WorldWideScience

Sample records for ground-based doas measurements

  1. NO2 DOAS measurements from ground and space: comparison of ground based measurements and OMI data in Mexico City

    Science.gov (United States)

    Rivera, C.; Stremme, W.; Grutter, M.

    2012-04-01

    The combination of satellite data and ground based measurements can provide valuable information about atmospheric chemistry and air quality. In this work we present a comparison between measured ground based NO2 differential columns at the Universidad Nacional Autónoma de México (UNAM) in Mexico City, using the Differential Optical Absorption Spectroscopy (DOAS) technique and NO2 total columns measured by the Ozone Monitoring Instrument (OMI) onboard the Aura satellite using the same measurement technique. From these data, distribution maps of average NO2 above the Mexico basin were constructed and hot spots inside the city could be identified. In addition, a clear footprint was detected from the Tula industrial area, ~50 km northwest of Mexico City, where a refinery, a power plant and other industries are located. A less defined footprint was identified in the Cuernavaca basin, South of Mexico City, and the nearby cities of Toluca and Puebla do not present strong enhancements in the NO2 total columns. With this study we expect to cross-validate space and ground measurements and provide useful information for future studies.

  2. Elevated aerosol layers modify the O2–O2 absorption measured by ground-based MAX-DOAS

    Energy Technology Data Exchange (ETDEWEB)

    Ortega, Ivan; Berg, Larry K.; Ferrare, Richard A.; Hair, Johnathan W.; Hostetler, Chris A.; Volkamer, Rainer

    2016-06-01

    The oxygen collisional complex (O2-O2, or O4) is a greenhouse gas, and a calibration trace gas used to infer aerosol and cloud properties by Differential Optical Absorption Spectroscopy (DOAS). Recent reports suggest the need for an O4 correction factor (CFO4) when comparing simulated and measured O4 differential slant column densities (dSCD) by passive DOAS. We investigate the sensitivity of O4 dSCD simulations at ultraviolet (360 nm) and visible (477 nm) wavelengths towards separately measured aerosol extinction profiles. Measurements were conducted by the University of Colorado 2D-MAX-DOAS instrument and NASA’s multispectral High Spectral Resolution Lidar (HSRL-2) during the Two Column Aerosol Project (TCAP) at Cape Cod, MA in July 2012. During two case study days with (1) high aerosol load (17 July, AOD ~ 0.35 at 477 nm), and (2) near molecular scattering conditions (22 July, AOD < 0.10 at 477 nm) the measured and calculated O4 dSCDs agreed within 6.4±0.4% (360 nm) and 4.7±0.6% (477 nm) if the HSRL-2 profiles were used as input to the calculations. However, if in the calculations the aerosol is confined to the surface layer (while keeping AOD constant) we find 0.53ground-based MAX-DOAS. Opportunities to identify and better characterize these layers are also discussed.

  3. Elevated aerosol layers modify the O2–O2 absorption measured by ground-based MAX-DOAS

    Energy Technology Data Exchange (ETDEWEB)

    Ortega, Ivan; Berg, Larry K.; Ferrare, Richard A.; Hair, Johnathan W.; Hostetler, Chris A.; Volkamer, Rainer

    2016-06-01

    The oxygen collisional complex (O2-O2, or O4) is a greenhouse gas, and a calibration trace gas used to infer aerosol and cloud properties by Differential Optical Absorption Spectroscopy (DOAS). Recent reports suggest the need for an O4 correction factor (CFO4) when comparing simulated and measured O4 differential slant column densities (dSCD) by passive DOAS. We investigate the sensitivity of O4 dSCD simulations at ultraviolet (360 nm) and visible (477 nm) wavelengths towards separately measured aerosol extinction profiles. Measurements were conducted by the University of Colorado 2D-MAX-DOAS instrument and NASA’s multispectral High Spectral Resolution Lidar (HSRL-2) during the Two Column Aerosol Project (TCAP) at Cape Cod, MA in July 2012. During two case study days with (1) high aerosol load (17 July, AOD ~ 0.35 at 477 nm), and (2) near molecular scattering conditions (22 July, AOD < 0.10 at 477 nm) the measured and calculated O4 dSCDs agreed within 6.4±0.4% (360 nm) and 4.7±0.6% (477 nm) if the HSRL-2 profiles were used as input to the calculations. However, if in the calculations the aerosol is confined to the surface layer (while keeping AOD constant) we find 0.53ground-based MAX-DOAS. Opportunities to identify and better characterize these layers are also discussed.

  4. Ground-based & satellite DOAS measurements integration for air quality evaluation/forecast management in the frame of QUITSAT Project.

    Science.gov (United States)

    Kostadinov, Ivan; Petritoli, Andrea; Giovanelli, Giorgio; Masieri, Samuele; Premuda, Margarita; Bortoli, Daniele; Ravegnani, Fabrizio; Palazzi, Elisa

    The observations of the Earth's atmosphere from space provide excellent opportunities for the exploration of the sophisticated physical-chemical processes on both global and regional scales. The major interest during the last three decades was focused mainly on the stratosphere and the ozone depletion. More recently the continuous improvements of satellite sensors have revealed new opportunities for larger applications of space observations, attracting scientific interest to the lower troposphere and air quality issues. The air quality depends strongly on the anthropogenic activity and therefore regional environmental agencies along with policy makers are in need of appropriate means for its continuous monitoring and control to ensure the adoption of the most appropriate actions. The goal of the pilot project QUITSAT, funded by the Italian Space Agency, is to develop algorithms and procedures for the evaluation and prediction of the air quality in Lombardia and Emilia-Romagna regions (Italy) by means of integrating satellite observations with ground-based in-situ and remote sensing measurements. This work presents dedicated Differential Optical Absorption Spectroscopy (DOAS) measurements performed during the summer of 2007 and the winter of 2008. One of the DOAS instruments operate at Mt.Cimone station (2165m a.s.l) and the other two instruments conducted measurements in/near Bologna (90 m. a.s.l). Different observational geometry was adopted (zenith-sky, multi-axis and long-path) aimed to provide tropospheric NO2 columns and O3, SO2 and HCHO concentrations at ground level as an input data for QUITSAT procedures. Details of the instruments, the radiative transfer model used and the algorithms for retrieving and calculation of the target gases concentrations are presented. The obtained experimental results are correlated with the corresponding ones retrieved from SCIAMACHY /ENVISAT observations during the overpasses above the ground-based instruments. The analysis

  5. Ozone ground-based measurements by the GASCOD near-UV and visible DOAS system

    Science.gov (United States)

    Giovanelli, G.; Bonasoni, P.; Cervino, M.; Evangelisti, F.; Ravegnani, F.

    1994-01-01

    GASCOD, a near-ultraviolet and visible differential optical spectrometer, was developed at CNR's FISBAT Institute in Bologna, Italy, and first tested at Terra Nova Bay station in Antarctica (74.6 deg S, 164.6 deg E) during the summer expeditions 1988-1990 of PNRA (PNRA is the national research program in Antarctica, 'Programma Nazionale di Ricerche in Atartide'). A comparison with coincident O3 total column measurements taken in the same Antarctic area is presented, as is another comparison performed in Italy. Also introduced is an updated model for solar zenith measurements taken from a ground-based, upward-looking GASCOD spectrometer, which was employed for the 1991-92 winter campaign at Aer-Ostersund in Sweden (63.3 deg N, 13.1 deg E) during AESOE (European Arctic Stratospheric Ozone Experiment). The GASCOD can examine the spectra from 300 to 700 nm, in 50 nm steps, by moving the spectrometer's grating. At present, it takes measurements of solar zenith radiation in the 310-342 nm range for O3 and in the 405-463 nm range for NO2.

  6. Comparisons of ground-based tropospheric NO2 MAX-DOAS measurements to satellite observations with the aid of an air quality model over the Thessaloniki area, Greece

    Science.gov (United States)

    Drosoglou, Theano; Bais, Alkiviadis F.; Zyrichidou, Irene; Kouremeti, Natalia; Poupkou, Anastasia; Liora, Natalia; Giannaros, Christos; Elissavet Koukouli, Maria; Balis, Dimitris; Melas, Dimitrios

    2017-05-01

    One of the main issues arising from the comparison of ground-based and satellite measurements is the difference in spatial representativeness, which for locations with inhomogeneous spatial distribution of pollutants may lead to significant differences between the two data sets. In order to investigate the spatial variability of tropospheric NO2 within a sub-satellite pixel, a campaign which lasted for about 6 months was held in the greater area of Thessaloniki, Greece. Three multi-axial differential optical absorption spectroscopy (MAX-DOAS) systems performed measurements of tropospheric NO2 columns at different sites representative of urban, suburban and rural conditions. The direct comparison of these ground-based measurements with corresponding products from the Ozone Monitoring Instrument onboard NASA's Aura satellite (OMI/Aura) showed good agreement over the rural and suburban areas, while the comparison with the Global Ozone Monitoring Experiment-2 (GOME-2) onboard EUMETSAT's Meteorological Operational satellites' (MetOp-A and MetOp-B) observations is good only over the rural area. GOME-2A and GOME-2B sensors show an average underestimation of tropospheric NO2 over the urban area of about 10.51 ± 8.32 × 1015 and 10.21 ± 8.87 × 1015 molecules cm-2, respectively. The mean difference between ground-based and OMI observations is significantly lower (6.60 ± 5.71 × 1015 molecules cm-2). The differences found in the comparisons of MAX-DOAS data with the different satellite sensors can be attributed to the higher spatial resolution of OMI, as well as the different overpass times and NO2 retrieval algorithms of the satellites. OMI data were adjusted using factors calculated by an air quality modeling tool, consisting of the Weather Research and Forecasting (WRF) mesoscale meteorological model and the Comprehensive Air Quality Model with Extensions (CAMx) multiscale photochemical transport model. This approach resulted in significant improvement of the

  7. MAX-DOAS measurements in southern China: retrieval of aerosol extinctions and validation using ground-based in-situ data

    Directory of Open Access Journals (Sweden)

    X. Li

    2010-03-01

    Full Text Available We performed MAX-DOAS measurements during the PRiDe-PRD2006 campaign in the Pearl River Delta region 50 km north of Guangzhou, China, for 4 weeks in June 2006. We used an instrument sampling at 7 different elevation angles between 3° and 90°. During 9 cloud-free days, differential slant column densities (DSCDs of O4 (O2 dimer absorptions between 351 nm and 389 nm were evaluated for 6 elevation angles. Here, we show that radiative transfer modeling of the DSCDS can be used to retrieve the aerosol extinction and the height of the boundary layer. A comparison of the aerosol extinction with simultaneously recorded, ground based nephelometer data shows excellent agreement.

  8. Simulated Radiative Transfer DOAS - A new method for improving volcanic SO2 emissions retrievals from ground-based UV-spectroscopic measurements of scattered solar radiation

    Science.gov (United States)

    Kern, C.; Deutschmann, T.; Vogel, L.; Bobrowski, N.; Hoermann, C.; Werner, C. A.; Sutton, A. J.; Elias, T.

    2011-12-01

    Passive Differential Optical Absorption Spectroscopy (DOAS) has become a standard tool for measuring SO2 at volcanoes. More recently, ultra-violet (UV) cameras have also been applied to obtain 2D images of SO2-bearing plumes. Both techniques can be used to derive SO2 emission rates by measuring SO2 column densities, integrating these along the plume cross-section, and multiplying by the wind speed. Recent measurements and model studies have revealed that the dominating source of uncertainty in these techniques often originates from an inaccurate assessment of radiative transfer through the volcanic plume. The typical assumption that all detected radiation is scattered behind the volcanic plume and takes a straight path from there to the instrument is often incorrect. We recently showed that the straight path assumption can lead to column density errors of 50% or more in cases where plumes with high SO2 and aerosol concentrations are measured from several kilometers distance, or where the background atmosphere contains a large amount of scattering aerosols. Both under- and overestimation are possible depending on the atmospheric conditions and geometry during spectral acquisition. Simulated Radiative Transfer (SRT) DOAS is a new evaluation scheme that combines radiative transfer modeling with spectral analysis of passive DOAS measurements in the UV region to derive more accurate SO2 column densities than conventional DOAS retrievals, which in turn leads to considerably more accurate emission rates. A three-dimensional backward Monte Carlo radiative transfer model is used to simulate realistic light paths in and around the volcanic plume containing variable amounts of SO2 and aerosols. An inversion algorithm is then applied to derive the true SO2 column density. For fast processing of large datasets, a linearized algorithm based on lookup tables was developed and tested on a number of example datasets. In some cases, the information content of the spectral data is

  9. Eight-component retrievals from ground-based MAX-DOAS observations

    Directory of Open Access Journals (Sweden)

    H. Irie

    2011-06-01

    Full Text Available We attempt for the first time to retrieve lower-tropospheric vertical profile information for 8 quantities from ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS observations. The components retrieved are the aerosol extinction coefficients at two wavelengths, 357 and 476 nm, and NO2, HCHO, CHOCHO, H2O, SO2, and O3 volume mixing ratios. A Japanese MAX-DOAS profile retrieval algorithm, version 1 (JM1, is applied to observations performed at Cabauw, the Netherlands (51.97° N, 4.93° E, in June–July 2009 during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI. Of the retrieved profiles, we focus here on the lowest-layer data (mean values at altitudes 0–1 km, where the sensitivity is usually highest owing to the longest light path. In support of the capability of the multi-component retrievals, we find reasonable overall agreement with independent data sets, including a regional chemical transport model (CHIMERE and in situ observations performed near the surface (2–3 m and at the 200-m height level of the tall tower in Cabauw. Plumes of enhanced HCHO and SO2 were likely affected by biogenic and ship emissions, respectively, and an improvement in their emission strengths is suggested for better agreement between CHIMERE simulations and MAX-DOAS observations. Analysis of air mass factors indicates that the horizontal spatial representativeness of MAX-DOAS observations is about 3–15 km (depending mainly on aerosol extinction, comparable to or better than the spatial resolution of current UV-visible satellite observations and model calculations. These demonstrate that MAX-DOAS provides multi-component data useful for the evaluation of satellite observations and model calculations and can play an important role in bridging different data sets having different spatial resolutions.

  10. Eight-component retrievals from ground-based MAX-DOAS observations

    Directory of Open Access Journals (Sweden)

    H. Irie

    2011-01-01

    Full Text Available We attempt for the first time to retrieve lower-tropospheric vertical profile information for 8 quantities from ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS observations. The components retrieved are the aerosol extinction coefficients at two wavelengths, 357 and 476 nm and NO2, HCHO, CHOCHO, H2O, SO2, and O3 volume mixing ratios. A Japanese MAX-DOAS profile retrieval algorithm, version 1 (JM1, is applied to observations performed at Cabauw, the Netherlands (51.97° N, 4.93° E, in June–July 2009 during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI. Of the retrieved profiles, we focus here on the lowest-layer data (mean values at altitudes 0–1 km, where the sensitivity is usually highest owing to the longest light path. In support of the capability of the multi-component retrievals, we find reasonable overall agreement with independent data sets, including a regional chemical transport model (CHIMERE and in situ observations performed at the 3 and 200 m height levels of the tall tower in Cabauw. Plumes of enhanced HCHO and SO2 were likely affected by biogenic and ship emissions, respectively, and an improvement in their emission strengths is suggested for better agreement between CHIMERE simulations and MAX-DOAS observations. Analysis of air mass factors indicates that the horizontal spatial representativeness of MAX-DOAS observations is about 3–15 km (depending mainly on aerosol extinction, comparable to or better than the spatial resolution of current UV-visible satellite observations and model calculations. These demonstrate that MAX-DOAS provides multi-component data useful for the evaluation of satellite observations and model calculations and can play an important role in bridging different data sets having different spatial resolutions.

  11. Eight-component retrievals from ground-based MAX-DOAS observations

    Science.gov (United States)

    Irie, H.; Takashima, H.; Kanaya, Y.; Boersma, K. F.; Gast, L.; Wittrock, F.; Brunner, D.; Zhou, Y.; van Roozendael, M.

    2011-06-01

    We attempt for the first time to retrieve lower-tropospheric vertical profile information for 8 quantities from ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations. The components retrieved are the aerosol extinction coefficients at two wavelengths, 357 and 476 nm, and NO2, HCHO, CHOCHO, H2O, SO2, and O3 volume mixing ratios. A Japanese MAX-DOAS profile retrieval algorithm, version 1 (JM1), is applied to observations performed at Cabauw, the Netherlands (51.97° N, 4.93° E), in June-July 2009 during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI). Of the retrieved profiles, we focus here on the lowest-layer data (mean values at altitudes 0-1 km), where the sensitivity is usually highest owing to the longest light path. In support of the capability of the multi-component retrievals, we find reasonable overall agreement with independent data sets, including a regional chemical transport model (CHIMERE) and in situ observations performed near the surface (2-3 m) and at the 200-m height level of the tall tower in Cabauw. Plumes of enhanced HCHO and SO2 were likely affected by biogenic and ship emissions, respectively, and an improvement in their emission strengths is suggested for better agreement between CHIMERE simulations and MAX-DOAS observations. Analysis of air mass factors indicates that the horizontal spatial representativeness of MAX-DOAS observations is about 3-15 km (depending mainly on aerosol extinction), comparable to or better than the spatial resolution of current UV-visible satellite observations and model calculations. These demonstrate that MAX-DOAS provides multi-component data useful for the evaluation of satellite observations and model calculations and can play an important role in bridging different data sets having different spatial resolutions.

  12. Multi-component vertical profile retrievals for ground-based MAX-DOAS

    Science.gov (United States)

    Irie, Hitoshi; Kanaya, Yugo; Takashima, Hisahiro; van Roozendael, Michel; Wittrock, Folkard; Piters, Ankie

    2010-05-01

    We attempt to retrieve lower-tropospheric vertical profile information for 8 components from ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements. The components retrieved include aerosol extinction coefficients (AEC) at two wavelengths 357 and 476 nm, NO2, HCHO, CHOCHO, H2O, SO2, and O3 volume mixing ratios (VMRs). This method was applied to MAX-DOAS observations performed at Cabauw, the Netherlands (52.0°N, 4.9°E) in June-July 2009 during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI) campaign. For the lowest layer of retrieved profiles at 0-1 km, two channels of AEC values reveal consistent variations. NO2 showed typical diurnal variations with maximum in early morning and minimum in the afternoon. Positive correlations between HCHO and CHOCHO were often seen. H2O VMR agreed well with that derived from NCEP surface data, and was used to judge cloudy cases after conversion to relative humidity. All these results support the capability of MAX-DOAS observations applicable to various air quality studies. Similar multi-component retrievals applied to observations in Japan are also presented in this talk.

  13. The 8-component retrievals from ground-based MAX-DOAS observations

    Science.gov (United States)

    Irie, H.; Takashima, H.; Kanaya, Y.; Boersma, F.; Gast, L.; Wittrock, F.; van Roozendael, M.

    2010-12-01

    We first attempt to retrieve lower-tropospheric vertical profile information on 8 components from ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations. Components retrieved are aerosol extinction coefficients (AEC) at two wavelengths 357 and 476 nm, NO2, HCHO, CHOCHO, H2O, SO2, and O3 volume mixing ratios (VMRs). A Japanese MAX-DOAS profile retrieval algorithm version 1 (JM1) is applied to observations performed at Cabauw, the Netherlands (51.97N, 4.93E) in June-July 2009 during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI). Of retrieved profiles, we focus here on the lowest layer data (mean values at altitudes 0-1 km), where the sensitivity is usually highest owing to the longest light path. In support of the capability of the multi-component retrievals, overall we find reasonable agreement with independent data sets, including a regional chemical transport model (CHIMERE) and in situ observations performed at 3- and 200-m height levels of a tower placed in Cabauw. Enhanced HCHO and SO2 plumes were likely affected by biogenic and ship emissions, respectively, but an improvement in their emission strengths was suggested for better agreement. Analysis of air mass factors indicates that the horizontal representativeness of MAX-DOAS observation is about 3-15 km, comparable to or better than the spatial resolution of relevant UV-visible satellite observations and model calculations. These demonstrate that MAX-DOAS provides multi-component data useful for evaluation of satellite observations and model calculations and plays a role in bridging different data sets having different spatial resolutions.

  14. Intercomparison of stratospheric nitrogen dioxide columns retrieved from ground-based DOAS and FTIR and satellite DOAS instruments over the subtropical Izana station

    OpenAIRE

    Robles-Gonzalez, Cristina; Navarro-Comas, Mónica; Puentedura, Olga; Schneider, Matthias; Hase, Frank; Garcia, Omaira; Blumenstock, Thomas; Gil-Ojeda, Manuel

    2016-01-01

    A 13-year analysis (2000–2012) of the NO2 vertical column densities derived from ground-based (GB) instruments and satellites has been carried out over the Izaña NDACC (Network for the Detection of the Atmospheric Composition Change) subtropical site. Ground-based DOAS (differential optical absorption spectroscopy) and FTIR (Fourier transform infrared spectroscopy) instruments are intercompared to test mutual consistency and then used for validation of stratospheric NO2 fro...

  15. Five Years of Ground-Based MAX-DOAS Observations of CHOCHO and HCHO in the Beijing Area

    Science.gov (United States)

    Hendrick, F.; Lerot, C.; De Smedt, I.; Stavrakou, T.; Fayt, C.; Gielen, C.; Hermans, C.; Muller, J. F.; Pinardi, G.; Van Roozendael, M.

    2015-12-01

    Glyoxal (CHOCHO) and formaldehyde (HCHO) are among the most important carbonyl compounds in the atmosphere. Given their short lifetime (typically a few hours) and since they are mainly produced by the oxidation of biogenic and anthropogenic volatile organic compounds (VOCs), they are very good proxy for detecting active VOCs chemistry which can be responsible for the formation of pollutants such as tropospheric ozone and secondary organic aerosols. Both CHOCHO and HCHO are also directly released by biomass burning and fossil fuel combustion. Measuring these species is therefore of major importance for air quality monitoring, especially given the scarcity of available observational data sets. In this presentation, CHOCHO and HCHO vertical profiles and corresponding column densities are retrieved from ground-based MAX-DOAS (Multi-AXis Differential Optical Absorption Spectroscopy) measurements in the Beijing city center and at the suburban site of Xianghe located at 60km East of Beijing. The periods covered by the observations are June 2008-April 2009 in Beijing and March 2010-December 2014 in Xianghe. We first investigate the capability of the MAX-DOAS technique to measure these species in such highly-polluted environment. Then the diurnal and seasonal cycles of CHOCHO and HCHO near-surface concentrations and vertical column densities as well as the corresponding CHOCHO/HCHO ratios (RGF) are examined on a long-term basis at both locations. This RGF ratio is often used as an indicator of changes in the atmospheric VOC mixture. Finally, these diurnal and seasonal cycles are further assessed using simulations from the 3D chemistry transport model IMAGES and observations from the OMI and GOME-2 satellite nadir sensors.

  16. The CU Airborne MAX-DOAS instrument: ground based validation, and vertical profiling of aerosol extinction and trace gases

    Directory of Open Access Journals (Sweden)

    S. Baidar

    2012-09-01

    Full Text Available The University of Colorado Airborne Multi Axis Differential Optical Absorption Spectroscopy (CU AMAX-DOAS instrument uses solar stray light remote sensing to detect and quantify multiple trace gases, including nitrogen dioxide (NO2, glyoxal (CHOCHO, formaldehyde (HCHO, water vapor (H2O, nitrous acid (HONO, iodine monoxide (IO, bromine monoxide (BrO, and oxygen dimers (O4 at multiple wavelengths (360 nm, 477 nm, 577 nm and 632 nm simultaneously, and sensitively in the open atmosphere. The instrument is unique, in that it presents the first systematic implementation of MAX-DOAS on research aircraft, i.e. (1 includes measurements of solar stray light photons from nadir, zenith, and multiple elevation angles forward and below the plane by the same spectrometer/detector system, and (2 features a motion compensation system that decouples the telescope field of view (FOV from aircraft movements in real-time (< 0.35° accuracy. Sets of solar stray light spectra collected from nadir to zenith scans provide some vertical profile information within 2 km above and below the aircraft altitude, and the vertical column density (VCD below the aircraft is measured in nadir view. Maximum information about vertical profiles is derived simultaneously for trace gas concentrations and aerosol extinction coefficients over similar spatial scales and with a vertical resolution of typically 250 m during aircraft ascent/descent.

    The instrument is described, and data from flights over California during the CalNex and CARES air quality field campaigns is presented. Horizontal distributions of NO2 VCDs (below the aircraft maps are sampled with typically 1 km resolution, and show good agreement with two ground based CU MAX-DOAS instruments (slope 0.95 ± 0.09, R2 = 0.86. As a case study vertical profiles of NO2, CHOCHO, HCHO, and H2O mixing ratios and aerosol extinction coefficients

  17. The CU Airborne MAX-DOAS instrument: ground based validation, and vertical profiling of aerosol extinction and trace gases

    Science.gov (United States)

    Baidar, S.; Oetjen, H.; Coburn, S.; Dix, B.; Ortega, I.; Sinreich, R.; Volkamer, R.

    2012-09-01

    The University of Colorado Airborne Multi Axis Differential Optical Absorption Spectroscopy (CU AMAX-DOAS) instrument uses solar stray light remote sensing to detect and quantify multiple trace gases, including nitrogen dioxide (NO2), glyoxal (CHOCHO), formaldehyde (HCHO), water vapor (H2O), nitrous acid (HONO), iodine monoxide (IO), bromine monoxide (BrO), and oxygen dimers (O4) at multiple wavelengths (360 nm, 477 nm, 577 nm and 632 nm) simultaneously, and sensitively in the open atmosphere. The instrument is unique, in that it presents the first systematic implementation of MAX-DOAS on research aircraft, i.e. (1) includes measurements of solar stray light photons from nadir, zenith, and multiple elevation angles forward and below the plane by the same spectrometer/detector system, and (2) features a motion compensation system that decouples the telescope field of view (FOV) from aircraft movements in real-time (CHOCHO, HCHO, and H2O mixing ratios and aerosol extinction coefficients, ɛ, at 477nm calculated from O4 measurements from a low approach at Brackett airfield inside the South Coast Air Basin (SCAB) are presented. These profiles contain ~ 12 degrees of freedom (DOF) over a 3.5 km altitude range, independent of signal-to-noise at which the trace gas is detected. The boundary layer NO2 concentration, and the integral aerosol extinction over height (aerosol optical depth, AOD) agrees well with nearby ground-based in-situ NO2 measurement, and AERONET station. The detection limits of NO2, CHOCHO, HCHO, ɛ360, ɛ477 from 30 s integration time spectra recorded forward of the plane are 5 ppt, 3 ppt, 100 ppt, 0.004 km-1, 0.002 km-1 in the free troposphere (FT), and 30 ppt, 16 ppt, 540 ppt, 0.012 km-1, 0.006 km-1 inside the boundary layer (BL), respectively. Mobile column observations of trace gases and aerosols are complimentary to in-situ observations, and help bridge the spatial scales probed by ground-based observations, satellites, and predicted by atmospheric

  18. Kerbside DOAS measurements of air pollutants

    Science.gov (United States)

    Schäfer, Klaus; Ling, Hong; Legelli, Stefan; Münkel, Christoph; Emeis, Stefan

    2014-10-01

    Emission sources as well as wind speed and direction and MLH are important factors which influence high air pollutant concentrations. This is generally known (Schäfer et al., 2006) but the detailed understanding of processes directing certain air pollutant concentrations like HCHO is not complete. To study these processes a long-term campaign in Augsburg, Germany, was performed since March 2012. The concentrations of NO, NO2, O3 and HCHO, which were measured with a DOAS from OPSIS across a main traffic road and a nearby park area, are analysed. A ceilometer CL31 from Vaisala which is an eye-safe commercial mini-lidar system is applied to detect layering of the lower atmosphere continuously. Special software for this ceilometer with MATLAB provides routine retrievals of lower atmosphere layering from vertical profiles of laser backscatter data. Meteorological data were measured by a ground-based weather station at the measurement site as well as taken from monitoring data archives of the German National Meteorological Service (DWD), which are measured by radiosondes (Oberschleißheim). Correlation analyses are applied to show the coupling of temporal variations of NO, NO2, O3 and HCHO concentrations with temperature, mixing layer height and wind speed. HCHO which is emitted from both anthropogenic and biogenic sources is studied especially.

  19. Ground-based FTIR and MAX-DOAS observations of formaldehyde at Réunion Island and comparisons with satellite and model data

    Directory of Open Access Journals (Sweden)

    C. Vigouroux

    2009-07-01

    Full Text Available Formaldehyde (HCHO columns have been retrieved from ground-based Fourier transform infrared (FTIR campaign measurements in 2004 and 2007 and from UV-Visible MAX-DOAS measurements in 2004–2005 at the NDACC site of Réunion Island (21° S, 55° E. The FTIR and MAX-DOAS daily mean formaldehyde total columns are intercompared in their common measurement period, from August to October 2004. The ground-based data are also compared to correlative SCIAMACHY data. The comparisons account for the vertical sensitivity differences of the data sets, by including their respective averaging kernels. Complete error budgets are also presented.

    The FTIR and MAX-DOAS daily mean total columns agree very well: no significant bias is observed and the standard deviation of the comparisons is only 8%. Both FTIR and MAX-DOAS HCHO total columns are in good agreement with SCIAMACHY values in the 2004–2005 period, with standard deviations of 21% and 31%, respectively. The same seasonal cycle is observed by the different instruments, with a minimum in austral winter and a maximum in February–March.

    The FTIR and MAX-DOAS data are confronted with HCHO columns calculated by a global CTM, the IMAGES model. The model underestimates the HCHO columns by 23–29% in comparison with FTIR, and by 15% in comparison with DOAS. This bias might have multiple causes, including an underestimation of OH concentrations in the model (as indicated by a sensitivity study using prescribed OH fields and/or an underestimated contribution of large-scale transport of HCHO precursors from Madagascar. The latter hypothesis is comforted by the large observed day-to-day variability of HCHO columns, and by the observation that the peak values of FTIR columns can often be associated with free tropospheric transport patterns from source regions over Madagascar to Réunion Island, according to simulations performed with the Lagrangian particle dispersion model FLEXPART.

  20. LED-CE-DOAS and MAX-DOAS measurements of glyoxal and NO2 at Milliken Library during CalNEX

    Science.gov (United States)

    Thalman, R. M.; Waxman, E.; Coburn, S.; Ortega, I.; Volkamer, R.

    2010-12-01

    The University of Colorado Light Emitting Diode Cavity Enhanced Differential Optical Absorption Spectroscopy (CU LED-CE-DOAS) and a CU Ground based MAX-DOAS instrument were deployed on top of Milliken Library at the CalNex-LA site (May.June 2010). The CU LED-CE-DOAS is a novel instrument that was deployed for the first time in the field to measure in-situ concentrations of nitrogen dioxide (NO2) and glyoxal (CHOCHO) at roof top level. The CU Ground MAX-DOAS measured vertical column integral amounts of the same gases, along with formaldehyde (HCHO) among other gases. For a period of time two CE-DOAS instruments were operated simultaneously with one in closed and one in open cavity mode. Open cavity mode allows air to flow between the mirrors of the cavity and does not utilize an inlet or aerosol filter. NO2 measurements by the two instruments are compared. Here we present the diurnal profiles for glyoxal and NO2 measured by CE-DOAS for the duration of the Cal-NEX campaign. The temporal evolution of in situ CE-DOAS measurements of NO2 and glyoxal is used in combination with that of the vertical column density measured by MAX-DOAS to assess transport to the site, as well as to estimate the boundary layer height.

  1. Intercomparison of stratospheric nitrogen dioxide columns retrieved from ground-based DOAS and FTIR and satellite DOAS instruments over the subtropical Izana station

    Science.gov (United States)

    Robles-Gonzalez, Cristina; Navarro-Comas, Mónica; Puentedura, Olga; Schneider, Matthias; Hase, Frank; Garcia, Omaira; Blumenstock, Thomas; Gil-Ojeda, Manuel

    2016-09-01

    A 13-year analysis (2000-2012) of the NO2 vertical column densities derived from ground-based (GB) instruments and satellites has been carried out over the Izaña NDACC (Network for the Detection of the Atmospheric Composition Change) subtropical site. Ground-based DOAS (differential optical absorption spectroscopy) and FTIR (Fourier transform infrared spectroscopy) instruments are intercompared to test mutual consistency and then used for validation of stratospheric NO2 from OMI (Ozone Monitoring Instrument) and SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY). The intercomparison has been carried out taking into account the various differences existing in instruments, namely temporal coincidence, collocation, sensitivity, field of view, etc. The paper highlights the importance of considering an "effective solar zenith angle" instead of the actual one when comparing direct-sun instruments with zenith sky ones for a proper photochemical correction. Results show that NO2 vertical column densities mean relative difference between FTIR and DOAS instruments is 2.8 ± 10.7 % for a.m. data. Both instruments properly reproduce the NO2 seasonal and the interannual variation. Mean relative difference of the stratospheric NO2 derived from OMI and DOAS is -0.2 ± 8.7 % and from OMI and FTIR is -1.6 ± 6.7 %. SCIAMACHY mean relative difference is of 3.7 ± 11.7 and -5.7 ± 11.0 % for DOAS and FTIR, respectively. Note that the days used for the intercomparison are not the same for all the pairs of instruments since it depends on the availability of data. The discrepancies are found to be seasonally dependent with largest differences in winter and excellent agreement in the spring months (AMJ). A preliminary analysis of NO2 trends has been carried out with the available data series. Results show increases in stratospheric NO2 columns in all instruments but larger values in those that are GB than that expected by nitrous oxide oxidation. The

  2. Validation of SCIAMACHY NO2 Vertical Column Densities with Mt.Cimone and Stara Zagora Ground-Based Zenith Sky DOAS Observations

    Science.gov (United States)

    Kostadinov, I.; Petritoli, A.; Werner, R.; Valev, D.; Atanasov, At.; Bortoli, D.; Markova, T.; Ravegnani, F.; Palazzi, E.; Giovanelli, G.

    2004-08-01

    Ground-based zenith sky Differential Optical Absorption Spectroscopy (DOAS) measurements performed by means of GASCOD instruments at Mt. Cimone (44N 11E), Italy and Stara Zagora (42N, 25E), Bulgaria are used for validation of SCIAMACHY NO2 vertical column density (vcd) of ESA SCI_NL product retrieved with 5.01 processor version. The results presented in this work regard satellite data for the JulyDecember 2002 period. On this base it is concluded that during summer-autumn period the overall NO2 vcd above both stations is fairly well reproduced by the SCIAMACHY data, while towards the winter period they deviate from the seasonal behaviour of NO2 vcd derived at both stations

  3. Monitoring stratospheric chlorine activation from time series of OClO DSCDs above Kiruna using ground-based zenith sky DOAS observations

    Science.gov (United States)

    Gu, Myojeong; Enell, Carl-Fredrik; Pukite, Janis; Platt, Ulrich; Raffalski, Uwe; Wagner, Thomas

    2017-04-01

    After to the Montreal protocol and amendments, the production of CFCs was strongly reduced. Since then scientists have steadily made efforts to monitor the amount of chlorine compounds which are responsible for the destruction of ozone in the stratosphere. Although very recent research of stratospheric ozone indicates an ozone recovery, ozone depletion is still observed in the polar spring and is expected to last for about another 70 years according to the WMO. Therefore, continuous observation and analysis of the stratospheric ozone as well as other stratospheric trace gases are highly demanded. Several previous studies have investigated OClO which is an indicator for stratospheric chlorine activation using satellite, ground-based, and balloon remote sensing measurements. In this work, we investigate long-term time series of OClO DSCDs (Differential Slant Column densities) above Kiruna, Sweden (67.84°N, 20.41°E) which is located inside the Arctic Circle by using the ground-based zenith sky DOAS measurements. Since our measurements are performed at the fixed site, for the interpretation also the relative position of the polar vortex has to be considered. Our long-term data obtained during about 15 years allows us to classify the dependence of the OClO amount on the various meteorological conditions. Our data show a large variability with high OClO SCDs in cold, and low OClO SCDs in warm winters. Our measurements also allow to investigate the effect of the chlorine activation and its duration on the strength of the ozone destruction.

  4. CU Airborne MAX-DOAS measurements over California during the CalNEx and CARES field campaigns

    Science.gov (United States)

    Baidar, S.; Oetjen, H.; Coburn, S.; Ortega, I.; Dix, B. K.; Sinreich, R.; Volkamer, R.

    2010-12-01

    The University of Colorado Airborne Multi-Axis Differential Optical Absorption Spectroscopy (CU AMAX-DOAS) instrument was deployed aboard the NOAA Optical Remote Sensing Twin Otter Research Aircraft during the CalNEx 2010 and CARES field campaigns. A total of 52 flights (48 research + 4 transfer flights) were carried out between May 19 and July 19 2010 and included flights in the South California Air Basin, the High deserts, Northern Mexico, the Central Valley, Sacramento, and the San Francisco Bay Area. A particular component of the CU AMAX-DOAS deployment was to enhance the value of ground-based super sites in Pasadena and Bakersfield, as well as the CARES T0 and T1 sites. The CU AMAX-DOAS is measuring column amounts of NO2, HCHO, CHOCHO, O4 and other gases above and below the aircraft. The focus of this deployment was to map the horizontal and vertical distribution of these gases. Here we describe the CU AMAX-DOAS instrument and give an overview of the NO2 vertical columns below the plane along the flight tracks. A first comparison of NO2 vertical columns measured by AMAX-DOAS and two CU Ground based MAX-DOAS instruments which were deployed in Pasadena and Fontana Arrows during CalNEx and at the T1 site during CARES is also presented.

  5. Spatiotemporal inhomogeneity in atmospheric trace-gas over Fukuoka, an urban area in Japan, observed by ground-based MAX-DOAS

    Science.gov (United States)

    Takashima, H.; Kanaya, Y.; Irie, H.

    2015-12-01

    Continuous trace-gas observations have been made using ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) at Fukuoka (33.55N, 130.36E), an urban area in Japan. The maximum of the NOx emissions at Fukuoka is estimated to be at the city center, and the monitoring site is located ~5 km southwest of the city center, outside of the central area. To clarify the inhomogeneity as well as the transport/mixing processes of the polluted air in the urban area, continuous profile measurements have been conducted in two azimuth directions: towards and away from the city center. From NO2 observations, we sometimes observed spatial inhomogeneity associated with vertical/horizontal transport of high concentrations of NO2 from the city center, and horizontal transport of low concentrations from the ocean via a land-sea breeze. On the other hand, we observed spatial inhomogeneity in HONO and HCHO during summer, which was probably due to photochemical production over the city center.

  6. Retrievals of formaldehyde from ground-based FTIR and MAX-DOAS observations at the Jungfraujoch station and comparisons with GEOS-Chem and IMAGES model simulations

    Science.gov (United States)

    Franco, B.; Hendrick, F.; Van Roozendael, M.; Müller, J.-F.; Stavrakou, T.; Marais, E. A.; Bovy, B.; Bader, W.; Fayt, C.; Hermans, C.; Lejeune, B.; Pinardi, G.; Servais, C.; Mahieu, E.

    2015-04-01

    As an ubiquitous product of the oxidation of many volatile organic compounds (VOCs), formaldehyde (HCHO) plays a key role as a short-lived and reactive intermediate in the atmospheric photo-oxidation pathways leading to the formation of tropospheric ozone and secondary organic aerosols. In this study, HCHO profiles have been successfully retrieved from ground-based Fourier transform infrared (FTIR) solar spectra and UV-visible Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) scans recorded during the July 2010-December 2012 time period at the Jungfraujoch station (Swiss Alps, 46.5° N, 8.0° E, 3580 m a.s.l.). Analysis of the retrieved products has revealed different vertical sensitivity between both remote sensing techniques. Furthermore, HCHO amounts simulated by two state-of-the-art chemical transport models (CTMs), GEOS-Chem and IMAGES v2, have been compared to FTIR total columns and MAX-DOAS 3.6-8 km partial columns, accounting for the respective vertical resolution of each ground-based instrument. Using the CTM outputs as the intermediate, FTIR and MAX-DOAS retrievals have shown consistent seasonal modulations of HCHO throughout the investigated period, characterized by summertime maximum and wintertime minimum. Such comparisons have also highlighted that FTIR and MAX-DOAS provide complementary products for the HCHO retrieval above the Jungfraujoch station. Finally, tests have revealed that the updated IR parameters from the HITRAN 2012 database have a cumulative effect and significantly decrease the retrieved HCHO columns with respect to the use of the HITRAN 2008 compilation.

  7. Retrievals of formaldehyde from ground-based FTIR and MAX-DOAS observations at the Jungfraujoch station and comparisons with GEOS-Chem and IMAGES model simulations

    Directory of Open Access Journals (Sweden)

    B. Franco

    2015-04-01

    Full Text Available As an ubiquitous product of the oxidation of many volatile organic compounds (VOCs, formaldehyde (HCHO plays a key role as a short-lived and reactive intermediate in the atmospheric photo-oxidation pathways leading to the formation of tropospheric ozone and secondary organic aerosols. In this study, HCHO profiles have been successfully retrieved from ground-based Fourier transform infrared (FTIR solar spectra and UV-visible Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS scans recorded during the July 2010–December 2012 time period at the Jungfraujoch station (Swiss Alps, 46.5° N, 8.0° E, 3580 m a.s.l.. Analysis of the retrieved products has revealed different vertical sensitivity between both remote sensing techniques. Furthermore, HCHO amounts simulated by two state-of-the-art chemical transport models (CTMs, GEOS-Chem and IMAGES v2, have been compared to FTIR total columns and MAX-DOAS 3.6–8 km partial columns, accounting for the respective vertical resolution of each ground-based instrument. Using the CTM outputs as the intermediate, FTIR and MAX-DOAS retrievals have shown consistent seasonal modulations of HCHO throughout the investigated period, characterized by summertime maximum and wintertime minimum. Such comparisons have also highlighted that FTIR and MAX-DOAS provide complementary products for the HCHO retrieval above the Jungfraujoch station. Finally, tests have revealed that the updated IR parameters from the HITRAN 2012 database have a cumulative effect and significantly decrease the retrieved HCHO columns with respect to the use of the HITRAN 2008 compilation.

  8. GIFTS EDU Ground-based Measurement Experiment

    Science.gov (United States)

    Zhou, Daniel K.; Smith, W. L., Sr.; Zollinger, L. J.; Huppi, R. J.; Reisse, R. A.; Larar, A. M.; Liu, X.; Tansock, J. J., Jr.; Jensen, S. M.; Revercomb, H. E.; Feltz, W. F.; Bingham, G. E.

    2007-01-01

    Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS) Engineering Demonstration Unit (EDU) is an imaging infrared spectrometer designed for atmospheric soundings. The EDU groundbased measurement experiment was held in Logan, Utah during September 2006 to demonstrate its extensive capabilities for geosynchronous and other applications.

  9. Ground-Based Aerosol Measurements | Science Inventory ...

    Science.gov (United States)

    Atmospheric particulate matter (PM) is a complex chemical mixture of liquid and solid particles suspended in air (Seinfeld and Pandis 2016). Measurements of this complex mixture form the basis of our knowledge regarding particle formation, source-receptor relationships, data to test and verify complex air quality models, and how PM impacts human health, visibility, global warming, and ecological systems (EPA 2009). Historically, PM samples have been collected on filters or other substrates with subsequent chemical analysis in the laboratory and this is still the major approach for routine networks (Chow 2005; Solomon et al. 2014) as well as in research studies. In this approach, air, at a specified flow rate and time period, is typically drawn through an inlet, usually a size selective inlet, and then drawn through filters, 1 INTRODUCTION Atmospheric particulate matter (PM) is a complex chemical mixture of liquid and solid particles suspended in air (Seinfeld and Pandis 2016). Measurements of this complex mixture form the basis of our knowledge regarding particle formation, source-receptor relationships, data to test and verify complex air quality models, and how PM impacts human health, visibility, global warming, and ecological systems (EPA 2009). Historically, PM samples have been collected on filters or other substrates with subsequent chemical analysis in the laboratory and this is still the major approach for routine networks (Chow 2005; Solomo

  10. Mini MAX-DOAS Measurements of Air Pollutants over China

    Science.gov (United States)

    Staadt, Steffen; Hao, Nan; Trautmann, Thomas

    2016-08-01

    This study continues the work of Clémer et al., (2010) and is aimed to improve trace gas retrievals with mini MAX-DOAS measurements in Nanjing. Based on that work, aerosol extinction vertical profiles are retrieved using the bePRO inversion algorithm developed by the Royal Belgian Institute for Space Aeronomy (BIRA- IASB). Afterwards, the tropospheric trace gas vertical profiles and vertical column densities (VCDs) are retrieved by applying the optimal estimation method to the O4 MAX-DOAS measurements. The Profiles for N O2 , S O2 , glyoxal, formaldehyde and nitrous acid are obtained with different results and different settings for the DOAS measurement. The AODs show small positive correlation against the AERONET values. For NO2, the retrieval shows reasonable concentrations in winter as opposed to summer and has small positive correlations with GOME-2 data. The SO2 VCDs are not correlated with the GOME-2 data, due to high uncertainties from MAX-DOAS and satellite retrievals, while the vertical mixing ratios (VMR) show good agreement with in-situ data (SORPES) at Nanjing. Nitrous acid shows a maximum in winter and a minimum in summer, while glyoxal has its maximum in August and September.

  11. Ground-Based Lidar for Atmospheric Boundary Layer Ozone Measurements

    Science.gov (United States)

    Kuang, Shi; Newchurch, Michael J.; Burris, John; Liu, Xiong

    2013-01-01

    Ground-based lidars are suitable for long-term ozone monitoring as a complement to satellite and ozonesonde measurements. However, current ground-based lidars are unable to consistently measure ozone below 500 m above ground level (AGL) due to both engineering issues and high retrieval sensitivity to various measurement errors. In this paper, we present our instrument design, retrieval techniques, and preliminary results that focus on the high-temporal profiling of ozone within the atmospheric boundary layer (ABL) achieved by the addition of an inexpensive and compact mini-receiver to the previous system. For the first time, to the best of our knowledge, the lowest, consistently achievable observation height has been extended down to 125 m AGL for a ground-based ozone lidar system. Both the analysis and preliminary measurements demonstrate that this lidar measures ozone with a precision generally better than 10% at a temporal resolution of 10 min and a vertical resolution from 150 m at the bottom of the ABL to 550 m at the top. A measurement example from summertime shows that inhomogeneous ozone aloft was affected by both surface emissions and the evolution of ABL structures.

  12. Ground-based lidar for atmospheric boundary layer ozone measurements.

    Science.gov (United States)

    Kuang, Shi; Newchurch, Michael J; Burris, John; Liu, Xiong

    2013-05-20

    Ground-based lidars are suitable for long-term ozone monitoring as a complement to satellite and ozonesonde measurements. However, current ground-based lidars are unable to consistently measure ozone below 500 m above ground level (AGL) due to both engineering issues and high retrieval sensitivity to various measurement errors. In this paper, we present our instrument design, retrieval techniques, and preliminary results that focus on the high-temporal profiling of ozone within the atmospheric boundary layer (ABL) achieved by the addition of an inexpensive and compact mini-receiver to the previous system. For the first time, to the best of our knowledge, the lowest, consistently achievable observation height has been extended down to 125 m AGL for a ground-based ozone lidar system. Both the analysis and preliminary measurements demonstrate that this lidar measures ozone with a precision generally better than ±10% at a temporal resolution of 10 min and a vertical resolution from 150 m at the bottom of the ABL to 550 m at the top. A measurement example from summertime shows that inhomogeneous ozone aloft was affected by both surface emissions and the evolution of ABL structures.

  13. Evaluation of tropospheric SO2 retrieved from MAX-DOAS measurements in Xianghe, China

    Directory of Open Access Journals (Sweden)

    T. Wang

    2014-03-01

    Full Text Available Ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS measurements of sulfur dioxide (SO2 have been performed at the Xianghe station (39.75° N, 116.96° E located at ~50 km southeast of Beijing from March 2010 to February 2013. Tropospheric SO2 vertical profiles and corresponding vertical column densities (VCDs, retrieved by applying the Optimal Estimation Method to the MAX-DOAS observations, have been used to study the seasonal and diurnal cycles of SO2, in combination to correlative measurements from in situ instruments, as well as meteorological data. A marked seasonality was observed in both SO2 VCD and surface concentration, with a maximum in winter (February and a minimum in summer (July. This can be explained by the larger emissions in winter due to the domestic heating and more favorable meteorological conditions for the accumulation of SO2 close to the ground during this period. Wind speed and direction are also found to be two key factors in controlling the level of the SO2-related pollution at Xianghe. In the case of east or southwest wind, the SO2 concentration rises with the increase of the wind speed, since heavy polluting industries are located to the east and southwest of the station. In contrast, when wind comes from other directions, the stronger the wind, the less SO2 is observed. Regarding the diurnal cycle, the SO2 amount is larger in the early morning and late evening and lower at noon, in line with the diurnal variation of pollutant emissions and atmospheric stability. The observed diurnal cycles of MAX-DOAS SO2 surface concentration are also in very good agreement (correlation coefficient close to 0.9 with those from collocated in-situ data, demonstrating the reliability and robustness of our retrieval.

  14. Retrieval of tropospheric NO2 using the MAX-DOAS method combined with relative intensity measurements for aerosol correction

    Directory of Open Access Journals (Sweden)

    P. F. Levelt

    2010-10-01

    Full Text Available Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS is a technique to measure trace gas amounts in the lower troposphere from ground-based scattered sunlight observations. MAX-DOAS observations are especially suitable for validation of tropospheric trace gas observations from satellite, since they have a representative range of several kilometers, both in the horizontal and in the vertical dimension. A two-step retrieval scheme is presented here, to derive aerosol corrected tropospheric NO2 columns from MAX-DOAS observations. In a first step, boundary layer aerosols, characterized in terms of aerosol optical thickness (AOT, are estimated from relative intensity observations, which are defined as the ratio of the sky radiance at elevation α and the sky radiance in the zenith. Relative intensity measurements have the advantage of a strong dependence on boundary layer AOT and almost no dependence on boundary layer height. In a second step, tropospheric NO2 columns are derived from differential slant columns, based on AOT-dependent air mass factors. This two-step retrieval scheme was applied to cloud free periods in a twelve month data set of observations in De Bilt, The Netherlands. In a comparison with AERONET (Cabauw site a mean difference in AOT (AERONET minus MAX-DOAS of −0.01±0.08 was found, and a correlation of 0.85. Tropospheric-NO2 columns were compared with OMI-satellite tropospheric NO2. For ground-based observations restricted to uncertainties below 10%, no significant difference was found, and a correlation of 0.88.

  15. Validation of ACE and OSIRIS ozone and NO2 measurements using ground-based instruments at 80° N

    Directory of Open Access Journals (Sweden)

    A. Pazmino

    2012-05-01

    Full Text Available The Optical Spectrograph and Infra-Red Imager System (OSIRIS and the Atmospheric Chemistry Experiment (ACE have been taking measurements from space since 2001 and 2003, respectively. This paper presents intercomparisons between ozone and NO2 measured by the ACE and OSIRIS satellite instruments and by ground-based instruments at the Polar Environment Atmospheric Research Laboratory (PEARL, which is located at Eureka, Canada (80° N, 86° W and is operated by the Canadian Network for the Detection of Atmospheric Change (CANDAC. The ground-based instruments included in this study are four zenith-sky differential optical absorption spectroscopy (DOAS instruments, one Bruker Fourier transform infrared spectrometer (FTIR and four Brewer spectrophotometers. Ozone total columns measured by the DOAS instruments were retrieved using new Network for the Detection of Atmospheric Composition Change (NDACC guidelines and agree to within 3.2%. The DOAS ozone columns agree with the Brewer spectrophotometers with mean relative differences that are smaller than 1.5%. This suggests that for these instruments the new NDACC data guidelines were successful in producing a homogenous and accurate ozone dataset at 80° N. Satellite 14–52 km ozone and 17–40 km NO2 partial columns within 500 km of PEARL were calculated for ACE-FTS Version 2.2 (v2.2 plus updates, ACE-FTS v3.0, ACE-MAESTRO (Measurements of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation v1.2 and OSIRIS SaskMART v5.0x ozone and Optimal Estimation v3.0 NO2 data products. The new ACE-FTS v3.0 and the validated ACE-FTS v2.2 partial columns are nearly identical, with mean relative differences of 0.0 ± 0.2% and −0.2 ± 0.1% for v2.2 minus v3.0 ozone and NO2, respectively. Ozone columns were constructed from 14–52 km satellite and 0–14 km ozonesonde partial columns and compared with the ground-based total column measurements. The satellite-plus-sonde measurements agree

  16. Aerosol properties measured by MAX-DOAS in Gwangju during the DRAGON NE-Asia Campaign and comparison with AERONET and MODIS data sets

    Science.gov (United States)

    Chong, J.; Kim, Y. J.; Irie, H.; Kanaya, Y.; Shin, D.; Kim, K.; Lee, K.; Kim, J.; Song, C.

    2013-12-01

    Atmospheric aerosol interacts both directly and indirectly with the Earth's radiation budget and cause climate change. Aerosols also can act as sites for chemical reactions to take place (heterogeneous chemistry). In Asia, the Distributed Regional Aerosol Gridded Observation Networks (DRAGON) campaign for validation of satellite aerosol products and comparison/validation of ground-based aerosol retrievals had been conducted in Korea (DRAGON-Korea) from March to May 2012 for three months with 21 CIMEL sunphotometers, 2 Pandoras, a MAX-DOAS and a multichannel Raman Lidar system. Level 2.0 sunphotometer data (cloud screened and quality assured) at the Gwangju AERONET 321 site (35.2°N, 126.8°E, 52 m above sea level) were used for comparing aerosol optical depths (AODs) derived from the GIST MAX-DOAS observations. Information on O4 slant column densities at several different elevation angles is used to determine the atmospheric aerosol optical depth within the lower troposphere using the MAX-DOAS measurement data. Also, in order to evaluate satellite aerosol products, MODIS Terra satellite aerosol products were compared with the ground-based AERONET aerosol data at the 550 nm spectral wavelength. Significant linear relationship was resulted with a correlation coefficient larger than 0.66 between the sunphotometer measured AODs and GIST MAX-DOAS retrieved AODs values at 476 nm. There is significant linear relationship with a correlation coefficient larger than 0.79 between the sunphotometer measured AODs and MODIS Terra AODs at 550 nm. Aerosol extinction coefficient values from MAX-DOAS and Lidar system were compared. Results from sunphotometer and MAX-DOAS measurements can be used for validation of geostationary satellite measurement in the near future.

  17. Comparison of total ozone and erythemal UV data from OMI with ground-based measurements at Rome station

    Directory of Open Access Journals (Sweden)

    I. Ialongo

    2008-02-01

    Full Text Available Ground-based total ozone and surface UV irradiance measurements have been collected since 1992 using Brewer spectrophotometer and Erythemal Dose Rates (EDRs have been determined by a broad-band radiometer (model YES UVB-1 operational since 2000 at Rome station. The methodology to retrieve the EDR and the Erythemal Daily Dose (EDD from the radiometer observations is described. Ground-based measurements were compared with satellite-derived total ozone and UV data from the Ozone Monitoring Instrument (OMI. OMI, onboard the NASA EOS Aura spacecraft, is a nadir viewing spectrometer that provides total ozone and surface UV retrievals. The results of the validation exercise showed satisfactory agreement between OMI and Brewer total ozone data, for both OMI-TOMS and OMI-DOAS ozone alghorithms (biases of −1.8% and −0.7%, respectively. Regarding UV data, OMI data overestimate ground-based erythemally weighted data retrieved from both Brewer and YES Radiometer (biases about 20%, probably because of the effect of absorbing aerosols in an urban site such as Rome.

  18. Tropospheric NO2 and HCHO columns derived from ground-based MAX-DOAS system in Guangzhou, China and comparison with satellite observations: First results within the EU FP7 project MarcoPolo

    Science.gov (United States)

    Drosoglou, Theano; Kouremeti, Natalia; Bais, Alkis; Zyrichidou, Irene; Li, Shu; Balis, Dimitris; Huang, Zhonghui

    2016-04-01

    A miniature MAX-DOAS system, Phaethon, has been developed at the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki, Greece, for ground-based monitoring of column densities of atmospheric gases. Simultaneous measurements with two Phaethon systems at the city centre of Thessaloniki and at a rural location about 30 km away have shown that Phaethon provides NO2 and HCHO tropospheric column measurements of acceptable accuracy under both low and high air-pollution levels. Currently three systems have been deployed in areas with different pollution patterns to support air quality and satellite validation studies. In the framework of the EU FP7 Monitoring and Assessment of Regional air quality in China using space Observations, Project Of Long-term sino-european co-Operation, MarcoPolo project, one of the Phaethon systems has been installed since April 2015 in the Guangzhou region in China. Tropospheric NO2 and HCHO columns derived at Guangzhou during the first 10 months of operation are compared with corresponding retrievals from OMI/Aura and GOME-2/Metop-A and /Metop-B satellite sensors. The area is characterized by humid subtropical monsoon climate and cloud-free conditions are rather rare from early March to mid-October. Despite this limitation and the short period of operation of Phaethon in Guangzhou, the agreement between ground-based and satellite observations is generally good for both NO2 and HCHO. It appears that GOME-2 sensors seem to underestimate the tropospheric NO2, possibly due to their large pixel size, whereas the comparison with OMI data is better, especially when a small cloud fraction (< 0.2) is used for cloud screening.

  19. Ground-based Measurements of Next Generation Spectroradiometric Standard Stars

    Science.gov (United States)

    McGraw, John T.

    2013-01-01

    Accurate, radiometric standards are essential to the future of ground- and space-based astronomy and astrophysics. While astronomers tend to think of “standard stars” as available calibration sources, progress at NIST to accurately calibrate inexpensive, easy to use photodiode detectors as spectroradiometric standards from 200 nm to 1800 nm allows referencing astronomical measurements to these devices. Direction-, time-, and wavelength-dependent transmission of Earth’s atmosphere is the single largest source of error for ground-based radiometric measurement of astronomical objects. Measurements and impacts of atmospheric extinction - scattering and absorption - on imaging radiometric and spectroradiometric measurements are described. The conclusion is that accurate real-time measurement of extinction in the column of atmosphere through which standard star observations are made, over the spectral region being observed and over the field of view of the telescope are required. New techniques to directly and simultaneously measure extinction in the column of atmosphere through which observations are made are required. Our direct extinction measurement solution employs three small facility-class instruments working in parallel: a lidar to measure rapidly time variable transmission at three wavelengths with uncertainty of 0.25% per airmass, a spectrophotometer to measure rapidly wavelength variable extinction with sub-1% precision per nanometer resolution element from 350 to 1050nm, and a wide-field camera to measure angularly variable extinction over the field of view. These instruments and their operation will be described. We assert that application of atmospheric metadata provided by this instrument suite corrects for a significant fraction of systematic errors currently limiting radiometric precision, and provides a major step towards measurements that are provably dominated by random noise.

  20. Mobile mini-DOAS measurement of the outflow of NO2 and HCHO from Mexico City

    Directory of Open Access Journals (Sweden)

    L. Molina

    2009-08-01

    Full Text Available We here present the results from mobile measurements using two ground-based zenith viewing Differential Optical Absorption Spectroscopy (DOAS instruments. The measurement was performed in a cross-section of the plume from the Mexico City Metropolitan Area (MCMA on 10 March 2006 as part of the MILAGRO field campaign. The two instruments operated in the UV and the visible wavelength region respectively and have been used to derive the differential vertical columns of HCHO and NO2 above the measurement route. This is the first time the mobile mini-DOAS instrument has been able to measure HCHO, one of the chemically most important and interesting gases in the polluted urban atmosphere. Using a mass-averaged wind speed and wind direction from the WRF model the instantaneous flux of HCHO and NO2 has been calculated from the measurements and the results are compared to the CAMx chemical model. The calculated flux through the measured cross-section was 1.9 (1.5–2.2 kg/s of HCHO and 4.4 (4.0–5.0 kg/s of NO2 using the UV instrument and 3.66 (3.63–3.73 kg/s of NO2 using the visible light instrument. The modeled values from CAMx for the outflow of both NO2 and HCHO, 1.1 and 3.6 kg/s, respectively, show a reasonable agreement with the measurement derived fluxes.

  1. MAX-DOAS measurements of NO2, HCHO and CHOCHO at a rural site in Southern China

    Directory of Open Access Journals (Sweden)

    M. Shao

    2013-02-01

    Full Text Available We performed MAX-DOAS measurements during the PRIDE-PRD2006 campaign in the Pearl River Delta region (PRD, China, for 4 weeks in July 2006 at a site located 60 km north of Guangzhou. The vertical distributions of NO2, HCHO, and CHOCHO were independently retrieved by an automated iteration method. The NO2 mixing ratios measured by MAX-DOAS showed reasonable agreement with the simultaneous, ground based in-situ data. The tropospheric NO2 vertical column densities (VCDs observed by OMI on board EOS-Aura satellite were higher than with those by MAX-DOAS. The 3-D chemical transport model CMAQ overestimated the NO2 VCDs as well as the surface concentrations by about 65%. From this observation, a reduction of NOx emission strength in CMAQ seems to be necessary in order to well reproduce the NO2 observations. The average mixing ratios of HCHO and CHOCHO were 7 ppb and 0.4 ppb, respectively, higher than in other rural or semirural environments. The high ratio of 0.062 between CHOCHO and HCHO corresponds to the high VOCs reactivity and high HOx turnover rate consistent with other observations during the campaign.

  2. MAX-DOAS measurements of NO2, HCHO and CHOCHO at a rural site in Southern China

    Directory of Open Access Journals (Sweden)

    M. Shao

    2012-02-01

    Full Text Available We performed MAX-DOAS measurements during the PRIDE-PRD2006 campaign in the Pearl River Delta region (PRD, China, for 4 weeks in July 2006 at a site located 60 km north of Guangzhou. The vertical distributions of NO2, HCHO, and CHOCHO were independently retrieved by an automated iteration method. The MAX-DOAS measured NO2 mixing ratios showed reasonable agreement with the simultaneous, ground based in-situ data. While the tropospheric NO2 vertical column densities (VCDs observed by OMI on board EOS-Aura satellite agreed with those by MAX-DOAS, the 3-D chemical transport model CMAQ overestimated the NO2 VCDs as well as the surface concentrations by about 40%. From this observation, a reduction of NOX emission strength in CMAQ seems to be necessary in order to well reproduce the NO2 observations. The average mixing ratios of HCHO and CHOCHO were 12 ppb and 1.6 ppb, respectively, substantially higher than in other rural or semirural environments. The high ratio of 0.135 between CHOCHO and HCHO corresponds to the high VOCs reactivity and high HOX turnover rate consistent with other observations during the campaign.

  3. MAX-DOAS measurements of NO2, HCHO and CHOCHO at a rural site in Southern China

    Science.gov (United States)

    Li, X.; Brauers, T.; Hofzumahaus, A.; Lu, K.; Li, Y. P.; Shao, M.; Wagner, T.; Wahner, A.

    2013-02-01

    We performed MAX-DOAS measurements during the PRIDE-PRD2006 campaign in the Pearl River Delta region (PRD), China, for 4 weeks in July 2006 at a site located 60 km north of Guangzhou. The vertical distributions of NO2, HCHO, and CHOCHO were independently retrieved by an automated iteration method. The NO2 mixing ratios measured by MAX-DOAS showed reasonable agreement with the simultaneous, ground based in-situ data. The tropospheric NO2 vertical column densities (VCDs) observed by OMI on board EOS-Aura satellite were higher than with those by MAX-DOAS. The 3-D chemical transport model CMAQ overestimated the NO2 VCDs as well as the surface concentrations by about 65%. From this observation, a reduction of NOx emission strength in CMAQ seems to be necessary in order to well reproduce the NO2 observations. The average mixing ratios of HCHO and CHOCHO were 7 ppb and 0.4 ppb, respectively, higher than in other rural or semirural environments. The high ratio of 0.062 between CHOCHO and HCHO corresponds to the high VOCs reactivity and high HOx turnover rate consistent with other observations during the campaign.

  4. MAX-DOAS measurements of aerosol, HCHO, and NO2 over Los Angeles from an elevated mountaintop site

    Science.gov (United States)

    Cheung, Ross

    MAX-DOAS measurements of aerosol, HCHO, and NO2 over Los Angeles from an elevated mountaintop site. By. Ross Cheung. Doctor of Philosophy in Atmospheric and Oceanic Sciences. University of California, Los Angeles, 2016. Professor Jochen Stutz, Chair. Differential Optical Absorption Spectroscopy (DOAS) has become a popular technique for measuring atmospheric trace gases using UV/Vis narrow-band absorption features along a light path through the atmosphere. The UCLA Multi-Axis DOAS instrument (MAX-DOAS) is a ground-based spectrometer currently located at Mt. Wilson, California (1700 meters above sea level) that measures solar scattered light at various viewing elevation angles. Since May of 2010, it has been taking regular measurements of atmospheric pollutants in the boundary layer of the atmosphere in and above the Los Angeles Basin. This thesis presents the experimental setup and spectral retrievals, as well as results of our observations of measurements of NO2 and HCHO from Mt. Wilson. Radiative transfer modeling efforts of the deployment at Mt. Wilson will be presented, as well as our efforts to model and account for the effects of clouds and aerosols on MAX-DOAS measurements. Because of the unique challenges presented by aerosols in the ultraviolet and visible light region in a polluted urban boundary layer, new techniques were developed to account for and quantify these effects. Observations of path-integrated NO2 and HCHO, some of the primary precursors to ozone formation in the lower troposphere, as well as aerosol extinctions using the UCLA MAX-DOAS will be presented, and the advantages of a mountaintop measurement strategy will be discussed in light of the amount of vertical information that can be retrieved from this approach. The techniques developed to improve the optimal estimation of vertical aerosol extinction profiles and trace gas concentration profiles will be discussed. Finally, an application of these observations uses the ratio of HCHO/NO2 to

  5. Observing Tsunamis in the Ionosphere Using Ground Based GPS Measurements

    Science.gov (United States)

    Galvan, D. A.; Komjathy, A.; Song, Y. Tony; Stephens, P.; Hickey, M. P.; Foster, J.

    2011-01-01

    Ground-based Global Positioning System (GPS) measurements of ionospheric Total Electron Content (TEC) show variations consistent with atmospheric internal gravity waves caused by ocean tsunamis following recent seismic events, including the Tohoku tsunami of March 11, 2011. We observe fluctuations correlated in time, space, and wave properties with this tsunami in TEC estimates processed using JPL's Global Ionospheric Mapping Software. These TEC estimates were band-pass filtered to remove ionospheric TEC variations with periods outside the typical range of internal gravity waves caused by tsunamis. Observable variations in TEC appear correlated with the Tohoku tsunami near the epicenter, at Hawaii, and near the west coast of North America. Disturbance magnitudes are 1-10% of the background TEC value. Observations near the epicenter are compared to estimates of expected tsunami-driven TEC variations produced by Embry Riddle Aeronautical University's Spectral Full Wave Model, an atmosphere-ionosphere coupling model, and found to be in good agreement. The potential exists to apply these detection techniques to real-time GPS TEC data, providing estimates of tsunami speed and amplitude that may be useful for future early warning systems.

  6. Ground-based measurements of UV Index (UVI at Helwan

    Directory of Open Access Journals (Sweden)

    H. Farouk

    2012-12-01

    Full Text Available On October 2010 UV Index (UVI ground-based measurements were carried out by weather station at solar laboratory in NRIAG. The daily variation has maximum values in spring and summer days, while minimum values in autumn and winter days. The low level of UVI between 2.55 and 2.825 was found in December, January and February. The moderate level of UVI between 3.075 and 5.6 was found in March, October and November. The high level of UVI between 6.7 and 7.65 was found in April, May and September. The very high level of UVI between 8 and 8.6 was found in June, July and August. High level of radiation over 6 months per year including 3 months with a very high level UVI. According to the equation {UVI=a[SZA]b} the UVI increases with decreasing SZA by 82% on a daily scale and 88% on a monthly scale. Helwan exposure to a high level of radiation over 6 months per year including 3 months with a very high level UVI, so it is advisable not to direct exposure to the sun from 11 am to 2:00 pm.

  7. NO2 DOAS Measurements of Traffic Emissions by Chasing Cars

    Science.gov (United States)

    Zhu, Ying; Lipkowitsch, Ivo; Chan, Ka Lok; Bräu, Melanie; Wenig, Mark

    2016-04-01

    On this poster we present NO2 measurements using a Cavity-Enhanced DOAS on a measurement bus which we used to chase other vehicles to measure their NO2 emissions. Emissions of nitrogen oxides from on-road vehicles have received highly attention recently due to the increasing trend of ambient NOx level. It is particularly important to identify and quantify the direct emission and secondary formation of NO2 contributed by traffic emissions, in order to study the impact to the local air quality. We sampled on-road emissions in different environments and different driving conditions (e.g. urban, highway, different speeds). We analyse the data set in terms of spatial and temporal variability to search for temporal and spatial patterns. We present mean values sorted for different vehicle types, distance to the target car and travelling speeds to provide an emission data base from this measurement study.

  8. Emission Flux Measurement Error with a Mobile DOAS System and Application to NOx Flux Observations

    Science.gov (United States)

    Wu, Fengcheng; Li, Ang; Xie, Pinhua; Chen, Hao; Hu, Zhaokun; Zhang, Qiong; Liu, Jianguo; Liu, Wenqing

    2017-01-01

    Mobile differential optical absorption spectroscopy (mobile DOAS) is an optical remote sensing method that can rapidly measure trace gas emission flux from air pollution sources (such as power plants, industrial areas, and cities) in real time. Generally, mobile DOAS is influenced by wind, drive velocity, and other factors, especially in the usage of wind field when the emission flux in a mobile DOAS system is observed. This paper presents a detailed error analysis and NOx emission with mobile DOAS system from a power plant in Shijiazhuang city, China. Comparison of the SO2 emission flux from mobile DOAS observations with continuous emission monitoring system (CEMS) under different drive speeds and wind fields revealed that the optimal drive velocity is 30–40 km/h, and the wind field at plume height is selected when mobile DOAS observations are performed. In addition, the total errors of SO2 and NO2 emissions with mobile DOAS measurements are 32% and 30%, respectively, combined with the analysis of the uncertainties of column density, wind field, and drive velocity. Furthermore, the NOx emission of 0.15 ± 0.06 kg/s from the power plant is estimated, which is in good agreement with that from CEMS observations of 0.17 ± 0.07 kg/s. This study has significantly contributed to the measurement of the mobile DOAS system on emission from air pollution sources, thus improving estimation accuracy. PMID:28125054

  9. Emission Flux Measurement Error with a Mobile DOAS System and Application to NOx Flux Observations.

    Science.gov (United States)

    Wu, Fengcheng; Li, Ang; Xie, Pinhua; Chen, Hao; Hu, Zhaokun; Zhang, Qiong; Liu, Jianguo; Liu, Wenqing

    2017-01-25

    Mobile differential optical absorption spectroscopy (mobile DOAS) is an optical remote sensing method that can rapidly measure trace gas emission flux from air pollution sources (such as power plants, industrial areas, and cities) in real time. Generally, mobile DOAS is influenced by wind, drive velocity, and other factors, especially in the usage of wind field when the emission flux in a mobile DOAS system is observed. This paper presents a detailed error analysis and NOx emission with mobile DOAS system from a power plant in Shijiazhuang city, China. Comparison of the SO₂ emission flux from mobile DOAS observations with continuous emission monitoring system (CEMS) under different drive speeds and wind fields revealed that the optimal drive velocity is 30-40 km/h, and the wind field at plume height is selected when mobile DOAS observations are performed. In addition, the total errors of SO₂ and NO₂ emissions with mobile DOAS measurements are 32% and 30%, respectively, combined with the analysis of the uncertainties of column density, wind field, and drive velocity. Furthermore, the NOx emission of 0.15 ± 0.06 kg/s from the power plant is estimated, which is in good agreement with that from CEMS observations of 0.17 ± 0.07 kg/s. This study has significantly contributed to the measurement of the mobile DOAS system on emission from air pollution sources, thus improving estimation accuracy.

  10. Emission Flux Measurement Error with a Mobile DOAS System and Application to NOx Flux Observations

    Directory of Open Access Journals (Sweden)

    Fengcheng Wu

    2017-01-01

    Full Text Available Mobile differential optical absorption spectroscopy (mobile DOAS is an optical remote sensing method that can rapidly measure trace gas emission flux from air pollution sources (such as power plants, industrial areas, and cities in real time. Generally, mobile DOAS is influenced by wind, drive velocity, and other factors, especially in the usage of wind field when the emission flux in a mobile DOAS system is observed. This paper presents a detailed error analysis and NOx emission with mobile DOAS system from a power plant in Shijiazhuang city, China. Comparison of the SO2 emission flux from mobile DOAS observations with continuous emission monitoring system (CEMS under different drive speeds and wind fields revealed that the optimal drive velocity is 30–40 km/h, and the wind field at plume height is selected when mobile DOAS observations are performed. In addition, the total errors of SO2 and NO2 emissions with mobile DOAS measurements are 32% and 30%, respectively, combined with the analysis of the uncertainties of column density, wind field, and drive velocity. Furthermore, the NOx emission of 0.15 ± 0.06 kg/s from the power plant is estimated, which is in good agreement with that from CEMS observations of 0.17 ± 0.07 kg/s. This study has significantly contributed to the measurement of the mobile DOAS system on emission from air pollution sources, thus improving estimation accuracy.

  11. Two instruments based on differential optical absorption spectroscopy (DOAS) to measure accurate ammonia concentrations in the atmosphere

    NARCIS (Netherlands)

    Volten, H.; Bergwerff, J.B.; Haaima, M.; Lolkema, D.E.; Berkhout, A.J.C.; Hoff, G.R.; Potma, C.J.M.; Wichink Kruit, R.J.; Pul, van W.A.J.; Swart, D.P.J.

    2012-01-01

    We present two Differential Optical Absorption Spectroscopy (DOAS) instruments built at RIVM: the RIVM DOAS and the miniDOAS. Both instruments provide virtually interference-free measurements of NH3 concentrations in the atmosphere, since they measure over an open path, without suffering from inlet

  12. MAX-DOAS measurements of nitrogen dioxide at the high altitude sites Zugspitze (2964 m) and Pico Espejo (4765 m)

    Science.gov (United States)

    Schreier, Stefan F.; Richter, Andreas; Wittrock, Folkard; Burrows, John P.

    2015-04-01

    Spectral measurements at two mountain sites were performed with a MAX-DOAS (Multi AXis Differential Optical Absorption Spectroscopy) instrument from February to July 2003 (Zugspitze, Germany) and from March 2004 to November 2008 (Pico Espejo, Venezuela). Here, these measurements are used for the retrieval of slant column densities (SCDs) of nitrogen dioxide (NO2). While at the altitude of observations the NO2 levels are usually small, uplifting of anthropogenic emissions from the valley and in Venezuela also transport of emissions from biomass burning can lead to significant enhancements. Daily, weekly, and seasonal cycles of NO2 SCDs are shown for the two stations, linked to different meteorological conditions and compared between the two sites. In a next step, a preliminary approach to derive vertical column densities (VCDs) is presented. VCDs of NO2 from ground-based MAX-DOAS instruments provide useful information for the validation of satellite instruments such as SCIAMACHY, OMI, and GOME-2. Comparisons between ground-based and satellite-based NO2 VCDs are shown for selected periods.

  13. MAX-DOAS measurements of NO2 column densities in Vienna

    Science.gov (United States)

    Schreier, Stefan; Weihs, Philipp; Peters, Enno; Richter, Andreas; Ostendorf, Mareike; Schönhardt, Anja; Burrows, John P.; Schmalwieser, Alois

    2017-04-01

    In the VINDOBONA (VIenna horizontal aNd vertical Distribution OBservations Of Nitrogen dioxide and Aerosols) project, two Multi AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) systems will be set up at two different locations and altitudes in Vienna, Austria. After comparison measurements in Bremen, Germany, and Cabauw, The Netherlands, the first of the two MAX-DOAS instruments was set up at the University of Veterinary Medicine in the northeastern part of Vienna in December 2016. The instrument performs spectral measurements of visible scattered sunlight at defined horizontal and vertical viewing directions. From these measurements, column densities of NO2 and aerosols are derived by applying the DOAS analysis. First preliminary results are presented. The second MAX-DOAS instrument will be set up in April/May 2017 at the University of Natural Resources and Life Sciences in the northwestern part of Vienna. Once these two instruments are measuring simultaneously, small campaigns including car DOAS zenith-sky and tower DOAS off-axis measurements are planned. The main emphasis of this project will be on the installation and operation of two MAX-DOAS instruments, the improvement of tropospheric NO2 and aerosol retrieval, and the characterization of the horizontal, vertical, and temporal variations of tropospheric NO2 and aerosols in Vienna, Austria.

  14. MAX-DOAS measurements of tropospheric NO2 over San Salvador: preliminary results

    Science.gov (United States)

    Alberti, Carlos; Wagner, Thomas

    2015-04-01

    We present the first Multi-AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements at San Salvador. MAX-DOAS observes spectra of scattered sun light taken at different elevation angles. From the spectra the so called slant column density (SCD, the integrated trace gas concentration along the atmospheric light path) is derived. We quantify the dSCD of NO2 at different measurement conditions. From the measured NO2 SCDs we calculate the tropospheric vertical column density using the so called geometric approximation. The preliminary results of this MAX DOAS observations and the diurnal variation of the retrieved trace gas dSCDs will be presented. We also use the MAX-DOAS results for the validation of satellite observations.

  15. Nördlinger Ries campaign on Soil Emissions (NORISE) - DOAS measurements of NO2 and HCHO in an agricultural region

    Science.gov (United States)

    Zörner, Jan; Remmers, Julia; Dörner, Steffen; Wang, Yang; Eger, Philipp; Pöhler, Dennis; Behrendt, Thomas; Meixner, Franz; Penning de Vries, Marloes; Wagner, Thomas

    2016-04-01

    Soil is a major source of total nitrogen oxide (NOx = NO + NO2) emissions with a fraction of about 15% on a global basis. Soil emissions, stemming from bacterial emissions of NO, are controlled by abiotic and microbiological processes which themselves depend on ambient environmental conditions like soil type, moisture content, temperature as well as agricultural management practices such as fertilization. In recent laboratory experiments it was found that dry soils also exhibit enhanced emissions of several volatile organic compounds (VOC) including HCHO when first wetted. At present, studies on soil emissions in humid climates are limited to point samples and laboratory measurements. Thus, a campaign was organized that is dedicated to the analysis of trace gases which are potentially emitted from soils over an entire area using ground based mini-MAX-DOAS measurements. Since soil emissions are assumed to be highest from lands predominantly used for agriculture, the Nördlinger Ries in Bavaria, Germany, a 25 km wide circular plain formed by a meteor impact about 14.5 million years ago, was chosen which nowadays is dominated by arable land. The main objective of the NORISE campaign was to characterize trace gas levels in a highly agricultural environment. The time frame, consequently, covered a whole growing season from April 2014 to January 2015. The focus was on trace gases which can be measured using the DOAS approach in the UV/VIS spectral range, i.e. NO2 and HCHO, using two mini-MAX-DOAS instruments and one long-path DOAS instrument. The retrieved NO2 and HCHO column densities were examined for long-term variations over the entire growing season and short-term events which are both linked to environmental conditions like precipitation patterns and temperature changes. In addition, the analysis of soil samples taken from fields, distinguished between organic and conventional cultivation, gives further insights into soil activities. In this work, we present

  16. MAX-DOAS measurements of BrO and NO2 in the marine boundary layer

    Science.gov (United States)

    Leser, H.; Hönninger, G.; Platt, U.

