of the sulfate is probably the pyrite in the fracture-fill material. Analysis of the measured water characteristics using the chemical equilibrium computer program EQ3 indicates that the waters are not in equilibrium with the local mineral assemblage. The solutions appear to be supersaturated with respect to the mineral calcite, quartz, kaolinite, muscovite, k-feldspar, and many others.

  18. Radon determination in ground water

    Energy Technology Data Exchange (ETDEWEB)

    Segovia A, N.; Bulbulian G, S

    1991-08-15

    Studies on natural radioactivity in ground water were started in Mexico in San Luis Potosi state followed by samplings from deep wells and springs in the states of Mexico and Michoacan. The samples were analyzed for solubilized and {sup 226} Ra- supported {sup 222} Rn. Some of them were also studied for {sup 234} U/ {sup 238} U activity ratio. In this paper we discuss the activities obtained and their relationship with the geologic characteristics of the studied zones. (Author)

  19. Report: Independent Ground Water Sampling Generally Confirms EPA’s Data at Wheeler Pit Superfund Site in Wisconsin

    Science.gov (United States)

    Report #10-P-0218, September 8, 2010. With minimal exceptions, our independent sampling results at the Wheeler Pit Superfund Site were consistent with the sampling results that EPA Region 5 has obtained historically.

  20. Comparative Study of Sampling Methods in Ground Water%地下水采样方法比对研究

    Institute of Scientific and Technical Information of China (English)

    李文攀; 朱擎; 嵇晓燕; 刘廷良; 孙宗光

    2016-01-01

    In this paper, three kinds of groundwater sampling are comparatively analyzed. Through systematically analyzes of the monitoring data, the significant differences in basic parameters, ions, metals, VOCs and, Sensory indexes of water sampling from the three methods are presented, and proposed the applicability of different methods. The results indicate that, the low⁃flow sampling,as compared to traditional methods, can effectively solve aeration in the sampling process, reduce the sample turbidity with small disturbance, minimize drawdown of the water table, avoid cross contamination resulting from mixing of different formation water with stagnant water in the well, save field time and eliminate sewage treatment costs associated with well purging and sampling. The Low⁃Flow sampling method is more advantage in taking representative samples.%选取3种地下水采样方法开展方法比对研究。通过系统分析监测数据,指出了3种方法所采水样在基本水质参数、无机离子、金属、挥发性有机物以及感官类指标等项目监测上的显著差异,指出了各种方法的适用性并分析原因。结果表明:与贝勒管法、潜水泵法相比,低流速法有效地解决了采样操作过程中易产生的曝气问题;对井内水体扰动较小,降低了水样浊度;减小了井内水位的大幅度泄降,避免了不同层位间污染物的迁移及周边水和井内滞水的交叉污染;节约了场地操作时间和后期污水处理所需花费。因此,低流速法在采取代表性水质样品方面更具方法优势。

  1. 40 CFR Appendix Ix to Part 264 - Ground-Water Monitoring List

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Ground-Water Monitoring List IX... Pt. 264, App. IX Appendix IX to Part 264—Ground-Water Monitoring List Ground-Water Monitoring List... species in the ground water that contain this element are included. 3 CAS index names are those used in...

  2. Ground Water Quality of Selected Wells

    Directory of Open Access Journals (Sweden)

    Mosher R. Ahmed

    2013-05-01

    Full Text Available In order to characterize ground water quality in Zaweta district / Dohuk governorate, eight wells are selected to represent their water quality. Monthly samples are collected from the wells for the period from October 2005 to April 2006. The samples are tested for conductivity, total dissolved solids, pH, total hardness, chloride, alkalinity and nitrate according to the standard methods. The results of statistical analysis showed significant difference among the wells water quality in the measured parameters. Ground water quality of Zaweta district has high dissolved ions due to the nature of studied area rocks. Total dissolved solids of more than 1000 mg/l made the wells Gre-Qassroka, Kora and Swaratoka need to be treated to make taste palatable. Additionally high electrical conductivity and TDS made Zaweta ground water have a slight to moderate restriction to crop growth. The high alkalinity of Zaweta ground water indicated stabilized pH. The water quality of all the wells is found excessively hard. The nitrate concentration of Zaweta ground water ranged between 0.19-42.4 mg/l below the guidelines for WHO and the maximum nitrate concentration is recorded in Kora well .

  3. Artificial recharge of humic ground water.

    Science.gov (United States)

    Alborzfar, M; Villumsen, A; Grøn, C

    2001-01-01

    The purpose of this study was to investigate the efficiency of soil in removing natural organic matter from humic ground waters using artificial recharge. The study site, in western Denmark, was a 10,000 ml football field of which 2,000 m2 served as an infiltration field. The impact of the artificial recharge was studied by monitoring the water level and the quality of the underlying shallow aquifer. The humic ground water contained mainly humic adds with an organic carbon (OC) concentration of 100 to 200 mg C L(-1). A total of 5,000 mS of humic ground water were sprinkled onto the infiltration field at an average rate of 4.25 mm h(-1). This resulted in a rise in the water table of the shallow aquifer. The organic matter concentration of the water in the shallow aquifer, however, remained below 2.7 mg C L(-1). The organic matter concentration of the pore water in the unsaturated zone was measured at the end of the experiment. The organic matter concentration of the pore water decreased from 105 mg C L(-1) at 0.5 m to 20 mg C L(-1) at 2.5 m under the infiltration field indicating that the soil removed the organic matter from the humic ground water. From these results we conclude that artificial recharge is a possible method for humic ground water treatment.

  4. Ground water and climate change

    NARCIS (Netherlands)

    Taylor, R.G.; Scanlon, B.; Döll, P.; Rodell, M.; Beek, R. van; Wada, Y.; Longuevergne, L.; Leblanc, M.; Famiglietti, J.S.; Edmunds, M.; Konikow, L.; Green, T.R.; Chen, J.; Taniguchi, M.; Bierkens, M.F.P.; MacDonald, A.; Fan, Y.; Maxwell, R.M.; Yechieli, Y.; Gurdak, J.J.; Allen, D.M.; Shamsudduha, M.; Hiscock, K.; Yeh, Pat J.-F.; Holman, Ian; Treidel, Holger

    2012-01-01

    As the world’s largest distributed store of fresh water, ground water plays a central part in sustaining ecosystems and enabling human adaptation to climate variability and change. The strategic importance of ground water for global water and food security will probably intensify under climate chang

  5. Ground water and climate change

    NARCIS (Netherlands)

    Taylor, R.G.; Scanlon, B.; Döll, P.; Rodell, M.; Beek, R. van; Wada, Y.; Longuevergne, L.; Leblanc, M.; Famiglietti, J.S.; Edmunds, M.; Konikow, L.; Green, T.R.; Chen, J.; Taniguchi, M.; Bierkens, M.F.P.; MacDonald, A.; Fan, Y.; Maxwell, R.M.; Yechieli, Y.; Gurdak, J.J.; Allen, D.M.; Shamsudduha, M.; Hiscock, K.; Yeh, Pat J.-F.; Holman, Ian; Treidel, Holger

    2012-01-01

    As the world’s largest distributed store of fresh water, ground water plays a central part in sustaining ecosystems and enabling human adaptation to climate variability and change. The strategic importance of ground water for global water and food security will probably intensify under climate

  6. Installation-Restoration Program Stage 3. McClellan AFB, California. Remedial investigation/feasibility study ground-water sampling and analysis program, January through March 1989 data summary. Final report, January-March 1989

    Energy Technology Data Exchange (ETDEWEB)

    1989-06-19

    This Data Summary presents the results of ground-water sampling activities conducted on and in the vicinity of McClellan Air Force Base from the sampling period of January through March, 1989. Concentrations of purgeable halocarbons and aromatic compounds detected in 336 wells 26 monitoring wells are located on base in Area A, B, C, D, and adjacent on-base areas and off-base in the Northwest and Southwest areas. There was no detected increase in the areal extent of contaminated ground-water, nor was there any increase in the depth that contaminated ground-water was detected. The Area D extraction system is effectively operating to change hydraulic gradients, so groundwater in Area D flows toward the extraction wells. Contaminant concentrations have decreased in Area D deep zone monitoring wells. Samples from three middle-zone monitoring wells located in Area D also show decreases in contaminant concentration during this sampling period. Decreasing contaminant concentrations have stabilized in shallow zone monitoring wells located off-base, west of Area D.

  7. Questa baseline and pre-mining ground-water quality investigation. 14. Interpretation of ground-water geochemistry in catchments other than the Straight Creek catchment, Red River Valley, Taos County, New Mexico, 2002-2003

    Science.gov (United States)

    Nordstrom, D. Kirk; McCleskey, R. Blaine; Hunt, Andrew G.; Naus, Cheryl A.

    2005-01-01

    determined on selected samples. Dissolved organic carbon (DOC), mercury, sulfate stable isotope composition (d34S and d18O of sulfate), stable isotope composition of water (d2H and d18O of water) were measured for selected samples. Chlorofluorocarbons (CFC) and 3He and 3H were measured for age dating on selected samples. Linear regressions from the Straight Creek ground-water data were used to compare ground-water chemistry trends in non-Straight Creek ground waters with Straight Creek alluvial ground-water chemistry dilution trends. Most of the solute trends for the ground waters are similar to those for Straight Creek but there are some notable exceptions. In lithologies that contain substantial pyrite mineralization, acid waters form with similar chemistries to those in Straight Creek and all the waters tend to be calcium-sulfate type. Hottentot ground waters contain substantially lower calcium concentrations relative to those in Straight Creek. This anomaly results from the exposure of rhyolite porphyry in the Hottentot scar and weathering zone. The rhyolite contains less calcium than the altered andesites and tuffs in the Straight Creek catchment and probably does not have the abundant gypsum and calcite. The Hansen ground waters have reached gypsum saturation and have similar calcium, magnesium, and beryllium concentrations as Straight Creek ground waters but have lower concentrations of fluoride, manganese, zinc, cobalt, nickel, copper, and lithium. Lower concentrations of elements related to mineralization at Hansen likely reflect the more distal location of Hansen with respect to intrusive centers that provided the heat source for hydrothermal alteration. The other ground water with water chemistry trends that are outside the Straight Creek trends was from an alluvial well from Capulin Canyon (CC2A). Although it had pH values near 6.0 and most major ions similar to the other Capulin Canyon ground waters, it contained high concentrations

  8. Evaluating data worth for ground-water management under uncertainty

    Science.gov (United States)

    Wagner, B.J.

    1999-01-01

    A decision framework is presented for assessing the value of ground-water sampling within the context of ground-water management under uncertainty. The framework couples two optimization models-a chance-constrained ground-water management model and an integer-programing sampling network design model-to identify optimal pumping and sampling strategies. The methodology consists of four steps: (1) The optimal ground-water management strategy for the present level of model uncertainty is determined using the chance-constrained management model; (2) for a specified data collection budget, the monitoring network design model identifies, prior to data collection, the sampling strategy that will minimize model uncertainty; (3) the optimal ground-water management strategy is recalculated on the basis of the projected model uncertainty after sampling; and (4) the worth of the monitoring strategy is assessed by comparing the value of the sample information-i.e., the projected reduction in management costs-with the cost of data collection. Steps 2-4 are repeated for a series of data collection budgets, producing a suite of management/monitoring alternatives, from which the best alternative can be selected. A hypothetical example demonstrates the methodology's ability to identify the ground-water sampling strategy with greatest net economic benefit for ground-water management.A decision framework is presented for assessing the value of ground-water sampling within the context of ground-water management under uncertainty. The framework couples two optimization models - a chance-constrained ground-water management model and an integer-programming sampling network design model - to identify optimal pumping and sampling strategies. The methodology consists of four steps: (1) The optimal ground-water management strategy for the present level of model uncertainty is determined using the chance-constrained management model; (2) for a specified data collection budget, the monitoring

  9. HANFORD SITE ENVIRONMENTAL DATA FOR CALENDAR YEAR 1989 - GROUND WATER

    Energy Technology Data Exchange (ETDEWEB)

    Bryce, R. W.; Gorst, W. R.

    1990-12-01

    In a continuing effort for the U.S. Department of Energy, Pacific Northwest Laboratory (PNL) is conducting ground-water monitoring at the Hanford Site, near Richland, Washington. This document contains the data listing of monitoring results obtained by PNL and Westinghouse Hanford Company during the period January through December 1989. Samples taken during 1989 were analyzed and reported by United States Testing Company, Inc., Richland, Washington. The data listing contains all chemical results (above contractual reporting limits) and radiochemical results (for which the result is larger than two times the total error).

  10. Questa baseline and pre-mining ground-water quality investigation. 5. Well installation, water-level data, and surface- and ground-water geochemistry in the Straight Creek drainage basin, Red River Valley, New Mexico, 2001-03

    Science.gov (United States)

    Naus, Cheryl A.; McCleskey, R. Blaine; Nordstrom, D. Kirk; Donohoe, Lisa C.; Hunt, Andrew G.; Paillet, Frederick L.; Morin, Roger H.; Verplanck, Philip L.

    2005-01-01

    The U.S. Geological Survey, in cooperation with the New Mexico Environment Department, is investigating the pre-mining ground-water chemistry at the Molycorp molybdenum mine in the Red River Valley, northern New Mexico. The primary approach is to determine the processes controlling ground-water chemistry at an unmined, off-site, proximal analog. The Straight Creek drainage basin, chosen for this purpose, consists of the same quartz-sericite-pyrite altered andesitic and rhyolitic volcanic rock of Tertiary age as the mine site. The weathered and rugged volcanic bedrock surface is overlain by heterogeneous debris-flow deposits that interfinger with alluvial deposits near the confluence of Straight Creek and the Red River. Pyritized rock in the upper part of the drainage basin is the source of acid rock drainage (pH 2.8-3.3) that infiltrates debris-flow deposits containing acidic ground water (pH 3.0-4.0) and bedrock containing water of circumneutral pH values (5.6-7.7). Eleven observation wells were installed in the Straight Creek drainage basin. The wells were completed in debris-flow deposits, bedrock, and interfingering debris-flow and Red River alluvial deposits. Chemical analyses of ground water from these wells, combined with chemical analyses of surface water, water-level data, and lithologic and geophysical logs, provided information used to develop an understanding of the processes contributing to the chemistry of ground water in the Straight Creek drainage basin. Surface- and ground-water samples were routinely collected for determination of total major cations and selected trace metals; dissolved major cations, selected trace metals, and rare-earth elements; anions and alkalinity; and dissolved-iron species. Rare-earth elements were determined on selected samples only. Samples were collected for determination of dissolved organic carbon, mercury, sulfur isotopic composition (34S and 18O of sulfate), and water isotopic composition (2H and 18O) during

  11. Nutrient Enrichment in Estuaries from Discharge of Shallow Ground Water, Mt. Desert Island, Maine

    Science.gov (United States)

    Culbertson, Charles W.; Huntington, Thomas G.; Caldwell, James M.

    2007-01-01

    Nutrient enrichment from atmospheric deposition, agricultural activities, wildlife, and domestic sources is a concern at Acadia National Park because of the potential problem of water-quality degradation and eutrophication in its estuaries. Water-quality degradation has been observed at the Park?s Bass Harbor Marsh estuary but not in Northeast Creek estuary. Previous studies at Acadia National Park have estimated nutrient inputs to estuaries from atmospheric deposition and surface-water runoff, but the importance of shallow ground water that may contain nutrients derived from domestic or other sources is unknown. Northeast Creek and Bass Harbor Marsh estuaries were studied to (1) identify shallow ground-water seeps, (2) assess the chemistry of the water discharged from selected seeps, and (3) assess the chemistry of ground water in shallow ground-water hyporheic zones. The hyporheic zone is defined here as the region beneath and lateral to a stream bed, where there is mixing of shallow ground water and surface water. This study also provides baseline chemical data for ground water in selected bedrock monitoring wells and domestic wells on Mt. Desert Island. Water samples were analyzed for concentrations of nutrients, wastewater compounds, dissolved organic carbon, pH, dissolved oxygen, temperature and specific conductance. Samples from bedrock monitoring wells also were analyzed for alkalinity, major cations and anions, and trace metals. Shallow ground-water seeps to Northeast Creek and Bass Harbor Marsh estuaries at Acadia National Park were identified and georeferenced using aerial infrared digital imagery. Monitoring included the deployment of continuously recording temperature and specific conductance sensors in the seep discharge zone to access marine or freshwater signatures related to tidal flooding, gradient-driven shallow ground-water flow, or shallow subsurface flow related to precipitation events. Many potential shallow ground-water discharge zones were

  12. Ground water and climate change

    Science.gov (United States)

    Taylor, Richard G.; Scanlon, Bridget; Döll, Petra; Rodell, Matt; van Beek, Rens; Wada, Yoshihide; Longuevergne, Laurent; Leblanc, Marc; Famiglietti, James S.; Edmunds, Mike; Konikow, Leonard; Green, Timothy R.; Chen, Jianyao; Taniguchi, Makoto; Bierkens, Marc F.P.; MacDonald, Alan; Fan, Ying; Maxwell, Reed M.; Yechieli, Yossi; Gurdak, Jason J.; Allen, Diana M.; Shamsudduha, Mohammad; Hiscock, Kevin; Yeh, Pat J.-F.; Holman, Ian; Treidel, Holger

    2012-01-01

    As the world's largest distributed store of fresh water, ground water plays a central part in sustaining ecosystems and enabling human adaptation to climate variability and change. The strategic importance of ground water for global water and food security will probably intensify under climate change as more frequent and intense climate extremes (droughts and floods) increase variability in precipitation, soil moisture and surface water. Here we critically review recent research assessing the impacts of climate on ground water through natural and human-induced processes as well as through groundwater-driven feedbacks on the climate system. Furthermore, we examine the possible opportunities and challenges of using and sustaining groundwater resources in climate adaptation strategies, and highlight the lack of groundwater observations, which, at present, limits our understanding of the dynamic relationship between ground water and climate.

  13. Ground water and climate change

    Science.gov (United States)

    Taylor, Richard G.; Scanlon, Bridget; Döll, Petra; Rodell, Matt; van Beek, Rens; Wada, Yoshihide; Longuevergne, Laurent; Leblanc, Marc; Famiglietti, James S.; Edmunds, Mike; Konikow, Leonard; Green, Timothy R.; Chen, Jianyao; Taniguchi, Makoto; Bierkens, Marc F. P.; MacDonald, Alan; Fan, Ying; Maxwell, Reed M.; Yechieli, Yossi; Gurdak, Jason J.; Allen, Diana M.; Shamsudduha, Mohammad; Hiscock, Kevin; Yeh, Pat J.-F.; Holman, Ian; Treidel, Holger

    2013-04-01

    As the world's largest distributed store of fresh water, ground water plays a central part in sustaining ecosystems and enabling human adaptation to climate variability and change. The strategic importance of ground water for global water and food security will probably intensify under climate change as more frequent and intense climate extremes (droughts and floods) increase variability in precipitation, soil moisture and surface water. Here we critically review recent research assessing the impacts of climate on ground water through natural and human-induced processes as well as through groundwater-driven feedbacks on the climate system. Furthermore, we examine the possible opportunities and challenges of using and sustaining groundwater resources in climate adaptation strategies, and highlight the lack of groundwater observations, which, at present, limits our understanding of the dynamic relationship between ground water and climate.

  14. Ground Water and Climate Change

    Science.gov (United States)

    Taylor, Richard G.; Scanlon, Bridget; Doell, Petra; Rodell, Matt; van Beek, Rens; Wada, Yoshihide; Longuevergne, Laurent; Leblanc, Marc; Famiglietti, James S.; Edmunds, Mike; Konikow, Leonard; Green, Timothy R.; Chen, Jianyao; Taniguchi, Makoto; Bierkens, Marc F. P.; MacDonald, Alan; Fan, Ying; Maxwell, Reed M.; Yechieli, Yossi; Gurdak, Jason J.; Allen, Diana M.; Shamsudduha, Mohammad; Hiscock, Kevin; Yeh, Pat J. -F; Holman, Ian; Treidel, Holger

    2013-01-01

    As the world's largest distributed store of fresh water, ground water plays a central part in sustaining ecosystems and enabling human adaptation to climate variability and change. The strategic importance of ground water for global water and food security will probably intensify under climate change as more frequent and intense climate extremes (droughts and floods) increase variability in precipitation, soil moisture and surface water. Here we critically review recent research assessing the impacts of climate on ground water through natural and human-induced processes as well as through groundwater-driven feedbacks on the climate system. Furthermore, we examine the possible opportunities and challenges of using and sustaining groundwater resources in climate adaptation strategies, and highlight the lack of groundwater observations, which, at present, limits our understanding of the dynamic relationship between ground water and climate.

  15. Ground-water provinces of southern Rhodesia

    Science.gov (United States)

    Dennis, Philip Eldon; Hindson, L.L.

    1964-01-01

    Ground-water development, utilization, and occurrence in nine ground-water provinces of Southern Rhodesia are summarized in this report. Water obtained from drilled wells for domestic and stock use has played an important part in the social and economic development of Southern Rhodesia from the beginnings of European settlement to the present. Most of the wells obtain water from fractures and weathered zones in crystalline rocks, before recently, there has been an interest in the possibility of obtaining water for irrigation from wells. Studies of the authors indicate that quantities of water sufficient for irrigation can be obtained from alluvial sediments in the S'abi Valley, from Kalahari sands in the western part of the country, are perhaps from aquifers in other areas. The ground-water provinces fall into two groups--those in the crystalline rocks and those in the noncrystalline rocks. Historically, the wells in crystalline rocks, especially the Gold belts province and the Intrusive granites province, have played a major role in supplying water for the needs of man. These provinces, together with two other less important crystalline rock provinces, form the broad arch which constitutes the central core of the country. The noncrystalline rocks overlie and flank the crystalline rocks to the southeast, northwest, and north. The noncrystalline rock provinces, especially the Alluvium-Kalahari province, contain the most productive or potentially productive ground-water reservoirs in Southern Rhodesia and offer promise of supplying water for irrigation and for other purposes.

  16. Effect of pesticide use in fruit production orchards on shallow ground water.

    Science.gov (United States)

    Loewy, R M; Carvajal, L G; Novelli, M; de D'Angelo, A M Pechen

    2003-05-01

    As a part of landscape-scale study, ground water samples were collected from 30 wells located in fruit production farms belonging to the valley of Neuquen river during the period 1995-1998 and analyzed for organophosphate pesticides. As a consequence of the leaching process, ground water from the Valley of Neuquen River frequently contained concentrations of organophosphorus pesticides that exceeded acute toxicity risk ratios established to protect aquatic life. It was found that some pesticides, as azinphos methyl, had a high detection frequency, 66% of the samples, with concentrations varying from no detection to 48.9 ppb. Dimethoate, metidathion and phosmet were also detected with frequencies of 14.1, 13.6 and 10.8% and with concentration ranks from no detection to a maximum value of 10.9, 2.0 and 15.5 ppb, respectively. Seasonal variations and temporal trends were found for these compounds in ground water.

  17. Ground-water surveillance at the Hanford Site for CY 1983

    Energy Technology Data Exchange (ETDEWEB)

    Prater, L.S.; Rieger, J.T.; Cline, C.S.; Jensen, E.J.; Liikala, T.L.; Oster, K.R.

    1984-07-01

    Operations at the Hanford Site have resulted in the discharge of large volumes of process cooling water and other waste waters to the ground. These effluents contain low level of radioactive and chemical substances. During 1983, 328 monitoring wells were sampled at various times for radioactive and chemical constituents. Three of these constituents, specifically tritium, nitrate, and gross beta activity, were selected for detailed discussion in this report because they are more readily transported in the ground water than some of the other constituents. Transport of these constituents in the ground water has resulted in the formation of plumes that can be mapped by contouring the analytical data obtained from the monitoring wells. This report describes recent changes in the configuration of the tritium, nitrate and gross beta plumes. Changes or trends in contaminant levels in wells located within both the main plumes (originating from the 200 Areas) and the smaller plumes are discussed in this report. Two potential pathways for radionuclide transport from the ground water to the environmental are discussed in this report, and the radiological impacts are examined. In addition to describing the present status of the ground water beneath the Hanford Site, this report contains the results of studies conducted in support of the ground-water surveillance effort during CY 1983. 21 references, 26 figures, 5 tables.

  18. Organic contamination of ground water at Gas Works Park, Seattle, Washington

    Science.gov (United States)

    Turney, G.L.; Goerlitz, D.F.

    1990-01-01

    Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water. Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large.

  19. Ground-water monitoring sites for Carson Valley, Nevada

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set contains the monitoring sites where water levels were collected and used to develop a spatial ground-water data base in Carson Valley, west-central...

  20. Procedures for ground-water investigations

    Energy Technology Data Exchange (ETDEWEB)

    1989-09-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water investigations are carried out to fulfill the requirements for the US Department of Energy (DOE) to meet the requirements of DOE Orders. Investigations are also performed for various clients to meet the requirements of the Resource Conservation and Recovery Act of 1976 (RCRA) and the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA). National standards including procedures published by the American Society for Testing and Materials (ASTM) and the US Geological Survey were utilized in developing the procedures contained in this manual.

  1. Shallow ground-water quality beneath rice areas in the Sacramento Valley, California, 1997

    Science.gov (United States)

    Dawson, Barbara J.

    2001-01-01

    , and non-agricultural purposes. All pesticide concentrations were below state and federal 2000 drinking-water standards. The relation of the ground-water quality to natural processes and human activities was tested using statistical methods (Spearman rank correlation, Kruskal?Wallis, or rank-sum tests) to determine whether an influence from rice land-use or other human activities on ground-water chemistry could be identified. The detection of pesticides in 89 percent of the wells sampled indicates that human activities have affected shallow ground-water quality. Concentrations of dissolved solids and inorganic constituents that exceeded state or federal 2000 drinking-water standards showed a statistical relation to geomorphic unit. This is interpreted as a relation to natural processes and variations in geology in the Sacramento River Basin; the high concentrations of dissolved solids and most inorganic constituents did not appear to be related to rice land use. No correlation was found between nitrate concentration and pesticide occurrence, indicating that an absence of high nitrate concentrations is not a predictor of an absence of pesticide contamination in areas with reducing ground-water conditions in the Sacramento Valley. Tritium concentrations, pesticide detections, stable isotope data, and dissolved-solids concentrations suggest that shallow ground water in the ricegrowing areas of the Sacramento Valley is a mix of recently recharged ground water containing pesticides, nitrate, and tritium, and unknown sources of water that contains high concentrations of dissolved solids and some inorganic constituents and is enriched in oxygen-18. Evaporation of applied irrigation water, which leaves behind salt, accounts for some of the elevated concentrations of dissolved solids. More work needs to be done to understand the connections between the land surface, shallow ground water, deep ground water, and the drinking-water supplies in the Sacramento Valley.

  2. Relationship between precipitation quality, shallow ground-water geochemistry, and dissolved aluminum in eastern Maryland. Final report, November 1983-April 1985

    Energy Technology Data Exchange (ETDEWEB)

    Bachman, L.J.; Katz, B.G.

    1986-04-01

    Precipitation, surface water, and shallow ground-water samples were collected in eastern Maryland to determine if acidic precipitation is affecting the chemical quality of water in the Columbia aquifer--an unconsolidated sand and gravel deposit. Thirty-eight water samples were collected from 11 wells, and 9 samples from 3 stream sites between February and June 1984. Ground-water and surface-water samples contained chemical species with significantly different concentration from those of precipitation. Ground-water samples were enriched with bicarbonate, silica, potassium, chloride, and sulfate and had lower hydrogen-ion concentrations than precipitation. Dissolved aluminum in most of the other ground-water samples was at or near the detection limit of 0.01 mg/l.

  3. Ground-Water Temperature, Noble Gas, and Carbon Isotope Data from the Espanola Basin, New Mexico

    Science.gov (United States)

    Manning, Andrew H.

    2009-01-01

    Ground-water samples were collected from 56 locations throughout the Espanola Basin and analyzed for general chemistry (major ions and trace elements), carbon isotopes (delta 13C and 14C activity) in dissolved inorganic carbon, noble gases (He, Ne, Ar, Kr, Xe, and 3He/4He ratio), and tritium. Temperature profiles were measured at six locations in the southeastern part of the basin. Temperature profiles suggest that ground water generally becomes warmer with distance from the mountains and that most ground-water flow occurs at depths 50 years old, consistent with the 14C ages. Terrigenic He (Heterr) concentrations in ground water are high (log Delta Heterr of 2 to 5) throughout much of the basin. High Heterr concentrations are probably caused by in situ production in the Tesuque Formation from locally high concentrations of U-bearing minerals (Northeast zone only), or by upward diffusive/advective transport of crustal- and mantle-sourced He possibly enhanced by basement piercing faults, or by both. The 3He/4He ratio of Heterr (Rterr) is commonly high (Rterr/Ra of 0.3-2.0, where Ra is the 3He/4He ratio in air) suggesting that Espanola Basin ground water commonly contains mantle-sourced He. The 3He/4He ratio of Heterr is generally the highest in the western and southern parts of the basin, closest to the western border fault system and the Quaternary to Miocene volcanics of the Jemez Mountains and Cerros del Rio.

  4. Ground water recharge and flow characterization using multiple isotopes.

    Science.gov (United States)

    Chowdhury, Ali H; Uliana, Matthew; Wade, Shirley

    2008-01-01

    Stable isotopes of delta(18)O, delta(2)H, and (13)C, radiogenic isotopes of (14)C and (3)H, and ground water chemical compositions were used to distinguish ground water, recharge areas, and possible recharge processes in an arid zone, fault-bounded alluvial aquifer. Recharge mainly occurs through exposed stream channel beds as opposed to subsurface inflow along mountain fronts. This recharge distribution pattern may also occur in other fault-bounded aquifers, with important implications for conceptualization of ground water flow systems, development of ground water models, and ground water resource management. Ground water along the mountain front near the basin margins contains low delta(18)O, (14)C (percent modern carbon [pmC]), and (3)H (tritium units [TU]), suggesting older recharge. In addition, water levels lie at greater depths, and basin-bounding faults that locally act as a flow barrier may further reduce subsurface inflow into the aquifer along the mountain front. Chemical differences in ground water composition, attributed to varying aquifer mineralogy and recharge processes, further discriminate the basin-margin and the basin-center water. Direct recharge through the indurated sandstones and mudstones in the basin center is minimal. Modern recharge in the aquifer is mainly through the broad, exposed stream channel beds containing coarse sand and gravel where ground water contains higher delta(18)O, (14)C (pmC), and (3)H (TU). Spatial differences in delta(18)O, (14)C (pmC), and (3)H (TU) and occurrences of extensive mudstones in the basin center suggest sluggish ground water movement, including local compartmentalization of the flow system.

  5. Comparison between agricultural and urban ground-water quality in the Mobile River Basin

    Science.gov (United States)

    Robinson, James L.

    2003-01-01

    . Samples from 8 of the agricultural wells and all 30 urban wells were age dated using analyses of chlorofluorocarbon, sulfur hexafluoride, and dissolved gases. Ground water sampled from the agricultural wells ranged in age from about 14 to 34 years, with a median age of about 18.5 years. Ground water sampled from the urban wells ranged in age from about 1 to 45 years, with a median age of about 12 years. The ages estimated for the ground water are consistent with the geology and hydrology of the study area and the design of the wells. All of the agricultural and urban wells sampled for this study produce water from the shallow aquifer that overlies and recharges the Black Warrior River aquifer, or from the uppermost unit of the Black Warrior River aquifer. The wells are located in the same physiographic setting, have similar depths, and the water collected from the wells had a similar range in age. Statistically significant differences in ground-water quality beneath the agricultural and urban areas can reasonably be attributed to the effects of land use. Ground water from the agricultural wells typically had acidic pH values and low specific conductance and alkalinity values. The water contained few dissolved solids, and typically had small concentrations of ions. Some of the agricultural ground-water contained concentrations of ammonia, nitrite plus nitrate, phosphorus, orthophosphate, and dissolved organic carbon in concentrations that exceeded those typically found in ground water. Pesticides were detected in ground water collected from 25 of the 29 agricultural wells. Nineteen different pesticide compounds were detected a total of 83 times. Herbicides were the most frequently detected class of pesticides. The greatest concentration of any pesticide was an estimated value of 1.4 microgram per liter of fluometuron. The Wilcoxan rank sum test was used to determine statistically significant differences in water quality between the agricultural and urba

  6. Ground-water quality in the central part of the Passaic River basin, northeastern New Jersey, 1959-88

    Science.gov (United States)

    Czarnik, T.S.; Kozinski, Jane

    1994-01-01

    Ground-water samples were collected from 71 wells screened in or open to three aquifers in the central part of the Passaic River basin during 1959-88. Water samples from aquifers in glacial sediments and aquifers in sedimentary and igneous bedrock of the Newark Supergroup were analyzed for major ions. Most samples were analyzed for metals, nutrients, and tritium; 38 samples were analyzed for purgeable organic compounds. Calcium and bicarbonate were the predominant ions in ground water in the study area. Ground water was dilute (median dissolved-solids concentration 239 milligrams per liter) and slightly basic (median pH 7.89). Concentrations of inorganic constituents were within U.S. Environmental Protection Agency (USEPA) primary drinking-water regulations. Concentrations of benzene, tetrachloroethylene, and trichloroethylene, however, were greater than USEPA primary drinking-water regulations in six samples. Ground-water samples from aquifers in sedimentary bedrock were enriched in barium, calcium, magnesium, strontium,and sulfate relative to samples form the other aquifers. Such ion enrichment can be attributed either to disolution of carbonate and sulfate-containing minerals or to human activities. Ground-water samples from two wells screened in glacial sediments near swamps contained sulfate in concentrations higher than the median for the aquifer. Sulfate enrichment could result from downward leaching of water enriched in sulfur from the decay of organic matter in the swamps, from the disolution of sulfate-containing minerals, or from human activities. No regional trends in the chemical composition of the ground water in the study area were identified. Sulfate concentrations in ground- water samples from the sedimentary bedrock tended to increase with decreasing altitude of the deepest opening of the well; the correlation coefficient for the ranks of sulfate concentration and the altitude of the deepest opening of the well for 17 pairs of data is -0

  7. Dynamic factor analysis for estimating ground water arsenic trends.

    Science.gov (United States)

    Kuo, Yi-Ming; Chang, Fi-John

    2010-01-01

    Drinking ground water containing high arsenic (As) concentrations has been associated with blackfoot disease and the occurrence of cancer along the southwestern coast of Taiwan. As a result, 28 ground water observation wells were installed to monitor the ground water quality in this area. Dynamic factor analysis (DFA) is used to identify common trends that represent unexplained variability in ground water As concentrations of decommissioned wells and to investigate whether explanatory variables (total organic carbon [TOC], As, alkalinity, ground water elevation, and rainfall) affect the temporal variation in ground water As concentration. The results of the DFA show that rainfall dilutes As concentration in areas under aquacultural and agricultural use. Different combinations of geochemical variables (As, alkalinity, and TOC) of nearby monitoring wells affected the As concentrations of the most decommissioned wells. Model performance was acceptable for 11 wells (coefficient of efficiency >0.50), which represents 52% (11/21) of the decommissioned wells. Based on DFA results, we infer that surface water recharge may be effective for diluting the As concentration, especially in the areas that are relatively far from the coastline. We demonstrate that DFA can effectively identify the important factors and common effects representing unexplained variability common to decommissioned wells on As variation in ground water and extrapolate information from existing monitoring wells to the nearby decommissioned wells.

  8. Status of ground water in the 1100 Area

    Energy Technology Data Exchange (ETDEWEB)

    Law, A.G.

    1990-12-01

    This document contains the results of monthly sampling of 1100 Area Wells and ground water monitoring. Included is a table that presents all of the results of monthly sampling and analyses between April 1989 and May 1990, for four constituents selected to be most indicative of the potential for contamination from US Department of Energy facilities. The samples were collected from the three wells near the city of Richland well field. Also included is a table that presents a listing of the analytical results from sampling and analyses of five wells between April 1989, and May 1990 in the 1100 Area. The detection limit and drinking water standards or maximum contaminant level are also listed in the tables for each constituent.

  9. Contamination of Ground Water Due To Landfill Leachate

    Directory of Open Access Journals (Sweden)

    M. V. S. Raju

    2012-12-01

    Full Text Available The present site under investigation at Ajitsingh Nagar in Vijayawada of Andhra Pradesh is initially a low lying area and used for disposing the urban solid waste for the last few years, through open dumping with out taking any measures to protect the Ground water against pollution. The present study has been taken up to measure the degree of pollution of ground water due to leachate produced in the landfill site. Bore holes were made at eight random locations to measure the depth and characteristics of solid waste. Four sampling wells were made for the collection of ground water samples and they were analyzed for various parameters. All parameters were measured based on Standard methods. It is found that the ground water is contaminated due leachates of Landfill to the large extent and is not suitable for Drinking, Domestic and Irrigation purposes.

  10. Ground-water system, estimation of aquifer hydraulic properties, and effects of pumping on ground-water flow in Triassic sedimentary rocks in and near Lansdale, Pennsylvania

    Science.gov (United States)

    Senior, Lisa A.; Goode, Daniel J.

    1999-01-01

    areas in three drainages, the Wissahickon, Towamencin, and Neshaminy Creeks.Ground-water flow was simulated for different pumping patterns representing past and current conditions. The three-dimensional numerical flow model (MODFLOW) was automatically calibrated by use of a parameter estimation program (MODFLOWP). Steady-state conditions were assumed for the calibration period of 1996. Model calibration indicates that estimated recharge is 8.2 inches (208 millimeters) and the regional anisotropy ratio for the sedimentary-rock aquifer is about 11 to 1, with permeability greatest along strike. The regional anisotropy is caused by up- and down-dip termination of high-permeability bed-oriented features, which were not explicitly simulated in the regional-scale model. The calibrated flow model was used to compare flow directions and capture zones in Lansdale for conditions corresponding to relatively high pumping rates in 1994 and to lower pumping rates in 1997. Comparison of the 1994 and 1997 simulations indicates that wells pumped at the lower 1997 rates captured less ground water from known sites of contamination than wells pumped at the 1994 rates. Ground-water flow rates away from Lansdale increased as pumpage decreased in 1997.A preliminary evaluation of the relation between ground-water chemistry and conditions favorable for the degradation of chlorinated solvents was based on measurements of dissolved-oxygen concentration and other chemical constituents in water samples from 92 wells. About 18 percent of the samples contained less than or equal to 5 milligrams per liter dissolved oxygen, a concentration that indicates reducing conditions favorable for degradation of chlorinated solvents.

  11. Identification of Naegleria fowleri in warm ground water aquifers.

    Science.gov (United States)

    Laseke, Ian; Korte, Jill; Lamendella, Regina; Kaneshiro, Edna S; Marciano-Cabral, Francine; Oerther, Daniel B

    2010-01-01

    The free-living amoeba Naegleria fowleri was identified as the etiological agent of primary amoebic meningoencephalitis that caused the deaths of two children in Peoria, Arizona, in autumn of 2002. It was suspected that the source of N. fowleri was the domestic water supply, which originates from ground water sources. In this study, ground water from the greater Phoenix Metropolitan area was tested for the presence of N. fowleri using a nested polymerase chain reaction approach. Phylogenetic analyses of 16S rRNA sequences of bacterial populations in the ground water were performed to examine the potential link between the presence of N. fowleri and bacterial groups inhabiting water wells. The results showed the presence of N. fowleri in five out of six wells sampled and in 26.6% of all ground water samples tested. Phylogenetic analyses showed that beta- and gamma-proteobacteria were the dominant bacterial populations present in the ground water. Bacterial community analyses revealed a very diverse community structure in ground water samples testing positive for N. fowleri.

  12. Ground-water contamination from lead shot at Prime Hook National Wildlife Refuge, Sussex County, Delaware

    Science.gov (United States)

    Soeder, Daniel J.; Miller, Cherie V.

    2003-01-01

    Prime Hook National Wildlife Refuge is located in southeastern Delaware in coastal lowlands along the margin of Delaware Bay. For 37 years, the Broadkiln Sportsman?s Club adjacent to the refuge operated a trap-shooting range, with the clay-target launchers oriented so that the expended lead shot from the range dropped into forested wetland areas on the refuge property. Investigators have estimated that up to 58,000 shotgun pellets per square foot are present in locations on the refuge where the lead shot fell to the ground. As part of the environmental risk assessment for the site, the U.S. Geological Survey (USGS) investigated the potential for lead contamination in ground water. Results from two sampling rounds in 19 shallow wells indicate that elevated levels of dissolved lead are present in ground water at the site. The lead and associated metals, such as antimony and arsenic (common shotgun pellet alloys), are being transported along shallow ground-water flowpaths toward an open-water slough in the forested wetland adjacent to the downrange target area. Water samples from wells located along the bank of the slough contained dissolved lead concentrations higher than 400 micrograms per liter, and as high as 1 milligram per liter. In contrast, a natural background concentration of lead from ground water in a well upgradient from the site is about 1 microgram per liter. Two water samples collected several months apart from the slough directly downgradient of the shooting range contained 24 and 212 micrograms per liter of lead, respectively. The data indicate that lead from a concentrated deposit of shotgun pellets on the refuge has been mobilized through a combination of acidic water conditions and a very sandy, shallow, unconfined aquifer, and is moving along ground-water flowpaths toward the surface-water drainage. Data from this study will be used to help delineate the lead plume, and determine the fate and transport of lead from the source area.

  13. Discussions on Ground Water Control Technologies for Tunneling in Ground Containing Rich High-pressure Water%高水压富水隧道地下水控制技术探讨

    Institute of Scientific and Technical Information of China (English)

    李治国

    2015-01-01

    During tunneling in ground containing rich high-pressure water,water inflow,mud bursting and collapse may occur due to the action the ground water,which may jeopardize the tunneling safety,the surrounding environment and even the tunnel operation.In the paper,the following two aspects are discussed on the basis of theoretical formulas, engineering cases and standards and specifications:1 )The water inflow rate and water pressure during tunneling are discussed on the basis of analysis on the ground water seepage flow rules and in the aspects of ground reinforcement and water stopping,pressure reducing under limited drainage and water pressure resistant lining;2)The classification of the drainage rate in tunneling and the control of the content of mud and sand in water and particle size are discussed and some control parameters and standards are proposed.Finally,the control of the rich high-pressure water in the construction of Zhongtianshan tunnel is presented.The paper can provide reference for similar works in the future.%高水压富水隧道施工中地下水的作用容易引发涌水突泥和坍塌,造成施工安全事故和破坏周围环境,甚至给运营带来安全隐患。文章通过理论公式、工程案例及规范规定等方面的分析,主要探讨了2方面的内容:1)通过分析地下水的渗流规律,从地层加固和止水、限排降压、抗水压衬砌等方面介绍了隧道涌水量和水压力;2)隧道排水量分级、水中泥砂含量及粒径控制问题,提出了一些控制参数和标准。并以中天山隧道为例,介绍了高水压富水区的地下水控制,促进高水压富水隧道的设计和施工水平的进一步提高,并供类似工程参考。

  14. Pushpoint sampling for defining spatial and temporal variations in contaminant concentrations in sediment pore water near the ground-water / surface-water interface

    Science.gov (United States)

    Zimmerman, Marc J.; Massey, Andrew J.; Campo, Kimberly W.

    2005-01-01

    During four periods from April 2002 to June 2003, pore-water samples were taken from river sediment within a gaining reach (Mill Pond) of the Sudbury River in Ashland, Massachusetts, with a temporary pushpoint sampler to determine whether this device is an effective tool for measuring small-scale spatial variations in concentrations of volatile organic compounds and selected field parameters (specific conductance and dissolved oxygen concentration). The pore waters sampled were within a subsurface plume of volatile organic compounds extending from the nearby Nyanza Chemical Waste Dump Superfund site to the river. Samples were collected from depths of 10, 30, and 60 centimeters below the sediment surface along two 10-meter-long, parallel transects extending into the river. Twenty-five volatile organic compounds were detected at concentrations ranging from less than 1 microgram per liter to hundreds of micrograms per liter (for example, 1,2-dichlorobenzene, 490 micrograms per liter; cis-1,2-dichloroethene, 290 micrograms per liter). The most frequently detected compounds were either chlorobenzenes or chlorinated ethenes. Many of the compounds were detected only infrequently. Quality-control sampling indicated a low incidence of trace concentrations of contaminants. Additional samples collected with passive-water-diffusion-bag samplers yielded results comparable to those collected with the pushpoint sampler and to samples collected in previous studies at the site. The results demonstrate that the pushpoint sampler can yield distinct samples from sites in close proximity; in this case, sampling sites were 1 meter apart horizontally and 20 or 30 centimeters apart vertically. Moreover, the pushpoint sampler was able to draw pore water when inserted to depths as shallow as 10 centimeters below the sediment surface without entraining surface water. The simplicity of collecting numerous samples in a short time period (routinely, 20 to 30 per day) validates the use of a

  15. Ground-water conditions in Utah, spring of 2009

    Science.gov (United States)

    Burden, Carole B.; Allen, David V.; Rowland, Ryan C.; Fisher, Martel J.; Freeman, Michael L.; Downhour, Paul; Nielson, Ashley; Eacret, Robert J.; Myers, Andrew; Slaugh, Bradley A.; Swenson, Robert L.; Howells, James H.; Christiansen, Howard K.

    2009-01-01

    This is the forty-sixth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2008. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights. utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/ GW2009.pdf.

  16. Ground-water conditions in Utah, spring of 2003

    Science.gov (United States)

    Burden, Carole B.; Enright, Michael; Danner, M.R.; Fisher, M.J.; Haraden, Peter L.; Kenney, T.A.; Wilkowske, C.D.; Eacret, Robert J.; Downhour, Paul; Slaugh, B.A.; Swenson, R.L.; Howells, J.H.; Christiansen, H.K.

    2003-01-01

    This is the fortieth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2002. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

  17. Ground-water conditions in Utah, spring of 2002

    Science.gov (United States)

    Burden, Carole B.; Enright, Michael; Danner, M.R.; Fisher, M.J.; Haraden, Peter L.; Kenney, T.A.; Wilkowske, C.D.; Eacret, Robert J.; Downhour, Paul; Slaugh, B.A.; Swenson, R.L.; Howells, J.H.; Christiansen, H.K.

    2002-01-01

    This is the thirty-ninth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2001. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

  18. Ground-water conditions in Utah, spring of 2008

    Science.gov (United States)

    Burden, Carole B.; Allen, David V.; Danner, M.R.; Fisher, Martel J.; Freeman, Michael L.; Downhour, Paul; Wilkowske, C.D.; Eacret, Robert J.; Enright, Michael; Swenson, Robert L.; Howells, James H.; Christiansen, Howard K.

    2008-01-01

    This is the forty-fifth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2007. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/GW2008.pdf.

  19. Ground-water conditions in Utah, spring of 2007

    Science.gov (United States)

    Burden, Carole B.; Allen, David V.; Danner, M.R.; Enright, Michael; Cillessen, J.L.; Gerner, S.J.; Eacret, Robert J.; Downhour, Paul; Slaugh, Bradley A.; Swenson, Robert L.; Howells, James H.; Christiansen, Howard K.; Fisher, Martel J.

    2007-01-01

    This is the forty-fourth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions.This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available.This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2006. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah. gov/ and http://ut.water.usgs.gov/newUTAH/GW2007.pdf.

  20. Oskarshamn site investigation. Hydrogeochemical monitoring programme for core and percussion drilled boreholes 2009. Summary of ground water chemistry results from spring and autumn sampling

    Energy Technology Data Exchange (ETDEWEB)

    Regander, Claes; Bergman, Bo (Sweco Environment AB (Sweden))

    2010-09-15

    This report summarises the results obtained in 2009 from the hydrogeochemical monitoring programme for core and percussion drilled boreholes. During 2009 groundwater sampling has been performed in monitored (permanently installed) boreholes in two sampling periods, spring (May-June), and autumn (October-November). Both in spring and autumn groundwater sampling was carried out in the following 12 sections; HLX28:2, HLX35:2, HLX37:1, HLX39:1, KLX08:4, KLX10:2, KLX10:5, KLX12A:2, KLX15A:3, KLX15A:6, KLX18A:3, KLX19A:3. The programme started in 2005 and since then water sampling has been performed twice every year. The objective of the hydrogeochemical monitoring programme is to determine the groundwater composition in selected sections chosen for this purpose. In 2009 the sampling of core drilled borehole sections has been conducted in time series, where each borehole section has been sampled at seven occasions. Percussion drilled borehole sections has been sampled at three occasions. The final sample in each section was taken when the electric conductivity had reached a stable level. Obtained results from the activities presented here include groundwater chemistry data in accordance with SKB chemistry class 5 including options and SKB chemistry reduced class 5. SKB chemistry reduced class 5 includes analysis of pH, electric conductivity, alkalinity, density, drill water (uranine), major cations (Chapter 5.4), F-, Br-, Cl-, SO{sub 4}2-, Fe(II)/Fe(tot), HS-, DOC, TOC and the isotopes delta2H, delta18O and 3H. Options for SKB chemistry class 5 include even lanthanoids and other trace elements, As, In, I, environmental metals, NH{sub 4}+, nutrient salts and the isotopes delta34S, delta37Cl, 87Sr/86Sr, 10B/11B, delta13C, 226Ra, 222Rn, 238U, 234U, 230Th and 232Th. All data from the activity are stored in the SICADA database

  1. Age and quality of ground water and sources of nitrogen in the aquifers in Pumpkin Creek Valley, western Nebraska, 2000

    Science.gov (United States)

    Steele, G.V.; Cannia, J.C.; Sibray, S.S.; McGuire, V.L.

    2005-01-01

    Ground water is the source of drinking water for the residents of Pumpkin Creek Valley, western Nebraska. In this largely agricultural area, shallow aquifers potentially are susceptible to nitrate contamination. During the last 10 years, ground-water levels in the North Platte Natural Resources District have declined and contamination has become a major problem for the district. In 2000, the U.S. Geological Survey and the North Platte Natural Resources District began a cooperative study to determine the age and quality of the ground water and the sources of nitrogen in the aquifers in Pumpkin Creek Valley. Water samples were collected from 8 surface-water sites, 2 springs, and 88 ground-water sites during May, July, and August 2000. These samples were analyzed for physical properties, nutrients or nitrate, and hydrogen and oxygen isotopes. In addition, a subset of samples was analyzed for any combination of chlorofluorocarbons, tritium, tritium/helium, sulfur-hexafluoride, carbon-14, and nitrogen-15. The apparent age of ground water in the alluvial aquifer typically varied from about 1980 to modern, whereas ground water in the fractured Brule Formation had a median value in the 1970s. The Brule Formation typically contained ground water that ranged from the 1940s to the 1990s, but low-yield wells had apparent ages of 5,000 to 10,000 years before present. Data for oxygen-18 and deuterium indicated that lake-water samples showed the greatest effects from evaporation. Ground-water data showed no substantial evaporative effects and some ground water became isotopically heavier as the water moved downgradient. In addition, the physical and chemical ground-water data indicate that Pumpkin Creek is a gaining stream because little, if any, of its water is lost to the ground-water system. The water-quality type changed from a sodium calcium bicarbonate type near Pumpkin Creek's headwaters to a calcium sodium bicarbonate type near its mouth. Nitrate concentrations were

  2. Ground-water-quality data for Albany and surrounding areas, Southwest Georgia, 1951-99

    Science.gov (United States)

    Warner, Debbie; Easoz, Jamie A.; Priest, Sherlyn

    2002-01-01

    This report presents ground-water-quality data from the surficial, Upper Floridan, Claiborne, Clayton, and Upper Cretaceous aquifers in the Albany and surrounding areas of southwest Georgia. Water-quality data from about 186 wells in Baker, Calhoun, Dougherty, Lee, Mitchell, Terrell, and Worth Counties are presented for the period from 1951 through 1999. The data include field water-quality parameters collected during 1951-99, volatile and semi-volatile organic compounds collected during 1981-97, inorganic compounds collected during 1951-99, trace metals collected during 1964-99, radiochemicals collected during 1993-95, herbicides and insecticides collected during 1980-97, and recovery data for laboratory surrogate compounds (used for quality control and quality assurance for organic samples) collected during 1993-97. Ground-water quality data are presented in tables by data type and arranged by well number. Illustrations in this report contain information about study area location, well location, stratigraphy, and formation water-bearing properties. Ground-water-quality data are presented in text files and in a data base that includes geographic and tabular data. Data presented in this report provide a base with which to better define and interpret the quality of ground water in Albany, Ga., and surrounding areas. Although some of these data may have been published in previous reports associated with water-resources investigations, water-quality data are compiled as a useful resource.

  3. Ground-water surveillance at the Hanford Site for CY 1982

    Energy Technology Data Exchange (ETDEWEB)

    Eddy, P.A.; Prater, L.S.; Rieger, J.T.

    1983-06-01

    Operations at the Hanford Site since 1944 have resulted in the discharge of large volumes of process cooling water and other waste waters to the ground. These effluents, which have reached the unconfined ground water, contain low levels of radioactive and chemical substances. The movement of these constituents in the unconfined ground water is monitored as part of the Ground-Water Surveillance Program. During 1982, 324 monitoring wells were sampled at various times for radioactive and chemical constituents. Tritium are the primary ones used to monitor the movement of the ground water. This report describes recent changes in the configuration of the tritium and nitrate plumes. The tritium plume continues to show increasing concentrations near the Columbia River. While it is mapped as having reached the Columbia River, its contribution to the river has not been distinguished from other sources at this time. The general plume configuration is much the same as in 1978, 1979, 1980, and 1981. The size of the nitrate plume appears stable. Concentrations of nitrate in the vicinity of the 100-H Area continue to be high as a result of past leaks from an evaporation facility.

  4. Ground-Water Quality Data in the Coastal Los Angeles Basin Study Unit, 2006: Results from the California GAMA Program

    Science.gov (United States)

    Mathany, Timothy M.; Land, Michael; Belitz, Kenneth

    2008-01-01

    ] and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at approximately one-fourth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most compounds. Assessment of the quality-control information resulted in applying ?V? codes to approximately 0.1 percent of the data collected for ground-water samples (meaning a constituent was detected in blanks as well as the corresponding environmental data). This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable drinking-water quality. Regulatory thresholds are applied to the treated drinking water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA), California Department of Public Health (CDPH, formerly California Department of Health Services [CADHS]) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with those thresholds. VOCs were detected in alm

  5. Assessment of shallow ground-water quality in recently urbanized areas of Sacramento, California, 1998

    Science.gov (United States)

    Shelton, Jennifer L.

    2005-01-01

    recently developed urban areas. Five arsenic sample concentrations exceeded the U.S. Environmental Protection Agency (USEPA) primary maximum contaminant level (MCL) of 10 milligrams per liter adopted in 2001. Measurements that exceeded USEPA or California Department of Health Services recommended secondary maximum contaminant levels include manganese, iron, chloride, total dissolved solids, and specific conductance. These exceedances are probably a result of natural processes. Variations in stable isotope ratios of hydrogen (2H/1H) and oxygen (18O/16O) may indicate different sources or a mixing of recharge waters to the urban ground water. These variations also may indicate recharge directly from surface water in one well adjacent to the Sacramento River. Tritium concentrations indicate that most shallow ground water has been recharged since the mid-1950s, and tritium/helium-3 age dates suggest that recharge has occurred in the last 2 to 30 years in some areas. In areas where water table depths exceed 20 meters and wells are deeper, ground-water recharge may have occurred prior to 1950, but low concentrations of pesticides and VOCs detected in these deeper wells indicate a mixing of younger and older waters. Overall, the recently urbanized areas can be divided into two groups. One group contains wells where few VOCs and pesticides were detected, nitrate mostly was not detected, and National and State maximum contaminant levels, including the USEPA MCL for arsenic, were exceeded; these wells are adjacent to rivers and generally are characterized by younger water, shallow (1 to 4 meters) water table, chemically reducing conditions, finer grained sediments, and higher organics in the soils. In contrast, the other group contains wells where more VOCs, pesticides, and elevated nitrate concentrations were detected; these wells are farther from rivers and are generally characterized by a mixture of young and old waters, intermediate to deep (7 to 35 meters) wate

  6. Chemometric characterisation of the quality of ground waters from different wells in Slovenia

    OpenAIRE

    Novič, Marjana; Vončina, Ernest; Brodnjak-Vončina, Darinka; Sovič, Nataša

    2015-01-01

    The quality of ground water as a source of drinking water in Slovenia is regularly monitored. One of the monitoring programmes is performed on 5 wells for drinking water supply, 3 industrial wells and 2 ground water monitoring wells. Two hundred and fourteen samples of ground waters were analysed in the time 2003-2004. Samples were gathered from ten different sampling sites and physical chemical measurements were performed. The following 13 physical chemical parameters were regularly controll...

  7. Environmental isotopes as indicators for ground water recharge to fractured granite.

    Science.gov (United States)

    Ofterdinger, U S; Balderer, W; Loew, S; Renard, P

    2004-01-01

    To assess the contribution of accumulated winter precipitation and glacial meltwater to the recharge of deep ground water flow systems in fracture crystalline rocks, measurements of environmental isotope ratios, hydrochemical composition, and in situ parameters of ground water were performed in a deep tunnel. The measurements demonstrate the significance of these ground water recharge components for deep ground water flow systems in fractured granites of a high alpine catchment in the Central Alps, Switzerland. Hydrochemical and in situ parameters, as well as delta(18)O in ground water samples collected in the tunnel, show only small temporal variations. The precipitation record of delta(18)O shows seasonal variations of approximately 14% and a decrease of 0.23% +/- 0.03% per 100 m elevation gain. delta(2)H and delta(18)O in precipitation are well correlated and plot close to the meteoric water line, as well as delta(2)H and delta(18)O in ground water samples, reflecting the meteoric origin of the latter. The depletion of 18O in ground water compared to 18O content in precipitation during the ground water recharge period indicates significant contributions from accumulated depleted winter precipitation to ground water recharge. The hydrochemical composition of the encountered ground water, Na-Ca-HCO3-SO4(-F), reflects an evolution of the ground water along the flowpath through the granite body. Observed tritium concentrations in ground water range from 2.6 to 16.6 TU, with the lowest values associated with a local negative temperature anomaly and anomalous depleted 18O in ground water. This demonstrates the effect of local ground water recharge from meltwater of submodern glacial ice. Such localized recharge from glaciated areas occurs along preferential flowpaths within the granite body that are mainly controlled by observed hydraulic active shear fractures and cataclastic faults.

  8. Ground-Water Quality Data in the Middle Sacramento Valley Study Unit, 2006 - Results from the California GAMA Program

    Science.gov (United States)

    Schmitt, Stephen J.; Fram, Miranda S.; Milby Dawson, Barbara J.; Belitz, Kenneth

    2008-01-01

    , replicates, laboratory matrix spikes) were collected at approximately 10 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a noticeable source of bias in the data for the ground-water samples. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most constituents. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and are not indicative of compliance or noncompliance with regulatory thresholds. Most constituents that were detected in ground-water samples were found at concentrations below drinking-water thresholds. VOCs were detected in less than one-third and pesticides and pesticide degradates in just over one-half of the grid wells, and all detections of these constituents in samples from all wells of the MSACV study unit were below health-based thresholds. All detections of trace elements in samples from MSACV grid wells were below health-based thresholds, with the exceptions of arsenic and boro

  9. Revised ground-water monitoring compliance plan for the 300 area process trenches

    Energy Technology Data Exchange (ETDEWEB)

    Schalla, R.; Aaberg, R.L.; Bates, D.J.; Carlile, J.V.M.; Freshley, M.D.; Liikala, T.L.; Mitchell, P.J.; Olsen, K.B.; Rieger, J.T.

    1988-09-01

    This document contains ground-water monitoring plans for process-water disposal trenches located on the Hanford Site. These trenches, designated the 300 Area Process Trenches, have been used since 1973 for disposal of water that contains small quantities of both chemicals and radionuclides. The ground-water monitoring plans contained herein represent revision and expansion of an effort initiated in June 1985. At that time, a facility-specific monitoring program was implemented at the 300 Area Process Trenches as part of a regulatory compliance effort for hazardous chemicals being conducted on the Hanford Site. This monitoring program was based on the ground-water monitoring requirements for interim-status facilities, which are those facilities that do not yet have final permits, but are authorized to continue interim operations while engaged in the permitting process. The applicable monitoring requirements are described in the Resource Conservation and Recovery Act (RCRA), 40 CFR 265.90 of the federal regulations, and in WAC 173-303-400 of Washington State's regulations (Washington State Department of Ecology 1986). The program implemented for the process trenches was designed to be an alternate program, which is required instead of the standard detection program when a facility is known or suspected to have contaminated the ground water in the uppermost aquifer. The plans for the program, contained in a document prepared by the US Department of Energy (USDOE) in 1985, called for monthly sampling of 14 of the 37 existing monitoring wells at the 300 Area plus the installation and sampling of 2 new wells. 27 refs., 25 figs., 15 tabs.

  10. Ground-water data for the Beryl-Enterprise area, Escalante Desert, Utah

    Science.gov (United States)

    Mower, R.W.

    1981-01-01

    This report contains a compilation of selected ground-water data for the Beryl-Enterprise area, Iron and Washington Counties, Utah. The records of the wells include such information as driller 's logs, yield, drawdown, use, and temperature of the well water. There are also records of water levels in selected wells for the period 1973-79, chemical analyses of ground water, records of selected springs, and a tabulation of ground-water withdrawals for 1937-78. (USGS)

  11. Shallow ground-water conditions, Tom Green County, Texas

    Science.gov (United States)

    Lee, J.N.

    1986-01-01

    Most of the water needs of Tom Green County, Texas, are supplied by ground water; however, the city of San Angelo is supplied by surface water. Groundwater withdrawals during 1980 (latest year for which data are available) in Tom Green County totaled about 15,300 acre-feet, all derived from shallow aquifers. Shallow aquifers in this report refer to the ground-water system generally less than 400 feet deep that contains water with less than a 10,000 milligrams per liter concentration of dissolved solids; aquifers comprising this system include: The Leona, Comanche Peak, Trinity, Blaine, San Angelo, Choza, Bullwagon, Vale, Standpipe, and Arroyo aquifers.

