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Sample records for geological isotope anomalies

  1. Geological isotope anomalies as signatures of nearby supernovae

    CERN Document Server

    Ellis, Jonathan Richard; Schramm, David N; Ellis, John; Fields, Brian D; Schramm, David N

    1996-01-01

    Nearby supernova explosions may cause geological isotope anomalies via the direct deposition of debris or by cosmic-ray spallation in the earth's atmosphere. We estimate the mass of material deposited terrestrially by these two mechanisms, showing the dependence on the supernova distance. A number of radioactive isotopes are identified as possible diagnostic tools, such as Be-10, Al-26, Cl-36, Mn-53, Fe-60, and Ni-59, as well as the longer-lived I-129, Sm-146, and Pu-244. We discuss whether the 35 and 60 kyr-old Be-10 anomalies observed in the Vostok antarctic ice cores could be due to supernova explosions. Combining our estimates for matter deposition with results of recent nucleosynthesis yields, we calculate the expected signal from nearby supernovae using ice cores back to \\sim 300 kyr ago, and we discuss using deep ocean sediments back to several hundred Myr. In particular, we examine the prospects for identifying isotope anomalies due to the Geminga supernova explosion, and signatures of the possibility...

  2. Using EVT for Geological Anomaly Design and Its Application in Identifying Anomalies in Mining Areas

    Directory of Open Access Journals (Sweden)

    Feilong Qin

    2016-01-01

    Full Text Available A geological anomaly is the basis of mineral deposit prediction. Through the study of the knowledge and characteristics of geological anomalies, the category of extreme value theory (EVT to which a geological anomaly belongs can be determined. Associating the principle of the EVT and ensuring the methods of the shape parameter and scale parameter for the generalized Pareto distribution (GPD, the methods to select the threshold of the GPD can be studied. This paper designs a new algorithm called the EVT model of geological anomaly. These study data on Cu and Au originate from 26 exploration lines of the Jiguanzui Cu-Au mining area in Hubei, China. The proposed EVT model of the geological anomaly is applied to identify anomalies in the Jiguanzui Cu-Au mining area. The results show that the model can effectively identify the geological anomaly region of Cu and Au. The anomaly region of Cu and Au is consistent with the range of ore bodies of actual engineering exploration. Therefore, the EVT model of the geological anomaly can effectively identify anomalies, and it has a high indicating function with respect to ore prospecting.

  3. Calcium isotopic anomalies in the Allende meteorite

    International Nuclear Information System (INIS)

    Lee, T.; Papanastassiou, D.A.; Wasserburg, G.J.

    1978-01-01

    We report isotopic anomalies in Ca which were found in two Ca-Al-rich inclusions of the Allende meteorite. These inclusions previously had been shown to contain special anomalies for Mg and O which were attributed to fractionation and unknown nuclear effects. The Ca data, when corrected for mass fractionation by using 40 Ca/ 44 Ca as a standard, show nonlinear isotopic effects in 48 Ca of +13.5 per mil and in 42 Ca of +1.7 per mil for one sample. The second sample shows a 48 Ca depletion of -2.9 per mil, but all other isotopes are normal. Samples with large excesses in 26 Mg show no Ca anomalies. The effects demonstrate that isotopic anomalies exist for higher-atomic-number refractory elements in solar-system materials and do not appear to be readily explainable by a simple model. The correlation of O, Mg, and Ca results on the same inclusions requires the addition and preservation in the solar system of components from idverse nucleosynthetic sources. Observed anomalous Mg and Ca compositions for coexisting mineral phases are uniform within each inclusion, and require initial isotopic homogeneity within an inclusion but the preservation of wide variations between inclusions. Assuming formation of these inclusions by condensation from a gaseous part of the solar nebula, this implies isotopic heterogeneity on a scale of 10-10 2 km within the nebula

  4. Isotope anomalies in oxygen isotope exchange equilibrium systems

    International Nuclear Information System (INIS)

    Kotaka, M.

    1997-01-01

    The purpose of the present work is to elucidate the isotope anomalies in oxygen isotope exchange equilibrium systems, according to the calculations of the equilibrium constants for oxygen isotopic exchange reactions, and the calculations of the oxygen isotope separation factors between two phases. The equilibrium constants (K65, K67, K68 and K69) of 16 O- 15 O, 16 O 17 O, 16 O- 18 O, and 16 O- 19 O exchange reactions between diatomic oxides were calculated in a wide temperature range on the basis of quantum statistical mechanics. Many equilibrium constants showed the anomalous mass effects, and then had the crossover temperatures and the mass independent fractionation (MIF) temperatures which held K67 = K65, K67 = K68, or K67 = K69, etc. For example, the equilibrium constants for the reactions between OH and the other diatomic oxides (MO) showed the anomalous mass effects, when M was Li, Na, Mg, K, Fe, Al, Ge, Zr, Pt, etc. The 16 O 15 O, 16 O 17 O, 16 O- 18 O, and 16 O- 19 O oxygen isotope separation factors (S65, S67, S68 and S69) between two phases were calculated, when OH and CO were in the first phase, and SiO was in the second phase. Although the oxygen isotopic exchange equilibria in the two phases had no MIF and crossover temperatures, the separation factors showed the anomalous mass effects and had the temperatures. According to what is called the normal mass effects for the equilibrium constant of isotopic exchange reaction, the value of InK68/InK67 is 1.885. Therefore, the value of InS68/InS67 should be 1.885 too. The value calculated, however, widely changed. It can be concluded from the results obtained in the present work that some oxygen isotopic exchange equilibria cause the anomalous mass effects, the anomalous oxygen isotope separation factors, and then isotope anomalies

  5. Utilizing Stable Isotopes and Isotopic Anomalies to Study Early Solar System Formation Processes

    Science.gov (United States)

    Simon, Justin

    2017-01-01

    Chondritic meteorites contain a diversity of particle components, i.e., chondrules and calcium-, aluminum-rich refractory inclusions (CAIs), that have survived since the formation of the Solar System. The chemical and isotopic compositions of these materials provide a record of the conditions present in the protoplanetary disk where they formed and can aid our understanding of the processes and reservoirs in which solids formed in the solar nebula, an important step leading to the accretion of planetesimals. Isotopic anomalies associated with nucleosynthetic processes are observed in these discrete materials, and can be compared to astronomical observations and astrophysical formation models of stars and more recently proplyds. The existence and size of these isotopic anomalies are typically thought to reflect a significant state of isotopic heterogeneity in the earliest Solar System, likely left over from molecular cloud heterogeneities on the grain scale, but some could also be due to late stellar injection. The homogenization of these isotopic anomalies towards planetary values can be used to track the efficiency and timescales of disk wide mixing,

  6. Geochemical and isotope-geochemical investigations on thermal waters from the Urach-Kirchheim thermal anomaly

    International Nuclear Information System (INIS)

    Koller, B.

    1980-01-01

    To confirm possible circulation systems, the 18 O/ 16 O D/H isotope conditions of the surface waters and the thermal waters in the investigation area were determined. The circulation systems are due to crosswise anomalies, the geologic situation and a trough-shaped lowering of the permianbeds. A decisive influence of meteoric water could not be detected. A depletion in 18 O with increasing depth was established. Obviously, there has been interaction with water. The applicability of chemical thermometers was tested. (DG) [de

  7. Titanium isotopic anomalies in meteorites

    International Nuclear Information System (INIS)

    Niemeyer, S.; Lugmair, G.W.

    1984-01-01

    High-precision analyses of Ti are reported for samples from a variety of meteorite classes. The expanded data base for Allende inclusions still shows Ti isotope anomalies in every inclusion. All the coarse-grained inclusions give quite similar patterns, but fine-grained inclusions show more variable, and sometimes larger, anomalies. One inclusion, 3675A, was analyzed because others identified it as a possible 'FUN' inclusion due to its mass-fractionated Mg. This designation is supported by the significantly more complex Ti isotopic pattern for 3675A compared to all our other Allende inclusions. Available data fail to suggest that any particular Allende mineral phase, including a chromite-carbon fraction from an acid residue, is especially rich in anomalous Ti. We also find anomalous Ti in a bulk sample of a C1 chondrite and in matrix separates from C2 chondrites. The excesses of 50 Ti are smaller than for Allende inclusions, and subtle differences in Ti isotopic patterns tentatively suggest that parent materials for C1-C2 matrix and Allende inclusions are not directly related. Analyses of chondrules from unequilibrated ordinary chondrites did not yield clear evidence for anomalous Ti, but some 'larger than usual' deficits at 50/46 give encouragement for future work in this direction. (author)

  8. Isotopic anomalies - chemical memory of Galactic evolution

    International Nuclear Information System (INIS)

    Clayton, D.D.

    1988-01-01

    New mechanisms for the chemical memory of isotopic anomalies are proposed which are based on the temporal change during the chemical evolution of the Galaxy of the isotopic composition of the mean ejecta from stars. Because of the differing temporal evolution of primary and secondary products of nucleosynthesis, the isotopic composition of the bulk interstellar medium changes approximately linearly with time, and thus any dust component having an age different from that of average dust will be isotopically anomalous. Special attention is given to C, O, Mg, Si, and isotopically heavy average-stellar condensates of SiC. 20 references

  9. Characteristics of uranium geological anomaly in Northern Guangdong province

    International Nuclear Information System (INIS)

    Wang Xinwu; Cheng Danping

    2001-01-01

    The geological anomaly characteristics of uranium deposit region in northern Guangdong are discussed on the aspects of uranium source, structure and thermal activity. Uranium deposits usually occur in the uranium-rich background field. Structure activity provides favourable places for the transportation and precipitation of uranium. Uranium deposits are formed in the central and edge of frequent thermal activity. The assembled entropy anomaly field is the synthetical display for above three anomaly. The biggest assembled entropy anomaly is the most favourable space field for forming uranium deposit

  10. Isotopic diversity in nebular dust: The distribution of Ti isotopic anomalies in carbonaceous chondrites

    International Nuclear Information System (INIS)

    Niemeyer, S.

    1988-01-01

    Average Ti isotopic patterns are derived for each class of carbonaceous chondrite from a chemically characterized suite of whole-rock samples. There is a well-resolved excess of 50 Ti in a subset of CI meteorites. Mean values of the 50 Ti excess for the four classes span a range of only 2 ε-units, with an apparent positive correlation with Al content. Previous evidence for anomalies in chondrules is augmented here by demonstrating that: (1) the more pristine Ca-Al-rich inclusions (CAIs) in Efremovka show the same isotopic pattern as the typical Allende CAI; and, (2) CM and CV matrix carry 50 Ti excesses of about 2 ε-units. The distribution of Ti isotopic anomalies among matrix, chondrules, and CAIs suggests a model in which all three constituents formed from precursor-assemblages in which some chemical memories were still intact; the isotopic differences reflect fractionations among the carrier phases of the different isotopic components. Chondrules formed by a mostly closed-system melting of their precursors, and thus provide a recording of the extent of nebular heterogeneity on the mg-size scale. The larger anomalies in CAIs, compared to matrix and most (but not all) chondrules, are attributed primarily to an open- rather than closed-system processing of the CAI precursors. Precursors of both FUN and normal CAIs experienced an episode of intense processing, perhaps partial melting, that created the FUN characteristics, but for normal CAIs the FUN effects were erased by subsequent isotopic equilibration and exchange

  11. Long-term sedimentary recycling of rare sulphur isotope anomalies.

    Science.gov (United States)

    Reinhard, Christopher T; Planavsky, Noah J; Lyons, Timothy W

    2013-05-02

    The accumulation of substantial quantities of O2 in the atmosphere has come to control the chemistry and ecological structure of Earth's surface. Non-mass-dependent (NMD) sulphur isotope anomalies in the rock record are the central tool used to reconstruct the redox history of the early atmosphere. The generation and initial delivery of these anomalies to marine sediments requires low partial pressures of atmospheric O2 (p(O2); refs 2, 3), and the disappearance of NMD anomalies from the rock record 2.32 billion years ago is thought to have signalled a departure from persistently low atmospheric oxygen levels (less than about 10(-5) times the present atmospheric level) during approximately the first two billion years of Earth's history. Here we present a model study designed to describe the long-term surface recycling of crustal NMD anomalies, and show that the record of this geochemical signal is likely to display a 'crustal memory effect' following increases in atmospheric p(O2) above this threshold. Once NMD anomalies have been buried in the upper crust they are extremely resistant to removal, and can be erased only through successive cycles of weathering, dilution and burial on an oxygenated Earth surface. This recycling results in the residual incorporation of NMD anomalies into the sedimentary record long after synchronous atmospheric generation of the isotopic signal has ceased, with dynamic and measurable signals probably surviving for as long as 10-100 million years subsequent to an increase in atmospheric p(O2) to more than 10(-5) times the present atmospheric level. Our results can reconcile geochemical evidence for oxygen production and transient accumulation with the maintenance of NMD anomalies on the early Earth, and suggest that future work should investigate the notion that temporally continuous generation of new NMD sulphur isotope anomalies in the atmosphere was likely to have ceased long before their ultimate disappearance from the rock record.

  12. Lectures in isotope geology

    International Nuclear Information System (INIS)

    Jaeger, E.; Hunziker, J.C.

    1979-01-01

    Designed for a introductory course in geochronology and the geochemistry of stable isotopes, this text has been written by recognized experts in the field. Emphasis is on the interpretation and on applications, and examples of these are offered along with each technique. Extraterrestrial applications have been avoided and the treatment of pure experimentation has been kept at a minimum. This text will be appreciated by geologists who want to learn more about methods used in isotope geology, how they can be applied, and how to gauge their usefulness. (orig.) [de

  13. Isotopic anomalies in organic nanoglobules from Comet 81P/Wild 2: Comparison to Murchison nanoglobules and isotopic anomalies induced in terrestrial organics by electron irradiation

    Science.gov (United States)

    De Gregorio, Bradley T.; Stroud, Rhonda M.; Nittler, Larry R.; Alexander, Conel M. O.'D.; Kilcoyne, A. L. David; Zega, Thomas J.

    2010-08-01

    Nanoglobules are a form of organic matter found in interplanetary dust particles and primitive meteorites and are commonly associated with 15N and D isotopic anomalies that are suggestive of interstellar processes. We report the discovery of two isotopically-anomalous organic globules from the Stardust collection of particles from Comet 81P/Wild 2 and compare them with nanoglobules from the Murchison CM2 meteorite. One globule from Stardust Cometary Track 80 contains highly aromatic organic matter and a large 15N anomaly (δ 15N = 1120‰). Associated, non-globular, organic matter from this track is less enriched in 15N and contains a mixture of aromatic and oxidized carbon similar to bulk insoluble organic material (IOM) from primitive meteorites. The second globule, from Cometary Track 2, contains non-aromatic organic matter with abundant nitrile ( sbnd C tbnd N) and carboxyl ( sbnd COOH) functional groups. It is significantly enriched in D (δD = 1000‰) but has a terrestrial 15N/ 14N ratio. Experiments indicate that similar D enrichments, unaccompanied by 15N fractionation, can be reproduced in the laboratory by electron irradiation of epoxy or cyanoacrylate. Thus, a terrestrial origin for this globule cannot be ruled out, and, conversely, exposure to high-energy electron irradiation in space may be an important factor in producing D anomalies in organic materials. For comparison, we report two Murchison globules: one with a large 15N enrichment and highly aromatic chemistry analogous to the Track 80 globule and the other only moderately enriched in 15N with IOM-like chemistry. The observation of organic globules in Comet 81P/Wild 2 indicates that comets likely sampled the same reservoirs of organic matter as did the chondrite parent bodies. The observed isotopic anomalies in the globules are most likely preserved signatures of low temperature (<10 K) chemistry in the interstellar medium or perhaps the outer regions of the solar nebula. In other

  14. Annual report 1982 of ZWO Laboratory of Isotope Geology

    International Nuclear Information System (INIS)

    1983-07-01

    This report gives a brief account of the activities of the ZWO Laboratory of Isotope Geology during 1982. The main point of interest is the research for new possible applications of gas-mass spectrometry in geology. Kr and Xe turn out to be produced at the spontaneous fission of 238 U present in zirconium crystals. Mass-spectrometric isotope analysis has been carried out, resulting in a tentative age estimation. (Auth.)

  15. Some isotopic and geochemical anomalies observed in Mexico prior to large scale earthquakes and volcanic eruptions

    International Nuclear Information System (INIS)

    Cruz R, S. de la; Armienta, M.A.; Segovia A, N.

    1992-05-01

    A brief account of some experiences obtained in Mexico, related with the identification of geochemical precursors of volcanic eruptions and isotopic precursors of earthquakes and volcanic activity is given. The cases of three recent events of volcanic activity and one large earthquake are discussed in the context of an active geological environment. The positive results in the identification of some geochemical precursors that helped to evaluate the eruptive potential during two volcanic crises (Tacana 1986 and Colima 1991), and the significant radon-in-soil anomalies observed during a volcanic catastrophic eruption (El Chichon, 1982) and prior to a major earthquake (Michoacan, 1985) are critically analysed. (Author)

  16. Some isotopic and geochemical anomalies observed in Mexico prior to large scale earthquakes and volcanic eruptions

    Energy Technology Data Exchange (ETDEWEB)

    Cruz R, S. de la; Armienta, M A; Segovia A, N

    1992-05-15

    A brief account of some experiences obtained in Mexico, related with the identification of geochemical precursors of volcanic eruptions and isotopic precursors of earthquakes and volcanic activity is given. The cases of three recent events of volcanic activity and one large earthquake are discussed in the context of an active geological environment. The positive results in the identification of some geochemical precursors that helped to evaluate the eruptive potential during two volcanic crises (Tacana 1986 and Colima 1991), and the significant radon-in-soil anomalies observed during a volcanic catastrophic eruption (El Chichon, 1982) and prior to a major earthquake (Michoacan, 1985) are critically analysed. (Author)

  17. Isotopic Anomalies in Organic Nanoglobules from Comet 81P/Wild 2: Comparison to Murchison Nanoglobules and Isotopic Anomalies Induced in Terrestrial Organics by Electron Irradiation

    Energy Technology Data Exchange (ETDEWEB)

    De Gregorio, B.; Stroud, R; Nittler, L; Alexander, C; Kilcoyne, A; Zega, T

    2010-01-01

    Nanoglobules are a form of organic matter found in interplanetary dust particles and primitive meteorites and are commonly associated with {sup 15}N and D isotopic anomalies that are suggestive of interstellar processes. We report the discovery of two isotopically-anomalous organic globules from the Stardust collection of particles from Comet 81P/Wild 2 and compare them with nanoglobules from the Murchison CM2 meteorite. One globule from Stardust Cometary Track 80 contains highly aromatic organic matter and a large {sup 15}N anomaly ({delta}{sup 15}N = 1120{per_thousand}). Associated, non-globular, organic matter from this track is less enriched in {sup 15}N and contains a mixture of aromatic and oxidized carbon similar to bulk insoluble organic material (IOM) from primitive meteorites. The second globule, from Cometary Track 2, contains non-aromatic organic matter with abundant nitrile ({single_bond}C{triple_bond}N) and carboxyl ({single_bond}COOH) functional groups. It is significantly enriched in D ({delta}D = 1000{per_thousand}) but has a terrestrial {sup 15}N/{sup 14}N ratio. Experiments indicate that similar D enrichments, unaccompanied by {sup 15}N fractionation, can be reproduced in the laboratory by electron irradiation of epoxy or cyanoacrylate. Thus, a terrestrial origin for this globule cannot be ruled out, and, conversely, exposure to high-energy electron irradiation in space may be an important factor in producing D anomalies in organic materials. For comparison, we report two Murchison globules: one with a large {sup 15}N enrichment and highly aromatic chemistry analogous to the Track 80 globule and the other only moderately enriched in {sup 15}N with IOM-like chemistry. The observation of organic globules in Comet 81P/Wild 2 indicates that comets likely sampled the same reservoirs of organic matter as did the chondrite parent bodies. The observed isotopic anomalies in the globules are most likely preserved signatures of low temperature (<10 K

  18. 3. South American symposium on isotope geology. Extended abstracts

    International Nuclear Information System (INIS)

    2001-10-01

    This publication include papers in the fields on Methodology, thermochronology, and geochronology; Evolution of cratonic South America; Magmatic processes; Environmental geology, hydrogeology, isotopic stratigraphy and paleoclimatology; Economic Geology and Evolution of the Andean margin of South America

  19. Carbon Isotopic tests on the Origins of the Shuram Anomaly from the San Juan Fm., Peru

    Science.gov (United States)

    Hodgin, E. B.

    2015-12-01

    Carbon isotope anomalies are associated with perturbations to the carbon cycle that offer insight into the geochemical evolution of the Earth. The largest Carbon isotope anomaly in earth history is the Shuram, which remains poorly understood in spite of being linked to the oxygenation of earth, the rise of metazoans, and a complete reorganization of the carbon cycle. From a basin transect of the carbonate-dominated San Juan Formation in southern Peru, we present evidence for the first clear example of the Shuram isotope anomaly in South America. Unique to this succession are ~140 meters of organic-rich black shale within the anomaly, containing as much as 4% TOC. Preliminary data from the organic-rich black shales of the San Juan Fm. confirm that δ13Corg is relatively invariant and does not covary with δ13Ccarb. These observations are consistent with other Shuram sections and support various models: an exogenous carbon source, an enlarged dissolved organic carbon pool, as well as authigenic carbonate production in organic-rich anoxic sediments. Critical tests of these models have been complicated by a paucity of organics in Shuram facies worldwide. Further analyses of the robust organics from the Shuram facies of the San Juan Fm. therefore hold promise in shedding light on the origin of the Shuram isotope anomaly and critical earth history events to which it has been linked.

  20. Oxygen isotopic anomalies in Allende inclusion HAL

    International Nuclear Information System (INIS)

    Lee, T.; Mayeda, T.K.; Clayton, R.N.

    1980-01-01

    The oxygen isotopic composition has been measured on the constituent phases of Allende inclusion HAL, which has unusual mineralogical, chemical, and calcium isotopic compositions. The oxygen in HAL is heterogeneous, with the rim showing more ''normal'' composition and the hibonite core showing large deviation from both the terrestrial material and the usual inclusions. The observed pattern indicates that HAL is a bona fide and more devious member of the rare ''FUN'' family, whose isotopic composition is characterized by correlated nuclear effects and extreme mass fractionation. The data imply that HAL has suffered a large oxygen mass fractionation of 25% 0 per mass unit, followed by exchange with oxygen in a second reservoir. The present experiment supports the identification of two distinct reservoirs from which all refractory inclusions in carbonaceous meteorites derived their oxygen. The required fractionation process seems to operate according to the volatility of various elements and could have been caused by evaporation during a heating event. Nuclear anomalies can be produced in the same heating event if the progenitors of the refractory inclusions were macroscopic aggregates of tiny pre-solar interstellar dust grains and if these grains were destroyed differentially during the evaporation

  1. Research on isotope geology. Assessment of heat production potential of granitic rocks and development of geothermal exploration techniques using radioactive/stable isotopes and fission track 2

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Seong Cheon; Chi, Se Jung [Korea Inst. of Geology Mining and Materials, Taejon (Korea, Republic of)

    1995-12-01

    Radioelements and heat production rates of granitic rocks and stable isotopes of groundwaters were analyzed to investigate the geothermal potential of Wolchulsan granite complex in the southern Yeongam area. Wolchulsan granite complex is composed mainly by Cretaceous pink alkali-feldspar granite and partly Jurassic biotite granite. The main target for the geothermal exploration is the alkali-feldspar granite that is known in general to be favorable geothermal reservoir(e.g., Shap granite in UK). To develop exploration techniques for geothermal anomalies, all geochemical data were compared to those from the Jeonju granite complex. Heat production rates(HPR) of the alkali-feldspar granite is 1.8 - 10.6 {mu}Wm{sup -3}. High radio-thermal anomalies were revealed from the central western and northern parts of the granite body. These are relatively higher than the Caledonian hot dry granites in the UK. The integrated assessment of Wolchulsan granite complex suggests potential of the Cretaceous alkali-feldspar granite as a geothermal targets. Groundwater geochemistry of the Yeongam area reflects simple evaporation process and higher oxidation environment. Stable isotope data of groundwaters are plotted on or close to the Meteoric Water Line(MWL). These isotopic data indicate a significant meteoric water dominance and do not show oxygen isotope fractionation between groundwater and wall rocks. In despite of high HPR values of the Yeongam alkali-feldspar granite, groundwater samples do not show the same geochemical properties as a thermal water in the Jeonju area. This reason can be well explained by the comparison with geological settings of the Jeonju area. The Yeongam alkali-feldspar granite does not possess any adjacent heat source rocks despite its high radio-thermal HPR. While the Jeonju granite batholith has later heat source intrusive and suitable deep fracture system for water circulation with sedimentary cap rocks. (Abstract Truncated)

  2. MULTIPLE ORIGINS OF NITROGEN ISOTOPIC ANOMALIES IN METEORITES AND COMETS

    International Nuclear Information System (INIS)

    Aleon, Jerome

    2010-01-01

    Isotopic fractionation and mixing calculations compared with coupled hydrogen and nitrogen isotopic composition of organic molecules from primitive chondrites, interplanetary dust particles (IDPs), and comets C/1995 O1 (Hale-Bopp) and 81P/Wild2 reveal that meteoritic and cometary organic matter contains three different isotopic components of different origins. (1) A major component of carbonaceous chondrites, IDPs, and comets Hale-Bopp and Wild2 shows correlated H and N isotopic compositions attributable to isotope exchange between an organic matter of solar composition and a reservoir formed by ion-molecule reactions at T 15 N-rich component having identical 15 N and D enrichments relative to the protosolar gas. Temperatures > 100 K deduced from the low D/H ratio and an anti-correlation between the abundance of this component and meteoritic age indicate a late origin in the solar protoplanetary disk. N 2 self-shielding and the non-thermal nucleosynthesis of 15 N upon irradiation are possible but unlikely sources of this component, and a chemical origin is preferred. (3) An interstellar component with highly fractionated hydrogen isotopes and unfractionated nitrogen isotopes is present in ordinary chondrites. A dominantly solar origin of D and 15 N excesses in primitive solar system bodies shows that isotopic anomalies do not necessarily fingerprint an interstellar origin and implies that only a very small fraction of volatile interstellar matter survived the events of solar system formation.

  3. Study of hyperfine anomaly in 9,11Be isotopes

    International Nuclear Information System (INIS)

    Parfenova, Y.; Leclercq-Willain

    2005-01-01

    The study of the hyperfine anomaly of neutron rich nuclei, in particular, neutron halo nuclei, can give a very specific and unique way to measure their neutron distribution and confirm a halo structure. The hyperfine structure anomaly in Be + ions is calculated with a realistic electronic wave function, obtained as a solution of the Dirac equation. In the calculations, the Coulomb potential modified by the charge distribution of the clustered nucleus and three electrons in the configuration 1s 2 2s is used. The nuclear wave function for the 11 Be nucleus is obtained in the core + nucleon model, and that for the 9 Be nucleus is calculated in the three-cluster (α+α + n) model. The aim of this study is to test whether the hyperfine structure anomaly reflects an extended spatial structure of '1 1 Be. The results of the calculations are listed. ε BW is the hyperfine anomaly in the Bohr-Weisskopf effect and δ is the charge structure correction, μ is the calculated magnetic moment, and μ exp is the experimental value of the magnetic moment, Q and Q exp are the calculated and measured values of the quadrupole moment. The results for 9 Be are obtained with two different three-body wave functions (WF1 and WF2) showing the sensitivity of the calculations to the input parameters. The value of ε BW is sensitive to the weights of the states in the nuclear ground state wave function. The total hyperfine anomaly value εε BW +δ in 11 Be differs from that in 9 Be by 25%. This gives a measure of the accuracy of the hyperfine anomaly measurements needed to study the neutron distribution in the Be isotopes. (authors)

  4. Charge state distribution studies of pure and oxygen mixed krypton ECR plasma - signature of isotope anomaly and gas mixing effect.

    Science.gov (United States)

    Kumar, Pravin; Mal, Kedar; Rodrigues, G

    2016-11-01

    We report the charge state distributions of the pure, 25% and 50% oxygen mixed krypton plasma to shed more light on the understanding of the gas mixing and the isotope anomaly [A. G. Drentje, Rev. Sci. Instrum. 63 (1992) 2875 and Y Kawai, D Meyer, A Nadzeyka, U Wolters and K Wiesemann, Plasma Sources Sci. Technol. 10 (2001) 451] in the electron cyclotron resonance (ECR) plasmas. The krypton plasma was produced using a 10 GHz all-permanent-magnet ECR ion source. The intensities of the highly abundant four isotopes, viz. 82 Kr (~11.58%), 83 Kr (~11.49%), 84 Kr (~57%) and 86 Kr (17.3%) up to ~ +14 charge state have been measured by extracting the ions from the plasma and analysing them in the mass and the energy using a large acceptance analyzer-cum-switching dipole magnet. The influence of the oxygen gas mixing on the isotopic krypton ion intensities is clearly evidenced beyond +9 charge state. With and without oxygen mixing, the charge state distribution of the krypton ECR plasma shows the isotope anomaly with unusual trends. The anomaly in the intensities of the isotopes having quite closer natural abundance, viz. 82 Kr, 86 Kr and 83 Kr, 86 Kr is prominent, whereas the intensity ratio of 86 Kr to 84 Kr shows a weak signature of it. The isotope anomaly tends to disappear with increasing oxygen mixing in the plasma. The observed trends in the intensities of the krypton isotopes do not follow the prediction of linear Landau wave damping in the plasma. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  5. Study of the Threshold Anomaly in the Scattering of Li Isotopes on 27Al

    International Nuclear Information System (INIS)

    Fernandez Niello, J.O.; Figueira, J.M.; Abriola, D.; Arazi, A.; Capurro, O.A.; Marti, G.V.; Martinez Heinmann, D.; Pacheco, A.J.; Barbara, E. de; Padron, I.; Gomes, P.R.S.; Lubian, J.

    2007-01-01

    Angular distributions of 6,7 Li scattered by 27 Al have been measured at different bombarding energies between 6 and 18 MeV. The results obtained from an optical model analysis using several potentials indicate that there is an isotopic dependence in the energy variation of the real and imaginary strengths. Whereas the 7 Li + 27 Al system shows no indication of any threshold anomaly, the 6 Li + 27 Al reaction suggests the presence of the so-called breakup threshold anomaly

  6. Earth's Coming of Age: Isotopically Tracking the Global Transformation from the Hadean to the Geologically Modern Earth

    Science.gov (United States)

    Bennett, V. C.; Nutman, A. P.

    2017-12-01

    Some of the strongest direct evidence that documents fundamental changes in the chemistry and organisation of Earth's interior derives from radiogenic isotopic compositions that include both long-lived (particularly 176Lu-176Hf and 147Sm-143Nd) and short-lived, i.e., now extinct parent isotope, systems (182Hf-182W, 146Sm-142Nd). Changes in patterns of isotopic evolution are linked to changes in mantle dynamics such that tracking these signatures in geologically well-characterised rocks can be used to discover the the nature and evolution of tectonic processes. Over the past decade, intensive geochemical investigations by various groups focussing on the oldest (> 4.0 Ga to 3.6 Ga) rock record, as preserved in several localities, have revealed isotopic distinctions in the early Earth compared with those in Proterozoic and younger rocks. For example, whilst the major and trace element compositions of Eoarchean gneisses have analogs in younger rocks in accord with a continuum of crust formation processes, radiogenic isotopic signatures from both long and short half-life decay schemes record an image of the Earth in transition from early differentiation processes, likely associated with planetary accretion and formation, to more modern style characterised by plate tectonics. The emerging image is that many Eoarchean rocks possess extinct nuclide anomalies in the form of 142Nd and 182Hf isotopic signatures that are absent in modern terrestrial samples; these signatures are evidence of chemical fractionation processes occuring within the first ca. 10-300 million years of Solar System history. In addition, viewing the global database, patterns of long-half life isotope signatures i.e., 143Nd and 176Hf differ from those seen in younger (modern Earth.

  7. Geological, Geochemical 1 and Rb-Sr isotopic studies on tungsten 2 ...

    Indian Academy of Sciences (India)

    37

    Geological, Geochemical and Rb-Sr isotopic studies on tungsten. 1 mineralised ..... From the field relations it is demonstrated that SG (biotite-bearing granitic gneiss) and. 120 ..... cases Ba) and vice-versa for the low concentration. 291.

  8. Application of ASTER SWIR bands in mapping anomaly pixels for Antarctic geological mapping

    International Nuclear Information System (INIS)

    Beiranvand Pour, Amin; Hashim, Mazlan; Park, Yongcheol

    2017-01-01

    Independent component analysis (ICA) was applied to shortwave infrared (SWIR) bands of ASTER satellite data for detailed mapping of alteration mineral zones in the context of polar environments, where little prior information is available. The Oscar II coast area north-eastern Graham Land, Antarctic Peninsula (AP) was selected to conduct a remote sensing satellite-based mapping approach to detect alteration mineral assemblages. Anomaly pixels in the ICA image maps related to spectral features of Al-O-H, Fe, Mg-O-H and CO3 groups were detected using SWIR datasets of ASTER. ICA method provided image maps of alteration mineral assemblages and discriminate lithological units with little available geological data for poorly mapped regions and/or without prior geological information for unmapped regions in northern and southern sectors of Oscar II coast area, Graham Land. The results of this investigation demonstrated the applicability of ASTER spectral data for lithological and alteration mineral mapping in poorly exposed lithologies and inaccessible regions, particularly using the image processing algorithm that are capable to detect anomaly pixels targets in the remotely sensed images, where no prior information is available. (paper)

  9. p-process xenon isotope anomalies in stardust grains from meteorites

    International Nuclear Information System (INIS)

    Ott, U.

    2013-01-01

    Full text: In measurements on 'bulk' samples of meteorites isotopic variations due to the p-process usually have taken a backseat compared to such in s- or r-isotopes, and, in the best case, can be qualitatively attributed to the p-process, with little to no inferences concerning detailed isotopic yields. The situation is different for grains of stardust that survived in primitive meteorites. In fact, isotopically strange xenon was the key feature that led to the first identification of a stardust mineral, nanodiamonds containing xenon with overabundances of up to a factor of ∼2 in both the r-only (≡H-Xe) and p-only (≡L-Xe) isotopes. Relative excesses of the two r-only isotopes ( 134 Xe, 136 Xe) as well as of the two p-only isotopes ( 124 Xe, 126 Xe) are not equal, hence the processes responsible for HL-xenon must differ from the 'average' r- and p-processes as reflected in solar system abundances. However, while considerable effort has been put into explaining H-Xe, there has been little work on the p-side (L-Xe). Relying on scarce nuclear data, Heymann and Dziczkaniec have studied photodisintegration reactions of Xe and Ba seeds in intermediate zones of supernovae and found that the relative production of the p-Xe isotopes depends sensitively on the yield of the (γ, α) reaction on 128 Ba. Another suggestion - applicable to both the r- and p-anomalies in diamond xenon - is that of a 'rapid separation' between stable Xe isotopes and radioactive precursors produced in the 'standard' p- (as well as r-) process. For the p-isotopes to work, this would require the bulk (87%) of 126 Xe to be produced via the 126 Ba precursor, with a half live of ∼100 minutes, in order to explain the high 124 Xe/ 126 Xe. In contrast to diamond xenon, xenon in silicon carbide contains - besides the component from the s-process in their parent AGB stars - 'almost normal' Xe, with indications for 124 Xe/ 126 Xe being few (∼8)% lower than in solar Xe.

  10. Pb, Sr and Nd isotope geological characteristics and its evolution of Jianchaling rock

    International Nuclear Information System (INIS)

    Pang Chunyong; Chen Minyang; Xu Wenxin

    2003-01-01

    It has been a long time debatable subject on the raw material source and its genesis of Jianchaling ultrabasic rock, because the original rock phases, the original mineral compositions, texture and structure, even part of the chemical components of the rocks had been changed completely after many periods and phases of metamorphism. According to the content of Pb, Rb, Sr, Nd elements and their Pb, Sr, Nd isotope compositions of the rocks, together with the isotope geological age of late magmatic activities, the authors analyze the evolution of Pb, Sr, Nd isotope compositions, The inferred initiate Nd isotope ratio of ultrabasic rocks is 0.510233, lower than that of meteorite unity at a corresponding period, its ε Nd(T)>O; The initiate Sr ratios inferred by the isotope geological age ranges from 0.702735 to 0.719028; Projecting the lead isotope compositions on the Pb tectonic evolution model, the result indicates that the raw material of Jianchaling ultrabasic rock coming from the deplete upper mantle. The ultrabasic magma which enrich of Mg, Ni and less S intruded the crust and formed the Jianchaling ultrabasic rock at late Proterozoic era (927 Ma±). The forming time of serpentinite is mostly equal to the granitoid intruding time, showing the intrusion o flate acidic magma caused a large scale alteration of the ultrabasic rocks and formed the meta-ultrabasic phase rock observed today. (authors)

  11. Cerium anomaly across the mid-Tournaisian carbon isotope excursion (TICE)

    Science.gov (United States)

    Jiang, G.; Morales, D. C.; Maharjan, D. K.

    2015-12-01

    The Early Mississippian (ca. 359-345 Ma) represents one of the most important greenhouse-icehouse climate transitions in Earth history. Closely associated with this critical transition is a prominent positive carbon isotope excursion (δ13C ≥ +5‰) that has been documented from numerous stratigraphic successions across the globe. This δ13C excursion, informally referred to as the TICE (mid-Tournaisian carbon isotope excursion) event, has been interpreted as resulting from enhanced organic carbon burial, with anticipated outcomes including the lowering of atmospheric CO2 and global cooling, the growth of continental ice sheets and sea-level fall, and the increase of ocean oxygenation and ocean redox changes. The casual relationship between these events has been addressed from various perspectives but not yet clearly demonstrated. To document the potential redox change associated with the perturbation of the carbon cycle, we have analyzed rare earth elements (REE) and trace elements across the TICE in two sections across a shallow-to-deep water transect in the southern Great Basin (Utah and Nevada), USA. In both sections, the REE data show a significant positive cerium (Ce) anomaly (Ce/Ce* = Ce/(0.5La+0.5Pr)). Prior to the positive δ13C shift, most Ce/Ce* values are around 0.3 (between 0.2 and 0.4). Across the δ13C peak, Ce/Ce* values increase up to 0.87, followed by a decrease back to 0.2~0.3 after the δ13C excursion (Figure 1). The positive Ce anomaly is best interpreted as recording expansion of oxygen minimum zone and anoxia resulted from increased primary production. This is consistent with a significant increase of nitrogen isotopes (δ15N) across the δ13C peak. Integration of the carbon, nitrogen, and REE data demonstrates a responsive earth systems change linked to the perturbation of the Early Mississippian carbon cycle.

  12. A novel procedure for Rubidium separation and its isotope measurements on geological samples by MC-ICP-MS

    Science.gov (United States)

    Ma, J.; Zhang, Z.; Wei, G.; Zhang, L.

    2017-12-01

    A method including a novel column Rb separation procedure and high-precision Rb isotope measurement in geological materials by using multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) in standard-sample-bracketing (SSB) mode has been developed. Sr-Spec resin was employed, in which the distribution coefficients for Rb, K, Ba and Sr are different in nitric acid, to sequentially separate them from the matrix. The dissolved samples were loaded on the column in 3 M HNO3, the main matrix such as Al, Ca, Fe, Mg, Mn and Na were removed by rinsing with 4.5 mL HNO3, Rb and K were then sequentially eluted by 3 M HNO3 in different volumes. After that, Ba was eluted by 8 M HNO3, and Sr was finally eluted by Milli-Q water. This enable us to collect the pure Rb, K, Ba and Sr one by one with recovery close to 100% for their isotopic compositions measurement on MC-ICP-MS. We here focus on Rb isotope measurement. The measurement using MC-ICP-MS yielded an internal precision for δ87Rb of external precision was generally better than ± 0.06‰ (2SD) based on the long-term results of the Rb standard solutions NIST SRM 984. A series of geological rock standards, were analyzed using this method, and the results indicate significant Rb isotope differences in different geologic materials. This will provide a powerful tool to investigate Rb isotope fractionation during geological processes.Based on this method, Rb isotope compositions from a basaltic weathering profile were carried out. The data show the lighter Rb (85Rb) isotope is preferentially leached from the weathering profile and remains heavy Rb isotope (87Rb) in the weathered residues during the incipient weathering stage. From the moderate to advanced weathering stage, the significant variations of Rb isotope were observed and multiple factors, such as leaching, adsorption, desorption, and precipitation, should play important role in fractionating Rb isotope.

  13. Isotopic anomalies in cosmic rays and winds from Wolf-Rayet stars - a new model

    International Nuclear Information System (INIS)

    Maeder, A.

    1984-01-01

    The insufficiency of the metal-rich supernovae model and of the Wolf-Rayet star model for explaining the isotopic anomalies in the galactic cosmic ray source (GCRS) is examined, and a new model for attacking the anomaly problem is proposed. The main properties of WR stars relevant to the study of GCRS are recalled, with particular emphasis on their chemical excesses and the steep galactic gradient in their distribution. The proposed model assumes that GCRs originate from two main sources of different composition and galactic distribution, probably SN's and WR stars. Their properties may change with galactocentric distance. The relevant physical physicochemical relationships are derived, and some approximations which account for the contributions of WR and SN sources in GCRS are worked out for comparison with observations. The model is found to account very well for the observed anomalies. 33 references

  14. System to provide 3D information on geological anomaly zone in deep subsea

    Science.gov (United States)

    Kim, W.; Kwon, O.; Kim, D.

    2017-12-01

    The study on building the ultra long and deep subsea tunnel of which length is 50km and depth is 200m at least, respectively, is underway in Korea. To analyze the geotechnical information required for designing and building subsea tunnel, topographic/geologiccal information analysis using 2D seabed geophysical prospecting and topographic, geologic, exploration and boring data were analyzed comprehensively and as a result, automation method to identify the geological structure zone under seabed which is needed to design the deep and long seabed tunnel was developed using geostatistical analysis. In addition, software using 3D visualized ground information to provide the information includes Gocad, MVS, Vulcan and DIMINE. This study is intended to analyze the geological anomaly zone for ultra deep seabed l and visualize the geological investigation result so as to develop the exclusive system for processing the ground investigation information which is convenient for the users. Particularly it's compatible depending on file of geophysical prospecting result and is realizable in Layer form and for 3D view as well. The data to be processed by 3D seabed information system includes (1) deep seabed topographic information, (2) geological anomaly zone, (3) geophysical prospecting, (4) boring investigation result and (5) 3D visualization of the section on seabed tunnel route. Each data has own characteristics depending on data and interface to allow interlocking with other data is granted. In each detail function, input data is displayed in a single space and each element is selectable to identify the further information as a project. Program creates the project when initially implemented and all output from detail information is stored by project unit. Each element representing detail information is stored in image file and is supported to store in text file as well. It also has the function to transfer, expand/reduce and rotate the model. To represent the all elements in

  15. Nd and Sr isotopes: implications of provenance and geological mapping

    International Nuclear Information System (INIS)

    Albuquerque, Marcio Fernando dos Santos; Horbe, Adriana Maria Coimbra; Dantas, Elton Luiz

    2015-01-01

    XRD, Nd and Sr isotopes, major, minor and traces elements quantification were applied to rocks, lateritic crusts and soils from Sumauma Supergroup and Alto Tapajos Group, in order to indicate provenance of the rocks and using lateritic products as geologic mapping tool. For the rocks, the results showed sources related to provinces Tapajos Parima, Rondonia Juruena, Sunsas, Carajas and Amazonia Central. However, the incision of Cachimbo graben allowed which the Sumauma Supergroup erosion also were source for the Alto Tapajos Group, allied to contribution of volcanics from Colider Group. Lateritic crusts and soils are correlates to bedrocks, allowing the use as geologic mapping tool. (author)

  16. Anomalies of natural gas compositions and carbon isotope ratios caused by gas diffusion - A case from the Donghe Sandstone reservoir in the Hadexun Oilfield, Tarim Basin, northwest China

    Science.gov (United States)

    Wang, Yangyang; Chen, Jianfa; Pang, Xiongqi; Zhang, Baoshou; Wang, Yifan; He, Liwen; Chen, Zeya; Zhang, Guoqiang

    2018-05-01

    Natural gases in the Carboniferous Donghe Sandstone reservoir within the Block HD4 of the Hadexun Oilfield, Tarim Basin are characterized by abnormally low total hydrocarbon gas contents ( δ13C ethane (C2) gas has never been reported previously in the Tarim Basin and such large variations in δ13C have rarely been observed in other basins globally. Based on a comprehensive analysis of gas geochemical data and the geological setting of the Carboniferous reservoirs in the Hadexun Oilfield, we reveal that the anomalies of the gas compositions and carbon isotope ratios in the Donghe Sandstone reservoir are caused by gas diffusion through the poorly-sealed caprock rather than by pathways such as gas mixing, microorganism degradation, different kerogen types or thermal maturity degrees of source rocks. The documentation of an in-reservoir gas diffusion during the post entrapment process as a major cause for gas geochemical anomalies may offer important insight into exploring natural gas resources in deeply buried sedimentary basins.

  17. A Learner-Centered Spiral Knowledge Approach to Teaching Isotope Geology

    Science.gov (United States)

    Reid, M. R.

    2006-12-01

    Aided by the insights I gained by participation in the Arizona Board of Regents Tri-University Collaboration on Learner-Centered Practice, I made major changes to a graduate course in isotope geology (GLG617), including: 1) implementation of a spiral knowledge approach (e.g., Bruner, 1990; Dyar et al., 2004); 2) incorporation of more learner-centered in-class activities; and 3) more explicit emphasis on skills that I regarded as important for success in geochemistry. In the geosciences, the field of isotope geology is now an essential area of inquiry with implications for geologic timescales, climate information, tracing geochemical processes, and biological evolution, to name a few. The traditional approach to teaching isotope geology suffers from the fact that learning tends to be compartmentalized by technique/approach and one subfield (e.g., stable or radiogenic isotopes) is usually favored by appearing earlier in semester. To make learning more integrated, I employed a simplified spiral learning approach so that common principles could be revisited several times over the course of the semester and, in so doing, students' grasp of the fundamental principles could be scaffolded into greater understanding. Other learner-centered changes to the course included more explicit emphasis on helping students become comfortable with interpreting data displayed graphically and explicit emphasis on helping students give and evaluate oral presentations that rely on isotope data. I also developed a detailed grading rubric for the final paper and allowed students to have a draft of their final papers evaluated and graded (guided by Huba and Freed, 2000) A number of cooperative learning activities developed specifically for this course (19 in all) enabled me to gain a better appreciation for students' learning. Activities included pair share, round-robin, small group explorations of techniques and case studies (sometimes as introduction to, sometimes as review of material

  18. Geological Sulfur Isotopes Indicate Elevated OCS in the Archean Atmosphere, Solving the Faint Young Sun Paradox

    DEFF Research Database (Denmark)

    Ueno, Yuichiro; Johnson, Matthew Stanley; Danielache, Sebastian Oscar

    2009-01-01

    Distributions of sulfur isotopes in geological samples would provide a record of atmospheric composition if the mechanism producing the isotope effects could be described quantitatively. We determined the UV absorption spectra of 32SO2, 33SO2, and 34SO2 and use them to interpret the geological re......-rich, reducing Archean atmosphere. The radiative forcing, due to this level of OCS, is able to resolve the faint young sun paradox. Further, the decline of atmospheric OCS may have caused the late Archean glaciation....

  19. Geological controls on isotopic signatures of streamflow: results from a nested catchment experiment in Luxembourg (Europe)

    Science.gov (United States)

    Pfister, Laurent; McDonnell, Jeffrey J.; Hissler, Christophe; Martinez-Carreras, Nuria; Gourdol, Laurent; Klaus, Julian; François Iffly, Jean; Barnich, François; Stewart, Mike K.

    2014-05-01

    Controls of geology and topography on hydrological metrics, like summer low flow (Grant and Tague, 2004) or dynamic storage (Sayama et al., 2011), have been identified in nested catchment experiments. However, most tracer-based studies on streamflow generation have been carried out in small (10 km2) homogenous catchments (Klaus and McDonnell, 2013). The controlling effects of catchment physiography on how catchments store and release water, and how this eventually controls stream isotope behaviour over a large range of scale are poorly understood. Here, we present results from a nested catchment analysis in the Alzette River basin (Luxembourg, Europe). Our hydro-climatological network consists of 16 recording streamgauges and 21 pluviographs. Catchment areas range from 0.47 to 285 km2, with clean and mixed combinations of distinct geologies ranging from schists to marls, sandstone, dolomite and limestone. Our objective was to identify geological controls on (i) winter runoff ratios, (ii) maximum storage and (iii) isotopic signatures in streamflow. For each catchment we determined average runoff ratios from winter season precipitation-discharge double-mass curves. Maximum catchment storage was based on the dynamic storage change approach of Sayama et al. (2011). Changes in isotopic signatures of streamflow were documented along individual catchment flow duration curves. We found strong correlations between average winter runoff ratios, maximum storage and the prevailing geological settings. Catchments with impermeable bedrock (e.g. marls or schists) were characterised by small storage potential and high average filling ratios. As a consequence, these catchments also exhibited the highest average runoff ratios. In catchments underlain by permeable bedrock (e.g. sandstone), storage potential was significantly higher and runoff ratios were considerably smaller. The isotopic signatures of streamflow showed large differences between catchments. In catchments dominated by

  20. Groundwater oxygen isotope anomaly before the M6.6 Tottori earthquake in Southwest Japan.

    Science.gov (United States)

    Onda, Satoki; Sano, Yuji; Takahata, Naoto; Kagoshima, Takanori; Miyajima, Toshihiro; Shibata, Tomo; Pinti, Daniele L; Lan, Tefang; Kim, Nak Kyu; Kusakabe, Minoru; Nishio, Yoshiro

    2018-03-19

    Geochemical monitoring of groundwater in seismically-active regions has been carried out since 1970s. Precursors were well documented, but often criticized for anecdotal or fragmentary signals, and for lacking a clear physico-chemical explanation for these anomalies. Here we report - as potential seismic precursor - oxygen isotopic ratio anomalies of +0.24‰ relative to the local background measured in groundwater, a few months before the Tottori earthquake (M 6.6) in Southwest Japan. Samples were deep groundwater located 5 km west of the epicenter, packed in bottles and distributed as drinking water between September 2015 and July 2017, a time frame which covers the pre- and post-event. Small but substantial increase of 0.07‰ was observed soon after the earthquake. Laboratory crushing experiments of aquifer rock aimed to simulating rock deformation under strain and tensile stresses were carried out. Measured helium degassing from the rock and 18 O-shift suggest that the co-seismic oxygen anomalies are directly related to volumetric strain changes. The findings provide a plausible physico-chemical basis to explain geochemical anomalies in water and may be useful in future earthquake prediction research.

  1. Geology and stable isotope geochemistry of Paleoarchean sulfur. Formation, preservation and geobiology of ancient pyrite and barite

    NARCIS (Netherlands)

    Roerdink, D.L.|info:eu-repo/dai/nl/318834340

    2013-01-01

    Sulfur isotopes in ancient sulfate and sulfide minerals provide a comprehensive record of microbial processes involved in the early sulfur cycle on Earth. However, the interpretation of these isotopic signatures requires information on the geological context of such samples, because abiotic

  2. Measurement of C and N isotopes of geological samples using Delta V Plus Stable Isotope Ratio Mass Spectrometer via different preparatory systems

    Digital Repository Service at National Institute of Oceanography (India)

    Karapurkar, S.; Methar, A.; Agnihotri, R.

    standard developed for routine C and N isotope analyses of various types of geological samples containing organic matter in order to assess stabilities/ reproducibility of the IRMS in different time windows....

  3. Lagoa Real design - Calculation of geologic reserves from AN-13 anomaly (Fazenda Cachoeira), Lagoa Real/BA, Brazil

    International Nuclear Information System (INIS)

    Marques, J.P.M.

    1982-12-01

    The conventional calculation of Geological Reserves from AN-13 Anomaly, Lagoa Real, with the limit ratio of U sub(3) O sub(8) at 700 ppm by Linear Method is presented. The information of 49 boreholes with chemical analysis and radiometric profile is included, evaluating the reserves to a maximum of 189 m deep. (author)

  4. Proceedings of the symposium on isotope geology progress: technology, methods, theory and application

    International Nuclear Information System (INIS)

    2003-11-01

    The symposium was held in Beijing, Nov. 7-11, and the proceedings collects 122 articles, the contents include: new technology and new methods on isotopic test; isotope fractionation mechanism; the early evolution of the solar system and the Earth; continental dynamics and evolution of orogenic belts; minerals, energy and water; major history events on life origin, evolution and geology; changes in the Earth's global and modern environment--the oceans, the atmosphere, rivers and lakes, karst and soil, ecological agriculture and modern environment

  5. ANALISIS ANOMALI GRAVITASI SEBAGAI ACUAN DALAM PENENTUAN STRUKTUR GEOLOGI BAWAH PERMUKAAN DAN POTENSI GEOTHERMAL (Studi Kasus Di Daerah Songgoriti Kota Batu

    Directory of Open Access Journals (Sweden)

    Nurul Hidayat, Abdul Basid

    2012-03-01

    Full Text Available Telah dilakukan penelitian dengan metode gravitasi pada tanggal 26 - 27 April 2011 di daerah Songgoriti Kota Batu dengan tujuan untuk mengetahui pola anomali Bouguer dan struktur geologi bawah permukaan serta potensi panasbumi di daerah tersebut. Berdasarkan interpretasi kualitatif pada kontur anomali Bouguer  lengkap didapatkan variasi nilai anomali Bouguer antara  47,3 - 67,4 mGal dengan nilai anomali tinggi terdapat pada arah tenggara penelitian dan nilai anomali sedang pada arah tenggara-selatan dan timur laut daerah penelitian. Hampir 75% daerah penelitian didominasi oleh nilai anomali Bouguer rendah. Hasil interpretasi kuantitatif pada model penampang 2D lintasan AB dan CD, didapatkan tujuh lapisan batuan di bawah permukaan yaitu lapisan lapuk, tufa pasiran, anglomerat, lempung pasir, breksi tufaan terlempungkan, lava, dan breksi Vulkanik. Berdasarkan interpretasi kualitatif dan kuantitatif serta penelitian sebelumya dapat disimpulkan bahwa potensi geothermal di daerah penelitian sangat kecil.

  6. Osmium isotope anomalies in chondrites: Results for acid residues and related leachates

    Science.gov (United States)

    Yokoyama, Tetsuya; O'D. Alexander, Conel M.; Walker, Richard J.

    2010-03-01

    We have investigated Os isotope anomalies in acid residues enriched in insoluble organic matter (IOM) extracted from ten primitive chondrites, acid leachates and residues of these fractions, as well as acid leachates of bulk chondrites. Osmium isotopic compositions of bulk carbonaceous, ordinary and enstatite chondrites are also reported. Consistent with prior results, bulk chondrites have homogeneous Os isotope compositions for s-, r-, and p-process nuclides that are indistinguishable from terrestrial, at the current level of resolution. In contrast, nearly all the IOM-rich residues are enriched in s-process Os, evidently due to the preferential incorporation of s-process enriched presolar grains (most likely presolar SiC). Presolar silicate grains that formed in red giant branch (RGB) or asymptotic giant branch (AGB) stars are also likely hosts of additional s-process Os in chondrites. Consistent with one prior study, Os released by weak acid leaching of bulk chondrites is slightly to strongly enriched in r-process nuclides, of which the carrier may be fine-grained presolar silicates formed in supernovae or unidentified solar phases. Collectively, the different, chemically concentrated components in these meteorites are variably enriched in s-, r-, and possibly p-process Os, of which the individual carriers must have been produced in multiple stellar environments. The lack of evidence for Os isotopic heterogeneity among bulk chondrites contrasts with evidence for isotopic heterogeneities for various other elements at approximately the same levels of resolution (e.g., Cr, Mo, Ru, Ba, Sm, and Nd). One possible explanation for this is that the heterogeneities for some elements in bulk materials reflect selective removal of some types of presolar grains as a result of nebular processes, and that because of the strong chemical differences between Os and the other elements, the Os was not significantly affected. Another possible explanation is that late-stage injection

  7. Geology, mineralogy and geochemistry of Ferezneh ferromanganese anomaly, east of Sangan mines complex, NE Iran

    Directory of Open Access Journals (Sweden)

    Nazi Mazhari

    2015-04-01

    Full Text Available Introduction The Ferezneh prospect area is one of the eastern anomalies of Khaf’s Sangan iron mine. The Sangan mines complex is located within the Khaf-Kashmar-Bardeskan volcano-plutonic and metallogenic belt in northeastern Iran. The Sangan mine is the largest Fe skarn in western Asia, having a proven reserve of over 1000 Mt iron ore @ 53% Fe (Golmohammadi et al., 2015 and consisting of three parts; western, central and eastern Sangan, each part including several anomalies. In this study, Ferezneh (North and West prospect area which is an eastern anomaly of the Sangan iron ore is discussed. Ferezneh anomaly is located in 60°36'7" - 60°34'27"E and 34°30'47" - 34°29'46"N, 35 km south of the city of Taybad, 10 km southeast of Karat and 1.5 km southwest of Ferezneh village. The purpose of this study was to prepare a geologic map for separation and identification of the intrusions, determining their relationships with mineralization, distinguishing the type of mineralization, mineralogy, petrology and geochemistry of the mineral deposits, and finally their relationship with other major Sangan’s deposits. Materials and methods In order to achieve the objectives of the study: 1- 140 thin sections of the intrusive rocks, marble limestone and dolomite, as well as 40 polished sections of ore were taken in an area of 9.5 km2. Mineralogy and mineralization studies were performed in the Economic Geology Laboratory of Ferdowsi University of Mashhad. 2- A few samples were selected for X-ray diffraction analysis in order to ensure accuracy of mineralogical studies and were sent to Binalood Laboratory in Tehran. 3- In addition to major and minor elements geochemistry study of the ores, 10 samples were sent to East Amitis Laboratory in Mashhad for XRF analysis and also to Canada S.G.S Laboratory for ICP-MS analysis. Discussion and results Mineralization in the Ferezneh prospect area was limited to iron and manganese oxides in the form of massive and

  8. Determination of natural alpha-emitting isotopes of uranium and thorium in environmental and geological samples

    International Nuclear Information System (INIS)

    Crespo, M.T.

    1996-01-01

    It is described the complete radiochemical procedure used for the determination of uranium and thorium isotopes in environmental and geological samples by alpha spectrometry. Source preparation methods, alpha-counting and spectral analysis are also included

  9. NUCLEOSYNTHETIC TUNGSTEN ISOTOPE ANOMALIES IN ACID LEACHATES OF THE MURCHISON CHONDRITE: IMPLICATIONS FOR HAFNIUM-TUNGSTEN CHRONOMETRY

    Energy Technology Data Exchange (ETDEWEB)

    Burkhardt, Christoph; Wieler, Rainer [Institute of Geochemistry and Petrology, Clausiusstrasse 25, ETH Zurich, CH-8092 Zurich (Switzerland); Kleine, Thorsten [Institut fuer Planetologie, Westfaelische Wilhelms-Universitaet Muenster, Wilhelm-Klemm-Strasse 10, D-48149 Muenster (Germany); Dauphas, Nicolas, E-mail: burkhardt@erdw.ethz.ch [Origins Laboratory, Department of the Geophysical Sciences and Enrico Fermi Institute, University of Chicago, 5734 South Ellis Avenue, Chicago, IL 60637 (United States)

    2012-07-01

    Progressive dissolution of the Murchison carbonaceous chondrite with acids of increasing strengths reveals large internal W isotope variations that reflect a heterogeneous distribution of s- and r-process W isotopes among the components of primitive chondrites. At least two distinct carriers of nucleosynthetic W isotope anomalies must be present, which were produced in different nucleosynthetic environments. The co-variation of {sup 182}W/{sup 184}W and {sup 183}W/{sup 184}W in the leachates follows a linear trend that is consistent with a mixing line between terrestrial W and a presumed s-process-enriched component. The composition of the s-enriched component agrees reasonably well with that predicted by the stellar model of s-process nucleosynthesis. The co-variation of {sup 182}W/{sup 184}W and {sup 183}W/{sup 184}W in the leachates provides a means for correcting the measured {sup 182}W/{sup 184}W and {sup 182}W/{sup 183}W of Ca-Al-rich inclusions (CAI) for nucleosynthetic anomalies using the isotopic variations in {sup 183}W/{sup 184}W. This new correction procedure is different from that used previously, and results in a downward shift of the initial {epsilon}{sup 182}W of CAI to -3.51 {+-} 0.10 (where {epsilon}{sup 182}W is the variation in 0.01% of the {sup 182}W/{sup 183}W ratio relative to Earth's mantle). This revision leads to Hf-W model ages of core formation in iron meteorite parent bodies that are {approx}2 Myr younger than previously calculated. The revised Hf-W model ages are consistent with CAI being the oldest solids formed in the solar system, and indicate that core formation in some planetesimals occurred within {approx}2 Myr of the beginning of the solar system.

  10. A study of Sr and Nd isotopic geology during anatexis in the area No.8411

    International Nuclear Information System (INIS)

    Ying Junlong

    1993-01-01

    An isotopic geology study in the area No.8411 indicates that the J 1-2 sandstone is lacustrine facies sediments mainly originated from Proterozoic old continental crust. Therefore, the magmatic rocks are derived from partial melting or remelting-contamination of Proterozoic old continents in the lower crust. The initial concentration of uranium is related with the magma contamination caused by anatexis in the old sialic crust. The isotopic compositions of both uranium minerals and magmatic rocks are relatively concordant. According to the results of this study, combined with petrology, mineralogy, isotopic evolution and REE contents, it is considered that uranium is derived from the deep source and uranium source rocks are Proterozoic old continents

  11. Aeromagnetic anomalies over faulted strata

    Science.gov (United States)

    Grauch, V.J.S.; Hudson, Mark R.

    2011-01-01

    High-resolution aeromagnetic surveys are now an industry standard and they commonly detect anomalies that are attributed to faults within sedimentary basins. However, detailed studies identifying geologic sources of magnetic anomalies in sedimentary environments are rare in the literature. Opportunities to study these sources have come from well-exposed sedimentary basins of the Rio Grande rift in New Mexico and Colorado. High-resolution aeromagnetic data from these areas reveal numerous, curvilinear, low-amplitude (2–15 nT at 100-m terrain clearance) anomalies that consistently correspond to intrasedimentary normal faults (Figure 1). Detailed geophysical and rock-property studies provide evidence for the magnetic sources at several exposures of these faults in the central Rio Grande rift (summarized in Grauch and Hudson, 2007, and Hudson et al., 2008). A key result is that the aeromagnetic anomalies arise from the juxtaposition of magnetically differing strata at the faults as opposed to chemical processes acting at the fault zone. The studies also provide (1) guidelines for understanding and estimating the geophysical parameters controlling aeromagnetic anomalies at faulted strata (Grauch and Hudson), and (2) observations on key geologic factors that are favorable for developing similar sedimentary sources of aeromagnetic anomalies elsewhere (Hudson et al.).

  12. The molecular physics of photolytic fractionation of sulfur and oxygen isotopes in planetary atmospheres (Invited)

    Science.gov (United States)

    Johnson, M. S.; Schmidt, J. A.; Hattori, S.; Danielache, S.; Meusinger, C.; Schinke, R.; Ueno, Y.; Nanbu, S.; Kjaergaard, H. G.; Yoshida, N.

    2013-12-01

    Atmospheric photochemistry is able to produce large mass independent anomalies in atmospheric trace gases that can be found in geological and cryospheric records. This talk will present theoretical and experimental investigations of the molecular mechanisms producing photolytic fractionation of isotopes with special attention to sulfur and oxygen. The zero point vibrational energy (ZPE) shift and reflection principle theories are starting points for estimating isotopic fractionation, but these models ignore effects arising from isotope-dependent changes in couplings between surfaces, excited state dynamics, line densities and hot band populations. The isotope-dependent absorption spectra of the isotopologues of HCl, N2O, OCS, CO2 and SO2 have been examined in a series of papers and these results are compared with experiment and ZPE/reflection principle models. Isotopic fractionation in planetary atmospheres has many interesting applications. The UV absorption of CO2 is the basis of photochemistry in the CO2-rich atmospheres of the ancient Earth, and of Mars and Venus. For the first time we present accurate temperature and isotope dependent CO2 absorption cross sections with important implications for photolysis rates of SO2 and H2O, and the production of a mass independent anomaly in the Ox reservoir. Experimental and theoretical results for OCS have implications for the modern stratospheric sulfur budget. The absorption bands of SO2 are complex with rich structure producing isotopic fractionation in photolysis and photoexcitation.

  13. Chemical methods for Sm-Nd separation and its application in isotopic geological dating

    International Nuclear Information System (INIS)

    Guo Qifeng.

    1990-01-01

    Three chemical methods for Sm-Nd separation are mainly desribed: low chromatography of butamone-ammonium thiocyanate for hight concentration Sm and Nd separation, P 240 column chromatography for medium concentration Sm-Nd separation, and pressure ion exchange for low concentration Sm-Nd. The first Sm-Nd synchrone obtained in China with Sm-Nd methods is introduced and Sm-Nd isotopic geological dating in Early Archaean rocks in eastern Hebei has been determined

  14. Marine magnetic anomalies off Ratnagiri, Western continental shelf of India

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, D.G.

    of magnetic anomalies. Two-dimensional model and spectral studies of these anomalies were carried out, and subsurface models of the geology in the area have been derived from anomalies at a number of places. The results suggest that the anomalies occur over a...

  15. The determination of initial ratio of strontium isotope in rocks and its geological application

    International Nuclear Information System (INIS)

    Ying Junlong; Zhao Puyun; Lin Xiulan

    1989-04-01

    The method to determine the initial ratio of strontium isotopes existed in rocks of poor rubidium and rich strontium and main carrier minerals is introduced. The initial ratio obtained from this method is equivalent to that acquired by Rb-Sr isochrone. Based on this result, information on regional rock genesis and mineralization regularities can be provided. It has great significance in the research on activities of ancient continental margin and material sources as well as their evolution. The migration of rock, and ore-forming materials, matallogenetic mechanism and its distribution in the space and time evolution are studied by using these data. In conclusion, the determination of strontium isotopes has broad prospects in the geological research

  16. Geochemistry of silicon isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Ding, Tiping; Li, Yanhe; Gao, Jianfei; Hu, Bin [Chinese Academy of Geological Science, Beijing (China). Inst. of Mineral Resources; Jiang, Shaoyong [China Univ. of Geosciences, Wuhan (China).

    2018-04-01

    Silicon is one of the most abundant elements in the Earth and silicon isotope geochemistry is important in identifying the silicon source for various geological bodies and in studying the behavior of silicon in different geological processes. This book starts with an introduction on the development of silicon isotope geochemistry. Various analytical methods are described and compared with each other in detail. The mechanisms of silicon isotope fractionation are discussed, and silicon isotope distributions in various extraterrestrial and terrestrial reservoirs are updated. Besides, the applications of silicon isotopes in several important fields are presented.

  17. The common property of isotope anomalies in meteorites

    International Nuclear Information System (INIS)

    Robert, F.

    2004-01-01

    The treatment proposed to account for the non-mass-dependent isotopic fractionation effect observed for oxygen isotopes during the synthesis of ozone (Robert and Camy-Peyret 2001) is applied to other chemical elements. A numerical treatment to calculate isotopic reaction rate ratios is proposed. This treatment yields non-mass-dependent isotopic effects in other chemical elements, qualitatively similar to those observed in some of the high temperature minerals found in the carbonaceous meteorites. This treatment may reflect the numerical consequences of an unrecognized quantum mechanical effect, linked to a property of chemical reactions involving indistinguishable isotopes. (author)

  18. Understanding wetland sub-surface hydrology using geologic and isotopic signatures

    Directory of Open Access Journals (Sweden)

    P. Sahu

    2009-07-01

    Full Text Available This paper attempts to utilize hydrogeology and isotope composition of groundwater to understand the present hydrological processes prevalent in a freshwater wetland, source of wetland groundwater, surface water/groundwater interaction and mixing of groundwater of various depth zones in the aquifer. This study considers East Calcutta Wetlands (ECW – a freshwater peri-urban inland wetland ecosystem located at the lower part of the deltaic alluvial plain of South Bengal Basin and east of Kolkata city. This wetland is well known over the world for its resource recovery systems, developed by local people through ages, using wastewater of the city. Geological investigations reveal that the sub-surface geology is completely blanketed by the Quaternary sediments comprising a succession of silty clay, sand of various grades and sand mixed with occasional gravels and thin intercalations of silty clay. At few places the top silty clay layer is absent due to scouring action of past channels. In these areas sand is present throughout the geological column and the areas are vulnerable to groundwater pollution. Groundwater mainly flows from east to west and is being over-extracted to the tune of 65×103 m3/day. δ18O and δD values of shallow and deep groundwater are similar indicating resemblance in hydrostratigraphy and climate of the recharge areas. Groundwater originates mainly from monsoonal rain with some evaporation prior to or during infiltration and partly from bottom of ponds, canals and infiltration of groundwater withdrawn for irrigation. Relatively high tritium content of the shallow groundwater indicates local recharge, while the deep groundwater with very low tritium is recharged mainly from distant areas. At places the deep aquifer has relatively high tritium, indicating mixing of groundwater of shallow and deep aquifers. Metals such as copper, lead, arsenic, cadmium, aluminium, nickel and chromium are also

  19. Understanding wetland sub-surface hydrology using geologic and isotopic signatures

    Science.gov (United States)

    Sikdar, P. K.; Sahu, P.

    2009-07-01

    This paper attempts to utilize hydrogeology and isotope composition of groundwater to understand the present hydrological processes prevalent in a freshwater wetland, source of wetland groundwater, surface water/groundwater interaction and mixing of groundwater of various depth zones in the aquifer. This study considers East Calcutta Wetlands (ECW) - a freshwater peri-urban inland wetland ecosystem located at the lower part of the deltaic alluvial plain of South Bengal Basin and east of Kolkata city. This wetland is well known over the world for its resource recovery systems, developed by local people through ages, using wastewater of the city. Geological investigations reveal that the sub-surface geology is completely blanketed by the Quaternary sediments comprising a succession of silty clay, sand of various grades and sand mixed with occasional gravels and thin intercalations of silty clay. At few places the top silty clay layer is absent due to scouring action of past channels. In these areas sand is present throughout the geological column and the areas are vulnerable to groundwater pollution. Groundwater mainly flows from east to west and is being over-extracted to the tune of 65×103 m3/day. δ18O and δD values of shallow and deep groundwater are similar indicating resemblance in hydrostratigraphy and climate of the recharge areas. Groundwater originates mainly from monsoonal rain with some evaporation prior to or during infiltration and partly from bottom of ponds, canals and infiltration of groundwater withdrawn for irrigation. Relatively high tritium content of the shallow groundwater indicates local recharge, while the deep groundwater with very low tritium is recharged mainly from distant areas. At places the deep aquifer has relatively high tritium, indicating mixing of groundwater of shallow and deep aquifers. Metals such as copper, lead, arsenic, cadmium, aluminium, nickel and chromium are also present in groundwater of various depths. Therefore

  20. Geological and radiometric study of the anomaly ''San Martin'' municipality of Sierra Mojada, Coahuila

    International Nuclear Information System (INIS)

    Ibarra Mora, P.

    1975-01-01

    When it first became known that there were uranium ores at the mine known as San Martin (72 hectares, Mining Agency, Sabinas, Mexico), exploration work was started with the sinking of two wells at the sites of maximum radiometric intensity. A short while afterwards, however, this work was suspended. In 1974, the work required for evaluation of the locality was begun. Geological and radiometric studies carried out both at the surface and underground pointed to the conclusion that the San Martin anomaly, down to the depth explored (40 metres), is a stockwork-type deposit or a tabular seam of the fissure type. It was concluded that in view of the grades obtained (0.0227%U 3 O 6 ) down to 40 metres, the deposit cannot be considered of econimic importance at the present time. (author)

  1. Isotopic exchange of carbon-bound hydrogen over geologic timescales

    Science.gov (United States)

    Sessions, Alex L.; Sylva, Sean P.; Summons, Roger E.; Hayes, John M.

    2004-04-01

    The increasing popularity of compound-specific hydrogen isotope (D/H) analyses for investigating sedimentary organic matter raises numerous questions about the exchange of carbon-bound hydrogen over geologic timescales. Important questions include the rates of isotopic exchange, methods for diagnosing exchange in ancient samples, and the isotopic consequences of that exchange. This article provides a review of relevant literature data along with new data from several pilot studies to investigate such issues. Published experimental estimates of exchange rates between organic hydrogen and water indicate that at warm temperatures (50-100°C) exchange likely occurs on timescales of 104 to 108 yr. Incubation experiments using organic compounds and D-enriched water, combined with compound-specific D/H analyses, provide a new and highly sensitive method for measuring exchange at low temperatures. Comparison of δD values for isoprenoid and n-alkyl carbon skeletons in sedimentary organic matter provides no evidence for exchange in young (exchange in ancient (>350 Ma) rocks. Specific rates of exchange are probably influenced by the nature and abundance of organic matter, pore-water chemistry, the presence of catalytic mineral surfaces, and perhaps even enzymatic activity. Estimates of equilibrium fractionation factors between organic H and water indicate that typical lipids will be depleted in D relative to water by ∼75 to 140‰ at equilibrium (30°C). Thus large differences in δD between organic molecules and water cannot be unambiguously interpreted as evidence against hydrogen exchange. A better approach may be to use changes in stereochemistry as a proxy for hydrogen exchange. For example, estimated rates of H exchange in pristane are similar to predicted rates for stereochemical inversion in steranes and hopanes. The isotopic consequences of this exchange remain in question. Incubations of cholestene with D2O indicate that the number of D atoms incorporated during

  2. Application and evaluation of the mass spectrometric isotope dilution technique in the determination of rare earths in geological materials

    International Nuclear Information System (INIS)

    Moraes, N.M.P. de.