    2003-05-01

    During a cruise of the German research vessel Polarstern from Bremerhaven, Germany to Capetown, South Africa in October 2000 mid latitude tropospheric bromine oxide (BrO) and nitrogen dioxide (NO2) abundances were investigated by ground-based MAX-DOAS (scattered light Multi Axis Differential Optical Absorption Spectroscopy). By comparing the slant column densities of absorbers measured at different elevation angles above the horizon (5° to 90°) it is possible to draw conclusions regarding the vertical distribution of the investigated absorbers (i.e., BrO and NO2). During a period of 2 days in the region north of the Canary Islands (around 35°N, 13°W) significant boundary layer BrO in the 1 ppt range was found. For the remaining time all data points ranged below the detection limit. Boundary layer NO2 was found near Europe and the Canary Islands with mixing ratios in the range of several ppb. In the remote marine air south west of Africa upper limits were derived.

  17. Ground-based DOAS observations of stratospheric O3, NO2, BrO and OClO at two different Antarctic sites

    Science.gov (United States)

    Yela, Margarita; Prados-Roman, Cristina; González, David; Puentedura, Olga; Navarro-Comas, Mónica; Ochoa, Héctor

    2017-04-01

    BrO and OClO are two of the most important halogen radicals involved in the ozone destruction. Although chlorine dioxide (OClO) does not participate directly in the destruction of ozone, observations of OClO are a good indicator for chlorine activation in the polar vortex based on the assumption of OClO concentration is linearly dependent on the ClO concentration. Accurate measurements of both components (BrO, OClO) are important to understand the halogen chemistry in the highly perturbed spring atmosphere in the polar regions, especially in Antarctica, where BrO and OClO ground-based measurements are very sparse and satellite observations have some limitations. Ground-based MAXDOAS observations were performed at Belgrano (78°S) and Marambio (64°S) by IAA/INTA during 2015. Stations are located close in longitude but separated 14° in latitude. Belgrano is representative of an in-polar vortex station during the winter-spring season until the vortex breakdown, while Marambio is frequently located in the edge region of the vortex. Simultaneous measurements of halogen species in both stations, using the same kind of instrumentation developed at INTA, are key factor to characterize the distribution of halogens, ozone and NO2 in two different although close scenarios and, also, to get a better understanding of the mechanisms that release halogens into the atmosphere. We report on the UV/Vis spectroscopic measurements performed during 2015 showing stratospheric BrO, OClO, NO2 and O3 above both stations. We present the seasonal evolution of these gases, as well as their role in the ozone depletion observed during the austral spring. The south polar vortex of 2015 was unusually stable and long-lived, so ozone depletion lasted longer than seen in recent years. A detailed analysis of the heat flux and of the position of the stations with respect to the polar vortex will be presented using equivalent latitude al 550 and 475 K isentropic levels.

  18. Monitoring shipping emissions in the German Bight using MAX-DOAS measurements

    Science.gov (United States)

    Seyler, André; Wittrock, Folkard; Kattner, Lisa; Mathieu-Üffing, Barbara; Peters, Enno; Richter, Andreas; Schmolke, Stefan; Burrows, John P.

    2017-09-01

    A 3-year time series of ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements of NO2 and SO2 on the island Neuwerk has been analyzed for contributions from shipping emissions. The island is located in the German Bight, close to the main shipping lane (at a distance of 6-7 km) into the river Elbe towards the harbor of Hamburg. Measurements of individual ship plumes as well as of background pollution are possible from this location. A simple approach using the column amounts of the oxygen molecule dimer or collision complex, O4, for the determination of the horizontal light path length has been applied to retrieve path-averaged volume mixing ratios. An excellent agreement between mixing ratios determined from NO2 retrievals in the UV and visible parts of the spectrum has been found, showing the validity of the approach. Obtained mixing ratios of NO2 and SO2 are compared to co-located in situ measurements showing good correlation on average but also a systematic underestimation by the MAX-DOAS O4 scaling approach. Comparing data before and after the introduction of stricter fuel sulfur content limits (from 1 to 0.1 %) on 1 January 2015 in the North Sea Emission Control Area (ECA), a significant reduction in SO2 levels is observed. For situations with wind from the open North Sea, where ships are the only local source of air pollution, the average mixing ratio of SO2 decreased by a factor of 8, while for NO2 in the whole time series from 2013 to 2016, no significant change in emissions was observed. More than 2000 individual ship emission plumes have been identified in the data and analyzed for the emission ratio of SO2 to NO2, yielding an average ratio of 0.3 for the years 2013/2014 and decreasing significantly, presumably due to lower fuel sulfur content, in 2015/2016. By sorting measurements according to the prevailing wind direction and selecting two angular reference sectors representative for wind from the open North Sea and

  19. A Tale of Two Cities - HSI-DOAS Measurements of Air Quality

    Science.gov (United States)

    Graves, Rosemarie; Leigh, Roland; Anand, Jasdeep; McNally, Michael; Lawrence, James; Monks, Paul

    2013-04-01

    Differential Optical Absorption Spectroscopy is now commonly used as an air quality measuring system; primarily through the measurements of nitrogen dioxide (NO2) both as a ground-based and satellite technique. CityScan is a Hemispherical Scanning Imaging Differential Optical Absorption Spectrometer (HSI-DOAS) which has been optimised to measure concentrations of nitrogen dioxide. CityScan has a 95˚ field of view (FOV) between the zenith and 5˚ below the horizon. Across this FOV there are 128 resolved elements which are measured concurrently, the spectrometer is rotated azimuthally 1˚ per second providing full hemispherical coverage every 6 minutes. CityScan measures concentrations of nitrogen dioxide over specific lines of sight and due to the extensive field of view of the instrument this produces measurements which are representative over city-wide scales. Nitrogen dioxide is an important air pollutant which is produced in all combustion processes and can reduce lung function; especially in sensitised individuals. These instruments aim to bridge the gap in spatial scales between point source measurements of air quality and satellite measurements of air quality offering additional information on emissions, transport and the chemistry of nitrogen dioxide. More information regarding the CityScan technique can be found at http://www.leos.le.ac.uk/aq/index.html. CityScan has been deployed in both London and Bologna, Italy during 2012. The London deployment took place as part of the large NERC funded ClearfLo project in January and July/August. CityScan was deployed in Bologna in June as part of the large EU project PEGASOS. Analysis of both of these campaigns of data will be used to give unprecedented levels of spatial information to air quality measurements whilst also showing the difference in air quality between a relatively isolated mega city and a smaller city situated in a very polluted region; in this case the Po Valley. Results from multiple City

  20. Ground-based MAX-DOAS observations of tropospheric aerosols, NO2, SO2 and HCHO in Wuxi, China, from 2011 to 2014

    Science.gov (United States)

    Wang, Yang; Lampel, Johannes; Xie, Pinhua; Beirle, Steffen; Li, Ang; Wu, Dexia; Wagner, Thomas

    2017-02-01

    We characterize the temporal variation and vertical distribution of nitrogen dioxide (NO2), sulfur dioxide (SO2), formaldehyde (HCHO) and aerosol extinction based on long-term multi-axis differential optical absorption spectroscopy (MAX-DOAS) observations from May 2011 to November 2014 in Wuxi, China. A new inversion algorithm (PriAM) is implemented to retrieve profiles of the trace gases (TGs) and aerosol extinction (AE) from the UV spectra of scattered sunlight recorded by the MAX-DOAS instrument. We investigated two important aspects of the retrieval process. We found that the systematic seasonal variation of temperature and pressure (which is regularly observed in Wuxi) can lead to a systematic bias of the retrieved aerosol profiles (e.g. up to 20 % for the AOD) if it is not explicitly considered. In this study we take this effect into account for the first time. We also investigated in detail the reason for the differences of tropospheric vertical column densities derived from either the geometric approximation or by the integration of the retrieved profiles, which were reported by earlier studies. We found that these differences are almost entirely caused by the limitations of the geometric approximation (especially for high aerosol loads). The results retrieved from the MAX-DOAS observations are compared with independent techniques not only under cloud-free sky conditions, but also under various cloud scenarios. Under most cloudy conditions (except fog and optically thick clouds), the trace gas results still show good agreements. In contrast, for the aerosol results, only near-surface AE could be still well retrieved under cloudy situations. After applying a quality control procedure, the MAX-DOAS data are used to characterize the seasonal, diurnal and weekly variations of NO2, SO2, HCHO and aerosols. A regular seasonality of the three trace gases is found, but not for aerosols. Similar annual variations of the profiles of the trace gases appear in different

  1. Ground-based measurement of surface temperature and thermal emissivity

    Science.gov (United States)

    Owe, M.; Van De Griend, A. A.

    1994-01-01

    Motorized cable systems for transporting infrared thermometers have been used successfully during several international field campaigns. Systems may be configured with as many as four thermal sensors up to 9 m above the surface, and traverse a 30 m transect. Ground and canopy temperatures are important for solving the surface energy balance. The spatial variability of surface temperature is often great, so that averaged point measurements result in highly inaccurate areal estimates. The cable systems are ideal for quantifying both temporal and spatial variabilities. Thermal emissivity is also necessary for deriving the absolute physical temperature, and measurements may be made with a portable measuring box.

  2. Retrieval of stratospheric and tropospheric BrO profiles and columns using ground-based zenith-sky DOAS observations at Harestua, 60° N

    Directory of Open Access Journals (Sweden)

    J. A. Pyle

    2007-09-01

    Full Text Available A profiling algorithm based on the optimal estimation method is applied to ground-based zenith-sky UV-visible measurements from Harestua, Southern Norway (60° N, 11° E in order to retrieve BrO vertical profiles. The sensitivity of the zenith-sky observations to the tropospheric BrO detection is increased by using for the spectral analysis a fixed reference spectrum corresponding to clear-sky noon summer conditions. The information content and retrieval errors are characterized and it is shown that the retrieved stratospheric profiles and total columns are consistent with correlative balloon and satellite observations, respectively. Tropospheric BrO columns are derived from profiles retrieved at 80° solar zenith angle during sunrise and sunset for the 2000–2006 period. They show a marked seasonality with mean column value ranging from 1.52±0.62×1013 molec/cm² in late winter/early spring to 0.92±0.38×1013 molec/cm² in summer, which corresponds to 1.0±0.4 and 0.6±0.2 pptv, respectively, if we assume that BrO is uniformly mixed in the troposphere. These column values are also consistent with previous estimates made from balloon, satellite, and other ground-based observations. Daytime (10:30 LT tropospheric BrO columns are compared to the p-TOMCAT 3-D tropospheric chemical transport model (CTM for the 2002–2003 period. p-TOMCAT shows a good agreement with the retrieved columns except in late winter/early spring where an underestimation by the model is obtained. This finding could be explained by the non-inclusion of sea-ice bromine sources in the current version of p-TOMCAT. Therefore the model cannot reproduce the possible transport of air-masses with enhanced BrO concentration due to bromine explosion events from the polar region to Harestua. The daytime stratospheric BrO columns are compared to the SLIMCAT stratospheric 3-D-CTM. The model run used in this study, which assumes 21.2 pptv for the Bry loading (15 pptv for long

  3. Ground-based intercomparison of two isoprene measurement techniques

    Directory of Open Access Journals (Sweden)

    E. Leibrock

    2003-01-01

    Full Text Available An informal intercomparison of two isoprene (C5H8 measurement techniques was carried out during Fall of 1998 at a field site located approximately 3 km west of Boulder, Colorado, USA. A new chemical ionization mass spectrometric technique (CIMS was compared to a well-established gas chromatographic technique (GC. The CIMS technique utilized benzene cation chemistry to ionize isoprene. The isoprene levels measured by the CIMS were often larger than those obtained with the GC. The results indicate that the CIMS technique suffered from an anthropogenic interference associated with air masses from the Denver, CO metropolitan area as well as an additional interference occurring in clean conditions. However, the CIMS technique is also demonstrated to be sensitive and fast. Especially after introduction of a tandem mass spectrometric technique, it is therefore a candidate for isoprene measurements in remote environments near isoprene sources.

  4. Dust optical properties retrieved from ground-based polarimetric measurements.

    Science.gov (United States)

    Li, Zhengqiang; Goloub, Philippe; Blarel, Luc; Damiri, Bahaiddin; Podvin, Thierry; Jankowiak, Isabelle

    2007-03-20

    We have systematically processed one year of sunphotometer measurements (recorded at five AERONET/PHOTONS sites in Africa) in order to assess mineral dust optical properties with the use of a new polarimetry-based algorithm. We consider the Cimel CE318 polarized sunphotometer version to obtain single-scattering albedo, scattering phase matrix elements F(11) and F(12) for dust aerosols selected with Angström exponents ranging from -0.05 to 0.25. Retrieved F(11) and F(12) differ significantly from those of spherical particles. The degree of linear polarization -F(12)/F(11) for single scattering of atmospheric total column dust aerosols in the case of unpolarized incident light is systematically retrieved for the first time to our knowledge from sunphotometer measurements and shows consistency with previous laboratory characterizations of nonspherical particles.

  5. Measurements of the gas emission from Holuhraun volcanic fissure eruption on Iceland, using Scanning DOAS instruments

    Science.gov (United States)

    Galle, Bo; Pfeffer, Melissa; Arellano, Santiago; Bergsson, Baldur; Conde, Vladimir; Barsotti, Sara; Stefansdottir, Gerdur; Ingvarsson, Thorgils; Bergsson, Bergur; Weber, Konradin

    2016-04-01

    On 31 August 2014 a volcanic fissure eruption started at Holuhraun on Iceland. The eruption lasted for 6 months and was by far the strongest source of sulfur dioxide in Europe over the last 230 years, with sustained emission rates exceeding 100 000 ton/day. This gas emission severely affected people within Iceland. Under the scope of the EU-project FUTUREVOLC, a project with 3.5 years duration, aiming at making Iceland a supersite for volcanological research as a European contribution to GEO, a version of the Scanning DOAS instrument that is adapted to high latitudes with low UV radiation and severe meteorological conditions was developed. Since the first day of the eruption several of these novel instruments were monitoring the SO2 emission from the eruption. A lot of work was needed to sustain this operation during the winter at a very remote site and under severe field conditions. At the same time the very high concentrations in the gas plume, in combination with bad meteorological conditions has required the development of novel methods to derive reliable flux estimates. A simple approach to make a first order correction for atmospheric scattering has been applied, as well as filtering of the dataset to remove the data most affected by scattering. Substantial work has also been made to obtain realistic information on plume height and wind speed. The data from these instruments are the only sustained ground-based measurements of this important gas emission event. In this presentation we will discuss the instrumental issues and evaluation procedures and present the latest version of the emission estimates made from our measurements.

  6. Multiple axis DOAS measurements for the retrieval of nitrogen dioxide and ozone vertical profiles in the presidential estate of Castel Porziano, Rome

    Science.gov (United States)

    Palazzi, Elisa; Petritoli, Andrea; Ravegnani, Fabrizio; Kostadinov, Ivan; Bortoli, Daniele; Masieri, Samuele; Premuda, Margherita; Giovanelli, Giorgio

    2007-10-01

    In this paper we present a methodology for the retrieval of the vertical profile of atmospheric gas pollutants in the boundary layer from ground based remote sensing measurements. Nitrogen dioxide (NO II) and ozone (O 3) slant column amounts have been obtained with the Differential Optical Absorption Spectroscopy (DOAS) technique used in the multiple axis configuration (the so called MAX-DOAS). The measurements have been carried out in the Presidential Estate at Castel Porziano (Rome) in the period from September to November 2006 in the frame of a programme started in 1994 for studying and monitoring the Estate's environment. The retrieval of information on the vertical profile of trace gases from their slant column amounts requires: (1) the simulation of the radiative transfer in the atmosphere for Air Mass Factor (AMF) calculation; (2) the application of inversion schemes. In this paper the vertical profiles of NO II and O 3 obtained from multiple axis DOAS measurements and their daily evolution are presented and discussed. The day under study is the 29th of October, 2006.

  7. NDACC UV-visible total ozone measurements: improved retrieval and comparison with correlative satellite and ground-based observations

    Directory of Open Access Journals (Sweden)

    F. Hendrick

    2010-08-01

    tropospheric ozone column being ignored by zonal climatologies. For those measurements sensitive to stratospheric temperature like TOMS, OMI-TOMS, Dobson and Brewer, the application of a temperature correction results in the almost complete removal of the seasonal difference with SAOZ, improving significantly the consistency between all ground-based and satellite total ozone observations.

  8. Atmospheric greenhouse gases retrieved from SCIAMACHY: comparison to ground-based FTS measurements and model results

    Directory of Open Access Journals (Sweden)

    O. Schneising

    2012-02-01

    Full Text Available SCIAMACHY onboard ENVISAT (launched in 2002 enables the retrieval of global long-term column-averaged dry air mole fractions of the two most important anthropogenic greenhouse gases carbon dioxide and methane (denoted XCO2 and XCH4. In order to assess the quality of the greenhouse gas data obtained with the recently introduced v2 of the scientific retrieval algorithm WFM-DOAS, we present validations with ground-based Fourier Transform Spectrometer (FTS measurements and comparisons with model results at eight Total Carbon Column Observing Network (TCCON sites providing realistic error estimates of the satellite data. Such validation is a prerequisite to assess the suitability of data sets for their use in inverse modelling.

    It is shown that there are generally no significant differences between the carbon dioxide annual increases of SCIAMACHY and the assimilation system CarbonTracker (2.00 ± 0.16 ppm yr−1 compared to 1.94 ± 0.03 ppm yr−1 on global average. The XCO2 seasonal cycle amplitudes derived from SCIAMACHY are typically larger than those from TCCON which are in turn larger than those from CarbonTracker. The absolute values of the northern hemispheric TCCON seasonal cycle amplitudes are closer to SCIAMACHY than to CarbonTracker and the corresponding differences are not significant when compared with SCIAMACHY, whereas they can be significant for a subset of the analysed TCCON sites when compared with CarbonTracker. At Darwin we find discrepancies of the seasonal cycle derived from SCIAMACHY compared to the other data sets which can probably be ascribed to occurrences of undetected thin clouds. Based on the comparison with the reference data, we conclude that the carbon dioxide data set can be characterised by a regional relative precision (mean standard deviation of the differences of about 2.2 ppm and a relative accuracy (standard deviation of the mean differences

  9. 3 dimensional distributions of NO2, CHOCHO, and HCHO measured by the University of Colorado 2D-MAX-DOAS during MAD-CAT

    Science.gov (United States)

    Ortega, Ivan; Sinreich, Roman; Volkamer, Rainer

    2014-05-01

    We present results of 2 dimensional Multi Axis-DOAS (2D-MAX-DOAS) measurements to infer 3-dimensional measurements of trace gases by characterizing boundary layer vertical profiles and near surface azimuth horizontal distribution of NO2 (14 angles covering 360°). We combine the established optimal estimation inversion with a new parameterization approach; the first method to derive NO2 tropospheric vertical profiles and boundary layer height and the second one to retrieve the azimuth horizontal distribution of near surface NO2 mixing ratios, both at multiple wavelengths (350 nm, 450 nm, and 560 nm). This was conducted for three cloud-free days in the framework of the intensive Multi Axis DOAS Comparison campaign for Aerosols and Trace gases (MAD-CAT) in Mainz, Germany 2013. By retrieving NO2 at multiple wavelengths range-resolved distributions of NO2 are derived using an 'Onion-peeling' approach, i.e., exploiting the fact that the optical path lengths at different wavelengths probe different horizontal air masses. We also measure glyoxal (CHOCHO) and formaldehyde (HCHO) distributions, and present to our knowledge the first 3-dimesional trace-gas distribution measurements of CHOCHO by a ground-based instrument. We expand the 2D-MAX-DOAS capabilities to calculate azimuth ratios of HCHO-to-NO2 (RFN) and CHOCHO-to-NO2 (RGN) to pinpoint volatile organic compound (VOC) oxidation chemistry and CHOCHO-to-HCHO (RGF) ratios as an indicator of biogenic and/or anthropogenic VOC emissions. The results of RFN correlate well with RGN and we identify azimuth variations that indicate gradients in the VOC/NOx chemistry that leads to O3 and secondary aerosol production. While there is a clear diurnal pattern in the RFN and RGN, no such variations are observed in the RGF, which shows rather constant values below 0.04 throughout the day, consistent with previous measurements, and indicative of urban air masses.

  10. Direct sun and airborne MAX-DOAS measurements of the collision induced oxygen complex, O2O2 absorption with significant pressure and temperature differences

    Directory of Open Access Journals (Sweden)

    E. Spinei

    2014-09-01

    Full Text Available The collision induced O2 complex, O2O2, is a very important trace gas in remote sensing measurements of aerosol and cloud properties. Some ground based MAX-DOAS measurements of O2O2 slant column density require correction factors of 0.75 ± 0.1 to reproduce radiative transfer modeling (RTM results for a near pure Rayleigh atmosphere. One of the potential causes of this discrepancy is believed to be uncertainty in laboratory measured O2O2 absorption cross section temperature and pressure dependence, due to difficulties in replicating atmospheric conditions in the laboratory environment. This paper presents direct-sun (DS and airborne multi-axis (AMAX DOAS measurements of O2O2 absorption optical depths under actual Earth atmospheric conditions in two wavelength regions (335–390 nm and 435–490 nm. DS irradiance measurements were made by the research grade MFDOAS instrument from 2007–2014 at seven sites with significant pressure (778–1013 hPa and O2O2 profile weighted temperature (247–275 K differences. Aircraft MAX-DOAS measurements were conducted by the University of Colorado AMAX-DOAS instrument on 29 January 2012 over the Southern Hemisphere subtropical Pacific Ocean. Scattered solar radiance spectra were collected at altitudes between 9 and 13.2 km, with O2O2 profile weighted temperatures of 231–244 K, and near pure Rayleigh scattering conditions. Due to the well defined DS air mass factors and extensively characterized atmospheric conditions during the AMAX-DOAS measurements, O2O2"pseudo" absorption cross sections, σ, are derived from the observed optical depths and estimated O2O2column densities. Vertical O2O2 columns are calculated from the atmospheric sounding temperature, pressure and specific humidity profiles. Based on the atmospheric DS observations, there is no pressure dependence of the O2O2 σ, within the measurement errors (3%. The two data sets are combined to derive peak σ temperature dependence of 360 and 477 nm

  11. MAX-DOAS measurements and satellite validation of tropospheric NO2 and SO2 vertical column densities at a rural site of North China

    Science.gov (United States)

    Jin, Junli; Ma, Jianzhong; Lin, Weili; Zhao, Huarong; Shaiganfar, Reza; Beirle, Steffen; Wagner, Thomas

    2016-05-01

    North China (NC), namely Huabei in Chinese, is one of the most severely polluted regions in China, and the air pollution issues in this region have received a worldwide attention. We performed ground-based Multi Axis Differential Absorption Spectroscopy (MAX-DOAS) measurements at Gucheng, (39°08‧N, 115°40‧E), a rural site of North China about 110 km southwest of Beijing, from September 2008 to September 2010. The tropospheric vertical column densities (VCDs) of NO2 and SO2 were retrieved using the so-called geometric approximation. The results show that the tropospheric NO2 and SO2 VCDs over NC have nearly the same seasonal variation pattern, with the maximum in winter and minimum in summer, while their diurnal variations are different. We also compared the tropospheric NO2 and SO2 VCDs from our MAX-DOAS measurements with several products of corresponding OMI (Ozone Monitoring Instrument) satellite observations. While in summer good agreement is found, the satellite observations systematically underestimate the tropospheric NO2 in winter over the polluted rural area of NC, probably mostly due to the so called aerosol shielding effect. In contrast, for SO2 no such clear conclusion can be drawn, probably owing to the larger uncertainties from MAX-DOAS and in particular satellite retrievals. This indicates that improvements of the retrieval algorithm for MAX-DOAS and off-line corrections of satellite measurements for the tropospheric SO2 VCDs should be given more emphasis in the future.

  12. BrO/SO2 molar ratios from scanning DOAS measurements in the NOVAC network

    Directory of Open Access Journals (Sweden)

    P. Lübcke

    2014-06-01

    Full Text Available The molar ratio of BrO to SO2 is, like other halogen/sulfur ratios, a possible precursor for dynamic changes in the shallow part of a volcanic system. While the predictive significance of the BrO/SO2 ratio has not been well constrained yet, it has the major advantage that this ratio can be readily measured using the remote-sensing technique differential optical absorption spectroscopy (DOAS in the UV. While BrO/SO2 ratios have been measured during several short-term field campaigns, this article presents an algorithm that can be used to obtain long-term time series of BrO/SO2 ratios from the scanning DOAS instruments of the Network for Observation of Volcanic and Atmospheric Change (NOVAC or comparable networks. Parameters of the DOAS retrieval of both trace gases are given. The influence of co-adding spectra on the retrieval error and influences of radiative transfer will be investigated. Difficulties in the evaluation of spectroscopic data from monitoring instruments in volcanic environments and possible solutions are discussed. The new algorithm is demonstrated by evaluating data from the NOVAC scanning DOAS systems at Nevado del Ruiz, Colombia, encompassing almost 4 years of measurements between November 2009 and end of June 2013. This data set shows variations of the BrO/SO2 ratio several weeks prior to the eruption on 30 June 2012.

  13. Comparison Between IASI/Metop-A and OMI/Aura Ozone Column Amounts with EUBREWNET Ground-Based Measurements

    Science.gov (United States)

    Lopez-Baeza, Ernesto

    2016-07-01

    This work addresses the comparison of {bf IASI (Infrared Atmospheric Sounding Interferometer)} on board Metop-A and {bf OMI (Ozone Monitoring Instrument)} on board Aura to several ground-based Brewer spectrophotometers belonging to the {bf European Brewer Network (EUBREWNET)} for the period September 2010 to December 2015. The focus of this study is to examine how well the satellite retrieval products capture the total ozone column amounts (TOC) at different latitudes and evaluate the different levels of Brewer spectrophotometer data. On this comparison Level 1, 1.5 and 2 Brewer data will be used to evaluate satellite data, where: 1) Level 1 Brewer data are the TOC calculated with the standard Brewer algorithm from the direct sun measurements; 2) Level 1.5 Brewer data are Level 1.0 observations filtered and corrected from instrumental issues: and 3) Level 2.0 Brewer data are 1.5 observations, but validated with a posteriori calibration. The IASI retrievals examined are operational IASI Level 2 products, version 5 from September 2010 to October 2014, and version 6 from October 2014 to December 2015, from {it EUMETSAT Data Centre}, while OMI retrievals are OMI-DOAS TOC products extracted from the {it NASA Goddard Earth Sciences Data and Information Services Center (GES DISC)}. The differences and their implications for the retrieved products will be discussed and, in order to evaluate the quality and sensitivity of each product, special attention will be put on analyzing the instrumental errors from these different measurement techniques. Furthermore, those parameters that could affect the comparison of the different datasets such as the different viewing geometry, the satellite data vertical sensitivity, cloudiness conditions, spectral region used for retrievals, and so on, will be analyzed in detail.

  14. Vertical profiles of pollutant gases measured with passive DOAS in the Po Valley devoted to satellite and chemical model data comparison

    Science.gov (United States)

    Masieri, S.; Petritoli, A.; Kostadinov, I.; Bortoli, D.; Premuda, M.; Ravegnani, F.; Giovanelli, G.

    2009-04-01

    In the frame of QUITSAT Italian pilot project (Air QUality with InTegration of ground-based and SAtellite measurement and chemical Transport model), two field campaigns were made in S.Pietro Capofiume (44.65˚ N; 11.37˚ E) and Bologna (44.52˚ N; 11.34˚ E) to provide concentration of ground particular matter and gaseous pollutants, namely nitrogen dioxide (NO2), formaldehyde (HCHO), sulphur dioxide (SO2) and ozone (O3). The aim of the campaigns was to provide experimental data need for tests and improvement of algorithms developed for integration of satellite and ground-based data together with chemical transport model data in order to retrieve air quality in the QUITSAT domain. Ground based measurements were carried out within a network of in-situ analyser in the Po Valley and with a scanning multi-axis DOAS (Differential Optical Absorption Spectroscopy) spectrometer system developed at ISAC-CNR institute [1], in collaboration with Geophysics Center of Evora [2]. TropoGAS (TROPOspheric Gas Analyser Spectrometer) spectrometer permits active and passive DOAS measurements at the chosen angles: α =1,2,3,6,10,15,20,90 and another measurement was taken along the sun direction. A Xenon lamp installed at 1km of distance from spectrometer was used as a reference concentration measured in the same place, and these values shows good agreement with in-situ analyser concentration. Gas spectral absorption was evaluated with DOAS [3] algorithms from 430 to 500 nm in two different windows: first from 436 to 460 nm for NO2 retrieval; second from 460 to 500 nm for O4 (best line at 477 nm) and NO2. Air Mass Factor (AMF) was calculated using PROMSAR (PROcessing of Multi-Scattered Atmospheric Radiation) model [4], that is a backward Montecarlo Radiative Transfer Model (RTM). An apposite inversion method [5][6], was applied to retrieve profiles of the target gases from their Slant Column Densities (SCD), using advanced approaches involving measurement of the atmospheric O4

  15. Ozone columns obtained by ground-based remote sensing in Kiev for Aura Ozone Measuring Instrument validation

    Science.gov (United States)

    Shavrina, A. V.; Pavlenko, Y. V.; Veles, A.; Syniavskyi, I.; Kroon, M.

    2007-12-01

    Ground-based observations with a Fourier transform spectrometer in the infrared region (FTIR) were performed in Kiev (Ukraine) during the time frames August-October 2005 and June-October 2006 within the Ozone Monitoring Instrument (OMI) validation project 2907 entitled "OMI validation by ground based remote sensing: ozone columns and profiles" in the frame of the international European Space Agency/Netherlands Agency for Aerospace Programmes/Royal Dutch Meteorological Institute OMI Announcement of Opportunity effort. Ozone column data for 2005 were obtained by modeling the ozone spectral band at 9.6 μm with the radiative transfer code MODTRAN3.5. Our total ozone column values were found to be lower than OMI Differential Optical Absorption Spectroscopy (DOAS) total ozone column data by 8-10 Dobson units (DU, 1 DU = 0.001 atm cm) on average, while our observations have a relatively small standard error of about 2 DU. Improved modeling of the ozone spectral band, now based on HITRAN-2004 spectral data as calculated by us, moves our results toward better agreement with the OMI DOAS total ozone column data. The observations made during 2006 with a modernized FTIR spectrometer and higher signal-to-noise ratio were simulated by the MODTRAN4 model computations. For ozone column estimates the Aqua Atmospheric Infrared Sounder satellite water vapor and temperature profiles were combined with the Aura Microwave Limb Sounder stratospheric ozone profiles and Tropospheric Emission Monitoring Internet Service-Koninklijk Nederlands Meteorologisch Instituut climatological profiles to create a priori input files for spectral modeling. The MODTRAN4 estimates of ozone columns from the 2006 observations compare rather well with the OMI total ozone column data: standard errors are of 1.11 DU and 0.68 DU, standard deviation are of 8.77 DU and 5.37 DU for OMI DOAS and OMI Total Ozone Mapping Spectrometer, respectively.

  16. Ground-Based Lidar Measurements During the CALIPSO and Twilight Zone (CATZ) Campaign

    Science.gov (United States)

    Berkoff, Timothy; Qian, Li; Kleidman, Richard; Stewart, Sebastian; Welton, Ellsworth; Li, Zhu; Holbem, Brent

    2008-01-01

    The CALIPSO and Twilight Zone (CATZ) field campaign was carried out between June 26th and August 29th of 2007 in the multi-state Maryland-Virginia-Pennsylvania region of the U.S. to study aerosol properties and cloud-aerosol interactions during overpasses of the CALIPSO satellite. Field work was conducted on selected days when CALIPSO ground tracks occurred in the region. Ground-based measurements included data from multiple Cimel sunphotometers that were placed at intervals along a segment of the CALIPSO ground-track. These measurements provided sky radiance and AOD measurements to enable joints inversions and comparisons with CALIPSO retrievals. As part of this activity, four ground-based lidars provided backscatter measurements (at 523 nm) in the region. Lidars at University of Maryland Baltimore County (Catonsville, MD) and Goddard Space Flight Center (Greenbelt, MD) provided continuous data during the campaign, while two micro-pulse lidar (MPL) systems were temporarily stationed at various field locations directly on CALIPSO ground-tracks. As a result, thirteen on-track ground-based lidar observations were obtained from eight different locations in the region. In some cases, nighttime CALIPSO coincident measurements were also obtained. In most studies reported to date, ground-based lidar validation efforts for CALIPSO rely on systems that are at fixed locations some distance away from the satellite ground-track. The CATZ ground-based lidar data provide an opportunity to examine vertical structure properties of aerosols and clouds both on and off-track simultaneously during a CALIPSO overpass. A table of available ground-based lidar measurements during this campaign will be presented, along with example backscatter imagery for a number of coincident cases with CALIPSO. Results indicate that even for a ground-based measurements directly on-track, comparisons can still pose a challenge due to the differing spatio-temporal properties of the ground and satellite

  17. Inhomogeneity of NO2 over Yokosuka, an urban site in Japan observed by MAX-DOAS

    Science.gov (United States)

    Takashima, H.; Irie, H.; Kanaya, Y.

    2010-12-01

    Since April 2007, continuous NO2 profile observations have been performed using ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) at Yokosuka (35.32°N, 139.65°E), an urban site in Japan. MAX-DOAS is a passive remote sensing technique using scatted visible and ultraviolet solar radiation at several elevation angles. It has been suggested that MAX-DOAS can allow us to retrieve vertical information on not only NO2 but also aerosol, H2 O, HCHO, and CHOCHO. In this study, we compare mean NO2 concentrations for 0-1 km layer derived from MAX-DOAS and surface values taken by in-situ measurements near the source region. Comparisons showed generally good agreement on seasonal, intraseasonal and diurnal time scales. However, MAX-DOAS NO2 was less than that of in-situ (surface) values particularly at higher surface values. Since the MAX-DOAS telescope used in this study was set in the azimuth direction of sea, it is expected that MAX-DOAS shows low values when the measured air masses contain information over ocean. To confirm this, MAX-DOAS NO2 was generally low when air was advected from sea. Also, for air masses measured by MAX-DOAS, the horizontal distance (depth) was estimated from the box air mass factor. We find that the concentration was generally higher when the horizontal distance was shorter, as expected. On the other hand, particularly low NO2 concentration was sometimes observed only in MAX-DOAS NO2 . For these cases, the air mass was likely vertically well mixed and the horizontal distance was long. Attention should be paid to consider such inhomogeneity to compare the MAX-DOAS measurement with in-situ surface measurement as well as to validate satellite-derived NO2 column amounts by MAX-DOAS over urban areas.

  18. Ground based measurements of the gas emission from the Holuhraun volcanic fissure eruption on Iceland 2014/2015

    Science.gov (United States)

    Galle, Bo; Arellano, Santiago; Conde, Vladimir; Pfeffer, Melissa; Barsotti, Sara; Stefansdottir, Gerður; Bergsson, Baldur; Bergsson, Bergur; Ingvarsson, Thorgils; Weber, Konradin

    2015-04-01

    The since 31 August 2014 ongoing volcanic eruption at Holuhraun on Iceland is by far the strongest source of sulfur dioxide in Europe over the last 230 years with sustained emission rates exceeding 100 000 ton/day. This gas emission severely affects local population and has become a concern also for air traffic. The eruption has in December continued at constant pace for 3.5 months. Three scenarios are envisaged for the future; (1) the eruption stops, (2) the fissure extends under the Vattnajökul glacier and (3) Bardarbunga volcano erupts. The two later scenarios will cause increased gas emission, severe ash emissions and extended flooding. Under the scope of the EU-project FUTUREVOLC, a project with 3.5 years duration, aiming at making Iceland a supersite for volcanological research as a European contribution to GEO, we are developing a version of the Scanning DOAS instrument that is adapted to high latitudes with low UV radiation and severe meteorological conditions. Since the first day of the eruption several of these novel instruments has been monitoring the SO2 emission from the eruption. Data from our instruments are still after 3.5 months the only sustained ground-based monitoring of this gas emission. A lot of work is however needed to sustain this operation at a very remote site and under severe field conditions. At the same time the very high concentrations in the gas plume, in combination with bad meteorological conditions require the development of novel methods to derive reliable flux estimates. In this presentation we will discuss the instrumental issues and present the latest version of the emission estimates made from our measurements.

  19. Validation of Aura OMI by Aircraft and Ground-Based Measurements

    Science.gov (United States)

    McPeters, R. D.; Petropavlovskikh, I.; Kroon, M.

    2006-12-01

    Both aircraft-based and ground-based measurements have been used to validate ozone measurements by the OMI instrument on Aura. Three Aura Validation Experiment (AVE) flights have been conducted, in November 2004 and June 2005 with the NASA WB57, and in January/February 2005 with the NASA DC-8. On these flights, validation of OMI was primarily done using data from the CAFS (CCD Actinic Flux Spectroradiometer) instrument, which is used to measure total column ozone above the aircraft. These measurements are used to differentiate changes in stratospheric ozone from changes in total column ozone. Also, changes in ozone over high clouds measured by OMI were checked in a flight over tropical storm Arlene on a flight on June 11th. Ground-based measurements were made during the SAUNA campaign in Sodankyla, Finland, in March and April 2006. Both total column ozone and the ozone vertical distribution were validated.

  20. Measurements of NO{sub 2} using MAX-DOAS observations of sun-illuminated targets

    Energy Technology Data Exchange (ETDEWEB)

    Javed, Umar; Kirk, Henning; Richter, Andreas; Schoenhardt, Anja; Wittrock, Folkard; Burrows, John P. [Institut fuer Umweltphysik, Universitaet Bremen (Germany)

    2009-07-01

    Nitrogen oxide radicals (NO+NO{sub 2}) are important trace gases in the atmosphere. They originate from combustion processes, lightning and soil emissions and largely control the tropospheric ozone production Since several decades it is possible to measure NO{sub 2} with different techniques. However, for the spatial distribution in the troposphere considerable uncertainty exists. Here we present measurements of NO{sub 2} on and close to the campus of the University of Bremen applying a novel technique: Topographic Target Light scattering Differential Optical Absorption Spectroscopy (ToTaL-DOAS, Frins et al.). The basic idea is to collect scattered sunlight reflected from natural and artificial targets (e.g. high buildings) at different distances from the measuring device. Then recorded spectra are analyzed for NO{sub 2} applying the DOAS method. Simple geometric treatments of the light-path reveal NO{sub 2} concentrations in the boundary layer as a final data set. This study presents NO{sub 2} data in 2008 in the surrounding of the University of Bremen. In addition for some days the ZARM Drop Tower has been used as illuminated target to investigate the vertical distribution of NO{sub 2}. Selected data sets have been compared to complementary measurements of the regular iup Bremen MAX-DOAS setup and to the Bremian BLUES air pollution network.

  1. Comparison of NO2 vertical profiles from satellite and ground based measurements over Antarctica

    OpenAIRE

    Kulkarni, Pavan; Bortoli, Daniele; Costa, Maria João; Silva, Ana Maria; Ravegnani, Fabrizio; Giovanelli, Giorgio

    2011-01-01

    The Intercomparison of nitrogen dioxide (NO2) vertical profiles, derived from the satellite based HALogen Occultation Experiment (HALOE) measurements and from the ground based UV-VIS spectrometer GASCOD (Gas Analyzer Spectrometer Correlating Optical Differences) observations at the Mario Zucchelli Station (MZS), in Antarctica, are done for the first time. It is shown here that both datasets are in good agreement showing the same features in terms of magnitude, profile structure, a...

  2. Intercomparison of ground-based ozone and NO2 measurements during the MANTRA 2004 campaign

    Directory of Open Access Journals (Sweden)

    K. Strong

    2007-11-01

    Full Text Available The MANTRA (Middle Atmosphere Nitrogen TRend Assessment 2004 campaign took place in Vanscoy, Saskatchewan, Canada (52° N, 107° W from 3 August to 15 September, 2004. In support of the main balloon launch, a suite of five zenith-sky and direct-Sun-viewing UV-visible ground-based spectrometers was deployed, primarily measuring ozone and NO2 total columns. Three Fourier transform spectrometers (FTSs that were part of the balloon payload also performed ground-based measurements of several species, including ozone. Ground-based measurements of ozone and NO2 differential slant column densities from the zenith-viewing UV-visible instruments are presented herein. They are found to partially agree within NDACC (Network for the Detection of Atmospheric Composition Change standards for instruments certified for process studies and satellite validation. Vertical column densities of ozone from the zenith-sky UV-visible instruments, the FTSs, a Brewer spectrophotometer, and ozonesondes are compared, and found to agree within the combined error estimates of the instruments (15%. NO2 vertical column densities from two of the UV-visible instruments are compared, and are also found to agree within combined error (15%.

  3. Retrieval of CHOCHO from MAX-DOAS measurements in the Beijing area

    Science.gov (United States)

    Hendrick, Francois; Lerot, Christophe; Stavrakou, Trissevgeni; De Smedt, Isabelle; Fayt, Caroline; Gielen, Clio; Hermans, Christian; Müller, Jean-Francois; Pinardi, Gaia; Van Roozendael, Michel

    2015-04-01

    Glyoxal (CHOCHO) is one of the most important carbonyl compounds in the atmosphere. It is produced mainly by the oxidation of biogenic and anthropogenic non-methane volatile organic compounds (NMVOCs) which participate to the formation of tropospheric ozone and secondary organic aerosols. CHOCHO is also directly released by biomass burning and fossil fuel combustion. Measuring this species is therefore of major importance for air quality monitoring, especially given the scarcity of available CHOCHO observational data sets. In this presentation, CHOCHO vertical profiles and corresponding column densities are retrieved from MAX-DOAS measurements in the Beijing city center and at the suburban site of Xianghe located at 60km East of Beijing. The periods covered by the observations are June 2008-April 2009 in Beijing and March 2010-December 2014 in Xianghe. We first investigate the capability of the MAX-DOAS technique to measure this species in such highly-polluted environment. Then the diurnal and seasonal cycles of CHOCHO near-surface concentrations and vertical column densities as well as the corresponding CHOCHO/HCHO ratios are examined on a long-term basis at both locations. The CHOCHO/HCHO ratios are derived from MAX-DOAS HCHO vertical profiles retrieved in parallel to the CHOCHO profiles. These diurnal and seasonal cycles are further assessed using simulations from the 3D-CTM IMAGES and observations from the OMI and GOME-2 satellite nadir instruments. The impact of these results on our knowledge about the CHOCHO budget is discussed.

  4. Multiple Sparse Measurement Gradient Reconstruction Algorithm for DOA Estimation in Compressed Sensing

    Directory of Open Access Journals (Sweden)

    Weijian Si

    2015-01-01

    Full Text Available A novel direction of arrival (DOA estimation method in compressed sensing (CS is proposed, in which the DOA estimation problem is cast as the joint sparse reconstruction from multiple measurement vectors (MMV. The proposed method is derived through transforming quadratically constrained linear programming (QCLP into unconstrained convex optimization which overcomes the drawback that l1-norm is nondifferentiable when sparse sources are reconstructed by minimizing l1-norm. The convergence rate and estimation performance of the proposed method can be significantly improved, since the steepest descent step and Barzilai-Borwein step are alternately used as the search step in the unconstrained convex optimization. The proposed method can obtain satisfactory performance especially in these scenarios with low signal to noise ratio (SNR, small number of snapshots, or coherent sources. Simulation results show the superior performance of the proposed method as compared with existing methods.

  5. Synergetic ground-based methods for remote measurements of ozone vertical profiles

    Science.gov (United States)

    Timofeyev, Yuriy; Kostsov, Vladimir; Virolainen, Yana

    2013-05-01

    The technique of combining ground-based measurements in infrared and microwave spectral regions in order to achieve higher accuracy of ozone profile retrieval in extensive altitude ranges is described and analyzed. The information content, errors, altitude ranges and vertical resolution of ozone profile retrieval have been studied on the basis of numerical simulation of synergetic experiments. Optimal conditions of measurements are defined and requirements to additional information are formulated. The first results on ozone vertical profile retrieval using groundbased measurements of FTIR-spectrometer and microwave radiometer are given.

  6. Effect of spectral resolution on the measurement of monoaromatic hydrocarbons by DOAS

    Institute of Scientific and Technical Information of China (English)

    PENG Fumin; XIE Pinhua; ZHANG Yinghua; ZHU Yanwu; SI Fuqi; LIU Wenqing; WANG Junde

    2008-01-01

    The excellent response characteristics and detection sensitivity with much lower operational cost and the capability to discriminate between the isomer of some monoaromatic hydrocarbons (MAHCs) make differential optical absorption spectroscopy (DOAS) a powerful tool to trace concentration variation of MAHCs. But due to the similarity in chemical structure, those MAHCs have the similar overlapped characteristic absorption structures, which make the selection of instrumental parameter critical to the accurate detection of MAHCs. Firstly, the spectral resolution used in DOAS system determines the nonlinear absorption of O2 and the mass dependence of characteristic absorption structure; thereby it determines the effect of elimination error of O2 absorption in the atmospheric spectra for the detection of MAHCs. Secondly, spectral resolution determines the differential absorption characteristics of twelve MAHCs representing major constituents in technical solvents used in the automobile industry and the interference of spectral overlapping. Thirdly, the spectral resolution determines the sensitivity, time resolution and linear range. So the spectral resolution range with the best ratio of signal to noise is used to determine the most suitable spectral resolution range, as well as the spectral resolution range that ensure the characteristic absorption structure of MAHCs and the minimization of O2 absorption interference. Finally, 0. 15-0. 16 nm (FWHM: full width at half maximum) is assumed to be closest to the optimum spectral resolution and it is confirmed by the results of practical measurement of MAHCs by DOAS.

  7. A new DOAS instrument on long-distance IAGOS-CARIBIC flights and airborne DOAS applications

    Science.gov (United States)

    Penth, Lara; Frieß, Udo; Pöhler, Denis; Platt, Ulrich; Zahn, Andreas

    2017-04-01

    Within the IAGOS-CARIBIC project airborne DOAS (Differential Optical Absorption Spectroscopy) measurements of atmospheric trace gases are performed aboard a commercial long range passenger aircraft from Lufthansa since 2005. They provide a unique dataset for episodic, long-term and seasonal observations. The DOAS instrument is the only remote sensing technique aboard. DOAS is a well-established remote sensing technique to retrieve trace gas columns in the atmosphere from scattered light spectra of the sun. A series of trace gas species can be observed simultaneously, including nitrogen dioxide (NO2), sulphur dioxide (SO2), bromine oxide (BrO), nitrous acid (HONO), formaldehyde (HCHO) and ozone (O3). Since DOAS is a contact-free measurement technique, it is specially well suited for measuring highly reactive trace gases. It is widely used on different platforms and the airborne DOAS measurements are filling the gap between ground-based measurements and satellite data. The CARIBIC DOAS instrument is divided into an instrument unit within the CARIBIC container in the cargo hold of the aircraft, a telescope unit, which is specially designed for the permanently mounted pylon underneath the aircraft, and fiber optics in between. The instrument unit consists of three temperature stabilized spectrometers and the readout and control electronics. The telescope unit contains three telescopes, which observe scattered sunlight to the right under the elevation angles of +10˚ , -10˚ and -82˚ (nadir) relative to the horizon. This measurement geometry allows the separation of boundary layer, free tropospheric and stratospheric trace gas columns along the flight track. A new DOAS instrument was designed and installed in 2016 (first flights expected from March 2017) to improve the detection limits of NO2, SO2, BrO, HCHO, HONO, O3 and O4. Furthermore, an extended wavelength range allows to measure in addition iodine monoxide (a potentially important oxidant in the free troposphere

  8. Ground-based SMART-COMMIT Measurements for Studying Aerosol and Cloud Properties

    Science.gov (United States)

    Tsay, Si-Chee

    2008-01-01

    From radiometric principles, it is expected that the retrieved properties of extensive aerosols and clouds from reflected/emitted measurements by satellite (and/or aircraft) should be consistent with those retrieved from transmitted/emitted radiance observed at the surface. Although space-borne remote sensing observations cover large spatial domain, they are often plagued by contamination of surface signatures. Thus, ground-based in-situ and remote-sensing measurements, where signals come directly from atmospheric constituents, the sun, and/or the Earth-atmosphere interactions, provide additional information content for comparisons that confirm quantitatively the usefulness of the integrated surface, aircraft, and satellite data sets. The development and deployment of SMARTCOMMIT (Surface-sensing Measurements for Atmospheric Radiative Transfer - Chemical, Optical & Microphysical Measurements of In-situ Troposphere) mobile facilities are aimed for the optimal utilization of collocated ground-based observations as constraints to yield higher fidelity satellite retrievals and to determine any sampling bias due to target conditions. To quantify the energetics of the surface-atmosphere system and the atmospheric processes, SMART-COMMIT instruments fall into three categories: flux radiometer, radiance sensor and in-situ probe. In this paper, we will demonstrate the capability of SMART-COMMIT in recent field campaigns (e.g., CRYSTAL-FACE, UAE 2, BASEASIA, NAMMA) that were designed and executed to study the compelling variability in temporal scale of both anthropogenic and natural aerosols (e.g., biomass-burning smoke, airborne dust) and cirrus clouds. We envision robust approaches in which well-collocated ground-based measurements and space-borne observations will greatly advance our knowledge of extensive aerosols and clouds.

  9. Ground-based microwave measuring of middle atmosphere ozone and temperature profiles during sudden stratospheric warming

    Science.gov (United States)

    Feigin, A. M.; Shvetsov, A. A.; Krasilnikov, A. A.; Kulikov, M. Y.; Karashtin, D. A.; Mukhin, D.; Bolshakov, O. S.; Fedoseev, L. I.; Ryskin, V. G.; Belikovich, M. V.; Kukin, L. M.

    2012-12-01

    We carried out the experimental campaign aimed to study the response of middle atmosphere on a sudden stratospheric warming in winter 2011-2012 above Nizhny Novgorod, Russia (56N, 44E). We employed the ground-based microwave complex for remote sensing of middle atmosphere developed in the Institute of Applied Physics of the Russian Academy of Science. The complex combines two room-temperature radiometers, i.e. microwave ozonometer and the stratospheric thermometer. Ozonometer is a heterodyne spectroradiometer, operating in a range of frequencies that include the rotation transition of ozone molecules with resonance frequency 110.8 GHz. Operating frequency range of the stratospheric thermometer is 52.5-5.4 GHz and includes lower frequency edge of 5 mm molecular oxygen absorption bands and among them two relatively weak lines of O2 emission. Digital fast Fourier transform spectrometers developed by "Acqiris" are employed for signal spectral analysis. The spectrometers have frequency range 0.05-1 GHz and realizes the effective resolution about 61 KHz. For retrieval vertical profiles of ozone and temperature from radiometric data we applied novel method based on Bayesian approach to inverse problem solution, which assumed a construction of probability distribution of the characteristics of retrieved profiles with taking into account measurement noise and available a priori information about possible distributions of ozone and temperature in the middle atmosphere. Here we introduce the results of the campaign in comparison with Aura MLS data. Presented data includes one sudden stratospheric warming event which took place in January 13-14 and was accompanied by temperature increasing up to 310 K at 45 km height. During measurement period, ozone and temperature variations were (almost) anti-correlated, and total ozone abundance achieved a local maxima during the stratosphere cooling phase. In general, results of ground-based measurements are in good agreement with

  10. Improved ground-based FTS measurement for column abundance CO2 retrievals(Conference Presentation)

    Science.gov (United States)

    Goo, Tae-Young

    2016-10-01

    The National Institute of Meteorological Sciences has operated a ground-based Fourier Transform Spectrometer (FTS) at Anmyeondo, Korea since December 2012. Anmyeondo FTS site is a designated operational station of Total Carbon Column Observing Network (TCCON) and belongs to regional Global Atmosphere Watch observatory. A Bruker IFS-125HR model, which has a significantly high spectral resolution by 0.02 cm-1, is employed and instrument specification is almost same as the TCCON configuration. such as a spectrum range of 3,800 16,000 cm-1, a resolution of 1 cm-1, InGaAs and Si-Diode detectors and CaF2 beam splitter. It is found that measured spectra have a good agreement with simulated spectra. In order to improve the spectral accuracy and stability, The Operational Automatic System for Intensity of Sunray (OASIS) has been developed. The OASIS can provide consistent photon energy optimized to detector range by controlling the diameter of solar beam reflected from the mirror of suntracker. As a result, monthly modulation efficiency (ME), which indicates the spectral accuracy of FTS measurement, has been recorded the vicinity of 99.9% since Feb 2015. The ME of 98% is regarded as the error of 0.1% in the ground-based in-situ CO2 measurement. Total column abundances of CO2 and CH4 during 2015 are estimated by using GGG v14 and compared with ground-based in-situ CO2 and CH4 measurements at the height of 86 m above sea level. The seasonality of CO2 is well captured by both FTS and in-situ measurements while there is considerable difference on the amplitude of CO2 seasonal variation due to the insensitivity of column CO2 to the surface carbon cycle dynamics in nature as well as anthropogenic sources. Total column CO2 and CH4 approximately vary from 395 ppm to 405 ppm and from 1.82 ppm to 1.88 ppm, respectively. It should be noted that few measurements obtained in July to August because of a lot of cloud and fog. It is found that enhancement of CH4 from the FTS at Anmyeondo

  11. DOAS measurements of formaldehyde and glyoxal above a south-east Asian tropical rainforest

    Directory of Open Access Journals (Sweden)

    S. M. MacDonald

    2012-07-01

    Full Text Available Tropical rainforests act as a huge contributor to the global emissions of biogenic volatile organic compounds (BVOCs. Measurements of their oxidation products, such as formaldehyde (HCHO and glyoxal (CHOCHO, provide useful indicators of fast photochemistry occurring in the lower troposphere. However, measurements of these species in tropical forest locations are extremely limited. To redress this, HCHO and CHOCHO were measured using the long-path (LP and multi-axis (MAX differential optical absorption spectroscopy (DOAS techniques above the rainforest canopy in Borneo during two campaigns in spring and summer 2008, as part of the Oxidant and Particle Photochemical Processes above a south-east Asian tropical rainforest (OP3 project. The results were compared with concurrent measurements of hydroxyl radical (OH, isoprene (C5H8 (which was the dominant organic species emitted in this forest environment, and various meteorological parameters. Formaldehyde was observed at a maximum concentration of 4.5 ppb and glyoxal at a maximum of 1.6 ppb, significantly higher than previous measurements in rural locations. A 1-D chemistry model was then used to assess the diurnal evolution of formaldehyde and glyoxal throughout the boundary layer. The results, which compare well with the LP-DOAS and MAX-DOAS observations, suggest that the majority of the glyoxal and formaldehyde is confined to the first 500 m of the boundary layer, and that the measured ratio of these species is reproduced using currently accepted product yields for the oxidation of isoprene by OH. An important conclusion is that the measured levels of glyoxal are consistent with the surprisingly high concentrations of OH measured in this environment.

  12. DOAS measurements of formaldehyde and glyoxal above a South-East Asian tropical rainforest

    Directory of Open Access Journals (Sweden)

    S. M. MacDonald

    2012-02-01

    Full Text Available Tropical rainforests act as a huge contributor to the global emissions of biogenic volatile organic compounds (BVOCs. Measurements of their oxidation products, such as formaldehyde (HCHO and glyoxal (CHOCHO, provide useful indicators of fast photochemistry occurring in the lower troposphere. However, measurements of these species in tropical forest locations are extremely limited. To redress this, HCHO and CHOCHO were measured using the long-path (LP and multi-axis (MAX differential optical absorption spectroscopy (DOAS techniques above the rainforest canopy in Borneo during two campaigns in spring and summer 2008, as part of the Oxidant and Particle Photochemical Processes above a South-East Asian tropical rainforest (OP3 project. The results were compared with concurrent measurements of hydroxyl radical (OH, isoprene (C5H8 (which was the dominant organic species emitted in this forest environment, and various meteorological parameters. Formaldehyde was observed at a maximum concentration of 4.5 ppb and glyoxal at a maximum of 1.6 ppb, significantly higher than previous measurements in rural locations. A 1-D chemistry model was then used to assess the diurnal evolution of formaldehyde and glyoxal throughout the boundary layer. The results, which compare well with the LP-DOAS and MAX-DOAS observations, suggest that the majority of the glyoxal and formaldehyde is confined to the first 500 m of the boundary layer, and that the measured ratio of these species is reproduced using currently accepted product yields for the oxidation of isoprene by OH. An important conclusion is that the measured levels of glyoxal are consistent with the surprisingly high concentrations of OH measured in this environment.

  13. DOAS measurements of formaldehyde and glyoxal above a south-east Asian tropical rainforest

    Science.gov (United States)

    MacDonald, S. M.; Oetjen, H.; Mahajan, A. S.; Whalley, L. K.; Edwards, P. M.; Heard, D. E.; Jones, C. E.; Plane, J. M. C.

    2012-07-01

    Tropical rainforests act as a huge contributor to the global emissions of biogenic volatile organic compounds (BVOCs). Measurements of their oxidation products, such as formaldehyde (HCHO) and glyoxal (CHOCHO), provide useful indicators of fast photochemistry occurring in the lower troposphere. However, measurements of these species in tropical forest locations are extremely limited. To redress this, HCHO and CHOCHO were measured using the long-path (LP) and multi-axis (MAX) differential optical absorption spectroscopy (DOAS) techniques above the rainforest canopy in Borneo during two campaigns in spring and summer 2008, as part of the Oxidant and Particle Photochemical Processes above a south-east Asian tropical rainforest (OP3) project. The results were compared with concurrent measurements of hydroxyl radical (OH), isoprene (C5H8) (which was the dominant organic species emitted in this forest environment), and various meteorological parameters. Formaldehyde was observed at a maximum concentration of 4.5 ppb and glyoxal at a maximum of 1.6 ppb, significantly higher than previous measurements in rural locations. A 1-D chemistry model was then used to assess the diurnal evolution of formaldehyde and glyoxal throughout the boundary layer. The results, which compare well with the LP-DOAS and MAX-DOAS observations, suggest that the majority of the glyoxal and formaldehyde is confined to the first 500 m of the boundary layer, and that the measured ratio of these species is reproduced using currently accepted product yields for the oxidation of isoprene by OH. An important conclusion is that the measured levels of glyoxal are consistent with the surprisingly high concentrations of OH measured in this environment.

  14. Estimation of Antarctic ozone loss from Ground-based total column measurements

    Directory of Open Access Journals (Sweden)

    J. Kuttippurath

    2010-03-01

    Full Text Available The passive ozone method is used to estimate ozone loss from ground-based measurements in the Antarctic. A sensitivity study shows that the O3 loss can be estimated within an accuracy of ~4%. The method is then applied to the observations from Amundsen-Scott/South Pole, Arrival Heights, Belgrano, Concordia, Dumont d'Urville, Faraday, Halley, Marambio, Neumayer, Rothera, Syowa and Zhongshan for the diagnosis of ozone loss in the Antarctic. On average, the five-day running mean of the vortex averaged ozone column loss deduced from the ground-based stations shows about 53% in 2009, 59% in 2008, 55% in 2007, 56% in 2006 and 61% in 2005. The observed O3 loss and loss rates are in very good agreement with the satellite observations (Ozone Monitoring Instrument and Sciamachy and are well reproduced by the model (Reprobus and SLIMCAT calculations.

    The historical ground-based total ozone measurements show that the depletion started in the late 1970s, reached a maximum in the early 1990s, stabilising afterwards at this level until present, with the exception of 2002, the year of an early vortex break-up. There is no indication of significant recovery yet.

    At southern mid-latitudes, a total ozone reduction of 40–50% is observed at the newly installed station Rio Gallegos and 25–35% at Kerguelen in October–November of 2008–2009 and 2005–2009 (except 2008 respectively, and of 10–20% at Macquarie Island in July–August of 2006–2009. This illustrates the significance of measurements at the edges of Antarctica.

  15. Comparison of OMI UV observations with ground-based measurements at high northern latitudes

    Directory of Open Access Journals (Sweden)

    G. Bernhard

    2015-03-01

    Full Text Available The Dutch-Finnish Ozone Monitoring Instrument (OMI on board NASA's Aura spacecraft provides estimates of erythemal (sunburning ultraviolet (UV dose rates and erythemal daily doses. These data were compared with ground-based measurements at 13 stations located throughout the Arctic and Scandinavia from 60 to 83° N. The study corroborates results from earlier work, but is based on a longer time series (eight vs. two years and considers additional data products, such as the erythemal dose rate at the time of the satellite overpass. Furthermore, systematic errors in satellite UV data resulting from inaccuracies in the surface albedo climatology used in the OMI UV algorithm are systematically assessed. At times when the surface albedo is correctly known, OMI data typically exceed ground-based measurements by 0–11%. When the OMI albedo climatology exceeds the actual albedo, OMI data may be biased high by as much as 55%. In turn, when the OMI albedo climatology is too low, OMI data can be biased low by up to 59%. Such large negative biases may occur when reflections from snow and ice, which increase downwelling UV irradiance, are misinterpreted as reflections from clouds, which decrease the UV flux at the surface. Results suggest that a better OMI albedo climatology would greatly improve the accuracy of OMI UV data products even if year-to-year differences of the actual albedo cannot be accounted for. A pathway for improving the OMI albedo climatology is discussed. Results also demonstrate that ground-based measurements from the center of Greenland, where high, homogenous surface albedo is observed year round, are ideally suited to detect systematic problems or temporal drifts in estimates of surface UV irradiance from space.

  16. Ground-based measurements of aerosol optical properties and radiative forcing in North China

    Institute of Scientific and Technical Information of China (English)

    Hongbin Chen; Xiangao Xia; Pucai Wang; Wenxing Zhang

    2007-01-01

    In order to gain an insight into the aerosol properties and their climatic effect over the continental source regions of China, it is of significance to carry out long-term ground-based measurements of aerosol optical properties and radiative forcing. A couple of temporary and permanent Aerosol Robotic Network (AERONET) sites and three comprehensive radiative sites were established in China as a result of international cooperation in recent years. Heavy aerosol loading and significant temporal and spatial variation over North China are revealed by the AERONET data.Aerosol-induced reductions in surface radiation budget are examined on the basis of collocated observations by sun photometers and pyranometers.

  17. A six-beam method to measure turbulence statistics using ground-based wind lidars

    DEFF Research Database (Denmark)

    Sathe, Ameya; Mann, Jakob; Vasiljevic, Nikola

    2015-01-01

    A so-called six-beam method is proposed to measure atmospheric turbulence using a ground-based wind lidar. This method requires measurement of the radial velocity variances at five equally spaced azimuth angles on the base of a scanning cone and one measurement at the centre of the scanning circle...... lidar (WindScanner), and the derived turbulence statistics (using both methods) such as the u and v variances are compared with those obtained from a reference cup anemometer and a wind vane at 89m height under different atmospheric stabilities. The measurements show that in comparison to the reference...... cup anemometer, depending on the atmospheric stability and the wind field component, the six-beam method measures between 85 and 101% of the reference turbulence, whereas the VAD method measures between 66 and 87% of the reference turbulence....

  18. A six-beam method to measure turbulence statistics using ground-based wind lidars

    DEFF Research Database (Denmark)

    Sathe, Ameya; Mann, Jakob; Vasiljevic, Nikola

    2014-01-01

    A so-called six-beam method is proposed to measure atmospheric turbulence using a ground-based wind lidar. This method requires measurement of the radial velocity variances at five equally spaced azimuth angles on the base of a scanning cone and one measurement at the center of the scanning circle...... lidar (WindScanner), and the derived turbulence statistics (using both methods) such as the u and v variances are compared with those obtained from a reference cup anemometer and a wind vane at 89m height under different atmospheric stabilities. The measurements show that in comparison to the reference...... cup anemometer, depending on the atmospheric stability and the wind field component, the six-beam method measures between 85–101% of the reference turbulence, whereas the VAD method measures between 66–87% of the reference turbulence....

  19. Airborne and ground based lidar measurements of the atmospheric pressure profile

    Science.gov (United States)

    Korb, C. Laurence; Schwemmer, Geary K.; Dombrowski, Mark; Weng, Chi Y.

    1989-01-01

    The first high accuracy remote measurements of the atmospheric pressure profile have been made. The measurements were made with a differential absorption lidar system that utilizes tunable alexandrite lasers. The absorption in the trough between two lines in the oxygen A-band near 760 nm was used for probing the atmosphere. Measurements of the two-dimensional structure of the pressure field were made in the troposphere from an aircraft looking down. Also, measurements of the one-dimensional structure were made from the ground looking up. Typical pressure accuracies for the aircraft measurements were 1.5-2 mbar with a 30-m vertical resolution and a 100-shot average (20 s), which corresponds to a 2-km horizontal resolution. Typical accuracies for the upward viewing ground based measurements were 2.0 mbar for a 30-m resolution and a 100-shot average.

  20. Airborne multi-axis DOAS measurements of tropospheric SO2 plumes in the Po-valley, Italy

    Directory of Open Access Journals (Sweden)

    P. Wang

    2006-01-01

    Full Text Available During the second FORMAT (FORMaldehyde as A Tracer of oxidation in the troposphere campaign in 2003 the airborne multi-axis DOAS instrument (AMAXDOAS performed scattered-light spectroscopic measurements of SO2 over the city of Mantova and the power plant Porto Tolle, both situated in the Po-valley, Northern Italy. The SO2 vertical columns and emission flux were derived from two days of measurements, 26 and 27 September 2003. The SO2 emission flux from the power plant Porto Tolle was calculated to 1.93×1025 molec s-1 on 26 September and in good agreement with official emission data, which quote 2.25×1025 molec s-1. On 27 September the measured flux was much lower (3.77×1024 molec s-1 if ECMWF wind data are used, but of comparable magnitude (2.4×1025 molec s-1 if the aircraft on-board wind measurements are utilised. Official emission data was 2.07×1025 molec s-1 indicating only a small change from the previous day. Over the city of Mantova, the observed SO2 vertical columns were 1.1×1016 molec cm-2 and 1.9×1016 molec cm-2 on 26 and 27 September, respectively. This is in good agreement with ground-based measurements of 5.9 ppbv and 10.0 ppbv which correspond to 1.2×1016 molec cm-2 and 2.2×1016 molec cm-2 if a well mixed boundary layer of 500m altitude is assumed.

  1. Slant column MAX-DOAS measurements of nitrogen dioxide, formaldehyde, glyoxal and oxygen dimer in the urban environment of Athens

    Science.gov (United States)

    Gratsea, Myrto; Vrekoussis, Mihalis; Richter, Andreas; Wittrock, Folkard; Schönhardt, Anja; Burrows, John; Kazadzis, Stelios; Mihalopoulos, Nikos; Gerasopoulos, Evangelos

    2016-06-01

    Slant column (SC) densities of nitrogen dioxide (NO2), formaldehyde (HCHO), glyoxal (CHOCHO) and oxygen dimer (O4) were successfully retrieved for the first time in Athens, by using spectral measurements from a ground-based multi-azimuth Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) system. The data span the period from October 2012 to March 2014 and measurements were conducted at NOA's (National Observatory of Athens) station in Penteli (38.0°N, 23.9°E, 527 m a.s.l.) at eight azimuth angles and eight off-axis elevation angles. The SCNO2, SCHCHO and SCCHOCHO measurements at +1ο elevation angle, pointing towards the urban area, range from 0.6 to 24·1016, 0.8-9.6·1016 and 0.3-5.2·1015 molec cm-2 (mean daily values throughout the whole period), respectively. Seasonal modulation characterised by summertime maximum and wintertime minimum was observed for HCHO and CHOCHO, while for NO2 the maximum values were recorded during winter. Changes in the diurnal variability of all trace gases with season and day of the week are investigated suggesting a strong link to primary anthropogenic sources for NO2 and a weaker one, compared to photochemistry, for HCHO and CHOCHO. In addition, the impact of the reduced anthropogenic emissions during weekends on the measured SC values was quantified and 30%-50% lower SCNO2 values were found during weekends. The contribution of local urban emissions to the overall recorded amounts of the selected species was assessed. Using meteorological data from NOA's station in Penteli, the impact of the local circulation patterns on the SC levels was estimated, and a strong relation between western wind direction, which is related to the industrial area, and enhanced SC measurements was found.

  2. Tropospheric profile of NO2 over the Po Valley measured with scan DOAS spectrometer

    Science.gov (United States)

    Masieri, S.; Bortoli, D.; Petritoli, A.; Kostadinov, I.; Premuda, M.; Ravegnani, F.; Carnevale, C.; Pisoni, E.; Volta, M.; Giovanelli, G.

    2009-09-01

    A simple method to determine the vertical distribution of a pollutant gas, namely NO2, by means of the spectral measurements obtained with a scan-DOAS spectrometer, is presented. The developed technique can be summarized as follows: i) a series of quasi simultaneous measurements in the zenith and in others directions allowing for the determination of the Slant Column Density of NO2 for different elevation angles; ii) an active DOAS measurement for the determination of the NO2 concentration at the ground; iii) a set of Radiative Transfer Model (RTM) calculation of the scattering distance from the spectrometer, for a set of visibility values; iv) a recursive procedure of profile calculation starting from the first measurement and subtracting the value of NO2 Slant Column Density (SCD) retrieved from the measurement taken at the previous angle of sight. Measurements are carried out during summer 2007 in S. Pietro Capofiume (Bologna-Italy). The vertical distribution for NO2 obtained with the above described method has been compared with the profiles calculated with the GAMES (Gas Aerosol Modelling Evaluation System) model. The results of this comparison show some differences between the modelled and the measured profiles, probably due to box approximations in RTM calculation for measured profiles and to the large pixel grid (about 10x10 km2), for model evaluation.

  3. Overview and Initial Results from the DEEPWAVE Airborne and Ground-Based Measurement Program

    Science.gov (United States)

    Fritts, D. C.

    2015-12-01

    The deep-propagating gravity wave experiment (DEEPWAVE) was performed on and over New Zealand, the Tasman Sea, and the Southern Ocean with core airborne measurements extending from 5 June to 21 July 2014 and supporting ground-based measurements spanning a longer interval. The NSF/NCAR GV employed standard flight-level measurements and new airborne lidar and imaging measurements of gravity waves (GWs) from sources at lower altitudes throughout the stratosphere and into the mesosphere and lower thermosphere (MLT). The new GV lidars included a Rayleigh lidar measuring atmospheric density and temperature from ~20-60 km and a sodium resonance lidar measuring sodium density and temperature at ~75-105 km. An airborne Advanced Mesosphere Temperature Mapper (AMTM) and two IR "wing" cameras imaged the OH airglow temperature and/or intensity fields extending ~900 km across the GV flight track. The DLR Falcon was equipped with its standard flight-level instruments and an aerosol Doppler lidar measuring radial winds below the Falcon. DEEPWAVE also included extensive ground-based measurements in New Zealand, Tasmania, and Southern Ocean Islands. DEEPWAVE performed 26 GV flights and 13 Falcon flights, and ground-based measurements occurred whether or not the aircraft were flying. Collectively, many diverse cases of GW forcing, propagation, refraction, and dissipation spanning altitudes of 0-100 km were observed. Examples include strong mountain wave (MW) forcing and breaking in the lower and middle stratosphere, weak MW forcing yielding MW penetration into the MLT having very large amplitudes and momentum fluxes, MW scales at higher altitudes ranging from ~10-250 km, large-scale trailing waves from orography refracting into the polar vortex and extending to high altitudes, GW generation by deep convection, large-scale GWs arising from jet stream sources, and strong MWs in the MLT arising from strong surface flow over a small island. DEEPWAVE yielded a number of surprises, among

  4. A review of turbulence measurements using ground-based wind lidars

    DEFF Research Database (Denmark)

    Sathe, Ameya; Mann, Jakob

    2013-01-01

    pioneered in the first 15 yr, i.e., from 1972–1997, when standard techniques could not be used to measure turbulence. Obtaining unfiltered turbulence statistics from the large probe volume of the lidars has been and still remains the most challenging aspect. Until now, most of the processing algorithms......A review of turbulence measurements using ground-based wind lidars is carried out. Works performed in the last 30 yr, i.e., from 1972–2012 are analyzed. More than 80% of the work has been carried out in the last 15 yr, i.e., from 1997–2012. New algorithms to process the raw lidar data were...... that have been developed have shown that by combining an isotropic turbulence model with raw lidar measurements, we can obtain unfiltered statistics.We believe that an anisotropic turbulence model will provide a more realistic measure of turbulence statistics. Future development in algorithms will depend...

  5. Ground based mobile isotopic methane measurements in the Front Range, Colorado

    Science.gov (United States)

    Vaughn, B. H.; Rella, C.; Petron, G.; Sherwood, O.; Mielke-Maday, I.; Schwietzke, S.

    2014-12-01

    Increased development of unconventional oil and gas resources in North America has given rise to attempts to monitor and quantify fugitive emissions of methane from the industry. Emission estimates of methane from oil and gas basins can vary significantly from one study to another as well as from EPA or State estimates. New efforts are aimed at reconciling bottom-up, or inventory-based, emission estimates of methane with top-down estimates based on atmospheric measurements from aircraft, towers, mobile ground-based vehicles, and atmospheric models. Attributing airborne measurements of regional methane fluxes to specific sources is informed by ground-based measurements of methane. Stable isotopic measurements (δ13C) of methane help distinguish between emissions from the O&G industry, Confined Animal Feed Operations (CAFO), and landfills, but analytical challenges typically limit meaningful isotopic measurements to individual point sampling. We are developing a toolbox to use δ13CH4 measurements to assess the partitioning of methane emissions for regions with multiple methane sources. The method was applied to the Denver-Julesberg Basin. Here we present data from continuous isotopic measurements obtained over a wide geographic area by using MegaCore, a 1500 ft. tube that is constantly filled with sample air while driving, then subsequently analyzed at slower rates using cavity ring down spectroscopy (CRDS). Pressure, flow and calibration are tightly controlled allowing precise attribution of methane enhancements to their point of collection. Comparisons with point measurements are needed to confirm regional values and further constrain flux estimates and models. This effort was made in conjunction with several major field campaigns in the Colorado Front Range in July-August 2014, including FRAPPÉ (Front Range Air Pollution and Photochemistry Experiment), DISCOVER-AQ, and the Air Water Gas NSF Sustainability Research Network at the University of Colorado.

  6. Exploring the relationship between monitored ground-based and satellite aerosol measurements over the City of Johannesburg

    CSIR Research Space (South Africa)

    Garland, Rebecca M

    2012-09-01

    Full Text Available This project studied the relationship between aerosol optical depth (AOD) from the Multi-angle Imaging SpectroRadiometer (MISR) instrument on the Terra satellite, and ground-based monitored particulate matter (PM) mass concentrations measured...

  7. MAX-DOAS aerosol and trace gases measurements in megacities in China

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xin [Institut fuer Energie- und Klimaforschung, Forschungszentrum Juelich (Germany); College of Environmental Science and Engineering Peking University, Beijing (China); Brauers, Theo [Institut fuer Energie- und Klimaforschung, Forschungszentrum Juelich (Germany); Shao, Min [College of Environmental Science and Engineering Peking University, Beijing (China)

    2011-07-01

    Multi Axis Differential Optical Absorption Spectroscopy (MAXDOAS) is a new remote sensing technique to measure atmospheric trace gases. Compared to other areas in the world, the atmospheric observations in megacities in China are rather limited. We present MAX-DOAS measurements at four sites in Beijing and Guangzhou in 2006 and 2008. At each site, the scattered sunlight was recorded at 7 elevation angles for about 1 months. Using the zenith spectrum as reference, the Differential Slant Column Densities (DSCDs) of HCHO, CHOCHO, O{sub 4} and NO{sub 2} at offaxis viewing geometries were derived from the DOAS fit. These DSCDs were simulated using a backward Monte Carlo radiative transfer model. The aerosol and trace gas profiles were defined by 3 parameters: the integrated quantities (T), the height of the surface layer (H), and the fraction of T below H. We fitted the modeled values to the measured values at the corresponding viewing geometries by varying the 3 parameters. The aerosol extinction and the boundary layer height were successfully retrieved from the measured O{sub 4} DSCDs as well as ground level concentrations of CHOCHO, HCHO, and NO{sub 2}, the latter being compared to simultaneous in-situ measurements.

  8. Concurrent aerial and ground-based optical turbulence measurements along a long elevated path

    Science.gov (United States)

    Nowlin, Scott R.; Hahn, Ila L.; Hugo, Ronald J.; Bishop, Kenneth P.

    1999-08-01

    We report concurrent ground-based scintillator/airborne constant-current anemometer (CCA) measurements made along a 51.4 km-long slant path between Salinas and North Oscura peaks, NM. Simultaneous path-averaged refractive index structure parameter (Cn2) measurements from the CCA and the scintillometer show good agreement, with deviations apparently due to localized effects of underlying topography and metrology. Statistics from both data sets are presented in the form of histograms and cumulative distribution functions. CCA Cn2 point measurements are compared to underlying surface topography. We discuss possible effects of instruments anomalies, analysis methods, and atmospheric velocity fluctuation levels. We present conclusions and made recommendations for future similar experimental efforts.

  9. Aerosol Single Scattering Albedo retrieved from ground-based measurements in the UV-visible

    Directory of Open Access Journals (Sweden)

    V. Buchard

    2010-07-01

    Full Text Available Estimates of Aerosol Single Scattering Albedo (SSA from ground-based spectral measurements in the UV-visible are conducted at Villeneuve d'Ascq (VdA in France. In order to estimate this parameter, measurements of global and diffuse UV-visible solar irradiances performed under cloud-free conditions since 2003 with a spectroradiometer operated by the Laboratoire d'Optique Atmosphérique (LOA are used. The technique consists in comparing the measured irradiance values to modelled irradiances computed for various SSA. The retrieval is restricted to the 330–450 nm range to avoid ozone influence.