  12. Iowa ground-water quality

    Science.gov (United States)

    Buchmiller, R.C.; Squillace, P.J.; Drustrup, R.D.

    1987-01-01

    The population served by ground-water supplies in Iowa (fig. L4) is estimated to be about 2,392,000, or 82 percent of the total population (U.S. Geological Survey, 1985, p. 211). The population of Iowa is distributed fairly uniformly throughout the State (fig. IB), with 59 percent residing in rural areas or towns of less than 10,000 (U.S. Bureau of the Census, 1982). Surficial aquifers, the Jordan aquifer, and aquifers that form the uppermost bedrock aquifer in a particular area are most commonly used for drinking-water supplies and usually provide ample amounts of good quality water. However, naturally occurring properties or substances such as hardness, dissolved solids, and radioactivity limit the use of water for drinking purposes in some areas of each of the five principal aquifers (fig. 2/4). Median concentrations of nitrate in all aquifers and radium-226 in all aquifers except the Jordan are within the primary drinking-water standards established by the U.S. Environmental Protection Agency (1986a). Median concentrations for dissolved solids in the surficial, Dakota, and Jordan aquifers exceed secondary drinking-water standards established by the U.S. Environmental Protection Agency (1986b).

  13. Guide to Louisiana's ground-water resources

    Science.gov (United States)

    Stuart, C.G.; Knochenmus, D.D.; McGee, B.D.

    1994-01-01

    Ground water is one of the most valuable and abundant natural resources of Louisiana. Of the 4-.4 million people who live in the State, 61 percent use ground water as a source for drinking water. Most industrial and rural users and half of the irrigation users in the State rely on ground water. Quantity, however, is not the only aspect that makes ground water so valuable; quality also is important for its use. In most areas, little or no water treatment is required for drinking water and industrial purposes. Knowledge of Louisiana's ground-water resources is needed to ensure proper development and protection of this valuable resource. This report is designed to inform citizens about the availability and quality of ground water in Louisiana. It is not intended as a technical reference; rather, it is a guide to ground water and the significant role this resource plays in the state. Most of the ground water that is used in the State is withdrawn from 13 aquifers and aquifer systems: the Cockfield, Sparta, and Carrizo-Wilcox aquifersin northern Louisiana; Chicot aquifer system, Evangeline aquifer, Jasper aquifer system, and Catahoula aquifer in central and southwestern Louisiana; the Chicot equivalent, Evangeline equivalent, and Jasper equivalent aquifer systems in southeastern Louisiana; and the MississippiRiver alluvial, Red River alluvial, and upland terrace aquifers that are statewide. Ground water is affected by man's activities on the land surface, and the major ground-water concerns in Louisiana are: (1) contamination from surface disposal of hazardous waste, agricultural chemicals, and petroleum products; (2) contamination from surface wastes and saltwater through abandoned wells; (3) saltwater encroachment; and (4) local overdevelopment. Information about ground water in Louisiana is extensive and available to the public. Several State and Federal agencies provide published and unpublished material upon request.

  14. CHEMICAL QUALITY CHARACTERISTICS OF TEHRAN GROUND WATER

    Directory of Open Access Journals (Sweden)

    K. Imandel

    1994-06-01

    Full Text Available For better understanding of Tehran ground water, samples were taken randomly from 340 out of 655 deep & semi deep wells in 1993, which dug by Tehran Water Supply and Sewage Engineering Company. 260 Water specimens were examined chemically and physically and compared with the 1993 World Health Organization (WHO and Food and Agriculture Organization (FAO criteria and analyzed statistically. Logarithmic diagram of arithmetic mean of 53 deep wells which are now connected to Tehran water supply system showed Sodium- Sulphate category. Main chemical components of water are closely adjusted to the international standards and no overdoses were observed in any cases. Logarithmic diagram of arithmetic mean of 72 deep wells, which were rsed for the Tehran’s orbital town's drinking water, showed that chemical components of the water were Calcic-Chloride category and there were not observed any increases within the other compounds.

  15. Hydrogeology, simulated ground-water flow, and ground-water quality, Wright-Patterson Air Force Base, Ohio

    Science.gov (United States)

    Dumouchelle, D.H.; Schalk, C.W.; Rowe, G.L.; De Roche, J.T.

    1993-01-01

    Ground water is the primary source of water in the Wright-Patterson Air Force Base area. The aquifer consists of glacial sands and gravels that fill a buried bedrock-valley system. Consolidated rocks in the area consist of poorly permeable Ordovician shale of the Richmondian stage, in the upland areas, the Brassfield Limestone of Silurian age. The valleys are filled with glacial sediments of Wisconsinan age consisting of clay-rich tills and coarse-grained outwash deposits. Estimates of hydraulic conductivity of the shales based on results of displacement/recovery tests range from 0.0016 to 12 feet per day; estimates for the glacial sediments range from less than 1 foot per day to more than 1,000 feet per day. Ground water flow from the uplands towards the valleys and the major rivers in the region, the Great Miami and the Mad Rivers. Hydraulic-head data indicate that ground water flows between the bedrock and unconsolidated deposits. Data from a gain/loss study of the Mad River System and hydrographs from nearby wells reveal that the reach of the river next to Wright-Patterson Air Force Base is a ground-water discharge area. A steady-state, three-dimensional ground-water-flow model was developed to simulate ground-water flow in the region. The model contains three layers and encompasses about 100 square miles centered on Wright-Patterson Air Force Base. Ground water enters the modeled area primarily by river leakage and underflow at the model boundary. Ground water exits the modeled area primarily by flow through the valleys at the model boundaries and through production wells. A model sensitivity analysis involving systematic changes in values of hydrologic parameters in the model indicates that the model is most sensitive to decreases in riverbed conductance and vertical conductance between the upper two layers. The analysis also indicates that the contribution of water to the buried-valley aquifer from the bedrock that forms the valley walls is about 2 to 4

  16. Geotechnics - the key to ground water protection

    DEFF Research Database (Denmark)

    Baumann, Jens; Foged, Niels; Jørgensen, Peter

    2000-01-01

    During the past 5 to 10 years research into ground water protection has proved that fractures in clay till may increase the hydraulic conductivity and herby the vulnerability of the ground water considerably. However, research has not identified a non-expensive and efficient method to map...

  17. Procedures for ground-water investigations

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program.

  18. Pesticides in Ground Water of the Maryland Coastal Plain

    Science.gov (United States)

    Denver, Judith M.; Ator, Scott W.

    2006-01-01

    Selected pesticides are detectable at low levels (generally less than 0.1 microgram per liter) in unconfined ground water in many parts of the Maryland Coastal Plain. Samples were recently collected (2001-04) from 47 wells in the Coastal Plain and analyzed for selected pesticides and degradate compounds (products of pesticide degradation). Most pesticide degradation occurs in the soil zone before infiltration to the water table, and degradates of selected pesticides were commonly detected in ground water, often at higher concentrations than their respective parent compounds. Pesticides and their degradates often occur in ground water in mixtures of multiple compounds, reflecting similar patterns in usage. All measured concentrations in ground water were below established standards for drinking water, and nearly all were below other health-based guidelines. Although drinking-water standards and guidelines are typically much higher than observed concentrations in ground water, they do not exist for many detected compounds (particularly degradates), or for mixtures of multiple compounds. The distribution of observed pesticide compounds reflects known usage patterns, as well as chemical properties and environmental factors that affect the fate and transport of these compounds in the environment. Many commonly used pesticides, such as glyphosate, pendimethalin, and 2,4-D were not detected in ground water, likely because they were sorbed onto organic matter or degraded in the soil zone. Others that are more soluble and (or) persistent, like atrazine, metolachlor, and several of their degradates, were commonly detected in ground water where they have been used. Atrazine, for example, an herbicide used primarily on corn, was most commonly detected in ground water on the Eastern Shore (where agriculture is common), particularly where soils are well drained. Conversely, dieldrin, an insecticide previously used heavily for termite control, was detected only on the Western

  19. Maps showing ground-water levels, springs, and depth to ground water, Basin and Range Province, Texas

    Science.gov (United States)

    Brady, B.T.; Bedinger, M.S.; Mulvihill, D.A.; Mikels, John; Langer, W.H.

    1984-01-01

    This report on ground-water levels, springs, and depth to ground water in the Basin and Range province of Texas (see index map) was prepared as part of a program of the U.S. Geological Survey to identify prospective regions for further study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984), utilizing program guidelines defined in Sargent and Bedinger (1984). Also included in this report are selected references on pertinent geologic and hydrologic studies of the region. Other map reports in this series contain detailed data on ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources.

  20. Radon-222 concentrations in ground water and soil gas on Indian reservations in Wisconsin

    Science.gov (United States)

    DeWild, John F.; Krohelski, James T.

    1995-01-01

    The weighted average radon-222 concentration of indoor air in homes located on Wisconsin Indian Reservations is 5.8 picocuries per liter, which exceeds the U.S. Environmental Protection Agency action limit of 4 picocuries per liter. Ground water is the principle source of drinking water on Wisconsin Indian Reservations and generally accounts for about 5 percent of the total indoor air radon-222 concentrations found in homes. To determine the distribution of radon-222, ground water from 29 private and community Wisconsin Indian Reservation wells and soil gas at a depth of about 3 feet below land surface adjacent to the wells were sampled. Sites with wells were distributed among the 11 Wisconsin Indian Reservations so that each Reservation contained at least 2 sites. The remaining seven sites were divided among the Reservation by acreage held by each tribe.

  1. Ground-water geology of the Bruneau-Grand View area, Owyhee County, Idaho

    Science.gov (United States)

    Littleton, Robert Thomas; Crosthwaite, E.G.

    1957-01-01

    water does not exceed about 2,700 feet above mean sea level. In some areas, where the land surface is below that altitude, the artesian system discharges water through springs and seeps and locally causes waterlogging and development of alkali soil. In chemical quality much of the water is unsuitable for irrigation and domestic use. The water contains a relatively moderate amount of dissolved solids, but the percent sodium and the concentration of fluoride are excessive for some uses. The quality of the water for irrigation ranges from excellent in the southern part of the artesian system to unsuitable in the northern part. All the artesian ground water that was sampled contained excessive amounts of fluoride. There is a substantial supply of undeveloped artesian water in the area, but

  2. Apparatus for ground water chemistry investigations in field caissons

    Energy Technology Data Exchange (ETDEWEB)

    Cokal, E.J.; Stallings, E.; Walker, R.; Nyhan, J.W.; Polzer, W.L.; Essington, E.H.

    1985-01-01

    Los Alamos is currently in its second season of ground water chemistry and hydrology experimentation in a field facility that incorporates clusters of six, 3-meter-diameter by 6-meter-deep, soil-filled caissons and required ancillaries. Initial experience gained during the 1983 field season indicated the need for further development of the technology of this type of experimentation supporting hydrologic waste management research. Uniform field application of water/matrix solutions to the caisson, matrix and tracer solution blending/storage, and devices for ground water sampling are discussed.

  3. Hanford site ground water protection management plan

    Energy Technology Data Exchange (ETDEWEB)

    1994-10-01

    Ground water protection at the Hanford Site consists of preventative and remedial measures that are implemented in compliance with a variety of environmental regulations at local, state, and federal levels. These measures seek to ensure that the resource can sustain a broad range of beneficial uses. To effectively coordinate and ensure compliance with applicable regulations, the U.S. Department of Energy has issued DOE Order 5400.1 (DOE 1988a). This order requires all U.S. Department of Energy facilities to prepare separate ground water protection program descriptions and plans. This document describes the Ground Water Protection Management Plan (GPMP) for the Hanford Site located in the state of Washington. DOE Order 5400.1 specifies that the GPMP covers the following general topical areas: (1) documentation of the ground water regime; (2) design and implementation of a ground water monitoring program to support resource management and comply with applicable laws and regulations; (3) a management program for ground water protection and remediation; (4) a summary and identification of areas that may be contaminated with hazardous waste; (5) strategies for controlling hazardous waste sources; (6) a remedial action program; and (7) decontamination, decommissioning, and related remedial action requirements. Many of the above elements are currently covered by existing programs at the Hanford Site; thus, one of the primary purposes of this document is to provide a framework for coordination of existing ground water protection activities. The GPMP provides the ground water protection policy and strategies for ground water protection/management at the Hanford Site, as well as an implementation plan to improve coordination of site ground water activities.

  4. Ground-Water Quality in the Vicinity of Coal-Refuse Areas Reclaimed with Biosolids in Fulton County, Illinois

    Science.gov (United States)

    Morrow, William S.

    2007-01-01

    The Metropolitan Water Reclamation District of Greater Chicago has applied biosolids, followed by revegetation, to reclaim three coal-refuse areas. Most of the reclamation at the three sites was done from 1989 through 1992, and included the application of lime, clay, and various loads of biosolids up to 1,000 dry tons per acre. Water samples collected from 12 monitoring wells installed in the vicinity of the three reclaimed coal-refuse areas were analyzed to better understand the hydrogeology and water-quality effects. Ground water probably flows along preferential paths in the disturbed coal-refuse areas, and is impeded by undisturbed glacial till. Most of the samples contained elevated concentrations of sulfate, iron, and manganese, constituents associated with ground water in coal-mined areas. Concentrations of aluminum, cadmium, nickel, or zinc were somewhat elevated in samples from four wells, and greatest in water samples with pH less than 5. The smaller nutrient concentrations indicate that the applied biosolids are not identifiably affecting nutrients or metal concentrations in shallow ground water near the refuse piles. The coal refuse likely is the primary influence on the chemical characterization of ground-water in the area.

  5. (Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio)

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    This report presents information related to the sampling of ground water at the Wright-Patterson Air Force Base. It is part of an investigation into possible ground water contamination. Information concerns well drilling/construction; x-ray diffraction and sampling; soil boring logs; and chain-of-custody records.

  6. Shallow ground-water quality beneath cropland in the Red River of the North Basin, Minnesota and North Dakota, 1993-95

    Science.gov (United States)

    Cowdery, Timothy K.

    1997-01-01

    During 1993-95, the agriculture on two sandy, surficial aquifers in the Red River of the North Basin affected the quality of shallow ground water in each aquifer differently. The Sheyenne Delta aquifer, in the western part of the basin, had land-use, hydrogeological, and rainfall characteristics that allowed few agricultural chemicals to reach or remain in the shallow ground water. The Otter Tail outwash aquifer, in the eastern part of the basin, had characteristics that caused significant amounts of nutrients and pesticides to reach and remain in the shallow ground water. Shallow ground water from both aquifers is dominated by calcium, magnesium, and bicarbonate ions. During the respective sampling periods, water from the Sheyenne Delta aquifer was mostly anoxic and water from the Otter Tail outwash aquifer had a median dissolved oxygen concentration of 3.6 mg/L (milligrams per liter). The median nitrate concentration was 0.03 mg/L as nitrogen (mg/L-N) in shallow ground water from the Sheyenne Delta aquifer and 6.1 mg/L-N in that from the Otter Tail outwash aquifer. Of 18 herbicides and 4 insecticides commonly used in the aquifer areas and for which analyses were done, 5 herbicides and 1 herbicide metabolite were detected in the shallow ground water from the Sheyenne Delta aquifer and 8 herbicides and 2 metabolites were detected in that from the Otter Tail outwash aquifer. The total herbicide concentration median was less than the detection limit in shallow ground water from the Sheyenne Delta aquifer and 0.023 μg/L (micorgrams per liter) in that from the Otter Tail outwash aquifer. Triazine herbicides were the most commonly detected herbicides and were detected at the highest concentrations in the shallow ground water from both study areas. One sample from the Sheyenne Delta aquifer contained a high concentration of picloram. Agricultural chemicals in both aquifers were stratified vertically and their concentration correlated inversely with ground-water age. The

  7. Hydrology and Ground-Water Quality in the Mine Workings within the Picher Mining District, Northeastern Oklahoma, 2002-03

    Science.gov (United States)

    DeHay, Kelli L.; Andrews, William J.; Sughru, Michael P.

    2004-01-01

    seepage from the aquifer to downstream portions of Tar Creek was much more likely. Water properties and major-ion concentrations indicate that water in the mining area was very hard, with large concentrations of dissolved solids that increased from areas of presumed recharge toward areas with older ground water. Most of the ground-water samples, particularly those from the airshafts, had dissolved-oxygen concentrations less than 1.0 milligram per liter. Small concentrations of dissolved oxygen may have been introduced during the sampling process. The small dissolved-oxygen concentrations were associated with samples containing large iron concentrations that indicates possible anoxic conditions in much of the aquifer. Ground water in the mining district was dominated by calcium, magnesium, and sulfate. Sodium concentrations tended to increase relative to calcium and magnesium concentrations. Ground-water samples collected in 2002-03 had large concentrations of many trace elements. Larger concentrations of metals and sulfate occurred in ground water with smaller pHs and dissolved-oxygen concentrations. Iron was the metal with the largest concentrations in the ground-water samples, occurring at concentrations up to 115,000 micrograms per liter. Cadmium, lead, manganese, zinc, and the other analyzed metals occurred in smaller concentrations in ground water than iron. However, larger cadmium concentrations appeared to be associated with sites that have small iron concentrations and more oxygenated waters. This is noteworthy because the small sulfate and iron concentrations in these waters could lead to conclusions that the waters are less contaminated than waters with large sulfate and iron concentrations. Ground-water quality in the mining district was compared with subsets of samples collected in 1983-85 and in 2002. Concentrations of most mine-water indicators such as specific conductance, acidity, magnesium, sulfate, and trace elements concentrations dec

  8. Radionuclides in ground water of the Carson River Basin, western Nevada and eastern California, U.S.A.

    Science.gov (United States)

    Thomas, J.M.; Welch, A.H.; Lico, M.S.; Hughes, J.L.; Whitney, R.

    1993-01-01

    in ground water in the aquifer, but instead is produced in the sample after collection and before analysis. Potassium-40 is primarily from the dissolution of K-containing minerals, probably K-feldspar and biotite. Radon-222 is primarily from the decay of 226Ra in the aquifer materials. Radium in the ground water is thought to be mainly from alpha recoil associated with the decay of Th in the aquifer material. Some Ra may be from dissolution (or desorption) or Ra-rich coatings on sediments. ?? 1993.

  9. Trace Analysis of Heavy Metals in Ground Waters of Vijayawada Industrial Area

    Science.gov (United States)

    Tadiboyina, Ravisankar; Ptsrk, Prasada Rao

    2016-01-01

    In recent years, the new environmental problem are arising due to industrial hazard wastage, global climate change, ground water contamination and etc., gives an attention to protect environment.one of the major source of contamination of ground water is improper discharge of industrial effluents these effluents contains so many heavy metals which…

  10. Ground-Water Protection and Monitoring Program

    Energy Technology Data Exchange (ETDEWEB)

    Dresel, P.E.

    1995-06-01

    This section of the 1994 Hanford Site Environmental Report summarizes the ground-water protection and monitoring program strategy for the Hanford Site in 1994. Two of the key elements of this strategy are to (1) protect the unconfined aquifer from further contamination, and (2) conduct a monitoring program to provide early warning when contamination of ground water does occur. The monitoring program at Hanford is designed to document the distribution and movement of existing ground-water contamination and provides a historical baseline for evaluating current and future risk from exposure to the contamination and for deciding on remedial action options.

  11. Ground-Water Quality Data in the Southern Sierra Study Unit, 2006 - Results from the California GAMA Program

    Science.gov (United States)

    Fram, Miranda S.; Belitz, Kenneth

    2007-01-01

    quality-control information resulted in censoring of less than 0.2 percent of the data collected for ground-water samples. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs and pesticides were detected in less than one-third of the grid wells, and all detections in samples from SOSA wells were below health-based thresholds. All detections of trace elements and nutrients in samples from SOSA wells were below health-based thresholds, with the exception of four detections of arsenic that were above the USEPA maximum contaminant level (MCL-US) and one detection of boron that was above the CDPH notification level (NL-CA). All detections of radioactive constituents were below health-based thresholds, although four samples had activities of radon-222 above the proposed MCL-US. Most of the samples from SOSA wells had concentrations of major elements, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns. A few samples contained iron, manganese, or total dissolved solids at concentrations above the SMCL-CA thresholds.

  12. Submarine ground-water discharge: nutrient loading and nitrogen transformations

    Science.gov (United States)

    Kroeger, Kevin D.; Swarzenski, Peter W.; Crusius, John; Bratton, John F.; Charette, Matthew A.

    2006-01-01

    samples across the salinity gradients of coastal aquifers. In addition, locating and quantifying rates of submarine ground-water discharge remains a challenge due to the diffuse and spatially and temporally heterogeneous nature of discharge. As a result, with regard to the study of biogeochemical cycles and chemical loads to coastal waters, the seepage face and subterranean estuary are relatively new and under-studied zones in the aquatic cascade from watershed to sea. Processes occurring in those zones must be understood and considered for proper modeling and management of coastal water resources.

  13. Geohydrological characterization, water-chemistry, and ground-water flow simulation model of the Sonoma Valley area, Sonoma County, California

    Science.gov (United States)

    Farrar, Christopher D.; Metzger, Loren F.; Nishikawa, Tracy; Koczot, Kathryn M.; Reichard, Eric G.; Langenheim, V.E.

    2006-01-01

    changes by region. In recent years, pumping depressions have developed southeast of Sonoma and southwest of El Verano. Water-chemistry data for samples collected from 75 wells during 2002-04 indicate that the ground-water quality in the study area generally is acceptable for potable use. The water from some wells, however, contains one or more constituents in excess of the recommended standards for drinking water. The chemical composition of water from creeks, springs, and wells sampled for major ions plot within three groups on a trilinear diagram: mixed-bicarbonate, sodium-mixed anion, and sodium-bicarbonate. An area of saline ground water in the southern part of the Sonoma Valley appears to have shifted since the late 1940s and early 1950s, expanding in one area, but receding in another. Sparse temperature data from wells southwest of the known occurrence of thermal water suggest that thermal water may be present beneath a larger part of the valley than previously thought. Thermal water contains higher concentrations of dissolved minerals than nonthermal waters because mineral solubilities generally increase with temperature. Geohydrologic Characterization, Water-Chemistry, and Ground-Water Flow Simulation Model of the Sonoma Valley Area, Sonoma County, California Oxygen-18 (d18 O) and deuterium (dD) values for water from most wells plot along the global meteoric water line, indicating that recharge primarily is derived from the direct infiltration of precipitation or the infiltration of seepage from creeks. Samples from shallow- and intermediate-depth wells located near Sonoma Creek and (or) in the vicinity of Shellville plot to the right of the global meteoric water line, indicating that these waters are partly evaporated. The d18 O and dD composition of water from sampled wells indicates that water from wells deeper than 200 feet is isotopically lighter (more negative) than water from wells less than 200 feet deep, possibly indicating that older ground wate

  14. Thermal use of ground water; Thermische Grundwassernutzung

    Energy Technology Data Exchange (ETDEWEB)

    Cathomen, N.; Stauffer, F.; Kinzelbach, W.; Osterkorn, F.

    2002-07-01

    This article discusses possible regional changes in ground water temperature caused by thermal use of the ground water in heat pump installations and by the infiltration of cooling water. The article reports on investigations made into the influence of ground water usage in the community of Altach in the Rhine Valley in Austria. The procedures used and the geology of the area investigated are described and the results of the measurements that were made are presented. The mathematical modelling of regional long-term heat transport is presented. The results of simulations are compared with long-term temperature measurements. The use of the results as a basis for the assessment of permissible thermal use of ground water is discussed.

  15. GROUND WATER CONTAMINATION POTENTIAL FROM STORMWATER INFILTRATION

    Science.gov (United States)

    Prior to urbanization, ground water recharge resulted from infiltration of precipitation through pervious surfaces, including grasslands and woods. This infiltration water was relatively uncontaminated. With urbanization, the permeable soil surface area through which recharge by...

  16. Section 10: Ground Water - Waste Characteristics & Targets

    Science.gov (United States)

    HRS Training. The waste characteristics factor category in the ground water pathway is made up of two components: the toxicity/mobility of the most hazardous substance associated with the site and the hazardous waste quantity at the site.

  17. Section 9: Ground Water - Likelihood of Release

    Science.gov (United States)

    HRS training. the ground water pathway likelihood of release factor category reflects the likelihood that there has been, or will be, a release of hazardous substances in any of the aquifers underlying the site.

  18. Estimating ground water discharge by hydrograph separation.

    Science.gov (United States)

    Hannula, Steven R; Esposito, Kenneth J; Chermak, John A; Runnells, Donald D; Keith, David C; Hall, Larry E

    2003-01-01

    Iron Mountain is located in the West Shasta Mining District in California. An investigation of the generation of acid rock drainage and metals loading to Boulder Creek at Iron Mountain was conducted. As part of that investigation, a hydrograph separation technique was used to determine the contribution of ground water to total flow in Boulder Creek. During high-flow storm events in the winter months, peak flow in Boulder Creek can exceed 22.7 m3/sec, and comprises surface runoff, interflow, and ground water discharge. A hydrograph separation technique was used to estimate ground water discharge into Boulder Creek during high-flow conditions. Total ground water discharge to the creek approaches 0.31 m3/sec during the high-flow season. The hydrograph separation technique combined with an extensive field data set provided reasonable estimates of ground water discharge. These estimates are useful for other investigations, such as determining a corresponding metals load from the metal-rich ground water found at Iron Mountain and thus contributing to remedial alternatives.

  19. Availability and quality of ground water, southern Ute Indian Reservation, southwestern Colorado

    Science.gov (United States)

    Brogden, Robert E.; Hutchinson, E. Carter; Hillier, Donald E.

    1979-01-01

    Population growth and the potential development of subsurface mineral resources have increased the need for information on the availability and quality of ground water on the Southern Ute Indian Reservation. The U.S. Geological Survey, in cooperation with the Southern Ute Tribal Council, the Four Corners Regional Planning Commission, and the U.S. Bureau of Indian Affairs, conducted a study during 1974-76 to assess the ground-water resources of the reservation. Water occurs in aquifers in the Dakota Sandstone, Mancos Shale, Mesaverde Group, Lewis Shale, Pictured Cliffs Sandstone, Fruitland Formation, Kirtland Shale, Animas and San Jose Formations, and terrace and flood-plain deposits. Well yields from sandstone and shale aquifers are small, generally in the range from 1 to 10 gallons per minute with maximum reported yields of 75 gallons per minute. Well yields from terrace deposits generally range from 5 to 10 gallons per minute with maximum yields of 50 gallons per minute. Well yields from flood-plain deposits are as much as 25 gallons per minute but average 10 gallons per minute. Water quality in aquifers depends in part on rock type. Water from sandstone, terrace, and flood-plain aquifers is predominantly a calcium bicarbonate type, whereas water from shale aquifers is predominantly a sodium bicarbonate type. Water from rocks containing interbeds of coal or carbonaceous shales may be either a calcium or sodium sulfate type. Dissolved-solids concentrations of ground water ranged from 115 to 7,130 milligrams per liter. Water from bedrock aquifers is the most mineralized, while water from terrace and flood-plain aquifers is the least mineralized. In many water samples collected from bedrock, terrace, and flood-plain aquifers, the concentrations of arsenic, chloride, dissolved solids, fluoride, iron, manganese, nitrate, selenium, and sulfate exceeded U.S. Public Health Service (1962) recommended limits for drinking water. Selenium in the ground water in excess of U

  20. A proposed ground-water quality monitoring network for Idaho

    Science.gov (United States)

    Whitehead, R.L.; Parliman, D.J.

    1979-01-01

    A ground water quality monitoring network is proposed for Idaho. The network comprises 565 sites, 8 of which will require construction of new wells. Frequencies of sampling at the different sites are assigned at quarterly, semiannual, annual, and 5 years. Selected characteristics of the water will be monitored by both laboratory- and field-analysis methods. The network is designed to: (1) Enable water managers to keep abreast of the general quality of the State 's ground water, and (2) serve as a warning system for undesirable changes in ground-water quality. Data were compiled for hydrogeologic conditions, ground-water quality, cultural elements, and pollution sources. A ' hydrologic unit priority index ' is used to rank 84 hydrologic units (river basins or segments of river basins) of the State for monitoring according to pollution potential. Emphasis for selection of monitoring sites is placed on the 15 highest ranked units. The potential for pollution is greatest in areas of privately owned agricultural land. Other areas of pollution potential are residential development, mining and related processes, and hazardous waste disposal. Data are given for laboratory and field analyses, number of site visits, manpower, subsistence, and mileage, from which costs for implementing the network can be estimated. Suggestions are made for data storage and retrieval and for reporting changes in water quality. (Kosco-USGS)

  1. Ground Water Arsenic Contamination: A Local Survey in India

    Science.gov (United States)

    Kumar, Arun; Rahman, Md. Samiur; Iqubal, Md. Asif; Ali, Mohammad; Niraj, Pintoo Kumar; Anand, Gautam; Kumar, Prabhat; Abhinav; Ghosh, Ashok Kumar

    2016-01-01

    Background: In the present times, arsenic poisoning contamination in the ground water has caused lots of health-related problems in the village population residing in middle Gangetic plain. In Bihar, about 16 districts have been reported to be affected with arsenic poisoning. For the ground water and health assessment, Simri village of Buxar district was undertaken which is a flood plain region of river Ganga. Methods: In this study, 322 water samples were collected for arsenic estimation, and their results were analyzed. Furthermore, the correlation between arsenic contamination in ground water with depth and its distance from river Ganga were analyzed. Results are presented as mean ± standard deviation and total variation present in a set of data was analyzed through one-way analysis of variance. The difference among mean values has been analyzed by applying Dunnett's test. The criterion for statistical significance was set at P arsenic concentration in hand pumps. Furthermore, a correlation between the arsenic concentration with the depth of the hand pumps and the distance from the river Ganga was also a significant study. Conclusions: The present study concludes that in Simri village there is high contamination of arsenic in ground water in all the strips. Such a huge population is at very high risk leading the village on the verge of causing health hazards among them. Therefore, an immediate strategy is required to combat the present problem. PMID:27625765

  2. Ground Water Arsenic Contamination: A Local Survey in India.

    Science.gov (United States)

    Kumar, Arun; Rahman, Md Samiur; Iqubal, Md Asif; Ali, Mohammad; Niraj, Pintoo Kumar; Anand, Gautam; Kumar, Prabhat; Abhinav; Ghosh, Ashok Kumar

    2016-01-01

    In the present times, arsenic poisoning contamination in the ground water has caused lots of health-related problems in the village population residing in middle Gangetic plain. In Bihar, about 16 districts have been reported to be affected with arsenic poisoning. For the ground water and health assessment, Simri village of Buxar district was undertaken which is a flood plain region of river Ganga. In this study, 322 water samples were collected for arsenic estimation, and their results were analyzed. Furthermore, the correlation between arsenic contamination in ground water with depth and its distance from river Ganga were analyzed. Results are presented as mean ± standard deviation and total variation present in a set of data was analyzed through one-way analysis of variance. The difference among mean values has been analyzed by applying Dunnett's test. The criterion for statistical significance was set at P arsenic concentration in hand pumps. Furthermore, a correlation between the arsenic concentration with the depth of the hand pumps and the distance from the river Ganga was also a significant study. The present study concludes that in Simri village there is high contamination of arsenic in ground water in all the strips. Such a huge population is at very high risk leading the village on the verge of causing health hazards among them. Therefore, an immediate strategy is required to combat the present problem.

  3. Ground-water resources of Riverton irrigation project area, Wyoming

    Science.gov (United States)

    Morris, Donald Arthur; Hackett, O.M.; Vanlier, K.E.; Moulder, E.A.; Durum, W.H.

    1959-01-01

    streams, drains, or lakes; by pumping or flow of wells; or by flow of springs. Waterlogging and the associated development of saline soils are common in parts of the Riverton irrigation project and adjacent irrigated land. The waterlogging is in part the result of the infiltration of irrigation water in excess of the capacity of the aquifers to store and transmit this added recharge. The solution of the drainage problems involves the consideration of a number of factors, some of which are inadequately known in some parts of the area and require further investigation before fully effective drainage measures can be designed. The results of an aquifer test to determine the hydrologic characteristics of the Wind River formation at Riverton indicate a transmissibility of 10,000 gallons per day per foot (10,000 gpd per ft) and a storage coefficient of 2 x 10-4. The results of the test provide a part of the necessary foundation for the solution of present and future water-supply problems at Riverton and throughout the project area. Water from shallow aquifers in irrigated tracts in the Riverton irrigation project area generally contains large amounts of dissolved solids that were leached from the soil and rocks by infiltrating irrigation water. However, wells tapping beds that receive considerable recharge from influent canal and drain seepage yield water of relatively low mineralizatoin. Dilute water is obtained also from some shallow wells in the alluvial bottom lands and on low stream terraces that border the Wind Rover. Water from deep aquifers generally is more dilute than that from shallow aquifers. However, ground water from the deep aquifers, unmixed with irrigation water, generally has a percent sodium greater than 80. Analyses of salt crusts on the ground surface in low areas that are affected by effluent seepage and a high water table show predominance of sodium sulfate salinity, and from determinations of the water-soluble and acid-soluble substances in several

  4. Effect of sewage sludge on formation of acidic ground water at a reclaimed coal mine

    Science.gov (United States)

    Cravotta, C.A.

    1998-01-01

    Data on rock, ground water, vadose water, and vadose gas chemistry were collected for two years after sewage sludge was applied at a reclaimed surface coal mine in Pennsylvania to determine if surface-applied sludge is an effective barrier to oxygen influx, contributes metals and nutrients to ground water, and promotes the acidification of ground water. Acidity, sulfate, and metals concentrations were elevated in the ground water (6- to 21-m depth) from spoil relative to unmined rock because of active oxidation of pyrite and dissolution of aluminosilicate, carbonate, and Mn-Fe-oxide minerals in the spoil. Concentrations of acidity, sulfate, metals (Fe, Mn, Al, Cd, Cu, Cr, Ni, Zn), and nitrate, and abundances of iron-oxidizing bacteria were elevated in the ground water from sludge-treated spoil relative to untreated spoil having a similar mineral composition; however, gaseous and dissolved oxygen concentrations did not differ between the treatments. Abundances of iron-oxidizing bacteria in the ground water samples were positively correlated with concentrations of ammonia, nitrate, acidity, metals, and sulfate. Concentrations of metals in vadose water samples (iron-oxidizing bacteria, the oxidation of pyrite, and the acidification of ground water. Nevertheless, the overall effects on ground water chemistry from the sludge were small and probably short-lived relative to the effects from mining only.

  5. SITE-94. Geochemical characterization of Simpevarp ground waters near the Aespoe Hard Rock Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Glynn, P.D.; Voss, C.I. [US Geological Survey, Reston, VA (United States)

    1999-09-01

    The present report analyzes the geochemical data in order to evaluate collection and interpretation techniques that will be used to site the repository and to assess its safety. Ground waters near the Aespoe Hard Rock Laboratory (HRL) may be grouped into five chemically and isotopically distinct water types, on the basis of their deuterium and chloride contents: 1) recent waters, 2) 5 g/L chloride waters, 3) deep waters, 4) seawater imprint waters, and 5) glacial melt waters. The sampled ground waters show a progressive change from a predominantly NaHCO{sub 3} composition at shallow depth to a CaCl{sub 2}-rich composition at depth. Despite the proximity of the Baltic, relatively few of the sampled ground waters contain any evidence of a seawater component. This finding, together with the rather shallow depths at which saline waters were found, indicates that Aespoe island is presently in a regional ground-water discharge area. The chemical and isotopic composition of the sampled waters also indicates that local recharge of dilute recent waters occurs only down to shallow depths (generally less than 100 in). The Aespoe ground waters are sulfidic and do not presently contain any dissolved oxygen. Measured E{sub H} values are generally near -300 mV, and on average are only about 50 mV lower than E{sub H} values calculated from the sulfide/sulfate couple. Maintenance of reducing conditions, such as presently found at the Aespoe HRL, is an important consideration in assessing the performance of nuclear waste disposal sites. Measurements of dissolved radon and of uranium concentrations in fracture-fill materials were used to calculate an average effective flow-wetted surface area of 3.1 m{sup 2} per liter of water for the Aespoe site. Estimation of flow-wetted surface areas is essential in determining the importance of matrix diffusion and surface sorption processes for radionuclide release calculations. The Rn calculation technique shows promise in helping narrow the

  6. Assessment of Ground Water Quality in Rajajinagar of Bangalore

    Directory of Open Access Journals (Sweden)

    Alimuddin

    2015-04-01

    Full Text Available Water borne diseases continue to be a dominant cause of water borne morbidities and mortality all over the world. Hence, drinking water needs to be protected from pollution and biological contamination. Ground water samples were collected from ten different sampling point in Rajajinagar area of Bangalore and analysed for water quality parameters viz. pH , total alkalinity, chloride, total dissolved solids, electrical conductivity, sodium, potassium, calcium, magnesium, dissolved oxygen, BOD, COD and total hardness. The pH value of the study area ranges between 7.3 to 8.4 indicating that ground water is slightly alkaline. The total alkalinity are varied in the range from 122 to 282 mg/l which is well within the limit prescribed by BIS. The TDS value found from 397 to 546 mg/l. The values of hardness of water ranges from 125 to 267 mg/l which is within the prescribed limit as per BIS.

  7. Ground-water quality, water year 1995, and statistical analysis of ground-water-quality data, water years 1994-95, at the Chromic Acid Pit site, US Army Air Defense Artillery Center and Fort Bliss, El Paso, Texas

    Science.gov (United States)

    Abeyta, Cynthia G.; Roybal, R.G.

    1996-01-01

    The Chromic Acid Pit site is an inactive waste disposal site that is regulated by the Resource Conservation and Recovery Act of 1976. The 2.2-cubic-yard cement-lined pit was operated from 1980 to 1983 by a contractor to the U.S. Army Air Defense Artillery Center and Fort Bliss. The pit, located on the Fort Bliss military reservation in El Paso, Texas, was used for disposal and evaporation of chromic acid waste generated from chrome plating operations. The site was closed in 1989, and the Texas Natural Resources Conservation Commission issued permit number HW-50296 (U.S. Environmental Protection Agency number TX4213720101), which approved and implemented post-closure care for the Chromic Acid Pit site. In accordance with an approved post-closure plan, the U.S. Geological Survey is cooperating with the U.S. Army in monitoring and evaluating ground-water quality at the site. One upgradient ground-water monitoring well (MW1) and two downgradient ground-water monitoring wells (MW2 and MW3), installed adjacent to the chromic acid pit, are monitored on a quarterly basis. Ground-water sampling of these wells by the U.S. Geological Survey began in December 1993. The ground-water level, measured in a production well located approximately 1,700 feet southeast of the Chromic Acid Pit site, has declined about 29.43 feet from 1982 to 1995. Depth to water at the Chromic Acid Pit site in September 1995 was 284.2 to 286.5 feet below land surface; ground-water flow at the water table is assumed to be toward the southeast. Ground-water samples collected from monitoring wells at the Chromic Acid Pit site during water year 1995 contained dissolved- solids concentrations of 481 to 516 milligrams per liter. Total chromium concentrations detected above the laboratory reporting limit ranged from 0.0061 to 0.030 milligram per liter; dissolved chromium concentrations ranged from 0.0040 to 0.010 milligram per liter. Nitrate as nitrogen concentrations ranged from 2.1 to 2.8 milligrams per

  8. Ground-water resources in the lower Milliken--Sarco--Tulucay Creeks area, southeastern Napa County, California, 2000-2002

    Science.gov (United States)

    Farrar, Christopher D.; Metzger, Loren F.

    2003-01-01

    extraction produced three large pumping depressions in the northern and east-central parts of the area. The general decline in ground-water levels is a result of increases in ground-water pumpage and possibly changes in infiltration capacity caused by changes in land use. Ground-water-level declines during 1960-2002 are evident in the records for 9 of 10 key monitoring wells. In five of these wells, water levels dropped by greater than 20 feet since the 1980s. The largest water-level declines have occurred since the mid 1970s, corresponding with a period of accelerated well construction and ground-water extraction. Analysis of samples from 15 wells indicates that the chemical quality of ground water in the study generally is acceptable. However, arsenic concentrations in samples from five wells exceed the U.S. Environmental Protection Agency primary drinking-water standard of 10 micrograms per liter, and iron concentrations in samples from five wells exceed the U.S. Environmental Protection Agency and the California Department of Health Services secondary drinking-water standard of 300 micrograms per liter. Water from 12 of 15 wells sampled contained concentrations of manganese that exceed the U.S. Environmental Protection Agency and the California Department of Health Services secondary drinking-water standard of 50 micrograms per liter. Two wells produced water that had boron in excess of the California Department of Health Services action level of 1 milligram per liter. Stable isotope, chlorofluorocarbon, and tritium data indicate that ground water in the area is a mixture of waters that recharged the aquifer system at different times. The presence of chlorofluorocarbons and tritium in water from the study area is evidence that modern recharge (post 1950) does take place. Water-temperature logs indicate that ground-water temperatures throughout the study area exceed 30?C at depths in excess of 600 feet. Further, water at

  9. Reagent removal of manganese from ground water

    Science.gov (United States)

    Brayalovsky, G.; Migalaty, E.; Naschetnikova, O.

    2017-06-01

    The study is aimed at the technology development of treating drinking water from ground waters with high manganese content and oxidizability. Current technologies, physical/chemical mechanisms and factors affecting in ground treatment efficiency are reviewed. Research has been conducted on manganese compound removal from ground waters with high manganese content (5 ppm) and oxidizability. The studies were carried out on granular sorbent industrial ODM-2F filters (0.7-1.5 mm fraction). It was determined that conventional reagent oxidization technologies followed by filtration do not allow us to obtain the manganese content below 0.1 ppm when treating ground waters with high oxidizability. The innovative oxidation-based manganese removal technology with continuous introduction of reaction catalytic agent is suggested. This technology is effective in alkalization up to pH 8.8-9. Potassium permanganate was used as a catalytic agent, sodium hypochlorite was an oxidizer and cauistic soda served an alkalifying agent.

  10. Ground-water quality atlas of Wisconsin

    Science.gov (United States)

    Kammerer, Phil A.

    1981-01-01

    This report summarizes data on ground-water quality stored in the U.S. Geological Survey's computer system (WATSTORE). The summary includes water quality data for 2,443 single-aquifer wells, which tap one of the State's three major aquifers (sand and gravel, Silurian dolomite, and sandstone). Data for dissolved solids, hardness, alkalinity, calcium, magnesium, sodium, potassium, iron, manganese, sulfate, chloride, fluoride, and nitrate are summarized by aquifer and by county, and locations of wells for which data are available 1 are shown for each aquifer. Calcium, magnesium, and bicarbonate (the principal component of alkalinity) are the major dissolved constituents in Wisconsin's ground water. High iron concentrations and hardness cause ground-water quality problems in much of the State. Statewide ,summaries of trace constituent (selected trace metals; arsenic, boron, and organic carbon) concentrations show that these constituents impair water quality in only a few isolated wells.

  11. Recharge estimation for transient ground water modeling.

    Science.gov (United States)

    Jyrkama, Mikko I; Sykes, Jon F; Normani, Stefano D

    2002-01-01

    Reliable ground water models require both an accurate physical representation of the system and appropriate boundary conditions. While physical attributes are generally considered static, boundary conditions, such as ground water recharge rates, can be highly variable in both space and time. A practical methodology incorporating the hydrologic model HELP3 in conjunction with a geographic information system was developed to generate a physically based and highly detailed recharge boundary condition for ground water modeling. The approach uses daily precipitation and temperature records in addition to land use/land cover and soils data. The importance of the method in transient ground water modeling is demonstrated by applying it to a MODFLOW modeling study in New Jersey. In addition to improved model calibration, the results from the study clearly indicate the importance of using a physically based and highly detailed recharge boundary condition in ground water quality modeling, where the detailed knowledge of the evolution of the ground water flowpaths is imperative. The simulated water table is within 0.5 m of the observed values using the method, while the water levels can differ by as much as 2 m using uniform recharge conditions. The results also show that the combination of temperature and precipitation plays an important role in the amount and timing of recharge in cooler climates. A sensitivity analysis further reveals that increasing the leaf area index, the evaporative zone depth, or the curve number in the model will result in decreased recharge rates over time, with the curve number having the greatest impact.

  12. Ground water budget analysis and cross-formational leakage in an arid basin.

    Science.gov (United States)

    Hutchison, William R; Hibbs, Barry J

    2008-01-01

    Ground water budget analysis in arid basins is substantially aided by integrated use of numerical models and environmental isotopes. Spatial variability of recharge, storage of water of both modern and pluvial age, and complex three-dimensional flow processes in these basins provide challenges to the development of a good conceptual model. Ground water age dating and mixing analysis with isotopic tracers complement standard hydrogeologic data that are collected and processed as an initial step in the development and calibration of a numerical model. Environmental isotopes can confirm or refute a priori assumptions of ground water flow, such as the general assumption that natural recharge occurs primarily along mountains and mountain fronts. Isotopes also serve as powerful tools during postaudits of numerical models. Ground water models provide a means of developing ground water budgets for entire model domains or for smaller regions within the model domain. These ground water budgets can be used to evaluate the impacts of pumping and estimate the magnitude of capture in the form of induced recharge from streams, as well as quantify storage changes within the system. The coupled analyses of ground water budget analysis and isotope sampling and analysis provide a means to confirm, refute, or modify conceptual models of ground water flow.

  13. Hanford Site ground-water monitoring for July through December 1987

    Energy Technology Data Exchange (ETDEWEB)

    Evans, J.C.; Dennison, D.I.; Bryce, R.W.; Mitchell, P.J.; Sherwood, D.R.; Krupka, K.M.; Hinman, N.W.; Jacobson, E.A.; Freshley, M.D.

    1988-12-01

    The Pacific Northwest Laboratory monitors ground-water quality at the Hanford Site for the US Department of Energy to assess the impact of Site operations on the environment. Work undertaken between July and December 1987 included monitoring ground-water elevations across the Site, monitoring hazardous chemicals and radionuclides in ground water, geochemical evaluations of unconfined ground-water data, and calibration of ground-water flow and transport models. Water levels continued to rise in areas receiving increased recharge (e.g., beneath B Pond) and decline in areas where the release of water to disposal facilities has been terminated (e.g., U Pond). The major areas of ground-water contamination defined by monitoring activities are (1) carbon tetrachloride in the 200-West Area; (2) cyanide in and north of the 200-East and 200-West Areas; (3) hexavalent chromium contamination in the 100-B, 100-D, 100-F, 100-H, 100-K, and 200-West Areas; (4) chlorinated hydrocarbons in the vicinity of the Central Landfill and 300 Area; (5) uranium in the 100-F, 100-H, 200-West, and 300 Areas; and (6) tritium and nitrate across the Site. The MINTEQ geochemical code was used to identify chemical reactions that may be affecting the concentrations of dissolved hazardous chemicals in the unconfined ground water. Results indicate that many cations are present mainly as dissolved carbonate complexes and that a majority of the ground-water samples are in near equilibrium with carbonate minerals (e.g., calcite, dolomite, otavite).

  14. Environmental and ground-water surveillance at Hanford

    Energy Technology Data Exchange (ETDEWEB)

    Dirkes, R.L.; Luttrell, S.P.

    1995-06-01

    Environmental and ground-water surveillance of the Hanford Site and surrounding region is conducted to demonstrate compliance with environmental regulations, confirm adherence to DOE environmental protection policies, support DOE environmental management decisions, and provide information to the public. Environmental surveillance encompasses sampling and analyzing for potential radiological and nonradiological chemical contaminants on and off the Hanford Site. Emphasis is placed on surveillance of exposure pathways and chemical constituents that pose the greatest risk to human health and the environment.

  15. Ground water discharge and the related nutrient and trace metal fluxes into Quincy Bay, Massachusetts

    Science.gov (United States)

    Poppe, L.J.; Moffett, A.M.

    1993-01-01

    Measurement of the rate and direction of ground water flow beneath Wollaston Beach, Quincy, Massachusetts by use of a heat-pulsing flowmeter shows a mean velocity in the bulk sediment of 40 cm d-1. The estimated total discharge of ground water into Quincy Bay during October 1990 was 1324-2177 m3 d-1, a relatively low ground Water discharge rate. The tides have only a moderate effect on the rate and direction of this flow. Other important controls on the rate and volume of ground water flow are the limited thickness, geographic extent, and permeability of the aquifer. Comparisons of published streamflow data and estimates of ground water discharge indicate that ground water makes up between 7.4-12.1% of the gaged freshwater input into Quincy Bay. The data from this study suggest the ground water discharge is a less important recharge component to Quincy Bay than predicted by National Urban Runoff Program (NURP) models. The high nitrate and low nitrite and ammonia concentrations in the ground water at the backshore we]l sites and low nitrate and high nitrite and ammonia concentrations in the water flowing from the foreshore suggests that denitrification is active in the sediments. The low ground water flow rates and low nitrate concentrations in the foreshore samples suggest that little or no nitrate is surviving the denitrification process to affect the planktonic community. Similarly, oxidizing conditions in the aquifer and low trace metal concentrations in the ground water samples suggest that the metals may be precipitating and binding to sedimentary phases before impacting the bay.

  16. 40 CFR 257.22 - Ground-water monitoring systems.

    Science.gov (United States)

    2010-07-01

    ... operator. When physical obstacles preclude installation of ground-water monitoring wells at the relevant... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water monitoring systems. 257... Waste Disposal Units Ground-Water Monitoring and Corrective Action § 257.22 Ground-water......

  17. Overview of investigations into mercury in ground water, soils, and septage, New Jersey coastal plain

    Science.gov (United States)

    Barringer, J.L.; Szabo, Z.

    2006-01-01

    Since the early 1980s, investigations by health departments of eight counties in southern New Jersey, by the NJ Department of Environmental Protection (NJDEP), and subsequently by the US Geological Survey (USGS), have shown that Hg concentrations in water tapped by about 600 domestic wells exceed the maximum contaminant level (MCL) of 2 ??g/L. The wells are finished in the areally extensive unconfined Kirkwood-Cohansey aquifer system of New Jersey's Coastal Plain; background concentrations of Hg in water from this system are point sources of Hg, such as landfills or commercial and industrial hazardous-waste sites, is lacking. During 1996-2003, the USGS collected water samples from 203 domestic, irrigation, observation, and production wells using ultraclean techniques; septage, leach-field effluent, soils, and aquifer sediments also were sampled. Elevated concentrations of NH4, B, Cl, NO3, and Na and presence of surfactants in domestic-well water indicate that septic-system effluent can affect water quality in unsewered residential areas, but neither septage nor effluent appears to be a major Hg source. Detections of hydrogen sulfide in ground water at a residential area indicate localized reducing conditions; undetectable SO4 concentrations in water from other residential areas indicate that reducing conditions, which could be conducive to Hg methylation, may be common locally. Volatile organic compounds (VOCs), mostly chlorinated solvents, also are found in ground water at the affected areas, but statistically significant associations between presence of Hg and VOCs were absent for most areas evaluated. Hg concentrations are lower in some filtered water samples than in paired unfiltered samples, likely indicating that some Hg is associated with particles or colloids. The source of colloids may be soils, which, when undisturbed, contain higher concentrations of Hg than do disturbed soils and aquifer sediments. Soil disturbance during residential development and

  18. Selenium speciation in ground water

    Energy Technology Data Exchange (ETDEWEB)

    Atalay, A.

    1990-07-10

    Selenium toxicity diseases in animals may occur when the intake exceeds 4 mg/kg and selenium deficiency symptoms may occur when dietary intake is less than 0.04 mg/kg. Since the selenium dietary requirement is very close to toxic concentration, it is important to understand the distribution of selenium in the environment. Selenium occurs in four oxidation states (-II, 0, +IV, and +VI) as selenide, elemental selenium, selenite and selenate. Selenate is reported as more soluble and less adsorbed than selenite. Selenate is more easily leached from soils and is the most available form for plants. Increased mobility of Se into the environment via anthropogenic activities, and the potential oxidation-reduction behavior of the element have made it imperative to study the aquatic chemistry of Se. For this purpose, Se species are divided into two different categories: dissolved Se (in material that passes through filters with 0.45 u openings) and particulate Se (in material of particle size > 0.45 mm) typically suspended sediment and other suspended solids. Element and colloidal phase, not truly dissolved, but passing through the filter is deemed to consist of selenium (-2,0). In dissolved state selenium may exist in three of its four oxidation states; Se(-II), Se(+IV), and Se(+VI). Particulate Se may exist in the same oxidation states as dissolved Se and can be found in different phases of the particulate matter. In sediments, Se may be within the organic material, iron and manganese oxides, carbonates or other mineral phases. The actual chemical forms of Se may be adsorbed to or coprecipitated with these phases (primarily selenite, SeO{sub 3}{sup 2{minus}}) and selenate, SeO{sub 4}{sup 2{minus}}. Selenide, Se(-II), can be covalently bound in the organic portion of a sediment. In addition, Se may be found in anoxic sediments as insoluble metal selenide precipitates, an insoluble elemental Se or as ferroselite (FeSe{sub 2}) and Se containing pyrite.

  19. Ground-water conditions and studies in Georgia, 2001

    Science.gov (United States)

    Leeth, David C.; Clarke, John S.; Craigg, Steven D.; Wipperfurth, Caryl J.

    2003-01-01

    the Upper Floridan aquifer. Ground-water quality in the Upper Floridan aquifer is monitored in the cities of Albany, Savannah, and Brunswick and in Camden County; and monitored in the Lower Floridan aquifer in the Savannah and Brunswick areas. In the Albany area since 1998, nitrate concentrations in the Upper Floridan aquifer have increased in 4 of the 11 wells monitored, and in 1 well, concentrations were above the U.S. Environmental Protection Agency's (USEPA) 10 milligrams per liter (mg/L) drinking-water standard. In the Savannah area, chloride concentration in water from four wells in the Upper Floridan aquifer showed no appreciable change during 2001, remaining within the USEPA 250 mg/L drinking-water standard; in seven wells completed in the Lower Floridan aquifer and in underlying zones, the chloride concentration remained above the drinking-water standard, with one well showing an increase over previous years. In the Brunswick area, water samples from 66 wells completed in the Upper or Lower Floridan aquifers were collected during June 2001 and analyzed for chloride. A map showing chloride concentrations in the Upper Floridan aquifer during June 2001 indicates that concentrations remained above USEPA drinking-water standards across a 2-square-mile area. In the north Brunswick area, chloride concentrations in the Upper Floridan aquifer continued to increase, whereas in the south Brunswick area, concentrations continued to decrease. In the Camden County area, chloride concentrations in six wells completed in the Upper Floridan aquifer remained within drinking-water standards. With the exception of one well, concentrations remained the same and were below 40 mg/L. In one well, concentrations showed a sharp decline during 2001, but remained above 130 mg/L. Ongoing studies during 2001 include evaluation of agricultural chemicals in shallow ground water in southwestern Georgia; evaluation of saltwater intrusion and water-level and water-quality m

  20. Estimation of ground water hydraulic parameters

    Energy Technology Data Exchange (ETDEWEB)

    Hvilshoej, Soeren

    1998-11-01

    The main objective was to assess field methods to determine ground water hydraulic parameters and to develop and apply new analysis methods to selected field techniques. A field site in Vejen, Denmark, which previously has been intensively investigated on the basis of a large amount of mini slug tests and tracer tests, was chosen for experimental application and evaluation. Particular interest was in analysing partially penetrating pumping tests and a recently proposed single-well dipole test. Three wells were constructed in which partially penetrating pumping tests and multi-level single-well dipole tests were performed. In addition, multi-level slug tests, flow meter tests, gamma-logs, and geologic characterisation of soil samples were carried out. In addition to the three Vejen analyses, data from previously published partially penetrating pumping tests were analysed assuming homogeneous anisotropic aquifer conditions. In the present study methods were developed to analyse partially penetrating pumping tests and multi-level single-well dipole tests based on an inverse numerical model. The obtained horizontal hydraulic conductivities from the partially penetrating pumping tests were in accordance with measurements obtained from multi-level slug tests and mini slug tests. Accordance was also achieved between the anisotropy ratios determined from partially penetrating pumping tests and multi-level single-well dipole tests. It was demonstrated that the partially penetrating pumping test analysed by and inverse numerical model is a very valuable technique that may provide hydraulic information on the storage terms and the vertical distribution of the horizontal and vertical hydraulic conductivity under both confined and unconfined aquifer conditions. (EG) 138 refs.

  1. Ground Water Flow No Longer A Mystery

    Science.gov (United States)

    Lehr, Jay H.; Pettyjohn, Wayne A.

    1976-01-01

    Examined are the physical characteristics of ground water movement. Some potential pollution problems are identified. Models are used to explain mathematical and hydraulic principles of flow toward a pumping well and an effluent stream, flow around and through lenticular beds, and effects of pumping on the water table. (Author/MR)

  2. Depth to ground water of Nevada

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This is a raster-based, depth to ground-water data set for the State of Nevada. The source of this data set is a statewide water-table contour data set constructed...

  3. Reconnaissance investigation of petroleum products in soil and ground water at Longmire, Mount Rainier National Park, Washington, 1990

    Science.gov (United States)

    Sumioka, S.S.

    1995-01-01

    The removal of an underground waste-oil storage tank in Mount Rainier National Park, at Longmire, Washington, led to the discovery that soil surrounding the tank was saturated with unidentified petroleum hydrocarbons. Subsequent investigations by the National Park Service indicated that a petroleum product smelling like diesel oil was present in the unsaturated zone as far as 120 feet from the tank site. A study was conducted by the U.S. Geological Survey in cooperation with the National Park Service to determine the extent to which the petroleum hydrocarbons have affected the unsaturated zone and ground water in the Longmire area. Measurements of water levels in wells and of water-surface elevations of the Nisqually River and a wetland west of Longmire indicate that ground water does not flow from the maintenance area to the river or to the wetland. Waste oil and diesel oil were detected in soil samples from the site closest to the waste-oil storage-tank site. Diesel oil was also detected in samples from a site about 200 feet northwest of the storage-tank site. Organic compounds of undetermined origin were detected in soil samples from all of the other sites. Waste oil was not conclusively detected in any of the ground-water samples. Diesel oil was detected in water samples from the well closest to the storage tank and from a well about 200 feet west of the storage-tank site. Ground-water samples from all of the other wells contained organic compounds of undetermined origin.

  4. Chemical reactions of uranium in ground water at a mill tailings site

    Science.gov (United States)

    Abdelouas, A.; Lutze, W.; Nuttall, E.

    1998-11-01

    We studied soil and ground water samples from the tailings disposal site near Tuba City, AZ, located on Navajo sandstone, in terms of uranium adsorption and precipitation. The uranium concentration is up to 1 mg/l, 20 times the maximum concentration for ground water protection in the United States. The concentration of bicarbonate (HCO 3-) in the ground water increased from ≤7×10 -4 M, the background concentration, to 7×10 -3 M. Negatively charged uranium carbonate complexes prevail at high carbonate concentrations and uranium is not adsorbed on the negatively charged mineral surfaces. Leaching experiments using contaminated and uncontaminated sandstone and 1 N HCl show that adsorption of uranium from the ground water is negligible. Batch adsorption experiments with the sandstone and ground water at 16°C, the in situ ground water temperature, show that uranium is not adsorbed, in agreement with the results of the leaching experiments. Adsorption of uranium at 16°C is observed when the contaminated ground water is diluted with carbonate-free water. The observed increase in pH from 6.7 to 7.3 after dilution is too small to affect adsorption of uranium on the sandstone. Storage of undiluted ground water to 24°C, the temperature in the laboratory, causes coprecipitation of uranium with aragonite and calcite. Our study provides knowledge of the on-site uranium chemistry that can be used to select the optimum ground water remediation strategy. We discuss our results in terms of ground water remediation strategies such as pump and treat, in situ bioremediation, steam injection, and natural flushing.

  5. Vulnerability of ground water to contamination, northern Bexar County, Texas

    Science.gov (United States)

    Clark, Amy R.

    2003-01-01

    soils in the study area are uniformly thin, they have only minimal effect on the vulnerability of ground water to contamination.The results of hydrogeologic mapping during the present study divide the outcrop of the Glen Rose Limestone into five mappable intervals, labeled (youngest to oldest) A through E. Of these intervals, only the middle (C) and the lowermost (E) generally provide appreciable permeability.The vulnerability assessment provided herein was determined by combining the presumed effects of selected natural features (with individual vulnerability ratings ranging from 0 through 35) using a grid-based, multilayer system of digital datasets and geographic information system analysis. The resulting vulnerability map comprises composite vulnerability ratings that range from 26 through 104. The relatively less vulnerable areas those containing no faults, sinkholes, or caves occupy about 92 percent of the study area. The most vulnerable areas are those containing both a fault and one or more caves. The distribution of the most vulnerable areas which trend from southwest to northeast, roughly parallel to the Balcones fault zone occur mainly where faults intersect caves.

  6. (Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio)

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    This report presents information concerning field procedures employed during the monitoring, well construction, well purging, sampling, and well logging at the Wright-Patterson Air Force Base. Activities were conducted in an effort to evaluate ground water contamination.

  7. General and Localized corrosion of Austenitic and Borated Stainless Steels in Simulated Concentrated Ground Waters

    Energy Technology Data Exchange (ETDEWEB)

    D. Fix; J. Estill; L. Wong; R. Rebak

    2004-05-28

    Boron containing stainless steels are used in the nuclear industry for applications such as spent fuel storage, control rods and shielding. It was of interest to compare the corrosion resistance of three borated stainless steels with standard austenitic alloy materials such as type 304 and 316 stainless steels. Tests were conducted in three simulated concentrated ground waters at 90 C. Results show that the borated stainless were less resistant to corrosion than the witness austenitic materials. An acidic concentrated ground water was more aggressive than an alkaline concentrated ground water.