    1988-01-01

    Establishment of the experimental procedures employed in the rare earth element determination of geological samples by mass spectrometric isotope dilution analysis is discussed in the present work. The procedures involve preparation and calibration of the isotope tracers isotope dilution, dissolution in a teflon pressure vessel, chemical separation and isotope analysis using a fully automated Micromass VG ISOTOPES model 354 thermal ionization mass spectrometer. For the initial chemical separation of total rare earths the cationic resin was employed and HC1 and HNO 3 acids as eluents. In the second step rare earths elements were separated into individual (La, Ce and Nd) and subgroups (Sm-Eu-Gd, Yb-Er-Dy) fractions using the same cationic resin and α-HIBA as eluent. Nine elements La, Ce, Nd, Sm, Eu, Gd, Dy, Er and Yb are determined by this method in the ''United States Geological Survey'' (USGS) standard samples GSP-1, AGV-1 and G-2, with an overall precision of +- 1 to 2% and an accuracy of 5%. The concentration of rare earth element determined in the standard sample PCC-1 showed that the total analytical blanks are in submicrogram levels. The concentration of rare earth elements in the same USGS standard samples were also determined by Instrumental neutron activation analysis, neutron activation analysis with chemical separation before irradiation and inductively coupled argon plasma spectroscopy. The chemical procedures employed for these methods are the same as that used for mass spectrometric isotope dilution. Based on the results obtained, each method was evaluated pointing out their merits and defects. The study clearly showed that the chemical procedure employed for all these techniques was satisfactory. (author) [pt

  3. Post-Metamorphic Thermal Anomaly across the Nacimiento Block, Central California: a Hydrothermal Overprint?

    Science.gov (United States)

    Lacroix, B.; Hughes, J.; Lahfid, A.; Delchini, S.

    2017-12-01

    The thermal history of the Nacimiento block located within the Franciscan Complex (California, USA) has been previously proposed based on both vitrinite reflectance (Rm) and illite cristallinity methods (Underwood et al., 1995). These authors suggest that the Nacimiento block is locally perturbed by a thermal anomaly (up to 300ºC), probably caused by post-metamorphic hydrothermal activity linked to the emplacement of an Au-deposit: the Los Burros Gold deposit. Although both thermal anomaly and deposit seem spatially correlated, their relationship is still poorly constrained. Detailed geological and structural mapping within the Los Burros Mining District (LBMD) coupled with a thermal study was conducted to better understand processes responsible for the anomalous temperatures recorded near the deposit. The regional maximum temperature reached by metasediments from the Nacimiento block have been first investigated using the Raman Spectroscopy of Carbonaceous Materials (RSCM) method. In addition, through careful fluid-inclusion and stable isotopes (O and C) studies on the deposit, the temperature and the potential source of the fluid responsible for the Los Burros Au-deposit emplacement were investigated. RSCM technique confirms the presence of a thermal anomaly in the range 260-320ºC near LBMD. However, our structural and petrographic results suggest that the thermal anomaly is not correlated to a post-metamorphic hydrothermal overprint but rather to a late, transpressive deformation uplifting buried metamorphic rocks.

  4. Simulation of the diurnal variations of the oxygen isotope anomaly (Δ17O of reactive atmospheric species

    Directory of Open Access Journals (Sweden)

    J. Savarino

    2011-04-01

    Full Text Available The isotope anomaly (Δ17O of secondary atmospheric species such as nitrate (NO3− or hydrogen peroxide (H2O2 has potential to provide useful constrains on their formation pathways. Indeed, the Δ17O of their precursors (NOx, HOx etc. differs and depends on their interactions with ozone, which is the main source of non-zero Δ17O in the atmosphere. Interpreting variations of Δ17O in secondary species requires an in-depth understanding of the Δ17O of their precursors taking into account non-linear chemical regimes operating under various environmental settings. This article reviews and illustrates a series of basic concepts relevant to the propagation of the Δ17O of ozone to other reactive or secondary atmospheric species within a photochemical box model. We present results from numerical simulations carried out using the atmospheric chemistry box model CAABA/MECCA to explicitly compute the diurnal variations of the isotope anomaly of short-lived species such as NOx and HOx. Using a simplified but realistic tropospheric gas-phase chemistry mechanism, Δ17O was propagated from ozone to other species (NO, NO2, OH, HO2, RO2, NO3, N2O5, HONO, HNO3, HNO4, H2O2 according to the mass-balance equations, through the implementation of various sets of hypotheses pertaining to the transfer of Δ17O during chemical reactions. The model results confirm that diurnal variations in Δ17O of NOx predicted by the photochemical steady-state relationship during the day match those from the explicit treatment, but not at night. Indeed, the Δ17O of NOx is "frozen" at night as soon as the photolytical lifetime of NOx drops below ca. 10 min. We introduce and quantify the diurnally-integrated isotopic signature (DIIS of sources of atmospheric nitrate and H2O2, which is of particular relevance to larger-scale simulations of Δ17O where high computational costs cannot be afforded.

  5. The gravity anomaly of Mount Amiata; different approaches for understanding anomaly source distribution

    Science.gov (United States)

    Girolami, C.; Barchi, M. R.; Heyde, I.; Pauselli, C.; Vetere, F.; Cannata, A.

    2017-11-01

    In this work, the gravity anomaly signal beneath Mount Amiata and its surroundings have been analysed to reconstruct the subsurface setting. In particular, the work focuses on the investigation of the geological bodies responsible for the Bouguer gravity minimum observed in this area.

  6. The geological, isotopic, botanical, invertebrate, and lower vertebrate contexts for aripithecus ramidus

    Energy Technology Data Exchange (ETDEWEB)

    Woldegabriel, Giday [Los Alamos National Laboratory; Ambrose, Stanley H [UNIV OF ILLINOIS; Barboni, Doris [CEREGE, FRANCE; Bonneffille, Raymond [CEREGE, FRANCE; Bremond, Laurent [MONTPELLIER, FRANCE; Currie, Brian [MIAMI UNIV, OXFORD, OHIO; Degusta, David [STANFORD UNIV.; Hart, William K [MIAMI UNIV, OXFORD, OHIO; Murray, Alison M [UNIV OF ALBERTA; Renne, Paul R [UC/BERKELEY; Jolly - Saad, M C [NANTERRE, FRANCE; Stewart, Kathlyn M [CANADA; White, Tim D [UC/BERKELEY

    2009-01-01

    Sediments containing Ardipithecus ramidus were deposited 4.4 million years ago on an alluvial floodplain in Ethiopia's western Afar rift. The Lower Aramis Member hominid-bearing unit, now exposed across a >9-kilometer structural arc, is sandwiched between two volcanic tuffs that have nearly identical {sup 40}Ar/{sup 39}Ar ages. Geological data presented here, along with floral, invertebrate, and vertebrate paleontological and taphonomic evidence associated with the hominids, suggest that they occupied a wooded biotope over the western three-fourths of the paleotransect. Phytoliths and oxygen and carbon stable isotopes of pedogenic carbonates provide evidence of humid cool woodlands with a grassy substrate.

  7. 238 series isotopes at different soil depths and disequilibrium over various geology and soil classifications along transects in selected parts of Ireland

    International Nuclear Information System (INIS)

    McAulay, I.R.; Hayes, A.

    1996-01-01

    Sampling of soils was carried out along linear transects in selected regions of the country, a technique known as Transect Sampling. This was a controlled rather than a random sampling technique. The transects were located in regions which were previously known to contain high levels of the 226 Ra isotope, from the 238 U series. The soil sampling was carried out at selected sites along these transects. At each transect site, two different soil depths were examined and the soil samples collected were identified as the top and bottom soil samples. This transect data set, consisting of the isotope activity levels and the influencing variables transect geology and soil types, provided a data base for investigation. Comparisons were made between the soil isotope activity levels measured at different soil depths. An examination of the 238 U decay series showed the existence of disequilibrium. Relationships between the disequilibrium data and the associated geology and soil types were investigated. (author)

  8. Isotopic coherence of refractory inclusions from CV and CK meteorites: Evidence from multiple isotope systems

    Science.gov (United States)

    Shollenberger, Quinn R.; Borg, Lars E.; Render, Jan; Ebert, Samuel; Bischoff, Addi; Russell, Sara S.; Brennecka, Gregory A.

    2018-05-01

    Calcium-aluminum-rich inclusions (CAIs) are the oldest dated materials in the Solar System and numerous previous studies have revealed nucleosynthetic anomalies relative to terrestrial rock standards in many isotopic systems. However, most of the isotopic data from CAIs has been limited to the Allende meteorite and a handful of other CV3 chondrites. To better constrain the isotopic composition of the CAI-forming region, we report the first Sr, Mo, Ba, Nd, and Sm isotopic compositions of two CAIs hosted in the CK3 desert meteorites NWA 4964 and NWA 6254 along with two CAIs from the CV3 desert meteorites NWA 6619 and NWA 6991. After consideration of neutron capture processes and the effects of hot-desert weathering, the Sr, Mo, Ba, Nd, and Sm stable isotopic compositions of the samples show clearly resolvable nucleosynthetic anomalies that are in agreement with previous results from Allende and other CV meteorites. The extent of neutron capture, as manifested by shifts in the observed 149Sm-150Sm isotopic composition of the CAIs is used to estimate the neutron fluence experienced by some of these samples and ranges from 8.40 × 1013 to 2.11 × 1015 n/cm2. Overall, regardless of CAI type or host meteorite, CAIs from CV and CK chondrites have similar nucleosynthetic anomalies within analytical uncertainty. We suggest the region that CV and CK CAIs formed was largely uniform with respect to Sr, Mo, Ba, Nd, and Sm isotopes when CAIs condensed and that CAIs hosted in CV and CK meteorites are derived from the same isotopic reservoir.

  9. About the variation mechanism of the isotopic composition of oxygen and carbon through the geological ages

    International Nuclear Information System (INIS)

    Torquato, J.R.F.; Frischkorn, H.

    1982-01-01

    The variations of the Δ 180 ratio found in the carbonates are shown as being of the primary origin. In addition it is shown that these values can be preserved, through the geological ages, even it one considers the carbonates to be worked over again. Are given some subsidies about the study of the paleoenvironments through the analysis of the isotopic composition of the carbon. (A.B.) [pt

  10. Basement configuration of KG offshore basin from magnetic anomalies

    Indian Academy of Sciences (India)

    of charnockites of neighbouring EGMB and onshore K–G basin areas indicates that EGMB geology. (charnockites ... Marine magnetic anomalies; offshore K–G basin; magnetic basement; extension of EGMB geology; continent– oceanic boundary. ..... of India; J. Australian Petroleum Exploration Association. 14 29–41.

  11. The precise measurement of TL isotopic compositions by MC-ICPMS: Application to the analysis of geological materials and meteorites.

    Science.gov (United States)

    Rehkämper, Mark; Halliday, Alex N.

    1999-07-01

    The precision of Tl isotopic measurements by thermal ionization mass spectrometry (TIMS) is severely limited by the fact that Tl possesses only two naturally occurring isotopes, such that there is no invariant isotope ratio that can be used to correct for instrumental mass discrimination. In this paper we describe new chemical and mass spectrometric techniques for the determination of Tl isotopic compositions at a level of precision hitherto unattained. Thallium is first separated from the geological matrix using a two-stage anion-exchange procedure. Thallium isotopic compositions are then determined by multiple-collector inductively coupled plasma-mass spectrometry with correction for mass discrimination using the known isotopic composition of Pb that is admixed to the sample solutions. With these procedures we achieve a precision of 0.01-0.02% for Tl isotope ratio measurements in geological samples and this is a factor of ≥3-4 better than the best published results by TIMS. However, without adequate precautions, experimental artifacts can be generated that result in apparent Tl isotopic fractionations of up to one per mil. Analysis of five terrestrial samples indicate the existence of Tl isotopic variations related to natural fractionation processes on the Earth. Two of the three igneous rocks analyzed in this study display Tl isotopic compositions indistinguishable from our laboratory standard, the reference material NIST-997 Tl. A third sample, however, is characterized by ɛ Tl ≈ 2.5 ± 1.5, where ɛ Tl represents the deviation of the 205Tl/ 203Tl ratio of the sample relative to NIST-997 Tl in parts per 10 4. Even larger deviations were identified for two ferromanganese crusts from the Pacific Ocean, which display ɛ Tl-values of +5.0 ± 1.5 and +11.7 ± 1.3. We suggest that the large variability of Tl isotopic compositions in the latter samples are caused by low-temperature processes related to the formation of the Fe-Mn crusts by precipitation and

  12. Stable Isotope Group 1982 progress report

    International Nuclear Information System (INIS)

    Stewart, M.K.

    1983-06-01

    The work of the Stable Isotope Group of the Institute of Nuclear Sciences during 1982, in the fields of isotope geology, isotope hydrology, geochronology, isotope biology and mass spectrometer instrumentation, is described

  13. Isotopic characterization of uranium in soils of the Ipanema National Forest (FLONA-Ipanema)

    International Nuclear Information System (INIS)

    Silva, F.B.; Marques, F.H.; Enzweiler, J.; Ladeira, F.S.B.

    2015-01-01

    The National Forest of Ipanema (FLONA) is situated on a geological anomaly, known as 'Domo de Aracoiaba'. The soils of the area include Oxisols, Inceptsols and Alfisols. The amount of uranium and respective isotope activities in a soil depend on the parental rock and on the pedologic processes. The aim of this study was to investigate the activities for uranium isotopes ("2"3"8U, "2"3"4U, "2"3"5U) and the activity ratio (AR) "2"3"4U/ "2"3"8U or secular equilibrium for different soil types of the area collected at horizons A and B. The amount of uranium showed no significant differences for soils generated from alkaline intrusive rocks and sandstone, however, secular equilibrium was observed for Oxisol (RA = 1), while Inceptsol presented RA> 1 and the other soils, Alfisols, presented RA values <1. (author)

  14. Stable Isotope Group 1983 progress report

    International Nuclear Information System (INIS)

    Stewart, M.K.

    1984-06-01

    The work of the Stable Isotope Group of the Institute of Nuclear Sciences in the fields of isotope geology, isotope hydrology, geochronology, isotope biology and related fields, and mass spectrometer instrumentation, during 1983, is described

  15. Exploration of geomagnetic field anomaly with balloon for geophysical research

    Science.gov (United States)

    Jia, Wen-Kui

    The use of a balloon to explore the geomagnetic field anomaly in the area east of Beijing is demonstrated. The present results are compared with those of aerial surveys. Descriptions are given of the fluxgate magnetometer, the sensor's attitude control and measurement, and data transmission and processing. At an altitude of about 30 km, a positive anomaly of the vertical component of about 100 nanoteslas was measured. The results suggest that, for this particular area, the shallow layer of a small-scale geological structure differs from the deep layer of a large-scale geological structure.

  16. Compilation of the Dakota Aquifer Project isotope data and publications: The Isotope Hydrology Program of the Isotope Sciences Division

    International Nuclear Information System (INIS)

    Davisson, M.L.; Smith, D.K.; Hudson, G.B.; Niemeyer, S.; Macfarlane, P.A.; Whittemore, D.O.

    1995-01-01

    In FY92 the then Nuclear Chemistry Division embarked on a scientific collaboration with the Kansas Geological Survey (KGS) to characterize with isotope techniques groundwater of the Dakota Formation of Kansas. The Dakota Formation is a Cretaceous-aged marine sandstone hosting potable groundwater in most regions of Kansas whose use will serve to partially offset the severe overdraft problems in the overlying Ogallala Formation. The isotope characterization of the Dakota groundwater has generated data that delineates sources, ages, and subsurface controls on the water quality. Initial interpretations of the data have been published in abstract volumes of (1) the 1993 Geological Society of America National Meeting, (2) the 8th International Conference on Geochronology, Cosmochronology and Isotope Geology, and (3) the 1994 Dakota Aquifer Workshop and Clinic. Copies of all abstracts are included in this brief review. One report will focus on the sources and ages of the groundwater, and the other will focus on the subsurface controls on the natural water quality

  17. Geological history of uranium

    International Nuclear Information System (INIS)

    Niini, Heikki

    1989-01-01

    Uranium is widely distributed in continental geological environments. The order of magnitude of uranium abundance in felsitic igneous rocks is 2-15 ppm, whereas it is less than 1 ppm in mafic rocks. Sedimentary rocks show a large range: from less than 0.1 ppm U in certain evaporites to over 100 ppm in phosphate rocks and organogenic matter. The content of U in seawater varies from 0.0005 to 0.005 ppm. The isotopic ratio U-238/U-235 is presently 137.5+-0.5, having gradually increased during geological time. The third natural isotope is U-234. On the basis of three fundamental economic criteria for ore reserves assessment (geological assurance, technical feasibility, and the grade and quantity of the deposits), the author finally comes to the following conclusions: Although the global uranium ores are not geologically renewable but continuously mined, they still, due to exploration and technical development, will tend to progressively increase for centuries to come

  18. Anthropogenic influences on Pb/Al and lead isotope signature in annually layered Holocene Maar lake sediments

    International Nuclear Information System (INIS)

    Schettler, G.; Romer, R.L.

    1998-01-01

    Annually laminated sediments from two Maar lakes in the West Eifel volcanic field (Germany) show anomalously high Pb within sections deposited during the first centuries A.D. exceeding the local geological background 8.5-fold in Lake Meerfelder Maar (MFM) and 4-fold in Lake Schalkenmehrener Maar (SMM). These Pb anomalies are associated with a distinct shift in the Pb isotope signature to less radiogenic compositions. The excess Pb causing the anomaly has the same isotopic composition as galena deposits 60 km to the NW of the Maar lakes. It is suggested that this component was transported airborne into the Maar lakes and originates from regional Roman Pb refinement and cupellation of argentiferous Pb. Varve chronostratigraphy of correlated cores indicates that significant Roman Pb input lasted for about 230 a. SMM does not get fluviatile input. Its sedimentary record is more sensitive to variations in airborne input than that of MFM, which had an inflow. SMM sediment sections deposited during periods of low soil erosion (early Holocene, Dark Ages) with comparably high Pb/Al values also show little radiogenic Pb. This is caused by airborne minerogenic matter from a geochemically and isotopically distinct remote source that becomes apparent only in sedimentation periods of very restricted local allochthonous input. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

  19. Geology Of Wadi Sidri Radioactive Ocurrences, Western Sinai, Egypt

    OpenAIRE

    El Kassas, I. A. [ابراهيم علي القصاص

    1995-01-01

    Geologic and radiomclric investigations have been carried out in the environs of Wadi Sidri in Western Sinai, applying a combination of various geological, geophysical and gcochcmical techniques. This work revealed the presence of some radioactive anomalies of various intensities, extensions and origin, associated with different rock types. The discovered anomalies arc classified into two main groups of quite different types but they seem to be genetically related to each other. The first typ...

  20. Trace uranium analysis in geological sample by isotope dilution-alpha spectrometry and comparison with other techniques

    International Nuclear Information System (INIS)

    Shihomatsu, H.M.; Iyer, S.S.

    1988-12-01

    Establishment of uranium determination in geological samples by alpha spectrometric isotope dilution technique using 233 U tracer is described in the present work. The various steps involved in the method namely, preparation of the sample, electrodeposition, alpha spectrometry, isotope dilution, calculation of the concentration and error statistics are discussed in detail. The experimental parameters for the electrodeposition of uranium, like current density, pH concentration of the electrolyte solution, deposition time, electrode distance were all optimised based on the efficiency of the deposition. The total accuracy and precision of the IDAS using 233 U tracer in the determination of uranium in mineral and granite samples were of the order of 1 to 2% for the concentration range of 50-1500 ppm of U. Our results are compared with those obtained by others workers using similar and different techniques. (author) [pt

  1. Regional magnetic anomaly constraints on continental rifting

    Science.gov (United States)

    Vonfrese, R. R. B.; Hinze, W. J.; Olivier, R.; Bentley, C. R.

    1985-01-01

    Radially polarized MAGSAT anomalies of North and South America, Europe, Africa, India, Australia and Antarctica demonstrate remarkably detailed correlation of regional magnetic lithospheric sources across rifted margins when plotted on a reconstruction of Pangea. These major magnetic features apparently preserve their integrity until a superimposed metamorphoric event alters the magnitude and pattern of the anomalies. The longevity of continental scale magnetic anomalies contrasts markedly with that of regional gravity anomalies which tend to reflect predominantly isostatic adjustments associated with neo-tectonism. First observed as a result of NASA's magnetic satellite programs, these anomalies provide new and fundamental constraints on the geologic evolution and dynamics of the continents and oceans. Accordingly, satellite magnetic observations provide a further tool for investigating continental drift to compliment other lines of evidence in paleoclimatology, paleontology, paleomagnetism, and studies of the radiometric ages and geometric fit of the continents.

  2. Investigation of the anomalous isotope ratios of the Central-Transdanubian bauxites

    International Nuclear Information System (INIS)

    Viczian, M.

    1977-01-01

    In the case of the Central Transdanubian bauxite deposits significant anomaly of the lead isotope ratios has been found. The 206 Pb/ 204 Pb isotope ratio in approximately 40 samples was investigated and the results have shown an average deviation from the literary value by about 80%. These results have been cont confirmed by thermal ionisation measurings, too. Some possibilities for the explanation of this isotope anomaly are also dealt with in the paper. (author)

  3. Anomalous isotope effects in the U(IV)-U(VI) exchange system

    International Nuclear Information System (INIS)

    Fujii, Yasuhiko; Nomura, Masao; Okamoto, Makoto; Onitsuka, Hatsuki; Nakanishi, Takashi.

    1992-01-01

    In previous papers, the enrichment of 236 U in the U(IV) - U(VI) chemical exchange system was found to be significantly smaller than the value estimated by the normal mass dependence enrichment of 235 U. Further experiments have been carried out in the present work to confirm the strange phenomenon of the isotopic anomaly in uranium enrichment. The results have indicated that the separation coefficient of 236 U is the same value as one previously reported. To confirm the anomaly of uranium isotope separation, α-ray spectrometry was implemented to check the enrichment behavior of 234 U. Although no theoretical explanation is given for the isotopic anomaly, this is favorable phenomenon for the re-enrichment of recycled uranium which contains isotopes 232 U and 236 U. (author)

  4. Statistical treatment of geochemical data and its application in the geologic mapping and in the definition of the geochemical anomalies in the Alvo 2-Corpo 4 -Provincia Mineral de Carajas

    International Nuclear Information System (INIS)

    Moura, C.A.V.

    1982-01-01

    It was given a statistical treatment for the geochemical data about soil in the are named Alvo2 - Corpo4- in the Provincia Mineral de Carajas, Para, Brazil, for application of the geological mapping and definition of geochemical anomalies. (A.B.) [pt

  5. Osmotic generation of 'anomalous' fluid pressures in geological environments

    Science.gov (United States)

    Neuzii, C.E.

    2000-01-01

    Osmotic pressures are generated by differences in chemical potential of a solution across a membrane. But whether osmosis can have a significant effect on the pressure of fluids in geological environments has been controversial, because the membrane properties of geological media are poorly understood. 'Anomalous' pressures - large departures from hydrostatic pressure that are not explicable in terms of topographic or fluid-density effects are widely found in geological settings, and are commonly considered to result from processes that alter the pore or fluid volume, which in turn implies crustal changes happening at a rate too slow to observe directly. Yet if osmosis can explain some anomalies, there is no need to invoke such dynamic geological processes in those cases. Here I report results of a nine- year in situ measurement of fluid pressures and solute concentrations in shale that are consistent with the generation of large (up to 20 MPa) osmotic-pressure anomalies which could persist for tens of millions of years. Osmotic pressures of this magnitude and duration can explain many of the pressure anomalies observed in geological settings. The require, however, small shale porosity and large contrasts in the amount of dissolved solids in the pore waters - criteria that may help to distinguish between osmotic and crystal-dynamic origins of anomalous pressures.

  6. Platinum stable isotope analysis of geological standard reference materials by double-spike MC-ICPMS.

    Science.gov (United States)

    Creech, J B; Baker, J A; Handler, M R; Bizzarro, M

    2014-01-10

    We report a method for the chemical purification of Pt from geological materials by ion-exchange chromatography for subsequent Pt stable isotope analysis by multiple-collector inductively coupled plasma mass spectrometry (MC-ICPMS) using a 196 Pt- 198 Pt double-spike to correct for instrumental mass bias. Double-spiking of samples was carried out prior to digestion and chemical separation to correct for any mass-dependent fractionation that may occur due to incomplete recovery of Pt. Samples were digested using a NiS fire assay method, which pre-concentrates Pt into a metallic bead that is readily dissolved in acid in preparation for anion-exchange chemistry. Pt was recovered from anion-exchange resin in concentrated HNO 3 acid after elution of matrix elements, including the other platinum group elements (PGE), in dilute HCl and HNO 3 acids. The separation method has been calibrated using a precious metal standard solution doped with a range of synthetic matrices and results in Pt yields of ≥90% with purity of ≥95%. Using this chemical separation technique, we have separated Pt from 11 international geological standard reference materials comprising of PGE ores, mantle rocks, igneous rocks and one sample from the Cretaceous-Paleogene boundary layer. Pt concentrations in these samples range from ca. 5 ng g -1 to 4 μg g -1 . This analytical method has been shown to have an external reproducibility on δ 198 Pt (permil difference in the 198 Pt/ 194 Pt ratio from the IRMM-010 standard) of ±0.040 (2 sd) on Pt solution standards (Creech et al., 2013, J. Anal. At. Spectrom. 28, 853-865). The reproducibility in natural samples is evaluated by processing multiple replicates of four standard reference materials, and is conservatively taken to be ca. ±0.088 (2 sd). Pt stable isotope data for the full set of reference materials have a range of δ 198 Pt values with offsets of up to 0.4‰ from the IRMM-010 standard, which are readily resolved with this technique. These

  7. Post-GOE redox insights from Mo isotopes, Ce anomalies, and Mn from the 2.24 Ga Kazput Formation

    Science.gov (United States)

    Thoby, M.; Konhauser, K.; Philippot, P.; Killingsworth, B.; Warchola, T.; Lalonde, S.

    2017-12-01

    Following the Great Oxidation event (GOE) defined from 2.45 to 2.2 Ga, an event marking the first appearance of widespread atmospheric oxygen, a combination of decreased Mn(II) supply from land and increased Mn(IV)-precipitation in the oceans should have resulted in lower concentrations of Mn in seawater. Nevertheless, it appears that some early Proterozoic marine sediments record high seawater Mn concentrations hundreds of millions of years after the GOE. Here we investigate a Mn excursion associated with marine carbonates and shales of the 2.31 Ga Kazput Formation. Samples were recovered from drill core collected during the Turee Creek Drilling Project (TCDP). Using molybdenum (Mo) isotope data coupled with cerium (Ce) anomalies, we define the redox condition of the Kazput depositional environment. Initial results show no Mo fractionation and few cerium anomalies in carbonates, pointing to an anoxic basin without Mn oxide precipitates. Additionally, XRF data on the shales indicates an association of Mn with calcium (Ca) suggesting an anoxic environment at the time of their deposition. Our results provide new insights into the nature and environment of the Turee Creek basin and the extent of oxygenation of surface waters after the GOE.

  8. Magnetic anomalies of offshore Krishna–Godavari basin, eastern continental margin of India

    Digital Repository Service at National Institute of Oceanography (India)

    Swamy, K.V.; Murthy, I.V.R.; Krishna, K.S.; Murthy, K.S.R.; Subrahmanyam, A.S.; Rao, M.M.M.

    with the volcanic material. Inversion of the magnetic and gravity anomalies was also carried out to establish the similarity of anomalies of the two geological features (structural high on the margin and the 85 degrees E Ridge) and their interpretations. In both...

  9. Deep Mantle Origin for the DUPAL Anomaly?

    Science.gov (United States)

    Ingle, S.; Weis, D.

    2002-12-01

    Twenty years after the discovery of the Dupal Anomaly, its origin remains a geochemical and geophysical enigma. This anomaly is associated with the Southern Hemisphere oceanic mantle and is recognized by basalts with geochemical characteristics such as low 206Pb/204Pb and high 87Sr/86Sr. Both mid-ocean ridge basalts (MORB) and ocean island basalts (OIB) are affected, despite originating from melting at different depths and of different mantle sources. We compile geochemical data for both MORB and OIB from the three major oceans to help constrain the physical distribution and chemical composition of the Dupal Anomaly. There is a clear decrease in 206Pb/204Pb and an increase in 87Sr/86Sr with more southerly latitude for Indian MORB and OIB; these correlations are less obvious in the Atlantic and non-existent in the Pacific. The average* 143Nd/144Nd for Pacific and Atlantic OIB is 0.5129, but is lower for Indian OIB (0.5128). Interestingly, Pacific, Atlantic and Indian OIB all have 176Hf/177Hf averages of 0.2830. Indian MORB also record this phenomenon of low Nd with normal Hf isotopic compositions (Chauvel and Blichert-Toft, EPSL, 2001). Hf isotopes appear, therefore, to be a valid isotopic proxy for measuring the presence and magnitude of the Dupal Anomaly at specific locations. Wen (EPSL, 2001) reported a low-velocity layer at the D'' boundary beneath the Indian Ocean from which the Dupal Anomaly may originate. This hypothesis may be consistent with our compilations demonstrating that the long-lived Dupal Anomaly does not appear to be either mixing efficiently into the upper mantle or spreading to other ocean basins through time. We suggest that the Dupal source could be continually tapped by upwelling Indian Ocean mantle plumes. Plumes would then emplace pockets of Dupal material into the upper mantle and other ascending plumes might further disperse this material into the shallow asthenosphere. This could explain both the presence of the Dupal signature in MORB

  10. New Isotopic clues to solar system formation

    International Nuclear Information System (INIS)

    Lee, T.

    1979-01-01

    The presence of two new extinct nuclides 26 Al and 107 Pd with half-lives approx.10 6 years in the early solar system implies that there were nucleosynthetic activities involving a great many elements almost at the instant of solar system formation. Rare gas and oxygen isotopic abundance variations [''anomalies''] relative to the ''cosmic'' composition were observed in a variety of planetary objects indicating that isotopic heterogeneities caused by the incomplete mixing of distinct nucleosynthetic components permeate of the entire solar system. The correlated nuclear [''FUN''] anomalies in O, Mg, Si, Ca, Sr, Ba, Nd, and Sm were found in three rare inclusions in the Allende meteorite, which show large mass-dependent isotopic fractionation effects. The signature of the nuclear component required to explain these anomalies suggests a source which has received a catastrophic neutron burst [e.g., an r-process event]. These extinct nuclides and nucleosynthetic anomalies provide new clues to solar system formation. In particular, these results have led to the speculation that a nearby supernova had injected freshly synthesized material into the early solar nebula and possibly triggered the collapse of the proto-solar interstellar cloud. Furthermore, these new results have major implications on cosmochronology, nucleosynthesis theory, star formation, planetary heating, and the genetic relationship between different planetary bodies

  11. Stable Isotope Systematics of Martian Perchlorate

    Science.gov (United States)

    Martin, P.; Farley, K. A.; Archer, D., Jr.; Atreya, S. K.; Conrad, P. G.; Eigenbrode, J. L.; Fairen, A.; Franz, H. B.; Freissinet, C.; Glavin, D. P.; Mahaffy, P. R.; Malespin, C.; Ming, D. W.; Navarro-Gonzalez, R.; Sutter, B.

    2015-12-01

    Chlorine isotopic compositions in HCl released during evolved gas analysis (EGA) runs have been detected by the Sample Analysis at Mars (SAM) instrument on the Curiosity rover ranging from approximately -9‰ to -50‰ δ37Cl, with two spatially and isotopically separated groups of samples averaging -15‰ and -45‰. These extremely low values are the first such detection of any known natural material; common terrestrial values very rarely exceed ±5‰, and the most extreme isotopic signature yet detected elsewhere in the solar system are values of around +24‰ on the Moon. The only other known location in the solar system with large negative chlorine isotopes is the Atacama Desert, where perchlorate with -14‰ δ37Cl has been detected. The Atacama perchlorate has unusual Δ17O signatures associated with it, indicating a formation mechanism involving O3, which suggests an atmospheric origin of the perchlorate and associated large isotopic anomalies. Identification of non-zero positive Δ17O signatures in the O2 released during EGA runs would allow definitive evidence for a similar process having occurred on Mars. Perchlorate is thought to be the most likely source of HCl in EGA runs due to the simultaneous onset of O2 release. If perchlorate is indeed the HCl source, atmospheric chemistry could be responsible for the observed isotopic anomalies, with variable extents of perchlorate production producing the isotopic variability. However, chloride salts have also been observed to release HCl upon heating; if the timing of O2 release is merely coincidental, observed HCl could be coming from chlorides. At thermodynamic equilibrium, the fractionation factor of perchlorate reduction is 0.93, meaning that differing amounts of post-deposition reduction of isotopically normal perchlorate to chloride could account for the highly variable Cl isotopes. Additionally, post-deposition reduction could account for the difference between the two Cl isotopic groups if perchlorate

  12. Review report about Puntas de Mataojo anomalies area

    International Nuclear Information System (INIS)

    Rossi, P.

    1987-01-01

    Puntas de Mataojo anomalies have been reviewed during 1986 in Maldonado and Lavalleja Province, Las Animas photo map. A pedestrian radiometric, geochemical samples and geological definition were developed as a main goals in this study

  13. Automatic program for the interpretation of two-dimensional gravity and magnetic anomalies

    International Nuclear Information System (INIS)

    Wagini, A.

    1985-01-01

    This automatic inversion program for the interpretation of two-dimensional gravity and magnetic anomalies has been developed mainly in support of the US Geological Survey's effort to characterize potential radioactive-waste storage sites at the Nevada Test Site, Nevada. Determining subsurface shapes and extensions of geologic bodies necessitates extensive modeling of magnetic and gravity data. Geologic models for the source of magnetic or gravity anomalies are often developed by trial and error: an approximation is made to establish an initial model, the anomaly due to the model is calculated and compared with the observed anomaly, and the model is iteratively modified to improve the agreement between calculated and observed anomalies. The method presented is not a least-squares method like other methods developed during the last few years, but minimizes the sum of the squares of the residuals by varying only one variable (coordinate) at a time. Varying one variable at a time allows one to use all available information in the model calculation, which can essentially reduce the computation time. The objective of this program is to find the shape of geologic bodies when the physical parameters are known. Except for the outermost corners, only the z-coordinate of each corner-point is varied. The variation of only one variable at a time has the advantage that a large number of bodies and corner-points (in this program up to 50 bodies, each with up to 50 corner-points) can be used for the model calculation without solving a large matrix. This can be important, especially for smaller computers. The program is written in ANSI Standard FORTRAN 77 and is interactive; thus it requires little knowledge of the computer system and its editing facilities. 5 refs

  14. Report on the geological-geochemical research carried out within the area of geochemical anomaly P7, Vathyrema, Drama Department

    International Nuclear Information System (INIS)

    Stavropoulos, Athanasios.

    1982-08-01

    The investigated area covering about 30 km 2 is situated in the crystalline massive of Rhodope (north of Drama deparment, E. Macedonia) where granitoids constitute its main petrological type. The geological-geochemical and radiometric investigations carried out so far in the area have localized a large number of places with high values of γ-radiation (1.000 - 15.000 c/s), as well as high concentrations of uranium (50-500 ppm). The uranium mineralization within the zone of oxidation is expressed by the uranium mineral autunite, accompanied by intensive hematitization-limonitization and chloritization-kaolinization, and additionally by small spots and veinlets of pyrite and galena. It seems that tectonic control exists on the uranium mineralization, since most of the anomalous concentrations of uranium are sitting along mylonite zones rich in chlorite and kaolin. There have been discerned seven more anomalous part areas which will have to be covered by geochemical stream sediment sampling (phase 3), as well as geological mapping (scale 1:5.000). The results from the research conducted within the concerned anomaly lead us to the conclusion that this area is very promising and possibilities of localization of uranium payable concentrations are very high. (N.Ch.)

  15. Geology, mineralization, U-Pb dating and Sr-Nd isotope geochemistry of intrusive bodies in northeast of Kashmar

    Directory of Open Access Journals (Sweden)

    Alireza Almasi

    2015-04-01

    Full Text Available Alireza Almasi1, Mohammad Hassan Karimpour1*, Khosrow Ebrahimi Nasrabadi1, Behnam Rahimi1, Urs KlÖtzli2 and Jose Francisco Santos3 Introduction The study area is located in central part of the Khaf- Kashmar-Bardeskan belt which is volcano-plutonic belt at the north of the Dorouneh fault in the north of Lut block. The north of the Lut block is affected by tectonic rotation and subduction processes which occur in the east of Iran (Tirrul et al., 1983. The magmatism of Lut block begins in Jurassic and continues in Tertiary (Aghanabati, 1995. Karimpour (Karimpour, 2006 pointed out the Khaf-Kashmar-Bardeskan belt has significant potential for IOCG type mineralization such as Kuh-e-Zar, Tannurjeh, and Sangan (Karimpour, 2006; Mazloumi, 2009. The data gathered on the I-type intrusive rocks include their field geology, petrography, U–Pb zircon dating and Sr–Nd isotope and also alteration and mineralization in the study area. Materials and methods - Preparation of 150 thin sections of rock samples for study of petrography and alteration of the intrusive rocks. - Magnetic susceptibility measuring of intrusive rocks. - U-Pb dating in zircon of I-type intrusive rocks by Laser-Ablation Multi Collector ICP-MS method. - Sr-Nd analysis on 5 samples of I-type intrusive rocks by Multi-Collector Thermal Ionization Mass Spectrometer (TIMS VG Sector 54 instrument. - Mineralography and paragenetic studies of ore-bearing quartz veins and geochemical analysis for 28 samples. - Production of the geology, alteration and mineralization maps by scale: 1:20000 in GIS. Results Oblique subduction in southern America initiated an arc-parallel fault and shear zones in the back of continental magmatic arc (Sillitoe, 2003. Because of this event, pull-apart basins were formed and high-K to shoshonitic calc-alkalineI- and A-type magmatism occur (Sillitoe, 2003. Most important deposits accompany with this magmatism are Au-Cu deposits types and Fe-Skarns (Sillitoe, 2003. We have

  16. Tales of volcanoes and El-Nino southern oscillations with the oxygen isotope anomaly of sulfate aerosol.

    Science.gov (United States)

    Shaheen, Robina; Abauanza, Mariana; Jackson, Teresa L; McCabe, Justin; Savarino, Joel; Thiemens, Mark H

    2013-10-29

    The ability of sulfate aerosols to reflect solar radiation and simultaneously act as cloud condensation nuclei renders them central players in the global climate system. The oxidation of S(IV) compounds and their transport as stable S(VI) in the Earth's system are intricately linked to planetary scale processes, and precise characterization of the overall process requires a detailed understanding of the linkage between climate dynamics and the chemistry leading to the product sulfate. This paper reports a high-resolution, 22-y (1980-2002) record of the oxygen-triple isotopic composition of sulfate (SO4) aerosols retrieved from a snow pit at the South Pole. Observed variation in the O-isotopic anomaly of SO4 aerosol is linked to the ozone variation in the tropical upper troposphere/lower stratosphere via the Ozone El-Niño Southern Oscillations (ENSO) Index (OEI). Higher (17)O values (3.3‰, 4.5‰, and 4.2‰) were observed during the three largest ENSO events of the past 2 decades. Volcanic events inject significant quantities of SO4 aerosol into the stratosphere, which are known to affect ENSO strength by modulating stratospheric ozone levels (OEI = 6 and (17)O = 3.3‰, OEI = 11 and (17)O = 4.5‰) and normal oxidative pathways. Our high-resolution data indicated that (17)O of sulfate aerosols can record extreme phases of naturally occurring climate cycles, such as ENSOs, which couple variations in the ozone levels in the atmosphere and the hydrosphere via temperature driven changes in relative humidity levels. A longer term, higher resolution oxygen-triple isotope analysis of sulfate aerosols from ice cores, encompassing more ENSO periods, is required to reconstruct paleo-ENSO events and paleotropical ozone variations.

  17. Nd and Sr isotopes: implications of provenance and geological mapping; Isotopos de Nd e Sr: implicacoes de proveniencia e mapeamento geologico

    Energy Technology Data Exchange (ETDEWEB)

    Albuquerque, Marcio Fernando dos Santos; Horbe, Adriana Maria Coimbra; Dantas, Elton Luiz, E-mail: mgeoroots@gmail.com, E-mail: ahorbe@unb.br, E-mail: elton@unb.br [Universidade de Brasilia (UnB), DF (Brazil). Instituto de Geociencias

    2015-07-01

    XRD, Nd and Sr isotopes, major, minor and traces elements quantification were applied to rocks, lateritic crusts and soils from Sumauma Supergroup and Alto Tapajos Group, in order to indicate provenance of the rocks and using lateritic products as geologic mapping tool. For the rocks, the results showed sources related to provinces Tapajos Parima, Rondonia Juruena, Sunsas, Carajas and Amazonia Central. However, the incision of Cachimbo graben allowed which the Sumauma Supergroup erosion also were source for the Alto Tapajos Group, allied to contribution of volcanics from Colider Group. Lateritic crusts and soils are correlates to bedrocks, allowing the use as geologic mapping tool. (author)

  18. Thermal infrared anomalies of several strong earthquakes.

    Science.gov (United States)

    Wei, Congxin; Zhang, Yuansheng; Guo, Xiao; Hui, Shaoxing; Qin, Manzhong; Zhang, Ying

    2013-01-01

    In the history of earthquake thermal infrared research, it is undeniable that before and after strong earthquakes there are significant thermal infrared anomalies which have been interpreted as preseismic precursor in earthquake prediction and forecasting. In this paper, we studied the characteristics of thermal radiation observed before and after the 8 great earthquakes with magnitude up to Ms7.0 by using the satellite infrared remote sensing information. We used new types of data and method to extract the useful anomaly information. Based on the analyses of 8 earthquakes, we got the results as follows. (1) There are significant thermal radiation anomalies before and after earthquakes for all cases. The overall performance of anomalies includes two main stages: expanding first and narrowing later. We easily extracted and identified such seismic anomalies by method of "time-frequency relative power spectrum." (2) There exist evident and different characteristic periods and magnitudes of thermal abnormal radiation for each case. (3) Thermal radiation anomalies are closely related to the geological structure. (4) Thermal radiation has obvious characteristics in abnormal duration, range, and morphology. In summary, we should be sure that earthquake thermal infrared anomalies as useful earthquake precursor can be used in earthquake prediction and forecasting.

  19. Determination of marble provenance: limits of isotopic analysis

    International Nuclear Information System (INIS)

    Germann, K.; Holzmann, G.; Winkler, F.J.

    1980-01-01

    Provenance determination of Thessalian stelae marbles using the C/O isotopic analysis proved to be misleading, as the isotopic composition even in very small quarrying areas is heterogeneous and isotopic coincidence of marbles from very distant sources occurs. Therefore additional geological features must be taken into consideration and preference should be given to combinations of both petrographical and geochemical properties. Geological field work to establish the range of possible marble sources and the variability within these sources is one of the prerequisites of provenance studies. (author)

  20. Ubiquitous isotopic anomalies in Ti from normal Allende inclusions

    International Nuclear Information System (INIS)

    Niemeyer, S.; Lugmair, G.W.

    1981-01-01

    A newly developed technique for high-precision isotopic analyses of titanium was applied to terrestrial rocks and course- and fine-grained Allende inclusions. Repeated analyses of three terrestrial rocks gave excellent agreement (usually less than 2 x 10 -4 deviations) with a Ti metal standard. All seven Allende inclusions studied here were previously determined to contain isotopically normal Nd and/or Sm, indicating that none belongs to a small group of peculiar inclusions, dubbed as FUN inclusions. (orig./ME)

  1. Calcium and titanium isotopes in refractory inclusions from CM, CO, and CR chondrites

    Science.gov (United States)

    Kööp, Levke; Davis, Andrew M.; Krot, Alexander N.; Nagashima, Kazuhide; Simon, Steven B.

    2018-05-01

    Previous studies have shown that CV and CM chondrites incorporated Ca, Al-rich inclusions (CAIs) with different isotopic characteristics, which may represent different snapshots in the isotopic evolution of the early Solar System. To better understand how the isotopic characteristics of CAIs vary between different chondrite groups, we have studied calcium and titanium isotopes in CAIs from CM, CO, and CR chondrites. We show that all three chondrite groups contain CAIs with large anomalies in 48Ca and/or 50Ti (10s of ‰ or 100s of ε-units) as well as CAIs with no anomalies resolved beyond measurement uncertainties. Isotopically, the anomalous CO and CR chondrite CAIs resemble the platy hibonite crystals (PLACs) from CM chondrites, but they are more mineralogically complex. The new data are consistent with the well-established mutual exclusivity relationship between incorporation of 26Al and the presence of large anomalies in 48Ca and 50Ti. The two highly anomalous CO chondrite CAIs have correlated anomalies in 46Ti and 50Ti, while most other highly anomalous CAIs do not. This result could indicate that the reservoir with coupled 46Ti and 50Ti that was sampled by bulk meteorites and CV chondrite CAIs already existed before arrival and/or homogeneous distribution of 26Al in the protoplanetary disk. Among the studied CM chondrite CAIs are ten spinel-hibonite inclusions (SHIBs) with known oxygen isotopic compositions. Our results show that these objects sampled a reservoir that was well-mixed in oxygen, calcium, and titanium isotopes. We further show that SHIBs tend to be slightly enriched in the heavy calcium isotopes, suggesting that their formation history was different from CV chondrite CAIs.

  2. Mercury stable isotope fractionation in a tropical ecosystem including human hair: New insights for an isotope balance

    Science.gov (United States)

    Laffont, Laure; Sonke, Jeroen; Maurice, Laurence; Behra, Philippe

    2010-05-01

    Mercury contamination is an environmental problem in the Amazon basin still relevant today as impacts on human health are poorly studied. In Bolivia, indigenous people have elevated methylmercury concentrations (between 2719 and 23701 ng.g-1) in their hair. This highly toxic molecule is formed after methylation of inorganic Hg released by chemical and physical weathering and from human activities. The aim of our study is to propose a first isotope balance in a Bolivian Amazon ecosystem, through variations in Hg isotopic compositions. The discovery of mass-independent fracionation (MIF) of odd-isotopes in our organic samples (fish and human hair) opened a new way of research in tracing the sources and the processes involved in the cycle of Hg. Four types of samples are studied: liquid Hg0 from gold mining, sediment samples, fish coming from the Beni River basin (from the main channel and an associated floodplain lake) and hair from gold miners and fish-eating native populations. Hg isotopic compositions were analyzed on a Thermo-Finnigan Neptune MC-ICP-MS at the LMTG after sample digestion by HCl/HNO3 or by H2O2/HNO3 for fish samples, at 120°C. The δ202Hg values (relative to NIST 3133) are signicantly different with respect to the external precision on UM-Almaden#2 of 0.18 ‰ (2σ, n = 42): -0.34 ± 0.02 ‰ for liquid mercury, between -1.33 and -0.81 ‰ for bottom and floodplain sediments (n=18), between -0.87 and 2.22 ‰ for miners hair (n=26), +1.29 ± 0.41 ‰ for native hair (n=13) and between -0.91 and -0.21 ‰ for fish samples (n=53). A large mass-independent isotope fractionation (MIF) was observed for odd isotope ratios in all hair samples and fish samples whereas weak anomalies were measured for sediment samples: - ∆199Hg anomaly: -0.12 to -0.04 ‰ for sediment, -0.22 to +0.63 ‰ for fish samples and +0.13 to +1.63 ‰ for hair - ∆201Hg anomaly: -0.12 to -0.02 ‰ for sediment, -0.21 to +0.43 ‰ for fish samples and +0.06 to +1.25 ‰ for hair

  3. Correlated O and Mg isotopic anomalies in Allende inclusions: II. Magnesium

    International Nuclear Information System (INIS)

    Wasserburg, G.J.; Lee, T.; Papanastassiou, D.A.

    1977-01-01

    Mg in two Allende Ca-Al rich inclusions shows large isotopic, mass-dependent fractionation which enriched the heavier isotopes. After normalization, Mg in these inclusions shows negative delta 26 Mg which appears to require the presence of nuclear effects in Mg distinct from 26 Al decay. The Mg mass fractionation is correlated with distinct but smaller fractionation effects for O reported by Clayton and Mayeda for the same inclusions (see companion paper). The observation of distinctive but uniform Mg isotopic composition in different phases within single Allende inclusions indicates that nuclear effects in O and Mg are not due to the entrapment of interstellar carrier grains as discrete entities, which are preserved as remnants, but are instead due to a homogenized mixture of components of extraordinary isotopic composition mixed with a component of ordinary solar system material and subjected to isotopic fractionation. The distinct O isotopic composition of different phases within a single inclusion is believed to be due to incomplete back-reaction of the higher temperature condensates with a cooler solar nebula of ''normal '' composition. The processes responsible for the O and Mg nuclear effects and the astrophysical site of their occurrence remain undefined

  4. Stable isotope geochemistry. 3. rev. and enl. ed.

    International Nuclear Information System (INIS)

    Hoefs, J.

    1987-01-01

    Stable Isotope Geochemistry is an authoritative book comprising theoretical and experimental principles; surveying important fractionation mechanisms affecting the most important elements; discussing the natural variations of geologically important reservoirs. This updated 3rd edition, with a completely rewritten and extended main part, contains two new chapters on stable isotope composition of mantle material and on changes of the ocean during the geological past. (orig.)

  5. Isotopes in day to day life

    Science.gov (United States)

    1984-06-01

    Developments are reported in the use of isotopic labeling and isotope irradiation in agriculture, medical science, hydrology, geochemistry, geophysics, environment pollution detection, and industries. Radioisotope instruments are described as well as techniques for gamma radiography, neutron radiography, and autoradiography. Isotope dating in geology and archaeology is covered. Basic scientific research topics in various areas are listed.

  6. Isotopic homogeneity of iron in the early solar nebula.

    Science.gov (United States)

    Zhu, X K; Guo, Y; O'Nions, R K; Young, E D; Ash, R D

    2001-07-19

    The chemical and isotopic homogeneity of the early solar nebula, and the processes producing fractionation during its evolution, are central issues of cosmochemistry. Studies of the relative abundance variations of three or more isotopes of an element can in principle determine if the initial reservoir of material was a homogeneous mixture or if it contained several distinct sources of precursor material. For example, widespread anomalies observed in the oxygen isotopes of meteorites have been interpreted as resulting from the mixing of a solid phase that was enriched in 16O with a gas phase in which 16O was depleted, or as an isotopic 'memory' of Galactic evolution. In either case, these anomalies are regarded as strong evidence that the early solar nebula was not initially homogeneous. Here we present measurements of the relative abundances of three iron isotopes in meteoritic and terrestrial samples. We show that significant variations of iron isotopes exist in both terrestrial and extraterrestrial materials. But when plotted in a three-isotope diagram, all of the data for these Solar System materials fall on a single mass-fractionation line, showing that homogenization of iron isotopes occurred in the solar nebula before both planetesimal accretion and chondrule formation.

  7. Reports on investigations of uranium anomalies. National Uranium Resource Evaluation

    International Nuclear Information System (INIS)

    Goodknight, C.S.; Burger, J.A.

    1982-10-01

    During the National Uranium Resource Evaluation (NURE) program, conducted for the US Department of Energy (DOE) by Bendix Field Engineering Corporation (BFEC), radiometric and geochemical surveys and geologic investigations detected anomalies indicative of possible uranium enrichment. Data from the Aerial Radiometric and Magnetic Survey (ARMS) and the Hydrogeochemical and Stream-Sediment Reconnaissance (HSSR), both of which were conducted on a national scale, yielded numerous anomalies that may signal areas favorable for the occurrence of uranium deposits. Results from geologic evaluations of individual 1 0 x 2 0 quadrangles for the NURE program also yielded anomalies, which could not be adequately checked during scheduled field work. Included in this volume are individual reports of field investigations for the following six areas which were shown on the basis of ARMS, HSSR, and (or) geologic data to be anomalous: (1) Hylas zone and northern Richmond basin, Virginia; (2) Sischu Creek area, Alaska; (3) Goodman-Dunbar area, Wisconsin; (4) McCaslin syncline, Wisconsin; (5) Mt. Withington Cauldron, Socorro County, New Mexico; (6) Lake Tecopa, Inyo County, California. Field checks were conducted in each case to verify an indicated anomalous condition and to determine the nature of materials causing the anomaly. The ultimate objective of work is to determine whether favorable conditions exist for the occurrence of uranium deposits in areas that either had not been previously evaluated or were evaluated before data from recent surveys were available. Most field checks were of short duration (2 to 5 days). The work was done by various investigators using different procedures, which accounts for variations in format in their reports. All papers have been abstracted and indexed

  8. Application of subinterval area median contrast filtering method in the recognizing of geochemical anomalies

    International Nuclear Information System (INIS)

    Zhao Ningbo; Fu Jin; Zhang Chuan; Liu Huan

    2012-01-01

    Traditional geochemical processing method sometimes maybe loses some weak anomalies related to mineralization, the authors can avoid the influence of geology background and can solve the problem of recognizing weak anomalies in the low-background and high-background area with the subinterval area median contrast filtering method. In an area of Jiangxi Province, several new anomalies are identified by this method and uranium mineralized prospects are found among them. (authors)

  9. Geophysical Investigation of Upper Mantle Anomalies of the Australian-Antarctic Ridge

    Science.gov (United States)

    Park, S. H.; Choi, H.; Kim, S. S.; Lin, J.

    2017-12-01

    Australian-Antarctic Ridge (AAR) is situated between the Pacific-Antarctic Ridge (PAR) and Southeast Indian Ridge (SEIR), extending eastward from the Australian-Antarctic Discordance (AAD). Much of the AAR has been remained uncharted until 2011 because of its remoteness and harsh weather conditions. Since 2011, four multidisciplinary expeditions initiated by the Korea Polar Research Institute (KOPRI) have surveyed the little-explored eastern ends of the AAR and investigated the tectonics, geochemistry, and hydrothermal activity of this intermediate spreading system. Recent isotope studies using the new basalt samples from the AAR have led to the new hypothesis of the Southern Ocean mantle domain (SOM), which may have originated from the super-plume activity associated with the Gondwana break-up. In this study, we characterize the geophysics of the Southern Ocean mantle using the newly acquired shipboard bathymetry and available geophysical datasets. First, we computed residual mantle Bouguer gravity anomalies (RMBA), gravity-derived crustal thickness, and residual topography along the AAR in order to obtain a geological proxy for regional variations in magma supply. The results of these analyses revealed that the southern flank of the AAR is associated with shallower seafloor, more negative RMBA, thicker crust, and/or less dense mantle in comparison to the conjugate northern flank. Furthermore, this north-south asymmetry becomes more prominent toward the central ridge segments of the AAR. Interestingly, the along-axis depths of the entire AAR are significantly shallower than the neighboring ridge systems and the global ridges of intermediate spreading rates. Such shallow depths are also correlated with regional negative geoid anomalies. Furthermore, recent mantle tomography models consistently showed that the upper mantle (< 250 km) below the AAR has low S-wave velocities, suggesting that it may be hotter than the nearby ridges. Such regional-scale anomalies of the

  10. Ice Ih anomalies: Thermal contraction, anomalous volume isotope effect, and pressure-induced amorphization

    Science.gov (United States)

    Salim, Michael A.; Willow, Soohaeng Yoo; Hirata, So

    2016-05-01

    Ice Ih displays several anomalous thermodynamic properties such as thermal contraction at low temperatures, an anomalous volume isotope effect (VIE) rendering the volume of D2O ice greater than that of H2O ice, and a pressure-induced transition to the high-density amorphous (HDA) phase. Furthermore, the anomalous VIE increases with temperature, despite its quantum-mechanical origin. Here, embedded-fragment ab initio second-order many-body perturbation (MP2) theory in the quasiharmonic approximation (QHA) is applied to the Gibbs energy of an infinite, proton-disordered crystal of ice Ih at wide ranges of temperatures and pressures. The quantum effect of nuclei moving in anharmonic potentials is taken into account from first principles without any empirical or nonsystematic approximation to either the electronic or vibrational Hamiltonian. MP2 predicts quantitatively correctly the thermal contraction at low temperatures, which is confirmed to originate from the volume-contracting hydrogen-bond bending modes (acoustic phonons). It qualitatively reproduces (but underestimates) the thermal expansion at higher temperatures, caused by the volume-expanding hydrogen-bond stretching (and to a lesser extent librational) modes. The anomalous VIE is found to be the result of subtle cancellations among closely competing isotope effects on volume from all modes. Consequently, even ab initio MP2 with the aug-cc-pVDZ and aug-cc-pVTZ basis sets has difficulty reproducing this anomaly, yielding qualitatively varied predictions of the sign of the VIE depending on such computational details as the choice of the embedding field. However, the temperature growth of the anomalous VIE is reproduced robustly and is ascribed to the librational modes. These solid-state MP2 calculations, as well as MP2 Born-Oppenheimer molecular dynamics, find a volume collapse and a loss of symmetry and long-range order in ice Ih upon pressure loading of 2.35 GPa or higher. Concomitantly, rapid softening of

  11. Ice Ih anomalies: Thermal contraction, anomalous volume isotope effect, and pressure-induced amorphization

    Energy Technology Data Exchange (ETDEWEB)

    Salim, Michael A.; Willow, Soohaeng Yoo; Hirata, So, E-mail: sohirata@illinois.edu [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801 (United States)

    2016-05-28

    Ice Ih displays several anomalous thermodynamic properties such as thermal contraction at low temperatures, an anomalous volume isotope effect (VIE) rendering the volume of D{sub 2}O ice greater than that of H{sub 2}O ice, and a pressure-induced transition to the high-density amorphous (HDA) phase. Furthermore, the anomalous VIE increases with temperature, despite its quantum-mechanical origin. Here, embedded-fragment ab initio second-order many-body perturbation (MP2) theory in the quasiharmonic approximation (QHA) is applied to the Gibbs energy of an infinite, proton-disordered crystal of ice Ih at wide ranges of temperatures and pressures. The quantum effect of nuclei moving in anharmonic potentials is taken into account from first principles without any empirical or nonsystematic approximation to either the electronic or vibrational Hamiltonian. MP2 predicts quantitatively correctly the thermal contraction at low temperatures, which is confirmed to originate from the volume-contracting hydrogen-bond bending modes (acoustic phonons). It qualitatively reproduces (but underestimates) the thermal expansion at higher temperatures, caused by the volume-expanding hydrogen-bond stretching (and to a lesser extent librational) modes. The anomalous VIE is found to be the result of subtle cancellations among closely competing isotope effects on volume from all modes. Consequently, even ab initio MP2 with the aug-cc-pVDZ and aug-cc-pVTZ basis sets has difficulty reproducing this anomaly, yielding qualitatively varied predictions of the sign of the VIE depending on such computational details as the choice of the embedding field. However, the temperature growth of the anomalous VIE is reproduced robustly and is ascribed to the librational modes. These solid-state MP2 calculations, as well as MP2 Born–Oppenheimer molecular dynamics, find a volume collapse and a loss of symmetry and long-range order in ice Ih upon pressure loading of 2.35 GPa or higher. Concomitantly, rapid

  12. Gamma radiation, an aid to geologic mapping on the Arabian shield, Kingdom of Saudi Arabia

    International Nuclear Information System (INIS)

    Flanigan, V.J.

    1972-01-01

    Aerial gamma-radiation measurements in the Jabal Al Qarah quadrangle, Saudi Arabia, correlate with and complement magnetic data in distinguishing common Precambrian rock types. Areas of lower total-count gamma radiation correlate with areas of more intense magnetic patterns, which in turn correlate with areas of mafic rocks, as suggested from the study of the geophysical and geologic data of the Jabal Ishmas and Jabal Yafikh quadrangles adjacent to the north. In contrast, areas that reflect a lower magnetic intensity tend to show considerable variation in the radiation intensity and can be interpreted as being underlain by granitic rocks. On the basis of extrapolation of geophysical-geologic relationships established previously, selected radiation levels may be used to identify mappable rock units. Thus, radioactivity levels of 2,000 to 4,000 cpM suggest mafic rocks, levels of 4,000 to 6,000 cpM represent metavolcanic and metasedimentary rocks, levels of 7,000 to 10,000 cpM are representative of granodiorite gneiss, and levels of more than 11,000 cpM typify granitic rocks. The spectral gamma-radiation data are used to evaluate total-count anomalies and indicators of geologic processes of enrichment, and estimating the amount of isotopes of U, Th, and K within each of the lithologic units. (U.S.)

  13. Glacial/interglacial wetland, biomass burning, and geologic methane emissions constrained by dual stable isotopic CH4 ice core records

    Science.gov (United States)

    Bock, Michael; Schmitt, Jochen; Beck, Jonas; Seth, Barbara; Chappellaz, Jérôme; Fischer, Hubertus

    2017-07-01

    Atmospheric methane (CH4) records reconstructed from polar ice cores represent an integrated view on processes predominantly taking place in the terrestrial biogeosphere. Here, we present dual stable isotopic methane records [δ13CH4 and δD(CH4)] from four Antarctic ice cores, which provide improved constraints on past changes in natural methane sources. Our isotope data show that tropical wetlands and seasonally inundated floodplains are most likely the controlling sources of atmospheric methane variations for the current and two older interglacials and their preceding glacial maxima. The changes in these sources are steered by variations in temperature, precipitation, and the water table as modulated by insolation, (local) sea level, and monsoon intensity. Based on our δD(CH4) constraint, it seems that geologic emissions of methane may play a steady but only minor role in atmospheric CH4 changes and that the glacial budget is not dominated by these sources. Superimposed on the glacial/interglacial variations is a marked difference in both isotope records, with systematically higher values during the last 25,000 y compared with older time periods. This shift cannot be explained by climatic changes. Rather, our isotopic methane budget points to a marked increase in fire activity, possibly caused by biome changes and accumulation of fuel related to the late Pleistocene megafauna extinction, which took place in the course of the last glacial.

  14. Sulfur and Hydrogen Isotope Anomalies in Meteorite Sulfonic Acids

    Science.gov (United States)

    Cooper, George W.; Thiemens, Mark H.; Jackson, Teresa L.; Chang, Sherwood

    1997-01-01

    Intramolecular carbon, hydrogen, and sulfur isotope ratios were measured on a homologous series of organic sulfonic acids discovered in the Murchison meteorite. Mass-independent sulfur isotope fractionations were observed along with high deuterium/hydrogen ratios. The deuterium enrichments indicate formation of the hydrocarbon portion of these compounds in a low-temperature environment that is consistent with that of interstellar clouds. Sulfur-33 enrichments observed in methanesulfonic acid could have resulted from gas-phase ultraviolet irradiation of a precursor, carbon disulfide. The source of the sulfonic acid precursors may have been the reactive interstellar molecule carbon monosulfide.

  15. Basement configuration of KG offshore basin from magnetic anomalies

    Digital Repository Service at National Institute of Oceanography (India)

    Subrahmanyam, V.; Swamy, K.V.; Raj, N.

    to Dept. of Science & Technology, New Delhi for granting the Junior Research Fel- lowship through Inspire Programme. This is NIO (CSIR) contribution no. 7132. References Aftalion M, Bowes D R, Dash B and Dempster T J 1988 Late proterozoic charnockites... anomaly map in figure 1. Keywords. Marine magnetic anomalies; offshore K–G basin; magnetic basement; extension of EGMB geology; continent– oceanic boundary. J. Earth Syst. Sci. 125, No. 3, April 2016, pp. 663–668 c© Indian Academy of Sciences 663 664 V...

  16. First-principles theory of anharmonicity and the inverse isotope effect in superconducting palladium-hydride compounds.

    Science.gov (United States)

    Errea, Ion; Calandra, Matteo; Mauri, Francesco

    2013-10-25

    Palladium hydrides display the largest isotope effect anomaly known in the literature. Replacement of hydrogen with the heavier isotopes leads to higher superconducting temperatures, a behavior inconsistent with harmonic theory. Solving the self-consistent harmonic approximation by a stochastic approach, we obtain the anharmonic free energy, the thermal expansion, and the superconducting properties fully ab initio. We find that the phonon spectra are strongly renormalized by anharmonicity far beyond the perturbative regime. Superconductivity is phonon mediated, but the harmonic approximation largely overestimates the superconducting critical temperatures. We explain the inverse isotope effect, obtaining a -0.38 value for the isotope coefficient in good agreement with experiments, hydrogen anharmonicity being mainly responsible for the isotope anomaly.

  17. Isotope effect in the Knight shift of potassium

    International Nuclear Information System (INIS)

    Sahm, W.; Schwenk, A.

    1975-01-01

    The Knight shifts of the potassium isotopes 39 K and 41 K were determined with high accuracy: Ksup((39)) = 0.274 35(10)% and Ksup((41)) = 0.274 93(12)%. The relative isotope effect ΔK/K = -0.210 (20)% is in agreement with the hyperfine structure anomaly 39 Δ 41 . (orig.) [de

  18. Isotopic anomalies and the early history of the solar system

    International Nuclear Information System (INIS)

    Begemann, F.

    1981-01-01

    Three elements are discussed in some detail. Inclusions from carbonaceous chondrites contain quite normal minerals where the oxygen is enriched by up to 5% in 16 O. The oxygen is neither in isotopic equilibrium with that of the bulk meteorites nor are the different minerals of a single inclusion isotopically homogenized. The xenon in acid-insoluble residues from carbonaceous chondrites contains at least two distinct anomalous components. One consists essentially of the middle-weight isotopes only; the abundance pattern is as expected for Xe produced in the s-process of nucleosynthesis. The second type is to some extent complementary to this s-xenon; it is characterized by an overabundance of the light and the heavy isotopes by up to 100%. Its origin is controversial. Direct production in a supernova has been suggested as well as a superposition of strongly mass-fractionated xenon, favouring the light isotopes, and fission xenon from the decay of (a) superheavy element (s), which in turn would presumably have to be produced in a supernova as well. Neon being more than 99% pure 22 Ne is most convincingly accounted for by in situ-decay of 2.6a 22 Na which implies a condensation of Na-bearing host phases within 10 years or so of the production of 22 Na. It is not clear at present whether this condensation took place in the expanding envelope of an exploding star or within the solar system, with the onset of the collapse of the pre-solar nebula being triggered by such an explosion. (orig./WL)

  19. Stable platinum isotope measurements in presolar nanodiamonds by TEAMS

    International Nuclear Information System (INIS)

    Wallner, A.; Melber, K.; Merchel, S.; Ott, U.; Forstner, O.; Golser, R.; Kutschera, W.; Priller, A.; Steier, P.

    2013-01-01

    Nanodiamonds are stardust grains commonly found in primitive meteorites. They survived the formation of the solar system and kept their own individuality. Measurements of trace-element isotopic signatures in these grains will help understanding heavy element nucleosynthesis in massive stars and dust formation from their ejecta. We have continued previous attempts to search for stable Pt isotope anomalies in nanodiamonds via trace element accelerator mass spectrometry (TEAMS). The installation of a new injector beam line at the VERA facility allowed studying low traces of stable elements in different materials. Moreover, recent experiments showed that VERA provides the required measurement precision together with a low Pt machine background. Here, we observed for the first time an indication for enhancements of 198 Pt/ 195 Pt isotope ratios in two diamond residues prepared by different chemical separation techniques from the Allende meteorite. Variations in other isotopic ratios were within analytical uncertainty, and no anomaly was identified in a third diamond fraction.

  20. Stable platinum isotope measurements in presolar nanodiamonds by TEAMS

    Energy Technology Data Exchange (ETDEWEB)

    Wallner, A., E-mail: anton.wallner@univie.ac.at [University of Vienna, Faculty of Physics, VERA Laboratory, Waehringer Strasse 17, A-1090 Vienna (Austria); Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University, Canberra (Australia); Australian Nuclear Science and Technology Organisation (ANSTO), Lucas Heights (Australia); Melber, K. [University of Vienna, Faculty of Physics, VERA Laboratory, Waehringer Strasse 17, A-1090 Vienna (Austria); Merchel, S. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), D-01314 Dresden (Germany); Ott, U. [Max-Planck-Institut fuer Chemie, Joh.-J.-Becherweg 27, D-55128 Mainz (Germany); Forstner, O.; Golser, R.; Kutschera, W.; Priller, A.; Steier, P. [University of Vienna, Faculty of Physics, VERA Laboratory, Waehringer Strasse 17, A-1090 Vienna (Austria)

    2013-01-15

    Nanodiamonds are stardust grains commonly found in primitive meteorites. They survived the formation of the solar system and kept their own individuality. Measurements of trace-element isotopic signatures in these grains will help understanding heavy element nucleosynthesis in massive stars and dust formation from their ejecta. We have continued previous attempts to search for stable Pt isotope anomalies in nanodiamonds via trace element accelerator mass spectrometry (TEAMS). The installation of a new injector beam line at the VERA facility allowed studying low traces of stable elements in different materials. Moreover, recent experiments showed that VERA provides the required measurement precision together with a low Pt machine background. Here, we observed for the first time an indication for enhancements of {sup 198}Pt/{sup 195}Pt isotope ratios in two diamond residues prepared by different chemical separation techniques from the Allende meteorite. Variations in other isotopic ratios were within analytical uncertainty, and no anomaly was identified in a third diamond fraction.

  1. French days on stable isotopes

    International Nuclear Information System (INIS)

    2000-01-01

    These first French days on stable isotopes took place in parallel with the 1. French days of environmental chemistry. Both conferences had common plenary sessions. The conference covers all aspects of the use of stable isotopes in the following domains: medicine, biology, environment, tracer techniques, agronomy, food industry, geology, petroleum geochemistry, cosmo-geochemistry, archaeology, bio-geochemistry, hydrology, climatology, nuclear and particle physics, astrophysics, isotope separations etc.. Abstracts available on CD-Rom only. (J.S.)

  2. Anomalies of Nuclear Criticality, Revision 6

    International Nuclear Information System (INIS)

    Clayton, E.D.; Prichard, Andrew W.; Durst, Bonita E.; Erickson, David; Puigh, Raymond J.

    2010-01-01

    This report is revision 6 of the Anomalies of Nuclear Criticality. This report is required reading for the training of criticality professionals in many organizations both nationally and internationally. This report describes many different classes of nuclear criticality anomalies that are different than expected. An anomaly is defined as something not in keeping with expected notions of fitness and order, a departure from the regular arrangement or general rule. In reviewing the literature and experimental data on nuclear criticality and the conditions under which a fission chain reaction can be achieved, a number of anomalies have come to light. The actinide group is composed of the fourteen elements beginning with thorium, Atomic No. 90, and ending with lawrencium, Atomic No. 103. There are about 220 known actinide isotopes, most of which are believed capable of supporting neutron chain reactions. Although every element in the actinide group has at least one isotope believed capable of supporting a chain reaction, from a practical point of view regarding the time for chemical processing, only those nuclides with half-lives more than several weeks are of obvious concern in criticality safety. Forty-six of the nuclides are known to have half-lives greater than six weeks. The selection of six weeks is somewhat arbitrary. There may well be shorter-lived nuclides of concern in criticality safety. These 46 nuclides are identified in Figure 44. Of the 46 nuclides, 4 are known and 37 are believed to be capable of supporting chain reactions, and 5 are known or believed to not support a chain reaction. Figure 44 was constructed in the format used for the Chart of the Nuclides.(1) Figure 44 also shows the distinction between fissile and fissible nuclides. The actinides derive their name from actinium (Atomic No. 89) because they tend to maintain an actinium-like electron structure as the fourteen inner electrons are added to the 5f electron shell. Actually, electrons do

  3. Isotopic anomalies in high Z elements: Uranium?

    International Nuclear Information System (INIS)

    Jovanovic, S.; Reed, G.W. Jr.; Essling, A.M.; Rauh, E.G.; Graczyk, D.G.

    1989-03-01

    Uranium in terrestrial volcanic ejecta from mantle-related sources has been analyzed mass spectrometrically. The objective was to seek supporting evidence for or refutation isotopic variations reported by Fried et al. (1985) for some such samples. The possibility that terrestrial U is not of constant isotopic composition is extraordinary. If true, mechanisms for creating the variation must be sought and the lack of homogenization within the earth addressed. Samples of 100 grams or more were processed in order to minimize reagent and environmental (laboratory) blank interference and to permit isolation of large amounts (several to tens of μg) of U for the mass spectrometer (MS) measurements, which utilizes aliquots of /approximately/1 μg. Aliquants from four volcanic samples gave data which indicate enrichments of 235 U ranging from 0.2% to 5.9% in the 235/238 ratio relative normal uranium ratios. These relative enrichments are consistent with, and in some cases, higher than the 0.18% enrichment reported by Fried et al. (1985) for two volcanic lava samples. However, we were not able to reproduce their results on the Kilauea lava for which they report 0.18% 235 U enrichment. The relative error in our MS ratios is 0.05% -- 0.07%. 1 tab

  4. Lithologic boundaries from gravity and magnetic anomalies over ...

    Indian Academy of Sciences (India)

    Pramod Kumar Yadav

    2018-03-02

    Mar 2, 2018 ... nature of causative source using Euler depth solutions and radially averaged power spectrum (RAPS). Residual anomaly maps of gravity and ... the lateral boundaries and nature of the source. It seems that the source is of ..... Goldfarb R J and Richards J P,. The Economic Geology Publishing Company, pp.

  5. Archean Isotope Anomalies as a Window into the Differentiation History of the Earth

    Science.gov (United States)

    Wainwright, A. N.; Debaille, V.; Zincone, S. A.

    2018-05-01

    No resolvable µ142Nd anomaly was detected in Paleo- Mesoarchean rocks of São Francisco and West African cratons. The lack of µ142Nd anomalies outside of North America and Greenland implies the Earth differentiated into at least two distinct domains.

  6. Santos Basin Geological Structures Mapped by Cross-gradient Method

    Science.gov (United States)

    Jilinski, P.; Fontes, S. L.

