WorldWideScience

Sample records for greenhouse gas co2

  1. Forgotten carbon: indirect CO2 in greenhouse gas emission inventories

    International Nuclear Information System (INIS)

    Gillenwater, Michael

    2008-01-01

    National governments that are Parties to the United Nations Framework Convention on Climate Change (UNFCCC) are required to submit greenhouse gas (GHG) inventories accounting for the emissions and removals occurring within their geographic territories. The Intergovernmental Panel on Climate Change (IPCC) provides inventory methodology guidance to the Parties of the UNFCCC. This methodology guidance, and national inventories based on it, omits carbon dioxide (CO 2 ) from the atmospheric oxidation of methane, carbon monoxide, and non-methane volatile organic compounds emissions that result from several source categories. The inclusion of this category of 'indirect' CO 2 in GHG inventories increases global anthropogenic emissions (excluding land use and forestry) between 0.5 and 0.7%. However, the effect of inclusion on aggregate UNFCCC Annex I Party GHG emissions would be to reduce the growth of total emissions, from 1990 to 2004, by 0.2% points. The effect on the GHG emissions and emission trends of individual countries varies. The paper includes a methodology for calculating these emissions and discusses uncertainties. Indirect CO 2 is equally relevant for GHG inventories at other scales, such as global, regional, organizational, and facility. Similarly, project-based methodologies, such as those used under the Clean Development Mechanism, may need revising to account for indirect CO 2

  2. Non-CO2 Greenhouse Gas Emissions in China 2012: Inventory and Supply Chain Analysis

    Science.gov (United States)

    Zhang, Bo; Zhang, Yaowen; Zhao, Xueli; Meng, Jing

    2018-01-01

    Reliable inventory information is critical in informing emission mitigation efforts. Using the latest officially released emission data, which is production based, we take a consumption perspective to estimate the non-CO2 greenhouse gas (GHG) emissions for China in 2012. The non-CO2 GHG emissions, which cover CH4, N2O, HFCs, PFCs, and SF6, amounted to 2003.0 Mt. CO2-eq (including 1871.9 Mt. CO2-eq from economic activities), much larger than the total CO2 emissions in some developed countries. Urban consumption (30.1%), capital formation (28.2%), and exports (20.6%) derived approximately four fifths of the total embodied emissions in final demand. Furthermore, the results from structural path analysis help identify critical embodied emission paths and key economic sectors in supply chains for mitigating non-CO2 GHG emissions in Chinese economic systems. The top 20 paths were responsible for half of the national total embodied emissions. Several industrial sectors such as Construction, Production and Supply of Electricity and Steam, Manufacture of Food and Tobacco and Manufacture of Chemicals, and Chemical Products played as the important transmission channels. Examining both production- and consumption-based non-CO2 GHG emissions will enrich our understanding of the influences of industrial positions, final consumption demands, and trades on national non-CO2 GHG emissions by considering the comprehensive abatement potentials in the supply chains.

  3. Cost-effectiveness of greenhouse gas tax and CO2 tax

    NARCIS (Netherlands)

    Kerkhof, A.C.; Moll, H.C.; Drissen, E.; Wilting, H.C.

    2006-01-01

    Current economic instruments aimed at mitigating climate change focus on CO2 emissions, but the Kyoto Protocol refers to six greenhouse gases (CO2, CH4, N2O, HFCs, PFCs and SF6). Inclusion of non-CO2 greenhouse gases in economic instruments can increase the cost-effectiveness of achieving the Kyoto

  4. Direct Conversion of Greenhouse Gas CO2 into Graphene via Molten Salts Electrolysis.

    Science.gov (United States)

    Hu, Liwen; Song, Yang; Jiao, Shuqiang; Liu, Yingjun; Ge, Jianbang; Jiao, Handong; Zhu, Jun; Wang, Junxiang; Zhu, Hongmin; Fray, Derek J

    2016-03-21

    Producing graphene through the electrochemical reduction of CO2 remains a great challenge, which requires precise control of the reaction kinetics, such as diffusivities of multiple ions, solubility of various gases, and the nucleation/growth of carbon on a surface. Here, graphene was successfully created from the greenhouse gas CO2 using molten salts. The results showed that CO2 could be effectively fixed by oxygen ions in CaCl2-NaCl-CaO melts to form carbonate ions, and subsequently electrochemically split into graphene on a stainless steel cathode; O2 gas was produced at the RuO2-TiO2 inert anode. The formation of graphene in this manner can be ascribed to the catalysis of active Fe, Ni, and Cu atoms at the surface of the cathode and the microexplosion effect through evolution of CO in between graphite layers. This finding may lead to a new generation of proceedures for the synthesis of high value-added products from CO2, which may also contribute to the establishment of a low-carbon and sustainable world. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. An approach for verifying biogenic greenhouse gas emissions inventories with atmospheric CO2 concentration data

    International Nuclear Information System (INIS)

    Ogle, Stephen M; Davis, Kenneth; Lauvaux, Thomas; Miles, Natasha L; Richardson, Scott; Schuh, Andrew; Cooley, Dan; Breidt, F Jay; West, Tristram O; Heath, Linda S; Smith, James E; McCarty, Jessica L; Gurney, Kevin R; Tans, Pieter; Denning, A Scott

    2015-01-01

    Verifying national greenhouse gas (GHG) emissions inventories is a critical step to ensure that reported emissions data to the United Nations Framework Convention on Climate Change (UNFCCC) are accurate and representative of a country’s contribution to GHG concentrations in the atmosphere. Furthermore, verifying biogenic fluxes provides a check on estimated emissions associated with managing lands for carbon sequestration and other activities, which often have large uncertainties. We report here on the challenges and results associated with a case study using atmospheric measurements of CO 2 concentrations and inverse modeling to verify nationally-reported biogenic CO 2 emissions. The biogenic CO 2 emissions inventory was compiled for the Mid-Continent region of United States based on methods and data used by the US government for reporting to the UNFCCC, along with additional sources and sinks to produce a full carbon balance. The biogenic emissions inventory produced an estimated flux of −408 ± 136 Tg CO 2 for the entire study region, which was not statistically different from the biogenic flux of −478 ± 146 Tg CO 2 that was estimated using the atmospheric CO 2 concentration data. At sub-regional scales, the spatial density of atmospheric observations did not appear sufficient to verify emissions in general. However, a difference between the inventory and inversion results was found in one isolated area of West-central Wisconsin. This part of the region is dominated by forestlands, suggesting that further investigation may be warranted into the forest C stock or harvested wood product data from this portion of the study area. The results suggest that observations of atmospheric CO 2 concentration data and inverse modeling could be used to verify biogenic emissions, and provide more confidence in biogenic GHG emissions reporting to the UNFCCC. (letter)

  6. CO2 abatement costs of greenhouse gas (GHG) mitigation by different biogas conversion pathways.

    Science.gov (United States)

    Rehl, T; Müller, J

    2013-01-15

    Biogas will be of increasing importance in the future as a factor in reducing greenhouse gas emissions cost-efficiently by the optimal use of available resources and technologies. The goal of this study was to identify the most ecological and economical use of a given resource (organic waste from residential, commercial and industry sectors) using one specific treatment technology (anaerobic digestion) but applying different energy conversion technologies. Average and marginal abatement costs were calculated based on Life Cycle Cost (LCC) and Life Cycle Assessment (LCA) methodologies. Eight new biogas systems producing electricity, heat, gas or automotive fuel were analyzed in order to identify the most cost-efficient way of reducing GHG emissions. A system using a combined heat and power station (which is connected to waste treatment and digestion operation facilities and located nearby potential residential, commercial or industrial heat users) was found to be the most cost-efficient biogas technology for reducing GHG emissions. Up to € 198 per tonne of CO(2) equivalents can be saved by replacing the "business as usual" systems based on fossil resources with ones based on biogas. Limited gas injection (desulfurized and dried biogas, without compression and upgrading) into the gas grid can also be a viable option with an abatement cost saving of € 72 per tonne of CO(2) equivalents, while a heating plant with a district heating grid or a system based on biogas results in higher abatement costs (€ 267 and € 270 per tonne CO(2) eq). Results from all systems are significantly influenced by whether average or marginal data are used as a reference. Beside that energy efficiency, the reference system that was replaced and the by-products as well as feedstock and investment costs were identified to be parameters with major impacts on abatement costs. The quantitative analysis was completed by a discussion of the role that abatement cost methodology can play in

  7. Non-CO2 greenhouse gas emissions associated with food production: methane (CH4) and nitrous oxide (N2O)

    International Nuclear Information System (INIS)

    Carlsson-Kanyama, Annika

    2007-01-01

    It is well known that the agriculture and livestock sectors are large contributors of N 2 O and CH 4 emissions in countries with agricultural activities and that remedial measures are needed in these sectors in order to curb contributions to global warming. This study examines non- CO 2 greenhouse gas emissions associated with the production of food. Methane (CH 4 ) and nitrous oxide (N 2 O) are the most relevant greenhouse gases in this category, and they are emitted mainly in the agricultural sector. These greenhouse gases have a Global Warming Potential much higher than CO 2 itself (25- and 298-fold higher, respectively, in a 100-year perspective). Emission intensities and the corresponding uncertainties were calculated based on the latest procedures and data published by the Intergovernmental Panel on Climate Change and used to facilitate calculations comparing greenhouse gas emissions for food products and diets. When the proposed emission intensities were applied to agricultural production, the results showed products of animal origin and the cultivation of rice under water to have high emissions compared with products of vegetable origin cultivated on upland soils, such as wheat and beans. In animal production the main source of greenhouse gas emissions was methane from enteric fermentation, while emissions of nitrous oxides from fertilisers were the main sources of greenhouse gas emissions for cereal and legume cultivation. For rice cultivation, methane emissions from flooded rice fields contributed most. Other significant sources of greenhouse gas emissions during animal production were manure storage and management. We suggest that the proposed emission factors, together with the associated uncertainties, can be a tool for better understanding the potential to mitigate emissions of greenhouse gases through changes in the diet

  8. An approach for verifying biogenic greenhouse gas emissions inventories with atmospheric CO2 concentration data

    Science.gov (United States)

    Stephen M Ogle; Kenneth Davis; Thomas Lauvaux; Andrew Schuh; Dan Cooley; Tristram O West; Linda S Heath; Natasha L Miles; Scott Richardson; F Jay Breidt; James E Smith; Jessica L McCarty; Kevin R Gurney; Pieter Tans; A Scott. Denning

    2015-01-01

    Verifying national greenhouse gas (GHG) emissions inventories is a critical step to ensure that reported emissions data to the United Nations Framework Convention on Climate Change (UNFCCC) are accurate and representative of a country's contribution to GHG concentrations in the atmosphere. Furthermore, verifying biogenic fluxes provides a check on estimated...

  9. CO2 Allowance Allocation in the Regional Greenhouse Gas Initiative and the Effect on Electricity Investors

    International Nuclear Information System (INIS)

    Burtraw, Dallas; Kahn, Danny; Palmer, Karen

    2006-01-01

    The Regional Greenhouse Gas Initiative among Northeastern states is expected to lead to an increase in the price of electricity in the region and beyond. In the RGGI region, changes in the value of electricity-generating assets may be positive or negative, while changes outside the Northeast are virtually always positive. For stakeholders in the industry, the change depends on the portfolio of assets held by affected firms. (author)

  10. Reduction of CO2 emissions from road transport in cities impact of dynamic route guidance system on greenhouse gas emission

    CERN Document Server

    Markiewicz, Michal

    2017-01-01

    Michal Markiewicz presents the outcomes of his research regarding the influence of dynamic route guidance system on overall emission of carbon dioxide from road transport in rural areas. Sustainable transportation in smart cities is a big challenge of our time, but before electric vehicles replace vehicles that burn fossil fuels we have to think about traffic optimization methods that reduce the amount of greenhouse gas emissions. Contents Comparison of Travel Time Measurements Using Floating Car Data and Intelligent Infrastructure Integration of Cellular Automata Traffic Simulator with CO2 Emission Model Impact of Dynamic Route Guidance System on CO2 Emission Naxos Vehicular Traffic Simulator Target Groups Lecturers and students of computer science, transportation and logistics Traffic engineers The Author Dr. Michal Markiewicz defended his PhD thesis in computer science at the University of Bremen,TZI Technologie-Zentrum Informatik und Informationstechnik, Germany. Currently, he is working on commercializat...

  11. Can Producing Oil Store Carbon? Greenhouse Gas Footprint of CO2EOR, Offshore North Sea.

    Science.gov (United States)

    Stewart, R Jamie; Haszeldine, R Stuart

    2015-05-05

    Carbon dioxide enhanced oil recovery (CO2EOR) is a proven and available technology used to produce incremental oil from depleted fields while permanently storing large tonnages of injected CO2. Although this technology has been used successfully onshore in North America and Europe, there are currently no CO2EOR projects in the United Kingdom. Here, we examine whether offshore CO2EOR can store more CO2 than onshore projects traditionally have and whether CO2 storage can offset additional emissions produced through offshore operations and incremental oil production. Using a high-level Life Cycle system approach, we find that the largest contribution to offshore emissions is from flaring or venting of reproduced CH4 and CO2. These can already be greatly reduced by regulation. If CO2 injection is continued after oil production has been optimized, then offshore CO2EOR has the potential to be carbon negative--even when emissions from refining, transport, and combustion of produced crude oil are included. The carbon intensity of oil produced can be just 0.056-0.062 tCO2e/bbl if flaring/venting is reduced by regulation. This compares against conventional Saudi oil 0.040 tCO2e/bbl or mined shale oil >0.300 tCO2e/bbl.

  12. A greenhouse gas source of surprising significance: anthropogenic CO2emissions from use of methanol in sewage treatment.

    Science.gov (United States)

    Willis, John L; Al-Omari, Ahmed; Bastian, Robert; Brower, Bill; DeBarbadillo, Christine; Murthy, Sudhir; Peot, Christopher; Yuan, Zhiguo

    2017-05-01

    The impact of methanol (CH 3 OH) as a source of anthropogenic carbon dioxide (CO 2 ) in denitrification at wastewater treatment plants (WWTPs) has never been quantified. CH 3 OH is the most commonly purchased carbon source for sewage denitrification. Until recently, greenhouse gas (GHG) reporting protocols consistently ignored the liberation of anthropogenic CO 2 attributable to CH 3 OH. This oversight can likely be attributed to a simplifying notion that CO 2 produced through activated-sludge-process respiration is biogenic because most raw-sewage carbon is un-sequestered prior to entering a WWTP. Instead, a biogenic categorization cannot apply to fossil-fuel-derived carbon sources like CH 3 OH. This paper provides a summary of how CH 3 OH use at DC Water's Blue Plains Advanced Wastewater Treatment Plant (AWTP; Washington, DC, USA) amounts to 60 to 85% of the AWTP's Scope-1 emissions. The United States Environmental Protection Agency and Water Environment Federation databases suggest that CH 3 OH CO 2 likely represents one quarter of all Scope-1 GHG emissions attributable to sewage treatment in the USA. Finally, many alternatives to CH 3 OH use exist and are discussed.

  13. Imagining CO2: development and assessment of interactive visualizations for high resolution greenhouse gas observations collected by BEACO2N

    Science.gov (United States)

    Raheja, G.; Shusterman, A.; Martin, S.; Shahar, E.; Laughner, J.; Turner, A. J.; Miller, M. K.; Cohen, R. C.

    2016-12-01

    The Berkeley Atmospheric CO2 Observation Network (BEACO2N) is a high-density network of 28 carbon dioxide sensors distributed around the San Francisco Bay Area that serve to enhance understanding of intra-city variations in CO2 concentrations that are not necessarily captured by sparser networks maintained by local and national air quality management agencies. We partner with designers at the San Francisco Exploratorium to create a suite of interactive exhibits and hands-on activities that creatively visualize data from BEACO2N for general audiences. Museum goers can manipulate a light-up "bar graph" of live CO2 concentrations by exhaling on an in-room sensor, query the current readings of rooftop sensors using a scale model of the Wired Pier observation system, scroll through the data from other BEACO2N sites projected on a 3-D "topographic table" of the Bay Area, and view interpolated CO2 fields driven by research-grade weather models on a nine-screen LCD display. We present lessons learned from these initial installations, from layperson audience feedback to details of the Stochastic Time-Inverted Lagrangian Transport (STILT) model coupled to Weather Research and Forecasting (WRF) weather fields used to generate intuitive concentration maps. We propose that compelling visual demonstrations of elevated CO2 concentrations due to routine small-scale high-emission anthropogenic activities (e.g. rush hour) and/or special events (such as fireworks or factory fires) generate deeper engagement in local environmental issues and interest in undertaking personal actions that can become part of the broader climate solution. While global means and other large-scale aggregate climate metrics can lead to feelings of disconnect and subsequent ambivalence, via such exhibitions, distributed network instruments like BEACO2N can provide the local sensitivity needed to "personalize" greenhouse gas concentrations to a given individual or community and incite the drive toward

  14. Developments in greenhouse gas emissions and net energy use in Danish agriculture - How to achieve substantial CO2 reductions?

    International Nuclear Information System (INIS)

    Dalgaard, T.; Olesen, J.E.; Petersen, S.O.; Petersen, B.M.; Jorgensen, U.; Kristensen, T.; Hutchings, N.J.; Gyldenkaerne, S.; Hermansen, J.E.

    2011-01-01

    Greenhouse gas (GHG) emissions from agriculture are a significant contributor to total Danish emissions. Consequently, much effort is currently given to the exploration of potential strategies to reduce agricultural emissions. This paper presents results from a study estimating agricultural GHG emissions in the form of methane, nitrous oxide and carbon dioxide (including carbon sources and sinks, and the impact of energy consumption/bioenergy production) from Danish agriculture in the years 1990-2010. An analysis of possible measures to reduce the GHG emissions indicated that a 50-70% reduction of agricultural emissions by 2050 relative to 1990 is achievable, including mitigation measures in relation to the handling of manure and fertilisers, optimization of animal feeding, cropping practices, and land use changes with more organic farming, afforestation and energy crops. In addition, the bioenergy production may be increased significantly without reducing the food production, whereby Danish agriculture could achieve a positive energy balance. - Highlights: → GHG emissions from Danish agriculture 1990-2010 are calculated, including carbon sequestration. → Effects of measures to further reduce GHG emissions are listed. → Land use scenarios for a substantially reduced GHG emission by 2050 are presented. → A 50-70% reduction of agricultural emissions by 2050 relative to 1990 is achievable. → Via bioenergy production Danish agriculture could achieve a positive energy balance. - Scenario studies of greenhouse gas mitigation measures illustrate the possible realization of CO 2 reductions for Danish agriculture by 2050, sustaining current food production.

  15. Greenhouse Gas (CH4, CO2 and N2O) Emission Levels by Wastewater Treatment Plant (WWTP) Ponds in Brazil

    Science.gov (United States)

    Rossete, A. L. M.; Sundefeld Junior, G.; Aparicio, C.; Baldi, G. G.; Montes, C. R.; Piveli, R. P.; Melfi, A. J.

    2015-12-01

    This study measured greenhouse gas emissions (GHG) by Facultative Ponds on Wastewater Treatment Plants. The most studied GHGs include CO2, CH4and N2O. The level of GHG (CO2, CH4 and N2O) emissions by WWTPs in Australian-type stabilization ponds was measured in the city of Lins (22º21'S, 49º50'W), state of São Paulo (SP), Brazil. GHG collection was carried outusing a collection chamber installed at the center of the facultative pond's final third. The effluent's pH and temperature (ET) were registered by probes, and meteorological information regarding air temperature (AT) and solar radiation (SR) were obtained from INMET, Brazil. GHG collection was carried out for 72 consecutive hours in June 2014, on an hourly basis, once every 5 minutes, for the first 30 minutes, and once every 10 minutes from 30 to 50 minutesand subsequently analyzed by gas chromatograph (GC).After three days of data collection, the average AT, SR, ET and pH values were, respectively, 18oC, 2583kJm-2, 23oC and 8.2. Average values for GHG emission levels (CH4, CO2 and N2O) were 79.01; 100.65 and 0.0 mg m-2 h-1, respectively. GHG emission levels were divided into light periods (morning, afternoon and evening)in order to verify the periods with the highest GHG emissions.The highest CH4 emission levels were measured between morning and early afternoon. The maximum CO2 emissions were observed from evening to early morning. N2O emissions were constant and values were close to the ones found in the atmosphere, which shows the emission of N2O by facultative ponds does not contribute to greenhouse gases emissions.The results enabled us to characterize and quantify GHG emission levels per Facultative Pond on Wastewater Treatment Plant. Acknowledgment to FAPESP and SABESP, Brazil.

  16. Effects of agricultural practices on greenhouse gas emissions (N2O, CH4 and CO2) from corn fields

    Science.gov (United States)

    Hui, D.; Wang, J.; Jima, T.; Dennis, S.; Stockert, C.; Smart, D.; Bhattarai, S.; Brown, K.; Sammis, T.; Reddy, C.

    2012-12-01

    The United States is, by far, the largest producer of corn (Zea mays L.) in the world. Recent increases in fertilizer cost and concerns over global climate change have farmers and others interested in more efficient fertilization management and greenhouse gas emissions reductions. To seek the best management practices, we conducted field experiments during the 2012 growing season at Tennessee State University Agricultural Research and Demonstration Center in Nashville, TN. Six treatments were applied including regular URAN application [2 times], multiple URAN applications [4 times], denitrification inhibitor with regular URAN application, and chicken litter plus regular URAN application in no-tilled plots, and URAN application plus bio-char in tilled plots, all compared to regular URAN application in conventional tilled plots. Each treatment was replicated six times (blocks). We measured N2O, CO2 and CH4 emissions using a closed chamber method after rainfall events, fertilizer applications or every two weeks whichever was shorter. Corresponding soil NH4+-N and NO3--N, soil temperature and moisture were also measured during the gas sampling. Plant physiology and growth were measured about every two weeks. While preliminary results indicate that N2O and CO2 fluxes were significantly influenced by the agricultural practices on some days, particularly after rainfall events, CH4 flux was not influenced by the treatments during most of the days. Plots with bio-char showed significantly lower N2O emissions. We also measured N2O flux in a commercial corn field using the Eddy Covariance (EC) technique to ground verify the chamber based N2O emissions at the field scale. Results obtained with the EC technique seem comparable with the chamber method.

  17. Non-CO2 greenhouse gases and climate change.

    Science.gov (United States)

    Montzka, S A; Dlugokencky, E J; Butler, J H

    2011-08-03

    Earth's climate is warming as a result of anthropogenic emissions of greenhouse gases, particularly carbon dioxide (CO(2)) from fossil fuel combustion. Anthropogenic emissions of non-CO(2) greenhouse gases, such as methane, nitrous oxide and ozone-depleting substances (largely from sources other than fossil fuels), also contribute significantly to warming. Some non-CO(2) greenhouse gases have much shorter lifetimes than CO(2), so reducing their emissions offers an additional opportunity to lessen future climate change. Although it is clear that sustainably reducing the warming influence of greenhouse gases will be possible only with substantial cuts in emissions of CO(2), reducing non-CO(2) greenhouse gas emissions would be a relatively quick way of contributing to this goal.

  18. CO2Explorer: Conducting Greenhouse-Gas Measurements of Landfills using a Small Fixed-wing UAV

    Science.gov (United States)

    Hollingsworth, Peter; Allen, Grant; Kabbabe, Khristopher; Pitt, Joseph

    2017-04-01

    Quantifying inventories of Greenhouse gas emissions, primarily Methane and Carbon Dioxide, from distributed sources such as a landfill has historically been undertaken using one of several ground based measurement techniques. These methods are either time and/or resource intensive. As a result regulatory agencies have started looking at the potential of using small-unmanned aircraft to supplement or supplant the current methods. The challenge of using a UAV to perform these tasks is the trade-off between accuracy, operational flexibility and operational productivity. This is driven by the state-of-the-art in measurement instruments, the operating environment at landfills and the regulatory/safety environment surrounding UAV operations. This work describes the development of the operational concept, and associated UAV measurement platform for the CO2Explorer. It looks at the scientific, engineering and possible policy trades and compares the use of small rotary and fixed-wing UAVs from both an operational and measurement perspective. This work also makes recommendations on system development and operation for users lacking in both systems engineering and operational experience.

  19. Greenhouse Gas (CO2 AND N2O Emissions from Soils: A Review Emisión de Gases invernadero (CO2 y N2O desde Suelos

    Directory of Open Access Journals (Sweden)

    Cristina Muñoz

    2010-09-01

    Full Text Available In agricultural activities, the main greenhouse gases (GHG are those related to C and N global cycles. The impact of agriculture on GHG emissions has become a key issue, especially when considering that natural C and N cycles are influenced by agricultural development. This review focuses on CO2 and N2O soil emissions in terrestrial ecosystems, with emphasis in Chilean and similar agro-ecosystems around the world. The influence of land use and crop management practices on CO2 and N2O emissions is analyzed; some mitigation measures to reduce such emissions are also discussed here. More knowledge on the biological processes that promote of GHG emissions from soil will allow creating opportunities for agricultural development under friendly-environmental conditions, where soil can act as a reservoir and/or emitter of GHG, depending on the balance of inputs and outputs.En actividades agrícolas los principales gases de efecto invernadero (GHG son los relacionados con los ciclos globales de C y N. El impacto de la agricultura sobre las emisiones GHG se ha convertido en una cuestión clave, especialmente si se considera que los ciclos naturales C y N se ven influidos por el desarrollo agrícola. Esta revisión se centra en emisiones de CO2 y N2O del suelo en los ecosistemas terrestres, con énfasis en agro-ecosistemas de Chile y similares alrededor del mundo. Se analiza la influencia del uso del suelo y las prácticas de manejo del cultivo sobre emisiones de CO2 y N2O, se discuten medidas de mitigación para reducir estas emisiones. Un mayor conocimiento sobre los procesos biológicos que promueven las emisiones GHG del suelo permitirá la creación de oportunidades para el desarrollo agrícola en condiciones ambientalmente amigables, donde el suelo puede actuar como un reservorio y/o emisor de GHG, dependiendo del balance de entradas y salidas.

  20. An overview on non-CO2 greenhouse gases

    NARCIS (Netherlands)

    Pulles, T.; Amstel, van A.R.

    2010-01-01

    Non-CO2 greenhouse gases, included in the Kyoto Protocol, are methane (CH4), nitrous oxide (N2O), hexafluorocarbons (HFC), perfluorinated compounds (PFC) and sulphur hexafluoride (SF6). Together they account for about 25% of the present global greenhouse gas emissions. Reductions in emissions of

  1. Full accounting of the greenhouse gas (CO2, N2O, CH4) budget of nine European grassland sites

    DEFF Research Database (Denmark)

    Soussana, J.E.; Allard, V.; Pilegaard, Kim

    2007-01-01

    The full greenhouse gas balance of nine contrasted grassland sites covering a major climatic gradient over Europe was measured during two complete years. The sites include a wide range of management regimes (rotational grazing, continuous grazing and mowing), the three main types of managed grass...

  2. Full accounting of the greenhouse gas (CO2, N2O, CH4) budget of nine European grassland sites

    NARCIS (Netherlands)

    Soussana, J.F.; Allard, V.; Pilegaard, K.; Ambus, P.; Amman, C.; Campbell, C.; Ceschia, E.; Clifton-Brown, J.; Czobel, S.; Domingues, R.; Flechard, C.; Fuhrer, J.; Hensen, A.; Horvath, L.; Jones, M.; Kasper, G.J.; Martin, C.; Nagy, Z.; Neftel, A.; Raschi, A.; Baronti, S.

    2007-01-01

    The full greenhouse gas balance of nine contrasted grassland sites covering a major climatic gradient over Europe was measured during two complete years. The sites include a wide range of management regimes (rotational grazing, continuous grazing and mowing), the three main types of managed

  3. Comparative study of Fischer–Tropsch production and post-combustion CO2 capture at an oil refinery: Economic evaluation and GHG (greenhouse gas emissions) balances

    International Nuclear Information System (INIS)

    Johansson, Daniella; Franck, Per-Åke; Pettersson, Karin; Berntsson, Thore

    2013-01-01

    The impact on CO 2 emissions of integrating new technologies (a biomass-to-Fischer–Tropsch fuel plant and a post-combustion CO 2 capture plant) with a complex refinery has previously been investigated separately by the authors. In the present study these designs are integrated with a refinery and evaluated from the point-of-view of economics and GHG (greenhouse gas emissions) emissions and are compared to a reference refinery. Stand-alone Fischer–Tropsch fuel production is included for comparison. To account for uncertainties in the future energy market, the assessment has been conducted for different future energy market conditions. For the post-combustion CO 2 capture process to be profitable, the present study stresses the importance of a high charge for CO 2 emission. A policy support for biofuels is essential for the biomass-to-Fischer–Tropsch fuel production to be profitable. The level of the support, however, differs depending on scenario. In general, a high charge for CO 2 economically favours Fischer–Tropsch fuel production, while a low charge for CO 2 economically favours Fischer–Tropsch fuel production. Integrated Fischer–Tropsch fuel production is most profitable in scenarios with a low wood fuel price. The stand-alone alternative shows no profitability in any of the studied scenarios. Moreover, the high investment costs make all the studied cases sensitive to variations in capital costs. - Highlights: • Comparison of Fischer–Tropsch (FT) fuel production and CO 2 capture at a refinery. • Subsidies for renewable fuels are essential for FT fuel production to be profitable. • A high charge for CO 2 is essential for post-combustion CO 2 capture to be profitable. • A low charge for CO 2 economically favours FT fuel production. • Of the studied cases, CO 2 capture shows the greatest reduction in GHG emissions

  4. Developments in greenhouse gas emissions and net energy use in Danish agriculture - How to achieve substantial CO2 reduction?

    DEFF Research Database (Denmark)

    Dalgaard, Tommy; Olesen, Jørgen E; Petersen, Søren O

    2011-01-01

    Greenhouse gas (GHG) emissions from agriculture are a significant contributor to total Danish emissions. Consequently, much effort is currently given to the exploration of potential strategies to reduce agricultural emissions. This paper presents results from a study estimating agricultural GHG...... emissions in the form of methane, nitrous oxide and carbon dioxide (including carbon sources and sinks, and the impact of energy consumption/bioenergy production) from Danish agriculture in the years 1990–2010. An analysis of possible measures to reduce the GHG emissions indicated that a 50–70% reduction...... of agricultural emissions by 2050 relative to 1990 is achievable, including mitigation measures in relation to the handling of manure and fertilisers, optimization of animal feeding, cropping practices, and land use changes with more organic farming, afforestation and energy crops. In addition, the bioenergy...

  5. U.S. regional greenhouse gas emissions analysis comparing highly resolved vehicle miles traveled and CO2 emissions: mitigation implications and their effect on atmospheric measurements

    Science.gov (United States)

    Mendoza, D. L.; Gurney, K. R.

    2010-12-01

    Carbon dioxide (CO2) is the most abundant anthropogenic greenhouse gas and projections of fossil fuel energy demand show CO2 concentrations increasing indefinitely into the future. After electricity production, the transportation sector is the second largest CO2 emitting economic sector in the United States, accounting for 32.3% of the total U.S. emissions in 2002. Over 80% of the transport sector is composed of onroad emissions, with the remainder shared by the nonroad, aircraft, railroad, and commercial marine vessel transportation. In order to construct effective mitigation policy for the onroad transportation sector and more accurately predict CO2 emissions for use in transport models and atmospheric measurements, analysis must incorporate the three components that determine the CO2 onroad transport emissions: vehicle fleet composition, average speed of travel, and emissions regulation strategies. Studies to date, however, have either focused on one of these three components, have been only completed at the national scale, or have not explicitly represented CO2 emissions instead relying on the use of vehicle miles traveled (VMT) as an emissions proxy. National-level projections of VMT growth is not sufficient to highlight regional differences in CO2 emissions growth due to the heterogeneity of vehicle fleet and each state’s road network which determines the speed of travel of vehicles. We examine how an analysis based on direct CO2 emissions and an analysis based on VMT differ in terms of their emissions and mitigation implications highlighting potential biases introduced by the VMT-based approach. This analysis is performed at the US state level and results are disaggregated by road and vehicle classification. We utilize the results of the Vulcan fossil fuel CO2 emissions inventory which quantified emissions for the year 2002 across all economic sectors in the US at high resolution. We perform this comparison by fuel type,12 road types, and 12 vehicle types

  6. Non-CO2 Greenhouse Gases: International Emissions and Projections

    Science.gov (United States)

    EPA August 2011 report on global non-CO2 emissions projections (1990-2030) for emissions of non-CO2 greenhouse gases (methane, nitrous oxide, and fluorinated greenhouse gases) from more than twenty emissions sources.

  7. Greenhouse gas (CO2 and CH4) emissions from a high altitude hydroelectric reservoir in the tropics (Riogrande II, Colombia)

    Science.gov (United States)

    Guérin, Frédéric; Leon, Juan

    2015-04-01

    Tropical hydroelectric reservoirs are considered as very significant source of methane (CH4) and carbon dioxide (CO2), especially when flooding dense forest. We report emissions from the Rio Grande II Reservoir located at 2000 m.a.s.l. in the Colombian Andes. The dam was built at the confluence of the Rio Grande and Rio Chico in 1990. The reservoir has a surface of 12 km2, a maximum depth of 40m and a residence time of 2.5 month. Water quality (temperature, oxygen, pH, conductivity), nitrate, ammonium, dissolved and particulate organic carbon (DOC and POC), CO2 and CH4 were monitored bi-monthly during 1.5 year at 9 stations in the reservoir. Diffusive fluxes of CO2 and CH4 and CH4 ebullition were measured at 5 stations. The Rio grande II Reservoir is weakly stratified thermally with surface temperature ranging from 20 to 24°C and a constant bottom temperature of 18°C. The reservoir water column is well oxygenated at the surface and usually anoxic below 10m depth. At the stations close to the tributaries water inputs, the water column is well mixed and oxygenated from the surface to the bottom. As reported for other reservoirs located in "clear water" watersheds, the concentrations of nutrients are low (NO3-10 mmol m-2 d-1) were observed during the dry season. Close to the tributaries water inputs where the water column is well mixed, the average diffusive flux is 8 mmol m-2 d-1. CH4 ebullition was 3.5 mmol m-2 d-1 and no ebullition was observed for a water depth higher than 5m. The zone under the influence of the water inputs from tributaries represents 25% of the surface of the reservoir but contributed half of total CH4 emissions from the reservoir (29MgC month-1). Ebullition contributed only to 12% of total CH4 emissions over a year but it contributed up to 60% during the dry season. CH4 emissions from the Rio Grande Reservoir contributed 30% of the total GHG emissions (38GgCO2eq y-1). Overall, this study show that the majority of CH4 emissions from this

  8. The IAGOS-core greenhouse gas package : a measurement system for continuous airborne observations of CO2, CH4, H2O and CO

    NARCIS (Netherlands)

    Filges, Annette; Gerbig, Christoph; Chen, Huilin; Franke, Harald; Klaus, Christoph; Jordan, Armin

    2015-01-01

    Within the framework of IAGOS-ERI (In-service Aircraft for a Global Observing System - European Research Infrastructure), a cavity ring-down spectroscopy (CRDS)-based measurement system for the autonomous measurement of the greenhouse gases (GHGs) CO2 and CH4, as well as CO and water vapour was

  9. The IAGOS-core greenhouse gas package: a measurement system for continuous airborne observations of CO2, CH4, H2O and CO

    Directory of Open Access Journals (Sweden)

    Annette Filges

    2015-09-01

    Full Text Available Within the framework of IAGOS-ERI (In-service Aircraft for a Global Observing System – European Research Infrastructure, a cavity ring-down spectroscopy (CRDS-based measurement system for the autonomous measurement of the greenhouse gases (GHGs CO2 and CH4, as well as CO and water vapour was designed, tested and qualified for deployment on commercial airliners. The design meets requirements regarding physical dimensions (size, weight, performance (long-term stability, low maintenance, robustness, full automation and safety issues (fire-prevention regulations. The system uses components of a commercially available CRDS instrument (G2401-m, Picarro Inc. mounted into a frame suitable for integration in the avionics bay of the Airbus A330 and A340 series. To enable robust and automated operation of the IAGOS-core GHG package over 6-month deployment periods, numerous technical issues had to be addressed. An inlet system was designed to eliminate sampling of larger aerosols, ice particles and water droplets, and to provide additional positive ram-pressure to ensure operation throughout an aircraft altitude operating range up to 12.5 km without an upstream sampling pump. Furthermore, no sample drying is required as the simultaneously measured water vapour mole fraction is used to correct for dilution and spectroscopic effects. This also enables measurements of water vapour throughout the atmosphere. To allow for trace gas measurements to be fully traceable to World Meteorological Organization scales, a two-standard calibration system has been designed and tested, which periodically provides calibration gas to the instrument during flight and on ground for each 6-month deployment period. The first of the IAGOS-core GHG packages is scheduled for integration in 2015. The aim is to have five systems operational within 4 yr, providing regular, long-term GHG observations covering major parts of the globe. This paper presents results from recent test

  10. The changing role of non co2 greenhouse gases

    Science.gov (United States)

    Khalil, M. A. K.

    During the last century, the concentrations of several greenhouse gases have increased considerably - most notably, methane and nitrous oxide. In addition, new, entirely man - made gases have been put into the atmosphere that also cause the greenhouse effect; these include the chlorofluorocarbons. Calculations have shown that the during the last century the non - CO2 greenhouse gases could together be almost as effective as the increase of carbon dioxide in causing global warming. These and similar gases were therefore included in the Kyoto Protocol to develop a comprehensive plan for controlling global warming. New studies show however that the other gases, with few exceptions, are likely to play a smaller than expected role in future global warming. The most significant non - CO2 man made greenhouse gases are methane and nitrous oxide. Methane rose from 800 ppbv about 200 years ago to about 1700 ppbv in recent times, while nitrous oxide rose from about 285 ppbv to 310 ppbv over the same time. These trends made methane the most important gas for global warming next to carbon dioxide. But now, the trends of methane have declined considerably. Budget analyses suggest that we may not see major changes of concentrations in the future comparable to the trends of the last century. Thus the role of methane in future global warming may be less than expected earlier. Nitrous oxide on the other hand, has increased slowly during the last century, but now there is an indication that it may be increasing faster. The increase of nitrous oxide is still slow, but in time it is likely to become more important than previously thought. While other greenhouse gases such as the perfluorocarbons, sulfur hexafluoride and hydrochlorofluorocarbons are included in the Kyoto Protocol, these are present in such minute concentrations that it is unlikely that they will have an important role in future global warming. Recent studies on the perfluorocarbons show that the trend of the major gas

  11. Biosequestration of atmospheric CO2 and flue gas-containing CO2 by microalgae.

    Science.gov (United States)

    Cheah, Wai Yan; Show, Pau Loke; Chang, Jo-Shu; Ling, Tau Chuan; Juan, Joon Ching

    2015-05-01

    The unceasing rise of greenhouse gas emission has led to global warming and climate change. Global concern on this phenomenon has put forward the microalgal-based CO2 sequestration aiming to sequester carbon back to the biosphere, ultimately reducing greenhouse effects. Microalgae have recently gained enormous attention worldwide, to be the valuable feedstock for renewable energy production, due to their high growth rates, high lipid productivities and the ability to sequester carbon. The photosynthetic process of microalgae uses atmospheric CO2 and CO2 from flue gases, to synthesize nutrients for their growth. In this review article, we will primarily discuss the efficiency of CO2 biosequestration by microalgae species, factors influencing microalgal biomass productions, microalgal cultivation systems, the potential and limitations of using flue gas for microalgal cultivation as well as the bio-refinery approach of microalgal biomass. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Silicon microring refractometric sensor for atmospheric CO(2) gas monitoring.

    Science.gov (United States)

    Mi, Guangcan; Horvath, Cameron; Aktary, Mirwais; Van, Vien

    2016-01-25

    We report a silicon photonic refractometric CO(2) gas sensor operating at room temperature and capable of detecting CO(2) gas at atmospheric concentrations. The sensor uses a novel functional material layer based on a guanidine polymer derivative, which is shown to exhibit reversible refractive index change upon absorption and release of CO(2) gas molecules, and does not require the presence of humidity to operate. By functionalizing a silicon microring resonator with a thin layer of the polymer, we could detect CO(2) gas concentrations in the 0-500ppm range with a sensitivity of 6 × 10(-9) RIU/ppm and a detection limit of 20ppm. The microring transducer provides a potential integrated solution in the development of low-cost and compact CO(2) sensors that can be deployed as part of a sensor network for accurate environmental monitoring of greenhouse gases.

  13. Panorama 2015 - Greenhouse gas emissions in the road transport sector: moving towards inclusion in the European system of CO2 allowances?

    International Nuclear Information System (INIS)

    Coussy, Paula; Portenart, Philomene; Afriat, Marion; Alberola, Emilie

    2014-12-01

    In the year 2000, out of 41.8 Gt of global greenhouse gas (GHG) emissions, almost 10% came from transports sector. In Europe, this share of transports GHG emissions rises to 21% and emissions are forecast to rise. Against this background, should the road transport sector be included in the European Union Emissions Trading Scheme and thereby contribute to national GHG emission reduction targets? (authors)

  14. Net exchanges of CO2, CH4 and N2O between the terrestrial ecosystems and the atmosphere in boreal and arctic region: Towards a full greenhouse gas budget

    Science.gov (United States)

    Zhang, B.; Tian, H.; Lu, C.; Yang, J.; Kamaljit, K.; Pan, S.

    2014-12-01

    Boreal and arctic terrestrial ecosystem is a unique ecological region due to large portion of wetland and permafrost distribution. Increasing disturbances, like permafrost-thaw, fire event, climate extreme, would greatly change the patterns and variations of greenhouse gas emission and further affect the feedback between terrestrial ecosystem and climate change. Carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) accounted for more than 85% of the radioactive forcing (RF) due to long-lived greenhouse gases. However, few studies have considered the full budget of three gases together in this region. In this study, we used a process-based model (Dynamic Land Ecosystem Model), driven by multiple global change factors, to quantify the magnitude, spatial and temporal variation of CO2, CH4 and N2O across the boreal and arctic regions. Simulated results have been evaluated against field observations, inventory-based and atmospheric inversion estimates. By implementing a set of factorial simulations, we further quantify the relative contribution of climate, atmospheric composition, fire to the CO2, CH4 and N2O fluxes. Continued warming climate potentially could shift the inter-annual and intra-annual variation of greenhouse gases fluxes. The understanding of full budget in this region could provide insights for reasonable future projection, which is also crucial for developing effective mitigation strategies.

  15. Why natural gas for CO2 and climate control?

    International Nuclear Information System (INIS)

    Roose, T.R.

    1996-01-01

    The Intergovernmental Panel on Climate Change (IPCC) and the US Environmental Protection Agency (EPA) have suggested that increased use of natural gas is a possible strategy for reducing the potential for global warming. Carbon dioxide (CO 2 ) contributes as much to global warming as all other greenhouse gases combined. During combustion, natural gas generates less CO 2 per unit of energy produced than either coal or oil. On the basis of the amount of CO 2 emitted, the potential for global warming could be reduced by substituting natural gas to coal or oil. However, since natural gas is primarily methane, a potent greenhouse gas, these emissions could reduce natural gas's inherent advantage of lower CO 2 emissions. To address this issue and compare the fuels on an equivalent basis, it is necessary to account for emissions of all greenhouse gases throughout the fuel cycle of each fuel and to determine the impact of these gases on global warming. Gas Research Institute and EPA jointly funded a study to quantify methane emissions from the natural gas industry so that this information could be used as input to address the issue of the fuel switching strategy. The study found that the natural gas industry emitted 1.4% of natural gas production (314 Bscf of methane) to the atmosphere in 1992. Today, due to voluntary reductions from the gas industry, the percent leaked is even less. This 1992 amount has been analyzed over a broad range of global warming potentials, and the conclusion that fuel switching to natural gas reduces the potential for global warming is supported. The results of this study are presented in this paper

  16. Compliance by Design: Influence of Acceleration Trade-offs on CO2Emissions and Costs of Fuel Economy and Greenhouse Gas Regulations.

    Science.gov (United States)

    Whitefoot, Kate S; Fowlie, Meredith L; Skerlos, Steven J

    2017-09-19

    The ability of automakers to improve the fuel economy of vehicles using engineering design modifications that compromise other performance attributes, such as acceleration, is not currently considered when setting fuel economy and greenhouse-gas emission standards for passenger cars and light trucks. We examine the role of these design trade-offs by simulating automaker responses to recently reformed vehicle standards with and without the ability to adjust acceleration performance. Results indicate that acceleration trade-offs can be important in two respects: (1) they can reduce the compliance costs of the standards, and (2) they can significantly reduce emissions associated with a particular level of the standards by mitigating incentives to shift sales toward larger vehicles and light trucks relative to passenger cars. We contrast simulation-based results with observed changes in vehicle attributes under the reformed standards. We find evidence that is consistent with firms using acceleration trade-offs to achieve compliance. Taken together, our analysis suggests that acceleration trade-offs play a role in automaker compliance strategies with potentially large implications for both compliance costs and emissions.

  17. Toolbox of Effects of CO2 Impurities on CO2 Transport and Storage Systems: 13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016. 14 November 2016 through 18 November 2016

    NARCIS (Netherlands)

    Neele, F.; Koornneef, J.; Jakobsen, J.P.; Brunsvold, A.; Eickhoff, C.

    2017-01-01

    There is a need to gather new knowledge on the fundamental properties of CO2 mixtures with impurities and their impact on the chain integrity and economics of Carbon Capture & Storage (CCS) chains. One of the main results from the FP7 IMPACTS project is the IMPACTS toolbox, which comprises new

  18. Greenhouse gas emissions from South Africa

    CSIR Research Space (South Africa)

    Scholes, RJ

    1996-05-01

    Full Text Available of CO2. These gases included 350 Tg CO2 (65.6% of the effect), 183 Tg CH4 (34.2%) and 1.2 Tg N2O (0.2%). The mining and burning of coal contributed more than 80% of the greenhouse gas emissions from South African territory....

  19. REVISITING THE SCATTERING GREENHOUSE EFFECT OF CO2 ICE CLOUDS

    International Nuclear Information System (INIS)

    Kitzmann, D.

    2016-01-01

    Carbon dioxide ice clouds are thought to play an important role for cold terrestrial planets with thick CO 2 dominated atmospheres. Various previous studies showed that a scattering greenhouse effect by carbon dioxide ice clouds could result in a massive warming of the planetary surface. However, all of these studies only employed simplified two-stream radiative transfer schemes to describe the anisotropic scattering. Using accurate radiative transfer models with a general discrete ordinate method, this study revisits this important effect and shows that the positive climatic impact of carbon dioxide clouds was strongly overestimated in the past. The revised scattering greenhouse effect can have important implications for the early Mars, but also for planets like the early Earth or the position of the outer boundary of the habitable zone

  20. Biological methanogenesis and the CO2 greenhouse effect

    Science.gov (United States)

    Guthrie, P. D.

    1986-01-01

    It is well established that plants tend to increase net photosynthesis under increased carbon dioxide. It is also well established that a large fraction of atmospheric methane is produced by microbial metabolism of organic sediments in paddies and freshwater wetlands, where a major source of organic debris is local plant growth. As CO2 increases, it may lead to increased methane production and a resulting enhancement of the expected greenhouse warming. A rough estimate of the present rate of this biologically mediated feedback on the climate system indicates that it might account for as much as 30 percent of the observed methane increase and speed up the greenhouse forcing by as much as 15 percent.

  1. Revisiting the Scattering Greenhouse Effect of CO2 Ice Clouds

    Science.gov (United States)

    Kitzmann, D.

    2016-02-01

    Carbon dioxide ice clouds are thought to play an important role for cold terrestrial planets with thick CO2 dominated atmospheres. Various previous studies showed that a scattering greenhouse effect by carbon dioxide ice clouds could result in a massive warming of the planetary surface. However, all of these studies only employed simplified two-stream radiative transfer schemes to describe the anisotropic scattering. Using accurate radiative transfer models with a general discrete ordinate method, this study revisits this important effect and shows that the positive climatic impact of carbon dioxide clouds was strongly overestimated in the past. The revised scattering greenhouse effect can have important implications for the early Mars, but also for planets like the early Earth or the position of the outer boundary of the habitable zone.

  2. Calculating CO2 footprint of the organic greenhouse horticulture

    NARCIS (Netherlands)

    Vermeulen, P.C.M.

    2010-01-01

    In recent years the horticultural sector has been confronted with questions about the carbon footprint of its products. However, the global standards used to calculate the greenhouse gas (GHG) emissions have some gaps that do not address the sector specific issues for horticulture, such as crop

  3. Power stabilized CO2 gas transport laser

    International Nuclear Information System (INIS)

    Foster, J.D.; Kirk, R.F.; Moreno, F.E.; Ahmed, S.A.

    1975-01-01

    The output power of a high power (1 kW or more) CO 2 gas transport laser is stabilized by flowing the gas mixture over copper plated baffles in the gas channel during operation of the laser. Several other metals may be used instead of copper, for example, nickel, manganese, palladium, platinum, silver and gold. The presence of copper in the laser gas circuit stabilizes output power by what is believed to be a compensation of the chemical changes in the gas due to the cracking action of the electrical discharge which has the effect of diminishing the capactiy of the carbon dioxide gas mixture to maintain the rated power output of the laser. (U.S.)

  4. The CO2 diet for a greenhouse planet: Assessing individual actions for slowing global warming

    International Nuclear Information System (INIS)

    DeCicco, J.; Cook, J.; Bolze, D.; Beyea, J.

    1990-01-01

    Because of uncontrolled population growth and a short-sighted choice of technologies, humankind is emitting enormous quantities of greenhouse gases. Reducing emissions of these gases which can disrupt the Earth's climate will require action by individuals as well as by governments and industries. Most energy use currently entails carbon dioxide (CO 2 ) emissions; increasing energy efficiency can therefore address a major portion of the emissions. Reducing emissions of other greenhouse gases, such as halocarbons, is also necessary. Following such a low-CO 2 diet will require lifestyle changes and prudent consumption choices by individuals. This paper focuses on the activities related to greenhouse gas emissions in the US over which individuals have some control

  5. National Greenhouse Gas Emission Inventory

    Data.gov (United States)

    U.S. Environmental Protection Agency — The National Greenhouse Gas Emission Inventory contains information on direct emissions of greenhouse gases as well as indirect or potential emissions of greenhouse...

  6. Integrated optimization of temperature, CO2, screen use and artificial lighting in greenhouse crops

    DEFF Research Database (Denmark)

    Aaslyng, J.M.; Körner, O.; Andreassen, A.U.

    2005-01-01

    A leaf photosynthesis model is suggested for integrated optimization of temperature, CO2, screen use and artificial lighting in greenhouse crops. Three different approaches for the optimization are presented. First, results from greenhouse experiments with model based optimization are presented...... of temperature, CO2, and light in the greenhouse...

  7. Greenhouse gas emissions related to Dutch food consumption

    NARCIS (Netherlands)

    Kramer, KJ; Moll, HC; Nonhebel, S; Wilting, HC

    The consumption of food products involves emissions of greenhouse gases. Emissions occur in the various stages of the life cycle of food products. In this paper we discuss the greenhouse gas emissions, CO2, CH4, and N2O, related to Dutch household food consumption. Combinations of greenhouse gas

  8. Petition for Reconsideration from Biogenic CO2 Coalition to Gina McCarthy, U.S. EPA, for the Finding that Greenhouse Gas Emissions from Aircraft Cause or Contribute to Air Pollution that May Reasonably be Anticipated to Endanger Public Health and Welfare

    Science.gov (United States)

    This page contains a Petition for Reconsideration From Biogenic CO2 Coalition to Gina McCarthy, U.S. EPA, for the finding that greenhouse gas emissions from aircraft cause or contribute to air pollution that may reasonably be anticipated to endanger public

  9. Greenhouse Gas Data Publication Tool

    Data.gov (United States)

    U.S. Environmental Protection Agency — This tool to gives you access to greenhouse gas data reported to EPA by large facilities and suppliers in the United States through EPA's Greenhouse Gas Reporting...

  10. Increased soil emissions of potent greenhouse gases under increased atmospheric CO2.

    Science.gov (United States)

    van Groenigen, Kees Jan; Osenberg, Craig W; Hungate, Bruce A

    2011-07-13

    Increasing concentrations of atmospheric carbon dioxide (CO(2)) can affect biotic and abiotic conditions in soil, such as microbial activity and water content. In turn, these changes might be expected to alter the production and consumption of the important greenhouse gases nitrous oxide (N(2)O) and methane (CH(4)) (refs 2, 3). However, studies on fluxes of N(2)O and CH(4) from soil under increased atmospheric CO(2) have not been quantitatively synthesized. Here we show, using meta-analysis, that increased CO(2) (ranging from 463 to 780 parts per million by volume) stimulates both N(2)O emissions from upland soils and CH(4) emissions from rice paddies and natural wetlands. Because enhanced greenhouse-gas emissions add to the radiative forcing of terrestrial ecosystems, these emissions are expected to negate at least 16.6 per cent of the climate change mitigation potential previously predicted from an increase in the terrestrial carbon sink under increased atmospheric CO(2) concentrations. Our results therefore suggest that the capacity of land ecosystems to slow climate warming has been overestimated. ©2011 Macmillan Publishers Limited. All rights reserved

  11. A "Greenhouse Gas" Experiment for the Undergraduate Laboratory

    Science.gov (United States)

    Gomez, Elaine; Paul, Melissa; Como, Charles; Barat, Robert

    2014-01-01

    This experiment and analysis offer an effective experience in greenhouse gas reduction. Ammoniated water is flowed counter-current to a simulated flue gas of air and CO2 in a packed column. The gaseous CO2 concentrations are measured with an on-line, non- dispersive, infrared analyzer. Column operating parameters include total gas flux, dissolved…

  12. Capturing and storing CO2 to combat the greenhouse effect. What IFP is doing

    International Nuclear Information System (INIS)

    2009-01-01

    The growing awareness of the international community and the convergence of the scientific data concerning climate change make it urgent to deploy, throughout the world, technologies to reduce emissions of greenhouse gases. Indeed, the growth of the world energy demand will prevent any rapid reduction of the use of fossil fuels - oil, natural gas, and coal - that are the main sources of greenhouse gas emissions. To reconcile the use of these resources with control of the emissions responsible for global warming, the capture and storage of CO 2 are a very promising approach; the economic and industrial stakes are high. To meet the objective of reducing CO 2 emissions, IFP is exploring three approaches: The first approach is to reduce energy consumption by improving the efficiency of energy converters, in particular internal combustion engines. A second approach is to reduce the carbon content of energy by favoring the use of natural gas or by incorporating in the fuel recycled carbon (biofuels and synfuels) and by developing hydrogen as an energy carrier. The third approach is to capture the CO 2 from industrial processes used for electricity, steel, and cement production, which emit it in large quantities, then store it underground so as to keep it out of the atmosphere. This approach for reducing the CO 2 emissions consists in capturing the CO 2 (Post-combustion, oxy-combustion), transporting it to the place of storage, then injecting it underground to store it. Storage sites are selected and evaluated prior to injection in order to estimate the injectivity, the propagation of CO 2 in the subsoil and the impact of geochemical and geomechanical transformations on the tightness of the overburden and of the injection well. The injection phase is followed by a phase of monitoring to ensure the safety and long-term viability of CO 2 storage facilities. IFP, through the research it is conducting either alone or in partnership with universities, research centers, and the

  13. CO2 Capture by Injection of Flue Gas or CO2-N2 Mixtures into Hydrate Reservoirs: Dependence of CO2 Capture Efficiency on Gas Hydrate Reservoir Conditions.

    Science.gov (United States)

    Hassanpouryouzband, Aliakbar; Yang, Jinhai; Tohidi, Bahman; Chuvilin, Evgeny; Istomin, Vladimir; Bukhanov, Boris; Cheremisin, Alexey

    2018-04-03

    Injection of flue gas or CO 2 -N 2 mixtures into gas hydrate reservoirs has been considered as a promising option for geological storage of CO 2 . However, the thermodynamic process in which the CO 2 present in flue gas or a CO 2 -N 2 mixture is captured as hydrate has not been well understood. In this work, a series of experiments were conducted to investigate the dependence of CO 2 capture efficiency on reservoir conditions. The CO 2 capture efficiency was investigated at different injection pressures from 2.6 to 23.8 MPa and hydrate reservoir temperatures from 273.2 to 283.2 K in the presence of two different saturations of methane hydrate. The results showed that more than 60% of the CO 2 in the flue gas was captured and stored as CO 2 hydrate or CO 2 -mixed hydrates, while methane-rich gas was produced. The efficiency of CO 2 capture depends on the reservoir conditions including temperature, pressure, and hydrate saturation. For a certain reservoir temperature, there is an optimum reservoir pressure at which the maximum amount of CO 2 can be captured from the injected flue gas or CO 2 -N 2 mixtures. This finding suggests that it is essential to control the injection pressure to enhance CO 2 capture efficiency by flue gas or CO 2 -N 2 mixtures injection.

  14. Greenhouse gas emissions from hydroelectric reservoirs

    International Nuclear Information System (INIS)

    Rosa, L.P.; Schaeffer, R.

    1994-01-01

    In a recent paper, Rudd et al. have suggested that, per unit of electrical energy produced, greenhouse-gas emissions from some hydroelectric reservoirs in northern Canada may be comparable to emissions from fossil-fuelled power plants. The purpose of this comment is to elaborate these issues further so as to understand the potential contribution of hydroelectric reservoirs to the greenhouse effect. More than focusing on the total budget of carbon emissions (be they in the form of CH 4 or be they in the form of CO 2 ), this requires an evaluation of the accumulated greenhouse effect of gas emissions from hydroelectric reservoirs and fossil-fuelled power plants. Two issues will be considered: (a) global warming potential (GWP) for CH 4 ; and (b) how greenhouse-gas emissions from hydroelectric power plants stand against emissions from fossil-fuelled power plants with respect to global warming

  15. Quantification of temperature, CO2, and light effects on crop photosynthesis as a basis for model-based greenhouse climate control

    NARCIS (Netherlands)

    Körner, O.; Heuvelink, E.; Niu, Q.

    2009-01-01

    Detailed measurements of crop photosynthesis at supra-optimal temperatures and high CO2 levels, to validate models for use in model-based greenhouse climate control, are still lacking. We performed CO2 gas exchange measurements to estimate gross crop photosynthesis (Pgc) from measured net crop gas

  16. Technological substitution options for controlling greenhouse gas emissions

    International Nuclear Information System (INIS)

    Barbier, E.B.; Burgess, J.C.; Pearce, D.W.

    1991-01-01

    This chapter is concerned with technological options for greenhouse gas substitution. The authors interpret the term substitution to exclude energy conservation/efficiency measures, investments in afforestation (sinks), and greenhouse gas removal or abatement technologies. Their working definition of greenhouse gas substitution includes (1) replacement technologies, for example, substituting a greenhouse gas technology with a nongreenhouse gas technology; and (2) reduction technologies, for example, substituting a greenhouse gas technology with an alternative technology that reduces greenhouse gas emissions. Essentially, replacement technologies involve 100 percent reduction in CO 2 ; reduction technologies involve a partial reduction in CO 2 . Of the man-made sources of greenhouse gases, energy is the most important and is expected to contribute to at least half of the global warming effect in the near future. The majority of this impact is from fossil fuel combustion as a source of carbon dioxide (CO 2 ), although fossil fuels also contribute significantly to methane (CH 4 ), to nitrous oxide (N 2 O), and to low-level ozone (O 3 ) through production of various nitrogen gases (NO x ) and carbon monoxide (CO). This study analyzes the available greenhouse gas substitutions and their costs. The authors concentrate particularly on substitutions for fossil-fuel combustion and CFC production and consumption. They conclude by summarizing the potential for greenhouse gas substitution, the cost-effectiveness of the various options and the design of incentives for substitution

  17. OPIC Greenhouse Gas Emissions Inventory

    Data.gov (United States)

    Overseas Private Investment Corporation — Independent analysis details quantifying the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private Investment Corporation...

  18. Trace Gases, CO2, Climate, and the Greenhouse Effect.

    Science.gov (United States)

    Aubrecht, Gordon J., II

    1988-01-01

    Reports carbon dioxide and other trace gases can be the cause of the Greenhouse Effect. Discusses some effects of the temperature change and suggests some solutions. Included are several diagrams, graphs, and a table. (YP)

  19. Modeling CO2 Gas Migration of Shallow Subsurface CO2 Leakage Experiments

    Science.gov (United States)

    Porter, M. L.; Plampin, M. R.; Pawar, R.; Illangasekare, T. H.

    2013-12-01

    Leakage of injected CO2 into shallow subsurface aquifers or back into the atmosphere at geologic carbon sequestration sites is a risk that must be minimized. One potential CO2 leakage pathway involves the transport of dissolved CO2 into a shallow aquifer where the CO2 exsolves, forming a free CO2 gas phase that subsequently migrates through the aquifer. In order to reduce the negative effects of CO2 exsolution, it is important to fully understand each of the processes controlling the movement CO2, as well as the effects of aquifer heterogeneity on the overall fate and transport of CO2. In this work, we present multiphase flow simulations of intermediate scale CO2 exsolution experiments. The multiphase flow simulations were carried out using the Finite Element Heat and Mass Transfer code (FEHM) developed at Los Alamos National Laboratory. Simulations were first designed to model experiments conducted in two different homogeneous packed sands. PEST (Parameter Estimation and Uncertainty Analysis) was used to optimize multiphase flow parameters (i.e., porosity, permeability, relative permeability, and capillary pressure) within FEHM. The optimized parameters were subsequently used to model heterogeneous experiments consisting of various packing configurations using the same sands. Comparisons of CO2 saturation between experiments and simulations will be presented and analyzed.

  20. CO2 capture by gas hydrate crystallization: Application on the CO2-N2 mixture

    International Nuclear Information System (INIS)

    Bouchemoua, A.

    2012-01-01

    CO 2 capture and sequestration represent a major industrial and scientific challenge of this century. There are different methods of CO 2 separation and capture, such as solid adsorption, amines adsorption and cryogenic fractionation. Although these processes are well developed at industrial level, they are energy intensive. Hydrate formation method is a less energy intensive and has an interesting potential to separate carbon dioxide. Gas hydrates are Document crystalline compounds that consist of hydrogen bonded network of water molecules trapping a gas molecule. Gas hydrate formation is favored by high pressure and low temperature. This study was conducted as a part of the SECOHYA ANR Project. The objective is to study the thermodynamic and kinetic conditions of the process to capture CO 2 by gas hydrate crystallization. Firstly, we developed an experimental apparatus to carry out experiments to determine the thermodynamic and kinetic formation conditions of CO 2 -N 2 gas hydrate mixture in water as liquid phase. We showed that the operative pressure may be very important and the temperature very low. For the feasibility of the project, we used TBAB (Tetrabutylammonium Bromide) as thermodynamic additive in the liquid phase. The use of TBAB may reduce considerably the operative pressure. In the second part of this study, we presented a thermodynamic model, based on the van der Waals and Platteeuw model. This model allows the estimation of thermodynamic equilibrium conditions. Experimental equilibrium data of CO 2 -CH 4 and CO 2 -N 2 mixtures are presented and compared to theoretical results. (author)

  1. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Fauth, D.J.; Filburn, T.P. (University of Hartford, West Hartford, CT); Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2

  2. Global Mitigation of Non-CO2 Greenhouse Gases - Data Annexes

    Data.gov (United States)

    U.S. Environmental Protection Agency — Marginal abatement curves (MAC) can be downloaded as data annexes to the Global Mitigation of Non-CO2 Greenhouse Gases report. This data allows for improved...

  3. Global Anthropogenic Emissions of Non-CO2 Greenhouse Gases 1990-2020

    Data.gov (United States)

    U.S. Environmental Protection Agency — The data in these Appendices to the Global Anthropogenic Emissions of Non-CO2 Greenhouse Gases (1990-2020) report provide historical and projected estimates of...