  8. General and Localized Corrosion of Austenitic And Borated Stainless Steels in Simulated Concentrated Ground Waters

    Energy Technology Data Exchange (ETDEWEB)

    Estill, J C; Rebak, R B; Fix, D V; Wong, L L

    2004-03-11

    Boron containing stainless steels are used in the nuclear industry for applications such as spent fuel storage, control rods and shielding. It was of interest to compare the corrosion resistance of three borated stainless steels with standard austenitic alloy materials such as type 304 and 316 stainless steels. Tests were conducted in three simulated concentrated ground waters at 90 C. Results show that the borated stainless were less resistant to corrosion than the witness austenitic materials. An acidic concentrated ground water was more aggressive than an alkaline concentrated ground water.

  9. Estrogen and androgen receptor activities of hydraulic fracturing chemicals and surface and ground water in a drilling-dense region

    Science.gov (United States)

    Kassotis, Christopher D.; Tillitt, Donald E.; Davis, J. Wade; Hormann, Anette M.; Nagel, Susan C.

    2014-01-01

    The rapid rise in natural gas extraction using hydraulic fracturing increases the potential for contamination of surface and ground water from chemicals used throughout the process. Hundreds of products containing more than 750 chemicals and components are potentially used throughout the extraction process, including more than 100 known or suspected endocrine-disrupting chemicals. We hypothesized thataselected subset of chemicalsusedin natural gas drilling operationsandalso surface and ground water samples collected in a drilling-dense region of Garfield County, Colorado, would exhibit estrogen and androgen receptor activities. Water samples were collected, solid-phase extracted, and measured for estrogen and androgen receptor activities using reporter gene assays in human cell lines. Of the 39 unique water samples, 89%, 41%, 12%, and 46% exhibited estrogenic, antiestrogenic, androgenic, and antiandrogenic activities, respectively. Testing of a subset of natural gas drilling chemicals revealed novel antiestrogenic, novel antiandrogenic, and limited estrogenic activities. The Colorado River, the drainage basin for this region, exhibited moderate levels of estrogenic, antiestrogenic, and antiandrogenic activities, suggesting that higher localized activity at sites with known natural gas–related spills surrounding the river might be contributing to the multiple receptor activities observed in this water source. The majority of water samples collected from sites in a drilling-dense region of Colorado exhibited more estrogenic, antiestrogenic, or antiandrogenic activities than reference sites with limited nearby drilling operations. Our data suggest that natural gas drilling operationsmayresult in elevated endocrine-disrupting chemical activity in surface and ground water.

  10. Detection of Ground Water Availability at Buhias Island, Sitaro Regency

    Directory of Open Access Journals (Sweden)

    Zetly E Tamod

    2016-08-01

    Full Text Available The study aims to detect ground water availability at Buhias Island, Siau Timur Selatan District, Sitaro Regency. The research method used the survey method by geoelectrical instrument based on subsurface rock resistivity as a geophysical exploration results with geoelectrical method of Wenner-Schlumberger configuration. Resistivity geoelectrical method is done by injecting a flow into the earth surface, then it is measured the potential difference. This study consists of 4 tracks in which each track is made the stretch model of soil layer on subsurface of ground.  Then, the exploration results were processed using software RES2DINV to look at the data of soil layer based on the value of resistivity (2D. Interpretation result of the track 1 to 4 concluded that there is a layer of ground water. State of dominant ground water contains the saline (brackish. Location of trajectory in the basin to the lowland areas is mostly mangrove swamp vegetation. That location is the junction between the results of the runoff of rainfall water that falls down from the hills with sea water. Bedrock as a constituent of rock layer formed from marine sediments that carry minerals salts.

  11. Isotopic composition of ground waters from Kufra (Lybia) as indicator for ground water formation

    Energy Technology Data Exchange (ETDEWEB)

    Swailem, F.M.; Hamza, M.S.; Aly, A.I.M. (Middle Eastern Regional Radioisotope Centre for the Arab Countries, Cairo (Egypt))

    1984-02-01

    The results of the isotopic composition of shallow and deep ground waters from the Kufra region indicate the fossil origin of these waters and that they are not recharged under the present climatic conditions. The virtual absence of tritium and the radiocarbon ages of these waters show that they were formed mainly in the past pluvial periods. Deuterium and oxygen-18 data indicate that the ground waters were recharged under cooler climatic conditions. These results may explain the origin of the large amounts of ground water which existed in the region.

  12. Precipitation; ground-water age; ground-water nitrate concentrations, 1995-2002; and ground-water levels, 2002-03 in Eastern Bernalillo County, New Mexico

    Science.gov (United States)

    Blanchard, Paul J.

    2004-01-01

    The eastern Bernalillo County study area consists of about 150 square miles and includes all of Bernalillo County east of the crests of the Sandia and Manzanita Mountains. Soil and unconsolidated alluvial deposits overlie fractured and solution-channeled limestone in most of the study area. North of Interstate Highway 40 and east of New Mexico Highway 14, the uppermost consolidated geologic units are fractured sandstones and shales. Average annual precipitation at three long-term National Oceanic and Atmospheric Administration precipitation and snowfall data-collection sites was 14.94 inches at approximately 6,300 feet (Sandia Ranger Station), 19.06 inches at about 7,020 feet (Sandia Park), and 23.07 inches at approximately 10,680 feet (Sandia Crest). The periods of record at these sites are 1933-74, 1939-2001, and 1953-79, respectively. Average annual snowfall during these same periods of record was 27.7 inches at Sandia Ranger Station, 60.8 inches at Sandia Park, and 115.5 inches at Sandia Crest. Seven precipitation data-collection sites were established during December 2000-March 2001. Precipitation during 2001-03 at three U.S. Geological Survey sites ranged from 66 to 94 percent of period-of-record average annual precipitation at corresponding National Oceanic and Atmospheric Administration long-term sites in 2001, from 51 to 75 percent in 2002, and from 34 to 81 percent during January through September 2003. Missing precipitation records for one site resulted in the 34-percent value in 2003. Analyses of concentrations of chlorofluorocarbons CFC-11, CFC-12, and CFC-113 in ground-water samples from nine wells and one spring were used to estimate when the sampled water entered the ground-water system. Apparent ages of ground water ranged from as young as about 10 to 16 years to as old as about 20 to 26 years. Concentrations of dissolved nitrates in samples collected from 24 wells during 2001-02 were similar to concentrations in samples collected from the same

  13. Automated Ground-Water Sampling and Analysis of Hexavalent Chromium using a “Universal” Sampling/Analytical System

    Directory of Open Access Journals (Sweden)

    Richard J. Venedam

    2005-02-01

    Full Text Available The capabilities of a “universal platform” for the deployment of analyticalsensors in the field for long-term monitoring of environmental contaminants were expandedin this investigation. The platform was previously used to monitor trichloroethene inmonitoring wells and at groundwater treatment systems (1,2. The platform was interfacedwith chromium (VI and conductivity analytical systems to monitor shallow wells installedadjacent to the Columbia River at the 100-D Area of the Hanford Site, Washington. Agroundwater plume of hexavalent chromium is discharging into the Columbia River throughthe gravels beds used by spawning salmon. The sampling/analytical platform was deployedfor the purpose of collecting data on subsurface hexavalent chromium concentrations atmore frequent intervals than was possible with the previous sampling and analysis methodsemployed a the Site.

  14. Radium and radon in ground water in the Chickies Quartzite, southeastern Pennsylvania

    Science.gov (United States)

    Senior, L.A.; Vogel, K.L.

    1995-01-01

    The Chickies Quartzite, a Lower Cambrian-age formation compromised of quartzite and slate overlying a basal conglomerate, forms a narrow ridges and crops out discontinuously over 112 square miles in the Piedmont physiographic province of southeastern Pennsylvania. The formation is a low-yielding, fractured- rock, water-table aquifer recharged primarily by local precipitation. It is the sole source of water supply for thousands of domestic users. Ground water in the Chickies Quartzite generally is soft and acidic. During 1986-88, the U.S. Geological Survey sampled water from 160 wells that penetrate the Chickies Quartzite to determine the magnitude and distribution of radium-226 (Ra-226), radium-228 (Ra-228), and radon-222 (Rn-222) activities in ground water in the formation and to characterize the geochemical environmental associated with elevated activities of radium (Ra). In addition, 28 wells penetrating adjacent geologic units and 1 well in the Hardyston Quartzite were sampled to determine relative background Ra and RN-222 activities in ground water. Analyses included determination of activities of dissolved Ra-226, Ra-228, and RN-222, and concentrations of dissolved uranium (U), dissolved organic carbon (DOC), and major and minor dissolved inorganic ions. Rock samples were analyzed for U and thorium (Th) and geophysical logs were run to determine sources of Ra and RN-222 in the Chickies Quartzite. Activities of up to 41 pCi/L (picocuries per liter) for Ra-226, 160 pCi/L for Ra-228, and 32,300 pCi/L for RN-222 were measured in ground water in the Chickies Quartzite. Forty-seven percent of the samples contained Ra-226 and Ra-228 activities greater than 5 pCi/L. Median activities measured were 1.2 pCi/L for Ra-226, 2.6 pCi/L for Ra-228, 4.2 pCi/L for combined Ra-226 and Ra-228, and 2,400 pCi/L for RN-222 Ra-228 activity exceeded Ra-226 activity in about 92 percent of 100 water samples; the median Ra-228/Ra226 activity ratio was 2.4. Ra-228/Ra-226 activity ratios

  15. [Metal contamination of the ground water in Mohammedia (Morocco)].

    Science.gov (United States)

    Serghini, Amal; Fekhaoui, Mohammed; El Abidi, Abdellah; Tahri, Latifa; Bouissi, Mostafa; El Houssine, Zaid

    2003-01-01

    This aim of this study was to assess the heavy metal contamination of the ground water in the Moroccan city of Mohammedia and its relation to the highly developed industrial and domestic activities in the region. Six heavy metals, Cu, Zn, Cd, Hg, Fe and Pb, were assayed in the waters of 19 wells throughout the city, in industrial areas, public landfills, and residential zones. Four sampling campaigns were conducted between January and May 1999. Analysis of the heavy metal levels revealed a causal relation between the human activities at the sites studied and the degree of contamination recorded. The sites in the industrial areas had elevated concentrations of Fe, Zn, Cu or Pb and most often a combination of at least two of these at a single site. Moreover, the spatial distribution of this pollution showed water in S7 areas to be high in iron and that in S5 and S7 (industrial) areas high in mercury. The concentrations measured are respectively 2.5 and 3-5 times greater than the Maximum Acceptable Concentration (MAC) recommended by WHO for potable water. This work has conclusively proven the presence of dangerous heavy metal contamination of the ground water supply in the area of Mohammedia; it demonstrates the need for conservation and antipollution measures aimed against heavy metal contamination of the overall water supply and in particular the ground water.

  16. Assessment of nitrification potential in ground water using short term, single-well injection experiments.

    Science.gov (United States)

    Smith, R L; Baumgartner, L K; Miller, D N; Repert, D A; Böhlke, J K

    2006-01-01

    Nitrification was measured within a sand and gravel aquifer on Cape Cod, MA, using a series of single-well injection tests. The aquifer contained a wastewater-derived contaminant plume, the core of which was anoxic and contained ammonium. The study was conducted near the downgradient end of the ammonium zone, which was characterized by inversely trending vertical gradients of oxygen (270 to 0 microM) and ammonium (19 to 625 microM) and appeared to be a potentially active zone for nitrification. The tests were conducted by injecting a tracer solution (ambient ground water + added constituents) into selected locations within the gradients using multilevel samplers. After injection, the tracers moved by natural ground water flow and were sampled with time from the injection port. Rates of nitrification were determined from changes in nitrate and nitrite concentration relative to bromide. Initial tests were conducted with (15)N-enriched ammonium; subsequent tests examined the effect of adding ammonium, nitrite, or oxygen above background concentrations and of adding difluoromethane, a nitrification inhibitor. In situ net nitrate production exceeded net nitrite production by 3- to 6- fold and production rates of both decreased in the presence of difluoromethane. Nitrification rates were 0.02-0.28 mumol (L aquifer)(-1) h(-1) with in situ oxygen concentrations and up to 0.81 mumol (L aquifer)(-1) h(-1) with non-limiting substrate concentrations. Geochemical considerations indicate that the rates derived from single-well injection tests yielded overestimates of in situ rates, possibly because the injections promoted small-scale mixing within a transport-limited reaction zone. Nonetheless, these tests were useful for characterizing ground water nitrification in situ and for comparing potential rates of activity when the tracer cloud included non-limiting ammonium and oxygen concentrations.

  17. U.S. Geological Survey ground-water studies in Illinois

    Science.gov (United States)

    Avery, Charles F.

    1994-01-01

    Ground water is an important source of water supply in Illinois. The largest amount of ground*water withdrawal is in the northern one-third of the State where aquifers to a depth of about 1,500 feet below land surface contain large quantities of potable water. Approximately 74 percent of the public water-supply systems in Illinois use ground water to supply potable water to more than 5.5 million people. Ground-water withdrawals account for almost 25 percent of the total water withdrawn for public water supplies in Illinois. Many public water-supply systems in the Chicago area have recently changed from using ground water pumped from wells to using water delivered from Lake Michigan. The major issues related to ground water in Illinois are: Water- quality degradation or contamination from point and nonpoint sources, and Water availability, because of the lowering of ground-water levels in the bedrock aquifers in northeastern Illinois and elsewhere in the State where pumpage has exceeded aquifer recharge and the susceptibility of the limited surface-water supplies in central and southern Illinois to drought.

  18. Ground-water data for the Riley and Andrews Resource Areas, southeastern Oregon

    Science.gov (United States)

    Townley, Paul J.; Soja, Constance M.; Sidle, W.C.

    1980-01-01

    Appraisals of the resources of selected management areas in eastern Oregon are being made by the U.S. Bureau of Land Mangement. To provide needed hydrologic information, the Bureau of Land Management requested the U.S. Geological Survey to inventory ground-water data for the Riley and Andrews Resource Areas. The inventory included field location of selected wells and springs; measurement of ground-water levels, temperatures, specific conductance, and pH; and the collection of ground-water samples from selected sources to determine dissolved chemical constituents.

  19. Geohydrology, Geochemistry, and Ground-Water Simulation-Optimization of the Central and West Coast Basins, Los Angeles County, California

    Science.gov (United States)

    Reichard, Eric G.; Land, Michael; Crawford, Steven M.; Johnson, Tyler D.; Everett, Rhett; Kulshan, Trayle V.; Ponti, Daniel J.; Halford, Keith L.; Johnson, Theodore A.; Paybins, Katherine S.; Nishikawa, Tracy

    2003-01-01

    Historical ground-water development of the Central and West Coast Basins in Los Angeles County, California through the first half of the 20th century caused large water-level declines and induced seawater intrusion. Because of this, the basins were adjudicated and numerous ground-water management activities were implemented, including increased water spreading, construction of injection barriers, increased delivery of imported water, and increased use of reclaimed water. In order to improve the scientific basis for these water management activities, an extensive data collection program was undertaken, geohydrological and geochemical analyses were conducted, and ground-water flow simulation and optimization models were developed. In this project, extensive hydraulic, geologic, and chemical data were collected from new multiple-well monitoring sites. On the basis of these data and data compiled and collected from existing wells, the regional geohydrologic framework was characterized. For the purposes of modeling, the three-dimensional aquifer system was divided into four aquifer systems?the Recent, Lakewood, Upper San Pedro, and Lower San Pedro aquifer systems. Most pumpage in the two basins is from the Upper San Pedro aquifer system. Assessment of the three-dimensional geochemical data provides insight into the sources of recharge and the movement and age of ground water in the study area. Major-ion data indicate the chemical character of water containing less than 500 mg/L dissolved solids generally grades from calcium-bicarbonate/sulfate to sodium bicarbonate. Sodium-chloride water, high in dissolved solids, is present in wells near the coast. Stable isotopes of oxygen and hydrogen provide information on sources of recharge to the basin, including imported water and water originating in the San Fernando Valley, San Gabriel Valley, and the coastal plain and surrounding hills. Tritium and carbon-14 data provide information on relative ground-water ages. Water with

  20. Geochemical characterization of shallow ground water in the Eutaw aquifer, Montgomery, Alabama

    Science.gov (United States)

    Robinson, J.L.; Journey, C.A.

    2004-01-01

    Ground water samples were collected from 30 wells located in, or directly down gradient from, recharge areas of the Eutaw aquifer in Montgomery, Alabama. The major ion content of the water evolves from calcium-sodium-chloride- dominated type in the recharge area to calcium-bicarbonate-dominated type in the confined portion of the aquifer. Ground water in the recharge area was undersaturated with respect to aluminosilicate and carbonate minerals. Ground water in the confined portion of the aquifer was at equilibrium levels for calcite and potassium feldspar. Dissolved oxygen and nitrite-plus-nitrate concentrations decreased as ground water age increased; pH, iron, and sulfate concentrations increased as ground water age increased. Aluminum, copper, and zinc concentrations decreased as ground water age and pH increased. These relations indicate that nitrate, aluminum, copper, and zinc are removed from solution as water moves from recharge areas to the confined areas of the Eutaw aquifer. The natural evolution of ground water quality, which typically increases the pH and decreases the dissolved oxygen content, may be an important limiting factor to the migration of nitrogen based compounds and metals.

  1. Case study on ground water flow (8)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-02-01

    The report comprises research activities made in fiscal year 1997 under the contract of Japan Nuclear Fuel Cycle Development Center and the main items are: (1) Evaluation of water permeability through discontinuous hard bedrock in deep strata in relevant with underground disposal of radioactive wastes, (2) Three dimensional analysis of permeated water in bedrock, including flow analysis in T ono district using neuro-network and modification of Evaporation Logging System, (3) Development of hydraulic tests and necessary equipment applicable to measurements of complex dielectric constants of contaminated soils using FUDR-V method, this giving information on soil component materials, (4) Investigation methods and modeling of hydraulics in deep strata, (5) Geological study of ground water using environmental isotopes such as {sup 14}C, {sup 36}Cl and {sup 4}He, particularly measurement of ages of ground water using an accelerator-mass spectrometer, and (6) Re-submerging phenomena affecting the long-term geological stability. (S. Ohno)

  2. Artificial Ground Water Recharge with Surface Water

    Science.gov (United States)

    Heviánková, Silvie; Marschalko, Marian; Chromíková, Jitka; Kyncl, Miroslav; Korabík, Michal

    2016-10-01

    With regard to the adverse manifestations of the recent climatic conditions, Europe as well as the world have been facing the problem of dry periods that reduce the possibility of drawing drinking water from the underground sources. The paper aims to describe artificial ground water recharge (infiltration) that may be used to restock underground sources with surface water from natural streams. Among many conditions, it aims to specify the boundary and operational conditions of the individual aspects of the artificial ground water recharge technology. The principle of artificial infiltration lies in the design of a technical system, by means of which it is possible to conduct surplus water from one place (in this case a natural stream) into another place (an infiltration basin in this case). This way, the water begins to infiltrate into the underground resources of drinking water, while the mixed water composition corresponds to the water parameters required for drinking water.

  3. Case study on ground water flow (8)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-02-01

    The report comprises research activities made in fiscal year 1997 under the contract of Japan Nuclear Fuel Cycle Development Center and the main items are: (1) Evaluation of water permeability through discontinuous hard bedrock in deep strata in relevant with underground disposal of radioactive wastes, (2) Three dimensional analysis of permeated water in bedrock, including flow analysis in T ono district using neuro-network and modification of Evaporation Logging System, (3) Development of hydraulic tests and necessary equipment applicable to measurements of complex dielectric constants of contaminated soils using FUDR-V method, this giving information on soil component materials, (4) Investigation methods and modeling of hydraulics in deep strata, (5) Geological study of ground water using environmental isotopes such as {sup 14}C, {sup 36}Cl and {sup 4}He, particularly measurement of ages of ground water using an accelerator-mass spectrometer, and (6) Re-submerging phenomena affecting the long-term geological stability. (S. Ohno)

  4. Nitrate Removal from Ground Water: A Review

    OpenAIRE

    Archna *; Surinder K. Sharma; Ranbir Chander Sobti

    2012-01-01

    Nitrate contamination of ground water resources has increased in Asia, Europe, United States, and various other parts of the world. This trend has raised concern as nitrates cause methemoglobinemia and cancer. Several treatment processes can remove nitrates from water with varying degrees of efficiency, cost, and ease of operation. Available technical data, experience, and economics indicate that biological denitrification is more acceptable for nitrate removal than reverse osmosis and ion ex...

  5. Physical and chemical data for ground water in the Michigan basin, 1986-89

    Science.gov (United States)

    Dannemiller, G.T.; Baltusis, M.A.

    1990-01-01

    Ground-water samples were collected from 459 wells located in the Michigan basin as part of a Regional Aquifer-System Analysis. Data on the physical and chemical characteristics of 476 ground-water samples from these wells represent ground-water characteristics in the Berea Sandstone, Coldwater Shale, Marshall Sandstone, Michigan Formation, Bayport Limestone, Saginaw Formation, Grand River Formation, and glacial deposits. Ground-water samples were measured in the Geld for specific conductance, temperature, and alkalinity. Analyses of ground water for concentrations of dissolved oxygen, ferrous iron, total iron, and sulfide were also done in the field. Additional laboratory analysis provided data on eight major and 18 minor inorganic constituents. Twenty-one samples were analyzed for tritium, 140 samples were analyzed for carbon-13, and 19 samples were analyzed for carbon-14. The stable-isotope ratio of deuterium to hydrogen was determined for 408 samples; the ratio of oxygen-18 to oxygen-16 was determined for 433 samples; and the ratio of sulfur-34 to sulfur-32 was determined for 20 samples. Sixteen samples were analyzed for the unstable isotopes of uranium; 13 samples were analyzed for radium-226; and the ratio of radium-228 to radium-226 was determined for 13 samples.

  6. Ground water and the rural homeowner

    Science.gov (United States)

    Waller, Roger M.

    1994-01-01

    As the salesmen sang in the musical The Music Man, "You gotta know the territory." This saying is also true when planning to buy or build a house. Learn as much as possible about the land, the water supply, and the septic system of the house before buying or building. Do not just look at the construction aspects or the beauty of the home and surroundings. Be sure to consider the environmental conditions around and beneath the site as well. Try to visit the site under adverse conditions, such as during heavy rain or meltwater runoff, to observe the drainage characteristics, particularly the condition of the basement. Many of the conditions discussed in this book, such as lowered well-water levels, flooded basements, and contamination from septic systems, are so common that rural families often have to deal with one or more of them. The purpose of this book is to awaken an interest in ground water and an awareness of where it is available, how it moves, how people can adjust to its patterns to avoid problems, and how it can be protected and used wisely. This booklet provides both present and prospective rural homeowners, particularly those in the glaciated northern parts of the United States, with a basic but comprehensive description of ground water. It also presents problems one may expect to encounter with ground water and some solutions or suggestions for help with these problems.

  7. Interim site characterization report and ground-water monitoring program for the Hanford site solid waste landfill

    Energy Technology Data Exchange (ETDEWEB)

    Fruland, R.M.; Hagan, R.A.; Cline, C.S.; Bates, D.J.; Evans, J.C.; Aaberg, R.L.

    1989-07-01

    Federal and state regulations governing the operation of landfills require utilization of ground-water monitoring systems to determine whether or not landfill operations impact ground water at the point of compliance (ground water beneath the perimeter of the facility). A detection-level ground-water monitoring system was designed, installed, and initiated at the Hanford Site Solid Waste Landfill (SWL). Chlorinated hydrocarbons were detected at the beginning of the ground-water monitoring program and continue to be detected more than 1 year later. The most probable source of the chlorinated hydrocarbons is washwater discharged to the SWL between 1985 and 1987. This is an interim report and includes data from the characterization work that was performed during well installation in 1987, such as field observations, sediment studies, and geophysical logging results, and data from analyses of ground-water samples collected in 1987 and 1988, such as field parameter measurements and chemical analyses. 38 refs., 27 figs., 8 tabs.

  8. Ground-Water Quality and its Relation to Land Use on Oahu, Hawaii, 2000-01

    Science.gov (United States)

    Hunt, Charles D.

    2003-01-01

    Water quality in the main drinking-water source aquifers of Oahu was assessed by a one-time sampling of untreated ground water from 30 public-supply wells and 15 monitoring wells. The 384 square-mile study area, which includes urban Honolulu and large tracts of forested, agricultural, and suburban residential lands in central Oahu, accounts for 93 percent of the island's ground-water withdrawals. Organic compounds were detected in 73 percent of public-supply wells, but mostly at low concentrations below minimum reporting levels. Concentrations exceeded drinking-water standards in just a few cases: the solvent trichloroethene and the radionuclide radon-222 exceeded Federal standards in one public-supply well each, and the fumigants 1,2-dibromo-3-chloropropane (DBCP) and 1,2,3-trichloropropane (TCP) exceeded State standards in three public-supply wells each. Solvents, fumigants, trihalomethanes, and herbicides were prevalent (detected in more than 30 percent of samples) but gasoline components and insecticides were detected in few wells. Most water samples contained complex mixtures of organic compounds: multiple solvents, fumigants, or herbicides, and in some cases compounds from two or all three of these classes. Characteristic suites of chemicals were associated with particular land uses and geographic locales. Solvents were associated with central Oahu urban-military lands whereas fumigants, herbicides, and fertilizer nutrients were associated with central Oahu agricultural lands. Somewhat unexpectedly, little contamination was detected in Honolulu where urban density is highest, most likely as a consequence of sound land-use planning, favorable aquifer structure, and less intensive application of chemicals (or of less mobile chemicals) over recharge zones in comparison to agricultural areas. For the most part, organic and nutrient contamination appear to reflect decades-old releases and former land use. Most ground-water ages were decades old, with recharge

  9. An Excel Workbook for Identifying Redox Processes in Ground Water

    Science.gov (United States)

    Jurgens, Bryant C.; McMahon, Peter B.; Chapelle, Francis H.; Eberts, Sandra M.

    2009-01-01

    The reduction/oxidation (redox) condition of ground water affects the concentration, transport, and fate of many anthropogenic and natural contaminants. The redox state of a ground-water sample is defined by the dominant type of reduction/oxidation reaction, or redox process, occurring in the sample, as inferred from water-quality data. However, because of the difficulty in defining and applying a systematic redox framework to samples from diverse hydrogeologic settings, many regional water-quality investigations do not attempt to determine the predominant redox process in ground water. Recently, McMahon and Chapelle (2008) devised a redox framework that was applied to a large number of samples from 15 principal aquifer systems in the United States to examine the effect of redox processes on water quality. This framework was expanded by Chapelle and others (in press) to use measured sulfide data to differentiate between iron(III)- and sulfate-reducing conditions. These investigations showed that a systematic approach to characterize redox conditions in ground water could be applied to datasets from diverse hydrogeologic settings using water-quality data routinely collected in regional water-quality investigations. This report describes the Microsoft Excel workbook, RedoxAssignment_McMahon&Chapelle.xls, that assigns the predominant redox process to samples using the framework created by McMahon and Chapelle (2008) and expanded by Chapelle and others (in press). Assignment of redox conditions is based on concentrations of dissolved oxygen (O2), nitrate (NO3-), manganese (Mn2+), iron (Fe2+), sulfate (SO42-), and sulfide (sum of dihydrogen sulfide [aqueous H2S], hydrogen sulfide [HS-], and sulfide [S2-]). The logical arguments for assigning the predominant redox process to each sample are performed by a program written in Microsoft Visual Basic for Applications (VBA). The program is called from buttons on the main worksheet. The number of samples that can be analyzed

  10. Salinity of the ground water in western Pinal County, Arizona

    Science.gov (United States)

    Kister, Lester Ray; Hardt, W.F.

    1966-01-01

    The chemical quality of the ground water in western Pinal County is nonuniform areally and stratigraphically. The main areas of highly mineralized water are near Casa Grande and near Coolidge. Striking differences have been noted in the quality of water from different depths in the same well. Water from one well, (D-6-7) 25cdd, showed an increase in chloride content from 248 ppm (parts per million) at 350 feet below the land surface to 6,580 ppm at 375 feet; the concentration of chloride increased to 10,400 ppm at 550 feet below the land surface. This change was accompanied by an increase in the total dissolved solids as indicated by conductivity measurements. The change in water quality can be correlated with sediment types. The upper and lower sand and gravel units seem to yield water of better quality than the intermediate silt and clay unit. In places the silt and clay unit contains zones of gypsum and common table salt. These zones yield water that contains large amounts of the dissolved minerals usually associated with water from playa deposits. Highly mineralized ground water in an area near Casa Grande has moved southward and westward as much as 4 miles. Similar water near Coolidge has moved a lesser distance. Good management practices and proper use of soil amendments have made possible the use of water that is high in salinity and alkali hazard for agricultural purposes in western Pinal County. The fluoride content of the ground water in western Pinal County is usually low; however, water from wells that penetrate either the bedrock or unconsolidated sediments that contain certain volcanic rocks may have as much as 9 ppm of fluoride.

  11. Ground-water monitoring compliance plan for the Hanford Site Solid Waste Landfill

    Energy Technology Data Exchange (ETDEWEB)

    Fruland, R.M.

    1986-10-01

    Washington state regulations required that solid waste landfill facilities have ground-water monitoring programs in place by May 27, 1987. This document describes the well locations, installation, characterization studies and sampling and analysis plan to be followed in implementing the ground-water monitoring program at the Hanford Site Solid Waste Landfill (SWL). It is based on Washington Administrative Code WAC 173-304-490. 11 refs., 19 figs., 4 tabs.

  12. Summary of Ground-Water-Quality Data in the Anacostia River Watershed, Washington, D.C., September - December 2005

    Science.gov (United States)

    Klohe, Cheryl A.; Debrewer, Linda M.

    2007-01-01

    The U.S. Geological Survey, in cooperation with the District Department of the Environment (formerly the District of Columbia, Department of Health, Environmental Health Administration), conducted a ground-water-quality investigation in the Anacostia River watershed within Washington, D.C. Samples were collected and analyzed from 17 ground-water monitoring wells located within the study area from September through December 2005. Samples were analyzed for a variety of constituents including major ions, nutrients, volatile organic compounds, semivolatile organic compounds, pesticides and degradates, oil and grease, phenols, total polychlorinated biphenyls, and other selected constituents. The concentrations of major ions in the study area indicate that the ground water is predominantly calcium-bicarbonate type water, with some wells containing a higher percentage of milliequivalents per liter of iron (cation), and chloride or sulfate (anions). Concentrations of nitrogen were generally less than 1 milligram per liter, and concentrations of phosphorus were generally less than 0.5 milligrams per liter. Twelve of 79 pesticides and degradates were detected at 6 out of 17 wells. Volatile organic compounds (predominantly gasoline oxygenates and solvents) were detected in 9 of the 17 wells. Two semivolatile organic compounds, (bis(2-ethylhexyl) phthalate and total phenols), out of the 51 analyzed, were detected in the study area.

  13. Identifying of ground water level by using geoelectric method in Karanganyar, Central Java, Indonesia

    Science.gov (United States)

    Koesuma, S.; Sulastoro

    2016-11-01

    This study aims to determine ground water level in Karanganyar regency, Central Java Province, Indonesia. Karanganyar regency is located in west flank of Lawu volcano, the third highest volcano in Central Java Province. Karanganyar lays from the top submit of Lawu volcano to down town of city with altitude 3265 m to 88 m. Same as other mountain area, Karanganyar has a lot of ground water potential. We use geoelectric method to finds out how deep of ground water level. The survey locations are distributed surround Karanganyar regency which contain 22 sites, in period survey of 2013 - 2015. Schlumberger configuration is used for acqusition data with lenght of current electrode distance varies from 1 m to 700 m. The result shows that ground water level are located in depth from 50 meter to 150 meter with lithology of tuff and sand. In Munggur and Kedung Jeruk sites, we found two potential aquifers, which are shallow and deep aquifers.

  14. Helium and neon isotope geochemistry of some ground waters from the Canadian Precambrian Shield

    Science.gov (United States)

    Bottomley, D. J.; Ross, J. D.; Clarke, W. B.

    1984-10-01

    Ground waters in a Precambrian granitic batholith at the Whiteshell Nuclear Research Establishment (WNRE) in Pinawa, Manitoba contain between 5 × 10 -5 and 10 -1 cc STP/g H 2O of radiogenic helium-4 but have relatively uniform 3He/ 4He ratios of between 0.6 × 10 -8 and 2.3 × 10 3. The highest helium samples also contain radiogenic 21,22Ne produced by (α, n) or ( n,α) reactions with other isotopes. As much as 1.8 × 10 -9ccSTP/ gH2O of excess 21Ne and 3.8 × 10 -9ccSTP/ gH2O of excess 22Ne have been measured. Helium and 21Ne ages of these ground waters, calculated on the basis of known crustal production rates of 4He and 21Ne, are unreasonably high (up to 2 × 10 5 years) and incompatible with the 14C ages and other isotopic and hydrogeologic data. Uranium enrichment in the flow porosity of the granite may dominate 4He and 21,22Ne production in this granite and mask the contributions from more typical U and Th concentrations in the rock matrix. At the Chalk River Nuclear Laboratories in Ontario helium concentrations in ground waters in a Precambrian monzonitic gneiss range from 1.5 × 10 -7 to 8.7 × 10 -4ccSTP/ gH2O with the 3He/ 4He ratios ranging from 2.0 × 10 -3 to 1.5 × 10 -7. The highest helium concentrations may be attributable to the presence of a thick uraniferous pegmatite vein and yield helium ages more than two orders of magnitude higher than the 14C ages. Application of He age dating equations to ground waters from Precambrian granitic rocks requires knowledge of the nature of uranium and thorium enrichment in the subsurface in order to select appropriate values for porosity and uranium and thorium concentration in the rock.

  15. Factors influencing ground-water recharge in the eastern United States

    Science.gov (United States)

    Nolan, B.T.; Healy, R.W.; Taber, P.E.; Perkins, K.; Hitt, K.J.; Wolock, D.M.

    2007-01-01

    Ground-water recharge estimates for selected locations in the eastern half of the United States were obtained by Darcian and chloride-tracer methods and compared using statistical analyses. Recharge estimates derived from unsaturated-zone (RUZC) and saturated-zone (RSZC) chloride mass balance methods are less variable (interquartile ranges or IQRs are 9.5 and 16.1 cm/yr, respectively) and more strongly correlated with climatic, hydrologic, land use, and sediment variables than Darcian estimates (IQR = 22.8 cm/yr). The unit-gradient Darcian estimates are a nonlinear function of moisture content and also reflect the uncertainty of pedotransfer functions used to estimate hydraulic parameters. Significance level is 0.3. Estimates of RSZC were evaluated using analysis of variance, multiple comparison tests, and an exploratory nonlinear regression (NLR) model. Recharge generally is greater in coastal plain surficial aquifers, fractured crystalline rocks, and carbonate rocks, or in areas with high sand content. Westernmost portions of the study area have low recharge, receive somewhat less precipitation, and contain fine-grained sediment. The NLR model simulates water input to the land surface followed by transport to ground water, depending on factors that either promote or inhibit water infiltration. The model explains a moderate amount of variation in the data set (coefficient of determination = 0.61). Model sensitivity analysis indicates that mean annual runoff, air temperature, and precipitation, and an index of ground-water exfiltration potential most influence estimates of recharge at sampled sites in the region. Soil characteristics and land use have less influence on the recharge estimates, but nonetheless are significant in the NLR model. ?? 2006 Elsevier B.V. All rights reserved.

  16. Water management, agriculture, and ground-water supplies

    Science.gov (United States)

    Nace, Raymond L.

    1960-01-01

    Encyclopedic data on world geography strikingly illustrate the drastic inequity in the distribution of the world's water supply. About 97 percent of the total volume of water is in the world's oceans. The area of continents and islands not under icecaps, glaciers, lakes, and inland seas is about 57.5 million square miles, of which 18 million (36 percent) is arid to semiarid. The total world supply of water is about 326.5 million cubic miles, of which about 317 million is in the oceans and about 9.4 million is in the land areas. Atmospheric moisture is equivalent to only about 3,100 cubic miles of water. The available and accessible supply of ground water in the United States is somewhat more than 53,000 cubic miles (about 180 billion acre ft). The amount of fresh water on the land areas of the world at any one time is roughly 30,300 cubic miles and more than a fourth of this is in large fresh-water lakes on the North American Continent. Annual recharge of ground water in the United States may average somewhat more than 1 billion acre-feet yearly, but the total volume of ground water in storage is equivalent to all the recharge in about the last 160 years. This accumulation of ground water is the nation's only reserve water resource, but already it is being withdrawn or mined on a large scale in a few areas. The principal withdrawals of water in the United States are for agriculture and industry. Only 7.4 percent of agricultural land is irrigated, however; so natural soil moisture is the principal source of agricultural water, and on that basis agriculture is incomparably the largest water user. In view of current forecasts of population and industrial expansion, new commitments of water for agriculture should be scrutinized very closely, and thorough justification should be required. The 17 Western States no longer contain all the large irrigation developments. Nearly 10 percent of the irrigated area is in States east of the western bloc, chiefly in several

  17. Water management, agriculture, and ground-water supplies

    Science.gov (United States)

    Nace, Raymond L.

    1960-01-01

    Encyclopedic data on world geography strikingly illustrate the drastic inequity in the distribution of the world's water supply. About 97 percent of the total volume of water is in the world's oceans. The area of continents and islands not under icecaps, glaciers, lakes, and inland seas is about 57.5 million square miles, of which 18 million (36 percent) is arid to semiarid. The total world supply of water is about 326.5 million cubic miles, of which about 317 million is in the oceans and about 9.4 million is in the land areas. Atmospheric moisture is equivalent to only about 3,100 cubic miles of water. The available and accessible supply of ground water in the United States is somewhat more than 53,000 cubic miles (about 180 billion acre ft). The amount of fresh water on the land areas of the world at any one time is roughly 30,300 cubic miles and more than a fourth of this is in large fresh-water lakes on the North American Continent. Annual recharge of ground water in the United States may average somewhat more than 1 billion acre-feet yearly, but the total volume of ground water in storage is equivalent to all the recharge in about the last 160 years. This accumulation of ground water is the nation's only reserve water resource, but already it is being withdrawn or mined on a large scale in a few areas. The principal withdrawals of water in the United States are for agriculture and industry. Only 7.4 percent of agricultural land is irrigated, however; so natural soil moisture is the principal source of agricultural water, and on that basis agriculture is incomparably the largest water user. In view of current forecasts of population and industrial expansion, new commitments of water for agriculture should be scrutinized very closely, and thorough justification should be required. The 17 Western States no longer contain all the large irrigation developments. Nearly 10 percent of the irrigated area is in States east of the western bloc, chiefly in several

  18. Corrosion of dissimilar metal crevices in simulated concentrated ground water solutions at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, B.M.; Quinn, M.J

    2003-01-01

    The disposal of high-level nuclear waste in the Yucca Mountain, Nevada is under consideration by the US Department of Energy. The proposed facility will be located in the unsaturated zone approximately 300 m below the surface and 300 m above the water table. The proposed waste container consists of an outer corrosion-resistant Alloy 22 shell surrounding a 316 NG stainless steel structural inner container that encapsulates the used nuclear fuel waste. A titanium drip shield is proposed to protect the waste container from ground water seepage arid rock-fail. A cycle of dripping/evaporation could result in the generation of concentrated aggressive solutions, which could contact the waste container. The waste container material could be susceptible to crevice corrosion from such solutions. The experiments described in this report support the modeling of waste package degradation processes. The intent was to provide parameter values that are required to model crevice corrosion chemistry, as it relates to hydrogen pick-up, and stress corrosion cracking for selected candidate waste package materials. The purpose of the experiments was to study the crevice corrosion behavior of various candidate materials under near freely corroding conditions and to determine the pH developed in crevice solutions. Experimental results of crevice corrosion of dissimilar metal pairs (Alloy 22, Grade-7 and -16 titanium and 316 stainless steel) immersed in a simulated concentrated ground water at {approx}90{sup o}C are reported. The corrosion potential was measured during exposure periods of between 330 and 630 h. Following the experiments, the pH of the crevice solution was measured. The results indicate that a limited degree of crevice acidification occurred during the experiment. The values for corrosion potential suggest that crevice corrosion may have initiated. The total corrosion was limited, with little visible evidence for crevice corrosion being observed on the sample coupon faces

  19. Assessment of ground water pollution in the residential areas of ...

    African Journals Online (AJOL)

    Assessment of ground water pollution in the residential areas of Ewekoro and Shagamu ... of the ground water distribution of the settlements around cement factories in ... The concentrations of lead and cadmium are above the World Health ...

  20. Hydrogeology and Water Quality of the Pepacton Reservoir Watershed in Southeastern New York. Part 4. Quantity and Quality of Ground-Water and Tributary Contributions to Stream Base Flow in Selected Main-Valley Reaches

    Science.gov (United States)

    Heisig, Paul M.

    2004-01-01

    Estimates of the quantity and quality of ground-water discharge from valley-fill deposits were calculated for nine valley reaches within the Pepacton watershed in southeastern New York in July and August of 2001. Streamflow and water quality at the upstream and downstream end of each reach and at intervening tributaries were measured under base-flow conditions and used in mass-balance equations to determine quantity and quality of ground-water discharge. These measurements and estimates define the relative magnitudes of upland (tributary inflow) and valley-fill (ground-water discharge) contributions to the main-valley streams and provide a basis for understanding the effects of hydrogeologic setting on these contributions. Estimates of the water-quality of ground-water discharge also provide an indication of the effects of road salt, manure, and human wastewater from villages on the water quality of streams that feed the Pepacton Reservoir. The most common contaminant in ground-water discharge was chloride from road salt; concentrations were less than 15 mg/L. Investigation of ground-water quality within a large watershed by measurement of stream base-flow quantity and quality followed by mass-balance calculations has benefits and drawbacks in comparison to direct ground-water sampling from wells. First, sampling streams is far less expensive than siting, installing, and sampling a watershed-wide network of wells. Second, base-flow samples represent composite samples of ground-water discharge from the most active part of the ground-water flow system across a drainage area, whereas a well network would only be representative of discrete points within local ground-water flow systems. Drawbacks to this method include limited reach selection because of unfavorable or unrepresentative hydrologic conditions, potential errors associated with a large number of streamflow and water-quality measurements, and limited ability to estimate concentrations of nonconservative

  1. Baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota

    Energy Technology Data Exchange (ETDEWEB)

    1994-11-01

    This baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota, evaluates the potential impacts to public health or the environment from contaminated ground water at this site. This contamination is a result of the uraniferous lignite ashing process, when coal containing uranium was burned to produce uranium. Potential risk is quantified only for constituents introduced by the processing activities and not for the constituents naturally occurring in background ground water in the site vicinity. Background ground water, separate from any site-related contamination, imposes a percentage of the overall risk from ground water ingestion in the Bowman site vicinity. The US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is developing plans to address soil and ground water contamination at the site. The UMTRA Surface Project involves the determination of the extent of soil contamination and design of an engineered disposal cell for long-term storage of contaminated materials. The UMTRA Ground Water Project evaluates ground water contamination. Based on results from future site monitoring activities as defined in the site observational work plan and results from this risk assessment, the DOE will propose an approach for managing contaminated ground water at the Bowman site.

  2. Geology and ground-water resources of Washington County, Colorado

    Science.gov (United States)

    McGovern, Harold E.

    1964-01-01

    to the thickness of saturated material. Development of ground water for irrigation has been generally restricted to the South Platte, Arikaree, and Beaver valleys. There were 134 irrigation wells, 3 industrial wells, and 10 municipal wells in the county in 1959. The annual ground-water pumpage from Washington County is estimated to be 18,000 acre-ft; about 10,000 acre-ft is from the High Plains ground-water province. Although some ground water enters the county as underflow, most of the recharge to ground-water reservoirs is from precipitation on the land surface. Recharge to the Ogallala Formation in the county is assumed to be approximately equal to the natural discharge from the county by underflow because ground-water withdrawals are from storage, and no other significant amount of natural discharge is apparent. Undertow in the Ogallala was calculated to be 83,000 acre-ft per year and the rate of recharge from precipitation to be about 0.95 inch per year. Neither recharge nor discharge was calculated for that part of the county in the South Platte River basin. All ground water in Washington County has a high proportion of carbonate and is classed as hard to very hard. The sodium-adsorption-ratio for all samples analyzed was below the limit recommended for irrigation water. All the water from the Ogallala Formation and most of the water from the Chadron Formation is suitable for domestic use. Some water from the alluvial deposits overlying the Pierre Shale was exceptionally high in calcium, magnesium, and sodium sulfates. Ground water has been heavily developed for irrigation in the South Platte valley and in some parts of the Beaver and Arikaree valleys. Some additional areas, however, could be developed in the latter two valleys. Large quantities of ground water in the Ogallala Formation are available for future development. The quantity of water in storage in the High Plains ground-water province in Washington County is about 6.5 million acre-f

  3. 40 CFR 258.51 - Ground-water monitoring systems.

    Science.gov (United States)

    2010-07-01

    ... preclude installation of ground-water monitoring wells at the relevant point of compliance at existing... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water monitoring systems. 258... CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Ground-Water Monitoring and Corrective Action § 258.51...

  4. Elements in cottonwood trees as an indicator of ground water contaminated by landfill leachate

    Science.gov (United States)

    Erdman, James A.; Christenson, Scott

    2000-01-01

    Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site. Leaf samples of broad-leafed cottonwood, Populus deltoides, were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or “well plant,” functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby. Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.

  5. Pumpage for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents ground-water discharged from the Death Valley regional ground-water flow system (DVRFS) through pumped wells. Pumping from wells in...

  6. Nitrate removal using Brevundimonas diminuta MTCC 8486 from ground water.

    Science.gov (United States)

    Kavitha, S; Selvakumar, R; Sathishkumar, M; Swaminathan, K; Lakshmanaperumalsamy, P; Singh, A; Jain, S K

    2009-01-01

    Brevundimonas diminuta MTCC 8486, isolated from marine soil of coastal area of Trivandrum, Kerala, was used for biological removal of nitrate from ground water collected from Kar village of Pali district, Rajasthan. The organism was found to be resistance for nitrate up to 10,000 mg L(-1). The optimum growth conditions for biological removal of nitrate were established in batch culture. The effect of carbon sources on nitrate removal was investigated using mineral salt medium (MSM) containing 500 mg L(-1) of nitrate to select the most effective carbon source. Among glucose and starch as carbon source, glucose at 1% concentration increased the growth (182+/-8.24 x 10(4) CFU mL(-1)) and induced maximum nitrate reduction (86.4%) at 72 h. The ground water collected from Kar village, Pali district of Rajasthan containing 460+/-5.92 mg L(-1) of nitrate was subjected to three different treatment processes in pilot scale (T1 to T3). Higher removal of nitrate was observed in T2 process (88%) supplemented with 1% glucose. The system was scaled up to 10 L pilot scale treatment plant. At 72 h the nitrate removal was observed to be 95% in pilot scale plant. The residual nitrate level (23+/-0.41 mg L(-1)) in pilot scale treatment process was found to be below the permissible limit of WHO.

  7. Bacteriophages as surface and ground water tracers

    Directory of Open Access Journals (Sweden)

    P. Rossi

    1998-01-01

    Full Text Available Bacteriophages are increasingly used as tracers for quantitative analysis in both hydrology and hydrogeology. The biological particles are neither toxic nor pathogenic for other living organisms as they penetrate only a specific bacterial host. They have many advantages over classical fluorescent tracers and offer the additional possibility of multi-point injection for tracer tests. Several years of research make them suitable for quantitative transport analysis and flow boundary delineation in both surface and ground waters, including karst, fractured and porous media aquifers. This article presents the effective application of bacteriophages based on their use in differing Swiss hydrological environments and compares their behaviour to conventional coloured dye or salt-type tracers. In surface water and karst aquifers, bacteriophages travel at about the same speed as the typically referenced fluorescent tracers (uranine, sulphurhodamine G extra. In aquifers of interstitial porosity, however, they appear to migrate more rapidly than fluorescent tracers, albeit with a significant reduction in their numbers within the porous media. This faster travel time implies that a modified rationale is needed for defining some ground water protection area boundaries. Further developments of other bacteriophages and their documentation as tracer methods should result in an accurate and efficient tracer tool that will be a proven alternative to conventional fluorescent dyes.

  8. Bacteriophages as surface and ground water tracers

    Science.gov (United States)

    Rossi, P.; Dörfliger, N.; Kennedy, K.; Müller, I.; Aragno, M.

    Bacteriophages are increasingly used as tracers for quantitative analysis in both hydrology and hydrogeology. The biological particles are neither toxic nor pathogenic for other living organisms as they penetrate only a specific bacterial host. They have many advantages over classical fluorescent tracers and offer the additional possibility of multi-point injection for tracer tests. Several years of research make them suitable for quantitative transport analysis and flow boundary delineation in both surface and ground waters, including karst, fractured and porous media aquifers. This article presents the effective application of bacteriophages based on their use in differing Swiss hydrological environments and compares their behaviour to conventional coloured dye or salt-type tracers. In surface water and karst aquifers, bacteriophages travel at about the same speed as the typically referenced fluorescent tracers (uranine, sulphurhodamine G extra). In aquifers of interstitial porosity, however, they appear to migrate more rapidly than fluorescent tracers, albeit with a significant reduction in their numbers within the porous media. This faster travel time implies that a modified rationale is needed for defining some ground water protection area boundaries. Further developments of other bacteriophages and their documentation as tracer methods should result in an accurate and efficient tracer tool that will be a proven alternative to conventional fluorescent dyes.

  9. Ground-water models: Validate or invalidate

    Science.gov (United States)

    Bredehoeft, J.D.; Konikow, L.F.

    1993-01-01

    The word validation has a clear meaning to both the scientific community and the general public. Within the scientific community the validation of scientific theory has been the subject of philosophical debate. The philosopher of science, Karl Popper, argued that scientific theory cannot be validated, only invalidated. Popper’s view is not the only opinion in this debate; however, many scientists today agree with Popper (including the authors). To the general public, proclaiming that a ground-water model is validated carries with it an aura of correctness that we do not believe many of us who model would claim. We can place all the caveats we wish, but the public has its own understanding of what the word implies. Using the word valid with respect to models misleads the public; verification carries with it similar connotations as far as the public is concerned. Our point is this: using the terms validation and verification are misleading, at best. These terms should be abandoned by the ground-water community.

  10. Nitrate-nitrogen concentrations in the perched ground water under seepage-irrigated potato cropping systems.

    Science.gov (United States)

    Munoz-Arboleda, F; Mylavarapu, R; Hutchinson, C; Portier, K

    2008-01-01

    Excessive nitrogen rates for potato production in northeast Florida have been declared as a potential source of nitrate pollution in the St. Johns River watershed. This 3-yr study examined the effect of N rates (0, 168, and 280 kg ha(-1)) split between planting and 40 d after planting on the NO(3)-N concentration in the perched ground water under potato (Solanum tuberosum cv. Atlantic) in rotation with sorghum sudan grass hybrid (Sorghum vulgare x Sorghum vulgare var. sudanese, cv. SX17), cowpea (Vigna unguiculata cv. Iron Clay), and greenbean (Phaseolus vulgare cv. Espada). Soil solution from the root zone and water from the perched ground water under potato were sampled periodically using lysimeters and wells, respectively. Fertilization at planting increased the NO(3)-N concentration in the perched ground water, but no effect of the legumes in rotation with potatoes on nitrate leaching was detected. Fertilization of green bean increased NO(3)-N concentration in the perched ground water under potato planted in the following season. The NO(3)-N concentration in the soil solution within the potato root zone followed a similar pattern to that of the perched ground water but with higher initial values. The NO(3)-N concentration in the perched ground water was proportional to the rainfall magnitude after potato planting. A significant increase in NO(3)-N concentration in the perched ground water under cowpea planted in summer after potato was detected for the side-dressing of 168 kg ha(-1) N applied to potato 40 d after planting but not at the 56 kg ha(-1) N side-dress. Elevation in NO(3)-N concentration in the perched ground water under sorghum was not significant, supporting its use as an effective N catch crop.

  11. Occurrence and fate of alkylphenol polyethoxylate degradation products and linear alkylbenzene sulfonate surfactants in urban ground water: Barcelona case study

    Science.gov (United States)

    Tubau, Isabel; Vázquez-Suñé, Enric; Carrera, Jesús; González, Susana; Petrovic, Mira; López de Alda, María J.; Barceló, Damià

    2010-03-01

    SummaryThis study investigates the fate of alkylphenol polyethoxylates (APEOs) degradation products (DPs) and the occurrence of linear alkylbenzene sulfonate (LAS) surfactants in urban ground water at field scale. The occurrence of APEOs DPs in ground water was studied in connection with: (1) sources of recharge or/and pollution containing these substances, (2) ground water redox conditions, (3) occurrence of LAS, which are currently the domestic surfactants more used in the study area and (4) other common contaminants in urban ground water in the city of Barcelona. The APEOs DPs analyzed included two nonylphenol carboxylates (NP2EC, NP1EC), two octylphenol carboxylates (OP2EC, OP1EC), nonylphenol (NP) and octylphenol (OP). The highest groundwater concentrations of APEOs DPs were detected in aquifers whose major source of recharge is a river receiving large amounts of effluents from secondary waste water treatment plants (WWTPs). In fact, APEOs DPs concentrations were above those in the river. NP2EC was the compound detected at highest concentrations. These increase with ammonium in samples with low dissolved oxygen. These degradation products were virtually absent in oxidizing aquifers whose main source of recharge is not the river. In this case, only the ultimate degradation product (NP) was detected, which suggests that parent compounds have degraded. These results indicate that APEOs are persistent or less degraded in reducing conditions, whereas they are degraded when oxidizing conditions prevail. By contrast, LAS concentrations were more than one order of magnitude lower than expected based on recharge sources in all (oxidizing and reducing) aquifers.

  12. Strontium isotopic identification of water-rock interaction and ground water mixing.

    Science.gov (United States)

    Frost, Carol D; Toner, Rachel N

    2004-01-01

    87Sr/86Sr ratios of ground waters in the Bighorn and Laramie basins' carbonate and carbonate-cemented aquifer systems, Wyoming, United States, reflect the distinctive strontium isotope signatures of the minerals in their respective aquifers. Well water samples from the Madison Aquifer (Bighorn Basin) have strontium isotopic ratios that match their carbonate host rocks. Casper Aquifer ground waters (Laramie Basin) have strontium isotopic ratios that differ from the bulk host rock; however, stepwise leaching of Casper Sandstone indicates that most of the strontium in Casper Aquifer ground waters is acquired from preferential dissolution of carbonate cement. Strontium isotope data from both Bighorn and Laramie basins, along with dye tracing experiments in the Bighorn Basin and tritium data from the Laramie Basin, suggest that waters in carbonate or carbonate-cemented aquifers acquire their strontium isotope composition very quickly--on the order of decades. Strontium isotopes were also used successfully to verify previously identified mixed Redbeds-Casper ground waters in the Laramie Basin. The strontium isotopic compositions of ground waters near Precambrian outcrops also suggest previously unrecognized mixing between Casper and Precambrian aquifers. These results demonstrate the utility of strontium isotopic ratio data in identifying ground water sources and aquifer interactions.

  13. INVESTIGATIONS OF PHYSICO-CHEMICAL STATUS OF GROUND WATER OF SINGRAULI DISTRICT, MADHYA PRADESH, INDIA

    Directory of Open Access Journals (Sweden)

    Rajesh Pandey et al

    2012-10-01

    Full Text Available Ground water is the most preferred water source in current scenario. Once believed to be safe from pollution as it is available many band below the surface, is now provided to be prone to pollution by research investigators. Various causes associated for the contamination of ground water. The major cause of the contamination of ground water may be due to improper disposal of industrial waste. The effort was made to assess the quality of ground water and thrash out the portability of ground water by physico-chemical temperament. Present study was carried out to assess the ground water quality of Singrauli district an energy hub station of Madhya Pradesh state of India Study was conduct in year 2012 by selecting 13 different spots, covered all the four directions of Singrauli. Ground water samples were taken from different sources such as bore well, well water, municipal supplier water etc. Investigations of Physico-chemical characteristics of groundwater quality based on Physico-chemical parameters have been taken up to evaluate its suitability for different objects. Quality analysis has been made through in terms of pH, EC, TDS, Total Hardness, Sodium, Potassium, Calcium, Magnesium, Chloride, Sulphate, Nitrate, Fluoride and Alkalinity. Comparative studies of collected samples indicated that there is no appreciable change in the different parameters during sampling season. The results were compared with standards prescribed by WHO and ICMR. The results showed that high total hardness content indicating the need of some treatment for minimization. Other investigated samples were found within the water quality standards but the quality of water is not completely favorable as per standard human requirement. Water is not completely fit for drinking purpose due to improper management of disposal of industrials, mines waste or garbage in these local energy hub environments.

  14. Ground-water resources of Catron County, New Mexico

    Science.gov (United States)

    Basabilvazo, G.T.

    1997-01-01

    alluvium in the San Agustin Basin range from 1 to 10 gallons per minute. Irrigation wells completed in the Quaternary bolson fill produce as much as 975 gallons per minute immediately east of the county. Water from the bolson fill in the Plains of San Agustin has specific-conductance values generally ranging from 180 to 3,300 microsiemens per centimeter at 25 degrees Celsius (microsiemens/cm). Yields from the Gila Conglomerate generally range from 2 to 5 gallons per minute. Water samples from two springs from the Gila Conglomerate have specific conductances of 289 and 381 microsiemens/cm. The Tertiary Datil Group is present in the Carrizo Wash, San Agustin, San Francisco, and Gila Basins. The Datil Group commonly is unconfined, but may be confined at depth. Water levels of wells completed in this unit range from 60 to 1,260 feet below land surface. Wells completed in the Datil Group typically yield 1 to 15 gallons per minute. Specific conductance of water from the Datil Group ranges from 210 to 820 microsiemens/cm. The Tertiary Baca Formation in the Carrizo Wash Basin produces 5 to 20 gallons per minute in stock wells. Water from wells completed in the Baca Formation has specific-conductance values ranging from 312 to 752 microsiemens/cm. Aquifers in Cretaceous rocks are present in the Carrizo Wash, North Plains, and Rio Salado Basins. The potential yield from wells completed in Cretaceous rocks in northwestern Catron County is from 1 to 122 gallons per minute. Specific conductance of water from Cretaceous rocks ranges from 210 microsiemens/cm in the Moreno Hill Formation to 4,490 microsiemens/cm in the Mancos Shale. Yields of ground water from Cretaceous rocks in the Carrizo Wash Basin typically range from 1 to 100 gallons per minute; in an artesian well, however, the yield in the main body of the Creta

  15. Ground-Water Resources in Kaloko-Honokohau National Historical Park, Island of Hawaii, and Numerical Simulation of the Effects of Ground-Water Withdrawals

    Science.gov (United States)

    Oki, Delwyn S.; Tribble, Gordon W.; Souza, William R.; Bolke, Edward L.

    1999-01-01

    Within the Kaloko-Honokohau National Historical Park, which was established in 1978, the ground-water flow system is composed of brackish water overlying saltwater. Ground-water levels measured in the Park range from about 1 to 2 feet above mean sea level, and fluctuate daily by about 0.5 to 1.5 feet in response to ocean tides. The brackish water is formed by mixing of seaward flowing fresh ground water with underlying saltwater from the ocean. The major source of fresh ground water is from subsurface flow originating from inland areas to the east of the Park. Ground-water recharge from the direct infiltration of precipitation within the Park area, which has land-surface altitudes less than 100 feet, is small because of low rainfall and high rates of evaporation. Brackish water flowing through the Park ultimately discharges to the fishponds in the Park or to the ocean. The ground water, fishponds, and anchialine ponds in the Park are hydrologically connected; thus, the water levels in the ponds mark the local position of the water table. Within the Park, ground water near the water table is brackish; measured chloride concentrations of water samples from three exploratory wells in the Park range from 2,610 to 5,910 milligrams per liter. Chromium and copper were detected in water samples from the three wells in the Park and one well upgradient of the Park at concentrations of 1 to 5 micrograms per liter. One semi-volatile organic compound, phenol, was detected in water samples from the three wells in the Park at concentrations between 4 and 10 micrograms per liter. A regional, two-dimensional (areal), freshwater-saltwater, sharp-interface ground-water flow model was used to simulate the effects of regional withdrawals on ground-water flow within the Park. For average 1978 withdrawal rates, the estimated rate of fresh ground-water discharge to the ocean within the Park is about 6.48 million gallons per day, or about 3 million gallons per day per mile of coastline

  16. Water-quality and ground-water-level data, Bernalillo County, central New Mexico, 1995

    Science.gov (United States)

    Rankin, D.R.

    1996-01-01

    Water-quality and ground-water-level data were collected in two areas of eastern Bernalillo County in central New Mexico between March and July of 1995. Fifty-one wells, two springs, and the Ojo Grande Acequia in the east mountain area of Bernalillo County and nine wells in the northeast area of the city of Albuquerque were sampled. The water samples were analyzed for selected nutrient species; total organic carbon; major dissolved constituents; dissolved arsenic, boron, iron, and manganese; and methylene blue active substances. Analytical results were used to compute hardness, sodium adsorption ratio, and dissolved solids. Specific conductance, pH, temperature, and alkalinity were measured in the field at the time of sample collection. Ground- water-level and well-depth measurements were made at the time of sample collection when possible. Water-quality data, ground- water-level data, and well-depth data are presented in tabular form.

  17. Baseline risk assessment of ground water contamination at the inactive uriniferous lignite ashing site near Belfield, North Dakota

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-08-01

    This Baseline Risk Assessment of Ground Water Contamination at the Inactive Uraniferous Lignite Ashing Site Near Belfield, North Dakota, evaluates potential impacts to public health or the environment resulting from ground water contamination at the site where coal containing uranium was burned to produce uranium. The US Department of Energy`s Uranium Mill Tailings Remedial Action (UMTRA) Project is evaluating plans to remedy soil and ground water contamination at the site. Phase I of the UMTRA Project consists of determining the extent of soil contamination. Phase II of the UMTRA Project consists of evaluating ground water contamination. Under Phase II, results of this risk assessment will help determine what remedial actions may be necessary for contaminated ground water at the site. This risk assessment evaluates the potential risks to human health and the environment resulting from exposure to contaminated ground water as it relates to historic processing activities at the site. Potential risk is quantified for constituents introduced from the processing activities, and not for those constituents naturally occurring in water quality in the site vicinity. Background ground water quality has the potential to cause adverse health effects from exposure through drinking. Any risks associated with contaminants attributable to site activities are incremental to these risks from background ground water quality. This incremental risk from site-related contaminants is quantified in this risk assessment. The baseline risk from background water quality is incorporated only into the assessment of potential chemical interactions and the definition of the overall site condition.