    2011-12-01

    Introduction We mapped regional-scale geological structures localized in offshore zone Santos Basin, South-East Brazilian Coast. The region is dominated by transition zone from oceanic to continental crust. Our objective was to determine the imprint of deeper crustal structures from correlation between bathymetric, gravity and magnetic anomaly maps. The region is extensively studied for oil and gas deposits including large tectonic sub-salt traps. Our method is based on gradient directions and their magnitudes product. We calculate angular differences and cross-product and access correlation between properties and map structures. Theory and Method We used angular differences and cross-product to determine correlated region between bathymetric, free-air gravity and magnetic anomaly maps. This gradient based method focuses on borders of anomalies and uses its morphological properties to access correlation between their sources. We generated maps of angles and cross-product distribution to locate correlated regions. Regional scale potential fields maps of FA and MA are a reflection of the overlaying and overlapping effects of the adjacent structures. Our interest was in quantifying and characterizing the relation between shapes of magnetic anomalies and gravity anomalies. Results Resulting maps show strong correlation between bathymetry and gravity anomaly and bathymetry and magnetic anomaly for large strictures including Serra do Mar, shelf, continental slope and rise. All maps display the regional dominance of NE-SW geological structures alignment parallel to the shore. Special interest is presented by structures transgressing this tendency. Magnetic, gravity anomaly and bathymetry angles map show large correlated region over the shelf zone and smaller scale NE-SW banded structures over abyssal plane. From our interpretation the large band of inverse correlation adjacent to the shore is generated by the gravity effect of Serra do Mar. Disrupting structures including

  7. Geohydrological investigation of an uranium anomaly near Vanzylsrus in the Northern Cape Province

    International Nuclear Information System (INIS)

    Levin, M.; Talma, A.S.; Vogel, J.C.

    1982-01-01

    An anomaly, caused by low-grade uranium accumulations in organic-rich diatomaceous earth deposits, was located by an airborne radiometric survey near Vanzylsrus in the Northern Cape. Low-grade uraniferous calcrete also occurs in the vicinity of the anomaly. A significant uranium anomaly was found along the whole course of the palaeodrainage with the highest values occuring behind a dolerite dyke a few kilometres south of the confluence. A multidisciplinary approach in corporating geohydrology, water geochemistry, isotopic data and radiometric borehole logging studies was used to evaluate its potential

  8. Gravity and magnetic anomaly modeling and correlation using the SPHERE program and Magsat data

    Science.gov (United States)

    Braile, L. W.; Hinze, W. J. (Principal Investigator); Vonfrese, R. R. B.

    1980-01-01

    The spherical Earth inversion, modeling, and contouring software were tested and modified for processing data in the Southern Hemisphere. Preliminary geologic/tectonic maps and selected cross sections for South and Central America and the Caribbean region are being compiled and as well as gravity and magnetic models for the major geological features of the area. A preliminary gravity model of the Andeas Beniff Zone was constructed so that the density columns east and west of the subducted plates are in approximate isostatic equilibrium. The magnetic anomaly for the corresponding magnetic model of the zone is being computed with the SPHERE program. A test tape containing global magnetic measurements was converted to a tape compatible with Purdue's CDC system. NOO data were screened for periods of high diurnal activity and reduced to anomaly form using the IGS-75 model. Magnetic intensity anomaly profiles were plotted on the conterminous U.S. map using the track lines as the anomaly base level. The transcontinental magnetic high seen in POGO and MAGSAT data is also represented in the NOO data.

  9. MODELLING EARTH SYSTEM CHANGES THROUGH THE SHURUM-WONOKA ANOMALY

    DEFF Research Database (Denmark)

    Bjerrum, Christian J.; Canfield, D. E.

    the oxygen isotope record is considered to be more sensitive to post depositional diagenesis. The Neoproterozoic d13CIC record, however, reveals prolonged excursions to less than mantle values that cannot be explained by our normal understanding of the carbon cycle. We present a quantitative model...... a powerful greenhouse gas, methane increased temperature and melted icecaps. These combined to produce a negative 18O anomaly, while the higher temperatures also accelerated the weathering of continental rocks, drawing down atmospheric CO2. Lower CO2, in turn, reduced the isotope fractionation between DIC...

  10. Chromium isotope variations (δ53/52Cr) in mantle-derived sources and their weathering products: Implications for environmental studies and the evolution of δ53/52Cr in the Earth’s mantle over geologic time

    Science.gov (United States)

    Farkaš, Juraj; Chrastný, Vladislav; Novák, Martin; Čadkova, Eva; Pašava, Jan; Chakrabarti, Ramananda; Jacobsen, Stein B.; Ackerman, Lukáš; Bullen, Thomas D.

    2013-12-01

    Here we report chromium isotope compositions, expressed as δ53/52Cr in per mil (‰) relative to NIST 979, measured in selected Cr-rich minerals and rocks formed by the primary magmatic as well as the secondary metamorphic and weathering processes. The main objectives of this study were: (i) to further constrain the isotope composition of the Earth’s mantle Cr inventory and its possible variation during geological history, based on the analysis of globally distributed and stratigraphically constrained mantle-derived chromites; and (ii) to investigate the magnitude and systematics of Cr isotope fractionation during oxidative weathering and secondary alteration (i.e., hydration, serpentinization) of the magmatic Cr sources. Specifically, we analyzed δ53/52Cr in a set of globally distributed mantle-derived chromites (FeMgCr2O4, n = 30) collected from various locations in Europe, Asia, Africa and South America, and our results confirm that a chromite-hosted Earth’s mantle Cr inventory is uniform at -0.079 ± 0.129‰ (2SD), which we named here as a ‘canonical’ mantle δ53/52Cr signature. Furthermore our dataset of stratigraphically constrained chromites, whose crystallization ages cover most of the Earth’s geological history, indicate that the bulk Cr isotope composition of the chromite-hosted mantle inventory has remained uniform, within about ±0.100‰, since at least the Early Archean times (∼3500 million years ago, Ma). To investigate the systematics of Cr isotope fractionation associated with alteration processes we analyzed a number of secondary Cr-rich minerals and variably altered ultramafic rocks (i.e., serpentinized harzburgites, lherzolites) that revealed large positive δ53/52Cr anomalies that are systematically shifted to higher values with an increasing degree of alteration and serpentinization. The degree of aqueous alteration and serpentinization was quantified by the abundances of fluid-mobile (Rb, K) elements, and by the Loss On

  11. Penentuan Anomali Gayaberat Regional dan Residual Menggunakan Filter Gaussian Daerah Mamuju Sulawesi Barat

    Directory of Open Access Journals (Sweden)

    Adhika Junara Karunianto

    2017-11-01

    Full Text Available Gravity method is a geophysical method that has been frequently used in prospecting mineral resources. The parameter of searched object is based on variations of gravity acceleration measurements on the surface due to variations in sub-surface geological changes. Research area is located in Mamuju Area of West Sulawesi Province where tectonically a complex geological region, which is at a meeting of three large plates, the Pacific plate, the Indo-Australian plate and the Eurasian plate and the smaller Philippine plate. In addition, Mamuju is an area with a high radioactivity dose rate that has potency to radioactive minerals resources. The purpose of the research is to obtain gravity anomalies by using qualitative separation and interpretation of regional and residual gravity anomalies. Complete Bouguer Anomaly (CBA value of the research area obtained from the measurements was 46.0 – 115.7 mGal. Based on the CBA map, the separation process of regional gravity anomalies and residual using Gaussian filtering technique conducted. This filtering technique works based on spectral analysis of gravity amplitude changes in spatial where the result is a cutoff wave number of 1.1736 x 10-3/meter and a wavelength of 5373.45 m. The regional and residual gravity anomalies range from 51.8 to 102 mGal and -10.4 to 14.8 mGal respectively. The depth of influence of each anomaly is calculated based on their spectral wavelengths, resulting 970.97 m and 100.21 m for regional and residual anomalies respectively. There are five zones based on the residual anomaly map, which are zones A, B, C, D and E. The heaviest positive gravity anomaly is found in zone A and B, which is predicted to be influenced by Adang lava with relative north – south distribution.

  12. ADMAP-2: The next-generation Antarctic magnetic anomaly map

    Science.gov (United States)

    Golynsky, Alexander; Golynsky, Dmitry; Ferraccioli, Fausto; Jordan, Tom; Damaske, Detlef; Blankenship, Don; Holt, Jack; Young, Duncan; Ivanov, Sergey; Kiselev, Alexander; Jokat, Wilfried; Gohl, Karsten; Eagles, Graeme; Bell, Robin; Armadillo, Egidio; Bozzo, Emanuelle; Caneva, Giorgio; Finn, Carol; Forsberg, Rene; Aitken, Alan

    2017-04-01

    The Antarctic Digital Magnetic Anomaly Project compiled the first international magnetic anomaly map of the Antarctic region south of 60°S (ADMAP-1) some six years after its 1995 launch (Golynsky et al., 2001; Golynsky et al., 2007; von Frese et al., 2007). This magnetic anomaly compilation provided new insights into the structure and evolution of Antarctica, including its Proterozoic-Archaean cratons, Proterozoic-Palaeozoic orogens, Palaeozoic-Cenozoic magmatic arc systems, continental rift systems and rifted margins, large igneous provinces and the surrounding oceanic gateways. The international working group produced the ADMAP-1 database from more than 1.5 million line-kilometres of terrestrial, airborne, marine and satellite magnetic observations collected during the IGY 1957-58 through 1999. Since the publication of the first magnetic anomaly map, the international geomagnetic community has acquired more than 1.9 million line-km of new airborne and marine data. This implies that the amount of magnetic anomaly data over the Antarctic continent has more than doubled. These new data provide important constraints on the geology of the enigmatic Gamburtsev Subglacial Mountains and Prince Charles Mountains, Wilkes Land, Dronning Maud Land, and other largely unexplored Antarctic areas (Ferraccioli et al., 2011, Aitken et al., 2014¸ Mieth & Jokat, 2014, Golynsky et al., 2013). The processing of the recently acquired data involved quality assessments by careful statistical analysis of the crossover errors. All magnetic data used in the ADMAP-2 compilation were delivered as profiles, although several of them were in raw form. Some datasets were decimated or upward continued to altitudes of 4 km or higher with the higher frequency geological signals smoothed out. The line data used for the ADMAP-1 compilation were reprocessed for obvious errors and residual corrugations. The new near-surface magnetic data were corrected for the international geomagnetic reference field

  13. Hydrogen isotope fractionation in methane plasma

    OpenAIRE

    Robert, François; Derenne, Sylvie; Lombardi, Guillaume; Hassouni, Khaled; Michau, Armelle; Reinhardt, Peter; Duhamel, Rémi; Gonzalez, Adriana; Biron, Kasia

    2017-01-01

    Large variations in light element isotope ratios (H, N, C) are routinely observed in meteorite organic matter. The origin of these so-called anomalies is not accounted for by the classical theory of isotope fractionation. In the case of H, micrometer-size areas within the insoluble organic matter (IOM) isolated from meteorites by acid treatment, exhibit extreme deuterium enrichment. They are generally interpreted as components exogenous to the solar system and attributed to surviving interste...

  14. Geology and uranium occurrences in the Forez tertiary plain (in the French 'Massif Central')

    International Nuclear Information System (INIS)

    Duclos, P.

    1967-01-01

    In the first part, the observations made during the geological survey of the Forez Tertiary plain (in the French 'Massif Central') are recalled. Then, using various methods, the author lists the formations according to chronology. Finally, a reconstitution of the geological history of this subsidence basin is attempted. In the second part, the occurrence of 17 uranium bearing geochemical anomalies is commented upon. Each of these various anomalies is given a place on the stratigraphic scale. This enables the author to put the successive phases of uranium deposition into their proper perspective in the history of the plain. In conclusion, the author points out the usefulness of these uraniferous geochemical anomalies. (author) [fr

  15. Isotopes in everyday life

    International Nuclear Information System (INIS)

    Seligman, H.; Gillen, V.A.

    1990-12-01

    Isotopes represent a tool which can do certain jobs better, easier, quicker, more simply and cheaper than competitive methods. Some measurements could not be done at all without the use of isotopes as there are no alternative methods available. A short review of these tools of science in their different fields is given: food and agriculture, human health applications, industry, hydrology, geology, geochemistry, geophysics and dating, environment, basic scientific research

  16. Understanding the Tectonic Features in the South China Sea By Analyzing Magnetic Anomalies

    Science.gov (United States)

    Guo, L.; Meng, X.; Shi, L.; Yao, C.

    2011-12-01

    The South China Sea (SCS) is surrounded by the Eurasia, Pacific and India-Australia plates. It formed during Late Oligocene-Early Miocene, and is one of the largest marginal seas in the Western Pacific. The collision of Indian subcontinent and Eurasian plate in the northwest, back-arc spreading in the centre and subduction beneath the Philippine plate along Manila trench in the east and along Palawan trough in the south had produced the complex tectonic features in the SCS that we can see today. In the past few decades, a variety of geophysical methods were conducted to study geological tectonics and evolution of the SCS. Here, we analyzed the magnetic data of this area using new data enhancement techniques to understand the regional tectonic features. We assembled the magnetic anomalies data with a resolution of two arc-minute from the World Digital Magnetic Anomaly Map, and then gridded the data on a regular grid. Then we used the method of reduction to the pole at low latitude with varying magnetic inclinations to stably reduce the magnetic anomalies. Then we used the preferential continuation method based on Wiener filtering and Green's equivalence principle to separate the reduced-to-pole (RTP) magnetic anomalies, and subsequently analyze the regional and residual anomalies. We also calculated the directional horizontal derivatives and the tilt-angle derivative of the data to derive clearer geological structures with more details. Then we calculated the depth of the magnetic basement surface in the area by 3D interface inversion. From the results of the preliminary processing, we analyzed the main faults, geological structures, magma distribution and tectonic features in the SCS. In the future, the integrated interpretation of the RTP magnetic anomalies, Bouguer gravity anomalies and other geophysical methods will be performed for better understanding the deep structure , the tectonic features and evolution of the South China Sea. Acknowledgment: We

  17. Isotopic characterization of uranium in soils of the Ipanema National Forest (FLONA-Ipanema); Caracterizacao isotopica de uranio em solos da Floresta Nacional de Ipanema (FLONA-Ipanema)

    Energy Technology Data Exchange (ETDEWEB)

    Silva, F.B.; Marques, F.H., E-mail: fernandobaliani@yahoo.com.br, E-mail: fernando_henrique06@hotmail.com [Laboratorio de Pocos de Caldas (LAPOC/CNEN-MG), Pocos de Caldas, MG (Brazil); Enzweiler, J.; Ladeira, F.S.B., E-mail: Jacinta@ige.unicamp.br, E-mail: fsbladeira@ige.unicamp.br [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil). Instituto de Geociencias

    2015-07-01

    The National Forest of Ipanema (FLONA) is situated on a geological anomaly, known as 'Domo de Aracoiaba'. The soils of the area include Oxisols, Inceptsols and Alfisols. The amount of uranium and respective isotope activities in a soil depend on the parental rock and on the pedologic processes. The aim of this study was to investigate the activities for uranium isotopes ({sup 238}U, {sup 234}U, {sup 235}U) and the activity ratio (AR) {sup 234}U/ {sup 238}U or secular equilibrium for different soil types of the area collected at horizons A and B. The amount of uranium showed no significant differences for soils generated from alkaline intrusive rocks and sandstone, however, secular equilibrium was observed for Oxisol (RA = 1), while Inceptsol presented RA> 1 and the other soils, Alfisols, presented RA values <1. (author)

  18. Radiogenic age and isotopic studies

    International Nuclear Information System (INIS)

    1992-01-01

    This is one of an annual collection of reports presenting data from the Geochronology Section of the Continental Geoscience Division of the Geological Survey of Canada (GSC). The main purpose of this collection is to make geochronological and other radiogenic isotope data produced by the section available promptly to the geological community. Reports make full presentation of the data, relate these to field settings and make comparatively short interpretations. Other geochronological and isotope data produced in the laboratory but published in outside journals or separate GSC publications are summarized at the end of this report. Report 5 contains 24 papers from most regions of Canada, but particularly from British Columbia. The Geochronology Laboratory has, over the years, provided substantial U-Pb dating for the Cordilleran Division of the Geological Survey of Canada in Vancouver, and the results of a number of these studies are presented this year. A compilation of K-Ar ages is given. (figs., tabs., refs.)

  19. 878787Sr/868686Sr anomalies in Late Cretaceous-Early Tertiary ...

    Indian Academy of Sciences (India)

    paper documents the occurrences of two positive. 87. Sr/. 86 ... Analysis of trace elemental and stable isotopic profiles, sedimentation history ... et al (1980) and report of similar anomalies from ...... through the financial assistance of Alexander von. Humboldt ... and extinction events in earth history; Science 240. 996–1002.

  20. Geologic and radiometric study of the Santa Rosalia area, Arizpe Department, Sonora Mexico

    International Nuclear Information System (INIS)

    Sanchez M, C.A.

    1977-01-01

    The importance of the radiometrical anomaly, discovered in the Santa Rosalia area, Arizpe Department, Sonota, is defined in this study through topographical and geological surveying of the area by the outline and systematical survey of rocks for sampling and registration of the radioactivity. Two radioactive anomalies were defined and called IIIA and IIIB, identifying the existence of secondary uranium minerals (Torbernite) in the IIIB anomaly. According to the results of the work which was carried out we can't deduce that both localities present signs of the existence of important uranium concentrations. We can conclude that the presence of uranium minerals obliges us to realize a more detailed exploration, suggesting the opening of little excavations and ditches and stretching out of the geochemical, geological and radiometrical exploration to adjacent areas. (author)

  1. A new feature in the internal heavy isotope distribution in ozone

    International Nuclear Information System (INIS)

    Bhattacharya, S. K.; Liang, Mao-Chang; Savarino, Joel; Michalski, G.

    2014-01-01

    Ozone produced by discharge or photolysis of oxygen has unusually heavy isotopic composition ( 18 O/ 16 O and 17 O/ 16 O ratio) which does not follow normal mass fractionation rule: δ 17 O ∼ 0.52 * δ 18 O, expressed as an anomaly Δ 17 O = δ 17 O − 0.52 * δ 18 O. Ozone molecule being an open isosceles triangle can have the heavy isotope located either in its apex or symmetric (s) position or the base or asymmetric (as) position. Correspondingly, one can define positional isotopic enrichment, written as δ 18 O (s) or δ 18 O (as) (and similarly for δ 17 O) as well as position dependent isotope anomaly Δ 17 O (s) and Δ 17 O (as). Marcus and co-workers have proposed a semi-empirical model based in principle on the RRKM model of uni-molecular dissociation but with slight modification (departure from statistical randomness assumption for symmetrical molecules) which explains many features of ozone isotopic enrichment. This model predicts that the bulk isotope anomaly is contained wholly in the asymmetric position and the Δ 17 O (s) is zero. Consequently, Δ 17 O (as) = 1.5 * Δ 17 O (bulk) (named here simply as the “1.5 rule”) which has been experimentally confirmed over a range of isotopic enrichment. We now show that a critical re-analysis of the earlier experimental data demonstrates a small but significant departure from this 1.5 rule at the highest and lowest levels of enrichments. This departure provides the first experimental proof that the dynamics of ozone formation differs from a statistical model constrained only by restriction of symmetry. We speculate over some possible causes for the departure

  2. A new feature in the internal heavy isotope distribution in ozone

    Science.gov (United States)

    Bhattacharya, S. K.; Savarino, Joel; Michalski, G.; Liang, Mao-Chang

    2014-10-01

    Ozone produced by discharge or photolysis of oxygen has unusually heavy isotopic composition (18O/16O and 17O/16O ratio) which does not follow normal mass fractionation rule: δ17O ˜ 0.52*δ18O, expressed as an anomaly Δ17O = δ17O - 0.52*δ18O. Ozone molecule being an open isosceles triangle can have the heavy isotope located either in its apex or symmetric (s) position or the base or asymmetric (as) position. Correspondingly, one can define positional isotopic enrichment, written as δ18O (s) or δ18O (as) (and similarly for δ17O) as well as position dependent isotope anomaly Δ17O (s) and Δ17O (as). Marcus and co-workers have proposed a semi-empirical model based in principle on the RRKM model of uni-molecular dissociation but with slight modification (departure from statistical randomness assumption for symmetrical molecules) which explains many features of ozone isotopic enrichment. This model predicts that the bulk isotope anomaly is contained wholly in the asymmetric position and the Δ17O (s) is zero. Consequently, Δ17O (as) = 1.5 * Δ17O (bulk) (named here simply as the "1.5 rule") which has been experimentally confirmed over a range of isotopic enrichment. We now show that a critical re-analysis of the earlier experimental data demonstrates a small but significant departure from this 1.5 rule at the highest and lowest levels of enrichments. This departure provides the first experimental proof that the dynamics of ozone formation differs from a statistical model constrained only by restriction of symmetry. We speculate over some possible causes for the departure.

  3. Magnetic anomalies over the Andaman Islands and their geological ...

    Indian Academy of Sciences (India)

    plate boundary zone (e.g., Gahalaut et al. 2008; ... Himalayan arc/collision system in the north and the Indonesian arc system .... prominent linear ridges, (b) geological map of the Andaman Islands (after Pal et al. 2003a) ... ophiolite rocks occur in N–S to NE–SW trending bodies. ... described above gave rise to three areas of.

  4. Carbon and oxygen isotope analysis of leaf biomass reveals contrasting photosynthetic responses to elevated CO2 near geologic vents in Yellowstone National Park

    Directory of Open Access Journals (Sweden)

    D. G. Williams

    2009-01-01

    Full Text Available In this study we explore the use of natural CO2 emissions in Yellowstone National Park (YNP in Wyoming, USA to study responses of natural vegetation to elevated CO2 levels. Radiocarbon (14C analysis of leaf biomass from a conifer (Pinus contortus; lodgepole pine and an invasive, non-native herb (Linaria dalmatica; Dalmation toadflax was used to trace the inputs of vent CO2 and quantify assimilation-weighted CO2 concentrations experienced by individual plants near vents and in comparable locations with no geologic CO2 exposure. The carbon and oxygen isotopic composition and nitrogen percent of leaf biomass from the same plants was used to investigate photosynthetic responses of these plants to naturally elevated atmospheric CO2 concentrations. The coupled shifts in carbon and oxygen isotope values suggest that dalmation toadflax responded to elevated CO2 exposure by increasing stomatal conductance with no change in photosynthetic capacity and lodgepole pine apparently responded by decreasing stomatal conductance and photosynthetic capacity. Lodgepole pine saplings exposed to elevated levels of CO2 likewise had reduced leaf nitrogen concentrations compared to plants with no enhanced CO2 exposure, further suggesting widespread and dominant conifer down-regulated photosynthetic capacity under elevated CO2 levels near geologic vents.

  5. Use of the ion microprobe in geological dating

    International Nuclear Information System (INIS)

    Compston, W.; Williams, I.S.; Black, L.P.

    1983-01-01

    SHRIMP, the Sensitive High Resolution Ion Microprobe with computerised control and data acquisition system, has recently been commissioned. It is used within the Research School of Earth Sciences, Australian National University, for the isotopic analysis of geological samples. Principles of operation and geological applications are outlined. One example described is the application to Pb-U dating of zircon

  6. Application of environmental isotope tracing technology to geothermal geochemistry

    International Nuclear Information System (INIS)

    Shang Yingnan

    2006-01-01

    This paper reviews the recent application and development of environmental isotope tracing technology to geothermal geochemistry in the following aspects: gas isotopes (He, C) tracing of warm springs; H, O isotope tracing on the origin and cause of geothermal water, environmental isotope dating of geothermal water, and the advantage of excess parameter of deuterium (d) in geothermal research. The author also suggests that isotope method should combine with other geological methods to expand its advantage. (authors)

  7. Stable carbon isotope response to oceanic anoxic events

    International Nuclear Information System (INIS)

    Hu Xiumian; Wang Chengshan; Li Xianghui

    2001-01-01

    Based on discussion of isotope compositions and fractionation of marine carbonate and organic carbon, the author studies the relationship between oceanic anoxic events and changes in the carbon isotope fractionation of both carbonate and organic matter. During the oceanic anoxic events, a great number of organisms were rapidly buried, which caused a kind of anoxic conditions by their decomposition consuming dissolved oxygen. Since 12 C-rich organism preserved, atmosphere-ocean system will enrich relatively of 13 C. As a result, simultaneous marine carbonate will record the positive excursion of carbon isotope. There is a distinctive δ 13 C excursion during oceanic anoxic events in the world throughout the geological time. In the Cenomanian-Turonian anoxic event. this positive excursion arrived at ∼0.2% of marine carbonate and at ∼0.4% of organic matter, respectively. Variations in the carbon isotopic compositions of marine carbonate and organic carbon record the changes in the fraction of organic carbon buried throughout the geological time and may provide clues to the changes in rates of weathering and burial of organic carbon. This will provide a possibility of interpreting not only the changes in the global carbon cycle throughout the geological time, but also that in atmospheric p CO 2

  8. The application of isotopic dating methods for prospection and exploration of nuclear raw material

    International Nuclear Information System (INIS)

    Komlev, L.V.; Anderson, E.B.

    1977-01-01

    Among the geological and geochemical methods for prospecting and searching the nuclear raw material, the isotope-dating methods determine the most important search criterion - the time of the ore-forming. The elaboration and use of these methods in uranium-ore regions reveal a series of geochemical epochs of uranium and thorium accumulation connected naturally with the history of geological evolution of the earth crust. The isotope-dating methods enable with confidence to establish the stages of tectono-magmatic activity resulting in the redistribution and the local concentration of uranium. The wide use of isotopic methods is a necessary condition for reasonable trends of the modern geological exploration [ru

  9. Development of the negative gravity anomaly of the 85 E Ridge ...

    Indian Academy of Sciences (India)

    2Department of Earth Sciences, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India. 3National ... different crust-sediment structural configurations of the ridge that were existing at three geological ages, ... characteristic negative gravity anomaly and com- ... to determine the crustal structure and isostatic.

  10. Isotopic ratios in the solar system

    International Nuclear Information System (INIS)

    1985-01-01

    This colloquium is aimed at presentation of isotope ratio measurements in different objects of solar system and surrounding interstellar space and evaluation of what information on composition and structure of primitive solar nebula and on chemical evolution of interstellar space in this part of the galaxy can be deduced from it. Isotope ratio in solar system got from laboratory study of extraterrestrial materials is a subject of this colloquium. Then isotope ratio measured in solar wind, planets and comets. Measurements either are made in-situ by mass spectrometry of ions in solar wind or planetery atmosphere gases either are remote measurements of spectra emitted by giant planets and comets. At last, planetology and astrophysics implications are presented and reviewed. Consraints for solar system formation model can be deduced from isotope ratio measurement. Particularly, isotope anomalies are marks of the processes, which have influenced the primitive solar nebula contraction [fr

  11. Compound-specific carbon isotopes from Earth’s largest flood basalt eruptions directly linked to the end-Triassic mass extinction

    Science.gov (United States)

    Whiteside, Jessica H.; Olsen, Paul E.; Eglinton, Timothy; Brookfield, Michael E.; Sambrotto, Raymond N.

    2010-01-01

    A leading hypothesis explaining Phanerozoic mass extinctions and associated carbon isotopic anomalies is the emission of greenhouse, other gases, and aerosols caused by eruptions of continental flood basalt provinces. However, the necessary serial relationship between these eruptions, isotopic excursions, and extinctions has never been tested in geological sections preserving all three records. The end-Triassic extinction (ETE) at 201.4 Ma is among the largest of these extinctions and is tied to a large negative carbon isotope excursion, reflecting perturbations of the carbon cycle including a transient increase in CO2. The cause of the ETE has been inferred to be the eruption of the giant Central Atlantic magmatic province (CAMP). Here, we show that carbon isotopes of leaf wax derived lipids (n-alkanes), wood, and total organic carbon from two orbitally paced lacustrine sections interbedded with the CAMP in eastern North America show similar excursions to those seen in the mostly marine St. Audrie’s Bay section in England. Based on these results, the ETE began synchronously in marine and terrestrial environments slightly before the oldest basalts in eastern North America but simultaneous with the eruption of the oldest flows in Morocco, a CO2 super greenhouse, and marine biocalcification crisis. Because the temporal relationship between CAMP eruptions, mass extinction, and the carbon isotopic excursions are shown in the same place, this is the strongest case for a volcanic cause of a mass extinction to date. PMID:20308590

  12. Isotopic tracers of sources, wells and of CO2 reactivity in geological reservoirs

    International Nuclear Information System (INIS)

    Assayag, N.

    2006-12-01

    The aim of this research works consisted in studying the behaviour of the carbonate system (dissolved inorganic carbon: DIC) following a CO 2 injection (artificial or natural), in geological reservoirs. One part of the study consisted in improving an analytical protocol for the measurement of δ 13 C DIC and DIC, using a continuous flow mass spectrometer. As a first study, we have focused our attention on the Pavin Lake (Massif Central, France). Owing to its limnologic characteristics (meromictic lake) and a deep volcanic CO 2 contribution, it can be viewed as a natural analogue of reservoir storing important quantities of CO 2 in the bottom part. Isotopic measurements (δ 18 O, δ 13 C DIC) allowed to better constrain the dynamics of the lake (stratification, seasonal variations), the magnitudes of biological activities (photosynthesis, organic matter decay, methane oxidation, methano-genesis), carbon sources (magmatic, methano-genetic), and the hydrological budgets (sub-lacustrine inputs). The second study was conducted on the Lamont-Doherty test well site (NY, USA). It includes an instrumental borehole which cuts through most of the section of the Palisades sill and into the Newark Basin sediments. Single well push-pull tests were performed: a test solution containing conservative tracers and a reactive tracer (CO 2 ) was injected at a permeable depth interval located in basaltic and meta sedimentary rocks. After an incubation period, the test solution/groundwater mixture was extracted from the hydraulically isolated zone. Isotopic measurements (δ 18 O, δ 13 C DIC) confronted to chemical data (major elements) allowed to investigate the extent of in-situ CO 2 -water-rock interactions: essentially calcite dissolution and at a lesser extend silicate dissolution...and for one of the test, CO 2 degassing. (author)

  13. The quest for the perfect gravity anomaly: Part 2 - Mass effects and anomaly inversion

    Science.gov (United States)

    Keller, Gordon R.; Hildenbrand, T.G.; Hinze, W. J.; Li, X.; Ravat, D.; Webring, M.

    2006-01-01

    Gravity anomalies have become an important tool for geologic studies since the widespread use of high-precision gravimeters after the Second World War. More recently the development of instrumentation for airborne gravity observations, procedures for acquiring data from satellite platforms, the readily available Global Positioning System for precise vertical and horizontal control, improved global data bases, and enhancement of computational hardware and software have accelerated the use of the gravity method. As a result, efforts are being made to improve the gravity databases that are made available to the geoscience community by broadening their observational holdings and increasing the accuracy and precision of the included data. Currently the North American Gravity Database as well as the individual databases of Canada, Mexico, and the United States of America are being revised using new formats and standards. The objective of this paper is to describe the use of the revised standards for gravity data processing and modeling and there impact on geological interpretations. ?? 2005 Society of Exploration Geophysicists.

  14. Communication: On the isotope anomaly of nuclear quadrupole coupling in molecules

    Science.gov (United States)

    Filatov, Michael; Zou, Wenli; Cremer, Dieter

    2012-10-01

    The dependence of the nuclear quadrupole coupling constants (NQCC) on the interaction between electrons and a nucleus of finite size is theoretically analyzed. A deviation of the ratio of the NQCCs obtained from two different isotopomers of a molecule from the ratio of the corresponding bare nuclear electric quadrupole moments, known as quadrupole anomaly, is interpreted in terms of the logarithmic derivatives of the electric field gradient at the nuclear site with respect to the nuclear charge radius. Quantum chemical calculations based on a Dirac-exact relativistic methodology suggest that the effect of the changing size of the Au nucleus in different isotopomers can be observed for Au-containing molecules, for which the predicted quadrupole anomaly reaches values of the order of 0.1%. This is experimentally detectable and provides an insight into the charge distribution of non-spherical nuclei.

  15. Oxygen isotope anomaly in tropospheric CO2 and implications for CO2 residence time in the atmosphere and gross primary productivity.

    Science.gov (United States)

    Liang, Mao-Chang; Mahata, Sasadhar; Laskar, Amzad H; Thiemens, Mark H; Newman, Sally

    2017-10-13

    The abundance variations of near surface atmospheric CO 2 isotopologues (primarily 16 O 12 C 16 O, 16 O 13 C 16 O, 17 O 12 C 16 O, and 18 O 12 C 16 O) represent an integrated signal from anthropogenic/biogeochemical processes, including fossil fuel burning, biospheric photosynthesis and respiration, hydrospheric isotope exchange with water, and stratospheric photochemistry. Oxygen isotopes, in particular, are affected by the carbon and water cycles. Being a useful tracer that directly probes governing processes in CO 2 biogeochemical cycles, Δ 17 O (=ln(1 + δ 17 O) - 0.516 × ln(1 + δ 18 O)) provides an alternative constraint on the strengths of the associated cycles involving CO 2 . Here, we analyze Δ 17 O data from four places (Taipei, Taiwan; South China Sea; La Jolla, United States; Jerusalem, Israel) in the northern hemisphere (with a total of 455 measurements) and find a rather narrow range (0.326 ± 0.005‰). A conservative estimate places a lower limit of 345 ± 70 PgC year -1 on the cycling flux between the terrestrial biosphere and atmosphere and infers a residence time of CO 2 of 1.9 ± 0.3 years (upper limit) in the atmosphere. A Monte Carlo simulation that takes various plant uptake scenarios into account yields a terrestrial gross primary productivity of 120 ± 30 PgC year -1 and soil invasion of 110 ± 30 PgC year -1 , providing a quantitative assessment utilizing the oxygen isotope anomaly for quantifying CO 2 cycling.

  16. Worldwide complete spherical Bouguer and isostatic anomaly maps

    Science.gov (United States)

    Bonvalot, S.; Balmino, G.; Briais, A.; Peyrefitte, A.; Vales, N.; Biancale, R.; Gabalda, G.; Reinquin, F.

    2011-12-01

    We present here a set of digital maps of the Earth's gravity anomalies (surface "free air", Bouguer and isostatic), computed at Bureau Gravimetric International (BGI) as a contribution to the Global Geodetic Observing Systems (GGOS) and to the global geophysical maps published by the Commission for the Geological Map of the World (CGMW). The free air and Bouguer anomaly concept is extensively used in geophysical interpretation to investigate the density distributions in the Earth's interior. Complete Bouguer anomalies (including terrain effects) are usually computed at regional scales by integrating the gravity attraction of topography elements over and beyond a given area (under planar or spherical approximations). Here, we developed and applied a worldwide spherical approach aimed to provide a set of homogeneous and high resolution gravity anomaly maps and grids computed at the Earth's surface, taking into account a realistic Earth model and reconciling geophysical and geodetic definitions of gravity anomalies. This first version (1.0) has been computed by spherical harmonics analysis / synthesis of the Earth's topography-bathymetry up to degree 10800. The detailed theory of the spherical harmonics approach is given in Balmino et al., (Journal of Geodesy, submitted). The Bouguer and terrain corrections have thus been computed in spherical geometry at 1'x1' resolution using the ETOPO1 topography/bathymetry, ice surface and bedrock models from the NOAA (National Oceanic and Atmospheric Administration) and taking into account precise characteristics (boundaries and densities) of major lakes, inner seas, polar caps and of land areas below sea level. Isostatic corrections have been computed according to the Airy Heiskanen model in spherical geometry for a constant depth of compensation of 30km. The gravity information given here is provided by the Earth Geopotential Model (EGM2008), developed at degree 2160 by the National Geospatial Intelligence Agency (NGA) (Pavlis

  17. Isotopic compositions of potassium and calcium in magnetic spherulesfrom marine sediments

    International Nuclear Information System (INIS)

    Shimarura, T.; Yanagita, S.; Yamakoshi, K.; Nogami, K.; Arai, O.; Tazawa, Y.; Kobayashi, K.

    1979-01-01

    Isotopic compositions of potassium and calcium in individual magnetic spherules were determined. No significant anomaly was observed for potassium within twice the statistical error (2sigma), although for calcium isotopes enrichment of 46 Ca, 44 Ca and 42 Ca were observed in one spherule. The relative excess of 46 Ca, 44 Ca and 42 Ca in the spherule agrees with the relative yield of spallogenic calcium isotopes observed in iron meteorites. This fact indicates that the enrichment in the calcium isotopes was caused by cosmic ray irradiation of the spherule in outer space. (Auth.)

  18. CREATING A GEOLOGIC PLAY BOOK FOR TRENTON-BLACK RIVER APPALACHIAN BASIN EXPLORATION

    Energy Technology Data Exchange (ETDEWEB)

    Douglas G. Patchen; James Drahovzal; Larry Wickstrom; Taury Smith; Chris Laughery; Katharine Lee Avary

    2004-04-01

    Private- and public-sector stakeholders formed the new ''Trenton-Black River Appalachian Basin Exploration Consortium'' and began a two-year research effort that will lead to a play book for Trenton-Black River exploration throughout the Appalachian basin. The final membership of the Consortium includes 17 gas exploration companies and 6 research team members, including the state geological surveys in Kentucky, Ohio, Pennsylvania and West Virginia, the New York State Museum Institute and West Virginia University. Seven integrated research tasks are being conducted by basin-wide research teams organized from this large pool of experienced professionals. More than 3400 miles of Appalachian basin digital seismic data have been quality checked. In addition, inquiries have been made regarding the availability of additional seismic data from government and industry partners in the consortium. Interpretations of the seismic data have begun. Error checking is being performed by mapping the time to various prominent reflecting horizons, and analyzing for any anomalies. A regional geological velocity model is being created to make time-to-depth conversions. Members of the stratigraphy task team compiled a generalized, basin-wide correlation chart, began the process of scanning geophysical logs and laid out lines for 16 regional cross sections. Two preliminary cross sections were constructed, a database of all available Trenton-Black River cores was created, and a basin-wide map showing these core locations was produced. Two cores were examined, described and photographed in detail, and were correlated to the network of geophysical logs. Members of the petrology team began the process of determining the original distribution of porous and permeable facies within a sequence stratigraphic framework. A detailed sedimentologic and petrographic study of the Union Furnace road cut in central Pennsylvania was completed. This effort will facilitate the calibration

  19. Depth study of insular shelf electric sounding Adelaida anomaly (Rivera)

    International Nuclear Information System (INIS)

    Cicalese, H.

    1983-01-01

    In the framework of the Uranium prospecting programme, the DINAMIGE geophysical equipment have made a study. It was about the depth of insular shelf electric sounding on the anomalies zone of Adelaida. This equipment carried out a study of the following subjects: geographical location, geologic framework, geophysical intervention, developed works, methods and material and results

  20. Application of isostatic gravity anomaly in the Yellow Sea area

    Science.gov (United States)

    Hao, Z.; Qin, J.; Huang, W.; Wu, X.

    2017-12-01

    In order to study the deep crustal structure of the Yellow Sea area, we used the Airy-Heiskanen model to calculate the isostatic gravity anomaly of this area. Based on the Bouguer gravity anomaly and water depth data of this area, we chose the calculating parameters as standard crustal thickness 30 km, crust-mantle density difference 0.6g/cm3and grid spacing 0.1°×0.1°. This study reveals that there are six faults and four isostatic negative anomalies in the study area. The isostatic anomalies in much of Yellow Sea areas give priority to those with positive anomalies. The isostatic anomalies in North Yellow Sea are higher than South Yellow Sea with Jiashan-Xiangshui fault as the boundary. In the north of the study area, isostatic anomalies are characterized by large areas of positive anomaly. The change is relatively slow, and the trends give priority to the trend NE or NEE. In the middle of the north Yellow Sea basin, there is a local negative anomaly, arranged as a string of beads in NE to discontinuous distribution. Negative anomaly range is small, basically corresponds to the region's former Cenozoic sedimentary basin position. To the south of Jiashan-Xiangshui fault and west of Yellow Sea eastern margin fault, including most of the south Yellow Sea and Jiangsu province, the isostatic anomalies are lower. And the positive and negative anomalies are alternative distribution, and negative anomaly trap in extensive development. The trends give priority to NE, NEE, both to the NW. On the basis of the characteristics of isostatic gravity anomalies, it is concluded that the Yellow Sea belongs to continental crustal isostatic area whose isostatic anomalies is smooth and slow. ReferencesHeiskanen, W. A., F. A. V. Meinesz, and S. A. Korff (1958), The Earth and Its Gravity Field, McGraw-Hill, New York. Meng, X. J., X. H. Zhang, and J. Y. Yang (2014), Geophysical survey in eastern China seas and the characteristics of gravity and magnetic fields, Marine Geoglogy

  1. Geocongress 84: 20. Geological congress of the Geological Society of South Africa. Pilanesberg excursion, 14-16 Jul 1984

    International Nuclear Information System (INIS)

    1984-01-01

    The Pilanesberg Complex is situated in Bophuthatswana about 50km to the north north-west of Rustenberg in the Western Transvaal. The basic geological setting of the Pilanesberg is discussed, as well as its geochemistry. Of the major rock types the co-called Ledig foyaite has the highest content of trace elements and this is followed by green foyaite. The Th/U ratio is approximately 5 for the complex as a whole. The high concentrations of uranium and thorium resulted in a pronounced radiometric anomaly over the whole complex, the details which are given in tables. The occurences of relatively high radiometric anomalies located during ground surveys are also described

  2. Nucleosynthesis in Wolf-Rayet stars and galactic cosmic-ray isotopic composition

    International Nuclear Information System (INIS)

    Prantzos, N.

    1984-01-01

    An explanation of the isotopic composition of galactic cosmic rays could provide some clues to the mystery of their origin. It seems now that the strong stellar winds of Wolf-Rayet stars could account for most of the isotopic anomalies that have been observed in cosmic rays. Some results are presented, obtained by detailed nucleosynthesis computations. 25 references

  3. Accurate isotope ratio mass spectrometry. Some problems and possibilities

    International Nuclear Information System (INIS)

    Bievre, P. de

    1978-01-01

    The review includes reference to 190 papers, mainly published during the last 10 years. It covers the following: important factors in accurate isotope ratio measurements (precision and accuracy of isotope ratio measurements -exemplified by determinations of 235 U/ 238 U and of other elements including 239 Pu/ 240 Pu; isotope fractionation -exemplified by curves for Rb, U); applications (atomic weights); the Oklo natural nuclear reactor (discovered by UF 6 mass spectrometry at Pierrelatte); nuclear and other constants; isotope ratio measurements in nuclear geology and isotope cosmology - accurate age determination; isotope ratio measurements on very small samples - archaeometry; isotope dilution; miscellaneous applications; and future prospects. (U.K.)

  4. Occurrence and multivariate exploratory analysis of the natural radioactivity anomaly in the south coastal region of Kenya

    Science.gov (United States)

    Kaniu, M. I.; Angeyo, K. H.; Darby, I. G.

    2018-05-01

    Characterized by a variety of rock formations, namely alkaline, igneous and sedimentary that contain significant deposits of monazite and pyrochlore ores, the south coastal region of Kenya may be regarded as highly heterogeneous with regard to its geochemistry, mineralogy as well as geological morphology. The region is one of the several alkaline carbonatite complexes of Kenya that are associated with high natural background radiation and therefore radioactivity anomaly. However, this high background radiation (HBR) anomaly has hardly been systematically assessed and delineated with regard to the spatial, geological, geochemical as well as anthropogenic variability and co-dependencies. We conducted wide-ranging in-situ gamma-ray spectrometric measurements in this area. The goal of the study was to assess the radiation exposure as well as determine the underlying natural radioactivity levels in the region. In this paper we report the occurrence, exploratory analysis and modeling to assess the multivariate geo-dependence and spatial variability of the radioactivity and associated radiation exposure. Unsupervised principal component analysis and ternary plots were utilized in the study. It was observed that areas which exhibit HBR anomalies are located along the south coast paved road and in the Mrima-Kiruku complex. These areas showed a trend towards enhanced levels of 232Th and 238U and low 40K. The spatial variability of the radioactivity anomaly was found to be mainly constrained by anthropogenic activities, underlying geology and geochemical processes in the terrestrial environment.

  5. Satellite magnetic anomalies of the Antarctic crust

    Directory of Open Access Journals (Sweden)

    D. E. Alsdorf

    2000-06-01

    Full Text Available Spatially and temporally static crustal magnetic anomalies are contaminated by static core field effects above spherical harmonic degree 12 and dynamic, large-amplitude external fields. To extract crustal magnetic anomalies from the measurements of NASA's Magsat mission, we separate crustal signals from both core and external field effects. In particular, we define Magsat anomalies relative to the degree 11 field and use spectral correlation theory to reduce them for external field effects. We obtain a model of Antarctic crustal thickness by comparing the region's terrain gravity effects to free-air gravity anomalies derived from the Earth Gravity Model 1996 (EGM96. To separate core and crustal magnetic effects, we obtain the pseudo-magnetic effect of the crustal thickness variations from their gravity effect via Poisson's theorem for correlative potentials. We compare the pseudo-magnetic effect of the crustal thickness variations to field differences between degrees 11 and 13 by spectral correlation analysis. We thus identify and remove possible residual core field effects in the Magsat anomalies relative to the degree 11 core field. The resultant anomalies reflect possible Antarctic contrasts due both to crustal thickness and intracrustal variations of magnetization. In addition, they provide important constraints on the geologic interpretation of aeromagnetic survey data, such as are available for the Weddell Province. These crustal anomalies also may be used to correct for long wavelength errors in regional compilations of near-surface magnetic survey data. However, the validity of these applications is limited by the poor quality of the Antarctic Magsat data that were obtained during austral Summer and Fall when south polar external field activity was maximum. Hence an important test and supplement for the Antarctic crustal Magsat anomaly map will be provided by the data from the recently launched Ørsted mission, which will yield coverage

  6. Evaluation of the uranium anomaly of Punta del Este in the territory Isla de la Juventud

    International Nuclear Information System (INIS)

    Sanchez R, J.; Macola, E.; Alcalde, J.; Olivera, J.; Fernandez, P.; Villarino, J.

    1995-01-01

    The work show the projection and execution of the geologic-geophysics works on profiles executed to verificate the airborne spectrometric anomaly uranium in the territory the Island Young located in Punta del Este. As soon as the interpretation of the prospection works realizated as fundamental conclusion we obtained that this anomaly is associated to reed soils development over limestone, which have not contains of phosphorus

  7. Unexpected variations in the triple oxygen isotope composition of stratospheric carbon dioxide

    Science.gov (United States)

    Wiegel, Aaron A.; Cole, Amanda S.; Hoag, Katherine J.; Atlas, Elliot L.; Schauffler, Sue M.; Boering, Kristie A.

    2013-10-01

    We report observations of stratospheric CO2 that reveal surprisingly large anomalous enrichments in 17O that vary systematically with latitude, altitude, and season. The triple isotope slopes reached 1.95 ± 0.05(1σ) in the middle stratosphere and 2.22 ± 0.07 in the Arctic vortex versus 1.71 ± 0.03 from previous observations and a remarkable factor of 4 larger than the mass-dependent value of 0.52. Kinetics modeling of laboratory measurements of photochemical ozone-CO2 isotope exchange demonstrates that non-mass-dependent isotope effects in ozone formation alone quantitatively account for the 17O anomaly in CO2 in the laboratory, resolving long-standing discrepancies between models and laboratory measurements. Model sensitivities to hypothetical mass-dependent isotope effects in reactions involving O3, O(1D), or CO2 and to an empirically derived temperature dependence of the anomalous kinetic isotope effects in ozone formation then provide a conceptual framework for understanding the differences in the isotopic composition and the triple isotope slopes between the laboratory and the stratosphere and between different regions of the stratosphere. This understanding in turn provides a firmer foundation for the diverse biogeochemical and paleoclimate applications of 17O anomalies in tropospheric CO2, O2, mineral sulfates, and fossil bones and teeth, which all derive from stratospheric CO2.

  8. Radionuclide transport behavior in a generic geological radioactive waste repository.

    Science.gov (United States)

    Bianchi, Marco; Liu, Hui-Hai; Birkholzer, Jens T

    2015-01-01

    We performed numerical simulations of groundwater flow and radionuclide transport to study the influence of several factors, including the ambient hydraulic gradient, groundwater pressure anomalies, and the properties of the excavation damaged zone (EDZ), on the prevailing transport mechanism (i.e., advection or molecular diffusion) in a generic nuclear waste repository within a clay-rich geological formation. By comparing simulation results, we show that the EDZ plays a major role as a preferential flowpath for radionuclide transport. When the EDZ is not taken into account, transport is dominated by molecular diffusion in almost the totality of the simulated domain, and transport velocity is about 40% slower. Modeling results also show that a reduction in hydraulic gradient leads to a greater predominance of diffusive transport, slowing down radionuclide transport by about 30% with respect to a scenario assuming a unit gradient. In addition, inward flow caused by negative pressure anomalies in the clay-rich formation further reduces transport velocity, enhancing the ability of the geological barrier to contain the radioactive waste. On the other hand, local high gradients associated with positive pressure anomalies can speed up radionuclide transport with respect to steady-state flow systems having the same regional hydraulic gradients. Transport behavior was also found to be sensitive to both geometrical and hydrogeological parameters of the EDZ. Results from this work can provide useful knowledge toward correctly assessing the post-closure safety of a geological disposal system. © 2014, National Ground Water Association.

  9. Utilizing HyspIRI Prototype Data for Geological Exploration Applications: A Southern California Case Study

    Directory of Open Access Journals (Sweden)

    Wendy M. Calvin

    2016-02-01

    Full Text Available The purpose of this study was to demonstrate the value of the proposed Hyperspectral Infrared Imager (HyspIRI instrument for geological mapping applications. HyspIRI-like data were collected as part of the HyspIRI airborne campaign that covered large regions of California, USA, over multiple seasons. This work focused on a Southern California area, which encompasses Imperial Valley, the Salton Sea, the Orocopia Mountains, the Chocolate Mountains, and a variety of interesting geological phenomena including fumarole fields and sand dunes. We have mapped hydrothermal alteration, lithology and thermal anomalies, demonstrating the value of this type of data for future geologic exploration activities. We believe HyspIRI will be an important instrument for exploration geologists as data may be quickly manipulated and used for remote mapping of hydrothermal alteration minerals, lithology and temperature anomalies.

  10. Sulfur-induced offsets in MC-ICP-MS silicon-isotope measurements

    NARCIS (Netherlands)

    van den Boorn, S.; Vroon, P.Z.; van Bergen, M.J.

    2009-01-01

    Sample preparation methods for MC-ICP-MS silicon-isotope measurements often involve a cation-exchange purification step. A previous study has argued that this would suffice for geological materials, as the occasional enrichment of anionic species would not compromise silicon-isotope analysis. Here

  11. Sulphur-induced offsets in MC-ICP-MS silicon-isotope measurements

    NARCIS (Netherlands)

    van den Boorn, S.; Vroon, P.Z.; van Bergen, M.J.

    2010-01-01

    Sample preparation methods for MC-ICP-MS silicon-isotope measurements often involve a cation-exchange purification step. A previous study has argued that this would suffice for geological materials, as the occasional enrichment of anionic species would not compromise silicon-isotope analysis. Here

  12. Molybdenum isotopic evidence for the origin of chondrules and a distinct genetic heritage of carbonaceous and non-carbonaceous meteorites

    Science.gov (United States)

    Budde, Gerrit; Burkhardt, Christoph; Brennecka, Gregory A.; Fischer-Gödde, Mario; Kruijer, Thomas S.; Kleine, Thorsten

    2016-11-01

    Nucleosynthetic isotope anomalies are powerful tracers to determine the provenance of meteorites and their components, and to identify genetic links between these materials. Here we show that chondrules and matrix separated from the Allende CV3 chondrite have complementary nucleosynthetic Mo isotope anomalies. These anomalies result from the enrichment of a presolar carrier enriched in s-process Mo into the matrix, and the corresponding depletion of this carrier in the chondrules. This carrier most likely is a metal and so the uneven distribution of presolar material probably results from metal-silicate fractionation during chondrule formation. The Mo isotope anomalies correlate with those reported for W isotopes on the same samples in an earlier study, suggesting that the isotope variations for both Mo and W are caused by the heterogeneous distribution of the same carrier. The isotopic complementary of chondrules and matrix indicates that both components are genetically linked and formed together from one common reservoir of solar nebula dust. As such, the isotopic data require that most chondrules formed in the solar nebula and are not a product of protoplanetary impacts. Allende chondrules and matrix together with bulk carbonaceous chondrites and some iron meteorites (groups IID, IIIF, and IVB) show uniform excesses in 92Mo, 95Mo, and 97Mo that result from the addition of supernova material to the solar nebula region in which these carbonaceous meteorites formed. Non-carbonaceous meteorites (enstatite and ordinary chondrites as well as most iron meteorites) do not contain this material, demonstrating that two distinct Mo isotope reservoirs co-existed in the early solar nebula that remained spatially separated for several million years. This separation was most likely achieved through the formation of the gas giants, which cleared the disk between the inner and outer solar system regions parental to the non-carbonaceous and carbonaceous meteorites. The Mo isotope

  13. Uranium isotopic disequilibrium in ground water as an indicator of anomalies

    International Nuclear Information System (INIS)

    Osmond, J.K.; Cowart, J.B.; Ivanovich, M.

    1983-01-01

    Because of the unique elemental and isotopic properties of uranium, ground water surveys are a most appropriate approach to prospecting for surficial and secondary uranium deposits. Uranium4+ is generally immobile, but in oxidising and carbonate bearing waters U 6 + is mobile and conservative. Uranium 234 is the radiogenic daughter of 238 U. The intervening α-decay event causes recoil displacements and radioactive disequilibrium between the two isotopes in open systems such as surficial aquifers. Extreme variations in dissolved uranium composition of ground waters combined with significant variations in the ratio 234 U/ 238 U are indicative of the proximity and stage of evolution of secondary deposits. (author)

  14. Electrochemically controlled iron isotope fractionation

    Science.gov (United States)

    Black, Jay R.; Young, Edward D.; Kavner, Abby

    2010-02-01

    Variations in the stable isotope abundances of transition metals have been observed in the geologic record and trying to understand and reconstruct the physical/environmental conditions that produced these signatures is an area of active research. It is clear that changes in oxidation state lead to large fractionations of the stable isotopes of many transition metals such as iron, suggesting that transition metal stable isotope signatures could be used as a paleo-redox proxy. However, the factors contributing to these observed stable isotope variations are poorly understood. Here we investigate how the kinetics of iron redox electrochemistry generates isotope fractionation. Through a combination of electrodeposition experiments and modeling of electrochemical processes including mass-transport, we show that electron transfer reactions are the cause of a large isotope separation, while mass transport-limited supply of reactant to the electrode attenuates the observed isotopic fractionation. Furthermore, the stable isotope composition of electroplated transition metals can be tuned in the laboratory by controlling parameters such as solution chemistry, reaction overpotential, and solution convection. These methods are potentially useful for generating isotopically-marked metal surfaces for tracking and forensic purposes. In addition, our studies will help interpret stable isotope data in terms of identifying underlying electron transfer processes in laboratory and natural samples.

  15. Chromium Isotope Anomaly Scaling with Past Warming Episodes

    Science.gov (United States)

    Remmelzwaal, S.; O'Connor, L.; Preston, W.; Parkinson, I. J.; Schmidt, D. N.

    2017-12-01

    The recent expansion of oxygen minimum zones caused by anthropogenic global warming raises questions about the scale of this expansion with different emission scenarios. Ocean deoxygenation will impact marine ecosystems and fisheries demanding an assessment of the possible extent and intensity of deoxygenation. Here, we used past climate warming events to quantify a potential link between warming and the spread of oxygen minimum zones: including Ocean Anoxic Event (OAE) 1a, OAE 2 in the Cretaceous, the Palaeocene-Eocene Thermal Maximum (PETM), the Eocene Thermal Maximum 2 (ETM2), and Pleistocene glacial-interglacial cycles. We applied the emerging proxy of chromium isotopes in planktic foraminifera to assess redox changes during the PETM, ETM2, and Pleistocene and bulk carbonate for the OAEs. Both δ53Cr and chromium concentrations respond markedly during the PETM indicative of a reduction in dissolved oxygen concentrations caused by changes in ocean ventilation and associated warming [1]. A strong correlation between Δδ53Cr and benthic Δδ18O, a measure of the excursion size in both oxygen and chromium isotopes, suggest temperatures to be one of the main drivers of ocean deoxygenation in the past [1]. Chromium concentrations decrease during ETM2 and OAE1a, and, increase by 4.5 ppm over the Plenus Cold Event during OAE2, which suggests enhanced seafloor ventilation. [1] Remmelzwaal, S.R.C., Dixon, S., Parkinson, I.J., Schmidt, D.N., Monteiro, F.M., Sexton, P., Fehr, M., Peacock, C., Donnadieu, Y., James, R.H., in review. Ocean deoxygenation during the Palaeocene-Eocene Thermal Maximum. EPSL.

  16. Scale of human mobility in the southern Andes (Argentina and Chile): A new framework based on strontium isotopes.

    Science.gov (United States)

    Barberena, Ramiro; Durán, Víctor A; Novellino, Paula; Winocur, Diego; Benítez, Anahí; Tessone, Augusto; Quiroga, María N; Marsh, Erik J; Gasco, Alejandra; Cortegoso, Valeria; Lucero, Gustavo; Llano, Carina; Knudson, Kelly J

    2017-10-01

    The goal of this article is to assess the scale of human paleomobility and ecological complementarity between the lowlands and highlands in the southern Andes during the last 2,300 years. By providing isotope results for human bone and teeth samples, we assess a hypothesis of "high residential mobility" suggested on the basis of oxygen isotopes from human remains. We develop an isotopic assessment of human mobility in a mountain landscape combining strontium and oxygen isotopes. We analyze bone and teeth samples as an approach to life-history changes in spatial residence. Human samples from the main geological units and periods within the last two millennia are selected. We present a framework for the analysis of bioavailable strontium based on the combination of the geological data with isotope results for rodent samples. The 87 Sr/ 86 Sr values from human samples indicate residential stability within geological regions along life history. When comparing strontium and oxygen values for the same human samples, we record a divergent pattern: while δ 18 O values for samples from distant regions overlap widely, there are important differences in 87 Sr/ 86 Sr values. Despite the large socio-economic changes recorded, 87 Sr/ 86 Sr values indicate a persisting scenario of low systematic mobility between the different geological regions. Our results suggest that strontium isotope values provide the most germane means to track patterns of human occupation of distinct regions in complex geological landscapes, offering a much higher spatial resolution than oxygen isotopes in the southern Andes. © 2017 Wiley Periodicals, Inc.

  17. Radiogenic age and isotopic studies

    International Nuclear Information System (INIS)

    1991-01-01

    This is one of an annual collection of reports presenting data from the Geochronology Section of the Continental Geoscience Division of the Geological Survey of Canada (GSC). The main purpose of this collection is to make geochronological and other radiogenic isotope data produced by the section available promptly to the geological community. Reports make full presentation of the data, relate these to field settings and make comparatively short interpretations. Other geochronological and isotope data produced in the laboratory but published in outside journals or separate GSC publications are summarized at the end of this report. Reports in this issue give U-Pb zircon ages for rocks in Newfoundland, Yukon Territory, Manitoba, Ontario, and the Northwest Territories; present a compilation of K-Ar ages; and discuss Precambrian activity in New Brunswick, the geochronology of rock from the Northwest Territories, and reconnaissance Nd studies of rocks from the Northwest Territories. (figs., tabs., refs.)

  18. l modeling of r—diogeni™ isotopes in twoE™omponent mixing

    Indian Academy of Sciences (India)

    The mixing other by a mathematical operation, such as summa- equation for the isotopic ratio is as follows (e.g., Faure ..... physical sciences (New York: McGraw Hill) 336 p. ... Faure G 1986 Principles of isotope geology (New York: John.

  19. Stable and strontium isotopic records of molluscan shells, lower jurassic, Cuenca Neuquina, southwestern Mendoza, Argentina

    International Nuclear Information System (INIS)

    Cagnoni, M.C.; Valencio, S.A.; Ramos, A.M; Riccardi, A.C; Panarello, H.O

    2001-01-01

    The strontium, carbon and oxygen isotopic signal of the past oceans is accurately recorded by authigenic marine minerals such as carbonates, sulfates and phosphates. The variation of these isotope ratios through the geological time is used as a tool in correlating and dating marine sedimentary rocks. Many works have been done concerning to the changes in carbon, oxygen and strontium isotope ratios of different marine successions in the world. These allow the construction of curves of secular variations of the isotope signals with geological time (Jones et al., 1994a, 1994b; Veizer et al., 1999; Jacobsen and Kaufman, 1999). This work presents strontium, carbon and oxygen isotope ratios of Early Jurassic biogenic marine carbonates of Cuenca Neuquina in southwestern Mendoza (au)

  20. Multi-element isotope dilution analyses using ICP-MS

    International Nuclear Information System (INIS)

    Volpe, A.M.

    1996-01-01

    Presently, 37 elements ranging from light (Li,B) through transition metals, noble, rare earth and heavy elements, to actinides and transuranics (Pu, Am, Cm) are measured by isotope dilution at Lawrence Livermore National Laboratory. Projects range from geological and hydrological to biological. The research goal is to measure accurately many elements present in diverse matrices at trace (ppb) levels using isotope dilution methods. Major advantages of isotope dilution methods are accuracy, elimination of ion intensity calibration, and quantitation for samples that require chemical separation. Accuracy depends on tracer isotope calibration, tracer-sample isotopic equilibration, and appropriate background, isobaric and mass bias corrections. Propagation of isotope ratio error due to improper tracer isotope addition is a major concern with multi-element analyses when abundances vary widely. 11 refs., 3 figs

  1. Age and isotope evidence for the evolution of continental crust

    International Nuclear Information System (INIS)

    Moorbath, S.

    1978-01-01

    Irreversible chemical differentiation of the mantle's essentially infinite reservoir for at least the past 3800 Ma has produced new continental, sialic crust during several relatively short (ca. 100-300 Ma) episodes which were widely separated in time and may have been of global extent. During each episode (termed 'accretion-differentiation superevent'), juvenile sial underwent profound igneous, metamorphic and geochemical differentiation, resulting in thick (ca. 25-40 km), stable, compositionally gradational, largely indestructible, continental crust exhibiting close grouping of isotopic ages of rock formation, as well as mantle-type initial Sr and Pb isotopic ratios for all major constituents. Isotopic evidence suggests that within most accretion-differentiation superevents - and especially during the earlier ones - continental growth predominated over reworking of older sialic crust. Reworking of older sialic crust can occur in several types of geological environment and appears to have become more prevalent with the passage of geological time. It is usually clearly distinguishable from continental growth, by application of appropriate age and isotope data. (author)

  2. Mineral associations and character of isotopically anomalous organic material in the Tagish Lake carbonaceous chondrite

    Science.gov (United States)

    Zega, Thomas J.; Alexander, Conel M. O.'D.; Busemann, Henner; Nittler, Larry R.; Hoppe, Peter; Stroud, Rhonda M.; Young, Andrea F.

    2010-10-01

    We report a coordinated analytical study of matrix material in the Tagish Lake carbonaceous chondrite in which the same small (⩽20 μm) fragments were measured by secondary ion mass spectrometry (SIMS), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), electron energy-loss spectroscopy (EELS), and X-ray absorption near-edge spectroscopy (XANES). SIMS analysis reveals H and N isotopic anomalies (hotspots), ranging from hundreds to thousands of nanometers in size, which are present throughout the fragments. Although the differences in spatial resolution of the SIMS techniques we have used introduce some uncertainty into the exact location of the hotspots, in general, the H and N isotopic anomalies are spatially correlated with C enrichments, suggesting an organic carrier. TEM analysis, enabled by site-specific extraction using a focused-ion-beam scanning-electron microscope, shows that the hotspots contain an amorphous component, Fe-Ni sulfides, serpentine, and mixed-cation carbonates. TEM imaging reveals that the amorphous component occurs in solid and porous forms, EDS indicates that it contains abundant C, and EELS and XANES at the C K edge reveal that it is largely aromatic. This amorphous component is probably macromolecular C, likely the carrier of the isotopic anomalies, and similar to the material extracted from bulk samples as insoluble organic matter. However, given the large sizes of some of the hotspots, the disparity in spatial resolution among the various techniques employed in our study, and the phases with which they are associated, we cannot entirely rule out that some of the isotopic anomalies are carried by inorganic material, e.g., sheet silicates. The isotopic composition of the organic matter points to an initially primitive origin, quite possibly within cold interstellar clouds or the outer reaches of the solar protoplanetary disk. The association of organic material with secondary phases, e.g., serpentine

  3. Resetting of Mg isotopes between calcite and dolomite during burial metamorphism: Outlook of Mg isotopes as geothermometer and seawater proxy

    Science.gov (United States)

    Hu, Zhongya; Hu, Wenxuan; Wang, Xiaomin; Lu, Yizhou; Wang, Lichao; Liao, Zhiwei; Li, Weiqiang

    2017-07-01

    Magnesium isotopes are an emerging tool to study the geological processes recorded in carbonates. Calcite, due to its ubiquitous occurrence and the large Mg isotope fractionation associated with the mineral, has attracted great interests in applications of Mg isotope geochemistry. However, the fidelity of Mg isotopes in geological records of carbonate minerals (e.g., calcite and dolomite) against burial metamorphism remains poorly constrained. Here we report our investigation on the Mg isotope systematics of a dolomitized Middle Triassic Geshan carbonate section in eastern China. Magnesium isotope analysis was complemented by analyses of Sr-C-O isotopic compositions, major and trace element concentrations, and petrographic and mineralogical features. Multiple lines of evidence consistently indicated that post-depositional diagenesis of carbonate minerals occurred to the carbonate rocks. Magnesium isotope compositions of the carbonate rocks closely follow a mixing trend between a high δ26Mg dolomite end member and a low δ26Mg calcite end member, irrespective of sample positions in the section and calcite/dolomite ratio in the samples. By fitting the measured Mg isotope data using a two-end member mixing model, an inter-mineral Δ26Mgdolomite-calcite fractionation of 0.72‰ was obtained. Based on the experimentally derived Mg isotope fractionation factors for dolomite and calcite, a temperature of 150-190 °C was calculated to correspond to the 0.72‰ Δ26Mgdolomite-calcite fractionation. Such temperature range matches with the burial-thermal history of the local strata, making a successful case of Mg isotope geothermometry. Our results indicate that both calcite and dolomite had been re-equilibrated during burial metamorphism, and based on isotope mass balance of Mg, the system was buffered by dolomite in the section. Therefore, burial metamorphism may reset Mg isotope signature of calcite, and Mg isotope compositions in calcite should be dealt with caution in

  4. La prospection geothermique de surface au Maroc: hydrodynamisme, anomalies thermiques et indices de surfaceGeothermal prospecting in Morocco: hydrodynamics, thermal anomalies and surface indices

    Science.gov (United States)

    Zarhloule, Y.; Lahrache, A.; Ben Abidate, L.; Khattach, D.; Bouri, S.; Boukdir, A.; Ben Dhia, H.

    2001-05-01

    Shallow geothermal prospecting ( < 700 m) has been performed in four zones in Morocco for which few deep data are available: northwestern basin, northeastern basin, Tadla Basin and Agadir Basin. These areas are different geologically and hydrogeologically. The temperature data from 250 wells at depths between 15 and 500 m have been analysed in order to estimate the natural geothermal gradient in these areas, to determine the principal thermal anomalies, to identify the main thermal indices and to characterise the recharge, discharge and potential mixing limits of the aquifers. The hydrostratigraphical study of each basin revealed several potential reservoir layers in which the Turonian carbonate aquifer (Tadal and Agadir Basins) and Liassic acquifer (Moroccan northwestern and northeastern basins) are the most important hot water reservoirs in Morocco. The recharge zones of each aquifer are characterised by high topography, high water potential, shallow cold water, low geothermal gradient and negative anomalies. The discharge zones are characterized by low topography, low piezometric level, high geothermal gradient, high temperature with hot springs and positive anomalies. The main thermal indices and the principal thermal anomalies that coincide with the artesian zones of the Turonian and Liassic aquifers have been identified.

  5. Hafnium isotope ratios of nine GSJ reference samples

    International Nuclear Information System (INIS)

    Hanyu, Takeshi; Nakai, Shun'ichi; Tatsuta, Riichiro

    2005-01-01

    176 Hf/ 177 Hf ratios of nine geochemical reference rocks from the Geological Survey of Japan, together with BIR-1 and BCR-2, were determined using multi-collector inductively coupled plasma mass spectrometry. Our data for BIR-1, BCR-2 and JB-1 are in agreement with those previously reported, demonstrating the appropriateness of the chemical procedure and isotopic measurement employed in this study. The reference rocks have a wide range of 176 Hf/ 177 Hf covering the field defined by various volcanic rocks, such as mid-ocean ridge basalts, ocean island basalts, and subduction related volcanic rocks. They are therefore suitable as rock standards for Hf isotope measurement of geological samples. (author)

  6. Recent development in isotope ratio mass spectrometry

    International Nuclear Information System (INIS)

    Platzner, I.

    1992-01-01

    Within the limited of this review the following topics will be briefly discussed: a) Accuracy, precision, internal relative standard deviation (RISD) and external relative standard deviation (RESD) of isotope ratio measurements. With advanced instrumentation and use of standard reference materials, high accuracy and RESD = 0.002% (or better) may be achieved; b) The advantages of modern automatic isotope ratio mass spectrometer are briefly described. Computer controlled operation and data acquisition, and multiple ion collection are the recent important improvement; c) The isotopic fractionation during the course of isotope ratio measurement is considered as a major source of errors in thermal ionization of metallic elements. The phenomenon in strontium, neodymium, uranium, lead and calcium and methods to correct the measured data are discussed; d) Applications of isotope ratio mass spectrometry in atomic weight determinations, the isotope dilution technique, isotope geology, and isotope effects in biological systems are described together with specific applications in various research and technology area. (author)

  7. Anomalies from aerial spectrometric and total count radiometric surveys in the southeastern United States

    International Nuclear Information System (INIS)

    Lee, C.H.; Lawton, D.E.

    1978-01-01

    Aerial radiometric reconnaissance surveys are conducted because of their cost, time, and manpower savings compared to surface studies. Two types of aerial surveys are being flown in the southeastern United States: total count gamma-ray surveys for the Coastal Plains Regional Commission and the US Geological Survey, and differential gamma-ray spectrometric surveys for the US Department of Energy. Anomalous radioactivity detected during aerial surveys is related to higher concentrations of naturally occurring uranium, or to cultural activities, natural causes, or mapping errors which simulate real uranium anomalies. Each anomaly should be ground checked; however, several types of anomalies may be eliminated by evaluation of the aerial data in the office if field time is limited

  8. Isotope hydrogeochemistry in exploration for buried and blind mineralization

    International Nuclear Information System (INIS)

    Andrew, A.S.; Carr, G.R.; Giblin, A.M.; Whitford, D.J.

    2000-01-01

    Buried and blind deposits, with no direct geological or geochemical manifestation at the surface, are becoming increasingly important targets in Australia. One of the key exploration challenges relates to assessing and ranking targets established from geophysical and other remotely sensed surveys. Sub-surface geology is reflected in the geochemistry of groundwaters (Giblin, 1996) and hydrogeochemical methods provide a particularly powerful technique in areas of poor surface exposure, deep weathering and where transported overburden obscures the underlying geology (Giblin, 1997). In such areas several hundred samples are used to define locally prospective areas although how these relate to a specific mineralization style may be difficult to determine. The question of proximity to an orebody is fundamental to mineral exploration and isotopic (S, Pb, Sr) methods are uniquely capable of contributing to an answer. The isotopic composition of ores and waters that interact with ores carries important information about the elemental source; S and Pb are direct ore indicators allowing straight-forward interpretation of possible ore associations. The isotopic methods also provide unequivocal evidence for mixing. The isotopic compositions of S, Pb and Sr in rocks are unaffected by weathering and in natural waters are unaffected by precipitation, evaporation or dilution. Isotopic methods provide information that is complementary to that obtainable from major and trace element abundances. The application of integrated isotopic studies to conventional hydrogeochemical interpretations was tested in several areas (Fig. 1); Menninnie Dam (Pb, Zn; Eyre Peninsula SA), Abra (Ag, Pb; Bangemall Basin WA), Benambra (Cu, Zn, Pb: Lachlan Fold Belt Vic), Goonumbla (Cu, Au; Lachlan Fold Belt NSW) and Kanmantoo (Cu, Pb, Zn, Au; Kanmantoo Fold Belt SA). These were chosen to include different deposit types, tectonic regimes, climatic and topographic environments and groundwater chemistry

  9. Laboratory-grown coccoliths exhibit no vital effect in clumped isotope (Δ47) composition on a range of geologically relevant temperatures

    Science.gov (United States)

    Katz, Amandine; Bonifacie, Magali; Hermoso, Michaël; Cartigny, Pierre; Calmels, Damien

    2017-07-01

    The carbonate clumped isotope (or Δ47) thermometer relies on the temperature dependence of the abundance of 13C18O16O22- ion groups within the mineral lattice. This proxy shows tremendous promise to reconstruct past sea surface temperatures (SSTs), but requires calibration of the relationship between Δ47 and calcification temperatures. Specifically, it is important to determine whether biologically-driven fractionation (the so-called "vital effect") overprints Δ47 values, as reported in some biominerals such as the foraminifera and the coccoliths for the carbon and oxygen isotope systems. Despite their abundance in the pelagic environment, coccolithophores have not been comprehensively investigated to test the reliability of coccolith Δ47-inferred temperatures. In this study, we cultured three geologically-relevant coccolith species (Emiliania huxleyi, Coccolithus pelagicus, and Calcidiscus leptoporus) at controlled temperatures between 7 and 25 ± 0.2 °C. Other variables such as pCO2, pH, alkalinity, nutrient concentrations and salinity were kept constant at mean present-day oceanic conditions. Although cultured coccoliths exhibit substantial species-specific oxygen and carbon isotope vital effects, we found that their Δ47 composition follows a statistically indistinguishable relationship with 1/T2 for all three species, indicating a lack of interspecific vital effects in coccoliths. Further, the Δ47 composition of coccolith calcite is identical to inorganic calcite precipitated at the same temperature, indicating an overall absence of clumped isotope vital effect in coccolith biominerals. From a paleoceanographic perspective, this study indicates that the Δ47 values of sedimentary coccoliths - even from highly diverse/mixed assemblages - can be analyzed to reconstruct SSTs with confidence, as such temperature estimates are not biased by taxonomic content or changing interspecies vital effects through time.