  4. Ozone: The secret greenhouse gas

    International Nuclear Information System (INIS)

    Berntsen, Terje; Tjernshaugen, Andreas

    2001-01-01

    The atmospheric ozone not only protects against harmful ultraviolet radiation; it also contributes to the greenhouse effect. Ozone is one of the jokers to make it difficult to calculate the climatic effect of anthropogenic emissions. The greenhouse effect and the ozone layer should not be confused. The greenhouse effect creates problems when it becomes enhanced, so that the earth becomes warmer. The problem with the ozone layer, on the contrary, is that it becomes thinner and so more of the harmful ultraviolet radiation gets through to the earth. However, ozone is also a greenhouse gas and so the greenhouse effect and the ozone layer are connected

  5. USDA Agriculture and Forestry Greenhouse Gas Inventory: 1990-2013

    Science.gov (United States)

    Carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) concentrations in the atmosphere have increased by approximately 43%, 152%, and 20% respectively since about 1750. In 2013, total U.S. greenhouse gas emissions were 6,673 million metric tons of carbon dioxide equivalents (MMT CO2 eq.), ris...

  6. TREATMENT OF NATURAL GAS BY ADSORPTION OF CO2

    Directory of Open Access Journals (Sweden)

    Kristýna Hádková

    2015-12-01

    Full Text Available Apart from burning, one of the possible uses of natural gas is as a fuel for motor vehicles. There are two types of fuel from natural gas — CNG (Compressed Natural Gas or LNG (Liquefied Natural Gas. Liquefaction of natural gas is carried out for transport by tankers, which are an alternative to long-distance gas pipelines, as well as for transport over short distance, using LNG as a fuel for motor vehicles. A gas adjustment is necessary to get LNG. As an important part of the necessary adjustment of natural gas to get LNG, a reduction of CO2 is needed. There is a danger of the carbon dioxide freezing during the gas cooling. This work deals with the testing of adsorption removal of CO2 from natural gas. The aim of these measurements was to find a suitable adsorbent for CO2 removal from natural gas. Two different types of adsorbents were tested: activated carbon and molecular sieve. The adsorption properties of the selected adsorbents were tested and compared. The breakthrough curves for CO2 for both adsorbents were measured. The conditions of the testing were estimated according to conditions at a gas regulation station — 4.0MPa pressure and 8 °C temperature. Natural gas was simulated by model gas mixture during the tests. The breakthrough volume was set as the gas volume passing through the adsorber up to the CO2 concentration of 300 ml/m3 in the exhaust gas. The thermal and pressure desorption of CO2 from saturated adsorbents were also tested after the adsorption.

  7. Improving material management to reduce greenhouse gas emissions

    NARCIS (Netherlands)

    Hekkert, Marko Peter

    2000-01-01

    Climate change due to greenhouse gas emissions caused by human actions is probably one of the major global environmental problems that we face today. In order to reduce the risk of climate change and the potential effects thereof, the emission of greenhouse gases like carbon dioxide (CO2) and

  8. Greenhouse gas trading starts up

    Science.gov (United States)

    Showstack, Randy

    While nations decide on whether to sign on to the Kyoto Protocol on climate change, some countries and private companies are moving forward with greenhouse gas emissions trading.A 19 March report, "The Emerging International Greenhouse Gas Market," by the Pew Center on Global Climate Change, reports that about 65 greenhouse gas emissions trades for quantities above 1,000 metric tons of carbon dioxideequivalent already have occurred worldwide since 1996. Many of these trades have taken place under a voluntary, ad hoc framework, though the United Kingdom and Denmark have established their own domestic emissions trading programs.

  9. Faults as Windows to Monitor Gas Seepage: Application to CO2 Sequestration and CO2-EOR

    Directory of Open Access Journals (Sweden)

    Ronald W. Klusman

    2018-03-01

    Full Text Available Monitoring of potential gas seepage for CO2 sequestration and CO2-EOR (Enhanced Oil Recovery in geologic storage will involve geophysical and geochemical measurements of parameters at depth and at, or near the surface. The appropriate methods for MVA (Monitoring, Verification, Accounting are needed for both cost and technical effectiveness. This work provides an overview of some of the geochemical methods that have been demonstrated to be effective for an existing CO2-EOR (Rangely, CA, USA and a proposed project at Teapot Dome, WY, USA. Carbon dioxide and CH4 fluxes and shallow soil gas concentrations were measured, followed by nested completions of 10-m deep holes to obtain concentration gradients. The focus at Teapot Dome was the evaluation of faults as pathways for gas seepage in an under-pressured reservoir system. The measurements were supplemented by stable carbon and oxygen isotopic measurements, carbon-14, and limited use of inert gases. The work clearly demonstrates the superiority of CH4 over measurements of CO2 in early detection and quantification of gas seepage. Stable carbon isotopes, carbon-14, and inert gas measurements add to the verification of the deep source. A preliminary accounting at Rangely confirms the importance of CH4 measurements in the MVA application.

  10. Innovative technologies for greenhouse gas emission reduction in steel production

    Directory of Open Access Journals (Sweden)

    D. Burchart-Korol

    2016-01-01

    Full Text Available The main goal of the study was to present the most significant technological innovations aiming at reduction of greenhouse gas emission in steel production. Reduction of greenhouse gas and dust pollution is a very important aspect in the iron and steel industry. New solutions are constantly being searched for to reduce greenhouse gases (GHG. The article presents the most recent innovative technologies which may be applied in the steel industry in order to limit the emission of GHG. The significance of CCS (CO2 Capture and Storage and CCU (CO2 Capture and Utilization in the steel industry are also discussed.

  11. Consequences of agro-biofuel production for greenhouse gas emissions

    DEFF Research Database (Denmark)

    Carter, Mette Sustmann; Hauggaard-Nielsen, Henrik; Johansen, Anders

    2009-01-01

    Currently CO2 from fossil fuel combustion accounts for 57% of the global greenhouse gas emissions, whereas the strong greenhouse gases nitrous oxide (N2O) and methane (CH4) contribute with 8% and 14%, respectively (IPCC, 2007). Agricultural activity is the dominant source of N2O, which is mainly...... as fertilizer for a maize energy crop within an organic cropping system. Furthermore, we assessed sustainability in terms of greenhouse gasses for co-production of bio-ethanol and bio-gas from maize. This was compared to estimated greenhouse gas balances for rye and grass-clover as alternative raw materials....

  12. How increasing CO2 leads to an increased negative greenhouse effect in Antarctica

    Science.gov (United States)

    Schmithüsen, Holger; Notholt, Justus; König-Langlo, Gert; Lemke, Peter; Jung, Thomas

    2015-12-01

    CO2 is the strongest anthropogenic forcing agent for climate change since preindustrial times. Like other greenhouse gases, CO2 absorbs terrestrial surface radiation and causes emission from the atmosphere to space. As the surface is generally warmer than the atmosphere, the total long-wave emission to space is commonly less than the surface emission. However, this does not hold true for the high elevated areas of central Antarctica. For this region, the emission to space is higher than the surface emission; and the greenhouse effect of CO2 is around zero or even negative, which has not been discussed so far. We investigated this in detail and show that for central Antarctica an increase in CO2 concentration leads to an increased long-wave energy loss to space, which cools the Earth-atmosphere system. These findings for central Antarctica are in contrast to the general warming effect of increasing CO2.

  13. A Highly Stable Microporous Covalent Imine Network Adsorbent for Natural Gas Upgrading and Flue Gas CO2 Capture

    KAUST Repository

    Das, Swapan Kumar

    2016-06-06

    The feasible capture and separation of CO2 and N2 from CH4 is an important task for natural gas upgrading and the control of greenhouse gas emissions. Here, we studied the microporous covalent imine networks (CIN) material prepared through Schiff base condensation and exhibited superior chemical robustness under both acidic and basic conditions and high thermal stability. The material possesses a relatively uniform nanoparticle size of approximately 70 to 100 nm. This network featured permanent porosity with a high surface area (722 m2g-1) and micropores. A single-component gas adsorption study showed enhanced CO2 and CH4 uptakes of 3.32 mmol/g and 1.14 mmol/g, respectively, at 273 K and 1 bar, coupled with high separation selectivities for CO2/CH4, CH4/N2, and CO2/N2 of 23, 11.8 and 211, respectively. The enriched Lewis basicity in the porous skeletons favours the interaction of quadrupolar CO2 and polarizable CH4, resulting in enhanced CH4 and CO2 uptake and high CH4/N2, CO2/CH4 and CO2/N2 selectivities. Breakthrough experiments showed high CO2/CH4, CH4/N2 and CO2/N2 selectivities of 7.29, 40 and 125, respectively, at 298 K and 1 bar. High heats of adsorption for CH4 and CO2 (QstCH4; 32.61 kJ mol-1 and QstCO2; 42.42 kJ mol-1) provide the ultimate validation for the high selectivity. To the best of our knowledge, such a versatile adsorbent material that displays both enhanced uptake and selectivity for a variety of binary gas mixtures, including CO2/ CH4, CO2/N2 and CH4/N2, has not been extensively explored.

  14. Transit Greenhouse Gas Management Compendium

    Science.gov (United States)

    2011-01-12

    This Compendium provides a framework for identifying greenhouse gas (GHG) reduction opportunities while highlighting specific examples of effective GHG reduction practices. The GHG savings benefits of public transit are first described. GHG saving op...

  15. Assisting Gas Optimization in CO2 Laser Welding

    DEFF Research Database (Denmark)

    Gong, Hui; Olsen, Flemming Ove

    1996-01-01

    are applied with three different flow rates for each of the gases. A number of systematic laboratory experiments is carried out by employing various experimental designs, 33 and 32 Factorial Design. In the experiments a CO2 laser is used to weld thin sheets of mild steel. The welding specimens are evaluated....... The relations between the gas parameters and signal frequencies are studied. Finally the relationships of the gas parameters and weld characteristics are studied. The possibility of using photo diode signals in controlling the gas parameters is discussed.KeywordsCO2 laser welding, assisting gas parameters...

  16. Gas permeation process for post combustion CO2 capture

    International Nuclear Information System (INIS)

    Pfister, Marc

    2017-01-01

    CO 2 Capture and Storage (CCS) is a promising solution to separate CO 2 from flue gas, to reduce the CO 2 emissions in the atmosphere, and hence to reduce global warming. In CCS, one important constraint is the high additional energy requirement of the different capture processes. That statement is partly explained by the low CO 2 fraction in the inlet flue gas and the high output targets in terms of CO 2 capture and purity (≥90%). Gas permeation across dense membrane can be used in post combustion CO 2 capture. Gas permeation in a dense membrane is ruled by a mass transfer mechanism and separation performance in a dense membrane are characterized by component's effective permeability and selectivity. One of the newest and encouraging type of membrane in terms of separation performance is the facilitated transport membrane. Each particular type of membrane is defined by a specific mass transfer law. The most important difference to the mass transfer behavior in a dense membrane is related to the facilitated transport mechanism and the solution diffusion mechanism and its restrictions and limitations. Permeation flux modelling across a dense membrane is required to perform a post combustion CO 2 capture process simulation. A CO 2 gas permeation separation process is composed of a two-steps membrane process, one drying step and a compression unit. Simulation on the energy requirement and surface area of the different membrane modules in the global system are useful to determine the benefits of using dense membranes in a post combustion CO 2 capture technology. (author)

  17. System-level modeling for economic evaluation of geological CO2 storage in gas reservoirs

    International Nuclear Information System (INIS)

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2007-01-01

    One way to reduce the effects of anthropogenic greenhouse gases on climate is to inject carbon dioxide (CO 2 ) from industrial sources into deep geological formations such as brine aquifers or depleted oil or gas reservoirs. Research is being conducted to improve understanding of factors affecting particular aspects of geological CO 2 storage (such as storage performance, storage capacity, and health, safety and environmental (HSE) issues) as well as to lower the cost of CO 2 capture and related processes. However, there has been less emphasis to date on system-level analyses of geological CO 2 storage that consider geological, economic, and environmental issues by linking detailed process models to representations of engineering components and associated economic models. The objective of this study is to develop a system-level model for geological CO 2 storage, including CO 2 capture and separation, compression, pipeline transportation to the storage site, and CO 2 injection. Within our system model we are incorporating detailed reservoir simulations of CO 2 injection into a gas reservoir and related enhanced production of methane. Potential leakage and associated environmental impacts are also considered. The platform for the system-level model is GoldSim [GoldSim User's Guide. GoldSim Technology Group; 2006, http://www.goldsim.com]. The application of the system model focuses on evaluating the feasibility of carbon sequestration with enhanced gas recovery (CSEGR) in the Rio Vista region of California. The reservoir simulations are performed using a special module of the TOUGH2 simulator, EOS7C, for multicomponent gas mixtures of methane and CO 2 . Using a system-level modeling approach, the economic benefits of enhanced gas recovery can be directly weighed against the costs and benefits of CO 2 injection

  18. Recent data concerning contribution of various greenhouse effect gas sources

    International Nuclear Information System (INIS)

    Lambert, G.

    1991-01-01

    The greenhouse effect contributes to a +33 degrees C warming of the earth atmosphere (mean temperature of +15 deg C instead of -18 deg C without any greenhouse effect). The roles of water vapour, carbon dioxide and methane in greenhouse effect are discussed; the CH 4 raise seems to be due to rice cultivation and cattle farming; the CO 2 raise is mainly due oil, coal and natural gas burning. Greenhouse gas increase will cause a 2 to 4 deg C increase of the earth mean temperature but the anthropogenous causes will be obviously seen only during the next century

  19. Pemanfaatan Emisi Gas Co2 Untuk Budidaya Spirulina Platensis Dalam Upaya Penurunan Gas Rumah Kaca (Grk)

    OpenAIRE

    Setiawan, Yusup; Surachman, Aep; Asthary, Prima Besty; Saepulloh

    2014-01-01

    Gas CO2 emisi boiler merupakan salahsatu Gas Rumah Kaca (GRK) harus diminimisasi emisinya ke atmosfir. Pada saat ini emisi boiler dibuang ke atmosfir belum termanfaatkan. Percobaan budi daya Spirulina platensis skala laboratorium dengan penambahan gas CO2 emisi boiler telah dilakukan. Emisi CO2 boiler berbahan bakar batubara industri kertas berbahan baku kertas bekas digunakan dalam percobaan ini. Gas CO2 emisi boiler ditambahkan ke dalam media tumbuh Spirulina platensis dengan laju alir 250 ...

  20. Techno-economic Issues and Trade-offs for CO2 Purity in CCS Chains: 13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016. 14 November 2016 through 18 November 2016

    NARCIS (Netherlands)

    Eickhoff, C.; Brown, A.; Neele, F.

    2017-01-01

    The IMPACTS project has the objective to develop the knowledge base of CO2 quality required for establishing norms and regulations to ensure safe and reliable design, construction and operation of CO2 pipelines and injection equipment, and safe long-term geological storage of CO2. More specifically

  1. Noble gas geochemistry to monitor CO2 geological storages

    International Nuclear Information System (INIS)

    Lafortune, St.

    2007-11-01

    According to the last IPCC (Intergovernmental Panel on Climate Change) report, a probability of 90 % can be now established for the responsibility of the anthropogenic CO 2 emissions for the global climate change observed since the beginning of the 20. century. To reduce these emissions and keep producing energy from coal, oil or gas combustions, CO 2 could be stored in geological reservoirs like aquifers, coal beds, and depleted oil or gas fields. Storing CO 2 in geological formations implies to control the efficiency and to survey the integrity of the storages, in order to be able to detect the possible leaks as fast as possible. Here, we study the feasibility of a geochemical monitoring through noble gas geochemistry. We present (1) the development of a new analytical line, Garodiox, developed to extract quantitatively noble gas from water samples, (2) the testing of Garodiox on samples from a natural CO 2 storage analogue (Pavin lake, France) and (3) the results of a first field work on a natural CO 2 accumulation (Montmiral, France). The results we obtain and the conclusions we draw, highlight the interest of the geochemical monitoring we suggest. (author)

  2. The effect of heating technologies on CO2 and energy efficiency of Dutch greenhouse firms

    NARCIS (Netherlands)

    Oude Lansink, A.G.J.M.; Bezlepkin, I.

    2003-01-01

    This paper uses Data Envelopment Analysis to compute measures of the efficiency (relative to a frontier) in terms of the use of all inputs as well as for single inputs like CO2 and energy for a sample of greenhouse firms in the Netherlands over the period 1991-1995. These efficiency measures are

  3. Advancing agricultural greenhouse gas quantification*

    Science.gov (United States)

    Olander, Lydia; Wollenberg, Eva; Tubiello, Francesco; Herold, Martin

    2013-03-01

    increased emissions unless we improve production efficiencies and management. Developing countries currently account for about three-quarters of direct emissions and are expected to be the most rapidly growing emission sources in the future (FAO 2011). Reducing agricultural emissions and increasing carbon sequestration in the soil and biomass has the potential to reduce agriculture's contribution to climate change by 5.5-6.0 gigatons (Gt) of carbon dioxide equivalent (CO2eq)/year. Economic potentials, which take into account costs of implementation, range from 1.5 to 4.3 GT CO2eq/year, depending on marginal abatement costs assumed and financial resources committed, with most of this potential in developing countries (Smith et al 2007). The opportunity for mitigation in agriculture is thus significant, and, if realized, would contribute to making this sector carbon neutral. Yet it is only through a robust and shared understanding of how much carbon can be stored or how much CO2 is reduced from mitigation practices that informed decisions can be made about how to identify, implement, and balance a suite of mitigation practices as diverse as enhancing soil organic matter, increasing the digestibility of feed for cattle, and increasing the efficiency of nitrogen fertilizer applications. Only by selecting a portfolio of options adapted to regional characteristics and goals can mitigation needs be best matched to also serve rural development goals, including food security and increased resilience to climate change. Expansion of agricultural land also remains a major contributor of greenhouse gases, with deforestation, largely linked to clearing of land for cultivation or pasture, generating 80% of emissions from developing countries (Hosonuma et al 2012). There are clear opportunities for these countries to address mitigation strategies from the forest and agriculture sector, recognizing that agriculture plays a large role in economic and development potential. In this context

  4. Greenhouse gas emissions from high demand, natural gas-intensive energy scenarios

    International Nuclear Information System (INIS)

    Victor, D.G.

    1990-01-01

    Since coal and oil emit 70% and 30% more CO 2 per unit of energy than natural gas (methane), fuel switching to natural gas is an obvious pathway to lower CO 2 emissions and reduced theorized greenhouse warming. However, methane is, itself, a strong greenhouse gas so the CO 2 advantages of natural gas may be offset by leaks in the natural gas recovery and supply system. Simple models of atmospheric CO 2 and methane are used to test this hypothesis for several natural gas-intensive energy scenarios, including the work of Ausubel et al (1988). It is found that the methane leaks are significant and may increase the total 'greenhouse effect' from natural gas-intensive energy scenarios by 10%. Furthermore, because methane is short-lived in the atmosphere, leaking methane from natural gas-intensive, high energy growth scenarios effectively recharges the concentration of atmospheric methane continuously. For such scenarios, the problem of methane leaks is even more serious. A second objective is to explore some high demand scenarios that describe the role of methane leaks in the greenhouse tradeoff between gas and coal as energy sources. It is found that the uncertainty in the methane leaks from the natural gas system are large enough to consume the CO 2 advantages from using natural gas instead of coal for 20% of the market share. (author)

  5. Determining CO2 storage potential during miscible CO2 enhanced oil recovery: Noble gas and stable isotope tracers

    Science.gov (United States)

    Shelton, Jenna L.; McIntosh, Jennifer C.; Hunt, Andrew; Beebe, Thomas L; Parker, Andrew D; Warwick, Peter D.; Drake, Ronald; McCray, John E.

    2016-01-01

    Rising atmospheric carbon dioxide (CO2) concentrations are fueling anthropogenic climate change. Geologic sequestration of anthropogenic CO2 in depleted oil reservoirs is one option for reducing CO2 emissions to the atmosphere while enhancing oil recovery. In order to evaluate the feasibility of using enhanced oil recovery (EOR) sites in the United States for permanent CO2 storage, an active multi-stage miscible CO2flooding project in the Permian Basin (North Ward Estes Field, near Wickett, Texas) was investigated. In addition, two major natural CO2 reservoirs in the southeastern Paradox Basin (McElmo Dome and Doe Canyon) were also investigated as they provide CO2 for EOR operations in the Permian Basin. Produced gas and water were collected from three different CO2 flooding phases (with different start dates) within the North Ward Estes Field to evaluate possible CO2 storage mechanisms and amounts of total CO2retention. McElmo Dome and Doe Canyon were sampled for produced gas to determine the noble gas and stable isotope signature of the original injected EOR gas and to confirm the source of this naturally-occurring CO2. As expected, the natural CO2produced from McElmo Dome and Doe Canyon is a mix of mantle and crustal sources. When comparing CO2 injection and production rates for the CO2 floods in the North Ward Estes Field, it appears that CO2 retention in the reservoir decreased over the course of the three injections, retaining 39%, 49% and 61% of the injected CO2 for the 2008, 2010, and 2013 projects, respectively, characteristic of maturing CO2 miscible flood projects. Noble gas isotopic composition of the injected and produced gas for the flood projects suggest no active fractionation, while δ13CCO2 values suggest no active CO2dissolution into formation water, or mineralization. CO2 volumes capable of dissolving in residual formation fluids were also estimated along with the potential to store pure-phase supercritical CO2. Using a combination

  6. CO2 gas sensitivity of sputtered zinc oxide thin films

    Indian Academy of Sciences (India)

    TECS

    Abstract. For the first time, sputtered zinc oxide (ZnO) thin films have been used as a CO2 gas sensor. Zinc oxide thin films have been synthesized using reactive d.c. sputtering method for gas sensor applications, in the deposition temperature range from 130–153°C at a chamber pressure of 8⋅5 mbar for 18 h. Argon and ...

  7. Calibrating Laser Gas Measurements by Use of Natural CO2

    Science.gov (United States)

    Webster, Chris

    2003-01-01

    An improved method of calibration has been devised for instruments that utilize tunable lasers to measure the absorption spectra of atmospheric gases in order to determine the relative abundances of the gases. In this method, CO2 in the atmosphere is used as a natural calibration standard. Unlike in one prior calibration method, it is not necessary to perform calibration measurements in advance of use of the instrument and to risk deterioration of accuracy with time during use. Unlike in another prior calibration method, it is not necessary to include a calibration gas standard (and the attendant additional hardware) in the instrument and to interrupt the acquisition of atmospheric data to perform calibration measurements. In the operation of an instrument of this type, the beam from a tunable diode laser or a tunable quantum-cascade laser is directed along a path through the atmosphere, the laser is made to scan in wavelength over an infrared spectral region that contains one or two absorption spectral lines of a gas of interest, and the transmission (and, thereby, the absorption) of the beam is measured. The concentration of the gas of interest can then be calculated from the observed depth of the absorption line(s), given the temperature, pressure, and path length. CO2 is nearly ideal as a natural calibration gas for the following reasons: CO2 has numerous rotation/vibration infrared spectral lines, many of which are near absorption lines of other gases. The concentration of CO2 relative to the concentrations of the major constituents of the atmosphere is well known and varies slowly and by a small enough amount to be considered constant for calibration in the present context. Hence, absorption-spectral measurements of the concentrations of gases of interest can be normalized to the concentrations of CO2. Because at least one CO2 calibration line is present in every spectral scan of the laser during absorption measurements, the atmospheric CO2 serves

  8. CAPTURING EXHAUST CO2 GAS USING MOLTEN CARBONATE FUEL CELLS

    Directory of Open Access Journals (Sweden)

    Prateek Dhawan

    2016-03-01

    Full Text Available Carbon dioxide is considered as one of the major contenders when the question of greenhouse effect arises. So for any industry or power plant it is of utmost importance to follow certain increasingly stringent environment protection rules and laws. So it is significant to keep eye on any possible methods to reduce carbon dioxide emissions in an efficient way. This paper reviews the available literature so as to try to provide an insight of the possibility of using Molten Carbonate Fuel Cells (MCFCs as the carbon capturing and segregating devices and the various factors that affect the performance of MCFCs during the process of CO2 capture.

  9. Tree species influence soil-atmosphere fluxes of the greenhouse gases CO2, CH4 and N2O

    Science.gov (United States)

    Steffens, Christina; Vesterdal, Lars; Pfeiffer, Eva-Maria

    2016-04-01

    In the temperate zone, forests are the greatest terrestrial sink for atmospheric CO2, and tree species affect soil C stocks and soil CO2 emissions. When considering the total greenhouse gas (GHG) balance of the forest soil, the relevant GHGs CH4 and N2O should also be considered as they have a higher global warming potential than CO2. The presented data are first results from a field study in a common garden site in Denmark where tree species with ectomycorrhizal colonization (beech - Fagus sylvatica, oak - Quercus robur) and with arbuscular mycorrhizal colonization (maple - Acer pseudoplatanus, ash - Fraxinus excelsior) have been planted in monocultures in adjacent blocks of about 0.25 ha in the year 1973 on former arable land. The soil-atmosphere fluxes of all three gases were measured every second week since August 2015. The hypothesis is that the total GHG efflux from forest soil would differ between species, and that these differences could be related to the type of mycorrhizal association and leaf litter quality. Preliminary results (August to December 2015) indicate that tree species influence the fluxes (converted to CO2-eq) of the three GHGs. Total soil CO2 efflux was in the low end of the range reported for temperate broadleaved forests but similar to the measurements at the same site approximately ten years ago. It was highest under oak (9.6±2.4 g CO2 m-2 d-1) and lowest under maple (5.2±1.6 g CO2 m-2 d-1). In contrast, soil under oak was a small but significant sink for CH4(-0.005±0.003 g CO2-eq m-2 d-1), while there were almost no detectable CH4 fluxes in maple. Emissions of N2O were highest under beech (0.6±0.6 g CO2-eq m-2 d-1) and oak (0.2±0.09 g CO2-eq m-2 d-1) and lowest under ash (0.03±0.04 g CO2-eq m-2 d-1). In the total GHG balance, soil CH4 uptake was negligible (≤0.1% of total emissions). Emissions of N2O (converted to CO2-eq) contributed mycorrhiza and produce leaf litter with a lower lignin:N ratio.

  10. Castration of piglets under CO2-gas anaesthesia.

    Science.gov (United States)

    Gerritzen, M A; Kluivers-Poodt, M; Reimert, H G M; Hindle, V; Lambooij, E

    2008-11-01

    It has become common practice in pig fattening production systems to castrate young boar piglets without the use of anaesthesia. In this study, we examined whether or not CO2 gas is capable of inducing an acceptable anaesthetic state during which castration can be performed. The first step was to identify the most promising CO2/O2 mixture. Based on the results from this first experiment, a mixture of 70% CO2 + 30% O2 was chosen for further investigation as a potential anaesthetic during the castration of young piglets. Thereby, it was established whether the duration and depth of anaesthesia were acceptable for castration where the animal has to be insensible and unconscious. Physiological effects were assessed based on electroencephalogram (EEG) and electrocardiogram (ECG) measurements, blood gas values and behavioural responses. During the induction phase, the only typical behaviour the piglets exhibited when exposed to the 70/30 gas mixture was heavy breathing. All piglets (n = 25) lost consciousness after approximately 30 s according to the EEG. Heart rate decreased slowly during the induction phase, a serious drop occurred when piglets lost their posture. Immediately after this drop, the heart rate neared zero or showed a very irregular pattern. Shortly after loss of posture, most animals showed a few convulsions. None of the animals showed any reaction to castration in behaviour and/or on the EEG and ECG. On average, the piglets recovered within 59 s, i.e. EEG returned to its pre-induction pattern and piglets were able to regain a standing position. After 120 s, heart rate returned to pre-induction levels. In order to explore the usage range of CO2 concentration, 24 piglets were exposed to 60% CO2 + 20% O2 + 20% N2 for up to 30 s after loss of consciousness (as registered on EEG), and castrated after removal from the chamber. Sixteen of the 24 animals showed a reaction to the castration on the EEG. To establish the maximum time piglets survive in 70% CO2 + 30

  11. Accounting for Greenhouse Gas Emissions from Reservoirs

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes ...

  12. Design of CO2 absorption plant for recovery of CO2 from flue gases of gas turbine

    International Nuclear Information System (INIS)

    Mofarahi, Masoud; Khojasteh, Yaser; Khaledi, Hiwa; Farahnak, Arsalan

    2008-01-01

    The ongoing human-induced emission of carbon dioxide (CO 2 ) threatens to change the earth's climate. A major factor in global warming is CO 2 emission from thermal power plants, which burn fossil fuels. One possible way of decreasing CO 2 emissions is to apply CO 2 removal, which involves recovering of CO 2 from energy conversion processes. This study is focused on recovery of CO 2 from gas turbine exhaust of Sarkhun gas refinery power station. The purpose of this study is to recover the CO 2 with minimum energy requirement. Many of CO 2 recovery processes from flue gases have been studied. Among all CO 2 recovery processes which were studied, absorption process was selected as the optimum one, due to low CO 2 concentration in flue gas. The design parameters considered in this regard, are: selection of suitable solvent, solvent concentration, solvent circulation rate, reboiler and condenser duty and number of stages in absorber and stripper columns. In the design of this unit, amine solvent such as, diethanolamine (DEA), diglycolamine (DGA), methyldiethanolamine (MDEA), and monoethanolamine (MEA) were considered and the effect of main parameters on the absorption and stripping columns is presented. Some results with simultaneous changing of the design variables have been obtained. The results show that DGA is the best solvent with minimum energy requirement for recovery of CO 2 from flue gases at atmospheric pressure. (author)

  13. How well can we assess impacts of agricultural land management changes on the total greenhouse gas balance (CO2, CH4 and N2O) of tropical rice-cropping systems with biogeochemical models?

    Science.gov (United States)

    Kraus, David; Weller, Sebastian; Janz, Baldur; Klatt, Steffen; Santabárbara, Ignacio; Haas, Edwin; Werner, Christian; Wassmann, Reiner; Kiese, Ralf; Butterbach-Bahl, Klaus

    2016-04-01

    Paddy rice cultivation is increasingly challenged by physical and economic irrigation water scarcity. This already results in the trend of converting paddy rice to upland crop cultivation (e.g., maize, aerobic rice) in large parts of South East Asia. Such land management change from flooded lowland systems to well-aerated upland systems drastically affects soil C and N cycling and related emissions of greenhouse gases. Emissions of methane (CH4) are expected to decrease, while emissions of nitrous oxide (N2O) will most likely increase. In addition to such fast evolving 'pollution swapping' it is expected that on longer time scales significant amounts of soil organic carbon (SOC) stocks will be lost in form of carbon dioxide (CO2). Within the DFG-funded research unit ICON (Introducing non-flooded crops in rice-dominated landscapes: Impact on carbon, nitrogen and water cycles), we investigated environmental impacts of land management change from historical paddy rice cultivation to the upland crops maize and aerobic rice at experimental sites at the International Rice Research Institute (IRRI), the Philippines. To present, more than three years of continuous measurement data of CH4 and N2O emissions under different fertilization regimes have been collected. In addition, measurements of SOC contents and bulk densities in different soil horizons allow for an overall very good characterization of the environmental impacts of mentioned land management change. In this contribution we will show how well mentioned land management change effects in tropical agricultural systems can be represented and thus better understood by the help of process-based biogeochemical models. Seasonal emissions of CH4 and N2O are simulated with r2 values of 0.85 and 0.78 and average underestimations of 15 and 14 %, respectively. These underestimations predominantly originate from treatments in which no fertilizer is applied (CH4) as well as uncertainties of soil hydrology (N2O). Long

  14. The CO2-tax and its ability to reduce CO2 emissions related to oil and gas production in Norway

    International Nuclear Information System (INIS)

    Roemo, F.; Lund, M.W.

    1994-01-01

    The primary ambition of the paper is to illustrate some relevant effects of the CO 2 -tax, and draw the line from company adaptation via national ambitions and goals to global emission consequences. The CO 2 -tax is a success for oil and gas production only to the extent that the CO 2 emission per produced unit oil/gas is reduced as a consequence of the tax. If not, the CO 2 -tax is a pure fiscal tax and has no qualitative impact on the CO 2 emissions. The reduction potential is then isolated to the fact that some marginal fields will not be developed, and the accelerated close down of fields in production. The paper indicates that a significant replacement of older gas turbines at a certain level of the CO 2 -tax could be profitable for the companies. This is dependent on change in turbine energy utilization, and the investment cost. The CO 2 -tax is a political success for the nation if it is a significant contributor to achieve national emission goals. Furthermore, is the CO 2 -tax an environmental success only to the extent it contributes to reductions in the CO 2 emissions globally. The paper indicates that there are possibilities for major suboptimal adaptations in connection with national CO 2 -taxation of the oil and gas production. 13 refs., 6 figs

  15. UNEP greenhouse gas abatement costing studies

    International Nuclear Information System (INIS)

    Morthorst, P.E.; Grohnheit, P.E.

    1992-04-01

    The project initiated by the United Nations Environment Programme aims to clarify some economic issues involved in greenhouse gas limitation by carrying out comparative studies of various nations. The programme should contribute to the establishment of a consistent methodological framework for making cost assessments of greenhouse gas abatement and help to support countries in the process of establishing national and international agreements on actions to combat climate change. The publication gives a survey of Danish energy demand and supply, emissions and current energy policy issues and reviews existing studies of carbon dioxide reductions. This includes the overall national environmental policy and the plan of action for the transport sector. Conclusions are that there seems to be a long-term potential for significant reduction of CO 2 emission by 10-15% by 2010 with no additional costs, a 50% reduction will cost DKK 25-50 per kg reduced CO 2 . The most promising options include increased use of cogeneration of heat and electricity, and electricity conservation in households, services and in industry. Economic growth is forecast as ca. 2.7% and energy prices for oil products should increase by ca. 4.8%. A 40% reduction of CO 2 emission in the year 2005 would increase costs by 1-2%, and a reduction of two thirds of present emission should be possible at no additional cost compared to the reference cases. There is general agreement that a reduction of carbon dioxide emission of 15-30% by 2005-10 should involve no additional costs to society. (AB) (11 refs.)

  16. Comparison of greenhouse gas emissions from Mexican intensive ...

    African Journals Online (AJOL)

    The objectives of this study were to compare estimates of greenhouse gas emissions (GHG) as CH4 (enteric-manure), N2O (manure), and CO2 (fuel and energy use), the use of water and soil, the excretion of nutrients in manure, and feed efficiency from Mexican intensive dairy farms. Data from 26 dairy farms were analysed ...

  17. Drivers of the Growth in Global Greenhouse Gas Emissions

    NARCIS (Netherlands)

    Arto, Inaki; Dietzenbacher, Erik

    2014-01-01

    Greenhouse gas emissions increased by 8.9 Gigatons CO2 equivalent (Gt) in the period 1995-2008. A phenomenon that has received due attention is the upsurge of emission transfers via international trade. A question that has remained unanswered is whether trade changes have affected global emissions.

  18. Simple model to estimate the contribution of atmospheric CO2 to the Earth's greenhouse effect

    Science.gov (United States)

    Wilson, Derrek J.; Gea-Banacloche, Julio

    2012-04-01

    We show how the CO2 contribution to the Earth's greenhouse effect can be estimated from relatively simple physical considerations and readily available spectroscopic data. In particular, we present a calculation of the "climate sensitivity" (that is, the increase in temperature caused by a doubling of the concentration of CO2) in the absence of feedbacks. Our treatment highlights the important role played by the frequency dependence of the CO2 absorption spectrum. For pedagogical purposes, we provide two simple models to visualize different ways in which the atmosphere might return infrared radiation back to the Earth. The more physically realistic model, based on the Schwarzschild radiative transfer equations, uses as input an approximate form of the atmosphere's temperature profile, and thus includes implicitly the effect of heat transfer mechanisms other than radiation.

  19. Global CO2 Distributions over Land from the Greenhouse Gases Observing Satellite (GOSAT)

    Science.gov (United States)

    Hammerling, Dorit M.; Michalak, Anna M.; O'Dell, Christopher; Kawa, Randolph S.

    2012-01-01

    January 2009 saw the successful launch of the first space-based mission specifically designed for measuring greenhouse gases, the Japanese Greenhouse gases Observing SATellite (GOSAT). We present global land maps (Level 3 data) of column-averaged CO2 concentrations (X(sub CO2)) derived using observations from the GOSAT ACOS retrieval algorithm, for July through December 2009. The applied geostatistical mapping approach makes it possible to generate maps at high spatial and temporal resolutions that include uncertainty measures and that are derived directly from the Level 2 observations, without invoking an atmospheric transport model or estimates of CO2 uptake and emissions. As such, they are particularly well suited for comparison studies. Results show that the Level 3 maps for July to December 2009 on a lO x 1.250 grid, at six-day resolution capture much of the synoptic scale and regional variability of X(sub CO2), in addition to its overall seasonality. The uncertainty estimates, which reflect local data coverage, X(sub CO2) variability, and retrieval errors, indicate that the Southern latitudes are relatively well-constrained, while the Sahara Desert and the high Northern latitudes are weakly-constrained. A probabilistic comparison to the PCTM/GEOS-5/CASA-GFED model reveals that the most statistically significant discrepancies occur in South America in July and August, and central Asia in September to December. While still preliminary, these results illustrate the usefulness of a high spatiotemporal resolution, data-driven Level 3 data product for direct interpretation and comparison of satellite observations of highly dynamic parameters such as atmospheric CO2.

  20. Greenhouse gas emissions intensity of global croplands

    Science.gov (United States)

    Carlson, Kimberly M.; Gerber, James S.; Mueller, Nathaniel D.; Herrero, Mario; MacDonald, Graham K.; Brauman, Kate A.; Havlik, Petr; O'Connell, Christine S.; Johnson, Justin A.; Saatchi, Sassan; West, Paul C.

    2017-01-01

    Stabilizing greenhouse gas (GHG) emissions from croplands as agricultural demand grows is a critical component of climate change mitigation. Emissions intensity metrics--including carbon dioxide equivalent emissions per kilocalorie produced (`production intensity’)--can highlight regions, management practices, and crops as potential foci for mitigation. Yet the spatial and crop-wise distribution of emissions intensity has been uncertain. Here, we develop global crop-specific circa 2000 estimates of GHG emissions and GHG intensity in high spatial detail, reporting the effects of rice paddy management, peatland draining, and nitrogen (N) fertilizer on CH4, CO2 and N2O emissions. Global mean production intensity is 0.16 Mg CO2e M kcal-1, yet certain cropping practices contribute disproportionately to emissions. Peatland drainage (3.7 Mg CO2e M kcal-1)--concentrated in Europe and Indonesia--accounts for 32% of these cropland emissions despite peatlands producing just 1.1% of total crop kilocalories. Methane emissions from rice (0.58 Mg CO2e M kcal-1), a crucial food staple supplying 15% of total crop kilocalories, contribute 48% of cropland emissions, with outsized production intensity in Vietnam. In contrast, N2O emissions from N fertilizer application (0.033 Mg CO2e M kcal-1) generate only 20% of cropland emissions. We find that current total GHG emissions are largely unrelated to production intensity across crops and countries. Climate mitigation policies should therefore be directed to locations where crops have both high emissions and high intensities.

  1. CO2 gas sensors based on rare earth oxycarbonates

    International Nuclear Information System (INIS)

    Haensch, Alexander

    2016-01-01

    This title presents a new type of CO 2 gas sensor, that allows the measurement of CO 2 gas with very low effort. The measurement principle is based on two semiconducting materials. One the ''receptor'' and a ''transducer'' form a semiconductor junction. Electronic changes in the receptor change the electrical resistance in the transducer and therefor allow the easy electrical measurement. The reactivity and the reaction mechanism is thoroughly studied. In the first part the basics and resistance measurements are presented. A comparison between different mixtures is done. The main part studies the surface chemistry with operando DRIFT spectroscopy. The chemical reactivity of different target gases and background gases is studied thoroughly. The electronic properties of Oxycarbonates and the combination of oxycarbonate and tin oxide were studied using operando Kelvin probes measurements. The result is that CO 2 alters the electron affinity of the material. Once moisture is present, an additional band bending is visible. The band bending dominated in a humid atmosphere, the work function changes. The electronic connection of oxycarbonate and tin oxide, the work function change of Oxycarbonates can be transferred to the tin oxide. Using the collected data, a basic idea of the operation will be presented by a two-semiconductor materials gas sensor.

  2. The greenhouse gas balance of European grasslands.

    Science.gov (United States)

    Chang, Jinfeng; Ciais, Philippe; Viovy, Nicolas; Vuichard, Nicolas; Sultan, Benjamin; Soussana, Jean-François

    2015-10-01

    The greenhouse gas (GHG) balance of European grasslands (EU-28 plus Norway and Switzerland), including CO2 , CH4 and N2 O, is estimated using the new process-based biogeochemical model ORCHIDEE-GM over the period 1961-2010. The model includes the following: (1) a mechanistic representation of the spatial distribution of management practice; (2) management intensity, going from intensively to extensively managed; (3) gridded simulation of the carbon balance at ecosystem and farm scale; and (4) gridded simulation of N2 O and CH4 emissions by fertilized grassland soils and livestock. The external drivers of the model are changing animal numbers, nitrogen fertilization and deposition, land-use change, and variable CO2 and climate. The carbon balance of European grassland (NBP) is estimated to be a net sink of 15 ± 7 g C m(-2 ) year(-1) during 1961-2010, equivalent to a 50-year continental cumulative soil carbon sequestration of 1.0 ± 0.4 Pg C. At the farm scale, which includes both ecosystem CO2 fluxes and CO2 emissions from the digestion of harvested forage, the net C balance is roughly halved, down to a small sink, or nearly neutral flux of 8 g C m(-2 ) year(-1) . Adding CH4 and N2 O emissions to net ecosystem exchange to define the ecosystem-scale GHG balance, we found that grasslands remain a net GHG sink of 19 ± 10 g C-CO2 equiv. m(-2 ) year(-1) , because the CO2 sink offsets N2 O and grazing animal CH4 emissions. However, when considering the farm scale, the GHG balance (NGB) becomes a net GHG source of -50 g C-CO2 equiv. m(-2 ) year(-1) . ORCHIDEE-GM simulated an increase in European grassland NBP during the last five decades. This enhanced NBP reflects the combination of a positive trend of net primary production due to CO2 , climate and nitrogen fertilization and the diminishing requirement for grass forage due to the Europe-wide reduction in livestock numbers. © 2015 John Wiley & Sons Ltd.

  3. Integrated system for capturing CO2 as feedstock for algae production: 13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016, 14-18 November 2016, Lausanne, Switzerland

    NARCIS (Netherlands)

    Könst, P.M.; Hernandez Mireles, I.; Stel, R.W. van der; Os, P.M van; Goetheer, E.L.V.

    2017-01-01

    In view of its promise as sustainable process for CO2 capture and its potential in the production of feed, food and natural high value products such as omega-3 fatty acids and anti-oxidants such as astaxanthin, large scale algae cultivation is gaining commercial interest. Currently, most systems are

  4. Numerical Simulations for Enhanced Methane Recovery from Gas Hydrate Accumulations by Utilizing CO2 Sequestration

    Science.gov (United States)

    Sridhara, Prathyusha

    In 2013, the International Energy Outlook (EIA, 2013) projected that global energy demand will grow by 56% between 2010 and 2040. Despite strong growth in renewable energy supplies, much of this growth is expected to be met by fossil fuels. Concerns ranging from greenhouse gas emissions and energy security are spawning new interests for other sources of energy including renewable and unconventional fossil fuel such as shale gas and oil as well as gas hydrates. The production methods as well as long-term reservoir behavior of gas hydrate deposits have been under extensive investigation. Reservoir simulators can be used to predict the production potentials of hydrate formations and to determine which technique results in enhanced gas recovery. In this work, a new simulation tool, Mix3HydrateResSim (Mix3HRS), which accounts for complex thermodynamics of multi-component hydrate phase comprised of varying hydrate solid crystal structure, is used to perform the CO2-assisted production technique simulations from CH4 hydrate accumulations. The simulator is one among very few reservoir simulators which can simulate the process of CH4 substitution by CO2 (and N2 ) in the hydrate lattice. Natural gas hydrate deposits around the globe are categorized into three different classes based on the characteristics of the geological sediments present in contact with the hydrate bearing deposits. Amongst these, the Class 2 hydrate accumulations predominantly confirmed in the permafrost and along seashore, are characterized by a mobile aqueous phase underneath a hydrate bearing sediment. The exploitation of such gas hydrate deposits results in release of large amounts of water due to the presence of permeable water-saturated sediments encompassing the hydrate deposits, thus lowering the produced gas rates. In this study, a suite of numerical simulation scenarios with varied complexity are considered which aimed at understanding the underlying changes in physical, thermodynamic and

  5. The effect of natural gas supply on US renewable energy and CO2 emissions

    International Nuclear Information System (INIS)

    Shearer, Christine; Davis, Steven J; Bistline, John; Inman, Mason

    2014-01-01

    Increased use of natural gas has been promoted as a means of decarbonizing the US power sector, because of superior generator efficiency and lower CO 2 emissions per unit of electricity than coal. We model the effect of different gas supplies on the US power sector and greenhouse gas (GHG) emissions. Across a range of climate policies, we find that abundant natural gas decreases use of both coal and renewable energy technologies in the future. Without a climate policy, overall electricity use also increases as the gas supply increases. With reduced deployment of lower-carbon renewable energies and increased electricity consumption, the effect of higher gas supplies on GHG emissions is small: cumulative emissions 2013–55 in our high gas supply scenario are 2% less than in our low gas supply scenario, when there are no new climate policies and a methane leakage rate of 1.5% is assumed. Assuming leakage rates of 0 or 3% does not substantially alter this finding. In our results, only climate policies bring about a significant reduction in future CO 2 emissions within the US electricity sector. Our results suggest that without strong limits on GHG emissions or policies that explicitly encourage renewable electricity, abundant natural gas may actually slow the process of decarbonization, primarily by delaying deployment of renewable energy technologies. (letter)

  6. Gas geochemistry of natural analogues for the studies of geological CO2 sequestration

    International Nuclear Information System (INIS)

    Voltattorni, N.; Sciarra, A.; Caramanna, G.; Cinti, D.; Pizzino, L.; Quattrocchi, F.

    2009-01-01

    Geological sequestration of anthropogenic CO 2 appears to be a promising method for reducing the amount of greenhouse gases released to the atmosphere. Geochemical modelling of the storage capacity for CO 2 in saline aquifers, sandstones and/or carbonates should be based on natural analogues both in situ and in the laboratory. The main focus of this paper has been to study natural gas emissions representing extremely attractive surrogates for the study and prediction of the possible consequences of leakage from geological sequestration sites of anthropogenic CO 2 (i.e., the return to surface, potentially causing localised environmental problems). These include a comparison among three different Italian case histories: (i) the Solfatara crater (Phlegraean Fields caldera, southern Italy) is an ancient Roman spa. The area is characterised by intense and diffuse hydrothermal activity, testified by hot acidic mud pools, thermal springs and a large fumarolic field. Soil gas flux measurements show that the entire area discharges between 1200 and 1500 tons of CO 2 per day; (ii) the Panarea Island (Aeolian Islands, southern Italy) where a huge submarine volcanic-hydrothermal gas burst occurred in November, 2002. The submarine gas emissions chemically modified seawater causing a strong modification of the marine ecosystem. All of the collected gases are CO 2 -dominant (maximum value: 98.43 vol.%); (iii) the Tor Caldara area (Central Italy), located in a peripheral sector of the quiescent Alban Hills volcano, along the faults of the Ardea Basin transfer structure. The area is characterised by huge CO 2 degassing both from water and soil. Although the above mentioned areas do not represent a storage scenario, these sites do provide many opportunities to study near-surface processes and to test monitoring methodologies.

  7. Detection of greenhouse-gas-induced climatic change

    International Nuclear Information System (INIS)

    Wigley, T.M.L.; Jones, P.D.

    1992-01-01

    The aims of the US Department of Energy's Carbon Dioxide Research Program are to improve assessments of greenhouse-gas-induced climatic change and to define and reduce uncertainties through selected research. This project will address: The regional and seasonal details of the expected climatic changes; how rapidly will these changes occur; how and when will the climatic effects of CO 2 and other greenhouse gases be first detected; and the relationships between greenhouse-gas-induced climatic change and changes caused by other external and internal factors. The present project addresses all of these questions. Many of the diverse facets of greenhouse-gas-related climate research can be grouped under three interlinked subject areas: modeling, first detection and supporting data. This project will include the analysis of climate forcing factors, the development and refinement of transient response climate models, and the use of instrumental data in validating General Circulation Models (GCMs)

  8. Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook

    Energy Technology Data Exchange (ETDEWEB)

    Biraud, S. C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Reichl, K. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2016-03-01

    The Greenhouse Gas (GhG) Measurement system is a combination of two systems in series: (1) the Tower Gas Processing (TGP) System, an instrument rack which pulls, pressurizes, and dries air streams from an atmospheric sampling tower through a series of control and monitoring components, and (2) the Picarro model G2301 cavity ringdown spectrometer (CRDS), which measures CO2, CH4, and H2O vapor; the primary measurements of the GhG system.

  9. The marginal costs of greenhouse gas emissions

    International Nuclear Information System (INIS)

    Tol, R.S.J.

    1999-01-01

    Estimates of the marginal costs of greenhouse gas emissions are on important input to the decision how much society would want to spend on greenhouse gas emission reduction. Marginal cost estimates in the literature range between $5 and $25 per ton of carbon. Using similar assumptions, the FUND model finds marginal costs of $9--23/tC, depending on the discount rate. If the aggregation of impacts over countries accounts for inequalities in income distribution or for risk aversion, marginal costs would rise by about a factor of 3. Marginal costs per region are an order of magnitude smaller than global marginal costs. The ratios between the marginal costs of CO 2 and those of CH 4 and N 2 O are roughly equal to the global warming potentials of these gases. The uncertainty about the marginal costs is large and right-skewed. The expected value of the marginal costs lies about 35% above the best guess, the 95-percentile about 250%

  10. L'effet de serre par le CO2 et les gaz traces Greenhouse Effect from CO2 and Trace Gases

    Directory of Open Access Journals (Sweden)

    Bertrand A.

    2006-11-01

    , mainly from combustion and deforestation, and have been progressively accumulating in the Earth's atmosphere, could result in a greenhouse effect that could cause the heating up of the Earth by several degrees in the 21st century. The climatic consequences (melting of ice, etc. would be disastrous. Therefore, we examined the leading parameters involved in this phenomenon: nature of the greenhouse effect, carbon cycle, CO2 transfer on a worldwide scale, trace gases, climatic consequences of the greenhouse effect due to CO2 and trace gases. We reached the following conclusions:(a The CO2 and trace-gas concentration in the atmosphere increases exponentially in the absence of any regulations, and this occurs at the same time as human production of the same substances also at an exponential rate. (b No increase has as yet been detected in the Earth's average temperature due to the greenhouse effect. Moreover, since 1940 we have been going through a period of cooling. (c Human activity also produces antagonistic cooling effects (effect of dust in the atmosphere, etc. that are rather poorly understood. (d The study of ancient climates indicates a regular succession of cool and warm periods, which should reassure us about any sudden and irreversible change in the climate. (e However, it is absolutely necessary to improve our fundamental understanding of the main factors governing the Earth's climate (chemistry of the atmosphere, ocean/ atmosphere transfers, etc. and eventually to limit the production of some trace gases (Freon, in particular.

  11. Mineral storage of CO2/H2S gas mixture injection in basaltic rocks

    Science.gov (United States)

    Clark, D. E.; Gunnarsson, I.; Aradottir, E. S.; Oelkers, E. H.; Sigfússon, B.; Snæbjörnsdottír, S. Ó.; Matter, J. M.; Stute, M.; Júlíusson, B. M.; Gíslason, S. R.

    2017-12-01

    carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions. Science 352 (6291), 1312-1314. [3] Snæbjörnsdottír, S.O., et al. (2017). The chemistry and saturation states of subsurface fluids during the in-situ mineralisation of CO2 and H2S at the CarbFix site in SW-Iceland. International Journal of Greenhouse Gas Control 58, 87-102.

  12. High-accuracy continuous airborne measurements of greenhouse gases (CO2 and CH4) during BARCA

    Science.gov (United States)

    Chen, H.; Winderlich, J.; Gerbig, C.; Hoefer, A.; Rella, C. W.; Crosson, E. R.; van Pelt, A. D.; Steinbach, J.; Kolle, O.; Beck, V.; Daube, B. C.; Gottlieb, E. W.; Chow, V. Y.; Santoni, G. W.; Wofsy, S. C.

    2009-12-01

    High-accuracy continuous measurements of greenhouse gases (CO2 and CH4) during the BARCA (Balanço Atmosférico Regional de Carbono na Amazônia) phase B campaign in Brazil in May 2009 were accomplished using a newly available analyzer based on the cavity ring-down spectroscopy (CRDS) technique. This analyzer was flown without a drying system or any in-flight calibration gases. Water vapor corrections associated with dilution and pressure-broadening effects for CO2 and CH4 were derived from laboratory experiments employing measurements of water vapor by the CRDS analyzer. Before the campaign, the stability of the analyzer was assessed by laboratory tests under simulated flight conditions. During the campaign, a comparison of CO2 measurements between the CRDS analyzer and a nondispersive infrared (NDIR) analyzer on board the same aircraft showed a mean difference of 0.22±0.09 ppm for all flights over the Amazon rain forest. At the end of the campaign, CO2 concentrations of the synthetic calibration gases used by the NDIR analyzer were determined by the CRDS analyzer. After correcting for the isotope and the pressure-broadening effects that resulted from changes of the composition of synthetic vs. ambient air, and applying those concentrations as calibrated values of the calibration gases to reprocess the CO2 measurements made by the NDIR, the mean difference between the CRDS and the NDIR during BARCA was reduced to 0.05±0.09 ppm, with the mean standard deviation of 0.23±0.05 ppm. The results clearly show that the CRDS is sufficiently stable to be used in flight without drying the air or calibrating in flight and the water corrections are fully adequate for high-accuracy continuous airborne measurements of CO2 and CH4.

  13. Greenhouse Gas Emissions in Norway 1990-2001

    International Nuclear Information System (INIS)

    2003-01-01

    The report presents an inventory of greenhouse gas emissions and sinks in Norway from 1990 to 2001. Trends in total greenhouse gas emissions by UNFCCC's sources and gases are described for carbon dioxide (CO 2 ), methane (CH 4 ), nitrous oxide (N 2 O), tetrafluoromethane (CF 4 ), hexafluoroethane (C 2 F 6 ), sulphur hexafluoride (SF 6 ) and HFCs. The methodology used in the calculation of emissions from key sources in the Norwegian Emission Inventory is presented. Emissions are reported according to UNFCCC/IPCC common reporting format (CRF) (author)

  14. Evaluation of Mars CO2 Capture and Gas Separation Technologies

    Science.gov (United States)

    Muscatello, Anthony C.; Santiago-Maldonado, Edgardo; Gibson, Tracy; Devor, Robert; Captain, James

    2011-01-01

    Recent national policy statements have established that the ultimate destination of NASA's human exploration program is Mars. In Situ Resource Utilization (ISRU) is a key technology required to ,enable such missions and it is appropriate to review progress in this area and continue to advance the systems required to produce rocket propellant, oxygen, and other consumables on Mars using the carbon dioxide atmosphere and other potential resources. The Mars Atmospheric Capture and Gas separation project is selecting, developing, and demonstrating techniques to capture and purify Martian atmospheric gases for their utilization for the production of hydrocarbons, oxygen, and water in ISRU systems. Trace gases will be required to be separated from Martian atmospheric gases to provide pure CO2 to processing elements. In addition, other Martian gases, such as nitrogen and argon, occur in concentrations high enough to be useful as buffer gas and should be captured as well. To achieve these goals, highly efficient gas separation processes will be required. These gas separation techniques are also required across various areas within the ISRU project to support various consumable production processes. The development of innovative gas separation techniques will evaluate the current state-of-the-art for the gas separation required, with the objective to demonstrate and develop light-weight, low-power methods for gas separation. Gas separation requirements include, but are not limited to the selective separation of: (1) methane and water from unreacted carbon oxides (C02-CO) and hydrogen typical of a Sabatier-type process, (2) carbon oxides and water from unreacted hydrogen from a Reverse Water-Gas Shift process, (3)/carbon oxides from oxygen from a trash/waste processing reaction, and (4) helium from hydrogen or oxygen from a propellant scavenging process. Potential technologies for the separations include' freezers, selective membranes, selective solvents, polymeric sorbents

  15. Summer fluxes of atmospheric greenhouse gases N2O, CH4 and CO2 from mangrove soil in South China.

    Science.gov (United States)

    Chen, G C; Tam, N F Y; Ye, Y

    2010-06-01

    The atmospheric fluxes of N(2)O, CH(4) and CO(2) from the soil in four mangrove swamps in Shenzhen and Hong Kong, South China were investigated in the summer of 2008. The fluxes ranged from 0.14 to 23.83 micromol m(-2)h(-1), 11.9 to 5168.6 micromol m(-2)h(-1) and 0.69 to 20.56 mmol m(-2)h(-1) for N(2)O, CH(4) and CO(2), respectively. Futian mangrove swamp in Shenzhen had the highest greenhouse gas fluxes, followed by Mai Po mangrove in Hong Kong. Sha Kong Tsuen and Yung Shue O mangroves in Hong Kong had similar, low fluxes. The differences in both N(2)O and CH(4) fluxes among different tidal positions, the landward, seaward and bare mudflat, in each swamp were insignificant. The N(2)O and CO(2) fluxes were positively correlated with the soil organic carbon, total nitrogen, total phosphate, total iron and NH(4)(+)-N contents, as well as the soil porosity. However, only soil NH(4)(+)-N concentration had significant effects on CH(4) fluxes. Copyright (c) 2010 Elsevier B.V. All rights reserved.

  16. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    Energy Technology Data Exchange (ETDEWEB)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and

  17. OPIC Greenhouse Gas Emissions Analysis Details

    Data.gov (United States)

    Overseas Private Investment Corporation — Summary project inventory with independent analysis to quantify the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private...

  18. Greenhouse gas benefits of fighting obesity

    International Nuclear Information System (INIS)

    Michaelowa, Axel; Dransfeld, Bjoern

    2008-01-01

    Obesity has become a serious public health problem in both industrialized and rapidly industrializing countries. It increases greenhouse gas emissions through higher fuel needs for transportation of heavier people, lifecycle emissions from additional food production and methane emissions from higher amounts of organic waste. A reduction of average weight by 5 kg could reduce OECD transport CO 2 emissions by more than 10 million t. While the shift from beef to other forms of meat in industrialized and countries in transition has lead to lifecycle emissions savings of 20 million t CO 2 equivalent between 1990 and 2005, emissions due to obesity-promoting foodstuffs have increased by more than 400 million t in advanced developing countries. Emissions in OECD countries could be reduced by more than 4 million t through reduction of associated food waste. Due to the intimate behavioural nature of the obesity problem, policies to reduce obesity such as food taxation, subsidization of human-powered transport, incentives to reduce sedentary leisure and regulation of fat in foodstuffs have not yet been implemented to any extent. The emissions benefits of fiscal and regulatory measures to reduce obesity could accelerate the tipping point where a majority of voters feels that the problem warrants policy action. (author)

  19. Global CO2 distributions over land from the Greenhouse Gases Observing Satellite (GOSAT)

    Science.gov (United States)

    Hammerling, Dorit M.; Michalak, Anna M.; O'Dell, Christopher; Kawa, S. Randolph

    2012-04-01

    January 2009 saw the successful launch of the first space-based mission specifically designed for measuring greenhouse gases, the Japanese Greenhouse gases Observing SATellite (GOSAT). We present global land maps (Level 3 data) of column-averaged CO2 concentrations (XCO2) derived using observations from the GOSAT ACOS retrieval algorithm, for July through December 2009. The applied geostatistical mapping approach makes it possible to generate maps at high spatial and temporal resolutions that include uncertainty measures and that are derived directly from the Level 2 observations, without invoking an atmospheric transport model or estimates of CO2 uptake and emissions. As such, they are particularly well suited for comparison studies. Results show that the Level 3 maps for July to December 2009 on a 1° × 1.25° grid, at six-day resolution capture much of the synoptic scale and regional variability of XCO2, in addition to its overall seasonality. The uncertainty estimates, which reflect local data coverage, XCO2 variability, and retrieval errors, indicate that the Southern latitudes are relatively well-constrained, while the Sahara Desert and the high Northern latitudes are weakly-constrained. A probabilistic comparison to the PCTM/GEOS-5/CASA-GFED model reveals that the most statistically significant discrepancies occur in South America in July and August, and central Asia in September to December. While still preliminary, these results illustrate the usefulness of a high spatiotemporal resolution, data-driven Level 3 data product for direct interpretation and comparison of satellite observations of highly dynamic parameters such as atmospheric CO2.

  20. Transition to a Moist Greenhouse with CO2 and solar forcing

    Science.gov (United States)

    Popp, Max; Schmidt, Hauke; Marotzke, Jochem

    2016-01-01

    Water-rich planets such as Earth are expected to become eventually uninhabitable, because liquid water turns unstable at the surface as temperatures increase with solar luminosity. Whether a large increase of atmospheric concentrations of greenhouse gases such as CO2 could also destroy the habitability of water-rich planets has remained unclear. Here we show with three-dimensional aqua-planet simulations that CO2-induced forcing as readily destabilizes the climate as does solar forcing. The climate instability is caused by a positive cloud feedback and leads to a new steady state with global-mean sea-surface temperatures above 330 K. The upper atmosphere is considerably moister in this warm state than in the reference climate, implying that the planet would be subject to substantial loss of water to space. For some elevated CO2 or solar forcings, we find both cold and warm equilibrium states, implying that the climate transition cannot be reversed by removing the additional forcing. PMID:26859279

  1. National greenhouse gas accounts: Current anthropogenic sources and sinks

    International Nuclear Information System (INIS)

    Subak, S.; Raskin, P.; Hippel, David von

    1992-01-01

    This study provides spatially disaggregated estimates of greenhouse gas emissions from the major anthropogenic sources for 145 countries. The data compilation is comprehensive in approach, including emissions from CO, CH 4 , N 2 O and ten halocarbons, in addition to CO 2 . The sources include emissions from fossil fuel production and use, cement production, halocarbons, landfills, land use changes, biomass burning, rice and livestock production and fertilizer consumption. The approach used to derive these estimates corresponds closely with the simple methodologies proposed by the Greenhouse Gas Emissions Task Force of the Intergovernmental Panel on Climate Change. The inventory includes a new estimate of greenhouse gas emissions from fossil fuel combustion based principally on data from the International Energy Agency. The research methodologies for estimating emissions from all sources is briefly described and compared with other recent studies in the literature. (112 refs.)

  2. Environmental Life Cycle Analysis of Water and CO2-Based Fracturing Fluids Used in Unconventional Gas Production.

    Science.gov (United States)

    Wilkins, Rodney; Menefee, Anne H; Clarens, Andres F

    2016-12-06

    Many of the environmental impacts associated with hydraulic fracturing of unconventional gas wells are tied to the large volumes of water that such operations require. Efforts to develop nonaqueous alternatives have focused on carbon dioxide as a tunable working fluid even though the full environmental and production impacts of a switch away from water have yet to be quantified. Here we report on a life cycle analysis of using either water or CO 2 for gas production in the Marcellus shale. The results show that CO 2 -based fluids, as currently conceived, could reduce greenhouse gas emissions by 400% (with sequestration credit) and water consumption by 80% when compared to conventional water-based fluids. These benefits are offset by a 44% increase in net energy use when compared to slickwater fracturing as well as logistical barriers resulting from the need to move and store large volumes of CO 2 . Scenario analyses explore the outlook for CO 2 , which under best-case conditions could eventually reduce life cycle energy, water, and greenhouse gas (GHG) burdens associated with fracturing. To achieve these benefits, it will be necessary to reduce CO 2 sourcing and transport burdens and to realize opportunities for improved energy recovery, averted water quality impacts, and carbon storage.