    For validation purpose, the retrieved values of SSA at 440 nm are compared to the ones obtained from sunphotometer measurements of the AERONET/PHOTONS network available on the LOA site. The results are rather satisfying: in 2003 and 2005–2006 the Root Mean Square (RMS of the differences are about 0.05, these values are within the uncertainty domain of retrieval of both products. Distinction between days characterized by different aerosol content, by means of the aerosol optical thickness (AOT retrieved from ground-based measurements at the same wavelength, shows that the comparisons between both products are better when AOT are higher. Indeed in case AOT are greater than 0.2, the RMS is 0.027 in 2003 and 0.035 in 2005–2006. The SSA estimated at 340 and 380 nm from ground-based spectra are also studied, though no validation can be carried out with sunphotometer data (440 nm is the shortest wavelength at which the SSA is provided by the network. The good comparisons observed at 440 nm can let assume that the SSA retrieved from spectroradiometer measurements at the two other wavelengths are also obtained with a good confidence level. Thus these values in the UV range can be used to complete aerosol data provided by AERONET/PHOTONS at VdA. Moreover they can be used for a best knowledge of the aerosol absorption that is necessary to quantify the

  10. Nighttime Aerosol Optical Depth Measurements Using a Ground-based Lunar Photometer

    Science.gov (United States)

    Berkoff, Tim; Omar, Ali; Haggard, Charles; Pippin, Margaret; Tasaddaq, Aasam; Stone, Tom; Rodriguez, Jon; Slutsker, Ilya; Eck, Tom; Holben, Brent; hide

    2015-01-01

    In recent years it was proposed to combine AERONET network photometer capabilities with a high precision lunar model used for satellite calibration to retrieve columnar nighttime AODs. The USGS lunar model can continuously provide pre-atmosphere high precision lunar irradiance determinations for multiple wavelengths at ground sensor locations. When combined with measured irradiances from a ground-based AERONET photometer, atmospheric column transmissions can determined yielding nighttime column aerosol AOD and Angstrom coefficients. Additional demonstrations have utilized this approach to further develop calibration methods and to obtain data in polar regions where extended periods of darkness occur. This new capability enables more complete studies of the diurnal behavior of aerosols, and feedback for models and satellite retrievals for the nighttime behavior of aerosols. It is anticipated that the nighttime capability of these sensors will be useful for comparisons with satellite lidars such as CALIOP and CATS in additional to ground-based lidars in MPLNET at night, when the signal-to-noise ratio is higher than daytime and more precise AOD comparisons can be made.

  11. MAX-DOAS measurements of African continental pollution outflow over the Atlantic Ocean

    Science.gov (United States)

    Behrens, Lisa K.; Hilboll, Andreas; Peters, Enno; Richter, Andreas; Alvarado, Leonardo; Wittrock, Folkard; Burrows, John P.; Vrekoussis, Mihalis

    2017-04-01

    Enhanced levels of atmospheric key pollutants can regularly be identified over the Atlantic Ocean in global trace gas maps retrieved from satellite measurements. The aim of the DFG project COPMAR (Continental outflow of pollutants towards the marine troposphere) was to validate these enhanced values using ship-based measurements and to identify the spatial gradients of the pollutants NO2, CHOCHO, and HCHO over the Atlantic Ocean. Therefore, a multi-axis differential optical absorption spectrometer (MAX-DOAS) was installed on board the research vessel Maria S. Merian for the cruise MSM58/2. This cruise was conducted in October 2016 and went from Ponta Delgada (Azores) to Cape Town (South Africa), crossing between Cape Verde and the African continent. The instrument was continuously scanning the horizon looking towards the African continent, and the ship sailed at nearly constant speed during the whole cruise. In this study, we present the results from the MAX-DOAS measurements for the three species. We discuss the influence of different fit settings and a-priori assumptions on the results and present the observed spatial gradients along the cruise track. Finally, we compare our results with satellite measurements by the GOME-2 and OMI instruments and discuss possible sources of the discrepancies.

  12. Chlorine oxide in the stratospheric ozone layer Ground-based detection and measurement

    Science.gov (United States)

    Parrish, A.; De Zafra, R. L.; Solomon, P. M.; Barrett, J. W.; Carlson, E. R.

    1981-01-01

    Stratospheric chlorine oxide, a significant intermediate product in the catalytic destruction of ozone by atomic chlorine, has been detected and measured by a ground-based 204 GHz, millimeter-wave receiver. Data taken at latitude 42 deg N on 17 days between January 10 and February 18, 1980 yield an average chlorine oxide column density of approximately 1.05 x 10 to the 14th/sq cm or approximately 2/3 that of the average of eight in situ balloon flight measurements (excluding the anomalously high data of July 14, 1977) made over the past four years at 32 deg N. Less chlorine oxide below 35 km and a larger vertical gradient than predicted by theoretical models of the stratospheric ozone layer are found.

  13. Horizontal and temporal evolution of tropospheric NO2 in Vienna as inferred from car DOAS measurements

    Science.gov (United States)

    Schreier, Stefan F.; Richter, Andreas; Li, Zheng; Burrows, John P.

    2016-04-01

    Zenith-sky measurements were performed with a car DOAS (Differential Optical Absorption Spectroscopy) instrument to obtain tropospheric nitrogen dioxide (NO2) distributions within the metropolitan area of Vienna, Austria, on nine days in April, September, October, and November 2015. Several single car journeys having an approximate distance of 110 km and covering known emission sources of nitrogen oxides (NOx) as well as a background region north of Vienna were carried out. The spectral measurements are analyzed using the DOAS technique applying a nonlinear least-squares fitting algorithm. The obtained NO2 differential slant column densities (DSCDs) are based on the 425-490 nm fitting window and the inclusion of relevant high resolution absorption cross-sections. Tropospheric NO2 vertical column densities (VCDs) are extracted from the NO2 DSCDs by making assumptions on the diurnal variation of stratospheric NO2 VCDs and determining a tropospheric NO2 airmass factor. Additional meteorological (wind speed and wind direction) and air quality (surface NO2 concentrations) data from nearby measurement stations is used to interpret the horizontal and temporal evolution of NO2 pollution. Our results show that elevated NO2 pollution originating from rush-hour traffic over busy highways is transported along the Danube River to the Northwest of Vienna under certain meteorological conditions.

  14. Mesospheric minor species determinations from rocket and ground-based i.r. measurements

    Science.gov (United States)

    Ulwick, J. C.; Baker, K. D.; Baker, D. J.; Steed, A. J.; Pendleton, W. R.; Grossmann, K.; Brückelmann, H. G.

    As part of the MAP/WINE campaign the infrared hydroxyl airglow layer was investigated at Kiruna, Sweden, by simultaneous measurements with rocket probes of OH ≠ and O2( a1Δg) infrared emissions and concentrations of odd oxygen species (O and O 3). Coordinated measurements of OH ≠ and O2( a1Δg) zenith radiance and emission spectra and their time histories were made from the ground. The rocket-borne Λ = 1.55 μm radiometer ( ΔΛ ≊ 0.23 μm) provided volume emission rates for OH for both rocket ascent and descent, showing a peak near 87 km with a maximum of nearly 10 6 photons sec -1 cm -3. The atomic oxygen distribution showed a concentration of about 10 11 cm -3 between 88 and 100 km, dropping off sharply below 85 km. The ground-based radiometer at Λ = 1.56 μm, which had a similar filter bandpass to the rocket-borne instrument, yielded an equivalent of 130 kR for the total OH Δv = 2 sequence, which is consistent with the zenith-corrected rocket-based sequence radiance value of ≌ 110 kR. The rotational temperature of the OH night airglow obtained from the rotational structure of the OH M (3,1) band observed by the ground-based interferometer was about 195K at the time of the rocket measurement. Atomic oxygen concentrations were calculated from the OH profile and show agreement with the directly measured values. Atomic hydrogen concentrations of a few times 10 7 cm -3 near 85 km were inferred from the data set.

  15. A six-beam method to measure turbulence statistics using ground-based wind lidars

    Directory of Open Access Journals (Sweden)

    A. Sathe

    2014-10-01

    Full Text Available A so-called six-beam method is proposed to measure atmospheric turbulence using a ground-based wind lidar. This method requires measurement of the radial velocity variances at five equally spaced azimuth angles on the base of a scanning cone and one measurement at the center of the scanning circle, i.e.using a vertical beam at the same height. The scanning configuration is optimized to minimize the sum of the random errors in the measurement of the second-order moments of the components (u,v, w of the wind field. We present this method as an alternative to the so-called velocity azimuth display (VAD method that is routinely used in commercial wind lidars, and which usually results in significant averaging effects of measured turbulence. In the VAD method, the high frequency radial velocity measurements are used instead of their variances. The measurements are performed using a pulsed lidar (WindScanner, and the derived turbulence statistics (using both methods such as the u and v variances are compared with those obtained from a reference cup anemometer and a wind vane at 89 m height under different atmospheric stabilities. The measurements show that in comparison to the reference cup anemometer, depending on the atmospheric stability and the wind field component, the six-beam method measures between 85–101% of the reference turbulence, whereas the VAD method measures between 66–87% of the reference turbulence.

  16. A six-beam method to measure turbulence statistics using ground-based wind lidars

    Science.gov (United States)

    Sathe, A.; Mann, J.; Vasiljevic, N.; Lea, G.

    2015-02-01

    A so-called six-beam method is proposed to measure atmospheric turbulence using a ground-based wind lidar. This method requires measurement of the radial velocity variances at five equally spaced azimuth angles on the base of a scanning cone and one measurement at the centre of the scanning circle, i.e.using a vertical beam at the same height. The scanning configuration is optimized to minimize the sum of the random errors in the measurement of the second-order moments of the components (u,v, w) of the wind field. We present this method as an alternative to the so-called velocity azimuth display (VAD) method that is routinely used in commercial wind lidars, and which usually results in significant averaging effects of measured turbulence. In the VAD method, the high frequency radial velocity measurements are used instead of their variances. The measurements are performed using a pulsed lidar (WindScanner), and the derived turbulence statistics (using both methods) such as the u and v variances are compared with those obtained from a reference cup anemometer and a wind vane at 89 m height under different atmospheric stabilities. The measurements show that in comparison to the reference cup anemometer, depending on the atmospheric stability and the wind field component, the six-beam method measures between 85 and 101% of the reference turbulence, whereas the VAD method measures between 66 and 87% of the reference turbulence.

  17. Mountain wave PSC dynamics and microphysics from ground-based lidar measurements and meteorological modeling

    Directory of Open Access Journals (Sweden)

    J. Reichardt

    2004-01-01

    Full Text Available The day-long observation of a polar stratospheric cloud (PSC by two co-located ground-based lidars at the Swedish research facility Esrange (67.9° N, 21.1° E on 16 January 1997 is analyzed in terms of PSC dynamics and microphysics. Mesoscale modeling is utilized to simulate the meteorological setting of the lidar measurements. Microphysical properties of the PSC particles are retrieved by comparing the measured particle depolarization ratio and the PSC-averaged lidar ratio with theoretical optical data derived for different particle shapes. In the morning, nitric acid trihydrate (NAT particles and then increasingly coexisting liquid ternary aerosol (LTA were detected as outflow from a mountain wave-induced ice PSC upwind Esrange. The NAT PSC is in good agreement with simulations for irregular-shaped particles with length-to-diameter ratios between 0.75 and 1.25, maximum dimensions from 0.7 to 0.9 µm, and a number density from 8 to 12 cm-3 and the coexisting LTA droplets had diameters from 0.7 to 0.9 µm, a refractive index of 1.39 and a number density from 7 to 11 cm-3. The total amount of condensed HNO3 was in the range of 8–12 ppbv. The data provide further observational evidence that NAT forms via deposition nucleation on ice particles as a number of recently published papers suggest. By early afternoon the mountain-wave ice PSC expanded above the lidar site. Its optical data indicate a decrease in minimum particle size from 3 to 1.9 µm with time. Later on, following the weakening of the mountain wave, wave-induced LTA was observed only. Our study demonstrates that ground-based lidar measurements of PSCs can be comprehensively interpreted if combined with mesoscale meteorological data.

  18. Effect of Atmospheric Interfering Absorption on Measurement of BTX by DOAS

    Institute of Scientific and Technical Information of China (English)

    Fu-min Peng; Pin-hua Xie; Hai-yang Li; Ying-hua Zhang; Jun-de Wang; Wen-qing Liu

    2008-01-01

    It was reported on the elimination of interfering absorption of BTX. the absorption of O2 includes different absorption bands, which change differently when the partial pressure of oxygen is varied. These cause the nonlinear absorption of O2 and the observed band shape to vary with the column density of O2. The absorption ratios of molecular absorption in each of the Herzberg bands and dimer absorptions, as well as the contribution to the correction error of molecular absorption, are studied based on the characteristic of these absorption bands. The optimized way to eliminate the interfering absorption is obtained in the end and the effectiveness of using interpolation proposed by Volkamer et al. to remove 02 absorption is proved again. As to O3 and SO2, the effect of the thermal effect of characteristic spectra on the elimination error of their absorption is studied. Solutions to these problems are discussed and demonstrated together with methods to optimize the interpolation of spectra. As a sample application, differential optical absorption spectroscopy (DOAS) measurements of BTX are carried out. Results show a low detection limit and the good correlation with point instruments are achieved. All these prove the feasibility of using spectral interpolation to improve the accuracy of DOAS measurements of aromatic hydrocarbons for practical purposes.

  19. On the Interpretation of Gravity Wave Measurements by Ground-Based Lidars

    Directory of Open Access Journals (Sweden)

    Andreas Dörnbrack

    2017-03-01

    Full Text Available This paper asks the simple question: How can we interpret vertical time series of middle atmosphere gravity wave measurements by ground-based temperature lidars? Linear wave theory is used to show that the association of identified phase lines with quasi-monochromatic waves should be considered with great care. The ambient mean wind has a substantial effect on the inclination of the detected phase lines. The lack of knowledge about the wind might lead to a misinterpretation of the vertical propagation direction of the observed gravity waves. In particular, numerical simulations of three archetypal atmospheric mountain wave regimes show a sensitivity of virtual lidar observations on the position relative to the mountain and on the scale of the mountain.

  20. The Holy Grail of Resource Assessment: Low Cost Ground-Based Measurements with Good Accuracy

    Energy Technology Data Exchange (ETDEWEB)

    Marion, Bill; Smith, Benjamin

    2017-06-22

    Using performance data from some of the millions of installed photovoltaic (PV) modules with micro-inverters may afford the opportunity to provide ground-based solar resource data critical for developing PV projects. The method used back-solves for the direct normal irradiance (DNI) and the diffuse horizontal irradiance (DHI) from the micro-inverter ac production data. When the derived values of DNI and DHI were then used to model the performance of other PV systems, the annual mean bias deviations were within +/- 4%, and only 1% greater than when the PV performance was modeled using high quality irradiance measurements. An uncertainty analysis shows the method better suited for modeling PV performance than using satellite-based global horizontal irradiance.

  1. Intermittency of the turbulent processes in the Earth's magnetosphere detected from the ground-based measurements

    Science.gov (United States)

    Stepanova, Marina; Foppiano, Alberto; Ovalle, Elias; Antonova, Elizavieta; Troshichev, Oleg

    2008-11-01

    Turbulent processes in the Earth's magnetosphere are reflected in the dynamical behavior of the geomagnetic indices and other parameters determined from ground based observations. Intermittent properties of one minute Polar Cap (PC) index and auroral radio wave absorption are studied using 1995-2000 data sets. It was found that the probability distribution functions (PDFs) of both PC-index and absorption fluctuations display a strong non-Gaussian shape. This indicates that they are not characterized by a global time self-similarity but rather exhibit intermittency, as previously reported for solar wind velocity and auroral electrojet index values. In the case of the auroral absorption it was also found that intermittency strongly depends on the magnetic local time, being largest in the nighttime sector. This shows that the acceleration of precipitating particles is intermittent, especially near the substorm eye, where the level of turbulence increases. Application of the Local Intermittency Measure (LIM) technique confirms the aforementioned results to a better precision.

  2. An evaluation of IASI-NH3 with ground-based Fourier transform infrared spectroscopy measurements

    Science.gov (United States)

    Dammers, Enrico; Palm, Mathias; Van Damme, Martin; Vigouroux, Corinne; Smale, Dan; Conway, Stephanie; Toon, Geoffrey C.; Jones, Nicholas; Nussbaumer, Eric; Warneke, Thorsten; Petri, Christof; Clarisse, Lieven; Clerbaux, Cathy; Hermans, Christian; Lutsch, Erik; Strong, Kim; Hannigan, James W.; Nakajima, Hideaki; Morino, Isamu; Herrera, Beatriz; Stremme, Wolfgang; Grutter, Michel; Schaap, Martijn; Wichink Kruit, Roy J.; Notholt, Justus; Coheur, Pierre-F.; Erisman, Jan Willem

    2016-08-01

    Global distributions of atmospheric ammonia (NH3) measured with satellite instruments such as the Infrared Atmospheric Sounding Interferometer (IASI) contain valuable information on NH3 concentrations and variability in regions not yet covered by ground-based instruments. Due to their large spatial coverage and (bi-)daily overpasses, the satellite observations have the potential to increase our knowledge of the distribution of NH3 emissions and associated seasonal cycles. However the observations remain poorly validated, with only a handful of available studies often using only surface measurements without any vertical information. In this study, we present the first validation of the IASI-NH3 product using ground-based Fourier transform infrared spectroscopy (FTIR) observations. Using a recently developed consistent retrieval strategy, NH3 concentration profiles have been retrieved using observations from nine Network for the Detection of Atmospheric Composition Change (NDACC) stations around the world between 2008 and 2015. We demonstrate the importance of strict spatio-temporal collocation criteria for the comparison. Large differences in the regression results are observed for changing intervals of spatial criteria, mostly due to terrain characteristics and the short lifetime of NH3 in the atmosphere. The seasonal variations of both datasets are consistent for most sites. Correlations are found to be high at sites in areas with considerable NH3 levels, whereas correlations are lower at sites with low atmospheric NH3 levels close to the detection limit of the IASI instrument. A combination of the observations from all sites (Nobs = 547) give a mean relative difference of -32.4 ± (56.3) %, a correlation r of 0.8 with a slope of 0.73. These results give an improved estimate of the IASI-NH3 product performance compared to the previous upper-bound estimates (-50 to +100 %).

  3. CO2 Total Column Variability From Ground-Based FTIR Measurements Over Central Mexico

    Science.gov (United States)

    Baylon, J. L.; Stremme, W.; Plaza, E.; Bezanilla, A.; Grutter, M.; Hase, F.; Blumenstock, T.

    2014-12-01

    There are now several space missions dedicated to measure greenhouse gases in order to improve the understanding of the carbon cycle. Ground based measurement sites are of great value in the validation process, however there are only a few stations in tropical latitudes. We present measurements of solar-absorption infrared spectra recorded on two locations over Central Mexico: the High-Altitude Station Altzomoni (19.12 N, 98.65 W), located in the Izta-Popo National Park outside of Mexico City; and the UNAM's Atmospheric Observatory (19.32 N, 99.17 W) in Mexico City. These measurements were performed using a high resolution Fourier transform infrared spectrometer FTIR (Bruker, HR 120/5) at Altzomoni and a moderate resolution FTIR (Bruker, Vertex 80) within the city. In this work, we present the first results for total vertical columns of CO2 derived from near-infrared spectra recorded at both locations using the retrieval code PROFFIT. We present the seasonal cycle and variability from the measurements, as well as the full diagnostics of the retrieval in order assess its quality and discuss the differences of both instruments and locations (altitudes, urban vs remote). This work aims to contribute to generate high quality datasets for satellite validation.

  4. DOAS measurements of NO2 from an ultralight aircraft during the Earth Challenge expedition

    Directory of Open Access Journals (Sweden)

    X. Toledo

    2012-02-01

    Full Text Available We report on airborne Differential Optical Absorption Spectroscopy (DOAS measurements of NO2 tropospheric columns above South Asia, Arabic peninsula, North Africa, and Italy in November and December 2009. The DOAS instrument was installed on an ultralight aircraft involved in the Earth Challenge project, an expedition of seven pilots flying on four ultralight aircraft between Australia and Belgium. The instrument recorded spectra in limb geometry with a large field-of-view, a set-up which provides a high sensitivity to the boundary layer NO2 while minimizing the uncertainties related to the attitude variations. We compare our measurements with OMI and GOME-2 tropospheric NO2 products when the latter are available. Above Rajasthan and the Po Valley, two areas where the NO2 field is homogeneous, data sets agree very well. Our measurements in this areas are respectively 0.1 ± 0.1 to 2.8 ± 1 × 1015 molec cm−2 and 2.5 ± 0.5 × 1016 molec cm−2. Flying downwind of Riyadh, our NO2 measurements show with a higher spatial resolution than OMI the structure of the megacities'exhaust plume. Moreover, our measurements indicate larger columns (up to 70% than the one seen by satellites. We also derived tropopsheric columns when no satellite data was available, if it was possible to get information on the visibility from satellite measurements of aerosol optical thickness. The maximum column we measured was above Benghazi, with 5.7 ± 2 × 1016 molec cm−2. This experiment also provides a confirmation for the recent finding of a soil signature above desert.

  5. Measuring atmospheric CO2 from space using Full Spectral Initiation (FSI WFM-DOAS

    Directory of Open Access Journals (Sweden)

    M. P. Barkley

    2006-01-01

    Full Text Available Satellite measurements of atmospheric CO2 concentrations are a rapidly evolving area of scientific research which can help reduce the uncertainties in the global carbon cycle fluxes and provide insight into surface sources and sinks. One of the emerging CO2 measurement techniques is a relatively new retrieval algorithm called Weighting Function Modified Differential Optical Absorption Spectroscopy (WFM-DOAS that has been developed by Buchwitz et al. (2000. This algorithm is designed to measure the total columns of CO2 (and other greenhouse gases through the application to spectral measurements in the near infrared (NIR, made by the SCIAMACHY instrument on-board ENVISAT. The algorithm itself is based on fitting the logarithm of a model reference spectrum and its derivatives to the logarithm of the ratio of a measured nadir radiance and solar irradiance spectrum. In this work, a detailed error assessment of this technique has been conducted and it has been found necessary to include suitable a priori information within the retrieval in order to minimize the errors on the retrieved CO2 columns. Hence, a more flexible implementation of the retrieval technique, called Full Spectral Initiation (FSI WFM-DOAS, has been developed which generates a reference spectrum for each individual SCIAMACHY observation using the estimated properties of the atmosphere and surface at the time of the measurement. Initial retrievals over Siberia during the summer of 2003 show that the measured CO2 columns are not biased from the input a priori data and that whilst the monthly averaged CO2 distributions contain a high degree of variability, they also contain interesting spatial features.

  6. Tomographic LP-DOAS measurements of 2D trace gas distributions above the city of Heidelberg, Germany

    Energy Technology Data Exchange (ETDEWEB)

    Poehler, Denis; Hartl, Andreas; Platt, Ulrich [Institute of Environmental Physics, University of Heidelberg (Germany)

    2007-07-01

    LP-DOAS (Long Path-Differential Optical Absorption Spectroscopy) is a well known remote sensing technique for measuring the average concentration of tropospheric trace gases along extended light paths in the open atmosphere. In order to retrieve information of the spatial trace gas distribution tomographic LP-DOAS measurements are useful. They combine the measurement along several intersecting light paths with tomographic inversion techniques and allow 2 and 3 dimensional retrieval of trace gas distributions. In a campaign in Heidelberg, Germany, a measurement set-up encompassing a total of 18 horizontal light paths by using three, Multibeam, LP-DOAS instruments is being tested. In the wavelength range from 285 nm to 365 nm the average concentrations of the trace gases NO{sub 2}, SO{sub 2}, O{sub 3}, HCHO and HONO along each light path could be retrieved with a temporal resolution below 15 minutes. The first evaluated data from winter 2005/06 show high accuracy for NO{sub 2} and SO{sub 2} mean concentrations. They allow deriving for these trace gases twodimensional distributions above the city. Different emission sources varying strongly in space and time can be identified. The results demonstrate that tomographic DOAS measurements can be used to study emissions and transport of trace gases and can be used to evaluate models predicting the air quality.

  7. First ground-based column measurements of CO{sub 2} in the tropics

    Energy Technology Data Exchange (ETDEWEB)

    Warneke, T.; Petersen, K.; Macatangay, R.; Notholt, J. [Institute of Environmental Physics, University of Bremen, Bremen (Germany); Koerner, S.; Jordan, A.; Gerbig, C.; Rothe, M. [Max-Planck-Institute for Biogeochemistry (MPI-BGC), Jena (Germany); Schrems, O. [Alfred Wegener Institute for Polar and Marine Research (AWI), Bremerhaven (Germany)

    2009-07-01

    The first ground-based remote sensing measurements of the column averaged volume mixing ratio of CO{sub 2} (X{sub CO{sub 2}}) for the inner tropics have been obtained at Paramaribo, Suriname (5.8 N, 55.2 W). Due to the migration of the ITCZ over the measurement location the probed air masses belong to the northern or southern hemisphere depending on the time of the year. The X{sub CO{sub 2}} shows an average annual increase in the Southern Hemisphere of 2.2 ppm for the time period 2004 to 2007, which agrees within the error with model simulations. Co-located in-situ measurements are strongly influenced by a local source. From the isotopic composition of the air samples the local source component is suggested to be the terrestrial biosphere. Using d{sup {sub 13C}} from the NOAA/ESRL stations Ascension Is. (ASC) and Ragged Point (RPB) the data has been corrected for the local source component. The corrected mixing ratios for the surface agree with model simulations for the measurement campaigns in the LDS (Southern Hemisphere), but not for the SDS (Northern Hemisphere).

  8. Long-path DOAS measurements of ozone and other species at Cape Arkona, Ruegen Island

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, R.; Flentje, H.; Karbach, H.J. [Institut fuer Troposphaerenforschung e.V. (IfT), Leipzig (Germany)]|[Institut fuer Umweltphysik (IUP), Heidelberg (Germany); Heintz, F.; Platt, U. [Institut fuer Umweltphysik (IUP), Heidelberg (Germany)

    1997-12-31

    A goal for this contribution was the installation of a DOAS system at Cape Arkona and the collection of a comprehensive and statistically representative data set of ozone and related species. Ozone data from Cape Arkona were used to derive long-term trends of this trace substance. In order to understand these trends in relation to local and regional anthropogenic influences, analysis of local air-chemical processes and meteorological conditions along with evaluation of available trace gas data should be performed. The comparison of point to long path ozone measurements should give an evaluation of the evenness of O{sub 3} concentrations. The first long term measurements of tropospheric concentrations of the NO{sub 3} radical should provide for a more accurate investigation of the importance of the NO{sub 3} radical in the night time chemistry and the non-photochemical conversion of NO{sub x} to HNO{sub 3}. (orig.)

  9. The high-resolution extraterrestrial solar spectrum (QASUMEFTS determined from ground-based solar irradiance measurements

    Directory of Open Access Journals (Sweden)

    J. Gröbner

    2017-09-01

    Full Text Available A high-resolution extraterrestrial solar spectrum has been determined from ground-based measurements of direct solar spectral irradiance (SSI over the wavelength range from 300 to 500 nm using the Langley-plot technique. The measurements were obtained at the Izaña Atmospheric Research Centre from the Agencia Estatal de Meteorología, Tenerife, Spain, during the period 12 to 24 September 2016. This solar spectrum (QASUMEFTS was combined from medium-resolution (bandpass of 0.86 nm measurements of the QASUME (Quality Assurance of Spectral Ultraviolet Measurements in Europe spectroradiometer in the wavelength range from 300 to 500 nm and high-resolution measurements (0.025 nm from a Fourier transform spectroradiometer (FTS over the wavelength range from 305 to 380 nm. The Kitt Peak solar flux atlas was used to extend this high-resolution solar spectrum to 500 nm. The expanded uncertainties of this solar spectrum are 2 % between 310 and 500 nm and 4 % at 300 nm. The comparison of this solar spectrum with solar spectra measured in space (top of the atmosphere gave very good agreements in some cases, while in some other cases discrepancies of up to 5 % were observed. The QASUMEFTS solar spectrum represents a benchmark dataset with uncertainties lower than anything previously published. The metrological traceability of the measurements to the International System of Units (SI is assured by an unbroken chain of calibrations leading to the primary spectral irradiance standard of the Physikalisch-Technische Bundesanstalt in Germany.

  10. TEMIS UV product validation using NILU-UV ground-based measurements in Thessaloniki, Greece

    Science.gov (United States)

    Zempila, Melina-Maria; van Geffen, Jos H. G. M.; Taylor, Michael; Fountoulakis, Ilias; Koukouli, Maria-Elissavet; van Weele, Michiel; van der A, Ronald J.; Bais, Alkiviadis; Meleti, Charikleia; Balis, Dimitrios

    2017-06-01

    This study aims to cross-validate ground-based and satellite-based models of three photobiological UV effective dose products: the Commission Internationale de l'Éclairage (CIE) erythemal UV, the production of vitamin D in the skin, and DNA damage, using high-temporal-resolution surface-based measurements of solar UV spectral irradiances from a synergy of instruments and models. The satellite-based Tropospheric Emission Monitoring Internet Service (TEMIS; version 1.4) UV daily dose data products were evaluated over the period 2009 to 2014 with ground-based data from a Norsk Institutt for Luftforskning (NILU)-UV multifilter radiometer located at the northern midlatitude super-site of the Laboratory of Atmospheric Physics, Aristotle University of Thessaloniki (LAP/AUTh), in Greece. For the NILU-UV effective dose rates retrieval algorithm, a neural network (NN) was trained to learn the nonlinear functional relation between NILU-UV irradiances and collocated Brewer-based photobiological effective dose products. Then the algorithm was subjected to sensitivity analysis and validation. The correlation of the NN estimates with target outputs was high (r = 0. 988 to 0.990) and with a very low bias (0.000 to 0.011 in absolute units) proving the robustness of the NN algorithm. For further evaluation of the NILU NN-derived products, retrievals of the vitamin D and DNA-damage effective doses from a collocated Yankee Environmental Systems (YES) UVB-1 pyranometer were used. For cloud-free days, differences in the derived UV doses are better than 2 % for all UV dose products, revealing the reference quality of the ground-based UV doses at Thessaloniki from the NILU-UV NN retrievals. The TEMIS UV doses used in this study are derived from ozone measurements by the SCIAMACHY/Envisat and GOME2/MetOp-A satellite instruments, over the European domain in combination with SEVIRI/Meteosat-based diurnal cycle of the cloud cover fraction per 0. 5° × 0. 5° (lat × long) grid cells. TEMIS

  11. Assessment of the quality of OSIRIS mesospheric temperatures using satellite and ground-based measurements

    Directory of Open Access Journals (Sweden)

    P. E. Sheese

    2012-12-01

    Full Text Available The Optical Spectrograph and InfraRed Imaging System (OSIRIS on the Odin satellite is currently in its 12th year of observing the Earth's limb. For the first time, continuous temperature profiles extending from the stratopause to the upper mesosphere have been derived from OSIRIS measurements of Rayleigh-scattered sunlight. Through most of the mesosphere, OSIRIS temperatures are in good agreement with coincident temperature profiles derived from other satellite and ground-based measurements. In the altitude region of 55–80 km, OSIRIS temperatures are typically within 4–5 K of those from the SABER, ACE-FTS, and SOFIE instruments on the TIMED, SciSat-I, and AIM satellites, respectively. The mean differences between individual OSIRIS profiles and those of the other satellite instruments are typically within the combined uncertainties and previously reported biases. OSIRIS temperatures are typically within 2 K of those from the University of Western Ontario's Purple Crow Lidar in the altitude region of 52–79 km, where the mean differences are within combined uncertainties. Near 84 km, OSIRIS temperatures exhibit a cold bias of 10–15 K, which is due to a cold bias in OSIRIS O2 A-band temperatures at 85 km, the upper boundary of the Rayleigh-scatter derived temperatures; and near 48 km OSIRIS temperatures exhibit a cold bias of 5–15 K, which is likely due to multiple-scatter effects that are not taken into account in the retrieval.

  12. OPUS BBM: Its performance and early results of ground-based measurements

    Science.gov (United States)

    Kuze, A.; Shibasaki, K.; Sano, T.; Kawashima, T.; Miyamura, N.; Tange, Y.; Yui, Y.; Suzuki, M.; Ogawa, T.

    2003-04-01

    OPUS(Ozone and Pollution measuring Ultraviolet Spectrometer) is the satellite-borne instrument for future Japanese mission. Its scientific goal is to monitor the tropospheric urban and severely polluted chemical species such as SO2 and NO2 as well as total and tropospheric ozone. Now its BBM has been constructed and under performance check. Several checks are now being made on performances under thermal and vacum environments suffered in orbit. The OPUS BBM showed very stable perfomance as expected. The CMOS type array detector reveals very low noise and high quantum efficiency suitable for space use. In this paper we show the results of performance check of OPUS BBM. We also carried out the ground-based, zenith sky (scatter light) measurement for checking the S/N ratio of OPUS BBM as well as for demonstrating its ability to derive NO2 in the atmosphere. A preliminary analysis result is shown, and also shown is the result of algorithm study for space mission.

  13. Airborne multi-axis DOAS measurements of atmospheric trace gases on CARIBIC long-distance flights

    Directory of Open Access Journals (Sweden)

    B. Dix

    2009-11-01

    Full Text Available A DOAS (Differential Optical Absorption Spectroscopy instrument was implemented and operated onboard a long-distance passenger aircraft within the framework of the CARIBIC project (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container. The instrument was designed to keep weight, size and power consumption low and to comply with civil aviation regulations. It records spectra of scattered light from three viewing directions (nadir, 10° above and below horizon using a miniaturized telescope system. The telescopes are integrated in the main pylon of the inlet system which is mounted at the belly of the aircraft. Fibre bundles transmit light from the telescopes to spectrograph-detector units inside the DOAS container instrument. The latter is part of the removable CARIBIC instrument container, which is installed monthly on the aircraft for a series of measurement flights.

    During 30 flight operations within three years, measurements of HCHO, HONO, NO2, BrO, O3 and the oxygen dimer O4 were conducted. All of these trace gases except BrO could be analysed with a 30 s time resolution. HONO was detected for the first time in a deep convective cloud over central Asia, while BrO, NO2 and O3 could be observed in tropopause fold regions. Biomass burning signatures over South America could be seen and measurements during ascent and descent provided information on boundary layer trace gas profiles (e.g. NO2 or HCHO.

  14. Mobile MAX-DOAS and in situ measurements of NO2 and SO2

    Science.gov (United States)

    Wittrock, Folkard; Peters, Enno; Seyler, André; Mathieu-Üffing, Barbara; Kattner, Lisa; Richter, Andreas; Burrows, John P.

    2017-04-01

    The project MeSMarT (Measurements of shipping emissions in the marine troposphere) has been established as a cooperation between the University of Bremen and the German Bundesamt für Seeschifffahrt und Hydrographie (Federal Maritime and Hydrographic Agency) to estimate the influence of shipping emissions on the chemistry of the atmospheric boundary layer and to establish a monitoring system for main shipping routes. As part of the project in 2015 a mobile lab has been set up, which includes among other instrumentation for air pollution and meteorological parameters a scientific-grade MAX-DOAS system as well as in situ instruments for nitrogen oxides and sulfur dioxide (trace level). Focusing on NO2 and SO2 we present intercomparison results between the different instruments onboard the mobile lab as well as comparisons to standard instrumentation used at different sites in Northern Germany within the project.

  15. Radiometric modeling and calibration of the Geostationary Imaging Fourier Transform Spectrometer (GIFTS) ground based measurement experiment

    Science.gov (United States)

    Tian, Jialin; Smith, William L.; Gazarik, Michael J.

    2008-12-01

    The ultimate remote sensing benefits of the high resolution Infrared radiance spectrometers will be realized with their geostationary satellite implementation in the form of imaging spectrometers. This will enable dynamic features of the atmosphere's thermodynamic fields and pollutant and greenhouse gas constituents to be observed for revolutionary improvements in weather forecasts and more accurate air quality and climate predictions. As an important step toward realizing this application objective, the Geostationary Imaging Fourier Transform Spectrometer (GIFTS) Engineering Demonstration Unit (EDU) was successfully developed under the NASA New Millennium Program, 2000-2006. The GIFTS-EDU instrument employs three focal plane arrays (FPAs), which gather measurements across the long-wave IR (LWIR), short/mid-wave IR (SMWIR), and visible spectral bands. The GIFTS calibration is achieved using internal blackbody calibration references at ambient (260 K) and hot (286 K) temperatures. In this paper, we introduce a refined calibration technique that utilizes Principle Component (PC) analysis to compensate for instrument distortions and artifacts, therefore, enhancing the absolute calibration accuracy. This method is applied to data collected during the GIFTS Ground Based Measurement (GBM) experiment, together with simultaneous observations by the accurately calibrated AERI (Atmospheric Emitted Radiance Interferometer), both simultaneously zenith viewing the sky through the same external scene mirror at ten-minute intervals throughout a cloudless day at Logan Utah on September 13, 2006. The accurately calibrated GIFTS radiances are produced using the first four PC scores in the GIFTS-AERI regression model. Temperature and moisture profiles retrieved from the PC-calibrated GIFTS radiances are verified against radiosonde measurements collected throughout the GIFTS sky measurement period. Using the GIFTS GBM calibration model, we compute the calibrated radiances from data

  16. Mapping the East African Ionosphere Using Ground-based GPS TEC Measurements

    Science.gov (United States)

    Mengist, Chalachew Kindie; Kim, Yong Ha; Yeshita, Baylie Damtie; Workayehu, Abyiot Bires

    2016-03-01

    The East African ionosphere (3°S-18°N, 32°E-50°E) was mapped using Total Electron Content (TEC) measurements from ground-based GPS receivers situated at Asmara, Mekelle, Bahir Dar, Robe, Arbaminch, and Nairobi. Assuming a thin shell ionosphere at 350 km altitude, we project the Ionospheric Pierce Point (IPP) of a slant TEC measurement with an elevation angle of >10° to its corresponding location on the map. We then infer the estimated values at any point of interest from the vertical TEC values at the projected locations by means of interpolation. The total number of projected IPPs is in the range of 24-66 at any one time. Since the distribution of the projected IPPs is irregularly spaced, we have used an inverse distance weighted interpolation method to obtain a spatial grid resolution of 1°×1° latitude and longitude, respectively. The TEC maps were generated for the year 2008, with a 2 hr temporal resolution. We note that TEC varies diurnally, with a peak in the late afternoon (at 1700 LT), due to the equatorial ionospheric anomaly. We have observed higher TEC values at low latitudes in both hemispheres compared to the magnetic equatorial region, capturing the ionospheric distribution of the equatorial anomaly. We have also confirmed the equatorial seasonal variation in the ionosphere, characterized by minimum TEC values during the solstices and maximum values during the equinoxes. We evaluate the reliability of the map, demonstrating a mean error (difference between the measured and interpolated values) range of 0.04-0.2 TECU (Total Electron Content Unit). As more measured TEC values become available in this region, the TEC map will be more reliable, thereby allowing us to study in detail the equatorial ionosphere of the African sector, where ionospheric measurements are currently very few.

  17. Validation of five years (2003–2007 of SCIAMACHY CO total column measurements using ground-based spectrometer observations

    Directory of Open Access Journals (Sweden)

    A. M. Poberovskii

    2010-10-01

    Full Text Available This paper presents a validation study of SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY carbon monoxide (CO total column measurements from the Iterative Maximum Likelihood Method (IMLM algorithm using ground-based spectrometer observations from twenty surface stations for the five year time period of 2003–2007. Overall we find a good agreement between SCIAMACHY and ground-based observations for both mean values as well as seasonal variations. For high-latitude Northern Hemisphere stations absolute differences between SCIAMACHY and ground-based measurements are close to or fall within the SCIAMACHY CO 2σ precision of 0.2 × 1018 molecules/cm2 (∼10% indicating that SCIAMACHY can observe CO accurately at high Northern Hemisphere latitudes. For Northern Hemisphere mid-latitude stations the validation is complicated due to the vicinity of emission sources for almost all stations, leading to higher ground-based measurements compared to SCIAMACHY CO within its typical sampling area of 8° × 8°. Comparisons with Northern Hemisphere mountain stations are hampered by elevation effects. After accounting for these effects, the validation provides satisfactory results. At Southern Hemisphere mid- to high latitudes SCIAMACHY is systematically lower than the ground-based measurements for 2003 and 2004, but for 2005 and later years the differences between SCIAMACHY and ground-based measurements fall within the SCIAMACHY precision. The 2003–2004 bias is consistent with previously reported results although its origin remains under investigation. No other systematic spatial or temporal biases could be identified based on the validation presented in this paper. Validation results are robust with regard to the choices of the instrument-noise error filter, sampling area, and time averaging required for the validation of SCIAMACHY CO total column measurements. Finally, our results show that the spatial coverage of the ground-based

  18. MAX-DOAS formaldehyde slant column measurements during CINDI: intercomparison and analysis improvement

    Directory of Open Access Journals (Sweden)

    G. Pinardi

    2013-01-01

    Full Text Available We present intercomparison results for formaldehyde (HCHO slant column measurements performed during the Cabauw Intercomparison campaign of Nitrogen Dioxide measuring Instruments (CINDI that took place in Cabauw, the Netherlands, in summer 2009. During two months, nine atmospheric research groups simultaneously operated MAX-DOAS (MultiAXis Differential Optical Absorption Spectroscopy instruments of various designs to record UV-visible spectra of scattered sunlight at different elevation angles that were analysed using common retrieval settings. The resulting HCHO data set was found to be highly consistent, the mean difference between instruments generally not exceeding 15% or 7.5 × 1015 molec cm−2, for all viewing elevation angles. Furthermore, a sensitivity analysis was performed to investigate the uncertainties in the HCHO slant column retrieval when varying key input parameters such as the molecular absorption cross sections, correction terms for the Ring effect or the width and position of the fitting interval. This study led to the identification of potentially important sources of errors associated with cross-correlation effects involving the Ring effect, O4, HCHO and BrO cross sections and the DOAS closure polynomial. As a result, a set of updated recommendations was formulated for HCHO slant column retrieval in the 336.5–359 nm wavelength range. To conclude, an error budget is proposed which distinguishes between systematic and random uncertainties. The total systematic error is estimated to be of the order of 20% and is dominated by uncertainties in absorption cross sections and related spectral cross-correlation effects. For a typical integration time of one minute, random uncertainties range between 5 and 30%, depending on the noise level of individual instruments.

  19. Investigation of tropical cirrus cloud properties using ground based lidar measurements

    Science.gov (United States)

    Dhaman, Reji K.; Satyanarayana, Malladi; Krishnakumar, V.; Mahadevan Pillai, V. P.; Jayeshlal, G. S.; Raghunath, K.; Venkat Ratnam, M.

    2016-05-01

    Cirrus clouds play a significant role in the Earths radiation budget. Therefore, knowledge of geometrical and optical properties of cirrus cloud is essential for the climate modeling. In this paper, the cirrus clouds microphysical and optical properties are made by using a ground based lidar measurements over an inland tropical station Gadanki (13.5°N, 79.2°E), Andhra Pradesh, India. The variation of cirrus microphysical and optical properties with mid cloud temperature is also studied. The cirrus clouds mean height is generally observed in the range of 9-17km with a peak occurrence at 13- 14km. The cirrus mid cloud temperature ranges from -81°C to -46°C. The cirrus geometrical thickness ranges from 0.9- 4.5km. During the cirrus occurrence days sub-visual, thin and dense cirrus were at 37.5%, 50% and 12.5% respectively. The monthly cirrus optical depth ranges from 0.01-0.47, but most (extinction ranges from 2.8E-06 to 8E-05 and depolarization ratio and lidar ratio varies from 0.13 to 0.77 and 2 to 52 sr respectively. A positive correlation exists for both optical depth and extinction with the mid-cloud temperature. The lidar ratio shows a scattered behavior with mid-cloud temperature.

  20. A ground-based measurement of the relativistic beaming effect in a detached double WD binary

    CERN Document Server

    Shporer, Avi; Steinfadt, Justin D R; Bildsten, Lars; Howell, Steve B; Mazeh, Tsevi

    2010-01-01

    We report on the first ground-based measurement of the relativistic beaming effect (aka Doppler boosting). We observed the beaming effect in the detached, non-interacting eclipsing double white dwarf (WD) binary NLTT 11748. Our observations were motivated by the system's high mass ratio and low luminosity ratio, leading to a large beaming-induced variability amplitude at the orbital period of 5.6 hr. We observed the system during 3 nights at the 2.0m Faulkes Telescope North with the SDSS-g' filter, and fitted the data simultaneously for the beaming, ellipsoidal and reflection effects. Our fitted relative beaming amplitude is (3.0 +/- 0.4) x 10^(-3), consistent with the expected amplitude from a blackbody spectrum given the photometric primary radial velocity amplitude and effective temperature. This result is a first step in testing the relation between the photometric beaming amplitude and the spectroscopic radial velocity amplitude in NLTT 11748 and similar systems. We did not identify any variability due t...

  1. Heavy precipitation retrieval from combined satellite observations and ground-based lightning measurements

    Science.gov (United States)

    Mugnai, A.; Dietrich, S.; Casella, D.; di Paola, F.; Formenton, M.; Sanò, P.

    2010-09-01

    We have developed a series of algorithms for the retrieval of precipitation (especially, heavy precipitation) over the Mediterranean area using satellite observations from the available microwave (MW) radiometers onboard low Earth orbit (LEO) satellites and from the visible-infrared (VIS-IR) SEVIRI radiometer onboard the European geosynchronous (GEO) satellite Meteosat Second Generation (MSG), in conjunction with lightning data from ground-based networks - such as ZEUS and LINET. These are: • A new approach for precipitation retrieval from space (which we call the Cloud Dynamics and Radiation Database approach, CDRD) that incorporates lightning and environmental/dynamical information in addition to the upwelling microwave brightness temperatures (TB’s) so as to reduce the retrieval uncertainty and improve the retrieval performance; • A new combined MW-IR technique for producing frequent precipitation retrievals from space (which we call PM-GCD technique), that uses passive-microwave (PM) retrievals in conjunction with lightning information and the Global Convection Detection (GCD) technique to discriminate deep convective clouds within the GEO observations; • A new morphing approach (which we call the Lightning-based Precipitation Evolving Technique, L-PET) that uses the available lightning measurements for propagating the rainfall estimates from satellite-borne MW radiometers to a much higher time resolution than the MW observations. We will present and discuss our combined MW/IR/lightning precipitation algorithms and analyses with special reference to some case studies over the western Mediterranean.

  2. Retrieval of aerosol composition using ground-based remote sensing measurements

    Science.gov (United States)

    Xie, Yisong; Li, Zhengqiang; Zhang, Ying; Li, Donghui; Li, Kaitao

    2016-04-01

    The chemical composition and mixing states of ambient aerosol are the main factors deciding aerosol microphysical and optical properties, and thus have significant impacts on regional or global climate change and air quality. Traditional approaches to detect atmospheric aerosol composition include sampling with laboratory analysis and in-situ measurements. They can accurately acquire aerosol components, however, the sampling or air exhausting could change the status of ambient aerosol or lead to some mass loss. Additionally, aerosol is usually sampled at the surface level so that it is difficult to detect the columnar aerosol properties. Remote sensing technology, however, can overcome these problems because it is able to detect aerosol information of entire atmosphere by optical and microphysical properties without destructing the natural status of ambient aerosol. This paper introduces a method to acquire aerosol composition by the remote sensing measurements of CIMEL CE318 ground-based sun-sky radiometer. A six component aerosol model is used in this study, including one strong absorbing component Black Carbon (BC), two partly absorbing components Brown Carbon (BrC) and Mineral Dust (MD), two scattering components Ammonia Sulfate-like (AS) and Sea Salt (SS), and Aerosol Water uptake (AW). Sensitivity analysis are performed to find the most sensitive parameters to each component and retrieval method for each component is accordingly developed. Different mixing models such as Maxwell-Garnett (MG), Bruggeman (BR) and Volume Average (VA) are also studied. The residual minimization method is used by comparing remote sensing measurements and simulation outputs to find the optimization of aerosol composition (including volume fraction and mass concentration of each component). This method is applied to measurements obtained from Beijing site under different weather conditions, including polluted haze, dust storm and clean days, to investigate the impacts of mixing

  3. Retrieval of atmospheric optical parameters from ground-based sun-photometer measurements for Zanjan, Iran

    Science.gov (United States)

    Bayat, A.; Masoumi, A.; Khalesifard, H. R.

    2011-05-01

    We are reporting the results of ground-based spectroradiometric measurements on aerosols and water vapor in the atmosphere of Zanjan for the period of October 2006 to September 2008 using a CIMEL CE318-2 sun-photometer. Zanjan is a city in Northwest Iran, located at 36.70° N, 48.51° E, and at an altitude of 1800 m a.m.s.l. (above mean sea level). The spectral aerosol optical depth, Ångström exponent, and columnar water vapor have been calculated using the data recorded by the sun-photometer through the direct measurements on the sun radiance (sun-mode). The average values of aerosol optical depth at 440 nm, columnar water vapor, and the Ångström exponent, α, during the mentioned period are measured as, 0.28 ± 0.14, 0.57 ± 0.37 cm and 0.73 ± 0.30, respectively. The maximum (minimum) value of the aerosol optical depth was recorded in May 2007 (November 2007), and that of columnar water vapor, in July 2007 (January 2008). Using the least-squares method, the Ångström exponent was calculated in the spectral interval 440-870 nm along with α1 and α2, the coefficients of a second order polynomial fit to the plotted logarithm of aerosol optical depth versus the logarithm of wavelength. The coefficient α2 shows that most of the aerosols in the Zanjan area have dimensions larger than 1 micron. The calculated values for α2 - α1 indicate that 80 % of the aerosols are in the coarse-mode (>1 μm) and 20 % of them are in the fine-mode (<1 μm). Comparison of α2 - α1 for the atmosphere over Zanjan with other regions indicates dust particles are the most dominant aerosols in the region.

  4. NDACC/SAOZ UV-visible total ozone measurements: improved retrieval and comparison with correlative ground-based and satellite observations

    Directory of Open Access Journals (Sweden)

    F. Hendrick

    2011-06-01

    Full Text Available Accurate long-term monitoring of total ozone is one of the most important requirements for identifying possible natural or anthropogenic changes in the composition of the stratosphere. For this purpose, the NDACC (Network for the Detection of Atmospheric Composition Change UV-visible Working Group has made recommendations for improving and homogenizing the retrieval of total ozone columns from twilight zenith-sky visible spectrometers. These instruments, deployed all over the world in about 35 stations, allow measuring total ozone twice daily with limited sensitivity to stratospheric temperature and cloud cover. The NDACC recommendations address both the DOAS spectral parameters and the calculation of air mass factors (AMF needed for the conversion of O3 slant column densities into vertical column amounts. The most important improvement is the use of O3 AMF look-up tables calculated using the TOMS V8 (TV8 O3 profile climatology, that allows accounting for the dependence of the O3 AMF on the seasonal and latitudinal variations of the O3 vertical distribution. To investigate their impact on the retrieved ozone columns, the recommendations have been applied to measurements from the NDACC/SAOZ (Système d'Analyse par Observation Zénithale network. The revised SAOZ ozone data from eight stations deployed at all latitudes have been compared to TOMS, GOME-GDP4, SCIAMACHY-TOSOMI, SCIAMACHY-OL3, OMI-TOMS, and OMI-DOAS satellite overpass observations, as well as to those of collocated Dobson and Brewer instruments at Observatoire de Haute Provence (44° N, 5.5° E and Sodankyla (67° N, 27° E, respectively. A significantly better agreement is obtained between SAOZ and correlative reference ground-based measurements after applying the new O3 AMFs. However, systematic seasonal differences between SAOZ and satellite instruments remain. These are shown to mainly originate from (i a possible

  5. TOMS and Ground-based Measurements: Long-term Trends, Spatial Variability, Cloud Effects, and Data Quality.

    Science.gov (United States)

    Eide, H. A.; Dahlback, A.; Stamnes, K.; Høyskar, B.; Olsen, R.; Schmidlin, F.; Tsay, S.

    2003-12-01

    Ground-based measurements and TOMS measurements are mutually beneficial to each other. Ground-based measurements of UV radiation and total column ozone amounts are important for the validation of TOMS measurements. For example, it has been shown that TOMS measurements has a tendency to under-estimate ground UV exposure. Some of these effects can perhaps be ascribed to local cloud effects or choice of ozone profiles in the retrieval algorithm. More ground-based measurements are needed to establish the cause of these discrepancies. Recent technology advances have made ground-based measurements of UV doses and ozone column amounts with inexpensive multi-channel filter instruments not only possible, but also an attractive alternative to other more labor-intensive and weather dependent methods. Filter instruments can operate unattended for long periods of time, and it is possible to obtain accurate ozone column amounts even on cloudy days. We present results from extensive comparisons of the performance of several ground-based instruments (the NILU-UV and GUV filter instruments, as well as the Dobson and Brewer instruments) against the EP-TOMS instrument. The data used in the comparisons are from three different sites where we have had the opportunity to operate more than one type of UV instruments for extended periods of time. The sites include the University of Oslo, Norway, the NASA Goddard Space Flight Center facilities at Wallops Island, VA, and Greenbelt, MD and the University of Alaska, Fairbanks (during the TOMS3F campaign). Our results show that ozone column amounts obtained with current filter-type instruments are just as good as those obtained with the Dobson instrument, and might even out-perform the Dobson instrument on cloudy days. The TOMS measurements are shown to exhibit some more variability, but there is on average very good agreement with the ground- based measurements even for high solar zenith angles (SZA). Further more, our comparison shows that

  6. Confronting remote sensing product with ground base measurements across time and scale

    Science.gov (United States)

    Pourmokhtarian, A.; Dietze, M.

    2015-12-01

    Ecosystem models are essential tools in forecasting ecosystem responses to global climate change. One of the most challenging issues in ecosystem modeling is scaling while preserving landscape characteristics and minimizing loss of information, when moving from point observation to regional scale. There is a keen interest in providing accurate inputs for ecosystem models which represent ecosystem initial state conditions. Remote sensing land cover products, such as Landsat NLCD and MODIS MCD12Q1, provide extensive spatio-temporal coverage but do not capture forest composition and structure. Lidar and hyperspectral have the potential to meet this need but lack sufficient spatial and historical coverage. Forest inventory measurements provide detailed information on the landscape but in a very small footprint. Combining inventory and land cover could improve estimates of ecosystem state and characteristic across time and space. This study focuses on the challenges associated with fusing and scaling the US Forest Service FIA database and NLCD across regional scales to quantify ecosystem characteristics and reduce associated uncertainties. Across Southeast of U.S. 400 stratified random samples of 10x10 km2 landscapes were selected. Data on plant density, species, age, and DBH of trees in FIA plots within each site were extracted. Using allometry equations, the canopy cover of different plant functional types (PFTs) was estimated using a PPA-style canopy model and used to assign each inventory plot to a land cover class. Inventory and land cover were fused in a Bayesian model that adjusts the fractional coverage of inventory plots while accounting for multiple sources of uncertainty. Results were compared to estimates derived from inventory alone, land cover alone, and model spin-up alone. Our findings create a framework of data assimilation to better interpret remote sensing data using ground-based measurements.

  7. Scanning and mobile multi-axis DOAS measurements of SO2 and NO2 emissions from an electric power plant in Montevideo, Uruguay

    Science.gov (United States)

    Frins, E.; Bobrowski, N.; Osorio, M.; Casaballe, N.; Belsterli, G.; Wagner, T.; Platt, U.

    2014-12-01

    In March 2012 the emissions of NO2 and SO2 from a power station located on the east side of Montevideo Bay (34° 53‧ 10″ S, 56° 11‧ 49″ W) were quantified by simultaneously using mobile and scanning multi-axis differential optical absorption spectroscopy (in the following mobile DOAS and scanning DOAS, respectively). The facility produces electricity by means of two technologies: internal combustion motors and steam generators. The motors are powered with centrifuged heavy oil and produce a maximum power of 80 MW approximately. The steam generators produce approximately 305 MW and are powered with heavy fuel oil. We compare the emissions obtained from the measured slant column densities (mobile DOAS and scanning DOAS) with the emissions estimated from fuel mass balance. On one occasion it was possible to distinguish between the two types of sources, observing two plumes with different SO2 and NO2 emission rates. During the period of the campaign the mean SO2 emission flux was determined to be 0.36 (±0.12) kg s-1 and 0.26 (±0.09) kg s-1 retrieved from mobile and scanning DOAS respectively, while the calculated SO2 flux from the sulphur content of the fuel was 0.34 (±0.03) kg s-1. The average NO2 flux calculated from mobile DOAS was determined to be 11 (±3) × 10-3 kg s-1. Using the scanning DOAS approach a mean NO2 flux of 5.4 (±1.7) × 10-3 kg s-1 was obtained, which is significantly lower than by the mobile measurements. The differences between the results of mobile MAX-DOAS measurements and scanning DOAS measurements are most probably caused by the variability and the limited knowledge of the wind speed and direction.

  8. Soil moisture on Polish territory - comparison of satellite and ground-based measurements

    Science.gov (United States)

    Rojek, Edyta; Łukowski, Mateusz; Marczewski, Wojciech; Usowicz, Bogusław

    2014-05-01

    Assessment of water resources due to changing climatic conditions in time and space is still very uncertain. The territory of Poland has a limited resource of waters, occasionally resulting in small agricultural droughts. From the other side intense rainfalls, floods or run-offs, causing soil erosion are observed. Therefore, it is important to predict and prevent of this adverse phenomena. Huge spatial variability of soil moisture does not allow for accurate estimation of its distribution using ground-based measurements. SMOS soil moisture data are quite much inherently consistent in time and space, but their validation is still a challenge for further use in the climate and hydrology studies. This is the motivation for the research: to examine soil moisture from SMOS and ground based stations of the SWEX network held over eastern Poland. The presented results are related to changes of the soil moisture on regional scales for Poland in the period 2010-2013. Some results with SMOS L2 data are extended on continental scales for Europe. Time series from ground and satellite SMOS data sources were compared by regression methods. The region of Poland indicates clearly some genetic spatial distributions in weekly averaged values. In continental scales, the country territory contrasts evidently to Lithuania and in Polesie, and indicates seasonal cycling observed in archives and well known traditional records. The central part of Poland is repeatedly susceptible on droughts with soil moisture values ranging from about 0.02 to 0.20 m3 m-3. SMOS data allows on creating systematic drought data for Poland and watching annual changes, and differences to other drought services kept on national scales for agricultural purposes. We bound that drought susceptibility to the content of sand clay components and the land use there. Lack of rainfall in the late 2011 summer, caused a significant deficit of water in soil moisture content (below 0.05 m3 m-3) throughout the entire country

  9. Validation of NH3 satellite observations by ground-based FTIR measurements

    Science.gov (United States)

    Dammers, Enrico; Palm, Mathias; Van Damme, Martin; Shephard, Mark; Cady-Pereira, Karen; Capps, Shannon; Clarisse, Lieven; Coheur, Pierre; Erisman, Jan Willem

    2016-04-01

    Global emissions of reactive nitrogen have been increasing to an unprecedented level due to human activities and are estimated to be a factor four larger than pre-industrial levels. Concentration levels of NOx are declining, but ammonia (NH3) levels are increasing around the globe. While NH3 at its current concentrations poses significant threats to the environment and human health, relatively little is known about the total budget and global distribution. Surface observations are sparse and mainly available for north-western Europe, the United States and China and are limited by the high costs and poor temporal and spatial resolution. Since the lifetime of atmospheric NH3 is short, on the order of hours to a few days, due to efficient deposition and fast conversion to particulate matter, the existing surface measurements are not sufficient to estimate global concentrations. Advanced space-based IR-sounders such as the Tropospheric Emission Spectrometer (TES), the Infrared Atmospheric Sounding Interferometer (IASI), and the Cross-track Infrared Sounder (CrIS) enable global observations of atmospheric NH3 that help overcome some of the limitations of surface observations. However, the satellite NH3 retrievals are complex requiring extensive validation. Presently there have only been a few dedicated satellite NH3 validation campaigns performed with limited spatial, vertical or temporal coverage. Recently a retrieval methodology was developed for ground-based Fourier Transform Infrared Spectroscopy (FTIR) instruments to obtain vertical concentration profiles of NH3. Here we show the applicability of retrieved columns from nine globally distributed stations with a range of NH3 pollution levels to validate satellite NH3 products.

  10. Ground-based and airborne measurements of volcanic gas emissions at White Island in New Zealand

    Science.gov (United States)

    Tirpitz, Jan-Lukas; Poehler, Denis; Bobrowski, Nicole; Christenson, Bruce; Platt, Ulrich

    2017-04-01

    Quantitative understanding of volcanic gas emissions has twofold relevance for nature and society: 1) Variation in gas emission and/or in emitted gas ratios are tracers of the dynamic processes in the volcano interior indicating its activity. 2) Volcanic degassing plays an important role for the Earth's climate, for local sometimes even regional air quality and atmospheric chemistry. In autumn 2015, a campaign to White Island Volcano in New Zealand was organized to perform ground-based as well as airborne in-situ and remote sensing gas measurements of sulfur dioxide (SO2), carbon dioxide (CO2) and bromine monoxide (BrO). For all three gases the ratios and total emission rates were determined in different plume types and ages. An overview over the data will be presented with focus on the two most notable outcomes: 1) The first determination of the BrO/SO2 ratio in the White Island plume and a minimum estimate of the volcano's bromine emission rate; two of many parameters, which are important to assess the impact of volcanic degassing on the atmospheric halogen chemistry. 2) In-situ SO2 data was very successfully recorded with the PITSA, a prototype of a portable and cost-effective optical instrument. It is based on the principle of non-dispersive UV absorption spectroscopy and features different advantages over the customary electrochemical sensors, including a sub second response time, negligible cross sensitivities to other gases, and inherent calibration. The campaign data demonstrates the capabilities and limitations of the PITSA and shows, that it can be well applied as substitute for conventional electrochemical systems.

  11. Analysis of ground-based 222Rn measurements over Spain: Filling the gap in southwestern Europe

    Science.gov (United States)

    Grossi, C.; Àgueda, A.; Vogel, F. R.; Vargas, A.; Zimnoch, M.; Wach, P.; Martín, J. E.; López-Coto, I.; Bolívar, J. P.; Morguí, J. A.; Rodó, X.

    2016-09-01

    Harmonized atmospheric 222Rn observations are required by the scientific community: these data have been lacking in southern Europe. We report on three recently established ground-based atmospheric 222Rn monitoring stations in Spain. We characterize the variability of atmospheric 222Rn concentrations at each of these stations in relation to source strengths, local, and regional atmospheric processes. For the study, measured atmospheric 222Rn concentrations, estimated 222Rn fluxes, and regional footprint analysis have been used. In addition, the atmospheric radon monitor operating at each station has been compared to a 222Rn progeny monitor. Annual means of 222Rn concentrations at Gredos (GIC3), Delta de l'Ebre (DEC3), and Huelva (UHU) stations were 17.3 ± 2.0 Bq m-3, 5.8 ± 0.8 Bq m-3, and 5.1 ± 0.7 Bq m-3, respectively. The GIC3 station showed high 222Rn concentration differences during the day and by seasons. The coastal station DEC3 presented background concentrations typical of the region, except when inland 222Rn-rich air masses are transported into the deltaic area. The highest 222Rn concentrations at UHU station were observed when local recirculation facilitates accumulation of 222Rn from nearby source represented by phosphogypsum piles. Results of the comparison performed between monitors revealed that the performance of the direct radon monitor is not affected by meteorological conditions, whereas the 222Rn progeny monitor seems to underestimate 222Rn concentrations under saturated atmospheric conditions. Initial findings indicate that the monitor responses seem to be in agreement for unsaturated atmospheric conditions but a further long-term comparison study will be needed to confirm this result.

  12. On reconciling ground-based with spaceborne normalized radar cross section measurements

    DEFF Research Database (Denmark)

    Baumgartner, Francois; Munk, Jens; Jezek, K C

    2002-01-01

    This study examines differences in the normalized radar cross section, derived from ground-based versus spaceborne radar data. A simple homogeneous half-space model, indicates that agreement between the two improves as 1) the distance from the scatterer is increased; and/or 2) the extinction...

  13. Unattended instruments for ground-based hyperspectral measurements: development and application for plant photosynthesis monitoring

    Science.gov (United States)

    Cogliati, S.; Rossini, M.; Meroni, M.; Barducci, A.; Julitta, T.; Colombo, R.

    2011-12-01

    The aim of the present work is the development of ground-based hyperspectral systems capable of collecting continuous and long-term hyperspectral measurements of the Earth-surface. The development of such instruments includes the optical design, the development of the data acquisition (Auto3S) and processing software as well as the definition of the calibration procedures. In particular an in-field calibration methodologie based on the comparison between field spectra and data modeled using Radiative Transfer (RT) approach has been proposed to regularly upgrade instrument calibration coefficients. Two different automatic spectrometric systems have been developed: the HyperSpectral Irradiometer (HSI) [Meroni et al., 2011] and the Multiplexer Radiometer Irradiometer (MRI) [Cogliati, 2011]. Both instruments are able to continuously measure: sun incoming irradiance (ETOT) and irradiance (ES, HSI)/radiance (LS, MRI) upwelling from the investigated surface. Both instruments employ two Ocean Optics HR4000 spectrometers sharing the same optical signal that allow to simultaneously collect "fine" (1 nm Full Width at Half Maximum, FWHM) spectra in the 400-1000 nm rangeand "ultra-fine" (0.1 nm FWHM) spectra within the 700-800 nm. The collected optical data allow to estimate biochemical/structural properties of vegetation (e.g. NDVI) as well as its photosynthetic efficiency through the Photochemical Reflectance Index (PRI) and the analysis of sun-induced chlorophyll Fluorescence in the O2-A Fraunhofer line (F@760). The automatic instruments were operated in coordination with eddy covariance flux tower measurements of carbon exchange in the framework of several field campaigns: HSI was employed in a subalpine pasture (2009-ongoing) (www.phenoalp.eu) while MRI was employed in 2009 in the Sen3Exp field survey promoted by the European Space Agency as consolidation study to the future mission Sentinel-3. Results show that the proposed instruments succeeded in collecting continuous

  14. Comparison of GOME tropospheric NO2 columns with NO2 profiles deduced from ground-based in situ measurements

    Directory of Open Access Journals (Sweden)

    D. Schaub

    2006-01-01

    Full Text Available Nitrogen dioxide (NO2 vertical tropospheric column densities (VTCs retrieved from the Global Ozone Monitoring Experiment (GOME are compared to coincident ground-based tropospheric NO2 columns. The ground-based columns are deduced from in situ measurements at different altitudes in the Alps for 1997 to June 2003, yielding a unique long-term comparison of GOME NO2 VTC data retrieved by a collaboration of KNMI (Royal Netherlands Meteorological Institute and BIRA/IASB (Belgian Institute for Space Aeronomy with independently derived tropospheric NO2 profiles. A first comparison relates the GOME retrieved tropospheric columns to the tropospheric columns obtained by integrating the ground-based NO2 measurements. For a second comparison, the tropospheric profiles constructed from the ground-based measurements are first multiplied with the averaging kernel (AK of the GOME retrieval. The second approach makes the comparison independent from the a priori NO2 profile used in the GOME retrieval. This allows splitting the total difference between the column data sets into two contributions: one that is due to differences between the a priori and the ground-based NO2 profile shapes, and another that can be attributed to uncertainties in both the remaining retrieval parameters (such as, e.g., surface albedo or aerosol concentration and the ground-based in situ NO2 profiles. For anticyclonic clear sky conditions the comparison indicates a good agreement between the columns (n=157, R=0.70/0.74 for the first/second comparison approach, respectively. The mean relative difference (with respect to the ground-based columns is −7% with a standard deviation of 40% and GOME on average slightly underestimating the ground-based columns. Both data sets show a similar seasonal behaviour with a distinct maximum of spring NO2 VTCs. Further analysis indicates small GOME columns being systematically smaller than the ground-based ones. The influence of different shapes in the a

  15. Measuring SO2 flow rate emission from ships by means of DOAS Spectrometer

    Science.gov (United States)

    Masieri, Samuele; Giovanelli, Giorgio; Bortoli, Daniele; Kostadinov, Ivan; Petritoli, Andrea; Premuda, Margherita; Ravegnani, Fabrizio

    2010-05-01

    The ships emissions are considered as a potential source of pollutants in harbour and nearby urban areas. For this reason the development of remote sensing methods for continuous monitoring of flow rate ship emissions is subject of increasing interest. This work presents a new approach for implementation of off-axis DOAS measurements devoted to this aim. The method, especially developed, was tested in a field campaign for measuring of ships gas emissions. The technique consists of some scanning in a vertical plane normal to ships direction at different line of sight, i.e. 1,2,3,4,5,6,8,10,15,20,30,40° over the horizon. The selected measurements performed before and after the passage of ships are used to retrieve the difference in SO2 optical depth. This difference is therefore used to retrieve flow rate emission of this gas. This technique was applied in Venice for a period of 5 month. Detailed description of adopted method and obtained results are presented.

  16. NOx emissions of various sources in Romania and the Rhein-Main region in Germany based on mobile MAX-DOAS measurements of NO2.

    Science.gov (United States)

    Riffel, Katharina; Sebastian, Donner; Shaiganfar, Reza; Wagner, Thomas; Dörner, Steffen

    2016-04-01

    The MAX DOAS-Method (Multi-AXis Differential Optical Absorption Spectroscopy) is used to analyze different trace gases (e.g. NO2, SO2, HCHO) at the same time and to determine the trace gas vertical column density (vertically integrated concentration). In summer 2015 we performed car-MAX-DOAS measurements in Romania during the AROMAT2 campaign. We encircled Bucharest at different weather situations and different times of the day. Afterwards the total NOx emissions were derived from the mobile MAX-DOAS observations in combination with wind data. In Germany we performed the same measurement procedure in fall/ winter/ spring 2015 /2016 by encircling the cities Mainz and Frankfurt. For the setting we mounted two MAX-DOAS instruments with different viewing directions (forward and backward) on the roof of a car. One instrument is a commercial mini MAX-DOAS that is built by the German company Hoffmann Messtechnik. The second one was built at the MPI in Mainz. This so-called Tube MAX-DOAS uses an AVANTES spectrometer with better optical characteristics than Hoffmann's mini MAX-DOAS. The advantage of two instruments working at the same time is (besides redundancy) that localized emission plumes can be measured from different directions at different locations. Thus, especially for emission plumes from power plants, tomographic methods can be applied to derive information about the plume altitude. Car-MAX-DOAS observations can cover large areas at a short time with reasonable resolution (depending on the speed of the car and the instruments integration time). Thus these measurements are well suited to validate satellites observations. This work will show the first AROMAT2 results of NOx emissions derived in Romania and in the Rhein-Main region, which is one of the most polluted area in Germany.

  17. a Compact Dial LIDAR for Ground-Based Ozone Atmospheric Profiling Measurements

    Science.gov (United States)

    De Young, R.; Carrion, W.; Pliutau, D.; Ganoe, R. E.

    2013-12-01

    A compact differential absorption lidar (DIAL) system has been developed at NASA Langley Research Center to provide ozone, aerosol and cloud atmospheric measurements in a mobile trailer for ground-based atmospheric ozone campaigns. This lidar will be integrated into the Air Quality lidar Network (AQLNet) currently made up of four other ozone lidars across the country. The lidar system consists of a UV and green laser transmitter, a telescope and an optical signal receiver box with associated Licel photon counting and analog channels. The laser transmitter consist of a Coherent Evolution 30 TEM00 1-kHz diode pumped Q-switched Nd:YLF inter-cavity doubled laser pumping a Ce:LiCAF tunable UV laser with all the associated power and lidar control support units on a single system rack. A custom-designed Ce:LiCAF tunable UV laser has a wavelength range of 282 to 300-nm that is selectable between two or more wavelengths. The current wavelengths are online 286.4 nm and offline 293.1 nm. The 527-nm visible beam is transmitted into the atmosphere for aerosol measurements. The fourth harmonic 262 nm beam is split by a beamsplitter into two pump beams that pump each face of the Ce:LiCAF crystal. A short laser cavity consisting of a 60% reflective (1m radius of curvature) output mirror, a dispersive prism and a flat HR mirror is used to produce the UV wavelengths. In order to produce different wavelengths, the high-reflectivity rear mirror is mounted on a servo controlled galvanometer motor to allow rapid tuning between the on and offline ozone wavelengths. Typical laser results are 6.8-W at 527-nm, 800-mW at 262-nm and 130-mW at the UV transmitted wavelengths. The lidar receiver system consists of a receiver telescope with a 40-cm diameter parabolic mirror. A fiber optic cable transmits the received signal from the telescope to the receiver box, which houses the detectors. A separate one inch diameter telescope with PMT and filter is used to sample the very near field to allow

  18. Measurements of the absorption cross section of (13)CHO(13)CHO at visible wavelengths and application to DOAS retrievals.

    Science.gov (United States)

    Goss, Natasha R; Waxman, Eleanor M; Coburn, Sean C; Koenig, Theodore K; Thalman, Ryan; Dommen, Josef; Hannigan, James W; Tyndall, Geoffrey S; Volkamer, Rainer

    2015-05-14

    The trace gas glyoxal (CHOCHO) forms from the atmospheric oxidation of hydrocarbons and is a precursor to secondary organic aerosol. We have measured the absorption cross section of disubstituted (13)CHO(13)CHO ((13)C glyoxal) at moderately high (1 cm(-1)) optical resolution between 21 280 and 23 260 cm(-1) (430-470 nm). The isotopic shifts in the position of absorption features were found to be largest near 455 nm (Δν = 14 cm(-1); Δλ = 0.29 nm), whereas no significant shifts were observed near 440 nm (Δν < 0.5 cm(-1); Δλ < 0.01 nm). These shifts are used to investigate the selective detection of (12)C glyoxal (natural isotope abundance) and (13)C glyoxal by in situ cavity enhanced differential optical absorption spectroscopy (CE-DOAS) in a series of sensitivity tests using synthetic spectra, and laboratory measurements of mixtures containing (12)C and (13)C glyoxal, nitrogen dioxide, and other interfering absorbers. We find the changes in apparent spectral band shapes remain significant at the moderately high optical resolution typical of CE-DOAS (0.55 nm fwhm). CE-DOAS allows for the selective online detection of both isotopes with detection limits of ∼200 pptv (1 pptv = 10(-12) volume mixing ratio), and sensitivity toward total glyoxal of few pptv. The (13)C absorption cross section is available for download from the Supporting Information.

  19. Intercomparison of Nox,SO2,O3,and Aromatic Hydrocarbons Measured by a Commercial DOAS System and Traditional Point Monitoring Techniques

    Institute of Scientific and Technical Information of China (English)

    谢品华; 刘文清; 付强; 王瑞斌; 刘建国; 魏庆农

    2004-01-01

    A field-based intercomparison study of a commercial Differential Optical Absorption Spectroscopy (DOAS) instrument (OPSIS AB, Sweden) and different point-sample monitoring techniques (PM, based on an air monitoring station, an air monitoring vehicle, and various chemical methods) was conducted in Beijing from October 1999 to January 2000. The mixing ratios of six trace gases including NO, NO2, SO2,O3, benzene, and toluene were monitored continuously during the four months. A good agreement between the DOAS and PM data was found for NO2 and SO2. However, the concentrations of benzene, toluene,and NO obtained by DOAS were significantly lower than those measured by the point monitors. The ozone levels monitored by the DOAS were generally higher than those measured by point monitors. These results may be attributed to a strong vertical gradient of the NO-O3-NO2 system and of the aromatics at the measurement site. Since the exact data evaluation algorithm is not revealed by the manufacturer of the DOAS system, the error in the DOAS analysis can also not be excluded.

  20. A comparison of ground-based hydroxyl airglow temperatures with SABER/TIMED measurements over 23° N, India

    Science.gov (United States)

    Parihar, Navin; Singh, Dupinder; Gurubaran, Subramanian

    2017-03-01

    Ground-based observations of OH (6, 2) Meinel band nightglow were carried out at Ranchi (23.3° N, 85.3° E), India, during January-March 2011, December 2011-May 2012 and December 2012-March 2013 using an all-sky imaging system. Near the mesopause, OH temperatures were derived from the OH (6, 2) Meinel band intensity information. A limited comparison of OH temperatures (TOH) with SABER/TIMED measurements in 30 cases was performed by defining almost coincident criterion of ±1.5° latitude-longitude and ±3 min of the ground-based observations. Using SABER OH 1.6 and 2.0 µm volume emission rate profiles as the weighing function, two sets of OH-equivalent temperature (T1. 6 and T2. 0 respectively) were estimated from its kinetic temperature profile for comparison with OH nightglow measurements. Overall, fair agreement existed between ground-based and SABER measurements in the majority of events within the limits of experimental errors. Overall, the mean value of OH-derived temperatures and SABER OH-equivalent temperatures were 197.3 ± 4.6, 192.0 ± 10.8 and 192.7 ± 10.3 K, and the ground-based temperatures were 4-5 K warmer than SABER values. A difference of 8 K or more is noted between two measurements when the peak of the OH emission layer lies in the vicinity of large temperature inversions. A comparison of OH temperatures derived using different sets of Einstein transition probabilities and SABER measurements was also performed; however, OH temperatures derived using Langhoff et al. (1986) transition probabilities were found to compare well.

  1. Trend analysis of greenhouse gases over Europe measured by a network of ground-based remote FTIR instruments

    Directory of Open Access Journals (Sweden)

    T. Gardiner

    2008-11-01

    Full Text Available This paper describes the statistical analysis of annual trends in long term datasets of greenhouse gas measurements taken over ten or more years. The analysis technique employs a bootstrap resampling method to determine both the long-term and intra-annual variability of the datasets, together with the uncertainties on the trend values. The method has been applied to data from a European network of ground-based solar FTIR instruments to determine the trends in the tropospheric, stratospheric and total columns of ozone, nitrous oxide, carbon monoxide, methane, ethane and HCFC-22. The suitability of the method has been demonstrated through statistical validation of the technique, and comparison with ground-based in-situ measurements and 3-D atmospheric models.