  10. Z.W.O. Laboratory for Isotopic Geology

    International Nuclear Information System (INIS)

    1979-01-01

    Summaries of the 14 most important research projects performed during the reporting year are presented. These are mainly concerned with isotope dating using Rb-Sr, K-Ar and U-Pb systems. Publications on this work are listed. Activities in mineralogy and mineral separation, X-ray analysis, chemistry, mass spectrometry, alpha spectrometry and fission-track dating are outlined. Information is also included on the laboratory personnel, speeches and papers, foreign trips and fieldwork, colloguia and receptions, foreign vistors and finance. (C.F.)

  11. Geologic environmental study

    International Nuclear Information System (INIS)

    Kim, Chun Soo; Bae, Dae Seok; Kim, Kyung Su; Park, Byung Yoon; Koh, Young Kown; Chun, Kwan Sik; Kim, Jhin Wung

    2000-05-01

    The geoscience research works are focused on the production of geologic basic data accompanying with the technical development of geology and hydrogeologic characterization. The lithology of the Korean peninsula consists of a complex structure of 29 rock types from Archean to Quaternary. The wide distribution of Mesozoic plutonic rock is an important consideration as a potential host rock allowing flexibility of siting. The recent tectonic activities are limited to localized particular area, which can be avoided by excluding in the early stage of siting. Three rock types such as plutonic rocks, crystalline gneisses and massive volcanic rocks were suggested as the preferred host rocks for the further study on HLW disposal system. This report contains grouping of regional faults, and on the distributional characteristics of faults and fractures(zones) in terms of lithological domain and tectonical provinces. The regional groundwater regime can be grouped into 3 regimes by tectonic setting and four groundwater regions based on an altitute. Groundwaters can be grouped by their chemistry and host rocks. The origin of groundwater was proposed by isotope ( 1 8O, 2 H, 1 3C, 3 4S, 8 7Sr, 1 5N) studies and the residence time of groundwater was inferred from their tritium contents. Based on the geochemical and isotope characteristics, the geochemical evolutions of each types of groundwater were simulated using SOLVEQ/CHILLER and PHREEQC programs

  12. Amplitude inversion of the 2D analytic signal of magnetic anomalies through the differential evolution algorithm

    Science.gov (United States)

    Ekinci, Yunus Levent; Özyalın, Şenol; Sındırgı, Petek; Balkaya, Çağlayan; Göktürkler, Gökhan

    2017-12-01

    In this work, analytic signal amplitude (ASA) inversion of total field magnetic anomalies has been achieved by differential evolution (DE) which is a population-based evolutionary metaheuristic algorithm. Using an elitist strategy, the applicability and effectiveness of the proposed inversion algorithm have been evaluated through the anomalies due to both hypothetical model bodies and real isolated geological structures. Some parameter tuning studies relying mainly on choosing the optimum control parameters of the algorithm have also been performed to enhance the performance of the proposed metaheuristic. Since ASAs of magnetic anomalies are independent of both ambient field direction and the direction of magnetization of the causative sources in a two-dimensional (2D) case, inversions of synthetic noise-free and noisy single model anomalies have produced satisfactory solutions showing the practical applicability of the algorithm. Moreover, hypothetical studies using multiple model bodies have clearly showed that the DE algorithm is able to cope with complicated anomalies and some interferences from neighbouring sources. The proposed algorithm has then been used to invert small- (120 m) and large-scale (40 km) magnetic profile anomalies of an iron deposit (Kesikköprü-Bala, Turkey) and a deep-seated magnetized structure (Sea of Marmara, Turkey), respectively to determine depths, geometries and exact origins of the source bodies. Inversion studies have yielded geologically reasonable solutions which are also in good accordance with the results of normalized full gradient and Euler deconvolution techniques. Thus, we propose the use of DE not only for the amplitude inversion of 2D analytical signals of magnetic profile anomalies having induced or remanent magnetization effects but also the low-dimensional data inversions in geophysics. A part of this paper was presented as an abstract at the 2nd International Conference on Civil and Environmental Engineering, 8

  13. Rb-Sr and Nd-Sr isotope geochemistry and petrogenesis of the Misho Mountains mafic dikes (NW Iran

    Directory of Open Access Journals (Sweden)

    Maryam Ahankoub

    2017-02-01

    the mafic dike. Discussion Geochemistry data indicate that Misho mafic dikes are similar to calc-alkaline basalts of the oceanic island basalts (OIB whereas Nb and Ti negative anomalies of the trace elements patterns are similar to crustal contamination. Negative amount of the εNd(T indicated depleted mantel source (array mantel with some continental crust contamination during AFC processes . Base on the results of analysis, the upper crust is the best candidates for magma contamination of the mafic dikes in Misho. Isotopic data indicated to replace mafic dike 232ma years ago by closing of paleotethys and forming the extension zone (break up in active continental margin. Acknowledgement We thank Professor Yamamoto, head of geochemistry department of the Nagoya University for help .We are grateful to professor Karimpour, Chief Editor of the Journal of Economic Geology, and three anonymous reviewers for their constructive suggestions and comments. Reference Ahankoub, M., 2012. Petrogenesis and geochemistry east Misho granitoides (NW of Iran. Ph.D. Thesis, Tabriz University, Tabriz, Iran, 171 pp. (in Persian with English abstract Eftekharnejad, J., 1981. Tectonic division of Iran with respect to sedimentary basins. Journal of Iran Petroleum Society, 82(3: 19–28. (in Persian with English abstract Martin, H, 1999. Adakitic magmas: modern analogues of Archaean granitoids. Lithos, 46(3: 411–429. Metcalfe, I., 2006. Paleozoic and Mesozoic tectonic evolution and palaeogeography of East Asian crustal fragments: the Korean Peninsula in context. Gondwana Research, 9(1-2: 24–46. Moayyed, M. and Hossainzade, G., 2011. Petrology and petroghraphy of A- type Granitoides of the East-Misho Mountain with theory on its geodynamic importance. Journal of Mineralogy and Crystalography, 3(19: 529–544. (in Persian with English abstract Sun, S.S. and McDonough, W.F., 1989. Chemical and isotopic systematic of ocean basalts: implications for mantle composition and process. In: A

  14. Could a secular increase in organic burial explain the rise of oxygen? Insights from a geological carbon cycle model constrained by the carbon isotope record

    Science.gov (United States)

    Krissansen-Totton, J.; Kipp, M.; Catling, D. C.

    2017-12-01

    The stable isotopes of carbon in marine sedimentary rock provide a window into the evolution of the Earth system. Conventionally, a relatively constant carbon isotope ratio in marine sedimentary rocks has been interpreted as implying constant organic carbon burial relative to total carbon burial. Because organic carbon burial corresponds to net oxygen production from photosynthesis, it follows that secular changes in the oxygen source flux cannot explain the dramatic rise of oxygen over Earth history. Instead, secular declines in oxygen sink fluxes are often invoked as causes for the rise of oxygen. However, constant fractional organic burial is difficult to reconcile with tentative evidence for low phosphate concentrations in the Archean ocean, which would imply lower marine productivity and—all else being equal—less organic carbon burial than today. The conventional interpretation of the carbon isotope record rests on the untested assumption that the isotopic ratio of carbon inputs into the ocean reflect mantle isotopic values throughout Earth history. In practice, differing rates of carbonate and organic weathering will allow for changes in isotopic inputs, as suggested by [1] and [2]. However, these inputs can not vary freely because large changes in isotopic inputs would induce secular trends in carbon reservoirs, which are not observed in the isotope record. We apply a geological carbon cycle model to all Earth history, tracking carbon isotopes in crustal, mantle, and ocean reservoirs. Our model is constrained by the carbon isotope record such that we can determine the extent to which large changes in organic burial are permitted. We find both constant organic burial and 3-5 fold increases in organic burial since 4.0 Ga can be reconciled with the carbon isotope record. Changes in the oxygen source flux thus need to be reconsidered as a possible contributor to Earth's oxygenation. [1] L. A. Derry, Organic carbon cycling and the lithosphere, in Treatise on

  15. Constraining new physics models with isotope shift spectroscopy

    Science.gov (United States)

    Frugiuele, Claudia; Fuchs, Elina; Perez, Gilad; Schlaffer, Matthias

    2017-07-01

    Isotope shifts of transition frequencies in atoms constrain generic long- and intermediate-range interactions. We focus on new physics scenarios that can be most strongly constrained by King linearity violation such as models with B -L vector bosons, the Higgs portal, and chameleon models. With the anticipated precision, King linearity violation has the potential to set the strongest laboratory bounds on these models in some regions of parameter space. Furthermore, we show that this method can probe the couplings relevant for the protophobic interpretation of the recently reported Be anomaly. We extend the formalism to include an arbitrary number of transitions and isotope pairs and fit the new physics coupling to the currently available isotope shift measurements.

  16. Z.W.O. Laboratory for isotope geology

    International Nuclear Information System (INIS)

    1980-01-01

    Accounts of a number of research projects, performed in the reporting year, are presented. Many of these involved isotope dating methods using the Rb-Sr, K-Ar and U-Pb systems. This is followed by a survey of associated publications. General details regarding staff, finance, conference, visits, vistors, etc. are given and a brief account of the activities is presented under the following subject areas - mineralogy and mineral separation, X-ray analysis, chemistry, mass spectrometry, electronics and computing, alpha spectrometry and fission track dating. (C.F.)

  17. Development of analytical techniques for determining rare earth elements in geological materials

    International Nuclear Information System (INIS)

    Moraes, Noemia M.P. de; Kakazu, M.H.; Iyer, S.S.

    1987-01-01

    This work presents a comparative study between instrumental neutron activation analysis, inductively coupled plasma emission spectrometry and mass spectrometric isotope dilution techniques. Some advantages and disadvantages of the techniques are presented, depending on the type of the analysis required. Emphasis in give upon mass spectrometric isotope dilution, and some procedures for the development of this technique are presented. This methodology is being established by the nuclear and isotopic geology group of the IPEN. (author) [pt

  18. Radiogenic age and isotopic studies

    International Nuclear Information System (INIS)

    Parrish, R.R.

    1990-01-01

    This is one of an annual collection of reports presenting data from the Geochronology Section of the Continental Geoscience Division of the Geological Survey of Canada (GSC). The main purpose of this collection is to make geochronological and other radiogenic isotope data produced by the section available promptly to the geological community. Reports make full presentation of the data, relate these to field settings and make comparatively short interpretations. Other geochronological and isotope data produced in the laboratory but published in outside journals or separate GSC publications are summarized at the end of this report. Reports in this issue cover methods for Rb-Sr and Sm-Nd isotopic analyses; 40 Ar- 39 Ar ages for the New Quebec Crater and for basaltic rocks; U-Pb ages for a differentiated mafic sill in the Ogilvie Mountains, plutonic rocks in the Contwoyto-Nose Lakes are, zircons from the Anton Complex, the Clinton-Colden gabbro-anorthosite intrusion, the Himag plutonic suite, the Campbell granite, the Central Gneiss Belt, Silurian granites, a metarhyolite, plagiogranite and gabbro, and the Wage shear zone; Rb-Sr ages for granitic rocks; K-Ar and Rb-Sr geochronology of granites; a compilation of K-Ar ages; ages of archean and proterozoic mylonites and pre-Misi granitoid domes; and reconnaissance geochronology of Baffin Island

  19. Geologic Map of the Helen Planitia Quadrangle (V-52), Venus

    Science.gov (United States)

    Lopez, Ivan; Hansen, Vicki L.

    2008-01-01

    The Magellan spacecraft orbited Venus from August 10, 1990, until it plunged into the Venusian atmosphere on October 12, 1994. Magellan Mission objectives included (1) improving the knowledge of the geological processes, surface properties, and geologic history of Venus by analysis of surface radar characteristics, topography, and morphology and (2) improving the knowledge of the geophysics of Venus by analysis of Venusian gravity. The Helen Planitia quadrangle (V-52), located in the southern hemisphere of Venus between lat 25 deg S. and 50 deg S. and between long 240 deg E. and 270 deg E., covers approximately 8,000,000 km2. Regionally, the map area is located at the southern limit of an area of enhanced tectonomagmatic activity and extensional deformation, marked by a triangle that has highland apexes at Beta, Atla, and Themis Regiones (BAT anomaly) and is connected by the large extensional belts of Devana, Hecate, and Parga Chasmata. The BAT anomaly covers approximately 20 percent of the Venusian surface.

  20. Methods for Enhancing Geological Structures in Spectral Spatial Difference-Based on Remote-Sensing Image

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    @@In this paper, some image processing methods such as directional template (mask) matching enhancement, pseudocolor or false color enhancement, K-L transform enhancement are used to enhance a geological structure, one of important ore-controlling factors, shown in the remote-sensing images.This geological structure is regarded as image anomaly in the remote-sensing image, since considerable differences, based on the spatial spectral distribution pattern, in gray values (spectral), color tones and texture, are always present between the geological structure and background. Therefore,the enhancement of the geological structure in the remotesensing image is that of the spectral spatial difference.

  1. Gravity and isostatic anomaly maps of Greece produced

    Science.gov (United States)

    Lagios, E.; Chailas, S.; Hipkin, R. G.

    A gravity anomaly map of Greece was first compiled in the early 1970s [Makris and Stavrou, 1984] from all available gravity data collected by different Hellenic institutions. However, to compose this map the data had to be smoothed to the point that many of the smaller-wavelength gravity anomalies were lost. New work begun in 1987 has resulted in the publication of an updated map [Lagios et al., 1994] and an isostatic anomaly map derived from it.The gravity data cover the area between east longitudes 19° and 27° and north latitudes 32° and 42°, organized in files of 100-km squares and grouped in 10-km squares using UTM zone 34 coordinates. Most of the data on land come from the gravity observations of Makris and Stavrou [1984] with additional data from the Institute of Geology and Mining Exploration, the Public Oil Corporation of Greece, and Athens University. These data were checked using techniques similar to those used in compiling the gravity anomaly map of the United States, but the horizontal gradient was used as a check rather than the gravity difference. Marine data were digitized from the maps of Morelli et al. [1975a, 1975b]. All gravity anomaly values are referred to the IGSN-71 system, reduced with the standard Bouger density of 2.67 Mg/m3. We estimate the errors of the anomalies in the continental part of Greece to be ±0.9 mGal; this is expected to be smaller over fairly flat regions. For stations whose height has been determined by leveling, the error is only ±0.3 mGal. For the marine areas, the errors are about ±5 mGal [Morelli, 1990].

  2. Geologic-radiometric techniques applied for uranium prospection at the Hierro-Cayo Largo area

    International Nuclear Information System (INIS)

    Gongora, L.E.; Olivera, J.

    1995-01-01

    Using geologic-radiometric techniques uraniferous anomalies were evaluated at the Hierro-Cayo Largo area located in Pinar del Rio province. During the uranium prospection works at most promising areas, geologic itineraries and gamma ray, radon emanation spectrometric survey were done. Trenches were made and some boreholes were drilled (up to 20-30 m depth). In addition a lot of samples were taken in order to determine the amount of U, Ra, Th, y K by spectrometric techniques. As result of this investigation, a geological placing, a mineralogical and geochemical characteristic of uraniferous mineralization was possible to find out. The appropriate prospection indications for uranium exploration at Esperanza geologic zone were defined

  3. Studies in the determination of lead isotope ratios by inductively coupled plasma mass spectrometry

    International Nuclear Information System (INIS)

    Date, A.R.; Yuk Ying Cheung

    1987-01-01

    The application of ICP-MS to the determination of lead isotope ratios in geological materials is described. Data presented for a series of lead mineral concentrates are compared with reference values obtained by conventional solid source thermal ionisation mass spectrometry. The simultaneous determination of lead isotope ratios and trace elements is carried out in a rapid analysis mode. The application of an electrothermal vaporisation technique for small solution aliquots is described. Lead isotope ratio data for the United States Geological Survey standard reference silicate rock BCR-1, obtained without separation of lead from the matrix, are compared with previously published values obtained after separation. (author)

  4. Ultra-high-precision Nd-isotope measurements of geological materials by MC-ICPMS

    DEFF Research Database (Denmark)

    Saji, Nikitha Susan; Wielandt, Daniel Kim Peel; Paton, Chad

    2016-01-01

    We report novel techniques allowing the measurement of Nd-isotope ratios with unprecedented accuracy and precision by multi-collector inductively coupled plasma mass spectrometry. Using the new protocol, we have measured the Nd-isotopic composition of rock and synthetic Nd standards as well as th...

  5. A three-dimensional model of the Pyrenees and their foreland basins from geological and gravimetric data

    Science.gov (United States)

    Wehr, H.; Chevrot, S.; Courrioux, G.; Guillen, A.

    2018-06-01

    We construct a three-dimensional geological model of the Pyrenees and their foreland basins with the Geomodeller. This model, which accounts for different sources of geological and geophysical informations, covers the whole Pyrenees, from the Atlantic Ocean to the Mediterranean Sea, and from the Iberian range to the Massif Central, down to 70 km depth. We model the geological structure with a stratigraphic column composed of a superposition of layers representing the mantle, lower, middle, and upper crusts. The sedimentary basins are described by two layers which allow us to make the distinction between Mesozoic and Cenozoic sediments, which are characterized by markedly different densities and seismic velocities. Since the Pyrenees result from the convergence between the Iberian and European plates, we ascribe to each plate its own stratigraphic column in order to be able to model the imbrication of Iberian and European crusts along this fossile plate boundary. We also introduce two additional units which describe the orogenic prism and the water column in the Bay of Biscay and in the Mediterranean Sea. The last ingredient is a unit that represents bodies of shallow exhumed and partly serpentinized lithospheric mantle, which are assumed to produce the positive Bouguer gravity anomalies in the North Pyrenean Zone. A first 3D model is built using only the geological information coming from geological maps, drill-holes, and seismic sections. We use the potential field method implemented in Geomodeller to interpolate these geological data. This model is then refined in order to better explain the observed Bouguer anomalies by adding new constraints on the main crustal interfaces. The final model explains the observed Bouguer anomalies with a standard deviation less than 3.4 mGal, and reveals anomalous deep structures beneath the eastern Pyrenees.

  6. Regional mantle upwelling on Venus: The Beta-Atla-Themis anomaly and correlation with global tectonic patterns

    Science.gov (United States)

    Crumpler, L. S.; Head, J. W.; Aubele, Jayne C.

    1993-01-01

    The morphology and global distribution of volcanic centers and their association with other geological characteristics offers significant insight into the global patterns of geology, tectonic style, thermal state, and interior dynamics of Venus. Magellan data permit the detailed geological interpretation necessary to address questions about interior dynamics of Venus particularly as they reflect relatively physical, chemical, and thermal conditions of the interior. This paper focuses on the distribution of anomalous concentrations of volcanic centers on Venus and regional patterns of tectonic deformation as it may relate to the identification of global internal anomalies, including mantle dynamic, petrological, or thermal patterns.

  7. Ion-microprobe measurements of Mg, Ca, Ti and Fe isotopic ratios and trace element abundance in hibonite-bearing inclusions in primitive meteorites

    International Nuclear Information System (INIS)

    Fahey, A.J.

    1988-01-01

    This thesis reports the isotopic abundances of Mg, Ca, and Ti and rare earth element (REE) abundances in 19 hibonite-bearing inclusions from primative meteorites. The isotopic ratios of Fe were measured in one of the samples, Lance HH-1. These measurements were made by means of secondary ion mass spectrometry (CAMECA IMS-3f). The novel hardware and software developments that made this work possible are described in detail. The samples were studied in thin section in order to investigate the relationship between the inclusions and their mineralogical environments. Inclusions from a number of different meteorites, specifically, Mighei, Murray, Murchison, Lance, Efremovka, Vigarano, Qingzhen, Dhajala, and Semarkona, were studied. The isotopes of Ca and Ti show large and correlated abundance anomalies in their most neutron-rich isotopes, 48 Ca and 50 Ti. The largest anomalies among the samples studied here are in the Murray inclusion MY-F6, with a 4.6% deficit in 48 Ca and a 5.2% deficit in 50 Ti, and Lance HH-1, with 3.3% and 6.0% deficits in 48 Ca and 50 Ti respectively. Correlated excesses of 48 Ca and 50 Ti, up to 2.4% and 1.4% respectively, are found in some other samples studied here. The fact that there is a correlation of isotopic anomalies in two different elements is clear evidence for a nucleosynthetic origin of these effects. Various possibilities for the origin of these isotopic anomalies are discussed and it is shown that a Cosmic Chemical Memory-like model of the incomplete mixing of dust grains from one or several supernovae is sufficient to explain the data. Magnesium isotopes show excesses of 26 Mg, attributable to the in-situ decay of 26 Al, in 7 of these inclusions

  8. Isotope composition and volume of Earth´s early oceans

    DEFF Research Database (Denmark)

    Pope, Emily Catherine; Bird, Dennis K.; Rosing, Minik Thorleif

    2012-01-01

    Oxygen and hydrogen isotope compositions of Earth´s seawater are controlled by volatile fluxes among mantle, lithospheric (oceanic and continental crust), and atmospheric reservoirs. Throughout geologic time the oxygen mass budget was likely conserved within these Earth system reservoirs, but hyd...... in Earth´s oceans. Our calculations predict that the oceans of early Earth were up to 26% more voluminous, and atmospheric CH4 and CO2 concentrations determined from limits on hydrogen escape to space are consistent with clement conditions on Archaean Earth.......Oxygen and hydrogen isotope compositions of Earth´s seawater are controlled by volatile fluxes among mantle, lithospheric (oceanic and continental crust), and atmospheric reservoirs. Throughout geologic time the oxygen mass budget was likely conserved within these Earth system reservoirs......, but hydrogen´s was not, as it can escape to space. Isotopic properties of serpentine from the approximately 3.8 Ga Isua Supracrustal Belt in West Greenland are used to characterize hydrogen and oxygen isotope compositions of ancient seawater. Archaean oceans were depleted in deuterium [expressed as Î...

  9. Water isotope systematics: Improving our palaeoclimate interpretations

    Science.gov (United States)

    Jones, M. D.; Dee, S.; Anderson, L.; Baker, A.; Bowen, G.; Noone, D.

    2016-01-01

    The stable isotopes of oxygen and hydrogen, measured in a variety of archives, are widely used proxies in Quaternary Science. Understanding the processes that control δ18O change have long been a focus of research (e.g. Shackleton and Opdyke, 1973; Talbot, 1990 ; Leng, 2006). Both the dynamics of water isotope cycling and the appropriate interpretation of geological water-isotope proxy time series remain subjects of active research and debate. It is clear that achieving a complete understanding of the isotope systematics for any given archive type, and ideally each individual archive, is vital if these palaeo-data are to be used to their full potential, including comparison with climate model experiments of the past. Combining information from modern monitoring and process studies, climate models, and proxy data is crucial for improving our statistical constraints on reconstructions of past climate variability.As climate models increasingly incorporate stable water isotope physics, this common language should aid quantitative comparisons between proxy data and climate model output. Water-isotope palaeoclimate data provide crucial metrics for validating GCMs, whereas GCMs provide a tool for exploring the climate variability dominating signals in the proxy data. Several of the studies in this set of papers highlight how collaborations between palaeoclimate experimentalists and modelers may serve to expand the usefulness of palaeoclimate data for climate prediction in future work.This collection of papers follows the session on Water Isotope Systematics held at the 2013 AGU Fall Meeting in San Francisco. Papers in that session, the breadth of which are represented here, discussed such issues as; understanding sub-GNIP scale (Global Network for Isotopes in Precipitation, (IAEA/WMO, 2006)) variability in isotopes in precipitation from different regions, detailed examination of the transfer of isotope signals from precipitation to geological archives, and the

  10. Calcium Isotope Analysis by Mass Spectrometry

    Science.gov (United States)

    Boulyga, S.; Richter, S.

    2010-12-01

    The variations in the isotopic composition of calcium caused by fractionation in heterogeneous systems and by nuclear reactions can provide insight into numerous biological, geological, and cosmic processes, and therefore isotopic analysis finds a wide spectrum of applications in cosmo- and geochemistry, paleoclimatic, nutritional, and biomedical studies. The measurement of calcium isotopic abundances in natural samples has challenged the analysts for more than three decades. Practically all Ca isotopes suffer from significant isobaric interferences, whereas low-abundant isotopes can be particularly affected by neighboring major isotopes. The extent of natural variations of stable isotopes appears to be relatively limited, and highly precise techniques are required to resolve isotopic effects. Isotope fractionation during sample preparation and measurements and instrumental mass bias can significantly exceed small isotope abundance variations in samples, which have to be investigated. Not surprisingly, a TIMS procedure developed by Russell et al. (Russell et al., 1978. Geochim Cosmochim Acta 42: 1075-1090) for Ca isotope measurements was considered as revolutionary for isotopic measurements in general, and that approach is used nowadays (with small modifications) for practically all isotopic systems and with different mass spectrometric techniques. Nevertheless, despite several decades of calcium research and corresponding development of mass spectrometers, the available precision and accuracy is still not always sufficient to achieve the challenging goals. This presentation discusses figures of merits of presently used analytical methods and instrumentation, and attempts to critically assess their limitations. Additionally, the availability of Ca isotope reference materials will be discussed.

  11. Stable Isotope Group progress report for the period July 1989-June 1990

    Energy Technology Data Exchange (ETDEWEB)

    Lyon, G L [Nuclear Sciences Group, DSIR Physical Sciences, Lower Hutt (New Zealand)

    1991-07-01

    The work of the stable isotope and geochronology laboratories in 1989-90 continued to emphasise geochemical and geological applications of mass spectrometry. Research included studies in mass spectrometer instrumentation, atmospheric science, isotope hydrology, geology and biology. A new sulphur isotope reference solid was prepared for international distribution. Geochronological research has included work on the dating and petrogenesis of Taupo Volcanic Zone eruptives, Coromandel Peninsula volcanics, Canterbury-Marlborough plutonics and volcanics, the Subantarctic Islands, West Coast granitoids and the schists and greywackes of New Zealand. Oxygen isotopes continue to be valuable in the study of geothermal systems and of a fossil geothermal system in Fiordland rocks. Geothermal studies have included work in El Salvador as well as a major new study of the Rotorua geothermal system. Atmospheric studies have concentrated on the applications of isotope ratios especially 13C/12C in the trace gases CH4 and CO. Groundwater research on the role of the unsaturated zone continued, and studies of the 14C and 13C content of deep groundwaters of Poverty Bay and Marlborough were carried out. Isotope variations in groundwater near faults are being monitored to look for earthquake precursors. (author). 45 refs., 1 fig.

  12. Stable Isotope Group progress report for the period July 1989-June 1990

    International Nuclear Information System (INIS)

    Lyon, G.L.

    1991-01-01

    The work of the stable isotope and geochronology laboratories in 1989-90 continued to emphasise geochemical and geological applications of mass spectrometry. Research included studies in mass spectrometer instrumentation, atmospheric science, isotope hydrology, geology and biology. A new sulphur isotope reference solid was prepared for international distribution. Geochronological research has included work on the dating and petrogenesis of Taupo Volcanic Zone eruptives, Coromandel Peninsula volcanics, Canterbury-Marlborough plutonics and volcanics, the Subantarctic Islands, West Coast granitoids and the schists and greywackes of New Zealand. Oxygen isotopes continue to be valuable in the study of geothermal systems and of a fossil geothermal system in Fiordland rocks. Geothermal studies have included work in El Salvador as well as a major new study of the Rotorua geothermal system. Atmospheric studies have concentrated on the applications of isotope ratios especially 13C/12C in the trace gases CH4 and CO. Groundwater research on the role of the unsaturated zone continued, and studies of the 14C and 13C content of deep groundwaters of Poverty Bay and Marlborough were carried out. Isotope variations in groundwater near faults are being monitored to look for earthquake precursors. (author). 45 refs., 1 fig

  13. Geologic environmental study

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chun Soo; Bae, Dae Seok; Kim, Kyung Su; Park, Byung Yoon; Koh, Young Kown; Chun, Kwan Sik; Kim, Jhin Wung

    2000-05-01

    The geoscience research works are focused on the production of geologic basic data accompanying with the technical development of geology and hydrogeologic characterization. The lithology of the Korean peninsula consists of a complex structure of 29 rock types from Archean to Quaternary. The wide distribution of Mesozoic plutonic rock is an important consideration as a potential host rock allowing flexibility of siting. The recent tectonic activities are limited to localized particular area, which can be avoided by excluding in the early stage of siting. Three rock types such as plutonic rocks, crystalline gneisses and massive volcanic rocks were suggested as the preferred host rocks for the further study on HLW disposal system. This report contains grouping of regional faults, and on the distributional characteristics of faults and fractures(zones) in terms of lithological domain and tectonical provinces. The regional groundwater regime can be grouped into 3 regimes by tectonic setting and four groundwater regions based on an altitute. Groundwaters can be grouped by their chemistry and host rocks. The origin of groundwater was proposed by isotope ({sup 1}8O, {sup 2}H, {sup 1}3C, {sup 3}4S, {sup 8}7Sr, {sup 1}5N) studies and the residence time of groundwater was inferred from their tritium contents. Based on the geochemical and isotope characteristics, the geochemical evolutions of each types of groundwater were simulated using SOLVEQ/CHILLER and PHREEQC programs.

  14. Heat flow anomalies and their interpretation

    Science.gov (United States)

    Chapman, David S.; Rybach, Ladislaus

    1985-12-01

    More than 10,000 heat flow determinations exist for the earth and the data set is growing steadily at about 450 observations per year. If heat flow is considered as a surface expression of geothermal processes at depth, the analysis of the data set should reveal properties of those thermal processes. They do, but on a variety of scales. For this review heat flow maps are classified by 4 different horizontal scales of 10 n km (n = 1, 2, 3 and 4) and attention is focussed on the interpretation of anomalies which appear with characteristic dimensions of 10 (n - 1) km in the respective representations. The largest scale of 10 4 km encompasses heat flow on a global scale. Global heat loss is 4 × 10 13 W and the process of sea floor spreading is the principal agent in delivering much of this heat to the surface. Correspondingly, active ocean ridge systems produce the most prominent heat flow anomalies at this scale with characteristic widths of 10 3 km. Shields, with similar dimensions, exhibit negative anomalies. The scale of 10 3 km includes continent wide displays. Heat flow patterns at this scale mimic tectonic units which have dimensions of a few times 10 2 km, although the thermal boundaries between these units are sometimes sharp. Heat flow anomalies at this scale also result from plate tectonic processes, and are associated with arc volcanism, back arc basins, hot spot traces, and continental rifting. There are major controversies about the extent to which these surface thermal provinces reflect upper mantle thermal conditions, and also about the origin and evolution of the thermal state of continental lithosphere. Beginning with map dimensions of 10 2 km thermal anomalies of scale 10 1 km, which have a definite crustal origin, become apparent. The origin may be tectonic, geologic, or hydrologic. Ten kilometers is a common wavelength of topographic relief which drives many groundwater flow systems producing thermal anomalies. The largest recognized continental

  15. Geological, geochemical and isotopic characteristics of the Archaean Kaap Valley pluton, Barberton mountain land, South Africa

    International Nuclear Information System (INIS)

    Robb, L.J.; Barton, J.M. Jr.; Kable, E.J.D.; Wallace, R.C.

    1984-01-01

    The Kaap Valley pluton consists predominantly of a homogeneous weakly foliated, hornblende-bearing tonalite. It is among the oldest granitoid bodies yet recognized in the environs of the Barberton greenstone belt, yielding 207 Pb/ 206 Pb mineral ages of about 3300 Ma and a Rb-Sr whole rock isochron age of about 3500 Ma. The Kaap Valley pluton is distinctive in many respects. Whereas all other gneiss plutons in the area are characterized by a trondhjemitic bulk composition with mafic mineralogies dominated by biotite, the Kaap Valley pluton is tonalitic in bulk composition with hornblende (plus minus minor biotite) as its major mafic phase. In this paper, the results of a detailed geological, geochemical and Pb-isotopic study of the Kaap Valley pluton are presented. Questions relating to the origin of the body are considered, with an emphasis on the formation of a tonalitic magma which is more mafic than those typically encountered in the region. Although exposure does not permit a detailed structural study of the gneiss pluton consideration is given to its mode of emplacement

  16. Iron isotopic systematics of oceanic basalts

    Science.gov (United States)

    Teng, Fang-Zhen; Dauphas, Nicolas; Huang, Shichun; Marty, Bernard

    2013-04-01

    The iron isotopic compositions of 93 well-characterized basalts from geochemically and geologically diverse mid-ocean ridge segments, oceanic islands and back arc basins were measured. Forty-three MORBs have homogeneous Fe isotopic composition, with δ56Fe ranging from +0.07‰ to +0.14‰ and an average of +0.105 ± 0.006‰ (2SD/√n, n = 43, MSWD = 1.9). Three back arc basin basalts have similar δ56Fe to MORBs. By contrast, OIBs are slightly heterogeneous with δ56Fe ranging from +0.05‰ to +0.14‰ in samples from Koolau and Loihi, Hawaii, and from +0.09‰ to +0.18‰ in samples from the Society Islands and Cook-Austral chain, French Polynesia. Overall, oceanic basalts are isotopically heavier than mantle peridotite and pyroxenite xenoliths, reflecting Fe isotope fractionation during partial melting of the mantle. Iron isotopic variations in OIBs mainly reflect Fe isotope fractionation during fractional crystallization of olivine and pyroxene, enhanced by source heterogeneity in Koolau samples.

  17. Geological interpretation of Eastern Cuba Laterites from an airborne magnetic and radioactive isotope survey

    Energy Technology Data Exchange (ETDEWEB)

    Batista, J.A; Blanco, J [Departamento de Geologia, Instituto Superior Minero Metalurgico de Moa, (Cuba); Perez-Flores, M.A [Centro de Investigacion Cientifica y Educacion Superior de Ensenada, Baja California (Mexico)

    2008-04-15

    In eastern Cuba area several geophysical techniques have been applied to distinguish the main geological characteristics of the laterites which are of economical importance for the extraction of iron, nickel and chrome. The geophysical measurements include an aeromagnetic survey and thorium (eTh), potassium (K) and uranium (eU) isotope measurements. The results of gamma spectrometer measurements make a distinction between laterite reservoirs. The application of the magnetic and isotope methods allowed the determination of the distribution and development of the laterite crust, as well as the determination of hydrothermal alterations affecting the laterites, which is very useful for mining exploration and exploitation. Such alterations indicate the presence of silicates, which have negative effects on the metallurgic process. It is known that laterite crust has a high content of eU and eTh. [Spanish] Se han utilizado varias tecnicas geofisicas en la region oriental de Cuba para distinguir las principales caracteristicas geologicas de las lateritas, que poseen importancia economica para la extraccion de hierro, niquel y cobalto. Las mediciones geofisicas incluyen un estudio aeromagnetico y mediciones de isotopos de torio (eTh), potasio (K) y uranio (eU). Los resultados de las mediciones espectrometricas establecen diferencias entre los yacimientos de lateritas. De la aplicacion del metodo magnetico e isotopico se determino la distribucion y desarrollo de las cortezas lateriticas, asi como la ubicacion de alteraciones hidrotermales que afectan a las lateritas, lo cual es muy util durante la exploracion y explotacion minera. Esas alteraciones indican la presencia de silicatos, que tienen un efecto negativo en el proceso metalurgico. Se conoce que las cortezas lateriticas tienen altos contenidos de eU y eTh. De los contenidos de eU y eTh se infiere que las lateritas de la region de Moa se formaron antes que las de Mayari. De estas mediciones fue posible inferir el

  18. Study of gases in six geologic faults in the Narino Department

    International Nuclear Information System (INIS)

    Moran Rodriguez, C; Chica Sanchez, A; Garzon Valencia, G

    2001-01-01

    Radon-222 and Carbon Dioxide emissions on the Manchabajoy, Pasto, Buesaco, Guaitara, Ancuya and Magdalena geological faults in the Narino Department were studied. As example of environmental influences like rainfall on the gas emissions in the San Francisco station, located in the Manchabajoy, Ancuya and Guaitara faults intersection was presented. Another environmental perturbations, like air temperature and atmospheric pressure no varies too much and minimum influence gas emissions from soils. In the first semester of the 2000, several radon anomalies in six stations of the volcanological and seismological observatory of Pasto were registered. After cited Radon anomalies inhabitants of Pasto city filled a seismic swarm in July months, and probably a correlation between radon anomalies and detected seismic signals have to be taken into account

  19. ADMAP-2: The second generation Antarctic crustal magnetic anomaly map.

    Science.gov (United States)

    Ferraccioli, F.; Golynsky, A.; Golynsky, D.; Young, D. A.; Eagles, G.; Damaske, D.; Finn, C.; Aitken, A.; von Frese, R. R. B.; Ghidella, M. E.; Kim, H. R.; Hong, J.

    2017-12-01

    ADMAP-2 is the second generation crustal magnetic anomaly compilation for the Antarctic region south of 60°S. It was produced from more than 3.5 million line-km of near-surface terrestrial, airborne and marine magnetic observations collected since the International Geophysical Year 1957/58 through 2013. The data were edited, IGRF corrected, profile levelled and gridded at a 1.5-km interval on a polar stereographic projection using the minimum curvature technique. Given the ubiquitous polar cover of snow, ice and sea water, the magnetic anomaly compilation offers important constraints on the global tectonic processes and crustal properties of the Antarctic. It also links widely separated areas of outcrop to help unify disparate geologic studies, and provides insights on the lithospheric transition between Antarctica and adjacent oceans, as well as the geodynamic evolution of the Antarctic lithosphere in the assembly and break-up of the Gondwana, Rodinia, and Columbia supercontinents and key piercing points for reconstructing linkages between the protocontinents. The magnetic data together with ice-probing radar and gravity information greatly facilitate understanding the evolution of fundamental large-scale geological processes such as continental rifting, intraplate mountain building, subduction and terrane accretion processes, and intraplate basin formation.

  20. Elevation Difference and Bouguer Anomaly Analysis Tool (EDBAAT) User's Guide

    Science.gov (United States)

    Smittle, Aaron M.; Shoberg, Thomas G.

    2017-06-16

    This report describes a software tool that imports gravity anomaly point data from the Gravity Database of the United States (GDUS) of the National Geospatial-Intelligence Agency and University of Texas at El Paso along with elevation data from The National Map (TNM) of the U.S. Geological Survey that lie within a user-specified geographic area of interest. Further, the tool integrates these two sets of data spatially and analyzes the consistency of the elevation of each gravity station from the GDUS with TNM elevation data; it also evaluates the consistency of gravity anomaly data within the GDUS data repository. The tool bins the GDUS data based on user-defined criteria of elevation misfit between the GDUS and TNM elevation data. It also provides users with a list of points from the GDUS data, which have Bouguer anomaly values that are considered outliers (two standard deviations or greater) with respect to other nearby GDUS anomaly data. “Nearby” can be defined by the user at time of execution. These outputs should allow users to quickly and efficiently choose which points from the GDUS would be most useful in reconnaissance studies or in augmenting and extending the range of individual gravity studies.

  1. Geological and structural interpretation of Peninsular Malaysia by marine and aeromagnetic data: Some preliminary results

    Science.gov (United States)

    Bahrudin, Nurul Fairuz Diyana Binti; Hamzah, Umar

    2016-11-01

    Magnetic data were processed to interpret the geology of Peninsular Malaysia especially in delineating the igneous bodies and structural lineament trends by potential field geophysical method. A total of about 32000 magnetic intensity data were obtained from Earth Magnetic Anomaly Grid (EMAG2) covering an area of East Sumatra to part of South China Sea within 99° E to 105° E Longitude and 1° N to 7°N Latitude. These data were used in several processing stages in generating the total magnetic intensity (TMI), reduce to equator (RTE), total horizontal derivative (THD) and total vertical derivative (TVD). Values of the possible surface and subsurface magnetic sources associated to the geological features of the study area. The magnetic properties are normally corresponding to features like igneous bodies and faults structures. The anomalies obtained were then compared to the geological features of the area. In general, the high magnetic anomalies of the TMI-RTE are closely matched with major igneous intrusion of Peninsular Malaysia such as the Main Range, Eastern Belt and the Mersing-Johor Bahru stretch. More dense lineaments of magnetic structures were observed in the THD and TVD results indicating the presence of more deep and shallow magnetic rich geological features. The positions of Bukit Tinggi, Mersing and Lepar faults are perfectly matched with the magnetic highs while the presence of Lebir and Bok Bak faults are not clearly observed in the magnetic results. The high magnetic values of igneous bodies may have concealed and obscured the magnetic values representing these faults.

  2. A multielement isotopic study of refractory FUN and F CAIs: Mass-dependent and mass-independent isotope effects

    Science.gov (United States)

    Kööp, Levke; Nakashima, Daisuke; Heck, Philipp R.; Kita, Noriko T.; Tenner, Travis J.; Krot, Alexander N.; Nagashima, Kazuhide; Park, Changkun; Davis, Andrew M.

    2018-01-01

    Calcium-aluminum-rich inclusions (CAIs) are the oldest dated objects that formed inside the Solar System. Among these are rare, enigmatic objects with large mass-dependent fractionation effects (F CAIs), which sometimes also have large nucleosynthetic anomalies and a low initial abundance of the short-lived radionuclide 26Al (FUN CAIs). We have studied seven refractory hibonite-rich CAIs and one grossite-rich CAI from the Murchison (CM2) meteorite for their oxygen, calcium, and titanium isotopic compositions. The 26Al-26Mg system was also studied in seven of these CAIs. We found mass-dependent heavy isotope enrichment in all measured elements, but never simultaneously in the same CAI. The data are hard to reconcile with a single-stage melt evaporation origin and may require reintroduction or reequilibration for magnesium, oxygen and titanium after evaporation for some of the studied CAIs. The initial 26Al/27Al ratios inferred from model isochrons span a range from <1 × 10-6 to canonical (∼5 × 10-5). The CAIs show a mutual exclusivity relationship between inferred incorporation of live 26Al and the presence of resolvable anomalies in 48Ca and 50Ti. Furthermore, a relationship exists between 26Al incorporation and Δ17O in the hibonite-rich CAIs (i.e., 26Al-free CAIs have resolved variations in Δ17O, while CAIs with resolved 26Mg excesses have Δ17O values close to -23‰). Only the grossite-rich CAI has a relatively enhanced Δ17O value (∼-17‰) in spite of a near-canonical 26Al/27Al. We interpret these data as indicating that fractionated hibonite-rich CAIs formed over an extended time period and sampled multiple stages in the isotopic evolution of the solar nebula, including: (1) an 26Al-poor nebula with large positive and negative anomalies in 48Ca and 50Ti and variable Δ17O; (2) a stage of 26Al-admixture, during which anomalies in 48Ca and 50Ti had been largely diluted and a Δ17O value of ∼-23‰ had been achieved in the CAI formation region; and (3

  3. Evaluation of geologic and geophysical techniques for surface-to-subsurface projections of geologic characteristics in crystalline rock

    International Nuclear Information System (INIS)

    1985-07-01

    Granitic and gneissic rock complexes are being considered for their potential to contain and permanently isolate high-level nuclear waste in a deep geologic repository. The use of surface geologic and geophysical techniques has several advantages over drilling and testing methods for geologic site characterization in that the techniques are typically less costly, provide data over a wider area, and do not jeopardize the physical integrity of a potential repository. For this reason, an extensive literature review was conducted to identify appropriate surface geologic and geophysical techniques that can be used to characterize geologic conditions in crystalline rock at proposed repository depths of 460 to 1,220 m. Characterization parameters such as rock quality; fracture orientation, spacing; and aperture; depths to anomalies; degree of saturation; rock body dimensions; and petrology are considered to be of primary importance. Techniques reviewed include remote sensing, geologic mapping, petrographic analysis, structural analysis, gravity and magnetic methods, electrical methods, and seismic methods. Each technique was reviewed with regard to its theoretical basis and field application; geologic parameters that can be evaluated; advantages and limitations, and, where available, case history applications in crystalline rock. Available information indicates that individual techniques provide reliable information on characteristics at the surface, but have limited success in projections to depths greater that approximately 100 m. A combination of integrated techniques combines with data from a limited number of boreholes would significantly improve the reliability and confidence of early characterization studies to provide qualitative rock body characteristics for region-to-area and area-to-site selection evaluations. 458 refs., 32 figs., 14 tabs

  4. Lead (Pb) Isotope Baselines for Studies of Ancient Human Migration and Trade in the Maya Region

    Science.gov (United States)

    Kamenov, George D.; Gilli, Adrian; Hodell, David A.; Emery, Kitty F.; Brenner, Mark; Krigbaum, John

    2016-01-01

    We examined the potential use of lead (Pb) isotopes to source archaeological materials from the Maya region of Mesoamerica. The main objectives were to determine if: 1) geologic terrains throughout the Maya area exhibit distinct lead isotope ratios (206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb), and 2) a combination of lead and strontium ratios can enhance sourcing procedures in the Mesoamerica region. We analyzed 60 rock samples for lead isotope ratios and a representative subset of samples for lead, uranium, and thorium concentrations across the Maya region, including the Northern Lowlands of the Mexican Yucatan Peninsula, the Southern Lowlands of Guatemala and Belize, the Volcanic Highlands, the Belizean Maya Mountains, and the Metamorphic Province/Motagua Valley. Although there is some overlap within certain sub-regions, particularly the geologically diverse Metamorphic Province, lead isotopes can be used to distinguish between the Northern Lowlands, the Southern Lowlands, and the Volcanic Highlands. The distinct lead isotope ratios in the sub-regions are related to the geology of the Maya area, exhibiting a general trend in the lowlands of geologically younger rocks in the north to older rocks in the south, and Cenozoic volcanic rocks in the southern highlands. Combined with other sourcing techniques such as strontium (87Sr/86Sr) and oxygen (δ18O), a regional baseline for lead isotope ratios can contribute to the development of lead isoscapes in the Maya area, and may help to distinguish among geographic sub-regions at a finer scale than has been previously possible. These isotope baselines will provide archaeologists with an additional tool to track the origin and movement of ancient humans and artifacts across this important region. PMID:27806065

  5. Lead (Pb) Isotope Baselines for Studies of Ancient Human Migration and Trade in the Maya Region.

    Science.gov (United States)

    Sharpe, Ashley E; Kamenov, George D; Gilli, Adrian; Hodell, David A; Emery, Kitty F; Brenner, Mark; Krigbaum, John

    2016-01-01

    We examined the potential use of lead (Pb) isotopes to source archaeological materials from the Maya region of Mesoamerica. The main objectives were to determine if: 1) geologic terrains throughout the Maya area exhibit distinct lead isotope ratios (206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb), and 2) a combination of lead and strontium ratios can enhance sourcing procedures in the Mesoamerica region. We analyzed 60 rock samples for lead isotope ratios and a representative subset of samples for lead, uranium, and thorium concentrations across the Maya region, including the Northern Lowlands of the Mexican Yucatan Peninsula, the Southern Lowlands of Guatemala and Belize, the Volcanic Highlands, the Belizean Maya Mountains, and the Metamorphic Province/Motagua Valley. Although there is some overlap within certain sub-regions, particularly the geologically diverse Metamorphic Province, lead isotopes can be used to distinguish between the Northern Lowlands, the Southern Lowlands, and the Volcanic Highlands. The distinct lead isotope ratios in the sub-regions are related to the geology of the Maya area, exhibiting a general trend in the lowlands of geologically younger rocks in the north to older rocks in the south, and Cenozoic volcanic rocks in the southern highlands. Combined with other sourcing techniques such as strontium (87Sr/86Sr) and oxygen (δ18O), a regional baseline for lead isotope ratios can contribute to the development of lead isoscapes in the Maya area, and may help to distinguish among geographic sub-regions at a finer scale than has been previously possible. These isotope baselines will provide archaeologists with an additional tool to track the origin and movement of ancient humans and artifacts across this important region.

  6. Review report about Puntas de Mataojo anomalies area; Informe sobre revision de anomalias del area Puntas de Mataojo

    Energy Technology Data Exchange (ETDEWEB)

    Rossi, P

    1987-07-01

    Puntas de Mataojo anomalies have been reviewed during 1986 in Maldonado and Lavalleja Province, Las Animas photo map. A pedestrian radiometric, geochemical samples and geological definition were developed as a main goals in this study.

  7. SO2 photoexcitation mechanism links mass-independent sulfur isotopic fractionation in cryospheric sulfate to climate impacting volcanism

    DEFF Research Database (Denmark)

    Hattori, Shohei; Schmidt, Johan Albrecht; Johnson, Matthew Stanley

    2013-01-01

    Natural climate variation, such as that caused by volcanoes, is the basis for identifying anthropogenic climate change. However, knowledge of the history of volcanic activity is inadequate, particularly concerning the explosivity of specific events. Some material is deposited in ice cores......, but the concentration of glacial sulfate does not distinguish between tropospheric and stratospheric eruptions. Stable sulfur isotope abundances contain additional information, and recent studies show a correlation between volcanic plumes that reach the stratosphere and mass-independent anomalies in sulfur isotopes...... plume chemistry, allowing the production and preservation of a mass-independent sulfur isotope anomaly in the sulfate product. The model accounts for the amplitude, phases, and time development of Δ(33)S/δ(34)S and Δ(36)S/Δ(33)S found in glacial samples. We are able to identify the process controlling...

  8. New Mars free-air and Bouguer gravity: Correlation with topography, geology and large impact basins

    Science.gov (United States)

    Frey, Herbert; Bills, Bruce G.; Kiefer, Walter S.; Nerem, R. Steven; Roark, James H.; Zuber, Maria T.

    1993-01-01

    Free-air and Bouguer gravity anomalies from a 50x50 field (MGM635), derived at the Goddard Space Flight Center, with global topography, geology, and the distribution of large impact basins was compared. The free-air gravity anomalies were derived from re-analysis of Viking Orbiter and Mariner 9 tracking data and have a spatial resolution of 250-300 km. Bouguer anomalies were calculated using a 50x50 expansion of the current Mars topography and the GSFC degree 50 geoid as the equipotential reference surface. Rotational flattening was removed using a moment of inertia of 0.365 and the corrections from Table B2 of Sleep and Phillips. Crustal density and mean density were assumed to be 2.9 and 3.93 gm/cm(sup 3). The spherical harmonic topography used has zero mean elevation, and differs from the USGS maps by about 2 km. Comparisons with global geology use a simplified map with about 1/3 the number of units on the current maps. For correlation with impact basins, the recent compilation by Schultz and Frey was used.

  9. Proceedings of the 39. Brazilian congress on geology. v. 6

    International Nuclear Information System (INIS)

    1996-01-01

    The book presents the 39. Brazilian Congress on Geology works, occurred in Salvador, Bahia, during the period of September 1 to 6, 1996. The meeting main subject - geology and society - reflects the current change epoch. The symposiums revealed the more important actions about geosciences applications to the society in the country. The round tables, structured for the polemical subject debates that involve the geosciences and the mineral sector crisis aspects, were achieved by several invited participants completely embraced with the subject. During the congress activities development there were some courses, technical excursions and external actions in Salvador, aiming to show the geosciences role to the social welfare. This volume focuses papers about geology and metallogenesis from high degree metamorphic terrain and isotope applications in geology

  10. Isotopic abundance in atom trap trace analysis

    Science.gov (United States)

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  11. Study of gases in six geologic faults in the Department of Narino

    International Nuclear Information System (INIS)

    Moran Rodriguez, C; Chica Sanchez, A; Garzon Valencia, G

    2001-01-01

    Radon-222 and carbon dioxide emissions on the Manchabajoy, Pasto, Buesaco, Guaitara, Ancuya and Magdalena geological faults in the Narino Department were studied. As example of environmental influences like rainfall on the gas emissions in the San Francisco Station, located in the Manchabajoy, Ancuya and Guaitara faults intersection was presented. Another environmental perturbations, like air temperature and atmospheric pressure no varies too much and minimum influence gas emissions from soils. In the first semester of the 2000, several radon anomalies in six stations of the volcanological and seismological observatory of Pasto were registered. After cited radon anomalies a seismic swarm were filled by inhabitants of Pasto City in July months, and probably a correlation between radon anomalies and detected seismic signals have to be taken into account

  12. The Stanford-U.S. Geological Survey SHRIMP ion microprobe--a tool for micro-scale chemical and isotopic analysis

    Science.gov (United States)

    Bacon, Charles R.; Grove, Marty; Vazquez, Jorge A.; Coble, Matthew A.

    2012-01-01

    Answers to many questions in Earth science require chemical analysis of minute volumes of minerals, volcanic glass, or biological materials. Secondary Ion Mass Spectrometry (SIMS) is an extremely sensitive analytical method in which a 5–30 micrometer diameter "primary" beam of charged particles (ions) is focused on a region of a solid specimen to sputter secondary ions from 1–5 nanograms of the sample under high vacuum. The elemental abundances and isotopic ratios of these secondary ions are determined with a mass spectrometer. These results can be used for geochronology to determine the age of a region within a crystal thousands to billions of years old or to precisely measure trace abundances of chemical elements at concentrations as low as parts per billion. A partnership of the U.S. Geological Survey and the Stanford University School of Earth Sciences operates a large SIMS instrument, the Sensitive High-Resolution Ion Microprobe with Reverse Geometry (SHRIMP–RG) on the Stanford campus.

  13. Barium isotopes in Allende meteorite - Evidence against an extinct superheavy element

    Science.gov (United States)

    Lewis, R. S.; Anders, E.; Shimamura, T.; Lugmair, G. W.

    1983-01-01

    Carbon and chromite fractions from the Allende meteorite that contain isotopically anomalous xenon-131 to xenon-136 (carbonaceous chondrite fission or CCF xenon) at up to 5 x 10 to the 11th atoms per gram show no detectable isotopic anomalies in barium-130 to barium-138. This rules out the possibility that the CCF xenon was formed by in situ fission of an extinct superheavy element. Apparently the CCF xenon and its carbonaceous carrier are relics from stellar nucleosynthesis.

  14. Geology and development: proceedings of the 40. Brazilian congress on geology; EXPOGEO 98 - Brazilian exposition of Geology. Abstracts

    International Nuclear Information System (INIS)

    1998-01-01

    The proceedings of the 40. Brazilian Congress on Geology register relevant papers on the nuclear and energy areas. The papers devoted to the nuclear area covers the following subjects: geochronology; stratigraphy; geochemistry; age estimation; isotope dating; litogeochemistry; mineralization; uranium deposits; crystallization; environmental impacts related to the uranium mines and the non nuclear mining industries; petrogenesis; paleoclimatology; natural radioactivity; spectrometry; and the uranium extraction. The articles on the energy area are referent to the petroleum, coal and natural gas exploration; environmental impacts related to the oil spilling; and the history and the perspectives of the petroleum exploration in Brazil

  15. Water radon anomaly fields

    Energy Technology Data Exchange (ETDEWEB)

    Yin, H.

    1980-01-01

    A striking aspect of water radon levels in relation to earthquakes is that before the Tangshan quake there was a remarkable synchronicity of behavior of many wells within 200 km of Tangshan. However, for many wells anomalous values persisted after the earthquake, particularly outside the immediate region of the quake. It is clear that radon may be produced by various processes; some candidates are pressure, shear, vibration, temperature and pressure, mixing of water-bearing strata, breakdown of mineral crystal structure, and the like, although it is not clear which of these are primary. It seems that a possible explanation of the persistence of the anomaly in the case of Tangshan may be that the earthquake released strain in the vicinity of Tangshan but increased it further along the geological structures involved, thus producing a continued radon buildup.

  16. Isostatic models and isostatic gravity anomalies of the Arabian plate and surroundings

    Science.gov (United States)

    Kaban, Mikhail K.; El Khrepy, Sami; Al-Arifi, Nassir

    2015-04-01

    Isostaic anomalies represent one of the most useful "geological" reduction of the gravity field. With the isostatic correction it is possible to remove a significant part of the effect of deep density heterogeneity, which dominates in the Bouguer gravity anomalies. This correction is based on the fact that a major part of the near-surface load is compensated by variations of the lithosphere boundaries (chiefly the Moho and LAB) and by density variations within the crust and upper mantle. It is usually supposed that it is less important to a first order, what is the actual compensation model when reducing the effect of compensating masses, since their total weight is exactly opposite to the near-surface load. We compare several compensating models for the Arabian plate and surrounding area. The Airy model gives very significant regional isostatic anomalies, which can not be explained by the upper crust structure or disturbances of the isostatic equilibrium. Also the predicted "isostatic" Moho is very different from the existing observations. The second group of the isostatic models includes the Moho, which is based on existing seismic determinations. Additional compensation is provided by density variations within the lithosphere (chiefly in the upper mantle). In this way we minimize regional anomalies over the Arabian plate. The residual local anomalies well correspond to tectonic structure of the plate. Still very significant anomalies are associated with the Zagros fold belt, the collision zone of the Arabian and Eurasian plates.

  17. A least-squares minimization approach for model parameters estimate by using a new magnetic anomaly formula

    Science.gov (United States)

    Abo-Ezz, E. R.; Essa, K. S.

    2016-04-01

    A new linear least-squares approach is proposed to interpret magnetic anomalies of the buried structures by using a new magnetic anomaly formula. This approach depends on solving different sets of algebraic linear equations in order to invert the depth ( z), amplitude coefficient ( K), and magnetization angle ( θ) of buried structures using magnetic data. The utility and validity of the new proposed approach has been demonstrated through various reliable synthetic data sets with and without noise. In addition, the method has been applied to field data sets from USA and India. The best-fitted anomaly has been delineated by estimating the root-mean squared (rms). Judging satisfaction of this approach is done by comparing the obtained results with other available geological or geophysical information.

  18. Determination of uranium, thorium and radium isotope ratio

    International Nuclear Information System (INIS)

    Sokolova, Z.A.

    1983-01-01

    The problems connected with the study of isotope composition of natural radioactive elements in natural objects are considered. It is pointed out that for minerals, ores and rocks the following ratios are usually determined: 234 U/ 238 U, 230 Th/ 238 U, 226 Ra/ 238 U, 228 Th/ 230 Th, 228 Th/ 232 Th and lead isotopes; for natural waters, besides the enumerated - 226 Ra/ 228 Ra. General content of uranium and thorium in the course of isotope investigations is determined from separate samples, most frequently by the X-ray spectral method, radium content - by usual radiochemical method, uranium and radium content in waters -respectively by calorimetric and emanation methods. Radiochemical preparation of geologic powder and aqueous samples for isotope analysis is described in detail. The technique of measuring and calculating isotope ratios (α-spectrometry for determining isotope composition of uranium and thorium and emanation method for determining 226 Ra/ 228 Ra) is presented

  19. INTURGEO: The international uranium geology information system

    International Nuclear Information System (INIS)

    1988-09-01

    The International Uranium Geology Information System (INTURGEO) is an international compilation of data on uranium deposits and occurrences. The purpose of INTURGEO is to provide a clearinghouse for uranium geological information that can serve for the better understanding of the worldwide distribution of uranium occurrences and deposits. The INTURGEO system is by no means complete for all regions of the world. Data have been available principally from the WOCA countries. INTURGEO currently covers 6,089 occurrences and deposits in 96 countries of which 4,596 occurrences in 92 countries are presented here. The information presented in this publication is a very brief, one line synopsis of deposits and occurrences, and has been collected from literature and through questionnaires sent directly to IAEA Member States. None of the information contained in the INTURGEO database was derived from confidential sources although there are many entries which come from the internal files of Member States and are not directly available in the general literature. The uniformity of the INTURGEO data presented in this report has depended heavily on the data provided by Member States. Basic information includes the deposit or occurrence name, the mining district, the tectonic setting, the geological type, status, size, host-rock type, age of mineralization and bibliographic references. The data contained in the maps of the atlas include all reported occurrences of uranium above the anomaly level. The categories of occurrence and deposit status includes: Anomaly; occurrences of unknown status; occurrences; prospects; developed prospects; subeconomic deposits; economic deposits; mines; inactive mines; depleted mines. A microcomputer version of INTURGEO on 21 Megabyte Bernoulli disks is available. 5 tabs, 102 maps

  20. Multi-isotope and Hydrogeochemical approach for characterizing Saturnia thermal groundwater (Grosseto, Italy

    Directory of Open Access Journals (Sweden)

    Alessio Barbagli

    2013-12-01

    Full Text Available Aim of this study is to define the groundwater flow of thermal area of Saturnia, through both chemical and isotope analyses. After a first detailed geological-geophysical survey and a quantification of the available groundwater resources, we analyzed several chemical compounds (Na, Ca, Mg, K, Chlorides, Sulfates, Nitrates, total alkalinity, Li, Sr, B, Fluorides, soluble Silica, free Carbon Dioxide, Sb, As, Se, H2S, Fe, Mn, Hg e Pb and isotopes (2H; 3H, 3He, 4He, 13C, 18O, 86Sr, 87Sr. Excluding the uncertainties mainly related to a large repetition of measures over time, we concluded the following conclusions. Both Lithium and Boron high values and 87Sr/86Sr values highlighted that “Calcare Cavernoso” limestone geological formation constitutes the Saturnia thermal aquifer. Such samples showed both the same chemical characteristics and source area. Boron, Lithium, δ2H, δ18O and 87Sr/86Sr show the Saturnia thermal aquifer is separated by those of Pitigliano (Latera- Bolsena thermal circuit and Bagni San Filippo (Mt. Amiata thermal circuit. 18O, 3H e δ13C measured in samples coming from Saturnia thermal spring respectively indicate that water feeding the thermal aquifer infiltrate at 350-440 m a.s.l., that they are almost 30 years old, and finally they that are isolated regarding to external infiltration. Low value of R/Ra tends to exclude the influence of Earth mantle to the geothermal anomaly of Saturnia area. The high content in Selenium indicates a possible interaction between Saturnia spring water and those coming from the Saturnia well, with volcanic fluids. However, considering also the evidence of the separation between the Saturnia groundwater flow and those of neighboring thermal fields (Bolsena and Mt. Amiata, we hypothesized that only a exchange among these volcanic complexes and the source area of thermal water points exists, but not among these complex and Saturnia aquifer.

  1. Isotopes as Tracers of the Hawaiian Coffee-Producing Regions

    Science.gov (United States)

    2011-01-01

    Green coffee bean isotopes have been used to trace the effects of different climatic and geological characteristics associated with the Hawaii islands. Isotope ratio mass spectrometry (IRMS) and inductively coupled plasma mass spectrometry ((MC)-ICP-SFMS and ICP-QMS) were applied to determine the isotopic composition of carbon (δ13C), nitrogen (δ15N), sulfur (δ34S), and oxygen (δ18O), the isotope abundance of strontium (87Sr/86Sr), and the concentrations of 30 different elements in 47 green coffees. The coffees were produced in five Hawaii regions: Hawaii, Kauai, Maui, Molokai, and Oahu. Results indicate that coffee plant seed isotopes reflect interactions between the coffee plant and the local environment. Accordingly, the obtained analytical fingerprinting could be used to discriminate between the different Hawaii regions studied. PMID:21838232

  2. Plutonium isotope ratios in polychaete worms

    International Nuclear Information System (INIS)

    Beasley, T.M.; Fowler, S.W.

    1976-01-01

    Reference is made to recent reports that suggest that terrestrial and aquatic organisms may preferentially take up 238 Pu compared with sup(239+240)Pu. It is stated that although kinetic isotope effects are known to occur in biological systems for low mass number elements, such as H, C and N, such effects are generally discounted with higher mass numbers, and differences in the biological 'uptake' of isotopes of high mass number elements, such as those of Pu, are normally attributable to differences in the chemical or physical forms of the isotopes or to different quantities of isotopes available to organisms. This has been applied to explain differential Pu isotope behaviour in animals under controlled laboratory conditions, but it is not certain that it can be applied to explain anomalies of Pu isotope behaviour in organisms contaminated by nuclear test debris or by wastes from nuclear fuel reprocessing plants. Geochemical weathering may also have an effect. Described here are experiments in which it was found that deposit feeding marine worms living in sediments contaminated in different ways with Pu isotopes did not show preferential accumulation of 238 Pu. The worms had been exposed to different chemical and physical forms of the isotopes, including exposure to laboratory-labelled sediment, sediment collected from a former weapons test site, and sediment contaminated by wastes from a nuclear fuel reprocessing plant. The worms were allowed to accumulate Pu for times of 5 to 40 days. Isotope ratios were determined by α-spectrometric techniques. It is considered that the results are important for environmental samples where Pu activity levels are low. (U.K.)

  3. To evaluate ERTS-1 data for usefulness as a geological sensor in the diverse geological terraines of New York State

    Science.gov (United States)

    Isachsen, Y. W. (Principal Investigator)

    1973-01-01

    The author has identified the following significant results. Linear anomalies dominate the new geological information derived from ERTS-1 imagery, total lengths now exceeding 6000 kms. Experimentation with a variety of viewing techniques suggests that conventional photogeologic analyses of band 7 results in the location of more than 97 percent of all linears found. Bedrock lithologic types are distinguishable only where they are topographically expressed or govern land use signatures. The maxima on rose diagrams for ERTS-1 anomalies correspond well with those for mapped faults and topographic lineaments, despite a difference in relative magnitudes of maxima thought due to solar illumination direction. A multiscale analysis of linears showed that single topographic linears at 1:2,500,000 became dashed jugate linears at 1:500,000, and shorter linears lacking any conspicuous zonal alignment at 1:250,000. Most circular features found were explained away by U-2 airphoto analysis but several remain as anomalies. Visible glacial features include individual drumlins, best seen in winter imagery, drumlinoids, eskers, ice-marginal drainage channels, glacial lake shorelines and sand plains, and end moraines.

  4. Complete Bouguer gravity anomaly map of the state of Colorado

    Science.gov (United States)

    Abrams, Gerda A.

    1993-01-01

    The Bouguer gravity anomaly map is part of a folio of maps of Colorado cosponsored by the National Mineral Resources Assessment Program (NAMRAP) and the National Geologic Mapping Program (COGEOMAP) and was produced to assist in studies of the mineral resource potential and tectonic setting of the State. Previous compilations of about 12,000 gravity stations by Behrendt and Bajwa (1974a,b) are updated by this map. The data was reduced at a 2.67 g/cm3 and the grid contoured at 3 mGal intervals. This map will aid in the mineral resource assessment by indicating buried intrusive complexes, volcanic fields, major faults and shear zones, and sedimentary basins; helping to identify concealed geologic units; and identifying localities that might be hydrothermically altered or mineralized.

  5. Shaded relief magnetic anomaly map of Italy and surrounding marine areas

    International Nuclear Information System (INIS)

    Chiappini, M.; Meloni, A.; Boschi, E.; Faggioni, O.; Beverini, N.; Carmisciano, C.; Marson, I.

    2000-01-01

    Magnetic observations made onshore the Italian Peninsula, and across the adjacent seas, have been compiled in a new digital database that provides the first complete regional scale view of the crustal scale magnetic anomalies of the regional at sea level. The offshore data were acquired between 1965-1972 by the Osservatorio Geofisico Sperimentale (OGS) while the ground measurements were performed within the framework of the Progetto Finalizzato Geodinamica of the Calling's Nazionale delle Ricerche (PFG-CNR) between 1977 and 1981. The new shaded relief magnetic anomaly map of total intensity of the Earth's magnetic field for Italy and the surrounding seas has been produced at sea level, for the geomagnetic epoch 1979.0. The most remarkable result of this new map, with respect to the previous compilations and to the aero magnetic map of Italy, is an unprecedented view of the magnetic signature of the major tectonic elements in their regional setting. There is good correlation between known structural geology and the magnetic anomalies, and now that the longer wavelength signatures have been corrected, deeper interpretations are possible

  6. Shaded relief magnetic anomaly map of Italy and surrounding marine areas

    Directory of Open Access Journals (Sweden)

    C. Carmisciano

    2000-06-01

    Full Text Available Magnetic observations made onshore the Italian Peninsula, and across the adjacent seas, have been compiled in a new digital database that provides the first complete regional scale view of the crustal scale magnetic anomalies of the region at sea level. The offshore data were acquired between 1965-1972 by the Osservatorio Geofisico Sperimentale (OGS while the ground measurements were performed within the framework of the Progetto Finalizzato Geodinamica of the Consiglio Nazionale delle Ricerche (PFG-CNR between 1977 and 1981. The new shaded relief magnetic anomaly map of total intensity of the Earth's magnetic field for Italy and the surrounding seas has been produced at sea level, for the geomagnetic epoch 1979.0. The most remarkable result of this new map, with respect to the previous compilations and to the aeromagnetic map of Italy, is an unprecedented view of the magnetic signature of the major tectonic elements in their regional setting. There is good correlation between known structural geology and the magnetic anomalies, and now that the longer wavelength signatures have been corrected, deeper interpretations are possible.

  7. Discrimination between preseismic electromagnetic anomalies and solar activity effects

    Science.gov (United States)

    Koulouras, Gr; Balasis, G.; Kontakos, K.; Ruzhin, Y.; Avgoustis, G.; Kavouras, D.; Nomicos, C.

    2009-04-01

    Laboratory studies suggest that electromagnetic emissions in a wide frequency spectrum ranging from kHz to very high MHz frequencies are produced by the opening of microcracks, with the MHz radiation appearing earlier than the kHz radiation. Earthquakes are large-scale fracture phenomena in the Earth's heterogeneous crust. Thus, the radiated kHz-MHz electromagnetic emissions are detectable not only at laboratory but also at geological scale. Clear MHz-to-kHz electromagnetic anomalies have been systematically detected over periods ranging from a few days to a few hours prior to recent destructive earthquakes in Greece. We bear in mind that whether electromagnetic precursors to earthquakes exist is an important question not only for earthquake prediction but mainly for understanding the physical processes of earthquake generation. An open question in this field of research is the classification of a detected electromagnetic anomaly as a pre-seismic signal associated to earthquake occurrence. Indeed, electromagnetic fluctuations in the frequency range of MHz are known to related to a few sources, i.e., they might be atmospheric noise (due to lightning), man-made composite noise, solar-terrestrial noise (resulting from the Sun-solar wind-magnetosphere-ionosphere-Earth's surface chain) or cosmic noise, and finally, lithospheric effect, namely pre-seismic activity. We focus on this point. We suggest that if a combination of detected kHz and MHz electromagnetic anomalies satisfies the herein presented set of criteria these anomalies could be considered as candidate precursory phenomena of an impending earthquake.

  8. Isotopic and geochemical precursors of earthquakes and volcanic eruptions

    International Nuclear Information System (INIS)

    1993-11-01

    Radon 222 seems to be one of the most promising precursors and is the tracer for which more data are available: according to statistics elaborated in China, 70% of earthquakes are preceded by radon anomalies detectable in soil, air and/or in groundwater. Also other changes of the fluid chemical composition and variations of 3 He/ 4 He, 2 H/ 1 H, 13 C/ 12 C, 18 O/ 16 O isotopic ratios have been detected. Among these indicators one can mention variations in concentration and/or isotopic ratios of hydrogen, helium, carbon, oxygen, neon, radon, radium and uranium. Refs, figs, tabs

  9. PENENTUAN POSISI SUMBER PROSPEK PANAS BUMI BERDASARKAN DATA ANOMALI MAGNETDI DAERAH AKESAHU, PULAU TIDORE, MALUKU UTARA

    Directory of Open Access Journals (Sweden)

    Rohima Wahyu Ningrum

    2015-04-01

    Full Text Available Penelitian geofisika dengan menggunakan metode magnetik yaitu dengan alat Magnetometer Fluxgate. Luas daerah penyelidikan ± 1 km x 1 km, dibatasi oleh koordinat geografis antara 127° 27’ 42” s/d 127° 27’ 43” BT dan 0° 43’ 17” s/d 0° 43’ 19” LU . Penelitian ini bertujuan untuk mengetahui posisi sumber prospek panas bumi di daerah Akesahu, Pulau Tidore berdasarkan data anomali medan magnet. Data medan magnet total yang terukur adalah medan utama, medan luar dan medan anomali. Untuk menghilangkan efek-efek anomali dari medan magnet luar dan anomali medan magnet utama dilakukan perhitungan koreksi variasi harian, koreksi drift (kesalahan alat, koreksi penyesuaian, koreksi IGRF, dan pemisahan anomali residual dan regional. Hasil penelitian menunjukkan bahwa, daerah Akesahu, Pulau Tidore memiliki potensi panas bumi yang masih cukup besar yang ditandai dengan adanya manifestasi panas bumi berupa mata air panas. Anomali medan magnet daerah Akesahu ditunjukkan dengan adanya anomali yang rendah (0.90 sampai dengan -2163.09 nT yang memanjang arah utara-selatan di bagian Timur Pulau Tidore. Disamping itu di sekitar mata air panas Akesahu secara geologis didukung dengan adanya empat buah sesar normal. Ini sebagai sistem pengontrol panas bumi yang lainnya di Pulau Tidore.

  10. Evidence from stable isotopes and 10Be for solar system formation triggered by a low-mass supernova

    Science.gov (United States)

    Banerjee, Projjwal; Qian, Yong-Zhong; Heger, Alexander; Haxton, W. C.

    2016-11-01

    About 4.6 billion years ago, some event disturbed a cloud of gas and dust, triggering the gravitational collapse that led to the formation of the solar system. A core-collapse supernova, whose shock wave is capable of compressing such a cloud, is an obvious candidate for the initiating event. This hypothesis can be tested because supernovae also produce telltale patterns of short-lived radionuclides, which would be preserved today as isotopic anomalies. Previous studies of the forensic evidence have been inconclusive, finding a pattern of isotopes differing from that produced in conventional supernova models. Here we argue that these difficulties either do not arise or are mitigated if the initiating supernova was a special type, low in mass and explosion energy. Key to our conclusion is the demonstration that short-lived 10Be can be readily synthesized in such supernovae by neutrino interactions, while anomalies in stable isotopes are suppressed.