  3. Geomechanical issues of anthropogenic CO2 sequestration in exploited gas fields

    International Nuclear Information System (INIS)

    Ferronato, Massimiliano; Gambolati, Giuseppe; Janna, Carlo; Teatini, Pietro

    2010-01-01

    Anthropogenic CO 2 sequestration in deep geological formations may represent a viable option to fulfil the requirements of the 1997 Kyoto protocol on the reduction of greenhouse gas emissions. Scenarios of CO 2 sequestration through three injection wells in an exploited gas field located in the Po sedimentary basin (Italy) are simulated with the final target to understand the geomechanical consequences of the injection of carbon dioxide. Investigated scenarios include, as a hypothetical case, the long-term injection of CO 2 until the initial reservoir pressure is exceeded by as much as 40% over a period of about 100 years. The process is analyzed from the geomechanical point of view using a finite element-interface element (FE-IE) model with the following main issues addressed: (1) prediction of the possible land vertical uplift and corresponding impact on the ground infrastructures; (2) evaluation of the stress state induced in the reservoir formation with the possible generation of fractures and (3) a risk analysis for the activation of existing faults. The geomechanical constitutive law of the Northern Adriatic basin relying on the radioactive marker interpretation is implemented into the FE model, while an elasto-plastic relationship based on the Mohr-Coulomb criterion is used for the IE reproducing the fault behaviour. The in situ stress prior to the gas field exploitation is compressive with the principal horizontal stress in the direction perpendicular to the major faults equal to the vertical stress. The results show that the ground surface rebound due to the overpressure generated by the CO 2 sequestration partially mitigates the land subsidence experienced by the area because of the previous gas field depletion with differential displacements that are confined within the safety bounds suggested in the literature for the surface infrastructures. Activation of a few faults lying close to the northern reservoir boundary points to a slip of a couple of

  4. Panorama 2009 - greenhouse gas emissions and the transport sector

    International Nuclear Information System (INIS)

    2008-01-01

    The fact that the transport sector is growing quickly brings advantages, such as quick access to any geographical location on earth, but also disadvantages: noise, congestion and polluting emissions such as carbon dioxide (CO 2 ), the greenhouse gas (GHG) primarily responsible for global warming. In the effort to bring GHG emissions under control, improving results in the transport sector is a prime long-term objective. What proportion of CO 2 emissions generated at global and national level are due to the road, air, maritime and rail transport sectors, respectively? What mechanisms can be used to reduce GHG emissions in the transport sector at large?

  5. Influence of meteorology and interrelationship with greenhouse gases (CO2 and CH4) at a sub-urban site of India

    Science.gov (United States)

    Sreenivas, G.; Mahesh, P.; Subin, J.; Kanchana, A. L.; Rao, P. V. N.; Dadhwal, V. K.

    2015-12-01

    Atmospheric greenhouse gases (GHGs) such as carbon dioxide (CO2) and methane (CH4) are important climate forcing agents due to their significant impact on the climate system. The present study brings out first continuous measurements of atmospheric GHG's using high precision Los Gatos Research's-greenhouse gas analyser (LGR-GGA) over Shadnagar, a suburban site of Central India during the period 2014. The annual mean of CO2 and CH4 over the study region is found to be 394 ± 2.92 and 1.92 ± 0.07 ppm (mean, μ ± 1 SD, σ) respectively. CO2 and CH4 showed a significant seasonal variation during the study period with maximum (minimum) CO2 observed during Pre-monsoon (Monsoon), while CH4 recorded maximum during post-monsoon and minimum in monsoon. A consistent diurnal mixing ratio of these gases is observed with high (low) during night (afternoon) hours throughout the study period. Influences of prevailing meteorology (air temperature, wind speed, wind direction and relative humidity) on GHG's have also been investigated. CO2 and CH4 showed a strong positive correlation during winter, pre-monsoon, monsoon and post-monsoon with R equal to 0.80, 0.80, 0.61 and 0.72 respectively. It implies the seasonal variations in source-sink mechanisms of CO2 and CH4. Present study also confirms implicitly the presence OH radicals as a major sink of CH4 over the study region.

  6. Highly Stable Porous Covalent Triazine-Piperazine Linked Nanoflower as a Feasible Adsorbent for Flue Gas CO2 Capture

    KAUST Repository

    Das, Swapan Kumar

    2016-02-11

    Here, we report a porous covalent triazine-piperazine linked polymer (CTPP) featuring 3D nanoflower morphology and enhanced capture/removal of CO2, CH4 from air (N2), essential to control greenhouse gas emission and natural gas upgrading. 13C solid-state NMR and FTIR analyses and CHN and X-ray photoelectron spectroscopy (XPS) elemental analyses confirmed the integration of triazine and piperazine components in the network. Scanning electron microscopic (SEM) and transmission electron microscopic (TEM) analyses revealed a relatively uniform particle size of approximately 400 to 500 nm with 3D nanoflower microstructure, which was formed by the self-assembly of interwoven and slight bent nanoflake components. The material exhibited outstanding chemical robustness under acidic and basic medium and high thermal stability up to 773 K. The CTPP possess high surface area (779 m2/g) and single-component gas adsorption study exhibited enhanced CO2 and CH4 uptake of 3.48 mmol/g, 1.09 mmol/g, respectively at 273 K, 1 bar; coupled with high sorption selectivities for CO2/N2 and CH4/N2 of 128 and 17, respectively. The enriched Lewis basicity of the CTPP favors the interaction with CO2, which results in an enhanced CO2 adsorption capacity and high CO2/N2 selectivity. The binary mixture breakthrough study for the flue gas composition at 298 K showed a high CO2/N2 selectivity of 82. CO2 heats of adsorption for the CTPP (34 kJ mol−1) were realized at the borderline between strong physisorption and weak chemisorption (QstCO2; 25−50 kJ mol−1) and low Qst value for N2 (22.09 kJ mol−1), providing the ultimate validation for the high selectivity of CO2 over N2.

  7. Porous materials as high performance adsorbents for CO2 capture, gas separation and purification

    Science.gov (United States)

    Wang, Jun

    Global warming resulted from greenhouse gases emission has received a widespread attention. Among the greenhouse gases, CO2 contributes more than 60% to global warming due to its huge emission amount. The flue gas contains about 15% CO2 with N2 as the balance. If CO2 can be separated from flue gas, the benefit is not only reducing the global warming effect, but also producing pure CO2 as a very useful industry raw material. Substantial progress is urgent to be achieved in an industrial process. Moreover, energy crisis is one of the biggest challenges for all countries due to the short life of fossil fuels, such as, petroleum will run out in 50 years and coal will run out in 150 years according to today's speed. Moreover, the severe pollution to the environment caused by burning fossil fuels requires us to explore sustainable, environment-friendly, and facile energy sources. Among several alternative energy sources, natural gas is one of the most promising alternative energy sources due to its huge productivity, abundant feed stock, and ease of generation. In order to realize a substantial adsorption process in industry, synthesis of new adsorbents or modification of existing adsorbent with improved properties has become the most critical issue. This dissertation reports systemic characterization and development of five serials of novel adsorbents with advanced adsorption properties. In chapter 2, nitrogen-doped Hypercross-linking Polymers (HCPs) have been synthesized successfully with non-carcinogenic chloromethyl methyl ether (CME) as the cross-linking agent within a single step. Texture properties, surface morphology, CO2/N2 selectivity, and adsorption heat have been presented and demonstrated properly. A comprehensive discussion on factors that affect the CO2 adsorption and CO2/N 2 separation has also been presented. It was found that high micropore proportion and N-content could effectively enhance CO2 uptake and CO2/N2 separation selectivity. In chapter 3, a

  8. Competitiveness of terrestrial greenhouse gas offsets. Are they a bridge to the future?

    International Nuclear Information System (INIS)

    McCarl, B.A.; Sands, R.D.

    2007-01-01

    Activities to reduce net greenhouse gas emissions by biological soil or forest carbon sequestration predominantly utilize currently known, readily implementable technologies. Many other greenhouse gas emission reduction options require future technological development or must wait for turnover of capital stock. Carbon sequestration options in soils and forests, while ready to go now, generally have a finite life, allowing use until other strategies are developed. This paper reports on an investigation of the competitiveness of biological carbon sequestration from a dynamic and multiple strategy viewpoint. Key factors affecting the competitiveness of terrestrial mitigation options are land availability and cost effectiveness relative to other options including CO2 capture and storage, energy efficiency improvements, fuel switching, and non-CO2 greenhouse gas emission reductions. The analysis results show that, at lower CO2 prices and in the near term, soil carbon and other agricultural/forestry options can be important bridges to the future, initially providing a substantial portion of attainable reductions in net greenhouse gas emissions, but with a limited role in later years. At higher CO2 prices, afforestation and biofuels are more dominant among terrestrial options to offset greenhouse gas emissions. But in the longer run, allowing for capital stock turnover, options to reduce greenhouse gas emissions from the energy system and biofuels provide an increasing share of potential reductions in total US greenhouse gas emissions

  9. Polymer blend membranes for CO2 separation from natural gas

    Science.gov (United States)

    Mukhtar, H.; Mannan, H. A.; Minh, D.; Nasir, R.; Moshshim, D. F.; Murugesan, T.

    2016-06-01

    Polymeric membranes are dominantly used in industrial gas separation membrane processes. Enhancement in membranes permeability and/or selectivity is a key challenge faced by membrane researchers. The current work represents the effect of poyetherimide blending on separation performance of polysulfone membranes. Polysulfone/poyetherimide (PSF/PEI) blend flat sheet dense membranes were synthesized and tested for permeation analysis of CO2 and CH4 gases at 6, 8 and 10 bar pressure and 25oC temperature. Morphology and thermal properties of membranes were characterized by field emission scanning electron microscope (FESEM) and thermo gravimetric analysis (TGA) respectively. Blend membranes were dense and homogeneous as deduced from FESEM analysis. Thermal stability of synthesized blend membranes was maintained by blending with PEI as characterized by TGA results. Decrease in permeability of both gases was observed by the addition of PEI due to rigidity of PEI chains. Additionally, selectivity of synthesized blend membranes was enhanced by blending PEI and blend membranes show improved selectivity over pure PSF membrane. This new material has the capability to be used as gas separation membrane material.

  10. Effect of the greenhouse gases (CO2, H2O, SO2) on Martian paleoclimate

    Science.gov (United States)

    Postawko, S. E.; Kuhn, W. R.

    1986-01-01

    There is general agreement that certain surface features on Mars are indicative of the presence of liquid water at various times in the geologic past. In particular, the valley networks are difficult to explain by a mechanism other than the flow of liquid water. It has been suggested in several studies that a thick CO2 atmosphere on Mars early in its history could have provided a greenhouse warming that would have allowed the flow of water either on the surface or just below the surface. However, this effect was examined with a detailed radiation model, and it was found that if reduced solar luminosity early in the history of the solar system is taken into account, even three bars of CO2 will not provide sufficient greeenhouse warming. The addition of water vapor and sulflur dioxide (both plausible gases that may have been emitted by Martian volcanoes) to the atmosphere also fail to warm the surface above 273 K for reduced solar luminosity conditions. The increase in temperature may be large enough, however, for the formation of these features by brines.

  11. Greenhouse gas abatement strategies for animal husbandry

    NARCIS (Netherlands)

    Monteny, G.J.; Bannink, A.; Chadwick, D.

    2006-01-01

    Agriculture contributes significantly to the anthropogenic emissions of non-CO2 greenhouse gases methane and nitrous oxide. In this paper, a review is presented of the agriculture related sources of methane and nitrous oxide, and of the main strategies for mitigation. The rumen is the most important

  12. Greenhouse gas emissions from Savanna ( Miombo ) woodlands ...

    African Journals Online (AJOL)

    Natural vegetation represents an important sink for greenhouse gases (GHGs); however, there is relatively little information available on emissions from southern African savannas. The effects of clearing savanna woodlands for crop production on soil fluxes of N2O, CO2 and CH4 were studied on clay (Chromic luvisol) and ...

  13. Patterns in CH4 and CO2 concentrations across boreal rivers: Major drivers and implications for fluvial greenhouse emissions under climate change scenarios.

    Science.gov (United States)

    Campeau, Audrey; Del Giorgio, Paul A

    2014-04-01

    It is now widely accepted that boreal rivers and streams are regionally significant sources of carbon dioxide (CO2), yet their role as methane (CH4) emitters, as well as the sensitivity of these greenhouse gas (GHG) emissions to climate change, are still largely undefined. In this study, we explore the large-scale patterns of fluvial CO2 and CH4 partial pressure (pCO2 , pCH4) and gas exchange (k) relative to a set of key, climate-sensitive river variables across 46 streams and rivers in two distinct boreal landscapes of Northern Québec. We use the resulting models to determine the direction and magnitude of C-gas emissions from these boreal fluvial networks under scenarios of climate change. River pCO2 and pCH4 were positively correlated, although the latter was two orders of magnitude more variable. We provide evidence that in-stream metabolism strongly influences the dynamics of surface water pCO2 and pCH4 , but whereas pCO2 is not influenced by temperature in the surveyed streams and rivers, pCH4 appears to be strongly temperature-dependent. The major predictors of ambient gas concentrations and exchange were water temperature, velocity, and DOC, and the resulting models indicate that total GHG emissions (C-CO2 equivalent) from the entire network may increase between by 13 to 68% under plausible scenarios of climate change over the next 50 years. These predicted increases in fluvial GHG emissions are mostly driven by a steep increase in the contribution of CH4 (from 36 to over 50% of total CO2 -equivalents). The current role of boreal fluvial networks as major landscape sources of C is thus likely to expand, mainly driven by large increases in fluvial CH4 emissions. © 2013 John Wiley & Sons Ltd.

  14. Greenhouse gas emissions from cultivation of energy crops may affect the sustainability of biofuels

    DEFF Research Database (Denmark)

    Carter, Mette Sustmann; Hauggaard-Nielsen, Henrik; Heiske, Stefan

    2011-01-01

    production. The net reduction in greenhouse gas emissions is calculated as the avoided fossil fuel‐derived CO2, where the N2O emission has been subtracted. This value does not include farm machinery CO2 emissions and fuel consumption during biofuel production. Thus, the actual net greenhouse gas reduction......Agro‐biofuels are expected to reduce the emissions of greenhouse gases because CO2 emitted during the combustion of the biofuels has recently been taken from the atmosphere by the energy crop. Thus, when replacing fossil fuels with biofuels we reduce the emission of fossil fuel‐derived CO2...... or incorporation of crop residues. In this study we relate measured field emissions of N2O to the reduction in fossil fuel‐derived CO2, which is obtained when energy crops are used for biofuel production. The analysis includes five organically managed crops (viz. maize, rye, rye‐vetch, vetch and grass...

  15. Continuous CO2 gas monitoring to clarify natural pattern and artificial leakage signals

    Science.gov (United States)

    Joun, W.; Ha, S. W.; Joo, Y. J.; Lee, S. S.; Lee, K. K.

    2017-12-01

    Continuous CO2 gas monitoring at shallow aquifer is significant for early detection and immediate handling of an aquifer impacted by leaking CO2 gas from the sequestration reservoir. However, it is difficult to decide the origin of CO2 gas because detected CO2 includes not only leaked CO2 but also naturally emitted CO2. We performed CO2 injection and monitoring tests in a shallow aquifer. Before the injection of CO2 infused water, we have conducted continuous monitoring of multi-level soil CO2 gas concentration and physical parameters such as temperature, humidity, pressure, wind speed and direction, and precipitation. The monitoring data represented that CO2 gas concentrations in unsaturated soil zone borehole showed differences at depths and daily variation (360 to 6980 ppm volume). Based on the observed data at 5 m and 8 m depths, vertical flux of gas was calculated as 0.471 L/min (LPM) for inflow from 5 m to 8 m and 9.42E-2 LPM for outflow from 8 m to 5 m. The numerical and analytical models were used to calculate the vertical flux of gas and to compare with observations. The results showed that pressure-based modeling could not explain the rapid change of CO2 gas concentration in borehole. Acknowledgement Financial support was provided by the "R&D Project on Environmental Management of Geologic CO2 Storage" from the KEITI (Project Number: 2014001810003)

  16. Greenhouse gas and carbon profile of the U.S. forest products industry value chain

    Science.gov (United States)

    Linda S. Heath; Van Maltby; Reid Miner; Kenneth E. Skog; James E. Smith; Jay Unwin; Brad Upton

    2010-01-01

    A greenhouse gas and carbon accounting profile was developed for the U.S. forest products industry value chain for 1990 and 2004-2005 by examining net atmospheric fluxes of CO2 and other greenhouse gases (GHGs) using a variety of methods and data sources. Major GHG emission sources include direct and indirect (from purchased electricity...

  17. Facile synthesis of triazine-triphenylamine-based microporous covalent polymer adsorbent for flue gas CO2 capture

    KAUST Repository

    Das, Swapan Kumar

    2017-07-17

    The sustainable capture and sequestration of CO2 from flue gas emission is an important and unavoidable challenge to control greenhouse gas release and climate change. In this report, we describe a triazine-triphenylamine-based microporous covalent organic polymer under mild synthetic conditions. 13C and 15N solid-state NMR and FTIR analyses confirm the linkage of the triazine and triphenylamine components in the porous polymer skeleton. The material is composed of spherical particles 1.0 to 2.0 μm in size and possesses a high surface area (1104 m2/g). The material exhibits superb chemical robustness under acidic and basic conditions and high thermal stability. Single-component gas adsorption exhibits an enhanced CO2 uptake of 3.12 mmol/g coupled with high sorption selectivity for CO2/N2 of 64 at 273 K and 1 bar, whereas the binary gas mixture breakthrough study using a model flue gas composition at 298 K shows a high CO2/N2 selectivity of 58. The enhanced performance is attributed to the high Lewis basicity of the framework, as it favors the interaction with CO2.

  18. Greenhouse gas mitigation options for Washington State

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, N.

    1996-04-01

    President Clinton, in 1993, established a goal for the United States to return emissions of greenhouse gases to 1990 levels by the year 2000. One effort established to help meet this goal was a three part Environmental Protection Agency state grant program. Washington State completed part one of this program with the release of the 1990 greenhouse gas emissions inventory and 2010 projected inventory. This document completes part two by detailing alternative greenhouse gas mitigation options. In part three of the program EPA, working in partnership with the States, may help fund innovative greenhouse gas reduction strategies. The greenhouse gas control options analyzed in this report have a wide range of greenhouse gas reductions, costs, and implementation requirements. In order to select and implement a prudent mix of control strategies, policy makers need to have some notion of the potential change in climate, the consequences of that change and the uncertainties contained therein. By understanding the risks of climate change, policy makers can better balance the use of scarce public resources for concerns that are immediate and present against those that affect future generations. Therefore, prior to analyzing alternative greenhouse gas control measures, this report briefly describes the phenomenon and uncertainties of global climate change, and then projects the likely consequences for Washington state.

  19. Urban form and greenhouse gas emissions in Finland

    International Nuclear Information System (INIS)

    Harmaajaervi, Irmeli

    2003-01-01

    Finland's regional form is becoming more concentrated, while urban sprawl is causing growth centres to become fragmented. The effects caused by these changes on greenhouse gas emissions were studied up to the year 2010, when, in accordance with the Kyoto protocol, Finland's greenhouse gas emissions should be reduced to the 1990 level. The urban form affects especially transportation inside regions, the potential to utilise district heating and the need for infrastructure. By preventing urban sprawl and by encouraging teleworking and some lifestyle changes, it would be possible to reduce annual transportation emissions by the year 2010 by 1.1 million tonnes CO 2 eq., i.e. 27%, the emissions from residential and service buildings by 1.1 million tonnes CO 2 eq., i.e. 5%, and the emissions from municipal infrastructure by 0.1 million tonnes CO 2 eq., i.e. 6%. Altogether, it is possible to reduce the greenhouse gas emissions by 2.3 million tonnes, which amounts to 15% of Finland's target for emissions reductions in 2010. If the target-oriented scenario is realised, the subsequent decrease of emissions would accelerate. To stop urban sprawl, measures are required in planning, land use and housing policy as well as in transportation and tax policies. Additionally, more needs to be done in regard to co-operation, interaction and information dissemination. This paper introduces a report which estimates, for the first time, the effects caused by changes in the regional and urban forms on the levels of greenhouse gas emissions in Finland

  20. Restoration of peatlands and greenhouse gas balances

    NARCIS (Netherlands)

    Höper, H.; Augustin, J.; Cagampan, J.P.; Drösler, M.; Lundin, L.; Moors, E.J.; Vasander, H.; Waddington, J.M.; Wilson, D.

    2008-01-01

    In this chapter the impact of peatland restoration on greenhouse gas fluxes is discussed based on a literature review. Casestudies are presented covering different peatland types, different regions and different starting conditions.

  1. Agriculture and greenhouse gas effect: status and perspectives

    International Nuclear Information System (INIS)

    2010-01-01

    In a first part, this report analyses the interactions between climate and agriculture: understanding of climate changes and their global impacts, understanding of carbon and nitrogen life cycles and their relationship with anthropic greenhouse gas emissions, emissions by agriculture and impacts of climate change on agriculture, N 2 O, CH 4 and CO 2 emissions by agriculture. The authors address how to reduce emissions and increase carbon storage by crop management and N 2 O emission reduction, by breeding management and CH 4 and CO 2 emission reduction, and by energy CO 2 emission reduction. They discuss emission reduction policies in agriculture within the international political, European and French frameworks. They also identify possible economic tools

  2. A single gas chromatograph for accurate atmospheric mixing ratio measurements of CO2, CH4, N2O, SF6 and CO

    NARCIS (Netherlands)

    van der Laan, S.; Neubert, R. E. M.; Meijer, H. A. J.; Simpson, W.R.

    2009-01-01

    We present an adapted gas chromatograph capable of measuring simultaneously and semi-continuously the atmospheric mixing ratios of the greenhouse gases CO2, CH4, N2O and SF6 and the trace gas CO with high precision and long-term stability. The novelty of our design is that all species are measured

  3. Bibliography of greenhouse-gas reduction strategies

    Energy Technology Data Exchange (ETDEWEB)

    Tompkins, M.M.; Mintz, M.M.

    1995-03-01

    A bibliography of greenhouse-gas reduction strategies has been compiled to assist the Climate change Action Plan Task Force in their consideration of strategies to reduce greenhouse-gas emissions from personal motor vehicles. The document contains a summary of the literature, including it major directions and implications; and annotated listing of 32 recent pertinent documents; and a listing of a larger group of related reports.

  4. An energetic analysis of CO2 capture on a gas turbine combining flue gas recirculation and membrane separation

    International Nuclear Information System (INIS)

    Belaissaoui, Bouchra; Cabot, Gilles; Cabot, Marie-Sophie; Willson, David; Favre, Eric

    2012-01-01

    Post-combustion Carbon Capture and Storage (CCS) is currently intensively investigated as a key issue for the mitigation of greenhouse gases emissions. A very large number of studies is dedicated to coal power plants. In this paper, the possibility to achieve carbon capture on a gas turbine, based on a combination of flue gas recycle and membrane separation is reported. Membrane processes are effectively known to offer attractive performances in terms of energy efficiency, as soon as concentrated and/or pressure mixtures have to be treated. Two different flow schemes have been simulated and compared: flue gas recycle with air combustion and flue gas recycle with an oxygen enriched feed mixture. The energy requirement of the different processes, expressed in GJ (thermal basis) per ton of recovered CO 2 , and the size of the membrane capture process (expressed in m 2 of membrane area) have been systematically estimated for different membrane separation performances. It is shown that an overall energy requirement down to 2.6 GJ per ton can possibly be achieved when optimal operating conditions, based on oxygen enriched air (OEA) combustion together with a highly selective membrane (CO 2 /N 2 selectivity of 200) are combined. Additional possibilities in order to minimise the energy penalty of the process are discussed. -- Highlights: ► A carbon capture process for gas turbine has been investigated for the first time, with membrane separation unit. ► Air combustion systematically induces CO 2 capture specific energy requirement far above alternative capture processes. ► Remarkably, a very low energy requirement can be achieved (down to 2.6 GJ/ton) with Oxygen Enriched Air combustion. ► Target membrane selectivities and optimal oxygen content for combustion have been identified.

  5. The relative greenhouse gas impacts of realistic dietary choices

    International Nuclear Information System (INIS)

    Berners-Lee, M.; Hoolohan, C.; Cammack, H.; Hewitt, C.N.

    2012-01-01

    The greenhouse gas (GHG) emissions embodied in 61 different categories of food are used, with information on the diet of different groups of the population (omnivorous, vegetarian and vegan), to calculate the embodied GHG emissions in different dietary scenarios. We calculate that the embodied GHG content of the current UK food supply is 7.4 kg CO 2 e person −1 day −1 , or 2.7 t CO 2 e person −1 y −1 . This gives total food-related GHG emissions of 167 Mt CO 2 e (1 Mt=10 6 metric tonnes; CO 2 e being the mass of CO 2 that would have the same global warming potential, when measured over 100 years, as a given mixture of greenhouse gases) for the entire UK population in 2009. This is 27% of total direct GHG emissions in the UK, or 19% of total GHG emissions from the UK, including those embodied in goods produced abroad. We calculate that potential GHG savings of 22% and 26% can be made by changing from the current UK-average diet to a vegetarian or vegan diet, respectively. Taking the average GHG saving from six vegetarian or vegan dietary scenarios compared with the current UK-average diet gives a potential national GHG saving of 40 Mt CO 2 e y −1 . This is equivalent to a 50% reduction in current exhaust pipe emissions from the entire UK passenger car fleet. Hence realistic choices about diet can make substantial differences to embodied GHG emissions. - Highlights: ► We calculate the greenhouse gas emissions embodied in different diets. ► The embodied GHG content of the current UK food supply is 7.4 kg CO 2 e person −1 day −1 . ► Changing to a vegetarian or vegan diet reduces GHG emissions by 22–26%. ► Changing to a vegetarian or vegan diet would reduce UK GHG emissions by 40 Mt CO 2 e y −1 .

  6. Study on the supercritical CO2 power cycles for landfill gas firing gas turbine bottoming cycle

    International Nuclear Information System (INIS)

    Kim, Min Seok; Ahn, Yoonhan; Kim, Beomjoo; Lee, Jeong Ik

    2016-01-01

    In this paper, a comparison of nine supercritical carbon dioxide (S-CO 2 ) bottoming power cycles in conjunction with a topping cycle of landfill gas (LFG) fired 5MWe gas turbine is presented. For the comparison purpose, a sensitivity study of the cycle design parameters for nine different cycles was conducted and each cycle thermodynamic performance is evaluated. In addition, the cycle performance evaluation dependency on the compressor inlet temperature variation is performed to investigate how S-CO 2 cycles sensitive to the heat sink temperature variation. Furthermore, the development of new S-CO 2 cycle layouts is reported and the suggested cycles' performances are compared to the existing cycle layouts. It was found that a recompression cycle is not suitable for the bottoming cycle application, but a partial heating cycle has relatively higher net produced work with a simple layout and small number of components. Although a dual heated and flow split cycle has the highest net produced work, it has disadvantages of having numerous components and complex process which requires more sophisticated operational strategies. This study identified that the recuperation process is much more important than the intercooling process to the S-CO 2 cycle design for increasing the thermal efficiency and the net produced work point of view. - Highlights: • Study of nine S-CO 2 power cycle layouts for a small scale landfill gas power generation application. • Development of new S-CO 2 cycle layouts. • Sensitivity analysis of S-CO 2 cycles to evaluate and compare nine cycles' performances.

  7. The operation of wholesale electricity, CO2 and natural gas markets in 2010-2011

    International Nuclear Information System (INIS)

    2011-01-01

    The first part analyses the electricity wholesale markets: development of the main wholesale market segments, electricity price, electricity production analysis and transparency of production data, transaction analysis. The second part analyses CO 2 markets: evolution of the institutional framework and perspectives, exchanges volumes on the CO 2 market, the CO 2 price in Europe, fundamentals of the European CO 2 market. The third part addresses the gas market: development of gas trade, gas price, gas infrastructures, supply and outlets for stake holders and new comers

  8. Livestock and greenhouse gas emissions

    DEFF Research Database (Denmark)

    Herrero, M; Gerber, P; Vellinga, T

    2011-01-01

    Estimates of global greenhouse gases (GHG) emissions attributable to livestock range from 8 to 51%. This variability creates confusion among policy makers and the public as it suggests that there is a lack of consensus among scientists with regard to the contribution of livestock to global GHG...

  9. CO2 , NOx and SOx removal from flue gas via microalgae cultivation: a critical review.

    Science.gov (United States)

    Yen, Hong-Wei; Ho, Shih-Hsin; Chen, Chun-Yen; Chang, Jo-Shu

    2015-06-01

    Flue gas refers to the gas emitting from the combustion processes, and it contains CO2 , NOx , SOx and other potentially hazardous compounds. Due to the increasing concerns of CO2 emissions and environmental pollution, the cleaning process of flue gas has attracted much attention. Using microalgae to clean up flue gas via photosynthesis is considered a promising CO2 mitigation process for flue gas. However, the impurities in the flue gas may inhibit microalgal growth, leading to a lower microalgae-based CO2 fixation rate. The inhibition effects of SOx that contribute to the low pH could be alleviated by maintaining a stable pH level, while NOx can be utilized as a nitrogen source to promote microalgae growth when it dissolves and is oxidized in the culture medium. The yielded microalgal biomass from fixing flue gas CO2 and utilizing NOx and SOx as nutrients would become suitable feedstock to produce biofuels and bio-based chemicals. In addition to the removal of SOx , NOx and CO2 , using microalgae to remove heavy metals from flue gas is also quite attractive. In conclusion, the use of microalgae for simultaneous removal of CO2 , SOx and NOx from flue gas is an environmentally benign process and represents an ideal platform for CO2 reutilization. Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Gas-liquid membrane contactors for CO2 removal

    NARCIS (Netherlands)

    Simons-Fischbein, K.; Nijmeijer, Dorothea C.; Wessling, Matthias

    2009-01-01

    In the present work we use a membrane contactor for the separation of CO2 from CH4 and we systematically investigate the influence of both the type of membrane and the different process parameters on the overall process performance (permeability and selectivity). This work is important because it

  11. Stakeholder Workshop Presentations: EPA Greenhouse Gas Data on Petroleum and Natural Gas Systems

    Science.gov (United States)

    View the summary and presentations from the November 2015 stakeholder workshop on greenhouse gas data on petroleum and natural gas systems from the Greenhouse Gas Reporting Program and U.S. Greenhouse Gas Inventory of Emissions and Sinks.

  12. Injeção de CO2 e lâminas de irrigação em tomateiro sob estufa CO2 injection and irrigation levels in greenhouse tomatoes

    Directory of Open Access Journals (Sweden)

    Denis Cesar Cararo

    2002-09-01

    -se os dados a funções quadráticas, foram de 78,82 t.ha-1 e 86,36 t.ha-1, correspondentes à aplicação de 335,2 mm e 333,6 mm de água para as estufas sem e com aplicação de CO2, respectivamente. Para uma faixa de variação do produto físico marginal de 0 a 1, as lâminas economicamente ótimas variaram de 335,2 mm a 322,4 mm em ausência de CO2 e de 333,6 mm a 323,8 mm com utilização do gás.The application of appropriate amounts of water and the usage of associated techniques improve the yield and quality of tomato fruits, assuring better profits to the farmer. We studied the effect of different water depth applications and carbon dioxide (CO2 injection in the irrigation system of a tomato crop, cv. Débora-Plus. An experiment was conducted in Piracicaba, São Paulo State (Brazil, under two greenhouses, using 40; 60; 80; 100; 120 and 140% of the water depth needed by the crop and C0 = 0 g of CO2.L-1 of water and C1 = 7.73 g.L-1 of CO2 concentrations were applied through irrigation water during 1999. The experiment was conducted in completely randomized blocks, with four replications. The CO2 treatments were applied in separate greenhouses. The irrigation was accomplished by using a drip irrigation system, based on reduced evaporimeters and tensiometers. The gas application was accomplished using a commercial cylinder and a Venturi type injector during the period necessary to reach the minimum water level. The application of CO2 through irrigation water increased the yield by 8.2%, raised the weight of small size fruits by 13% and the dry matter content of fruits by 8.5%. However, CO2 injection was ineffective in increasing the number and weight of medium sized fruits. The soil solution analysis indicated that CO2 possibly contributes to the improvement of the nutritional conditions of the tomato crop. The gas injection was economically feasible. The water depth did not have any significant effect on the yield, on total number of fruits, medium fruit weight

  13. Greenhouse Gas Emissions from Brazilian Sugarcane Soils

    Science.gov (United States)

    Carmo, J.; Pitombo, L.; Cantarella, H.; Rosseto, R.; Andrade, C.; Martinelli, L.; Gava, G.; Vargas, V.; Sousa-Neto, E.; Zotelli, L.; Filoso, S.; Neto, A. E.

    2012-04-01

    Bioethanol from sugarcane is increasingly seen as a sustainable alternative energy source. Besides having high photosynthetic efficiency, sugarcane is a perennial tropical grass crop that can re-grow up to five or more years after being planted. Brazil is the largest producer of sugarcane in the world and management practices commonly used in the country lead to lower rates of inorganic N fertilizer application than sugarcane grown elsewhere, or in comparison to other feedstocks such as corn. Therefore, Brazilian sugarcane ethanol potentially promotes greenhouse gas savings. For that reason, several recent studies have attempted to assess emissions of greenhouse gases (GHG) during sugarcane production in the tropics. However, estimates have been mainly based on models due to a general lack of field data. In this study, we present data from in situ experiments on emission of three GHG (CO2, N2O, and CH4) in sugarcane fields in Brazil. Emissions are provided for sugarcane in different phases of the crop life cycle and under different management practices. Our results show that the use of nitrogen fertilizer in sugarcane crops resulted in an emission factor for N2O similar to those predicted by IPCC (1%), ranging from 0.59% in ratoon cane to 1.11% in plant cane. However, when vinasse was applied in addition to mineralN fertilizer, emissions of GHG increased in comparison to those from the use of mineral N fertilizer alone. Emissions increased significantly when experiments mimicked the accumulation of cane trash on the soil surface with 14 tons ha-1and 21 tons ha-1, which emission factor were 1.89% and 3.03%, respectively. This study is representative of Brazilian sugarcane systems under specific conditions for key factors affecting GHG emissions from soils. Nevertheless, the data provided will improve estimates of GHG from Brazilian sugarcane, and efforts to assess sugarcane ethanol sustainability and energy balance. Funding provided by the São Paulo Research

  14. Microfluidic devices as gas – Ionic liquid membrane contactors for CO2 removal from anaesthesia gases

    NARCIS (Netherlands)

    Malankowska, Magdalena; Martins, C. F.; Rho, H. S.; Neves, L. A.; Tiggelaar, R. M.; Crespo, João G.; Pina, M.P.; Mallada, R.; Gardeniers, J.G.E.; Coelhoso, I. M.

    2018-01-01

    This work proposes a microfluidic gas – ionic liquid contactor for CO2 removal from anaesthesia gas, containing Xe. The working principle involves the transport of CO2 through a polymer flat membrane followed by its capture and enzymatic bioconversion in the ionic liquid solvent. Microfluidic

  15. The NOAA Annual Greenhouse Gas Index - 2012 Update

    Science.gov (United States)

    Butler, J. H.; Montzka, S. A.; Conway, T. J.; Dlugokencky, E. J.; Elkins, J. W.; Masari, K. A.; Schnell, R. C.; Tans, P. P.

    2012-04-01

    For the past several decades, the U.S. National Oceanic and Atmospheric Administration (NOAA) has monitored all of the long-lived atmospheric greenhouse gases. These global measurements have provided input to databases, analyses, and various relevant products, including national and international climate assessments. To make these data more useful and available, NOAA several years ago released its Annual Greenhouse Gas Index (AGGI), http://www.esrl.noaa.gov/gmd/aggi. This index, based on the climate forcing properties of long-lived greenhouse gases, was designed to enhance the connection between scientists and society by providing a normalized standard that can be easily understood and followed. The long-lived gases capture most of the radiative forcing, and uncertainty in their measurement is very small. This allows us to provide a robust measure and assessment of the long-term, radiative influence of these gases. Continuous greenhouse gas measurements are made at baseline climate observatories (Pt. Barrow, Alaska; Mauna Loa, Hawaii; American Samoa; and the South Pole) and weekly flask air samples are collected through a global network of over 60 sites, including an international cooperative program for carbon dioxide and other greenhouse gases. The gas samples are analyzed at NOAA's Earth System Research Laboratory (NOAA/ESRL) in Boulder, Colorado, using WMO standard reference gases prepared by NOAA/ESRL. The AGGI is normalized to 1.00 in 1990, the Kyoto Climate Protocol baseline year. In 2010, the AGGI was 1.29, indicating that global radiative forcing by long-lived greenhouse gases had increased 29% since 1990. During the 1980s CO2 accounted for about 50-60% of the annual increase in radiative forcing by long-lived greenhouse gases, whereas, since 2000, it has accounted for 85-90% of this increase each year. After nearly a decade of virtually level concentrations in the atmosphere, methane (CH4) increased measurably over the past 2-3 years, as did its

  16. Effect of Elevated CO2 in Different Fertilizer Conditions on Physiological Traits in Lemon Balm (Melissa officinalis at Greenhouse

    Directory of Open Access Journals (Sweden)

    M Shoor

    2012-07-01

    Full Text Available Increasing atmospheric CO2 concentrations and nutrients supply are generally expected to enhance photosynthesis and growth of crops as a result considerably increase yields. The present study aims to investigate effects of elevated CO2 and different fertilizer conditions on physiological traits in Lemon balm. A factorial experiment was conducted based on completely randomized design with three replications and nine treatments at the greenhouse in 2010. The experiment factors were included three CO2 concentrations (380, 700 and 1050 ppm and three kinds of conditions fertilizer (no fertilizer, manure fertilizer and nitrogen fertilizer. The results indicated that increasing of CO2 from 380 to 1050 ppm led to improve in leaf area, plant height, relative growth ratio, total dry matter and final yield of individual plant. The highest and the lowest amount of measured traits related to with and without nitrogen fertilizer, respectively. Impact of elevated CO2 in conjunction with nitrogen and manure fertilizers increased. These effects were more on total dry matter and final yield than other growth indices. Therefore, it can be concluded that, whereas increase of temperature caused by rising CO2 is not considered or there is not any limitation for resources, CO2 enrichment will be improved lemon balm production.

  17. How to prevent greenhouse gas emissions in electrical installations: lighting energy savings and solar energy approaches

    International Nuclear Information System (INIS)

    Yavuz, C.; Aksoy, C.

    2012-01-01

    Day by day greenhouse gas emissions increase dramatically. A passive adaptive method of lighting energy savings, daylight responsive systems are considered one of the best solutions for energy efficiency, saving and prevent CO 2 emissions. Results of an annual experiment which was held in Sakarya University proves the necessity of daylight responsive systems with a 41% energy saving and 942.5 kg of prevented CO 2 emissions Thinking this prevention is realized just only in a 36 m 2 room with the use of 8 luminaries spreading such systems to nationwide, a major amount of greenhouse gas emissions would be prohibited. On the other hand energy saving is not the only way to reduce CO 2 emissions. Again in Sakarya University a project has started to investigate the possibility of illumination of a complete building by using solar energy. This paper evaluates these mentioned systems both in energy efficiency, greenhouse gas emissions prevention and economic point of views. (author)

  18. Greenhouse Gas Laser Imaging Tomography Experiment (GreenLITE

    Directory of Open Access Journals (Sweden)

    Dobler Jeremy

    2016-01-01

    Full Text Available Exelis has recently developed a novel laser-based instrument to aid in the autonomous real-time monitoring and mapping of CO2 concentration over a two-dimensional area. The Greenhouse gas Laser Imaging Tomography Experiment (GreenLITE instrument uses two transceivers and a series of retroreflectors to continuously measure the differential transmission over a number of overlapping lines of sight or “chords”, forming a plane. By inverting the differential transmission measurements along with locally measured temperature (T, pressure (P and relative humidity (RH the average concentration of CO2 along each chord can be determined and, based on the overlap between chords, a 2D map of CO2 concentration over the measurement plane can be estimated. The GreenLITE system was deployed to the Zero Emissions Research and Technology (ZERT center in Bozeman, Montana, in Aug-Sept 2014, where more than 200 hours of data were collected over a wide range of environmental conditions, while utilizing a controlled release of CO2 into a segmented underground pipe [1]. The system demonstrated the ability to identify persistent CO2 sources at the test facility and showed strong correlation with an independent measurement using a LI-COR based system. Here we describe the measurement approach, instrument design, and results from the deployment to the ZERT site.

  19. Amino acid salt solutions as solvents in CO2 capture from flue gas

    DEFF Research Database (Denmark)

    Lerche, Benedicte Mai; Thomsen, Kaj; Stenby, Erling Halfdan

    solutions is their ability to form solid precipitates upon the absorption of CO2. The occurrence of crystallization offers the possibility of increasing the CO2 loading capacity of the solvent. However, precipitation can also have negative effect on the CO2 capture process. The chemical nature of the solid...... formed is a decisive factor in determining the effect of precipitation on the process. For the purpose of studying the CO2 loading capacity of amino acid salt solutions, we developed an experimental set-up based on a dynamic analytical mode, with analysis of the effluent gas. Using this set-up, the CO2......New solvents based on the salts of amino acids have emerged as an alternative to the alkanolamine solutions, for the chemical absorption of CO2 from flue gas. But only few studies on amino acids as CO2 capturing agents have been performed so far. One of the interesting features of amino acid salt...

  20. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    OpenAIRE

    Delucchi, Mark

    1997-01-01

    The use of energy accounts for a major fraction of all anthropogenic emissions of greenhouse gases (IPCC, 1995) , and in most industrialized countries the use of transportation fuels and electricity accounts for a major fraction of all energy-related emissions. In the transportation sector alone, emissions of carbon dioxide (CO2) from the production and use of motor-vehicle fuels account for as much as 30% of CO2 emissions from the use of all fossil fuels (DeLuchi, 1991). The production and...

  1. State and Territory Greenhouse Gas Emissions 2004

    International Nuclear Information System (INIS)

    2006-06-01

    This document provides an overview of the latest available estimates of greenhouse gas emissions for Australia's States and Territories. Australia's total greenhouse gas emissions in 2004 amounted to 564.7 million tonnes. The State and Territory breakdown was: New South Wales: 158.7 million tonnes (Mt); Queensland: 158.5 Mt; Victoria: 123.0 Mt; Western Australia: 68.5 Mt; South Australia: 27.6 Mt; Northern Territory: 15.6 Mt; Tasmania: 10.7 Mt; ACT: 1.2 Mt. The summary of State and Territory inventories presented in this document reports estimates of greenhouse gas emissions for each State and Territory for the period 1990 to 2004. It is the first time that a complete annual time-series has been reported

  2. Future forecast for life-cycle greenhouse gas emissions of LNG and city gas 13A

    International Nuclear Information System (INIS)

    Okamura, Tomohito; Furukawa, Michinobu; Ishitani, Hisashi

    2007-01-01

    The objective of this paper is to analyze the most up-to-date data available on total greenhouse-gas emissions of a LNG fuel supply chain and life-cycle of city gas 13A based on surveys of the LNG projects delivering to Japan, which should provide useful basic-data for conducting life-cycle analyses of other product systems as well as future alternative energy systems, because of highly reliable data qualified in terms of its source and representativeness. In addition, the life-cycle greenhouse-gas emissions of LNG and city-gas 13A in 2010 were also predicted, taking into account not only the improvement of technologies, but also the change of composition of LNG projects. As a result of this analysis, the total amount of greenhouse-gas emissions of the whole city-gas 13A chain at present was calculated to be 61.91 g-CO 2 /MJ, and the life-cycle greenhouse-gas emissions of LNG and city-gas 13A in 2010 could be expected to decrease by about 1.1% of the current emissions

  3. Greenhouse gas emissions from shale gas and coal for electricity generation in South Africa

    Directory of Open Access Journals (Sweden)

    Brett Cohen

    2014-03-01

    Full Text Available There is increased interest, both in South Africa and globally, in the use of shale gas for electricity and energy supply. The exploitation of shale gas is, however, not without controversy, because of the reported environmental impacts associated with its extraction. The focus of this article is on the greenhouse gas footprint of shale gas, which some literature suggests may be higher than what would have been expected as a consequence of the contribution of fugitive emissions during extraction, processing and transport. Based on some studies, it has been suggested that life-cycle emissions may be higher than those from coal-fired power. Here we review a number of studies and analyse the data to provide a view of the likely greenhouse gas emissions from producing electricity from shale gas, and compare these emissions to those of coal-fired power in South Africa. Consideration was given to critical assumptions that determine the relative performance of the two sources of feedstock for generating electricity � that is the global warming potential of methane and the extent of fugitive emissions. The present analysis suggests that a 100-year time horizon is appropriate in analysis related to climate change, over which period the relative contribution is lower than for shorter periods. The purpose is to limit temperature increase in the long term and the choice of metric should be appropriate. The analysis indicates that, regardless of the assumptions about fugitive emissions and the period over which global warming potential is assessed, shale gas has lower greenhouse gas emissions per MWh of electricity generated than coal. Depending on various factors, electricity from shale gas would have a specific emissions intensity between 0.3 tCO2/MWh and 0.6 tCO2/MWh, compared with about 1 tCO2/MWh for coal-fired electricity in South Africa.

  4. Greenhouse gas neutral Germany in 2050

    International Nuclear Information System (INIS)

    Benndorf, Rosemarie; Bernicke, Maja; Bertram, Andreas

    2014-01-01

    In order to answer the question how a greenhouse gas neutral Germany would look like an interdisciplinary process was started by the Federal Environmental Agency. It was clear from the beginning of this work that a sustainable regenerative energy supply could not be sufficient. Therefore all relevant emission sources were included into the studies: traffic, industry, waste and waste water, agriculture, land usage, land usage changes and forestry. The necessary transformation paths to reach the aim of a greenhouse gas neutral Germany in 2050, economic considerations and political instruments were not part of this study.

  5. Greenhouse Gas Emissions From Cattle

    Directory of Open Access Journals (Sweden)

    Podkówka Zbigniew

    2015-03-01

    Full Text Available Cattle produce greenhouse gases (GHG which lead to changes in the chemical composition of the atmosphere. These gases which cause greenhouse effect include: methane (CH4, nitrous oxide (N2O, nitrogen oxides (NOx, sulphur dioxide (SO2, ammonia (NH3, dust particles and non-methane volatile organic compounds, commonly described as other than methane hydrocarbons. Fermentation processes taking place in the digestive tract produce ‘digestive gases’, distinguished from gases which are emitted during the decomposition of manure. Among these digestive gases methane and non-methane volatile organic compounds are of particular relevance importance. The amount of gases produced by cows can be reduced by choosing to rear animals with an improved genetically based performance. A dairy cow with higher production efficiency, producing milk with higher protein content and at the same time reduced fat content emits less GHG into the environment. Increasing the ratio of feed mixtures in a feed ration also reduces GHG emissions, especially of methane. By selection of dairy cows with higher production efficiency and appropriate nutrition, the farm's expected milk production target can be achieved while at the same time, the size of the herd is reduced, leading to a reduction of GHG emissions.

  6. Catchment-Wide Atmospheric Greenhouse Gas Exchange as Influenced by Land Use Diversity

    DEFF Research Database (Denmark)

    Herbst, Mathias; Friborg, Thomas; Ringgaard, Rasmus

    2011-01-01

    . The measurements also included the turbulent fl uxes of methane above the wet grassland and of nitrous oxide above the agricultural area and ran continuously throughout the year 2009. The highest CO2 uptake rates (around 30 µmol m-2 s-1) were observed at the agricultural site; however, the site was a CO2 sink only......, and its annual CO2 fixation was only marginally higher than that of the agricultural site. The emission of CH4 from the wet grassland showed large seasonal variations. Its annual total corresponded to 276 g CO2 equivalents m-2 (based on a 100-yrtime horizon) and reduced the greenhouse gas sink strength...

  7. Effects of CO2 gas as leaks from geological storage sites on agro-ecosystems

    DEFF Research Database (Denmark)

    Patil, Ravi; Colls, Jeremy J; Steven, Michael D

    2010-01-01

    Carbon capture and storage in geological formations has potential risks in the long-term safety because of the possibility of CO2 leakage. Effects of leaking gas, therefore, on vegetation, soil, and soil-inhabiting organisms are critical to understand. An artificial soil gassing and response...... detection field facility developed at the University of Nottingham was used to inject CO2 gas at a controlled flow rate (1 l min-1) into soil to simulate build-up of soil CO2 concentrations and surface fluxes from two land use types: pasture grassland, and fallow followed by winter bean. Mean soil CO2...

  8. Greenhouse gas and energy analysis of substitute natural gas from biomass for space heat

    International Nuclear Information System (INIS)

    Pucker, Johanna; Zwart, Robin; Jungmeier, Gerfried

    2012-01-01

    In this paper, the greenhouse gas and energy balances of the production and use for space heating of substitute natural gas from biomass (bio-SNG) for space heat are analysed. These balances are compared to the use of natural gas and solid biomass as wood chips to provide the same service. The reduction of the greenhouse gas emissions (CO 2 -eq.) – carbon dioxide, methane and nitrous oxide – and of the fossil primary energy use is investigated in a life cycle assessment (LCA). This assessment was performed for nine systems for bio-SNG; three types of gasification technologies (O 2 -blown entrained flow, O 2 -blown circulating fluidised bed and air–steam indirect gasification) with three different types of feedstock (forest residues, miscanthus and short rotation forestry). The greenhouse gas analysis shows that forest residues using the air–steam indirect gasification technology result in the lowest greenhouse gas emissions (in CO 2 -eq. 32 kg MWh −1 of heat output). This combination results in 80% reduction of greenhouse gas emissions when compared to natural gas and a 29% reduction of greenhouse gases if the forest residues were converted to wood chips and combusted. The gasification technologies O 2 -blown entrained flow and O 2 -blown circulating fluidised bed gasification have higher greenhouse gas emissions that range between in CO 2 -eq. 41 to 75 kg MWh −1 of heat output depending on the feedstock. When comparing feedstocks in the bio-SNG systems, miscanthus had the highest greenhouse gas emissions bio-SNG systems producing in CO 2 -eq. 57–75 kg MWh −1 of heat output. Energy analysis shows that the total primary energy use is higher for bio-SNG systems (1.59–2.13 MWh MWh −1 of heat output) than for the reference systems (in 1.37–1.51 MWh MWh −1 of heat output). However, with bio-SNG the fossil primary energy consumption is reduced compared to natural gas. For example, fossil primary energy use is reduced by 92% when air

  9. Greenhouse gas emission offsets: A global warming insurance policy

    International Nuclear Information System (INIS)

    Sturges, S.D.

    1993-01-01

    While scientists work to define the nature and extent of potential climate change, policy makers debate the appropriateness of different responses. One voluntary initiative has pursued a possible response: greenhouse gas offsets. This article describes a program undertaken by The AES Corporation to attempt to offset CO 2 emissions from cogeneration facilities run by the corporation. Independent investigations indicated that an extensive reforestation program might be a practical way to create sinks for CO 2 . This article describes some of the practical concerns of this project. It also describes efforts made to locate areas to carry out a reforestation program, groups worked with, and effort devoted to finding ways to quantify the success of any effort undertaken

  10. [Effects of superphosphate addition on NH3 and greenhouse gas emissions during vegetable waste composting].

    Science.gov (United States)

    Yang, Yan; Sun, Qin-ping; Li, Ni; Liu, Chun-sheng; Li, Ji-jin; Liu, Ben-sheng; Zou, Guo-yuan

    2015-01-01

    To study the effects of superphosphate (SP) on the NH, and greenhouse gas emissions, vegetable waste composting was performed for 27 days using 6 different treatments. In addition to the controls, five vegetable waste mixtures (0.77 m3 each) were treated with different amounts of the SP additive, namely, 5%, 10%, 15%, 20% and 25%. The ammonia volatilization loss and greenhouse gas emissions were measured during composting. Results indicated that the SP additive significantly decreased the ammonia volatilization and greenhouse gas emissions during vegetable waste composting. The additive reduced the total NH3 emission by 4.0% to 16.7%. The total greenhouse gas emissions (CO2-eq) of all treatments with SP additives were decreased by 10.2% to 20.8%, as compared with the controls. The NH3 emission during vegetable waste composting had the highest contribution to the greenhouse effect caused by the four different gases. The amount of NH3 (CO2-eq) from each treatment ranged from 59.90 kg . t-1 to 81.58 kg . t-1; NH3(CO2-eq) accounted for 69% to 77% of the total emissions from the four gases. Therefore, SP is a cost-effective phosphorus-based fertilizer that can be used as an additive during vegetable waste composting to reduce the NH3 and greenhouse gas emissions as well as to improve the value of compost as a fertilizer.

  11. Glacial greenhouse-gas fluctuations controlled by ocean circulation changes.

    Science.gov (United States)

    Schmittner, Andreas; Galbraith, Eric D

    2008-11-20

    Earth's climate and the concentrations of the atmospheric greenhouse gases carbon dioxide (CO(2)) and nitrous oxide (N(2)O) varied strongly on millennial timescales during past glacial periods. Large and rapid warming events in Greenland and the North Atlantic were followed by more gradual cooling, and are highly correlated with fluctuations of N(2)O as recorded in ice cores. Antarctic temperature variations, on the other hand, were smaller and more gradual, showed warming during the Greenland cold phase and cooling while the North Atlantic was warm, and were highly correlated with fluctuations in CO(2). Abrupt changes in the Atlantic meridional overturning circulation (AMOC) have often been invoked to explain the physical characteristics of these Dansgaard-Oeschger climate oscillations, but the mechanisms for the greenhouse-gas variations and their linkage to the AMOC have remained unclear. Here we present simulations with a coupled model of glacial climate and biogeochemical cycles, forced only with changes in the AMOC. The model simultaneously reproduces characteristic features of the Dansgaard-Oeschger temperature, as well as CO(2) and N(2)O fluctuations. Despite significant changes in the land carbon inventory, CO(2) variations on millennial timescales are dominated by slow changes in the deep ocean inventory of biologically sequestered carbon and are correlated with Antarctic temperature and Southern Ocean stratification. In contrast, N(2)O co-varies more rapidly with Greenland temperatures owing to fast adjustments of the thermocline oxygen budget. These results suggest that ocean circulation changes were the primary mechanism that drove glacial CO(2) and N(2)O fluctuations on millennial timescales.

  12. Multi-sectorial convergence in greenhouse gas emissions.

    Science.gov (United States)

    Oliveira, Guilherme de; Bourscheidt, Deise Maria

    2017-07-01

    This paper uses the World Input-Output Database (WIOD) to test the hypothesis of per capita convergence in greenhouse gas (GHG) emissions for a multi-sectorial panel of countries. The empirical strategy applies conventional estimators of random and fixed effects and Arellano and Bond's (1991) GMM to the main pollutants related to the greenhouse effect. For reasonable empirical specifications, the model revealed robust evidence of per capita convergence in CH 4 emissions in the agriculture, food, and services sectors. The evidence of convergence in CO 2 emissions was moderate in the following sectors: agriculture, food, non-durable goods manufacturing, and services. In all cases, the time for convergence was less than 15 years. Regarding emissions by energy use, the largest source of global warming, there was only moderate evidence in the extractive industry sector-all other pollutants presented little or no evidence. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Recovery of [CO2]T from Aqueous Bicarbonate using a Gas Permeable Membrane

    Science.gov (United States)

    2008-06-25

    Gabelman, A.; Hwang, S-T. Hollow Fiber Membrane Contactors . J. Membr. Sci. 1999, 159, 61. 17. Bhave, R. R.; Sirkar, K. K. Gas Permeation and...Naval Research Laboratory Washington, DC 20375-5320 NRL/MR/6180--08-9129 Recovery of [CO2]T from Aqueous Bicarbonate using a Gas Permeable Membrane ...17. LIMITATION OF ABSTRACT Recovery of [CO2]T from Aqueous Bicarbonate using a Gas Permeable Membrane Heather D. Willauer, Dennis R. Hardy, M. Kathleen

  14. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    Energy Technology Data Exchange (ETDEWEB)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  15. 2013 Update of NOAA's Annual Greenhouse Gas Index

    Science.gov (United States)

    Butler, James H.; Montzka, Stephen A.; Dlugokencky, Edward J.; Elkins, James W.; Masari, Kenneth A.; Schnell, Russell C.; Tans, Pieter P.

    2013-04-01

    Indexes are becoming increasingly important in communicating messages about climate change to a diverse public. Indexes exist for a number of climate-related phenomena including heat, precipitation, and extreme events. These help communicate complex phenomena to the public and, at times, policy makers, to aid in understanding or making decisions. Several years ago, NOAA introduced a unique index for expressing the influence of human-emitted, long-lived greenhouse gases in the atmosphere (DJ Hofmann et al., Tellus, 2006, S8B 614-619). Essentially a condensation and normalization of radiative forcing from long-lived gases, the NOAA Annual Greenhouse Gas Index (AGGI) was designed to enhance the connection between scientists and society by providing a standard that could be easily understood and followed. The index each year is calculated from high quality, long-term observations by NOAA's Global Monitoring Division, which includes real-time measurements extending over the past five decades, as well as published ice core record that go back to 1750. The AGGI is normalized to 1.00 in 1990, the Kyoto Climate Protocol baseline year. At the end of 2011, the AGGI was 1.30, indicating that global radiative forcing by long-lived greenhouse gases had increased 30% since 1990. During the 1980s CO2 accounted for about 50-60% of the annual increase in radiative forcing by long-lived greenhouse gases, whereas, since 2000, it has accounted for 85-90% of this increase each year. After nearly a decade of virtually level concentrations in the atmosphere, methane (CH4) increased measurably over the past 2-3 years, as did its contribution to radiative forcing. In addition to presenting the AGGI for 2012, increases in radiative forcing will be evaluated and discussed with respect to the contributions from CO2, CH4, nitrous oxide (N2O), chlorofluorocarbons (CFCs), and other emerging greenhouse gases.

  16. Peat and the greenhouse effect - Comparison of peat with coal, oil, natural gas and wood

    International Nuclear Information System (INIS)

    Hillebrand, K.

    1993-01-01

    The earth's climate is effected both by natural factors and human activities. So called greenhouse gas emissions increase the increment of the temperature of the air nearby the earth's surface, due to which the social changes can be large. The increment of greenhouse gas concentration in the atmosphere is due to increasing energy consumption. About 50 % of the climatic changes are caused by increase of the CO 2 concentration in the atmosphere. Other gases, formed in the energy production, intensifying the greenhouse effect are methane and nitrous oxide. The effect of greenhouse gases is based on their ability to absorb infrared radiation coming from the earth. This presentation discusses some of the greenhouse effect caused by some peat production and utilization chains in comparison with corresponding effects of coal, oil, natural gas and wood. The instantaneous greenhouse effects and the cumulative effects of the emissions of the gases (CO 2 , CH 4 and N 2 O) during a time period has been reviewed. The greenhouse effect has been calculated as CO 2 - equivalents. (5 figs.)

  17. Greenhouse gas balances of biomass energy systems

    International Nuclear Information System (INIS)

    Marland, G.; Schlamadinger, B.

    1996-01-01

    A full energy-cycle analysis of greenhouse gas emissions of biomass energy systems requires analysis well beyond the energy sector. For example, production of biomass fuels impacts on the global carbon cycle by altering the amount of carbon stored in the biosphere and often by producing a stream of by-products or co-products which substitute for other energy-intensive products like cement, steel, concrete or, in case of ethanol form corn, animal feed. It is necessary to distinguish between greenhouse gas emissions associated with the energy product as opposed to those associated with other products. Production of biomass fuels also has an opportunity cost because it uses large land areas which could have been used otherwise. Accounting for the greenhouse gas emissions from biomass fuels in an environment of credits and debits creates additional challenges because there are large non-linearities in carbon flows over time. This paper presents some of the technical challenges of comprehensive greenhouse gas accounting and distinguishes between technical and public policy issues. (author). 5 refs, 5 figs

  18. Earthworms and the soil greenhouse gas balance

    NARCIS (Netherlands)

    Lubbers, I.M.

    2014-01-01

    Earthworms play an essential part in determining the greenhouse gas (GHG) balance of soils worldwide. Their activity affects both biotic and abiotic soil properties, which in turn influence soil GHG emissions, carbon (C) sequestration and plant growth. Yet, the balance of earthworms

  19. The EU Greenhouse Gas Emissions Trading Scheme

    NARCIS (Netherlands)

    Woerdman, Edwin; Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

    2015-01-01

    This chapter explains how greenhouse gas emissions trading works, provides the essentials of the Directive on the European Union Emissions Trading Scheme (EU ETS) and summarizes the main implementation problems of the EU ETS. In addition, a law and economics approach is used to discuss the dilemmas

  20. Greenhouse gas balances of biomass energy systems

    International Nuclear Information System (INIS)

    Marland, G.; Schlamadinger, B.

    1994-01-01

    A full energy-cycle analysis of greenhouse gas emissions of biomass energy systems requires analysis well beyond the energy sector. For example, production of biomass fuels impacts on the global carbon cycle by altering the amount of carbon stored in the biosphere and often by producing a stream of by-products or co-products which substitute for other energy-intensive products like cement, steel, concrete or, in case of ethanol from corn, animal feed. It is necessary to distinguish between greenhouse gas emissions associated with the energy product as opposed to those associated with other products. Production of biomass fuels also has an opportunity cost because it uses large land areas which could have been used otherwise. Accounting for the greenhouse gas emissions from biomass fuels in an environment of credits and debits creates additional challenges because there are large nonlinearities in the carbon flows over time. This paper presents some of the technical challenges of comprehensive greenhouse gas accounting and distinguishes between technical and public policy issues

  1. Earthworms and the soil greenhouse gas balance

    NARCIS (Netherlands)

    Lubbers, I.M.

    2014-01-01

      Earthworms play an essential part in determining the greenhouse gas (GHG) balance of soils worldwide. Their activity affects both biotic and abiotic soil properties, which in turn influence soil GHG emissions, carbon (C) sequestration and plant growth. Yet, the balance of earthworms

  2. Modeling greenhouse gas emissions from dairy farms

    Science.gov (United States)

    Dairy farms have been identified as an important source of greenhouse gas emissions. Within the farm, important emissions include enteric methane (CH4) from the animals, CH4 and nitrous oxide (N2O) from manure in housing facilities, during long-term storage and during field application, and N2O from...

  3. Life Cycle Assessment of Greenhouse Gas Emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.Y.; Suzuki, T.; Lackner, M.

    2015-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products "from cradle to grave": from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production, and waste

  4. Life cycle assessment of greenhouse gas emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.-Y.; Suzuki, T.; Lackner, M.

    2017-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products “from cradle to grave”: from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production, and waste

  5. Life cycle assessment of greenhouse gas emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.Y.; Seiner, J.; Suzuki, T.; Lackner, M.

    2012-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products "from cradle to grave": from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production and to waste

  6. Australia's consumption-based greenhouse gas emissions

    DEFF Research Database (Denmark)

    Levitt, Clinton J.; Saaby, Morten; Sørensen, Anders

    2017-01-01

    We use data from the World Input-Output Database in a multiregional input–output model to analyse Australian consumption-based greenhouse gas emissions for the years 1995 to 2009. We find that the emission content of Australian macroeconomic activity has changed over the 15-year period. Consumption...

  7. Greenhouse Gas Emissions from Agricultural Production

    DEFF Research Database (Denmark)

    Bennetzen, Eskild Hohlmann

    Global climate change is recognised as one of the major current challenges to humanity. At the same time, climate change is human induced and we hold the opportunity to react accordingly. While global greenhouse gas (GHG) emissions continue to rise, emissions from agriculture and land-use change...