  18. Measurement and interpretation of low levels of dissolved oxygen in ground water

    Science.gov (United States)

    White, A.F.; Peterson, M.L.; Solbau, R.D.

    1990-01-01

    A Rhodazine-D colorimetric technique was adapted to measure low-level dissolved oxygen concentrations in ground water. Prepared samples containing between 0 and 8.0 ??moles L-1 dissolved oxygen in equilibrium with known gas mixtures produced linear spectrophotometric absorbance with a lower detection limit of 0.2 ??moles L-1. Excellent reproducibility was found for solutions ranging in composition from deionized water to sea water with chemical interferences detected only for easily reduced metal species such as ferric ion, cupric ion, and hexavalent chromium. Such effects were correctable based on parallel reaction stoichiometries relative to oxygen. The technique, coupled with a downhole wire line tool, permitted low-level monitoring of dissolved oxygen in wells at the selenium-contaminated Kesterson Reservoir in California. Results indicated a close association between low but measurable dissolved oxygen concentrations and mobility of oxidized forms of selenium. -from Authors

  19. Animating ground water levels with Excel.

    Science.gov (United States)

    Shikaze, Steven G; Crowe, Allan S

    2003-01-01

    This note describes the use of Microsoft Excel macros (programs written in Excel's internal language, Visual Basic for Applications) to create simple onscreen animations of transient ground water data within Excel. Compared to many specialized visualization software packages, the use of Excel macros is much cheaper, much simpler, and can rapidly be learned. The Excel macro can also be used to create individual GIF files for each animation frame. This series of frames can then be used to create an AVI video file using any of a number of graphics packages, such as Corel PhotoPaint. The technique is demonstrated through a macro that animates changes in the elevation of a water table along a transect over several years.

  20. The 226Ra isotope activities in ground water samples drawn of two wells from the Meridional Pluton, Morungaba Granitoids, eastern Sao Paulo State; Atividades do 226Ra em aguas subterraneas extraidas de dois pocos localizados no pluton meridional, granitoides de Morungaba, SP

    Energy Technology Data Exchange (ETDEWEB)

    Lucas, Fabio de Oliveira; Silva Junior, Mario Goncalves da; Bertolla, Luciana; Ribeiro, Fernando Brenha [Sao Paulo Univ., SP (Brazil). Inst. de Astronomia, Geofisica e Ciencias Atmosfericas. Dept. de Geofisica]. E-mail: brenha@iag.usp.br

    2005-07-01

    The 226Ra activities, both in solution and associated with suspended solids, were measured in ground water samples drawn from two wells drilled in a fractured granitic aquifer from the Meridional Pluton, Morungaba Granitoids, eastern Sao Paulo State. The 226Ra isotope activities were measured in a sequence of samples collected about one month apart between March, 2003 and April 2004. The 226Ra activities were measured by radon gas emanometry. The mean dissolved 226Ra activity concentration activities observed in the two wells were (44.9 {+-} 7.1) mBq/L and (51.6 {+-} 8.8) mBq/L. The 226Ra activity of the suspend solids in a liter of these waters varied between (0,6 {+-} 0,1) mBq and (13 {+-} 1) mBq, respectively. (author)

  1. Ground-Water Age and Quality in the High Plains Aquifer near Seward, Nebraska, 2003-04

    Science.gov (United States)

    Stanton, Jennifer S.; Landon, Matthew K.; Turco, Michael J.

    2007-01-01

    The U.S. Geological Survey, in cooperation with the City of Seward, Nebraska, conducted a study of ground-water age and quality to improve understanding of: (1) traveltimes from recharge areas to public-supply wells, (2) the effects of geochemical reactions in the aquifer on water quality, and (3) how water quality has changed historically in response to land-use practices. Samples were collected from four supply wells in the Seward west well field and from nine monitoring wells along two approximate ground-water flow paths leading to the well field. Concentrations of three different chlorofluorocarbons (CFC-12, CFC-11, and CFC-113), sulfur hexafluoride (SF6), and ratios of tritium (3H) to helium-3 (3He) isotope derived from radioactive decay of 3H were used to determine the apparent recharge age of ground-water samples. Age interpretations were based primarily on 3H/3He and CFC-12 data. Estimates of apparent ground-water age from tracer data were complicated by mixing of water of different ages in 10 of the 13 ground-water samples collected. Apparent recharge dates of unmixed ground-water samples or mean recharge dates of young fractions of mixed water in samples collected from monitoring wells ranged from 1985 to 2002. For monitoring-well samples containing mixed water, the fraction of the sample composed of young water ranged from 26 to 77 percent of the sample. Apparent mean recharge dates of young fractions in samples collected from four supply wells in the Seward west well field ranged from about 1980 to 1990. Estimated fractions of the samples composed of young water ranged from 39 to 54 percent. It is implicit in the mixing calculations that the remainder of the sample that is not young water is composed of water that is more than 60 years old and contains no detectable quantities of modern atmospheric tracers. Estimated fractions of the mixed samples composed of 'old' water ranged from 23 to 74 percent. Although alternative mixing models can be used to

  2. Sealing and External Sterilization of a Sample Container

    Science.gov (United States)

    Bar-Cohen, Yoseph; Badescu, Mircea; Bao, Xiaoqi; Sherrit, Stewart; Olorunsola, Ayoola

    2008-01-01

    A method of (1) sealing a sample of material acquired in a possibly b iologically contaminated ("dirty") environment into a hermetic conta iner, (2) sterilizing the outer surface of the container, then (3) d elivering the sealed container to a clean environment has been propos ed. The method now proposed was originally intended to be used to ret urn samples from Mars to Earth, but could also be used on Earth to t ransport material samples acquired in environments that contain biol ogical hazards and/or, in some cases, chemical hazards.

  3. Hydrogeology and ground-water quality of the Chromic Acid Pit site, US Army Air Defense Artillery Center and Fort Bliss, El Paso, Texas

    Science.gov (United States)

    Abeyta, Cynthia G.; Thomas, C.L.

    1996-01-01

    The Chromic Acid Pit site is an inactive waste disposal site that is regulated by the Resource Conservation and Recovery Act of 1976. The 2.2-cubic-yard cement-lined pit was operated from 1980 to 1983 by a contractor to the U.S. Army Air Defense Artillery Center and Fort Bliss. The pit, located on the Fort Bliss military reservation, in El Paso, Texas, was used for disposal and evaporation of chromic acid waste generated from chrome plating operations. The site was certified closed in 1989 and the Texas Natural Resources Conservation Commission issued Permit Number HW-50296 (U.S. Environmental Protection Agency Permit Number TX4213720101), which approved and implemented post-closure care for the Chromic Acid Pit site. In accordance with an approved post-closure plan, the U.S. Geological Survey is cooperating with the U.S. Army in evaluating hydrogeologic conditions and ground- water quality at the site. One upgradient and two downgradient ground-water monitoring wells were installed adjacent to the chromic acid pit by a private contractor. Quarterly ground-water sampling of these wells by the U.S. Geological Survey began in December 1993. The Chromic Acid Pit site is situated in the Hueco Bolson intermontane valley. The Hueco Bolson is a primary source of ground water in the El Paso area. City of El Paso and U.S. Army water-supply wells are located on all sides of the study area and are completed 600 to more than 1,200 feet below land surface. The ground-water level in the area of the Chromic Acid Pit site has declined about 25 feet from 1982 to 1993. Depth to water at the Chromic Acid Pit site in September 1994 was about 284 feet below land surface; ground-water flow is to the southeast. Ground-water samples collected from monitoring wells at the Chromic Acid Pit site contained dissolved-solids concentrations of 442 to 564 milligrams per liter. Nitrate as nitrogen concentrations ranged from 2.1 to 2.7 milligrams per liter; nitrite plus nitrate as nitrogen

  4. Nutrients in ground water and surface water of the United States; an analysis of data through 1992

    Science.gov (United States)

    Mueller, D.K.; Hamilton, P.A.; Helsel, D.R.; Hitt, K.J.; Ruddy, B.C.

    1995-01-01

    Historical data on nutrient (nitrogen and phosphorus species) concentrations in ground-and surface-water samples were compiled from 20 study units of the National Water-Quality Assessment (NAWQA) Program and 5 supplemental study areas. The resultant national retrospective data sets contained analyses of about 12,000 Found-water and more than 22,000 surface-water samples. These data were interpreted on regional and national scales by relating the distributions of nutrient concentrations to ancillary data, such as land use, soil characteristics, and hydrogeology, provided by local study-unit personnel. The information provided in this report on environmental factors that affect nutrient concentrations in ground and surface water can be used to identify areas of the Nation where the vulnerability to nutrient contamination is greatest. Nitrate was the nutrient of greatest concern in the historical ground-water data. It is the only nutrient that is regulated by a national drinking-water standard. Nitrate concentrations were significantly different in ground water affected by various land uses. Concentrations in about 16 percent of the samples collected in agricultural areas exceeded the drinking-water standard. However, the standard was exceeded in only about 1 percent of samples collected from public-supply wells. A variety of ancillary factors had significant relations to nitrate concentrations in ground water beneath agricultural areas. Concentrations generally were highest within 100 feet of the land surface. They were also higher in areas where soil and geologic characteristics promoted rapid movement of water to the aquifer. Elevated concentrations commonly occurred in areas underlain by permeable materials, such as carbonate bedrock or unconsolidated sand and gravel, and where soils are generally well drained. In areas where water movement is impeded, denitrification might lead to low concentrations of nitrate in the ground water. Low concentrations were also

  5. Ground-water quality in the Davie Landfill, Broward County, Florida

    Science.gov (United States)

    Mattraw, H.C.

    1976-01-01

    Ground-water adjacent to a disposal pond for septic tank sludge, oil, and grease at the Davie landfill, Broward County, Florida was tested for a variety of ground-water contaminants. Three wells adjacent to the disposal pond yielded water rich in nutrients, organic carbon and many other chemical constituents. Total coliform bacteria ranged from less than 100 to 660 colonies per 100 milliliters in samples collected from the shallowest well (depth 20 feet). At well depths of 35 and 45 feet bacterial counts were less than 20 colonies per 100 milliliters or zero. Concentrations of several constituents in water samples collected from the wells downgradient from the landfill, disposal pond, and an incinerator wash pond were greater than in samples collected from wells immediately upgradient of the landfill. A comparison of sodium-chloride ion ratios indicated that downgradient ground-water contamination was related to the incinerator wash water pond rather than the septic tank sludge pond. (Woodard-USGS)

  6. Application of environmental tracers to mixing, evolution, and nitrate contamination of ground water in Jeju Island, Korea

    Science.gov (United States)

    Koh, D.-C.; Niel, Plummer L.; Kip, Solomon D.; Busenberg, E.; Kim, Y.-J.; Chang, H.-W.

    2006-01-01

    Tritium/helium-3 (3H/3He) and chlorofluorocarbons (CFCs) were investigated as environmental tracers in ground water from Jeju Island (Republic of Korea), a basaltic volcanic island. Ground-water mixing was evaluated by comparing 3H and CFC-12 concentrations with lumped-parameter dispersion models, which distinguished old water recharged before the 1950s with negligible 3H and CFC-12 from younger water. Low 3H levels in a considerable number of samples cannot be explained by the mixing models, and were interpreted as binary mixing of old and younger water; a process also identified in alkalinity and pH of ground water. The ground-water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seogwipo Formation in coastal areas than in water from the basaltic aquifer. Major cation concentrations are much higher in young water with high nitrate than those in uncontaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite-smectite phase boundary. The calcite saturation state of ground water increases with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water is consistent with the known history of chemical fertilizer use on the island, but increase of nitrate concentration in ground water is more abrupt after the late 1970s compared with the exponential growth of nitrogen inputs. ?? 2005 Elsevier B.V. All rights reserved.

  7. Statistical evaluation of effects of riparian buffers on nitrate and ground water quality

    Science.gov (United States)

    Spruill, T.B.

    2000-01-01

    A study was conducted to statistically evaluate the effectiveness of riparian buffers for decreasing nitrate concentrations in ground water and for affecting other chemical constituents. Values for pH, specific conductance, alkalinity, dissolved organic carbon (DOC), silica, ammonium, phosphorus, iron, and manganese at 28 sites in the Contentnea Creek Basin were significantly higher (p 20 yr) discharging ground water draining areas with riparian buffers compared with areas without riparian buffers. No differences in chloride, nitrate nitrogen, calcium, sodium, and dssolved oxygen concentrations in old ground water between buffer and nonbuffer areas were detected. Comparison of samples of young (20 yr) discharging ground water draining areas with riparian buffers compared with areas without riparian buffers. No differences in chloride, nitrate nitrogen, calcium, sodium, and dissolved oxygen concentrations in old ground water between buffer and nonbuffer areas were detected. Comparison of samples of young (water samples from buffer and nonbuffer areas indicated significantly higher specific conductance, calcium, chloride, and nitrate nitrogen in nonbuffer areas. Riparian buffers along streams can affect the composition of the hyporheic zone by providing a source of organic carbon to the streambed, which creates reducing geochemical conditions that consequently can affect the chemical quality of old ground water discharging through it. Buffer zones between agricultural fields and streams facilitate dilution of conservative chemical constituents in young ground water that originate from fertilizer applications and also allow denitrification in ground water by providing an adequate source of organic carbon generated by vegetation in the buffer zone. Based on the median chloride and nitrate values for young ground water in the Contentnea Creek Basin, nitrate was 95% lower in buffer areas compared with nonbuffer areas, with a 30 to 35% reduction estimated to be due to

  8. Ground-Water Quality in Western New York, 2006

    Science.gov (United States)

    Eckhardt, David A.V.; Reddy, James E.; Tamulonis, Kathryn L.

    2008-01-01

    Water samples were collected from 7 production wells and 26 private residential wells in western New York from August through December 2006 and analyzed to characterize the chemical quality of ground water. Wells at 15 of the sites were screened in sand and gravel aquifers, and 18 were finished in bedrock aquifers. The wells were selected to represent areas of greatest ground-water use and to provide a geographical sampling from the 5,340-square-mile study area. Samples were analyzed for 5 physical properties and 219 constituents that included nutrients, major inorganic ions, trace elements, radionuclides, pesticides, volatile organic compounds (VOC), phenolic compounds, organic carbon, and bacteria. Results indicate that ground water used for drinking supply is generally of acceptable quality, although concentrations of some constituents or bacteria exceeded at least one drinking-water standard at 27 of the 33 wells. The cations that were detected in the highest concentrations were calcium, magnesium, and sodium; anions that were detected in the highest concentrations were bicarbonate, chloride, and sulfate. The predominant nutrients were nitrate and ammonia; nitrate concentrations were higher in samples from sand and gravel aquifers than in samples from bedrock. The trace elements barium, boron, copper, lithium, nickel, and strontium were detected in every sample; the trace elements with the highest concentrations were barium, boron, iron, lithium, manganese, and strontium. Eighteen pesticides, including 9 pesticide degradates, were detected in water from 14 of the 33 wells, but none of the concentrations exceeded State or Federal Maximum Contaminant Levels (MCLs). Fourteen volatile organic compounds were detected in water from 12 of the 33 wells, but none of the concentrations exceeded MCLs. Eight chemical analytes and three types of bacteria were detected in concentrations that exceeded Federal and State drinking-water standards, which are typically identical

  9. Ground-water resources of Cambodia

    Science.gov (United States)

    Rasmussen, William Charles; Bradford, Gary M.

    1977-01-01

    available information is on the central lowlands and contiguous low plateaus, as the mountainous areas on the west and the high plateaus on the east are relatively unexplored with respect to their ground-water availability. No persistent artesian aquifer has been identified nor have any large potential ground-water sources been found .although much of the country yet remains to be explored by test drilling. Well irrigation for garden produce is feasible on a modest scale in many localities throughout Cambodia. It does not seem likely, however, that large-scale irrigation from wells will come about in the future. Ground water may be regarded as a widely available supplemental source to surface water for domestic, small-scale industrial, and irrigation use.

  10. Ground Water Redox Zonation near La Pine, Oregon: Relation to River Position within the Aquifer-Riparian Zone Continuum

    Science.gov (United States)

    Hinkle, Stephen R.; Morgan, David S.; Orzol, Leonard L.; Polette, Danial J.

    2007-01-01

    Increasing residential development since in the 1960s has lead to increases in nitrate concentrations in shallow ground water in parts of the 247 square mile study area near La Pine, Oregon. Denitrification is the dominant nitrate-removal process that occurs in suboxic ground water, and suboxic ground water serves as a barrier to transport of most nitrate in the aquifer. Oxic ground water, on the other hand, represents a potential pathway for nitrate transport from terrestrial recharge areas to the Deschutes and Little Deschutes Rivers. The effects of present and potential future discharge of ground-water nitrate into the nitrogen-limited Deschutes and Little Deschutes Rivers are not known. However, additions of nitrogen to nitrogen-limited rivers can lead to increases in primary productivity which, in turn, can increase the magnitudes of dissolved oxygen and pH swings in river water. An understanding of the distribution of oxic ground water in the near-river environment could facilitate understanding the vulnerability of these rivers and could be a useful tool for management of these rivers. In this study, transects of temporary wells were installed in sub-river sediments beneath the Deschutes and Little Deschutes Rivers near La Pine to characterize near-river reduction/oxidation (redox) conditions near the ends of ground-water flow paths. Samples from transects installed near the center of the riparian zone or flood plain were consistently suboxic. Where transects were near edges of riparian zones, most ground-water samples also were suboxic. Oxic ground water (other than hyporheic water) was uncommon, and was only detected near the outside edge of some meander bends. This pattern of occurrence likely reflects geochemical controls throughout the aquifer as well as geochemical processes in the microbiologically active riparian zone near the end of ground-water flow paths. Younger, typically less reduced ground water generally enters near-river environments through

  11. Ground Water Redox Zonation near La Pine, Oregon: Relation to River Position within the Aquifer-Riparian Zone Continuum

    Science.gov (United States)

    Hinkle, Stephen R.; Morgan, David S.; Orzol, Leonard L.; Polette, Danial J.

    2007-01-01

    Increasing residential development since in the 1960s has lead to increases in nitrate concentrations in shallow ground water in parts of the 247 square mile study area near La Pine, Oregon. Denitrification is the dominant nitrate-removal process that occurs in suboxic ground water, and suboxic ground water serves as a barrier to transport of most nitrate in the aquifer. Oxic ground water, on the other hand, represents a potential pathway for nitrate transport from terrestrial recharge areas to the Deschutes and Little Deschutes Rivers. The effects of present and potential future discharge of ground-water nitrate into the nitrogen-limited Deschutes and Little Deschutes Rivers are not known. However, additions of nitrogen to nitrogen-limited rivers can lead to increases in primary productivity which, in turn, can increase the magnitudes of dissolved oxygen and pH swings in river water. An understanding of the distribution of oxic ground water in the near-river environment could facilitate understanding the vulnerability of these rivers and could be a useful tool for management of these rivers. In this study, transects of temporary wells were installed in sub-river sediments beneath the Deschutes and Little Deschutes Rivers near La Pine to characterize near-river reduction/oxidation (redox) conditions near the ends of ground-water flow paths. Samples from transects installed near the center of the riparian zone or flood plain were consistently suboxic. Where transects were near edges of riparian zones, most ground-water samples also were suboxic. Oxic ground water (other than hyporheic water) was uncommon, and was only detected near the outside edge of some meander bends. This pattern of occurrence likely reflects geochemical controls throughout the aquifer as well as geochemical processes in the microbiologically active riparian zone near the end of ground-water flow paths. Younger, typically less reduced ground water generally enters near-river environments through

  12. Delineating ground water recharge from leaking irrigation canals using water chemistry and isotopes.

    Science.gov (United States)

    Harvey, F E; Sibray, S S

    2001-01-01

    Across the Great Plains irrigation canals are used to transport water to cropland. Many of these canals are unlined, and leakage from them has been the focus of an ongoing legal, economic, and philosophical debate as to whether this lost water should be considered waste or be viewed as a beneficial and reasonable use since it contributes to regional ground water recharge. While historically there has been much speculation about the impact of canal leakage on local ground water, actual data are scarce. This study was launched to investigate the impact of leakage from the Interstate Canal, in the western panhandle of Nebraska, on the hydrology and water quality of the local aquifer using water chemistry and environmental isotopes. Numerous monitoring wells were installed in and around a small wetland area adjacent to the canal, and ground water levels were monitored from June 1992 until January 1995. Using the water level data, the seepage loss from the canal was estimated. In addition, the canal, the monitoring wells, and several nearby stock and irrigation wells were sampled for inorganic and environmental isotope analysis to assess water quality changes, and to determine the extent of recharge resulting from canal leakage. The results of water level monitoring within study wells indicates a rise in local ground water levels occurs seasonally as a result of leakage during periods when the canal is filled. This rise redirects local ground water flow and provides water to nearby wetland ecosystems during the summer months. Chemical and isotopic results were used to delineate canal, surface, and ground water and indicate that leaking canal water recharges both the surface alluvial aquifer and upper portions of the underlying Brule Aquifer. The results of this study indicate that lining the Interstate Canal could lower ground water levels adjacent to the canal, and could adversely impact the local aquifer.

  13. Sub-Saharan African ground water protection-building on international experience.

    Science.gov (United States)

    Kreamer, David K; Usher, Brent

    2010-01-01

    Sub-Saharan Africa faces significant challenges in dealing with ground water pollution. These countries can look to successes and missteps on other continents to help choose their own individual paths to ensuring reliable and clean supplies of ground water. In the large view, sub-Saharan Africa can define specific levels of acceptable risk in water quality that drive cleanup efforts and are amenable to acceptance across national and geographic boundaries. Ground water quality databases must be expanded, and data must be available in an electronic form that is flexible, expandable, and uniform, and that can be used over wide geographic areas. Guidance from other continents is available on well construction, sampling and monitoring, interim remediation, technical impracticability, monitored natural attenuation, and many specific issues such as how to deal with small waste generators and septic contamination of water supply wells. It is important to establish a common African view on the appropriateness of other nations' ground water quality guidance for African issues, economic conditions, and community circumstances. Establishing numerical, concentration-based, water quality action levels for pollutants in ground water, which many neighboring African nations could hold comparable, would set the stage for risk-based remediation of contaminated sites. Efforts to gain public, grass-roots understanding and support for stable and balanced enforcement of standards are also key. Finally, effective capacity building in the region could be an eventual solution to ground water quality problems; with increased numbers of trained environmental professionals, ground water throughout the region can be protected and contaminated sites cleaned up.

  14. Radiological status of the ground water beneath the Hanford project, January-December 1979

    Energy Technology Data Exchange (ETDEWEB)

    Eddy, P.A.; Wilbur, J.S.

    1980-04-01

    Operations on the Hanford Site since 1944 have resulted in discharge of large volumes of process cooling water and low-level liquid radioactive waste to the ground. Radioactivity and chemical substances have been carried with these discharges and have reached the Hanford ground water. For may years wells have been used as groundwater sampling structures to gather data on the distribution and movement of these discharges as they interact with the unconfined ground water beneath the site. During 1979, 317 wells were sampled on various frequencies from weekly to annually. This report is one of a series prepared annually to document the evaluation of the status of ground water on the Hanford Site. Data collected during 1979 describe the movement of radionuclide (Tritium and Beta) and nitrate plumes that respond to the influence of groundwater flow, ionic dispersion and radioactive decay.

  15. Questa baseline and pre-mining ground-water quality investigation. 12. Geochemical and reactive-transport modeling based on tracer injection-synoptic sampling studies for the Red River, New Mexico, 2001-2002

    Science.gov (United States)

    Ball, James W.; Runkel, Robert L.; Nordstrom, D. Kirk

    2005-01-01

    Reactive-transport processes in the Red River, downstream from the town of Red River in north-central New Mexico, were simulated using the OTEQ reactive-transport model. The simulations were calibrated using physical and chemical data from synoptic studies conducted during low-flow conditions in August 2001 and during March/April 2002. Discharge over the 20-km reach from the town of Red River to the USGS streamflow-gaging station near the town of Questa ranged from 395 to 1,180 L/s during the 2001 tracer and from 234 to 421 L/s during the 2002 tracer. The pH of the Red River ranged from 7.4 to 8.5 during the 2001 tracer and from 7.1 to 8.7 during the 2002 tracer, and seep and tributary samples had pH values of 2.8 to 9.0 during the 2001 tracer and 3.8 to 7.2 during the 2002 tracer. Mass-loading calculations allowed identification of several specific locations where elevated concentrations of potential contaminants entered the Red River . These locations, characterized by features on the north side of the Red River that are known to be sources of low-pH water containing elevated metal and sulfate concentrations, are: the initial 2.4 km of the study reach, including Bitter Creek, the stream section from 6.2 to 7.8 km, encompassing La Bobita well and the Hansen debris fan, Sulphur Gulch, at about 10.5 km, the area near Portal Springs, from 12.2 to 12.6 km, and the largest contributors of mass loading, the 13.7 to 13.9 km stream section near Cabin Springs and the 14.7 to 17.5 km stream section from Shaft Spring to Thunder Bridge, Goathill Gulch, and Capulin Canyon. Speciation and saturation index calculations indicated that although solubility limits the concentration of aluminum above pH 5.0, at pH values above 7 and aluminum concentrations below 0.3 mg/L inorganic speciation and mineral solubility controls no longer dominate and aluminum-organic complexing may occur. The August 2001 reactive-transport simulations included dissolved iron(II) oxidation, constrained

  16. Tracing ground water input to base flow using sulfate (S, O) isotopes.

    Science.gov (United States)

    Gu, Ailiang; Gray, Floyd; Eastoe, Christopher J; Norman, Laura M; Duarte, Oscar; Long, Austin

    2008-01-01

    Sulfate (S and O) isotopes used in conjunction with sulfate concentration provide a tracer for ground water contributions to base flow. They are particularly useful in areas where rock sources of contrasting S isotope character are juxtaposed, where water chemistry or H and O isotopes fail to distinguish water sources, and in arid areas where rain water contributions to base flow are minimal. Sonoita Creek basin in southern Arizona, where evaporite and igneous sources of sulfur are commonly juxtaposed, serves as an example. Base flow in Sonoita Creek is a mixture of three ground water sources: A, basin ground water with sulfate resembling that from Permian evaporite; B, ground water from the Patagonia Mountains; and C, ground water associated with Temporal Gulch. B and C contain sulfate like that of acid rock drainage in the region but differ in sulfate content. Source A contributes 50% to 70%, with the remainder equally divided between B and C during the base flow seasons. The proportion of B generally increases downstream. The proportion of A is greatest under drought conditions.

  17. Tracing ground water input to base flow using sulfate (S, O) isotopes

    Science.gov (United States)

    Gu, A.; Gray, F.; Eastoe, C.J.; Norman, L.M.; Duarte, O.; Long, A.

    2008-01-01

    Sulfate (S and O) isotopes used in conjunction with sulfate concentration provide a tracer for ground water contributions to base flow. They are particularly useful in areas where rock sources of contrasting S isotope character are juxtaposed, where water chemistry or H and O isotopes fail to distinguish water sources, and in arid areas where rain water contributions to base flow are minimal. Sonoita Creek basin in southern Arizona, where evaporite and igneous sources of sulfur are commonly juxtaposed, serves as an example. Base flow in Sonoita Creek is a mixture of three ground water sources: A, basin ground water with sulfate resembling that from Permian evaporite; B, ground water from the Patagonia Mountains; and C, ground water associated with Temporal Gulch. B and C contain sulfate like that of acid rock drainage in the region but differ in sulfate content. Source A contributes 50% to 70%, with the remainder equally divided between B and C during the base flow seasons. The proportion of B generally increases downstream. The proportion of A is greatest under drought conditions.

  18. Test holes drilled in support of ground-water investigations, Project Gnome, Eddy County, New Mexico

    Science.gov (United States)

    Cooper, J.B.

    1962-01-01

    Project Gnome is a proposed underground nuclear shot to be detonated within a massive salt bed in Eddy County, N. Mex. Potable and neat potable ground water is present in rocks above the salt and is being studied in relation to this nuclear event. This report presents details of two test holes which were drilled to determine ground-water conditions in the near vicinity of the shot point. A well-defined aquifer is present at the site of USGS test hole 1, about 1,000 feet south of the access shaft to the underground shot point. Water with 75 feet of artesian pressure head is contained in the Culebra dolomite member of the Rustler formation. The dolomite aquifer is 32 feet thick and its top lies at a depth of 517 feet below land surface. The aquifer yielded 100 gpm (gallons per minute) with a drawdown of 40 feet during a pumping period of 24 hours. Water was not found in rocks above or below the Culebra dolomite. At the site of USGS test hole 2, about 2 miles southwest of the access shaft no distinctive aquifer exists. About one-half gpm was yielded to the well from the rocks between the Culebra dolomite and the top of the salt. Water could not be detected in the Culebra dolomite or overlying rocks. The report contains drawdown and recovery curves of yield tests, drilling-time charts, and electric logs. The data are given in tables; they include summaries of hole construction, sample description logs, water measurements, drilling-time logs, and water analyses.

  19. Temporal trends in nitrate and selected pesticides in mid-atlantic ground water

    Science.gov (United States)

    Debrewer, L.M.; Ator, S.W.; Denver, J.M.

    2008-01-01

    Evaluating long-term temporal trends in regional ground-water quality is complicated by variable hydrogeologic conditions and typically slow flow, and such trends have rarely been directly measured. Ground-water samples were collected over near-decadal and annual intervals from unconfined aquifers in agricultural areas of the Mid-Atlantic region, including fractured carbonate rocks in the Great Valley, Potomac River Basin, and unconsolidated sediments on the Delmarva Peninsula. Concentrations of nitrate and selected pesticides and degradates were compared among sampling events and to apparent recharge dates. Observed temporal trends are related to changes in land use and chemical applications, and to hydrogeology and climate. Insignificant differences in nitrate concentrations in the Great Valley between 1993 and 2002 are consistent with relatively steady fertilizer application during respective recharge periods and are likely related to drought conditions in the later sampling period. Detecting trends in Great Valley ground water is complicated by long open boreholes characteristic of wells sampled in this setting which facilitate significant ground-water mixing. Decreasing atrazine and prometon concentrations, however, reflect reported changes in usage. On the Delmarva Peninsula between 1988 and 2001, median nitrate concentrations increased 2 mg per liter in aerobic ground water, reflecting increasing fertilizer applications. Correlations between selected pesticide compounds and apparent recharge date are similarly related to changing land use and chemical application. Observed trends in the two settings demonstrate the importance of considering hydrogeology and recharge date along with, changing land and chemical uses when interpreting trends in regional ground-water quality. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  20. General database for ground water site information.

    Science.gov (United States)

    de Dreuzy, Jean-Raynald; Bodin, Jacques; Le Grand, Hervé; Davy, Philippe; Boulanger, Damien; Battais, Annick; Bour, Olivier; Gouze, Philippe; Porel, Gilles

    2006-01-01

    In most cases, analysis and modeling of flow and transport dynamics in ground water systems require long-term, high-quality, and multisource data sets. This paper discusses the structure of a multisite database (the H+ database) developed within the scope of the ERO program (French Environmental Research Observatory, http://www.ore.fr). The database provides an interface between field experimentalists and modelers, which can be used on a daily basis. The database structure enables the storage of a large number of data and data types collected from a given site or multiple-site network. The database is well suited to the integration, backup, and retrieval of data for flow and transport modeling in heterogeneous aquifers. It relies on the definition of standards and uses a templated structure, such that any type of geolocalized data obtained from wells, hydrological stations, and meteorological stations can be handled. New types of platforms other than wells, hydrological stations, and meteorological stations, and new types of experiments and/or parameters could easily be added without modifying the database structure. Thus, we propose that the database structure could be used as a template for designing databases for complex sites. An example application is the H+ database, which gathers data collected from a network of hydrogeological sites associated with the French Environmental Research Observatory.

  1. Electrochemical reduction of hexavalent chromium in ground water

    Energy Technology Data Exchange (ETDEWEB)

    Bansal, S. [Lawrence Livermore National Lab., CA (United States)

    1994-12-01

    Electrochemical reduction of hexavalent chromium (Cr{sup +6}) to its trivalent state (Cr{sup +3}) is showing promising results in treating ground water at Lawrence Livermore National Laboratory`s (LLNL`s) Main Site. An electrolytic cell using stainless-steel and brass electrodes has been found to offer the most efficient reduction while yielding the least amount of precipitate. Trials have successfully lowered concentrations of Cr{sup +6} to below 11 parts per billion (micrograms/liter), the California state standard. We ran several trials to determine optimal voltage for running the cell; each trial consisted of applying a voltage between 6V and 48V for ten minutes through samples obtained at Treatment Facility C(TFC). No conclusive data has been obtained yet.

  2. Ground water quality evaluation near mining area and development of heavy metal pollution index

    Science.gov (United States)

    Prasad, Bably; Kumari, Puja; Bano, Shamima; Kumari, Shweta

    2014-03-01

    Opencast as well as underground coal mining are likely to disturb the underground water table in terms of quantity as well as quality. Added to this is the problem of leachates from the large number of industrial waste and overburden dumps that are in abundance in mining areas, reaching the ground water and adversely affecting its quality. Enhancement of heavy metals contamination of the ground water is one eventuality. In the present work, concentrations of 7 heavy metals have been evaluated at 20 important ground water sampling stations at Dhanbad township situated very near to Jharia coalfields. The concentration of heavy metals in general was found to be below the permissible levels although concentration of iron and manganese was found above the permissible limits at a few stations. These data have been used for the calculation of heavy metal pollution index (HPI). The HPI of ground water in total was found to be 6.8860 which is far below the critical index limit of 100 pointing to the fact that the ground water is not polluted with respect to heavy metals in spite of the prolific growth of mining and allied industrial activities near the town.

  3. The Effect of Degradation of Ground water Resources on Capital of Pistachio Growers in Kerman Province

    Directory of Open Access Journals (Sweden)

    Seyed Mostafa Mortazavi

    2014-12-01

    Full Text Available Real cost evaluation of water is necessary in agricultural products depending on obtained value by this input. In most areas of world especially in arid and semiarid areas, exist over pumping of ground water because the real value of water is much most than the costs of water supply and the lack of fit management water resources. In this study, using a sample of 110 farmers, water dealing value of over using of groundwater in Rafsanjan pistachio production area were investigated. Analysis and regression methods were used in this regard. The average determined value obtained 24 cents, for each share of water in this region which with over drafting of ground water, and decreasing quality and quantity of water has had significant relationship in the one percent significance level. Finally, for elimination or reduction of ground water degradation and its effects, this paper recommended in addition to reduction of licenses for ground water pumping. Determination of optimal economic water/land ratio in new and old pistachio producing areas is the other proposal of this research for alleviation groundwater over drafting effects. Permission for water conduction between wells and combination of fresh and saline water and also using desalination systems are methods for solving low quality of ground water.

  4. Ground-water flow and the possible effects of remedial actions at J-Field, Aberdeen Proving Ground, Maryland

    Science.gov (United States)

    Hughes, W.B.

    1995-01-01

    J-Field, located in the Edgewood Area of Aberdeen Proving Ground, Md, has been used since World War II to test and dispose of explosives, chemical warfare agents, and industrial chemicals resulting in ground-water, surface-water, and soil contami- nation. The U.S. Geological Survey finite-difference model was used to better understand ground-water flow at the site and to simulate the effects of remedial actions. A surficial aquifer and a confined aquifer were simulated with the model. A confining unit separates these units and is represented by leakance between the layers. The area modeled is 3.65 mi2; the model was constructed with a variably spaced 40 X 38 grid. The horizontal and lower boundaries of the model are all no-flow boundaries. Steady-state conditions were used. Ground water at the areas under investigation flows from disposal pit areas toward discharge areas in adjacent estuaries or wetlands. Simulations indicate that capping disposal areas with an impermeable cover effectively slows advective ground water flow by 0.7 to 0.5 times. Barriers to lateral ground-water flow were simulated and effectively prevented the movement of ground water toward discharge areas. Extraction wells were simulated as a way to contain ground-water contamination and to extract ground water for treatment. Two wells pumping 5 gallons per minute each at the toxic-materials disposal area and a single well pumping 2.5 gallons per minute at the riot-control-agent disposal area effectively contained contamination at these sites. A combi- nation of barriers to horizontal flow east and south of the toxic-materials disposal area, and a single extraction well pumping at 5 gallons per minute can extract contaminated ground water and prevent pumpage of marsh water.

  5. Effects of uranium-mining releases on ground-water quality in the Puerco River Basin, Arizona and New Mexico

    Science.gov (United States)

    Van Metre, Peter C.; Wirt, Laurie; Lopes, T.J.; Ferguson, S.A.

    1997-01-01

    Shallow ground water beneath the Puerco River of Arizona and New Mexico was studied to determine the effects of uranium-mining releases on water quality. Ground-water samples collected from 1989 to 1991 indicate that concentrations of dissolved uranium have decreased. Most samples from the alluvial aquifer downstream from Gallup, New Mexico, met with U.S. Environmental Protection Agency's maximum contaminant levels for gross alpha, gross beta, and radium and the proposed maximum contaminant level for uranium.

  6. Spatial and temporal variability of ground water recharge in central Australia: a tracer approach.

    Science.gov (United States)

    Harrington, Glenn A; Cook, Peter G; Herczeg, Andrew L

    2002-01-01

    Two environmental tracer methods are applied to the Ti-Tree Basin in central Australia to shed light on the importance of recharge from floodouts of ephemeral rivers in this arid environment. Ground water carbon-14 concentrations from boreholes are used to estimate the average recharge rate over the interval between where the ground water sample first entered the saturated zone and the bore. Environmental chloride concentrations in ground water samples provide estimates of the recharge rate at the exact point in the landscape where the sample entered the saturated zone. The results of the two tracer approaches indicate that recharge rates around one of the rivers and an extensive floodplain are generally higher than rates of diffuse recharge that occurs in areas of lower topographic relief. Ground water 2H/1H and 18O/16O compositions are all depleted in the heavier isotopes (delta2H = -67 per thousand to -50 per thousand; delta18O = -9.2 per thousand to -5.7%o) compared with the long-term, amount-weighted mean isotopic composition of rainfall in the area (delta2H = -33.8 per thousand; delta18O = -6.3 per thousand). This indicates that recharge throughout the basin occurs only after intense rainfall events of at least 150 to 200 mm/month. Finally, a recharge map is developed to highlight the spatial extent of the two recharge mechanisms. Floodout recharge to the freshest ground water (TDS recharge rate of approximately 0.2 mm/year to the remainder of the basin. These findings have important implications for management of the ground water resource.

  7. Methyl tert-Butyl Ether (MTBE) in Ground Water, Air, and Precipitation at North Windham, Maine

    Science.gov (United States)

    Nielsen, Martha G.; Peckenham, John M.

    2000-01-01

    Thirty-one monitoring wells in the Windham aquifer in North Windham, Maine, were sampled for methyl tert-butyl ether (MTBE) from July 1998 to May 1999. MTBE was detected in 35 percent of the wells sampled in the Windham aquifer. MTBE was detected in 64 percent of wells in the high-yielding part of the aquifer; these wells account for 82 percent of all wells with detectable MTBE. Land cover also was found to be associated with MTBE in the wells in the study area, with the urban and low-density residential areas having more MTBE than undeveloped areas. The median concentration in wells with detectable MTBE was 1.13 micrograms per liter. Air and precipitation samples were collected in North Windham along with ground-water samples. Air samples were collected every 10 days from December 1998 to July 1999 (20 samples). MTBE was present in all 20 air samples collected, at concentrations ranging from 0.03 ppbv (parts per billion by volume) to 1.0 ppbv. Before Maine opted out of the reformulated gasoline (RFG) program in the spring of 1999, median concentrations in air at the North Windham site were 0.25 ppbv. After Maine stopped using RFG, the median concentration in air dropped to 0.09 ppbv. No MTBE was detected in four samples of precipitation at North Windham. The lack of rainfall during the study period prevented the collection of an adequate number of samples, and technical difficulties negated the results of some of the analyses of the samples that were collected. Based on the equilibrium partitioning of MTBE from the air into rain, the hypothetical average concentration of MTBE in rainfall during months when recharge typically occurs (March-April and October-December) would be approximately 0.3 to 0.4 micrograms per liter during the time that RFG was being used in Maine. After the phaseout of RFG, the maximum average concentration of MTBE in rainfall during these months would be approximately 0.1 micrograms per liter. The distribution and concentrations of MTBE that

  8. Ground-water and geohydrologic conditions in Queens County, Long Island, New York

    Science.gov (United States)

    Soren, Julian

    1971-01-01

    Queens County is a heavily populated borough of New York City, at the western end of Long Island, N. Y., in which large amounts of ground water are used, mostly for public supply. Ground water, pumped from local aquifers, by privately owned water-supply companies, supplied the water needs of about 750,000 of the nearly 2 million residents of the county in 1967; the balance was supplied by New York City from surface sources outside the county in upstate New York. The county's aquifers consist of sand and gravel of Late Cretaceous and of Pleistocene ages, and the aquifers comprise a wedge-shaped ground-water reservoir lying on a southeastward-sloping floor of Precambrian(?) bedrock. Beds of clay and silt generally confine water in the deeper parts of the reservoir; water in the deeper aquifers ranges from poorly confined to well confined. Wisconsin-age glacial deposits in the uppermost part of the reservoir contain ground water under water-table conditions. Ground water pumpage averaged about 60 mgd (million gallons per day) in Queens County from about 1900 to 1967. Much of the water was used in adjacent Kings County, another borough of New York City, prior to 1950. The large ground-water withdrawal has resulted in a wide-spread and still-growing cone of depression in the water table, reflecting a loss of about 61 billion gallons of fresh water from storage. Significant drawdown of the water table probably began with rapid urbanization of Queens County in the 1920's. The county has been extensively paved, and storm and sanitary sewers divert water, which formerly entered the ground, to tidewater north and south of the county. Natural recharge to the aquifers has been reduced to about one half of the preurban rate and is below the withdrawal rate. Ground-water levels have declined more than 40. feet from the earliest-known levels, in 1903, to 1967, and the water table is below sea level in much of the county. The aquifers are being contaminated by the movement of

  9. Ground-water quality and vulnerability to contamination in selected agricultural areas of southeastern Michigan, northwestern Ohio, and northeastern Indiana

    Science.gov (United States)

    Thomas, Mary Ann

    2000-01-01

    Ground-water quality was assessed in the northeastern part of the Corn Belt, where tile-drained row crops are underlain by fractured glacial till. Data were collected from 30 shallow monitor wells and 18 co-located domestic wells as part of the U.S. Geological Survey?s National Water-Quality Assessment in the Lake Erie-Lake St. Clair Basin. Pesticides or pesticide degradates were detected in 41 percent of the monitor wells and 6 percent of the domestic wells. The pesticides detected closely correspond to those most heavily applied?herbicides used on corn and soybeans. Pesticide degradates were detected three times more frequently, and at higher concentrations, than were parent compounds. No pesticide concentration exceeded a USEPA Maximum Contaminant Level (MCL), but MCL?s have not been established for 9 of the 11 compounds detected. Thirty-seven percent of monitor-well samples had nitrate concentrations indicative of human influences such as fertilizer, manure or septic systems. Nitrate was the only chemical constituent detected at a concentration greater than an MCL. The MCL was exceeded in 7 percent of samples from monitor wells which were too shallow to be used as a source of drinking water. Pesticide and nitrate concentrations in the study area are low relative to other agricultural areas of the Nation. Several authors have suggested that ground water in parts of the Upper Mid-west is minimally contaminated because it is protected by the surficial glacial till or tile drains. These ideas are examined in light of the relations between concentration, well depth, and ground-water age in the study area. Most of the shallow ground water is hydraulically connected to the land surface, based on the observations that 83 percent of waters from monitor wells were recharged after 1953, and 57 percent contained a pesticide or an elevated nitrate concentration. Fractures or sand-and-gravel stringers within the till are the probable pathways. In some areas, deeper parts of

  10. Hydrochemistry of the Mahomet Bedrock Valley Aquifer, East-Central Illinois: indicators of recharge and ground-water flow

    Science.gov (United States)

    Panno, S.V.; Hackley, Keith C.; Cartwright, K.; Liu, Chao-Li

    1994-01-01

    A conceptual model of the ground-water flow and recharge to the Mahomet Bedrock Valley Aquifer (MVA), east-central Illinois, was developed using major ion chemistry and isotope geochemistry. The MVA is a 'basal' fill in the east-west trending buried bedrock valley composed of clean, permeable sand and gravel to thicknesses of up to 61 m. It is covered by a thick sequence of glacial till containing thinner bodies of interbedded sand and gravel. Ground water from the MVA was found to be characterized by clearly defined geochemical regions with three distinct ground-water types. A fourth ground-water type was found at the confluence of the MVA and the Mackinaw Bedrock Valley Aquifer (MAK) to the west. Ground water in the Onarga Valley, a northeastern tributary of the MVA, is of two types, a mixed cation-SO42- type and a mixed cation-HCO3- type. The ground water is enriched in Na+, Ca2+, Mg2+, and SO42- which appears to be the result of an upward hydraulic gradient and interaction of deeper ground water with oxidized pyritic coals and shale. We suggest that recharge to the Onarga Valley and overlying aquifers is 100% from bedrock (leakage) and lateral flow from the MVA to the south. The central MVA (south of the Onarga Valley) is composed of relatively dilute ground water of a mixed cation-HCO3- type, with low total dissolved solids, and very low concentrations of Cl- and SO42-. Stratigraphic relationships of overlying aquifers and ground-water chemistry of these and the MVA suggest recharge to this region of the MVA (predominantly in Champaign County) is relatively rapid and primarily from the surface. Midway along the westerly flow path of the MVA (western MVA), ground water is a mixed cation-HCO3- type with relatively high Cl-, where Cl- increases abruptly by one to ??? two orders of magnitude. Data suggest that the increase in Cl- is the result of leakage of saline ground water from bedrock into the MVA. Mass-balance calculations indicate that approximately 9.5% of

  11. Quality-control results for ground-water and surface-water data, Sacramento River Basin, California, National Water-Quality Assessment, 1996-1998

    Science.gov (United States)

    Munday, Cathy; Domagalski, Joseph L.

    2003-01-01

    Evaluating the extent that bias and variability affect the interpretation of ground- and surface-water data is necessary to meet the objectives of the National Water-Quality Assessment (NAWQA) Program. Quality-control samples used to evaluate the bias and variability include annual equipment blanks, field blanks, field matrix spikes, surrogates, and replicates. This report contains quality-control results for the constituents critical to the ground- and surface-water components of the Sacramento River Basin study unit of the NAWQA Program. A critical constituent is one that was detected frequently (more than 50 percent of the time in blank samples), was detected at amounts exceeding water-quality standards or goals, or was important for the interpretation of water-quality data. Quality-control samples were collected along with ground- and surface-water samples during the high intensity phase (cycle 1) of the Sacramento River Basin NAWQA beginning early in 1996 and ending in 1998. Ground-water field blanks indicated contamination of varying levels of significance when compared with concentrations detected in environmental ground-water samples for ammonia, dissolved organic carbon, aluminum, and copper. Concentrations of aluminum in surface-water field blanks were significant when compared with environmental samples. Field blank samples collected for pesticide and volatile organic compound analyses revealed no contamination in either ground- or surface-water samples that would effect the interpretation of environmental data, with the possible exception of the volatile organic compound trichloromethane (chloroform) in ground water. Replicate samples for ground water and surface water indicate that variability resulting from sample collection, processing, and analysis was generally low. Some of the larger maximum relative percentage differences calculated for replicate samples occurred between samples having lowest absolute concentration differences and(or) values near

  12. 40 CFR 257.3-4 - Ground water.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground water. 257.3-4 Section 257.3-4... and Practices § 257.3-4 Ground water. (a) A facility or practice shall not contaminate an underground drinking water source beyond the solid waste boundary or beyond an alternative boundary specified...

  13. Ground-water conditions in Whisky Flat, Mineral County, Nevada

    Science.gov (United States)

    Eakin, T.E.; Robinson, T.W.

    1950-01-01

    As a part of the State-wide cooperative program between the Office of the State Engineer of Nevada and the U.S. Geological Survey, the Ground Water Branch of the Geological Survey made a reconnaissance study of ground-water conditions in Whisky Flat, Mineral County, Nevada.

  14. IN-SITU BIOREMEDIATION OF CONTAMINATED GROUND WATER

    Science.gov (United States)

    This document is one in a series of Ground Water Issue papers which have been prepared in response to needs expressed by the Ground Water Forum. It is based on findings from the research community in concert with experience gained at sites undergoing remediation. the intent of th...

  15. Ground water hydrology report: Revision 1, Attachment 3. Final

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    This report presents ground water hydrogeologic activities for the Maybell, Colorado, Uranium Mill Tailings Remedial Action Project site. The Department of Energy has characterized the hydrogeology, water quality, and water resources at the site and determined that the proposed remedial action would comply with the requirements of the EPA ground water protection standards.

  16. Procedures for ground-water investigations. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program.

  17. Evaluation of geohydrologic framework, recharge estimates and ground-water flow of the Joshua Tree area, San Bernardino County, California

    Science.gov (United States)

    Nishikawa, Tracy; Izbicki, John A.; Hevesi, Joseph A.; Stamos, Christina L.; Martin, Peter

    2005-01-01

    Ground water historically has been the sole source of water supply for the community of Joshua Tree in the Joshua Tree ground-water subbasin of the Morongo ground-water basin in the southern Mojave Desert. The Joshua Basin Water District (JBWD) supplies water to the community from the underlying Joshua Tree ground-water subbasin. The JBWD is concerned with the long-term sustainability of the underlying aquifer. To help meet future demands, the JBWD plans to construct production wells in the adjacent Copper Mountain ground-water subbasin. As growth continues in the desert, there may be a need to import water to supplement the available ground-water resources. In order to manage the ground-water resources and to identify future mitigating measures, a thorough understanding of the ground-water system is needed. The purpose of this study was threefold: (1) improve the understanding of the geohydrologic framework of the Joshua Tree and Copper Mountain ground-water subbasins, (2) determine the distribution and quantity of recharge using field and numerical techniques, and (3) develop a ground-water flow model that can be used to help manage the water resources of the region. The geohydrologic framework was refined by collecting and interpreting water-level and water-quality data, geologic and electric logs, and gravity data. The water-bearing deposits in the Joshua Tree and Copper Mountain ground-water subbasins are Quarternary alluvial deposits and Tertiary sedimentary and volcanic deposits. The Quarternary alluvial deposits were divided into two aquifers (referred to as the 'upper' and the 'middle' alluvial aquifers), which are about 600 feet (ft) thick, and the Tertiary sedimentary and volcanic deposits were assigned to a single aquifer (referred to as the 'lower' aquifer), which is as thick as 1,500 ft. The ground-water quality of the Joshua Tree and Copper Mountain ground-water subbasins was defined by collecting 53 ground-water samples from 15 wells (10 in the

  18. Ground-water flow related to streamflow and water quality

    Science.gov (United States)

    Van Voast, W. A.; Novitzki, R.P.

    1968-01-01

    A ground-water flow system in southwestern Minnesota illustrates water movement between geologic units and between the land surface and the subsurface. The flow patterns indicate numerous zones of ground-water recharge and discharge controlled by topography, varying thicknesses of geologic units, variation in permeabilities, and the configuration of the basement rock surface. Variations in streamflow along a reach of the Yellow Medicine River agree with the subsurface flow system. Increases and decreases in runoff per square mile correspond, apparently, to ground-water discharge and recharge zones. Ground-water quality variations between calcium sulfate waters typical of the Quaternary drift and sodium chloride waters typical of the Cretaceous rocks are caused by mixing of the two water types. The zones of mixing are in agreement with ground-water flow patterns along the hydrologic section.

  19. Ground Water Monitoring Using Laser Fluorescence And Fiber Optics

    Science.gov (United States)

    Chudyk, Wayne; Pohlig, Kenneth; Rico, Nicola; Johnson, Gregory

    1989-01-01

    In-situ measurement of aromatic ground water contaminants, including the benzene, ethylbenzene, toluene, and xylenes (BTEX) fraction of gasoline, has been demonstrated using fiber optic systems. A prototype field instrument has shown that this method has advantages over traditional sampling and analysis. Problems encountered and solved include coupling of the laser energy into to fiber, sensor design, and detector configuration to optimize instrument sensitivity. The effects of sensor length, corresponding to well depth, on limits of detection are presented. Effects of potential interferences, including external fluorescence quenchers, are discuss-ed. The resolution of complex mixtures is addressed, with modifications to the detector shown to be effective in separation of groups of contaminants. Instrument design considerations include the need for portability, ruggedness at field sites, and ease of operation. The modular instrument design used is shown to help solve these potential problems, while maintaining analytical sensitivity and reproducibility. Modular optical system design has also shown to be useful when modifications are made. Changes in the detector as well as provisions for multiple laser sources have allowed a flexible system to be configured to meet analytical demands as they arise. Sensor design considerations included high ultraviolet transmission, physical flexibility, resistance to breakage, and resistance to chemical and/or biological fouling. The approach to these problem areas is presented, as well as discussion of the methods used to minimize effects of fiber solarization. Results of testing the field portable prototype are presented for a variety of typical ground water analysis sites, illustrating the usefulness of this new technology in environmental monitoring.

  20. Design and analysis of a natural-gradient ground-water tracer test in a freshwater tidal wetland, West Branch Canal Creek, Aberdeen Proving Ground, Maryland

    Science.gov (United States)

    Olsen, Lisa D.; Tenbus, Frederick J.

    2005-01-01

    A natural-gradient ground-water tracer test was designed and conducted in a tidal freshwater wetland at West Branch Canal Creek, Aberdeen Proving Ground, Maryland. The objectives of the test were to characterize solute transport at the site, obtain data to more accurately determine the ground-water velocity in the upper wetland sediments, and to compare a conservative, ionic tracer (bromide) to a volatile tracer (sulfur hexafluoride) to ascertain whether volatilization could be an important process in attenuating volatile organic compounds in the ground water. The tracer test was conducted within the upper peat unit of a layer of wetland sediments that also includes a lower clayey unit; the combined layer overlies an aquifer. The area selected for the test was thought to have an above-average rate of ground-water discharge based on ground-water head distributions and near-surface detections of volatile organic compounds measured in previous studies. Because ground-water velocities in the wetland sediments were expected to be slow compared to the underlying aquifer, the test was designed to be conducted on a small scale. Ninety-seven ?-inch-diameter inverted-screen stainless-steel piezometers were installed in a cylindrical array within approximately 25 cubic feet (2.3 cubic meters) of wetland sediments, in an area with a vertically upward hydraulic gradient. Fluorescein dye was used to qualitatively evaluate the hydrologic integrity of the tracer array before the start of the tracer test, including verifying the absence of hydraulic short-circuiting due to nonnatural vertical conduits potentially created during piezometer installation. Bromide and sulfur hexafluoride tracers (0.139 liter of solution containing 100,000 milligrams per liter of bromide ion and 23.3 milligrams per liter of sulfur hexafluoride) were co-injected and monitored to generate a dataset that could be used to evaluate solute transport in three dimensions. Piezometers were sampled 2 to 15 times

  1. [Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio]. Volume 5, Appendix A, Part 1, Field Investigation report

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    This report presents information related to the sampling of ground water at the Wright-Patterson Air Force Base. It is part of an investigation into possible ground water contamination. Information concerns well drilling/construction; x-ray diffraction and sampling; soil boring logs; and chain-of-custody records.

  2. City of Flagstaff Project: Ground Water Resource Evaluation, Remote Sensing Component

    Science.gov (United States)

    Chavez, Pat S.; Velasco, Miguel G.; Bowell, Jo-Ann; Sides, Stuart C.; Gonzalez, Rosendo R.; Soltesz, Deborah L.

    1996-01-01

    Many regions, cities, and towns in the Western United States need new or expanded water resources because of both population growth and increased development. Any tools or data that can help in the evaluation of an area's potential water resources must be considered for this increasingly critical need. Remotely sensed satellite images and subsequent digital image processing have been under-utilized in ground water resource evaluation and exploration. Satellite images can be helpful in detecting and mapping an area's regional structural patterns, including major fracture and fault systems, two important geologic settings for an area's surface to ground water relations. Within the United States Geological Survey's (USGS) Flagstaff Field Center, expertise and capabilities in remote sensing and digital image processing have been developed over the past 25 years through various programs. For the City of Flagstaff project, this expertise and these capabilities were combined with traditional geologic field mapping to help evaluate ground water resources in the Flagstaff area. Various enhancement and manipulation procedures were applied to the digital satellite images; the results, in both digital and hardcopy format, were used for field mapping and analyzing the regional structure. Relative to surface sampling, remotely sensed satellite and airborne images have improved spatial coverage that can help study, map, and monitor the earth surface at local and/or regional scales. Advantages offered by remotely sensed satellite image data include: 1. a synoptic/regional view compared to both aerial photographs and ground sampling, 2. cost effectiveness, 3. high spatial resolution and coverage compared to ground sampling, and 4. relatively high temporal coverage on a long term basis. Remotely sensed images contain both spectral and spatial information. The spectral information provides various properties and characteristics about the surface cover at a given location or pixel

  3. THE ASSESSMENT OF GROUND WATERS POLLUTION WITH PETROCHEMICALS AROUND CIVIL AVIATION ENTERPRISES

    Directory of Open Access Journals (Sweden)

    Svitlana Madzhd

    2015-04-01

    Full Text Available In the article we determine the level of ground waters pollution with oil hydrocarbons around the enterprises of aviation machines exploitation and repair. The calculations of the sample size required to achieve 95 % confidence probability of petrochemicals content analysis have been resulted. The sanitary hygienic assessment of drinking water from the wells around the civil aviation enterprises has been conducted.

  4. Astronaut Alan Bean holds Special Environmental Sample Container

    Science.gov (United States)

    1969-01-01

    Astronaut Alan L. Bean, lunar module pilot for the Apollo 12 lunar landing mission, holds a Special Environmental Sample Container filled with lunar soil collected during the extravehicular activity (EVA) in which Astronauts Charles Conrad Jr., commander, and Bean participated. Connrad, who took this picture, is reflected in the helmet visor of the lunar module pilot.

  5. Questa baseline and pre-mining ground-water-quality investigation. 16. Quality assurance and quality control for water analyses

    Science.gov (United States)

    McCleskey, R. Blaine; Nordstrom, D. Kirk; Naus, Cheryl A.

    2004-01-01

    The Questa baseline and pre-mining ground-water quality investigation has the main objective of inferring the ground-water chemistry at an active mine site. Hence, existing ground-water chemistry and its quality assurance and quality control is of crucial importance to this study and a substantial effort was spent on this activity. Analyses of seventy-two blanks demonstrated that contamination from processing, handling, and analyses were minimal. Blanks collected using water deionized with anion and cation exchange resins contained elevated concentrations of boron (0.17 milligrams per liter (mg/L)) and silica (3.90 mg/L), whereas double-distilled water did not. Boron and silica were not completely retained by the resins because they can exist as uncharged species in water. Chloride was detected in ten blanks, the highest being 3.9 mg/L, probably as the result of washing bottles, filter apparatuses, and tubing with hydrochloric acid. Sulfate was detected in seven blanks; the highest value was 3.0 mg/L, most likely because of carryover from the high sulfate waters sampled. With only a few exceptions, the remaining blank analyses were near or below method detection limits. Analyses of standard reference water samples by cold-vapor atomic fluorescence spectrometry, ion chromatography, inductively coupled plasma-optical emission spectrometry, inductively coupled plasma-mass spectrometry, FerroZine, graphite furnace atomic absorption spectrometry, hydride generation atomic spectrometry, and titration provided an accuracy check. For constituents greater than 10 times the detection limit, 95 percent of the samples had a percent error of less than 8.5. For constituents within 10 percent of the detection limit, the percent error often increased as a result of measurement imprecision. Charge imbalance was calculated using WATEQ4F and 251 out of 257 samples had a charge imbalance less than 11.8 percent. The charge imbalance for all samples ranged from -16 to 16 percent. Spike

  6. Movement of coliform bacteria and nutrients in ground water flowing through basalt and sand aquifers.

    Science.gov (United States)

    Entry, J A; Farmer, N

    2001-01-01

    Large-scale deposition of animal manure can result in contamination of surface and ground water and in potential transfer of disease-causing enteric bacteria to animals or humans. We measured total coliform bacteria (TC), fecal coliform bacteria (FC), NO3, NH4, total P, and PO4 in ground water flowing from basalt and sand aquifers, in wells into basalt and sand aquifers, in irrigation water, and in river water. Samples were collected monthly for 1 yr. Total coliform and FC numbers were always higher in irrigation water than in ground water, indicating that soil and sediment filtered most of these bacteria before they entered the aquifers. Total coliform and FC numbers in ground water were generally higher in the faster flowing basalt aquifer than in the sand aquifer, indicating that the slower flow and finer grain size may filter more TC and FC bacteria from water. At least one coliform bacterium/100 mL of water was found in ground water from both basalt and sand aquifers, indicating that ground water pumped from these aquifers is not necessarily safe for human consumption according to the American Public Health Association and the USEPA. The NO3 concentrations were usually higher in water flowing from the sand aquifer than in water flowing from the basalt aquifer or in perched water tables in the basalt aquifer. The PO4 concentrations were usually higher in water flowing from the basalt aquifer than in water flowing from the sand aquifer. The main concern is fecal contamination of these aquifers and health consequences that may arise from human consumption.

  7. Heat, chloride, and specific conductance as ground water tracers near streams

    Science.gov (United States)

    Cox, M.H.; Su, G.W.; Constantz, J.