  11. Isotopes in the earth sciences

    Energy Technology Data Exchange (ETDEWEB)

    Bowen, Robert

    1988-01-01

    This book examines significant aspects of isotope applications in geology and geochemistry commencing with basic matters, such as atomic structure, stable nuclides and their fractionation, as well as the various decay modes of unstable nuclides. Modern mass spectrometry techniques including electrostatic tandem accelerators are followed by a review of radioisotope dating technology. The relatively new method using the rare earth elements samarium and neodymium are covered. Other geochronometers, applicable to both rocks and minerals not dateable otherwise, are included. A review is given of isotopes in the atmosphere, hydrosphere and lithosphere of the Earth. Those of oxygen and hydrogen together with the cosmogenic radionuclides tritium and radiocarbon are discussed in relation to the biosphere. The role of isotopes of carbon, nitrogen and sulphur is described and extended to fossil fuels and rocks as well as meteorites. Related themes such as Phanerozoic oceans, oceanic palaeothermometry, snow and ice stratigraphy and geothermal waters are covered. The field of isotopic palaeoecology is discussed. Radioactive wastes, their accumulation, dangers and disposal are investigated with especial reference to their environmental impacts.

  12. Stable isotopic composition of East African lake waters

    International Nuclear Information System (INIS)

    Odada, E.O.

    2001-01-01

    The investigation of stable isotopic composition of East African lake waters was conducted by scientists from the Department of Geology, University of Nairobi, as part of the International Decade for the East African Lakes (IDEAL) project and in close collaboration with the scientists from Large Lakes Observatory of the University of Minnesota and the Isotope Hydrology Laboratory of the IAEA in Vienna. The Research Contract was part of the IAEA Co-ordinated Research Programme on Isotope Techniques in Lake Dynamics Investigations, and was sponsored by the Agency. Water and grab sediment samples were obtained from East African Lakes during the month of January and February 1994 and July/August 1995. Water samples were analysed for oxygen and deuterium isotopic composition at the IAEA Laboratories in Vienna, Austria. In this final paper we report the results of the study of oxygen and deuterium isotopic composition from the East African lake waters. (author)

  13. The Ellsworth terrane, coastal Maine: Geochronology, geochemistry, and Nd-Pb isotopic composition - Implications for the rifting of Ganderia

    Science.gov (United States)

    Schulz, K.J.; Stewart, D.B.; Tucker, R.D.; Pollock, J.C.; Ayuso, R.A.

    2008-01-01

    The Ellsworth terrane is one of a number of fault-bounded blocks that occur along the eastern margin of Ganderia, the western-most of the peri-Gondwanan domains in the northern Appalachians that were accreted to Laurentia in the Paleozoic. Geologic relations, detrital zircon ages, and basalt geochemistry suggest that the Ellsworth terrane is part of Ganderia and not an exotic terrane. In the Penobscot Bay area of coastal Maine, the Ellsworth terrane is dominantly composed of bimodal basalt-rhyolite volcanic sequences of the Ellsworth Schist and unconformably overlying Castine Volcanics. We use new U-Pb zircon geochronology, geochemistry, and Nd and Pb isotopes for these volcanic sequences to constrain the petrogenetic history and paleotectonic setting of the Ellsworth terrane and its relationship with Ganderia. U-Pb zircon geochronology for rhyolites indicates that both the Ellsworth Schist (508.6 ?? 0.8 Ma) and overlying Castine Volcanics (503.5 ?? 2.5 Ma) are Middle Cambrian in age. Two tholefitic basalt types are recognized. Type Tb-1 basalt, present as pillowed and massive lava flows and as sills in both units, has depleted La and Ce ([La/Nd]N = 0.53-0.87) values, flat heavy rare earth element (REE) values, and no positive Th or negative Ta anomalies on primitive mantle-normalized diagrams. In contrast, type Th-2 basalt, present only in the Castine Volcanics, has stightly enriched LREE ([La/Yb]N = 1.42-2.92) values and no Th or Th anomalies. Both basalt types have strongly positive ??Nd (500) values (Th-1 = +7.9-+8.6; Th-2 = +5.6-+7.0) and relatively enriched Pb isotopic compositions (206Ph/204Pb = 18.037-19.784; 207/204Pb = 15.531-15.660; 2088Pb/204Pb = 37.810-38.817). The basalts have compositions transitional between recent normal and enriched mid-ocean-ridge basalt, and they were probably derived by partial melting of compositionatly heterogeneous asthenosphenc mantle. Two types of rhyolite also are present. Type R-1 rhyolite, which mostly occurs as tuffs

  14. Synthesis of the works of geophysical (electrical soundings) carried out in the region of the anomalies of Yerba Sola (Cerro Largo) Uruguay

    International Nuclear Information System (INIS)

    Perrin, J.

    1983-01-01

    In this report has been studied geographical localization, geology, geophysics prospection, equipment and methods used and their results in Yerba Sola anomalies Province Cerro Largo and Fraile Muerto formation

  15. Gravitational anomalies

    Energy Technology Data Exchange (ETDEWEB)

    Leutwyler, H; Mallik, S

    1986-12-01

    The effective action for fermions moving in external gravitational and gauge fields is analyzed in terms of the corresponding external field propagator. The central object in our approach is the covariant energy-momentum tensor which is extracted from the regular part of the propagator at short distances. It is shown that the Lorentz anomaly, the conformal anomaly and the gauge anomaly can be expressed in terms of the local polynomials which determine the singular part of the propagator. (There are no coordinate anomalies). Except for the conformal anomaly, for which we give explicit representations only in dless than or equal to4, we consider an arbitrary number of dimensions.

  16. Traverse across the Nelspruit batholith and the geology of the excursion route between Sabie and Witbank

    International Nuclear Information System (INIS)

    Robb, L.J.; Anhaeusser, C.R.

    1981-01-01

    A geologic survey was done on the traverse across the Nelspruit batholith and the geology of the excursion route between Sabie and Witbank. Rubidium isotopes, strontium 86 and strontium 87 were used to determine the rock age. The petrogenetic aspects relating to the Nelspruit batholith were also studied

  17. Quantitative Interpretation of Gravity Anomaly Data in Geothermal Field Seulawah Agam, Aceh Besar

    Directory of Open Access Journals (Sweden)

    Aprillino Wangsa

    2018-01-01

    Keywords: Gravity Method, Density, Grav2DC, Geothermal System, Seulawah Agam REFERENSI Bennett, J.D., dkk. 1981. Peta Geologi Lembar Banda Aceh, Sumatera. Bandung: Pusat Penelitian dan Pengembangan Geologi. Hidayat, N dan Basid, A. 2011. Analisis Anomali Gravitasi Sebagai Acuan Dalam Penentuan Struktur Geologi Bawah Permukaan dan Potensi Geothermal, Jurnal Neutrino, 4.1,p-36. Muzakir. 2014. Investigasi Struktur 2D Lapangan Panasbumi Seulawah Agam Berdasarkan Data Pengukuran Magnetotellurik. Skripsi. Universitas Syiah Kuala, Banda Aceh. Saptadji, N. M. 2001. Teknik Panas Bumi. Departemen Teknik Perminyakan Fakultas Ilmu Kebumian dan Teknologi Mineral. Institut Teknologi Bandung: Bandung. Yu, G., He, Z. X., Hu, Z.Z., borbergsdottir, I. M., Strack, K. –M., dan Tulinius, H.2009. Geothermal Exploration Using MT and Gravity Techniques at Szentlorinc Area in Hungary - SEG 2009 International Expoloration and Annuad Meeting. Houston. P-4333

  18. Radioactive and geological analysis of airborne gamma spectrometric data for locating favorable traps for uranium prospecting in the Syrian desert (Area-1), Syria

    International Nuclear Information System (INIS)

    Asfahani, J.; Al-Hent, R.; Aissa, M.

    2012-01-01

    Statistical analysis has been applied to the airborne spectrometric data for the Syrian desert (Area-1), Syria in order to characterize and isolate the anomalous uranium radioactive zones. Equivalent uranium eU values vary between a minimum of 0.01 and a maximum of 32.74 ppm. Uranium prospecting methodology recently proposed is successfully applied in order to explain the origin of the radioactive anomalies related to Area-1. The dominant geological conditions effectively contributing to the uranium radioactive anomalies in the study area have been determined through the analysis of five radioactive-geological profiles. Different favorable traps have been identified and localized for uranium prospecting. Those uranium traps merit further detailed exploration for determining their uranium potential with depth. - Highlights: ► Determine the radioactive characteristics of Area-1. ► Apply a uranium prospecting methodology for guiding uranium exploration activities in Area-1. ► Explain the origin of the radioactive anomalies in Area-1. ► Relate the structural and geological conditions with the anomalous radioactive occurrences.

  19. Geologic and geophysical maps of the eastern three-fourths of the Cambria 30' x 60' quadrangle, central California Coast Ranges

    Science.gov (United States)

    Graymer, R.W.; Langenheim, V.E.; Roberts, M.A.; McDougall, Kristin

    2014-01-01

    The Cambria 30´ x 60´ quadrangle comprises southwestern Monterey County and northwestern San Luis Obispo County. The land area includes rugged mountains of the Santa Lucia Range extending from the northwest to the southeast part of the map; the southern part of the Big Sur coast in the northwest; broad marine terraces along the southwest coast; and broadvalleys, rolling hills, and modest mountains in the northeast. This report contains geologic, gravity anomaly, and aeromagnetic anomaly maps of the eastern three-fourths of the 1:100,000-scale Cambria quadrangle and the associated geologic and geophysical databases (ArcMap databases), as well as complete descriptions of the geologic map units and the structural relations in the mapped area. A cross section is based on both the geologic map and potential-field geophysical data. The maps are presented as an interactive, multilayer PDF, rather than more traditional pre-formatted map-sheet PDFs. Various geologic, geophysical, paleontological, and base map elements are placed on separate layers, which allows the user to combine elements interactively to create map views beyond the traditional map sheets. Four traditional map sheets (geologic map, gravity map, aeromagnetic map, paleontological locality map) are easily compiled by choosing the associated data layers or by choosing the desired map under Bookmarks.

  20. Eaglet property, southeastern British Columbia: Re-Os geochronology, sulphur isotopes, and thermobarometry

    Czech Academy of Sciences Publication Activity Database

    Hora, Z. D.; Stein, H.; Žák, Karel; Dobeš, P.

    2018-01-01

    Roč. 2017, č. 1 (2018), s. 157-166 ISSN 0381-243X Institutional support: RVO:67985831 Keywords : Eaglet deposit * MINFILE 093A 046 * fluorite * celestite * molybdenite * sulphur isotopes * Re-Os geochronology * fluid inclusion microthermobarometry Subject RIV: DB - Geology ; Mineralogy OBOR OECD: Geology http://cmscontent.nrs.gov.bc.ca/geoscience/PublicationsCatalogue/Fieldwork/Documents/2017/P2018-1.pdf

  1. Geological Corrections in Gravimetry

    Science.gov (United States)

    Mikuška, J.; Marušiak, I.

    2015-12-01

    Applying corrections for the known geology to gravity data can be traced back into the first quarter of the 20th century. Later on, mostly in areas with sedimentary cover, at local and regional scales, the correction known as gravity stripping has been in use since the mid 1960s, provided that there was enough geological information. Stripping at regional to global scales became possible after releasing the CRUST 2.0 and later CRUST 1.0 models in the years 2000 and 2013, respectively. Especially the later model provides quite a new view on the relevant geometries and on the topographic and crustal densities as well as on the crust/mantle density contrast. Thus, the isostatic corrections, which have been often used in the past, can now be replaced by procedures working with an independent information interpreted primarily from seismic studies. We have developed software for performing geological corrections in space domain, based on a-priori geometry and density grids which can be of either rectangular or spherical/ellipsoidal types with cells of the shapes of rectangles, tesseroids or triangles. It enables us to calculate the required gravitational effects not only in the form of surface maps or profiles but, for instance, also along vertical lines, which can shed some additional light on the nature of the geological correction. The software can work at a variety of scales and considers the input information to an optional distance from the calculation point up to the antipodes. Our main objective is to treat geological correction as an alternative to accounting for the topography with varying densities since the bottoms of the topographic masses, namely the geoid or ellipsoid, generally do not represent geological boundaries. As well we would like to call attention to the possible distortions of the corrected gravity anomalies. This work was supported by the Slovak Research and Development Agency under the contract APVV-0827-12.

  2. Holonomy anomalies

    International Nuclear Information System (INIS)

    Bagger, J.; Nemeschansky, D.; Yankielowicz, S.

    1985-05-01

    A new type of anomaly is discussed that afflicts certain non-linear sigma models with fermions. This anomaly is similar to the ordinary gauge and gravitational anomalies since it reflects a topological obstruction to the reparametrization invariance of the quantum effective action. Nonlinear sigma models are constructed based on homogeneous spaces G/H. Anomalies arising when the fermions are chiral are shown to be cancelled sometimes by Chern-Simons terms. Nonlinear sigma models are considered based on general Riemannian manifolds. 9 refs

  3. Isotopic study of Karst water

    International Nuclear Information System (INIS)

    Leskovsek-Sefman, H.

    1985-01-01

    Measurement of the isotopic composition of water formed part of an extended investigation of the water drainage system in the Slovenian Karst. These studies were planned to complement geological and speleological investigations which are already being performed in this area, with the knowledge of the mechanism of changes in the isotopic composition of water in the natural environment on some smaller locations, Planina cave near Postojna where the vertical percolation of meteoric water through the karstified carbonate ceiling was studied and the water catchment areas of some small rivers, Ljubljanica, Rizana and Idrijca. Mass spectrometric investigations of the isotopic composition of some elements ( 18 O, D, 13 C and T) in water and in dissolved carbonates, as well as the isotopic composition of 18 O and 13 C in cave carbonates were performed. The results allow to conclude that the waters in karst aquifers in spite of producing the homogenisation to a great extent, qualitative determination of the retention time and of the prevailing sources for some springs and surface and underground water flows is nevertheless possible. The isotopic composition of 18 O in water and of 18 O and 13 C in dissolved carbonates depends on climatic conditions and on denudation processes. The investigation of cave carbonates revealed that they have different isotopic compositions of 18 O and 13 C because of different locations and also different ages

  4. Performance evaluation of nitrogen isotope ratio determination in marine and lacustrine sediments: An inter-laboratory comparison

    NARCIS (Netherlands)

    Bahlmann, E.; Bernasconi, S.M.; Bouillon, S.; Houtekamer, M.J.; Korntheuer, M.; Langenberg, F.; Mayr, C.; Metzke, M.; Middelburg, J.J.; Nagel, B.; Struck, U.; Voß, M.; Emeis, K.C.

    2010-01-01

    Nitrogen isotopes of organic matter are increasingly studied in marine biogeochemistry and geology, plant and animal ecology, and paleoceanography. Here, we present results of an inter-laboratory test on determination of nitrogen isotope ratios in marine and lacustrine sediments. Six different

  5. CO self-shielding as the origin of oxygen isotope anomalies in the early solar nebula.

    Science.gov (United States)

    Lyons, J R; Young, E D

    2005-05-19

    The abundances of oxygen isotopes in the most refractory mineral phases (calcium-aluminium-rich inclusions, CAIs) in meteorites have hitherto defied explanation. Most processes fractionate isotopes by nuclear mass; that is, 18O is twice as fractionated as 17O, relative to 16O. In CAIs 17O and 18O are nearly equally fractionated, implying a fundamentally different mechanism. The CAI data were originally interpreted as evidence for supernova input of pure 16O into the solar nebula, but the lack of a similar isotope trend in other elements argues against this explanation. A symmetry-dependent fractionation mechanism may have occurred in the inner solar nebula, but experimental evidence is lacking. Isotope-selective photodissociation of CO in the innermost solar nebula might explain the CAI data, but the high temperatures in this region would have rapidly erased the signature. Here we report time-dependent calculations of CO photodissociation in the cooler surface region of a turbulent nebula. If the surface were irradiated by a far-ultraviolet flux approximately 10(3) times that of the local interstellar medium (for example, owing to an O or B star within approximately 1 pc of the protosun), then substantial fractionation of the oxygen isotopes was possible on a timescale of approximately 10(5) years. We predict that similarly irradiated protoplanetary disks will have H2O enriched in 17O and 18O by several tens of per cent relative to CO.

  6. Osmium isotopic tracing of atmospheric emissions from an aluminum smelter

    Science.gov (United States)

    Gogot, Julien; Poirier, André; Boullemant, Amiel

    2015-09-01

    We present for the first time the use of osmium isotopic composition as a tracer of atmospheric emissions from an aluminum smelter, where alumina (extracted from bauxite) is reduced through electrolysis into metallic aluminum using carbonaceous anodes. These anodes are consumed in the process; they are made of petroleum coke and pitch and have high Re/Os elementary ratio. Due to the relatively large geological age of their source material, their osmium shows a high content of radiogenic 187Os produced from in situ187Re radioactive decay. The radiogenic isotopic composition (187Os/188Os ∼ 2.5) of atmospheric particulate emissions from this smelter is different from that of other typical anthropogenic osmium sources (that come from ultramafic geological contexts with unradiogenic Os isotopes, e.g., 187Os/188Os < 0.2) and also different from average eroding continental crust 187Os/188Os ratios (ca. 1.2). This study demonstrates the capacity of osmium measurements to monitor particulate matter emissions from the Al-producing industry.

  7. Anomalies

    International Nuclear Information System (INIS)

    Bardeen, W.A.

    1985-08-01

    Anomalies have a diverse impact on many aspects of physical phenomena. The role of anomalies in determining physical structure from the amplitude for π 0 decay to the foundations of superstring theory will be reviewed. 36 refs

  8. Geologic and mineral and water resources investigations in western Colorado using ERTS-1 data

    Science.gov (United States)

    Knepper, D. H. (Principal Investigator)

    1974-01-01

    The author has identified the following significant results. Most of the geologic information in ERTS-1 imagery can be extracted from bulk processed black and white transparencies by a skilled interpreter using standard photogeologic techniques. In central and western Colorado, the detectability of lithologic contacts on ERTS-1 imagery is closely related to the time of year the imagery was acquired. Geologic structures are the most readily extractable type of geologic information contained in ERTS images. Major tectonic features and associated minor structures can be rapidly mapped, allowing the geologic setting of a large region to be quickly accessed. Trends of geologic structures in younger sedimentary appear to strongly parallel linear trends in older metamorphic and igneous basement terrain. Linears and color anomalies mapped from ERTS imagery are closely related to loci of known mineralization in the Colorado mineral belt.

  9. Identification of active fault using analysis of derivatives with vertical second based on gravity anomaly data (Case study: Seulimeum fault in Sumatera fault system)

    Science.gov (United States)

    Hududillah, Teuku Hafid; Simanjuntak, Andrean V. H.; Husni, Muhammad

    2017-07-01

    Gravity is a non-destructive geophysical technique that has numerous application in engineering and environmental field like locating a fault zone. The purpose of this study is to spot the Seulimeum fault system in Iejue, Aceh Besar (Indonesia) by using a gravity technique and correlate the result with geologic map and conjointly to grasp a trend pattern of fault system. An estimation of subsurface geological structure of Seulimeum fault has been done by using gravity field anomaly data. Gravity anomaly data which used in this study is from Topex that is processed up to Free Air Correction. The step in the Next data processing is applying Bouger correction and Terrin Correction to obtain complete Bouger anomaly that is topographically dependent. Subsurface modeling is done using the Gav2DC for windows software. The result showed a low residual gravity value at a north half compared to south a part of study space that indicated a pattern of fault zone. Gravity residual was successfully correlate with the geologic map that show the existence of the Seulimeum fault in this study space. The study of earthquake records can be used for differentiating the active and non active fault elements, this gives an indication that the delineated fault elements are active.

  10. POTENTIAL GEOLOGICAL SIGNIFICATIONS OF CRISIUM BASIN REVEALED BY CE-2 CELMS DATA

    Directory of Open Access Journals (Sweden)

    Z. Meng

    2018-04-01

    Full Text Available Mare Crisium is one of the most prominent multi-ring basins on the nearside of the Moon. In this study, the regolith thermophysical features of Mare Crisium are studied with the CELMS data from CE-2 satellite. Several important results are as follows. Firstly, the current geological interpretation only by optical data is not enough, and a new geological perspective is provided. Secondly, the analysis of the low TB anomaly combined with the (FeO+TiO2 abundance and Rock abundance suggests a special unknown material in shallow layer of the Moon surface. At last, a new basaltic volcanism is presented for Crisium Basin. The study hints the potential significance of the CELMS data in understanding the geological units over the Moon surface.

  11. Isotope effects of sulfur in chemical reactions

    International Nuclear Information System (INIS)

    Mikolajczuk, A.

    1999-01-01

    Sulfur is an important component of organic matter because it forms compounds with many elements. Due to high chemical activity of sulfur, it takes part in biological and geological processes in which isotope effects are occurring. It has been shown during last years research of isotope effects that we have take into account not only mass difference but also many other physical properties of nuclides e.g. even or odd number of neutrons in nuclei, shape and distribution of charge, turn of nuclear spin etc. The factor remains that new theoretical ideas have been formed on the base of data, being obtained in fractionation processes of heavy element isotope, particularly uranium. Now it is being well known that effects unconnected with vibration energy have also caused an effect on fractionation of considerably lighter elements like iron and magnesium. The important question is, if these effects would come to light during the separation of sulfur isotopes. Sulfur have three even isotopes M = (32, 34, 36) and one odd M 33). This problem is still open. (author)

  12. Anomaly-free models for flavour anomalies

    Science.gov (United States)

    Ellis, John; Fairbairn, Malcolm; Tunney, Patrick

    2018-03-01

    We explore the constraints imposed by the cancellation of triangle anomalies on models in which the flavour anomalies reported by LHCb and other experiments are due to an extra U(1)^' gauge boson Z^' . We assume universal and rational U(1)^' charges for the first two generations of left-handed quarks and of right-handed up-type quarks but allow different charges for their third-generation counterparts. If the right-handed charges vanish, cancellation of the triangle anomalies requires all the quark U(1)^' charges to vanish, if there are either no exotic fermions or there is only one Standard Model singlet dark matter (DM) fermion. There are non-trivial anomaly-free models with more than one such `dark' fermion, or with a single DM fermion if right-handed up-type quarks have non-zero U(1)^' charges. In some of the latter models the U(1)^' couplings of the first- and second-generation quarks all vanish, weakening the LHC Z^' constraint, and in some other models the DM particle has purely axial couplings, weakening the direct DM scattering constraint. We also consider models in which anomalies are cancelled via extra vector-like leptons, showing how the prospective LHC Z^' constraint may be weakened because the Z^' → μ ^+ μ ^- branching ratio is suppressed relative to other decay modes.

  13. Hf Isotope Evidence for Subducted Basalt and Sediment Contributions to the Eastern Trans-Mexican Volcanic Belt

    Science.gov (United States)

    Cai, Y.; Tuena, A. G.; Capra, L.; Straub, S. M.; Goldstein, S. L.; Langmuir, C. H.

    2005-12-01

    Magmas generated at thick crust continental arcs often have enriched continental crust-like trace element patterns and Pb-Sr-Nd isotope ratios that are intermediate to both upper mantle and crustal compositions. Thus it is difficult to distinguish between contributions from (a) the subducted basalt and the upper mantle wedge, and (b) subducted sediment and the continental crust. These issues have been the focus of major controversy. Here we show evidence for subduction contributions to lavas in a classic thick crust environment. In Eastern Trans-Mexican Volcanic Belt, the upper continental crust is 30 km to 45 km thick. However, primitive mafic lavas erupt on many sites across the arc. We have analyzed the subducting sediments as represented by DSDP 487, located seaward of the trench, where the lower third of the sediment column has strongly hydrothermal pelagic features and the upper two-thirds is composed of terrigenous sediments. The pelagic sediments have distinctive features that could be used to identify a subduction component in the volcanics, including high REE/Hf, negative Ce anomalies, and Nd-Hf isotopes that lie on the "seawater array" and offset from the "mantle-crust" array. We have focused on a unique series of lavas from volcano Nevado de Toluca, located southwest of Mexico City. These lavas show negative Ce anomalies coupled with low REE/Hf and Zr/Nd ratios. Hf-Nd isotope ratios show a shallow trend compared to the mantle-crust array, consistent with a pelagic component. In addition, Hf isotopes show a striking positive correlation with Ce anomalies that trend toward the pelagic sediment compositions. These and other observations provide clear evidence for a component from subducted sediment in the lavas. In addition, there is a negative correlation of Lu/Hf and Hf isotopes that requires a mixing endmember with MORB-like Hf isotope ratios but with lower than MORB Lu/Hf. This indicates a melt from eclogitic subducted basalt. Compared to other

  14. Ages and Growth of the Continental Crust from Radiogenic Isotopes

    Science.gov (United States)

    Patchett, P. J.; Samson, S. D.

    2003-12-01

    The development and application of radiogenic isotopes to dating of geologic events, and to questions of growth, evolution, and recycling processes in the continental crust are mature areas of scientific inquiry. By this we understand that many of the approaches used to date rocks and constrain the evolution of the continents are well established, even routine, and that the scope of data available on age and evolution of continents is very large. This is not to say that new approaches have not been developed in recent years, or that new approaches and/or insights cannot be developed in the future. However, the science of continental crustal evolution is definitely a domain where many of the problems are well defined, the power of the techniques used to solve them are well known, and the limitations of field and laboratory databases, as well as the preserved geologic record, are understood.From the very early days of crustal evolution studies, it was innovations and improvements in laboratory techniques that drove the pace of discovery (e.g., Holmes, 1911; Nier, 1939). This remained true through all the increments in capability reviewed in this chapter, up to the present day. Thus, continental crustal evolution is an area of Earth science where a species of very laboratory-oriented investigator, the "radiogenic isotope geologist" or "geochronologist," has made major advances, even breakthroughs, in understanding. This is true in spite of the fact that many of the individuals of the species may have lacked field expertise, or even more than a primitive level of geologic background. Because design and building of instruments like radiation detectors or mass spectrometers requires a knowledge of physics, many of the early practitioners of rock dating were physicists, like Alfred Nier (cited above). Since the 1970s, essentially all mass spectrometers have been constructed by specialized commercial firms, and the level of physics expertise among isotope geologists has

  15. Validation of multi-element isotope dilution ICPMS for the analysis of basalts

    Energy Technology Data Exchange (ETDEWEB)

    Willbold, M.; Jochum, K.P.; Raczek, I.; Amini, M.A.; Stoll, B.; Hofmann, A.W. [Max-Planck-Institut fuer Chemie, Mainz (Germany)

    2003-09-01

    In this study we have validated a newly developed multi-element isotope dilution (ID) ICPMS method for the simultaneous analysis of up to 12 trace elements in geological samples. By evaluating the analytical uncertainty of individual components using certified reference materials we have quantified the overall analytical uncertainty of the multi-element ID ICPMS method at 1-2%. Individual components include sampling/weighing, purity of reagents, purity of spike solutions, calibration of spikes, determination of isotopic ratios, instrumental sources of error, correction of mass discrimination effect, values of constants, and operator bias. We have used the ID-determined trace elements for internal standardization to improve indirectly the analysis of 14 other (mainly mono-isotopic trace elements) by external calibration. The overall analytical uncertainty for those data is about 2-3%. In addition, we have analyzed USGS and MPI-DING geological reference materials (BHVO-1, BHVO-2, KL2-G, ML3B-G) to quantify the overall bias of the measurement procedure. Trace element analysis of geological reference materials yielded results that agree mostly within about 2-3% relative to the reference values. Since these results match the conclusions obtained by the investigation of the overall analytical uncertainty, we take this as a measure for the validity of multi-element ID ICPMS. (orig.)

  16. What can Fe stable isotopes tell us about magmas?

    DEFF Research Database (Denmark)

    Stausberg, Niklas

    the differentiation of magmas from the perspective of Fe stable isotopes, integrated with petrology, by studying igneous rocks and their constituent phases (minerals and glasses) from the Bushveld Complex, South Africa, Thingmuli, Iceland, Pantelleria, Italy, and the Bishop Tuff, USA. The findings are interpreted......The majority of the Earth’s crust is formed by magmas, and understanding their production and differentiation is important to interpret the geologic rock record. A powerful tool to investigate magmatic processes is the distribution of the stable isotopes of the major redox-sensitive element...... in magmas, Fe. Fe isotope compositions of magmatic rocks exhibit systematic differences, where the heaviest compositions are found in rhyolites and granites. Understanding of these systematics is complicated by a lack of constraints on Fe isotope fractionation among minerals and liquids under magmatic...

  17. Stable Isotope Group 1984 progress report

    International Nuclear Information System (INIS)

    Lyon, G.L.

    1985-04-01

    The work of the group in 1984 is described and includes studies in isotope geology, isotope hydrology, geochronology, isotope biology and mass spectrometer instrumentation. Geothermal studies have decreased compared to other years, but major data summaries were made for Wairakei and Ngawha. The hydrology of Whakarewarewa and Rotorua is being elucidated using water isotopes. Models of the subsurface flows at Kawerau and Ngawha are being made to relate fluid to mineral isotope compositions. A study of the δ 13 C and δ 34 S compositions of New Zealand oils has been started. Groups of oils of related origin are being defined, and compositions will be compared with those of potential source rocks. A method was developed for isotope analysis of sulphur in rocks. The isotopic composition of water is being used to identify and characterise groundwater aquifers in the Wairarapa and at Poverty Bay. Stable carbon isotopes have been used to identify food sources for invertebrates, and to show biochemical pathways in lactation by cows. The geochronology group is involved in major studies in Antarctica, using U-Pb, Rb-Sr and K-Ar methods. Rocks from North Victoria Land, Marie Byrd Land and the USARP mountains are being compared with possible correlatives in New Zealand and Argentina. Strontium isotope data is being applied to the origin of magmas in several regions of New Zealand. The K-Ar data is being stored on computer files. Fission track measurements are being applied to unravel uplift histories in Westland and Taranaki

  18. Testing Urey's carbonate-silicate cycle using the calcium isotopic composition of sedimentary carbonates

    Science.gov (United States)

    Blättler, Clara L.; Higgins, John A.

    2017-12-01

    Carbonate minerals constitute a major component of the sedimentary geological record and an archive of a fraction of the carbon and calcium cycled through the Earth's surface reservoirs for over three billion years. For calcium, carbonate minerals constitute the ultimate sink for almost all calcium liberated during continental and submarine weathering of silicate minerals. This study presents >500 stable isotope ratios of calcium in Precambrian carbonate sediments, both limestones and dolomites, in an attempt to characterize the isotope mass balance of the sedimentary carbonate reservoir through time. The mean of the dataset is indistinguishable from estimates of the calcium isotope ratio of bulk silicate Earth, consistent with the Urey cycle being the dominant mechanism exchanging calcium among surface reservoirs. The variability in bulk sediment calcium isotope ratios within each geological unit does not reflect changes in the global calcium cycle, but rather highlights the importance of local mineralogical and/or diagenetic effects in the carbonate record. This dataset demonstrates the potential for calcium isotope ratios to help assess these local effects, such as the former presence of aragonite, even in rocks with a history of neomorphism and recrystallization. Additionally, 29 calcium isotope measurements are presented from ODP (Ocean Drilling Program) Site 801 that contribute to the characterization of altered oceanic crust as an additional sink for calcium, and whose distinct isotopic signature places a limit on the importance of this subduction flux over Earth history.

  19. Uranium-lead dating method at the Pará-Iso isotope geology laboratory, UFPA, Belém - Brazil

    Directory of Open Access Journals (Sweden)

    Robert S. Krymsky

    2007-03-01

    Full Text Available Analytical procedures for U-Pb isotope dilution analyses at the Pará-Iso isotope geology laboratory of the Federal University of Pará (UFPA are described in detail. The procedures are applied to zircon, titanite, rutile, apatite, columbite-tantalite and whole rock. Reagent preparation and chemical processing are done in clean-room conditions. Samples are dissolved using TeflonTM microcapsules in steel jacket TeflonTM Parr InstrumentTM bomb or TeflonTM screw cap containers. U and Pb are separated using anion exchange AG 1x8 resin columns. Typical blanks for mineral sample amounts of 0.01 to 1.0 mg are less than 1 pg U and 20-30 pg Pb. Isotope analysis of the U and Pb from the same filament are carried out using a Finnigan MAT 262 mass-spectrometer in static and dynamic modes. The current analytical level is demonstrated on analyses of international standard zircon 91500 with three different 235U-205Pb and 235U-208Pb isotope tracers and whole rock standards. Results of analyses of two zircon samples are also presented.Os procedimentos analíticos para análises U-Pb por diluição isotópica no Laboratório de Geologia Isotópica (Pará-Iso da Universidade Federal do Pará (UFPA são descritos detalhadamente. Esses procedimentos são aplicados para análises de zircão, titanita, rutilo, apatita, columbita-tantalita e rocha total. A purificação dos reagentes e os procedimentos químicos são feitos em salas limpas. As amostras são dissolvidas em microcápsulas de Teflon em bombas do tipo Parr InstrumentTM. U e Pb são separados em colunas com resina de troca iônica AG 1x8. Os brancos de procedimento para amostra típica(0,01-1 mg são menores que 1 pg de U e 20-30 pg de Pb. As análises isotópicas de Pb e de U são feitas em um único filamento de Re em um espectrômetro de massa Finnigan MAT 262 nos modos estático e dinâmico. O nível analítico atual é comprovado pelas análises do padrão internacional de zircão 91500, usando tr

  20. SO2 photoexcitation mechanism links mass-independent sulfur isotopic fractionation in cryospheric sulfate to climate impacting volcanism

    Science.gov (United States)

    Hattori, Shohei; Schmidt, Johan A.; Johnson, Matthew S.; Danielache, Sebastian O.; Yamada, Akinori; Ueno, Yuichiro; Yoshida, Naohiro

    2013-01-01

    Natural climate variation, such as that caused by volcanoes, is the basis for identifying anthropogenic climate change. However, knowledge of the history of volcanic activity is inadequate, particularly concerning the explosivity of specific events. Some material is deposited in ice cores, but the concentration of glacial sulfate does not distinguish between tropospheric and stratospheric eruptions. Stable sulfur isotope abundances contain additional information, and recent studies show a correlation between volcanic plumes that reach the stratosphere and mass-independent anomalies in sulfur isotopes in glacial sulfate. We describe a mechanism, photoexcitation of SO2, that links the two, yielding a useful metric of the explosivity of historic volcanic events. A plume model of S(IV) to S(VI) conversion was constructed including photochemistry, entrainment of background air, and sulfate deposition. Isotopologue-specific photoexcitation rates were calculated based on the UV absorption cross-sections of 32SO2, 33SO2, 34SO2, and 36SO2 from 250 to 320 nm. The model shows that UV photoexcitation is enhanced with altitude, whereas mass-dependent oxidation, such as SO2 + OH, is suppressed by in situ plume chemistry, allowing the production and preservation of a mass-independent sulfur isotope anomaly in the sulfate product. The model accounts for the amplitude, phases, and time development of Δ33S/δ34S and Δ36S/Δ33S found in glacial samples. We are able to identify the process controlling mass-independent sulfur isotope anomalies in the modern atmosphere. This mechanism is the basis of identifying the magnitude of historic volcanic events. PMID:23417298

  1. Seismic yield verification and a regional M/sub s/ vs m/sub b/ anomaly

    International Nuclear Information System (INIS)

    Rodean, H.C.

    1976-01-01

    The surface-wave magnitude (M/sub s/) and body-wave magnitude (m/sub b/) data for explosions in the western United States are anomalous with respect to such data for the Aleutians, the Sahara, and the USSR. The degree of this anomaly is such that it has significant implications with respect to using magnitude vs yield data from the Nevada Test Site to estimate the yields of explosions in other parts of the world. This report presents the results of a literature survey of seismic and other geophysical evidence relating to this anomaly. The geology and geophysics of three regions are considered: (1) the Basin and Range province in the western United States, (2) the Baikal rift zone in the USSR, and (3) central Kazakhstan in the USSR. Complete geophysical models, which would be of value in explaining the M/sub s/ vs m/sub b/ anomaly, have not been developed for any of these regions

  2. Recognition of possible strong earthquake epicenters. VII. Use of gravitational Bouguer anomaly for California and adjacent regions

    Energy Technology Data Exchange (ETDEWEB)

    Artem' ev, M E; Rotvain, I M; Sadovskii, A M

    1977-01-01

    The possibility of using gravimetric data (Bouguer anomalies) as initial material for determining possible strong earthquake epicenters is determined with the aid of recognition algorithms. This was done for the purpose of correlating geological-geomorphological results and analyzing gravimetric indicators obtained in the study. 9 references, 4 figures, 6 tables.

  3. Introduction to chemistry and applications in nature of mass independent isotope effects special feature.

    Science.gov (United States)

    Thiemens, Mark H

    2013-10-29

    Stable isotope ratio variations are regulated by physical and chemical laws. These rules depend on a relation with mass differences between isotopes. New classes of isotope variation effects that deviate from mass dependent laws, termed mass independent isotope effects, were discovered in 1983 and have a wide range of applications in basic chemistry and nature. In this special edition, new applications of these effects to physical chemistry, solar system origin models, terrestrial atmospheric and biogenic evolution, polar paleo climatology, snowball earth geology, and present day atmospheric sciences are presented.

  4. The Etendeka lavas SWA/Namibia: geology, chemistry and spatial and temporal relationships

    International Nuclear Information System (INIS)

    Marsh, J.S.; Erlank, A.J.; Duncan, A.R.; Miller, R.McG.; Rex, D.C.

    1981-01-01

    The paper discusses a geologic survey on the Etendeka lavas in South West Africa/Namibia with special attention to the geology, chemistry and spatial and temporal relationships in the area. K/Ar age data indicate that the bulk of the Etendeka lavas are about 120 m.y. old. In the study use was also made of 87 Sr/ 86 Sr, 143 Nd/ 144 Nd, 206 Pb/ 204 Pb, 207 Pb/ 204 Pb and 208 Pb/ 204 Pb isotope ratios

  5. Stable isotope ratio mass spectrometry in forensic science and food adulteration research

    International Nuclear Information System (INIS)

    Kumar, B.

    2009-01-01

    Stable Isotope Ratio Mass Spectrometry (SIRMS) is an established technique for the determination of origin of geological, biological, chemical and physio-chemical samples/materials. With the development of highly precise mass spectrometers, the stable isotope ratio determination of hydrogen, carbon, nitrogen and oxygen have gained considerable interest in the fields of forensic science and food authentication. Natural variations in the isotopic composition of lighter elements occur due to fractionation effects, resulting in the finger printing of specific isotope ratio values that are characteristic of the origin, purity, and manufacturing processes of the products and their constituents. Forensic science uses scientific and technical methods to investigate traceable evidence of criminal acts. Stable isotope ratio mass spectrometry has been applied to numerous aspects of the forensic science. The analysis of explosives such as ammonium nitrate, gun powder and tri-nitro-toluene (TNT), cases of murder, armed robbery, drug smuggling, terrorism, arson and hit and run traffic accidents are a few of them. The main types of geological evidences in such cases are mud, soil, rocks, sand, gravel, dust particles, biological materials, organic particles and anthropogenic components. Stable isotopes are used as tools to corroborate and confirm the evidential leads in the investigation of such crimes. The variation in natural abundances of carbon and nitrogen and their isotopic ratios δ 13 C and δ 15 N can identify links between items found at crime scene with those of suspect. The paper discusses the applications of SIRMS in the field of forensic science and food adulteration research

  6. CHARACTERIZATION OF GEOLOGICAL MATERIALS USING ION AND PHOTON BEAMS

    International Nuclear Information System (INIS)

    TOROK, SZ.B.; JONES, K.W.; TUNIZ, C.

    1998-01-01

    Geological specimens are often complex materials that require different analytical methods for their characterization. The parameters of interest may include the chemical composition of major, minor and trace elements. The chemical compounds incorporated in the minerals, the crystal structure and isotopic composition need to be considered. Specimens may be highly heterogeneous thus necessitating analytical methods capable of measurements on small sample volumes with high spatial resolution and sensitivity. Much essential information on geological materials can be obtained by using ion or photon beams. In this chapter we describe the principal analytical techniques based on particle accelerators, showing some applications that are hardly possible with conventional methods. In particular, the following techniques will be discussed: (1) Synchrotron radiation (SR) induced X-ray emission (SRIXE) and particle-induced X-ray emission (PEE) and other ion beam techniques for trace element analysis. (2) Accelerator mass spectrometry (AMS) for ultra sensitive analysis of stable nuclides and long-lived radionuclides. In most of the cases also the possibilities of elemental and isotopic analysis with high resolution will be discussed

  7. Geological factors of the isotopic distribution of carbon of organic matter in sedimentary rocks

    International Nuclear Information System (INIS)

    Maass, J.

    1981-01-01

    The isotope ratio of carbon of fossile organic matter can be regarded as a definite criterion of its genetic origin. As the biofacial character of organic matter, especially the chemical composition (H/C-ratio), decisively influences the mode and quantity of the potential hydrocarbon production, isotopic analysis is an essential method for the prognostic evaluation of sedimentary basins with regard to their oil and gas perspectives. The genetic relations to the parent substance continue in the bituminization and coalification products and make it possible to apply the isotopic analysis of carbon to prospection work for hydrocarbons. (author)

  8. Tracking ENSO with tropical trees: Progress in stable isotope dendroclimatology

    Science.gov (United States)

    Evans, M. N.; Poussart, P. F.; Saleska, S. R.; Schrag, D. P.

    2002-12-01

    The terrestrial tropics remain an important gap in the growing proxy network used to characterize past ENSO behavior. Here we describe a strategy for development of proxy estimates of paleo-ENSO, via proxy rainfall estimates derived from stable isotope (δ18O) measurements made on tropical trees. The approach applies a new model of oxygen isotopic composition of alpha-cellulose (Roden et al., 2000), a rapid method for cellulose extraction from raw wood (Brendel et al., 2000), and continuous flow isotope ratio mass spectrometry (Brand, 1996) to develop proxy chronological, rainfall and growth rate estimates from tropical trees, even those lacking annual rings. The promise and pitfalls of the approach are illustrated in pilot datasets from the US, Costa Rica, Brazil, and Peru, which show isotopic cycles of 4-6 per mil, and interannual anomalies of up to 8 per mil. Together with the mature ENSO proxies (corals, extratropical tree-rings, varved sediments, and ice cores), replicated and well-dated stable isotope chronologies from tropical trees may eventually improve our understanding of ENSO history over the past several hundred years.

  9. Rubidium-strontium and uranium-lead isotopic age studies

    International Nuclear Information System (INIS)

    Loveridge, W.D.

    1981-01-01

    The results of five Rb-Sr isotopic age studies predominantly on whole-rock samples, and six U-Pb studies on zircon monazite concentrates are presented. Descriptions of the geological problems and interpretations of the measured ages are included. Laboratory age determination methods and techniques are described or referenced

  10. Lithologic boundaries from gravity and magnetic anomalies over Proterozoic Dalma volcanics

    Science.gov (United States)

    Yadav, Pramod Kumar; Adhikari, P. K.; Srivastava, Shalivahan; Maurya, Ved P.; Tripathi, Anurag; Singh, Shailendra; Singh, Roshan K.; Bage, Ashish K.

    2018-03-01

    Dalma volcanics (DVs) has intruded the older Singhbhum Group of Metapelites. Despite DVs being rich in mineralisation, its boundaries are not clearly demarcated. Gravity and magnetic surveys have been attempted for mapping the boundaries in DVs. These surveys were made in the northern fringe of the DVs over an area of ˜ 0.70 km2 along 13 parallel lines at 50 m spacing. The data was acquired at ˜ 25 m spacing. The surveys were taken for determination of lithological boundaries, depths and nature of causative source using Euler depth solutions and radially averaged power spectrum (RAPS). Residual anomaly maps of gravity and magnetic intensity show the same trend as that of Bouguer gravity anomaly and total magnetic intensity anomaly map indicating towards shallow sources. The magnetic map in general follows the same pattern as that of gravity anomaly maps. The map shows coincident high gravity and magnetic anomalies. These anomalies together with resistivity signatures confirm that the northern fringe of DVs hosts volcanogenic massive sulphide settings. The Euler depth solution delineated the lateral boundaries and nature of the source. It seems that the source is of spherical nature lying within a depth range of 25-40 m. The obtained lithological (vertical) units from RAPS are between Lower DVs, Upper DVs and Singhbhum Group Metapelites at depths of ˜ 15, ˜ 25 and ˜ 40 m, respectively. The metallogeny is associated with the Upper DVs and the corresponding delineated lithological (vertical) unit is indicative of the top of the ore body. Good agreement is observed with the geological succession from the drilling data and resistivity data. The findings suggest that the northern fringe of DVs could be a preferred target for drilling.

  11. Gravity and Areomagnetic Signatures and their Geological Significance in the Abu Gharadig Basin, Nortwestern Desert, Egypt

    International Nuclear Information System (INIS)

    Ibrahim, H.A.

    2000-01-01

    Geological interpretation of Bouguer gravity anomalies and total intensity magnetic anomalies of two profiles from the Abu Gharadig Basin suggests a general northward increase in basement depth (about 3 to 6 km). Gravity modeling using software given by Enmark (1981) and Beg et. al (1987) are applied along the gravity profiles, giving reliable results agreeing with the available geological information on the area. The magenetic profiles are interpreted and analyzed using two methods: non-linear optimization techniques and interactive techniques. A prominent uplift of the basement rock is observed to the south, which is considered a part of the major basement high in the north Western Desert of the Egypt. In addition a significant deepning of the basement is found to the north, which represents a part of the major subsidence including the present Mediterranean BasinThe abnormal thickness of the sedimentary section of varius facies, and the presence of deep-causative intrabasement (acidic or basic bodies) are possibly considered the main cause for 1) the origin of different gravity anamolies (negative and positive respectively); and 2) the origin of different magnetic anomalies (low and high), particularly those in the middle part of the study area. (author)

  12. Isotopic evidence bearing on Late Triassic extinction events, Queen Charlotte Islands, British Columbia, and implications for the duration and cause of the Triassic/Jurassic mass extinction

    Science.gov (United States)

    Ward, P.D.; Garrison, G.H.; Haggart, J.W.; Kring, D.A.; Beattie, M.J.

    2004-01-01

    Stable isotope analyses of Late Triassic to earliest Jurassic strata from Kennecott Point in the Queen Charlotte Islands, British Columbia, Canada shows the presence of two distinct and different organic carbon isotope anomalies at the Norian/Rhaetian and Rhaetian/Hettangian (=Triassic/Jurassic) stage boundaries. At the older of these boundaries, which is marked by the disappearance of the bivalve Monotis, the isotope record shows a series of short-lived positive excursions toward heavier values. Strata approaching this boundary show evidence of increasing anoxia. At the higher boundary, marked by the disappearance of the last remaining Triassic ammonites and over 50 species of radiolarians, the isotopic pattern consists of a series of short duration negative anomalies. The two events, separated by the duration of the Rhaetian age, comprise the end-Triassic mass extinction. While there is no definitive evidence as to cause, the isotopic record does not appear similar to that of the impact-caused Cretaceous/Tertiary boundary extinction. ?? 2004 Published by Elsevier B.V.

  13. Geochemical behavior of beryllium isotopes in the ocean

    International Nuclear Information System (INIS)

    Kusakabe, M.; Ku, T.L.; Cusimano, G.L.; Southon, J.R.; Measures, C.I.

    1989-01-01

    9 Be and 10 Be have been measured in a variety of geological samples: sea water, marine particulate, bottom sediment and river water. While the 10 Be/ 9 Be ratio in the Pacific deep water seems to be constant, ∼ 1 x 10 -7 , the deep water in the Atlantic Ocean has significantly lower and variable ratio (0.7 x 10 -7 or less), reflecting larger input of riverine 9 Be to the Atlantic Ocean. The study of Be isotopes in river water, sea water, and sediment pore water from the southern California borderland shows that coastal areas play an important role in the removal of Be isotopes from the ocean. The behavior of particulate Be isotopes in the ocean is also discussed

  14. The effect of scale on the interpretation of geochemical anomalies

    Science.gov (United States)

    Theobald, P.K.; Eppinger, R.G.; Turner, R.L.; Shiquan, S.

    1991-01-01

    conduits for mineralizing fluids. At a larger scale, the linear, northeast-trending anomalies can be shown to result from a series of discrete mineralized systems with different ages and mineral assemblages. The linear pattern of anomalies disintegrates. A regional geochemical survey in the Sonoran Desert in southwestern Arizona displays a cluster of samples anomalous in Pb, Mo, Bi and W. In detail, the original regional anomaly separates into four discrete anomalous areas, each with its own distinctive suite of elements, geographic distribution and age of mineralization. A prominent regional gold anomaly in the Gobi Desert, Xinjiang, Peoples Republic of China, extends southeastward for 30 km from known lode gold deposits. Because the anomaly cuts both lithologic units and the structural grain, and because it parallels the prevailing direction of high-velocity winds, it was originally attributed to eolian dispersion. In detail, the regional anomaly consists of several east-west-trending anomalies, parallel to local lithology and structure that most likely reflect independent sources of lode gold. The regional anomaly results from smoothing of an en-echelon set of local anomalies. These examples emphasize that interpretation of regional anomalies must be tempered to consider regional-sized geologic features. Attempts to overinterpret anomalies by assigning deposit-scale attributes to regional anomalies can lead to confusion and incorrect interpretations. Potential targets that can be readily resolved only at intermediate or detailed scales of study may be overlooked. ?? 1991.

  15. How the oxygen isotope ratio of rain water influences the isotope ratio of chicken eggshell carbonate

    Science.gov (United States)

    Price, Gregory; Grimes, Stephen

    2015-04-01

    The stable oxygen isotope ratio of chicken eggshell carbonate was analysed from chicken eggs laid under free range, and organic farming regimes from across the UK. The eggshell carbonate oxygen isotope data shows a clear depletion in delta18O distribution from the southwest to the northeast. Although consistently offset by around 1 permil, the same isotopic distribution as that seen in eggshell carbonate is observed in the delta18O ratio of rainfall and groundwater from across the UK. This distribution is related to the Rayleigh distillation of rainfall driven by westerly winds across the UK landmass. The clear relationship observed between eggshell delta18O values and that of rainwater presumably reflects the nature of free range chickens which must be drinking locally derived rainwater and supplementing their diet and water intake with locally derived food. These results suggest that the oxygen isotope value of chicken eggshells can be used as a forensic tool to identify the locality that free range and organic eggs were laid within the UK. Furthermore, if suitable material is preserved in the archaeological and geological record then such a relationship can potentially be used to establish the oxygen isotope value of rainwater from which ancient and / or ancestral birds lived.

  16. The chlorine isotope fingerprint of the lunar magma ocean.

    Science.gov (United States)

    Boyce, Jeremy W; Treiman, Allan H; Guan, Yunbin; Ma, Chi; Eiler, John M; Gross, Juliane; Greenwood, James P; Stolper, Edward M

    2015-09-01

    The Moon contains chlorine that is isotopically unlike that of any other body yet studied in the Solar System, an observation that has been interpreted to support traditional models of the formation of a nominally hydrogen-free ("dry") Moon. We have analyzed abundances and isotopic compositions of Cl and H in lunar mare basalts, and find little evidence that anhydrous lava outgassing was important in generating chlorine isotope anomalies, because (37)Cl/(35)Cl ratios are not related to Cl abundance, H abundance, or D/H ratios in a manner consistent with the lava-outgassing hypothesis. Instead, (37)Cl/(35)Cl correlates positively with Cl abundance in apatite, as well as with whole-rock Th abundances and La/Lu ratios, suggesting that the high (37)Cl/(35)Cl in lunar basalts is inherited from urKREEP, the last dregs of the lunar magma ocean. These new data suggest that the high chlorine isotope ratios of lunar basalts result not from the degassing of their lavas but from degassing of the lunar magma ocean early in the Moon's history. Chlorine isotope variability is therefore an indicator of planetary magma ocean degassing, an important stage in the formation of terrestrial planets.

  17. Early inner solar system origin for anomalous sulfur isotopes in differentiated protoplanets.

    Science.gov (United States)

    Antonelli, Michael A; Kim, Sang-Tae; Peters, Marc; Labidi, Jabrane; Cartigny, Pierre; Walker, Richard J; Lyons, James R; Hoek, Joost; Farquhar, James

    2014-12-16

    Achondrite meteorites have anomalous enrichments in (33)S, relative to chondrites, which have been attributed to photochemistry in the solar nebula. However, the putative photochemical reactions remain elusive, and predicted accompanying (33)S depletions have not previously been found, which could indicate an erroneous assumption regarding the origins of the (33)S anomalies, or of the bulk solar system S-isotope composition. Here, we report well-resolved anomalous (33)S depletions in IIIF iron meteorites (solar system (solar system S-isotope composition was chondritic (consistent with IAB iron meteorites, Earth, Moon, and Mars). The range of mass-independent sulfur isotope compositions may reflect spatial or temporal changes influenced by photochemical processes. A tentative correlation between S isotopes and Hf-W core segregation ages suggests that the two systems may be influenced by common factors, such as nebular location and volatile content.

  18. Offshore geology and geomorphology from Point Piedras Blancas to Pismo Beach, San Luis Obispo County, California

    Science.gov (United States)

    Watt, Janet Tilden; Johnson, Samuel Y.; Hartwell, Stephen R.; Roberts, Michelle

    2015-01-01

    Marine geology and geomorphology were mapped along the continental shelf and upper slope between Point Piedras Blancas and Pismo Beach, California. The map area is divided into the following three (smaller) map areas, listed from north to south: San Simeon, Morro Bay, and Point San Luis. Each smaller map area consists of a geologic map and the corresponding geophysical data that support the geologic mapping. Each geophysical data sheet includes shaded-relief multibeam bathymetry, seismic-reflection-survey tracklines, and residual magnetic anomalies, as well as a smaller version of the geologic map for reference. Offshore geologic units were delineated on the basis of integrated analysis of adjacent onshore geology, seafloor-sediment and rock samples, multibeam bathymetry and backscatter imagery, magnetic data, and high-resolution seismic-reflection profiles. Although the geologic maps are presented here at 1:35,000 scale, map interpretation was conducted at scales of between 1:6,000 and 1:12,000.

  19. Mixed total screening for sulfur isotope

    International Nuclear Information System (INIS)

    Cui Bin; Zhao Lei; Zhan Zhaoyang; He Zhijun

    2003-01-01

    The research on modern economic geology indicates that most ore deposits formed with characters of multi-origin, multi-stage and multi-genesis. Quantificational research of Sulfur isotope origin is a difficult problem that puzzles Geochemists all along. So the formation process of an ore deposit can be taken as the mix or the superposition of multi totals, which can be described by the mathematics model of mixed total screening. In the study of mid-down Yangtze River and Dongpo ore field in Hunan province, the authors successfully applied the mathematics model of mixed total screening, quantificationally resolved the problem of Sulfur isotope origin and mineralizing matter origin, and found out the mineralizing mechanism. This is very valuable. (authors)

  20. 196Hg and 202Hg isotopic ratios in chondrites: revisited

    International Nuclear Information System (INIS)

    Jovanovic, S.; Reed, G.W. Jr.

    1976-01-01

    Additional evidence for an isotopically anomalous Hg fraction in unequilibrated meteorites has been obtained using neutron activation to produce 196 Hg and 202 Hg followed by stepwise heating to extract the Hg. In the latest experiments Allende matrix samples released the anomalous Hg but various high-temperature inclusions did not. Nucleogenetic processes are suggested as the probable cause of the anomaly. (Auth.)

  1. Isotope composition and volume of Earth's early oceans.

    Science.gov (United States)

    Pope, Emily C; Bird, Dennis K; Rosing, Minik T

    2012-03-20

    Oxygen and hydrogen isotope compositions of Earth's seawater are controlled by volatile fluxes among mantle, lithospheric (oceanic and continental crust), and atmospheric reservoirs. Throughout geologic time the oxygen mass budget was likely conserved within these Earth system reservoirs, but hydrogen's was not, as it can escape to space. Isotopic properties of serpentine from the approximately 3.8 Ga Isua Supracrustal Belt in West Greenland are used to characterize hydrogen and oxygen isotope compositions of ancient seawater. Archaean oceans were depleted in deuterium [expressed as δD relative to Vienna standard mean ocean water (VSMOW)] by at most 25 ± 5‰, but oxygen isotope ratios were comparable to modern oceans. Mass balance of the global hydrogen budget constrains the contribution of continental growth and planetary hydrogen loss to the secular evolution of hydrogen isotope ratios in Earth's oceans. Our calculations predict that the oceans of early Earth were up to 26% more voluminous, and atmospheric CH(4) and CO(2) concentrations determined from limits on hydrogen escape to space are consistent with clement conditions on Archaean Earth.

  2. Modeling and Inversion of three-dimensional crustal structures beneath the Pyrenees and their foreland basins based upon geological, gravimetric and seismological data

    Science.gov (United States)

    Spangenberg, Hannah; Chevrot, Sébastien; Courrioux, Gabriel; Guillen, Antonio

    2017-04-01

    Our goal is to obtain a three-dimensional (3D) model of mass density and seismic velocities beneath the Pyrenees and their foreland basins (Aquitaine and Ebro basins), which accounts for all the geological and geophysical information available for that region. This model covers the whole mountain range going from the Atlantic Ocean to the Mediterranean Sea, and from the Iberian range to the Massif Central. The model is described by different units: the lower, middle, and upper crusts, the accretionary prism, and the consolidated and unconsolidated sediment layers. Furthermore, a sub-continental, serpentinized European mantle is introduced to describe the exhumed mantle bodies which are responsible for the positive Bouguer gravity anomalies in the western Pyrenees. We build a first 3D model using all the geological information: drill-hole surveys, seismic sections, and the geological map. We use the potential field method implemented in Geomodeler to interpolate these geological data. However, these data are too sparse to build a model that explains seismic travel times or gravimetric data, especially the Labourd and the St. Gaudens Bouguer gravity anomalies. In addition, inconsistencies between the different data sets exist. We thus add by trial and error additional data points, comparing modeled and observed Bouguer gravimetric anomalies. The result of this procedure is a 3D geological model that respects the geological data and explains the measured Bouguer gravimetric anomalies. In a second step, we use this model to determine the average density and seismic velocities inside each geological unit assuming uniform layers. To constrain the seismic velocities we use travel time picks extracted from the bulletin of the Pyrenean seismicity released by the Observatoire Midi Pyrenées. In a third step, we use this 3D a priori model in a Monte Carlo inversion to invert jointly gravimetric data and seismic travel times from the bulletin. This probabilistic approach

  3. Investigation of Isotope Anomalies in Meteorites and their Components

    DEFF Research Database (Denmark)

    Holst, Jesper Christian

    Cosmochemistry aims to clarify the origin of our solar system and the preconditions for life as we know it. Through the study of meteorites, it is possible to constrain our Sun’s birth environment, the formation and the evolution of the protoplanetary disk of dust and gas that evolved...... then terminated their evolution either on the asymptotic giant branch (AGB) or in supernova explosions at the time when low mass stars like our Sun were forming. In this way, matter incorporated into the nascent solar system must have had diverse origins, some being old inherited presolar grains, others being...... the bulk solar system. Therefore, in order to establish a detailed history of the early solar system and processing of the protoplanetary disk, it is critical to ascertain the isotope variability of a large range of elements of different nucleosynthetic origin. In this thesis, we establish methods...

  4. Using multiple isotopes to understand the source of ingredients used in golden beverages

    Science.gov (United States)

    Wynn, J. G.

    2011-12-01

    Traditionally, beer contains 4 simple ingredients: water, barley, hops and yeast. Each of these ingredients used in the brewing process contributes some combination of a number of "traditional" stable isotopes (i.e., isotopes of H, C, O, N and S) to the final product. As an educational exercise in an "Analytical Techniques in Geology" course, a group of students analyzed the isotopic composition of the gas, liquid and solid phases of a variety of beer samples collected from throughout the world (including other beverages). The hydrogen and oxygen isotopic composition of the water followed closely the isotopic composition of local meteoric water at the source of the brewery, although there is a systematic offset from the global meteoric water line that may be due to the effects of CO2-H2O equilibration. The carbon isotopic composition of the CO2 reflected that of the solid residue (the source of carbon used as a fermentation substrate), but may potentially be modified by addition of gas-phase CO2 from an inorganic source. The carbon isotopic composition of the solid residue similarly tracks that of the fermentation substrate, and may indicate some alcohol fermented from added sugars in some cases. The nitrogen isotopic composition of the solid residue was relatively constant, and may track the source of nitrogen in the barley, hops and yeast. Each of the analytical methods used is a relatively standard technique used in geological applications, making this a "fun" exercise for those involved, and gives the students hands-on experience with a variety of analytes from a non-traditional sample material.

  5. Discrimination between pre-seismic electromagnetic anomalies and solar activity effects

    Science.gov (United States)

    Koulouras, G.; Balasis, G.; Kiourktsidis, I.; Nannos, E.; Kontakos, K.; Stonham, J.; Ruzhin, Y.; Eftaxias, K.; Cavouras, D.; Nomicos, C.

    2009-04-01

    Laboratory studies suggest that electromagnetic emissions in a wide frequency spectrum ranging from kilohertz (kHz) to very high megahertz (MHz) frequencies are produced by the opening of microcracks, with the MHz radiation appearing earlier than the kHz radiation. Earthquakes are large-scale fracture phenomena in the Earth's heterogeneous crust. Thus, the radiated kHz-MHz electromagnetic emissions are detectable not only in the laboratory but also at a geological scale. Clear MHz-to-kHz electromagnetic anomalies have been systematically detected over periods ranging from a few days to a few hours prior to recent destructive earthquakes in Greece. We should bear in mind that whether electromagnetic precursors to earthquakes exist is an important question not only for earthquake prediction but mainly for understanding the physical processes of earthquake generation. An open question in this field of research is the classification of a detected electromagnetic anomaly as a pre-seismic signal associated with earthquake occurrence. Indeed, electromagnetic fluctuations in the frequency range of MHz are known to be related to a few sources, including atmospheric noise (due to lightning), man-made composite noise, solar-terrestrial noise (resulting from the Sun-solar wind-magnetosphere-ionosphere-Earth's surface chain) or cosmic noise, and finally, the lithospheric effect, namely pre-seismic activity. We focus on this point in this paper. We suggest that if a combination of detected kHz and MHz electromagnetic anomalies satisfies the set of criteria presented herein, these anomalies could be considered as candidate precursory phenomena of an impending earthquake.

  6. Discrimination between pre-seismic electromagnetic anomalies and solar activity effects

    International Nuclear Information System (INIS)

    Koulouras, G; Kiourktsidis, I; Stonham, J; Balasis, G; Nannos, E; Kontakos, K; Nomicos, C; Ruzhin, Y; Eftaxias, K; Cavouras, D

    2009-01-01

    Laboratory studies suggest that electromagnetic emissions in a wide frequency spectrum ranging from kilohertz (kHz) to very high megahertz (MHz) frequencies are produced by the opening of microcracks, with the MHz radiation appearing earlier than the kHz radiation. Earthquakes are large-scale fracture phenomena in the Earth's heterogeneous crust. Thus, the radiated kHz-MHz electromagnetic emissions are detectable not only in the laboratory but also at a geological scale. Clear MHz-to-kHz electromagnetic anomalies have been systematically detected over periods ranging from a few days to a few hours prior to recent destructive earthquakes in Greece. We should bear in mind that whether electromagnetic precursors to earthquakes exist is an important question not only for earthquake prediction but mainly for understanding the physical processes of earthquake generation. An open question in this field of research is the classification of a detected electromagnetic anomaly as a pre-seismic signal associated with earthquake occurrence. Indeed, electromagnetic fluctuations in the frequency range of MHz are known to be related to a few sources, including atmospheric noise (due to lightning), man-made composite noise, solar-terrestrial noise (resulting from the Sun-solar wind-magnetosphere-ionosphere-Earth's surface chain) or cosmic noise, and finally, the lithospheric effect, namely pre-seismic activity. We focus on this point in this paper. We suggest that if a combination of detected kHz and MHz electromagnetic anomalies satisfies the set of criteria presented herein, these anomalies could be considered as candidate precursory phenomena of an impending earthquake.

  7. Isotope analytics for the evaluation of the feeding influence on the isotope ratio in beef samples

    International Nuclear Information System (INIS)

    Herwig, Nadine

    2010-01-01

    Information about the origin of food and associated production systems has a high significance for food control. An extremely promising approach to obtain such information is the determination of isotope ratios of different elements. In this study the correlation of the isotope ratios C-13/C-12, N-15/N-14, Mg-25/Mg-24, and Sr-87/Sr-86 in bovine samples (milk and urine) and the corresponding isotope ratios in feed was investigated. It was shown that in the bovine samples all four isotope ratios correlate with the isotope composition of the feed. The isotope ratios of strontium and magnesium have the advantage that they directly reflect the isotope ratios of the ingested feed since there is no isotope fractionation in the bovine organism which is in contrast to the case of carbon and nitrogen isotope ratios. From the present feeding study it is evident, that a feed change leads to a significant change in the delta C-13 values in milk and urine within 10 days already. For the deltaN-15 values the feed change was only visible in the bovine urine after 49 days. Investigations of cows from two different regions (Berlin/Germany and Goestling/Austria) kept at different feeding regimes revealed no differences in the N-15/N-14 and Mg-26/Mg-24 isotope ratios. The strongest correlation between the isotope ratio of the bovine samples and the kind of ingested feed was observed for the carbon isotope ratio. With this ratio even smallest differences in the feed composition were traceable in the bovine samples. Since different regions usually coincide with different feeding regimes, carbon isotope ratios can be used to distinguish bovine samples from different regions if the delta C-13 values of the ingested feed are different. Furthermore, the determination of strontium isotope ratios revealed significant differences between bovine and feed samples of Berlin and Goestling due to the different geologic realities. Hence the carbon and strontium isotope ratios allow the best

  8. Isotopic Generation and Confirmation of the PWR Application Model?

    International Nuclear Information System (INIS)

    L.B. Wimmer

    2003-01-01

    The objective of this calculation is to establish an isotopic database to represent commercial spent nuclear fuel (CSNF) from pressurized water reactors (PWRs) in criticality analyses performed for the proposed Monitored Geologic Repository at Yucca Mountain, Nevada. Confirmation of the conservatism with respect to criticality in the isotopic concentration values represented by this isotopic database is performed as described in Section 3.5.3.1.2 of the ''Disposal Criticality Analysis Methodology Topical Report'' (YMP 2000). The isotopic database consists of the set of 14 actinides and 15 fission products presented in Section 3.5.2.1.1 of YMP 2000 for use in CSNF burnup credit. This set of 29 isotopes is referred to as the principal isotopes. The oxygen isotope from the UO 2 fuel is also included in the database. The isotopic database covers enrichments of 235 U ranging from 1.5 to 5.5 weight percent (wt%) and burnups ranging from approximately zero to 75 GWd per metric ton of uranium (mtU). The choice of fuel assembly and operating history values used in generating the isotopic database are provided is Section 5. Tables of isotopic concentrations for the 29 principal isotopes (plus oxygen) as a function of enrichment and burnup are provided in Section 6.1. Results of the confirmation of the conservatism with respect to criticality in the isotopic concentration values are provided in Section 6.2

  9. Molecular Identification of the Carrier of the D-Anomaly in Insoluble Organic Matter of Orgueil Meteorite: Revising the Origin of the IOM?

    Science.gov (United States)

    Remusat, L.; Robert, F.; Meibom, A.; Mostefaoui, S.; Delpoux, O.; Binet, L.; Gourier, D.; Derenne, S.

    2008-03-01

    By combining NanoSIMS measurements and pulsed EPR data, we have identified the organic radicals as the carrier of the D-isotopic anomaly in the insoluble organic matter of Orgueil chondrite. This is consistent with a solar origin of the D-signature.

  10. Measurement of mercury isotopic ratio in stone meteorites by neutron activation analysis

    International Nuclear Information System (INIS)

    Thakur, A.N.

    1997-01-01

    196 Hg and 202 Hg isotopes have been measured by neutron activation analysis in samples of twelve stone meteorites. Hg is extracted from an irradiated sample by stepwise heating. The mercury concentrations vary from 0.07 to 33 ppm. While most of the samples give 196 Hg/ 202 Hg ratios similar to terrestrial value within error limits, in some cases large anomalies are observed. A number of control experiments have been devised, that show the absence of experimental artifacts, during sample preparation, neutron irradiation, chemical separation and counting stages. Several anomalous and normal Hg distillate have been re-irradiated as Hg-diethyl-dithio-carbamate complex to eliminate the influence of neutron self shielding and interfering reactions from matrix elements. The isotopic ratio patterns persist in the distillates too proving that any artifacts during meteorite irradiation and measurement are essentially absent. Both positive and negative anomalies are observed: however, the negative anomalies are much more frequent and abundant. In an extreme case of fine grained magnetic particles of Ambapur Nagla the 196 Hg is apparently absent in the Hg released at 100 deg C. A 2σ 196 Hg/ 202 Hg value is only 6% relative to the monitor. This experiment shows the robustness of neutron activation analysis and suggest some constrains on the formation history of stone meteorites. (author)

  11. Isotopic approach to the provenance study of artifacts

    International Nuclear Information System (INIS)

    Mabuchi, Hisao

    1994-01-01

    Isotopic abundance ratios, which are proved to be generally constant, are known to vary, for certain elements, from one place to another. Light elements, such as hydrogen, lithium, boron, carbon, nitrogen, oxygen and sulfur, show measurable variations of their isotope ratios due to isotopic fractionation which takes place during geochemical or biochemical processes. Isotope ratios of strontium and lead vary due to the decay of long-lived radioactive nuclides 87 Rb and 238 U- 235 U- 232 Th, respectively. Such isotopic anomalies can be applicable to provenance studies of archaeological objects. Thus, 13 C/ 12 C, 18 O/ 16 O, or 87 Sr/ 86 Sr were used to examine the authenticity of Greek marble statues. Also, lead isotope ratios have been used since mid-1960s extensively for provenance studies of glasses and bronzes of different civilizations. As an example, the author presents a series of his own works on lead isotope ratios applied to ancient Japanese bronzes, which are summarized as follows. 1) It was generally observed that lead isotope ratios reflect difference in culture to which bronzes belong. 2) Mirrors in the Western Han period (206 B.C. - A.D.8) are clearly distinguished by lead isotope ratios from those made after the mid-Eastern Han period (ca.A.D.150 - 300). 3) Korean mirrors and weapons excavated from the Yayoi sites contain lead of easily recognizable Mississippi Valley type. 4) Bronze objects made in Japan (imitative Han style mirrors, Dotaku, imitative weapons, arrowheads etc.) in the Yayoi and Kofun periods are classified by lead isotope ratios in the following order: the Korean mirror type to the Western Han mirror type in the Yayoi period and the mid- to post- Han mirror type in the Kofun period. 5) Indigenous Japanese lead seems to have been used after the mid-7th century. (J.P.N.)

  12. A stable isotope-based approach to tropical dendroclimatology

    Science.gov (United States)

    Evans, Michael N.; Schrag, Daniel P.

    2004-08-01

    We describe a strategy for development of chronological control in tropical trees lacking demonstrably annual ring formation, using high resolution δ 18O measurements in tropical wood. The approach applies existing models of the oxygen isotopic composition of alpha-cellulose (Roden et al., 2000), a rapid method for cellulose extraction from raw wood (Brendel et al., 2000), and continuous flow isotope ratio mass spectrometry (Brenna et al., 1998) to develop proxy chronological, rainfall and growth rate estimates from tropical trees lacking visible annual ring structure. Consistent with model predictions, pilot datasets from the temperate US and Costa Rica having independent chronological control suggest that observed cyclic isotopic signatures of several permil (SMOW) represent the annual cycle of local rainfall and relative humidity. Additional data from a plantation tree of known age from ENSO-sensitive northwestern coastal Peru suggests that the 1997-8 ENSO warm phase event was recorded as an 8‰ anomaly in the δ 18O of α-cellulose. The results demonstrate reproducibility of the stable isotopic chronometer over decades, two different climatic zones, and three tropical tree genera, and point to future applications in paleoclimatology.

  13. On the 3He anomaly in hot subdwarf B stars

    Science.gov (United States)

    Schneider, David; Irrgang, Andreas; Heber, Ulrich; Nieva, Maria F.; Przybilla, Norbert

    2017-12-01

    Decades ago, 3He isotope enrichment in helium-weak B-type main-sequence, in blue horizontal branch and in hot subdwarf B (sdB) stars, i.e., helium-core burning stars of the extreme horizontal branch, were discovered. Diffusion processes in the atmosphere of these stars lead to the observed abundance anomalies. Quantitative spectral analyses of high-resolution spectra to derive photospheric isotopic helium abundance ratios for known 3He sdBs have not been performed yet. We present preliminary results of high-resolution and high S/N spectra to determine the 3He and 4He abundances of nine known 3He sdBs. We used a hybrid local/non-local thermodynamic equilibrium (LTE/NLTE) approach for B-type stars investigating multiple He i lines, including λ4922 Å and λ6678 Å, which show the strongest isotopic shifts in the optical spectral range.We also report the discovery of four new 3He sdBs from the ESO Supernova Progenitor survey. Most of the 3He sdBs cluster in a narrow temperature strip between ˜ 26000 K and ˜ 30000 K and have almost no atmospheric 4He at all. Interestingly, three 3He sdBs show evidence for vertical helium stratification.