  8. Improving the Greenlandic Greenhouse Gas Inventory

    DEFF Research Database (Denmark)

    Nielsen, Ole-Kenneth; Baunbæk, Lene; Gyldenkærne, Steen

    The project to improve the Greenlandic greenhouse gas (GHG) inventory was undertaken due to the recommendations made by the UNFCCC review team in connection with the 2008 and 2009 submissions by the Kingdom of Denmark. The improvements made to the Greenlandic GHG emission inventory were substantial...

  9. Highly integrated CO2 capture and conversion: Direct synthesis of cyclic carbonates from industrial flue gas

    KAUST Repository

    Barthel, Alexander

    2016-02-08

    Robust and selective catalytic systems based on early transition metal halides (Y, Sc, Zr) and organic nucleophiles were found able to quantitatively capture CO2 from diluted streams via formation of hemicarbonate species and to convert it to cyclic organic carbonates under ambient conditions. This observation was exploited in the direct and selective chemical fixation of flue gas CO2 collected from an industrial exhaust, affording high degrees of CO2 capture and conversion.

  10. The sequestration of CO2

    International Nuclear Information System (INIS)

    Le Thiez, P.

    2004-01-01

    The reduction of greenhouse gas emissions, especially CO 2 , represents a major technological and societal challenge in the fight against climate change. Among the measures likely to reduce anthropic CO 2 emissions, capture and geological storage holds out promise for the future. (author)

  11. A microporous MOF with a polar pore surface exhibiting excellent selective adsorption of CO2 from CO2-N2 and CO2-CH4 gas mixtures with high CO2 loading.

    Science.gov (United States)

    Pal, Arun; Chand, Santanu; Elahi, Syed Meheboob; Das, Madhab C

    2017-11-14

    A microporous MOF {[Zn(SDB)(L) 0.5 ]·S} n (IITKGP-5) with a polar pore surface has been constructed by the combination of a V-shaped -SO 2 functionalized organic linker (H 2 SDB = 4,4'-sulfonyldibenzoic acid) with an N-rich spacer (L = 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene), forming a network with sql(2,6L1) topology. IITKGP-5 is characterized by TGA, PXRD and single crystal X-ray diffraction. The framework exhibits lozenge-shaped channels of an approximate size of 4.2 × 5.6 Å 2 along the crystallographic b axis with a potential solvent accessible volume of 26%. The activated IITKGP-5a revealed a CO 2 uptake capacity of 56.4 and 49 cm 3 g -1 at 273 K/1 atm and 295 K/1 atm, respectively. On the contrary, it takes up a much smaller amount of CH 4 (17 cm 3 g -1 at 273 K and 13.6 cm 3 g -1 at 295 K) and N 2 (5.5 cm 3 g -1 at 273 K; 4 cm 3 g -1 at 295 K) under 1 atm pressure exhibiting its potential for a highly selective adsorption of CO 2 from flue gas as well as a landfill gas mixture. Based on the ideal adsorbed solution theory (IAST), a CO 2 /N 2 selectivity of 435.5 and a CO 2 /CH 4 selectivity of 151.6 have been realized at 273 K/100 kPa. The values at 295 K are 147.8 for CO 2 /N 2 and 23.8 for CO 2 /CH 4 gas mixtures under 100 kPa. In addition, this MOF nearly approaches the target values proposed for PSA and TSA processes for practical utility exhibiting its prospect for flue gas separation with a CO 2 loading capacity of 2.04 mmol g -1 .

  12. Surrogate gas proxy prediction model for Delta 14C-based measurements of fossil fuel-CO2

    Science.gov (United States)

    Coakley, K. J.; Miller, J. B.; Montzka, S. A.; Sweeney, C.; Miller, B.

    2016-12-01

    The measured {}14}C {:12} {C isotopic ratio ofatmospheric CO2 (and its associated derived Δ 14Cvalue) is an ideal tracer for determination of the fossil fuelderived CO2 enhancement contributing to any atmosphericCO2 measurement (Cff). Given enough such measurements,independent top-down estimation of US fossil fuel- CO2emissions should be possible. However, the number of Δ 14Cmeasurements is presently constrained by cost, available samplevolume, and availability of mass spectrometer measurement facilities.Δ 14C is therefore measured in just a small fraction ofsamples obtained by flask air sampling networks around the world.Here, we develop a Projection Pursuit Regression model topredict Cff as a function of multiple surrogate gases acquiredwithin the NOAA/ESRL Global Greenhouse Gas Reference Network (GGGRN).The surrogates consist of measured enhancements of various anthropogenictrace gases, including CO, SF6, and halo- andhydro-carbons acquired in vertical airborne sampling profiles nearCape May, NJ and Portsmouth, NH from 2005 through 2010. Modelperformance is quantified based on predicted values correspondingto test data excluded from the model building process. Chi-squarehypothesis test analysis indicates that these predictions andcorresponding observations are consistent given our uncertaintybudget which accounts for random effects and one particular systematiceffect. To account for the possibility of additional systematiceffects, we incorporate another component of uncertainty into ourbudget. Provided that these estimates are of comparable qualityto Δ 14C -based estimates, we expect an improved determinationof fossil fuel-CO2 emissions.

  13. Uncertainties in the Finnish greenhouse gas emission inventory

    International Nuclear Information System (INIS)

    Monni, Suvi; Syri, Sanna; Savolainen, Ilkka

    2004-01-01

    Reliable uncertainty estimates are a tool for increasing the quality of national emission inventories which are essential for the implementation of the Kyoto Protocol. The first detailed uncertainty assessment was performed for the Finnish greenhouse gas emission inventory considering the years 1990 and 2001 using Monte Carlo simulation to combine uncertainties. In this work, uncertainty estimates were based on available measurement data, domestic and international literature, expert judgement and the recommendations of the Intergovernmental Panel on Climate Change (IPCC). Uncertainties were estimated at a more detailed level than in studies performed in many other countries, thus giving additional information on the most important emission sources in terms of uncertainty. The emissions of the most important greenhouse gas, CO 2 , are often well known, but the other gases contain higher uncertainties. The resulting total uncertainty in the year 2001 emissions was -5 to +6% and that of trend ±5%-points. The uncertainty range indicates that Finnish emissions were 75-84 Mt CO 2 equivalents in 2001. In countries with larger emissions the effect of uncertainty is even more significant. Countries which have performed an uncertainty estimate are able to use the information on most uncertain sources in allocation of resources for inventory improvements. In climate policy, information on uncertainty can be used in negotiations on the use of Kyoto mechanisms and in negotiations of inclusion of new sources or gases in future climate conventions. Integration of uncertainty aspects in decision making ensures that climate conventions are of real benefit in terms of mitigating climate change

  14. Soil greenhouse gas emissions reduce the contribution of mangrove plants to the atmospheric cooling effect

    Science.gov (United States)

    Chen, Guangcheng; Chen, Bin; Yu, Dan; Tam, Nora F. Y.; Ye, Yong; Chen, Shunyang

    2016-12-01

    Mangrove soils have been recognized as sources of greenhouse gases, but the atmospheric fluxes are poorly characterized, and their adverse warming effect has rarely been considered with respect to the potential contribution of mangrove wetlands to climate change mitigation. The current study balanced the warming effect of soil greenhouse gas emissions with the plant carbon dioxide (CO2) sequestration rate derived from the plants’ net primary production in a productive mangrove wetland in South China to assess the role of mangrove wetlands in reducing the atmospheric warming effect. Soil characteristics were also studied in the summer to examine their relationships with gas fluxes. The soil to atmosphere fluxes of nitrous oxide (N2O), methane (CH4) and CO2 ranged from -1.6 to 50.0 μg m-2 h-1, from -1.4 to 5360.1 μg m-2 h-1 and from -31 to 512 mg m-2 h-1, respectively, which indicated that the mangrove soils act as sources of greenhouse gases in this area. The gas fluxes were higher in summer than in the cold seasons and were variable across mangrove sites. Gas fluxes in summer were positively correlated with the soil organic carbon, total nitrogen, and ammonia contents. The mangrove plants sequestered a considerable amount of atmospheric CO2 at rates varying from 3652 to 7420 g CO2 m-2 yr-1. The ecosystem acted as a source of CH4 and N2O gases but was a more intense CO2 sink. However, the warming effect of soil gas emissions accounted for 9.3-32.7% of the plant CO2 sequestration rate, partially reducing the benefit of mangrove plants, and the two trace gases comprised 9.7-33.2% of the total warming effect. We therefore propose that an assessment of the reduction of atmospheric warming effects by a mangrove ecosystem should consider both soil greenhouse gas emissions and plant CO2 sequestration.

  15. Implications of the recent reductions in natural gas prices for emissions of CO2 from the US power sector.

    Science.gov (United States)

    Lu, Xi; Salovaara, Jackson; McElroy, Michael B

    2012-03-06

    CO(2) emissions from the US power sector decreased by 8.76% in 2009 relative to 2008 contributing to a decrease over this period of 6.59% in overall US emissions of greenhouse gases. An econometric model, tuned to data reported for regional generation of US electricity, is used to diagnose factors responsible for the 2009 decrease. More than half of the reduction is attributed to a shift from generation of power using coal to gas driven by a recent decrease in gas prices in response to the increase in production from shale. An important result of the model is that, when the cost differential for generation using gas rather than coal falls below 2-3 cents/kWh, less efficient coal fired plants are displaced by more efficient natural gas combined cycle (NGCC) generation alternatives. Costs for generation using NGCC decreased by close to 4 cents/kWh in 2009 relative to 2008 ensuring that generation of electricity using gas was competitive with coal in 2009 in contrast to the situation in 2008 when gas prices were much higher. A modest price on carbon could contribute to additional switching from coal to gas with further savings in CO(2) emissions.

  16. Globally significant greenhouse-gas emissions from African inland waters

    Science.gov (United States)

    Borges, Alberto V.; Bouillon, Steven

    2017-04-01

    The relevance of inland waters to global biogeochemical cycles is increasingly recognized, and of particular importance is their contribution of greenhouse gases to the atmosphere. The latter remain largely unreported in African inland waters. Here we report dissolved CO2, CH4 and N2O from 12 rivers in Sub-Saharan Africa acquired during >30 field expeditions and additional seasonally resolved sampling at >30 sites between 2006 and 2014. Fluxes were calculated from reported gas transfer velocity values, and upscaled using available spatial datasets, with an estimated uncertainty of about ±19%. CO2 equivalent emissions ( 0.4±0.1 PgC yr-1) match 2/3 of the overall net carbon sink previously reported for Africa. Including emissions from wetlands of the Congo, the putative total emission ( 0.9±0.1 PgC yr-1) is about half of the global oceanic or land carbon sinks. In-situ respiration supported <14% of riverine CO2 emissions, which must therefore largely be driven by mineralization in wetlands or uplands. Riverine CO2 and CH4 emissions were directly correlated to wetland coverage and aboveground vegetation biomass, implying that future changes in wetland and upland vegetation cover will strongly impact GHG emissions from African inland waters.

  17. 6.1 Greenhouse gas emissions and climate change

    International Nuclear Information System (INIS)

    2004-01-01

    In Austria, greenhouse gas emissions (GHG) have increased by about 10 % between 1990 and 2001. This means that already in 2001 the emissions reached the level projected with current measures for 2010. Thus Austria is far from complying with the 13 % reduction required under the Kyoto Protocol, meaning that GHG emissions will have to be reduce annually by 1.4 million tons of CO 2 -equivalents to fulfill its protocol obligation. It is shown that 2001 GHG emissions had increased by 9.6 % since the base year 1990, the main reason for this increase is the growing use of fossil fuels and the resulting increase in CO 2 emissions. The highest growth rates can be observed in the transport sector by almost half (+ 49 %). Basically, greenhouse gas emission trends depend on a number of factors, about two thirds of them are caused by energy production, so the most important parameters affecting GHG are the trends of energy consumption, the energy mix and the following factors: population growth, economic growth, outdoor temperature and the resulting heating requirements, improvement of energy efficiency, the proportion of renewable energy sources such as electricity generation in hydroelectric power stations (which influences the need for supplementary power production in thermal power plants), the mix of fossil fuels, for example in caloric power plants (natural gas combustion produces about 40 % less CO 2 per energy unit than coal combustion), the structure and price effects of energy market liberalization, which influence the use of various fuels in electricity production and the import of electricity, world market prices for energy, structural changes in the economy and in the behavior of consumers. Changes in important driving forces and in GHG emissions, sector emissions trends and Austrian, European and global emissions projections are provided. (nevyjel)

  18. DFT study of the reactions of Mo and Mo with CO2 in gas phase

    Indian Academy of Sciences (India)

    Abstract. Density functional theory (DFT) calculations have been performed to explore the potential energy surfaces of C–O bond activation in CO2 molecule by gas-phase Mo. + cation and Mo atom, in order to better understanding the mechanism of second-row metal reacting with CO2. The minimum energy reaction path is.

  19. Consequences of thermal fracture developments due to injection cold CO2 into depleted gas fields

    NARCIS (Netherlands)

    Peters, E.; Pizzocolo, F.; Loeve, D.; Fokker, P.A.; Hofstee, C.; Orlic, B.; Maas, J.G.

    2013-01-01

    CO2 storage is planned in a depleted gas field called P18, which is located offshore in the vicinity of the Dutch coast. This project is also known as the ROAD project, which is the Rotterdam capture and storage demonstration project. In the P18-4 compartment, cold CO2 will be injected into a

  20. Geochemical evaluation of CO2 injection and containment in a depleted gas field

    NARCIS (Netherlands)

    Tambach, T.J.; Koenen, M.; Wasch, L.J.; Bergen, F. van

    2015-01-01

    The short- and long-term geochemical impact of CO2 injection into a depleted gas reservoir (DGR) is investigated using reservoir/geochemical modeling with TOUGH2/TOUGHREACT and 1D kinetic diffusion modeling with PHREEQC (caprock/well-cement). Simulations of CO2 injection into the reservoir predict

  1. Analyzing the Effects of Car Sharing Services on the Reduction of Greenhouse Gas (GHG) Emissions

    OpenAIRE

    Jiyeon Jung; Yoonmo Koo

    2018-01-01

    This study examines the environmental impacts of roundtrip car sharing services by investigating transportation behavior. Car sharing should contribute to reduced greenhouse gas GHG emissions; however, such schemes include both positive and negative environmental effects, including: (1) reduced CO2e (carbon dioxide equivalent) from substituting private vehicle use for more fuel-efficient car sharing vehicles, (2) increased CO2e as car-less individuals switch from public transit to car sharing...

  2. Greenhouse gas emissions of hydropower in the Mekong River Basin

    Science.gov (United States)

    Räsänen, Timo A.; Varis, Olli; Scherer, Laura; Kummu, Matti

    2018-03-01

    The Mekong River Basin in Southeast Asia is undergoing extensive hydropower development, but the magnitudes of related greenhouse gas emissions (GHG) are not well known. We provide the first screening of GHG emissions of 141 existing and planned reservoirs in the basin, with a focus on atmospheric gross emissions through the reservoir water surface. The emissions were estimated using statistical models that are based on global emission measurements. The hydropower reservoirs (119) were found to have an emission range of 0.2-1994 kg CO2e MWh-1 over a 100 year lifetime with a median of 26 kg CO2e MWh-1. Hydropower reservoirs facilitating irrigation (22) had generally higher emissions reaching over 22 000 kg CO2e MWh-1. The emission fluxes for all reservoirs (141) had a range of 26-1813 000 t CO2e yr-1 over a 100 year lifetime with a median of 28 000 t CO2e yr-1. Altogether, 82% of hydropower reservoirs (119) and 45% of reservoirs also facilitating irrigation (22) have emissions comparable to other renewable energy sources (380 kg CO2e MWh-1). These results are tentative and they suggest that hydropower in the Mekong Region cannot be considered categorically as low-emission energy. Instead, the GHG emissions of hydropower should be carefully considered case-by-case together with the other impacts on the natural and social environment.

  3. Greenhouse-gas-trading markets.

    Science.gov (United States)

    Sandor, Richard; Walsh, Michael; Marques, Rafael

    2002-08-15

    This paper summarizes the extension of new market mechanisms for environmental services, explains of the importance of generating price information indicative of the cost of mitigating greenhouse gases (GHGs) and presents the rationale and objectives for pilot GHG-trading markets. It also describes the steps being taken to define and launch pilot carbon markets in North America and Europe and reviews the key issues related to incorporating carbon sequestration into an emissions-trading market. There is an emerging consensus to employ market mechanisms to help address the threat of human-induced climate changes. Carbon-trading markets are now in development around the world. A UK market is set to launch in 2002, and the European Commission has called for a 2005 launch of an European Union (EU)-wide market, and a voluntary carbon market is now in formation in North America. These markets represent an initial step in resolving a fundamental problem in defining and implementing appropriate policy actions to address climate change. Policymakers currently suffer from two major information gaps: the economic value of potential damages arising from climate changes are highly uncertain, and there is a lack of reliable information on the cost of mitigating GHGs. These twin gaps significantly reduce the quality of the climate policy debate. The Chicago Climate Exchange, for which the authors serve as lead designers, is intended to provide an organized carbon-trading market involving energy, industry and carbon sequestration in forests and farms. Trading among these diverse sectors will provide price discovery that will help clarify the cost of combating climate change when a wide range of mitigation options is employed. By closing the information gap on mitigation costs, society and policymakers will be far better prepared to identify and implement optimal policies for managing the risks associated with climate change. Establishment of practical experience in providing

  4. Computational investigation of thermal gas separation for CO2 capture.

    Energy Technology Data Exchange (ETDEWEB)

    Gallis, Michail A.; Bryan, Charles R.; Brady, Patrick Vane; Torczynski, John Robert; Brooks, Carlton, F.

    2009-09-01

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 09-1351, 'Computational Investigation of Thermal Gas Separation for CO{sub 2} Capture'. Thermal gas separation for a binary mixture of carbon dioxide and nitrogen is investigated using the Direct Simulation Monte Carlo (DSMC) method of molecular gas dynamics. Molecular models for nitrogen and carbon dioxide are developed, implemented, compared to theoretical results, and compared to several experimental thermophysical properties. The molecular models include three translational modes, two fully excited rotational modes, and vibrational modes, whose degree of excitation depends on the temperature. Nitrogen has one vibrational mode, and carbon dioxide has four vibrational modes (two of which are degenerate). These models are used to perform a parameter study for mixtures of carbon dioxide and nitrogen confined between parallel walls over realistic ranges of gas temperatures and nominal concentrations of carbon dioxide. The degree of thermal separation predicted by DSMC is slightly higher than experimental values and is sensitive to the details of the molecular models.

  5. The U.S. Gas Flooding Experience: CO2 Injection Strategies and Impact on Ultimate Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Nunez-Lopez, Vanessa [The University of Texas at Austin; Hosseini, Seyyed; Gil-Egui, Ramon

    2017-09-29

    The Permian Basin in West Texas and southwestern New Mexico has seen 45 years of oil reserve growth through CO2 enhanced oil recovery (CO2 EOR). More than 60 CO2 EOR projects are currently active in the region’s limestone, sandstone and dolomite reservoirs. Water alternating gas (WAG) has been the development strategy of choice in the Permian for several technical and economic reasons. More recently, the technology started to get implemented in the much more porous and permeable clastic depositional systems of the onshore U.S. Gulf Coast. Continued CO2 injection (CGI), as opposed to WAG, was selected as the injection strategy to develop Gulf Coast oil fields, where CO2 injection volumes are significantly larger (up to 6 times larger) than those of the Permian. We conducted a compositional simulation based study with the objective of comparing the CO2 utilization ratios (volume of CO2 injected to produce a barrel of oil) of 4 conventional and novel CO2 injection strategies: (1) continuous gas injection (CGI), (2) water alternating gas (WAG), (3) water curtain injection (WCI), and (4) WAG and WCI combination. These injection scenarios were simulated using the GEM module from the Computer Modeling Group (CMG). GEM is an advanced general equation-of-state compositional simulator, which includes equation of state, CO2 miscible flood, CO2/brine interactions, and complex phase behavior. The simulator is set up to model three fluid phases including water, oil, and gas. Our study demonstrates how the selected field development strategy has a significant impact on the ultimate recovery of CO2-EOR projects, with GCI injection providing maximum oil recovery in absolute volume terms, but with WAG offering a more balanced technical-economical approach.

  6. Accounting For Greenhouse Gas Emissions From Flooded Lands

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a method...

  7. CO2 emission costs and Gas/Coal competition for power production

    International Nuclear Information System (INIS)

    Santi, Federico

    2005-01-01

    This paper demonstrates how a CO 2 emission reduction programme can change the competition between the two power production technologies which will probably dominate the future of the Italian power industry: the coal fired USC steam power plant and the natural gas fired CCGT power plant. An economic value of the CO 2 emission is calculated, in order to make the short-run-marginal-cost (or the long-run-marginal-cost). equal for both technologies, under a CO 2 emission trading scheme and following a single-plant specific CO 2 emission homogenizing approach [it

  8. Predicting gas decomposition in an industrialized pulsed CO2 laser

    CSIR Research Space (South Africa)

    Forbes, A

    2005-03-01

    Full Text Available , and then test this against experimental data. This is because rate laws must be determined from measurements of reaction rates, and cannot be deduced from reaction stoichiometry. The reader is refered to standard physical chemistry texts5 for further... if kd is not gas species dependent. 3. CATALYSTS PRESENT With catalysts present in the laser, the oxygen concentration stabilise quickly and at lower levels than in the case of no catalysts. Using the model already found for the discharge chemistry...

  9. Gas solubility of H2S and CO2 in aqueous solutions of N-methyldiethanolamine

    NARCIS (Netherlands)

    Huttenhuis, P.J.G.; Agrawal, N.J.; Hogendoorn, Kees; Versteeg, Geert

    2007-01-01

    Alkanolamine processes are used in the industry to remove acid gases, like CO2, H2S and other sulphur components, from natural gas and industrial gas streams. In this process the acid components react with the basic alkanolamine solution via an exothermic, reversible reaction in a gas/liquid

  10. Enceladus' near-surface CO2 gas pockets and surface frost deposits

    Science.gov (United States)

    Matson, Dennis L.; Davies, Ashley Gerard; Johnson, Torrence V.; Combe, Jean-Philippe; McCord, Thomas B.; Radebaugh, Jani; Singh, Sandeep

    2018-03-01

    Solid CO2 surface deposits were reported in Enceladus' South Polar Region by Brown et al. (2006). They noted that such volatile deposits are temporary and posited ongoing replenishment. We present a model for this replenishment by expanding on the Matson et al. (2012) model of subsurface heat and chemical transport in Enceladus. Our model explains the distributions of both CO2 frost and complexed CO2 clathrate hydrate as seen in the Cassini Visual and Infrared Mapping Spectrometer (VIMS) data. We trace the journey of CO2 from a subsurface ocean. The ocean-water circulation model of Matson et al. (2012) brings water up to near the surface where gas exsolves to form bubbles. Some of the CO2 bubbles are trapped and form pockets of gas in recesses at the bottom of the uppermost ice layer. When fissures break open these pockets, the CO2 gas is vented. Gas pocket venting is episodic compared to the more or less continuous eruptive plumes, emanating from the "tiger stripes", that are supported by plume chambers. Two styles of gas pocket venting are considered: (1) seeps, and (2) blowouts. The presence of CO2 frost patches suggests that the pocket gas slowly seeped through fractured, cold ice and when some of the gas reached the surface it was cold enough to condense (i.e., T ∼70 to ∼119 K). If the fissure opening is large, a blowout occurs. The rapid escape of gas and drop in pocket pressure causes water in the pocket to boil and create many small aerosol droplets of seawater. These may be carried along by the erupting gas. Electrically charged droplets can couple to the magnetosphere, and be dragged away from Enceladus. Most of the CO2 blowout gas escapes from Enceladus and the remainder is distributed globally. However, CO2 trapped in a clathrate structure does not escape. It is much heavier and slower moving than the CO2 gas. Its motion is ballistic and has an average range of about 17 km. Thus, it contributes to deposits in the vicinity of the vent. Local heat

  11. Greenhouse gas emissions from septic systems in New York State

    Science.gov (United States)

    Truhlar, A. M.; Rahm, B. G.; Brooks, R. A.; Nadeau, S. A.; Walter, M. T.

    2015-12-01

    Onsite septic systems are a practical way to treat wastewater in rural or less-densely populated areas. Septic systems utilize microbial processes to eliminate organic wastes and nutrients such as nitrogen; these processes can contribute to air pollution through the release of greenhouse gases (GHGs). At each of nine septic systems, we measured fluxes of CH4, CO2, and N2O from the soil over the leach field and sand filter, and from the roof outlet vent. These are the most likely locations for gas emissions during normal operation of the septic system. The majority of all septic system gas emissions were released from the roof vent. However, our comparisons of the gas fluxes from these locations suggest that biological processes in the soil, especially the soil over the leach field, can influence the type and quantity of gas that is released from the system. The total vent, sand filter, and leach field GHG emissions were 0.12, 0.045, and 0.046 tonne CO2e capita-1 year-1, respectively. In total, this represents about 1.5% of the annual carbon footprint of an individual living in the US.

  12. Continuous greenhouse gas measurements from ice cores

    DEFF Research Database (Denmark)

    Stowasser, Christopher

    Ice cores offer the unique possibility to study the history of past atmospheric greenhouse gases over the last 800,000 years, since past atmospheric air is trapped in bubbles in the ice. Since the 1950s, paleo-scientists have developed a variety of techniques to extract the trapped air from...... individual ice core samples, and to measure the mixing ratio of greenhouse gases such as carbon dioxide, methane and nitrous oxide in the extracted air. The discrete measurements have become highly accurate and reproducible, but require relatively large amounts of ice per measured species and are both time......-consuming and labor-intensive. This PhD thesis presents the development of a new method for measurements of greenhouse gas mixing ratios from ice cores based on a melting device of a continuous flow analysis (CFA) system. The coupling to a CFA melting device enables time-efficient measurements of high resolution...

  13. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    Energy Technology Data Exchange (ETDEWEB)

    Eric P. Robertson

    2007-09-01

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  14. Photocatalytic Reduction of CO2 from Simulated Flue Gas with Colored Anatase

    Directory of Open Access Journals (Sweden)

    Yebin Guan

    2018-02-01

    Full Text Available Photocatalytic reduction with sunlight is an economical and promising advanced approach for reducing the excessive emissions of CO2 from the combustion of fossil fuels. Aimed at practical applications, a type of inexpensive colored anatase material was used to evaluate CO2 photoreduction performance on a platform with a continuous flow of gas mixtures (10 vol % CO2, 90% N2, which resembles realistic flue gas conditions. The results showed an enhanced photocatalytic activity compared with standard P25 and significant improvement over pristine anatase. Based on a series of characterization techniques, we propose that the oxygen vacancies and surface hydroxyl groups on colored anatase can reduce the bandgap and assist the binding of CO2 molecules. Our results showed that photoreduction of CO2 is feasible under practical conditions, and the efficiency could be improved through modification of catalysts.

  15. Greenhouse gas emissions from domestic hot water: heat pumps compared to most commonly used systems

    OpenAIRE

    Hong, Bongghi; Howarth, Robert

    2017-01-01

    We estimate the emissions of the two most important greenhouse gasses (GHG), carbon dioxide (CO2) and methane (CH4), from the use of modern high-efficiency heat pump water heaters compared to the most commonly used domestic hot water systems: natural gas storage tanks, tankless natural gas demand heaters, electric resistance storage tanks, and tankless electric resistance heaters. We considered both natural gas-powered electric plants and coal-powered plants as the source of the electricity f...

  16. Growth response of Spirulina platensis PCC9108 to elevated CO2 levels and flue gas

    Directory of Open Access Journals (Sweden)

    Seyedmahdi Hoseini

    2014-01-01

    Full Text Available Introduction: Because their ability to capture CO2, photosynthetical microorganisms have some advantages to CO2 mitigation from high CO2 streams such as flue gases and they can use CO2 as carbon source. Recently, experts have made efforts to exploit microorganisms intended for recovering CO2 from power plants. Materials and methods: To achieve this purpose, we studied the growth response of the cyanobacterium Spirulina platensis PCC9108 under different concentrations of carbon dioxide (ranging from 0.036% to 10% and flue gas in a bench-scale system. Preparation of different concentrations of CO2 and injection into Erlenmeyer flasks was performed by a system including air compressor, CO2 capsule, pressure gauge and flow meter. Results: The main goal of studying this paper is a survey of organism's potential to grow by generated CO2 from flue gas of power plant. It already had the potential and highest biomass production recorded at 8% CO2 (v/v. Also we proved that S.platensis PCC9108 can be grown under flue gas, although biomass production decreased fairly. Total lipid content of algae interestingly enhanced with elevated CO2 levels from ambient air to 4% and 6% which ranged from 14.5 to 15.8 and 16 dry weight (wt. % respectively. In contrast, total protein content illustrated no difference between all treatment and its value was about 46 wt.%. Discussion and conclusion: The results of present study suggested that understudied S.platensis PCC9108 is appropriate for mitigating CO2 because of its carbon fixation ability. Also due to its high protein content, this cyanobacterium is a good candidate to produce SCP (single cell protein.

  17. Greenhouse-gas emissions from biomass energy use: Comparison with other energy technologies

    International Nuclear Information System (INIS)

    Morris, G.P.; Norman, N.A.; Gleick, P.H.

    1991-01-01

    Recently a major new concern has arisen: the accumulation of greenhouse gases in the atmosphere. It is now generally believed that continued emissions of these gases are current or increasing levels will lead to significant climatic changes with the potential for dramatic, adverse impacts. Since the major anthropogenic source of greenhouse gas emissions is energy production and use, it is essential to future energy policy to understand how energy sources differ with respect to greenhouse gas emissions. Characterizing the greenhouse gas emissions associated with biomass energy use is extremely complicated. It is necessary to consider both the source and alternative use of the biomass material and its alternative disposal (if any), as well as the biomass energy application itself. It is desirable also to consider not just CO 2 emissions, but also CH 4 and N 2 O, both potent greenhouse gases. The authors' analysis shows that in many cases biomass energy use can actually help to ameliorate the greenhouse effect by converting emissions that would have been CH 4 into the less potent greenhouse gas CO 2 . In many cases the beneficial effect is very dramatic. This major new research result should help increase public support for biomass research and development, and for further development of waste conversion technology and installations

  18. Warming effects on greenhouse gas fluxes in peatlands are modulated by vegetation composition.

    Science.gov (United States)

    Ward, Susan E; Ostle, Nicholas J; Oakley, Simon; Quirk, Helen; Henrys, Peter A; Bardgett, Richard D

    2013-10-01

    Understanding the effects of warming on greenhouse gas feedbacks to climate change represents a major global challenge. Most research has focused on direct effects of warming, without considering how concurrent changes in plant communities may alter such effects. Here, we combined vegetation manipulations with warming to investigate their interactive effects on greenhouse gas emissions from peatland. We found that although warming consistently increased respiration, the effect on net ecosystem CO2 exchange depended on vegetation composition. The greatest increase in CO2 sink strength after warming was when shrubs were present, and the greatest decrease when graminoids were present. CH4 was more strongly controlled by vegetation composition than by warming, with largest emissions from graminoid communities. Our results show that plant community composition is a significant modulator of greenhouse gas emissions and their response to warming, and suggest that vegetation change could alter peatland carbon sink strength under future climate change. © 2013 John Wiley & Sons Ltd/CNRS.

  19. Portuguese agriculture and the evolution of greenhouse gas emissions-can vegetables control livestock emissions?

    Science.gov (United States)

    Mourao, Paulo Reis; Domingues Martinho, Vítor

    2017-07-01

    One of the most serious externalities of agricultural activity relates to greenhouse gas emissions. This work tests this relationship for the Portuguese case by examining data compiled since 1961. Employing cointegration techniques and vector error correction models (VECMs), we conclude that the evolution of the most representative vegetables and fruits in Portuguese production are associated with higher controls on the evolution of greenhouse gas emissions. Reversely, the evolution of the output levels of livestock and the most representative animal production have significantly increased the level of CO 2 (carbon dioxide) reported in Portugal. We also analyze the cycle length of the long-term relationship between agricultural activity and greenhouse gas emissions. In particular, we highlight the case of synthetic fertilizers, whose values of CO 2 have quickly risen due to changes in Portuguese vegetables, fruit, and animal production levels.

  20. Impact of stream geomorphology on greenhouse gas concentration in a New York mountain stream

    Science.gov (United States)

    Philippe Vidon; Satish Serchan

    2016-01-01

    As increased greenhouse gas concentrations (GHG: N2O, CO2, CH4) in our atmosphere remain a major concern, better quantifying GHG fluxes from natural systems is essential. In this study, we investigate GHG concentrations in saturated riparian sediments (dry, wet, mucky), streambed hyporheic zone...

  1. Influence of urban infrastructure on water quality and greenhouse gas dynamics in streams

    Science.gov (United States)

    Streams and rivers are significant sources of nitrous oxide (N2O), carbon dioxide (CO2), and methane (CH4), and watershed management can alter greenhouse gas emissions from streams. GHG emissions from streams in agricultural watersheds have been investigated in numerous studies,...

  2. Greenhouse gas emissions from willow-based electricity: a scenario analysis for Portugal and The Netherlands

    NARCIS (Netherlands)

    Rebelo de Mira, R.; Kroeze, C.

    2006-01-01

    This study focuses on greenhouse gas emissions from power plants using willow as fuel compared to those using fossil fuels. More specifically, we quantify emissions of nitrous oxide (N2O) from soils on which willow is grown, and compare these to emissions of carbon dioxide (CO2) from fossil

  3. Software for evaluating greenhouse gas emissions and the carbon footprint of dairy production systems

    Science.gov (United States)

    Abstract: Dairy production, along with all other types of animal agriculture, is a recognized source of greenhouse gas (GHG) emissions, but little information exists on the net emissions from our farms. Component models for representing all important sources and sinks of CH4, N2O, and CO2 in dairy p...

  4. Total greenhouse gas emissions related to the Dutch crop production system

    NARCIS (Netherlands)

    Kramer, K.J.; Moll, H.C.; Nonhebel, S.

    1999-01-01

    This article discusses the greenhouse gas emissions (CO2, CH4, N2O) related to Dutch agricultural crop production. Emissions occur during agricultural processes (direct emissions) as well as in the life cycle of the required inputs (indirect emissions). An integrated approach assesses the total

  5. Mitigation of greenhouse gas emissions from reed canary grass in paludiculture: effect of groundwater level

    DEFF Research Database (Denmark)

    Karki, Sandhya; Elsgaard, Lars; Audet, Joachim

    2014-01-01

    Background and aims Combination of rewetting and wetland crop cultivation (paludiculture) is pursued as a wider carbon dioxide (CO2) mitigation option in drained peatland. However, information on the overall greenhouse gas (GHG) balance for paludiculture is lacking. We investigated the GHG balance...

  6. Effect of condensed tannins on forage nutritive value and greenhouse gas output of an orchardgrass diet

    Science.gov (United States)

    Greenhouse gas (GHG) emissions from livestock account for 43%, 29%, and 27% of CH4, N2O and CO2, respectively, of global GHG emissions from livestock. Legumes containing condensed tannins (CT) have been shown to decrease enteric CH4 in ruminants; however, research is lacking on how increased CT leve...

  7. A life cycle greenhouse gas inventory of a tree production system

    Science.gov (United States)

    Alissa Kendall; E. Gregory McPherson

    2012-01-01

    PurposeThis study provides a detailed, process-based life cycle greenhouse gas (GHG) inventory of an ornamental tree production system for urban forestry. The success of large-scale tree planting initiatives for climate protection depends on projects being net sinks for CO2 over their entire life cycle....

  8. Application of Factorial Design for Gas Parameter Optimization in CO2 Laser Welding

    DEFF Research Database (Denmark)

    Gong, Hui; Dragsted, Birgitte; Olsen, Flemming Ove

    1997-01-01

    The effect of different gas process parameters involved in CO2 laser welding has been studied by applying two-set of three-level complete factorial designs. In this work 5 gas parameters, gas type, gas flow rate, gas blowing angle, gas nozzle diameter, gas blowing point-offset, are optimized...... to be a very useful tool for parameter optimi-zation in laser welding process. Keywords: CO2 laser welding, gas parameters, factorial design, Analysis of Variance........ The bead-on-plate welding specimens are evaluated by a number of quality char-acteristics, such as the penetration depth and the seam width. The significance of the gas pa-rameters and their interactions are based on the data found by the Analysis of Variance-ANOVA. This statistic methodology is proven...

  9. Biomimetic Membrane for CO2 Capture from Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Michael C. Trachtenberg

    2007-05-31

    These Phase III experiments successfully addressed several issues needed to characterize a permeator system for application to a pulverized coal (PC) burning furnace/boiler assuming typical post-combustion cleanup devices in place. We completed key laboratory stage optimization and modeling efforts needed to move towards larger scale testing. The SOPO addressed six areas. Task 1--Post-Combustion Particle Cleanup--The first object was to determine if the Carbozyme permeator performance was likely to be reduced by particles (materials) in the flue gas stream that would either obstruct the mouth of the hollow fibers (HF) or stick to the HF bore wall surface. The second, based on the Acceptance Standards (see below), was to determine whether it would be preferable to clean the inlet gas stream (removing acid gases and particulates) or to develop methods to clean the Carbozyme permeator if performance declined due to HF block. We concluded that condensation of particle and particulate emissions, in the heat exchanger, could result in the formation of very sticky sulfate aerosols with a strong likelihood of obtruding the HF. These must be managed carefully and minimized to near-zero status before entering the permeator inlet stream. More extensive post-combustion cleanup is expected to be a necessary expense, independent of CO{sub 2} capture technology This finding is in agreement with views now emerging in the literature for a variety of CO{sub 2} capture methods. Task 2--Water Condensation--The key goal was to monitor and control temperature distributions within the permeator and between the permeator and its surroundings to determine whether water condensation in the pores or the HF bore would block flow, decreasing performance. A heat transfer fluid and delivery system were developed and employed. The result was near isothermal performance that avoided all instances of flow block. Direct thermocouple measurements provided the basis for developing a heat transfer

  10. Influence of Meteorology and interrelationship with greenhouse gases (CO2 and CH4 at a suburban site of India

    Directory of Open Access Journals (Sweden)

    G. Sreenivas

    2016-03-01

    Full Text Available Atmospheric greenhouse gases (GHGs, such as carbon dioxide (CO2 and methane (CH4, are important climate forcing agents due to their significant impacts on the climate system. The present study brings out first continuous measurements of atmospheric GHGs using high-precision LGR-GGA over Shadnagar, a suburban site of Central India during the year 2014. The annual mean CO2 and CH4 over the study region are found to be 394 ± 2.92 and 1.92 ± 0.07 ppm (μ ± 1σ respectively. CO2 and CH4 show a significant seasonal variation during the study period with maximum (minimum CO2 observed during pre-monsoon (monsoon, while CH4 recorded the maximum during post-monsoon and minimum during monsoon. Irrespective of the seasons, consistent diurnal variations of these gases are observed. Influences of prevailing meteorology (air temperature, wind speed, wind direction, and relative humidity on GHGs have also been investigated. CO2 and CH4 show a strong positive correlation during winter, pre-monsoon, monsoon, and post-monsoon with correlation coefficients (Rs equal to 0.80, 0.80, 0.61, and 0.72 respectively, indicating a common anthropogenic source for these gases. Analysis of this study reveals the major sources for CO2 are soil respiration and anthropogenic emissions while vegetation acts as a main sink, whereas the major source and sink for CH4 are vegetation and presence of hydroxyl (OH radicals.

  11. More Gas, Less Coal, and Less CO2?

    DEFF Research Database (Denmark)

    Daubanes, Julien Xavier; Henriet, Fanny; Schubert, Katheline

    We examine an open economy’s strategy to reduce its carbon emissions by replacing its consumption of coal—very carbon intensive—with gas—less so. Unlike the standard analysis of carbon leakage, unilateral carbon-reduction policies with more than one carbon energy source may turn counter......-productive, ultimately increasing world emissions. Thus, we establish testable conditions as to whether a governmental emission-reduction commitment warrants the exploitation of gas, and whether such a strategy increases global emissions. We also characterize the extent to which this unilateral policy makes the rest...... of the world’s emission commitments more difficult to meet. Finally, we apply our results to the case of the US....

  12. Sectoral Approaches to Greenhouse Gas Mitigation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    This paper explores sectoral approaches as a new set of options to enhance the effectiveness of greenhouse gas reduction policies and to engage emerging economies on a lower emission path. It surveys existing literature and recent policy trends in international climate change discussions, and provides an overview of sectoral approaches and related issues for trade-exposed, greenhouse-gas intensive industries (cement, iron and steel and aluminium). It is also based on interviews conducted by the IEA Secretariat in Australia, China, Europe, Japan, and the United States. Sectoral approaches were also discussed during workshops on technology and energy efficiency policies in industry, following the IEA's mandate under the Gleneagles Plan of Action.

  13. On greenhouse gas signal detection strategies

    International Nuclear Information System (INIS)

    Barnett, T.P.; Schlesinger, M.E.; Xingjian Jiang

    1990-01-01

    Important elements of a greenhouse gas signal detection strategy are discussed and demonstrated with both model and observed data. The analysis also demonstrates the high level of unexplained interdecadal variability that occurs naturally in the climate system and how this noise will greatly complicate any detection strategy. The indisputable detection of a greenhouse gas signal in the global climate system will be a true decision point for mankind. Yet, at this stage of knowledge, the details of an appropriate detection strategy are only beginning to be developed. Two key elements in the eventual strategy are the subject of this report: (1) what variables should be monitored in a detection program, and (2) the comparison of the equilibrium versus transient climate system response. Subsequent sections consider these items in turn, while a final section summarizes the main conclusion of the study

  14. Cogeneration, renewables and reducing greenhouse gas emissions

    International Nuclear Information System (INIS)

    Naughten, B.; Dlugosz, J.

    1996-01-01

    The MENSA model is used to assess the potential role of cogeneration and selected new renewable energy technologies in cost-effectively reducing Greenhouse gas emissions. The model framework for analyzing these issues is introduced, together with an account of relevant aspects of its application. In the discussion of selected new renewable energy technologies, it is shown how microeconomic reform may encourage these technologies and fuels, and thereby reduce sector wide carbon dioxide emissions. Policy scenarios modelled are described and the simulation results are presented. Certain interventions in microeconomic reform may result in economic benefits while also reducing emissions: no regrets' opportunities. Some renewable energy technologies are also shown to be cost-effective in the event that targets and timetables for reducing Greenhouse gas emissions are imposed. However, ad hoc interventions in support of particular renewables options are unlikely to be consistent with a least cost approach to achieving environmental objectives. (author). 5 tabs., 5 figs., 21 refs

  15. Energy budget and greenhouse gas balance evaluation of sustainable coppice systems for electricity production

    International Nuclear Information System (INIS)

    Lettens, Suzanna; Muys, Bart; Ceulemans, Reinhart; Moons, Ellen; Garcia, Juan; Coppin, Pol

    2003-01-01

    The use of bio-energy crops for electricity production is considered an effective means to mitigate the greenhouse effect, mainly due to its ability to substitute fossil fuels. A whole range of crops qualify for bio-energy production and a rational choice is not readily made. This paper evaluates the energy and greenhouse gas balance of a mixed indigenous hardwood coppice as an extensive, low-input bio-energy crop. The impact on fossil energy use and greenhouse gas emission is calculated and discussed by comparing its life cycle (cultivation, processing and conversion into energy) with two conventional bio-energy crops (short rotation systems of willow and Miscanthus). For each life cycle process, the flows of fossil energy and greenhouse gas that are created for the production of one functional unit are calculated. The results show that low-input bio-energy crops use comparatively less fossil fuel and avoid more greenhouse gas emission per unit of produced energy than conventional bio-energy crops during the first 100 yr. Where the mixed coppice system avoids up till 0.13 t CO 2 eq./GJ, Miscanthus does not exceed 0.07 t CO 2 eq./GJ. After 100 yr their performances become comparable, amounting to 0.05 t CO 2 eq./ha/GJ. However, if the land surface itself is chosen as a functional unit, conventional crops perform better with respect to mitigating the greenhouse effect. Miscanthus avoids a maximum of 12.9 t CO 2 eq./ha/yr, while mixed coppice attains 9.5 t CO 2 eq./ha/yr at the most

  16. Greenhouse gas emissions - a global challenge

    International Nuclear Information System (INIS)

    Aarebrot, Eivind; Langvik, Sveinung

    2000-01-01

    The article describes some greenhouse gas emission challenges in the Norwegian petroleum industry. Some of the conclusions are that the national taxation policies are insufficient and that international co-operation is essential in order to obtain significant pollution abatement. The mechanisms for this are not yet in place. Some possible measures are mentioned. The main solution to the problems internationally seems to be international co-operation projects generally with quota trade in order to meet the Kyoto agreement obligations

  17. Are optimal CO2 emissions really optimal? Four critical issues for economists in the greenhouse

    International Nuclear Information System (INIS)

    Azar, C.

    1998-01-01

    Although the greenhouse effect is by many considered as one of the most serious environmental problems, several economic studies of the greenhouse effect, most notably Nordhaus's DICE model, suggest that it is optimal to allow the emissions of greenhouse gases (GHG) to increase by a factor of three over the next century. Other studies have found that substantial reductions can be justified on economic grounds. This paper explores into the reasons for these differences and identifies four (partly overlapping) crucial issues that have to be dealt with when analysing the economics of the greenhouse effect low-probability but catastrophic events; cost evaluation methods; the choice of discount rate; the choice of decision criterion. The paper shows that (1) these aspects are crucial for the policy conclusions drawn from models of the economics of climate change, and that (2) ethical choices have to be made for each of these issues. This fact needs wider recognition since economics is very often perceived as a value neutral tool that can be used to provide policy makers with 'optimal' policies. 62 refs

  18. Effects of CO2 concentration on photosynthesis, transpiration and production of greenhouse fruit vegetable crops

    NARCIS (Netherlands)

    Nederhoff, E.M.

    1994-01-01

    The effect of the C0 2 concentration of the greenhouse air (C) in the range 200 to 1100 μmol mol -1was investigated in tomato ( Lycopersicon esculentum Mill.), cucumber ( Cucumis sativus L.), sweet

  19. Multi Wavelength Greenhouse gas LIDAR (MUGGLE), Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Climate change is a growing concern, leading NASA to the need to track concentrations of such greenhouse gases as CO2 and CH4, including the need to detect them...

  20. Comparison of soil greenhouse gas fluxes from extensive and intensive grazing in a temperate maritime climate

    Science.gov (United States)

    Skiba, U.; Jones, S. K.; Drewer, J.; Helfter, C.; Anderson, M.; Dinsmore, K.; McKenzie, R.; Nemitz, E.; Sutton, M. A.

    2013-02-01

    Greenhouse gas (GHG) fluxes from a seminatural, extensively sheep-grazed drained moorland and intensively sheep-grazed fertilised grassland in South East (SE) Scotland were compared over 4 yr (2007-2010). Nitrous oxide (N2O) and methane (CH4) fluxes were measured by static chambers, respiration from soil plus ground vegetation by a flow-through chamber, and the net ecosystem exchange (NEE) of carbon dioxide (CO2) by eddy-covariance. All GHG fluxes displayed high temporal and interannual variability. Temperature, radiation, water table height and precipitation could explain a significant percentage of seasonal and interannual variations. Greenhouse gas fluxes were dominated by the net ecosystem exchange of CO2 at both sites. Net ecosystem exchange of CO2 and respiration was much larger on the productive fertilised grassland (-1567 and 7157 g CO2eq m-2 yr-1, respectively) than on the seminatural moorland (-267 and 2554 g CO2eq m-2 yr-1, respectively). Large ruminant CH4 (147 g CO2eq m-2 yr-1) and soil N2O (384 g CO2eq m-2 yr-1) losses from the grazed grassland counteracted the CO2 uptake by 34%, whereas the small N2O (0.8 g CO2eq m-2 yr-1) and CH4 (7 g CO2eq m-2 yr-1) emissions from the moorland only impacted the NEE flux by 3%. The 4-yr average GHG budget for the grazed grassland was -1034 g CO2eq m-2 yr-1 and -260 g CO2eq m-2 yr-1 for the moorland.

  1. Accounting for Greenhouse Gas Emissions from Reservoirs ...

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used as a ‘basis for future methodological development’ due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. In the U.S., research approaches include: 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane em

  2. Accounting For Greenhouse Gas Emissions From Flooded ...

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used a ‘basis for future methodological development’ due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. The research approaches include 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane emissions. To inform th

  3. Greenhouse Gas Management Program Overview (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2011-11-01

    Program fact sheet highlighting federal requirements for GHG emissions management, FEMP services to help agencies reduce emissions, and additional resources. The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) assists Federal agencies with managing their greenhouse gas (GHG) emissions. GHG management entails measuring emissions and understanding their sources, setting a goal for reducing emissions, developing a plan to meet this goal, and implementing the plan to achieve reductions in emissions. FEMP provides the following services to help Federal agencies meet the requirements of inventorying and reducing their GHG emissions: (1) FEMP offers one-on-one technical assistance to help agencies understand and implement the Federal Greenhouse Gas Accounting and Reporting Guidance and fulfill their inventory reporting requirements. (2) FEMP provides training, tools, and resources on FedCenter to help agencies complete their annual inventories. (3) FEMP serves a leadership role in the interagency Federal Working Group on Greenhouse Gas Accounting and Reporting that develops recommendations to the Council on Environmental Quality (CEQ) for the Federal Greenhouse Gas Accounting and Reporting Guidance. (4) As the focus continues to shift from measuring emissions (completing inventories) to mitigating emissions (achieving reductions), FEMP is developing a strategic planning framework and resources for agencies to prioritize among a variety of options for mitigating their GHG emissions, so that they achieve their reduction goals in the most cost-effective manner. These resources will help agencies analyze their high-quality inventories to make strategic decisions about where to use limited resources to have the greatest impact on reducing emissions. Greenhouse gases trap heat in the lower atmosphere, warming the earth's surface temperature in a natural process known as the 'greenhouse effect.' GHGs include carbon dioxide (CO{sub 2

  4. An experimental evaluation of the greenhouse effect in the substitution of R134a with CO2

    International Nuclear Information System (INIS)

    Aprea, C.; Greco, A.; Maiorino, A.

    2012-01-01

    This paper addresses the problem of R314a substitution with a natural refrigerant fluid. Attention is devoted to the evaluation of the environmental impact, in terms of greenhouse effect. R134a and R744 (CO 2 ) are compared to one another. The hydrofluorocarbon R134a has a large direct warming impact (GWP), whereas the R744 contribution is negligible. The greenhouse effect is determined by the experimental evaluation of the TEWI index (Total Equivalent Warming Impact) that takes into account both direct and indirect contributions to global warming. This paper compares a commercial R134a refrigeration plant and a prototype R744 system working in a trans-critical cycle. The experimental results clearly show that the latter has a larger TEWI than the system operating with R134a. The indirect contribution to global warming provided by R744 is always greater than that of R134a. This contribution prevails in most cases. Only few operating conditions corresponding to a refrigerating plant working as a classical split system benefits, in terms of greenhouse effect, of the substitution of R134a with R744. -- Highlights: ► A comparison between a classical vapour compression plant and a trans-critical cycle. ► Evaluation of the greenhouse effect in R134a substitution with R744. ► Evaluation of direct and indirect contribution to global warming. ► Minimization of the global warming impact of a R744 transcritical cycle.

  5. Evaluation of greenhouse gas emissions from waste management approaches in the islands.

    Science.gov (United States)

    Chen, Ying-Chu

    2017-07-01

    Concerns about waste generation and climate change have attracted worldwide attention. Small islands, which account for more than one-sixth of the global land area, are facing problems caused by global climate change. This study evaluated the greenhouse gas emissions from five small islands surrounding Taiwan. These islands - Penghu County, Liuqui Island, Kinmen County, Matsu Island and Green Island - have their own waste management approaches that can serve as a guideline for waste management with greenhouse gas mitigation. The findings indicate that the total annual greenhouse gas emissions of the islands ranged from 292.1 to 29,096.2 [metric] tonne CO 2 -equivalent. The loading waste volumes and shipping distances were positively related to greenhouse gas emissions from transportation. The greenhouse gas emissions from waste-to-energy plants, mainly carbon dioxide and nitrous oxide, can be offset by energy recovery (approximately 38.6% of greenhouse gas emissions from incineration). In addition, about 34% and 11% of waste generated on the islands was successfully recycled and composted, respectively. This study provides valuable insights into the applicability of a policy framework for waste management approaches for greenhouse gas mitigation.

  6. National plans for reducing greenhouse gas emissions in the Republic of Korea

    International Nuclear Information System (INIS)

    Ki Dong Song

    1996-01-01

    The present and future Korean emission of greenhouse gases are discussed in view of the current status of and projections of the national energy consumption under fast economic growth. Present dependence on energy import is very high (94.7%) and will only marginally decrease after a maximum of 97.1% in 2010 to 95.1% in 2030 due to increased use of renewables. The annual CO 2 emissions will be three times higher in 2030 and amount to almost 200 Mtonnes. The national CO 2 /energy intensity will decrease from 0.75 in 1990 to 0.69 in 2030. Coal combustion will remain the main source of CO 2 , whereas give the largest contribution to lowering the CO 2 intensity. The strategy and the bodies created to implement the commitments made by Korea to lower greenhouse gas emissions are described. (author). 14 tabs

  7. Potential restrictions for CO2 sequestration sites due to shale and tight gas production.

    Science.gov (United States)

    Elliot, T R; Celia, M A

    2012-04-03

    Carbon capture and geological sequestration is the only available technology that both allows continued use of fossil fuels in the power sector and reduces significantly the associated CO(2) emissions. Geological sequestration requires a deep permeable geological formation into which captured CO(2)can be injected, and an overlying impermeable formation, called a caprock, that keeps the buoyant CO(2) within the injection formation. Shale formations typically have very low permeability and are considered to be good caprock formations. Production of natural gas from shale and other tight formations involves fracturing the shale with the explicit objective to greatly increase the permeability of the shale. As such, shale gas production is in direct conflict with the use of shale formations as a caprock barrier to CO(2) migration. We have examined the locations in the United States where deep saline aquifers, suitable for CO(2) sequestration, exist, as well as the locations of gas production from shale and other tight formations. While estimated sequestration capacity for CO(2) sequestration in deep saline aquifers is large, up to 80% of that capacity has areal overlap with potential shale-gas production regions and, therefore, could be adversely affected by shale and tight gas production. Analysis of stationary sources of CO(2) shows a similar effect: about two-thirds of the total emissions from these sources are located within 20 miles of a deep saline aquifer, but shale and tight gas production could affect up to 85% of these sources. These analyses indicate that colocation of deep saline aquifers with shale and tight gas production could significantly affect the sequestration capacity for CCS operations. This suggests that a more comprehensive management strategy for subsurface resource utilization should be developed.

  8. Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates.

    Science.gov (United States)

    Hashimoto, Hidenori; Yamaguchi, Tsutomu; Ozeki, Hiroyuki; Muromachi, Sanehiro

    2017-12-08

    Ionic clathrate hydrates can selectively capture small gas molecules such as CO 2 , N 2 , CH 4 and H 2 . We investigated CO 2  + N 2 mixed gas separation properties of ionic clathrate hydrates formed with tetra-n-butylammonium bromide (TBAB), tetra-n-butylammonium chloride (TBAC), tetra-n-butylphosphonium bromide (TBPB) and tetra-n-butylphosphonium chloride (TBPC). The results showed that CO 2 selectivity of TBAC hydrates was remarkably higher than those of the other hydrates despite less gas capacity of TBAC hydrates. The TBAB hydrates also showed irregularly high CO 2 selectivity at a low pressure. X-ray diffraction and Raman spectroscopic analyses clarified that TBAC stably formed the tetragonal hydrate structure, and TBPB and TBPC formed the orthorhombic hydrate structure. The TBAB hydrates showed polymorphic phases which may consist of the both orthorhombic and tetragonal hydrate structures. These results showed that the tetragonal hydrate captured CO 2 more efficiently than the orthorhombic hydrate, while the orthorhombic hydrate has the largest gas capacity among the basic four structures of ionic clathrate hydrates. The present study suggests new potential for improving gas capacity and selectivity of ionic clathrate hydrates by choosing suitable ionic guest substances for guest gas components.

  9. Carbon soundings: greenhouse gas emissions of the UK music industry

    International Nuclear Information System (INIS)

    Bottrill, C; Liverman, D; Boykoff, M

    2010-01-01

    Over the past decade, questions regarding how to reduce human contributions to climate change have become more commonplace and non-nation state actors-such as businesses, non-government organizations, celebrities-have increasingly become involved in climate change mitigation and adaptation initiatives. For these dynamic and rapidly expanding spaces, this letter provides an accounting of the methods and findings from a 2007 assessment of greenhouse gas (GHG) emissions in the UK music industry. The study estimates that overall GHG emissions associated with the UK music market are approximately 540 000 t CO 2 e per annum. Music recording and publishing accounted for 26% of these emissions (138 000 t CO 2 e per annum), while three-quarters (74%) derived from activities associated with live music performances (400 000 t CO 2 e per annum). These results have prompted a group of music industry business leaders to design campaigns to reduce the GHG emissions of their supply chains. The study has also provided a basis for ongoing in-depth research on CD packaging, audience travel, and artist touring as well as the development of a voluntary accreditation scheme for reducing GHG emissions from activities of the UK music industry.

  10. Carbon soundings: greenhouse gas emissions of the UK music industry

    Science.gov (United States)

    Bottrill, C.; Liverman, D.; Boykoff, M.

    2010-01-01

    Over the past decade, questions regarding how to reduce human contributions to climate change have become more commonplace and non-nation state actors—such as businesses, non-government organizations, celebrities—have increasingly become involved in climate change mitigation and adaptation initiatives. For these dynamic and rapidly expanding spaces, this letter provides an accounting of the methods and findings from a 2007 assessment of greenhouse gas (GHG) emissions in the UK music industry. The study estimates that overall GHG emissions associated with the UK music market are approximately 540 000 t CO2e per annum. Music recording and publishing accounted for 26% of these emissions (138 000 t CO2e per annum), while three-quarters (74%) derived from activities associated with live music performances (400 000 t CO2e per annum). These results have prompted a group of music industry business leaders to design campaigns to reduce the GHG emissions of their supply chains. The study has also provided a basis for ongoing in-depth research on CD packaging, audience travel, and artist touring as well as the development of a voluntary accreditation scheme for reducing GHG emissions from activities of the UK music industry.

  11. Effects of CO 2 on a High Performance Hollow-Fiber Membrane for Natural Gas Purification

    KAUST Repository

    Omole, Imona C.

    2010-05-19

    A 6FDA-based, cross-linkable polyimide was characterized in the form of a defect-free asymmetric hollow-fiber membrane. The novel membrane was cross-linked at various temperatures and tested for natural gas purification in the presence of high CO2 partial pressures. The cross-linked membrane material shows high intrinsic separation performance for CO2 and CH4 (selectivity ∼49, CO2 permeability ∼161 barrer, with a feed at 65 psia, 35 °C, and 10% CO2). Cross-linked asymmetric hollow-fiber membranes made from the material show good resistance to CO2-induced plasticization. Carbon dioxide partial pressures as high as ∼400 psia were employed, and the membrane was shown to be promisingly stable under these aggressive conditions. The performance of the membrane was also analyzed using the dual-mode sorption/transport model. © 2010 American Chemical Society.

  12. Change of properties after oxidation of IG-11 graphite by air and CO2 gas

    International Nuclear Information System (INIS)

    Lim, Yun-Soo; Chi, Se-Hwan; Cho, Kwang-Yun

    2008-01-01

    Artificial graphite is typically manufactured by carbonization of a shaped body of a kneaded mixture using granular cokes as a filler and pitch as a binder. It undergoes a pitch impregnation process if necessary and finally applying graphitization heat treatment. The effect of thermal oxidation in air or a CO 2 atmosphere on IG-11 graphite samples is investigated in this study. The results show a localized oxidation process that progressively reveals the large coke particles with increasing level of overall weight loss in air. The surface of the graphite was peeled off and no change was found in the specific gravity after air oxidation. However, the specific gravity of graphite was continuously decreased by CO 2 oxidation. The decrease in the specific gravity by CO 2 oxidation was due to CO 2 gas that progressed from the surface to the interior. The pore shape after CO 2 oxidation differed from that under air oxidation

  13. CO2 Capture from Flue Gas using Amino Acid Salt Solutions

    DEFF Research Database (Denmark)

    Lerche, Benedicte Mai; Stenby, Erling Halfdan; Thomsen, Kaj

    2009-01-01

    amine and the pH dropped between 2 and 3 units during the absorption process. In both types of solutions the temperature increased as a result of the CO2 absorption, which is expected due to the exothermic nature of the absorption reaction. The increase in temperature for the potassium glycinate......The reversible absorption of CO2 into a chemical solvent is currently the leading CO2 capture technology. Available solvents are almost exclusively based on aqueous alkanolamine solutions, which entail both economic and environmental complications, making the commercialization of the technology...... difficult. Amino acid salt solutions have emerged as an alternative to the alkanolamine solutions. A number of advantages make amino acid salt solutions attractive solvents for CO2 capture from flue gas. In the present study CO2 absorption in aqueous solutions of 0.5 M potassium glycinate and 0.5 M...

  14. Soil Greenhouse Gas Emissions from a Subtropical Mangrove in Hong Kong

    Science.gov (United States)

    Lai, D. Y. F.; Xu, J.

    2014-12-01

    The concept of "blue carbon" has received increasing attention recently, which points to the potential role of vegetated coastal wetlands in carbon sequestration. Yet, the magnitude and controls of greenhouse gas emissions from coastal wetland ecosystems, especially mangroves in the subtropical regions, are still largely unknown. In this study, we conducted chamber measurements in the Mai Po Marshes Nature Reserve of Hong Kong at monthly intervals to characterize the spatial and temporal variability of the emission of greenhouse gases, including CO2, CH4 and N2O from mangrove soils, and examine the influence of environmental and biotic variables on greenhouse gas fluxes. We found the highest mean CH4 and N2O emissions in autumn and the highest CO2 flux in summer. Along the tidal gradient, we observed significantly higher CH4 and N2O emissions from the middle zones and landward zones, respectively, while no clear spatial variation of CO2 emissions was observed. There were significantly higher soil greenhouse gas emissions from sites dominated by Avicennia marina than those dominated by Kandelia obovata, which might be due to the presence of pneumatophores which facilitated gas transport. We found a significant, negative correlation between CH4 flux and soil NO3-N concentration, while CO2 flux was positively correlation with total Kjeldahl nitrogen content. Soil temperature was positively correlated with the emissions of all three greenhouse gases, while water table depth was positively and negatively correlated with CH4 and N2O emissions, respectively. Our findings demonstrate the high spatial and temporal variability of greenhouse gas emissions from mangrove soils which could be attributed in part to the differences in environmental conditions and dominant plant species.

  15. Effect of CO2 injection on brine flow and salt precipitation after gas field production

    NARCIS (Netherlands)

    Tambach, T.J.; Loeve, D.; Hofstee, C.; Plug, W.J.; Maas, J.G.

    2014-01-01

    This paper reports modeling of gas field production and CO2 injection in a theoretical reservoir based on characteristics of the P18 gas field in the Dutch offshore, which consists of four geological deposits with different petrophysical properties. We especially focus on the brine flow during and

  16. New absorption liquids for the removal of CO2 from dilute gas streams using membrane contactors

    NARCIS (Netherlands)

    Kumar, P.S.; Hogendoorn, J.A.; Feron, P.H.M.; Versteeg, G.F.

    2002-01-01

    A new absorption liquid based on amino acid salts has been studied for CO2 removal in membrane gas-liquid contractors. Unlike conventional gas treating solvents like aqueous alkanolamines solutions, the new absorption liquid does not wet polyolefin microporous membranes. The wetting characteristics

  17. UNEP greenhouse gas abatement costing studies

    International Nuclear Information System (INIS)

    Shakespeare Maya, R.; Muguti, E.; Fenhann, J.; Morthorst, P.E.