    2007-01-01

    Commonly measured water quality parameters were compared to heat as tracers of stream water exchange with ground water. Temperature, specific conductance, and chloride were sampled at various frequencies in the stream and adjacent wells over a 2-year period. Strong seasonal variations in stream water were observed for temperature and specific conductance. In observation wells where the temperature response correlated to stream water, chloride and specific conductance values were similar to stream water values as well, indicating significant stream water exchange with ground water. At sites where ground water temperature fluctuations were negligible, chloride and/or specific conductance values did not correlate to stream water values, indicating that ground water was not significantly influenced by exchange with stream water. Best-fit simulation modeling was performed at two sites to derive temperature-based estimates of hydraulic conductivities of the alluvial sediments between the stream and wells. These estimates were used in solute transport simulations for a comparison of measured and simulated values for chloride and specific conductance. Simulation results showed that hydraulic conductivities vary seasonally and annually. This variability was a result of seasonal changes in temperature-dependent hydraulic conductivity and scouring or clogging of the streambed. Specific conductance fits were good, while chloride data were difficult to fit due to the infrequent (quarterly) stream water chloride measurements during the study period. Combined analyses of temperature, chloride, and specific conductance led to improved quantification of the spatial and temporal variability of stream water exchange with shallow ground water in an alluvial system. ?? 2007 National Ground Water Association.

  8. Ground-water contribution to dose from past Hanford Operations

    Energy Technology Data Exchange (ETDEWEB)

    Freshley, M.D.; Thorne, P.D.

    1992-08-01

    The Hanford Environmental Dose Reconstruction (HEDR) Project is being conducted to estimate radiation doses that populations and individuals could have received from Hanford Site operations from 1944 to the present. Four possible pathways by which radionuclides migrating in ground water on the Hanford Site could have reached the public have been identified: (1) through contaminated ground water migrating to the Columbia River; (2) through wells on or adjacent to the Hanford Site; (3) through wells next to the Columbia River downstream of Hanford that draw some or all of their water from the river (riparian wells); and (4) through atmospheric deposition resulting in contamination of a small watershed that, in turn, results in contamination of a shallow well or spring by transport in the ground water. These four pathways make up the ground-water pathway,'' which is the subject of this study. Assessment of the ground-water pathway was performed by (1) reviewing the existing extensive literature on ground water and ground-water monitoring at Hanford and (2) performing calculations to estimate radionuclide concentrations where no monitoring data were collected. Radiation doses that would result from exposure to these radionuclides were calculated.

  9. Hanford Site ground-water monitoring for 1994

    Energy Technology Data Exchange (ETDEWEB)

    Dresel, P.E.; Thorne, P.D.; Luttrell, S.P. [and others

    1995-08-01

    This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1994 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiologic and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1994 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1993 and June 1994. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal.

  10. Environmental impact of municipal dumpsite leachate on ground-water quality in Jawaharnagar, Rangareddy, Telangana, India

    Science.gov (United States)

    Soujanya Kamble, B.; Saxena, Praveen Raj

    2016-10-01

    The aim of the present work was to study the impact of dumpsite leachate on ground-water quality of Jawaharnagar village. Leachate and ground-water samples were investigated for various physico-chemical parameters viz., pH, total dissolved solids (TDS), total hardness (TH), calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), chloride (Cl-), carbonates (CO3 2-), bicarbonates (HCO3 -), nitrates (NO3 -), and sulphates (SO4 2-) during dry and wet seasons in 2015 and were reported. The groundwater was hard to very hard in nature, and the concentrations of total dissolved solids, chlorides, and nitrates were found to be exceeding the permissible levels of WHO drinking water quality standards. Piper plots revealed that the dominant hydrochemical facies of the groundwater were of calcium chloride (CaCl2) type and alkaline earths (Ca2+ and Mg2+) exceed the alkali (Na+ and SO4 2-), while the strong acids (Cl- and SO4 2-) exceed the weak acids (CO3 2- and HCO3 -). According to USSL diagram, all the ground-water samples belong to high salinity and low-sodium type (C3S1). Overall, the ground-water samples collected around the dumpsite were found to be polluted and are unfit for human consumption but can be used for irrigation purpose with heavy drainage and irrigation patterns to control the salinity.

  11. Assessment of ground water quality for drinking purpose, District Nainital, Uttarakhand, India.

    Science.gov (United States)

    Jain, C K; Bandyopadhyay, A; Bhadra, A

    2010-07-01

    The ground water quality of District Nainital (Uttarakhand, India) has been assessed to see the suitability of ground water for drinking and irrigation applications. This is a two-part series paper and this paper examines the suitability of ground water including spring water for drinking purposes. Forty ground water samples (including 28 spring samples) were collected during pre- and post-monsoon seasons and analyzed for various water quality constituents. The hydrochemical and bacteriological data was analyzed with reference to BIS and WHO standards and their hydrochemical facies were determined. The concentration of total dissolved solids exceeds the desirable limit of 500 mg/L in about 10% of the samples, alkalinity values exceed the desirable limit of 200 mg/L in about 30% of the samples, and total hardness values exceed the desirable limit of 300 mg/L in 15% of the samples. However, no sample crosses the maximum permissible limit for TDS, alkalinity, hardness, calcium, magnesium, chloride, sulfate, nitrate, and fluoride. The concentration of chloride, sulfate, nitrate, and fluoride are well within the desirable limit at all the locations. The bacteriological analysis of the samples does not show any sign of bacterial contamination in hand pump and tube-well water samples. However, in the case of spring water samples, six samples exceed the permissible limit of ten coliforms per 100 ml of sample. It is recommended that water drawn from such sources should be properly disinfected before being used for drinking and other domestic applications. Among the metal ions, the concentration of iron and lead exceeds the permissible limit at one location whereas the concentration of nickel exceeds the permissible limit in 60 and 32.5% of the samples during pre- and post-monsoon seasons, respectively. The grouping of samples according to their hydrochemical facies indicates that majority of the samples fall in Ca-Mg-HCO(3) hydrochemical facies.

  12. Environmental Effect / Impact Assessment of Industrial Effulent on Ground Water

    Directory of Open Access Journals (Sweden)

    Dr. Parmod Kumar

    2013-12-01

    Full Text Available In the present study the aim of investigation is physical and chemical parameters of ground water and soil. By selected Physical and chemical parameters it is found that (1.Biological oxygen demand (BOD and chemical oxygen demand (COD are directly proportional to each other where dissolved oxygen (DO is indirectly proportional to BOD and COD. (2. Total dissolved solids, alkalinity and hardness are significantly higher in pre monsoon and winter season as compared to monsoon season.(3. High values of different parameters of ground water sources indicate the influence of industrial wastes on ground water.

  13. Ground-water and precipitation data for South Carolina, 1990

    Science.gov (United States)

    Conrads, Paul A.; Jones, Kathy H.; Stringfield, Whitney J.

    1994-01-01

    Continuous water-level data collected from 53 wells in South Carolina during 1990 provide the basic data for this report. Hydrographs are presented for selected wells to illustrate the effects that changes in ground-water recharge and artificial ground-water discharge have had on the ground-water reservoirs in the State. Daily mean water levels are listed in tables. Monthly mean water levels for 1990 and for the entire period of record at each monitoring well are depicted in hydrographs. Also included are precipitation records from ten National Weather Service stations in South Carolina.

  14. The hydrogeologic framework and a reconnaissance of ground-water quality in the Piedmont Province of North Carolina, with a design for future study

    Science.gov (United States)

    Harned, Douglas

    1989-01-01

    The U.S. Geological Survey is investigating the relation of ground- water quality and land use in the regolith and fractured rock ground-water system of the North Carolina Piedmont. The initial phase of this study provides a description of the ground-water flow system and a review of available ground-water data and formulates hypotheses that guide the design of a water-quality monitoring network for study of selected areas. In the Piedmont, the solid igneous and metamorphic bedrock grades upward into unweathered fractured rock that is covered by a transition zone of highly-fractured, partially weathered rock, clay-rich saprolite, and the soil. The fractured bedrock, transition zone, saprolite, and soil make up a complex flow system. A review of available ground-water quality data shows a lack of information about organic compounds and trace metals and changes in ground- water quality with depth. Land use, soils, and geology significantly influence ground-water quality. The hypotheses that need to be tested in the next study phase are: (1) that ground-water contamination can be related to land use, and (2) that the transition zone between bedrock and regolith serves as a primary transmitter of contaminants. Monitoring of basins containing industrial, urban, residential, and agricultural land uses in future studies will help define the relation of ground-water quality to land use. Water quality at different depths in the flow system and in streams during base flow needs to be identified.

  15. Death Valley regional ground-water flow system, Nevada and California -- hydrogeologic framework and transient ground-water flow model

    Science.gov (United States)

    : Belcher, Wayne R.

    2004-01-01

    A numerical three-dimensional (3D) transient ground-water flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the ground-water flow system and previous less extensive ground-water flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect ground-water flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley Regional Ground-Water Flow System (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the ground-water flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural ground-water discharge occurring through evapotranspiration and spring flow; the history of ground-water pumping from 1913 through 1998; ground-water recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were

  16. Distinguishing sources of ground water recharge by using delta2H and delta18O.

    Science.gov (United States)

    Blasch, Kyle W; Bryson, Jeannie R

    2007-01-01

    Stable isotope values of hydrogen and oxygen from precipitation and ground water samples were compared by using a volumetrically based mixing equation and stable isotope gradient to estimate the season and location of recharge in four basins. Stable isotopes were sampled at 11 precipitation sites of differing elevation during a 2-year period to quantify seasonal stable isotope contributions as a function of elevation. Supplemental stable isotope data collected by the International Atomic Energy Association during a 14-year period were used to reduce annual variability of the mean seasonal stable isotope data. The stable isotope elevation relationships and local precipitation elevation relationships were combined by using a digital elevation model to calculate the total volumetric contribution of water and stable isotope values as a function of elevation within the basins. The results of these precipitation calculations were compared to measured ground water stable isotope values at the major discharge points near the terminus of the basins. Volumetric precipitation contributions to recharge were adjusted to isolate contributing elevations. This procedure provides an improved representation of recharge contributions within the basins over conventional stable isotope methods. Stable isotope values from wells and springs at the terminus of each basin were used to infer the elevations of precipitation important for recharge of the regional ground water flow system. Ancillary climatic, geologic, and stable isotope values were used to further constrain the location where precipitation is entering the ground water flow system.

  17. Determination of 210Pb and 222Rn in ground water of Okinawa Island

    Science.gov (United States)

    Ito, M.; Tanahara, A.

    2012-12-01

    In this study, we developed the method of 210Pb measurement from a large amount of ground water. The chelating resin (NOBIAS CHELATE-PA1; Hitachi High-technology) column combined with the ion-exchange resin (DOWEX-88; Dow Chemical Company) column were used for pre-treatment of 210Pb from ground water of 20 litter. It should be mentioned that this determination procedure is simple, fast, and give high recovery (more than 80 %). It avoids precipitation and large consumption of chemicals. Finally 210Pb was precipitated as PbSO4 and determined with low background 2πgas flow counter. 210Pb concentration in ground water of Okinawa Island ranged from 1.40-16.7 mBq/L. We also found that the organo-210Pb complex which could not be detected by this method was involved in some water samples. By increasing the column radius and the resin mass, while keeping a constant height of the resin column, it is possible to additionally increase the flow rate and accelerate the isolation procedure. 222Rn was determined by the direct method. The emulsion scintillation cocktail (10 mL) and water sample (10 mL) were put into a vial. After shaking and stand for 200 min, 222Rn was counted by LSC for 120 min. 222Rn concentration in ground water of Okinawa Island ranged from 0.71-14.0 Bq/L.

  18. Decadal-scale changes of nitrate in ground water of the United States, 1988-2004

    Science.gov (United States)

    Rupert, Michael G.

    2008-01-01

    This study evaluated decadal-scale changes of nitrate concentrations in groundwater samples collected by the USGS National Water-Quality Assessment Program from 495 wells in 24 well networks across the USA in predominantly agricultural areas. Each well network was sampled once during 1988-1995 and resampled once during 2000-2004. Statistical tests of decadal-scale changes of nitrate concentrations in water from all 495 wells combined indicate there is a significant increase in nitrate concentrations in the data set as a whole. Eight out of the 24 well networks, or about 33%, had significant changes of nitrate concentrations. Of the eight well networks with significant decadal-scale changes of nitrate, all except one, the Willamette Valley of Oregon, had increasing nitrate concentrations. Median nitrate concentrations of three of those eight well networks increased above the USEPA maximum contaminant level of 10 mg L-1. Nitrate in water from wells with reduced conditions had significantly smaller decadal-scale changes in nitrate concentrations than oxidized and mixed waters. A subset of wells had data on ground water recharge date; nitrate concentrations increased in response to the increase of N fertilizer use since about 1950. Determining ground water recharge dates is an important component of a ground water trends investigation because recharge dates provide a link between changes in ground water quality and changes in land-use practices. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  19. Demonstration of the Gore Module for Passive Ground Water Sampling

    Science.gov (United States)

    2014-06-01

    and industrial facilities and as a national wildlife refuge . The Air Force retained 229 acres for use by the New Hampshire Air National Guard...G. Sitarenios, 2003. Measuring Emotional Intelligence With the MSCEIT V2.0. American Psychological Association, Inc. http://unh.edu...D.D. Rucker, D. DeSteno, D.T. Wegener, and J. Braverman, 2004. Discrete Emotions and Persuasion: The Role of Emotion -Induced Expectancies. American

  20. GROUND-WATER SAMPLING BIAS OBSERVED IN SHALLOW, CONVENTIONAL WELLS

    Science.gov (United States)

    A previous field demonstration project on nitrate-based bioremediation of a fuel-contaminated aquifer used short-screened clustered well points in addition to shallow (10 foot), conventional monitoring wells to monitor the progress of remediation during surface application of rec...

  1. Estimating pumping time and ground-water withdrawals using energy-consumption data. Water-Resources Investigation

    Energy Technology Data Exchange (ETDEWEB)

    Hurr, R.T.; Litke, D.W.

    1989-01-01

    Evaluation of the hydrology of an aquifer requires knowledge about the volume of ground water in storage and also about the volume of ground-water withdrawals. Totalizer flow meters may be installed at pumping plants to measure withdrawals; however, it generally is impractical to equip all wells in an area with meters. A viable alternative is the use of rate-time methods to estimate withdrawals. The relation between power demand and pumping rate at a pumping plant can be described through the use of the power-consumption coefficient. Where equipment and hydrologic conditions are stable, this coefficient can be applied to total energy consumption at a site to estimate total ground-water withdrawals. Random sampling of power-consumption coefficients can be used to estimate area-wide ground-water withdrawals.

  2. STUDY OF INFLUENCE OF EFFLUENT ON GROUND WATER USING REMOTE SENSING, GIS AND MODELING TECHNIQUES

    Directory of Open Access Journals (Sweden)

    S. Pathak

    2012-07-01

    Full Text Available The area lies in arid zone of western Rajasthan having very scanty rains and very low ground water reserves. Some of the other problems that are faced by the area are disposal of industrial effluent posing threat to its sustainability of water resource. Textiles, dyeing and printing industries, various mechanical process and chemical/synthetic dyes are used and considerable wastewater discharged from these textile units contains about high amount of the dyes into the adjoining drainages. This has caused degradation of water quality in this water scarce semi-arid region of the country. Pali city is located South-West, 70 Kms from Jodhpur in western Rajasthan (India. There are four Common Effluent Treatment Plant (CETP treating wastewater to meet the pollutant level permissible to river discharge, a huge amount of effluent water of these factories directly meets the into the river Bandi – a tributary of river Luni. In order to monitor the impact of industrial effluents on the environment, identifying the extent of the degradation and evolving possible means of minimizing the impacts studies on quality of effluents, polluted river water and water of adjoining wells, the contamination migration of the pollutants from the river to ground water were studied. Remote sensing analysis has been carried out using Resourcesat −1 multispectral satellite data along with DEM derived from IRS P5 stereo pair. GIS database generated of various thematic layers viz. base layer – inventorying all waterbodies in the vicinity, transport network and village layer, drainage, geomorphology, structure, land use. Analysis of spatial distribution of the features and change detection in land use/cover carried out. GIS maps have been used to help factor in spatial location of source and hydro-geomorphological settings. DEM & elevation contour helped in delineation of watershed and identifying flow modelling boundaries. Litholog data analysis carried out for aquifer

  3. Study of Influence of Effluent on Ground Water Using Remote Sensing, GIS and Modeling Techniques

    Science.gov (United States)

    Pathak, S.; Bhadra, B. K.; Sharma, J. R.

    2012-07-01

    The area lies in arid zone of western Rajasthan having very scanty rains and very low ground water reserves. Some of the other problems that are faced by the area are disposal of industrial effluent posing threat to its sustainability of water resource. Textiles, dyeing and printing industries, various mechanical process and chemical/synthetic dyes are used and considerable wastewater discharged from these textile units contains about high amount of the dyes into the adjoining drainages. This has caused degradation of water quality in this water scarce semi-arid region of the country. Pali city is located South-West, 70 Kms from Jodhpur in western Rajasthan (India). There are four Common Effluent Treatment Plant (CETP) treating wastewater to meet the pollutant level permissible to river discharge, a huge amount of effluent water of these factories directly meets the into the river Bandi - a tributary of river Luni. In order to monitor the impact of industrial effluents on the environment, identifying the extent of the degradation and evolving possible means of minimizing the impacts studies on quality of effluents, polluted river water and water of adjoining wells, the contamination migration of the pollutants from the river to ground water were studied. Remote sensing analysis has been carried out using Resourcesat -1 multispectral satellite data along with DEM derived from IRS P5 stereo pair. GIS database generated of various thematic layers viz. base layer - inventorying all waterbodies in the vicinity, transport network and village layer, drainage, geomorphology, structure, land use. Analysis of spatial distribution of the features and change detection in land use/cover carried out. GIS maps have been used to help factor in spatial location of source and hydro-geomorphological settings. DEM & elevation contour helped in delineation of watershed and identifying flow modelling boundaries. Litholog data analysis carried out for aquifer boundaries using specialized

  4. EFFECT OF GROUND-WATER REMEDIATION ACTIVITIES ON INDIGENOUS MICROFLORA

    Science.gov (United States)

    The United States Environmental Protection Agency (EPA), working with the Interagency DNAPL Consortium, completed an independent evaluation of microbial responses to ground-water remediation technology demonstrations at Launch Pad 34 at Cape Canaveral Air Station in Brevard Count...

  5. Arsenic in Ground Water of the United States - Direct Download

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This image shows national-scale patterns of naturally occurring arsenic in potable ground-water resources of the continental United States. The image was generated...

  6. Study Design and Percent Recoveries of Anthropogenic Organic Compounds With and Without the Addition of Ascorbic Acid to Preserve Water Samples Containing Free Chlorine, 2004-06

    Science.gov (United States)

    Valder, Joshua F.; Delzer, Gregory C.; Price, Curtis V.; Sandstrom, Mark W.

    2008-01-01

    The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS) began implementing Source Water-Quality Assessments (SWQAs) in 2002 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems in the United States. As used for SWQA studies, source water is the raw (ambient) water collected at the supply well prior to water treatment (for ground water) or the raw (ambient) water collected from the river near the intake (for surface water). Finished water is the water that is treated, which typically involves, in part, the addition of chlorine or other disinfection chemicals to remove pathogens, and is ready to be delivered to consumers. Finished water is collected before the water enters the distribution system. This report describes the study design and percent recoveries of anthropogenic organic compounds (AOCs) with and without the addition of ascorbic acid to preserve water samples containing free chlorine. The percent recoveries were determined by using analytical results from a laboratory study conducted in 2004 by the USGS's National Water Quality Laboratory (NWQL) and from data collected during 2004-06 for a field study currently (2008) being conducted by the USGS's NAWQA Program. The laboratory study was designed to determine if preserving samples with ascorbic acid (quenching samples) adversely affects analytical performance under controlled conditions. During the laboratory study, eight samples of reagent water were spiked for each of five analytical schedules evaluated. Percent recoveries from these samples were then compared in two ways: (1) four quenched reagent spiked samples analyzed on day 0 were compared with four quenched reagent spiked samples analyzed on day 7 or 14, and (2) the combined eight quenched reagent spiked samples analyzed on day 0, 7, or 14 were compared with eight laboratory reagent spikes (LRSs). Percent

  7. Environmental occurrence and shallow ground water detection of the antibiotic monensin from dairy farms

    Science.gov (United States)

    Watanabe, N.; Harter, T.H.; Bergamaschi, B.A.

    2008-01-01

    Pharmaceuticals used in animal feeding operations have been detected in various environmental settings. There is a growing concern about the impact on terrestrial and aquatic organisms and the development of antibiotic-resistant strains of microorganisms. Pharmaceutical use in milking cows is relatively limited compared with other livestock operations, except for the ionophore monensin, which is given to lactating cows as a feed. By weight, monensin can be the most significant antibiotic used in a dairy farm. This study investigates the potential of monensin to move from dairy operations into the surrounding ground water. Using two dairy farms in California as study sites, we twice collected samples along the environmental pathway-from flush lanes, lagoon waters, and shallow ground water beneath the dairies and beneath its associated manured fields. Monensin concentrations were determined using solid-phase extraction and liquid chromatography-tandem mass spectrometry with positive electrospray ionization. Monensin was detected in all of the flush lane and lagoon water samples. Theoretical maximum concentration estimated from the actual dosing rate and the theoretical excretion rate assuming no attenuation was one order of magnitude greater than observed concentrations, suggesting significant attenuation in the manure collection and storage system. Monensin was also detected, at levels ranging from 0.04 to 0.39 microg L(-1), in some of the ground water samples underneath the production area of the dairy but not from the adjacent manured fields. Concentrations in ground water immediately downgradient of the lagoons were one to two orders of magnitude lower than the concentrations detected in lagoons, suggesting attenuation in the subsurface. The data suggest the possibility of monensin transport into shallow (2-5 m) alluvial ground water from dairy management units, including manure storage lagoons and freestalls occupied by heifers, lactating cows, and dry cows.

  8. Environmental occurrence and shallow ground water detection of the antibiotic monensin from dairy farms

    Science.gov (United States)

    Watanabe, N.; Harter, T.H.; Bergamaschi, B.A.

    2008-01-01

    Pharmaceuticals used in animal feeding operations have been detected in various environmental settings. There is a growing concern about the impact on terrestrial and aquatic organisms and the development of antibiotic-resistant strains of microorganisms. Pharmaceutical use in milking cows is relatively limited compared with other livestock operations, except for the ionophore monensin, which is given to lactating cows as a feed. By weight, monensin can be the most significant antibiotic used in a dairy farm. This study investigates the potential of monensin to move from dairy operations into the surrounding ground water. Using two dairy farms in California as study sites, we twice collected samples along the environmental pathway - from flush lanes, lagoon waters, and shallow ground water beneath the dairies and beneath its associated manured fields. Monensin concentrations were determined using solid-phase extraction and liquid chromatography-tandem mass spectrometry with positive electrospray ionization. Monensin was detected in all of the flush lane and lagoon water samples. Theoretical maximum concentration estimated from the actual dosing rate and the theoretical excretion rate assuming no attenuation was one order of magnitude greater than observed concentrations, suggesting significant attenuation in the manure collection and storage system. Monensin was also detected, at levels ranging from 0.04 to 0.39 ??g L-1, in some of the ground water samples underneath the production area of the dairy but not from the adjacent manured fields. Concentrations in ground water immediately downgradient of the lagoons were one to two orders of magnitude lower than the concentrations detected in lagoons, suggesting attenuation in the subsurface. The data suggest the possibility of monensin transport into shallow (2-5 m) alluvial ground water from dairy management units, including manure storage lagoons and freestalls occupied by heifers, lactating cows, and dry cows

  9. A national look at nitrate contamination of ground water

    Science.gov (United States)

    Nolan, Bernard T.; Ruddy, Barbara C.; Hitt, Kerie J.; Helsel, Dennis R.

    1998-01-01

    Ground water provides drinking water for more than one-half of the Nation's population (Solley and others, 1993), and is the sole source of drinking water for many rural communities and some large cities. In 1990, ground water accounted for 39 percent of water withdrawn for public supply for cities and towns and 96 percent of water withdrawn by self-supplied systems for domestic use.

  10. Petroleum contaminated ground-water: Remediation using activated carbon.

    OpenAIRE

    2006-01-01

    Ground-water contamination resulting from the leakage of crude oil and refined petroleum products during extraction and processing operations is a serious and a growing environmental problem in Nigeria. Consequently, a study of the use of activated carbon (AC) in the clean up was undertaken with the aim of reducing the water contamination to a more acceptable level. In the experiments described, crude-oil contamination of ground water was simulated under laboratory conditions using ground-wat...

  11. An imminent human resource crisis in ground water hydrology?

    Science.gov (United States)

    Stephens, Daniel B

    2009-01-01

    Anecdotal evidence, mostly from the United States, suggests that it has become increasingly difficult to find well-trained, entry-level ground water hydrologists to fill open positions in consulting firms and regulatory agencies. The future prospects for filling positions that require training in ground water hydrology are assessed by considering three factors: the market, the numbers of qualified students entering colleges and universities, and the aging of the existing workforce. The environmental and water resources consulting industry has seen continuous albeit variable growth, and demand for environmental scientists and hydrologists is expected to increase significantly. Conversely, students' interest and their enrollment in hydrology and water resources programs have waned in recent years, and the interests of students within these departments have shifted away from ground water hydrology in some schools. This decrease in the numbers of U.S. students graduating in hydrology or emphasizing ground water hydrology is coinciding with the aging of and pending retirement of ground water scientists and engineers in the baby boomer generation. We need to both trigger the imagination of students at the elementary school level so that they later want to apply science and math and communicate the career opportunities in ground water hydrology to those high school and college graduates who have acquired the appropriate technical background. Because the success of a consulting firm, research organization, or regulatory agency is derived from the skills and judgment of the employees, human resources will be an increasingly more critical strategic issue for many years.

  12. Radon concentrations of ground waters in Aichi Prefecture

    Energy Technology Data Exchange (ETDEWEB)

    Ohnuma, Shoko; Kawamura, Norihisa [Aichi Prefectural Inst. of Public Health, Nagoya (Japan)

    1997-02-01

    Aichi Prefectural Institute of Public Health has been collecting the data concerning the spacial distribution of Rn concentration of groundwater in Aichi Prefecture and its time course changes. In this report, the data was described chiefly from 1991 and the availability of newly developed polyethylene vessel was discussed. Determination of Rn concentration was performed at a total of 104 sites within the range from the horizon to the depth of 1800 m. The measurement has been repeatedly conducted for ca. 20 years. The maximum level of Rn was 896 Bq/l and the minimum was 0.3 Bq/l for the groundwater samples collected from different springs. Correlation of Rn concentration with other chemical and physical factors for ground water was investigated and a significant correlation was found only between Rn concentration and pH ({gamma}=0.304, p<0.01). No time course changes in Rn concentration was observed except for the water sample from the site affected by some newly dug wells. In addition, the newly developed extraction vessel was shown to be available for the determination and its operability in the field was superior to the conventional glass ware. (M.N.)

  13. Ground-water quality assessment of the central Oklahoma Aquifer, Oklahoma; project description

    Science.gov (United States)

    Christenson, S.C.; Parkhurst, D.L.

    1987-01-01

    , selenium, and gross-alpha activity that exceed drinking-water standards. Suspected problems include possible contamination of the aquifer by oil-field brines and drilling fluids, pesticides, industrial chemicals, septic-tank effluent, fertilizers, and leakage from sewage systems and underground tanks used for storage of hydrocarbons. There are four major components of the Central Oklahoma aquifer project. The first component is the collection and analysis of existing information, including chemical, hydrologic, and land-use data. The second component is the geohydrologic and geochemical investigations of the aquifer flow system. The third component is the sampling for a wide variety of inorganic, organic, and radioactive constituents as part a regional survey that will produce a consistent set of data among all ground-water pilot projects. These data can be used to: (1) Define regional ground-water quality within the Central Oklahoma aquifer, and (2) compare water quality in the Central Oklahoma aquifer to the water quality in the other ground-water study units of the NAWQA program. The fourth component is topical studies that will address, in more detail, some of the major water-quality issues pertaining to the aquifer.

  14. Potential structural barriers to ground-water flow, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital dataset defines the surface traces of regional geologic structures designated as potential ground-water flow barriers in an approximately 45,000...

  15. Potential structural barriers to ground-water flow, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital dataset defines the surface traces of regional geologic structures designated as potential ground-water flow barriers in an approximately 45,000...

  16. Chemical Analyses of Ground Water in the Carson Desert near Stillwater, Churchill County, Nevada, 2005

    Science.gov (United States)

    Fosbury, DeEtta; Walker, Mark; Stillings, Lisa L.

    2008-01-01

    This report presents the chemical analyses of ground-water samples collected in 2005 from domestic wells located in the Stillwater area of the Carson Desert (fig. 1). These data were evaluated for evidence of mixing with nearby geothermal waters (Fosbury, 2007). That study used several methods to identify mixing zones of ground and geothermal waters using trace elements, chemical equilibria, water temperature, geothermometer estimates, and statistical techniques. In some regions, geothermal sources influence the chemical quality of ground water used for drinking water supplies. Typical geothermal contaminants include arsenic, mercury, antimony, selenium, thallium, boron, lithium, and fluoride (Webster and Nordstrom, 2003). The Environmental Protection Agency has established primary drinking water standards for these, with the exception of boron and lithium. Concentrations of some trace metals in geothermal water may exceed drinking water standards by several orders of magnitude. Geothermal influences on water quality are likely to be localized, depending on directions of ground water flow, the relative volumes of geothermal sources and ground water originating from other sources, and depth below the surface from which water is withdrawn. It is important to understand the areal extent of shallow mixing of geothermal water because it may have adverse chemical and aesthetic effects on domestic drinking water. It would be useful to understand the areal extent of these effects.

  17. Hanford Site ground-water monitoring for January through June 1988

    Energy Technology Data Exchange (ETDEWEB)

    Evans, J.C.; Bryce, R.W.; Sherwood, D.R.

    1989-05-01

    The Pacific Northwest Laboratory monitors ground-water quality at the Hanford Site for the US Department of Energy to assess the impact of Site operations on the environment. Work undertaken between January and June 1988 included monitoring ground-water elevations across the Site, and monitoring hazardous chemicals and radionuclides in ground water. Water levels continued to rise in areas receiving increased recharge (e.g., beneath B Pond) and decline in areas where the release of water to disposal facilities has been terminated (e.g., U Pond). The major areas of ground-water contamination defined by monitoring activities are (1) carbon tetrachloride in the 200-West Area; (2) cyanide in and north of the 200-East and 200-West Areas; (3) hexavalent chromium contamination in the 100-B, 100-D, 100-F, 100-H, 100-K, and 200-West Areas; (4) chlorinated hydrocarbons in the vicinity of the Solid Waste Landfill and 300 Area; (5) uranium in the 100-F, 100-H, 200-West, and 300 Areas; and (6) tritium and nitrate across the Site. In addition, several new analytical initiatives were undertaken during this period. These include cyanide speciation in the BY Cribs plume, inductively coupled argon plasma/mass spectrometry (ICP/MS) measurements on a broad selection of samples from the 100, 200, 300, and 600 Areas, and high sensitivity gas chromatography measurements performed at the Solid Waste Landfill-Nonradioactive Dangerous Waste Landfill. 23 figs., 25 tabs.

  18. Hanford ground-water data base management guide and user's manual. [CIRMIS

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, P.J.; Argo, R.S.; Bradymire, S.L.; Newbill, C.A.

    1985-05-01

    This management guide and user's manual is a working document for the computerized Hanford Ground-water Data Base maintained by the Geosciences Research and Engineering Department at Pacific Northwest Laboratory for the Hanford Ground-Water Surveillance Program. The program is managed by the Occupational and Environmental Protection Department for the US Department of Energy. The data base is maintained to provide rapid access to data that are rountinely collected from ground-water monitoring wells at the Hanford site. The data include water levels, sample analyses, geologic descriptions and well construction information of over 3000 existing or destroyed wells. These data are used to monitor water quality and for the evaluation of ground-water flow and pollutant transport problems. The management guide gives instructions for maintenance of the data base on the Digital Equipment Corporation PDP 11/70 Computer using the CIRMIS (Comprehensive Information Retrieval and Model Input Sequence) data base management software developed at Pacific Northwest Laboratory. Maintenance activities include inserting, modifying and deleting data, making back-up copies of the data base, and generating tables for annual monitoring reports. The user's guide includes instructions for running programs to retrieve the data in the form of listings of graphical plots. 3 refs.

  19. Remedial Action Plan and Site Design for Stabilization of the Inactive Uranium Mill Tailings Site, Maybell, Colorado. Appendixes to Attachment 3: Appendix A, Hydrological services calculations: Appendix B, Ground water quality by location, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    This report contains chemical analysis data for ground water for the following: elements; cyanides; chlorides; dissolved organic carbon; fluorides; silica; sulfates; sulfides; dissolved solids; nitrates; and nitrites.

  20. Environmental Assessment of Ground Water Compliance at the Naturita, Colorado, UMTRA Project Site

    Energy Technology Data Exchange (ETDEWEB)

    None

    2003-04-23

    This Environmental Assessment addresses the environmental effects of a proposed action and the no action alternative to comply with U.S. Environmental Protection Agency (EPA) ground water standards at the Naturita, Colorado, Uranium Mill Tailings Remedial Action Project site. In 1998, the U.S. Department of Energy (DOE) completed surface cleanup at the site and encapsulated the tailings in a disposal cell 15 miles northwest near the former town of Uravan, Colorado. Ground water contaminants of potential concern at the Naturita site are uranium and vanadium. Uranium concentrations exceed the maximum concentration limit (MCL) of 0.044 milligram per liter (mg/L). Vanadium has no MCL; however, vanadium concentrations exceed the EPA Region III residential risk-based concentration of 0.33 mg/L (EPA 2002). The proposed compliance strategy for uranium and vanadium at the Naturita site is no further remediation in conjunction with the application of alternate concentration limits. Institutional controls with ground water and surface water monitoring will be implemented for these constituents as part of the compliance strategy. This compliance strategy will be protective of human health and the environment. The proposed monitoring program will begin upon regulatory concurrence with the Ground Water Compliance Action Plan (DOE 2002a). Monitoring will consist of verifying that institutional controls remain in place, collecting ground water samples to verify that concentrations of uranium and vanadium are decreasing, and collecting surface water samples to verify that contaminant concentrations do not exceed a regulatory limit or risk-based concentration. If these criteria are not met, DOE would reevaluate the proposed action and determine the need for further National Environmental Policy Act documentation. No comments were received from the public during the public comment period. Two public meetings were held during this period. Minutes of these meetings are included as

  1. Hydrology, Water Quality, and Surface- and Ground-Water Interactions in the Upper Hillsborough River Watershed, West-Central Florida

    Science.gov (United States)

    Trommer, J.T.; Sacks, L.A.; Kuniansky, E.L.

    2007-01-01

    A study of the Hillsborough River watershed was conducted between October 1999 through September 2003 to characterize the hydrology, water quality, and interaction between the surface and ground water in the highly karstic uppermost part of the watershed. Information such as locations of ground-water recharge and discharge, depth of the flow system interacting with the stream, and water quality in the watershed can aid in prudent water-management decisions. The upper Hillsborough River watershed covers a 220-square-mile area upstream from Hillsborough River State Park where the watershed is relatively undeveloped. The watershed contains a second order magnitude spring, many karst features, poorly drained swamps, marshes, upland flatwoods, and ridge areas. The upper Hillsborough River watershed is subdivided into two major subbasins, namely, the upper Hillsborough River subbasin, and the Blackwater Creek subbasin. The Blackwater Creek subbasin includes the Itchepackesassa Creek subbasin, which in turn includes the East Canal subbasin. The upper Hillsborough River watershed is underlain by thick sequences of carbonate rock that are covered by thin surficial deposits of unconsolidated sand and sandy clay. The clay layer is breached in many places because of the karst nature of the underlying limestone, and the highly variable degree of confinement between the Upper Floridan and surficial aquifers throughout the watershed. Potentiometric-surface maps indicate good hydraulic connection between the Upper Floridan aquifer and the Hillsborough River, and a poorer connection with Blackwater and Itchepackesassa Creeks. Similar water level elevations and fluctuations in the Upper Floridan and surficial aquifers at paired wells also indicate good hydraulic connection. Calcium was the dominant ion in ground water from all wells sampled in the watershed. Nitrate concentrations were near or below the detection limit in all except two wells that may have been affected by

  2. Prevalence of Campylobacter species in ground water in Sokoto, Sokoto state, Nigeria

    OpenAIRE

    Agatha N. Ugboma; Muhammed D. Salihu; Abdullahi A. Magaji; Abubakar, Mikail B.

    2013-01-01

    Aim: The present study was conducted to determine the presence and prevalence of Campylobacter species in ground water in Sokoto, Sokoto State. Materials and Methods: The prevalence of Campylobacter species was determined by collecting a total of 74 water samples from wells in Sokoto over a period of four months from May to August 2011 and analyzed using cultural isolation techniques and biochemical characterization. Results: Totally 39 (52.70%) water samples were Campylobacter positive. The ...

  3. GWM-a ground-water management process for the U.S. Geological Survey modular ground-water model (MODFLOW-2000)

    Science.gov (United States)

    Ahlfeld, David P.; Barlow, Paul M.; Mulligan, Anne E.

    2005-01-01

    components of the linear management formulation to form a complete linear formulation; the formulation is then solved by use of the simplex algorithm, which is incorporated into the RMS Package. Nonlinear formulations arise for simulated conditions that include water?table (unconfined) aquifers or head?dependent boundary conditions (such as streams, drains, or evapotranspiration from the water table). Nonlinear formulations are solved by sequential linear programming; that is, repeated linearization of the nonlinear features of the management problem. In this approach, response coefficients are recalculated for each iteration of the solution process. Mixed?binary linear (or mildly nonlinear) formulations are solved by use of the branch and bound algorithm, which is also incorporated into the RMS Package. Three sample problems are provided to demonstrate the use of GWM for typical ground?water flow management problems. These sample problems provide examples of how GWM input files are constructed to specify the decision variables, objective function, constraints, and solution process for a GWM run. The GWM Process runs with the MODFLOW?2000 Global and Ground?Water Flow Processes, but in its current form GWM cannot be used with the Observation, Sensitivity, Parameter?Estimation, or Ground?Water Transport Processes. The GWM Process is written with a modular structure so that new objective functions, constraint types, and solution algorithms can be added.

  4. Ground-water quality in the West Salt River Valley, Arizona, 1996-98: relations to hydrogeology, water use, and land use

    Science.gov (United States)

    Edmonds, Robert J.; Gellenbeck, Dorinda J.

    2002-01-01

    February 1998. Analyses of all samples collected from the monitoring wells indicated low concentrations of pesticides and volatile organic compounds. The most frequently detected pesticides were deethylatrazine and atrazine. Trichloromethane (chloroform) and tetrachloroethene (PCE) were the most frequently detected volatile organic compounds in the monitoring wells. Two compounds [dieldrin and 1,1-dichloro-2,2-bis(p-dichlorodiphenyl)ethylene (DDE)], decomposition products of two banned pesticides, aldrin and dichlorodiphenylethylene (DDT), were detected at low concentrations in samples analyzed for the agricultural land-use study. In the West Salt River Valley, a high concentration of the heavier oxygen isotope?oxygen-18?in ground water generally indicates effects of evaporation on recharge water from irrigation. Wells in undeveloped areas and wells that have openings beneath a confining bed generally yield ground water that is free of the effects of irrigation seepage. Samples from these wells did not contain detectable concentrations of pesticides. The median concentrations of nitrate (as nitrogen) and dissolved solids in samples from wells in undeveloped areas were 1.7 milligrams per liter and 257 milligrams per liter, respectively. The median concentrations of nitrate (as nitrogen) and dissolved solids in samples from wells that yield water from below confining beds were 2.0 and 747 milligrams per liter, respectively.

  5. Geochemical and isotopic composition of ground water with emphasis on sources of sulfate in the upper Floridan Aquifer in parts of Marion, Sumter, and Citrus counties, Florida

    Science.gov (United States)

    Sacks, Laura A.

    1996-01-01

    In inland areas of northwest central Florida, sulfate concentrations in the Upper Floridan aquifer are extremely variable and sometimes exceed drinking water standards (250 milligrams per liter). This is unusual because the aquifer is unconfined and near the surface, allowing for active recharge. The sources of sulfate and geochemical processes controlling ground-water composition were evaluated in this area. Water was sampled from thirty-three wells in parts of Marion, Sumter, and Citrus Counties, within the Southwest Florida Water Management District; these included at least a shallow and a deep well at fifteen separate locations. Ground water was analyzed for major ions, selected trace constituents, dissolved organic carbon, and stable isotopes (sulfur-34 of sulfate and sulfide, carbon-13 of inorganic carbon, deuterium, and oxygen-18). Sulfate concentrations ranged from less than 0.2 to 1,400 milligrams per liter, with higher sulfate concentrations usually in water from deeper wells. The samples can be categorized into a low sulfate group (less than 30 milligrams per liter) and a high sulfate group (greater than 30 milligrams per liter). For the high sulfate water, concentrations of calcium and magnesium increased concurrently with sulfate. Chemical and isotopic data and mass-balance modeling indicate that the composition of high sulfate waters is controlled by dedolomitization reactions (dolomite dissolution and calcite precipitation, driven by dissolution of gypsum). Gypsum occurs deeper in the aquifer than open intervals of sampled wells. Upward flow has been documented in deeper parts of the aquifer in the study area, which may be driven by localized discharge areas or rapid flow in shallow parts of the aquifer. Mixing between shallow ground water and sulfate-rich water that dissolved gypsum at the base of the aquifer is probably responsible for the range of concentrations observed in the study area. Other solutes that increased with sulfate apparently

  6. Ground-water resources of the Yucca Valley-Joshua Tree area, San Bernardino County, California

    Science.gov (United States)

    Lewis, R.E.

    1972-01-01

    The southeastern part of the Mojave Water Agency area included in this report comprises about 600 square miles. Recharge into the area is almost exclusively from precipitation in the San Bernardino and Little San Bernardino Mountains. About 500 acre-feet per year of recharge enters the western part of the area as underflow through Pipes Wash. Little direct recharge occurs as a result of precipitation directly on the unconsolidated deposits. Presently about 11,000 persons reside in the area and current gross pumpage is about 1,600 acre-feet annually. By the year 2000 the population is estimated to be 62,000 and annual gross pumpage is expected to be nearly 11,000 acre-feet. Although over 1,200,000 acre-feet of ground water are presently in storage, most of the population is centered in the southern part of the area around the towns of Yucca Valley and Joshua Tree. About 70 percent of the population resides in the vicinity of Yucca Valley and is supplied by ground water pumped from the Warren Valley basin. Of the 96,000 acre-feet of ground water in storage in that basin in 1969, about 80,000 acre-feet will be necessary to sustain projected growth there until 2000. Assuming negligible recharge and only about 50 percent recovery of the ground water in storage, if imported water from northern California is not available before about 1990, additional local supplies will have to be developed, possibly in the adjacent Pipes subbasin to the north. Ground water in the southern part of the study area generally contains less than 250 mg/l (milligrams per liter) dissolved solids and 1.0 mg/l fluoride. A general degradation of ground-water quality occurs northward toward the dry lakes where the concentrations of dissolved solids and fluoride approach 2,000 and 5.0 mg/l, respectively. In Reche subbasin some isolated occurrences of fluoride exceeding 1.5 mg/l were noted. The chemical character of ground water in Johnson Valley and Morongo Valley basins differs from well to well

  7. Microanalysis study of archaeological mural samples containing Maya blue pigment

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez del Rio, M. [ESRF, BP220, F-38043 Grenoble (France)]. E-mail: srio@esrf.fr; Martinetto, P. [Laboratoire de Cristallographie, CNRS, BP166 F-30842 Grenoble (France); Somogyi, A. [ESRF, BP220, F-38043 Grenoble (France); Reyes-Valerio, C. [INAH, Mexico DF (Mexico); Dooryhee, E. [Laboratoire de Cristallographie, CNRS, BP166 F-30842 Grenoble (France); Peltier, N. [Laboratoire de Cristallographie, CNRS, BP166 F-30842 Grenoble (France); Alianelli, L. [INFM-OGG c/o ESRF, BP220, F-38043 Grenoble Cedex (France); Moignard, B. [C2RMF, 6 Rue des Pyramides, F-75041 Paris Cedex 01 (France); Pichon, L. [C2RMF, 6 Rue des Pyramides, F-75041 Paris Cedex 01 (France); Calligaro, T. [C2RMF, 6 Rue des Pyramides, F-75041 Paris Cedex 01 (France); Dran, J.-C. [C2RMF, 6 Rue des Pyramides, F-75041 Paris Cedex 01 (France)

    2004-10-08

    Elemental analysis by X-ray fluorescence and particle induced X-ray emission is applied to the study of several Mesoamerican mural samples containing blue pigments. The most characteristic blue pigment is Maya blue, a very stable organo-clay complex original from Maya culture and widely used in murals, pottery and sculptures in a vast region of Mesoamerica during the pre-hispanic time (from VIII century) and during the colonization until 1580. The mural samples come from six different archaeological sites (four pre-hispanic and two from XVI century colonial convents). The correlation between the presence of some elements and the pigment colour is discussed. From the comparative study of the elemental concentration, some conclusions are drawn on the nature of the pigments and the technology used.

  8. Inorganic ground-water chemistry at an experimental New Albany Shale (Devonian-Mississippian) in situ gasification site

    Science.gov (United States)

    Branam, T.D.; Comer, J.B.; Shaffer, N.R.; Ennis, M.V.; Carpenter, S.H.

    1991-01-01

    Experimental in situ gasification of New Albany Shale (Devonian-Mississippian) has been conducted in Clark County. Analyses of ground water sampled from a production well and nine nearby monitoring wells 3 months after a brief in situ gasification period revealed changes in water chemistry associated with the gasification procedure. Dissolved iron, calcium and sulphate in ground water from the production well and wells as much as 2 m away were significantly higher than in ground water from wells over 9 m away. Dissolved components in the more distant wells are in the range of those in regional ground water. Thermal decomposition of pyrite during the gasification process generated the elevated levels of iron and sulphate in solution. High concentrations of calcium indicate buffering by dissolution of carbonate minerals. While iron quickly precipitates, calcium and sulphate remain in the ground water. Trends in the concentration of sulphate show that altered ground water migrated mostly in a south-westerly direction from the production well along natural joints in the New Albany Shale. ?? 1991.

  9. Shallow ground-water quality in selected agricultural areas of south-central Georgia, 1994

    Science.gov (United States)

    Crandall, C.A.

    1996-01-01

    The Georgia-Florida Coastal Plain National Water-Quality Assessment Program began an agricultural land-use study in March 1994. The study area is located in the upper Suwannee River basin in Tift, Turner, Worth, Irwin, Wilcox, and Crisp Counties, Ga. Twenty-three shallow monitoring wells were installed in a 1,335-square- mile area characterized by intensive row-crop agriculture (peanuts, corn, cotton, and soybeans). The study focused on recently recharged shallow ground water in surficial aquifers to assess the relation between land-use activities and ground- water quality. All wells were sampled in March and April (spring) 1994, and 14 of these wells were resampled in August (summer) 1994. Shallow ground water in the study area is characterized by oxic and acidic conditions, low bicarbonate, and low dissolved-solids concentrations. The median pH of shallow ground water was 4.7 and the median bicarbonate concentration was 1.7 mg/L (milligrams per liter). Dissolved oxygen concentrations ranged from 3.0 to 8.0 mg/L. The median dissolved-solids concentration in samples collected in the spring was 86 mg/L. Major inorganic ion composition was generally mixed with no dominant cation; nitrate was the dominant anion (greater than 60 percent of the anion composition) in 14 of 23 samples. Only concentrations of bicarbonate, dissolved organic carbon, and nitrate had significant differences in concentrations between samples collected in the spring and the background samples. However, median concentrations of some of the major ingredients in fertilizer (including magnesium, chloride, nitrate, iron, and manganese) were higher in water samples from agricultural wells than in background samples. The median concentration of dissolved solids in ground-water samples collected in the spring (86 mg/L) was more than double the median concentration (41 mg/L) of the background samples. The median nitrate as nitrogen concentration of 6.7 mg/L in the spring samples reflects the effects of

  10. Hanford Site ground-water monitoring for 1993

    Energy Technology Data Exchange (ETDEWEB)

    Dresel, P.E.; Luttrell, S.P.; Evans, J.C. [and others

    1994-09-01

    This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1993 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1993 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1992 and June 1993. The greatest declines occurred in the 200-West Area. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal. Water levels remained nearly constant in the vicinity of B Pond, as a result of continued disposal to the pond. Water levels measured from wells in the unconfined aquifer north and east of the Columbia River indicate that the primary source of recharge is irrigation practices.

  11. Standard Practice for Field Sampling of Aerospace Fluids in Containers

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2009-01-01

    1.1 This practice covers field sampling of fluids from hermetically sealed containers and other fluid containers of 208-L volume maximum. It may be utilized at manufacturing, storage, or use levels for obtaining representative fluid samples for chemical, physical, or particulate matter determinations. 1.2 Use of this practice depends upon variables such as fluid toxicity, restrictive fluid odors, fluid flammability, and so forth. It is suitable for most hydraulic fluids; however, care should be exercised in determining compatibility before use. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For hazard statement, see 6.5.1.

  12. Chester County ground-water atlas, Chester County, Pennsylvania

    Science.gov (United States)

    Ludlow, Russell A.; Loper, Connie A.

    2004-01-01

    gneiss rocks can indicate a potential for corrosive water. The only constituent measured in the field that has a USEPA Secondary Maximum Contaminant Level (SMCL) is pH. The SMCL for pH is 6.5-8.5; 64 percent of samples analyzed for pH were acidic (below pH 6.5). Only 1 percent of samples were basic (above pH 8.5). Of the common ions, the USEPA has SMCLs for chloride, sulfate, and total dissolved solids. The USEPA has a SMCL and a Primary Maximum Contaminant Level (PMCL) for fluoride. Chloride is more closely related to land use than geology. In Chester County, chloride exceeded the SMCL (250 mg/L) only in 5 percent of the services (commercial services, community services, and military) land-use areas. No samples analyzed for sulfate exceeded the SMCL (250 mg/L). Only 3 percent of samples analyzed for total dissolved solids exceeded the SMCL (500 milligrams per liter) (mg/L). No samples analyzed for fluoride equaled or exceeded the SMCL (2.0 mg/L) or PMCL (4.0 mg/L). Iron concentrations exceeded the USEPA SMCL in 11 percent of samples and were highest in schist (14 percent) and gneiss (13 percent). Manganese concentrations exceeded the SMCL in 19 percent of samples and were highest in quartzite and schist (both 28 percent). Lead and arsenic were present in low concentrations: the highest concentrations of lead occurred in water from quartzite (8 percent exceeded the USEPA Action Level), and arsenic was detected mostly in Triassic sedimentary rocks (9 percent exceeded the USEPA PMCL). The highest concentrations of copper occurred more frequently in quartzite rocks, and to a lesser extent were evenly distributed between ground water in gneiss, schist, and Triassic sedimentary rocks. Elevated concentrations of radon-222 and the combined radium-226/radium-228 radionuclides were common in water from quartzite and schist. Gross alpha and gross beta particle activities were elevated in water from quartzite and carbonate rocks. In contrast, elevated concentrations of uranium

  13. Ground-Water Quality Data in the Santa Clara River Valley Study Unit, 2007: Results from the California GAMA Program

    Science.gov (United States)

    Montrella, Joseph; Belitz, Kenneth

    2009-01-01

    Ground-water quality in the approximately 460-square-mile Santa Clara River Valley study unit (SCRV) was investigated from April to June 2007 as part of the statewide Priority Basin project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of the quality of raw ground water used for public water supplies within SCRV, and to facilitate a statistically consistent basis for comparing water quality throughout California. Fifty-seven ground-water samples were collected from 53 wells in Ventura and Los Angeles Counties. Forty-two wells were selected using a randomized grid-based method to provide statistical representation of the study area (grid wells). Eleven wells (understanding wells) were selected to further evaluate water chemistry in particular parts of the study area, and four depth-dependent ground-water samples were collected from one of the eleven understanding wells to help understand the relation between water chemistry and depth. The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, potential wastewater-indicator compounds, and pharmaceutical compounds), a constituent of special interest (perchlorate), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial constituents. Naturally occurring isotopes (tritium, carbon-13, carbon-14 [abundance], stable isotopes of hydrogen and oxygen in water, stable isotopes of nitrogen and oxygen in nitrate, chlorine-37, and bromine-81), and dissolved noble gases also were measured to help identify the source

  14. Quality of the ground water in basalt of the Columbia River group, Washington, Oregon, and Idaho

    Science.gov (United States)

    Newcomb, Reuben Clair

    1972-01-01

    The ground water within the 50,000-square-mile area of the layered basalt of the Columbia River Group is a generally uniform bicarbonate water having calcium and sodium in nearly equal amounts as the principal cations. water contains a relatively large amount of silica. The 525 chemical analyses indicate that the prevalent ground water is of two related kinds--a calcium and a sodium water. The sodium water is more common beneath the floors of the main synclinal valleys; the calcium water, elsewhere. In addition to the prevalent type, five special types form a small part of the ground water; four of these are natural and one is artificial. The four natural special types are: (1) calcium sodium chloride waters that rise from underlying sedimentary rocks west of the Cascade Range, (2) mineralized water at or near warm or hot springs, (3) water having unusual ion concentrations, especially of chloride, near sedimentary rocks intercalated at the edges of the basalt, and (4) more mineralized water near one locality of excess carbon dioxide. The one artificial kind of special ground water has resulted from unintentional artificial recharge incidental to irrigation in parts of central Washington. The solids dissolved in the ground water have been picked up on the surface, within the overburden, and from minerals and glasses within the basalt. Evidence for the removal of ions from solution is confined to calcium and magnesium, only small amounts of which are present in some of the sodium-rich water. Minor constituents, such as the heavy metals, alkali metals, and alkali earths, occur in the ground water in trace, or small, amounts. The natural radioactivity of the ground waters is very low. Except for a few of the saline calcium sodium chloride waters and a few occurrences of excessive nitrate, the ground water generally meets the common standards of water good for most ordinary uses, but some of it can be improved by treatment. The water is clear and colorless and has a

  15. Geochemistry and the understanding of ground-water systems

    Science.gov (United States)

    Glynn, Pierre D.; Plummer, L. Niel

    2005-03-01

    Geochemistry has contributed significantly to the understanding of ground-water systems over the last 50 years. Historic advances include development of the hydrochemical facies concept, application of equilibrium theory, investigation of redox processes, and radiocarbon dating. Other hydrochemical concepts, tools, and techniques have helped elucidate mechanisms of flow and transport in ground-water systems, and have helped unlock an archive of paleoenvironmental information. Hydrochemical and isotopic information can be used to interpret the origin and mode of ground-water recharge, refine estimates of time scales of recharge and ground-water flow, decipher reactive processes, provide paleohydrological information, and calibrate ground-water flow models. Progress needs to be made in obtaining representative samples. Improvements are needed in the interpretation of the information obtained, and in the construction and interpretation of numerical models utilizing hydrochemical data. The best approach will ensure an optimized iterative process between field data collection and analysis, interpretation, and the application of forward, inverse, and statistical modeling tools. Advances are anticipated from microbiological investigations, the characterization of natural organics, isotopic fingerprinting, applications of dissolved gas measurements, and the fields of reaction kinetics and coupled processes. A thermodynamic perspective is offered that could facilitate the comparison and understanding of the multiple physical, chemical, and biological processes affecting ground-water systems. La géochimie a contribué de façon importante à la compréhension des systèmes d'eaux souterraines pendant les 50 dernières années. Les avancées ont portées sur le développement du concept des faciès hydrochimiques, sur l'application de la théorie des équilibres, l'étude des processus d'oxydoréduction, et sur la datation au radiocarbone. D'autres concepts, outils et

  16. Shallow Alluvial Aquifer Ground Water System and Surface Water/Ground Water Interaction, Boulder Creek, Boulder, Colorado

    Science.gov (United States)

    Babcock, K. P.; Ge, S.; Crifasi, R. R.

    2006-12-01

    Water chemistry in Boulder Creek, Colorado, shows significant variation as the Creek flows through the City of Boulder [Barber et al., 2006]. This variation is partially due to ground water inputs, which are not quantitatively understood. The purpose of this study is (1) to understand ground water movement in a shallow alluvial aquifer system and (2) to assess surface water/ground water interaction. The study area, encompassing an area of 1 mi2, is located at the Sawhill and Walden Ponds area in Boulder. This area was reclaimed by the City of Boulder and Boulder County after gravel mining operations ceased in the 1970's. Consequently, ground water has filled in the numerous gravel pits allowing riparian vegetation regrowth and replanting. An integrated approach is used to examine the shallow ground water and surface water of the study area through field measurements, water table mapping, graphical data analysis, and numerical modeling. Collected field data suggest that lateral heterogeneity exists throughout the unconsolidated sediment. Alluvial hydraulic conductivities range from 1 to 24 ft/day and flow rates range from 0.01 to 2 ft/day. Preliminary data analysis suggests that ground water movement parallels surface topography and does not noticeably vary with season. Recharge via infiltrating precipitation is dependent on evapotranspiration (ET) demands and is influenced by preferential flow paths. During the growing season when ET demand exceeds precipitation rates, there is little recharge; however recharge occurs during cooler months when ET demand is insignificant. Preliminary data suggest that the Boulder Creek is gaining ground water as it traverses the study area. Stream flow influences the water table for distances up to 400 feet. The influence of stream flow is reflected in the zones relatively low total dissolved solids concentration. A modeling study is being conducted to synthesize aquifer test data, ground water levels, and stream flow data. The

  17. Ground water for public water supply at Windigo, Isle Royale National Park, Michigan

    Science.gov (United States)

    Grannemann, N.G.; Twenter, F.R.

    1982-01-01

    Three test holes drilled at Windigo in Isle Royale National Park in 1981 indicate that the ophitic basaltic lava flows underlying the area contain little water and cannot be considered a source for public water supply. The holes were 135, 175, and 71 feet deep. One hole yielded about 1 gallon of water perminute; the other two yielded less. Glacial deposits seem to offer the best opportunity for developing a ground-water supply of 5 to 10 gallons per minute.

  18. Geology and ground-water resources of Goshen County, Wyoming; Chemical quality of the ground water

    Science.gov (United States)

    Rapp, J.R.; Visher, F.N.; Littleton, R.T.; Durum, W.H.

    1957-01-01

    Goshen County, which has an area of 2,186 square miles, lies in southeastern Wyoming. The purpose of this study was to evaluate the ground-water resources of the county by determining the character, thickness, and extent of the waterbearing materials; the source, occurrence, movement, quantity, and quality of the ground water; and the possibility of developing additional ground water. The rocks exposed in the area are sedimentary and range in age from Precambrian to Recent. A map that shows the areas of outcrop and a generalized section that summarizes the age, thickness, physical character, and water supply of these formations are included in the report. Owing to the great depths at which they lie beneath most of the county, the formations older than the Lance formation of Late Cretaceous age are not discussed in detail. The Lance formation, of Late Cretaceous age, which consists mainly of beds of fine-grained sandstone and shale, has a maximum thickness of about 1,400 feet. It yields water, which usually is under artesian pressure, to a large number of domestic and stock wells in the south-central part of the county. Tertiary rocks in the area include the Chadron and Brule formations of Oligocene age, the Arikaree formation of Miocene age, and channel deposits of Pliocene age. The Chadron formation is made up of two distinct units: a lower unit of highly variegated fluviatile deposits that has been found only in the report area; and an upper unit that is typical of the formation as it occurs in adjacent areas. The lower unit, which ranges in thickness from a knife edge to about 95 feet, is not known to yield water to wells, but its coarse-grained channel deposits probably would yield small quantities of water to wells. The upper unit, which ranges in thickness from a knife edge to about 150 feet, yields sufficient quantities of water for domestic and stock uses from channel deposits of sandstone under artesian pressure. The Brule formation, which is mainly a

  19. Use of environmental tracers to evaluate ground-water age and water-quality trends in a buried-valley aquifer, Dayton area, southwestern, Ohio

    Science.gov (United States)

    Rowe, Gary L.; Shapiro, Stephanie Dunkle; Schlosser, Peter

    1999-01-01

    Chlorofluorocarbons (CFC method) and tritium and helium isotopes (3H-3He method) were used as environmental tracers to estimate ground-water age in conjunction with efforts to develop a regional ground-water flow model of the buried-valley aquifer in the Dayton area, southwestern Ohio. This report describes results of CFC and water-quality sampling, summarizes relevant aspects of previously published work, and describes the use of 3H-3He ages to characterize temporal trends in ground-water quality of the buried-valley aquifer near Dayton, Ohio. Results of CFC sampling indicate that approximately 25 percent of the 137 sampled wells were contaminated with excess CFC's that rendered the ground water unsuitable for age dating. Evaluation of CFC ages obtained for the remaining samples indicated that the CFC compounds used for dating were being affected by microbial degradation. The degradation occurred under anoxic conditions that are found in most parts of the buried-valley aquifer. As a result, ground-water ages derived by the CFC method were too old and were inconsistent with measured tritium concentrations and independently derived 3H-3He ages. Limited data indicate that dissolved methane may play an important role in the degradation of the CFC's. In contrast, the 3H-3He technique was found to yield ground-water ages that were chemically and hydrologically reasonable. Ground-water ages derived by the 3H-3He technique were compared to values for selected water- quality characteristics to evaluate temporal trends in ground-water quality in the buried- valley aquifer. Distinct temporal trends were not identified for pH, alkalinity, or calcium and magnesium because of rapid equilibration of ground-water with calcite and dolomite in aquifer sediments. Temporal trends in which the amount of scatter and the number of outlier concentrations increased as ground-water age decreased were noted for sodium, potassium, boron, bromide, chloride, ammonia, nitrate, phosphate

  20. Ground water dependence of endangered ecosystems: Nebraska's eastern saline wetlands.

    Science.gov (United States)

    Harvey, F Edwin; Ayers, Jerry F; Gosselin, David C

    2007-01-01

    Many endangered or threatened ecosystems depend on ground water for their survival. Nebraska's saline wetlands, home to a number of endangered species, are ecosystems whose development, sustenance, and survival depend on saline ground water discharge at the surface. This study demonstrates that the saline conditions present within the eastern Nebraska saline wetlands result from the upwelling of saline ground water from within the underlying Dakota Aquifer and deeper underlying formations of Pennsylvanian age. Over thousands to tens of thousands of years, saline ground water has migrated over regional scale flowpaths from recharge zones in the west to the present-day discharge zones along the saline streams of Rock, Little Salt, and Salt Creeks in Lancaster and Saunders counties. An endangered endemic species of tiger beetle living within the wetlands has evolved under a unique set of hydrologic conditions, is intolerant to recent anthropogenic changes in hydrology and salinity, and is therefore on the brink of extinction. As a result, the fragility of such systems demands an even greater understanding of the interrelationships among geology, hydrology, water chemistry, and biology than in less imperiled systems where adaptation is more likely. Results further indicate that when dealing with ground water discharge-dependent ecosystems, and particularly those dependent on dissolved constituents as well as the water, wetland management must be expanded outside of the immediate surface location of the visible ecosystem to include areas where recharge and lateral water movement might play a vital role in wetland hydrologic and chemical mixing dynamics.