  14. On the 3He anomaly in hot subdwarf B stars

    Directory of Open Access Journals (Sweden)

    Schneider David

    2017-12-01

    Full Text Available Decades ago, 3He isotope enrichment in helium-weak B-type main-sequence, in blue horizontal branch and in hot subdwarf B (sdB stars, i.e., helium-core burning stars of the extreme horizontal branch, were discovered. Diffusion processes in the atmosphere of these stars lead to the observed abundance anomalies. Quantitative spectral analyses of high-resolution spectra to derive photospheric isotopic helium abundance ratios for known 3He sdBs have not been performed yet. We present preliminary results of high-resolution and high S/N spectra to determine the 3He and 4He abundances of nine known 3He sdBs. We used a hybrid local/non-local thermodynamic equilibrium (LTE/NLTE approach for B-type stars investigating multiple He i lines, including λ4922 Å and λ6678 Å, which show the strongest isotopic shifts in the optical spectral range.We also report the discovery of four new 3He sdBs from the ESO Supernova Progenitor survey. Most of the 3He sdBs cluster in a narrow temperature strip between ∼ 26000 K and ∼ 30000 K and have almost no atmospheric 4He at all. Interestingly, three 3He sdBs show evidence for vertical helium stratification.

  15. Global gravitational anomalies

    International Nuclear Information System (INIS)

    Witten, E.

    1985-01-01

    A general formula for global gauge and gravitational anomalies is derived. It is used to show that the anomaly free supergravity and superstring theories in ten dimensions are all free of global anomalies that might have ruined their consistency. However, it is shown that global anomalies lead to some restrictions on allowed compactifications of these theories. For example, in the case of O(32) superstring theory, it is shown that a global anomaly related to π 7 (O(32)) leads to a Dirac-like quantization condition for the field strength of the antisymmetric tensor field. Related to global anomalies is the question of the number of fermion zero modes in an instanton field. It is argued that the relevant gravitational instantons are exotic spheres. It is shown that the number of fermion zero modes in an instanton field is always even in ten dimensional supergravity. (orig.)

  16. A geologic and geophysic study of the Sierra de Pena Blanca, in the state of Chihuahua, Mexico

    International Nuclear Information System (INIS)

    Lopez S, F.A.

    1976-01-01

    Within the sistematic aerial exploration program realized by the Instituto Nacional de Energia Nuclear, an aeroradiometric study was carried out in the zone which includes Sierra de Pena Blanca. This study took into consideration the former and present geological investigations and compromised the sierra together with the bordering valleys. The main objective consists in the localization of areas presenting favorable conditions for the existence of uranium isotopes minerlization, in order to determine a mineralized body or ore deposit. For that purpose the area was explored with an airplane to which a differential gamma rays spectrometer was adapted, this spectrometer will show us clearly the integration of the number of radiations which fall into the detectors obtaining this way a valuable information about the radiometric anomalous sites of the studied zone and also about the existence of bismuth, thallium and the abundant potassium of the igneous rocks. These anomalies are under the stage of ground verification, this stage includes a superficial study and the study of the underlying rocks through drilling, radiometric logs and chemical analysis of the samples. In fact, through this method we can obtain very truthful data. (author)

  17. Mass spectrometric investigation of the isotopes of ozone in the laboratory and the stratosphere

    International Nuclear Information System (INIS)

    Mauersberger, K.; Morton, J.; Schueler, B.

    1991-01-01

    During the last few years information on the isotope anomalies of ozone has substantially increased. Whenever ozone is formed in a gas phase reaction, an enhancement in its heavy isotopes is found of magnitude 12-14% ( 50 O 3 ) above the statistically expected values. The mass-independent enhancement decreases toward higher pressures and also shows a pronounced temperature dependence. Toward lower temperatures the enhancement becomes less. Studies of all possible ozone isotopes have shown that molecular symmetry plays a major role. Even large enhancements, above the laboratory results, have been occasionally measured in the stratosphere using a number of different experimental techniques. A correlation between very high heavy ozone enhancement (> 30%) and high solar activity may exist. The behavior of ozone isotopes will provide information about the ozone formation process

  18. Geologic evolution of the SE.23 Sheet - Belo Horizonte, MG, Brazil

    International Nuclear Information System (INIS)

    Pereira, A.D.C.; Fonseca, E.G. da; Braz, E.R.C.

    1987-01-01

    The aim of this paper is to present a synthesis of the geologic evolution in the Belo Horizonte Sheet comprising an area about 281.210 Km 2 . Rb-Sr and K-Ar isotope dating methods are used for age estimation of geologic deposits. The geologic evolution of the cratonic area is reflected by a stable central nucleus surrounded by marginal orogenic belts. In the central area were recognized greenstone belts structures involved by granite terrains and bordered by a granulitic region. The framework of the Sao Francisco Craton involves events of metamorphism, granitogenesis, sedimentary, volcanism and plutonism developed in the Early to Late Proterozoic. The stratigraphic column is complemented by Late Jurassic-Early Cretaceous continental deposits belonging to Parana-Basin. (M.V.M.)

  19. Kohn anomalies in superconductors

    International Nuclear Information System (INIS)

    Flatte, M.E.

    1994-01-01

    The detailed behavior of phonon dispersion curves near momenta which span the electronic Fermi sea in a superconductor is presented. An anomaly, similar to the metallic Kohn anomaly, exists in a superconductor's dispersion curves when the frequency of the photon spanning the Fermi sea exceeds twice the superconducting energy gap. This anomaly occurs at approximately the same momentum but is stronger than the normal-state Kohn anomaly. It also survives at finite temperature, unlike the metallic anomaly. Determination of Fermi-surface diameters from the location of these anomalies, therefore, may be more successful in the superconducting phase than in the normal state. However, the superconductor's anomaly fades rapidly with increased phonon frequency and becomes unobservable when the phonon frequency greatly exceeds the gap. This constraint makes these anomalies useful only in high-temperature superconductors such as La 1.85 Sr 0.15 CuO 4

  20. The Study of Geological Structures in Suli and Tulehu Geothermal Regions (Ambon, Indonesia Based on Gravity Gradient Tensor Data Simulation and Analytic Signal

    Directory of Open Access Journals (Sweden)

    Richard Lewerissa

    2017-12-01

    Full Text Available In early 2017, the geothermal system in the Suli and Tulehu areas of Ambon (Indonesia was investigated using a gravity gradient tensor and analytic signal. The gravity gradient tensor and analytic signal were obtained through forward modeling based on a rectangular prism. It was applied to complete Bouguer anomaly data over the study area by using Fast Fourier Transform (FFT. The analysis was conducted to enhance the geological structure like faults as a pathway of geothermal fluid circulation that is not visible on the surface because it is covered by sediment. The complete Bouguer anomaly ranges of 93 mGal up to 105 mGal decrease from the southwest in Suli to the northeast in Tulehu. A high gravity anomaly indicates a strong magmatic intrusion below the Suli region. The gravity anomalies decrease occurs in the Eriwakang mountain and most of Tulehu, and it is associated with a coral limestone. The lower gravity anomalies are located in the north to the northeast part of Tulehu are associated with alluvium. The residual anomaly shows that the drill well TLU-01 and geothermal manifestations along with the Banda, and Banda-Hatuasa faults are associated with lowest gravity anomaly (negative zone. The gravity gradient tensor simulation and an analytic signal of Suli and Tulehu give more detailed information about the geological features. The gzz component allows accurate description of the shape structures, especially the Banda fault associated with a zero value. This result will be useful as a geophysical constraint to subsurface modeling according to gravity gradient inversion over the area.

  1. Seasonal and ENSO Influences on the Stable Isotopic Composition of Galápagos Precipitation

    Science.gov (United States)

    Martin, N. J.; Conroy, J. L.; Noone, D.; Cobb, K. M.; Konecky, B. L.; Rea, S.

    2018-01-01

    The origin of stable isotopic variability in precipitation over time and space is critical to the interpretation of stable isotope-based paleoclimate proxies. In the eastern equatorial Pacific, modern stable isotope measurements in precipitation (δ18Op and δDp) are sparse and largely unevaluated in the literature, although insights from such analyses would benefit the interpretations of several regional isotope-based paleoclimate records. Here we present a new 3.5 year record of daily-resolved δ18Op and δDp from Santa Cruz, Galápagos. With a prior 13 year record of monthly δ18Op and δDp from the island, these new data reveal controls on the stable isotopic composition of regional precipitation on event to interannual time scales. Overall, we find Galápagos δ18Op is significantly correlated with precipitation amount on daily and monthly time scales. The majority of Galápagos rain events are drizzle, or garúa, derived from local marine boundary layer vapor, with corresponding high δ18Op values due to the local source and increased evaporation and equilibration of smaller drops with boundary layer vapor. On monthly time scales, only precipitation in very strong, warm season El Niño months has substantially lower δ18Op values, as the sea surface temperature threshold for deep convection (28°C) is only surpassed at these times. The 2015/2016 El Niño event did not produce strong precipitation or δ18Op anomalies due to the short period of warm SST anomalies, which did not extend into the peak of the warm season. Eastern Pacific proxy isotope records may be biased toward periods of high rainfall during strong to very strong El Niño events.

  2. Isotopic reconstruction of ancient human migrations: A comprehensive Sr isotope reference database for France and the first case study at Tumulus de Sables, south-western France

    Science.gov (United States)

    Willmes, M.; Boel, C.; Grün, R.; Armstrong, R.; Chancerel, A.; Maureille, B.; Courtaud, P.

    2012-04-01

    Strontium isotope ratios (87Sr/86Sr) can be used for the reconstruction of human and animal migrations across geologically different terrains. Sr isotope ratios in rocks are a product of age and composition and thus vary between geologic units. From the eroding environment Sr is transported into the soils, plants and rivers of a region. Humans and animals incorporate Sr from their diet into their bones and teeth, where it substitutes for calcium. Tooth enamel contains Sr isotope signatures acquired during childhood and is most resistant to weathering and overprinting, while the dentine is often diagenetically altered towards the local Sr signature. For the reconstruction of human and animal migrations the tooth enamel 87Sr/86Sr ratio is compared to the Sr isotope signature in the vicinity of the burial site and the surrounding area. This study focuses on the establishment of a comprehensive reference map of bioavailable 87Sr/86Sr ratios for France. In a next step we will compare human and animal teeth from key archaeological sites to this reference map to investigate mobility. So far, we have analysed plant and soil samples from ~200 locations across France including the Aquitaine basin, the western and northern parts of the Paris basin, as well as three transects through the Pyrenees Mountains. The isotope data, geologic background information (BRGM 1:1M), field images, and detailed method descriptions are available through our online database iRhum (http://rses.anu.edu.au/research/ee). This database can also be used in forensic studies and food sciences. As an archaeological case study teeth from 16 adult and 8 juvenile individuals were investigated from an early Bell Beaker (2500-2000 BC) site at Le Tumulus des Sables, south-west France (Gironde). The teeth were analysed for Sr isotope ratios using laser ablation ICP-MS. Four teeth were also analysed using solution ICP-MS, which showed a significant offset to the laser ablation results. This requires further

  3. Do Strontium Isotope Ratios of Animal Bone and Teeth Really Reflect the Isotope Ratios of its birth- and growth-places?

    Science.gov (United States)

    Minami, M.; Goto, A.; Suzuki, K.; Kato, T.; Watanabe, K.; Hasegawa, T.

    2007-12-01

    Strontium enters the human body through the food chain as nutrients pass from bedrock through soil and water to plants and animals. Strontium substitutes for calcium in the hydroxyapatite mineral of skeletal tissue, and is stored there. 87Sr/86Sr ratios in an individual's bone and teeth could directly reflect the isotopic ratios found in the plants and animals that she or he consumed, which reflect the isotope ratios found in the soil and bedrock of that geologic region. Therefore, 87Sr/86Sr ratios of human skeletons could be useful tools for assessing human residential mobility in prehistory, and many studies on them have been often made. In this study, to evaluate whether the 87Sr/86Sr ratio of a bone or teeth really reflects the isotopic ratios of its birth and growth places, several bone and teeth samples were measured for 87Sr/86Sr ratios, compared with 87Sr/86Sr ratios of geological samples in their growth-places. Bone and teeth samples were leached with 5% acetic acid. After drying, samples were ashed in a muffle furnace at 825°C for 8h, and then digested in nitric acid, followed by cation exchange chromatography with 2.4M hydrochloric acid. 87Sr/86Sr ratios were measured using a thermal ionization mass Spectrometer (VG Sector 54) or an inductively coupled plasma mass spectrometer (Finnigan ELEMENT2). A modern boar bone collected at Asuke, Toyota City, Aichi prefecture, Japan showed a 87Sr/86Sr of 0.71001±0.00002 (2 σ), while stream sediments in the Asuke area showed around 0.710 (Asahara et al., 2006). The 87Sr/86Sr ratio of a modern black bass bone collected from Lake Biwa, Shiga prefecture, Japan was 0.71215±0.00002, while those of surface water in Lake Biwa was 0.71233±0.00002. The similar 87Sr/86Sr ratios between bone and its provenance geology could indicate that the 87Sr/86Sr ratios of bones reflect the isotopic ratios of the birth- and growth-places. The more results of modern and fossil skeletons will be shown in our presentation.

  4. Application of benchtop micro-XRF to geological materials

    DEFF Research Database (Denmark)

    Flude, Stephanie; Haschke, Michael; Storey, Michael

    2017-01-01

    Recent developments in X-ray optics have allowed the development of a range of commercially available benchtop micro-XRF (μ-XRF) instruments that can produce X-ray spot sizes of 20–30 μm on the sample, allowing major- and trace-element analysis on a range of sample types and sizes with minimal......, by using a simple type-calibration against a reference material of similar matrix and composition. Qualitative analysis with micro-XRF can simplify and streamline sample characterization and processing for subsequent geochemical and isotopic analysis....... sample preparation. Such instruments offer quantitative analysis using fundamental parameter based 'standardless' quantification algorithms. The accuracy and precision of this quantitative analysis on geological materials, and application of micro-XRF to wider geological problems is assessed using...

  5. Stable isotope composition of cocoa beans of different geographical origin.

    Science.gov (United States)

    Perini, Matteo; Bontempo, Luana; Ziller, Luca; Barbero, Alice; Caligiani, Augusta; Camin, Federica

    2016-09-01

    The isotopic profile (δ(13) C, δ(15) N, δ(18) O, δ(2) H, δ(34) S) was used to characterise a wide selection of cocoa beans from different renowned production areas (Africa, Asia, Central and South America). The factors most influencing the isotopic signatures of cocoa beans were climate and altitude for δ(13) C and the isotopic composition of precipitation water for δ(18) O and δ(2) H, whereas δ(15) N and δ(34) S were primarily affected by geology and fertilisation practises. Multi-isotopic analysis was shown to be sufficiently effective in determining the geographical origin of cocoa beans, and combining it with Canonical Discriminant Analysis led to more than 80% of samples being correctly reclassified. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  6. Uranium, RADON and radon isotopes in selected brines of Poland

    International Nuclear Information System (INIS)

    Kozlowska, B.; Walencik, A.; Zipper, W.; Dorda, J.; Przylibski, T.A.

    2010-01-01

    Natural radioactive isotopes were studied in nine different types of brines from four locations in Poland. Investigated brines are exploited from various geological structures composed of the rocks of different chemical and mineral composition as well as different age and depth. All investigated brines are used in balneotherapy (i.e. baths, inhalations, showers). The main goal of this study was to obtain some basic knowledge on the activity range of natural elements such as uranium, RADON and radon in different brine types in Poland and their variability depending on their location in certain geological structures. Activities of 234,238 U, 226,228 Ra and 222 Rn isotopes were measured with the use of two nuclear spectrometry techniques: liquid scintillation and alpha spectrometry. The activity concentrations of 222 Rn vary from below 1 to 76.1±3.7 Bq/l, for the 226 Ra isotope from 0.19±0.01 to 85.5±0.4 Bq/l and for 228 Ra from below 0.03 to 2.17±0.09 Bq/l. For uranium isotopes, the concentrations are in the range from below 0.5 to 5.1±0.4 mBq/l for 238 U and from 1.6±0.4 to 45.6±2.0 mBq/l for 2 34U . The obtained results indicate high RADON activity concentrations corresponding to high mineralization of waters. (authors)

  7. Introduction to anomalies

    International Nuclear Information System (INIS)

    Alvarez-Gaume, L.

    1986-01-01

    These lectures are dedicated to the study of the recent progress and implications of anomalies in quantum field theory. In this introduction the author recapitulates some of the highlights in the history of the subject. The outline of these lectures is as follows: Section II contains a quick review of spinors in Euclidean and Minkowski space, some other group theory results relevant for the computation of anomalies in various dimensions, and an exposition of the index theorem. Section III starts the analysis of fermion determinants and chiral effective actions by deriving the non-Abelian anomaly from index theory. Using the results of Section II, the anomaly cancellation recently discovered by Green and Schwarz will be presented in Section IV as well as the connection of these results of Section III with the descent equations and the Wess-Zumino-Witten Lagrangians. Section V contains the generalization of anomalies to σ-models and some of its application in string theory. Section VI will deal with the anomalies from the Hamiltonian point of view. An exact formula for the imaginary part of the effective action for chiral fermions in the presence of arbitrary external gauge and gravitational fields will be derived in Section VII, and used in Section VIII for the study of global anomalies. 85 references

  8. Algebraic structure of chiral anomalies

    International Nuclear Information System (INIS)

    Stora, R.

    1985-09-01

    I will describe first the algebraic aspects of chiral anomalies, exercising however due care about the topological delicacies. I will illustrate the structure and methods in the context of gauge anomalies and will eventually make contact with results obtained from index theory. I will go into two sorts of generalizations: on the one hand, generalizing the algebraic set up yields e.g. gravitational and mixed gauge anomalies, supersymmetric gauge anomalies, anomalies in supergravity theories; on the other hand most constructions applied to the cohomologies which characterize anomalies easily extend to higher cohomologies. Section II is devoted to a description of the general set up as it applies to gauge anomalies. Section III deals with a number of algebraic set ups which characterize more general types of anomalies: gravitational and mixed gauge anomalies, supersymmetric gauge anomalies, anomalies in supergravity theories. It also includes brief remarks on σ models and a reminder on the full BRST algebra of quantized gauge theories

  9. Structural modeling of the Vichada impact structure from interpreted ground gravity and magnetic anomalies

    International Nuclear Information System (INIS)

    Hernandez, Orlando; Khurama, Sait; Alexander, Gretta C

    2011-01-01

    A prominent positive free-air gravity anomaly mapped over a roughly 50-km diameter basin is consistent with a mascon centered on (4 degrades 30 minutes N, 69 degrades 15 minutes W) in the Vichada Department, Colombia, South America. Ground follow up gravity and magnetic anomalies were modeled confirming the regional free air gravity anomalies. These potential field anomalies infer a hidden complex impact basin structure filled with tertiary sedimentary rocks and recent quaternary deposits. Negative Bouguer anomalies of 8 mgals to 15 mgals amplitude are associated with a concentric sedimentary basin with a varying thickness from 100 m to 500 m in the outer rings to 700 m to 1000 m at the center of the impact crater basin. Strong positive magnetic anomalies of 100 nt to 300 nt amplitude infer the presence of a local Precambrian crystalline basement that was affected by intensive faulting producing tectonic blocks dipping to the center of the structure, showing a typical domino structure of impact craters such as that of Sudbury, Ontario, Canada. Basic to intermediate mineralized veins and dikes with contrasting density and magnetic susceptibility properties could be emplaced along these faulting zones, as inferred from local gravity and magnetic highs. The geologic mapping of the area is limited by the flat topography and absence of outcrops/ geomorphologic units. Nevertheless, local normal faults along the inner ring together with radially sparse irregular blocks over flat terrains can be associated with terraced rims or collapse of the inner crater structure and eject blanket, respectively. A detailed airborne electromagnetic survey is recommended to confirm the gravity and magnetic anomalies together with a seismic program to evaluate the economic implications for energy and mineral exploration of the Vichada impact structure.

  10. Chiral anomalies and differential geometry

    International Nuclear Information System (INIS)

    Zumino, B.

    1983-10-01

    Some properties of chiral anomalies are described from a geometric point of view. Topics include chiral anomalies and differential forms, transformation properties of the anomalies, identification and use of the anomalies, and normalization of the anomalies. 22 references

  11. Behavior of rare earth elements in fractured aquifers: an application to geological disposal criteria for radioactive waste

    International Nuclear Information System (INIS)

    Lee, Seung Gu; Kim, Yong Je; Lee, Kil Yong; Kim, Kun Han

    2003-01-01

    An understanding of the geochemistry of potential host rocks is very important in the site evaluation for construction of an underground geologic repository for radioactive waste. Because of similar valence and ionic radii and high similarity in electronic structure with trivalent actinides (such as Am 3+ and Cm 3+ ), the rare earth elements (REEs) have been used to predict the behavior of actinide-series elements in solution (Runde et al., 1992). For Am and Cm, which occur only in the trivalent states in most waste-disposal repository environments, the analogy with the REEs is particularly relevant. In order to discuss the behavior of REEs in geological media and to deduce the behavior of actinides in geological environments based on the REE abundance, and to provide an useful tool in deciding an optimum geological condition for radioactive disposal, we estimated the REE abundance from various kinds of fractured rock type. In fractured granitic aquifer, chondrite-normalized REE pattern show Eu positive anomaly due to fracture-filling calcite precipitation. However, in fractured meta-basaltic and volcanic tuffaceous aquifer, REE pattern do not show the change of Eu anomaly due to fracture-filling calcite precipitation. Eu shows very similar properties such as cohesive energy, ionic radii with coordination number compared to Am. Therefore, if we consider the Eu behavior in fractured rocks and the similar physical/chemical properties of Eu and Am, together, our results strongly suggest that Eu is a very useful analogue for predicting the behavior of Am in geological environment

  12. ICP-MS applications for the analysis of geological materials and environmental samples

    International Nuclear Information System (INIS)

    Bendl, J.

    1997-01-01

    This work deals with applications of inductively coupled plasma - mass spectrometry applications for the analysis of geological materials and environmental samples. There are instrumentation, calibration, alternatives of sample introduction, interferences, trace elements analysis, rare earth elements and uranium and thorium, precious metals, isotopic analysis and environmental analysis discussed

  13. Clustering and Recurring Anomaly Identification: Recurring Anomaly Detection System (ReADS)

    Science.gov (United States)

    McIntosh, Dawn

    2006-01-01

    This viewgraph presentation reviews the Recurring Anomaly Detection System (ReADS). The Recurring Anomaly Detection System is a tool to analyze text reports, such as aviation reports and maintenance records: (1) Text clustering algorithms group large quantities of reports and documents; Reduces human error and fatigue (2) Identifies interconnected reports; Automates the discovery of possible recurring anomalies; (3) Provides a visualization of the clusters and recurring anomalies We have illustrated our techniques on data from Shuttle and ISS discrepancy reports, as well as ASRS data. ReADS has been integrated with a secure online search

  14. Tracheobronchial Branching Anomalies

    International Nuclear Information System (INIS)

    Hong, Min Ji; Kim, Young Tong; Jou, Sung Shick; Park, A Young

    2010-01-01

    There are various congenital anomalies with respect to the number, length, diameter, and location of tracheobronchial branching patterns. The tracheobronchial anomalies are classified into two groups. The first one, anomalies of division, includes tracheal bronchus, cardiac bronchus, tracheal diverticulum, pulmonary isomerism, and minor variations. The second one, dysmorphic lung, includes lung agenesis-hypoplasia complex and lobar agenesis-aplasia complex

  15. Tracheobronchial Branching Anomalies

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Min Ji; Kim, Young Tong; Jou, Sung Shick [Soonchunhyang University, Cheonan Hospital, Cheonan (Korea, Republic of); Park, A Young [Soonchunhyang University College of Medicine, Asan (Korea, Republic of)

    2010-04-15

    There are various congenital anomalies with respect to the number, length, diameter, and location of tracheobronchial branching patterns. The tracheobronchial anomalies are classified into two groups. The first one, anomalies of division, includes tracheal bronchus, cardiac bronchus, tracheal diverticulum, pulmonary isomerism, and minor variations. The second one, dysmorphic lung, includes lung agenesis-hypoplasia complex and lobar agenesis-aplasia complex

  16. Tin isotope fractionation during magmatic processes and the isotope composition of the bulk silicate Earth

    Science.gov (United States)

    Wang, Xueying; Amet, Quentin; Fitoussi, Caroline; Bourdon, Bernard

    2018-05-01

    Tin is a moderately volatile element whose isotope composition can be used to investigate Earth and planet differentiation and the early history of the Solar System. Although the Sn stable isotope composition of several geological and archaeological samples has been reported, there is currently scarce information about the effect of igneous processes on Sn isotopes. In this study, high-precision Sn isotope measurements of peridotites and basalts were obtained by MC-ICP-MS with a double-spike technique. The basalt samples display small variations in δ124/116Sn ranging from -0.01 ± 0.11 to 0.27 ± 0.11‰ (2 s.d.) relative to NIST SRM 3161a standard solution, while peridotites have more dispersed and more negative δ124Sn values ranging from -1.04 ± 0.11 to -0.07 ± 0.11‰ (2 s.d.). Overall, basalts are enriched in heavy Sn isotopes relative to peridotites. In addition, δ124Sn in peridotites become more negative with increasing degrees of melt depletion. These results can be explained by different partitioning behavior of Sn4+ and Sn2+ during partial melting. Sn4+ is overall more incompatible than Sn2+ during partial melting, resulting in Sn4+-rich silicate melt and Sn2+-rich residue. As Sn4+ has been shown experimentally to be enriched in heavy isotopes relative to Sn2+, the effect of melting is to enrich residual peridotites in relatively more compatible Sn2+, which results in isotopically lighter peridotites and isotopically heavier mantle-derived melts. This picture can be disturbed partly by the effect of refertilization. Similarly, the presence of enriched components such as recycled oceanic crust or sediments could explain part of the variations in Sn isotopes in oceanic basalts. The most primitive peridotite analyzed in this study was used for estimating the Sn isotope composition of the BSE, with δ124Sn = -0.08 ± 0.11‰ (2 s.d.) relative to the Sn NIST SRM 3161a standard solution. Altogether, this suggests that Sn isotopes may be a powerful probe of

  17. Branchial anomalies in children.

    Science.gov (United States)

    Bajaj, Y; Ifeacho, S; Tweedie, D; Jephson, C G; Albert, D M; Cochrane, L A; Wyatt, M E; Jonas, N; Hartley, B E J

    2011-08-01

    Branchial cleft anomalies are the second most common head and neck congenital lesions seen in children. Amongst the branchial cleft malformations, second cleft lesions account for 95% of the branchial anomalies. This article analyzes all the cases of branchial cleft anomalies operated on at Great Ormond Street Hospital over the past 10 years. All children who underwent surgery for branchial cleft sinus or fistula from January 2000 to December 2010 were included in this study. In this series, we had 80 patients (38 female and 42 male). The age at the time of operation varied from 1 year to 14 years. Amongst this group, 15 patients had first branchial cleft anomaly, 62 had second branchial cleft anomaly and 3 had fourth branchial pouch anomaly. All the first cleft cases were operated on by a superficial parotidectomy approach with facial nerve identification. Complete excision was achieved in all these first cleft cases. In this series of first cleft anomalies, we had one complication (temporary marginal mandibular nerve weakness. In the 62 children with second branchial cleft anomalies, 50 were unilateral and 12 were bilateral. In the vast majority, the tract extended through the carotid bifurcation and extended up to pharyngeal constrictor muscles. Majority of these cases were operated on through an elliptical incision around the external opening. Complete excision was achieved in all second cleft cases except one who required a repeat excision. In this subgroup, we had two complications one patient developed a seroma and one had incomplete excision. The three patients with fourth pouch anomaly were treated with endoscopic assisted monopolar diathermy to the sinus opening with good outcome. Branchial anomalies are relatively common in children. There are three distinct types, first cleft, second cleft and fourth pouch anomaly. Correct diagnosis is essential to avoid inadequate surgery and multiple procedures. The surgical approach needs to be tailored to the type

  18. Application of carbon and oxygen stable isotopes to the study of Brazilian precambrian

    International Nuclear Information System (INIS)

    Torquato, J.R.F.

    1980-01-01

    Samples of carbonated rocks of precambrian age are studied. The stable carbon and oxygen isotopes are applied to the study of terrestrial materials considering the variations of some element isotopic composition in function of the environment of sedimentation. The isotopic analysis was done using mass spectrometers. The analytical results and the description of region geology of the site of each sample are presented. The isotopic data are interpreted aiming to the environment of sedimentation. New techniques for better improvement of carbon and oxygen ratios, are proposed, such as: to use the analysis of surface trend and the isotopic logging in mapping of surface and subsurface. A new method for approximated determination of the ages of precambrian carbonated rocks, considering the limitations of their new technique, is also presented. (M.C.K.) [pt

  19. Geologic studies in Alaska by the U.S. Geological Survey, 1992

    Science.gov (United States)

    Dusel-Bacon, Cynthia; Till, Alison B.

    1993-01-01

    This collection of 19 papers continues the annual series of U.S. Geological Survey reports on the geology of Alaska. The contributions, which include full-length Articles and shorter Geologic Notes, cover a broad range of topics including dune formation, stratigraphy, paleontology, isotopic dating, mineral resources, and tectonics. Articles, grouped under four regional headings, span nearly the entire State from the North Slope to southwestern, south-central, and southeastern Alaska (fig. 1).In the section on northern Alaska, Galloway and Carter use new data on dune morphology and radiocarbon ages from the western Arctic Coastal Plain to develop a late Holocene chronology of multiple episodes of dune stabilization and reactivation for the region. Their study has important implications for climatic changes in northern Alaska during the past 4,000 years. In two papers, Dumoulin and her coauthors describe lithofacies and conodont faunas of Carboniferous strata in the western Brooks Range, discuss depositional environments, and propose possible correlations and source areas for some of the strata. Schenk and Bird propose a preliminary division of the Lower Cretaceous stratigraphic section in the central part of the North Slope into depositional sequences. Aleinikoff and others present new U-Pb data for zircons from metaigneous rocks from the central Brooks Range. Karl and Mull, reacting to a proposal regarding terrane nomenclature for northern Alaska that was published in last year's Alaskan Studies Bulletin, provide a historical perspective of the evolution of terminology for tectonic units in the Brooks Range and present their own recommendations.

  20. Evaluation of uranium geochemical anomalies in the Charlotte 10 x 20 NTMS quadrangle

    International Nuclear Information System (INIS)

    Carpenter, R.H.

    1981-11-01

    This report contains a synthesis of published geological, geophysical, and geochemical information for portions of Cabarrus and Rowan Counties, NC, where uranium geochemical anomalies have been described by Heffner and Ferguson (1978). The results of a ground radiation survey in selected areas are also described. Based on an evaluation of published information and the data obtained in the field study, conclusions are made regarding the possible occurrence of uranium concentration. Recommendations for detailed surveys in certain areas are also presented

  1. Stable isotope applications of AMS in geology

    International Nuclear Information System (INIS)

    Rucklidge, J.C.

    1981-01-01

    The subject of geochemistry has become increasingly concerned with the distribution of trace elements in and between mineral phases. Part per million detection is routine, but part per billion measurements are, for certain elements, beyond the range of such sensitive analytical methods as neutron activation analysis (NAA). Tandem AMS has the ability to extend this limit several orders of magnitude for those elements which readily form negative ions. There is no doubt that such information can be most valuable for elements which are partitioned strongly between different mineral phases. While bulk analyses may indicate trace levels of certain elements to be present in a rock, it has always been difficult to state with certainty whether the trace element occurs at a uniformly low level throughout the various phases, or whether it is concentrated at a high level in small grains of an extremely rare phase scattered through the rock. The milli- or micro-probe analytical capability, which can be part of AMS, enables such problems concerning ultra-low level element concentrations to be tackled. With the same approach isotopic ratios of both major and minor elements in microgram amounts of material may be undertaken

  2. Fractal Dimension Change Point Model for Hydrothermal Alteration Anomalies in Silk Road Economic Belt, the Beishan Area, Gansu, China

    Science.gov (United States)

    Han, H. H.; Wang, Y. L.; Ren, G. L.; LI, J. Q.; Gao, T.; Yang, M.; Yang, J. L.

    2016-11-01

    Remote sensing plays an important role in mineral exploration of “One Belt One Road” plan. One of its applications is extracting and locating hydrothermal alteration zones that are related to mines. At present, the extracting method for alteration anomalies from principal component image mainly relies on the data's normal distribution, without considering the nonlinear characteristics of geological anomaly. In this study, a Fractal Dimension Change Point Model (FDCPM), calculated by the self-similarity and mutability of alteration anomalies, is employed to quantitatively acquire the critical threshold of alteration anomalies. The realization theory and access mechanism of the model are elaborated by an experiment with ASTER data in Beishan mineralization belt, also the results are compared with traditional method (De-Interfered Anomalous Principal Component Thresholding Technique, DIAPCTT). The results show that the findings produced by FDCPM are agree with well with a mounting body of evidence from different perspectives, with the extracting accuracy over 80%, indicating that FDCPM is an effective extracting method for remote sensing alteration anomalies, and could be used as an useful tool for mineral exploration in similar areas in Silk Road Economic Belt.

  3. Preliminary report on the geology and metallogenesis of uranium in Bolivia

    International Nuclear Information System (INIS)

    Pardo-Leyton, E.; Barron, E.

    1984-01-01

    The paper is a preliminary study of aspects of the geology and metallogenesis of uranium in Bolivia. It must be considered as a first study which will serve as a basis for possible future work of this type. Its purpose is to show the possible relationships of the uranium anomalies and prospects to the country's various mineralized belts and also to the Nazca tectonic plate and to lineaments and intrusive bodies. (author)

  4. Detection of geothermal anomalies in Tengchong, Yunnan Province, China from MODIS multi-temporal night LST imagery

    Science.gov (United States)

    Li, H.; Kusky, T. M.; Peng, S.; Zhu, M.

    2012-12-01

    Thermal infrared (TIR) remote sensing is an important technique in the exploration of geothermal resources. In this study, a geothermal survey is conducted in Tengchong area of Yunnan province in China using multi-temporal MODIS LST (Land Surface Temperature). The monthly night MODIS LST data from Mar. 2000 to Mar. 2011 of the study area were collected and analyzed. The 132 month average LST map was derived and three geothermal anomalies were identified. The findings of this study agree well with the results from relative geothermal gradient measurements. Finally, we conclude that TIR remote sensing is a cost-effective technique to detect geothermal anomalies. Combining TIR remote sensing with geological analysis and the understanding of geothermal mechanism is an accurate and efficient approach to geothermal area detection.

  5. Preandean geological configuration of the eastern North Patagonian Massif, Argentina

    Directory of Open Access Journals (Sweden)

    Daniel A. Gregori

    2013-11-01

    Full Text Available The Preandean geological configuration of the eastern North Patagonian Massif is established through the use of geological and geophysical analysis. The positive gravity anomalies located near the Atlantic coast are due to 535 and 540 Ma old rocks belonging to the Pampean Orogeny (Precambrian–middle Cambrian, which are widely recognized in central and northern Argentina. The Famatinian Cycle (Ordovician–Devonian is represented by a Silurian–Devonian marine basin equivalent to those of eastern-central Argentina and South Africa, and which was deformed at the end of the Devonian by an ∼E–W to WNW–ESE compressional event, part of the Famatinian Orogeny. Containing strong gravity gradients, the NW–SE belt is coincident with fault zones which were originated during the Gondwanide Orogeny. This event also produced NW–SE overthrusting of the Silurian–Devonian sequences and strike-slip faults that displaced blocks in the same direction. This deformation event belongs to the Gondwanide Orogeny that includes movements related to a counterclockwise rotation of blocks in northern Patagonia. The strong negative anomalies located in the western part of the area stem from the presence of rocks of the Jurassic Cañadón Asfalto basin interbedded in the Marifil Complex. These volcaniclastic sequences show mild deformation of accommodation zones in a pre-Jurassic paleorelief.

  6. Near Surface CO2 Triple Oxygen Isotope Composition

    Directory of Open Access Journals (Sweden)

    Sasadhar Mahata

    2016-02-01

    Full Text Available The isotopic composition of carbon dioxide in the atmosphere is a powerful tool for constraining its sources and sinks. In particular, the 17O oxygen anomaly [Δ17O = 1000 × ln(1 + δ17O/1000 - 0.516 × 1000 × ln(1 + δ18O/1000], with a value > 0.5‰ produced in the middle atmosphere, provides an ideal tool for probing the exchange of carbon dioxide between the biosphere/hydrosphere and atmosphere. The biosphere/hydrosphere and anthropogenic emissions give values ≤ 0.3‰. Therefore, any anomaly in near surface CO2 would reflect the balance between stratospheric input and exchange with the aforementioned surface sources. We have analyzed Δ17O values of CO2 separated from air samples collected in Taipei, Taiwan, located in the western Pacific region. The obtained mean anomaly is 0.42 ± 0.14‰ (1-σ standard deviation, in good agreement with model prediction and a published decadal record. Apart from typically used δ13C and δ18O values, the Δ17O value could provide an additional tracer for constraining the carbon cycle.

  7. Geology and uranium occurrences in the Forez tertiary plain (in the French 'Massif Central'); Geologie et mineralisations uraniferes de la plaine tertiaire du Forez (Massif Central francais)

    Energy Technology Data Exchange (ETDEWEB)

    Duclos, P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses - 92 (France). Centre d' Etudes Nucleaires

    1967-01-01

    In the first part, the observations made during the geological survey of the Forez Tertiary plain (in the French 'Massif Central') are recalled. Then, using various methods, the author lists the formations according to chronology. Finally, a reconstitution of the geological history of this subsidence basin is attempted. In the second part, the occurrence of 17 uranium bearing geochemical anomalies is commented upon. Each of these various anomalies is given a place on the stratigraphic scale. This enables the author to put the successive phases of uranium deposition into their proper perspective in the history of the plain. In conclusion, the author points out the usefulness of these uraniferous geochemical anomalies. (author) [French] Dans la premiere partie, l'auteur rappelle les observations faites au cours de l'etude geologique de la plaine tertiaire du Forez (Massif Central francais). Puis se servant de differentes methodes, il etablit une chronologie des formations. Enfin, il termine par un essai de reconstitution de l'histoire geologique de ce bassin de subsidence. Dans la deuxieme partie, il commente la decouverte de 17 anomalies geochimiques uraniferes. Il situe ces differentes anomalies dans la serie stratigraphique. Ceci lui permet de replacer les depots successifs de l'uranium dans l'histoire de la plaine. Enfin, il indique l'interet de ces anomalies geochimiques uraniferes. (auteur)

  8. Technical Report on the Behavior of Trace Elements, Stable Isotopes, and Radiogenic Isotopes During the Processing of Uranium Ore to Uranium Ore Concentrate

    Energy Technology Data Exchange (ETDEWEB)

    Marks, N. E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Borg, L. E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Eppich, G. R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Gaffney, A. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Genneti, V. G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hutcheon, I. D. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Kristo, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Lindvall, R. E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Ramon, C. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Robel, M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Roberts, S. K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Schorzman, K. C. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Sharp, M. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Singleton, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Williams, R. W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-07-09

    The goals of this SP-1 effort were to understand how isotopic and elemental signatures behave during mining, milling, and concentration and to identify analytes that might preserve geologic signatures of the protolith ores. The impurities that are preserved through the concentration process could provide useful forensic signatures and perhaps prove diagnostic of sample origin.

  9. Isotope hydrology: Investigating groundwater contamination

    International Nuclear Information System (INIS)

    Dubinchuk, V.; Froehlich, K.; Gonfiantini, R.

    1989-01-01

    Groundwater quality has worsened in many regions, with sometimes serious consequences. Decontaminating groundwater is an extremely slow process, and sometimes impossible, because of the generally long residence time of the water in most geological formations. Major causes of contamination are poor groundwater management (often dictated by immediate social needs) and the lack of regulations and control over the use and disposal of contaminants. These types of problems have prompted an increasing demand for investigations directed at gaining insight into the behaviour of contaminants in the hydrological cycle. Major objectives are to prevent pollution and degradation of groundwater resources, or, if contamination already has occurred, to identify its origin so that remedies can be proposed. Environmental isotopes have proved to be a powerful tool for groundwater pollution studies. The IAEA has had a co-ordinated research programme since 1987 on the application of nuclear techniques to determine the transport of contaminants in groundwater. An isotope hydrology project is being launched within the framework of the IAEA's regional co-operative programme in Latin America (known as ARCAL). Main objectives are the application of environmental isotopes to problems of groundwater assessment and contamination in Latin America. In 1989, another co-ordinated research programme is planned under which isotopic and other tracers will be used for the validation of mathematical models in groundwater transport studies

  10. Isotopic variations in primitive meteorites

    International Nuclear Information System (INIS)

    Clayton, R.N.; Chicago Univ., IL; Chicago Univ., IL

    1981-01-01

    The presence of large internal 16 O variability in ordinary chondrites greatly extends the range of meteorite types in which this phenomenon has been observed. These results may lead to identification of major gas and dust reservoirs in the cloud from which the Solar System formed. The demonstration that live 107 Pd was present in the differentiated parent bodies of some iron meteorites supports the million year time scale between a major nucleosynthetic event and Solar System formation, as implied by the presence of live 26 Al in carbonaceous chondrites. However, the variability of radiogenic 26 Mg abundances in these meteorites makes it clear that the data cannot be interpreted simply in terms of time variations. Models of nucleosynthesis for elements from calcium to the iron peak should be aided by the new observations of abundances of titanium isotopes. Progress has been made in establishing the carrier phases of isotopically anomalous xenon and krypton. The apparent location of anomalous xenon and 14 N-rich nitrogen in identical carriers supports the notion that nucleosynthetic anomalies in nitrogen are also present in Allende. (author)

  11. SAS2H Generated Isotopic Concentrations For B and W 15X15 PWR Assembly

    International Nuclear Information System (INIS)

    J.W. Davis

    1996-01-01

    This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development Department (WPDD) to provide pressurized water reactor (PWR) isotopic composition data as a function of time for use in criticality analyses. The objectives of this evaluation are to generate burnup and decay dependant isotopic inventories and to provide these inventories in a form which can easily be utilized in subsequent criticality calculations

  12. Using a laser-based CO2 carbon isotope analyser to investigate gas transfer in geological media

    International Nuclear Information System (INIS)

    Guillon, S.; Pili, E.; Agrinier, P.

    2012-01-01

    CO 2 stable carbon isotopes are very attractive in environmental research to investigate both natural and anthropogenic carbon sources. Laser-based CO 2 carbon isotope analysis provides continuous measurement at high temporal resolution and is a promising alternative to isotope ratio mass spectrometry (IRMS). We performed a thorough assessment of a commercially available CO 2 Carbon Isotope Analyser (CCIA DLT-100, Los Gatos Research) that allows in situ measurement of C-13 in CO 2 . Using a set of reference gases of known CO 2 concentration and carbon isotopic composition, we evaluated the precision, long-term stability, temperature sensitivity and concentration dependence of the analyser. Despite good precision calculated from Allan variance (5.0 ppm for CO 2 concentration, and 0.05 per thousand for δC-13 at 60 s averaging), real performances are altered by two main sources of error: temperature sensitivity and dependence of C-13 on CO 2 concentration. Data processing is required to correct for these errors. Following application of these corrections, we achieve an accuracy of 8.7 ppm for CO 2 concentration and 1.3 per thousand for δC-13, which is worse compared to mass spectrometry performance, but still allowing field applications. With this portable analyser we measured CO 2 flux degassed from rock in an underground tunnel. The obtained carbon isotopic composition agrees with IRMS measurement, and can be used to identify the carbon source. (authors)

  13. Gravity Anomalies in the Northern Hawaiian Islands: Evidence for an Alternative Magma Chamber on Kauai and a Conjoined Niihau-Kauai Island

    Science.gov (United States)

    Flinders, A. F.; Ito, G.; Garcia, M.; Kim, S.; Appelgate, B.

    2008-12-01

    The shield stage evolution of the islands of Kauai and Niihau are poorly understood. Previous land-based gravity surveys provide only a coarse constraint on the observed gravitational field. Questions as to whether the island of Kauai was formed by a single or multiple shields and the developmental relationship between these neighboring islands are still debated. Our new land-based gravity survey of Kauai and ship-board gravity surveys around both islands identified large complete Bouguer gravitational anomalies under Kauai's Lihue Basin and offshore in the Kaulakahi Channel, a 30-km-long bathymetric ridge connecting the two islands. These gravitational highs are consistent in size and magnitude with those of other Hawaiian islands and imply local zones of high density crust, most likely attributed to magmatic intrusions; e.g. former magma chambers, or rift zones. The Lihue Basin anomaly observed is offset 20 km east from the geologically mapped caldera region. This offset implies either the unlikely case that the shield stage plumbing system connecting the magma chamber and caldera could have been inclined by up to 75 degrees from the vertical, or that the currently mapped caldera is a late feature, unrelated to shield volcanism. The location of the gravitational anomaly, in the Kaulakahi Channel, 20 km east of Niihau is consistent with geologic mapping, which indicates that Niihau is a remnant of an ancient shield volcano centered east of the island. The proximity of the Niihau gravitational anomaly 10 km from the western edge of Kauai supports the hypothesis that the two volcanoes were part of the same island.

  14. Hydrogen isotope fractionation in methane plasma

    Science.gov (United States)

    Robert, François; Derenne, Sylvie; Lombardi, Guillaume; Hassouni, Khaled; Michau, Armelle; Reinhardt, Peter; Duhamel, Rémi; Gonzalez, Adriana; Biron, Kasia

    2017-01-01

    The hydrogen isotope ratio (D/H) is commonly used to reconstruct the chemical processes at the origin of water and organic compounds in the early solar system. On the one hand, the large enrichments in deuterium of the insoluble organic matter (IOM) isolated from the carbonaceous meteorites are interpreted as a heritage of the interstellar medium or resulting from ion-molecule reactions taking place in the diffuse part of the protosolar nebula. On the other hand, the molecular structure of this IOM suggests that organic radicals have played a central role in a gas-phase organosynthesis. So as to reproduce this type of chemistry between organic radicals, experiments based on a microwave plasma of CH4 have been performed. They yielded a black organic residue in which ion microprobe analyses revealed hydrogen isotopic anomalies at a submicrometric spatial resolution. They likely reflect differences in the D/H ratios between the various CHx radicals whose polymerization is at the origin of the IOM. These isotopic heterogeneities, usually referred to as hot and cold spots, are commensurable with those observed in meteorite IOM. As a consequence, the appearance of organic radicals in the ionized regions of the disk surrounding the Sun during its formation may have triggered the formation of organic compounds.

  15. Geologic-geochemical characteristics of Guidong granitic massif and recognition of geo-tectonic environment at the time of its emplacement

    Energy Technology Data Exchange (ETDEWEB)

    Jianhong, Li; Shanyuan, Wei; Mingyue, Feng [Beijing Research Inst. of Uranium Geology, Beijing (China); Liang, Liang [East China Inst. of Technology, Fuzhou (China)

    2004-11-01

    Based on the study of geologic characteristics, such as mineralogic assemblage, structural and textural features of granite of Guidong granitic massif, and by using petrochemical, trace-element and isotopic data, and some petrochemical, trace-element and isotopic diagrams widely applied to the identification of geo-tectonic environments, authors recognize that Guidong granitic massif was emplaced in post-orogenic collision environment. (authors)

  16. A model for osmium isotopic evolution of metallic solids at the core-mantle boundary

    Science.gov (United States)

    Humayun, Munir

    2011-03-01

    Some plumes are thought to originate at the core-mantle boundary, but geochemical evidence of core-mantle interaction is limited to Os isotopes in samples from Hawaii, Gorgona (89 Ma), and Kostomuksha (2.7 Ga). The Os isotopes have been explained by physical entrainment of Earth's liquid outer core into mantle plumes. This model has come into conflict with geophysical estimates of the timing of core formation, high-pressure experimental determinations of the solid metal-liquid metal partition coefficients (D), and the absence of expected 182W anomalies. A new model is proposed where metallic liquid from the outer core is partially trapped in a compacting cumulate pile of Fe-rich nonmetallic precipitates (FeO, FeS, Fe3Si, etc.) at the top of the core and undergoes fractional crystallization precipitating solid metal grains, followed by expulsion of the residual metallic liquid back to the outer core. The Os isotopic composition of the solids and liquids in the cumulate pile is modeled as a function of the residual liquid remaining and the emplacement age using 1 bar D values, with variable amounts of oxygen (0-10 wt %) as the light element. The precipitated solids evolve Os isotope compositions that match the trends for Hawaii (at an emplacement age of 3.5-4.5 Ga; 5%-10% oxygen) and Gorgona (emplacement age < 1.5 Ga; 0%-5% oxygen). The Fe-rich matrix of the cumulate pile dilutes the precipitated solid metal decoupling the Fe/Mn ratio from Os and W isotopes. The advantages to using precipitated solid metal as the Os host include a lower platinum group element and Ni content to the mantle source region relative to excess iron, miniscule anomalies in 182W (<0.1 ɛ), and no effects for Pb isotopes, etc. A gradual thermomechanical erosion of the cumulate pile results in incorporation of this material into the base of the mantle, where mantle plumes subsequently entrain it. Fractional crystallization of metallic liquids within the CMB provides a consistent explanation of

  17. Isotope dilution analysis of environmental samples

    International Nuclear Information System (INIS)

    Tolgyessy, J.; Lesny, J.; Korenova, Z.; Klas, J.; Klehr, E.H.

    1986-01-01

    Isotope dilution analysis has been used for the determination of several trace elements - especially metals - in a variety of environmental samples, including aerosols, water, soils, biological materials and geological materials. Variations of the basic concept include classical IDA, substoichiometric IDA, and more recently, sub-superequivalence IDA. Each variation has its advantages and limitations. A periodic chart has been used to identify those elements which have been measured in environmental samples using one or more of these methods. (author)

  18. The velocity dependent dissolution of spent nuclear fuel in a geologic repository

    International Nuclear Information System (INIS)

    Nutt, W.M.

    1990-02-01

    A model describing the dissolution of fission products and transuranic isotopes from spent nuclear fuel into flowing ground water has been developed. This model is divided into two parts. The first part of the model calculates the temperature within a consolidated spent fuel waste form at a given time and ground water velocity. This model was used to investigate whether water flowing at rates representative of a geological repository located at Yucca Mountain, Nevada, will cool a wasteform consisting of consolidated spent nuclear fuel pins. Time and velocity dependent temperature profiles were generated. These profiles were input into the second model, which calculates the dissolution rate of waste isotopes from a spent fuel pin. Two dissolution limiting processes were modeled; the processes are dissolution limited by the solubility limit of an isotopes in the ground water, and dissolution limited by the diffusion of waste isotopes from the interior of a spent fuel pin to the surface where dissolution can occur

  19. Geology of the hills in the region of the City of Santiago de Chile: New isotopic constraints

    International Nuclear Information System (INIS)

    Vergara, M; Lopez-Escobar, I; Palma, J.L; Hickey-Vargas, R

    2001-01-01

    Geological, geochronological and geochemical data demonstrate that the area where the city of Santiago de Chile is established used to be a huge volcanic field. At present, it is possible to distinguish in the area at least three volcanic cycles, which are geographically superimposed and deeply eroded. The first is Oligocene in age, the second Lower to Middle Miocene and the third is Middle to Upper Miocene. The Oligocene cycle is represented by volcanic and volcanoclastic rocks of the Provincia-San Ramon-Abanico and Conchali belts, and welded tuffs of the San Cristobal and Renca hills. The Lower to Middle Miocene cycle consists of subvolcanic rocks, mostly of basaltic to basaltic-andesite composition, characterized by the presence of clino- and orthopyroxene. The Middle to Upper Miocene cycle is composed predominantly of amphibole-bearing subvolcanic rocks of dacitic composition. The latter are found at the Manquehue hill, which limits the northern part of the city, and the hills at the Rinconada de Conchali. In this communication, we present new Sr-, Nd- and Pb- isotope data obtained from two subvolcanic samples of basaltic composition collected from the San Cristobal hill and at the Santa Lucia hill (Lower to Middle Miocene) and one amphibole-bearing subvolcanic sample of dacitic composition from the Manquehue hill (Middle to Upper Miocene) (au)

  20. Experiences in the ICP-MS analysis of geological and environmental samples

    International Nuclear Information System (INIS)

    Kallio, E.

    1994-01-01

    Inductively coupled plasma mass spectrometry (ICP-MS) has been used at the Geological Survey of Finland since 1991. Applied to determination of trace and ultra trace elements in water, sediments, biological samples and rocks. The strength of the technique lies in the ability to determine isotope ratios, and elements that are difficult or expensive to determine by other techniques, e.g. platinum group elements (PGEs), rare earths elements (REEs) and toxic metals (As, Be, Cd, Hg, Pb, Tl, U). An important part of the analysis is the pretreatment of the samples before the measurement. This paper gives an overview of the methods used at the Geological Survey. (orig.). (5 refs.)

  1. Use of isotope ratios to assess sources of Pb and Zn dispersed in the environment during mining and ore processing within the Orlovka-Spokoinoe mining site (Russia)

    International Nuclear Information System (INIS)

    Dolgopolova, A.; Weiss, D.J.; Seltmann, R.; Kober, B.; Mason, T.F.D.; Coles, B.; Stanley, C.J.

    2006-01-01

    Element concentrations, element ratios and Pb and Zn isotope data are reported for different geologic samples (barren and ore-bearing granites and host rocks), technogenic products (ore concentrates and tailings) and biologic samples (lichens and birch leaves) from the Orlovka-Spokoinoe mining district, Eastern Transbaikalia, Russia, with the aim to trace the sources of Pb and Zn at a local level within the mining site. Lichens and birch leaves were used as receptors of contamination within the mining site. Pb/Zr and Zn/Zr values indicated Pb and Zn enrichment relative to host rocks. Zn isotope data of 15 geologic and 11 lichen samples showed different Zn isotopic signatures with the total range for the geologic suite of -0.4 per mille to +1.2 per mille and for lichens of +0.4 per mille to +1.4 per mille in δ 66 Zn relative to Lyon JMC Zn standard. The source of isotopically heavy Zn within the Orlovka-Spokoinoe mining site could be potentially associated with long-range atmospheric aerosols that also contributed Pb to the studied mining site. Our results demonstrated that Zn isotopes might be used as new tools for Zn source assessment

  2. Isostatic Model and Isostatic Gravity Anomalies of the Arabian Plate and Surroundings

    Science.gov (United States)

    Kaban, Mikhail K.; El Khrepy, Sami; Al-Arifi, Nassir

    2016-04-01

    The isostatic modeling represents one of the most useful "geological" reduction methods of the gravity field. With the isostatic correction, it is possible to remove a significant part of the effect of deep density heterogeneity, which dominates in the Bouguer gravity anomalies. Although there exist several isostatic compensation schemes, it is usually supposed that a choice of the model is not an important factor to first order, since the total weight of compensating masses remains the same. We compare two alternative models for the Arabian plate and surrounding area. The Airy model gives very significant regional isostatic anomalies, which cannot be explained by the upper crust structure or disturbances of the isostatic equilibrium. Also, the predicted "isostatic" Moho is very different from existing seismic observations. The second isostatic model includes the Moho, which is based on seismic determinations. Additional compensation is provided by density variations within the lithosphere (chiefly in the upper mantle). According to this model, the upper mantle under the Arabian Shield is less dense than under the Platform. In the Arabian platform, the maximum density coincides with the Rub' al Khali, one of the richest oil basin in the world. This finding agrees with previous studies, showing that such basins are often underlain by dense mantle, possibly related to an eclogite layer that has caused their subsidence. The mantle density variations might be also a result of variations of the lithosphere thickness. With the combined isostatic model, it is possible to minimize regional anomalies over the Arabian plate. The residual local anomalies correspond well to tectonic structure of the plate. Still very significant anomalies, showing isostatic disturbances of the lithosphere, are associated with the Zagros fold belt, the collision zone of the Arabian and Eurasian plates.

  3. Uranium Content in the Geological Samples of Different River Valleys in the Dauki fault Belt of Jaintiapur

    International Nuclear Information System (INIS)

    Chowdhury, Minhaz ul Islam; Ahmed Monir; Bhuiyan Abu Daiyan; Akon Eunus

    1996-01-01

    Thirty four geological samples that include six radioactive rock samples, four soil samples, two ooze samples,twelve stream-sediment samples and ten water samples, collected during a field survey in Jaintiapur area of the Dauki fault belt, oriented to the study on probable mobility of uranium either as detritus or in aquatic solution through the region, have been investigated with fluorimeter so as to find out content of uranium in the samples. The investigation aims at determining geochemical significance on uranium occurrence prevailing in the area. In general, the content of uranium in the rock samples lies in average distribution of geochemical interest. However, 194 ppm of uranium content in the gross material of the rock sample, collected from Lalakhal anomaly that records 1500 cps in situ, bears geochemical significance. But, the anomaly being associated with a cross -bedding, the presence of uranium may be inferred as an accumulation in placer sediment transported from a nearby source, Despite absence of in situ radiometric anomalies in the overall geological formations other than the Tipam and the Dupitila Sandstone members as encountered in the traverse of Sari valley , the area, in general, appears to be potential for possible occurrence of uranium. The transported stream sediments ooze and surface run-off water, as collected from the Rangapani, the Sari and even the Nayagang show geochemically significant distribution of uranium. Laboratory analyses of soil samples refers to dispersion of U bearing materials in the soil along the major channels.Uranium content in the surface run-off water of the Sari, the Rangapani and the Nayagang that have originated from the uranium bearing Meghalayan hills strongly support previous inference on mobility of uranium in aquatic solution through the geological formations of the area for possible formation of secondary uranium deposits. Eventually, prevailing geological evidences advocate that the area may be brought

  4. The U.S. Geological Survey's TRIGA® reactor

    Science.gov (United States)

    DeBey, Timothy M.; Roy, Brycen R.; Brady, Sally R.

    2012-01-01

    The U.S. Geological Survey (USGS) operates a low-enriched uranium-fueled, pool-type reactor located at the Federal Center in Denver, Colorado. The mission of the Geological Survey TRIGA® Reactor (GSTR) is to support USGS science by providing information on geologic, plant, and animal specimens to advance methods and techniques unique to nuclear reactors. The reactor facility is supported by programs across the USGS and is organizationally under the Associate Director for Energy and Minerals, and Environmental Health. The GSTR is the only facility in the United States capable of performing automated delayed neutron analyses for detecting fissile and fissionable isotopes. Samples from around the world are submitted to the USGS for analysis using the reactor facility. Qualitative and quantitative elemental analyses, spatial elemental analyses, and geochronology are performed. Few research reactor facilities in the United States are equipped to handle the large number of samples processed at the GSTR. Historically, more than 450,000 sample irradiations have been performed at the USGS facility. Providing impartial scientific information to resource managers, planners, and other interested parties throughout the world is an integral part of the research effort of the USGS.

  5. Intercontinental correlation of organic carbon and carbonate stable isotope records: evidence of climate and sea-evel change during the Turonian (Cretaceous)

    Czech Academy of Sciences Publication Activity Database

    Jarvis, I.; Trabucho-Alexandre, J.; Gröcke, D. R.; Uličný, David; Laurin, Jiří

    2015-01-01

    Roč. 1, č. 2 (2015), s. 53-90 ISSN 2055-4877 R&D Projects: GA ČR GAP210/10/1991; GA MŠk LH12041 Institutional support: RVO:67985530 Keywords : carbon isotopes * chemostratigraphy * climate change * Cretaceous * oxygen isotopes Subject RIV: DB - Geology ; Mineralogy

  6. Insights from stable S and O isotopes into biogeochemical processes and genesis of Lower Cambrian barite–pyrite concretions of South China

    Digital Repository Service at National Institute of Oceanography (India)

    Goldberg, T.; Mazumdar, A.; Strauss, H.; Shields, G.

    water trace metal chemistry of laminated sediments from the Gulf of California, Mexico. Marine Chemistry 14, 89-106. Canfield, D.E., 2001. Biogeochemistry of sulphur isotopes. In: Valley, J.W. & Cole, D.R. (Eds.), Stable Isotope Geochemistry. Reviews.... Age curves of sulphur and oxygen isotopes in marine sulphate and their mutual interpretation. Chemical Geology 28, 199-206. Coleman, M.L. & Raiswell, R., 1981. Carbon, oxygen and sulphur isotope variations in concretions from the Upper Lias of N...

  7. Isotopic composition of steam samples from Lanzarote, Canary Islands

    Energy Technology Data Exchange (ETDEWEB)

    Arana, V. (CSIC, Madrid); Panichi, C.

    1974-12-01

    The isotopic analysis of the steam samples collected in the geothermal area of Lanzarote show that the values of delta D are practically constant, and those of delta /sup 18/O range in a shift of 17 /sup 0///sub 00/ reaching a maximum of +14.7 /sup 0///sub 00/ versus SMOW, this last value being the highest found in steam samples. This composition can be explained as a consequence of the isotopic exchange at high temperature between limestones and a mixture of marine and local meteoric waters. This interpretation agrees with previous geological and geophysical studies which consider that a promising geothermal field could exist in Lanzarote. (auth)

  8. PSO (Particle Swarm Optimization) for Interpretation of Magnetic Anomalies Caused by Simple Geometrical Structures

    Science.gov (United States)

    Essa, Khalid S.; Elhussein, Mahmoud

    2018-04-01

    A new efficient approach to estimate parameters that controlled the source dimensions from magnetic anomaly profile data in light of PSO algorithm (particle swarm optimization) has been presented. The PSO algorithm has been connected in interpreting the magnetic anomaly profiles data onto a new formula for isolated sources embedded in the subsurface. The model parameters deciphered here are the depth of the body, the amplitude coefficient, the angle of effective magnetization, the shape factor and the horizontal coordinates of the source. The model parameters evaluated by the present technique, generally the depth of the covered structures were observed to be in astounding concurrence with the real parameters. The root mean square (RMS) error is considered as a criterion in estimating the misfit between the observed and computed anomalies. Inversion of noise-free synthetic data, noisy synthetic data which contains different levels of random noise (5, 10, 15 and 20%) as well as multiple structures and in additional two real-field data from USA and Egypt exhibits the viability of the approach. Thus, the final results of the different parameters are matched with those given in the published literature and from geologic results.

  9. High resolution Slovak Bouguer gravity anomaly map and its enhanced derivative transformations: new possibilities for interpretation of anomalous gravity fields

    Science.gov (United States)

    Pašteka, Roman; Zahorec, Pavol; Kušnirák, David; Bošanský, Marián; Papčo, Juraj; Szalaiová, Viktória; Krajňák, Martin; Ivan, Marušiak; Mikuška, Ján; Bielik, Miroslav

    2017-06-01

    The paper deals with the revision and enrichment of the present gravimetric database of the Slovak Republic. The output of this process is a new version of the complete Bouguer anomaly (CBA) field on our territory. Thanks to the taking into account of more accurate terrain corrections, this field has significantly higher quality and higher resolution capabilities. The excellent features of this map will allow us to re-evaluate and improve the qualitative interpretation of the gravity field when researching the structural and tectonic geology of the Western Carpathian lithosphere. In the contribution we also analyse the field of the new CBA based on the properties of various transformed fields - in particular the horizontal gradient, which by its local maximums defines important density boundaries in the lateral direction. All original and new transformed maps make a significant contribution to improving the geological interpretation of the CBA field. Except for the horizontal gradient field, we are also interested in a new special transformation of TDXAS, which excellently separates various detected anomalies of gravity field and improves their lateral delimitation.

  10. Geological Mapping of Sabah, Malaysia, Using Airborne Gravity Survey

    DEFF Research Database (Denmark)

    Fauzi Nordin, Ahmad; Jamil, Hassan; Noor Isa, Mohd

    2016-01-01

    Airborne gravimetry is an effective tool for mapping local gravity fields using a combination of airborne sensors, aircraft and positioning systems. It is suitable for gravity surveys over difficult terrains and areas mixed with land and ocean. This paper describes the geological mapping of Sabah...... using airborne gravity surveys. Airborne gravity data over land areas of Sabah has been combined with the marine airborne gravity data to provide a seamless land-to-sea gravity field coverage in order to produce the geological mapping. Free-air and Bouguer anomaly maps (density 2.67 g/cm3) have been...... derived from the airborne data both as simple ad-hoc plots (at aircraft altitude), and as final plots from the downward continued airborne data, processed as part of the geoids determination. Data are gridded at 0.025 degree spacing which is about 2.7 km and the data resolution of the filtered airborne...

  11. Free-air and Bouguer gravity anomalies and the Martian crustal dichotomy

    Science.gov (United States)

    Frey, Herbert; Bills, Bruce G.; Kiefer, Walter S.; Nerem, R. Steven; Roark, James H.; Zuber, Maria T.

    1993-01-01

    Free-air and Bouguer gravity anomalies from a 50x50 field, derived from re-analysis of Viking Orbiter and Mariner 9 tracking data and using a 50x50 expansion of the current Mars topography and the GSFC degree 50 geoid as the equipotential reference surface, with the Martian crustal dichotomy are compared. The spherical harmonic topography used has zero mean elevation, and differs from the USGS maps by about 2 km. In this field the dichotomy boundary in eastern Mars lies mostly at -1 to -2 km elevation. Bouguer gravity anomalies are shown on a map of Noachian, Hesperian, and Amazonian age terrains, simplified from current geologic maps. The map is centered at 300 deg W to show the continuity of the dichotomy boundary. Contour interval is 100 mgals. Gravity and topography were compared along approximately 40 profiles oriented parallel to the dichotomy boundary topographic gradient, to determine how the geophysical character of the boundary changes along its length and what this implies for its origin and development.

  12. UTEX modeling of xenon signature sensitivity to geology and explosion cavity characteristics following an underground nuclear explosion

    Science.gov (United States)

    Lowrey, J. D.; Haas, D.

    2013-12-01

    Underground nuclear explosions (UNEs) produce anthropogenic isotopes that can potentially be used in the verification component of the Comprehensive Nuclear-Test-Ban Treaty. Several isotopes of radioactive xenon gas have been identified as radionuclides of interest within the International Monitoring System (IMS) and in an On-Site Inspection (OSI). Substantial research has been previously undertaken to characterize the geologic and atmospheric mechanisms that can drive the movement of radionuclide gas from a well-contained UNE, considering both sensitivities on gas arrival time and signature variability of xenon due to the nature of subsurface transport. This work further considers sensitivities of radioxenon gas arrival time and signatures to large variability in geologic stratification and generalized explosion cavity characteristics, as well as compares this influence to variability in the shallow surface.

  13. New Isotope Analysis Method: Atom Trap Mass Spectrometry

    International Nuclear Information System (INIS)

    Ko, Kwang Hoon; Park, Hyun Min; Han, Jae Min; Kim, Taek Soo; Cha, Yong Ho; Lim, Gwon; Jeong, Do Young

    2011-01-01

    Trace isotope analysis has been an important role in science, archaeological dating, geology, biology and nuclear industry. Some fission products such as Sr-90, Cs-135 and Kr-85 can be released to the environment when nuclear accident occurs and the reprocessing factory operates. Thus, the analysis of artificially produced radioactive isotopes has been of interest in nuclear industry. But it is difficult to detect them due to low natural abundance less then 10 -10 . In general, radio-chemical method has been applied to detect ultra-trace radio isotopes. But this method has disadvantages of long measurement time for long lived radioisotopes and toxic chemical process for the purification. The Accelerator Mass Spectrometer has high isotope selectivity, but the system is huge and its selectivity is affected by isobars. The laser based method, such as RIMS (Resonance Ionization Mass Spectrometry) has the advantage of isobar-effect free characteristics. But the system size is still huge for high isotope selective system. Recently, ATTA (Atom Trap Trace Analysis) has been successfully applied to detect ultra-trace isotope, Kr-81 and Kr-85. ATTA is the isobar-effect free detection with high isotope selectivity and the system size is small. However, it requires steady atomic beam source during detection, and is not allowed simultaneous detection of several isotopes. In this presentation, we introduce new isotope detection method which is a coupled method of Atom Trap Mass Spectrometry (ATMS). We expect that it can overcome the disadvantage of ATTA while it has both advantages of ATTA and mass spectrometer. The basic concept and the system design will be presented. In addition, the experimental status of ATMS will also be presented

  14. Investigation of remote sensing geology in the northern Anxi area of Gansu Province

    International Nuclear Information System (INIS)

    Dai Wenhan

    1993-07-01

    The study of 1 : 50,000 remote sensing geology survey and prognosis of gold (uranium) mineralization in the area of northern Anxi of Gansu province has been completed. The synthetical remote sensing and multi-source information compounding technologies, such as land-satellites TM and MSS images, airborne color infrared photography and infrared ray scanning digital images, are used in the study. On the basis of information enhancement and extraction of remote-sensing images, using the theory of remote sensing to explore mineral deposits and the field investigations, many achievements have been reached, such as applications of synthetical remote sensing technology, fundamental study of geology, prognosis of gold (uranium) minerals and 1 : 50,000 remote-geologic mapping. 21 mineral resource maps and geologic maps are obtained. Nearly one thousand of altered rock zones are interpreted and found. 71 new gold anomaly hydrothermal alteration zones and 23 gold mineralized places are discovered (maximum Au 71 x 10 -6 ). 17 minerogeneration prospective areas, 67 gold-ore searching targets and favorable areas of uranium mineralization are identified. It gives important materials for searching new mines

  15. Ancient bronze coins from Mediterranean basin: LAMQS potentiality for lead isotopes comparative analysis with former mineral

    Energy Technology Data Exchange (ETDEWEB)

    Torrisi, L., E-mail: Lorenzo.Torrisi@unime.it [Department of Physics Science - MIFT, Messina University, V.le F.S. d’Alcontres 31, 98166 S. Agata, Messina (Italy); Italiano, A. [INFN, Sezione di Catania, Gruppo collegato di Messina (Italy); Torrisi, A. [Institute of Optoelectronics, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw (Poland)

    2016-11-30

    Highlights: • Surface and bulk compositional elements in ancient bronze coins were investigated using XRF analysis. • Lead stable isotope {sup 204}Pb, {sup 206}Pb, {sup 207}Pb and {sup 208}Pb were measured in ancient coins with LAMQS analysis. • Lead ratios {sup 208}Pb/{sup 206}Pb and {sup 207}Pb/{sup 206}Pb, measured by LAMQS, were compared with Brettscaife.net geological database relative to the minerals in different mines of Mediterranean basin. • Bronze coins were correlated to possible ancient mining sites of minerals from which lead was extracted. - Abstract: Bronze coins coming from the area of the Mediterranean basin, dated back the II–X Cent. A.D., were analyzed using different physical analytical techniques. Characteristic X-ray fluorescence was used with electrons and photons, in order to investigate the elemental composition of both the surface layers and bulk. Moreover, the quadrupole mass spectrometry coupled to laser ablation (LAMQS technique) in high vacuum was used to analyse typical material compounds from surface contamination. Mass spectrometry, at high resolution and sensitivity, extended up to 300 amu, allowed measuring the {sup 208}Pb/{sup 206}Pb and {sup 207}Pb/{sup 206}Pb isotopic ratios into the coins. Quantitative relative analyses of these isotopic ratios identify the coin composition such as a “fingerprint” depending on the mineral used to extract the lead. Isotopic ratios in coins can be compared to those of the possible minerals used to produce the bronze alloy. A comparison between the measured isotope ratios in the analyzed coins and the literature database, related to the mineral containing Pb as a function of its geological and geophysical extraction mine, is presented. The analysis, restricted to old coins and the mines of the Mediterranean basin, indicates a possible correlation between the coin compositions and the possible geological sites of the extracted mineral.

  16. Determination of δ13C, δ15N, or δ34S by isotope-ratio-monitoring mass spectrometry using an elemental analyzer

    Science.gov (United States)

    Johnson, Craig A.; Stricker, Craig A.; Gulbransen, Cayce A.; Emmons, Matthew P.

    2018-02-14

    This report describes procedures used in the Geology, Geophysics, and Geochemistry Science Center of the U.S. Geological Survey in Denver, Colorado, to determine the stable-isotope ratios 13C/12C, 15N/14N, and 34S/32S in solid materials. The procedures use elemental analyzers connected directly to gas-source isotope-ratio mass spectrometers. A different elemental–analyzer–mass-spectrometer system is used for 13C/12C and 15N/14N than is used for 34S/32S to accommodate differences in reagents, catalysts, and instrument settings.

  17. Reduction of hexavalent chromium by ferrous iron: A process of chromium isotope fractionation and its relevance to natural environments

    DEFF Research Database (Denmark)

    Døssing, Lasse Nørbye; Dideriksen, Knud; Stipp, Susan Louise Svane

    2011-01-01

    Stable chromium (Cr) isotopes can be used as a tracer for changing redox conditions in modern marine systems and in the geological record. We have investigated isotope fractionation during reduction of Cr(VI)aq by Fe(II)aq. Reduction of Cr(VI)aq by Fe(II)aq in batch experiments leads to significant...

  18. A novel methodology to investigate isotopic biosignatures

    Science.gov (United States)

    Horner, T. J.; Lee, R. B. Y.; Henderson, G. M.; Rickaby, R. E. M.