    1992-08-01

    The UNEP (United Nations Environment Programme) programme of Greenhouse Gas Abatement Costing Studies is intended to clarify the economic issues involved in assessing the costs of limiting emissions of greenhouse gases and to propose approaches to comparable costing studies. Phase 1 of the Zimbabwe country study describes the current energy situation in Zimbabwe related to the national economy, energy supply and demand and amounts of greenhouse gas emissions. Factors regarding the geography, (including a map illustrating the degree and character of land degradation by erosion) population, politics, international relations, land-use and management of the energy sector are dealt with in detail and the text is illustrated with data compiled from the study. It is estimated that Zimbabwe consumed 270.4 Tj of energy during 1988 and emitted 21.7 tonnes of carbon dioxide. An emission intensity of 80.2 tonnes/Tj for the whole economy and 63.6 tonnes/Tj for electric power generation alone was calculated. Forecasting for the year 2020 estimated carbon dioxide emission intensities of 73.5 tonnes/Tj for the whole economy and 43.7 tonnes for power generation. Net carbon dioxide emissions are predicted to be 30-42 tonnes during 2020. (AB)

  18. Characteristics of Greenhouse Gas Emissions from the Wheat Fields with Different Returning Methods of Maize Straws

    Directory of Open Access Journals (Sweden)

    LI Xin-hua

    2016-03-01

    Full Text Available In order to investigate the effect of different returning methods of maize straw on the greenhouse gas emissions from the wheat fields, we explored the greenhouse gas CO2, N2O and CH4 emissions from the wheat fields using static chamber-gas chromatograph technique from December 2013 to May 2014. The experiments set four treatments including no maize straw returning(CK, direct maize straw returning directly(CS, maize straw-rumen-cattle dung returning(CGS and maize straw-mushroom residue returning(CMS, and the four treatments were investigated under the same watering and fertilizing conditions. The results showed that the greenhouse gas emissions from the wheat fields all had distinct seasonal variations and the cumulative emissions of greenhouse gas emissions were different. During the maize growing season, the cumulative emissions of both CO2 and N2O were emitted and in the order of CK >CGS >CS >CMS while the cumulative absorptions of CH4 were in the order of CS >CGS >CK >CMS with the significant difference between different treatments(PCGS >CK >CMS under the different returning methods of maize straw, which indicated that direct straw returning could significantly increase the global warming potential of greenhouse gases from the wheat field, followed by CGS while the straw-mushroom residue returning(CMS could decrease the global warming potential of greenhouse gases from the wheat field. The method of straw-mushroom residue returning should be recommended from the viewpoint of reducing GWP of the greenhouse gas. In all, our study could provide the scientific foundation for the efficiency straw recycle and reducing greenhouse gas emission.

  19. A CO 2-rich gas trigger of explosive paroxysms at Stromboli basaltic volcano, Italy

    Science.gov (United States)

    Allard, Patrick

    2010-01-01

    In addition to rhythmic slug-driven Strombolian activity, Stromboli volcano occasionally produces discrete explosive paroxysms (2 per year on average for the most frequent ones) that constitute a major hazard and whose origin remains poorly elucidated. Partial extrusion of the volatile-rich feeding basalt as aphyric pumice during these events has led to consider their triggering by the fast ascent of primitive magma blobs from possibly great depth. Here I examine and discuss the alternative hypothesis that most of the paroxysms could be triggered and driven by the fast upraise of CO 2-rich gas pockets generated by bubble foam growth and collapse in the sub-volcano plumbing system. Data for the SO 2 and CO 2 crater plume emissions are used to show that Stromboli's feeding magma may originally contain as much as 2 wt.% of carbon dioxide and early coexists with an abundant CO 2-rich gas phase with high CO 2/SO 2 molar ratio (≥ 60 at 10 km depth below the vents, compared to ˜ 7 in time-averaged crater emissions). Pressure-related modelling indicates that the time-averaged crater gas composition and output are well accounted for by closed system decompression of the basalt-gas mixture until the volcano-crust interface (˜ 3 km depth), followed by open degassing and crystallization in the volcano conduits. However, both the low viscosity and high vesicularity of the basaltic magma permit bubble segregation and bubble foam growth at deep sill-like feeder discontinuities and at shallower physical boundaries (such as the volcano-crust interface) where the gas-rich aphyric basalt interacts with the unerupted crystal-rich and viscous magma drained back from the volcano conduits. Gas pressure build-up and bubble foam collapse at these boundaries will intermittently trigger the sudden upraise of CO 2-rich gas blobs that constitute the main driving force of the paroxysms. Deeper-sourced gas blobs, driving the most powerful explosions, will be the richest in CO 2 and have

  20. Climate Change and the Impact of Greenhouse Gasses: CO2 and NO, Friends and Foes of Plant Oxidative Stress

    Directory of Open Access Journals (Sweden)

    Raúl Cassia

    2018-03-01

    Full Text Available Here, we review information on how plants face redox imbalance caused by climate change, and focus on the role of nitric oxide (NO in this response. Life on Earth is possible thanks to greenhouse effect. Without it, temperature on Earth’s surface would be around -19°C, instead of the current average of 14°C. Greenhouse effect is produced by greenhouse gasses (GHG like water vapor, carbon dioxide (CO2, methane (CH4, nitrous oxides (NxO and ozone (O3. GHG have natural and anthropogenic origin. However, increasing GHG provokes extreme climate changes such as floods, droughts and heat, which induce reactive oxygen species (ROS and oxidative stress in plants. The main sources of ROS in stress conditions are: augmented photorespiration, NADPH oxidase (NOX activity, β-oxidation of fatty acids and disorders in the electron transport chains of mitochondria and chloroplasts. Plants have developed an antioxidant machinery that includes the activity of ROS detoxifying enzymes [e.g., superoxide dismutase (SOD, ascorbate peroxidase (APX, catalase (CAT, glutathione peroxidase (GPX, and peroxiredoxin (PRX], as well as antioxidant molecules such as ascorbic acid (ASC and glutathione (GSH that are present in almost all subcellular compartments. CO2 and NO help to maintain the redox equilibrium. Higher CO2 concentrations increase the photosynthesis through the CO2-unsaturated Rubisco activity. But Rubisco photorespiration and NOX activities could also augment ROS production. NO regulate the ROS concentration preserving balance among ROS, GSH, GSNO, and ASC. When ROS are in huge concentration, NO induces transcription and activity of SOD, APX, and CAT. However, when ROS are necessary (e.g., for pathogen resistance, NO may inhibit APX, CAT, and NOX activity by the S-nitrosylation of cysteine residues, favoring cell death. NO also regulates GSH concentration in several ways. NO may react with GSH to form GSNO, the NO cell reservoir and main source of S

  1. Climate Change and the Impact of Greenhouse Gasses: CO2 and NO, Friends and Foes of Plant Oxidative Stress.

    Science.gov (United States)

    Cassia, Raúl; Nocioni, Macarena; Correa-Aragunde, Natalia; Lamattina, Lorenzo

    2018-01-01

    Here, we review information on how plants face redox imbalance caused by climate change, and focus on the role of nitric oxide (NO) in this response. Life on Earth is possible thanks to greenhouse effect. Without it, temperature on Earth's surface would be around -19°C, instead of the current average of 14°C. Greenhouse effect is produced by greenhouse gasses (GHG) like water vapor, carbon dioxide (CO 2 ), methane (CH 4 ), nitrous oxides (N x O) and ozone (O 3 ). GHG have natural and anthropogenic origin. However, increasing GHG provokes extreme climate changes such as floods, droughts and heat, which induce reactive oxygen species (ROS) and oxidative stress in plants. The main sources of ROS in stress conditions are: augmented photorespiration, NADPH oxidase (NOX) activity, β-oxidation of fatty acids and disorders in the electron transport chains of mitochondria and chloroplasts. Plants have developed an antioxidant machinery that includes the activity of ROS detoxifying enzymes [e.g., superoxide dismutase (SOD), ascorbate peroxidase (APX), catalase (CAT), glutathione peroxidase (GPX), and peroxiredoxin (PRX)], as well as antioxidant molecules such as ascorbic acid (ASC) and glutathione (GSH) that are present in almost all subcellular compartments. CO 2 and NO help to maintain the redox equilibrium. Higher CO 2 concentrations increase the photosynthesis through the CO 2 -unsaturated Rubisco activity. But Rubisco photorespiration and NOX activities could also augment ROS production. NO regulate the ROS concentration preserving balance among ROS, GSH, GSNO, and ASC. When ROS are in huge concentration, NO induces transcription and activity of SOD, APX, and CAT. However, when ROS are necessary (e.g., for pathogen resistance), NO may inhibit APX, CAT, and NOX activity by the S-nitrosylation of cysteine residues, favoring cell death. NO also regulates GSH concentration in several ways. NO may react with GSH to form GSNO, the NO cell reservoir and main source of S

  2. Experimental Study of Matrix Permeability of Gas Shale: An Application to CO2-Based Shale Fracturing

    Directory of Open Access Journals (Sweden)

    Chengpeng Zhang

    2018-03-01

    Full Text Available Because the limitations of water-based fracturing fluids restrict their fracturing efficiency and scope of application, liquid CO2 is regarded as a promising substitute, owing to its unique characteristics, including its greater environmental friendliness, shorter clean-up time, greater adsorption capacity than CH4 and less formation damage. Conversely, the disadvantage of high leak-off rate of CO2 fracturing due to its very low viscosity determines its applicability in gas shales with ultra-low permeability, accurate measurement of shale permeability to CO2 is therefore crucial to evaluate the appropriate injection rate and total consumption of CO2. The main purpose of this study is to accurately measure shale permeability to CO2 flow during hydraulic fracturing, and to compare the leak-off of CO2 and water fracturing. A series of permeability tests was conducted on cylindrical shale samples 38 mm in diameter and 19 mm long using water, CO2 in different phases and N2 considering multiple influencing factors. According to the experimental results, the apparent permeability of shale matrix to gaseous CO2 or N2 is greatly over-estimated compared with intrinsic permeability or that of liquid CO2 due to the Klinkenberg effect. This phenomenon explains that the permeability values measured under steady-state conditions are much higher than those under transient conditions. Supercritical CO2 with higher molecular kinetic energy has slightly higher permeability than liquid CO2. The leak-off rate of CO2 is an order of magnitude higher than that of water under the same injection conditions due to its lower viscosity. The significant decrease of shale permeability to gas after water flooding is due to the water block effect, and much longer clean-up time and deep water imbibition depth greatly impede the gas transport from the shale matrix to the created fractures. Therefore, it is necessary to substitute water-based fracturing fluids with liquid or super

  3. Regional greenhouse gas emissions from cultivation of winter wheat and winter rapeseed for biofuels in Denmark

    DEFF Research Database (Denmark)

    Elsgaard, Lars; Olesen, Jørgen E; Hermansen, John Erik

    2013-01-01

    by such regional factors as soil conditions, climate and input of agrochemicals. Here we analysed at a regional scale the greenhouse gas (GHG) emissions associated with cultivation of winter wheat for bioethanol and winter rapeseed for rapeseed methyl ester (RME) under Danish conditions. Emitted CO2 equivalents...... (CO2eq) were quantified from the footprints of CO2, CH4 and N2O associated with cultivation and the emissions were allocated between biofuel energy and co-products. Greenhouse gas emission at the national level (Denmark) was estimated to 22.1 g CO2eq MJ−1 ethanol for winter wheat and 26.0 g CO2eq MJ−1...... RME for winter rapeseed. Results at the regional level (level 2 according to the Nomenclature of Territorial Units for Statistics [NUTS]) ranged from 20.0 to 23.9 g CO2eq MJ−1 ethanol and from 23.5 to 27.6 g CO2eq MJ−1 RME. Thus, at the regional level emission results varied by up to 20%. Differences...

  4. Dual Alkali Solvent System for CO2 Capture from Flue Gas.

    Science.gov (United States)

    Li, Yang; Wang, H Paul; Liao, Chang-Yu; Zhao, Xinglei; Hsiung, Tung-Li; Liu, Shou-Heng; Chang, Shih-Ger

    2017-08-01

    A novel two-aqueous-phase CO 2 capture system, namely the dual alkali solvent (DAS) system, has been developed. Unlike traditional solvent-based CO 2 capture systems in which the same solvent is used for both CO 2 absorption and stripping, the solvent of the DAS system consists of two aqueous phases. The upper phase, which contains an organic alkali 1-(2-hydroxyethyl) piperazine (HEP), is used for CO 2 absorption. The lower phase, which consists of a mixture of K 2 CO 3 /KHCO 3 aqueous solution and KHCO 3 precipitate, is used for CO 2 stripping. Only a certain kind of amine (such as HEP) is able to ensure the phase separation, satisfactory absorption efficiency, effective CO 2 transfer from the upper phase to the lower phase, and regeneration of the upper phase. In the meantime, due to the presence of K 2 CO 3 /KHCO 3 in the lower phase, HEP in the upper phase is capable of being regenerated from its sulfite/sulfate heat stable salt, which enables the simultaneous absorption of CO 2 and SO 2 /SO 3 from the flue gas. Preliminary experiments and simulations indicate that the implementation of the DAS system can lead to 24.0% stripping energy savings compared to the Econamine process, without significantly lowering the CO 2 absorption efficiency (∼90%).

  5. Students' Understanding of the Greenhouse Effect, the Societal Consequences of Reducing CO2 Emissions and the Problem of Ozone Layer Depletion.

    Science.gov (United States)

    Andersson, Bjorn; Wallin, Anita

    2000-01-01

    Contributes to the growing body of knowledge about students' conceptions and views of environmental and natural resource issues. Questions 9th and 12th grade Swedish students' understandings of the greenhouse effect, reduction of CO2 emissions, and the depletion of the ozone layer. Observes five models of the greenhouse effect that appear among…

  6. Analysis of Urban Forest Needs as Anthropogenic (CO2) Gas Absorbent in Semarang City

    Science.gov (United States)

    Febriani, Anisa Putri; Retnaningsih Soeprobowati, Tri; Maryono

    2018-02-01

    Green open space in cities in significant needs to maintenance environment quality. On of the critical function is to absorb increasing number of gas CO2. Therefore, developing urban forest in cities is very importance. The objective of the study is to determine the area of urban forest as CO2 gas anthropogenic absorb which is formed from fuel, diesel fuel, liquid petroleum gas. The study consists of (1) Analyzing the number of CO2 gas emission by calculating the needs of petroleum and gas based on the number of population, (2) Analyzing the power of gas absorption, (3) Measuring the air concentration of CO2 gas ambient based on daily traffic activities. This study shown that from year 2013 to year 2017, the increasing of urban forest is not so significant. For year 2013 the green open space in Semarang City are 373.67 hectares (7.5 percent from Semarang City area), consists of 239 parks, 11 public cemeteries, production forests, community forests, and urban forests, however the area of urban forest is not increase. The study assess that Antidesmabunius is one of the green species which high absorb capacity planted for Semarang. This trees produce 31,31 ton annually. This study proposed to fostering Antidesmabunius as one principle threes in Semarang urban forest.

  7. A CO2-gas precursor to the March 2015 Villarrica volcano eruption

    Science.gov (United States)

    Aiuppa, Alessandro; Bitetto, Marcello; Francofonte, Vincenzo; Velasquez, Gabriela; Parra, Claudia Bucarey; Giudice, Gaetano; Liuzzo, Marco; Moretti, Roberto; Moussallam, Yves; Peters, Nial; Tamburello, Giancarlo; Valderrama, Oscar. A.; Curtis, Aaron

    2017-06-01

    We present here the first volcanic gas compositional time-series taken prior to a paroxysmal eruption of Villarrica volcano (Chile). Our gas plume observations were obtained using a fully autonomous Multi-component Gas Analyser System (Multi-GAS) in the 3 month-long phase of escalating volcanic activity that culminated into the 3 March 2015 paroxysm, the largest since 1985. Our results demonstrate a temporal evolution of volcanic plume composition, from low CO2/SO2 ratios (0.65-2.7) during November 2014-January 2015 to CO2/SO2 ratios up to ≈ 9 then after. The H2O/CO2 ratio simultaneously declined to <38 in the same temporal interval. We use results of volatile saturation models to demonstrate that this evolution toward CO2-enriched gas was likely caused by unusual supply of deeply sourced gas bubbles. We propose that separate ascent of over-pressured gas bubbles, originating from at least 20-35 MPa pressures, was the driver for activity escalation toward the 3 March climax.

  8. Membrane-assisted CO2 liquefaction: performance modelling of CO2 capture from flue gas in cement production

    NARCIS (Netherlands)

    Bouma, R.H.B.; Vercauteren, F.F.; Os, P.J. van; Goetheer, E.L.V.; Berstad, D.; Anantharaman, R.

    2017-01-01

    CEMCAP is an international R&D project under the Horizon 2020 Programme preparing the ground for the large-scale implementation of CO2 capture in the European cement industry. This paper concerns the performance modeling of membraneassisted CO2 liquefaction as a possible retrofit application for

  9. Proportional counters aged anode wire recovering using an 80%CF4 + 20%CO2 gas mixture

    CERN Document Server

    Gavrilov, Gennady; Conti, Richard; Fetisov, Andrey; Maysuzenko, Dmitry; Shvecova, Natalia; Vakhtel, Victor

    2011-01-01

    A technique to recover a gas proportional counter having an aged anode wire using a glow discharge in an 80%CF4 + 20%CO2 gas mixture has been developed and tested. Studies of aging effects were carried out under sustained irradiation by an intense 90Sr -source of the straw proportional counters operated with a 60%Ar + 30%CO2 + 10%CF4 gas mixture. Special attention was paid to the aging mechanism of the anode wires. Our experience showed that using a given gas mixture the swelling of the anode wires is a typical mode of aging that leads to degradation of the gas gain. The proposed method of recovery provided a complete restoration of the gas gain and the signal amplitude in the damaged zone of the wire. SEM/XEM analysis confirmed successful cleaning WOx deposits from the wire surface. The application of this method to recover the aged gaseous detectors in real experimental conditions is discussed.

  10. Greenhouse gas contribution of municipal solid waste collection: A case study in the city of Istanbul, Turkey.

    Science.gov (United States)

    Korkut, Nafiz E; Yaman, Cevat; Küçükağa, Yusuf; Jaunich, Megan K; Demir, İbrahim

    2018-02-01

    This article estimates greenhouse gas emissions and global warming factors resulting from collection of municipal solid waste to the transfer stations or landfills in Istanbul for the year of 2015. The aim of this study is to quantify and compare diesel fuel consumption and estimate the greenhouse gas emissions and global warming factors associated with municipal solid waste collection of the 39 districts of Istanbul. Each district's greenhouse gas emissions resulting from the provision and combustion of diesel fuel was estimated by considering the number of collection trips and distances to municipal solid waste facilities. The estimated greenhouse gases and global warming factors for the districts varied from 61.2 to 2759.1 t CO 2 -eq and from 4.60 to 15.20 kg CO 2 -eq t -1 , respectively. The total greenhouse gas emission was estimated as 46.4E3 t CO 2 -eq. Lastly, the collection data from the districts was used to parameterise a collection model that can be used to estimate fuel consumption associated with municipal solid waste collection. This mechanistic model can then be used to predict future fuel consumption and greenhouse gas emissions associated with municipal solid waste collection based on projected population, waste generation, and distance to transfer stations and landfills. The greenhouse gas emissions can be reduced by decreasing the trip numbers and trip distances, building more transfer stations around the city, and making sure that the collection trucks are full in each trip.

  11. System for δ13C-CO2 and xCO2 analysis of discrete gas samples by cavity ring-down spectroscopy

    Science.gov (United States)

    Dickinson, Dane; Bodé, Samuel; Boeckx, Pascal

    2017-11-01

    A method was devised for analysing small discrete gas samples (50 mL syringe) by cavity ring-down spectroscopy (CRDS). Measurements were accomplished by inletting 50 mL syringed samples into an isotopic-CO2 CRDS analyser (Picarro G2131-i) between baseline readings of a reference air standard, which produced sharp peaks in the CRDS data feed. A custom software script was developed to manage the measurement process and aggregate sample data in real time. The method was successfully tested with CO2 mole fractions (xCO2) ranging from 20 000 ppm and δ13C-CO2 values from -100 up to +30 000 ‰ in comparison to VPDB (Vienna Pee Dee Belemnite). Throughput was typically 10 samples h-1, with 13 h-1 possible under ideal conditions. The measurement failure rate in routine use was ca. 1 %. Calibration to correct for memory effects was performed with gravimetric gas standards ranging from 0.05 to 2109 ppm xCO2 and δ13C-CO2 levels varying from -27.3 to +21 740 ‰. Repeatability tests demonstrated that method precision for 50 mL samples was ca. 0.05 % in xCO2 and 0.15 ‰ in δ13C-CO2 for CO2 compositions from 300 to 2000 ppm with natural abundance 13C. Long-term method consistency was tested over a 9-month period, with results showing no systematic measurement drift over time. Standardised analysis of discrete gas samples expands the scope of application for isotopic-CO2 CRDS and enhances its potential for replacing conventional isotope ratio measurement techniques. Our method involves minimal set-up costs and can be readily implemented in Picarro G2131-i and G2201-i analysers or tailored for use with other CRDS instruments and trace gases.

  12. Regulation of leaf-gas exchange strategies of woody plants under elevated CO2

    Science.gov (United States)

    Belmecheri, S.; Guerrieri, R.; Voelker, S.

    2016-12-01

    Estimates of vegetation water use efficiency (WUE) have increasingly been assessed using both eddy covariance and plant stable isotope techniques but these data have often lead to differing conclusions. Eddy covariance can provide forest ecosystem-level responses of coupled carbon and water exchanges to recent global change phenomena. These direct observations, however, are generally less than one or two decades, thus documenting ecosystem-level responses at elevated [CO2] concentrations (350-400 ppm). Therefore, eddy covariance data cannot directly address plant physiological mechanisms and adaptation to climate variability and anthropogenic factors, e.g., increasing atmospheric [CO2]. By contrast, tree based carbon isotope approaches can retrospectively assess intrinsic WUE over long periods and have documented physiological responses to ambient atmospheric [CO2] (ca), which have often been contextualized within generalized strategies for stomatal regulation of leaf gas-exchange. These include maintenance of a constant leaf internal [CO2] (ci), a constant drawdown in [CO2] (ca - ci), and a constant ci/ca . Tree carbon isotope studies, however, cannot account for changes in leaf area of individual trees or canopies, which makes scaling up a difficult task. The limitations of these different approaches to understanding how forest water use efficiency has been impacted by rising [CO2] has contributed to the uncertainty in global terrestrial carbon cycling and the "missing" terrestrial carbon sink. We examined stable C isotope ratios (d13C) from woody plants over a wide range of [CO2] (200-400 ppm) to test for patterns of ci-regulation in response to rising ca. The analyses are not consistent with any of the leaf gas-exchange regulation strategies noted above. The data suggest that ca - ci is still recently increasing in most species but that the rate of increase is less than expected from paleo trees which grew at much lower [CO2]. This evidence demonstrates that a

  13. Fundamental research on gas-solid reaction between CO2 and Li2CuO2 linking application for solid CO2 absorbent

    Science.gov (United States)

    Oh-ishi, Katsuyoshi; Matsukura, Yusuke; Okumura, Takeshi; Matsunaga, Yuuki; Kobayashi, Ryota

    2014-03-01

    We compared reactivity between CO2 and Li2CuO2 with that between CO2 and Li4SiO4 by using XRD, SEM observation, and thermogravimetry in order to study fundamentally a potential of Li2CuO2 oxide for application to solid CO2 absorbents. The CO2 absorption ability of Li2CuO2 was examined by measuring rate constants for the gas-solid reaction between perfectly single-phase Li2CuO2 and CO2 at various temperatures in 100 vol% CO2 atmosphere using the rate theory with thermogravimetry using rapid heating. The measured rate constants were compared with those reported previously for Li4SiO4 at various temperatures. Almost no difference was found between these rate constants of Li2CuO2 and Li4SiO4 at temperatures less than 660 °C, but at temperatures higher than 670 °C, the rate constants of Li2CuO2 were greater than those of Li4SiO4. These results demonstrate that Li2CuO2 can outstrip the ability of Li4SiO4 to absorb CO2. Moreover, different from Li4SiO4, the CO2 absorption ability of Li2CuO2 decays only slightly, even if the atmospheric CO2 concentration decreases.

  14. Quantifying and reporting greenhouse gas emissions at local level

    Directory of Open Access Journals (Sweden)

    Sόwka Izabela

    2017-01-01

    Full Text Available Cities as global centers of consumption and production often are a significant and growing source of greenhouse gas (GHG emissions. At the same time, local authorities are increasingly taking action on climate change by focusing on reducing GHG emissions and efficiency improvement opportunities. To assess and reduce the overall greenhouse gas emission level from an urban area, it is necessary to identify all the activities and processes which generate these emissions. GHG inventory gives an opportunity to get wider knowledge for city’s community about spatial emission processes and emissions contribution of key sources categories at the local scale. Inventory is being used for decision-making purposes and strategic planning in emission reduction policy. The goal of this paper was to clarify the major methodological challenges of GHG monitoring at the urban level. The paper is based on the discussion of different methods and approaches to assessing GHG emissions at the local level. It is presented sectoral GHGs emission trends in selected urban areas and compared CO2 emission level in different countries and metropolises and variable European cities guidance. The study determines the inventory tools of GHGs emission taking into account the characteristics of main sources at local levels.

  15. Deep greenhouse gas emission reductions in Europe: Exploring different options

    International Nuclear Information System (INIS)

    Deetman, Sebastiaan; Hof, Andries F.; Pfluger, Benjamin; Vuuren, Detlef P. van; Girod, Bastien; Ruijven, Bas J. van

    2013-01-01

    Most modelling studies that explore emission mitigation scenarios only look into least-cost emission pathways, induced by a carbon tax. This means that European policies targeting specific – sometimes relatively costly – technologies, such as electric cars and advanced insulation measures, are usually not evaluated as part of cost-optimal scenarios. This study explores an emission mitigation scenario for Europe up to 2050, taking as a starting point specific emission reduction options instead of a carbon tax. The purpose is to identify the potential of each of these policies and identify trade-offs between sectoral policies in achieving emission reduction targets. The reduction options evaluated in this paper together lead to a reduction of 65% of 1990 CO 2 -equivalent emissions by 2050. More bottom-up modelling exercises, like the one presented here, provide a promising starting point to evaluate policy options that are currently considered by policy makers. - Highlights: ► We model the effects of 15 climate change mitigation measures in Europe. ► We assess the greenhouse gas emission reduction potential in different sectors. ► The measures could reduce greenhouse gas emissions by 60% below 1990 levels in 2050. ► The approach allows to explore arguably more relevant climate policy scenarios

  16. Global initiatives to mitigate greenhouse gas emissions

    International Nuclear Information System (INIS)

    Helme, N.; Gille, J.A.

    1994-01-01

    Joint implementation (JI) is a provision, included in the Framework Convention on Climate Change, that allows for two or more nations to jointly plan and implement a greenhouse gas or offsetting project. Joint implementation is important environmentally for two principal reasons: (1) it provides an opportunity to select projects on a global basis that maximize both greenhouse gas reduction benefits and other environmental benefits such as air pollution reduction while minimizing cost, and (2) it creates incentives for developing countries as well as multinational companies to begin to evaluate potential investments through a climate-friendly lens. While the debate on how to establish the criteria and institutional capacity necessary to encourage joint implementation projects continues in the international community, the US government is creating new incentives for US companies to develop joint implementation pilot projects now. While delegates to the United Nations' International Negotiating Committee (INC) debate whether to permit all Parties to the convention to participate in JI, opportunities in Eastern and Central Europe and the former Soviet states abound. The US has taken a leadership role in joint implementation, establishing two complementary domestic programs that allow US companies to measure, track and score their net greenhouse gas reduction achievements now. With a financial investment by three US utilities, the Center for Clean Air Policy is developing a fuel-switching and energy efficiency project in the city of Decin in the Czech Republic which offers a concrete example of what a real-world JI project could look like. The Decin project provides an ideal test case for assessing the adequacy and potential impact of the draft criteria for the US Initiative on Joint Implementation, as well as for the draft criteria prepared by the INC Secretariat

  17. A Comparative Data-Based Modeling Study on Respiratory CO2 Gas Exchange during Mechanical Ventilation

    Directory of Open Access Journals (Sweden)

    Chang-Sei eKim

    2016-02-01

    Full Text Available The goal of this study is to derive a minimally complex but credible model of respiratory CO2 gas exchange that may be used in systematic design and pilot testing of closed-loop end-tidal CO2 controllers in mechanical ventilation. We first derived a candidate model that captures the essential mechanisms involved in the respiratory CO2 gas exchange process. Then, we simplified the candidate model to derive two lower-order candidate models. We compared these candidate models for predictive capability and reliability using experimental data collected from 25 pediatric subjects undergoing dynamically varying mechanical ventilation during surgical procedures. A two-compartment model equipped with transport delay to account for CO2 delivery between the lungs and the tissues showed modest but statistically significant improvement in predictive capability over the same model without transport delay. Aggregating the lungs and the tissues into a single compartment further degraded the predictive fidelity of the model. In addition, the model equipped with transport delay demonstrated superior reliability to the one without transport delay. Further, the respiratory parameters derived from the model equipped with transport delay, but not the one without transport delay, were physiologically plausible. The results suggest that gas transport between the lungs and the tissues must be taken into account to accurately reproduce the respiratory CO2 gas exchange process under conditions of wide-ranging and dynamically varying mechanical ventilation conditions.

  18. Measuring Greenhouse Gas Emissions and Sinks Across California Land Cover

    Science.gov (United States)

    Fischer, M. L.

    2017-12-01

    Significant reductions in greenhouse gas (GHG) emissions are needed to limit rising planetary temperatures that will otherwise limit Earth's capacity to support life, introducing geopolitical instability. To help mitigate this threat, California has legislated landmark reductions in state-level greenhouse gas (GHG) emissions that set an example for broader action. Beginning with relatively assured reduction of current emissions to 1990 levels by 2020, future goals are much more challenging with 40% and 80% reductions below 1990 emissions by 2030 and 2050, respectively. While the majority of the reductions must focus on fossil fuels, inventory estimates of non-CO2 GHG emissions (i.e., CH4, N2O, and industrial compounds) constitute 15% of the total, suggesting reductions are required across multiple land use sectors. However, recent atmospheric inversion studies show methane and nitrous oxide (CH4 & N2O) emissions exceed current inventory estimates by factors of 1.2-1.8 and 1.6-2.6 (at 95% confidence), respectively, perhaps constituting up to 30% of State total emissions. The discrepancy is likely because current bottom-up models used for inventories do not accurately capture important management or biophysical factors. In the near term, process level experiments and sector-specific inversions are being planned to quantify the factors controlling non-CO2 GHG emissions for several of the dominant emission sectors. For biosphere carbon, California forests lands, which also depend on the combination of management, climate, and weather, lost above ground carbon from 2001-2010, and may be expected to lose soil and root carbon as a longer-term result. Here, it is important to identify and apply the best principles in forestry and agriculture to increase carbon stocks in depleted forest and agricultural areas, focusing on approaches that provide resilience to future climate and weather variations. Taken together, improved atmospheric, plant, and soil observations, together

  19. The French wholesale electricity, natural gas and CO2 markets in 2010-2011

    International Nuclear Information System (INIS)

    2011-10-01

    . With the resumption of demand, wholesale prices on the principal European markets were above the low points reached in 2010. The average spot price in the North zone was euro 17.6 /MWh in 2010, corresponding to a rise of 40% compared to 2009. This rise continued in 2011, with the spot price reaching levels close to euro 25 /MWh. This fourth CRE report on performance of the French energy markets incorporates an analysis of the CO 2 markets for the first time. Since the entry into effect of the banking and financial regulation law in October 2010, CRE has been charged with monitoring transactions carried out by suppliers, traders and producers of electricity and natural gas on greenhouse gas emission quotas, and on the term contracts and financial instruments for which they constitute the underlying. This monitoring, which is a transposition of the recommendations of the Prada report, is coordinated with the French financial regulator AMF (Autorite des Marches Financiers), which monitors French spot and futures exchanges in CO 2 . Cooperation between CRE and the AMF was formalised in a memorandum of understanding signed and made public in December 2010. As provided by the banking and financial regulation law, this agreement covers the electricity, gas and CO 2 markets and allows to implement a regulation adapted to both the financialisation of the energy markets and their specificities. Confidence in the European carbon market was affected at the beginning of 2010 by quota thefts recorded in some European countries. The European Commission has since acted to strengthen the security of the registries, one of the key links in the carbon market infrastructure. European carbon prices have varied in a volatile fashion in a context of an excess supply of quotas compared to actual emissions in both 2010 and 2009. The prospect of going to phase III in 2013, when quotas will become paid in large part - completely for the electricity sector - is supporting prices. Recently, prices

  20. Interactions between the Design and Operation of Shale Gas Networks, Including CO2 Sequestration

    Directory of Open Access Journals (Sweden)

    Sharifzadeh Mahdi

    2017-04-01

    Full Text Available As the demand for energy continues to increase, shale gas, as an unconventional source of methane (CH4, shows great potential for commercialization. However, due to the ultra-low permeability of shale gas reservoirs, special procedures such as horizontal drilling, hydraulic fracturing, periodic well shut-in, and carbon dioxide (CO2 injection may be required in order to boost gas production, maximize economic benefits, and ensure safe and environmentally sound operation. Although intensive research is devoted to this emerging technology, many researchers have studied shale gas design and operational decisions only in isolation. In fact, these decisions are highly interactive and should be considered simultaneously. Therefore, the research question addressed in this study includes interactions between design and operational decisions. In this paper, we first establish a full-physics model for a shale gas reservoir. Next, we conduct a sensitivity analysis of important design and operational decisions such as well length, well arrangement, number of fractures, fracture distance, CO2 injection rate, and shut-in scheduling in order to gain in-depth insights into the complex behavior of shale gas networks. The results suggest that the case with the highest shale gas production may not necessarily be the most profitable design; and that drilling, fracturing, and CO2 injection have great impacts on the economic viability of this technology. In particular, due to the high costs, enhanced gas recovery (EGR using CO2 does not appear to be commercially competitive, unless tax abatements or subsidies are available for CO2 sequestration. It was also found that the interactions between design and operational decisions are significant and that these decisions should be optimized simultaneously.

  1. Greenhouse gas emission factor for coal power chain in China and the comparison with nuclear power chain

    International Nuclear Information System (INIS)

    Ma Zhonghai; Pan Ziqiang; He Huimin

    1999-01-01

    The Greenhouse Gas Emission for coal power chain in China is analyzed in detail and comprehensively by using the Life Cycle Analysis method. The Greenhouse Gas Emission Factors (GGEF) in each link and for the total power chain are calculated. The total GGEF for coal power chain is 1302.3 gCO 2 /kWh, about 40 times more than that for nuclear power chain. And consequently greenhouse effect could not be aggravated further by nuclear power. The energy strategy for nuclear power development is one of reality ways to retard the greenhouse effect, put resources into rational use and protect environment

  2. Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations

    Energy Technology Data Exchange (ETDEWEB)

    Zoback, Mark D. [Stanford Univ., CA (United States); Kovscek, Anthony R. [Stanford Univ., CA (United States); Wilcox, Jennifer [Stanford Univ., CA (United States)

    2013-09-30

    This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

  3. Greenhouse gas emissions from municipal wastewater treatment plants

    Science.gov (United States)

    Parravicini, Vanessa; Svardal, Karl

    2016-04-01

    by a person in Germany or Austria (10.6 t CO2e/p/a, UBA, 2016). The results indicate that GHG emissions from WWTP have at global scale a small impact, as also highlighted by the Austrian national inventory report (NIR, 2015), where the estimated CO2e emissions from WWTPs account for only 0.23% of the total CO2e emission in Austria. References IPCC (2006). Intergovernmental Panel on Climate Change, Guidelines for National Greenhouse Gas Inventories, Prepared by the National Greenhouse Gas Inventories Program, Eggleston H.S., Buendia L., Miwa K., Ngara T. and Anabe K. (eds). Published: IGES, Japan. http://www.ipcc-nggip.iges.or.jp/public/2006gl/. NIR (2015). Austria's National Inventory Report 2015. Submission under the United Nations Framework Convention on Climate Change and under the Kyoto Protocol. Reports, Band 0552, ISBN: 978-3-99004-364-6, Umweltbundesamt, Wien. Parravicini V., Valkova T., Haslinger J., Saracevic E., Winkelbauer A., Tauber J., Svardal K., Hohenblum P., Clara M., Windhofer G., Pazdernik K., Lampert C. (2015). Reduktionspotential bei den Lachgasemissionen aus Kläranlagen durch Optimierung des Betriebes (ReLaKO). The research project was financially supported by the Ministry for agriculture, forestry, Environment and Water Management. Project leader: TU Wien, Institute for Water Quality, Ressources and Waste Management; Project partner: Umweltbundesamt GmbH. Final report: http://www.bmlfuw.gv.at/service/publikationen/wasser/Lachgasemissionen---Kl-ranlagen.html. UBA (2016). German average carbon footprint. Umweltbundesamt, Januar 2016, http://uba.klimaktiv-co2-rechner.de/de_DE/page/footprint/

  4. Arbuscular mycorrhizal colonization on carbon economy in perennial ryegrass: quantification by 13CO2/12CO2 steady-state labelling and gas exchange.

    Science.gov (United States)

    Grimoldi, Agustín A; Kavanová, Monika; Lattanzi, Fernando A; Schäufele, Rudi; Schnyder, Hans

    2006-01-01

    Effects of the arbuscular mycorrhizal fungus (AMF) Glomus hoi on the carbon economy of perennial ryegrass (Lolium perenne) were investigated by comparing nonmycorrhizal and mycorrhizal plants of the same size, morphology and phosphorus status. Plants were grown in the presence of CO2 sources with different C isotope composition (delta13C -1 or -44). Relative respiration and gross photosynthesis rates, and belowground allocation of C assimilated during one light period ('new C'), as well as its contribution to respiration, were quantified by the concerted use of 13CO2/12CO2 steady-state labelling and 13CO2/12CO2 gas-exchange techniques. AMF (G. hoi) enhanced the relative respiration rate of the root + soil system by 16%, inducing an extra C flow amounting to 3% of daily gross photosynthesis. Total C flow into AMF growth and respiration was estimated at rates. Therefore the instantaneous relative growth rate was lower in mycorrhizal plants.

  5. Spatial and temporal variability of greenhouse gas emissions from a small and shallow temperate lake

    Science.gov (United States)

    Praetzel, Leandra; Schmiedeskamp, Marcel; Broder, Tanja; Hüttemann, Caroline; Jansen, Laura; Metzelder, Ulrike; Wallis, Ronya; Knorr, Klaus-Holger; Blodau, Christian

    2017-04-01

    Small inland waters (measured CO2 and CH4 gas fluxes with different techniques across the sediment/water and water/atmosphere interface. Atmospheric exchange was measured using mini-chambers equipped with CO2 sensors and with an infra-red greenhouse gas analyzer for high temporal resolution flux measurements. Ebullition of CH4 was quantified with funnel traps. Sediment properties were examined using pore-water peepers. All measurements were carried out along a transect covering both littoral and central parts of the lake. Moreover, a weather station on a floating platform in the center of the lake recorded meteorological data as well as CO2 concentration in different depths of the water column. So far, Lake Windsborn seems to be a source for both CO2 and CH4 on an annual scale. CO2 emissions generally increased from spring to summer. Even though CO2 uptake could be observed during some periods in spring and fall, CO2 emissions in the summer exceeded the uptake. CO2 and CH4 emissions also appeared to be spatially variable between littoral areas and the inner lake. Shallow areas turned out to be "hot spots" of CO2 emissions whereas CH4 emissions were - against our expectations - highest in the center of the lake. Moreover, CH4 ebullition contributed substantially to total CH4 emissions. Our results show the importance of spatially and temporally highly resolved long-term measurements of greenhouse gas emissions and of potential controlling factors to address diurnal, seasonal and inter-annual variability as well as possible feedbacks to climate change.

  6. Coastal vegetation invasion increases greenhouse gas emission from wetland soils but also increases soil carbon accumulation

    International Nuclear Information System (INIS)

    Chen, Yaping; Chen, Guangcheng; Ye, Yong

    2015-01-01

    Soil properties and soil–atmosphere fluxes of CO 2 , CH 4 and N 2 O from four coastal wetlands were studied throughout the year, namely, native Kandelia obovata mangrove forest vs. exotic Sonneratia apetala mangrove forest, and native Cyperus malaccensis salt marsh vs. exotic Spartina alterniflora salt marsh. Soils of the four wetlands were all net sources of greenhouse gases while Sonneratia forest contributed the most with a total soil–atmosphere CO 2 -equivalent flux of 137.27 mg CO 2 m −2 h −1 , which is 69.23%, 99.75% and 44.56% higher than that of Kandelia, Cyperus and Spartina, respectively. The high underground biomass and distinctive root structure of Sonneratia might be responsible for its high greenhouse gas emission from the soil. Soils in Spartina marsh emitted the second largest amount of total greenhouse gases but it ranked first in emitting trace greenhouse gases. Annual average CH 4 and N 2 O fluxes from Spartina soil were 13.77 and 1.14 μmol m −2 h −1 , respectively, which are 2.08 and 1.46 times that of Kandelia, 1.03 and 1.15 times of Sonneratia, and 1.74 and 1.02 times of Cyperus, respectively. Spartina has longer growing season and higher productivity than native marshes which might increase greenhouse gas emission in cold seasons. Exotic wetland soils had higher carbon stock as compared to their respective native counterparts but their carbon stocks were offset by a larger proportion because of their higher greenhouse gas emissions. Annual total soil–atmosphere fluxes of greenhouse gases reduced soil carbon burial benefits by 8.1%, 9.5%, 6.4% and 7.2% for Kandelia, Sonneratia, Cyperus and Spartina, respectively, which narrowed down the gaps in net soil carbon stock between native and exotic wetlands. The results indicated that the invasion of exotic wetland plants might convert local coastal soils into a considerable atmospheric source of greenhouse gases although they at the same time increase soil carbon accumulation

  7. Soil greenhouse gas fluxes during wetland forest retreat along the Lower Savannah River, Georgia (USA)

    Science.gov (United States)

    Krauss, Ken W.; Whitbeck, Julie L.

    2012-01-01

    Tidal freshwater forested wetlands (tidal swamps) are periodically affected by salinity intrusion at seaward transitions with marsh, which, along with altered hydrology, may affect the balance of gaseous carbon (C) and nitrogen (N) losses from soils. We measured greenhouse gas emissions (CO2, CH4, N2O) from healthy, moderately degraded, and degraded tidal swamp soils undergoing sea-level-rise-induced retreat along the lower Savannah River, Georgia, USA. Soil CO2 flux ranged from 90.2 to 179.1 mg CO2 m-2 h-1 among study sites, and was the dominant greenhouse gas emitted. CO2 flux differed among sites in some months, while CH4 and N2O fluxes were 0.18 mg CH4 m-2 h-1 and 1.23 μg N2O m-2 h-1, respectively, with no differences among sites. Hydrology, soil temperature, and air temperature, but not salinity, controlled the annual balance of soil CO2 emissions from tidal swamp soils. No clear drivers were found for CH4 or N2O emissions. On occasion, large ebbing or very low tides were even found to draw CO2 fluxes into the soil (dark CO2 uptake), along with CH4 and N2O. Overall, we hypothesized a much greater role for salinity and site condition in controlling the suite of greenhouse gases emitted from tidal swamps than we discovered, and found that CO2 emissions–not CH4 or N2O–contributed most to the global warming potential from these tidal swamp soils.

  8. Greenhouse gas reductions; not warranted, not beneficial

    International Nuclear Information System (INIS)

    Green, K.

    2003-01-01

    This report deals with climate change and greenhouse gas emissions, especially regional climate change predictions, from a sceptic's point of view. It rejects all the conventional evidence supporting claims of extreme man-made climate changes, dismissing them as alarmist and inherently uncertain. Similarly, it characterizes policy prescriptions based on this evidence as faulty and as measures which, if implemented, would do both current and future generations considerably more harm than good. Calls for energy efficiency and conservation, reliance on renewable energy sources, improved efficiency of conventional vehicles, hybrid and fuel-cell-driven cars, reducing the amount of driving, establishing greenhouse gas registries, are all dismissed as impractical, imposing higher costs on energy generally, slowing economic growth in the process, and scaring people to adopt unwise public policies by exaggerating the certainty of predictions about man-made climate change. While dismissing the arguments advanced by 'old-school' environmentalists, the report does not question the validity of the overall theory or details of the core greenhouse effect, its main targets are the anthropogenic components of the observed temperature record, and the evidence of a clear cause-and-effect link between anthropogenic forcing and changes in the Earth's surface temperature. Overall, the report dismisses the 'conventional' view of the extent of climate change, the cause of that change and the risk it poses. It emphasizes the limitations on economic freedom that proposed policies would inflict, and argues in favour of more studies to provide the foundation for a societal response based on a solid understanding of the science behind climate change, and the impact of proposed policy options. 32 refs., 2 figs

  9. NWT greenhouse gas strategy 2007-2011

    International Nuclear Information System (INIS)

    2007-03-01

    In response to concerns about climate change, the Government of the Northwest Territories (GNWT) is committed to working with federal, provincial and territorial governments to develop an equitable approach to Canada's international commitment to reduce national emissions to 6 per cent below 1990 levels by the year 2012. In 2001, the GNWT released its greenhouse gas strategy, which was subsequently revised after a review in 2005. This report discussed the GNWT's greenhouse gas strategy. It provided background information on global climate change and impacts in the Northwest Territories (NWT), NWT emission challenges, as well as the 2001 strategy and its renewal. The report also presented the strategy framework with reference to goals and objectives; principles; emissions inventory; forest carbon sinks and sources; and targets and measures. The report also presented the action plan for the community and residential sector; commercial and industrial sector; government sector; cross-cutting; and a summary of actions. Some of these 39 actions include energy conservation initiatives by the NWT Housing Corporation; community woodlot planning; community energy planning; commercial energy efficiency audits; and energy efficiency measures in industry. 2 tabs, 3 figs., 2 appendices

  10. GREENHOUSE GAS EMISSIONS, ESPECIALLY FROM TRAFFIC (Contribution to the analysis of greenhouse gas emissions, especially from traffic)

    OpenAIRE

    Brozović, Ivo; Regent, Aleksandar; Grgurević, Matea

    2014-01-01

    This paper presents the results of studies on the greenhouse gas emissions caused by human activities, especially the emissions originating from transport. Since the beginning of the industrial revolution until today a steady increase has been recorded in anthropogenic greenhouse gas emissions which increase the concentration of greenhouse gases (imission values) in the troposphere and thereby increase the intensity of the greenhouse effect. This paper analyzes the impacts of anthropoge...

  11. Review of the impacts of leaking CO 2 gas and brine on groundwater quality

    Energy Technology Data Exchange (ETDEWEB)

    Qafoku, Nikolla P.; Lawter, Amanda R.; Bacon, Diana H.; Zheng, Liange; Kyle, Jennifer; Brown, Christopher F.

    2017-06-01

    This review paper provides a synthetic view of the existing knowledge and summarizes data and findings of the recent literature on the subject of the potential leaking of CO2 from the deep subsurface storage reservoirs and the effects on aquifer quality. New ideas and concepts are developed and insights are also provided. The objectives of this paper are to: 1) present and discuss potential risks for groundwater degradation due to CO2 gas and brine exposure; 2) identify the set of geochemical data required to assess and predict aquifer responses to CO2 and brine leakage. Specifically, this paper will discuss the following issues: 1) Aquifer responses (such as changes in aqueous phase/groundwater chemical composition; changes in solid phase chemistry and mineralogy; changes in the extent and rate of reactions and processes and possible establishment of a new network of reactions and processes affecting or controlling overall mobility of major, minor, and trace elements; development of conceptual and reduced order models (ROMs) to describe and predict aquifer responses); 2) The degree of impact such as significant or insignificant changes in pH and major, minor, and trace element release that depend on the following controlling variables; the effect of leaking plume characteristics (gas composition, pure CO2 and/or CO2 -CH4 -H2S mixtures and brine concentration and composition (trace metals); aquifer properties [such as initial aqueous phase conditions and mineralogy: minerals controlling sediments’ response (e.g., calcite, Si bearing minerals, etc.)]; overview of relevant hydrogeological and geochemical processes related to the impact of CO2 gas and brine on groundwater quality; the fate of the elements released from sediments or transported with brine (such as precipitation/incorporation into minerals (calcite and other minerals), adsorption, electron transfer reactions, the role of natural attenuation; whether or not the release of metals following exposure to

  12. CO2 + N2O mixture gas hydrate formation kinetics and effect of soil minerals on mixture-gas hydrate formation process

    Science.gov (United States)

    Enkh-Amgalan, T.; Kyung, D.; Lee, W.

    2012-12-01

    CO2 mitigation is one of the most pressing global scientific topics in last 30 years. Nitrous oxide (N2O) is one of the main greenhouse gases (GHGs) defined by the Kyoto Protocol and its global warming potential (GWP) of one metric ton is equivalent to 310 metric tons of CO2. They have similar physical and chemical properties and therefore, mixture-gas (50% CO2 + 50% N2O) hydrate formation process was studied experimentally and computationally. There were no significant research to reduce N20 gas and we tried to make hydrate to mitigate N20 and CO2 in same time. Mixture gas hydrate formation periods were approximately two times faster than pure N2O hydrate formation kinetic in general. The fastest induction time of mixture-gas hydrate formation observed in Illite and Quartz among various soil mineral suspensions. It was also observed that hydrate formation kinetic was faster with clay mineral suspensions such as Nontronite, Sphalerite and Montmorillonite. Temperature and pressure change were not significant on hydrate formation kinetic; however, induction time can be significantly affected by various chemical species forming under the different suspension pHs. The distribution of chemical species in each mineral suspension was estimated by a chemical equilibrium model, PHREEQC, and used for the identification of hydrate formation characteristics in the suspensions. With the experimental limitations, a study on the molecular scale modeling has a great importance for the prediction of phase behavior of the gas hydrates. We have also performed molecular dynamics computer simulations on N2O and CO2 hydrate structures to estimate the residual free energy of two-phase (hydrate cage and guest molecule) at three different temperature ranges of 260K, 273K, and 280K. The calculation result implies that N2O hydrates are thermodynamically stable at real-world gas hydrate existing condition within given temperature and pressure. This phenomenon proves that mixture-gas could be

  13. CO2 Storage Capacity for Multi-Well Pads Scheme in Depleted Shale Gas Reservoirs

    Directory of Open Access Journals (Sweden)

    Zhan Meng

    2017-10-01

    Full Text Available As a promising technology to improve shale gas (SG recovery and CO2 storage capacity, the multi-well pads (MWPs scheme has gained more and more attention. The semi-analytical pressure-buildup method has been used to estimate CO2 storage capacity. It focuses on single multi-fractured horizontal wells (SMFHWs and does not consider multi-well pressure interference (MWPI induced by the MWPs scheme. This severely limits the application of this method as incidences of multi-well pressure interference have been widely reported. This paper proposed a new methodology to optimize the injection strategy of the MWPs scheme and maximize CO2 storage capacity. The new method implements numerical discretization, the superposition theory, Gauss elimination, and the Stehfest numerical algorithm to obtain pressure-buildup solutions for the MWPs scheme. The solution by the new method was validated with numerical simulation and pressure-buildup curves were generated to identify MWPI. Using the new method, we observed that the fracture number and fracture half-length have a positive influence on CO2 storage capacity. Both can be approximately related to the CO2 storage capacity by a linear correlation. For a given injection pressure, there is an optimal fracture number; the bigger the limited injection pressure, the smaller the optimal fracture number. Stress sensitivity has positive influences on CO2 storage capacity, thus extending the injection period would improve CO2 storage capacity. This work gains some insights into the CO2 storage capacity of the MWPs scheme in depleted SG reservoirs, and provides considerable guidance on injection strategies to maximize CO2 storage capacity in depleted SG reservoirs.

  14. The challenge of meeting Canada's greenhouse gas reduction targets

    International Nuclear Information System (INIS)

    Hughes, Larry; Chaudhry, Nikhil

    2011-01-01

    In 2007, the Government of Canada announced its medium- and long-term greenhouse gas (GHG) emissions reduction plan entitled Turning the Corner, proposed emission cuts of 20% below 2006 levels by 2020 and 60-70% below 2006 levels by 2050. A report from a Canadian government advisory organization, the National Round Table on Environment and Economy (NRTEE), Achieving 2050: A carbon pricing policy for Canada, recommended 'fast and deep' energy pathways to emissions reduction through large-scale electrification of Canada's economy by relying on a major expansion of hydroelectricity, adoption of carbon capture and storage for coal and natural gas, and increasing the use of nuclear. This paper examines the likelihood of the pathways being met by considering the report's proposed energy systems, their associated energy sources, and the magnitude of the changes. It shows that the pathways assume some combination of technological advances, access to secure energy supplies, or rapid installation in order to meet both the 2020 and 2050 targets. This analysis suggests that NRTEE's projections are optimistic and unlikely to be achieved. The analysis described in this paper can be applied to other countries to better understand and develop strategies that can help reduce global greenhouse gas emissions. - Research highlights: → An analysis of a Canadian government advisory organization's GHG reduction plans. → Hydroelectricity and wind development is overly optimistic. → Declining coal and natural gas supplies and lack of CO 2 storage may hamper CCS. → Changing precipitation patterns may limit nuclear and hydroelectricity. → Bioenergy and energy reduction policies largely ignored despite their promise.

  15. CO2utilization via a novel anaerobic bioprocess configuration with simulated gas mixture and real stack gas samples.

    Science.gov (United States)

    Daglioglu, S Tugce; Karabey, Burcin; Ozdemir, Guven; Azbar, Nuri

    2017-11-28

    CO 2 , which is considered to be one of the major causes of climate change, has reached to critical levels in the atmosphere due to tremendous consumption of fossil fuels all over the world. In this study, anaerobic bioconversion of CO 2 into bio-methane using a novel bioprocess configuration (HYBRID bioreactor) was studied under mesophilic conditions. Varying ratios of H 2 /CO 2 gas mixture and volumetric feeding rates were investigated and no additional organic matter and trace element were needed throughout the study. The maximum methane production of 19 m 3 CH 4 /m 3 reactor/ d was achieved at a H 2 /CO 2 ratio of 4:1 and feeding rate of 24 m 3 gas/m 3 reactor /d. It was determined that H 2 conversion rate is about 96%. For demonstration purpose, real stack gas sample from a petrochemical industry was also tested under optimized operational conditions. No inhibitory effect from stack gas mixture was observed. This study provided an environmentally friendly and sustainable solution for industries such as petrochemical industry in order to produce extra energy while capturing their waste CO 2 . Thereby, a sustainable and environmentally friendly model solution was presented for industries with high CO 2 emissions. COV: coefficient of variation; Gt: gigatone; IEA: International Energy Agency; IPCC: International Panel on Climate Change; MBBR: moving bed biofilm reactor; MJ: Megajoule; UASB: upflow anaerobic sludge blanket; VFR: volumetric feeding rate.

  16. HEAT RECOVERY FROM A NATURAL GAS POWERED INTERNAL COMBUSTION ENGINE BY CO2 TRANSCRITICAL POWER CYCLE

    Directory of Open Access Journals (Sweden)

    Mahmood Farzaneh-Gord

    2010-01-01

    Full Text Available The present work provides details of energy accounting of a natural gas powered internal combustion engine and achievable work of a utilized CO2 power cycle. Based on experimental performance analysis of a new designed IKCO (Iran Khodro Company 1.7 litre natural gas powered engine, full energy accounting of the engine were carried out on various engine speeds and loads. Further, various CO2 transcritical power cycle configurations have been appointed to take advantages of exhaust and coolant water heat lost. Based on thermodynamic analysis, the amount of recoverable work obtainable by CO2 transcritical power cycles have been calculated on various engine conditions. The results show that as much as 18 kW power could be generated by the power cycle. This would be considerable amount of power especially if compared with the engine brake power.

  17. COMPARISON OF CO2-EMISSIONS OF HOUSEHOLDS HEATED BY NATURAL GAS AND FIREWOOD

    Directory of Open Access Journals (Sweden)

    MÓNIKA PALÁDI

    2013-12-01

    Full Text Available In terms of climate protection, one of the most important questions is the reduction of the GHG emission. In this study, I compared CO2 -emission of households heated by natural gas and firewood, which had similar heated area and volume of air, considering the carbon-dioxide absorbing of forests of the households heated by firewood. Natural gas is a fossil fuel; however, the firewood (solid biomass is a renewable energy resource. One of the main features of renewable energy sources is to get into the atmosphere less CO2 than fossil fuels. The renewable energy resources emit into the air just as much CO2 as they absorb during their life cycle.

  18. Modeling of Gas Diffusion in Ni/YSZ Electrodes in CO2 and Co-electrolysis

    DEFF Research Database (Denmark)

    Duhn, Jakob Dragsbæk; Jensen, Anker Degn; Wedel, Stig

    2017-01-01

    to prevent its formation. For prediction of carbon formation, the gas composition in the electrode must be known. In this work, the diffusion of gases in the electrode has been modeled with the dusty gas model in 1 and 2 dimensions, and the effect of tortuosity, porosity, temperature, electrode thickness......Carbon formation may occur during CO2 and CO2/H2O electrolysis using solid oxide electrolyzer cells due to the Boudouard reaction (2CO →  CO2 + C(s)). Formed carbon may disintegrate the cell structure and it is therefore of importance to be able to predict when carbon is formed, and take actions......, pore diameter, current density, pitch and rib width has been investigated. It is shown that diffusion limitations on reactant/product transport may lead to carbon formation. The parameters describing the microstructure and the dimensions of the cathode channels and interconnect ribs are found to have...

  19. Removal of CO2 in closed loop off-gas treatment systems

    International Nuclear Information System (INIS)

    Clemens, M.K.; Nelson, P.A.; Swift, W.M.

    1994-01-01

    A closed loop test system has been installed at Argonne National Laboratory (ANL) to demonstrate off-gas treatment, absorption, and purification systems to be used for incineration and vitrification of hazardous and mixed waste. Closed loop systems can virtually eliminate the potential for release of hazardous or toxic materials to the atmosphere during both normal and upset conditions. In initial tests, a 250,000 Btu/h (75 kW thermal) combustor was operated in an open loop to produce a combustion product gas. The CO 2 in these tests was removed by reaction with a fluidized bed of time to produce CaCO 3 . Subsequently, recirculation system was installed to allow closed loop operation with the addition of oxygen to the recycle stream to support combustion. Commercially marketed technologies for removal of CO 2 can be adapted for use on closed loop incineration systems. The paper also describes the Absorbent Solution Treatment (AST) process, based on modifications to commercially demonstrated gas purification technologies. In this process, a side loop system is added to the main loop for removing CO 2 in scrubbing towers using aqueous-based CO 2 absorbents. The remaining gas is returned to the incinerator with oxygen addition. The absorbent is regenerated by driving off the CO 2 and water vapor, which are released to the atmosphere. Contaminants are either recycled for further treatment or form precipitates which are removed during the purification and regeneration process. There are no direct releases of gases or particulates to the environment. The CO 2 and water vapor go through two changes of state before release, effectively separating these combustion products from contaminants released during incineration. The AST process can accept a wide range of waste streams. The system may be retrofitted to existing Facilities or included in the designs for new installations

  20. Experimental and Numerical Modelling of CO2 Atmospheric Dispersion in Hazardous Gas Emission Sites.

    Science.gov (United States)

    Gasparini, A.; sainz Gracia, A. S.; Grandia, F.; Bruno, J.

    2015-12-01

    Under stable atmospheric conditions and/or in presence of topographic depressions, CO2 concentrations can reach high values resulting in lethal effect to living organisms. The distribution of denser than air gases released from the underground is governed by gravity, turbulence and dispersion. Once emitted, the gas distribution is initially driven by buoyancy and a gas cloud accumulates on the ground (gravitational phase); with time the density gradient becomes less important due to dispersion or mixing and gas distribution is mainly governed by wind and atmospheric turbulence (passive dispersion phase). Natural analogues provide evidences of the impact of CO2 leakage. Dangerous CO2 concentration in atmosphere related to underground emission have been occasionally reported although the conditions favouring the persistence of such a concentration are barely studied.In this work, the dynamics of CO2 in the atmosphere after ground emission is assessed to quantify their potential risk. Two approaches have been followed: (1) direct measurement of air concentration in a natural emission site, where formation of a "CO2 lake" is common and (2) numerical atmospheric modelling. Two sites with different morphology were studied: (a) the Cañada Real site, a flat terrain in the Volcanic Field of Campo de Calatrava (Spain); (b) the Solforata di Pomezia site, a rough terrain in the Alban Hills Volcanic Region (Italy). The comparison between field data and model calculations reveal that numerical dispersion models are capable of predicting the formation of CO2 accumulation over the ground as a consequence of underground gas emission. Therefore, atmospheric modelling could be included as a valuable methodology in the risk assessment of leakage in natural degassing systems and in CCS projects. Conclusions from this work provide clues on whether leakage may be a real risk for humans and under which conditions this risk needs to be included in the risk assessment.

  1. Monitoring greenhouse gas emissions in Australian landscapes: Comparing ground based mobile surveying data to GOSAT observations

    Science.gov (United States)

    Bashir, S.; Iverach, C.; Kelly, B. F. J.

    2016-12-01

    Climate change is threatening the health and stability of the natural world and human society. Such concerns were emphasized at COP21 conference in Paris 2015 which highlighted the global need to improve our knowledge of sources of greenhouse gas and to develop methods to mitigate the effects of their emissions. Ongoing spatial and temporal measurements of greenhouse gases at both point and regional scales is important for clarification of climate change mechanisms and accounting. The Greenhouse gas Observing SATellite (GOSAT) is designed to monitor the global distribution of carbon dioxide (CO2) and methane (CH4) from orbit. As existing ground monitoring stations are limited and still unevenly distributed, satellite observations provide important frequent, spatially extensive, but low resolution observations. Recent developments in portable laser based greenhouse gas measurement systems have enabled the rapid measurement of greenhouse gases in ppb at the ground surface. This study was conducted to map major sources of CO2 and CH4 in the eastern states of Australia at the landscape scale and to compare the results to GOSAT observations. During April 2016 we conducted a regional CH4 and CO2 mobile survey, using an LGR greenhouse gas analyzer. Measurements were made along a 4000 KM circuit through major cities, country towns, dry sclerophyll forests, coastal wetlands, coal mining regions, coal seam gas developments, dryland farming and irrigated agricultural landscapes. The ground-based survey data were then compared with the data (L2) from GOSAT. Ground-based mobile surveys showed that there are clear statistical differences in the ground level atmospheric concentration of CH4 and CO2 associated with all major changes in land use. These changes extend for kilometers, and cover one or more GOSAT pixels. In the coal mining districts the ground-level atmospheric concentration of CH4 exceeded 2 ppm for over 40 km, yet this was not discernable in the retrieved data (L2

  2. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2014-06-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

  3. Dynamics of CO 2 transport and injection strategies in a depleted gas field

    NARCIS (Netherlands)

    Veltin, J.; Belfroid, S.P.C.

    2012-01-01

    As Carbon Capture and Storage slowly gets accepted and integrated as a mean for cleaner utilization of fossil fuels, accurate knowledge of the transport of CO2 through pipelines and into wells becomes crucial. A representative North Sea transport and injection scenario into a depleted gas field is

  4. Development of CO2 and KrF gas lasers as drivers for inertial confinement fusion

    International Nuclear Information System (INIS)

    Rockwood, S.D.

    1983-01-01

    Several different driver systems are currently under development in the national ICF program. Los Alamos has traditionally emphasized gas laser systems because of their intrinsic high average power capability and ease of operation. This paper will review the status of activities in both carbon dioxide (CO 2 ) and krypton fluoride (KrF) development at the Laboratory

  5. CO2-mitigation options for the offshore oil and gas sector

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; Tock, Laurence; Breuhaus, Peter

    2016-01-01

    The offshore extraction of oil and gas is an energy-intensive process leading to the production of CO2and methane, discharged into the atmosphere, and of chemicals, rejected into the sea. The taxation of these emissions, in Norway, has encouraged the development of more energy...