  2. Global Fine Particulate Matter Concentrations and Trends Inferred from Satellite Observations, Modeling, and Ground-Based Measurements

    Science.gov (United States)

    Martin, Randall; van Donkelaar, Aaron; Boys, Brian; Philip, Sajeev; Lee, Colin; Snider, Graydon; Weagle, Crystal

    2014-05-01

    Outdoor fine particulate matter (PM2.5) is a leading environmentally-related cause of premature mortality worldwide. However, ground-level PM2.5 monitors remain sparse in many regions of the world. Satellite remote sensing from MODIS, MISR, and SeaWiFS yields a powerful global data source to address this issue. Global modeling (GEOS-Chem) plays a critical role in relating these observations to ground-level concentrations. The resultant satellite-based estimates of PM2.5 indicate dramatic variation around the world, with implications for global public health. A new ground-based aerosol network (SPARTAN) offers valuable measurements to understand the relationship between satellite observations of aerosol optical depth and ground-level PM2.5 concentrations. This talk will highlight recent advances in combining satellite remote sensing, global modeling, and ground-based measurements to improve understanding of global population exposure to outdoor fine particulate matter.

  3. Towards a Handshake of Ground-Based Measurements and Remote-Sensing of Vegetation Traits at Global Scale?

    Science.gov (United States)

    Kattge, J.; Díaz, S.; Lavorel, S.; Prentice, I. C.; Leadley, P.; Reich, P. B.; Banerjee, A.; Fazayeli, F.; Schrodt, F. I.; Joswig, J.; Mahecha, M. D.; Wirth, C.

    2014-12-01

    Plant traits determine how primary producers respond to environmental factors, affect other trophic levels, influence ecosystem processes and services, and provide a link from species richness to ecosystem functional diversity. Plant traits thus are a key to understand and predict the adaptation of ecosystems to environmental changes. At the same time ground based measurements of plant trait data are dispersed over a wide range of databases, many of these not publicly available. To overcome this deficiency IGBP and DIVERSITAS have initiated the development of a joint database, called TRY, aiming at constructing a standard resource of ground based plant trait observations for the ecological community and for the development of global vegetation models. So far the TRY initiative has united a wide range of the plant trait research community worldwide and gained an unprecedented buy-in of trait data: about 250 trait databases have been contributed and the data repository currently contains about 5.6 million trait entries for 90,000 out of the world's 350,000 plant species. The database includes data for 1100 traits, characterizing the vegetative and regeneration stages of the plant life cycle, including growth, dispersal, establishment and persistence. Based on advanced methods for gap-filling and spatial extrapolation currently being developed in applied statistics and machine learning and in combination with environmental information and species distribution ranges, the unprecedented availability of ground based trait measurements is expected to allow for up-scaling of trait observations from plant to ecosystem level and from point measurements to regional and global scales. These up-scaled data products are expected to provide a link from ground based trait measurements to remote sensing of vegetation function and traits with global coverage.

  4. Characterisation of Central-African emissions based on MAX-DOAS measurements, satellite observations and model simulations over Bujumbura, Burundi.

    Science.gov (United States)

    Gielen, Clio; Hendrick, Francois; Pinardi, Gaia; De Smedt, Isabelle; Stavrakou, Trissevgeni; Yu, Huan; Fayt, Caroline; Hermans, Christian; Bauwens, Maité; Ndenzako, Eugene; Nzohabonayo, Pierre; Akimana, Rachel; Niyonzima, Sébastien; Müller, Jean-Francois; Van Roozendael, Michel

    2016-04-01

    Central Africa is known for its strong biogenic, pyrogenic, and to a lesser extent anthropogenic emissions. Satellite observations of species like nitrogen dioxide (NO2) and formaldehyde (HCHO), as well as inverse modelling results have shown that there are large uncertainties associated with the emissions in this region. There is thus a need for additional measurements, especially from the ground, in order to better characterise the biomass-burning and biogenic products emitted in this area. We present MAX-DOAS measurements of NO2, HCHO, and aerosols performed in Central Africa, in the city of Bujumbura, Burundi (3°S, 29°E, 850m). A MAX-DOAS instrument has been operating at this location by BIRA-IASB since late 2013. Aerosol-extinction and trace-gases vertical profiles are retrieved by applying the optimal-estimation-based profiling tool bePRO to the measured O4, NO2 and HCHO slant-column densities. The MAX-DOAS vertical columns and profiles are used for investigating the diurnal and seasonal cycles of NO2, HCHO, and aerosols. Regarding the aerosols, the retrieved AODs are compared to co-located AERONET sun photometer measurements for verification purpose, while in the case of NO2 and HCHO, the MAX-DOAS vertical columns and profiles are used for validating GOME-2 and OMI satellite observations. To characterise the biomass-burning and biogenic emissions in the Bujumbura region, the trace gases and aerosol MAX-DOAS retrievals are used in combination to MODIS fire counts/radiative-power and GOME-2/OMI NO2 and HCHO satellite data, as well as simulations from the NOAA backward trajectory model HYSPLIT. First results show that HCHO seasonal variation around local noon is driven by the alternation of rain and dry periods, the latter being associated with intense biomass-burning agricultural activities and forest fires in the south/south-east and transport from this region to Bujumbura. In contrast, NO2 is seen to depend mainly on local emissions close to the city, due

  5. PROMSAR: A backward Monte Carlo spherical RTM for the analysis of DOAS remote sensing measurements

    Science.gov (United States)

    Palazzi, E.; Petritoli, A.; Giovanelli, G.; Kostadinov, I.; Bortoli, D.; Ravegnani, F.; Sackey, S. S.

    A correct interpretation of diffuse solar radiation measurements made by Differential Optical Absorption Spectroscopy (DOAS) remote sensors require the use of radiative transfer models of the atmosphere. The simplest models consider radiation scattering in the atmosphere as a single scattering process. More realistic atmospheric models are those which consider multiple scattering and their application is useful and essential for the analysis of zenith and off-axis measurements regarding the lowest layers of the atmosphere, such as the boundary layer. These are characterized by the highest values of air density and quantities of particles and aerosols acting as scattering nuclei. A new atmospheric model, PROcessing of Multi-Scattered Atmospheric Radiation (PROMSAR), which includes multiple Rayleigh and Mie scattering, has recently been developed at ISAC-CNR. It is based on a backward Monte Carlo technique which is very suitable for studying the various interactions taking place in a complex and non-homogeneous system like the terrestrial atmosphere. PROMSAR code calculates the mean path of the radiation within each layer in which the atmosphere is sub-divided taking into account the large variety of processes that solar radiation undergoes during propagation through the atmosphere. This quantity is then employed to work out the Air Mass Factor (AMF) of several trace gases, to simulate in zenith and off-axis configurations their slant column amounts and to calculate the weighting functions from which informations about the gas vertical distribution is obtained using inversion methods. Results from the model, simulations and comparisons with actual slant column measurements are presented and discussed.

  6. PROMSAR: a multiple scattering atmospheric model for the analysis of DOAS remote sensing measurements

    Science.gov (United States)

    Palazzi, E.; Premuda, M.; Petritoli, A.; Giovanelli, G.; Kostadinov, I.; Ravegnani, F.; Bortoli, D.

    A correct interpretation of diffuse solar radiation measurements made by DOAS (Differential Optical Absorption Spectroscopy) remote sensors, requires the use of radiative transfer models of the atmosphere. The simplest models, the geometrical ones, consider radiation scattering in the atmosphere as a single scattering process. This means that the photons collected by the receiver have changed their direction from the sun only once. More realistic atmospheric models are those which consider multiple scattering: their application is useful and essential for the analysis of zenith and off-axis measurements regarding the lowest layers of the atmosphere, characterized by the highest values of air density and quantities of particles and aerosols acting as scattering nuclei. A new atmospheric model, called PROMSAR (PROcessing of Multi-Scattered Atmospheric Radiation), including multiple Rayleigh and Mie scattering, has recently been developed at the ISAC-CNR institute. It is based on a backward Monte Carlo technique, very suitable for studying the various interactions taking place in a complex and non-homogeneous system like the terrestrial atmosphere. PROMSAR code calculates the mean path of the radiation within each layer into which the atmosphere is sub-divided, taking into account the large variety of processes which solar radiation undergoes during propagation through the atmosphere. This quantity is then employed to work out the Air Mass Factor (AMF) of several trace gases, to simulate, both in zenith and off-axis configurations, their slant column amounts and to calculate the weighting functions from which information about the gas vertical distribution is obtained using inversion methods. Results from the model, simulations and comparisons with slant column measurements are presented and discussed.

  7. Impact of particles on the Planck HFI detectors: Ground-based measurements and physical interpretation

    CERN Document Server

    Catalano, A; Atik, Y; Benoit, A; Bréele, E; Bock, J J; Camus, P; Chabot, M; Charra, M; Crill, B P; Coron, N; Coulais, A; Désert, F -X; Fauvet, L; Giraud-Héraud, Y; Guillaudin, O; Holmes, W; Jones, W C; Lamarre, J -M; Macías-Pérez, J; Martinez, M; Miniussi, A; Monfardini, A; Pajot, F; Patanchon, G; Pelissier, A; Piat, M; Puget, J -L; Renault, C; Rosset, C; Santos, D; Sauvé, A; Spencer, L D; Sudiwala, R

    2014-01-01

    The Planck High Frequency Instrument (HFI) surveyed the sky continuously from August 2009 to January 2012. Its noise and sensitivity performance were excellent, but the rate of cosmic ray impacts on the HFI detectors was unexpectedly high. Furthermore, collisions of cosmic rays with the focal plane produced transient signals in the data (glitches) with a wide range of characteristics. A study of cosmic ray impacts on the HFI detector modules has been undertaken to categorize and characterize the glitches, to correct the HFI time-ordered data, and understand the residual effects on Planck maps and data products. This paper presents an evaluation of the physical origins of glitches observed by the HFI detectors. In order to better understand the glitches observed by HFI in flight, several ground-based experiments were conducted with flight-spare HFI bolometer modules. The experiments were conducted between 2010 and 2013 with HFI test bolometers in different configurations using varying particles and impact ener...

  8. Validation of middle atmospheric campaign-based water vapour measured by the ground-based microwave radiometer MIAWARA-C

    Directory of Open Access Journals (Sweden)

    B. Tschanz

    2013-02-01

    Full Text Available Middle atmospheric water vapour can be used as a tracer for dynamical processes. It is mainly measured by satellite instruments and ground-based microwave radiometers. Ground-based instruments capable of measuring middle atmospheric water vapour are sparse but valuable as they complement satellite measurements, are relatively easy to maintain and have a long lifetime. MIAWARA-C is a ground-based microwave radiometer for middle atmospheric water vapour designed for use on measurement campaigns for both atmospheric case studies and instrument intercomparisons. MIAWARA-C's retrieval version 1.1 (v1.1 is set up in a way to provide a consistent data set even if the instrument is operated from different locations on a campaign basis. The sensitive altitude range for v1.1 extends from 4 hPa (37 km to 0.017 hPa (75 km. MIAWARA-C measures two polarisations of the incident radiation in separate receiver channels and can therefore provide two independent measurements of the same air mass. The standard deviation of the difference between the profiles obtained from the two polarisations is in excellent agreement with the estimated random error of v1.1. In this paper, the quality of v1.1 data is assessed during two measurement campaigns: (1 five months of measurements in the Arctic (Sodankylä, 67.37° N/26.63° E and (2 nine months of measurements at mid-latitudes (Zimmerwald, 46.88° N/7.46° E. For both campaigns MIAWARA-C's profiles are compared to measurements from the satellite experiments Aura MLS and MIPAS. In addition, comparisons to ACE-FTS and SOFIE are presented for the Arctic and to the ground-based radiometer MIAWARA for the mid-latitudinal campaign. In general all intercomparisons show high correlation coefficients, above 0.5 at altitudes above 45 km, confirming the ability of MIAWARA-C to monitor temporal variations on the order of days. The biases are generally below 10% and within the estimated systematic uncertainty of MIAWARA-C. No

  9. Tropospheric BrO column densities in the Arctic derived from satellite: retrieval and comparison to ground-based measurements

    Directory of Open Access Journals (Sweden)

    H. Sihler

    2012-11-01

    Full Text Available During polar spring, halogen radicals like bromine monoxide (BrO play an important role in the chemistry of tropospheric ozone destruction. Satellite measurements of the BrO distribution have become a particularly useful tool to investigate this probably natural phenomenon, but the separation of stratospheric and tropospheric partial columns of BrO is challenging. In this study, an algorithm was developed to retrieve tropospheric vertical column densities of BrO from data of high-resolution spectroscopic satellite instruments such as the second Global Ozone Monitoring Experiment (GOME-2. Unlike recently published approaches, the presented algorithm is capable of separating the fraction of BrO in the activated troposphere from the total BrO column solely based on remotely measured properties. The presented algorithm furthermore allows to estimate a realistic measurement error of the tropospheric BrO column. The sensitivity of each satellite pixel to BrO in the boundary layer is quantified using the measured UV radiance and the column density of the oxygen collision complex O4. A comparison of the sensitivities with CALIPSO LIDAR observations demonstrates that clouds shielding near-surface trace-gas columns can be reliably detected even over ice and snow. Retrieved tropospheric BrO columns are then compared to ground-based BrO measurements from two Arctic field campaigns in the Amundsen Gulf and at Barrow in 2008 and 2009, respectively. Our algorithm was found to be capable of retrieving enhanced near-surface BrO during both campaigns in good agreement with ground-based data. Some differences between ground-based and satellite measurements observed at Barrow can be explained by both elevated and shallow surface layers of BrO. The observations strongly suggest that surface release processes are the dominating source of BrO and that boundary layer meteorology influences the vertical distribution.

  10. Tropospheric BrO column densities in the Arctic from satellite: retrieval and comparison to ground-based measurements

    Directory of Open Access Journals (Sweden)

    H. Sihler

    2012-05-01

    Full Text Available During polar spring, halogen radicals like bromine monoxide (BrO play an important role in the chemistry of tropospheric ozone destruction. Satellite measurements of the BrO-distribution have become a particularly useful tool to investigate this probably natural phenomenon, but the separation of stratospheric and tropospheric partial columns of BrO is challenging. In this study, an algorithm was developed to retrieve tropospheric vertical column densities of BrO from data of high-resolution spectroscopic satellite instruments such as the second Global Ozone Monitoring Experiment (GOME-2. Unlike recently published approaches, the presented algorithm is capable of separating the fraction of BrO in the activated troposphere from the total BrO column solely based on remotely measured properties. The sensitivity of each satellite pixel to BrO in the boundary-layer is quantified using the measured UV-radiance and the column density of the oxygen collision complex O4. A comparison of the sensitivities with CALIPSO LIDAR observations demonstrates that clouds shielding near-surface trace-gas columns can be reliably detected even over ice and snow. Retrieved tropospheric BrO columns are then compared to ground-based BrO measurements from two Arctic field campaigns in the Amundsen Gulf and at Barrow in 2008 and 2009, respectively. Our algorithm was found to be capable of retrieving enhanced near-surface BrO during both campaigns in good agreement to ground-based data. Some differences between ground-based and satellite measurements observed at Barrow can be explained by both, elevated and shallow surface layers of BrO. The observations strongly suggest that surface release processes are the dominating source of BrO and that boundary-layer meteorology influences the vertical distribution.

  11. Examination of temporal and spatial variability of NO2 VCDs measured using mobile-MAX-DOAS in Toronto, Canada.

    Science.gov (United States)

    Davis, Zoe; Baray, Sabour; Khanbabkhani, Aida; Fujs, William; Csukat, Csilla; McLaren, Robert

    2017-04-01

    Mobile-MAX-DOAS is an innovative technique used to estimate pollutant emission rates and validate satellite measurements and air quality models. It is essential to identify and examine factors that can significantly impact the accuracy of this developing technique. Mobile-MAX-DOAS measurements were conducted in Toronto, Canada with a mini-MAX-DOAS instrument mounted (pointing backwards) on top of a car during August and September, 2016. Scattered sunlight spectra were collected every 45 seconds in the continuously repeated sequence of elevation angles of 30o, 30o, 30o, 30o, 40o, 30o, 90o. Tropospheric VCDs were determined using the geometric approximation from DSCDs fitted using a near-noon, low NO2 VCD FRS spectrum. The study goal was to examine the validity of the assumption that VCDs remain relatively constant at each measured location on a driving route encircling an urban area of interest with typical time periods of 1.5-3 hours to estimate emissions and whether driving direction significantly impacts results. NO2 VCD temporal variability was therefore determined by repeating driving routes in both directions in quick succession on multiple days. Strong temporal variability in NO2 VCDs of up to a factor of two were observed for some routes for the same vehicle locations under constant prevailing wind conditions within indicates sufficient horizontal inhomogeneity for the instrument to view significantly different NO2 regimes while at the same vehicle geographical location due to the different azimuth direction. NO2line fluxes were determined during weekday afternoon rush-hours by driving repeatedly in both directions under tangential prevailing winds conditions on a road that is 8km downwind of Toronto and 4km downwind of a major highway. During one afternoon the average NO2 VCD was 6(±2)x1016 molec. cm-2with a standard deviation of 3x1015 molec. cm-2. This average value is consistent with NO2 VCDs retrieved using optimal estimation methods from stationary

  12. Comparison of airborne radar altimeter and ground-based Ku-band radar measurements on the ice cap Austfonna, Svalbard

    Directory of Open Access Journals (Sweden)

    O. Brandt

    2008-11-01

    Full Text Available We compare coincident data from the European Space Agency's Airborne SAR/Interferometric Radar Altimeter System (ASIRAS with ground-based Very High Bandwidth (VHB stepped-frequency radar measurements in the Ku-band. The ASIRAS instrument obtained data from ~700 m above the surface, using a 13.5 GHz center frequency and a 1 GHz bandwidth. The ground-based VHB radar measurements were acquired using the same center frequency, but with a variable bandwidth of either 1 or 8 GHz. Four sites were visited with the VHB radar; two sites within the transition region from superimposed ice to firn, and two sites in the long-term firn area (wet-snow zone. The greater bandwidth VHB measurements show that the first peak in the airborne data is a composite of the return from the surface (i.e. air-snow interface and returns of similar or stronger amplitude from reflectors in the upper ~30 cm of the subsurface. The peak position in the airborne data is thus not necessarily a good proxy for the surface since the maximum and width of the first return depend on the degree of interference between surface and subsurface reflectors. The major response from the winter snowpack was found to be caused by units of thin crust/ice layers (0.5–2 mm surrounded by large crystals (>3 mm. In the airborne data, it is possible to track such layers for tens of kilometers. The winter snowpack lacked thicker ice layers. The last year's summer surface, characterized by a low density large crystal layer overlaying a harder denser layer, gives a strong radar response, frequently the strongest. The clear relationship observed between the VHB and ASIRAS waveforms, justifies the use of ground-based radar measurements in the validation of air- or spaceborne radars.

  13. Measurements of total and tropospheric ozone from IASI: comparison with correlative satellite, ground-based and ozonesonde observations

    Directory of Open Access Journals (Sweden)

    A. Boynard

    2009-08-01

    Full Text Available In this paper, we present measurements of total and tropospheric ozone, retrieved from infrared radiance spectra recorded by the Infrared Atmospheric Sounding Interferometer (IASI, which was launched on board the MetOp-A European satellite in October 2006. We compare IASI total ozone columns to Global Ozone Monitoring Experiment-2 (GOME-2 observations and ground-based measurements from the Dobson and Brewer network for one full year of observations (2008. The IASI total ozone columns are shown to be in good agreement with both GOME-2 and ground-based data, with correlation coefficients of about 0.9 and 0.85, respectively. On average, IASI ozone retrievals exhibit a positive bias of about 9 DU (3.3% compared to both GOME-2 and ground-based measurements. In addition to total ozone columns, the good spectral resolution of IASI enables the retrieval of tropospheric ozone concentrations. Comparisons of IASI tropospheric columns to 490 collocated ozone soundings available from several stations around the globe have been performed for the period of June 2007–August 2008. IASI tropospheric ozone columns compare well with sonde observations, with correlation coefficients of 0.95 and 0.77 for the [surface–6 km] and [surface–12 km] partial columns, respectively. IASI retrievals tend to overestimate the tropospheric ozone columns in comparison with ozonesonde measurements. Positive average biases of 0.15 DU (1.2% and 3 DU (11% are found for the [surface–6 km] and for the [surface–12 km] partial columns respectively.

  14. Marine boundary layer NO2 measurements by ship-borne MAX-DOAS during an offshore observation campaign, 2015

    Science.gov (United States)

    Li, Xianxin; Wang, Zhangjun; Chen, Chao; Meng, Xiangqian; Liu, Xingtao; Liu, Qiaojun; Qu, Junle; Du, Libin

    2017-02-01

    The observations of marine boundary layer NO2 vertical column density (VCD) over the yellow sea near Qingdao by ship-borne Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) were conducted with a Chinese oceanographic research vessel, XYH 08, during an offshore observation campaign, from 13 September 2015 to 18 September 2015. During the observation campaign, the ship-borne MAX-DOAS system made anchor point measurements in different sea areas including Qingdao coastal waters, the Yellow Sea, the Jiaozhou Bay and the Yangkou Bay area. Measurements results of anchor point measurements are presented in this paper. The air mass factor (AMF) errors caused by the vibration of the ship are also studied in this paper. Under good sea conditions on 14 September, the AMF errors of NO2 measurements caused by the ship vibration were evaluated to be less than 5%. By combining geometric character of monitoring area and weather condition, it can be concluded from the Jiaozhou Bay and the Yellow Sea measurement results that the meteorological conditions cause significant influence on local boundary layer NO2 content. The comparison of different anchor point measurements showed that the Jiaozhou Bay sea area had much more NO2 content than Yangkou sea area because the Jiaozhou Bay sea area is located in Qingdao urban area with surrounding NO2 contamination.

  15. The "RED Versa NIR" Plane to Retrieve Broken-Cloud Optical Depth from Ground-Based Measurements"

    Science.gov (United States)

    Marshak, A.; Knyazikhin, Y.; Evans, K.; Wiscombe, W.

    2003-01-01

    A new method for retrieving cloud optical depth from ground-based measurements of zenith radiance in the RED and near infrared (MR) spectral regions is introduced. Because zenith radiance does not have a one-to-one relationship with optical depth, it is absolutely impossible to use a monochromatic retrieval. On the other side, algebraic combinations of spectral radiances such as NDCI while largely removing nouniquiness and the radiative effects of cloud inhomogeneity, can result in poor retrievals due to its insensitivity to cloud fraction. Instead, both RED and NIR radiances as points on the 'RED vs. NIR' plane are proposed to be used for retrieval. The proposed retrieval method is applied to Cimel measurements at the Atmospheric Radiation Measurements (ARM) site in Oklahoma. Cimel, a multi-channel sunphotometer, is a part of AERONET - a ground-based network for monitoring aerosol optical properties. The results of retrieval are compared with the ones from Microwave Radiometer (MWR) and Multi-Filter Rotating Shadowband Radiometers (MFRSR) located next to Cimel at the ARM site. In addition, the performance of the retrieval method is assessed using a fractal model of cloud inhomogeneity and broken cloudiness. The preliminary results look very promising both theoretically and from measurements.

  16. Method for validating cloud mask obtained from satellite measurements using ground-based sky camera.

    Science.gov (United States)

    Letu, Husi; Nagao, Takashi M; Nakajima, Takashi Y; Matsumae, Yoshiaki

    2014-11-01

    Error propagation in Earth's atmospheric, oceanic, and land surface parameters of the satellite products caused by misclassification of the cloud mask is a critical issue for improving the accuracy of satellite products. Thus, characterizing the accuracy of the cloud mask is important for investigating the influence of the cloud mask on satellite products. In this study, we proposed a method for validating multiwavelength satellite data derived cloud masks using ground-based sky camera (GSC) data. First, a cloud cover algorithm for GSC data has been developed using sky index and bright index. Then, Moderate Resolution Imaging Spectroradiometer (MODIS) satellite data derived cloud masks by two cloud-screening algorithms (i.e., MOD35 and CLAUDIA) were validated using the GSC cloud mask. The results indicate that MOD35 is likely to classify ambiguous pixels as "cloudy," whereas CLAUDIA is likely to classify them as "clear." Furthermore, the influence of error propagations caused by misclassification of the MOD35 and CLAUDIA cloud masks on MODIS derived reflectance, brightness temperature, and normalized difference vegetation index (NDVI) in clear and cloudy pixels was investigated using sky camera data. It shows that the influence of the error propagation by the MOD35 cloud mask on the MODIS derived monthly mean reflectance, brightness temperature, and NDVI for clear pixels is significantly smaller than for the CLAUDIA cloud mask; the influence of the error propagation by the CLAUDIA cloud mask on MODIS derived monthly mean cloud products for cloudy pixels is significantly smaller than that by the MOD35 cloud mask.

  17. Analysis of global climate variability from homogenously reprocessed ground-based GNSS measurements

    Science.gov (United States)

    Ahmed, Furqan; Hunegnaw, Addisu; Teferle, Felix Norman; Bingley, Richard

    2015-04-01

    The tropospheric delay information obtained through long-term homogenous reprocessing of Global Navigation Satellite System (GNSS) observations can be used for climate change and variability analysis on a global scale. A reprocessed global dataset of GNSS-derived zenith total delay (ZTD) and position estimates, based on the network double differencing (DD) strategy and covering 1994-2012, has been recently produced at the University of Luxembourg using the Bernese GNSS Software 5.2 (BSW5.2) and the reprocessed products from the Centre for Orbit Determination in Europe (CODE). The network of ground-based GNSS stations processed to obtain this dataset consists of over 400 globally distributed stations. The GNSS-derived ZTD has been validated by comparing it to that derived from reanalysis data from the European Centre for Medium-Range Weather Forecasts (ECMWF). After validation and quality control, the ZTD dataset obtained using the DD strategy has been used to investigate the inter-annual, seasonal and diurnal climate variability and trends in the tropospheric delay on various regional to global spatial scales. Precise point positioning (PPP) is a processing strategy for GNSS observations which is based on observations from a single station rather than a network of baselines and is therefore computationally more efficient than the DD strategy. However, the two processing strategies, i.e. DD and PPP, have their own strengths and weaknesses and could affect the solutions differently at different geographical locations. In order to explore the use of PPP strategy for climate monitoring, another experimental dataset covering a shorter period has been produced using the PPP strategy and compared to the DD based ZTD dataset.

  18. Improving the atmospheric wind speed measured accuracy by the ground-based airglow imaging interferometer

    Science.gov (United States)

    Tang, Yuanhe; Yang, Rui; Gao, Haiyang; Zhai, Fengtao; Yu, Yang; Cui, Jin

    2017-02-01

    A prototype ground based airglow imaging interferometer (GBAII) has been constructed to observe the upper atmospheric wind velocity and temperature at an altitude of 90-100 km, but the GBAII's wind speed accuracy was found to be unsatisfactory with a value of 21.0 m/s. Three theoretical aspects have been investigated to improve the accuracy, with the following finding: 1) By replacing the surface coatings of the GBAII's 6 lenses and Michelson interferometer (MI) with a new wind-speed infrared film rather than the original visible light film, the accuracy can be increased by 3.0 m/s. 2) By replacing the original charge-coupled device (CCD) with a quantum efficiency (QE) of 0.38 at the wavelength of approximately 866 nm by an electron multiplying CCD (EMCCD) with QE of 0.95, the accuracy can be increased by 6.7 m/s. By adding all the factors that improve the accuracy of the GBAII, it can be improved by 15.0 m/s, which realizes the original aim of wind speed accuracy of 6.0 m/s. Experimental results have been obtained for two aspects: 1) By replacing the surface film on the GBAII's 6 lenses and MI interface, the wind speed accuracy has been increased by 3.8 m/s. 2) A new GBAII temperature controller has been constructed to control the environmental temperature in 0.2 K steps. The results obtained by the GBAII on Dec. 6, 2013 show an average atmospheric temperature of 206.5 K, zonal wind speed of -26.8 m/s and meridional wind speed of 28.1 m/s. These results are close to those of the TIMED (Thermosphere Ionosphere Mesosphere Energetics and Dynamics) satellite Doppler interferometer (TIDI) data collected at almost the same time.

  19. Initial Results from the DEEPWAVE Airborne and Ground-Based Measurement Program in New Zealand in 2014

    Science.gov (United States)

    Fritts, Dave; Smith, Ron; Taylor, Mike; Doyle, Jim; Eckermann, Steve; Dörnbrack, Andreas; Rapp, Markus; Williams, Biff; Bossert, Katrina; Pautet, Dominique

    2015-04-01

    The deep-propagating gravity wave experiment (DEEPWAVE) was performed on and over New Zealand, Tasmania, the Tasman Sea, and the Southern Ocean with core airborne measurements extending from 5 June to 21 July 2014 and supporting ground-based measurements beginning in late May and extending beyond the airborne component. DEEPWAVE employed two aircraft, the NSF/NCAR GV and the German DLR Falcon. The GV carried the standard flight-level instruments, dropsondes, and the Microwave Temperature Profiler (MTP). It also hosted new airborne lidar and imaging instruments built specifically to allow quantification of gravity waves (GWs) from sources at lower altitudes (e.g., orography, convection, jet streams, fronts, and secondary GW generation) throughout the stratosphere and into the mesosphere and lower thermosphere (MLT). The new GV lidars included a Rayleigh lidar measuring atmospheric density and temperature from ~20-60 km and a sodium resonance lidar measuring sodium density and temperature at ~75-100 km. An airborne Advanced Mesosphere Temperature Mapper (AMTM) was also developed for the GV, and together with additional IR "wing" cameras, imaged the OH airglow temperature and/or intensity fields extending ~900 km across the GV flight track. The DLR Falcon was equipped with its standard flight-level instruments and an aerosol Doppler lidar able to measure radial winds below the Falcon where aerosol backscatter was sufficient. Additional ground-based instruments included a 449 MHz boundary layer radar, balloons at multiple sites, two ground-based Rayleigh lidars, a second ground-based AMTM, a Fabry Perot interferometer measuring winds and temperatures at ~87 and 95 km, and a meteor radar measuring winds from ~80-100 km. DEEPWAVE performed 26 GV flights, 13 Falcon flights, and an extensive series of ground-based measurements whether or not the aircraft were flying. Together, these observed many diverse cases of GW forcing, propagation, refraction, and dissipation

  20. Comparison of the TRMM Precipitation Radar rainfall estimation with ground-based disdrometer and radar measurements in South Greece

    Science.gov (United States)

    Ioannidou, Melina P.; Kalogiros, John A.; Stavrakis, Adrian K.

    2016-11-01

    The performance of the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR) rainfall estimation algorithm is assessed, locally, in Crete island, south Greece, using data from a 2D-video disdrometer and a ground-based, X-band, polarimetric radar. A three-parameter, normalized Gamma drop size distribution is fitted to the disdrometer rain spectra; the latter are classified in stratiform and convective rain types characterized by different relations between distribution parameters. The method of moments estimates more accurately the distribution parameters than the best fit technique, which exhibits better agreement with and is more biased by the observed droplet distribution at large diameter values. Power laws between the radar reflectivity factor (Z) and the rainfall rate (R) are derived from the disdrometer data. A significant diversity of the prefactor and the exponent of the estimated power laws is observed, depending on the scattering model and the regression technique. The Z-R relationships derived from the disdrometer data are compared to those obtained from TRMM-PR data. Generally, the power laws estimated from the two datasets are different. Specifically, the greater prefactor found for the disdrometer data suggests an overestimation of rainfall rate by the TRMM-PR algorithm for light and moderate stratiform rain, which was the main rain type in the disdrometer dataset. Finally, contemporary data from the TRMM-PR and a ground-based, X-band, polarimetric radar are analyzed. Comparison of the corresponding surface rain rates for a rain event with convective characteristics indicates a large variability of R in a single TRMM-PR footprint, which typically comprises several hundreds of radar pixels. Thus, the coarse spatial resolution of TRMM-PR may lead to miss of significant high local peaks of convective rain. Also, it was found that the high temporal variability of convective rain may introduce significant errors in the estimation of bias of

  1. Aerosol optical properties over the Svalbard region of Arctic: ground-based measurements and satellite remote sensing

    Science.gov (United States)

    Gogoi, Mukunda M.; Babu, S. Suresh

    2016-05-01

    In view of the increasing anthropogenic presence and influence of aerosols in the northern polar regions, long-term continuous measurements of aerosol optical parameters have been investigated over the Svalbard region of Norwegian Arctic (Ny-Ålesund, 79°N, 12°E, 8 m ASL). This study has shown a consistent enhancement in the aerosol scattering and absorption coefficients during spring. The relative dominance of absorbing aerosols is more near the surface (lower single scattering albedo), compared to that at the higher altitude. This is indicative of the presence of local anthropogenic activities. In addition, long-range transported biomass burning aerosols (inferred from the spectral variation of absorption coefficient) also contribute significantly to the higher aerosol absorption in the Arctic spring. Aerosol optical depth (AOD) estimates from ground based Microtop sun-photometer measurements reveals that the columnar abundance of aerosols reaches the peak during spring season. Comparison of AODs between ground based and satellite remote sensing indicates that deep blue algorithm of Moderate Resolution Imaging Spectroradiometer (MODIS) retrievals over Arctic snow surfaces overestimate the columnar AOD.

  2. A novel dual-LED based long-path DOAS instrument for the measurement of aromatic hydrocarbons

    Science.gov (United States)

    Stutz, Jochen; Hurlock, Stephen C.; Colosimo, Santo F.; Tsai, Catalina; Cheung, Ross; Festa, James; Pikelnaya, Olga; Alvarez, Sergio; Flynn, James H.; Erickson, Matthew H.; Olaguer, Eduardo P.

    2016-12-01

    Aromatic hydrocarbons are well known air toxics which are regulated by the US EPA and other air quality agencies. Accurate, long-term monitoring of these compounds at low part-per-billion levels, as well as identifying emission point sources is therefore crucial to protect human health in neighborhoods near large emission sources. Here we present a new long-path differential optical absorption spectroscopy (LP-DOAS) instrument specifically designed to monitor aromatic hydrocarbons. The system is based on a novel dual - light emitting diode (LED) light source, which eliminates the requirement to suppress spectrometer stray light. This light source, together with a high stability fiber-based sending/receiving telescope, allows the measurement of aromatic hydrocarbons on once-folded absorptions paths of 200-1200 m length. The new instrument shows very good agreement with simultaneous in-situ measurements if inhomogeneities of the trace gas spatial distributions are considered. The new instrument performed well during a three-month field test as an automated fence-line monitor at a refinery, successfully distinguishing upwind background levels of ∼1 ppb from emissions reflected in elevated mixing ratios of 3-4 ppb. A two-dimensional measurement network based on two identical LP-DOAS instruments operating on seven crossed light paths was operated successfully in Houston, TX. Qualitative and quantitative analysis of two events with toluene and xylene plumes demonstrate how this setup can be used to derive the spatial distribution of aromatic hydrocarbons, and identify point sources.

  3. First comparison between ground-based and satellite-borne measurements of tropospheric nitrogen dioxide in the Po basin

    Science.gov (United States)

    Petritoli, Andrea; Bonasoni, Paolo; Giovanelli, Giorgio; Ravegnani, Fabrizio; Kostadinov, Ivan; Bortoli, Daniele; Weiss, Andrea; Schaub, Daniel; Richter, Andreas; Fortezza, Francesco

    2004-08-01

    In this paper we present in situ and tropospheric column measurements of NO2 in the Po river basin (northern Italy). The aim of the work is to provide a quantitative comparison between ground-based and satellite measurements in order to assess the validity of spaceborne measurements for estimating NO2 emissions and evaluate possible climatic effects. The study is carried out using in situ chemiluminescent instrumentation installed in the Po valley, a UV/Vis spectrometer installed at Mount Cimone (44.2°N, 10.7°E, 2165 m asl), and tropospheric column measurements obtained from the Global Ozone Monitoring Experiment (GOME) spectrometer. Results show that the annual cycle in surface concentrations and also some specific pollution periods observed by the air quality network are well reproduced by the GOME measurements. However, tropospheric columns derived from the surface measurements assuming a well-mixed planetary boundary layer (PBL) are much larger than the GOME columns and also have a different seasonal cycle. This is interpreted as indication of a smaller and less variable mixing height for NO2 in the boundary layer. Under particular meteorological conditions the agreement between UV/Vis tropospheric column observations and GOME measurements in the Mount Cimone area is good (R2 = 0.9) with the mixing properties of the atmosphere being the most important parameter for a valid comparison of the measurements. However, even when the atmospheric mixing properties are optimal for comparison, the ratio between GOME and ground-based tropospheric column data may not be unity. It is demonstrated that the values obtained (less than 1) are related to the fraction of the satellite ground pixel occupied by the NO2 hot spot.

  4. Estimation of sulphur dioxide emission rate from a power plant based on the remote sensing measurement with an imaging-DOAS instrument

    Science.gov (United States)

    Chong, Jihyo; Kim, Young J.; Baek, Jongho; Lee, Hanlim

    2016-10-01

    Major anthropogenic sources of sulphur dioxide in the troposphere include point sources such as power plants and combustion-derived industrial sources. Spatially resolved remote sensing of atmospheric trace gases is desirable for better estimation and validation of emission from those sources. It has been reported that Imaging Differential Optical Absorption Spectroscopy (I-DOAS) technique can provide the spatially resolved two-dimensional distribution measurement of atmospheric trace gases. This study presents the results of I-DOAS observations of SO2 from a large power plant. The stack plume from the Taean coal-fired power plant was remotely sensed with an I-DOAS instrument. The slant column density (SCD) of SO2 was derived by data analysis of the absorption spectra of the scattered sunlight measured by an I-DOAS over the power plant stacks. Two-dimensional distribution of SO2 SCD was obtained over the viewing window of the I-DOAS instrument. The measured SCDs were converted to mixing ratios in order to estimate the rate of SO2 emission from each stack. The maximum mixing ratio of SO2 was measured to be 28.1 ppm with a SCD value of 4.15×1017 molecules/cm2. Based on the exit velocity of the plume from the stack, the emission rate of SO2 was estimated to be 22.54 g/s. Remote sensing of SO2 with an I-DOAS instrument can be very useful for independent estimation and validation of the emission rates from major point sources as well as area sources.

  5. Airborne & Ground-based measurements of atmospheric CO2 using the 1.57-μm laser absorption spectrometer

    Science.gov (United States)

    Sakaizawa, D.; Kawakami, S.; Nakajima, M.; Tanaka, T.; Miyamoto, Y.; Morino, I.; Uchino, O.; Asai, K.

    2009-12-01

    Greenhouse gases observing satellite (GOSAT) started the measurement of global CO2 abundances to reveal its continental inventory using two passive remote sensors. The goal that the sensor needs to be done is to achieve an 1% relative accuracy in order to reduce uncertainties of CO2 budget. Nevertheless, in the future global CO2 monitoring, more accurate measurement of global tropospheric CO2 abundances with the monthly regional scale are required to improve the knowledge of CO2 exchanges among the land, ocean, and atmosphere. In order to fulfill demands, a laser remote sensor, such as DIAL or laser absorption spectrometer (LAS), is a potential candidate of future space-based missions. Nowadays, those technologies are required to demonstrate an accuracy of the few-ppm level through airborne & ground-based measurements. We developed the prototype of the 1.57um LAS for a step of the next missions and perform it at the ground-based and airborne platform to show the properly validated performance in the framework of GOSAT validation. Our CO2 LAS is consisted of all optical fiber circuits & compact receiving /transmitting optics to achieve the portable, flexible and rigid system. The optical sources of on- and off-line are distributed feedback lasers, which are tuned at the strong and weak position of the R12 line in the (30012rate and combined and amplified using an erbium doped fiber amplifier. Scattered signals from the hard target are collected by the 11cm receiving telescope and detected and stored into the laptop computer. After that, we evaluated the atmospheric CO2 density using the meteorological parameters and ratio between the on- and off-line signals. The resultant of the ground-based measurement of 3km optical length indicated that the statistical error of the path averaged atmospheric CO2 density is less than 2.8ppm with 25 minutes averaging. The variation of the path averaged atmospheric CO2 is also quite consistent with that obtained from the in

  6. The interdependence of continental warm cloud properties derived from unexploited solar background signal in ground-based lidar measurements

    Directory of Open Access Journals (Sweden)

    J. C. Chiu

    2014-04-01

    Full Text Available We have extensively analysed the interdependence between cloud optical depth, droplet effective radius, liquid water path (LWP and geometric thickness for stratiform warm clouds using ground-based observations. In particular, this analysis uses cloud optical depths retrieved from untapped solar background signal that is previously unwanted and needs to be removed in most lidar applications. Combining these new optical depth retrievals with radar and microwave observations at the Atmospheric Radiation Measurement (ARM Climate Research Facility in Oklahoma during 2005–2007, we have found that LWP and geometric thickness increase and follow a power-law relationship with cloud optical depth regardless of the presence of drizzle; LWP and geometric thickness in drizzling clouds can be generally 20–40% and at least 10% higher than those in non-drizzling clouds, respectively. In contrast, droplet effective radius shows a negative correlation with optical depth in drizzling clouds, while it increases with optical depth and reaches an asymptote of 10 μm in non-drizzling clouds. This asymptotic behaviour in non-drizzling clouds is found in both droplet effective radius and optical depth, making it possible to use simple thresholds of optical depth, droplet size, or a combination of these two variables for drizzle delineation. This paper demonstrates a new way to enhance ground-based cloud observations and drizzle delineations using existing lidar networks.

  7. Summer-time Mass Balance of Wolverine Glacier, Alaska, Derived from Ground-based Time-lapse Microgravity Measurements

    Science.gov (United States)

    Young, E. V.; Muto, A.; Babcock, E.

    2016-12-01

    Monitoring the mass balance of alpine glaciers is important because alpine glaciers presently account for about half of the cryospheric contribution to the global sea-level rise. Mass balance measurements of alpine glaciers have predominantly relied upon glaciological and hydrological methods. However, these methods can be logistically costly and have potential extrapolation errors. Remote sensing approaches, such as gravimetric methods using data from GRACE satellite missions, have provided monthly mass-balance estimates of aggregates of alpine glaciers but their spatial resolution is far too large for studying a single glacier. On the other hand, ground-based time-lapse microgravity geophysical measurements can potentially circumvent some of the disadvantages of the glaciological and hydrological methods. It may detect the change in a single glacier's mass and its spatial distribution. We conducted ground-based time-lapse microgravity surveys on Wolverine Glacier, Alaska, in May and August of 2016, using a Scintrex CG-5 Autograv gravimeter. We collected data at seventy-nine individual stations on the glacier, roughly five stations per square kilometer. We included repeat-station and base-station measurements made at least twice a day for instrumental drift control. The uncertainty of our gravity measurements is better than 0.03 mGal, which is about 0.7 meters water equivalent of surface mass balance. Our summer-time mass balance of Wolverine Glacier determined from the time-lapse gravity measurements is independent of that derived from the stake-network or stream-gauge measurements, and could provide spatial insight into the mass balance process on Wolverine Glacier and similar glaciers.

  8. Cosmic ray measurements in the knee region: new perspectives for simultaneous air-borne and ground-based observations

    Energy Technology Data Exchange (ETDEWEB)

    Marrocchesi, P.S. [Physics Dept., Univ. of Siena and INFN, 56 via Roma, 53100 Siena (Italy)]. E-mail: marrocchesi@pi.infn.it

    2006-01-15

    Direct measurements of cosmic ray composition and energy spectra in the knee region (10{sup 15} to 10{sup 16} eV) represent a real challenge for balloon and space borne experiments due to their limited exposure. On the other hand, ground-based extensive air shower arrays (EAS) can provide a measurement of the primary particle energy but fail to identify unambiguously its nature. The possibility to couple a large area instrument in flight, dedicated to the charge identification of the primary nucleus, with a ground array is explored. This task is within the reach of today detector technologies but requires a formidable step in the current development of stratospheric airship platforms capable of maintaining a long-duration stationary position above the EAS array.

  9. Validation of TRMM Precipitation Radar Through Comparison of its Multi-Year Measurements to Ground-Based Radar

    Science.gov (United States)

    Liao, Liang; Meneghini, Robert

    2010-01-01

    A procedure to accurately resample spaceborne and ground-based radar data is described, and then applied to the measurements taken from the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR) and the ground-based Weather Surveillance Radar-1988 Doppler (WSR-88D or WSR) for the validation of the PR measurements and estimates. Through comparisons with the well-calibrated, non-attenuated WSR at Melbourne, Florida for the period 1998-2007, the calibration of the Precipitation Radar (PR) aboard the TRMM satellite is checked using measurements near the storm top. Analysis of the results indicates that the PR, after taking into account differences in radar reflectivity factors between the PR and WSR, has a small positive bias of 0.8 dB relative to the WSR, implying a soundness of the PR calibration in view of the uncertainties involved in the comparisons. Comparisons between the PR and WSR reflectivities are also made near the surface for evaluation of the attenuation-correction procedures used in the PR algorithms. It is found that the PR attenuation is accurately corrected in stratiform rain but is underestimated in convective rain, particularly in heavy rain. Tests of the PR estimates of rainfall rate are conducted through comparisons in the overlap area between the TRMM overpass and WSR scan. Analyses of the data are made both on a conditional basis, in which the instantaneous rain rates are compared only at those pixels where both the PR and WSR detect rain, and an unconditional basis, in which the area-averaged rain rates are estimated independently for the PR and WSR. Results of the conditional rain comparisons show that the PR-derived rain is about 9% greater and 19% less than the WSR estimates for stratiform and convective storms, respectively. Overall, the PR tends to underestimate the conditional mean rain rate by 8% for all rain categories, a finding that conforms to the results of the area-averaged rain (unconditional) comparisons.

  10. Precipitable water vapor and its relationship with the Standardized Precipitation Index: ground-based GPS measurements and reanalysis data

    Science.gov (United States)

    Bordi, Isabella; Zhu, Xiuhua; Fraedrich, Klaus

    2016-01-01

    Monthly means of ground-based GPS measurements of precipitable water vapor (PWV) from six stations in the USA covering the period January 2007-December 2012 are analyzed to investigate their usefulness for monitoring meteorological wet/dry spells. For this purpose, the relationship between PWV and the Standardized Precipitation Index (SPI) on 1-month timescale is investigated. The SPI time series at grid points close to the stations are computed using gridded precipitation records from the NOAA Climate Prediction Center (CPC) unified precipitation dataset (January 1948-April 2012). GPS measurements are first verified against PWV data taken from the latest ECMWF reanalysis ERA-Interim; these PWV reanalysis data, which extend back to 1979, are then used jointly with CPC precipitation to compute precipitation efficiency (PE), defined as the percentage of total water vapor content that falls onto the surface as measurable precipitation in a given time period. The overall results suggest that (i) PWV time series are dominated by the seasonal cycle with maximum values during summer months, (ii) the comparison between GPS and ERA-Interim PWV monthly data shows good agreement with differences less than 4 mm, (iii) at all stations and for almost all months, PWV is only poorly correlated with recorded precipitation and the SPI, while PE correlates highly with the SPI, providing an estimate of the water availability at a given location and useful information on wet/dry spell occurrence, and (iv) long data records would allow, for each month of the year, the identification of PE thresholds associated with different SPI classes that, in turn, have potential for forecasting meteorological wet/dry spells. Thus, it is through PE that ground-based GPS measurements appear of relevance for assessing wet/dry spells, although there is not a direct relationship between PWV and SPI.

  11. The comparison of IR and MW ground-based measurements of total precipitable water

    Science.gov (United States)

    Berezin, I. A.; Virolainen, Ya. A.; Timofeyev, Yu. M.; Poberovskii, A. V.

    2016-05-01

    Water vapor is one of the basic climate gases playing a key role in various processes at different altitudes of the Earth's atmosphere. An intercomparison and validation of different total precipitable water (TPW) measurement methods are important for determining the true accuracy of these methods, the shared use of data from multiple sources, the creation of data archives of different measurements, etc. In this paper, the TPW values obtained from measurements of solar IR spectral radiation (~8-9 μm absorption band) and thermal MW radiation of the atmosphere (1.35 cm absorption line) for 138 days of observation are compared. Measurements have been carried out from March 2013 to June 2014 at Peterhof station of the St. Petersburg State University in (59.88° N, 29.82° E). It is shown that MW measurements usually give higher TPW values than IR measurements. The bias between the two methods varies from 1 to 8% for small and large TPW values, respectively. With increasing TPW values, the bias reduces and for TPW > 1 cm it is ~1%. Standard deviation (SD) between the two methods reaches 7% for TPW 1 cm. These data show the high quality of both remote sensing methods. Moreover, the IR measurements have a higher accuracy than MW measurements for small TPW values.

  12. Ground-based integrated path coherent differential absorption lidar measurement of CO2: hard target return

    Directory of Open Access Journals (Sweden)

    A. Sato

    2012-11-01

    Full Text Available The National Institute of Information and Communications Technology (NICT have made a great deal of effort to develop a coherent 2-μm differential absorption and wind lidar (Co2DiaWiL for measuring CO2 and wind speed. First, coherent Integrated Path Differential Absorption (IPDA lidar experiments were conducted using the Co2DiaWiL and a hard target (surface return located about 7.12 km south of NICT on 11, 27, and 28 December 2010. The detection sensitivity of a 2-μm IPDA lidar was examined in detail using the CO2 concentration measured by the hard target. The precisions of CO2 measurement for the hard target and 900, 4500 and 27 000 shot pairs were 6.5, 2.8, and 1.2%, respectively. The results indicated that a coherent IPDA lidar with a laser operating at a high pulse repetition frequency of a few tens of KHz is necessary for measuring the CO2 concentration of the hard target with a precision of 1–2 ppm. Statistical comparisons indicated that, although a small amount of in situ data and the fact that they were not co-located with the hard target made comparison difficult, the CO2 volume mixing ratio measured with the Co2DiaWiL was about 5 ppm lower than that measured with the in situ sensor. The statistical results indicated that there were no differences between the hard target and atmospheric return measurements. A precision of 1.5% was achieved from the atmospheric return, which is lower than that obtained from the hard-target returns. Although long-range DIfferential Absorption Lidar (DIAL CO2 measurement with the atmospheric return can result in highly precise measurement, the precision of the atmospheric return measurement was widely distributed comparing to that of the hard target return. Our results indicated that it is important to use a Q-switched laser to measure the range-gated differential absorption optical depth with the atmospheric return and that it is better to simultaneously conduct both hard target and atmospheric return

  13. Error analysis for the ground-based microwave ozone measurements during STOIC

    Science.gov (United States)

    Connor, Brian J.; Parrish, Alan; Tsou, Jung-Jung; McCormick, M. Patrick

    1995-01-01

    We present a formal error analysis and characterization of the microwave measurements made during the Stratospheric Ozone Intercomparison Campaign (STOIC). The most important error sources are found to be determination of the tropospheric opacity, the pressure-broadening coefficient of the observed line, and systematic variations in instrument response as a function of frequency ('baseline'). Net precision is 4-6% between 55 and 0.2 mbar, while accuracy is 6-10%. Resolution is 8-10 km below 3 mbar and increases to 17km at 0.2 mbar. We show the 'blind' microwave measurements from STOIC and make limited comparisons to other measurements. We use the averaging kernels of the microwave measurement to eliminate resolution and a priori effects from a comparison to SAGE 2. The STOIC results and comparisons are broadly consistent with the formal analysis.

  14. Tropospheric and total ozone columns over Paris (France) measured using medium-resolution ground-based solar-absorption Fourier-transform infrared spectroscopy

    OpenAIRE

    C. Viatte; B. Gaubert; Eremenko, M.; Hase, F.; Schneider, M; Blumenstock, T.; Ray, M; P. Chelin; J.-M. Flaud; Orphal, J

    2011-01-01

    Ground-based Fourier-transform infrared (FTIR) solar absorption spectroscopy is a powerful remote sensing technique providing information on the vertical distribution of various atmospheric constituents. This work presents the first evaluation of a mid-resolution ground-based FTIR to measure tropospheric ozone, independently of stratospheric ozone. This is demonstrated using a new atmospheric observatory (named OASIS for "Observations of the Atmosphere by Solar absorption Infrared Spectroscop...

  15. Tropospheric and total ozone columns over Paris (France) measured using medium-resolution ground-based solar-absorption Fourier-transform infrared spectroscopy [Discussion paper

    OpenAIRE

    C. Viatte; B. Gaubert; Eremenko, M.; Hase, F.; Schneider, M; Blumenstock, T.; Ray, M; P. Chelin; J.-M. Flaud; Orphal, J

    2011-01-01

    Ground-based Fourier-transform infrared (FTIR) solar absorption spectroscopy is a powerful remote sensing technique providing information on the vertical distribution of various atmospheric constituents. This work presents the first evaluation of a mid-resolution ground-based FTIR to measure tropospheric ozone, independently of stratospheric ozone. This is demonstrated using a new atmospheric observatory (named OASIS for "Observations of the Atmosphere by Solar absorption Infrared Spectroscop...

  16. Cloud and aerosol optics by polarized micro pulse Lidar and ground based measurements of zenith radiance

    Science.gov (United States)

    Delgadillo, Rodrigo

    Clouds impact Earth's climate through cloud transmission and reflection properties. Clouds reflect approximately 15 percent of the incoming solar radiation at the top of the atmosphere. A key cloud radiative variable is cloud optical depth, which gives information about how much light is transmitted through a cloud. Historically, remote measurements of cloud optical depth have been limited to uniform overcast conditions and had low temporal and spatial resolution. We present a novel method to measure cloud optical depth for coastal regions from spectral zenith radiance measurements for optically thin clouds, which removes some of these limitations. Our measurement site is part of South Florida's Cloud-Aerosol-Rain Observatory (CAROb), located on Virginia Key, FL (6 km from Miami). This work is based on Marshak et al.'s method for finding cloud optical depth from vegetative sites that provide a strong spectral contrast between red and near infrared surface albedo. However, given the unique nature of our site, which contains water, vegetation, beach, and urban surface types, we found no such spectral contrast at those wavelength pairs. We measured albedo, with hyperspectral resolution, for different surface types around our measurement site to estimate the effective spectral albedo for the area centered on the site with a 5km radius. From this analysis, we found the best possible albedo contrast (573.9 and 673.1 nm) for our site. We tested the derived cloud optical depth from zenith radiance at these two wavelengths against a concurrently running polarized micro pulse LIDAR (MPL) and found good agreement.

  17. Ground-based integrated path coherent differential absorption lidar measurement of CO2: foothill target return

    Directory of Open Access Journals (Sweden)

    S. Ishii

    2013-05-01

    Full Text Available The National Institute of Information and Communications Technology (NICT has made a great deal of effort to develop a coherent 2 μm differential absorption and wind lidar (Co2DiaWiL for measuring CO2 and wind speed. First, coherent Integrated Path Differential Absorption (IPDA lidar experiments were conducted using the Co2DiaWiL and a foothill target (tree and ground surface located about 7.12 km south of NICT on 11, 27, and 28 December 2010. The detection sensitivity of a 2 μm IPDA lidar was examined in detail using the CO2 concentration measured by the foothill reflection. The precisions of CO2 measurements for the foothill target and 900, 4500 and 27 000 shot pairs were 6.5, 2.8, and 1.2%, respectively. The results indicated that a coherent IPDA lidar with a laser operating at a high pulse repetition frequency of a few tens of KHz is necessary for XCO2 (column-averaged dry air mixing ratio of CO2 measurement with a precision of 1–2 ppm in order to observe temporal and spatial variations in the CO2. Statistical comparisons indicated that, although a small amount of in situ data and the fact that they were not co-located with the foothill target made comparison difficult, the CO2 volume mixing ratio obtained by the Co2DiaWiL measurements for the foothill target and atmospheric returns was about −5 ppm lower than the 5 min running averages of the in situ sensor. Not only actual difference of sensing volume or the natural variability of CO2 but also the fluctuations of temperature could cause this difference. The statistical results indicated that there were no biases between the foothill target and atmospheric return measurements. The 2 μm coherent IPDA lidar can detect the CO2 volume mixing ratio change of 3% in the 5 min signal integration. In order to detect the position of the foothill target, to measure a range with a high SNR (signal-to-noise ratio, and to reduce uncertainty due to the presence of aerosols and clouds, it is

  18. Ground based infrared measurements of the global distribution of ozone in the atmosphere of Mars

    Science.gov (United States)

    Kostiuk, Theodor; Espenak, F.; Mumma, M. J.; Zipoy, D.

    1991-01-01

    The global distribution of ozone in the atmosphere of Mars was determined from Doppler-limited infrared heterodyne spectroscopy measurements at the NASA Infrared Telescope Facility (IRTF) facility during June 3-7, 1988. Mars spectra near two O3 lines arising from the v sub 3 band near 1031.45 cm (-1) were used. The lines were Doppler shifted out of the strong terrestrial ozone absorption spectrum and its effect was removed. Ozone measurements were obtained at eight beam positions over a range of latitudes and local solar zenith angles. The beam size of the planet was 1.4 arcsec. A Martian CO2 line appeared in the spectra and was inverted to retrieve local temperature profiles. Using these temperature profiles, the total ozone column abundance at each position was retrieved by fitting the measured line with synthetic spectra generated by a radiative transfer program. The only previous measurement of ozone at this season was made above the South polar cap by Mariner 7 and revealed an abundance of 10 micron-atm. However, the retrieved O3 column abundances from this investigation are less than 2.2 micron-atm at all positions sampled. These results are consistent with mid-spring abundances predicted by photochemical models of Liu and Donahue, and Shimazaki and Shimizu.

  19. Earth's albedo variations 1998-2014 as measured from ground-based earthshine observations

    CERN Document Server

    Palle, E; Montanes-Rodriguez, P Pilar; Shumko, A; Gonzalez-Merino, B; Lombilla, C Martinez; Jimenez-Ibarra, F; Shumko, S; Sanroma, E; Hulist, A; Miles-Paez, P; Murgas, F; Nowak, G; Koonin, SE

    2016-01-01

    The Earth's albedo is a fundamental climate parameter for understanding the radiation budget of the atmosphere. It has been traditionally measured from space platforms, but also from the ground for sixteen years from Big Bear Solar Observatory by observing the Moon. The photometric ratio of the dark (earthshine) to the bright (moonshine) sides of the Moon is used to determine nightly anomalies in the terrestrial albedo, with the aim is of quantifying sustained monthly, annual and/or decadal changes. We find two modest decadal scale cycles in the albedo, but with no significant net change over the sixteen years of accumulated data. Within the evolution of the two cycles, we find periods of sustained annual increases, followed by comparable sustained decreases in albedo. The evolution of the earthshine albedo is in remarkable agreement with that from the CERES instruments, although each method measures different slices of the Earth's Bond albedo.

  20. Earth's albedo variations 1998-2014 as measured from ground-based earthshine observations

    Science.gov (United States)

    Palle, E.; Goode, P. R.; Montañés-Rodríguez, P.; Shumko, A.; Gonzalez-Merino, B.; Lombilla, C. Martinez; Jimenez-Ibarra, F.; Shumko, S.; Sanroma, E.; Hulist, A.; Miles-Paez, P.; Murgas, F.; Nowak, G.; Koonin, S. E.

    2016-05-01

    The Earth's albedo is a fundamental climate parameter for understanding the radiation budget of the atmosphere. It has been traditionally measured not only from space platforms but also from the ground for 16 years from Big Bear Solar Observatory by observing the Moon. The photometric ratio of the dark (earthshine) to the bright (moonshine) sides of the Moon is used to determine nightly anomalies in the terrestrial albedo, with the aim of quantifying sustained monthly, annual, and/or decadal changes. We find two modest decadal scale cycles in the albedo, but with no significant net change over the 16 years of accumulated data. Within the evolution of the two cycles, we find periods of sustained annual increases, followed by comparable sustained decreases in albedo. The evolution of the earthshine albedo is in remarkable agreement with that from the Clouds and the Earth's Radiant Energy System instruments, although each method measures different slices of the Earth's Bond albedo.

  1. Ground-based aerosol measurements during CHARMEX/ADRIMED campaign at Granada station

    Science.gov (United States)

    Granados-Muñoz, Maria Jose; Bravo-Aranda, Juan Antonio; Navas-Guzman, Francisco; Guerro-Rascado, Juan Luis; Titos, Gloria; Lyamani, Hassan; Valenzuela, Antonio; Cazorla, Alberto; Olmo, Francisco Jose; Mallet, Marc; Alados-Arboledas, Lucas

    2015-04-01

    In the framework of ChArMEx/ADRIMED (Chemistry-Aerosol Mediterranean Experiment, http://charmex.lsce.ipsl.fr/; Aerosol Direct Radiative Impact on the regional climate in the MEDiterranean region) projects, a field experiment based on in situ and remote sensing measurements from surface and airborne platforms was performed. The ADRIMED project aimed to capture the high complexity of the Mediterranean region by using an integrated approach based on intensive experimental field campaign and spaceborne observations, radiative transfer calculations and climate modelling with Regional Climate Models better adapted than global circulation models. For this purpose, measurements were performed at different surface super-sites (including Granada station) over the Occidental Mediterranean region during summer 2013 for creating an updated database of the physical, chemical, optical properties and the vertical distribution of the major "Mediterranean aerosols". Namely, measurements at Granada station were performed on 16 and 17 July 2013, in coincidence with the overpasses of the ATR aircraft over the station. The instrumentation used for the campaign includes both remote sensing instruments (a multiwavelength Raman lidar and a sun photometer) and in-situ measurements (a nephelometer, a Multi-Angle Absorption Photometer (MAAP), an Aerodynamic particle sizer (APS), a high volume sampler of PM10 and an aethalometer). During the measurement period a mineral dust event was detected, with similar dust load on both days. According to in-situ measurements, the event reached the surface level on 16 of June. Vertically resolved lidar measurements indicated presence of mineral dust layers up to 5 km asl both on 16 and 17 June 2013. Temporal evolution analysis indicated that on 17 June the dust layer decoupled from the boundary layer and disappeared around 14:00 UTC. In addition, lidar and sun-photometer data were used to retrieve volume concentration profiles by means of LIRIC (Lidar

  2. Ground-based lidar measurements from Ny-Ålesund during ASTAR 2007

    Directory of Open Access Journals (Sweden)

    A. Herber

    2009-11-01

    Full Text Available During the Arctic Study of Tropospheric Aerosol, Clouds and Radiation (ASTAR in March and April 2007, measurements obtained at the AWIPEV Arctic Research Base in Ny-Ålesund, Spitsbergen at 78.9° N, 11.9° E (operated by the Alfred Wegener Institute for Polar and Marine Research – AWI and the Institut polaire français Paul-Emile Victor – IPEV, supported the airborne campaign. This included lidar data from the Koldewey Aerosol Raman Lidar (KARL and the Micro Pulse Lidar (MPL, located in the atmospheric observatory as well as photometer data and the daily launched radiosonde. The MPL features nearly continuous measurements; the KARL was switched on whenever weather conditions allowed observations (145 h in 61 days. From 1 March to 30 April, 71 meteorological balloon soundings were performed and compared with the concurrent MPL measurements; photometer measurements are available from 18 March. For the KARL data, a statistical overview of particle detection based on their optical properties backscatter ratio and volume depolarization can be given. The altitudes of the occurrence of the named features (subvisible and visible ice and water as well as mixed-phase clouds, aerosol layers as well as their dependence on different air mass origins are analyzed. Although the spring 2007 was characterized by rather clean conditions, diverse case studies of cloud and aerosol occurrence during March and April 2007 are presented in more detail, including temporal development and main optical properties as depolarization, backscatter and extinction coefficients. Links between air mass origins and optical properties can be presumed but need further evidence.

  3. Cloud recognition from ground-based solar radiation measurements: preliminary results

    Science.gov (United States)

    Calbo, Josep; Gonzalez, Josep-Abel

    1998-12-01

    Despite cloud recognition techniques that can routinely identify cloud classes form satellite images, observation of clouds from the ground is still needed to acquire a complete description of cloud climatology. Solar radiation in a given site is one of the meteorological magnitudes that are most affected by cloud cover. Presently, the number of stations where both global and diffuse total solar radiation is measured is growing, due basically to energetic applications of solar radiation. Global and diffuse hourly irradiation, along with some measure of the temporal variability of solar radiation, are used in this paper to describe the sky condition, and to classify it into several cloud types. A classical maximum likelihood method is applied for clustering data. One year of solar radiation data and cloud observations at a site in Catalonia, Spain is used to illustrate the ability of solar radiation measurements to describe cloud types. Preliminary results of the above methodology show that three clusters appear using global and diffuse hourly irradiation only. Fog, stratus, and stratocumulus from the first group. A second group includes altocumulus alone or mixed with other clouds, as well as scattered cumulus congestus. In a third group, we find clear skies, cirrus and scattered cumulus. Especially in this third group, variability of solar radiation within an hour helps to separate different situations.

  4. New ground-based lidar enables volcanic CO2 flux measurements.

    Science.gov (United States)

    Aiuppa, Alessandro; Fiorani, Luca; Santoro, Simone; Parracino, Stefano; Nuvoli, Marcello; Chiodini, Giovanni; Minopoli, Carmine; Tamburello, Giancarlo

    2015-09-01

    There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2-the most reliable gas precursor to an eruption-has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest.

  5. Shipborne solar absorption measurements of CO2, CH4, N2O and CO and comparison with SCIAMACHY WFM-DOAS retrievals

    Directory of Open Access Journals (Sweden)

    V. Velazco

    2005-02-01

    Full Text Available CO, CH4, N2O and CO2 were retrieved from high resolution solar absorption spectra obtained during a ship cruise from Capetown to Bremerhaven in January/February 2003 by Fourier Transform Infrared (FTIR spectroscopy. Precisions of better than 0.5% for the column averaged volume mixing ratios (VMR of CH4 and CO2 are achieved using of O2 as a reference gas. Shipborne FTIR-measurements of CO and data from SCIAMACHY/ENVISAT retrieved by the Weighting Function Modified Differential Optical Absorption Spectroscopy (WFM-DOAS retrieval algorithm show qualitatively the same latitudinal variations. WFM-DOAS data of CH4, N2O and CO2 measured over sea exhibit a great spread. The spread is significantly reduced for satellite measurements over land and a reasonable agreement can be obtained if the shipborne data is compared with the closest SCIAMACHY measurements over land. The number of comparisons is too small to draw conclusions. However, by including only WFM-DOAS data with small errors the shipborne and WFM-DOAS data compare within 5% for CH4 and CO2 and within 30% for N2O.

  6. Shipborne solar absorption measurements of CO2, CH4, N2O and CO and comparison with SCIAMACHY WFM-DOAS retrievals

    Directory of Open Access Journals (Sweden)

    T. Warneke

    2005-01-01

    Full Text Available CO, CH4, N2O and CO2 were retrieved from high resolution solar absorption spectra obtained during a ship cruise from Capetown to Bremerhaven in January/February 2003 by Fourier Transform Infrared (FTIR spectroscopy. Precisions of better than 0.5% for the column averaged volume mixing ratios (VMR of CH4 and CO2 are achieved using of O2 as a reference gas. Shipborne FTIR-measurements of CO and data from SCIAMACHY/ENVISAT retrieved by the Weighting Function Modified Differential Optical Absorption Spectroscopy (WFM-DOAS retrieval algorithm show qualitatively the same latitudinal variations. WFM-DOAS data of CH4, N2O and CO2 measured over sea exhibit a great spread. The spread is significantly reduced for satellite measurements over land and a reasonable agreement can be obtained if the shipborne data are compared with the closest SCIAMACHY measurements over land. The number of comparisons is too small to draw conclusions. However, by including only WFM-DOAS data with small errors the shipborne and WFM-DOAS data compare within 5% for CH4 and CO2 and within 30% for N2O.

  7. Shipborne solar absorption measurements of CO2, CH4, N2O and CO and comparison with SCIAMACHY WFM-DOAS retrievals

    Science.gov (United States)

    Warneke, T.; de Beek, R.; Buchwitz, M.; Notholt, J.; Schulz, A.; Velazco, V.; Schrems, O.

    2005-08-01

    CO, CH4, N2O and CO2 were retrieved from high resolution solar absorption spectra obtained during a ship cruise from Capetown to Bremerhaven in January/February 2003 by Fourier Transform Infrared (FTIR) spectroscopy. Precisions of better than 0.5% for the column averaged volume mixing ratios (VMR) of CH4 and CO2 are achieved using of O2 as a reference gas. Shipborne FTIR-measurements of CO and data from SCIAMACHY/ENVISAT retrieved by the Weighting Function Modified Differential Optical Absorption Spectroscopy (WFM-DOAS) retrieval algorithm show qualitatively the same latitudinal variations. WFM-DOAS data of CH4, N2O and CO2 measured over sea exhibit a great spread. The spread is significantly reduced for satellite measurements over land and a reasonable agreement can be obtained if the shipborne data are compared with the closest SCIAMACHY measurements over land. The number of comparisons is too small to draw conclusions. However, by including only WFM-DOAS data with small errors the shipborne and WFM-DOAS data compare within 5% for CH4 and CO2 and within 30% for N2O.

  8. Ground-based infrared measurements of the global distribution of ozone in the atmosphere of Mars

    Science.gov (United States)

    Espenak, Fred; Mumma, Michael J.; Kostiuk, Theodor; Zipoy, David

    1991-01-01

    Doppler-limited IR spectroscopy measurements of the Mars atmosphere's global ozone distribution have been obtained for June 3-7, 1988; surface pressures and temperature profiles are retrieved through inversion of the fully-resolved (C-12)(O-16)2 line. The total O3 column abundance at each position has been retrieved at each of eight positions over a range of Martian latitudes by fitting the lines with synthetic spectra generated by a radiative transfer program: column burdens of O3 are less than 2.2 microns-atm for all latitudes sampled.

  9. High precision ground-based measurements of solar diameter in support of Picard mission

    CERN Document Server

    Sigismondi, Costantino

    2011-01-01

    The measurement of the solar diameter is introduced in the wider framework of solar variability, and, consequently of the influences of the Sun upon the Earth's climate. It is possible to measure the solar diameter with enough accuracy to study climate changes and irradiation variations using ancient eclipses. This would permit to extend the knowledge of the solar luminosity back to three centuries, through the parameter W=dLogL/dLog R. The method of eclipses and Baily beads is discussed, and a significant improvement with respect to the last 40 years, has been obtained by reconstructing the Limb Darkening Function from the Baily's bead light curve, and the search of its inflexion point. The case of the Jan 15, 2010 annular eclipse has been studied in detail, while the atlas of Baily's beads with worldwide contributions by IOTA members, along with the solar diameter during the eclipse of 2006, have been published. The transition between the photographic atlas of the lunar limb (Watts, 1963) and the laser-alti...

  10. Wind measurements in Saturn's atmosphere with UVES/VLT ground-based Doppler velocimetry

    Science.gov (United States)

    Machado, Pedro; Silva, Miguel; Peralta, Javier; Luz, David; Sánchez-Lavega, Agustin; Hueso, Ricardo

    2016-04-01

    We will present preliminary Doppler wind velocity results of Saturn's zonal flow at cloud level. Our aim is help to constrain the characterization of the equatorial jet at cloud level and the latitudinal variation of the zonal winds, to measure its spatial and temporal variability, to contribute to monitor the variability in order to achieve a better understanding of the dynamics of Saturn's zonal winds, whose equatorial jet has a complex vertical structure and temporal variability (Sanchez-Lavega et al., Nature, 423, 623, 3003; Garcia-Melendo et al., Geophys. Res. Lett., 37, L22204. 2010). Finally, the complementarity with Cassini, providing an independent set of observations. The UVES/VLT instrument has been used, which simultaneously achieves high spectral resolving power and high spatial resolution. The field has been derotated in order to have the aperture aligned perpendicularly to Saturn's rotation axis. In this configuration, spatial information in the East-West direction is preserved in a set of spectra in the direction perpendicular to dispersion. The technique of absolute accelerometry (AA, Connes, 1985, ApSS 110, 211) has been applied to the backscattered solar spectrum in order to determine the Doppler shift associated with the zonal circulation. Our measurements have been made in the wavelength range of 480-680 nm. Previously we successfully adapted this Doppler velocimetry technique for measuring winds at Venus cloud tops (Machado et al. 2012). In the present study we will show the adaptation of this method for Saturn's case. Since the AA technique only allows to compare spectra where the line shifts are within the line width, in fast rotating atmospheres (as is the case of Saturn) the spectra must be compared by pairs from adjacent areas of the disk (adjacent pixels in the slit). We will use coordinated observations from the Cassini's Visible and Infrared Mapping Spectrometer (VIMS), in order to compare with the Doppler winds obtained from the UVES

  11. Diurnal variation of atmospheric water vapor at Gale crater: Analysis from ground-based measurements

    Science.gov (United States)

    Martinez, German; McConnochie, Timothy; Renno, Nilton; Meslin, Pierre-Yves; Fischer, Erik; Vicente-Retortillo, Alvaro; Borlina, Caue; Kemppinen, Osku; Genzer, Maria; Harri, Ari-Matti; de la Torre-Juárez, Manuel; Zorzano, Mari-Paz; Martin-Torres, Javier; Bridges, Nathan; Maurice, Sylvestre; Gasnault, Olivier; Gomez-Elvira, Javier; Wiens, Roger

    2016-04-01

    We analyze measurements obtained by Curiosity's Rover Environmental Monitoring Station (REMS) and ChemCam (CCAM) instruments to shed light on the hydrological cycle at Gale crater. In particular, we use nighttime REMS measurements taken when the atmospheric volume mixing ratio (VMR) and its uncertainty are the lowest (between 05:00 and 06:00 LTST) [1], and daytime CCAM passive sky measurements taken when the VMR is expected to be the highest (between 10:00 and 14:00 LTST) [2]. VMR is calculated from simultaneous REMS measurements of pressure (P), temperature (T) and relative humidity (RH) at 1.6 m (VMR is defined as RH×es(T)/P , where es is the saturation water vapor pressure over ice). The REMS relative humidity sensor has recently been recalibrated (June 2015), providing RH values slightly lower than those in the previous calibration (Dec 2014). The full diurnal cycle of VMR cannot be analyzed using only REMS data because the uncertainty in daytime VMR derived from REMS measurements is extremely high. Daytime VMR is inferred by fitting the output of a multiple-scattering discrete-ordinates radiative transfer model to CCAM passive sky observations [3]. CCAM makes these observations predominately in the vicinity of 11:00 - 12:00 LTST, but occasionally in the early morning near 08:00 LTST. We find that throughout the Martian year, the daytime VMR is higher than at night, with a maximum day-to-night ratio of about 6 during winter. Various processes might explain the differences between nighttime REMS and daytime CCAM VMR values. Potential explanations include: (i) surface nighttime frost formation followed by daytime sublimation [1], (ii) surface nighttime adsorption of water vapor by the regolith followed by daytime desorption and (iii) large scale circulations changing vertical H2O profiles at different times of the year. Potential formation of surface frost can only occur in late fall and winter [1], coinciding with the time when the diurnal amplitude of the near

  12. Volcanic ash from Iceland over Munich: mass concentration retrieved from ground-based remote sensing measurements

    Science.gov (United States)

    Gasteiger, J.; Gro{ß}, S.; Freudenthaler, V.; Wiegner, M.

    2011-03-01

    Volcanic ash plumes, emitted by the Eyjafjallajökull volcano (Iceland) in spring 2010, were observed by the lidar systems MULIS and POLIS in Maisach (near Munich, Germany), and by a CIMEL Sun photometer and a JenOptik ceilometer in Munich. We retrieve mass concentrations of volcanic ash from the lidar measurements; spectral optical properties, i.e.~extinction coefficients, backscatter coefficients, and linear depolarization ratios, are used as input for an inversion. The inversion algorithm searches for model aerosol ensembles with optical properties that agree with the measured values within their uncertainty ranges. The non-sphericity of ash particles is considered by assuming spheroids. Optical particle properties are calculated using the T-matrix method supplemented by the geometric optics approach. The lidar inversion is applied to observations of the pure volcanic ash plume in the morning of 17 April 2010. We find 1.45 g m-2 for the ratio between the mass concentration and the extinction coefficient at λ = 532 nm, assuming an ash density of 2.6 g cm-3. The uncertainty range for this ratio is from 0.87 g m-2 to 2.32 g m-2. At the peak of the ash concentration over Maisach the extinction coefficient at λ = 532 nm was 0.75 km-1 (1-h-average), which corresponds to a maximum mass concentration of 1.1 mg m-3 (0.65 to 1.8 mg m-3). Model calculations show that particle backscatter at our lidar wavelengths (λ ≤ 1064 nm), and thus the lidar retrieval, is hardly sensitive to large particles (r ≳ 3 μm); large particles, however, may contain significant amounts of mass. Therefore, as an independent cross check of the lidar retrieval and to investigate the presence of large particles in more detail, we model ratios of sky radiances in the aureole of the Sun and compare them to measurements of the CIMEL. These ratios are sensitive to particles up to r ≈ 10 μm. This approach confirms the mass concentrations from the lidar retrieval. We conclude that synergistic

  13. Airborne DOAS observations of tropospheric NO2 using an UltraLight Trike and flux calculation

    Science.gov (United States)

    Constantin, Daniel-Eduard; Voiculescu, Mirela; Merlaud, Alexis; Dragomir, Carmelia; Georgescu, Lucian; Hendrick, Francois; Van Roozendael, Michel

    2016-04-01

    In this paper we present airborne DOAS observations of tropospheric NO2 using an Ultralight Trike (ULT) and associated flux calculation. The instrument onboard the ULT was developed for measuring the tropospheric NO2 Vertical Column Density (VCD). Measurements were performed for several days during 2011-2014, in a region SE of Romania, over the cities of Galati (45.43°N, 28.03°E) and Braila (45.26°N, 27.95°E). Measurements of the NO2 column in the same area were performed using car-DOAS observations. The correlation between the tropospheric NO2 VCD from airborne and mobile ground-based DOAS observations was used to validate the airborne observations. A specific AMF for each case was calculated using the radiative transfer model (RTM) UVspec/DISORT. We present also a comparison between SCDstrato derived from DOMINO (Dutch OMI NO2) and the SCDstrato obtained from ground and airborne measurements. Due to the mobility and flexibility of the ULT flights, this aerial platform provides a promising tool for satellite validation, especially for space observations by high resolution sensors such as the future TROPOMI instrument. A key added value of the ULT-DOAS, illustrated in this work, is the capacity to investigate the spatial variability of NO2 inside the horizontal extent of satellite pixels, e.g. above plant exhaust plumes.

  14. Near-infrared thermal emissivity from ground based atmospheric dust measurements at ORM

    CERN Document Server

    Lombardi, G; Ortolani, S; Melnick, J; Ghedina, A; Garcia, A; Molinari, E; Gatica, C

    2011-01-01

    We present an analysis of the atmospheric content of aerosols measured at Observatorio del Roque de los Muchachos (ORM; Canary Islands). Using a laser diode particle counter located at the Telescopio Nazionale Galileo (TNG) we have detected particles of 0.3, 0.5, 1.0, 3.0, 5.0 and 10.0 um size. The seasonal behavior of the dust content in the atmosphere is calculated. The Spring has been found to be dustier than the Summer, but dusty conditions may also occur in Winter. A method to estimate the contribution of the aerosols emissivity to the sky brightness in the near-infrared (NIR) is presented. The contribution of dust emission to the sky background in the NIR has been found to be negligible comparable to the airglow, with a maximum contribution of about 8-10% in the Ks band in the dusty days.