    2012-04-01

    An enduring goal of trace metal isotopic studies of Earth History is to find isotopic 'fingerprints' of life or of life's individual physiochemical processes. Generally, such signatures are sought by relating an isotopic effect observed in controlled laboratory conditions or a well-characterized environment to a more complex system or the geological record. However, such an approach is ultimately limited because life exerts numerous isotopic fractionations on any one element so it is hard to dissect the resultant net fractionation into its individual components. Further, different organisms, often with the same apparent cellular function, can express different isotopic fractionation factors. We have used a novel method to investigate the isotopic fractionation associated with a single physiological process-enzyme specific isotopic fractionation. We selected Cd isotopes since only one biological use of Cd is known, CdCA (a Cd/Zn carbonic anhydrase from the coastal diatom T. Weissflogii). Thus, our investigation can also inform the long standing mystery as to why this generally toxic element appears to have a nutrient-like dissolved isotopic and concentration profile in the oceans. We used the pET-15b plasmid to insert the CdCA gene into the E. coli genome. There is no known biochemical function for Cd in E. coli, making it an ideal vector for studying distinct physiological processes within a single organism. The uptake of Cd and associated isotopic fractionation was determined for both normal cells and those expressing CdCA. It was found that whole cells always exhibited a preference for the light isotopes of Cd, regardless of the expression of CdCA; adsorption of Cd to cell surfaces was not seen to cause isotopic fractionation. However, the cleaning procedure employed exerted a strong control on the observed isotopic composition of cells. Using existing protein purification techniques, we measured the Cd isotopic composition of different subcellular fractions of E

  19. Geology and uranium occurrences in the Forez tertiary plain (in the French 'Massif Central'); Geologie et mineralisations uraniferes de la plaine tertiaire du Forez (Massif Central francais)

    Energy Technology Data Exchange (ETDEWEB)

    Duclos, P. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses - 92 (France). Centre d' Etudes Nucleaires

    1967-01-01

    In the first part, the observations made during the geological survey of the Forez Tertiary plain (in the French 'Massif Central') are recalled. Then, using various methods, the author lists the formations according to chronology. Finally, a reconstitution of the geological history of this subsidence basin is attempted. In the second part, the occurrence of 17 uranium bearing geochemical anomalies is commented upon. Each of these various anomalies is given a place on the stratigraphic scale. This enables the author to put the successive phases of uranium deposition into their proper perspective in the history of the plain. In conclusion, the author points out the usefulness of these uraniferous geochemical anomalies. (author) [French] Dans la premiere partie, l'auteur rappelle les observations faites au cours de l'etude geologique de la plaine tertiaire du Forez (Massif Central francais). Puis se servant de differentes methodes, il etablit une chronologie des formations. Enfin, il termine par un essai de reconstitution de l'histoire geologique de ce bassin de subsidence. Dans la deuxieme partie, il commente la decouverte de 17 anomalies geochimiques uraniferes. Il situe ces differentes anomalies dans la serie stratigraphique. Ceci lui permet de replacer les depots successifs de l'uranium dans l'histoire de la plaine. Enfin, il indique l'interet de ces anomalies geochimiques uraniferes. (auteur)

  20. Consequences of the proposed near equality of neutron and proton radii in the calcium isotopes

    International Nuclear Information System (INIS)

    Zamick, L.

    1976-01-01

    If the difference in neutron and proton radii in the Calcium Isotopes is much less than has up to now been calculated, one does have a mechanism for solving the Nolen-Schiffer anomaly; but then one runs into difficulty with other quantities such as the renormalized effective interaction between identical nucleons. (B.G.)

  1. New zircon U-Pb LA-ICP-MS ages and Hf isotope data from the Central Pontides (Turkey): Geological and geodynamic constraints

    Science.gov (United States)

    Çimen, Okay; Göncüoğlu, M. Cemal; Simonetti, Antonio; Sayit, Kaan

    2018-05-01

    The Central Pontides in northern Anatolia is located on the accretionary complex formed by the closure of Neotethyan Intra-Pontide Ocean between the southern Eurasian margin (Istanbul-Zonguldak Terrane) and the Cimmerian Sakarya Composite Terrane. Among other components of the oceanic lithosphere, it comprises not yet well-dated felsic igneous rocks formed in arc-basin as well as continent margin settings. In-situ U-Pb age results for zircons from the arc-basin system (öangaldağ Metamorphic Complex) and the continental arc (Devrekani Metadiorite and Granitoid) yield ages of 176 ± 6 Ma, 163 ± 9 Ma and 165 ± 3 Ma, respectively. Corresponding in-situ average (initial) 176Hf/177Hf initial ratios are 0.28261 ± 0.00003, 0.28267 ± 0.00002 and 0.28290 ± 0.00004 for these units and indicative of a subduction-modified mantle source. The new U-Pb ages and Hf isotope data from these oceanic and continental arc units together with regional geological constraints support the presence of a multiple subduction system within the Intra-Pontide Ocean during the Middle Jurassic.

  2. Stable isotope deltas: Tiny, yet robust signatures in nature

    Science.gov (United States)

    Brand, Willi A.; Coplen, Tyler B.

    2012-01-01

    Although most of them are relatively small, stable isotope deltas of naturally occurring substances are robust and enable workers in anthropology, atmospheric sciences, biology, chemistry, environmental sciences, food and drug authentication, forensic science, geochemistry, geology, oceanography, and paleoclimatology to study a variety of topics. Two fundamental processes explain the stable isotope deltas measured in most terrestrial systems: isotopic fractionation and isotope mixing. Isotopic fractionation is the result of equilibrium or kinetic physicochemical processes that fractionate isotopes because of small differences in physical or chemical properties of molecular species having different isotopes. It is shown that the mixing of radioactive and stable isotope end members can be modelled to provide information on many natural processes, including 14C abundances in the modern atmosphere and the stable hydrogen and oxygen isotopic compositions of the oceans during glacial and interglacial times. The calculation of mixing fractions using isotope balance equations with isotope deltas can be substantially in error when substances with high concentrations of heavy isotopes (e.g. 13C, 2H, and 18O ) are mixed. In such cases, calculations using mole fractions are preferred as they produce accurate mixing fractions. Isotope deltas are dimensionless quantities. In the International System of Units (SI), these quantities have the unit 1 and the usual list of prefixes is not applicable. To overcome traditional limitations with expressing orders of magnitude differences in isotope deltas, we propose the term urey (symbol Ur), after Harold C. Urey, for the unit 1. In such a manner, an isotope delta value expressed traditionally as−25 per mil can be written as−25 mUr (or−2.5 cUr or−0.25 dUr; the use of any SI prefix is possible). Likewise, very small isotopic differences often expressed in per meg ‘units’ are easily included (e.g. either+0.015 ‰ or+15 per meg

  3. Chemical and isotopic characteristics of the warm and cold waters of the Luigiane Spa near Guardia Piemontese (Calabria, Italy) in a complex faulted geological framework

    International Nuclear Information System (INIS)

    Vespasiano, Giovanni; Apollaro, Carmine; Muto, Francesco; Dotsika, Elissavet; De Rosa, Rosanna; Marini, Luigi

    2014-01-01

    Highlights: • Geo-structural and hydrogeological patterns: thermal waters discharge in a tectonic window. • Use of S isotopes to discriminate different evaporite sources, considering effects of BSR. • Use of the local approach instead of the regional approach to investigate the thermal site. • Use of geothermometric functions specifically calibrated for the thermal waters of interest. • Synthesis of geo-structural, hydrogeological and geochemical results in a conceptual model. - Abstract: Waters discharging at the Luigiane Spa come from two different hydrogeological circuits, which are chiefly hosted in the carbonate rocks and Upper Triassic evaporites of two distinct geological units, known as Verbicaro Unit and Cetraro Unit. The first unit contains a cold and relatively shallow aquifer behaving as a sort of piston-flow circuit with high flow rate, whereas the second unit encloses a warm and comparatively deep aquifer acting as a sort of well-mixed reservoir, where the circulation is slower and the rate is lower. Meteoric waters infiltrating along the Coastal Chain at similar elevations (615–670 m asl on average, in spite of considerable uncertainties) recharge both aquifers and, in the first case, acquire heat from rocks through conductive transfer as a consequence of deepening along a fault system and/or crossing between different systems, as suggested by local structural geology. In particular, the warm deeper reservoir has a temperature of ∼60 °C, as indicated by the chalcedony solubility and the Ca–Mg and SO 4 –F geothermometers, which were specifically calibrated for the peculiar water–rock-interaction (WRI) processes originating the Na–Cl–SO 4 high-salinity warm waters that discharge at the Luigiane Spa. The warm deeper reservoir is probably located at depths close to 1.4 km, assuming a geothermal gradient of 33 °C km −1 . The water leaving the deep reservoir discharges at the surface at 40.9 ± 3.3 °C after a relatively fast

  4. Analysis of genitourinary anomalies in patients with VACTERL (Vertebral anomalies, Anal atresia, Cardiac malformations, Tracheo-Esophageal fistula, Renal anomalies, Limb abnormalities) association.

    Science.gov (United States)

    Solomon, Benjamin D; Raam, Manu S; Pineda-Alvarez, Daniel E

    2011-06-01

    The goal of this study was to describe a novel pattern of genitourinary (GU) anomalies in VACTERL association,which involves congenital anomalies affecting the vertebrae,anus, heart, trachea and esophagus, kidneys, and limbs.We collected clinical data on 105 patients diagnosed with VACTERL association and analyzed a subset of 89 patients who met more stringent inclusion criteria. Twenty-one percent of patients have GU anomalies, which are more severe (but not more frequent) in females. Anomalies were noted in patients without malformations affecting the renal, lower vertebral, or lower gastrointestinal systems. There should be a high index of suspicion for the presence of GU anomalies even in patients who do not have spatially similar malformations.

  5. Radiologic analysis of congenital limb anomalies

    International Nuclear Information System (INIS)

    Chung, Hong Jun; Kim, Ok Hwa; Shinn, Kyung Sub; Kim, Nam Ae

    1994-01-01

    Congenital limb anomalies are manifested in various degree of severity and complexity bearing conclusion for description and nomenclature of each anomaly. We retrospectively analyzed the roentgenograms of congenital limb anomalies for the purpose of further understanding of the radiologic manifestations based on the embryonal defect and also to find the incidence of each anomaly. Total number of the patients was 89 with 137 anomalies. Recently the uniform system of classification for congenital anomalies of the upper limb was adopted by International Federation of Societies for Surgery of the Hand (IFSSH), which were categorized as 7 classifications. We used the IFSSH classification with some modification as 5 classifications; failure of formation of parts, failure of differentiation of parts, duplications, overgrowth and undergrowth. The patients with upper limb anomalies were 65 out of 89(73%), lower limb were 21(24%), and both upper and lower limb anomalies were 3(4%). Failure of formation was seen in 18%, failure of differentiation 39%, duplications 39%, overgrowth 8%, and undergrowth in 12%. Thirty-five patients had more than one anomaly, and 14 patients had intergroup anomalies. The upper limb anomalies were more common than lower limb. Among the anomalies, failure of differentiation and duplications were the most common types of congenital limb anomalies. Patients with failure of formation, failure of differentiation, and undergrowth had intergroup association of anomalies, but duplication and overgrowth tended to be isolated anomalies

  6. Dental Anomalies: An Update

    Directory of Open Access Journals (Sweden)

    Fatemeh Jahanimoghadam

    2016-01-01

    Full Text Available Dental anomalies are usual congenital malformation that can happen either as isolated findings or as a part of a syndrome. Developmental anomalies influencing the morphology exists in both deciduous and permanent dentition and shows different forms such as gemination, fusion, concrescence, dilaceration, dens evaginatus (DE, enamel pearls, taurodontism or peg-shaped laterals. All These anomalies have clinical significance concerning aesthetics, malocclusion and more necessary preparing of the development of dental decays and oral diseases. Through a search in PubMed, Google, Scopus and Medline, a total of eighty original research papers during 1928-2016 were found with the keywords such as dental anomaly, syndrome, tooth and hypodontia. One hundred review titles were identified, eighty reviews were retrieved that were finally included as being relevant and of sufficient quality. In this review, dental anomalies including gemination, fusion, concrescence, dilaceration, dens invaginatus, DE, taurodontism, enamel pearls, fluorosis, peg-shaped laterals, dentinal dysplasia, regional odontodysplasia and hypodontia are discussed. Diagnosing dental abnormality needs a thorough evaluation of the patient, involving a medical, dental, familial and clinical history. Clinical examination and radiographic evaluation and in some of the cases, specific laboratory tests are also needed. Developmental dental anomalies require careful examination and treatment planning. Where one anomaly is present, clinicians should suspect that other anomalies may also be present. Moreover, careful clinical and radiographical examination is required. Furthermore, more complex cases need multidisciplinary planning and treatment.

  7. Mass independent isotope effects and their observations in nature

    International Nuclear Information System (INIS)

    Thiemens, M.H.

    2002-01-01

    In 1983, Thiemens and Heidenreich reported the first chemically produced mass independent isotope effect. A significant feature of the fractionation was that it identically produced the isotopic relation observed in the calcium-aluminum inclusions in the Allende meteorite. This δ 17 O=δ 18 O composition had previously been thought to represent a nucleosynthetic component as no chemical process was capable of producing a mass independent isotopic composition. It now appears nearly certain that the meteoritic oxygen isotopic anomalies were produced by chemical, rather than nuclear, processes. Since oxygen is the major element in stony planets this represents a major event in the formation of the solar system. In a recent review (Thiemens, 1999), it has been shown that mass independent isotopic compositions are pervasive in the Earth's atmosphere. Molecules which have been demonstrated to possess mass independent isotopic compositions include: O 2 , O 3 , CO 2 , CO, and N 2 O. In each case, the specific nature of the mass independent isotopic composition has provided details of their atmospheric chemistry that could not have been obtained by any other measurement technique. Most recently, solid materials have been observed to possess mass independent isotopic composition. In this paper, these observations are briefly discussed. These solid reservoirs include: 1) carbonates and sulphates from Mars, 2) terrestrial aerosol sulphate, 3) sulphides and sulphates from the Earth, ranging in time from 3.8 to 2.2 billion years before present, 4) sulphates from the Namibian desert and 5) the Antartic Dry Valleys. The information obtained from these measurements is extraordinarily wide ranging, extending from understanding the history of Martian atmosphereregolith interaction to the evolution of the oxygen in the Earth's earliest atmosphere. As was the case for gas phase species, this information and insight could not have been obtained by any other measurement technique

  8. Crustal Poisson’s ratio anomalies in the eastern part of North China and their origins

    Directory of Open Access Journals (Sweden)

    Wencai Yang

    2011-07-01

    Full Text Available Seismic tomography can provide both fine P-wave and S-wave velocity structures of the crust and upper mantle. In addition, with proper computation, Poisson’s ratio images from the seismic velocities can be determined. However, it is unknown whether Poisson’s ratio images have any advantages when compared with the P-wave and S-wave velocity images. For the purposes of this study, high-resolution seismic tomography under the eastern part of North China region was used to determine detailed 3-D crustal P- and S-wave seismic velocities structure, as well as Poisson’s ratio images. Results of Poisson’s ratio imaging show high Poisson’s ratio (high-PR anomalies located in the Hengshan-North Taihang-Zhangjiakou (H-NT-Z region, demonstrating that Poisson’s ratio imaging can provide new geophysical constraints for regional tectonic evolution. The H-NT-Z region shows a prominent and continuous high-PR anomaly in the upper crust. Based on Poisson’s ratio images at different depths, we find that this high-PR anomaly is extending down to the middle crust with thickness up to about 26 km. According to rock physical property measurements and other geological data, this crustal Poisson’s ratio anomaly can be explained by Mesozoic partial melting of the upper mantle and basaltic magma underplating related to the lithospheric thinning of the North China craton.

  9. Gravity and magnetic anomalies of the Cyprus arc and tectonic implications

    Science.gov (United States)

    Ergün, M.; Okay, S.; Sari, C.; Oral, E. Z.

    2003-04-01

    In present day, eastern Mediterranean is controlled by the collision of the African and Eurasian plates and displacements of Arabian, Anatolian and Aegean micro-plates. The boundary between African and Eurasian plates is delineated by the Hellenic arc and Pliny-Strabo trench in the west and the Cyprus arc and a diffuse fault system of the Eastern Anatolian Fault zone in the east. The available gravity and magnetic data from the easternmost Mediterranean allow to subdivide this basin into three provinces: the northeastern Mediterranean north of the Cyprus Arc; the Levant Basin south of the Cyprus Arc and east of the line that roughly continues the Suez rift trend toward the Gulf of Antalya, between Cyprus and Anaximander Mountains; and the Mediterranean Ridge, Herodotus Basin west of this line. High anomalies observed in Cyprus and the sea region at the south is prominent in the gravity data. The Bouguer gravity anomaly reaches its maximum values over Cyprus, where it is most probably caused by high dense Troodos ophiolites. The uplifted oceanic crust causes high Bouguer anomaly also seen in the vicinity of Eratosthenes Seamount. Another result obtained from gravity data is that the crust under Herodotos and Rhodes basins is somehow oceanic and Anaximander, Eratosthenes and Cyprus are continental fragments. There are no linear magnetic anomalies in the Mediterranean. But there are magnetic anomalies over the Eratosthenes seamount and as well as from Cyprus to the Antalya basin due to the ophiolitic bodies. In Cyprus, the last compressional deformations were defined near the Miocene/Pliocene boundary. The extensional deformation associated with the Antalya basin appears to be separated by a zone of the Florence rise and Anaximander Mountains affected by differential tectonic movements. Eratosthenes Seamount is a positive crustal feature in the process of collision with Cyprus along an active margin; there is clearly a potential tectonic relationship to the onland

  10. Platinum stable isotopes in ferromanganese crust and nodules

    Science.gov (United States)

    Corcoran, Loretta; Seward, Terry; Handler, Monica R.

    2015-04-01

    Hydrogenetic ferromanganese (Fe-Mn) crust and nodules are slow-growing chemical sediments that form by direct precipitation from seawater, resulting in a record of changing seawater chemistry. These sediments are the primary sink for platinum in the modern oxic marine environment, hosting well-documented enrichments over other platinum-group elements (PGEs): the Pt anomaly [1]. Platinum is a non-bio-essential, highly siderophile, transition metal with six stable isotopes (190Pt, 192Pt, 194Pt, 195Pt, 196Pt, and 198Pt) with several oxidation states (Pt0, Pt2+ and Pt4+). Platinum is generally considered to exist in the hydrosphere as Pt2+ although its behaviour in the marine environment is poorly constrained, and Pt4+may also be present. Variations in ocean redox state, together with changes in source fluxes to the oceans, may therefore lead to small variations (Leaching experiments conducted on platinum rich terrestrial materials underwent platinum stable isotopic measurement as an analogue for the Pt isotopic fractionation associated with continental weathering. [1] Hodge, V.F. et al. (1985) Earth and Planetary Science Letters, 72, 158-162. [2] Creech, J. et al. (2013) Journal of Analytical Atomic Spectrometry, 28. 853-865.

  11. World Gravity Map: a set of global complete spherical Bouguer and isostatic anomaly maps and grids

    Science.gov (United States)

    Bonvalot, S.; Balmino, G.; Briais, A.; Kuhn, M.; Peyrefitte, A.; Vales, N.; Biancale, R.; Gabalda, G.; Reinquin, F.

    2012-04-01

    We present here a set of digital maps of the Earth's gravity anomalies (surface free air, Bouguer and isostatic), computed at Bureau Gravimetric International (BGI) as a contribution to the Global Geodetic Observing Systems (GGOS) and to the global geophysical maps published by the Commission for the Geological Map of the World (CGMW) with support of UNESCO and other institutions. The Bouguer anomaly concept is extensively used in geophysical interpretation to investigate the density distributions in the Earth's interior. Complete Bouguer anomalies (including terrain effects) are usually computed at regional scales by integrating the gravity attraction of topography elements over and beyond a given area (under planar or spherical approximations). Here, we developed and applied a worldwide spherical approach aimed to provide a set of homogeneous and high resolution gravity anomaly maps and grids computed at the Earth's surface, taking into account a realistic Earth model and reconciling geophysical and geodetic definitions of gravity anomalies. This first version (1.0) has been computed by spherical harmonics analysis / synthesis of the Earth's topography-bathymetry up to degree 10800. The detailed theory of the spherical harmonics approach is given in Balmino et al., (Journal of Geodesy, 2011). The Bouguer and terrain corrections have thus been computed in spherical geometry at 1'x1' resolution using the ETOPO1 topography/bathymetry, ice surface and bedrock models from the NOAA (National Oceanic and Atmospheric Administration) and taking into account precise characteristics (boundaries and densities) of major lakes, inner seas, polar caps and of land areas below sea level. Isostatic corrections have been computed according to the Airy-Heiskanen model in spherical geometry for a constant depth of compensation of 30km. The gravity information given here is provided by the Earth Geopotential Model (EGM2008), developed at degree 2160 by the National Geospatial

  12. Isotope characterization of shallow aquifers in the Horombe region, South of Madagascar

    International Nuclear Information System (INIS)

    Fareze, L.P.; Rajaobelison, J.; Ramaroson, V.; Raoelina Andriambololona; Andriamiarintsoa, G.; Razafitsalama, P.R.; Rahobisoa, J.J.; Randrianarison, H.; Ranaivoarisoa, A.; Marah, H.

    2011-01-01

    The present study deals with the problem of evaluation of the recharge mechanism and the characterization of the groundwater flow system in the basement shallow aquifer, which is one of the groundwater resource in the semi-arid South region of Madagascar. Stable isotopes (deuterium and oxygen-18) and tritium are used to achieve with accuracy the hydrogeological and geochemical dynamics study. Chemical analysis is used to provide complementary information to the investigation. A space distribution of tritium concentration and isotopic composition in groundwater shows evidence of two opposite categories of aquifers, which is confirmed by the chemical analysis results and by the geological features of the study site. Some groundwater flow path directions have been identified in the study area thanks to the tritium concentration space distribution and the geological formation. Besides, the groundwater recharge of the shallow aquifers in the South of Madagascar has been characterized by the exponential mixing model.

  13. The Holographic Weyl anomaly

    CERN Document Server

    Henningson, M; Henningson, Mans; Skenderis, Kostas

    1998-01-01

    We calculate the Weyl anomaly for conformal field theories that can be described via the adS/CFT correspondence. This entails regularizing the gravitational part of the corresponding supergravity action in a manner consistent with general covariance. Up to a constant, the anomaly only depends on the dimension d of the manifold on which the conformal field theory is defined. We present concrete expressions for the anomaly in the physically relevant cases d = 2, 4 and 6. In d = 2 we find for the central charge c = 3 l/ 2 G_N in agreement with considerations based on the asymptotic symmetry algebra of adS_3. In d = 4 the anomaly agrees precisely with that of the corresponding N = 4 superconformal SU(N) gauge theory. The result in d = 6 provides new information for the (0, 2) theory, since its Weyl anomaly has not been computed previously. The anomaly in this case grows as N^3, where N is the number of coincident M5 branes, and it vanishes for a Ricci-flat background.

  14. MAGSAT anomaly map and continental drift

    Science.gov (United States)

    Lemouel, J. L. (Principal Investigator); Galdeano, A.; Ducruix, J.

    1981-01-01

    Anomaly maps of high quality are needed to display unambiguously the so called long wave length anomalies. The anomalies were analyzed in terms of continental drift and the nature of their sources is discussed. The map presented confirms the thinness of the oceanic magnetized layer. Continental magnetic anomalies are characterized by elongated structures generally of east-west trend. Paleomagnetic reconstruction shows that the anomalies found in India, Australia, and Antarctic exhibit a fair consistency with the African anomalies. It is also shown that anomalies are locked under the continents and have a fixed geometry.

  15. Advances in the knowledge of the mining geological anomaly uraniferous Medano Rico, Disc. Jachal, San Juan Province

    International Nuclear Information System (INIS)

    Matar, M.; Arroqui, A.; Wetten, A.; Banchig, P.; Iglesias, R.

    2010-01-01

    Preliminary results of research carried out in the area of ​​Medano Rico, Dto Jachal San Juan Province, under the project Implementation of a model for exploration of uranium in Pre cordillera describes this work. The research tasks are intended to deepen the knowledge of the area to establish a genetic model of uranium anomaly

  16. SAS2H Generated Isotopic Concentrations For B&W 15X15 PWR Assembly (SCPB:N/A)

    Energy Technology Data Exchange (ETDEWEB)

    J.W. Davis

    1996-08-29

    This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development Department (WPDD) to provide pressurized water reactor (PWR) isotopic composition data as a function of time for use in criticality analyses. The objectives of this evaluation are to generate burnup and decay dependant isotopic inventories and to provide these inventories in a form which can easily be utilized in subsequent criticality calculations.

  17. In Situ Carbon Isotope Analysis by Laser Ablation MC-ICP-MS.

    Science.gov (United States)

    Chen, Wei; Lu, Jue; Jiang, Shao-Yong; Zhao, Kui-Dong; Duan, Deng-Fei

    2017-12-19

    Carbon isotopes have been widely used in tracing a wide variety of geological and environmental processes. The carbon isotope composition of bulk rocks and minerals was conventionally analyzed by isotope ratio mass spectrometry (IRMS), and, more recently, secondary ionization mass spectrometry (SIMS) has been widely used to determine carbon isotope composition of carbon-bearing solid materials with good spatial resolution. Here, we present a new method that couples a RESOlution S155 193 nm laser ablation system with a Nu Plasma II MC-ICP-MS, with the aim of measuring carbon isotopes in situ in carbonate minerals (i.e., calcite and aragonite). Under routine operating conditions for δ 13 C analysis, instrumental bias generally drifts by 0.8‰-2.0‰ in a typical analytical session of 2-3 h. Using a magmatic calcite as the standard, the carbon isotopic composition was determined for a suite of calcite samples with δ 13 C values in the range of -6.94‰ to 1.48‰. The obtained δ 13 C data are comparable to IRMS values. The combined standard uncertainty for magmatic calcite is ICP-MS can serve as an appropriate method to analyze carbon isotopes of carbonate minerals in situ.

  18. Laboratory calibration of the calcium carbonate clumped isotope thermometer in the 25-250 °C temperature range

    Science.gov (United States)

    Kluge, Tobias; John, Cédric M.; Jourdan, Anne-Lise; Davis, Simon; Crawshaw, John

    2015-05-01

    Many fields of Earth sciences benefit from the knowledge of mineral formation temperatures. For example, carbonates are extensively used for reconstruction of the Earth's past climatic variations by determining ocean, lake, and soil paleotemperatures. Furthermore, diagenetic minerals and their formation or alteration temperature may provide information about the burial history of important geological units and can have practical applications, for instance, for reconstructing the geochemical and thermal histories of hydrocarbon reservoirs. Carbonate clumped isotope thermometry is a relatively new technique that can provide the formation temperature of carbonate minerals without requiring a priori knowledge of the isotopic composition of the initial solution. It is based on the temperature-dependent abundance of the rare 13C-18O bonds in carbonate minerals, specified as a Δ47 value. The clumped isotope thermometer has been calibrated experimentally from 1 °C to 70 °C. However, higher temperatures that are relevant to geological processes have so far not been directly calibrated in the laboratory. In order to close this calibration gap and to provide a robust basis for the application of clumped isotopes to high-temperature geological processes we precipitated CaCO3 (mainly calcite) in the laboratory between 23 and 250 °C. We used two different precipitation techniques: first, minerals were precipitated from a CaCO3 supersaturated solution at atmospheric pressure (23-91 °C), and, second, from a solution resulting from the mixing of CaCl2 and NaHCO3 in a pressurized reaction vessel at a pressure of up to 80 bar (25-250 °C).

  19. Geochemical analysis of core from a geothermal anomaly

    International Nuclear Information System (INIS)

    Haverslew, B.; Tammemagi, H.Y.

    1985-04-01

    A mild geothermal area in western Montana, USA, has been studied, as a natural analog, to learn about the effects that long-term heat generated by a repository containing spent nuclear fuel might have on the surrounding rock mass. The results of previous geological, geophysical and hydrogeological studies are briefly summarized. Extensive petrological studies have been undertaken on core samples obtained from a 2 km deep borehole drilled into the Empire Creek Stock. These include a detailed petrographic study, x-ray diffraction analyses, scanning electron microscope and electron microprobe analyses, porosity and permeability measurements, oxygen isotope analyses, uranium disequilibrium analyses and K-Ar age determinations. The implications to deep burial of nuclear wastes are discussed. 40 refs

  20. High-resolution residual geoid and gravity anomaly data of the northern Indian Ocean - An input to geological understanding

    Digital Repository Service at National Institute of Oceanography (India)

    Sreejith, K.M.; Rajesh, S.; Majumdar, T.J.; Rao, G.S.; Radhakrishna, M.; Krishna, K.S.; Rajawat, A.S.

    ') geoid anomaly map of the northern Indian Ocean generated from the altimeter data obtained from Geodetic Missions of GEOSAT and ERS-1 along with ERS-2, TOPEX/POSIDEON and JASON satellites is presented. The geoid map of the Indian Ocean is dominated by a...

  1. The Swiss national network for isotopes in the hydrological cycle

    International Nuclear Information System (INIS)

    Schotterer, U.

    1998-01-01

    The network is based on the long-term stations of the Climate and Environmental Physics Group and includes 11 precipitation, 6 river and 3 ground water stations. For the isotope measurements the Universities of Bern (Climate and Environmental Physics Group, tritium and oxygen-18) and Lausanne (Institute for Mineralogy and Petrography, deuterium) are contracted on a year to year basis. Sampling instructions, collection and shipment of samples are within the responsibility of the Bern group. The sampling apart from monthly composites of precipitation includes also samples from surface and ground water. The isotope data are available by contacting the Swiss Hydrological and Geological Survey directly

  2. Global aspects of gauge anomalies

    International Nuclear Information System (INIS)

    Zhang, H.

    1988-01-01

    This dissertation discusses the global aspects of gauge anomalies in even dimensions. After a very brief description of local gauge anomalies, the possible global gauge anomalies for various gauge theories are discussed using homotopy theory. One of the main results obtained in a general formula for the SU(n - k) global gauge anomaly coefficient in arbitrary 2n dimensions. The result is expressed in terms of the James number of the Stiefel manifold SU(n + 1)/SU(n - k) and the generalized Dynkin indices. From this, the possibilities of SU(n), SU(n - 1), and SU(2) global gauge anomalies in arbitrary 2n dimensions have been determined. We have also determined the possibilities of global gauge anomalies for the gauge groups SP(2N) and SO(N) in certain general dimensions, as well as for the exceptional gauge groups in specific dimensions. Moreover, several general propositions are formulated and proved which are very useful in the study of global gauge anomalies

  3. Isotopic and Chemical Evidence for Primitive Aqueous Alteration in the Tagish Lake Meteorite

    Science.gov (United States)

    Sakuma, Keisuke; Hidaka, Hiroshi; Yoneda, Shigekazu

    2018-01-01

    Aqueous alteration is one of the primitive activities that occurred on meteorite parent bodies in the early solar system. The Tagish Lake meteorite is known to show an intense parent body aqueous alteration signature. In this study, quantitative analyses of the alkaline elements and isotopic analyses of Sr and Ba from acid leachates of TL (C2-ungrouped) were performed to investigate effects of aqueous alteration. The main purpose of this study is to search for isotopic evidence of extinct 135Cs from the Ba isotopic analyses in the chemical separates from the Tagish Lake meteorite. Barium isotopic data from the leachates show variable 135Ba isotopic anomalies (ε = ‑2.6 ∼ +3.6) which correlatewith 137Ba and 138Ba suggesting a heterogeneous distribution of s- and r-rich nucleosynthetic components in the early solar system. The 87Rb–87Sr and 135Cs–135Ba decay systems on TL in this study do not provide any chronological information. The disturbance of the TL chronometers is likely a reflection of the selective dissolution of Cs and Rb given the relatively higher mobility of Cs and Rb compared to Ba and Sr, respectively, during fluid mineral interactions.

  4. Essentials of iron, chromium, and calcium isotope analysis of natural materials by thermal ionization mass spectrometry

    Science.gov (United States)

    Fantle, M.S.; Bullen, T.D.

    2009-01-01

    The use of isotopes to understand the behavior of metals in geological, hydrological, and biological systems has rapidly expanded in recent years. One of the mass spectrometric techniques used to analyze metal isotopes is thermal ionization mass spectrometry, or TIMS. While TIMS has been a useful analytical technique for the measurement of isotopic composition for decades and TIMS instruments are widely distributed, there are significant difficulties associated with using TIMS to analyze isotopes of the lighter alkaline earth elements and transition metals. Overcoming these difficulties to produce relatively long-lived and stable ion beams from microgram-sized samples is a non-trivial task. We focus here on TIMS analysis of three geologically and environmentally important elements (Fe, Cr, and Ca) and present an in-depth look at several key aspects that we feel have the greatest potential to trouble new users. Our discussion includes accessible descriptions of different analytical approaches and issues, including filament loading procedures, collector cup configurations, peak shapes and interferences, and the use of isotopic double spikes and related error estimation. Building on previous work, we present quantitative simulations, applied specifically in this study to Fe and Ca, that explore the effects of (1) time-variable evaporation of isotopically homogeneous spots from a filament and (2) interferences on the isotope ratios derived from a double spike subtraction routine. We discuss how and to what extent interferences at spike masses, as well as at other measured masses, affect the double spike-subtracted isotope ratio of interest (44Ca/40Ca in the case presented, though a similar analysis can be used to evaluate 56Fe/54Fe and 53Cr/52Cr). The conclusions of these simulations are neither intuitive nor immediately obvious, making this examination useful for those who are developing new methodologies. While all simulations are carried out in the context of a

  5. Lidar-enhanced geologic mapping, examples from the Medford and Hood River areas, Oregon

    Science.gov (United States)

    Wiley, T. J.; McClaughry, J. D.

    2012-12-01

    Lidar-based 3-foot digital elevation models (DEMs) and derivatives (slopeshade, hillshade, contours) were used to help map geology across 1700 km2 (650 mi2) near Hood River and Medford, Oregon. Techniques classically applied to interpret coarse DEMs and small-scale topographic maps were adapted to take advantage of lidar's high resolution. Penetration and discrimination of plant cover by the laser system allowed recognition of fine patterns and textures related to underlying geologic units and associated soils. Surficial geologic maps were improved by the ability to examine tiny variations in elevation and slope. Recognition of low-relief features of all sizes was enhanced where pixel elevation ranges of centimeters to meters, established by knowledge of the site or by trial, were displayed using thousands of sequential colors. Features can also be depicted relative to stream level by preparing a DEM that compensates for gradient. Near Medford, lidar-derived contour maps with 1- to 3-foot intervals revealed incised bajada with young, distal lobes defined by concentric contour lines. Bedrock geologic maps were improved by recognizing geologic features associated with surface textures and patterns or topographic anomalies. In sedimentary and volcanic terrain, structure was revealed by outcrops or horizons lying at one stratigraphic level. Creating a triangulated irregular network (TIN) facet from positions of three or more such points gives strike and dip. Each map area benefited from hundreds of these measurements. A more extensive DEM in the plane of the TIN facet can be subtracted from surface elevation (lidar DEM) to make a DEM with elevation zero where the stratigraphic horizon lies at the surface. The distribution of higher and lower stratigraphic horizons can be shown by highlighting areas similarly higher or lower on the same DEM. Poor fit of contacts or faults projected between field traverses suggest the nature and amount of intervening geologic structure

  6. Stable isotopes of transition and post-transition metals as tracers in environmental studies

    Science.gov (United States)

    Bullen, Tomas D.; Baskaran, Mark

    2011-01-01

    The transition and post-transition metals, which include the elements in Groups 3–12 of the Periodic Table, have a broad range of geological and biological roles as well as industrial applications and thus are widespread in the environment. Interdisciplinary research over the past decade has resulted in a broad understanding of the isotope systematics of this important group of elements and revealed largely unexpected variability in isotope composition for natural materials. Significant kinetic and equilibrium isotope fractionation has been observed for redox sensitive metals such as iron, chromium, copper, molybdenum and mercury, and for metals that are not redox sensitive in nature such as cadmium and zinc. In the environmental sciences, the isotopes are increasingly being used to understand important issues such as tracing of metal contaminant sources and fates, unraveling metal redox cycles, deciphering metal nutrient pathways and cycles, and developing isotope biosignatures that can indicate the role of biological activity in ancient and modern planetary systems.

  7. Evaluation of new geological reference materials for uranium-series measurements: Chinese Geological Standard Glasses (CGSG) and macusanite obsidian.

    Science.gov (United States)

    Denton, J S; Murrell, M T; Goldstein, S J; Nunn, A J; Amato, R S; Hinrichs, K A

    2013-10-15

    Recent advances in high-resolution, rapid, in situ microanalytical techniques present numerous opportunities for the analytical community, provided accurately characterized reference materials are available. Here, we present multicollector thermal ionization mass spectrometry (MC-TIMS) and multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) uranium and thorium concentration and isotopic data obtained by isotope dilution for a suite of newly available Chinese Geological Standard Glasses (CGSG) designed for microanalysis. These glasses exhibit a range of compositions including basalt, syenite, andesite, and a soil. Uranium concentrations for these glasses range from ∼2 to 14 μg g(-1), Th/U weight ratios range from ∼4 to 6, (234)U/(238)U activity ratios range from 0.93 to 1.02, and (230)Th/(238)U activity ratios range from 0.98 to 1.12. Uranium and thorium concentration and isotopic data are also presented for a rhyolitic obsidian from Macusani, SE Peru (macusanite). This glass can also be used as a rhyolitic reference material, has a very low Th/U weight ratio (around 0.077), and is approximately in (238)U-(234)U-(230)Th secular equilibrium. The U-Th concentration data agree with but are significantly more precise than those previously measured. U-Th concentration and isotopic data agree within estimated errors for the two measurement techniques, providing validation of the two methods. The large (238)U-(234)U-(230)Th disequilibria for some of the glasses, along with the wide range in their chemical compositions and Th/U ratios should provide useful reference points for the U-series analytical community.

  8. Anomalies on orbifolds

    Energy Technology Data Exchange (ETDEWEB)

    Arkani-Hamed, Nima; Cohen, Andrew G.; Georgi, Howard

    2001-03-16

    We discuss the form of the chiral anomaly on an S1/Z2 orbifold with chiral boundary conditions. We find that the 4-divergence of the higher-dimensional current evaluated at a given point in the extra dimension is proportional to the probability of finding the chiral zero mode there. Nevertheless the anomaly, appropriately defined as the five dimensional divergence of the current, lives entirely on the orbifold fixed planes and is independent of the shape of the zero mode. Therefore long distance four dimensional anomaly cancellation ensures the consistency of the higher dimensional orbifold theory.

  9. Radiometric geological exploration method used in the central part of the State of Sonora

    International Nuclear Information System (INIS)

    Pacheco R, R.

    1978-01-01

    The purpose of this study is to make known the importance of the radiometric data, the physical principles on which they are based and the geological interpretation which will permit in an indirect way to select important radioactive areas in order to carry out verification studies on the ground to see if there are sufficient reasons to show any interest in these areas. Till now this work has been realized in the State of Sonora (Mexico) in an area of 51,000 Km 2 subdivided in 14 zones, numbered from 201 to 214, and for the present work the zone 208 has been selected. This Zone is located at the north-west of the City of Hermosillo, and has a total area of 3400 Km 2 which has been the object of the study by plane through systematic flights in an east-west direction, in order to obtain the configuration and interpret it from a radiometrical point of view. The obtained isorads configuration plans of 4 channels of detection are the following: total counting, potassium, bismuth and thallium as well as their relations. From the 14 verified anomalies the anomaly Noche Buena was selected in order to carry out reconnaissance surveys and preliminary and detailed geological studies. The geology of the area is represented by extrusive and intrusive igneous rocks as well as sedimentary. The uraniferous mineralization is secondary and is represented by autunite, meta-autunite and torbenite which represent an average of 200 g to 3.08 Kg. of U 3 O 8 per ton. (author)

  10. First branchial groove anomaly.

    Science.gov (United States)

    Kumar, M; Hickey, S; Joseph, G

    2000-06-01

    First branchial groove anomalies are very rare. We report a case of a first branchial groove anomaly presented as an infected cyst in an 11-month-old child. Management of such lesions is complicated because of their close association with the facial nerve. Surgical management must include identification and protection of the facial nerve. Embryology and facial nerve disposition in relation to the anomaly are reviewed.

  11. Search for isotopic signatures of a supernova explosion close to the solar system in marine sediments

    International Nuclear Information System (INIS)

    Fitoussi, Caroline

    2006-06-01

    The recent observation of a 60 Fe peak in a deep-sea ferro-manganese crust has been interpreted as due to a supernova explosion relatively close to the solar system 2.8 ± 0.4 Myr ago. To confirm this interpretation with better time-resolved measurements, and the simultaneous access, on the same sample, to other isotopes and geochemical phases, marine sediments seem to be a tool of choice. The objective of this work was to search for isotopic anomalies which would be characteristic for residues of this supernova. More specifically, 129 I, 60 Fe, and 26 Al have been investigated, being measured by Accelerator Mass Spectrometry (AMS). Quantifying these nuclides' fluxes would help constrain stellar nucleosynthesis models. These residues are isotopes initially produced during hydrostatic and/or explosive nucleosynthesis. The physical conditions during the explosion (temperature, neutron density) are such that supernovae are thought to be good candidates for the astrophysical site of the r-process. The 129 I study showed that measurement of pre-anthropogenic 129 I/ 127 I ratios need a very strict control of the various potential 129 I sources, especially when working with small quantities (micrograms) of iodine. This study revealed that the expected pre-anthropogenic 129 I/ 127 I ratio for pre-nuclear samples in the marine environment shows a large discrepancy between theoretical calculations and experimental measurements. 60 Fe and 26 Al measurements allow us to conclude that, in the authigenic phase of the marine sediments, there is no 60 Fe anomaly in the time interval defined by the signal found on the Fe-Mn crust (from 2.4 to 3.2 Myr), and no 26 Al anomaly from 2.6 to 3.2 Myr. (author)

  12. New geologic, fluid inclusion and stable isotope studies on the controversial Igarapé Bahia Cu-Au deposit, Carajás Province, Brazil

    Science.gov (United States)

    Dreher, Ana M.; Xavier, Roberto P.; Taylor, Bruce E.; Martini, Sérgio L.

    2008-02-01

    contribution of reduced and oxydized sulfur is also evident. Oxygen isotopic ratios in magnetite, quartz, and siderite yield calculated temperatures of ˜400°C and δ18O-enriched compositions (5 to 16.5 per mil) for the ore-forming fluids that suggest a magmatic input and/or an interaction with 18O-rich, probably sedimentary rocks. The late veins of the Igarapé Bahia deposit area were formed from saline aqueous fluids (2 to 60 wt% NaCl + CaCl2 equiv) with δ18Ofluid compositions around 0 per mil that indicate contribution from meteoric fluids. With respect to geological features, Igarapé Bahia bears similarity with syngenetic, volcanic-hosted massive sulfide (VHMS)-type deposits, as indicated by the volcano-sedimentary geological context, stratabound character, and association with submarine volcanic flows, hyaloclastite, and exhalative beds such as BIF and chert. On the other hand, the highly saline ore fluids and the mineral assemblage, dominated by magnetite and chalcopyrite, with associated gold, U- and LREE-minerals and scarce pyrite, indicate that Igarapé Bahia belongs to the Fe oxide Cu-Au (IOCG) group of deposits. The available geochronologic data used to attest syngenetic or epigenetic origins for the mineralization are either imprecise or may not represent the main mineralization episode but a later, superimposed event. The C, S, and O isotopic results obtained in this study do not clearly discriminate between fluid sources. However, recent B isotope data obtained on tourmaline from the matrix of the fragmental rock ore unit (Xavier, Wiedenbeck, Dreher, Rhede, Monteiro, Araújo, Chemical and boron isotopic composition of tourmaline from Archean and Paleoproterozoic Cu-Au deposits in the Carajás Mineral Province, 1° Simpósio Brasileiro de Metalogenia, Gramado, Brazil, extended abstracts, CD-ROM, 2005) provide strong evidence of the involvement of a marine evaporitic source in the hydrothermal system of Igarapé Bahia. Evaporite-derived fluids may explain the

  13. Isotope characterisation of historical alabaster quarries in Western Europe.

    Science.gov (United States)

    Kloppmann, Wolfram; Leroux, Lise; Bromblet, Philippe; Cooper, Anthony H.; Nestler, Angela; Guerrot, Catherine; Montech, Anne-Thérèse; Worley, Noel

    2015-04-01

    The origin of the raw material of gypsum alabaster artwork is still largely underinvestigated as conventional chemical and mineralogical analyses have not yielded convincing results due to the rather homogeneous composition, especially of the most wanted pure white varieties. Yet, identifying the origin of raw materials used for sculpture is crucial for art historians and museums aiming at identifying artists, rarely nominally documented before the 16th century, workshops and historic trade roads. A pilot study (Kloppmann et al., 2014) revealed the potential of multi-isotope fingerprinting of alabaster provenance, using a combination of sulphur, oxygen and strontium isotopes. Here we present an enlarged data base of isotope analyses of samples from known or suspected historical alabaster exploitations in France (Jura, Alps, Provence, Burgundy, Lorraine, Aquitaine, Paris region), Spain (Aragon and Catalonia), England (East Midlands/Nottingham region, Cumberland, N Yorkshire), Germany (Harz Mountain foreland). Strontium and sulphur isotopes appear to be particularly discriminative with a strong inter-site variability and intra-site homogeneity. Isotope ratios of both elements in seawater and associated evaporites have strongly varied over geological timescales (Claypool et al. 1980; Burke et al. 1982; Denison et al. 1998) so that W-European alabaster samples, ranging from Permian (Zechstein) to Miocene ages, show age-specific differentiation. Additionally, for both elements, non-marine sources such as sulphides, organic sulphur and strontium derived from mineral weathering provide basin- or sub-basin-specific signatures that further discriminate alabaster provenances. Oxygen isotopes provide supplementary evidence even if there is a stronger overlap of signatures. In conclusion, we consider that we have now an operational tool to distinguish the main alabaster sources for historical workshops in Western Europe. This methodology is currently applied to sculptures

  14. A compilation of Sr and Nd isotope data on Mexico

    International Nuclear Information System (INIS)

    Verma, S.P.; Verma, M.P.

    1986-01-01

    A compilation is given of the available Sr and Nd isotope data on Mexican volcanic-plutonic terranes which cover about one-third of Mexico's territory. The available data are arranged according to a subdivision of the Mexican territory in terms of geological provinces. Furthermore, site and province averages and standard deviations are calculated and their petrogenetic implications are pointed out. (author)

  15. Hyperfine spectra of the radioactive isotopes 81Kr and 85Kr

    International Nuclear Information System (INIS)

    Cannon, B.D.

    1993-01-01

    Isotope shifts and hyperfine constants are reported for the radioactive isotopes 81 Kr and 85 Kr and the stable isotope 83 Kr. The previously unreported nuclear moments of 81 Kr were determined to be μ I =-0.909(4) nuclear magneton and Q=+0.630(13) b from the hyperfine constants. This work increases the number of transitions for which 85 Kr hyperfine constants and isotope shifts have been measured from 1 to 4. The hyperfine anomaly for krypton reported in the previous measurement of 85 Kr hyperfine constants [H. Gerhardt et al., Hyperfine Interact. 9, 175 (1981)] is not supported by this work. The isotope shifts and hyperfine constants of 83 Kr measured in this work are in excellent agreement with previous work. Saturation spectroscopy was used to study transitions from krypton's metastable 1s 5 state to the 2p 9 , 2p 7 , and 2p 6 states. In saturation spectra, different line shapes were observed for the even- and odd-mass krypton isotopes. This even- versus odd-line-mass shape difference can be explained using the large cross section that has been reported for collisional transfer of the 1s 5 state excitation between krypton atoms. Two-color two-photon laser-induced fluorescence was used to measure the hyperfine spectra of the 1s 5- 4d 4 ' transition using the 2p 9 state as the intermediate state. This technique proved to be more sensitive than saturation spectroscopy

  16. Anglo-Saxon animal husbandry techniques revealed though isotope and chemical variations in cattle teeth

    International Nuclear Information System (INIS)

    Evans, J.A.; Tatham, S.; Chenery, S.R.; Chenery, C.A.

    2007-01-01

    The Sr concentration and isotope composition of tooth enamel from domesticated animals from two neighbouring Anglo-Saxon settlements, at Empingham (6-7th century) and Ketton (10-12th century) in Rutland, central England, are compared both with each other, and with associated human populations. Data from the Empingham II site form discrete fields in Sr concentration and isotope composition space for cattle, pig and sheep with a partial overlap of the human and pig fields. By contrast there is significant overlap in all the animal and human data fields from the Ketton site. The differences in data distribution between the two sites are attributed to animal husbandry techniques, as the surface geology of the two areas is very similar, implying geological factors are an unlikely cause of the difference. It is suggested that the grazing and feeding patterns of animals at the Empingham II site were controlled and restricted, whereas at the Ketton site the animals grazed and foraged freely over a common area. Strontium isotope variation within cattle molars from the two settlements show marked differences that reflect the nature of their feeding and rearing. The enamel from a cattle molar from the Empingham II site has a well-defined, systematic variation of Sr isotope composition with Sr concentration, whereas no such patterns exist in a comparable cattle molar from Ketton. Chemical and O isotope variations in the cattle tooth from Empingham II show sympathetic variation of Sr and Ba concentrations with Sr isotope composition from cusp to cervix. The cusp has higher Sr and Ba concentrations log (Sr/Ca) ratio of -3.1 and 87 Sr/ 86 Sr ratio of 0.71151 where as the cervical region of the enamel has log (Sr/Ca) = -3.3 and 87 Sr/ 86 Sr = 0.71061

  17. Anglo-Saxon animal husbandry techniques revealed though isotope and chemical variations in cattle teeth

    Energy Technology Data Exchange (ETDEWEB)

    Evans, J.A. [NERC Isotope Geosciences Laboratory, BGS, Keyworth, Nottingham NG12 5GG (United Kingdom)], E-mail: je@nigl.nerc.ac.uk; Tatham, S. [School of Archaeology and Ancient History, University of Leicester, Leicester LE1 7RH (United Kingdom); Chenery, S.R. [British Geological Survey, Keyworth, Nottingham NG12 5GG (United Kingdom); Chenery, C.A. [NERC Isotope Geosciences Laboratory, BGS, Keyworth, Nottingham NG12 5GG (United Kingdom)

    2007-09-15

    The Sr concentration and isotope composition of tooth enamel from domesticated animals from two neighbouring Anglo-Saxon settlements, at Empingham (6-7th century) and Ketton (10-12th century) in Rutland, central England, are compared both with each other, and with associated human populations. Data from the Empingham II site form discrete fields in Sr concentration and isotope composition space for cattle, pig and sheep with a partial overlap of the human and pig fields. By contrast there is significant overlap in all the animal and human data fields from the Ketton site. The differences in data distribution between the two sites are attributed to animal husbandry techniques, as the surface geology of the two areas is very similar, implying geological factors are an unlikely cause of the difference. It is suggested that the grazing and feeding patterns of animals at the Empingham II site were controlled and restricted, whereas at the Ketton site the animals grazed and foraged freely over a common area. Strontium isotope variation within cattle molars from the two settlements show marked differences that reflect the nature of their feeding and rearing. The enamel from a cattle molar from the Empingham II site has a well-defined, systematic variation of Sr isotope composition with Sr concentration, whereas no such patterns exist in a comparable cattle molar from Ketton. Chemical and O isotope variations in the cattle tooth from Empingham II show sympathetic variation of Sr and Ba concentrations with Sr isotope composition from cusp to cervix. The cusp has higher Sr and Ba concentrations log (Sr/Ca) ratio of -3.1 and {sup 87}Sr/{sup 86}Sr ratio of 0.71151 where as the cervical region of the enamel has log (Sr/Ca) = -3.3 and {sup 87}Sr/{sup 86}Sr = 0.71061.

  18. TWO EXAMPLES FOR IMAGING BURIED GEOLOGICAL BOUNDARIES: SINKHOLE STRUCTURE AND SEYİT HACI FAULT, KARAPINAR, KONYA

    Directory of Open Access Journals (Sweden)

    Ertan TOKER

    2014-12-01

    Full Text Available Once anomalies with positive and negative circular closures are assessed together inpotential field maps, the ones which have meaningful geometric structure appear as moredistinguishable. When the edge detection is applied, the preliminary geological modelabout the geological structure may or may not be verified. When it is not verified then it isunderstood that the predicted geological model should be reconsidered and discussedagain. In this study, the edge detection was introduced and the success of the method wastested in an artificial data. Following that, its effect on sinkholes was studied applying themethod on detailed gravity data collected in Karapınar (Konya region. At the same time,this method was applied on data related to active Seyit Hacı Fault zone. It was detectedthat the fault had shown continuity towards SW and these evidences were discussed

  19. New Bouguer Gravity Maps of Venezuela: Representation and Analysis of Free-Air and Bouguer Anomalies with Emphasis on Spectral Analyses and Elastic Thickness

    Directory of Open Access Journals (Sweden)

    Javier Sanchez-Rojas

    2012-01-01

    Full Text Available A new gravity data compilation for Venezuela was processed and homogenized. Gravity was measured in reference to the International Gravity Standardization Net 1971, and the complete Bouguer anomaly was calculated by using the Geodetic Reference System 1980 and 2.67 Mg/m3. A regional gravity map was computed by removing wavelengths higher than 200 km from the Bouguer anomaly. After the anomaly separation, regional and residual Bouguer gravity fields were then critically discussed in term of the regional tectonic features. Results were compared with the previous geological and tectonic information obtained from former studies. Gravity and topography data in the spectral domain were used to examine the elastic thickness and depths of the structures of the causative measured anomaly. According to the power spectrum analysis results of the gravity data, the averaged Moho depths for the massif, plains, and mountainous areas in Venezuela are 42, 35, and 40 km, respectively. The averaged admittance function computed from the topography and Free-Air anomaly profiles across Mérida Andes showed a good fit for a regional compensation model with an effective elastic thickness of 15 km.

  20. Precambrian continental crustal evolution of Southeastern Sao Paulo state - Brazil: based on isotopic evidences

    International Nuclear Information System (INIS)

    Tassinari, C.C.G.

    1988-01-01

    The isotopic studies on granitic intrusions, orthogneissic rocks and migmatitic terranes in the Southeastern Sao Paulo are presented, indicating the age and the geochemical nature of the continental crust of this area. Approximately 300 Ar, Sr and Pb isotopic age determinations are included in this paper, categorized as to their reliability and significance. Looking for the continental crust growth related to the geological time, at the end of the lower Proterozoic, at least 85% of the continental crust has already accreted and differentiated. (C.G.C.)

  1. Studies of cesium and strontium migration in unconsolidated Canadian geological materials

    International Nuclear Information System (INIS)

    Gillham, R.W.; Lindsay, L.E.; Reynolds, W.D.; Kewen, T.J.; Cherry, J.A.; Reddy, M.R.

    1981-06-01

    Distribution coefficients (Ksub(d)) were measured for cesium and strontium in 16 samples of Canadian unconsolidated geological materials. The samples were collected to cover a wide range of grain size, clay-mineral composition, cation exchange capacity and carbonate mineral content. Distribution coefficients ranged between 10 2 and 2.0 x 10 4 ml/g for cesium and between 2.5 and 10 2 ml/g for strontium, indicating that most unconsolidated geological materials have a substantial ability to retard the migration of cesium, while strontium could generally be expected to be somewhat more mobile. The measured K values were not significantly correlated with the measured soil properties, but appeared to be significantly affected by the background concentration of stable isotopes of the respective radionuclides

  2. Low Count Anomaly Detection at Large Standoff Distances

    Science.gov (United States)

    Pfund, David Michael; Jarman, Kenneth D.; Milbrath, Brian D.; Kiff, Scott D.; Sidor, Daniel E.

    2010-02-01

    Searching for hidden illicit sources of gamma radiation in an urban environment is difficult. Background radiation profiles are variable and cluttered with transient acquisitions from naturally occurring radioactive materials and medical isotopes. Potentially threatening sources likely will be nearly hidden in this noise and encountered at high standoff distances and low threat count rates. We discuss an anomaly detection algorithm that characterizes low count sources as threatening or non-threatening and operates well in the presence of high benign source variability. We discuss the algorithm parameters needed to reliably find sources both close to the detector and far away from it. These parameters include the cutoff frequencies of background tracking filters and the integration time of the spectrometer. This work is part of the development of the Standoff Radiation Imaging System (SORIS) as part of DNDO's Standoff Radiation Detection System Advanced Technology Demonstration (SORDS-ATD) program.

  3. Uranium, plutonium, and thorium isotopes in the atmosphere and the lithosphere

    International Nuclear Information System (INIS)

    Essien, I.O.

    1983-01-01

    Concentration of 238 U in rain and snow collected at Fayetteville (36 0 N, 94 0 W), Arkansas, showed a marked increase during the summer months of 1980, while Mount St. Helens remained active. This observed increase of 238 U can be explained as due to the fallout of natural uranium from the eruption of Mount St. Helens. Large increases in the concentration of thorium isotopes detected in rain and snow samples during the last months of 1982 and early months of 1983 probably originated from the eruption of El Chichon volcano, which occurred on 28 March 1982. About 450 Ci of 232 Th is estimated to have been injected into the atmosphere by this eruption. Isotopic anomalies were observed in atmospheric samples such as rain and snow. These anomalies can be attributed to various natural as well as man-made sources: nuclear weapon tests, nuclear accidents involving the burn-up of nuclear powered satellites, and volcanic eruptions. The variation of 234 U/ 238 U ratios in radioactive minerals when leached with nitric acid were also noticed and this variation, while 235 U/ 238 U remained fairly constant, can be explained in terms of the α-recoil effect and changes in oxidation state of uranium. Difference found in 239 Pu/ 238 U ratios in terrestrial samples and uranium minerals can be explained as due to fallout contamination

  4. Carbon and hydrogen isotopic effects of stomatal density in Arabidopsis thaliana

    Science.gov (United States)

    Lee, Hyejung; Feakins, Sarah J.; Sternberg, Leonel da S. L.

    2016-04-01

    Stomata are key gateways mediating carbon uptake and water loss from plants. Varied stomatal densities in fossil leaves raise the possibility that isotope effects associated with the openness of exchange may have mediated plant wax biomarker isotopic proxies for paleovegetation and paleoclimate in the geological record. Here we use Arabidopsis thaliana, a widely used model organism, to provide the first controlled tests of stomatal density on carbon and hydrogen isotopic compositions of cuticular waxes. Laboratory grown wildtype and mutants with suppressed and overexpressed stomatal densities allow us to directly test the isotope effects of stomatal densities independent of most other environmental or biological variables. Hydrogen isotope (D/H) measurements of both plant waters and plant wax n-alkanes allow us to directly constrain the isotopic effects of leaf water isotopic enrichment via transpiration and biosynthetic fractionations, which together determine the net fractionation between irrigation water and n-alkane hydrogen isotopic composition. We also measure carbon isotopic fractionations of n-alkanes and bulk leaf tissue associated with different stomatal densities. We find offsets of +15‰ for δD and -3‰ for δ13C for the overexpressed mutant compared to the suppressed mutant. Since the range of stomatal densities expressed is comparable to that found in extant plants and the Cenozoic fossil record, the results allow us to consider the magnitude of isotope effects that may be incurred by these plant adaptive responses. This study highlights the potential of genetic mutants to isolate individual isotope effects and add to our fundamental understanding of how genetics and physiology influence plant biochemicals including plant wax biomarkers.

  5. Space weather and space anomalies

    Directory of Open Access Journals (Sweden)

    L. I. Dorman

    2005-11-01

    Full Text Available A large database of anomalies, registered by 220 satellites in different orbits over the period 1971-1994 has been compiled. For the first time, data from 49 Russian Kosmos satellites have been included in a statistical analysis. The database also contains a large set of daily and hourly space weather parameters. A series of statistical analyses made it possible to quantify, for different satellite orbits, space weather conditions on the days characterized by anomaly occurrences. In particular, very intense fluxes (>1000 pfu at energy >10 MeV of solar protons are linked to anomalies registered by satellites in high-altitude (>15000 km, near-polar (inclination >55° orbits typical for navigation satellites, such as those used in the GPS network, NAVSTAR, etc. (the rate of anomalies increases by a factor ~20, and to a much smaller extent to anomalies in geostationary orbits, (they increase by a factor ~4. Direct and indirect connections between anomaly occurrence and geomagnetic perturbations are also discussed.

  6. Geophysical anomalies associated with uranium mineralization from Beldih mine, South Purulia Shear Zone, India

    International Nuclear Information System (INIS)

    Mandal, Animesh; Biswas, Arkoprovo; Mittal, Saurabh; Mohanty, William K.; Sharma, Shashi Prakash; Sengupta, Debashish; Sen, Joydip; Bhatt, A.K.

    2013-01-01

    Beldih mine at the central part of the South Purulia Shear Zone (SPSZ) has been reported with low grade uranium-bearing formation within quartz-magnetite-apatite host in kaolinized formation. Therefore, the present integrated geophysical study with gravity, magnetic, radiometric, very low frequency electromagnetic (VLF) and gradient resistivity profiling methods around the known mineralized zones aimed at identifying the exact geophysical signatures and lateral extent of these uranium mineralization bands. The closely spaced gravity-magnetic contours over the low to high anomaly transition zones of Bouguer, reduced-to-pole magnetic, and trend surface separated residual gravity-magnetic anomaly maps indicate the possibility of high altered zone(s) along NW-SE direction at the central part of the study area. High current density plots of VLF method and the low resistive zones in gradient resistivity study depict the coincidence with low gravity, moderately high magnetic and low resistivity anomalies at the same locations. Moderate high radioactive zones have also been observed over these locations. This also suggests the existence of radioactive mineralization over this region. Along profile P2, drilled borehole data revealed the presence of uranium mineralization at a depth of ∼100 m. The vertical projection of this mineralization band also identified as low gravity, low resistivity and high magnetic anomaly zone. Thus, the application of integrated geophysical techniques supported by geological information successfully recognized the nature of geophysical signatures associated with the uranium mineralization of this region. This enhances the scope of further integrated geophysical investigations in the unexplored regions of SPSZ. (author)

  7. Discussions of the uranium geology working groups IGC, Sydney

    International Nuclear Information System (INIS)

    1978-01-01

    The report is divided into six working group discussions on the following subjects: 1) Chemical and physical mechanisms in the formation of uranium mineralization, geochronology, isotope geology and mineralogy; 2) Sedimentary basins and sandstone-type uranium deposits; 3) Uranium in quartz-pebble conglomerates; 4) Vein and similar type deposits (pitchblende); 5) Other uranium deposits; 6) Relation of metallogenic, tectonic and zoning factors to the origin of uranium deposits. Each working group paper contains a short introductory part followed by a discussion by the working group members

  8. Mapping magnetized geologic structures from space: The effect of orbital and body parameters

    Science.gov (United States)

    Schnetzler, C. C.; Taylor, P. T.; Langel, R. A.

    1984-01-01

    When comparing previous satellite magnetometer missions (such as MAGSAT) with proposed new programs (for example, Geopotential Research Mission, GRM) it is important to quantify the difference in scientific information obtained. The ability to resolve separate magnetic blocks (simulating geological units) is used as a parameter for evaluating the expected geologic information from each mission. The effect of satellite orbital altitude on the ability to resolve two magnetic blocks with varying separations is evaluated and quantified. A systematic, nonlinear, relationship exists between resolution and distance between magnetic blocks as a function of orbital altitude. The proposed GRM would provide an order-of-magnitude greater anomaly resolution than the earlier MAGSAT mission for widely separated bodies. The resolution achieved at any particular altitude varies depending on the location of the bodies and orientation.

  9. A study of radionuclides, metals and stable lead isotope ratios in sediments and soils in the vicinity of natural U-mineralisation areas in the Northern Territory

    International Nuclear Information System (INIS)

    Frostick, A.; Bollhoefer, A.; Parry, D.

    2011-01-01

    Australian guidelines recommend that tailings materials from uranium (U) mining and milling be contained without any detrimental impact on the environment for at least 1000 years. Natural analogue sites are being investigated to determine if they can provide data on the rates of natural erosion processes which occur over these timescales, for input into predictive geomorphic computer models. This paper presents radionuclide, metal and stable lead (Pb) isotope data from sediment cores and surface soils in the vicinity of two mineralised areas in the Alligator Rivers Region. Surface scrapes from the natural Anomaly no. 2, south of the Ranger mineral lease, exhibit radiogenic 206 Pb/ 207 Pb and 208 Pb/ 207 Pb ratios, and elevated U and metal concentrations typical for a near surface U anomaly. In contrast, samples taken from the Koongarra mineral lease (KML) show radionuclide activity and metal concentrations similar to natural areas elsewhere in the Alligator Rivers Region and Pb isotope ratios are closer to present day average crustal ratios (PDAC), as the orebodies at KML are covered by surficial sand. A sediment core collected from Anbangbang Billabong, downstream of KML, exhibits small variations in Pb isotope ratios that indicate that approximately 1% of the upper sediments in the sediment core may be derived from material originating from the U anomaly at Koongarra.

  10. A study of radionuclides, metals and stable lead isotope ratios in sediments and soils in the vicinity of natural U-mineralisation areas in the Northern Territory

    Energy Technology Data Exchange (ETDEWEB)

    Frostick, A., E-mail: Alison.Frostick@cdu.edu.au [Charles Darwin University, School of Environment and Life Sciences, Darwin NT 0909 (Australia); ERISS, GPO Box 461, Darwin NT 0801 (Australia); Bollhoefer, A. [ERISS, GPO Box 461, Darwin NT 0801 (Australia); Parry, D. [AIMS, PO Box 41775, Casuarina NT 0811 (Australia)

    2011-10-15

    Australian guidelines recommend that tailings materials from uranium (U) mining and milling be contained without any detrimental impact on the environment for at least 1000 years. Natural analogue sites are being investigated to determine if they can provide data on the rates of natural erosion processes which occur over these timescales, for input into predictive geomorphic computer models. This paper presents radionuclide, metal and stable lead (Pb) isotope data from sediment cores and surface soils in the vicinity of two mineralised areas in the Alligator Rivers Region. Surface scrapes from the natural Anomaly no. 2, south of the Ranger mineral lease, exhibit radiogenic {sup 206}Pb/{sup 207}Pb and {sup 208}Pb/{sup 207}Pb ratios, and elevated U and metal concentrations typical for a near surface U anomaly. In contrast, samples taken from the Koongarra mineral lease (KML) show radionuclide activity and metal concentrations similar to natural areas elsewhere in the Alligator Rivers Region and Pb isotope ratios are closer to present day average crustal ratios (PDAC), as the orebodies at KML are covered by surficial sand. A sediment core collected from Anbangbang Billabong, downstream of KML, exhibits small variations in Pb isotope ratios that indicate that approximately 1% of the upper sediments in the sediment core may be derived from material originating from the U anomaly at Koongarra.

  11. Upward revision of global fossil fuel methane emissions based on isotope database.

    Science.gov (United States)

    Schwietzke, Stefan; Sherwood, Owen A; Bruhwiler, Lori M P; Miller, John B; Etiope, Giuseppe; Dlugokencky, Edward J; Michel, Sylvia Englund; Arling, Victoria A; Vaughn, Bruce H; White, James W C; Tans, Pieter P

    2016-10-06

    Methane has the second-largest global radiative forcing impact of anthropogenic greenhouse gases after carbon dioxide, but our understanding of the global atmospheric methane budget is incomplete. The global fossil fuel industry (production and usage of natural gas, oil and coal) is thought to contribute 15 to 22 per cent of methane emissions to the total atmospheric methane budget. However, questions remain regarding methane emission trends as a result of fossil fuel industrial activity and the contribution to total methane emissions of sources from the fossil fuel industry and from natural geological seepage, which are often co-located. Here we re-evaluate the global methane budget and the contribution of the fossil fuel industry to methane emissions based on long-term global methane and methane carbon isotope records. We compile the largest isotopic methane source signature database so far, including fossil fuel, microbial and biomass-burning methane emission sources. We find that total fossil fuel methane emissions (fossil fuel industry plus natural geological seepage) are not increasing over time, but are 60 to 110 per cent greater than current estimates owing to large revisions in isotope source signatures. We show that this is consistent with the observed global latitudinal methane gradient. After accounting for natural geological methane seepage, we find that methane emissions from natural gas, oil and coal production and their usage are 20 to 60 per cent greater than inventories. Our findings imply a greater potential for the fossil fuel industry to mitigate anthropogenic climate forcing, but we also find that methane emissions from natural gas as a fraction of production have declined from approximately 8 per cent to approximately 2 per cent over the past three decades.

  12. Geological Structure and Radon Hazards in Lublin Region

    Directory of Open Access Journals (Sweden)

    Lucjan Gazda

    2018-03-01

    Full Text Available The purpose of the study was to show the relationship between the geological structure of the Lublin region (eastern Poland and radon concentrations in the ground air, and therefore, in the indoor environment of buildings located in that area. The study was based on the information pertaining to the geological structure of Lublin region available in the literature. The radon concentrations in buildings, caves, wells, as well as coal, phosphate and chalk mines were measured with both passive and active methods. Elemental analyses and uranium and lead isotope analyses of ground rocks were also performed. The conducted studies indicated that the sources of radon in Lublin region constitute Paleogene and Mesozoic sedimentary rocks rich in radionuclides. Application of radon remediation methods is recommended in the existing buildings located in the vicinity of these rocks, which are characterized by relatively high radon exhalations. On the other hand, the designed buildings should employ the measures protecting against harmful effects of radon presence.

  13. Preliminary results of oxygen isotope ratio measurement with a particle-gamma coincidence method

    Energy Technology Data Exchange (ETDEWEB)

    Borysiuk, Maciek, E-mail: maciek.borysiuk@pixe.lth.se; Kristiansson, Per; Ros, Linus; Abdel, Nassem S.; Elfman, Mikael; Nilsson, Charlotta; Pallon, Jan

    2015-04-01

    The possibility to study variations in the oxygen isotopic ratio with photon tagged nuclear reaction analysis (pNRA) is evaluated in the current work. The experiment described in the article was performed at Lund Ion Beam Analysis Facility (LIBAF) with a 2 MeV deuteron beam. Isotopic fractionation of light elements such as carbon, oxygen and nitrogen is the basis of many analytical tools in hydrology, geology, paleobiology and paleogeology. IBA methods provide one possible tool for measurement of isotopic content. During this experimental run we focused on measurement of the oxygen isotopic ratio. The measurement of stable isotopes of oxygen has a number of applications; the particular one driving the current investigation belongs to the field of astrogeology and specifically evaluation of fossil extraterrestrial material. There are three stable isotopes of oxygen: {sup 16}O, {sup 17}O and {sup 18}O. We procured samples highly enriched with all three isotopes. Isotopes {sup 16}O and {sup 18}O were easily detected in the enriched samples, but no significant signal from {sup 17}O was detected in the same samples. The measured yield was too low to detect {sup 18}O in a sample with natural abundances of oxygen isotopes, at least in the current experimental setup, but the spectral line from the reaction with {sup 16}O was clearly visible.

  14. 6d, Coulomb branch anomaly matching

    Science.gov (United States)

    Intriligator, Kenneth

    2014-10-01

    6d QFTs are constrained by the analog of 't Hooft anomaly matching: all anomalies for global symmetries and metric backgrounds are constants of RG flows, and for all vacua in moduli spaces. We discuss an anomaly matching mechanism for 6d theories on their Coulomb branch. It is a global symmetry analog of Green-Schwarz-West-Sagnotti anomaly cancellation, and requires the apparent anomaly mismatch to be a perfect square, . Then Δ I 8 is cancelled by making X 4 an electric/magnetic source for the tensor multiplet, so background gauge field instantons yield charged strings. This requires the coefficients in X 4 to be integrally quantized. We illustrate this for theories. We also consider the SCFTs from N small E8 instantons, verifying that the recent result for its anomaly polynomial fits with the anomaly matching mechanism.

  15. Surface Exposure Geochronology Using Cosmogenic Nuclides: Applications in Antarctic Glacial Geology

    Science.gov (United States)

    1994-02-01

    in rocks, are particularly promising for directly dating 1 geological surfaces . In 1934, Grosse et al. first suggested that cosmic rays produce rare...and muons produced by cosmic ray irteractions in the atmosphere and in rocks, and spallation by I neutrons produced in muon capture reactions (Kurz...stable isotopes are useful for surface 3 exposure studies because they can act as integrators of cosmic ray exposure on long time scales, potentially up

  16. WIPP site and vicinity geological field trip

    International Nuclear Information System (INIS)

    Chaturvedi, L.

    1980-10-01

    The Environmental Evaluation Group is conducting an assessment of the radiological health risks to people from the Waste Isolation Pilot Plant. As a part of this work, EEG is making an effort to improve the understanding of those geological issues concerning the WIPP site which may affect the radiological consequences of the proposed repository. One of the important geological issues to be resolved is the timing and the nature of the dissolution processes which may have affected the WIPP site. EEG organized a two-day conference of geological scientists, on January 17-18, 1980. On the basis of the January conference and the June field trip, EEG has formed the following conclusions: (1) it has not been clearly established that the site or the surrounding area has been attacked by deep dissolution to render it unsuitable for the nuclear waste pilot repository; (2) the existence of an isolated breccia pipe at the site unaccompanied by a deep dissolution wedge, is a very remote possibility; (3) more specific information about the origin and the nature of the brine reservoirs is needed. An important question that should be resolved is whether each encounter with artesian brine represents a separate pocket or whether these occurrences are interconnected; (4) Anderson has postulated a major tectonic fault or a fracture system at the Basin margin along the San Simon Swale; (5) the area in the northern part of the WIPP site, identified from geophysical and bore hole data as the disturbed zone, should be further investigated to cleary understand the nature and significance of this structural anomaly; and (6) a major drawback encountered during the discussions of geological issues related to the WIPP site is the absence of published material that brings together all the known information related to a particular issue

  17. A least-squares minimisation approach to depth determination from numerical second horizontal self-potential anomalies

    Science.gov (United States)

    Abdelrahman, El-Sayed Mohamed; Soliman, Khalid; Essa, Khalid Sayed; Abo-Ezz, Eid Ragab; El-Araby, Tarek Mohamed

    2009-06-01

    This paper develops a least-squares minimisation approach to determine the depth of a buried structure from numerical second horizontal derivative anomalies obtained from self-potential (SP) data using filters of successive window lengths. The method is based on using a relationship between the depth and a combination of observations at symmetric points with respect to the coordinate of the projection of the centre of the source in the plane of the measurement points with a free parameter (graticule spacing). The problem of depth determination from second derivative SP anomalies has been transformed into the problem of finding a solution to a non-linear equation of the form f(z)=0. Formulas have been derived for horizontal cylinders, spheres, and vertical cylinders. Procedures are also formulated to determine the electric dipole moment and the polarization angle. The proposed method was tested on synthetic noisy and real SP data. In the case of the synthetic data, the least-squares method determined the correct depths of the sources. In the case of practical data (SP anomalies over a sulfide ore deposit, Sariyer, Turkey and over a Malachite Mine, Jefferson County, Colorado, USA), the estimated depths of the buried structures are in good agreement with the results obtained from drilling and surface geology.