  6. Electricity, Natural Gas and CO2 markets Observatory - 2. Quarter of 2013

    International Nuclear Information System (INIS)

    2013-06-01

    The purpose of the Observatory is to provide the general public with indicators for monitoring market deregulation. It both covers the wholesale and retail electricity and gas markets in Metropolitan France. Since 2013, it also covers the wholesale CO 2 market. This Observatory is updated every three months and data are available on CRE web site (www.cre.fr)

  7. New absorption liquids for the removal of CO2 from dilute gas streams using membrane contactors

    NARCIS (Netherlands)

    Kumar, P.S.; Hogendoorn, J.A.; Feron, P.H.M.; Versteeg, G.F.

    2002-01-01

    A new absorption liquid based on amino acid salts has been studied for CO2 removal in membrane gas–liquid contactors. Unlike conventional gas treating solvents like aqueous alkanolamines solutions, the new absorption liquid does not wet polyolefin microporous membranes. The wetting characteristics

  8. New absorption liquids for the removal of CO2 from dilute gas streams using mebrane contractors

    NARCIS (Netherlands)

    Kumar Paramasivam Senthil, P.S.; Hogendoorn, Kees; Feron, P.H.M.; Versteeg, Geert

    2002-01-01

    A new absorption liquid based on amino acid salts has been studied for CO2 removal in membrane gas–liquid contactors. Unlike conventional gas treating solvents like aqueous alkanolamines solutions, the new absorption liquid does not wet polyolefin microporous membranes. The wetting characteristics

  9. DFT study of the reactions of Mo and Mo with CO 2 in gas phase

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 123; Issue 3. DFT study of the reactions of Mo and Mo+ with CO2 in gas phase. Deman Han Guoliang Dai Hao Chen Hua Yan Junyong Wu Chuanfeng Wang Aiguo Zhong. Volume 123 Issue 3 May 2011 pp 299-309 ...

  10. Phase Behavior and Physical Parameters of Natural Gas Mixture with CO2

    Directory of Open Access Journals (Sweden)

    Dali Hou

    2015-01-01

    Full Text Available The two-flash experiment, constant composition expansion experiment, saturation pressure measurement experiment, and phase transition observation experiment from well bottom hole to well head of four high CO2 content natural gas samples were carried out by using the JEFRI-PVT apparatus made from DBR Company of Canada. The experimental results show that in the four high CO2 content gas samples no phase transitions will take place at temperatures greater than 35°C. In the gas-liquid two-phase region, saturation pressures, critical pressure, critical temperature, and an integrated P-T phase diagram of different CO2 content natural gases are calculated by using the modified PR equation of state and modified (T equation proposed by Saffari. The deviations between the saturation pressure calculated by using the model proposed in this study and experimental measured saturation pressure are very small; the average relative error is only 2.86%. Thus, the model can be used to predict the phase equilibrium parameters of high CO2 content natural gas.

  11. Livestock greenhouse gas emissions and mitigation potential in Europe.

    Science.gov (United States)

    Bellarby, Jessica; Tirado, Reyes; Leip, Adrian; Weiss, Franz; Lesschen, Jan Peter; Smith, Pete

    2013-01-01

    The livestock sector contributes considerably to global greenhouse gas emissions (GHG). Here, for the year 2007 we examined GHG emissions in the EU27 livestock sector and estimated GHG emissions from production and consumption of livestock products; including imports, exports and wastage. We also reviewed available mitigation options and estimated their potential. The focus of this review is on the beef and dairy sector since these contribute 60% of all livestock production emissions. Particular attention is paid to the role of land use and land use change (LULUC) and carbon sequestration in grasslands. GHG emissions of all livestock products amount to between 630 and 863 Mt CO2 e, or 12-17% of total EU27 GHG emissions in 2007. The highest emissions aside from production, originate from LULUC, followed by emissions from wasted food. The total GHG mitigation potential from the livestock sector in Europe is between 101 and 377 Mt CO2 e equivalent to between 12 and 61% of total EU27 livestock sector emissions in 2007. A reduction in food waste and consumption of livestock products linked with reduced production, are the most effective mitigation options, and if encouraged, would also deliver environmental and human health benefits. Production of beef and dairy on grassland, as opposed to intensive grain fed production, can be associated with a reduction in GHG emissions depending on actual LULUC emissions. This could be promoted on rough grazing land where appropriate. © 2012 Blackwell Publishing Ltd.

  12. Addressing biogenic greenhouse gas emissions from hydropower in LCA.

    Science.gov (United States)

    Hertwich, Edgar G

    2013-09-03

    The ability of hydropower to contribute to climate change mitigation is sometimes questioned, citing emissions of methane and carbon dioxide resulting from the degradation of biogenic carbon in hydropower reservoirs. These emissions are, however, not always addressed in life cycle assessment, leading to a bias in technology comparisons, and often misunderstood. The objective of this paper is to review and analyze the generation of greenhouse gas emissions from reservoirs for the purpose of technology assessment, relating established emission measurements to power generation. A literature review, data collection, and statistical analysis of methane and CO2 emissions are conducted. In a sample of 82 measurements, methane emissions per kWh hydropower generated are log-normally distributed, ranging from micrograms to 10s of kg. A multivariate regression analysis shows that the reservoir area per kWh electricity is the most important explanatory variable. Methane emissions flux per reservoir area are correlated with the natural net primary production of the area, the age of the power plant, and the inclusion of bubbling emissions in the measurement. Even together, these factors fail to explain most of the variation in the methane flux. The global average emissions from hydropower are estimated to be 85 gCO2/kWh and 3 gCH4/kWh, with a multiplicative uncertainty factor of 2. GHG emissions from hydropower can be largely avoided by ceasing to build hydropower plants with high land use per unit of electricity generated.

  13. Capacity expansion analysis of UGSs rebuilt from low-permeability fractured gas reservoirs with CO2 as cushion gas

    Directory of Open Access Journals (Sweden)

    Yufei Tan

    2016-11-01

    Full Text Available The techniques of pressurized mining and hydraulic fracturing are often used to improve gas well productivity at the later development stage of low-permeability carbonate gas reservoirs, but reservoirs are watered out and a great number of micro fractures are produced. Therefore, one of the key factors for underground gas storages (UGS rebuilt from low-permeability fractured gas reservoirs with CO2 as the cushion gas is how to expand storage capacity effectively by injecting CO2 to displace water and to develop control strategies for the stable migration of gas–water interface. In this paper, a mathematical model was established to simulate the gas–water flow when CO2 was injected into dual porosity reservoirs to displace water. Then, the gas–water interface migration rules while CO2 was injected in the peripheral gas wells for water displacement were analyzed with one domestic UGS rebuilt from fractured gas reservoirs as the research object. And finally, discussion was made on how CO2 dissolution, bottom hole flowing pressure (BHFP, CO2 injection rate and micro fracture parameters affect the stability of gas–water interface in the process of storage capacity expansion. It is shown that the speed of capacity expansion reaches the maximum value at the fifth cycle and then decreases gradually when UGS capacity is expanded in the pattern of more injection and less withdrawal. Gas–water interface during UGS capacity expansion is made stable due to that the solubility of CO2 in water varies with the reservoir pressure. When the UGS capacity is expanded at constant BHFP and the flow rate, the expansion speed can be increased effectively by increasing the BHFP and the injection flow rate of gas wells in the central areas appropriately. In the reservoir areas with high permeability and fracture-matrix permeability ratio, the injection flow rate should be reduced properly to prevent gas–water interface fingering caused by a high-speed flow

  14. Gas power plant with CO2 handling. A study of alternative technologies

    International Nuclear Information System (INIS)

    Bolland, Olav; Hagen, Roger I.; Maurstad, Ola; Tangen, Grethe; Juliussen, Olav; Svendsen, Hallvard

    2002-01-01

    The report documents a study which compares 12 different technologies for gas power plants with CO 2 handling. The additional costs in removing the CO 2 in connection with electricity production is calculated to at least 18-19 oere /kWh compared to conventional gas power production without CO 2 capture. The calculated extra costs are somewhat higher than previously published figures. The difference is mainly due to that the estimated costs for pipelines and injection system for CO 2 are higher than in other studies. The removal of CO 2 in connection with gas power production implies increased use of natural gas. The most developed technologies would lead to a procentual increase in the gas consumption per kWh electricity of 18-25%. Gas power plants based on the present technologies would have efficiencies in the size of 46-49%. The efficiency of power plants without CO 2 handling is supposed to be 58%. There is no foundation for pointing out a ''winner's' among the compared technologies in the study. The present available technologies excepted, there are no technology which stands out as better than the others from an economic viewpoint. Gas turbine with membrane based separation of oxygen from air (AZEP) has a potential for lower costs but implies challenging technological development and thence considerable technological risks. Two technologies, capture of carbon from natural gas previous to combustion and exhaust gas purification based on absorption, may be employed in 3 - 4 years. The other technologies require more development and maturing. Three of the technologies may be particularly interesting because hydrogen may be produced as a byproduct. Demonstration plant and choice of technology: 1) There is a limited need for demonstration plants with respect to technology development. 2) It is important for the technology development to be able to test various technologies in a laboratory or in a flexible pilot plant. 3) Many technologies and components may be

  15. Numerical simulation of CO2 separation from gas mixtures in membrane modules: Effect of chemical absorbent

    Directory of Open Access Journals (Sweden)

    Seyed Mohammad Reza Razavi

    2016-01-01

    Full Text Available In this study, a mathematical model is proposed for prediction of CO2 absorption from N2/CO2 mixture by potassium threonate in a hollow-fiber membrane contactor (HFMC. CFD technique using numerical method of finite element was applied to solve the governing equations of model. Effect of different factors on CO2 absorption was analyzed and for investigation of absorbent type effect, functioning of potassium threonate was compared with diethanolamine (DEA. Axial and radial diffusion can be described with the two dimensional model established in this work. The obtained simulation results were compared with the reported experimental data to ensure accuracy of the model predictions. Comparison of model results with experimental data revealed that the developed model can well predict CO2 capture by potassium threonate in HFMCs. Increment of absorbent flow rate and concentration eventuate in enhancement of CO2 absorption. On the other hand, capture of CO2 will be reduced with increment of gas flow rate. According to the model results, potassium threonate can be considered as a more efficient absorbent as compared with DEA.

  16. Relationships between carbonyl sulfide (COS) and CO2 during leaf gas exchange.

    Science.gov (United States)

    Stimler, Keren; Montzka, Stephen A; Berry, Joseph A; Rudich, Yinon; Yakir, Dan

    2010-06-01

    *Carbonyl sulfide (COS) exchange in C(3) leaves is linked to that of CO(2), providing a basis for the use of COS as a powerful tracer of gross CO(2) fluxes between plants and the atmosphere, a critical element in understanding the response of the land biosphere to global change. *Here, we carried out controlled leaf-scale gas-exchange measurements of COS and CO(2) in representative C(3) plants under a range of light intensities, relative humidities and temperatures, CO(2) and COS concentrations, and following abscisic acid treatments. *No 'respiration-like' emission of COS or detectable compensation point, and no cross-inhibition effects between COS and CO(2) were observed. The mean ratio of COS to CO(2) assimilation flux rates, A(s)/A(c), was c. 1.4 pmol micromol(-1) and the leaf relative uptake (assimilation normalized to ambient concentrations, (A(s)/A(c))(C(a)(c)/C(a)(s))) was 1.6-1.7 across species and conditions, with significant deviations under certain conditions. Stomatal conductance was enhanced by increasing COS, which was possibly mediated by hydrogen sulfide (H(2)S) produced from COS hydrolysis, and a correlation was observed between A(s) and leaf discrimination against C(18)OO. *The results provide systematic and quantitative information necessary for the use of COS in photosynthesis and carbon-cycle research on the physiological to global scales.

  17. CO2 adsorption on carbon models of organic constituents of gas shale and coal.

    Science.gov (United States)

    Liu, Yangyang; Wilcox, Jennifer

    2011-01-15

    Imperfections of the organic matrix in coal and gas shales are modeled using defective and defect-free graphene surfaces to represent the structural heterogeneity and related chemical nature of these complex systems. Based upon previous experimental investigations that have validated the stability and existence of defect sites in graphene, plane-wave electronic density functional theory (DFT) calculations have been performed to investigate the mechanisms of CO(2) adsorption. The interactions of CO(2) with different surfaces have been compared, and the physisorption energy of CO(2) on the defective graphene adsorption site with one carbon atom missing (monovacancy) is approximately 4 times as strong as that on a perfect defect-free graphene surface, specifically, with a physisorption energy of ∼210 meV on the monovacancy site compared to ∼50 meV on a perfect graphene surface. The energy associated with the chemisorption of CO(2) on the monovacancy site is substantially stronger at ∼1.72 eV. Bader charge, density of states, and vibrational frequency estimations were also carried out and the results indicate that the CO(2) molecule binds to the surface becoming more stable upon physisorption onto the monovacancy site followed by the original C═O bonds weakening upon CO(2) chemisorption onto the vacancy site.

  18. Gas temperature measurement in CH4/CO2 dielectric-barrier discharges by optical emission spectroscopy

    Science.gov (United States)

    Luque, Jorge; Kraus, Martin; Wokaun, Alexander; Haffner, Ken; Kogelschatz, Ulrich; Eliasson, Baldur

    2003-04-01

    The gas temperatures were determined by optical emission in a dielectric-barrier discharge at atmospheric pressure. The feed gases were either pure CH4 to yield higher hydrocarbons or CH4/CO2 mixtures to yield synthesis gas (H2/CO). The monitored emission was from the CH radical A 2Δ-X 2Π electronic system and the gas temperature range characterized was from 300 to 600 K. The technique described in this article enables the measurement of the neutral gas temperature in the discharge that is not accessible via conventional methodology using thermocouples. A bimodal rotational population distribution in the CH A 2Δ v'=0 state was determined in the investigated gas mixtures of CO2/CH4 and in pure methane. Most of the rotational population was at temperatures from 300 to 600 K depending on experimental conditions, which are only slightly higher than the set temperature of the reactor. A small fraction of the emitting species was found to have a much higher rotational temperature of ˜4000 K for the pure methane gas and the mixture of CO2 and CH4. The low temperature rotational distribution correlated with changes in the ambient conditions and is used as a thermometer, while the high rotational temperature component and the vibrational temperature reflect the excess of energy during the CH radical formation by electron impact dissociative excitation of methane, and the extent of collisional relaxation before emission takes place.

  19. Eocene Hyperthermal Climate Sensitivity to Greenhouse Gas and Aerosol Forcing

    Science.gov (United States)

    Winguth, A. M. E.; Hughlett, T. M.; Brown, M.; Rothstein, M.; Shields, C. A.; Winguth, C.

    2017-12-01

    A series of DeepMIP climate sensitivity experiments have been carried out with the Community Earth System Model CESM1.2 to evaluate how changes in the radiative forcing could have contributed to explain Eocene hyperthermal events. A rise in Eocene greenhouse gas forcing could have been linked to an increase in volcanism and associated destabilization of marine carbon reservoirs by dissociation of clathrathes, reorganization of the marine microbial loop, or terrestrial sources from e.g. wetlands. Such environmental changes could potentially have led to additional biophysical feedbacks altering the cloud aerosol optical depth for example by alteration of marine plankton productivity and DMS emissions to the atmosphere. The analysis of our simulations suggests a substantial warming from 3x to 12x CO2 PAL, reaching moderate temperatures of up to 20 °C over Antarctica and in the Article realm in the most extreme scenario, consistent to proxy estimates in a high CO2 world. The lower equator-to-pole temperature gradient compared to present-day is due to the lack of an ice sheet, an increase in greenhouse gases, and a lower cloud optical depth. The climate simulations suggest an intensified hydrological cycle with higher precipitation in the tropics, particularly over the Indian Eocene continent, and in mid-latitudes, whereas mega-droughts are prominent in the subtropics, particularly in Africa and South America. The Eocene geography (the closure of the Drake Passage and the more southern location of Australia) and a lower-than-present meridional temperature gradient contribute to a much weaker surface ocean circulation near the Antarctic continent as compared to the current pronounced Antarctic Circumpolar Current.

  20. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    International Nuclear Information System (INIS)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-01-01

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid-peak hours and

  1. Catalytic combustion of the retentate gas from a CO2/H2 separation membrane reactor for further CO2 enrichment and energy recovery

    International Nuclear Information System (INIS)

    Hwang, Kyung-Ran; Park, Jin-Woo; Lee, Sung-Wook; Hong, Sungkook; Lee, Chun-Boo; Oh, Duck-Kyu; Jin, Min-Ho; Lee, Dong-Wook; Park, Jong-Soo

    2015-01-01

    The CCR (catalytic combustion reaction) of the retentate gas, consisting of 90% CO 2 and 10% H 2 obtained from a CO 2 /H 2 separation membrane reactor, was investigated using a porous Ni metal catalyst in order to recover energy and further enrich CO 2 . A disc-shaped porous Ni metal catalyst, namely Al[0.1]/Ni, was prepared by a simple method and a compact MCR (micro-channel reactor) equipped with a catalyst plate was designed for the CCR. CO 2 and H 2 concentrations of 98.68% and 0.46%, respectively, were achieved at an operating temperature of 400 °C, GHSV (gas-hourly space velocity) of 50,000 h −1 and a H 2 /O 2 ratio (R/O) of 2 in the unit module. In the case of the MCR, a sheet of the Ni metal catalyst was easily installed along with the other metal plates and the concentration of CO 2 in the retentate gas increased up to 96.7%. The differences in temperatures measured before and after the CCR were 31 °C at the product outlet and 19 °C at the N 2 outlet in the MCR. The disc-shaped porous metal catalyst and MCR configuration used in this study exhibit potential advantages, such as high thermal transfer resulting in improved energy recovery rate, simple catalyst preparation, and easy installation of the catalyst in the MCR. - Highlights: • The catalytic combustion of a retentate gas obtained from the H 2 /CO 2 separation membrane. • A disc-shaped porous nickel metal catalyst and a micro-channel reactor for catalytic hydrogen combustion. • CO 2 enrichment up to 98.68% at 400 °C, 50,000 h −1 and H 2 /O 2 ratio of 2.

  2. Clouds in the atmospheres of extrasolar planets. IV. On the scattering greenhouse effect of CO2 ice particles: Numerical radiative transfer studies

    Science.gov (United States)

    Kitzmann, D.; Patzer, A. B. C.; Rauer, H.

    2013-09-01

    Context. Owing to their wavelength-dependent absorption and scattering properties, clouds have a strong impact on the climate of planetary atmospheres. The potential greenhouse effect of CO2 ice clouds in the atmospheres of terrestrial extrasolar planets is of particular interest because it might influence the position and thus the extension of the outer boundary of the classic habitable zone around main sequence stars. Such a greenhouse effect, however, is a complicated function of the CO2 ice particles' optical properties. Aims: We study the radiative effects of CO2 ice particles obtained by different numerical treatments to solve the radiative transfer equation. To determine the effectiveness of the scattering greenhouse effect caused by CO2 ice clouds, the radiative transfer calculations are performed over the relevant wide range of particle sizes and optical depths, employing different numerical methods. Methods: We used Mie theory to calculate the optical properties of particle polydispersion. The radiative transfer calculations were done with a high-order discrete ordinate method (DISORT). Two-stream radiative transfer methods were used for comparison with previous studies. Results: The comparison between the results of a high-order discrete ordinate method and simpler two-stream approaches reveals large deviations in terms of a potential scattering efficiency of the greenhouse effect. The two-stream methods overestimate the transmitted and reflected radiation, thereby yielding a higher scattering greenhouse effect. For the particular case of a cool M-type dwarf, the CO2 ice particles show no strong effective scattering greenhouse effect by using the high-order discrete ordinate method, whereas a positive net greenhouse effect was found for the two-stream radiative transfer schemes. As a result, previous studies of the effects of CO2 ice clouds using two-stream approximations overrated the atmospheric warming caused by the scattering greenhouse effect

  3. Enhanced greenhouse gas emissions from the Arctic with experimental warming

    Science.gov (United States)

    Voigt, Carolina; Lamprecht, Richard E.; Marushchak, Maija E.; Lind, Saara E.; Novakovskiy, Alexander; Aurela, Mika; Martikainen, Pertti J.; Biasi, Christina

    2017-04-01

    Temperatures in the Arctic are projected to increase more rapidly than in lower latitudes. With temperature being a key factor for regulating biogeochemical processes in ecosystems, even a subtle temperature increase might promote the release of greenhouse gases (GHGs) to the atmosphere. Usually, carbon dioxide (CO2) and methane (CH4) are the GHGs dominating the climatic impact of tundra. However, bare, patterned ground features in the Arctic have recently been identified as hot spots for nitrous oxide (N2O). N2O is a potent greenhouse gas, which is almost 300 times more effective in its global warming potential than CO2; but studies on arctic N2O fluxes are rare. In this study we examined the impact of temperature increase on the seasonal GHG balance of all three important GHGs (CO2, CH4 and N2O) from three tundra surface types (vegetated peat soils, unvegetated peat soils, upland mineral soils) in the Russian Arctic (67˚ 03' N 62˚ 55' E), during the course of two growing seasons. We deployed open-top chambers (OTCs), inducing air and soil surface warming, thus mimicking predicted warming scenarios. We combined detailed CO2, CH4 and N2O flux studies with concentration measurements of these gases within the soil profile down to the active layer-permafrost interface, and complemented these GHG measurements with detailed soil nutrient (nitrate and ammonium) and dissolved organic carbon (DOC) measurements in the soil pore water profile. In our study, gentle air warming (˜1.0 ˚ C) increased the seasonal GHG release of all dominant surface types: the GHG budget of vegetated peat and mineral soils, which together cover more than 80 % of the land area in our study region, shifted from a sink to a source of -300 to 144 g CO2-eq m-2 and from -198 to 105 g CO2-eq m-2, respectively. While the positive warming response was governed by CO2, we provide here the first in situ evidence that warming increases arctic N2O emissions: Warming did not only enhance N2O emissions from

  4. Mitigating greenhouse gas emissions: Voluntary reporting

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  5. UNEP greenhouse gas abatement costing studies

    International Nuclear Information System (INIS)

    Maya, R.S.; Nziramasanga, N.; Muguti, E.; Fenhann, J.

    1993-10-01

    The aim was to assess options and cost of reducing emissions of greenhouse gases (with emphasis on carbon dioxide) from human activity in Zimbabwe. A brief description of the country's economy and energy sector, policy and pricing and regulations is given and substantial data related to the country's economy, technology, energy consumption, emission and fuel prices are presented. The energy demand in households and for other sectors in Zimbabwe are assessed, and documented in the case of the former. The reference scenarios on energy demand and supply assess greenhouse gas emissions under conditions whereby the present economic growth trends predominate. Energy efficiency improvements are discussed. Abatement technology options are stated as afforestation for carbon sequestration, more efficient coal-fired industrial boilers, extended use of hydroelectricity, prepayment electric meters, minimum tillage, optimization of coal-fired tobacco barns, industrial power factor correction equipment, domestic biogas digesters, solar water heating systems, time switches in electric geysers, optimization of industrial furnaces, photovoltaic water pumps, production of ammonia from coal for fertilizing purposes, and recovery of coke oven gases for use in thermal power generation. (AB)

  6. Mixed microalgae consortia growth under higher concentration of CO2 from unfiltered coal fired flue gas: Fatty acid profiling and biodiesel production.

    Science.gov (United States)

    Aslam, Ambreen; Thomas-Hall, Skye R; Manzoor, Maleeha; Jabeen, Faiza; Iqbal, Munawar; Uz Zaman, Qamar; Schenk, Peer M; Asif Tahir, M

    2018-02-01

    Biodiesel is produced by transesterification of fatty acid methyl esters (FAME) from oleaginous microalgae feedstock. Biodiesel fuel properties were studied and compared with biodiesel standards. Qualitative analysis of FAME was done while cultivating mixed microalgae consortia under three concentrations of coal fired flue gas (1%, 3.0% and 5.5% CO 2 ). Under 1% CO 2 concentration (flue gas), the FAME content was 280.3 μg/mL, whereas the lipid content was 14.03 μg/mL/D (day). Both FAMEs and lipid contents were low at other CO 2 concentrations (3.0 and 5.5%). However, mixed consortia in the presence of phosphate buffer and flue gas (PB + FG) showed higher saturated fatty acids (SFA) (36.28%) and unsaturated fatty acids (UFA) (63.72%) versus 5.5% CO 2 concentration, which might be responsible for oxidative stability of biodiesel. Subsequently, higher cetane number (52) and low iodine value (136.3 gI 2 /100 g) biodiesel produced from mixed consortia (PB + FG) under 5.5% CO 2 along with 50 mM phosphate buffer were found in accordance with European (EN 14214) standard. Results revealed that phosphate buffer significantly enhanced the biodiesel quality, but reduced the FAME yield. This study intended to develop an integrated approach for significant improvement in biodiesel quality under surplus phosphorus by utilizing waste flue gas (as CO 2 source) using microalgae. The CO 2 sequestration from industrial flue gas not only reduced greenhouse gases, but may also ensure the sustainable and eco-benign production of biodiesel. Copyright © 2018. Published by Elsevier B.V.

  7. Designing building energy efficiency programs for greenhouse gas reductions

    International Nuclear Information System (INIS)

    Blackhurst, Michael; Lima Azevedo, Ines; Scott Matthews, H.; Hendrickson, Chris T.

    2011-01-01

    Costs and benefits of building energy efficiency are estimated as a means of reducing greenhouse gas emissions in Pittsburgh, PA and Austin, TX. The analysis includes electricity and natural gas consumption, covering 75% of building energy consumption in Pittsburgh and 85% in Austin. Two policy objectives were evaluated: maximize GHG reductions given initial budget constraints or maximize social savings given target GHG reductions. This approach evaluates the trade-offs between three primary and often conflicting program design parameters: initial capital constraints, social savings, and GHG reductions. Results suggest uncertainty in local stocks, demands, and efficiency significantly impacts anticipated outcomes. Annual GHG reductions of 1 ton CO 2 eq/capita/yr in Pittsburgh could cost near nothing or over $20 per capita annually. Capital-constrained policies generate slightly less social savings (a present value of a few hundred dollars per capita) than policies that maximize social savings. However, sectors and end uses targeted for intervention vary depending on policy objectives and constraints. Optimal efficiency investment strategies for some end uses vary significantly (in excess of 100%) between Pittsburgh and Austin, suggesting that resources and guidance conducted at the national scale may mislead state and local decision-makers. Results are used to provide recommendations for efficiency program administrators. - Highlights: → We use public data to estimate local building energy costs, benefits and greenhouse gas reductions. → We use optimization to evaluate trade-offs between program objectives and capital constraints. → Local energy market conditions significantly influence efficiency expectations. → Different program objectives can lead to different effective investment strategies. → We reflect on the implications of our results for efficiency program design.

  8. A breakthrough in flue gas cleanup, CO2 mitigation and H2S removal

    Energy Technology Data Exchange (ETDEWEB)

    Koch, Wolf; Wasas, James; Stenger, Raymond; Howell, Evan

    2010-09-15

    SWAPSOL Corp. is developing commercial processes around a newly discovered reaction that reduces H2S below detectable levels while reacting with CO2 to form water, sulfur and carsuls, a carbon-sulfur polymer. The Stenger-Wasas Process (SWAP) stands to simplify sulfur removal technology as it consumes CO2 in an exothermic reaction. The SWAP has applications in landfill, sour, flue and Claus tail gas cleanup and may replace Claus technology. Destruction of waste hydrocarbons provides a source of H2S. The primary reactions and variants have been independently verified and the chemical kinetics determined by a third party laboratory.

  9. [Effects of understory removal on soil greenhouse gas emissions in Carya cathayensis stands].

    Science.gov (United States)

    Liu, Juan; Chen, Xue-shuang; Wu, Jia-sen; Jiang, Pei-kun; Zhou, Guo-mo; Li, Yong-fu

    2015-03-01

    CO2, N2O and CH4 are important greenhouse gases, and soils in forest ecosystems are their important sources. Carya cathayensis is a unique tree species with seeds used for high-grade dry fruit and oil production. Understory vegetation management plays an important role in soil greenhouse gases emission of Carya cathayensis stands. A one-year in situ experiment was conducted to study the effects of understory removal on soil CO2, N2O and CH4 emissions in C. cathayensis plantation by closed static chamber technique and gas chromatography method. Soil CO2 flux had a similar seasonal trend in the understory removal and preservation treatments, which was high in summer and autumn, and low in winter and spring. N2O emission occurred mainly in summer, while CH4 emission showed no seasonal trend. Understory removal significantly decreased soil CO, emission, increased N2O emission and CH4 uptake, but had no significant effect on soil water soluble organic carbon and microbial biomass carbon. The global warming potential of soil greenhouse gases emitted in the understory removal. treatment was 15.12 t CO2-e . hm-2 a-1, which was significantly lower than that in understory preservation treatment (17.04 t CO2-e . hm-2 . a-1).

  10. Simple Synthesis of ZnCo2O4 Nanoparticles as Gas-sensing Materials

    Directory of Open Access Journals (Sweden)

    S. V. Bangale

    2011-11-01

    Full Text Available Semiconductive nanometer-size material ZnCo2O4 was synthesized by a solution combustion reaction of inorganic reagents of Zn(NO33. 6H2O, Co(NO33.6H2O and glycine as a fuel. The process was a convenient, environment friendly, inexpensive and efficient preparation method for the ZnCo2O4 nanomaterial. The synthesized materials were characterized by TG/DTA, XRD, EDX, SEM, and TEM. Conductance responses of the nanocrystalline ZnCo2O4 thick film were measured by exposing the film to reducing gases like Acetone, Ethanol, Ammonia (NH3, Hydrogen (H2, Hydrogen sulphide (H2S, Chlorine (Cl2 and Liquefied petroleum gas (LPG. It was found that the sensors exhibited various sensing responses to these gases at different operating temperature. Furthermore, the sensor exhibited a fast response and a good recovery. The results demonstrated that ZnCo2O4 can be used as a new type of gas-sensing material which has a high sensitivity and good selectivity to Liquefied petroleum gas (LPG at 100 ppm.

  11. CO and CO2 dual-gas detection based on mid-infrared wideband absorption spectroscopy

    Science.gov (United States)

    Dong, Ming; Zhong, Guo-qiang; Miao, Shu-zhuo; Zheng, Chuan-tao; Wang, Yi-ding

    2018-03-01

    A dual-gas sensor system is developed for CO and CO2 detection using a single broadband light source, pyroelectric detectors and time-division multiplexing (TDM) technique. A stepper motor based rotating system and a single-reflection spherical optical mirror are designed and adopted for realizing and enhancing dual-gas detection. Detailed measurements under static detection mode (without rotation) and dynamic mode (with rotation) are performed to study the performance of the sensor system for the two gas samples. The detection period is 7.9 s in one round of detection by scanning the two detectors. Based on an Allan deviation analysis, the 1σ detection limits under static operation are 3.0 parts per million (ppm) in volume and 2.6 ppm for CO and CO2, respectively, and those under dynamic operation are 9.4 ppm and 10.8 ppm for CO and CO2, respectively. The reported sensor has potential applications in various fields requiring CO and CO2 detection such as in the coal mine.

  12. Polyimide hollow fiber membranes for CO2 separation from wet gas mixtures

    Directory of Open Access Journals (Sweden)

    F. Falbo

    2014-12-01

    Full Text Available Matrimid®5218 hollow fiber membranes were prepared using the dry-wet spinning process. The transport properties were measured with pure gases (H2, CO2, N2, CH4 and O2 and with a mixture (30% CO2 and 70% N2 in dry and wet conditions at 25 ºC, 50 ºC, 60 ºC and 75 ºC and up to 600 kPa. Interesting values of single gas selectivity up to 60 ºC (between 31 and 28 for CO2/N2 and between 33 and 30 for CO2/CH4 in dry condition were obtained. The separation factor measured for the mixture was 20% lower compared to the single gas selectivity, in the whole temperature range analyzed. In saturation conditions the data showed that water influences the performance of the membranes, inducing a reduction of the permeance of all gases. Moreover, the presence of water caused a decrease of single gas selectivity and separation factor, although not so significant, highlighting the very high water resistance of hollow fiber membrane modules.

  13. Greenhouse Gas Emissions from Three Cage Layer Housing Systems

    Directory of Open Access Journals (Sweden)

    John Feddes

    2011-12-01

    Full Text Available Agriculture accounts for 10 to 12% of the World’s total greenhouse gas (GHG emissions. Manure management alone is responsible for 13% of GHG emissions from the agricultural sector. During the last decade, Québec’s egg production systems have shifted from deep-pit housing systems to manure belt housing systems. The objective of this study was to measure and compare carbon dioxide (CO2, methane (CH4 and nitrous oxide (N2O emissions from three different cage layer housing systems: a deep liquid manure pit and a manure belt with natural or forced air drying. Deep liquid manure pit housing systems consist of “A” frame layer cages located over a closed pit containing the hens’ droppings to which water is added to facilitate removal by pumping. Manure belt techniques imply that manure drops on a belt beneath each row of battery cages where it is either dried naturally or by forced air until it is removed. The experiment was replicated with 360 hens reared into twelve independent bench-scale rooms during eight weeks (19–27 weeks of age. The natural and forced air manure belt systems reduced CO2 (28.2 and 28.7 kg yr−1 hen−1, respectively, CH4 (25.3 and 27.7 g yr−1 hen−1, respectively and N2O (2.60 and 2.48 g yr−1 hen−1, respectively emissions by about 21, 16 and 9% in comparison with the deep-pit technique (36.0 kg CO2 yr−1 hen−1, 31.6 g CH4 yr−1 hen−1 and 2.78 g N2O yr−1 hen−1. The shift to manure belt systems needs to be encouraged since this housing system significantly decreases the production of GHG.

  14. Stakeholder resource information on greenhouse gas emissions

    International Nuclear Information System (INIS)

    1997-01-01

    Some of the many measures which have already been taken by the petroleum industry to safeguard the air, land and water were described in a background paper produced by the Petroleum Communication Foundation. It is entitled 'Canada's oil and gas industry and our global environment'. This complementary report includes a brief review of greenhouse gases and related issues such as the nature of global warming, Canadian emissions in a global context, the relationship between the economy and the environment, mitigation possibilities and successes achieved by actions such as those undertaken by the Voluntary Challenge and Registry (VCR) program. Also included are notes and quotes from authoritative sources regarding emissions, emissions control and success stories. A sample presentation was also provided that could be used to discuss global warming issues with general audiences and other communication activities. figs

  15. Greenhouse gas mitigation with scarce land

    DEFF Research Database (Denmark)

    Meyer-Aurich, A; Olesen, Jørgen E; Prochnow, A

    2013-01-01

    production. The surplus area could be used for energy production without affecting the land use necessary for food and feed production. We built a model to investigate the effect of changing nitrogen (N) fertilizer rates on cropping area required for a given amount of crops. We found that an increase...... should rather be used to produce crops at moderate fertilizer rate than to produce energy crops. This may change if farmers are forced to reduce their N input due to taxes or governmental regulations as it is the case in Denmark. However, with a fertilizer rate 10 % below the economical optimum......Agricultural lands have been identified to mitigate greenhouse gas (GHG) emissions primarily by production of energy crops and substituting fossil energy resources and through carbon sequestration in soils. Increased fertilizer input resulting in increased yields may reduce the area needed for crop...

  16. Air-water gas exchange and CO2 flux in a mangrove-dominated estuary

    Science.gov (United States)

    Ho, David T.; Ferrón, Sara; Engel, Victor C.; Larsen, Laurel G.; Barr, Jordan G.

    2014-01-01

    Mangrove forests are highly productive ecosystems, but the fate of mangrove-derived carbon remains uncertain. Part of that uncertainty stems from the fact that gas transfer velocities in mangrove-surrounded waters are not well determined, leading to uncertainty in air-water CO2 fluxes. Two SF6 tracer release experiments were conducted to determine gas transfer velocities (k(600) = 8.3 ± 0.4 and 8.1 ± 0.6 cm h−1), along with simultaneous measurements of pCO2 to determine the air-water CO2 fluxes from Shark River, Florida (232.11 ± 23.69 and 171.13 ± 20.28 mmol C m−2 d−1), an estuary within the largest contiguous mangrove forest in North America. The gas transfer velocity results are consistent with turbulent kinetic energy dissipation measurements, indicating a higher rate of turbulence and gas exchange than predicted by commonly used wind speed/gas exchange parameterizations. The results have important implications for carbon fluxes in mangrove ecosystems.

  17. Integrated underground gas storage of CO2 and CH4 for renewable energy storage for a test case in China

    Science.gov (United States)

    Kühn, Michael; Li, Qi; Nakaten, Natalie, Christine; Kempka, Thomas

    2017-04-01

    Integration and further development of the energy supply system in China is a major challenge for the years to come. Part of the strategy is the implementation of a low carbon energy system based on carbon dioxide capture and storage (CCS). The innovative idea presented here is based on an extension of the power-to-gas-to-power (PGP) technology by establishing a closed carbon dioxide cycle [1]. Thereto, hydrogen generated from excess renewable energy is transformed into methane for combustion in a combined cycle gas power plant. To comply with the fluctuating energy demand, carbon dioxide produced during methane combustion and required for the methanation process as well as excess methane are temporarily stored in two underground reservoirs located close to each other [2]. Consequently, renewable energy generation units can be operated even if energy demand is below consumption, while stored energy can be fed into the grid as energy demand exceeds production [3]. We studied a show case for Xinjiang in China [4] to determine the energy demand of the entire process chain based on numerical computer simulations for the operation of the CO2 and CH4 storage reservoirs, and to ascertain the pressure regimes present in the storage formations during the injection and production phases of the annual cycle. [1] Streibel M., Nakaten N., Kempka T., Kühn M. (2013) Analysis of an integrated carbon cycle for storage of renewables. Energy Procedia 40, 202-211. doi: 10.1016/j.egypro.2013.08.024. [2] Kühn M., Streibel M., Nakaten N.C., Kempka T. (2014) Integrated Underground Gas Storage of CO2 and CH4 to Decarbonise the "Power-to-gas-to-gas-to-power" Technology. Energy Procedia 59, 9-15. doi: 10.1016/j.egypro.2014.10.342 [3] Kühn M., Nakaten N.C., Streibel M., Kempka T. (2014) CO2 Geological Storage and Utilization for a Carbon Neutral "Power-to-gas-to-power" Cycle to Even Out Fluctuations of Renewable Energy Provision. Energy Procedia 63, 8044-8049. doi: 10.1016/j.egypro.2014

  18. Modeling greenhouse gas emissions from dairy farms.

    Science.gov (United States)

    Rotz, C Alan

    2017-11-15

    Dairy farms have been identified as an important source of greenhouse gas emissions. Within the farm, important emissions include enteric CH 4 from the animals, CH 4 and N 2 O from manure in housing facilities during long-term storage and during field application, and N 2 O from nitrification and denitrification processes in the soil used to produce feed crops and pasture. Models using a wide range in level of detail have been developed to represent or predict these emissions. They include constant emission factors, variable process-related emission factors, empirical or statistical models, mechanistic process simulations, and life cycle assessment. To fully represent farm emissions, models representing the various emission sources must be integrated to capture the combined effects and interactions of all important components. Farm models have been developed using relationships across the full scale of detail, from constant emission factors to detailed mechanistic simulations. Simpler models, based upon emission factors and empirical relationships, tend to provide better tools for decision support, whereas more complex farm simulations provide better tools for research and education. To look beyond the farm boundaries, life cycle assessment provides an environmental accounting tool for quantifying and evaluating emissions over the full cycle, from producing the resources used on the farm through processing, distribution, consumption, and waste handling of the milk and dairy products produced. Models are useful for improving our understanding of farm processes and their interacting effects on greenhouse gas emissions. Through better understanding, they assist in the development and evaluation of mitigation strategies for reducing emissions and improving overall sustainability of dairy farms. The Authors. Published by the Federation of Animal Science Societies and Elsevier Inc. on behalf of the American Dairy Science Association®. This is an open access article

  19. CO2 capture-sequestration

    International Nuclear Information System (INIS)

    Huffer, Elisabeth

    2008-01-01

    CO 2 capture-sequestration could be an acceptable temporary solution for the abatement of greenhouse gas releases to the atmosphere, before the implementation of new carbon-free power generation means. This paper briefly summarizes the principles of this technology: capture (post-combustion, oxi-combustion, pre-combustion); CO 2 transport and sequestration (deep saline aquifers, injection in depleted hydrocarbon reservoirs, injection in abandoned coal seams); examples of operations in progress

  20. Quantitative measurement of carbon isotopic composition in CO2 gas reservoir by Micro-Laser Raman spectroscopy

    Science.gov (United States)

    Li, Jiajia; Li, Rongxi; Zhao, Bangsheng; Guo, Hui; Zhang, Shuan; Cheng, Jinghua; Wu, Xiaoli

    2018-04-01

    The use of Micro-Laser Raman spectroscopy technology for quantitatively determining gas carbon isotope composition is presented. In this study, 12CO2 and 13CO2 were mixed with N2 at various molar fraction ratios to obtain Raman quantification factors (F12CO2 and F13CO2), which provide a theoretical basis for calculating the δ13C value. And the corresponding values were 0.523 (0 CO2/CN2 CO2/CN2 CO2/12CO2 binary mixtures when F12CO2/F13CO2 is 0.466972625. In addition, measurement of δ13C values by Micro-Laser Raman analysis were carried out on natural CO2 gas from Shengli Oil-field at room temperature under different pressures. The δ13C values obtained by Micro-Laser Raman spectroscopy technology and Isotope Ratio Mass Spectrometry (IRMS) technology are in good agreement with each other, and the relative errors range of δ13C values is 1.232%-6.964%. This research provides a fundamental analysis tool for determining gas carbon isotope composition (δ13C values) quantitatively by using Micro-Laser Raman spectroscopy. Experiment of results demonstrates that this method has the potential for obtaining δ13C values in natural CO2 gas reservoirs.

  1. Predicting mixed-gas adsorption equilibria on activated carbon for precombustion CO2 capture.

    Science.gov (United States)

    García, S; Pis, J J; Rubiera, F; Pevida, C

    2013-05-21

    We present experimentally measured adsorption isotherms of CO2, H2, and N2 on a phenol-formaldehyde resin-based activated carbon, which had been previously synthesized for the separation of CO2 in a precombustion capture process. The single component adsorption isotherms were measured in a magnetic suspension balance at three different temperatures (298, 318, and 338 K) and over a large range of pressures (from 0 to 3000-4000 kPa). These values cover the temperature and pressure conditions likely to be found in a precombustion capture scenario, where CO2 needs to be separated from a CO2/H2/N2 gas stream at high pressure (~1000-1500 kPa) and with a high CO2 concentration (~20-40 vol %). Data on the pure component isotherms were correlated using the Langmuir, Sips, and dual-site Langmuir (DSL) models, i.e., a two-, three-, and four-parameter model, respectively. By using the pure component isotherm fitting parameters, adsorption equilibrium was then predicted for multicomponent gas mixtures by the extended models. The DSL model was formulated considering the energetic site-matching concept, recently addressed in the literature. Experimental gas-mixture adsorption equilibrium data were calculated from breakthrough experiments conducted in a lab-scale fixed-bed reactor and compared with the predictions from the models. Breakthrough experiments were carried out at a temperature of 318 K and five different pressures (300, 500, 1000, 1500, and 2000 kPa) where two different CO2/H2/N2 gas mixtures were used as the feed gas in the adsorption step. The DSL model was found to be the one that most accurately predicted the CO2 adsorption equilibrium in the multicomponent mixture. The results presented in this work highlight the importance of performing experimental measurements of mixture adsorption equilibria, as they are of utmost importance to discriminate between models and to correctly select the one that most closely reflects the actual process.

  2. Life-cycle greenhouse gas assessment of Nigerian liquefied natural gas addressing uncertainty.

    Science.gov (United States)

    Safaei, Amir; Freire, Fausto; Henggeler Antunes, Carlos

    2015-03-17

    Natural gas (NG) has been regarded as a bridge fuel toward renewable sources and is expected to play a greater role in future global energy mix; however, a high degree of uncertainty exists concerning upstream (well-to-tank, WtT) greenhouse gas (GHG) emissions of NG. In this study, a life-cycle (LC) model is built to assess uncertainty in WtT GHG emissions of liquefied NG (LNG) supplied to Europe by Nigeria. The 90% prediction interval of GHG intensity of Nigerian LNG was found to range between 14.9 and 19.3 g CO2 eq/MJ, with a mean value of 16.8 g CO2 eq/MJ. This intensity was estimated considering no venting practice in Nigerian fields. The mean estimation can shift up to 25 g CO2 eq when considering a scenario with a higher rate of venting emissions. A sensitivity analysis of the time horizon to calculate GHG intensity was also performed showing that higher GHG intensity and uncertainty are obtained for shorter time horizons, due to the higher impact factor of methane. The uncertainty calculated for Nigerian LNG, specifically regarding the gap of data for methane emissions, recommends initiatives to measure and report emissions and further LC studies to identify hotspots to reduce the GHG intensity of LNG chains.

  3. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    Energy Technology Data Exchange (ETDEWEB)

    Greenblatt, Jeffery B.

    2013-10-10

    A California Greenhouse Gas Inventory Spreadsheet (GHGIS) model was developed to explore the impact of combinations of state policies on state greenhouse gas (GHG) and regional criteria pollutant emissions. The model included representations of all GHG- emitting sectors of the California economy (including those outside the energy sector, such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees of detail, and was carefully calibrated using available data and projections from multiple state agencies and other sources. Starting from basic drivers such as population, numbers of households, gross state product, numbers of vehicles, etc., the model calculated energy demands by type (various types of liquid and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three criteria pollutants: reactive organic gases (ROG), nitrogen oxides (NOx), and fine (2.5 ?m) particulate matter (PM2.5). Calculations were generally statewide, but in some sectors, criteria pollutants were also calculated for two regional air basins: the South Coast Air Basin (SCAB) and the San Joaquin Valley (SJV). Three scenarios were developed that attempt to model: (1) all committed policies, (2) additional, uncommitted policy targets and (3) potential technology and market futures. Each scenario received extensive input from state energy planning agencies, in particular the California Air Resources Board. Results indicate that all three scenarios are able to meet the 2020 statewide GHG targets, and by 2030, statewide GHG emissions range from between 208 and 396 MtCO2/yr. However, none of the scenarios are able to meet the 2050 GHG target of 85 MtCO2/yr, with emissions ranging from 188 to 444 MtCO2/yr, so additional policies will need to be developed for California to meet this stringent future target. A full sensitivity study of major scenario assumptions was also performed. In terms of criteria pollutants

  4. Tail gas treatment of sour-SEWGS CO2 product. Public version

    Energy Technology Data Exchange (ETDEWEB)

    Van Dijk, H.A.J. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

    2012-06-15

    This literature review covers the technologies suitable for the CO2-H2S separation within the context of CO2 purification of a pre-combustion captured stream intended for storage or reuse. The technologies considered cover existing industrially applied processes, emerging processes as well as processes in development. Several technologies capable of achieving the desired CO2-H2S separation were identified. Among them are liquid scrubbing processes Thiopaq and CrystaSulf producing elemental sulphur, selective oxidation to elemental sulphur such as MODOP or based on novel catalysts and sorbent-based (reactive) separations using low-, medium- or high-temperature (reactive) sorbents. SEWGS stands for Sorption Enhanced Water Gas Shift process.

  5. Optimized CO2-flue gas separation model for a coal fired power plant

    Energy Technology Data Exchange (ETDEWEB)

    Arachchige, Udara S.P.R. [Telemark University College, Porsgrunn (Norway); Mohsin, Muhammad [Telemark University College, Porsgrunn (Norway); Melaaen, Morten C. [Telemark University College, Porsgrunn (Norway); Tel-Tek, Porsgrunn (Norway)

    2013-07-01

    The detailed description of the CO2 removal process using mono-ethylamine (MEA) as a solvent for coal-fired power plant is present in this paper. The rate based Electrolyte NRTL activity coefficient model was used in the Aspen Plus. The complete removal process with re-circulating solvent back to the absorber was implemented with the sequential modular method in Aspen Plus. The most significant cost related to CO2 capture is the energy requirement for re-generating solvent, i.e. re-boiler duty. Parameters’ effects on re-boiler duty were studied, resulting decreased re-boiler duty with the packing height and absorber packing diameter, absorber pressure, solvent temperature, stripper packing height and diameter. On the other hand, with the flue gas temperature, re-boiler duty is increased. The temperature profiles and CO2 loading profiles were used to check the model behavior.

  6. Unusually large magmatic CO2 gas emissions prior to a basaltic paroxysm

    Science.gov (United States)

    Aiuppa, Alessandro; Burton, Mike; Caltabiano, Tommaso; Giudice, Gaetano; Guerrieri, Sergio; Liuzzo, Marco; Murè, Filippo; Salerno, Giuseppe

    2010-09-01

    The low-intensity activity of basaltic volcanoes is occasionally interrupted by short-lived but energetic explosions which, whilst frequently observed, are amongst the most enigmatic volcanic events in Nature. The combination of poorly understood and deep, challenging to measure, source processes make such events currently impossible to forecast. Here we report increases in quiescent degassing CO2 emissions (>10,000 t/day) prior to a powerful explosive event on Stromboli volcano on 15 March 2007. We interpret such large CO2 flux as being sourced by passive gas leakage from a deeply (>4 km) stored magma, whose depressurization, possibly caused by the onset of an effusive eruption on 28 February 2007, was the explosion trigger. Our observations suggest that continuous CO2 flux monitoring may allow anomalously large explosions to be accurately forecast at basaltic volcanoes.

  7. A new estimation of global soil greenhouse gas fluxes using a simple data-oriented model.

    Science.gov (United States)

    Hashimoto, Shoji

    2012-01-01

    Soil greenhouse gas fluxes (particularly CO(2), CH(4), and N(2)O) play important roles in climate change. However, despite the importance of these soil greenhouse gases, the number of reports on global soil greenhouse gas fluxes is limited. Here, new estimates are presented for global soil CO(2) emission (total soil respiration), CH(4) uptake, and N(2)O emission fluxes, using a simple data-oriented model. The estimated global fluxes for CO(2) emission, CH(4) uptake, and N(2)O emission were 78 Pg C yr(-1) (Monte Carlo 95% confidence interval, 64-95 Pg C yr(-1)), 18 Tg C yr(-1) (11-23 Tg C yr(-1)), and 4.4 Tg N yr(-1) (1.4-11.1 Tg N yr(-1)), respectively. Tropical regions were the largest contributor of all of the gases, particularly the CO(2) and N(2)O fluxes. The soil CO(2) and N(2)O fluxes had more pronounced seasonal patterns than the soil CH(4) flux. The collected estimates, including both the previous and the present estimates, demonstrate that the means of the best estimates from each study were 79 Pg C yr(-1) (291 Pg CO(2) yr(-1); coefficient of variation, CV = 13%, N = 6) for CO(2), 21 Tg C yr(-1) (29 Tg CH(4) yr(-1); CV = 24%, N = 24) for CH(4), and 7.8 Tg N yr(-1) (12.2 Tg N(2)O yr(-1); CV = 38%, N = 11) for N(2)O. For N(2)O, the mean of the estimates that was calculated by excluding the earliest two estimates was 6.6 Tg N yr(-1) (10.4 Tg N(2)O yr(-1); CV = 22%, N = 9). The reported estimates vary and have large degrees of uncertainty but their overall magnitudes are in general agreement. To further minimize the uncertainty of soil greenhouse gas flux estimates, it is necessary to build global databases and identify key processes in describing global soil greenhouse gas fluxes.

  8. System for δ13C–CO2 and xCO2 analysis of discrete gas samples by cavity ring-down spectroscopy

    Directory of Open Access Journals (Sweden)

    D. Dickinson

    2017-11-01

    Full Text Available A method was devised for analysing small discrete gas samples (50 mL syringe by cavity ring-down spectroscopy (CRDS. Measurements were accomplished by inletting 50 mL syringed samples into an isotopic-CO2 CRDS analyser (Picarro G2131-i between baseline readings of a reference air standard, which produced sharp peaks in the CRDS data feed. A custom software script was developed to manage the measurement process and aggregate sample data in real time. The method was successfully tested with CO2 mole fractions (xCO2 ranging from  <  0.1 to  >  20 000 ppm and δ13C–CO2 values from −100 up to +30 000 ‰ in comparison to VPDB (Vienna Pee Dee Belemnite. Throughput was typically 10 samples h−1, with 13 h−1 possible under ideal conditions. The measurement failure rate in routine use was ca. 1 %. Calibration to correct for memory effects was performed with gravimetric gas standards ranging from 0.05 to 2109 ppm xCO2 and δ13C–CO2 levels varying from −27.3 to +21 740 ‰. Repeatability tests demonstrated that method precision for 50 mL samples was ca. 0.05 % in xCO2 and 0.15 ‰ in δ13C–CO2 for CO2 compositions from 300 to 2000 ppm with natural abundance 13C. Long-term method consistency was tested over a 9-month period, with results showing no systematic measurement drift over time. Standardised analysis of discrete gas samples expands the scope of application for isotopic-CO2 CRDS and enhances its potential for replacing conventional isotope ratio measurement techniques. Our method involves minimal set-up costs and can be readily implemented in Picarro G2131-i and G2201-i analysers or tailored for use with other CRDS instruments and trace gases.

  9. Greenhouse Gas Emissions in the Netherlands 1990-2010. National Inventory Report 2012

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Van der Hoek, K.W.; Te Molder, R.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C.W.M.; Zijlema, P.J.; Van den Berghe, A.C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J.D.; Brandt, A.T. [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J.A.; Peek, C.J.; Vonk, J.; Van den Wyngaert, I. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  10. Greenhouse Gas Emissions in the Netherlands 1990-2009. National Inventory Report 2011

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Van der Hoek, K.W.; Te Molder, R.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C.W.M.; Zijlema, P.J.; Van den Berghe, A.C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J.D.; Brandt, A.T. [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J.A.; Peek, C.J.; Vonk, J.; Van den Wyngaert, I. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  11. Greenhouse Gas Emissions in the Netherlands 1990-2011. National Inventory Report 2013

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Zijlema, P.J. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Arets, E.J.M.M. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Van den Berghe, A.C.W.M. [Rijkswaterstaat, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Brandt, A.T. [Dutch Emissions Authority NEa, P.O. Box 91503, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [PBL Netherlands Environmental Assessment Agency, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Van der Maas, C.W.M.; Te Biesebeek, J.D.; Van der Hoek, K.W.; Te Molder, R.; Montfoort, J.A.; Peek, C.J.; Vonk, J. [National Institute of Public Health and Environmental Protection RIVM, Bilthoven (Netherlands)

    2013-04-15

    Total greenhouse gas emissions from The Netherlands in 2011 decreased by approximately 7 per cent compared with 2010 emissions. This decrease is mainly the result of decreased fuel combustion in the Energy sector (less electricity production) and in the petrochemical industry. Fuel use for space heating decreased due to the mild winter compared with the very cold 2010 winter. In 2011, total direct greenhouse gas emissions (excluding emissions from LULUCF (land use, land use change and forestry) in The Netherlands amounted to 194.4 Tg CO2 eq. This is approximately 9 per cent below the emissions in the base year 2 (213.2 Tg CO2 eq). This report documents the Netherlands' 2012 annual submission of its greenhouse gas emissions inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  12. The role of process intensification in cutting greenhouse gas emissions

    International Nuclear Information System (INIS)

    Reay, David

    2008-01-01

    Between 1900 and 1955 the average rate of global energy use rose from about 1 TW to 2 TW. Between 1955 and 1999 energy use rose from 2 TW to about 12 TW, and to 2006 a further 16% growth in primary energy use was recorded world-wide. There are recommendations by the UK Royal Commission on Environmental Pollution, subsequently supported by others in the UK, that we need to reduce CO 2 emissions by over 50% in order to stabilise their impact on global warming (CO 2 being the principal gas believed to be contributing to this phenomenon). One way in which we can address this is by judicious use of process intensification technology. Process intensification may be defined as: 'Any engineering development that leads to a substantially smaller, cleaner, safer and more energy-efficient technology.' It is most often characterised by a huge reduction in plant volume - orders of magnitude - but its contribution to reducing greenhouse gas emissions may also be significant. Potential energy savings due to investment in process intensification were studied by several UK organisations in the mid 1990s, to assist the UK Government in formulating a strategy on intensification. It is relevant to the themes of the PRES 07 Conference that process integration features in these analyses. Overall plant intensification in the UK was identified as having a technical potential of 40 PJ/year (about 1 million tonnes of oil equivalent/annum). The total potential energy savings due to investment in process intensification in a range of process unit operations were predicted to be over 74 PJ/year (1 PJ = 10 15 J). Projections for The Netherlands suggest that savings of 50-100 PJ/year should be achieved across chemicals and food processing by 2050. Substantial benefits to industry in the USA are highlighted by US Department of Energy studies. This paper relates by discussion and example process intensification to the main themes of the PRES 07 Conference, including process integration. It also

  13. Net global warming potential and greenhouse gas intensity

    Science.gov (United States)

    Various methods exist to calculate global warming potential (GWP) and greenhouse gas intensity (GHG) as measures of net greenhouse gas (GHG) emissions from agroecosystems. Little is, however, known about net GWP and GHGI that account for all sources and sinks of GHG emissions. Sources of GHG include...

  14. Greenhouse Gas Emissions Calculator for Grain and Biofuel Farming Systems

    Science.gov (United States)

    McSwiney, Claire P.; Bohm, Sven; Grace, Peter R.; Robertson, G. Philip

    2010-01-01

    Opportunities for farmers to participate in greenhouse gas (GHG) credit markets require that growers, students, extension educators, offset aggregators, and other stakeholders understand the impact of agricultural practices on GHG emissions. The Farming Systems Greenhouse Gas Emissions Calculator, a web-based tool linked to the SOCRATES soil…

  15. USDA Northeast climate hub greenhouse gas mitigation workshop technical report

    Science.gov (United States)

    In April 2015, USDA Secretary Vilsack announced the Greenhouse Gas Building Blocks for Climate Smart Agriculture and Forestry in an effort to reduce greenhouse gas emissions, increase carbon sequestration, and expand renewable energy production in the agricultural and forestry sectors. This initiati...

  16. Simulation of Transcritical CO2 Refrigeration System with Booster Hot Gas Bypass in Tropical Climate

    Science.gov (United States)

    Santosa, I. D. M. C.; Sudirman; Waisnawa, IGNS; Sunu, PW; Temaja, IW

    2018-01-01

    A Simulation computer becomes significant important for performance analysis since there is high cost and time allocation to build an experimental rig, especially for CO2 refrigeration system. Besides, to modify the rig also need additional cos and time. One of computer program simulation that is very eligible to refrigeration system is Engineering Equation System (EES). In term of CO2 refrigeration system, environmental issues becomes priority on the refrigeration system development since the Carbon dioxide (CO2) is natural and clean refrigerant. This study aims is to analysis the EES simulation effectiveness to perform CO2 transcritical refrigeration system with booster hot gas bypass in high outdoor temperature. The research was carried out by theoretical study and numerical analysis of the refrigeration system using the EES program. Data input and simulation validation were obtained from experimental and secondary data. The result showed that the coefficient of performance (COP) decreased gradually with the outdoor temperature variation increasing. The results show the program can calculate the performance of the refrigeration system with quick running time and accurate. So, it will be significant important for the preliminary reference to improve the CO2 refrigeration system design for the hot climate temperature.

  17. A catchment-scale carbon and greenhouse gas budget of a subarctic landscape

    DEFF Research Database (Denmark)

    Christensen, Torben R; Johansson, Torbjörn; Olsrud, Maria

    2007-01-01

    forest, and mires, lakes and alpine ecosystems. The magnitudes of atmospheric exchange of carbon in the form of the GHGs, CO2 and CH4 in these various ecosystems differ significantly, ranging from little or no flux in barren ecosystems over a small CO2 sink function and low rates of CH4 exchange......This is the first attempt to budget average current annual carbon (C) and associated greenhouse gas (GHG) exchanges and transfers in a subarctic landscape, the Lake Torneträsk catchment in northern Sweden. This is a heterogeneous area consisting of almost 4000km2 of mixed heath, birch and pine...

  18. Approach for Self-Calibrating CO2 Measurements with Linear Membrane-Based Gas Sensors

    Directory of Open Access Journals (Sweden)

    Detlef Lazik

    2016-11-01

    Full Text Available Linear membrane-based gas sensors that can be advantageously applied for the measurement of a single gas component in large heterogeneous systems, e.g., for representative determination of CO2 in the subsurface, can be designed depending on the properties of the observation object. A resulting disadvantage is that the permeation-based sensor response depends on operating conditions, the individual site-adapted sensor geometry, the membrane material, and the target gas component. Therefore, calibration is needed, especially of the slope, which could change over several orders of magnitude. A calibration-free approach based on an internal gas standard is developed to overcome the multi-criterial slope dependency. This results in a normalization of sensor response and enables the sensor to assess the significance of measurement. The approach was proofed on the example of CO2 analysis in dry air with tubular PDMS membranes for various CO2 concentrations of an internal standard. Negligible temperature dependency was found within an 18 K range. The transformation behavior of the measurement signal and the influence of concentration variations of the internal standard on the measurement signal were shown. Offsets that were adjusted based on the stated theory for the given measurement conditions and material data from the literature were in agreement with the experimentally determined offsets. A measurement comparison with an NDIR reference sensor shows an unexpectedly low bias (<1% of the non-calibrated sensor response, and comparable statistical uncertainty.

  19. Analyzing the Effects of Car Sharing Services on the Reduction of Greenhouse Gas (GHG Emissions

    Directory of Open Access Journals (Sweden)

    Jiyeon Jung

    2018-02-01

    Full Text Available This study examines the environmental impacts of roundtrip car sharing services by investigating transportation behavior. Car sharing should contribute to reduced greenhouse gas GHG emissions; however, such schemes include both positive and negative environmental effects, including: (1 reduced CO2e (carbon dioxide equivalent from substituting private vehicle use for more fuel-efficient car sharing vehicles, (2 increased CO2e as car-less individuals switch from public transit to car sharing vehicles and (3 reduced CO2e due to fewer vehicles. This study examines the impacts of this modal shift on greenhouse gas (GHG emissions using three types of models: a mixed logit model to analyze car sharing service preferences; a binary logit model to analyze whether individuals are willing to forgo vehicle ownership or planned purchases to use car sharing services; and a linear regression to determine how much private vehicle or public transportation use would be replaced by car sharing and the resulting effects on mobility. Total emissions from the current car sharing market equal 1,025,589.36 t CO2e/year. However, an increase in electric vehicle (EV charging stations to 50% of the number of gasoline-fuel stations would increase the probability of electric car sharing vehicle use, thereby reducing emissions by 655,773 t CO2e. This study shows that forgoing vehicle purchases does not offset the increased GHG emissions caused by the shift from public transportation or private vehicle use to car sharing.

  20. Estimating greenhouse gas fluxes from constructed wetlands used for water quality improvement

    Directory of Open Access Journals (Sweden)

    Sukanda Chuersuwan

    2014-06-01

    Full Text Available Methane (CH4 , nitrous oxide (N2O and carbon dioxide (CO2 fluxes were evaluated from constructed wetlands (CWs used to improve domestic wastewater quality. Experiments employed subsurface flow (SF and free water surface flow (FWS CWs planted with Cyperus spp. Results showed seasonal fluctuations of greenhouse gas fluxes. Greenhouse gas fluxes from SF-CWs and FWS-CWS were significantly different (p<0.05 while pollutant removal efficiencies of both CWs were not significantly different. The average CH4 , N2O and CO2 fluxes from SF-CWs were 2.9±3.5, 1.0±1.7, and 15.2±12.3 mg/m2 /hr, respectively, corresponding to the average global warming potential (GWP of 392 mg CO2 equivalents/m2 /hr. For FWS-CWs, the average CH4 , N2O and CO2 fluxes were 5.9±4.8, 1.8±1.0, and 29.6±20.2 mg/m2 /hr, respectively, having an average GWP of 698 mg CO2 equivalents/m2 /hr. Thus, FWS-CWs have a higher GWP than SF-CWs when they were used as a system for domestic water improvement.