  1. GWVis: A tool for comparative ground-water data visualization

    Science.gov (United States)

    Best, Daniel M.; Lewis, Robert R.

    2010-11-01

    The Ground-Water Visualization application ( GWVis) presents ground-water data visually in order to educate the public on ground-water issues. It is also intended for presentations to government and other funding agencies. GWVis works with ground-water level elevation data collected or modeled over a given time span, together with a matching fixed underlying terrain. GWVis was developed using the Python programming language in conjunction with associated extension packages and application program interfaces such as OpenGLTM to improve performance and allow us fine control of attributes of the model such as lighting, material properties, transformations, and interpolation. There are currently several systems available for visualizing ground-water data. We classify these into two categories: research-oriented models and static presentation-based models. While both of them have their strengths, we find the former overly complex and non-intuitive and the latter not engaging and presenting problems showing multiple data dimensions. GWVis bridges the gap between static and research based visualizations by providing an intuitive, interactive design that allows participants to view the model from different perspectives, infer information about simulations, and view a comparison of two datasets. By incorporating scientific data in an environment that can be easily understood, GWVis allows that information to be presented to a large audience base.

  2. Quality of surface and ground waters, Yakima Indian Reservation, Washington, 1973-74

    Science.gov (United States)

    Fretwell, M.O.

    1977-01-01

    This report describes the quality of the surface and ground waters of the Yakima Indian Reservation in south-central Washington, during the period November 1973-October 1974. The average dissolved-solids concentrations ranged from 48 to 116 mg/L (milligrams per liter) in the mountain streams, and from 88 to 372 mg/L in the lowland streams, drains, and a canal. All the mountain streams contain soft water (classified as 0-60 mg/L hardness as CaC03), and the lowland streams, drains, and canal contain soft to very hard water (more than 180 mg/L hardness as CaC03). The water is generally of suitable quality for irrigation, and neither salinity nor sodium hazards are a problem in waters from any of the streams studied. The specific conductance of water from the major aquifers ranged from 20 to 1 ,540 micromhos. Ground water was most dilute in mineral content in the Klickitat River basin and most concentrated in part of the Satus Creek basin. The ground water in the Satus Creek basin with the most concentrated mineral content also contained the highest percentage composition of sulfate, chloride, and nitrate. For drinking water, the nitrate-nitrogen concentrations exceeded the U.S. Public Health Service 's recommended limit of 10 mg/L over an area of several square miles, with a maximum observed concentration of 170 mg/L. (Woodard-USGS).

  3. Ground-water-quality assessment of the Central Oklahoma Aquifer, Oklahoma; geochemical and geohydrologic investigations

    Science.gov (United States)

    Parkhurst, D.L.; Christenson, S.C.; Breit, G.N.

    1993-01-01

    The National Water-Quality Assessment pilot project for the Central Oklahoma aquifer examined the chemical and isotopic composition of ground water, the abundances and textures of minerals in core samples, and water levels and hydraulic properties in the flow system to identify geochemical reactions occurring in the aquifer and rates and directions of ground-water flow. The aquifer underlies 3,000\\x11square miles of central Oklahoma and consists of Permian red beds, including parts of the Permian Garber Sandstone, Wellington Formation, and Chase, Council Grove, and Admire Groups, and Quaternary alluvium and terrace deposits. In the part of the Garber Sandstone and Wellington Formation that is not confined by the Permian Hennessey Group, calcium, magnesium, and bicarbonate are the dominant ions in ground water; in the confined part of the Garber Sandstone and Wellington Formation and in the Chase, Council Grove, and Admire Groups, sodium and bicarbonate are the dominant ions in ground water. Nearly all of the Central Oklahoma aquifer has an oxic or post-oxic environment as indicated by the large dissolved concentrations of oxygen, nitrate, arsenic (V), chromium (VI), selenium (VI), vanadium, and uranium. Sulfidic and methanic environments are virtually absent. Petrographic textures indicate dolomite, calcite, sodic plagioclase, potassium feldspars, chlorite, rock fragments, and micas are dissolving, and iron oxides, manganese oxides, kaolinite, and quartz are precipitating. Variations in the quantity of exchangeable sodium in clays indicate that cation exchange is occurring within the aquifer. Gypsum may dissolve locally within the aquifer, as indicated by ground water with large concentrations of sulfate, but gypsum was not observed in core samples. Rainwater is not a major source for most elements in ground water, but evapotranspiration could cause rainwater to be a significant source of potassium, sulfate, phosphate and nitrogen species. Brines derived from

  4. Ground-Water Quality Data in the Southern Sacramento Valley, California, 2005 - Results from the California GAMA Program

    Science.gov (United States)

    Milby Dawson, Barbara J.; Bennett, George L.; Belitz, Kenneth

    2008-01-01

    Ground-water quality in the approximately 2,100 square-mile Southern Sacramento Valley study unit (SSACV) was investigated from March to June 2005 as part of the Statewide Basin Assessment Project of Ground-Water Ambient Monitoring and Assessment (GAMA) Program. This study was designed to provide a spatially unbiased assessment of raw ground-water quality within SSACV, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 83 wells in Placer, Sacramento, Solano, Sutter, and Yolo Counties. Sixty-seven of the wells were selected using a randomized grid-based method to provide statistical representation of the study area. Sixteen of the wells were sampled to evaluate changes in water chemistry along ground-water flow paths. Four additional samples were collected at one of the wells to evaluate water-quality changes with depth. The GAMA Statewide Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001 and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The ground-water samples were analyzed for a large number of man-made organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and wastewater-indicator constituents), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, matrix spikes

  5. Ground-water resources of the Houston district, Texas

    Science.gov (United States)

    White, Walter N.; Rose, N.A.; Guyton, William F.

    1944-01-01

    This report covers the current phase of an investigation of the supply of ground water available for the Houston district and adjacent region, Texas,- that has been in progress during the past 10 years. The field operations included routine inventories of pumpage, measurements of water levels in observation wells and collection of other hydrologic data, pumping tests on 21 city-owned wells to determine coefficients of permeability and storage, and the drilling of 13 deep test wells in unexplored parts of the district. Considerable attention has been given to studies of the location of areas or beds of sand that contain salt water. The ground water occurs in beds of sand, sandstone, and gravel of Miocene, Pliocene, and Pleistocene age. These formations crop out in belts that dip southeastward from their outcrop areas and are encountered by wells at progressively greater depths toward the southeast. The beds throughout the section are lithologically similar, and there is little agreement among geologists as to their correlation. -In this investigation, however, the sediments, penetrated by the wells are separated into six zones, chiefly on the basis of electrical logs. Most of the water occurs in zone 3, which ranges in thickness from 800 to 1,200 feet. Large quantities of ground water are pumped in three areas in the Houston district, as follows: The Houston tromping area, which includes Houston and the areas immediately adjacent; the Pasadena pumping area, which includes the industrial section extending along the ship channel from the Houston city limits eastward to Deer Park; and the Katy pumping area, an irregular-shaped area of several hundred square miles, which is roughly centered around the town of Katy, 30 miles west of Houston. In 1930 the total combined withdrawal of ground water in the Houston and Pasadena pumping areas averaged about 50 million gallons a day. It declined somewhat during 1932 and 1933 and then gradually increased, until in 1935 the total

  6. Questa Baseline and Pre-Mining Ground-Water Quality Investigation. 25. Summary of Results and Baseline and Pre-Mining Ground-Water Geochemistry, Red River Valley, Taos County, New Mexico, 2001-2005

    Science.gov (United States)

    Nordstrom, D. Kirk

    2008-01-01

    Active and inactive mine sites are challenging to remediate because of their complexity and scale. Regulations meant to achieve environmental restoration at mine sites are equally challenging to apply for the same reasons. The goal of environmental restoration should be to restore contaminated mine sites, as closely as possible, to pre-mining conditions. Metalliferous mine sites in the Western United States are commonly located in hydrothermally altered and mineralized terrain in which pre-mining concentrations of metals were already anomalously high. Typically, those pre-mining concentrations were not measured, but sometimes they can be reconstructed using scientific inference. Molycorp?s Questa molybdenum mine in the Red River Valley, northern New Mexico, is located near the margin of the Questa caldera in a highly mineralized region. The State of New Mexico requires that ground-water quality standards be met on closure unless it can be shown that potential contaminant concentrations were higher than the standards before mining. No ground water at the mine site had been chemically analyzed before mining. The aim of this investigation, in cooperation with the New Mexico Environment Department (NMED), is to infer the pre-mining ground-water quality by an examination of the geologic, hydrologic, and geochemical controls on ground-water quality in a nearby, or proximal, analog site in the Straight Creek drainage basin. Twenty-seven reports contain details of investigations on the geological, hydrological, and geochemical characteristics of the Red River Valley that are summarized in this report. These studies include mapping of surface mineralogy by Airborne Visible-Infrared Imaging Spectrometry (AVIRIS); compilations of historical surface- and ground- water quality data; synoptic/tracer studies with mass loading and temporal water-quality trends of the Red River; reaction-transport modeling of the Red River; environmental geology of the Red River Valley; lake

  7. Low-Level Volatile Organic Compounds in Active Public Supply Wells as Ground-Water Tracers in the Los Angeles Physiographic Basin, California, 2000

    Science.gov (United States)

    Shelton, Jennifer L.; Burow, Karen R.; Belitz, Kenneth; Dubrovsky, Neil M.; Land, Michael; Gronberg, JoAnn

    2001-01-01

    Data were collected to evaluate the use of low-level volatile organic compounds (VOC) to assess the vulnerability of public supply wells in the Los Angeles physiographic basin. Samples of untreated ground water from 178 active public supply wells in the Los Angeles physiographic basin show that VOCs were detected in 61 percent of the ground-water samples; most of these detections were low, with only 29 percent above 1 mg/L (microgram per liter). Thirty-nine of the 86 VOCs analyzed were detected in at least one sample, and 11 VOCs were detected in 7 percent or more of the samples. The six most frequently detected VOCs were trichloromethane (chloroform) (46 percent); trichloroethene (TCE) (28 percent); tetrachloro-ethene (PCE) (19 percent); methyl tert-butyl ether (MTBE) (14 percent); 1,1-dichloroethane (11 percent); and 1,1,1-trichloroethane (TCA) (11 percent). These VOCs were also the most frequently detected VOCs in ground water representative of a wide range of hydrologically conditions in urban areas nationwide. Only two VOCs (TCE and PCE) exceeded state and federal primary maximum contaminant levels (MCL) for drinking water in a total of seven samples. Because samples were collected prior to water treatment, sample concentrations do not represent the concentrations entering the drinking-water system.Ground water containing VOCs may be considered to be a tracer of postindustrial-aged water-water that was recharged after the onset of intense urban development. The overall distribution of VOC detections is related to the hydrological and the engineered recharge facilities in the Coastal Los Angeles Basin and the Coastal Santa Ana Basin that comprise the Los Angeles physiographic basin. Most of the ground-water recharge occurs at engineered recharge facilities in the generally coarse-grained northeastern parts of the study area (forebay areas). Ground-water recharge from the land surface is minimal in the southwestern part of the basins, distal from the recharge

  8. Decadal-scale changes of pesticides in ground water of the United States, 1993-2003

    Science.gov (United States)

    Bexfield, L.M.

    2008-01-01

    Pesticide data for ground water sampled across the United States between 1993-1995 and 2001-2003 by the U.S. Geological Survey National Water-Quality Assessment Program were evaluated for trends in detection frequency and concentration. The data analysis evaluated samples collected from a total of 362 wells located in 12 local well networks characterizing shallow ground water in agricultural areas and six local well networks characterizing the drinking water resource in areas of variable land use. Each well network was sampled once during 1993-1995 and once during 2001-2003. The networks provide an overview of conditions across a wide range of hydrogeologic settings and in major agricultural areas that vary in dominant crop type and pesticide use. Of about 80 pesticide compounds analyzed, only six compounds were detected in ground water from at least 10 wells during both sampling events. These compounds were the triazine herbicides atrazine, simazine, and prometon; the acetanilide herbicide metolachlor; the urea herbicide tebuthiuron; and an atrazine degradate, deethylatrazine (DEA). Observed concentrations of these compounds generally were Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  9. Fly Ash Disposal in Ash Ponds: A Threat to Ground Water Contamination

    Science.gov (United States)

    Singh, R. K.; Gupta, N. C.; Guha, B. K.

    2016-07-01

    Ground water contamination due to deposition of fly ash in ash ponds was assessed by simulating the disposal site conditions using batch leaching test with fly ash samples from three thermal power plants. The periodic analysis of leachates was performed for selected elements, Fe, Cu, Ni, Cr, Pb and Cd in three different extraction solutions to determine the maximum amount that can be leached from fly ash. It was observed that at low pH value, maximum metals are released from the surface of the ash into leachate. The average concentration of these elements found in ground water samples from the nearby area of ash ponds shows that almost all the metals except `Cr' are crossing the prescribed limits of drinking water. The concentration of these elements at this level can endanger public health and environment.

  10. Geostatical Modelling For Ground Water Pollution in Salem by Using Gis

    Directory of Open Access Journals (Sweden)

    T. Subramani

    2014-06-01

    Full Text Available Ground waters are the major resources to meet out the entire requirements. Pollution of air, water and land has an effect on the quality of the ground waters. The chemical characteristics of groundwater in Salem taluk of Salem district have been studied using Geostatistical modeling to evaluate the suitability of water for irrigation and domestic uses. The 32 water samples from PWD wells taken during the years 1999 to 2009 for post monsson and pre monsoon were tested for various chemical parameters like pH and TDS .The Geostatistical analyst of mean, mode, standard deviation, cluster & simple to study the spatial pattern of contamination movement for the years 1999 to 2009. Trend analysis was performed to identify trends in the input dataset. The concentrations of physical and chemical constituents in the water samples were compared with the World Health Organization (WHO standard to know the suitability of water for drinking.

  11. Prevalence of Campylobacter species in ground water in Sokoto, Sokoto state, Nigeria

    Directory of Open Access Journals (Sweden)

    Agatha N. Ugboma

    2013-12-01

    Full Text Available Aim: The present study was conducted to determine the presence and prevalence of Campylobacter species in ground water in Sokoto, Sokoto State. Materials and Methods: The prevalence of Campylobacter species was determined by collecting a total of 74 water samples from wells in Sokoto over a period of four months from May to August 2011 and analyzed using cultural isolation techniques and biochemical characterization. Results: Totally 39 (52.70% water samples were Campylobacter positive. The species identified were Campylobacter jejuni 23 (58.97%, Campylobacter coli 11 (28.21% and Campylobacter hyointestinalis 5 (12.82%. Conclusion: Based on this study, the isolation of Campylobacter species from ground water (wells in this study is of serious public health importance as untreated water has been implicated as the cause of sporadic infections and outbreaks of Campylobacteriosis worldwide. [Vet World 2013; 6(6.000: 285-287

  12. Assessment of soil and ground water quality in Rewa district of Vindhyan Plateau (India).

    Science.gov (United States)

    Dwivedi, A P; Tripathi, I P; Kumar, M Suresh

    2013-01-01

    A systematic seasonal study has been carried out to assess the physico-chemical characteristics of ground water and soils in Rewa district of India. The drinking water in the study area is supplied mainly through Public Health Engineering (PHE) department from river (Bichhia, Bihar) and ground water. Water and soil samples were collected from different locations in the Rewa district, i.e. 10 hand pumps and 10 bore wells around all over the district. Regular monitoring was carried out during summer, rainy and winter seasons, to study the seasonal variation in physico-chemical parameters and metals concentration. The parameters like pH, turbidity, dissolved oxygen (DO), biochemical oxygen demand (BOD), chemical oxygen demand (COD), nitrate, nitrite, chloride, sulphate, phosphate and heavy metals were estimated for water and soil samples collected from the Rewa district. The results obtained are discussed, correlated with probable sources of contamination and suggested the measures to minimize the pollution.

  13. Fly Ash Disposal in Ash Ponds: A Threat to Ground Water Contamination

    Science.gov (United States)

    Singh, R. K.; Gupta, N. C.; Guha, B. K.

    2016-09-01

    Ground water contamination due to deposition of fly ash in ash ponds was assessed by simulating the disposal site conditions using batch leaching test with fly ash samples from three thermal power plants. The periodic analysis of leachates was performed for selected elements, Fe, Cu, Ni, Cr, Pb and Cd in three different extraction solutions to determine the maximum amount that can be leached from fly ash. It was observed that at low pH value, maximum metals are released from the surface of the ash into leachate. The average concentration of these elements found in ground water samples from the nearby area of ash ponds shows that almost all the metals except `Cr' are crossing the prescribed limits of drinking water. The concentration of these elements at this level can endanger public health and environment.

  14. Regional estimation of total recharge to ground water in Nebraska.

    Science.gov (United States)

    Szilagyi, Jozsef; Harvey, F Edwin; Ayers, Jerry F

    2005-01-01

    Naturally occurring long-term mean annual recharge to ground water in Nebraska was estimated by a novel water-balance approach. This approach uses geographic information systems (GIS) layers of land cover, elevation of land and ground water surfaces, base recharge, and the recharge potential in combination with monthly climatic data. Long-term mean recharge > 140 mm per year was estimated in eastern Nebraska, having the highest annual precipitation rates within the state, along the Elkhorn, Platte, Missouri, and Big Nemaha River valleys where ground water is very close to the surface. Similarly high recharge values were obtained for the Sand Hills sections of the North and Middle Loup, as well as Cedar River and Beaver Creek valleys due to high infiltration rates of the sandy soil in the area. The westernmost and southwesternmost parts of the state were estimated to typically receive recharge a year.

  15. Coliphages and bacteria in ground water from Tehran, Iran

    Energy Technology Data Exchange (ETDEWEB)

    Shariatpanahi, M.; Anderson, A.C.

    1987-07-01

    The purpose of this study was to examine the microbial quality of Tehran's ground water and selected springs, using coliphages and selected bacteria as indicator organisms. The water table in Tehran varies from approximately 160 meters in the north to approximately 5 meters in the south. Individual wells and subterranean man-made aqueducts (qanate) tap the ground water. Since Tehran lacks municipal sewage facilities, waste disposal is by means of seepage pits, privies and leaching cesspools. There is potential for waste from these sites to leach into the ground water, particularly in the south where the water table is near the surface and the clay content of the soil holds moisture during periods of heavy rainfall.

  16. Selected aquifer-test and specific-capacity data for wells in the Lost Creek Designated Ground Water Basin, Weld, Adams, and Arapahoe Counties, Colorado

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This point dataset contains estimates of aquifer transmissivity and hydraulic conductivity at selected well locations in the Lost Creek Designated Ground Water...

  17. Ground-water quality and its relation to hydrogeology, land use, and surface-water quality in the Red Clay Creek basin, Piedmont Physiographic Province, Pennsylvania and Delaware

    Science.gov (United States)

    Senior, Lisa A.

    1996-01-01

    The Red Clay Creek Basin in the Piedmont Physiographic Province of Pennsylvania and Delaware is a 54-square-mile area underlain by a structurally complex assemblage of fractured metamorphosed sedimentary and igneous rocks that form a water-table aquifer. Ground-water-flow systems generally are local, and ground water discharges to streams. Both ground water and surface water in the basin are used for drinking-water supply. Ground-water quality and the relation between ground-water quality and hydrogeologic and land-use factors were assessed in 1993 in bedrock aquifers of the basin. A total of 82 wells were sampled from July to November 1993 using a stratified random sampling scheme that included 8 hydrogeologic and 4 land-use categories to distribute the samples evenly over the area of the basin. The eight hydrogeologic units were determined by formation or lithology. The land-use categories were (1) forested, open, and undeveloped; (2) agricultural; (3) residential; and (4) industrial and commercial. Well-water samples were analyzed for major and minor ions, nutrients, volatile organic compounds (VOC's), pesticides, polychlorinated biphenyl compounds (PCB's), and radon-222. Concentrations of some constituents exceeded maximum contaminant levels (MCL) or secondary maximum contaminant levels (SMCL) established by the U.S. Environmental Protection Agency for drinking water. Concentrations of nitrate were greater than the MCL of 10 mg/L (milligrams per liter) as nitrogen (N) in water from 11 (13 percent) of 82 wells sampled; the maximum concentration was 38 mg/L as N. Water from only 1 of 82 wells sampled contained VOC's or pesticides that exceeded a MCL; water from that well contained 3 mg/L chlordane and 1 mg/L of PCB's. Constituents or properties of well-water samples that exceeded SMCL's included iron, manganese, dissolved solids, pH, and corrosivity. Water from 70 (85 percent) of the 82 wells sampled contained radon-222 activities greater than the proposed MCL of

  18. Ground-water quality and its relation to hydrogeology, land use, and surface-water quality in the Red Clay Creek basin, Piedmont Physiographic Province, Pennsylvania and Delaware

    Science.gov (United States)

    Senior, Lisa A.

    1996-01-01

    The Red Clay Creek Basin in the Piedmont Physiographic Province of Pennsylvania and Delaware is a 54-square-mile area underlain by a structurally complex assemblage of fractured metamorphosed sedimentary and igneous rocks that form a water-table aquifer. Ground-water-flow systems generally are local, and ground water discharges to streams. Both ground water and surface water in the basin are used for drinking-water supply. Ground-water quality and the relation between ground-water quality and hydrogeologic and land-use factors were assessed in 1993 in bedrock aquifers of the basin. A total of 82 wells were sampled from July to November 1993 using a stratified random sampling scheme that included 8 hydrogeologic and 4 land-use categories to distribute the samples evenly over the area of the basin. The eight hydrogeologic units were determined by formation or lithology. The land-use categories were (1) forested, open, and undeveloped; (2) agricultural; (3) residential; and (4) industrial and commercial. Well-water samples were analyzed for major and minor ions, nutrients, volatile organic compounds (VOC's), pesticides, polychlorinated biphenyl compounds (PCB's), and radon-222. Concentrations of some constituents exceeded maximum contaminant levels (MCL) or secondary maximum contaminant levels (SMCL) established by the U.S. Environmental Protection Agency for drinking water. Concentrations of nitrate were greater than the MCL of 10 mg/L (milligrams per liter) as nitrogen (N) in water from 11 (13 percent) of 82 wells sampled; the maximum concentration was 38 mg/L as N. Water from only 1 of 82 wells sampled contained VOC's or pesticides that exceeded a MCL; water from that well contained 3 mg/L chlordane and 1 mg/L of PCB's. Constituents or properties of well-water samples that exceeded SMCL's included iron, manganese, dissolved solids, pH, and corrosivity. Water from 70 (85 percent) of the 82 wells sampled contained radon-222 activities greater than the proposed MCL of

  19. The role of hand calculations in ground water flow modeling.

    Science.gov (United States)

    Haitjema, Henk

    2006-01-01

    Most ground water modeling courses focus on the use of computer models and pay little or no attention to traditional analytic solutions to ground water flow problems. This shift in education seems logical. Why waste time to learn about the method of images, or why study analytic solutions to one-dimensional or radial flow problems? Computer models solve much more realistic problems and offer sophisticated graphical output, such as contour plots of potentiometric levels and ground water path lines. However, analytic solutions to elementary ground water flow problems do have something to offer over computer models: insight. For instance, an analytic one-dimensional or radial flow solution, in terms of a mathematical expression, may reveal which parameters affect the success of calibrating a computer model and what to expect when changing parameter values. Similarly, solutions for periodic forcing of one-dimensional or radial flow systems have resulted in a simple decision criterion to assess whether or not transient flow modeling is needed. Basic water balance calculations may offer a useful check on computer-generated capture zones for wellhead protection or aquifer remediation. An easily calculated "characteristic leakage length" provides critical insight into surface water and ground water interactions and flow in multi-aquifer systems. The list goes on. Familiarity with elementary analytic solutions and the capability of performing some simple hand calculations can promote appropriate (computer) modeling techniques, avoids unnecessary complexity, improves reliability, and is likely to save time and money. Training in basic hand calculations should be an important part of the curriculum of ground water modeling courses.

  20. Ground-Water Quality Data in the Coachella Valley Study Unit, 2007: Results from the California GAMA Program

    Science.gov (United States)

    Goldrath, Dara A.; Wright, Michael T.; Belitz, Kenneth

    2009-01-01

    Ground-water quality in the approximately 820 square-mile Coachella Valley Study Unit (COA) was investigated during February and March 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of raw ground water used for public-water supplies within the Coachella Valley, and to facilitate statistically consistent comparisons of ground-water quality throughout California. Samples were collected from 35 wells in Riverside County. Nineteen of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Sixteen additional wells were sampled to evaluate changes in water chemistry along selected ground-water flow paths, examine land use effects on ground-water quality, and to collect water-quality data in areas where little exists. These wells were referred to as 'understanding wells'. The ground-water samples were analyzed for a large number of organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (uranium, tritium, carbon-14, and stable isotopes of hydrogen, oxygen, and boron), and dissolved noble gases (the last in collaboration with Lawrence Livermore National Laboratory) also were measured to help identify the source and age of the sampled

  1. Study on Some Physico-Chemical Characteristics of Ground Water of District Rampur - A Statistical Approach

    OpenAIRE

    Susheel Kumar Sindhu; Amit Sharma

    2007-01-01

    A systematic study has been carried out to explore the water quality index of ground water of various tehsils of Rampur district. Twenty five water samples from tube wells, open wells and hand pumps at various locations were collected and analyzed for pH, nitrate, turbidity, total dissolve solid, chlorides, total hardness, alkalinity and fluoride. In this study overall water quality of Rampur district is very poor and unsuitable for drinking purpose. Water quality of Bilaspur, Shahabad and Ra...

  2. Reconnaissance of the geology and ground-water hydrology of the Belle Fourche irrigation project, South Dakota

    Science.gov (United States)

    Rosier, Arthur J.

    1952-01-01

    The Belle Fourche irrigation project is in western South Dakota on the plains adjacent to the northeastern edge of the Black Hills. The project is drained by the Belle Fourche River and is characterized generally by broad shallow valleys that lie between hills with gentle slopes. The climate is semiarid. Most of the area is mantled by residual clay, terrace deposits, and alluvium. The terrace deposits contain much water and are the most permeable deposits in the project area. The alluvial deposits of the Belle Fourche River and of the creeks south of the river contain much sand and gravel and are relatively permeable. The alluvium of the creeks north of the river is predominantly clay and is only slightly permeable; it greatly resembles the residual clay of the weathered bedrock formations, which are mostly shale in this area. Although relatively abundant ground water is found in the unconsolidated materials above the bedrock formations, the ground water from the clayey deposits generally contains too great a concentration of objectionable salts to be fit for human or livestock consumption. The ground water in the more coarse materials is of better quality and in some small areas is satisfactory for domestic use. Most of the water for domestic use is hauled from deep artesian wells within the area. The chief source of ground water is seepage from irrigation canals in the terrace and alluvial deposits. When this water moves to areas of lower permeability a correspondingly greater rise of the water table compensates for the lower permeability and results in the waterlogging of many areas. Open drainage ditches have been constructed in all large areas that are affected by high ground-water levels. Except in those areas that are underlain predominantly by clayey materials, these ditches usually have proven to be satisfactory for the control of ground-water levels. However, lining the canals seems to be a more satisfactory method of preventing the seepage that causes

  3. Ground-Water Quality Data in the Southeast San Joaquin Valley, 2005-2006 - Results from the California GAMA Program

    Science.gov (United States)

    Burton, Carmen A.; Belitz, Kenneth

    2008-01-01

    Ground-water quality in the approximately 3,800 square-mile Southeast San Joaquin Valley study unit (SESJ) was investigated from October 2005 through February 2006 as part of the Priority Basin Assessment Project of Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001 and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The SESJ study was designed to provide a spatially unbiased assessment of raw ground-water quality within SESJ, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 99 wells in Fresno, Tulare, and Kings Counties, 83 of which were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 16 of which were sampled to evaluate changes in water chemistry along ground-water flow paths or across alluvial fans (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine, and 1,2,3-trichloropropane), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected at approximately 10 percent of the wells, and the results

  4. Ground-Water Quality Data in the Central Sierra Study Unit, 2006 - Results from the California GAMA Program

    Science.gov (United States)

    Ferrari, Matthew J.; Fram, Miranda S.; Belitz, Kenneth

    2008-01-01

    Ground-water quality in the approximately 950 square kilometer (370 square mile) Central Sierra study unit (CENSIE) was investigated in May 2006 as part of the Priority Basin Assessment project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). This study was designed to provide a spatially unbiased assessment of the quality of raw ground water used for drinking-water supplies within CENSIE, and to facilitate statistically consistent comparisons of ground-water quality throughout California. Samples were collected from thirty wells in Madera County. Twenty-seven of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and three were selected to aid in evaluation of specific water-quality issues (understanding wells). Ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], gasoline oxygenates and degradates, pesticides and pesticide degradates), constituents of special interest (N-nitrosodimethylamine, perchlorate, and 1,2,3-trichloropropane), naturally occurring inorganic constituents [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon], and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. In total, over 250 constituents and water-quality indicators were investigated. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at approximately one-sixth of the wells, and

  5. Maps showing ground-water units and withdrawal, Basin and Range Province, Texas

    Science.gov (United States)

    Brady, B.T.; Bedinger, M.S.; Mikels, John

    1984-01-01

    This report on ground-water units and withdrawal in the Basin and Range province of Texas (see index map) was prepared as part of a program of the U.S. Geological Survey to identify prospective regions for further study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984), utilizing program guidelines defined in Sargent and Bedinger (1984). Also included in this report are selected references on pertinent geologic and hydrologic studies of the region. Other map reports in this series contain detailed data on ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources.

  6. Methanogenic biodegradation of creosote contaminants in natural and simulated ground-water ecosystems

    Science.gov (United States)

    Godsy, E. Michael; Goerlitz, Donald; Grbic-Galic, Dunja

    1992-01-01

    Wastes from a wood preserving plant in Pensacola, Florida have contaminated the near-surface sand-and-gravel aquifer with creosote-derived compounds and pentachlorophenol. Contamination resulted from the discharge of plant waste waters to and subsequent seepage from unlined surface impoundments that were in direct hydraulic contact with the ground water. Two distinct phases resulted when the creosote and water mixed: a denser than water hydrocarbon phase that moved vertically downward, and an organic-rich aqueous phase that moved laterally with the ground-water flow. The aqueous phase is enriched in organic acids, phenolic compounds, single- and double-ring nitrogen, sulfur, and oxygen containing compounds, and single- and double-ring aromatic hydrocarbons. The ground water is devoid of dissolved O2, is 60-70% saturated with CH4 and contains H2S. Field analyses document a greater decrease in concentration of organic fatty acids, benzoic acid, phenol, 2-, 3-, 4-methylphenol, quinoline, isoquinoline, 1(2H)-quinolinone, and 2(1H)-isoquinolinone during downgradient movement in the aquifer than could be explained by dilution and/or dispersion. Laboratory microcosm studies have shown that within the study region, this effect can be attributed to microbial degradation to CH4 and CO2. A small but active methanogenic population was found on sediment materials taken from highly contaminated parts of the aquifer.

  7. Ground-water quality and geochemistry in Dayton, Stagecoach, and Churchill Valleys, western Nevada

    Science.gov (United States)

    Thomas, James M.; Lawrence, Stephen J.

    1994-01-01

    (5) results of optical, X-ray diffraction, and scanning-electron microscopy examination of mineral grains in the aquifer sediments. Sulfur-isotopic composition of ground- water samples also supports the models. In general, the quality of ground water in the study area meets Nevada State drinking-water standards and is acceptable for most uses. In addition to analysis for major ions, samples were analyzed for 22 inorganic trace elements, 3 nutrients, and 4 radionuclides. Selenium in 1 sample is the only constituent that exceeded Nevada State primary drinking-water standards. Nevada State secondary- drinking water standards were exceeded for fluoride in 1 sample, for iron in 7 samples, and for manganese in 19 samples. Minor constituent con- centrations are generally the result of local redox conditions, and are primarily from minerals in volcanic and marine metasedimentary rocks, metal- oxide coatings on mineral grains, and organic matter.

  8. Preliminary hydrogeologic assessment of a ground-water contamination area in Wolcott, Connecticut

    Science.gov (United States)

    Stone, J.R.; Casey, G.D.; Mondazzi, R.A.; Frick, T.W.

    1997-01-01

    Contamination of ground water by volatile organic compounds and inorganic constituents has been identified at a number of industrial sites in the Town of Wolcott, Connecticut. Contamination is also present at a municipal landfill in the City of Waterbury that is upgradient from the industrial sites in the local ground-water-flow system. The study area, which lies in the Western Highlands of Connecticut, is in the Mad River Valley, a tributary to the Naugatuck River. Geohydrologic units (aquifer materials) include unconsolidated glacial sediments (surficial materials) and fractured crystalline (metamorphic) bedrock. Surficial materials include glacial till, coarse-grained andfine-grained glacial stratified deposits, and postglacial floodplain alluvium and swamp deposits. The ground-water-flow system in the surficial aquifer is complex because the hydraulic properties of the surficial materials are highly variable. In the bedrock aquifer, ground water moves exclusively through fractures. Hydrologic characteristics of the crystalline bedrock-degree of confinement, hydraulic conductivity, storativity, and porosity-are poorly defined in the study area. Further study is needed to adequately assess ground-water flow and contaminant migration under current or past hydrologic conditions. All known water-supply wells in the study area obtain water from the bedrock aquifer. Twenty households in a hillside residential area on Tosun Road currently obtain drinking water from private wells tapping the bedrock aquifer. The extent of contamination in the bedrock aquifer and the potential for future contamination from known sources of contamination in the surficial aquifer is of concern to regulatory agencies. Previous investigations have identified ground-water contamination by volatile organic compounds at the Nutmeg Valley Road site area. Contamination has been associated with on-site disposal of heavy metals, chlorinated and non-chlorinated volatile organic compounds, and

  9. Environmental surveillance master sampling schedule

    Energy Technology Data Exchange (ETDEWEB)

    Bisping, L.E.

    1996-02-01

    Environmental surveillance of the Hanford Site and surrounding areas is conducted by the Pacific Northwest National Laboratory (PNNL) for the US Department of Energy (DOE). This document contains the planned 1996 schedules for routine collection of samples for the Surface Environmental Surveillance Project (SESP), Drinking Water Project, and Ground-Water Surveillance Project.

  10. Discharge areas for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents discharge areas in the Death Valley regional ground-water flow system (DVRFS) transient model. Natural ground-water discharge occurs...

  11. Material-property zones used in the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Zones in this data set represent spatially contiguous areas that influence ground-water flow in the Death Valley regional ground-water flow system (DVRFS), an...

  12. Model grid and infiltration values for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the model grid and infiltration values simulated in the transient ground-water flow model of the Death Valley regional ground-water...

  13. Boundary of the ground-water flow model by IT Corporation (1996), for the Death Valley regional ground-water flow system study, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the boundary of the steady-state ground-water flow model built by IT Corporation (1996). The regional, 20-layer ground-water flow...

  14. Material-property zones used in the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Zones in this data set represent spatially contiguous areas that influence ground-water flow in the Death Valley regional ground-water flow system (DVRFS), an...

  15. Model grid and infiltration values for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the model grid and infiltration values simulated in the transient ground-water flow model of the Death Valley regional ground-water...

  16. Discharge areas for the transient ground-water flow model, Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set represents discharge areas in the Death Valley regional ground-water flow system (DVRFS) transient model. Natural ground-water discharge...

  17. Ground water heat pumps and cooling with ground water basins as seasonal storage; Grundvandsvarmepumper og -koeling med grundvandsmagasiner som saesonlager

    Energy Technology Data Exchange (ETDEWEB)

    2008-04-15

    Ground water temperature is constant all the year round, in Denmark approximately 9 deg. C, which is ideal for a number of cooling purposes including cooling of buildings. The structures in which the ground water flows (sand, gravel and chalk) are efficient for storing coldness and heat over longer periods. By using seasonal storage of low-temperature heat and coldness in ground water layers close to the terrain it is feasible to reach profitable energy savings of up to 90% for cooling and heating of e.g. hotels, airports, shopping malls, office buildings and other larger buildings. At the same time the large energy savings means major reduction of CO{sub 2} emissions. (BA)

  18. Ground water heat pumps and cooling with ground water basins as seasonal storage; Grundvandsvarmepumper og -koeling med grundvandsmagasiner som saesonlager

    Energy Technology Data Exchange (ETDEWEB)

    2008-04-15

    Ground water temperature is constant all the year round, in Denmark approximately 9 deg. C, which is ideal for a number of cooling purposes including cooling of buildings. The structures in which the ground water flows (sand, gravel and chalk) are efficient for storing coldness and heat over longer periods. By using seasonal storage of low-temperature heat and coldness in ground water layers close to the terrain it is feasible to reach profitable energy savings of up to 90% for cooling and heating of e.g. hotels, airports, shopping malls, office buildings and other larger buildings. At the same time the large energy savings means major reduction of CO{sub 2} emissions. (BA)

  19. Efficiency of silver nanoparticles against bacterial contaminants isolated from surface and ground water in Egypt

    Directory of Open Access Journals (Sweden)

    Reem Dosoky

    2015-06-01

    Full Text Available The bactericidal efficiency of silver nanoparticles (AgNP was evaluated against bacteria isolated from surface and ground water samples in Egypt. The AgNP were synthesized by typical one-step synthesis protocol, and were characterized using transmission electron microscopy and atomic absorption spectrophotometer. The bactericidal efficiency of AgNP was evaluated by its application in three concentrations i.e., 0.1, 0.05 and 0.01 ppm to water sample, and allowed to interact with bacteria for different duration e.g., 5 min 15 min, 30 min, 1 h and 2 h. Then, the bactericidal efficiency of AgNPs was determined by comparing the counted bacteria before and after the treatments. Higher mean values of total bacterial count (TBC, total coliform count (TCC, and total streptococcal count (TFS were detected in surface water than in ground water. Also, the results showed that TBC, TCC and TFS exceeded permissible limits. Application of AgNP at different concentration, the number of bacteria in TBC was significantly reduced in all AgNP-exposed samples as compared to the control group (p<0.05. The highest concentration of AgNP exhibited highest bactericidal efficiency in TBC, where, after two hours, 0.1, 0.05 and 0.01 mg/L AgNP was found to be sufficient to inhibit 91.85, 89.14 and 74.92%, and 92.33, 85.23 and 53.17% in TBC of surface and ground water, respectively. Moreover, the inhibition efficiency of the highest concentration (0.1 ppm against TCC reached to 98.10 and 99.88% in surface water and 95.54 and 99.20% in ground water after 1 h and 2 h, respectively. Similar results were found against TFS count. The AgNPs were found to be effective against bacteria of water origin.

  20. Selenium speciation in ground water. Quarterly report

    Energy Technology Data Exchange (ETDEWEB)

    Atalay, A.

    1990-07-10

    Selenium toxicity diseases in animals may occur when the intake exceeds 4 mg/kg and selenium deficiency symptoms may occur when dietary intake is less than 0.04 mg/kg. Since the selenium dietary requirement is very close to toxic concentration, it is important to understand the distribution of selenium in the environment. Selenium occurs in four oxidation states (-II, 0, +IV, and +VI) as selenide, elemental selenium, selenite and selenate. Selenate is reported as more soluble and less adsorbed than selenite. Selenate is more easily leached from soils and is the most available form for plants. Increased mobility of Se into the environment via anthropogenic activities, and the potential oxidation-reduction behavior of the element have made it imperative to study the aquatic chemistry of Se. For this purpose, Se species are divided into two different categories: dissolved Se (in material that passes through filters with 0.45 u openings) and particulate Se (in material of particle size > 0.45 mm) typically suspended sediment and other suspended solids. Element and colloidal phase, not truly dissolved, but passing through the filter is deemed to consist of selenium (-2,0). In dissolved state selenium may exist in three of its four oxidation states; Se(-II), Se(+IV), and Se(+VI). Particulate Se may exist in the same oxidation states as dissolved Se and can be found in different phases of the particulate matter. In sediments, Se may be within the organic material, iron and manganese oxides, carbonates or other mineral phases. The actual chemical forms of Se may be adsorbed to or coprecipitated with these phases (primarily selenite, SeO{sub 3}{sup 2{minus}}) and selenate, SeO{sub 4}{sup 2{minus}}. Selenide, Se(-II), can be covalently bound in the organic portion of a sediment. In addition, Se may be found in anoxic sediments as insoluble metal selenide precipitates, an insoluble elemental Se or as ferroselite (FeSe{sub 2}) and Se containing pyrite.

  1. Monitoring of the antioxidant BHT and its metabolite BHT-CHO in German river water and ground water.

    Science.gov (United States)

    Fries, Elke; Püttmann, Wilhelm

    2004-02-05

    The behavior of anthropogenic polar organic compounds in ground water during infiltration of river water to ground water was studied at the Oderbruch area on the eastern border of Germany. Additionally, waste water sewage treatment works (STWs) discharging their treated waste water into the Oder River and rain water precipitation from the Oderbruch area were investigated. The study was carried out from March 2000 to July 2001 to investigate seasonal variations of the target analytes. Samples were collected from four sites along the Oder River, from 24 ground water monitoring wells located close to the Oder, from one rain water collection station, from two roof runoffs, and from four STWs upstream of the Oderbruch. Results of the investigations of the antioxidant 3,5-di-tert-butyl-4-hydroxy-toluene (BHT) and its degradation product 3,5-di-tert-butyl-4-hydroxy-benzaldehyde (BHT-CHO) are presented. BHT and BHT-CHO were detected in all samples of the Oder River with mean concentrations of 178 and 102 ngl(-1), respectively. BHT and BHT-CHO were also detected in effluent waste water samples from municipal STWs at mean concentrations of 132 and 70 ngl(-1), respectively. Both compounds are discharged into river water directly via treated waste water. In the rain water sample, 308 ngl(-1) of BHT and 155 ngl(-1) of BHT-CHO were measured. Both compounds were detected in roof runoff with mean concentrations of 92 ngl(-1) for BHT and 138 ngl(-1) for BHT-CHO. The median values of BHT and BHT-CHO in ground water samples were 132 and 84 ngl(-1), respectively. The chemical composition of ground water from parts of the aquifer located less than 4.5 m distant from the river are greatly influenced by bank filtration. However, wet deposition followed by seepage of rain water into the aquifer is also a source of BHT and BHT-CHO in ground water.

  2. The ion chemistry of surface and ground waters in the Taklimakan Desert of Tarim Basin, western China

    Institute of Scientific and Technical Information of China (English)

    ZHU BingQi; YANG XiaoPing

    2007-01-01

    The physio-chemical and chemical features of water in natural conditions are controlled by the weathering of bedrocks, local climate, landforms and other geo-environmental parameters. In order to understand the characteristics of water and the origins of the dissolved loads in the rivers and in the ground waters of the Taklimakan Desert, western China, we studied the ions in the water samples collected from rivers and wells. We collected water samples from four rivers (Keriya River, Cele River, Tumiya River and Yulongkashi River) in the southern desert and ground water samples from many parts of the desert. Major cations and anions were measured using ion-chromatograph and titration with HCl. The total dissolved solids (TDS), pH and conductivity were examined on site by a portable multi-parameter analyzer. The data show that the water in the rivers of southern Taklimakan is still of fresh water quality and slight alkalinity, although the TDS is comparatively higher than that of many other rivers of the world. The ground water is fresh to slightly saline, with TDS a little higher than that of river water in the study area. The concentration of ions is slightly different between the four rivers in the southern Taklimakan. However, the chemistries of ground water in all samples are to a large degree controlled by sodium and chloride. The ions in the ground water are concluded to be mainly from dissolving of evaporites, consistent with the dry climate in the region, whereas the ions in the rivers are mainly from rock weathering. Low-level human imprints are recognized in the ground water samples also.

  3. Geology and ground-water resources of Wichita and Greeley Counties, Kansas

    Science.gov (United States)

    Prescott, G.C.; Branch, J.R.; Wilson, W.W.

    1954-01-01

    supplies are obtained from wells. It is estimated that probably more than 2 billion gallons of water is pumped annually from wells in the area. Since 1947, ground-water recharge has been about equal to ground-water discharge.The use of ground water for irrigation has increased greatly since 1946 and indications are that many more wells may be drilled and pumped without dangerously lowering the water table. Approximately 11,000 to 12,000 acres were irrigated in 1951. A map showing the thickness of water-bearing materials indicates that although much of the area has enough water-bearing material to support irrigation wells, parts of Wichita and Greeley counties have little or none.The Ogallala is the principal water-bearing formation in the area. Small amounts of water may also be obtained locally from alluvial deposits and from cracks in the Niobrara formation. Two deep test wells to the Dakota formation have been drilled but, because of the poor quality of the water, have never been used.The ground water in Wichita and Greeley counties, though hard, is suitable for most purposes. Water from the Ogallala is generally high in fluoride and in some cases may be injurious to the teeth of children. Water from the Dakota, though soft, is unfit for irrigation because of a high content of sodium.The field data upon which most of this report is based are given in tables; they include records of 417 wells, chemical analyses of 31 samples of water, and logs of 57 test holes and wells.

  4. Use of a ground-water flow model with particle tracking to evaluate ground-water vulnerability, Clark County, Washington

    Science.gov (United States)

    Snyder, D.T.; Wilkinson, J.M.; Orzol, L.L.

    1996-01-01

    A ground-water flow model was used in conjunction with particle tracking to evaluate ground-water vulnerability in Clark County, Washington. Using the particle-tracking program, particles were placed in every cell of the flow model (about 60,000 particles) and tracked backwards in time and space upgradient along flow paths to their recharge points. A new computer program was developed that interfaces the results from a particle-tracking program with a geographic information system (GIS). The GIS was used to display and analyze the particle-tracking results. Ground-water vulnerability was evaluated by selecting parts of the ground-water flow system and combining the results with ancillary information stored in the GIS to determine recharge areas, characteristics of recharge areas, downgradient impact of land use at recharge areas, and age of ground water. Maps of the recharge areas for each hydrogeologic unit illustrate the presence of local, intermediate, or regional ground-water flow systems and emphasize the three-dimensional nature of the ground-water flow system in Clark County. Maps of the recharge points for each hydrogeologic unit were overlaid with maps depicting aquifer sensitivity as determined by DRASTIC (a measure of the pollution potential of ground water, based on the intrinsic characteristics of the near-surface unsaturated and saturated zones) and recharge from on-site waste-disposal systems. A large number of recharge areas were identified, particularly in southern Clark County, that have a high aquifer sensitivity, coincide with areas of recharge from on-site waste-disposal systems, or both. Using the GIS, the characteristics of the recharge areas were related to the downgradient parts of the ground-water system that will eventually receive flow that has recharged through these areas. The aquifer sensitivity, as indicated by DRASTIC, of the recharge areas for downgradient parts of the flow system was mapped for each hydrogeologic unit. A number of

  5. Ground-Water Quality Data in the Kern County Subbasin Study Unit, 2006 - Results from the California GAMA Program

    Science.gov (United States)

    Shelton, Jennifer L.; Pimentel, Isabel; Fram, Miranda S.; Belitz, Kenneth

    2008-01-01

    Ground-water quality in the approximately 3,000 square-mile Kern County Subbasin study unit (KERN) was investigated from January to March, 2006, as part of the Priority Basin Assessment Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Assessment project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The Kern County Subbasin study was designed to provide a spatially unbiased assessment of raw (untreated) ground-water quality within KERN, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 50 wells within the San Joaquin Valley portion of Kern County. Forty-seven of the wells were selected using a randomized grid-based method to provide a statistical representation of the ground-water resources within the study unit. Three additional wells were sampled to aid in the evaluation of changes in water chemistry along regional ground-water flow paths. The ground-water samples were analyzed for a large number of man-made organic constituents (volatile organic compounds [VOCs], pesticides, and pesticide degradates), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon) and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, and laboratory matrix spikes) were collected and analyzed at approximately 10 percent of

  6. Recommended Immunological Assays to Screen for Ricin-Containing Samples

    Directory of Open Access Journals (Sweden)

    Stéphanie Simon

    2015-11-01

    Full Text Available Ricin, a toxin from the plant Ricinus communis, is one of the most toxic biological agents known. Due to its availability, toxicity, ease of production and absence of curative treatments, ricin has been classified by the Centers for Disease Control and Prevention (CDC as category B biological weapon and it is scheduled as a List 1 compound in the Chemical Weapons Convention. An international proficiency test (PT was conducted to evaluate detection and quantification capabilities of 17 expert laboratories. In this exercise one goal was to analyse the laboratories’ capacity to detect and differentiate ricin and the less toxic, but highly homologuous protein R. communis agglutinin (RCA120. Six analytical strategies are presented in this paper based on immunological assays (four immunoenzymatic assays and two immunochromatographic tests. Using these immunological methods “dangerous” samples containing ricin and/or RCA120 were successfully identified. Based on different antibodies used the detection and quantification of ricin and RCA120 was successful. The ricin PT highlighted the performance of different immunological approaches that are exemplarily recommended for highly sensitive and precise quantification of ricin.

  7. SUPERFUND GROUND WATER ISSUE - ACCURACY OF DEPTH TO WATER MEASUREMENTS

    Science.gov (United States)

    Accuracy of depth to water measurements is an issue identified by the Forum as a concern of Superfund decision-makers as they attempt to determine directions of ground-water flow, areas of recharge of discharge, the hydraulic characteristics of aquifers, or the effects of manmade...

  8. Influence on shallow ground water by nitrogen in polluted river

    Institute of Scientific and Technical Information of China (English)

    LI Zhi-ping; CAO Lian-hai; CHEN Xiao-gang; SHEN Zhao-li; ZHONG Zuo-shen

    2008-01-01

    The main purpose of the research is to discuss the influence on ground water by NH4-N in polluted river and river bed. In the lab-scale experiment three kinds of natural sand were chosen as infiltration medium, and polluted rivers were simulated by domestic sewage, after 10-month sand column test it was found that NH4-N came to adsorption sa-turation on the 17th day in coarse sand and on the 130~140th day in medium sand, then had a higher effluent concentration because of desorption. It is concluded that NH4-N eas-ily moved to ground water. When the concentration of NH4-N in Liangshui River were 46.86, 26.95 mg/L, that in groundwater are less than 1.10 mg/L. It is found that Liangshui River have a little influence on groundwater because of bottom mud, thickness and char-acter of the infiltration medium under the river bed and seepage quantity of river water.Clean water leaching test states that after the silt is cleared away and clean water is poured, NH4-N in the penetration media under the polluted river is obviously carried into ground water, and ground water is polluted secondly.

  9. The Use Of Permeable Concrete For Ground Water Recharge

    Directory of Open Access Journals (Sweden)

    Akshay Tejankar

    2016-09-01

    Full Text Available In order to develop Smart Cities in India, we need to develop smart technologies and smart construction materials. Permeable concrete an innovative material is environment friendly and a smart material which can be used for construction of several structures. In India, the ground water table is decreasing at a faster rate due to reduction in ground water recharge. These days, the vegetation cover is replaced by infrastructure hence the water gets very less opportunity to infiltrate itself into the soil. If the permeable concrete which has a high porosity is used for the construction of pavements, walking tracks, parking lots, well lining, etc. then it can reduce the runoff from the site and help in the ground water recharge. Such type of smart materials will play an important role for Indian conditions where government is putting lot of efforts to implement ground water recharging techniques. During the research work, the runoff for a particular storm was calculated for a bitumen pavement on a sloping ground. Later after studying the various topographical features, the traffic intensity and the rainfall for that particular area, the concrete was designed and tested for the different proportion and thus the mix design for the permeable concrete was finalized based upon its permeability and strength characteristics. Later by using this permeable concrete the infiltration and runoff for the same storm was compared and studied. The research paper will thus give an account of the properties of permeable concrete where it can be used over an existing road.

  10. Water law, with special reference to ground water

    Science.gov (United States)

    McGuinness, C.L.

    1951-01-01

    This report was prepared in July 1950 at the request of the President's Water Resources Policy Commission. It followed the report entitled Water facts in relation to a national water-resources policy," which, in part, has been published as Geological Survey Circular 114 under the title "The water situation in the United States, with special reference to ground water.''

  11. Reduction of large-scale numerical ground water flow models

    NARCIS (Netherlands)

    Vermeulen, P.T.M.; Heemink, A.W.; Testroet, C.B.M.

    2002-01-01

    Numerical models are often used for simulating ground water flow. Written in state space form, the dimension of these models is of the order of the number of model cells and can be very high (> million). As a result, these models are computationally very demanding, especially if many different scena

  12. RESEARCH TO SUPPORT RESTORATION OF GROUND WATER CONTAMINATED WITH ARSENIC

    Science.gov (United States)

    A brief programmatic overview will be presented to highlight research and technical support efforts underway at the Ground Water and Ecosystems Restoration Division in Ada, Oklahoma. Details from a case study will be presented to emphasize the technical challenges encountered du...

  13. Ground water arsenic contamination: A local survey in India

    Directory of Open Access Journals (Sweden)

    Arun Kumar

    2016-01-01

    Conclusions: The present study concludes that in Simri village there is high contamination of arsenic in ground water in all the strips. Such a huge population is at very high risk leading the village on the verge of causing health hazards among them. Therefore, an immediate strategy is required to combat the present problem.

  14. (Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio)

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Bill

    1991-10-01

    In April 1990, Wright-Patterson Air Force Base (WPAFB), initiated an investigation to evaluate a potential Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) removal action to prevent, to the extent practicable, the offsite migration of contaminated ground water from WPAFB. WPAFB retained the services of the Environmental Management Operations (EMO) and its principle subcontractor, International Technology Corporation (IT) to complete Phase 1 of the environmental investigation of ground-water contamination at WPAFB. Phase 1 of the investigation involves the short-term evaluation and potential design for a program to remove ground-water contamination that appears to be migrating across the western boundary of Area C, and across the northern boundary of Area B along Springfield Pike. Primarily, Task 4 of Phase 1 focuses on collection of information at the Area C and Springfield Pike boundaries of WPAFB. This Sampling and Analysis Plan (SAP) has been prepared to assist in completion of the Task 4 field investigation and is comprised of the Quality Assurance Project Plan (QAPP) and the Field Sampling Plan (FSP).

  15. Hydrologic and biogeochemical controls of river subsurface solutes under agriculturally enhanced ground water flow

    Science.gov (United States)

    Wildman, R.A.; Domagalski, J.L.; Hering, J.G.

    2009-01-01

    The relative influences of hydrologic processes and biogeochemistry on the transport and retention of minor solutes were compared in the riverbed of the lower Merced River (California, USA). The subsurface of this reach receives ground water discharge and surface water infiltration due to an altered hydraulic setting resulting from agricultural irrigation. Filtered ground water samples were collected from 30 drive point locations in March, June, and October 2004. Hydrologic processes, described previously, were verified by observations of bromine concentrations; manganese was used to indicate redox conditions. The separate responses of the minor solutes strontium, barium, uranium, and phosphorus to these influences were examined. Correlation and principal component analyses indicate that hydrologic processes dominate the distribution of trace elements in the ground water. Redox conditions appear to be independent of hydrologic processes and account for most of the remaining data variability. With some variability, major processes are consistent in two sampling transects separated by 100 m. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  16. Ground-water resources in the vicinity of Cortland, Trumbull County, Ohio

    Science.gov (United States)

    Barton, G.J.; Wright, P.R.

    1997-01-01

    The city of Cortland lies on the southeast ern shoreline of the 12.3-square-mile Mosquito Creek Lake in Trumbull County, Ohio. Cortland relies upon public wells completed in the Cussewago Sandstone for potable water. The Cussewago Sandstone, the principal aquifer in the study area, is a subcrop of the glaciofluvial sediments in the lake; the unit dips gently towards the southeast. Thickness of the Cussewago Sandstone ranges from less than 20 feet in south-central Bazetta Township to 152 feet in Cortland. The Bedford Shale overlies and confines the Cussewago Sandstone and separates it hydraulically from the Berea Sandstone. The Bedford Shale and Berea Sandstone are not a prolific source of ground water. In places, the Bedford Shale was completely eroded away prior to deposition of the Berea Sandstone. Where the Bedford Shale is absent, such as at the City of Cortland North Well Field, the Berea Sandstone and Cussewago Sandstone are likely in hydraulic connection. Throughout most of the study area, the Cussewago Sandstone is a confined aquifer. Ground-water flow is to the east and southeast. Pumping at both Cortland well fields has created cones of depression in the potentiometric surface. These cones of depression cause a local reversal in ground-water flow immediately east of both well fields. The absence of detectable concentrations of tritium in water samples from wells completed in the Cussewago Sandstone at Cortland indicates that ground water predates the atmospheric nuclear testing of the 1950's. Ground water requires about 60 to 110 years to flow from the Cussewago Sandstone subcrop of the glaciofluvial sediments in the lake to the Cortland public-supply wells. A comparison of aquifer storage and pumpage in the study area shows that the Cussewago Sandstone receives adequate recharge to support current withdrawals by Cortland public-supply wells. In the immediate vicinity of Cortland- between Route 305 and the Bazetta-Mecca Town ship line and between the

  17. Hydrogeology, ground-water use, and ground-water levels in the Mill Creek Valley near Evendale, Ohio

    Science.gov (United States)

    Schalk, Charles; Schumann, Thomas

    2002-01-01

    Withdrawals of ground water in the central Mill Creek Valley near Evendale, Ohio, caused water-level declines of more than 100 feet by the 1950s. Since the 1950s, management practices have changed to reduce the withdrawals of ground water, and recovery of water levels in long-term monitoring wells in the valley has been documented. Changing conditions such as these prompted a survey of water use, streamflow conditions, and water levels in several aquifers in the central Mill Creek Valley, Hamilton and Butler Counties, Ohio. Geohydrologic information, water use, and water levels were compiled from historical records and collected during the regional survey. Data collected during the survey are presented in terms of updated geohydrologic information, water use in the study area, water levels in the aquifers, and interactions between ground water and surface water. Some of the data are concentrated at former Air Force Plant 36 (AFP36), which is collocated with the General Electric Aircraft Engines (GEAE) plant, and these data are used to describe geohydrology and water levels on a more local scale at and near the plant. A comparison of past and current ground-water use and levels indicates that the demand for ground water is decreasing and water levels are rising. Before 1955, most of the major industrial ground-water users had their own wells, ground water was mined from a confined surficial (lower) aquifer, and water levels were more than 100 feet below their predevelopment level. Since 1955, however, these users have been purchasing their water from the city of Cincinnati or a private water purveyor. The cities of Reading and Lockland, both producers of municipal ground-water supplies in the area, shut down their well fields within their city limits. Because the demand for ground-water supplies in the valley has lessened greatly since the 1950s, withdrawals have decreased, and, consequently, water levels in the lower aquifer are 65 to 105 feet higher than they were

  18. Ground-water quality in the carbonate-rock aquifer of the Great Basin, Nevada and Utah, 2003

    Science.gov (United States)

    Schaefer, Donald H.; Thiros, Susan A.; Rosen, Michael R.

    2005-01-01

    The carbonate-rock aquifer of the Great Basin is named for the thick sequence of Paleozoic limestone and dolomite with lesser amounts of shale, sandstone, and quartzite. It lies primarily in the eastern half of the Great Basin and includes areas of eastern Nevada and western Utah as well as the Death Valley area of California and small parts of Arizona and Idaho. The carbonate-rock aquifer is contained within the Basin and Range Principal Aquifer, one of 16 principal aquifers selected for study by the U.S. Geological Survey’s National Water- Quality Assessment Program.Water samples from 30 ground-water sites (20 in Nevada and 10 in Utah) were collected in the summer of 2003 and analyzed for major anions and cations, nutrients, trace elements, dissolved organic carbon, volatile organic compounds (VOCs), pesticides, radon, and microbiology. Water samples from selected sites also were analyzed for the isotopes oxygen-18, deuterium, and tritium to determine recharge sources and the occurrence of water recharged since the early 1950s.Primary drinking-water standards were exceeded for several inorganic constituents in 30 water samples from the carbonate-rock aquifer. The maximum contaminant level was exceeded for concentrations of dissolved antimony (6 μg/L) in one sample, arsenic (10 μg/L) in eleven samples, and thallium (2 μg/L) in one sample. Secondary drinking-water regulations were exceeded for several inorganic constituents in water samples: chloride (250 mg/L) in five samples, fluoride (2 mg/L) in two samples, iron (0.3 mg/L) in four samples, manganese (0.05 mg/L) in one sample, sulfate (250 mg/L) in three samples, and total dissolved solids (500 mg/L) in seven samples.Six different pesticides or metabolites were detected at very low concentrations in the 30 water samples. The lack of VOC detections in water sampled from most of the sites is evidence thatVOCs are not common in the carbonate-rock aquifer. Arsenic values for water range from 0.7 to 45.7

  19. Hydrogeology and ground-water quality of glacial-drift aquifers, Leech Lake Indian Reservation, north-central Minnesota

    Science.gov (United States)

    Lindgren, R.J.