  15. Investigating mixed phase clouds using a synergy of ground based remote sensing measurements

    Science.gov (United States)

    Gierens, Rosa; Kneifel, Stefan; Löhnert, Ulrich

    2017-04-01

    Low level mixed phase clouds occur frequently in the Arctic, and can persist from hours to several days. However, the processes that lead to the commonality and persistence of these clouds are not well understood. The aim of our work is to get a more detailed understanding of the dynamics of and the processes in Arctic mixed phase clouds using a combination of instruments operating at the AWIPEV station in Svalbard. In addition, an aircraft campaign collecting in situ measurements inside mixed phase clouds above the station is planned for May-June 2017. The in situ data will be used for developing and validating retrievals for microphysical properties from Doppler cloud radar measurements. Once observational data for cloud properties is obtained, it can be used for evaluating model performance, for studies combining modeling and observational approaches, and eventually lead to developing model parameterizations of mixed phase microphysics. To describe the low-level mixed phase clouds, and the atmospheric conditions in which they occur, we present a case study of a persistent mixed phase cloud observed above the AWIPEV station. In the frame of the Arctic Amplification: Climate Relevant Atmospheric and Surface Processes and Feedback Mechanisms ((AC)3) -project, a millimeter wavelength cloud radar was installed at the site in June 2016. The high vertical (4 m in the lowest layer) and temporal (2.5 sec) resolution allows for a detailed description of the structure of the cloud. In addition to radar reflectivity and mean vertical velocity, we also utilize the higher moments of the Doppler spectra, such as skewness and kurtosis. To supplement the radar measurements, a ceilometer is used to detect liquid layers inside the cloud. Liquid water path and integrated water vapor are estimated using a microwave radiometer, which together with soundings can also provide temperature and humidity profiles in the lower troposphere. Moreover, a three-dimensional wind field is be

  16. Ground based measurements of particulate emissions from supersonic transports. Concorde olympus engine

    Energy Technology Data Exchange (ETDEWEB)

    Whitefield, Ph.D.; Hagen, D.E. [Missouri Univ., Rolla, MO (United States). Cloud and Aerosol Sciences Lab.; Lilenfeld, H.V. [McDonnell Douglas Corp., St. Louis, MO (United States)

    1997-12-31

    The application of a mobile aerosol monitoring facility, the Mobile Aerosol Sampling System (MASS) is described to characterize engine aerosol emissions from the Rolls Royce Olympus Engine. The multi-configurational MASS has been employed in both ground and airborne field operations. It has been successfully flown on research aircrafts. In ground tests the MASS has participated in numerous jet engine related ground tests, and has been deployed to resolve aerosol generation problems in a high power chemical laser system. In all cases the measurements were made on samples taken from a harsh physical and chemical environment, with both high and low temperature and pressure, and in the presence of highly reactive gases. (R.P.) 9 refs.

  17. Comparison of columnar water vapor over northern China derived from ground-based measurements and MODIS

    Science.gov (United States)

    Liu, Chaoshun; Shi, Runhe; Gao, Wei; Bai, Kaixu

    2011-09-01

    Water vapor represents a small but environmentally significant constituent of the atmosphere. This study retrieved columnar water vapor (CWV) with the 939.3 nm band of a Multi-filter Rotating Shadowband Radiometer (MFRSR) using the modified Langley technique from September 23, 2004 to June 20, 2005 at the XiangHe site.To improve the credibility, the MFRSR results were compared with those obtained from the AERONET (AErosol RObotic NETwork) CIMEL sun-photometer measurements, co-located at the XiangHe site, and the Moderate Resolution Imaging Spectroradiometer (MODIS) Near-Infrared Total Precipitable Water Product (MOD05), respectively. These comparisons show a good agreement in terms of correlation coefficients, slopes, and offsets, revealing that the accuracy of CWV estimation using the MFRSR instrument is reliable and suitable for extended studies in northern China.

  18. MIAWARA-C, a new ground based water vapor radiometer for measurement campaigns

    Directory of Open Access Journals (Sweden)

    C. Straub

    2010-09-01

    Full Text Available In this paper a new 22 GHz water vapor spectro-radiometer which has been specifically designed for profile measurement campaigns of the middle atmosphere is presented. The instrument is of a compact design and has a simple set up procedure. It can be operated as a standalone instrument as it maintains its own weather station and a calibration scheme that does not rely on other instruments or the use of liquid nitrogen. The optical system of MIAWARA-C combines a choked gaussian horn antenna with a parabolic mirror which reduces the size of the instrument in comparison with currently existing radiometers. For the data acquisition a correlation receiver is used together with a digital cross correlating spectrometer. The complete backend section, including the computer, is located in the same housing as the instrument. The receiver section is temperature stabilized to minimize gain fluctuations. Calibration of the instrument is achieved through a balancing scheme with the sky used as the cold load and the tropospheric properties are determined by performing regular tipping curves. Since MIAWARA-C is used in measurement campaigns it is important to be able to determine the elevation pointing in a simple manner as this is a crucial parameter in the calibration process. Here we present two different methods; scanning the sky and the Sun. Finally, we report on the first spectra and retrieved water vapor profiles acquired during the Lapbiat campaign at the Finnish Meteorological Institute Arctic Research Centre in Sodankylä, Finland. The performance of MIAWARA-C is validated here by comparison of the presented profiles against the equivalent profiles from the Microwave Limb Sounder on the EOS/Aura satellite.

  19. Solar-absorption measurements of ozone from two ground based FTIR sites

    Science.gov (United States)

    Plaza, Eddy; Stremme, Wolfgang; Bezanilla, Alejandro; Grutter, Michel; Blumenstock, Thomas; Hase, Frank; Gisi, Michael

    2013-04-01

    Ozone reduces the amount of ultraviolet light entering earths atmosphere and continuous monitoring of total ozone column especially in higher latitudes has been a major task since the discovery of the stratospheric ozone depletion. As tropospheric ozone is a main greenhouse gas, monitoring of ozone in the lower atmosphere and also in the tropics gains importance. Tropospheric ozone also plays an important role in air quality and high levels of ozone in the boundary layer affects the public health. Ozone is produced through a complicated path of photochemistry processes from volatile organic compounds and nitrogen oxides (NOx)[1]. In large cities, these ozone precursors are mainly emitted from anthropogenic activities and in Mexico City the ozone concentration frequently exceedes the local standard for air quality (e.g. on 80% of the days of the year 2002)[2]. Since May 2012 high resolution Fourier transform infrared solar absorption spectra have been used for determining the total column and profile of ozone at the high altitude remote site Altzomoni (19°.12`N, 98°.65`E) located 60 km southeast of Mexico City at 4000 m a.s.l. These measurements are complemented with solar absorption spectra recorded with a moderate resolution FTIR spectrometer at the UNAM campus in Mexcio City (19°25`N, 99°10`W, 2240 m a.s.l.). The vertical profiles and total columns of ozone are inferred from solar spectra by using the retrieval code PROFFIT. The results are compared with simulations of the Whole Atmosphere Community Climate Model (WACCM) and other correlative data. The ozone column amount in the polluted mixing layer of Mexico City is estimated from the intercomparison of measurements at the urban and remote sites and discussed. [1] Tie, X.; Brasseur, G.; Ying, Z. Impact of Model Resolution on Chemical Ozone Formation in Mexico City: Application of the Wrf-Chem Model. Atmospheric Chemistry and Physics. 2010, 10, 8983-8995. [2] McKinley, G.; Zuk, M.; Hojer, M.; Avalos, M

  20. Tracking of urban aerosols using combined lidar-based remote sensing and ground-based measurements

    Directory of Open Access Journals (Sweden)

    T.-Y. He

    2011-10-01

    Full Text Available A measuring campaign was performed over the neighboring towns of Nova Gorica in Slovenia and Gorizia in Italy on 24 and 25 May 2010, to investigate the concentration and distribution of urban aerosols. Tracking of two-dimensional spatial and temporal aerosol distributions was performed using scanning elastic lidar operating at 1064 nm. In addition, PM10 concentrations of particles, NOx and meteorological data were continuously monitored within the lidar scanning region. Based on the collected data, we investigated the flow dynamics and the aerosol concentrations within the lower troposphere and an evidence for daily aerosol cycles. We observed a number of cases with spatially localized increased lidar returns, which were found to be due to the presence of point sources of particulate matter. Daily aerosol concentration cycles were also clearly visible with a peak in aerosol concentration during the morning rush hours and daily maximum at around 17:00 Central European Time. We also found that the averaged horizontal atmospheric extinction within the scanning region 200 m above the ground is correlated to the PM10 concentration at the ground level with a correlation coefficient of 0.64, which may be due to relatively quiet meteorological conditions and basin-like terrain configuration.

  1. Measuring galaxy [OII] emission line doublet with future ground-based wide-field spectroscopic surveys

    CERN Document Server

    Comparat, Johan; Bacon, Roland; Mostek, Nick J; Newman, Jeffrey A; Schlegel, David J; Yèche, Christophe

    2013-01-01

    The next generation of wide-field spectroscopic redshift surveys will map the large-scale galaxy distribution in the redshift range 0.7< z<2 to measure baryonic acoustic oscillations (BAO). The primary optical signature used in this redshift range comes from the [OII] emission line doublet, which provides a unique redshift identification that can minimize confusion with other single emission lines. To derive the required spectrograph resolution for these redshift surveys, we simulate observations of the [OII] (3727,3729) doublet for various instrument resolutions, and line velocities. We foresee two strategies about the choice of the resolution for future spectrographs for BAO surveys. For bright [OII] emitter surveys ([OII] flux ~30.10^{-17} erg /cm2/s like SDSS-IV/eBOSS), a resolution of R~3300 allows the separation of 90 percent of the doublets. The impact of the sky lines on the completeness in redshift is less than 6 percent. For faint [OII] emitter surveys ([OII] flux ~10.10^{-17} erg /cm2/s like ...

  2. Ground-Based Measurement Experiment and First Results with Geosynchronous-Imaging Fourier Transform Spectrometer Engineering Demonstration Unit

    Science.gov (United States)

    Zhou, Daniel K.; Smith, William L.; Bingham, Gail E.; Huppi, Ronald J.; Revercomb, Henry E.; Zollinger, Lori J.; Larar, Allen M.; Liu, Xu; Tansock, Joseph J.; Reisse, Robert A.; Hooker, Ronald

    2007-01-01

    The geosynchronous-imaging Fourier transform spectrometer (GIFTS) engineering demonstration unit (EDU) is an imaging infrared spectrometer designed for atmospheric soundings. It measures the infrared spectrum in two spectral bands (14.6 to 8.8 microns, 6.0 to 4.4 microns) using two 128 x 128 detector arrays with a spectral resolution of 0.57 cm(exp -1) with a scan duration of approximately 11 seconds. From a geosynchronous orbit, the instrument will have the capability of taking successive measurements of such data to scan desired regions of the globe, from which atmospheric status, cloud parameters, wind field profiles, and other derived products can be retrieved. The GIFTS EDU provides a flexible and accurate testbed for the new challenges of the emerging hyperspectral era. The EDU ground-based measurement experiment, held in Logan, Utah during September 2006, demonstrated its extensive capabilities and potential for geosynchronous and other applications (e.g., Earth observing environmental measurements). This paper addresses the experiment objectives and overall performance of the sensor system with a focus on the GIFTS EDU imaging capability and proof of the GIFTS measurement concept.

  3. Validation of OMI-TOMS and OMI-DOAS total ozone column using five Brewer spectroradiometers at the Iberian peninsula

    Science.gov (United States)

    Antón, M.; López, M.; Vilaplana, J. M.; Kroon, M.; McPeters, R.; Bañón, M.; Serrano, A.

    2009-07-01

    This article focuses on the comparison of the total ozone column data from the Ozone Monitoring Instrument (OMI) flying aboard the NASA EOS-Aura satellite platform with ground-based measurement recorded by Brewer spectroradiometers located at five Spanish remote sensing ground stations between January 2005 and December 2007. The satellite data are derived from two algorithms: OMI Total Ozone Mapping Spectrometer (OMI-TOMS) and OMI Differential Optical Absorption Spectroscopy (OMI-DOAS). The largest relative differences between these OMI total ozone column estimates reach 5% with a significant seasonal dependence. The agreement between OMI ozone data and Brewer measurements is excellent. Total ozone columns from OMI-TOMS are on average a mere 2.0% lower than Brewer data. For OMI-DOAS data the bias is a mere 1.4%. However, the relative difference between OMI-TOMS and Brewer measurements shows a notably lower seasonal dependence and variability than the differences between OMI-DOAS and ground-based data. For both OMI ozone data products these relative differences show significant dependence on the satellite ground pixel solar zenith angle for cloud-free cases as well as for cloudy conditions. However, the OMI ozone data products are shown to reveal opposite behavior with respect to the two antagonistic sky conditions. No significant dependency of the ground-based to satellite-based differences with respect to the satellite cross-track position is seen for either OMI retrieval algorithm.

  4. Investigation the optical and radiative properties of aerosol vertical profile of boundary layer by lidar and ground based measurements

    Science.gov (United States)

    Chen, W.; Chou, C.; Lin, P.; Wang, S.

    2011-12-01

    The planetary boundary layer is the air layer near the ground directly affected by diurnal heat, moisture, aerosol, and cloud transfer to or from the surface. In the daytime solar radiation heats the surface, initiating thermal instability or convection. Whereas, the scattering and absorption of aerosols or clouds might decrease the surface radiation or heat atmosphere which induce feedbacks such as the enhanced stratification and change in relative humidity in the boundary layer. This study is aimed to understand the possible radiative effect of aerosols basing on ground based aerosol measurements and lidar installed in National Taiwan University in Taipei. The optical and radiative properties of aerosols are dominated by aerosol composition, particle size, hygroscopicity property, and shape. In this study, aerosol instruments including integrating nephelometer, open air nephelometer, aethalometer are applied to investigate the relationship between aerosol hygroscopicity properties and aerosol types. The aerosol hygroscopicity properties are further applied to investigate the effect of relative humidity on aerosol vertical profiles measured by a dual-wavelength and depolarization lidar. The possible radiative effect of aerosols are approached by vertical atmospheric extinction profiles measured by lidar. Calculated atmospheric and aerosol heating effects was compared with vertical meteorological parameters measured by radiosonde. The result shows light-absorbing aerosol has the potential to affect the stability of planetary boundary layer.

  5. Ground-based measurements of the vertical E-field in mountainous regions and the "Austausch" effect

    Science.gov (United States)

    Yaniv, Roy; Yair, Yoav; Price, Colin; Mkrtchyan, Hripsime; Lynn, Barry; Reymers, Artur

    2017-06-01

    Past measurements of the atmospheric vertical electric field (Ez or potential gradient) at numerous land stations showed a strong response of the daily electric field to a morning local effect known as ;Austausch; - the transport of electrical charges due to increased turbulence. In mountainous regions, nocturnal charge accumulation, followed by an attachment process to aerosols near the surface in valleys, known as the electrode effect, is lifted as a charged aerosol layer by anabatic (upslope) winds during the morning hours due to solar heating. Ground-based measurements during fair weather days were conducted at three mountain stations in Israel and Armenia. We present results of the mean diurnal variation of Ez and make comparisons with the well-known Carnegie curve and with past measurements of Ez on mountains. We report a good agreement between the mean diurnal curves of Ez at various mountain stations and the time of local sunrise when the Ez is found to increase. We attribute this morning maximum to the Austausch (or exchange) layer effect. We support our findings with conduction and turbulent current measurements showing high values of ions and charged aerosols being transported by winds from morning to noon local time, and by model simulations showing the convergence of winds in the early morning hours toward the mountain peak.

  6. Co-located ground-based remote sensing and in situ measurements at the tropical atmospheric observatory in Suriname

    Science.gov (United States)

    Warneke, T.; Petersen, K.; Gerbig, C.; Macatangay, R.; Koerner, S.; Jordan, A.; Rothe, M.; Notholt, J.; Schrems, O.

    2009-04-01

    The first ground-based remote sensing measurements of the column averaged volume mixing ratio of CO2 (XCO2) for the inner tropics have been obtained at Paramaribo, Suriname (5.8°N, 55.2°W). Due to the migration of the ITCZ over the measurement location the probed air masses belong to the northern or southern hemisphere depending on the time of the year. The XCO2 shows an average annual increase in the Southern Hemisphere of 2.2 ppm for the time period 2004 to 2007, which agrees within the error with model simulations. Co-located in-situ measurements are strongly influenced by a local source. From the isotopic composition of the air samples the local source component is suggested to be the terrestrial biosphere. Using d13C from the NOAA/ESRL stations Ascension Is. (ASC) and Ragged Point (RPB) the data has been corrected for the local source component. The corrected mixing ratios for the surface as well as the XCO2 qualitatively agree with model simulations.

  7. Simultaneous Retrieval of Aerosol and Surface Optical Properties from Combined Airborne- and Ground-Based Direct and Diffuse Radiometric Measurements

    Science.gov (United States)

    Gatebe, C. K.; Dubovik, O.; King, M. D.; Sinyuk, A.

    2010-01-01

    This paper presents a new method for simultaneously retrieving aerosol and surface reflectance properties from combined airborne and ground-based direct and diffuse radiometric measurements. The method is based on the standard Aerosol Robotic Network (AERONET) method for retrieving aerosol size distribution, complex index of refraction, and single scattering albedo, but modified to retrieve aerosol properties in two layers, below and above the aircraft, and parameters on surface optical properties from combined datasets (Cloud Absorption Radiometer (CAR) and AERONET data). A key advantage of this method is the inversion of all available spectral and angular data at the same time, while accounting for the influence of noise in the inversion procedure using statistical optimization. The wide spectral (0.34-2.30 m) and angular range (180 ) of the CAR instrument, combined with observations from an AERONET sunphotometer, provide sufficient measurement constraints for characterizing aerosol and surface properties with minimal assumptions. The robustness of the method was tested on observations made during four different field campaigns: (a) the Southern African Regional Science Initiative 2000 over Mongu, Zambia, (b) the Intercontinental Transport Experiment-Phase B over Mexico City, Mexico (c) Cloud and Land Surface Interaction Campaign over the Atmospheric Radiation Measurement (ARM) Central Facility, Oklahoma, USA, and (d) the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) over Elson Lagoon in Barrow, Alaska, USA. The four areas are dominated by different surface characteristics and aerosol types, and therefore provide good test cases for the new inversion method.

  8. Simultaneous ground-based thermospheric wind measurements using Doppler asymmetric spatial heterodyne spectroscopy (DASH) and Fabry-Perot Interferometry

    Science.gov (United States)

    Englert, C. R.; Harlander, J. M.; Meriwether, J. W.; Brown, C. M.; Drob, D. P.; Emmert, J. T.; Castelaz, M.; Roesler, F. L.

    2011-12-01

    The concept of Doppler Asymmetric Spatial Heterodyne (DASH) instruments to measure upper atmospheric winds was initially published in 2006. The DASH approach is identical to the concept of Spatial Heterodyne Spectroscopy (SHS) except that one interferometer arm includes an additional fixed optical path offset, similar to the phase stepping Michelson technique which was used for the WINDII (Wind Imaging Interferometer) experiment. The advantages of DASH include having no moving parts, high sensitivity, and the ability to simultaneously observe multiple isolated emission lines, including a known light source for real time calibration. Since it was first proposed, the development of the DASH technique has progressed significantly. Major milestones include a proof of concept in the laboratory, the design, fabrication and test of a monolithic DASH interferometer for the thermospheric red line (O I 630nm), and initial ground based thermospheric wind measurements using this interferometer. To further increase the technical readiness level (TRL) of DASH for a future satellite instrument, we have conducted coordinated measurements with a DASH prototype and Fabry-Perot interferometer (FPI) from the Pisgah Astronomical Research Institute in North Carolina in the summer of 2011. We will present a comparison of the two experimental data sets and examine how they compare with the empirical horizontal wind model HWM-07.

  9. Re-analysis of ground-based microwave ClO measurements from Mauna Kea, 1992 to early 2012

    Directory of Open Access Journals (Sweden)

    B. J. Connor

    2013-09-01

    Full Text Available We present a re-analysis of upper stratospheric ClO measurements from the ground-based millimeter-wave instrument from January 1992 to February 2012. These measurements are made as part of the Network for the Detection of Atmospheric Composition Change (NDACC from Mauna Kea, Hawaii, (19.8° N, 204.5° E. Here, we use daytime and nighttime measurements together to form a day–night spectrum, from which the difference in the day and night profiles is retrieved. These results are then compared to the day–night difference profiles from the Upper Atmosphere Research Satellite (UARS and Aura Microwave Limb Sounder (MLS instruments. We also compare them to our previous analyses of the same data, in which we retrieved the daytime ClO profile. The major focus will be on comparing the year-to-year and long-term changes in ClO derived by the two analysis methods, and comparing these results to the long-term changes reported by others. We conclude that the re-analyzed data set has less short-term variability and exhibits a more constant long-term trend that is more consistent with other observations. Data from 1995 to 2012 indicate a linear decline of mid-stratospheric ClO of 0.64 ± 0.15% yr−1 (2σ.

  10. Re-analysis of ground-based microwave ClO measurements from Mauna Kea, 1992 to early 2012

    Directory of Open Access Journals (Sweden)

    B. J. Connor

    2012-11-01

    Full Text Available We present a re-analysis of upper stratospheric ClO measurements from the ground-based millimeter-wave instrument from January 1992 to February 2012. These measurements are made as part of the Network for the Detection of Atmospheric Composition Change (NDACC from Mauna Kea, Hawaii, (19.8° N, 204.5° E. Here, we use daytime and nighttime measurements together to form a day-night spectrum, from which the difference in the day and night profiles is retrieved. These results are then compared to the day-night difference profiles from the UARS and Aura Microwave Limb Sounder (MLS instruments. We also compare them to our previous analyses of the same data, in which we retrieved the daytime ClO profile. The major focus will be on comparing the year-to-year and long-term changes in ClO derived by the two analysis methods. We conclude that the re-analyzed data set has less short-term variability and exhibits a more constant long-term trend. Data from 1995–2012 indicate a linear decline of mid-stratospheric ClO of 0.64 ± 0.08% yr−1.

  11. Retrieval and validation of O3 measurements from ground-based FTIR spectrometer at equatorial station: Addis Ababa, Ethiopia

    Science.gov (United States)

    Takele Kenea, S.; Mengistu Tsidu, G.; Blumenstock, T.; Hase, F.; von Clarmann, T.; Stiller, G. P.

    2012-09-01

    Since May 2009 high-resolution Fourier transform infrared (FTIR) solar absorption spectra are recorded at Addis Ababa (9.01° N latitude, 38.76° E longitude, 2443 m altitude a.s.l.), Ethiopia. The vertical profiles and total column amounts of ozone (O3) are deduced from the spectra by using the retrieval code PROFFIT (V9.5) and regularly determined instrumental line shape (ILS). A detailed error analysis of the O3 retrieval is performed. Averaging kernels analysis of the target gas shows that the major contribution to the retrieved information always comes from the measurement. We obtained 2.1 degrees of freedom on average for signals in the retrieval of O3 from the observed FTIR spectra. We have compared the FTIR retrieval of ozone Volume Mixing Ratio (VMR) profiles and column amounts with the coincident satellite observations of Microwave Limb Sounding (MLS), Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) and Tropospheric Emission Spectrometer (TES), Ozone Monitoring Instrument (OMI), Atmospheric Infrared Sounding (AIRS) and Global Ozone Monitoring Experiment (GOME-2) instrument. The mean relative differences are generally found below +15% in the altitude range of 27 to 36 km for comparison of VMR profiles made between MLS and MIPAS, whereas comparison with TES has shown below 9.4% relative difference. Furthermore, the mean relative difference is positive above 31 km, suggesting positive bias in the FTIR measurement of O3 VMR with respect to MLS, MIPAS and TES. The overall comparisons of column amounts of satellite measurements with the ground-based FTIR instruments show better agreement exhibiting mean relative differences of ground-based FTIR with respect to MLS and GOME-2 within +0.4% to +4.0% and corresponding standard deviations of 2.2 to 4.3% whereas, in the case of OMI, TES, AIRS, the mean relative differences are from -0.38 to -6.8%. Thus, the retrieved O3 VMR and column amounts from a tropical site, Addis Ababa, is found to exhibit

  12. Ground-based multispectral measurements for airborne data verification in non-operating open pit mine "Kremikovtsi"

    Science.gov (United States)

    Borisova, Denitsa; Nikolov, Hristo; Petkov, Doyno

    2013-10-01

    The impact of mining industry and metal production on the environment is presented all over the world. In our research we set focus on the impact of already non-operating ferrous "Kremikovtsi"open pit mine and related waste dumps and tailings which we consider to be the major factor responsible for pollution of one densely populated region in Bulgaria. The approach adopted is based on correct estimation of the distribution of the iron oxides inside open pit mines and the neighboring regions those considered in this case to be the key issue for the ecological state assessment of soils, vegetation and water. For this study the foremost source of data are those of airborne origin and those combined with ground-based in-situ and laboratory acquired data were used for verification of the environmental variables and thus in process of assessment of the present environmental status influenced by previous mining activities. The percentage of iron content was selected as main indicator for presence of metal pollution since it could be reliably identified by multispectral data used in this study and also because the iron compounds are widely spread in the most of the minerals, rocks and soils. In our research the number of samples from every source (air, field, lab) was taken in the way to be statistically sound and confident. In order to establish relationship between the degree of pollution of the soil and mulspectral data 40 soil samples were collected during a field campaign in the study area together with GPS measurements for two types of laboratory measurements: the first one, chemical and mineralogical analysis and the second one, non-destructive spectroscopy. In this work for environmental variables verification over large areas mulspectral satellite data from Landsat instruments TM/ETM+ and from ALI/OLI (Operational Land Imager) were used. Ground-based (laboratory and in-situ) spectrometric measurements were performed using the designed and constructed in Remote

  13. Comparison of 7 years of satellite-borne and ground-based tropospheric NO2 measurements around Milan, Italy

    Science.gov (United States)

    OrdóñEz, C.; Richter, A.; Steinbacher, M.; Zellweger, C.; Nüß, H.; Burrows, J. P.; PréVôT, A. S. H.

    2006-03-01

    Tropospheric NO2 vertical column densities (VCDs) over the Lombardy region were retrieved from measurements of the Global Ozone Monitoring Experiment (GOME) spectrometer for the period 1996-2002 using a differential optical absorption method. This data set was compared with in situ measurements of NO2 at around 100 ground stations in the Lombardy region, northern Italy. The tropospheric NO2 VCDs are reasonably well correlated with the near-surface measurements under cloud-free conditions. However, the slope of the tropospheric VCDs versus ground measurements is higher in autumn-winter than in spring-summer. This effect is clearly reduced when the peroxyacetyl nitrate and nitric acid (HNO3) interferences of conventional NOx analyzers are taken into account. For a more quantitative comparison, the NO2 ground measurements were scaled to tropospheric VCDs using a seasonal NO2 vertical profile over northern Italy calculated by the Model of Ozone and Related Tracers 2 (MOZART-2). The tropospheric VCDs retrieved from satellite and those determined from ground measurements agree well, with a correlation coefficient R = 0.78 and a slope close to 1 for slightly polluted stations. GOME cannot reproduce the high NO2 amounts over the most polluted stations, mainly because of the large spatial variability in the distribution of pollution within the GOME footprint. The yearly and weekly cycles of the tropospheric NO2 VCDs are similar for both data sets, with significantly lower values in the summer months and on Sundays, respectively. Considering the pollution level and high aerosol concentrations of this region, the agreement is very good. Furthermore, uncertainties in the ground-based measurements, including the extrapolation to NO2 VCDs, might be as important as those of the NO2 satellite retrieval itself.

  14. Optical and geometrical properties of cirrus clouds in Amazonia derived from 1 year of ground-based lidar measurements

    Science.gov (United States)

    Gouveia, Diego A.; Barja, Boris; Barbosa, Henrique M. J.; Seifert, Patric; Baars, Holger; Pauliquevis, Theotonio; Artaxo, Paulo

    2017-03-01

    Cirrus clouds cover a large fraction of tropical latitudes and play an important role in Earth's radiation budget. Their optical properties, altitude, vertical and horizontal coverage control their radiative forcing, and hence detailed cirrus measurements at different geographical locations are of utmost importance. Studies reporting cirrus properties over tropical rain forests like the Amazon, however, are scarce. Studies with satellite profilers do not give information on the diurnal cycle, and the satellite imagers do not report on the cloud vertical structure. At the same time, ground-based lidar studies are restricted to a few case studies. In this paper, we derive the first comprehensive statistics of optical and geometrical properties of upper-tropospheric cirrus clouds in Amazonia. We used 1 year (July 2011 to June 2012) of ground-based lidar atmospheric observations north of Manaus, Brazil. This dataset was processed by an automatic cloud detection and optical properties retrieval algorithm. Upper-tropospheric cirrus clouds were observed more frequently than reported previously for tropical regions. The frequency of occurrence was found to be as high as 88 % during the wet season and not lower than 50 % during the dry season. The diurnal cycle shows a minimum around local noon and maximum during late afternoon, associated with the diurnal cycle of precipitation. The mean values of cirrus cloud top and base heights, cloud thickness, and cloud optical depth were 14.3 ± 1.9 (SD) km, 12.9 ± 2.2 km, 1.4 ± 1.1 km, and 0.25 ± 0.46, respectively. Cirrus clouds were found at temperatures down to -90 °C. Frequently cirrus were observed within the tropical tropopause layer (TTL), which are likely associated to slow mesoscale uplifting or to the remnants of overshooting convection. The vertical distribution was not uniform, and thin and subvisible cirrus occurred more frequently closer to the tropopause. The mean lidar ratio was 23.3 ± 8.0 sr. However, for

  15. Comparing multiple model-derived aerosol optical properties to spatially collocated ground-based and satellite measurements

    Science.gov (United States)

    Ocko, Ilissa B.; Ginoux, Paul A.

    2017-04-01

    Anthropogenic aerosols are a key factor governing Earth's climate and play a central role in human-caused climate change. However, because of aerosols' complex physical, optical, and dynamical properties, aerosols are one of the most uncertain aspects of climate modeling. Fortunately, aerosol measurement networks over the past few decades have led to the establishment of long-term observations for numerous locations worldwide. Further, the availability of datasets from several different measurement techniques (such as ground-based and satellite instruments) can help scientists increasingly improve modeling efforts. This study explores the value of evaluating several model-simulated aerosol properties with data from spatially collocated instruments. We compare aerosol optical depth (AOD; total, scattering, and absorption), single-scattering albedo (SSA), Ångström exponent (α), and extinction vertical profiles in two prominent global climate models (Geophysical Fluid Dynamics Laboratory, GFDL, CM2.1 and CM3) to seasonal observations from collocated instruments (AErosol RObotic NETwork, AERONET, and Cloud-Aerosol Lidar with Orthogonal Polarization, CALIOP) at seven polluted and biomass burning regions worldwide. We find that a multi-parameter evaluation provides key insights on model biases, data from collocated instruments can reveal underlying aerosol-governing physics, column properties wash out important vertical distinctions, and improved models does not mean all aspects are improved. We conclude that it is important to make use of all available data (parameters and instruments) when evaluating aerosol properties derived by models.

  16. Comparison of OMI NO2 observations and their seasonal and weekly cycles with ground-based measurements in Helsinki

    Science.gov (United States)

    Ialongo, Iolanda; Herman, Jay; Krotkov, Nick; Lamsal, Lok; Folkert Boersma, K.; Hovila, Jari; Tamminen, Johanna

    2016-10-01

    We present the comparison of satellite-based OMI (Ozone Monitoring Instrument) NO2 products with ground-based observations in Helsinki. OMI NO2 total columns, available from NASA's standard product (SP) and KNMI DOMINO product, are compared with the measurements performed by the Pandora spectrometer in Helsinki in 2012. The relative difference between Pandora no. 21 and OMI SP total columns is 4 and -6 % for clear-sky and all-sky conditions, respectively. DOMINO NO2 retrievals showed slightly lower total columns with median differences about -5 and -14 % for clear-sky and all-sky conditions, respectively. Large differences often correspond to cloudy fall-winter days with solar zenith angles above 65°. Nevertheless, the differences remain within the retrieval uncertainties. The average difference values are likely the result of different factors partly canceling each other: the overestimation of the stratospheric columns causes a positive bias partly compensated by the limited spatial representativeness of the relatively coarse OMI pixel for sharp NO2 gradients. The comparison between Pandora and the new version (V3) of OMI NO2 retrievals shows a larger negative difference (about -30 %) than the current version (V2.1) because the revised spectral fitting procedure reduces the overestimation of the stratospheric column. The weekly and seasonal cycles from OMI, Pandora and NO2 surface concentrations are also compared. Both satellite- and ground-based data show a similar weekly cycle, with lower NO2 levels during the weekend compared to the weekdays as a result of reduced emissions from traffic and industrial activities. The seasonal cycle also shows a similar behavior, even though the results are affected by the fact that most of the data are available during spring-summer because of cloud cover in other seasons. This is one of few works in which OMI NO2 retrievals are evaluated in a urban site at high latitudes (60° N). Despite the city of Helsinki having

  17. Radiometric Modeling and Calibration of the Geostationary Imaging Fourier Transform Spectrometer (GIFTS)Ground Based Measurement Experiment

    Science.gov (United States)

    Tian, Jialin; Smith, William L.; Gazarik, Michael J.

    2008-01-01

    The ultimate remote sensing benefits of the high resolution Infrared radiance spectrometers will be realized with their geostationary satellite implementation in the form of imaging spectrometers. This will enable dynamic features of the atmosphere s thermodynamic fields and pollutant and greenhouse gas constituents to be observed for revolutionary improvements in weather forecasts and more accurate air quality and climate predictions. As an important step toward realizing this application objective, the Geostationary Imaging Fourier Transform Spectrometer (GIFTS) Engineering Demonstration Unit (EDU) was successfully developed under the NASA New Millennium Program, 2000-2006. The GIFTS-EDU instrument employs three focal plane arrays (FPAs), which gather measurements across the long-wave IR (LWIR), short/mid-wave IR (SMWIR), and visible spectral bands. The GIFTS calibration is achieved using internal blackbody calibration references at ambient (260 K) and hot (286 K) temperatures. In this paper, we introduce a refined calibration technique that utilizes Principle Component (PC) analysis to compensate for instrument distortions and artifacts, therefore, enhancing the absolute calibration accuracy. This method is applied to data collected during the GIFTS Ground Based Measurement (GBM) experiment, together with simultaneous observations by the accurately calibrated AERI (Atmospheric Emitted Radiance Interferometer), both simultaneously zenith viewing the sky through the same external scene mirror at ten-minute intervals throughout a cloudless day at Logan Utah on September 13, 2006. The accurately calibrated GIFTS radiances are produced using the first four PC scores in the GIFTS-AERI regression model. Temperature and moisture profiles retrieved from the PC-calibrated GIFTS radiances are verified against radiosonde measurements collected throughout the GIFTS sky measurement period. Using the GIFTS GBM calibration model, we compute the calibrated radiances from data

  18. Intermittency of the turbulent processes in the Earth's magnetosphere detected from the ground-based measurements

    Energy Technology Data Exchange (ETDEWEB)

    Stepanova, Marina [Physical Department, Universidad de Santiago de Chile (Chile); Foppiano, Alberto; Ovalle, Elias [Departmento de Geofisica, Universidad de Conception (Chile); Antonova, Elizavieta [Skobeltsyn Institute of Nuclear Physics, Moscow State University, Moscow (Russian Federation); Troshichev, Oleg [Department of Geophysics, Arctic and Antarctic Research Institute, St. Petersburg (Russian Federation)], E-mail: mstepano@usach.cl

    2008-11-01

    Turbulent processes in the Earth's magnetosphere are reflected in the dynamical behavior of the geomagnetic indices and other parameters determined from ground based observations. Intermittent properties of one minute Polar Cap (PC) index and auroral radio wave absorption are studied using 1995-2000 data sets. It was found that the probability distribution functions (PDFs) of both PC-index and absorption fluctuations display a strong non-Gaussian shape. This indicates that they are not characterized by a global time self-similarity but rather exhibit intermittency, as previously reported for solar wind velocity and auroral electrojet index values. In the case of the auroral absorption it was also found that intermittency strongly depends on the magnetic local time, being largest in the nighttime sector. This shows that the acceleration of precipitating particles is intermittent, especially near the substorm eye, where the level of turbulence increases. Application of the Local Intermittency Measure (LIM) technique confirms the aforementioned results to a better precision.

  19. Validation of ACE-FTS measurements of CFC-11, CFC-12, and HCFC-22 using ground-based FTIR spectrometers

    Science.gov (United States)

    Kolonjari, F.; Walker, K. A.; Mahieu, E.; Batchelor, R. L.; Bernath, P. F.; Boone, C.; Conway, S. A.; Dan, L.; Griffin, D.; Harrett, A.; Kasai, Y.; Kagawa, A.; Lindenmaier, R.; Strong, K.; Whaley, C.

    2013-12-01

    Satellite datasets can be an effective global monitoring tool for long-lived compounds in the atmosphere. The Atmospheric Chemistry Experiment (ACE) is a mission on-board the Canadian satellite SCISAT-1. The primary instrument on SCISAT-1 is a high-resolution infrared Fourier transform spectrometer (ACE-FTS) which is capable of measuring a range of gases including key chlorofluorocarbon (CFC) and hydrochlorofluorocarbon (HCFC) species. These families of species are of interest because of their significant contribution to anthropogenic ozone depletion and to global warming. To assess the quality of data derived from satellite measurements, validation using other data sources is essential. Ground-based Fourier transform infrared (FTIR) spectrometers are particularly useful for this purpose. In this study, five FTIR spectrometers located at four sites around the world are used to validate the CFC-11 (CCl3F), CFC-12 (CCl2F2), and HCFC-22 (CHClF2) retrieved profiles from ACE-FTS measurements. These species are related because HCFC-22 was the primary replacement for CFC-11 and CFC-12 in refrigerant and propellant applications. The FTIR spectrometers used in this study record solar absorption spectra at Eureka (Canada), Jungfraujoch (Switzerland), Poker Flat (USA), and Toronto (Canada). The retrieval of CFC-11, CFC-12, and HCFC-22 are not standard products for many of these instruments, and as such, a harmonization of retrieval parameters between the sites has been conducted. The retrievals of these species from the FTIR spectra are sensitive from the surface to approximately 20 km, while the ACE-FTS profiles extend from approximately 6 to 30 km. For each site, partial column comparisons between coincident measurements of the three species and a validation of the observed trends will be discussed.

  20. Characterization of downwelling radiance measured from a ground-based microwave radiometer using numerical weather prediction model data

    Science.gov (United States)

    Ahn, M.-H.; Won, H. Y.; Han, D.; Kim, Y.-H.; Ha, J.-C.

    2016-01-01

    The ground-based microwave sounding radiometers installed at nine weather stations of Korea Meteorological Administration alongside with the wind profilers have been operating for more than 4 years. Here we apply a process to assess the characteristics of the observation data by comparing the measured brightness temperature (Tb) with reference data. For the current study, the reference data are prepared by the radiative transfer simulation with the temperature and humidity profiles from the numerical weather prediction model instead of the conventional radiosonde data. Based on the 3 years of data, from 2010 to 2012, we were able to characterize the effects of the absolute calibration on the quality of the measured Tb. We also showed that when clouds are present the comparison with the model has a high variability due to presence of cloud liquid water therefore making cloudy data not suitable for assessment of the radiometer's performance. Finally we showed that differences between modeled and measured brightness temperatures are unlikely due to a shift in the selection of the center frequency but more likely due to spectroscopy issues in the wings of the 60 GHz absorption band. With a proper consideration of data affected by these two effects, it is shown that there is an excellent agreement between the measured and simulated Tb. The regression coefficients are better than 0.97 along with the bias value of better than 1.0 K except for the 52.28 GHz channel which shows a rather large bias and variability of -2.6 and 1.8 K, respectively.

  1. Spatial extent of new particle formation events over the Mediterranean Basin from multiple ground-based and airborne measurements

    Science.gov (United States)

    Berland, Kevin; Rose, Clémence; Pey, Jorge; Culot, Anais; Freney, Evelyn; Kalivitis, Nikolaos; Kouvarakis, Giorgios; Cerro, José Carlos; Mallet, Marc; Sartelet, Karine; Beckmann, Matthias; Bourriane, Thierry; Roberts, Greg; Marchand, Nicolas; Mihalopoulos, Nikolaos; Sellegri, Karine

    2017-08-01

    Over the last two decades, new particle formation (NPF), i.e., the formation of new particle clusters from gas-phase compounds followed by their growth to the 10-50 nm size range, has been extensively observed in the atmosphere at a given location, but their spatial extent has rarely been assessed. In this work, we use aerosol size distribution measurements performed simultaneously at Ersa (Corsica) and Finokalia (Crete) over a 1-year period to analyze the occurrence of NPF events in the Mediterranean area. The geographical location of these two sites, as well as the extended sampling period, allows us to assess the spatial and temporal variability in atmospheric nucleation at a regional scale. Finokalia and Ersa show similar seasonalities in the monthly average nucleation frequencies, growth rates, and nucleation rates, although the two stations are located more than 1000 km away from each other. Within this extended period, aerosol size distribution measurements were performed during an intensive campaign (3 July to 12 August 2013) from a ground-based station on the island of Mallorca, as well as onboard the ATR-42 research aircraft. This unique combination of stationary and mobile measurements provides us with detailed insights into the horizontal and vertical development of the NPF process on a daily scale. During the intensive campaign, nucleation events occurred simultaneously both at Ersa and Mallorca over delimited time slots of several days, but different features were observed at Finokalia. The results show that the spatial extent of the NPF events over the Mediterranean Sea might be as large as several hundreds of kilometers, mainly determined by synoptic conditions. Airborne measurements gave additional information regarding the origin of the clusters detected above the sea. The selected cases depicted contrasting situations, with clusters formed in the marine boundary layer or initially nucleated above the continent or in the free troposphere (FT) and

  2. Spektroskopische (DOAS)-Langzeitmessungen von Ozon und Vorlaeufersubstanzen an der Ostseekuestenstation Arkona. Abschlussbericht; Long term spectroscopic (DOAS) measurement of ozone and related species at the Baltic coast station Arkona. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, R. [Institut fuer Troposphaerenforschung e.V. (IfT), Leipzig (Germany); Flentje, H. [Institut fuer Troposphaerenforschung e.V. (IfT), Leipzig (Germany); Heintz, F. [Heidelberg Univ. (Germany). Inst. fuer Umweltphysik; Karbach, H.J. [Institut fuer Troposphaerenforschung e.V. (IfT), Leipzig (Germany); Stutz, J. [Heidelberg Univ. (Germany). Inst. fuer Umweltphysik; Platt, U. [Heidelberg Univ. (Germany). Inst. fuer Umweltphysik

    1996-08-01

    Boundary layer ozone concentrations have been recorded since 1956 by the German Weather Service, (MD / DWD) at Cape Arkona, Island of Ruegen, GDR / FRG. In April 1993, a Long Path Differential Optical Absorption Spectrometer (LP-DOAS) was set up near the DWD-site. Measurements of the concentrations of O{sub 3}, NO{sub 2}, NO{sub 3} and SO{sub 2} were carried out with a newly developed DOAS system. The system incorporates two coaxially arranged Newton-type telescopes, a flat field holographic grating spectrometer and a retro reflector array. Combining the meteorological data with ozone and other gas concentrations, sector-classified results are used to identify the constraints for future evaluations of regional long-term trends of ozone concentrations. A statistical analysis of different trace gases for the periods summer, autumn, winter and spring is prepared. The long term nitrate radicals data record is used to retrieve information on the production rate of nitrate radicals, its lifetime, and possible depletion mechanism. (orig.)

  3. Comparison of OH concentration measurements by DOAS and LIF during SAPHIR chamber experiments at high OH reactivity and low NO concentration

    Directory of Open Access Journals (Sweden)

    H. Fuchs

    2012-07-01

    Full Text Available During recent field campaigns, hydroxyl radical (OH concentrations that were measured by laser-induced fluorescence (LIF were up to a factor of ten larger than predicted by current chemical models for conditions of high OH reactivity and low NO concentration. These discrepancies, which were observed in forests and urban-influenced rural environments, are so far not entirely understood. In summer 2011, a series of experiments was carried out in the atmosphere simulation chamber SAPHIR in Jülich, Germany, in order to investigate the photochemical degradation of isoprene, methyl-vinyl ketone (MVK, methacrolein (MACR and aromatic compounds by OH. Conditions were similar to those experienced during the PRIDE-PRD2006 campaign in the Pearl River Delta (PRD, China, in 2006, where a large difference between OH measurements and model predictions was found. During experiments in SAPHIR, OH was simultaneously detected by two independent instruments: LIF and differential optical absorption spectroscopy (DOAS. Because DOAS is an inherently calibration-free technique, DOAS measurements are regarded as a reference standard. The comparison of the two techniques was used to investigate potential artifacts in the LIF measurements for PRD-like conditions of OH reactivities of 10 to 30 s−1 and NO mixing ratios of 0.1 to 0.3 ppbv. The analysis of twenty experiment days shows good agreement. The linear regression of the combined data set (averaged to the DOAS time resolution, 2495 data points yields a slope of 1.02 ± 0.01 with an intercept of (0.10 ± 0.03 × 106 cm−3 and a linear correlation coefficient of R2 = 0.86. This indicates that the sensitivity of the LIF instrument is well-defined by its calibration procedure. No hints for artifacts are observed for isoprene, MACR, and different aromatic compounds. LIF measurements were approximately 30–40% (median larger than those by DOAS after MVK (20 ppbv and

  4. Comparison of OH concentration measurements by DOAS and LIF during SAPHIR chamber experiments at high OH reactivity and low NO concentration

    Science.gov (United States)

    Fuchs, H.; Dorn, H.-P.; Bachner, M.; Bohn, B.; Brauers, T.; Gomm, S.; Hofzumahaus, A.; Holland, F.; Nehr, S.; Rohrer, F.; Tillmann, R.; Wahner, A.

    2012-07-01

    During recent field campaigns, hydroxyl radical (OH) concentrations that were measured by laser-induced fluorescence (LIF) were up to a factor of ten larger than predicted by current chemical models for conditions of high OH reactivity and low NO concentration. These discrepancies, which were observed in forests and urban-influenced rural environments, are so far not entirely understood. In summer 2011, a series of experiments was carried out in the atmosphere simulation chamber SAPHIR in Jülich, Germany, in order to investigate the photochemical degradation of isoprene, methyl-vinyl ketone (MVK), methacrolein (MACR) and aromatic compounds by OH. Conditions were similar to those experienced during the PRIDE-PRD2006 campaign in the Pearl River Delta (PRD), China, in 2006, where a large difference between OH measurements and model predictions was found. During experiments in SAPHIR, OH was simultaneously detected by two independent instruments: LIF and differential optical absorption spectroscopy (DOAS). Because DOAS is an inherently calibration-free technique, DOAS measurements are regarded as a reference standard. The comparison of the two techniques was used to investigate potential artifacts in the LIF measurements for PRD-like conditions of OH reactivities of 10 to 30 s-1 and NO mixing ratios of 0.1 to 0.3 ppbv. The analysis of twenty experiment days shows good agreement. The linear regression of the combined data set (averaged to the DOAS time resolution, 2495 data points) yields a slope of 1.02 ± 0.01 with an intercept of (0.10 ± 0.03) × 106 cm-3 and a linear correlation coefficient of R2 = 0.86. This indicates that the sensitivity of the LIF instrument is well-defined by its calibration procedure. No hints for artifacts are observed for isoprene, MACR, and different aromatic compounds. LIF measurements were approximately 30-40% (median) larger than those by DOAS after MVK (20 ppbv) and toluene (90 ppbv) had been added. However, this discrepancy has a

  5. The CU 2-D-MAX-DOAS instrument - Part 2: Raman scattering probability measurements and retrieval of aerosol optical properties

    Science.gov (United States)

    Ortega, Ivan; Coburn, Sean; Berg, Larry K.; Lantz, Kathy; Michalsky, Joseph; Ferrare, Richard A.; Hair, Johnathan W.; Hostetler, Chris A.; Volkamer, Rainer

    2016-08-01

    The multiannual global mean of aerosol optical depth at 550 nm (AOD550) over land is ˜ 0.19, and that over oceans is ˜ 0.13. About 45 % of the Earth surface shows AOD550 smaller than 0.1. There is a need for measurement techniques that are optimized to measure aerosol optical properties under low AOD conditions. We present an inherently calibrated retrieval (i.e., no need for radiance calibration) to simultaneously measure AOD and the aerosol phase function parameter, g, based on measurements of azimuth distributions of the Raman scattering probability (RSP), the near-absolute rotational Raman scattering (RRS) intensity. We employ radiative transfer model simulations to show that for solar azimuth RSP measurements at solar elevation and solar zenith angle (SZA) smaller than 80°, RSP is insensitive to the vertical distribution of aerosols and maximally sensitive to changes in AOD and g under near-molecular scattering conditions. The University of Colorado two-dimensional Multi-AXis Differential Optical Absorption Spectroscopy (CU 2-D-MAX-DOAS) instrument was deployed as part of the Two Column Aerosol Project (TCAP) at Cape Cod, MA, during the summer of 2012 to measure direct sun spectra and RSP from scattered light spectra at solar relative azimuth angles (SRAAs) between 5 and 170°. During two case study days with (1) high aerosol load (17 July, 0.3 CIMEL sun photometer, Multi-Filter Rotating Shadowband Radiometer (MFRSR), and an airborne High Spectral Resolution Lidar (HSRL-2). The average difference (relative to DOAS) for AOD430 is +0.012 ± 0.023 (CIMEL), -0.012 ± 0.024 (MFRSR), -0.011 ± 0.014 (HSRL-2), and +0.023 ± 0.013 (CIMELAOD - MFRSRAOD) and yields the following expressions for correlations between different instruments: DOASAOD = -(0.019 ± 0.006) + (1.03 ± 0.02) × CIMELAOD (R2 = 0.98), DOASAOD = -(0.006 ± 0.005) + (1.08 ± 0.02) × MFRSRAOD (R2 = 0.98), and CIMELAOD = (0.013 ± 0.004) + (1.05 ± 0.01)

  6. Simultaneous retrieval of aerosol and surface optical properties from combined airborne- and ground-based direct and diffuse radiometric measurements

    Directory of Open Access Journals (Sweden)

    C. K. Gatebe

    2009-12-01

    Full Text Available This paper presents a new method for simultaneously retrieving aerosol and surface reflectance properties from combined airborne and ground-based direct and diffuse radiometric measurements. The method is based on the standard Aerosol Robotic Network (AERONET method for retrieving aerosol size distribution, complex index of refraction, and single scattering albedo, but modified to retrieve aerosol properties in two layers, below and above the aircraft, and parameters on surface optical properties from combined datasets (Cloud Absorption Radiometer, CAR, and AERONET data. A key advantage of this method is the inversion of all available spectral and angular data at the same time, while accounting for the influence of noise in the inversion procedure using statistical optimization. The wide spectral (0.34–2.30 μm and angular range (180° of the CAR instrument, combined with observations from an AERONET sunphotometer, provide sufficient measurement constraints for characterizing aerosol and surface properties with minimal assumptions. The robustness of the method was tested on observations made during four different field campaigns: (a the Southern African Regional Science Initiative 2000 over Mongu, Zambia, (b the Intercontinental Transport Experiment-Phase B over Mexico City, Mexico (c Cloud and Land Surface Interaction Campaign over the Atmospheric Radiation Measurement (ARM Central Facility, Oklahoma, USA, and (d the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS over Elson Lagoon in Barrow, Alaska, USA. The four areas are dominated by different surface characteristics and aerosol types, and therefore provide good test cases for the new inversion method.

  7. A new ground-based differential absorption sunphotometer for measuring atmospheric columnar CO2 and preliminary applications

    Science.gov (United States)

    Xie, Yisong; Li, Zhengqiang; Zhang, Xingying; Xu, Hua; Li, Donghui; Li, Kaitao

    2015-10-01

    Carbon dioxide is commonly considered as the most important greenhouse gas. Ground-based remote sensing technology of acquiring CO2 columnar concentration is needed to provide validation for spaceborne CO2 products. A new groundbased sunphotometer prototype for remotely measuring atmospheric CO2 is introduced in this paper, which is designed to be robust, portable, automatic and suitable for field observation. A simple quantity, Differential Absorption Index (DAI) related to CO2 optical depth, is proposed to derive the columnar CO2 information based on the differential absorption principle around 1.57 micron. Another sun/sky radiometer CE318, is used to provide correction parameters of aerosol extinction and water vapor absorption. A cloud screening method based on the measurement stability is developed. A systematic error assessment of the prototype and DAI is also performed. We collect two-year DAI observation from 2010 to 2012 in Beijing, analyze the DAI seasonal variation and find that the daily average DAI decreases in growing season and reaches to a minimum on August, while increases after that until January of the next year, when DAI reaches its highest peak, showing generally the seasonal cycle of CO2. We also investigate the seasonal differences of DAI variation and attribute the tendencies of high in the morning and evening while low in the noon to photosynthesis efficiency variation of vegetation and anthropogenic emissions. Preliminary comparison between DAI and model simulated XCO2 (Carbon Tracker 2011) is conducted, showing that DAI roughly reveals some temporal characteristics of CO2 when using the average of multiple measurements.

  8. Simultaneous retrieval of aerosol and surface optical properties from combined airborne- and ground-based direct and diffuse radiometric measurements

    Directory of Open Access Journals (Sweden)

    C. K. Gatebe

    2010-03-01

    Full Text Available This paper presents a new method for simultaneously retrieving aerosol and surface reflectance properties from combined airborne and ground-based direct and diffuse radiometric measurements. The method is based on the standard Aerosol Robotic Network (AERONET method for retrieving aerosol size distribution, complex index of refraction, and single scattering albedo, but modified to retrieve aerosol properties in two layers, below and above the aircraft, and parameters on surface optical properties from combined datasets (Cloud Absorption Radiometer (CAR and AERONET data. A key advantage of this method is the inversion of all available spectral and angular data at the same time, while accounting for the influence of noise in the inversion procedure using statistical optimization. The wide spectral (0.34–2.30 μm and angular range (180° of the CAR instrument, combined with observations from an AERONET sunphotometer, provide sufficient measurement constraints for characterizing aerosol and surface properties with minimal assumptions. The robustness of the method was tested on observations made during four different field campaigns: (a the Southern African Regional Science Initiative 2000 over Mongu, Zambia, (b the Intercontinental Transport Experiment-Phase B over Mexico City, Mexico (c Cloud and Land Surface Interaction Campaign over the Atmospheric Radiation Measurement (ARM Central Facility, Oklahoma, USA, and (d the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS over Elson Lagoon in Barrow, Alaska, USA. The four areas are dominated by different surface characteristics and aerosol types, and therefore provide good test cases for the new inversion method.

  9. Vertical Profiles of SO2 and NO2 in the Alberta Oil Sands: MAX-DOAS Measurements and Comparison to in-situ Instrumentation

    Science.gov (United States)

    Davis, Zoe; Lobo, Akshay; McLaren, Robert

    2015-04-01

    Understanding the levels of industrially emitted gas pollutants in the Alberta oil sands is essential to making quality environmental management decisions but is currently limited due to scarcity of top-down quantification studies. Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements of nitrogen dioxide (NO2) and sulfur dioxide (SO2) , important tropospheric trace gas pollutants, contributes to improved knowledge of these pollutants' levels, vertical distributions and chemical transformations. A mini-MAX-DOAS instrument measured spectra at multiple viewing elevation angles in order to retrieve NO2 and SO2 differential slant column densities (dSCDs) at an Environment Canada research site north of Fort McMurray, Alberta in the fall of 2013. For the first time in the oil sands, tropospheric vertical profiles of NO2 and SO2 were retrieved by applying the optimal estimation technique to the MAX-DOAS measurements. The DOAS fit retrievals of SO2 dSCDs were validated by comparison with retrievals obtained with a quartz calibration cell with known SO2 SCD placed in front of the MAX-DOAS telescope at multiple elevation angles on a clean day. Retrieved SO2 dSCDs varied significantly from the true value depending on the chosen wavelength fitting interval. At the lowest wavelength intervals, interference by stray light and O3 differential structures significantly reduced dSCDs and caused an elevation angle dependence. These results indicate that MAX-DOAS dSCD retrieval settings, particularly for weak absorbers with differential absorption structures in low-intensity spectral regions, must be chosen carefully in order to achieve the most accurate results. Tropospheric vertical column densities (VCDs) and vertical profile retrievals of NO2, SO2 and aerosol extinction during significant pollution events will be illustrated. Trace gas vertical profiles exhibited significant variability between days and at different times of day and were often spatially

  10. Mapping the bathymetry of a turbid, sand-bed river using ground-based reflectance measurements and hyperspectral image data

    Science.gov (United States)

    Legleiter, C. J.; Kinzel, P. J.; Nelson, J. M.

    2010-12-01

    The Platte River in central Nebraska encompasses relatively stable, single-thread to island-braided reaches as well as wider, fully braided segments with highly mobile bar forms. Across this range of morphologies, suspended sediment and organic material contribute to turbid water conditions. In addition, the Platte is the focus of management activities intended to mitigate encroachment of vegetation and improve habitat for various migratory bird species, primarily by increasing the areal extent of shallow to slightly emergent mid-channel sand bars. The diversity of channel types and optical properties make this a challenging environment in which to implement a remote sensing approach, but the Platte also provides an opportunity for these methods to support management objectives. To evaluate the potential utility of remote sensing techniques along the Platte, we acquired hyperspectral image data, collected field spectra, and surveyed bed topography for three reaches. Ground-based measurements of reflectance Rλ were made above the water surface for flow depths d from 5 - 67 cm and a range of substrate types. An optimal band ratio analysis (OBRA) of these data, whereby regressions of log-transformed band ratios against measured depths were performed for all possible band combinations, yielded a strong, linear relationship (R2 = 0.95) between ln ({R593}/{R{647}) and d. Similar band ratio analyses were performed using reflectance spectra extracted from the hyperspectral image data for locations at which bed elevations were surveyed and compared to measured water surface elevations to calculate flow depths. Image-based OBRA produced variable results for the three sites. For a narrower, deeper reach lacking mobile mid-channel bars, a ln ({R490}/{R{638}) vs. d relation had an R2 of 0.83; applying this expression to the image generated a bathymetric map that agreed closely with our survey data. The other two sites featured fully braided morphologies, shallower depths, and

  11. Three methods to retrieve slant total electron content measurements from ground-based GPS receivers and performance assessment

    Science.gov (United States)

    Zhang, Baocheng

    2016-07-01

    The high sampling rate along with the global coverage of ground-based receivers makes Global Positioning System (GPS) data particularly ideal for sensing the Earth's ionosphere. Retrieval of slant total electron content measurements (TECMs) constitutes a key first step toward extracting various ionospheric parameters from GPS data. Within the ionospheric community, the interpretation of TECM is widely recognized as the slant total electron content along the satellite receiver line of sight, biased by satellite and receiver differential code biases (DCBs). The Carrier-to-Code Leveling (CCL) has long been used as a geometry-free method for retrieving TECM, mainly because of its simplicity and effectiveness. In fact, however, the CCL has proven inaccurate as it may give rise to TECM very susceptible to so-called leveling errors. With the goal of attaining more accurate TECM retrieval, we report in this contribution two other methods than the CCL, namely, the Precise Point Positioning (PPP) and the Array-aided PPP (A-PPP). The PPP further exploits the International GPS Service (IGS) orbit and clock products and turns out to be a geometry-based method. The A-PPP is designed to retrieve TECM from an array of colocated receivers, taking advantage of the broadcast orbit and clock products. Moreover, A-PPP also takes into account the fact that the ionospheric effects measured from one satellite to all colocated receivers ought to be the same, thus leading to the estimability of interreceiver DCB. We perform a comparative study of the formal precision and the empirical accuracy of the TECM that are retrieved, respectively, by three methods from the same set of GPS data. Results of such a study can be used to assess the actual performance of the three methods. In addition, we check the temporal stability in A-PPP-derived interreceiver DCB estimates over time periods ranging from 1 to 3 days.

  12. All satellites total ozone evaluation in the tropics by comparison with SAOZ-NDACC ground-based measurements

    Science.gov (United States)

    Pommereau, Jean-Pierre; Lerot, Christophe; Van Roozendael, Michel; Goutail, Florence; Pazmino, Andrea; Frihi, Aymen; Bekki, Slimane; Clerbaux, Cathy

    2016-07-01

    All satellites total ozone measurements available from SBUV, OMI-T, OMI-D, OMI-CCI, GOME-CCI, GOME2-CCI, SCIAMACHY-CCI, NPP and IASI, since 2001 until 2015 are compared to those provided by the UV-Vis SAOZ/NDACC spectrometer at the two tropical stations of Reunion Island in the Indian Ocean and Bauru in Southern Brazil. The differences between satellites and SAOZ except IASI do show systematic seasonal variations of 0-3% (0-9 DU) amplitude and sharp negative peaks in Jan-Mar in Reunion Is in the austral summer. Whereas the summer negative peaks seen particularly on IASI, OMI-T, NPP and OMI-CCI at Reunion are shown to correlate with hurricanes and those seen in Brazil with high altitude overshooting convective clouds both not properly removed, ozone minima outside these events are shown to correlate with high altitude volcanic plumes impacting all satellites as well as ground-based total ozone measurements The seasonality of the Sat-SAOZ difference of varying amplitude from 0 to 3% with the satellite is attributed to the satellite retrieval. Surprisingly and though there has been no change in either SAOZ instruments or data analysis processes, the amplitude of the seasonal cycle of the Sat-SAOZ difference reduces in 2012 and drops to less than ± 0.5% (1.5 DU) after 2013 in Reunion Island and less than ±1% in Bauru, reduction for which there is no clear explanation yet. Shown in the presentation will be the demonstration of the impact of hurricanes, high altitude convective clouds and volcanic plumes on satellites total ozone retrievals, followed by a discussion of possible causes of seasonality of Sat-SAOZ amplitude drop after 2012.

  13. Pi-MAX: a new parametrized algorithm to retrieve vertical profiles of trace gases and aerosols from MAX-DOAS measurements

    Science.gov (United States)

    Remmers, Julia; Beirle, Steffen; Doerner, Steffen; Wagner, Thomas

    2013-04-01

    Multi-Axis (MAX-) DOAS instruments observe scattered sunlight under various mostly slant elevation angles. From such observations information on tropospheric profiles of trace gases and aerosols can be retrieved. MAX-DOAS observations can be used to quantify emissions and to study chemical processes in the atmosphere. Measuring (horizontally and vertically) averaged concentrations the technique can be used as a link between in-situ and satellite measurements. Thus satellite observations of tropospheric trace gases can be validated. IMAX (Parametrized Inversion for MAX-DOAS measurements) is a parametrized method to retrieve vertical profiles of trace gases (such as H2O, NO2, HCHO, CHOCHO) and aerosols. No online calculations are necessary, since look-up tables (LUT) calculated with a Monte Carlo based radiative Transport Model are used. In this manner it is user-friendly, easy to distribute and applicable to every measurement location. The here shown measurements took place in the Maldives in March, 2012, during the CARDEX campaign. Simultaneous sun photometry-, Lidar- and UAV-measurements provide the possibility to validate the new algorithm. We present time series of profiles of trace gas concentrations and aerosol extinction We discuss the effects of clouds on the retrieved results.

  14. First middle-atmospheric zonal wind profile measurements with a new ground-based microwave Doppler-spectro-radiometer

    Directory of Open Access Journals (Sweden)

    R. Rüfenacht

    2012-11-01

    Full Text Available We report on the wind radiometer WIRA, a new ground-based microwave Doppler-spectro-radiometer specifically designed for the measurement of middle-atmospheric horizontal wind by observing ozone emission spectra at 142.17504 GHz. Currently, wind speeds in five levels between 30 and 79 km can be retrieved which makes WIRA the first instrument able to continuously measure horizontal wind in this altitude range. For an integration time of one day the measurement error on each level lies at around 25 m s−1. With a planned upgrade this value is expected to be reduced by a factor of 2 in the near future. On the altitude levels where our measurement can be compared to wind data from the European Centre for Medium-Range Weather Forecasts (ECMWF very good agreement in the long-term statistics as well as in short time structures with a duration of a few days has been found.

    WIRA uses a passive double sideband heterodyne receiver together with a digital Fourier transform spectrometer for the data acquisition. A big advantage of the radiometric approach is that such instruments can also operate under adverse weather conditions and thus provide a continuous time series for the given location. The optics enables the instrument to scan a wide range of azimuth angles including the directions east, west, north, and south for zonal and meridional wind measurements. The design of the radiometer is fairly compact and its calibration does not rely on liquid nitrogen which makes it transportable and suitable for campaign use. WIRA is conceived in a way that it can be operated remotely and does hardly require any maintenance.

    In the present paper, a description of the instrument is given, and the techniques used for the wind retrieval based on the determination of the Doppler shift of the measured atmospheric ozone emission spectra are outlined. Their reliability was tested using Monte Carlo simulations. Finally, a time series of 11

  15. Question No. 5: What Role Can Satellites Take, as a Complement to Ground Based Measurement Systems, to Provide Sustained Observations to Monitor GHG Emissions?

    Science.gov (United States)

    Chahine, Moustafa; Olsen, Edward

    2011-01-01

    What role can satellites take, as a complement to ground based measurement systems, to provide sustained observations to monitor GHG emissions (e.g., CO2, CH4, O3, N2O, CFC s, NH3, and NF3) that contribute to global warming?

  16. Absolute calibration of the colour index and O4 absorption derived from Multi AXis (MAX-)DOAS measurements and their application to a standardised cloud classification algorithm

    Science.gov (United States)

    Wagner, Thomas; Beirle, Steffen; Remmers, Julia; Shaiganfar, Reza; Wang, Yang

    2016-09-01

    A method is developed for the calibration of the colour index (CI) and the O4 absorption derived from differential optical absorption spectroscopy (DOAS) measurements of scattered sunlight. The method is based on the comparison of measurements and radiative transfer simulations for well-defined atmospheric conditions and viewing geometries. Calibrated measurements of the CI and the O4 absorption are important for the detection and classification of clouds from MAX-DOAS observations. Such information is needed for the identification and correction of the cloud influence on Multi AXis (MAX-)DOAS profile inversion results, but might be also be of interest on their own, e.g. for meteorological applications. The calibration algorithm was successfully applied to measurements at two locations: Cabauw in the Netherlands and Wuxi in China. We used CI and O4 observations calibrated by the new method as input for our recently developed cloud classification scheme and also adapted the corresponding threshold values accordingly. For the observations at Cabauw, good agreement is found with the results of the original algorithm. Together with the calibration procedure of the CI and O4 absorption, the cloud classification scheme, which has been tuned to specific locations/conditions so far, can now be applied consistently to MAX-DOAS measurements at different locations. In addition to the new threshold values, further improvements were introduced to the cloud classification algorithm, namely a better description of the SZA (solar zenith angle) dependence of the threshold values and a new set of wavelengths for the determination of the CI. We also indicate specific areas for future research to further improve the cloud classification scheme.

  17. Development and characterization of the CU ground MAX-DOAS instrument: lowering RMS noise and first measurements of BrO, IO, and CHOCHO near Pensacola, FL

    Science.gov (United States)

    Coburn, S.; Dix, B.; Sinreich, R.; Volkamer, R.

    2011-01-01

    We designed and assembled the University of Colorado Ground Multi AXis Differential Optical Absorption Spectroscopy (CU GMAX-DOAS) instrument to retrieve bromine oxide (BrO), iodine oxide (IO), formaldehyde (HCHO), glyoxal (CHOCHO), nitrogen dioxide (NO2) and the oxygen dimer O4 in the coastal atmosphere of the Gulf of Mexico. The detection sensitivity of DOAS measurements is directly proportional to the root mean square (RMS) of the residual spectrum that remains after all absorbers have been subtracted. Here we describe the CU GMAX-DOAS instrument and demonstrate that the hardware is capable of attaining RMS values of ~6 × 10-6 without apparent limitations other than photon shot noise. Laboratory tests revealed two factors that, in practice, limit the RMS: (1) detector non-linearity noise, RMSNLin, and (2) temperature fluctuations that cause variations in optical resolution (full width at half the maximum, FWHM, of atomic emission lines) and give rise to optical resolution noise, RMSFWHM. The non-linearity of our detector is low (~10-3) yet - unless actively controlled - is sufficiently large to create a RMSNLin limit of up to 1.4 × 10-4. The optical resolution is sensitive to temperature changes (0.03 detector pixels/°C at 334 nm), and temperature variations of 0.1 °C can cause residual RMSFWHM of ~1 × 10-4. Both factors were actively addressed in the design of the CU GMAX-DOAS instrument. The CU GMAX-DOAS was set up at a coastal site near Pensacola, FL, where we detected BrO, IO and CHOCHO in the marine boundary layer (MBL), with daytime average tropospheric vertical column densities, VCDs, of ~2 × 1013 molec cm-2, 8 × 1012 molec cm-2 and 4 × 1014 molec cm-2, respectively. HCHO and NO2 were also detected with typical MBL VCDs of 1 × 1016 and 3 × 1015. These are the first measurements of BrO, IO and CHOCHO over the Gulf of Mexico. The atmospheric implications of these observations for elevated mercury wet deposition rates in this area are briefly

  18. Ground-Based Lidar Measurements of Forest Canopy Structure as Predictors of Net Primary Production Across Successional Time

    Science.gov (United States)

    Scheuermann, C. M.; Gough, C. M.; Nave, L. E.

    2015-12-01

    Forest canopy structure is a key predictor of gas exchange processes that control carbon (C) uptake, including the allocation of photosynthetically fixed C to new plant biomass growth, or net primary production (NPP). Prior work suggests forest canopy structural complexity (CSC), the arrangement of leaves within a volume of canopy, changes as forests develop and is a strong predictor of NPP. However, the expressions of CSC that best predict NPP over decadal to century timescales is unknown. Our objectives were to use multiple remote sensing observations to characterize forest canopy structure in increasing dimensional complexity over a forest age gradient, and to identify which expressions of physical structure best served as proxies of NPP. The study at the University of Michigan Biological Station in Pellston, MI, USA uses two parallel forest chronosequences with different harvesting and fire disturbance histories and includes three old-growth ecosystems varying in canopy composition. We have derived several expressions of 2-D and 3-D forest canopy structure from hemispherical images, a ground-based portable canopy lidar (PCL), and a 3-D terrestrial lidar scanner (TLS), and are relating these structural metrics with NPP and light and nitrogen allocation within the canopy. Preliminary analysis shows that old-growth stands converged on a common mean CSC, but with substantially higher within-stand variation in complexity as deciduous tree species increased in forest canopy dominance. Forest stands that were more intensely disturbed were slower to recover leaf area index (LAI) as they regrew, but 2-D measures of CSC increased similarly as forests aged, regardless of disturbance history. Ongoing work will relate long-term trends in forest CSC with NPP and resource allocation to determine which forest structure remote sensing products are most useful for modeling and scaling C cycling processes through different stages of forest development.

  19. Retrieval of aerosol optical and physical properties from ground-based measurements for Zanjan, a city in Northwest Iran

    Science.gov (United States)

    Masoumi, A.; Khalesifard, H. R.; Bayat, A.; Moradhaseli, R.

    2013-02-01

    A ground-based sun and sky scanning radiometer, CIMEL CE 318-2 sunphotometer, has been used to study the atmosphere of Zanjan, a city in Northwest Iran (36.70°N, 48.51°E, and 1800 m above the mean sea level) in the periods of October 2006-October 2008, and January-September 2010. Direct sun and solar principal plane sky radiance measurements by the sunphotometer have been used to retrieve the optical and physical properties of atmospheric aerosols, such as aerosol optical depth (AOD), Ångström exponent (α), single scattering albedo (SSA), refractive index, and volume size distributions. About 50 dusty days (daily averaged AOD (870) > 0.35, α < 0.5) have been recorded during the mentioned periods. Considering the different values obtained for SSA, real part of refractive index, and volume size distributions, it has been found that just dust and anthropogenic aerosols are making the atmospheric aerosols in this region. In these recordings it has been observed that AODs (Ångström exponents) were increasing (decreasing) during spring and early summer. This was accompanied by increase of SSA, real part of refractive index, and coarse mode part of volume size distributions of aerosols. This behavior could be due to transport of dust, mostly from Tigris-Euphrates basin or sometimes with lower probability from the region between Caspian and Aral seas and rarely from sources inside the Iran plateau like the Qom dry lake, especially in dry seasons. In this work NCEP/NCAR reanalysis, HYSPLIT model back trajectories, and MODIS Deep Blue AODs have been used to track the air masses and dust plumes during the recorded dust events.

  20. A Ground-based Measurement of the Relativistic Beaming Effect in a Detached Double White Dwarf Binary

    Science.gov (United States)

    Shporer, Avi; Kaplan, David L.; Steinfadt, Justin D. R.; Bildsten, Lars; Howell, Steve B.; Mazeh, Tsevi

    2010-12-01

    We report on the first ground-based measurement of the relativistic beaming effect (aka Doppler boosting). We observed the beaming effect in the detached, non-interacting eclipsing double white dwarf (WD) binary NLTT 11748. Our observations were motivated by the system's high mass-ratio and low-luminosity ratio, leading to a large beaming-induced variability amplitude at the orbital period of 5.6 hr. We observed the system during three nights at the 2.0 m Faulkes Telescope North with the SDSS-g' filter and fitted the data simultaneously for the beaming, ellipsoidal, and reflection effects. Our fitted relative beaming amplitude is (3.0 ± 0.4) × 10-3, consistent with the expected amplitude from a blackbody spectrum given the photometric primary radial velocity (RV) amplitude and effective temperature. This result is a first step in testing the relation between the photometric beaming amplitude and the spectroscopic RV amplitude in NLTT 11748 and similar systems. We did not identify any variability due to the ellipsoidal or reflection effects, consistent with their expected undetectable amplitude for this system. Low-mass, helium-core WDs are expected to reside in binary systems, where in some of those systems the binary companion is a faint C/O WD and the two stars are detached and non-interacting, as in the case of NLTT 11748. The beaming effect can be used to search for the faint binary companion in those systems using wide-band photometry.

  1. A compact ground-based laser heterodyne radiometer for global column measurements of CO2 and CH4

    Science.gov (United States)

    Steel, Emily; Clarke, Gregory; Ramanathan, Anand; Mao, Jianping; Ott, Lesley; Duncan, Bryan; Melroy, Hilary; McLinden, Matthew; Holben, Brent; Houston Miller, J.

    2015-04-01

    Implementing effective global strategies to understand climate change is hindered by a lack of understanding of both anthropogenic emissions and land and ocean carbon reservoirs. Though in situ surface measurements and satellites provide valuable information for estimating carbon fluxes, areas not well covered by current observing systems (e.g. high latitude regions, tropical forests and wetlands) remain poorly understood. Deficiencies in understanding the processes governing carbon flux introduce considerable uncertainty to predictions of climate change over the coming century. Our vision is to enhance worldwide carbon monitoring by developing a low-cost ground network of miniaturized laser heterodyne radiometer (Mini-LHR) instruments that measure CO2 and CH4 in the atmospheric column. Ground-based remote sensing has the potential to fill gaps in the satellite data record while providing a complementary long-term observational record. This uninterrupted data record, would both bridge gaps in data sets and offer validation for key flight missions such as OCO-2, OCO-3 and ASCENDS. Mini-LHR instruments will be deployed as an accompaniment to AERONET. In addition to the complementary aerosol optical depth measurement, tandem operation with AERONET provides a clear pathway for the Mini-LHR to be expanded into a global monitoring network. AERONET has more than 500 instruments worldwide offering coverage in key arctic regions (not covered by OCO-2) where accelerated warming due to the release of CO2 and CH4 from thawing tundra and permafrost is a concern. Mini-LHR instruments at AERONET locations could also greatly improve data coverage in regions with large flux uncertainties such as North America and Western Europe, and under-sampled areas such as South America and Asia. Currently, the only ground global network that routinely measures multiple greenhouse gases in the atmospheric column is TCCON with 18 operational sites worldwide and two in the US. Cost and size of

  2. Ground-based measurements of tropospheric and stratospheric bromine monoxide above Nairobi (1° S, 36° E

    Directory of Open Access Journals (Sweden)

    M. van Roozendael

    2007-05-01

    Full Text Available Ground based observations of stratospheric and tropospheric bromine monoxide, BrO, from a multi axial differential optical absorption spectrometer, MAXDOAS, located at the UNEP/UNON site in Nairobi (1° S, 36° E are presented for the year 2003. Differences in BrO slant column densities at 90° and 80° solar zenith angle retrieved from the zenith-sky measurements are used to study stratospheric BrO. They show only small variations with season, as expected for the small seasonality in stratospheric Bry and NO2 in this region. A pronounced diurnal variation can be observed, the average value for the morning being 1.3×1014 molecules/cm2 and for the evening 1.5×1014 molecules/cm2. The measurements are compared with simulations from a one-dimensional photochemical stacked box model which is coupled with a radiative transfer model to allow direct comparisons between the observations and the model calculations. In general the model reproduces the measurements very well. The differences in the absolute values are 15% for the evening and 20% for the morning which is within the limits of the combined uncertainties. Both seasonality and diurnal variation are well reproduced by the model. A sensitivity study shows that inclusion of the reaction BrONO2 + O(3P significantly improves the agreement between model calculations and measurements, indicating an important role of this reaction in the stratosphere near to the equator. Tropospheric BrO columns and profile information is derived from the combined results obtained in the different viewing directions for the average over several clear days. The resulting tropospheric BrO columns are in the range of 4–7.5×1012 molecules/cm2 which is significant but lower than in previous studies at mid and high latitudes. The vertical distribution of the tropospheric BrO peaks at about 3 km indicating the absence of local sources at this high altitude site.