  1. CO2 abatement policies in the power sector under an oligopolistic gas market

    International Nuclear Information System (INIS)

    Hecking, Harald

    2014-01-01

    The paper at hand examines the power system costs when a coal tax or a fixed bonus for renewables is combined with CO 2 emissions trading. It explicitly accounts for the interaction between the power and the gas market and identifies three cost effects: First, a tax and a subsidy both cause deviations from the cost-efficient power market equilibrium. Second, these policies also impact the power sector's gas demand function as well as the gas market equilibrium and therefore have a feedback effect on power generation quantities indirectly via the gas price. Thirdly, by altering gas prices, a tax or a subsidy also indirectly affects the total costs of gas purchase by the power sector. However, the direction of the change in the gas price, and therefore the overall effect on power system costs, remains ambiguous. In a numerical analysis of the European power and gas market, I find using a simulation model integrating both markets that a coal tax affects gas prices ambiguously whereas a fixed bonus for renewables decreases gas prices. Furthermore, a coal tax increases power system costs, whereas a fixed bonus can decrease these costs because of the negative effect on the gas price. Lastly, the more market power that gas suppliers have, the stronger the outlined effects will be.

  2. Tailoring gas-phase CO2 electroreduction selectivity to hydrocarbons at Cu nanoparticles

    Science.gov (United States)

    Merino-Garcia, I.; Albo, J.; Irabien, A.

    2018-01-01

    Copper-based surfaces appear as the most active catalysts for CO2 electroreduction to hydrocarbons, even though formation rates and efficiencies still need to be improved. The aim of the present work is to evaluate the continuous gas-phase CO2 electroreduction to hydrocarbons (i.e. ethylene and methane) at copper nanoparticulated-based surfaces, paying attention to particle size influence (ranging from 25-80 nm) on reaction productivity, selectivity, and Faraday efficiency (FE) for CO2 conversion. The effect of the current density and the presence of a microporous layer within the working electrode are then evaluated. Copper-based gas diffusion electrodes are prepared by airbrushing the catalytic ink onto carbon supports, which are then coupled to a cation exchange membrane (Nafion) in a membrane electrode assembly. The results show that the use of smaller copper nanoparticles (25 nm) leads to a higher ethylene production (1148 μmol m-2 s-1) with a remarkable high FE (92.8%), at the same time, diminishing the competitive hydrogen evolution reaction in terms of FE. This work demonstrates the importance of nanoparticle size on reaction selectivity, which may be of help to design enhanced electrocatalytic materials for CO2 valorization to hydrocarbons.

  3. Greenhouse gas emission factors associated with rewetting of organic soils

    Directory of Open Access Journals (Sweden)

    D. Wilson

    2016-04-01

    Full Text Available Drained organic soils are a significant source of greenhouse gas (GHG emissions to the atmosphere. Rewetting these soils may reduce GHG emissions and could also create suitable conditions for return of the carbon (C sink function characteristic of undrained organic soils. In this article we expand on the work relating to rewetted organic soils that was carried out for the 2014 Intergovernmental Panel on Climate Change (IPCC Wetlands Supplement. We describe the methods and scientific approach used to derive the Tier 1 emission factors (the rate of emission per unit of activity for the full suite of GHG and waterborne C fluxes associated with rewetting of organic soils. We recorded a total of 352 GHG and waterborne annual flux data points from an extensive literature search and these were disaggregated by flux type (i.e. CO2, CH4, N2O and DOC, climate zone and nutrient status. Our results showed fundamental differences between the GHG dynamics of drained and rewetted organic soils and, based on the 100 year global warming potential of each gas, indicated that rewetting of drained organic soils leads to: net annual removals of CO2 in the majority of organic soil classes; an increase in annual CH4 emissions; a decrease in N2O and DOC losses; and a lowering of net GHG emissions. Data published since the Wetlands Supplement (n = 58 generally support our derivations. Significant data gaps exist, particularly with regard to tropical organic soils, DOC and N2O. We propose that the uncertainty associated with our derivations could be significantly reduced by the development of country specific emission factors that could in turn be disaggregated by factors such as vegetation composition, water table level, time since rewetting and previous land use history.

  4. Occurrence of greenhouse gases (CO2, N2O and CH4) in groundwater of the Walloon Region (Belgium).

    Science.gov (United States)

    Jurado, Anna; Borges, Alberto V.; Pujades, Estanislao; Hakoun, Vivien; Knöller, Kay; Brouyère, Serge

    2017-04-01

    Greenhouse gases (GHGs) are an environmental problem because their concentrations in the atmosphere have continuously risen since the industrial revolution. They can be indirectly transferred to the atmosphere through groundwater discharge into surface water bodies such as rivers. However, their occurrence is poorly evaluated in groundwater. The aim of this work is to identify the hydrogeological contexts (e.g., chalk and limestone aquifers) and the most conductive conditions for the generation of GHGs in groundwater at a regional scale. To this end, carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) concentrations, major and minor elements and environmental isotopes were monitored in several groundwater bodies of the Walloon Region (Belgium) from September 2014 to June 2016. The concentrations of GHGs in groundwater ranged from 1769 to 100519 ppm for the partial pressure of CO2 and from 0 to 1064 nmol/L and 1 to 37062 nmol/L for CH4 and N2O respectively. Overall, groundwater was supersaturated in GHGs with respect to atmospheric equilibrium, suggesting that groundwater contribute to the atmospheric GHGs budget. Prior inspection of the data suggested that N2O in groundwater can be produced by denitrification and nitrification. The most suitable conditions for the accumulation of N2O are promoted by intermediate dissolved oxygen concentrations (2.5-3 mg L-1) and the availability of nitrate (NO3-). These observations will be compared with the isotopes of NO3-. CH4 was less detected and at lower concentration than N2O, suggesting that groundwater redox conditions are not reducing enough to promoted the production of CH4. The results will be presented and discussed in detail in the presentation.

  5. Reducing cement's CO2 footprint

    Science.gov (United States)

    van Oss, Hendrik G.

    2011-01-01

    The manufacturing process for Portland cement causes high levels of greenhouse gas emissions. However, environmental impacts can be reduced by using more energy-efficient kilns and replacing fossil energy with alternative fuels. Although carbon capture and new cements with less CO2 emission are still in the experimental phase, all these innovations can help develop a cleaner cement industry.

  6. Greenhouse gas emission factor development for coal-fired power plants in Korea

    International Nuclear Information System (INIS)

    Jeon, Eui-Chan; Myeong, Soojeong; Sa, Jae-Whan; Kim, Jinsu; Jeong, Jae-Hak

    2010-01-01

    Accurate estimation of greenhouse gas emissions is essential for developing an appropriate strategy to mitigate global warming. This study examined the characteristics of greenhouse gas emission from power plants, a major greenhouse gas source in Korea. The power plants examined use bituminous coal, anthracite, and sub-bituminous coal as fuel. The CO 2 concentration from power plants was measured using GC-FID with methanizer. The amount of carbon, hydrogen, and calorific values in the input fuel was measured using an elemental analyzer and calorimeter. For fuel analysis, CO 2 emission factors for anthracite, bituminous coal, and sub-bituminous coal were 108.9, 88.4, and 97.9 Mg/kJ, respectively. The emission factors developed in this study were compared with those for IPCC. The results showed that CO 2 emission was 10.8% higher for anthracite, 5.5% lower for bituminous coal, and 1.9% higher for sub-bituminous coal than the IPCC figures.

  7. Modeling of Single and Dual Reservoir Porous Media Compressed Gas (Air and CO2) Storage Systems

    Science.gov (United States)

    Oldenburg, C. M.; Liu, H.; Borgia, A.; Pan, L.

    2017-12-01

    Intermittent renewable energy sources are causing increasing demand for energy storage. The deep subsurface offers promising opportunities for energy storage because it can safely contain high-pressure gases. Porous media compressed air energy storage (PM-CAES) is one approach, although the only facilities in operation are in caverns (C-CAES) rather than porous media. Just like in C-CAES, PM-CAES operates generally by injecting working gas (air) through well(s) into the reservoir compressing the cushion gas (existing air in the reservoir). During energy recovery, high-pressure air from the reservoir is mixed with fuel in a combustion turbine to produce electricity, thereby reducing compression costs. Unlike in C-CAES, the storage of energy in PM-CAES occurs variably across pressure gradients in the formation, while the solid grains of the matrix can release/store heat. Because air is the working gas, PM-CAES has fairly low thermal efficiency and low energy storage density. To improve the energy storage density, we have conceived and modeled a closed-loop two-reservoir compressed CO2 energy storage system. One reservoir is the low-pressure reservoir, and the other is the high-pressure reservoir. CO2 is cycled back and forth between reservoirs depending on whether energy needs to be stored or recovered. We have carried out thermodynamic and parametric analyses of the performance of an idealized two-reservoir CO2 energy storage system under supercritical and transcritical conditions for CO2 using a steady-state model. Results show that the transcritical compressed CO2 energy storage system has higher round-trip efficiency and exergy efficiency, and larger energy storage density than the supercritical compressed CO2 energy storage. However, the configuration of supercritical compressed CO2 energy storage is simpler, and the energy storage densities of the two systems are both higher than that of PM-CAES, which is advantageous in terms of storage volume for a given

  8. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 3. Quarter 2014

    International Nuclear Information System (INIS)

    2014-09-01

    The wholesale markets Observatory aims to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key Graphs and graphs) are detailed in the second part

  9. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 1. Quarter 2015

    International Nuclear Information System (INIS)

    2015-03-01

    The wholesale markets Observatory aims to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key Graphs and graphs) are detailed in the second part

  10. Phase equilibrium modeling of gas hydrate systems for CO2 capture

    DEFF Research Database (Denmark)

    Herslund, Peter Jørgensen; Thomsen, Kaj; Abildskov, Jens

    2012-01-01

    Two thermodynamic models capable of describing dissociation pressures of mixed gas clathrate hydrates formed from ternary mixtures of CO2, N2 and liquid water, are presented. Both of the models utilize the Cubic-Plus-Association (CPA) equation of state (EOS) for the thermodynamic description...... literature data for this system, it was not possible to determine unequivocally, which of the two models perform better....

  11. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 4. Quarter 2015

    International Nuclear Information System (INIS)

    2015-12-01

    The wholesale markets Observatory aims to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key Graphs and graphs) are detailed in the second part

  12. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 2. Quarter 2014

    International Nuclear Information System (INIS)

    2014-06-01

    The wholesale markets Observatory aims to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key Graphs and graphs) are detailed in the second part

  13. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 2. Quarter 2015

    International Nuclear Information System (INIS)

    2015-06-01

    The wholesale markets Observatory aims to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key Graphs and graphs) are detailed in the second part

  14. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 3. Quarter 2015

    International Nuclear Information System (INIS)

    2015-09-01

    The wholesale markets Observatory aims to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key Graphs and graphs) are detailed in the second part

  15. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 4. Quarter 2014

    International Nuclear Information System (INIS)

    2014-12-01

    The wholesale markets Observatory aims to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key Graphs and graphs) are detailed in the second part

  16. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 3. Quarter 2013

    International Nuclear Information System (INIS)

    2013-09-01

    The objective of this wholesale markets Observatory is to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key figures and graphs) are detailed in the second part

  17. Wholesale markets. Electricity, Natural Gas and CO2 markets Observatory - 4. Quarter 2013

    International Nuclear Information System (INIS)

    2013-12-01

    The objective of this wholesale markets Observatory is to provide general monitoring indicators of electricity, natural gas and CO 2 markets in France. This Observatory is updated on a Quarterly basis and published on CRE's web site (www.cre.fr). The first part of the report summarises the highlights of the Quarter. The indicators (main dates, key figures and graphs) are detailed in the second part

  18. Greenhouse gas emissions from solid waste in Beijing: The rising trend and the mitigation effects by management improvements.

    Science.gov (United States)

    Yu, Yongqiang; Zhang, Wen

    2016-04-01

    Disposal of solid waste poses great challenges to city managements. Changes in solid waste composition and disposal methods, along with urbanisation, can certainly affect greenhouse gas emissions from municipal solid waste. In this study, we analysed the changes in the generation, composition and management of municipal solid waste in Beijing. The changes of greenhouse gas emissions from municipal solid waste management were thereafter calculated. The impacts of municipal solid waste management improvements on greenhouse gas emissions and the mitigation effects of treatment techniques of greenhouse gas were also analysed. Municipal solid waste generation in Beijing has increased, and food waste has constituted the most substantial component of municipal solid waste over the past decade. Since the first half of 1950s, greenhouse gas emission has increased from 6 CO2-eq Gg y(-1)to approximately 200 CO2-eq Gg y(-1)in the early 1990s and 2145 CO2-eq Gg y(-1)in 2013. Landfill gas flaring, landfill gas utilisation and energy recovery in incineration are three techniques of the after-emission treatments in municipal solid waste management. The scenario analysis showed that three techniques might reduce greenhouse gas emissions by 22.7%, 4.5% and 9.8%, respectively. In the future, if waste disposal can achieve a ratio of 4:3:3 by landfill, composting and incineration with the proposed after-emission treatments, as stipulated by the Beijing Municipal Waste Management Act, greenhouse gas emissions from municipal solid waste will decrease by 41%. © The Author(s) 2016.

  19. A lot left over: Reducing CO2 emissions in the United States’ electric power sector through the use of natural gas

    International Nuclear Information System (INIS)

    Lafrancois, Becky A.

    2012-01-01

    As the leading contributor of greenhouse gas emissions, the electricity sector stands to be impacted by policies seeking to curtail emissions. Instead of increasing electricity from renewable resources or nuclear power facilities, an alternative approach to reducing emissions in the electric power sector is changing the dispatch order of fossil fuels. Important differences between fossil fuels, and in the technologies used to burn them, make it possible to substantially reduce emissions from the sector. On average, each gigawatt-year of electricity generation switched from coal to natural gas reduces CO 2 emissions by 59 percent. As a result of significant investments in natural gas fired power plants in the United States between 1998 and 2005, there is an opportunity for electricity producers to take advantage of underutilized capacity. This is the first study to closely examine the new capital additions and analyze the technical potential for reductions in emissions. The analysis finds that 188 GW of capacity may be available to replace coal-fired baseload electricity generation. Utilizing this excess gas-fired capacity will reduce the sector's CO 2 emissions by 23 to 42 percent and reduce overall U.S. CO 2 emissions between 9 percent and 17 percent. - Highlights: ► Utilizing recently built natural gas fired power plants can significantly reduce CO 2 emissions in the United States. ► CO 2 emissions from electricity production can be reduced by 23–42 percent. ► U.S. overall CO 2 emissions reduced by 9–17 percent.

  20. Uncertainties in the Norwegian greenhouse gas emission inventory

    Energy Technology Data Exchange (ETDEWEB)

    Flugsrud, Ketil; Hoem, Britta

    2011-11-15

    The national greenhouse gas (GHG) emission inventory is compiled from estimates based on emission factors and activity data and from direct measurements by plants. All these data and parameters will contribute to the overall inventory uncertainty. The uncertainties and probability distributions of the inventory input parameters have been assessed based on available data and expert judgements.Finally, the level and trend uncertainties of the national GHG emission inventory have been estimated using Monte Carlo simulation. The methods used in the analysis correspond to an IPCC tier 2 method, as described in the IPCC Good Practice Guidance (IPCC 2000) (IPCC 2000). Analyses have been made both excluding and including the sector LULUCF (land use, land-use change and forestry). The uncertainty analysis performed in 2011 is an update of the uncertainty analyses performed for the greenhouse gas inventory in 2006 and 2000. During the project we have been in contact with experts, and have collected information about uncertainty from them. Main focus has been on the source categories where changes have occured since the last uncertainty analysis was performed in 2006. This includes new methodology for several source categories (for example for solvents and road traffic) as well as revised uncertainty estimates. For the installations included in the emission trading system, new information from the annual ETS reports about uncertainty in activity data and CO2 emission factor (and N2O emission factor for nitric acid production) has been used. This has improved the quality of the uncertainty estimates for the energy and manufacturing sectors. The results show that the uncertainty level in the total calculated greenhouse gas emissions for 2009 is around 4 per cent. When including the LULUCF sector, the total uncertainty is around 17 per cent in 2009. The uncertainty estimate is lower now than previous analyses have shown. This is partly due to a considerable work made to improve

  1. Fighting global warming by greenhouse gas removal: destroying atmospheric nitrous oxide thanks to synergies between two breakthrough technologies.

    Science.gov (United States)

    Ming, Tingzhen; de Richter, Renaud; Shen, Sheng; Caillol, Sylvain

    2016-04-01

    Even if humans stop discharging CO2 into the atmosphere, the average global temperature will still increase during this century. A lot of research has been devoted to prevent and reduce the amount of carbon dioxide (CO2) emissions in the atmosphere, in order to mitigate the effects of climate change. Carbon capture and sequestration (CCS) is one of the technologies that might help to limit emissions. In complement, direct CO2 removal from the atmosphere has been proposed after the emissions have occurred. But, the removal of all the excess anthropogenic atmospheric CO2 will not be enough, due to the fact that CO2 outgases from the ocean as its solubility is dependent of its atmospheric partial pressure. Bringing back the Earth average surface temperature to pre-industrial levels would require the removal of all previously emitted CO2. Thus, the atmospheric removal of other greenhouse gases is necessary. This article proposes a combination of disrupting techniques to transform nitrous oxide (N2O), the third most important greenhouse gas (GHG) in terms of current radiative forcing, which is harmful for the ozone layer and possesses quite high global warming potential. Although several scientific publications cite "greenhouse gas removal," to our knowledge, it is the first time innovative solutions are proposed to effectively remove N2O or other GHGs from the atmosphere other than CO2.

  2. Is CO2 gas unsufflator necessary for laparoscopic training in animals?

    Directory of Open Access Journals (Sweden)

    Tiraboshi Ricardo Brianezi

    2003-01-01

    Full Text Available OBJECTIVE: To verify the efficacy and safety of compressed air to produce pneumoperitoneum for laparoscopic surgery in pigs for a training program of residence. METHODS: Dalland pigs weighing 15-17kg underwent general anethesia and mechanical ventilation. They were divided in 3 groups: A - (38 the pneumoperitnoneum was established with an automatic CO2 insufflator, B - (7 as in A except the CO2 gas was changed by compressed air, and C - (11 abdomen insufflation was obtained with compressed air directly from hospital pipe network system. Intra-abdominal pressure in all groups was kept between 12 and 15 mmHg. The laparoscopic procedures performed were distributed proportionally among groups: 20 bilateral nephrectomy, 20 dismembered pyeloplasty and 16 partial nephrectomy. Arterial blood sampling for gasometry was obtained before and 2h after establishment of pneumoperitoneum in 5 pigs of group C. RESULTS: The cost of 25 4,5kg CO2 container used in group A was R$ 3,150.00 (U$ 1,050.00. The mean length time of surgeries in groups A, B and C were respectively: 181±30min, 196±39min e 210±47min (p>0.05. Respiratory alkalosis occurred in 3 out of 5 pigs of group C. No animal exhibited signs of gas embolism or died during surgery. CONCLUSION: The use of compressed air for laparoscopy in pigs was safe, reduced costs and did not require the use of an automatic gas insufflator.

  3. Preface: Towards a full greenhouse gas balance of the biosphere

    DEFF Research Database (Denmark)

    Merbold, L.; Wohlfahrt, G.; Butterbach-Bahl, K.

    2015-01-01

    and modeling networks (Baldocchi et al., 2001; Friend et al., 2007; Raymond et al., 2013; Tranvik et al., 2009), similar information on the biosphere–atmosphere exchange of non-CO2 greenhouse gases (i.e., CH4 and N2O) is sparsely available in comparison. To date, a strong focus has been given to so-called high...

  4. Evaluation of the Life Cycle Greenhouse Gas Emissions from Different Biomass Feedstock Electricity Generation Systems

    Directory of Open Access Journals (Sweden)

    Akhil Kadiyala

    2016-11-01

    Full Text Available This paper evaluates life cycle greenhouse gas (GHG emissions from the use of different biomass feedstock categories (agriculture residues, dedicated energy crops, forestry, industry, parks and gardens, wastes independently on biomass-only (biomass as a standalone fuel and cofiring (biomass used in combination with coal electricity generation systems. The statistical evaluation of the life cycle GHG emissions (expressed in grams of carbon dioxide equivalent per kilowatt hour, gCO2e/kWh for biomass electricity generation systems was based on the review of 19 life cycle assessment studies (representing 66 biomass cases. The mean life cycle GHG emissions resulting from the use of agriculture residues (N = 4, dedicated energy crops (N = 19, forestry (N = 6, industry (N = 4, and wastes (N = 2 in biomass-only electricity generation systems are 291.25 gCO2e/kWh, 208.41 gCO2e/kWh, 43 gCO2e/kWh, 45.93 gCO2e/kWh, and 1731.36 gCO2e/kWh, respectively. The mean life cycle GHG emissions for cofiring electricity generation systems using agriculture residues (N = 10, dedicated energy crops (N = 9, forestry (N = 9, industry (N = 2, and parks and gardens (N = 1 are 1039.92 gCO2e/kWh, 1001.38 gCO2e/kWh, 961.45 gCO2e/kWh, 926.1 gCO2e/kWh, and 1065.92 gCO2e/kWh, respectively. Forestry and industry (avoiding the impacts of biomass production and emissions from waste management contribute the least amount of GHGs, irrespective of the biomass electricity generation system.

  5. Program Energy of the CNRS. Topic 10 combustion and capture of CO2. PRI 10.1. Capture by adsorption of the CO2 in thermal power plants gas and their injection in petroleum wells. Final report period 2002-2004

    International Nuclear Information System (INIS)

    Tondeur, D.

    2005-01-01

    In the framework of the global warming resulting of the greenhouse gases emission increase, the carbon dioxide capture and storage in deep underground cavities of old petroleum and gas deposits, are studied. This report presents the researches realized by the CNRS (France) in the domain: technology and knowledge assessment concerning the carbon dioxide capture and storage, active coals for the CO 2 capture, methodology of thermo-economical optimization of the combined cycle, global simulation of an IGCC (Integrated gasification combined cycle) with CO 2 capture and integration in the process scheme, petroleum recovery-aided by CO 2 injection, storage in geological deposits. (A.L.B.)

  6. Full energy chain analysis of greenhouse gas emissions from different energy sources

    International Nuclear Information System (INIS)

    Vate, J.F. van de

    1996-01-01

    The field of work of the Advisory Group Meeting/Workshop, i.e. full-energy chain emissions of greenhouse gases, is defined, and its environment, i.e. the Earth Summit -the 1992 UN Conference on Environment and Development in Rio-, is discussed. It is inferred that countries that ratified the Earth Summit's Convention on Climate Change have committed themselves to lower the greenhouse gas emissions from their energy use, and that this can be done most effectively by accounting in energy planning for the full-energy chain emissions of all greenhouse gases. The scatter in literature values of greenhouse gas emission factors of the full energy chain of individual energy sources is discussed. The scatter among others is due to different analytical methods, data bases and system boundaries, and due to neglect of the non-CO 2 greenhouse gases and professional biases. Generic values for greenhouse gas emission factors of energy and materials use are proposed. (author). 10 refs, 2 tabs

  7. High-accuracy continuous airborne measurements of greenhouse gases (CO2 and CH4) using the cavity ring-down spectroscopy (CRDS) technique

    NARCIS (Netherlands)

    Chen, H.; Winderlich, J.; Gerbig, C.; Hoefer, A.; Rella, C. W.; Crosson, E. R.; Van Pelt, A. D.; Steinbach, J.; Kolle, O.; Beck, V.; Daube, B. C.; Gottlieb, E. W.; Chow, V. Y.; Santoni, G. W.; Wofsy, S. C.

    2010-01-01

    High-accuracy continuous measurements of greenhouse gases (CO2 and CH4) during the BARCA (Balancao Atmosferico Regional de Carbono na Amazonia) phase B campaign in Brazil in May 2009 were accomplished using a newly available analyzer based on the cavity ring-down spectroscopy (CRDS) technique. This

  8. Deep microbial life in the Altmark natural gas reservoir: baseline characterization prior CO2 injection

    Science.gov (United States)

    Morozova, Daria; Shaheed, Mina; Vieth, Andrea; Krüger, Martin; Kock, Dagmar; Würdemann, Hilke

    2010-05-01

    Within the framework of the CLEAN project (CO2 Largescale Enhanced gas recovery in the Altmark Natural gas field) technical basics with special emphasis on process monitoring are explored by injecting CO2 into a gas reservoir. Our study focuses on the investigation of the in-situ microbial community of the Rotliegend natural gas reservoir in the Altmark, located south of the city Salzwedel, Germany. In order to characterize the microbial life in the extreme habitat we aim to localize and identify microbes including their metabolism influencing the creation and dissolution of minerals. The ability of microorganisms to speed up dissolution and formation of minerals might result in changes of the local permeability and the long-term safety of CO2 storage. However, geology, structure and chemistry of the reservoir rock and the cap rock as well as interaction with saline formation water and natural gases and the injected CO2 affect the microbial community composition and activity. The reservoir located at the depth of about 3500m, is characterised by high salinity fluid and temperatures up to 127° C. It represents an extreme environment for microbial life and therefore the main focus is on hyperthermophilic, halophilic anaerobic microorganisms. In consequence of the injection of large amounts of CO2 in the course of a commercial EGR (Enhanced Gas Recovery) the environmental conditions (e.g. pH, temperature, pressure and solubility of minerals) for the autochthonous microorganisms will change. Genetic profiling of amplified 16S rRNA genes are applied for detecting structural changes in the community by using PCR- SSCP (PCR-Single-Strand-Conformation Polymorphism) and DGGE (Denaturing Gradient Gel Electrophoresis). First results of the baseline survey indicate the presence of microorganisms similar to representatives from other saline, hot, anoxic, deep environments. However, due to the hypersaline and hyperthermophilic reservoir conditions, cell numbers are low, so that

  9. Monitoring CO2 gas-phase migration in a shallow sand aquifer using cross-borehole ground penetrating radar

    DEFF Research Database (Denmark)

    Lassen, Rune Nørbæk; Sonnenborg, T.O.; Jensen, Karsten Høgh

    2015-01-01

    gaseous CO2 evolved and the method was thus useful for mapping the migration of the CO2 gas plume. The experimental results demonstrated that the migration of the gas plume was highly irregular. Initially, the gaseous CO2 migrated upwards due to buoyancy effects and subsequently it moved laterally...... and transversely to the groundwater flow direction. As the injection continued, the main flow direction of the gaseous CO2 shifted and CO2 gas pockets with a gas saturation of up to 0.3 formed below lower-permeable sand layers. CO2 gas was detected in a GPR-panel 5 m away from the injection point after 21 h....... The GPR measurements showed that CO2 gas never penetrated the fine Aeolian sand at 6 m depth and that the gas saturation appeared to become constant in the survey area after less than 24 h of CO2 injection. The results of the experiments have emphasized that lateral spreading is of significance in case...

  10. Real-time breath gas analysis of CO and CO2 using an EC-QCL

    Science.gov (United States)

    Ghorbani, Ramin; Schmidt, Florian M.

    2017-05-01

    Real-time breath gas analysis is a promising, non-invasive tool in medical diagnostics, and well-suited to investigate the physiology of carbon monoxide (CO), a potential biomarker for oxidative stress and respiratory diseases. A sensor for precise, breath-cycle resolved, simultaneous detection of exhaled CO (eCO) and carbon dioxide (eCO2) was developed based on a continuous wave, external-cavity quantum cascade laser (EC-QCL), a low-volume multi-pass cell and wavelength modulation spectroscopy. The system achieves a noise-equivalent (1σ) sensitivity of 8.5 × 10-8 cm-1 Hz-1/2 and (2σ) detection limits of 9 ± 2 ppbv and 650 ± 7 ppmv at 0.14 s spectrum acquisition time for CO and CO2, respectively. Integration over 15 s yields a precision of 0.6 ppbv for CO. The fact that the eCO2 expirograms measured by capnography and laser spectroscopy have essentially identical shape confirms true real-time detection. It is found that the individual eCO exhalation profiles from healthy non-smokers have a slightly different shape than the eCO2 profiles and exhibit a clear dependence on exhalation flow rate and breath-holding time. Detection of indoor air CO and broadband breath profiling across the 93 cm-1 mode-hop-free tuning range of the EC-QCL are also demonstrated.

  11. Greenhouse gas flux dynamics in wetlands

    Energy Technology Data Exchange (ETDEWEB)

    Silvola, J.; Alm, J.; Saarnio, S. [Joensuu Univ. (Finland). Dept. of Biology; Martikainen, P.J. [National Public Health Inst., Kuopio (Finland). Dept. of Environmental Microbiology

    1996-12-31

    Two important greenhouse gases, CO{sub 2} and CH{sub 4}, are closely connected to the carbon cycling of wetlands. Although virgin wetlands are mostly carbon accumulating ecosystems, major proportion of the CO{sub 2} bound annually in photosynthesis is released back to the atmosphere. Main portion of the carbon cycling in wetlands is quite fast while a small proportion of carbon diffusing from soil is released from organic matter, which may be ten thousand years old. Methane is formed in the anaerobic layers of wetlands, from where it is released gradually to the atmosphere. The decomposition in anaerobic conditions is very slow, which means that usually only a few percent of the annual carbon cycling takes place as methane. Research on CO{sub 2} fluxes of different virgin and managed peatlands was the main topic of this project during the first phase of SILMU. The measurements were made during two seasons in varying conditions in c. 30 study sites. In the second phase of SILMU the research topics were the spatial and temporal variation of CO{sub 2} and CH{sub 4} fluxes, the relationships between vegetation and gas fluxes as well as carbon balance studies in wetlands at some intensive sites

  12. Modeling of greenhouse gas emission from livestock

    Directory of Open Access Journals (Sweden)

    Sanjo eJose

    2016-04-01

    Full Text Available The effects of climate change on humans and other living ecosystems is an area of on-going research. The ruminant livestock sector is considered to be one of the most significant contributors to the existing greenhouse gas (GHG pool. However the there are opportunities to combat climate change by reducing the emission of GHGs from ruminants. Methane (CH4 and nitrous oxide (N2O are emitted by ruminants via anaerobic digestion of organic matter in the rumen and manure, and by denitrification and nitrification processes which occur in manure. The quantification of these emissions by experimental methods is difficult and takes considerable time for analysis of the implications of the outputs from empirical studies, and for adaptation and mitigation strategies to be developed. To overcome these problems computer simulation models offer substantial scope for predicting GHG emissions. These models often include all farm activities while accurately predicting the GHG emissions including both direct as well as indirect sources. The models are fast and efficient in predicting emissions and provide valuable information on implementing the appropriate GHG mitigation strategies on farms. Further, these models help in testing the efficacy of various mitigation strategies that are employed to reduce GHG emissions. These models can be used to determine future adaptation and mitigation strategies, to reduce GHG emissions thereby combating livestock induced climate change.

  13. Greenhouse gas accounting and waste management.

    Science.gov (United States)

    Gentil, Emmanuel; Christensen, Thomas H; Aoustin, Emmanuelle

    2009-11-01

    Accounting of emissions of greenhouse gas (GHG) is a major focus within waste management. This paper analyses and compares the four main types of GHG accounting in waste management including their special features and approaches: the national accounting, with reference to the Intergovernmental Panel on Climate Change (IPCC), the corporate level, as part of the annual reporting on environmental issues and social responsibility, life-cycle assessment (LCA), as an environmental basis for assessing waste management systems and technologies, and finally, the carbon trading methodology, and more specifically, the clean development mechanism (CDM) methodology, introduced to support cost-effective reduction in GHG emissions. These types of GHG accounting, in principle, have a common starting point in technical data on GHG emissions from specific waste technologies and plants, but the limited availability of data and, moreover, the different scopes of the accounting lead to many ways of quantifying emissions and producing the accounts. The importance of transparency in GHG accounting is emphasised regarding waste type, waste composition, time period considered, GHGs included, global warming potential (GWP) assigned to the GHGs, counting of biogenic carbon dioxide, choice of system boundaries, interactions with the energy system, and generic emissions factors. In order to enhance transparency and consistency, a format called the upstream-operating-downstream framework (UOD) is proposed for reporting basic technology-related data regarding GHG issues including a clear distinction between direct emissions from waste management technologies, indirect upstream (use of energy and materials) and indirect downstream (production of energy, delivery of secondary materials) activities.

  14. Estonian greenhouse gas emissions inventory report

    Energy Technology Data Exchange (ETDEWEB)

    Punning, J.M.; Ilomets, M.; Karindi, A.; Mandre, M.; Reisner, V. [Inst. of Ecology, Tallinn (Estonia); Martins, A.; Pesur, A. [Inst. of Energy Research, Tallinn (Estonia); Roostalu, H.; Tullus, H. [Estonian Agricultural Univ., Tartu (Estonia)

    1996-07-01

    It is widely accepted that the increase of greenhouse gas concentrations in the atmosphere due to human activities would result in warming of the Earth`s surface. To examine this effect and better understand how the GHG increase in the atmosphere might change the climate in the future, how ecosystems and societies in different regions of the World should adapt to these changes, what must policymakers do for the mitigation of that effect, the worldwide project within the Framework Convention on Climate Change was generated by the initiative of United Nations. Estonia is one of more than 150 countries, which signed the Framework Convention on Climate Change at the United Nations Conference on Environment and Development held in Rio de Janeiro in June 1992. In 1994 a new project, Estonian Country Study was initiated within the US Country Studies Program. The project will help to compile the GHG inventory for Estonia, find contemporary trends to investigate the impact of climate change on the Estonian ecosystems and economy and to formulate national strategies for Estonia addressing to global climate change.

  15. Greenhouse gas benefits of fighting obesity

    Energy Technology Data Exchange (ETDEWEB)

    Michaelowa, Axel [University of Zuerich, Muehlegasse 21, 8001 Zuerich (Switzerland); Dransfeld, Bjoern [Perspectives GmbH, Sonnenredder 55, 22045 Hamburg (Germany)

    2008-06-15

    Obesity has become a serious public health problem in both industrialized and rapidly industrializing countries. It increases greenhouse gas emissions through higher fuel needs for transportation of heavier people, lifecycle emissions from additional food production and methane emissions from higher amounts of organic waste. A reduction of average weight by 5 kg could reduce OECD transport CO{sub 2} emissions by more than 10 million t. While the shift from beef to other forms of meat in industrialized and countries in transition has lead to lifecycle emissions savings of 20 million t CO{sub 2} equivalent between 1990 and 2005, emissions due to obesity-promoting foodstuffs have increased by more than 400 million t in advanced developing countries. Emissions in OECD countries could be reduced by more than 4 million t through reduction of associated food waste. Due to the intimate behavioural nature of the obesity problem, policies to reduce obesity such as food taxation, subsidization of human-powered transport, incentives to reduce sedentary leisure and regulation of fat in foodstuffs have not yet been implemented to any extent. The emissions benefits of fiscal and regulatory measures to reduce obesity could accelerate the tipping point where a majority of voters feels that the problem warrants policy action. (author)

  16. Surrogate gas prediction model as a proxy for Δ14C-based measurements of fossil fuel–CO2

    Science.gov (United States)

    Coakley, Kevin J; Miller, John B; Montzka, Stephen A; Sweeney, Colm; Miller, Ben R

    2016-01-01

    The measured 14C:12C isotopic ratio of atmospheric CO2 (and its associated derived Δ14C value) is an ideal tracer for determination of the fossil fuel derived CO2 enhancement contributing to any atmospheric CO2 measurement (Cff). Given enough such measurements, independent top-down estimation of US fossil fuel-CO2 emissions should be possible. However, the number of Δ14C measurements is presently constrained by cost, available sample volume, and availability of mass spectrometer measurement facilities. Δ14C is therefore measured in just a small fraction of samples obtained by ask air sampling networks around the world. Here, we develop a Projection Pursuit Regression (PPR) model to predict Cff as a function of multiple surrogate gases acquired within the NOAA/ESRL Global Greenhouse Gas Reference Network (GGGRN). The surrogates consist of measured enhancements of various anthropogenic trace gases, including CO, SF6, and halo- and hydrocarbons acquired in vertical airborne sampling profiles near Cape May, NJ and Portsmouth, NH from 2005 through 2010. Model performance for these sites is quantified based on predicted values corresponding to test data excluded from the model building process. Chi-square hypothesis test analysis indicates that these predictions and corresponding observations are consistent given our uncertainty budget which accounts for random effects and one particular systematic effect. However, quantification of the combined uncertainty of the prediction due to all relevant systematic effects is difficult because of the limited range of the observations and their relatively high fractional uncertainties at the sampling sites considered here. To account for the possibility of additional systematic effects, we incorporate another component of uncertainty into our budget. Expanding the number of Δ14C measurements in the NOAA GGGRN and building new PPR models at additional sites would improve our understanding of uncertainties and potentially

  17. Surrogate gas prediction model as a proxy for Δ14C-based measurements of fossil fuel CO2

    Science.gov (United States)

    Coakley, Kevin J.; Miller, John B.; Montzka, Stephen A.; Sweeney, Colm; Miller, Ben R.

    2016-06-01

    The measured 14C:12C isotopic ratio of atmospheric CO2 (and its associated derived Δ14C value) is an ideal tracer for determination of the fossil fuel derived CO2 enhancement contributing to any atmospheric CO2 measurement (Cff). Given enough such measurements, independent top-down estimation of U.S. fossil fuel CO2 emissions should be possible. However, the number of Δ14C measurements is presently constrained by cost, available sample volume, and availability of mass spectrometer measurement facilities. Δ14C is therefore measured in just a small fraction of samples obtained by flask air sampling networks around the world. Here we develop a projection pursuit regression (PPR) model to predict Cff as a function of multiple surrogate gases acquired within the NOAA/Earth System Research Laboratory (ESRL) Global Greenhouse Gas Reference Network (GGGRN). The surrogates consist of measured enhancements of various anthropogenic trace gases, including CO, SF6, and halocarbon and hydrocarbon acquired in vertical airborne sampling profiles near Cape May, NJ and Portsmouth, NH from 2005 to 2010. Model performance for these sites is quantified based on predicted values corresponding to test data excluded from the model building process. Chi-square hypothesis test analysis indicates that these predictions and corresponding observations are consistent given our uncertainty budget which accounts for random effects and one particular systematic effect. However, quantification of the combined uncertainty of the prediction due to all relevant systematic effects is difficult because of the limited range of the observations and their relatively high fractional uncertainties at the sampling sites considered here. To account for the possibility of additional systematic effects, we incorporate another component of uncertainty into our budget. Expanding the number of Δ14C measurements in the NOAA GGGRN and building new PPR models at additional sites would improve our understanding of

  18. Effect of elevated CO2 concentration and nitrate: ammonium ratios on gas exchange and growth of cassava (Manihot esculenta Crantz)

    Science.gov (United States)

    This study evaluated how different nitrogen forms affect growth and photosynthetic responses of cassava to CO2 concentration. Cassava was grown in 12-L pots in a greenhouse (30/25o C day / night) at 390 or 750 ppm of CO2. Three nitrogen treatments were applied: (a) 12 mM NO3-, (b) 6 mM NO3- + 6 mM N...

  19. Greenhouse effect gases sources and sinks (CO2, CH4, N2O) in grasslands and reduction strategies. Greenhouse effect gases prairies. Final report of the second part of the project. April 2004

    International Nuclear Information System (INIS)

    Soussana, J.F.

    2004-04-01

    The project 'GES-Prairies' (Greenhouse Gases - Grasslands) had two main objectives: 1. To measure more accurately the fluxes of CO 2 , CH 4 and N 2 O of French grasslands and determine the greenhouse gas (GHG) balance of these areas. 2. To calculate the net GHG emissions of cattle production farms and finally to propose and evaluate some management scenarios leading to a reduction of GHG emissions. This project deals with three different spatial scales: the field scale, the farm scale and finally, the regional scale. At the field scale, during two years, fluxes of CO 2 , CH 4 and N 2 O were measured in a mid-mountain permanent grassland, previously managed intensively by cutting and grazing (Laqueuille, Auvergne, France). Results from the first complete year of measurements show that the extensification process (reduction of the stocking rate and stopping N fertilization) allows to stock more carbon in the ecosystem. At the farm scale, We developed a model (FARMSIM, coupled to PASIM) able to simulate the GHG balance of a livestock farm. FARMSIM has been tested with data obtained from a mixed livestock farm in Lorraine (dairy and meat production, annual average stocking rate = 1.3 LU ha -1 ) of 100 ha (including 76 ha of grasslands and 21 of annual crops). The results indicate a net emission of 175 t equivalent C-CO 2 for this farm. If expressed per unit of product, it represents 1.34 t equivalent C-CO 2 per LU and per year or 0.54 kg CO 2 per kg of milk and per year. At the regional scale/. The PASIM model has been used to simulate the European grasslands with a spatial resolution of 1' (about 200 * 200 km). For each grid cell, a sensibility analysis allowed to determine the N application which correspond to 30% of the N application that would maximize the annual yield of the pasture. Simulation runs on mixed systems (combining grazing and cutting) show that almost one half of the grassland area is, on average, used for cutting. These simulations predict N 2 O

  20. Uncertainty analysis of a coupled ecosystem response model simulating greenhouse gas fluxes from a temperate grassland

    Science.gov (United States)

    Liebermann, Ralf; Kraft, Philipp; Houska, Tobias; Breuer, Lutz; Müller, Christoph; Kraus, David; Haas, Edwin; Klatt, Steffen

    2015-04-01

    Among anthropogenic greenhouse gas emissions, CO2 is the dominant driver of global climate change. Next to its direct impact on the radiation budget, it also affects the climate system by triggering feedback mechanisms in terrestrial ecosystems. Such mechanisms - like stimulated photosynthesis, increased root exudations and reduced stomatal transpiration - influence both the input and the turnover of carbon and nitrogen compounds in the soil. The stabilization and decomposition of these compounds determines how increasing CO2 concentrations change the terrestrial trace gas emissions, especially CO2, N2O and CH4. To assess the potential reaction of terrestrial greenhouse gas emissions to rising tropospheric CO2 concentration, we make use of a comprehensive ecosystem model integrating known processes and fluxes of the carbon-nitrogen cycle in soil, vegetation and water. We apply a state-of-the-art ecosystem model with measurements from a long term field experiment of CO2 enrichment. The model - a grassland realization of LandscapeDNDC - simulates soil chemistry coupled with plant physiology, microclimate and hydrology. The data - comprising biomass, greenhouse gas emissions, management practices and soil properties - has been attained from a FACE (Free Air Carbon dioxide Enrichment) experiment running since 1997 on a temperate grassland in Giessen, Germany. Management and soil data, together with weather records, are used to drive the model, while cut biomass as well as CO2 and N2O emissions are used for calibration and validation. Starting with control data from installations without CO2 enhancement, we begin with a GLUE (General Likelihood Uncertainty Estimation) assessment using Latin Hypercube to reduce the range of the model parameters. This is followed by a detailed sensitivity analysis, the application of DREAM-ZS for model calibration, and an estimation of the effect of input uncertainty on the simulation results. Since first results indicate problems with

  1. Evaluating the Effects of Elevated CO2 on the Competition Ability between Various C3 and C4 Crops and Weeds in Greenhouse Condition

    Directory of Open Access Journals (Sweden)

    S. Anvarkhah

    2012-04-01

    Full Text Available Since agriculture is both the source and sink of greenhouse gases, and plants show different responses to the elevated CO2 concentration, an experiment was conducted in 2006 at the research greenhouse of the faculty of agriculture of Ferdowsi University of Mashhad. The purpose of the experiment was to examine the effects of elevated CO2 on the competition ability between various crops and weeds in factorial arrangement within a completely randomized design with three replications. The factors included ambient (360ppm CO2 and elevated (700 ppm CO2 concentrations and various combinations of the plantation of crops (millet and soybean and weeds (pigweed and lambsquarters of C3 and C4 species, whether of the pure culture or intercropping. The results of the experiment showed that, as the CO2 concentration increased, the leaf area and root dry weight of millet increased whereas those of other species decreased. Millet,s root length increased whereas those of other species decreased. Root dry weight in each cultural combinations, compared to the ambient CO2 concentration, decreased. The amount of chlorophyll in lambsquarters, increased whereas it decreased in pigweed, millet and soybean.

  2. Biochar and manure effects on net nitrogen mineralization and greenhouse gas emissions from calcareous soil under corn

    Science.gov (United States)

    Few multiyear field studies have examined the impacts of a one-time biochar application on net N mineralization and greenhouse gas emissions in an irrigated, calcareous soil; yet such applications are hypothesized as a means of sequestering atmospheric CO2 and improving soil quality. We fall-applie...

  3. Climate and site management as driving factors for the atmospheric greenhouse gas exchange of a restored wetland

    DEFF Research Database (Denmark)

    Herbst, Mathias; Friborg, Thomas; Schelde, Kirsten

    2012-01-01

    The full atmospheric greenhouse gas (GHG) budget of a restored wetland in Western Denmark could be established for the years 2009–2011 from eddy covariance measurements of carbon dioxide (CO2) and methane (CH4) fluxes. The water table in the wetland, being restored in 2002, was unregulated, and t...

  4. Climate and site management as driving factors for the atmospheric greenhouse gas exchange of a restored wetland

    DEFF Research Database (Denmark)

    Herbst, Mathias; Friborg, Thomas; Schelde, Kirsten

    2013-01-01

    The atmospheric greenhouse gas (GHG) budget of a restored wetland in western Denmark was established for the years 2009–2011 from eddy covariance measurements of carbon dioxide (CO2) and methane (CH4) fluxes. The water table in the wetland, which was restored in 2002, was unregulated, and the veg...

  5. Seasonal greenhouse gas and soil nutrient cycling in semi-arid native and non-native perennial grass pastures

    Science.gov (United States)

    Previous research indicates that a difference occurs in native and non-native grass species in regard to drivers of greenhouse gas (GHG, (carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O))) emissions from soil. Drivers of soil nutrients could help establish best management practices to mit...

  6. Greenhouse gas emissions from international aviation and allocation options

    International Nuclear Information System (INIS)

    Krueger Nielsen, S.

    2003-01-01

    Annex I shall pursue limitation or reduction of emissions of greenhouse gases not controlled by the Montreal Protocol from international aviation and marine bunker fuels, working through the International Civil Aviation Organisation (ICAO) and the International Maritime Organisation (IMO), respectively' (UNFCCC 1997). As yet, the ICAO Assembly has not agreed upon new initiatives specifically aimed at reducing greenhouse gas emissions, but ICAOs Committee on Aviation Environmental Protection (CAEP) is investigating several options. Some of these options may have implications for the airlines' reporting requirements as well as the allocation issue. For example, CAEP is currently discussing the possibility of negotiating with the airline industry on options to set up a voluntary scheme for improving the fuel efficiency of airlines. Such a scheme may involve the need for airlines to engage in a reporting scheme for fuel consumption and emissions. CAEP is furthermore discussing the possibility of setting up an emissions trading scheme based on a system where airlines are allowed to buy emission quotas in other sectors included under the Kyoto Protocol. Such a framework may involve the setting of a cap for aviation emissions and allocation of emission permits to airlines and probably also the allocation of the emissions of CO 2 from international aviation to Parties as well as the need for airlines to engage in a reporting scheme for fuel consumption and emissions. Therefore, the discussion on data availability and requirements seems to be closely connected to the issues of options for allocation and control. This explains why this report focuses broadly on all these issues. (au)

  7. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2013-08-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

  8. Designing optimal greenhouse gas monitoring networks for Australia

    Science.gov (United States)

    Ziehn, T.; Law, R. M.; Rayner, P. J.; Roff, G.

    2016-01-01

    Atmospheric transport inversion is commonly used to infer greenhouse gas (GHG) flux estimates from concentration measurements. The optimal location of ground-based observing stations that supply these measurements can be determined by network design. Here, we use a Lagrangian particle dispersion model (LPDM) in reverse mode together with a Bayesian inverse modelling framework to derive optimal GHG observing networks for Australia. This extends the network design for carbon dioxide (CO2) performed by Ziehn et al. (2014) to also minimise the uncertainty on the flux estimates for methane (CH4) and nitrous oxide (N2O), both individually and in a combined network using multiple objectives. Optimal networks are generated by adding up to five new stations to the base network, which is defined as two existing stations, Cape Grim and Gunn Point, in southern and northern Australia respectively. The individual networks for CO2, CH4 and N2O and the combined observing network show large similarities because the flux uncertainties for each GHG are dominated by regions of biologically productive land. There is little penalty, in terms of flux uncertainty reduction, for the combined network compared to individually designed networks. The location of the stations in the combined network is sensitive to variations in the assumed data uncertainty across locations. A simple assessment of economic costs has been included in our network design approach, considering both establishment and maintenance costs. Our results suggest that, while site logistics change the optimal network, there is only a small impact on the flux uncertainty reductions achieved with increasing network size.

  9. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  10. CO2 Removal from Multi-component Gas Mixtures Utilizing Spiral-Wound Asymmetric Membranes

    International Nuclear Information System (INIS)

    Said, W.B.; Fahmy, M.F.M.; Gad, F.K.; EI-Aleem, G.A.

    2004-01-01

    A systematic procedure and a computer program have been developed for simulating the performance of a spiral-wound gas permeate for the CO 2 removal from natural gas and other hydrocarbon streams. The simulation program is based on the approximate multi-component model derived by Qi and Henson(l), in addition to the membrane parameters achieved from the binary simulation program(2) (permeability and selectivity). Applying the multi-component program on the same data used by Qi and Henson to evaluate the deviation of the approximate model from the basic transport model, showing results more accurate than those of the approximate model, and are very close to those of the basic transport model, while requiring significantly less than 1 % of the computation time. The program was successfully applied on the data of Salam gas plant membrane unit at Khalda Petroleum Company, Egypt, for the separation of CO 2 from hydrocarbons in an eight-component mixture to estimate the stage cut, residue, and permeate compositions, and gave results matched with the actual Gas Chromatography Analysis measured by the lab

  11. Greenhouse gas emissions in salt marshes and their response to nitrogen loading

    Science.gov (United States)

    Tang, J.; Moseman-Valtierra, S.; Kroeger, K. D.; Morkeski, K.; Carey, J.

    2015-12-01

    Salt marshes play an important role in global and regional carbon and nitrogen cycling. Anthropogenic nitrogen loading may alter greenhouse gas (GHG, including CO2, CH4, and N2O) emissions and carbon sequestration in salt marshes. We measured GHG emissions biweekly for two growing seasons across a nitrogen-loading gradient of four Spartina salt marshes in Waquoit Bay, Massachusetts. In addition, we conducted nitrogen addition experiments in a pristine marsh by adding low and high nitrate bi-weekly during the summer. The GHG flux measurements were made in situ with a state-of-the-art mobile gas measurement system using the cavity ring down technology that consists of a CO2/CH4 analyzer (Picarro) and an N2O/CO analyzer (Los Gatos). We observed strong seasonal variations in greenhouse gas emissions. The differences in gas emissions across the nitrogen gradient (between 1 and 10 gN m-2y-1) were not significant, but strong pulse emissions of N2O were observed after nitrogen was artificially added to the marsh. We found that the studied salt marsh was a significant carbon sink (NEP ~ 380 gC m-2y-1). CH4 fluxes are 3 orders of magnitude less than CO2 fluxes in the salt marsh. Carbon fluxes are driven by light, salinity, tide, and temperature. We conclude that restoration or conservation of this carbon sink has a significant social benefit for carbon credit.

  12. Construction and testing of a simple and economical soil greenhouse gas automatic sampler

    Science.gov (United States)

    Ginting, D.; Arnold, S.L.; Arnold, N.S.; Tubbs, R.S.

    2007-01-01

    Quantification of soil greenhouse gas emissions requires considerable sampling to account for spatial and/or temporal variation. With manual sampling, additional personnel are often not available to sample multiple sites within a narrow time interval. The objectives were to construct an automatic gas sampler and to compare the accuracy and precision of automatic versus manual sampling. The automatic sampler was tested with carbon dioxide (CO2) fluxes that mimicked the range of CO2 fluxes during a typical corn-growing season in eastern Nebraska. Gas samples were drawn from the chamber at 0, 5, and 10 min manually and with the automatic sampler. The three samples drawn with the automatic sampler were transferred to pre-vacuumed vials after 1 h; thus the samples in syringe barrels stayed connected with the increasing CO2 concentration in the chamber. The automatic sampler sustains accuracy and precision in greenhouse gas sampling while improving time efficiency and reducing labor stress. Copyright ?? Taylor & Francis Group, LLC.

  13. Energy-saving options for the mitigation of greenhouse gas emissions from the Mongolian energy sector

    Energy Technology Data Exchange (ETDEWEB)

    Dorjpurev, J.; Purevjal, O.; Erdenechimeg, Ch. [and others

    1996-12-31

    The Energy sector is the largest contributor to GHG emission in Mongolia. The Energy sector emits 54 percent of CO2 and 4 percent of methane. All emissions of other greenhouse gases are accounted from energy related activities. The activities in this sector include coal production, fuel combustion, and biomass combustion at the thermal power stations and in private houses (stoves) for heating purposes. This paper presents some important Demand-side options considered for mitigation of CO2 emissions from energy sector such as Energy Conservation in Industrial Sector and in Buildings. Changes in energy policies and programmes in the Mongolian situation that promote more efficient and sustainable practices are presented in the paper. These energy saving measures will not only help reduce greenhouse gas emissions, but will also promote economic development and alleviate other environmental problems.

  14. Outsourcing CO2 Emissions

    Science.gov (United States)

    Davis, S. J.; Caldeira, K. G.

    2009-12-01

    CO2 emissions from the burning of fossil fuels are the primary cause of global warming. Much attention has been focused on the CO2 directly emitted by each country, but relatively little attention has been paid to the amount of emissions associated with consumption of goods and services in each country. This consumption-based emissions inventory differs from the production-based inventory because of imports and exports of goods and services that, either directly or indirectly, involved CO2 emissions. Using the latest available data and reasonable assumptions regarding trans-shipment of embodied carbon through third-party countries, we developed a global consumption-based CO2 emissions inventory and have calculated associated consumption-based energy and carbon intensities. We find that, in 2004, 24% of CO2 emissions are effectively outsourced to other countries, with much of the developed world outsourcing CO2 emissions to emerging markets, principally China. Some wealthy countries, including Switzerland and Sweden, outsource over half of their consumption-based emissions, with many northern Europeans outsourcing more than three tons of emissions per person per year. The United States is both a big importer and exporter of emissions embodied in trade, outsourcing >2.6 tons of CO2 per person and at the same time as >2.0 tons of CO2 per person are outsourced to the United States. These large flows indicate that CO2 emissions embodied in trade must be taken into consideration when considering responsibility for increasing atmospheric greenhouse gas concentrations.

  15. Comparison of Dry Gas Seasonal Storage with CO2 Storage and Re-Use Potential

    OpenAIRE

    Killerud, Marie

    2013-01-01

    To make large-scale CO2 storage economic, many groups have proposed using CO2in EOR projects to create value for CO2 storage. However, CO2 EOR projectsgenerally require a large and variable supply of CO2 and consequently may requiretemporary storage of CO2 in geological formations. In order to store CO2 atoffshore sites as a source for CO2 EOR projects, the CO2 needs to be extractedfrom a storage site to a certain extent. Alternatively, CO2 EOR projects maybe developed alongside saline aquife...

  16. The functioning of the electricity, CO2 and natural gas wholesale markets in 2011-2012

    International Nuclear Information System (INIS)

    2012-11-01

    The Commission for Energy Regulation (CRE) monitors electricity and natural gas transactions carried out between suppliers, traders and producers, transactions carried out on the organised markets as well as cross-border trades. CRE's mission of monitoring wholesale markets aims to ensure that wholesale market energy prices are consistent with the technical and economic fundamentals of these markets. In particular, CRE strives to verify that no market power is exercised in such a way that a participant abuses its situation to attain abnormal prices, notably with regard to its costs. This task is now also in line with the Regulation on Energy Market Integrity and Transparency known as REMIT. This fifth surveillance report of the CRE presents and analyses the developments of wholesale markets in France in 2011 and the first semester of 2012 for electricity, gas and CO 2 . It also details the investigations carried out in relation to the behaviour of stakeholders or in case of particular market events. On the electricity market, the average spot price increased slightly and was established at euro 49/MWh (base-load), i.e. an increase of 3% compared with 2010; the price of the Calendar 2013 product increased following the German moratorium on nuclear energy before gradually decreasing over the second half of the year. The announcement of the moratorium also resulted in a price differential reversal with Germany (German prices becoming more expensive) until February 2012. Volumes traded also remained stable despite a drop in trade on the futures market. On the gas market, the LNG offer in Europe and France clearly fell on account of trade-offs with the Asian market where demand greatly increased following the accident of Fukushima, with gas replacing nuclear in electricity generation. Gas prices rose on average but remained more stable than in 2010 both on spot markets and futures markets. They progressed, however, at a lower rate than oil products on which long

  17. The potential of renewables versus natural gas with CO2 capture and storage for power generation under CO2 constraints

    NARCIS (Netherlands)

    Van Den Broek, Machteld; Berghout, Niels; Rubin, Edward S.

    2015-01-01

    The costs of intermittent renewable energy systems (IRES) and power storage technologies are compared on a level playing field to those of natural gas combined cycle power plants with CO2 capture and storage (NGCC-CCS). To account for technological progress over time, an "experience

  18. Measurements of capillary pressure and electric permittivity of gas-water systems in porous media at elevated pressures : Application to geological storage of CO2 in aquifers and wetting behavior in coal

    NARCIS (Netherlands)

    Plug, W.J.

    2007-01-01

    Sequestration of CO2 in aquifers and coal layers is a promising technique to reduce greenhouse gas emissions. Considering the reservoir properties, e.g. wettability, heterogeneity and the caprocks sealing capacity, the capillary pressure is an important measure to evaluate the efficiency, the

  19. Influences of Land Use on Greenhouse Gas Fluxes within Mixed Landscapes

    Science.gov (United States)

    Xiao, J.; Contosta, A.; Deng, J.; Lepine, L. C.; Li, C.; Ollinger, S. V.; Ouimette, A.; Tang, J.; Varner, R. K.

    2015-12-01

    Human activities (e.g., urbanization, land use planning) have led to complex patterns of urban, suburban, agricultural, and forested landscapes. Ecosystems within these landscapes play an important role in climate regulation by acting as regulators of CO2 and other greenhouse gases and altering surface albedo and other biophysical properties. The overarching goal of our work is to examine the interactions among carbon cycling, land use, and climate change in a human-dominated, mixed land use region that includes urban, suburban, agriculture, and forest land uses. We combine field measurements of carbon storage and greenhouse gas emissions (CO2, CH4, and N2O), an improved process-based biogeochemical model - DNDC (DeNitrification and DeComposition) designed to predict C fluxes and trace gas emissions, and historical and projected land use change data derived from Landsat imagery and cellular automata/agent-based modeling. Our specific objectives designed to achieve the overarching goal are to: (1) Measure C pools and greenhouse gas emissions (CO2, CH4, and N2O) in urban, suburban, agricultural, and forested landscapes; (2) Improve and parameterize the DNDC (DeNitrification and DeComposition) model and validate model predictions; (3) Develop historical land use change data for the last three decades from Landsat imagery and projections of future land use change; (4) Generate spatially continuous predictions of C pools and greenhouse gas emissions using Urban-DNDC and assess how land use interacts with C cycling and climate change and how future land use change will influence carbon sequestration potential within these complex landscapes. Our results will have implications for crafting effective land management policies that balance C sequestration and climate mitigation with food production, forest resources and many other services that these landscapes provide.

  20. Utilization of high CO2 content formation gas for steam and electricity generation; Aprovechamiento del gas de formacion con alto contenido de CO2 para generacion de vapor y electricidad

    Energy Technology Data Exchange (ETDEWEB)

    Villagomez, Paul; Lamino, Marcelo; Jacome, Jose; Pastor, Santiago [EcuadorTLC, Quito (Ecuador). Grupo PETROBRAS

    2008-07-01

    Ecuador TLC SA, as part of the PETROBRAS Group, respecting its mission to act safe, cost-effectiveness, social and environmental responsibility, currently operates an oil production project in the Ecuatorian Amazon, known as Block 18. In Block 18, the process of gas burning is response for launch approximately 10 MMSCF of the gas associated with 77% CO2 in the environment. For this reason it was built a centralized power generation plants (PGE), of 17.38 MW, taking advantage of the gas with 77% CO2 from boilers to burn it, using it as a source of heat in a combined cycle steam turbines, generating electricity. This project is environmentally efficient with reduced emissions of CO2 and as reducing fuel costs to zero. The results of CO2 reduction is a corporate goal of PETROBRAS and this project will contribute to reducing CO2 emissions by approximately 400,000 Ton over the life of the project.

  1. Reducing greenhouse gas emissions for climate stabilization: framing regional options.

    Science.gov (United States)

    Olabisi, Laura Schmitt; Reich, Peter B; Johnson, Kris A; Kapuscinski, Anne R; Su, Sangwon H; Wilson, Elizabeth J

    2009-03-15

    The Intergovernmental Panel on Climate Change (IPCC) has stated that stabilizing atmospheric CO2 concentrations will require reduction of global greenhouse gas (GHG) emissions by as much as 80% by 2050. Subnational efforts to cut emissions will inform policy development nationally and globally. We projected GHG mitigation strategies for Minnesota, which has adopted a strategic goal of 80% emissions reduction by 2050. A portfolio of conservation strategies, including electricity conservation, increased vehicle fleet fuel efficiency, and reduced vehicle miles traveled, is likely the most cost-effective option for Minnesota and could reduce emissions by 18% below 2005 levels. An 80% GHG reduction would require complete decarbonization of the electricity and transportation sectors, combined with carbon capture and sequestration at power plants, or deep cuts in other relatively more intransigent GHG-emitting sectors. In order to achieve ambitious GHG reduction goals, policymakers should promote aggressive conservation efforts, which would probably have negative net costs, while phasing in alternative fuels to replace coal and motor gasoline over the long-term.

  2. Using greenhouse gas fluxes to define soil functional types

    Energy Technology Data Exchange (ETDEWEB)

    Petrakis, Sandra; Barba, Josep; Bond-Lamberty, Ben; Vargas, Rodrigo

    2017-12-04

    Soils provide key ecosystem services and directly control ecosystem functions; thus, there is a need to define the reference state of soil functionality. Most common functional classifications of ecosystems are vegetation-centered and neglect soil characteristics and processes. We propose Soil Functional Types (SFTs) as a conceptual approach to represent and describe the functionality of soils based on characteristics of their greenhouse gas (GHG) flux dynamics. We used automated measurements of CO2, CH4 and N2O in a forested area to define SFTs following a simple statistical framework. This study supports the hypothesis that SFTs provide additional insights on the spatial variability of soil functionality beyond information represented by commonly measured soil parameters (e.g., soil moisture, soil temperature, litter biomass). We discuss the implications of this framework at the plot-scale and the potential of this approach at larger scales. This approach is a first step to provide a framework to define SFTs, but a community effort is necessary to harmonize any global classification for soil functionality. A global application of the proposed SFT framework will only be possible if there is a community-wide effort to share data and create a global database of GHG emissions from soils.