    1996-01-01

    Among the duties of the water managers of the Leech Lake Indian Reservation in north-central Minnesota are the development and protection of the water resources of the Reservation. The U.S. Geological Survey, in cooperation with the Leech Lake Indian Reservation Business Committee, conducted a three and one half-year study (1988-91) of the ground-water resources of the Leech Lake Indian Reservation. The objectives of this study were to describe the availability and quality of ground water contained in glacial-drift aquifers underlying the Reservation.

  20. Ground-water conditions in the Dutch Flats area, Scotts Bluff and Sioux Counties, Nebraska, with a section on chemical quality of the ground water

    Science.gov (United States)

    Babcock, H.M.; Visher, F.N.; Durum, W.H.

    1951-01-01

    The U.S. Department of the Interior (DOI) studied contamination induced by irrigation drainage in 26 areas of the Western United States during 1986-95. Comprehensive compilation, synthesis, and evaluation of the data resulting from these studies were initiated by DOI in 1992. Soils and ground water in irrigated areas of the West can contain high concentrations of selenium because of (1) residual selenium from the soil's parent rock beneath irrigated land; (2) selenium derived from rocks in mountains upland from irrigated land by erosion and transport along local drainages, and (3) selenium brought into the area in surface water imported for irrigation. Application of irrigation water to seleniferous soils can dissolve and mobilize selenium and create hydraulic gradients that cause the discharge of seleniferous ground water into irrigation drains. Given a source of selenium, the magnitude of selenium contamination in drainage-affected aquatic ecosystems is strongly related to the aridity of the area and the presence of terminal lakes and ponds. Marine sedimentary rocks and deposits of Late Cretaceous or Tertiary age are generally seleniferous in the Western United States. Depending on their origin and history, some Tertiary continental sedimentary deposits also are seleniferous. Irrigation of areas associated with these rocks and deposits can result in concentrations of selenium in water that exceed criteria for the protection of freshwater aquatic life. Geologic and climatic data for the Western United States were evaluated and incorporated into a geographic information system (GIS) to produce a map identifying areas susceptible to irrigation-induced selenium contamination. Land is considered susceptible where a geologic source of selenium is in or near the area and where the evaporation rate is more than 2.5 times the precipitation rate. In the Western United States, about 160,000 square miles of land, which includes about 4,100 square miles (2.6 million acres) of

  1. Guide to ground water remediation at CERCLA response action and RCRA corrective action sites

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    This Guide contains the regulatory and policy requirements governing remediation of ground water contaminated with hazardous waste [including radioactive mixed waste (RMW)], hazardous substances, or pollutants/contaminants that present (or may present) an imminent and substantial danger. It was prepared by the Office of Environmental Policy and Assistance, RCRA/CERCLA Division (EH-413), to assist Environmental Program Managers (ERPMs) who often encounter contaminated ground water during the performance of either response actions under CERCLA or corrective actions under Subtitle C of RCRA. The Guide begins with coverage of the regulatory and technical issues that are encountered by ERPM`s after a CERCLA Preliminary Assessment/Site Investigation (PA/SI) or the RCRA Facility Assessment (RFA) have been completed and releases into the environment have been confirmed. It is based on the assumption that ground water contamination is present at the site, operable unit, solid waste management unit, or facility. The Guide`s scope concludes with completion of the final RAs/corrective measures and a determination by the appropriate regulatory agencies that no further response action is necessary.

  2. Reconnaissance of ground-water quality, eastern Snake River basin, Idaho

    Science.gov (United States)

    Parliman, D.J.

    1982-01-01

    Water-quality, geologic, and hydrologic data were collected for 165 wells in the eastern Snake River basin, Idaho. Water-quality characteristics analyzed include specific conductance, pH, water temperature, major dissolved cations and anions, and coliform bacteria. Ground water from aquifers in all rock units is generally composed of calcium, magnesium, and bicarbonate type and contains carbonate ions. Changes in area trends of ground-water composition probably are most directly related to variability in aquifer composition and proximity to varying sources of recharge, especially those related to man 's land- and water-use activities. In the uplands subareas, median values for selected ground-water characteristics from current analyses are 2000 mg/l hardness; 7.6, pH; 200 mg/l alkalinity; 13C; 0.2 mg/l fluoride; 15 mg/l silica; 0.51 mg/l nitrite (as nitrogen); less than 1 colony per 100 milliliters of water coliform bacteria; 0.02 mg/l phosphorus (total); and 25 mg/l hardness; 7.7, pH; 180 mg/l alkalinity; 11C; 0.4 mg/l fluoride; 26 mg/l silica; 1.2 mg/l nitrite plus nitrate; less than 1 colony per 100 milliliters of water coliform bacteria; 0.01 amg/l phosphorus; and 283 mg/l dissolved solids. Ground-water quality in most of the study area meets recommended standards or criteria for most uses. (USGS)

  3. Occurrence of selected radionuclides in ground water used for drinking water in the United States; a reconnaissance survey, 1998

    Science.gov (United States)

    Focazio, Michael J.; Szabo, Zoltan; Kraemer, Thomas F.; Mullin, Ann H.; Barringer, Thomas H.; dePaul, Vincent T.

    2001-01-01

    The U.S. Geological Survey, in collaboration with the U.S. Environmental Protection Agency, the American Water Works Association, and the American Water Works Service Company, completed a targeted national reconnaissance survey of selected radionuclides in public ground-water supplies. Radionuclides analyzed included radium-224 (Ra-224), radium-226 (Ra-226), radium-228 (Ra-228), polonium-210 (Po-210) and lead-210 (Pb-210).This U.S. Geological Survey reconnaissance survey focused intentionally on areas with known or suspected elevated concentrations of radium in ground water to determine if Ra-224 was also present in the areas where other isotopes of radium had previously been detected and to determine the co-occurrence characteristics of the three radium isotopes (Ra-224, Ra-226, and Ra-228) in those areas. Ninety-nine raw-water samples (before water treatment) were collected once over a 6-month period in 1998 and 1999 from wells (94 of which are used for public drinking water) in 27 States and 8 physiographic provinces. Twenty-one of the 99 samples exceeded the current U.S. Environmental Protection Agency drinking-water maximum contaminant level of 5 picocuries per liter (pCi/L) for combined radium (Ra-226 + Ra-228). Concentrations of Ra-224 were reported to exceed 1 pCi/L in 30 percent of the samples collected, with a maximum concentration of 73.6 pCi/L measured in water from a nontransient, noncommunity, public-supply well in Maryland. Radium-224 concentrations generally were higher than those of the other isotopes of radium. About 5 percent of the samples contained concentrations of Ra-224 greater than 10 pCi/L, whereas only 2 percent exceeded 10 pCi/L for either Ra-226 or Ra-228. Concentrations of Ra-226 greater than 1 pCi/L were reported in 33 percent of the samples, with a maximum concentration of 16.9 pCi/L measured in water from a public-supply well in Iowa. Concentrations of Ra-228 greater than 1 pCi/L were reported in 22 samples, with a maximum

  4. Ground-water temperature of the Wyoming quadrangle in central Delaware : with application to ground-water-source heat pumps

    Science.gov (United States)

    Hodges, Arthur L.

    1982-01-01

    Ground-water temperature was measured during a one-year period (1980-81) in 20 wells in the Wyoming Quadrangle in central Delaware. Data from thermistors set at fixed depths in two wells were collected twice each week, and vertical temperature profiles of the remaining 18 wells were made monthly. Ground-water temperature at 8 feet below land surface in well Jc55-1 ranged from 45.0 degrees F in February to 70.1 degrees F in September. Temperature at 35 feet below land surface in the same well reached a minimum of 56.0 degrees F in August, and a maximum of 57.8 degrees F in February. Average annual temperature of ground water at 25 feet below land surface in all wells ranged from 54.6 degrees F to 57.8 degrees F. Variations of average temperature probably reflect the presence or absence of forestation in the recharge areas of the wells. Ground-water-source heat pumps supplied with water from wells 30 or more feet below land surface will operate more efficiently in both heating and cooling modes than those supplied with water from shallower depths. (USGS)

  5. A Guide for Using the Transient Ground-Water Flow Model of the Death Valley Regional Ground-Water Flow System, Nevada and California

    Energy Technology Data Exchange (ETDEWEB)

    Joan B. Blainey; Claudia C. Faunt, and Mary C. Hill

    2006-05-16

    This report is a guide for executing numerical simulations with the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California using the U.S. Geological Survey modular finite-difference ground-water flow model, MODFLOW-2000. Model inputs, including observations of hydraulic head, discharge, and boundary flows, are summarized. Modification of the DVRFS transient ground-water model is discussed for two common uses of the Death Valley regional ground-water flow system model: predictive pumping scenarios that extend beyond the end of the model simulation period (1998), and model simulations with only steady-state conditions.

  6. Hydrogeologic setting, ground-water flow, and ground-water quality at the Lake Wheeler Road research station, 2001-03 : North Carolina Piedmont and Mountains Resource Evaluation Program

    Science.gov (United States)

    Chapman, Melinda J.; Bolich, Richard E.; Huffman, Brad A.

    2005-01-01

    variations in vertical gradients are apparent. Water-quality sampling and monitoring efforts were conducted to characterize the interaction of components of the ground-water system. Elevated nitrate concentrations as high as 22 milligrams per liter were detected in shallow ground water from the regolith at the study site. These elevated nitrate concentrations likely are related to land use, which includes agricultural practices that involve animal feeding operations and crop fertilization. Continuous ground-water-quality data indicate seasonal fluctuations in field water-quality properties, differences with respect to depth, and fluctuations during recharge events. Water-quality properties recorded in the regolith well following rainfall indicate the upwelling of deeper ground water in the discharge area, likely from ground water in the transition-zone fractures. Additionally, interaction with a surface-water boundary appears likely in the ground-water discharge area, as water levels in all three ground-water zones, including the deep bedrock, mimic the surface-water rise during rainfall.

  7. Ground-Water Quality Data in the San Francisco Bay Study Unit, 2007: Results from the California GAMA Program

    Science.gov (United States)

    Ray, Mary C.; Kulongoski, Justin T.; Belitz, Kenneth

    2009-01-01

    Ground-water quality in the approximately 620-square-mile San Francisco Bay study unit (SFBAY) was investigated from April through June 2007 as part of the Priority Basin project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of raw ground-water quality, as well as a statistically consistent basis for comparing water quality throughout California. Samples in SFBAY were collected from 79 wells in San Francisco, San Mateo, Santa Clara, Alameda, and Contra Costa Counties. Forty-three of the wells sampled were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Thirty-six wells were sampled to aid in evaluation of specific water-quality issues (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, trace elements, chloride and bromide isotopes, and uranium and strontium isotopes), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14 isotopes, and stable isotopes of hydrogen, oxygen, nitrogen, boron, and carbon), and dissolved noble gases (noble gases were analyzed in collaboration with Lawrence Livermore National Laboratory) also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blank samples

  8. Status Of Physico-Chemical Parameter Of Ground Water Of Gorakhpur City U.P. India

    Directory of Open Access Journals (Sweden)

    Priyanka Chaudhary

    2015-08-01

    Full Text Available ABSTRACT The ground water is most prime water which has multipurpose use ranging from drinking to industrial and agricultural uses. The continuously increase in the level of pollution of water is a serious problem. The city of Gorakhpur is not untouched with this serious issue .The pollution level of the major water sources in and around the city is increase rapidly. The main objective of the present study is to study the variation of ground water quality in Gorakhpur district by collecting 20 samples of water from hand pump from 20 locations well distributed with in Gorakhpur district were analyzed for different parameters such as pH electric conductivity chloride total free chlorine hardness fluoride nitrate iron Turbidity potassium. Groundwater is polluted from seepage pits refuse dumps septic tanks barnyards manures transport accident and different pollutant. Important sources of ground water pollution are sewage is dumped in shallow soak pits. It gives rise to cholera hepatitis dysenteries etc. especially in areas with high water table.

  9. Baseline risk assessment of ground water contamination at the uranium mill tailings site near Durango, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    1995-02-01

    This risk assessment evaluates the possibility of health and environmental risks from contaminated ground water at the uranium mill tailings site near Durango, Colorado. The former uranium processing site`s contaminated soil and material were removed and placed at a disposal site located in Body Canyon, Colorado, during 1986--1991 by the US Departments of Energy`s Uranium Mill Tailings Remedial Action (UMTRA) Project. Currently, the UMTRA Project is evaluating the nature and extent of ground water contamination at the site. This risk assessment follows an approach similar to that used by the US Environmental Protection Agency. The first step is to determine what site-related contaminants are found in ground water samples. The next step in the risk assessment is to determine how much of these contaminants people might ingest if they got their drinking water from a well on the site. In accordance with standard practice for this type of risk assessment, the highest contaminant concentrations from the most contaminated wells are used. The risk assessment then explains the possible health problems that could result from this amount of contamination.

  10. Ground-Water Conditions and Studies in the Brunswick-Glynn County Area, Georgia, 2007

    Science.gov (United States)

    Cherry, Gregory S.; Clarke, John S.

    2008-01-01

    The Upper Floridan aquifer is contaminated with saltwater in a 2-square-mile area of downtown Brunswick, Georgia. This contamination has limited the development of the ground-water supply in the Glynn County area. Hydrologic, geologic, and water-quality data are needed to effectively manage water resources. Since 1959, the U.S. Geological Survey has conducted a cooperative water-resources program with the City of Brunswick to monitor and assess the effect of ground-water development on saltwater contamination of the Floridan aquifer system. The potential development of alternative sources of water in the Brunswick and surficial aquifer systems also is an important consideration in coastal areas. During calendar year 2007, the cooperative water-resources monitoring program included continuous water-level recording of 13 wells completed in the Floridan, Brunswick, and surficial aquifer systems; collecting water levels from 22 wells to map the potentiometric surface of the Upper Floridan aquifer during July and August 2007; and collecting and analyzing water samples from 76 wells to map chloride concentrations in the Upper Floridan aquifer during July and August 2007. In addition, work was initiated to refine an existing ground-water flow model for evaluation of water-management scenarios.

  11. Integrationof Remote Sensing and Geographic information system in Ground Water Quality Assessment and Management

    Science.gov (United States)

    Shakak, N.

    2015-04-01

    Spatial variations in ground water quality in the Khartoum state, Sudan, have been studied using geographic information system (GIS) and remote sensing technique. Gegraphical informtion system a tool which is used for storing, analyzing and displaying spatial data is also used for investigating ground water quality information. Khartoum landsat mosac image aquired in 2013was used, Arc/Gis software applied to extract the boundary of the study area, the image was classified to create land use/land cover map. The land use map,geological and soil map are used for correlation between land use , geological formations, and soil types to understand the source of natural pollution that can lower the ground water quality. For this study, the global positioning system (GPS), used in the field to identify the borehole location in a three dimentional coordinate (Latitude, longitude, and altitude), water samples were collected from 156 borehole wells, and analyzed for physico-chemical parameters like electrical conductivity, Total dissolved solid,Chloride, Nitrate, Sodium, Magnisium, Calcium,and Flouride, using standard techniques in the laboratory and compared with the standards.The ground water quality maps of the entire study area have been prepared using spatial interpolation technique for all the above parameters.then the created maps used to visualize, analyze, and understand the relationship among the measured points. Mapping was coded for potable zones, non-potable zones in the study area, in terms of water quality sutability for drinking water and sutability for irrigation. In general satellite remote sensing in conjunction with geographical information system (GIS) offers great potential for water resource development and management.

  12. Ground-Water Recharge in Humid Areas of the United States--A Summary of Ground-Water Resources Program Studies, 2003-2006

    Science.gov (United States)

    Delin, Geoffrey N.; Risser, Dennis W.

    2007-01-01

    Increased demands on water resources by a growing population and recent droughts have raised awareness about the adequacy of ground-water resources in humid areas of the United States. The spatial and temporal variability of ground-water recharge are key factors that need to be quantified to determine the sustainability of ground-water resources. Ground-water recharge is defined herein as the entry into the saturated zone of water made available at the water-table surface, together with the associated flow away from the water table within the saturated zone (Freeze and Cherry, 1979). In response to the need for better estimates of ground-water recharge, the Ground-Water Resources Program (GWRP) of the U.S. Geological Survey (USGS) began an initiative in 2003 to estimate ground-water recharge rates in the relatively humid areas of the United States.

  13. Resource conservation and recovery act ground-water monitoring projects for Hanford facilities: Progress report, January 1--March 31, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R.M.; Bates, D.J.; Lundgren, R.E.

    1989-06-01

    This document describes the progress of 13 Hanford Site ground-water monitoring projects for the period January 1 to March 31, 1989. The work described in this document is conducted by the Pacific Northwest Laboratory under the management of Westinghouse Hanford Company for the US Department of Energy. Concentrations of ground-water constituents are compared to federal drinking water standards throughout this document for reference purposes. All drinking water supplied from the sampled aquifer meets regulatory standards for drinking water quality. 32 refs., 30 figs., 103 tabs.

  14. Ground-water resources in the Hood Basin, Oregon

    Science.gov (United States)

    Grady, Stephen J.

    1983-01-01

    The Hood Basin, an area of 1,035 square miles in north-central Oregon, includes the drainage basins of all tributaries of the Columbia River between Eagle Creek and Fifteenmile Creek. The physical characteristics and climate of the basin are diverse. The Wasco subarea, in the eastern half of the basin, has moderate relief, mostly intermittent streams, and semiarid climate. The Hood subarea, in the western half, has rugged topography, numerous perennial streams, and a humid climate.Water-bearing geologic units that underlie the basin include volcanic, volcaniclastic, and sedimentary rocks of Miocene to Holocene age, and unconsolidated surficial deposits of Pleistocene and Holocene age. The most important water-bearing unit, the Columbia River Basalt Group, underlies almost the entire basin. Total thickness probably exceeds 2,000 feet, but by 1980 only the upper 1,000 feet or less had been developed by wells. Wells in this unit generally yield from 15 to 1,000 gallons per minute and a few yield as much as 3,300 gallons per minute.The most productive aquifer in the Columbia River Basalt Group is The Dalles Ground Water Reservoir, a permeable zone of fractured basalt about 25 to 30 square miles in extent that underlies the city of The Dalles. During the late 1950's and mid-1960's, withdrawals of 15,000 acre-feet per year or more caused water levels in the aquifer to decline sharply. Pumpage had diminished to about 5,000 acre-feet per year in 1979 and water levels have stabilized, indicating that ground water recharge and discharge, including the pumping, are in balance.The other principal geologic units in the basin have more limited areal distribution and less saturated thickness than the Columbia River Basalt Group. Generally, these units are capable of yielding from a few to a hundred gallons per minute to wells.Most of the ground water in the basin is chemically suitable for domestic, irrigation, or other uses. Some ground water has objectionable concentrations of

  15. Linking ground-water age and chemistry data along flow paths: Implications for trends and transformations of nitrate and pesticides

    Science.gov (United States)

    Tesoriero, Anthony J.; Saad, David A.; Burow, Karen R.; Frick, Elizabeth A.; Puckett, Larry J.; Barbash, Jack E.

    2007-10-01

    Tracer-based ground-water ages, along with the concentrations of pesticides, nitrogen species, and other redox-active constituents, were used to evaluate the trends and transformations of agricultural chemicals along flow paths in diverse hydrogeologic settings. A range of conditions affecting the transformation of nitrate and pesticides (e.g., thickness of unsaturated zone, redox conditions) was examined at study sites in Georgia, North Carolina, Wisconsin, and California. Deethylatrazine (DEA), a transformation product of atrazine, was typically present at concentrations higher than those of atrazine at study sites with thick unsaturated zones but not at sites with thin unsaturated zones. Furthermore, the fraction of atrazine plus DEA that was present as DEA did not increase as a function of ground-water age. These findings suggest that atrazine degradation occurs primarily in the unsaturated zone with little or no degradation in the saturated zone. Similar observations were also made for metolachlor and alachlor. The fraction of the initial nitrate concentration found as excess N 2 (N 2 derived from denitrification) increased with ground-water age only at the North Carolina site, where oxic conditions were generally limited to the top 5 m of saturated thickness. Historical trends in fluxes to ground water were evaluated by relating the times of recharge of ground-water samples, estimated using chlorofluorocarbon concentrations, with concentrations of the parent compound at the time of recharge, estimated by summing the molar concentrations of the parent compound and its transformation products in the age-dated sample. Using this approach, nitrate concentrations were estimated to have increased markedly from 1960 to the present at all study sites. Trends in concentrations of atrazine, metolachlor, alachlor, and their degradates were related to the timing of introduction and use of these compounds. Degradates, and to a lesser extent parent compounds, were detected

  16. Statistical study to identify the key factors governing ground water recharge in the watersheds of the arid Central Asia.

    Science.gov (United States)

    Zhu, Binq-Qi; Wang, Yue-Ling

    2016-01-01

    Understanding the source and recharge of ground waters is of great significance to our knowledge in hydrological cycles in arid environments over the world. Northern Xinjiang in northwestern China is a significant repository of information relating to the hydrological evolution and climatic changes in central Asia. In this study, two multivariate statistical techniques, hierarchical cluster analysis (HCA) and principal component analysis (PCA), were used to assess the ground water recharge and its governing factors, with the principal idea of exploring the above techniques to utilize all available hydrogeochemical variables in the quality assessment, which are not considered in the conventional techniques like Stiff and Piper diagrams. Q-mode HCA and R-mode PCA were combined to partition the water samples into seven major water clusters (C1-C7) and three principal components (PC1-PC3, PC1 salinity, PC2 hydroclimate, PC3 contaminant). The water samples C1 + C4 were classified as recharge area waters (Ca-HCO3 water), C2 + C3 as transitional zone waters (Ca-Mg-HCO3-SO4 water), and C5 + C6 + C7 as discharge area waters (Na-SO4 water). Based on the Q-mode PCA scores, three groups of geochemical processes influencing recharge regimes were identified: geogenic (i.e., caused by natural geochemical processes), geomorphoclimatic (caused by topography and climate), and anthropogenic (caused by ground water contamination). It is proposed that differences in recharge mechanism and ground water evolution, and possible bedrock composition difference, are responsible for the chemical genesis of these waters. These will continue to influence the geochemistry of the northern Xinjiang drainage system for a long time due to its steady tectonics and arid climate. This study proved that the chemistry differentiation of ground water can effectively support the identification of ground water recharge and evolution patterns.

  17. Surface-Water, Water-Quality, and Ground-Water Assessment of the Municipio of Mayaguez, Puerto Rico, 1999-2002

    Science.gov (United States)

    Rodríguez-Martínez, Jesús; Santiago-Rivera, Luis; Guzman-Rios, Senen; Gómez-Gómez, Fernando; Oliveras-Feliciano, Mario L.

    2004-01-01

    five hydrogeologic terranes. This integrated database then was used to evaluate the ground-water potential of each hydrogeologic terrane. Lineament-trace analysis was used to help assess the ground-water development potential in the hydrogeologic terranes containing igneous rocks. Analyses suggest that areas with slopes greater than 15 degrees have relatively low ground-water development potential. The presence of fractures, independent of the topographic slope, may locally enhance the water-bearing properties in the hydrogeologic terranes containing igneous rocks. The results of this study indicate that induced streamflow generally is needed to sustain low to moderate ground-water withdrawal rates in the five hydrogeologic terranes. The ground-water flow systems in the hydrogeologic terranes are only able to sustain small withdrawal rates that rarely exceed 50 gallons per minute. Areas with a high density of fractures, as could be the case at the intersection of lineament traces in the upper parts of the Rio Ca?as and Rio Yaguez watersheds, are worthy of exploratory drilling for ground-water development.

  18. Land management impacts on dairy-derived dissolved organic carbon in ground water.

    Science.gov (United States)

    Chomycia, Jill C; Hernes, Peter J; Harter, Thomas; Bergamaschi, Brian A

    2008-01-01

    Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L(-1) in wells downgradient from wastewater ponds, 8 to 30 mg L(-1) in corral wells, 5 to 12 mg L(-1) in tile drains, and 4 to 15 mg L(-1) in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 microg L(-1), well in excess of the maximum contaminant level of 80 microg L(-1) established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation ( approximately 4 to approximately 8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow

  19. Land management impacts on dairy-derived dissolved organic carbon in ground water

    Science.gov (United States)

    Chomycia, J.C.; Hernes, P.J.; Harter, T.; Bergamaschi, B.A.

    2008-01-01

    Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L-1 in wells downgradient from wastewater ponds, 8 to 30 mg L-1 in corral wells, 5 to 12 mg L-1 in tile drains, and 4 to 15 mg L-1 in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 ??g L-1, well in excess of the maximum contaminant level of 80 ??g L-1 established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation (???4 to ???8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow ground water and hence should be considered

  20. CHEMICAL REACTIONS SIMULATED BY GROUND-WATER-QUALITY MODELS.

    Science.gov (United States)

    Grove, David B.; Stollenwerk, Kenneth G.

    1987-01-01

    Recent literature concerning the modeling of chemical reactions during transport in ground water is examined with emphasis on sorption reactions. The theory of transport and reactions in porous media has been well documented. Numerous equations have been developed from this theory, to provide both continuous and sequential or multistep models, with the water phase considered for both mobile and immobile phases. Chemical reactions can be either equilibrium or non-equilibrium, and can be quantified in linear or non-linear mathematical forms. Non-equilibrium reactions can be separated into kinetic and diffusional rate-limiting mechanisms. Solutions to the equations are available by either analytical expressions or numerical techniques. Saturated and unsaturated batch, column, and field studies are discussed with one-dimensional, laboratory-column experiments predominating. A summary table is presented that references the various kinds of models studied and their applications in predicting chemical concentrations in ground waters.

  1. Questa Baseline and Pre-Mining Ground-Water Quality Investigation. 17. Geomorphology of the Red River Valley, Taos County, New Mexico, and Influence on Ground-Water Flow in the Shallow Alluvial Aquifer

    Science.gov (United States)

    Vincent, Kirk R.

    2008-01-01

    In April 2001, the U.S. Geological Survey (USGS) and the New Mexico Environment Department (NMED) began a cooperative study to infer the pre-mining ground-water chemistry at the Molycorp molybdenum mine site in the Red River Valley of north-central New Mexico. This report is one in a series of reports that can be used to determine pre-mining ground-water conditions at the mine site. Molycorp?s Questa molybdenum mine in the Red River Valley, northern New Mexico, is located near the margin of the Questa caldera in a highly mineralized region. The bedrock of the Taos Range surrounding the Red River is composed of Proterozoic rocks of various types, which are intruded and overlain by Oligocene volcanic rocks associated with the Questa caldera. Locally, these rocks were altered by hydrothermal activity. The alteration zones that contain sulfide minerals are particularly important because they constitute the commercial ore bodies of the region and, where exposed to weathering, form sites of rapid erosion referred to as alteration scars. Over the past thousand years, if not over the entire Holocene, erosion rates were spatially variable. Forested hillslopes eroded at about 0.04 millimeter per year, whereas alteration scars eroded at about 2.7 millimeters per year. The erosion rate of the alteration scars is unusually rapid for naturally occurring sites that have not been disturbed by humans. Watersheds containing large alteration scars delivered more sediment to the Red River Valley than the Red River could remove. Consequently, large debris fans, as much as 80 meters thick, developed within the valley. The geomorphology of the Red River Valley has had several large influences on the hydrology of the shallow alluvial aquifer, and those influences were in effect before the onset of mining within the watershed. Several reaches where alluvial ground water emerges to become Red River streamflow were observed by a tracer dilution study conducted in 2001. The aquifer narrows

  2. Tritium/Helium-3 Apparent Ages of Shallow Ground Water, Portland Basin, Oregon, 1997-98

    Science.gov (United States)

    Hinkle, Stephen R.

    2009-01-01

    Water samples for tritium/helium-3 age dating were collected from 12 shallow monitoring wells in the Portland basin, Oregon, in 1997, and again in 1998. Robust tritium/helium-3 apparent (piston-flow) ages were obtained for water samples from 10 of the 12 wells; apparent ages ranged from 1.1 to 21.2 years. Method precision was demonstrated by close agreement between data collected in 1997 and 1998. Tritium/helium-3 apparent ages generally increase with increasing depth below the water table, and agree well with age/depth relations based on assumptions of effects of recharge rate on vertical ground-water movement.

  3. Sample container for neutron activation analysis. Probenbehaelter fuer die Neutronen-Aktivierungsanalyse

    Energy Technology Data Exchange (ETDEWEB)

    Lersmacher, B.; Verheijke, M.L.; Jaspers, H.J.

    1983-06-23

    The sample container avoids contaminating the sample substance by diffusion of foreign matter from the wall of the sample container into the sample. It cannot be activated, so that the results of measurements are not falsified by a radioactive container wall. It consists of solid carbon.

  4. Determining extreme parameter correlation in ground water models

    DEFF Research Database (Denmark)

    Hill, Mary Cole; Østerby, Ole

    2003-01-01

    In ground water flow system models with hydraulic-head observations but without significant imposed or observed flows, extreme parameter correlation generally exists. As a result, hydraulic conductivity and recharge parameters cannot be uniquely estimated. In complicated problems, such correlation...... correlation coefficients, but it required sensitivities that were one to two significant digits less accurate than those that required using parameter correlation coefficients; and (3) both the SVD and parameter correlation coefficients identified extremely correlated parameters better when the parameters...

  5. INVESTIGATIONS ON BIOCHEMICAL PURIFICATION OF GROUND WATER FROM HYDROGEN SULFIDE

    Directory of Open Access Journals (Sweden)

    Yu. P. Sedlukho

    2015-01-01

    Full Text Available The paper considers problems and features of biochemical removal of hydrogen sulfide from ground water. The analysis of existing methods for purification of ground water from hydrogen sulfide has been given in the paper. The paper has established shortcomings of physical and chemical purification of ground water. While using aeration methods for removal of hydrogen sulfide formation of colloidal sulfur that gives muddiness and opalescence to water occurs due to partial chemical air oxidation. In addition to this violation of sulfide-carbonate equilibrium taking place in the process of aeration due to desorption of H2S and CO2, often leads to clogging of degasifier nozzles with formed CaCO3 that causes serious operational problems. Chemical methods require relatively large flow of complex reagent facilities, storage facilities and transportation costs.In terms of hydrogen sulfide ground water purification the greatest interest is given to the biochemical method. Factors deterring widespread application of the biochemical method is its insufficient previous investigation and necessity to execute special research in order to determine optimal process parameters while purifying groundwater of a particular water supply source. Biochemical methods for oxidation of sulfur compounds are based on natural biological processes that ensure natural sulfur cycle. S. Vinogradsky has established a two-stage mechanism for oxidation of hydrogen sulfide with sulfur bacteria (Beggiatoa. The first stage presupposes oxidation of hydrogen sulphide to elemental sulfur which is accumulating in the cytoplasm in the form of globules. During the second stage sulfur bacteria begin to oxidize intracellular sulfur to sulfuric acid due to shortage of hydrogen sulfide.The paper provides the results of technological tests of large-scale pilot plants for biochemical purification of groundwater from hydrogen sulfide in semi-industrial conditions. Dependences of water quality

  6. Geology and ground-water resources of Richardson County, Nebraska

    Science.gov (United States)

    Emery, Philip A.

    1964-01-01

    Richardson County is in the extreme southeast corner of Nebraska. It has an area of 545 square miles, and in 1960 it had a population of 13,903. The county is in the physiographic region referred to as the Dissected Loess-covered Till Prairies. Major drainage consists of the Big Nemaha River, including its North and South Forks, and Muddy Creek. These streams flow southeastward and empty into the Missouri River, which forms the eastern boundary of the county. The climate of Richardson County is subhumid; the normal annual precipitation is about 35 inches. Agriculture is the chief industry, and corn is the principal crop. Pleistocene glacial drift, loess, and alluvial deposits mantle the bedrock except in the southern and southwestern parts of the county where the bedrock is at the surface. Ground water is obtained from glacial till, fluvioglacial material, terrace deposits, and coarse alluvial deposits, all of Pleistocene age--and some is obtained from bedrock aquifers of Pennsylvanian and Permian age. Adequate supplies of ground water are in many places difficult to locate because the water-bearing sands and gravels of Pleistocene age vary in composition and lack lateral persistence. Perched water tables are common in the upland areas and provide limited amounts of water to many of the shallow wells, Very few wells in bedrock yield adequate supplies, as the permeability of the rock is low and water that is more than a few tens of feet below the bedrock surface is highly mineralized. Recharge is primarily from local precipitation, and water levels in many wells respond rapidly to increased or decreased precipitation. The quality of the ground water is generally satisfactory for most uses, although all the water is hard, and iron and manganese concentrations, in some areas, are relatively high. Ground water is used mainly for domestic and stock purposes.

  7. Axially perpendicular offset Raman scheme for reproducible measurement of housed samples in a noncircular container under variation of container orientation.

    Science.gov (United States)

    Duy, Pham K; Chang, Kyeol; Sriphong, Lawan; Chung, Hoeil

    2015-03-17

    An axially perpendicular offset (APO) scheme that is able to directly acquire reproducible Raman spectra of samples contained in an oval container under variation of container orientation has been demonstrated. This scheme utilized an axially perpendicular geometry between the laser illumination and the Raman photon detection, namely, irradiation through a sidewall of the container and gathering of the Raman photon just beneath the container. In the case of either backscattering or transmission measurements, Raman sampling volumes for an internal sample vary when the orientation of an oval container changes; therefore, the Raman intensities of acquired spectra are inconsistent. The generated Raman photons traverse the same bottom of the container in the APO scheme; the Raman sampling volumes can be relatively more consistent under the same situation. For evaluation, the backscattering, transmission, and APO schemes were simultaneously employed to measure alcohol gel samples contained in an oval polypropylene container at five different orientations and then the accuracies of the determination of the alcohol concentrations were compared. The APO scheme provided the most reproducible spectra, yielding the best accuracy when the axial offset distance was 10 mm. Monte Carlo simulations were performed to study the characteristics of photon propagation in the APO scheme and to explain the origin of the optimal offset distance that was observed. In addition, the utility of the APO scheme was further demonstrated by analyzing samples in a circular glass container.

  8. Ground-Water Quality Data in the Central Eastside San Joaquin Basin 2006: Results from the California GAMA Program

    Science.gov (United States)

    Landon, Matthew K.; Belitz, Kenneth

    2008-01-01

    Ground-water quality in the approximately 1,695-square-mile Central Eastside study unit (CESJO) was investigated from March through June 2006 as part of the Statewide Basin Assessment Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The study was designed to provide a spatially unbiased assessment of raw ground-water quality within CESJO, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 78 wells in Merced and Stanislaus Counties. Fifty-eight of the 78 wells were selected using a randomized grid-based method to provide statistical representation of the study unit (grid wells). Twenty of the wells were selected to evaluate changes in water chemistry along selected lateral or vertical ground-water flow paths in the aquifer (flow-path wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), gasoline oxygenates and their degradates, pesticides and pesticide degradates], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), and 1,2,3-trichloropropane (1,2,3-TCP)], inorganic constituents that can occur naturally [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, carbon-14, and uranium isotopes and stable isotopes of hydrogen, oxygen, nitrogen, sulfur, and carbon], and dissolved noble and other gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected

  9. Apparent chlorofluorocarbon age of ground water of the shallow aquifer system, Naval Weapons Station Yorktown, Yorktown, Virginia

    Science.gov (United States)

    Nelms, David L.; Harlow, George E.; Brockman, Allen R.

    2001-01-01

    Apparent ages of ground water are useful in the analysis of various components of flow systems, and results of this analysis can be incorporated into investigations of potential pathways of contaminant transport. This report presents the results of a study in 1997 by the U.S. Geological Survey (USGS), in cooperation with the Naval Weapons Station Yorktown, Base Civil Engineer, Environmental Directorate, to describe the apparent age of ground water of the shallow aquifer system at the Station. Chlorofluorocarbons (CFCs), tritium (3H), dissolved gases, stable isotopes, and water-quality field properties were measured in samples from 14 wells and 16 springs on the Station in March 1997.Nitrogen-argon recharge temperatures range from 5.9°C to 17.3°C with a median temperature of 10.9°C, which indicates that ground-water recharge predominantly occurs in the cold months of the year. Concentrations of excess air vary depending upon geohydrologic setting (recharge and discharge areas). Apparent ground-water ages using a CFC-based dating technique range from 1 to 48 years with a median age of 10 years. The oldest apparent CFC ages occur in the upper parts of the Yorktown-Eastover aquifer, whereas the youngest apparent ages occur in the Columbia aquifer and the upper parts of the discharge area setting, especially springs. The vertical distribution of apparent CFC ages indicates that groundwater movement between aquifers is somewhat retarded by the leaky confining units, but the elapsed time is relatively short (generally less than 35 years), as evidenced by the presence of CFCs at depth. The identification of binary mixtures by CFC-based dating indicates that convergence of flow lines occurs not only at the actual point of discharge, but also in the subsurface.The CFC-based recharge dates are consistent with expected 3H concentrations measured in the water samples from the Station. The concentration of 3H in ground water ranges from below the USGS laboratory minimum

  10. Effects of highway-deicer application on ground-water quality in a part of the Calumet Aquifer, northwestern Indiana

    Science.gov (United States)

    Watson, Lee R.; Bayless, E. Randall; Buszka, Paul M.; Wilson, John T.

    2002-01-01

    in ground water were determined in samples collected during the spring and summer from wells open to the water table within about 9 feet of the highway. Chloride concentrations in ground water that were attributable to highway deicers also were found in tested wells about 400 feet downgradient from US?12 during the fall and winter and at greater depths than in wells closer to US?12. Chloride concentrations exceeded the U.S. Environmental Protection Agency?s (USEPA) secondary maximum contaminant level of 250 milligrams per liter for drinking water at seven wells downgradient from the highway during late winter, spring, and summer samplings. The chloride standard was exceeded only in water from wells with total depths that are less than about 10 feet below land surface. Sodium concentrations in water periodically exceeded the USEPA drinking-water equivalency level of 20 milligrams per liter in both the uppermost (deicer affected) and lower one-thirds of the aquifer. Sodium concentrations in ground water downgradient from US?12 and in the upper 5 feet of the aquifer also occasionally exceeded drinking-water standards for sodium (160 milligrams per liter) as set by the State of Florida and a standard for taste (200 milligrams per liter) as set by the World Health Organization. Dispersion was identified by analysis of aquifer-test data, isotopic dating of ground water, and water-quality data to be the process most responsible for reducing concentrations of highway deicers in the aquifer. Chemical analyses of the sand composing the aquifer indicated that cation exchange decreased the mass of deicer-related sodium in ground water, although the sand has a limited capacity to sustain the process. Automated daily measurements of specific conductance, correlated to chloride concentrations, indicated that some deicer is retained in the aquifer near the highway throughout the entire year and acts as a continuous chloride source for ground water. Peak concentrations of

  11. Self-contained cryogenic gas sampling apparatus and method

    Science.gov (United States)

    McManus, G.J.; Motes, B.G.; Bird, S.K.; Kotter, D.K.

    1996-03-26

    Apparatus for obtaining a whole gas sample, is composed of: a sample vessel having an inlet for receiving a gas sample; a controllable valve mounted for controllably opening and closing the inlet; a valve control coupled to the valve for opening and closing the valve at selected times; a portable power source connected for supplying operating power to the valve control; and a cryogenic coolant in thermal communication with the vessel for cooling the interior of the vessel to cryogenic temperatures. A method is described for obtaining an air sample using the apparatus described above, by: placing the apparatus at a location at which the sample is to be obtained; operating the valve control to open the valve at a selected time and close the valve at a selected subsequent time; and between the selected times maintaining the vessel at a cryogenic temperature by heat exchange with the coolant. 3 figs.

  12. Photodegradation of dimethenamid-P in deionised and ground water

    Directory of Open Access Journals (Sweden)

    Glavaški O.S.

    2016-01-01

    Full Text Available The study of photodegradation of dimethenamid-P herbicide was performed in deionised and ground water using TiO2 as a catalyst under UV light. The effect of electron acceptor (H2O2, scavenger of •OH radicals (C2H5OH and scavenger of holes (NaCl and Na2SO4 as well as solution pH was analyzed. The photodegradation of dimethenamid-P was followed by HPLC. The formation of transformation products was followed using high performance liquid chromatography-electrospray mass spectrometry. Ion chromatography and total organic carbon measurements were used for the determination of the mineralization level. HPLC analysis showed the almost complete removal of herbicide after 90 min in deionised and ground water, while total organic carbon analysis showed that dimethenamid-P was mineralized 64 and 50 % in deionised and ground water, respectively. The ion chromatography results showed that the mineralization process leads to the formation of chloride, sulphate and nitrate anions during the process. Transformation products were identified and the degradation mechanism was proposed. [Projekat Ministarstva nauke Republike Srbije, br. 172013

  13. Trace organic chemicals contamination in ground water recharge.

    Science.gov (United States)

    Díaz-Cruz, M Silvia; Barceló, Damià

    2008-06-01

    Population growth and unpredictable climate changes will pose high demands on water resources in the future. Even at present, surface water is certainly not enough to cope with the water requirement for agricultural, industrial, recreational and drinking purposes. In this context, the usage of ground water has become essential, therefore, their quality and quantity has to be carefully managed. Regarding quantity, artificial recharge can guarantee a sustainable level of ground water, whilst the strict quality control of the waters intended for recharge will minimize contamination of both the ground water and aquifer area. However, all water resources in the planet are threatened by multiple sources of contamination coming from the extended use of chemicals worldwide. In this respect, the environmental occurrence of organic micropollutants such as pesticides, pharmaceuticals, industrial chemicals and their metabolites has experienced fast growing interest. In this paper an overview of the priority and emerging organic micropollutants in the different source waters used for artificial aquifer recharge purposes and in the recovered water is presented. Besides, some considerations regarding fate and removal of such compounds are also addressed.

  14. Impacts of Irrigation and Drought on Salem Ground Water

    Directory of Open Access Journals (Sweden)

    T. Subramani

    2014-06-01

    Full Text Available This investigation is the first of three phases of a ground-water management study. In this report, effects of irrigation and drought on the ground-water resources of Salem are examined. Irrigation water use for five soil types is estimated from a monthly water budget model on the basis of precipitation and temperature data from the last 30 years at selected weather stations across Salem. Moisture deficits are computed for each soil type on the basis of the water requirements of a corn crop. It is assumed that irrigation is used to make up the moisture deficit in those places where irrigation systems already exist. Irrigation water use from each township with irrigated acreage is added to municipal and industrial ground-water use data and then compared to aquifer potential yields. The spatial analysis is accomplished with a statewide geographic information system. An important distinction is made between the seasonal effects of irrigation water use and the annual or long-term effects.

  15. User interface for ground-water modeling: Arcview extension

    Science.gov (United States)

    Tsou, M.-S.; Whittemore, D.O.

    2001-01-01

    Numerical simulation for ground-water modeling often involves handling large input and output data sets. A geographic information system (GIS) provides an integrated platform to manage, analyze, and display disparate data and can greatly facilitate modeling efforts in data compilation, model calibration, and display of model parameters and results. Furthermore, GIS can be used to generate information for decision making through spatial overlay and processing of model results. Arc View is the most widely used Windows-based GIS software that provides a robust user-friendly interface to facilitate data handling and display. An extension is an add-on program to Arc View that provides additional specialized functions. An Arc View interface for the ground-water flow and transport models MODFLOW and MT3D was built as an extension for facilitating modeling. The extension includes preprocessing of spatially distributed (point, line, and polygon) data for model input and postprocessing of model output. An object database is used for linking user dialogs and model input files. The Arc View interface utilizes the capabilities of the 3D Analyst extension. Models can be automatically calibrated through the Arc View interface by external linking to such programs as PEST. The efficient pre- and postprocessing capabilities and calibration link were demonstrated for ground-water modeling in southwest Kansas.

  16. A FIXED BED SORPTION SYSTEM FOR DEFLUORIDATION OF GROUND WATER

    Directory of Open Access Journals (Sweden)

    Ayoob Sulaiman

    2009-06-01

    Full Text Available The presence of excess fluoride in ground water has become a global threat with as many as 200 million people affected in more than 35 countries in all the continents. Of late, there have been significant advances in the knowledge base regarding the effects of excess fluoride on human health. As a result, defluoridation of ground water is regarded as one of the key areas of attention among the universal water community triggering global research. This study describes the sorptive responses of a newly developed adsorbent, alumina cement granules (ALC, in its real-life application in fixed beds, for removing fluoride from the ground waters of a rural Indian village. ALC exhibited almost consistent scavenging capacity at various bed depths in column studies with an enhanced adsorption potential of 0.818 mg/g at a flow rate of 4 ml/min. The Thomas model was examined to describe the sorption process. The process design parameters of the column were obtained by linear regression of the model. In all the conditions examined, the Thomas model could consistently predict its characteristic parameters and describe the breakthrough sorption profiles in the whole range of sorption process.

  17. Estimating the Ground Water Resources of Atoll Islands

    Directory of Open Access Journals (Sweden)

    Arne E. Olsen

    2010-01-01

    Full Text Available Ground water resources of atolls, already minimal due to the small surface area and low elevation of the islands, are also subject to recurring, and sometimes devastating, droughts. As ground water resources become the sole fresh water source when rain catchment supplies are exhausted, it is critical to assess current groundwater resources and predict their depletion during drought conditions. Several published models, both analytical and empirical, are available to estimate the steady-state freshwater lens thickness of small oceanic islands. None fully incorporates unique shallow geologic characteristics of atoll islands, and none incorporates time-dependent processes. In this paper, we provide a review of these models, and then present a simple algebraic model, derived from results of a comprehensive numerical modeling study of steady-state atoll island aquifer dynamics, to predict the ground water response to changes in recharge on atoll islands. The model provides an estimate thickness of the freshwater lens as a function of annual rainfall rate, island width, Thurber Discontinuity depth, upper aquifer hydraulic conductivity, presence or absence of a confining reef flat plate, and in the case of drought, time. Results compare favorably with published atoll island lens thickness observations. The algebraic model is incorporated into a spreadsheet interface for use by island water resources managers.

  18. UMTRA Ground Water Project management action process document

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A critical U.S. Department of Energy (DOE) mission is to plan, implement, and complete DOE Environmental Restoration (ER) programs at facilities that were operated by or in support of the former Atomic Energy Commission (AEC). These facilities include the 24 inactive processing sites the Uranium Mill Tailings Radiation Control Act (UMTRCA) (42 USC Section 7901 et seq.) identified as Title I sites, which had operated from the late 1940s through the 1970s. In UMTRCA, Congress acknowledged the potentially harmful health effects associated with uranium mill tailings and directed the DOE to stabilize, dispose of, and control the tailings in a safe and environmentally sound manner. The UMTRA Surface Project deals with buildings, tailings, and contaminated soils at the processing sites and any associated vicinity properties (VP). Surface remediation at the processing sites will be completed in 1997 when the Naturita, Colorado, site is scheduled to be finished. The UMTRA Ground Water Project was authorized in an amendment to the UMTRCA (42 USC Section 7922(a)), when Congress directed DOE to comply with U.S. Environmental Protection Agency (EPA) ground water standards. The UMTRA Ground Water Project addresses any contamination derived from the milling operation that is determined to be present at levels above the EPA standards.

  19. Final programmatic environmental impact statement for the uranium mill tailings remedial action ground water project. Volume I

    Energy Technology Data Exchange (ETDEWEB)

    None

    1996-10-01

    in accordance with the final standards. The EPA reserves the right to modify the ground water standards, if necessary, based on changes in EPA drinking water standards. Appendix A contains a copy of the 1983 EPA ground water compliance standards, the 1987 proposed changes to the standards, and the 1995 final rule. Under UMTRA, DOE is responsible for bringing the designated processing sites into compliance with the EPA ground water standards and complying with all other applicable standards and requirements. The U.S. Nuclear Regulatory Commission (NRC) must concur with DOE's actions. States are full participants in the process. The DOE also must consult with any affected Indian tribes and the Bureau of Indian Affairs. Uranium processing activities at most of the inactive mill sites resulted in the contamination of ground water beneath and, in some cases, downgradient of the sites. This contaminated ground water often has elevated levels of constituents such as but not limited to uranium and nitrates. The purpose of the UMTRA Ground Water Project is to eliminate or reduce to acceptable levels the potential health and environmental consequences of milling activities by meeting the EPA ground water standards.

  20. Preliminary report on geology and ground water of the Pajaro Valley area, Santa Cruz and Monterey counties, California

    Science.gov (United States)

    Muir, K.S.

    1972-01-01

    The Pajaro Valley area, California, covering about 120 square miles, extends from the southern part of Santa Cruz County to several miles south of the county line into Monterey County. It borders the Pacific Ocean on the west and the Santa Cruz Mountains on the east. The city of Watsonville is the largest center of population. Deposits that range in age from Pliocene to Holocene make up the ground-water reservoir. These include, from oldest to youngest, the Purisima Formation, Aromas Red Sands of Allen (1946), terrace deposits, alluvium, and dune sand. These deposits underlie an area of about 80 square miles and have a maximum thickness of about 4,000 feet. The alluvium yields most of the water pumped from wells in the area. Pre-Pliocene rocks underlie and form the boundaries of the ground-water reservoir. These rocks contain ground water in fractures and in sandstone beds. However, they are not an important source of ground water. There is close continuity between the geology of the Pajaro Valley area and that of the Soquel-Aptos area, which is contiguous on the north. Ground water in the Pajaro Valley area is derived from three sources: (1) Precipitation within the Pajaro Valley area that reaches the ground-water body by direct infiltration or by seepage from streams, (2) seepage from the Pajaro River as it crosses the Pajaro Valley carrying runoff which originates upstream from the valley, and (3) precipitation in the Soquel-Aptos area that infiltrates and then moves southeastward at depth into the Pajaro Valley area. Ground water in most wells in the Pajaro Valley area occurs under confined (artesian) conditions; the only exception is ground water in the upper, near-surface part of the alluvium and that in the dune sand. It moves south from the north part of the area and southwest away from the San Andreas fault toward and out under Monterey Bay. In the south part of the area, ground-water movement is almost due west. The San Andreas fault probably is the only

  1. Water-quality and ground-water-level trends, 1990-99, and data collected from 1995 through 1999, East Mountain area, Bernalillo County, central New Mexico

    Science.gov (United States)

    Rankin, D.R.

    2000-01-01

    Bernalillo County officials recognize the importance of monitoring water quality and ground-water levels in rapidly developing areas. For this reason, water-quality and ground-water- level data were collected from 87 wells, 3 springs, and the Ojo Grande Acequia in the east mountain area of Bernalillo County between January 1990 and June 1999. The water samples were analyzed for selected nutrient species; total organic carbon; major dissolved constituents; methylene blue active substances; and dissolved arsenic. Analytical results were used to compute hardness, sodium adsorption ratio, and dissolved solids. Specific conductance, pH, air and water temperature, alkalinity, and dissolved oxygen were measured in the field at the time of sample collection. Ground-water levels were measured at the time of sample collection. From January 1990 through June 1993, water-quality and ground- water-level data were collected monthly from an initial set of 20 wells; these data were published in a 1995 report. During 1995, water samples and ground-water-level data were collected and analyzed from the initial set of 20 wells and from an additional 31 wells, 2 springs, and the Ojo Grande Acequia; these data were published in a 1996 report. Additional water-quality and ground-water-level data have been collected from sites in the east mountain area: 34 wells and the acequia during 1997, 14 wells and 1 spring during 1998, and 6 wells during 1999. Water-quality and ground- water-level data collected in the east mountain area during 1995 through 1999 are presented in tables. In addition, temporal trends for ground-water levels, concentrations of total and dissolved nitrite plus nitrate, concentrations of dissolved chloride, and specific conductance are presented for 20 selected wells in water-quality and water- level hydrographs.

  2. Geospatial Database of Ground-Water Altitude and Depth-to-Ground-Water Data for Utah, 1971-2000

    Science.gov (United States)

    Buto, Susan G.; Jorgensen, Brent E.

    2007-01-01

    A geospatial database of ground-water-level altitude and depth-to-ground-water data for Utah was developed. Water-level contours from selected published reports were converted to digital Geographic Information System format and attributes describing the contours were added. Water-level altitude values were input to an inverse distance weighted interpolator to create a raster of interpolated water-level altitude for each report. The water-level altitude raster was subtracted from digital land-surface altitude data to obtain depth-to-water rasters for each study. Comparison of the interpolated rasters to actual water-level measurements shows that the interpolated water-level altitudes are well correlated with measured water-level altitudes from the same time period. The data can be downloaded and displayed in any Geographic Information System or can be explored by downloading a data package and map from the U.S. Geological Survey.

  3. Estimating nitrogen loading to ground water and assessing vulnerability to nitrate contamination in a large karstic springs Basin, Florida

    Science.gov (United States)

    Katz, B.G.; Sepulveda, A.A.; Verdi, R.J.

    2009-01-01

    A nitrogen (N) mass-balance budget was developed to assess the sources of N affecting increasing ground-water nitrate concentrations in the 960-km 2 karstic Ichetucknee Springs basin. This budget included direct measurements of N species in rainfall, ground water, and spring waters, along with estimates of N loading from fertilizers, septic tanks, animal wastes, and the land application of treated municipal wastewater and residual solids. Based on a range of N leaching estimates, N loads to ground water ranged from 262,000 to 1.3 million kg/year; and were similar to N export from the basin in spring waters (266,000 kg/year) when 80-90% N losses were assumed. Fertilizers applied to cropland, lawns, and pine stands contributed about 51% of the estimated total annual N load to ground water in the basin. Other sources contributed the following percentages of total N load to ground water: animal wastes, 27%; septic tanks, 12%; atmospheric deposition, 8%; and the land application of treated wastewater and biosolids, 2%. Due to below normal rainfall (97.3 cm) during the 12-month rainfall collection period, N inputs from rainfall likely were about 30% lower than estimates for normal annual rainfall (136 cm). Low N-isotope values for six spring waters (??15N-NO3 = 3.3 to 6.3???) and elevated potassium concentrations in ground water and spring waters were consistent with the large N contribution from fertilizers. Given ground-water residence times on the order of decades for spring waters, possible sinks for excess N inputs to the basin include N storage in the unsaturated zone and parts of the aquifer with relatively sluggish ground-water movement and denitrification. A geographical-based model of spatial loading from fertilizers indicated that areas most vulnerable to nitrate contamination were located in closed depressions containing sinkholes and other dissolution features in the southern half of the basin. ?? 2009 American Water Resources Association.

  4. Surface-water, water-quality, and ground-water assessment of the Municipio of Carolina, Puerto Rico, 1997-99

    Science.gov (United States)

    Rodríguez-Martínez, Jesús; Gómez-Gómez, Fernando; Santiago-Rivera, Luis; Oliveras-Feliciano, M. L.

    2001-01-01

    concentrations above the water-quality goal established by the Puerto Rico Environmental Quality Board (Junta de Calidad Ambiental de Puerto Rico) for inland surface waters. Sources of fecal contamination may include: illegal discharge of sewage to storm-water drains, malfunctioning sanitary sewer ejectors, clogged and leaking sewage pipes, septic tank leakage, unfenced livestock, and runoff from livestock pens. Long-term fecal coliform data at two sampling stations, Quebrada Blasina in Carolina and the Rio Grande de Loiza, downstream from the town of Trujillo Alto, indicate that the sanitary quality of Quebrada Blasina is and has generally been poor for more than a decade. The sanitary quality of the Rio Grande de Loiza has generally been in compliance with the water-quality goal standard fecal coliform concentrations established in July 1990 by the Puerto Rico Environmental Quality Board. Geologic, topographic, soil, hydrogeologic, and streamflow data were used to divide the municipio of Carolina into five hydrogeologic terranes. This integrated database was then used to evaluate the ground-water potential of each hydrogeologic terrane. Analysis suggests that areas with slopes greater than 15 degrees have relatively low ground-water development potential. Fractures may be locally important in enhancing the water-bearing properties in the hydrogeologic terranes containing igneous rocks. Potentiometric-surface elevations recorded in piezometers installed in the coastal area during this study were used to define ground-water flow directions in the hydrogeologic terranes composed of coastal plain clastic and limestone units. The resultant potentiometric map indicates that the coastal plain aquifer and streams in the lowland parts of the municipio of Carolina are hydraulically connected. The potentiometric map also indicates that ground-water discharge to the Rio Grande de Loiza, downstream from highway PR-3, has been enhanced by dredging of the streambed for

  5. Delineation of ground-water contamination using soil-gas analyses near Jackson, Tennessee

    Science.gov (United States)

    Lee, R.W.

    1991-01-01

    An investigation of the ground-water resources near Jackson, West Tennessee, was conducted during 1988-89. The study included determination of the occurrence of contaminants in the shallow aquifer using soil-gas analyses in the unsaturated zone. Between 1980 and 1988, an underground fuel-storage tank leaked about 3,000 gallons of unleaded fuel to the water table about 4 feet below land surface. A survey of soil gas using a gas chromatograph equipped with a photoionization detector showed concentrations of volatile organic compounds greater than IO, 000 parts per million near the leak These compounds were detected in an area about 240 feet long and 110 feet wide extending west from the point source. The chromatograms provided two distinct 'fingerprints' of volatile organic compounds. The first revealed the presence of benzene, toluene, andxylenes, which are constituents of unleaded fuel, in addition to other volatile compounds, in soil gas in the area near the leak The second did not reveal any detectable benzene, toluene, or xylenes in the soil-gas samples, but showed the presence of other unidentified volatile organic compounds in soil gas north of the storage tank. The distribution of total concentrations of volatile organic compounds in the unsaturated zone indicated that a second plume about 200 feet long and 90 feet wide was present about 100 feet north of the storage tank The second plume could have been the result of previous activities at this site during the 1950's or earlier. Activities at the site are believed to have included storage of solvents used at the nearby railyard and flushing of tanks containing tar onto a gravel-covered parking area. The delineation of these plumes has shown that soil-gas analyses can be a useful technique for identifying areas of contamination with volatile organic compounds in shallow water-table aquifers and may have broad applications in similar situations where the water table is relatively close to the surface.

  6. Application of nonlinear-regression methods to a ground-water flow model of the Albuquerque Basin, New Mexico

    Science.gov (United States)

    Tiedeman, C.R.; Kernodle, J.M.; McAda, D.P.

    1998-01-01

    flow from adjacent regions; irrigation and septic field seepage; and leakage through the Rio Grande, canal, and Cochiti Reservoir beds. Ground water is discharged from the basin by withdrawal; evapotranspiration; subsurface flow; and flow to the Rio Grande, canals, and drains. The transient, three-dimensional numerical model of ground-water flow to which nonlinear-regression methods were applied simulates flow in the Albuquerque Basin from 1900 to March 1995. Six different basin subsurface configurations are considered in the model. These configurations are designed to test the effects of (1) varying the simulated basin thickness, (2) including a hypothesized hydrogeologic unit with large hydraulic conductivity in the western part of the basin (the west basin high-K zone), and (3) substantially lowering the simulated hydraulic conductivity of a fault in the western part of the basin (the low-K fault zone). The model with each of the subsurface configurations was calibrated using a nonlinear least- squares regression technique. The calibration data set includes 802 hydraulic-head measurements that provide broad spatial and temporal coverage of basin conditions, and one measurement of net flow from the Rio Grande and drains to the ground-water system in the Albuquerque area. Data are weighted on the basis of estimates of the standard deviations of measurement errors. The 10 to 12 parameters to which the calibration data as a whole are generally most sensitive were estimated by nonlinear regression, whereas the remaining model parameter values were specified. Results of model calibration indicate that the optimal parameter estimates as a whole are most reasonable in calibrations of the model with with configurations 3 (which contains 1,600-ft-thick basin deposits and the west basin high-K zone), 4 (which contains 5,000-ft-thick basin de

  7. Baseline risk assessment of ground water contamination at the Uranium Mill Tailings Site in Lakeview, Oregon

    Energy Technology Data Exchange (ETDEWEB)

    1994-10-01

    This Baseline Risk Assessment of Ground Water Contamination at the Uranium Mill Tailings Site in Lake view, Oregon evaluates potential impacts to public health or the environment resulting from ground water contamination at the former uranium mill processing site.

  8. Subregions of the Death Valley regional ground-water flow system, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the subregions of the transient ground-water flow model of the Death Valley regional ground-water flow system (DVRFS). Subregions are...

  9. Depth to ground water contours of hydrographic area 153, Diamond Valley, Nevada

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of depth to ground water contours for hydrographic-area (HA) 153, Diamond Valley, Nevada. These data represent static ground-water levels...

  10. Digital data set describing ground-water regions with unconsolidated watercourses in the conterminous US

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set describes ground-water regions in the United States defined by the U.S. Geological Survey. These ground-water regions are useful for dividing the...

  11. Ground-water resources of the Lambayeque Valley, Department of Lambayeque, northern Peru

    Science.gov (United States)

    Schoff, Stuart L.; Sayan, M. Juan Luis

    1969-01-01

    Ground water in the Lambayeque Valley has been developed mainly for irrigation of sugarcane and rice. The locality is on the coastal plain of northern Peru, about 650 km (kilometers) northwest of Lima, the national capital. The area considered in this study is about 1,670 sq km (square kilometers) and is mainly on the alluvial fan of Rio Chancay and entirely in the Department of Lambayeque. Chiclayo, the departmental capital and largest city, has a population, of about 46,000. The climate is hot and virtually rainless. Agriculture is dependent on irrigation. The available water, whether in stream s or underground, is introduced from the Andean highlands by Rio Chancay. Rocks in the area range in age from Cretaceous, or possibly Jurassic, to Quaternary and in lithology from dense and hard igneous, sedimentary, and metamorphic rocks to unconsolidated sediments. The bedrock contains and yields water only in small quantities, if at all. The principal water-bearing strata are in the alluvium comprising the fan of Rio Chancay. Where ground water in the alluvium has been most intensively developed, the productive zone is within 20 m (meters) of the land surface and is composed approximately as follows: (1) relatively impermeable soil, clay, and clayey sand, 5 to 10 m thick, (2) permeable sand and gravel, 6 to 10 m thick, at places including one or more layers of clay, so that several water-bearing beds are distinguishable, and (3) relatively impermeable mixtures of clay, sand, and gravel extending below the bottom of wells. Unit 3 in the deepest test continued to 102 m. Unit 2 is the principal source of water tapped by irrigation wells. In the northern part of the area wells locally yield water rather freely from strata as deep as 73 m, but elsewhere in the area the strata deeper than 20 m are not very productive. Wells at and near Chiclayo yield only small amounts, and the deepest well disclosed, in 100 m of material, only 5.5 m of material that can be considered as

  12. Ground-water hydraulics - A summary of lectures presented by John G. Ferris at short courses conducted by the Ground Water Branch, part 1, Theory

    Science.gov (United States)

    Knowles, D.B.