  3. Inferring hydroxyl layer peak heights from ground-based measurements of OH(6-2 band integrated emission rate at Longyearbyen (78° N, 16° E

    Directory of Open Access Journals (Sweden)

    F. Sigernes

    2009-11-01

    Full Text Available Measurements of hydroxyl nightglow emissions over Longyearbyen (78° N, 16° E recorded simultaneously by the SABER instrument onboard the TIMED satellite and a ground-based Ebert-Fastie spectrometer have been used to derive an empirical formula for the height of the OH layer as a function of the integrated emission rate (IER. Altitude profiles of the OH volume emission rate (VER derived from SABER observations over a period of more than six years provided a relation between the height of the OH layer peak and the integrated emission rate following the procedure described by Liu and Shepherd (2006. An extended period of overlap of SABER and ground-based spectrometer measurements of OH(6-2 IER during the 2003–2004 winter season allowed us to express ground-based IER values in terms of their satellite equivalents. The combination of these two formulae provided a method for inferring an altitude of the OH emission layer over Longyearbyen from ground-based measurements alone. Such a method is required when SABER is in a southward looking yaw cycle. In the SABER data for the period 2002–2008, the peak altitude of the OH layer ranged from a minimum near 76 km to a maximum near 90 km. The uncertainty in the inferred altitude of the peak emission, which includes a contribution for atmospheric extinction, was estimated to be ±2.7 km and is comparable with the ±2.6 km value quoted for the nominal altitude (87 km of the OH layer. Longer periods of overlap of satellite and ground-based measurements together with simultaneous on-site measurements of atmospheric extinction could reduce the uncertainty to approximately 2 km.

  4. Calibration and evaluation of CCD spectroradiometers for ground-based and airborne measurements of spectral actinic flux densities

    Science.gov (United States)

    Bohn, Birger; Lohse, Insa

    2017-09-01

    The properties and performance of charge-coupled device (CCD) array spectroradiometers for the measurement of atmospheric spectral actinic flux densities (280-650 nm) and photolysis frequencies were investigated. These instruments are widely used in atmospheric research and are suitable for aircraft applications because of high time resolutions and high sensitivities in the UV range. The laboratory characterization included instrument-specific properties like the wavelength accuracy, dark signal, dark noise and signal-to-noise ratio (SNR). Spectral sensitivities were derived from measurements with spectral irradiance standards. The calibration procedure is described in detail, and a straightforward method to minimize the influence of stray light on spectral sensitivities is introduced. From instrument dark noise, minimum detection limits ≈ 1 × 1010 cm-2 s-1 nm-1 were derived for spectral actinic flux densities at wavelengths around 300 nm (1 s integration time). As a prerequisite for the determination of stray light under field conditions, atmospheric cutoff wavelengths were defined using radiative transfer calculations as a function of the solar zenith angle (SZA) and total ozone column (TOC). The recommended analysis of field data relies on these cutoff wavelengths and is also described in detail taking data from a research flight on HALO (High Altitude and Long Range Research Aircraft) as an example. An evaluation of field data was performed by ground-based comparisons with a double-monochromator-based, highly sensitive reference spectroradiometer. Spectral actinic flux densities were compared as well as photolysis frequencies j(NO2) and j(O1D), representing UV-A and UV-B ranges, respectively. The spectra expectedly revealed increased daytime levels of stray-light-induced signals and noise below atmospheric cutoff wavelengths. The influence of instrument noise and stray-light-induced noise was found to be insignificant for j(NO2) and rather limited for j(O1D

  5. Inherent calibration of a novel LED-CE-DOAS instrument to measure iodine oxide, glyoxal, methyl glyoxal, nitrogen dioxide, water vapour and aerosol extinction in open cavity mode

    Science.gov (United States)

    Thalman, R.; Volkamer, R.

    2010-06-01

    The combination of Cavity Enhanced Absorption Spectroscopy (CEAS) with broad-band light sources (e.g. Light-Emitting Diodes, LEDs) lends itself to the application of cavity enhanced Differential Optical Absorption Spectroscopy (CE-DOAS) to perform sensitive and selective point measurements of multiple trace gases and aerosol extinction with a single instrument. In contrast to other broad-band CEAS techniques, CE-DOAS relies only on the measurement of relative intensity changes, i.e. does not require knowledge of the light intensity in the absence of trace gases and aerosols (I0). We have built a prototype LED-CE-DOAS instrument in the blue spectral range (420-490 nm) to measure nitrogen dioxide (NO2), glyoxal (CHOCHO), methyl glyoxal (CH3COCHO), iodine oxide (IO), water vapour (H2O) and oxygen dimers (O4). We demonstrate the first CEAS detection of methyl glyoxal, and the first CE-DOAS detection of CHOCHO and IO. A further innovation consists in the measurement of extinction losses from the cavity, e.g. due to aerosols, at two wavelengths by observing O4 (477 nm) and H2O (443 nm) and measuring the pressure, relative humidity and temperature independently. This approach is demonstrated by experiments where laboratory aerosols of known size and refractive index were generated and their extinction measured. The measured extinctions were then compared to the theoretical extinctions calculated using Mie theory (3-7×10-7 cm-1). Excellent agreement is found from both the O4 and H2O retrievals. This enables the first inherently calibrated CEAS measurement in open cavity mode (mirrors facing the open atmosphere), and eliminates the need for sampling lines to supply air to the cavity, and/or keep the cavity enclosed and aerosol free. Measurements in open cavity mode are demonstrated for CHOCHO, CH3COCHO, NO2, H2O and aerosol extinction at 477 nm and 443 nm. Our prototype LED-CE-DOAS provides a low cost, yet research grade innovative instrument for applications in simulation

  6. Inherent calibration of a novel LED-CE-DOAS instrument to measure iodine oxide, glyoxal, methyl glyoxal, nitrogen dioxide, water vapour and aerosol extinction in open cavity mode

    Directory of Open Access Journals (Sweden)

    R. Thalman

    2010-06-01

    Full Text Available The combination of Cavity Enhanced Absorption Spectroscopy (CEAS with broad-band light sources (e.g. Light-Emitting Diodes, LEDs lends itself to the application of cavity enhanced Differential Optical Absorption Spectroscopy (CE-DOAS to perform sensitive and selective point measurements of multiple trace gases and aerosol extinction with a single instrument. In contrast to other broad-band CEAS techniques, CE-DOAS relies only on the measurement of relative intensity changes, i.e. does not require knowledge of the light intensity in the absence of trace gases and aerosols (I0. We have built a prototype LED-CE-DOAS instrument in the blue spectral range (420–490 nm to measure nitrogen dioxide (NO2, glyoxal (CHOCHO, methyl glyoxal (CH3COCHO, iodine oxide (IO, water vapour (H2O and oxygen dimers (O4. We demonstrate the first CEAS detection of methyl glyoxal, and the first CE-DOAS detection of CHOCHO and IO. A further innovation consists in the measurement of extinction losses from the cavity, e.g. due to aerosols, at two wavelengths by observing O4 (477 nm and H2O (443 nm and measuring the pressure, relative humidity and temperature independently. This approach is demonstrated by experiments where laboratory aerosols of known size and refractive index were generated and their extinction measured. The measured extinctions were then compared to the theoretical extinctions calculated using Mie theory (3–7×10-7 cm-1. Excellent agreement is found from both the O4 and H2O retrievals. This enables the first inherently calibrated CEAS measurement in open cavity mode (mirrors facing the open atmosphere, and eliminates the need for sampling lines to supply air to the cavity, and/or keep the cavity enclosed and aerosol free. Measurements in open cavity mode are demonstrated for CHOCHO, CH3COCHO, NO2, H2

  7. Inherent calibration of a blue LED-CE-DOAS instrument to measure iodine oxide, glyoxal, methyl glyoxal, nitrogen dioxide, water vapour and aerosol extinction in open cavity mode

    Directory of Open Access Journals (Sweden)

    R. Thalman

    2010-12-01

    Full Text Available The combination of Cavity Enhanced Absorption Spectroscopy (CEAS with broad-band light sources (e.g. Light-Emitting Diodes, LEDs lends itself to the application of cavity enhanced Differential Optical Absorption Spectroscopy (CE-DOAS to perform sensitive and selective point measurements of multiple trace gases and aerosol extinction with a single instrument. In contrast to other broad-band CEAS techniques, CE-DOAS relies only on the measurement of relative intensity changes, i.e. does not require knowledge of the light intensity in the absence of trace gases and aerosols (I0. We have built a prototype LED-CE-DOAS instrument in the blue spectral range (420–490 nm to measure nitrogen dioxide (NO2, glyoxal (CHOCHO, methyl glyoxal (CH3COCHO, iodine oxide (IO, water vapour (H2O and oxygen dimers (O4. We demonstrate the first direct detection of methyl glyoxal, and the first CE-DOAS detection of CHOCHO and IO. The instrument is further inherently calibrated for light extinction from the cavity by observing O4 or H2O (at 477 nm and 443 nm and measuring the pressure, relative humidity and temperature independently. This approach is demonstrated by experiments where laboratory aerosols of known size and refractive index were generated and their extinction measured. The measured extinctions were then compared to the theoretical extinctions calculated using Mie theory (3–7 × 10−7cm−1. Excellent agreement is found from both the O4 and H2O retrievals. This enables the first inherently calibrated CEAS measurement at blue wavelengths in open cavity mode, and eliminates the need for sampling lines to supply air to the cavity, i.e., keep the cavity enclosed and/or aerosol free. Measurements in open cavity mode are demonstrated for CHOCHO, CH3COCHO, NO2, H2O and aerosol extinction. Our prototype

  8. Inherent calibration of a blue LED-CE-DOAS instrument to measure iodine oxide, glyoxal, methyl glyoxal, nitrogen dioxide, water vapour and aerosol extinction in open cavity mode

    Science.gov (United States)

    Thalman, R.; Volkamer, R.

    2010-12-01

    The combination of Cavity Enhanced Absorption Spectroscopy (CEAS) with broad-band light sources (e.g. Light-Emitting Diodes, LEDs) lends itself to the application of cavity enhanced Differential Optical Absorption Spectroscopy (CE-DOAS) to perform sensitive and selective point measurements of multiple trace gases and aerosol extinction with a single instrument. In contrast to other broad-band CEAS techniques, CE-DOAS relies only on the measurement of relative intensity changes, i.e. does not require knowledge of the light intensity in the absence of trace gases and aerosols (I0). We have built a prototype LED-CE-DOAS instrument in the blue spectral range (420-490 nm) to measure nitrogen dioxide (NO2), glyoxal (CHOCHO), methyl glyoxal (CH3COCHO), iodine oxide (IO), water vapour (H2O) and oxygen dimers (O4). We demonstrate the first direct detection of methyl glyoxal, and the first CE-DOAS detection of CHOCHO and IO. The instrument is further inherently calibrated for light extinction from the cavity by observing O4 or H2O (at 477 nm and 443 nm) and measuring the pressure, relative humidity and temperature independently. This approach is demonstrated by experiments where laboratory aerosols of known size and refractive index were generated and their extinction measured. The measured extinctions were then compared to the theoretical extinctions calculated using Mie theory (3-7 × 10-7cm-1). Excellent agreement is found from both the O4 and H2O retrievals. This enables the first inherently calibrated CEAS measurement at blue wavelengths in open cavity mode, and eliminates the need for sampling lines to supply air to the cavity, i.e., keep the cavity enclosed and/or aerosol free. Measurements in open cavity mode are demonstrated for CHOCHO, CH3COCHO, NO2, H2O and aerosol extinction. Our prototype LED-CE-DOAS provides a low cost, yet research grade innovative instrument for applications in simulation chambers and in the open atmosphere.

  9. OMI/Aura UV product validation using NILU-UV ground-based measurements in Thessaloniki, Greece

    Science.gov (United States)

    Zempila, Melina-Maria; Koukouli, Maria-Elissavet; Bais, Alkiviadis; Fountoulakis, Ilias; Arola, Antti; Kouremeti, Natalia; Balis, Dimitris

    2016-09-01

    The main aim of this work is to evaluate the NASA EOS AURA Ozone Monitoring Instrument (OMI) UV irradiance estimates through ground-based measurements performed by a NILU-UV multichannel radiometer (NILU-UV) operating in Thessaloniki, Greece, for the time period between January 2005 and December 2014. NILU-UV multi-filter radiometers can provide measurements at 5 UV wavelength bands with full width at half maximum (FWHM) of 10 nm approximately and a time analysis of 1 min. An additional channel measuring the Photosynthetically Active Radiation (PAR) is also incorporated to the instrument and is used for the stringent characterization of the cloud free instances. The OMI instrument estimates solar UV irradiances at four wavelengths close to those of the NILU-UV in Thessaloniki. Clear and all-sky overpass-time, as well as solar local-noon time, UV estimates are provided by the NASA Aura Data Validation Center. Spectra measured from a collocated MKIII Brewer spectrophotometer with serial number 086 (Brewer #086) were utilized for the whole period (2005-2014) in order to estimate the NILU-UV irradiances at the OMI wavelength irradiances and therefore provide a direct comparison and validation to the NILU UV measurements provided by OMI. For the nominal comparisons, using un-flagged OMI data within a 50 km radius from Thessaloniki, the linear determination coefficient, R2, ranges between 0.91 and 0.97 for the 305 nm and between 0.75 and 0.92 for 380 nm depending on the choice of overpass or local-noon time data and the cloudiness flags. The best agreement is found for the clear-sky overpass-time comparisons as well as the both PAR- and satellite algorithm-deduced clear-sky overpass and local-noon comparisons for all wavelengths. The OMI irradiances were found to overestimate the NILU-UV observations in Thessaloniki between ∼4.5% and 13.5% for the 305 nm and between ∼1.5% and ∼10.0% for the 310 nm wavelength depending on the choice of time [overpass vs local noon

  10. Retrieval and satellite intercomparison of O3 measurements from ground-based FTIR Spectrometer at Equatorial Station: Addis Ababa, Ethiopia

    Directory of Open Access Journals (Sweden)

    T. von Clarmann

    2013-02-01

    Full Text Available Since May 2009, high-resolution Fourier Transform Infrared (FTIR solar absorption spectra have been recorded at Addis Ababa (9.01° N latitude, 38.76° E longitude, 2443 m altitude above sea level, Ethiopia. The vertical profiles and total column amounts of ozone (O3 are deduced from the spectra by using the retrieval code PROFFIT (V9.5 and regularly determined instrumental line shape (ILS. A detailed error analysis of the O3 retrieval is performed. Averaging kernels of the target gas shows that the major contribution to the retrieved information comes from the measurement. The degrees of freedom for signals is found to be 2.1 on average for the retrieval of O3 from the observed FTIR spectra. The ozone Volume Mixing Ratio (VMR profiles and column amounts retrieved from FTIR spectra are compared with the coincident satellite observations of Microwave Limb Sounding (MLS, Michelson Interferometer for Passive Atmospheric Sounding (MIPAS, Tropospheric Emission Spectrometer (TES, Ozone Monitoring Instrument (OMI, Atmospheric Infrared Sounding (AIRS and Global Ozone Monitoring Experiment (GOME-2 instruments. The mean relative differences in ozone profiles of FTIR from MLS and MIPAS are generally lower than 15% within the altitude range of 27 to 36 km, whereas difference from TES is lower than 1%. Comparisons of measurements of column amounts from the satellite and the ground-based FTIR show very good agreement as exhibited by relative differences within +0.2% to +2.8% for FTIR versus MLS and GOME-2; and −0.9 to −9.0% for FTIR versus OMI, TES and AIRS. The corresponding standard deviations are within 2.0 to 2.8% for FTIR versus MLS and GOME-2 comparisons whereas that of FTIR versus OMI, TES and AIRS are within 3.5 to 7.3%. Thus, the retrieved O3 VMR and column amounts from a tropical site, Addis Ababa, is found to exhibit very good agreement with all coincident satellite observations over an approximate 3-yr period.

  11. Retrieval and satellite intercomparison of O3 measurements from ground-based FTIR Spectrometer at Equatorial Station: Addis Ababa, Ethiopia

    Science.gov (United States)

    Takele Kenea, S.; Mengistu Tsidu, G.; Blumenstock, T.; Hase, F.; von Clarmann, T.; Stiller, G. P.

    2013-02-01

    Since May 2009, high-resolution Fourier Transform Infrared (FTIR) solar absorption spectra have been recorded at Addis Ababa (9.01° N latitude, 38.76° E longitude, 2443 m altitude above sea level), Ethiopia. The vertical profiles and total column amounts of ozone (O3) are deduced from the spectra by using the retrieval code PROFFIT (V9.5) and regularly determined instrumental line shape (ILS). A detailed error analysis of the O3 retrieval is performed. Averaging kernels of the target gas shows that the major contribution to the retrieved information comes from the measurement. The degrees of freedom for signals is found to be 2.1 on average for the retrieval of O3 from the observed FTIR spectra. The ozone Volume Mixing Ratio (VMR) profiles and column amounts retrieved from FTIR spectra are compared with the coincident satellite observations of Microwave Limb Sounding (MLS), Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), Tropospheric Emission Spectrometer (TES), Ozone Monitoring Instrument (OMI), Atmospheric Infrared Sounding (AIRS) and Global Ozone Monitoring Experiment (GOME-2) instruments. The mean relative differences in ozone profiles of FTIR from MLS and MIPAS are generally lower than 15% within the altitude range of 27 to 36 km, whereas difference from TES is lower than 1%. Comparisons of measurements of column amounts from the satellite and the ground-based FTIR show very good agreement as exhibited by relative differences within +0.2% to +2.8% for FTIR versus MLS and GOME-2; and -0.9 to -9.0% for FTIR versus OMI, TES and AIRS. The corresponding standard deviations are within 2.0 to 2.8% for FTIR versus MLS and GOME-2 comparisons whereas that of FTIR versus OMI, TES and AIRS are within 3.5 to 7.3%. Thus, the retrieved O3 VMR and column amounts from a tropical site, Addis Ababa, is found to exhibit very good agreement with all coincident satellite observations over an approximate 3-yr period.

  12. Aerosol physical and chemical properties retrieved from ground-based remote sensing measurements during heavy haze days in Beijing winter

    Science.gov (United States)

    Li, Z.; Gu, X.; Wang, L.; Li, D.; Xie, Y.; Li, K.; Dubovik, O.; Schuster, G.; Goloub, P.; Zhang, Y.; Li, L.; Ma, Y.; Xu, H.

    2013-10-01

    With the increase in economic development over the past thirty years, many large cities in eastern and southwestern China are experiencing increased haze events and atmospheric pollution, causing significant impacts on the regional environment and even climate. However, knowledge on the aerosol physical and chemical properties in heavy haze conditions is still insufficient. In this study, two winter heavy haze events in Beijing that occurred in 2011 and 2012 were selected and investigated by using the ground-based remote sensing measurements. We used a CIMEL CE318 sun-sky radiometer to retrieve haze aerosol optical, physical and chemical properties, including aerosol optical depth (AOD), size distribution, complex refractive indices and aerosol fractions identified as black carbon (BC), brown carbon (BrC), mineral dust (DU), ammonium sulfate-like (AS) components and aerosol water content (AW). The retrieval results from a total of five haze days showed that the aerosol loading and properties during the two winter haze events were comparable. Therefore, average heavy haze property parameters were drawn to present a research case for future studies. The average AOD is about 3.0 at 440 nm, and the Ångström exponent is 1.3 from 440 to 870 nm. The fine-mode AOD is 2.8 corresponding to a fine-mode fraction of 0.93. The coarse particles occupied a considerable volume fraction of the bimodal size distribution in winter haze events, with the mean particle radius of 0.21 and 2.9 μm for the fine and coarse modes respectively. The real part of the refractive indices exhibited a relatively flat spectral behavior with an average value of 1.48 from 440 to 1020 nm. The imaginary part showed spectral variation, with the value at 440 nm (about 0.013) higher than the other three wavelengths (about 0.008 at 675 nm). The aerosol composition retrieval results showed that volume fractions of BC, BrC, DU, AS and AW are 1, 2, 49, 15 and 33%, respectively, on average for the investigated

  13. Integration of Remote Sensing Products with Ground-Based Measurements to Understand the Dynamics of Nepal's Forests and Plantation Sites

    Science.gov (United States)

    Gilani, H.; Jain, A. K.

    2016-12-01

    This study assembles information from three sources - remote sensing, terrestrial photography and ground-based inventory data, to understand the dynamics of Nepal's tropical and sub-tropical forests and plantation sites for the period 1990-2015. Our study focuses on following three specific district areas, which have conserved forests through social and agroforestry management practices: 1. Dolakha district: This site has been selected to study the impact of community-based forest management on land cover change using repeat photography and satellite imagery, in combination with interviews with community members. The study time period is during the period 1990-2010. We determined that satellite data with ground photographs can provide transparency for long term monitoring. The initial results also suggests that community-based forest management program in the mid-hills of Nepal was successful. 2. Chitwan district: Here we use high resolution remote sensing data and optimized community field inventories to evaluate potential application and operational feasibility of community level REDD+ measuring, reporting and verification (MRV) systems. The study uses temporal dynamics of land cover transitions, tree canopy size classes and biomass over a Kayar khola watershed REDD+ study area with community forest to evaluate satellite Image segmentation for land cover, linear regression model for above ground biomass (AGB), and estimation and monitoring field data for tree crowns and AGB. We study three specific years 2002, 2009, 2012. Using integration of WorldView-2 and airborne LiDAR data for tree species level. 3. Nuwakot district: This district was selected to study the impact of establishment of tree plantation on total barren/fallow. Over the last 40 year, this area has went through a drastic changes, from barren land to forest area with tree species consisting of Dalbergia sissoo, Leucaena leucocephala, Michelia champaca, etc. In 1994, this district area was registered

  14. A strategic outlook for coordination of ground-based measurement networks of atmospheric state variables and atmospheric composition

    Science.gov (United States)

    Bodeker, G. E.; Thorne, P.; Braathen, G.; De Maziere, M.; Thompson, A. M.; Kurylo, M. J., III

    2016-12-01

    There are a number of ground-based global observing networks that collectively aim to make key measurements of atmospheric state variables and atmospheric chemical composition. These networks include, but are not limited to:NDACC: Network for the Detection of Atmospheric Composition Change GUAN: GCOS Upper Air Network GRUAN: GCOS Reference Upper Air Network EARLINET: the European Aerosol Research Lidar Network GAW: Global Atmosphere Watch SHADOZ: Southern Hemisphere ADditional OZonesondes TCCON: Total Carbon Column Observing Network BSRN: Baseline Surface Radiation Network While each network brings unique capabilities to the global observing system, there are many instances where the activities and capabilities of the networks overlap. These commonalities across multiple networks can confound funding agencies when allocating scarce financial resources. Overlaps between networks may also result in some duplication of effort and a resultant sub-optimal use of funding resource for the global observing system. While some degree of overlap is useful for quality assurance, it is essential to identify the degree to which one network can take on a specific responsibility on behalf of all other networks to avoid unnecessary duplication, to identify where expertise in any one network may serve other networks, and to develop a long-term strategy for the evolution of these networks that clarifies to funding agencies where new investment is required. This presentation will briefly summarise the key characteristics of each network listed above, adopt a matrix approach to identify commonalities and, in particular, where there may be a danger of duplication of effort, and where gaps between the networks may be compromising the services that these networks are expected to collectively deliver to the global atmospheric and climate science research communities. The presentation will also examine where sharing of data and tools between networks may result in a more efficient delivery

  15. Empirical model for mean temperature for Indian zone and estimation of precipitable water vapor from ground based GPS measurements

    Directory of Open Access Journals (Sweden)

    C. Suresh Raju

    2007-10-01

    Full Text Available Estimation of precipitable water (PW in the atmosphere from ground-based Global Positioning System (GPS essentially involves modeling the zenith hydrostatic delay (ZHD in terms of surface Pressure (Ps and subtracting it from the corresponding values of zenith tropospheric delay (ZTD to estimate the zenith wet (non-hydrostatic delay (ZWD. This further involves establishing an appropriate model connecting PW and ZWD, which in its simplest case assumed to be similar to that of ZHD. But when the temperature variations are large, for the accurate estimate of PW the variation of the proportionality constant connecting PW and ZWD is to be accounted. For this a water vapor weighted mean temperature (Tm has been defined by many investigations, which has to be modeled on a regional basis. For estimating PW over the Indian region from GPS data, a region specific model for Tm in terms of surface temperature (Ts is developed using the radiosonde measurements from eight India Meteorological Department (IMD stations spread over the sub-continent within a latitude range of 8.5°–32.6° N. Following a similar procedure Tm-based models are also evolved for each of these stations and the features of these site-specific models are compared with those of the region-specific model. Applicability of the region-specific and site-specific Tm-based models in retrieving PW from GPS data recorded at the IGS sites Bangalore and Hyderabad, is tested by comparing the retrieved values of PW with those estimated from the altitude profile of water vapor measured using radiosonde. The values of ZWD estimated at 00:00 UTC and 12:00 UTC are used to test the validity of the models by estimating the PW using the models and comparing it with those obtained from radiosonde data. The region specific Tm-based model is found to be in par with if not better than a

  16. MAX-DOAS tropospheric nitrogen dioxide column measurements compared with the Lotos-Euros air quality model

    NARCIS (Netherlands)

    Vlemmix, T.; Eskes, H.J.; Piters, A.J.M.; Schaap, M.; Sauter, F.J.; Kelder, H.; Levelt, P.F.

    2015-01-01

    A 14-month data set of MAX-DOAS (Multi-Axis Differential Optical Absorption Spectroscopy) tropospheric NO2 column observations in De Bilt, the Netherlands, has been compared with the regional air quality model Lotos-Euros. The model was run on a 7×7 km2 grid, the same resolution as the emission inve

  17. Comparison of aromatic hydrocarbon measurements made by PTR-MS, DOAS and GC-FID during the MCMA 2003 Field Experiment

    Directory of Open Access Journals (Sweden)

    B. T. Jobson

    2010-02-01

    Full Text Available A comparison of aromatic hydrocarbon measurements is reported for the CENICA supersite in the district of Iztapalapa during the Mexico City Metropolitan Area field experiment in April 2003 (MCMA 2003. Data from three different measurement methods were compared: a Proton Transfer Reaction Mass Spectrometer (PTR-MS, long path measurements using a UV Differential Optical Absorption Spectrometer (DOAS, and Gas Chromatography-Flame Ionization analysis (GC-FID of canister samples. The principle focus was on the comparison between PTR-MS and DOAS data. Lab tests established that the PTR-MS and DOAS calibrations were consistent for a suite of aromatic compounds including benzene, toluene, p-xylene, ethylbenzene, 1,2,4-trimethylbenzene, phenol and styrene. The point sampling measurements by the PTR-MS and GC-FID showed good correlations (r=0.6, and were in reasonable agreement for toluene, C2-alkylbenzenes and C3-alkylbenzenes. The PTR-MS benzene data were consistently high, indicating interference from ethylbenzene fragmentation for the 145 Td drift field intensity used in the experiment. Correlations between the open-path data measured at 16-m height over a 860-m path length (retroreflector in 430 m distance, and the point measurements collected at 37-m sampling height were best for benzene (r=0.61, and reasonably good for toluene, C2-alkylbenzenes, naphthalene, styrene, cresols and phenol (r>0.5. There was good agreement between DOAS and PTR-MS measurements of benzene after correction for the PTR-MS ethylbenzene interference. Mixing ratios measured by DOAS were on average a factor of 1.7 times greater than the PTR-MS data for toluene, C2-alkylbenzenes, naphthalene and styrene. The level of agreement for the toluene data displayed a modest dependence on wind direction, establishing that spatial gradients – horizontal, vertical, or both – in toluene mixing ratios were significant, and

  18. Tropospheric and total ozone columns over Paris (France measured using medium-resolution ground-based solar-absorption Fourier-transform infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    C. Viatte

    2011-10-01

    Full Text Available Ground-based Fourier-transform infrared (FTIR solar absorption spectroscopy is a powerful remote sensing technique providing information on the vertical distribution of various atmospheric constituents. This work presents the first evaluation of a mid-resolution ground-based FTIR to measure tropospheric ozone, independently of stratospheric ozone. This is demonstrated using a new atmospheric observatory (named OASIS for "Observations of the Atmosphere by Solar absorption Infrared Spectroscopy", installed in Créteil (France. The capacity of the technique to separate stratospheric and tropospheric ozone is demonstrated. Daily mean tropospheric ozone columns derived from the Infrared Atmospheric Sounding Interferometer (IASI and from OASIS measurements are compared for summer 2009 and a good agreement of −5.6 (±16.1 % is observed. Also, a qualitative comparison between in-situ surface ozone measurements and OASIS data reveals OASIS's capacity to monitor seasonal tropospheric ozone variations, as well as ozone pollution episodes in summer 2009 around Paris. Two extreme pollution events are identified (on the 1 July and 6 August 2009 for which ozone partial columns from OASIS and predictions from a regional air-quality model (CHIMERE are compared following strict criteria of temporal and spatial coincidence. An average bias of 0.2%, a mean square error deviation of 7.6%, and a correlation coefficient of 0.91 is found between CHIMERE and OASIS, demonstrating the potential of a mid-resolution FTIR instrument in ground-based solar absorption geometry for tropospheric ozone monitoring.

  19. Validation of GOME-2/Metop total column water vapour with ground-based and in situ measurements

    Science.gov (United States)

    Kalakoski, Niilo; Kujanpää, Jukka; Sofieva, Viktoria; Tamminen, Johanna; Grossi, Margherita; Valks, Pieter

    2016-04-01

    The total column water vapour product from the Global Ozone Monitoring Experiment-2 on board Metop-A and Metop-B satellites (GOME-2/Metop-A and GOME-2/Metop-B) produced by the Satellite Application Facility on Ozone and Atmospheric Chemistry Monitoring (O3M SAF) is compared with co-located radiosonde observations and global positioning system (GPS) retrievals. The validation is performed using recently reprocessed data by the GOME Data Processor (GDP) version 4.7. The time periods for the validation are January 2007-July 2013 (GOME-2A) and December 2012-July 2013 (GOME-2B). The radiosonde data are from the Integrated Global Radiosonde Archive (IGRA) maintained by the National Climatic Data Center (NCDC). The ground-based GPS observations from the COSMIC/SuomiNet network are used as the second independent data source. We find a good general agreement between the GOME-2 and the radiosonde/GPS data. The median relative difference of GOME-2 to the radiosonde observations is -2.7 % for GOME-2A and -0.3 % for GOME-2B. Against the GPS, the median relative differences are 4.9 % and 3.2 % for GOME-2A and B, respectively. For water vapour total columns below 10 kg m-2, large wet biases are observed, especially against the GPS retrievals. Conversely, at values above 50 kg m-2, GOME-2 generally underestimates both ground-based observations.

  20. Cloud Properties under Different Synoptic Circulations: Comparison of Radiosonde and Ground-Based Active Remote Sensing Measurements

    Directory of Open Access Journals (Sweden)

    Jinqiang Zhang

    2016-11-01

    Full Text Available In this study, long-term (10 years radiosonde-based cloud data are compared with the ground-based active remote sensing product under six prevailing large-scale synoptic patterns, i.e., cyclonic center (CC, weak pressure pattern (WP, the southeast bottom of cyclonic center (CB, cold front (CF, anticyclone edge (AE and anticyclone center (AC over the Southern Great Plains (SGP site. The synoptic patterns are generated by applying the self-organizing map weather classification method to the daily National Centers for Environmental Protection mean sea level pressure records from the North American Regional Reanalysis. It reveals that the large-scale synoptic circulations can strongly influence the regional cloud formation, and thereby have impact on the consistency of cloud retrievals from the radiosonde and ground-based cloud product. The total cloud cover at the SGP site is characterized by the least in AC and the most in CF. The minimum and maximum differences between the two cloud methods are 10.3% for CC and 13.3% for WP. Compared to the synoptic patterns characterized by scattered cloudy and clear skies (AE and AC, the agreement of collocated cloud boundaries between the two cloud approaches tends to be better under the synoptic patterns dominated by overcast and cloudy skies (CC, WP and CB. The rainy and windy weather conditions in CF synoptic pattern influence the consistency of the two cloud retrieval methods associated with the limited capabilities inherent to the instruments. The cloud thickness distribution from the two cloud datasets compares favorably with each other in all synoptic patterns, with relative discrepancy of ≤0.3 km.

  1. Investigation of the 3D distribution of tropospheric formaldehyde (HCHO) at the city of Mainz (Germany) using measurements of a 4 azimuth MAX-DOAS instrument

    Science.gov (United States)

    Donner, Sebastian; Gu, Myojeong; Remmers, Julia; Wang, Yang; Wagner, Thomas

    2017-04-01

    The Differential Optical Absorption Spectroscopy (DOAS)-method allows to investigate the distribution of different atmospheric trace gases (e.g. NO2, SO2, HCHO...) simultaneously. This is done by analysing the absorptions of these species in spectra of scattered sunlight. Multi-AXis (MAX)-DOAS measurements observe scattered sun light under different elevation angles. From such measurements tropospheric vertical column densities (VCDs) and vertical profiles of the measured trace gases and aerosols can be determined. We performed measurements using a 4 azimuth MAX-DOAS system on the roof of the Max Planck Institute for Chemistry in Mainz/Germany since 2013. This instrument observes scattered sunlight in 4 separate orthogonal azimuth directions. We derive vertical profiles of trace gases in these 4 different azimuth directions. From these results we can investigate the 3D distribution of the trace gases. Mainz is located at the edge of the Rhine-Main area which is one of the densest populated areas in Germany. Therefore it experiences episodes of high and low pollution depending on the meteorological conditions. In this study we focus on formaldehyde (HCHO). It is either emitted directly by industries and other anthropogenic and biogenic activities. Usually higher amounts are produced by photochemical reactions from precursor substances (secondary production), where it plays an important role in photochemical smog chemistry and O3 chemistry. As it is an intermediate product of basic oxidation cycles of other hydrocarbons (also referred to as volatile organic compounds (VOCs)) especially in summer its concentrations are determined by the abundances of VOCs. Therefore HCHO observations can be used as an indicator for VOCs. Up to now we have nearly 4 years (starting from May 2013) of almost continuous data which provides already a quite large dataset. In this work we present a first overview of our HCHO results including time series of HCHO columns, a first comparison of

  2. A method for the retrieval of atomic oxygen density and temperature profiles from ground-based measurements of the O(+)(2D-2P) 7320 A twilight airglow

    Science.gov (United States)

    Fennelly, J. A.; Torr, D. G.; Richards, P. G.; Torr, M. R.; Sharp, W. E.

    1991-01-01

    This paper describes a technique for extracting thermospheric profiles of the atomic-oxygen density and temperature, using ground-based measurements of the O(+)(2D-2P) doublet at 7320 and 7330 A in the twilight airglow. In this method, a local photochemical model is used to calculate the 7320-A intensity; the method also utilizes an iterative inversion procedure based on the Levenberg-Marquardt method described by Press et al. (1986). The results demonstrate that, if the measurements are only limited by errors due to Poisson noise, the altitude profiles of neutral temperature and atomic oxygen concentration can be determined accurately using currently available spectrometers.

  3. The CU ground MAX-DOAS instrument: characterization of RMS noise limitations and first measurements near Pensacola, FL of BrO, IO, and CHOCHO

    Directory of Open Access Journals (Sweden)

    S. Coburn

    2011-11-01

    Full Text Available We designed and assembled the University of Colorado Ground Multi AXis Differential Optical Absorption Spectroscopy (CU GMAX-DOAS instrument to retrieve bromine oxide (BrO, iodine oxide (IO, formaldehyde (HCHO, glyoxal (CHOCHO, nitrogen dioxide (NO2 and the oxygen dimer (O4 in the coastal atmosphere of the Gulf of Mexico. The detection sensitivity of DOAS measurements is proportional to the root mean square (RMS of the residual spectrum that remains after all absorbers have been subtracted. Here we describe the CU GMAX-DOAS instrument and demonstrate that the hardware is capable of attaining RMS of ∼6 × 10−6 from solar stray light noise tests using high photon count spectra (compatible within a factor of two with photon shot noise.

    Laboratory tests revealed two critical instrument properties that, in practice, can limit the RMS: (1 detector non-linearity noise, RMSNLin, and (2 temperature fluctuations that cause variations in optical resolution (full width at half the maximum, FWHM, of atomic emission lines and give rise to optical resolution noise, RMSFWHM. The non-linearity of our detector is low (∼10−2 yet – unless actively controlled – is sufficiently large to create RMSNLin of up to 2 × 10−4. The optical resolution is sensitive to temperature changes (0.03 detector pixels °C−1 at 334 nm, and temperature variations of 0.1°C can cause RMSFWHM of ~1 × 10−4. Both factors were actively addressed in the design of the CU GMAX-DOAS instrument. With an integration time of 60 s the instrument can reach RMS noise of 3 × 10−5, and typical RMS in field measurements ranged from 6 × 10−5 to 1.4 × 10−4.

    The CU GMAX-DOAS was set up at a coastal site near Pensacola, Florida, where we detected BrO, IO and CHOCHO in the marine boundary layer (MBL, with daytime

  4. The CU ground MAX-DOAS instrument: characterization of RMS noise limitations and first measurements near Pensacola, FL of BrO, IO, and CHOCHO

    Science.gov (United States)

    Coburn, S.; Dix, B.; Sinreich, R.; Volkamer, R.

    2011-11-01

    We designed and assembled the University of Colorado Ground Multi AXis Differential Optical Absorption Spectroscopy (CU GMAX-DOAS) instrument to retrieve bromine oxide (BrO), iodine oxide (IO), formaldehyde (HCHO), glyoxal (CHOCHO), nitrogen dioxide (NO2) and the oxygen dimer (O4) in the coastal atmosphere of the Gulf of Mexico. The detection sensitivity of DOAS measurements is proportional to the root mean square (RMS) of the residual spectrum that remains after all absorbers have been subtracted. Here we describe the CU GMAX-DOAS instrument and demonstrate that the hardware is capable of attaining RMS of ∼6 × 10-6 from solar stray light noise tests using high photon count spectra (compatible within a factor of two with photon shot noise). Laboratory tests revealed two critical instrument properties that, in practice, can limit the RMS: (1) detector non-linearity noise, RMSNLin, and (2) temperature fluctuations that cause variations in optical resolution (full width at half the maximum, FWHM, of atomic emission lines) and give rise to optical resolution noise, RMSFWHM. The non-linearity of our detector is low (∼10-2) yet - unless actively controlled - is sufficiently large to create RMSNLin of up to 2 × 10-4. The optical resolution is sensitive to temperature changes (0.03 detector pixels °C-1 at 334 nm), and temperature variations of 0.1°C can cause RMSFWHM of ~1 × 10-4. Both factors were actively addressed in the design of the CU GMAX-DOAS instrument. With an integration time of 60 s the instrument can reach RMS noise of 3 × 10-5, and typical RMS in field measurements ranged from 6 × 10-5 to 1.4 × 10-4. The CU GMAX-DOAS was set up at a coastal site near Pensacola, Florida, where we detected BrO, IO and CHOCHO in the marine boundary layer (MBL), with daytime average tropospheric vertical column densities (average of data above the detection limit), VCDs, of ∼2 × 1013 molec cm-2, 8 × 1012 molec cm-2 and 4 × 1014 molec cm-2, respectively. HCHO and

  5. Observation of the volcanic plume of Eyjafjallajoekull over continental Europe by MAX-DOAS

    Energy Technology Data Exchange (ETDEWEB)

    Yilmaz, S.; Bobrowski, N.; Friess, U.; Platt, U. [IUP, University of Heidelberg (Germany); Flentje, H. [DWD, Hohenpeissenberg (Germany); Hoermann, C.; Sihler, H. [IUP, University of Heidelberg (Germany); MPI, Mainz (Germany); Kern, C. [USGS, Vancouver (Canada); Wagner, T. [MPI, Mainz (Germany)

    2011-07-01

    The recent eruption of Eyjafjallajoekull Volcano (Iceland) and the emitted ash plume which disrupted commercial air traffic over Europe has led to an exhaustive debate on how to improve our ability to quantitatively determine the ash load in the atmosphere as a function of time and geographical location. Satellite instruments detecting ash and SO{sub 2} and ground-based LIDAR stations can help constrain atmospheric transport and meteorology models used to predict ash dispersion. However, MAX-DOAS represents an additional tool with considerable potential for the quantitative detection of elevated volcanic ash and SO{sub 2} plumes. It performs especially well during weather conditions in which satellites and LIDARs are impeded in their effectiveness, e.g. in the case of dense clouds above or below the plume, respectively. Here, the advantages and disadvantages of the DOAS technique are discussed, and its potential for monitoring of volcanic ash hazards explored. Results of ash and SO{sub 2} measurements of the Eyjafjallajoekull plume as it passed over Heidelberg are presented as an example of a positive detection of a highly diluted volcanic plume. Their low cost and complementary nature makes MAX-DOAS a promising technology in the field of aviation hazard detection and management.

  6. Development and characterization of the CU ground MAX-DOAS instrument: lowering RMS noise and first measurements of BrO, IO, and CHOCHO near Pensacola, FL

    Directory of Open Access Journals (Sweden)

    S. Coburn

    2011-01-01

    Full Text Available We designed and assembled the University of Colorado Ground Multi AXis Differential Optical Absorption Spectroscopy (CU GMAX-DOAS instrument to retrieve bromine oxide (BrO, iodine oxide (IO, formaldehyde (HCHO, glyoxal (CHOCHO, nitrogen dioxide (NO2 and the oxygen dimer O4 in the coastal atmosphere of the Gulf of Mexico. The detection sensitivity of DOAS measurements is directly proportional to the root mean square (RMS of the residual spectrum that remains after all absorbers have been subtracted. Here we describe the CU GMAX-DOAS instrument and demonstrate that the hardware is capable of attaining RMS values of ~6 × 10-6 without apparent limitations other than photon shot noise.

    Laboratory tests revealed two factors that, in practice, limit the RMS: (1 detector non-linearity noise, RMSNLin, and (2 temperature fluctuations that cause variations in optical resolution (full width at half the maximum, FWHM, of atomic emission lines and give rise to optical resolution noise, RMSFWHM. The non-linearity of our detector is low (~10−3 yet – unless actively controlled – is sufficiently large to create a RMSNLin limit of up to 1.4 × 10-4. The optical resolution is sensitive to temperature changes (0.03 detector pixels/°C at 334 nm, and temperature variations of 0.1 °C can cause residual RMSFWHM of ~1 × 10-4. Both factors were actively addressed in the design of the CU GMAX-DOAS instrument.

    The CU GMAX-DOAS was set up at a coastal site near Pensacola, FL, where we detected BrO, IO and CHOCHO in the marine boundary layer (MBL, with daytime average tropospheric vertical column densities, VCDs, of ~2 × 1013 molec cm−2, 8 × 1012 molec cm−2 and 4 × 1014 molec cm−2, respectively. HCHO and NO2 were also detected with typical MBL VCDs of 1

  7. Water erosion as a cause for agricultural soil loss: modeling of dynamic processes using high-resolution ground based LiDAR measurements

    Science.gov (United States)

    Oz, Imri; Filin, Sagi; Assouline, Shmuel; Shtain, Zachi; Furman, Alexander

    2016-04-01

    Soil erosion by rainfall and water flow is a frequent natural geomorphic process shaping the earth's surface at various scales. Conventional agrotechnical methods enhance soil erosion at the field scale and are at the origin of the reduction of the upper soil layer depth. This reduction is expressed in two aspects: decrease of soil depth, mainly due to erosion, and the diminution of soil quality, mainly due to the loss of fine material, nutrients and organic matter. Rain events, not even the most extremes, cause detachment and transport of fertile soil rich in organic matter and nutrients away from the fields, filling and plugging drainage channels, blocking infrastructure and contaminating water sources. Empirical, semi-empirical and mechanistic models are available to estimate soil erosion by water flow and sediment transport (e.g. WEPP, KINEROSS, EUROSEM). Calibration of these models requires data measured at high spatial and temporal resolutions. Development of high-resolution measurement tools (for both spatial and temporal aspects) should improve the calibration of functions related to particles detachment and transport from the soil surface. In addition, despite the great impact of different tillage systems on the soil erosion process, the vast majority of the models ignore this fundamental factor. The objective of this study is to apply high-resolution ground-based LiDAR measurements to different tillage schemes and scales to improve the ability of models to accurately describe the process of soil erosion induced by rainfall and overland flow. Ground-based laser scans provide high resolution accurate and subtle geomorphic changes, as well as larger-scale deformations. As such, it allows frequent monitoring, so that even the effect of a single storm can be measured, thus improving the calibration of the erosion models. Preliminary results for scans made in the field show the potential and limitations of ground-based LiDAR, and at this point qualitatively can

  8. Inter-comparison of glyoxal retrievals from MAX-DOAS during the MAD-CAT campaign

    Science.gov (United States)

    Ortega, Ivan; Wagner, Thomas; Lampel, Johannes; van Roozendael, Michel; Richter, Andreas; Sinha, Vinayak; Xie, Pinhua; Volkamer, Rainer

    2015-04-01

    Over the past few years the smallest α-dicarbonyl compound glyoxal (CHOCHO) has received attention in order to inform relevant atmospheric chemistry processes such as oxidative capacity and secondary organic aerosol (SOA) formation. A method to detect glyoxal in the atmosphere is through the Differential Optical Absorption Spectroscopy (DOAS) applied to solar scattered light passive remote sensing measurements on different platforms, including ground based, aircrafts, and satellites. Although these measurements are often described still many questions about DOAS fitting parameters need to be investigated. We present results from a comprehensive Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) comparison effort during the Multi Axis DOAS-Comparison campaign for Aerosols and Trace gases (MAD-CAT) held at the Max Planck institute for Chemistry in Mainz, Germany with an intensive operation period from June to August 2013. We evaluate the comparison for glyoxal differential Slant Column Densities (dSCD) from 6 different research groups during the MAD-CAT campaign. The data analysis is performed following three retrieval common settings. In general, good agreement between different groups is found, especially for days with low cloud coverage. Based on the diurnal variability of the glyoxal-to-formaldehyde ratio we identified that Mainz is influenced mostly by anthropogenic volatile organic compounds (AVOC) emission type. Also, for most of the days glyoxal was often clearly above the respective detection limits. We will present results of sensitivity studies in order to know influence of the wavelength window, dependence of the NO2 air mass factor, cross correlation with H2O, among others. Finally, synthetic spectra created with the SCIATRAN radiative transfer model using measurement related inputs are analysed and first results are presented.

  9. Comparing the Cloud Vertical Structure Derived from Several Methods Based on Radiosonde Profiles and Ground-based Remote Sensing Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Costa-Suros, M.; Calbo, J.; Gonzalez, J. A.; Long, Charles N.

    2014-08-27

    The cloud vertical distribution and especially the cloud base height, which is linked to cloud type, is an important characteristic in order to describe the impact of clouds in a changing climate. In this work several methods to estimate the cloud vertical structure (CVS) based on atmospheric sounding profiles are compared, considering number and position of cloud layers, with a ground based system which is taken as a reference: the Active Remote Sensing of Clouds (ARSCL). All methods establish some conditions on the relative humidity, and differ on the use of other variables, the thresholds applied, or the vertical resolution of the profile. In this study these methods are applied to 125 radiosonde profiles acquired at the ARM Southern Great Plains site during all seasons of year 2009 and endorsed by GOES images, to confirm that the cloudiness conditions are homogeneous enough across their trajectory. The overall agreement for the methods ranges between 44-88%; four methods produce total agreements around 85%. Further tests and improvements are applied on one of these methods. In addition, we attempt to make this method suitable for low resolution vertical profiles, which could be useful in atmospheric modeling. The total agreement, even when using low resolution profiles, can be improved up to 91% if the thresholds for a moist layer to become a cloud layer are modified to minimize false negatives with the current data set, thus improving overall agreement.

  10. Global consistency check of AIRS and IASI total CO2 column concentrations using WDCGG ground-based measurements

    Science.gov (United States)

    Diao, Anyuan; Shu, Jiong; Song, Ci; Gao, Wei

    2017-03-01

    This article describes a global consistency check of CO2 satellite retrieval products from the Atmospheric Infrared Sounder (AIRS) and Infrared Atmospheric Sounding Interferometer (IASI) using statistical analysis and data from the World Data Centre for Greenhouse Gases (WDCGG). We use the correlation coefficient (r), relative difference (RD), root mean square errors (RMSE), and mean bias error (MBE) as evaluation indicators for this study. Statistical results show that a linear positive correlation between AIRS/IASI and WDCGG data occurs for most regions around the world. Temporal and spatial variations of these statistical quantities reflect obvious differences between satellite-derived and ground-based data based on geographic position, especially for stations near areas of intense human activities in the Northern Hemisphere. It is noteworthy that there appears to be a very weak correlation between AIRS/IASI data and ten groundbased observation stations in Europe, Asia, and North America. These results indicate that retrieval products from the two satellite-based instruments studied should be used with great caution.

  11. Effect of Water Vapor Absorption on Measurements of Atmospheric Nitrate Radical by LP-DOAS

    Institute of Scientific and Technical Information of China (English)

    Su-wen Li; Wen-qing Liu; Pin-hua Xie; Yi-jun Yang; De-bao Chen; Zheng Li

    2008-01-01

    During the measurement of atmospheric nitrate radical by long-path differential optical absorption spectroscopy, water vapor strong absorption could affect the measurement of nitrate radical and detection limits of system. Under the tropospheric condition, the optical density of water vapor absorption is non-linearly dependent on column density. An effective method was developed to eliminate the effect of water vapor absorption. Reference spectra of water vapor based on the daytime atmospheric absorption spectra, when fitted together with change of cross section with water vapor column densities, gave a more accurate fitting of water vapor absorptions, thus its effect on the measurements of nitrate radical could he restricted to a minimum and detection limits of system reached 3.6 ppt. The modified method was applied during an intensive field campaign in the Pearl River Delta, China. The NO3 concentration in polluted air masses varied from 3.6 ppt to 82.5 ppt with an average level of 23.6±1.8 ppt.

  12. Effect of Water Vapor Absorption on Measurements of Atmospheric Nitrate Radical by LP-DOAS

    Science.gov (United States)

    Li, Su-wen; Liu, Wen-qing; Xie, Pin-hua; Yang, Yi-jun; Chen, De-bao; Li, Zheng

    2008-10-01

    During the measurement of atmospheric nitrate radical by long-path differential optical absorption spec-troscopy, water vapor strong absorption could affect the measurement of nitrate radical and detection limits of system. Under the tropospheric condition, the optical density of water vapor absorption is non-linearly dependent on column density. An effective method was developed to eliminate the effect of water vapor absorption. Reference spectra of water vapor based on the daytime atmospheric absorption spectra, when fitted together with change of cross section with water vapor column densities, gave a more accurate fitting of water vapor absorptions, thus its effect on the measurements of nitrate radical could be restricted to a minimum and detection limits of system reached 3.6 ppt. The modified method was applied during an intensive field campaign in the Pearl River Delta, China. The NO3 concentration in polluted air masses varied from 3.6 ppt to 82.5 ppt with an average level of 23.6±1.8 ppt.

  13. Single snapshot DOA estimation

    OpenAIRE

    Häcker, P.; Yang, B.

    2010-01-01

    In array signal processing, direction of arrival (DOA) estimation has been studied for decades. Many algorithms have been proposed and their performance has been studied thoroughly. Yet, most of these works are focused on the asymptotic case of a large number of snapshots. In automotive radar applications like driver assistance systems, however, only a small number of snapshots of the radar sensor array or, in the worst case, a single snapshot is available for DOA estimation...

  14. Tropospheric and total ozone columns over Paris (France measured using medium-resolution ground-based solar-absorption Fourier-transform infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    C. Viatte

    2011-05-01

    Full Text Available Ground-based Fourier-transform infrared (FTIR solar absorption spectroscopy is a powerful remote sensing technique providing information on the vertical distribution of various atmospheric constituents. This work presents the first evaluation of a mid-resolution ground-based FTIR to measure tropospheric ozone, independently of stratospheric ozone. This is demonstrated using a new atmospheric observatory (named OASIS for "Observations of the Atmosphere by Solar absorption Infrared Spectroscopy", installed in Créteil (France. Indeed, the information content of OASIS ozone retrievals is clearly sufficient to monitor separately tropospheric (from the surface up to 8 km and stratospheric ozone. Daily mean tropospheric ozone columns derived from the Infrared Atmospheric Sounding Interferometer (IASI and from OASIS measurements have been compared for summer 2009 and a good agreement of −5.6 (±16.1 % is observed. Also, a qualitative comparison between in-situ surface ozone measurements and OASIS data clearly shows OASIS's capacity to monitor seasonal tropospheric ozone variations, as well as ozone pollution episodes in summer 2009 around Paris. Two extreme pollution events were identified (on the 1 July and 6 August 2009 for which ozone partial columns from OASIS and predictions from a regional air-quality model (CHIMERE were compared by respecting temporal and spatial coincidence criteria. Quantitatively, an average bias of 0.2 %, a mean square error deviation of 7.6 %, and a correlation coefficient of 0.91 was found between CHIMERE and OASIS. This demonstrates that a mid-resolution FTIR instrument in ground-based solar absorption geometry is a promising technique for monitoring tropospheric ozone.

  15. Measuring Effective Leaf Area Index, Foliage Profile, and Stand Height in New England Forest Stands Using a Full-Waveform Ground-Based Lidar

    Science.gov (United States)

    Zhao, Feng; Yang, Xiaoyuan; Schull, Mithcell A.; Roman-Colon, Miguel O.; Yao, Tian; Wang, Zhuosen; Zhang, Qingling; Jupp, David L. B.; Lovell, Jenny L.; Culvenor, Darius; Newnham, Glenn J.; Richardson, Andrew D.; Ni-Meister, Wenge; Schaaf, Crystal L.; Woodcock, Curtis E.; Strahler, Alan H.

    2011-01-01

    Effective leaf area index (LAI) retrievals from a scanning, ground-based, near-infrared (1064 nm) lidar that digitizes the full return waveform, the Echidna Validation Instrument (EVI), are in good agreement with those obtained from both hemispherical photography and the Li-Cor LAI-2000 Plant Canopy Analyzer. We conducted trials at 28 plots within six stands of hardwoods and conifers of varying height and stocking densities at Harvard Forest, Massachusetts, Bartlett Experimental Forest, New Hampshire, and Howland Experimental Forest, Maine, in July 2007. Effective LAI values retrieved by four methods, which ranged from 3.42 to 5.25 depending on the site and method, were not significantly different ( b0.1 among four methods). The LAI values also matched published values well. Foliage profiles (leaf area with height) retrieved from the lidar scans, although not independently validated, were consistent with stand structure as observed and as measured by conventional methods. Canopy mean top height, as determined from the foliage profiles, deviated from mean RH100 values obtained from the Lidar Vegetation Imaging Sensor (LVIS) airborne large-footprint lidar system at 27 plots by .0.91 m with RMSE=2.04 m, documenting the ability of the EVI to retrieve stand height. The Echidna Validation Instrument is the first realization of the Echidna lidar concept, devised by Australia's Commonwealth Scientific and Industrial Research Organization (CSIRO), for measuring forest structure using full-waveform, ground-based, scanning lidar.

  16. Measuring Effective Leaf Area Index, Foliage Profile, and Stand Height in New England Forest Stands Using a Full-Waveform Ground-Based Lidar

    Science.gov (United States)

    Zhao, Feng; Yang, Xiaoyuan; Schull, Mithcell A.; Roman-Colon, Miguel O.; Yao, Tian; Wang, Zhuosen; Zhang, Qingling; Jupp, David L. B.; Lovell, Jenny L.; Culvenor, Darius; hide

    2011-01-01

    Effective leaf area index (LAI) retrievals from a scanning, ground-based, near-infrared (1064 nm) lidar that digitizes the full return waveform, the Echidna Validation Instrument (EVI), are in good agreement with those obtained from both hemispherical photography and the Li-Cor LAI-2000 Plant Canopy Analyzer. We conducted trials at 28 plots within six stands of hardwoods and conifers of varying height and stocking densities at Harvard Forest, Massachusetts, Bartlett Experimental Forest, New Hampshire, and Howland Experimental Forest, Maine, in July 2007. Effective LAI values retrieved by four methods, which ranged from 3.42 to 5.25 depending on the site and method, were not significantly different ( b0.1 among four methods). The LAI values also matched published values well. Foliage profiles (leaf area with height) retrieved from the lidar scans, although not independently validated, were consistent with stand structure as observed and as measured by conventional methods. Canopy mean top height, as determined from the foliage profiles, deviated from mean RH100 values obtained from the Lidar Vegetation Imaging Sensor (LVIS) airborne large-footprint lidar system at 27 plots by .0.91 m with RMSE=2.04 m, documenting the ability of the EVI to retrieve stand height. The Echidna Validation Instrument is the first realization of the Echidna lidar concept, devised by Australia's Commonwealth Scientific and Industrial Research Organization (CSIRO), for measuring forest structure using full-waveform, ground-based, scanning lidar.

  17. Assessing the need for a O4 scaling factor for MAX-DOAS measurements during the MAD-CAT campaign in Mainz Germany, Summer 2013

    Science.gov (United States)

    Wagner, Thomas; Remmers, Julia; Shaiganfar, Reza; Lampel, Johannes; Wang, Yang; Beirle, Steffen; Dörner, Steffen

    2016-04-01

    MAX-DOAS measurements of the atmospheric absorption of the oxygen dimer O4 are often used to derive information about the tropospheric aerosol distribution. For that purpose measured absorptions are compared to results of a forward model based on radiative transfer simulations and assumptions about the atmospheric state. Many studies demonstrated good agreement of the derived aerosol results with independent observations. Nevertheless, in some studies also systematic differences between the measurements and the forward model were found. E.g. measured O4 absorptions on clear days were found to be even larger than the forward model results for an assumed aerosol-free atmosphere. These discrepancies motivated the use of a scaling factor for the retrieved O4 absorptions. Reported values of this scaling factor range from about 0.7 to 0.9. On the other hand, several studies found excellent agreement between measurements and forward model without the need of a scaling factor. So far, there is no convincing explanation for these conflicting findings. In this study we compare measurements and forward model results for two clear days during the MAD-CAT (Multi Axis DOAS - Comparison campaign of Aerosols and Trace gases) campaign in Mainz, Germany in Summer 2013. On these days the aerosol extinction profiles were well constraint by measurements of a ceilometer and a sun photometer. For almost all of these measurements (made in 4 azimuth directions) we find a systematic underestimation of the measured O4 absorptions by the forward model indicating the need for a scaling factor of about 0.65 to 0.9. We investigate several potential reasons for the observed discrepancy including the influence of the profiles of temperature, pressure and aerosol extinction as well as the aerosol optical properties.

  18. Validation of middle-atmospheric campaign-based water vapour measured by the ground-based microwave radiometer MIAWARA-C

    Directory of Open Access Journals (Sweden)

    B. Tschanz

    2013-07-01

    Full Text Available Middle atmospheric water vapour can be used as a tracer for dynamical processes. It is mainly measured by satellite instruments and ground-based microwave radiometers. Ground-based instruments capable of measuring middle-atmospheric water vapour are sparse but valuable as they complement satellite measurements, are relatively easy to maintain and have a long lifetime. MIAWARA-C is a ground-based microwave radiometer for middle-atmospheric water vapour designed for use on measurement campaigns for both atmospheric case studies and instrument intercomparisons. MIAWARA-C's retrieval version 1.1 (v1.1 is set up in a such way as to provide a consistent data set even if the instrument is operated from different locations on a campaign basis. The sensitive altitude range for v1.1 extends from 4 hPa (37 km to 0.017 hPa (75 km. For v1.1 the estimated systematic error is approximately 10% for all altitudes. At lower altitudes it is dominated by uncertainties in the calibration, with altitude the influence of spectroscopic and temperature uncertainties increases. The estimated random error increases with altitude from 5 to 25%. MIAWARA-C measures two polarisations of the incident radiation in separate receiver channels, and can therefore provide two measurements of the same air mass with independent instrumental noise. The standard deviation of the difference between the profiles obtained from the two polarisations is in excellent agreement with the estimated random measurement error of v1.1. In this paper, the quality of v1.1 data is assessed for measurements obtained at two different locations: (1 a total of 25 months of measurements in the Arctic (Sodankylä, 67.37° N, 26.63° E and (2 nine months of measurements at mid-latitudes (Zimmerwald, 46.88° N, 7.46° E. For both locations MIAWARA-C's profiles are compared to measurements from the satellite experiments Aura MLS and MIPAS. In addition, comparisons to ACE-FTS and SOFIE are presented for the

  19. Comments to the Article by Thuillier et al. "The Infrared Solar Spectrum Measured by the SOLSPEC Spectrometer Onboard the International Space Station" on the Interpretation of Ground-based Measurements at the Izaña Site

    Science.gov (United States)

    Bolsée, D.; Pereira, N.; Cuevas, E.; García, R.; Redondas, A.

    2016-10-01

    Thuillier et al. ( Solar Phys. 290, 1581, 2015) article compares ATLAS-3 reference composite solar spectral irradiance (SSI) with more recent spatial measurements, as well as ground-based ones, including IRSPERAD. With respect to the IRSPERAD spectrum of Bolsée et al. ( Solar Phys. 289, 2433, 2014), Thuillier et al. (2015) presents an analysis based on a set of meteorological parameters retrieved at the moment of the respective ground-based campaign. This comment is intended to give a new insight to the said analysis which is based upon revised values of the meteorological parameters incorrectly used in Thuillier et al. (2015).

  20. Quality assessment of ground-based microwave measurements of chlorine monoxide, ozone, and nitrogen dioxide from the NDSC radiometer at the plateau de bure

    Energy Technology Data Exchange (ETDEWEB)

    Ricaud, P.; Noe, J. de la [Observatoire Aquitain des Sciences de l' Univers (OASU), Lab. d' Astrodynamique, d' Astrophysique et d' Aeronomie de Bordeaux, Floirac (France); Baron, P. [Noveltis, Toulouse (France)

    2004-07-01

    A ground-based microwave radiometer dedicated to chlorine monoxide (ClO) measurements around 278 GHz has been in operation from December 1993-June 1996 at the Plateau de Bure, France (45 N, 5.9 E, 2500 m altitude). It belongs to the international network for the detection of stratospheric change. A detailed study of both measurements and retrieval schemes has been undertaken. Although dedicated to the measurements of ClO, simultaneous profiles of O{sub 3}, ClO and NO{sub 2}, together with information about the instrumental baseline, have been retrieved using the optimal estimation method. The vertical profiles have been compared with other ground-based microwave data, satellite-borne data and model results. Data quality shows: 1) the weak sensitivity of the instrument that obliges to make time averages over several hours; 2) the site location where measurements of good opacities are possible for only a few days per year; 3) the baseline undulation affecting all the spectra, an issue common to all the microwave instruments; 4) the slow drift of some components affecting frequencies by 3-4 MHz within a couple of months. Nevertheless, when temporally averaging data over a few days, ClO temporal variations (diurnal and over several weeks in winter 1995) from 35-50 km are consistent with model results and satellite data, particularly at the peak altitude around 40 km, although temporal coincidences are infrequent in winter 1995. In addition to ClO, it is possible to obtain O{sub 3} information from 30-60 km whilst the instrument is not optimized at all for this molecule. Retrievals of O{sub 3} are reasonable when compared with model and another ground-based data set, although the lowermost layers are affected by the contamination of baseline remnants. Monthly-averaged diurnal variations of NO{sub 2} are detected at 40 km and appear in agreement with photochemical model results and satellite zonally-averaged data, although the amplitude is weaker than the other data sets

  1. Quality assessment of ground-based microwave measurements of chlorine monoxide, ozone, and nitrogen dioxide from the NDSC radiometer at the Plateau de Bure

    Directory of Open Access Journals (Sweden)

    P. Ricaud

    2004-06-01

    Full Text Available A ground-based microwave radiometer dedicated to chlorine monoxide (ClO measurements around 278GHz has been in operation from December 1993-June 1996 at the Plateau de Bure, France (45° N, 5.9° E, 2500m altitude. It belongs to the international Network for the Detection of Stratospheric Change. A detailed study of both measurements and retrieval schemes has been undertaken. Although dedicated to the measurements of ClO, simultaneous profiles of O3, ClO and NO2, together with information about the instrumental baseline, have been retrieved using the optimal estimation method. The vertical profiles have been compared with other ground-based microwave data, satellite-borne data and model results. Data quality shows: 1 the weak sensitivity of the instrument that obliges to make time averages over several hours; 2 the site location where measurements of good opacities are possible for only a few days per year; 3 the baseline undulation affecting all the spectra, an issue common to all the microwave instruments; 4 the slow drift of some components affecting frequencies by 3-4MHz within a couple of months. Nevertheless, when temporally averaging data over a few days, ClO temporal variations (diurnal and over several weeks in winter 1995 from 35-50km are consistent with model results and satellite data, particularly at the peak altitude around 40km, although temporal coincidences are infrequent in winter 1995. In addition to ClO, it is possible to obtain O3 information from 30-60km whilst the instrument is not optimized at all for this molecule. Retrievals of O3 are reasonable when compared with model and another ground-based data set, although the lowermost layers are affected by the contamination of baseline remnants. Monthly-averaged diurnal variations of NO2 are detected at 40km and appear in agreement with photochemical model results and satellite zonally-averaged data, although the amplitude

  2. Investigations of the Diurnal Variation of Vertical HCHO Profiles Based on MAX-DOAS Measurements in Beijing: Comparisons with OMI Vertical Column Data

    Directory of Open Access Journals (Sweden)

    Hanlim Lee

    2015-11-01

    Full Text Available An investigation into the diurnal characteristics of vertical formaldehyde (HCHO profiles was conducted based on multi-axis differential optical absorption spectroscopy (MAX-DOAS measurements in Beijing during the CAREBEIJING campaign, covering a month-long period through August and September 2006. Vertical HCHO profiles were retrieved based on a combined differential optical absorption spectroscopy (DOAS technique and an optimal estimation method (OEM. The HCHO volume-mixing ratio (VMR was found to be highest in the layer from the surface up to an altitude of 1 km and to decrease with altitude above this layer. In all retrieved profiles, HCHO was not detected in the layer from 3–4 km. Over the diurnal cycle, the HCHO VMR values were generally highest at 15:00 local time (LT and were lower in the morning and late afternoon. The mean HCHO VMRs were 6.17, 1.82, and 0.80 ppbv for the 0–1, 1–2, and 2–3-km layers, respectively, at 15:00 LT, whereas they were 3.54 (4.79, 1.06 (1.43, and 0.46 (0.63 ppbv for the 0–1, 1–2, and 2–3-km layers, respectively, at 09:00 (17:00 LT. The HCHO VMRs reached their highest values at 15:00 LT on August 19, which were 17.71, 5.20, and 2.31 ppbv for the 0–1, 1–2, and 2–3-km layers, respectively. This diurnal pattern implies that the photo-oxidation of volatile organic compounds (VOCs was most active at 15:00 LT for several days during the campaign period. In a comparison of the derived HCHO VCDs with those obtained from the Ozone Monitoring Instrument (OMI measurements, the HCHO vertical column density (VCD values obtained from the OMI measurements tend to be smaller than those from the MAX-DOAS.

  3. Evaluating the quality of ground-based microwave radiometer measurements and retrievals using detrended fluctuation and spectral analysis methods

    CERN Document Server

    Ivanova, K; Shirer, H N; Ackerman, T P; Liljegren, J C; Ausloos, M

    2001-01-01

    Time series both of microwave radiometer brightness temperature measurements at 23.8 and 31.4 GHz and of retrievals of water vapor and liquid water path from these brightness temperatures are evaluated using the detrended fluctuation analysis method. As quantified by the parameter $\\alpha$, this method (i) enables identification of the time scales over which noise dominates the time series and (ii) characterizes the temporal range of correlations in the time series. The more common spectral analysis method is also used to assess the data and its results are compared with those from detrended fluctuation analysis method. The assumption that measurements should have certain scaling properties allows the quality of the measurements to be characterized. The additional assumption that the scaling properties of the measurements of an atmospheric quantity are preserved in a useful retrieval provides a means for evaluating the retrieval itself. Applying these two assumptions to microwave radiometer measurements and r...

  4. Ground-Based Remote or In Situ Measurement of Vertical Profiles of Wind in the Lower Troposphere

    Energy Technology Data Exchange (ETDEWEB)

    Clifton, Andrew; Newman, Jennifer

    2017-02-24

    Knowledge of winds in the lower troposphere is essential for a range of applications, including weather forecasting, transportation, natural hazards, and wind energy. This presentation focuses on the measurement of vertical profiles of wind in the lower troposphere for wind energy applications. This presentation introduces the information that wind energy site development and operations require, how it used, and the benefits and problems of current measurements from in-situ measurements and remote sensing. The development of commercial Doppler wind lidar systems over the last 10 years are shown, along with the lessons learned from this experience. Finally, potential developments in wind profiling aimed at reducing uncertainty and increasing data availability are introduced.

  5. Ground-based FTIR measurements of CO from the Jungfraujoch: characterisation and comparison with in situ surface and MOPITT data

    Directory of Open Access Journals (Sweden)

    B. Barret

    2003-01-01

    Full Text Available CO vertical profiles have been retrieved from solar absorption FTIR spectra recorded at the NDSC station of the Jungfraujoch (46.5º N, 8º E and 3580 m a.s.l. for the period from January 1997 to May 2001. The characterisation of these profiles has been established by an information content analysis and an estimation of the error budgets. A partial validation of the profiles has been performed through comparisons with correlative measurements. The average volume mixing ratios (vmr in the 3 km layer above the station have been compared with coincident surface measurements. The agreement between monthly means from both measurement techniques is very good, with a correlation coefficient of 0.87, and no significant bias observed. The FTIR total columns have also been compared to CO partial columns above 3580 m a.s.l. derived from the MOPITT (Measurement Of Pollution In The Troposphere instrument for the period March 2000 to May 2001. Relative to the FTIR columns, the MOPITT partial columns exhibit a positive bias of 8±8% for daytime and of 4±7% for nighttime measurements.

  6. Ground-based instrumentation for measurements of atmospheric conduction current and electric field at the South Pole

    Science.gov (United States)

    Byrne, G. J.; Benbrook, J. R.; Bering, E. A.; Few, A. A.; Morris, G. A.; Trabucco, W. J.; Paschal, E. W.

    1993-01-01

    Attention is given to instruments constructed to measure the atmospheric conduction current and the atmospheric electric field - two fundamental parameters of the global-electric circuit. The instruments were deployed at the Amundsen-Scott South Pole Station in January 1991 and are designed to operate continuously for up to one year without operator intervention. The atmospheric current flows into one hemisphere, through the electronics where it is measured, and out the other hemisphere. The electric field is measured by a field mill of the rotating dipole type. Sample data from the first days of operation at the South Pole indicate variations in the global circuit over time scales from minutes to hours to days.

  7. Comparison of ground-based and Viking Orbiter measurements of Martian water vapor - Variability of the seasonal cycle

    Science.gov (United States)

    Jakosky, B. M.; Barker, E. S.

    1984-03-01

    Earth-based observations of Mars atmospheric water vapor are presented for the 1975-1976, 1977-1978, and 1983 apparitions. Comparisons are made with near-simultaneous spacecraft measurements made from the Viking Orbiter Mars Atmospheric Water Detection experiment during 1976-1978 and with previous earth-based measurements. Differences occur between the behavior in the different years, and may be related to the Mars climate. Measurements during the southern summer in 1969 indicate a factor of three times as much water as is present at this same season in other years. This difference may have resulted from the sublimation of water from the south polar residual cap upon removal of most or all of the CO2 ice present; sublimation of all of the CO2 ice during some years could be a result of a greater thermal load being placed on the cap due to the presence of differing amounts of atmospheric dust.

  8. Studies on aerosol properties during ICARB–2006 campaign period at Hyderabad, India using ground-based measurements and satellite data

    Indian Academy of Sciences (India)

    K V S Badarinath; Shailesh Kumar Kharol

    2008-07-01

    Continuous and campaign-based aerosol field measurements are essential in understanding fundamental atmospheric aerosol processes and for evaluating their effect on global climate, environment and human life. Synchronous measurements of Aerosol Optical Depth (AOD), Black Carbon (BC) aerosol mass concentration and aerosol particle size distribution were carried out during the campaign period at tropical urban regions of Hyderabad, India. Daily satellite datasets of DMSP-OLS were processed for night-time forest fires over the Indian region in order to understand the additional sources (forest fires) of aerosol. The higher values in black carbon aerosol mass concentration and aerosol optical depth correlated well with forest fires occurring over the region. Ozone Monitoring Instrument (OMI) aerosol index (AI) variations showed absorbing aerosols over the region and correlated with ground measurements.

  9. EVALUATION OF OPPORTUNITIES OF SOLAR ENERGETICS ON THE BASIS OF ACCURATE GROUND-BASED MEASUREMENTS OF SOLAR RADIATION

    Directory of Open Access Journals (Sweden)

    Aculinin A.

    2008-04-01

    Full Text Available Expected quantity of a solar energy received by solar panel is estimated on the basis of accurate measurements of solar radiation in Kishinev. Optimal orientation of solar panels and apparent volume of the electric power generated by solar panels are determined.

  10. L-band active/passive time series measurements over a growing season usign the COMRAD ground-based SMAP

    Science.gov (United States)

    Scheduled to launch in October 2014, NASA’s Soil Moisture Active Passive (SMAP) mission will provide high-resolution global mapping of soil moisture and freeze/thaw state every 2-3 days. These new measurements of the hydrological condition of the Earth’s surface will build on data from European Spa...

  11. Coordinated airborne, spaceborne, and ground-based measurements of massive thick aerosol layers during the dry season in southern Africa

    NARCIS (Netherlands)

    Schmid, B.; Redemann, J.; Russell, P.B.; Hobbs, P.V.; Hlavka, D.L.; McGill, M.J.; Holben, B.N.; Welton, E.J.; Campbell, J.R.; Torres, O.; Kahn, R.A.; Diner, D.J.; Helmlinger, M.C.; Chu, D.A.; Robles-Gonzalez, C.; Leeuw, G.de

    2003-01-01

    During the dry season airborne campaign of the Southern African Regional Science Initiative (SAFARI 2000), coordinated observations were made of massive thick aerosol layers. These layers were often dominated by aerosols from biomass burning. We report on airborne Sun photometer measurements of aero

  12. Coordinated airborne, spaceborne, and ground-based measurements of massive thick aerosol layers during the dry season in southern Africa

    NARCIS (Netherlands)

    Schmid, B.; Redemann, J.; Russell, P.B.; Hobbs, P.V.; Hlavka, D.L.; McGill, M.J.; Holben, B.N.; Welton, E.J.; Campbell, J.R.; Torres, O.; Kahn, R.A.; Diner, D.J.; Helmlinger, M.C.; Chu, D.A.; Robles-Gonzalez, C.; Leeuw, G.de

    2003-01-01

    During the dry season airborne campaign of the Southern African Regional Science Initiative (SAFARI 2000), coordinated observations were made of massive thick aerosol layers. These layers were often dominated by aerosols from biomass burning. We report on airborne Sun photometer measurements of

  13. The Impact of Sunlight Conditions on the Consistency of Vegetation Indices in Croplands—Effective Usage of Vegetation Indices from Continuous Ground-Based Spectral Measurements

    Directory of Open Access Journals (Sweden)

    Mitsunori Ishihara

    2015-10-01

    Full Text Available A ground-based network of spectral observations is useful for ecosystem monitoring and validation of satellite data. However, these observations contain inherent uncertainties due to the change of sunlight conditions. This study investigated the impact of changing solar zenith angles and diffuse/direct light conditions on the consistency of vegetation indices (normalized difference vegetation index (NDVI and green-red vegetation index (GRVI derived from ground-based spectral measurements in three different types of cropland (paddy field, upland field, cultivated grassland in Japan. In general, the vegetation indices decreased with decreasing solar zenith angle. This response was affected significantly by the growth stage and diffuse/direct light conditions. The decreasing response of the NDVI to the decreasing solar zenith angle was high during the middle growth stage (0.4 < NDVI < 0.8. On the other hand, a similar response of the GRVI was evident except in the early growth stage (GRVI < 0. The response of vegetation indices to the solar zenith angle was evident under clear sky conditions but almost negligible under cloudy sky conditions. At large solar zenith angles, neither the NDVI nor the GRVI were affected by diffuse/direct light conditions in any growth stage. These experimental results were supported well by the results of simulations based on a physically-based canopy reflectance model (PROSAIL. Systematic selection of the data from continuous diurnal spectral measurements in consideration of the solar light conditions would be effective for accurate and consistent assessment of the canopy structure and functioning.

  14. Ground based NO2 and O3 measurements by visible spectrometer at Syowa Base (69 deg S), Antarctica

    Science.gov (United States)

    Kondo, Y.; Matthews, W. A.; Johnston, Paul V.; Hayashi, M.; Koike, M.; Iwasaka, Y.; Shimizu, A.; Budiyono, A.; Yamanouchi, T.; Aoki, S.

    1994-01-01

    The column amounts of NO2 and ozone have been measured using visible spectroscopy at Syowa Base (69 deg S) since March 1990. Ozone was also measured at the same location with a Dobson spectrometer as well as ozonesondes being flown regularly. The characteristic features of the seasonal and diurnal variations of NO2 are presented. The column ozone values from the visible spectrometers are compared with the Dobson data. The very low values of NO2 in midwinter and early spring are consistent with the conditions predicted to be needed for heterogeneous ozone destruction in early spring. In late spring and summer of 1991, NO2 amounts were considerably smaller than in 1990, presumably due to the effect of Mt. Pinatubo eruption.

  15. Tropospheric BrO column densities in the Arctic derived from satellite: retrieval and comparison to ground-based measurements

    OpenAIRE

    H Sihler; Platt, U.; Beirle, S.; Marbach, T.; S. Kühl; S. Dörner; Verschaeve, J.; Frieß, U.; Pöhler, D.; Vogel, L.; Sander, R.; T. Wagner

    2012-01-01

    During polar spring, halogen radicals like bromine monoxide (BrO) play an important role in the chemistry of tropospheric ozone destruction. Satellite measurements of the BrO distribution have become a particularly useful tool to investigate this probably natural phenomenon, but the separation of stratospheric and tropospheric partial columns of BrO is challenging. In this study, an algorithm was developed to retrieve tropospheric vertical...

  16. Comparison of Cloud Base Height Derived from a Ground-Based Infrared Cloud Measurement and Two Ceilometers

    Directory of Open Access Journals (Sweden)

    Lei Liu

    2015-01-01

    Full Text Available The cloud base height (CBH derived from the whole-sky infrared cloud-measuring system (WSIRCMS and two ceilometers (Vaisala CL31 and CL51 from November 1, 2011, to June 12, 2012, at the Chinese Meteorological Administration (CMA Beijing Observatory Station are analysed. Significant differences can be found by comparing the measurements of different instruments. More exactly, the cloud occurrence retrieved from CL31 is 3.8% higher than that from CL51, while WSIRCMS data shows 3.6% higher than ceilometers. More than 75.5% of the two ceilometers’ differences are within ±200 m and about 89.5% within ±500 m, while only 30.7% of the differences between WSIRCMS and ceilometers are within ±500 m and about 55.2% within ±1000 m. These differences may be caused by the measurement principles and CBH retrieval algorithm. A combination of a laser ceilometer and an infrared cloud instrument is recommended to improve the capability for determining cloud occurrence and retrieving CBHs.