  18. waterData--An R package for retrieval, analysis, and anomaly calculation of daily hydrologic time series data, version 1.0

    Science.gov (United States)

    Ryberg, Karen R.; Vecchia, Aldo V.

    2012-01-01

    Hydrologic time series data and associated anomalies (multiple components of the original time series representing variability at longer-term and shorter-term time scales) are useful for modeling trends in hydrologic variables, such as streamflow, and for modeling water-quality constituents. An R package, called waterData, has been developed for importing daily hydrologic time series data from U.S. Geological Survey streamgages into the R programming environment. In addition to streamflow, data retrieval may include gage height and continuous physical property data, such as specific conductance, pH, water temperature, turbidity, and dissolved oxygen. The package allows for importing daily hydrologic data into R, plotting the data, fixing common data problems, summarizing the data, and the calculation and graphical presentation of anomalies.

  19. Renal anomalies in congenital heart disease

    International Nuclear Information System (INIS)

    Lee, Byung Hee; Kim, In One; Yeon, Kyung Mo; Yoon, Yong Soo

    1987-01-01

    In general, the incidence of urinary tract anomalies in congenital heart disease is higher than that in general population. So authors performed abdominal cineradiography in 1045 infants and children undergoing cineangiographic examinations for congenital heart disease, as a screening method for the detection, the incidence, and the nature of associated urinary tract anomalies. The results were as follows: 1. The incidence of urinary tract anomaly associated with congenital heart disease was 4.1% (<2% in general population). 2. Incidence of urinary tract anomalies was 4.62% in 671 acyanotic heart diseases, 3.20% in 374 cyanotic heart diseases. 3. There was no constant relationship between the type of cardiac anomaly and the type of urinary tract anomaly

  20. Structural, chemical and isotopic examinations of interstellar organic matter extracted from meteorites and interstellar dust particles

    Science.gov (United States)

    Busemann, Henner; Alexander, Conel M. O'D.; Nittler, Larry R.; Stroud, Rhonda M.; Zega, Tom J.; Cody, George D.; Yabuta, Hikaru; Kilcoyne, A. L. David

    2008-10-01

    Meteorites and Interplanetary Dust Particles (IDPs) are supposed to originate from asteroids and comets, sampling the most primitive bodies in the Solar System. They contain abundant carbonaceous material. Some of this, mostly insoluble organic matter (IOM), likely originated in the protosolar molecular cloud, based on spectral properties and H and N isotope characteristics. Together with cometary material returned with the Stardust mission, these samples provide a benchmark for models aiming to understand organic chemistry in the interstellar medium, as well as for mechanisms that secured the survival of these fragile molecules during Solar System formation. The carrier molecules of the isotope anomalies are largely unknown, although amorphous carbonaceous spheres, so-called nanoglobules, have been identified as carriers. We are using Secondary Ion Mass Spectrometry to identify isotopically anomalous material in meteoritic IOM and IDPs at a ~100-200 nm scale. Organics of most likely interstellar origin are then extracted with the Focused-Ion-Beam technique and prepared for synchrotron X-ray and Transmission Electron Microscopy. These experiments yield information on the character of the H- and N-bearing interstellar molecules: While the association of H and N isotope anomalies with nanoglobules could be confirmed, we have also identified amorphous, micron-sized monolithic grains. D-enrichments in meteoritic IOM appear not to be systematically associated with any specific functional groups, whereas 15N-rich material can be related to imine and nitrile functionality. The large 15N- enrichments observed here (δ15N > 1000 ‰) cannot be reconciled with models using interstellar ammonia ice reactions, and hence, provide new constraints for understanding the chemistry in cold interstellar clouds.

  1. Isotopic and geochemical evolution of ground and surface waters in a karst dominated geological setting: a case study from Belize, Central America

    International Nuclear Information System (INIS)

    Marfia, A.M.; Krishnamurthy, R.V.; Atekwana, E.A.; Panton, W.F.

    2004-01-01

    Analysis of stable isotopes and major ions in groundwater and surface waters in Belize, Central America was carried out to identify processes that may affect drinking water quality. Belize has a subtropical rainforest/savannah climate with a varied landscape composed predominantly of carbonate rocks and clastic sediments. Stable oxygen (δ 18 O) and hydrogen (δD) isotope ratios for surface and groundwater have a similar range and show high d-excess (10-40.8%o). The high d-excess in water samples suggest secondary continental vapor flux mixing with incoming vapor from the Caribbean Sea. Model calculations indicate that moisture derived from continental evaporation contributes 13% to overhead vapor load. In surface and groundwater, concentrations of dissolved inorganic carbon (DIC) ranged from 5.4 to 112.9 mg C/l and δ 13 C DIC ranged from -7.4 to -17.4%o. SO 4 2 , Ca 2+ and Mg 2+ in the water samples ranged from 2-163, 2-6593 and 2-90 mg/l, respectively. The DIC and δ 13 C DIC indicate both open and closed system carbonate evolution. Combined δ 13 C DIC and Ca 2+ , Mg 2+ , and SO 4 2- suggest additional groundwater evolution by gypsum dissolution and calcite precipitation. The high SO 4 2- content of some water samples indicates regional geologic control on water quality. Similarity in the range of δ 18 O, δD and δ 13 C DIC for surface waters and groundwater used for drinking water supply is probably due to high hydraulic conductivities of the karstic aquifers. The results of this study indicate rapid recharge of groundwater aquifers, groundwater influence on surface water chemistry and the potential of surface water to impact groundwater quality and vise versa

  2. Isotopic composition of salt efflorescence from the sandstone castellated rocks of the Bohemian Cretaceous Basin (Czech Republic)

    Czech Academy of Sciences Publication Activity Database

    Schweigstillová, Jana; Přikryl, R.; Novotná, M.

    2009-01-01

    Roč. 58, č. 1 (2009), s. 217-225 ISSN 0943-0105 Institutional research plan: CEZ:AV0Z30460519 Keywords : stable isotopes * salt efflorescence * sandstone Subject RIV: DB - Geology ; Mineralogy Impact factor: 1.078, year: 2009

  3. Geologic and radiometric study in the Picacho, Arizpe's Municipality, Sorora (Mexico) area

    International Nuclear Information System (INIS)

    Garcia y Barragan, J.C.

    1975-01-01

    This research work was aimed chiefly at studying the geology and radiometry of the El Picacho area in order to establish its uranium mineralization potential. Another purpose was to ascertain the factors favouring deposition of radioactive material in areas bordering on the Sierra del Manzanal, where the work was carried out. Detailed geological-radiometric surveys were made, both inside the El Picacho mine and at the surface. The geological surveys were carried out by means of compass bearings and stadia, while scintillometers and spectrometers were used for the radiometric studies. The work was supported by a general geological exploration of the central part of the Serra del Manzanal. To ascertain the radiometric anomalies, the distribution of the population of values was determined by statistical methods, the frequency, cumulative frequency and frequency percentage being evaluated for that purpose. The geological survey at the El Picacho mine revealed a group of fractures enclosing the following minerals: torbernite, iriginite and autunite. These fractures are no thicker than 5 cm and tend to wedge out after 3 meters. Primary uraniferous ore is likely to be found in this zone, so surveys based on (a) radon gas emanometry and (b) sediment geochemistry in the Siera del Manzanal are recommended. The basic data relating to this area could be supplemented by mineragraphic and X-ray studies, which would provide a fuller picture of the class of mineralogical species and of the paragenesis of radioactive material presnent in the zone. (author)

  4. Situs anomalies on prenatal MRI

    International Nuclear Information System (INIS)

    Nemec, Stefan F.; Brugger, Peter C.; Nemec, Ursula; Bettelheim, Dieter; Kasprian, Gregor; Amann, Gabriele; Rimoin, David L.; Graham, John M.; Prayer, Daniela

    2012-01-01

    Objective: Situs anomalies refer to an abnormal organ arrangement, which may be associated with severe errors of development. Due regard being given to prenatal magnetic resonance imaging (MRI) as an adjunct to ultrasonography (US), this study sought to demonstrate the in utero visualization of situs anomalies on MRI, compared to US. Materials and methods: This retrospective study included 12 fetuses with situs anomalies depicted on fetal MRI using prenatal US as a comparison modality. With an MRI standard protocol, the whole fetus was assessed for anomalies, with regard to the position and morphology of the following structures: heart; venous drainage and aorta; stomach and intestines; liver and gallbladder; and the presence and number of spleens. Results: Situs inversus totalis was found in 3/12 fetuses; situs inversus with levocardia in 1/12 fetuses; situs inversus abdominis in 2/12 fetuses; situs ambiguous with polysplenia in 3/12 fetuses, and with asplenia in 2/12 fetuses; and isolated dextrocardia in 1/12 fetuses. Congenital heart defects (CHDs), vascular anomalies, and intestinal malrotations were the most frequent associated malformations. In 5/12 cases, the US and MRI diagnoses were concordant. Compared to US, in 7/12 cases, additional MRI findings specified the situs anomaly, but CHDs were only partially visualized in six cases. Conclusions: Our initial MRI results demonstrate the visualization of situs anomalies and associated malformations in utero, which may provide important information for perinatal management. Using a standard protocol, MRI may identify additional findings, compared to US, which confirm and specify the situs anomaly, but, with limited MRI visualization of fetal CHDs.

  5. RARE BRANCHIAL ARCH ANOMALIES

    Directory of Open Access Journals (Sweden)

    Jayanta Kumar

    2016-03-01

    Full Text Available AIM Amongst the branchial arch anomalies third arch anomaly occurs rarely and more so the fourth arch anomalies. We present our experience with cases of rare branchial arch anomalies. PATIENTS AND METHODS From June 2006 to January 2016, cases having their external opening in the lower third of sternocleidomastoid muscle with the tract going through thyroid gland and directing to pyriform sinus (PFS or cysts with internal opening in the PFS were studied. RESULTS No fourth arch anomaly was encountered. One cyst with internal opening which later on formed a fistula, three fistulae from beginning and two sinuses were encountered. The main stay of diagnosis was the fistula in the PFS and the tract lying posterior to the internal carotid artery. Simple excision technique with a small incision around the external opening was done. There was no recurrence. CONCLUSION Third arch fistula is not very rare as it was thought. Internal fistula is found in most of the cases. Though radiological investigations are helpful, fistulae can be diagnosed clinically and during operation. Extensive operation of the neck, mediastinum and pharynx is not required.

  6. Algorithms for Anomaly Detection - Lecture 1

    CERN Multimedia

    CERN. Geneva

    2017-01-01

    The concept of statistical anomalies, or outliers, has fascinated experimentalists since the earliest attempts to interpret data. We want to know why some data points don’t seem to belong with the others: perhaps we want to eliminate spurious or unrepresentative data from our model. Or, the anomalies themselves may be what we are interested in: an outlier could represent the symptom of a disease, an attack on a computer network, a scientific discovery, or even an unfaithful partner. We start with some general considerations, such as the relationship between clustering and anomaly detection, the choice between supervised and unsupervised methods, and the difference between global and local anomalies. Then we will survey the most representative anomaly detection algorithms, highlighting what kind of data each approach is best suited to, and discussing their limitations. We will finish with a discussion of the difficulties of anomaly detection in high-dimensional data and some new directions for anomaly detec...

  7. Algorithms for Anomaly Detection - Lecture 2

    CERN Multimedia

    CERN. Geneva

    2017-01-01

    The concept of statistical anomalies, or outliers, has fascinated experimentalists since the earliest attempts to interpret data. We want to know why some data points don’t seem to belong with the others: perhaps we want to eliminate spurious or unrepresentative data from our model. Or, the anomalies themselves may be what we are interested in: an outlier could represent the symptom of a disease, an attack on a computer network, a scientific discovery, or even an unfaithful partner. We start with some general considerations, such as the relationship between clustering and anomaly detection, the choice between supervised and unsupervised methods, and the difference between global and local anomalies. Then we will survey the most representative anomaly detection algorithms, highlighting what kind of data each approach is best suited to, and discussing their limitations. We will finish with a discussion of the difficulties of anomaly detection in high-dimensional data and some new directions for anomaly detec...

  8. Water vapour source impacts on oxygen isotope variability in tropical precipitation during Heinrich events

    Directory of Open Access Journals (Sweden)

    S. C. Lewis

    2010-06-01

    Full Text Available Water isotope records such as speleothems provide extensive evidence of past tropical hydrological changes. During Heinrich events, isotopic changes in monsoon regions have been interpreted as implying a widespread drying through the Northern Hemisphere tropics and an anti-phased precipitation response in the south. Here, we examine the sources of this variability using a water isotope-enabled general circulation model, Goddard Institute for Space Studies ModelE. We incorporate a new suite of vapour source distribution tracers to help constrain the impact of precipitation source region changes on the isotopic composition of precipitation and to identify nonlocal amount effects. We simulate a collapse of the North Atlantic meridional overturning circulation with a large freshwater input to the region as an idealised analogue to iceberg discharge during Heinrich events. An increase in monsoon intensity, defined by vertical wind shear, is modelled over the South American domain, with small decreases simulated over Asia. Simulated isotopic anomalies agree well with proxy climate records, with lighter isotopic values simulated over South America and enriched values across East Asia. For this particular abrupt climate event, we identify which climatic change is most likely linked to water isotope change – changes in local precipitation amount, monsoon intensity, water vapour source distributions or precipitation seasonality. We categorise individual sites according to the climate variability that water isotope changes are most closely associated with, and find that the dominant isotopic controls are not consistent across the tropics – simple local explanations, in particular, fall short of explaining water isotope variability at all sites. Instead, the best interpretations appear to be site specific and often regional in scale.

  9. Elucidating the formation of terra fuscas using Sr–Nd–Pb isotopes and rare earth elements

    International Nuclear Information System (INIS)

    Hissler, Christophe; Stille, Peter; Juilleret, Jérôme; Iffly, Jean François; Perrone, Thierry; Morvan, Gilles

    2015-01-01

    Highlights: • Geochemical evidences on stabile phase confirm Bajocian marl as terra fusca parent material. • Precipitation/Dissolution of secondary carbonates controls geochemistry of labile phases. • This terra fusca sequence record at least four geological and environmental events. - Abstract: Carbonate weathering mantles, like terra fusca, are common in Europe but their formation and evolution is still badly understood. We propose to combine geological, mineralogical and pedological knowledge with trace element and isotope data of a weathering mantle as a novel approach to understand the evolution of terra fuscas. Sr–Nd–Pb isotopes and rare earth element (REE) contents were analyzed in a cambisol developing on a typical terra fusca on top of a condensed Bajocian limestone-marl succession from the eastern side of the Paris Basin. The isotope data, REE distribution patterns and mass balance calculations suggest that the cambisol mirrors the trace element enrichments present in this carbonate lithology, which are exceptionally high compared to global average carbonate. The deeper soil horizons are strongly enriched not only in REE (ΣREE: 2640 ppm) but also in redox-sensitive elements such as Fe (44 wt.%), V (1000 ppm), Cr (700 ppm), Zn (550 ppm), As (260 ppm), Co (45 ppm) and Cd (2.4 ppm). The trace element distribution patterns of the carbonate bedrock are similar to those of the soil suggesting their close genetic relationships. Sr–Nd–Pb isotope data allow to identify four principal components in the soil: a silicate-rich pool close to the surface, a leachable REE enriched pool at the bottom of the soil profile, the limestone on which the weathering profile developed and an anthropogenic, atmosphere-derived component detected in the soil leachates of the uppermost soil horizon. The leachable phases are mainly secondary carbonate-bearing REE phases such as bastnaesite ((X) Ca(CO 3 ) 2 F) (for X: Ce, La and Nd). The isotope data and trace element

  10. Direct determination of halogens in powdered geological and environmental samples using isotope dilution laser ablation ICP-MS

    Science.gov (United States)

    Boulyga, Sergei F.; Heumann, Klaus G.

    2005-04-01

    Laser ablation inductively coupled plasma isotope dilution mass spectrometry (LA-ICP-IDMS) with a special laser ablation system for bulk analyses (LINA-Spark(TM)-Atomiser) was applied for direct determinations of chlorine, bromine, and iodine in rock and sediment samples. Special attention was focused on possible inter-halogen fractionations and analyte/spike isotope fractionations by using LA-ICP-MS and LA-ICP-IDMS, respectively. A variation of Br/Cl and I/Cl element intensity ratios by a factor of 1.3-3 was observed when changing the nebulizer gas flow rate in the range of 0.84-1.0 L min-1 and the laser power density in the range of 2-10 GW cm-2, respectively. When using an internal standard for halogen quantification in LA-ICP-MS, this inter-element fractionation can cause systematic errors, which can be avoided by applying the isotope dilution technique. However, at high laser power densities (>5.7 GW cm-2 for iodine and >4.0 GW cm-2 for bromine and chlorine) the corresponding measured isotope ratio of the isotope-diluted sample deviates significantly from the target value. Under optimised conditions concentrations in the range of 30 [mu]g g-1-16 × 103 [mu]g g-1 for chlorine, <2-140 [mu]g g-1 for bromine, and <0.1-31 [mu]g g-1 for iodine were determined by LA-ICP-IDMS in two sediment reference materials (SRM 1646, SRM 2704) and three rock reference samples (GS-N, Granite; BX-N, Bauxite; DT-N, Disthene), which have not been certified for these halogens. The sediment results agree well within the given uncertainties with indicative values by different methods and the results of the rock samples with those obtained by negative thermal ionisation isotope dilution mass spectrometry. The detection limits of LA-ICP-IDMS are 8 [mu]g g-1 for chlorine, 1.7 [mu]g g-1 for bromine, and 0.1 [mu]g g-1 for iodine.

  11. Trace-element and Sr-Nd isotopic evidence for the origin of the Sardinian fluorite mineralization (Italy)

    International Nuclear Information System (INIS)

    Castorina, F.; Masi, U.; Padalino, G.; Palomba, M.

    2008-01-01

    The fluorite-bearing hydrothermal mineralization in Sardinia mainly occurs within Paleozoic volcanic and metasedimentary rocks. Only 3 occurrences are located in volcanic and siliciclastic Cenozoic rocks. Most Sardinian fluorites exhibit relatively high rare earth and Y (REY) contents, strong positive Y anomalies, slightly negative Ce and generally positive Eu anomalies. These features indicate that the REY were mobilized mainly from non-carbonate rocks. Neither Sr nor Nd isotopes can be used to date radiometrically the Sardinian fluorites. However, the measured Sr-isotope ratios of the fluorites hosted by Paleozoic rocks fit mixing lines in the 1000/Sr versus 87 Sr/ 86 Sr plot once recalculated at 280 Ma, suggesting that the age inferred for the correction probably represents that of the formation of the fluorite mineralization. Mixing likely occurred between diluted surficial waters and brines circulating mainly through the Lower Paleozoic metasedimentary basement. The Cenozoic fluorites exhibit chemical and isotopic features similar to those of the Paleozoic fluorites, except the Nuraghe Onigu fluorite displaying a possible contribution of Sr from Cenozoic magmatic rocks. The initial ε Nd values of the Paleozoic fluorites fit the age proposed for the formation of the deposits. Moreover, the values suggest that radiogenic Nd was provided to the fluids from the Ordovician siliciclastic basement, except for 3 deposits where the potential source rocks of Nd were mainly Ordovician acidic magmatic rocks. The initial ε Nd values of the Cenozoic fluorites suggest a provenance of Nd essentially from the leaching of Variscan granitoids

  12. Engineering Geology | Alaska Division of Geological & Geophysical Surveys

    Science.gov (United States)

    Alaska's Mineral Industry Reports AKGeology.info Rare Earth Elements WebGeochem Engineering Geology Alaska content Engineering Geology Additional information Engineering Geology Posters and Presentations Alaska Alaska MAPTEACH Tsunami Inundation Mapping Engineering Geology Staff Projects The Engineering Geology

  13. Road Anomalies Detection System Evaluation.

    Science.gov (United States)

    Silva, Nuno; Shah, Vaibhav; Soares, João; Rodrigues, Helena

    2018-06-21

    Anomalies on road pavement cause discomfort to drivers and passengers, and may cause mechanical failure or even accidents. Governments spend millions of Euros every year on road maintenance, often causing traffic jams and congestion on urban roads on a daily basis. This paper analyses the difference between the deployment of a road anomalies detection and identification system in a “conditioned” and a real world setup, where the system performed worse compared to the “conditioned” setup. It also presents a system performance analysis based on the analysis of the training data sets; on the analysis of the attributes complexity, through the application of PCA techniques; and on the analysis of the attributes in the context of each anomaly type, using acceleration standard deviation attributes to observe how different anomalies classes are distributed in the Cartesian coordinates system. Overall, in this paper, we describe the main insights on road anomalies detection challenges to support the design and deployment of a new iteration of our system towards the deployment of a road anomaly detection service to provide information about roads condition to drivers and government entities.

  14. Linking descriptive geology and quantitative machine learning through an ontology of lithological concepts

    Science.gov (United States)

    Klump, J. F.; Huber, R.; Robertson, J.; Cox, S. J. D.; Woodcock, R.

    2014-12-01

    Despite the recent explosion of quantitative geological data, geology remains a fundamentally qualitative science. Numerical data only constitute a certain part of data collection in the geosciences. In many cases, geological observations are compiled as text into reports and annotations on drill cores, thin sections or drawings of outcrops. The observations are classified into concepts such as lithology, stratigraphy, geological structure, etc. These descriptions are semantically rich and are generally supported by more quantitative observations using geochemical analyses, XRD, hyperspectral scanning, etc, but the goal is geological semantics. In practice it has been difficult to bring the different observations together due to differing perception or granularity of classification in human observation, or the partial observation of only some characteristics using quantitative sensors. In the past years many geological classification schemas have been transferred into ontologies and vocabularies, formalized using RDF and OWL, and published through SPARQL endpoints. Several lithological ontologies were compiled by stratigraphy.net and published through a SPARQL endpoint. This work is complemented by the development of a Python API to integrate this vocabulary into Python-based text mining applications. The applications for the lithological vocabulary and Python API are automated semantic tagging of geochemical data and descriptions of drill cores, machine learning of geochemical compositions that are diagnostic for lithological classifications, and text mining for lithological concepts in reports and geological literature. This combination of applications can be used to identify anomalies in databases, where composition and lithological classification do not match. It can also be used to identify lithological concepts in the literature and infer quantitative values. The resulting semantic tagging opens new possibilities for linking these diverse sources of data.

  15. Neutron activation determination of iridium, gold, platinum, and silver in geologic samples

    International Nuclear Information System (INIS)

    Millard, H.T.

    1986-01-01

    Low-level methods for the determination of iridium and other noble metals have been important in recent years due to interest in locating abundance anomalies associated with the Cretaceous/Tertiary (K/T) boundary. Typical iridium anomalies are in the range of 1 to 100 ppb. Thus methods with detection limits near 0.1 ppb should be adequate to detect K/T boundary anomalies. Radiochemical neutron activation analysis methods continue to be required although instrumental neutron activation analysis techniques employing elaborate gamma-counters are under development. In the procedure employed in this study samples irradiated in the epithermal neutron facility of the U.S. Geological Survey TRIGA Reactor are treated with a mini-fire assay technique. The iridium, gold, and silver are collected in a 1-gram metallic lead button. Primary contaminants at this stage are arsenic and antimony. These can be removed by heating the button with a mixture of sodium peroxide and sodium hydroxide. The resulting 0.2-gram lead bead is counted in a Compton suppression spectrometer. Carrier yields are determined by reirradiation of the lead beads. This procedure has been applied to the U.S.G.S. Standard Rock PCC-1. and samples from K/T boundary sites in the Western Interior of North America. (author)

  16. The geochemical record of the ancient nitrogen cycle, nitrogen isotopes, and metal cofactors.

    Science.gov (United States)

    Godfrey, Linda V; Glass, Jennifer B

    2011-01-01

    The nitrogen (N) cycle is the only global biogeochemical cycle that is driven by biological functions involving the interaction of many microorganisms. The N cycle has evolved over geological time and its interaction with the oxygen cycle has had profound effects on the evolution and timing of Earth's atmosphere oxygenation (Falkowski and Godfrey, 2008). Almost every enzyme that microorganisms use to manipulate N contains redox-sensitive metals. Bioavailability of these metals has changed through time as a function of varying redox conditions, and likely influenced the biological underpinnings of the N cycle. It is possible to construct a record through geological time using N isotopes and metal concentrations in sediments to determine when the different stages of the N cycle evolved and the role metal availability played in the development of key enzymes. The same techniques are applicable to understanding the operation and changes in the N cycle through geological time. However, N and many of the redox-sensitive metals in some of their oxidation states are mobile and the isotopic composition or distribution can be altered by subsequent processes leading to erroneous conclusions. This chapter reviews the enzymology and metal cofactors of the N cycle and describes proper utilization of methods used to reconstruct evolution of the N cycle through time. Copyright © 2011 Elsevier Inc. All rights reserved.

  17. First stage of INTRAMAP: INtegrated Transantarctic Mountains and Ross Sea Area Magnetic Anomaly Project

    Directory of Open Access Journals (Sweden)

    D. Damaske

    1999-06-01

    Full Text Available INTRAMAP (INtegrated Transantarctic Mountains and Ross Sea Area Magnetic Anomaly Project is an international effort to merge the magnetic data acquired throughout the "Ross Sea Antarctic Sector" (south of 60°S between 135°-255°E including the Transantarctic Mountains (TAM, the Ross Sea, Marie Byrd Land, and the Pacific coast, and also to begin the compilation efforts for new data over the Wilkes Basin. This project is a component of the continental scale Antarctic Digital Magnetic Anomaly Project (ADMAP. The first stage of INTRAMAP addresses the analysis and merging of GITARA (1991-1994 and GANOVEX (1984 aeromagnetic surveys together with ground magnetic data (1984-1989. The combined data sets cover an area of approximately 30 km2 over Victoria Land and adjacent Ross Sea. Map and profile gridding were implemented to integrate the data sets. These approaches are studied for improving existing strategies to adopt for the whole magnetic compilation effort. The final microlevelled grid that we produce is a new tool for regional interpretation of the main tectonic and geologic features of this sector of Antarctica.

  18. Congenital hand anomalies in Upper Egypt

    Directory of Open Access Journals (Sweden)

    Tarek Abulezz

    2016-01-01

    Full Text Available Background: Congenital hand anomalies are numerous and markedly variant. Their significance is attributed to the frequent occurrence and their serious social, psychological and functional impacts on patient's life. Patients and Methods: This is a follow-up study of 64 patients with hand anomalies of variable severity. All patients were presented to Plastic Surgery Department of Sohag University Hospital in a period of 24 months. Results: This study revealed that failure of differentiation and duplication deformities were the most frequent, with polydactyly was the most common anomaly encountered. The mean age of presentation was 6 years and female to male ratio was 1.46:1. Hand anomalies were either isolated, associated with other anomalies or part of a syndrome. Conclusion: Incidence of congenital hand anomalies in Upper Egypt is difficult to be estimated due to social and cultural concepts, lack of education, poor registration and deficient medical survey. Management of hand anomalies should be individualised, carefully planned and started as early as possible to achieve the best outcome.

  19. Hamiltonian Anomalies from Extended Field Theories

    Science.gov (United States)

    Monnier, Samuel

    2015-09-01

    We develop a proposal by Freed to see anomalous field theories as relative field theories, namely field theories taking value in a field theory in one dimension higher, the anomaly field theory. We show that when the anomaly field theory is extended down to codimension 2, familiar facts about Hamiltonian anomalies can be naturally recovered, such as the fact that the anomalous symmetry group admits only a projective representation on the Hilbert space, or that the latter is really an abelian bundle gerbe over the moduli space. We include in the discussion the case of non-invertible anomaly field theories, which is relevant to six-dimensional (2, 0) superconformal theories. In this case, we show that the Hamiltonian anomaly is characterized by a degree 2 non-abelian group cohomology class, associated to the non-abelian gerbe playing the role of the state space of the anomalous theory. We construct Dai-Freed theories, governing the anomalies of chiral fermionic theories, and Wess-Zumino theories, governing the anomalies of Wess-Zumino terms and self-dual field theories, as extended field theories down to codimension 2.

  20. High magnetic susceptibility granodiorite as a source of surface magnetic anomalies in the King George Island, Antarctica

    Science.gov (United States)

    Kon, S.; Nakamura, N.; Funaki, M.; Sakanaka, S.

    2012-12-01

    Change in plate motion produces convergence of the two oceanic lithospheres and the formation of volcanic island arcs above the subducted older and thicker plate. The association of calc-alkaline diorites to tonalites and granodiorites (ACG) is typical plutonic rocks of the volcanic arcs. In the many island arcs that surround the Pacific Ocean, ACG generally forms shallow level plutons and is closely associated with volcanic rocks. The Japan Arc setting had occurred the emplacement of the highly magnetic granitoid along the fore-arc basin before back-arc spreading at middle Miocene, showing a linear positive magnetic anomaly. Similar magnetic anomalies have also been exhibited along the Circum-Pacific Belt. Along East Antarctica, it is well known that the South Shetland Islands have been formed by back-arc spreading related to the subduction along the South Shetland trench during the late Cretaceous and middle Miocene. Moreover, geology in the South Shetland Islands consists of lava flows with subordinate pyroclastic deposits, intrusive dykes-sills, granitic plutons, displaying a typical subduction-related calc-alkaline volcanic association. However, there is little report on the presence of fore-arc granitoid. Here we report the distribution and structure of the granitic plutons around Marian Cove in the King George Island, South Shetland, East Antarctica by surface geological survey and magnetic anisotropic studies. Then we compare the distribution of granitic plutons with surface magnetic anomalies through our ship-borne and foot-borne magnetic surveys. The granitic plutons are distributed only shallow around the Marian cove in the King George Island, and the plutons had been intruded in the Sejong formation with pyroclastic deposits and basaltic/rhyoritic lavas, suggesting the post back-arc spreading. We sampled 8 plutons, 12 basaltic lavas and 6 andestic dykes, all located within four kilometer radius from the Korean Antarctic research station (King Sejong

  1. TITANIUM ISOTOPE SOURCE RELATIONS AND THE EXTENT OF MIXING IN THE PROTO-SOLAR NEBULA EXAMINED BY INDEPENDENT COMPONENT ANALYSIS

    Energy Technology Data Exchange (ETDEWEB)

    Steele, Robert C. J.; Boehnke, Patrick [Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, CA 90095 (United States)

    2015-04-01

    The Ti isotope variations observed in hibonites represent some of the largest isotope anomalies observed in the solar system. Titanium isotope compositions have previously been reported for a wide variety of different early solar system materials, including calcium, aluminum rich inclusions (CAIs) and CM hibonite grains, some of the earliest materials to form in the solar system, and bulk meteorites which formed later. These data have the potential to allow mixing of material to be traced between many different regions of the early solar system. We have used independent component analysis to examine the mixing end-members required to produce the compositions observed in the different data sets. The independent component analysis yields results identical to a linear regression for the bulk meteorites. The components identified for hibonite suggest that most of the grains are consistent with binary mixing from one of three highly anomalous nucleosynthetic sources. Comparison of these end-members show that the sources which dominate the variation of compositions in the meteorite parent body forming regions was not present in the region in which the hibonites formed. This suggests that the source which dominates variation in Ti isotope anomalies between the bulk meteorites was not present when the hibonite grains were forming. One explanation is that the bulk meteorite source may not be a primary nucleosynthetic source but was created by mixing two or more of the hibonite sources. Alternatively, the hibonite sources may have been diluted during subsequent nebula processing and are not a dominant solar system signatures.

  2. Lunar magnetic anomalies detected by the Apollo substatellite magnetometers

    Science.gov (United States)

    Hood, L.L.; Coleman, P.J.; Russell, C.T.; Wilhelms, D.E.

    1979-01-01

    Properties of lunar crustal magnetization thus far deduced from Apollo subsatellite magnetometer data are reviewed using two of the most accurate presently available magnetic anomaly maps - one covering a portion of the lunar near side and the other a part of the far side. The largest single anomaly found within the region of coverage on the near-side map correlates exactly with a conspicuous, light-colored marking in western Oceanus Procellarum called Reiner Gamma. This feature is interpreted as an unusual deposit of ejecta from secondary craters of the large nearby primary impact crater Cavalerius. An age for Cavalerius (and, by implication, for Reiner Gamma) of 3.2 ?? 0.2 ?? 109 y is estimated. The main (30 ?? 60 km) Reiner Gamma deposit is nearly uniformly magnetized in a single direction, with a minimum mean magnetization intensity of ???7 ?? 10-2 G cm3/g (assuming a density of 3 g/cm3), or about 700 times the stable magnetization component of the most magnetic returned samples. Additional medium-amplitude anomalies exist over the Fra Mauro Formation (Imbrium basin ejecta emplaced ???3.9 ?? 109 y ago) where it has not been flooded by mare basalt flows, but are nearly absent over the maria and over the craters Copernicus, Kepler, and Reiner and their encircling ejecta mantles. The mean altitude of the far-side anomaly gap is much higher than that of the near-side map and the surface geology is more complex, so individual anomaly sources have not yet been identified. However, it is clear that a concentration of especially strong sources exists in the vicinity of the craters Van de Graaff and Aitken. Numerical modeling of the associated fields reveals that the source locations do not correspond with the larger primary impact craters of the region and, by analogy with Reiner Gamma, may be less conspicuous secondary crater ejecta deposits. The reason for a special concentration of strong sources in the Van de Graaff-Aitken region is unknown, but may be indirectly

  3. Determination of isotopic ratios of osmium and ruthenium in meteorites by pretreatment and radiochemical neutron activation analysis

    International Nuclear Information System (INIS)

    Chinfang Chai; Yongzhong Liu; Xueying Mao

    1996-01-01

    The isotopic abundance ratios of 190 Os/ 184 Os and 96 Ru/ 102 Ru for the metal phases of the Jilin and Taonan stone meteorites were determined by pretreatment and radiochemical neutron activation analysis. All experimental factors affecting Os and Ru isotopic ratios were discussed, including sampling, standard, irradiation, separation and counting. The statistical errors of measurements for the 199 Os/ 184 Os ratio can be controlled within 1%. The experimental results indicate that the statistically significant anomalies of the 190 Os/ 184 Os and 96 Ru/ 102 Ru ratios have not been found relative to the terrestrial Os and Ru standards. (author). 6 refs., 1 fig., 5 tabs

  4. Development and validation of an analytical method for the determination of lead isotopic composition using ICP-QMS

    OpenAIRE

    Rodríguez-Salazar, M. T.; Morton Bermea, O.; Hernández-Álvarez, E.; García-Arreola, M. E.; Ortuño-Arzate, M. T.

    2010-01-01

    This work reports a method for the precise and accurate determination of Pb isotope composition in soils and geological matrices by ICP-QMS. Three reference materials (AGV-2, SRM 2709 and JSO-1) were repeatedly measured, using ICP-QMS instruments in order to assess the quality of this analytical procedure. Mass discrimination was evaluated for Pb/Pb with Pb isotope reference material NIST SRM 981, and the correction applied to the above mentioned reference materials to achieve good accuracy o...

  5. Airborne radiometric anomalies caused by late kinematic granite rocks in the Molson Lake-Red Sucker Lake area, east-central Manitoba

    International Nuclear Information System (INIS)

    Weber, W.; Schledewitz, D.C.P.; Soonawala, N.M.

    1982-01-01

    Geological mapping with simultaneous ground gamma ray spectrometer surveys in an area with a chain of airborne radiometric anomalies of greater than 2 ppm eU indicate uranium enrichment in late kinematic pink leucogranitic rocks including granites, alaskites, and syenites which form dykes, stocks and small plutons in a batholithic tonalite - granodiorite complex. Field geolocial evidence suggests that the potassium-rich rocks were formed by hydrothermal solutions and that at least some of them are metasomatic replacement bodies. Results of geophysical grid survey over a pronounced anomaly indicate that it is caused by a significant volume of leucogranitic rocks with an unusually high background concentration of uranium averaging 25 ppm eU. The uranium seems to be associated with hematite which coats mineral grains and fills small fractures

  6. Prenatal sonographic diagnosis of focal musculoskeletal anomalies

    International Nuclear Information System (INIS)

    Ryu, Jung-Kyu; Cho, Jeong-Yeon; Choi, Jong-Sun

    2003-01-01

    Focal musculoskeletal anomalies vary, and can manifest as part of a syndrome or be accompanied by numerous other conditions such as genetic disorders, karyotype abnormalities, central nervous system anomalies and other skeletal anomalies, lsolated focal musculoskeletal anomaly does, however, also occur; its early prenatal diagnosis is important in deciding prenatal care, and also helps in counseling parents about the postnatal effects of numerous possible associated anomalies. We have encountered 50 cases involving focal musculoskeletal anomalies, including total limb dysplasia [radial ray abnormality (n=3), mesomelic dysplasia (n=1)]; anomalies of the hand [polydactyly (n=8), syndactyly (n=3), ectrodactyly (n=1), clinodactyly (n=6), clenched hand (n=5)]; anomalies of the foot [clubfoot (n=10), rockerbottom foot (n=5), sandal gap deformity (n=1), curly toe (n=2)]; amniotic band syndrome (n=3); and anomalies of the focal spine [block vertebra (n=1), hemivertebra (n=1)]. Among these 50 cases, five [polydactyly (n=1), syndactyly (n=2) and curly toe (n=2) were confirmed by postnatal physical evaluation, two (focal spine anomalies) were diagnosed after postnatal radiologic examination, and the remaining 43 were proven at autopsy. For each condition, we describe the prenatal sonographic findings, and include a brief review

  7. Prenatal sonographic diagnosis of focal musculoskeletal anomalies

    Energy Technology Data Exchange (ETDEWEB)

    Ryu, Jung-Kyu; Cho, Jeong-Yeon; Choi, Jong-Sun [Sungkyunkwan University School of Medicine, Seoul (Korea, Republic of)

    2003-12-15

    Focal musculoskeletal anomalies vary, and can manifest as part of a syndrome or be accompanied by numerous other conditions such as genetic disorders, karyotype abnormalities, central nervous system anomalies and other skeletal anomalies, lsolated focal musculoskeletal anomaly does, however, also occur; its early prenatal diagnosis is important in deciding prenatal care, and also helps in counseling parents about the postnatal effects of numerous possible associated anomalies. We have encountered 50 cases involving focal musculoskeletal anomalies, including total limb dysplasia [radial ray abnormality (n=3), mesomelic dysplasia (n=1)]; anomalies of the hand [polydactyly (n=8), syndactyly (n=3), ectrodactyly (n=1), clinodactyly (n=6), clenched hand (n=5)]; anomalies of the foot [clubfoot (n=10), rockerbottom foot (n=5), sandal gap deformity (n=1), curly toe (n=2)]; amniotic band syndrome (n=3); and anomalies of the focal spine [block vertebra (n=1), hemivertebra (n=1)]. Among these 50 cases, five [polydactyly (n=1), syndactyly (n=2) and curly toe (n=2) were confirmed by postnatal physical evaluation, two (focal spine anomalies) were diagnosed after postnatal radiologic examination, and the remaining 43 were proven at autopsy. For each condition, we describe the prenatal sonographic findings, and include a brief review.

  8. Tellurium stable isotope fractionation in chondritic meteorites and some terrestrial samples

    Science.gov (United States)

    Fehr, Manuela A.; Hammond, Samantha J.; Parkinson, Ian J.

    2018-02-01

    New methodologies employing a 125Te-128Te double-spike were developed and applied to obtain high precision mass-dependent tellurium stable isotope data for chondritic meteorites and some terrestrial samples by multiple-collector inductively coupled plasma mass spectrometry. Analyses of standard solutions produce Te stable isotope data with a long-term reproducibility (2SD) of 0.064‰ for δ130/125Te. Carbonaceous and enstatite chondrites display a range in δ130/125Te of 0.9‰ (0.2‰ amu-1) in their Te stable isotope signature, whereas ordinary chondrites present larger Te stable isotope fractionation, in particular for unequilibrated ordinary chondrites, with an overall variation of 6.3‰ for δ130/125Te (1.3‰ amu-1). Tellurium stable isotope variations in ordinary chondrites display no correlation with Te contents or metamorphic grade. The large Te stable isotope fractionation in ordinary chondrites is likely caused by evaporation and condensation processes during metamorphism in the meteorite parent bodies, as has been suggested for other moderately and highly volatile elements displaying similar isotope fractionation. Alternatively, they might represent a nebular signature or could have been produced during chondrule formation. Enstatite chondrites display slightly more negative δ130/125Te compared to carbonaceous chondrites and equilibrated ordinary chondrites. Small differences in the Te stable isotope composition are also present within carbonaceous chondrites and increase in the order CV-CO-CM-CI. These Te isotope variations within carbonaceous chondrites may be due to mixing of components that have distinct Te isotope signatures reflecting Te stable isotope fractionation in the early solar system or on the parent bodies and potentially small so-far unresolvable nucleosynthetic isotope anomalies of up to 0.27‰. The Te stable isotope data of carbonaceous and enstatite chondrites displays a general correlation with the oxidation state and hence might

  9. Complete second branchial cleft anomaly presenting as a fistula and a tonsillar cyst: an interesting congenital anomaly.

    Science.gov (United States)

    Thottam, Prasad John; Bathula, Samba S; Poulik, Janet M; Madgy, David N

    2014-01-01

    Branchial cleft anomalies make up 30% of all pediatric neck masses, but complete second branchial cleft anomalies are extremely rare. We report an unusual case of a complete second branchial cleft anomaly that presented as a draining neck fistula and a tonsillar cyst in an otherwise healthy 3-month-old girl. At the age of 7 months, the patient had been experiencing feeding difficulties, and there was increasing concern about the risk of persistent infections. At that point, the anomaly was excised in its entirety. Our suspicion that the patient had a complete second branchial cleft anomaly was confirmed by imaging, surgical excision, and histopathologic analysis.

  10. Numerical model to simulate the isotopic and heat release and transport through the geosphere from a geological repository of radioactive wastes

    International Nuclear Information System (INIS)

    Hidalgo Lopez, A.

    2002-01-01

    The aim of this research is to simulate the isotopic and heat release and transport through the geosphere, from a geological repository of high level nuclear waste. in order to achieve it, different physical processes, that have to do with the problem, are considered: groundwater flow, radioactive decay, nuclide dissolution in groundwater, heat generation, mass and heat transport. Some of these phenomena are related among the, which allows to build a coupled model,which is the starting point to generate a FORTRAN code. The flow and transport models are developed in two spatial dimensions and are integrated in space by means of a finite volume method. The time integration is fulfilled by a θ-method. Moreover, the advection-diffusion equation is solved by two finite volume techniques. In the first one a linear interpolation is used whereas in the second it is used a quadratic one. Also, a consistency an stability study of both methods is carried out in order to compare their stability zones and the errors appearing. Stability is analysed by applying the von Neumann method, which is based upon Fourier series. Although it is a classical technique when dealing with finite-difference schemes, it is here applied to two finite volume schemes. (Author)

  11. Analysis of Renal Anomalies in VACTERL Association

    OpenAIRE

    Cunningham, Bridget K.; Khromykh, Alina; Martinez, Ariel F.; Carney, Tyler; Hadley, Donald W.; Solomon, Benjamin D.

    2014-01-01

    VACTERL association refers to a combination of congenital anomalies that can include: Vertebral anomalies, Anal atresia, Cardiac malformations, Tracheo-Esophageal fistula with esophageal atresia, Renal anomalies (typically structural renal anomalies), and Limb anomalies. We conducted a description of a case series to characterize renal findings in a cohort of patients with VACTERL association. Out of the overall cohort, 48 patients (with at least 3 component features of VACTERL and who had ab...

  12. Sea surface temperature anomalies in the Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    RameshKumar, M.R.

    temperature anomalies for the above regions respectively. An analysis has shown that most of the short duration anomalies (i.e., anomalies with periods less than 4 months) are driven by the surface heat fluxes. The medium duration anomalies (i.e., anomalies...

  13. Anomalies and gravity

    International Nuclear Information System (INIS)

    Mielke, Eckehard W.

    2006-01-01

    Anomalies in Yang-Mills type gauge theories of gravity are reviewed. Particular attention is paid to the relation between the Dirac spin, the axial current j5 and the non-covariant gauge spin C. Using diagrammatic techniques, we show that only generalizations of the U(1)- Pontrjagin four-form F and F = dC arise in the chiral anomaly, even when coupled to gravity. Implications for Ashtekar's canonical approach to quantum gravity are discussed

  14. Fivebrane gravitational anomalies

    International Nuclear Information System (INIS)

    Becker, Katrin; Becker, Melanie

    2000-01-01

    Freed, Harvey, Minasian and Moore (FHMM) have proposed a mechanism to cancel the gravitational anomaly of the M-theory fivebrane coming from diffeomorphisms acting on the normal bundle. This procedure is based on a modification of the conventional M-theory Chern-Simons term. We apply the FHMM mechanism in the ten-dimensional type IIA theory. We then analyze the relation to the anomaly cancellation mechanism for the type IIA fivebrane proposed by Witten

  15. Gaining the necessary geologic, hydrologic, and geochemical understanding for additional brackish groundwater development, coastal San Diego, California, USA

    Science.gov (United States)

    Danskin, Wesley R.

    2012-01-01

    Local water agencies and the United States Geological Survey are using a combination of techniques to better understand the scant freshwater resources and the much more abundant brackish resources in coastal San Diego, California, USA. Techniques include installation of multiple-depth monitoring well sites; geologic and paleontological analysis of drill cuttings; geophysical logging to identify formations and possible seawater intrusion; sampling of pore-water obtained from cores; analysis of chemical constituents including trace elements and isotopes; and use of scoping models including a three-dimensional geologic framework model, rainfall-runoff model, regional groundwater flow model, and coastal density-dependent groundwater flow model. Results show that most fresh groundwater was recharged during the last glacial period and that the coastal aquifer has had recurring intrusions of fresh and saline water. These intrusions disguise the source, flowpaths, and history of ground water near the coast. The flow system includes a freshwater lens resting on brackish water; a 100-meter-thick flowtube of freshwater discharging under brackish estuarine water and above highly saline water; and broad areas of fine-grained coastal sediment filled with fairly uniform brackish water. Stable isotopes of hydrogen and oxygen indicate the recharged water flows through many kilometers of fractured crystalline rock before entering the narrow coastal aquifer.

  16. Analyticity properties of Graham-Witten anomalies

    International Nuclear Information System (INIS)

    Asnin, Vadim

    2008-01-01

    Analytic properties of Graham-Witten anomalies are considered. Weyl anomalies according to their analytic properties are of type A (coming from δ-singularities in correlators of several energy-momentum tensors) or of type B (originating in counterterms which depend logarithmically on a mass scale). It is argued that all Graham-Witten anomalies can be divided into two groups, internal and external, and that all external anomalies are of type B, whereas among internal anomalies there is one term of type A and all the rest are of type B. This argument is checked explicitly for the case of a free scalar field in a six-dimensional space with a two-dimensional submanifold

  17. Geologic and geophysical data for wells drilled at Raft River Valley, Cassia County, Idaho, in 1977-1978 and data for wells drilled previously

    Science.gov (United States)

    Nathenson, Manuel; Urban, Thomas C.; Covington, Harry R.

    2014-01-01

    In order to better define the size of the thermal anomaly in the Raft River Valley, Idaho, the U.S. Geological Survey drilled a series of intermediate-depth (nominal 500-ft depth) wells in 1977 and 1978.  This report presents geologic, geophysical, and temperature data for these drill holes, along with data for five wells drilled by the Idaho National Engineering Laboratory with U.S. Department of Energy Funding.  Data previously reported for other drill holes are also included in order to make them available as digital files.

  18. Holographic entanglement entropy and gravitational anomalies

    NARCIS (Netherlands)

    Castro, A.; Detournay, S.; Iqbal, N.; Perlmutter, E.

    2014-01-01

    We study entanglement entropy in two-dimensional conformal field theories with a gravitational anomaly. In theories with gravity duals, this anomaly is holographically represented by a gravitational Chern-Simons term in the bulk action. We show that the anomaly broadens the Ryu-Takayanagi minimal

  19. Toward Baseline Software Anomalies in NASA Missions

    Science.gov (United States)

    Layman, Lucas; Zelkowitz, Marvin; Basili, Victor; Nikora, Allen P.

    2012-01-01

    In this fast abstract, we provide preliminary findings an analysis of 14,500 spacecraft anomalies from unmanned NASA missions. We provide some baselines for the distributions of software vs. non-software anomalies in spaceflight systems, the risk ratings of software anomalies, and the corrective actions associated with software anomalies.

  20. Seawater calcium isotope ratios across the Eocene-Oligocene transition

    Science.gov (United States)

    Griffith, E.M.; Paytan, A.; Eisenhauer, A.; Bullen, T.D.; Thomas, E.

    2011-01-01

    During the Eocene-Oligocene transition (EOT, ca. 34 Ma), Earth's climate cooled significantly from a greenhouse to an icehouse climate, while the calcite (CaCO3) compensation depth (CCD) in the Pacific Ocean increased rapidly. Fluctuations in the CCD could result from various processes that create an imbalance between calcium (Ca) sources to, and sinks from, the ocean (e.g., weathering and CaCO3 deposition), with different effects on the isotopic composition of dissolved Ca in the oceans due to differences in the Ca isotopic composition of various inputs and outputs. We used Ca isotope ratios (??44/40Ca) of coeval pelagic marine barite and bulk carbonate to evaluate changes in the marine Ca cycle across the EOT. We show that the permanent deepening of the CCD was not accompanied by a pronounced change in seawater ??44/40Ca, whereas time intervals in the Neogene with smaller carbonate depositional changes are characterized by seawater ??44/40Ca shifts. This suggests that the response of seawater ??44/40Ca to changes in weathering fluxes and to imbalances in the oceanic alkalinity budget depends on the chemical composition of seawater. A minor and transient fluctuation in the Ca isotope ratio of bulk carbonate may reflect a change in isotopic fractionation associated with CaCO3 precipitation from seawater due to a combination of factors, including changes in temperature and/or in the assemblages of calcifying organisms. ?? 2011 Geological Society of America.

  1. A state geological survey commitment to environmental geology - the Texas Bureau of Economic Geology

    International Nuclear Information System (INIS)

    Wermund, E.G.

    1990-01-01

    In several Texas environmental laws, the Bureau of Economic Geology is designated as a planning participant and review agency in the process of fulfilling environmental laws. Two examples are legislation on reclamation of surface mines and regulation of processing low level radioactive wastes. Also, the Bureau is the principal geological reviewer of all Environmental Assessments and Environmental Impact Statements which the Office of the Governor circulates for state review on all major developmental activities in Texas. The BEG continues its strong interest in environmental geology. In February 1988, it recommitted its Land Resources Laboratory, initiated in 1974, toward fulfilling needs of state, county, and city governments for consultation and research on environmental geologic problems. An editorial from another state geological survey would resemble the about description of texas work in environmental geology. State geological surveys have led federal agencies into many developments of environmental geology, complemented federal efforts in their evolution, and continued a strong commitment to the maintenance of a quality environment through innovative geologic studies

  2. Branchial anomalies in the pediatric population.

    Science.gov (United States)

    Schroeder, James W; Mohyuddin, Nadia; Maddalozzo, John

    2007-08-01

    We sought to review the presentation, evaluation, and treatment of branchial anomalies in the pediatric population and to relate these findings to recurrences and complications. We conducted a retrospective study at a tertiary care pediatric hospital. Ninety-seven pediatric patients who were treated for branchial anomalies over a 10-year period were reviewed. Patients were studied if they underwent surgical treatment for the branchial anomaly and had 1 year of postoperative follow-up; 67 children met criteria, and 74 anomalies were studied. Patients with cysts presented at a later age than did those with branchial anomaly fistulas or sinus branchial anomalies. 32% of branchial anomalies were previously infected. Of these, 71% had more than one preoperative infection. 18% of the BA were first arch derivatives, 69% were second arch derivatives and 7% were third arch derivatives. There were 22 branchial cysts, 31 branchial sinuses and 16 branchial fistulas. The preoperative and postoperative diagnoses differed in 17 cases. None of the excised specimens that contained a cystic lining recurred; all five recurrences had multiple preoperative infections. Recurrence rates are increased when there are multiple preoperative infections and when there is no epithelial lining identified in the specimen.

  3. Dynamical supersymmetry breaking and gauge anomalies

    International Nuclear Information System (INIS)

    Zhang, H.

    1991-01-01

    Some aspects of supersymmetric gauge theories are discussed. It is shown that dynamical supersymmetry breaking does not occur in supersymmetric QED in higher dimensions. The cancellation of both local (perturbative) and global (non-perturbative) gauge anomalies are also discussed in supersymmetric gauge theories. We argue that there is no dynamical supersymmetry breaking in higher dimensions in any supersymmetric gauge theories free of gauge anomalies. It is also shown that for supersymmetric gauge theories in higher dimensions with a compact connected simple gauge group, when the local anomaly-free condition is satisfied, there can be at most a possible Z 2 global gauge anomaly in extended supersymmetric SO(10) (or spin (10)) gauge theories in D=10 dimensions containing additional Weyl fermions in a spinor representation of SO(10) (or spin (10)). In four dimensions with local anomaly-free condition satisfied, the only possible global gauge anomalies in supersymmetric gauge theories are Z 2 global gauge anomalies for extended supersymmetric SP(2N) (N=rank) gauge theories containing additional Weyl fermions in a representation of SP(2N) with an odd 2nd-order Dynkin index. (orig.)

  4. On Newton-Cartan trace anomalies

    International Nuclear Information System (INIS)

    Auzzi, Roberto; Baiguera, Stefano; Nardelli, Giuseppe

    2016-01-01

    We classify the trace anomaly for parity-invariant non-relativistic Schrödinger theories in 2+1 dimensions coupled to background Newton-Cartan gravity. The general anomaly structure looks very different from the one in the z=2 Lifshitz theories. The type A content of the anomaly is remarkably identical to that of the relativistic 3+1 dimensional case, suggesting the conjecture that an a-theorem should exist also in the Newton-Cartan context.

  5. On Newton-Cartan trace anomalies

    Energy Technology Data Exchange (ETDEWEB)

    Auzzi, Roberto [Dipartimento di Matematica e Fisica, Università Cattolica del Sacro Cuore,Via Musei 41, 25121 Brescia (Italy); INFN Sezione di Perugia,Via A. Pascoli, 06123 Perugia (Italy); Baiguera, Stefano [Dipartimento di Matematica e Fisica, Università Cattolica del Sacro Cuore,Via Musei 41, 25121 Brescia (Italy); Nardelli, Giuseppe [Dipartimento di Matematica e Fisica, Università Cattolica del Sacro Cuore,Via Musei 41, 25121 Brescia (Italy); TIFPA - INFN, c/o Dipartimento di Fisica, Università di Trento,38123 Povo (Italy)

    2016-02-01

    We classify the trace anomaly for parity-invariant non-relativistic Schrödinger theories in 2+1 dimensions coupled to background Newton-Cartan gravity. The general anomaly structure looks very different from the one in the z=2 Lifshitz theories. The type A content of the anomaly is remarkably identical to that of the relativistic 3+1 dimensional case, suggesting the conjecture that an a-theorem should exist also in the Newton-Cartan context.

  6. Iodine-129 in thyroids and tellurium isotopes in meteorites by neutron activation analysis

    International Nuclear Information System (INIS)

    Ballad, R.V.

    1978-06-01

    A combination of neutron activation and mass spectrometry has been used to determine the concentration of fissiogenic 129 I and the value of the 129 I/ 127 I ratio in thyroids of man, cow, and deer from Missouri. Deer thyroids show an average value of 129 I/ 127 I = 1.8 x 10 -8 and an average concentration of 3 x 10 -3 pCi 129 I per gram of thyroid (wet weight). Thyroids of cows and humans show successively lower values for the 129 I/ 127 I ratio and the 129 I content because their diets dilute fission-produced 129 I in the natural iodine cycle with mineral iodine. The results of analyses on a few thyroids from other geographic areas are also reported. The isotopic compositions of tellurium, krypton, and xenon were determined in acid-resistant residues of the Allende meteorite. Neutron activation and γ-counting were used to determine the relative abundances of six tellurium isotopes, and mass spectrometry was used to determine the isotopic compositions of krypton and xenon in aliquots of the same residues. Nucleogenetic anomalies were observed in the isotopic compositions of these three elements. The presence of isotopically distinct components of tellurium, krypton, and xenon in these residues provides strong support for the suggestion that our solar system formed directly from the debris of a supernova

  7. Sm-Nd isotope system of the Ukrainian shield (Korosten'sky massif) anorthosite-granite formation

    Energy Technology Data Exchange (ETDEWEB)

    Bogatikov, O A; Karpenko, S F; Sukhanov, M K; Spiridonov, V G

    1988-01-01

    The results of Sm-Nd isotope investigation of rocks of the Ukrainian shield anorthosite-granite association are described; this association, according to the geologic data, is the latest association in a seriesof self-contained anorthosited. The latters are connected with considerable masses of rapakiwi-granited. Isotope analysis is carried out by mass spectrometry. Isotope ratios /sup 147/Sm//sup 144/Nd and /sup 143/Nd//sup 144/Nd for five samples investigated are presented. Isotope data obtained are marked to be important information about the origin of rocks studied. Evident age difference of granite and basic components of the association is established, that idnores the possibility of the rock formation during crystallization differentiation. The basic value of the radiometric 1.89-1.74 milliared years age of the Ukrainian shield anorthosites lied in the fact that these data confirm once more the specific nature of the earth's crust evolution especially at early stages of its formation.

  8. Coronary Artery Anomalies in Animals

    Directory of Open Access Journals (Sweden)

    Brian A. Scansen

    2017-04-01

    Full Text Available Coronary artery anomalies represent a disease spectrum from incidental to life-threatening. Anomalies of coronary artery origin and course are well-recognized in human medicine, but have received limited attention in veterinary medicine. Coronary artery anomalies are best described in the dog, hamster, and cow though reports also exist in the horse and pig. The most well-known anomaly in veterinary medicine is anomalous coronary artery origin with a prepulmonary course in dogs, which limits treatment of pulmonary valve stenosis. A categorization scheme for coronary artery anomalies in animals is suggested, dividing these anomalies into those of major or minor clinical significance. A review of coronary artery development, anatomy, and reported anomalies in domesticated species is provided and four novel canine examples of anomalous coronary artery origin are described: an English bulldog with single left coronary ostium and a retroaortic right coronary artery; an English bulldog with single right coronary ostium and transseptal left coronary artery; an English bulldog with single right coronary ostium and absent left coronary artery with a prepulmonary paraconal interventricular branch and an interarterial circumflex branch; and a mixed-breed dog with tetralogy of Fallot and anomalous origin of all coronary branches from the brachiocephalic trunk. Coronary arterial fistulae are also described including a coronary cameral fistula in a llama cria and an English bulldog with coronary artery aneurysm and anomalous shunting vessels from the right coronary artery to the pulmonary trunk. These examples are provided with the intent to raise awareness and improve understanding of such defects.

  9. Geologic and geophysical investigations of the Zuni-Bandera volcanic field, New Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ander, M.E.; Heiken, G.; Eichelberger, J.; Laughlin, A.W.; Huestis, S.

    1981-05-01

    A positive, northeast-trending gravity anomaly, 90 km long and 30 km wide, extends southwest from the Zuni uplift, New Mexico. The Zuni-Bandera volcanic field, an alignment of 74 basaltic vents, is parallel to the eastern edge of the anomaly. Lavas display a bimodal distribution of tholeiitic and alkalic compositions, and were erupted over a period from 4 Myr to present. A residual gravity profile taken perpendicular to the major axis of the anomaly was analyzed using linear programming and ideal body theory to obtain bounds on the density contrast, depth, and minimum thickness of the gravity body. Two-dimensionality was assumed. The limiting case where the anomalous body reaches the surface gives 0.1 g/cm/sup 3/ as the greatest lower bound on the maximum density contrast. If 0.4 g/cm/sup 3/ is taken as the geologically reasonable upper limit on the maximum density contrast, the least upper bound on the depth of burial is 3.5 km and minimum thickness is 2 km. A shallow mafic intrusion, emplaced sometime before Laramide deformation, is proposed to account for the positive gravity anomaly. Analysis of a magnetotelluric survey suggests that the intrusion is not due to recent basaltic magma associated with the Zuni-Bandera volcanic field. This large basement structure has controlled the development of the volcanic field; vent orientations have changed somewhat through time, but the trend of the volcanic chain followed the edge of the basement structure. It has also exhibited some control on deformation of the sedimentary section.

  10. Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

    Energy Technology Data Exchange (ETDEWEB)

    Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

    1985-01-01

    An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

  11. Nd isotopes and crustal growth rate

    International Nuclear Information System (INIS)

    Albarede, F.

    1988-01-01

    Sm/Nd isotopic constraints on crustal growth is discussed. In order to constrain Sm/Nd fractionation between continental crust and depleted mantle, an extensive data base of isotopic measurements (assumed to be adequately representative of continental crust) was compiled. The results imply that the evolution of depleted mantles was roughly linear, with no major discontinuities over the course of geologic time. This is different from other determinations of depleting mantle evolution, which show nonlinear behavior. The Sm/Nd evolution lines for continental crust and depleted mantle intersect between 3.8 to 4.0 Ga, which may indicate that the onset of continental growth was later than 4.5 Ga. A mathematical model is described, the results of which imply that time integrated crustal additions from the mantle are about 1.8 to 2.5 cu km/a, whereas crustal subtractions by sediment recycling are about 0.6 to 1.5 cu km/a. This results in a net time integrated crustal growth rate of about 1 cu km/a, which is similar to present day rates determined, for example, by Reymer and Schubert

  12. PLANETARY-SCALE STRONTIUM ISOTOPIC HETEROGENEITY AND THE AGE OF VOLATILE DEPLETION OF EARLY SOLAR SYSTEM MATERIALS

    Energy Technology Data Exchange (ETDEWEB)

    Moynier, Frederic; Podosek, Frank A. [Department of Earth and Planetary Science and McDonnell Center for Space Sciences, Washington University, St. Louis, MO 63130 (United States); Day, James M. D. [Geosciences Research Division, Scripps Institution of Oceanography, La Jolla, CA 92093-0244 (United States); Okui, Wataru; Yokoyama, Tetsuya [Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551 (Japan); Bouvier, Audrey [Department of Earth Sciences, University of Minnesota, Minneapolis, MN 55455-0231 (United States); Walker, Richard J., E-mail: moynier@levee.wustl.edu, E-mail: fap@levee.wustl.edu, E-mail: jmdday@ucsd.edu, E-mail: rjwalker@umd.edu, E-mail: okui.w.aa@m.titech.ac.jp, E-mail: tetsuya.yoko@geo.titech.ac.jp, E-mail: abouvier@umn.edu [Department of Geology, University of Maryland, College Park, MD 20742 (United States)

    2012-10-10

    Isotopic anomalies in planetary materials reflect both early solar nebular heterogeneity inherited from presolar stellar sources and processes that generated non-mass-dependent isotopic fractionations. The characterization of isotopic variations in heavy elements among early solar system materials yields important insight into the stellar environment and formation of the solar system, and about initial isotopic ratios relevant to long-term chronological applications. One such heavy element, strontium, is a central element in the geosciences due to wide application of the long-lived {sup 87}Rb-{sup 87}Sr radioactive as a chronometer. We show that the stable isotopes of Sr were heterogeneously distributed at both the mineral scale and the planetary scale in the early solar system, and also that the Sr isotopic heterogeneities correlate with mass-independent oxygen isotope variations, with only CI chondrites plotting outside of this correlation. The correlation implies that most solar system material formed by mixing of at least two isotopically distinct components: a CV-chondrite-like component and an O-chondrite-like component, and possibly a distinct CI-chondrite-like component. The heterogeneous distribution of Sr isotopes may indicate that variations in initial {sup 87}Sr/{sup 86}Sr of early solar system materials reflect isotopic heterogeneity instead of having chronological significance, as interpreted previously. For example, given the differences in {sup 84}Sr/{sup 86}Sr between calcium aluminum inclusions and eucrites ({epsilon}{sup 84}Sr > 2), the difference in age between these materials would be {approx}6 Ma shorter than previously interpreted, placing the Sr chronology in agreement with other long- and short-lived isotope systems, such as U-Pb and Mn-Cr.

  13. Geological, geochemical, and geophysical studies by the U.S. Geological Survey in Big Bend National Park, Texas

    Science.gov (United States)

    Page, W.R.; Turner, K.J.; Bohannon, R.G.; Berry, M.E.; Williams, V.S.; Miggins, D.P.; Ren, M.; Anthony, E.Y.; Morgan, L.A.; Shanks, P.W.C.; Gray, J. E.; Theodorakos, P.M.; Krabbenhoft, D. P.; Manning, A.H.; Gemery-Hill, P. A.; Hellgren, E.C.; Stricker, C.A.; Onorato, D.P.; Finn, C.A.; Anderson, E.; Gray, J. E.; Page, W.R.

    2008-01-01

    . Because the last geologic map of the entire BBNP was published in the 1960s, one of the primary goals of the USGS is to provide a new geologic map of BBNP at a scale 1:100,000; this work is ongoing among the USGS, NPS, the Texas Bureau of Economic Geology, and university scientists. This USGS Circular summarizes eight studies funded and primarily carried out by the USGS, but it is not intended to be a comprehensive reference of work conducted in BBNP. This Circular describes topical research of the recently completed interdisciplinary USGS project, which has provided information leading to a more complete understanding of the following topics in BBNP: Tectonic and geologic history (Chapters 1, 2, and 3), Age and formation processes of a skarn mineral deposit (Chapter 4), Geoenvironmental effects of abandoned mercury mines (Chapter 5), Age, source, and geochemistry of surface and subsurface water resources (Chapter 6), Isotopic tracing of food sources of bears (Chapter 7), and Geophysical characteristics of surface and subsurface geology (Chapter 8).Additional information and the geochemical and geophysical data of the USGS studies in BBNP are available on line at http://minerals.cr.usgs.gov/projects/big_bend/index.html.

  14. Ferret Workflow Anomaly Detection System

    National Research Council Canada - National Science Library

    Smith, Timothy J; Bryant, Stephany

    2005-01-01

    The Ferret workflow anomaly detection system project 2003-2004 has provided validation and anomaly detection in accredited workflows in secure knowledge management systems through the use of continuous, automated audits...

  15. Geographic variation of stable isotopes in African elephant ivory

    Science.gov (United States)

    Ziegler, S.; Merker, S.; Jacob, D.

    2012-04-01

    In 1989, the international community listed the African elephant in Appendix I of the Convention on International Trade in Endangered Species of Wild Fauna and Flora (CITES) thus prohibiting commercial ivory trade. Recent surveillance data show that the illegal trade in ivory has been growing worldwide. Long-term preservation of many of the African elephant populations can be supported with a control mechanism that helps with the implementation of remedial conservation action. Therefore, setting up a reference database that predicts the origin of ivory specimens can assist in determining smuggling routes and the provenance of illegal ivory. Our research builds on earlier work to seek an appropriate method for determining the area of origin for individual tusks. Several researchers have shown that the provenance of elephant ivory can be traced by its isotopic composition, but this is the first attempt to produce an integrated isotopic reference database of elephant ivory provenance. We applied a combination of various routine geochemical analyses to measure the stable isotope ratios of hydrogen, carbon, nitrogen, oxygen, and sulphur. Up to now, we analysed 606 ivory samples of known geographical origin from African range states, museums and private collections, comprising 22 African elephant range states. The isotopic measurements were superimposed with data layers from vegetation, geology and climate. A regression function for the isotope composition of the water isotopes in precipitation and collagen in ivory was developed to overcome the problem of imprecise origin of some of the sampled material. Multivariate statistics, such as nearest neighborhood and discriminate analysis were applied to eventually allow a statistical determination of the provenance for ivory of unknown origin. Our results suggest that the combination of isotopic parameters have the potential to provide predictable and complementary markers for estimating the origin of seized elephant ivory.

  16. Analysis and application of heavy isotopes in the environment

    Science.gov (United States)

    Steier, Peter; Dellinger, Franz; Forstner, Oliver; Golser, Robin; Knie, Klaus; Kutschera, Walter; Priller, Alfred; Quinto, Francesca; Srncik, Michaela; Terrasi, Filippo; Vockenhuber, Christof; Wallner, Anton; Wallner, Gabriele; Wild, Eva Maria

    2010-04-01

    A growing number of AMS laboratories are pursuing applications of actinides. We discuss the basic requirements of the AMS technique of heavy (i.e., above ˜150 amu) isotopes, present the setup at the Vienna Environmental Research Accelerator (VERA) which is especially well suited for the isotope 236U, and give a comparison with other AMS facilities. Special emphasis will be put on elaborating the effective detection limits for environmental samples with respect to other mass spectrometric methods. At VERA, we have carried out measurements for radiation protection and environmental monitoring ( 236U, 239,240,241,242,244Pu), astrophysics ( 182Hf, 236U, 244Pu, 247Cm), nuclear physics, and a search for long-lived super-heavy elements ( Z > 100). We are pursuing the environmental distribution of 236U, as a basis for geological applications of natural 236U.

  17. Analysis and application of heavy isotopes in the environment

    International Nuclear Information System (INIS)

    Steier, Peter; Dellinger, Franz; Forstner, Oliver; Golser, Robin; Knie, Klaus; Kutschera, Walter; Priller, Alfred; Quinto, Francesca; Srncik, Michaela; Terrasi, Filippo; Vockenhuber, Christof; Wallner, Anton; Wallner, Gabriele; Wild, Eva Maria

    2010-01-01

    A growing number of AMS laboratories are pursuing applications of actinides. We discuss the basic requirements of the AMS technique of heavy (i.e., above ∼150 amu) isotopes, present the setup at the Vienna Environmental Research Accelerator (VERA) which is especially well suited for the isotope 236 U, and give a comparison with other AMS facilities. Special emphasis will be put on elaborating the effective detection limits for environmental samples with respect to other mass spectrometric methods. At VERA, we have carried out measurements for radiation protection and environmental monitoring ( 236 U, 239,240,241,242,244 Pu), astrophysics ( 182 Hf, 236 U, 244 Pu, 247 Cm), nuclear physics, and a search for long-lived super-heavy elements (Z > 100). We are pursuing the environmental distribution of 236 U, as a basis for geological applications of natural 236 U.

  18. Sr and Nd isotopes in basalts form the East Pacific Rise: Significance for mantle heterogeneity

    International Nuclear Information System (INIS)

    Macdougall, J.D.; Lugmair, G.W.

    1986-01-01

    Isotopic data for Sr and Nd from fresh glassy East Pacific Rise basalts suggest that this part of the suboceanic mantle is characterized by subtle but distinct large-scale regional isotopic variability which may reflect differences between cells of the convecting mantle. In spite of a systematic N-S change in spreading rate of a factor of three along the sampled portion of the EPR, no correlation is observed between spreading rate and range of isotopic composition, indicating that the regional variations override homogenization effects which may be correlated with rate of magma generation and hence spreading rate. There is no clear signature in our data of effects from the postulated global ''Dupal Anomaly''. However, for a restricted ridge segment at the latitude of Easter Island, anomalously high 87 Sr/ 86 Sr and low 143 Nd/ 144 Nd occur, coupled with high incompatible element concentrations. These features are most easily understood as being the result of inclusion of a ''plume'' component in these ridge basalts. (orig.)

  19. Measurement of zinc stable isotope ratios in biogeochemical matrices by double-spike MC-ICPMS and determination of the isotope ratio pool available for plants from soil.

    Science.gov (United States)

    Arnold, Tim; Schönbächler, Maria; Rehkämper, Mark; Dong, Schuofei; Zhao, Fang-Jie; Kirk, Guy J D; Coles, Barry J; Weiss, Dominik J

    2010-12-01

    Analysis of naturally occurring isotopic variations is a promising tool for investigating Zn transport and cycling in geological and biological settings. Here, we present the recently installed double-spike (DS) technique at the MAGIC laboratories at Imperial College London. The procedure improves on previous published DS methods in terms of ease of measurement and precisions obtained. The analytical method involves addition of a (64)Zn-(67)Zn double-spike to the samples prior to digestion, separation of Zn from the sample matrix by ion exchange chromatography, and isotopic analysis by multiple-collector inductively coupled plasma mass spectrometry. The accuracy and reproducibility of the method were validated by analyses of several in-house and international elemental reference materials. Multiple analyses of pure Zn standard solutions consistently yielded a reproducibility of about ±0.05‰ (2 SD) for δ(66)Zn, and comparable precisions were obtained for analyses of geological and biological materials. Highly fractionated Zn standards analyzed by DS and standard sample bracketing yield slightly varying results, which probably originate from repetitive fractionation events during manufacture of the standards. However, the δ(66)Zn values (all reported relative to JMC Lyon Zn) for two less fractionated in-house Zn standard solutions, Imperial Zn (0.10 ± 0.08‰: 2 SD) and London Zn (0.08 ± 0.04‰), are within uncertainties to data reported with different mass spectrometric techniques and instruments. Two standard reference materials, blend ore BCR 027 and ryegrass BCR 281, were also measured, and the δ(66)Zn were found to be 0.25 ± 0.06‰ (2 SD) and 0.40 ± 0.09‰, respectively. Taken together, these standard measurements ascertain that the double-spike methodology is suitable for accurate and precise Zn isotope analyses of a wide range of natural samples. The newly installed technique was consequently applied to soil samples and soil leachates to

  20. Prenatal sonographic diagnosis of focal musculoskeletal anomalies

    Energy Technology Data Exchange (ETDEWEB)

    Ryu, Jung Kyu; Cho, Jeong Yeon; Lee, Young Ho; Kim, Ei Jeong; Chun, Yi Kyeong [Samsung Cheil Hospital, Sungkyunkwan University School of Medicine, Seoul (Korea, Republic of)

    2002-09-15

    Focal musculoskeletal anomalies are various and may be an isolated finding or may be found in conjunction with numerous associations, including genetic syndromes, Karyotype abnormals, central nervous system anomalies and other general musculoskeletal disorders. Early prenatal diagnosis of these focal musculoskeletal anomalies nor only affects prenatal care and postnatal outcome but also helps in approaching other numerous associated anomalies.