    1955-01-01

    The objective of the Ground Water Branch is to evaluate the occurrence, availability, and quality of ground water.  The science of ground-water hydrology is applied toward attaining that goal.  Although many ground-water investigations are of a qualitative nature, quantitative studies are necessarily an integral component of the complete evaluation of occurrence and availability.  The worth of an aquifer as a fully developed source of water depends largely on two inherent characteristics: its ability to store, and its ability to transmit water.  Furthermore, quantitative knowledge of these characteristics facilitates measurement of hydrologic entities such as recharge, leakage, evapotranspiration, etc.  It is recognized that these two characteristics, referred to as the coefficients of storage and transmissibility, generally provide the very foundation on which quantitative studies are constructed.  Within the science of ground-water hydrology, ground-water hydraulics methods are applied to determine these constats from field data.

  13. Simulation of the Regional Ground-Water-Flow System and Ground-Water/Surface-Water Interaction in the Rock River Basin, Wisconsin

    Science.gov (United States)

    Juckem, Paul F.

    2009-01-01

    A regional, two-dimensional, areal ground-water-flow model was developed to simulate the ground-water-flow system and ground-water/surface-water interaction in the Rock River Basin. The model was developed by the U.S. Geological Survey (USGS), in cooperation with the Rock River Coalition. The objectives of the regional model were to improve understanding of the ground-water-flow system and to develop a tool suitable for evaluating the effects of potential regional water-management programs. The computer code GFLOW was used because of the ease with which the model can simulate ground-water/surface-water interactions, provide a framework for simulating regional ground-water-flow systems, and be refined in a stepwise fashion to incorporate new data and simulate ground-water-flow patterns at multiple scales. The ground-water-flow model described in this report simulates the major hydrogeologic features of the modeled area, including bedrock and surficial aquifers, ground-water/surface-water interactions, and ground-water withdrawals from high-capacity wells. The steady-state model treats the ground-water-flow system as a single layer with hydraulic conductivity and base elevation zones that reflect the distribution of lithologic groups above the Precambrian bedrock and a regionally significant confining unit, the Maquoketa Formation. In the eastern part of the Basin where the shale-rich Maquoketa Formation is present, deep ground-water flow in the sandstone aquifer below the Maquoketa Formation was not simulated directly, but flow into this aquifer was incorporated into the GFLOW model from previous work in southeastern Wisconsin. Recharge was constrained primarily by stream base-flow estimates and was applied uniformly within zones guided by regional infiltration estimates for soils. The model includes average ground-water withdrawals from 1997 to 2006 for municipal wells and from 1997 to 2005 for high-capacity irrigation, industrial, and commercial wells. In addition

  14. Grain Growth in Samples of Aluminum Containing Alumina Particles

    DEFF Research Database (Denmark)

    Tweed, C. J.; Hansen, Niels; Ralph, B.

    1983-01-01

    A study of the two-dimensional and three-dimensional grain size distributions before and after grain growth treatments has been made in samples having a range of oxide contents. In order to collect statistically useful amounts of data, an automatic image analyzer was used and the resulting data w...

  15. Chlorofluorocarbons, Sulfur Hexafluoride, and Dissolved Permanent Gases in Ground Water from Selected Sites In and Near the Idaho National Engineering and Environmental Laboratory, Idaho, 1994 - 1997

    Energy Technology Data Exchange (ETDEWEB)

    Busenberg, E.; Plummer, L.N.; Bartholomay, R.C.; Wayland, J.E.

    1998-08-01

    From July 1994 through May 1997, the U.S. Geological Survey, in cooperations with the Department of Energy, sampled 86 wells completed in the Snake River Plain aquifer at and near the Idaho National Engineering and Environmental Laboratory (INEEL). The wells were sampled for a variety of constituents including one- and two-carbon halocarbons. Concentrations of dichlorodifluoromethane (CFC-12), trichlorofluoromethane (CFC-11), and trichlorotrifluororoethane (CFC-113) were determined. The data will be used to evaluate the ages of ground waters at INEEL. The ages of the ground water will be used to determine recharge rates, residence time, and travel time of water in the Snake River Plain aquifer in and near INEEL. The chromatograms of 139 ground waters are presented showing a large number of halomethanes, haloethanes, and haloethenes present in the ground waters underlying the INEEL. The chromatograms can be used to qualitatively evaluate a large number of contaminants at parts per trillion to parts per billion concentrations. The data can be used to study temporal and spatial distribution of contaminants in the Snake River Plain aquifer. Representative compressed chromatograms for all ground waters sampled in this study are available on two 3.5-inch high density computer disks. The data and the program required to decompress the data can be obtained from the U.S. Geological Survey office at Idaho Falls, Idaho. Sulfur hexafluoride (SF6) concentrations were measured in selected wells to determine the feasibility of using this environmental tracer as an age dating tool of ground water. Concentrations of dissolved nitrogen, argon, carbon dioxide, oxygen, and methane were measured in 79 ground waters. Concentrations of dissolved permanent gases are tabulated and will be used to evaluate the temperature of recharge of ground water in and near the INEEL.

  16. Rapid analysis of small samples containing forskolin using monoclonal antibodies.

    Science.gov (United States)

    Yanagihara, H; Sakata, R; Shoyama, Y; Murakami, H

    1996-04-01

    The effective range of the competitive ELISA test for detection of forskolin content in clonally propagated plant organs of Coleus forskohlii using monoclonal antibodies extends from 5ng to 5 micrograms. A correlation between the forskolin accumulation and the growth rate was investigated using the clonally propagated shoots. An increase of forskolin content was noted, beginning at week 6. Flowers, rachises, leaves, stems, tuberous roots, and roots were analyzed. Tuberous roots and the stem base contained higher amounts of forskolin than other organs. The forskolin content in the stem decreased gradually towards the top of the shoot.

  17. Physical and hydrochemical evidence of lake leakage near Jim Woodruff lock and dam and ground-water inflow to Lake Seminole, and an assessment of karst features in and near the lake, southwestern Georgia and northwestern Florida

    Science.gov (United States)

    Torak, Lynn J.; Crilley, Dianna M.; Painter, Jaime A.

    2006-01-01

    a sinkhole located on the western floodplain of the river and is transmitted through the Upper Floridan aquifer, eventually discharging to the Apalachicola River at the River Boil. Acoustic Doppler current profiling yielded flow estimates from the River Boil in the range from about 140 to 220 cubic feet per second, which represents from about 1 to 3 percent of the average daily flow in the river. Binary mixing-model analysis using naturally occurring isotopes of oxygen and hydrogen (oxygen-18 and deuterium) indicates that discharge from the River Boil consists of a 13-to-1 ratio of lake water to ground water and that other sources of lake leakage and discharge to the boil probably exist. Analyses of major ions, nutrients, radon-222, and stable isotopes of hydrogen and oxygen contained in water samples collected from 29 wells, 7 lake locations, and 5 springs in the Lake Seminole area during 2000 indicate distinct chemical signatures for ground water and surface water. Ground-water samples contained higher concentrations of calcium and magnesium, and higher alkalinity and specific conductance than surface-water samples, which contained relatively high concentrations of total organic carbon and sulfate. Solute and isotopic tracers indicate that, from May to October 2000, springflow exhibited more ground-water qualities (high specific conductance, low dissolved oxygen, and low temperature) than surface water; however, the ratio of ground water to surface water of the springs was difficult to quantify from November to April because of reduced springflow and rapid mixing of springflow and lake water during sampling. The saturation index of calcite in surface-water samples indicates that while surface water is predominately undersaturated with regard to calcite year-round, a higher potential for dissolution of the limestone matrix exists from late fall through early spring than during summer. The relatively short residence time (5-7 hours) and rapid flow velocity

  18. Ground-Water Resource Assessment in the Rio Grande de Manati Alluvial Plain, Rio Arriba Saliente Area, Puerto Rico

    Science.gov (United States)

    Torres-Gonzalez, Sigfredo; Gómez-Gómez, Fernando; Warne, Andrew G.

    2002-01-01

    The alluvial aquifer within a 160-acre area of the Rio Grande de Manati alluvial plain was investigated to evaluate its potential as a water-supply source for the Barrios Rio Arriba Saliente and Pugnado Afuera, municipio of Manati, Puerto Rico. Analysis of well boring samples and the results of electric resistivity surveys indicate that the average thickness of the unconsolidated alluvial deposits in the study area is about 100 to 110 feet. The alluvium is a mixture of sand and gravel, which generally has a porosity of 0.2 to 0.35. Short-duration pump tests in small-diameter piezometers indicate that the alluvial aquifer has a hydraulic conductivity of about 200 feet per day and a transmissivity of about 7,900 feet squared per day. Analyses of water levels in piezometers, combined with stage measurements at a series of surveyed reference points along the Rio Grande de Manati channel, indicate that the water-table gradient in the alluvial aquifer is about 0.001, and that ground-water flow is generally from south to north, in the general direction of river flow. The water-table data indicate that the Rio Grande de Manati is the principal source of ground-water recharge to the alluvial aquifer in the study area. Because base flow for the Rio Grande de Manati is usually greater than 44 cubic feet per second, a continuous withdrawal rate of 0.5 to 1.0 cubic foot per second (225 to 450 gallons per minute) from a production well is possible. Chemical analysis of a ground-water sample indicates that the alluvial aquifer water meets U.S. Environmental Protection Agency secondary standards for selected constituents. Bacteriological analysis of ground-water samples indicates that the ground water contains little or no fecal coliform or fecal streptococcus bacteria. Although long-term data from upstream of the study area indicate high levels of fecal coliform and fecal streptococcus prior to 1996, bacteriological analyses of Rio Grande de Manati water samples obtained during

  19. Memorandum describing the geology and ground-water conditions in the vicinity of Simpsonville, Maryland

    Science.gov (United States)

    Otton, E.G.

    1955-01-01

    This memorandum summarizes briefly the result of a study of the ground-water conditions of a small area near Simpsonville, Maryland, underlain chiefly by the Guilford granite (granite-pegmatite) of early Paleozoic or late Precambrian age. The records. of 15 wells and 5 sprints are given, as are t he sample-study legs of 3 test wells drilled at the site of a planned industrial labratory. A geologic map revised some-what from a published map by Cloos and Broedel is included (fig. 1).

  20. Surface-water, water-quality, and ground-water assessment of the Municipio of Comerio, Puerto Rico, 1997-99

    Science.gov (United States)

    Rodríguez-Martínez, Jesús; Gómez-Gómez, Fernando; Santiago-Rivera, Luis; Oliveras-Feliciano, M. L.

    2001-01-01

    sewer ejectors, clogged and leaking sewage pipes, septic tank leakage, unfenced livestock, runoff from livestock pens, and seepage from pits containing animal wastes. Long-term fecal coliform data at two sampling stations on the Rio de la Plata indicate that since 1984, the geometric mean of five consecutive samples commonly has been at or below 2,000 colonies per 100 milliliters (established as the sanitary quality goal in Puerto Rico for Class SD type waters). At the sampling station upstream of Comerio, the geometric mean concentration has been near 500 colonies per 100 milliliters; downstream of the town of Comerio, the geometric mean concentration has been near 2,000 colonies per 100 milliliters concentration. The data at these stations also indicate that fecal coliform concentrations increase commonly above 2,000 colonies per 100 milliliters during storm-runoff events, ranging from 1,000 to 100,000 colonies per 100 milliliters at both stations. Geologic, topographic, soil, hydrogeologic, and streamflow data were used to divide the municipio of Comerio into five hydrogeologic terranes. The integrated database was then used to evaluate the ground-water development potential of each hydrogeologic terrane. Analysis suggests that areas with slopes greater than 15 degrees have relatively low ground-water development potential. Fractures may be important locally in enhancing the water-bearing properties in the hydrogeologic terranes containing igneous rocks. The integrated hydrogeologic approach used in this study can serve as an important tool for regulatory agencies of Puerto Rico and the municipio of Comerio to evaluate the ground-water resource development potential, examine ground- and surface-water interaction, and determine the effect of land-use practices on ground-water quantity and quality. Stream low-flow statistics document the general hydrology under current land and water uses. Low-flow characteristics may substantially change as a re

  1. 40 CFR 264.97 - General ground-water monitoring requirements.

    Science.gov (United States)

    2010-07-01

    ... FACILITIES Releases From Solid Waste Management Units § 264.97 General ground-water monitoring requirements. The owner or operator must comply with the following requirements for any ground-water monitoring... 40 Protection of Environment 25 2010-07-01 2010-07-01 false General ground-water...

  2. Used motor oil as a source of MTBE, TAME, and BTEX to ground water

    Science.gov (United States)

    Baker, R.J.; Best, E.W.; Baehr, A.L.

    2002-01-01

    Methyl tert-butyl ether (MTBE), the widely used gasoline oxygenate, has been identified as a common ground water contaminant, and BTEX compounds (benzene, toluene, ethylbenzene, and xylenes) have long been associated with gasoline spills. Because not all instances of ground water contamination by MTBE and BTEX can be attributed to spills or leaking storage tanks, other potential sources need to be considered. In this study, used motor oil was investigated as a potential source of these contaminants. MTBE in oil was measured directly by methanol extraction and gas chromatography using a flame ionization detector (GC/FID). Water was equilibrated with oil samples and analyzed for MTBE, BTEX, and the oxygenate tert-amyl methyl ether (TAME) by purge-and-trap concentration followed by GC/FID analysis. Raoult's law was used to calculate oil-phase concentrations of MTBE, BTEX, and TAME from aqueous-phase concentrations. MTBE, TAME, and BTEX were not detected in any of five new motor oil samples, whereas these compounds were found at significant concentrations in all six samples of the used motor oil tested for MTBE and all four samples tested for TAME and BTEX. MTBE concentrations in used motor oil were on the order of 100 mg/L. TAME concentrations ranged from 2.2 to 87 mg/L. Concentrations of benzene were 29 to 66 mg/L, but those of other BTEX compounds were higher, typically 500 to 2000 mg/L.

  3. Ground-water-quality data in Pennsylvania: A compilation of computerized [electronic] databases, 1979-2004

    Science.gov (United States)

    Low, Dennis J.; Chichester, Douglas C.

    2006-01-01

    This study, by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP), provides a compilation of ground-water-quality data for a 25-year period (January 1, 1979, through August 11, 2004) based on water samples from wells. The data are from eight source agencies唯orough of Carroll Valley, Chester County Health Department, Pennsylvania Department of Environmental Protection-Ambient and Fixed Station Network, Montgomery County Health Department, Pennsylvania Drinking Water Information System, Pennsylvania Department of Agriculture, Susquehanna River Basin Commission, and the U.S. Geological Survey. The ground-water-quality data from the different source agencies varied in type and number of analyses; however, the analyses are represented by 12 major analyte groups:biological (bacteria and viruses), fungicides, herbicides, insecticides, major ions, minor ions (including trace elements), nutrients (dominantly nitrate and nitrite as nitrogen), pesticides, radiochemicals (dominantly radon or radium), volatile organic compounds, wastewater compounds, and water characteristics (dominantly field pH, field specific conductance, and hardness).A summary map shows the areal distribution of wells with ground-water-quality data statewide and by major watersheds and source agency. Maps of 35 watersheds within Pennsylvania are used to display the areal distribution of water-quality information. Additional maps emphasize the areal distribution with respect to 13 major geolithologic units in Pennsylvania and concentration ranges of nitrate (as nitrogen). Summary data tables by source agency provide information on the number of wells and samples collected for each of the 35 watersheds and analyte groups. The number of wells sampled for ground-water-quality data varies considerably across Pennsylvania. Of the 8,012 wells sampled, the greatest concentration of wells are in the southeast (Berks, Bucks, Chester, Delaware

  4. Hydrogeology and ground-water resources of Ngatik Island, Sapwuahfik Atoll, State of Pohnpei, Federated States of Micronesia

    Science.gov (United States)

    Anthony, S.S.

    1996-01-01

    The lens of fresh ground water on Ngatik Island contains about 509 million gallons of potable water. Recharge to the freshwater lens is estimated to be 990,000 gallons per day on the basis of an estimated mean annual rainfall of 160 inches. The long-term average sustainable yield is estimated to be about 280,000 gallons per day. The estimated demand for water is about 30,000 gallons per day. Shallow-vertical-tube-wells or horizontal-infiltration wells could be used to develop the freshwater lens. The effect of development on the lens can be determined by monitoring the chloride concentration of water from a network of shallow-water-table wells and deep driven wells. The ground-water resource on Ngatik can be used in conjunction with individual rainwater-catchment systems: rainwater can be used for drinking and cooking and ground water can be used for sanitary purposes. When rainwater- catchment systems fail during extended dry periods, ground water would be available to meet the total demand.

  5. Hydrogeology and ground-water resources of Pingelap Island, Pingelap Atoll, State of Pohnpei, Federated States of Micronesia

    Science.gov (United States)

    Anthony, S.S.

    1996-01-01

    The lens of fresh ground water on Pingelap Island, Pingelap Atoll contains about 384 million gallons of potable water. Recharge to the freshwater lens is estimated to be 230,000 gallons per day on the basis of an average annual rainfall of 160 inches. The long-term average sustainable yield is estimated to be about 69,000 gallons per day. The estimated demand for water is about 50,000 gallons per day. Shallow-vertical-tube wells or horizontal-infiltration wells could be used to develop the freshwater lens. The effect of development on the lens can be determined by monitoring the chloride concentration of water from a network of shallow-water-table wells and deep driven wells. The ground-water resource on Pingelap can be used in conjunction with individual rainwater-catchment systems: rainwater can be used for drinking and cooking, and ground water can be used for sanitary uses. When rainwater-catchment systems fail during extended dry periods, ground water would be available to meet the total demand.

  6. Hydrogeology and ground-water resources of Kahlap Island, Mwoakilloa Atoll, State of Pohnpei, Federated States of Micronesia

    Science.gov (United States)

    Anthony, S.S.

    1996-01-01

    The lens of fresh ground water on Kahlap Island contains about 21.3 million gallons of potable water. Recharge to the freshwater lens is estimated to be 125,000 gallons per day on the basis of a mean annual rainfall of 120 inches. The long-term average sustainable yield is estimated to be about 17,300 gallons per day. The estimated demand for water is about 13,500 gallons per day. Shallow-vertical-tube wells or horizontal- infiltration wells could be used to develop the freshwater lens. The effect of development on the lens can be determined by monitoring the chloride concentration of water from a network of shallow- water-table and deep driven wells. The ground- water resource on Kahlap can be used in conjunc- tion with individual rainwater-catchment systems: rainwater can be used for drinking and cooking, and ground water can be used for sanitary uses. When rainwater-catchment systems fail during extended dry periods, ground water would be available to meet the total demand.

  7. Simulations of Ground-Water Flow and Particle Pathline Analysis in the Zone of Contribution of a Public-Supply Well in Modesto, Eastern San Joaquin Valley, California

    Science.gov (United States)

    Burow, Karen R.; Jurgens, Bryant C.; Kauffman, Leon J.; Phillips, Steven P.; Dalgish, Barbara A.; Shelton, Jennifer L.

    2008-01-01

    Shallow ground water in the eastern San Joaquin Valley is affected by high nitrate and uranium concentrations and frequent detections of pesticides and volatile organic compounds (VOC), as a result of ground-water development and intensive agricultural and urban land use. A single public-supply well was selected for intensive study to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Modesto area. A network of 23 monitoring wells was installed, and water and sediment samples were collected within the approximate zone of contribution of the public-supply well, to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state local ground-water-flow and transport model was developed to evaluate the age of ground water reaching the well and to evaluate the vulnerability of the well to nonpoint source input of nitrate and uranium. Particle tracking was used to compute pathlines and advective travel times in the ground-water flow model. The simulated ages of particles reaching the public-supply well ranged from 9 to 30,000 years, with a median of 54 years. The age of the ground water contributed to the public-supply well increased with depth below the water table. Measured nitrate concentrations, derived primarily from agricultural fertilizer, were highest (17 milligrams per liter) in shallow ground water and decreased with depth to background concentrations of less than 2 milligrams per liter in the deepest wells. Because the movement of water is predominantly downward as a result of ground-water development, and because geochemical conditions are generally oxic, high nitrate concentrations in shallow ground water are expected to continue moving downward without significant attenuation. Simulated long-term nitrate concentrations indicate that concentrations have peaked and will decrease in the public-supply well during the next 100 years

  8. Hydrogeology and simulation of ground-water flow at the Gettysburg Elevator Plant Superfund Site, Adams County, Pennsylvania

    Science.gov (United States)

    Low, Dennis J.; Goode, Daniel J.; Risser, Dennis W.

    2000-01-01

    to water can range from flowing at land surface to more than 71 feet below land surface. Potentiometric maps based on measured water levels at the Gettysburg Elevator Plant indicate ground water flows from west to east, towards Rock Creek. Multiple-well aquifer tests indicate the system is heterogeneous and flow is primarily in dipping beds that contain discrete secondary openings separated by less permeable beds. Water levels in wells open to the pumped bed, as projected along the dipping stratigraphy, are drawn down more than water levels in wells not open to the pumped bed. Ground-water flow was simulated for steady-state conditions prior to pumping and long-term average pumping conditions. The three-dimensional numerical flow model (MODFLOW) was calibrated by use of a parameter estimation program (MODFLOWP). Steady-state conditions were assumed for the calibration period of 1996. An effective areal recharge rate of 7 inches was used in model calibration. The calibrated flow model was used to evaluate the effectiveness of the current onsite and offsite extraction well system. The simulation results generally indicate that the extraction system effectively captures much of the ground-water recharge at the Gettysburg Elevator Plant and, hence, contaminated ground-water migrating from the site. Some of the extraction wells pump at low rates and have very small contributing areas. Results indicate some areal recharge onsite will move to offsite extraction wells.

  9. Selected Ground-Water-Quality Data in Pennsylvania - 1979-2006

    Science.gov (United States)

    Low, Dennis J.; Chichester, Douglas C.; Zarr, Linda F.

    2009-01-01

    This study, by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP), provides a compilation of ground-water-quality data for a 28-year period (January 1, 1979, through December 31, 2006) based on water samples from wells and springs. The data are from 14 source agencies or programs - Borough of Carroll Valley, Chester County Health Department, Montgomery County Health Department, Pennsylvania Department of Agriculture, Pennsylvania Department of Environmental Protection 2002 Pennsylvania Water-Quality Assessment, Pennsylvania Department of Environmental Protection Agency Act 537 Sewage Facilities Program, Pennsylvania Department of Environmental Protection-Ambient and Fixed Station Network, Pennsylvania Department of Environmental Protection-North-Central Region, Pennsylvania Department of Environmental Protection-South-Central Region, Pennsylvania Drinking Water Information System, Pennsylvania Topographic and Geologic Survey, Susquehanna River Basin Commission, U.S. Environmental Protection Agency, and the U.S. Geological Survey. The ground-water-quality data from the different source agencies or programs varied in type and number of analyses; however, the analyses are represented by 11 major analyte groups: antibiotics, major ions, microorganisms (bacteria, viruses, and other microorganisms), minor ions (including trace elements), nutrients (predominantly nitrate and nitrite as nitrogen), pesticides, pharmaceuticals, radiochemicals (predominantly radon or radium), volatiles (volatile organic compounds), wastewater compounds, and water characteristics (field measurements, predominantly field pH, field specific conductance, and hardness). For the USGS and the PADEP-North-Central Region, the pesticide analyte group was broken down into fungicides, herbicides, and insecticides. Summary maps show the areal distribution of wells and springs with ground-water-quality data statewide by source agency or

  10. Pan-European survey on the occurrence of selected polar organic persistent pollutants in ground water.

    Science.gov (United States)

    Loos, Robert; Locoro, Giovanni; Comero, Sara; Contini, Serafino; Schwesig, David; Werres, Friedrich; Balsaa, Peter; Gans, Oliver; Weiss, Stefan; Blaha, Ludek; Bolchi, Monica; Gawlik, Bernd Manfred

    2010-07-01

    This study provides the first pan-European reconnaissance of the occurrence of polar organic persistent pollutants in European ground water. In total, 164 individual ground-water samples from 23 European Countries were collected and analysed (among others) for 59 selected organic compounds, comprising pharmaceuticals, antibiotics, pesticides (and their transformation products), perfluorinated acids (PFAs), benzotriazoles, hormones, alkylphenolics (endocrine disrupters), Caffeine, Diethyltoluamide (DEET), and Triclosan. The most relevant compounds in terms of frequency of detection and maximum concentrations detected were DEET (84%; 454 ng/L), Caffeine (83%; 189 ng/L), PFOA (66%; 39 ng/L), Atrazine (56%; 253 ng/L), Desethylatrazine (55%; 487 ng/L), 1H-Benzotriazole (53%; 1032 ng/L), Methylbenzotriazole (52%; 516 ng/L), Desethylterbutylazine (49%; 266 ng/L), PFOS (48%, 135 ng/L), Simazine (43%; 127 ng/L), Carbamazepine (42%; 390 ng/L), nonylphenoxy acetic acid (NPE(1)C) (42%; 11 microg/L), Bisphenol A (40%; 2.3 microg/L), PFHxS (35%; 19 ng/L), Terbutylazine (34%; 716 ng/L), Bentazone (32%; 11 microg/L), Propazine (32%; 25 ng/L), PFHpA (30%; 21 ng/L), 2,4-Dinitrophenol (29%; 122 ng/L), Diuron (29%; 279 ng/L), and Sulfamethoxazole (24%; 38 ng/L). The chemicals which were detected most frequently above the European ground water quality standard for pesticides of 0.1 microg/L were Chloridazon-desphenyl (26 samples), NPE(1)C (20), Bisphenol A (12), Benzotriazole (8), N,N'-Dimethylsulfamid (DMS) (8), Desethylatrazine (6), Nonylphenol (6), Chloridazon-methyldesphenyl (6), Methylbenzotriazole (5), Carbamazepine (4), and Bentazone (4). However, only 1.7% of all single analytical measurements (in total 8000) were above this threshold value of 0.1 microg/L; 7.3% were > than 10 ng/L.

  11. Hydrology and simulation of ground-water flow in Kamas Valley, Summit County, Utah

    Science.gov (United States)

    Brooks, L.E.; Stolp, B.J.; Spangler, L.E.

    2003-01-01

    Kamas Valley, Utah, is located about 50 miles east of Salt Lake City and is undergoing residential development. The increasing number of wells and septic systems raised concerns of water managers and prompted this hydrologic study. About 350,000 acre-feet per year of surface water flows through Kamas Valley in the Weber River, Beaver Creek, and Provo River, which originate in the Uinta Mountains east of the study area. The ground-water system in this area consists of water in unconsolidated deposits and consolidated rock; water budgets indicate very little interaction between consolidated rock and unconsolidated deposits. Most recharge to consolidated rock occurs at higher altitudes in the mountains and discharges to streams and springs upgradient of Kamas Valley. About 38,000 acre-feet per year of water flows through the unconsolidated deposits in Kamas Valley. Most recharge is from irrigation and seepage from major streams; most discharge is to Beaver Creek in the middle part of the valley. Long-term water-level fluctuations range from about 3 to 17 feet. Seasonal fluctuations exceed 50 feet. Transmissivity varies over four orders of magnitude in both the unconsolidated deposits and consolidated rock and is typically 1,000 to 10,000 feet squared per day in unconsolidated deposits and 100 feet squared per day in consolidated rock as determined from specific capacity. Water samples collected from wells, streams, and springs had nitrate plus nitrite concentrations (as N) substantially less than 10 mg/L. Total and fecal coliform bacteria were detected in some surface-water samples and probably originate from livestock. Septic systems do not appear to be degrading water quality. A numerical ground-water flow model developed to test the conceptual understanding of the ground-water system adequately simulates water levels and flow in the unconsolidated deposits. Analyses of model fit and sensitivity were used to refine the conceptual and numerical models.

  12. Chemistry of ground water in the Silver Springs basin, Florida, with an emphasis on nitrate

    Science.gov (United States)

    Phelps, G.G.

    2004-01-01

    The Silver Springs group, in central Marion County, Florida, has a combined average discharge rate of 796 cubic feet per second and forms the headwaters of the Silver River. The springs support a diverse ecosystem and are an important cultural and economic resource. Concentrations of nitrite-plus-nitrate (nitrate-N) in water from the Main Spring increased from less than 0.5 milligrams per liter (mg/L) in the 1960s to about 1.0 mg/L in 2003. The Upper Floridan aquifer supplies the ground water to support spring discharge. This aquifer is at or near land surface in much of the ground-water basin; nutrients leached at land surface can easily percolate downward into the aquifer. Sources of nitrogen in ground water in the Silver Springs basin include atmospheric deposition, fertilizers used by agricultural and urban activities, and human and animal wastes. During 2000-2001, 56 wells in the area contributing recharge to Silver Springs were sampled for major ions, nutrients, and some trace constituents. Selected wells also were sampled for a suite of organic constituents commonly found in domestic and industrial wastewater and for the ratio of nitrogen isotopes (15N/14N) to better understand the sources of nitrate. Wells were selected to be representative of both confined and unconfined conditions of the Upper Floridan aquifer, as well as a variety of land-use types. Data from this study were compared to data collected from 25 wells in 1989-90. Concentrations of nitrate-N in ground water during this study ranged from less than the detection limit of 0.02 to 12 mg/L, with a median of 1.2 mg/L. For data from 1989-90, the range was from less than 0.02 to 3.6 mg/L, with a median of 1.04 mg/L. Water from wells in agricultural land-use areas had the highest median nitrate-N concentration (1.7 mg/L), although it is uncertain if the 12 mg/L maximum concentration was influenced by land-use activities or proximity to a septic tank. The median value for all urban land-use areas was

  13. Ground-water and surface-water quality data for the West Branch Canal Creek area, Aberdeen Proving Ground, Maryland

    Science.gov (United States)

    Spencer, Tracey A.; Phelan, Daniel J.; Olsen, Lisa D.; Lorah, Michelle M.

    2001-01-01

    This report presents ground-water and surface-water quality data from samples collected by the U.S. Geological Survey from November 1999 through May 2001 at West Branch Canal Creek, Aberdeen Proving Ground, Maryland. The report also provides a description of the sampling and analytical methods that were used to collect and analyze the samples, and includes an evaluation of the quality-assurance data. The ground-water sampling network included two 4-inch wells, two 2-inch wells, sixteen 1-inch piezometers, one hundred thirteen 0.75-inch piezometers, two 0.25-inch flexible-tubing piezo-meters, twenty-seven 0.25-inch piezometers, and forty-two multi-level monitoring system depths at six sites. Ground-water profiler samples were collected from nine sites at 34 depths. In addition, passive-diffusion-bag samplers were deployed at four sites, and porous-membrane sampling devices were installed in the upper sediment at five sites. Surface-water samples were collected from 20 sites. Samples were collected from wells and 0.75-inch piezometers for measurement of field parameters and reduction-oxidation constituents, and analysis of inorganic and organic constituents, during three sampling events in March?April and June?August 2000, and May 2001. Surface-water samples were collected from November 1999 through September 2000 during five sampling events for analysis of organic constituents. Ground-water profiler samples were collected in April?May 2000, and analyzed for field measure-ments, reduction-oxidation constituents, and inorganic constituents and organic constituents. Passive-diffusion-bag samplers were installed in September 2000, and samples were analyzed for organic constituents. Multi-level monitoring system samples were collected and analyzed for field measurements and reduction-oxidation con-stituents, inorganic constituents, and organic con-stituents in March?April and June?August 2000. Field measurements and organic constituents were collected from 0.25-inch

  14. Geology and ground-water resources in the Zebulon area, Georgia

    Science.gov (United States)

    Chapman, M.J.; Milby, B.J.; Peck, M.F.

    1993-01-01

    The current (1991) surface-water source of drinking-water supply for the city of Zebulon, Pike County, Georgia, no longer provides an adequate water supply and periodically does not meet water-quality standards. The hydrogeology of crystalline rocks in the Zebulon area was evaluated to assess the potential of ground-water resources as a supplemental or alternative source of water to present surface-water supplies. As part of the ground-water resource evaluation, well location and construction data were compiled, a geologic map was constructed, and ground water was sampled and analyzed. Three mappable geologic units delineated during this study provide a basic understanding of hydrogeologic settings in the Zebulon area. Rock types include a variety of aluminosilicate schists, granitic rocks, amphibolites/honblende gneisses, and gondites. Several geologic features that may enhance ground-water availability were identified in the study area. These features include contacts between contrasting rock types, where a high degree of differential weathering has occurred, and well-developed structural features, such as foliation and jointing are present. High-yielding wells (greater than 25 gallons per minute) and low-yielding wells (less than one gallon per minute) were located in all three geologic units in a variety of topographic settings. Well yields range from less than one gallon per minute to 250 gallons per minute. The variable total depths and wide ranges of casing depths of the high-yielding wells are indicative of variations in depths to water-bearing zones and regolith thicknesses, respectively. The depth of water-bearing zones is highly variable, even on a local scale. Analyses of ground-water samples indicate that the distribution of iron concentration is as variable as well yield in the study area and does not seem to be related to a particular rock type. Iron concentrations in ground-water samples ranged from 0.02 to 5.3 milligrams per liter. Both iron

  15. An adulticidal sticky ovitrap for sampling container-breeding mosquitoes.

    Science.gov (United States)

    Ritchie, Scott A; Long, Sharron; Hart, Alistair; Webb, Cameron E; Russell, Richard C

    2003-09-01

    The efficacy of a standard ovitrap and an ovitrap featuring an internal wall covered by a polybutylene adhesive was compared in field studies in Cairns, Australia. The sticky ovitrap was as effective as the standard ovitrap in detecting Aedes aegypti, with 67.5% and 64% of traps positive for Ae. aegypti, respectively. Significantly higher numbers of Ae. aegypti were collected by traps set outside rather than inside premises. Sticky ovitraps also readily collected Ochlerotatus notoscriptus and, especially, Culex quinquefasciatus. With a 10X hand lens, mosquitoes of these species could readily be identified in traps set for 3 and 7 days. The sticky ovitraps were comparable in cost and as time efficient as standard ovitraps. The greatest advantage of the sticky ovitrap is the collection of adult female mosquitoes, negating the need to rear larvae for identification and providing a faster, more direct measure of the effectiveness of ovipositional attractants than egg counts. Finally, we demonstrated that sticky ovitraps, being adulticidal, have potential as a supplementary control measure, especially for quarantine programs designed to prevent the import and export of container-breeding vector mosquitoes at sea- and airports.

  16. Ground-water quality and susceptibility of ground water to effects from domestic wastewater disposal in eastern Bernalillo County, central New Mexico, 1990-91

    Science.gov (United States)

    Blanchard, Paul J.; Kues, Georgianna E.

    1999-01-01

    Eastern Bernalillo County is a historically rural, mountainous area east of Albuquerque, New Mexico. Historically, the primary economic activity consisted of subsistence farming and ranching and support of these activities from small communities. During the last 40 to 50 years, however, the area increasingly has become the site of residential developments. Homes in these developments typically are on 1- to 2-acre lots and are serviced by individual wells and septic systems. Between 1970 and 1990, the population of the area increased from about 4,000 to more than 12,000, and housing units increased from about 1,500 to more than 5,000. Results of analysis of water samples collected from 121 wells throughout eastern Bernalillo County in 1990 indicated that (1) total-nitrate concentrations in 10 samples exceeded the U.S. Environmental Protection Agency national primary drinking-water regulation maximum contaminant level of 10 milligrams per liter as nitrogen; (2) total-nitrate concentrations may be related to the length of time an area has been undergoing development; and (3) large dissolved-chloride concentrations may result from geologic origins, such as interbedded salt deposits or upward movement of saline ground water along faults and fractures, as well as from domestic wastewater disposal. Ground water throughout eastern Bernalillo County was assessed to be highly susceptible to contamination by overlying domestic wastewater disposal because (1) soils in more than 95 percent of eastern Bernalillo County were determined by the U.S. Department of Agriculture Natural Resources Conservation Service to have severe limitations for use as septic-system absorption fields and (2) a fractured carbonate geologic terrane, which typically has large secondary permeability and limited sorption capacity, is at the surface or underlying unconsolidated material in 73 percent of the area. Ground-water-level rises following an episodal precipitation event during July 22-27, 1991

  17. Availability and chemical characteristics of ground water in central La Plata County, Colorado

    Science.gov (United States)

    Brogden, R.E.; Giles, T.F.

    1976-01-01

    The central part of La Plata County, Colo., has undergone rapid population growth in recent years. This growth has resulted in an increased demand for information for additional domestic, industrial, and municipal water supplies. A knowledge of the occurrence of ground water will permit a more efficient allocation of the resource. Aquifers in central La Plata County include: alluvium, Animas Formation of Quaternary and Tertiary age, Fruitland Formation, Pictured Cliffs Sandstone, three formations of the Mesa Verde Group, the Mancos Shale, Dakota Sandstone, Morrison Formation of Cretaceous and Jurassic age, and undifferentiated formations. Well yields generally are low, usually less than 25 gallons per minute. However, higher yields, 25 to 50 gallons per minute may be found locally in aquifers in the alluvium and the Animas Formation. The quality of water from the aquifers is dependent on rock type. Most of the water is a calcium bicarbonate type. However, aquifers that are predominantly fine-grained or contain interbeds of shale may contain sodium bicarbonate type water. The dissolution of minerals in the coal beds, which are present in the Mesa Verde Group and the Dakota Sandstone, can contribute high concentrations of iron, sulfate, and chloride to ground water. (Woodard-USGS)

  18. Historical trends in occurrence and atmospheric inputs of halogenated volatile organic compounds in untreated ground water used as a source of drinking water

    Science.gov (United States)

    Shapiro, S.D.; Busenberg, E.; Focazio, M.J.; Plummer, L.N.

    2004-01-01

    Analyses of samples of untreated ground water from 413 community-, non-community- (such as restaurants), and domestic-supply wells throughout the US were used to determine the frequency of detection of halogenated volatile organic compounds (VOCs) in drinking-water sources. The VOC data were compiled from archived chromatograms of samples analyzed originally for chlorofluorocarbons (CFCs) by purge-and-trap gas chromatography with an electron-capture detector (GC-ECD). Concentrations of the VOCs could not be ascertained because standards were not routinely analyzed for VOCs other than trichloromonofluoromethane (CFC-11), dichlorodifluoromethane (CFC-12) and 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113). Nevertheless, the peak areas associated with the elution times of other VOCs on the chromatograms can be classified qualitatively to assess concentrations at a detection limit on the order of parts per quadrillion. Three or more VOCs were detected in 100% (percent) of the chromatograms, and 77.2% of the samples contained 10 or more VOCs. The maximum number of VOCs detected in any sample was 24. Modeled ground-water residence times, determined from concentrations of CFC-12, were used to assess historical trends in the cumulative occurrence of all VOCs detected in this analysis, as well as the occurrence of individual VOCs, such as CFC-11, carbon tetrachloride (CCl4), chloroform and tetrachloroethene (PCE). The detection frequency for all of the VOCs detected has remained relatively constant from approximately 1940 to 2000; however, the magnitude of the peak areas on the chromatograms for the VOCs in the water samples has increased from 1940 to 2000. For CFC-11, CCl4, chloroform and PCE, small peaks decrease from 1940 to 2000, and large peaks increase from 1940 to 2000. The increase in peak areas on the chromatograms from analyses of more recently recharged water is consistent with reported increases in atmospheric concentrations of the VOCs. Approximately 44% and 6

  19. Geology and ground-water conditions in the Wilmington-Reading area, Massachusetts

    Science.gov (United States)

    Baker, John Augustus; Healy, H.G.; Hackett, O.M.

    1964-01-01

    The Wilmington-Reading area, as defined for this report, contains the headwaters of the Ipswich River in northeastern Massachusetts. Since World War II the growth of communities in this area and the change in character of some of them from rural to suburban have created new water problems and intensified old ones. The purpose of this report on ground-water conditions is to provide information that will aid in understanding and resolving some of these problems. The regional climate, which is humid and temperate, assures the area an ample natural supply of water. At the current stage of water-resources development a large surplus of water drains from the area by way of the Ipswich River during late autumn, winter, and spring each year and is unavailable for use during summer and early autumn, when during some years there is a general water deficiency. Ground water occurs both in bedrock and in the overlying deposits of glacial drift. The bedrock is a source of small but generally reliable supplies of water throughout the area. Glacial till also is a source of small supplies of water, but wells in till often fail to meet modern demands. Stratified glacial drift, including ice-contact deposits and outwash, yields small to large supplies of water. Stratified glacial drift forms the principal ground-water reservoir. It partly fills a system of preglacial valleys corresponding roughly to the valleys of the present Ipswich River system and is more than 100 feet thick at places. The ice-contact deposits generally are more permeable than the outwash deposits. Ground water occurs basically under water-table conditions. Recharge in the Wilmington-Reading area is derived principally from precipitation on outcrop areas of ice-contact deposits and outwash during late autumn, winter. and spring. It is estimated that the net annual recharge averages about 10 inches and generally ranges from 5 inches during unusually dry years to 15 inches during unusually wet years. Ground water

  20. Work plan for preliminary investigation of organic constituents in ground water at the New Rifle site, Rifle, Colorado. Revision 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-01-01

    A special study screening for Appendix 9 (40 CFR Part 264) analytes identified the New Rifle site as a target for additional screening for organic constituents. Because of this recommendation and the findings in a recent independent technical review, the US Department of Energy (DOE) has requested that the Technical Assistance Contractor (TAC) perform a preliminary investigation of the potential presence of organic compounds in the ground water at the New Rifle Uranium Mill Tailings Remedial Action (UMTRA) Project site, Rifle, Colorado. From 1958 to 1972, organic chemicals were used in large quantities during ore processing at the New Rifle site, and it is possible that some fraction was released to the environment. Therefore, the primary objective of this investigation is to determine whether organic chemicals used at the milling facility are present in the ground water. The purpose of this document is to describe the work that will be performed and the procedures that will be followed during installation of ground water well points at the New Rifle site. The selection of analytes and the procedures for collecting ground water samples for analysis of organic constituents are also described.

  1. Probabilistic Modeling for Risk Assessment of California Ground Water Contamination by Pesticides

    Science.gov (United States)

    Clayton, M.; Troiano, J.; Spurlock, F.

    2007-12-01

    The California Department of Pesticide Regulation (DPR) is responsible for the registration of pesticides in California. DPR's Environmental Monitoring Branch evaluates the potential for pesticide active ingredients to move to ground water under legal agricultural use conditions. Previous evaluations were primarily based on threshold values for specific persistence and mobility properties of pesticides as prescribed in the California Pesticide Contamination Prevention Act of 1985. Two limitations identified with that process were the univariate nature where interactions of the properties were not accounted for, and the inability to accommodate multiple values of a physical-chemical property. We addressed these limitations by developing a probabilistic modeling method based on prediction of potential well water concentrations. A mechanistic pesticide transport model, LEACHM, is used to simulate sorption, degradation and transport of a candidate pesticide through the root zone. A second empirical model component then simulates pesticide degradation and transport through the vadose zone to a receiving ground water aquifer. Finally, degradation during transport in the aquifer to the well screen is included in calculating final potential well concentrations. Using Monte Carlo techniques, numerous LEACHM simulations are conducted using random samples of the organic carbon normalized soil adsorption coefficients (Koc) and soil dissipation half-life values derived from terrestrial field dissipation (TFD) studies. Koc and TFD values are obtained from gamma distributions fitted to pooled data from agricultural-use pesticides detected in California ground water: atrazine, simazine, diuron, bromacil, hexazinone, and norflurazon. The distribution of predicted well water concentrations for these pesticides is in good agreement with concentrations measured in domestic wells in coarse, leaching vulnerable soils of Fresno and Tulure Counties. The leaching potential of a new

  2. ENVIRONMENTAL SAFETY IMPROVEMENT OF SURFACE AND GROUND WATER CONTAMINATION AT THE AIRPORT AREA

    Directory of Open Access Journals (Sweden)

    Svitlana Madzhd

    2016-11-01

    Full Text Available Purpose: Taking into account that the airport "Kyiv" is located in one of the central districts of Kyiv and does not have clearly established sanitary protection zones, the problem of environmental pollution is topical and requires monitoring and research. In order to improve environmental compliance we made assessment of superficial and ground water quality in airport zone. Methods: Water quality was estimated by the biotesting method, hydrochemical analysis, and by oil products detection method. Results We performed analysis of wastewaters of airport “Kyiv” and superficial waters of river Nyvka. The samples took place: above the airport drainage, in the drainage place and below drainage place. We conducted assessment of ground waters, which are sources of water supply, on different distance from an airport (20 m, 500 m, 1000 m, 1500 min. Results of hydrochemical investigations of river indicated excess of nitrogen compounds content compare to regulatory discharge. Thus, it was defined excess of ammonia nitrogen in wastewaters in three times and in place of dispersion – in ten times; the content of nitrite nitrogen in the river sample after discharge exceeds in 22 times norm. Analysis of drinking water in airport zone has showed extremely high level of pollution by nitrite nitrogen exceeding norm in 7-17 times. After analysis it was defined high level of river pollution by oil products (in 26-32 times higher than MPC, and ground water in 1, 5-2 times. Results of biotesting confirmed data of hydrochemical investigations of superficial water state (acute toxicity was observed in drainage area and in place of drainage dispersion. Discussion: Increased content of nitrite indicates the strengthening of decomposition process of organic matter in conditions of slower oxidation of NO into NO. This parameter is major sanitary indicator which indicates pollution of water body. High content of such specific pollutant for aviation transport

  3. Long-term ground-water monitoring program and performance-evaluation plan for the extraction system at the former Nike Missile Battery Site, Aberdeen Proving Ground, Maryland

    Science.gov (United States)

    Senus, Michael P.; Tenbus, Frederick J.

    2000-01-01

    This report presents lithologic and ground-water-quality data collected during April and May 2000 in the remote areas of the tidal wetland of West Branch Canal Creek, Aberdeen Proving Ground, Maryland. Contamination of the Canal Creek aquifer with volatile organic compounds has been documented in previous investigations of the area. This study was conducted to investigate areas that were previously inaccessible because of deep mud and shallow water, and to support ongoing investigations of the fate and transport of volatile organic compounds in the Canal Creek aquifer. A unique vibracore drill rig mounted on a hovercraft was used for drilling and ground-water sampling. Continuous cores of the wetland sediment and of the Canal Creek aquifer were collected at five sites. Attempts to sample ground water were made by use of a continuous profiler at 12 sites, without well installation, at a total of 81 depths within the aquifer. Of those 81 attempts, only 34 sampling depths produced enough water to collect samples. Ground-water samples from two sites had the highest concentrations of volatile organic compounds?with total volatile organic compound concentrations in the upper part of the aquifer ranging from about 15,000 to 50,000 micrograms per liter. Ground-water samples from five sites had much lower total volatile organic compound concentrations (95 to 2,100 micrograms per liter), whereas two sites were essentially not contaminated, with total volatile organic compound concentrations less than or equal to 5 micrograms per liter.

  4. Potential risk of microplastics transportation into ground water

    Science.gov (United States)

    Huerta, Esperanza; Gertsen, Hennie; Gooren, Harm; Peters, Piet; Salánki, Tamás; van der Ploeg, Martine; Besseling, Ellen; Koelmans, Albert A.; Geissen, Violette

    2016-04-01

    Microplastics, are plastics particles with a size smaller than 5mm. They are formed by the fragmentation of plastic wastes. They are present in the air, soil and water. But only in aquatic systems (ocean and rivers) are studies over their distribution, and the effect of microplastics on organisms. There is a lack of information of what is the distribution of microplastics in the soil, and in the ground water. This study tries to estimate the potential risk of microplastics transportation into the ground water by the activity of earthworms. Earthworms can produce burrows and/or galleries inside the soil, with the presence of earthworms some ecosystem services are enhanced, as infiltration. In this study we observed after 14 days with 5 treatments (0, 7, 28 and 60% w/w microplastics mixed with Populus nigra litter) and the anecic earthworm Lumbricus terrestris, in microcosms (3 replicas per treatment) that macroplastics are indeed deposit inside earthworms burrows, with 7% microplastics on the surface is possible to find 1.8 g.kg-1 microplastics inside the burrows, with a bioaumentation factor of 0.65. Burrows made by earthworms under 60% microplastics, are significant bigger (pmicroplastics in their soil surface. The amount of litter that is deposit inside the burrows is significant higher (pmicroplastics on the surface than without microplastics. The microplastics size distribution is smaller inside the burrows than on the surface, with an abundance of particles under 63 μm.

  5. Factors influencing biological treatment of MTBE contaminated ground water

    Energy Technology Data Exchange (ETDEWEB)

    Stringfellow, William T.; Hines Jr., Robert D.; Cockrum, Dirk K.; Kilkenny, Scott T.

    2001-09-14

    Methyl tert-butyl ether (MTBE) contamination has complicated the remediation of gasoline contaminated sites. Many sites are using biological processes for ground water treatment and would like to apply the same technology to MTBE. However, the efficiency and reliability of MTBE biological treatment is not well documented. The objective of this study was to examine the operational and environmental variables influencing MTBE biotreatment. A fluidized bed reactor was installed at a fuel transfer station and used to treat ground water contaminated with MTBE and gasoline hydrocarbons. A complete set of chemical and operational data was collected during this study and a statistical approach was used to determine what variables were influencing MTBE treatment efficiency. It was found that MTBE treatment was more sensitive to up-set than gasoline hydrocarbon treatment. Events, such as excess iron accumulation, inhibited MTBE treatment, but not hydrocarbon treatment. Multiple regression analysis identified biomass accumulation and temperature as the most important variables controlling the efficiency of MTBE treatment. The influent concentration and loading of hydrocarbons, but not MTBE, also impacted MTBE treatment efficiency. The results of this study suggest guidelines for improving MTBE treatment. Long cell retention times in the reactor are necessary for maintaining MTBE treatment. The onset of nitrification only occurs when long cell retention times have been reached and can be used as an indicator in fixed film reactors that conditions favorable to MTBE treatment exist. Conversely, if the reactor can not nitrify, it is unlikely to have stable MTBE treatment.

  6. Tomography of ground water flow from self-potential data

    Science.gov (United States)

    Revil, A.; Jardani, A.

    2007-12-01

    An inversion algorithm is developed to interpret self-potential (SP) data in terms of distribution of the seepage velocity of the ground water. The model is based on the proportionality existing between the electrokinetic source current density and the seepage velocity of the water phase. As the inverse problem is underdetermined, we use a Tikhonov regularization method with a smoothness constraint based on the differential Laplacian operator to solve the inverse problem. The regularization parameter is determined by the L-shape method. The recovery of the distribution of the seepage velocity vector of the ground water flow depends on the localization and number of non-polarizing electrodes and information relative to the distribution of the electrical resistivity of the ground. The inversion method is tested on two 2D synthetic cases and on two real SP data. The first field test corresponds to the infiltration of water from a ditch. The second one corresponds to large flow at the Cerro Prieto geothermal field in Baja California.

  7. A three-dimensional numerical model of predevelopment conditions in the Death Valley regional ground-water flow system, Nevada and California

    Science.gov (United States)

    D'Agnese, Frank A.; O'Brien, G. M.; Faunt, C.C.; Belcher, W.R.; San Juan, C.

    2002-01-01

    having two main components: a series of relatively shallow and localized flow paths that are superimposed on deeper regional flow paths. A significant component of the regional ground-water flow is through a thick Paleozoic carbonate rock sequence. Throughout the flow system, ground water flows through zones of high transmissivity that have resulted from regional faulting and fracturing. The conceptual model of the Death Valley regional ground-water flow system used for this study is adapted from the two previous ground-water modeling studies. The three-dimensional digital hydrogeologic framework model developed for the region also contains elements of both of the hydrogeologic framework models used in the previous investigations. As dictated by project scope, very little reinterpretation and refinement were made where these two framework models disagree; therefore, limitations in the hydrogeologic representation of the flow system exist. Despite limitations, the framework model provides the best representation to date of the hydrogeologic units and structures that control regional ground-water flow and serves as an important information source used to construct and calibrate the predevelopment, steady-state flow model. In addition to the hydrogeologic framework, a complex array of mechanisms accounts for flow into, through, and out of the regional ground-water flow system. Natural discharges from the regional ground-water flow system occur by evapotranspiration, springs, and subsurface outflow. In this study, evapotranspiration rates were adapted from a related investigation that developed maps of evapotranspiration areas and computed rates from micrometeorological data collected within the local area over a multiyear period. In some cases, historical spring flow records were used to derive ground-water discharge rates for isolated regional springs. For this investigation, a process-based, numerical model was developed to estimat

  8. Field demonstration of on-site analytical methods for TNT and RDX in ground water

    Energy Technology Data Exchange (ETDEWEB)

    Craig, H. [Environmental Protection Agency Region 10, Portland, OR (United States); Ferguson, G.; Markos, A. [Black and Veatch Special Projects Corp., Tacoma, WA (United States); Kusterbeck, A.; Shriver-Lake, L. [Naval Research Lab., Washington, DC (United States). Center for Bio/Molecular Science and Engineering; Jenkins, T.; Thorne, P. [Army Corps of Engineers, Hanover, NH (United States). Cold Regions Research and Engineering Lab.

    1996-12-31

    A field demonstration was conducted to assess the performance of eight commercially-available and emerging colorimetric, immunoassay, and biosensor on-site analytical methods for explosives 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in ground water and leachate at the Umatilla Army Depot Activity, Hermiston, Oregon and US Naval Submarine Base, Bangor, Washington, Superfund sites. Ground water samples were analyzed by each of the on-site methods and results compared to laboratory analysis using high performance liquid chromatography (HPLC) with EPA SW-846 Method 8330. The commercial methods evaluated include the EnSys, Inc., TNT and RDX colorimetric test kits (EPA SW-846 Methods 8515 and 8510) with a solid phase extraction (SPE) step, the DTECH/EM Science TNT and RDX immunoassay test kits (EPA SW-846 Methods 4050 and 4051), and the Ohmicron TNT immunoassay test kit. The emerging methods tested include the antibody-based Naval Research Laboratory (NRL) Continuous Flow Immunosensor (CFI) for TNT and RDX, and the Fiber Optic Biosensor (FOB) for TNT. Accuracy of the on-site methods were evaluated using linear regression analysis and relative percent difference (RPD) comparison criteria. Over the range of conditions tested, the colorimetric methods for TNT and RDX showed the highest accuracy of the emerging methods for TNT and RDX. The colorimetric method was selected for routine ground water monitoring at the Umatilla site, and further field testing on the NRL CFI and FOB biosensors will continue at both Superfund sites.

  9. Ground-water recharge in Fortymile Wash near Yucca Mountain, Nevada, 1992--1993

    Energy Technology Data Exchange (ETDEWEB)

    Savard, C.S.

    1994-12-31

    Quantification of the ground-water recharge from streamflow in the Fortymile Wash watershed will contribute to regional ground-water studies. Regional ground-water studies are an important component in the studies evaluating the ground-water flow system as a barrier to the potential migration of radionuclides from the potential underground high-level nuclear waste repository. Knowledge gained in understanding the ground-water recharge mechanisms and pathways in the Pah Canyon area, which is 10 km to the northeast of Yucca Mountain, may transfer to Yucca site specific studies. The current data collection network in Fortymile Canyon does not permit quantification of ground-water recharge, however a qualitative understanding of ground-water recharge was developed from these data.

  10. Seasonal Variation of Arsenic Concentration in Ground Water of Nawalparasi District of Nepal

    Directory of Open Access Journals (Sweden)

    Rajib Kumar Shrestha

    2014-03-01

    Full Text Available Ground water of southern part of Nepal, also known as Terai region where population density is relatively very high, has been contaminated with poisonous element Arsenic. This study has been carried out to determine variability of the level of arsenic contamination in groundwater with seasons of Pathkhauli village of Devgaun VDC and Mahuwa village of Manari VDC in Nawalparasi district, the western Terai district. Hydride Generation Atomic Absorption Spectrophotometer (HG-AAS and UV-visible Spectrophotometry was used for analysis. Total 55 groundwater samples in post-monsoon season and 45 groundwater samples in pre-monsoon season were collected. The level of arsenic contamination in groundwater was found above the Nepal interim standard of 50 ppb. Of the total 42 water samples from each pre- and post- monsoon seasons analyzed, 28 water samples (67.67% showed higher As-concentration in pre-monsoon season.

  11. Boundary of the ground-water flow model by IT Corporation (1996), for the Death Valley regional ground-water flow system study, Nevada and California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This digital data set defines the boundary of the steady-state ground-water flow model built by IT Corporation (1996). The regional, 20-layer ground-water flow model...

  12. Evaluation of baseline ground-water conditions in the Mosteiros, Ribeira Paul, and Ribeira Faja Basins, Republic of Cape Verde, West Africa, 2005-06

    Science.gov (United States)

    Heilweil, Victor M.; Earle, John D.; Cederberg, Jay R.; Messer, Mickey M.; Jorgensen, Brent E.; Verstraeten, Ingrid M.; Moura, Miguel A.; Querido, Arrigo; Spencer,; Osorio, Tatiana

    2006-01-01

    residence times. In the Mosteiros Basin, measured well and spring discharge is about 220,000 cubic meters per year. For the Ribeira Paul Basin, measured well discharge, spring discharge, and ground-water seepage to springs is about 1,600,000 cubic meters per year. Ribeira Faj? Basin is the driest of the three basins with a precipitation rate of about half that of the other two basins. The only measurable ground-water discharge from this basin is from Galleria Faj?, estimated to be about 150,000 cubic meters per year. Measured discharge for all three basins does not include submarine outflow or agricultural/phreatophyte consumptive use (Paul Basin, only) and is assumed to be less than total ground-water discharge. Ground-water ages indicate that recharge to wells and springs occurred from more than 50 years ago at some locations to within the past decade at other sites. Ground water in Paul is younger than that in the other two basins, indicating that recharge generally occurred within the past 50 years. Ground water at all the dateable sites using tritium/helium in both the Mosteiros and Ribeira Faj? Basins show that recharge occurred more than 50 years before the sampling dates. Ground-water tritium/helium age dating was not possible at some sites in Mosteiros and Ribeira Faj? Basins because of the presence of helium in the aquifer derived from the mantle or aquifer matrix. However, this helium was useful for accurate age dating of the unaffected ground-water sites. Dissolved gases indicate that most ground-water recharge occurs at mid and high altitudes within all three basins; calculated recharge altitudes ranged from 700 to more than 2,000 meters. In the Mosteiros and Ribeira Faj? Basins, recharge altitudes are much higher than the wells and springs. This suggests that it may take many years for artificial recharge to result in a beneficial impact on the aquifer in areas where the agricultural projects are implemented. Recharge altitudes in Paul Basin

  13. Ground-Water Geochemistry of Kwajalein Island, Republic of the Marshall Islands, 1991

    Science.gov (United States)

    Tribble, Gordon W.

    1997-01-01

    Ground water on Kwajalein Island is an important source of drinking water, particularly during periods of low rainfall. Fresh ground water is found as a thin lens underlain by saltwater. The concentration of dissolved ions increases with depth below the water table and proximity to the shoreline as high-salinity seawater mixes with fresh ground water. The maximum depth of the freshwater lens is 37 ft. Chloride is assumed to be non-reactive under the range of geochemical conditions on the atoll. The concentration of chloride thus is used as a conservative constituent to evaluate freshwater-saltwater mixing within the aquifer. Concentrations of sodium and for the most part, potassium and sulfate, also appear to be determined by conservative mixing between saltwater and rain. Concentrations of calcium, magnesium, and strontium are higher than expected from conservative mixing; these higher concentrations are a result of the dissolution of carbonate minerals. An excess in dissolved inorganic carbon results from carbonate-mineral dissolution and from the oxidation of organic matter in the aquifer; the stoichiometric difference between excess dissolved inorganic carbon and excess bivalent cations is used as a measure of the amount of organic-matter oxidation. Organic-matter oxidation also is indicated by the low concentration of dissolved oxygen, high concentrations of nutrients, and the presence of hydrogen sulfide in many of the water samples. Low levels of dissolved oxygen indicate oxic respiration, and sulfate reduction is indicated by hydrogen sulfide. The amount of dissolved inorganic carbon released during organic-matter oxidation is nearly equivalent to the amount of carbonate-mineral dissolution. Organic-matter oxidation and carbonate-mineral dissolution seem to be most active either in the unsaturated zone or near the top of the water table. The most plausible explanation is that high amounts of oxic respiration in the unsaturated zone generate carbon dioxide

  14. Ground-Water Quality Data in the Monterey Bay and Salinas Valley Basins, California, 2005 - Results from the California GAMA Program

    Science.gov (United States)

    Kulongoski, Justin T.; Belitz, Kenneth

    2007-01-01

    Ground-water quality in the approximately 1,000-square-mile Monterey Bay and Salinas Valley study unit was investigated from July through October 2005 as part of the California Ground-Water Ambient Monitoring and Assessment (GAMA) program. The study was designed to provide a spatially unbiased assessment of raw ground-water quality, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 94 public-supply wells and 3 monitoring wells in Monterey, Santa Cruz, and San Luis Obispo Counties. Ninety-one of the public-supply wells sampled were selected to provide a spatially distributed, randomized monitoring network for statistical representation of the study area. Six wells were sampled to evaluate changes i