  17. observation and analysis of the structure of winter precipitation-generating clouds using ground-based sensor measurements

    Science.gov (United States)

    Menéndez José Luis, Marcos; Gómez José Luis, Sánchez; Campano Laura, López; Ortega Eduardo, García; Suances Andrés, Merino; González Sergio, Fernández; Salvador Estíbaliz, Gascón; González Lucía, Hermida

    2015-04-01

    In this study, we used a 28-day database corresponding to December, January and February of 2011/2012 and 2012/2013 campaigns to analyze cloud structure that produced precipitation in the Sierra Norte near Madrid, Spain. We used remote sensing measurements, both active type like the K-band Micro Rain Radar (MRR) and passive type like the Radiometrics MP-3000A multichannel microwave radiometer. Using reflectivity data from the MRR, we determined the important microphysical parameters of Ice Water Content (IWC) and its integrated value over the atmospheric column, or Ice Water Path (IWP). Among the measurements taken by the MP-3000A were Liquid Water Path (LWP) and Integrated Water Vapor (IWV). By representing these data together, sharp declines in LWP and IWV were evident, coincident with IWP increases. This result indicates the ability of a K-band radar to measure the amount of ice in the atmospheric column, simultaneously revealing the Wegener-Bergeron-Findeisen mechanism. We also used a Present Weather Sensor (VPF-730; Biral Ltd., Bristol, UK) to determine the type and amount of precipitation at the surface. With these data, we used regression equations to establish the relationship between visibility and precipitation intensity. In addition, through theoretical precipitation visibility-intensity relationships, we estimated the type of crystal, degree of accretion (riming), and moisture content of fallen snow crystals.

  18. Background CO2 levels and error analysis from ground-based solar absorption IR measurements in central Mexico

    Science.gov (United States)

    Baylon, Jorge L.; Stremme, Wolfgang; Grutter, Michel; Hase, Frank; Blumenstock, Thomas

    2017-07-01

    In this investigation we analyze two common optical configurations to retrieve CO2 total column amounts from solar absorption infrared spectra. The noise errors using either a KBr or a CaF2 beam splitter, a main component of a Fourier transform infrared spectrometer (FTIR), are quantified in order to assess the relative precisions of the measurements. The configuration using a CaF2 beam splitter, as deployed by the instruments which contribute to the Total Carbon Column Observing Network (TCCON), shows a slightly better precision. However, we show that the precisions in XCO2 ( = 0.2095 ṡ size: .7em; color: #68;">Total Column CO2size: .7em; color: #68;">Total Column O2) retrieved from > 96 % of the spectra measured with a KBr beam splitter fall well below 0.2 %. A bias in XCO2 (KBr - CaF2) of +0.56 ± 0.25 ppm was found when using an independent data set as reference. This value, which corresponds to +0.14 ± 0.064 %, is slightly larger than the mean precisions obtained. A 3-year XCO2 time series from FTIR measurements at the high-altitude site of Altzomoni in central Mexico presents clear annual and diurnal cycles, and a trend of +2.2 ppm yr-1 could be determined.

  19. Estimation of leaf area index using ground-based remote sensed NDVI measurements: validation and comparison with two indirect techniques

    Energy Technology Data Exchange (ETDEWEB)

    Pontailler, J.-Y. [Univ. Paris-Sud XI, Dept. d' Ecophysiologie Vegetale, Orsay Cedex (France); Hymus, G.J.; Drake, B.G. [Smithsonian Environmental Research Center, Kennedy Space Center, Florida (United States)

    2003-06-01

    This study took place in an evergreen scrub oak ecosystem in Florida. Vegetation reflectance was measured in situ with a laboratory-made sensor in the red (640-665 nm) and near-infrared (750-950 nm) bands to calculate the normalized difference vegetation index (NDVI) and derive the leaf area index (LAI). LAI estimates from this technique were compared with two other nondestructive techniques, intercepted photosynthetically active radiation (PAR) and hemispherical photographs, in four contrasting 4 m{sup 2} plots in February 2000 and two 4m{sup 2} plots in June 2000. We used Beer's law to derive LAI from PAR interception and gap fraction distribution to derive LAI from photographs. The plots were harvested manually after the measurements to determine a 'true' LAI value and to calculate a light extinction coefficient (k). The technique based on Beer's law was affected by a large variation of the extinction coefficient, owing to the larger impact of branches in winter when LAI was low. Hemispherical photographs provided satisfactory estimates, slightly overestimated in winter because of the impact of branches or underestimated in summer because of foliage clumping. NDVI provided the best fit, showing only saturation in the densest plot (LAI = 3.5). We conclude that in situ measurement of NDVI is an accurate and simple technique to nondestructively assess LAI in experimental plots or in crops if saturation remains acceptable. (author)

  20. Annual variation of strato-mesospheric carbon monoxide measured by ground-based Fourier transform infrared spectrometry

    Directory of Open Access Journals (Sweden)

    V. Velazco

    2007-01-01

    Full Text Available We present long-term time-series of strato-mesospheric CO vertical columns measured from stations located in Antarctica, mid-latitudes and the Arctic, covering the period from 1997–2005. The instrument and the measurement technique allows the separation of tropospheric and strato-mesospheric contributions to the CO column, therefore providing information on the chemistry and dynamics both at low and high altitudes. Data from polar stations show a similar annual variability of strato-mesospheric CO with a strong maximum in late winter and spring. A small enhancement in late summer for some stations, which we call the "summer bulge", can be seen occasionally. Generally, the mid-latitude stations show no significant annual variability of strato-mesospheric CO columns. Measurements were compared with a two-dimensional chemistry-transport model of the middle atmosphere. The annual and latitudinal variations of CO are reproduced well by a model run including thermospheric CO. Comparison with two model scenarios show that the polar winter maximum is due solely to downward transport of thermospheric CO, while CHOx chemistry in the stratosphere could probably contribute to the summer maximum.

  1. Monitoring middle-atmospheric dynamics using independent ground-based wind and temperature measurements at Reunion Island

    Science.gov (United States)

    Le Pichon, Alexis; Hauchecorne, Alain; Keckhut, Philippe; Khaykin, Sergey; Camas, Jean Pierre; Payen, Guillaume; Kämpfer, Niklaus; Rüfenacht, Rolf; Ceranna, Lars

    2016-04-01

    There are very few multi-instrumented sites in the tropics and particularly in the Southern Hemisphere. In these regions, developing atmospheric sounding methods in the middle and high-atmosphere provides valuable means to improve the physical representation of deep convection in atmospheric models (breaking of gravity waves, coupling between layers) and to better characterize large-scale atmospheric perturbations (cyclones, storms, tropical convection). The Maïdo observatory at Reunion Island (21°S, 55°E) offers trans-national access to host experiments or measurement campaigns for high resolution measurements of dynamic atmospheric processes in a wide range of altitude such as Rayleigh lidar, Doppler lidar, Modem radiosonde, or microwave Doppler spectro-radiometer (WIRA, operated by Institute of Applied Physics, University of Bern). Collocated to the existing instruments, a small aperture infrasound array (CEA) has been operating continuously since 2014. In the 0.1-1 Hz band, the coherent energy is dominated by microbarom signals resulting from the non-linear interaction of large swells systems which circulate along the Antarctic Circumpolar Current (ACC). The seasonal transition in the bearings along with the stratospheric general circulation between summer and winter is clearly noted. Interestingly, the semiannual oscillation (SAO) of the zonal stratospheric wind is well captured by infrasound measurements. It manifests by opposite ducts between 30 and 60 km that persist for several weeks during the equinox period. For the ARISE project (http://arise-project.eu/), this multi-technology site opens new perspectives to study the climatology of SAO as well as poorly resolved atmospheric disturbances of the tropical middle atmosphere where data coverage is sparse.

  2. Ground based measurements on reflectance towards validating atmospheric correction algorithms on IRS-P6 AWiFS data

    Science.gov (United States)

    Rani Sharma, Anu; Kharol, Shailesh Kumar; Kvs, Badarinath; Roy, P. S.

    In Earth observation, the atmosphere has a non-negligible influence on the visible and infrared radiation which is strong enough to modify the reflected electromagnetic signal and at-target reflectance. Scattering of solar irradiance by atmospheric molecules and aerosol generates path radiance, which increases the apparent surface reflectance over dark surfaces while absorption by aerosols and other molecules in the atmosphere causes loss of brightness to the scene, as recorded by the satellite sensor. In order to derive precise surface reflectance from satellite image data, it is indispensable to apply the atmospheric correction which serves to remove the effects of molecular and aerosol scattering. In the present study, we have implemented a fast atmospheric correction algorithm to IRS-P6 AWiFS satellite data which can effectively retrieve surface reflectance under different atmospheric and surface conditions. The algorithm is based on MODIS climatology products and simplified use of Second Simulation of Satellite Signal in Solar Spectrum (6S) radiative transfer code, which is used to generate look-up-tables (LUTs). The algorithm requires information on aerosol optical depth for correcting the satellite dataset. The proposed method is simple and easy to implement for estimating surface reflectance from the at sensor recorded signal, on a per pixel basis. The atmospheric correction algorithm has been tested for different IRS-P6 AWiFS False color composites (FCC) covering the ICRISAT Farm, Patancheru, Hyderabad, India under varying atmospheric conditions. Ground measurements of surface reflectance representing different land use/land cover, i.e., Red soil, Chick Pea crop, Groundnut crop and Pigeon Pea crop were conducted to validate the algorithm and found a very good match between surface reflectance and atmospherically corrected reflectance for all spectral bands. Further, we aggregated all datasets together and compared the retrieved AWiFS reflectance with

  3. Information operator approach applied to the retrieval of the vertical distribution of atmospheric constituents from ground-based high-resolution FTIR measurements

    Directory of Open Access Journals (Sweden)

    C. Senten

    2012-01-01

    Full Text Available The analysis of high spectral resolution Fourier Transform infrared (FTIR solar absorption spectra is an important issue in remote sensing. If this is done carefully, one can obtain information, not only about the total column abundances, but also about the vertical distribution of various constituents in the atmosphere. This work introduces the application of the information operator approach for extracting vertical profile information from ground-based FTIR measurements. The algorithm is implemented and tested within the well-known retrieval code SFIT2, adapting the optimal estimation method such as to take into account only the significant contributions to the solution. In particular, we demonstrate the feasibility of the method in an application to ground-based FTIR spectra taken in the framework of the Network for the Detection of Atmospheric Composition Change (NDACC at Ile de La Réunion (21° S, 55° E. A thorough comparison is made between the original optimal estimation method, Tikhonov regularization and this alternative retrieval algorithm, regarding information content, retrieval robustness and corresponding full error budget evaluation for the target species ozone (O3, nitrous oxide (N2O, methane (CH4, and carbon monoxide (CO. It is shown that the information operator approach performs well and in most cases yields both a better accuracy and stability than the optimal estimation method. Additionally, the information operator approach has the advantage of being less sensitive to the choice of a priori information than the optimal estimation method and Tikhonov regularization. On the other hand, in general the Tikhonov regularization results seem to be slightly better than the optimal estimation method and information operator approach results when it comes to error budgets and column stability.

  4. The contribution of NOAA/CMDL ground-based measurements to understanding long-term stratospheric changes

    Science.gov (United States)

    Montzka, S. A.; Butler, J. H.; Dutton, G.; Thompson, T. M.; Hall, B.; Mondeel, D. J.; Elkins, J. W.

    2005-05-01

    The El-Nino/Southern-Oscillation (ENSO) dominates interannual climate variability and plays, therefore, a key role in seasonal-to-interannual prediction. Much is known by now about the main physical mechanisms that give rise to and modulate ENSO, but the values of several parameters that enter these mechanisms are an important unknown. We apply Extended Kalman Filtering (EKF) for both model state and parameter estimation in an intermediate, nonlinear, coupled ocean--atmosphere model of ENSO. The coupled model consists of an upper-ocean, reduced-gravity model of the Tropical Pacific and a steady-state atmospheric response to the sea surface temperature (SST). The model errors are assumed to be mainly in the atmospheric wind stress, and assimilated data are equatorial Pacific SSTs. Model behavior is very sensitive to two key parameters: (i) μ, the ocean-atmosphere coupling coefficient between SST and wind stress anomalies; and (ii) δs, the surface-layer coefficient. Previous work has shown that δs determines the period of the model's self-sustained oscillation, while μ measures the degree of nonlinearity. Depending on the values of these parameters, the spatio-temporal pattern of model solutions is either that of a delayed oscillator or of a westward propagating mode. Estimation of these parameters is tested first on synthetic data and allows us to recover the delayed-oscillator mode starting from model parameter values that correspond to the westward-propagating case. Assimilation of SST data from the NCEP-NCAR Reanalysis-2 shows that the parameters can vary on fairly short time scales and switch between values that approximate the two distinct modes of ENSO behavior. Rapid adjustments of these parameters occur, in particular, during strong ENSO events. Ways to apply EKF parameter estimation efficiently to state-of-the-art coupled ocean--atmosphere GCMs will be discussed.

  5. Dust impact on surface solar irradiance assessed with model simulations, satellite observations and ground-based measurements

    Science.gov (United States)

    Kosmopoulos, Panagiotis G.; Kazadzis, Stelios; Taylor, Michael; Athanasopoulou, Eleni; Speyer, Orestis; Raptis, Panagiotis I.; Marinou, Eleni; Proestakis, Emmanouil; Solomos, Stavros; Gerasopoulos, Evangelos; Amiridis, Vassilis; Bais, Alkiviadis; Kontoes, Charalabos

    2017-07-01

    This study assesses the impact of dust on surface solar radiation focussing on an extreme dust event. For this purpose, we exploited the synergy of AERONET measurements and passive and active satellite remote sensing (MODIS and CALIPSO) observations, in conjunction with radiative transfer model (RTM) and chemical transport model (CTM) simulations and the 1-day forecasts from the Copernicus Atmosphere Monitoring Service (CAMS). The area of interest is the eastern Mediterranean where anomalously high aerosol loads were recorded between 30 January and 3 February 2015. The intensity of the event was extremely high, with aerosol optical depth (AOD) reaching 3.5, and optical/microphysical properties suggesting aged dust. RTM and CTM simulations were able to quantify the extent of dust impact on surface irradiances and reveal substantial reduction in solar energy exploitation capacity of PV and CSP installations under this high aerosol load. We found that such an extreme dust event can result in Global Horizontal Irradiance (GHI) attenuation by as much as 40-50 % and a much stronger Direct Normal Irradiance (DNI) decrease (80-90 %), while spectrally this attenuation is distributed to 37 % in the UV region, 33 % in the visible and around 30 % in the infrared. CAMS forecasts provided a reliable available energy assessment (accuracy within 10 % of that obtained from MODIS). Spatially, the dust plume resulted in a zonally averaged reduction of GHI and DNI of the order of 150 W m-2 in southern Greece, and a mean increase of 20 W m-2 in the northern Greece as a result of lower AOD values combined with local atmospheric processes. This analysis of a real-world scenario contributes to the understanding and quantification of the impact range of high aerosol loads on solar energy and the potential for forecasting power generation failures at sunshine-privileged locations where solar power plants exist, are under construction or are being planned.

  6. Comparing data obtained from ground-based measurements of the total contents of O3, HNO3,HCl, and NO2 and from their numerical simulation

    Science.gov (United States)

    Virolainen, Ya. A.; Timofeyev, Yu. M.; Polyakov, A. V.; Ionov, D. V.; Kirner, O.; Poberovskii, A. V.; Imhasin, H. Kh.

    2016-01-01

    Chemistry climate models of the gas composition of the atmosphere make it possible to simulate both space and time variations in atmospheric trace-gas components (TGCs) and predict their changes. Both verification and improvement of such models on the basis of a comparison with experimental data are of great importance. Data obtained from the 2009-2012 ground-based spectrometric measurements of the total contents (TCs) of a number of TGCs (ozone, HNO3, HCl, and NO2) in the atmosphere over the St. Petersburg region (Petergof station, St. Petersburg State University) have been compared to analogous EMAC model data. Both daily and monthly means of their TCs for this period have been analyzed in detail. The seasonal dependences of the TCs of the gases under study are shown to be adequately reproduced by the EMAC model. At the same time, a number of disagreements (including systematic ones) have been revealed between model and measurement data. Thus, for example, the EMAC model underestimates the TCs of NO2, HCl, and HNO3, when compared to measurement data, on average, by 14, 22, and 35%, respectively. However, the TC of ozone is overestimated by the EMAC model (on average, by 12%) when compared to measurement data. In order to reveal the reasons for such disagreements between simulated and measured data on the TCs of TGCs, it is necessary to continue studies on comparisons of the contents of TGCs in different atmospheric layers.

  7. Measuring Gap Fraction, Element Clumping Index and LAI in Sierra Forest Stands Using a Full-Waveform Ground-Based Lidar

    Science.gov (United States)

    Zhao, Feng; Strahler, Alan H.; Crystal L. Schaaf; Yao, Tian; Yang, Xiaoyuan; Wang, Zhuosen; Schull, Mitchell A.; Roman, Miguel O.; Woodcock, Curtis E.; Olofsson, Pontus; Ni-Meister, Wenge; Jupp, David L. B.; Lovell, Jenny L.; Culvenor, Darius S.; Newnham, Glenn J.

    2012-01-01

    The Echidna Validation Instrument (EVI), a ground-based, near-infrared (1064 nm) scanning lidar, provides gap fraction measurements, element clumping index measurements, effective leaf area index (LAIe) and leaf area index (LAI) measurements that are statistically similar to those from hemispherical photos. In this research, a new method integrating the range dimension is presented for retrieving element clumping index using a unique series of images of gap probability (Pgap) with range from EVI. From these images, we identified connected gap components and found the approximate physical, rather than angular, size of connected gap component. We conducted trials at 30 plots within six conifer stands of varying height and stocking densities in the Sierra National Forest, CA, in August 2008. The element clumping index measurements retrieved from EVI Pgap image series for the hinge angle region are highly consistent (R2=0.866) with those of hemispherical photos. Furthermore, the information contained in connected gap component size profiles does account for the difference between our method and gap-size distribution theory based method, suggesting a new perspective to measure element clumping index with EVI Pgap image series and also a potential advantage of three dimensional Lidar data for element clumping index retrieval. Therefore further exploration is required for better characterization of clumped condition from EVI Pgap image series.

  8. Design and application of a mobile ground-based observatory for continuous measurements of atmospheric trace-gas and criteria pollutant species

    Directory of Open Access Journals (Sweden)

    S. E. Bush

    2015-01-01

    Full Text Available Ground-based measurements of atmospheric trace gas species and criteria pollutants are essential for understanding emissions dynamics across space and time. Gas composition in the surface 50 m has the greatest direct impacts on human health as well as ecosystem processes, hence data at this level is necessary for addressing carbon cycle and public health related questions. However, such surface data are generally associated with stationary measurement towers, where spatial representation is limited due to the high cost of establishing and maintaining an extensive network of measurement stations. We describe here a compact mobile laboratory equipped to provide high-precision, high-frequency, continuous, on-road synchronous measurements of CO2, CO, CH4, H2O, NOx, O3, aerosol, meteorological, and geospatial position data. The mobile laboratory has been deployed across the western USA. In addition to describing the vehicle and its capacity, we present data that illustrate the use of the laboratory as a powerful tool for investigating the spatial structure of urban trace gas emissions and criteria pollutants at spatial scales ranging from single streets to whole ecosystem and regional scales. We identify fugitive urban CH4 emissions and assess the magnitude of CH4 emissions from known point sources. We illustrate how such a mobile laboratory can be used to better understand emissions dynamics and quantify emissions ratios associated with trace gas emissions from wildfire incidents. Lastly, we discuss additional mobile laboratory applications in health and urban metabolism.

  9. Design and application of a mobile ground-based observatory for continuous measurements of atmospheric trace gas and criteria pollutant species

    Science.gov (United States)

    Bush, S. E.; Hopkins, F. M.; Randerson, J. T.; Lai, C.-T.; Ehleringer, J. R.

    2015-08-01

    Ground-based measurements of atmospheric trace gas species and criteria pollutants are essential for understanding emissions dynamics across space and time. Gas composition in the lower 50 m of the atmosphere has the greatest direct impacts on human health as well as ecosystem processes; hence data at this level are necessary for addressing carbon-cycle- and public-health-related questions. However, such surface data are generally associated with stationary measurement towers, where spatial representation is limited due to the high cost of establishing and maintaining an extensive network of measurement stations. We describe here a compact mobile laboratory equipped to provide high-precision, high-frequency, continuous, on-road synchronous measurements of CO2, CO, CH4, H2O, NOx, O3, aerosol, meteorological, and geospatial position data. The mobile laboratory has been deployed across the western USA. In addition to describing the vehicle and its capacity, we present data that illustrate the use of the laboratory as a powerful tool for investigating the spatial structure of urban trace gas emissions and criteria pollutants at spatial scales ranging from single streets to whole ecosystem and regional scales. We assess the magnitude of known point sources of CH4 and also identify fugitive urban CH4 emissions. We illustrate how such a mobile laboratory can be used to better understand emissions dynamics and quantify emissions ratios associated with trace gas emissions from wildfire incidents. Lastly, we discuss additional mobile laboratory applications in health and urban metabolism.

  10. Design and application of a mobile ground-based observatory for continuous measurements of atmospheric trace-gas and criteria pollutant species

    Science.gov (United States)

    Bush, S. E.; Hopkins, F. M.; Randerson, J. T.; Lai, C.-T.; Ehleringer, J. R.

    2015-01-01

    Ground-based measurements of atmospheric trace gas species and criteria pollutants are essential for understanding emissions dynamics across space and time. Gas composition in the surface 50 m has the greatest direct impacts on human health as well as ecosystem processes, hence data at this level is necessary for addressing carbon cycle and public health related questions. However, such surface data are generally associated with stationary measurement towers, where spatial representation is limited due to the high cost of establishing and maintaining an extensive network of measurement stations. We describe here a compact mobile laboratory equipped to provide high-precision, high-frequency, continuous, on-road synchronous measurements of CO2, CO, CH4, H2O, NOx, O3, aerosol, meteorological, and geospatial position data. The mobile laboratory has been deployed across the western USA. In addition to describing the vehicle and its capacity, we present data that illustrate the use of the laboratory as a powerful tool for investigating the spatial structure of urban trace gas emissions and criteria pollutants at spatial scales ranging from single streets to whole ecosystem and regional scales. We identify fugitive urban CH4 emissions and assess the magnitude of CH4 emissions from known point sources. We illustrate how such a mobile laboratory can be used to better understand emissions dynamics and quantify emissions ratios associated with trace gas emissions from wildfire incidents. Lastly, we discuss additional mobile laboratory applications in health and urban metabolism.

  11. Climatology of Ultra Violet (UV) irradiance as measured through the Belgian ground-based monitoring network during the time period of 1995-2014

    Science.gov (United States)

    Pandey, Praveen; Gillotay, Didier; Depiesse, Cedric

    2016-04-01

    In this study we describe the network of ground-based ultraviolet (UV) radiation monitoring stations in Belgium. The evolution of the entire network, together with the details of measuring instruments is given. The observed cumulative irradiances -UVB, UVA and total solar irradiance (TSI)- over the course of measurement for three stations -a northern (Ostende), central (Uccle) and a southern (Redu)- are shown. The longest series of measurement shown in this study is at Uccle, Brussels, from 1995 till 2014. Thus, the variation of the UV index (UVI), together with the variation of irradiances during summer and winter months at Uccle are shown as a part of this climatological study. The trend of UVB irradiance over the above mentioned three stations is shown. This UVB trend is studied in conjunction with the long-term satellite-based total column ozone value over Belgium, which shows two distinct trends marked by a change point. The total column ozone trend following the change point is positive. It is also seen that the UVB trend is positive for the urban/sub-urban sites: Uccle and Redu. Whereas the UVB trend at Ostende, which is a coastal site, is not positive. A possible explanation of this relation between total column ozone and UVB trend could be associated with aerosols, which is shown in this paper by means of a radiative transfer model based study -as a part of a preliminary investigation. It is seen that the UVI is influenced by the type of aerosols.

  12. An Investigation of Widespread Ozone Damage to the Soybean Crop in the Upper Midwest Determined From Ground-Based and Satellite Measurements

    Science.gov (United States)

    Fishman, Jack; Creilson, John K.; Parker, Peter A.; Ainsworth, Elizabeth A.; Vining, G. Geoffrey; Szarka, John; Booker, Fitzgerald L.; Xu, Xiaojing

    2010-01-01

    Elevated concentrations of ground-level ozone (O3) are frequently measured over farmland regions in many parts of the world. While numerous experimental studies show that O3 can significantly decrease crop productivity, independent verifications of yield losses at current ambient O3 concentrations in rural locations are sparse. In this study, soybean crop yield data during a 5-year period over the Midwest of the United States were combined with ground and satellite O3 measurements to provide evidence that yield losses on the order of 10% could be estimated through the use of a multiple linear regression model. Yield loss trends based on both conventional ground-based instrumentation and satellite-derived tropospheric O3 measurements were statistically significant and were consistent with results obtained from open-top chamber experiments and an open-air experimental facility (SoyFACE, Soybean Free Air Concentration Enrichment) in central Illinois. Our analysis suggests that such losses are a relatively new phenomenon due to the increase in background tropospheric O3 levels over recent decades. Extrapolation of these findings supports previous studies that estimate the global economic loss to the farming community of more than $10 billion annually.

  13. A long-term study of aerosol-cloud interactions and their radiative effect at the Southern Great Plains using ground-based measurements

    Science.gov (United States)

    Sena, Elisa T.; McComiskey, Allison; Feingold, Graham

    2016-09-01

    Empirical estimates of the microphysical response of cloud droplet size distribution to aerosol perturbations are commonly used to constrain aerosol-cloud interactions in climate models. Instead of empirical microphysical estimates, here macroscopic variables are analyzed to address the influence of aerosol particles and meteorological descriptors on instantaneous cloud albedo and the radiative effect of shallow liquid water clouds. Long-term ground-based measurements from the Atmospheric Radiation Measurement (ARM) program over the Southern Great Plains are used. A broad statistical analysis was performed on 14 years of coincident measurements of low clouds, aerosol, and meteorological properties. Two cases representing conflicting results regarding the relationship between the aerosol and the cloud radiative effect were selected and studied in greater detail. Microphysical estimates are shown to be very uncertain and to depend strongly on the methodology, retrieval technique and averaging scale. For this continental site, the results indicate that the influence of the aerosol on the shallow cloud radiative effect and albedo is weak and that macroscopic cloud properties and dynamics play a much larger role in determining the instantaneous cloud radiative effect compared to microphysical effects. On a daily basis, aerosol shows no correlation with cloud radiative properties (correlation = -0.01 ± 0.03), whereas the liquid water path shows a clear signal (correlation = 0.56 ± 0.02).

  14. The CU 2-D-MAX-DOAS instrument – Part 2: Raman scattering probability measurements and retrieval of aerosol optical properties

    Energy Technology Data Exchange (ETDEWEB)

    Ortega, Ivan; Coburn, Sean; Berg, Larry K.; Lantz, Kathy; Michalsky, Joseph; Ferrare, Richard A.; Hair, Johnathan W.; Hostetler, Chris A.; Volkamer, Rainer

    2016-01-01

    The multiannual global mean of aerosol optical depth at 550 nm (AOD550) over land is ~0.19, and that over oceans is ~0.13. About 45 % of the Earth surface shows AOD550 smaller than 0.1. There is a need for measurement techniques that are optimized to measure aerosol optical properties under low AOD conditions. We present an inherently calibrated retrieval (i.e., no need for radiance calibration) to simultaneously measure AOD and the aerosol phase function parameter, g, based on measurements of azimuth distributions of the Raman scattering probability (RSP), the near-absolute rotational Raman scattering (RRS) intensity. We employ radiative transfer model simulations to show that for solar azimuth RSP measurements at solar elevation and solar zenith angle (SZA) smaller than 80°, RSP is insensitive to the vertical distribution of aerosols and maximally sensitive to changes in AOD and g under near-molecular scattering conditions. The University of Colorado two-dimensional Multi-AXis Differential Optical Absorption Spectroscopy (CU 2-D-MAX-DOAS) instrument was deployed as part of the Two Column Aerosol Project (TCAP) at Cape Cod, MA, during the summer of 2012 to measure direct sun spectra and RSP from scattered light spectra at solar relative azimuth angles (SRAAs) between 5 and 170°. During two case study days with (1) high aerosol load (17 July, 0.3 < AOD430 < 0.6) and (2) near-molecular scattering conditions (22 July, AOD430 < 0.13) we compare RSP-based retrievals of AOD430 and g with data from a co-located CIMEL sun photometer, Multi-Filter Rotating Shadowband Radiometer (MFRSR), and an airborne High Spectral Resolution Lidar (HSRL-2). The average difference (relative to DOAS) for AOD430 is +0.012 ± 0.023 (CIMEL), -0.012 ± 0.024 (MFRSR), -0.011 ± 0.014 (HSRL-2), and +0.023 ± 0.013 (CIMELAOD - MFRSRAOD) and yields the following

  15. Single snapshot DOA estimation

    Science.gov (United States)

    Häcker, P.; Yang, B.

    2010-10-01

    In array signal processing, direction of arrival (DOA) estimation has been studied for decades. Many algorithms have been proposed and their performance has been studied thoroughly. Yet, most of these works are focused on the asymptotic case of a large number of snapshots. In automotive radar applications like driver assistance systems, however, only a small number of snapshots of the radar sensor array or, in the worst case, a single snapshot is available for DOA estimation. In this paper, we investigate and compare different DOA estimators with respect to their single snapshot performance. The main focus is on the estimation accuracy and the angular resolution in multi-target scenarios including difficult situations like correlated targets and large target power differences. We will show that some algorithms lose their ability to resolve targets or do not work properly at all. Other sophisticated algorithms do not show a superior performance as expected. It turns out that the deterministic maximum likelihood estimator is a good choice under these hard conditions.

  16. CO measurements from the ACE-FTS satellite instrument: data analysis and validation using ground-based, airborne and spaceborne observations

    Directory of Open Access Journals (Sweden)

    C. Clerbaux

    2007-10-01

    Full Text Available The Atmospheric Chemistry Experiment (ACE mission was launched in August 2003 to sound the atmosphere by solar occultation. Carbon monoxide (CO, a good tracer of pollution plumes and atmospheric dynamics, is one of the key species provided by the primary instrument, the ACE-Fourier Transform Spectrometer (ACE-FTS. This instrument performs measurements in both the CO 1-0 and 2-0 ro-vibrational bands, from which vertically resolved CO concentration profiles are retrieved, from the mid-troposphere to the thermosphere. This paper presents an updated description of the ACE-FTS version 2.2 CO data product, along with a comprehensive validation of these profiles using available observations (February 2004 to December 2006. We have compared the CO partial columns with ground-based measurements using Fourier transform infrared spectroscopy and millimeter wave radiometry, and the volume mixing ratio profiles with airborne (both high-altitude balloon flight and airplane observations. CO satellite observations provided by nadir-looking instruments (MOPITT and TES as well as limb-viewing remote sensors (MIPAS, SMR and MLS were also compared with the ACE-FTS CO products. We show that the ACE-FTS measurements provide CO profiles with small retrieval errors (better than 5% from the upper troposphere to 40 km, and better than 10% above. These observations agree well with the correlative measurements, considering the rather loose coincidence criteria in some cases. Based on the validation exercise we assess the following uncertainties to the ACE-FTS measurement data: better than 15% in the upper troposphere (8–12 km, than 30% in the lower stratosphere (12–30 km, and than 25% from 30 to 100 km.

  17. CO measurements from the ACE-FTS satellite instrument: data analysis and validation using ground-based, airborne and spaceborne observations

    Directory of Open Access Journals (Sweden)

    C. Clerbaux

    2008-05-01

    Full Text Available The Atmospheric Chemistry Experiment (ACE mission was launched in August 2003 to sound the atmosphere by solar occultation. Carbon monoxide (CO, a good tracer of pollution plumes and atmospheric dynamics, is one of the key species provided by the primary instrument, the ACE-Fourier Transform Spectrometer (ACE-FTS. This instrument performs measurements in both the CO 1-0 and 2-0 ro-vibrational bands, from which vertically resolved CO concentration profiles are retrieved, from the mid-troposphere to the thermosphere. This paper presents an updated description of the ACE-FTS version 2.2 CO data product, along with a comprehensive validation of these profiles using available observations (February 2004 to December 2006. We have compared the CO partial columns with ground-based measurements using Fourier transform infrared spectroscopy and millimeter wave radiometry, and the volume mixing ratio profiles with airborne (both high-altitude balloon flight and airplane observations. CO satellite observations provided by nadir-looking instruments (MOPITT and TES as well as limb-viewing remote sensors (MIPAS, SMR and MLS were also compared with the ACE-FTS CO products. We show that the ACE-FTS measurements provide CO profiles with small retrieval errors (better than 5% from the upper troposphere to 40 km, and better than 10% above. These observations agree well with the correlative measurements, considering the rather loose coincidence criteria in some cases. Based on the validation exercise we assess the following uncertainties to the ACE-FTS measurement data: better than 15% in the upper troposphere (8–12 km, than 30% in the lower stratosphere (12–30 km, and than 25% from 30 to 100 km.

  18. High Resolution Direction of Arrival (DOA Estimation Based on Improved Orthogonal Matching Pursuit (OMP Algorithm by Iterative Local Searching

    Directory of Open Access Journals (Sweden)

    Renbiao Wu

    2013-08-01

    Full Text Available DOA (Direction of Arrival estimation is a major problem in array signal processing applications. Recently, compressive sensing algorithms, including convex relaxation algorithms and greedy algorithms, have been recognized as a kind of novel DOA estimation algorithm. However, the success of these algorithms is limited by the RIP (Restricted Isometry Property condition or the mutual coherence of measurement matrix. In the DOA estimation problem, the columns of measurement matrix are steering vectors corresponding to different DOAs. Thus, it violates the mutual coherence condition. The situation gets worse when there are two sources from two adjacent DOAs. In this paper, an algorithm based on OMP (Orthogonal Matching Pursuit, called ILS-OMP (Iterative Local Searching-Orthogonal Matching Pursuit, is proposed to improve DOA resolution by Iterative Local Searching. Firstly, the conventional OMP algorithm is used to obtain initial estimated DOAs. Then, in each iteration, a local searching process for every estimated DOA is utilized to find a new DOA in a given DOA set to further decrease the residual. Additionally, the estimated DOAs are updated by substituting the initial DOA with the new one. The simulation results demonstrate the advantages of the proposed algorithm.

  19. High resolution direction of arrival (DOA) estimation based on improved orthogonal matching pursuit (OMP) algorithm by iterative local searching.

    Science.gov (United States)

    Wang, Wenyi; Wu, Renbiao

    2013-08-22

    DOA (Direction of Arrival) estimation is a major problem in array signal processing applications. Recently, compressive sensing algorithms, including convex relaxation algorithms and greedy algorithms, have been recognized as a kind of novel DOA estimation algorithm. However, the success of these algorithms is limited by the RIP (Restricted Isometry Property) condition or the mutual coherence of measurement matrix. In the DOA estimation problem, the columns of measurement matrix are steering vectors corresponding to different DOAs. Thus, it violates the mutual coherence condition. The situation gets worse when there are two sources from two adjacent DOAs. In this paper, an algorithm based on OMP (Orthogonal Matching Pursuit), called ILS-OMP (Iterative Local Searching-Orthogonal Matching Pursuit), is proposed to improve DOA resolution by Iterative Local Searching. Firstly, the conventional OMP algorithm is used to obtain initial estimated DOAs. Then, in each iteration, a local searching process for every estimated DOA is utilized to find a new DOA in a given DOA set to further decrease the residual. Additionally, the estimated DOAs are updated by substituting the initial DOA with the new one. The simulation results demonstrate the advantages of the proposed algorithm.

  20. Establishing a long-term, global stratospheric HNO3 data record combining UARS MLS with Aura MLS data by means of ground-based measurements

    Science.gov (United States)

    Fiorucci, I.; Muscari, G.; Froidevaux, L.; Santee, M. L.; de Zafra, R. L.

    2009-12-01

    Nitric Acid (HNO3) is a major player in processes controlling stratospheric ozone depletion. It is a primary reservoir for reactive nitrogen in the stratosphere and has a key role in both the activation and the deactivation of chlorine and bromine species. Since 1993 HNO3 observations have been carried out by means of a Ground-Based Millimeter-wave Spectrometer (GBMS) from a variety of sites in both hemispheres, at polar and mid-latitudes. The GBMS observes a cluster of weak emission lines centered at 269 GHz, with a pass band of 600 MHz and a resolution of 1 MHz. The retrieval of vertical profiles from the pressure-blended multiple line spectra is carried out with an Optimal Estimation Method. The GBMS provides HNO3 profiles from ~15 up to 50 km, with a vertical resolution of 6-8 km and a total uncertainty of ~15%. GBMS HNO3 measurements have been used within GOZCARDS (Global Ozone Chemistry and Related Trace gas Data Records for the Stratosphere), a multi-year MEaSUREs project, aimed at developing a long-term, commonly-formatted Earth system data record (ESDR) of stratospheric constituents relevant to the issues of ozone decline and expected recovery. This data record is based mainly on satellite-derived measurements. Nevertheless, ground-based observations can be critically used for assessing offsets between satellite data sets, as well as to fill gaps in temporal coverage when possible. Since the GBMS has been operated for more than 15 years (with minor instrumental upgrading), the GBMS HNO3 data record is well-suited for the GOZCARDS objectives; it offers a unique opportunity for the cross-calibration of HNO3 measurements from the NASA/JPL Microwave Limb Sounder (MLS) experiments (aboard the Upper Atmosphere Research Satellite (UARS) from 1991 to 1999, and on the Earth Observing System (EOS) Aura mission from 2004 to date). In this study we compare Aura MLS observations and GBMS HNO3 measurements obtained from the Italian Alpine station of Plateau Rosa, during

  1. Summertime tropospheric ozone enhancement associated with a cold front passage due to stratosphere-to-troposphere transport and biomass burning: Simultaneous ground-based lidar and airborne measurements

    Science.gov (United States)

    Kuang, Shi; Newchurch, Michael J.; Johnson, Matthew S.; Wang, Lihua; Burris, John; Pierce, Robert B.; Eloranta, Edwin W.; Pollack, Ilana B.; Graus, Martin; de Gouw, Joost; Warneke, Carsten; Ryerson, Thomas B.; Markovic, Milos Z.; Holloway, John S.; Pour-Biazar, Arastoo; Huang, Guanyu; Liu, Xiong; Feng, Nan

    2017-01-01

    Stratosphere-to-troposphere transport (STT) and biomass burning (BB) are two important natural sources for tropospheric ozone that can result in elevated ozone and air-quality episode events. High-resolution observations of multiple related species are critical for complex ozone source attribution. In this article, we present an analysis of coinciding ground-based and airborne observations, including ozone lidar, ozonesonde, high spectral resolution lidar (HSRL), and multiple airborne in situ measurements, made on 28 and 29 June 2013 during the Southeast Nexus field campaign. The ozone lidar and HSRL reveal detailed ozone and aerosol structures as well as the temporal evolution associated with a cold front passage. The observations also captured two enhanced (+30 ppbv) ozone layers in the free troposphere (FT), which were determined from this study to be caused by a mixture of BB and stratospheric sources. The mechanism for this STT is tropopause folding associated with a cutoff upper level low-pressure system according to the analysis of its potential vorticity structure. The depth of the tropopause fold appears to be shallow for this case compared to events observed in other seasons; however, the impact on lower tropospheric ozone was clearly observed. This event suggests that strong STT may occur in the southeast United States during the summer and can potentially impact lower troposphere during these times. Statistical analysis of the airborne observations of trace gases suggests a coincident influence of BB transport in the FT impacting the vertical structure of ozone during this case study.

  2. Aerosol backscatter measurements at 10. 6 micrometers with airborne and ground-based CO sub 2 Doppler lidars over the Colorado high plains. 2. Backscatter structure

    Energy Technology Data Exchange (ETDEWEB)

    Bowdle, D.A. (Univ. of Alabama, Huntsville (USA)); Rothermel, J. (NASA Marshall Space Flight Center, Huntsville, AL (USA)); Vaughan, J.M. (Royal Signals and Radar Establishment, Worcestershire (England)); Post, M.J. (National Oceanic and Atmospheric Administration, Boulder, CO (USA))

    1991-03-20

    Measurements of tropospheric aerosol volume backscatter coefficients at 10.6-{mu}m wavelength were obtained with airborne continuous wave and ground-based pulsed CO{sub 2} Doppler lidars over the Colorado High Plains during a 20-day period in summer 1982. A persistent 'background' layer was found between 6- and 10-km altitude, with a generally uniform backscatter mixing ratio of {approximately}10{sup {minus}10} m{sup 2} kg{sup {minus}1} sr{sup {minus}1}. The upper boundary of this background layer varied with the tropopause height; the lower boundary varied with the strength and diurnal cycle of convective mixing in the planetary boundary layer (PBL). For quiescent meteorological conditions the transition from the PBL to the background layer was usually very sharp, with backscatter decreases sometimes as large as 3 decades in {approximately}70 m. Sharp gradients were also found at the boundaries of shallow (tens of meters) subvisible cirrus clouds. For less stable conditions, associated with vertical aerosol transport by deep comuliform clouds, backscatter tended to decrease exponentially with altitude.

  3. Aerosol backscatter measurements at 10. 6 micrometers with airborne and ground-based CO sub 2 Doppler lidars over the Colorado high plains. 1. Lidar intercomparison

    Energy Technology Data Exchange (ETDEWEB)

    Bowdle, D.A. (Univ. of Alabama, Huntsville (USA)); Rothermel, J. (NASA Marshall Space Flight Center, Huntsville, AL (USA)); Vaughan, J.M.; Brown, D.W. (Royal Signals and Radar Establishment, Worcestershire (England)); Post, M.J. (National Oceanic and Atmospheric Administration, Boulder, CO (USA))

    1991-03-20

    An airborne continuous wave (CW) focused CO{sub 2} Doppler lidar and a ground-based pulsed CO{sub 2} Doppler lidar were used to obtain seven pairs of comparative measurements of tropospheric aerosol backscatter profiles at 10.6 {mu}m wavelength, near Denver, Colorado, during a 20-day period in July 1982. In regions of uniform backscatter the two lidars show good agreement, with differences usually less than {approximately}50% near 8-km altitude and less than a factor of 2 or 3 elsewhere but with the pulsed lidar often lower than the CW lidar. Near sharp backscatter gradients the two lidars show poorer agreement, with the pulsed lidar usually higher than the CW lidar. Most discrepancies arise from a combination of atmospheric factors and instrument factors, particularly small-scale areal and temporal backscatter heterogeneity above the planetary boundary layer, unusual large-scale vertical backscatter structure in the upper troposphere and lower stratosphere, and differences in the spatial resolution, detection threshold, and noise estimation for the two lidars.

  4. Simultaneous ground-based and airborne measurements of biogenic VOC oxidation products using iodide-adduct HR-ToF-CIMS in the Southeast U.S

    Science.gov (United States)

    Lee, B.; Mohr, C.; Lopez-Hilfiker, F.; Warneke, C.; Graus, M.; Gilman, J.; Lerner, B. M.; Pollack, I. B.; Ryerson, T. B.; Roberts, J. M.; Edwards, P. M.; Brown, S. S.; Holloway, J.; Aikin, K.; Dube, W. P.; Liao, J.; Welti, A.; Middlebrook, A. M.; Nowak, J. B.; Neuman, J. A.; Brioude, J. F.; McKeen, S. A.; Hanisco, T. F.; Kaiser, J.; Keutsch, F. N.; Wolfe, G. M.; Hallquist, M.; Trainer, M.; De Gouw, J. A.; Thornton, J. A.

    2013-12-01

    We present measurements by two high-resolution time-of-flight chemical-ionization mass spectrometers (HR-ToF-CIMS) during the Southeast Atmosphere Study in June and July of 2013. Both HR-ToF-CIMS used iodide as the reagent ion, which provides minimum fragmentation during ionization. Isoprene and monoterpene oxidation byproducts such as hydroxy hydroperoxides, carboxylic acids and organic nitrates, were ubiquitous in the mass spectra. In addition, we observed select inorganic gases such as N2O5 and ClNO2. The flight instrument was deployed aboard the NOAA WP-3D during SENEX, which explored the lower atmosphere over the Southeast U.S., logging a total of 125 flight hours. These measurements provide insight into the spatial and temporal variation of these types of compounds and the influence of natural gas fields, power plants, biomass burning, urban and biogenic emissions on their abundance under both day and nighttime conditions. The ground-based instrument was located near Brent, Alabama as part of the SOAS campaign and utilized the Filter Inlet for Gas and AEROsol (FIGAERO) - developed at the University of Washington - which allows measurement of both the gas and particle phases. Continuous observations spanning more than 4 weeks show the diurnal variability and the influence of meteorology and anthropogenic emissions on the gas-particle partitioning. Flights during SENEX over the ground site provide a unique opportunity to investigate the vertical distribution of a whole suite of these chemical species measured by these two cross-calibrated nearly identical instruments.

  5. Methane cross-validation between three Fourier transform spectrometers: SCISAT ACE-FTS, GOSAT TANSO-FTS, and ground-based FTS measurements in the Canadian high Arctic

    Science.gov (United States)

    Holl, Gerrit; Walker, Kaley A.; Conway, Stephanie; Saitoh, Naoko; Boone, Chris D.; Strong, Kimberly; Drummond, James R.

    2016-05-01

    We present cross-validation of remote sensing measurements of methane profiles in the Canadian high Arctic. Accurate and precise measurements of methane are essential to understand quantitatively its role in the climate system and in global change. Here, we show a cross-validation between three data sets: two from spaceborne instruments and one from a ground-based instrument. All are Fourier transform spectrometers (FTSs). We consider the Canadian SCISAT Atmospheric Chemistry Experiment (ACE)-FTS, a solar occultation infrared spectrometer operating since 2004, and the thermal infrared band of the Japanese Greenhouse Gases Observing Satellite (GOSAT) Thermal And Near infrared Sensor for carbon Observation (TANSO)-FTS, a nadir/off-nadir scanning FTS instrument operating at solar and terrestrial infrared wavelengths, since 2009. The ground-based instrument is a Bruker 125HR Fourier transform infrared (FTIR) spectrometer, measuring mid-infrared solar absorption spectra at the Polar Environment Atmospheric Research Laboratory (PEARL) Ridge Laboratory at Eureka, Nunavut (80° N, 86° W) since 2006. For each pair of instruments, measurements are collocated within 500 km and 24 h. An additional collocation criterion based on potential vorticity values was found not to significantly affect differences between measurements. Profiles are regridded to a common vertical grid for each comparison set. To account for differing vertical resolutions, ACE-FTS measurements are smoothed to the resolution of either PEARL-FTS or TANSO-FTS, and PEARL-FTS measurements are smoothed to the TANSO-FTS resolution. Differences for each pair are examined in terms of profile and partial columns. During the period considered, the number of collocations for each pair is large enough to obtain a good sample size (from several hundred to tens of thousands depending on pair and configuration). Considering full profiles, the degrees of freedom for signal (DOFS) are between 0.2 and 0.7 for TANSO-FTS and

  6. First results of the CINDI-2 semi-blind MAX-DOAS intercomparison

    Science.gov (United States)

    Kreher, Karin; van Roozendael, Michel; Hendrick, Francois; Apituley, Arnoud; Friess, Udo; Lampel, Johannes; Piters, Ankie; Richter, Andreas; Wagner, Thomas; Cindi-2 Participants, All

    2017-04-01

    The second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2) took place at the Cabauw Experimental Site for Atmospheric Research (CESAR; Utrecht area, The Netherlands) from 25 August until 7 October 2016. The goals of this inter-comparison campaign are to support the creation of high-quality ground-based data sets (e.g. to provide reliable long-term time series for trend analysis and satellite data validation), to characterise and better understand the differences between a large number of MAX-DOAS and DOAS instruments and analysis methods, and to contribute to a harmonisation of the measurement settings and retrieval methods. During a time period of 17 days, from 12 to 28 September 2016, a formal semi-blind intercomparison was held following a detailed measurement protocol. The development of this protocol was based on the experience gained during the first CINDI campaign held in 2009 as well as more recent projects and campaigns such as the MADCAT campaign in Mainz, Germany, in 2013. Strong emphasis was put on the careful synchronisation of the measurement sequence and on exact alignment of the elevation angles using horizon scans and lamp measurements. In this presentation, we provide an overview and some highlights of the MAX-DOAS semi-blind intercomparison campaign. We will introduce the participating groups, their instruments and the measurement protocol details, and then summarize the campaign outcomes to date. The CINDI-2 data sets have been investigated using a range of diagnostics including comparisons of daily time series and relative differences between the data sets, regression analysis and correlation plots. The data products so far investigated are NO2 (nitrogen dioxide) in the UV and visible wavelength region, O4 (oxygen dimer) in the same two wavelength intervals, O3 (ozone) in the UV and visible wavelength region, HCHO (formaldehyde) and NO2 in an additional (smaller) wavelength range in the visible. The results

  7. Time series analysis of ground-based microwave measurements at K- and V-bands to detect temporal changes in water vapor and temperature profiles

    Science.gov (United States)

    Panda, Sibananda; Sahoo, Swaroop; Pandithurai, Govindan

    2017-01-01

    Ground-based microwave measurements performed at water vapor and oxygen absorption line frequencies are widely used for remote sensing of tropospheric water vapor density and temperature profiles, respectively. Recent work has shown that Bayesian optimal estimation can be used for improving accuracy of radiometer retrieved water vapor and temperature profiles. This paper focuses on using Bayesian optimal estimation along with time series of independent frequency measurements at K- and V-bands. The measurements are used along with statistically significant but short background data sets to retrieve and sense temporal variations and gradients in water vapor and temperature profiles. To study this capability, the Indian Institute of Tropical Meteorology (IITM) deployed a microwave radiometer at Mahabubnagar, Telangana, during August 2011 as part of the Integrated Ground Campaign during the Cloud Aerosol Interaction and Precipitation Enhancement Experiment (CAIPEEX-IGOC). In this study, temperature profiles for the first time have been estimated using short but statistically significant background information so as to improve the accuracy of the retrieved profiles as well as to be able to detect gradients. Estimated water vapor and temperature profiles are compared with those taken from the reanalysis data updated by the Earth System Research Laboratory, National Oceanic and Atmospheric Administration (NOAA), to determine the range of possible errors. Similarly, root mean square errors are evaluated for a month for water vapor and temperature profiles to estimate the accuracy of the retrievals. It is found that water vapor and temperature profiles can be estimated with an acceptable accuracy by using a background information data set compiled over a period of 1 month.

  8. Characterization and error analysis of an operational retrieval algorithm for estimating column ozone and aerosol properties from ground-based ultra-violet irradiance measurements

    Science.gov (United States)

    Taylor, Thomas E.; L'Ecuyer, Tristan; Slusser, James; Stephens, Graeme; Krotkov, Nick; Davis, John; Goering, Christian

    2005-08-01

    Extensive sensitivity and error characteristics of a recently developed optimal estimation retrieval algorithm which simultaneously determines aerosol optical depth (AOD), aerosol single scatter albedo (SSA) and total ozone column (TOC) from ultra-violet irradiances are described. The algorithm inverts measured diffuse and direct irradiances at 7 channels in the UV spectral range obtained from the United States Department of Agriculture's (USDA) UV-B Monitoring and Research Program's (UVMRP) network of 33 ground-based UV-MFRSR instruments to produce aerosol optical properties and TOC at all seven wavelengths. Sensitivity studies of the Tropospheric Ultra-violet/Visible (TUV) radiative transfer model performed for various operating modes (Delta-Eddington versus n-stream Discrete Ordinate) over domains of AOD, SSA, TOC, asymmetry parameter and surface albedo show that the solutions are well constrained. Realistic input error budgets and diagnostic and error outputs from the retrieval are analyzed to demonstrate the atmospheric conditions under which the retrieval provides useful and significant results. After optimizing the algorithm for the USDA site in Panther Junction, Texas the retrieval algorithm was run on a cloud screened set of irradiance measurements for the month of May 2003. Comparisons to independently derived AOD's are favorable with root mean square (RMS) differences of about 3% to 7% at 300nm and less than 1% at 368nm, on May 12 and 22, 2003. This retrieval method will be used to build an aerosol climatology and provide ground-truthing of satellite measurements by running it operationally on the USDA UV network database.

  9. Calibration of Ground-based Lidar instrument

    DEFF Research Database (Denmark)

    Villanueva, Héctor; Gómez Arranz, Paula

    This report presents the result of the lidar calibration performed for the given Ground-based Lidar at DTU’s test site for large wind turbines at Høvsøre, Denmark. Calibration is here understood as the establishment of a relation between the reference wind speed measurements with measurement unce...

  10. Calibration of Ground -based Lidar instrument

    DEFF Research Database (Denmark)

    Villanueva, Héctor; Yordanova, Ginka

    This report presents the result of the lidar calibration performed for the given Ground-based Lidar at DTU’s test site for large wind turbines at Høvsøre, Denmark. Calibration is here understood as the establishment of a relation between the reference wind speed measurements with measurement unce...

  11. Development of 2-D-MAX-DOAS and retrievals of trace gases and aerosols optical properties

    Science.gov (United States)

    Ortega, Ivan

    satellites and atmospheric models. Chapter 3 presents an innovative retrieval approach to measure AOD430 and the aerosol phase function parameter, g, without the need for absolute radiance calibration; the retrieval is based on solar azimuth distributions of the Raman Scattering Probability (RSP), the near-absolute Rotational Raman Scattering (RRS) intensity, during the Department of Energy Two Column Aerosol Project (TCAP) at Cape Cod, MA. Furthermore, the TCAP field campaign provides a unique dataset to evaluate innovative retrieval algorithms and perform radiation closure studies. In Chapters 4 I describe the effect of persistent elevated aerosol layers on the apparent absorption of the collision induced absorption of oxygen (O2-O2, or O4) as seen by the ground based 2-D-MAX-DOAS. Chapter 5 discusses the effect of chemical composition of aerosols for optical closure of aerosol extinction as characterized by ground based (2-D-MAX-DOAS) and airborne remote sensing instruments (HSRL-2) and in-situ observations of aerosol optical properties calculated from size distributions measured aboard the DoE G-1 aircraft. Chapter 5 also includes a discussion on the effects of dry, moist, and size-corrections that need to be applied to the in-situ observations in order to infer extinction in the atmosphere. In the final Chapter 6, I present a comprehensive analysis of CHOCHO, HCHO, and NO2 column measurements obtained in multiple field deployments of MAX-DOAS under different NOx (NO + NO2) conditions and VOC precursors. In particular, I assess the magnitude of the ratio of CHOCHO to HCHO (RGF), which has been proposed as a metric to distinguish biogenic and/or anthropogenic VOC (BVOC/AVOC) influences, and show with box-modeling that the concentration of NO2 and dictates the value of RGF . I proposed a new metric of RGF based on box-modeling and field measurements to distinguish AVOC/BVOC influences and split in BVOCs.

  12. Particulate matter pollution in the coal-producing regions of the Appalachian Mountains: Integrated ground-based measurements and satellite analysis.

    Science.gov (United States)

    Aneja, Viney P; Pillai, Priya R; Isherwood, Aaron; Morgan, Peter; Aneja, Saurabh P

    2017-04-01

    This study integrates the relationship between measured surface concentrations of particulate matter 10 μm or less in diameter (PM10), satellite-derived aerosol optical depth (AOD), and meteorology in Roda, Virginia, during 2008. A multiple regression model was developed to predict the concentrations of particles 2.5 μm or less in diameter (PM2.5) at an additional location in the Appalachia region, Bristol, TN. The model was developed by combining AOD retrievals from Moderate Resolution Imaging Spectro-radiometer (MODIS) sensor on board the EOS Terra and Aqua Satellites with the surface meteorological observations. The multiple regression model predicted PM2.5 (r(2) = 0.62), and the two-variable (AOD-PM2.5) model predicted PM2.5 (r(2) = 0.4). The developed model was validated using particulate matter recordings and meteorology observations from another location in the Appalachia region, Hazard, Kentucky. The model was extrapolated to the Roda, VA, sampling site to predict PM2.5 mass concentrations. We used 10 km x 10 km resolution MODIS 550 nm AOD to predict ground level PM2.5. For the relevant period in 2008, in Roda, VA, the predicted PM2.5 mass concentration is 9.11 ± 5.16 μg m(-3) (mean ± 1SD). This is the first study that couples ground-based Particulate Matter measurements with satellite retrievals to predict surface air pollution at Roda, Virginia. Roda is representative of the Appalachian communities that are commonly located in narrow valleys, or "hollows," where homes are placed directly along the roads in a region of active mountaintop mining operations. Our study suggests that proximity to heavy coal truck traffic subjects these communities to chronic exposure to coal dust and leads us to conclude that there is an urgent need for new regulations to address the primary sources of this particulate matter.

  13. Physical and optical properties of 2010 Eyjafjallajökull volcanic eruption aerosol: ground-based, Lidar and airborne measurements in France

    Directory of Open Access Journals (Sweden)

    M. Hervo

    2012-02-01

    Full Text Available During the Eyjafjallajökull eruption (14 April to 24 May 2010, the volcanic aerosol cloud was observed across Europe by several airborne in situ and ground-based remote-sensing instruments. On 18 and 19 May, layers of depolarizing particles (i.e. non-spherical particles were detected in the free troposphere above the Puy de Dôme station, (PdD, France with a Rayleigh-Mie LIDAR emitting at a wavelength of 355 nm, with parallel and crossed polarization channels. These layers in the free troposphere (FT were also well captured by simulations with the Lagrangian particle dispersion model FLEXPART, which furthermore showed that the ash was eventually entrained into the planetary boundary layer (PBL. Indeed, the ash cloud was then detected and characterized with a comprehensive set of in situ instruments at the Puy de Dôme station (PdD. In agreement with the FLEXPART simulation, up to 65 μg m−3 of particle mass and 2.2 ppb of SO2 were measured at PdD, corresponding to concentrations higher than the 95 percentile of 2 yr of measurements at PdD. Moreover, the number concentration of particles increased to 24 000 cm−3, mainly in the submicronic mode, but a supermicronic mode was also detected with a modal diameter of 2 μm. The resulting optical properties of the ash aerosol were characterized by a low scattering Ångström exponent (0.98, showing the presence of supermicronic particles. For the first time to our knowledge, the combination of in situ optical and physical characterization of the volcanic ash allowed the calculation of the mass-to-extinction ratio (η with no assumptions on the aerosol density. The mass-to-extinction ratio was found to be significantly different from the background boundary layer aerosol (max: 1.57 g m−2 as opposed to 0.33 ± 0.03 g m−2. Using this ratio, ash mass concentration in the volcanic plume derived from LIDAR measurements was found to be 655 ± 23

  14. Physical and optical properties of 2010 Eyjafjallajökull volcanic eruption aerosol: ground-based, Lidar and airborne measurements in France

    Science.gov (United States)

    Hervo, M.; Quennehen, B.; Kristiansen, N. I.; Boulon, J.; Stohl, A.; Fréville, P.; Pichon, J.-M.; Picard, D.; Labazuy, P.; Gouhier, M.; Roger, J.-C.; Colomb, A.; Schwarzenboeck, A.; Sellegri, K.

    2012-02-01

    During the Eyjafjallajökull eruption (14 April to 24 May 2010), the volcanic aerosol cloud was observed across Europe by several airborne in situ and ground-based remote-sensing instruments. On 18 and 19 May, layers of depolarizing particles (i.e. non-spherical particles) were detected in the free troposphere above the Puy de Dôme station, (PdD, France) with a Rayleigh-Mie LIDAR emitting at a wavelength of 355 nm, with parallel and crossed polarization channels. These layers in the free troposphere (FT) were also well captured by simulations with the Lagrangian particle dispersion model FLEXPART, which furthermore showed that the ash was eventually entrained into the planetary boundary layer (PBL). Indeed, the ash cloud was then detected and characterized with a comprehensive set of in situ instruments at the Puy de Dôme station (PdD). In agreement with the FLEXPART simulation, up to 65 μg m-3 of particle mass and 2.2 ppb of SO2 were measured at PdD, corresponding to concentrations higher than the 95 percentile of 2 yr of measurements at PdD. Moreover, the number concentration of particles increased to 24 000 cm-3, mainly in the submicronic mode, but a supermicronic mode was also detected with a modal diameter of 2 μm. The resulting optical properties of the ash aerosol were characterized by a low scattering Ångström exponent (0.98), showing the presence of supermicronic particles. For the first time to our knowledge, the combination of in situ optical and physical characterization of the volcanic ash allowed the calculation of the mass-to-extinction ratio (η) with no assumptions on the aerosol density. The mass-to-extinction ratio was found to be significantly different from the background boundary layer aerosol (max: 1.57 g m-2 as opposed to 0.33 ± 0.03 g m-2). Using this ratio, ash mass concentration in the volcanic plume derived from LIDAR measurements was found to be 655 ± 23 μg m-3 when the plume was located in the FT (3000 m above the sea level

  15. Vertical mass impact and features of Saharan dust intrusions derived from ground-based remote sensing in synergy with airborne in-situ measurements

    Science.gov (United States)

    Córdoba-Jabonero, Carmen; Andrey-Andrés, Javier; Gómez, Laura; Adame, José Antonio; Sorribas, Mar; Navarro-Comas, Mónica; Puentedura, Olga; Cuevas, Emilio; Gil-Ojeda, Manuel

    2016-10-01

    A study of the vertical mass impact of Saharan dust intrusions is presented in this work. Simultaneous ground-based remote-sensing and airborne in-situ measurements performed during the AMISOC-TNF campaign over the Tenerife area (Canary Islands) in summertime from 01 July to 11 August 2013 were used for that purpose. A particular dusty (DD) case, associated to a progressively arriving dust intrusion lasting for two days on 31 July (weak incidence) and 01 August (strong incidence), is especially investigated. AERONET AOD and AEx values were ranging, respectively, from 0.2 to 1.4 and 0.35 to 0.05 along these two days. Vertical particle size distributions within fine and coarse modes (0.16-2.8 μm range) were obtained from aircraft aerosol spectrometer measurements. Extinction profiles and Lidar Ratio (LR) values were derived from MPLNET/Micro Pulse Lidar observations. MAXDOAS measurements were also used to retrieve the height-resolved aerosol extinction for evaluation purposes in comparison to Lidar-derived profiles. The synergy between Lidar observations and airborne measurements is established in terms of the Mass Extinction Efficiency (MEE) to calculate the vertical mass concentration of Saharan dust particles. Both the optical and microphysical profilings show dust particles mostly confined in a layer of 4.3 km thickness from 1.7 to 6 km height. LR ranged between 50 and 55 sr, typical values for Saharan dust particles. In addition, this 2-day dust event mostly affected the Free Troposphere (FT), being less intense in the Boundary Layer (BL). In particular, rather high Total Mass Concentrations (TMC) were found on the stronger DD day (01 August 2013): 124, 70 and 21 μg m-3 were estimated, respectively, at FT and BL altitudes and on the near-surface level. This dust impact was enhanced due to the increase of large particles affecting the FT, but also the BL, likely due to their gravitational settling. However, the use of an assumed averaged MEE value can be

  16. HCOOH distributions from IASI for 2008-2014: comparison with ground-based FTIR measurements and a global chemistry-transport model

    Science.gov (United States)

    Pommier, Matthieu; Clerbaux, Cathy; Coheur, Pierre-François; Mahieu, Emmanuel; Müller, Jean-François; Paton-Walsh, Clare; Stavrakou, Trissevgeni; Vigouroux, Corinne

    2016-07-01

    Formic acid (HCOOH) is one of the most abundant volatile organic compounds in the atmosphere. It is a major contributor to rain acidity in remote areas. There are, however, large uncertainties on the sources and sinks of HCOOH and therefore HCOOH is misrepresented by global chemistry-transport models. This work presents global distributions from 2008 to 2014 as derived from the measurements of the Infrared Atmospheric Sounding Interferometer (IASI), based on conversion factors between brightness temperature differences and representative retrieved total columns over seven regions: Northern Africa, southern Africa, Amazonia, Atlantic, Australia, Pacific, and Russia. The dependence of the measured HCOOH signal on the thermal contrast is taken into account in the conversion method. This conversion presents errors lower than 20 % for total columns ranging between 0.5 and 1 × 1016 molec cm-2 but reaches higher values, up to 78 %, for columns that are lower than 0.3 × 1016 molec cm-2. Signatures from biomass burning events are highlighted, such as in the Southern Hemisphere and in Russia, as well as biogenic emission sources, e.g., over the eastern USA. A comparison between 2008 and 2014 with ground-based Fourier transform infrared spectroscopy (FTIR) measurements obtained at four locations (Maido and Saint-Denis at La Réunion, Jungfraujoch, and Wollongong) is shown. Although IASI columns are found to correlate well with FTIR data, a large bias (> 100 %) is found over the two sites at La Réunion. A better agreement is found at Wollongong with a negligible bias. The comparison also highlights the difficulty of retrieving total columns from IASI measurements over mountainous regions such as Jungfraujoch. A comparison of the retrieved columns with the global chemistry-transport model IMAGESv2 is also presented, showing good representation of the seasonal and interannual cycles over America, Australia, Asia, and Siberia. A global model underestimation of the distribution

  17. CFC-11, CFC-12 and HCFC-22 ground-based remote sensing FTIR measurements at Réunion Island and comparisons with MIPAS/ENVISAT data

    Science.gov (United States)

    Zhou, Minqiang; Vigouroux, Corinne; Langerock, Bavo; Wang, Pucai; Dutton, Geoff; Hermans, Christian; Kumps, Nicolas; Metzger, Jean-Marc; Toon, Geoff; De Mazière, Martine

    2016-11-01

    Profiles of CFC-11 (CCl3F), CFC-12 (CCl2F2) and HCFC-22 (CHF2Cl) have been obtained from Fourier transform infrared (FTIR) solar absorption measurements above the Saint-Denis (St Denis) and Maïdo sites at Réunion Island (21° S, 55° E) with low vertical resolution. FTIR profile retrievals are performed by the well-established SFIT4 program and the detail retrieval strategies along with the systematic/random uncertainties of CFC-11, CFC-12 and HCFC-22 are discussed in this study. The FTIR data of all three species are sensitive to the whole troposphere and the lowermost stratosphere, with the peak sensitivity between 5 and 10 km. The ground-based FTIR data have been compared with the collocated Michelson Interferometer for Passive Atmospheric Sounding (MIPAS/ENVISAT) data and found to be in good agreement: the observed mean relative biases and standard deviations of the differences between the smoothed MIPAS and FTIR partial columns (6-30 km) are (-4.3 and 4.4 %), (-2.9 and 4.6 %) and (-0.7 and 4.8 %) for CFC-11, CFC-12 and HCFC-22, respectively, which are within the combined error budgets from both measurements. The season cycles of CFC-11, CFC-12 and HCFC-22 from FTIR measurements and MIPAS data show a similar variation: concentration is highest in February-April and lowest in August-October. The trends derived from the combined St Denis and Maïdo FTIR time series are -0.86 ± 0.12 and 2.84 ± 0.06 % year-1 for CFC-11 and HCFC-22, respectively, for the period 2004 to 2016, and -0.76 ± 0.05 % year-1 for CFC-12 for 2009 to 2016. These measurements are consistent with the trends observed by the National Oceanic and Atmospheric Administration (NOAA) Global Monitoring Division's (GMD) Halocarbons & other Atmospheric Trace Species Group (HATS) measurements at Samoa (14.2° S, 170.5° W) for CFC-11 (-0.87 ± 0.04 % year-1), but slightly weaker for HCFC-22 (3.46 ± 0.05 %) year-1 and stronger for CFC-12 (-0.60 ± 0.02 % year-1).

  18. Critical Evaluation of 0-30 km Profile Information in Ground-Based Zenith-Sky and Satellite-Measured Backscattered UV Radiation

    Science.gov (United States)

    Bhartia, Pawan; Petropavlovskikh, Irina; Deluishi, John; Einaudi, Franco (Technical Monitor)

    2000-01-01

    We now have several decades of experience in deriving vertical ozone profiles from the measurements of diffuse ultraviolet radiation by both ground and satellite-based instruments using Umkehr and BUV techniques. Continuing technological advances are pushing the state-of-the-art of these measurements to high spectral resolution and broader wavelength coverage. These modern instruments include the ground-based Brewer and satellite-based Global Ozone Monitoring Experiment (GOME) instruments, as well as advanced instruments being developed by ESA(SCIAMACHY), Netherlands(OMI) and Japan(ODUS). However, one of the issues that remains unresolved is the 0-30 km ozone profile information retrievable from these measurements. Though it is commonly believed that both the Umkehr and the satellite-based BUV techniques have very limited profile information below 30 km, there are those who argue that the data from these instruments should continue to be reported in this altitude range for they compare well with ozonesondes and hence there is useful scientific information. Others claim that the limitations of the Umkehr and BUV techniques are largely due to their low spectral resolution, and that the profile information below 30 km can be greatly improved by going to high spectral resolution instruments, such as Brewer and GOME. The purpose of this paper is to provide a critical evaluation of the 0-30 km ozone profile information in the various UV remote sensing techniques. We use a database of individual ozone profiles created using ozonesondes and SAGE and 4D ozone fields generated by data assimilation techniques to simulate radiances measured by the various techniques. We then apply a common inversion approach to all the methods to systematically examine how much profile information is available simply from the knowledge of total ozone, how much additional profile information is added by the traditional Dobson Umkehr and satellite buv techniques, and how much better one can do

  19. Ground-based, integrated path differential absorption LIDAR measurement of CO2, CH4, and H2O near 1.6  μm.

    Science.gov (United States)

    Wagner, Gerd A; Plusquellic, David F

    2016-08-10

    A ground-based, integrated path, differential absorption light detection and ranging (IPDA LIDAR) system is described and characterized for a series of nighttime studies of CO2, CH4, and H2O. The transmitter is based on an actively stabilized, continuous-wave, single-frequency external-cavity diode laser (ECDL) operating from 1.60 to 1.65 μm. The fixed frequency output of the ECDL is microwave sideband tuned using an electro-optical phase modulator driven by an arbitrary waveform generator and filtered using a confocal cavity to generate a sequence of 123 frequencies separated by 300 MHz. The scan sequence of single sideband frequencies of 600 ns duration covers a 37 GHz region at a spectral scan rate of 10 kHz (100 μs per scan). Simultaneously, an eye-safe backscatter LIDAR system at 1.064 μm is used to monitor the atmospheric boundary layer. IPDA LIDAR measurements of the CO2 and CH4 dry air mixing ratios are presented in comparison with those from a commercial cavity ring-down (CRD) instrument. Differences between the IPDA LIDAR and CRD concentrations in several cases appear to be well correlated with the atmospheric aerosol structure from the backscatter LIDAR measurements. IPDA LIDAR dry air mixing ratios of CO2 and CH4 are determined with fit uncertainties of 2.8 μmol/mol (ppm) for CO2 and 22 nmol/mol (ppb) for CH4 over 30 s measurement periods. For longer averaging times (up to 1200 s), improvements in these detection limits by up to 3-fold are estimated from Allan variance analyses. Two sources of systematic error are identified and methods to remove them are discussed, including speckle interference from wavelength decorrelation and the seed power dependence of amplified spontaneous emission. Accuracies in the dry air retrievals of CO2 and CH4 in a 30 s measurement period are estimated at 4 μmol/mol (1% of ambient levels) and 50 nmol/mol (3%), respectively.

  20. Technical Note: New ground-based FTIR measurements at Ile de La Réunion: observations, error analysis, and comparisons with independent data

    Directory of Open Access Journals (Sweden)

    C. Senten

    2008-07-01

    Full Text Available Ground-based high spectral resolution Fourier-transform infrared (FTIR solar absorption spectroscopy is a powerful remote sensing technique to obtain information on the total column abundances and on the vertical distribution of various constituents in the atmosphere. This work presents results from two FTIR measurement campaigns in 2002 and 2004, held at Ile de La Réunion (21° S, 55° E. These campaigns represent the first FTIR observations carried out at a southern (subtropical site. They serve the initiation of regular, long-term FTIR monitoring at this site in the near future. To demonstrate the capabilities of the FTIR measurements at this location for tropospheric and stratospheric monitoring, a detailed report is given on the retrieval strategy, information content and corresponding full error budget evaluation for ozone (O3, methane (CH4, nitrous oxide (N2O, carbon monoxide (CO, ethane (C2H6, hydrogen chloride (HCl, hydrogen fluoride (HF and nitric acid (HNO3 total and partial column retrievals. Moreover, we have made a thorough comparison of the capabilities at sea level altitude (St.-Denis and at 2200 m a.s.l. (Maïdo. It is proved that the performances of the technique are such that the atmospheric variability can be observed, at both locations and in distinct altitude layers. Comparisons with literature and with correlative data from ozone sonde and satellite (i.e., ACE-FTS, HALOE and MOPITT measurements are given to confirm the results. Despite the short time series available at present, we have been able to detect the seasonal variation of CO in the biomass burning season, as well as the impact of particular biomass burning events in Africa and Madagascar on the atmospheric composition above Ile de La Réunion. We also show that differential measurements between St.-Denis and Maïdo provide useful information about the concentrations in the boundary layer.

  1. A Modified Rife Algorithm for Off-Grid DOA Estimation Based on Sparse Representations.

    Science.gov (United States)

    Chen, Tao; Wu, Huanxin; Guo, Limin; Liu, Lutao

    2015-11-24

    In this paper we address the problem of off-grid direction of arrival (DOA) estimation based on sparse representations in the situation of multiple measurement vectors (MMV). A novel sparse DOA estimation method which changes MMV problem to SMV is proposed. This method uses sparse representations based on weighted eigenvectors (SRBWEV) to deal with the MMV problem. MMV problem can be changed to single measurement vector (SMV) problem by using the linear combination of eigenvectors of array covariance matrix in signal subspace as a new SMV for sparse solution calculation. So the complexity of this proposed algorithm is smaller than other DOA estimation algorithms of MMV. Meanwhile, it can overcome the limitation of the conventional sparsity-based DOA estimation approaches that the unknown directions belong to a predefined discrete angular grid, so it can further improve the DOA estimation accuracy. The modified Rife algorithm for DOA estimation (MRife-DOA) is simulated based on SRBWEV algorithm. In this proposed algorithm, the largest and sub-largest inner products between the measurement vector or its residual and the atoms in the dictionary are utilized to further modify DOA estimation according to the principle of Rife algorithm and the basic idea of coarse-to-fine estimation. Finally, simulation experiments show that the proposed algorithm is effective and can reduce the DOA estimation error caused by grid effect with lower complexity.

  2. A Modified Rife Algorithm for Off-Grid DOA Estimation Based on Sparse Representations

    Directory of Open Access Journals (Sweden)

    Tao Chen

    2015-11-01

    Full Text Available In this paper we address the problem of off-grid direction of arrival (DOA estimation based on sparse representations in the situation of multiple measurement vectors (MMV. A novel sparse DOA estimation method which changes MMV problem to SMV is proposed. This method uses sparse representations based on weighted eigenvectors (SRBWEV to deal with the MMV problem. MMV problem can be changed to single measurement vector (SMV problem by using the linear combination of eigenvectors of array covariance matrix in signal subspace as a new SMV for sparse solution calculation. So the complexity of this proposed algorithm is smaller than other DOA estimation algorithms of MMV. Meanwhile, it can overcome the limitation of the conventional sparsity-based DOA estimation approaches that the unknown directions belong to a predefined discrete angular grid, so it can further improve the DOA estimation accuracy. The modified Rife algorithm for DOA estimation (MRife-DOA is simulated based on SRBWEV algorithm. In this proposed algorithm, the largest and sub-largest inner products between the measurement vector or its residual and the atoms in the dictionary are utilized to further modify DOA estimation according to the principle of Rife algorithm and the basic idea of coarse-to-fine estimation. Finally, simulation experiments show that the proposed algorithm is effective and can reduce the DOA estimation error caused by grid effect with lower complexity.

  3. Measurements of ozone columns in different atmospheric layers over St. Petersburg (Russia) using ground-based FTIR spectrometer in comparison with IASI satellite data

    Science.gov (United States)

    Virolainen, Yana; Eremenko, Maxim; Timofeyev, Yury; Dufour, Gaelle; Poberovsky, Anatoly; Polyakov, Alexander; Imhasin, Hamud

    2014-05-01

    Ozone plays a key role in the photochemical equilibrium of the atmosphere. In the stratosphere, it absorbs harmful ultraviolet solar radiation, in the troposphere it is one of the main air pollutant, greenhouse gases and it is involved in the troposphere's oxidative capacity. In this study, we analyze the ozone variability in different atmospheric layers over St. Petersburg (Russia) measured with the ground-based FTIR spectrometer Bruker 125 HR at the Peterhof station (59.82 N, 29.88 E), and compare it to the satellite Infrared Atmospheric Sounding Interferometer (IASI) ozone retrievals. The FTIR spectrometer has a maximum optical path difference of 180 cm, yielding an apodized spectral resolution of 0.008 cm-1, and has been recording IR spectra since 2009. The high spectral resolution of the registered spectra allows the retrieval of the ozone content in four atmospheric layers. We applied the PROFFIT inversion code to the ozone vertical profiles retrievals in 9.6-µm O3 absorption band and calculated the daily means of ozone partial columns for about 300 days between 2009 and 2013. The IASI instrument onboard the satellite MetOp-A measures the thermal infrared radiation emitted by the Earth's surface and the atmosphere with an apodized spectral resolution of 0.5 cm-1. We used the LISA (Laboratoire Inter-universitaire des Systemes Atmospheriques) retrieval algorithm for deriving the ozone profiles between 0 and 60 km for the region of 2 degrees around the Peterhof station in coincidence with FTIR-observation dates, and averaged profiles daily over all the pixels in the considered region. In this study, we compare and discuss the both types of ozone retrievals: total and partial columns in four atmospheric layers (0-12 km, 12-18 km, 18-25 km, and 25-60 km) for 285 coincident days in 2009-2013. This study was partly supported by Saint-Petersburg State University (project No. 11.0.44.2010) and Russian Foundation for Basic Research (grants No. 12-05-00596, 12

  4. Metrology of ground-based satellite validation: co-location mismatch and smoothing issues of total ozone comparisons

    Directory of Open Access Journals (Sweden)

    T. Verhoelst

    2015-12-01

    Full Text Available Comparisons with ground-based correlative measurements constitute a key component in the validation of satellite data on atmospheric composition. The error budget of these comparisons contains not only the measurement errors but also several terms related to differences in sampling and smoothing of the inhomogeneous and variable atmospheric field. A versatile system for Observing System Simulation Experiments (OSSEs, named OSSSMOSE, is used here to quantify these terms. Based on the application of pragmatic observation operators onto high-resolution atmospheric fields, it allows a simulation of each individual measurement, and consequently, also of the differences to be expected from spatial and temporal field variations between both measurements making up a comparison pair. As a topical case study, the system is used to evaluate the error budget of total ozone column (TOC comparisons between GOME-type direct fitting (GODFITv3 satellite retrievals from GOME/ERS2, SCIAMACHY/Envisat, and GOME-2/MetOp-A, and ground-based direct-sun and zenith–sky reference measurements such as those from Dobsons, Brewers, and zenith-scattered light (ZSL-DOAS instruments, respectively. In particular, the focus is placed on the GODFITv3 reprocessed GOME-2A data record vs. the ground-based instruments contributing to the Network for the Detection of Atmospheric Composition Change (NDACC. The simulations are found to reproduce the actual measurements almost to within the measurement uncertainties, confirming that the OSSE approach and its technical implementation are appropriate. This work reveals that many features of the comparison spread and median difference can be understood as due to metrological differences, even when using strict co-location criteria. In particular, sampling difference errors exceed measurement uncertainties regularly at most mid- and high-latitude stations, with values up to 10 % and more in extreme cases. Smoothing difference errors only

  5. Metrology of ground-based satellite validation: co-location mismatch and smoothing issues of total ozone comparisons

    Science.gov (United States)

    Verhoelst, T.; Granville, J.; Hendrick, F.; Köhler, U.; Lerot, C.; Pommereau, J.-P.; Redondas, A.; Van Roozendael, M.; Lambert, J.-C.