  3. Greenhouse gas dynamics in degraded and restored tropical peatlands

    Directory of Open Access Journals (Sweden)

    J. Jauhiainen

    2016-06-01

    Full Text Available Agricultural and other land uses on ombrotrophic lowland tropical peat swamps typically lead to reduced vegetation biomass and water table drawdown. We review what is known about greenhouse gas (GHG dynamics in natural and degraded tropical peat systems in south-east Asia, and on this basis consider what can be expected in terms of GHG dynamics under restored conditions. Only limited in situ data are available on the effects of restoration and the consequences for peat carbon (C dynamics. Hydrological restoration seeks to bring the water table closer to the peat surface and thus re-create near-natural water table conditions, in order to reduce wildfire risk and associated fire impacts on the peat C store, as well as to reduce aerobic peat decomposition rates. However, zero emissions are unlikely to be achieved due to the notable potential for carbon dioxide (CO2 production from anaerobic peat decomposition processes. Increased vegetation cover (ideally woody plants resulting from restoration will increase shading and reduce peat surface temperatures, and this may in turn reduce aerobic decomposition rates. An increase in litter deposition rate will compensate for C losses by peat decomposition but also increase the supply of labile C, which may prime decomposition, especially in peat enriched with recalcitrant substrates. The response of tropical peatland GHG emissions to peatland restoration will also vary according to previous land use and land use intensity.

  4. Biochar Impacts on Soil Physical Properties and Greenhouse Gas Emissions

    Directory of Open Access Journals (Sweden)

    Rattan Lal

    2013-04-01

    Full Text Available Biochar, a co-product of a controlled pyrolysis process, can be used as a tool for sequestering C in soil to offset greenhouse gas (GHG emissions, and as a soil amendment. Whereas the impacts of biochar application on soil chemical properties are widely known, the research information on soil physical properties is scarce. The objectives of this review are to (i synthesize available data on soil physical properties and GHG emissions, (ii offer possible mechanisms related to the biochar-amended soil processes, and (iii identify researchable priorities. Application rates of 1%–2% (w/w of biochar can significantly improve soil physical quality in terms of bulk density (BD, and water holding capacity (WHC. However, little data are available on surface area (SA, aggregation stability, and penetration resistance (PR of biochar-amended soil. While biochar amendment can initially accentuate the flux of carbon dioxide (CO2, the emission of GHGs may be suppressed over time. A 2-phase complexation hypothesis is proposed regarding the mechanisms of the interaction between soil and biochar.

  5. Greenhouse gas mitigation potentials in the livestock sector

    Science.gov (United States)

    Herrero, Mario; Henderson, Benjamin; Havlík, Petr; Thornton, Philip K.; Conant, Richard T.; Smith, Pete; Wirsenius, Stefan; Hristov, Alexander N.; Gerber, Pierre; Gill, Margaret; Butterbach-Bahl, Klaus; Valin, Hugo; Garnett, Tara; Stehfest, Elke

    2016-05-01

    The livestock sector supports about 1.3 billion producers and retailers, and contributes 40-50% of agricultural GDP. We estimated that between 1995 and 2005, the livestock sector was responsible for greenhouse gas emissions of 5.6-7.5 GtCO2e yr-1. Livestock accounts for up to half of the technical mitigation potential of the agriculture, forestry and land-use sectors, through management options that sustainably intensify livestock production, promote carbon sequestration in rangelands and reduce emissions from manures, and through reductions in the demand for livestock products. The economic potential of these management alternatives is less than 10% of what is technically possible because of adoption constraints, costs and numerous trade-offs. The mitigation potential of reductions in livestock product consumption is large, but their economic potential is unknown at present. More research and investment are needed to increase the affordability and adoption of mitigation practices, to moderate consumption of livestock products where appropriate, and to avoid negative impacts on livelihoods, economic activities and the environment.

  6. Drivers of the growth in global greenhouse gas emissions.

    Science.gov (United States)

    Arto, Iñaki; Dietzenbacher, Erik

    2014-05-20

    Greenhouse gas emissions increased by 8.9 Gigatons CO2 equivalent (Gt) in the period 1995-2008. A phenomenon that has received due attention is the upsurge of emission transfers via international trade. A question that has remained unanswered is whether trade changes have affected global emissions. For each of five factors (one of which is trade changes) in 40 countries we quantify its contribution to the growth in global emissions. We find that the changes in the levels of consumption per capita have led to an enormous growth in emissions (+14.0 Gt). This effect was partly offset by the changes in technology (-8.4 Gt). Smaller effects are found for population growth (+4.2 Gt) and changes in the composition of the consumption (-1.5 Gt). Changes in the trade structure had a very moderate effect on global emissions (+0.6 Gt). Looking at the geographical distribution, changes in the emerging economies (Brazil, Russia, India, Indonesia and China) have caused 44% of emission growth whereas the increase in their national emissions accounted for 59% of emission growth. This means that 15% (1.4 Gt) of all extra GHG emissions between 1995 and 2008 have been emitted in emerging countries but were caused by changes in other countries.

  7. Increased photosynthetic acclimation in alfalfa associated with arbuscular mycorrhizal fungi (AMF) and cultivated in greenhouse under elevated CO2.

    Science.gov (United States)

    Goicoechea, Nieves; Baslam, Marouane; Erice, Gorka; Irigoyen, Juan José

    2014-11-15

    Medicago sativa L. (alfalfa) can exhibit photosynthetic down-regulation when grown in greenhouse conditions under elevated atmospheric CO2. This forage legume can establish a double symbiosis with nitrogen fixing bacteria and arbuscular mycorrhizal fungi (AMF), which may increase the carbon sink effect of roots. Our aim was to assess whether the association of alfalfa with AMF can avoid, diminish or delay the photosynthetic acclimation observed in previous studies performed with nodulated plants. The results, however, showed that mycorrhizal (M) alfalfa at the end of their vegetative period had lower carbon (C) discrimination than non-mycorrhizal (NM) controls, indicating photosynthetic acclimation under ECO2 in plants associated with AMF. Decreased C discrimination was due to the acclimation of conductance, since the amount of Rubisco and the expression of genes codifying both large and small subunits of Rubisco were similar or slightly higher in M than in NM plants. Moreover, M alfalfa accumulated a greater amount of soluble sugars in leaves than NM plants, thus favoring a down-regulation effect on photosynthetic rates. The enhanced contents of sugars in leaves coincided with a reduced percentage of arbuscules in roots, suggesting decreased sink of carbohydrates from shoots to roots in M plants. The shorter life cycle of alfalfa associated with AMF in comparison with the NM controls may also be related to the accelerated photosynthetic acclimation in M plants. Further research is needed to clarify to what extent this behavior could be extrapolated to alfalfa cultivated in the field and subjected to periodic cutting of shoots under climatic change scenarios. Copyright © 2014 Elsevier GmbH. All rights reserved.

  8. Greenhouse-gas emissions from soils increased by earthworms

    NARCIS (Netherlands)

    Lubbers, I.M.; Groenigen, van K.J.; Fonte, S.J.; Six, J.; Brussaard, L.; Groenigen, van J.W.

    2013-01-01

    Earthworms play an essential part in determining the greenhouse-gas balance of soils worldwide, and their influence is expected to grow over the next decades. They are thought to stimulate carbon sequestration in soil aggregates, but also to increase emissions of the main greenhouse gases carbon

  9. How to design greenhouse gas trading in the EU?

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard; Vesterdal, Morten

    2001-01-01

    A new and remarkable Green Paper about how to trade Greenhouse gases (GHG) in the EU has recently been published by the Commission of the European Union. This to achieve the stated 8% reduction target level. The Green Paper raises ten questions about how greenhouse gas permit trading should...

  10. Can savannas help balance the South African greenhouse gas budget?

    CSIR Research Space (South Africa)

    Scholes, RJ

    1996-02-01

    Full Text Available This article discusses the South African Greenhouse Experiment on Savannas (SAGES) study conducted by the CSIR' Division of Forest Science and Technology (Foretek) on the role of savannas in the balance of the greenhouse gas budget of South Africa...

  11. Impact of the choice of emission metric on greenhouse gas abatement and costs

    Science.gov (United States)

    van den Berg, Maarten; Hof, Andries F.; van Vliet, Jasper; van Vuuren, Detlef P.

    2015-02-01

    This paper analyses the effect of different emission metrics and metric values on timing and costs of greenhouse gas mitigation in least-cost emission pathways aimed at a forcing level of 3.5 W m-2 in 2100. Such an assessment is currently relevant in view of UNFCCC’s decision to replace the values currently used. An emission metric determines the relative weights of non-CO2 greenhouse gases in obtaining CO2-equivalent emissions. For the first commitment period of the Kyoto Protocol, the UNFCCC has used 100 year global warming potential (GWP) values as reported in IPCC’s Second Assessment Report. For the second commitment period, the UNFCCC has decided to use 100 year GWP values from IPCC’s Fourth Assessment Report. We find that such a change has only a minor impact on (the optimal timing of) global emission reductions and costs. However, using 20 year or 500 year GWPs to value non-CO2 greenhouse gases does result in a significant change in both costs and emission reductions in our model. CO2 reductions are favored over non-CO2 gases when the time horizon of the GWPs is increased. Application of GWPs with time horizons longer than 100 year can increase abatement costs substantially, by about 20% for 500 year GWPs. Surprisingly, we find that implementation of a metric based on a time-dependent global temperature potential does not necessary lead to lower abatement costs. The crucial factor here is how fast non-CO2 emissions can be reduced; if this is limited, the delay in reducing methane emissions cannot be (fully) compensated for later in the century, which increases total abatement costs.

  12. SnO2/PPy Screen-Printed Multilayer CO2 Gas Sensor

    Directory of Open Access Journals (Sweden)

    S.A. WAGHULEY

    2007-05-01

    Full Text Available Tin dioxide (SnO2 plays a dominant role in solid state gas sensors and exhibit sensitivity towards oxidizing and reducing gases by a variation of its electrical properties. The electrical conducting polymer-polypyrrole (PPy has high anisotropy of electrical conduction and used as a gas sensor. SnO2/PPy multilayer, pure SnO2, pure PPy sensors were prepared by screen-printing method on Al2O3 layer followed by glass substrate. The sensors were used for different concentration (ppm of CO2 gas investigation at room temperature (303 K. The sensitivity of SnO2/PPy multilayer sensor was found to be higher, compared with pure SnO2 and pure PPy sensors. The multilayer sensor exhibited improved stability. The response and recovery time of multilayer sensor were found to be ~2 min and ~10 min respectively.

  13. Effect of Feed Gas Flow Rate on CO2 Absorption through Super Hydrophobic Hollow Fiber membrane Contactor

    Science.gov (United States)

    Kartohardjono, Sutrasno; Alexander, Kevin; Larasati, Annisa; Sihombing, Ivander Christian

    2018-03-01

    Carbon dioxide is pollutant in natural gas that could reduce the heating value of the natural gas and cause problem in transportation due to corrosive to the pipeline. This study aims to evaluate the effects of feed gas flow rate on CO2 absorption through super hydrophobic hollow fiber contactor. Polyethyleneglycol-300 (PEG-300) solution was used as absorbent in this study, whilst the feed gas used in the experiment was a mixture of 30% CO2 and 70% CH4. There are three super hydrophobic hollow fiber contactors sized 6 cm and 25 cm in diameter and length used in this study, which consists of 1000, 3000 and 5000 fibers, respectively. The super hydrophobic fiber membrane used is polypropylene-based with outer and inner diameter of about 525 and 235 μm, respectively. In the experiments, the feed gas was sent through the shell side of the membrane contactor, whilst the absorbent solution was pumped through the lumen fibers. The experimental results showed that the mass transfer coefficient, flux, absorption efficiency for CO2-N2 system and CO2 loading increased with the feed gas flow rate, but the absorption efficiency for CO2-N2 system decreased. The mass transfer coefficient and the flux, at the same feed gas flow rate, decreased with the number of fibers in the membrane contactor, but the CO2 absorption efficiency and the CO2 loading increased.

  14. Embodied greenhouse gas emission by Macao

    International Nuclear Information System (INIS)

    Li, J.S.; Chen, G.Q.; Lai, T.M.; Ahmad, B.; Chen, Z.M.; Shao, L.; Ji, Xi

    2013-01-01

    Comprehensive inventory of cities' greenhouse gas emissions (GHG) is the basis for cities to make appropriate mitigation plans. However, previous studies on cities' GHG emissions consider emissions occurring within the city boundary (Scope 1) and out of boundary electricity emissions (Scope 2), but neglect indirect emissions associated with commodities consumed by cities (Scope 3), resulting in emission leakage. To cope with this problem, a systematic accounting covering all 3 scopes is presented in a case study of Macao for the years 2005–2009, based on the latest embodied emission intensity databases for China and for the world. The results show that total emissions are dominated by indirect emissions mainly embodied in imports, which is 3–4 times direct emissions during the period concerned. It is verified that accounting under Scopes 1 and 2 cannot capture the full picture of cities' emissions, especially cities like Macao which are dominated by service industry and inevitably sustained by massive materials and services from other regions. Our study suggests that Macao should adjust its current GHG mitigation policies which consider only its emissions occurring within its border, as Macao is a net GHG emissions importer. This work is the first assessment of Macao's embodied GHG emissions. - Highlights: • A systematic accounting procedure is presented to inventory a city's GHG emissions. • A comprehensive review of GHG emissions is performed for Macao. • Indirect GHG emissions dominate Macao's embodied GHG emissions. • Macao induced large amount of GHG emissions in other regions through trade. • The variation in GHG emission structure against socio-economic changes is revealed

  15. Measuring and controlling greenhouse gas emissions

    International Nuclear Information System (INIS)

    Bourrier, Herve; LAFONT, Bruno; Fischer, Severin; Leonard, Damien; Tutenuit, Claire

    2011-05-01

    As providing a reporting of their greenhouse gas emissions has become mandatory for a large number of French companies, this publication proposes a methodology to perform an assessment or measurement, and a control of such emissions. In its first part, it explains why measurements are required: indication of concerned gases, international consensus to limit temperature rise, definition and chronology of the main steps adopted at the international level and which must be considered in the approach adopted by enterprises in this respect. It outlines the benefits of such a measurement for the enterprise in terms of competitiveness, personnel commitment, new markets and products, image, compliance with the law, operational and financial aspects, and so on. It identifies the various stakeholders to be informed: civil society, financial community, public authorities, clients and consumers, personnel, suppliers. It outlines the diversity and evolution of legal frameworks at the international level as well as at national levels. While evoking many examples of French companies (SNCF, EDF, Seche Environnement, RTE, Michelin, Arcelormittal, AREVA, Air France, EADS-Airbus, AXA, Veolia, and so on), the next part addresses how to measure emissions. It outlines the complexity of the methodological landscape with its various criteria, evokes the various existing standards, outlines the distinction between organisation-based, product-based and project-based approaches, and the distinction between direct and indirect emissions in relationship with the notion of scope. It comments the existence of sector-based methodologies and guidelines, and discusses some difficulties and methodological decisions. The third part proposes some lessons learned from the experience which could lead to a harmonisation of methodologies, proposes a synthesis of reporting approaches, outlines risks and opportunities related to communication

  16. Dissolution of cemented fractures in gas bearing shales in the context of CO2 sequestration

    Science.gov (United States)

    Kwiatkowski, Kamil; Szymczak, Piotr

    2016-04-01

    Carbon dioxide has a stronger binding than methane to the organic matter contained in the matrix of shale rocks [1]. Thus, the injection of CO2 into shale formation may enhance the production rate and total amount of produced methane, and simultaneously permanently store pumped CO2. Carbon dioxide can be injected during the initial fracking stage as CO2 based hydraulic fracturing, and/or later, as a part of enhanced gas recovery (EGR) [2]. Economic and environmental benefits makes CO2 sequestration in shales potentially very for industrial-scale operation [3]. However, the effective process requires large area of fracture-matrix interface, where CO2 and CH4 can be exchanged. Usually natural fractures, existing in shale formation, are preferentially reactivated during hydraulic fracturing, thus they considerably contribute to the flow paths in the resulting fracture system [4]. Unfortunately, very often these natural fractures are sealed by calcite [5]. Consequently the layer of calcite coating surfaces impedes exchange of gases, both CO2 and CH4, between shale matrix and fracture. In this communication we address the question whether carbonic acid, formed when CO2 is mixed with brine, is able to effectively dissolve a calcite layer present in the natural fractures. We investigate numerically fluid flow and dissolution of calcite coating in natural shale fractures, with CO2-brine mixture as a reactive fluid. Moreover, we discuss the differences between slow dissolution (driven by carbonic acid) and fast dissolution (driven by stronger hydrochloric acid) of calcite layer. We compare an impact of the flow rate and geometry of the fracture on the parameters of practical importance: available surface area, morphology of dissolution front, time scale of the dissolution, and the penetration length. We investigate whether the dissolution is sufficiently non-uniform to retain the fracture permeability, even in the absence of the proppant. The sizes of analysed fractures

  17. Transmucosal gas-loss rates in middle ears initially filled with O2 or CO2.

    Science.gov (United States)

    Kania, Romain E; Vérillaud, Benjamin; Ars, Bernard; Tran Ba Huy, Patrice; Herman, Philippe; Ar, Amos

    2016-10-01

    This study investigates the role of different gases in clearance of gas in the middle ear cavity (ME) by its mucosal blood flow. A rat model was used to measure gas volume changes in the ME cavity at constant pressure without ventilation. We disturbed the normal gas composition of the ME by filling it with O 2 or CO 2 , measured the consequent changes in gas volume over time and compared these results with previously obtained ones for air and N 2 . The first 5 min of the primary transient phase (phase I) for O 2 or CO 2 was characterized by a volume loss decrease of -0.49 ± 0.34 μL and -46.28 ± 8.49 μL, respectively, with volume loss increase for air and N 2 differing greatly, at +0.17 ± 0.17 and +2.31 ± 0.81, respectively. The CO 2 value of -46.28 μL showed that a volume of gas equivalent to that of the ME cleft volume was eliminated within the first 5 min. In the second phase (phase II), all gases showed a linear decrease in volume, which presumably represents a steady-state gas loss rate. However, the gas loss rate of -0.307 ± 0.170 μL min -1 for O 2 -filled MEs was significantly higher than the mean of -0.124 μL min -1 for all other gases. We used a previously established mathematical model to calculate the effective ME mucosal blood flow rate under steady-state (phase II) conditions. The blood flow results for O 2 -filled MEs differed greatly from those of the other gases (89.0 ± 49.28 vs. 26.5 μL min -1 , on average), which suggest that the model used to calculate blood flow should be modified if used with O 2 -filled MEs. Further work should involve a comparison of our method with different methods to verify ME blood flow rate. Copyright © 2016 Elsevier B.V. All rights reserved.

  18. Wellbeing impacts of city policies for reducing greenhouse gas emissions

    DEFF Research Database (Denmark)

    Hiscock, Rosemary; Mudu, Pierpaolo; Braubach, Matthias

    2014-01-01

    To mitigate climate change, city authorities are developing policies in areas such as transportation, housing and energy use, to reduce greenhouse gas emissions. In addition to their effects on greenhouse gas emissions, these policies are likely to have consequences for the wellbeing of their pop......To mitigate climate change, city authorities are developing policies in areas such as transportation, housing and energy use, to reduce greenhouse gas emissions. In addition to their effects on greenhouse gas emissions, these policies are likely to have consequences for the wellbeing...... of their populations for example through changes in opportunities to take physical exercise. In order to explore the potential consequences for wellbeing, we first explore what ?wellbeing? is and how it can be operationalised for urban planners. In this paper, we illustrate how wellbeing can be divided into objective...

  19. FY2010 Federal Government Greenhouse Gas Inventory by Agency

    Data.gov (United States)

    Council on Environmental Quality, Executive Office of the President — The comprehensive Greenhouse Gas (GHG) Emissions Inventory for the Federal Government accounts for emissions associated with Federal operations in FY 2010. Attached...

  20. Incorporating greenhouse gas (GHG) emissions in long range transportation planning.

    Science.gov (United States)

    2014-05-01

    Greenhouse gas (GHG) emissions continue to be an important focus area for state, local, and federal : agencies. The transportation sector is the second biggest contributor to GHG emissions in the U.S., and : Texas contributes the highest emissions am...

  1. Greenhouse gas emission impacts of carsharing in North America

    Science.gov (United States)

    2010-06-01

    This report presents the results of a study evaluating the greenhouse gas (GHG) emission changes that result from individuals participating in a carsharing organization. In this study, the authors conducted a survey of carsharing members across the c...

  2. Interagency Pilot of Greenhouse Gas Accounting Tools: Lessons Learned

    Energy Technology Data Exchange (ETDEWEB)

    Carpenter, A.; Hotchkiss, E.; Kandt, A.

    2013-02-01

    The Greater Yellowstone Area (GYA) and Tongass National Forest (Tongass) partnered with the National Renewable Energy Laboratory (NREL) to conduct a pilot study of three greenhouse gas (GHG) inventorying tools.

  3. Detection of Greenhouse-Gas-Induced Climatic Change

    Energy Technology Data Exchange (ETDEWEB)

    Jones, P.D.; Wigley, T.M.L.

    1998-05-26

    The objective of this report is to assemble and analyze instrumental climate data and to develop and apply climate models as a basis for (1) detecting greenhouse-gas-induced climatic change, and (2) validation of General Circulation Models.

  4. Are national greenhouse gas emissions reports scientifically valid

    NARCIS (Netherlands)

    Swart, R.J.; Bergamaschi, P.; Pulles, T.; Raes, F.

    2007-01-01

    While countries have recently been accused of misreporting greenhouse gas emissions for their benefit, internationally agreed procedures minimize such possibilities and allow for new scientific results to be taken into account in a stepwise manner.

  5. Are national greenhouse gas emissions reports scientifically valid?

    NARCIS (Netherlands)

    Swart, R.; Bergamaschi, P.; Pulles, M.P.J.; Raes, F.

    2007-01-01

    While countries have recently been accused of misreporting greenhouse gas emissions for their benefit, internationally agreed procedures minimize such possibilities and allow for new scientific results to be taken into account in a stepwise manner. © 2007 Earthscan.

  6. Synthesizing greenhouse gas fluxes across nine European peatlands and shrublands - responses to climatic and environmental changes

    DEFF Research Database (Denmark)

    Carter, M.S.; Larsen, Klaus Steenberg; Emmett, B.

    2012-01-01

    degrees C, and in annual precipitation from 300 to 1300 mm yr(-1). The effects of climate change, including temperature increase and prolonged drought, were tested at five shrubland sites. At one peatland site, the long-term (> 30 yr) effect of drainage was assessed, while increased nitrogen deposition...... in control plots ranged from 310 to 732 g CO2-Cm-2 yr(-1). Drought and long-term drainage generally reduced the soil CO2 efflux, except at a hydric shrubland where drought tended to increase soil respiration. In terms of fractional importance of each greenhouse gas to the total numerical global warming...... response, the change in CO2 efflux dominated the response in all treatments (ranging 71-96%), except for NO3- addition where 89% was due to change in CH4 emissions. Thus, in European peatlands and shrublands the effect on global warming induced by the investigated anthropogenic disturbances...

  7. Quantifying greenhouse gas emissions from coal fires using airborne and ground-based methods

    Science.gov (United States)

    Engle, Mark A.; Radke, Lawrence F.; Heffern, Edward L.; O'Keefe, Jennifer M.K.; Smeltzer, Charles; Hower, James C.; Hower, Judith M.; Prakash, Anupma; Kolker, Allan; Eatwell, Robert J.; ter Schure, Arnout; Queen, Gerald; Aggen, Kerry L.; Stracher, Glenn B.; Henke, Kevin R.; Olea, Ricardo A.; Román-Colón, Yomayara

    2011-01-01

    Coal fires occur in all coal-bearing regions of the world and number, conservatively, in the thousands. These fires emit a variety of compounds including greenhouse gases. However, the magnitude of the contribution of combustion gases from coal fires to the environment is highly uncertain, because adequate data and methods for assessing emissions are lacking. This study demonstrates the ability to estimate CO2 and CH4 emissions for the Welch Ranch coal fire, Powder River Basin, Wyoming, USA, using two independent methods: (a) heat flux calculated from aerial thermal infrared imaging (3.7–4.4 t d−1 of CO2 equivalent emissions) and (b) direct, ground-based measurements (7.3–9.5 t d−1 of CO2 equivalent emissions). Both approaches offer the potential for conducting inventories of coal fires to assess their gas emissions and to evaluate and prioritize fires for mitigation.

  8. Quantitative measurement of carbon isotopic composition in CO2gas reservoir by Micro-Laser Raman spectroscopy.

    Science.gov (United States)

    Li, Jiajia; Li, Rongxi; Zhao, Bangsheng; Guo, Hui; Zhang, Shuan; Cheng, Jinghua; Wu, Xiaoli

    2018-04-15

    The use of Micro-Laser Raman spectroscopy technology for quantitatively determining gas carbon isotope composition is presented. In this study, 12 CO 2 and 13 CO 2 were mixed with N 2 at various molar fraction ratios to obtain Raman quantification factors (F 12CO2 and F 13CO2 ), which provide a theoretical basis for calculating the δ 13 C value. And the corresponding values were 0.523 (0CO2 /C N2 <2) and 1.11998 (0CO2 /C N2 <1.5) respectively. It has shown that the representative Raman peak area can be used for the determination of δ 13 C values within the relative errors range of 0.076% to 1.154% in 13 CO 2 / 12 CO 2 binary mixtures when F 12CO2 /F 13CO2 is 0.466972625. In addition, measurement of δ 13 C values by Micro-Laser Raman analysis were carried out on natural CO 2 gas from Shengli Oil-field at room temperature under different pressures. The δ 13 C values obtained by Micro-Laser Raman spectroscopy technology and Isotope Ratio Mass Spectrometry (IRMS) technology are in good agreement with each other, and the relative errors range of δ 13 C values is 1.232%-6.964%. This research provides a fundamental analysis tool for determining gas carbon isotope composition (δ 13 C values) quantitatively by using Micro-Laser Raman spectroscopy. Experiment of results demonstrates that this method has the potential for obtaining δ 13 C values in natural CO 2 gas reservoirs. Copyright © 2018. Published by Elsevier B.V.

  9. Historical greenhouse gas concentrations for climate modelling (CMIP6)

    Science.gov (United States)

    Meinshausen, Malte; Vogel, Elisabeth; Nauels, Alexander; Lorbacher, Katja; Meinshausen, Nicolai; Etheridge, David M.; Fraser, Paul J.; Montzka, Stephen A.; Rayner, Peter J.; Trudinger, Cathy M.; Krummel, Paul B.; Beyerle, Urs; Canadell, Josep G.; Daniel, John S.; Enting, Ian G.; Law, Rachel M.; Lunder, Chris R.; O'Doherty, Simon; Prinn, Ron G.; Reimann, Stefan; Rubino, Mauro; Velders, Guus J. M.; Vollmer, Martin K.; Wang, Ray H. J.; Weiss, Ray

    2017-05-01

    Atmospheric greenhouse gas (GHG) concentrations are at unprecedented, record-high levels compared to the last 800 000 years. Those elevated GHG concentrations warm the planet and - partially offset by net cooling effects by aerosols - are largely responsible for the observed warming over the past 150 years. An accurate representation of GHG concentrations is hence important to understand and model recent climate change. So far, community efforts to create composite datasets of GHG concentrations with seasonal and latitudinal information have focused on marine boundary layer conditions and recent trends since the 1980s. Here, we provide consolidated datasets of historical atmospheric concentrations (mole fractions) of 43 GHGs to be used in the Climate Model Intercomparison Project - Phase 6 (CMIP6) experiments. The presented datasets are based on AGAGE and NOAA networks, firn and ice core data, and archived air data, and a large set of published studies. In contrast to previous intercomparisons, the new datasets are latitudinally resolved and include seasonality. We focus on the period 1850-2014 for historical CMIP6 runs, but data are also provided for the last 2000 years. We provide consolidated datasets in various spatiotemporal resolutions for carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O), as well as 40 other GHGs, namely 17 ozone-depleting substances, 11 hydrofluorocarbons (HFCs), 9 perfluorocarbons (PFCs), sulfur hexafluoride (SF6), nitrogen trifluoride (NF3) and sulfuryl fluoride (SO2F2). In addition, we provide three equivalence species that aggregate concentrations of GHGs other than CO2, CH4 and N2O, weighted by their radiative forcing efficiencies. For the year 1850, which is used for pre-industrial control runs, we estimate annual global-mean surface concentrations of CO2 at 284.3 ppm, CH4 at 808.2 ppb and N2O at 273.0 ppb. The data are available at https://esgf-node.llnl.gov/search/input4mips/ and http

  10. Idaho National Laboratory’s FY14 Greenhouse Gas Report

    Energy Technology Data Exchange (ETDEWEB)

    Frerichs, Kimberly Irene [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2014 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho. In recent years, concern has grown about the environmental impact of GHGs. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of an inventory of the total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions. INL’s GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL’s organizational boundaries, but are a consequence of INL’s activities). This inventory found that INL generated 73,521 metric tons (MT) of CO2 equivalent (CO2e ) emissions during FY14. The following conclusions were made from looking at the results of the individual contributors to INL’s FY14 GHG inventory: • Electricity (including the associated transmission and distribution losses) is the largest contributor to INL’s GHG inventory, with over 50% of the CO2e emissions • Other sources with high emissions were

  11. Assessing the greenhouse gas emissions of Brazilian soybean biodiesel production

    Science.gov (United States)

    You, Xin; Cherubin, Maurício Roberto; Moreira, Cindy Silva; Raucci, Guilherme Silva; Castigioni, Bruno de Almeida; Alves, Priscila Aparecida; Cerri, Domingos Guilherme Pellegrino; Mello, Francisco Fujita de Castro; Cerri, Carlos Clemente

    2017-01-01

    Soybean biodiesel (B100) has been playing an important role in Brazilian energy matrix towards the national bio-based economy. Greenhouse gas (GHG) emissions is the most widely used indicator for assessing the environmental sustainability of biodiesels and received particular attention among decision makers in business and politics, as well as consumers. Former studies have been mainly focused on the GHG emissions from the soybean cultivation, excluding other stages of the biodiesel production. Here, we present a holistic view of the total GHG emissions in four life cycle stages for soybean biodiesel. The aim of this study was to assess the GHG emissions of Brazilian soybean biodiesel production system with an integrated life cycle approach of four stages: agriculture, extraction, production and distribution. Allocation of mass and energy was applied and special attention was paid to the integrated and non-integrated industrial production chain. The results indicated that the largest source of GHG emissions, among four life cycle stages, is the agricultural stage (42–51%) for B100 produced in integrated systems and the production stage (46–52%) for B100 produced in non-integrated systems. Integration of industrial units resulted in significant reduction in life cycle GHG emissions. Without the consideration of LUC and assuming biogenic CO2 emissions is carbon neutral in our study, the calculated life cycle GHG emissions for domestic soybean biodiesel varied from 23.1 to 25.8 gCO2eq. MJ-1 B100 and those for soybean biodiesel exported to EU ranged from 26.5 to 29.2 gCO2eq. MJ-1 B100, which represent reductions by 65% up to 72% (depending on the delivery route) of GHG emissions compared with the EU benchmark for diesel fuel. Our findings from a life cycle perspective contributed to identify the major GHG sources in Brazilian soybean biodiesel production system and they can be used to guide mitigation priority for policy and decision-making. Projected scenarios in

  12. The FAOSTAT database of greenhouse gas emissions from agriculture

    International Nuclear Information System (INIS)

    Tubiello, Francesco N; Salvatore, Mirella; Rossi, Simone; Ferrara, Alessandro; Fitton, Nuala; Smith, Pete

    2013-01-01

    Greenhouse gas (GHG) emissions from agriculture, including crop and livestock production, forestry and associated land use changes, are responsible for a significant fraction of anthropogenic emissions, up to 30% according to the Intergovernmental Panel on Climate Change (IPCC). Yet while emissions from fossil fuels are updated yearly and by multiple sources—including national-level statistics from the International Energy Agency (IEA)—no comparable efforts for reporting global statistics for agriculture, forestry and other land use (AFOLU) emissions exist: the latest complete assessment was the 2007 IPCC report, based on 2005 emission data. This gap is critical for several reasons. First, potentially large climate funding could be linked in coming decades to more precise estimates of emissions and mitigation potentials. For many developing countries, and especially the least developed ones, this requires improved assessments of AFOLU emissions. Second, growth in global emissions from fossil fuels has outpaced that from AFOLU during every decade of the period 1961–2010, so the relative contribution of the latter to total climate forcing has diminished over time, with a need for regular updates. We present results from a new GHG database developed at FAO, providing a complete and coherent time series of emission statistics over a reference period 1961–2010, at country level, based on FAOSTAT activity data and IPCC Tier 1 methodology. We discuss results at global and regional level, focusing on trends in the agriculture sector and net deforestation. Our results complement those available from the IPCC, extending trend analysis to a longer historical period and, critically, beyond 2005 to more recent years. In particular, from 2000 to 2010, we find that agricultural emissions increased by 1.1% annually, reaching 4.6 Gt CO 2 yr −1 in 2010 (up to 5.4–5.8 Gt CO 2 yr −1 with emissions from biomass burning and organic soils included). Over the same decade

  13. Assessing the greenhouse gas emissions of Brazilian soybean biodiesel production.

    Directory of Open Access Journals (Sweden)

    Carlos Eduardo Pellegrino Cerri

    Full Text Available Soybean biodiesel (B100 has been playing an important role in Brazilian energy matrix towards the national bio-based economy. Greenhouse gas (GHG emissions is the most widely used indicator for assessing the environmental sustainability of biodiesels and received particular attention among decision makers in business and politics, as well as consumers. Former studies have been mainly focused on the GHG emissions from the soybean cultivation, excluding other stages of the biodiesel production. Here, we present a holistic view of the total GHG emissions in four life cycle stages for soybean biodiesel. The aim of this study was to assess the GHG emissions of Brazilian soybean biodiesel production system with an integrated life cycle approach of four stages: agriculture, extraction, production and distribution. Allocation of mass and energy was applied and special attention was paid to the integrated and non-integrated industrial production chain. The results indicated that the largest source of GHG emissions, among four life cycle stages, is the agricultural stage (42-51% for B100 produced in integrated systems and the production stage (46-52% for B100 produced in non-integrated systems. Integration of industrial units resulted in significant reduction in life cycle GHG emissions. Without the consideration of LUC and assuming biogenic CO2 emissions is carbon neutral in our study, the calculated life cycle GHG emissions for domestic soybean biodiesel varied from 23.1 to 25.8 gCO2eq. MJ-1 B100 and those for soybean biodiesel exported to EU ranged from 26.5 to 29.2 gCO2eq. MJ-1 B100, which represent reductions by 65% up to 72% (depending on the delivery route of GHG emissions compared with the EU benchmark for diesel fuel. Our findings from a life cycle perspective contributed to identify the major GHG sources in Brazilian soybean biodiesel production system and they can be used to guide mitigation priority for policy and decision-making. Projected

  14. Assessing the greenhouse gas emissions of Brazilian soybean biodiesel production.

    Science.gov (United States)

    Cerri, Carlos Eduardo Pellegrino; You, Xin; Cherubin, Maurício Roberto; Moreira, Cindy Silva; Raucci, Guilherme Silva; Castigioni, Bruno de Almeida; Alves, Priscila Aparecida; Cerri, Domingos Guilherme Pellegrino; Mello, Francisco Fujita de Castro; Cerri, Carlos Clemente

    2017-01-01

    Soybean biodiesel (B100) has been playing an important role in Brazilian energy matrix towards the national bio-based economy. Greenhouse gas (GHG) emissions is the most widely used indicator for assessing the environmental sustainability of biodiesels and received particular attention among decision makers in business and politics, as well as consumers. Former studies have been mainly focused on the GHG emissions from the soybean cultivation, excluding other stages of the biodiesel production. Here, we present a holistic view of the total GHG emissions in four life cycle stages for soybean biodiesel. The aim of this study was to assess the GHG emissions of Brazilian soybean biodiesel production system with an integrated life cycle approach of four stages: agriculture, extraction, production and distribution. Allocation of mass and energy was applied and special attention was paid to the integrated and non-integrated industrial production chain. The results indicated that the largest source of GHG emissions, among four life cycle stages, is the agricultural stage (42-51%) for B100 produced in integrated systems and the production stage (46-52%) for B100 produced in non-integrated systems. Integration of industrial units resulted in significant reduction in life cycle GHG emissions. Without the consideration of LUC and assuming biogenic CO2 emissions is carbon neutral in our study, the calculated life cycle GHG emissions for domestic soybean biodiesel varied from 23.1 to 25.8 gCO2eq. MJ-1 B100 and those for soybean biodiesel exported to EU ranged from 26.5 to 29.2 gCO2eq. MJ-1 B100, which represent reductions by 65% up to 72% (depending on the delivery route) of GHG emissions compared with the EU benchmark for diesel fuel. Our findings from a life cycle perspective contributed to identify the major GHG sources in Brazilian soybean biodiesel production system and they can be used to guide mitigation priority for policy and decision-making. Projected scenarios in this

  15. Vehicle emissions of greenhouse gases and related tracers from a tunnel study: : CO: CO2, N2O: CO2, CH4: CO2, O2: CO2 ratios, and the stable isotopes 13C and 18O in CO2 and CO

    NARCIS (Netherlands)

    Popa, Maria Elena; Vollmer, M. K.; Jordan, A.; Brand, W. A.; Pathirana, S. L.; Rothe, M.; Röckmann, T.

    2014-01-01

    Measurements of CO2, CO, N2O and CH4 mole fractions, O2/N2 ratios and the stable isotopes 13C and 18O in CO2 and CO have been performed in air samples from the Islisberg highway tunnel (Switzerland). The molar CO : CO2 ratios, with an average of (4.15 ± 0.34) ppb:ppm, are lower than reported in

  16. Greenhouse gas emissions from heavy-duty natural gas, hybrid, and conventional diesel on-road trucks during freight transport

    Science.gov (United States)

    Quiros, David C.; Smith, Jeremy; Thiruvengadam, Arvind; Huai, Tao; Hu, Shaohua

    2017-11-01

    Heavy-duty on-road vehicles account for 70% of all freight transport and 20% of transportation-sector greenhouse gas (GHG) emissions in the United States. This study measured three prevalent GHG emissions - carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) - from seven heavy-duty vehicles, fueled by diesel and compressed natural gas (CNG), and compliant to the MY 2007 or 2010 U.S. EPA emission standards, while operated over six routes used for freight movement in California. Total combined (tractor, trailer, and payload) weights were 68,000 ± 1000 lbs. for the seven vehicles. Using the International Panel on Climate Change (IPCC) radiative forcing values for a 100-year time horizon, N2O emissions accounted for 2.6-8.3% of total tailpipe CO2 equivalent emissions (CO2-eq) for diesel vehicles equipped with Diesel Oxidation Catalyst, Diesel Particulate Filter, and Selective Catalytic Reduction system (DOC + DPF + SCR), and CH4 emissions accounted for 1.4-5.9% of CO2-eq emissions from the CNG-powered vehicle with a three-way catalyst (TWC). N2O emissions from diesel vehicles equipped with SCR (0.17-0.30 g/mi) were an order of magnitude higher than diesel vehicles without SCR (0.013-0.023 g/mi) during highway operation. For the vehicles selected in this test program, we measured 11-22% lower CO2-eq emissions from a hybrid compared to conventional diesel vehicles during transport over lower-speed routes of the freight transport system, but 20-27% higher CO2-eq emissions during higher-speed routes. Similarly, a CNG vehicle emitted up to 15% lower CO2-eq compared to conventional diesel vehicles over more neutral-grade highway routes, but emitted up to 12% greater CO2-eq emissions over routes with higher engine loads.

  17. More gas, less coal, and less CO2? Unilateral CO2 reduction policy with more than one carbon energy source

    DEFF Research Database (Denmark)

    Daubanes, Julien Xavier; Henriet, Fanny; Schubert, Katheline

    We examine an open economy’s strategy to reduce its carbon emissions by replacing its consumption of coal—very carbon intensive—with gas—less so. Unlike the standard analysis of carbon leakage, unilateral carbon-reduction policies with more than one carbon energy source may turn counter......-productive, ultimately increasing world emissions. Thus, we establish testable conditions as to whether a governmental emission-reduction commitment warrants the exploitation of gas, and whether such a strategy increases global emissions. We also characterize the extent to which this unilateral policy makes the rest...

  18. CO2 Sequestration short course

    Energy Technology Data Exchange (ETDEWEB)

    DePaolo, Donald J. [Lawrence Berkeley National Laboratory; Cole, David R [The Ohio State University; Navrotsky, Alexandra [University of California-Davis; Bourg, Ian C [Lawrence Berkeley National Laboratory

    2014-12-08

    Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  19. Quantifying and reporting greenhouse gas emissions at local level

    OpenAIRE

    Sόwka Izabela; Bezyk Yaroslav

    2017-01-01

    Cities as global centers of consumption and production often are a significant and growing source of greenhouse gas (GHG) emissions. At the same time, local authorities are increasingly taking action on climate change by focusing on reducing GHG emissions and efficiency improvement opportunities. To assess and reduce the overall greenhouse gas emission level from an urban area, it is necessary to identify all the activities and processes which generate these emissions. GHG inventory gives an ...

  20. Wellbeing impacts of city policies for reducing greenhouse gas emissions

    OpenAIRE

    Hiscock, Rosemary; Mudu, Pierpaolo; Braubach, Matthias; Martuzzi, Marco; Perez, Laura; Sabel, Clive

    2014-01-01

    To mitigate climate change, city authorities are developing policies in areas such as transportation, housing and energy use, to reduce greenhouse gas emissions. In addition to their effects on greenhouse gas emissions, these policies are likely to have consequences for the wellbeing of their populations for example through changes in opportunities to take physical exercise. In order to explore the potential consequences for wellbeing, we first explore what ‘wellbeing’ is and how it can be op...

  1. Estimation of greenhouse gases (N2O, CH4 and CO2) from no-till cropland under increased temperature and altered precipitation regime: a DAYCENT model approach

    Science.gov (United States)

    Rafique, Rashad; Kumar, Sandeep; Luo, Yiqi; Xu, Xianli; Li, Dejun; Zhang, Wei; Asam, Zaki-ul-Zaman

    2014-07-01

    Greenhouse gas (GHG) emissions play an important role in regulating the Earth surface temperature. GHG emissions from soils are sensitive to climate change and land management practices. According to general circulation model (GCM) predictions, the Earth will experience a combination of increased temperature and altered precipitation regimes which may result in an increase or a decrease of GHG exchange. The effect of climate change on GHG emissions can be examined through both experiments and by applying process-based models, which have become more popular. The performance of those models can be improved significantly by appropriate calibration procedures. The objectives of this study are to: (i) calibrate the DAYCENT model using advance parameter estimation (PEST) software and to (ii) examine simulated GHG dynamics at daily and seasonal time-scales under a climate change scenario of increased temperature (2 °C) and a precipitation regime change where 40% of precipitation during the dry season was redistributed to the wet season. The algorithmic calibration improved the model performance by reducing the sum of weighted squared residual differences by up to 223% (decreased from 1635 to 505 g N2O-N ha- 1 d- 1) for N2O and 22% (decreased from 623 to 507% WFPS) for water filled pore space (WFPS) simulation results. In the altered climate scenario, total N2O and CO2 fluxes decreased by 9% (from 2.31 to 2.10 kg N2O-N ha- 1 yr- 1) and 38% (from 1134.08 to 699.56 kg CO2 ha- 1 yr- 1) respectively, whereas CH4 fluxes increased by 10% (from 1.62 to 1.80 kg CH4 ha- 1 yr- 1). Our results show a larger impact of altered climate on CO2 as compared to N2O and CH4 emissions. The main difference in all GHG emissions was observed in summer period due to drought conditions created by reduced precipitation and increased temperatures. However, the GHG dynamics can also be attributed to no-till practices which play an important role in changing the soil moisture conditions for aerobic

  2. Coastal vegetation invasion increases greenhouse gas emission from wetland soils but also increases soil carbon accumulation.

    Science.gov (United States)

    Chen, Yaping; Chen, Guangcheng; Ye, Yong

    2015-09-01

    Soil properties and soil-atmosphere fluxes of CO2, CH4 and N2O from four coastal wetlands were studied throughout the year, namely, native Kandelia obovata mangrove forest vs. exotic Sonneratia apetala mangrove forest, and native Cyperus malaccensis salt marsh vs. exotic Spartina alterniflora salt marsh. Soils of the four wetlands were all net sources of greenhouse gases while Sonneratia forest contributed the most with a total soil-atmosphere CO2-equivalent flux of 137.27 mg CO2 m(-2) h(-1), which is 69.23%, 99.75% and 44.56% higher than that of Kandelia, Cyperus and Spartina, respectively. The high underground biomass and distinctive root structure of Sonneratia might be responsible for its high greenhouse gas emission from the soil. Soils in Spartina marsh emitted the second largest amount of total greenhouse gases but it ranked first in emitting trace greenhouse gases. Annual average CH4 and N2O fluxes from Spartina soil were 13.77 and 1.14 μmol m(-2) h(-1), respectively, which are 2.08 and 1.46 times that of Kandelia, 1.03 and 1.15 times of Sonneratia, and 1.74 and 1.02 times of Cyperus, respectively. Spartina has longer growing season and higher productivity than native marshes which might increase greenhouse gas emission in cold seasons. Exotic wetland soils had higher carbon stock as compared to their respective native counterparts but their carbon stocks were offset by a larger proportion because of their higher greenhouse gas emissions. Annual total soil-atmosphere fluxes of greenhouse gases reduced soil carbon burial benefits by 8.1%, 9.5%, 6.4% and 7.2% for Kandelia, Sonneratia, Cyperus and Spartina, respectively, which narrowed down the gaps in net soil carbon stock between native and exotic wetlands. The results indicated that the invasion of exotic wetland plants might convert local coastal soils into a considerable atmospheric source of greenhouse gases although they at the same time increase soil carbon accumulation. Copyright © 2015. Published

  3. Effects of Greenhouse Gas Emissions on World Agriculture, Food Consumption, and Economic Welfare

    International Nuclear Information System (INIS)

    Darwin, R.

    2004-01-01

    Because of many uncertainties, quantitative estimates of agriculturally related economic impacts of greenhouse gas emissions are often given low confidence. A major source of uncertainty is our inability to accurately project future changes in economic activity, emissions, and climate. This paper focuses on two issues. First, to what extent do variable projections of climate generate uncertainty in agriculturally related economic impacts? Second, to what extent do agriculturally related economic impacts of greenhouse gas emissions depend on economic conditions at the time of impacts? Results indicate that uncertainty due to variable projections of climate is fairly large for most of the economic effects evaluated in this analysis. Results also indicate that economic conditions at the time of impact influence the direction and size of as well as the confidence in the economic effects of identical projections of greenhouse gas impacts. The economic variable that behaves most consistently in this analysis is world crop production. Increases in mean global temperature, for example, cause world crop production to decrease on average under both 1990 and improved economic conditions and in both instances the confidence with respect to variable projections of climate is medium (e.g., 67%) or greater. In addition and as expected, CO2 fertilization causes world crop production to increase on average under 1990 and improved economic conditions. These results suggest that crop production may be a fairly robust indicator of the potential impacts of greenhouse gas emissions. A somewhat unexpected finding is that improved economic conditions are not necessarily a panacea to potential greenhouse-gas-induced damages, particularly at the region level. In fact, in some regions, impacts of climate change or CO2 fertilization that are beneficial under current economic conditions may be detrimental under improved economic conditions (relative to the new economic base). Australia plus

  4. Pengaruh penambahan Ca(OH2 pada Proses Pirolisis terhadap Hasil Gasifikasi Batubara Bituminus dengan medium Gas CO2

    Directory of Open Access Journals (Sweden)

    Saripah Sobah

    2014-06-01

    Full Text Available Pemanfaatan batubara melalui proses gasifikasi perlu dikembangkan lebih lanjut karena proses ini dapat dijadikan alternatif untuk menggantikan peranan  gas alam sebagai sumber gas sintesis. Di samping itu, proses ini dapat mengurangi pencemaran lingkungan karena teknologi gasifikasi merupakan teknologi yang bersih dan dapat mengurangi jumlah gas CO2 yang dibuang ke lingkungan. Penelitian ini bertujuan untuk mengetahui pengaruh penambahan Ca(OH2 pada proses pirolisis terhadap hasil gasifikasi arang batubara bituminus dengan medium gas CO2. Reaksi karbon dari arang batubara dengan gas CO2 pada proses gasifikasi merupakan reaksi endotermis dan berlangsung sangat lambat pada suhu di bawah 1000oC sehingga digunakan Ca(OH2 sebagai katalisator. Proses gasifikasi batubara dijalankan dalam reaktor fixed bed. Hasil penelitian menunjukkan bahwa gasifikasi arang batubara dengan penambahan Ca(OH2 pada proses pirolisis memberikan pengaruh terhadap komposisi gas hasil yaitu berkurangnya kadar gas CO2 dan menyebabkan berkurangnya kadar belerang pada arang hasil pirolisis dan gasifikasi. Proses ini juga dapat mengurangi kadar gas CO2 sebesar 63,17% dan untuk  gasifikasi tanpa Ca(OH2 , CO2 dapat dikurangi kadarnya sampai 35,2%.

  5. Positive feedback of greenhouse gas balances to warming is determined by non-growing season emissions in an alpine meadow

    Science.gov (United States)

    Niu, S.; Wang, J.; Quan, Q.; Chen, W.; Wen, X.; Yu, G.

    2017-12-01

    Large uncertainties exist in the sources and sinks of greenhouse gases (CO2, CH4, N2O) in response to climate warming and human activity. So far, numerous previous studies have evaluated the CO2 budget, but little attention has paid to CH4 and N2O budgets and the concurrent balance of these three gases in combination, especially in the non-growing season. Here, we synthesized eddy covariance measurement with the automatic chamber measurements of CO2, CH4, and N2O exposed to three levels of temperature treatments (ambient, +1.5 °C, +2.5 °C) and two disturbance treatments (ummowing, mowing) in an alpine meadow on the Tibetan Plateau. We have found that warming caused increase in CH4 uptake and decrease in N2O emission offset little of the enhancement in CO2 emission, triggering a positive feedback to climate warming. Warming switches the ecosystem from a net sink (-17 ± 14 g CO2-eq m-2 yr-1) in the control to a net source of greenhouse gases of 94 ± 36 gCO2-eq m-2 yr-1 in the plots with +1.5 °C warming treatment, and 177 ± 6 gCO2-eq m-2 yr-1 in the plots with +2.5 °C warming treatment. The changes in the non-growing season balance, rather than those in the growing season, dominate the warming responses of annual greehouse gas balance. And this is not changed by mowing. The dominant role of responses of winter greenhouse gas balance in the positive feedback of ecosystem to climate warming highlights that greenhouse gas balance in cold season has to be considered when assessing climate-carbon cycle feedback.

  6. Achieving 80% greenhouse gas reduction target in Saudi Arabia under low and medium oil prices

    International Nuclear Information System (INIS)

    Alshammari, Yousef M.; Sarathy, S. Mani

    2017-01-01

    COP 21 led to a global agreement to limit the earth's rising temperature to less than 2 °C. This will require countries to act upon climate change and achieve a significant reduction in their greenhouse gas emissions which will play a pivotal role in shaping future energy systems. Saudi Arabia is the World's largest exporter of crude oil, and the 11th largest CO 2 emitter. Understanding the Kingdom's role in global greenhouse gas reduction is critical in shaping the future of fossil fuels. Hence, this work presents an optimisation study to understand how Saudi Arabia can meet the CO 2 reduction targets to achieve the 80% reduction in the power generation sector. It is found that the implementation of energy efficiency measures is necessary to enable meeting the 80% target, and it would also lower costs of transition to low carbon energy system while maintaining cleaner use of hydrocarbons with CCS. Setting very deep GHG reduction targets may be economically uncompetitive in consideration of the energy supply requirements. In addition, we determine the breakeven price of crude oil needed to make CCS economically viable. Results show important dimension for pricing CO 2 and the role of CCS compared with alternative sources of energy. - Highlights: • Energy efficiency measures are needed to achieve 80% reduction. • Nuclear appears as an important option to achieve deep cuts in CO 2 by 2050. • Technology improvement can enable using heavy fuel oil with CCS until 2050. • IGCC requires lower net CO 2 footprint in order to be competitive. • Nuclear power causes a sharp increase in the CO 2 avoidance costs.

  7. Interfacial Tension and Contact Angle Determination in Water-sandstone Systems with Injection of Flue Gas and CO2

    NARCIS (Netherlands)

    Shojaikaveh, N.; Rudolph, E.S.J.; Rossen, W.R.; Van Hemert, P.; Wolf, K.H.A.A.

    2013-01-01

    Carbon capture and storage (CCS) has the potential for reducing CO2 emissions to the atmosphere. This option includes storage strategies such as CO2 injection into deep saline aquifers, depleted oil and gas reservoirs, and unmineable coal seams. This process is largely controlled by the interactions

  8. Metal organic framework absorbent platforms for removal of co2 and h2s from natural gas

    KAUST Repository

    Belmabkhout, Youssef

    2016-10-13

    Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

  9. CO2, the greenhouse effect and global warming: from the pioneering work of Arrhenius and Callendar to today's Earth System Models.

    Science.gov (United States)

    Anderson, Thomas R; Hawkins, Ed; Jones, Philip D

    2016-09-01

    to ongoing emissions of CO 2 and other greenhouse gases to the atmosphere. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  10. An energy balance and greenhouse gas profile for county Wexford, Ireland in 2006

    International Nuclear Information System (INIS)

    Curtin, Richard

    2011-01-01

    Highlights: → Residential sector emits 38% of total CO 2 emissions. → Transport and industry/commerce sectors emit 28% each. → Oil composes 91% of total primary energy requirement (TPER). → Methane accounts for 25% of total greenhouse gas emissions. → Agriculture accounts for 36% of total greenhouse gas emissions. -- Abstract: In this paper an energy balance and a greenhouse gas profile has been formulated for the county of Wexford, situated in the south east of Ireland. The energy balance aims to aggregate all energy consumption in the county for the year 2006 across the following sectors; residential, agriculture, commerce and industry, and transport. The results of the energy balance are compared with the previous energy balance of 2001 where it is found that the residential sector is the biggest emitter of CO 2 with 38% of total emissions with the transport and industry/commerce sectors sharing second place on 28%. Consumption of oil is seen to have increased significantly in nearly all sectors, accounting for over 70% of the total final energy consumed (TFC) while the total primary energy requirement (TPER) sees oil consumption accounting for 91% of all fuels consumed. To take into account the contribution of agriculture in total GHG emissions the gases CH 4 and N 2 O will be estimated from the agricultural and waste sectors. The results show that methane contributes 25% of total GHG emissions with agriculture being the primary contributor accounting for 36% of total emissions.

  11. CO2 storage in depleted gas reservoirs: A study on the effect of residual gas saturation

    Directory of Open Access Journals (Sweden)

    Arshad Raza

    2018-03-01

    Full Text Available Depleted gas reservoirs are recognized as the most promising candidate for carbon dioxide storage. Primary gas production followed by injection of carbon dioxide after depletion is the strategy adopted for secondary gas recovery and storage practices. This strategy, however, depends on the injection strategy, reservoir characteristics and operational parameters. There have been many studies to-date discussing critical factors influencing the storage performance in depleted gas reservoirs while little attention was given to the effect of residual gas. In this paper, an attempt was made to highlight the importance of residual gas on the capacity, injectivity, reservoir pressurization, and trapping mechanisms of storage sites through the use of numerical simulation. The results obtained indicated that the storage performance is proportionally linked to the amount of residual gas in the medium and reservoirs with low residual fluids are a better choice for storage purposes. Therefore, it would be wise to perform the secondary recovery before storage in order to have the least amount of residual gas in the medium. Although the results of this study are useful to screen depleted gas reservoirs for the storage purpose, more studies are required to confirm the finding presented in this paper.

  12. Underwater photosynthesis and respiration in leaves of submerged wetland plants: gas films improve CO2 and O2 exchange

    DEFF Research Database (Denmark)

    Colmer, Timothy David; Pedersen, Ole

    2007-01-01

    Many wetland plants have gas films on submerged leaf surfaces. We tested the hypotheses that leaf gas films enhance CO(2) uptake for net photosynthesis (P(N)) during light periods, and enhance O(2) uptake for respiration during dark periods. Leaves of four wetland species that form gas films......(N) was enhanced up to sixfold. Gas films on submerged leaves enable continued gas exchange via stomata and thus bypassing of cuticle resistance, enhancing exchange of O(2) and CO(2) with the surrounding water, and therefore underwater P(N) and respiration......., and two species that do not, were used. Gas films were also experimentally removed by brushing with 0.05% (v/v) Triton X. Net O(2) production in light, or O(2) consumption in darkness, was measured at various CO(2) and O(2) concentrations. When gas films were removed, O(2) uptake in darkness was already...

  13. Energy consumption, greenhouse gas emissions and assessment of sustainability index in corn agroecosystems of Iran

    International Nuclear Information System (INIS)

    Yousefi, Mohammad; Damghani, Abdolmajid Mahdavi; Khoramivafa, Mahmud

    2014-01-01

    The objectives of this study were to assess the energy flow, greenhouse gas (GHG) emission, global warming potential (GWP) and sustainability of corn production systems in Kermanshah province, western Iran. The data were collected from 70 corn agroecosystems which were selected based on randomly sampled method in the summer of 2011. The results indicated that total input and output energy were 50,485 and 134,946 MJ ha −1 , respectively. The highest share of total input energy in corn production systems was recorded for N fertilizer, electricity power and diesel fuel with 35, 25 and 20%, respectively. Energy use efficiency and energy productivity were 2.67 and 0.18 kg MJ −1 , respectively. Also agrochemical energy ratio was estimated as 40%. Applying chemical inputs produced the following emissions of greenhouse gases: 2994.66 kg CO 2, 31.58 kg N 2 O and 3.82 kg CH 4 per hectare . Hence, total GWP was 12,864.84 kg Co 2 eq ha −1 in corn production systems. In terms of CO 2 equivalents 23% of the GWPs came from CO 2 , 76% from N 2 O, and 1% from CH 4 . In this study input and output C equivalents per total GHG and Biomass production were 3508.59 and 10,696.34 kg C ha −1 . Net carbon and sustainability indexes in corn production systems were 7187.75 kg C ha −1 and 2.05. Accordingly, efficient use of energy is essential to reduce the greenhouse gas emissions and environmental impact in corn agroecosystems. - Highlights: • Increasing of energy consumption leaded to decreasing energy use efficiency in corn agroecosystems. • Total greenhouse gas (GHG) emission as CO 2 , N 2 O and CH 4 in corn production systems were 2994.66, 31.58 and 3.82 kg ha -1 , respectively. • Global warming potential (GWP) was 12864.84 kg CO 2 eq ha -1 in corn production systems. • Sustainability index in corn production systems was 2.05. • Reducing use of chemicals fertilizer and diesel fuel are necessary for better management of energy flow, global warming potential and

  14. Greenhouse gas mitigation using poultry litter management techniques in Bangladesh

    International Nuclear Information System (INIS)

    Mainali, Brijesh; Emran, Saad Been; Silveira, Semida

    2017-01-01

    Poultry activities have expanded significantly in Bangladesh in recent years. The litter generated from rural poultry farms is often dumped in low ground neighboring areas resulting in greenhouse gas emissions, as well as water and air pollution. This study estimates the GHG emissions of a typical rural layer poultry farm in Bangladesh, and identifies the GHG emissions reduction potential when poultry litter management techniques are used to produce biogas, generating electricity and bio-fertilizer. Life-cycle assessment (LCA) has been used for a systematic evaluation of GHG-emissions considering the local supply chain in a typical rural layer poultry farm. The analysis shows that the GHG-emissions at the poultry farm amount to 1735 KgCO 2eq /10000 eggs produced if the litter is untreated. With the installation of an anaerobic digester, the emission intensity could be reduced by 65% if the gas is used to replace LPG for cooking purposes. If 100% digested slurry is utilized as bio-fertilizer, the emissions intensity could be further reduced by 17 times compared to the case without slurry utilization. These results justify the consideration of national programs to improve conditions in poultry farms in Bangladesh. - Highlights: • This study estimates GHG-emissions reduction potential of utilizing poultry litter for energy production in a rural farm. • Energy/mass flow and GHG balances are evaluated considering the local supply chain. • On-farm activities significantly affect GHG emissions among others across the supply chain. • Biogas production and use of slurry as bio-fertilizer significantly reduces the emission intensity. • Results from LCA and sensitivity analysis have been discussed to identify key influential parameters.

  15. Greenhouse gas emissions from vegetation fires in Southern Africa

    International Nuclear Information System (INIS)

    Scholes, R.J.

    1995-01-01

    Methane (CH 4 ), carbon monoxide (CO), nitrogen oxides (NO x ), volatile organic carbon, and aerosols emitted as a result of the deliberate or accidental burning of natural vegetation constitute a large component of the greenhouse gas emissions of many African countries, but the data needed for calculating these emissions by the IPCC methodology is sparse and subject to estimation errors. An improved procedure for estimating emissions from fires in southern Africa has been developed. The proposed procedure involves reclassifying existing vegetation maps into one of eleven broad, functional vegetation classes. Fuel loads are calculated within each 0.5 x 0.5 o cell based on empirical relationships to climate data for each class. The fractional area of each class that bums is estimated by using daily low-resolution satellite fire detection, which is calibrated against a subsample of pre- and post-fire high-resolution satellite images. The emission factors that relate the quantity of gas released to the mass of fuel burned are based on recent field campaigns in Africa and are related to combustion efficiency, which is in turn related to the fuel mix. The emissions are summed over the 1989 fire season for Africa south of the equator. The estimated emissions from vegetation burning in the subcontinent are 0.5 Tg CH 4 , 14.9 Tg CO, 1.05 Tg NO x , and 1.08 Tg of particles smaller than 2.5μm. The 324 Tg CO 2 emitted is expected to be reabsorbed in subsequent years. These estimates are smaller than previous estimates. 5 tabs., 18 refs

  16. Modeling of municipal greenhouse gas emissions. Calculation of greenhouse gas emissions and the reduction possibilities of Dutch municipalities

    NARCIS (Netherlands)

    Vries de, Willem

    2011-01-01

    Summary Municipalities represent an active governmental layer in the Netherlands. They often have ambitions to reduce greenhouse gas emissions. In this way the municipalities take responsibility to reduce the threat of global warming. To implement effect

  17. Nuclear power for greenhouse gas mitigation

    International Nuclear Information System (INIS)

    Rogner, H.-H.

    2000-11-01

    The possibility of global climate change resulting from an increase in greenhouse gas (GHG) concentrations in the atmosphere is a major global concern. At the Third Conference of the Parties (CoP 3) to the United Nations Framework Convention on Climate Change (UNFCCC) held at Kyoto, in December 1997, industrialized countries agreed to accept binding commitments that would reduce their collective GHG emissions, in the 2008-2012 commitment period, by at least 5% below 1990 levels. These countries also agreed to make demonstrable progress towards reducing GHG emissions by 2005. Because climate change is a global problem, i.e. it does not matter where on the globe GHGs are emitted - they all end up in the same atmosphere, many market economists maintain that mitigation should first occur wherever it is cheapest. Thus Article 12 of the Kyoto Protocol makes provisions by which whose signatories who are required to limit emissions can gain credit for financing cost-effective mitigation projects in developing countries, while at the same time promoting sustainable development through the provision of financial and technical assistance. This option is known as the Clean Development Mechanism (CDM). The CDM could be of particular interest to developing countries, which are not subject to emission limitations in the Kyoto Protocol. For example, the use of capital-intensive nuclear power instead of less costly coal-fired electricity generation would result in a significant reduction in GHG emissions. Because many developing countries may not be able to afford the higher investments associated with a nuclear power project, or because nuclear may simply not be the least-cost generation option for a given country, CDM offers an opportunity for (incremental) capital and technology transfer sponsored by countries of the CoP 3 in exchange for GHG emission credits. The benefit to the sponsor would be compliance with the emission limits set out in the Protocol, at a lower cost than if

  18. Trace gas exchange above the floor of a deciduous forest: 1. Evaporation and CO2 efflux

    Science.gov (United States)

    Baldocchi, Denni