    2015-12-01

    Comparisons with ground-based correlative measurements constitute a key component in the validation of satellite data on atmospheric composition. The error budget of these comparisons contains not only the measurement errors but also several terms related to differences in sampling and smoothing of the inhomogeneous and variable atmospheric field. A versatile system for Observing System Simulation Experiments (OSSEs), named OSSSMOSE, is used here to quantify these terms. Based on the application of pragmatic observation operators onto high-resolution atmospheric fields, it allows a simulation of each individual measurement, and consequently, also of the differences to be expected from spatial and temporal field variations between both measurements making up a comparison pair. As a topical case study, the system is used to evaluate the error budget of total ozone column (TOC) comparisons between GOME-type direct fitting (GODFITv3) satellite retrievals from GOME/ERS2, SCIAMACHY/Envisat, and GOME-2/MetOp-A, and ground-based direct-sun and zenith-sky reference measurements such as those from Dobsons, Brewers, and zenith-scattered light (ZSL-)DOAS instruments, respectively. In particular, the focus is placed on the GODFITv3 reprocessed GOME-2A data record vs. the ground-based instruments contributing to the Network for the Detection of Atmospheric Composition Change (NDACC). The simulations are found to reproduce the actual measurements almost to within the measurement uncertainties, confirming that the OSSE approach and its technical implementation are appropriate. This work reveals that many features of the comparison spread and median difference can be understood as due to metrological differences, even when using strict co-location criteria. In particular, sampling difference errors exceed measurement uncertainties regularly at most mid- and high-latitude stations, with values up to 10 % and more in extreme cases. Smoothing difference errors only play a role in the

  6. 2-D reconstruction of atmospheric concentration peaks from horizontal long path DOAS tomographic measurements: parametrisation and geometry within a discrete approach

    Directory of Open Access Journals (Sweden)

    A. Hartl

    2005-11-01

    Full Text Available In this study, we theoretically investigate the reconstruction of 2-D cross sections through Gaussian concentration distributions, e.g. emission plumes, from long path DOAS measurements along a limited number of light paths. This is done systematically with respect to the extension of the up to four peaks and for six different measurement setups with 2–4 telescopes and 36 light paths each. We distinguish between cases with and without additional background concentrations. Our approach parametrises the unknown distribution by local piecewise constant or linear functions on a regular grid and solves the resulting discrete, linear system by a least squares minimum norm principle. We show that the linear parametrisation not only allows better representation of the distributions in terms of discretisation errors, but also better inversion of the system. We calculate area integrals of the concentration field (i.e. total emissions rates for non-vanishing perpendicular wind speed components and show that reconstruction errors and reconstructed area integrals within the peaks for narrow distributions crucially depend on the resolution of the reconstruction grid. A recently suggested grid translation method for the piecewise constant basis functions, combining reconstructions from several shifted grids, is modified for the linear basis functions and proven to reduce overall reconstruction errors, but not the uncertainty of concentration integrals. We suggest a procedure to subtract additional background concentration fields before inversion. We find large differences in reconstruction quality between the geometries and conclude that, in general, for a constant number of light paths increasing the number of telescopes leads to better reconstruction results. It appears that geometries that give better results for negligible measurement errors and parts of the geometry that are better resolved are also less sensitive to increasing measurement errors.

  7. 2-D reconstruction of atmospheric concentration peaks from horizontal long path DOAS tomographic measurements: parametrisation and geometry within a discrete approach

    Directory of Open Access Journals (Sweden)

    A. Hartl

    2006-01-01

    Full Text Available In this study, we theoretically investigate the reconstruction of 2-D cross sections through Gaussian concentration distributions, e.g. emission plumes, from long path DOAS measurements along a limited number of light paths. This is done systematically with respect to the extension of the up to four peaks and for six different measurement setups with 2-4 telescopes and 36 light paths each. We distinguish between cases with and without additional background concentrations. Our approach parametrises the unknown distribution by local piecewise constant or linear functions on a regular grid and solves the resulting discrete, linear system by a least squares minimum norm principle. We show that the linear parametrisation not only allows better representation of the distributions in terms of discretisation errors, but also better inversion of the system. We calculate area integrals of the concentration field (i.e. total emissions rates for non-vanishing perpendicular wind speed components and show that reconstruction errors and reconstructed area integrals within the peaks for narrow distributions crucially depend on the resolution of the reconstruction grid. A recently suggested grid translation method for the piecewise constant basis functions, combining reconstructions from several shifted grids, is modified for the linear basis functions and proven to reduce overall reconstruction errors, but not the uncertainty of concentration integrals. We suggest a procedure to subtract additional background concentration fields before inversion. We find large differences in reconstruction quality between the geometries and conclude that, in general, for a constant number of light paths increasing the number of telescopes leads to better reconstruction results. It appears that geometries that give better results for negligible measurement errors and parts of the geometry that are better resolved are also less sensitive to increasing measurement errors.

  8. Measurements of diurnal variations and Eddy Covariance (EC fluxes of glyoxal in the tropical marine boundary layer: description of the Fast LED-CE-DOAS instrument

    Directory of Open Access Journals (Sweden)

    S. Coburn

    2014-06-01

    Full Text Available Here we present first Eddy Covariance (EC measurements of fluxes of glyoxal, the smallest α-dicarbonyl product of hydrocarbon oxidation, and a precursor for secondary organic aerosol (SOA. The unique physical and chemical properties of glyoxal, i.e., high solubility in water (Henry's Law constant, KH = 4.2 × 105 M atm−1 and short atmospheric lifetime (~2 h at solar noon make it a unique indicator species for organic carbon oxidation in the marine atmosphere. Previous reports of elevated glyoxal over oceans remain unexplained by atmospheric models. Here we describe a Fast Light Emitting Diode Cavity Enhanced Differential Optical Absorption Spectroscopy (Fast LED-CE-DOAS instrument to measure diurnal variations and EC fluxes of glyoxal, and inform about its unknown sources. The fast in situ sensor is described, and first results are presented from a cruise deployment over the Eastern tropical Pacific Ocean (20° N to 10° S; 133° W to 85° W as part of the Tropical Ocean Troposphere Exchange of Reactive Halogens and OVOC (TORERO field experiment (January to March 2012. The Fast LED-CE-DOAS is a multispectral sensor that selectively and simultaneously measures glyoxal (CHOCHO, nitrogen dioxide (NO2, oxygen dimers (O4 and water vapor (H2O with ~2 Hz time resolution, and a precision of ~40 pptv Hz−0.5 for glyoxal. The instrument is demonstrated to be a "white-noise" sensor suitable for EC flux measurements; further, highly sensitive and inherently calibrated glyoxal measurements are obtained from temporal averaging of data (~2 pptv detection limit over 1 h. The campaign averaged mixing ratio in the Southern Hemisphere (SH is found to be 43 ± 9 pptv glyoxal, and is higher than in the Northern Hemisphere (NH: 32 ± 6 pptv; error reflects variability over multiple days. The diurnal variation of glyoxal in the MBL is measured for the first time, and mixing ratios vary by ~8 ppt (NH and ~12 pptv (SH over the course of 24 h. Consistently, maxima

  9. Trends, interannual and seasonal variations of tropospheric CO, C2H6 and HCN columns measured from ground-based FTIR at Lauder and Arrival Heights

    Directory of Open Access Journals (Sweden)

    N. B. Jones

    2012-02-01

    Full Text Available We analyse the carbon monoxide (CO, ethane (C2H6 and hydrogen cyanide (HCN partial columns (from the ground to 12 km derived from measurements by ground-based solar Fourier Transform Spectroscopy at Lauder, New Zealand (45° S, 170° E and at Arrival Heights, Antarctica (78° S, 167° E from 1997 to 2009. Significant negative trends are calculated for all species at both locations: CO (−0.90 ± 0.31% yr−1 and C2H6 (−3.10 ± 1.07% yr−1 at Arrival Heights and CO (−0.87 ± 0.30% yr−1, C2H6 (−2.70 ± 0.94% yr−1 and HCN (−0.93 ± 0.32% yr−1 at Lauder. The uncertainties reflect the 95% confidence limits. The dominant seasonal trends of CO and C2H6 at Lauder, and to a lesser degree at Arrival Heights, occur in austral spring when the correlations between CO and C2H6 and between CO and HCN maximize. Tropospheric columns of all three species are characterised by minima in March–June and maxima from August to November; this season is the southern-hemisphere tropical and sub-tropical biomass burning period. A tropospheric chemistry-climate model is used to simulate CO and C2H6 columns for the period of 1997–2009 using interannually varying biomass burning emissions; the model simulated tropospheric columns of CO and C2H6 compare well with the measured partial columns of both species. However, the model does not re-produce the significant negative trends of observed CO and C2H6 partial columns at both locations. Weak negative trends are calculated from model data. The model sensitivity calculations indicate that long-range transport of biomass burning emissions from Southern Africa and South America dominate the seasonal cycles of CO and C2H6 at both Lauder and Arrival Heights. Interannual variability of these compounds at both locations is largely triggered by variations in biomass burning emissions associated with large-scale El Nino Southern Oscillation and prolonged biomass burning events, e.g. the Australian bush fires.

  10. Measurements of diurnal variations and eddy covariance (EC) fluxes of glyoxal in the tropical marine boundary layer: description of the Fast LED-CE-DOAS instrument

    Science.gov (United States)

    Coburn, S.; Ortega, I.; Thalman, R.; Blomquist, B.; Fairall, C. W.; Volkamer, R.

    2014-10-01

    Here we present first eddy covariance (EC) measurements of fluxes of glyoxal, the smallest α-dicarbonyl product of hydrocarbon oxidation, and a precursor for secondary organic aerosol (SOA). The unique physical and chemical properties of glyoxal - i.e., high solubility in water (effective Henry's law constant, KH = 4.2 × 105 M atm-1) and short atmospheric lifetime (~2 h at solar noon) - make it a unique indicator species for organic carbon oxidation in the marine atmosphere. Previous reports of elevated glyoxal over oceans remain unexplained by atmospheric models. Here we describe a Fast Light-Emitting Diode Cavity-Enhanced Differential Optical Absorption Spectroscopy (Fast LED-CE-DOAS) instrument to measure diurnal variations and EC fluxes of glyoxal and inform about its unknown sources. The fast in situ sensor is described, and first results are presented from a cruise deployment over the eastern tropical Pacific Ocean (20° N to 10° S; 133 to 85° W) as part of the Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated VOCs (TORERO) field experiment (January to March 2012). The Fast LED-CE-DOAS is a multispectral sensor that selectively and simultaneously measures glyoxal (CHOCHO), nitrogen dioxide (NO2), oxygen dimers (O4), and water vapor (H2O) with ~2 Hz time resolution (Nyquist frequency ~1 Hz) and a precision of ~40 pptv Hz-0.5 for glyoxal. The instrument is demonstrated to be a "white-noise" sensor suitable for EC flux measurements. Fluxes of glyoxal are calculated, along with fluxes of NO2, H2O, and O4, which are used to aid the interpretation of the glyoxal fluxes. Further, highly sensitive and inherently calibrated glyoxal measurements are obtained from temporal averaging of data (e.g., detection limit smaller than 2.5 pptv in an hour). The campaign average mixing ratio in the Southern Hemisphere (SH) is found to be 43 ± 9 pptv glyoxal, which is higher than the Northern Hemisphere (NH) average of 32 ± 6 pptv (error reflects

  11. New-Measurement Techniques to Diagnose Charged Dust and Plasma Layers in the Near-Earth Space Environment Using Ground-Based Ionospheric Heating Facilities

    OpenAIRE

    Mahmoudian, Alireza

    2013-01-01

    Recently, experimental observations have shown that radar echoes from the irregularitysource region associated with mesospheric dusty space plasmas may be modulated by radio wave heating with ground-based ionospheric heating facilities. These experiments show great promise as a diagnostic for the associated dusty plasma in the Near-Earth Space Environment which is believed to have links to global change. This provides an alternative to more complicated and costly space-based observational app...

  12. Multi-year comparison of stratospheric BrO vertical profiles retrieved from SCIAMACHY limb and ground-based UV-visible measurements

    Directory of Open Access Journals (Sweden)

    M. Van Roozendael

    2009-06-01

    Full Text Available Vertical profiles of stratospheric bromine monoxide (BrO retrieved daily from ENVISAT/SCIAMACHY (ENVIronmental SATellite/SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY limb scatter data and from ground-based UV-visible observations performed at Harestua (60° N, 11° E, Observatoire de Haute-Provence (44° N, 5.5° E, and Lauder (45° S, 170° E are compared in the 15–27 km altitude range for the 2002–2006, 2005–2006, and 2002–2005 periods, respectively. At the three stations, the SCIAMACHY and ground-based UV-visible mean profiles agree reasonably well, with relative difference smaller than 23%. When comparing the BrO partial columns, the agreement obtained is good, with mean relative differences smaller than 11% and corresponding standard deviations in the 13–19% range. These comparison results are obtained, however, using different BrO cross sections in SCIAMACHY limb and ground-based UV-visible retrievals. The seasonal variation of the BrO columns at the three stations is consistently captured by both retrievals as well as large BrO column events occurring during the winter and early spring at Harestua which are associated with bromine activation.

  13. Accounting for surface reflectance in the derivation of vertical column densities of NO2 from airborne imaging DOAS

    Science.gov (United States)

    Meier, Andreas Carlos; Schönhardt, Anja; Richter, Andreas; Bösch, Tim; Seyler, André; Constantin, Daniel Eduard; Shaiganfar, Reza; Merlaud, Alexis; Ruhtz, Thomas; Wagner, Thomas; van Roozendael, Michel; Burrows, John. P.

    2016-04-01

    the derivation of air mass factors used to convert the measurements into vertical columns. Due to the high-resolution measurements, no data product of surface reflectance with sufficient spatial resolution is available. Thus the surface reflectance is estimated from AirMAP's own spectra. In this work the results of the research flights will be presented. The study focuses on the validation of AirMAP's measurements by comparison to other ground-based platforms like (mobile) MAX-DOAS measurements. Conclusions will be drawn on the quality of the measurements, their applicability for satellite data validation and possible improvements for future measurements.

  14. Automated ground-based remote sensing measurements of greenhouse gases at the Bialystok site in comparison with collocated in situ measurements and model data

    NARCIS (Netherlands)

    Messerschmidt, J.; Chen, H.; Deutscher, N. M.; Gerbig, C.; Grupe, P.; Katrynski, K.; Koch, F. -T.; Lavric, J. V.; Notholt, J.; Roedenbeck, C.; Ruhe, W.; Warneke, T.; Weinzierl, C.

    2012-01-01

    The in situ boundary layer measurement site in Bialystok (Poland) has been upgraded with a fully automated observatory for total greenhouse gas column measurements. The automated Fourier Transform Spectrometer (FTS) complements the on-site in situ facilities and FTS solar absorption measurements hav

  15. Automated ground-based remote sensing measurements of greenhouse gases at the Bialystok site in comparison with collocated in situ measurements and model data

    NARCIS (Netherlands)

    Messerschmidt, J.; Chen, H.; Deutscher, N. M.; Gerbig, C.; Grupe, P.; Katrynski, K.; Koch, F. -T.; Lavric, J. V.; Notholt, J.; Roedenbeck, C.; Ruhe, W.; Warneke, T.; Weinzierl, C.

    2012-01-01

    The in situ boundary layer measurement site in Bialystok (Poland) has been upgraded with a fully automated observatory for total greenhouse gas column measurements. The automated Fourier Transform Spectrometer (FTS) complements the on-site in situ facilities and FTS solar absorption measurements hav

  16. New concepts for the comparison of tropospheric NO2 column densities derived from car-MAX-DOAS observations, OMI satellite observations and the regional model CHIMERE during two MEGAPOLI campaigns in Paris 2009/10

    Directory of Open Access Journals (Sweden)

    R. Shaiganfar

    2015-03-01

    Full Text Available We compare tropospheric column densities (vertically integrated concentrations of NO2 from three data sets for the metropolitan area of Paris during two extensive measurement campaigns (25 days in summer 2009 and 29 days in winter 2010 within the European research project MEGAPOLI. The selected data sets comprise a regional chemical transport model (CHIMERE as well as two observational data sets: ground based mobile Multi-AXis-Differential Optical Absorption Spectroscopy (car-MAX-DOAS measurements and satellite measurements from the Ozone Monitoring Instrument (OMI. On most days, car-MAX-DOAS measurements were carried out along large circles (diameter ~35 km around Paris. The car-MAX-DOAS results are compared to coincident data from CHIMERE and OMI. All three data sets have their specific strengths and weaknesses, especially with respect to their spatio-temporal resolution and coverage as well as their uncertainties. Thus we compare them in two different ways: first, we simply consider the original data sets. Second, we compare modified versions making synergistic use of the complementary information from different data sets. For example, profile information from the regional model is used to improve the satellite data, observations of the horizontal trace gas distribution are used to adjust the respective spatial patterns of the model simulations, or the model is used as a transfer tool to bridge the spatial scales between car-MAX-DOAS and satellite observations. Using the modified versions of the data sets, the comparison results substantially improve compared to the original versions. In general, good agreement between the data sets is found outside the emission plume, but inside the emission plumes the tropospheric NO2 VCDs are systematically underestimated by the CHIMERE model and the satellite observations (compared to the car-MAX-DOAS observations. One major result from our study is that for satellite validation close to strong emission

  17. A study of O3 and NO2 vertical structure in a coastal wooded zone near a metropolitan area, by means of DOAS measurements

    Science.gov (United States)

    Premuda, Margherita; Petritoli, Andrea; Masieri, Samuele; Palazzi, Elisa; Kostadinov, Ivan; Bortoli, Daniele; Ravegnani, Fabrizio; Giovanelli, Giorgio

    2013-06-01

    The possible influence on the Castel Porziano Presidential Estate pine forest (Italy) of pollutant-rich air masses from the neighboring metropolitan area of Rome is analyzed. This study aims to highlight the consequences which this natural reserve located along the coast may suffer due to the vicinity of the metropolitan area. Two case studies, one representative of synoptic and the other of breeze patterns, are presented and analyzed to evaluate how the local wind circulation can influence these processes of mutual interaction between the wooded and the urban area nearby. This is a common situation in many other places around the world. To this end an up-to-date version of a method for gas profile retrieval in the lower troposphere, developed by the authors, is exploited to study the time evolution of the vertical structure of O3 and NO2 concentrations on the Estate. The method consists of applying an inversion technique, based on the weighted Chahine algorithm, to DOAS (Differential Optical Absorption Spectroscopy) remote-sensing measurements. The analysis of the retrieved vertical profiles shows that the degradation process associated with the arrival of air masses rich in photo-chemical pollutants, due to breeze circulation modified by the Coriolis Effect, is more apparent at upper levels than near the surface, affecting to a greater degree the higher branches of the trees. The paper also examines the impact of O3 on the wooded part of the Castel Porziano Estate. The incidence of this effect is evaluated with the analysis of the so-called AOT40 parameter.

  18. Comparative Analysis of Atmospheric Glyoxal Column Densities Retrieved from MAX-DOAS Observations in Pakistan and during MAD-CAT Field Campaign in Mainz, Germany

    Directory of Open Access Journals (Sweden)

    Muhammad Fahim Khokhar

    2016-05-01

    Full Text Available Photolysis of glyoxal (CHOCHO and other volatile organic compounds (VOC in the presence of NOx results in tropospheric ozone and secondary organic pollutants formation. Glyoxal, with a relatively short lifetime, plays an important role in VOC formation in the planetary boundary layer. This study presents a comparative analysis of CHOCHO retrieval from mini MAX-DOAS observations at two different monitoring sites in Germany and Pakistan. Firstly, CHOCHO differential slant column densities (DSCDs were retrieved by using differential optical absorption spectroscopy (DOAS technique during a field campaign called MAD-CAT (Multi Axis DOAS-Comparison Campaign for Aerosols and Trace gases from 18 June to 17 July 2013 in Mainz, Germany (49.965387°N, 8.242531°E. A second dataset was acquired from 18 June to 17 July 2015 at ground-based measurements taken with mini MAX-DOAS at IESE (Institute of Environmental Sciences and Engineering, NUST (National University of Sciences and Technology Islamabad (33.6416°N, 72.9835°E, Pakistan. Tropospheric vertical column densities (VCDs of CHOCHO were derived from measured DSCDs by using geometric air mass factor approach. Results show that CHOCHO emissions from biogenic sources are largely driven by actinic flux. Covariance of ambient temperature and relative humidity was also investigated at both sites. Significant correlation between actinic flux and CHOCHO VCDs (r > 0.8 along with similar diurnal variation was observed at both monitoring sites. Quantitative difference observed in CHOCHO VCDs is primarily triggered by the difference in actinic flux and vegetation profiles of both monitoring sites.

  19. Application of Technical Measures and Software in Constructing Photorealistic 3D Models of Historical Building Using Ground-Based and Aerial (UAV) Digital Images

    Science.gov (United States)

    Zarnowski, Aleksander; Banaszek, Anna; Banaszek, Sebastian

    2015-12-01

    Preparing digital documentation of historical buildings is a form of protecting cultural heritage. Recently there have been several intensive studies using non-metric digital images to construct realistic 3D models of historical buildings. Increasingly often, non-metric digital images are obtained with unmanned aerial vehicles (UAV). Technologies and methods of UAV flights are quite different from traditional photogrammetric approaches. The lack of technical guidelines for using drones inhibits the process of implementing new methods of data acquisition. This paper presents the results of experiments in the use of digital images in the construction of photo-realistic 3D model of a historical building (Raphaelsohns' Sawmill in Olsztyn). The aim of the study at the first stage was to determine the meteorological and technical conditions for the acquisition of aerial and ground-based photographs. At the next stage, the technology of 3D modelling was developed using only ground-based or only aerial non-metric digital images. At the last stage of the study, an experiment was conducted to assess the possibility of 3D modelling with the comprehensive use of aerial (UAV) and ground-based digital photographs in terms of their labour intensity and precision of development. Data integration and automatic photo-realistic 3D construction of the models was done with Pix4Dmapper and Agisoft PhotoScan software Analyses have shown that when certain parameters established in an experiment are kept, the process of developing the stock-taking documentation for a historical building moves from the standards of analogue to digital technology with considerably reduced cost.

  20. DOA estimation in multipath based on third-order cyclic moment

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A new direction of arrival (DOA) estimation algorithm in multipath based on third-order cyclic moment is proposed in this paper. The algorithm can highly solute every DOA in multipath, and the use of third-order cyclic moment suppresses all stationary measurement noises. The simulation shows the advantages of this algorithm.

  1. Tropospheric vertical column densities of NO2 over managed dryland ecosystems (Xinjiang, China): MAX-DOAS measurements vs. 3-D dispersion model simulations based on laboratory-derived NO emission from soil samples

    Science.gov (United States)

    Mamtimin, B.; Behrendt, T.; Badawy, M. M.; Wagner, T.; Qi, Y.; Wu, Z.; Meixner, F. X.

    2015-01-01

    We report on MAX-DOAS observations of NO2 over an oasis-ecotone-desert ecosystem in NW China. There, local ambient NO2 concentrations originate from enhanced biogenic NO emission of intensively managed soils. Our target oasis "Milan" is located at the southern edge of the Taklimakan desert, very remote and well isolated from other potential anthropogenic and biogenic NOx sources. Four observation sites for MAX-DOAS measurements were selected, at the oasis centre, downwind and upwind of the oasis, and in the desert. Biogenic NO emissions in terms of (i) soil moisture and (ii) soil temperature of Milan oasis (iii) different land-cover type sub-units (cotton, Jujube trees, cotton/Jujube mixture, desert) were quantified by laboratory incubation of corresponding soil samples. Net potential NO fluxes were up-scaled to oasis scale by areal distribution and classification of land-cover types derived from satellite images using GIS techniques. A Lagrangian dispersion model (LASAT, Lagrangian Simulation of Aerosol Transport) was used to calculate the dispersion of soil emitted NO into the atmospheric boundary layer over Milan oasis. Three-dimensional (3-D) NO concentrations (30 m horizontal resolution) have been converted to 3-D NO2 concentrations, assuming photostationary state conditions. NO2 column densities were simulated by suitable vertical integration of modelled 3-D NO2 concentrations at those downwind and upwind locations, where the MAX-DOAS measurements were performed. Downwind-upwind differences (a direct measure of Milan oasis' contribution to the areal increase of ambient NO2 concentration) of measured and simulated slant (as well as vertical) NO2 column densities show excellent agreement. This agreement is considered as the first successful attempt to prove the validity of the chosen approach to up-scale laboratory-derived biogenic NO fluxes to ecosystem field conditions, i.e. from the spatial scale of a soil sample (cm2) to the size of an entire agricultural

  2. Tropospheric vertical column densities of NO2 over managed dryland ecosystems (Xinjiang, China): MAX-DOAS measurements vs. 3-D dispersion model simulations based on laboratory derived NO emission from soil samples

    Science.gov (United States)

    Mamtimin, B.; Behrendt, T.; Badawy, M. M.; Wagner, T.; Qi, Y.; Wu, Z.; Meixner, F. X.

    2014-07-01

    We report on MAX-DOAS observations of NO2 over an oasis-ecotone-desert ecosystem in NW-China. There, local ambient NO2 concentrations originate from enhanced biogenic NO emission of intensively managed soils. Our target oasis "Milan" is located at the southern edge of the Taklimakan desert, very remote and well isolated from other potential anthropogenic and biogenic NOx sources. Four observation sites for MAX-DOAS measurements were selected, at the oasis center, downwind and upwind of the oasis, and in the desert. Biogenic NO emissions in terms of (i) soil moisture and (ii) soil temperature of Milan oasis' (iii) different land-cover type sub-units (cotton, Jujube trees, cotton/Jujube mixture, desert) were quantified by laboratory incubation of corresponding soil samples. Net potential NO fluxes were up-scaled to oasis scale by areal distribution and classification of land-cover types derived from satellite images using GIS techniques. A Lagrangian dispersion model (LASAT, Lagrangian Simulation of Aerosol-Transport) was used to calculate the dispersion of soil emitted NO into the atmospheric boundary layer over Milan oasis. Three dimensional NO concentrations (30 m horizontal resolution) have been converted to 3-D NO2 concentrations, assuming photostationary state conditions. NO2 column densities were simulated by suitable vertical integration of modeled 3-D NO2 concentrations at those downwind and upwind locations, where the MAX-DOAS measurements were performed. Downwind-upwind differences (a direct measure of Milan oasis' contribution to the areal increase of ambient NO2 concentration) of measured and simulated slant (as well as vertical) NO2 column densities show excellent agreement. This agreement is considered as the first successful attempt to prove the validity of the chosen approach to up-scale laboratory derived biogenic NO fluxes to ecosystem field conditions, i.e. from the spatial scale of a soil sample (cm2) to the size of an entire agricultural

  3. Tropospheric vertical column densities of NO2 over managed dryland ecosystems (Xinjiang, China: MAX-DOAS measurements vs. 3-D dispersion model simulations based on laboratory derived NO emission from soil samples

    Directory of Open Access Journals (Sweden)

    B. Mamtimin

    2014-07-01

    Full Text Available We report on MAX-DOAS observations of NO2 over an oasis-ecotone-desert ecosystem in NW-China. There, local ambient NO2 concentrations originate from enhanced biogenic NO emission of intensively managed soils. Our target oasis "Milan" is located at the southern edge of the Taklimakan desert, very remote and well isolated from other potential anthropogenic and biogenic NOx sources. Four observation sites for MAX-DOAS measurements were selected, at the oasis center, downwind and upwind of the oasis, and in the desert. Biogenic NO emissions in terms of (i soil moisture and (ii soil temperature of Milan oasis' (iii different land-cover type sub-units (cotton, Jujube trees, cotton/Jujube mixture, desert were quantified by laboratory incubation of corresponding soil samples. Net potential NO fluxes were up-scaled to oasis scale by areal distribution and classification of land-cover types derived from satellite images using GIS techniques. A Lagrangian dispersion model (LASAT, Lagrangian Simulation of Aerosol-Transport was used to calculate the dispersion of soil emitted NO into the atmospheric boundary layer over Milan oasis. Three dimensional NO concentrations (30 m horizontal resolution have been converted to 3-D NO2 concentrations, assuming photostationary state conditions. NO2 column densities were simulated by suitable vertical integration of modeled 3-D NO2 concentrations at those downwind and upwind locations, where the MAX-DOAS measurements were performed. Downwind-upwind differences (a direct measure of Milan oasis' contribution to the areal increase of ambient NO2 concentration of measured and simulated slant (as well as vertical NO2 column densities show excellent agreement. This agreement is considered as the first successful attempt to prove the validity of the chosen approach to up-scale laboratory derived biogenic NO fluxes to ecosystem field conditions, i.e. from the spatial scale of a soil sample (cm2 to the size of an entire

  4. Automated ground-based remote sensing measurements of greenhouse gases at the Białystok site in comparison with collocated in situ measurements and model data

    Directory of Open Access Journals (Sweden)

    J. Messerschmidt

    2012-08-01

    Full Text Available The in situ boundary layer measurement site in Białystok (Poland has been upgraded with a fully automated observatory for total greenhouse gas column measurements. The automated Fourier Transform Spectrometer (FTS complements the on-site in situ facilities and FTS solar absorption measurements have been recorded nearly continuously in clear and partially cloudy conditions since March 2009. Here, the FTS measurements are compared with the collocated tall tower data. Additionally, simulations of the Jena CO2 inversion model are evaluated with the Białystok measurement facilities. The simulated seasonal CO2 cycle is slightly overestimated by a mean difference of 1.2 ppm ± 0.9 ppm (1σ in comparison with the FTS measurements. CO2 concentrations at the surface, measured at the tall tower (5 m, 90 m, 300 m, are slightly underestimated by −1.5 ppm, −1.6 ppm, and −0.7 ppm respectively during the day and by −9.1 ppm, −5.9 ppm, and −1.3 ppm during the night. The comparison of the simulated CO2 profiles with low aircraft profiles shows a slight overestimation of the lower troposphere (by up to 1 ppm and an underestimation in near-surface heights until 800 m (by up to 2.5 ppm. In an appendix the automated FTS observatory, including the hardware components and the automation software, is described in its basics.

  5. The CU Airborne MAX-DOAS instrument: vertical profiling of aerosol extinction and trace gases

    Directory of Open Access Journals (Sweden)

    S. Baidar

    2013-03-01

    Full Text Available The University of Colorado Airborne Multi-Axis Differential Optical Absorption Spectroscopy (CU AMAX-DOAS instrument uses solar stray light to detect and quantify multiple trace gases, including nitrogen dioxide (NO2, glyoxal (CHOCHO, formaldehyde (HCHO, water vapor (H2O, nitrous acid (HONO, iodine monoxide (IO, bromine monoxide (BrO, and oxygen dimers (O4 at multiple wavelengths (absorption bands at 360, 477, 577, 632 nm simultaneously in the open atmosphere. The instrument is unique as it (1 features a motion compensation system that decouples the telescope field of view from aircraft movements in real time ( The instrument is described, and data from flights over California during the CalNex (California Research at the Nexus of Air Quality and Climate Change and CARES (Carbonaceous Aerosols and Radiative Effects Study air quality field campaigns is presented. Horizontal distributions of NO2 VCD (below the aircraft maps are sampled with typically 1 km resolution, and show good agreement with two ground-based MAX-DOAS instruments (slope = 0.95 ± 0.09, R2 = 0.86. As a case study vertical profiles of NO2, CHOCHO, HCHO, and H2O concentrations and aerosol extinction coefficients, ε, at 477 nm calculated from O4 measurements from a low approach at Brackett airfield inside the South Coast Air Basin (SCAB are presented. These profiles contain ~12 degrees of freedom (DOF over a 3.5 km altitude range, an independent information approximately every 250 m. The boundary layer NO2 concentration, and the integral aerosol extinction over height (aerosol optical depth, AOD agrees well with nearby ground-based in situ NO2 measurement, and AERONET station. The detection limits of NO2, CHOCHO, HCHO, H2O442, ϵ360, ϵ477 for 30 s integration time spectra recorded forward of the plane are 5 ppt, 3 ppt, 100 ppt, 42 ppm, 0.004 km−1, 0.002 km−1 in the free troposphere (FT, and 30 ppt, 16 ppt, 540 ppt, 252 ppm, 0.012 km−1, 0.006 km−1

  6. Calibration of Ground-based Lidar instrument

    DEFF Research Database (Denmark)

    Yordanova, Ginka; Gómez Arranz, Paula

    This report presents the result of the lidar calibration performed for the given Ground-based Lidar at DTU’s test site for large wind turbines at Høvsøre, Denmark. Calibration is here understood as the establishment of a relation between the reference wind speed measurements with measurement...... uncertainties provided by measurement standard and corresponding lidar wind speed indications with associated measurement uncertainties. The lidar calibration concerns the 10 minute mean wind speed measurements. The comparison of the lidar measurements of the wind direction with that from wind vanes...

  7. Calibration of Ground -based Lidar instrument

    DEFF Research Database (Denmark)

    Villanueva, Héctor; Yordanova, Ginka

    This report presents the result of the lidar calibration performed for the given Ground-based Lidar at DTU’s test site for large wind turbines at Høvsøre, Denmark. Calibration is here understood as the establishment of a relation between the reference wind speed measurements with measurement...... uncertainties provided by measurement standard and corresponding lidar wind speed indications with associated measurement uncertainties. The lidar calibration concerns the 10 minute mean wind speed measurements. The comparison of the lidar measurements of the wind direction with that from wind vanes...

  8. Calibration of Ground-based Lidar instrument

    DEFF Research Database (Denmark)

    Yordanova, Ginka; Gómez Arranz, Paula

    This report presents the result of the lidar calibration performed for the given Ground-based Lidar at DTU’s test site for large wind turbines at Høvsøre, Denmark. Calibration is here understood as the establishment of a relation between the reference wind speed measurements with measurement...... uncertainties provided by measurement standard and corresponding lidar wind speed indications with associated measurement uncertainties. The lidar calibration concerns the 10 minute mean wind speed measurements. The comparison of the lidar measurements of the wind direction with that from wind vanes...

  9. Calibration of Ground -based Lidar instrument

    DEFF Research Database (Denmark)

    Villanueva, Héctor; Georgieva Yankova, Ginka

    This report presents the result of the lidar calibration performed for the given Ground-based Lidar at DTU’s test site for large wind turbines at Høvsøre, Denmark. Calibration is here understood as the establishment of a relation between the reference wind speed measurements with measurement...... uncertainties provided by measurement standard and corresponding lidar wind speed indications with associated measurement uncertainties. The lidar calibration concerns the 10 minute mean wind speed measurements. The comparison of the lidar measurements of the wind direction with that from wind vanes...

  10. Multi-year comparison of stratospheric BrO vertical profiles retrieved from SCIAMACHY limb and ground-based UV-visible measurements

    Directory of Open Access Journals (Sweden)

    F. Hendrick

    2008-12-01

    Full Text Available Vertical profiles of stratospheric bromine monoxide (BrO daily retrieved from ENVISAT/SCIAMACHY (ENVIronmental SATellite/SCanning Imaging Absorption spectrometer for Atmospheric CHartographY limb scatter data and from ground-based UV-visible observations performed at Harestua (60° N, 11° E, Observatoire de Haute-Provence (44° N, 5.5° E, and Lauder (45° S, 170° E are compared in the 15–27 km altitude range for the period from 2002 until 2006. At the three stations, the SCIAMACHY and ground-based UV-visible profiles agree reasonably well, with relative difference smaller than 23% on average. When comparing the BrO partial columns, the agreement obtained is good, with mean relative differences smaller than 11% and corresponding standard deviations in the 13–19% range. The seasonal variation of the BrO columns at the three stations is consistently captured by both retrievals as well as large BrO column events occurring during the winter and early spring at Harestua which are associated with chlorine activation.

  11. Flux Emissions of SO2 and NO2 Measured at the Tula Industrial Complex (Mexico) during MCMA 2006 Field Campaign using a Mini-DOAS System

    Science.gov (United States)

    Sosa, G.; Rivera, C.; Wöhrnschimmel, H.; de Foy, B.; Johansson, M.; Molina, L. T.

    2007-05-01

    The Tula industrial zone is located 60 km northeast from the Mexico City Metropolitan Area (MCMA), in the Hidalgo State in México. This region is known as the Tula-Vito-Apasco industrial corridor, where a number of industries are located. According to the latest information from the environmental authority, about 313,000 ton/year of SO2 and 40,000 ton/year of NOx are released in this region. The Miguel Hidalgo refinery (MHR) and the Francisco Pérez Ríos power plant (FPRPP) are the main emitters, contributing almost 90% of SO2 and 80% of NOx from the total emission inside the Hidalgo State. Other industries such as cement plants, open-sky mines and agricultural activities are also responsible for important emissions of particulat matter (PM) into the atmosphere and soil erosion. This highly industrialized region is thought to influence the air quality in the MCMA, where in some occasions SO2 concentrations in the north part of the city have exceeded the Mexican air quality standard (130 ppb as a 24 hour average), which could not be attributed to irregular operations of industries located in the surrounding area. To address the question of emissions from the refinery and the power plant, the total fluxes of SO2 and NO2 were determined by measurements of their respective integrated vertical column in the neighborhood of the Tula industrial zone, using a Mini-DOAS system. These measurements were carried out as part of the MCMA-2006/MILAGRO Field Campaign, from March 24th to April 18th 2006. Meteorological measurements at the height of the plume dispersion were also determined using pilot balloons and radiosondes techniques. The experimental data were complemented by model simulations. Forward Lagrangian stochastic trajectories were calculated to simulate the plume using FLEXPART in combination with meso-scale meteorological simulations with MM5. The experimental data set was used to evaluate model performance. The simulations were used as an additional estimate of

  12. Calibration of Ground-based Lidar instrument

    DEFF Research Database (Denmark)

    Yordanova, Ginka; Gómez Arranz, Paula

    This report presents the result of a test of a ground-based lidar of other type. The test was performed at DTU’s test site for large wind turbines at Høvsøre, Denmark. The result as an establishment of a relation between the reference wind speed measurements with measurement uncertainties provided...... by measurement standard and corresponding lidar wind speed indications with associated measurement uncertainties. The comparison of the lidar measurements of the wind direction with that from the wind vanes is also given....

  13. Long-term ground-based microwave radiometric measurements of atmospheric brightness temperature in SKYNET Hefei (31.90N, 117.17E) site

    Science.gov (United States)

    Wang, Zhenzhu; Liu, Dong; Xie, Chenbo; Wang, Bangxin; Zhong, Zhiqing; Wang, Yingjian; Chen, Bin

    2017-02-01

    A dual-frequency, ground-based microwave radiometer (WVR-1100) is used to investigate the behavior of the atmosphere in terms of zenith brightness temperature (TB) at 23.8 and 31.4 GHz respectively. Some experimental findings in SKYNET Hefei site from September 2002 to August 2012 are presented. The cumulative distributions of TB at both frequencies for all sky conditions show four different regions, while only two regions can be identified for clear, lightly cloudy and cloudy condition. Annual cycle of TB at 23.8 GHz is apparently remarkable, indicating the large annual cycle of atmospheric water vapor. Regular seasonal variations of TB are observed with the strongest value in summer and the weakest in winter.

  14. Comparison of ambient aerosol extinction coefficients obtained from in-situ, MAX-DOAS and LIDAR measurements at Cabauw

    NARCIS (Netherlands)

    Zieger, P.; Weingartner, E.; Henzing, J.; Moerman, M.; Leeuw, G. de; Mikkilä, J.; Ehn, M.; Petäjä, T.; Clémer, K.; Roozendael, M. van; Yilmaz, S.; Frieß, U.; Irie, H.; Wagner, T.; Shaiganfar, R.; Beirle, S.; Apituley, A.; Wilson, K.; Baltensperger, U.

    2011-01-01

    In the field, aerosol in-situ measurements are often performed under dry conditions (relative humidity RH<30-40%). Since ambient aerosol particles experience hygroscopic growth at enhanced RH, their microphysical and optical properties especially the aerosol light scattering are also strongly

  15. Ground based materials science experiments

    Science.gov (United States)

    Meyer, M. B.; Johnston, J. C.; Glasgow, T. K.

    1988-01-01

    The facilities at the Microgravity Materials Science Laboratory (MMSL) at the Lewis Research Center, created to offer immediate and low-cost access to ground-based testing facilities for industrial, academic, and government researchers, are described. The equipment in the MMSL falls into three categories: (1) devices which emulate some aspect of low gravitational forces, (2) specialized capabilities for 1-g development and refinement of microgravity experiments, and (3) functional duplicates of flight hardware. Equipment diagrams are included.

  16. Ground based materials science experiments

    Science.gov (United States)

    Meyer, M. B.; Johnston, J. C.; Glasgow, T. K.

    1988-01-01

    The facilities at the Microgravity Materials Science Laboratory (MMSL) at the Lewis Research Center, created to offer immediate and low-cost access to ground-based testing facilities for industrial, academic, and government researchers, are described. The equipment in the MMSL falls into three categories: (1) devices which emulate some aspect of low gravitational forces, (2) specialized capabilities for 1-g development and refinement of microgravity experiments, and (3) functional duplicates of flight hardware. Equipment diagrams are included.

  17. Retrieval of HCHO from MAX-DOAS measurements at the high-altitude alpine station of Jungfraujoch (46.5°N, 8.0°E)

    Science.gov (United States)

    Hendrick, Francois; Fayt, Caroline; Franco, Bruno; Gielen, Clio; Hermans, Christian; Mahieu, Emmanuel; Müller, Jean-Francois; Pinardi, Gaia; Stavrakou, Trissevgeni; Van Roozendael, Michel

    2014-05-01

    Formaldehyde (HCHO) plays an important intermediate role in the atmospheric photo-oxidation pathways. It is produced during the oxidation of methane and many non-methane volatile organic compounds (NMVOCs) which participate to the formation of tropospheric ozone and secondary organic aerosols. HCHO is also directly released by biomass burning and fossil fuel combustion and to a lesser extent by vegetation. Measuring this species is therefore of major importance for air quality and climate change monitoring. In this presentation, HCHO near-surface concentrations and vertical column densities are retrieved from MAX-DOAS measurements performed at the high-altitude station of Jungfraujoch (3580m asl) in the Swiss Alps from July 2010 till December 2012. Although being most of the time located in the free troposphere, this station can be temporarily affected by pollution events originating from the valley, leading to a local increase of air pollutant concentrations. The capability of the MAX-DOAS technique to retrieve HCHO in such high-altitude location is investigated. The spatial representativeness and the impact of cloud cover on the measurements is also discussed. For verification purpose, our retrievals are compared to collocated FTIR observations, taking into account the difference in vertical resolution between both techniques. Simulations from the 3D-CTM IMAGES are also used to further assess the observed seasonal and diurnal cycles of HCHO surface concentration and vertical column.

  18. Metrology of ground-based satellite validation: co-location mismatch and smoothing issues of total ozone comparisons

    Directory of Open Access Journals (Sweden)

    T. Verhoelst

    2015-08-01

    Full Text Available Comparisons with ground-based correlative measurements constitute a key component in the validation of satellite data on atmospheric composition. The error budget of these comparisons contains not only the measurement uncertainties but also several terms related to differences in sampling and smoothing of the inhomogeneous and variable atmospheric field. A versatile system for Observing System Simulation Experiments (OSSEs, named OSSSMOSE, is used here to quantify these terms. Based on the application of pragmatic observation operators onto high-resolution atmospheric fields, it allows a simulation of each individual measurement, and consequently also of the differences to be expected from spatial and temporal field variations between both measurements making up a comparison pair. As a topical case study, the system is used to evaluate the error budget of total ozone column (TOC comparisons between on the one hand GOME-type direct fitting (GODFITv3 satellite retrievals from GOME/ERS2, SCIAMACHY/Envisat, and GOME-2/MetOp-A, and on the other hand direct-sun and zenith-sky reference measurements such as from Dobsons, Brewers, and zenith scattered light (ZSL-DOAS instruments respectively. In particular, the focus is placed on the GODFITv3 reprocessed GOME-2A data record vs. the ground-based instruments contributing to the Network for the Detection of Atmospheric Composition Change (NDACC. The simulations are found to reproduce the actual measurements almost to within the measurement uncertainties, confirming that the OSSE approach and its technical implementation are appropriate. This work reveals that many features of the comparison spread and median difference can be understood as due to metrological differences, even when using strict co-location criteria. In particular, sampling difference errors exceed measurement uncertainties regularly at most mid- and high-latitude stations, with values up to 10 % and more in extreme cases. Smoothing

  19. Illumination compensation in ground based hyperspectral imaging

    Science.gov (United States)

    Wendel, Alexander; Underwood, James

    2017-07-01

    Hyperspectral imaging has emerged as an important tool for analysing vegetation data in agricultural applications. Recently, low altitude and ground based hyperspectral imaging solutions have come to the fore, providing very high resolution data for mapping and studying large areas of crops in detail. However, these platforms introduce a unique set of challenges that need to be overcome to ensure consistent, accurate and timely acquisition of data. One particular problem is dealing with changes in environmental illumination while operating with natural light under cloud cover, which can have considerable effects on spectral shape. In the past this has been commonly achieved by imaging known reference targets at the time of data acquisition, direct measurement of irradiance, or atmospheric modelling. While capturing a reference panel continuously or very frequently allows accurate compensation for illumination changes, this is often not practical with ground based platforms, and impossible in aerial applications. This paper examines the use of an autonomous unmanned ground vehicle (UGV) to gather high resolution hyperspectral imaging data of crops under natural illumination. A process of illumination compensation is performed to extract the inherent reflectance properties of the crops, despite variable illumination. This work adapts a previously developed subspace model approach to reflectance and illumination recovery. Though tested on a ground vehicle in this paper, it is applicable to low altitude unmanned aerial hyperspectral imagery also. The method uses occasional observations of reference panel training data from within the same or other datasets, which enables a practical field protocol that minimises in-field manual labour. This paper tests the new approach, comparing it against traditional methods. Several illumination compensation protocols for high volume ground based data collection are presented based on the results. The findings in this paper are

  20. Correlation Study Between Suspended Particulate Matter and DOAS Data

    Institute of Scientific and Technical Information of China (English)

    SI Fuqi; LIU Jianguo; XIE Pinghua; ZHANG Yujun; LIU Wenqing; Hiroaki KUZE; Nofel LAGROSAS; Nobuo TAKEUCHI

    2006-01-01

    Continuous data of aerosol optical thickness monitored using differential optical absorption spectroscopy (DOAS) are correlated with the concentration of ground-measured suspended particulate matter (SPM).A high correlation is found between the DOAS and the ground SPM data, making it possible to calculate the mass extinction efficiency of the aerosols in the atmosphere. It is found that the value of mean mass extinction efficiency (MEE) varies over a range of 2.6-13.7 m2 g-1, with smaller and larger values occurring for size distributions dominated by coarse and fine particles, respectively.

  1. DOA estimation for attitude determination on communication satellites

    Directory of Open Access Journals (Sweden)

    Yang Bin

    2014-06-01

    Full Text Available In order to determine an appropriate attitude of three-axis stabilized communication satellites, this paper describes a novel attitude determination method using direction of arrival (DOA estimation of a ground signal source. It differs from optical measurement, magnetic field measurement, inertial measurement, and global positioning system (GPS attitude determination. The proposed method is characterized by taking the ground signal source as the attitude reference and acquiring attitude information from DOA estimation. Firstly, an attitude measurement equation with DOA estimation is derived in detail. Then, the error of the measurement equation is analyzed. Finally, an attitude determination algorithm is presented using a dynamic model, the attitude measurement equation, and measurement errors. A developing low Earth orbit (LEO satellite which tests mobile communication technology with smart antennas can be stabilized in three axes by corporately using a magnetometer, reaction wheels, and three-axis magnetorquer rods. Based on the communication satellite, simulation results demonstrate the effectiveness of the method. The method could be a backup of attitude determination to prevent a system failure on the satellite. Its precision depends on the number of snapshots and the input signal-to-noise ratio (SNR with DOA estimation.

  2. DOA estimation for attitude determination on communication satellites

    Institute of Scientific and Technical Information of China (English)

    Yang Bin; He Feng; Jin Jin; Xiong Huagang; Xu Guanghan

    2014-01-01

    In order to determine an appropriate attitude of three-axis stabilized communication satellites, this paper describes a novel attitude determination method using direction of arrival (DOA) estimation of a ground signal source. It differs from optical measurement, magnetic field measurement, inertial measurement, and global positioning system (GPS) attitude determination. The proposed method is characterized by taking the ground signal source as the attitude reference and acquiring attitude information from DOA estimation. Firstly, an attitude measurement equation with DOA estimation is derived in detail. Then, the error of the measurement equation is analyzed. Finally, an attitude determination algorithm is presented using a dynamic model, the attitude measurement equation, and measurement errors. A developing low Earth orbit (LEO) satellite which tests mobile communication technology with smart antennas can be stabilized in three axes by corporately using a magnetometer, reaction wheels, and three-axis magnetorquer rods. Based on the communication satellite, simulation results demonstrate the effectiveness of the method. The method could be a backup of attitude determination to prevent a system failure on the satellite. Its precision depends on the number of snapshots and the input signal-to-noise ratio (SNR) with DOA estimation.

  3. [Numerical modeling analysis of secondary organic aerosol (SOA) combined with the ground-based measurements in the Pearl River Delta region].

    Science.gov (United States)

    Guo, Xiao-Shuang; Situ, Shu-Ping; Wang, Xue-Mei; Ding, Xiang; Wang, Xin-Ming; Yan, Cai-Qing; Li, Xiao-Ying; Zheng, Mei

    2014-05-01

    Two simulations were conducted with different secondary organic aerosol (SOA) methods-VBS (volatile basis set) approach and SORGAM (secondary organic aerosol model) , which have been coupled in the WRF/Chem (weather research and forecasting model with chemistry) model. Ground-based observation data from 18th to 25th November 2008 were used to examine the model performance of SOA in the Pearl River Delta(PRD)region. The results showed that VBS approach could better reproduce the temporal variation and magnitude of SOA compared with SORGAM, and the mean absolute deviation and correlation coefficient between the observed and the simulated data using VBS approach were -4.88 microg m-3 and 0.91, respectively, while they were -5.32 microg.m-3 and 0. 18 with SORGAM. This is mainly because the VBS approach considers SOA precursors with a wider volatility range and the process of chemical aging in SOA formation. Spatiotemporal distribution of SOA in the PRD from the VBS simulation was also analyzed. The results indicated that the SOA has a significant diurnal variation, and the maximal SOA concentration occurred at noon and in the early afternoon. Because of the transport and the considerable spatial distribution of O3 , the SOA concentrations were different in different PRD cities, and the highest concentration of SOA was observed in the downwind area, including Zhongshan, Zhuhai and Jiangmen.

  4. Analysis of Dual- and Full-Circular Polarimetric SAR Modes for Rice Phenology Monitoring: An Experimental Investigation through Ground-Based Measurements

    Directory of Open Access Journals (Sweden)

    Yuta Izumi

    2017-04-01

    Full Text Available Circularly polarized synthetic aperture radar (CP-SAR is known to be insensitive to polarization mismatch losses caused by the Faraday rotation effect and antenna misalignment. Additionally, the dual-circular polarimetric (DCP mode has proven to have more polarimetric information than that of the corresponding mode of linear polarization, i.e., the dual-linear polarimetric (DLP mode. Owing to these benefits, this paper investigates the feasibility of CP-SAR for rice monitoring. A ground-based CP-radar system was exploited, and C-band anechoic chamber data of a self-cultivated Japanese rice paddy were acquired from germination to ripening stages. Temporal variations of polarimetric observables derived from full-circular polarimetric (FCP and DCP as well as synthetically generated DLP data are analyzed and assessed with regard to their effectiveness in phenology retrieval. Among different observations, the H / α ¯ plane and triangle plots obtained by three scattering components (surface, double-bounce, and volume scattering for both the FCP and DCP modes are confirmed to have reasonable capability in discriminating the relevant intervals of rice growth.

  5. Ground-Based Global Positioning System (GPS) Meteorology Integrated Precipitable Water Vapor (IPW)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Ground-Based Global Positioning System (GPS) Meteorology Integrated Precipitable Water Vapor (IPW) data set measures atmospheric water vapor using ground-based...

  6. Analysis of global and regional CO burdens measured from space between 2000 and 2009 and validated by ground-based solar tracking spectrometers

    Directory of Open Access Journals (Sweden)

    L. Yurganov

    2010-04-01

    Full Text Available Interannual variations in AIRS and MOPITT retrieved CO burdens are validated, corrected, and compared with CO emissions from wild fires from the Global Fire Emission Dataset (GFED2 inventory. Validation of daily mean CO total column (TC retrievals from MOPITT version 3 and AIRS version 5 is performed through comparisons with archived TC data from the Network for Detection of Atmospheric Composition Change (NDACC ground-based Fourier Transform Spectrometers (FTS between March 2000 and December 2007. MOPITT V3 retrievals exhibit an increasing temporal bias with a rate of 1.4–1.8% per year; thus far, AIRS retrievals appear to be more stable. For the lowest CO values in the Southern Hemisphere (SH, AIRS TC retrievals overestimate FTS TC by 20%. MOPITT's bias and standard deviation do not depend on CO TC absolute values. Empirical corrections are derived for AIRS and MOPITT retrievals based on the observed annually averaged bias versus the FTS TC. Recently published MOPITT V4 is found to be in a good agreement with MOPITT V3 corrected by us (with exception of 2000–2001 period. With these corrections, CO burdens from AIRS V5 and MOPITT V3 (as well as MOPITT V4 come into good agreement in the mid-latitudes of the Northern Hemisphere (NH and in the tropical belt. In the SH, agreement between AIRS and MOPITT CO burdens is better for the larger CO TC in austral winter and worse in austral summer when CO TC are smaller. Before July 2008, all variations in retrieved CO burden can be explained by changes in fire emissions. After July 2008, global and tropical CO burdens decreased until October before recovering by the beginning of 2009. The NH CO burden also decreased but reached a minimum in January 2009 before starting to recover. The decrease in tropical CO burdens is explained by lower than usual fire emissions in South America and Indonesia. This decrease in tropical emissions also accounts for most of the change in the global CO burden. However, no

  7. PhotoSpec - Ground-based Remote Sensing of Solar-Induced Chlorophyll Fluorescence: First Results

    Science.gov (United States)

    Grossmann, K.; Magney, T. S.; Frankenberg, C.; Seibt, U.; Pivovaroff, A. L.; Hurlock, S. C.; Stutz, J.

    2016-12-01

    Solar-Induced Chlorophyll Fluorescence (SIF) emitted from vegetation can be used as a proxy for photosynthetic activity and is observable on a global scale from space. However, many issues on a leaf-to-canopy scale remain poorly understood, such as influences on the SIF signal from environmental conditions, water stress, or radiation. We have developed a novel ground-based spectrometer system for measuring SIF from natural ecosystems. The instrumental set-up, requirements, and measurement technique are based on decades of experience using Differential Optical Absorption Spectroscopy (DOAS), an established method to measure atmospheric trace gases. The instrument consists of three thermally stabilized commercial spectrometers that are linked to a 2D scanning telescope unit via optical fiber bundles, and also includes a commercial photosynthetic active radiation (PAR) sensor. The spectrometers cover a SIF retrieval wavelength range at high spectral resolution (670 - 780 nm, 0.1 nm FWHM), and also provide moderate resolution spectra (400 - 800 nm, 1.5 nm FWHM) to retrieve vegetation indices and the photochemical reflectance index (PRI). We report on results of the first continuous field measurements of this novel system at Stunt Ranch Santa Monica Mountains UC Reserve, where the PhotoSpec instrument was monitoring SIF of four native Californian shrubland species with different adaptations to seasonal summer drought. We report on the correlation with CO2 fluxes over both the growing season and the hot summer period in 2016. We also show detailed measurements of the diurnal cycle of the SIF signal of single broad leaves, as well as dark-light transitions, under controlled experimental conditions. In addition to demonstrating the instrumental set-up, retrieval algorithm, and instrument performance, our results illustrate that SIF measurements at the leaf to ecosystem scale are needed to understand and interpret the SIF signals retrieved at larger scales.

  8. Monitoring of atmospheric ozone and nitrogen dioxide over the south of Portugal by ground-based and satellite observations.

    Science.gov (United States)

    Bortoli, Daniele; Silva, Ana Maria; Costa, Maria João; Domingues, Ana Filipa; Giovanelli, Giorgio

    2009-07-20

    The SPATRAM (Spectrometer for Atmospheric TRAcers Monitoring) instrument has been developed as a result of the collaboration between CGE-UE, ISAC-CNR and Italian National Agency for New Technologies, Energy and the Environment (ENEA). SPATRAM is a multi-purpose UV-Vis-scanning spectrometer (250 - 950 nm) and it is installed at the Observatory of the CGE, in Evora, since April 2004. A brief description of the instrument is given, highlighting the technological innovations with respect to the previous version of similar equipment. The need for such measurements automatically taken on a routine basis in south-western European regions, specifically in Portugal, has encouraged the development and installation of the equipment and constitutes a major driving force for the present work. The main features and some improvements introduced in the DOAS (Differential Optical Absorption Spectroscopy) algorithms are discussed. The results obtained applying DOAS methodology to the SPATRAM spectrometer measurements of diffused spectral sky radiation are presented in terms of diurnal and seasonal variations of nitrogen dioxide (NO(2)) and ozone (O(3)). NO(2) confirms the typical seasonal cycle reaching the maximum of (6.5 +/- 0.3) x 10(+15) molecules cm(-2) for the sunset values (PM), during the summer season, and the minimum of (1.55 +/- 0.07) x 10(+15) molecules cm(-2) for the sunrise values (AM) in winter. O(3) presents the maximum total column of (433 +/- 5) Dobson Unit (DU) in the spring season and the minimum of (284 +/- 3) DU during the fall period. The huge daily variations of the O(3) total column during the spring season are analyzed and discussed. The ground-based results obtained for NO(2) and O(3) column contents are compared with data from satellite-borne equipment (GOME - Global Ozone Monitoring Experiment; SCIAMACHY - Scanning Imaging Absorption Spectrometer for Atmospheric CHartographY; TOMS - Total Ozone Monitoring Spectrometer) and it is shown that the two data

  9. Sparse DOA estimation with polynomial rooting

    OpenAIRE

    Xenaki, Angeliki; Gerstoft, Peter; Fernandez Grande, Efren

    2015-01-01

    Direction-of-arrival (DOA) estimation involves the localization of a few sources from a limited number of observations on an array of sensors. Thus, DOA estimation can be formulated as a sparse signal reconstruction problem and solved efficiently with compressive sensing (CS) to achieve highresolution imaging. Utilizing the dual optimal variables of the CS optimization problem, it is shown with Monte Carlo simulations that the DOAs are accurately reconstructed through polynomial rooting (Root...

  10. Multisnapshot Sparse Bayesian Learning for DOA

    Science.gov (United States)

    Gerstoft, Peter; Mecklenbrauker, Christoph F.; Xenaki, Angeliki; Nannuru, Santosh

    2016-10-01

    The directions of arrival (DOA) of plane waves are estimated from multi-snapshot sensor array data using Sparse Bayesian Learning (SBL). The prior source amplitudes is assumed independent zero-mean complex Gaussian distributed with hyperparameters the unknown variances (i.e. the source powers). For a complex Gaussian likelihood with hyperparameter the unknown noise variance, the corresponding Gaussian posterior distribution is derived. For a given number of DOAs, the hyperparameters are automatically selected by maximizing the evidence and promote sparse DOA estimates. The SBL scheme for DOA estimation is discussed and evaluated competitively against LASSO ($\\ell_1$-regularization), conventional beamforming, and MUSIC

  11. The CU Airborne MAX-DOAS instrument: vertical profiling of aerosol extinction and trace gases

    Science.gov (United States)

    Baidar, S.; Oetjen, H.; Coburn, S.; Dix, B.; Ortega, I.; Sinreich, R.; Volkamer, R.

    2013-03-01

    The University of Colorado Airborne Multi-Axis Differential Optical Absorption Spectroscopy (CU AMAX-DOAS) instrument uses solar stray light to detect and quantify multiple trace gases, including nitrogen dioxide (NO2), glyoxal (CHOCHO), formaldehyde (HCHO), water vapor (H2O), nitrous acid (HONO), iodine monoxide (IO), bromine monoxide (BrO), and oxygen dimers (O4) at multiple wavelengths (absorption bands at 360, 477, 577, 632 nm) simultaneously in the open atmosphere. The instrument is unique as it (1) features a motion compensation system that decouples the telescope field of view from aircraft movements in real time (CHOCHO, HCHO, and H2O concentrations and aerosol extinction coefficients, ɛ, at 477 nm calculated from O4 measurements from a low approach at Brackett airfield inside the South Coast Air Basin (SCAB) are presented. These profiles contain ~12 degrees of freedom (DOF) over a 3.5 km altitude range, an independent information approximately every 250 m. The boundary layer NO2 concentration, and the integral aerosol extinction over height (aerosol optical depth, AOD) agrees well with nearby ground-based in situ NO2 measurement, and AERONET station. The detection limits of NO2, CHOCHO, HCHO, H2O442, ϵ360, ϵ477 for 30 s integration time spectra recorded forward of the plane are 5 ppt, 3 ppt, 100 ppt, 42 ppm, 0.004 km-1, 0.002 km-1 in the free troposphere (FT), and 30 ppt, 16 ppt, 540 ppt, 252 ppm, 0.012 km-1, 0.006 km-1 inside the boundary layer (BL), respectively. Mobile column observations of trace gases and aerosols are complimentary to in situ observations, and help bridge the spatial scales that are probed by satellites and ground-based observations, and predicted by atmospheric models.

  12. Ground-based measurements of O3, NO2, OClO, and BrO during the 1987 Antarctic ozone depletion event

    Science.gov (United States)

    Sanders, R. W.; Solomon, S.; Carroll, M. A.; Schmeltekopf, A. L.

    1988-01-01

    Near-ultraviolet absorption spectroscopy in the wavelength range from 330 to 370 nm was used to measure O3, NO2, OClO, and BrO at McMurdo Station (78S) during 1987. Visible absorption measurements of O3, NO2, and OClO were also obtained using the wavelength range from about 403 to 453 nm. These data are described and compared to observations obtained in 1986. It is shown that comparisons of observations in the two wavelength ranges provide a sensitive measure of the altitude where the bulk of atmospheric absorption takes place.

  13. Ground-based FTIR measurements of CO from the Jungfraujoch: characterisation and comparison with in situ surface andMOPITT data

    Directory of Open Access Journals (Sweden)

    E. Mahieu

    2003-09-01

    Full Text Available CO vertical profiles have been retrieved from solar absorption FTIR spectra recorded at the NDSC station of the Jungfraujoch (46.5° N, 8° E and 3580 m a.s.l. for the period from January 1997 to May 2001. The characterisation of these profiles has been established by an information content analysis and an estimation of the error budgets. A partial validation of the profiles has been performed through comparisons with correlative measurements. The average volume mixing ratios (vmr in the 3 km layer above the station have been compared with coincident surface measurements. The agreement between monthly means from both measurement techniques is very good, with a correlation coefficient of 0.87, and no significant bias observed. The FTIR total columns have also been compared to CO partial columns above 3580 m a.s.l. derived from the MOPITT (Measurement Of Pollution In The Troposphere instrument for the period March 2000 to May 2001. Relative to the FTIR columns, the MOPITT partial columns exhibit a positive bias of 8±8% for daytime and of 4±7% for nighttime measurements.

  14. MODIS GPP/NPP for complex land use area: a case study of comparison between MODIS GPP/NPP and ground-based measurements over Korea

    Science.gov (United States)

    Shim, C.

    2013-12-01

    The Moderate Resolution Imaging Radiometer (MODIS) Gross Primary Productivity (GPP)/Net Primary Productivity (NPP) has been widely used for the study on global terrestrial ecosystem and carbon cycle. The current MODIS product with ~ 1 km spatial resolution, however, has limitation on the information on local scale environment (Pinus densiflora) agreed well with -0.2% of bias (1.6 gCm-2yr-1). The fairly comparable values of the MODIS here however, cannot assure the quality of the MOD17 over the complex vegetation area of Korea since the ground measurements except the eddy covariance tower flux measurements are highly inconsistent. Therefore, the comprehensive experiments to represents GPP/NPP over diverse vegetation types for a comparable scale of MODIS with a consistent measurement technique are necessary in order to evaluate the MODIS vegetation productivity data over Korea, which contains a large portion of highly heterogeneous vegetation area.

  15. Pathway to the Galactic Distribution of Planets: Combined Spitzer and Ground-Based Microlens Parallax Measurements of 21 Single-Lens Events

    CERN Document Server

    Novati, S Calchi; Udalski, A; Menzies, J W; Bond, I A; Shvartzvald, Y; Street, R A; Hundertmark, M; Beichman, C A; Yee, J C; Carey, S; Poleski, R; Skowron, J; Kozlowski, S; Mroz, P; Pietrukowicz, P; Pietrzynski, G; Szymanski, M K; Soszynski, I; Ulaczyk, K; Wyrzykowski, L; Albrow, M; Beaulieu, J P; Caldwell, J A R; Cassan, A; Coutures, C; Danielski, C; Prester, D Dominis; Donatowicz, J; Lonvcaric, K; McDougall, A; Morales, J C; Ranc, C; Zhu, W; Abe, F; Barry, R K; Bennett, D P; Bhattacharya, A; Fukunaga, D; Inayama, K; Koshimoto, N; Namba, S; Sumi, T; Suzuki, D; Tristram, P J; Wakiyama, Y; Yonehara, A; Maoz, D; Kaspi, S; Friedmann, M; Bachelet, E; Jaimes, R Figuera; Bramich, D M; Tsapras, Y; Horne, K; Snodgrass, C; Wambsganss, J; Steele, I A; Kains, N; Bozza, V; Dominik, M; Jorgensen, U G; Alsubai, K A; Ciceri, S; D'Ago, G; Haugbolle, T; Hessman, F V; Hinse, T C; Juncher, D; Korhonen, H; Mancini, L; Popovas, A; Rabus, M; Rahvar, S; Scarpetta, G; Schmidt, R W; Skottfelt, J; Southworth, J; Starkey, D; Surdej, J; Wertz, O; Zarucki, M; Gaudi, B S; Pogge, R W; DePoy, D L

    2014-01-01

    We present microlens parallax measurements for 21 (apparently) isolated lenses observed toward the Galactic bulge that were imaged simultaneously from Earth and Spitzer, which was ~1 AU West of Earth in projection. We combine these measurements with a kinematic model of the Galaxy to derive distance estimates for each lens, with error bars that are small compared to the Sun's Galactocentric distance. The ensemble therefore yields a well-defined cumulative distribution of lens distances. In principle it is possible to compare this distribution against a set of planets detected in the same experiment in order to measure the Galactic distribution of planets. Since these Spitzer observations yielded only one planet, this is not yet possible in practice. However, it will become possible as larger samples are accumulated.

  16. Pathway to the Galactic Distribution of Planets: Combined Spitzer and Ground-Based Microlens Parallax Measurements of 21 Single-Lens Events

    Science.gov (United States)

    Novati, S. Calchi; Gould, A.; Udalski, A.; Menzies, J. W.; Bond, I. A.; Shvartzvald, Y.; Street, R. A.; Hundertmark, M.; Beichman, C. A.; Barry, R. K.

    2015-01-01

    We present microlens parallax measurements for 21 (apparently) isolated lenses observed toward the Galactic bulge that were imaged simultaneously from Earth and Spitzer, which was approximately 1 Astronomical Unit west of Earth in projection. We combine these measurements with a kinematic model of the Galaxy to derive distance estimates for each lens, with error bars that are small compared to the Sun's galactocentric distance. The ensemble therefore yields a well-defined cumulative distribution of lens distances. In principle, it is possible to compare this distribution against a set of planets detected in the same experiment in order to measure the Galactic distribution of planets. Since these Spitzer observations yielded only one planet, this is not yet possible in practice. However, it will become possible as larger samples are accumulated.

  17. Study of aerosol microphysical properties profiles retrieved from ground-based remote sensing and aircraft in-situ measurements during a Saharan dust event

    Science.gov (United States)

    Granados-Muñoz, M. J.; Bravo-Aranda, J. A.; Baumgardner, D.; Guerrero-Rascado, J. L.; Pérez-Ramírez, D.; Navas-Guzmán, F.; Veselovskii, I.; Lyamani, H.; Valenzuela, A.; Olmo, F. J.; Titos, G.; Andrey, J.; Chaikovsky, A.; Dubovik, O.; Gil-Ojeda, M.; Alados-Arboledas, L.

    2015-09-01

    In this work we present an analysis of mineral dust optical and microphysical properties obtained from different retrieval techniques applied to active and passive remote sensing measurements, including a comparison with simultaneous in-situ aircraft measurements. Data were collected in a field campaign performed during a mineral dust outbreak a Granada, Spain, experimental site (37.16° N, 3.61° W, 680 m a.s.l.) on the 27 June 2011. Column-integrated properties are provided by sun- and star-photometry which allows a continuous evaluation of the mineral dust optical properties during both day and night-time. Both the Linear Estimation and AERONET (Aerosol Robotic Network) inversion algorithms are applied for the retrieval of the column-integrated microphysical particle properties. In addition, vertically-resolved microphysical properties are obtained from a multi-wavelength Raman lidar system included in EARLINET (European Aerosol Research Lidar Network), by using both LIRIC (Lidar Radiometer Inversion Code) algorithm during daytime and an algorithm applied to the Raman measurements based on the regularization technique during night-time. LIRIC retrievals reveal several dust layers between 3 and 5 km a.s.l. with volume concentrations of the coarse spheroid mode up to 60 μm3 cm-3. The combined use of the regularization and LIRIC methods reveals the night-to-day evolution of the vertical structure of the mineral dust microphysical properties and offers complementary information to that from column-integrated variables retrieved from passive remote sensing. Additionally, lidar depolarization profiles and LIRIC retrieved volume concentration are compared with aircraft in-situ measurements. This study presents for the first time a comparison of both volume concentration and dust particle polarization ratios measured with in-situ and remote sensing techniques. Results for the depolarization measurements in the dust layer indicate reasonable agreement within the

  18. Trends of HCl, ClONO 2 and HF column abundances from ground-based FTIR measurements in Kiruna (Sweden in comparison with KASIMA model calculations

    Directory of Open Access Journals (Sweden)

    U. Raffalski

    2011-01-01

    Full Text Available Trends of hydrogen chloride (HCl, chlorine nitrate (ClONO2 and hydrogen fluoride (HF column abundances above Kiruna (Northern Sweden, 67.84° N, 20.41° E derived from nearly 14 years (1996–2009 of measurement and model data are presented. The measurements have been performed with a Bruker 120 HR (later Bruker 125 HR Fourier transform infrared (FTIR spectrometer and the model used was KASIMA (KArlsruhe SImulation model of the Middle Atmosphere. To calculate the long-term trends, a linear function combined with an annual cycle was fitted to the data using a least squares method. The precision of the resulting trends was estimated with the so-called bootstrap resampling method. The relative trends were calculated on the basis of the linear fit result on 1 January 2000, 12:00 UTC. For hydrogen fluoride, both model and measurements show a positive trend that seems to decrease in the last few years. This suggests a stabilisation of the HF total column abundance. For the summer data (August to November, the FTIR trend of (+1.25 ± 0.28%/yr agrees within errors with the KASIMA one of (+1.55 ± 0.11%/yr. The trends determined for HCl and ClONO2 are significantly negative over the time period considered here. This corresponds to the expectations because the emission of their precursors (chlorofluorocarbons and hydrochlorofluorocarbons has been restricted in the Montreal Protocol in 1987 and its amendments and adjustments. The relative trend for ClONO2 from the FTIR measurements amounts to (−3.28 ± 0.56%/yr and the one for HCl to (−0.81± 0.23%/yr. KASIMA simulates a weaker decrease: For ClONO2, the result is (−0.90 ± 0.10%/yr and for HCl (−0.17± 0.06%/yr. Part of the difference between measurement and model data can be explained by sampling and the stronger annual cycle indicated by the measurements. There is a factor of about four between the trends of HCl and ClONO2 above Kiruna for both measurement and model data. The absolute values of

  19. Quantitative observation of cyanobacteria and diatoms from space using PhytoDOAS on SCIAMACHY data

    OpenAIRE

    Bracher, A.; M. Vountas; T. Dinter; Burrows, J. P.; Röttgers, R.; I. Peeken

    2009-01-01

    In this study the technique of Differential Optical Absorption Spectroscopy (DOAS) has been adapted for the retrieval of the absorption and biomass of two major phytoplankton groups (PhytoDOAS) from data of the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) satellite sensor. SCIAMACHY measures back scattered solar radiation in the UV-Vis-NIR spectral regions with a high spectral resolution (0.2 to 1.5 nm). In order to identify phytoplankton absorption charac...

  20. Validation and understanding of Moderate Resolution Imaging Spectroradiometer aerosol products (C5) using ground-based measurements from the handheld Sun photometer network in China

    Science.gov (United States)

    Zhanqing Li; Feng Niu; Kwon-Ho Lee; Jinyuan Xin; Wei Min Hao; Bryce L. Nordgren; Yuesi Wang; Pucai Wang

    2007-01-01

    The Moderate Resolution Imaging Spectroradiometer (MODIS) currently provides the most extensive aerosol retrievals on a global basis, but validation is limited to a small number of ground stations. This study presents a comprehensive evaluation of Collection 4 and 5 MODIS aerosol products using ground measurements from the Chinese Sun Hazemeter Network (CSHNET). The...

  1. Ground-based water vapor Raman lidar measurements up to the upper troposphere and lower stratosphere – Part 2: Data analysis and calibration for long-term monitoring

    Directory of Open Access Journals (Sweden)

    T. Leblanc

    2011-08-01

    Full Text Available The well-recognized, key role of water vapor in the upper troposphere and lower stratosphere (UT/LS and the scarcity of high-quality, long-term measurements triggered the development by JPL of a powerful Raman lidar to try to meet these needs. This development started in 2005 and was endorsed by the Network for the Detection of Atmospheric Composition Change (NDACC and the validation program for the EOS-Aura satellite. In this paper we review all the stages of the instrument data acquisition, data analysis, profile retrieval and calibration procedures, as well as selected results from the recent validation campaign MOHAVE-2009 (Measurements of Humidity in the Atmosphere and Validation Experiments. The stages in the instrumental development and the conclusions from three validation campaigns (including MOHAVE-2009 are presented in details in a companion paper (McDermid et al., 2011. In its current configuration, the lidar demonstrated capability to measure water vapor profiles from ~1 km above the ground to the lower stratosphere with an estimated accuracy of 5 %. Since 2005, nearly 1000 profiles have been routinely measured with a precision of 10 % or better near 13 km. Since 2009, the profiles have typically reached 14 km for 1 h integration times and 1.5 km vertical resolution, and can reach 21 km for 6-h integration times using degraded vertical resolutions.

  2. Characterizing the seasonal cycle and vertical structure of ozone in Paris, France using four years of ground based LIDAR measurements in the lowermost troposphere

    Science.gov (United States)

    Klein, Amélie; Ancellet, Gérard; Ravetta, François; Thomas, Jennie L.; Pazmino, Andrea

    2017-10-01

    Systematic ozone LIDAR measurements were completed during a 4 year period (2011-2014) in Paris, France to study the seasonal variability of the vertical structure of ozone in the urban boundary layer. In addition, we use in-situ measurements from the surface air quality network that is located in Paris (AIRPARIF). Specifically, we use ozone and NO2 measurements made at two urban stations: Paris13 (60 m ASL) and the Eiffel Tower (310 m ASL) to validate and interpret the LIDAR profiles. Remote sensed tropospheric NO2 integrated columns from the SAOZ instrument located in Paris are also used to interpret ozone measurements. Comparison between ozone LIDAR measurements averaged from 250 m to 500 m and the Eiffel Tower in-situ measurements shows that the accuracy of the LIDAR (originally ±14 μg·m-3) is significantly improved (±7 μg·m-3) when a small telescope with a wide angular aperture is used. Results for the seasonal cycle of the ozone vertical gradient are found to be similar using two methods: (1) measured differences between AIRPARIF stations with measurements at 60 m ASL and 310 m ASL and (2) using LIDAR profiles from 300 m to the top of the Planetary Boundary Layer (PBL). Ozone concentrations measured by the LIDAR increase with altitude within the PBL, with a steeper gradient in winter (60 μg·m-3·km-1) and a less strong gradient in summer (20 μg·m-3·km-1). Results show that in winter, there is a sharp positive gradient of ozone at the surface, which is explained by ozone titration by NO combined with increased atmospheric stability in winter. In the afternoon during summer, photochemistry a